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Sample records for agglomerated debris particles

  1. Air agglomeration of hydrophobic particles

    SciTech Connect

    Drzymala, J.; Wheelock, T.D.

    1995-12-31

    The agglomeration of hydrophobic particles in an aqueous suspension was accomplished by introducing small amounts of air into the suspension while it was agitated vigorously. The extent of aggregation was proportional both to the air to solids ratio and to the hydrophobicity of the solids. For a given air/solids ratio, the extent of aggregation of different materials increased in the following order: graphite, gilsonite, coal coated with heptane, and Teflon. The structure of agglomerates produced from coarse Teflon particles differed noticeably from the structure of bubble-particle aggregates produced from smaller, less hydrophobic particles.

  2. Particle Agglomeration in Bipolar Barb Agglomerator Under AC Electric Field

    NASA Astrophysics Data System (ADS)

    Huang, Chao; Ma, Xiuqin; Sun, Youshan; Wang, Meiyan; Zhang, Changping; Lou, Yueya

    2015-04-01

    The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious. To improve agglomeration effectiveness of fine particles, a dual zone electric agglomeration device consisting of a charging chamber and an agglomeration chamber with bipolar barb electrodes was developed. The bipolar barb electric agglomerator with a polar distance of 200 mm demonstrates good agglomeration effectiveness for particles with a size less than 8.0 μm under applied AC electric field. An optimal condition for achieving better agglomeration effectiveness was found to be as follows: flue gas flow velocity of 3.00 m/s, particle concentration of 2.00 g/m3, output voltage of 35 kV and length of the barb of 16 mm. In addition, 4.0-6.0 μm particles have the best effectiveness with the variation of particle volume occupancy of -3.2. supported by the Key Technology R&D Program of Hebei, China (No. 13211207D)

  3. Modeling of particle agglomeration in nanofluids

    NASA Astrophysics Data System (ADS)

    Krishna, K. Hari; Neti, S.; Oztekin, A.; Mohapatra, S.

    2015-03-01

    Agglomeration strongly influences the stability or shelf life of nanofluid. The present computational and experimental study investigates the rate of agglomeration quantitatively. Agglomeration in nanofluids is attributed to the net effect of various inter-particle interaction forces. For the nanofluid considered here, a net inter-particle force depends on the particle size, volume fraction, pH, and electrolyte concentration. A solution of the discretized and coupled population balance equations can yield particle sizes as a function of time. Nanofluid prepared here consists of alumina nanoparticles with the average particle size of 150 nm dispersed in de-ionized water. As the pH of the colloid was moved towards the isoelectric point of alumina nanofluids, the rate of increase of average particle size increased with time due to lower net positive charge on particles. The rate at which the average particle size is increased is predicted and measured for different electrolyte concentration and volume fraction. The higher rate of agglomeration is attributed to the decrease in the electrostatic double layer repulsion forces. The rate of agglomeration decreases due to increase in the size of nano-particle clusters thus approaching zero rate of agglomeration when all the clusters are nearly uniform in size. Predicted rates of agglomeration agree adequate enough with the measured values; validating the mathematical model and numerical approach is employed.

  4. Modeling of particle agglomeration in nanofluids

    SciTech Connect

    Krishna, K. Hari; Neti, S.; Oztekin, A.; Mohapatra, S.

    2015-03-07

    Agglomeration strongly influences the stability or shelf life of nanofluid. The present computational and experimental study investigates the rate of agglomeration quantitatively. Agglomeration in nanofluids is attributed to the net effect of various inter-particle interaction forces. For the nanofluid considered here, a net inter-particle force depends on the particle size, volume fraction, pH, and electrolyte concentration. A solution of the discretized and coupled population balance equations can yield particle sizes as a function of time. Nanofluid prepared here consists of alumina nanoparticles with the average particle size of 150 nm dispersed in de-ionized water. As the pH of the colloid was moved towards the isoelectric point of alumina nanofluids, the rate of increase of average particle size increased with time due to lower net positive charge on particles. The rate at which the average particle size is increased is predicted and measured for different electrolyte concentration and volume fraction. The higher rate of agglomeration is attributed to the decrease in the electrostatic double layer repulsion forces. The rate of agglomeration decreases due to increase in the size of nano-particle clusters thus approaching zero rate of agglomeration when all the clusters are nearly uniform in size. Predicted rates of agglomeration agree adequate enough with the measured values; validating the mathematical model and numerical approach is employed.

  5. Modeling of Particle Agglomeration in Nanofluids

    NASA Astrophysics Data System (ADS)

    Kanagala, Hari Krishna

    Nanofluids are colloidal dispersions of nano sized particles (<100nm in diameter) in dispersion mediums. They are of great interest in industrial applications as heat transfer fluids owing to their enhanced thermal conductivities. Stability of nanofluids is a major problem hindering their industrial application. Agglomeration and then sedimentation are some reasons, which drastically decrease the shelf life of these nanofluids. Current research addresses the agglomeration effect and how it can affect the shelf life of a nanofluid. The reasons for agglomeration in nanofluids are attributable to the interparticle interactions which are quantified by the various theories. By altering the governing properties like volume fraction, pH and electrolyte concentration different nanofluids with instant agglomeration, slow agglomeration and no agglomeration can be produced. A numerical model is created based on the discretized population balance equations which analyses the particle size distribution at different times. Agglomeration effects have been analyzed for alumina nanoparticles with average particle size of 150nm dispersed in de-ionized water. As the pH was moved towards the isoelectric point of alumina nanofluids, the particle size distribution became broader and moved to bigger sizes rapidly with time. Particle size distributions became broader and moved to bigger sizes more quickly with time with increase in the electrolyte concentration. The two effects together can be used to create different temporal trends in the particle size distributions. Faster agglomeration is attributed to the decrease in the electrostatic double layer repulsion forces which is due to decrease in the induced charge and the double layer thickness around the particle. Bigger particle clusters show lesser agglomeration due to reaching the equilibrium size. The procedures and processes described in this work can be used to generate more stable nanofluids.

  6. Method for producing ceramic particles and agglomerates

    DOEpatents

    Phillips, Jonathan; Gleiman, Seth S.; Chen, Chun-Ku

    2001-01-01

    A method for generating spherical and irregularly shaped dense particles of ceramic oxides having a controlled particle size and particle size distribution. An aerosol containing precursor particles of oxide ceramics is directed into a plasma. As the particles flow through the hot zone of the plasma, they melt, collide, and join to form larger particles. If these larger particles remain in the hot zone, they continue melting and acquire a spherical shape that is retained after they exit the hot zone, cool down, and solidify. If they exit the hot zone before melting completely, their irregular shape persists and agglomerates are produced. The size and size distribution of the dense product particles can be controlled by adjusting several parameters, the most important in the case of powder precursors appears to be the density of powder in the aerosol stream that enters the plasma hot zone. This suggests that particle collision rate is responsible for determining ultimate size of the resulting sphere or agglomerate. Other parameters, particularly the gas flow rates and the microwave power, are also adjusted to control the particle size distribution.

  7. Agglomeration rate and action forces between atomized particles of agglomerator and inhaled-particles from coal combustion.

    PubMed

    Wei, Feng; Zhang, Jun-ying; Zheng, Chu-guang

    2005-01-01

    In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the flue before precipitation devices of power station boiler in order to make inhaled-particles agglomerate into bigger particles, which can be easily removed but not change existing running conditions of boiler. According to this idea, a model is set up to study agglomeration rate and effect forces between fly ash inhaled-particles and atomized agglomerator particles. The developed agglomeration rate was expressed by relative particle number decreasing speed per unit volume. The result showed that viscosity force and flow resistance force give main influences on agglomeration effect of inhaled-particles, while springiness force and gravity have little effect on agglomeration effect of theirs. Factors influencing the agglomeration rate and effect forces are studied, including agglomerator concentration, agglomerator flux and agglomerator density, atomized-particles diameters and inhaled-particles diameter and so on. PMID:16295917

  8. Effect of particle agglomeration in nanotoxicology.

    PubMed

    Bruinink, Arie; Wang, Jing; Wick, Peter

    2015-05-01

    The emission of engineered nanoparticles (ENPs) into the environment in increasing quantity and variety raises a general concern regarding potential effects on human health. Compared with soluble substances, ENPs exhibit additional dimensions of complexity, that is, they exist not only in various sizes, shapes and chemical compositions but also in different degrees of agglomeration. The effect of the latter is the topic of this review in which we explore and discuss the role of agglomeration on toxicity, including the fate of nanomaterials after their release and the biological effects they may induce. In-depth investigations of the effect of ENP agglomeration on human health are still rare, but it may be stated that outside the body ENP agglomeration greatly reduces human exposure. After uptake, agglomeration of ENPs reduces translocation across primary barriers such as lungs, skin or the gastrointestinal tract, preventing exposure of "secondary" organs. In analogy, also cellular ENP uptake and intracellular distribution are affected by agglomeration. However, agglomeration may represent a risk factor if it occurs after translocation across the primary barriers, and ENPs are able to accumulate within the tissue and thus reduce clearance efficiency. PMID:25618546

  9. Modeling Agglomeration of Dust Particles in Plasma

    SciTech Connect

    Matthews, Lorin S.; Land, Victor; Ma Qianyu; Perry, Jonathan D.; Hyde, Truell W.

    2011-11-29

    The charge on an aggregate immersed in a plasma environment distributes itself over the aggregate's surface; this can be approximated theoretically by assuming a multipole distribution. The dipole-dipole (or higher order) charge interactions between fractal aggregates lead to rotations of the grains as they interact. Other properties of the dust grains also influence the agglomeration process, such as the monomer shape (spherical or ellipsoidal) or the presence of magnetic material. Finally, the plasma and grain properties also determine the morphology of the resultant aggregates. Porous and fluffy aggregates are more strongly coupled to the gas, leading to reduced collisional velocities, and greater collisional cross sections. These factors in turn can determine the growth rate of the aggregates and evolution of the dust cloud. This paper gives an overview of the numerical and experimental methods used to study dust agglomeration at CASPER and highlights some recent results.

  10. Agglomeration of soot particles in diffusion flames under microgravity

    SciTech Connect

    Ito, H.; Fujita, O.; Ito, K.

    1994-11-01

    Experiments have been conducted to investigate the behavior of soot particles in diffusion flames under microgravity conditions using a 490-m drop shaft (10-s microgravity duration) in Hokkaido, Japan. Flames from the combustion of paper sheets and butane jet diffusion flames are observed under microgravity. The oxygen concentration of the surroundings, the butane flow rate,and the burner diameter are varied as experimental parameters. The generated soot particles are sampled under microgravity and observed using scanning electron and transmission electron microscopes. The flames with a residual convection or forced convection are also observed to examine the influence of flow field on soot particle generation under microgravity. From these results, it is found that a number of large luminous spots appear in diffusion flames under microgravity. From the observation of TEM images, the luminous spots are the result of agglomerated soot particles and the growth of their diameters to a discernible level. The diameter of the agglomerated particles measure about 0.1 mm, 200 to 500 times as large as those generated under normal gravity. It is suggested that these large soot particles are generated in the limited areas where the conditions for the formation of these particles, such as gas velocity (residence time) and oxygen concentration, are satisfied.

  11. DETERMINATION OF STOKES SHAPE FACTOR FOR SINGLE PARTICLES AND AGGLOMERATES

    SciTech Connect

    Matyas, Josef; Schaible, Micah J.; Vienna, John D.

    2011-09-01

    The large octahedral crystals of spinel can precipitate from glass during the high-level waste vitrification process and potentially block the glass discharge riser of electrically heated ceramic melters. To help predict the settling behavior of spinel in the riser, the settling of single particles and agglomerates was studied in stagnant and transparent viscosity oils at room temperature with developed optical particle-dynamics-analyzer. Determined dimensions and terminal settling velocities of particles were used for calculation of their Stokes shape factors. Calculated shape factor for the glass beads was almost identical with the theoretical shape factor of 2/9 for a perfect sphere. The shape factor for single spinel crystal was about 7.6 % higher compare to the theoretically predicted value for octahedron. Stokes shape factor of irregularly shaped multi-particle agglomerates was lower than that of the glass beads and individual spinel crystals because of the higher surface drag caused by the larger surface area to volume ratio.

  12. Reducing adhesion and agglomeration within a cloud of combustible particles

    NASA Technical Reports Server (NTRS)

    Ross, Howard D.

    1988-01-01

    The study of combustible particle clouds inside flame tubes is of fundamental scientific interest as well as a practical concern. Only the suspended concentration is important to the combustion process, so that assurances must be provided that a minimum of particles adheres to the tube wall. This paper demonstrates experimentally the ability to minimize adhesion and agglomeration of acoustically-mixed lycopodium particles within a 5-cm diameter lexan flame tube. The area density of particles (ADP) adhering to the wall of bare lexan tubes was measured at greater than 100 particles/sq mm. The nature of adhesion was found to be clearly electrostatic, with the ADP level aggravated by increased mixing time, vigor, and the concentration of particles. Increases in the conductivity of the air and the tube wall did not affect ADP levels substantially. However, the observed adhesion was reduced to less than 10 p/sq mm when the air was ionized by use of an alpha emitter mounted on the inner walls of the flame tube.

  13. Simulation of acoustic agglomeration processes of poly-disperse solid particles

    SciTech Connect

    Changdong Sheng; Xianglin Shen

    2007-01-15

    This article presents the simulation of acoustic agglomeration of poly-disperse solid particles with the direct simulation Monte Carlo method. The modelled processes include the agglomeration due to the orthokinetic and hydrodynamic mechanisms, Brownian coagulation and wall deposition. The aggregates formed during the agglomeration process were characterised as mass fractal aggregates with an equivalent radius to estimate the average radius of the primary particles in individual aggregates. Acoustic agglomeration of fly ash with a lognormal size distribution and TiO{sub 2} particles with a bimodal size distribution was simulated and validated against the experimental data in the literature. It was found that the acoustic agglomeration process of solid particles could be represented with a modified version of Song's orthokinetic model and Koenig's hydrodynamic equation that account for the fractal-like morphology of the aggregates. The fractal dimensions of around 1.8 and 2.2 were obtained for the fly ash and TiO{sub 2} particles, respectively, consistent with the values reported for the aggregates in the literature. The poly-disperse nature of the primary particles is essential to the simulation; assuming mono-disperse primary particles leads to a significant underestimation of the agglomeration rate and the particle size growth particularly during the early stages of the acoustic agglomeration process. Particle deposition on the chamber walls also has some effect on acoustic agglomeration.

  14. A MODEL FOR FINE PARTICLE AGGLOMERATION IN CIRCULATING FLUIDIZED BED ABSORBERS

    EPA Science Inventory

    A model for fine particle agglomeration in circulating fluidized bed absorbers (CFBAS) has been developed. It can model the influence of different factors on agglomeration, such as the geometry of CFBAs, superficial gas velocity, initial particle size distribution, and type of ag...

  15. Numerical derivation of forces on particles and agglomerates in a resonant acoustic field

    NASA Astrophysics Data System (ADS)

    Knoop, Claas; Fritsching, Udo

    2013-10-01

    Particles and agglomerates are investigated in gaseous acoustic flow fields. Acoustic fields exert forces on solid objects, which can influence the shape of the exposed bodies, even to the point of breakage of the structures. Motivated by experimentally observed breakage of agglomerates in an acoustic levitator (f = 20 kHz), a numerical study is presented that derives the acoustic forces on a complex model agglomerate from the pressure and velocity fields of a resonant standing ultrasound wave, calculated by computational fluid dynamics (CFD). It is distinguished between the drag and lift/lateral forces on the overall agglomerate and on the different primary particles of the model.

  16. Development and scale-up of particle agglomeration processes for coal beneficiation

    NASA Astrophysics Data System (ADS)

    Shen, Meiyu

    The development of two modified agglomeration processes for coal beneficiation is presented separately in Parts I and II of this dissertation. Part I is based on research which was conducted to study the mechanism and characteristics of a gas-promoted oil agglomeration process. Part II is based on research which was carried out to develop a newer and more innovative method for agglomerating coal particles with microscopic gas bubbles in aqueous suspensions. In Part I, the development of a gas-promoted oil agglomeration process for cleaning coal was carried out with scale model mixing systems in which aqueous suspensions of ultrafine coal particles were treated with a liquid hydrocarbon and a small amount of air. The resulting agglomerates were recovered by screening. During batch agglomeration tests the progress of agglomeration was monitored by observing changes in agitator torque in the case of concentrated suspension. A key parameter turned out to be the minimum time te required to produce compact spherical agglomerates. Other important parameters included the projected area mean particle diameter of the agglomerates recovered at the end of a test as well as the ash content and yield of agglomerates. Batch agglomeration tests were conducted with geometrically similar mixing tanks which ranged in volume from 0.346 to 11.07 liters. It was shown that gas bubbles trigger the process of agglomeration and participate in a very complex mechanism involving the interaction of particles, oil droplets, and gas bubbles. The process takes place in stages involving dispersion of oil and gas, flocculation, coagulation, and agglomerate building. Numerous agglomeration tests were conducted with two kinds of coal in concentrated suspensions to determine the important characteristics of the process and to study the effects of the following operating parameters: i-octane concentration, air concentration, particle concentration, tank diameter, impeller diameter, and impeller speed

  17. Impact debris particles in Jupiter's stratosphere.

    PubMed

    West, R A; Karkoschka, E; Friedson, A J; Seymour, M; Baines, K H; Hammel, H B

    1995-03-01

    The aftermath of the impacts of periodic comet Shoemaker-Levy 9 on Jupiter was studied with the Wide Field Planetary Camera 2 on the Hubble Space Telescope. The impact debris particles may owe their dark brown color to organic material rich in sulfur and nitrogen. The total volume of aerosol 1 day after the last impact is equal to the volume of a sphere of radius 0.5 kilometer. In the optically thick core regions, the particle mean radius is between 0.15 and 0.3 micrometer, and the aerosol is spread over many scale heights, from approximately 1 millibar to 200 millibars of pressure or more. Particle coagulation can account for the evolution of particle radius and total optical depth during the month following the impacts. PMID:7871426

  18. Dynamic forces on agglomerated particles caused by high-intensity ultrasound.

    PubMed

    Knoop, Claas; Fritsching, Udo

    2014-03-01

    In this paper the acoustic forces on particles and agglomerates caused by high-intensity ultrasound in gaseous atmosphere are derived by means of computational fluid dynamics (CFD). Sound induced forces cause an oscillating stress scenario where the primary particles of an agglomerate are alternatingly pressed together and torn apart with the frequency of the applied wave. A comparison of the calculated acoustic forces with respect to the inter particle adhesion forces from Van-der-Waals and liquid bridge interactions reveals that the separation forces may reach the same order of magnitude for 80 μm sized SiO2-particles. Hence, with finite probability acoustically agitated gases may de-agglomerate/disperse solid agglomerate structures. This effect is confirmed by dispersion experiments in an acoustic particle levitation setup. PMID:24152872

  19. Influence of primary-particle density in the morphology of agglomerates.

    PubMed

    Camejo, M D; Espeso, D R; Bonilla, L L

    2014-07-01

    Agglomeration processes occur in many different realms of science, such as colloid and aerosol formation or formation of bacterial colonies. We study the influence of primary-particle density in agglomerate structures using diffusion-controlled Monte Carlo simulations with realistic space scales through different regimes (diffusion-limited aggregation and diffusion-limited colloid aggregation). The equivalence of Monte Carlo time steps to real time scales is given by Hirsch's hydrodynamical theory of Brownian motion. Agglomerate behavior at different time stages of the simulations suggests that three indices (the fractal exponent, the coordination number, and the eccentricity index) characterize agglomerate geometry. Using these indices, we have found that the initial density of primary particles greatly influences the final structure of the agglomerate, as observed in recent experimental works. PMID:25122302

  20. Influence of primary-particle density in the morphology of agglomerates

    NASA Astrophysics Data System (ADS)

    Camejo, M. D.; Espeso, D. R.; Bonilla, L. L.

    2014-07-01

    Agglomeration processes occur in many different realms of science, such as colloid and aerosol formation or formation of bacterial colonies. We study the influence of primary-particle density in agglomerate structures using diffusion-controlled Monte Carlo simulations with realistic space scales through different regimes (diffusion-limited aggregation and diffusion-limited colloid aggregation). The equivalence of Monte Carlo time steps to real time scales is given by Hirsch's hydrodynamical theory of Brownian motion. Agglomerate behavior at different time stages of the simulations suggests that three indices (the fractal exponent, the coordination number, and the eccentricity index) characterize agglomerate geometry. Using these indices, we have found that the initial density of primary particles greatly influences the final structure of the agglomerate, as observed in recent experimental works.

  1. Temperature-Switchable Agglomeration of Magnetic Particles Designed for Continuous Separation Processes in Biotechnology.

    PubMed

    Paulus, Anja S; Heinzler, Raphael; Ooi, Huey Wen; Franzreb, Matthias

    2015-07-01

    The purpose of this work was the synthesis and characterization of thermally switchable magnetic particles for use in biotechnological applications such as protein purification and enzymatic conversions. Reversible addition-fragmentation chain-transfer polymerization was employed to synthesize poly(N-isopropylacrylamide) brushes via a "graft-from" approach on the surface of magnetic microparticles. The resulting particles were characterized by infrared spectroscopy and thermogravimetric analysis and their temperature-dependent agglomeration behavior was assessed. The influence of several factors on particle agglomeration (pH, temperature, salt type, and particle concentration) was evaluated. The results showed that a low pH value (pH 3-4), a kosmotropic salt (ammonium sulfate), and a high particle concentration (4 g/L) resulted in improved agglomeration at elevated temperature (40 °C). Recycling of particles and reversibility of the temperature-switchable agglomeration were successfully demonstrated for ten heating-cooling cycles. Additionally, enhanced magnetic separation was observed for the modified particles. Ionic monomers were integrated into the polymer chain to create end-group functionalized particles as well as two- and three-block copolymer particles for protein binding. The adsorption of lactoferrin, bovine serum albumin, and lysozyme to these ion exchange particles was evaluated and showed a binding capacity of up to 135 mg/g. The dual-responsive particles combined magnetic and thermoresponsive properties for switchable agglomeration, easy separability, and efficient protein adsorption. PMID:26069936

  2. Direct numerical simulations of agglomeration of circular colloidal particles in two-dimensional shear flow

    NASA Astrophysics Data System (ADS)

    Choi, Young Joon; Djilali, Ned

    2016-01-01

    Colloidal agglomeration of nanoparticles in shear flow is investigated by solving the fluid-particle and particle-particle interactions in a 2D system. We use an extended finite element method in which the dynamics of the particles is solved in a fully coupled manner with the flow, allowing an accurate description of the fluid-particle interfaces without the need of boundary-fitted meshes or of empirical correlations to account for the hydrodynamic interactions between the particles. Adaptive local mesh refinement using a grid deformation method is incorporated with the fluid-structure interaction algorithm, and the particle-particle interaction at the microscopic level is modeled using the Lennard-Jones potential. Motivated by the process used in fabricating fuel cell catalysts from a colloidal ink, the model is applied to investigate agglomeration of colloidal particles under external shear flow in a sliding bi-periodic Lees-Edwards frame with varying shear rates and particle fraction ratios. Both external shear and particle fraction are found to have a crucial impact on the structure formation of colloidal particles in a suspension. Segregation intensity and graph theory are used to analyze the underlying agglomeration patterns and structures, and three agglomeration regimes are identified.

  3. A new stochastic approach for the simulation of agglomeration between colloidal particles.

    PubMed

    Henry, Christophe; Minier, Jean-Pierre; Pozorski, Jacek; Lefèvre, Grégory

    2013-11-12

    This paper presents a stochastic approach for the simulation of particle agglomeration, which is addressed as a two-step process: first, particles are transported by the flow toward each other (collision step) and, second, short-ranged particle-particle interactions lead either to the formation of an agglomerate or prevent it (adhesion step). Particle collisions are treated in the framework of Lagrangian approaches where the motions of a large number of particles are explicitly tracked. The key idea to detect collisions is to account for the whole continuous relative trajectory of particle pairs within each time step and not only the initial and final relative distances between two possible colliding partners at the beginning and at the end of the time steps. The present paper is thus the continuation of a previous work (Mohaupt M., Minier, J.-P., Tanière, A. A new approach for the detection of particle interactions for large-inertia and colloidal particles in a turbulent flow, Int. J. Multiphase Flow, 2011, 37, 746-755) and is devoted to an extension of the approach to the treatment of particle agglomeration. For that purpose, the attachment step is modeled using the DLVO theory (Derjaguin and Landau, Verwey and Overbeek) which describes particle-particle interactions as the sum of van der Waals and electrostatic forces. The attachment step is coupled with the collision step using a common energy balance approach, where particles are assumed to agglomerate only if their relative kinetic energy is high enough to overcome the maximum repulsive interaction energy between particles. Numerical results obtained with this model are shown to compare well with available experimental data on agglomeration. These promising results assert the applicability of the present modeling approach over a whole range of particle sizes (even nanoscopic) and solution conditions (both attractive and repulsive cases). PMID:24111685

  4. Method of producing non-agglomerating submicron size particles

    DOEpatents

    Bourne, Roy S.; Eichman, Clarence C.; Welbon, William W.

    1989-01-01

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in "metallic inks".

  5. Impact of agglomeration state of nano- and submicron sized gold particles on pulmonary inflammation

    PubMed Central

    2010-01-01

    Background Nanoparticle (NP) toxicity testing comes with many challenges. Characterization of the test substance is of crucial importance and in the case of NPs, agglomeration/aggregation state in physiological media needs to be considered. In this study, we have addressed the effect of agglomerated versus single particle suspensions of nano- and submicron sized gold on the inflammatory response in the lung. Rats were exposed to a single dose of 1.6 mg/kg body weight (bw) of spherical gold particles with geometric diameters of 50 nm or 250 nm diluted either by ultrapure water or by adding phosphate buffered saline (PBS). A single dose of 1.6 mg/kg bw DQ12 quartz was used as a positive control for pulmonary inflammation. Extensive characterization of the particle suspensions has been performed by determining the zetapotential, pH, gold concentration and particle size distribution. Primary particle size and particle purity has been verified using transmission electron microscopy (TEM) techniques. Pulmonary inflammation (total cell number, differential cell count and pro-inflammatory cytokines), cell damage (total protein and albumin) and cytotoxicity (alkaline phosphatase and lactate dehydrogenase) were determined in bronchoalveolar lavage fluid (BALF) and acute systemic effects in blood (total cell number, differential cell counts, fibrinogen and C-reactive protein) 3 and 24 hours post exposure. Uptake of gold particles in alveolar macrophages has been determined by TEM. Results Particles diluted in ultrapure water are well dispersed, while agglomerates are formed when diluting in PBS. The particle size of the 50 nm particles was confirmed, while the 250 nm particles appear to be 200 nm using tracking analysis and 210 nm using TEM. No major differences in pulmonary and systemic toxicity markers were observed after instillation of agglomerated versus single gold particles of different sizes. Both agglomerated as well as single nanoparticles were taken up by

  6. Particle Trajectories and Agglomeration/Accumulation in Branching Arteries subjected to Orbital Atherectomy

    PubMed Central

    Helgeson, Zach L; Jenkins, Jed S; Abraham, John P; Sparrow, Ephraim M

    2011-01-01

    Background: The transport of particles in surrogate and actual arterial geometries has been investigated synergistically by experimentation and numerical simulation. The motivating application for this work is orbital atherectomy which spawns a particle cloud in the process of debulking plaque from arterial walls. Methods: Paired simulations and experiments were performed to prove the capability of the simulation model to predict both fluid and particle motions in branched arterial geometries. The verified model was then employed to predict the pattern of fluid flow in an actual multi-branched arterial geometry, including the flowrates passing through each of the individual branches. These predictions are in very good agreement with experimental data. Focus was then shifted to the issues of particle agglomeration within the flowing fluid and particle accumulation on the vessel walls. Once again, a synergistic approach was used. Flow visualization was employed to track the particle motions and to identify possible particle agglomeration within the fluid. Results and Conclusions: Accumulation of particles on walls was identified by measuring size distributions of effluent and residue within the artery. Scanning Electron Microscopy (SEM) evaluation showed evidence of a size-based sorting as the particles passed through vessels. It was found that plaque-facsimile particles resisted particle-particle agglomeration. They also did not accumulate to the wall of the facsimile artery. In addition, simulations showed that if particle-wall accumulation were to occur, it would be limited to very small regions in the artery branches. PMID:21643425

  7. Cation effects during aggregation and agglomeration of gibbsite particles under synthetic Bayer crystallisation conditions

    NASA Astrophysics Data System (ADS)

    Prestidge, Clive A.; Ametov, Igor

    2000-02-01

    Rheological methods have been used to study the influence of the liquor cation (sodium versus potassium) on the time-dependent gibbsite particle interactions that occur during Bayer process crystallisation. The temperature, supersaturation and seeding levels investigated simulate those experienced in industrial crystallisers. Gibbsite agglomeration was shown to occur by reversible aggregation followed by irreversible cementation. These two sub-steps were individually characterised by careful choice of seed surface area and liquor supersaturation during batch crystallisation. At seed loading levels less than 10% w/w aggregates are rapidly cemented into agglomerates, this is more pronounced in sodium- than potassium-based liquors. These suspensions were Newtonian and the extent of agglomeration correlated with their viscosity. At seed loading levels greater than 20% w/w particle aggregation resulted in extensively time-dependent and non-Newtonian rheology. However, the aggregates did not undergo cementation into agglomerates and no irreversible size enlargement was evident. Yield stress development with time was used to probe the kinetics of aggregation and quantify the particle interaction behaviour. The rate and extent of the particle network formation is more pronounced in sodium rather than potassium-based liquors, supersaturation dependent, alkali concentration dependent, but only weakly temperature dependent. These findings are discussed with respect to the chemical and physical mechanisms of agglomeration in Bayer crystallisation and the role of cation.

  8. Saltation threshold reduction due to the electrostatic agglomeration of fine particles

    NASA Technical Reports Server (NTRS)

    Leach, Rodman N.; Greeley, Ronald

    1991-01-01

    Particles between 80 and 110 microns in diameter are the most easily moved by the wind. As the particle size decreases below 60 microns, they are increasingly more difficult to move by surface winds, and a number of experiments were performed in an attempt to reduce the required wind velocity. These include: (1) the bombardment of a bed of fine particles by particles near the optimum size, the larger particles kicking the fine particles into the windstream where they are entrained; and (2) the electrostatic agglomeration of fine particles into sizes more easily saltated. The results of these experiments are discussed.

  9. Combined deterministic-stochastic framework for modeling the agglomeration of colloidal particles.

    PubMed

    Mortuza, S M; Kariyawasam, Lahiru K; Banerjee, Soumik

    2015-07-01

    We present a multiscale model, based on molecular dynamics (MD) and kinetic Monte Carlo (kMC), to study the aggregation driven growth of colloidal particles. Coarse-grained molecular dynamics (CGMD) simulations are employed to detect key agglomeration events and calculate the corresponding rate constants. The kMC simulations employ these rate constants in a stochastic framework to track the growth of the agglomerates over longer time scales and length scales. One of the hallmarks of the model is a unique methodology to detect and characterize agglomeration events. The model accounts for individual cluster-scale effects such as change in size due to aggregation as well as local molecular-scale effects such as changes in the number of neighbors of each molecule in a colloidal cluster. Such definition of agglomeration events allows us to grow the cluster to sizes that are inaccessible to molecular simulations as well as track the shape of the growing cluster. A well-studied system, comprising fullerenes in NaCl electrolyte solution, was simulated to validate the model. Under the simulated conditions, the agglomeration process evolves from a diffusion limited cluster aggregation (DLCA) regime to percolating cluster in transition and finally to a gelation regime. Overall the data from the multiscale numerical model shows good agreement with existing theory of colloidal particle growth. Although in the present study we validated our model by specifically simulating fullerene agglomeration in electrolyte solution, the model is versatile and can be applied to a wide range of colloidal systems. PMID:26274304

  10. Boron Particles Agglomeration and Slag Formation During Combustion of Energetic Condensed Systems

    NASA Astrophysics Data System (ADS)

    Meerov, D.; Monogarov, K.; Bragin, A.; Frolov, Yu.; Nikiforova, Anna

    Boron is a promising component of energetic condensed systems due to its high gravimetric heat value, which is significantly higher than that one of aluminum. In the present work, two non-equilibrium processes, i.e., boron particles agglomeration and framework (slag) formation during combustion of high-energy compositions were investigated experimentally. The quench particle collection bomb technique was used to collect the condensed combustion products formed under nitrogen pressures of 0.1 - 4 MPa. The formation of a framework was visualized using high-speed video registration (1200 fps). Particle size, morphology, and surface structure of collected condensed products were evaluated using laser diffractometry and scanning electron microscopy. In the experiments, the weight of the collected condensed combustion products was about 30% of the initial sample weight, where 26% belonged to the products collected from the gas phase and 4% were remained in a highly-porous framework. The initial amorphous boron powder consisted of 1-micron particles, whereas agglomerated particles, which were collected from the gas phase, were 10 μm in diameter. The burning rate of compositions without binder was 4 times higher and the diameter of collected agglomerates was 10 times larger than those for compositions with binder.

  11. Hebbian learning in the agglomeration of conducting particles

    NASA Astrophysics Data System (ADS)

    Sperl, M.; Chang, A.; Weber, N.; Hübler, A.

    1999-03-01

    The Hebbian learning rule is a fundamental concept in the learning of a neuronal net, where a frequently used connection of two neurons is continually reinforced. We study the properties of self-assembling connections of conducting particles in a dielectric liquid, and find that the strength of the connection between different electrodes represents a memory for the history of the system. Optimal parameters and sequences of stimulation for effective training are determined. We discuss a future application of our results for the implementation of a nonvolatile neuronal network based on self-assembling nanowires on a semiconductor surface.

  12. Evolution of particle angularity in natural and laboratory debris flows

    NASA Astrophysics Data System (ADS)

    Mclaughlin, M. K.; Arabnia, O.; Sklar, L. S.

    2014-12-01

    The sizes of particles entrained in debris flows influence flow dynamics, affecting erosive power and runout distance. Particle size distributions evolve due to wear by abrasion and fracturing, and by gains or losses of sediment mass during transport. To tease apart these factors, we need a better understanding of the controls on rates and patterns of particle wear in debris flows. Here we focus on changes in particle angularity with travel distance, combining laboratory experiments with field study of a rocky debris flow at Inyo Creek, Sierra Nevada California. Angularity can indicate proximity to sediment source, assuming abrasion leads to progressive smoothing of particle surfaces. However, particle fracture can create fresh angular surfaces, confounding estimates of travel distance from angularity. This study is a component of an ongoing set of experiments using a 4 m diameter rotating drum to create near-prototype-scale debris flows. We load the drum with 1.7 Mg of highly angular granodiorite clasts, with median b-axis diameter of 100 mm. The 0.75 m deep, shearing mass flows at 1 m/s. After each 250 m travel distance, we measure mass and length of principal axes for every particle >19 mm, and sieve all smaller particles, to track evolution of the size distribution. We document the angularity of subsamples of selected particle sizes, using several techniques, including analysis of 2D photographs, 3D laser scans, and hand-placed equilibrium points. We use the same techniques in analyzing particles collected in the field study of the downstream evolution of rock clasts along a 1 km length of Inyo Creek. In this catchment, underlain by granodiorite, sediment transport is dominated by debris flows, which leave deposits on the bed and channel margins at slopes >20%. Preliminary laboratory results show rapid smoothing of large particle surfaces combined with creation of smaller angular particles by fracture. In contrast, downstream evolution of angularity in the

  13. Model for coal ash agglomeration based on two-particle dynamics

    SciTech Connect

    Moseley, J.L.; O'Brien, T.J.

    1986-01-01

    The agglomeration of coal and coal ash in fluidized-bed gasifiers (FBG's) is of great interest in coal conversion. However, only limited work has been done to develop analytical models in order to understand ash agglomeration in FBG's. This paper focuses on two-particle collision dynamics, which is then used to develop a criterion for the agglutination of the two particles. The main assumption of this mechanism is that the binding force can be modeled as ''piecewise'' conservative. This makes it possible to compute the maximum energy that can be dissipated by the system. Comparison of this quantity with the initial kinetic energy provides the agglutination criteria. A specific version of this model is obtained by making specific choices for the contact force and the binding force. An analytic formula for the critical velocity, the relative collision velocity below which agglutination takes place, is obtained for head-on collisions; a numerical technique is developed for collisions which are not head-on. A process change which increases the critical velocity increases the likelihood of agglutination of particles with random relative velocities. To examine the critical velocity as a function of temperature, the model requires correlations for the shear modulus and surface adhesiveness coefficient of the particles. Although these correlations are derived from limited experimental information, they lead to reasonable results and agreement with existing experimental data on agglomeration and defluidization. By considering the agglutination of particles of average size and temperature, a measure of the agglomeration tendency of a FBG can be obtained. Finally, the sensitivity of the model to system parameters is also investigated and an assessment of needed additional work is made. 35 refs., 12 figs.

  14. Acoustic agglomeration of fine particles based on a high intensity acoustical resonator

    NASA Astrophysics Data System (ADS)

    Zhao, Yun; Zeng, Xinwu; Tian, Zhangfu

    2015-10-01

    Acoustic agglomeration (AA) is considered to be a promising method for reducing the air pollution caused by fine aerosol particles. Removal efficiency and energy consuming are primary parameters and generally have a conflict with each other for the industry applications. It was proved that removal efficiency is increased with sound intensity and optimal frequency is presented for certain polydisperse aerosol. As a result, a high efficiency and low energy cost removal system was constructed using acoustical resonance. High intensity standing wave is generated by a tube system with abrupt section driven by four loudspeakers. Numerical model of the tube system was built base on the finite element method, and the resonance condition and SPL increase were confirmd. Extensive tests were carried out to investigate the acoustic field in the agglomeration chamber. Removal efficiency of fine particles was tested by the comparison of filter paper mass and particle size distribution at different operating conditions including sound pressure level (SPL), and frequency. The experimental study has demonstrated that agglomeration increases with sound pressure level. Sound pressure level in the agglomeration chamber is between 145 dB and 165 dB from 500 Hz to 2 kHz. The resonance frequency can be predicted with the quarter tube theory. Sound pressure level gain of more than 10 dB is gained at resonance frequency. With the help of high intensity sound waves, fine particles are reduced greatly, and the AA effect is enhanced at high SPL condition. The optimal frequency is 1.1kHz for aerosol generated by coal ash. In the resonace tube, higher resonance frequencies are not the integral multiplies of the first one. As a result, Strong nonlinearity is avoided by the dissonant characteristic and shock wave is not found in the testing results. The mechanism and testing system can be used effectively in industrial processes in the future.

  15. Quasi-two-dimensional complex plasma containing spherical particles and their binary agglomerates

    NASA Astrophysics Data System (ADS)

    Chaudhuri, M.; Semenov, I.; Nosenko, V.; Thomas, H. M.

    2016-05-01

    A unique type of quasi-two-dimensional complex plasma system was observed which consisted of monodisperse microspheres and their binary agglomerations (dimers). The particles and their dimers levitated in a plasma sheath at slightly different heights and formed two distinct sublayers. The system did not crystallize and may be characterized as a disordered solid. The dimers were identified based on their characteristic appearance in defocused images, i.e., rotating interference fringe patterns. The in-plane and interplane particle separations exhibit nonmonotonic dependence on the discharge pressure.

  16. Design of sustained release fine particles using two-step mechanical powder processing: particle shape modification of drug crystals and dry particle coating with polymer nanoparticle agglomerate.

    PubMed

    Kondo, Keita; Ito, Natsuki; Niwa, Toshiyuki; Danjo, Kazumi

    2013-09-10

    We attempted to prepare sustained release fine particles using a two-step mechanical powder processing method; particle-shape modification and dry particle coating. First, particle shape of bulk drug was modified by mechanical treatment to yield drug crystals suitable for the coating process. Drug crystals became more rounded with increasing rotation speed, which demonstrates that powerful mechanical stress yields spherical drug crystals with narrow size distribution. This process is the result of destruction, granulation and refinement of drug crystals. Second, the modified drug particles and polymer coating powder were mechanically treated to prepare composite particles. Polymer nanoparticle agglomerate obtained by drying poly(meth)acrylate aqueous dispersion was used as a coating powder. The porous nanoparticle agglomerate has superior coating performance, because it is completely deagglomerated under mechanical stress to form fine fragments that act as guest particles. As a result, spherical drug crystals treated with porous agglomerate were effectively coated by poly(meth)acrylate powder, showing sustained release after curing. From these findings, particle-shape modification of drug crystals and dry particle coating with nanoparticle agglomerate using a mechanical powder processor is expected as an innovative technique for preparing controlled-release coated particles having high drug content and size smaller than 100 μm. PMID:23796831

  17. Field observations of particle impacts by debris flows and debris floods on instrumented rock samples

    NASA Astrophysics Data System (ADS)

    McArdell, B. W.; Hsu, L.; Fritschi, B.; Dietrich, W. E.

    2011-12-01

    Bedrock incision and sediment entrainment by debris flows are important processes in torrent channels. As part of our effort to gain a better understanding of these processes, we installed instrumented rock samples in the bed of the Illgraben channel. Three rock samples, 0.4 m long (in the flow direction), 0.3 m wide, and 0.2 m thick, were installed in steel frames which were mounted on the upslope side of a concrete check dam, with the surface of the stones flush with the channel bed. Accelerometer sensors were installed on the bottom of one rock sample, with a range of up to 500 g (vertical) and 200 g (horizontal, parallel to the channel axis), where g is the acceleration due to gravity. Elastomer elements, typically used in the field as overload protection for load sensors, were placed between the rock samples and the steel frames. Data were sampled at 2 kHz and stored on a computer outside of the channel. The sensors provided data for 4 debris floods and part of one debris flow. For all of the events, the vertical acceleration data indicate a large background noise in the range of ±10 g, punctuated by very short duration impulses of up to several hundred g. The large accelerations are interpreted to represent hard impacts of cobbles or boulders in the flow with the rock tablet. Using a value of >20 g to define the occurrence of a large particle impact, it is possible to differentiate between debris floods (which have on the order of 0.1 impact per second) and the debris flow (on the order of 1 impact per second). The frequency of the sampling is too small to resolve details about the impacts, so it is not possible to precisely determine the maximum accelerations. However the peak recorded values are larger for debris flows, with values up to the measurement limit of the sensors, whereas for floods the maximum accelerations are typically less than 100 g. The results for the accelerometer which measures accelerations in the downstream direction generally mirror

  18. Optical scattering (TAOS) by tire debris particles: preliminary results

    NASA Astrophysics Data System (ADS)

    Crosta, Giovanni F.; Camatini, Marina C.; Zomer, Simeone; Holler, Stephen; Pan, Yongle; Bhaskara, Praveena; Muangchareon, Pongphisanu; Sung, Changmo; Cencetti, Simone; Regazzoni, Claudia

    2001-03-01

    Tire debris particles from low severity laboratory wear tests have been investigated by the TAOS optical scattering facility at Yale University. The incident wavelength is 532 nm. After the TAOS event some particle samples have been imaged by a scanning electron microscope and microanalyzed. The TAOS intensity patterns recorded within a solid angle in the backward sector have been processed by cluster analysis and compared with the patterns computed by a T-matrix code. Preliminary agreement has been found between TAOS data and the particle models (size, shape, refractive index). The purpose of the investigation is to obtain signatures of the material, based on its TAOS pattern.

  19. A micromanipulation particle tester for agglomeration contact mechanism studies in a controlled environment

    NASA Astrophysics Data System (ADS)

    Haider, C. I.; Althaus, T.; Niederreiter, G.; Hounslow, M. J.; Palzer, S.; Salman, A. D.

    2012-10-01

    Pressure agglomeration of powders is widely applied in various industries and an increasing interest lies in the identification and description of contact mechanisms between particles, which are responsible for the compaction product properties. In this paper, the design and development of a novel micromanipulation particle tester (MPT) is presented. This device makes it possible to measure the deformation kinetics and resulting adhesion of two individual particles in contact under load, which are strongly influenced by the applied process conditions. The MPT set-up is, therefore, designed to offer a unique control over the process conditions most relevant to the compaction of powders: external stress, dwell or holding time at constant deformation, compression velocity as well as relative humidity and temperature determining the physical state and mechanical characteristics of hygrosensitive amorphous particles. The latter are often part of powder formulations, e.g. in the food industry, and have been used for force and contact-zone development studies with the MPT. The experimental results on the microscale level will deliver valuable quantitative information for an improved tailoring of pressure agglomeration process conditions of bulk solids.

  20. Steric stabilization of nonaqueous silicon slips. I - Control of particle agglomeration and packing. II - Pressure casting of powder compacts

    NASA Technical Reports Server (NTRS)

    Kerkar, Awdhoot V.; Henderson, Robert J. M.; Feke, Donald L.

    1990-01-01

    The application of steric stabilization to control particle agglomeration and packing of silicon powder in benzene and trichloroethylene is reported. The results provide useful guidelines for controlling unfavorable particle-particle interactions during nonaqueous processing of silicon-based ceramic materials. The application of steric stabilization to the control and improvement of green processing of nonaqueous silicon slips in pressure consolidation is also demonstrated.

  1. Rheological and flow characteristics of nanofluids: Influence of electroviscous effects and particle agglomeration

    NASA Astrophysics Data System (ADS)

    Anoop, K. B.; Kabelac, S.; Sundararajan, T.; Das, Sarit K.

    2009-08-01

    Nanofluids have shown remarkable attraction in heat transfer community due to its reported enhanced thermal properties. One factor which can restrict nanofluids in heat transfer application is the increased viscosity value (compared to classical predictions). Particle aggregation occurring was the major reason for this observation. Even though majority of the aqueous nanofluids prepared in literature were stabilized electrostatically by adjusting the pH, studies on the effect of the electrical double layer thus created and its influence on viscosity increase has not been investigated for these nanofluids so far. Thus, in the present paper, rheological properties of alumina-water nanofluids, which are electrostatically stabilized, are measured and the increase in suspension viscosity due to presence of this electrical double layer causing additional electroviscous effects is brought out. Based on dynamic light scattering studies, particle agglomeration and its subsequent effect in increasing the viscosity of alumina-ethylene glycol nanofluid, where electroviscous effects are absent, are also considered. It is noted that the understanding of electroviscous effect is equally important as understanding the particle agglomeration effect and understanding both the effects is central to revealing the physics of nanofluid rheology. Further, hydrodynamic experiments are made, which show that nanofluids behaves almost like a homogeneous fluids under flow conditions, and by knowing their properties, such as viscosity and density, pressure drop can be predicted.

  2. THE PHYSICS OF PROTOPLANETESIMAL DUST AGGLOMERATES. VI. EROSION OF LARGE AGGREGATES AS A SOURCE OF MICROMETER-SIZED PARTICLES

    SciTech Connect

    Schraepler, Rainer; Blum, Juergen

    2011-06-20

    Observed protoplanetary disks consist of a large amount of micrometer-sized particles. Dullemond and Dominik pointed out for the first time the difficulty in explaining the strong mid-infrared excess of classical T Tauri stars without any dust-retention mechanisms. Because high relative velocities in between micrometer-sized and macroscopic particles exist in protoplanetary disks, we present experimental results on the erosion of macroscopic agglomerates consisting of micrometer-sized spherical particles via the impact of micrometer-sized particles. We find that after an initial phase, in which an impacting particle erodes up to 10 particles of an agglomerate, the impacting particles compress the agglomerate's surface, which partly passivates the agglomerates against erosion. Due to this effect, the erosion halts for impact velocities up to {approx}30 m s{sup -1} within our error bars. For higher velocities, the erosion is reduced by an order of magnitude. This outcome is explained and confirmed by a numerical model. In a next step, we build an analytical disk model and implement the experimentally found erosive effect. The model shows that erosion is a strong source of micrometer-sized particles in a protoplanetary disk. Finally, we use the stationary solution of this model to explain the amount of micrometer-sized particles in the observational infrared data of Furlan et al.

  3. The effect of particle agglomeration on the formation of a surface-connected compartment induced by hydroxyapatite nanoparticles in human monocyte-derived macrophages☆

    PubMed Central

    Müller, Karin H.; Motskin, Michael; Philpott, Alistair J.; Routh, Alexander F.; Shanahan, Catherine M.; Duer, Melinda J.; Skepper, Jeremy N.

    2014-01-01

    Agglomeration dramatically affects many aspects of nanoparticle–cell interactions. Here we show that hydroxyapatite nanoparticles formed large agglomerates in biological medium resulting in extensive particle uptake and dose-dependent cytotoxicity in human macrophages. Particle citration and/or the addition of the dispersant Darvan 7 dramatically reduced mean agglomerate sizes, the amount of particle uptake and concomitantly cytotoxicity. More surprisingly, agglomeration governed the mode of particle uptake. Agglomerates were sequestered within an extensive, interconnected membrane labyrinth open to the extracellular space. In spite of not being truly intracellular, imaging studies suggest particle degradation occurred within this surface-connected compartment (SCC). Agglomerate dispersion prevented the SCC from forming, but did not completely inhibit nanoparticle uptake by other mechanisms. The results of this study could be relevant to understanding particle–cell interactions during developmental mineral deposition, in ectopic calcification in disease, and during application of hydroxyapatite nanoparticle vectors in biomedicine. PMID:24183166

  4. IMPACT OF PARTICLE AGGLOMERATION ON ACCUMULATION RATES IN THE GLASS DISCHARGE RISER OF HLW MELTER

    SciTech Connect

    Matyas, Josef; Jansik, Danielle P.; Owen, Antionette T.; Rodriguez, Carmen P.; Lang, Jesse B.; Kruger, Albert A.

    2013-08-05

    The major factor limiting waste loading in continuous high-level radioactive waste (HLW) melters is an accumulation of particles in the glass discharge riser during a frequent and periodic idling of more than 20 days. An excessive accumulation can produce robust layers a few centimeters thick, which may clog the riser, preventing molten glass from being poured into canisters. Since the accumulation rate is driven by the size of particles we investigated with X-ray microtomography, scanning electron microscopy, and image analysis the impact of spinel forming components, noble metals, and alumina on the size, concentration, and spatial distribution of particles, and on the accumulation rate. Increased concentrations of Fe and Ni in the baseline glass resulted in the formation of large agglomerates that grew over the time to an average size of ~185±155 µm, and produced >3 mm thick layer after 120 h at 850 °C. The noble metals decreased the particle size, and therefore significantly slowed down the accumulation rate. Addition of alumina resulted in the formation of a network of spinel dendrites which prevented accumulation of particles into compact layers.

  5. Impact Of Particle Agglomeration On Accumulation Rates In The Glass Discharge Riser Of HLW Melter

    SciTech Connect

    Kruger, A. A.; Rodriguez, C. A.; Matyas, J.; Owen, A. T.; Jansik, D. P.; Lang, J. B.

    2012-11-12

    The major factor limiting waste loading in continuous high-level radioactive waste (HLW) melters is an accumulation of particles in the glass discharge riser during a frequent and periodic idling of more than 20 days. An excessive accumulation can produce robust layers a few centimeters thick, which may clog the riser, preventing molten glass from being poured into canisters. Since the accumulation rate is driven by the size of particles we investigated with x-ray microtomography, scanning electron microscopy, and image analysis the impact of spinel forming components, noble metals, and alumina on the size, concentration, and spatial distribution of particles, and on the accumulation rate. Increased concentrations of Fe and Ni in the baseline glass resulted in the formation of large agglomerates that grew over the time to an average size of ~185+-155 {mu}m, and produced >3 mm thick layer after 120 h at 850 deg C. The noble metals decreased the particle size, and therefore significantly slowed down the accumulation rate. Addition of alumina resulted in the formation of a network of spinel dendrites which prevented accumulation of particles into compact layers.

  6. Composite propellant aluminum agglomeration reduction using tailored Al/PTFE particles

    NASA Astrophysics Data System (ADS)

    Sippel, Travis R.

    can be ignited via optical flash. Propellant aluminum agglomeration is assessed through replacement of reference aluminum powders (spherical, flake, or nanoscale) with Al/PTFE (90/10 or 70/30 wt.%) particles. The effects on burning rate, pressure dependence, and aluminum ignition, combustion, and agglomeration are quantified. Microscopic imaging shows tailored particles promptly ignite at the burning surface and appear to breakup into smaller particles. Replacement of spherical aluminum with Al/PTFE 70/30 wt.% also increases the pressure exponent from 0.36 to 0.58, which results in a 50% increase in propellant burning rate at 13.8 MPa. Combustion products were quench collected using a liquid-free technique at 2.1 and 6.9 MPa. Sizing of products indicates that composite particles result in nominally 25 μm coarse products, which are smaller than the original, average particle size and are also 66% smaller in diameter (96% by volume) than the 76 μm products collected from reference spherical aluminized propellant. Smaller diameter condensed phase products and more gaseous products will likely decrease two-phase flow loss and reduce slag accumulation in solid rocket motors.

  7. Are the stratospheric dust particles meteor ablation debris or interplanetary dust?

    NASA Technical Reports Server (NTRS)

    Blanchard, M. B.; Kyte, F. T.

    1978-01-01

    Natural and laboratory created fusion crusts and debris from artificial meteor samples were used to develop criteria for recognizing meteor ablation debris in a collection of 5 to 50 micron particles from the stratosphere. These laboratory studies indicate that meteor ablation debris from nickel-iron meteoroids produce spherules containing taenite, wuestite, magnetite, and hematite. These same studies also indicate that ablation debris from chondritic meteoroids produce spheres and fragmentary debris. The spheres may be either silicate rich, containing zoned olivine, magnetite, and glass, or sulfide rich, containing iron oxides (e.g., magnetite, wuestite) and iron sulfides (e.g., pyrrhotite, pentlandite). The fragmentary debris may be either fine-grained aggregates of olivine, magnetite, pyroxene, and occasionally pyrrhotite (derived from the meteorite matrix) or individual olivine and pyroxene grains (derived from meteorite inclusions).

  8. Theoretical model for surface diffusion driven Ni-particle agglomeration in anode of solid oxide fuel cell

    NASA Astrophysics Data System (ADS)

    Gao, Sheng; Li, Jiayu; Lin, Zijing

    2014-06-01

    The agglomeration of Ni particles in nickel-yttria stabilized zirconia (YSZ) anode is an important degradation mechanism for the solid oxide fuel cell and is widely believed to be driven by surface diffusion. This work aims to develop a quantitative model to describe the agglomeration kinetics. The model treats the anode as a system of random packing Ni and YSZ particles. Surface diffusion occurs between the connected Ni particles of different sizes characterized by two representative radii, but is influenced by the YSZ network. The Fick's law for diffusion, the Gibbs-Thomson relation for vacancy concentration and the coordination number theory for percolating Ni network are employed in the mathematical derivation. The growth kinetics is expressed as an analytical function consisting of two model parameters, one for the Ni-particle size distribution and the other for the influence of the YSZ backbone. The model is in excellent agreement with the available experiments. The influence of the YSZ backbone is further considered to obtain a model with just one fitting parameter. The one-parameter model is also in good agreement with the experiments and the fundamental physics for the Ni-particle growth is therefore believed to be well characterized.

  9. Instrumentation for near-Earth measurement of orbital debris and cosmic dust particles

    NASA Technical Reports Server (NTRS)

    Tuzzolino, Anthony J.

    1992-01-01

    Dust instrumentation based on polyvinylidene fluoride (PVDF) dust sensor arrays is described which will measure the masses, fluxes, velocities, and trajectories of orbital debris particles and natural micrometeoroids. Orbital debris particles are distinguished from natural particles (cosmic dust) by means of the velocity/trajectory information. The instrumentation will measure particle trajectory with a mean error of approximately 7 degrees (for isotropic flux) and is designed for measurements over the particle diameter range of approximately 2 to 200 micro-m. For future missions having Earth-return capabilities, arrays of capture cell devices positioned behind the PVDF trajectory system would provide for Earth-based chemical and isotopic analysis of captured dust.

  10. The surface properties of nanoparticles determine the agglomeration state and the size of the particles under physiological conditions

    PubMed Central

    Galla, Hans-Joachim; Kirkpatrick, C James; Stauber, Roland H

    2014-01-01

    Summary Due to the recent widespread application of nanomaterials to biological systems, a careful consideration of their physiological impact is required. This demands an understanding of the complex processes at the bio–nano interface. Therefore, a comprehensive and accurate characterization of the material under physiological conditions is crucial to correlate the observed biological impact with defined colloidal properties. As promising candidates for biomedical applications, two SiO2-based nanomaterial systems were chosen for extensive size characterization to investigate the agglomeration behavior under physiological conditions. To combine the benefits of different characterization techniques and to compensate for their respective drawbacks, transmission electron microscopy, dynamic light scattering and asymmetric flow field-flow fractionation were applied. The investigated particle systems were (i) negatively charged silica particles and (ii) poly(organosiloxane) particles offering variable surface modification opportunities (positively charged, polymer coated). It is shown that the surface properties primarily determine the agglomeration state of the particles and therefore their effective size, especially under physiological conditions. Thus, the biological identity of a nanomaterial is clearly influenced by differentiating surface properties. PMID:25383289

  11. Agglomerates of ultrafine particles of elemental carbon and TiO2 induce generation of lipid mediators in alveolar macrophages.

    PubMed Central

    Beck-Speier, I; Dayal, N; Karg, E; Maier, K L; Roth, C; Ziesenis, A; Heyder, J

    2001-01-01

    Agglomerates of ultrafine particles (AUFPs) may cause adverse health effects because of their large surface area. To evaluate physiologic responses of immune cells, we studied whether agglomerates of 77-nm elemental carbon [(EC); specific surface area 750 m2/g] and 21 nm titanium dioxide (TiO(2) particles (specific surface area 50 m(2)/g) affect the release of lipid mediators by alveolar macrophages (AMs). After 60-min incubation with 1 microg/mL AUFP-EC (corresponding to 7.5 cm(2) particle surface area), canine AMs (1 x 10(6) cells/mL) released arachidonic acid (AA) and the cyclooxygenase (COX) products prostaglandin E(2) (PGE(2), thromboxane B(2), and 12-hydroxyheptadecatrienoic acid but not 5-lipoxygenase (5-LO) products. AUFP-TiO(2) with a 10-fold higher mass (10 microg/mL) than AUFP-EC, but a similar particle surface area (5 cm(2) also induced AMs to release AA and COX products. Agglomerates of 250 nm TiO(2) particles (specific surface area 6.5 m(2)/g) at 100 microg/mL mass concentration (particle surface area 6.5 cm(2) showed the same response. Interestingly, 75 cm(2)/mL surface area of AUFP-EC and 16 cm(2)/mL surface area of AUFP-TiO(2) additionally induced the release of the 5-LO products leukotriene B(4) and 5-hydroxyeicosatetraenoic acid. Respiratory burst activity of stimulated canine neutrophils was partially suppressed by supernatants of AMs treated with various mass concentrations of the three types of particles. Inhibition of neutrophil activity was abolished by supernatants of AMs treated with COX inhibitors prior to AUFP-incubation. This indicates that anti-inflammatory properties of PGE(2) dominate the overall response of lipid mediators released by AUFP-affected AMs. In conclusion, our data indicate that surface area rather than mass concentration determines the effect of AUFPs, and that activation of phospholipase A(subscript)2(/subscript) and COX pathway occurs at a lower particle surface area than that of 5-LO-pathway. We hypothesize a

  12. Synthesis of crystalline and amorphous, particle-agglomerated 3-D nanostructures of Al and Si oxides by femtosecond laser and the prediction of these particle sizes

    PubMed Central

    2012-01-01

    We report a single step technique of synthesizing particle-agglomerated, amorphous 3-D nanostructures of Al and Si oxides on powder-fused aluminosilicate ceramic plates and a simple novel method of wafer-foil ablation to fabricate crystalline nanostructures of Al and Si oxides at ambient conditions. We also propose a particle size prediction mechanism to regulate the size of vapor-condensed agglomerated nanoparticles in these structures. Size characterization studies performed on the agglomerated nanoparticles of fabricated 3-D structures showed that the size distributions vary with the fluence-to-threshold ratio. The variation in laser parameters leads to varying plume temperature, pressure, amount of supersaturation, nucleation rate, and the growth rate of particles in the plume. The novel wafer-foil ablation technique could promote the possibilities of fabricating oxide nanostructures with varying Al/Si ratio, and the crystallinity of these structures enhances possible applications. The fabricated nanostructures of Al and Si oxides could have great potentials to be used in the fabrication of low power-consuming complementary metal-oxide-semiconductor circuits and in Mn catalysts to enhance the efficiency of oxidation on ethylbenzene to acetophenone in the super-critical carbon dioxide. PMID:23140103

  13. Agglomeration of Dust

    SciTech Connect

    Annaratone, B. M.; Arnas, C.; Elskens, Y.

    2008-09-07

    The agglomeration of the matter in plasma, from the atomic level up to millimetre size particles, is here considered. In general we identify a continuous growth, due to deposition, and two agglomeration steps, the first at the level of tens of nanometres and the second above the micron. The agglomeration of nano-particles is attributed to electrostatic forces in presence of charge polarity fluctuations. Here we present a model based on discrete currents. With increasing grain size the positive charge permanence decreases, tending to zero. This effect is only important in the range of nanometre for dust of highly dispersed size. When the inter-particle distance is of the order of the screening length another agglomeration mechanism dominates. It is based on attractive forces, shadow forces or dipole-dipole interaction, overcoming the electrostatic repulsion. In bright plasma radiation pressure also plays a role.

  14. Particle size reduction in debris flows: Laboratory experiments compared with field data from Inyo Creek, California

    NASA Astrophysics Data System (ADS)

    Arabnia, O.; Sklar, L. S.; Mclaughlin, M. K.

    2014-12-01

    Rock particles in debris flows are reduced in size through abrasion and fracture. Wear of coarse sediments results in production of finer particles, which alter the bulk material rheology and influence flow dynamics and runout distance. Particle wear also affects the size distribution of coarse particles, transforming the initial sediment size distribution produced on hillslopes into that delivered to the fluvial channel network. A better understanding of the controls on particle wear in debris flows would aid in the inferring flow conditions from debris flow deposits, in estimating the initial size of sediments entrained in the flow, and in modeling debris flow dynamics and mapping hazards. The rate of particle size reduction with distance traveled should depend on the intensity of particle interactions with other particles and the flow boundary, and on rock resistance to wear. We seek a geomorphic transport law to predict rate of particle wear with debris flow travel distance as a function of particle size distribution, flow depth, channel slope, fluid composition and rock strength. Here we use four rotating drums to create laboratory debris flows across a range of scales. Drum diameters range from 0.2 to 4.0 m, with the largest drum able to accommodate up to 2 Mg of material, including boulders. Each drum has vanes along the boundary to prevent sliding. Initial experiments use angular clasts of durable granodiorite; later experiments will use less resistant rock types. Shear rate is varied by changing drum rotational velocity. We begin experiments with well-sorted coarse particle size distributions, which are allowed to evolve through particle wear. The fluid is initially clear water, which rapidly acquires fine-grained wear products. After each travel increment all coarse particles (mass > 0.4 g) are weighed individually. We quantify particle wear rates using statistics of size and mass distributions, and by fitting various comminution functions to the data

  15. Debris flow impact on mitigation barriers: a new method for particle-fluid-structure interactions

    NASA Astrophysics Data System (ADS)

    Marchelli, Maddalena; Pirulli, Marina; Pudasaini, Shiva P.

    2016-04-01

    Channelized debris-flows are a type of mass movements that involve water-charged, predominantly coarse-grained inorganic and organic material flowing rapidly down steep confined pre-existing channels (Van Dine, 1985). Due to their rapid movements and destructive power, structural mitigation measures have become an integral part of counter measures against these phenomena, to mitigate and prevent damages resulting from debris-flow impact on urbanized areas. In particular, debris barriers and storage basins, with some form of debris-straining structures incorporated into the barrier constructed across the path of a debris-flow, have a dual role to play: (1) to stimulate deposition by presenting a physical obstruction against flow, and (2) to guarantee that during normal conditions stream water and bedload can pass through the structure; while, during and after an extreme event, the water that is in the flow and some of the fine-grained sediment can escape. A new method to investigate the dynamic interactions between the flowing mass and the debris barrier is presented, with particular emphasis on the effect of the barrier in controlling the water and sediment content of the escaping mass. This aspect is achieved by implementing a new mechanical model into an enhanced two-phase dynamical mass flow model (Pudasaini, 2012), in which solid particles mixture and viscous fluid are taken into account. The complex mechanical model is defined as a function of the energy lost during impact, the physical and geometrical properties of the debris barrier, separate but strongly interacting dynamics of boulder and fluid flows during the impact, particle concentration distribution, and the slope characteristics. The particle-filtering-process results in a large variation in the rheological properties of the fluid-dominated escaping mass, including the substantial reduction in the bulk density, and the inertial forces of the debris-flows. Consequently, the destructive power and run

  16. Control of Phase Transformation and Growth of Primary Particle in Photocatalytic Coating Sprayed Using Agglomerated Anatase TiO2 Nano Particles

    NASA Astrophysics Data System (ADS)

    Yasuoka, Junichi; Ohmori, Akira

    The phase transformation of anatase to rutile and the growth of nano primary particle in agglomerated TiO2 powder in heat treatment and HOVF spraying processes were investigated systematically. The 200nm, 30nm and 7nm primary particles were agglomerated by spray dry method for the feedstock powders of P200, P20 and P7, respectively. From the heat treatment results of feedstock powders, it was found that the phase transformation temperature of P7 was 100K and 150K lower than that of P30 and P200, respectively. The growth of primary particles of P7 and P30 happened earlier than their phase transformation, and increased drastically with increasing the heat treat temperature. Under various fuel pressure HVOF conditions, the anatase phase content was between 86% and 5% for sprayed P7 coating, whereas it was higher than 50% for P30 coating. The particle sizes of P7 and P30 grew during spraying processes. The anatase content of collected particles was lower than that of HVOF sprayed coatings in all conditions if phase transformation happened. Although the particle size had not significant change for P200, it grew obviously for P7 and P30. It was considered that the phase transformation and growth of primary particles were frozen for the rapid cooling effect due to the low temperature substrate. Therefore, it was concluded that the coating with high anatase ratio (approximately 100%) and primary particle size of single nano might be developed using the substrate with high thermal conductivity and large heat capacity.

  17. An adaptive extended finite element method for the analysis of agglomeration of colloidal particles in a flowing fluid

    SciTech Connect

    Choi, Young Joon; Jorshari, Razzi Movassaghi; Djilali, Ned

    2015-03-10

    Direct numerical simulations of the flow-nanoparticle interaction in a colloidal suspension are presented using an extended finite element method (XFEM) in which the dynamics of the nanoparticles is solved in a fully-coupled manner with the flow. The method is capable of accurately describing solid-fluid interfaces without the need of boundary-fitted meshes to investigate the dynamics of particles in complex flows. In order to accurately compute the high interparticle shear stresses and pressures while minimizing computing costs, an adaptive meshing technique is incorporated with the fluid-structure interaction algorithm. The particle-particle interaction at the microscopic level is modeled using the Lennard-Jones (LJ) potential and the corresponding potential parameters are determined by a scaling procedure. The study is relevant to the preparation of inks used in the fabrication of catalyst layers for fuel cells. In this paper, we are particularly interested in investigating agglomeration of the nanoparticles under external shear flow in a sliding bi-periodic Lees-Edwards frame. The results indicate that the external shear has a crucial impact on the structure formation of colloidal particles in a suspension.

  18. From Agglomerates of Spheres to Irregularly Shaped Particles: Determination of Dynamic Shape Factors from Measurements of Mobility and Vacuum Aerodynamic Diameters

    SciTech Connect

    Zelenyuk, Alla; Cai, Yong; Imre, Dan G.

    2006-03-01

    With the advert of aerosol instrumentation it has become possible to simultaneously measure individual particle mobility and vacuum aerodynamic diameters. For spherical particles these two diameters yield individual particle density. In contrast, assigning a physical meaning to the mobility or aerodynamic diameter of aspherical particles is not straightforward. This paper presents an experimental exploration of the effect of particle shape on the relationship between mobility and vacuum aerodynamic diameters. We make measurements on systems of three types: 1) Agglomerates of spheres, for which the density and the volume are known; 2) Ammonium sulfate, sodium chloride, succinic acid and lauric acid irregularly shaped particles of known density; and 3) Internally mixed particles, containing organics and ammonium sulfate, of unknown density and shape. For agglomerates of spheres we observed alignment effects in the DMA and report the first measurements of the dynamic shape factors (DSFs) in free molecular regime. We present here the first experimental determination of the DSF of ammonium sulfate particles. We find for ammonium sulfate particles a DSF that increases from 1.03 to 1.07 as particle mobility diameter increases from 160 nm to 500 nm. Three types of NaC1 particles were generated and characterized: nearly spherical particles with DSF of ~1.02; cubic with DSF that increases from 1.065 to 1.17 as particle mobility diameter increases from 200 nm to 900 nm; and compact agglomerates with DSF 1.3-1.4. Organic particles were found very nearly spherical. The data suggest that particles composed of binary mixtures of ammonium sulfate and succinic acid have lower dynamic shape factors than pure ammonium sulfate particles. However, for internally mixed ammonium sulfate and lauric acid particles we cannot distinguish between nearly spherical particles with low density and particles with DSF of 1.17.

  19. Modeling the oblique hypervelocity impact of orbital debris particles on spacecraft structures using elementary shock physics

    NASA Astrophysics Data System (ADS)

    Ebrahim, Ahmed Roushdy

    1998-11-01

    During their missions in space, spacecraft are subjected to high velocity impacts by orbital debris particles. Such impacts are expected to occur at non-normal angles of incidence and can cause severe damage to the spacecraft as well as its internal and external flight- critical systems. In order to ensure crew safety as well as the proper function of internal and external spacecraft systems, the characteristics of the debris clouds generated from orbital debris impacts must be determined. The effects of these debris clouds can then be considered in the design of spacecraft protective systems. In this dissertation, a new first principles- based analytical model is developed for the characterization of the penetration and ricochet debris clouds created by an oblique hypervelocity impact of a spherical projectile on a thin bumper plate. This model employs normal and oblique shock wave theories to characterize the penetration and ricochet processes. The model formulation consists of two mechanisms. The first predicts the leading edge velocities and trajectories of centers of mass of the normal and in-line debris clouds created in an oblique hypervelocity impact of a spherical projectile on a thin plate. The second predicts the leading edge velocity and trajectory of center of mass of ricochet debris cloud. In each of these two mechanisms, a new functional form of a reflected Hugoniot is developed to approximate the release of the bumper material. It was found that, unlike normal impact where there is only one reflected Hugoniot, the release of the bumper material in case of an oblique impact is approximated by a set of reflected Hugoniots that depends upon the impact obliquity angle. The methodology for characterizing the debris clouds created in an oblique hypervelocity impact uses the conservation equations that, governing the impact event, calculates the debris clouds' leading edge velocities and trajectories of debris cloud centers-of- mass using an elementary

  20. Particle Hydrodynamics with Material Strength for Multi-Layer Orbital Debris Shield Design

    NASA Technical Reports Server (NTRS)

    Fahrenthold, Eric P.

    1999-01-01

    Three dimensional simulation of oblique hypervelocity impact on orbital debris shielding places extreme demands on computer resources. Research to date has shown that particle models provide the most accurate and efficient means for computer simulation of shield design problems. In order to employ a particle based modeling approach to the wall plate impact portion of the shield design problem, it is essential that particle codes be augmented to represent strength effects. This report describes augmentation of a Lagrangian particle hydrodynamics code developed by the principal investigator, to include strength effects, allowing for the entire shield impact problem to be represented using a single computer code.

  1. Biological Responses of Human Mesenchymal Stem Cells to Titanium Wear Debris Particles

    PubMed Central

    Haleem-Smith, Hana; Argintar, Evan; Bush, Curtis; Hampton, Daniel; Postma, William F.; Chen, Faye H.; Rimington, Todd; Lamb, Joshua; Tuan, Rocky S.

    2011-01-01

    Wear debris-induced osteolysis is a major cause of orthopaedic implant aseptic loosening, and various cell types, including macrophages, monocytes, osteoblasts, and osteoclasts, are involved. We recently showed that mesenchymal stem/osteoprogenitor cells (MSCs) are another target, and that endocytosis of titanium (Ti) particles causes reduced MSC proliferation and osteogenic differentiation. Here we investigated the mechanistic aspects of the endocytosis-mediated responses of MSCs to Ti particulates. Dose-dependent effects were observed on cell viability, with doses >300 Ti particles/cell resulting in drastic cell death. To maintain cell viability and analyze particle-induced effects, doses <300 particles/cell were used. Increased production of IL- 8, but not IL-6, was observed in treated MSCs, while levels of TGF-β, IL-1β, and TNF-α were undetectable in treated or control cells, suggesting MSCs as a likely major producer of IL-8 in the periprosthetic zone. Disruptions in cytoskeletal and adherens junction organization were also observed in Ti particles-treated MSCs. However, neither IL-8 and IL-6 treatment nor conditioned medium from Ti particle-treated MSCs failed to affect MSC osteogenic differentiation. Among other Ti particle-induced cytokines, only GM-CSF appeared to mimic the effects of reduced cell viability and osteogenesis. Taken together, these results strongly suggest that MSCs play both responder and initiator roles in mediating the osteolytic effects of the presence of wear debris particles in periprosthetic zones. PMID:22083964

  2. Size of metallic and polyethylene debris particles in failed cemented total hip replacements

    NASA Technical Reports Server (NTRS)

    Lee, J. M.; Salvati, E. A.; Betts, F.; DiCarlo, E. F.; Doty, S. B.; Bullough, P. G.

    1992-01-01

    Reports of differing failure rates of total hip prostheses made of various metals prompted us to measure the size of metallic and polyethylene particulate debris around failed cemented arthroplasties. We used an isolation method, in which metallic debris was extracted from the tissues, and a non-isolation method of routine preparation for light and electron microscopy. Specimens were taken from 30 cases in which the femoral component was of titanium alloy (10), cobalt-chrome alloy (10), or stainless steel (10). The mean size of metallic particles with the isolation method was 0.8 to 1.0 microns by 1.5 to 1.8 microns. The non-isolation method gave a significantly smaller mean size of 0.3 to 0.4 microns by 0.6 to 0.7 microns. For each technique the particle sizes of the three metals were similar. The mean size of polyethylene particles was 2 to 4 microns by 8 to 13 microns. They were larger in tissue retrieved from failed titanium-alloy implants than from cobalt-chrome and stainless-steel implants. Our results suggest that factors other than the size of the metal particles, such as the constituents of the alloy, and the amount and speed of generation of debris, may be more important in the failure of hip replacements.

  3. Analysis of particle-particle interactions in fluidized catalytic cracking units: Effects of collisions, agglomeration, and vaporization

    SciTech Connect

    Kruis, F.E.; Terguer, V.; Lede, J.

    1996-12-31

    A theoretical background is developed for the understanding of the role of particulate interactions in three-phase reactors resulting from turbulent motion, with special application to the Fluid Catalytic Cracking unit. The characteristic times between two collisions in a mixture of catalyst particles and liquid droplets in a gas, the strength of aggregates and efficiency of particle collisions are discussed. A new model has been developed to describe the interaction process between a hot particle, e.g. a catalyst: particle, and a liquid droplet. The vaporization from the droplet surface results in a overpressure in the film around the droplet, thus preventing the droplets and catalysts particles touching each other (similar to the so-called Leidenfrost: phenomenon). A balance of the relevant forces in combination with the heat balance permits the calculation of both the time-dependent distance between the particle and the droplet and the diameter of the evaporating droplet. 10 refs.

  4. Space Debris Symposium (A6.) Measurements and Space Surveillance (1.): Measurements of the Small Particle Debris Cloud from the 11 January, 2007 Chinese Anti-satellite Test

    NASA Technical Reports Server (NTRS)

    Matney, Mark J.; Stansbery, Eugene; J.-C Liou; Stokely, Christopher; Horstman, Matthew; Whitlock, David

    2008-01-01

    On January 11, 2007, the Chinese military conducted a test of an anti-satellite (ASAT) system, destroying their own Fengyun-1C spacecraft with an interceptor missile. The resulting hypervelocity collision created an unprecedented number of tracked debris - more than 2500 objects. These objects represent only those large enough for the US Space Surveillance Network (SSN) to track - typically objects larger than about 5-10 cm in diameter. There are expected to be even more debris objects at sizes too small to be seen and tracked by the SSN. Because of the altitude of the target satellite (865 x 845 km orbit), many of the debris are expected to have long orbital lifetimes and contribute to the orbital debris environment for decades to come. In the days and weeks following the ASAT test, NASA was able to use Lincoln Laboratory s Haystack radar on several occasions to observe portions of the ASAT debris cloud. Haystack has the capability of detecting objects down to less than one centimeter in diameter, and a large number of centimeter-sized particles corresponding to the ASAT cloud were clearly seen in the data. While Haystack cannot track these objects, the statistical sampling procedures NASA uses can give an accurate statistical picture of the characteristics of the debris from a breakup event. For years computer models based on data from ground hypervelocity collision tests (e.g., the SOCIT test) and orbital collision experiments (e.g., the P-78 and Delta-180 on-orbit collisions) have been used to predict the extent and characteristics of such hypervelocity collision debris clouds, but until now there have not been good ways to verify these models in the centimeter size regime. It is believed that unplanned collisions of objects in space similar to ASAT tests will drive the long-term future evolution of the debris environment in near-Earth space. Therefore, the Chinese ASAT test provides an excellent opportunity to test the models used to predict the future debris

  5. Aqueous Hg(2+) associates with TiO2 nanoparticles according to particle size, changes particle agglomeration, and becomes less bioavailable to zebrafish.

    PubMed

    Boran, Halis; Boyle, David; Altinok, Ilhan; Patsiou, Danae; Henry, Theodore B

    2016-05-01

    Engineered nanoparticles (NPs) have unique physicochemistry and potential to interact with other substances in the aqueous phase. Here, gene [metallothionein 2 (mt2)] expression changes in larval zebrafish were used to evaluate the association between aqueous Hg(2+) and TiO2 (NPs and bulk particle size control) to investigate the relationship between changes in Hg(2+) behavior and TiO2 size. During 24h exposures, TiO2 agglomerates increased in size and in the presence of 25μg Hg(2+)/L, greater increases in size were observed. The concentration of Hg(2+) in suspension also decreased in the presence of TiO2-NPs. Mercury increased expression of mt2 in larval zebrafish, but this response was lessened when zebrafish were exposed to Hg(2+) in the presence of TiO2-NPs, and which suggests that TiO2-NPs alter the bioavailability of Hg(2+) to zebrafish larvae. This ameliorative effect of TiO2 was also likely due to surface binding of Hg(2+) because a greater decrease in mt2 expression was observed in the presence of 1mg/L TiO2-NPs than 1mg/L TiO2-bulk. In conclusion, the results show that Hg(2+) will associate with TiO2-NPs, TiO2-NPs that have associated Hg(2+) will settle out of the aqueous phase more rapidly, and agglomerates will deliver associated Hg(2+) to sediment surfaces. PMID:26970871

  6. In vitro studies on the effect of particle size on macrophage responses to nanodiamond wear debris

    PubMed Central

    Thomas, Vinoy; Halloran, Brian A.; Ambalavanan, Namasivayam; Catledge, Shane A.; Vohra, Yogesh K.

    2012-01-01

    Nanostructured diamond coatings improve the smoothness and wear characteristics of the metallic component of total hip replacements and increase the longevity of these implants, but the effect of nanodiamond wear debris on macrophages needs to be determined to estimate the long-term inflammatory effects of wear debris. The objective was to investigate the effect of the size of synthetic nanodiamond particles on macrophage proliferation (BrdU incorporation), apoptosis (Annexin-V flow cytometry), metabolic activity (WST-1 assay) and inflammatory cytokine production (qPCR). RAW 264.7 macrophages were exposed to varying sizes (6, 60, 100, 250 and 500 nm) and concentrations (0, 10, 50, 100 and 200 μg ml−1) of synthetic nanodiamonds. We observed that cell proliferation but not metabolic activity was decreased with nanoparticle sizes of 6–100 nm at lower concentrations (50 μg ml−1), and both cell proliferation and metabolic activity were significantly reduced with nanodiamond concentrations of 200 μg ml−1. Flow cytometry indicated a significant reduction in cell viability due to necrosis irrespective of particle size. Nanodiamond exposure significantly reduced gene expression of tumor necrosis factor-α, interleukin-1β, chemokine Ccl2 and platelet-derived growth factor compared to serum-only controls or titanium oxide (anatase 8 nm) nanoparticles, with variable effects on chemokine Cxcl2 and vascular endothelial growth factor. In general, our study demonstrates a size and concentration dependence of macrophage responses in vitro to nanodiamond particles as possible wear debris from diamond-coated orthopedic joint implants. PMID:22342422

  7. Neutron Resonance Densitometry for Particle-like Debris of Melted Fuel

    NASA Astrophysics Data System (ADS)

    Harada, H.; Kitatani, F.; Koizumi, M.; Takamine, J.; Kureta, M.; Tsutiya, H.; Iimura, H.; Seya, M.; Becker, B.; Kopecky, S.; Schillebeeckx, P.

    2014-04-01

    Neutron Resonance Densitometry (NRD) is proposed for the quantification of nuclear materials in particle-like debris of melted fuel from the reactors of the Fukushima Daiichi nuclear power plant. The method is based on a combination of neutron resonance transmission analysis (NRTA) and neutron resonance capture analysis (NRCA). It uses the neutron time-of-flight (TOF) technique with a pulsed white neutron source and a neutron flight path as short as 5 m. The spectrometer for NRCA is made of LaBr3(Ce) detectors. The achievable uncertainty due to only counting statistics is less than 1 % to determine Pu and U isotopes.

  8. Acoustic agglomeration methods and apparatus

    NASA Technical Reports Server (NTRS)

    Barmatz, M. B. (Inventor)

    1984-01-01

    Methods are described for using acoustic energy to agglomerate fine particles on the order of one micron diameter that are suspended in gas, to provide agglomerates large enough for efficient removal by other techniques. The gas with suspended particles, is passed through the length of a chamber while acoustic energy at a resonant chamber mode is applied to set up one or more acoustic standing wave patterns that vibrate the suspended particles to bring them together so they agglomerate. Several widely different frequencies can be applied to efficiently vibrate particles of widely differing sizes. The standing wave pattern can be applied along directions transversed to the flow of the gas. The particles can be made to move in circles by applying acoustic energy in perpendicular directions with the energy in both directions being of the same wavelength but 90 deg out of phase.

  9. Colloidal Instability Fosters Agglomeration of Subvisible Particles Created by Rupture of Gels of a Monoclonal Antibody Formed at Silicone Oil-Water Interfaces.

    PubMed

    Mehta, Shyam B; Carpenter, John F; Randolph, Theodore W

    2016-08-01

    In this study, we investigated the effect of ionic strength (1.25-231 mM) on viscoelastic interfacial gels formed by a monoclonal antibody at silicone oil-water interfaces, and the formation of subvisible particles due to rupture of these gels. Rates of gel formation and their elastic moduli did not vary significantly with ionic strength. Likewise, during gel rupture no significant effects of ionic strength were observed on particle formation and aggregation as detected by microflow imaging, resonance mass measurement, and size exclusion chromatography. Subvisible particles formed by mechanical rupturing of the gels agglomerated over time, even during quiescent incubation, due to the colloidal instability of the particles. PMID:27422087

  10. Coal Cleaning by Gas Agglomeration

    SciTech Connect

    Meiyu Shen; Royce Abbott; T. D. Wheelock

    1998-03-01

    The gas agglomeration method of coal cleaning was demonstrated with laboratory scale mixing equipment which made it possible to generate microscopic gas bubbles in aqueous suspensions of coal particles. A small amount of i-octane was introduced to enhance the hydrophobicity of the coal. Between 1.0 and 2.5 v/w% i-octane was sufficient based on coal weight. Coal agglomerates or aggregates were produced which were bound together by small gas bubbles.

  11. Microbial effects on colloidal agglomeration

    SciTech Connect

    Hersman, L.

    1995-11-01

    Colloidal particles are known to enhance the transport of radioactive metals through soil and rock systems. This study was performed to determine if a soil microorganism, isolated from the surface samples collected at Yucca Mountain, NV, could affect the colloidal properties of day particles. The agglomeration of a Wyoming bentonite clay in a sterile uninoculated microbial growth medium was compared to the agglomeration in the medium inoculated with a Pseudomonas sp. In a second experiment, microorganisms were cultured in the succinate medium for 50 h and removed by centrifugation. The agglomeration of the clay in this spent was compared to sterile uninoculated medium. In both experiments, the agglomeration of the clay was greater than that of the sterile, uninoculated control. Based on these results, which indicate that this microorganism enhanced the agglomeration of the bentonite clay, it is possible to say that in the presence of microorganisms colloidal movement through a rock matrix could be reduced because of an overall increase in the size of colloidal particle agglomerates. 32 refs.

  12. MTCI acoustic agglomeration particulate control

    SciTech Connect

    Chandran, R.R.; Mansour, M.N.; Scaroni, A.W.; Koopmann, G.H.; Loth, J.L.

    1994-10-01

    The overall objective of this project is to demonstrate pulse combination induced acoustic enhancement of coal ash agglomeration and sulfur capture at conditions typical of direct coal-fired turbines and PFBC hot gas cleanup. MTCI has developed an advanced compact pulse combustor island for direct coal-firing in combustion gas turbines. This combustor island comprises a coal-fired pulse combustor, a combined ash agglomeration and sulfur capture chamber (CAASCC), and a hot cyclone. In the MTCI proprietary approach, the pulse combustion-induced high intensity sound waves improve sulfur capture efficiency and ash agglomeration. The resulting agglomerates allow the use of commercial cyclones and achieve very high particulate collection efficiency. In the MTCI proprietary approach, sorbent particles are injected into a gas stream subjected to an intense acoustic field. The acoustic field serves to improve sulfur capture efficiency by enhancing both gas film and intra-particle mass transfer rates. In addition, the sorbent particles act as dynamic filter foci, providing a high density of stagnant agglomerating centers for trapping the finer entrained (in the oscillating flow field) fly ash fractions. A team has been formed with MTCI as the prime contractor and Penn State University and West Virginia University as subcontractors to MTCI. MTCI is focusing on hardware development and system demonstration, PSU is investigating and modeling acoustic agglomeration and sulfur capture, and WVU is studying aerovalve fluid dynamics. Results are presented from all three studies.

  13. IMPACT OF PARTICLE SIZE AND AGGLOMERATION ON SETTLING OF SOLIDS IN CONTINUOUS MELTERS PROCESSING RADIOACTIVE WASTE GLASS

    SciTech Connect

    HRMA PR

    2008-12-18

    The major factor limiting waste loading for many waste compositions in continuous waste glass melters is the settling of crystalline materials. The currently used constraints, i.e., the minimum liquidus temperature or the maximum fraction of equilibrium crystallinity at a given temperature, are based on thennodynamic equilibria. Because of the rapid circular convection in the melter, these constraints are probably irrelevant and cannot prevent large crystals from settling. The main factor that detennines the rate of settling ofindividual crystals, such as those ofspinel, is their size. The tiny crystals of RU02 are too small to settle, but they readily fonn large agglomerates that accelerate their rate ofsettling by severalorders ofmagnitude. The RU02 agglomerates originate early in the melting process and then grow by the shear-flocculation mechanism. It is estimated that these agglomerates must either be ofhundreds micrometers in size or have an elongated shape to match the observed rates ofthe sludge-layer fonnation. PACS: 47.57.ef, 81.05.Kj, 81.10.Fg

  14. Numerical modeling of debris flow runout for a case in southwestern China with Smooth Particle Hydrodynamics

    NASA Astrophysics Data System (ADS)

    Braun, Anika; Cuomo, Sabatino; Wang, Xueliang; Zhang, Luqing

    2016-04-01

    Debris flows and landslide dams are a major natural hazard causing high socioeconomic risk in inhabited mountainous areas. This is also true for vast parts of southwestern China, which are highly prone to slope failures due to several factors, such as a humid climate with high precipitation in the summer months, geological predisposing factors with highly weathered sedimentary rocks and a high seismicity. Not only do the landslides and flooding related to landslide dams threaten residents, buildings and transportation structures, but also do flooding conditions endanger power supply, which relies in this region partly on hydropower. In order to assess the potential of landslides to block rivers, it is crucial to understand which factors influence possible run-out distances and how they can be quantified. In the study we are presenting a numerical modeling analysis for a particular case of a complex landslide in Ningnan county, southwestern China, which transformed into a debris flow and blocked the river and the major road leading through the valley after heavy rainfall. For this purpose a quasi-3D Smooth Particle Hydrodynamics (SPH) model was implemented that can account for geotechnical slope parameters, run-out distance, velocities and deposition heights. A digital terrain model and the geometry information of the landslide were used as input data in order to estimate the relevant geotechnical parameters by back-analysis. The results of the analysis can be used for the prediction of run-out distances for future events at this site and other similar sites.

  15. Natural and orbital debris particles on LDEF's trailing and forward-facing surfaces

    NASA Technical Reports Server (NTRS)

    Hoerz, Friedrich; See, Thomas H.; Bernhard, Ronald P.; Brownlee, Donald E.

    1995-01-01

    Approximately 1000 impact craters on the Chemistry of Meteoroid Experiment (CME) have been analyzed by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Analysis (EDXA) to determine the compositional make-up of projectile residues. This report completes our systematic survey of gold and aluminum surfaces exposed at the trailing-edge (A03) and forward-facing (A11) LDEF sites, respectively. The major categories for the projectile residues were (1) natural, with diverse subgroups such as chondritic, monomineralic silicates, and sulfides, and (2) man made, that were classified into aluminum (metallic or oxide) and miscellaneous materials (such as stainless steel, paint flakes, etc). On CME gold collectors on LDEF's trailing edge approximately 11 percent of all craters greater than 100 micron in diameter were due to man-made debris, the majority (8.6 percent) caused by pure aluminum, approximately 31.4 percent were due to cosmic dust, while the remaining 58 percent were indeterminate via the analytical techniques utilized in this study. The aluminum surfaces located at the A11 forward-facing site did not permit analysis of aluminum impactors, but approximately 9.4 percent of all craters were demonstratably caused by miscellaneous debris materials and approximately 39.2 percent were the result of natural particles, leaving approximately 50 percent which were indeterminate. Model considerations and calculations are presented that focus on the crater-production rates for features greater than 100 micron in diameter, and on assigning the intermediate crater population to man-made or natural particles. An enhancement factor of 6 in the crater-production rate of natural impactors for the 'forward-facing' versus the 'trailing-edge' CME collectors was found to best explain all observations (i.e., total crater number(s), as well as their computational characteristics). Enhancement factors of 10 and 4 are either too high or too low. It is also suggested that

  16. Porous Chromatographic Materials as Substrates for Preparing Synthetic Nuclear Explosion Debris Particles

    SciTech Connect

    Harvey, Scott D.; Liezers, Martin; Antolick, Kathryn C.; Garcia, Ben J.; Sweet, Lucas E.; Carman, April J.; Eiden, Gregory C.

    2013-06-13

    In this study, we investigated several porous chromatographic materials as synthetic substrates for preparing surrogate nuclear explosion debris particles. The resulting synthetic debris materials are of interest for use in developing analytical methods. Eighteen metals, including some of forensic interest, were loaded onto materials by immersing them in metal solutions (556 mg/L of each metal) to fill the pores, applying gentle heat (110°C) to drive off water, and then treating them at high temperatures (up to 800°C) in air to form less soluble metal species. High-boiling-point metals were uniformly loaded on spherical controlled-pore glass to emulate early fallout, whereas low-boiling-point metals were loaded on core-shell silica to represent coated particles formed later in the nuclear fallout-formation process. Analytical studies were applied to characterize solubility, material balance, and formation of recalcitrant species. Dissolution experiments indicated loading was 1.5 to 3 times higher than expected from the pore volume alone, a result attributed to surface coating. Analysis of load solutions before and after filling the material pores revealed that most metals were passively loaded; that is, solutions filled the pores without active metal discrimination. However, niobium and tin concentrations were lower in solutions after pore filling, and were found in elevated concentrations in the final products, indicating some metals were selectively loaded. High-temperature treatments caused reduced solubility of several metal species, and loss of some metals (rhenium and tellurium) because volatile species were formed. Sample preparation reproducibility was high (the inter-batch relative standard deviation was 7.8%, and the intra-batch relative standard deviation was 0.84%) indicating that this material is suitable for use as a working standard for analytical methods development. We anticipate future standardized radionuclide-loaded materials will find use in

  17. Powder agglomeration in a microgravity environment

    NASA Technical Reports Server (NTRS)

    Cawley, James D.

    1994-01-01

    This is the final report for NASA Grant NAG3-755 entitled 'Powder Agglomeration in a Microgravity Environment.' The research program included both two types of numerical models and two types of experiments. The numerical modeling included the use of Monte Carlo type simulations of agglomerate growth including hydrodynamic screening and molecular dynamics type simulations of the rearrangement of particles within an agglomerate under a gravitational field. Experiments included direct observation of the agglomeration of submicron alumina and indirect observation, using small angle light scattering, of the agglomeration of colloidal silica and aluminum monohydroxide. In the former class of experiments, the powders were constrained to move on a two-dimensional surface oriented to minimize the effect of gravity. In the latter, some experiments involved mixture of suspensions containing particles of opposite charge which resulted in agglomeration on a very short time scale relative to settling under gravity.

  18. Mechanisms for selective agglomeration of coals

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.-C.; Tyson, D.; Xiaoping, Qiu; Lessa, A.

    1989-05-01

    Work continued on the basic mechanisms which underlie various processes for beneficiating aqueous suspensions of coal by selective agglomeration with oil. A new method was demonstrated for characterizing the agglomerability of coal suspensions. This method utilizes a photometric dispersion analyzer to monitor changes in the turbidity of a particle suspension as increasing amounts of oil are added to the suspension in a batch agglomeration test. Agglomeration of the particles leads to a marked decrease in the turbidity of the suspension. Another experimental technique was also demonstrated for characterizing oil agglomeration. This technique involves measuring the rate of growth of agglomerates in a continuous flow system operating under stead-state conditions. The data are analyzed by means of a population balance. The results of a preliminary set of experiments in which Indiana V seam coal was agglomerated with tetralin seemed to fit a particular growth model very well. Equipment was also constructed for studying the kinetics of agglomeration in a batch process. While earlier work showed that quebracho (a commercially available dispersant) is a strong agglomeration depressant for pyrite, recent experiments with mixtures of Upper Freeport coal and mineral pyrite showed that quebracho does not appear to be sufficiently selective. Further consideration was given to the separation of mixtures of coal and pyrite agglomeration with heptane. 2 refs., 17 figs., 1 tab.

  19. Fuel agglomerates and method of agglomeration

    DOEpatents

    Wen, Wu-Wey

    1986-01-01

    Solid fuel agglomerates are prepared of particulate coal or other carbonaceous material with a binder having a high humic acid or humate salt content. The humic acid is extracted from oxidized carbonaceous material with a mild aqueous alkali solution of, for instance, ammonia. The particulate material is blended with the extract which serves as the binder for the agglomerates. The water-resistant agglomerates are formed such as by pelletizing, followed by drying to remove moisture and solidify the humic acid binder throughout the agglomerate.

  20. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect

    T.D. Wheelock

    1999-03-01

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  1. Enhancement of the Wear Particle Monitoring Capability of Oil Debris Sensors Using a Maximal Overlap Discrete Wavelet Transform with Optimal Decomposition Depth

    PubMed Central

    Li, Chuan; Peng, Juan; Liang, Ming

    2014-01-01

    Oil debris sensors are effective tools to monitor wear particles in lubricants. For in situ applications, surrounding noise and vibration interferences often distort the oil debris signature of the sensor. Hence extracting oil debris signatures from sensor signals is a challenging task for wear particle monitoring. In this paper we employ the maximal overlap discrete wavelet transform (MODWT) with optimal decomposition depth to enhance the wear particle monitoring capability. The sensor signal is decomposed by the MODWT into different depths for detecting the wear particle existence. To extract the authentic particle signature with minimal distortion, the root mean square deviation of kurtosis value of the segmented signal residue is adopted as a criterion to obtain the optimal decomposition depth for the MODWT. The proposed approach is evaluated using both simulated and experimental wear particles. The results show that the present method can improve the oil debris monitoring capability without structural upgrade requirements. PMID:24686730

  2. Multidimensional nature of fluidized nanoparticle agglomerates.

    PubMed

    de Martín, Lilian; Bouwman, Wim G; van Ommen, J Ruud

    2014-10-28

    We show that fluidized nanoparticle agglomerates are hierarchical fractal structures with three fractal dimensions: one characterizing sintered aggregates formed during nanoparticle synthesis, one that is also found in stored agglomerates and represents unbroken agglomerates, and one describing the large agglomerates broken during fluidization. This has been possible by using spin-echo small-angle neutron scattering-a relatively novel technique that, for the first time, allowed to characterize in situ the structure of fluidized nanoparticle agglomerates from 21 nm to ∼20 μm. The results show that serial agglomeration mechanisms in the gas phase can generate nanoparticle clusters with different fractal dimensions, contradicting the common approach that considers fluidized nanoparticle agglomerates as single fractals, in analogy to the agglomerates formed by micron-sized particles. This work has important implications for the fluidization field but also has a wider impact. Current studies deal with the formation and properties of clusters where the building blocks are particles and the structure can be characterized by only one fractal dimension. However, fluidized nanoparticle agglomerates are low-dimensional clusters formed by higher-dimensional clusters that are formed by low-dimensional clusters. This multifractality demands a new type of multiscale model able to capture the interplay between different scales. PMID:25313446

  3. Dust agglomeration

    NASA Technical Reports Server (NTRS)

    2000-01-01

    John Marshall, an investigator at Ames Research Center and a principal investigator in the microgravity fluid physics program, is studying the adhesion and cohesion of particles in order to shed light on how granular systems behave. These systems include everything from giant dust clouds that form planets to tiny compressed pellets, such as the ones you swallow as tablets. This knowledge should help us control the grains, dust, and powders that we encounter or use on a daily basis. Marshall investigated electrostatic charge in microgravity on the first and second U.S. Microgravity Laboratory shuttle missions to see how grains aggregate, or stick together. With gravity's effects eliminated on orbit, Marshall found that the grains of sand that behaved ever so freely on Earth now behaved like flour. They would just glom together in clumps and were quite difficult to disperse. That led to an understanding of the prevalence of the electrostatic forces. The granules wanted to aggregate as little chains, like little hairs, and stack end to end. Some of the chains had 20 or 30 grains. This phenomenon indicated that another force, what Marshall believes to be an electrostatic dipole, was at work.(The diagram on the right emphasizes the aggregating particles in the photo on the left, taken during the USML-2 mission in 1995.)

  4. Engineering development of selective agglomeration. Final report

    SciTech Connect

    Not Available

    1993-04-01

    This report presents the findings of the project entitled ``Engineering Development of Selective Agglomeration.`` The purpose is to develop selective agglomeration technology to a commercially acceptable level by 1993. Engineering development included bench-scale process development, component development adaptation or modification of existing unit operations, proof-of-concept (POC) module design, fabrication, testing, data evaluation, and conceptual design of a commercial facility. The information obtained during POC operation resulted in a technical and economic design base sufficient to support construction and operation of a commercial plant. Throughout this project performance targets for the engineering development of selective agglomeration process were to achieve 85% or greater Btu recovery at 85% or greater pyritic sulfur rejection (PSR). Additional objectives included producing a final clean-coal product with an ash content of 6% or less which is suitable for conventional coal handling systems. The selective agglomeration process, as applied to coal cleaning, is based on differences in the surface chemistry of coal and its associated impurities. Coal particles are hydrophobic (i.e., repel water) while the majority of its impurities are hydrophilic (i.e., stabilized in water). During selective agglomeration, a liquid (the agglomerant) that is immiscible with water is introduced into a coal-water slurry and agitated to disperse it in the slurry, thereby allowing it to come into contact with all particles in the slurry. The coal particles, due to their hydrophobic nature, are attracted to the agglomerant phase. The hydrophilic mineral impurities remain in the water phase. Continued agitation of the agglomerant-coated coal particles causes them to coalesce to form agglomerates. Once the agglomerates are formed, they are separated from the mineral matter-bearing aqueous phase by subsequent processing steps.

  5. Investigation of Gear and Bearing Fatigue Damage Using Debris Particle Distributions

    NASA Technical Reports Server (NTRS)

    Dempsey, Paula J.; Lewicki, David G.; Decker, Harry J.

    2004-01-01

    A diagnostic tool was developed for detecting fatigue damage to spur gears, spiral bevel gears, and rolling element bearings. This diagnostic tool was developed and evaluated experimentally by collecting oil debris data from fatigue tests performed in the NASA Glenn Spur Gear Fatigue Rig, Spiral Bevel Gear Test Facility, and the 500hp Helicopter Transmission Test Stand. During each test, data from an online, in-line, inductance type oil debris sensor was monitored and recorded for the occurrence of pitting damage. Results indicate oil debris alone cannot discriminate between bearing and gear fatigue damage.

  6. Large-scale Particle Simulations for Debris Flows using Dynamic Load Balance on a GPU-rich Supercomputer

    NASA Astrophysics Data System (ADS)

    Tsuzuki, Satori; Aoki, Takayuki

    2016-04-01

    Numerical simulations for debris flows including a countless of objects is one of important topics in fluid dynamics and many engineering applications. Particle-based method is a promising approach to carry out the simulations for flows interacting with objects. In this paper, we propose an efficient method to realize a large-scale simulation for fluid-structure interaction by combining SPH (Smoothed Particle Hydrodynamics) method for fluid with DEM (Discrete Element Method) for objects on a multi-GPU system. By applying space filling curves to decomposition of the computational domain, we are able to contain the same number of particles in each decomposed domain. In our implementation, several techniques for particle counting and data movement have been introduced. Fragmentation of the memory used for particles happens during the time-integration and the frequency of de-fragmentation is examined by taking account for computational load balance and the communication cost between CPU and GPU. A link-list technique of the particle interaction is introduced to save the memory drastically. It is found that the sorting of particle data for the neighboring particle list using linked-list method improves the memory access greatly with a certain interval. The weak and strong scalabilities for a SPH simulation using 111 Million particles was measured from 4 GPUs to 512 GPUs for three types of space filling curves. A large-scale debris flow simulation of tsunami with 10,368 floating rubbles using 117 Million particles were successfully carried out with 256 GPUs on the TSUBAME 2.5 supercomputer at Tokyo Institute of Technology.

  7. Varying the agglomeration position of particles in a micro-channel using Acoustic Radiation Force beyond the resonance condition.

    PubMed

    Dron, Olivier; Aider, Jean-Luc

    2013-09-01

    It is well-known that particles can be focused at mid-height of a micro-channel using Acoustic Radiation Force (ARF) tuned at the resonance frequency (h=λ/2). The resonance condition is a strong limitation to the use of acoustophoresis (particles manipulation using acoustic force) in many applications. In this study we show that it is possible to focus the particles anywhere along the height of a micro-channel just by varying the acoustic frequency, in contradiction with the resonance condition. This result has been thoroughly checked experimentally. The different physical properties as well as wall materials have been changed. The wall materials is finally the only critical parameters. One of the specificity of the micro-channel is the thickness of the carrier and reflector layer. A preliminary analysis of the experimental results suggests that the acoustic focusing beyond the classic resonance condition can be explained in the framework of the multilayered resonator proposed by Hill [1]. Nevertheless, further numerical studies are needed in order to confirm and fully understand how the acoustic pressure node can be moved over the entire height of the micro channel by varying the acoustic frequency. Despite some uncertainties about the origin of the phenomenon, it is robust and can be used for improved acoustic sorting or manipulation of particles or biological cells in confined set-ups. PMID:23628114

  8. Agglomeration of microparticles in complex plasmas

    SciTech Connect

    Du, Cheng-Ran; Thomas, Hubertus M.; Ivlev, Alexei V.; Konopka, Uwe; Morfill, Gregor E.

    2010-11-15

    Agglomeration of highly charged microparticles was observed and studied in complex plasma experiments carried out in a capacitively coupled rf discharge. The agglomeration was caused by strong waves triggered in a particle cloud by decreasing neutral gas pressure. Using a high-speed camera during this unstable regime, it was possible to resolve the motion of individual microparticles and to show that the relative velocities of some particles were sufficiently high to overcome the mutual Coulomb repulsion and hence to result in agglomeration. After stabilizing the cloud again through the increase of the pressure, we were able to observe the aggregates directly with a long-distance microscope. We show that the agglomeration rate deduced from our experiments is in good agreement with theoretical estimates. In addition, we briefly discuss the mechanisms that can provide binding of highly charged microparticles in a plasma.

  9. Successfully use agglomeration for size enlargement

    SciTech Connect

    Pietsch, W.

    1996-04-01

    The processing of fine and ultrafine particles by size enlargement finds an ever increasing application. At the same time, undesirable agglomeration such as buildup, caking, bridging, and uncontrolled aggregation of fine particles can occur during processing and handling of these particulate solids. This article will provide a survey of the phenomena of agglomeration and discuss the unit operation of size enlargement by agglomeration. This article is also an invitation, particularly to young engineers, to become interested in agglomeration. Considering that mechanical process technologies are requiring more energy every year than any other group of consumers and efficiencies are typically in the single digits or teens at best, considerable rewards can be expected from the development of scientifically modified, more energy-efficient methods and equipment.

  10. Mechanisms for selective agglomeration of coals

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.-C.; Tyson, D.; Xiaoping, Qiu; Lessa, A.

    1989-10-01

    Measurement and control of the surface properties of coal and pyrite are important in the application of selective oil agglomeration for coal beneficiation and both received further study and consideration. One method of surface characterization involves measuring the heat of immersion of coal in water or other liquids. To develop a useful and consistent measurement technique, numerous measurements were conducted with Illinois No. 6 coal to study the effects of coal particle size and moisture content on the heat of immersion in heptane, water, hexadecane and methanol. The effect of particle size was also studied. Also, ground mineral pyrite was pretreated with dilute solutions of sodium sulfide at various Ph and then agglomerated with heptane. To achieve better control over the oil agglomeration process, oil agglomeration experiments were conducted with aqueous suspensions of graphite which were first degassed with a vacuum pump. 7 refs., 16 figs., 2 tabs.

  11. Advances in food powder agglomeration engineering.

    PubMed

    Cuq, B; Gaiani, C; Turchiuli, C; Galet, L; Scher, J; Jeantet, R; Mandato, S; Petit, J; Murrieta-Pazos, I; Barkouti, A; Schuck, P; Rondet, E; Delalonde, M; Dumoulin, E; Delaplace, G; Ruiz, T

    2013-01-01

    Food powders are used in everyday life in many ways and offer technological solutions to the problem of food production. The natural origin of food powders, diversity in their chemical composition, variability of the raw materials, heterogeneity of the native structures, and physicochemical reactivity under hydrothermal stresses contribute to the complexity in their behavior. Food powder agglomeration has recently been considered according to a multiscale approach, which is followed in the chapter layout: (i) at the particle scale, by a presentation of particle properties and surface reactivity in connection with the agglomeration mechanisms, (ii) at the mechanisms scale, by describing the structuration dynamics of agglomerates, (iii) at the process scale, by a presentation of agglomeration technologies and sensors and by studying the stress transmission mode in the powder bed, and finally (iv) by an integration of the acquired knowledge, thanks to a dimensional analysis carried out at each scale. PMID:23522795

  12. Multifrequency scanning probe microscopy study of nanodiamond agglomerates

    NASA Astrophysics Data System (ADS)

    Aravind, Vasudeva; Lippold, Stephen; Li, Qian; Strelcov, Evgheny; Okatan, Baris; Legum, Benjamin; Kalinin, Sergei; Clarion University Team; Oak Ridge National Laboratory Team

    Due to their rich surface chemistry and excellent mechanical properties and non-toxic nature, nanodiamond particles have found applications such as biomedicine, tribology and lubrication, targeted drug delivery systems, tissue scaffolds and surgical implants. Although single nanodiamond particles have diameters about 4-5nm, they tend to form agglomerates. While these agglomerates can be useful for some purposes, many applications of nanodiamonds require single particle, disaggregated nanodiamonds. This work is oriented towards studying forces and interactions that contribute to agglomeration in nanodiamonds. In this work, using multifrequency scanning probe microscopy techniques, we show that agglomerate sizes can vary between 50-100nm in raw nanodiamonds. Extremeties of particles and Interfaces between agglomerates show dissipative forces with scanning probe microscope tip, indicating agglomerates could act as points of increased adhesion, thus reducing lubricating efficiency when nanodiamonds are used as lubricant additives. This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

  13. Effect of temperature on wet agglomeration of crystals

    PubMed Central

    Maghsoodi, Maryam; Yari, Zahra

    2014-01-01

    Objective(s): This study dealt with the wet agglomeration process in which a small quantity of binder liquid was added into a suspension of crystals, directly in the stirring vessel where the crystallization took place. The purpose of this investigation was evaluation of the effect of temperature on the agglomeration process in order to gain insight into the mechanism of the formation of the agglomerates. Materials and Methods: Carbamazepine was used as a model drug and water/ethanol and isopropyl acetate were used as crystallization system and binder liquid, respectively. The agglomeration of crystals was carried out at various temperatures and the agglomerates were characterized in terms of size, morphology, density and mechanical strength. Results: Evaluation of the agglomerates along the course of agglomeration shows that the properties of the particles change gradually but substantially. Higher temperature of the system during agglomeration process favors the formation of more regular agglomerates with mechanically stronger and denser structure; this can be explained by the promotion effect of temperature on the agglomeration process. Conclusion: With optimized wet agglomeration temperature, spherical, dense, and strong agglomerates can be obtained. PMID:24967063

  14. Development of a Gas-Promoted Oil Agglomeration Process

    SciTech Connect

    C. Nelson; F. Zhang; J. Drzymala; M. Shen; R. Abbott; T. D. Wheelock

    1997-11-01

    The preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal was carried out with scale model mixing systems in which aqueous suspensions of ultrafine coal particles were treated with a liquid hydrocarbon and a small amount of air. The resulting agglomerates were recovered by screening. During a batch agglomeration test the progress of agglomeration was monitored by observing changes in agitator torque in the case of concentrated suspensions or by observing changes in turbidity in the case of dilute suspensions. Dilute suspensions were employed for investigating the kinetics of agglomeration, whereas concentrated suspensions were used for determining parameters that characterize the process of agglomeration. A key parameter turned out to be the minimum time te required to produce compact spherical agglomerates. Other important parameters included the projected area mean particle diameter of the agglomerates recovered at the end of a test as well as the ash content and yield of agglomerates. Batch agglomeration tests were conducted with geometrically similar mixing tanks which ranged in volume from 0.346 to 11.07 liters. Each tank was enclosed to control the amount of air present. A variable speed agitator fitted with a six blade turbine impeller was used for agitation. Tests were conducted with moderately hydrophobic Pittsburgh No. 8 coal and with more hydrophobic Upper Freeport coal using either n-heptane, i-octane, or hexadecane as an agglomerant.

  15. Microstickies agglomeration by electric field.

    PubMed

    Du, Xiaotang Tony; Hsieh, Jeffery S

    2016-01-01

    Microstickies deposits on both paper machine and paper products when it agglomerates under step change in ionic strength, pH, temperature and chemical additives. These stickies increase the down time of the paper mill and decrease the quality of paper. The key property of microstickies is its smaller size, which leads to low removal efficiency and difficulties in measurement. Thus the increase of microstickies size help improve both removal efficiency and reduce measurement difficulty. In this paper, a new agglomeration technology based on electric field was investigated. The electric treatment could also increase the size of stickies particles by around 100 times. The synergetic effect between electric field treatment and detacky chemicals/dispersants, including polyvinyl alcohol, poly(diallylmethylammonium chloride) and lignosulfonate, was also studied. PMID:27332828

  16. Rapid determination of plasmonic nanoparticle agglomeration status in blood.

    PubMed

    Jenkins, Samir V; Qu, Haiou; Mudalige, Thilak; Ingle, Taylor M; Wang, Rongrong; Wang, Feng; Howard, Paul C; Chen, Jingyi; Zhang, Yongbin

    2015-05-01

    Plasmonic nanomaterials as drug delivery or bio-imaging agents are typically introduced to biological systems through intravenous administration. However, the potential for agglomeration of nanoparticles in biological systems could dramatically affect their pharmacokinetic profile and toxic potential. Development of rapid screening methods to evaluate agglomeration is urgently needed to monitor the physical nature of nanoparticles as they are introduced into blood. Here, we establish novel methods using darkfield microscopy with hyperspectral detection (hsDFM), single particle inductively-coupled plasma mass spectrometry (spICP-MS), and confocal Raman microscopy (cRM) to discriminate gold nanoparticles (AuNPs) and their agglomerates in blood. Rich information about nanoparticle agglomeration in situ is provided by hsDFM monitoring of the plasmon resonance of primary nanoparticles and their agglomerates in whole blood; cRM is an effective complement to hsDFM to detect AuNP agglomerates in minimally manipulated samples. The AuNPs and the particle agglomerates were further distinguished in blood for the first time by quantification of particle mass using spICP-MS with excellent sensitivity and specificity. Furthermore, the agglomeration status of synthesized and commercial NPs incubated in blood was successfully assessed using the developed methods. Together, these complementary methods enable rapid determination of the agglomeration status of plasmonic nanomaterials in biological systems, specifically blood. PMID:25771013

  17. Rapid Determination of Plasmonic Nanoparticle Agglomeration Status in Blood

    PubMed Central

    Jenkins, Samir V.; Qu, Haiou; Mudalige, Thilak; Ingle, Taylor; Wang, RongRong; Wang, Feng; Howard, Paul C.; Chen, Jingyi; Zhang, Yongbin

    2015-01-01

    Plasmonic nanomaterials as drug delivery or bio-imaging agents are typically introduced to biological systems through intravenous administration. However, the potential for agglomeration of nanoparticles in biological systems could dramatically affect their pharmacokinetic profile and toxic potential. Development of rapid screening methods to evaluate agglomeration is urgently needed to monitor the physical nature of nanoparticles as they are introduced into blood. Here, we establish novel methods using darkfield microscopy with hyperspectral detection (hsDFM), single particle inductively-coupled plasma mass spectrometry (spICP-MS), and confocal Raman microscopy (cRM) to discriminate gold nanoparticles (AuNPs) and their agglomerates in blood. Rich information about nanoparticle agglomeration in situ is provided by hsDFM monitoring of the plasmon resonance of primary nanoparticles and their agglomerates in whole blood; cRM is an effective complement to hsDFM to detect AuNP agglomerates in minimally manipulated samples. The AuNPs and the particle agglomerates were further distinguished in blood for the first time by quantification of particle mass using spICP-MS with excellent sensitivity and specificity. Furthermore, the agglomeration status of synthesized and commercial NPs incubated in blood was successfully assessed using the developed methods. Together, these complementary methods enable rapid determination of the agglomeration status of plasmonic nanomaterials in biological systems, specifically blood. PMID:25771013

  18. The orbital characteristics of debris particle rings as derived from IDE observations of multiple orbit intersections with LDEF

    NASA Technical Reports Server (NTRS)

    Cooke, William J.; Oliver, John P.; Simon, Charles G.

    1995-01-01

    During the first 346 days of the LDEF's almost 6 year stay in space, the metal oxide silicon detectors of the Interplanetary Dust Experiment (IDE) recorded over 15,000 impacts, most of which were separated in time by integer multiples of the LDEF orbital period (called multiple orbit event sequences, or MOES). Simple celestial mechanics provides ample reason to expect that a good deal of information about the orbits of the impacting debris particles can be extracted from these MOES, and so a procedure, based on the work of Greenberg, has been developed and applied to one of these events, the so-called 'May swarm'. This technique, the 'Method of Differential Precession,' allows for the determination of the geometrical elements of a particle orbit from the change in the position of the impact point with time. The application of this approach to the May swarm gave the following orbital elements for the orbit of the particles striking LDEF during this MOES: a = 6746.5 km; 0.0165 less than e less than 0.025; i = 66.55 deg; Omega(sub 0) = 179.0 deg plus or minus 0.2 deg; omega = 178.1 deg plus or minus 0.2 deg.

  19. The orbital characteristics of debris particle rings as derived from IDE observations of multiple orbit intersections with LDEF

    SciTech Connect

    Cooke, W.J.; Oliver, J.P.; Simon, C.G.

    1995-02-01

    During the first 346 days of the LDEF`s almost 6 year stay in space, the metal oxide silicon detectors of the Interplanetary Dust Experiment (IDE) recorded over 15,000 impacts, most of which were separated in time by integer multiples of the LDEF orbital period (called multiple orbit event sequences, or MOES). Simple celestial mechanics provides ample reason to expect that a good deal of information about the orbits of the impacting debris particles can be extracted from these MOES, and so a procedure, based on the work of Greenberg, has been developed and applied to one of these events, the so-called `May swarm`. This technique, the `Method of Differential Precession,` allows for the determination of the geometrical elements of a particle orbit from the change in the position of the impact point with time. The application of this approach to the May swarm gave the following orbital elements for the orbit of the particles striking LDEF during this MOES: a = 6746.5 km; 0.0165 less than e less than 0.025; i = 66.55 deg; Omega(sub 0) = 179.0 deg plus or minus 0.2 deg; omega = 178.1 deg plus or minus 0.2 deg.

  20. Frequency comparative study of coal-fired fly ash acoustic agglomeration.

    PubMed

    Liu, Jianzhong; Wang, Jie; Zhang, Guangxue; Zhou, Junhu; Cen, Kefa

    2011-01-01

    Particulate pollution is main kind of atmospheric pollution. The fine particles are seriously harmful to human health and environment. Acoustic agglomeration is considered as a promising pretreatment technology for fine particle agglomeration. The mechanisms of acoustic agglomeration are very complex and the agglomeration efficiency is affected by many factors. The most important and controversial factor is frequency. Comparative studies between high-frequency and low-frequency sound source to agglomerate coal-fired fly ash were carried out to investigate the influence of frequency on agglomeration efficiency. Acoustic agglomeration theoretical analysis, experimental particle size distributions (PSDs) and orthogonal design were examined. The results showed that the 20 kHz high-frequency sound source was not suitable to agglomerate coal-fired fly ash. Only within the size ranging from 0.2 to 0.25 microm the particles agglomerated to adhere together, and the agglomerated particles were smaller than 2.5 microm. The application of low-frequency (1000-1800 Hz) sound source was proved as an advisable pretreatment with the highest agglomeration efficiency of 75.3%, and all the number concentrations within the measuring range decreased. Orthogonal design L16 (4)3 was introduced to determine the optimum frequency and optimize acoustic agglomeration condition. According to the results of orthogonal analysis, frequency was the dominant factor of coal-fired fly ash acoustic agglomeration and the optimum frequency was 1400 Hz. PMID:22432309

  1. Is there a real danger of concealing gunshot residue (GSR) particles by skin debris using the tape-lift method for sampling GSR from hands?

    PubMed

    Zeichner, A

    2001-11-01

    Experiments were carried out to assess the danger of concealing GSR particles by skin debris using the tape-lift method for sampling GSR from hands. Thirty discrete spherical particles (from GSR and from the debris of oxygen cutting of steel) sized from 8 to 30 microns were mounted on a double-side adhesive coated stubs in known locations using a stereomicroscope. These stubs were then used for dabbing hands 50 times. Some of the particles or parts thereof were covered by skin flakes, however, all particles could be detected using the backscattered electron image (BEI) in the scanning electron microscope (SEM). Also, all could be identified by the energy dispersive X-ray spectroscopy (EDX). PMID:11714158

  2. Agglomeration of ceramic powders

    NASA Technical Reports Server (NTRS)

    Cawley, James D.; Larosa, Judith; Dirkse, Fredrick

    1989-01-01

    A research program directed at a critical comparison of numerical models for power agglomeration with experimental observations is currently underway. Central to this program is the quantitative characterization of the distribution of mass within an agglomerate as a function of time. Current experiments are designed to restrict agglomeration to a surface, which is oriented perpendicular to the force of gravity. These experiments are discussed with reference to: their significance to ceramic processing; artifacts which may be avoided in microgravity experiments; and the comparison of information available in real space (from optical microscopy) to that in reciprocal space (from light scattering). The principle machine requirement appears to be a need to obtain information at small scattering angles.

  3. General concepts of hydrargillite Al(OH) 3, agglomeration

    NASA Astrophysics Data System (ADS)

    Veesler, S.; Roure, S.; Boistelle, R.

    1994-02-01

    Agglomeration is an important stage of the Bayer process aiming at increasing the initial size of Al(OH) 3 particles. In the present work, we investigate the effects of supersaturation, seed charge and stirring rate on the agglomeration of hydrargillite crystallites, the size of which ranges from about 2 to 10 μm. The experiments are carried out in a batch crystallizer at constant temperature and caustic concentration. It is shown that the agglomeration rate increases with increasing seed charge, but rapidly reaches a plateau before decreasing when the seed charge is too high. On the other hand, agglomeration continuously decreases with increasing stirring rate, while it is favoured by increasing supersaturation. In the latter case, growth of the crystallites contributes to coarsening the agglomerates. We propose the general outlines of an agglomeration model taking collision and disagglomeration probabilities into account.

  4. Analysis and synthesis of solutions for the agglomeration process modeling

    NASA Astrophysics Data System (ADS)

    Babuk, V. A.; Dolotkazin, I. N.; Nizyaev, A. A.

    2013-03-01

    The present work is devoted development of model of agglomerating process for propellants based on ammonium perchlorate (AP), ammonium dinitramide (ADN), HMX, inactive binder, and nanoaluminum. Generalization of experimental data, development of physical picture of agglomeration for listed propellants, development and analysis of mathematical models are carried out. Synthesis of models of various phenomena taking place at agglomeration implementation allows predicting of size and quantity, chemical composition, structure of forming agglomerates and its fraction in set of condensed combustion products. It became possible in many respects due to development of new model of agglomerating particle evolution on the surface of burning propellant. Obtained results correspond to available experimental data. It is supposed that analogical method based on analysis of mathematical models of particular phenomena and their synthesis will allow implementing of the agglomerating process modeling for other types of metalized solid propellants.

  5. An LDEF 2 dust instrument for discrimination between orbital debris and natural particles in near-Earth space

    NASA Technical Reports Server (NTRS)

    Tuzzolino, A. J.; Simpson, J. A.; Mckibben, R. B.; Voss, H. D.; Gursky, H.

    1993-01-01

    The characteristics of a space dust instrument which would be ideally suited to carry out near-Earth dust measurements on a possible Long Duraction Exposure Facility reflight mission (LDEF 2) is discussed. As a model for the trajectory portion of the instrument proposed for LDEF 2, the characteristics of a SPAce DUSt instrument (SPADUS) currently under development for flight on the USA ARGOS mission to measure the flux, mass, velocity, and trajectory of near-Earth dust is summarized. Since natural (cosmic) dust and man-made dust particles (orbital debris) have different velocity and trajectory distributions, they are distinguished by means of the SPADUS velocity/trajectory information. The SPADUS measurements will cover the dust mass range approximately 5 x 10(exp -12) g (2 microns diameter) to approximately 1 x 10(exp -5) g (200 microns diameter), with an expected mean error in particle trajectory of approximately 7 deg (isotropic flux). Arrays of capture cell devices positioned behind the trajectory instrumentation would provide for Earth-based chemical and isotopic analysis of captured dust. The SPADUS measurement principles, characteristics, its role in the ARGOS mission, and its application to an LDEF 2 mission are summarized.

  6. Debris characteristics from a colloidal microjet target containing tin dioxide nano-particles

    NASA Astrophysics Data System (ADS)

    Higashiguchi, Takeshi; Suetake, Sumihiro; Senba, Yusuke; Sato, Yusuke; Hosotani, Akira; Takahashi, Yukari; Kubodera, Shoichi

    2007-03-01

    Characteristics of suprathermal ions and neutral particles from a laser-produced tin plasma by use of a colloidal microjet target containing tin dioxide (SnO II) nanoparticles were investigated. Suprathermal ion emissions were reduced by producing a low-density preplasma. Simultaneously, the maximum conversion efficiency of 1.2% at 13.5 nm with a bandwidth of 2% and a solid angle of 2π sr was observed. Neutral particles, however, were not suppressed under the optimum laser-plasma conditions.

  7. Unstructured multigrid through agglomeration

    NASA Technical Reports Server (NTRS)

    Venkatakrishnan, V.; Mavriplis, D. J.; Berger, M. J.

    1993-01-01

    In this work the compressible Euler equations are solved using finite volume techniques on unstructured grids. The spatial discretization employs a central difference approximation augmented by dissipative terms. Temporal discretization is done using a multistage Runge-Kutta scheme. A multigrid technique is used to accelerate convergence to steady state. The coarse grids are derived directly from the given fine grid through agglomeration of the control volumes. This agglomeration is accomplished by using a greedy-type algorithm and is done in such a way that the load, which is proportional to the number of edges, goes down by nearly a factor of 4 when moving from a fine to a coarse grid. The agglomeration algorithm has been implemented and the grids have been tested in a multigrid code. An area-weighted restriction is applied when moving from fine to coarse grids while a trivial injection is used for prolongation. Across a range of geometries and flows, it is shown that the agglomeration multigrid scheme compares very favorably with an unstructured multigrid algorithm that makes use of independent coarse meshes, both in terms of convergence and elapsed times.

  8. Agglomeration and Sedimentation of MWCNTS in Chloroform

    NASA Astrophysics Data System (ADS)

    Eremin, Yu. S.; Kolesnikova, A. A.; Grekhov, A. M.

    The kinetics of agglomeration of multiwalled carbon nanotubes dispersed in chloroform has been studied by the methods of optical spectroscopy and dynamic light scattering. With the use of the models of the diffusion of cylindrical particles, the sizes of particles obtained by this method can be recalculated to the DLS data and the concentration at which the dispersion of individual МWCNTs occurs can be determined.

  9. Laboratory simulation of the influence of space debris particles on structural and functional materials

    NASA Astrophysics Data System (ADS)

    Novikov, Lev; Samokhina, Maria S.; Bednyakov, Sergey A.; Zhilyakov, Lev A.; Ermolaev, Igor K.

    This paper presents results of laboratory experiments to study the impact of Al, Cr, Ti particles with diameter of 0.5-10 mum and speed of 0.1-10 km/s as well as steel balls (d = 0.5-1.0 mm; v = 0.05-4 km/s) on the samples of spacecraft materials (aluminum alloys, glass, silicon, polymer films). Metal microparticles were accelerated by electrostatic method with a Van de Graaff generator and a cascade generator. Charging of microparticles was performed by the contact method in a special injector. Steel balls were accelerated with a gas gun. The data on configurations of crates formed in ductile and fragile targets by the microparticle impact are presented. For metallized polymer films, peculiarities of films damage due to the combined impact of atomic oxygen and of hard microparticles, were studied. The results of laboratory experiments are compared with the data obtained in experiments on International Space Station. In experiments with metal balls, the relationship between a crater volume and a kinetic energy of an incident particle was thoroughly investigated. A nonmonotonic dependence of the specific energy per crater unit volume on the incident particle velocity in the range of 0.05-0.6 km/s was obtained. The observed behavior of this dependence in the specific energy range of 0.1-2.5 J/mm3 was explained by the distinction of physical processes happening in the collision zone at different velocities. With increasing the collision velocity, there occurred a gradual transition from the elastic interaction to the plastic deformation with partial melting of the target at the highest velocities.

  10. Influence of excipients and processing conditions on the development of agglomerates of racecadotril by crystallo-co-agglomeration

    PubMed Central

    Garala, Kevin; Patel, Jaydeep; Patel, Anjali; Raval, Mihir; Dharamsi, Abhay

    2012-01-01

    Purpose: The purpose of the present investigation was to improve the flow and mechanical properties of racecadotril by a crystallo-co-agglomeration (CCA) technique. Direct tableting is a requirement of pharmaceutical industries. Poor mechanical properties of crystalline drug particles require wet granulation which is uneconomical, laborious, and tedious. Materials and Methods: The objective of this work was to study the influence of various polymers/excipients and processing conditions on the formation of directly compressible agglomerates of the water-insoluble drug, racecadotril, an antidiarrheal agent. The agglomerates of racecadotril were prepared using dichloromethane (DCM)–water as the crystallization system. DCM acted as a good solvent for racecadotril as well as a bridging liquid for the agglomeration of the crystallized drug and water as the nonsolvent. The prepared agglomerates were tested for micromeritic and mechanical properties. Results: The process yielded ~90 to 96% wt/ wt spherical agglomerates containing racecadotril with the diameter between 299 and 521 μ. A higher rotational speed of crystallization system reduces the size of the agglomerates and disturbs the sphericity. Spherical agglomerates were generated with a uniform dispersion of the crystallized drug. CCA showed excellent flowability and crushing strength. Conclusion: Excipients and processing conditions can play a key role in preparing spherical agglomerates of racecadotril by CCA, an excellent alternative to the wet granulation process to prepare intermediates for direct compression. PMID:23580935

  11. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; K. A. Lewandowski; J. A. Gurtler

    2006-09-30

    Heap leaching is one of the methods being used to recover metal from low grade ore deposits. The main problem faced during heap leaching is the migration of fine grained particles through the heap, forming impermeable beds which result in poor solution flow. The poor solution flow leads to less contact between the leach solution and the ore, resulting in low recovery rates. Agglomeration of ore into coarse, porous masses prevents fine particles from migrating and clogging the spaces and channels between the larger ore particles. Currently, there is one facility in the United States which uses agglomeration. This operation agglomerates their ore using leach solution (raffinate), but is still experiencing undesirable metal recovery from the heaps due to agglomerate breakdown. The use of a binder, in addition to the leach solution, during agglomeration would help to produce stronger agglomerates that did not break down during processing. However, there are no known binders that will work satisfactorily in the acidic environment of a heap, at a reasonable cost. As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. Increasing copper recovery in heap leaching by the use of binders and agglomeration would result in a significant decrease in the amount of energy consumed. Assuming that 70% of all the leaching heaps would convert to using agglomeration technology, as much as 1.64*10{sup 12} BTU per year would be able to be saved if a 25% increase in copper recovery was experienced, which is equivalent to saving approximately 18% of the energy currently being used in leaching heaps. For every week a leach cycle was decreased, a savings of as much as 1.23*10{sup 11} BTU per week would result. This project has identified several acid-resistant binders and agglomeration procedures. These binders and experimental procedures will be able to be used for use in improving the energy efficiency of

  12. Research approach and first results on agglomerate compaction in protoplanetary dust simulation in the Cloud Manipulation System

    NASA Astrophysics Data System (ADS)

    Vedernikov, Andrei; Blum, Jurgen; Ingo Von Borstel, Olaf; Schraepler, Rainer; Balapanov, Daniyar; Cecere, Anselmo

    2016-07-01

    Nanometre and micrometre-sized solid particles are ubiquitous in space and on Earth - from galaxies, interstellar space, protoplanetary and debris disks to planetary rings and atmospheres, planetary surfaces, comets, interplanetary space, Earth's atmosphere. Apparently, the most intriguing problem in the picture of the formation of planets is the transition from individual microscopic dust grains to kilometre-sized planetesimals. Revealing the mechanisms of this transition is one of the main tasks of the European Space Agency's project Interaction in Cosmic and Atmospheric Particle Systems (ICAPS). It was found that Brownian motion driven agglomeration could not provide the transition within reasonable time scale. As a result, at this stage top scientific goals shifted towards forced agglomeration and concentration of particles, targeting revealing the onset of compaction, experimental study of the evolution of fractal dimensions, size and mass distribution, occurrence of bouncing. The main tasks comprise 1) development of the rapid agglomeration model 2) development of the experimental facilities creating big fractal-type agglomerates from 10 to 1000 μm from a cloud of micrometre-size grains; 3) experimental realization of the rapid agglomeration in microgravity and ground conditions; and 4) in situ investigation of the morphology, mobility, mechanical and optical properties of the free-floating agglomerates, including investigation of thermophoresis, photophoresis of the agglomerates and of the two-phase flow phenomena. To solve the experimental part of the tasks we developed a Cloud Manipulation System, realized as a breadboard (CMS BB) for long duration microgravity platforms and a simplified laboratory version (CMS LV) mostly oriented on short duration microgravity and ground tests. The new system is based on the use of thermophoresis, most favourable for cloud manipulation without creating additional particle-particle forces in the cloud with a possibility

  13. Percolative fragmentation and spontaneous agglomeration

    SciTech Connect

    Hurt, R.; Davis, K.

    1999-03-01

    Captive particle imaging experiments were performed on over 200 coal and char particles in the pulverized size range from four coals of various rank at oxygen concentration from 3--19 mol% and at gas temperatures of about 1250 K. Despite wide variations in single-particle behavior, the data set reveals two clear trends that provide new information on the nature of char combustion. First, the low-rank coal chars are observed to maintain their high reactivity through the late stages of combustion, thus avoiding the near-extinction events and long burnout tails observed for bituminous coal chars. Secondly, percolative fragmentation in the late stages of combustion is a rare event under these conditions. Some particles reach a percolation threshold rate in combustion, but typically undergo spontaneous agglomeration rather than liberation of the incipient fragments. It is concluded that percolative fragmentation behavior in the pulverized size range is determined not only by solid-phase connectivity, but also by a real competition between disruptive and cohesive forces present at the time of formation of the colloidal-sized incipient fragments.

  14. Effects of coarse grain size distribution and fine particle content on pore fluid pressure and shear behavior in experimental debris flows

    NASA Astrophysics Data System (ADS)

    Kaitna, Roland; Palucis, Marisa C.; Yohannes, Bereket; Hill, Kimberly M.; Dietrich, William E.

    2016-02-01

    Debris flows are typically a saturated mixture of poorly sorted particles and interstitial fluid, whose density and flow properties depend strongly on the presence of suspended fine sediment. Recent research suggests that grain size distribution (GSD) influences excess pore pressures (i.e., pressure in excess of predicted hydrostatic pressure), which in turn plays a governing role in debris flow behaviors. We report a series of controlled laboratory experiments in a 4 m diameter vertically rotating drum where the coarse particle size distribution and the content of fine particles were varied independently. We measured basal pore fluid pressures, pore fluid pressure profiles (using novel sensor probes), velocity profiles, and longitudinal profiles of the flow height. Excess pore fluid pressure was significant for mixtures with high fines fraction. Such flows exhibited lower values for their bulk flow resistance (as measured by surface slope of the flow), had damped fluctuations of normalized fluid pressure and normal stress, and had velocity profiles where the shear was concentrated at the base of the flow. These effects were most pronounced in flows with a wide coarse GSD distribution. Sustained excess fluid pressure occurred during flow and after cessation of motion. Various mechanisms may cause dilation and contraction of the flows, and we propose that the sustained excess fluid pressures during flow and once the flow has stopped may arise from hindered particle settling and yield strength of the fluid, resulting in transfer of particle weight to the fluid. Thus, debris flow behavior may be strongly influenced by sustained excess fluid pressures controlled by particle settling rates.

  15. Selective oil agglomeration of lignite

    SciTech Connect

    Halime Abakay Temel; Volkan Bozkurt; Arun Kumar Majumder

    2009-01-15

    In this study, desulfurization and deashing of Adiyaman-Glbai lignite by the agglomeration method were studied. For this purpose, three groups of agglomeration experiments were made. The effects of solid concentration, bridging liquid type and dosage, pH, and screen size on the agglomeration after desliming were investigated in the first group of experiments. The effects of lake water and sea water (the Mediterranean Sea water, the Aegean Sea water, and the Black Sea water) on the agglomeration were investigated in the second group of experiments. The effects of different salts (NaCl, MgCl{sub 2}, and FeCl{sub 3}) on the agglomeration were investigated in the third group of experiments. Agglomeration results showed that the usage of sea waters and soda lake water in the agglomeration medium had a positive effect on the reduction of total sulfur content of agglomerates. In addition, the usage of NaCl, MgCl{sub 2}, and FeCl{sub 3} in the agglomeration medium had a positive effect on the ash content reduction of the agglomerates. 27 refs., 10 figs., 6 tabs.

  16. Smoothed particle hydrodynamic modeling of volcanic debris flows: Application to Huiloac Gorge lahars (Popocatépetl volcano, Mexico)

    NASA Astrophysics Data System (ADS)

    Haddad, Bouchra; Palacios, David; Pastor, Manuel; Zamorano, José Juan

    2016-09-01

    Lahars are among the most catastrophic volcanic processes, and the ability to model them is central to mitigating their effects. Several lahars recently generated by the Popocatépetl volcano (Mexico) moved downstream through the Huiloac Gorge towards the village of Santiago Xalitzintla. The most dangerous was the 2001 lahar, in which the destructive power of the debris flow was maintained throughout the extent of the flow. Identifying the zone of hazard can be based either on numerical or empirical models, but a calibration and validation process is required to ensure hazard map quality. The Geoflow-SPH depth integrated numerical model used in this study to reproduce the 2001 lahar was derived from the velocity-pressure version of the Biot-Zienkiewicz model, and was discretized using the smoothed particle hydrodynamics (SPH) method. The results of the calibrated SPH model were validated by comparing the simulated deposit depth with the field depth measured at 16 cross sections distributed strategically along the gorge channel. Moreover, the dependency of the results on topographic mesh resolution, initial lahar mass shape and dimensions is also investigated. The results indicate that to accurately reproduce the 2001 lahar flow dynamics the channel topography needed to be discretized using a mesh having a minimum 5 m resolution, and an initial lahar mass shape that adopted the source area morphology. Field validation of the calibrated model showed that there was a satisfactory relationship between the simulated and field depths, the error being less than 20% for 11 of the 16 cross sections. This study demonstrates that the Geoflow-SPH model was able to accurately reproduce the lahar path and the extent of the flow, but also reproduced other parameters including flow velocity and deposit depth.

  17. SPECS: Orbital debris removal

    NASA Technical Reports Server (NTRS)

    1991-01-01

    The debris problem has reached a stage at which the risk to satellites and spacecraft has become substantial in low Earth orbit (LEO). This research discovered that small particles posed little threat to spacecraft because shielding can effectively prevent these particles from damaging the spacecraft. The research also showed that, even though collision with a large piece of debris could destroy the spacecraft, the large pieces of debris pose little danger because they can be tracked and the spacecraft can be maneuvered away from these pieces. Additionally, there are many current designs to capture and remove large debris particles from the space environment. From this analysis, it was decided to concentrate on the removal of medium-sized orbital debris, that is, those pieces ranging from 1 cm to 50 cm in size. The current design incorporates a transfer vehicle and a netting vehicle to capture the medium-sized debris. The system is based near an operational space station located at 28.5 deg inclination and 400 km altitude. The system uses ground-based tracking to determine the location of a satellite breakup or debris cloud. These data are uploaded to the transfer vehicle, which proceeds to rendezvous with the debris at a lower altitude parking orbit. Next, the netting vehicle is deployed, tracks the targeted debris, and captures it. After expending the available nets, the netting vehicle returns to the transfer vehicle for a new netting module and continues to capture more debris in the target area. Once all the netting modules are expended, the transfer vehicle returns to the space station's orbit where it is resupplied with new netting modules from a space shuttle load. The new modules are launched by the shuttle from the ground and the expended modules are taken back to Earth for removal of the captured debris, refueling, and repacking of the nets. Once the netting modules are refurbished, they are taken back into orbit for reuse. In a typical mission, the

  18. Magnetic agglomeration method for size control in the synthesis of magnetic nanoparticles

    DOEpatents

    Huber, Dale L.

    2011-07-05

    A method for controlling the size of chemically synthesized magnetic nanoparticles that employs magnetic interaction between particles to control particle size and does not rely on conventional kinetic control of the reaction to control particle size. The particles are caused to reversibly agglomerate and precipitate from solution; the size at which this occurs can be well controlled to provide a very narrow particle size distribution. The size of particles is controllable by the size of the surfactant employed in the process; controlling the size of the surfactant allows magnetic control of the agglomeration and precipitation processes. Agglomeration is used to effectively stop particle growth to provide a very narrow range of particle sizes.

  19. THE PHYSICS OF PROTOPLANETESIMAL DUST AGGLOMERATES. VII. THE LOW-VELOCITY COLLISION BEHAVIOR OF LARGE DUST AGGLOMERATES

    SciTech Connect

    Schraepler, Rainer; Blum, Juergen; Seizinger, Alexander; Kley, Wilhelm

    2012-10-10

    We performed micro-gravity collision experiments in our laboratory drop tower using 5 cm sized dust agglomerates with volume filling factors of 0.3 and 0.4, respectively. This work is an extension of our previous experiments reported in Beitz et al. to aggregates of more than one order of magnitude higher masses. The dust aggregates consisted of micrometer-sized silica particles and were macroscopically homogeneous. We measured the coefficient of restitution for collision velocities ranging from 1 cm s{sup -1} to 0.5 m s{sup -1}, and determined the fragmentation velocity. For low velocities, the coefficient of restitution decreases with increasing impact velocity, in contrast to findings by Beitz et al. At higher velocities, the value of the coefficient of restitution becomes constant, before the aggregates break at the onset of fragmentation. We interpret the qualitative change in the coefficient of restitution as the transition from a solid-body-dominated to a granular-medium-dominated behavior. We complement our experiments by molecular-dynamics simulations of porous aggregates and obtain a reasonable match to the experimental data. We discuss the importance of our experiments for protoplanetary disks, debris disks, and planetary rings. This work is an extension to the previous work of our group and gives new insight into the velocity dependency of the coefficient of restitution due to improved measurements, better statistics, and a theoretical approach.

  20. Fragmentation and bond strength of airborne diesel soot agglomerates

    PubMed Central

    Rothenbacher, Sonja; Messerer, Armin; Kasper, Gerhard

    2008-01-01

    Background The potential of diesel soot aerosol particles to break up into smaller units under mechanical stress was investigated by a direct impaction technique which measures the degree of fragmentation of individual agglomerates vs. impact energy. Diesel aerosol was generated by an idling diesel engine used for passenger vehicles. Both the aerosol emitted directly and aerosol that had undergone additional growth by Brownian coagulation ("aging") was investigated. Optionally a thermo-desoption technique at 280°C was used to remove all high-volatility and the majority of low-volatility HC adsorbates from the aerosol before aging. Results It was found that the primary soot agglomerates emitted directly from the engine could not be fragmented at all. Soot agglomerates permitted to grow additionally by Brownian coagulation of the primary emitted particles could be fragmented to a maximum of 75% and 60% respectively, depending on whether adsorbates were removed from their surface prior to aging or not. At most, these aged agglomerates could be broken down to roughly the size of the agglomerates from the primary emission. The energy required for a 50% fragmentation probability of all bonds within an agglomerate was reduced by roughly a factor of 2 when aging "dry" agglomerates. Average bond energies derived from the data were 0.52*10-16 and 1.2*10-16 J, respectively. This is about 2 orders of magnitude higher than estimates for pure van-der-Waals agglomerates, but agrees quite well with other observations. Conclusion Although direct conclusions regarding the behavior of inhaled diesel aerosol in contact with body fluids cannot be drawn from such measurements, the results imply that highly agglomerated soot aerosol particles are unlikely to break up into units smaller than roughly the size distribution emitted as tail pipe soot. PMID:18533015

  1. Spectral Element Agglomerate AMGe

    SciTech Connect

    Chartier, T; Falgout, R; Henson, V E; Jones, J E; Vassilevski, P S; Manteuffel, T A; McCormick, S F; Ruge, J W

    2005-05-20

    The purpose of this note is to describe an algorithm resulting from the uniting of two ideas introduced and applied elsewhere. For many problems, AMG has always been difficult due to complexities whose natures are difficult to discern from the entries of matrix A alone. Element-based interpolation has been shown to be an effective method for some of these problems, but it requires access to the element matrices on all levels. One way to obtain these has been to perform element agglomeration to form coarse elements, but in complicated situations defining the coarse degrees of freedom (dofs) is not easy. The spectral approach to coarse dof selection is very attractive due to its elegance and simplicity. The algorithm presented here combines the robustness of element interpolation, the ease of coarsening by element agglomeration, and the simplicity of defining coarse dofs through the spectral approach. As demonstrated in the numerical results, the method does yield a reasonable solver for the problems described. It can, however, be an expensive method due to the number and cost of the local, small dense linear algebra problems; making it a generally competitive method remains an area for further research.

  2. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; J. A. Gurtler; K. Lewandowski

    2005-09-30

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily at a reasonable cost. A primary example of this is copper heap leaching, where there are no binders currently encountered in this acidic environment process. As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching. The active involvement of our industrial partners will help to ensure rapid commercialization of any agglomeration technologies developed by this project.

  3. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; K. A. Lewandowski; J. A. Gurtler

    2006-03-31

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily at a reasonable cost. A primary example of this is copper heap leaching, where there are no binders currently encountered in this acidic environment process. As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching. The active involvement of our industrial partners will help to ensure rapid commercialization of any agglomeration technologies developed by this project.

  4. Antioxidant Impregnated Ultra-High Molecular Weight Polyethylene Wear Debris Particles Display Increased Bone Remodeling and a Superior Osteogenic:Osteolytic Profile vs. Conventional UHMWPE Particles in a Murine Calvaria Model

    PubMed Central

    Chen, Yu; Hallab, Nadim J.; Liao, Yen-Shuo; Narayan, Venkat; Schwarz, Edward M.; Xie, Chao

    2015-01-01

    Periprosthetic osteolysis remains a major limitation of long-term successful total hip replacements with ultra-high molecular weight polyethylene (UHMWPE) bearings. As intra and extracellular reactive oxygen species are know to contribute to wear debris-induced osteoclastic bone resorption and decreased osteoblastic bone formation, antioxidant doped UHMWPE has emerged as an approach to reduce the osteolytic potential of wear debris and maintain coupled bone remodeling. To test this hypothesis in vivo, we evaluated the effects of crosslinked UHMWPE wear debris particles (AltrX™), versus similar wear particles made from COVERNOX™ containing UHMWPE (AOX™), in an established murine calvaria model. Eight-week-old female C57B/6 mice (n=10/Group) received a pre-op micro-CT scan prior to surgical implantation of the UHMWPE particles (2mg), or surgery without particles (sham). Dynamic labeling was performed by intraperitoneal injection of calcein on day 7 and alizarin on day 9, and the calvaria were harvested for micro-CT and histology on day 10. Surprisingly, we found that AOX particles induced significantly more bone resorption (1.72-fold) and osteoclast numbers (1.99-fold) vs. AltrX (p<0.001). However, AOX also significantly induced 1.64-fold more new bone formation vs. AltrX (p<0.01). Moreover, while the osteolytic:osteogenic ratio of both particles was very close to 1.0, which is indicative of coupled remodeling, AOX was more osteogenic (Slope=1.13±0.10 vs. 0.97±0.10). Histomorphometry of the metabolically labeled undecalcified calvaria revealed a consistent trend of greater MAR in AOX vs. AltrX. Collectively, these results demonstrate that anti-oxidant impregnated UHMWPE particles have decreased osteolytic potential due to their increased osteogenic properties that support coupled bone remodeling. PMID:26495749

  5. Ultrasonic de-agglomeration of barium titanate powder.

    PubMed

    Marković, S; Mitrić, M; Starcević, G; Uskoković, D

    2008-01-01

    BaTiO3 (BT) powder, with average particle size of 1.4 microm, was synthesized by solid-state reaction. A high-intensity ultrasound irradiation (ultrasonication) was used to de-agglomerate micro-sized powder to nano-sized one. The crystal structure, crystallite size, morphology, particle size, particle size distribution, and specific surface area of the BT powder de-agglomerated for different ultrasonication times (0, 10, 60, and 180 min) were determined. It was found that the particles size of the BT powder was influenced by ultrasonic treatment, while its tetragonal structure was maintained. Therefore, ultrasonic irradiation can be proposed as an environmental-friendly, economical, and effective tool for the de-agglomeration of barium titanate powders. PMID:17845864

  6. Space Debris & its Mitigation

    NASA Astrophysics Data System (ADS)

    Kaushal, Sourabh; Arora, Nishant

    2012-07-01

    : In this technique we will use the nano tubes. We will create a mesh that will act as a touch panel of the touch screen cell phone. When any small or tiny particle will come on this mesh and touch it then the mesh will act as a touch panel and so that the corresponding processor or sensor will come to know the co-ordinates of it then further by using Destructive laser beam we can destroy that particle. B. Use of the Nano tubes and Nano Bots for the collection of the Space Debris: In this method also we will use a nano mesh which is made up of the nano tubes and the corresponding arrangement will be done so that that mesh will act as a touch panel same as that of the touch screen phones. So when tiny particles will dash on the nano mesh then the Nano Bots which will be at the specific co-ordinates collect the particles and store them into the garbage storage. C. Further the space Debris can be use for the other purposes too:- As we know that the space debris can be any tiny particle in the space. So instead of decomposing that particles or destroying it we can use those particles for the purpose of energy production by using the fuel cells, but for this the one condition is that the particle material should be capable of forming the ionize liquid or solution which can be successfully use in the fuel cell for energy production. But this is useful for only the big projects where in smallest amount of energy has also the great demand or value. D. RECYCLING OF SPACE DEBRIS The general idea of making space structures by recycling space debris is to capture the aluminum of the upper stages, melt it, and form it into new aluminum structures, perhaps by coating the inside of inflatable balloons, to make very large structures of thin aluminum shells. CONCLUSION Space debris has become the topic of great concern in recent years. Space debris creation can't be stopped completely but it can be minimized by adopting some measures. Many methods of space debris mitigation have been

  7. Development of a gas-promoted oil agglomeration process. Quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Wheelock, T.D.

    1995-12-31

    The preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal advanced in three major research areas. One area of research resulted in the development of a method for measuring the rate of agglomeration of dilute particle suspensions and using the method to relate the rate of agglomeration of coal particles to various key parameters. A second area of research led to the development of a method for monitoring a batch agglomeration process by measuring changes in agitator torque. With this method it was possible to show that the agglomeration of a concentrated coal particle suspension is triggered by the introduction of a small amount of gas. The method was also used in conjunction with optical microscopy to study the mechanism of agglomeration. A third area of research led to the discovery that highly hydrophobic particles in an aqueous suspension can be agglomerated by air alone.

  8. NOVEL BINDERS AND METHODS FOR AGGLOMERATION OF ORE

    SciTech Connect

    S.K. Kawatra; T.C. Eisele; J.A. Gurtler; C.A. Hardison; K. Lewandowski

    2004-04-01

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. Primary examples of this are copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process, and advanced ironmaking processes, where binders must function satisfactorily over an extraordinarily large range of temperatures (from room temperature up to over 1200 C). As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching and advanced primary ironmaking.

  9. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; J. A. Gurtler

    2004-03-31

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. A primary example of this is copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process. As a result, operators of acidic heap-leach facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of other agglomeration applications, particularly advanced primary ironmaking.

  10. NOVEL BINDERS AND METHODS FOR AGGLOMERATION OF ORE

    SciTech Connect

    S.K. Kawatra; T.C. Eisele; J.A. Gurtler; K. Lewandowski

    2005-04-01

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not breakdown during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. Primary examples of this are copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process. As a result, operators of many facilities see large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching.

  11. Hydrophobic Agglomeration of Mineral Fines in Aqueous Suspensions and its Application in Flotation: a Review

    NASA Astrophysics Data System (ADS)

    Yang, Bingqiao; Song, Shaoxian

    2014-05-01

    Hydrophobic agglomeration is originated from the hydrophobic attraction between particles, which is essentially different from electrolyte coagulation and polymer flocculation. It is applied to mineral processing in floc-flotation process to improve the recovery of mineral fines. In this paper, the applications of this phenomenon in mineral fines were summarized, including the origin of hydrophobic agglomeration, the main factors affect hydrophobic agglomeration (particle hydrophobicity, shear rate and duration, nonpolar oil and tank geometry), as well as hydrophobic agglomeration based separation processes (carrier flotation and floc-flotation).

  12. Acoustic agglomeration of power plant fly ash. Final report

    SciTech Connect

    Reethof, G.; McDaniel, O.H.

    1982-01-01

    The work has shown that acoustic agglomeration at practical acoustic intensities and frequencies is technically and most likely economically viable. The following studies were performed with the listed results: The physics of acoustic agglomeration is complex particularly at the needed high acoustic intensities in the range of 150 to 160 dB and frequencies in the 2500 Hz range. The analytical model which we developed, although not including nonlinear acoustic efforts, agreed with the trends observed. We concentrated our efforts on clarifying the impact of high acoustic intensities on the generation of turbulence. Results from a special set of tests show that although some acoustically generated turbulence of sorts exists in the 150 to 170 dB range with acoustic streaming present, such turbulence will not be a significant factor in acoustic agglomeration compared to the dominant effect of the acoustic velocities at the fundamental frequency and its harmonics. Studies of the robustness of the agglomerated particles using the Anderson Mark III impactor as the source of the shear stresses on the particles show that the agglomerates should be able to withstand the rigors of flow through commercial cyclones without significant break-up. We designed and developed a 700/sup 0/F tubular agglomerator of 8'' internal diameter. The electrically heated system functioned well and provided very encouraging agglomeration results at acoustic levels in the 150 to 160 dB and 2000 to 3000 Hz ranges. We confirmed earlier results that an optimum frequency exists at about 2500 Hz and that larger dust loadings will give better results. Studies of the absorption of acoustic energy by various common gases as a function of temperature and humidity showed the need to pursue such an investigation for flue gas constituents in order to provide necessary data for the design of agglomerators. 65 references, 56 figures, 4 tables.

  13. Orbital Debris

    NASA Technical Reports Server (NTRS)

    Kessler, D. J. (Compiler); Su, S. Y. (Compiler)

    1985-01-01

    Earth orbital debris issues and recommended future activities are discussed. The workshop addressed the areas of environment definition, hazards to spacecraft, and space object management. It concluded that orbital debris is a potential problem for future space operations. However, before recommending any major efforts to control the environment, more data are required. The most significant required data are on the population of debris smaller than 4 cm in diameter. New damage criteria are also required. When these data are obtained, they can be combined with hypervelocity data to evaluate the hazards to future spacecraft. After these hazards are understood, then techniques to control the environment can be evaluated.

  14. Recent Advances in Agglomerated Multigrid

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.; Hammond, Dana P.

    2013-01-01

    We report recent advancements of the agglomerated multigrid methodology for complex flow simulations on fully unstructured grids. An agglomerated multigrid solver is applied to a wide range of test problems from simple two-dimensional geometries to realistic three- dimensional configurations. The solver is evaluated against a single-grid solver and, in some cases, against a structured-grid multigrid solver. Grid and solver issues are identified and overcome, leading to significant improvements over single-grid solvers.

  15. Compression behavior of porous dust agglomerates

    NASA Astrophysics Data System (ADS)

    Seizinger, A.; Speith, R.; Kley, W.

    2012-05-01

    Context. The early planetesimal growth proceeds through a sequence of sticking collisions of dust agglomerates. Very uncertain is still the relative velocity regime in which growth rather than destruction can take place. The outcome of a collision depends on the bulk properties of the porous dust agglomerates. Aims: Continuum models of dust agglomerates require a set of material parameters that are often difficult to obtain from laboratory experiments. Here, we aim at determining those parameters from ab initio molecular dynamics simulations. Our goal is to improve on the existing model that describe the interaction of individual monomers. Methods: We use a molecular dynamics approach featuring a detailed micro-physical model of the interaction of spherical grains. The model includes normal forces, rolling, twisting and sliding between the dust grains. We present a new treatment of wall-particle interaction that allows us to perform customized simulations that directly correspond to laboratory experiments. Results: We find that the existing interaction model by Dominik & Tielens leads to a too soft compressive strength behavior for uni- and omni-directional compression. Upon making the rolling and sliding coefficients stiffer we find excellent agreement in both cases. Additionally, we find that the compressive strength curve depends on the velocity with which the sample is compressed. Conclusions: The modified interaction strengths between two individual dust grains will lead to a different behavior of the whole dust agglomerate. This will influences the sticking probabilities and hence the growth of planetesimals. The new parameter set might possibly lead to an enhanced sticking as more energy can be stored in the system before breakup.

  16. Development of a gas-promoted oil agglomeration process: Air-promoted oil agglomeration of moderately hydrophobic coals. 2: Effect of air dosage in a model mixing system

    SciTech Connect

    Drzymala, J.; Wheelock, T.D.

    1996-07-01

    In a selective oil agglomeration process for cleaning coal, fine-size particles are suspended in water and treated with a water-immiscible hydrocarbon which can range from pentane to heavy fuel oil. Vigorous agitation is applied to disperse the oil and to produce frequent contacts between oil-coated particles. In Part 1 of this series of papers, it was shown that a definite amount of air had to be present in a laboratory mixing unit which produced a moderate shear rate in order to form compact, spherical agglomerates in an aqueous suspension of moderately hydrophobic coal using heptane or hexadecane as an agglomerate. In this paper, the effects of different amounts of air including dissolved air are discussed. The results indicate that a small amount of air will trigger the process of agglomeration, and even the air dissolved in water under equilibrium conditions at room temperature and pressure is sufficient to promote agglomeration provided it is released from solution.

  17. Effect of calcium ions on agglomeration of bayer aluminium trihydroxide

    NASA Astrophysics Data System (ADS)

    Brown, N.

    1988-10-01

    Small amounts of calcium ions in caustic aluminate solution can lead to enhanced agglomeration of aluminium trihydroxide [Al(OH) 3] particles in the crystallization step of the Bayer process. The present study shows that the magnitude of the effect is strongly dependent on the nature and polycrystallinity of the Al(OH) 3 seed crystals. The more irregular and polycrystalline the seed crystals, the smaller is the optimum amount of added calcium for maximum coarsening ( ≈ 50 mg/l, expressed as CaO). While the same degree of agglomeration can be achieved using well-rounded, smooth-surfaced seed crystals of the same overall size, more calcium is required (75-100 mg/l, expressed as CaO) and the agglomerated particles formed are weaker and less resistant to size reduction on handling.

  18. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; K. A. Lewandowski; J. A. Gurtler

    2006-12-31

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. Primary examples of this are copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process, and advanced ironmaking processes, where binders must function satisfactorily over an extraordinarily large range of temperatures (from room temperature up to over 1200 C). As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching and advanced primary ironmaking. This project has identified several acid-resistant binders and agglomeration procedures that can be used for improving the energy efficiency of heap leaching, by preventing the ''ponding'' and ''channeling'' effects that currently cause reduced recovery and extended leaching cycle times. Methods have also been developed for iron ore processing which are intended to improve the

  19. Antioxidant impregnated ultra-high molecular weight polyethylene wear debris particles display increased bone remodeling and a superior osteogenic:osteolytic profile vs. conventional UHMWPE particles in a murine calvaria model.

    PubMed

    Chen, Yu; Hallab, Nadim J; Liao, Yen-Shuo; Narayan, Venkat; Schwarz, Edward M; Xie, Chao

    2016-05-01

    Periprosthetic osteolysis remains a major limitation of long-term successful total hip replacements with ultra-high molecular weight polyethylene (UHMWPE) bearings. As intra and extracellular reactive oxygen species are know to contribute to wear debris-induced osteoclastic bone resorption and decreased osteoblastic bone formation, antioxidant doped UHMWPE has emerged as an approach to reduce the osteolytic potential of wear debris and maintain coupled bone remodeling. To test this hypothesis in vivo, we evaluated the effects of crosslinked UHMWPE wear debris particles (AltrX(™) ), versus similar wear particles made from COVERNOX(™) containing UHMWPE (AOX(™) ), in an established murine calvaria model. Eight-week-old female C57B/6 mice (n = 10/Group) received a pre-op micro-CT scan prior to surgical implantation of the UHMWPE particles (2mg), or surgery without particles (sham). Dynamic labeling was performed by intraperitoneal injection of calcein on day 7 and alizarin on day 9, and the calvaria were harvested for micro-CT and histology on day 10. Surprisingly, we found that AOX particles induced significantly more bone resorption (1.72-fold) and osteoclast numbers (1.99-fold) vs. AltrX (p < 0.001). However, AOX also significantly induced 1.64-fold more new bone formation vs. AltrX (p < 0.01). Moreover, while the osteolytic:osteogenic ratio of both particles was very close to 1.0, which is indicative of coupled remodeling, AOX was more osteogenic (Slope = 1.13 ± 0.10 vs. 0.97 ± 0.10). Histomorphometry of the metabolically labeled undecalcified calvaria revealed a consistent trend of greater MAR in AOX vs. AltrX. Collectively, these results demonstrate that anti-oxidant impregnated UHMWPE particles have decreased osteolytic potential due to their increased osteogenic properties that support coupled bone remodeling. © 2015 Orthopaedic Research Society. Published by Wiley Periodicals, Inc. J Orthop Res 34:845-851, 2016. PMID:26495749

  20. A pocket model for aluminum agglomeration in composite propellants

    NASA Technical Reports Server (NTRS)

    Cohen, N. S.

    1981-01-01

    This paper presents a model for the purpose of estimating the fraction of aluminum powder that will form agglomerates at the surface of deflagrating composite propellants. The basic idea is that the fraction agglomerated depends upon the amount of aluminum that melts within effective binder pocket volumes framed by oxidizer particles. The effective pocket depends upon the ability of ammonium perchlorate modals to encapsulate the aluminum and provide a local temperature sufficient to ignite the aluminum. Model results are discussed in the light of data showing effects of propellant formulation variables and pressure.

  1. Ice slurry cooling research: Storage tank ice agglomeration and extraction

    SciTech Connect

    Kasza, K.; Hayashi, Kanetoshi

    1999-08-01

    A new facility has been built to conduct research and development on important issues related to implementing ice slurry cooling technology. Ongoing studies are generating important information on the factors that influence ice particle agglomeration in ice slurry storage tanks. The studies are also addressing the development of methods to minimize and monitor agglomeration and improve the efficiency and controllability of tank extraction of slurry for distribution to cooling loads. These engineering issues impede the utilization of the ice slurry cooling concept that has been under development by various groups.

  2. Comparison of diffusion charging and mobility-based methods for measurement of aerosol agglomerate surface area

    PubMed Central

    Ku, Bon Ki; Kulkarni, Pramod

    2015-01-01

    We compare different approaches to measure surface area of aerosol agglomerates. The objective was to compare field methods, such as mobility and diffusion charging based approaches, with laboratory approach, such as Brunauer, Emmett, Teller (BET) method used for bulk powder samples. To allow intercomparison of various surface area measurements, we defined ‘geometric surface area’ of agglomerates (assuming agglomerates are made up of ideal spheres), and compared various surface area measurements to the geometric surface area. Four different approaches for measuring surface area of agglomerate particles in the size range of 60–350 nm were compared using (i) diffusion charging-based sensors from three different manufacturers, (ii) mobility diameter of an agglomerate, (iii) mobility diameter of an agglomerate assuming a linear chain morphology with uniform primary particle size, and (iv) surface area estimation based on tandem mobility–mass measurement and microscopy. Our results indicate that the tandem mobility–mass measurement, which can be applied directly to airborne particles unlike the BET method, agrees well with the BET method. It was also shown that the three diffusion charging-based surface area measurements of silver agglomerates were similar within a factor of 2 and were lower than those obtained from the tandem mobility–mass and microscopy method by a factor of 3–10 in the size range studied. Surface area estimated using the mobility diameter depended on the structure or morphology of the agglomerate with significant underestimation at high fractal dimensions approaching 3. PMID:26692585

  3. Low-rank coal oil agglomeration

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.

    1991-01-01

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  4. Basic principles and mechanisms of selective oil agglomeration

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.-C.; Tyson, D.; Xiaoping, Qiu; Lessa, A.

    1990-01-01

    Numerous measurements of the heat of immersion of coal were conducting using several different particle size fractions of No. 2 Gas Seam coal from Raleigh County, West Virginia. The heat of immersion was determined in water, methanol, heptane, hexadecane and neohexane (2,2-dimethybutane). A comparison of the results with those determined previously for Illinois No. 6 coal is discussed. A number of potential pyrite depressants for use in oil agglomeration of coal were screened by testing the response of sulfidized mineral pyrite to agglomeration with heptane in the presence of the potential depressant. The following were tested; sodium dithionite, sodium thiosulfate, ferrous sulfate, ferric sulfate, titanous chloride, hydrogen peroxide, Oxone (a form of potassium monopersulfate), pyrogallol, quebracho (colloidal dispersant derived from tree bark), milk whey, and several organic thiols. Ferric chloride was applied to mixtures of Upper Freeport coal and sulfidized mineral pyrite before subjecting the mixtures to agglomeration with heptane. 7 refs., 23 figs., 3 tabs.

  5. Hydroclimatic influence on particle size distribution of suspended sediments evacuated from debris-covered Chorabari Glacier, upper Mandakini catchment, central Himalaya

    NASA Astrophysics Data System (ADS)

    Kumar, Amit; Gokhale, Anupam Anand; Shukla, Tanuj; Dobhal, Dwarika Prasad

    2016-07-01

    Sediments released from high altitude glaciers exhibit varying evacuation patterns and transport characteristics owing to the presence of thick debris cover over the glacier. Despite the recent needs for integrated hydrometeorological studies in the Himalaya, little is known about the impacts of suspended sediment on hydropower generation, reservoir sedimentation, and abrasion of turbine components. Present study involves analysis of particle size distribution of suspended sediments to understand sediment evacuation patterns and transport characteristics in variable energy conditions during the ablation season. Peak suspended sediments were evacuated during extreme rainfall events. The estimated seasonal modern sediment erosion rate varies from 0.6 to 2.3 mm y- 1 for the study period (2009-2012). The analysis shows dominance of medium silt-sized to fine sand-sized particles having sediment size of 0.0156-0.25 mm corresponding to 70-80% without any significant seasonal variation. These transported sediments show that they are poorly sorted, coarser in nature with a nearly symmetrical to coarse skewed texture and kurtosis analysis suggesting mesokurtic distribution of sediments. The particle size fraction ranges between 4.65 and 5.23 ϕ, which is dominantly medium to coarse silty in texture. Results indicate that suspended sediments are evacuated in highly variable energy conditions through subglacial transport pathways because of increase in availability of meltwater with the progressive ablation season. Bulk geochemical characterization has been carried out to differentiate the source of suspended sediments and intensity of weathering. Chemical Index of Alterations (CIA) values of sediment flux range from 54.68 to 55.18 compared to the Upper Continental Crust (UCC) ~ 50, indicating moderate intensity of weathering. Mean seasonal (2009-2012) elemental fluxes and their contribution to the suspended sediment flux reflect that Si and Al are responsible for about 85% of

  6. Acoustic agglomeration of power-plant fly ash. A comprehensive semi-annual progress report

    SciTech Connect

    Reethof, G.

    1980-02-01

    Results obtained during the reporting period are presented. The agglomeration of submicron fly ash particles has been studied as a function of sound pressure level, sound frequency, loading, and exposure time. A second generation model of the agglomeration process is being developed. A high-frequency, high-intensity variable speed siren delivering at least 600 W at frequencies up to 4000 Hz has been developed and tested. Details on the design and operation are presented. The agglomeration chamber has been completely cleaned and the aerosol generating system has been rebuilt. A mathematical model of the acoustics of agglomeration is being developed. Preliminary results of computerized electron microscopic scanning of fly ash particles during agglomeration are presented. (DMC)

  7. Observations of debris flows at Chalk Cliffs, Colorado, USA: Part 1, in-situ measurements of flow dynamics, tracer particle movement and video imagery from the summer of 2009

    USGS Publications Warehouse

    McCoy, Scott W.; Coe, Jeffrey A.; Kean, Jason W.; Tucker, Greg E.; Staley, Dennis M.; Wasklewicz, Thad A.

    2011-01-01

    Debris flows initiated by surface-water runoff during short duration, moderate- to high-intensity rainfall are common in steep, rocky, and sparsely vegetated terrain. Yet large uncertainties remain about the potential for a flow to grow through entrainment of loose debris, which make formulation of accurate mechanical models of debris-flow routing difficult. Using a combination of in situ measurements of debris flow dynamics, video imagery, tracer rocks implanted with passive integrated transponders (PIT) and pre- and post-flow 2-cm resolution digital terrain models (terrain data presented in a companion paper by STALEY et alii, 2011), we investigated the entrainment and transport response of debris flows at Chalk Cliffs, CO, USA. Four monitored events during the summer of 2009 all initiated from surface-water runoff, generally less than an hour after the first measurable rain. Despite reach-scale morphology that remained relatively constant, the four flow events displayed a range of responses, from long-runout flows that entrained significant amounts of channel sediment and dammed the main-stem river, to smaller, short-runout flows that were primarily depositional in the upper basin. Tracer-rock travel-distance distributions for these events were bimodal; particles either remained immobile or they travelled the entire length of the catchment. The long-runout, large-entrainment flow differed from the other smaller flows by the following controlling factors: peak 10-minute rain intensity; duration of significant flow in the channel; and to a lesser extent, peak surge depth and velocity. Our growing database of natural debris-flow events can be used to develop linkages between observed debris-flow transport and entrainment responses and the controlling rainstorm characteristics and flow properties.

  8. Preparation and evaluation of agglomerated crystals by crystallo-co-agglomeration: an integrated approach of principal component analysis and Box-Behnken experimental design.

    PubMed

    Garala, Kevin C; Patel, Jaydeep M; Dhingani, Anjali P; Dharamsi, Abhay T

    2013-08-16

    Poor mechanical properties of crystalline drug particles require wet granulation technique for tablet production which is uneconomical, laborious, and tedious. The present investigation was aimed to improve flow and mechanical properties of racecadotril (RCD), a poorly water soluble antidiarrheal agent, by a crystallo-co-agglomeration (CCA) technique. The influence of various excipients and processing conditions on formation of directly compressible agglomerates of RCD was evaluated. Principal component analysis and Box-Behnken experimental design was implemented to optimize the agglomerates with good micromeritics and mechanical properties. The overall yield of the process was 88-98% with size of agglomerates between 351 and 1214 μm. Further, higher rotational speed reduced the size of agglomerates and disturbed sphericity. The optimized batch of agglomerates exhibited excellent flowability and crushing strength. The optimized batch of RCD agglomerates was characterized by fourier transform infrared spectroscopy, differential scanning calorimetry, powder X-ray diffractometry and gas chromatography which illustrated absence of drug-excipient interaction with minimal entrapment of residual solvent. Hence, it may be concluded that both excipients and processing conditions played a vital role to prepare spherical crystal agglomerates of RCD by CCA and it can be adopted as an excellent alternative to wet granulation. PMID:23684660

  9. Experimental study on static and impact strength of sintered agglomerates

    NASA Astrophysics Data System (ADS)

    Machii, Nagisa; Nakamura, Akiko M.

    2011-01-01

    Porous internal structure is common among small bodies in the planetary systems and possible range of porosity, strength, and scale of in-homogeneity is wide. Icy agglomerates, such as icy dust aggregates in the proto-planetary disks or icy re-accumulated bodies of fragments from impact disruption beyond snow-line would have stronger bulk strength once the component particles physically connect each other due to sintering. In this study, in order to get better understanding of impact disruption process of such bodies, we first investigated the critical tensile (normal) and bending (tangential) forces to break a single neck, the connected part of the sintered particles, using sintered dimer of macro glass particles of ˜5 mm in diameter. We found that the critical tensile force is proportional to the cross-section of the neck when the neck grows sufficiently larger than the surface roughness of the original particles. We also found that smaller force is required to break a neck when the force is applied tangentially to the neck than normally applied. Then we measured the bulk tensile strength of sintered glass agglomerates consisting of 90 particles and showed that the average tensile stress to break a neck of agglomerates in static loading is consistent with the measured value for dimers. Impact experiments with velocity from 40 to 280 m/s were performed for the sintered agglomerates with ˜40% porosity, of two different bulk tensile strengths. The size ratio of the beads to the target was 0.19. The energy density required to catastrophically break the agglomerate was shown to be much less than those required for previously investigated sintered glass beads targets with ˜40% porosity, of which the size of component bead is 10 -2 times smaller and the size ratio of the bead to target is also ˜10 -2 times smaller than the agglomerates in this study. This is probably due to much smaller number of necks for the stress wave to travel through the agglomerates and

  10. Adapting agglomeration techniques to today's needs

    SciTech Connect

    Brown, D.C.

    1984-07-01

    New industries and economic trends have created new problems and opportunities for which applications of agglomeration have been developed. These applications are presented and discussed briefly. The areas include sintering of finely divided ores, briquetting feed stocks, agglomerate forms for air pollution control, hazardous waste immobilization, briquetting solid fuels for energy conservation, manufacturing synfuel charges, biomass densification, and agglomerate forms for metallurgical coke.

  11. Biological response to prosthetic debris

    PubMed Central

    Bitar, Diana; Parvizi, Javad

    2015-01-01

    Joint arthroplasty had revolutionized the outcome of orthopaedic surgery. Extensive and collaborative work of many innovator surgeons had led to the development of durable bearing surfaces, yet no single material is considered absolutely perfect. Generation of wear debris from any part of the prosthesis is unavoidable. Implant loosening secondary to osteolysis is the most common mode of failure of arthroplasty. Osteolysis is the resultant of complex contribution of the generated wear debris and the mechanical instability of the prosthetic components. Roughly speaking, all orthopedic biomaterials may induce a universal biologic host response to generated wear débris with little specific characteristics for each material; but some debris has been shown to be more cytotoxic than others. Prosthetic wear debris induces an extensive biological cascade of adverse cellular responses, where macrophages are the main cellular type involved in this hostile inflammatory process. Macrophages cause osteolysis indirectly by releasing numerous chemotactic inflammatory mediators, and directly by resorbing bone with their membrane microstructures. The bio-reactivity of wear particles depends on two major elements: particle characteristics (size, concentration and composition) and host characteristics. While any particle type may enhance hostile cellular reaction, cytological examination demonstrated that more than 70% of the debris burden is constituted of polyethylene particles. Comprehensive understanding of the intricate process of osteolysis is of utmost importance for future development of therapeutic modalities that may delay or prevent the disease progression. PMID:25793158

  12. Biological response to prosthetic debris.

    PubMed

    Bitar, Diana; Parvizi, Javad

    2015-03-18

    Joint arthroplasty had revolutionized the outcome of orthopaedic surgery. Extensive and collaborative work of many innovator surgeons had led to the development of durable bearing surfaces, yet no single material is considered absolutely perfect. Generation of wear debris from any part of the prosthesis is unavoidable. Implant loosening secondary to osteolysis is the most common mode of failure of arthroplasty. Osteolysis is the resultant of complex contribution of the generated wear debris and the mechanical instability of the prosthetic components. Roughly speaking, all orthopedic biomaterials may induce a universal biologic host response to generated wear débris with little specific characteristics for each material; but some debris has been shown to be more cytotoxic than others. Prosthetic wear debris induces an extensive biological cascade of adverse cellular responses, where macrophages are the main cellular type involved in this hostile inflammatory process. Macrophages cause osteolysis indirectly by releasing numerous chemotactic inflammatory mediators, and directly by resorbing bone with their membrane microstructures. The bio-reactivity of wear particles depends on two major elements: particle characteristics (size, concentration and composition) and host characteristics. While any particle type may enhance hostile cellular reaction, cytological examination demonstrated that more than 70% of the debris burden is constituted of polyethylene particles. Comprehensive understanding of the intricate process of osteolysis is of utmost importance for future development of therapeutic modalities that may delay or prevent the disease progression. PMID:25793158

  13. Coal beneficiation by gas agglomeration

    DOEpatents

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  14. Diffusion-Limited Agglomeration and Defect Generation during Chemical Mechanical Planarization

    SciTech Connect

    Biswas, R.; Han, Y.; Karra, P.; Sherman, P.; Chandra, A.

    2008-06-06

    Chemical mechanical planarization (CMP) of copper involves removal of surface asperities with abrasive particles and polishing processes. This leads to copper-containing nanoparticles extruded into the solution. We model the diffusion-limited agglomeration (DLA) of such nanoparticles which can rapidly grow to large sizes. These large particles are detrimental because they can participate in polishing, causing scratches and surface defects during CMP. The agglomeration is much slower in the reaction-limited agglomeration process. Under realistic conditions the defect generation probability can increase significantly over time scales of {approx}10 to 20 min from DLA, unless prevented by slurry rejuvenation or process modification measures.

  15. D5 debris bed experiment-extended post-dryout observations of a UO/sub 2/-sodium particle bed. [In ACPR reactor

    SciTech Connect

    Gronager, J E

    1982-01-01

    The D5 experiment is the sixth in a series of debris bed coolability experiments. The principal objective of the experiment is to investigate debris bed behavior, for various sodium subcoolings, at temperatures exceeding 2100/sup 0/K. The experiment is scheduled for early February 1982.

  16. Segregation dynamics in debris flows

    NASA Astrophysics Data System (ADS)

    Hill, K. M.; Fei, M.

    2014-12-01

    Debris flows are massive flows consisting of mixtures of particles of different sizes and interstitial fluids such as water and mud. In sheared mixtures of different-sized (same density) particles, it is well known that larger particles tend to go up (toward the free surface), and the smaller particles, down, commonly referred to as the "Brazil-nut problem" or "kinetic sieving". When kinetic sieving fluxes are combined with advection in flows, they can give rise to a spectacular range of segregation patterns. These segregation / advection dynamics are recognized as playing a role in the coarsening of a debris flow front (its "snout") and the coarsening of the self-formed channel sides or levees. Since particle size distribution influences the flow dynamics including entrainment of bed materials, modeling segregation dynamics in debris flows is important for modeling the debris flows themselves. In sparser systems, the Brazil-nut segregation is well-modeled using kinetic theory applied to dissipative systems, where an underlying assumption involves random, uncorrelated collisions. In denser systems, where kinetic theory breaks down we have recently developed a new mixture model that demonstrates the segregation fluxes are driven by two effects associated with the kinetic stress or granular temperature (the kinetic energy associated with velocity fluctuations): (1) the difference between the partitioning of kinetic and contact stresses among the species in the mixture and (2) a kinetic stress gradient. Both model frameworks involve the temperature gradient as a driving force for segregation, but kinetic theory sends larger particles toward lower temperatures, and our mixture model sends larger particles away from lower temperatures. Which framework works under what conditions appears to depend on correlations in the flow such as those manifested in clusters and force chains. We discuss the application of each theoretical framework to representing segregation dynamics

  17. Nanosized rods agglomerates as a new approach for formulation of a dry powder inhaler

    PubMed Central

    Salem, HF; Abdelrahim, ME; Eid, K Abo; Sharaf, MA

    2011-01-01

    Background: Nanosized dry powder inhalers provide higher stability for poorly water-soluble drugs as compared with liquid formulations. However, the respirable particles must have a diameter of 1–5 μm in order to deposit in the lungs. Controlled agglomeration of the nanoparticles increases their geometric particle size so they can deposit easily in the lungs. In the lungs, they fall apart to reform nanoparticles, thus enhancing the dissolution rate of the drugs. Theophylline is a bronchodilator with poor solubility in water. Methods: Nanosized theophylline colloids were formed using an amphiphilic surfactant and destabilized using dilute sodium chloride solutions to form the agglomerates. Results: The theophylline nanoparticles thus obtained had an average particle size of 290 nm and a zeta potential of −39.5 mV, whereas the agglomerates were 2.47 μm in size with a zeta potential of −28.9 mV. The release profile was found to follow first-order kinetics (r2 > 0.96). The aerodynamic characteristics of the agglomerated nanoparticles were determined using a cascade impactor. The behavior of the agglomerate was significantly better than unprocessed raw theophylline powder. In addition, the nanoparticles and agglomerates resulted in a significant improvement in the dissolution of theophylline. Conclusion: The results obtained lend support to the hypothesis that controlled agglomeration strategies provide an efficient approach for the delivery of poorly water-soluble drugs into the lungs. PMID:21383856

  18. Nanoparticle agglomerates of fluticasone propionate in combination with albuterol sulfate as dry powder aerosols

    PubMed Central

    El-Gendy, Nashwa; Pornputtapitak, Warangkana; Berkland, Cory

    2015-01-01

    Particle engineering strategies remain at the forefront of aerosol research for localized treatment of lung diseases and represent an alternative for systemic drug therapy. With the hastily growing popularity and complexity of inhalation therapy, there is a rising demand for tailor-made inhalable drug particles capable of affording the most proficient delivery to the lungs and the most advantageous therapeutic outcomes. To address this formulation demand, nanoparticle agglomeration was used to develop aerosols of the asthma therapeutics, fluticasone or albuterol. In addition, a combination aerosol was formed by drying agglomerates of fluticasone nanoparticles in the presence of albuterol in solution. Powders of the single drug nanoparticle agglomerates or of the combined therapeutics possessed desirable aerodynamic properties for inhalation. Powders were efficiently aerosolized (~75% deposition determined by cascade impaction) with high fine particle fraction and rapid dissolution. Nanoparticle agglomeration offers a unique approach to obtain high performance aerosols from combinations of asthma therapeutics. PMID:21964203

  19. Noble Gas and Mineralogical Tracers of Interplanetary Dust Particles and Impact Debris in a Central Pacific Sediment Core

    NASA Astrophysics Data System (ADS)

    Darrah, T. H.; Poreda, R. J.

    2005-12-01

    Thirty-five deep ocean sediment samples from the Central Pacific sediment core LL-44 GPC-3 were examined for their noble gas composition and mineralogy. The samples spanned from 30 to 71 Ma in age, including the Cretaceous/Tertiary (K/T), Paleocene/Eocene (P/E), and Eocene/Oligocene (E/O) boundaries. From each bulk sediment sample, magnetic grains (5-200 μg/g; 1-20 μm diameter) were isolated and analyzed. Noble gas measurements determined the helium and neon isotopic compositions and the abundance of extra-terrestrial (ET) noble gases for the bulk and magnetic fractions. 3He/4He ratios of 3.1x10-4 and 20Ne/22Ne ratios of 9.96-12.62 are consistent with the SEP (solar energetic particle) signature seen in both zero-age magnetic grains (Z-MAG) from the central Pacific sediments and stratospheric interplanetary dust particles (IDPs). The isolated magnetic fraction typically consisted of less than 1% of the bulk sample while accounting for 3 to 10% of the bulk sediment 3He with a maximum of 40% at K/T boundary. The magnetic isolates revealed no significant differences of 3He/4He, 20Ne/22Ne, or (3He/20Ne)solar from the bulk GPC-3 sediments or Z-MAG grains. No temporal variation in He or Ne or anomalous gas signatures associated with the boundaries present within this time interval was observed. Scanning electron microscope analysis was utilized to determine the mineralogy of the magnetic isolates in an effort to distinguish between the continuous flux of interplanetary dust particles and the flux associated with major impact events. This information may also assist in determining the carrier phase of ET noble gases. Anomalously high Ni, Mg, Al, and Cr compositions combined with low or nonexistent abundances of titanium can distinguish extraterrestrial spinel grains from terrestrial spinel. The SEM analysis revealed stark contrasts in composition and morphology in the samples associated with the boundaries included in this study. A survey of ``background'' samples

  20. Agglomeration characteristics of river sand and wheat stalk ash mixture at high temperatures

    NASA Astrophysics Data System (ADS)

    Shang, Linlin; Li, Shiyuan; Lu, Qinggang

    2013-02-01

    The agglomeration characteristics of river sand and wheat stalk ash mixture at various temperatures are investigated using a muffle furnace. The surface structural changes, as well as the elemental makeup of the surface and cross-section of the agglomerates, are analyzed by polarized light microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray (EDX). Multi-phase equilibrium calculation is performed with FactSage in identifying the melting behavior of the river sand-wheat stalk ash mixture at high temperatures. No indication of agglomeration is detected below 850°C. At a temperature of 900-1000°C, however, obvious agglomeration is observed and the agglomerates solidify further as temperature increases. The presence of potassium and calcium enrichment causes the formation of a sticky sand surface that induces agglomeration. The main component of the agglomerate surface is K2O-CaO-SiO2, which melts at low temperatures. The formation of molten silicates causes particle cohesion. The main ingredient of the binding phase in the cross-section is K2O-SiO2-Na2O-Al2O3-CaO; the agglomeration is not the result of the melting behavior of wheat stalk ash itself but the comprehensive results of chemical reaction and the melting behavior at high temperatures. The multi-phase equilibrium calculations agree well with the experimental results.

  1. Behavior of tethered debris with flexible appendages

    NASA Astrophysics Data System (ADS)

    Aslanov, Vladimir S.; Yudintsev, Vadim V.

    2014-11-01

    Active exploration of the space leads to growth of a near-Earth space pollution. The frequency of the registered collisions of space debris with functional satellites highly increased during last 10 years. As a rule a large space debris can be observed from the Earth and catalogued, then it is possible to avoid collision with the active spacecraft. However every large debris is a potential source of a numerous small debris particles. To reduce debris population in the near Earth space the large debris should be removed from working orbits. The active debris removal technique is considered that intend to use a tethered orbital transfer vehicle, or a space tug attached by a tether to the space debris. This paper focuses on the dynamics of the space debris with flexible appendages. Mathematical model of the system is derived using the Lagrange formalism. Several numerical examples are presented to illustrate the mutual influence of the oscillations of flexible appendages and the oscillations of a tether. It is shown that flexible appendages can have a significant influence on the attitude motion of the space debris and the safety of the transportation process.

  2. Removal of orbital debris

    NASA Technical Reports Server (NTRS)

    Petro, Andrew J.; Talent, David L.

    1989-01-01

    The several methods presently identified for the reduction of orbital debris populations are broadly classifiable as either preventive or remedial, and fall within distinctive operational regimes. For all particles, (1) in the 250-2000-km altitude band, intelligent sweepers may be used; (2) for large objects, in the 80-250-km altitude band, orbital decay renders removal impractical; (3) for the 250-750-km altitude band, deorbit devices should be used; (4) for 750-2500-km altitude, OMV rendezvous for propulsive deorbit package attachment is foreseeable; and beyond 2500 km, (5) propulsive escape from earth orbit is required.

  3. Liquid bridge agglomeration: A fundamental approach to toner deinking

    SciTech Connect

    Snyder, B.A.; Berg, J.C. . Chemical Engineering Dept.)

    1994-05-01

    An alternative agglomeration technique for deinking toner-printed furnishes has been investigated. This technique requires only the addition of an immiscible hydrocarbon oil dispersed in water at dosages of approximately 1% by weight on fiber. The addition is made during repulping: the process appears to be effective at all temperatures of interest (23 C and 70 C are tested) and requires no surfactants or additional chemicals. The result of the oil addition is the agglomeration of the toner particles into spheres of 1 mm to 1 cm in size. These spheres contain the added oil which acts as a binder, holding the toner particles together by liquid bridges. The process is ineffective when the furnish contains highly sized fibers or starched paper, and future work seeks to address these crucial problems.

  4. Orbital debris sweeper and method

    NASA Technical Reports Server (NTRS)

    Petro, Andrew J. (Inventor)

    1991-01-01

    An orbital debris sweeper is provided for removing particles from orbit which otherwise may impact and damage an orbiting spacecraft. The debris sweeper includes a central sweeper core which carries a debris monitoring unit, and a plurality of large area impact panels rotatable about a central sweeper rotational axis. In response to information from the debris monitoring unit, a computer determines whether individual monitored particles preferably impact one of the rotating panels or pass between the rotating panels. A control unit extends or retracts one or more booms which interconnect the sweeper core and the panels to change the moment of inertia of the sweeper and thereby the rotational velocity of the rotating panels. According to the method of the present invention, the change in panel rotational velocity increases the frequency of particles which desirably impact one of the panels and are thereby removed from orbit, while large particles which may damage the impact panels pass between the trailing edge of one panel and the leading edge of the rotationally succeeding panel.

  5. Nanoparticle agglomeration in an evaporating levitated droplet for different acoustic amplitudes

    NASA Astrophysics Data System (ADS)

    Tijerino, Erick; Basu, Saptarshi; Kumar, Ranganathan

    2013-01-01

    Radiatively heated levitated functional droplets with nanosilica suspensions exhibit three distinct stages namely pure evaporation, agglomeration, and finally structure formation. The temporal history of the droplet surface temperature shows two inflection points. One inflection point corresponds to a local maximum and demarcates the end of transient heating of the droplet and domination of vaporization. The second inflection point is a local minimum and indicates slowing down of the evaporation rate due to surface accumulation of nanoparticles. Morphology and final precipitation structures of levitated droplets are due to competing mechanisms of particle agglomeration, evaporation, and shape deformation. In this work, we provide a detailed analysis for each process and propose two important timescales for evaporation and agglomeration that determine the final diameter of the structure formed. It is seen that both agglomeration and evaporation timescales are similar functions of acoustic amplitude (sound pressure level), droplet size, viscosity, and density. However, we show that while the agglomeration timescale decreases with initial particle concentration, the evaporation timescale shows the opposite trend. The final normalized diameter can be shown to be dependent solely on the ratio of agglomeration to evaporation timescales for all concentrations and acoustic amplitudes. The structures also exhibit various aspect ratios (bowls, rings, spheroids) which depend on the ratio of the deformation timescale (tdef) and the agglomeration timescale (tg). For tdef

  6. Effects of operating conditions on agglomeration and habit of paracetamol crystals in anti-solvent crystallization

    NASA Astrophysics Data System (ADS)

    Yu, Z. Q.; Tan, R. B. H.; Chow, P. S.

    2005-06-01

    Effects of agitation speed and feeding rate on agglomeration and habit of paracetamol crystals in anti-solvent crystallization from water-acetone mixture are reported. Water is used as anti-solvent and is added in a semi-batch manner to a baffled 1-l crystallizer equipped with a marine-type impeller. A simple new method to characterize agglomeration degree has been proposed. Results show that agglomeration degree of crystals depends on particle size and elevated agitation reduces agglomeration degree of big particles. Particle mean size exhibits a maximum with increasing agitation intensity in the range of 200-600 rpm, which is explained from the perspective of anti-solvent dispersion and crystal agglomeration/disruption. Agglomeration degree of products deteriorates with increasing feeding rate ranging from 1 to 20 g/min due to enhanced nucleation. Crystal habit changes when feeding rate is altered, mainly in the faces of [0 0 1] and [1 1 0]. Focused beam reflectance measurement (FBRM) was used to monitor indirectly the particle size distribution in situ. The data demonstrated that FBRM may potentially be used as a tool to control crystallization process.

  7. Combustion of metal agglomerates in a solid rocket core flow

    NASA Astrophysics Data System (ADS)

    Maggi, Filippo; Dossi, Stefano; DeLuca, Luigi T.

    2013-12-01

    The need for access to space may require the use of solid propellants. High thrust and density are appealing features for different applications, spanning from boosting phase to other service applications (separation, de-orbiting, orbit insertion). Aluminum is widely used as a fuel in composite solid rocket motors because metal oxidation increases enthalpy release in combustion chamber and grants higher specific impulse. Combustion process of metal particles is complex and involves aggregation, agglomeration and evolution of reacting particulate inside the core flow of the rocket. It is always stated that residence time should be enough in order to grant complete metal oxidation but agglomerate initial size, rocket grain geometry, burning rate, and other factors have to be reconsidered. New space missions may not require large rocket systems and metal combustion efficiency becomes potentially a key issue to understand whether solid propulsion embodies a viable solution or liquid/hybrid systems are better. A simple model for metal combustion is set up in this paper. Metal particles are represented as single drops trailed by the core flow and reacted according to Beckstead's model. The fluid dynamics is inviscid, incompressible, 1D. The paper presents parametric computations on ideal single-size particles as well as on experimental agglomerate populations as a function of operating rocket conditions and geometries.

  8. Target response to debris cloud incidence

    SciTech Connect

    Kipp, M.E.

    1993-07-01

    The extent of penetration and/or perforation of a target layer by a debris cloud, whose particle mass distribution and velocities were calculated from a previous impact, was determined with two computational approaches. First, the size of single or paired particles required for target perforation was calculated and compared with the largest particle expected based on the fragment size distribution in the debris cloud. A second approach used a three-dimensional shock-wave code to calculate the explicit interaction of individual particles in the debris cloud with the target. The cloud was represented by randomly locating the particles within an envelope, maintaining the mass and size distribution of the particles. This interaction of the cloud of particles produced target surface craters and penetration comparable to recovered witness plates from impact experiments.

  9. Low-rank coal oil agglomeration

    DOEpatents

    Knudson, C.L.; Timpe, R.C.

    1991-07-16

    A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

  10. Orbital debris-debris collision avoidance

    NASA Astrophysics Data System (ADS)

    Mason, James; Stupl, Jan; Marshall, William; Levit, Creon

    2011-11-01

    We focus on preventing collisions between debris and debris, for which there is no current, effective mitigation strategy. We investigate the feasibility of using a medium-powered (5 kW) ground-based laser combined with a ground-based telescope to prevent collisions between debris objects in low-Earth orbit (LEO). The scheme utilizes photon pressure alone as a means to perturb the orbit of a debris object. Applied over multiple engagements, this alters the debris orbit sufficiently to reduce the risk of an upcoming conjunction. We employ standard assumptions for atmospheric conditions and the resulting beam propagation. Using case studies designed to represent the properties (e.g. area and mass) of the current debris population, we show that one could significantly reduce the risk of nearly half of all catastrophic collisions involving debris using only one such laser/telescope facility. We speculate on whether this could mitigate the debris fragmentation rate such that it falls below the natural debris re-entry rate due to atmospheric drag, and thus whether continuous long-term operation could entirely mitigate the Kessler syndrome in LEO, without need for relatively expensive active debris removal.

  11. Nifedipine Nanoparticle Agglomeration as a Dry Powder Aerosol Formulation Strategy

    PubMed Central

    Plumley, Carl; Gorman, Eric M.; Munson, Eric J.; Berkland, Cory

    2009-01-01

    Efficient administration of drugs represents a leading challenge in pulmonary medicine. Dry powder aerosols are of great interest compared to traditional aerosolized liquid formulations in that they may offer improved stability, ease of administration, and simple device design. Particles 1–5 µm in size typically facilitate lung deposition. Nanoparticles may be exhaled as a result of their small size; however, they are desired to enhance the dissolution rate of poorly soluble drugs. Nanoparticles of the hypertension drug nifedipine were co-precipitated with stearic acid to form a colloid exhibiting negative surface charge. Nifedipine nanoparticle colloids were destabilized by using sodium chloride to disrupt the electrostatic repulsion between particles as a means to achieve the agglomerated nanoparticles of a controlled size. The aerodynamic performance of agglomerated nanoparticles was determined by cascade impaction. The powders were found to be well suited for pulmonary delivery. In addition, nanoparticle agglomerates revealed enhanced dissolution of the drug species suggesting the value of this formulation approach for poorly water soluble pulmonary medicines. Ultimately, nifedipine powders are envisioned as an approach to treat pulmonary hypertension. PMID:19015016

  12. Reversible or not? Distinguishing agglomeration and aggregation at the nanoscale.

    PubMed

    Sokolov, Stanislav V; Tschulik, Kristina; Batchelor-McAuley, Christopher; Jurkschat, Kerstin; Compton, Richard G

    2015-10-01

    Nanoparticles are prone to clustering either via aggregation (irreversible) or agglomeration (reversible) processes. It is exceedingly difficult to distinguish the two via conventional techniques such as dynamic light scattering (DLS), nanoparticle tracking analysis (NTA), or electron microscopy imaging (scanning electron microscopy (SEM), transmission electron microscopy (TEM)) as such techniques only generally confirm the presence of large particle clusters. Herein we develop a joint approach to tackle the issue of distinguishing between nanoparticle aggregation vs agglomeration by characterizing a colloidal system of Ag NPs using DLS, NTA, SEM imaging and the electrochemical nanoimpacts technique. In contrast to the conventional techniques which all reveal the presence of large clusters of particles, electrochemical nanoimpacts provide information regarding individual nanoparticles in the solution phase and reveal the presence of small nanoparticles (<30 nm) even in high ionic strength (above 0.5 M KCl) and allow a more complete analysis. The detection of small nanoparticles in high ionic strength media evidence the clustering to be a reversible process. As a result it is concluded that agglomeration rather than irreversible aggregation takes place. This observation is of general importance for all colloids as it provides a feasible analysis technique for a wide range of systems with an ability to distinguish subtly different processes. PMID:26352558

  13. Analyzing turbidity, suspended-sediment concentration, and particle-size distribution resulting from a debris flow on Mount Jefferson, Oregon, November 2006

    USGS Publications Warehouse

    Uhrich, Mark A.

    2010-01-01

    A debris flow and sediment torrent occurred on the flanks of Mt Jefferson in Oregon on November 6, 2006, inundating 150 acres of forest. The massive debris flow was triggered by a rock and snow avalanche from the Milk Creek glaciers and snowfields during the early onset of an intense storm originating near the Hawaiian Islands. The debris flow consisted of a heavy conglomerate of large boulders, cobbles, and coarse-grained sediment that was deposited at depths of up to 15 ft and within 3 mi of the glaciers, and a viscous slurry that deposited finer-grained sediments at depths of 0.5 to 3 ft. The muddy slurry coated standing trees within the lower reaches of Milk Creek as it moved downslope.

  14. Effects of baffle configuration and tank size on spherical agglomerates of dimethyl fumarate in a common stirred tank.

    PubMed

    Lin, Po Yen; Lee, Hung Lin; Chen, Chih Wei; Lee, Tu

    2015-11-30

    To pave the way for technology transfer and scale up of the spherical agglomeration (SA) process for dimethyl fumarate, effects of the US, European and Kawashima type baffles and 0.5, 2.0 and 10 L-sized common stirred tank were studied. It was found that the particle size distribution varied significantly. However, the size-related properties such as dissolution profile and flowability of agglomerates from the same size cut after sieving could remain unchanged. The interior structure-related properties such as particle density and mechanical property of agglomerates upon baffle change and scale up from the same size cut were decayed and the agglomerates could become denser and stronger by prolonged maturation time. To maintain the same size distribution, agglomerates from any batch could have been separated and classified by sieving and then blended back together artificially by the desired weight% of each cut. PMID:26417848

  15. Orbital Debris: A Chronology

    NASA Technical Reports Server (NTRS)

    Portree, Davis S. F. (Editor); Loftus, Joseph P., Jr. (Editor)

    1999-01-01

    This chronology covers the 37-year history of orbital debris concerns. It tracks orbital debris hazard creation, research, observation, experimentation, management, mitigation, protection, and policy. Included are debris-producing, events; U.N. orbital debris treaties, Space Shuttle and space station orbital debris issues; ASAT tests; milestones in theory and modeling; uncontrolled reentries; detection system development; shielding development; geosynchronous debris issues, including reboost policies: returned surfaces studies, seminar papers reports, conferences, and studies; the increasing effect of space activities on astronomy; and growing international awareness of the near-Earth environment.

  16. Preparation of sustained release matrix pellets by melt agglomeration in the fluidized bed: influence of formulation variables and modelling of agglomerate growth.

    PubMed

    Pauli-Bruns, Anette; Knop, Klaus; Lippold, Bernhard C

    2010-03-01

    The one-step preparation of sustained release matrix pellets, using a melting procedure in a fluidized bed apparatus, was tested in a 2(3) full factorial design of experiments, using microcrystalline wax as lipophilic binder, theophylline as model drug and talc as additional matrix forming agent. The three influence parameters were (A) size of binder particles, (B) fraction of theophylline in solid particles and (C) fraction of microcrystalline wax in formulation. The response variables were agglomerate size and size distribution, dissolution time, agglomerate crush resistance, sphericity, yield and porosity. Nearly spherical pellets comprising a smooth, closed surface could be obtained with the used method, exhibiting the hollow core typical for the immersion and layering mechanism. The reproducibility was very good concerning all responses. The size of agglomerates is proportional to the size of the binder particles, which serve as cores for pellet formation in the molten state in the fluidized bed. Additionally, the agglomerate size is influenced by the volume of the solid particles in relation to the binder particles, with more solid particles leading to larger agglomerates and vice versa. Dissolution times vary in a very wide range, resulting from the interplay between amount of drug in relation to the meltable matrix substance microcrystalline wax and the non-meltable matrix substance talc. The change of binder particle size does not lead to a structural change of the matrix; both dissolution times and porosity are not significantly altered. Agglomerate crush resistance is low due to the hollow core of the pellets. However, it is significantly increased if the volume fraction of microcrystalline wax in the matrix is high, which means that the matrix is mechanically better stabilized. A theoretical model has been established to quantitatively explain agglomerate growth and very good accordance of the full particle size distributions between predicted and

  17. Chemical and physicochemial properties of submicron aerosol agglomerates

    SciTech Connect

    Scripsick, R.C.; Ehrman, S.; Friedlander, S.K.

    1998-12-31

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory. The formation of nanometer-sized aerosol particles in a premixed methane flame from both solid-phase aerosol precursors and gas-phase precursors was investigated. Techniques were developed to determine the distribution of the individual chemical species as a function of agglomerate size by using inductively coupled plasma atomic emission spectroscopy (ICP-AES). To determine the distribution of chemical species both from particle to particle and within the particles on a nanometer scale, we used the analytical electron microscopy techniques of energy dispersive x-ray spectrometry (EDS) and electron energy loss spectrometry (EELS) coupled with transmission electron microscopy (TEM). The observed distribution of individual chemical species as a function of agglomerate size was linked to the material properties of the solid-phase precursors. For aerosol formed from gas-phase precursors by gas-to-particle conversion, the distribution of species on a manometer scale was found to correspond to the equilibrium phase distribution expected from equilibrium for the system at the flame temperatures.

  18. Flocculation, hydrophobic agglomeration and filtration of ultrafine coal

    NASA Astrophysics Data System (ADS)

    Yu, Zhimin

    In coal preparation plant circuits, fine coal particles are aggregated either by oil agglomeration or by flocculation. In a new hydrophobic agglomeration process, recently developed hydrophobic latices are utilized. While the selectivity of such aggregation processes determines the beneficiation results, the degree of aggregation has a strong effect on fine coal filtration. The aim of this research was to study the fundamentals and analyze the common grounds for these processes, including the potential effect of the coal surface properties. The selective flocculation tests, in which three types of coal, which differed widely in surface wettability, and three additives (hydrophobic latices, a semi-hydrophobic flocculant and a typical hydrophilic polyelectrolyte) were utilized, showed that coal wettability plays a very important role in selective flocculation. The abstraction of a hydrophobic latex on coal and silica revealed that the latex had a much higher affinity towards hydrophobic coal than to hydrophilic mineral matter. As a result, the UBC-1 hydrophobic latex flocculated only hydrophobic coal particles while the polyelectrolyte (PAM) flocculated all the tested coal samples and minerals, showing no selectivity in the fine coal beneficiation. The oil agglomeration was tested using kerosene emulsified with various surfactants (e.g. cationic, anionic and non-ionic). Surfactants enhance not only oil emulsification, hence reducing oil consumption (down to 0.25--0.5%), but also entirely change the electrokinetic properties of the droplets and affect the interaction energy between oil droplets and coal particles. Consequently, the results found in the course of the experimental work strongly indicate that even oxidized coals can be agglomerated if cationic surfactants are used to emulsify the oil. Oil agglomeration of the Ford-4 ultrafine coal showed that even at extremely low oil consumption (0.25 to 0.5%), a clean coal product with an ash content around 5% at over

  19. Report on orbital debris

    NASA Technical Reports Server (NTRS)

    1989-01-01

    The success of space endeavors depends upon a space environment sufficiently free of debris to enable the safe and dependable operation of spacecraft. An environment overly cluttered with debris would threaten the ability to utilize space for a wide variety of scientific, technological, military, and commercial purposes. Man made space debris (orbital debris) differs from natural meteoroids because it remains in earth orbit during its lifetime and is not transient through the space around the Earth. The orbital debris environment is considered. The space environment is described along with sources of orbital debris. The current national space policy is examined, along with ways to minimize debris generation and ways to survive the debris environment. International efforts, legal issues and commercial regulations are also examined.

  20. Debris exhaust system

    DOEpatents

    McBride, D.D.; Bua, D.; Domankevitz, Y.; Nishioka, N.

    1998-06-23

    A debris removal system removes debris from a work site by flowing fluid away from the work site toward the periphery of a structure. The fluid flow can be kept constant around the periphery so that debris is removed evenly. The structure can have a reduced cross section between the fluid inlet and the work site so that the resulting increased fluid velocity works to prevent debris from escaping. 9 figs.

  1. Debris exhaust system

    DOEpatents

    McBride, Donald D.; Bua, Dominic; Domankevitz, Yacov; Nishioka, Norman

    1998-01-01

    A debris removal system removes debris from a work site by flowing fluid away from the work site toward the periphery of a structure. The fluid flow can be kept constant around the periphery so that debris is removed evenly. The structure can have a reduced cross section between the fluid inlet and the work site so that the resulting increased fluid velocity works to prevent debris from escaping.

  2. Laser-induced agglomeration of gold nanoparticles dispersed in a liquid

    NASA Astrophysics Data System (ADS)

    Serkov, A. A.; Shcherbina, M. E.; Kuzmin, P. G.; Kirichenko, N. A.

    2015-05-01

    Dynamics of gold nanoparticles (NPs) ensemble in dense aqueous solution under exposure to picosecond laser radiation is studied both experimentally and theoretically. Properties of NPs are examined by means of transmission electron microscopy, optical spectroscopy, and size-measuring disk centrifuge. Theoretical investigation of NPs ensemble behavior is based on the analytical model taking into account collisions and agglomeration of particles. It is shown that in case of dense NPs colloidal solutions (above 1014 particles per milliliter) the process of laser fragmentation typical for nanosecond laser exposure turns into laser-induced agglomeration which leads to formation of the particles with larger sizes. It is shown that there is a critical concentration of NPs: at higher concentrations agglomeration rate increases tremendously. The results of mathematical simulation are in compliance with experimental data.

  3. On the Mechanism of Ultrasound-Driven Deagglomeration of Nanoparticle Agglomerates in Aluminum Melt

    NASA Astrophysics Data System (ADS)

    Kudryashova, Olga; Vorozhtsov, Sergey

    2016-05-01

    One of the promising directions in the technology of composite alloys with improved mechanical properties is reinforcement of the metallic matrix with nanopowders introduced in the liquid metal. Ultrasonic processing is known to significantly improve the introduction of submicrone particles to the metallic melt. This study focuses on the mechanisms of deagglomeration and wettability of such particles by the melt under the action of ultrasound. The suggested mechanism involves the penetration of the liquid metal into the pores and cracks of the agglomerates under the excess pressure created by imploding cavitation bubbles and further destruction of the agglomerate by the sound wave. The main dependences connecting the acoustic parameters and processing time with the physical and chemical properties of particles and the melt are obtained through analytical modeling. The mathematical description of the ultrasonic deagglomeration in liquid metal is presented; a dependence of the threshold intensity of ultrasound for the break-up of agglomerates on their size is reported.

  4. A Novel Equivalent Agglomeration Model for Heat Conduction Enhancement in Nanofluids

    NASA Astrophysics Data System (ADS)

    Sui, Jize; Zheng, Liancun; Zhang, Xinxin; Chen, Ying; Cheng, Zhengdong

    2016-01-01

    We propose a multilevel equivalent agglomeration (MEA) model in which all particles in an irregular cluster are treated as a new particle with equivalent volume, the liquid molecules wrapping the cluster and in the gaps are considered to assemble on the surface of new particle as mixing nanolayer (MNL), the thermal conductivity in MNL is assumed to satisfy exponential distribution. Theoretical predictions for thermal conductivity enhancement are highly in agreement with the classical experimental data. Also, we first try to employ TEM information quantitatively to offer probable reference agglomeration ratio (not necessary a very precise value) to just test rational estimations range by present model. The comparison results indicate the satisfactory priori agglomeration ratio estimations range from renovated model.

  5. A Novel Equivalent Agglomeration Model for Heat Conduction Enhancement in Nanofluids

    PubMed Central

    Sui, Jize; Zheng, Liancun; Zhang, Xinxin; Chen, Ying; Cheng, Zhengdong

    2016-01-01

    We propose a multilevel equivalent agglomeration (MEA) model in which all particles in an irregular cluster are treated as a new particle with equivalent volume, the liquid molecules wrapping the cluster and in the gaps are considered to assemble on the surface of new particle as mixing nanolayer (MNL), the thermal conductivity in MNL is assumed to satisfy exponential distribution. Theoretical predictions for thermal conductivity enhancement are highly in agreement with the classical experimental data. Also, we first try to employ TEM information quantitatively to offer probable reference agglomeration ratio (not necessary a very precise value) to just test rational estimations range by present model. The comparison results indicate the satisfactory priori agglomeration ratio estimations range from renovated model. PMID:26777389

  6. Bed material agglomeration during fluidized bed combustion

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  7. Debris Flows and Related Phenomena

    NASA Astrophysics Data System (ADS)

    Ancey, C.

    Torrential floods are a major natural hazard, claiming thousands of lives and millions of dollars in lost property each year in almost all mountain areas on the Earth. After a catastrophic eruption of Mount St. Helen in the USA in May 1980, water from melting snow, torrential rains from the eruption cloud, and water displaced from Spirit Lake mixed with deposited ash and debris to produce very large debris flows and cause extensive damage and loss of life [1]. During the 1985 eruption of Nevado del Ruiz in Colombia, more than 20,000 people perished when a large debris flow triggered by the rapid melting of snow and ice at the volcano summit, swept through the town of Armero [2]. In 1991, the eruption of Pinatubo volcano in the Philippines disperses more than 5 cubic kilometres of volcanic ash into surrounding valleys. Much of that sediment has subsequently been mobilised as debris flows by typhoon rains and has devastated more than 300 square kilometres of agricultural land. Even, in Eur opean countries, recent events that torrential floods may have very destructive effects (Sarno and Quindici in southern Italy in May 1998, where approximately 200 people were killed). The catastrophic character of these floods in mountainous watersheds is a consequence of significant transport of materials associated with water flows. Two limiting flow regimes can be distinguished. Bed load and suspension refer to dilute transport of sediments within water. This means that water is the main agent in the flow dynamics and that the particle concentration does not exceed a few percent. Such flows are typically two-phase flows. In contrast, debris flows are mas s movements of concentrated slurries of water, fine solids, rocks and boulders. As a first approximation, debris flows can be treated as one-phase flows and their flow properties can be studied using classical rheological methods. The study of debris flows is a very exciting albeit immature science, made up of disparate elements

  8. Transport and Deposition of Welding Fume Agglomerates in a Realistic Human Nasal Airway.

    PubMed

    Tian, Lin; Inthavong, Kiao; Lidén, Göran; Shang, Yidan; Tu, Jiyuan

    2016-07-01

    Welding fume is a complex mixture containing ultra-fine particles in the nanometer range. Rather than being in the form of a singular sphere, due to the high particle concentration, welding fume particles agglomerate into long straight chains, branches, or other forms of compact shapes. Understanding the transport and deposition of these nano-agglomerates in human respiratory systems is of great interest as welding fumes are a known health hazard. The neurotoxin manganese (Mn) is a common element in welding fumes. Particulate Mn, either as soluble salts or oxides, that has deposited on the olfactory mucosa in human nasal airway is transported along the olfactory nerve to the olfactory bulb within the brain. If this Mn is further transported to the basal ganglia of the brain, it could accumulate at the part of the brain that is the focal point of its neurotoxicity. Accounting for various dynamic shape factors due to particle agglomeration, the current computational study is focused on the exposure route, the deposition pattern, and the deposition efficiency of the inhaled welding fume particles in a realistic human nasal cavity. Particular attention is given to the deposition pattern and deposition efficiency of inhaled welding fume agglomerates in the nasal olfactory region. For particles in the nanoscale, molecular diffusion is the dominant transport mechanism. Therefore, Brownian diffusion, hydrodynamic drag, Saffman lift force, and gravitational force are included in the model study. The deposition efficiencies for single spherical particles, two kinds of agglomerates of primary particles, two-dimensional planar and straight chains, are investigated for a range of primary particle sizes and a range of number of primary particles per agglomerate. A small fraction of the inhaled welding fume agglomerates is deposited on the olfactory mucosa, approximately in the range 0.1-1%, and depends on particle size and morphology. The strong size dependence of the deposition

  9. Proceedings, volume 17, Institute for Briquetting and Agglomeration

    SciTech Connect

    Not Available

    1982-01-01

    Papers presented discussed pelletizing of coal fines, graphite manufacture, compacting of coal, use of computers in agglomeration, HYL-III process, briquetting of iron ore fines, RECLAFORM, INMETCO process, binders for agglomeration, acoustic agglomeration, pelletizing of lime-fly ash mixtures, extrusion of aluminas for catalysts, and agglomeration of wastes. Seven papers have been abstracted separately.

  10. Detailed analysis of a quench bomb for the study of aluminum agglomeration in solid propellants

    NASA Astrophysics Data System (ADS)

    Gallier, S.; Kratz, J.-G.; Quaglia, N.; Fouin, G.

    2016-07-01

    A standard quench bomb (QB) - widely used to characterize condensed phase from metalized solid propellant combustion - is studied in detail. Experimental and numerical investigations proved that collected particles are mostly unburned aluminum (Al) agglomerates despite large quenching distances. Particles are actually found to quench early as propellant surface is swept by inert pressurant. Further improvements of the QB are proposed which allow measuring both Al agglomerates and alumina residue with the same setup. Finally, the results obtained on a typical aluminized ammonium perchlorate (AP) / hydroxyl-terminated polybutadiene (HTPB) propellant are briefly discussed.

  11. Erosion of steepland valleys by debris flows

    USGS Publications Warehouse

    Stock, J.D.; Dietrich, W.E.

    2006-01-01

    Episodic debris flows scour the rock beds of many steepland valleys. Along recent debris-flow runout paths in the western United States, we have observed evidence for bedrock lowering, primarily by the impact of large particles entrained in debris flows. This evidence may persist to the point at which debris-flow deposition occurs, commonly at slopes of less than ???0.03-0.10. We find that debris-flow-scoured valleys have a topographic signature that is fundamentally different from that predicted by bedrock river-incision models. Much of this difference results from the fact that local valley slope shows a tendency to decrease abruptly downstream of tributaries that contribute throughgoing debris flows. The degree of weathering of valley floor bedrock may also decrease abruptly downstream of such junctions. On the basis of these observations, we hypothesize that valley slope is adjusted to the long-term frequency of debris flows, and that valleys scoured by debris flows should not be modeled using conventional bedrock river-incision laws. We use field observations to justify one possible debris-flow incision model, whose lowering rate is proportional to the integral of solid inertial normal stresses from particle impacts along the flow and the number of upvalley debris-flow sources. The model predicts that increases in incision rate caused by increases in flow event frequency and length (as flows gain material) downvalley are balanced by rate reductions from reduced inertial normal stress at lower slopes, and stronger, less weathered bedrock. These adjustments lead to a spatially uniform lowering rate. Although the proposed expression leads to equilibrium long-profiles with the correct topographic signature, the crudeness with which the debris-flow dynamics are parameterized reveals that we are far from a validated debris-flow incision law. However, the vast extent of steepland valley networks above slopes of ???0.03-0.10 illustrates the need to understand debris

  12. Geosynchronous Large Debris Reorbiter: Challenges and Prospects

    NASA Astrophysics Data System (ADS)

    Schaub, Hanspeter; Moorer, Daniel F.

    2012-06-01

    An elegant solution is proposed to an old problem of how to remove expired or malfunctioning satellites from the geosynchronous belt. Previous "space-tug" concepts describe a scenario where one craft (the tug) docks with another (debris) and then boosts that object to a super-synchronous orbit. The most challenging aspect of these concepts is the very complex proximity operations to an aging, possibly rotating and, probably, non-cooperative satellite. Instead, the proposed method uses an elegant blend of electrostatic charge control and low-thrust propulsion to avoid any contact requirement. The Geosynchronous Large Debris Reorbiter (GLiDeR) uses active charge emission to raise its own absolute potential to 10's of kilovolts and, in addition, directs a stream of charged particles at the debris to increase its absolute potential. In a puller configuration the opposite polarity of the debris creates an attractive force between the GLiDeR and the debris. Pusher configurations are feasible as well. Next, fuel-efficient micro-thrusters are employed to gently move the reorbiter relative to the debris, and then accelerate the debris out of its geosynchronous slot and deposit it in a disposal orbit. Preliminary analysis shows that a 1000 kg debris object can be re-orbited over two-four months. During the reorbit phase the separation distance is held nominally fixed without physical contact, even if the debris is tumbling, by actively controlling the charge transfer between the reorbiter and the debris. Numerical simulations are presented illustrating the expected performance, taking into account also the solar radiation pressure.

  13. Factors affecting the oil agglomeration of Sivas-Divrigi Ulucayir lignite

    SciTech Connect

    Unal, I.; Gorgun Ersan, M.

    2007-07-01

    In the coal industry, the coal particles need to be decreased to a very fine size because of the need of removing inorganic materials from coal. Oil agglomeration is a kind of coal cleaning technique that is used for separation of organic and inorganic parts of fine sized coal. In this study, the oil agglomeration of Sivas-Divrigi (S-D) Ulucayir lignite was carried out by using kerosene, diesel oil, fuel oil, poppy oil, and sunflower oil. The amount of bridging oil was varied from 5% to 25% of the amount of lignite. The effect of oil amount, oil type, solid content, agitation rate and time, pH on agglomeration performance was investigated. Maximum recovery value of 98.18% was observed by using poppy oil. In order to investigate the effect of pH on agglomeration NaOH and HCl is added to the slurry in various amounts. It is decided that the best agglomeration condition is obtained at low pH values. The effect of nonionic surface active agent (Igepal-CA 630) on agglomeration is investigated by adding to the slurry and it is observed that the grade is increased with the amount of surface active agent.

  14. Iron Oxide Nanoparticle Agglomeration Influences Dose-Rates and Modulates Oxidative Stress Mediated Dose-Response Profiles In Vitro

    SciTech Connect

    Sharma, Gaurav; Kodali, Vamsi K.; Gaffrey, Matthew J.; Wang, Wei; Minard, Kevin R.; Karin, Norman J.; Teeguarden, Justin G.; Thrall, Brian D.

    2013-07-31

    Spontaneous agglomeration of engineered nanoparticles (ENPs) is a common problem in cell culture media which can confound interpretation of in vitro nanotoxicity studies. The authors created stable agglomerates of iron oxide nanoparticles (IONPs) in conventional culture medium, which varied in hydrodynamic size (276 nm-1.5 μm) but were composed of identical primary particles with similar surface potentials and protein coatings. Studies using C10 lung epithelial cells show that the dose rate effects of agglomeration can be substantial, varying by over an order of magnitude difference in cellular dose in some cases. Quantification by magnetic particle detection showed that small agglomerates of carboxylated IONPs induced greater cytotoxicity and redox-regulated gene expression when compared with large agglomerates on an equivalent total cellular IONP mass dose basis, whereas agglomerates of amine-modified IONPs failed to induce cytotoxicity or redox-regulated gene expression despite delivery of similar cellular doses. Dosimetry modelling and experimental measurements reveal that on a delivered surface area basis, large and small agglomerates of carboxylated IONPs have similar inherent potency for the generation of ROS, induction of stress-related genes and eventual cytotoxicity. The results suggest that reactive moieties on the agglomerate surface are more efficient in catalysing cellular ROS production than molecules buried within the agglomerate core. Because of the dynamic, size and density-dependent nature of ENP delivery to cells in vitro, the biological consequences of agglomeration are not discernible from static measures of exposure concentration (μg/ml) alone, highlighting the central importance of integrated physical characterisation and quantitative dosimetry for in vitro studies. The combined experimental and computational approach provides a quantitative framework for evaluating relationships between the biocompatibility of nanoparticles and their

  15. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1995-01-01

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 mm) needed to achieve adequate liberation of the mineral matter from the coal matrix. It is generally recognized that surface-based separation processes such as froth flotation or selective agglomeration offer considerable potential for such applications but there remain many problems in obtaining the required selectivity with acceptable recovery of combustible matter. In froth flotation, selectivity is substantially reduced at fine sizes due, primarily, to overloading of the froth phase which leads to excessive carryover of water and entrained mineral matter. Oil agglomeration, on the other hand, can provide good selectivity at low levels of oil addition but the agglomerates tend to be too fragile for separation by the screening methods normally used. The addition of larger amounts of oil can yield large, strong agglomerates which are easily separated but the selectivity is reduced and reagent costs can become excessive. We are investigating the use of a hybrid process - micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30-50 mm in size) rather than individual coal particles (1-10 mm) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale.

  16. Development of a gas-promoted oil agglomeration process. Technical progress report, October 1, 1993--September 30, 1994

    SciTech Connect

    Wheelock, T.D.

    1994-10-01

    During the first year of the project two model mixing systems, which differed in size but were similar in design, were constructed and tested. The systems were equipped for measuring agitator speed and torque and for measuring the turbidity of coal particle suspensions undergoing agglomeration. Preliminary measurements of aqueous suspensions of coal particles showed that the Beer-Lambert law applies to such suspensions at least for low concentrations. Therefore, the measured turbidity can be used as an indicator of particle concentration and a means for monitoring the progress of oil agglomeration. However, the method is not applicable for large particle concentrations so a different technique was tested for monitoring the agglomeration of large concentrations. This technique involves measuring agitator torque and observing changes in torque while agitator speed is held constant. The results of preliminary tests of the technique were encouraging. In these tests significant changes in agitator torque were observed when particle agglomeration took place as long as solids concentration of 25 w/v % or more were utilized. A number of agglomeration tests were conducted using either one or the other of the two monitoring techniques. Both methods showed that even very small amounts of air can promote the oil agglomeration of coal particles suspended in water. Even the amount of air dissolved in water at room temperature and pressure can affect the process providing the air is displaced from the solution by a slightly soluble agglomerant such as heptane. The apparent rate of agglomeration was observed to increase as more air was introduced and also as agitator speed was increased.

  17. Reduced bed agglomeration by co-combustion biomass with peat fuels in a fluidized bed

    SciTech Connect

    Karin Lundholm; Anders Nordin; Marcus Oehman; Dan Bostroem

    2005-12-01

    Fluidized bed combustion is an energy conversion technology that is very suitable for biomass combustion because of its fuel flexibility and low process temperatures. However, agglomeration of bed material may cause severe operating problems. To prevent or at least reduce this, peat has been suggested as an additive to the main fuels. Nevertheless, the characteristics of peat fuels vary and there is limited information of the effect of different peat fuels and of the mechanisms behind the agglomeration prevention. The objectives of the present work were therefore to: (I) quantify the potential positive effect by co-combustion peat with forest fuels in terms of initial agglomeration temperatures; (ii) determine the amount of peat fuel that is needed to significantly reduce the agglomeration tendencies; and, if possible, (iii) elucidate the governing mechanisms. The results showed that all peat fuels prevented agglomeration in the studied interval of 760-1020{sup o}C and even as little as 5% peat fuel was found to have significant effects. The results also indicated that the mechanism of the agglomeration prevention varies between different peat fuels. Possible mechanisms are the minerals in the peat fuel retain alkali, which then is either elutriated up from the bed or captured in the bed; calcium and other refractory elements increase the melting temperature and thereby counteract the melting of alkali; and sulfur reacts with alkali metals and the alkali sulfates is either elutriated up from the bed or prevents agglomeration by increased melting temperature and lowered viscosity. Results from elemental analysis of the coating on bed particles showed that all mixtures with peat fuel resulted in a decreased or unchanged fraction of potassium and an increased fraction of aluminum in the coatings. The results also indicated a complex relationship between the fuel inorganic contents and the agglomeration process. 21 refs., 6 figs., 5 tabs.

  18. Dimensional analysis of natural debris flows

    NASA Astrophysics Data System (ADS)

    Zhou, Gordon; Ouyang, Chaojun

    2015-04-01

    Debris flows occur when masses of poorly sorted sediment, agitated and saturated with water, surge down slopes in response to gravitational attraction. They are of great concern because they often cause catastrophic disasters due to the long run-out distance and large impact forc-es. Different from rock avalanches and sediment-laden water floods, both solid and fluid phases affected by multiple parameters can influence the motion of debris flows and govern their rheological properties. A dimensional analysis for a systematic study of the governing parameters is presented in this manuscript. Multiple dimensionless numbers with clear physical meanings are critically reviewed. Field data on natural debris flows are available here based on the fifty years' observation and measurement in the Jiangjia Gully, which is located in the Dongchuan City, Yunnan Province of China. The applications of field data with the dimensional analysis for studying natural debris flows are demonstrated. Specific values of dimensionless numbers (e.g., modified Savage Number, Reynolds number, Friction number) for classifying flowing regimes of natural debris flows on the large scales are obtained. Compared to previous physical model tests conducted mostly on small scales, this study shows that the contact friction between particles dominates in natural debris flows. In addition, the solid inertial stress due to particle collisions and the pore fluid viscous shear stress play key roles in governing the dynamic properties of debris flows and the total normal stress acting on the slope surfaces. The channel width as a confinement to the flows can affect the solids discharge per unit width significantly. Furthermore, a dimensionless number related to pore fluid pressure dissipation is found for distinguishing surge flows and continuous flows in field satisfactorily. It indicates that for surge debris flows, the high pore fluid pressures generated in granular body dissipate quite slowly and may

  19. Tracking Debris Shed by a Space-Shuttle Launch Vehicle

    NASA Technical Reports Server (NTRS)

    Stuart, Phillip C.; Rogers, Stuart E.

    2009-01-01

    The DEBRIS software predicts the trajectories of debris particles shed by a space-shuttle launch vehicle during ascent, to aid in assessing potential harm to the space-shuttle orbiter and crew. The user specifies the location of release and other initial conditions for a debris particle. DEBRIS tracks the particle within an overset grid system by means of a computational fluid dynamics (CFD) simulation of the local flow field and a ballistic simulation that takes account of the mass of the particle and its aerodynamic properties in the flow field. The computed particle trajectory is stored in a file to be post-processed by other software for viewing and analyzing the trajectory. DEBRIS supplants a prior debris tracking code that took .15 minutes to calculate a single particle trajectory: DEBRIS can calculate 1,000 trajectories in .20 seconds on a desktop computer. Other improvements over the prior code include adaptive time-stepping to ensure accuracy, forcing at least one step per grid cell to ensure resolution of all CFD-resolved flow features, ability to simulate rebound of debris from surfaces, extensive error checking, a builtin suite of test cases, and dynamic allocation of memory.

  20. Morphology, size distribution and elemental composition of several dental debris

    NASA Astrophysics Data System (ADS)

    Abe, Shigeaki; Iwadera, Nobuki; Esaki, Mitsue; Aoyama, Ken-Ichi; Akasaka, Tsukasa; Uo, Motohiro; Morita, Manabu; Yawaka, Yasutaka; Watari, Fumio

    2012-12-01

    We investigated morphologies, size distributions and elemental compositions of dental debris formed by cutting/grinding teeth or dental alloys. The average size of debris formed by cutting/grinding dental alloy was around 100 μm and that of teeth was 20 μm. The debris formed by grinding with diamond or carborundum point had isotropic irregular shape, while the debris formed by cutting with carbide bar had characteristic lathe-cut shape. The elemental analysis indicated that the debris formed by grinding dental alloy with carborundum point consisted of not only the particles of the alloy but also the particles of Si compounds with the size of around 10 μm. The particles of Si compounds would be formed by abrasion of the grinding instrument (carborundum, SiC). Similarly, the debris formed by grinding with diamond point also contained submicro-sized particles consisting of C compounds. The results indicate that the morphology and composition of dental debris are varied depending on the combination between the workpiece and the cutting/grinding materials and that the dental debris consist of both the workpiece and the cutting/grinding materials in some combination. In addition, some of the debris of tooth had the size less than 2 μm, which has a potential to induce inflammation. Though the inflammation can be expected at low level, it is required to investigate the details in future.

  1. Effect of Drying Phase on the Agglomerates Prepared by Spherical Crystallization

    PubMed Central

    Maghsoodi, Maryam; Yari, Zahra

    2015-01-01

    In this paper, differences in porosity, compressive strength and tablet- forming ability of carbamazepine crystals agglomerated under similar condition, but subjected to different drying temperatures are reported. The agglomerates were prepared by spherical crystallization method and thereafter dried without agitation at different temperature. An increased drying temperature did not affect the shape and structure texture of dried particles and did not cause them to fracture. Drying of particles at higher temperature suppressed the particle contraction as a consequence of fast evaporation and hence produced particles of larger mean diameter, higher porosity and thus lower compressive strength than those dried at lower temperature. Through a relationship with particle porosity, the drying rate also affected the ability of particles to form tablets. PMID:25561911

  2. Identification of micro parameters for discrete element simulation of agglomerates

    NASA Astrophysics Data System (ADS)

    Palis, Stefan; Antonyuk, Sergiy; Dosta, Maksym; Heinrich, Stefan

    2013-06-01

    The mechanical behaviour of solid particles like agglomerates, granules or crystals strongly depends on their micro structure, e.g. structural defects and porosity. In order to model the mechanical behaviour of these inhomogeneous media the discrete element method has been proven to be an appropriate tool. The model parameters used are typically micro parameters like bond stiffness, particle-particle contact stiffness, strength of the bonds. Due to the lack of general methods for a direct micro parameter determination, normally laborious parameter adaptation has to be done in order to fit experiment and simulation. In this contribution a systematic and automatic way for parameter adaptation using real experiments is proposed. Due to the fact, that discrete element models are typically systems of differential equations of very high order, gradient based methods are not suitable. Hence, the focus will be on derivative free methods.

  3. Nuclear-powered space debris sweeper

    NASA Technical Reports Server (NTRS)

    Metzger, John D.; Leclaire, Rene J., Jr.; Howe, Steven D.; Burgin, Karen C.

    1989-01-01

    Future spacecraft design will be affected by collisions with man-made debris orbiting the earth. Most of this orbital space debris comes from spent rocket stages. It is projected that the source of future debris will be the result of fragmentation of large objects through hypervelocity collisions. Orbiting spacecraft will have to be protected from hypervelocity debris in orbit. The options are to armor the spacecraft, resulting in increased mass, or actively removing the debris from orbit. An active space debris sweeper is described which will utilize momentum transfer to the debris through laser-induced ablation to alter its orbital parameters to reduce orbital lifetime with eventual entry into the earth's atmosphere where it will burn. The paper describes the concept, estimates the amount of velocity change (Delta V) that can be imparted to an object through laser-induced ablation, and investigates the use of a neutral particle beam for the momentum transfer. The space sweeper concept could also be extended to provide a collision avoidance system for the space station and satellites, or could be used for collision protection during interplanetary travel.

  4. Parametric analysis: SOC meteoroid and debris protection

    NASA Technical Reports Server (NTRS)

    Kowalski, R.

    1985-01-01

    The meteoroid and man made space debris environments of an Earth orbital manned space operations center are discussed. Protective shielding thickness and design configurations for providing given levels of no penetration probability were also calculated. Meteoroid/debris protection consists of a radiator/shield thickness, which is actually an outer skin, separated from the pressure wall, thickness by a distance. An ideal shield thickness, will, upon impact with a particle, cause both the particle and shield to vaporize, allowing a minimum amount of debris to impact the pressure wall itself. A shield which is too thick will crater on the outside, and release small particles of shield from the inside causing damage to the pressure wall. Inversely, if the shield is too thin, it will afford no protection, and the backup must provide all necessary protection. It was concluded that a double wall concept is most effective.

  5. Characterization of the fretting corrosion behavior, surface and debris from head-taper interface of two different modular hip prostheses.

    PubMed

    Dos Santos, Claudio T; Barbosa, Cassio; Monteiro, Maurício J; Abud, Ibrahim C; Caminha, Ieda M V; Roesler, Carlos R M

    2016-09-01

    Modular hip prostheses are flexible to match anatomical variations and to optimize mechanical and tribological properties of each part by using different materials. However, micromotions associated with the modular components can lead to fretting corrosion and, consequently, to release of debris which can cause adverse local tissue reactions in human body. In the present study, the surface damage and residues released during in vitro fretting corrosion tests were characterized by stereomicroscope, SEM and EDS. Two models of modular hip prosthesis were studied: Model SS/Ti Cementless whose stem was made of ASTM F136 Ti-6Al-4V alloy and whose metallic head was made of ASTM F138 austenitic stainless steel, and Model SS/SS Cemented with both components made of ASTM F138 stainless steel. The fretting corrosion tests were evaluated according to the criteria of ASTM F1875 standard. Micromotions during the test caused mechanical wear and material loss in the head-taper interface, resulting in fretting-corrosion. Model SS/SS showed higher grade of corrosion. Different morphologies of debris predominated in each model studied. Small and agglomerated particles were observed in the Model SS/Ti and irregular particles in the Model SS/SS. After 10 million cycles, the Model SS/Ti was more resistant to fretting corrosion than the Model SS/SS. PMID:27179766

  6. In-Situ Agglomeration and De-agglomeration by Milling of Nano-Engineered Lubricant Particulate Composites for Cold Spray Deposition

    NASA Astrophysics Data System (ADS)

    Neshastehriz, M.; Smid, I.; Segall, A. E.

    2014-10-01

    Nano-engineered self-lubricating particles comprised of hexagonal-boron-nitride powder (hBN) encapsulated in nickel have been developed for cold spray coating of aluminum components. The nickel encapsulant consists of several nano-sized layers, which are deposited on the hBN particles by electroless plating. In the cold spray deposition, the nickel becomes the matrix in which hBN acts as the lubricant. The coating demonstrated a very promising performance by reducing the coefficient of friction by almost 50% and increasing the wear resistance more than tenfold. The coatings also exhibited higher bond strength, which was directly related to the hardenability of the particles. During the encapsulation process, the hBN particles agglomerate and form large clusters. De-agglomeration has been studied through low- and high-energy ball milling to create more uniform and consistent particle sizes and to improve the cold spray deposition efficiency. The unmilled and milled particles were characterized with Scanning Electron Microscopy, Energy-Dispersive X-Ray Spectroscopy, BET, and hardness tests. It was found that in low-energy ball milling, the clusters were compacted to a noticeable extent. However, the high-energy ball milling resulted in breakup of agglomerations and destroyed the nickel encapsulant.

  7. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, 1 April--30 June 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1994-07-01

    The authors are investigating the use of a hybrid process--Micro-agglomerate flotation--which is a combination of oil-agglomeration and froth flotation. The basic concepts is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload water/mineral carryover should be significantly alleviated. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response. The research program has been organized into several specific tasks: Task 1, interfacial studies; Task 2, emulsification; Task 3, agglomerate growth and structure; and Task 4, agglomerate flotation. This report summarizes the status of Tasks 2, 3, and 4.

  8. A discrete element and ray framework for rapid simulation of acoustical dispersion of microscale particulate agglomerations

    NASA Astrophysics Data System (ADS)

    Zohdi, T. I.

    2016-03-01

    In industry, particle-laden fluids, such as particle-functionalized inks, are constructed by adding fine-scale particles to a liquid solution, in order to achieve desired overall properties in both liquid and (cured) solid states. However, oftentimes undesirable particulate agglomerations arise due to some form of mutual-attraction stemming from near-field forces, stray electrostatic charges, process ionization and mechanical adhesion. For proper operation of industrial processes involving particle-laden fluids, it is important to carefully breakup and disperse these agglomerations. One approach is to target high-frequency acoustical pressure-pulses to breakup such agglomerations. The objective of this paper is to develop a computational model and corresponding solution algorithm to enable rapid simulation of the effect of acoustical pulses on an agglomeration composed of a collection of discrete particles. Because of the complex agglomeration microstructure, containing gaps and interfaces, this type of system is extremely difficult to mesh and simulate using continuum-based methods, such as the finite difference time domain or the finite element method. Accordingly, a computationally-amenable discrete element/discrete ray model is developed which captures the primary physical events in this process, such as the reflection and absorption of acoustical energy, and the induced forces on the particulate microstructure. The approach utilizes a staggered, iterative solution scheme to calculate the power transfer from the acoustical pulse to the particles and the subsequent changes (breakup) of the pulse due to the particles. Three-dimensional examples are provided to illustrate the approach.

  9. Micro-agglomerate flotation for deep cleaning of coal. Final report

    SciTech Connect

    Chander, S.; Hogg, R.

    1997-01-15

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 {micro}m) needed to achieve adequate liberation of the mineral matter from the coal matrix. In this investigation a hybrid process--Micro-agglomerate flotation--which is a combination of oil-agglomeration and froth flotation was studied. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles and to use froth flotation to separate these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units will be relatively large agglomerates (30--50 {micro}m in size) rather than fine coal particles (1--10 {micro}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is demonstrated in this study that the process is very sensitive to fluctuations in operating parameters. It is necessary to maintain precise control over the chemistry of the liquid phases as well as the agitation conditions in order to promote selectivity. Both kinetics as well as thermodynamic factors play a critical role in determining overall system response.

  10. The fast debris evolution model

    NASA Astrophysics Data System (ADS)

    Lewis, H. G.; Swinerd, G. G.; Newland, R. J.; Saunders, A.

    2009-09-01

    The 'particles-in-a-box' (PIB) model introduced by Talent [Talent, D.L. Analytic model for orbital debris environmental management. J. Spacecraft Rocket, 29 (4), 508-513, 1992.] removed the need for computer-intensive Monte Carlo simulation to predict the gross characteristics of an evolving debris environment. The PIB model was described using a differential equation that allows the stability of the low Earth orbit (LEO) environment to be tested by a straightforward analysis of the equation's coefficients. As part of an ongoing research effort to investigate more efficient approaches to evolutionary modelling and to develop a suite of educational tools, a new PIB model has been developed. The model, entitled Fast Debris Evolution (FADE), employs a first-order differential equation to describe the rate at which new objects ⩾10 cm are added and removed from the environment. Whilst Talent [Talent, D.L. Analytic model for orbital debris environmental management. J. Spacecraft Rocket, 29 (4), 508-513, 1992.] based the collision theory for the PIB approach on collisions between gas particles and adopted specific values for the parameters of the model from a number of references, the form and coefficients of the FADE model equations can be inferred from the outputs of future projections produced by high-fidelity models, such as the DAMAGE model. The FADE model has been implemented as a client-side, web-based service using JavaScript embedded within a HTML document. Due to the simple nature of the algorithm, FADE can deliver the results of future projections immediately in a graphical format, with complete user-control over key simulation parameters. Historical and future projections for the ⩾10 cm LEO debris environment under a variety of different scenarios are possible, including business as usual, no future launches, post-mission disposal and remediation. A selection of results is presented with comparisons with predictions made using the DAMAGE environment model

  11. In-Situ Observations of Interaction Between Particulate Agglomerates and an Advancing Planar Solid/Liquid Interface: Microgravity Experiments

    NASA Technical Reports Server (NTRS)

    Sen, S.; Juretzko, F.; Stefanescu, D. M.; Dhindaw, B. K.; Curreri, P. A.

    1999-01-01

    Results are reported of directional solidification experiments on particulate agglomerate pushing and engulfment by a planar solid/liquid (s/1) interface. These experiments were conducted on the Space Shuttle Columbia during the United States Microgravity Payload 4 (USMP-4) Mission. It was found that the pushing to engulfment transition velocity, V(sub ct),, for agglomerates depends not only on their effective size but also their orientation with respect to the s/l interface. The analytical model for predicting V(sub cr) of a single particle was subsequently enhanced to predict V(sub cr) of the agglomerates by considering their shape factor and orientation.

  12. In Situ Observations of Interaction Between Particulate Agglomerates and an Advancing Planar Solid/Liquid Interface: Microgravity Experiments

    NASA Technical Reports Server (NTRS)

    Sen, S.; Juretzko, F.; Stafanescu, D. M.; Dhindaw, B. K.; Curreri, P. A.

    1999-01-01

    Results are reported of directional solidification experiments on particulate agglomerate pushing and engulfment by a planar solid/liquid (s/l) interface. These experiments were conducted on the Space Shuttle Columbia during the United States Microgravity Payload 4 (USMP-4) Mission. It was found that the pushing to engulfment transition velocity, V(sub cr) for agglomerates depends not only on their effective size but also their orientation with respect to the s,1 interface. The analytical model for predicting V(sub cr) of a single particle was subsequently enhanced to predict V(sub cr) of the agglomerates by considering their shape factor and orientation.

  13. Micrometeoroid and orbital debris impact inspection of the Hubble Space Telescope Wide Field Planetary Camera 2 radiator and the implications for the near-Earth small particle environment

    NASA Astrophysics Data System (ADS)

    Liou, J.-C.; Anz-Meador, P.; Opiela, J.; Christiansen, E.; Cowardin, H.; Davidson, W.; Ed-Wards, D.; Hedman, T.; Herrin, J.; Hyde, J.; Juarez, Q.; Lear, D.; McNamara, K.; Moser, D.; Ross, D.; Stansbery, E.

    The STS-125 Atlantis astronauts retrieved the Hubble Space Telescope (HST) Wide Field Planetary Camera 2 (WFPC2) during a very successful servicing mission to the HST in May 2009. The radiator attached to WFPC2 has dimensions of 2.2 m by 0.8 m. Its outermost layer is a 4-mm thick aluminum plate covered with a white thermal control coating. This radiator had been exposed to space since the deployment of WFPC2 in 1993. Due to its large surface area and long exposure time, the radiator serves as a unique witness plate for the micrometeoroid and orbital debris (MMOD) environment between 560 and 620 km altitude. The NASA Orbital Debris Program Office is leading an effort, with full support from the HST Program at GSFC, NASA Curation Office at JSC, NASA Hypervelocity Impact Technology Facility at JSC, and NASA Meteoroid Environment Office at MSFC, to inspect the exposed radiator surface. The objective is to measure and analyze the MMOD impact damage on the radiator, and then apply the data to validate or improve the near-Earth MMOD environment definition. The initial inspection was completed in September 2009. A total of 685 MMOD impact features (larger than about 0.3 mm) were identified and documented. This paper will provide an overview of the inspection, the analysis of the data, and the initial effort to use the data to model the MMOD environment.

  14. Orbital Debris and NASA's Measurement Program

    NASA Astrophysics Data System (ADS)

    Africano, J. L.; Stansbery, E. G.

    2002-05-01

    Since the launch of Sputnik in 1957, the number of manmade objects in orbit around the Earth has dramatically increased. The United States Space Surveillance Network (SSN) tracks and maintains orbits on over nine thousand objects down to a limiting diameter of about ten centimeters. Unfortunately, active spacecraft are only a small percentage ( ~ 7%) of this population. The rest of the population is orbital debris or ``space junk" consisting of expended rocket bodies, dead payloads, bits and pieces from satellite launches, and fragments from satellite breakups. The number of these smaller orbital debris objects increases rapidly with decreasing size. It is estimated that there are at least 130,000 orbital debris objects between one and ten centimeters in diameter. Most objects smaller than 10 centimeters go untracked! As the orbital debris population grows, the risk to other orbiting objects, most importantly manned space vehicles, of a collision with a piece of debris also grows. The kinetic energy of a solid 1 cm aluminum sphere traveling at an orbital velocity of 10 km/sec is equivalent to a 400 lb. safe traveling at 60 mph. Fortunately, the volume of space in which the orbiting population resides is large, collisions are infrequent, but they do occur. The Space Shuttle often returns to earth with its windshield pocked with small pits or craters caused by collisions with very small, sub-millimeter-size pieces of debris (paint flakes, particles from solid rocket exhaust, etc.), and micrometeoroids. To get a more complete picture of the orbital-debris environment, NASA has been using both radar and optical techniques to monitor the orbital debris environment. This paper gives an overview of the orbital debris environment and NASA's measurement program.

  15. Space debris detection and mitigation

    SciTech Connect

    Allahdadi, F.

    1993-01-01

    Space debris is defined as all useless man-made objects in space. This conference covers the following areas: debris detection, tracking, and surveillance; orbital debris analytical modeling; debris environment and safety issues; and orbital debris mitigation. Separate abstracts were prepared for 26 papers in this conference.

  16. Mechanism of nanoparticle agglomeration during the combustion synthesis

    NASA Astrophysics Data System (ADS)

    Altman, Igor S.; Agranovski, Igor E.; Choi, Mansoo

    2005-08-01

    The mechanism of agglomeration of nanoparticles generated during combustion synthesis is discussed. This is based on the analysis of the transmission electron microscope images of probes collected at different heights. Although direct temperature measurements were not available, the qualitative temperature dependence of the particle formation streamlines is taken into account. It is demonstrated that agglomeration of the MgO nanoparticles, which are formed during a Mg particle combustion, occurs as the result of bonding the mature nanoparticles by the supercritical clusters existing in the system. Accumulation of these supercritical clusters in the flame has been revealed and their nature has been explained in our recent paper [I.S. Altman, I.E. Agranovski, and M. Choi, Phys. Rev E 70, 062603 (2004)]. Also, some inspection of the previously published experimental data on the nanoparticle generation shows that the similar supercritical clusters may exist in another flame reactor generating titania nanopaprticles. If this is the case, the cluster-based process of nanoparticle bonding we suggest can be considered to be general.

  17. Ferrographic analysis of wear debris from boundary lubrication experiments with a five-ring polyphenyl ether

    NASA Technical Reports Server (NTRS)

    Jones, W. R., Jr.

    1974-01-01

    The types of wear particles generated by a five-ring polyphenyl ether in boundary lubrication experiments in various atmospheres were determined by ferrographic analysis. The types of wear particles observed included cylindrical or rocklike organometallic debris, adhesive and cutting wear particles, and some spherical debris. Interpretations as to the mechanism of generation of the various types of particles are presented.

  18. Orbiting meteoroid and debris counting experiment

    NASA Technical Reports Server (NTRS)

    Kinard, William H.; Armstrong, Dwayne; Crockett, Sharon K.; Jones, James L., Jr.; Kassel, Philip C., Jr.; Wortman, J. J.

    1995-01-01

    The Orbiting Meteoroid and Debris Counting Experiment (OMDC) flew for approximately 90 days in a highly elliptical earth orbit onboard the Clementine Interstage Adapter (ISA) Spacecraft. This experiment obtained data on the impact flux of natural micrometeoroids and it provided limited information on the population of small mass man-made debris as a function of altitude in near earth space. The flight of the OMDC experiment on the ISA spacecraft also demonstrated that the ultra-lightweight, low-power, particle impact detector system that was used is a viable system for flights on future spacecraft to monitor the population of small mass man-made debris particles and to map the cosmic dust environment encountered on interplanetary missions. An overview of the ISA spacecraft mission, the approach to the OMDC experiment, and the data obtained by the experiment are presented.

  19. Procedures for analysis of debris relative to Space Shuttle systems

    NASA Technical Reports Server (NTRS)

    Kim, Hae Soo; Cummings, Virginia J.

    1993-01-01

    Debris samples collected from various Space Shuttle systems have been submitted to the Microchemical Analysis Branch. This investigation was initiated to develop optimal techniques for the analysis of debris. Optical microscopy provides information about the morphology and size of crystallites, particle sizes, amorphous phases, glass phases, and poorly crystallized materials. Scanning electron microscopy with energy dispersive spectrometry is utilized for information on surface morphology and qualitative elemental content of debris. Analytical electron microscopy with wavelength dispersive spectrometry provides information on the quantitative elemental content of debris.

  20. Orbital Debris Mitigation

    NASA Technical Reports Server (NTRS)

    Kelley, R. L.; Jarkey, D. R.; Stansbery, G.

    2014-01-01

    Policies on limiting orbital debris are found throughout the US Government, many foreign space agencies, and as adopted guidelines in the United Nations. The underlying purpose of these policies is to ensure the environment remains safe for the operation of robotic and human spacecraft in near- Earth orbit. For this reason, it is important to consider orbital debris mitigation during the design of all space vehicles. Documenting compliance with the debris mitigation guidelines occurs after the vehicle has already been designed and fabricated for many CubeSats, whereas larger satellites are evaluated throughout the design process. This paper will provide a brief explanation of the US Government Orbital Debris Mitigation Standard Practices, a discussion of international guidelines, as well as NASA's process for compliance evaluation. In addition, it will discuss the educational value of considering orbital debris mitigation requirements as a part of student built satellite design.

  1. BINARIES AMONG DEBRIS DISK STARS

    SciTech Connect

    Rodriguez, David R.; Zuckerman, B.

    2012-02-01

    We have gathered a sample of 112 main-sequence stars with known debris disks. We collected published information and performed adaptive optics observations at Lick Observatory to determine if these debris disks are associated with binary or multiple stars. We discovered a previously unknown M-star companion to HD 1051 at a projected separation of 628 AU. We found that 25% {+-} 4% of our debris disk systems are binary or triple star systems, substantially less than the expected {approx}50%. The period distribution for these suggests a relative lack of systems with 1-100 AU separations. Only a few systems have blackbody disk radii comparable to the binary/triple separation. Together, these two characteristics suggest that binaries with intermediate separations of 1-100 AU readily clear out their disks. We find that the fractional disk luminosity, as a proxy for disk mass, is generally lower for multiple systems than for single stars at any given age. Hence, for a binary to possess a disk (or form planets) it must either be a very widely separated binary with disk particles orbiting a single star or it must be a small separation binary with a circumbinary disk.

  2. Characterizing Secondary Debris Impact Ejecta

    NASA Technical Reports Server (NTRS)

    Schonberg, W. P.

    1999-01-01

    All spacecraft in low-Earth orbit are subject to high-speed impacts by meteoroids and orbital debris particles. These impacts can damage flight-critical systems which can in turn lead to catastrophic failure of the spacecraft. Therefore, the design of a spacecraft for an Earth-orbiting mission must take into account the possibility of such impacts and their effects on the spacecraft structure and on all of its exposed subsystem components. In addition to threatening the operation of the spacecraft itself, on-orbit impacts also generate a significant amount of ricochet particles. These high-speed particles can destroy critical external spacecraft subsystem and also increase the contamination of the orbital environment. This report presents a summary of the work performed towards the development of an empirical model that characterizes the secondary ejecta created by a high-speed impacta on a typical aerospace structural surface.

  3. Characterizing Secondary Debris Impact Ejecta

    NASA Astrophysics Data System (ADS)

    Schonberg, W. P.

    1999-08-01

    All spacecraft in low-Earth orbit are subject to high-speed impacts by meteoroids and orbital debris particles. These impacts can damage flight-critical systems which can in turn lead to catastrophic failure of the spacecraft. Therefore, the design of a spacecraft for an Earth-orbiting mission must take into account the possibility of such impacts and their effects on the spacecraft structure and on all of its exposed subsystem components. In addition to threatening the operation of the spacecraft itself, on-orbit impacts also generate a significant amount of ricochet particles. These high-speed particles can destroy critical external spacecraft subsystem and also increase the contamination of the orbital environment. This report presents a summary of the work performed towards the development of an empirical model that characterizes the secondary ejecta created by a high-speed impacta on a typical aerospace structural surface.

  4. Effects of caustic sodium concentration and molecular ratio of Na2O to Al2O3 on agglomeration in the precipitation process

    NASA Astrophysics Data System (ADS)

    Liu, Zhanwei; Chen, Wenmi; Li, Wangxing

    2010-11-01

    The supersaturation of sodium aluminate solution (liquor) is a prerequisite for agglomeration and the key factors that determine supersaturation of liquor are caustic sodium concentration (Nk) and molecular ratio of Na2O to Al2O3 (αk). In this paper, the effects of Nk and αk on the agglomeration process of seeded precipitation were studied. The results show that the Nk plays an important role in the agglomeration process. The supersaturation of liquor decreases with the increasing of Nk and so not only does the precipitation ratio of liquor decrease but also the particle size of agglomerate decreases. The supersaturation of liquor decreases with the increasing of αk and so the precipitation rate and depth of liquor decrease and thus the agglomeration of fine particles is weakened.

  5. Analysis of Urban Agglomeration and Its Meaning for Rural People.

    ERIC Educational Resources Information Center

    Spiegelman, Robert G.

    Agglomeration--the clustering of people, businesses, or structures within an area--is investigated for two purposes: (1) defining the nature of agglomeration and erecting a suitable agglomeration theory, and (2) suggesting further research. These two objectives are seen as being vital to help improve the economic well-being of rural people by…

  6. Method for providing improved solid fuels from agglomerated subbituminous coal

    DOEpatents

    Janiak, Jerzy S.; Turak, Ali A.; Pawlak, Wanda; Ignasiak, Boleslaw L.

    1989-01-01

    A method is provided for separating agglomerated subbituminous coal and the heavy bridging liquid used to form the agglomerates. The separation is performed by contacting the agglomerates with inert gas or steam at a temperature in the range of 250.degree. to 350.degree. C. at substantially atmospheric pressure.

  7. Modeling debris-covered glaciers: response to steady debris deposition

    NASA Astrophysics Data System (ADS)

    Anderson, Leif S.; Anderson, Robert S.

    2016-05-01

    Debris-covered glaciers are common in rapidly eroding alpine landscapes. When thicker than a few centimeters, surface debris suppresses melt rates. If continuous debris cover is present, ablation rates can be significantly reduced leading to increases in glacier length. In order to quantify feedbacks in the debris-glacier-climate system, we developed a 2-D long-valley numerical glacier model that includes englacial and supraglacial debris advection. We ran 120 simulations on a linear bed profile in which a hypothetical steady state debris-free glacier responds to a step increase of surface debris deposition. Simulated glaciers advance to steady states in which ice accumulation equals ice ablation, and debris input equals debris loss from the glacier terminus. Our model and parameter selections can produce 2-fold increases in glacier length. Debris flux onto the glacier and the relationship between debris thickness and melt rate strongly control glacier length. Debris deposited near the equilibrium-line altitude, where ice discharge is high, results in the greatest glacier extension when other debris-related variables are held constant. Debris deposited near the equilibrium-line altitude re-emerges high in the ablation zone and therefore impacts melt rate over a greater fraction of the glacier surface. Continuous debris cover reduces ice discharge gradients, ice thickness gradients, and velocity gradients relative to initial debris-free glaciers. Debris-forced glacier extension decreases the ratio of accumulation zone to total glacier area (AAR). Our simulations reproduce the "general trends" between debris cover, AARs, and glacier surface velocity patterns from modern debris-covered glaciers. We provide a quantitative, theoretical foundation to interpret the effect of debris cover on the moraine record, and to assess the effects of climate change on debris-covered glaciers.

  8. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, January 1--March 31, 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1994-04-01

    We are investigating the use of a hybrid process -- Micro-agglomerate flotation which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases- two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  9. Micro-agglomerate location flotation for deep cleaning of coal. Quarterly progress report, October 1--December 31, 1993

    SciTech Connect

    Chander, S.; Hogg, R.

    1994-01-01

    We are investigating the use of a hybrid process -- Micro-agglomerate flotation which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  10. Experimental Modelling of Debris Flows

    NASA Astrophysics Data System (ADS)

    Paleo Cageao, P.; Turnbull, B.; Bartelt, P.

    2012-04-01

    Debris flows are gravity-driven mass movements typically containing water, sediments, soil and rocks. These elements combine to give a flow complex phenomenology that exhibits characteristics common to diverse geophysical flows from dry granular media (e.g. levee formation) to viscous gravity currents (viscous fingering and surge instabilities). The exceptional speeds and range debris flows can achieve motivate the need for a co-ordinated modelling approach that can provide insight into the key physical processes that dictate the hazard associated with the flows. There has been recent progress in theoretical modelling approaches that capture the details of the multi-component nature of debris flows. The promise of such models is underlined by their qualitatively successful comparison with field-scale experimental data. The aim of the present work is to address the technical difficulties in achieving a controlled and repeatable laboratory-scale experiment for robust testing of these multi-component models. A laboratory experiment has been designed and tested that can provide detailed information of the internal structure of debris flows. This constitutes a narrow Perspex chute that can be tilted to any angle between 0° and ≈ 60°. A mixture of glycerine and glass balls was initially held behind a lock-gate, before being released down the chute. The evolving flow was captured through high speed video, analysed with a Particle Image Velocimetry algorithm to provide the changing velocity field. A wide parameter space has been tested, allowing variations in particle size, dispersity, surface roughness, fluid viscosity, slope angle and solid volume fraction. While matching key similarity criteria, such as Froude number, with a typical field event, these experiments allow close examination of a wide range of physical scenarios for the robust testing of new multi-component flow models. Further diagnostics include force plate and pore pressure measurements, with a view

  11. A new debris sensor based on dual excitation sources for online debris monitoring

    NASA Astrophysics Data System (ADS)

    Hong, Wei; Wang, Shaoping; Tomovic, Mileta M.; Liu, Haokuo; Wang, Xingjian

    2015-09-01

    Mechanical systems could be severely damaged by loose debris generated through wear processes between contact surfaces. Hence, debris detection is necessary for effective fault diagnosis, life prediction, and prevention of catastrophic failures. This paper presents a new in-line debris sensor for hydraulic systems based on dual excitation sources. The proposed sensor makes magnetic lines more concentrated while at the same time improving magnetic field uniformity. As a result the sensor has higher sensitivity and improved precision. This paper develops the sensor model, discusses sensor structural features, and introduces a measurement method for debris size identification. Finally, experimental verification is presented indicating that that the sensor can effectively detect 81 μm (cube) or larger particles in 12 mm outside diameter (OD) organic glass pipe.

  12. Engineering development of selective agglomeration. Final report

    SciTech Connect

    Not Available

    1993-10-01

    This report presents the findings of the project entitled {open_quotes}Engineering Development of Selective Agglomeration.{close_quotes} In 1989 the US Department of Energy contracted with Southern Company Services, Inc. (DOE Contract No. DE-AC22-89PC88879) to develop selective agglomeration technology to a commercially acceptable level by 1993. This project is part of DOE`s program to advance the state of physical coal cleaning technologies in order to accelerate the utilization of high-sulfur coals while complying with environmental regulations. Such projects assume added importance in light of the 1990 Clean Air Act Amendments. Appropriate utilization of the abundant reserves of high-sulfur coal in the United States can make a significant contribution to achieving the goal of energy independence.

  13. Encapsulation of hazardous wastes into agglomerates

    SciTech Connect

    Guloy, A.

    1992-01-28

    The objective of this study was to investigate the feasibility of using the cementitious properties and agglomeration characteristics of coal conversion byproducts to encapsulate and immobilize hazardous waste materials. The intention was to establish an economical way of co-utilization and co-disposal of wastes. In addition, it may aid in the eradication of air pollution problems associated with the fine-powdery nature of fly ash. Encapsulation into agglomerates is a novel approach of treating toxic waste. Although encapsulation itself is not a new concept, existing methods employ high-cost resins that render them economically unfeasible. In this investigation, the toxic waste was contained in a concrete-like matrix whereby fly ash and other cementitious waste materials were utilized. The method incorporates the principles of solidification, stabilization and agglomeration. Another aspect of the study is the evaluation of the agglomeration as possible lightweight aggregates. Since fly ash is commercially used as an aggregate, it would be interesting to study the effect of incorporating toxic wastes in the strength development of the granules. In the investigation, the fly ash self-cementation process was applied to electroplating sludges as the toxic waste. The process hoped to provide a basis for delisting of the waste as hazardous and, thereby greatly minimize the cost of its disposal. Owing to the stringent regulatory requirements for hauling and disposal of hazardous waste, the cost of disposal is significant. The current practice for disposal is solidifying the waste with portland cement and dumping the hardened material in the landfill where the cost varies between $700--950/ton. Partially replacing portland cement with fly ash in concrete has proven beneficial, therefore applying the same principles in the treatment of toxic waste looked very promising.

  14. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Chander, S.; Hogg, R.

    1995-04-01

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 mm) needed to achieve adequate liberation of the mineral matter from the coal matrix. In froth flotation, selectivity is substantially reduced at fine sizes due, primarily, to overloading of the froth phase which leads to excessive carryover of water and entrained mineral matter. Oil agglomeration, on the other hand, can provide good selectivity at low levels of oil addition but the agglomerates tend to be too fragile for separation by the screening methods normally used. The addition of larger amounts of oil can yield large, strong agglomerates which are easily separated but the selectivity is reduced and reagent costs can become excessive. We are investigating the use of a hybrid process - Micro-agglomerate flotation which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30-50 mm in size) rather than individual coal particles (1-10 mm) the problems of froth overload and water/mineral carryover should be significantly alleviated. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  15. Orbital debris: A technical assessment

    NASA Technical Reports Server (NTRS)

    Gleghorn, George; Asay, James; Atkinson, Dale; Flury, Walter; Johnson, Nicholas; Kessler, Donald; Knowles, Stephen; Rex, Dietrich; Toda, Susumu; Veniaminov, Stanislav

    1995-01-01

    To acquire an unbiased technical assessment of (1) the research needed to better understand the debris environment, (2) the necessity and means of protecting spacecraft against the debris environment, and (3) potential methods of reducing the future debris hazard, NASA asked the National Research Council to form an international committee to examine the orbital debris issue. The committee was asked to draw upon available data and analyses to: characterize the current debris environment, project how this environment might change in the absence of new measures to alleviate debris proliferation, examine ongoing alleviation activities, explore measures to address the problem, and develop recommendations on technical methods to address the problems of debris proliferation.

  16. Riding a Trail of Debris

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1

    This image taken by NASA's Spitzer Space Telescope shows the comet Encke riding along its pebbly trail of debris (long diagonal line) between the orbits of Mars and Jupiter. This material actually encircles the solar system, following the path of Encke's orbit. Twin jets of material can also be seen shooting away from the comet in the short, fan-shaped emission, spreading horizontally from the comet.

    Encke, which orbits the Sun every 3.3 years, is well traveled. Having exhausted its supply of fine particles, it now leaves a long trail of larger more gravel-like debris, about one millimeter in size or greater. Every October, Earth passes through Encke's wake, resulting in the well-known Taurid meteor shower.

    This image was captured by Spitzer's multiband imaging photometer when Encke was 2.6 times farther away than Earth is from the Sun. It is the best yet mid-infrared view of the comet at this great distance. The data are helping astronomers understand how rotating comets eject particles as they circle the Sun.

  17. Orbital Debris Modeling

    NASA Technical Reports Server (NTRS)

    Liou, J. C.

    2012-01-01

    Presentation outlne: (1) The NASA Orbital Debris (OD) Engineering Model -- A mathematical model capable of predicting OD impact risks for the ISS and other critical space assets (2) The NASA OD Evolutionary Model -- A physical model capable of predicting future debris environment based on user-specified scenarios (3) The NASA Standard Satellite Breakup Model -- A model describing the outcome of a satellite breakup (explosion or collision)

  18. Influence of the nanoparticles agglomeration state in the quantum-confinement effects: Experimental evidences

    SciTech Connect

    Lorite, I.; Romero, J. J.; Fernandez, J. F.

    2015-03-15

    The agglomeration state facilitates particle-particle interaction which produces important effects in the phonon confinement effects at the nanoscale. A partial phonon transmission between close nanoparticles yields a lower momentum conservation relaxation than in a single isolated nanoparticle. It means a larger red shift and broadening of the Raman modes than the expected ones for Raman quantum confinement effects. This particle-particle interaction can drive to error when Raman responses are used to estimate the size of the nanoscaled materials. In this work different corrections are suggested to overtake this source of error.

  19. Agglomerating combustor-gasifier method and apparatus for coal gasification

    DOEpatents

    Chen, Joseph L. P.; Archer, David H.

    1976-09-21

    A method and apparatus for gasifying coal wherein the gasification takes place in a spout fluid bed at a pressure of about 10 to 30 atmospheres and a temperature of about 1800.degree. to 2200.degree.F and wherein the configuration of the apparatus and the manner of introduction of gases for combustion and fluidization is such that agglomerated ash can be withdrawn from the bottom of the apparatus and gas containing very low dust loading is produced. The gasification reaction is self-sustaining through the burning of a stoichiometric amount of coal with air in the lower part of the apparatus to form the spout within the fluid bed. The method and apparatus are particularly suitable for gasifying coarse coal particles.

  20. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.D.

    1993-04-01

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed boilers is in progress. Preliminary results indicate that at least five boilers were experiencing some form of bed material agglomeration. In these instances it was observed that large particles were forming within the bed which were larger that the feed. Four operators could confirm that the larger bed particles had formed due to bed particles sticking together or agglomerating. Deposit formation was reported at nine sites with these deposits being found most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Examples of these agglomerates and deposits have been received from five of the surveyed facilities. Also during this quarter, a bulk sample of Illinois No. 6 coal was obtained from the Fossil Energy Program at Ames Laboratory here at Iowa State University and prepared for combustion tests. This sample was first ground to a top-size of 3/8`` using a jaw crusher then a size fraction of 3/8`` {times} 8 (US mesh) was then obtained by sieving using a Gilson Test-Master. This size fraction was selected for the preliminary laboratory-scale experiments designed to simulate the dense bed conditions that exist in the bottom of CFB combustors. To ensure uniformity of fuel composition among combustion runs, the sized coal was riffled using, a cone and long row method and stored in bags for each experiment. During this quarter additional modifications were made to achieve better control of fluidization regimes and to aid in monitoring the hydrodynamic and chemical conditions within the reactor.

  1. Basic principles and mechanisms of selective oil agglomeration. Fossil energy interim report, October 1, 1983--September 30, 1992

    SciTech Connect

    Wheelock, T.D.

    1992-12-31

    Numerous agglomeration tests were conducted with several types of low-ash coal and graphite, high grade mineral pyrite, and other materials. Relatively pure hydrocarbons, including heptane and hexadecane, were used as agglomerants. Access of air to the system was controlled. Particle recovery by agglomeration was observed to depend on a number of system parameters. Among the most important parameters are the hydrophobicity of the particles and the oil dosage, so that the, recovery of solids per unit of oil administered is proportional to the hydrophobicity. The pH and ionic strength of the aqueous suspension affect particle recovery in different ways depending on the surface properties of the particles. On the other hand, the presence of air in the system generally improves particle recovery. The greatest effect of air was observed in a closely related study which showed that air had to be present to produce good agglomerates from a moderately hydrophobic coal in a mixer producing a lower shear rate. The rate of agglomeration was found to be much greater for a strongly hydrophobic coal than for a moderately hydrophobic coal, and the rate was observed to be proportional to the oil dosage. Also the rate was enhanced by the presence of air in the, system. For hydrophobic coals, the rate increased with increasing ionic strength of the aqueous medium, but it was not affected greatly by pH over a wide range. The separation of coal and pyrite particles by selective agglomeration was found to depend on the relative hydrophobicity of the materials, the oil dosage, and the properties of the aqueous medium.

  2. Agglomeration in Stripper Ash Coolers and Its Possible Remedial Solutions: a Case Study

    NASA Astrophysics Data System (ADS)

    Singh, Ravi Inder

    2016-04-01

    The bottom ash of circulating fluidized bed (CFB) boiler contains large amounts of physical heat. When low quality coals are used in these types of boilers, the ash content is normally more than 40 % and the physical heat loss is approximately 3 % if the bottom ash is discharged without cooling. Bottom ash cooler (BAC) is often used to treat the high temperature bottom ash to reclaim heat, and to facilitate the easily handling and transportation of ash. The CFB boiler at BLA Power, Newari, MP (India) is facing problems of clinker formation in strip ash coolers of plant since the installation of unit. These clinkers are basically agglomerates, which leads to defluidization of stripper ash cooler (BAC) units. There are two strip ash coolers in unit. Each strip ash cooler is capable of working independently. The proper functioning of both strip coolers is very important as it is going to increase the combustion efficiency of boiler by stripping of fine unburnt coal particles from ash, which are injected into the furnace. In this paper causes, characterization of agglomerates, thermo gravimetric analysis of fuel used, particular size distribution of coal and sand and possible remedial solution to overcome these agglomerates in strip ash coolers has also been presented. High temperature in compact separators, non uniform supply of coal and not removing small agglomerates from stripper ash cooler are among main causes of agglomeration in stripper ash cooler. Control of compact separator temperature, replacing 10-12 % of bed material and cleaning stripper ash cooler periodically will decrease agglomeration in stripper ash cooler of unit.

  3. Characterization of Debris from the DebriSat Hypervelocity Test

    NASA Technical Reports Server (NTRS)

    Rivero, M.; Kleespies, J.; Patankar, K.; Fitz-Coy, N.; Liou, J.-C.; Sorge, M.; Huynh, T.; Opiela, J.; Krisko, P.; Cowardin, H.

    2015-01-01

    The DebriSat project is an effort by NASA and the DoD to update the standard break-up model for objects in orbit. The DebriSat object, a 56 kg representative LEO satellite, was subjected to a hypervelocity impact in April 2014. For the hypervelocity test, the representative satellite was suspended within a "soft-catch" arena formed by polyurethane foam panels to minimize the interactions between the debris generated from the hypervelocity impact and the metallic walls of the test chamber. After the impact, the foam panels and debris not caught by the panels were collected and shipped to the University of Florida where the project has now advanced to the debris characterization stage. The characterization effort has been divided into debris collection, measurement, and cataloguing. Debris collection and cataloguing involves the retrieval of debris from the foam panels and cataloguing the debris in a database. Debris collection is a three-step process: removal of loose debris fragments from the surface of the foam panels; X-ray imaging to identify/locate debris fragments embedded within the foam panel; extraction of the embedded debris fragments identified during the X-ray imaging process. As debris fragments are collected, they are catalogued into a database specifically designed for this project. Measurement involves determination of size, mass, shape, material, and other physical properties and well as images of the fragment. Cataloguing involves a assigning a unique identifier for each fragment along with the characterization information.

  4. The Fast Debris Evolution Model

    NASA Astrophysics Data System (ADS)

    Lewis, Hugh G.; Swinerd, Graham; Newland, Rebecca; Saunders, Arrun

    The ‘Particles-in-a-box' (PIB) model introduced by Talent (1992) removed the need for computerintensive Monte Carlo simulation to predict the gross characteristics of an evolving debris environment. The PIB model was described using a differential equation that allows the stability of the low Earth orbit (LEO) environment to be tested by a straightforward analysis of the equation's coefficients. As part of an ongoing research effort to investigate more efficient approaches to evolutionary modelling and to develop a suite of educational tools, a new PIB model has been developed. The model, entitled Fast Debris Evolution (FaDE), employs a first-order differential equation to describe the rate at which new objects (˜ 10 cm) are added and removed from the environment. Whilst Talent (1992) based the collision theory for the PIB approach on collisions between gas particles and adopted specific values for the parameters of the model from a number of references, the form and coefficients of the FaDE model equations can be inferred from the outputs of future projections produced by high-fidelity models, such as the DAMAGE model. The FaDE model has been implemented as a client-side, web-based service using Javascript embedded within a HTML document. Due to the simple nature of the algorithm, FaDE can deliver the results of future projections immediately in a graphical format, with complete user-control over key simulation parameters. Historical and future projections for the ˜ 10 cm low Earth orbit (LEO) debris environment under a variety of different scenarios are possible, including business as usual, no future launches, post-mission disposal and remediation. A selection of results is presented with comparisons with predictions made using the DAMAGE environment model. The results demonstrate that the FaDE model is able to capture comparable time-series of collisions and number of objects as predicted by DAMAGE in several scenarios. Further, and perhaps more importantly

  5. Nucleocapsid Protein from Fig Mosaic Virus Forms Cytoplasmic Agglomerates That Are Hauled by Endoplasmic Reticulum Streaming

    PubMed Central

    Ishikawa, Kazuya; Miura, Chihiro; Maejima, Kensaku; Komatsu, Ken; Hashimoto, Masayoshi; Tomomitsu, Tatsuya; Fukuoka, Misato; Yusa, Akira; Yamaji, Yasuyuki

    2014-01-01

    ABSTRACT Although many studies have demonstrated intracellular movement of viral proteins or viral replication complexes, little is known about the mechanisms of their motility. In this study, we analyzed the localization and motility of the nucleocapsid protein (NP) of Fig mosaic virus (FMV), a negative-strand RNA virus belonging to the recently established genus Emaravirus. Electron microscopy of FMV-infected cells using immunogold labeling showed that NPs formed cytoplasmic agglomerates that were predominantly enveloped by the endoplasmic reticulum (ER) membrane, while nonenveloped NP agglomerates also localized along the ER. Likewise, transiently expressed NPs formed agglomerates, designated NP bodies (NBs), in close proximity to the ER, as was the case in FMV-infected cells. Subcellular fractionation and electron microscopic analyses of NP-expressing cells revealed that NBs localized in the cytoplasm. Furthermore, we found that NBs moved rapidly with the streaming of the ER in an actomyosin-dependent manner. Brefeldin A treatment at a high concentration to disturb the ER network configuration induced aberrant accumulation of NBs in the perinuclear region, indicating that the ER network configuration is related to NB localization. Dominant negative inhibition of the class XI myosins, XI-1, XI-2, and XI-K, affected both ER streaming and NB movement in a similar pattern. Taken together, these results showed that NBs localize in the cytoplasm but in close proximity to the ER membrane to form enveloped particles and that this causes passive movements of cytoplasmic NBs by ER streaming. IMPORTANCE Intracellular trafficking is a primary and essential step for the cell-to-cell movement of viruses. To date, many studies have demonstrated the rapid intracellular movement of viral factors but have failed to provide evidence for the mechanism or biological significance of this motility. Here, we observed that agglomerates of nucleocapsid protein (NP) moved rapidly

  6. Space debris hazard to defense systems

    SciTech Connect

    Canavan, G.H.

    1996-05-01

    Natural and man-made debris are argued to present hazards to space systems, but recent data indicate that at low altitudes, the impact rates from small particles may have been overestimated by an order of magnitude. At high altitudes, small particles only present an impact hazard to large satellites; they would not support a cascade. Large particles would apparently produce a cascade only on time scales of centuries or millennia. Radar and optical data should be capable of resolving these uncertainties, but their observations are, as yet, inconsistent. While independent analytic and numerical estimates of collision and cascade rates agree, given consistent inputs, different groups produced significantly different estimates of debris growth rates. This note examines the basis for these discrepancies.

  7. Development of a gas-promoted oil agglomeration process. Technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Zhang, F.; Nelson, C.

    1994-09-01

    The overall purpose of this research project is to carry out the preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal using model mixing systems. The design and construction of a model mixing system for conducting oil agglomeration tests were reported previously as well as the results of a series of calibration and shakedown tests. The system consists of a flat bottom tank which is fitted with four vertical baffles, a cover, and a turbine agitator. The tank has an inside diameter of 15.24 cm (6.0 in.), height of 15.24 cm (6.0 in.), and net volume of 2.87 L. The tank is connected to a photometric dispersion analyzer so that the turbidity of a coal particle suspension undergoing agglomeration can be monitored. Measuring the turbidity of a particle suspension requires application of the Beer-Lambert law. However, since this law applies for dilute suspensions, it is questionable whether or not it applies to the somewhat more concentrated coal suspensions required for the present project. Therefore, to determine the law`s applicability, a series of turbidity measurements was conducted on particle suspensions which varied in particle concentration over a wide range, and the results were analyzed to see how well they agreed with the law. To determine the effect of air in promoting the oil agglomeration of coal particles in an aqueous suspension, a number of agglomeration tests were conducted with the model mixing system. Finely ground Pittsburgh No. 8 coal was used for these tests, and the amount of air present was controlled carefully. The agglomeration process was monitored by observing the change in turbidity of the system.

  8. Agglomeration defects on irradiated carbon nanotubes

    SciTech Connect

    Steini Moura, Cassio; Balzaretti, Naira Maria; Amaral, Livio; Gribel Lacerda, Rodrigo; Pimenta, Marcos A.

    2012-03-15

    Aligned carbon nanotubes (CNT) were irradiated in the longitudinal and perpendicular directions, with low energy carbon and helium ions in order to observe the formation of defects in the atomic structure. Analysis through Raman spectroscopy and scanning electron microscopy indicated bundle rupture and ion track formation on nanotube bundles. Aligned CNT presented a kind of defect comprising ravine formation and tube agglomeration on top of the substrate. The latter structure is possibly caused by static charge accumulation induced by the incoming ions. Fluence plays a role on the short range order. Higher fluence irradiation transforms CNT into amorphous carbon nanowires.

  9. Debris flows in Grand Canyon National Park, Arizona: magnitude, frequency and effects on the Colorado River

    USGS Publications Warehouse

    Melis, Theodre S.; Webb, Robert H.

    1993-01-01

    Debris flows are recurrent sediment-transport processes in 525 tributaries of the Colorado River in Grand Canyon. Arizona. Initiated by slope failures in bedrock and (or) colluvium during intense rainfall, Grand Canyon debris flows are high-magnitude, short-duration floods. Debris flows in these tributaries transport very large boulders into the river where they accumulate on debris fans and form rapids. The frequency of debris flows range from less than 1 per century to 10 or more per century in these tributaries. Before regulation by Glen Canyon Dam in 1963, high-magnitude floods on the Colorado River reworked debris fans by eroding all particles except large boulders. Because flow regulation has substantially decreased the river's competence, debris flows occurring after 1963 have increased accumulation of finer-grained sediments on debris fans and in rapids.

  10. Benefits of Active Debris Removal on the LEO Debris Population

    NASA Astrophysics Data System (ADS)

    Maniwa, Kazuaki; Hanada, Toshiya; Kawamoto, Satomi

    Since the launch of Sputnik, orbital debris population continues to increase due to ongoing space activities, on-orbit explosions, and accidental collisions. In the future, a great deal of fragments can be expected to be created by explosions and collisions. In spite of prevention of satellite and rocket upper stage explosions and other mitigation measures, debris population in low Earth orbit may not be stabilized. To better limit the growth of the future debris population, it is necessary to remove the existing debris actively. This paper studies about the effectiveness of active debris removal in low Earth orbit where the collision rate with and between space debris is high. This study does not consider economic problems, but investigates removing debris which may stabilize well the current debris population based on the concept of Japan Aerospace Exploration Agency.

  11. Apparatus and method for compacting, degassing and carbonizing carbonaceous agglomerates

    SciTech Connect

    Theodore, F.W.

    1980-08-19

    An apparatus for compacting, degassing and carbonizing carbonaceous agglomerates is described. The apparatus comprises a rotary kiln having an agglomerate inlet means for introducing green agglomerates into the kiln near the inlet of the kiln and a heating medium inlet for introducing a heating medium comprising a finely divided solid into the kiln at a preselected location intermediate the inlet end of the kiln and the outlet end of the kiln to produce a mixture at a temperature above the carbonizing temperature of the agglomerates and a sieve positioned to receive the products from the rotary kiln and separate the heating medium and the compacted, degassed, carbonized agglomerate product. A method for producing compacted, degassed, carbonized carbonaceous agglomerates by the use of the apparatus is also disclosed.

  12. Space debris detection

    NASA Astrophysics Data System (ADS)

    Eather, Robert H.

    1992-12-01

    A feasibility study on the possibility of detecting less than or = 10 cm space debris using a large-aperture ground-based telescope (with an intensified CCD detector) was completed, showing that detection should be possible. A detector system was designed and built, and installed on the 2.54 m WRDC telescope at Wright Patterson AFB. Bad seeing conditions in the Dayton area prevented the expected debris detection. Subsequently, a small 40 cm telescope was built and operated from the Haystack Observatory (Groton, MA). Known objects were used to test pointing and acquisition procedures, and the system was then shipped to Rattlesnake Observatory (Richland, WA) for participation in the ODERAC's debris calibration experiment from the Space Shuttle. This experiment failed, and our instrument has been stored at Rattlesnake in anticipation of a new ODERAC's flight in late 1993.

  13. Density Estimations in Laboratory Debris Flow Experiments

    NASA Astrophysics Data System (ADS)

    Queiroz de Oliveira, Gustavo; Kulisch, Helmut; Malcherek, Andreas; Fischer, Jan-Thomas; Pudasaini, Shiva P.

    2016-04-01

    Bulk density and its variation is an important physical quantity to estimate the solid-liquid fractions in two-phase debris flows. Here we present mass and flow depth measurements for experiments performed in a large-scale laboratory set up. Once the mixture is released and it moves down the inclined channel, measurements allow us to determine the bulk density evolution throughout the debris flow. Flow depths are determined by ultrasonic pulse reflection, and the mass is measured with a total normal force sensor. The data were obtained at 50 Hz. The initial two phase material was composed of 350 kg debris with water content of 40%. A very fine pebble with mean particle diameter of 3 mm, particle density of 2760 kg/m³ and bulk density of 1400 kg/m³ in dry condition was chosen as the solid material. Measurements reveal that the debris bulk density remains high from the head to the middle of the debris body whereas it drops substantially at the tail. This indicates lower water content at the tail, compared to the head and the middle portion of the debris body. This means that the solid and fluid fractions are varying strongly in a non-linear manner along the flow path, and from the head to the tail of the debris mass. Importantly, this spatial-temporal density variation plays a crucial role in determining the impact forces associated with the dynamics of the flow. Our setup allows for investigating different two phase material compositions, including large fluid fractions, with high resolutions. The considered experimental set up may enable us to transfer the observed phenomena to natural large-scale events. Furthermore, the measurement data allows evaluating results of numerical two-phase mass flow simulations. These experiments are parts of the project avaflow.org that intends to develop a GIS-based open source computational tool to describe wide spectrum of rapid geophysical mass flows, including avalanches and real two-phase debris flows down complex natural

  14. Debris flow deposition and reworking by the Colorado River in Grand Canyon, Arizona

    NASA Astrophysics Data System (ADS)

    Yanites, Brian J.; Webb, Robert H.; Griffiths, Peter G.; Magirl, Christopher S.

    2006-11-01

    Flow regulation by large dams affects downstream flow competence and channel maintenance. Debris flows from 740 tributaries in Grand Canyon, Arizona, transport coarse-grained sediment onto debris fans adjacent to the Colorado River. These debris fans constrict the river to form rapids and are reworked during river flows that entrain particles and transport them downstream. Beginning in 1963, flood control operations of Glen Canyon Dam limited the potential for reworking of aggraded debris fans. We analyzed change in debris fans at the mouths of 75-Mile and Monument Creeks using photogrammetry of aerial photography taken from 1965 to 2000 and supplemented with ground surveys performed from 1987 to 2005. Our results quantify the debris fan aggradation that resulted from debris flows from 1984 to 2003. Volume, area, and river constriction increased at both debris fans. Profiles of the two debris fans show that net aggradation occurred in the middle of debris fans at stages above maximum dam releases, and surface shape shifted from concave to convex. Dam releases above power plant capacity partially reworked both debris fans, although reworking removed much less sediment than what was added by debris flow deposition. Large dam releases would be required to create additional reworking to limit the rate of debris fan aggradation in Grand Canyon.

  15. Debris flow deposition and reworking by the Colorado River in Grand Canyon, Arizona

    USGS Publications Warehouse

    Yanites, B.J.; Webb, R.H.; Griffiths, P.G.; Magirl, C.S.

    2006-01-01

    Flow regulation by large dams affects downstream flow competence and channel maintenance. Debris flows from 740 tributaries in Grand Canyon, Arizona, transport coarse-grained sediment onto debris fans adjacent to the Colorado River. These debris fans constrict the river to form rapids and are reworked during river flows that entrain particles and transport them downstream. Beginning in 1963, flood control operations of Glen Canyon Dam limited the potential for reworking of aggraded debris fans. We analyzed change in debris fans at the mouths of 75-Mile and Monument Creeks using photogrammetry of aerial photography taken from 1965 to 2000 and supplemented with ground surveys performed from 1987 to 2005. Our results quantify the debris fan aggradation that resulted from debris flows from 1984 to 2003. Volume, area, and river constriction increased at both debris fans. Profiles of the two debris fans show that net aggradation occurred in the middle of debris fans at stages above maximum dam releases, and surface shape shifted from concave to convex. Dam releases above power plant capacity partially reworked both debris fans, although reworking removed much less sediment than what was added by debris flow deposition. Large dam releases would be required to create additional reworking to limit the rate of debris fan aggradation in Grand Canyon.

  16. Hollow sphere ceramic particles for abradable coatings

    SciTech Connect

    Longo, F.N.; Bader, N.F. III; Dorfman, M.R.

    1984-05-22

    A hollow sphere ceramic flame spray powder is disclosed. The desired constituents are first formed into agglomerated particles in a spray drier. Then the agglomerated particles are introduced into a plasma flame which is adjusted so that the particles collected are substantially hollow. The hollow sphere ceramic particles are suitable for flame spraying a porous and abradable coating. The hollow particles may be selected from the group consisting of zirconium oxide and magnesium zirconate.

  17. Meteoroid/Debris Shielding

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.

    2003-01-01

    This report provides innovative, low-weight shielding solutions for spacecraft and the ballistic limit equations that define the shield's performance in the meteoroid/debris environment. Analyses and hypervelocity impact testing results are described that have been used in developing the shields and equations. Spacecraft shielding design and operational practices described in this report are used to provide effective spacecraft protection from meteoroid and debris impacts. Specific shield applications for the International Space Station (ISS), Space Shuttle Orbiter and the CONTOUR (Comet Nucleus Tour) space probe are provided. Whipple, Multi-Shock and Stuffed Whipple shield applications are described.

  18. Micrometeoroids and debris on LDEF

    NASA Technical Reports Server (NTRS)

    Mandeville, Jean-Claude

    1993-01-01

    Two experiments within the French Cooperative Payload (FRECOPA) and devoted to the detection of cosmic dust were flown on the Long Duration Exposure Facility (LDEF). A variety of sensors and collecting devices have made possible the study of impact processes on dedicated sensors and on materials of technological interest. Examination of hypervelocity impact features on these experiments gives valuable information on the size distribution and nature of interplanetary dust particles in low-Earth orbit (LEO), within the 0.5-300 micrometer size range. However no crater smaller than 1.5 microns has been observed, thus suggesting a cut-off in the near Earth particle distribution. Chemical investigation of craters by EDX clearly shows evidence of elements (Na, Mg, Si, S, Ca, and Fe) consistent with cosmic origin. However, remnants of orbital debris have been found in a few craters; this can be the result of particles in eccentric orbits about the Earth and of the 8 deg offset in the orientation of LDEF. Crater size distribution is compared with results from other dust experiments flown on LDEF and with current models. Possible origin and orbital evolution of micrometeoroids is discussed. Use of thin foil detectors for the chemical study of particle remnants looks promising for future experiments.

  19. Development of in-situ micro-debris measurement system

    NASA Astrophysics Data System (ADS)

    Nakamura, Maki; Kitazawa, Yukihito; Matsumoto, Haruhisa; Okudaira, Osamu; Hanada, Toshiya; Sakurai, Akira; Funakoshi, Kunihiro; Yasaka, Tetsuo; Hasegawa, Sunao; Kobayashi, Masanori

    2015-08-01

    The in-situ debris environment awareness system has been developed. The objective of the system is to measure small debris (between 100 μm and several cm) in orbit. The orbital distribution and the size distribution of the debris are not well understood. The size distribution is difficult to measure from the ground, although the size distribution is very important for the risk evaluation of the impact of debris on spacecraft. The in-situ measurement of the size distribution is useful for: (1) verification of meteoroid and debris environment models, (2) verification of meteoroid and debris environment evolution models, (3) real time detection of unexpected events, such as explosions and/or collisions on an orbit. This paper reports the development study of the in-situ debris measurement system and shows demonstration experiments and their results to describe the performance of the micro-debris sensor system. The sensor system for monitoring micro-debris with sizes ranging from 100 μm to a few mm must have a large detection area, while the constraints of space deployment require that these systems be low in mass, low in power, robust and have low telemetry requirements. For this reason, we have been developing a simple trans-film sensor. Thin and conductive stripes (copper) are formed with fine pitch (100 μm) on a thin film of nonconductive material (12.5-μm thick polyimide). A hypervelocity micro-particle impact is detected when one or more stripes are severed by perforation of the film. We designed a debris detector specialized for measuring the micro-debris size and collision rate. We then manufactured and calibrated the detector.

  20. The orbital debris detector consortium: Suppliers of instruments for in-situ measurements of small-particles in the space environment

    NASA Technical Reports Server (NTRS)

    Simon, C. G.; Muenzenmeyer, R.; Tanner, W. G., Jr.; Uy, O. M.; Skrivanek, R. A.; Tuzzolino, A. J.; Maag, C.; Wortman, J. J.

    1995-01-01

    Industry and university participants have joined together to form the IMPA:Ct consortium (In-situ Monitors of the Particulate Ambient: Circumterrestrial) which offers a broad range of flight qualified instruments for monitoring the small particle (0.1 micron to 10 cm) environment in space. Instruments are available in 12 months or less at costs ranging from 0.5 to 1.5 million dollars (US) for the total program. Detector technologies represented by these groups are: impact-induced capacitor-discharge (MOS, metal-oxide-silicon), cratering or penetration of electroactive thin film (polyvinylidene fluoride (PVDF)), impact-plasma detection, acoustic detection, CCD tracking of optical scatter of sunlight, and photodiode detection of optical scatter of laser light. The operational characteristics, general spacecraft interface and resource requirements (mass/power/telemetry), cost and delivery schedules, and points of contact for seven different instruments are presented.

  1. Method for recovering light hydrocarbons from coal agglomerates

    DOEpatents

    Huettenhain, Horst; Benz, August D.; Getsoian, John

    1991-01-01

    A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

  2. Development and Application of Agglomerated Multigrid Methods for Complex Geometries

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.

    2010-01-01

    We report progress in the development of agglomerated multigrid techniques for fully un- structured grids in three dimensions, building upon two previous studies focused on efficiently solving a model diffusion equation. We demonstrate a robust fully-coarsened agglomerated multigrid technique for 3D complex geometries, incorporating the following key developments: consistent and stable coarse-grid discretizations, a hierarchical agglomeration scheme, and line-agglomeration/relaxation using prismatic-cell discretizations in the highly-stretched grid regions. A signi cant speed-up in computer time is demonstrated for a model diffusion problem, the Euler equations, and the Reynolds-averaged Navier-Stokes equations for 3D realistic complex geometries.

  3. Agglomeration in a fluidized bed using multiple jet streams

    SciTech Connect

    Rehmat, A.; Abbasian, J. ); Kothari, M.; Hariri, H.; Arastoopour, H. )

    1992-01-01

    Tests were conducted to determine the overall temperature distribution, temperature in the vicinity of the jets, and the rate of agglomeration in a fluidized bed containing multiple jet streams. Agglomeration of ash during coal gasification increases carbon utilization efficiency considerably. The agglomeration requires a fluidized-bed reactor with a specially designed distributor equipped with a jet to yield a hot zone confined within the bed. The rate of agglomeration depends upon the size and the intensity of the zone. This rate, and hence the unit capacity, could be increased by adding multiple jets to the distributor. The purpose of this study was to verify this phenomenon. The temperature distribution inside the agglomerating fluidized-bed reactor with a single jet was studied by Hariri et al. Various parameters were involved in agglomeration phenomena -- bed material, fluidization velocity, bed temperature, jet velocity, jet temperature, bed geometry, and distributor geometry. Controlled agglomerates were produced in the fluidized bed when a sloped gas distributor consisting of a central jet and a porous plate was used. Gas at temperatures above the melting temperature of a bed material was introduced into the jet and gas at temperatures below the softening temperature was introduced into the distributor. The rate of agglomerate formation was significantly influenced by an increase in either jet air or auxiliary (grid) air temperature. The extent of agglomeration also depended strongly upon the volume of the hot zone confined within the isotherms with temperatures higher than the melting point of the bed material.

  4. Agglomeration in a fluidized bed using multiple jet streams

    SciTech Connect

    Rehmat, A.; Abbasian, J.; Kothari, M.; Hariri, H.; Arastoopour, H.

    1992-12-31

    Tests were conducted to determine the overall temperature distribution, temperature in the vicinity of the jets, and the rate of agglomeration in a fluidized bed containing multiple jet streams. Agglomeration of ash during coal gasification increases carbon utilization efficiency considerably. The agglomeration requires a fluidized-bed reactor with a specially designed distributor equipped with a jet to yield a hot zone confined within the bed. The rate of agglomeration depends upon the size and the intensity of the zone. This rate, and hence the unit capacity, could be increased by adding multiple jets to the distributor. The purpose of this study was to verify this phenomenon. The temperature distribution inside the agglomerating fluidized-bed reactor with a single jet was studied by Hariri et al. Various parameters were involved in agglomeration phenomena -- bed material, fluidization velocity, bed temperature, jet velocity, jet temperature, bed geometry, and distributor geometry. Controlled agglomerates were produced in the fluidized bed when a sloped gas distributor consisting of a central jet and a porous plate was used. Gas at temperatures above the melting temperature of a bed material was introduced into the jet and gas at temperatures below the softening temperature was introduced into the distributor. The rate of agglomerate formation was significantly influenced by an increase in either jet air or auxiliary (grid) air temperature. The extent of agglomeration also depended strongly upon the volume of the hot zone confined within the isotherms with temperatures higher than the melting point of the bed material.

  5. Orbital Debris: A Policy Perspective

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2007-01-01

    A viewgraph presentation describing orbital debris from a policy perspective is shown. The contents include: 1) Voyage through near-Earth Space-animation; 2) What is Orbital Debris?; 3) Orbital Debris Detectors and Damage Potential; 4) Hubble Space Telescope; 5) Mir Space Station Solar Array; 6) International Space Station; 7) Space Shuttle; 8) Satellite Explosions; 9) Satellite Collisions; 10) NASA Orbital Debris Mitigation Guidelines; 11) International Space Station Jettison Policy; 12) Controlled/Uncontrolled Satellite Reentries; 13) Return of Space Objects; 14) Orbital Debris and U.S. National Space Policy; 15) U.S Government Policy Strategy; 16) Bankruptcy of the Iridium Satellite System; 17) Inter-Agency Space Debris Coordination Committee (IADC); 18) Orbital Debris at the United Nations; 19) Chinese Anti-satellite System; 20) Future Evolution of Satellite Population; and 21) Challenge of Orbital Debris

  6. Constitutive Models for Debris-bearing Ice Layers

    NASA Astrophysics Data System (ADS)

    Moore, P. L.

    2013-12-01

    Rock debris is incorporated within many glaciers and ice sheets, particularly in basal ice layers and englacial debris bands. Field observations and laboratory experiments have shown that debris inclusions can both strengthen and weaken ice by as much as two orders of magnitude compared to debris-free ice under the same conditions. Nevertheless, models of glacier flow usually neglect any effect of debris-bearing layers. Where debris-bearing ice is present, proper treatment of its deformation could profoundly impact model results. A three-phase mechanical model is presented that reproduces many of the key observations of debris-bearing ice rheology. First order variables in the model are limited to debris concentration, particle size, solute concentration and temperature. At low debris concentrations (less than about 40% by volume), the mixture is treated under the framework of a dispersion-strengthened metal alloy but with a fluidity that is enhanced by premelted water at ice-debris interfaces. While debris strengthens the ice by interfering with the motion of dislocations, thermally-activated detachment can reduce the effect at temperatures close to melting. At these warm temperatures, recovery aided by unfrozen interfacial water acts to weaken the mixture, an effect that is further ehnanced by the presence of solutes at particle surfaces. Whether the debris-bearing ice is stronger or weaker than debris-free ice in the model depends strongly on the specific surface area of the debris and on a parameter that describes the thermal detachment of dislocations. As debris concentrations exceed about 40%, dispersion-strengthened ice flow still governs bulk deformation but the effective viscosity is further increased by enhanced strain rates in the ice "matrix" as the average inter-particle distance declines. At still higher concentrations (greater than about 52% by volume for sand), deformation is primarily frictional. The mixture is thus treated as a dilatant Coulomb

  7. Nanoparticle agglomerates of indomethacin: The role of poloxamers and matrix former on their dissolution and aerosolisation efficiency.

    PubMed

    Malamatari, Maria; Somavarapu, Satyanarayana; Bloxham, Mark; Buckton, Graham

    2015-11-10

    Nanoparticles (NPs) were prepared and assembled to microsized agglomerates with and without matrix formers (mannitol and L-leucine) by coupling wet milling and spray drying to harmonise the advantages of NPs with handling and aerodynamics of microparticles without induction of amorphisation. Indomethacin was selected as poorly water-soluble drug and poloxamers with different ratios of hydrophilic to hydrophobic domains were evaluated as stabilisers comparatively to D-α-Tocopherol polyethylene-glycol succinate (TPGS). Particle size of nanosuspensions and morphology, size, crystal form, drug loading, redispersibility, in vitro dissolution, and in vitro aerosolisation of NP-agglomerates were determined. Molecular weight of stabilisers affected the rate but not the limit of NP size reduction and the length of hydrophilic segment in poloxamers was found important for the nanosuspension stabilisation. SEM revealed the structure of agglomerates consisting of nanocrystal assemblies. XRPD with DSC proved that NP agglomerates retained their crystallinity. NP-agglomerates exhibited enhanced dissolution compared to physical mixtures of drug and stabilisers while incorporation of matrix formers enabled redispersibility upon hydration and further increased the drug dissolution. Also, matrix formers resulted in significantly improved aerosolisation with higher fine particle fractions (49-62%) and smaller mass median aerodynamic diameters (<3.5 μm), compared to cases without matrix formers (34-43% and <4.5 μm). PMID:26364709

  8. Influence of oxalic acid on the agglomeration process and total soda content in precipitated Al(OH) 3

    NASA Astrophysics Data System (ADS)

    Nikolić, I.; Blec̆ić, D.; Blagojević, N.; Radmilović, V.; Kovac̆ević, K.

    2003-05-01

    Decomposition of caustic soda solutions is an important part of Bayer process for alumina production. The physico-chemical properties of precipitated Al(OH) 3 are dependent on several processes that take place simultaneously during the decomposition process and they are: nucleation, agglomeration and Al(OH) 3 crystals. An important industrial requirement is increase of Al(OH) 3 crystal grain size, and hence agglomeration and growth of Al(OH) 3 crystals become important processes and they enable increase of particle size. The influence of oxalic acid concentration on the agglomeration process and total soda content in precipitated Al(OH) 3 at different temperatures and caustic soda concentrations has been investigated. The results have shown that the agglomeration process is increased with increase of temperature and decrease of caustic soda concentration. Total soda content in precipitated Al(OH) 3 is changed in the same way. Besides, agglomeration process of Al(OH) 3 particles is favored in the presence of oxalic acid.

  9. Fatigue life performance comparisons of tapered roller bearings with debris-damaged raceways{copyright}

    SciTech Connect

    Nixon, H.P.; Zantopulos, H.

    1995-09-01

    Debris-contaminated lubrication environments is inherent in many equipment applications and requires mechanical components that, as much as possible, are resistant to the potential effects of debris particles. Bearing fatigue life performance comparisons were made for various bearing materials and manufacturer origin, in order to assess the variability in performance of debris-damaged raceways. The evaluation was conducted using a repeatable debris-damaging process prior to fatigue testing of each group of bearings. The performance results reveal wide variations in the impact that debris damage can have on various bearing products and materials. 11 refs., 4 figs., 4 tabs.

  10. Space Debris Mitigation Guidelines

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2011-01-01

    The purpose of national and international space debris mitigation guides is to promote the preservation of near-Earth space for applications and exploration missions far into the future. To accomplish this objective, the accumulation of objects, particularly in long-lived orbits, must be eliminated or curtailed.

  11. Nearshore dynamics of artificial sand and oil agglomerates

    USGS Publications Warehouse

    Dalyander, P. Soupy; Plant, Nathaniel G.; Long, Joseph W.; McLaughlin, Molly R.

    2015-01-01

    Weathered oil can mix with sediment to form heavier-than-water sand and oil agglomerates (SOAs) that can cause beach re-oiling for years after a spill. Few studies have focused on the physical dynamics of SOAs. In this study, artificial SOAs (aSOAs) were created and deployed in the nearshore, and shear stress-based mobility formulations were assessed to predict SOA response. Prediction sensitivity to uncertainty in hydrodynamic conditions and shear stress parameterizations were explored. Critical stress estimates accounting for large particle exposure in a mixed bed gave the best predictions of mobility under shoaling and breaking waves. In the surf zone, the 10-cm aSOA was immobile and began to bury in the seafloor while smaller size classes dispersed alongshore. aSOAs up to 5 cm in diameter were frequently mobilized in the swash zone. The uncertainty in predicting aSOA dynamics reflects a broader uncertainty in applying mobility and transport formulations to cm-sized particles.

  12. Orbital Debris Shape and Orientation Effects on Ballistic Limits

    NASA Technical Reports Server (NTRS)

    Evans, Steven W.; Williamsen, Joel E.

    2005-01-01

    The SPHC hydrodynamic code was used to evaluate the effects of orbital debris particle shape and orientation on penetration of a typical spacecraft dual-wall shield. Impacts were simulated at near-normal obliquity at 12 km/sec. Debris cloud characteristics and damage potential are compared with those from impacts by spherical projectiles. Results of these simulations indicate the uncertainties in the predicted ballistic limits due to modeling uncertainty and to uncertainty in the impactor orientation.

  13. Characterizing Secondary Debris Impact Ejecta

    NASA Astrophysics Data System (ADS)

    Schonberg, W. P.

    1999-08-01

    All spacecraft in low-Earth orbit are subject to high-speed impacts by meteoroids and orbital debris particles. These impacts can damage flight-critical systems, which can in turn lead to catastrophic failure of the spacecraft. Therefore, the design of a spacecraft for an Earth-orbiting mission must take into account the possibility of such impacts and their effects on the spacecraft structure and on all of its exposed subsystem components. In addition to threatening the operation of the spacecraft itself, on-orbit impacts also generate a significant amount of ricochet particles. These high-speed particles can destroy critical external spacecraft subsystems and also increase the contamination of the orbital environment. This report presents a summary of the work performed towards the development of an empirical model that characterizes the secondary ejecta created by a high-speed impacta on a typical aerospace structural surface. This report presents a summary of the work performed towards the development of an empirical model that characterizes the secondary ejecta created by a high-speed impact on a typical aerospace structural surface.

  14. Agglomeration multigrid for viscous turbulent flows

    NASA Technical Reports Server (NTRS)

    Mavriplis, D. J.; Venkatakrishnan, V.

    1994-01-01

    Agglomeration multigrid, which has been demonstrated as an efficient and automatic technique for the solution of the Euler equations on unstructured meshes, is extended to viscous turbulent flows. For diffusion terms, coarse grid discretizations are not possible, and more accurate grid transfer operators are required as well. A Galerkin coarse grid operator construction and an implicit prolongation operator are proposed. Their suitability is evaluated by examining their effect on the solution of Laplace's equation. The resulting strategy is employed to solve the Reynolds-averaged Navier-Stokes equations for aerodynamic flows. Convergence rates comparable to those obtained by a previously developed non-nested mesh multigrid approach are demonstrated, and suggestions for further improvements are given.

  15. Soot agglomeration in isolated, free droplet combustion

    NASA Technical Reports Server (NTRS)

    Choi, M. Y.; Dryer, F. L.; Green, G. J.; Sangiovanni, J. J.

    1993-01-01

    Under the conditions of an isolated, free droplet experiment, hollow, carbonaceous structures, called soot spheres, were observed to form during the atmospheric pressure, low Reynolds number combustion of 1-methylnaphthalene. These structures which are agglomerates composed of smaller spheroidal units result from both thermophoretic effects induced by the envelope flame surrounding each drop and aerodynamic effects caused by changes in the relative gas/drop velocities. A chemically reacting flow model was used to analyze the process of sootshell formation during microgravity droplet combustion. The time-dependent temperature and gas property field surrounding the droplet was determined, and the soot cloud location for microgravity combustion of n-heptane droplets was predicted. Experiments showed that the sooting propensity of n-alkane fuel droplets can be varied through diluent substitution, oxygen-index variations, and ambient pressure reductions.

  16. Pulse combusted acoustic agglomeration apparatus and process

    DOEpatents

    Mansour, Momtaz N.; Chandran, Ravi

    1994-01-01

    An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance agglomeration of particulates which may be collected and removed using a conventional separation apparatus. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, added particulates may include a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

  17. Pulse combusted acoustic agglomeration apparatus and process

    DOEpatents

    Mansour, Momtaz N.

    1993-01-01

    An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance bimodal agglomeration of particulates which may be collected and removed using a conventional separation apparatus. A particulate having a size different from the size of the particulate in the gas stream to be cleaned is introduced into the system to effectuate the bimodal process. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, the added particulate may be a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

  18. GEO Debris Observation of PMO

    NASA Astrophysics Data System (ADS)

    Ping, Yiding; Zhao, Changyin; Zhao, Haibin

    2009-03-01

    This paper summarizes observations and results obtained by Purple Mountain Observatory in March 2007 of space debris at geosynchronous orbit (GEO) in support of WG1 Action Item 23.4, International 2007 Optical Debris Campaign in Higher Earth Orbit, organized by the Inter-Agency Space Debris Coordination Committee (IADC). The main goal of Pmo's work is to develop the observational techniques of Higher Earth Orbit Space debris for the future work. A new telescope designed for debris observation is also described here.

  19. The Collisional Evolution of Debris Disks

    NASA Astrophysics Data System (ADS)

    Gáspár, A.; Rieke, G. H.; Psaltis, D.; Özel, F.; Balog, Z.

    2014-03-01

    With their discovery, debris disks gave the first proof of existence of extrasolar planetary systems (Aumann et al. 1984, Smith & Terrile 1984). Although extrasolar planets are now readily detected, the importance of debris disks in characterizing their host systems is not diminished. Debris disks are relatively easy to detect at infrared wavelengths, independent of their viewing angle; they enable the study of the dynamical evolution of their host systems; they are able to reveal the outer regions of the systems where planets are difficult to detect; and coronagraphic scattered light images show the active sites of major dust production within the systems. During their operational lifetime, the Spitzer Space Telescope and the Herschel Space Observatory have observed many hundreds of resolved and unresolved debris disks. These detections have helped us characterize the thermal emission and also location of the disks. The observations have also shown a general decay in the observed infrared luminosity of the debris disks as a function of system age and disk location. This evolution must be understood thoroughly before probing other parameters, such as their dependence on stellar metallicity or binarity. A second critical parameter is the shape of the particle size distribution, which can strongly influence conclusions from spectral energy distribution models. I will describe results obtained with our collisional cascade code, which has been optimized to study the time evolution of debris disk dust. I will show that the rate of the decay varies throughout the evolution of the disks, increasing its rate up to a certain point, which is followed by a leveling off to a value of Lir(t)~-0.6. This is slower than the ~-1 decay given by traditional analytic models. I will show how our numerical code can reproduce the fraction of detected debris disk sources within an extensive catalog of Spitzer and Herschel 24, 70, and 100 µm observations (Gaspar et al. 2013). I will also

  20. Biological effects of agglomerated multi-walled carbon nanotubes.

    PubMed

    Song, Zheng-Mei; Wang, Lin; Chen, Ni; Cao, Aoneng; Liu, Yuanfang; Wang, Haifang

    2016-06-01

    The physicochemical properties of nanomaterials play crucial roles in determining their biological effects. Agglomeration of nanomaterials in various systems is a common phenomenon, however, how agglomeration affects the biological consequence of nanomaterials has not been well investigated because of its complexity. Herein, we prepared variable sized agglomerates of oxidized multi-walled carbon nanotubes (O-MWCNTs) by using Ca(2+) and studied their cellular uptake and cytotoxicity in HeLa cells. We found the altered property of O-MWCNTs agglomerates could be controlled and adjusted by the amount of Ca(2+). Agglomeration remarkably facilitated the cellular uptake of O-MWCNTs at the initial contact stage, due to the easy contact of agglomerates with cells. But agglomeration did not induce evident cytotoxicity when the concentration of O-MWCNTs was less than 150μg/mL. That was assayed by cell proliferation, membrane integrity, apoptosis and ROS generation. This study suggests us that the biological behaviors of nanomaterials could be altered by their states of agglomeration. PMID:26930035

  1. Measuring agglomerate size distribution and dependence of localized surface plasmon resonance absorbance on gold nanoparticle agglomerate size using analytical ultracentrifugation.

    PubMed

    Zook, Justin M; Rastogi, Vinayak; Maccuspie, Robert I; Keene, Athena M; Fagan, Jeffrey

    2011-10-25

    Agglomeration of nanoparticles during measurements in relevant biological and environmental media is a frequent problem in nanomaterial property characterization. The primary problem is typically that any changes to the size distribution can dramatically affect the potential nanotoxicity or other size-determined properties, such as the absorbance signal in a biosensor measurement. Herein we demonstrate analytical ultracentrifugation (AUC) as a powerful method for measuring two critical characteristics of nanoparticle (NP) agglomerates in situ in biological media: the NP agglomerate size distribution, and the localized surface plasmon resonance (LSPR) absorbance spectrum of precise sizes of gold NP agglomerates. To characterize the size distribution, we present a theoretical framework for calculating the hydrodynamic diameter distribution of NP agglomerates from their sedimentation coefficient distribution. We measure sedimentation rates for monomers, dimers, and trimers, as well as for larger agglomerates with up to 600 NPs. The AUC size distributions were found generally to be broader than the size distributions estimated from dynamic light scattering and diffusion-limited colloidal aggregation theory, an alternative bulk measurement method that relies on several assumptions. In addition, the measured sedimentation coefficients can be used in nanotoxicity studies to predict how quickly the agglomerates sediment out of solution under normal gravitational forces, such as in the environment. We also calculate the absorbance spectra for monomer, dimer, trimer, and larger gold NP agglomerates up to 600 NPs, to enable a better understanding of LSPR biosensors. Finally, we validate a new method that uses these spectra to deconvolute the net absorbance spectrum of an unknown bulk sample and approximate the proportions of monomers, dimers, and trimers in a polydisperse sample of small agglomerates, so that every sample does not need to be measured by AUC. These results

  2. Activities on Space Debris in U.S.

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2001-01-01

    In the U.S. space debris activities are addressed at all government levels, from the Executive Office of the President to the individual federal agencies to specialized centers, laboratories, organizations, and research groups. U.S. Space Policy specifically challenges government agencies to seek to minimize the creation of space debris and to promote debris minimization practices both domestically and internationally. A set of space debris mitigation standard practices has been developed and adopted by relevant US government agencies, and their application by the commercial aerospace community is highly encouraged. A growing number of US government agencies have issued their own space debris mitigation policies, directives, regulations, and standards. Space debris research, including the definition and modeling of the current and future near-Earth space environment and the development of debris protection technologies, is principally conducted by NASA and the Department of Defense. The U.S. Space Surveillance Network continues to provide the most complete and timely characterization of the population of space debris larger than 10 cm. During the past several years major advancements have been achieved in extending this environment definition in LEO to include particles as small as only a few millimeters. The inspection of returned spacecraft surfaces continues to shed light on the even smaller debris population. With improvements in computer technology, new and more capable programs have been and are being developed to solve a number of operational and research problems. Finally, the academic and industrial sectors of the U.S. are also increasing their participation in and contributions to space debris operations and research. The cooperation of satellite and launch vehicle developers and operators is essential to the U.S. objective of promoting the preservation of the space environment for future generations.

  3. Activities on space debris in U.S.

    NASA Astrophysics Data System (ADS)

    Johnson, Nicholas L.

    2001-10-01

    In the U.S. space debris activities are addressed at all government levels, from the Executive Office of the President to the individual federal agencies to specialized centers, laboratories, organizations, and research groups. U.S. Space Policy specifically challenges government agencies to seek to minimize the creation of space debris and to promote debris minimization practices, both domestically and internationally. A set of space debris mitigation standard practices has been developed and adopted by relevant U.S. government agencies, and their application by the commercial aerospace community is highly encouraged. A growing number of U.S. government agencies have issued their own space debris mitigation policies, directives, regulations, and standards. Space debris research, including the definition and modeling of the current and future near-Earth space environment and the development of debris protection technologies, is principally conducted by NASA and the Department of Defense. The U.S. Space Surveillance Network continues to provide the most complete and timely characterization of the population of space debris larger than 10 cm. During the past several years major advancements have been achieved in extending this environment definition in LEO to include particles as small as only a few millimeters. The inspection of returned spacecraft surfaces continues to shed light on the even smaller debris population. With improvements in computer technology, new and more capable programs have been and are being developed to solve a number of operational and research problems. Finally, the academic and industrial sectors of the U.S. are also increasing their participation in and contributions to space debris operations and research. The cooperation of spacecraft and launch vehicle developers and operators is essential to the U.S. objective of promoting the preservation of the space environment for future generations.

  4. AMG by element agglomeration and constrained energy minimization interpolation

    SciTech Connect

    Kolev, T V; Vassilevski, P S

    2006-02-17

    This paper studies AMG (algebraic multigrid) methods that utilize energy minimization construction of the interpolation matrices locally, in the setting of element agglomeration AMG. The coarsening in element agglomeration AMG is done by agglomerating fine-grid elements, with coarse element matrices defined by a local Galerkin procedure applied to the matrix assembled from the individual fine-grid element matrices. This local Galerkin procedure involves only the coarse basis restricted to the agglomerated element. To construct the coarse basis, one exploits previously proposed constraint energy minimization procedures now applied to the local matrix. The constraints are that a given set of vectors should be interpolated exactly, not only globally, but also locally on every agglomerated element. The paper provides algorithmic details, as well as a convergence result based on a ''local-to-global'' energy bound of the resulting multiple-vector fitting AMG interpolation mappings. A particular implementation of the method is illustrated with a set of numerical experiments.

  5. Agglomeration multigrid for the three-dimensional Euler equations

    NASA Technical Reports Server (NTRS)

    Venkatakrishnan, V.; Mavriplis, D. J.

    1994-01-01

    A multigrid procedure that makes use of coarse grids generated by the agglomeration of control volumes is advocated as a practical approach for solving the three dimensional Euler equations on unstructured grids about complex configurations. It is shown that the agglomeration procedure can be tailored to achieve certain coarse grid properties such as the sizes of the coarse grids and aspect ratios of the coarse grid cells. The agglomeration is done as a preprocessing step and runs in linear time. The implications for multigrid of using arbitrary polyhedral coarse grids are discussed. The agglomeration multigrid technique compares very favorably with existing multigrid procedures both in terms of convergence rates and elapsed times. The main advantage of the present approach is the ease with which coarse grids of any desired degree of coarseness may be generated in three dimensions, without being constrained by considerations of geometry. Inviscid flows over a variety of complex configurations are computed using the agglomeration multigrid strategy.

  6. Agglomeration processes sustained by dust density waves in Ar/C{sub 2}H{sub 2} plasma: From C{sub 2}H{sub 2} injection to the formation of an organized structure

    SciTech Connect

    Dap, Simon; Hugon, Robert; Poucques, Ludovic de; Briancon, Jean-Luc; Bougdira, Jamal; Lacroix, David

    2013-03-15

    In this paper, an experimental investigation of dust particle agglomeration in a capacitively coupled RF discharge is reported. Carbonaceous particles are produced in an argon plasma using acetylene. As soon as the particle density becomes sufficient, dust density waves (DDWs) are spontaneously excited within the cathode sheath. Recently, it was proven that DDWs can significantly enhance the agglomeration rate between particles by transferring them a significant kinetic energy. Thus, it helps them to overcome Coulomb repulsion. The influence of this mechanism is studied from acetylene injection to the formation of very large agglomerates forming an organized structure after a few dozens of seconds. For this purpose, three diagnostic tools are used: extinction measurements to probe nanometer-sized particles, fast imaging for large agglomerates and a dust extraction technique developed for ex-situ analysis.

  7. Effect of drug content and agglomerate size on tabletability and drug release characteristics of bromhexine hydrochloridetalc agglomerates prepared by crystallo-co-agglomeration.

    PubMed

    Jadhav, Namdeo; Pawar, Atmaram; Paradkar, Anant

    2010-03-01

    The objective of the investigation was to study the effect of bromhexine hydrochloride (BXH) content and agglomerate size on mechanical, compressional and drug release properties of agglomerates prepared by crystallo-co-agglomeration (CCA). Studies on optimized batches of agglomerates (BXT1 and BXT2) prepared by CCA have showed adequate sphericity and strength required for efficient tabletting. Trend of strength reduction with a decrease in the size of agglomerates was noted for both batches, irrespective of drug loading. However, an increase in mean yield pressure (14.189 to 19.481) with an increase in size was observed for BXT2 having BXH-talc (1:15.7). Surprisingly, improvement in tensile strength was demonstrated by compacts prepared from BXT2, due to high BXH load, whereas BXT1, having a low amount of BXH (BXH-talc, 1:24), showed low tensile strength. Consequently, increased tensile strength was reflected in extended drug release from BXT2 compacts (Higuchi model, R(2) = 0.9506 to 0.9981). Thus, it can be concluded that interparticulate bridges formed by BXH and agglomerate size affect their mechanical, compressional and drug release properties. PMID:20228039

  8. Interplanetary meteoroid debris in LDEF metal craters

    NASA Technical Reports Server (NTRS)

    Brownlee, D. E.; Joswiak, D.; Bradley, J.; Hoerz, Friedrich

    1993-01-01

    We have examined craters in Al and Au LDEF surfaces to determine the nature of meteoroid residue in the rare cases where projectile material is abundantly preserved in the crater floor. Typical craters contain only small amounts of residue and we find that less than 10 percent of the craters in Al have retained abundant residue consistent with survival of a significant fraction (greater than 20 percent) of the projectile mass. The residue-rich craters can usually be distinguished optically because their interiors are darker than ones with little or no apparent projectile debris. The character of the meteoroid debris in these craters ranges from thin glass liners, to thick vesicular glass containing unmelted mineral fragments, to debris dominated by unmelted mineral fragments. In the best cases of meteoroid survival, unmelted mineral fragments preserve both information on projectile mineralogy as well as other properties such as nuclear tracks caused by solar flare irradiation. The wide range of the observed abundance and alteration state of projectile residue is most probably due to differences in impact velocity. The crater liners are being studied to determine the composition of meteoroids reaching the Earth. The compositional types most commonly seen in the craters are: (1) chondritic (Mg, Si, S, Fe in approximately solar proportions), (2) Mg silicate. amd (3) iron sulfide. These are also the most common compositional types of extraterrestrial particle types collected in the stratosphere. The correlation between these compositions indicates that vapor fractionation was not a major process influencing residue composition in these craters. Although the biases involved with finding analyzable meteoroid debris in metal craters differ from those for extraterrestrial particles collected in and below the atmosphere, there is a common bias favoring particles with low entry velocity. For craters this is very strong and probably all of the metal craters with abundant

  9. Development and Flight Demonstration of Space Debris Monitor (SDM)

    NASA Astrophysics Data System (ADS)

    Kitazawa, Yukihito; Hanada, Toshiya; Matsumoto, Haruhisa; Kobayashi, Masanori; Sakurai, Akira; Yasaka, Tetsuo; Funakoshi, Kunihiro; Hasegawa, Sunao; Akahoshi, Yasuhiro; Kimoto, Yugo; Okudaira, Osamu; Kamiya, Koki; Nakamura, Maki

    2016-07-01

    The space debris monitor (SDM) is a large-area impact sensor for in situ measurements of micro-meteoroids and space debris of the sub-millimeter to millimeter size in the near-Earth space environment. These meteoroid and debris particles are very small to be detected by ground-based observations (radars and optical telescopes) but are sufficiently large to cause serious damage to spacecraft equipment in the low Earth orbit region. The nominal detection area of the SDM is 0.1 m^2 (0.35 m × 0.3 m), but its dimensions can be easily modified to accommodate different SDM constraints. The SDM is made from a flexible printed circuit, which is produced from a thin film of a nonconductive material (such as polyimide) on which thin conductive stripes are formed in parallel. The stripe width is approximately 50 μm, and the spatial separation is approximately 100 μm, as shown in Figure 1. When a micro-debris particle with an effective diameter near to or larger than the spatial separation of the stripes (here approximately 100 μm) collides with the sensor film at a velocity sufficient to penetrate it, one or more of the stripes are cut and become nonconductive. Debris impacts can thus be detected by monitoring the electrical conductivity (resistivity) of the stripes. This sensor system can measure the size of the incident micro-debris particles by detecting the number of severed stripes. The measurement concept is registered as a patent in many countries. The first SDM was launched with HTV-5 on August 19, 2015 and represented the world's first micro-debris measurement demonstration experiment to be conducted on the ISS using the concept of conductive (resistive) strip lines for real-time debris detection.

  10. Colloidal nanoparticles produced from Cu metal in water by laser ablation and their agglomeration

    NASA Astrophysics Data System (ADS)

    Im, Hee-Jung; Jung, Euo Chang

    2016-01-01

    Colloidal nanoparticles were prepared from Cu metal in water without any surfactant using a simple one-step laser ablation process with 532 nm Nd-YAG beam irradiation. A surface plasmon band of Cu nanoparticles near 580 nm was not observed; instead, oxidation of the Cu colloidal nanoparticles was noticed. This seems to be due to the partially oxidized copper oxides through the route Cu→Cu2O→CuO. Around 10-nm sized colloidal nanoparticles were agglomerated as a result of oxidation according to the time elapsed, and their sizes were increased to near 200 nm. The agglomeration was confirmed by not only images from transmission electron microscopy but also the long-term observation of the particle size distribution using photon correlation spectroscopy, laser-induced breakdown detection, and field flow fractionation.

  11. Orbital debris measurements

    NASA Technical Reports Server (NTRS)

    Kessler, D. J.

    1986-01-01

    What is currently known about the orbital debris flux is from a combination of ground based and in-space measurements. These measurements have revealed an increasing population with decreasing size. A summary of measurements is presented for the following sources: the North American Aerospace Defense Command Catalog, the Perimeter Acquisition and Attack Characterization System Radar, ground based optical telescopes, the Explorer 46 Meteoroid Bumper Experiment, spacecraft windows, and Solar Max surfaces.

  12. Diamond-like-carbon nanoparticle production and agglomeration following UV multi-photon excitation of static naphthalene/helium gas mixtures.

    PubMed

    Walsh, A J; Tielens, A G G M; Ruth, A A

    2016-07-14

    We report the formation of nanoparticles with significant diamond character after UV multi-photon laser excitation of gaseous naphthalene, buffered in static helium gas, at room temperature. The nanoparticles are identified in situ by their absorption and scattering spectra between 400 and 850 nm, which are modeled using Mie theory. Comparisons of the particles' spectroscopic and optical properties with those of carbonaceous materials indicate a sp(3)/sp(2) hybridization ratio of 8:1 of the particles formed. The particle extinction in the closed static (unstirred) gas-phase system exhibits a complex and quasi-oscillatory time dependence for the duration of up to several hours with periods ranging from seconds to many minutes. The extinction dynamics of the system is based on a combination of transport features and particle interaction, predominantly agglomeration. The relatively long period of agglomeration allows for a unique analysis of the agglomeration process of diamond-like carbon nanoparticles in situ. PMID:27421401

  13. Diamond-like-carbon nanoparticle production and agglomeration following UV multi-photon excitation of static naphthalene/helium gas mixtures

    NASA Astrophysics Data System (ADS)

    Walsh, A. J.; Tielens, A. G. G. M.; Ruth, A. A.

    2016-07-01

    We report the formation of nanoparticles with significant diamond character after UV multi-photon laser excitation of gaseous naphthalene, buffered in static helium gas, at room temperature. The nanoparticles are identified in situ by their absorption and scattering spectra between 400 and 850 nm, which are modeled using Mie theory. Comparisons of the particles' spectroscopic and optical properties with those of carbonaceous materials indicate a sp3/sp2 hybridization ratio of 8:1 of the particles formed. The particle extinction in the closed static (unstirred) gas-phase system exhibits a complex and quasi-oscillatory time dependence for the duration of up to several hours with periods ranging from seconds to many minutes. The extinction dynamics of the system is based on a combination of transport features and particle interaction, predominantly agglomeration. The relatively long period of agglomeration allows for a unique analysis of the agglomeration process of diamond-like carbon nanoparticles in situ.

  14. Debris Characterization Diagnostic for the National Ignition Facility

    SciTech Connect

    Miller, M.C.; Celeste, J.R. Stoyer, M.A.; Suter, L.J.; Tobin, M.T.; Grun, J.; Davis, J.F.; Barnes, C.W.; Wilson, D.C.

    2000-06-07

    Generation of debris from targets and by x-ray ablation of surrounding materials will be a matter of concern for experimenters and the operations staff at the National Ignition Facility (NIF). Target chamber and final optics protection, for example debris shield damage, and efficient facility operation drive the interest for the NIF staff. Experimenters are primarily concerned with diagnostic survivability, separation of mechanical versus radiation induced test object response in the case of effects tests, and radiation transport through the debris field when the net radiation output is used to benchmark computer codes. In addition, radiochemical analysis of activated capsule debris during ignition shots can provide a measure of the ablator. Conceptual design of the Debris Monitor and Rad-Chem Station, one of the NIF core diagnostics, is presented. Methods of debris collection, particle size and mass analysis, impulse measurement, and radiochemical analysis are given. A description of recent experiments involving debris collection and impulse measurement on the OMEGA and Pharos lasers is also provided.

  15. Operational source receptor calculations for large agglomerations

    NASA Astrophysics Data System (ADS)

    Gauss, Michael; Shamsudheen, Semeena V.; Valdebenito, Alvaro; Pommier, Matthieu; Schulz, Michael

    2016-04-01

    For Air quality policy an important question is how much of the air pollution within an urbanized region can be attributed to local sources and how much of it is imported through long-range transport. This is critical information for a correct assessment of the effectiveness of potential emission measures. The ratio between indigenous and long-range transported air pollution for a given region depends on its geographic location, the size of its area, the strength and spatial distribution of emission sources, the time of the year, but also - very strongly - on the current meteorological conditions, which change from day to day and thus make it important to provide such calculations in near-real-time to support short-term legislation. Similarly, long-term analysis over longer periods (e.g. one year), or of specific air quality episodes in the past, can help to scientifically underpin multi-regional agreements and long-term legislation. Within the European MACC projects (Monitoring Atmospheric Composition and Climate) and the transition to the operational CAMS service (Copernicus Atmosphere Monitoring Service) the computationally efficient EMEP MSC-W air quality model has been applied with detailed emission data, comprehensive calculations of chemistry and microphysics, driven by high quality meteorological forecast data (up to 96-hour forecasts), to provide source-receptor calculations on a regular basis in forecast mode. In its current state, the product allows the user to choose among different regions and regulatory pollutants (e.g. ozone and PM) to assess the effectiveness of fictive emission reductions in air pollutant emissions that are implemented immediately, either within the agglomeration or outside. The effects are visualized as bar charts, showing resulting changes in air pollution levels within the agglomeration as a function of time (hourly resolution, 0 to 4 days into the future). The bar charts not only allow assessing the effects of emission

  16. Space Debris Modeling at NASA

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2001-01-01

    Since the Second European Conference on Space Debris in 1997, the Orbital Debris Program Office at the NASA Johnson Space Center has undertaken a major effort to update and improve the principal software tools employed to model the space debris environment and to evaluate mission risks. NASA's orbital debris engineering model, ORDEM, represents the current and near-term Earth orbital debris population from the largest spacecraft to the smallest debris in a manner which permits spacecraft engineers and experimenters to estimate the frequency and velocity with which a satellite may be struck by debris of different sizes. Using expanded databases and a new program design, ORDEM2000 provides a more accurate environment definition combined with a much broader array of output products in comparison with its predecessor, ORDEM96. Studies of the potential long-term space debris environment are now conducted with EVOLVE 4.0, which incorporates significant advances in debris characterization and breakup modeling. An adjunct to EVOLVE 4.0, GEO EVOLVE has been created to examine debris issues near the geosynchronous orbital regime. In support of NASA Safety Standard 1740.14, which establishes debris mitigation guidelines for all NASA space programs, a set of evaluation tools called the Debris Assessment Software (DAS) is specifically designed for program offices to determine whether they are in compliance with NASA debris mitigation guidelines. DAS 1.5 has recently been released with improved WINDOWS compatibility and graphics functions. DAS 2.0 will incorporate guideline changes in a forthcoming revision to NASA Safety Standard 1740.14. Whereas DAS contains a simplified model to calculate possible risks associated with satellite reentries, NASA's higher fidelity Object Reentry Survival Analysis Tool (ORSAT) has been upgraded to Version 5.0. With the growing awareness of the potential risks posed by uncontrolled satellite reentries to people and property on Earth, the

  17. Crystal growth and agglomeration of calcium sulfite hemihydrate crystals

    SciTech Connect

    Tai, C.Y.; Chen, P.C.

    1995-04-01

    Flue gas desulfurization (FGD) processes are most commonly utilized to remove sulfur dioxide from stack gases of coal- or oil-fired plants. In the simple slurry technology, SO{sub 2} is absorbed by a slurry of lime/limestone to form calcium sulfite crystals of acicular habit and its strong agglomeration, requiring large clarifiers and filters to dewater the sludge to make an acceptable landfill. Crystal growth and agglomeration of calcium sulfite hemihydrate crystals from solution were studied by reacting Ca(OH){sub 2} with NaHSO{sub 3} in a pH-stat semibatch crystallizer. Single platelet crystals and agglomerates of platelet crystals were produced in the pH range from 5.80 to 6.80. The crystallization mechanism changed from primary nucleation to crystal growth in the progressive precipitation. Using the titration curves, the growth rate was calculated from the titration rate at the final stage of operation. The crystal growth rates of calcium sulfate hemihydrate crystals were found to obey the parabolic rate law in the low supersaturation range. Another point to be noted is that the precipitates of calcium sulfite hemihydrate in agitated suspensions have a tendency to form agglomerates. It was found that the degree of agglomeration is a weak function of relative supersaturation and magma density, while the pH value is a key factor that affects the degree of agglomeration. Addition of EDTA also has an effect on the agglomeration of calcium sulfite hemihydrates.

  18. Engineering development of selective agglomeration. Executive summary: Final report

    SciTech Connect

    Not Available

    1993-04-01

    Project performance targets for the selective agglomeration process were to achieve 85% or greater Btu recovery at 85% or greater pyritic sulfur rejection (PSR) on a run-of-mine (ROM) coal basis, while producing a final clean-coal product with an ash content of 6% or less which is handleable by conventional coal handling systems. Engineering development of selective agglomeration included: (1) Batch and continuous bench-scale precess development testing; (2) Continuous pilot-scale (3-t/h) component development testing to evaluate the adaptation and/or modification of existing unit operations for selective agglomeration; (3) Continuous pilot-scale (2-t/h) POC testing to optimize the selective agglomeration process and demonstrate precess reliability; (4) Vendor testing to evaluate pelletization and thermal drying precesses as applied to selective agglomeration; (5) Conceptual design of a commercial-scale (200-V/h) selective agglomeration facility; (6) Economic analysis of the selective agglomeration precess at a commercial (200-t/h) scale. The information obtained from the various modes of testing and analysis, particularly POC operations, resulted in a technical and economic design base sufficient to support construction and operation of a commercial plant.

  19. Analysis of atmospheric fluidized bed combustion agglomerates. Final report

    SciTech Connect

    Perkins, D. III; Brekke, D.W.; Karner, F.R.

    1984-04-01

    Chemical and textural studies of AFBC agglomerates have revealed detailed information regarding the mechanisms of agglomeration. The formation of agglomerates in a silica sand bed can be described by a four step process: initial ash coatings of quartz grains; thickening of ash coatings and the formation of nodules; cementation of nodules to each other by a sulfated aluminosilicate matrix; and partial or complete melting of eutectic compositions to produce a sticky glass phase between grains and along fractures. Once agglomeration has begun, large scale solidification and restricted flow within the bed will lead to hot spots, wholesale melting and further agglomeration which ultimately forces a shutdown. Standard operating temperatures during normal AFBC runs come quite close to, or may actually exceed, the minimum temperatures for eutectic melting of the silicate phases in the coal and standard bed materials. The partially melted material may be expected to lead to the formation of dense, sticky areas within the bed, and the formation of hot spots which further exacerbate the problem. Ultimately, large scale bed agglomeration will result. Attempts to eliminate agglomeration by removal of sodium via an ion exchange process have yielded encouraging results. A second approach, used to raise melting temperatures within the bed, has been to use bed materials that may react with low-temperature minerals to produce high-temperature refractory phases such as mullite or other alkali and alkali-earth alumino-silicates.

  20. Capillary condensation onto titania (TiO2) nanoparticle agglomerates.

    PubMed

    Kim, Seonmin; Ehrman, Sheryl H

    2007-02-27

    A capillary condensation process was developed for the purpose of forming interconnections between nanoparticles at low temperatures. The process was performed in a temperature-controlled flow chamber on nanoparticle agglomerates deposited at submonolayer coverage on a transmission electron microscope grid. The partial pressure of the condensing species, tetraethyl orthosilicate, and the temperature of the chamber were adjusted in order to obtain the various saturation conditions for capillary condensation. The modified samples were characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, BET surface area method, and scanning transmission electron microscopy with electron energy-loss spectrometry. Experimental results show that bridge-shaped layers were dominantly formed in the neck region between particles and were composed of amorphous silica. The analysis of TEM micrographs verified that the coverage of the layers is strongly dependent on the saturation ratio. Image analysis of TEM micrographs shows that this dependency is qualitatively in agreement with theoretical predictions based on the classical Kelvin equation for the specific geometries in our system. PMID:17243733

  1. Design of orbital debris shields for oblique hypervelocity impact

    NASA Astrophysics Data System (ADS)

    Fahrenthold, Eric P.

    1994-02-01

    A new impact debris propagation code was written to link CTH simulations of space debris shield perforation to the Lagrangian finite element code DYNA3D, for space structure wall impact simulations. This software (DC3D) simulates debris cloud evolution using a nonlinear elastic-plastic deformable particle dynamics model, and renders computationally tractable the supercomputer simulation of oblique impacts on Whipple shield protected structures. Comparison of three dimensional, oblique impact simulations with experimental data shows good agreement over a range of velocities of interest in the design of orbital debris shielding. Source code developed during this research is provided on the enclosed floppy disk. An abstract based on the work described was submitted to the 1994 Hypervelocity Impact Symposium.

  2. Shields for Enhanced Protection Against High-Speed Debris

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.; Kerr, Justin H.

    2003-01-01

    A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arises mainly from breakup of older spacecraft. The improved shields include exterior "bumper" layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cubic cm, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

  3. Shields for Enhanced Protection Against High-Speed Debris

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.; Kerr, Justin H.

    2003-01-01

    A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arise mainly from breakup of older spacecraft. The improved shields include exterior bumper layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cm3, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape-memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

  4. Design of orbital debris shields for oblique hypervelocity impact

    NASA Technical Reports Server (NTRS)

    Fahrenthold, Eric P.

    1994-01-01

    A new impact debris propagation code was written to link CTH simulations of space debris shield perforation to the Lagrangian finite element code DYNA3D, for space structure wall impact simulations. This software (DC3D) simulates debris cloud evolution using a nonlinear elastic-plastic deformable particle dynamics model, and renders computationally tractable the supercomputer simulation of oblique impacts on Whipple shield protected structures. Comparison of three dimensional, oblique impact simulations with experimental data shows good agreement over a range of velocities of interest in the design of orbital debris shielding. Source code developed during this research is provided on the enclosed floppy disk. An abstract based on the work described was submitted to the 1994 Hypervelocity Impact Symposium.

  5. Debris flows from tributaries of the Colorado River, Grand Canyon National Park, Arizona; executive summary

    USGS Publications Warehouse

    Webb, R.H.

    1987-01-01

    Debris flows are a major process of sediment transport to the Colorado River from ungaged tributaries in Grand Canyon National Park, Arizona. Debris flows are slurries of clay to boulder-sized particles of large magnitude and short duration that occur infrequently. They are the source for potential large volumes of sand for beaches on the Colorado River. Debris flows create and maintain hydraulic controls (rapids) on the Colorado River at tributary mouths. (See also W89-09240) (Author 's abstract)

  6. A CCD search for geosynchronous debris

    NASA Technical Reports Server (NTRS)

    Gehrels, Tom; Vilas, Faith

    1986-01-01

    Using the Spacewatch Camera, a search was conducted for objects in geosynchronous earth orbit. The system is equipped with a CCD camera cooled with dry ice; the image scale is 1.344 arcsec/pixel. The telescope drive was off so that during integrations the stars were trailed while geostationary objects appeared as round images. The technique should detect geostationary objects to a limiting apparent visual magnitude of 19. A sky area of 8.8 square degrees was searched for geostationary objects while geosynchronous debris passing through was 16.4 square degrees. Ten objects were found of which seven are probably geostationary satellites having apparent visual magnitudes brighter than 13.1. Three objects having magnitudes equal to or fainter than 13.7 showed motion in the north-south direction. The absence of fainter stationary objects suggests that a gap in debris size exists between satellites and particles having diameters in the millimeter range.

  7. Review of ash agglomeration in fluidized bed gasifiers

    SciTech Connect

    Matulevicius, E.S.; Golan, L.P.

    1984-07-01

    The purpose of this study is to review the data and mathematical models which describe the phenomena involved in the agglomeration of ash in fluidized bed coal gasifiers (FBG). Besides highlighting the data and theoretical models, this review lists areas where there is a lack of information regarding the actual mechanisms of agglomeration. Also, potential areas for further work are outlined. The work is directed at developing models of agglomeration which could be included in computer codes describing fluidized bed gasifier phenomena, e.g., FLAG and CHEMFLUB which have been developed for the US Department of Energy. 134 references, 24 figures, 13 tables.

  8. Agglomeration of proteins in acoustically levitated droplets.

    PubMed

    Delissen, Friedmar; Leiterer, Jork; Bienert, Ralf; Emmerling, Franziska; Thünemann, Andreas F

    2008-09-01

    An ultrasonic trap (acoustic levitator) was used as an analytical tool to allow container-free handling of proteins in small sample volumes. This trap was combined for the first time with synchrotron small-angle X-ray scattering (SAXS) for structure analysis of biological macromolecules in a solution. The microfocus beamline at BESSY was used as a source of intense X-ray radiation. Apoferritin (APO) was used as a model protein, and its aggregation behavior in a levitator was followed from a diluted solution to the solid state. Different stages of APO agglomeration were observed without solid container walls, which may influence aggregation behavior and produce a parasitic scattering background. Starting with a volume of 5 microL we analyzed the concentration dependence of APO structure factors in the range from 5 to 1,200 mg/mL (solid protein). The solution was stirred automatically due to convection inside the droplet caused by the ultrasonic field. SAXS data recording of APO was performed in time intervals of 60 s during an aggregation experiment of 30 to 60 min. PMID:18607573

  9. MEO Debris Environment Projection Study

    NASA Astrophysics Data System (ADS)

    Jenkin, Alan B.; Sorge, Marlon E.; McVey, John P.; Peterson, Glenn E.; Yoo, Bernard Y.

    2013-08-01

    The recently developed Aerospace Debris Environment Projection Tool was used to project the future debris environment in medium Earth orbit (MEO) over the next 200 years. The entire Earth orbital population was modeled to account for the possibility of cross-coupling between the MEO population and the low Earth orbit (LEO) and geosynchronous populations via objects on highly eccentric orbits that transit through MEO. It was found that a large fraction of the MEO debris originated from collisions in LEO involving satellites and rocket bodies that transit through LEO and MEO. Results showed that world-wide compliance with orbit lifetime reduction will significantly reduce the amount of debris in MEO.

  10. Current Issues in Orbital Debris

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2011-01-01

    During the past two decades, great strides have been made in the international community regarding orbital debris mitigation. The majority of space-faring nations have reached a consensus on an initial set of orbital debris mitigation measures. Implementation of and compliance with the IADC and UN space debris mitigation guidelines should remain a high priority. Improvements of the IADC and UN space debris mitigation guidelines should continue as technical consensus permits. The remediation of the near-Earth space environment will require a significant and long-term undertaking.

  11. Agglomeration-Free Distributor for Fluidized Beds

    NASA Technical Reports Server (NTRS)

    Ouyang, F.; Sinica, A.; Levenspiel, O.

    1986-01-01

    New gas distributor for fluidized beds prevents hot particles from reacting on it and forming hard crust. In reduction of iron ore in fluidized bed, ore particles do not sinter on distributor and perhaps clog it or otherwise interfere with gas flow. Distributor also relatively cool. In fluidized-bed production of silicon, inflowing silane does not decompose until within bed of hot silicon particles and deposits on them. Plates of spiral distributor arranged to direct incoming gas into spiral flow. Turbulence in flow reduces frequency of contact between fluidized-bed particles and distributor.

  12. Diffusion mediated agglomeration of CdS nanoparticles via Langmuir–Blodgett technique

    SciTech Connect

    Das, Nayan Mani Roy, Dhrubojyoti; Gupta, P.S.

    2013-10-15

    Graphical abstract: - Highlights: • Diffusion mediated agglomeration of CdS nanoparticles are discussed. • Formation of CdS nanoparticles are confirmed by the change of chain length in XRD. • AFM shows the agglomeration of particles with a film swelling of about 5 Å. • UV–vis absorbance suggests that the grown particles show quantum confinement. • Hexagonal form of particle was confirmed by UV–vis reflectivity. - Abstract: We have reported a diffusion mediated agglomeration of cadmium sulphide (CdS) nanoparticles within cadmium arachidate (CdA{sub 2}) film matrix. The structural morphology and formation of CdS nanoparticles are characterized by X-ray diffraction (XRD), X-ray reflectivity (XRR), atomic force microscopy (AFM) and ultraviolet-visible spectroscopy techniques. X-ray diffraction (XRD) results show a change in bilayer difference from 53.04 Å to 43 Å after the sulphidation. An epitaxial growth of the films by ∼5 Å after sulphidation is confirmed from atomic force microscopy studies. The particle size calculated form UV–vis absorption edges are found to be varying from 2.6 nm to 3.3 nm for the different layers. A lateral dimension of 72–80 nm from AFM measurements and a size of 2.6–3.3 nm have confirmed one side flat pseudo two-dimensional disk-like nanoparticles. UV–vis reflectivity peak at E{sub 1} (A) confirms the formation of hexagonal CdS nanoparticles along the c-axis.

  13. Microplastic debris in sandhoppers

    NASA Astrophysics Data System (ADS)

    Ugolini, A.; Ungherese, G.; Ciofini, M.; Lapucci, A.; Camaiti, M.

    2013-09-01

    Adults of the sandhopper Talitrus saltator were fed with dry fish food mixed with polyethylene microspheres (diameter 10-45 μm). Observations of homogenized guts revealed the presence of microspheres independently of their dimensions. The gut resident time (GRT) was recorded and most of the microspheres are expelled in 24 h. Microspheres are totally expelled in one week. Preliminary investigations did not show any consequence of microsphere ingestion on the survival capacity in the laboratory. FT-IR analyses carried out on faeces of freshly collected individuals revealed the presence of polyethylene and polypropylene. This confirms that microplastic debris could be swallowed by T. saltator in natural conditions.

  14. Space Debris Hazard Evaluation

    NASA Technical Reports Server (NTRS)

    Davison, Elmer H.; Winslow, Paul C., Jr.

    1961-01-01

    The hazard to space vehicles from natural space debris has been explored. A survey of the available information pertinent to this problem is presented. The hope is that this presentation gives a coherent picture of the knowledge to date in terms of the topic covered. The conclusion reached is that a definite hazard exists but that it can only be poorly assessed on the basis of present information. The need for direct measurement of this hazard is obvious, and some of the problems involved in making these direct measurements have been explored.

  15. Column oil agglomeration of fly ash with ultrasonics

    SciTech Connect

    Gray, M.L.; Champagne, K.J.; Soong, Y.; Finseth, D.H.

    1999-07-01

    A promising oil agglomeration process has been developed for the beneficiation of fly ash using a six-foot agglomeration column. Carbon concentrates have been separated from fly ash with yields greater than 60 % and purities of 55 to 74 %. The parameters examined in the study include ultrasonic exposure, pulse rate, frequency, agitation speed, and blade configuration. The effects of the experimental variables on the quality of separation are discussed.

  16. Dispersion of TiO₂ nanoparticle agglomerates by Pseudomonas aeruginosa.

    PubMed

    Horst, Allison M; Neal, Andrea C; Mielke, Randall E; Sislian, Patrick R; Suh, Won Hyuk; Mädler, Lutz; Stucky, Galen D; Holden, Patricia A

    2010-11-01

    Engineered nanoparticles are increasingly incorporated into consumer products and are emerging as potential environmental contaminants. Upon environmental release, nanoparticles could inhibit bacterial processes, as evidenced by laboratory studies. Less is known regarding bacterial alteration of nanoparticles, including whether bacteria affect physical agglomeration states controlling nanoparticle settling and bioavailability. Here, the effects of an environmental strain of Pseudomonas aeruginosa on TiO₂ nanoparticle agglomerates formed in aqueous media are described. Environmental scanning electron microscopy and cryogenic scanning electron microscopy visually demonstrated bacterial dispersion of large agglomerates formed in cell culture medium and in marsh water. For experiments in cell culture medium, quantitative image analysis verified that the degrees of conversion of large agglomerates into small nanoparticle-cell combinations were similar for 12-h-growth and short-term cell contact experiments. Dispersion in cell growth medium was further characterized by size fractionation: for agglomerated TiO₂ suspensions in the absence of cells, 81% by mass was retained on a 5-μm-pore-size filter, compared to only 24% retained for biotic treatments. Filtrate cell and agglomerate sizes were characterized by dynamic light scattering, revealing that the average bacterial cell size increased from 1.4 μm to 1.9 μm because of nano-TiO₂ biosorption. High-magnification scanning electron micrographs showed that P. aeruginosa dispersed TiO₂ agglomerates by preferential biosorption of nanoparticles onto cell surfaces. These results suggest a novel role for bacteria in the environmental transport of engineered nanoparticles, i.e., growth-independent, bacterially mediated size and mass alterations of TiO₂ nanoparticle agglomerates. PMID:20851981

  17. De-agglomeration Effect of the US Pharmacopeia and Alberta Throats on Carrier-Based Powders in Commercial Inhalation Products.

    PubMed

    Leung, Sharon Shui Yee; Tang, Patricia; Zhou, Qi Tony; Tong, Zhenbo; Leung, Cassandra; Decharaksa, Janwit; Yang, Runyu; Chan, Hak-Kim

    2015-11-01

    The US pharmacopeia (USP) and Alberta throats were recently reported to cause further de-agglomeration of carrier-free powders emitted from some dry powder inhalers (DPIs). This study assessed if they have similar influences on commercially available carrier-based DPIs. A straight tube, a USP throat, and an Alberta throat (non-coated and coated) were used for cascade impaction testing. Aerosol fine particle fraction (FPF ≤ 5 μm) was computed to evaluate throat-induced de-agglomeration. Computational fluid dynamics are employed to simulate airflow patterns and particle trajectories inside the USP and Alberta throats. For all tested products, no significant differences in the in vitro aerosol performance were observed between the USP throat and the straight tube. Using fine lactose carriers (<10 μm), Symbicort(®) and Oxis(™) showed minimal impaction inside the Alberta throat and resulted in similar FPF among all induction ports. For products using coarse lactose carriers (>10 μm), impaction frequency and energy inside the Alberta throat were significant. Further de-agglomeration was noted inside the non-coated Alberta throat for Seretide(®) and Spiriva(®), but agglomerates emitted from Relenza(®), Ventolin(®), and Foradil(®) did not further break up into smaller fractions. The coated Alberta throat considerably reduced the FPF values of these products due to the high throat retention, but they generally agreed better with the in vivo data. In conclusion, depending on the powder formulation (including carrier particle size), the inhaler, and the induction port, further de-agglomeration could happen ex-inhaler and create differences in the in vitro measurements. PMID:26201967

  18. Solid Hydrogen Particles Analyzed for Atomic Fuels

    NASA Technical Reports Server (NTRS)

    Palaszewski, Bryan A.

    2001-01-01

    Solid hydrogen particles have been selected as a means of storing atomic propellants in future launch vehicles (refs. 1 to 2). In preparation for this, hydrogen particle formation in liquid helium was tested experimentally. These experiments were conducted to visually characterize the particles and to observe their formation and molecular transformations (aging) while in liquid helium. The particle sizes, molecular transformations, and agglomeration times were estimated from video image analyses. The experiments were conducted at the NASA Glenn Research Center in the Supplemental Multilayer Insulation Research Facility (SMIRF, ref. 3). The facility has a vacuum tank, into which the experimental setup was placed. The vacuum tank prevented heat leaks and subsequent boiloff of the liquid helium, and the supporting systems maintained the temperature and pressure of the liquid helium bath where the solid particles were created. As the operation of the apparatus was developed, the hydrogen particles were easily visualized. The figures (ref. 1) show images from the experimental runs. The first image shows the initial particle freezing, and the second image shows the particles after the small particles have agglomerated. The particles finally all clump, but stick together loosely. The solid particles tended to agglomerate within a maximum of 11 min, and the agglomerate was very weak. Because the hydrogen particles are buoyant in the helium, the agglomerate tends to compact itself into a flat pancake on the surface of the helium. This pancake agglomerate is easily broken apart by reducing the pressure above the liquid. The weak agglomerate implies that the particles can be used as a gelling agent for the liquid helium, as well as a storage medium for atomic boron, carbon, or hydrogen. The smallest particle sizes that resulted from the initial freezing experiments were about 1.8 mm. About 50 percent of the particles formed were between 1.8 to 4.6 mm in diameter. These very

  19. Quantum dot agglomerates in biological media and their characterization by asymmetrical flow field-flow fractionation.

    PubMed

    Moquin, Alexandre; Neibert, Kevin D; Maysinger, Dusica; Winnik, Françoise M

    2015-01-01

    The molecular composition of the biological environment of nanoparticles influences their physical properties and changes their pristine physicochemical identity. In order to understand, or predict, the interactions of cells with specific nanoparticles, it is critical to know their size, shape, and agglomeration state not only in their nascent state but also in biological media. Here, we use asymmetrical flow field-flow fractionation (AF4) with on-line multiangle light scattering (MALS), dynamic light scattering (DLS) and UV-Visible absorption detections to determine the relative concentration of isolated nanoparticles and agglomerates in the case of three types of semi-conductor quantum dots (QDs) dispersed in Dulbecco's Modified Eagle Media (DMEM) containing 10% of fetal bovine serum (DMEM-FBS). AF4 analysis also yielded the size and size distribution of the agglomerates as a function of the time of QDs incubation in DMEM-FBS. The preferred modes of internalization of the QDs are assessed for three cell-types, N9 microglia, human hepatocellular carcinoma cells (HepG2) and human embryonic kidney cells (Hek293), by confocal fluorescence imaging of live cells, quantitative determination of the intracellular QD concentration, and flow cytometry. There is an excellent correlation between the agglomeration status of the three types of QDs in DMEM-FBS determined by AF4 analysis and their preferred mode of uptake by the three cell lines, which suggests that AF4 yields an accurate description of the nanoparticles as they encounter cells and advocates its use as a means to characterize particles under evaluation. PMID:25542679

  20. Space debris executive summary

    SciTech Connect

    Canavan, G.H.; Judd, O.; Naka, R.F.

    1996-09-01

    Spacecraft, boosters, and fragments are potential hazards to space vehicles, and it is argued that collisions between them could produce a cascade that could preclude activity in LEO in 25 to 50 years. That has generated pressure for constraints on military space operations, so the AF SAB performed a study of technical aspects of the debris problem. The Study was independent of the efforts of the Air Force Space Command (AFSPC) as well as those of and NASA Johnson Space Center (JSC), which is the principal advocate for cascades and constraints. Most work on space debris has been performed by AFSPC and JSC, so the Study was in part an assessment of their efforts, in which both have been cooperative. The Study identified the main disagreements and quantified their impacts. It resolved some issues and provided bounds for the rest. It treated radar and optical observations; launch, explosion, and decay rates; and the number and distribution of fragments from explosions and collisions. That made it possible to address hazard to manned spacecraft at low altitudes and the possibility of cascading at higher altitudes, both of which now appear less likely.

  1. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  2. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.; Potas, Todd A.; DeWall, Raymond A.; Musich, Mark A.

    1992-01-01

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  3. Failure Analysis in Space: International Space Station (ISS) Starboard Solar Alpha Rotary Joint (SARJ) Debris Analysis

    NASA Technical Reports Server (NTRS)

    Long, V. S.; Wright, M. C.; McDanels, S. J.; Lubas, D.; Tucker, B.; Marciniak, P. J.

    2010-01-01

    This slide presentation reviews the debris analysis of the Starboard Solar Alpha Rotary Joint (SARJ), a mechanism that is designed to keep the solar arrays facing the sun. The goal of this was to identify the failure mechanism based on surface morphology and to determine the source of debris through elemental and particle analysis.

  4. Space debris modeling at NASA

    NASA Astrophysics Data System (ADS)

    Johnson, Nicholas L.

    2001-10-01

    Since the Second European Conference on Space Debris in 1997, the Orbital Debris Program Office at the NASA Johnson Space Center has undertaken a major effort to update and improve the principal software tools employed to model the space debris environment and to evaluate mission risks. NASA's orbital debris engineering model, ORDEM, represents the current and near-term Earth orbital debris population from the largest spacecraft to the smallest debris in a manner which permits spacecraft engineers and experimenters to estimate the frequency and velocity with which a satellite may be struck by debris of different sizes. Using expanded databases and a new program design, ORDEM2000 provides a more accurate environment definition combined with a much broader array of output products in comparison with its predecessor, ORDEM96. Studies of the potential long-term space debris environment are now conducted with EVOVLE 4.0, which incorporates significant advances in debris characterization and breakup modeling. An adjunct to EVOLVE 4.0, GEO EVOLVE has been created to examine debris issues near the geosynchronous orbital regime. In support of NASA Safety Standard (NSS) 1740.14, which establishes debris mitigation guidelines for all NASA space programs, a set of evaluation tools called the Debris Assessment Software (DAS) is specifically designed for program offices to determine whether they are in compliance with NASA debris mitigation guidelines. DAS 1.5 has recently been completed with improved WINDOWS compatibility and graphics functions. DAS 2.0 will incorporate guideline changes in a forthcoming revision to NSS 1740.14. Whereas DAS contains a simplified model to calculate possible risks associated with satellite reentries, NASA's higher fidelity Object Reentry Survival Analysis Tool (ORSAT) has been upgraded to Version 5.0. With the growing awareness of the potential risks posed by uncontrolled satellite reentries to people and property on Earth, the application of

  5. TMI-2 core debris-cesium release/settling test. Volume 3

    SciTech Connect

    Akers, D W; Johnson, D A

    1984-12-01

    Cesium release, turbidity and airborne potential tests were conducted on 50 grams of TMI-2 core debris materials. The tests were performed on the debris in two conditions: on the as-received core debris specimen, and after crushing the debris to alter the particle size distribution. The crushing was intended to simulate the breakup of TMI-2 core material that may occur during reactor defueling. These tests are intended to assist GPU Nuclear in predicting the effect of defueling on the reactor environment.

  6. The Challenge of Orbital Debris

    NASA Technical Reports Server (NTRS)

    Matney, Mark

    2012-01-01

    Since the dawn of the Space Age more than 50 years ago, humans have been launching objects into the space environment faster than they have been removed by active means or natural decay. This has led to a proliferation of debris -- derelict satellites, discarded rocket upper stages, and pieces from satellite breakups -- in Earth orbit, especially in well-used orbital regimes. This talk will summarize the current knowledge of the debris environment and describe plans to address the challenges orbital debris raises for the future usability of near-Earth space. The talk will be structured around 4 categories: Measurements, Modeling, Shielding, and Mitigation. This will include discussions of the long-term prognosis of debris growth (i.e., the "Kessler Syndrome") as well as plans for active debris removal.

  7. Plastic debris in the open ocean

    PubMed Central

    Cózar, Andrés; Echevarría, Fidel; González-Gordillo, J. Ignacio; Irigoien, Xabier; Úbeda, Bárbara; Hernández-León, Santiago; Palma, Álvaro T.; Navarro, Sandra; García-de-Lomas, Juan; Ruiz, Andrea; Fernández-de-Puelles, María L.; Duarte, Carlos M.

    2014-01-01

    There is a rising concern regarding the accumulation of floating plastic debris in the open ocean. However, the magnitude and the fate of this pollution are still open questions. Using data from the Malaspina 2010 circumnavigation, regional surveys, and previously published reports, we show a worldwide distribution of plastic on the surface of the open ocean, mostly accumulating in the convergence zones of each of the five subtropical gyres with comparable density. However, the global load of plastic on the open ocean surface was estimated to be on the order of tens of thousands of tons, far less than expected. Our observations of the size distribution of floating plastic debris point at important size-selective sinks removing millimeter-sized fragments of floating plastic on a large scale. This sink may involve a combination of fast nano-fragmentation of the microplastic into particles of microns or smaller, their transference to the ocean interior by food webs and ballasting processes, and processes yet to be discovered. Resolving the fate of the missing plastic debris is of fundamental importance to determine the nature and significance of the impacts of plastic pollution in the ocean. PMID:24982135

  8. Plastic debris in the open ocean.

    PubMed

    Cózar, Andrés; Echevarría, Fidel; González-Gordillo, J Ignacio; Irigoien, Xabier; Ubeda, Bárbara; Hernández-León, Santiago; Palma, Alvaro T; Navarro, Sandra; García-de-Lomas, Juan; Ruiz, Andrea; Fernández-de-Puelles, María L; Duarte, Carlos M

    2014-07-15

    There is a rising concern regarding the accumulation of floating plastic debris in the open ocean. However, the magnitude and the fate of this pollution are still open questions. Using data from the Malaspina 2010 circumnavigation, regional surveys, and previously published reports, we show a worldwide distribution of plastic on the surface of the open ocean, mostly accumulating in the convergence zones of each of the five subtropical gyres with comparable density. However, the global load of plastic on the open ocean surface was estimated to be on the order of tens of thousands of tons, far less than expected. Our observations of the size distribution of floating plastic debris point at important size-selective sinks removing millimeter-sized fragments of floating plastic on a large scale. This sink may involve a combination of fast nano-fragmentation of the microplastic into particles of microns or smaller, their transference to the ocean interior by food webs and ballasting processes, and processes yet to be discovered. Resolving the fate of the missing plastic debris is of fundamental importance to determine the nature and significance of the impacts of plastic pollution in the ocean. PMID:24982135

  9. Orbital debris removal and salvage system

    NASA Technical Reports Server (NTRS)

    1990-01-01

    Four Texas A&M University projects are discussed. The first project is a design to eliminate a majority of orbital debris. The Orbital Debris and Salvage System will push the smaller particles into lower orbits where their orbits will decay at a higher rate. This will be done by momentum transfer via laser. The salvageable satellites will be delivered to the Space Station by an Orbital Transfer Vehicle. The rest of the debris will be collected by Salvage I. The second project is the design of a space based satellite system to prevent the depletion of atmospheric ozone. The focus is on ozone depletion in the Antarctic. The plan is to use an orbiting solar array system designed to transmit microwaves at a frequency of 22 GHz over the region in order to dissipate polar stratospheric clouds that form during the months beginning in August and ending in October. The third project, Project Poseidon, involves a conceptual design of a space based hurricane control system consisting of a network of 21 low-orbiting laser platforms arranged in three rings designed to heat the upper atmosphere of a developing tropical depression. Fusion power plants are proposed to provide power for the lasers. The fourth project, Project Donatello, involves a proposed Mars exploration initiative for the year 2050. The project is a conceptual design for a futuristic superfreighter that will transport large numbers of people and supplies to Mars for the construction of a full scale scientific and manufacturing complex.

  10. Summary of Disposable Debris Shields (DDS) Analysis for Development of Solid Debris Collection at NIF

    SciTech Connect

    Shaughnessy, D A; Moody, K J; Grant, P M; Lewis, L A; Hutcheon, I D; Lindvall, R; Gostic, J M

    2011-11-20

    is simply falling to the bottom of the chamber. In either case, it was determined that using the DDS, or fielding a debris collector at the chamber wall, was not feasible for solid debris collection at NIF due to the small amount of debris that had been collected. In addition, since the glass shields suffered quite a bit of damage from particles impacting the surface, glass was ruled out as a collection medium.

  11. Developing an expert system assistant for filter debris analysis

    SciTech Connect

    Roberge, P.R.; Selkirk, C.G.; Fisher, G.F.

    1994-09-01

    In oil-wetted aircraft machinery fitted with coarse (>50 micron) filtration systems, sufficient fine particulate wear debris can pass through the filter to enable meaningful spectrometric oil analysis (SOA) of the oil sample debris for off-line condition monitoring. The use of finer (10 {mu}m) filters in the F404 engines of the CF-18 aircraft has severely limited the usefulness of SOA because the filters remove almost all debris of significance from the oil. To acquire useful information from this trapped debris Filter Debris Analysis (FDA) has been developed as an alternative off-line monitoring procedure for the CF-18 F404 engines. In addition, FDA can supplement conventional oil analysis techniques for condition monitoring of coarse filtration machinery by evaluating the accumulated wear debris generated between filter changers. A knowledge based expert system is currently being developed which will incorporate FDA results and offer advice to the used by following the logical reasoning of an experienced analyst in determining the type of metallic material and the wear condition of the machinery based on the color, morphological attributers, and surface texture of the wear particles. Using this expert system, as a foundation, it is hoped that the other condition monitoring (CM) techniques will be assimilated to provide the CM analyst with a tool to correlate data and results thereby increasing the utility of each individual method of analysis. 22 refs., 5 figs., 1 tab.

  12. Spatial patterns of plastic debris along Estuarine shorelines.

    PubMed

    Browne, Mark A; Galloway, Tamara S; Thompson, Richard C

    2010-05-01

    The human population generates vast quantities of waste material. Macro (>1 mm) and microscopic (<1 mm) fragments of plastic debris represent a substantial contamination problem. Here, we test hypotheses about the influence of wind and depositional regime on spatial patterns of micro- and macro-plastic debris within the Tamar Estuary, UK. Debris was identified to the type of polymer using Fourier-transform infrared spectroscopy (FT-IR) and categorized according to density. In terms of abundance, microplastic accounted for 65% of debris recorded and mainly comprised polyvinylchloride, polyester, and polyamide. Generally, there were greater quantities of plastic at downwind sites. For macroplastic, there were clear patterns of distribution for less dense items, while for microplastic debris, clear patterns were for denser material. Small particles of sediment and plastic are both likely to settle slowly from the water-column and are likely to be transported by the flow of water and be deposited in areas where the movements of water are slower. There was, however, no relationship between the abundance of microplastic and the proportion of clay in sediments from the strandline. These results illustrate how FT-IR spectroscopy can be used to identify the different types of plastic and in this case was used to indicate spatial patterns, demonstrating habitats that are downwind acting as potential sinks for the accumulation of debris. PMID:20377170

  13. An Introduction to Space Debris

    NASA Astrophysics Data System (ADS)

    Wright, David

    2008-04-01

    Space debris is any human-made object in orbit that no longer serves a useful purpose, including defunct satellites, discarded equipment and rocket stages, and fragments from the breakup of satellites and rocket stages. It is a concern because--due to its very high speed in orbit--even relatively small pieces can damage or destroy satellites in a collision. Since debris at high altitudes can stay in orbit for decades or longer, it accumulates as more is produced and the risk of collisions with satellites grows. Since there is currently no effective way to remove large amounts of debris from orbit, controlling the production of debris is essential for preserving the long-term use of space. Today there are 860 active satellites in orbit, supporting a wide range of civil and military uses. The 50 years of space activity since the launch of Sputnik 1 has also resulted in well over half a million pieces of orbiting debris larger than 1 cm in size. There are two main sources of space debris: (1) routine space activity and the accidental breakup of satellites and stages placed in orbit by such activity, and (2) the testing or use of destructive anti-satellite (ASAT) weapons that physically collide with satellites at high speed. The international community is attempting to reduce the first category by developing strict guidelines to limit the debris created as a result of routine space activities. However, the destruction of a single large spy satellite by an ASAT weapon could double the total amount of large debris in low earth orbit, and there are currently no international restrictions on these systems. This talk will give an introduction to what's in space, the origins of space debris, efforts to stem its growth, the threat it poses to satellites in orbit, and the long-term evolution of the debris population.

  14. Orbital Debris Research at NASA

    NASA Technical Reports Server (NTRS)

    Stansbery, Eugene G.

    2009-01-01

    The United States has one of the most active programs of research of the orbital debris environment in the world. Much of the research is conducted by NASA s Orbital Debris Program Office at the Johnson Space Center. Past work by NASA has led to the development of national space policy which seeks to limit the growth of the debris population and limit the risk to spacecraft and humans in space and on the Earth from debris. NASA has also been instrumental in developing consistent international policies and standards. Much of NASA's efforts have been to measure and characterize the orbital debris population. The U.S. Department of Defense tracks and catalogs spacecraft and large debris with it's Space Surveillance Network while NASA concentrates on research on smaller debris. In low Earth orbit, NASA has utilized short wavelength radars such as Haystack, HAX, and Goldstone to statistically characterize the population in number, size, altitude, and inclination. For higher orbits, optical telescopes have been used. Much effort has gone into the understanding and removal of observational biases from both types of measurements. NASA is also striving to understand the material composition and shape characteristics of debris to assess these effects on the risk to operational spacecraft. All of these measurements along with data from ground tests provide the basis for near- and long-term modeling of the environment. NASA also develops tools used by spacecraft builders and operators to evaluate spacecraft and mission designs to assess compliance with debris standards and policies which limit the growth of the debris environment.

  15. Tethers and debris mitigation

    NASA Astrophysics Data System (ADS)

    van der Heide, Erik Jan; Kruijff, Michiel

    2001-03-01

    In recent years, the use of tethers has been proposed for reduction of space debris either through momentum transfer or use of electrodynamic effects. Tethers have been shown to at least theoretically allow for quick, elegant and cost-effective deorbit of defunct satellites or spent stages. On the other hand, the large risk that tethers themselves may pose to other satellites in orbit has been recognized as well. The large collision area of tethers, combined with operational hazards and meteoroid risk may result in a large orbital exposure. For example, in 1997, the ESA/Dutch 35-km tether deployment of YES from TEAMSAT was inhibited after an analysis of the collision risk for the case the tether operation would fail. The question rises how these two points of view compare to eachother. This paper intends to highlight a representative selection of the proposed tether applications while taking into account the added risks caused by the tethers themselves. Typical applications from recent literature will be briefly described, such as an Ariane 502 spent stage re-entry from GTO and the concept of deboost of defunct satellites by interaction of a conductive tether with the Earth magnetic field. Mass savings of the tethered sytems versus conventional equivalents will be evaluated. Based on a crude risk analysis, involving elements such as mission complexity, dynamic stability, meteoroid risk and orbital life time, a general outline of limiting factors can be given for the various applications. Special attention is reserved for implementation of mechanisms that help reduce this tether risk, such as the DUtether (Tether Degradable by Ultraviolet), utilization of airdrag and solar pressure, the effect of residual current in bare tethers, tether retrieval etc. It is proposed how a net tether-induced mitigation can be compared to that of conventional alternatives, i.e. deboost by rocket engine or a completely passive approach. This comparison is put in the perspective of an

  16. On the effects of solar storms to the decaying orbital space debris

    SciTech Connect

    Herdiwijaya, Dhani; Rachman, Abdul

    2014-03-24

    Any man-made object in Earth's orbit that no longer serves a useful purpose is classified as orbital debris. Debris objects come from a variety of sources. The majority is related to satellite fragmentation. Other major sources of debris are propulsion systems, and fragmentation of spent upper stages, payload and mission related debris. Serious concern about orbital debris has been growing. Knowledge of the future debris environment is important to both satellite designers, and mission planners, who need to know what hazards a satellite might encounter during the course of its mission. Therefore, it is important to know how much debris is in orbit, where it is located, and when it will decay. The debris environment is complex and dynamically evolving. Objects of different shape and size behave differently in orbit. The geoeffectiveness space environments include solar flux at 10.7 cm, solar energetic particles flux or speed, solar wind flow pressure, electric field, and geomagnetic indices. We study the decaying orbital debris from Tracking and Impact Prediction (TIP) messages in conjuction with geoeffectiveness space environments through time epoch correlation. We found that the decaying and reentry orbital debris are triggered by space environment enhancement within at least one week before reentry. It is not necessary a transient or high energetic and severe solar storm events are needed in decaying processes. We propose that the gradual enhancement processes of space environment will cause satellite surface charging due to energetic electron and enhance drag force.

  17. Ultrasonic echo waveshape features extraction based on QPSO-matching pursuit for online wear debris discrimination

    NASA Astrophysics Data System (ADS)

    Xu, Chao; Zhang, Peilin; Wang, Huaiguang; Li, Yining; Lv, Chun

    2015-08-01

    The ultrasonic echoes reflected from debris in lubricant contain a lot of useful information, which can represent the size, material and geometric characteristics of the debris. Our preliminary simulation investigations and physical model analysis results show that the waveshape features are feasible and essential to discriminate debris in lubricant. An accurate waveshape features extraction method of debris echoes is presented based on the matching pursuit (MP). The dictionary of Gabor functions, which is suitable for ultrasonic signal processing, is adopted for MP. To seek faster and more accurate calculation of MP, quantum-behaved particle swarm optimization (QPSO) is introduced to optimize the MP algorithm. The simulation and experimental results reveal that the proposed method can effectively extract the waveshape features of debris echoes and air bubble echoes. Utilizing the extracted waveshape features, the debris with different shapes and air bubble can be distinguished.

  18. Dispersion and Filtration of Carbon Nanotubes (CNTs) and Measurement of Nanoparticle Agglomerates in Diesel Exhaust

    PubMed Central

    Wang, Jing; Pui, David Y.H.

    2012-01-01

    Carbon nanotubes (CNTs) tend to form bundles due to their geometry and van der Walls forces, which usually complicates studies of the CNT properties. Dispersion plays a significant role in CNT studies and we summarize dispersion techniques to generate airborne CNTs from suspensions or powders. We describe in detail our technique of CNT aerosolization with controlled degree of agglomeration using an electrospray system. The results of animal inhalation studies using the electrosprayed CNTs are presented. We have performed filtration experiments for CNTs through a screen filter. A numerical model has been established to simulate the CNT filtration experiments. Both the modeling and experimental results show that the CNT penetration is less than the penetration for a sphere with the same mobility diameter, which is mainly due to the larger interception length of the CNTs. There is a need for instruments capable of fast and online measurement of gas-borne nanoparticle agglomerates. We developed an instrument Universal NanoParticle Analyzer (UNPA) and the measurement results for diesel exhaust particulates are presented. The results presented here are pertinent to non-spherical aerosol particles, and illustrate the effects of particle morphology on aerosol behaviors. PMID:23355749

  19. Colloidal stability of coal-simulated suspensions in selective agglomeration

    SciTech Connect

    Schurger, M.L.

    1989-01-01

    A coal suspension was simulated by using graphite to simulate the carbonaceous fraction and kaolinite clay to simulate the ash fraction. Separate studies on each material established their response to additions of oxidized pyrite (ferrous sulfate) and a humic acid simulate (salicylic acid) in terms of zeta potentials profiles with pH and Ionic strength. Concentrations of iron and salicylic acid evaluated were 4.5 {times} 10{sup {minus}3} M and 2.0 {times} 10{sup {minus}4} M, respectively. The zeta potentials profiles of graphite, clay and hexadecane were negative throughout the pH ranges studied. The addition of iron lowered the zeta potentials all of the suspensions under all pH and ionic strength conditions. Salicylic acid decreased the graphite and hexadecane zeta potentials but had no effect on the clay zeta potential profiles. Agglomeration of graphite with bridging liquid shows distinct time dependent rate mechanisms, a initial growth of graphite agglomerates followed by consolidation phase. Graphite agglomeration was rapid with the maximum amount of agglomerate volume growth occurring in under 2-4 minutes. Agglomeration in the first two minutes was characterized by a 1st order rate mechanism. The presence of either Iron and salicylic acid generally improved the first order rates. The addition of clay also improved the first order rates except in the presence of salicylic acid. Heteroagglomeration of graphite with clay was found by hydrodynamic arguments to be unfavored. A multicomponent population balance model which had been developed for evaluating collision efficiencies of coal, ash and pyrite selective agglomeration was evaluated to explain these results. The growth and consolidation characteristics of graphite agglomeration for the experimental conditions examined herein revealed the limitations of such as model for this application.

  20. Debris and meteoroid proportions deduced from impact crater residue analysis

    NASA Technical Reports Server (NTRS)

    Berthoud, Lucinda; Mandeville, Jean-Claude; Durin, Christian; Borg, Janet

    1995-01-01

    This study is a further investigation of space-exposed samples recovered from the LDEF satellite and the Franco-Russian 'Aragatz' dust collection experiment on the Mir Space Station. Impact craters with diameters ranging from 1 to 900 micron were found on the retrieved samples. Elemental analysis of residues found in the impact craters was carried out using Energy Dispersive X-ray spectrometry (EDX). The analyses show evidence of micrometeoroid and orbital debris origins for the impacts. The proportions of these two components vary according to particle size and experimental position with respect to the leading edge of the spacecraft. On the LDEF leading edge 17 percent of the impacts were apparently caused by micrometeoroids and 11 percent by debris; on the LDEF trailing edge 23 percent of the impacts are apparently caused by micrometeoroids and 4 percent consist of debris particles - mostly larger than 3 micron in diameter - in elliptical orbits around the Earth. For Mir, the analyses indicate that micrometeoroids form 23 percent of impacts and debris 9 percent. However, we note that 60-70 percent of the craters are unidentifiable, so the definitive proportions of natural v. man-made particles are yet to be determined. Experiments carried out using a light gas gun to accelerate glass spheres and fragments demonstrate the influence of particle shape on crater morphology. The experiments also show that it is more difficult to analyze the residues produced by an irregular fragment than those produced by a spherical projectile. If the particle is travelling above a certain velocity, it vaporizes upon impact and no residues are left. Simulation experiments carried out with an electrostatic accelerator indicate that this limit is about 14 km/s for Fe particles impacting Al targets. This chemical analysis cut-off may bias interpretations of the relative populations of meteoroid and orbital debris. Oblique impacts and multiple foil detectors provide a higher likelihood

  1. Implementation of the hazardous debris rule

    SciTech Connect

    Sailer, J.E.

    1993-01-05

    Hazardous debris includes objects contaminated with hazardous waste. Examples of debris include tree stumps, timbers, boulders, tanks, piping, crushed drums, personal protective clothing, etc. Most of the hazardous debris encountered comes from Superfund sites and other facility remediation, although generators and treaters of hazardous waste also generate hazardous debris. Major problems associated with disposal of debris includes: Inappropriateness of many waste treatments to debris; Difficulties in obtaining representative samples; Costs associated with applying waste specific treatments to debris; Subtitle C landfill space was being used for many low hazard debris types. These factors brought about the need for debris treatment technologies and regulations that addressed these issues. The goal of such regulation was to provide treatment to destroy or remove the contamination if possible and, if this is achieved, to dispose of the cleaned debris as a nonhazardous waste. EPA has accomplished this goal through promulgation of the Hazardous Debris Rule, August 18, 1992.

  2. Influence of hydrostatic pressure and sound amplitude on the ultrasound induced dispersion and de-agglomeration of nanoparticles.

    PubMed

    Sauter, C; Emin, M A; Schuchmann, H P; Tavman, S

    2008-04-01

    In most applications, nanoparticles are required to be in a well-dispersed state prior to commercialisation. Conventional technology for dispersing particles into liquids, however, usually is not sufficient, since the nanoparticles tend to form very strong agglomerates requiring extremely high specific energy inputs in order to overcome the adhesive forces. Besides conventional systems as stirred media mills, ultrasound is one means to de-agglomerate nanoparticles in aqueous dispersions. In spite of several publications on ultrasound emulsification there is insufficient knowledge on the de-agglomeration of nanoparticulate systems in dispersions and their main parameters of influence. Aqueous suspensions of SiO2-particles were stressed up to specific energies EV of 10(4) kJ/m3 using ultrasound. Ultrasonic de-agglomeration of nanoparticles in aqueous solution is considered to be mainly a result of cavitation. Both hydrostatic pressure of the medium and the acoustic amplitude of the sound wave affect the intensity of cavitation. Furthermore, the presence of gas in the dispersion medium influences cavitation intensity and thus the effectiveness of the de-agglomeration process. In this contribution both, the influence of these parameters on the result of dispersion and the relation to the specific energy input are taken into account. For this, ultrasound experiments were carried out at different hydrostatic pressure levels (up to 10 bars) and amplitude values (64-123 microm). Depending on the optimisation target (time, energy input,...) different parameters limit the dispersion efficiency and result. All experimental results can be explained with the specific energy input that is a function of the primary input parameters of the process. PMID:17977777

  3. Meteoroid/Orbital Debris Shield Engineering Development Practice and Procedure

    NASA Technical Reports Server (NTRS)

    Zwitter, James G.; Adams, Marc A.

    2011-01-01

    A document describes a series of models created for the determination of the probability of survival of critical spacecraft components from particle strike damage caused by hypervelocity impact of meteoroids and/or orbital debris. These models were integrated with both shield design and hypervelocity impact testing to develop adequate protection of said components to meet mission survivability requirements.

  4. JSC Orbital Debris Website Description

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2006-01-01

    Purpose: The website provides information about the NASA Orbital Debris Program Office at JSC, which is the lead NASA center for orbital debris research. It is recognized world-wide for its leadership in addressing orbital debris issues. The NASA Orbital Debris Program Office has taken the international lead in conducting measurements of the environment and in developing the technical consensus for adopting mitigation measures to protect users of the orbital environment. Work at the center continues with developing an improved understanding of the orbital debris environment and measures that can be taken to control its growth. Major Contents: Orbital Debris research is divided into the following five broad efforts. Each area of research contains specific information as follows: 1) Modeling - NASA scientists continue to develop and upgrade orbital debris models to describe and characterize the current and future debris environment. Evolutionary and engineering models are described in detail. Downloadable items include a document in PDF format and executable software. 2) Measurements - Measurements of near-Earth orbital debris are accomplished by conducting ground-based and space-based observations of the orbital debris environment. The data from these sources provide validation of the environment models and identify the presence of new sources. Radar, optical and surface examinations are described. External links to related topics are provided. 3) Protection - Orbital debris protection involves conducting hypervelocity impact measurements to assess the risk presented by orbital debris to operating spacecraft and developing new materials and new designs to provide better protection from the environment with less weight penalty. The data from this work provides the link between the environment defined by the models and the risk presented by that environment to operating spacecraft and provides recommendations on design and operations procedures to reduce the risk as

  5. Investigation of Orbital Debris: Mitigation, Removal, and Modeling the Debris Population

    NASA Astrophysics Data System (ADS)

    Slotten, Joel

    The population of objects in orbit around Earth has grown since the late 1950s. Today there are over 21,000 objects over 10 cm in length in orbit, and an estimated 500,000 more between 1 and 10 cm. Only a small fraction of these objects are operational satellites. The rest are debris: old derelict spacecraft or rocket bodies, fragments created as the result of explosions or collisions, discarded objects, slag from solid rockets, or even flaked off paint. Traveling at up to 7 km/s, a collision with even a 1 cm piece of debris could severely damage or destroy a satellite. This dissertation examines three aspects of orbital debris. First, the concept of a self-consuming satellite is explored. This nanosatellite would use its own external structure as propellant to execute a deorbit maneuver at the end of its operational life, thus allowing it to meet current debris mitigation standards. Results from lab experiments examining potential materials for this concept have shown favorable results. Second, Particle in Cell techniques are modified and used to model the plasma plume from a micro-cathode arc thruster. This model is then applied to the concept of an ion beam shepherd satellite. This satellite would use its plasma plume to deorbit another derelict satellite. Results from these simulations indicate the micro-cathode arc thruster could potentially deorbit a derelict CubeSat in a matter of a few weeks. Finally, the orbital debris population at geosynchronous orbit is examined, focusing on variations in the density of the population as a function of longitude. New insights are revealed demonstrating that the variation in population density is slightly less than previously reported.

  6. A non-immersed induction conductivity system for controlling supersaturation in corrosive media: the case of gibbsite crystals agglomeration in Bayer liquors

    NASA Astrophysics Data System (ADS)

    Seyssiecq, I.; Veesler, S.; Boistelle, R.

    1996-11-01

    Agglomeration of gibbsite Al(OH) 3 crystallites is an important stage of the Bayer process, aiming at increasing the initial size of the particles. In the present work, a semi-continuous crystallizer working at constant and imposed supersaturation, and equipped with an automatic withdrawal system was developed to study the agglomeration of gibbsite crystals in supersaturated Bayer liquors. The liquor conductivity was measured using an induction conductivity system placed around the crystallizer, the conductivity regulation being used to work at constant supersaturation. Using this system allowed one to work with both a small crystallizer and a highly corrosive and abrasive suspension of gibbsite in a five molar caustic soda solution at 70°C. Analyses of the withdrawals were carried out with an Elzone particle counter, in order to draw {N(t)}/{N(0) = f(t)} plots, representing the decrease of crystal number with time, due to agglomeration.

  7. Space Shuttle and Launch Pad Lift-Off Debris Transport Analysis: SRB Plume-Driven

    NASA Technical Reports Server (NTRS)

    West, Jeff; Strutzenberg, Louis; Dougherty, Sam; Radke, Jerry; Liever, Peter

    2007-01-01

    This paper discusses the Space Shuttle Lift-Off model developed for potential Lift-Off Debris transport. A critical Lift-Off portion of the flight is defined from approximately 1.5 sec after SRB Ignition up to 'Tower Clear', where exhaust plume interactions with the Launch Pad occur. A CFD model containing the Space Shuttle and Launch Pad geometry has been constructed and executed. The CFD model works in conjunction with a debris particle transport model and a debris particle impact damage tolerance model. These models have been used to assess the effects of the Space Shuttle plumes, the wind environment, their interactions with the Launch Pad, and their ultimate effect on potential debris during Lift-Off. Emphasis in this paper is on potential debris that might be caught by the SRB plumes.

  8. A Critical Study of Agglomerated Multigrid Methods for Diffusion

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.

    2011-01-01

    Agglomerated multigrid techniques used in unstructured-grid methods are studied critically for a model problem representative of laminar diffusion in the incompressible limit. The studied target-grid discretizations and discretizations used on agglomerated grids are typical of current node-centered formulations. Agglomerated multigrid convergence rates are presented using a range of two- and three-dimensional randomly perturbed unstructured grids for simple geometries with isotropic and stretched grids. Two agglomeration techniques are used within an overall topology-preserving agglomeration framework. The results show that multigrid with an inconsistent coarse-grid scheme using only the edge terms (also referred to in the literature as a thin-layer formulation) provides considerable speedup over single-grid methods but its convergence deteriorates on finer grids. Multigrid with a Galerkin coarse-grid discretization using piecewise-constant prolongation and a heuristic correction factor is slower and also grid-dependent. In contrast, grid-independent convergence rates are demonstrated for multigrid with consistent coarse-grid discretizations. Convergence rates of multigrid cycles are verified with quantitative analysis methods in which parts of the two-grid cycle are replaced by their idealized counterparts.

  9. Theranostic potential of gold nanoparticle-protein agglomerates.

    PubMed

    Sanpui, Pallab; Paul, Anumita; Chattopadhyay, Arun

    2015-11-28

    Owing to the ever-increasing applications, glittered with astonishing success of gold nanoparticles (Au NPs) in biomedical research as diagnostic and therapeutic agents, the study of Au NP-protein interaction seems critical for maximizing their theranostic efficiency, and thus demands comprehensive understanding. The mutual interaction of Au NPs and proteins at physiological conditions may result in the aggregation of protein, which can ultimately lead to the formation of Au NP-protein agglomerates. In the present article, we try to appreciate the plausible steps involved in the Au NP-induced aggregation of proteins and also the importance of the proteins' three-dimensional structures in the process. The Au NP-protein agglomerates can potentially be exploited for efficient loading and subsequent release of various therapeutically important molecules, including anticancer drugs, with the unique opportunity of incorporating hydrophilic as well as hydrophobic drugs in the same nanocarrier system. Moreover, the Au NP-protein agglomerates can act as 'self-diagnostic' systems, allowing investigation of the conformational state of the associated protein(s) as well as the protein-protein or protein-Au NP interaction within the agglomerates. Furthermore, the potential of these Au NP-protein agglomerates as a novel platform for multifunctional theranostic application along with exciting future-possibilities is highlighted here. PMID:26508277

  10. Advanced physical fine coal cleaning spherical agglomeration. Final report

    SciTech Connect

    Not Available

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  11. A Critical Study of Agglomerated Multigrid Methods for Diffusion

    NASA Technical Reports Server (NTRS)

    Thomas, James L.; Nishikawa, Hiroaki; Diskin, Boris

    2009-01-01

    Agglomerated multigrid techniques used in unstructured-grid methods are studied critically for a model problem representative of laminar diffusion in the incompressible limit. The studied target-grid discretizations and discretizations used on agglomerated grids are typical of current node-centered formulations. Agglomerated multigrid convergence rates are presented using a range of two- and three-dimensional randomly perturbed unstructured grids for simple geometries with isotropic and highly stretched grids. Two agglomeration techniques are used within an overall topology-preserving agglomeration framework. The results show that multigrid with an inconsistent coarse-grid scheme using only the edge terms (also referred to in the literature as a thin-layer formulation) provides considerable speedup over single-grid methods but its convergence deteriorates on finer grids. Multigrid with a Galerkin coarse-grid discretization using piecewise-constant prolongation and a heuristic correction factor is slower and also grid-dependent. In contrast, grid-independent convergence rates are demonstrated for multigrid with consistent coarse-grid discretizations. Actual cycle results are verified using quantitative analysis methods in which parts of the cycle are replaced by their idealized counterparts.

  12. Theranostic potential of gold nanoparticle-protein agglomerates

    NASA Astrophysics Data System (ADS)

    Sanpui, Pallab; Paul, Anumita; Chattopadhyay, Arun

    2015-11-01

    Owing to the ever-increasing applications, glittered with astonishing success of gold nanoparticles (Au NPs) in biomedical research as diagnostic and therapeutic agents, the study of Au NP-protein interaction seems critical for maximizing their theranostic efficiency, and thus demands comprehensive understanding. The mutual interaction of Au NPs and proteins at physiological conditions may result in the aggregation of protein, which can ultimately lead to the formation of Au NP-protein agglomerates. In the present article, we try to appreciate the plausible steps involved in the Au NP-induced aggregation of proteins and also the importance of the proteins' three-dimensional structures in the process. The Au NP-protein agglomerates can potentially be exploited for efficient loading and subsequent release of various therapeutically important molecules, including anticancer drugs, with the unique opportunity of incorporating hydrophilic as well as hydrophobic drugs in the same nanocarrier system. Moreover, the Au NP-protein agglomerates can act as `self-diagnostic' systems, allowing investigation of the conformational state of the associated protein(s) as well as the protein-protein or protein-Au NP interaction within the agglomerates. Furthermore, the potential of these Au NP-protein agglomerates as a novel platform for multifunctional theranostic application along with exciting future-possibilities is highlighted here.

  13. Recognizing Patterns in Debris Disks

    NASA Technical Reports Server (NTRS)

    Kuchner, Marc

    2009-01-01

    An extrasolar planet sculpts the famous debris dish around Fomalhaut; probably many other debris disks contain planets that we could locate if only we could better recognize their signatures in the dust that surrounds them. I will describe the latest 3-D models of debris dish dynamics / models that include planets, grain-grain collisions and even ISM-disk interactions. I will show why all these ingredients are needed to explain disk images--and what the images are telling us about planet formation.

  14. Uncertainties in debris growth predictions

    SciTech Connect

    McKnight, D.S. )

    1991-01-10

    The growth of artificial space debris in Earth orbit may pose a significant hazard to satellites in the future though the collision hazard to operational spacecraft is presently manageable. The stability of the environment is dependent on the growth of debris from satellite deployment, mission operations and fragmentation events. Growth trends of the trackable on-orbit population are investigated highlighting the complexities and limitations of using the data that supports this modeling. The debris produced by breakup events may be a critical aspect of the present and future environment. As a result, growth predictions produced using existing empirically-based models may have large, possibly even unacceptable, uncertainties.

  15. Formulation effects on the release of silica dioxide nanoparticles from paint debris to water.

    PubMed

    Zuin, Stefano; Massari, Andrea; Ferrari, Arlen; Golanski, Luana

    2014-04-01

    Waterborne paints with integrated nanoparticles have been recently introduced into the market as nanoparticles offer improved or novel functionalities to paints. However, the release of nanoparticles during the life cycle of nano-enhanced paint has only been studied to a very limited extent. The paint composition could determine in what quantities and forms the nanoparticles are released. In this work, paint formulations containing the same amount of silicon dioxide (SiO2) nanoparticles but differing in the pigment volume concentration (PVC) and in amount and type of binder and pigment, were studied through leaching test to investigate the influence of these parameters on release of Si from paint. The results indicate greater release of Si, about 1.7 wt.% of the SiO2 nanoparticles in the paint, for paint formulated with higher PVC value (63%), suggesting that the PVC is a crucial factor for release of SiO2 nanoparticles from paints. This hypothesis was also based on the fact that agglomerates of SiO2 nanoparticles were only found in leachates from paint with higher PVC. A paint sample with the higher amount of binder and less calcite filler exhibited a lower release of Si among the paints with a low PVC value (35%), and no SiO2 particles were detected in leachates collected from this paint. This could be due to the fact that a high portion of binder forms a suitable matrix to hold the SiO2 ENPs in paint. The paint sample in which the amount of calcite was partially substituted with TiO2 pigment did not show an important reduction on Si release. Our work suggests that paint debris containing SiO2 nanoparticles may release a limited amount of Si into the environment, and that by adjusting the properties of the binder in combination with common pigments it is possible to reduce the release of SiO2 nanoparticles. PMID:24468504

  16. Effect of Electromagnetic Vibration on the Agglomeration Behavior of Primary Silicon in Hypereutectic Al-Si Alloy

    NASA Astrophysics Data System (ADS)

    Han, Yecong; Li, Qiulin; Liu, Wei; He, Yanjie

    2012-05-01

    An experimental apparatus that enables the simultaneous application of an alternating electric field and a stationary magnetic field was developed. Electromagnetic vibration was induced in a hypereutectic Al-Si alloy melt during solidification at a constant cooling rate. The results showed that the silicon particles collide with each other and agglomerate into clusters with the application of an electromagnetic vibration. With the increase of the electromagnetic force F, the sizes of the silicon clusters decrease and the clusters become more compact.

  17. Modeling collisions in circumstellar debris disks

    NASA Astrophysics Data System (ADS)

    Nesvold, Erika

    2015-10-01

    resonances near the chaotic zone. I investigate the effects of the initial eccentricity distribution of the disk particles and find a negligible effect on the gap size at Jovian planet masses, since collisions tend to erase memory of the initial particle eccentricity distributions. I also find that the presence of Trojan analogs is a potentially powerful diagnostic of planets in the mass range ˜1--10MJup. I apply my model to place new upper limits on planets around Fomalhaut, HR 4796 A, HD 202628, HD 181327, and beta Pictoris. Finally, to show how SMACK can be used to analyze a single debris disk in detail, I present a new model of the beta Pictoris disk and planet system that, for the first time, combines simulations of the colliding planetesimals and the dynamics of the dust grains, allowing me to model features and asymmetries in both submillimeter and scattered light images of the disk. I combine a 100,000 superparticle SMACK simulation with N-body integrations of the dust produced by the simulated collisions. I find that secular perturbations of the planet's measured inclination and eccentricity can explain the observed warp and planetesimal ring, while collisions between planetesimals shape the disk by eroding close-in material. The complex 3D structure of the disk due to the perturbations from the planet creates an azimuthally asymmetric spatial distribution of collisions, which could contribute to the observed azimuthal clump of CO gas seen with ALMA. My simulations of the small dust grains produced by collisions demonstrate that the "birth ring" approximation for beta Pictoris fails to account for the ˜54% of dust mass produced outside of the planetesimal ring. I also reproduce the gross morphology of high-resolution scattered light images of the disk, including the two-disk "x"-pattern seen in scattered light, which has not been replicated by previous dust dynamics models.

  18. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 4 2011-01-01 2011-01-01 false Debris analysis. 417.211 Section 417.211... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris...

  19. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 4 2010-01-01 2010-01-01 false Debris analysis. 417.211 Section 417.211... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris...

  20. 44 CFR 206.224 - Debris removal.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 44 Emergency Management and Assistance 1 2010-10-01 2010-10-01 false Debris removal. 206.224... Debris removal. (a) Public interest. Upon determination that debris removal is in the public interest, the Regional Administrator may provide assistance for the removal of debris and wreckage from...

  1. Powder fed sheared dispersal particle generator

    NASA Technical Reports Server (NTRS)

    Morrisette, E. L.; Bushnell, D. M. (Inventor)

    1984-01-01

    A particle generating system is described which is capable of breaking up agglomerations of particles and producing a cloud of uniform, submicron-sized particles at high pressure and high flow rates. This is achieved by utilizing a tubular structure which has injection microslits on is periphery to accept and disperse the desired particle feed. By suppling a carrying fluid at a pressure, of approximately twice the ambient pressure of the velocimeter's settling chamber, the microslits operate at choked flow conditions. The shearing action of this choked flow is sufficient to overcome interparticle bonding forces, thereby breaking up the agglomerates of the particles feed into individual particles.

  2. DIAGNOSING CIRCUMSTELLAR DEBRIS DISKS

    SciTech Connect

    Hahn, Joseph M.

    2010-08-20

    A numerical model of a circumstellar debris disk is developed and applied to observations of the circumstellar dust orbiting {beta} Pictoris. The model accounts for the rates at which dust is produced by collisions among unseen planetesimals, and the rate at which dust grains are destroyed due to collisions. The model also accounts for the effects of radiation pressure, which is the dominant perturbation on the disk's smaller but abundant dust grains. Solving the resulting system of rate equations then provides the dust abundances versus grain size and dust abundances over time. Those solutions also provide the dust grains' collisional lifetime versus grain size, and the debris disk's optical depth and surface brightness versus distance from the star. Comparison to observations then yields estimates of the unseen planetesimal disk's radius, and the rate at which the disk sheds mass due to planetesimal grinding. The model can also be used to measure or else constrain the dust grain's physical and optical properties, such as the dust grains' strength, their light-scattering asymmetry parameter, and the grains' efficiency of light scattering Q{sub s}. The model is then applied to optical observations of the edge-on dust disk orbiting {beta} Pictoris, and good agreement is achieved when the unseen planetesimal disk is broad, with 75 {approx}< r {approx}< 150 AU. If it is assumed that the dust grains are bright like Saturn's icy rings (Q{sub s} = 0.7), then the cross section of dust in the disk is A{sub d} {approx_equal} 2 x 10{sup 20} km{sup 2} and its mass is M{sub d} {approx_equal} 11 lunar masses. In this case, the planetesimal disk's dust-production rate is quite heavy, M-dot {sub d{approx}}9 M {sub +} Myr{sup -1}, implying that there is or was a substantial amount of planetesimal mass there, at least 110 Earth masses. If the dust grains are darker than assumed, then the planetesimal disk's mass-loss rate and its total mass are heavier. In fact, the apparent dearth

  3. Occurrence of spherical ceramic debris in indentation and sliding contact

    NASA Technical Reports Server (NTRS)

    Miyoshi, K.; Buckley, D. H.

    1982-01-01

    Indenting experiments were conducted with the silicon carbide (0001) surface in contact with a spherical diamond indenter in air. Sliding friction experiments were also conducted with silicon carbide in contact with iron and iron-based binary alloys at room temperature and 800 C. Fracture pits with a spherical particle and spherical wear debris were observed as a result of indenting and sliding. Spherical debris may be produced by a mechanism that involves a spherical-shaped fracture along the circular or spherical stress trajectories under the inelastic deformation zone.

  4. NASA Orbital Debris Baseline Populations

    NASA Technical Reports Server (NTRS)

    Krisko, Paula H.; Vavrin, A. B.

    2013-01-01

    The NASA Orbital Debris Program Office has created high fidelity populations of the debris environment. The populations include objects of 1 cm and larger in Low Earth Orbit through Geosynchronous Transfer Orbit. They were designed for the purpose of assisting debris researchers and sensor developers in planning and testing. This environment is derived directly from the newest ORDEM model populations which include a background derived from LEGEND, as well as specific events such as the Chinese ASAT test, the Iridium 33/Cosmos 2251 accidental collision, the RORSAT sodium-potassium droplet releases, and other miscellaneous events. It is the most realistic ODPO debris population to date. In this paper we present the populations in chart form. We describe derivations of the background population and the specific populations added on. We validate our 1 cm and larger Low Earth Orbit population against SSN, Haystack, and HAX radar measurements.

  5. Lightweight Shield Against Space Debris

    NASA Technical Reports Server (NTRS)

    Redmon, John W., Jr.; Lawson, Bobby E.; Miller, Andre E.; Cobb, W. E.

    1992-01-01

    Report presents concept for lightweight, deployable shield protecting orbiting spacecraft against meteoroids and debris, and functions as barrier to conductive and radiative losses of heat. Shield made in four segments providing 360 degree coverage of cylindrical space-station module.

  6. Element Agglomeration Algebraic Multilevel Monte-Carlo Library

    SciTech Connect

    2015-02-19

    ElagMC is a parallel C++ library for Multilevel Monte Carlo simulations with algebraically constructed coarse spaces. ElagMC enables Multilevel variance reduction techniques in the context of general unstructured meshes by using the specialized element-based agglomeration techniques implemented in ELAG (the Element-Agglomeration Algebraic Multigrid and Upscaling Library developed by U. Villa and P. Vassilevski and currently under review for public release). The ElabMC library can support different type of deterministic problems, including mixed finite element discretizations of subsurface flow problems.

  7. Agglomeration behavior of solid nickel on polycrystalline barium titanate

    SciTech Connect

    Weil, K Scott; Mast, Eric S; Sprenkle, Vince

    2007-11-01

    This letter describes the phenomenon that takes place between nickel/barium titanate couples when heated under conditions employed in multilayer ceramic capacitor manufacturing practice: a 4hr, 1300°C isothermal anneal in 1% H2 – 99% N2. Dense, sputtered nickel films were observed to dewet the titanate and agglomerate into discrete or interconnected islands via a solid-state process. Up to a critical film thickness value of ~1.4 μm, the degree of agglomeration was found to display an exponential dependence on the thickness of the original nickel film.

  8. Element Agglomeration Algebraic Multilevel Monte-Carlo Library

    2015-02-19

    ElagMC is a parallel C++ library for Multilevel Monte Carlo simulations with algebraically constructed coarse spaces. ElagMC enables Multilevel variance reduction techniques in the context of general unstructured meshes by using the specialized element-based agglomeration techniques implemented in ELAG (the Element-Agglomeration Algebraic Multigrid and Upscaling Library developed by U. Villa and P. Vassilevski and currently under review for public release). The ElabMC library can support different type of deterministic problems, including mixed finite element discretizationsmore » of subsurface flow problems.« less

  9. Continuous air agglomeration method for high carbon fly ash beneficiation

    DOEpatents

    Gray, McMahon L.; Champagne, Kenneth J.; Finseth, Dennis H.

    2000-01-01

    The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

  10. Continuous air Agglomeration Method for high Carbon fly ash Beneficiation

    SciTech Connect

    Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

    1998-09-29

    The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

  11. Debris flows: Experiments and modelling

    NASA Astrophysics Data System (ADS)

    Turnbull, Barbara; Bowman, Elisabeth T.; McElwaine, Jim N.

    2015-01-01

    Debris flows and debris avalanches are complex, gravity-driven currents of rock, water and sediments that can be highly mobile. This combination of component materials leads to a rich morphology and unusual dynamics, exhibiting features of both granular materials and viscous gravity currents. Although extreme events such as those at Kolka Karmadon in North Ossetia (2002) [1] and Huascarán (1970) [2] strongly motivate us to understand how such high levels of mobility can occur, smaller events are ubiquitous and capable of endangering infrastructure and life, requiring mitigation. Recent progress in modelling debris flows has seen the development of multiphase models that can start to provide clues of the origins of the unique phenomenology of debris flows. However, the spatial and temporal variations that debris flows exhibit make this task challenging and laboratory experiments, where boundary and initial conditions can be controlled and reproduced, are crucial both to validate models and to inspire new modelling approaches. This paper discusses recent laboratory experiments on debris flows and the state of the art in numerical models.

  12. Experimental investigation of sedimentation of LOCA - generated fibrous debris and sludge in BWR suppression pools

    SciTech Connect

    Souto, F.J.; Rao, D.V.

    1995-12-01

    Several tests were conducted in a 1:2.4 scale model of a Mark I suppression pool to investigate the behavior of fibrous insulation and sludge debris under LOCA conditions. NUKON{trademark} shreds, manually cut and tore up in a leaf shredder, and iron oxide particles were used to simulate fibrous and sludge debris, respectively. The suppression pool model included four downcomers fitted with pistons to simulate the steam-water oscillations during chugging expected during a LOCA. The study was conducted to provide debris settling velocity data for the models used in the BLOCKAGE computer code, developed to estimate the ECCS pump head loss due to clogging of the strainers with LOCA generated debris. The tests showed that the debris, both fibrous and particulate, remains fully mixed during chugging; they also showed that, during chugging, the fibrous debris underwent fragmentation into smaller sizes, including individual fibers. Measured concentrations showed that fibrous debris settled slower than the sludge, and that the settling behavior of each material is independent of the presence of the other material. Finally, these tests showed that the assumption of considering uniform debris concentration during strainer calculations is reasonable. The tests did not consider the effects of the operation of the ECCS on the transport of debris in the suppression pool.

  13. Debris about asteroids: Where and how much?

    NASA Technical Reports Server (NTRS)

    Burns, Joseph A.; Hamilton, Douglas P.

    1992-01-01

    We summarize several recent findings on the size and shape of the region within which material can stably orbit an asteroid. If the asteroid (with assumed density 2.38 g/cu cm) circles the Sun at 2.55 AU, co-planar prograde material will remain trapped whenever started on unperturbed circular orbits at less than about 220 R(sub A) (asteroid radii); co-planar retrograde particles are stable out twice as far. Our 3-D stability surface, which encloses several hundred numerically calculated orbits that start with various inclinations, is shaped like a sphere with its top and bottom sliced off; its dimensions scale like the Hill radius =(mu/3)(exp 1/3)R, where mu is the asteroid-to-solar mass ratio and R is the asteroid's orbital radius. If the asteroid moves along an elliptical orbit, a fairly reliable indicator of the dimensions of the hazard zone is the size of its Hill sphere at the orbit's pericenter. Grains with radii less than a few mm will be lost through the action of radiation forces which can induce escape or cause collisions with the asteroid on times scales of a few years; interplanetary micrometeoroids produce collisional break-up of these particles in approximately 10(exp 4) yrs. The effects of Jupiter and of asteroids that pass close to the target asteroid allow particles to diffuse from the system, again shrinking the hazard zone. None of the considered sources-primordial formation, debris spalled off the asteroid during micrometeoroid impact, captured interplanetary particles, feeder satellites, etc., seem capable of densely populating distant orbits from the asteroid. No certain detections of debris clouds or of binary asteroids have been made. Thus, it seems highly unlikely that a spacecraft fly-by targeted at 100 R(sub A) from the asteroid over its orbital pole would encounter any material.

  14. Probing Nearby Planetary Systems by Debris Disk Imaging

    NASA Technical Reports Server (NTRS)

    Stapelfeldt, Karl

    2011-01-01

    Many main-sequence stars possess tenuous circumstellar dust clouds believed to trace extrasolar analogs of the Sun's asteroidand Kuiper Belts. While most of these "debris disks" are known only from far-infrared photometry, a growing number of them are now spatially resolved. In this talk, I'll review what is currently known about the structure of debris disks. Using images from the Hubble, Spitzer, and Herschel Space Telescopes, I will show how modeling of these resolved systems can place strong constraints on dust particle properties in the disks. Some of the disks show disturbed structures suggestive of planetary perturbations: specific cases will be discussed where directly-imaged exoplanets are clearly affecting debris disk structure. I'll conclude with thoughts on the future of high contrast exoplanet imaging.

  15. Debris Disks as Tracers of Nearby Planetary Systems

    NASA Technical Reports Server (NTRS)

    Stapelfeldt, Karl

    2012-01-01

    Many main-sequence stars possess tenuous circumstellar dust clouds believed to trace extrasolar analogs of the Sun's asteroid and Kuiper Belts. While most of these "debris disks" are known only from far-infrared photometry, dozens are now spatially resolved. In this talk, I'll review the observed structural properties of debris disks as revealed by imaging with the Hubble, Spitzer, and Herschel Space Telescopes. I will show how modeling of the far-infrared spectral energy distributions of resolved disks can be used to constrain their dust particle sizes and albedos. I will review cases of disks whose substructures suggest planetary perturbations, including a newly-discovered eccentric ring system. I'll conclude with thoughts on the potential of upcoming and proposed facilities to resolve similar structures around a greatly expanded sample of nearby debris systems.

  16. The fate of debris in the Pluto-Charon system

    NASA Astrophysics Data System (ADS)

    Smullen, Rachel; Kratter, Kaitlin M.

    2016-05-01

    Pluto has recently been thrust into the spotlight with the fly-by of New Horizons. This dwarf planet and its moons provide an opportunity to study circumbinary dynamics close to home. We perform N-body simulations of a test-particle disk around the Pluto-Charon binary to study the fate of debris that should result from the formation of the Pluto-Charon binary. We not only investigate the stability and time evolution of debris within the Pluto system, but also track ejected debris to see where it may collect in the solar system. By studying the dynamics of the Pluto-Charon system, we may be able to place constraints on the cratering rates from its natal disk and identify tracers of the formation of this system.

  17. Debris flows as geomorphic agents in the Huachuca Mountains of southeastern Arizona

    USGS Publications Warehouse

    Wohl, E.E.; Pearthree, P.P.

    1991-01-01

    Numerous debris flows occurred in the Huachuca Mountains of southeastern Arizona during the summer rainy season of 1988 in areas that were burned by a forest fire earlier in the summer. Debris flows occurred following a major forest fire in 1977 as well, suggesting a causal link between fires and debris flows. Abundant evidence of older debris flows preserved along channels and in mountain front fans indicates that debris flows have occurred repeteadly during the late Quaternary in this environment. Soil development in sequences of debris-flow deposits indicates that debris flows probably recur over time intervals of several hundred to a thousand years in individual drainage basins in the study area. Surface runoff in the steep drainage basins of the Huachuca Mountains is greatly enhanced following forest fires, as the hillslopes are denuded of their vegetative cover. Water and sediment eroded from the hillslope regolith are rapidly introduced into the upper reaches of tributary channels by widespread rilling and slope wash during rainfall events. This influx of water and sediment destabilizes regolith previously accumulated in the channel, triggering debris flows that scour the channel to bedrock in the upper reaches. Following a debris flow, the scoured, trapezoidally-shaped channel gradually assumes a swale shape and the percentage of exposed bedrock declines, as material is introduced from the slopes. Debris flows do a tremendous amount of work in a very short time, however, and are the major channel-forming events. Where the tributary channels enter larger, trunk channels, the debris flows serve as the main source of very coarse sediment. The local slope and coarse particle distribution of the trunk channel depend on the competence of water flows in the channel to transport the material introduced by debris flows. Where the smaller channels drain directly to the mountain front, debris flows create extensive alluvial fans which dominate the morphology of the

  18. Debris flows from tributaries of the Colorado River, Grand Canyon National Park, Arizona

    USGS Publications Warehouse

    Webb, R.H.; Pringle, P.T.; Rink, G.R.

    1987-01-01

    A reconnaissance of 36 tributaries of the Colorado River indicates that debris flows are a major process by which sediment is transported to the Colorado River in Grand Canyon National Park. Debris flows are slurries of sediment and water that have a water content < 40% by volume. Debris flows occur frequently in arid and semiarid regions. Slope failures commonly trigger debris flows, which can originate from any rock formation in the Grand Canyon. The largest and most frequent flows originate from the Permian Hermit Shale, the underlying Esplanade Sandstone of the Supai Group, and other formations of the Permian and Pennsylvanian Supai Group. Debris flows have reached the Colorado River on an average of once every 20 to 30 yr in the Lava-Chuar Creek drainage since about 1916. Two debris flows have reached the Colorado River in the last 25 yr in Monument Creek. The Crystal Creek drainage has had an average of one debris flow reaching the Colorado River every 50 yr, although the debris flow of 1966 has been the only flow that reached the Colorado River since 1900. Debris flows may actually reach the Colorado River more frequently in these drainages because evidence for all debris flows may not have been preserved in the channel-margin stratigraphy. Discharges were estimated for the peak flow of three debris flows that reached the Colorado River. The debris flow of 1966 in the Lava-Chuar Creek drainage had an estimated discharge of 4,000 cu ft/sec. The debris flow of 1984 in the Monument Creek drainage had a discharge estimated between 3,600 and 4,200 cu ft/sec. The debris flow of 1966 in the Crystal Creek drainage had a discharge estimated between 9,200 and 14,000 cu ft/sec. Debris flows in the Grand Canyon generally are composed of 10 to 40% sand by weight and may represent a significant source of beach-building sand along the Colorado River. The particle size distributions are very poorly sorted and the largest transported boulders were in the Crystal Creek

  19. Microstructural evolution and macroscopic shrinkage in the presence of density gradients and agglomeration

    NASA Astrophysics Data System (ADS)

    Lu, Peizhen

    X-ray computed tomography (CT) can characterize internal density gradients. An in-situ laser dilatometry has been constructed to track dimensional change at different positions of a sample during binder removal and sintering. This combination of tools not only allows us to better understand how microscopic change affects macroscopic dimensions, but also provides guidance for a variety of ceramic processes. Non-uniform agglomerate packing and deformation provide density gradients which drive binder migration during binder removal. Simultaneously, density undergoes a slight decrease accompanied by a 1.0% loss in dimensional tolerance. This and CT difference images suggest that capillary forces generated during binder melting can change the density distribution. During sintering, nonuniformities present in the green state persist into the fired state and become exaggerated. Regions of different initial density can occupy different stages sintering. At ˜88% sintered density, CT clearly showed that open porosity follows the distribution of low density areas. Mercury porosimetry detected three distinct levels of porosity. Microstructural examination correlated the porosity level with the coordination of (i) two to three or (ii) multiple grains around pores. Microstructural packing controls both the observed macroscopic expansion at T ≤ 1000°C and the onset of shrinkage. Neck formation initiates during expansion and not exclusively during shrinkage. Inter- and intra-agglomerate expansion/shrinkage proceed simultaneously but the effective 'transmission' of particle-level behavior to the macroscopic level appears to be controlled by the initial agglomerate bonding and internal agglomerate densities. Discrete element modeling provides corroborating evidence regarding the importance of compact continuity. Following the expansion-shrinkage transition, the higher the zone density the faster the initial shrinkage. The 25% RH sample shrank more rapidly than the same zone in

  20. Estimating Foreign-Object-Debris Density from Photogrammetry Data

    NASA Technical Reports Server (NTRS)

    Long, Jason; Metzger, Philip; Lane, John

    2013-01-01

    Within the first few seconds after launch of STS-124, debris traveling vertically near the vehicle was captured on two 16-mm film cameras surrounding the launch pad. One particular piece of debris caught the attention of engineers investigating the release of the flame trench fire bricks. The question to be answered was if the debris was a fire brick, and if it represented the first bricks that were ejected from the flame trench wall, or was the object one of the pieces of debris normally ejected from the vehicle during launch. If it was typical launch debris, such as SRB throat plug foam, why was it traveling vertically and parallel to the vehicle during launch, instead of following its normal trajectory, flying horizontally toward the north perimeter fence? By utilizing the Runge-Kutta integration method for velocity and the Verlet integration method for position, a method that suppresses trajectory computational instabilities due to noisy position data was obtained. This combination of integration methods provides a means to extract the best estimate of drag force and drag coefficient under the non-ideal conditions of limited position data. This integration strategy leads immediately to the best possible estimate of object density, within the constraints of unknown particle shape. These types of calculations do not exist in readily available off-the-shelf simulation software, especially where photogrammetry data is needed as an input.

  1. The physics of debris flows

    USGS Publications Warehouse

    Iverson, R.M.

    1997-01-01

    Recent advances in theory and experimentation motivate a thorough reassessment of the physics of debris flows. Analyses of flows of dry, granular solids and solid-fluid mixtures provide a foundation for a comprehensive debris flow theory, and experiments provide data that reveal the strengths and limitations of theoretical models. Both debris flow materials and dry granular materials can sustain shear stresses while remaining static; both can deform in a slow, tranquil mode characterized by enduring, frictional grain contacts; and both can flow in a more rapid, agitated mode characterized by brief, inelastic grain collisions. In debris flows, however, pore fluid that is highly viscous and nearly incompressible, composed of water with suspended silt and clay, can strongly mediate intergranular friction and collisions. Grain friction, grain collisions, and viscous fluid flow may transfer significant momentum simultaneously. Both the vibrational kinetic energy of solid grains (measured by a quantity termed the granular temperature) and the pressure of the intervening pore fluid facilitate motion of grains past one another, thereby enhancing debris flow mobility. Granular temperature arises from conversion of flow translational energy to grain vibrational energy, a process that depends on shear rates, grain properties, boundary conditions, and the ambient fluid viscosity and pressure. Pore fluid pressures that exceed static equilibrium pressures result from local or global debris contraction. Like larger, natural debris flows, experimental debris flows of ???10 m3 of poorly sorted, water-saturated sediment invariably move as an unsteady surge or series of surges. Measurements at the base of experimental flows show that coarse-grained surge fronts have little or no pore fluid pressure. In contrast, finer-grained, thoroughly saturated debris behind surge fronts is nearly liquefied by high pore pressure, which persists owing to the great compressibility and moderate

  2. Aerosol-Assisted Solid Debris Collection for the National Ignition Facility

    SciTech Connect

    Nelson, S L; Shaughnessy, D A; Moody, K J; Ivanov, V V; Astanovitskiy, A L; Lewis, L A; Rundberg, R S

    2010-05-21

    collection device entirely. Our goal is to use this primary ablation wave to our advantage, by the creation of ionized alkali metal halide salt aerosols. This technique is similar to that used by many particle accelerator groups for gas-jet transport. Ideally the salt would be ablated from a substrate, encounter the reaction debris, agglomerate, and be collected for further study. We have done studies at laser and pulsed-power facilities (Titan laser at LLNL, Trident laser at LANL, Zebra z-pinch at Nevada Terawatt Facility) evaluating the hardiness of materials for placement in the NIF target chamber, as well as testing aerosol generation by the incident x-rays generated in device shots. To test this method's potential success in the NIF environment, we have tested KCl, KI, RbI, and CsI films of 1 and 2 um linear thickness on aluminum and silicon wafer substrates in these aforementioned facilities, at varied distances. These salts do ablate in the presence of sufficient x-ray fluence. Further analysis to quantify the final ablation depth as a function of x-ray fluence is ongoing. Half of each sample was masked with a thick tungsten foil for photon opacity. KCl was the most difficult salt to ablate, from comparing the tungsten-masked side of the samples to the unmasked side of the samples. This is likely due to KCl's absorbance peak being at lower wavelengths than that of KI, {approx}160 nm vs. {approx}220 nm, respectively. Samples with and without collimation were tested to identify if any condensation of these ablated salts occurred after ablation. Visual inspection of the silicon wafer witness plates placed parallel to the direction of the incident photons showed that a vapor was deposited on the wafers next to the collimators. Further analysis with EDS in the case of the collimated samples conclusively identified the vapor as CsI. We also intend to examine samples of bare substrate exposed to the same experimental conditions for post-shot change via SEM images, optical

  3. Atmospheric collection of debris from the Revelstoke and Allende fireballs

    USGS Publications Warehouse

    Carr, M.H.

    1970-01-01

    In two separate events, Revelstoke and Allende, the air through which a fireball had been observed to pass was sampled for meteoritic debris. Particulate matter was collected on fibrous filters, which were mounted on aircraft and flown downwind from the site of the meteorite fall at altitudes of 10,000-12,000 m. From Revelstoke, a highly distinctive assemblage of particles was collected. Included were large numbers of magnetite spherules, transparent siliceous spherules, and several types of irregular nickel-bearing particles. The Allende collections yielded only slightly more magnetite and siliceous spherules than background and no nickel-bearing particles. Revelstoke and Allende are believed to be representative of two different types of events. In the Revelstoke type, large amounts of meteoritic debris are left in the atmosphere and little reaches the ground in large coherent fragments; in the Allende type, little material remains in the atmosphere but large fragments reach the ground in the fall area. ?? 1970.

  4. Space Debris Environment Remediation Concepts

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.; Klinkrad, Heiner

    2009-01-01

    Long-term projections of the space debris environment indicate that even drastic measures, such as an immediate, complete halt of launch and release activities, will not result in a stable environment of man-made space objects. Collision events between already existing space hardware will within a few decades start to dominate the debris population, and result in a net increase of the space debris population, also in size regimes which may cause further catastrophic collisions. Such a collisional cascading will ultimately lead to a run-away situation ("Kessler syndrome"), with no further possibility of human intervention. The International Academy of Astronautics (IAA) has been investigating the status and the stability of the space debris environment in several studies by first looking into space traffic management possibilities and then investigating means of mitigating the creation of space debris. In an ongoing activity, an IAA study group looks at ways of active space debris environment remediation. In contrast to the former mitigation study, the current activity concentrates on the active removal of small and large objects, such as defunct spacecraft, orbital stages, and mission-related objects, which serve as a latent mass reservoir that fuels initial catastrophic collisions and later collisional cascading. The paper will outline different mass removal concepts, e.g. based on directed energy, tethers (momentum exchange or electrodynamic), aerodynamic drag augmentation, solar sails, auxiliary propulsion units, retarding surfaces, or on-orbit capture. Apart from physical principles of the proposed concepts, their applicability to different orbital regimes, and their effectiveness concerning mass removal efficiency will be analyzed. The IAA activity on space debris environment remediation is a truly international project which involves more than 23 contributing authors from 9 different nations.

  5. Optical Observations of Space Debris

    NASA Technical Reports Server (NTRS)

    Seitzer, Patrick; Abercromby, Kira; Rodriquez, Heather; Barker, Edwin S.; Kelecy, Thomas

    2008-01-01

    This viewgraph presentation reviews the use of optical telescopes to observe space debris. .It will present a brief review of how the survey is conducted, and what some of the significant results encompass. The goal is to characterize the population of debris objects at GEO, with emphasis on the faint object population. Because the survey observations extend over a very short arc (5 minutes), a full six parameter orbit can not be determined. Recently we have begun to use a second telescope, the 0.9-m at CTIO, as a chase telescope to do follow-up observations of potential GEO debris candidates found by MODEST. With a long enough sequence of observations, a full six-parameter orbit including eccentricity can be determined. The project has used STK since inception for planning observing sessions based on the distribution of bright cataloged objects and the anti-solar point (to avoid eclipse). Recently, AGI's Orbit Determination Tool Kit (ODTK) has been used to determine orbits, including the effects of solar radiation pressure. Since an unknown fraction of the faint debris at GEO has a high area-to-mass ratio (A/M), the orbits are perturbed significantly by solar radiation. The ODTK analysis results indicate that temporal variations in the solar perturbations, possibly due to debris orientation dynamics, can be estimated in the OD process. Additionally, the best results appear to be achieved when solar forces orthogonal to the object-Sun line are considered. Determining the A/M of individual objects and the distribution of A/M values of a large sample of debris is important to understanding the total population of debris at GEO

  6. Engineering development of selective agglomeration. Site closeout report

    SciTech Connect

    Not Available

    1993-04-01

    The Selective Agglomeration POC facility consisted of a coal crushing and grinding circuit, followed by an agglomeration circuit and product dewatering. (A plot plan of the facility is shown in Figure 1-2.) The coal crushing and grinding system consisted of a hammermill coal crusher, weigh-belt feeder, two ball mills (primary and secondary), and necessary hoppers, pumps, and conveyors. The mills were capable of providing coal over a range of grinds from a d{sub 50} of 125 to 25 microns. Slurry discharged from the ball mills was pumped to the agglomeration circuit. The agglomeration circuit began with a high-shear mixer, where diesel was added to the slurry to begin the formation of microagglomerates. The high-shear mixer was followed by two stages of conventional flotation cells for microagglomerate recovery. The second-stage-flotation-cell product was pumped to either a rotary-drum vacuum filter or a high-G centrifuge for dewatering. The dewatered product was then convoyed to the product pad from which dump trucks were used to transfer it to the utility plant located next to the facility. Plant tailings were pumped to the water clarifier for thickening and then dewatered in plate-and-frame filter presses. These dewatered tailings were also removed to the utility via dump truck. Clarified water (thickener overflow) was recycled to the process via a head tank.

  7. Basic principles and mechanisms of selective oil agglomeration

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.C.; Tyson, D.; Ziaoping, Qiu, Lessa, A.

    1990-04-01

    The overall objective is to determine the basic principles and mechanisms which underlie a number of selective oil agglomeration processes that have been proposed for beneficiating fine-size coal. An understanding of the basic principles and mechanisms will greatly facilitate technical development and application of such processes to various types of coal. 5 refs., 16 figs., 2 tabs.

  8. Universities' Entrepreneurial Performance: The Role of Agglomeration Economies

    ERIC Educational Resources Information Center

    Chen, Ping Penny

    2011-01-01

    In spite of the extensive research on universities' entrepreneurship, whether research strength fosters or dampens their entrepreneurial performance remains controversial. Much research claims an influential role of research universities in regional economy, however, little has been said about what a part that the agglomeration economies may play…

  9. Debris-flow observations in the Zermatt Valley

    NASA Astrophysics Data System (ADS)

    Graf, Christoph

    2015-04-01

    related slide and fall processes, increasingly large amounts of loose sediment are delivered into debris-flow systems. Extensive till, scree slopes and rock glaciers represent the principal and extensive sediment sources for debris flows which are commonly triggered at elevations between 2000 and 3000 m asl. Here, high annual and daily thermal ranges favour frost weathering and regolith production delivered to scree slopes. Slope angles in the initiation zones range from 27 to 41° and are dominated by permafrost in all of the catchments. Debris flows are triggered either through the wetting of material continuously delivered by the permafrost body to the channel or due to release at the rock glacier fronts during exceptional water input. The wetting typically occurs during rainstorms, but debris flows at these sites also happen when sediment shear resistance is reduced by the melting of ice particles, by snow melting and/or a combination of both. In the Dorfbach torrent near Randa, WSL operates an automated debris-flow observation station, measuring the typical parameters such as flow heights and velocities since several years. As part of an interdisciplinary project on data acquisition and numerical modelling of debris flows for hazard mapping, we monitor several other debris-flow prone torrents in the valley and combine these data with observations of ongoing processes in the headwater of the catchments. Several debris-flow events in some of the torrents could be observed and measured in the last years. Total volume, discharge per surge, frontal speed, run out length and impact on the inhabited fans varied considerably. Typically one first event cluster is dominated by snow melting controlled conditions starting late May until end of June and a second cluster are the rainstorm dominated events in midsummer. The largest events are expected in late summer or in fall, when long-lasting advective precipitation events over several days prevail.

  10. Stability and Temperature-Induced Agglomeration of Rh Nanoparticles Supported by CeO2.

    PubMed

    Varga, Erika; Pusztai, Péter; Oszkó, Albert; Baán, Kornélia; Erdőhelyi, András; Kónya, Zoltán; Kiss, János

    2016-03-22

    The effects of reduction by H2 and by heat treatment in vacuum and in O2 flow on Rh particle size changes of Rh/CeO2 samples were studied by X-ray photoelectron spectroscopy (XPS), high-resolution electron microscopy (HRTEM), and CO adsorption followed by diffuse reflectance infrared spectroscopy (DRIFTS). Low-temperature (373-423 K) reduction of Rh without agglomeration is demonstrated. An average particle size of 2.3 ± 1.1 nm was measured by HRTEM regardless of the metal loading (1-5%). On Rh/CeO2, a significant particle size increase of the Rh particles was detected on heating (773 K). In this work, we suggest that the temperature-induced surface decrease resulting from the sintering of Rh is favored only for well-dispersed particles. XP spectra revealed that the mobile oxygens of CeO2 fundamentally determine the oxidation state of the supported metals. At elevated temperature, the oxidation of the reduced support surface as well as the metal component takes place because of the segregation of ceria oxygens. When the aggregated particles were reoxidized, the redispersion of Rh was observed probably because of the formation of Rh-O-Ce bonds. PMID:26914641

  11. Remote Sensing of Debris Flow Deposition and Reworking by the Colorado River in Grand Canyon, Arizona

    NASA Astrophysics Data System (ADS)

    Yanites, B. J.; Webb, R. H.; Griffiths, P. G.; Magirl, C. S.

    2005-12-01

    Debris flows from 740 tributaries transport sediment ranging from clay to large (>3m) boulders into the Colorado River in Grand Canyon, Arizona. The resulting debris fans constrict the river to form rapids. Debris fans and rapids are in turn altered by the river, which entrains particles and transports them downstream. River regulation in Grand Canyon began with the closure of Glen Canyon Dam in 1963, and the geomorphic character of the debris fans has been adjusting to the change in flow regime ever since. Previous studies have suggested that the debris fans have and will continue to aggrade in response to reduced discharge on the Colorado River. In order to monitor and evaluate changes in debris fans, we created a time series of digital terrain models for two frequently aggraded debris fans (75-Mile Wash and Monument Creek) using ground surveys and photogrammetry acquired between 1984 and 2005. Two-dimensional photogrammetric analysis was extended to include years 1965 and 1973. Debris fan volume, surface area, and river constriction confirm that these two debris fans have recently aggraded owing to multiple debris flows that occurred from 1984 through 2003. Debris fan volumes increased at 75-Mile Wash by over 10,000 m3 and at Monument Creek by almost 8000 m3. Some of this aggradation is likely the effect of the preferential growth of small, non-resolvable plants and settling of sediments in topographical lows. Aggradation has also altered the geometry of the fans. Profiles of the surface models show maximum aggradation near the middle of the debris fan and a shift of surface morphology from a concave to a convex profile. Although small controlled-flood releases partially reworked both fans at the edges, reworking removed far less sediment than was added by debris-flow deposition. This is partly the result of the geography of debris-flow deposition, as material deposited in the middle of the fan can be reworked only by large floods that overtop the debris fans

  12. The Space Debris Environment for the ISS Orbit

    NASA Technical Reports Server (NTRS)

    Theall, Jeff; Liou, Jer-Chyi; Matney, Mark; Kessler, Don

    2001-01-01

    With thirty-five planned missions over the next five years, the International Space Station (ISS) will be the focus for manned space activity. At least 6 different vehicles will transport crew and supplies to and from the nominally 400 km, 51.6 degree orbit. When completed, the ISS will be the largest space structure ever assembled and hence the largest target for space debris. Recent work at the Johnson Space Center has focused on updating the existing space debris models. The Orbital Debris Engineering Model, has been restructured to take advantage of state of the art desktop computing capability and revised with recent measurements from Haystack and Goldstone radars, additional analysis of LDEF and STS impacts, and the most recent SSN catalog. The new model also contains the capability to extrapolate the current environment in time to the year 2030. A revised meteoroid model based on the work of Divine has also been developed, and is called the JSC Meteoroid Model. The new model defines flux on the target per unit angle per unit speed, and for Earth orbit, includes the meteor showers. This paper quantifies the space debris environment for the ISS orbit from natural and anthropogenic sources. Particle flux and velocity distributions as functions of size and angle are be given for particles 10 microns and larger for altitudes from 350 to 450 km. The environment is projected forward in time until 2030.

  13. ORDEM 3.0 and the Risk of High-Density Debris

    NASA Technical Reports Server (NTRS)

    Matney, Mark; Anz-Meador, Philip

    2014-01-01

    NASA’s Orbital Debris Engineering Model was designed to calculate orbital debris fluxes on spacecraft in order to assess collision risk. The newest of these models, ORDEM 3.0, has a number of features not present in previous models. One of the most important is that the populations and fluxes are now broken out into material density groups. Previous models concentrated on debris size alone, but a particle’s mass and density also determine the amount of damage it can cause. ORDEM 3.0 includes a high-density component, primarily consisting of iron/steel particles that drive much of the risk to spacecraft. This paper will outline the methods that were used to separate and identify the different densities of debris, and how these new densities affect the overall debris flux and risk.

  14. Proceedings of the 19 biennial conference of the institute for briquetting and agglomeration

    SciTech Connect

    Not Available

    1985-01-01

    This book presents the papers given at a conference on the briquetting and agglomeration of materials. Topics considered at the conference included the pelletizing of carbon black, the agglomeration of hard coal, the selection of a coal agglomerate for gasification, the briquetting of soft lignite, fiber addition for increased pellet strength, properties of granules, compaction, the Iowa agglomeration process, land disposal restrictions, the disposal of hazardous materials and industrial wastes, and the compaction of sludges from municipal waste treatment plants.

  15. Carbon particles

    DOEpatents

    Hunt, Arlon J.

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  16. Charging of space debris in the LEO and GEO regions

    NASA Astrophysics Data System (ADS)

    Sen, Abhijit; Tiwari, Sanat Kumar

    The near exponential rise of space debris at the satellite orbital altitudes (particularly in the low earth orbit (LEO) region) and the risk they pose for space assets is a source of major concern for all nations engaged in space activities. Considerable efforts are therefore being expended into accurate modeling and tracking of these objects and various ideas for the safe removal of these debris are being explored. The debris objects are likely to acquire a large amount of charge since they are typically found in a plasma environment - such as the earth’s ionospheric plasma in the LEO region (100 kms to 1000 kms) and the radiation belts in the geosynchronous orbit (GEO) region. The consequent flow of electron and ion currents on them lead to the accumulation of a large amount of surface charge and the development of a surface potential on these objects. The influence of the plasma environment on the dynamics and charging of the debris is a relatively unexplored area of Space Situational Awareness (SSA) and Space Debris (SD) research and can be potentially important for the accurate prediction of the long-term evolution of debris orbits and their collision probabilities with other space objects. In this paper we will report on the charging of space debris under a variety of orbital conditions in the LEO and GEO regions using both analytic and particle-in-cell (PIC) modeling. The analytic estimates are obtained using refined Orbit Motion Limited (OML) modeling while the simulation studies are carried out using the SPIS code [1]. In the GEO region account is taken of charging due to photoemission processes as well as energetic beam charging. The PIC approach enables us to study charging of irregularly shaped debris objects as well as differential charging on objects that are composed of patches of conducting and insulated regions. The dynamical consequences of the debris charging on their orbital trajectories and rotational characteristics will be discussed. [1] J

  17. Space Debris Environent Remediation Concepts

    NASA Astrophysics Data System (ADS)

    Klinkrad, H.; Johnson, N. L.

    2009-03-01

    Long-term projections of the space debris environment indicate that even drastic measures, such as an immediate, complete halt of launch and release activities, will not result in a stable environment of man-made space objects. Collision events between already existing space hardware will within a few decades start to dominate the debris population, and result in a net increase of the space debris population, also at sizes which may cause further catastrophic collisions. A collisional cascading may ultimately lead to a run-away situation ("Kessler syndrome"), with no further possibility of human intervention.The International Academy of Astronautics (IAA) has been investigating the status and the stability of the space debris environment in several studies by first looking into space traffic management possibilities, and then investigating means of mitigating the creation of space debris. In an on-going activity, an IAA study group looks into methods of active space debris environment remediation. In contrast to the former mitigation study, the current activity concentrates on the active removal of large objects, such as defunct spacecraft, orbital stages, and mission-related objects, which serve as a latent mass reservoir that fuels initial castastrophic collisions and later collisional cascading. The paper will outline different mass removal concepts, e.g. based on directed energy, tethers (momentum exchange or electro-dynamic), aerodynamic drag augmentation, solar sails, auxiliary propulsion units, retarding surfaces, or on-orbit capture. Apart from physical principles of the proposed concepts, their applicability to different orbital regimes, and their effectiveness concerning mass removal efficiency will be discussed.

  18. OXIDATIVE STRESS AND LIPID MEDIATORS INDUCED IN ALVEOLAR MACHROPHAGES BY ULTRAFINE PARTICLES

    EPA Science Inventory

    In ambient aerosols, ultrafine particles (UFP) and their agglomerates are considered to be major factors contributing to adverse health effects. Reactivity of agglomerated UFP of elemental carbon (EC), Printex 90, Printex G, and diesel exhaust particles (DEP) was evaluated by the...

  19. Impact of agglomeration on the relaxometric properties of paramagnetic ultra-small gadolinium oxide nanoparticles

    NASA Astrophysics Data System (ADS)

    Faucher, Luc; Gossuin, Yves; Hocq, Aline; Fortin, Marc-André

    2011-07-01

    Ultra-small gadolinium oxide nanoparticles (US-Gd2O3) are used to provide 'positive' contrast effects in magnetic resonance imaging (MRI), and are being considered for molecular and cellular imaging applications. However, these nanoparticles can aggregate over time in aqueous medium, as well as when internalized into cells. This study is aimed at measuring in vitro, in aqueous medium, the impact of aggregation on the relaxometric properties of paramagnetic US-Gd2O3 particles. First, the nanoparticle core size as well as aggregation behaviour was assessed by HRTEM. DLS (hydrodynamic diameter) was used to measure the hydrodynamic diameter of nanoparticles and nanoaggregates. The relaxometric properties were measured by NMRD profiling, as well as with 1H NMR relaxometers. Then, the positive contrast enhancement effect was assessed by using magnetic resonance scanners (at 1.5 and 7 T). At every magnetic field, the longitudinal relaxivity (r1) decreased upon agglomeration, while remaining high enough to provide positive contrast. On the other hand, the transverse relaxivity (r2) slightly decreased at 0.47 and 1.41 T, but it was enhanced at higher fields (7 and 11.7 T) upon agglomeration. All NMRD profiles revealed a characteristic relaxivity peak in the range 60-100 MHz, suggesting the possibility to use US-Gd2O3 as an efficient 'positive-T1' contrast agent at clinical magnetic fields (1-3 T), in spite of aggregation.

  20. A Collisional Algorithm for Modeling Circumstellar Debris Disks

    NASA Technical Reports Server (NTRS)

    Nesvold, Erika; Kuchner, Marc

    2011-01-01

    Many planetary systems harbor circumstellar disks of dust and planetesimals thought to be debris left over from planet formation. These debris disks exhibit a range of morphological features which can arise from the gravitational perturbations of planets. Accurate models of these features, accounting for the interactions of the particles in a disk with each other and with whatever planets they contain, can act as signposts for planets in debris disks that otherwise could not be detected. Such models can also constrain the planet's mass and orbital parameters. Current models for many disks consider the gravitational and radiative effects of the star and planets on the disk, but neglect the morphological consequences of collisional interactions between the planetesimals. Many observed disk features are not satisfactorily explained by the current generation of models. I am developing a new kind of debris disk model that considers both the gravitational shaping of the disk by planets and the inelastic collisions between particles. I will use a hybrid N-body integrator to numerically solve the equations of motion for the particles and planets in the disk. To include the collisional effects, I begin with an algorithm that tests for collisions at each step of the orbit integration and readjusts the velocities of colliding particles. I am adapting this algorithm to the problem at hand by allowing each particle to represent a "swarm" of planetesimals with a range of masses. When the algorithm detects an encounter between swarms, two or three swarms are produced to approximate the range of possible trajectories of the daughter planetesimals. Here I present preliminary results from my collisional algorithm.

  1. Analysis of debris from Spacelab Space Life Sciences-1

    NASA Astrophysics Data System (ADS)

    Caruso, S. V.; Rodgers, E. B.; Huff, T. L.

    1992-07-01

    Airborne microbiological and particulate contamination generated aboard Spacelab modules is a potential safety hazard. In order to shed light on the characteristics of these contaminants, microbial and chemical/particulate analyses were performed on debris vacuumed from cabin and avionics air filters in the Space Life Sciences-1 (SLS-1) module of the Space Transportation System 40 (STS-40) mission 1 month after landing. The debris was sorted into categories (e.g., metal, nonmetal, hair/fur, synthetic fibers, food particles, insect fragments, etc.). Elemental analysis of particles was done by energy dispersive analysis of x rays (metals) and Fourier transform infrared spectroscopy (nonmetals). Scanning electron micrographs were done of most particles. Microbiological samples were grown on R2A culture medium and identified. Clothing fibers dominated the debris by volume. Other particles, all attributed to the crew, resulted from abrasions and impacts during missions operations (e.g., paint chips, plastic, electronic scraps and clothing fibers). All bacterial species identified are commonly found in the atmosphere or on the human body. Bacillus sp. was the most frequently seen bacterium. One of the bacterial species, Enterobacter agglomerans, could cause illness in crew members with depressed immune systems.

  2. Analysis of debris from Spacelab Space Life Sciences-1

    NASA Technical Reports Server (NTRS)

    Caruso, S. V.; Rodgers, E. B.; Huff, T. L.

    1992-01-01

    Airborne microbiological and particulate contamination generated aboard Spacelab modules is a potential safety hazard. In order to shed light on the characteristics of these contaminants, microbial and chemical/particulate analyses were performed on debris vacuumed from cabin and avionics air filters in the Space Life Sciences-1 (SLS-1) module of the Space Transportation System 40 (STS-40) mission 1 month after landing. The debris was sorted into categories (e.g., metal, nonmetal, hair/fur, synthetic fibers, food particles, insect fragments, etc.). Elemental analysis of particles was done by energy dispersive analysis of x rays (metals) and Fourier transform infrared spectroscopy (nonmetals). Scanning electron micrographs were done of most particles. Microbiological samples were grown on R2A culture medium and identified. Clothing fibers dominated the debris by volume. Other particles, all attributed to the crew, resulted from abrasions and impacts during missions operations (e.g., paint chips, plastic, electronic scraps and clothing fibers). All bacterial species identified are commonly found in the atmosphere or on the human body. Bacillus sp. was the most frequently seen bacterium. One of the bacterial species, Enterobacter agglomerans, could cause illness in crew members with depressed immune systems.

  3. What is the velocity profile of debris flows?

    NASA Astrophysics Data System (ADS)

    Walter, Fabian; McArdell, Brian

    2015-04-01

    The distribution of flow velocity within a debris flow is difficult to determine at full scale in the field due to the large forces and inherently destructive nature of the flow. However, knowledge of the distribution of velocity within a flow would be helpful to constrain rheological models and to better understand the internal dynamics of such flows. Here we describe recent efforts to determine the velocity of debris flows as a function of distance from the channel bed. Measurements were made at the Illgraben, Switzerland, which exhibits a wide variety of flows, ranging from turbulent debris floods to flows which resemble laminar mud flows to more classical debris flows with a clear granular front. The Illgraben observation station is therefore an ideal location to investigate debris flow dynamics. Our measurements were made using sensors embedded on a 14 m long, 2.5 m tall steel-reinforced concrete wall constructed flush with the torrent channel walls. The main instrumentation consists of 18 geophones (10 Hz natural frequency) installed on square steel plates with a side length of 0.3 m. Each steel plate is acoustically isolated from the wall and the other plates through the use of elastomer elements. The geophone plates are arranged in six rows of three sensors with a dimension of 1.8 m in the vertical direction and 1.5 m in the horizontal direction (i.e. parallel to the flow direction). A sensorless plate separates each plate in the horizontal direction. The data are collected at 2 kHz using a high-speed (synchronous) capture card in a pc. The elevation of the flow surface is determined at a cross-stream distance 1 m away from the wall, using a laser sensor installed on a bridge above the wall. We present a processing approach for the geophone data with the goal to track particle sliding across the sensor plates. For signals near or above the sensors' natural frequency (10 Hz), the measured time series are poorly correlated between sensors. Therefore, we use a

  4. Agglomeration of tungsten carbide nanoparticles in exposure medium does not prevent uptake and toxicity toward a rainbow trout gill cell line.

    PubMed

    Kühnel, Dana; Busch, Wibke; Meissner, Tobias; Springer, Armin; Potthoff, Annegret; Richter, Volkmar; Gelinsky, Michael; Scholz, Stefan; Schirmer, Kristin

    2009-06-28

    Due to their increased production and use, engineered nanoparticles are expected to be released into the aquatic environment where particles may agglomerate. The aim of this study was to explore the role of agglomeration of nanoparticles in the uptake and expression of toxicity in the rainbow trout (Oncorhynchus mykiss) gill cell line, RTgill-W1. This cell line was chosen as model because it is known to be amenable to culture in complete as well as greatly simplified exposure media. Nano-sized tungsten carbide (WC) with or without cobalt doping (WC-Co), two materials relevant in the heavy metal industry, were applied as model particles. These particles were suspended in culture media with decreasing complexity from L15 with 10% fetal bovine serum (FBS) to L15 to L15/ex, containing only salts, galactose and pyruvate of the complete medium L15. Whereas the serum supplement in L15 retained primary nanoparticle suspensions, agglomerates were formed quickly in L15 and L15/ex. Nevertheless, scanning electron microscopy (SEM) coupled with energy dispersive X-ray (EDX) elemental analysis revealed an uptake of both WC and WC-Co nanoparticles into RTgill-W1 cells irrespective of the state of agglomeration of nanoparticles. The localisation seemed to be restricted to the cytoplasm, as no particles were observed in the nucleus of cells. Moreover, reduction in cell viability between 10 and 50% compared to controls were observed upon particle exposure in all media although the pattern of impact varied depending on the medium and exposure time. Short-term exposure of cells led to significant cytotoxicity at the highest nominal particle concentrations, irrespective of the particle type or exposure medium. In contrast, long-term exposures led to preferential toxicity in the simplest medium, L15/ex, and an enhanced toxicity by the cobalt-containing WC nanoparticles in all exposure media. The composition of the exposure media also influenced the toxicity of the cobalt ions, which may

  5. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... activation; (2) Launch vehicle explosion; (3) Aerodynamic loads; (4) Inertial loads; (5) Atmospheric reentry heating; and (6) Impact of intact vehicle. (c) Debris fragment lists. A debris analysis must produce...

  6. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... activation; (2) Launch vehicle explosion; (3) Aerodynamic loads; (4) Inertial loads; (5) Atmospheric reentry heating; and (6) Impact of intact vehicle. (c) Debris fragment lists. A debris analysis must produce...

  7. DebriSat Project Update and Planning

    NASA Technical Reports Server (NTRS)

    Sorge, M.; Krisko, P. H.

    2016-01-01

    DebriSat Reporting Topics: DebriSat Fragment Analysis Calendar; Near-term Fragment Extraction Strategy; Fragment Characterization and Database; HVI (High-Velocity Impact) Considerations; Requirements Document.

  8. NASA Orbital Debris Requirements and Best Practices

    NASA Technical Reports Server (NTRS)

    Hull, Scott

    2014-01-01

    Limitation of orbital debris accumulation is an international and national concern, reflectedin NASA debris limitation requirements. These requirements will be reviewed, along with some practices that can be employed to achieve the requirements.

  9. Differentiation of debris-flow and flash-flood deposits: implications for paleoflood investigations

    USGS Publications Warehouse

    Waythomas, Christopher F.; Jarrett, Robert D.

    1993-01-01

    Debris flows and flash floods are common geomorphic processes in the Colorado Rocky Mountain Front Range and foothills. Usually, debris flows and flash floods are associated with excess summer rainfall or snowmelt, in areas were unconsolidated surficial deposits are relatively thick and slopes are steep. In the Front Range and foothills, flash flooding is limited to areas below about 2300m whereas, debris flow activity is common throughout the foothill and alpine zones and is not necessarily elevation limited. Because flash floods and debris flows transport large quantities of bouldery sediment, the resulting deposits appear somewhat similar even though such deposits were produced by different processes. Discharge estimates based on debris-flow deposits interpreted as flash-flood deposits have large errors because techniques for discharge retrodiction were developed for water floods with negligible sediment concentrations. Criteria for differentiating between debris-flow and flash-flood deposits are most useful for deposits that are fresh and well-exposed. However, with the passage of time, both debris-flow and flash-flood deposits become modified by the combined effects of weathering, colluviation, changes in surface morphology, and in some instances removal of interstitial sediment. As a result, some of the physical characteristics of the deposits become more alike. Criteria especially applicable to older deposits are needed. We differentiate flash-flood from debris-flow and other deposits using clast fabric measurements and other morphologic and sedimentologic techniques (e.g., deposit morphology, clast lithology, particle size and shape, geomorphic setting).

  10. Electrolytic plating apparatus for discrete microsized particles

    DOEpatents

    Mayer, Anton

    1976-11-30

    Method and apparatus are disclosed for electrolytically producing very uniform coatings of a desired material on discrete microsized particles. Agglomeration or bridging of the particles during the deposition process is prevented by imparting a sufficiently random motion to the particles that they are not in contact with a powered cathode for a time sufficient for such to occur.

  11. Electroless plating apparatus for discrete microsized particles

    DOEpatents

    Mayer, Anton

    1978-01-01

    Method and apparatus are disclosed for producing very uniform coatings of a desired material on discrete microsized particles by electroless techniques. Agglomeration or bridging of the particles during the deposition process is prevented by imparting a sufficiently random motion to the particles that they are not in contact with each other for a time sufficient for such to occur.

  12. Quantitative organic vapor-particle sampler

    DOEpatents

    Gundel, Lara; Daisey, Joan M.; Stevens, Robert K.

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  13. Debris shield survivability and lifetimes for NIF

    SciTech Connect

    Davis, S; Duewer, T; Eder, D; Ertel, J; Horton, R; Latkowski, Brereton, S; MacGowan, B; Thomas, I; Tobin, M; Zaka, F

    1999-09-01

    The survivability and performance of the NIF debris shields on the National Ignition Facility are a key factor for the successful conduct and affordable operation of the facility. Estimates of debris shield lifetime in the presence of target emissions indicate severely shortened lifetimes. We have tested a new coating design that improves debris shield cleaning. A combination of modeling and continuous data collection on NIF is described/recommended to allow cost effective debris shield operation.

  14. Space Debris: Its Causes and Management

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2002-01-01

    Orbital debris is internationally recognized as an environmental issue which needs to be addressed today to preserve near-Earth space for future generations. All major space agencies are committed to mitigating the growth of the debris environment. Many commercial space system operators have responded positively to orbital debris mitigation principles and recommendations. Orbital debris mitigation measures are most cost-effective if included in the design development phase.

  15. ORDEM 3.0 and MASTER-2009 Modeled Small Debris Population Comparison

    NASA Technical Reports Server (NTRS)

    Krisko, P. H.; Flegel, S.

    2014-01-01

    The latest versions of the two premier orbital debris engineering models, NASA's ORDEM 3.0 and ESA's MASTER-2009, have been publically released. Both models have gone through significant advancements since inception, and now represent the state-of-the-art in orbital debris knowledge of their respective agencies. The purpose of these models is to provide satellite designers/operators and debris researchers with reliable estimates of the artificial debris environment in low Earth orbit (LEO) to geosynchronous orbit (GEO). The small debris environment within the size range of 1 mm to 1 cm is of particular interest to both human and robotic spacecraft programs, particularly in LEO. These objects are much more numerous than larger trackable debris and can have enough momentum to cause significant, if not catastrophic, damage to spacecraft upon impact. They are also small enough to elude routine detection by existing observation systems (radar and telescope). Without reliable detection the modeling of these populations has always coupled theoretical origins with supporting observational data in different degrees. In this paper, we present and detail the 1 mm to 1 cm orbital debris populations from both ORDEM 3.0 and MASTER-2009 in LEO. We review population categories: particle sources for MASTER-2009, particle densities for ORDEM 3.0. We describe data sources and their uses, and supporting models. Fluxes on spacecraft for chosen orbits are also presented and discussed within the context of each model.

  16. Computational methodology to predict satellite system-level effects from impacts of untrackable space debris

    NASA Astrophysics Data System (ADS)

    Welty, N.; Rudolph, M.; Schäfer, F.; Apeldoorn, J.; Janovsky, R.

    2013-07-01

    This paper presents a computational methodology to predict the satellite system-level effects resulting from impacts of untrackable space debris particles. This approach seeks to improve on traditional risk assessment practices by looking beyond the structural penetration of the satellite and predicting the physical damage to internal components and the associated functional impairment caused by untrackable debris impacts. The proposed method combines a debris flux model with the Schäfer-Ryan-Lambert ballistic limit equation (BLE), which accounts for the inherent shielding of components positioned behind the spacecraft structure wall. Individual debris particle impact trajectories and component shadowing effects are considered and the failure probabilities of individual satellite components as a function of mission time are calculated. These results are correlated to expected functional impairment using a Boolean logic model of the system functional architecture considering the functional dependencies and redundancies within the system.

  17. New technique for collecting ambient diesel particles for bioassays

    SciTech Connect

    Hallock, M.F.; Smith, T.J.; Hammond, S.K.; Beck, B.D.; Brain, J.D.

    1987-05-01

    This paper describes a new application of viable aerosol sampler, the Liquid electrostatic Aerosol Precipitator (LEAP), for the collection of diesel particles for bioassays of pulmonary toxicity and mutagenicity or carinogenicity. Currently used methods (filtration, dry electrostatic precipitation) cause agglomeration of particles and increases in particle size up to twenty-fold, which may alter particle toxicity significantly. Collection of diesel particles with the LEAP preserved submicronic particle size. Differences in chemical composition of extracts of surface adsorbents as compared to particles collected on filters also were observed. This technique may be applicable for collection other types of combustion products or oil mists that agglomerate when collected by filtration.

  18. A new technique for collecting ambient diesel particles for bioassays.

    PubMed

    Hallock, M F; Smith, T J; Hammond, S K; Beck, B D; Brain, J D

    1987-05-01

    This paper describes a new application of a viable aerosol sampler, the Liquid Electrostatic Aerosol Precipitator (LEAP), for the collection of diesel particles for bioassays of pulmonary toxicity and mutagenicity or carcinogenicity. Currently used methods (filtration, dry electrostatic precipitation) cause agglomeration of particles and increases in particle size up to twenty-fold, which may alter particle toxicity significantly. Collection of diesel particles with the LEAP preserved submicronic particle size. Differences in chemical composition of extracts of surface adsorbents as compared to particles collected on filters also were observed. This technique may be applicable for collection of other types of combustion products or oil mists that agglomerate when collected by filtration. PMID:2438921

  19. On Some Versions of the Element Agglomeration AMGe Method

    SciTech Connect

    Lashuk, I; Vassilevski, P

    2007-08-09

    The present paper deals with element-based AMG methods that target linear systems of equations coming from finite element discretizations of elliptic PDEs. The individual element information (element matrices and element topology) is the main input to construct the AMG hierarchy. We study a number of variants of the spectral agglomerate element based AMG method. The core of the algorithms relies on element agglomeration utilizing the element topology (built recursively from fine to coarse levels). The actual selection of the coarse degrees of freedom (dofs) is based on solving large number of local eigenvalue problems. Additionally, we investigate strategies for adaptive AMG as well as multigrid cycles that are more expensive than the V-cycle utilizing simple interpolation matrices and nested conjugate gradient (CG) based recursive calls between the levels. The presented algorithms are illustrated with an extensive set of experiments based on a matlab implementation of the methods.

  20. Preventing ash agglomeration during gasification of high-sodium lignite

    SciTech Connect

    Robert S. Dahlin; Johnny R. Dorminey; WanWang Peng; Roxann F. Leonard; Pannalal Vimalchand

    2009-01-15

    Various additives were evaluated to assess their ability to prevent ash agglomeration during the gasification of high-sodium lignite. Additives that showed promise in simple muffle furnace tests included meta-kaolin, vermiculite, two types of silica fume, and one type of bauxite. Additives that were tested and rejected included dolomite, calcite, sand flour, kaolinite, fine kaolin, and calcined bauxite. Based on the muffle furnace test results, the meta-kaolin was selected for a follow-on demonstration in a pilot-scale coal gasifier. Pilot-scale testing showed that the addition of coarse (minus 14-mesh, 920-{mu}m mean size) meta-kaolin at a feed rate roughly equivalent to the ash content of the lignite (10 wt %) successfully prevented agglomeration and deposition problems during gasification of high-sodium lignite at a maximum operating temperature of 927{sup o}C (1700{sup o}F). 13 refs., 24 figs., 1 tab.

  1. Engineering development of selective agglomeration: Trace element removal study

    SciTech Connect

    Not Available

    1993-09-01

    Southern Company Services, Inc., (SCS) was contracted in 1989 by the US Department of Energy (DOE) to develop a commercially acceptable selective agglomeration technology to enhance the use of high-sulfur coals by 1993. The project scope involved development of a bench-scale process and components, as well as the design, testing, and evaluation of a proof-of-concept (POC) facility. To that end, a two-ton-per-hour facility was constructed and tested near Wilsonville, Alabama. Although it was not the primary focus of the test program, SCS also measured the ability of selective agglomeration to remove trace elements from coal. This document describes the results of that program.

  2. Development of methods to predict agglomeration and disposition in FBCs

    SciTech Connect

    Mann, M.D.; Henderson, A.K.; Swanson, M.K.; Erickson, T.A.

    1995-11-01

    This 3-year, multiclient program is providing the information needed to determine the behavior of inorganic components in FBC units using advanced methods of analysis coupled with bench-scale combustion experiments. The major objectives of the program are as follows: (1) To develop further our advanced ash and deposit characterization techniques to quantify the effects of the liquid-phase components in terms of agglomerate formation and ash deposits, (2) To determine the mechanisms of inorganic transformations that lead to bed agglomeration and ash deposition in FBC systems, and (3) To develop a better means to predict the behavior of inorganic components as a function of coal composition, bed material characteristics, and combustion conditions.

  3. Functionally graded porous scaffolds made of Ti-based agglomerates.

    PubMed

    Nazari, Keivan A; Hilditch, Tim; Dargusch, Matthew S; Nouri, Alireza

    2016-10-01

    Mono- and double-layer porous scaffolds were successfully fabricated using ball-milled agglomerates of Ti and Ti-10Nb-3Mo alloy. For selectively controlling the level of porosity and pore size, the agglomerates were sieved into two different size fractions of 100-300μm and 300-500μm. Compressive mechanical properties were measured on a series of cylindrical sintered compacts with different ratios of solid core diameter to porous layer width. The graded porous scaffolds exhibited stress-strain curves typical for metallic foams with a defined plateau region after yielding. The compressive strengths and elastic moduli ranged from 300 to 700MPa and 14 to 55GPa, respectively, depending on the core diameter and the material used. The obtained properties make these materials suitable for load-bearing implant applications. PMID:27389321

  4. Is the Sky Really Falling? An Overview of Orbital Debris

    NASA Technical Reports Server (NTRS)

    Hull, Scott M.

    2015-01-01

    Orbital debris has been a prominent topic for a while, even before the movie Gravity came out. An anti-satellite test and a collision with an operational satellite both produced large highly-publicized debris clouds within recent years. While large objects like abandoned satellites and rocket bodies may be the most recognizable and identifiable concerns, a majority of the daily threat comes from the much more numerous smaller particles. In fact, small particle penetration continues to rank among the leading risks for manned space missions to the International Space Station and beyond. How much 'stuff' is up there, where did it come from, what harm can it do, and what is being done about it? These questions and more will be discussed.

  5. International Space Station (ISS) Meteoroid/Orbital Debris Shielding

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.

    1999-01-01

    Design practices to provide protection for International Space Station (ISS) crew and critical equipment from meteoroid and orbital debris (M/OD) Impacts have been developed. Damage modes and failure criteria are defined for each spacecraft system. Hypervolocity Impact -1 - and analyses are used to develop ballistic limit equations (BLEs) for each exposed spacecraft system. BLEs define Impact particle sizes that result in threshold failure of a particular spacecraft system as a function of Impact velocity, angles and particle density. The BUMPER computer code Is used to determine the probability of no penetration (PNP) that falls the spacecraft shielding based on NASA standard meteoroid/debris models, a spacecraft geometry model, and the BLEs. BUMPER results are used to verify spacecraft shielding requirements Low-weight, high-performance shielding alternatives have been developed at the NASA Johnson Space Center (JSC) Hypervelocity Impact Technology Facility (HITF) to meet spacecraft protection requirements.

  6. Laser-reactive protection of spacecraft from fine debris

    SciTech Connect

    Kuznetsov, L I; Savichev, V Yu; Tikhonov, N N

    1998-04-30

    An analysis is made of the optimal conditions for laser irradiation and of typical paths of man-made debris in laser-reactive protection of spacecraft. Protection is provided by the recoil momentum resulting from laser evaporation of the surface layers of a debris particle, which can change its path, thus avoiding an collision with a spacecraft. Estimates are obtained of changes in the paths of particles with a characteristic size 1 cm when they are irradiated by radiation from a laser located on the protected spacecraft moving along one of the circular orbits at altitudes of 200, 400, or 700 km above the Earth's surface. (laser applications and other topics in quantum electronics)

  7. Orbital Debris and Future Environment Remediation

    NASA Technical Reports Server (NTRS)

    Liou, Jer-Chyi

    2011-01-01

    This slide presentation is an overview of the historical and current orbital debris environment. Included is information about: Projected growth of the future debris population, The need for active debris removal (ADR), A grand challenge for the 21st century and The forward path

  8. Simulations of SSLV Ascent and Debris Transport

    NASA Technical Reports Server (NTRS)

    Rogers, Stuart; Aftosmis, Michael; Murman, Scott; Chan, William; Gomez, Ray; Gomez, Ray; Vicker, Darby; Stuart, Phil

    2006-01-01

    A viewgraph presentation on Computational Fluid Dynamic (CFD) Simulation of Space Shuttle Launch Vehicle (SSLV) ascent and debris transport analysis is shown. The topics include: 1) CFD simulations of the Space Shuttle Launch Vehicle ascent; 2) Debris transport analysis; 3) Debris aerodynamic modeling; and 4) Other applications.

  9. Microchemical Analysis Of Space Operation Debris

    NASA Technical Reports Server (NTRS)

    Cummings, Virginia J.; Kim, Hae Soo

    1995-01-01

    Report discusses techniques used in analyzing debris relative to space shuttle operations. Debris collected from space shuttle, expendable launch vehicles, payloads carried by space shuttle, and payloads carried by expendable launch vehicles. Optical microscopy, scanning electron microscopy with energy-dispersive spectrometry, analytical electron microscopy with wavelength-dispersive spectrometry, and X-ray diffraction chosen as techniques used in examining samples of debris.

  10. A Passive Nuclear Debris Collector.

    ERIC Educational Resources Information Center

    Griffin, John J.; And Others

    1979-01-01

    Describes a nuclear debris collector which removes trace substances from the lower atmosphere during rainfall. Suggests that the collector could be implemented into courses at various educational levels and could result in developing a network for monitoring the geographical extent of nuclear contamination. (Author/SA)

  11. Development of a full scale selective oil agglomeration plant

    SciTech Connect

    Donnelly, J.C.; Cooney, B.; Hoare, I.; Waugh, B.; Robinson, R.

    1998-12-31

    A research and development program managed by Australian Mining Investments Limited (AMI) on behalf of an investment syndicate was conducted with the objective of improving the efficiency and economy of the Selective Oil Agglomeration Process (SOAP), and developing viable commercial sized operating plants. Fewer than half the coal preparation plants in Australia beneficiate fine coal by froth flotation, the only viable alternative to SOAP for the recovery of low ash, fine and ultra fine coal. Those plants without flotation generally dispose of the ultra fine material, approximately {minus}100{micro}m in size, as tailings to waste. In the majority of cases this ultra fine waste contains more than 50% relatively low ash coal of saleable quality. It is believed that this coal constitutes a loss of 8--10 million tonnes per annum and that the coal mining industry would welcome a recovery process which has low capital and operating costs and will function automatically with minimal operator attention. The authors carried out a comprehensive literature study of selective oil agglomeration in order to gain a full understanding of the process and to plan the research program. Extensive studies were then undertaken on oil dispersion in the water phase, formation of oil water emulsions with surfactants and the optimization of surfactant selection. Oil and emulsion properties were investigated including stability, viscosity, temperature, concentration of components, time of formation, and cost. This work was followed by characterization studies on coals from the Gunnedah Basin and agglomeration test work on these coals. These agglomeration studies were performed firstly at bench level and then by using a small, 200 kg/hr continuous process development unit. The results were sufficiently encouraging to justify the design and construction of a fully instrumented, PLC controlled, 2 tph pilot plant at Gunnedah Colliery Coal Preparation Plant. Extensive trials were carried out on

  12. Parallel Element Agglomeration Algebraic Multigrid and Upscaling Library

    2015-02-19

    ParFELAG is a parallel distributed memory C++ library for numerical upscaling of finite element discretizations. It provides optimal complesity algorithms ro build multilevel hierarchies and solvers that can be used for solving a wide class of partial differential equations (elliptic, hyperbolic, saddle point problems) on general unstructured mesh (under the assumption that the topology of the agglomerated entities is correct). Additionally, a novel multilevel solver for saddle point problems with divergence constraint is implemented.

  13. Debris Detector Verification by Hvi-Tests

    NASA Astrophysics Data System (ADS)

    Bauer, Waldemar; Drolshagen, Gerhard; Vörsmann, Peter; Romberg, Oliver; Putzar, Robin

    Information regarding Space Debris (SD) or Micrometeoroids (MM) impacting on spacecraft (S/C) or payloads (P/L) can be obtained by using environmental models e.g. MASTER (ESA) or ORDEM (NASA). The validation of such models is performed by comparison of simulated results with measured or orbital observed data. The latter is utilised for large particles and can be obtained from ground based or space based radars or telescopes. Data regarding very small but abundant particles can also be gained by analysis of retrieved hardware (e.g. Hubble Space Telescope, Space Shuttle Windows), which are brought from orbit back to Earth. Furthermore, in-situ impact detectors are an essential source for information on small size meteoroids and space debris. These kind of detectors are placed in orbit and collect impact data regarding SD and MM, sending data near real time via telemetry. Compared to the impact data which is gained by analysis of retrieved surfaces, the detected data comprise additional information regarding exact impact time and, depending on the type of detector, on the orbit and particles composition. Nevertheless, existing detectors have limitations. Since the detection area is small, statistically meaningful number of impacts are obtained for very small particles only. Measurements of particles in the size range of hundreds of microns to mm which are potentially damaging to S/C require larger sensor areas. To make use of the advantages of in-situ impact detectors and to increase the amount of impact data an innovative impact detector concept is currently under development at DLR in Bremen. Different to all previous impact detectors the Solar Generator based Impact Detector (SOLID) is not an add-on component on the S/C. SOLID makes use of existing subsystems of the S/C and adopts them for impact detection purposes. Since the number of impacts on a target in space depends linearly on the exposed area, the S/C solar panels offer a unique opportunity to use them for

  14. Photometric Studies of GEO Debris

    NASA Technical Reports Server (NTRS)

    Seitzer, Patrick; Cowardin, Heather M.; Barker, Edwin; Abercromby, Kira J.; Foreman, Gary; Horstman, Matt

    2009-01-01

    The photometric signature of a debris object can be useful in determining what the physical characteristics of a piece of debris are. We report on optical observations in multiple filters of debris at geosynchronous Earth orbit (GEO). Our sample is taken from GEO objects discovered in a survey with the University of Michigan's 0.6-m aperture Schmidt telescope MODEST (for Michigan Orbital DEbris Survey Telescope), and then followed up in real-time with the SMARTS (Small and Medium Aperture Research Telescope System) 0.9-m at CTIO for orbits and photometry. Our goal is to determine 6 parameter orbits and measure colors for all objects fainter than R = 15 th magnitude that are discovered in the MODEST survey. At this magnitude the distribution of observed angular rates changes significantly from that of brighter objects. There are two objectives: 1. Estimate the orbital distribution of objects selected on the basis of two observational criteria: brightness (magnitude) and angular rates. 2. Obtain magnitudes and colors in standard astronomical filters (BVRI) for comparison with reflectance spectra of likely spacecraft materials. What is the faint debris likely to be? In this paper we report on the photometric results. For a sample of 50 objects, more than 90 calibrated sequences of R-B-V-I-R magnitudes have been obtained with the CTIO 0.9-m. For objects that do not show large brightness variations, the colors are largely redder than solar in both B-R and R-I. The width of the color distribution may be intrinsic to the nature of the surfaces, but also could be that we are seeing irregularly shaped objects and measuring the colors at different times with just one telescope. For a smaller sample of objects we have observed with synchronized CCD cameras on the two telescopes. The CTIO 0.9-m observes in B, and MODEST in R. The CCD cameras are electronically linked together so that the start time and duration of observations are the same to better than 50 milliseconds. Thus

  15. Bed Agglomeration During the Steam Gasification of a High Lignin Corn Stover Simultaneous Saccharification and Fermentation (SSF) Digester Residue

    SciTech Connect

    Howe, Daniel T.; Taasevigen, Danny J.; Gerber, Mark A.; Gray, Michel J.; Fernandez, Carlos A.; Saraf, Laxmikant; Garcia-Perez, Manuel; Wolcott, Michael P.

    2015-11-13

    This research investigates the bed agglomeration phenomena during the steam gasification of a high lignin residue produced from the simultaneous saccharification and fermentation (SSF) of corn stover in a bubbling fluidized bed. The studies were conducted at 895°C using alumina as bed material. Biomass was fed at 1.5 kg/hr, while steam was fed to give a velocity equal to 2.5 times the minimum fluidization velocity, with a steam/carbon ratio of 0.9. The pelletized feedstock was co-fed with a cooling nitrogen stream to mitigate feed line plugging issues. Tar production was high at 50.3 g/Nm3, and the fraction of C10+ compounds was greater than that seen in the gasification of traditional lignocellulosic feedstocks. Carbon closures over 94 % were achieved for all experiments. Bed agglomeration was found to be problematic, indicated by pressure drop increases observed below the bed and upstream of the feed line. Two size categories of solids were recovered from the reactor, +60 mesh and -60 mesh. After a 2.75-hour experiment, 61.7 wt % was recovered as -60 mesh particles and 38.2 wt% of the recovered reactor solids were +60 mesh. A sizeable percentage, 31.8 wt%, was +20 mesh. The -60 mesh particles were mainly formed by the initial bed material (Al2O3). Almost 50 wt. % of the + 20 mesh particles was found to be formed by organics. The unreacted carbon remaining in the reactor resulted in a low conversion rate to product gas. ICP-AES, SEM, SEM-EDS, and XRD confirmed that the large agglomerates (+ 20 mesh) were not encapsulated bed material but rather un-gasified feedstock pellets with sand particles attached to it.

  16. Factoring-in agglomeration of carbon nanotubes and nanofibers for better prediction of their toxicity versus asbestos

    PubMed Central

    2012-01-01

    Background Carbon nanotubes (CNT) and carbon nanofibers (CNF) are allotropes of carbon featuring fibrous morphology. The dimensions and high aspect ratio of CNT and CNF have prompted the comparison with naturally occurring asbestos fibers which are known to be extremely pathogenic. While the toxicity and hazardous outcomes elicited by airborne exposure to single-walled CNT or asbestos have been widely reported, very limited data are currently available describing adverse effects of respirable CNF. Results Here, we assessed pulmonary inflammation, fibrosis, oxidative stress markers and systemic immune responses to respirable CNF in comparison to single-walled CNT (SWCNT) and asbestos. Pulmonary inflammatory and fibrogenic responses to CNF, SWCNT and asbestos varied depending upon the agglomeration state of the particles/fibers. Foci of granulomatous lesions and collagen deposition were associated with dense particle-like SWCNT agglomerates, while no granuloma formation was found following exposure to fiber-like CNF or asbestos. The average thickness of the alveolar connective tissue - a marker of interstitial fibrosis - was increased 28 days post SWCNT, CNF or asbestos exposure. Exposure to SWCNT, CNF or asbestos resulted in oxidative stress evidenced by accumulations of 4-HNE and carbonylated proteins in the lung tissues. Additionally, local inflammatory and fibrogenic responses were accompanied by modified systemic immunity, as documented by decreased proliferation of splenic T cells ex vivo on day 28 post exposure. The accuracies of assessments of effective surface area for asbestos, SWCNT and CNF (based on geometrical analysis of their agglomeration) versus estimates of mass dose and number of particles were compared as predictors of toxicological outcomes. Conclusions We provide evidence that effective surface area along with mass dose rather than specific surface area or particle number are significantly correlated with toxicological responses to carbonaceous

  17. Physics of debris clouds from hypervelocity impacts

    NASA Technical Reports Server (NTRS)

    Zee, Ralph

    1993-01-01

    The protection scheme developed for long duration space platforms relies primarily upon placing thin metal plates or 'bumpers' around flight critical components. The effectiveness of this system is highly dependent upon its ability to break up and redistribute the momentum of any particle which might otherwise strike the outer surface of the spacecraft. Therefore it is of critical importance to design the bumpers such that maximum dispersion of momentum is achieved. This report is devoted to an in-depth study into the design and development of a laboratory instrument which would permit the in-situ monitoring of the momentum distribution as the impact event occurs. A series of four designs were developed, constructed and tested culminating with the working instrument which is currently in use. Each design was individually tested using the Space Environmental Effects Facility (SEEF) at the Marshall Space Flight Center in Huntsville, Alabama. Along with the development of the device, an experimental procedure was developed to assist in the investigation of various bumper materials and designs at the SEEF. Preliminary results were used to compute data which otherwise were not experimentally obtainable. These results were shown to be in relative agreement with previously obtained values derived through other methods. The results of this investigation indicated that momentum distribution could in fact be measured in-situ as the impact event occurred thus giving a more accurate determination of the effects of experimental parameters on the momentum spread. Data produced by the instrument indicated a Gaussian-type momentum distribution. A second apparatus was developed and it was placed before the shield in the line of travel utilized a plate to collect impact debris scattered backwards. This plate had a passage hole in the center to allow the particle to travel through it and impact the proposed shield material. Applying the law of conservation of angular momentum a

  18. Debris and micrometeorite impact measurements in the laboratory

    NASA Technical Reports Server (NTRS)

    Resnick, J.; Grun, J.; Crawford, J.; Burris, R.; Manka, C. K.; Ford, J. L.; Ripin, B. H.

    1992-01-01

    A method was developed to simulate space debris in the laboratory. This method, which is an outgrowth of research in inertial confinement fusion (ICF), uses laser ablation to accelerate material. Using this method, single 60 micron aluminum spheres were accelerated to 15 km/sec and larger 500 micron aluminum spheres were accelerated to 2 km/sec. Also, many small (less than 10 micron diameter) irregularly shaped particles were accelerated to speeds of 100 km/sec.

  19. Design of a shuttle-based space debris telescope

    NASA Technical Reports Server (NTRS)

    Richardson, E. H.; Talent, D. L.; Tritsch, C. L.; Vilas, F.

    1990-01-01

    A 1.6-meter diameter f/0.95 all-reflecting telescope was designed to observe orbital debris particles as small as 1 mm from the shuttle payload bay. The telescope was specified to have a flat focal surface without the imposition of refractive elements. Two design configurations involving three mirrors were evaluated - a reflective Schmidt-Cassegrain and a modified Paul corrector. The Paul system was found to be more compact and appropriate for this application.

  20. Orbital debris and meteoroid population as estimated from LDEF impact data

    NASA Technical Reports Server (NTRS)

    Zhang, Jingchang; Kessler, Donald J.

    1995-01-01

    Examination of LDEF's various surfaces shows numerous craters and holes due to hypervelocity impacts of meteoroids and man-made orbital debris. In this paper, the crater numbers as reported by Humes have been analyzed in an effort to understand the orbital debris and natural meteoroid environment in LEO. To determine the fraction of man-made to natural impacts, the side to top ratio of impacts and results of the Chemistry of Micrometeoroids Experiment are used. For craters in the 100 micron to 500 micron size range, about 25 percent to 30 percent of the impacts on the forward-facing surfaces and about 10 percent of the impacts on the trailing surfaces were estimated due to man-made orbital debris. A technique has been developed to convert crater numbers to particle fluxes, taking the fact into account that the distributions of impact velocity and incidence angle vary over the different surfaces of LDEF, as well as the ratio of the surface area flux to the cross-sectional area flux. Applying this technique, Humes' data concerning craters with limiting lip diameters of 100 micron, 200 micron and 500 micron have been converted into orbital debris and meteoroid fluxes ranging from about 20 micron to 200 micron particle diameter. The results exhibit good agreement with orbital debris model and meteoroid model. The converted meteoroid flux is slightly larger than Grun's model (by 40 to 70 percent). The converted orbital debris flux is slightly lower than Kessler's model for particle diameter smaller than about 30 micron and slightly larger than the model for particle diameter larger than about 40 micron. Taking also into account the IDE data point at about 0.8 micron particle diameter, it suggests to change the slope log (flux) versus log (diameter) of orbital debris flux in the 1 micron to 100 micron particle diameter range from 2.5 to 1.9.

  1. SCDAP/RELAP5 Modeling of Movement of Melted Material through Porous Debris in Lower Head (Rev. 2)

    SciTech Connect

    Siefken, Larry James

    1999-10-01

    A model is described for the movement of melted metallic material through a ceramic porous debris bed. The model is designed for the analysis of severe accidents in LWRs, wherein melted core plate material may slump onto the top of a porous bed of relocated core material supported by the lower head. The permeation of the melted core plate material into the porous debris bed influences the heatup of the debris bed and the heatup of the lower head supporting the debris. A model for mass transport of melted metallic material is applied that includes terms for viscosity and turbulence but neglects inertial and capillary terms because of their small value relative to gravity and viscous terms in the momentum equation. The relative permeability and passability of the porous debris are calculated as functions of debris porosity, particle size, and effective saturation. An iterative numerical solution is used to solve the set of nonlinear equations for mass transport. The effective thermal conductivity of the debris is calculated as a function of porosity, particle size, and saturation. The model integrates the equations for mass transport with a model for the two-dimensional conduction of heat through porous debris. The integrated model has been implemented into the SCDAP/RELAP5 code for the analysis of the integrity of LWR lower heads during severe accidents. The results of the model indicate that melted core plate material my permeate in about 120 s to the bottom of a 1 m deep hot porous debris bed supported by the lower head. The presence of the relocated core plate material at the bottom of the debris bed decreases the thermal resistance of the interface between the debris bed and the lower head. This report is a revision of the report with the identifier of INEEL/EXT-98-01178 REV 1, entitled "SCDAP/RELAP5 Modeling of Movement of Melted Material Through Porous Debris in Lower Head."

  2. Evaluation of optical and electronic properties of silicon nano-agglomerates embedded in SRO: applying density functional theory.

    PubMed

    Espinosa-Torres, Néstor D; la Luz, David Hernández-de; Flores-Gracia, José Francisco J; Luna-López, José A; Martínez-Juárez, Javier; Vázquez-Valerdi, Diana E

    2014-01-01

    In systems in atomic scale and nanoscale such as clusters or agglomerates constituted by particles from a few to less than 100 atoms, quantum confinement effects are very important. Their optical and electronic properties are often dependent on the size of the systems and the way in which the atoms in these clusters are bonded. Generally, these nanostructures display optical and electronic properties significantly different to those found in corresponding bulk materials. Silicon agglomerates embedded in silicon rich oxide (SRO) films have optical properties, which have been reported to be directly dependent on silicon nanocrystal size. Furthermore, the room temperature photoluminescence (PL) of SRO has repeatedly generated a huge interest due to its possible applications in optoelectronic devices. However, a plausible emission mechanism has not been widely accepted in the scientific community. In this work, we present a short review about the experimental results on silicon nanoclusters in SRO considering different techniques of growth. We focus mainly on their size, Raman spectra, and photoluminescence spectra. With this as background, we employed the density functional theory with a functional B3LYP and a basis set 6-31G* to calculate the optical and electronic properties of clusters of silicon (constituted by 15 to 20 silicon atoms). With the theoretical calculation of the structural and optical properties of silicon clusters, it is possible to evaluate the contribution of silicon agglomerates in the luminescent emission mechanism, experimentally found in thin SRO films. PMID:25276105

  3. Evaluation of optical and electronic properties of silicon nano-agglomerates embedded in SRO: applying density functional theory

    PubMed Central

    2014-01-01

    In systems in atomic scale and nanoscale such as clusters or agglomerates constituted by particles from a few to less than 100 atoms, quantum confinement effects are very important. Their optical and electronic properties are often dependent on the size of the systems and the way in which the atoms in these clusters are bonded. Generally, these nanostructures display optical and electronic properties significantly different to those found in corresponding bulk materials. Silicon agglomerates embedded in silicon rich oxide (SRO) films have optical properties, which have been reported to be directly dependent on silicon nanocrystal size. Furthermore, the room temperature photoluminescence (PL) of SRO has repeatedly generated a huge interest due to its possible applications in optoelectronic devices. However, a plausible emission mechanism has not been widely accepted in the scientific community. In this work, we present a short review about the experimental results on silicon nanoclusters in SRO considering different techniques of growth. We focus mainly on their size, Raman spectra, and photoluminescence spectra. With this as background, we employed the density functional theory with a functional B3LYP and a basis set 6-31G* to calculate the optical and electronic properties of clusters of silicon (constituted by 15 to 20 silicon atoms). With the theoretical calculation of the structural and optical properties of silicon clusters, it is possible to evaluate the contribution of silicon agglomerates in the luminescent emission mechanism, experimentally found in thin SRO films. PMID:25276105

  4. Treatability Variance for Containerised Liquids in Mixed Debris Waste - 12101

    SciTech Connect

    Alstatt, Catherine M.

    2012-07-01

    The TRU Waste Processing Center (TWPC) is a Department of Energy facility whose mission is to receive and process for appropriate disposal legacy Contact Handled (CH) and Remote Handled (RH) waste, including debris waste stored at various DOE Oak Ridge facilities. Acceptable Knowledge (AK) prepared for the waste characterizes the waste as mixed waste, meaning it is both radioactive and regulated under the Resource Conservation and Recovery Act (RCRA). The AK also indicates that a number of the debris waste packages contain small amounts of containerised liquids. The documentation indicates liquid wastes generated in routine lab operations were typically collected for potential recovery of valuable isotopes. However, during activities associated with decontamination and decommissioning (D and D), some containers with small amounts of liquids were placed into the waste containers with debris waste. Many of these containers now hold from 2.5 milliliters (ml) to 237 ml of liquid; a few contain larger volumes. At least some of these containers were likely empty at the time of generation, but documentation of this condition is lacking. Since WIPP compliant AK is developed on a waste stream basis, rather than an individual container basis, and includes every potential RCRA hazardous constituent within the waste stream, it is insufficient for the purpose of characterizing individual containers of liquid. Debris waste is defined in 40 CFR 268.2(g) as 'solid material exceeding a 60 mm particle size that is intended for disposal and that is: a manufactured object; or plant or animal matter; or natural geologic material'. The definition further states that intact containers of hazardous waste that are not ruptured and that retain at least 75% of their original volume are not debris. The prescribed treatment is removal of intact containers from the debris waste, and treatment of their contents to meet specific Land Disposal Restrictions (LDR) standards. This is true for

  5. Pebble orientation on large, experimental debris-flow deposits

    USGS Publications Warehouse

    Major, J.J.

    1998-01-01

    Replicable, pronounced orientation of discoid pebbles (??? 8 mm) embedded on surfaces of large (??? 10 m3) experimental debris-flow deposits reveals that strongly aligned, imbricate fabric can develop rapidly over short distances in mass flows. Pebble long axes aligned subparallel to deposit margins as well as subparallel to margins of surge waves arrested within the deposits. Pebble alignment exhibited modes both parallel to (a(p)), and normal to (a(t)), the primary flow direction; intermediate axes dipped preferentially inward from surge-wave margins (b(i) orientation). Repetitive development of margin-parallel, imbricate fabric distributed across deposit surfaces provides compelling evidence that deposits formed dominantly through progressive incremental accretion rather than through simple en masse emplacement. Pronounced fabric along deposit and arrested surge-wave margins reflects significant grain interaction along flow margins. This sedimentological evidence for significant marginal grain interaction complements theoretical analyses (Iverson, 1997) and other experimental data (Major, 1996: Iverson, 1997) that indicate that resistance along flow margins is an important factor affecting debris-flow deposition. The fabric on the experimental deposits demonstrates that debris flows can develop strongly imbricate particle orientation that mimics fabric developed during fluvial deposition. Particle shape and local stress fields appear to have more control over fabric development than does general depositional process. Other criteria in addition to particle orientation are needed to discriminate mass flow from fluvial gravel deposits and to unravel depositional history. ?? 1998 Elsevier Science B.V. All rights reserved.

  6. Detecting debris flows using ground vibrations

    USGS Publications Warehouse

    LaHusen, Richard G.

    1998-01-01

    Debris flows are rapidly flowing mixtures of rock debris, mud, and water that originate on steep slopes. During and following volcanic eruptions, debris flows are among the most destructive and persistent hazards. Debris flows threaten lives and property not only on volcanoes but far downstream in valleys that drain volcanoes where they arrive suddenly and inundate entire valley bottoms. Debris flows can destroy vegetation and structures in their path, including bridges and buildings. Their deposits can cover roads and railways, smother crops, and fill stream channels, thereby reducing their flood-carrying capacity and navigability.

  7. An optimal trajectory design for debris deorbiting

    NASA Astrophysics Data System (ADS)

    Ouyang, Gaoxiang; Dong, Xin; Li, Xin; Zhang, Yang

    2016-01-01

    The problem of deorbiting debris is studied in this paper. As a feasible measure, a disposable satellite would be launched, attach to debris, and deorbit the space debris using a technology named electrodynamic tether (EDT). In order to deorbit multiple debris as many as possible, a suboptimal but feasible and efficient trajectory set has been designed to allow a deorbiter satellite tour the LEO small bodies per one mission. Finally a simulation given by this paper showed that a 600 kg satellite is capable of deorbiting 6 debris objects in about 230 days.

  8. Orbital Debris Research in the United States

    NASA Technical Reports Server (NTRS)

    Stansbery, Gene

    2009-01-01

    The presentation includes information about growth of the satellite population, the U.S. Space Surveillance Network, tracking and catalog maintenance, Haystack and HAX radar observation, Goldstone radar, the Michigan Orbital Debris Survey Telescope (MODEST), spacecraft surface examinations and sample of space shuttle impacts. GEO/LEO observations from Kwajalein Atoll, NASA s Orbital Debris Engineering Model (ORDEM2008), a LEO-to-GEO Environment Debris Model (LEGEND), Debris Assessment Software (DAS) 2.0, the NASA/JSC BUMPER-II meteoroid/debris threat assessment code, satellite reentry risk assessment, optical size and shape determination, work on more complicated fragments, and spectral studies.

  9. Working group written presentation: Meteoroid/orbital debris effects on materials

    NASA Technical Reports Server (NTRS)

    Potter, Andrew

    1989-01-01

    Low earth orbit (LEO) is the most significant region relative to orbital debris, since the flux of orbital debris peaks in the region from 800 to 1000 kilometers, and the relative velocities of objects in LEO are about 10 kilometers per second. The flux and relative velocities of objects in geosynchronous orbit (GEO) are small, so that debris is not considered to be a problem in GEO. The meteoroid environment is independent of orbit or altitude, so that its effects are the same in LEO and GEO. The effects of orbital debris and meteoroid impacts can be divided into two broad regions: (1) Erosion and pitting; Small particles (less than 100 microns) are very numerous. Impacts from these generally do not lead to penetration of surfaces, but cause pitting and erosion. The Solar Max surfaces were peppered with thousands of tiny impact pits. (2) Catastrophic impacts; Large debris particles are few in number relative to small debris, so that the probability of an impact is low. However, the effects of an impact of a large particle at 10 kilometers per second are devastating. These effects are examined.

  10. The Dynamical Structure of HR 8799's Inner Debris Disk.

    PubMed

    Contro, B; Wittenmyer, Robert A; Horner, J; Marshall, Jonathan P

    2015-06-01

    The HR 8799 system, with its four giant planets and two debris belts, has an architecture closely mirroring that of our Solar system where the inner, warm asteroid belt and outer, cool Edgeworth-Kuiper belt bracket the giant planets. As such, it is a valuable laboratory for examining exoplanetary dynamics and debris disk-exoplanet interactions. Whilst the outer debris belt of HR 8799 has been well resolved by previous observations, the spatial extent of the inner disk remains unknown. This leaves a significant question mark over both the location of the planetesimals responsible for producing the belt's visible dust and the physical properties of those grains. We have performed the most extensive simulations to date of the inner, unresolved debris belt around HR 8799, using UNSW Australia's Katana supercomputing facility to follow the dynamical evolution of a model inner disk comprising 300,298 particles for a period of 60 Ma. These simulations have enabled the characterisation of the extent and structure of the inner disk in detail, and will in future allow us to provide a first estimate of the small-body impact rate and water delivery prospects for possible (as-yet undetected) terrestrial planet (s) in the inner system. PMID:25862330

  11. The dynamical structure of the HR8799 inner debris disk

    NASA Astrophysics Data System (ADS)

    Wittenmyer, Robert A.; Contro de Godoy, Bruna; Horner, Jonathan; Marshall, Jonathan P.

    2014-11-01

    The HR 8799 system, with its four giant planets and two debris belts, has an architecture closely mirroring that of our Solar System where the inner, warm asteroid belt and outer, cool Edgeworth-Kuiper belt bracket the giant planets. As such, it is a valuable laboratory for examining exoplanet dynamics and debris disc-exoplanet interactions. Whilst the outer debris belt of HR 8799 has been well resolved by previous observations, the spatial extent of the inner disc remains unknown, leaving a question mark over both the location of the planetesimals responsible for producing the belt's visible dust and the physical properties of those grains. We have performed the most extensive simulations to date of the inner, unresolved debris belt around HR 8799, using University of New South Wales's Katana supercomputing facility to follow the dynamical evolution of a model inner disc comprising 250,000 particles for a period of 100 million years. These simulations will (1) characterise the extent and structure of the inner disk in detail and (2) provide the first estimate of the small-body impact rate and water delivery prospects for possible (as-yet undetected) terrestrial planet(s) in the inner system.

  12. The Dynamical Structure of HR 8799's Inner Debris Disk

    NASA Astrophysics Data System (ADS)

    Contro, B.; Wittenmyer, Robert A.; Horner, J.; Marshall, Jonathan P.

    2015-06-01

    The HR 8799 system, with its four giant planets and two debris belts, has an architecture closely mirroring that of our Solar system where the inner, warm asteroid belt and outer, cool Edgeworth-Kuiper belt bracket the giant planets. As such, it is a valuable laboratory for examining exoplanetary dynamics and debris disk-exoplanet interactions. Whilst the outer debris belt of HR 8799 has been well resolved by previous observations, the spatial extent of the inner disk remains unknown. This leaves a significant question mark over both the location of the planetesimals responsible for producing the belt's visible dust and the physical properties of those grains. We have performed the most extensive simulations to date of the inner, unresolved debris belt around HR 8799, using UNSW Australia's Katana supercomputing facility to follow the dynamical evolution of a model inner disk comprising 300,298 particles for a period of 60 Ma. These simulations have enabled the characterisation of the extent and structure of the inner disk in detail, and will in future allow us to provide a first estimate of the small-body impact rate and water delivery prospects for possible (as-yet undetected) terrestrial planet (s) in the inner system.

  13. SCDAP/RELAP5 Modeling of Movement of Melted Material Through Porous Debris in Lower Head

    SciTech Connect

    Siefken, Larry James; Harvego, Edwin Allan

    2000-04-01

    A model is described for the movement of melted metallic material through a ceramic porous debris bed. The model is designed for the analysis of severe accidents in LWRs, wherein melted core plate material may slump onto the top of a porous bed of relocated core material supported by the lower head. The permeation of the melted core plate material into the porous debris bed influences the heatup of the debris bed and the heatup of the lower head supporting the debris. A model for mass transport of melted metallic material is applied that includes terms for viscosity and turbulence but neglects inertial and capillary terms because of their small value relative to gravity and viscous terms in the momentum equation. The relative permeability and passability of the porous debris are calculated as functions of debris porosity, particle size, and effective saturation. An iterative numerical solution is used to solve the set of nonlinear equations for mass transport. The effective thermal conductivity of the debris is calculated as a function of porosity, particle size, and saturation. The model integrates the equations for mass transport with a model for the two-dimensional conduction of heat through porous debris. The integrated model has been implemented into the SCDAP/RELAP5 code for the analysis of the integrity of LWR lower heads during severe accidents. The results of the model indicate that melted core plate material may permeate to near the bottom of a 1m deep hot porous debris bed supported by the lower head. The presence of the relocated core plate material was calculated to cause a 12% increase in the heat flux on the external surface of the lower head.

  14. SCDAP/RELAP5 modeling of movement of melted material through porous debris in lower head

    SciTech Connect

    L. J. Siefken; E. A. Harvego

    2000-04-02

    A model is described for the movement of melted metallic material through a ceramic porous debris bed. The model is designed for the analysis of severe accidents in LWRs, wherein melted core plate material may slump onto the top of a porous bed of relocated core material supported by the lower head. The permeation of the melted core plate material into the porous debris bed influences the heatup of the debris bed and the heatup of the lower head supporting the debris. A model for mass transport of melted metallic material is applied that includes terms for viscosity and turbulence but neglects inertial and capillary terms because of their small value relative to gravity and viscous terms in the momentum equation. The relative permeability and passability of the porous debris are calculated as functions of debris porosity, particle size, and effective saturation. An iterative numerical solution is used to solve the set of nonlinear equations for mass transport. The effective thermal conductivity of the debris is calculated as a function of porosity, particle size, and saturation. The model integrates the equations for mass transport with a model for the two-dimensional conduction of heat through porous debris. The integrated model has been implemented into the SCDAP/RELAP5 code for the analysis of the integrity of LWR lower heads during severe accidents. The results of the model indicate that melted core plate material may permeate to near the bottom of a 1m deep hot porous debris bed supported by the lower head. The presence of the relocated core plate material was calculated to cause a 12% increase in the heat flux on the external surface of the lower head.

  15. Space Tourism: Orbital Debris Considerations

    NASA Astrophysics Data System (ADS)

    Mahmoudian, N.; Shajiee, S.; Moghani, T.; Bahrami, M.

    2002-01-01

    Space activities after a phase of research and development, political competition and national prestige have entered an era of real commercialization. Remote sensing, earth observation, and communication are among the areas in which this growing industry is facing competition and declining government money. A project like International Space Station, which draws from public money, has not only opened a window of real multinational cooperation, but also changed space travel from a mere fantasy into a real world activity. Besides research activities for sending man to moon and Mars and other outer planets, space travel has attracted a considerable attention in recent years in the form of space tourism. Four countries from space fairing nations are actively involved in the development of space tourism. Even, nations which are either in early stages of space technology development or just beginning their space activities, have high ambitions in this area. This is worth noting considering their limited resources. At present, trips to space are available, but limited and expensive. To move beyond this point to generally available trips to orbit and week long stays in LEO, in orbital hotels, some of the required basic transportations, living requirements, and technological developments required for long stay in orbit are already underway. For tourism to develop to a real everyday business, not only the price has to come down to meaningful levels, but also safety considerations should be fully developed to attract travelers' trust. A serious hazard to space activities in general and space tourism in particular is space debris in earth orbit. Orbiting debris are man-made objects left over by space operations, hazardous to space missions. Since the higher density of debris population occurs in low earth orbit, which is also the same orbit of interest to space tourism, a careful attention should be paid to the effect of debris on tourism activities. In this study, after a

  16. Comparison of debris flux models

    NASA Astrophysics Data System (ADS)

    Sdunnus, H.; Beltrami, P.; Klinkrad, H.; Matney, M.; Nazarenko, A.; Wegener, P.

    The availability of models to estimate the impact risk from the man-made space debris and the natural meteoroid environment is essential for both, manned and unmanned satellite missions. Various independent tools based on different approaches have been developed in the past years. Due to an increased knowledge of the debris environment and its sources e.g. from improved measurement capabilities, these models could be updated regularly, providing more detailed and more reliable simulations. This paper addresses an in-depth, quantitative comparison of widely distributed debris flux models which were recently updated, namely ESA's MASTER 2001 model, NASA's ORDEM 2000 and the Russian SDPA 2000 model. The comparison was performed in the frame of the work of the 20t h Interagency Debris Coordination (IADC) meeting held in Surrey, UK. ORDEM 2000ORDEM 2000 uses careful empirical estimates of the orbit populations based onthree primary data sources - the US Space Command Catalog, the H ystackaRadar, and the Long Duration Exposure Facility spacecraft returned surfaces.Further data (e.g. HAX and Goldstone radars, impacts on Shuttle windows andradiators, and others) were used to adjust these populations for regions in time,size, and space not covered by the primary data sets. Some interpolation andextrapolation to regions with no data (such as projections into the future) wasprovided by the EVOLVE model. MASTER 2001The ESA MASTER model offers a full three dimensional description of theterrestrial debris distribution reaching from LEO up to the GEO region. Fluxresults relative to an orbiting target or to an inertial volume can be resolved intosource terms, impactor characteristics and orbit, as well as impact velocity anddirection. All relevant debris source terms are considered by the MASTERmodel. For each simulated source, a corresponding debris generation model interms of mass/diameter distribution, additional velocities, and directionalspreading has been developed. A

  17. Recent Advances in the Development and Application of Power Plate Transducers in Dense Gas Extraction and Aerosol Agglomeration Processes

    NASA Astrophysics Data System (ADS)

    Riera, E.; Cardoni, A.; Gallego-Juárez, J. A.; Acosta, V. M.; Blanco, A.; Rodríguez, G.; Blasco, M.; Herranz, L. E.

    Power ultrasound (PU) is an emerging, innovative, energy saving and environmental friendly technology that is generating a great interest in sectors such as food and pharmaceutical industries, green chemistry, environmental pollution, and other processes, where sustainable and energy efficient methods are required to improve and/or produce specific effects. Two typical effects of PU are the enhancement of mass transfer in gases and liquids, and the induction of particle agglomeration in aerosols. These effects are activated by a variety of mechanisms associated to the nonlinear propagation of high amplitude ultrasonic waves such as diffusion, agitation, entrainment, turbulence, etc. During the last years a great effort has been jointly made by the Spanish National Research Council (CSIC) and the company Pusonics towards introducing novel processes into the market based on airborne ultrasonic plate transducers. This technology was specifically developed for the treatment of gas and multiphasic media characterized by low specific acoustic impedance and high acoustic absorption. Different strategies have been developed to mitigate the effects of the nonlinear dynamic behavior of such ultrasonic piezoelectric transducers in order to enhance and stabilize their response at operational power conditions. This work deals with the latter advances in the mitigation of nonlinear problems found in power transducers; besides it describes two applications assisted by ultrasound developed at semi-industrial and laboratory scales and consisting in extraction via dense gases and particle agglomeration. Dense Gas Extraction (DGE) assisted by PU is a new process with a potential to enhance the extraction kinetics with supercritical CO2. Acoustic agglomeration of fine aerosol particles has a great potential for the treatment of air pollution problems generated by particulate materials. Experimental and numerical results in both processes will be shown and discussed.

  18. Study of the structuralization of the magnetic particles in magnetic fluids

    NASA Astrophysics Data System (ADS)

    Tomco, L.; Kopcansky, P.; Koneracka, M.; Kellnerova, V.

    1994-03-01

    A magnetic field induced agglomeration of magnetic particles in magnetic fluids (mineral oil and kerosene based) with several volume concentrations was studied by means of optical microscope equipped with a video camera. Scrutiny of the video revealed that time evolution of the aggregation process results from two processes i.e.: (1) the formation of new (or primary) agglomerations (t less than or equal to 2s); and (2) the coalescence of primary agglomerations (t greater than 2s).

  19. Surfactant protein A (SP-A) inhibits agglomeration and macrophage uptake of toxic amine modified nanoparticles

    PubMed Central

    McKenzie, Zofi; Kendall, Michaela; Mackay, Rose-Marie; Whitwell, Harry; Elgy, Christine; Ding, Ping; Mahajan, Sumeet; Morgan, Cliff; Griffiths, Mark; Clark, Howard; Madsen, Jens

    2015-01-01

    Abstract The lung provides the main route for nanomaterial exposure. Surfactant protein A (SP-A) is an important respiratory innate immune molecule with the ability to bind or opsonise pathogens to enhance phagocytic removal from the airways. We hypothesised that SP-A, like surfactant protein D, may interact with inhaled nanoparticulates, and that this interaction will be affected by nanoparticle (NP) surface characteristics. In this study, we characterise the interaction of SP-A with unmodified (U-PS) and amine-modified (A-PS) polystyrene particles of varying size and zeta potential using dynamic light scatter analysis. SP-A associated with both 100 nm U-PS and A-PS in a calcium-independent manner. SP-A induced significant calcium-dependent agglomeration of 100 nm U-PS NPs but resulted in calcium-independent inhibition of A-PS self agglomeration. SP-A enhanced uptake of 100 nm U-PS into macrophage-like RAW264.7 cells in a dose-dependent manner but in contrast inhibited A-PS uptake. Reduced association of A-PS particles in RAW264.7 cells following pre-incubation of SP-A was also observed with coherent anti-Stokes Raman spectroscopy. Consistent with these findings, alveolar macrophages (AMs) from SP-A−/− mice were more efficient at uptake of 100 nm A-PS compared with wild type C57Bl/6 macrophages. No difference in uptake was observed with 500 nm U-PS or A-PS particles. Pre-incubation with SP-A resulted in a significant decrease in uptake of 100 nm A-PS in macrophages isolated from both groups of mice. In contrast, increased uptake by AMs of U-PS was observed after pre-incubation with SP-A. Thus we have demonstrated that SP-A promotes uptake of non-toxic U-PS particles but inhibits the clearance of potentially toxic A-PS particles by blocking uptake into macrophages. PMID:25676620

  20. Warm Debris Disks from WISE

    NASA Technical Reports Server (NTRS)

    Padgett, Deborah L.

    2011-01-01

    "The Wide Field Infrared Survey Explorer (WISE) has just completed a sensitive all-sky survey in photometric bands at 3.4, 4.6, 12, and 22 microns. We report on a preliminary investigation of main sequence Hipparcos and Tycho catalog stars with 22 micron emission in excess of photospheric levels. This warm excess emission traces material in the circumstellar region likely to host terrestrial planets and is preferentially found in young systems with ages < 1 Gyr. Nearly a hundred new warm debris disk candidates are detected among FGK stars and a similar number of A stars within 120 pc. We are in the process of obtaining spectra to determine spectral types and activity level of these stars and are using HST, Herschel and Keck to characterize the dust, multiplicity, and substellar companions of these systems. In this contribution, we will discuss source selection methods and individual examples from among the WISE debris disk candidates. "

  1. Comparison of space debris estimates

    SciTech Connect

    Canavan, G.H.; Judd, O.P.; Naka, R.F.

    1996-10-01

    Debris is thought to be a hazard to space systems through impact and cascading. The current environment is assessed as not threatening to defense systems. Projected reductions in launch rates to LEO should delay concerns for centuries. There is agreement between AFSPC and NASA analyses on catalogs and collision rates, but not on fragmentation rates. Experiments in the laboratory, field, and space are consistent with AFSPC estimates of the number of fragments per collision. A more careful treatment of growth rates greatly reduces long-term stability issues. Space debris has not been shown to be an issue in coming centuries; thus, it does not appear necessary for the Air Force to take additional steps to mitigate it.

  2. Debris flow study in Malaysia

    NASA Astrophysics Data System (ADS)

    Bahrin Jaafar, Kamal

    2016-04-01

    The phenomenon of debris flow occurs in Malaysia occasionally. The topography of Peningsular Malysia is characterized by the central mountain ranges running from south to north. Several parts of hilly areas with steep slopes, combined with high saturation of soil strata that deliberately increase the pore water pressure underneath the hill slope. As a tropical country Malaysia has very high intensity rainfall which is triggered the landslide. In the study area where the debris flow are bound to occur, there are a few factors that contribute to this phenomenon such as high rainfall intensity, very steep slope which an inclination more than 35 degree and sandy clay soil type which is easily change to liquidity soil. This paper will discuss the study of rainfall, mechanism, modeling and design of mitigation measure to avoid repeated failure in future in same area.

  3. Debris Disks and Hidden Planets

    NASA Technical Reports Server (NTRS)

    Kuchner, Marc

    2008-01-01

    When a planet orbits inside a debris disk like the disk around Vega or Beta Pictoris, the planet may be invisible, but the patterns it creates in the disk may give it away. Observing and decoding these patterns may be the only way we can detect exo-Neptunes orbiting more than 20 AU from their stars, and the only way we can spot planets in systems undergoing the late stages of planet formation. Fortunately, every few months, a new image of a debris disk appears with curious structures begging for explanation. I'll describe some new ideas in the theory of these planet-disk interactions and provide a buyers guide to the latest models (and the planets they predict).

  4. Meteoroid and space debris impacts in grazing-incidence telescopes

    NASA Astrophysics Data System (ADS)

    Carpenter, J. D.; Wells, A.; Abbey, A. F.; Ambrosi, R. M.

    2008-06-01

    Context: Micrometeoroid or space debris impacts have been observed in the focal planes of the XMM-Newton and Swift-XRT (X-ray Telescope) X-ray observatories. These impacts have resulted in damage to, and in one case the failure of, focal-plane Charge-Coupled Device (CCDs) detectors. Aims: We aim to quantify the future risks of focal-plane impacts in present and future X-ray observatories. Methods: We present a simple model for the propagation of micrometeoroids and space debris particles into telescopes with grazing-incidence X-ray optics, which is based on the results of previous investigations into grazing-incidence hypervelocity impacts by microscopic particles. We then calculate micrometeoroid and space debris fluxes using the Micrometeoroid and Space Debris Terrestrial Environment Reference model (MASTER2005). The risks of future focal-plane impact events in three present (Swift-XRT, XMM-Newton, and Chandra) and two future (SIMBOL-X and XEUS) X-ray observatories are then estimated on the basis of the calculated fluxes and the model for particle propagation. Results: The probabilities of at least one impact occurring in the Swift-XRT, XMM-Newton, and Chandra focal planes, in a one year period from the time of writing in November 2007 are calculated to be ~5% and ~50% and ~3%. First-order predictions of the impact rates expected for the future SIMBOL-X and XEUS X-ray observatories yield probabilities for at least one focal-plane impact, during nominal 5-year missions, of more than 94% and 99%, respectively. Conclusions: The propagation of micrometeoroids and space debris particles into the focal planes of X-ray telescopes is highest for Wolter optics with the largest collecting areas and the lowest grazing angles. Telescopes in low-Earth orbits encounter enhanced particle fluxes compared with those in higher orbits and a pointing avoidance strategy for certain directions can reduce the risk of impacts. Future X-ray observatories, with large collecting areas and

  5. Modeling debris-covered glaciers: extension due to steady debris input

    NASA Astrophysics Data System (ADS)

    Anderson, L. S.; Anderson, R. S.

    2015-11-01

    Debris-covered glaciers are common in rapidly-eroding alpine landscapes. When thicker than a few centimeters, surface debris suppresses melt rates. If continuous debris cover is present, mass balance gradients can be reduced leading to increases in glacier length. In order to quantify feedbacks in the debris-glacier-climate system, we developed a 2-D long-valley numerical glacier model that includes englacial and supraglacial advection. We ran 120 simulations in which a steady state debris-free glacier responds to a step increase of surface debris deposition. Simulated glaciers advance to steady states in which ice accumulation equals ice ablation, and debris input equals debris loss from the glacier. Our model and parameter selections produce two-fold increases in glacier length. Debris flux onto the glacier and the relationship between debris thickness and melt rate strongly control glacier length. Debris deposited near the equilibrium-line altitude, where ice discharge is high, results in the greatest glacier extension when other debris related variables are held constant. Continuous debris cover reduces ice discharge gradients, ice thickness gradients, and velocity gradients relative to initial debris-free glaciers. Debris-forced glacier extension decreases the ratio of accumulation zone to total glacier area (AAR). The model reproduces first-order relationships between debris cover, AARs, and glacier surface velocities from glaciers in High Asia. We provide a quantitative, theoretical foundation to interpret the effect of debris cover on the moraine record, and to assess the effects of climate change on debris-covered glaciers.

  6. Workers Search for Columbia's Debris

    NASA Technical Reports Server (NTRS)

    2003-01-01

    Members of a US Forest Service search team walk a grid during a Columbia recovery search near the Hemphill, Texas site. The group is accompanied by a space program worker able to identify potential hazards of Shuttle parts. Workers from every NASA Center and numerous federal, state, and local agencies searched for Columbia's debris in the recovery effort. For more information on STS-107, please see GRIN Columbia General Explanation

  7. Orbital Debris Observations with WFCAM

    NASA Astrophysics Data System (ADS)

    Kendrick, R.; Mann, B.; Read, M.; Kerr, T.; Irwin, M.; Cross, N.; Bold, M.,; Varricatt, W.; Madsen, G.

    2014-09-01

    The United Kingdom Infrared Telescope has been operating for 35 years on the summit of Mauna Kea as a premier Infrared astronomical facility. In its 35th year the telescope has been turned over to a new operating group consisting of University of Arizona, University of Hawaii and the LM Advanced Technology Center. UKIRT will continue its astronomical mission with a portion of observing time dedicated to orbital debris and Near Earth Object detection and characterization. During the past 10 years the UKIRT Wide Field CAMera (WFCAM) has been performing large area astronomical surveys in the J, H and K bands. The data for these surveys have been reduced by the Cambridge Astronomical Survey Unit in Cambridge, England and archived by the Wide Field Astronomy Unit in Edinburgh, Scotland. During January and February of 2014 the Wide Field CAMera (WFCAM) was used to scan through the geostationary satellite belt detecting operational satellites as well as nearby debris. Accurate photometric and astrometric parameters have been developed by CASU for each of the detections and all data has been archived by WFAU. This paper will present the January and February results of the orbital debris surveys with WFCAM.

  8. Lightcurves of Extreme Debris Disks

    NASA Astrophysics Data System (ADS)

    Rieke, George; Meng, Huan; Su, Kate

    2012-12-01

    We have recently discovered that some planetary debris disks with extreme fractional luminosities are variable on the timescale of a few years. This behavior opens a new possibility to understand planet building. Two of the known variable disks are around solar-like stars in the age range of 30 to 100+ Myr, which is the expected era of the final stages of terrestrial planet building. Such variability can be attributed to violent collisions (up to ones on the scale of the Moon-forming event between the proto-Earth and another proto-planet). The collisional cascades that are the aftermaths of these events can produce large clouds of tiny dust grains, possibly even condensed from silica vapor. A Spitzer pilot program has obtained the lightcurve of such a debris disk and caught two minor outbursts. Here we propose to continue the lightcurve monitoring with higher sampling rates and to expand it to more disks. The proposed time domain observations are a new dimension of debris disk studies that can bring unique insight to their evolution, providing important constraints on the collisional and dynamical models of terrestrial planet formation.

  9. An online debris sensor system with vibration resistance for lubrication analysis

    NASA Astrophysics Data System (ADS)

    Ding, Yongbin; Wang, Yanxue; Xiang, Jiawei

    2016-02-01

    The health condition of the lubricated systems can be directly indicated by the concentration and material type of the abrasive particles, which may provide very early warnings of faults/failures and benefit the condition based maintenance. Oil debris particle detecting techniques are thus important for machinery condition monitoring and fault diagnosis. This work proposes a new structure of online debris sensor (ODS), which applies the radial magnetic field, different from the traditional axial magnetic field. The designed ODS can effectively reduce the interferences of the background noise and the vibration of the machine in operation. Moreover, in order to optimally determine the number of turns of an inductive coil and the current of the drive coils, two methods are developed respectively in this work which can ensure sensitivity and anti-vibration features of the ODS. The instrumentation circuit system for detecting debris particles and sensing signals has been also designed to extract and to record the signatures of particles. The designed ODS device is then applied to analyze micro debris particles in the lubricating system on a test rig. Experimental results have demonstrated that ODS can successfully detect the 120 μm(H) ferrous particles and 500 μm(H) non-ferrous particles under vibration conditions.

  10. An online debris sensor system with vibration resistance for lubrication analysis.

    PubMed

    Ding, Yongbin; Wang, Yanxue; Xiang, Jiawei

    2016-02-01

    The health condition of the lubricated systems can be directly indicated by the concentration and material type of the abrasive particles, which may provide very early warnings of faults/failures and benefit the condition based maintenance. Oil debris particle detecting techniques are thus important for machinery condition monitoring and fault diagnosis. This work proposes a new structure of online debris sensor (ODS), which applies the radial magnetic field, different from the traditional axial magnetic field. The designed ODS can effectively reduce the interferences of the background noise and the vibration of the machine in operation. Moreover, in order to optimally determine the number of turns of an inductive coil and the current of the drive coils, two methods are developed respectively in this work which can ensure sensitivity and anti-vibration features of the ODS. The instrumentation circuit system for detecting debris particles and sensing signals has been also designed to extract and to record the signatures of particles. The designed ODS device is then applied to analyze micro debris particles in the lubricating system on a test rig. Experimental results have demonstrated that ODS can successfully detect the 120 μm(H) ferrous particles and 500 μm(H) non-ferrous particles under vibration conditions. PMID:26931893

  11. Debris flows from tributaries of the Colorado River, Grand Canyon National Park, Arizona

    USGS Publications Warehouse

    Webb, Robert H.; Pringle, Patrick T.; Rink, Glenn R.

    1989-01-01

    second. The debris flow of 1966 in the Crystal Creek drainage had a discharge estimated between 9,200 and 14,000 cubic feet per second. Determination of the effective cross-sectional area was a problem in all calculations involving superelevations on bends because areas near superelevation marks were 1.5 to 3.5 times larger than areas of upstream or downstream cross sections. Debris flows in the Grand Canyon generally are composed of 10 to 40 percent sand by weight and may represent a significant source of beach-building sand along the Colorado River. The particle-size distributions are very poorly sorted and the largest transported boulders were in the Crystal Creek drainage. The large boulders transported into the Colorado River by debris flows create or change hydraulic controls (rapids); these controls appear to be governed by the magnitude and frequency of tributary-flow events and the history of discharges on the Colorado River. Reworking of debris fans by the Colorado River creates debris bars that constrain the size of eddy systems and forms secondary rapids and riffles below tributary mouths.

  12. Space Shuttle Solid Rocket Booster Debris Assessment

    NASA Technical Reports Server (NTRS)

    Kendall, Kristin; Kanner, Howard; Yu, Weiping

    2006-01-01

    The Space Shuttle Columbia Accident revealed a fundamental problem of the Space Shuttle Program regarding debris. Prior to the tragedy, the Space Shuttle requirement stated that no debris should be liberated that would jeopardize the flight crew and/or mission success. When the accident investigation determined that a large piece of foam debris was the primary cause of the loss of the shuttle and crew, it became apparent that the risk and scope of - damage that could be caused by certain types of debris, especially - ice and foam, were not fully understood. There was no clear understanding of the materials that could become debris, the path the debris might take during flight, the structures the debris might impact or the damage the impact might cause. In addition to supporting the primary NASA and USA goal of returning the Space Shuttle to flight by understanding the SRB debris environment and capability to withstand that environment, the SRB debris assessment project was divided into four primary tasks that were required to be completed to support the RTF goal. These tasks were (1) debris environment definition, (2) impact testing, (3) model correlation and (4) hardware evaluation. Additionally, the project aligned with USA's corporate goals of safety, customer satisfaction, professional development and fiscal accountability.

  13. NASA Orbital Debris Large-Object Baseline Population in ORDEM 3.0

    NASA Technical Reports Server (NTRS)

    Krisco, Paula H.; Vavrin, A. B.; Anz-Meador, P. D.

    2013-01-01

    The NASA Orbital Debris Program Office (ODPO) has created and validated high fidelity populations of the debris environment for the latest Orbital Debris Engineering Model (ORDEM 3.0). Though the model includes fluxes of objects 10 um and larger, this paper considers particle fluxes for 1 cm and larger debris objects from low Earth orbit (LEO) through Geosynchronous Transfer Orbit (GTO). These are validated by several reliable radar observations through the Space Surveillance Network (SSN), Haystack, and HAX radars. ORDEM 3.0 populations were designed for the purpose of assisting, debris researchers and sensor developers in planning and testing. This environment includes a background derived from the LEO-to-GEO ENvironment Debris evolutionary model (LEGEND) with a Bayesian rescaling as well as specific events such as the FY-1C anti-satellite test, the Iridium 33/Cosmos 2251 accidental collision, and the Soviet/Russian Radar Ocean Reconnaissance Satellite (RORSAT) sodium-potassium droplet releases. The environment described in this paper is the most realistic orbital debris population larger than 1 cm, to date. We describe derivations of the background population and added specific populations. We present sample validation charts of our 1 cm and larger LEO population against Space Surveillance Network (SSN), Haystack, and HAX radar measurements.

  14. Field observations of artificial sand and oil agglomerates

    USGS Publications Warehouse

    Dalyander, Patricia (Soupy); Long, Joseph W.; Plant, Nathaniel G.; McLaughlin, Molly R.; Mickey, Rangley C.

    2015-01-01

    Oil that comes into the surf zone following spills, such as occurred during the 2010 Deepwater Horizon (DWH) blowout, can mix with local sediment to form heavier-than-water sand and oil agglomerates (SOAs), at times in the form of mats a few centimeters thick and tens of meters long. Smaller agglomerates that form in situ or pieces that break off of larger mats, sometimes referred to as surface residual balls (SRBs), range in size from sand-sized grains to patty-shaped pieces several centimeters (cm) in diameter. These mobile SOAs can cause beach oiling for extended periods following the spill, on the scale of years as in the case of DWH. Limited research, including a prior effort by the U.S. Geological Survey (USGS) investigating SOA mobility, alongshore transport, and seafloor interaction using numerical model output, focused on the physical dynamics of SOAs. To address this data gap, we constructed artificial sand and oil agglomerates (aSOAs) with sand and paraffin wax to mimic the size and density of genuine SOAs. These aSOAs were deployed in the nearshore off the coast of St. Petersburg, Florida, during a field experiment to investigate their movement and seafloor interaction. This report presents the methodology for constructing aSOAs and describes the field experiment. Data acquired during the field campaign, including videos and images of aSOA movement in the nearshore (1.5-meter and 0.5-meter water depth) and in the swash zone, are also presented in this report.

  15. KT Boundary Impact Debris from DSDP Site 577

    NASA Technical Reports Server (NTRS)

    Kyte, Frank T.; Vakulenko, Marta

    2001-01-01

    The KT boundary at DSDP Site 577 (Shatsky Rise, western North Pacific) is in a calcareous nannofossil ooze. It is bioturbated so Ir and impact debris are smeared across less than 15 cm of core. An absence of sulfides and chalcophile enrichment and the presence of Mn-micronodules indicate that this boundary did not experience anoxic conditions typical of many other calcareous KT sites. Because of its shallow burial (109 m) ejecta is extremely well preserved and has been the subject of numerous studies. Three high-temperature minerals have been identified at this site. Clinopyroxene (cpx), found only at Site 577 may be precursor to diagenetic sanidine in some European sites. Magnesioferrite spinel has the highest Fe2O3/FeO of any locality and can have and trace inclusions of Ni-magnesiowustite, which is known at only one other site (Site 596). Other debris described includes shocked quartz grains less than 200 microns, hollow spherules possibly related to impact melt glasses found near Chicxulub, and irregular Ir-rich particles that may be derived directly from meteoritic materials. The latter may be related to the fossil meteorite found at Site 576, just 500 km to the east. A large-volume (approx. 10 cc) sample was taken to systematically characterize debris. The less than 60 microns fraction of the carbonate-free sediment contained 44 mg of impact debris. 2700 particles less than l00 microns were classified based on color, shape, and morphology. About 55% are generally light colored, composed mostly of clays, and typically lack magnesioferrite spinel. Less than half of these are quite spherical; many have irregular shapes, possibly from fragmentation. Hollow spherules with smooth shiny surfaces are only 2% of the total but many fragments in the 60 - 100 microns fraction suggest that they were more abundant and that some may have been quite large; 800 microns or more. Cpx-bearing spherules, easily identified by green crystals at the surface, constitute only 2.5% of

  16. Intra-metropolitan migration in the Warsaw agglomeration.

    PubMed

    Rykiel, Z

    1984-01-01

    "Two questions of intra-metropolitan migration are analyzed in the paper, intra-metropolitan hierarchy and intra-metropolitan spatial barriers. The former embraces four detailed questions: ranking of centers; spatial pattern of hierarchical subordination; degree of unequivocalness of the subordinations, or degree of dominance; and degree of hierarchicality of interrelationships. Two specialties of the Warsaw [Poland] agglomeration are discussed, the influence of the present crisis, and the administrative restrictions to migration to the city, or the spatial barriers. Social connotations of the latter are also presented." PMID:12312885

  17. Coolability of LWR debris: a summary of the DCC experiments

    SciTech Connect

    Reed, A.W.; Boldt, K.R.; Schmidt, T.R.

    1985-01-01

    The Degraded Core Coolability (DCC) experiments were designed to examine post-accident heat removal from reactor fuel debris using prototypic materials over a pressure range of 1 to 170 atmospheres. The purpose of these experiments is to provide dryout data for comparison with current predictive models. DCC-1 was composed of smaller particles (effective diameter of 0.31 diameter) and produced dryout heat fluxes below those expected in a reactor accident. The pressure dependence of the dryout flux was less than anticipated. DCC-2 was composed of larger particles (effective diameter of 1.43 mm) and was a coolable configuration. Stable localized dryouts were observed as well as global dryouts. DCC-3 was a stratified bed in which smaller particles (effective diameter of 0.92 mm) overlay larger particles (effective diameter of 3.64 mm). As predicted by current models, this configuration was uncoolable even though a homogeneous bed composed exclusively of the smaller particles would have been coolable. This demonstrated the impact that surface tension forces can have even in a deep bed. The effect of inlet flow was also demonstrated in DCC-3. By injecting a small amount of water at the bottom of the debris bed, the dryout heat level was increased six-fold to in excess of 0.25 W/g. 14 refs.

  18. Momentum distribution in debris cloud during hypervelocity impact

    NASA Technical Reports Server (NTRS)

    Lemaster, P.; Mount, A.; Zee, R. H.

    1992-01-01

    The long term operation of the Space Station Freedom requires a scheme to protect it from high velocity impacts by both man-made particles and micrometeor fragments. One such scheme is the use of metal plates to serve as shields against such orbital debris. These 'bumper' plates, as they are referred to, serve to break up any incident particle and redistribute its momentum over a larger area. It is therefore necessary to determine the momentum distribution within the debris cloud produced by such collisions in order to evaluate a materials effectiveness at accomplishing this task. This paper details the design and development of an innovative device which has made this possible. Momentum profiles were obtained for a series of test conditions. Total momentum values in the debris cloud were then calculated from these profiles. These results indicated that a momentum amplification exists with a multiplication factor of between 2 and 3. Thus the role of the bumper to serve as a means for momentum redistribution and not reduction was verified.

  19. Active space debris charging for contactless electrostatic disposal maneuvers

    NASA Astrophysics Data System (ADS)

    Schaub, Hanspeter; Sternovsky, Zoltán

    2014-01-01

    The remote charging of a passive object using an electron beam enables touchless re-orbiting of large space debris from geosynchronous orbit (GEO) using electrostatic forces. The advantage of this method is that it can operate with a separation distance of multiple craft radii, thus reducing the risk of collision. The charging of the tug-debris system to high potentials is achieved by active charge transfer using a directed electron beam. Optimal potential distributions using isolated- and coupled-sphere models are discussed. A simple charging model takes into account the primary electron beam current, ultra-violet radiation induced photoelectron emission, collection of plasma particles, secondary electron emission and the recapture of emitted particles. The results show that through active charging in a GEO space environment high potentials can be both achieved and maintained with about a 75% transfer efficiency. Further, the maximum electrostatic tractor force is shown to be insensitive to beam current levels. This latter later result is important when considering debris with unknown properties.

  20. Relationships among the abundances of plastic debris in different size classes on beaches in South Korea.

    PubMed

    Lee, Jongmyoung; Hong, Sunwook; Song, Young Kyung; Hong, Sang Hee; Jang, Yong Chang; Jang, Mi; Heo, Nak Won; Han, Gi Myung; Lee, Mi Jeong; Kang, Daeseok; Shim, Won Joon

    2013-12-15

    Plastic debris on six beaches near the Nakdong River Estuary, South Korea, was sampled in May and September 2012 and classified into three size classes, large microplastics (1-5 mm), mesoplastics (5-25 mm), and macroplastics (>25 mm). The relationships among the abundances of the size classes were then examined. The abundances of each size category in May (before rainy season) and in September (after rainy season) were 8205 and 27,606 particles/m(2) for large microplastics, 238 and 237 particles/m(2) for mesoplastics, and 0.97 and 1.03 particles/m(2) for macroplastics, respectively. Styrofoam was the most abundant item both in microplastic and mesoplastic debris, while intact plastics were most common in macroplastic debris. The abundances of meso- and micro-plastics were the most strongly correlated. There was a higher correlation between the abundances of macro- and meso-plastics than between macro- and micro-plastics. PMID:24054782

  1. Debris from terrestrial planet formation: the Moon-forming collision

    NASA Astrophysics Data System (ADS)

    Jackson, Alan P.; Wyatt, Mark C.

    2012-09-01

    We study the evolution of debris created in the giant impacts expected during the final stages of terrestrial planet formation. The starting point is the debris created in a simulation of the Moon-forming impact. The dynamical evolution is followed for 10 Myr including the effects of Earth, Venus, Mars and Jupiter. The spatial distribution evolves from a clump in the first few months to an asymmetric ring for the first 10 kyr and finally becoming an axisymmetric ring by about 1 Myr after the impact. By 10 Myr after the impact 20 per cent of the particles have been accreted on to Earth and 17 per cent on to Venus, with 8 per cent ejected by Jupiter and other bodies playing minor roles. However, the fate of the debris also depends strongly on how fast it is collisionally depleted, which depends on the poorly constrained size distribution of the impact debris. Assuming that the debris is made up of 30 per cent by mass mm-cm-sized vapour condensates and 70 per cent boulders up to 500 km, we find that the condensates deplete rapidly on ˜1000 yr time-scales, whereas the boulders deplete predominantly dynamically. By considering the luminosity of dust produced in collisions within the boulder-debris distribution we find that the Moon-forming impact would have been readily detectable around other stars in Spitzer 24 μm surveys for around 25 Myr after the impact, with levels of emission comparable to many known hot dust systems. The vapour condensates meanwhile produce a short-lived, optically thick, spike of emission. We use these surveys to make an estimate of the fraction of stars that form terrestrial planets, FTPF. Since current terrestrial planet formation models invoke multiple giant impacts, the low fraction of 10-100 Myr stars found to have warm (>rsim150 K) dust implies that FTPF≲10 per cent. For this number to be higher, it would require that either terrestrial planets are largely fully formed when the protoplanetary disc disperses, or that impact generated

  2. Improving The Near-Earth Meteoroid And Orbital Debris Environment Definition With LAD-C

    NASA Technical Reports Server (NTRS)

    Liou, J.-C.; Giovane, F. J.; Corsaro, R. C.; Burchell, M. J.; Drolshagen, G.; Kawai, H.; Tabata, M.; Stansbery, E. G.; Westphal, A. J.; Yano, H.

    2006-01-01

    To improve the near-Earth meteoroid and orbital debris environment definition, a large area particle sensor/collector is being developed to be placed on the International Space Station (ISS). This instrument, the Large Area Debris Collector (LAD-C), will attempt to record meteoroid and orbital debris impact flux, and capture the same particles with aerogel. After at least one year of deployment, the whole system will be brought back for additional laboratory analysis of the captured meteoroids and orbital debris. This project is led by the U.S. Naval Research Laboratory (NRL) while the U.S. Department of Defense (DoD) Space Test Program (STP) is responsible for the integration, deployment, and retrieval of the system. Additional contributing team members of the consortium include the NASA Orbital Debris Program Office, JAXA Institute of Space and Astronautical Science (ISAS), Chiba University (Japan), ESA Space Debris Office, University of Kent (UK), and University of California at Berkeley. The deployment of LAD-C on the ISS is planned for 2008, with the system retrieval in late 2009.

  3. Desulfurization and deashing of Hazro coal by selective oil agglomeration in various water mediums

    SciTech Connect

    Halime Abakay Temel; Fatma Deniz Ayhan

    2006-10-15

    The aim of this study was to study the effects of various water mediums on desulfurization and deashing of Hazro coal by the agglomeration method. For this purpose, three groups of agglomeration experiments were made. The effects of some parameters that markedly influence the effectiveness of selective oil agglomeration, such as solid concentration, bridging liquid concentration, and pH, on the agglomeration were investigated in the first group of experiments. The effects of different salts (NaCl, MgCl{sub 2}, and FeCl{sub 3}) on the agglomeration were investigated in the second group of experiments. The effects of lake water and sea water on the agglomeration were investigated in the third group of experiments. The influences of the Mediterranean Sea water and Aegean Sea water on the removal of ash and total sulfur were found to be important. 22 refs., 7 figs., 6 tabs.

  4. A hypervelocity debris simulating technique with laser driven flyer

    NASA Astrophysics Data System (ADS)

    Tong, J.; Dong, H.; Wang, J.

    Theoretical models suggest that most of the space debris in LEO consist of particles are smaller than 0.5mm. LDEF exposed a total surface area of about 130m 2 for 69 months in the LEO environment. It provided a huge collection of impact data that covers a wide size range of impact crater. Total of 34336 impacts were found on the LDEF surface, of which 27385 impact craters were less than 0.5mm in diameter. The small space debris can cause a gradual degradation of a satellite surfaces, including mechanical damage and contamination generated by impacts. Moreover the small debris may cause greater synergistic effects with AO. AO undercutting of impact damage can further expand the damage areas. This paper describes a new method to simulate small space debris by the laser driven flyer technique. A neodymium-glass pulsed laser was used in this work, capable of up 20 joules in 20 nanoseconds. Tow bonding methods to adhere the aluminum foil to the glass substrate were used. One was a field assisted thermal diffusion bond. The other used silicon oil as the adhesive. In the diffusion bond, the laser is used to vaporize the interface of a aluminum foil diffusively bonded to a glass substrate. The vapor reaches high pressures and then cuts out and accelerates a aluminum disk in the diameter of the periphery of the laser beam. In the second flyer configuration, the silicon oil was vaporized by the laser beam and the expanding gas drove the aluminum disc to the hypervelocity. In our tests, both of methods were successful. In the method of silicon oil adhesion, a 2mm diameter, 60micron thick aluminum disc was accelerated to 3.2km/s. But the velocity data of diffusion bond could not be obtained because the meas uring appliance was improper. The method to measure velocity was very simple and cheap. First, the flight time of a particle was measured with a piezoelectric transducer and a digital oscilloscope. Then attaining the flight time and distance of the particle, its velocity

  5. Size-dependent cytotoxicity of silver nanoparticles in human lung cells: the role of cellular uptake, agglomeration and Ag release

    PubMed Central

    2014-01-01

    Background Silver nanoparticles (AgNPs) are currently one of the most manufactured nanomaterials. A wide range of toxicity studies have been performed on various AgNPs, but these studies report a high variation in toxicity and often lack proper particle characterization. The aim of this study was to investigate size- and coating-dependent toxicity of thoroughly characterized AgNPs following exposure of human lung cells and to explore the mechanisms of toxicity. Methods BEAS-2B cells were exposed to citrate coated AgNPs of different primary particle sizes (10, 40 and 75 nm) as well as to 10 nm PVP coated and 50 nm uncoated AgNPs. The particle agglomeration in cell medium was investigated by photon cross correlation spectroscopy (PCCS); cell viability by LDH and Alamar Blue assay; ROS induction by DCFH-DA assay; genotoxicity by alkaline comet assay and γH2AX foci formation; uptake and intracellular localization by transmission electron microscopy (TEM); and cellular dose as well as Ag release by atomic absorption spectroscopy (AAS). Results The results showed cytotoxicity only of the 10 nm particles independent of surface coating. In contrast, all AgNPs tested caused an increase in overall DNA damage after 24 h assessed by the comet assay, suggesting independent mechanisms for cytotoxicity and DNA damage. However, there was no γH2AX foci formation and no increased production of intracellular reactive oxygen species (ROS). The reasons for the higher toxicity of the 10 nm particles were explored by investigating particle agglomeration in cell medium, cellular uptake, intracellular localization and Ag release. Despite different agglomeration patterns, there was no evident difference in the uptake or intracellular localization of the citrate and PVP coated AgNPs. However, the 10 nm particles released significantly more Ag compared with all other AgNPs (approx. 24 wt% vs. 4–7 wt%) following 24 h in cell medium. The released fraction in cell medium did not induce any

  6. Styrofoam Debris as a Source of Hazardous Additives for Marine Organisms.

    PubMed

    Jang, Mi; Shim, Won Joon; Han, Gi Myung; Rani, Manviri; Song, Young Kyoung; Hong, Sang Hee

    2016-05-17

    There is growing concern over plastic debris and their fragments as a carrier for hazardous substances in marine ecosystem. The present study was conducted to provide field evidence for the transfer of plastic-associated chemicals to marine organisms. Hexabromocyclododecanes (HBCDs), brominated flame retardants, were recently detected in expanded polystyrene (styrofoam) marine debris. We hypothesized that if styrofoam debris acts as a source of the additives in the marine environment, organisms inhabiting such debris might be directly influenced by them. Here we investigated the characteristics of HBCD accumulation by mussels inhabiting styrofoam. For comparison, mussels inhabiting different substrates, such as high-density polyethylene (HDPE), metal, and rock, were also studied. The high HBCD levels up to 5160 ng/g lipid weight and the γ-HBCD dominated isomeric profiles in mussels inhabiting styrofoam strongly supports the transfer of HBCDs from styrofoam substrate to mussels. Furthermore, microsized styrofoam particles were identified inside mussels, probably originating from their substrates. PMID:27100560

  7. Measuring Small Debris - What You Can't See Can Hurt You

    NASA Technical Reports Server (NTRS)

    Matney, Mark

    2016-01-01

    While modeling gives us a tool to better understand the Earth orbit debris environment, it is measurements that give us "ground truth" about what is happening in space. Assets that can detect orbital debris remotely from the surface of the Earth, such as radars and telescopes, give us a statistical view of how debris are distributed in space, how they are being created, and how they are evolving over time. In addition, in situ detectors in space are giving us a better picture of how the small particle environment is actually damaging spacecraft today. IN addition, simulation experiments on the ground help us to understand what we are seeing in orbit. This talk will summarize the history of space debris measurements, how it has changed our view of the Earth orbit environment, and how we are designing the experiments of tomorrow.

  8. Evaluating tsunami hazards from debris flows

    USGS Publications Warehouse

    Watts, P.; Walder, J.S.

    2003-01-01

    Debris flows that enter water bodies may have significant kinetic energy, some of which is transferred to water motion or waves that can impact shorelines and structures. The associated hazards depend on the location of the affected area relative to the point at which the debris flow enters the water. Three distinct regions (splash zone, near field, and far field) may be identified. Experiments demonstrate that characteristics of the near field water wave, which is the only coherent wave to emerge from the splash zone, depend primarily on debris flow volume, debris flow submerged time of motion, and water depth at the point where debris flow motion stops. Near field wave characteristics commonly may be used as & proxy source for computational tsunami propagation. This result is used to assess hazards associated with potential debris flows entering a reservoir in the northwestern USA. ?? 2003 Millpress,.

  9. The impact of debris on marine life.

    PubMed

    Gall, S C; Thompson, R C

    2015-03-15

    Marine debris is listed among the major perceived threats to biodiversity, and is cause for particular concern due to its abundance, durability and persistence in the marine environment. An extensive literature search reviewed the current state of knowledge on the effects of marine debris on marine organisms. 340 original publications reported encounters between organisms and marine debris and 693 species. Plastic debris accounted for 92% of encounters between debris and individuals. Numerous direct and indirect consequences were recorded, with the potential for sublethal effects of ingestion an area of considerable uncertainty and concern. Comparison to the IUCN Red List highlighted that at least 17% of species affected by entanglement and ingestion were listed as threatened or near threatened. Hence where marine debris combines with other anthropogenic stressors it may affect populations, trophic interactions and assemblages. PMID:25680883

  10. Orbital debris: Technical issues and future directions

    NASA Technical Reports Server (NTRS)

    Potter, Andrew (Editor)

    1992-01-01

    An international conference on orbital debris sponsored jointly by the American Institute of Aeronautics and Astronautics, NASA, and the Department of Defense, was held in Baltimore, Maryland, 16-19 Apr. 1990. Thirty-three papers were presented. The papers were grouped into the areas of measurements, modeling, and implications of orbital debris for space flight. New radar and optical measurements of orbital debris were presented that showed the existence of a large population of small debris. Modeling of potential future environments showed that runaway growth of the debris population from random collisions was a real possibility. New techniques for shielding against orbital debris and methods for removal of satellites from orbit were discussed.

  11. Agglomeration of Ag and TiO2 nanoparticles in surface and wastewater: Role of calcium ions and of organic carbon fractions.

    PubMed

    Topuz, Emel; Traber, Jacqueline; Sigg, Laura; Talinli, Ilhan

    2015-09-01

    This study aims to investigate factors leading to agglomeration of citrate coated silver (AgNP-Cit), polyvinylpyrrolidone coated AgNPPVP and titanium dioxide (TiO2) nanoparticles in surface waters and wastewater. ENPs (1 mg/L) were spiked to unfiltered, filtered, ultrafiltered (<10 kDa and <1 kDa) samples. Z-average particle sizes were measured after 1 h, 1 day and 1 week. AgNP-PVP was stable in all fractions of the samples and kept their original size around 60 nm over 1 week. Agglomeration of AgNP-Cit and TiO2 was positively correlated with Ca(2+) concentration, but dissolved organic carbon concentrations > 2 mg/L contributed to stabilizing these NP. Moreover, agglomeration of AgNP-Cit in the various organic matter fractions showed that high molecular weight organic compounds such as biopolymers provide stabilization in natural water. A generalized scheme for the agglomeration behavior of AgNP-Cit, AgNP-PVP and TiO2 in natural waters was proposed based on their relation with Ca(2+), Mg(2+) and DOC concentration. PMID:26057362

  12. Generalized flooded agglomerate model for the cathode catalyst layer of a polymer electrolyte membrane fuel cell

    NASA Astrophysics Data System (ADS)

    Kamarajugadda, Sai; Mazumder, Sandip

    2012-06-01

    The flooded agglomerate model has found prolific usage in modeling the oxygen reduction reaction within the cathode catalyst layer of a polymer electrolyte membrane fuel cell (PEMFC). The assumption made in this model is that the ionomer-coated carbon-platinum agglomerate is spherical in shape and that the spheres are non-overlapping. This assumption is convenient because the governing equations lend themselves to closed-form analytical solution when a spherical shape is assumed. In reality, micrographs of the catalyst layer show that the agglomerates are best represented by sets of overlapping spheres of unequal radii. In this article, the flooded agglomerate is generalized by considering overlapping spheres of unequal radii. As a first cut, only two overlapping spheres are considered. The governing reaction-diffusion equations are solved numerically using the unstructured finite-volume method. The volumetric current density is extracted for various parametric variations, and tabulated. This sub-grid-scale generalized flooded agglomerate model is first validated and finally coupled to a computational fluid dynamics (CFD) code for predicting the performance of the PEMFC. Results show that when the agglomerates are small (<200 nm equivalent radius), the effect of agglomerate shape on the overall PEMFC performance is insignificant. For large agglomerates, on the other hand, the effect of agglomerate shape was found to be critical, especially for high current densities for which the mass transport resistance within the agglomerate is strongly dependent on the shape of the agglomerate, and was found to correlate well with the surface-to-volume ratio of the agglomerate.

  13. Debris Removal: An Opportunity for Cooperative Research?

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2007-01-01

    Space debris mitigation practices will be insufficient to prevent the continued growth of the Earth satellite population. Removal of orbital debris can improve the reliability of present and future space systems. The challenges of developing an effective, affordable debris removal capability are considerable. The time is right for a new look at space remediation concepts. In concert with or following the current IAA study An international approach to the remediation of the near-Earth space environment will likely be required.

  14. Agglomeration of Luminescent Porous Silicon Nanoparticles in Colloidal Solutions.

    PubMed

    Herynková, Kateřina; Šlechta, Miroslav; Šimáková, Petra; Fučíková, Anna; Cibulka, Ondřej

    2016-12-01

    We have prepared colloidal solutions of clusters composed from porous silicon nanoparticles in methanol, water and phosphate-buffered saline (PBS). Even if the size of the nanoclusters is between 60 and 500 nm, due to their highly porous "cauliflower"-like structure, the porous silicon nanoparticles are composed of interconnected nanocrystals having around 2.5 nm in size and showing strong visible luminescence in the orange-red spectral region (centred at 600-700 nm). Hydrophilic behaviour and good solubility of the nanoclusters in water and water-based solutions were obtained by adding hydrogen peroxide into the etching solution during preparation and 16 min long after-bath in hydrogen peroxide. By simple filtration of the solutions with syringe filters, we have extracted smaller nanoclusters with sizes of approx. 60-70 nm; however, these nanoclusters in water and PBS solution (pH neutral) are prone to agglomeration, as was confirmed by zeta potential measurements. When the samples were left at ambient conditions for several weeks, the typical nanocluster size increased to approx. 330-400 nm and then remained stable. However, both freshly filtered and aged samples (with agglomerated porous silicon nanoparticles) of porous silicon in water and PBS solutions can be further used for biological studies or as luminescent markers in living cells. PMID:27541815

  15. Combination Chemotherapeutic Dry Powder Aerosols via Controlled Nanoparticle Agglomeration

    PubMed Central

    El-Gendy, Nashwa; Berkland, Cory

    2014-01-01

    Purpose To develop an aerosol system for efficient local lung delivery of chemotherapeutics where nanotechnology holds tremendous potential for developing more valuable cancer therapies. Concurrently, aerosolized chemotherapy is generating interest as a means to treat certain types of lung cancer more effectively with less systemic exposure to the compound. Methods Nanoparticles of the potent anticancer drug, paclitaxel, were controllably assembled to form low density microparticles directly after preparation of the nanoparticle suspension. The amino acid, L-leucine, was used as a colloid destabilizer to drive the assembly of paclitaxel nanoparticles. A combination chemotherapy aerosol was formed by assembling the paclitaxel nanoparticles in the presence of cisplatin in solution. Results Freeze-dried powders of the combination chemotherapy possessed desirable aerodynamic properties for inhalation. In addition, the dissolution rates of dried nanoparticle agglomerate formulations (~60% to 66% after 8 h) were significantly faster than that of micronized paclitaxel powder as received (~18% after 8 h). Interestingly, the presence of the water soluble cisplatin accelerated the dissolution of paclitaxel. Conclusions Nanoparticle agglomerates of paclitaxel alone or in combination with cisplatin may serve as effective chemotherapeutic dry powder aerosols to enable regional treatment of certain lung cancers. PMID:19415471

  16. Pathways of marine debris in statistical and diagnostic ocean circulation models

    NASA Astrophysics Data System (ADS)

    Maximenko, N.; Hafner, J.; Lumpkin, R.

    2012-04-01

    Statistical and diagnostic models are used in this study to describe long-term dynamics of objects floating at the sea surface. The statistical model is based of the particle displacement probability density function, derived from trajectories of drifting buoys, and is supplemented by the probability of running aground. This model reveals five main areas of debris accumulation in the subtropical ocean, all confirmed with direct observations. It also reveals the global pattern of shores impacted by marine debris, correlated with dominant winds. The diagnostic model (SCUD - Surface CUrrents from Diagnostic) utilizes satellite data of altimetry and QuikSCAT/ASCAT winds to assess near-real time surface velocities and its parameters are optimized using drifter trajectories. Numerical experiments with various sources and life times of the model debris help to understand main pathways of the tracer and distributions of its properties within and across individual oceans. Applications of statistical and diagnostic models help to assess probable motion of the debris, generated in Japan by tsunami of March 11, 2011. The timeline, derived from the statistical model, and maps, computed with SCUD, are used to coordinate operational at-sea and on-coast observations and preparations for the debris impact. Most of debris is drifting from Japan towards east, while dispersing over increasing area. After passing Hawaii in the north it is expected to recirculate into the so-called North Pacific Garbage Patch - the area, located between Hawaii and California, where convergent surface currents collect all floating waste. Only a small fraction of tsunami debris, on the edge of the debris field, will "touch" Hawaii and US/Canada west coast. Yet the amount and composition may be anomalous. Mixed with the older waste, tsunami debris will slowly leak from the patch, polluting Hawaiian Islands.

  17. Effects of tributary debris on the longitudinal profile of the Colorado River in Grand Canyon

    USGS Publications Warehouse

    Hanks, T.C.; Webb, R.H.

    2006-01-01

    The Colorado River in Grand Canyon has long been known as a "rapids-and-pools" river, with the rapids owing their existence primarily to tributary debris flows. The debris flows deposit subaerial debris fans that constrict the channel laterally and, when they enter the river, raise the bed elevation. The rapids are short-wavelength (???0.1 to ???1 km), small-amplitude (??????5 m) convexities in the river's longitudinal profile, arising from the shallow gradient in the upstream pool and the steep gradient through the rapid itself. Analysis of the entire longitudinal profile through Grand Canyon reveals two long-wavelength (???100 km), large-amplitude (15-30 m) river profile convexities: the eastern canyon convexity between river mile (RM) 30 and RM 80 and the western canyon convexity between RM 150 and RM 250. Convexities of intermediate scale are also identified in the longitudinal profile. These longer-wavelength, larger-amplitude convexities have strong spatial correlations with high rates of debris flow occurrence, high densities of Holocene debris fans, the largest debris fans along the river, and alluvial thicknesses of 10 m or more. River profile convexities are unstable and require an active and powerful geologic process to maintain them, in this case the abundant, frequent, and voluminous Holocene debris flow activity in Grand Canyon. At all wavelengths the most likely cause for these river profile convexities is Holocene aggradation of the riverbed beneath them, driven by the coarse particles of tributary debris flows. Large enough debris flows will slow river flow for kilometers upstream, causing it to drop much of its suspended load. Integrated over time and all of the tributary point source contributions, this process will build short-wavelength convexities into long-wavelength convexities. For most if not all of the Holocene the Colorado River has been dissipating most of its energy in the rapids and expending the remainder in transporting fine

  18. Variations in debris distribution and thickness on Himalayan debris-covered glaciers

    NASA Astrophysics Data System (ADS)

    Gibson, Morgan; Rowan, Ann; Irvine-Fynn, Tristram; Quincey, Duncan; Glasser, Neil

    2016-04-01

    Many Himalayan glaciers are characterised by extensive supraglacial debris coverage; in Nepal 33% of glaciers exhibit a continuous layer of debris covering their ablation areas. The presence of such a debris layer modulates a glacier's response to climatic change. However, the impact of this modulation is poorly constrained due to inadequate quantification of the impact of supraglacial debris on glacier surface energy balance. Few data exist to describe spatial and temporal variations in parameters such as debris thickness, albedo and surface roughness in energy balance calculations. Consequently, improved understanding of how debris affects Himalayan glacier ablation requires the assessment of surface energy balance model sensitivity to spatial and temporal variability in these parameters. Measurements of debris thickness, surface temperature, reflectance and roughness were collected across Khumbu Glacier during the pre- and post-monsoon seasons of 2014 and 2015. The extent of the spatial variation in each of these parameters are currently being incorporated into a point-based glacier surface energy balance model (CMB-RES, Collier et al., 2014, The Cryosphere), applied on a pixel-by-pixel basis to the glacier surface, to ascertain the sensitivity of glacier surface energy balance and ablation values to these debris parameters. A time series of debris thickness maps have been produced for Khumbu Glacier over a 15-year period (2000-2015) using Mihalcea et al.'s (2008, Cold Reg. Sci. Technol.) method, which utilised multi-temporal ASTER thermal imagery and our in situ debris surface temperature and thickness measurements. Change detection between these maps allowed the identification of variations in debris thickness that could be compared to discrete measurements, glacier surface velocity and morphology of the debris-covered area. Debris thickness was found to vary spatially between 0.1 and 4 metres within each debris thickness map, and temporally on the order of 1

  19. MODELING COLLISIONAL CASCADES IN DEBRIS DISKS: THE NUMERICAL METHOD

    SciTech Connect

    Gaspar, Andras; Psaltis, Dimitrios; Oezel, Feryal; Rieke, George H.; Cooney, Alan E-mail: dpsaltis@as.arizona.edu E-mail: grieke@as.arizona.edu

    2012-04-10

    We develop a new numerical algorithm to model collisional cascades in debris disks. Because of the large dynamical range in particle masses, we solve the integro-differential equations describing erosive and catastrophic collisions in a particle-in-a-box approach, while treating the orbital dynamics of the particles in an approximate fashion. We employ a new scheme for describing erosive (cratering) collisions that yields a continuous set of outcomes as a function of colliding masses. We demonstrate the stability and convergence characteristics of our algorithm and compare it with other treatments. We show that incorporating the effects of erosive collisions results in a decay of the particle distribution that is significantly faster than with purely catastrophic collisions.

  20. Best Mitigation Paths To Effectively Reduce Earth's Orbital Debris

    NASA Technical Reports Server (NTRS)

    Wiegman, Bruce M.

    2009-01-01

    This slide presentation reviews some ways to reduce the problem posed by debris in orbit around the Earth. It reviews the orbital debris environment, the near-term needs to minimize the Kessler syndrome, also known as collisional cascading, a survey of active orbital debris mitigation strategies, the best paths to actively remove orbital debris, and technologies that are required for active debris mitigation.