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Sample records for agglomerated debris particles

  1. Backscattering of agglomerate particles

    NASA Astrophysics Data System (ADS)

    Zubko, Evgenij; Ovcharenko, Andrey; Bondarenko, Sergey; Shkuratov, Yuriy; Scotto, Cathy S.; Merritt, Charles; Hart, Matthew B.; Eversole, Jay D.; Videen, Gorden W.

    2004-12-01

    We examine how aggregation affects the light-scattering signatures, especially the polarization in the near-backward-scattering direction. We use the discrete dipole approximation (DDA) to study the backscatter of agglomerate particles consisting of oblong monomers. We examine the effects of monomer number and packing structure on the resulting negative polarization branch at small phase angle. We find large a dependence on the orientation of the monomers within the agglomerate and a smaller dependence on the number of monomers, suggesting that the mechanism producing the negative polarization minimum depends strongly on the interactions between the individual monomers. We also examine experimental measurements of substrates composed of biological cells. We find that the light-scattering signatures in the backward direction are not only different for different spore species, but for spores that have been prepared using different methodologies. These signatures are reproducible in different substrates composed of the spores from the same batches.

  2. Particle Agglomeration in Bipolar Barb Agglomerator Under AC Electric Field

    NASA Astrophysics Data System (ADS)

    Huang, Chao; Ma, Xiuqin; Sun, Youshan; Wang, Meiyan; Zhang, Changping; Lou, Yueya

    2015-04-01

    The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious. To improve agglomeration effectiveness of fine particles, a dual zone electric agglomeration device consisting of a charging chamber and an agglomeration chamber with bipolar barb electrodes was developed. The bipolar barb electric agglomerator with a polar distance of 200 mm demonstrates good agglomeration effectiveness for particles with a size less than 8.0 μm under applied AC electric field. An optimal condition for achieving better agglomeration effectiveness was found to be as follows: flue gas flow velocity of 3.00 m/s, particle concentration of 2.00 g/m3, output voltage of 35 kV and length of the barb of 16 mm. In addition, 4.0-6.0 μm particles have the best effectiveness with the variation of particle volume occupancy of -3.2. supported by the Key Technology R&D Program of Hebei, China (No. 13211207D)

  3. Modeling of particle agglomeration in nanofluids

    NASA Astrophysics Data System (ADS)

    Krishna, K. Hari; Neti, S.; Oztekin, A.; Mohapatra, S.

    2015-03-01

    Agglomeration strongly influences the stability or shelf life of nanofluid. The present computational and experimental study investigates the rate of agglomeration quantitatively. Agglomeration in nanofluids is attributed to the net effect of various inter-particle interaction forces. For the nanofluid considered here, a net inter-particle force depends on the particle size, volume fraction, pH, and electrolyte concentration. A solution of the discretized and coupled population balance equations can yield particle sizes as a function of time. Nanofluid prepared here consists of alumina nanoparticles with the average particle size of 150 nm dispersed in de-ionized water. As the pH of the colloid was moved towards the isoelectric point of alumina nanofluids, the rate of increase of average particle size increased with time due to lower net positive charge on particles. The rate at which the average particle size is increased is predicted and measured for different electrolyte concentration and volume fraction. The higher rate of agglomeration is attributed to the decrease in the electrostatic double layer repulsion forces. The rate of agglomeration decreases due to increase in the size of nano-particle clusters thus approaching zero rate of agglomeration when all the clusters are nearly uniform in size. Predicted rates of agglomeration agree adequate enough with the measured values; validating the mathematical model and numerical approach is employed.

  4. Modeling of particle agglomeration in nanofluids

    SciTech Connect

    Krishna, K. Hari; Neti, S.; Oztekin, A.; Mohapatra, S.

    2015-03-07

    Agglomeration strongly influences the stability or shelf life of nanofluid. The present computational and experimental study investigates the rate of agglomeration quantitatively. Agglomeration in nanofluids is attributed to the net effect of various inter-particle interaction forces. For the nanofluid considered here, a net inter-particle force depends on the particle size, volume fraction, pH, and electrolyte concentration. A solution of the discretized and coupled population balance equations can yield particle sizes as a function of time. Nanofluid prepared here consists of alumina nanoparticles with the average particle size of 150 nm dispersed in de-ionized water. As the pH of the colloid was moved towards the isoelectric point of alumina nanofluids, the rate of increase of average particle size increased with time due to lower net positive charge on particles. The rate at which the average particle size is increased is predicted and measured for different electrolyte concentration and volume fraction. The higher rate of agglomeration is attributed to the decrease in the electrostatic double layer repulsion forces. The rate of agglomeration decreases due to increase in the size of nano-particle clusters thus approaching zero rate of agglomeration when all the clusters are nearly uniform in size. Predicted rates of agglomeration agree adequate enough with the measured values; validating the mathematical model and numerical approach is employed.

  5. Method for producing ceramic particles and agglomerates

    DOEpatents

    Phillips, Jonathan; Gleiman, Seth S.; Chen, Chun-Ku

    2001-01-01

    A method for generating spherical and irregularly shaped dense particles of ceramic oxides having a controlled particle size and particle size distribution. An aerosol containing precursor particles of oxide ceramics is directed into a plasma. As the particles flow through the hot zone of the plasma, they melt, collide, and join to form larger particles. If these larger particles remain in the hot zone, they continue melting and acquire a spherical shape that is retained after they exit the hot zone, cool down, and solidify. If they exit the hot zone before melting completely, their irregular shape persists and agglomerates are produced. The size and size distribution of the dense product particles can be controlled by adjusting several parameters, the most important in the case of powder precursors appears to be the density of powder in the aerosol stream that enters the plasma hot zone. This suggests that particle collision rate is responsible for determining ultimate size of the resulting sphere or agglomerate. Other parameters, particularly the gas flow rates and the microwave power, are also adjusted to control the particle size distribution.

  6. Agglomeration rate and action forces between atomized particles of agglomerator and inhaled-particles from coal combustion.

    PubMed

    Wei, Feng; Zhang, Jun-ying; Zheng, Chu-guang

    2005-01-01

    In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the flue before precipitation devices of power station boiler in order to make inhaled-particles agglomerate into bigger particles, which can be easily removed but not change existing running conditions of boiler. According to this idea, a model is set up to study agglomeration rate and effect forces between fly ash inhaled-particles and atomized agglomerator particles. The developed agglomeration rate was expressed by relative particle number decreasing speed per unit volume. The result showed that viscosity force and flow resistance force give main influences on agglomeration effect of inhaled-particles, while springiness force and gravity have little effect on agglomeration effect of theirs. Factors influencing the agglomeration rate and effect forces are studied, including agglomerator concentration, agglomerator flux and agglomerator density, atomized-particles diameters and inhaled-particles diameter and so on.

  7. Reducing adhesion and agglomeration within a cloud of combustible particles

    NASA Technical Reports Server (NTRS)

    Ross, Howard D.

    1988-01-01

    The study of combustible particle clouds inside flame tubes is of fundamental scientific interest as well as a practical concern. Only the suspended concentration is important to the combustion process, so that assurances must be provided that a minimum of particles adheres to the tube wall. This paper demonstrates experimentally the ability to minimize adhesion and agglomeration of acoustically-mixed lycopodium particles within a 5-cm diameter lexan flame tube. The area density of particles (ADP) adhering to the wall of bare lexan tubes was measured at greater than 100 particles/sq mm. The nature of adhesion was found to be clearly electrostatic, with the ADP level aggravated by increased mixing time, vigor, and the concentration of particles. Increases in the conductivity of the air and the tube wall did not affect ADP levels substantially. However, the observed adhesion was reduced to less than 10 p/sq mm when the air was ionized by use of an alpha emitter mounted on the inner walls of the flame tube.

  8. A MODEL FOR FINE PARTICLE AGGLOMERATION IN CIRCULATING FLUIDIZED BED ABSORBERS

    EPA Science Inventory

    A model for fine particle agglomeration in circulating fluidized bed absorbers (CFBAS) has been developed. It can model the influence of different factors on agglomeration, such as the geometry of CFBAs, superficial gas velocity, initial particle size distribution, and type of ag...

  9. Dynamic forces on agglomerated particles caused by high-intensity ultrasound.

    PubMed

    Knoop, Claas; Fritsching, Udo

    2014-03-01

    In this paper the acoustic forces on particles and agglomerates caused by high-intensity ultrasound in gaseous atmosphere are derived by means of computational fluid dynamics (CFD). Sound induced forces cause an oscillating stress scenario where the primary particles of an agglomerate are alternatingly pressed together and torn apart with the frequency of the applied wave. A comparison of the calculated acoustic forces with respect to the inter particle adhesion forces from Van-der-Waals and liquid bridge interactions reveals that the separation forces may reach the same order of magnitude for 80 μm sized SiO2-particles. Hence, with finite probability acoustically agitated gases may de-agglomerate/disperse solid agglomerate structures. This effect is confirmed by dispersion experiments in an acoustic particle levitation setup.

  10. Impact debris particles in Jupiter's stratosphere.

    PubMed

    West, R A; Karkoschka, E; Friedson, A J; Seymour, M; Baines, K H; Hammel, H B

    1995-03-03

    The aftermath of the impacts of periodic comet Shoemaker-Levy 9 on Jupiter was studied with the Wide Field Planetary Camera 2 on the Hubble Space Telescope. The impact debris particles may owe their dark brown color to organic material rich in sulfur and nitrogen. The total volume of aerosol 1 day after the last impact is equal to the volume of a sphere of radius 0.5 kilometer. In the optically thick core regions, the particle mean radius is between 0.15 and 0.3 micrometer, and the aerosol is spread over many scale heights, from approximately 1 millibar to 200 millibars of pressure or more. Particle coagulation can account for the evolution of particle radius and total optical depth during the month following the impacts.

  11. Influence of the pan pelletizer rotational velocity and the particles size on the agglomeration of alumina oxide granules

    NASA Astrophysics Data System (ADS)

    Radeva, Zheni; Müller, Peter; Tomas, Juergen

    2013-06-01

    High fraction of agglomerates and better agglomerate strength are main purpose for every agglomeration process. For optimizing the agglomeration process of industrial produced granules, using liquid binders, it is necessary to understand the microinteractions between primary particles and binder and the marcointeractions between the agglomerates themselves. In order to investigate the influence of the rotational velocity of the pan pelletizer and the primary particle size on the fraction of agglomerates and the mechanical properties of the produced agglomerates, the obtained structures have to be basically analyzed. Agglomeration of industrial produced Alumina Oxide (γ-Al2O3) granules is carried out in a rotating pan pelletizer. A 6 mass-% solution of viscoelastic polymer - hydroxypropyl methylcellulose (HPMC) is used as binder. The rotational velocity of the pelletizer pan is previously measured and calibrated. By changing the rotational velocity of the process chamber it was found that there are critical speed limits for the pan. The minimum critical velocity of the pelletizer plate does not provide enough contact collisions between the particles and the necessary kinetic level for agglomeration cannot be reached. The maximum critical velocity leads to higher rotational kinetic energy and this causes breakages of the agglomerates. It was also proven that the breakage strength of the agglomerates decreases with the reduction of the agglomerate size. The conclusions from the experimental work help us to understand the basics of agglomeration process and tend to develop and facilitate the operating with particle collectives in science and industry.

  12. Direct numerical simulations of agglomeration of circular colloidal particles in two-dimensional shear flow

    SciTech Connect

    Choi, Young Joon Djilali, Ned

    2016-01-15

    Colloidal agglomeration of nanoparticles in shear flow is investigated by solving the fluid-particle and particle-particle interactions in a 2D system. We use an extended finite element method in which the dynamics of the particles is solved in a fully coupled manner with the flow, allowing an accurate description of the fluid-particle interfaces without the need of boundary-fitted meshes or of empirical correlations to account for the hydrodynamic interactions between the particles. Adaptive local mesh refinement using a grid deformation method is incorporated with the fluid-structure interaction algorithm, and the particle-particle interaction at the microscopic level is modeled using the Lennard-Jones potential. Motivated by the process used in fabricating fuel cell catalysts from a colloidal ink, the model is applied to investigate agglomeration of colloidal particles under external shear flow in a sliding bi-periodic Lees-Edwards frame with varying shear rates and particle fraction ratios. Both external shear and particle fraction are found to have a crucial impact on the structure formation of colloidal particles in a suspension. Segregation intensity and graph theory are used to analyze the underlying agglomeration patterns and structures, and three agglomeration regimes are identified.

  13. Hydrodynamic chromatography coupled with single particle-inductively coupled plasma mass spectrometry for investigating nanoparticles agglomerates.

    PubMed

    Rakcheev, Denis; Philippe, Allan; Schaumann, Gabriele E

    2013-11-19

    Studying the environmental fate of engineered or natural colloids requires efficient methods for measuring their size and quantifying them in the environment. For example, an ideal method should maintain its correctness, accuracy, reproducibility, and robustness when applied to samples contained in complex matrixes and distinguish the target particles from the natural colloidal background signals. Since it is expected that a large portion of nanoparticles will form homo- or heteroagglomerates when released into environmental media, it is necessary to differentiate agglomerates from primary particles. At present, most sizing techniques do not fulfill these requirements. In this study, we used online coupling of two promising complementary sizing techniques: hydrodynamic chromatography (HDC) and single-particle ICPMS analysis to analyze gold nanoparticles agglomerated under controlled conditions. We used the single-particle mode of the ICPMS detector to detect single particles eluted from an HDC-column and determine a mass and an effective diameter for each particle using a double calibration approach. The average agglomerate relative density and fractal dimension were calculated using these data and used to follow the morphological evolution of agglomerates over time during the agglomeration process. The results demonstrate the ability of HDC coupled to single-particle analysis to identify and characterize nanoparticle homoagglomerates and is a very promising technique for the analysis of colloids in complex media.

  14. Method of producing non-agglomerating submicron size particles

    DOEpatents

    Bourne, Roy S.; Eichman, Clarence C.; Welbon, William W.

    1989-01-01

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in "metallic inks".

  15. Preparation of submicron-sized gold particles using laser-induced agglomeration-fusion process

    NASA Astrophysics Data System (ADS)

    Tsuji, T.; Higashi, Y.; Tsuji, M.; Ishikawa, Y.; Koshizaki, N.

    2014-03-01

    Recently, laser irradiation (LI) of colloidal nanoparticles (NPs) using a non-focused laser beam at moderate fluence attracts much attention as a novel and simple technique to obtain submicron-sized spherical particles. In the present study, we applied this technique to prepare gold SMPs. It was revealed that agglomeration of the source nanoparticles prior to laser irradiation is necessary to produce SMPs. However, when the agglomeration occurred in too much extent, significant amount of the source particles remained as the sediment after LI, leading to the lowering of the formation efficiency of SMPs. Therefore, the control of the agglomeration conditions of the source NPs is necessary to obtain SMPs efficiently. In the present study, we tried to adjust the agglomeration conditions of the source NPs by adjusting the concentration of citrate that was used as the stabilizing reagent of the source NPs. It was revealed that SMPs were obtained efficiently while the sedimentation of the source NPs were suppressed when the concentration of citrate was adjusted around 0.01-0.005 mM. In addition, observation of the temporal change in the shape of the colloidal particles during LI revealed that there is an induction period in which no formation of SMPs is brought about by LI. This finding suggested that LI removes the citrate ligands from the source NPs and induces the agglomeration of the source NPs, i.e. the agglomeration condition of the source NPs is also controlled by LI.

  16. Combined deterministic-stochastic framework for modeling the agglomeration of colloidal particles

    NASA Astrophysics Data System (ADS)

    Mortuza, S. M.; Kariyawasam, Lahiru K.; Banerjee, Soumik

    2015-07-01

    We present a multiscale model, based on molecular dynamics (MD) and kinetic Monte Carlo (kMC), to study the aggregation driven growth of colloidal particles. Coarse-grained molecular dynamics (CGMD) simulations are employed to detect key agglomeration events and calculate the corresponding rate constants. The kMC simulations employ these rate constants in a stochastic framework to track the growth of the agglomerates over longer time scales and length scales. One of the hallmarks of the model is a unique methodology to detect and characterize agglomeration events. The model accounts for individual cluster-scale effects such as change in size due to aggregation as well as local molecular-scale effects such as changes in the number of neighbors of each molecule in a colloidal cluster. Such definition of agglomeration events allows us to grow the cluster to sizes that are inaccessible to molecular simulations as well as track the shape of the growing cluster. A well-studied system, comprising fullerenes in NaCl electrolyte solution, was simulated to validate the model. Under the simulated conditions, the agglomeration process evolves from a diffusion limited cluster aggregation (DLCA) regime to percolating cluster in transition and finally to a gelation regime. Overall the data from the multiscale numerical model shows good agreement with existing theory of colloidal particle growth. Although in the present study we validated our model by specifically simulating fullerene agglomeration in electrolyte solution, the model is versatile and can be applied to a wide range of colloidal systems.

  17. Thermal conductivity and particle agglomeration in alumina nanofluids: Experiment and theory

    NASA Astrophysics Data System (ADS)

    Timofeeva, Elena V.; Gavrilov, Alexei N.; McCloskey, James M.; Tolmachev, Yuriy V.; Sprunt, Samuel; Lopatina, Lena M.; Selinger, Jonathan V.

    2007-12-01

    In recent years many experimentalists have reported an anomalously enhanced thermal conductivity in liquid suspensions of nanoparticles. Despite the importance of this effect for heat transfer applications, no agreement has emerged about the mechanism of this phenomenon, or even about the experimentally observed magnitude of the enhancement. To address these issues, this paper presents a combined experimental and theoretical study of heat conduction and particle agglomeration in nanofluids. On the experimental side, nanofluids of alumina particles in water and ethylene glycol are characterized using thermal conductivity measurements, viscosity measurements, dynamic light scattering, and other techniques. The results show that the particles are agglomerated, with an agglomeration state that evolves in time. The data also show that the thermal conductivity enhancement is within the range predicted by effective medium theory. On the theoretical side, a model is developed for heat conduction through a fluid containing nanoparticles and agglomerates of various geometries. The calculations show that elongated and dendritic structures are more efficient in enhancing the thermal conductivity than compact spherical structures of the same volume fraction, and that surface (Kapitza) resistance is the major factor resulting in the lower than effective medium conductivities measured in our experiments. Together, these results imply that the geometry, agglomeration state, and surface resistance of nanoparticles are the main variables controlling thermal conductivity enhancement in nanofluids.

  18. Secondary impact generated particles: implications for the orbital debris population

    NASA Astrophysics Data System (ADS)

    Mandeville, J. C.; Rival, M.; Alby, F.

    1999-01-01

    Every time a debris or a meteoroid hits a part of a satellite in orbit, a great amount of secondary particles is ejected in the neighborhood of the impact site. This phenomenon is important for brittle materials, such as used for solar generators. The secondary particles that do not impact other parts of the spacecraft are added to the primary debris population and increase the small debris flux. We present an ejecta production model that gives the size and the velocity distribution of ejected particles as a function of primary impact parameters. We derive the parameters of all ejecta created during one orbital revolution of a satellite. An orbital evolution program is used to extrapolate the secondary debris position at later times. Preliminary results show that spall fragments ejected at low velocities remain in the vicinity of the parent satellite. The ejecta trajectories are similar and their inclination is very close to those of the parent satellite. Their orbital evolution depends mainly on the size of the debris and on the altitude of the parent body: the smallest particles in low earth orbit quickly reenter the earth atmosphere, while the largest spalls have a very slow decay. The antagonistic action of debris production and debris decay by drag leads to an equilibrium for particles within a given size range. Quantitative results on densities and fluxes compared to the primary debris population are presented for the peculiar case of heliosynchronous orbits.

  19. Combustion of single and agglomerated aluminum particles in solid rocket motor flows

    NASA Astrophysics Data System (ADS)

    Melcher, John Charles, IV

    2001-07-01

    Single and agglomerated aluminum droplets were studied in a solid rocket motor (SRM) test chamber with optical access to the internal flow at 6--22 atm and 2300 K. The chamber was pressurized by burning a main grain AP/HTPB propellant, and the burning aluminum droplets were generated by a smaller aluminized solid propellant sample, center-mounted in the flow. A 35 mm camera was used with a chopper wheel to give droplet flame diameter vs. time measurements of the burning droplets in flight, from which bum-rate laws were developed. A high-speed video CCD was used with high-magnification optics in order to image the flame/smoke cloud surrounding the burning liquid droplets. The intensity profiles of the droplet images were de-convoluted using an Abel inversion to give true intensity profiles. Both single and agglomerated droplets were studied, where agglomerates are comprised of hundreds of parent particles or more. The Abel inversion results show that the relative smoke cloud size is not constant with diameter, but instead grows as the droplet shrinks, by ˜D -0.5, for both the single and agglomerated droplets. Measured diameter trajectories show that for single droplets, the diameter law is D 0.75 = DO0.75 = 8·t [mu m, msec], and for agglomerated droplets, D 1.0 = Do1.0 - 20·t, such that the single droplets burn faster than the agglomerates. For both single and agglomerated droplets, the burning rate slope k did not change significantly over the chamber pressure studied. Lastly, a model was developed to describe the oxide cap accumulation on the droplet surface from the oxide smoke cloud surrounding the droplet. Results suggest that less oxide accumulates in high-pressure SRMs when considering mass burning rates for different relative cap sizes. The thermophoretic force, which can control oxide transport only over the cap, decreases with pressure.

  20. An accelerated stochastic vortex structure method for particle collision and agglomeration in homogeneous turbulence

    NASA Astrophysics Data System (ADS)

    Dizaji, Farzad F.; Marshall, Jeffrey S.

    2016-11-01

    Modeling the response of interacting particles, droplets, or bubbles to subgrid-scale fluctuations in turbulent flows is a long-standing challenge in multiphase flow simulations using the Reynolds-Averaged Navier-Stokes approach. The problem also arises for large-eddy simulation for sufficiently small values of the Kolmogorov-scale particle Stokes number. This paper expands on a recently proposed stochastic vortex structure (SVS) method for modeling of turbulence fluctuations for colliding or otherwise interacting particles. An accelerated version of the SVS method was developed using the fast multipole expansion and local Taylor expansion approach, which reduces computation speed by two orders of magnitude compared to the original SVS method. Detailed comparisons are presented showing close agreement of the energy spectrum and probability density functions of various fields between the SVS computational model, direct numerical simulation (DNS) results, and various theoretical and experimental results found in the literature. Results of the SVS method for particle collision rate and related measures of particle interaction exhibit excellent agreement with DNS predictions for homogeneous turbulent flows. The SVS method was also used with adhesive particles to simulate formation of particle agglomerates with different values of the particle Stokes and adhesion numbers, and various measures of the agglomerate structure are compared to the DNS results.

  1. Agglomerates, smoke oxide particles, and carbon inclusions in condensed combustion products of an aluminized GAP-based propellant

    NASA Astrophysics Data System (ADS)

    Ao, Wen; Liu, Peijin; Yang, Wenjing

    2016-12-01

    In solid propellants, aluminum is widely used to improve the performance, however the condensed combustion products especially the large agglomerates generated from aluminum combustion significantly affect the combustion and internal flow inside the solid rocket motor. To clarify the properties of the condensed combustion products of aluminized propellants, a constant-pressure quench vessel was adopted to collect the combustion products. The morphology and chemical compositions of the collected products, were then studied by using scanning electron microscopy coupled with energy dispersive (SEM-EDS) method. Various structures have been observed in the condensed combustion products. Apart from the typical agglomerates or smoke oxide particles observed before, new structures including the smoke oxide clusters, irregular agglomerates and carbon-inclusions are discovered and investigated. Smoke oxide particles have the highest amount in the products. The highly dispersed oxide particle is spherical with very smooth surface and is on the order of 1-2 μm, but due to the high temperature and long residence time, these small particles will aggregate into smoke oxide clusters which are much larger than the initial particles. Three types of spherical agglomerates have been found. As the ambient gas temperature is much higher than the boiling point of Al2O3, the condensation layer inside which the aluminum drop is burning would evaporate quickly, which result in the fact that few "hollow agglomerates" has been found compared to "cap agglomerates" and "solid agglomerates". Irregular agglomerates usually larger than spherical agglomerates. The formation of irregular agglomerates likely happens by three stages: deformation of spherical aluminum drops; combination of particles with various shape; finally production of irregular agglomerates. EDS results show the ratio of O to Al on the surface of agglomerates is lower in comparison to smoke oxide particles. C and O account for

  2. Nanostructured natural-based polyelectrolyte multilayers to agglomerate chitosan particles into scaffolds for tissue engineering.

    PubMed

    Miranda, Emanuel Sá; Silva, Tiago H; Reis, Rui L; Mano, João F

    2011-11-01

    The layer-by-layer (LbL) deposition technique is a self-assembly process that allows the coating of material's surface with nanostructured layers of polyelectrolytes, allowing to control several surface properties. This technique presents some advantages when compared with other thin film assembly techniques, like having the possibility to coat surfaces with complex geometries in mild conditions or to incorporate active compounds. Tissue engineering (TE) involves typically the use of porous biodegradable scaffolds for the temporary support of cells. Such structures can be produced by agglomeration of microspheres that needs to be fixed into a three-dimensional (3D) structure. In this work we suggest the use of LbL to promote such mechanical fixation in free-formed microspheres assemblies and simultaneously to control the properties of its surface. For the proof of concept the biological performance of chitosan/alginate multilayers is first investigated in two-dimensional (2D) models in which the attachment and proliferation of L929 and ATDC5 cells are studied in function of the number of layers and the nature of the final layer. Scaffolds prepared by agglomeration of chitosan particles using the same multilayered system were processed and characterized; it was found that they could support the attachment and proliferation of ATDC5 cells. This study suggests that LbL can be used as a versatile methodology to prepare scaffolds by particle agglomeration that could be suitable for TE applications.

  3. Design of sustained release fine particles using two-step mechanical powder processing: particle shape modification of drug crystals and dry particle coating with polymer nanoparticle agglomerate.

    PubMed

    Kondo, Keita; Ito, Natsuki; Niwa, Toshiyuki; Danjo, Kazumi

    2013-09-10

    We attempted to prepare sustained release fine particles using a two-step mechanical powder processing method; particle-shape modification and dry particle coating. First, particle shape of bulk drug was modified by mechanical treatment to yield drug crystals suitable for the coating process. Drug crystals became more rounded with increasing rotation speed, which demonstrates that powerful mechanical stress yields spherical drug crystals with narrow size distribution. This process is the result of destruction, granulation and refinement of drug crystals. Second, the modified drug particles and polymer coating powder were mechanically treated to prepare composite particles. Polymer nanoparticle agglomerate obtained by drying poly(meth)acrylate aqueous dispersion was used as a coating powder. The porous nanoparticle agglomerate has superior coating performance, because it is completely deagglomerated under mechanical stress to form fine fragments that act as guest particles. As a result, spherical drug crystals treated with porous agglomerate were effectively coated by poly(meth)acrylate powder, showing sustained release after curing. From these findings, particle-shape modification of drug crystals and dry particle coating with nanoparticle agglomerate using a mechanical powder processor is expected as an innovative technique for preparing controlled-release coated particles having high drug content and size smaller than 100 μm.

  4. Application of acoustic agglomeration to reduce fine particle emissions from coal combustion plants

    SciTech Connect

    Gallego-Juarez, J.A.; Riera-Franco De Sarabia, E.; Rodriguez-Corral, G.

    1999-11-01

    Removal of fine particles (smaller than 2.5 {micro}m) from industrial flue gases is, at present, one of the most important problems in air pollution abatement. These particles which are hazardous because of their ability to penetrate deeply into the lungs, are difficult to remove by conventional separation technology. Sonic energy offers a means to solve this problem. The application of a high-intensity acoustic field to an aerosol induces agglomeration processes which changes the size distribution in favor of larger particles, which are then easier to precipitate with a conventional separator. In this work, the authors present a semiindustrial pilot plant in which this process is applied for reduction of particle emissions in coal combustion fumes. This installation basically consists of an acoustic agglomeration chamber with a rectangular cross-section, driven by four high-power and highly directional acoustic transducers of 10 and/or 20 kHz, and an electrostatic precipitator (ESP). In the experiments, a fluidized bed coal combustor was used as fume generator, and a sophisticated air sampling station was set up to carry out measurements with fume flow rates up to about 2,000 m{sup 3}/h, gas temperatures of about 150 C, and mass concentrations in the range 1--5 g/m{sup 3}. The fine particle reduction produced by the acoustic filter was about 40% of the number concentration.

  5. A micromanipulation particle tester for agglomeration contact mechanism studies in a controlled environment

    NASA Astrophysics Data System (ADS)

    Haider, C. I.; Althaus, T.; Niederreiter, G.; Hounslow, M. J.; Palzer, S.; Salman, A. D.

    2012-10-01

    Pressure agglomeration of powders is widely applied in various industries and an increasing interest lies in the identification and description of contact mechanisms between particles, which are responsible for the compaction product properties. In this paper, the design and development of a novel micromanipulation particle tester (MPT) is presented. This device makes it possible to measure the deformation kinetics and resulting adhesion of two individual particles in contact under load, which are strongly influenced by the applied process conditions. The MPT set-up is, therefore, designed to offer a unique control over the process conditions most relevant to the compaction of powders: external stress, dwell or holding time at constant deformation, compression velocity as well as relative humidity and temperature determining the physical state and mechanical characteristics of hygrosensitive amorphous particles. The latter are often part of powder formulations, e.g. in the food industry, and have been used for force and contact-zone development studies with the MPT. The experimental results on the microscale level will deliver valuable quantitative information for an improved tailoring of pressure agglomeration process conditions of bulk solids.

  6. Steric stabilization of nonaqueous silicon slips. I - Control of particle agglomeration and packing. II - Pressure casting of powder compacts

    NASA Technical Reports Server (NTRS)

    Kerkar, Awdhoot V.; Henderson, Robert J. M.; Feke, Donald L.

    1990-01-01

    The application of steric stabilization to control particle agglomeration and packing of silicon powder in benzene and trichloroethylene is reported. The results provide useful guidelines for controlling unfavorable particle-particle interactions during nonaqueous processing of silicon-based ceramic materials. The application of steric stabilization to the control and improvement of green processing of nonaqueous silicon slips in pressure consolidation is also demonstrated.

  7. TEM and HRTEM of Soot-in-oil particles and agglomerates from internal combustion engines

    NASA Astrophysics Data System (ADS)

    Fay, M. W.; La Rocca, A.; Shayler, P. J.

    2014-06-01

    Over time, the performance of lubricating oil in a diesel engine is affected by the build-up of carbon soot produced by the combustion process. TEM and HRTEM are commonly used to investigate the characteristics of individual and agglomerated particles from diesel exhaust, to understand the structure and distribution of the carbon sheets in the primary particles and the nanostructure morphology. However, high resolution imaging of soot-in-oil is more challenging, as mineral oil is a contaminant for the electron microscope and leads to instability under the electron beam. In this work we compare solvent extraction and centrifugation techniques for removing the mineral oil contaminant, and the effect on particle size distribution.

  8. Particle swarm optimization based space debris surveillance network scheduling

    NASA Astrophysics Data System (ADS)

    Jiang, Hai; Liu, Jing; Cheng, Hao-Wen; Zhang, Yao

    2017-02-01

    The increasing number of space debris has created an orbital debris environment that poses increasing impact risks to existing space systems and human space flights. For the safety of in-orbit spacecrafts, we should optimally schedule surveillance tasks for the existing facilities to allocate resources in a manner that most significantly improves the ability to predict and detect events involving affected spacecrafts. This paper analyzes two criteria that mainly affect the performance of a scheduling scheme and introduces an artificial intelligence algorithm into the scheduling of tasks of the space debris surveillance network. A new scheduling algorithm based on the particle swarm optimization algorithm is proposed, which can be implemented in two different ways: individual optimization and joint optimization. Numerical experiments with multiple facilities and objects are conducted based on the proposed algorithm, and simulation results have demonstrated the effectiveness of the proposed algorithm.

  9. THE PHYSICS OF PROTOPLANETESIMAL DUST AGGLOMERATES. VI. EROSION OF LARGE AGGREGATES AS A SOURCE OF MICROMETER-SIZED PARTICLES

    SciTech Connect

    Schraepler, Rainer; Blum, Juergen

    2011-06-20

    Observed protoplanetary disks consist of a large amount of micrometer-sized particles. Dullemond and Dominik pointed out for the first time the difficulty in explaining the strong mid-infrared excess of classical T Tauri stars without any dust-retention mechanisms. Because high relative velocities in between micrometer-sized and macroscopic particles exist in protoplanetary disks, we present experimental results on the erosion of macroscopic agglomerates consisting of micrometer-sized spherical particles via the impact of micrometer-sized particles. We find that after an initial phase, in which an impacting particle erodes up to 10 particles of an agglomerate, the impacting particles compress the agglomerate's surface, which partly passivates the agglomerates against erosion. Due to this effect, the erosion halts for impact velocities up to {approx}30 m s{sup -1} within our error bars. For higher velocities, the erosion is reduced by an order of magnitude. This outcome is explained and confirmed by a numerical model. In a next step, we build an analytical disk model and implement the experimentally found erosive effect. The model shows that erosion is a strong source of micrometer-sized particles in a protoplanetary disk. Finally, we use the stationary solution of this model to explain the amount of micrometer-sized particles in the observational infrared data of Furlan et al.

  10. Optical scattering (TAOS) by tire debris particles: preliminary results

    NASA Astrophysics Data System (ADS)

    Crosta, Giovanni F.; Camatini, Marina C.; Zomer, Simeone; Holler, Stephen; Pan, Yongle; Bhaskara, Praveena; Muangchareon, Pongphisanu; Sung, Changmo; Cencetti, Simone; Regazzoni, Claudia

    2001-03-01

    Tire debris particles from low severity laboratory wear tests have been investigated by the TAOS optical scattering facility at Yale University. The incident wavelength is 532 nm. After the TAOS event some particle samples have been imaged by a scanning electron microscope and microanalyzed. The TAOS intensity patterns recorded within a solid angle in the backward sector have been processed by cluster analysis and compared with the patterns computed by a T-matrix code. Preliminary agreement has been found between TAOS data and the particle models (size, shape, refractive index). The purpose of the investigation is to obtain signatures of the material, based on its TAOS pattern.

  11. Optical scattering (TAOS) by tire debris particles: preliminary results.

    PubMed

    Crosta, G; Camatini, M; Zomer, S; Holler, S; Pan, Y; Bhaskara, P; Muangchareon, P; Sung, C; Cencetti, S; Regazzoni, C

    2001-03-12

    Tire debris particles from low severity laboratory wear tests have been investigated by the TAOS optical scattering facility at Yale University. The incident wavelength is 532 nm. After the TAOS event some particle samples have been imaged by a scanning electron microscope and microanalyzed. The TAOS intensity patterns recorded within a solid angle in the backward sector have been processed by cluster analysis and compared with the patterns computed by a T-matrix code. Preliminary agreement has been found between TAOS data and the particle models (size, shape, refractive index). The purpose of the investigation is to obtain signatures of the material, based on its TAOS pattern.

  12. Field observations of particle impacts by debris flows and debris floods on instrumented rock samples

    NASA Astrophysics Data System (ADS)

    McArdell, B. W.; Hsu, L.; Fritschi, B.; Dietrich, W. E.

    2011-12-01

    Bedrock incision and sediment entrainment by debris flows are important processes in torrent channels. As part of our effort to gain a better understanding of these processes, we installed instrumented rock samples in the bed of the Illgraben channel. Three rock samples, 0.4 m long (in the flow direction), 0.3 m wide, and 0.2 m thick, were installed in steel frames which were mounted on the upslope side of a concrete check dam, with the surface of the stones flush with the channel bed. Accelerometer sensors were installed on the bottom of one rock sample, with a range of up to 500 g (vertical) and 200 g (horizontal, parallel to the channel axis), where g is the acceleration due to gravity. Elastomer elements, typically used in the field as overload protection for load sensors, were placed between the rock samples and the steel frames. Data were sampled at 2 kHz and stored on a computer outside of the channel. The sensors provided data for 4 debris floods and part of one debris flow. For all of the events, the vertical acceleration data indicate a large background noise in the range of ±10 g, punctuated by very short duration impulses of up to several hundred g. The large accelerations are interpreted to represent hard impacts of cobbles or boulders in the flow with the rock tablet. Using a value of >20 g to define the occurrence of a large particle impact, it is possible to differentiate between debris floods (which have on the order of 0.1 impact per second) and the debris flow (on the order of 1 impact per second). The frequency of the sampling is too small to resolve details about the impacts, so it is not possible to precisely determine the maximum accelerations. However the peak recorded values are larger for debris flows, with values up to the measurement limit of the sensors, whereas for floods the maximum accelerations are typically less than 100 g. The results for the accelerometer which measures accelerations in the downstream direction generally mirror

  13. The effect of particle agglomeration on the formation of a surface-connected compartment induced by hydroxyapatite nanoparticles in human monocyte-derived macrophages☆

    PubMed Central

    Müller, Karin H.; Motskin, Michael; Philpott, Alistair J.; Routh, Alexander F.; Shanahan, Catherine M.; Duer, Melinda J.; Skepper, Jeremy N.

    2014-01-01

    Agglomeration dramatically affects many aspects of nanoparticle–cell interactions. Here we show that hydroxyapatite nanoparticles formed large agglomerates in biological medium resulting in extensive particle uptake and dose-dependent cytotoxicity in human macrophages. Particle citration and/or the addition of the dispersant Darvan 7 dramatically reduced mean agglomerate sizes, the amount of particle uptake and concomitantly cytotoxicity. More surprisingly, agglomeration governed the mode of particle uptake. Agglomerates were sequestered within an extensive, interconnected membrane labyrinth open to the extracellular space. In spite of not being truly intracellular, imaging studies suggest particle degradation occurred within this surface-connected compartment (SCC). Agglomerate dispersion prevented the SCC from forming, but did not completely inhibit nanoparticle uptake by other mechanisms. The results of this study could be relevant to understanding particle–cell interactions during developmental mineral deposition, in ectopic calcification in disease, and during application of hydroxyapatite nanoparticle vectors in biomedicine. PMID:24183166

  14. Development of a fluidized bed agglomeration modeling methodology to include particle-level heterogeneities in ash chemistry and granular physics

    NASA Astrophysics Data System (ADS)

    Khadilkar, Aditi B.

    The utility of fluidized bed reactors for combustion and gasification can be enhanced if operational issues such as agglomeration are mitigated. The monetary and efficiency losses could be avoided through a mechanistic understanding of the agglomeration process and prediction of operational conditions that promote agglomeration. Pilot-scale experimentation prior to operation for each specific condition can be cumbersome and expensive. So the development of a mathematical model would aid predictions. With this motivation, the study comprised of the following model development stages- 1) development of an agglomeration modeling methodology based on binary particle collisions, 2) study of heterogeneities in ash chemical composition and gaseous atmosphere, 3) computation of a distribution of particle collision frequencies based on granular physics for a poly-disperse particle size distribution, 4) combining the ash chemistry and granular physics inputs to obtain agglomerate growth probabilities and 5) validation of the modeling methodology. The modeling methodology comprised of testing every binary particle collision in the system for sticking, based on the extent of dissipation of the particles' kinetic energy through viscous dissipation by slag-liquid (molten ash) covering the particles. In the modeling methodology developed in this study, thermodynamic equilibrium calculations are used to estimate the amount of slag-liquid in the system, and the changes in particle collision frequencies are accounted for by continuously tracking the number density of the various particle sizes. In this study, the heterogeneities in chemical composition of fuel ash were studied by separating the bulk fuel into particle classes that are rich in specific minerals. FactSage simulations were performed on two bituminous coals and an anthracite to understand the effect of particle-level heterogeneities on agglomeration. The mineral matter behavior of these constituent classes was studied

  15. Impact Of Particle Agglomeration On Accumulation Rates In The Glass Discharge Riser Of HLW Melter

    SciTech Connect

    Kruger, A. A.; Rodriguez, C. A.; Matyas, J.; Owen, A. T.; Jansik, D. P.; Lang, J. B.

    2012-11-12

    The major factor limiting waste loading in continuous high-level radioactive waste (HLW) melters is an accumulation of particles in the glass discharge riser during a frequent and periodic idling of more than 20 days. An excessive accumulation can produce robust layers a few centimeters thick, which may clog the riser, preventing molten glass from being poured into canisters. Since the accumulation rate is driven by the size of particles we investigated with x-ray microtomography, scanning electron microscopy, and image analysis the impact of spinel forming components, noble metals, and alumina on the size, concentration, and spatial distribution of particles, and on the accumulation rate. Increased concentrations of Fe and Ni in the baseline glass resulted in the formation of large agglomerates that grew over the time to an average size of ~185+-155 {mu}m, and produced >3 mm thick layer after 120 h at 850 deg C. The noble metals decreased the particle size, and therefore significantly slowed down the accumulation rate. Addition of alumina resulted in the formation of a network of spinel dendrites which prevented accumulation of particles into compact layers.

  16. Composite propellant aluminum agglomeration reduction using tailored Al/PTFE particles

    NASA Astrophysics Data System (ADS)

    Sippel, Travis R.

    can be ignited via optical flash. Propellant aluminum agglomeration is assessed through replacement of reference aluminum powders (spherical, flake, or nanoscale) with Al/PTFE (90/10 or 70/30 wt.%) particles. The effects on burning rate, pressure dependence, and aluminum ignition, combustion, and agglomeration are quantified. Microscopic imaging shows tailored particles promptly ignite at the burning surface and appear to breakup into smaller particles. Replacement of spherical aluminum with Al/PTFE 70/30 wt.% also increases the pressure exponent from 0.36 to 0.58, which results in a 50% increase in propellant burning rate at 13.8 MPa. Combustion products were quench collected using a liquid-free technique at 2.1 and 6.9 MPa. Sizing of products indicates that composite particles result in nominally 25 μm coarse products, which are smaller than the original, average particle size and are also 66% smaller in diameter (96% by volume) than the 76 μm products collected from reference spherical aluminized propellant. Smaller diameter condensed phase products and more gaseous products will likely decrease two-phase flow loss and reduce slag accumulation in solid rocket motors.

  17. Particle aerosolisation and break-up in dry powder inhalers: evaluation and modelling of impaction effects for agglomerated systems.

    PubMed

    Wong, William; Fletcher, David F; Traini, Daniela; Chan, Hak-kim; Crapper, John; Young, Paul M

    2011-07-01

    This study utilised a combination of computational fluid dynamics (CFD) and standardised entrainment tubes to investigate the influence of impaction on the break-up and aerosol performance of a model inhalation formulation. A series of entrainment tubes, with different impaction plate angles were designed in silico and the flow characteristics, and particle tracks, were simulated using CFD. The apparatuses were constructed using three-dimensional printing. The deposition and aerosol performance of a model agglomerate system (496.3-789.2 μm agglomerates containing 3.91 μm median diameter mannitol particles) were evaluated by chemical analysis and laser diffraction, respectively. Analysis of the mannitol recovery from the assembly and CFD simulations indicated that mass deposition on the plate was dependent on the impactor angle (45°-90°) but independent of the airflow rate (60-140 L·min(-1)). In comparison, wall losses, perpendicular to the impactor plate were dependent on both the impactor angle and flow rate. Analysis of the particle size distribution exiting the impactor assembly suggested mannitol aerosolisation to be independent of impactor angle but dependent on the air velocity directly above the impactor plate. It is proposed that particle-wall impaction results in initial agglomerate fragmentation followed by reentrainment in the airstream above the impaction plate. Such observations have significant implications in the design of dry powder inhaler devices.

  18. Investigation into the impact of sub-populations of agglomerates on the particle size distribution and flow properties of conventional microcrystalline cellulose grades.

    PubMed

    Gamble, John F; Chiu, Wing-Sin; Tobyn, Mike

    2011-10-01

    Microcrystalline cellulose (MCC) is regarded as one of the most versatile tablet filler binders, finding a wide use in both granulation and direct compression operations. It has been shown that MCC particle populations consist of a mixture of 'rod like' primary particles, and agglomerates, and that the proportion of these primary particles and agglomerates differs within the different grades of materials, contributing to the different bulk properties of these materials. However, the proportion of primary particles and agglomerates has not previously been fully elucidated, and their contribution to the performance factors such as flow explained. In this paper we use a novel microscopy-based characterization technique to demonstrate that the proportion of 'agglomerates' in the series of MCC grades between PH101 and PH200 is, by number, very low, but sufficient to perturb a volume-based particle size method by significant amounts.

  19. Are the stratospheric dust particles meteor ablation debris or interplanetary dust?

    NASA Technical Reports Server (NTRS)

    Blanchard, M. B.; Kyte, F. T.

    1978-01-01

    Natural and laboratory created fusion crusts and debris from artificial meteor samples were used to develop criteria for recognizing meteor ablation debris in a collection of 5 to 50 micron particles from the stratosphere. These laboratory studies indicate that meteor ablation debris from nickel-iron meteoroids produce spherules containing taenite, wuestite, magnetite, and hematite. These same studies also indicate that ablation debris from chondritic meteoroids produce spheres and fragmentary debris. The spheres may be either silicate rich, containing zoned olivine, magnetite, and glass, or sulfide rich, containing iron oxides (e.g., magnetite, wuestite) and iron sulfides (e.g., pyrrhotite, pentlandite). The fragmentary debris may be either fine-grained aggregates of olivine, magnetite, pyroxene, and occasionally pyrrhotite (derived from the meteorite matrix) or individual olivine and pyroxene grains (derived from meteorite inclusions).

  20. Effect of mechanical vibration on platinum particle agglomeration and growth in Polymer Electrolyte Membrane Fuel Cell catalyst layers

    NASA Astrophysics Data System (ADS)

    Diloyan, Georgiy; Sobel, Marcus; Das, Kiranmoy; Hutapea, Parsaoran

    2012-09-01

    The effect of mechanical vibration on Platinum (Pt) particle agglomeration and growth in the catalyst layer of a Membrane Electrode Assembly (MEA) for a Proton Exchange Membrane Fuel Cell (PEMFC) was investigated. A series of experiments were conducted using a 300-h accelerated test with potential cycling and transmission electron microscopy (TEM). Each of the 300-h accelerated tests used different constant mechanical vibration conditions (frequency and acceleration). It was observed that the average diameter of Pt particles under vibration is 10% smaller than the ones that were under no vibration conditions. The Pt particles in the order of 2-2.5 nm in the pristine state have grown to approximately 6 nm (after 300-h accelerated test without vibration condition) and to approximately 5.47 nm (after 300 h accelerated test under 1 g 20 Hz vibration condition).

  1. Agglomeration of Dust

    SciTech Connect

    Annaratone, B. M.; Arnas, C.; Elskens, Y.

    2008-09-07

    The agglomeration of the matter in plasma, from the atomic level up to millimetre size particles, is here considered. In general we identify a continuous growth, due to deposition, and two agglomeration steps, the first at the level of tens of nanometres and the second above the micron. The agglomeration of nano-particles is attributed to electrostatic forces in presence of charge polarity fluctuations. Here we present a model based on discrete currents. With increasing grain size the positive charge permanence decreases, tending to zero. This effect is only important in the range of nanometre for dust of highly dispersed size. When the inter-particle distance is of the order of the screening length another agglomeration mechanism dominates. It is based on attractive forces, shadow forces or dipole-dipole interaction, overcoming the electrostatic repulsion. In bright plasma radiation pressure also plays a role.

  2. Particle size reduction in debris flows: Laboratory experiments compared with field data from Inyo Creek, California

    NASA Astrophysics Data System (ADS)

    Arabnia, O.; Sklar, L. S.; Mclaughlin, M. K.

    2014-12-01

    Rock particles in debris flows are reduced in size through abrasion and fracture. Wear of coarse sediments results in production of finer particles, which alter the bulk material rheology and influence flow dynamics and runout distance. Particle wear also affects the size distribution of coarse particles, transforming the initial sediment size distribution produced on hillslopes into that delivered to the fluvial channel network. A better understanding of the controls on particle wear in debris flows would aid in the inferring flow conditions from debris flow deposits, in estimating the initial size of sediments entrained in the flow, and in modeling debris flow dynamics and mapping hazards. The rate of particle size reduction with distance traveled should depend on the intensity of particle interactions with other particles and the flow boundary, and on rock resistance to wear. We seek a geomorphic transport law to predict rate of particle wear with debris flow travel distance as a function of particle size distribution, flow depth, channel slope, fluid composition and rock strength. Here we use four rotating drums to create laboratory debris flows across a range of scales. Drum diameters range from 0.2 to 4.0 m, with the largest drum able to accommodate up to 2 Mg of material, including boulders. Each drum has vanes along the boundary to prevent sliding. Initial experiments use angular clasts of durable granodiorite; later experiments will use less resistant rock types. Shear rate is varied by changing drum rotational velocity. We begin experiments with well-sorted coarse particle size distributions, which are allowed to evolve through particle wear. The fluid is initially clear water, which rapidly acquires fine-grained wear products. After each travel increment all coarse particles (mass > 0.4 g) are weighed individually. We quantify particle wear rates using statistics of size and mass distributions, and by fitting various comminution functions to the data

  3. An adaptive extended finite element method for the analysis of agglomeration of colloidal particles in a flowing fluid

    SciTech Connect

    Choi, Young Joon; Jorshari, Razzi Movassaghi; Djilali, Ned

    2015-03-10

    Direct numerical simulations of the flow-nanoparticle interaction in a colloidal suspension are presented using an extended finite element method (XFEM) in which the dynamics of the nanoparticles is solved in a fully-coupled manner with the flow. The method is capable of accurately describing solid-fluid interfaces without the need of boundary-fitted meshes to investigate the dynamics of particles in complex flows. In order to accurately compute the high interparticle shear stresses and pressures while minimizing computing costs, an adaptive meshing technique is incorporated with the fluid-structure interaction algorithm. The particle-particle interaction at the microscopic level is modeled using the Lennard-Jones (LJ) potential and the corresponding potential parameters are determined by a scaling procedure. The study is relevant to the preparation of inks used in the fabrication of catalyst layers for fuel cells. In this paper, we are particularly interested in investigating agglomeration of the nanoparticles under external shear flow in a sliding bi-periodic Lees-Edwards frame. The results indicate that the external shear has a crucial impact on the structure formation of colloidal particles in a suspension.

  4. From Agglomerates of Spheres to Irregularly Shaped Particles: Determination of Dynamic Shape Factors from Measurements of Mobility and Vacuum Aerodynamic Diameters

    SciTech Connect

    Zelenyuk, Alla; Cai, Yong; Imre, Dan G.

    2006-03-01

    With the advert of aerosol instrumentation it has become possible to simultaneously measure individual particle mobility and vacuum aerodynamic diameters. For spherical particles these two diameters yield individual particle density. In contrast, assigning a physical meaning to the mobility or aerodynamic diameter of aspherical particles is not straightforward. This paper presents an experimental exploration of the effect of particle shape on the relationship between mobility and vacuum aerodynamic diameters. We make measurements on systems of three types: 1) Agglomerates of spheres, for which the density and the volume are known; 2) Ammonium sulfate, sodium chloride, succinic acid and lauric acid irregularly shaped particles of known density; and 3) Internally mixed particles, containing organics and ammonium sulfate, of unknown density and shape. For agglomerates of spheres we observed alignment effects in the DMA and report the first measurements of the dynamic shape factors (DSFs) in free molecular regime. We present here the first experimental determination of the DSF of ammonium sulfate particles. We find for ammonium sulfate particles a DSF that increases from 1.03 to 1.07 as particle mobility diameter increases from 160 nm to 500 nm. Three types of NaC1 particles were generated and characterized: nearly spherical particles with DSF of ~1.02; cubic with DSF that increases from 1.065 to 1.17 as particle mobility diameter increases from 200 nm to 900 nm; and compact agglomerates with DSF 1.3-1.4. Organic particles were found very nearly spherical. The data suggest that particles composed of binary mixtures of ammonium sulfate and succinic acid have lower dynamic shape factors than pure ammonium sulfate particles. However, for internally mixed ammonium sulfate and lauric acid particles we cannot distinguish between nearly spherical particles with low density and particles with DSF of 1.17.

  5. Debris flow impact on mitigation barriers: a new method for particle-fluid-structure interactions

    NASA Astrophysics Data System (ADS)

    Marchelli, Maddalena; Pirulli, Marina; Pudasaini, Shiva P.

    2016-04-01

    Channelized debris-flows are a type of mass movements that involve water-charged, predominantly coarse-grained inorganic and organic material flowing rapidly down steep confined pre-existing channels (Van Dine, 1985). Due to their rapid movements and destructive power, structural mitigation measures have become an integral part of counter measures against these phenomena, to mitigate and prevent damages resulting from debris-flow impact on urbanized areas. In particular, debris barriers and storage basins, with some form of debris-straining structures incorporated into the barrier constructed across the path of a debris-flow, have a dual role to play: (1) to stimulate deposition by presenting a physical obstruction against flow, and (2) to guarantee that during normal conditions stream water and bedload can pass through the structure; while, during and after an extreme event, the water that is in the flow and some of the fine-grained sediment can escape. A new method to investigate the dynamic interactions between the flowing mass and the debris barrier is presented, with particular emphasis on the effect of the barrier in controlling the water and sediment content of the escaping mass. This aspect is achieved by implementing a new mechanical model into an enhanced two-phase dynamical mass flow model (Pudasaini, 2012), in which solid particles mixture and viscous fluid are taken into account. The complex mechanical model is defined as a function of the energy lost during impact, the physical and geometrical properties of the debris barrier, separate but strongly interacting dynamics of boulder and fluid flows during the impact, particle concentration distribution, and the slope characteristics. The particle-filtering-process results in a large variation in the rheological properties of the fluid-dominated escaping mass, including the substantial reduction in the bulk density, and the inertial forces of the debris-flows. Consequently, the destructive power and run

  6. On the origin of extraterrestrial stratospheric particles: Interplanetary dust or meteor ablation debris?. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Kyte, F. T.

    1977-01-01

    Meteor ablation debris was distinguished from unablated interplanetary dust in a collection of extraterrestrial particles collected in the stratosphere using NASA U-2 aircraft. A 62 g sample of the Murchison (C2) meteorite was artificially ablated to characterize ablation debris for comparison with the stratospheric particles. By using proper experimental conditions, artificial ablation debris can be produced that is similar to natural ablation debris. Analyses of natural fusion crusts, artificial fusion crust, and artificial ablation debris of the Murchison meteorite produced criteria for recognizing debris ablated by a primitive meteoroid. Ninety-five percent of the stratospheric particles can be described as either ablation debris from a primitive meteoroid, or as very primitive interplanetary dust.

  7. Effect of mechanical vibration on platinum particle agglomeration and growth in proton exchange membrane fuel cell catalyst layer

    NASA Astrophysics Data System (ADS)

    Diloyan, Georgiy

    The objective of the current research is to study the effect of mechanical vibration on catalyst layer degradation via Platinum (Pt) particle agglomeration and growth in the membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEM Fuel Cell). This study is of great importance, since many PEM fuel cells operate under a vibrating environment, such as the case of vehicular applications, and this may influence the catalyst layer degradation and fuel cell performance. Through extensive literature review, there are only few researches that have been studied the effect of mechanical vibration on PEM fuel cells. These studies focused only on PEM fuel cell performance under vibration for less than 50 hours and none of them considered the degradation of the fuel cell components, such as MEA and its catalyst layer. To study the effect of the mechanical vibration on the catalyst layer an accelerated test with potential cycling was specially designed to simulate a typical vehicle driving condition. The length of the accelerated test was designed to be 300 hour with potential cycling comprised of idle running, constant load, triangle (variable) load and overload running at various mechanical vibration conditions. These mechanical vibration conditions were as follows: 1g 20 Hz, 1g 40 Hz, 4g 20 Hz and 4g 40 Hz. No vibration tests were also conducted to study the influence of operating time and were used as a baseline for comparison study. The series of accelerated tests were followed by microscopy and spectroscopy analyses using environmental scanning electron microscopy (ESEM), transmission electron microscopy (TEM) and X-Ray diffraction (XRD). An ESEM was used to qualitatively analyze pristine and degraded catalyst. TEM and XRD were used to quantitatively analyze catalyst layer degradation via Pt agglomeration and growth in pristine and degraded states. For each test condition, PEM fuel cell performance by means of Voltage - Current (VI) curves was

  8. Particle Hydrodynamics with Material Strength for Multi-Layer Orbital Debris Shield Design

    NASA Technical Reports Server (NTRS)

    Fahrenthold, Eric P.

    1999-01-01

    Three dimensional simulation of oblique hypervelocity impact on orbital debris shielding places extreme demands on computer resources. Research to date has shown that particle models provide the most accurate and efficient means for computer simulation of shield design problems. In order to employ a particle based modeling approach to the wall plate impact portion of the shield design problem, it is essential that particle codes be augmented to represent strength effects. This report describes augmentation of a Lagrangian particle hydrodynamics code developed by the principal investigator, to include strength effects, allowing for the entire shield impact problem to be represented using a single computer code.

  9. Size of metallic and polyethylene debris particles in failed cemented total hip replacements

    NASA Technical Reports Server (NTRS)

    Lee, J. M.; Salvati, E. A.; Betts, F.; DiCarlo, E. F.; Doty, S. B.; Bullough, P. G.

    1992-01-01

    Reports of differing failure rates of total hip prostheses made of various metals prompted us to measure the size of metallic and polyethylene particulate debris around failed cemented arthroplasties. We used an isolation method, in which metallic debris was extracted from the tissues, and a non-isolation method of routine preparation for light and electron microscopy. Specimens were taken from 30 cases in which the femoral component was of titanium alloy (10), cobalt-chrome alloy (10), or stainless steel (10). The mean size of metallic particles with the isolation method was 0.8 to 1.0 microns by 1.5 to 1.8 microns. The non-isolation method gave a significantly smaller mean size of 0.3 to 0.4 microns by 0.6 to 0.7 microns. For each technique the particle sizes of the three metals were similar. The mean size of polyethylene particles was 2 to 4 microns by 8 to 13 microns. They were larger in tissue retrieved from failed titanium-alloy implants than from cobalt-chrome and stainless-steel implants. Our results suggest that factors other than the size of the metal particles, such as the constituents of the alloy, and the amount and speed of generation of debris, may be more important in the failure of hip replacements.

  10. Space Debris Symposium (A6.) Measurements and Space Surveillance (1.): Measurements of the Small Particle Debris Cloud from the 11 January, 2007 Chinese Anti-satellite Test

    NASA Technical Reports Server (NTRS)

    Matney, Mark J.; Stansbery, Eugene; J.-C Liou; Stokely, Christopher; Horstman, Matthew; Whitlock, David

    2008-01-01

    On January 11, 2007, the Chinese military conducted a test of an anti-satellite (ASAT) system, destroying their own Fengyun-1C spacecraft with an interceptor missile. The resulting hypervelocity collision created an unprecedented number of tracked debris - more than 2500 objects. These objects represent only those large enough for the US Space Surveillance Network (SSN) to track - typically objects larger than about 5-10 cm in diameter. There are expected to be even more debris objects at sizes too small to be seen and tracked by the SSN. Because of the altitude of the target satellite (865 x 845 km orbit), many of the debris are expected to have long orbital lifetimes and contribute to the orbital debris environment for decades to come. In the days and weeks following the ASAT test, NASA was able to use Lincoln Laboratory s Haystack radar on several occasions to observe portions of the ASAT debris cloud. Haystack has the capability of detecting objects down to less than one centimeter in diameter, and a large number of centimeter-sized particles corresponding to the ASAT cloud were clearly seen in the data. While Haystack cannot track these objects, the statistical sampling procedures NASA uses can give an accurate statistical picture of the characteristics of the debris from a breakup event. For years computer models based on data from ground hypervelocity collision tests (e.g., the SOCIT test) and orbital collision experiments (e.g., the P-78 and Delta-180 on-orbit collisions) have been used to predict the extent and characteristics of such hypervelocity collision debris clouds, but until now there have not been good ways to verify these models in the centimeter size regime. It is believed that unplanned collisions of objects in space similar to ASAT tests will drive the long-term future evolution of the debris environment in near-Earth space. Therefore, the Chinese ASAT test provides an excellent opportunity to test the models used to predict the future debris

  11. Acoustic agglomeration methods and apparatus

    NASA Technical Reports Server (NTRS)

    Barmatz, M. B. (Inventor)

    1984-01-01

    Methods are described for using acoustic energy to agglomerate fine particles on the order of one micron diameter that are suspended in gas, to provide agglomerates large enough for efficient removal by other techniques. The gas with suspended particles, is passed through the length of a chamber while acoustic energy at a resonant chamber mode is applied to set up one or more acoustic standing wave patterns that vibrate the suspended particles to bring them together so they agglomerate. Several widely different frequencies can be applied to efficiently vibrate particles of widely differing sizes. The standing wave pattern can be applied along directions transversed to the flow of the gas. The particles can be made to move in circles by applying acoustic energy in perpendicular directions with the energy in both directions being of the same wavelength but 90 deg out of phase.

  12. An improved theoretical model of acoustic agglomeration

    SciTech Connect

    Song, L. ); Koopmann, G.H. . Center for Acoustics and Vibration); Hoffmann, T.L. )

    1994-04-01

    An improved theoretical model is developed to describe the acoustic agglomeration of particles entrained in a gas medium. The improvements to the present theories are twofold: first, wave scattering is included in the orthokinetic interaction of particles and second, hydrodynamic interaction, shown to be an important agglomeration mechanism for certain operation conditions, is incorporated into the model. The influence of orthokinetic and hydrodynamic interactions introduce associated convergent velocities that cause particles to approach each other and collide. The convergent velocities are related with an acoustic agglomeration frequency function (AAFF) through a semi-statistical method. This function is the key parameter for the theoretical simulation of acoustic agglomeration.

  13. IMPACT OF PARTICLE SIZE AND AGGLOMERATION ON SETTLING OF SOLIDS IN CONTINUOUS MELTERS PROCESSING RADIOACTIVE WASTE GLASS

    SciTech Connect

    HRMA PR

    2008-12-18

    The major factor limiting waste loading for many waste compositions in continuous waste glass melters is the settling of crystalline materials. The currently used constraints, i.e., the minimum liquidus temperature or the maximum fraction of equilibrium crystallinity at a given temperature, are based on thennodynamic equilibria. Because of the rapid circular convection in the melter, these constraints are probably irrelevant and cannot prevent large crystals from settling. The main factor that detennines the rate of settling ofindividual crystals, such as those ofspinel, is their size. The tiny crystals of RU02 are too small to settle, but they readily fonn large agglomerates that accelerate their rate ofsettling by severalorders ofmagnitude. The RU02 agglomerates originate early in the melting process and then grow by the shear-flocculation mechanism. It is estimated that these agglomerates must either be ofhundreds micrometers in size or have an elongated shape to match the observed rates ofthe sludge-layer fonnation. PACS: 47.57.ef, 81.05.Kj, 81.10.Fg

  14. In vitro studies on the effect of particle size on macrophage responses to nanodiamond wear debris

    PubMed Central

    Thomas, Vinoy; Halloran, Brian A.; Ambalavanan, Namasivayam; Catledge, Shane A.; Vohra, Yogesh K.

    2012-01-01

    Nanostructured diamond coatings improve the smoothness and wear characteristics of the metallic component of total hip replacements and increase the longevity of these implants, but the effect of nanodiamond wear debris on macrophages needs to be determined to estimate the long-term inflammatory effects of wear debris. The objective was to investigate the effect of the size of synthetic nanodiamond particles on macrophage proliferation (BrdU incorporation), apoptosis (Annexin-V flow cytometry), metabolic activity (WST-1 assay) and inflammatory cytokine production (qPCR). RAW 264.7 macrophages were exposed to varying sizes (6, 60, 100, 250 and 500 nm) and concentrations (0, 10, 50, 100 and 200 μg ml−1) of synthetic nanodiamonds. We observed that cell proliferation but not metabolic activity was decreased with nanoparticle sizes of 6–100 nm at lower concentrations (50 μg ml−1), and both cell proliferation and metabolic activity were significantly reduced with nanodiamond concentrations of 200 μg ml−1. Flow cytometry indicated a significant reduction in cell viability due to necrosis irrespective of particle size. Nanodiamond exposure significantly reduced gene expression of tumor necrosis factor-α, interleukin-1β, chemokine Ccl2 and platelet-derived growth factor compared to serum-only controls or titanium oxide (anatase 8 nm) nanoparticles, with variable effects on chemokine Cxcl2 and vascular endothelial growth factor. In general, our study demonstrates a size and concentration dependence of macrophage responses in vitro to nanodiamond particles as possible wear debris from diamond-coated orthopedic joint implants. PMID:22342422

  15. MTCI acoustic agglomeration particulate control

    SciTech Connect

    Chandran, R.R.; Mansour, M.N.; Scaroni, A.W.; Koopmann, G.H.; Loth, J.L.

    1994-10-01

    The overall objective of this project is to demonstrate pulse combination induced acoustic enhancement of coal ash agglomeration and sulfur capture at conditions typical of direct coal-fired turbines and PFBC hot gas cleanup. MTCI has developed an advanced compact pulse combustor island for direct coal-firing in combustion gas turbines. This combustor island comprises a coal-fired pulse combustor, a combined ash agglomeration and sulfur capture chamber (CAASCC), and a hot cyclone. In the MTCI proprietary approach, the pulse combustion-induced high intensity sound waves improve sulfur capture efficiency and ash agglomeration. The resulting agglomerates allow the use of commercial cyclones and achieve very high particulate collection efficiency. In the MTCI proprietary approach, sorbent particles are injected into a gas stream subjected to an intense acoustic field. The acoustic field serves to improve sulfur capture efficiency by enhancing both gas film and intra-particle mass transfer rates. In addition, the sorbent particles act as dynamic filter foci, providing a high density of stagnant agglomerating centers for trapping the finer entrained (in the oscillating flow field) fly ash fractions. A team has been formed with MTCI as the prime contractor and Penn State University and West Virginia University as subcontractors to MTCI. MTCI is focusing on hardware development and system demonstration, PSU is investigating and modeling acoustic agglomeration and sulfur capture, and WVU is studying aerovalve fluid dynamics. Results are presented from all three studies.

  16. Microbial effects on colloidal agglomeration

    SciTech Connect

    Hersman, L.

    1995-11-01

    Colloidal particles are known to enhance the transport of radioactive metals through soil and rock systems. This study was performed to determine if a soil microorganism, isolated from the surface samples collected at Yucca Mountain, NV, could affect the colloidal properties of day particles. The agglomeration of a Wyoming bentonite clay in a sterile uninoculated microbial growth medium was compared to the agglomeration in the medium inoculated with a Pseudomonas sp. In a second experiment, microorganisms were cultured in the succinate medium for 50 h and removed by centrifugation. The agglomeration of the clay in this spent was compared to sterile uninoculated medium. In both experiments, the agglomeration of the clay was greater than that of the sterile, uninoculated control. Based on these results, which indicate that this microorganism enhanced the agglomeration of the bentonite clay, it is possible to say that in the presence of microorganisms colloidal movement through a rock matrix could be reduced because of an overall increase in the size of colloidal particle agglomerates. 32 refs.

  17. Bovine Serum Albumin Adsorption on TiO2 Colloids: The Effect of Particle Agglomeration and Surface Composition.

    PubMed

    Márquez, Augusto; Berger, Thomas; Feinle, Andrea; Hüsing, Nicola; Himly, Martin; Duschl, Albert; Diwald, Oliver

    2017-02-28

    Protein adsorption at nanostructured oxides strongly depends on the synthesis conditions and sample history of the material investigated. We measured the adsorption of bovine serum albumin (BSA) to commercial Aeroxide TiO2 P25 nanoparticles in aqueous dispersions. Significant changes in the adsorption capacity were induced by mild sample washing procedures and attributed to the structural modification of adsorbed water and surface hydroxyls. Motivated by the lack of information about the sample history of commercial TiO2 nanoparticle samples, we used vapor-phase-grown TiO2 nanoparticles, a well-established model system for adsorption and photocatalysis studies, and performed on this material for the first time a systematic and quantitative BSA adsorption study. After alternating vacuum and oxygen treatment of the nanoparticle powders at elevated temperatures for surface purification, we determined size distributions covering both the size of the individualized nanoparticles and nanoparticle agglomerates using transmission electron microscopy (TEM), X-ray diffraction (XRD), and dynamic light scattering (DLS) in an aqueous dispersion. Quantitative BSA adsorption measurements at different pH values and thus variable combinations of surface-charged proteins and TiO2 nanoparticles revealed a consistent picture: BSA adsorbs only at the outer agglomerate surfaces without penetrating the interior of the agglomerates. This process levels at coverages of single monolayers, which resist consecutive simple washing procedures. A detailed analysis of the protein-specific IR amide bands reveals that the adsorption-induced protein conformational change is associated with a decrease in the helical content. This study underlines that robust qualitative and quantitative statements about protein adsorption and corona formation require well-documented and controllable surface properties of the nanomaterials involved.

  18. Soft- and hard-agglomerate aerosols made at high temperatures.

    PubMed

    Tsantilis, Stavros; Pratsinis, Sotiris E

    2004-07-06

    Criteria for aerosol synthesis of soft-agglomerate, hard-agglomerate, or even nonagglomerate particles are developed on the basis of particle sintering and coalescence. Agglomerate (or aggregate) particles are held together by weak, physical van der Waals forces (soft agglomerates) or by stronger chemical or sintering bonds (hard agglomerates). Accounting for simultaneous gas phase chemical reaction, coagulation, and sintering during the formation and growth of silica (SiO2) nanoparticles by silicon tetrachloride (SiCl4) oxidation and neglecting the spread of particle size distribution, the onset of hard-agglomerate formation is identified at the end of full coalescence, while the onset of soft-agglomerate formation is identified at the end of sintering. Process conditions such as the precursor initial volume fraction, maximum temperature, residence time, and cooling rate are explored, identifying regions for the synthesis of particles with a controlled degree of agglomeration (ratio of collision to primary particle diameters).

  19. Direct Pb Isotopic Analysis of a Nuclear Fallout Debris Particle from the Trinity Nuclear Test.

    PubMed

    Bellucci, Jeremy J; Snape, Joshua F; Whitehouse, Martin J; Nemchin, Alexander A

    2017-02-07

    The Pb isotope composition of a nuclear fallout debris particle has been directly measured in post-detonation materials produced during the Trinity nuclear test by a secondary ion mass spectrometry (SIMS) scanning ion image technique (SII). This technique permits the visual assessment of the spatial distribution of Pb and can be used to obtain full Pb isotope compositions in user-defined regions in a 70 μm × 70 μm analytical window. In conjunction with backscattered electron (BSE) and energy-dispersive spectroscopy (EDS) mapping of the same particle, the Pb measured in this fallout particle cannot be from a major phase in the precursor arkosic sand. Similarly, the Pb isotope composition of the particle is resolvable from the surrounding glass at the 2σ uncertainty level (where σ represents the standard deviation). The Pb isotope composition measured in the particle here is in excellent agreement with that inferred from measurements of green and red trinitite, suggesting that these types of particles are responsible for the Pb isotope compositions measured in both trinitite glasses.

  20. Agglomeration tendency in dry pharmaceutical granular systems.

    PubMed

    Lachiver, Emilie DesRosiers; Abatzoglou, Nicolas; Cartilier, Louis; Simard, Jean-Sébastien

    2006-10-01

    The agglomeration tendency of dry pharmaceutical mixtures containing various concentrations of Xylitab 100 (Xylitol), calcium carbonate precipitated (CCP) and magnesium stearate (MgSt) was evaluated statistically as a function of mixing time. A Ro-Tap tester was employed to mix the three pharmaceutical components, and the agglomerates formed were measured with respect to their weight and size. An experimental design was devised and applied to structure and then statistically analyze the results. Xylitab was found not to be influential in the formation of agglomerates, but aided in deagglomeration when mixed with other components. CCP and MgSt formed agglomerates over time and showed positive interactions favouring agglomeration. The agglomerates started to fracture when they reached a critical size, at which stage the particles' attraction forces (cohesion forces) were weaker than both gravity and inertia. It has been shown and quantitatively demonstrated that the mixing time and ingredient concentrations of a three-component pharmaceutical mixture can affect agglomeration tendency.

  1. Powder agglomeration in a microgravity environment

    NASA Technical Reports Server (NTRS)

    Cawley, James D.

    1994-01-01

    This is the final report for NASA Grant NAG3-755 entitled 'Powder Agglomeration in a Microgravity Environment.' The research program included both two types of numerical models and two types of experiments. The numerical modeling included the use of Monte Carlo type simulations of agglomerate growth including hydrodynamic screening and molecular dynamics type simulations of the rearrangement of particles within an agglomerate under a gravitational field. Experiments included direct observation of the agglomeration of submicron alumina and indirect observation, using small angle light scattering, of the agglomeration of colloidal silica and aluminum monohydroxide. In the former class of experiments, the powders were constrained to move on a two-dimensional surface oriented to minimize the effect of gravity. In the latter, some experiments involved mixture of suspensions containing particles of opposite charge which resulted in agglomeration on a very short time scale relative to settling under gravity.

  2. Mechanisms for selective agglomeration of coals

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.-C.; Tyson, D.; Xiaoping, Qiu; Lessa, A.

    1989-05-01

    Work continued on the basic mechanisms which underlie various processes for beneficiating aqueous suspensions of coal by selective agglomeration with oil. A new method was demonstrated for characterizing the agglomerability of coal suspensions. This method utilizes a photometric dispersion analyzer to monitor changes in the turbidity of a particle suspension as increasing amounts of oil are added to the suspension in a batch agglomeration test. Agglomeration of the particles leads to a marked decrease in the turbidity of the suspension. Another experimental technique was also demonstrated for characterizing oil agglomeration. This technique involves measuring the rate of growth of agglomerates in a continuous flow system operating under stead-state conditions. The data are analyzed by means of a population balance. The results of a preliminary set of experiments in which Indiana V seam coal was agglomerated with tetralin seemed to fit a particular growth model very well. Equipment was also constructed for studying the kinetics of agglomeration in a batch process. While earlier work showed that quebracho (a commercially available dispersant) is a strong agglomeration depressant for pyrite, recent experiments with mixtures of Upper Freeport coal and mineral pyrite showed that quebracho does not appear to be sufficiently selective. Further consideration was given to the separation of mixtures of coal and pyrite agglomeration with heptane. 2 refs., 17 figs., 1 tab.

  3. Numerical modeling of debris flow runout for a case in southwestern China with Smooth Particle Hydrodynamics

    NASA Astrophysics Data System (ADS)

    Braun, Anika; Cuomo, Sabatino; Wang, Xueliang; Zhang, Luqing

    2016-04-01

    Debris flows and landslide dams are a major natural hazard causing high socioeconomic risk in inhabited mountainous areas. This is also true for vast parts of southwestern China, which are highly prone to slope failures due to several factors, such as a humid climate with high precipitation in the summer months, geological predisposing factors with highly weathered sedimentary rocks and a high seismicity. Not only do the landslides and flooding related to landslide dams threaten residents, buildings and transportation structures, but also do flooding conditions endanger power supply, which relies in this region partly on hydropower. In order to assess the potential of landslides to block rivers, it is crucial to understand which factors influence possible run-out distances and how they can be quantified. In the study we are presenting a numerical modeling analysis for a particular case of a complex landslide in Ningnan county, southwestern China, which transformed into a debris flow and blocked the river and the major road leading through the valley after heavy rainfall. For this purpose a quasi-3D Smooth Particle Hydrodynamics (SPH) model was implemented that can account for geotechnical slope parameters, run-out distance, velocities and deposition heights. A digital terrain model and the geometry information of the landslide were used as input data in order to estimate the relevant geotechnical parameters by back-analysis. The results of the analysis can be used for the prediction of run-out distances for future events at this site and other similar sites.

  4. Natural and orbital debris particles on LDEF`s trailing and forward-facing surfaces

    SciTech Connect

    Hoerz, F.; See, T.H.; Bernhard, R.P.; Brownlee, D.E. |

    1995-02-01

    Approximately 1000 impact craters on the Chemistry of Meteoroid Experiment (CME) have been analyzed by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Analysis (EDXA) to determine the compositional make-up of projectile residues. This report completes the authors systematic survey of gold and aluminum surfaces exposed at the trailing-edge (A03) and forward-facing (A11) LDEF sites, respectively. The major categories for the projectile residues were (1) natural, with diverse subgroups such as chondritic, monomineralic silicates, and sulfides, and (2) man made, that were classified into aluminum (metallic or oxide) and miscellaneous materials (such as stainless steel, paint flakes, etc). On CME gold collectors on LDEF`s trailing edge approximately 11 percent of all craters greater than 100 micron in diameter were due to man-made debris, the majority (8.6 percent) caused by pure aluminum, approximately 31.4 percent were due to cosmic dust, while the remaining 58 percent were indeterminate via the analytical techniques utilized in this study. The aluminum surfaces located at the A11 forward-facing site did not permit analysis of aluminum impactors, but approximately 9.4 percent of all craters were demonstratably caused by miscellaneous debris materials and approximately 39.2 percent were the result of natural particles, leaving approximately 50 percent which were indeterminate. Model considerations and calculations are presented that focus on the crater-production rates for features greater than 100 micron in diameter, and on assigning the intermediate crater population to man-made or natural particles. An enhancement factor of 6 in the crater-production rate of natural impactors for the `forward-facing` versus the `trailing-edge` CME collectors was found to best explain all observations (i.e., total crater number(s), as well as their computational characteristics). Enhancement factors of 10 and 4 are either too high or too low.

  5. Natural and orbital debris particles on LDEF's trailing and forward-facing surfaces

    NASA Technical Reports Server (NTRS)

    Hoerz, Friedrich; See, Thomas H.; Bernhard, Ronald P.; Brownlee, Donald E.

    1995-01-01

    Approximately 1000 impact craters on the Chemistry of Meteoroid Experiment (CME) have been analyzed by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Analysis (EDXA) to determine the compositional make-up of projectile residues. This report completes our systematic survey of gold and aluminum surfaces exposed at the trailing-edge (A03) and forward-facing (A11) LDEF sites, respectively. The major categories for the projectile residues were (1) natural, with diverse subgroups such as chondritic, monomineralic silicates, and sulfides, and (2) man made, that were classified into aluminum (metallic or oxide) and miscellaneous materials (such as stainless steel, paint flakes, etc). On CME gold collectors on LDEF's trailing edge approximately 11 percent of all craters greater than 100 micron in diameter were due to man-made debris, the majority (8.6 percent) caused by pure aluminum, approximately 31.4 percent were due to cosmic dust, while the remaining 58 percent were indeterminate via the analytical techniques utilized in this study. The aluminum surfaces located at the A11 forward-facing site did not permit analysis of aluminum impactors, but approximately 9.4 percent of all craters were demonstratably caused by miscellaneous debris materials and approximately 39.2 percent were the result of natural particles, leaving approximately 50 percent which were indeterminate. Model considerations and calculations are presented that focus on the crater-production rates for features greater than 100 micron in diameter, and on assigning the intermediate crater population to man-made or natural particles. An enhancement factor of 6 in the crater-production rate of natural impactors for the 'forward-facing' versus the 'trailing-edge' CME collectors was found to best explain all observations (i.e., total crater number(s), as well as their computational characteristics). Enhancement factors of 10 and 4 are either too high or too low. It is also suggested that

  6. Porous Chromatographic Materials as Substrates for Preparing Synthetic Nuclear Explosion Debris Particles

    SciTech Connect

    Harvey, Scott D.; Liezers, Martin; Antolick, Kathryn C.; Garcia, Ben J.; Sweet, Lucas E.; Carman, April J.; Eiden, Gregory C.

    2013-06-13

    In this study, we investigated several porous chromatographic materials as synthetic substrates for preparing surrogate nuclear explosion debris particles. The resulting synthetic debris materials are of interest for use in developing analytical methods. Eighteen metals, including some of forensic interest, were loaded onto materials by immersing them in metal solutions (556 mg/L of each metal) to fill the pores, applying gentle heat (110°C) to drive off water, and then treating them at high temperatures (up to 800°C) in air to form less soluble metal species. High-boiling-point metals were uniformly loaded on spherical controlled-pore glass to emulate early fallout, whereas low-boiling-point metals were loaded on core-shell silica to represent coated particles formed later in the nuclear fallout-formation process. Analytical studies were applied to characterize solubility, material balance, and formation of recalcitrant species. Dissolution experiments indicated loading was 1.5 to 3 times higher than expected from the pore volume alone, a result attributed to surface coating. Analysis of load solutions before and after filling the material pores revealed that most metals were passively loaded; that is, solutions filled the pores without active metal discrimination. However, niobium and tin concentrations were lower in solutions after pore filling, and were found in elevated concentrations in the final products, indicating some metals were selectively loaded. High-temperature treatments caused reduced solubility of several metal species, and loss of some metals (rhenium and tellurium) because volatile species were formed. Sample preparation reproducibility was high (the inter-batch relative standard deviation was 7.8%, and the intra-batch relative standard deviation was 0.84%) indicating that this material is suitable for use as a working standard for analytical methods development. We anticipate future standardized radionuclide-loaded materials will find use in

  7. Fuel agglomerates and method of agglomeration

    DOEpatents

    Wen, Wu-Wey

    1986-01-01

    Solid fuel agglomerates are prepared of particulate coal or other carbonaceous material with a binder having a high humic acid or humate salt content. The humic acid is extracted from oxidized carbonaceous material with a mild aqueous alkali solution of, for instance, ammonia. The particulate material is blended with the extract which serves as the binder for the agglomerates. The water-resistant agglomerates are formed such as by pelletizing, followed by drying to remove moisture and solidify the humic acid binder throughout the agglomerate.

  8. Dust agglomeration

    NASA Technical Reports Server (NTRS)

    2000-01-01

    John Marshall, an investigator at Ames Research Center and a principal investigator in the microgravity fluid physics program, is studying the adhesion and cohesion of particles in order to shed light on how granular systems behave. These systems include everything from giant dust clouds that form planets to tiny compressed pellets, such as the ones you swallow as tablets. This knowledge should help us control the grains, dust, and powders that we encounter or use on a daily basis. Marshall investigated electrostatic charge in microgravity on the first and second U.S. Microgravity Laboratory shuttle missions to see how grains aggregate, or stick together. With gravity's effects eliminated on orbit, Marshall found that the grains of sand that behaved ever so freely on Earth now behaved like flour. They would just glom together in clumps and were quite difficult to disperse. That led to an understanding of the prevalence of the electrostatic forces. The granules wanted to aggregate as little chains, like little hairs, and stack end to end. Some of the chains had 20 or 30 grains. This phenomenon indicated that another force, what Marshall believes to be an electrostatic dipole, was at work.(The diagram on the right emphasizes the aggregating particles in the photo on the left, taken during the USML-2 mission in 1995.)

  9. Enhancement of the Wear Particle Monitoring Capability of Oil Debris Sensors Using a Maximal Overlap Discrete Wavelet Transform with Optimal Decomposition Depth

    PubMed Central

    Li, Chuan; Peng, Juan; Liang, Ming

    2014-01-01

    Oil debris sensors are effective tools to monitor wear particles in lubricants. For in situ applications, surrounding noise and vibration interferences often distort the oil debris signature of the sensor. Hence extracting oil debris signatures from sensor signals is a challenging task for wear particle monitoring. In this paper we employ the maximal overlap discrete wavelet transform (MODWT) with optimal decomposition depth to enhance the wear particle monitoring capability. The sensor signal is decomposed by the MODWT into different depths for detecting the wear particle existence. To extract the authentic particle signature with minimal distortion, the root mean square deviation of kurtosis value of the segmented signal residue is adopted as a criterion to obtain the optimal decomposition depth for the MODWT. The proposed approach is evaluated using both simulated and experimental wear particles. The results show that the present method can improve the oil debris monitoring capability without structural upgrade requirements. PMID:24686730

  10. Engineering development of selective agglomeration. Final report

    SciTech Connect

    Not Available

    1993-04-01

    This report presents the findings of the project entitled ``Engineering Development of Selective Agglomeration.`` The purpose is to develop selective agglomeration technology to a commercially acceptable level by 1993. Engineering development included bench-scale process development, component development adaptation or modification of existing unit operations, proof-of-concept (POC) module design, fabrication, testing, data evaluation, and conceptual design of a commercial facility. The information obtained during POC operation resulted in a technical and economic design base sufficient to support construction and operation of a commercial plant. Throughout this project performance targets for the engineering development of selective agglomeration process were to achieve 85% or greater Btu recovery at 85% or greater pyritic sulfur rejection (PSR). Additional objectives included producing a final clean-coal product with an ash content of 6% or less which is suitable for conventional coal handling systems. The selective agglomeration process, as applied to coal cleaning, is based on differences in the surface chemistry of coal and its associated impurities. Coal particles are hydrophobic (i.e., repel water) while the majority of its impurities are hydrophilic (i.e., stabilized in water). During selective agglomeration, a liquid (the agglomerant) that is immiscible with water is introduced into a coal-water slurry and agitated to disperse it in the slurry, thereby allowing it to come into contact with all particles in the slurry. The coal particles, due to their hydrophobic nature, are attracted to the agglomerant phase. The hydrophilic mineral impurities remain in the water phase. Continued agitation of the agglomerant-coated coal particles causes them to coalesce to form agglomerates. Once the agglomerates are formed, they are separated from the mineral matter-bearing aqueous phase by subsequent processing steps.

  11. Varying the agglomeration position of particles in a micro-channel using Acoustic Radiation Force beyond the resonance condition.

    PubMed

    Dron, Olivier; Aider, Jean-Luc

    2013-09-01

    It is well-known that particles can be focused at mid-height of a micro-channel using Acoustic Radiation Force (ARF) tuned at the resonance frequency (h=λ/2). The resonance condition is a strong limitation to the use of acoustophoresis (particles manipulation using acoustic force) in many applications. In this study we show that it is possible to focus the particles anywhere along the height of a micro-channel just by varying the acoustic frequency, in contradiction with the resonance condition. This result has been thoroughly checked experimentally. The different physical properties as well as wall materials have been changed. The wall materials is finally the only critical parameters. One of the specificity of the micro-channel is the thickness of the carrier and reflector layer. A preliminary analysis of the experimental results suggests that the acoustic focusing beyond the classic resonance condition can be explained in the framework of the multilayered resonator proposed by Hill [1]. Nevertheless, further numerical studies are needed in order to confirm and fully understand how the acoustic pressure node can be moved over the entire height of the micro channel by varying the acoustic frequency. Despite some uncertainties about the origin of the phenomenon, it is robust and can be used for improved acoustic sorting or manipulation of particles or biological cells in confined set-ups.

  12. Investigation of Gear and Bearing Fatigue Damage Using Debris Particle Distributions

    NASA Technical Reports Server (NTRS)

    Dempsey, Paula J.; Lewicki, David G.; Decker, Harry J.

    2004-01-01

    A diagnostic tool was developed for detecting fatigue damage to spur gears, spiral bevel gears, and rolling element bearings. This diagnostic tool was developed and evaluated experimentally by collecting oil debris data from fatigue tests performed in the NASA Glenn Spur Gear Fatigue Rig, Spiral Bevel Gear Test Facility, and the 500hp Helicopter Transmission Test Stand. During each test, data from an online, in-line, inductance type oil debris sensor was monitored and recorded for the occurrence of pitting damage. Results indicate oil debris alone cannot discriminate between bearing and gear fatigue damage.

  13. Large-scale Particle Simulations for Debris Flows using Dynamic Load Balance on a GPU-rich Supercomputer

    NASA Astrophysics Data System (ADS)

    Tsuzuki, Satori; Aoki, Takayuki

    2016-04-01

    Numerical simulations for debris flows including a countless of objects is one of important topics in fluid dynamics and many engineering applications. Particle-based method is a promising approach to carry out the simulations for flows interacting with objects. In this paper, we propose an efficient method to realize a large-scale simulation for fluid-structure interaction by combining SPH (Smoothed Particle Hydrodynamics) method for fluid with DEM (Discrete Element Method) for objects on a multi-GPU system. By applying space filling curves to decomposition of the computational domain, we are able to contain the same number of particles in each decomposed domain. In our implementation, several techniques for particle counting and data movement have been introduced. Fragmentation of the memory used for particles happens during the time-integration and the frequency of de-fragmentation is examined by taking account for computational load balance and the communication cost between CPU and GPU. A link-list technique of the particle interaction is introduced to save the memory drastically. It is found that the sorting of particle data for the neighboring particle list using linked-list method improves the memory access greatly with a certain interval. The weak and strong scalabilities for a SPH simulation using 111 Million particles was measured from 4 GPUs to 512 GPUs for three types of space filling curves. A large-scale debris flow simulation of tsunami with 10,368 floating rubbles using 117 Million particles were successfully carried out with 256 GPUs on the TSUBAME 2.5 supercomputer at Tokyo Institute of Technology.

  14. Agglomeration of microparticles in complex plasmas

    SciTech Connect

    Du, Cheng-Ran; Thomas, Hubertus M.; Ivlev, Alexei V.; Konopka, Uwe; Morfill, Gregor E.

    2010-11-15

    Agglomeration of highly charged microparticles was observed and studied in complex plasma experiments carried out in a capacitively coupled rf discharge. The agglomeration was caused by strong waves triggered in a particle cloud by decreasing neutral gas pressure. Using a high-speed camera during this unstable regime, it was possible to resolve the motion of individual microparticles and to show that the relative velocities of some particles were sufficiently high to overcome the mutual Coulomb repulsion and hence to result in agglomeration. After stabilizing the cloud again through the increase of the pressure, we were able to observe the aggregates directly with a long-distance microscope. We show that the agglomeration rate deduced from our experiments is in good agreement with theoretical estimates. In addition, we briefly discuss the mechanisms that can provide binding of highly charged microparticles in a plasma.

  15. Advances in food powder agglomeration engineering.

    PubMed

    Cuq, B; Gaiani, C; Turchiuli, C; Galet, L; Scher, J; Jeantet, R; Mandato, S; Petit, J; Murrieta-Pazos, I; Barkouti, A; Schuck, P; Rondet, E; Delalonde, M; Dumoulin, E; Delaplace, G; Ruiz, T

    2013-01-01

    Food powders are used in everyday life in many ways and offer technological solutions to the problem of food production. The natural origin of food powders, diversity in their chemical composition, variability of the raw materials, heterogeneity of the native structures, and physicochemical reactivity under hydrothermal stresses contribute to the complexity in their behavior. Food powder agglomeration has recently been considered according to a multiscale approach, which is followed in the chapter layout: (i) at the particle scale, by a presentation of particle properties and surface reactivity in connection with the agglomeration mechanisms, (ii) at the mechanisms scale, by describing the structuration dynamics of agglomerates, (iii) at the process scale, by a presentation of agglomeration technologies and sensors and by studying the stress transmission mode in the powder bed, and finally (iv) by an integration of the acquired knowledge, thanks to a dimensional analysis carried out at each scale.

  16. Multifrequency scanning probe microscopy study of nanodiamond agglomerates

    NASA Astrophysics Data System (ADS)

    Aravind, Vasudeva; Lippold, Stephen; Li, Qian; Strelcov, Evgheny; Okatan, Baris; Legum, Benjamin; Kalinin, Sergei; Clarion University Team; Oak Ridge National Laboratory Team

    Due to their rich surface chemistry and excellent mechanical properties and non-toxic nature, nanodiamond particles have found applications such as biomedicine, tribology and lubrication, targeted drug delivery systems, tissue scaffolds and surgical implants. Although single nanodiamond particles have diameters about 4-5nm, they tend to form agglomerates. While these agglomerates can be useful for some purposes, many applications of nanodiamonds require single particle, disaggregated nanodiamonds. This work is oriented towards studying forces and interactions that contribute to agglomeration in nanodiamonds. In this work, using multifrequency scanning probe microscopy techniques, we show that agglomerate sizes can vary between 50-100nm in raw nanodiamonds. Extremeties of particles and Interfaces between agglomerates show dissipative forces with scanning probe microscope tip, indicating agglomerates could act as points of increased adhesion, thus reducing lubricating efficiency when nanodiamonds are used as lubricant additives. This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

  17. Development of a Gas-Promoted Oil Agglomeration Process

    SciTech Connect

    C. Nelson; F. Zhang; J. Drzymala; M. Shen; R. Abbott; T. D. Wheelock

    1997-11-01

    The preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal was carried out with scale model mixing systems in which aqueous suspensions of ultrafine coal particles were treated with a liquid hydrocarbon and a small amount of air. The resulting agglomerates were recovered by screening. During a batch agglomeration test the progress of agglomeration was monitored by observing changes in agitator torque in the case of concentrated suspensions or by observing changes in turbidity in the case of dilute suspensions. Dilute suspensions were employed for investigating the kinetics of agglomeration, whereas concentrated suspensions were used for determining parameters that characterize the process of agglomeration. A key parameter turned out to be the minimum time te required to produce compact spherical agglomerates. Other important parameters included the projected area mean particle diameter of the agglomerates recovered at the end of a test as well as the ash content and yield of agglomerates. Batch agglomeration tests were conducted with geometrically similar mixing tanks which ranged in volume from 0.346 to 11.07 liters. Each tank was enclosed to control the amount of air present. A variable speed agitator fitted with a six blade turbine impeller was used for agitation. Tests were conducted with moderately hydrophobic Pittsburgh No. 8 coal and with more hydrophobic Upper Freeport coal using either n-heptane, i-octane, or hexadecane as an agglomerant.

  18. Space debris tracking based on fuzzy running Gaussian average adaptive particle filter track-before-detect algorithm

    NASA Astrophysics Data System (ADS)

    Torteeka, Peerapong; Gao, Peng-Qi; Shen, Ming; Guo, Xiao-Zhang; Yang, Da-Tao; Yu, Huan-Huan; Zhou, Wei-Ping; Zhao, You

    2017-02-01

    Although tracking with a passive optical telescope is a powerful technique for space debris observation, it is limited by its sensitivity to dynamic background noise. Traditionally, in the field of astronomy, static background subtraction based on a median image technique has been used to extract moving space objects prior to the tracking operation, as this is computationally efficient. The main disadvantage of this technique is that it is not robust to variable illumination conditions. In this article, we propose an approach for tracking small and dim space debris in the context of a dynamic background via one of the optical telescopes that is part of the space surveillance network project, named the Asia-Pacific ground-based Optical Space Observation System or APOSOS. The approach combines a fuzzy running Gaussian average for robust moving-object extraction with dim-target tracking using a particle-filter-based track-before-detect method. The performance of the proposed algorithm is experimentally evaluated, and the results show that the scheme achieves a satisfactory level of accuracy for space debris tracking.

  19. Kinetic energy density and agglomerate abrasion rate during blending of agglomerates into powders.

    PubMed

    Willemsz, Tofan A; Hooijmaijers, Ricardo; Rubingh, Carina M; Tran, Thanh N; Frijlink, Henderik W; Vromans, Herman; van der Voort Maarschalk, Kees

    2012-01-23

    Problems related to the blending of a cohesive powder with a free flowing bulk powder are frequently encountered in the pharmaceutical industry. The cohesive powder often forms lumps or agglomerates which are not dispersed during the mixing process and are therefore detrimental to blend uniformity. Achieving sufficient blend uniformity requires that the blending conditions are able to break up agglomerates, which is often an abrasion process. This study was based on the assumption that the abrasion rate of agglomerates determines the required blending time. It is shown that the kinetic energy density of the moving powder bed is a relevant parameter which correlates with the abrasion rate of agglomerates. However, aspects related to the strength of agglomerates should also be considered. For this reason the Stokes abrasion number (St(Abr)) has been defined. This parameter describes the ratio between the kinetic energy density of the moving powder bed and the work of fracture of the agglomerate. The St(Abr) number is shown to predict the abrasion potential of agglomerates in the dry-mixing process. It appeared possible to include effects of filler particle size and impeller rotational rate into this concept. A clear relationship between abrasion rate of agglomerates and the value of St(Abr) was demonstrated.

  20. Influence of stability and mechanical properties of a spinal fixation device on production of wear debris particles in vivo.

    PubMed

    Mochida, Y; Bauer, T W; Nitto, H; Kambic, H E; Muschler, G F

    2000-01-01

    A prospective and quantitative animal study was performed to evaluate the production of wear particles from a spinal fixation device, and to test the hypothesis that the concentration of wear debris particles adjacent to spinal fixation hardware is correlated with the stiffness of the spinal fusion construct and local bone formation at the fusion site. An established canine segmental spinal fusion model with three interfacet fusions was used in this study. Several bone substitute materials were grafted to the area of the interfacet fusion. Internal fixation was performed on both sides of the spinous processes at each site using a stainless steel plate system in 19 dogs. After 12 weeks, spinal segments were excised, then 3-dimensional computerized tomography was used to measure bone volume and bone area of the individual fusion sites. The stiffness of each segment was tested using a servohydraulic materials testing machine. Biopsies were obtained from the soft tissues immediately around the plate system, and wear particles were collected and characterized using an electrical resistance particle analyzer, light and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX). Biopsies from para-spinal tissue from adjacent, unoperated spinal levels served as negative controls. Histologically, 24 of 57 specimens (42.1%) showed only fibrous tissue with no recognizable macrophages, inflammation, or debris. Fourteen of 57 specimens (24.6%), however, contained many particles that were composed of Fe, Cr, and Ni, corresponding to elements found in the fixation hardware. Another 19 specimens showed only occasional particles. The mean concentration of particles from the tissue around the plate system was 2.8 x 10(9) per gram dry tissue weight, compared to 0.5 x 10(9) particles per gram for controls (p < 0.05). Statistical analyses showed significant inverse correlation between the log particle number and stiffness (r = -0.41, p < 0.01), bone volume (r

  1. Video monitoring in the Gadria debris flow catchment: preliminary results of large scale particle image velocimetry (LSPIV)

    NASA Astrophysics Data System (ADS)

    Theule, Joshua; Crema, Stefano; Comiti, Francesco; Cavalli, Marco; Marchi, Lorenzo

    2015-04-01

    Large scale particle image velocimetry (LSPIV) is a technique mostly used in rivers to measure two dimensional velocities from high resolution images at high frame rates. This technique still needs to be thoroughly explored in the field of debris flow studies. The Gadria debris flow monitoring catchment in Val Venosta (Italian Alps) has been equipped with four MOBOTIX M12 video cameras. Two cameras are located in a sediment trap located close to the alluvial fan apex, one looking upstream and the other looking down and more perpendicular to the flow. The third camera is in the next reach upstream from the sediment trap at a closer proximity to the flow. These three cameras are connected to a field shelter equipped with power supply and a server collecting all the monitoring data. The fourth camera is located in an active gully, the camera is activated by a rain gauge when there is one minute of rainfall. Before LSPIV can be used, the highly distorted images need to be corrected and accurate reference points need to be made. We decided to use IMGRAFT (an opensource image georectification toolbox) which can correct distorted images using reference points and camera location, and then finally rectifies the batch of images onto a DEM grid (or the DEM grid onto the image coordinates). With the orthorectified images, we used the freeware Fudaa-LSPIV (developed by EDF, IRSTEA, and DeltaCAD Company) to generate the LSPIV calculations of the flow events. Calculated velocities can easily be checked manually because of the already orthorectified images. During the monitoring program (since 2011) we recorded three debris flow events at the sediment trap area (each with very different surge dynamics). The camera in the gully was in operation in 2014 which managed to record granular flows and rockfalls, which particle tracking may be more appropriate for velocity measurements. The four cameras allows us to explore the limitations of camera distance, angle, frame rate, and image

  2. Rapid determination of plasmonic nanoparticle agglomeration status in blood.

    PubMed

    Jenkins, Samir V; Qu, Haiou; Mudalige, Thilak; Ingle, Taylor M; Wang, Rongrong; Wang, Feng; Howard, Paul C; Chen, Jingyi; Zhang, Yongbin

    2015-05-01

    Plasmonic nanomaterials as drug delivery or bio-imaging agents are typically introduced to biological systems through intravenous administration. However, the potential for agglomeration of nanoparticles in biological systems could dramatically affect their pharmacokinetic profile and toxic potential. Development of rapid screening methods to evaluate agglomeration is urgently needed to monitor the physical nature of nanoparticles as they are introduced into blood. Here, we establish novel methods using darkfield microscopy with hyperspectral detection (hsDFM), single particle inductively-coupled plasma mass spectrometry (spICP-MS), and confocal Raman microscopy (cRM) to discriminate gold nanoparticles (AuNPs) and their agglomerates in blood. Rich information about nanoparticle agglomeration in situ is provided by hsDFM monitoring of the plasmon resonance of primary nanoparticles and their agglomerates in whole blood; cRM is an effective complement to hsDFM to detect AuNP agglomerates in minimally manipulated samples. The AuNPs and the particle agglomerates were further distinguished in blood for the first time by quantification of particle mass using spICP-MS with excellent sensitivity and specificity. Furthermore, the agglomeration status of synthesized and commercial NPs incubated in blood was successfully assessed using the developed methods. Together, these complementary methods enable rapid determination of the agglomeration status of plasmonic nanomaterials in biological systems, specifically blood.

  3. Rapid Determination of Plasmonic Nanoparticle Agglomeration Status in Blood

    PubMed Central

    Jenkins, Samir V.; Qu, Haiou; Mudalige, Thilak; Ingle, Taylor; Wang, RongRong; Wang, Feng; Howard, Paul C.; Chen, Jingyi; Zhang, Yongbin

    2015-01-01

    Plasmonic nanomaterials as drug delivery or bio-imaging agents are typically introduced to biological systems through intravenous administration. However, the potential for agglomeration of nanoparticles in biological systems could dramatically affect their pharmacokinetic profile and toxic potential. Development of rapid screening methods to evaluate agglomeration is urgently needed to monitor the physical nature of nanoparticles as they are introduced into blood. Here, we establish novel methods using darkfield microscopy with hyperspectral detection (hsDFM), single particle inductively-coupled plasma mass spectrometry (spICP-MS), and confocal Raman microscopy (cRM) to discriminate gold nanoparticles (AuNPs) and their agglomerates in blood. Rich information about nanoparticle agglomeration in situ is provided by hsDFM monitoring of the plasmon resonance of primary nanoparticles and their agglomerates in whole blood; cRM is an effective complement to hsDFM to detect AuNP agglomerates in minimally manipulated samples. The AuNPs and the particle agglomerates were further distinguished in blood for the first time by quantification of particle mass using spICP-MS with excellent sensitivity and specificity. Furthermore, the agglomeration status of synthesized and commercial NPs incubated in blood was successfully assessed using the developed methods. Together, these complementary methods enable rapid determination of the agglomeration status of plasmonic nanomaterials in biological systems, specifically blood. PMID:25771013

  4. Modeling of crushed ore agglomeration for heap leach operations

    NASA Astrophysics Data System (ADS)

    Dhawan, Nikhil

    The focus of this dissertation is modeling of the evolution of size distribution in batch agglomeration drum. There has been no successful work on modeling of crushed ore agglomeration although the framework for population balance modeling of pelletization and granulation is readily available. In this study three different batch agglomeration drums were used to study the agglomeration kinetics of copper, gold and nickel ores. The agglomerate size distribution is inherently subject to random fluctuation due the very nature of the process. Yet, with careful experimentation and size analysis the evolution of size distribution can be followed. The population balance model employing the random coalesce model with a constant rate kernel was shown to work well in a micro and lab scale agglomerator experiments. In small drums agglomerates begin to break in a short time, whereas the growth is uniform in the lab scale drum. The experimental agglomerate size distributions exhibit self-preserving size spectra which confirms the applicability of coalescence rate based model. The same spectra became a useful fact for predicting the size distribution with an empirical model. Since moisture is a principal variable, the absolute deviation from optimum moisture was used as the primary variable in the empirical model. Having established a model for the size distribution, the next step was to delve into the internal constituents of each agglomerate size class. To this end, an experimental scheme known as dip test was devised. The outcome of the test was the size distribution of progeny particles which make up a given size class of agglomerate. The progeny size distribution was analyzed with a model that partitions the particles into a host and guest category. The ensuing partition coefficient is a valuable in determining how a particle in a size class participates in larger agglomerates. This dissertation lays out the fundamentals for applying the population balance concept to batch

  5. Frequency comparative study of coal-fired fly ash acoustic agglomeration.

    PubMed

    Liu, Jianzhong; Wang, Jie; Zhang, Guangxue; Zhou, Junhu; Cen, Kefa

    2011-01-01

    Particulate pollution is main kind of atmospheric pollution. The fine particles are seriously harmful to human health and environment. Acoustic agglomeration is considered as a promising pretreatment technology for fine particle agglomeration. The mechanisms of acoustic agglomeration are very complex and the agglomeration efficiency is affected by many factors. The most important and controversial factor is frequency. Comparative studies between high-frequency and low-frequency sound source to agglomerate coal-fired fly ash were carried out to investigate the influence of frequency on agglomeration efficiency. Acoustic agglomeration theoretical analysis, experimental particle size distributions (PSDs) and orthogonal design were examined. The results showed that the 20 kHz high-frequency sound source was not suitable to agglomerate coal-fired fly ash. Only within the size ranging from 0.2 to 0.25 microm the particles agglomerated to adhere together, and the agglomerated particles were smaller than 2.5 microm. The application of low-frequency (1000-1800 Hz) sound source was proved as an advisable pretreatment with the highest agglomeration efficiency of 75.3%, and all the number concentrations within the measuring range decreased. Orthogonal design L16 (4)3 was introduced to determine the optimum frequency and optimize acoustic agglomeration condition. According to the results of orthogonal analysis, frequency was the dominant factor of coal-fired fly ash acoustic agglomeration and the optimum frequency was 1400 Hz.

  6. Analysis and synthesis of solutions for the agglomeration process modeling

    NASA Astrophysics Data System (ADS)

    Babuk, V. A.; Dolotkazin, I. N.; Nizyaev, A. A.

    2013-03-01

    The present work is devoted development of model of agglomerating process for propellants based on ammonium perchlorate (AP), ammonium dinitramide (ADN), HMX, inactive binder, and nanoaluminum. Generalization of experimental data, development of physical picture of agglomeration for listed propellants, development and analysis of mathematical models are carried out. Synthesis of models of various phenomena taking place at agglomeration implementation allows predicting of size and quantity, chemical composition, structure of forming agglomerates and its fraction in set of condensed combustion products. It became possible in many respects due to development of new model of agglomerating particle evolution on the surface of burning propellant. Obtained results correspond to available experimental data. It is supposed that analogical method based on analysis of mathematical models of particular phenomena and their synthesis will allow implementing of the agglomerating process modeling for other types of metalized solid propellants.

  7. The orbital characteristics of debris particle rings as derived from IDE observations of multiple orbit intersections with LDEF

    NASA Technical Reports Server (NTRS)

    Cooke, William J.; Oliver, John P.; Simon, Charles G.

    1995-01-01

    During the first 346 days of the LDEF's almost 6 year stay in space, the metal oxide silicon detectors of the Interplanetary Dust Experiment (IDE) recorded over 15,000 impacts, most of which were separated in time by integer multiples of the LDEF orbital period (called multiple orbit event sequences, or MOES). Simple celestial mechanics provides ample reason to expect that a good deal of information about the orbits of the impacting debris particles can be extracted from these MOES, and so a procedure, based on the work of Greenberg, has been developed and applied to one of these events, the so-called 'May swarm'. This technique, the 'Method of Differential Precession,' allows for the determination of the geometrical elements of a particle orbit from the change in the position of the impact point with time. The application of this approach to the May swarm gave the following orbital elements for the orbit of the particles striking LDEF during this MOES: a = 6746.5 km; 0.0165 less than e less than 0.025; i = 66.55 deg; Omega(sub 0) = 179.0 deg plus or minus 0.2 deg; omega = 178.1 deg plus or minus 0.2 deg.

  8. The orbital characteristics of debris particle rings as derived from IDE observations of multiple orbit intersections with LDEF

    SciTech Connect

    Cooke, W.J.; Oliver, J.P.; Simon, C.G.

    1995-02-01

    During the first 346 days of the LDEF`s almost 6 year stay in space, the metal oxide silicon detectors of the Interplanetary Dust Experiment (IDE) recorded over 15,000 impacts, most of which were separated in time by integer multiples of the LDEF orbital period (called multiple orbit event sequences, or MOES). Simple celestial mechanics provides ample reason to expect that a good deal of information about the orbits of the impacting debris particles can be extracted from these MOES, and so a procedure, based on the work of Greenberg, has been developed and applied to one of these events, the so-called `May swarm`. This technique, the `Method of Differential Precession,` allows for the determination of the geometrical elements of a particle orbit from the change in the position of the impact point with time. The application of this approach to the May swarm gave the following orbital elements for the orbit of the particles striking LDEF during this MOES: a = 6746.5 km; 0.0165 less than e less than 0.025; i = 66.55 deg; Omega(sub 0) = 179.0 deg plus or minus 0.2 deg; omega = 178.1 deg plus or minus 0.2 deg.

  9. The influence of third-body particles on wear rate in unicondylar knee arthroplasty: a wear simulator study with bone and cement debris.

    PubMed

    Schroeder, Christian; Grupp, Thomas M; Fritz, Bernhard; Schilling, Christoph; Chevalier, Yan; Utzschneider, Sandra; Jansson, Volkmar

    2013-05-01

    The reduced intraoperative visibility of minimally invasive implanted unicondylar knee arthroplasty makes it difficult to remove bone and cement debris, which have been reported on the surface of damaged and retrieved bearings. Therefore, the aim of this study was to analyze the influence of bone and cement particles on the wear rate of unicompartmental knee prostheses in vitro. Fixed bearing unicompartmental knee prostheses were tested using a knee-wear-simulator according to the ISO standard 14243-1:2002(E) for 5.0 million cycles. Afterwards bone debris (particle size 671 ± 262 μm) were added to the test fluid in a concentration of 5 g/l for 1.5 million cycles, followed by 1.5 million cycles blended with cement debris (particle size 644 ± 186 μm) in the same concentration. Wear rate, knee-kinematics and wear-pattern were analyzed. The wear rate reached 12.5 ± 1.0 mm³/million cycles in the running-in and decreased during the steady state phase to 4.4 ± 0.91 mm³/million cycles. Bone particles resulted in a wear rate of 3.0 ± 1.27 mm³/million cycles with no influence on the wear rate compared to the steady state phase. Cement particles, however, lead to a significantly higher wear rate (25.0 ± 16.93 mm³/million cycles) compared to the steady state phase. The careful removal of extruded cement debris during implantation may help in reducing wear rate. Bone debris are suggested to have less critical influence on the prostheses wear rate.

  10. Agglomeration and Sedimentation of MWCNTS in Chloroform

    NASA Astrophysics Data System (ADS)

    Eremin, Yu. S.; Kolesnikova, A. A.; Grekhov, A. M.

    The kinetics of agglomeration of multiwalled carbon nanotubes dispersed in chloroform has been studied by the methods of optical spectroscopy and dynamic light scattering. With the use of the models of the diffusion of cylindrical particles, the sizes of particles obtained by this method can be recalculated to the DLS data and the concentration at which the dispersion of individual МWCNTs occurs can be determined.

  11. An LDEF 2 dust instrument for discrimination between orbital debris and natural particles in near-Earth space

    NASA Technical Reports Server (NTRS)

    Tuzzolino, A. J.; Simpson, J. A.; Mckibben, R. B.; Voss, H. D.; Gursky, H.

    1993-01-01

    The characteristics of a space dust instrument which would be ideally suited to carry out near-Earth dust measurements on a possible Long Duraction Exposure Facility reflight mission (LDEF 2) is discussed. As a model for the trajectory portion of the instrument proposed for LDEF 2, the characteristics of a SPAce DUSt instrument (SPADUS) currently under development for flight on the USA ARGOS mission to measure the flux, mass, velocity, and trajectory of near-Earth dust is summarized. Since natural (cosmic) dust and man-made dust particles (orbital debris) have different velocity and trajectory distributions, they are distinguished by means of the SPADUS velocity/trajectory information. The SPADUS measurements will cover the dust mass range approximately 5 x 10(exp -12) g (2 microns diameter) to approximately 1 x 10(exp -5) g (200 microns diameter), with an expected mean error in particle trajectory of approximately 7 deg (isotropic flux). Arrays of capture cell devices positioned behind the trajectory instrumentation would provide for Earth-based chemical and isotopic analysis of captured dust. The SPADUS measurement principles, characteristics, its role in the ARGOS mission, and its application to an LDEF 2 mission are summarized.

  12. Influence of excipients and processing conditions on the development of agglomerates of racecadotril by crystallo-co-agglomeration

    PubMed Central

    Garala, Kevin; Patel, Jaydeep; Patel, Anjali; Raval, Mihir; Dharamsi, Abhay

    2012-01-01

    Purpose: The purpose of the present investigation was to improve the flow and mechanical properties of racecadotril by a crystallo-co-agglomeration (CCA) technique. Direct tableting is a requirement of pharmaceutical industries. Poor mechanical properties of crystalline drug particles require wet granulation which is uneconomical, laborious, and tedious. Materials and Methods: The objective of this work was to study the influence of various polymers/excipients and processing conditions on the formation of directly compressible agglomerates of the water-insoluble drug, racecadotril, an antidiarrheal agent. The agglomerates of racecadotril were prepared using dichloromethane (DCM)–water as the crystallization system. DCM acted as a good solvent for racecadotril as well as a bridging liquid for the agglomeration of the crystallized drug and water as the nonsolvent. The prepared agglomerates were tested for micromeritic and mechanical properties. Results: The process yielded ~90 to 96% wt/ wt spherical agglomerates containing racecadotril with the diameter between 299 and 521 μ. A higher rotational speed of crystallization system reduces the size of the agglomerates and disturbs the sphericity. Spherical agglomerates were generated with a uniform dispersion of the crystallized drug. CCA showed excellent flowability and crushing strength. Conclusion: Excipients and processing conditions can play a key role in preparing spherical agglomerates of racecadotril by CCA, an excellent alternative to the wet granulation process to prepare intermediates for direct compression. PMID:23580935

  13. In vitro dosimetry of agglomerates

    NASA Astrophysics Data System (ADS)

    Hirsch, V.; Kinnear, C.; Rodriguez-Lorenzo, L.; Monnier, C. A.; Rothen-Rutishauser, B.; Balog, S.; Petri-Fink, A.

    2014-06-01

    Agglomeration of nanoparticles in biological fluids is a pervasive phenomenon that leads to difficulty in the interpretation of results from in vitro exposure, primarily due to differing particokinetics of agglomerates to nanoparticles. Therefore, well-defined small agglomerates were designed that possessed different particokinetic profiles, and their cellular uptake was compared to a computational model of dosimetry. The approach used here paves the way for a better understanding of the impact of agglomeration on the nanoparticle-cell interaction.Agglomeration of nanoparticles in biological fluids is a pervasive phenomenon that leads to difficulty in the interpretation of results from in vitro exposure, primarily due to differing particokinetics of agglomerates to nanoparticles. Therefore, well-defined small agglomerates were designed that possessed different particokinetic profiles, and their cellular uptake was compared to a computational model of dosimetry. The approach used here paves the way for a better understanding of the impact of agglomeration on the nanoparticle-cell interaction. Electronic supplementary information (ESI) available: ITC data for tiopronin/Au-NP interactions, agglomeration kinetics at different pHs for tiopronin-coated Au-NPs, UV-Vis spectra in water, PBS and DMEM and temporal correlation functions for single Au-NPs and corresponding agglomerates, calculation of diffusion and sedimentation parameters, modelling of relative cell uptake based on the ISDD model and cytotoxicity of single Au-NPs and their agglomerates, and synthesis and cell uptake of large spherical Au-NPs. See DOI: 10.1039/c4nr00460d

  14. Percolative fragmentation and spontaneous agglomeration

    SciTech Connect

    Hurt, R.; Davis, K.

    1999-03-01

    Captive particle imaging experiments were performed on over 200 coal and char particles in the pulverized size range from four coals of various rank at oxygen concentration from 3--19 mol% and at gas temperatures of about 1250 K. Despite wide variations in single-particle behavior, the data set reveals two clear trends that provide new information on the nature of char combustion. First, the low-rank coal chars are observed to maintain their high reactivity through the late stages of combustion, thus avoiding the near-extinction events and long burnout tails observed for bituminous coal chars. Secondly, percolative fragmentation in the late stages of combustion is a rare event under these conditions. Some particles reach a percolation threshold rate in combustion, but typically undergo spontaneous agglomeration rather than liberation of the incipient fragments. It is concluded that percolative fragmentation behavior in the pulverized size range is determined not only by solid-phase connectivity, but also by a real competition between disruptive and cohesive forces present at the time of formation of the colloidal-sized incipient fragments.

  15. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; K. A. Lewandowski; J. A. Gurtler

    2006-09-30

    Heap leaching is one of the methods being used to recover metal from low grade ore deposits. The main problem faced during heap leaching is the migration of fine grained particles through the heap, forming impermeable beds which result in poor solution flow. The poor solution flow leads to less contact between the leach solution and the ore, resulting in low recovery rates. Agglomeration of ore into coarse, porous masses prevents fine particles from migrating and clogging the spaces and channels between the larger ore particles. Currently, there is one facility in the United States which uses agglomeration. This operation agglomerates their ore using leach solution (raffinate), but is still experiencing undesirable metal recovery from the heaps due to agglomerate breakdown. The use of a binder, in addition to the leach solution, during agglomeration would help to produce stronger agglomerates that did not break down during processing. However, there are no known binders that will work satisfactorily in the acidic environment of a heap, at a reasonable cost. As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. Increasing copper recovery in heap leaching by the use of binders and agglomeration would result in a significant decrease in the amount of energy consumed. Assuming that 70% of all the leaching heaps would convert to using agglomeration technology, as much as 1.64*10{sup 12} BTU per year would be able to be saved if a 25% increase in copper recovery was experienced, which is equivalent to saving approximately 18% of the energy currently being used in leaching heaps. For every week a leach cycle was decreased, a savings of as much as 1.23*10{sup 11} BTU per week would result. This project has identified several acid-resistant binders and agglomeration procedures. These binders and experimental procedures will be able to be used for use in improving the energy efficiency of

  16. Research approach and first results on agglomerate compaction in protoplanetary dust simulation in the Cloud Manipulation System

    NASA Astrophysics Data System (ADS)

    Vedernikov, Andrei; Blum, Jurgen; Ingo Von Borstel, Olaf; Schraepler, Rainer; Balapanov, Daniyar; Cecere, Anselmo

    2016-07-01

    Nanometre and micrometre-sized solid particles are ubiquitous in space and on Earth - from galaxies, interstellar space, protoplanetary and debris disks to planetary rings and atmospheres, planetary surfaces, comets, interplanetary space, Earth's atmosphere. Apparently, the most intriguing problem in the picture of the formation of planets is the transition from individual microscopic dust grains to kilometre-sized planetesimals. Revealing the mechanisms of this transition is one of the main tasks of the European Space Agency's project Interaction in Cosmic and Atmospheric Particle Systems (ICAPS). It was found that Brownian motion driven agglomeration could not provide the transition within reasonable time scale. As a result, at this stage top scientific goals shifted towards forced agglomeration and concentration of particles, targeting revealing the onset of compaction, experimental study of the evolution of fractal dimensions, size and mass distribution, occurrence of bouncing. The main tasks comprise 1) development of the rapid agglomeration model 2) development of the experimental facilities creating big fractal-type agglomerates from 10 to 1000 μm from a cloud of micrometre-size grains; 3) experimental realization of the rapid agglomeration in microgravity and ground conditions; and 4) in situ investigation of the morphology, mobility, mechanical and optical properties of the free-floating agglomerates, including investigation of thermophoresis, photophoresis of the agglomerates and of the two-phase flow phenomena. To solve the experimental part of the tasks we developed a Cloud Manipulation System, realized as a breadboard (CMS BB) for long duration microgravity platforms and a simplified laboratory version (CMS LV) mostly oriented on short duration microgravity and ground tests. The new system is based on the use of thermophoresis, most favourable for cloud manipulation without creating additional particle-particle forces in the cloud with a possibility

  17. Sem Analysis of particles from the 28, 000 B.P El Zaguan debris avalanche deposit, Nevado de Toluca volcano, Central Mexico: evidences of flow behavior during emplacement

    NASA Astrophysics Data System (ADS)

    Caballero, L.; Capra, L.

    2008-12-01

    The Zaguan deposit originated at 28, 000 yr. B.P from the flank collapse of the Nevado de Toluca volcano, a dacitic stratovolcano of the Transmexican Volcanic Belt. A Scanning Electron Microprobe analysis (SEM) was made to some clasts of this deposit to observe microtextures produced during transport and emplacement of the debris avalanche flow. Particles from 2, 0 and -2 Φ granulometric classes were randomly selected and their surface textures were described. The textures observed were divided in two groups, collision and shear structures indicating different clast interaction. Shear textures were observed predominantly on the basal part of the deposit and consisted of parallel ridges, parallel grooves, scratches and lips. Collision textures were mainly present in the upper part of the deposit and consisted of fractures, percussion marks, and broken or grinded crystals. These characteristics, coupled with field observation, like the presence of clast dikes and deformed lacustrine megaclasts, indicate that the basal part of the debris avalanche was moving in a partially liquefied state, were particles were not able to move freely because of the confinement exerted by the upper part of the flow, so shear stresses dominated. On the contrary, the particles in the upper part were able to move freely so the principal mechanism of interaction between particles was collision. These microscopic textures are in agreement with previously described behavior of emplacement of debris avalanches of volcanic origin, that suggest a stratified flow dominated by different transport and depositional mechanism depending on flow depth and possible fluid content at their base.

  18. Development of a Gas-Promoted Oil Agglomeration Process

    SciTech Connect

    M. Shen; T. D. Wheelock

    1998-10-30

    Further agglomeration tests were conducted in a series of tests designed to determine the effects of various parameters on the size and structure of the agglomerates formed, the rate of agglomeration, coal recovery, and ash rejection. For this series of tests, finely ground Pittsburgh No. 8 coal has been agglomerated with i-octane in a closed mixing system with a controlled amount of air present to promote particle agglomeration. The present results provide further evidence of the role played by air. As the concentration of air in the system was increased from 4.5 to 18 v/w% based on the weight of coal, coal recovery and ash rejection both increased. The results also show that coal recovery and ash rejection were improved by increasing agitator speed. On the other hand, coal recovery was not affected by a change in solids concentration from 20 to 30 w/w%.

  19. Selective oil agglomeration of lignite

    SciTech Connect

    Halime Abakay Temel; Volkan Bozkurt; Arun Kumar Majumder

    2009-01-15

    In this study, desulfurization and deashing of Adiyaman-Glbai lignite by the agglomeration method were studied. For this purpose, three groups of agglomeration experiments were made. The effects of solid concentration, bridging liquid type and dosage, pH, and screen size on the agglomeration after desliming were investigated in the first group of experiments. The effects of lake water and sea water (the Mediterranean Sea water, the Aegean Sea water, and the Black Sea water) on the agglomeration were investigated in the second group of experiments. The effects of different salts (NaCl, MgCl{sub 2}, and FeCl{sub 3}) on the agglomeration were investigated in the third group of experiments. Agglomeration results showed that the usage of sea waters and soda lake water in the agglomeration medium had a positive effect on the reduction of total sulfur content of agglomerates. In addition, the usage of NaCl, MgCl{sub 2}, and FeCl{sub 3} in the agglomeration medium had a positive effect on the ash content reduction of the agglomerates. 27 refs., 10 figs., 6 tabs.

  20. Magnetic agglomeration method for size control in the synthesis of magnetic nanoparticles

    DOEpatents

    Huber, Dale L.

    2011-07-05

    A method for controlling the size of chemically synthesized magnetic nanoparticles that employs magnetic interaction between particles to control particle size and does not rely on conventional kinetic control of the reaction to control particle size. The particles are caused to reversibly agglomerate and precipitate from solution; the size at which this occurs can be well controlled to provide a very narrow particle size distribution. The size of particles is controllable by the size of the surfactant employed in the process; controlling the size of the surfactant allows magnetic control of the agglomeration and precipitation processes. Agglomeration is used to effectively stop particle growth to provide a very narrow range of particle sizes.

  1. Textural analysis of particles from El Zaguán debris avalanche deposit, Nevado de Toluca volcano, Mexico: Evidence of flow behavior during emplacement

    NASA Astrophysics Data System (ADS)

    Caballero, Lizeth; Capra, Lucia

    2011-02-01

    El Zaguán deposit originated at 28,000 yrs. B.P. from the flank collapse of Nevado de Toluca, a dacitic stratovolcano of the Transmexican Volcanic Belt. Scanning Electron Microprobe analyses (SEM) were performed on some particles from this deposit to observe microtextures produced during transport and emplacement of the debris avalanche flow. Particles from 2ϕ (250 μm), 0ϕ (1 mm) and - 2ϕ (4 mm) granulometric classes were randomly selected at different outcrops, and their surface textures were described. The observed textures are divided in two groups, Basal and Upper textures, each one indicating different clast interactions. Basal textures are observed predominantly in the lower part of the deposit and consist of parallel ridges, parallel grooves, scratches and lips. Upper textures are mainly present in the upper part of the deposit and consisted of fractures, percussion marks, and broken or grinded crystals. These characteristics, coupled with field observations such as the presence of clastic dikes and deformed lacustrine mega-blocks, indicate that the basal part of the debris avalanche was moving in a partially liquefied state. By contrast, the particles in the upper part were able to move freely, interacting by collision. These microscopic textures are in agreement with previously described emplacement behaviors in debris avalanches of volcanic origin, suggesting a stratified flow dominated by different transport and depositional mechanisms depending upon flow depth and possible fluid content at their base.

  2. THE PHYSICS OF PROTOPLANETESIMAL DUST AGGLOMERATES. VII. THE LOW-VELOCITY COLLISION BEHAVIOR OF LARGE DUST AGGLOMERATES

    SciTech Connect

    Schraepler, Rainer; Blum, Juergen; Seizinger, Alexander; Kley, Wilhelm

    2012-10-10

    We performed micro-gravity collision experiments in our laboratory drop tower using 5 cm sized dust agglomerates with volume filling factors of 0.3 and 0.4, respectively. This work is an extension of our previous experiments reported in Beitz et al. to aggregates of more than one order of magnitude higher masses. The dust aggregates consisted of micrometer-sized silica particles and were macroscopically homogeneous. We measured the coefficient of restitution for collision velocities ranging from 1 cm s{sup -1} to 0.5 m s{sup -1}, and determined the fragmentation velocity. For low velocities, the coefficient of restitution decreases with increasing impact velocity, in contrast to findings by Beitz et al. At higher velocities, the value of the coefficient of restitution becomes constant, before the aggregates break at the onset of fragmentation. We interpret the qualitative change in the coefficient of restitution as the transition from a solid-body-dominated to a granular-medium-dominated behavior. We complement our experiments by molecular-dynamics simulations of porous aggregates and obtain a reasonable match to the experimental data. We discuss the importance of our experiments for protoplanetary disks, debris disks, and planetary rings. This work is an extension to the previous work of our group and gives new insight into the velocity dependency of the coefficient of restitution due to improved measurements, better statistics, and a theoretical approach.

  3. Preliminary characterization of a gas-promoted oil agglomeration process

    SciTech Connect

    Drzymala, J.; Wheelock, T.D.

    1996-12-31

    The agglomeration of aqueous suspensions of Pittsburgh No. 8 coal particles with i-octane was studied by employing a scale model mixing system which measured both agitator speed and torque. The progress of agglomeration was monitored by observing changes in agitator torque and was confirmed by examining samples of the suspension with an optical microscope. When a suspension containing 30 w/w% solids was degassed and then conditioned with 20 v/w% i-octane (20 ml i-octane/100 g coal), no agglomeration took place until a small amount of air (e.g., 9 v/w%) was introduced. Subsequent changes in agitator torque indicated that the ensuing process of agglomeration was complex and consisted of several stages involving various interactions between coal particles, oil drops, and gas bubbles. The time required to produce spherical agglomerates was determined for different experimental conditions by conducting a number of agglomeration tests involving different mixing tank sizes and different impeller sizes and speeds. The results indicate that agglomeration time decreases with increasing power input per unit volume and increasing gas concentration.

  4. Using Concatenated Profiles from High-Speed Laser Profile Scanners to Estimate Debris-Flow Characteristics: A Novel Approach Based on Particle Image Velocimetry

    NASA Astrophysics Data System (ADS)

    Jacquemart, M. F.; Meier, L.; Graf, C.; Morsdorf, F.

    2015-12-01

    We use globally unique datasets from paired laser profile scanners to measure debris-flow height, velocity and discharge in two well-known debris-flow channels in Switzerland. Since 2011, these scanners have been scanning passing debris flows at rates of up to 75 Hz, acquiring millions of cross-bed profiles. The profiles can be concatenated through time, generating unique 2.5D representations of passing debris flows. Applying a large-scale Particle Image Velocimetry (PIV) approach to these datasets has proven successful to measure surface flow velocities. Flow height can also be estimated from the laser scanners, and thus a discharge estimate can be given. To account for changes to the channel bed due to erosion and deposition during the debris flow, we compute two flow height estimates using a pre-event as well as a post-event channel geometry in order to visualize discharge variability.Velocity outliers need to be excluded to provide reliable estimates of peak discharge, and changes to the channel bed are assumed to be the largest source of uncertainty. However, the latter problem is inherent to all debris-flow discharge measurements, and we have found the new system to offer distinct advantages over the conventional system relying on geophones and a radar gauge. The wide scan angle of up to 190° renders the scanners insensitive to changes of the flow path, and the point density of roughly 20 points per meter offer unprecedented spatial coverage.In addition, the geometries of the cross-bed profiles have been analyzed, revealing distinct changes of cross-flow convexity between the front and the tail of the flows in several cases. This is assumed to indicate changes of debris-flow mixtures, but further research is needed to better understand this signal.We hope that our preliminary analysis and toolbox will facilitate working with these kinds of datasets so as to further improve debris-flow understanding, monitoring and modeling efforts in the future.

  5. Effects of coarse grain size distribution and fine particle content on pore fluid pressure and shear behavior in experimental debris flows

    NASA Astrophysics Data System (ADS)

    Kaitna, Roland; Palucis, Marisa C.; Yohannes, Bereket; Hill, Kimberly M.; Dietrich, William E.

    2016-02-01

    Debris flows are typically a saturated mixture of poorly sorted particles and interstitial fluid, whose density and flow properties depend strongly on the presence of suspended fine sediment. Recent research suggests that grain size distribution (GSD) influences excess pore pressures (i.e., pressure in excess of predicted hydrostatic pressure), which in turn plays a governing role in debris flow behaviors. We report a series of controlled laboratory experiments in a 4 m diameter vertically rotating drum where the coarse particle size distribution and the content of fine particles were varied independently. We measured basal pore fluid pressures, pore fluid pressure profiles (using novel sensor probes), velocity profiles, and longitudinal profiles of the flow height. Excess pore fluid pressure was significant for mixtures with high fines fraction. Such flows exhibited lower values for their bulk flow resistance (as measured by surface slope of the flow), had damped fluctuations of normalized fluid pressure and normal stress, and had velocity profiles where the shear was concentrated at the base of the flow. These effects were most pronounced in flows with a wide coarse GSD distribution. Sustained excess fluid pressure occurred during flow and after cessation of motion. Various mechanisms may cause dilation and contraction of the flows, and we propose that the sustained excess fluid pressures during flow and once the flow has stopped may arise from hindered particle settling and yield strength of the fluid, resulting in transfer of particle weight to the fluid. Thus, debris flow behavior may be strongly influenced by sustained excess fluid pressures controlled by particle settling rates.

  6. Smoothed particle hydrodynamic modeling of volcanic debris flows: Application to Huiloac Gorge lahars (Popocatépetl volcano, Mexico)

    NASA Astrophysics Data System (ADS)

    Haddad, Bouchra; Palacios, David; Pastor, Manuel; Zamorano, José Juan

    2016-09-01

    Lahars are among the most catastrophic volcanic processes, and the ability to model them is central to mitigating their effects. Several lahars recently generated by the Popocatépetl volcano (Mexico) moved downstream through the Huiloac Gorge towards the village of Santiago Xalitzintla. The most dangerous was the 2001 lahar, in which the destructive power of the debris flow was maintained throughout the extent of the flow. Identifying the zone of hazard can be based either on numerical or empirical models, but a calibration and validation process is required to ensure hazard map quality. The Geoflow-SPH depth integrated numerical model used in this study to reproduce the 2001 lahar was derived from the velocity-pressure version of the Biot-Zienkiewicz model, and was discretized using the smoothed particle hydrodynamics (SPH) method. The results of the calibrated SPH model were validated by comparing the simulated deposit depth with the field depth measured at 16 cross sections distributed strategically along the gorge channel. Moreover, the dependency of the results on topographic mesh resolution, initial lahar mass shape and dimensions is also investigated. The results indicate that to accurately reproduce the 2001 lahar flow dynamics the channel topography needed to be discretized using a mesh having a minimum 5 m resolution, and an initial lahar mass shape that adopted the source area morphology. Field validation of the calibrated model showed that there was a satisfactory relationship between the simulated and field depths, the error being less than 20% for 11 of the 16 cross sections. This study demonstrates that the Geoflow-SPH model was able to accurately reproduce the lahar path and the extent of the flow, but also reproduced other parameters including flow velocity and deposit depth.

  7. DebriSat Laboratory Analyses

    DTIC Science & Technology

    2015-01-05

    foam panels. Deposits on the SEM stubs and witness plate assembly are predominantly carbon and consist of agglomerates of nano carbonaceous material...side of the support posts indicating early directional deposition from DebriSat. The coating was carbonaceous (disordered graphite) with nano metal...droplets. Fluorine from Teflon wire insulation was also common in the SEM stub and witness plates deposits. Nano droplets of metallic materials

  8. Improving the de-agglomeration and dissolution of a poorly water soluble drug by decreasing the agglomerate strength of the cohesive powder.

    PubMed

    Allahham, Ayman; Stewart, Peter J; Das, Shyamal C

    2013-11-30

    Influence of ternary, poorly water-soluble components on the agglomerate strength of cohesive indomethacin mixtures during dissolution was studied to explore the relationship between agglomerate strength and extent of de-agglomeration and dissolution of indomethacin (Ind). Dissolution profiles of Ind from 20% Ind-lactose binary mixtures, and ternary mixtures containing additional dibasic calcium phosphate (1% or 10%; DCP), calcium sulphate (10%) and talc (10%) were determined. Agglomerate strength distributions were estimated by Monte Carlo simulation of particle size, work of cohesion and packing fraction distributions. The agglomerate strength of Ind decreased from 1.19 MPa for the binary Ind mixture to 0.84 MPa for 1DCP:20Ind mixture and to 0.42 MPa for 1DCP:2Ind mixture. Both extent of de-agglomeration, demonstrated by the concentration of the dispersed indomethacin distribution, and extent of dispersion, demonstrated by the particle size of the dispersed indomethacin, were in descending order of 1DCP:2Ind>1DCP:20Ind>binary Ind. The addition of calcium sulphate dihydrate and talc also reduced the agglomerate strength and improved de-agglomeration and dispersion of indomethacin. While not definitively causal, the improved de-agglomeration and dispersion of a poorly water soluble drug by poorly water soluble components was related to the agglomerate strength of the cohesive matrix during dissolution.

  9. Albedo estimates for debris

    NASA Technical Reports Server (NTRS)

    Potter, A. E.; Henize, Karl G.; Talent, D. L.

    1989-01-01

    The albedo of upper-stage breakup debris is proposed as an accurate discriminator among the various possible causes of breakup, which encompass residual fuel explosions and hypervelocity particle impacts. The fragments from an impact are covered with a thin layer of soot deposited from the destruction of polymeric circuit boards, while pressure vessel explosion fragments can be expected to remain soot-free. Albedo also facilitates the interpretation of small-debris optical telescope measurements.

  10. SPECS: Orbital debris removal

    NASA Technical Reports Server (NTRS)

    1991-01-01

    The debris problem has reached a stage at which the risk to satellites and spacecraft has become substantial in low Earth orbit (LEO). This research discovered that small particles posed little threat to spacecraft because shielding can effectively prevent these particles from damaging the spacecraft. The research also showed that, even though collision with a large piece of debris could destroy the spacecraft, the large pieces of debris pose little danger because they can be tracked and the spacecraft can be maneuvered away from these pieces. Additionally, there are many current designs to capture and remove large debris particles from the space environment. From this analysis, it was decided to concentrate on the removal of medium-sized orbital debris, that is, those pieces ranging from 1 cm to 50 cm in size. The current design incorporates a transfer vehicle and a netting vehicle to capture the medium-sized debris. The system is based near an operational space station located at 28.5 deg inclination and 400 km altitude. The system uses ground-based tracking to determine the location of a satellite breakup or debris cloud. These data are uploaded to the transfer vehicle, which proceeds to rendezvous with the debris at a lower altitude parking orbit. Next, the netting vehicle is deployed, tracks the targeted debris, and captures it. After expending the available nets, the netting vehicle returns to the transfer vehicle for a new netting module and continues to capture more debris in the target area. Once all the netting modules are expended, the transfer vehicle returns to the space station's orbit where it is resupplied with new netting modules from a space shuttle load. The new modules are launched by the shuttle from the ground and the expended modules are taken back to Earth for removal of the captured debris, refueling, and repacking of the nets. Once the netting modules are refurbished, they are taken back into orbit for reuse. In a typical mission, the

  11. Development of a gas-promoted oil agglomeration process. Quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Wheelock, T.D.

    1995-12-31

    The preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal advanced in three major research areas. One area of research resulted in the development of a method for measuring the rate of agglomeration of dilute particle suspensions and using the method to relate the rate of agglomeration of coal particles to various key parameters. A second area of research led to the development of a method for monitoring a batch agglomeration process by measuring changes in agitator torque. With this method it was possible to show that the agglomeration of a concentrated coal particle suspension is triggered by the introduction of a small amount of gas. The method was also used in conjunction with optical microscopy to study the mechanism of agglomeration. A third area of research led to the discovery that highly hydrophobic particles in an aqueous suspension can be agglomerated by air alone.

  12. Antioxidant Impregnated Ultra-High Molecular Weight Polyethylene Wear Debris Particles Display Increased Bone Remodeling and a Superior Osteogenic:Osteolytic Profile vs. Conventional UHMWPE Particles in a Murine Calvaria Model

    PubMed Central

    Chen, Yu; Hallab, Nadim J.; Liao, Yen-Shuo; Narayan, Venkat; Schwarz, Edward M.; Xie, Chao

    2015-01-01

    Periprosthetic osteolysis remains a major limitation of long-term successful total hip replacements with ultra-high molecular weight polyethylene (UHMWPE) bearings. As intra and extracellular reactive oxygen species are know to contribute to wear debris-induced osteoclastic bone resorption and decreased osteoblastic bone formation, antioxidant doped UHMWPE has emerged as an approach to reduce the osteolytic potential of wear debris and maintain coupled bone remodeling. To test this hypothesis in vivo, we evaluated the effects of crosslinked UHMWPE wear debris particles (AltrX™), versus similar wear particles made from COVERNOX™ containing UHMWPE (AOX™), in an established murine calvaria model. Eight-week-old female C57B/6 mice (n=10/Group) received a pre-op micro-CT scan prior to surgical implantation of the UHMWPE particles (2mg), or surgery without particles (sham). Dynamic labeling was performed by intraperitoneal injection of calcein on day 7 and alizarin on day 9, and the calvaria were harvested for micro-CT and histology on day 10. Surprisingly, we found that AOX particles induced significantly more bone resorption (1.72-fold) and osteoclast numbers (1.99-fold) vs. AltrX (p<0.001). However, AOX also significantly induced 1.64-fold more new bone formation vs. AltrX (p<0.01). Moreover, while the osteolytic:osteogenic ratio of both particles was very close to 1.0, which is indicative of coupled remodeling, AOX was more osteogenic (Slope=1.13±0.10 vs. 0.97±0.10). Histomorphometry of the metabolically labeled undecalcified calvaria revealed a consistent trend of greater MAR in AOX vs. AltrX. Collectively, these results demonstrate that anti-oxidant impregnated UHMWPE particles have decreased osteolytic potential due to their increased osteogenic properties that support coupled bone remodeling. PMID:26495749

  13. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; J. A. Gurtler

    2004-03-31

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. A primary example of this is copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process. As a result, operators of acidic heap-leach facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of other agglomeration applications, particularly advanced primary ironmaking.

  14. NOVEL BINDERS AND METHODS FOR AGGLOMERATION OF ORE

    SciTech Connect

    S.K. Kawatra; T.C. Eisele; J.A. Gurtler; C.A. Hardison; K. Lewandowski

    2004-04-01

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. Primary examples of this are copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process, and advanced ironmaking processes, where binders must function satisfactorily over an extraordinarily large range of temperatures (from room temperature up to over 1200 C). As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching and advanced primary ironmaking.

  15. Micro-agglomerate flotation for deep cleaning of coal

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-04-01

    We are investigating the use of a hybrid process, Micro-agglomerate flotation, which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 [mu]m in size) rather than individual coal particles (1--10 [mu]m) the problems of froth overload and water/mineral carryover should be significantly alleviated.Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  16. Micro-agglomerate flotation for deep cleaning of coal

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-01-01

    We are investigating the use of a hybrid process - Micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 [mu]m in size) rather than individual coal particles (1--10 [mu]m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  17. Hydrophobic Agglomeration of Mineral Fines in Aqueous Suspensions and its Application in Flotation: a Review

    NASA Astrophysics Data System (ADS)

    Yang, Bingqiao; Song, Shaoxian

    2014-05-01

    Hydrophobic agglomeration is originated from the hydrophobic attraction between particles, which is essentially different from electrolyte coagulation and polymer flocculation. It is applied to mineral processing in floc-flotation process to improve the recovery of mineral fines. In this paper, the applications of this phenomenon in mineral fines were summarized, including the origin of hydrophobic agglomeration, the main factors affect hydrophobic agglomeration (particle hydrophobicity, shear rate and duration, nonpolar oil and tank geometry), as well as hydrophobic agglomeration based separation processes (carrier flotation and floc-flotation).

  18. Acoustic agglomeration of power plant fly ash. Final report

    SciTech Connect

    Reethof, G.; McDaniel, O.H.

    1982-01-01

    The work has shown that acoustic agglomeration at practical acoustic intensities and frequencies is technically and most likely economically viable. The following studies were performed with the listed results: The physics of acoustic agglomeration is complex particularly at the needed high acoustic intensities in the range of 150 to 160 dB and frequencies in the 2500 Hz range. The analytical model which we developed, although not including nonlinear acoustic efforts, agreed with the trends observed. We concentrated our efforts on clarifying the impact of high acoustic intensities on the generation of turbulence. Results from a special set of tests show that although some acoustically generated turbulence of sorts exists in the 150 to 170 dB range with acoustic streaming present, such turbulence will not be a significant factor in acoustic agglomeration compared to the dominant effect of the acoustic velocities at the fundamental frequency and its harmonics. Studies of the robustness of the agglomerated particles using the Anderson Mark III impactor as the source of the shear stresses on the particles show that the agglomerates should be able to withstand the rigors of flow through commercial cyclones without significant break-up. We designed and developed a 700/sup 0/F tubular agglomerator of 8'' internal diameter. The electrically heated system functioned well and provided very encouraging agglomeration results at acoustic levels in the 150 to 160 dB and 2000 to 3000 Hz ranges. We confirmed earlier results that an optimum frequency exists at about 2500 Hz and that larger dust loadings will give better results. Studies of the absorption of acoustic energy by various common gases as a function of temperature and humidity showed the need to pursue such an investigation for flue gas constituents in order to provide necessary data for the design of agglomerators. 65 references, 56 figures, 4 tables.

  19. Recent Advances in Agglomerated Multigrid

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.; Hammond, Dana P.

    2013-01-01

    We report recent advancements of the agglomerated multigrid methodology for complex flow simulations on fully unstructured grids. An agglomerated multigrid solver is applied to a wide range of test problems from simple two-dimensional geometries to realistic three- dimensional configurations. The solver is evaluated against a single-grid solver and, in some cases, against a structured-grid multigrid solver. Grid and solver issues are identified and overcome, leading to significant improvements over single-grid solvers.

  20. Spherical agglomerates of lactose with enhanced mechanical properties.

    PubMed

    Lamešić, Dejan; Planinšek, Odon; Lavrič, Zoran; Ilić, Ilija

    2017-01-10

    The aim of this study was to prepare spherical agglomerates of lactose and to evaluate their physicochemical properties, flow properties, particle friability and compaction properties, and to compare them to commercially available types of lactose for direct compression (spray-dried, granulated and anhydrous β-lactose). Porous spherical agglomerates of α-lactose monohydrate with radially arranged prism-like primary particles were prepared exhibiting a high specific surface area. All types of lactose analysed had passable or better flow properties, except for anhydrous β-lactose, which had poor flowability. Particle friability was more pronounced in larger granulated lactose particles; however, particle structure was retained in all samples analysed. The mechanical properties of spherical agglomerates of lactose, in terms of compressibility, established with Walker analysis, and compactibility, established with a compactibility profile, were found to be superior to any commercially available types of lactose. Higher compactibility of spherical agglomerates of lactose is ascribed to significantly higher particle surface area due to a unique internal structure with higher susceptibility to fragmentation.

  1. Coal beneficiation kinetics of a gas-promoted oil agglomeration process

    SciTech Connect

    Zhang, F.; Wheelock, T.D.

    1996-12-31

    The kinetics of a gas-promoted oil agglomeration process were investigated by monitoring the change in the turbidity of an aqueous particle suspension as the particles were agglomerated with heptane in a closed tank fitted with baffles and an agitator. Measured amounts of air and heptane were added to a suspension of Pittsburgh No. 8 coal under vigorous agitation. The subsequent rate of change of particle concentration was taken to be an indication of the rate of agglomeration. The rate was found to be proportional to the particle number concentration raised to a power and dependent on agitator speed and the amounts of air and oil added.

  2. Space Debris & its Mitigation

    NASA Astrophysics Data System (ADS)

    Kaushal, Sourabh; Arora, Nishant

    2012-07-01

    : In this technique we will use the nano tubes. We will create a mesh that will act as a touch panel of the touch screen cell phone. When any small or tiny particle will come on this mesh and touch it then the mesh will act as a touch panel and so that the corresponding processor or sensor will come to know the co-ordinates of it then further by using Destructive laser beam we can destroy that particle. B. Use of the Nano tubes and Nano Bots for the collection of the Space Debris: In this method also we will use a nano mesh which is made up of the nano tubes and the corresponding arrangement will be done so that that mesh will act as a touch panel same as that of the touch screen phones. So when tiny particles will dash on the nano mesh then the Nano Bots which will be at the specific co-ordinates collect the particles and store them into the garbage storage. C. Further the space Debris can be use for the other purposes too:- As we know that the space debris can be any tiny particle in the space. So instead of decomposing that particles or destroying it we can use those particles for the purpose of energy production by using the fuel cells, but for this the one condition is that the particle material should be capable of forming the ionize liquid or solution which can be successfully use in the fuel cell for energy production. But this is useful for only the big projects where in smallest amount of energy has also the great demand or value. D. RECYCLING OF SPACE DEBRIS The general idea of making space structures by recycling space debris is to capture the aluminum of the upper stages, melt it, and form it into new aluminum structures, perhaps by coating the inside of inflatable balloons, to make very large structures of thin aluminum shells. CONCLUSION Space debris has become the topic of great concern in recent years. Space debris creation can't be stopped completely but it can be minimized by adopting some measures. Many methods of space debris mitigation have been

  3. Novel Binders and Methods for Agglomeration of Ore

    SciTech Connect

    S. K. Kawatra; T. C. Eisele; K. A. Lewandowski; J. A. Gurtler

    2006-12-31

    Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily. Primary examples of this are copper heap leaching, where there are no binders that will work in the acidic environment encountered in this process, and advanced ironmaking processes, where binders must function satisfactorily over an extraordinarily large range of temperatures (from room temperature up to over 1200 C). As a result, operators of many facilities see a large loss of process efficiency due to their inability to take advantage of agglomeration. The large quantities of ore that must be handled in metal extraction processes also means that the binder must be inexpensive and useful at low dosages to be economical. The acid-resistant binders and agglomeration procedures developed in this project will also be adapted for use in improving the energy efficiency and performance of a broad range of mineral agglomeration applications, particularly heap leaching and advanced primary ironmaking. This project has identified several acid-resistant binders and agglomeration procedures that can be used for improving the energy efficiency of heap leaching, by preventing the ''ponding'' and ''channeling'' effects that currently cause reduced recovery and extended leaching cycle times. Methods have also been developed for iron ore processing which are intended to improve the

  4. Morphological characterization of diesel soot agglomerates based on the Beer-Lambert law

    NASA Astrophysics Data System (ADS)

    Lapuerta, Magín; Martos, Francisco J.; José Expósito, Juan

    2013-03-01

    A new method is proposed for the determination of the number of primary particles composing soot agglomerates emitted from diesel engines as well as their individual fractal dimension. The method is based on the Beer-Lambert law and it is applied to micro-photographs taken in high resolution transmission electron microscopy. Differences in the grey levels of the images lead to a more accurate estimation of the geometry of the agglomerate (in this case radius of gyration) than other methods based exclusively on the planar projections of the agglomerates. The method was validated by applying it to different images of the same agglomerate observed from different angles of incidence, and proving that the effect of the angle of incidence is minor, contrary to other methods. Finally, the comparisons with other methods showed that the size, number of primary particles and fractal dimension (the latter depending on the particle size) are usually underestimated when only planar projections of the agglomerates are considered.

  5. Antioxidant impregnated ultra-high molecular weight polyethylene wear debris particles display increased bone remodeling and a superior osteogenic:osteolytic profile vs. conventional UHMWPE particles in a murine calvaria model.

    PubMed

    Chen, Yu; Hallab, Nadim J; Liao, Yen-Shuo; Narayan, Venkat; Schwarz, Edward M; Xie, Chao

    2016-05-01

    Periprosthetic osteolysis remains a major limitation of long-term successful total hip replacements with ultra-high molecular weight polyethylene (UHMWPE) bearings. As intra and extracellular reactive oxygen species are know to contribute to wear debris-induced osteoclastic bone resorption and decreased osteoblastic bone formation, antioxidant doped UHMWPE has emerged as an approach to reduce the osteolytic potential of wear debris and maintain coupled bone remodeling. To test this hypothesis in vivo, we evaluated the effects of crosslinked UHMWPE wear debris particles (AltrX(™) ), versus similar wear particles made from COVERNOX(™) containing UHMWPE (AOX(™) ), in an established murine calvaria model. Eight-week-old female C57B/6 mice (n = 10/Group) received a pre-op micro-CT scan prior to surgical implantation of the UHMWPE particles (2mg), or surgery without particles (sham). Dynamic labeling was performed by intraperitoneal injection of calcein on day 7 and alizarin on day 9, and the calvaria were harvested for micro-CT and histology on day 10. Surprisingly, we found that AOX particles induced significantly more bone resorption (1.72-fold) and osteoclast numbers (1.99-fold) vs. AltrX (p < 0.001). However, AOX also significantly induced 1.64-fold more new bone formation vs. AltrX (p < 0.01). Moreover, while the osteolytic:osteogenic ratio of both particles was very close to 1.0, which is indicative of coupled remodeling, AOX was more osteogenic (Slope = 1.13 ± 0.10 vs. 0.97 ± 0.10). Histomorphometry of the metabolically labeled undecalcified calvaria revealed a consistent trend of greater MAR in AOX vs. AltrX. Collectively, these results demonstrate that anti-oxidant impregnated UHMWPE particles have decreased osteolytic potential due to their increased osteogenic properties that support coupled bone remodeling. © 2015 Orthopaedic Research Society. Published by Wiley Periodicals, Inc. J Orthop Res 34:845-851, 2016.

  6. Orbital Debris

    NASA Technical Reports Server (NTRS)

    Kessler, D. J. (Compiler); Su, S. Y. (Compiler)

    1985-01-01

    Earth orbital debris issues and recommended future activities are discussed. The workshop addressed the areas of environment definition, hazards to spacecraft, and space object management. It concluded that orbital debris is a potential problem for future space operations. However, before recommending any major efforts to control the environment, more data are required. The most significant required data are on the population of debris smaller than 4 cm in diameter. New damage criteria are also required. When these data are obtained, they can be combined with hypervelocity data to evaluate the hazards to future spacecraft. After these hazards are understood, then techniques to control the environment can be evaluated.

  7. Ice slurry cooling research: Storage tank ice agglomeration and extraction

    SciTech Connect

    Kasza, K.; Hayashi, Kanetoshi

    1999-08-01

    A new facility has been built to conduct research and development on important issues related to implementing ice slurry cooling technology. Ongoing studies are generating important information on the factors that influence ice particle agglomeration in ice slurry storage tanks. The studies are also addressing the development of methods to minimize and monitor agglomeration and improve the efficiency and controllability of tank extraction of slurry for distribution to cooling loads. These engineering issues impede the utilization of the ice slurry cooling concept that has been under development by various groups.

  8. Anti-oxidation treatment of ultra high molecular weight polyethylene components to decrease periprosthetic osteolysis: evaluation of osteolytic and osteogenic properties of wear debris particles in a murine calvaria model.

    PubMed

    Green, Justin M; Hallab, Nadim J; Liao, Yen-Shuo; Narayan, Venkat; Schwarz, Edward M; Xie, Chao

    2013-05-01

    Wear debris-induced osteolysis remains the greatest limitation of long-term success for total joint replacements with ultra-high molecular weight polyethylene (UHMWPE) bearings. To address oxidative degradation post-gamma irradiation, manufacturers are investigating the incorporation of antioxidants into PE resins. Similarly, larger molecular weight monomers have been developed to increase crosslinking and decrease wear debris, and ultimately osteolysis. However, the effects of modifying monomer size, crosslink density, and antioxidant incorporation on UHMWPE particle-induced osteoclastic bone resorption and coupled osteoblastic bone formation have never been tested. Here, we review the field of antioxidant-containing UHMWPE, and present an illustrative pilot study evaluating the osteolytic and osteogenic potential of wear debris generated from three chemically distinct particles (MARATHON®, XLK, and AOX™) as determined by a novel 3D micro-CT algorithm designed for the murine calvaria model. The results demonstrate an approach by which the potential osteoprotective effects of antioxidants in UHMWPE can be evaluated.

  9. Low-rank coal oil agglomeration

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.

    1991-01-01

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  10. Basic principles and mechanisms of selective oil agglomeration

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Allen, R.W.; Hu, Y.-C.; Tyson, D.; Xiaoping, Qiu; Lessa, A.

    1990-01-01

    Numerous measurements of the heat of immersion of coal were conducting using several different particle size fractions of No. 2 Gas Seam coal from Raleigh County, West Virginia. The heat of immersion was determined in water, methanol, heptane, hexadecane and neohexane (2,2-dimethybutane). A comparison of the results with those determined previously for Illinois No. 6 coal is discussed. A number of potential pyrite depressants for use in oil agglomeration of coal were screened by testing the response of sulfidized mineral pyrite to agglomeration with heptane in the presence of the potential depressant. The following were tested; sodium dithionite, sodium thiosulfate, ferrous sulfate, ferric sulfate, titanous chloride, hydrogen peroxide, Oxone (a form of potassium monopersulfate), pyrogallol, quebracho (colloidal dispersant derived from tree bark), milk whey, and several organic thiols. Ferric chloride was applied to mixtures of Upper Freeport coal and sulfidized mineral pyrite before subjecting the mixtures to agglomeration with heptane. 7 refs., 23 figs., 3 tabs.

  11. Modifying drug release and tablet properties of starch acetate tablets by dry powder agglomeration.

    PubMed

    Mäki, Riikka; Suihko, Eero; Rost, Susanne; Heiskanen, Minna; Murtomaa, Matti; Lehto, Vesa-Pekka; Ketolainen, Jarkko

    2007-02-01

    In this study three model drugs (N-acetyl-D-glucosamine (NAG), anhydrous caffeine, and propranolol hydrochloride) were agglomerated with starch acetate (SA) by mixing the binary powders on a stainless steel (SS) plate. Agglomeration was induced by triboelectrification of the particles during mixing, and it was evaluated as a method to achieve controlled drug release rate. These agglomerates, mixed with different amounts of a disintegrant, were compressed into tablets whose dissolution characteristics were determined. Triboelectric measurements showed that when the drugs were in contact with SS, charges of the opposite polarity were generated to SA (+) and caffeine and NAG (-) promoting adhesion. Instead, propranolol HCl was charged with the same polarity as SA. SEM micrographs showed that smaller caffeine particles, in spite of their larger negative charge, agglomerated less efficiently with SA than larger NAG particles. This emphasizes the importance of particle size in the agglomeration process. Propranolol HCl did not form agglomerates with SA since their particle sizes and charges were identical. As a result, agglomeration of powders prior to tablet compression allows for modification and control of the release rate of the drugs from the SA matrix tablets as well as the tensile strength of the tablets.

  12. Acoustic agglomeration of power-plant fly ash. A comprehensive semi-annual progress report

    SciTech Connect

    Reethof, G.

    1980-02-01

    Results obtained during the reporting period are presented. The agglomeration of submicron fly ash particles has been studied as a function of sound pressure level, sound frequency, loading, and exposure time. A second generation model of the agglomeration process is being developed. A high-frequency, high-intensity variable speed siren delivering at least 600 W at frequencies up to 4000 Hz has been developed and tested. Details on the design and operation are presented. The agglomeration chamber has been completely cleaned and the aerosol generating system has been rebuilt. A mathematical model of the acoustics of agglomeration is being developed. Preliminary results of computerized electron microscopic scanning of fly ash particles during agglomeration are presented. (DMC)

  13. Development of a gas-promoted oil agglomeration process. Technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect

    Wheelock, T.D.

    1995-12-01

    Several scale model mixing systems have been built and are being utilized to study the gas-promoted, oil agglomeration process for cleaning coal. Numerous batch agglomeration tests have been conducted with these systems. During an individual test the progress of agglomeration has been monitored by observing either changes in agitator torque in the case of concentrated particle suspensions or changes in turbidity in the case of dilute suspensions. A mathematical model has been developed for relating the rate of agglomeration of coal particles to the rate of change of turbidity of a dilute particle suspension undergoing agglomeration. The model has been utilized for analyzing and interpreting the results of a number of oil agglomeration tests in which several different system parameters were varied.

  14. Transport and Deposition of Welding Fume Agglomerates in a Realistic Human Nasal Airway.

    PubMed

    Tian, Lin; Inthavong, Kiao; Lidén, Göran; Shang, Yidan; Tu, Jiyuan

    2016-07-01

    Welding fume is a complex mixture containing ultra-fine particles in the nanometer range. Rather than being in the form of a singular sphere, due to the high particle concentration, welding fume particles agglomerate into long straight chains, branches, or other forms of compact shapes. Understanding the transport and deposition of these nano-agglomerates in human respiratory systems is of great interest as welding fumes are a known health hazard. The neurotoxin manganese (Mn) is a common element in welding fumes. Particulate Mn, either as soluble salts or oxides, that has deposited on the olfactory mucosa in human nasal airway is transported along the olfactory nerve to the olfactory bulb within the brain. If this Mn is further transported to the basal ganglia of the brain, it could accumulate at the part of the brain that is the focal point of its neurotoxicity. Accounting for various dynamic shape factors due to particle agglomeration, the current computational study is focused on the exposure route, the deposition pattern, and the deposition efficiency of the inhaled welding fume particles in a realistic human nasal cavity. Particular attention is given to the deposition pattern and deposition efficiency of inhaled welding fume agglomerates in the nasal olfactory region. For particles in the nanoscale, molecular diffusion is the dominant transport mechanism. Therefore, Brownian diffusion, hydrodynamic drag, Saffman lift force, and gravitational force are included in the model study. The deposition efficiencies for single spherical particles, two kinds of agglomerates of primary particles, two-dimensional planar and straight chains, are investigated for a range of primary particle sizes and a range of number of primary particles per agglomerate. A small fraction of the inhaled welding fume agglomerates is deposited on the olfactory mucosa, approximately in the range 0.1-1%, and depends on particle size and morphology. The strong size dependence of the deposition

  15. Coal beneficiation by gas agglomeration

    DOEpatents

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  16. Sonic enhanced ash agglomeration and sulfur capture. Technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-12-31

    This program will demonstrate the effectiveness of a unique approach which uses a bimodal distribution composed of large sorbent particles and fine fly ash particles to enhance ash agglomeration and sulfur capture at conditions found in direct coal-fired turbines. Under the impact of high-intensity sound waves, sorbent reactivity and utilization, it is theorized, will increase while agglomerates of fly ash and sorbents are formed which are readily collected in commercial cyclones.

  17. Agglomeration of food powder and applications.

    PubMed

    Dhanalakshmi, K; Ghosal, S; Bhattacharya, S

    2011-05-01

    Agglomeration has many applications in food processing and major applications include easy flow table salt, dispersible milk powder and soup mix, instant chocolate mix, beverage powder, compacted cubes for nutritional-intervention program, health bars using expanded/puffed cereals, etc. The main purpose of agglomeration is to improve certain physical properties of food powders such as bulk density, flowability, dispersability, and stability. Agglomerated products are easy to use by the consumers and hence are preferred over the traditional non-agglomerated products that are usually non-flowable in nature. The properties of food agglomerates and the process of agglomeration like employing pressure, extrusion, rewetting, spray-bed drying, steam jet, heat/sintering, and binders have been reviewed. The physical and instant properties of agglomerated food products have also been discussed.

  18. Hydroclimatic influence on particle size distribution of suspended sediments evacuated from debris-covered Chorabari Glacier, upper Mandakini catchment, central Himalaya

    NASA Astrophysics Data System (ADS)

    Kumar, Amit; Gokhale, Anupam Anand; Shukla, Tanuj; Dobhal, Dwarika Prasad

    2016-07-01

    Sediments released from high altitude glaciers exhibit varying evacuation patterns and transport characteristics owing to the presence of thick debris cover over the glacier. Despite the recent needs for integrated hydrometeorological studies in the Himalaya, little is known about the impacts of suspended sediment on hydropower generation, reservoir sedimentation, and abrasion of turbine components. Present study involves analysis of particle size distribution of suspended sediments to understand sediment evacuation patterns and transport characteristics in variable energy conditions during the ablation season. Peak suspended sediments were evacuated during extreme rainfall events. The estimated seasonal modern sediment erosion rate varies from 0.6 to 2.3 mm y- 1 for the study period (2009-2012). The analysis shows dominance of medium silt-sized to fine sand-sized particles having sediment size of 0.0156-0.25 mm corresponding to 70-80% without any significant seasonal variation. These transported sediments show that they are poorly sorted, coarser in nature with a nearly symmetrical to coarse skewed texture and kurtosis analysis suggesting mesokurtic distribution of sediments. The particle size fraction ranges between 4.65 and 5.23 ϕ, which is dominantly medium to coarse silty in texture. Results indicate that suspended sediments are evacuated in highly variable energy conditions through subglacial transport pathways because of increase in availability of meltwater with the progressive ablation season. Bulk geochemical characterization has been carried out to differentiate the source of suspended sediments and intensity of weathering. Chemical Index of Alterations (CIA) values of sediment flux range from 54.68 to 55.18 compared to the Upper Continental Crust (UCC) ~ 50, indicating moderate intensity of weathering. Mean seasonal (2009-2012) elemental fluxes and their contribution to the suspended sediment flux reflect that Si and Al are responsible for about 85% of

  19. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, July 1-September 30, 1996

    SciTech Connect

    Chander, S.; Hogg, R.

    1996-12-01

    The goals of this research program are to demonstrate the technical and economic feasibility of a micro-agglomerate flotation process and to establish the essential criteria for reagent selection and system design and operation. We are investigating the use of a hybrid process - Micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro- agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30-50 mm in size) rather than individual coal particles (1-10 mm) the problems of froth overload and water/mineral carryover should be significantly alleviated.

  20. Observations of debris flows at Chalk Cliffs, Colorado, USA: Part 1, in-situ measurements of flow dynamics, tracer particle movement and video imagery from the summer of 2009

    USGS Publications Warehouse

    McCoy, Scott W.; Coe, Jeffrey A.; Kean, Jason W.; Tucker, Greg E.; Staley, Dennis M.; Wasklewicz, Thad A.

    2011-01-01

    Debris flows initiated by surface-water runoff during short duration, moderate- to high-intensity rainfall are common in steep, rocky, and sparsely vegetated terrain. Yet large uncertainties remain about the potential for a flow to grow through entrainment of loose debris, which make formulation of accurate mechanical models of debris-flow routing difficult. Using a combination of in situ measurements of debris flow dynamics, video imagery, tracer rocks implanted with passive integrated transponders (PIT) and pre- and post-flow 2-cm resolution digital terrain models (terrain data presented in a companion paper by STALEY et alii, 2011), we investigated the entrainment and transport response of debris flows at Chalk Cliffs, CO, USA. Four monitored events during the summer of 2009 all initiated from surface-water runoff, generally less than an hour after the first measurable rain. Despite reach-scale morphology that remained relatively constant, the four flow events displayed a range of responses, from long-runout flows that entrained significant amounts of channel sediment and dammed the main-stem river, to smaller, short-runout flows that were primarily depositional in the upper basin. Tracer-rock travel-distance distributions for these events were bimodal; particles either remained immobile or they travelled the entire length of the catchment. The long-runout, large-entrainment flow differed from the other smaller flows by the following controlling factors: peak 10-minute rain intensity; duration of significant flow in the channel; and to a lesser extent, peak surge depth and velocity. Our growing database of natural debris-flow events can be used to develop linkages between observed debris-flow transport and entrainment responses and the controlling rainstorm characteristics and flow properties.

  1. Liquid bridge agglomeration: A fundamental approach to toner deinking

    SciTech Connect

    Snyder, B.A.; Berg, J.C. . Chemical Engineering Dept.)

    1994-05-01

    An alternative agglomeration technique for deinking toner-printed furnishes has been investigated. This technique requires only the addition of an immiscible hydrocarbon oil dispersed in water at dosages of approximately 1% by weight on fiber. The addition is made during repulping: the process appears to be effective at all temperatures of interest (23 C and 70 C are tested) and requires no surfactants or additional chemicals. The result of the oil addition is the agglomeration of the toner particles into spheres of 1 mm to 1 cm in size. These spheres contain the added oil which acts as a binder, holding the toner particles together by liquid bridges. The process is ineffective when the furnish contains highly sized fibers or starched paper, and future work seeks to address these crucial problems.

  2. Cell agglomeration in the wells of a 24-well plate using acoustic streaming.

    PubMed

    Kurashina, Yuta; Takemura, Kenjiro; Friend, James

    2017-02-28

    Cell agglomeration is essential both to the success of drug testing and to the development of tissue engineering. Here, a MHz-order acoustic wave is used to generate acoustic streaming in the wells of a 24-well plate to drive particle and cell agglomeration. Acoustic streaming is known to manipulate particles in microfluidic devices, and even provide concentration in sessile droplets, but concentration of particles or cells in individual wells has never been shown, principally due to the drag present along the periphery of the fluid in such a well. The agglomeration time for a range of particle sizes suggests that shear-induced migration plays an important role in the agglomeration process. Particles with a diameter of 45 μm agglomerated into a suspended pellet under exposure to 2.134 MHz acoustic waves at 1.5 W in 30 s. Additionally, BT-474 cells also agglomerated as adherent masses at the center bottom of the wells of tissue-culture treated 24-well plates. By switching to low cell binding 24-well plates, the BT-474 cells formed suspended agglomerations that appeared to be spheroids, fully fifteen times larger than any cell agglomerates without the acoustic streaming. In either case, the viability and proliferation of the cells were maintained despite acoustic irradiation and streaming. Intermittent excitation was effective in avoiding temperature excursions, consuming only 75 mW per well on average, presenting a convenient means to form fully three-dimensional cellular masses potentially useful for tissue, cancer, and drug research.

  3. Biological response to prosthetic debris

    PubMed Central

    Bitar, Diana; Parvizi, Javad

    2015-01-01

    Joint arthroplasty had revolutionized the outcome of orthopaedic surgery. Extensive and collaborative work of many innovator surgeons had led to the development of durable bearing surfaces, yet no single material is considered absolutely perfect. Generation of wear debris from any part of the prosthesis is unavoidable. Implant loosening secondary to osteolysis is the most common mode of failure of arthroplasty. Osteolysis is the resultant of complex contribution of the generated wear debris and the mechanical instability of the prosthetic components. Roughly speaking, all orthopedic biomaterials may induce a universal biologic host response to generated wear débris with little specific characteristics for each material; but some debris has been shown to be more cytotoxic than others. Prosthetic wear debris induces an extensive biological cascade of adverse cellular responses, where macrophages are the main cellular type involved in this hostile inflammatory process. Macrophages cause osteolysis indirectly by releasing numerous chemotactic inflammatory mediators, and directly by resorbing bone with their membrane microstructures. The bio-reactivity of wear particles depends on two major elements: particle characteristics (size, concentration and composition) and host characteristics. While any particle type may enhance hostile cellular reaction, cytological examination demonstrated that more than 70% of the debris burden is constituted of polyethylene particles. Comprehensive understanding of the intricate process of osteolysis is of utmost importance for future development of therapeutic modalities that may delay or prevent the disease progression. PMID:25793158

  4. Application of Dynamic Light Scattering to Characterize Nanoparticle Agglomeration in Alumina Nanofluids and its Effect on Thermal Conductivity

    DTIC Science & Technology

    2012-07-11

    Application of Dynamic Light Scattering to Characterize Nanoparticle Agglomeration in Alumina Nanofluids and its Effect on Thermal Conductivity Bridget...increased thermal conductivity and increased heat transfer potential. In practical applications, these particles agglomerate in nanofluid to form...aggregates, as opposed to completely dispersing in the base fluid. The resulting nanofluid has a size distribution of aggregated nanoparticles at different

  5. Segregation dynamics in debris flows

    NASA Astrophysics Data System (ADS)

    Hill, K. M.; Fei, M.

    2014-12-01

    Debris flows are massive flows consisting of mixtures of particles of different sizes and interstitial fluids such as water and mud. In sheared mixtures of different-sized (same density) particles, it is well known that larger particles tend to go up (toward the free surface), and the smaller particles, down, commonly referred to as the "Brazil-nut problem" or "kinetic sieving". When kinetic sieving fluxes are combined with advection in flows, they can give rise to a spectacular range of segregation patterns. These segregation / advection dynamics are recognized as playing a role in the coarsening of a debris flow front (its "snout") and the coarsening of the self-formed channel sides or levees. Since particle size distribution influences the flow dynamics including entrainment of bed materials, modeling segregation dynamics in debris flows is important for modeling the debris flows themselves. In sparser systems, the Brazil-nut segregation is well-modeled using kinetic theory applied to dissipative systems, where an underlying assumption involves random, uncorrelated collisions. In denser systems, where kinetic theory breaks down we have recently developed a new mixture model that demonstrates the segregation fluxes are driven by two effects associated with the kinetic stress or granular temperature (the kinetic energy associated with velocity fluctuations): (1) the difference between the partitioning of kinetic and contact stresses among the species in the mixture and (2) a kinetic stress gradient. Both model frameworks involve the temperature gradient as a driving force for segregation, but kinetic theory sends larger particles toward lower temperatures, and our mixture model sends larger particles away from lower temperatures. Which framework works under what conditions appears to depend on correlations in the flow such as those manifested in clusters and force chains. We discuss the application of each theoretical framework to representing segregation dynamics

  6. Phosphate-enhanced cytotoxicity of zinc oxide nanoparticles and agglomerates.

    PubMed

    Everett, W Neil; Chern, Christina; Sun, Dazhi; McMahon, Rebecca E; Zhang, Xi; Chen, Wei-Jung A; Hahn, Mariah S; Sue, H-J

    2014-02-10

    Zinc oxide (ZnO) nanoparticles (NPs) have been found to readily react with phosphate ions to form zinc phosphate (Zn3(PO4)2) crystallites. Because phosphates are ubiquitous in physiological fluids as well as waste water streams, it is important to examine the potential effects that the formation of Zn3(PO4)2 crystallites may have on cell viability. Thus, the cytotoxic response of NIH/3T3 fibroblast cells was assessed following 24h of exposure to ZnO NPs suspended in media with and without the standard phosphate salt supplement. Both particle dosage and size have been shown to impact the cytotoxic effects of ZnO NPs, so doses ranging from 5 to 50 μg/mL were examined and agglomerate size effects were investigated by using the bioinert amphiphilic polymer polyvinylpyrrolidone (PVP) to generate water-soluble ZnO ranging from individually dispersed 4 nm NPs up to micron-sized agglomerates. Cell metabolic activity measures indicated that the presence of phosphate in the suspension media can led to significantly reduced cell viability at all agglomerate sizes and at lower ZnO dosages. In addition, a reduction in cell viability was observed when agglomerate size was decreased, but only in the phosphate-containing media. These metabolic activity results were reflected in separate measures of cell death via the lactate dehydrogenase assay. Our results suggest that, while higher doses of water-soluble ZnO NPs are cytotoxic, the presence of phosphates in the surrounding fluid can lead to significantly elevated levels of cell death at lower ZnO NP doses. Moreover, the extent of this death can potentially be modulated or offset by tuning the agglomerate size. These findings underscore the importance of understanding how nanoscale materials can interact with the components of surrounding fluids so that potential adverse effects of such interactions can be controlled.

  7. Agglomeration and defluidization in fluidized beds due to thermally induced sintering

    SciTech Connect

    Compo, P.; Pfeffer, R.; Tardos, G.I.

    1987-01-01

    The surfaces of fluidizable particles often soften at temperatures well below the material's bulk solid melting point. When particles come into contact at elevated temperatures, there is a tendency for material bridges to form resulting in an interparticle adhesive force. This phenomenon, known as sintering, is driven by the reduction of excess surface energy and for each material is dependent on factors such as particle size and morphology, the interparticle compression force and most importantly, temperature. High temperature fluidization of cohesive powders results in agglomeration, thereby increasing the effective diameter and changing the hydrodynamic properties of the particles. If interparticle forces become significantly greater than forces generated by particle motion, defluidization will occur. In industrial practice, agglomeration is usually undesirable and must be avoided, although there are cases where controlled agglomeration is useful as in fluid-bed coal gasification where the mineral matter agglomerates and is removed from the reactor. The experimental work reported here consists of dilatometry to determine the sintering behavior of a powder as a function of temperature and high temperature fluidization in a pilot size unit to measure the minimum fluidization velocity (defluidization limit) and the voidage at minimum fluidization in the cohesive temperature range of the material. A wide variety of particles have been studied ranging from pure substances including polymers, salts and glass beads to ores and cracking catalysts obtained from industrial reactors where problematic agglomeration at high temperature fluidization was encountered.

  8. Looking inside a debris flow

    NASA Astrophysics Data System (ADS)

    Bowman, Elisabeth; Sanvitale, Nicoletta; Bird, Joshua

    2014-05-01

    Debris flows, masses of saturated, channelized, granular materials that flow at high speeds downslope, present a hazard to lives and infrastructure in regions of high relief and runoff. They also present a challenge to modelling due to the heterogeneous, multi-phase, nature of the constituent materials, with particles ranging from boulder-size to silt-size and fluid viscosity being altered by the presence of fine particles and clay. As a debris flow travels on its flow path, it will tend to segregate, with larger particles being focused to the flow front and fluid being concentrated in the tail - resulting in different rheological behaviour in time and space. It will also tend to erode and deposit material as it moves through different channel segments or reaches, with this behaviour influenced by the confinement of the channel and the angle of the slope within each reach. Flume studies offer the potential to examine in detail the behaviour of model debris flows within the penultimate and final (deposit fan area) reaches - zones which are generally of most interest in terms of human risk. Flume studies which are conducted using transparent debris offer additional benefits to more traditional methods that use opaque materials, enabling insights to the flow behaviour that are inaccessible via other physical methods. We present flume model work which has been designed to capture some essential aspects of debris flow behaviour using well graded (polydisperse) transparent debris, albeit at reduced scale. These aspects include the final deposit spread or runout increasing for a lower concentration of solids and a higher penultimate reach slope angle, and observable particle size segregation during downslope motion. We present time-varying measurements made internally and externally at a point in the channel via Plane Laser Induced Fluorescence and Particle Image Velocimetry, PIV. The measurements enable velocity distributions of the segregating flows over time to be

  9. Low-rank coal oil agglomeration

    DOEpatents

    Knudson, C.L.; Timpe, R.C.

    1991-07-16

    A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

  10. Synthesis and agglomeration of gold nanoparticles in reverse micelles

    NASA Astrophysics Data System (ADS)

    Herrera, Adriana P.; Resto, Oscar; Briano, Julio G.; Rinaldi, Carlos

    2005-07-01

    Reverse micelles prepared in the system water, sodium bis-(2-ethylhexyl) sulfoccinate (AOT), and isooctane were investigated as a templating system for the production of gold nanoparticles from Au(III) and the reducing agent sulfite. A core-shell Mie model was used to describe the optical properties of gold nanoparticles in the reverse micelles. Dynamic light scattering of gold colloids in aqueous media and in reverse micelle solution indicated agglomeration of micelles containing particles. This was verified theoretically with an analysis of the total interaction energy between pairs of particles as a function of particle size. The analysis indicated that particles larger than about 8 nm in diameter should reversibly flocculate. Transmission electron microscopy measurements of gold nanoparticles produced in our reverse micelles showed diameters of 8-10 nm. Evidence of cluster formation was also observed. Time-correlated UV-vis absorption measurements showed a red shift for the peak wavelength. This was interpreted as the result of multiple scattering and plasmon interaction between particles due to agglomeration of micelles with particles larger than 8 nm.

  11. Effects of baffle configuration and tank size on spherical agglomerates of dimethyl fumarate in a common stirred tank.

    PubMed

    Lin, Po Yen; Lee, Hung Lin; Chen, Chih Wei; Lee, Tu

    2015-11-30

    To pave the way for technology transfer and scale up of the spherical agglomeration (SA) process for dimethyl fumarate, effects of the US, European and Kawashima type baffles and 0.5, 2.0 and 10 L-sized common stirred tank were studied. It was found that the particle size distribution varied significantly. However, the size-related properties such as dissolution profile and flowability of agglomerates from the same size cut after sieving could remain unchanged. The interior structure-related properties such as particle density and mechanical property of agglomerates upon baffle change and scale up from the same size cut were decayed and the agglomerates could become denser and stronger by prolonged maturation time. To maintain the same size distribution, agglomerates from any batch could have been separated and classified by sieving and then blended back together artificially by the desired weight% of each cut.

  12. Removal of orbital debris

    NASA Technical Reports Server (NTRS)

    Petro, Andrew J.; Talent, David L.

    1989-01-01

    The several methods presently identified for the reduction of orbital debris populations are broadly classifiable as either preventive or remedial, and fall within distinctive operational regimes. For all particles, (1) in the 250-2000-km altitude band, intelligent sweepers may be used; (2) for large objects, in the 80-250-km altitude band, orbital decay renders removal impractical; (3) for the 250-750-km altitude band, deorbit devices should be used; (4) for 750-2500-km altitude, OMV rendezvous for propulsive deorbit package attachment is foreseeable; and beyond 2500 km, (5) propulsive escape from earth orbit is required.

  13. Flocculation, hydrophobic agglomeration and filtration of ultrafine coal

    NASA Astrophysics Data System (ADS)

    Yu, Zhimin

    In coal preparation plant circuits, fine coal particles are aggregated either by oil agglomeration or by flocculation. In a new hydrophobic agglomeration process, recently developed hydrophobic latices are utilized. While the selectivity of such aggregation processes determines the beneficiation results, the degree of aggregation has a strong effect on fine coal filtration. The aim of this research was to study the fundamentals and analyze the common grounds for these processes, including the potential effect of the coal surface properties. The selective flocculation tests, in which three types of coal, which differed widely in surface wettability, and three additives (hydrophobic latices, a semi-hydrophobic flocculant and a typical hydrophilic polyelectrolyte) were utilized, showed that coal wettability plays a very important role in selective flocculation. The abstraction of a hydrophobic latex on coal and silica revealed that the latex had a much higher affinity towards hydrophobic coal than to hydrophilic mineral matter. As a result, the UBC-1 hydrophobic latex flocculated only hydrophobic coal particles while the polyelectrolyte (PAM) flocculated all the tested coal samples and minerals, showing no selectivity in the fine coal beneficiation. The oil agglomeration was tested using kerosene emulsified with various surfactants (e.g. cationic, anionic and non-ionic). Surfactants enhance not only oil emulsification, hence reducing oil consumption (down to 0.25--0.5%), but also entirely change the electrokinetic properties of the droplets and affect the interaction energy between oil droplets and coal particles. Consequently, the results found in the course of the experimental work strongly indicate that even oxidized coals can be agglomerated if cationic surfactants are used to emulsify the oil. Oil agglomeration of the Ford-4 ultrafine coal showed that even at extremely low oil consumption (0.25 to 0.5%), a clean coal product with an ash content around 5% at over

  14. Selective agglomeration of a Pittsburgh Seam coal with isooctane

    SciTech Connect

    Lai, R.; Killmeyer, R.; Utz, B.; Richardson, A.; Sinha, K.

    1992-01-01

    The Pittsburgh Energy Technology Center initiated a research program in 1989 to investigate the fundamentals of selective agglomeration as applied to the cleaning of coals. The results of the initial study with Bruceton mine, Pittsburgh seam coal, using isooctane as an agglomerant, have been published. Subsequent to the successful reduction of the ash content of Bruceton coal to less than 0.9% after two cleaning stages, the study was extended to compare a coal from the same seam, but from Ohio. In the previous parameter optimization tests with Bruceton coal, particle size and slurry pH were found to be important parameters governing coal cleanability. Other researchers have obtained similar conclusions of the effects of particle size and coal slurry pH on the cleanability of various coals. In this study, the effects of these parameters on the cleanability of Powhatan coal were examined. Particle size reduction kinetics was examined first. Effects of size reduction (degree of mineral matter liberation), oil (isooctane)-to-coal ratio, and slurry pH on mineral matter rejection and combustible recovery were also examined. A petrographic comparison was conducted on the Powhatan and Bruceton coals to examine the degree of pyrite liberation as a function of particle size to elucidate why one coal from the same seam can be cleaned significantly better than another. (VC)

  15. On the Mechanism of Ultrasound-Driven Deagglomeration of Nanoparticle Agglomerates in Aluminum Melt

    NASA Astrophysics Data System (ADS)

    Kudryashova, Olga; Vorozhtsov, Sergey

    2016-05-01

    One of the promising directions in the technology of composite alloys with improved mechanical properties is reinforcement of the metallic matrix with nanopowders introduced in the liquid metal. Ultrasonic processing is known to significantly improve the introduction of submicrone particles to the metallic melt. This study focuses on the mechanisms of deagglomeration and wettability of such particles by the melt under the action of ultrasound. The suggested mechanism involves the penetration of the liquid metal into the pores and cracks of the agglomerates under the excess pressure created by imploding cavitation bubbles and further destruction of the agglomerate by the sound wave. The main dependences connecting the acoustic parameters and processing time with the physical and chemical properties of particles and the melt are obtained through analytical modeling. The mathematical description of the ultrasonic deagglomeration in liquid metal is presented; a dependence of the threshold intensity of ultrasound for the break-up of agglomerates on their size is reported.

  16. A Novel Equivalent Agglomeration Model for Heat Conduction Enhancement in Nanofluids

    NASA Astrophysics Data System (ADS)

    Sui, Jize; Zheng, Liancun; Zhang, Xinxin; Chen, Ying; Cheng, Zhengdong

    2016-01-01

    We propose a multilevel equivalent agglomeration (MEA) model in which all particles in an irregular cluster are treated as a new particle with equivalent volume, the liquid molecules wrapping the cluster and in the gaps are considered to assemble on the surface of new particle as mixing nanolayer (MNL), the thermal conductivity in MNL is assumed to satisfy exponential distribution. Theoretical predictions for thermal conductivity enhancement are highly in agreement with the classical experimental data. Also, we first try to employ TEM information quantitatively to offer probable reference agglomeration ratio (not necessary a very precise value) to just test rational estimations range by present model. The comparison results indicate the satisfactory priori agglomeration ratio estimations range from renovated model.

  17. A Novel Equivalent Agglomeration Model for Heat Conduction Enhancement in Nanofluids

    PubMed Central

    Sui, Jize; Zheng, Liancun; Zhang, Xinxin; Chen, Ying; Cheng, Zhengdong

    2016-01-01

    We propose a multilevel equivalent agglomeration (MEA) model in which all particles in an irregular cluster are treated as a new particle with equivalent volume, the liquid molecules wrapping the cluster and in the gaps are considered to assemble on the surface of new particle as mixing nanolayer (MNL), the thermal conductivity in MNL is assumed to satisfy exponential distribution. Theoretical predictions for thermal conductivity enhancement are highly in agreement with the classical experimental data. Also, we first try to employ TEM information quantitatively to offer probable reference agglomeration ratio (not necessary a very precise value) to just test rational estimations range by present model. The comparison results indicate the satisfactory priori agglomeration ratio estimations range from renovated model. PMID:26777389

  18. Bed material agglomeration during fluidized bed combustion

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  19. Analyzing turbidity, suspended-sediment concentration, and particle-size distribution resulting from a debris flow on Mount Jefferson, Oregon, November 2006

    USGS Publications Warehouse

    Uhrich, Mark A.

    2010-01-01

    A debris flow and sediment torrent occurred on the flanks of Mt Jefferson in Oregon on November 6, 2006, inundating 150 acres of forest. The massive debris flow was triggered by a rock and snow avalanche from the Milk Creek glaciers and snowfields during the early onset of an intense storm originating near the Hawaiian Islands. The debris flow consisted of a heavy conglomerate of large boulders, cobbles, and coarse-grained sediment that was deposited at depths of up to 15 ft and within 3 mi of the glaciers, and a viscous slurry that deposited finer-grained sediments at depths of 0.5 to 3 ft. The muddy slurry coated standing trees within the lower reaches of Milk Creek as it moved downslope.

  20. Detailed analysis of a quench bomb for the study of aluminum agglomeration in solid propellants

    NASA Astrophysics Data System (ADS)

    Gallier, S.; Kratz, J.-G.; Quaglia, N.; Fouin, G.

    2016-07-01

    A standard quench bomb (QB) - widely used to characterize condensed phase from metalized solid propellant combustion - is studied in detail. Experimental and numerical investigations proved that collected particles are mostly unburned aluminum (Al) agglomerates despite large quenching distances. Particles are actually found to quench early as propellant surface is swept by inert pressurant. Further improvements of the QB are proposed which allow measuring both Al agglomerates and alumina residue with the same setup. Finally, the results obtained on a typical aluminized ammonium perchlorate (AP) / hydroxyl-terminated polybutadiene (HTPB) propellant are briefly discussed.

  1. Space Shuttle Debris Transport

    NASA Technical Reports Server (NTRS)

    Gomez, Reynaldo J., III

    2010-01-01

    This slide presentation reviews the assessment of debris damage to the Space Shuttle, and the use of computation to assist in the space shuttle applications. The presentation reviews the sources of debris, a mechanism for determining the probability of damaging debris impacting the shuttle, tools used, eliminating potential damaging debris sources, the use of computation to assess while inflight damage, and a chart showing the applications that have been used on increasingly powerful computers simulate the shuttle and the debris transport.

  2. Development of a gas-promoted oil agglomeration process. Quarterly report, October 1, 1996--December 31, 1996

    SciTech Connect

    Wheelock, T.D.

    1996-12-01

    Further agglomeration tests were conducted in a series of tests designed to determine the effects of various parameters on the size and structure of the agglomerates formed, the rate of agglomeration, coal recovery, and ash rejection. For this series of tests, finely ground Pittsburgh No. 8 coal has been agglomerated with i-octane in a closed mixing system with a controlled amount of air present to promote particle agglomeration. The present results provide further evidence of the role played by air. As the concentration of air in the system was increased from 4.5 to 18 v/w% based on the weight of coal, coal recovery and ash rejection both increased. The results also show that coal recovery and ash rejection were improved by increasing agitator speed. On the other hand, coal recovery was not affected by a change in solids concentration from 20 to 30 w/w%.

  3. Effect of the Additives on the Desulphurization Rate of Flash Hydrated and Agglomerated CFB Fly Ash

    NASA Astrophysics Data System (ADS)

    Li, D. X.; Li, H. L.; Xu, M.; Lu, J. F.; Liu, Q.; Zhang, J. S.; Yue, G. X.

    CFB fly ash from separators was mixed with water or the mixture of water and additives under the temperature of 363K by use of a blender. Then, this compound of fly ash and water or additives was pumped into a CFB combustion chamber by a sludge pump. Because the temperature of flue gas was high in CFB, the fly ash was hydrated fast and agglomerated in the same time. Through this process, the size of agglomerating fly ash is larger than the original particle and the relative residence time of agglomerated fly ash in CFB becomes longer. Therefore, the rate of utility of calcium in fly ash improves and the content of carbon in fly ash decreases. This results in a low Ca/S and low operational cost for CFB boiler. The additive is one key factor, which affects the rate of desulfurization of agglomerated fly ash. Effect of different additives on rate of desulfurization is not same. Cement and limestone are beneficiated to sulfur removal of agglomerated fly ash, but sodium silicate does not devote to the rate of sulfur removal of agglomerated fly ash.

  4. Factors affecting the oil agglomeration of Sivas-Divrigi Ulucayir lignite

    SciTech Connect

    Unal, I.; Gorgun Ersan, M.

    2007-07-01

    In the coal industry, the coal particles need to be decreased to a very fine size because of the need of removing inorganic materials from coal. Oil agglomeration is a kind of coal cleaning technique that is used for separation of organic and inorganic parts of fine sized coal. In this study, the oil agglomeration of Sivas-Divrigi (S-D) Ulucayir lignite was carried out by using kerosene, diesel oil, fuel oil, poppy oil, and sunflower oil. The amount of bridging oil was varied from 5% to 25% of the amount of lignite. The effect of oil amount, oil type, solid content, agitation rate and time, pH on agglomeration performance was investigated. Maximum recovery value of 98.18% was observed by using poppy oil. In order to investigate the effect of pH on agglomeration NaOH and HCl is added to the slurry in various amounts. It is decided that the best agglomeration condition is obtained at low pH values. The effect of nonionic surface active agent (Igepal-CA 630) on agglomeration is investigated by adding to the slurry and it is observed that the grade is increased with the amount of surface active agent.

  5. Development of a gas-promoted oil agglomeration process. Technical progress report, October 1, 1993--September 30, 1994

    SciTech Connect

    Wheelock, T.D.

    1994-10-01

    During the first year of the project two model mixing systems, which differed in size but were similar in design, were constructed and tested. The systems were equipped for measuring agitator speed and torque and for measuring the turbidity of coal particle suspensions undergoing agglomeration. Preliminary measurements of aqueous suspensions of coal particles showed that the Beer-Lambert law applies to such suspensions at least for low concentrations. Therefore, the measured turbidity can be used as an indicator of particle concentration and a means for monitoring the progress of oil agglomeration. However, the method is not applicable for large particle concentrations so a different technique was tested for monitoring the agglomeration of large concentrations. This technique involves measuring agitator torque and observing changes in torque while agitator speed is held constant. The results of preliminary tests of the technique were encouraging. In these tests significant changes in agitator torque were observed when particle agglomeration took place as long as solids concentration of 25 w/v % or more were utilized. A number of agglomeration tests were conducted using either one or the other of the two monitoring techniques. Both methods showed that even very small amounts of air can promote the oil agglomeration of coal particles suspended in water. Even the amount of air dissolved in water at room temperature and pressure can affect the process providing the air is displaced from the solution by a slightly soluble agglomerant such as heptane. The apparent rate of agglomeration was observed to increase as more air was introduced and also as agitator speed was increased.

  6. Diffusion and reaction in microbead agglomerates.

    PubMed

    Nunes Kirchner, Carolina; Träuble, Markus; Wittstock, Gunther

    2010-04-01

    Scanning electrochemical microscopy has been used to analyze the flux of p-aminonophenol (PAP) produced by agglomerates of polymeric microbeads modified with galactosidase as a model system for the bead-based heterogeneous immunoassays. With the use of mixtures of enzyme-modified and bare beads in defined ratio, agglomerates with different saturation levels of the enzyme modification were produced. The PAP flux depends on the intrinsic kinetics of the galactosidase, the local availability of the substrate p-aminophenyl-beta-D-galactopyranoside (PAPG), and the external mass transport conditions in the surrounding of the agglomerate and the internal mass transport within the bead agglomerate. The internal mass transport is influenced by the diffusional shielding of the modified beads by unmodified beads. SECM in combination with optical microscopy was used to determine experimentally the external flux. These data are in quantitative agreement with boundary element simulation considering the SECM microelectrode as an interacting probe and treating the Michaelis-Menten kinetics of the enzyme as nonlinear boundary conditions with two independent concentration variables [PAP] and [PAPG]. The PAPG concentration at the surface of the bead agglomerate was taken as a boundary condition for the analysis of the internal mass transport condition as a function of the enzyme saturation in the bead agglomerate. The results of this analysis are represented as PAP flux per contributing modified bead and the flux from freely suspended galactosidase-modified beads. These numbers are compared to the same number from the SECM experiments. It is shown that depending on the enzyme saturation level a different situation can arise where either beads located at the outer surface of the agglomerate dominate the contribution to the measured external flux or where the contribution of buried beads cannot be neglected for explaining the measured external flux.

  7. Iron Oxide Nanoparticle Agglomeration Influences Dose-Rates and Modulates Oxidative Stress Mediated Dose-Response Profiles In Vitro

    SciTech Connect

    Sharma, Gaurav; Kodali, Vamsi K.; Gaffrey, Matthew J.; Wang, Wei; Minard, Kevin R.; Karin, Norman J.; Teeguarden, Justin G.; Thrall, Brian D.

    2013-07-31

    Spontaneous agglomeration of engineered nanoparticles (ENPs) is a common problem in cell culture media which can confound interpretation of in vitro nanotoxicity studies. The authors created stable agglomerates of iron oxide nanoparticles (IONPs) in conventional culture medium, which varied in hydrodynamic size (276 nm-1.5 μm) but were composed of identical primary particles with similar surface potentials and protein coatings. Studies using C10 lung epithelial cells show that the dose rate effects of agglomeration can be substantial, varying by over an order of magnitude difference in cellular dose in some cases. Quantification by magnetic particle detection showed that small agglomerates of carboxylated IONPs induced greater cytotoxicity and redox-regulated gene expression when compared with large agglomerates on an equivalent total cellular IONP mass dose basis, whereas agglomerates of amine-modified IONPs failed to induce cytotoxicity or redox-regulated gene expression despite delivery of similar cellular doses. Dosimetry modelling and experimental measurements reveal that on a delivered surface area basis, large and small agglomerates of carboxylated IONPs have similar inherent potency for the generation of ROS, induction of stress-related genes and eventual cytotoxicity. The results suggest that reactive moieties on the agglomerate surface are more efficient in catalysing cellular ROS production than molecules buried within the agglomerate core. Because of the dynamic, size and density-dependent nature of ENP delivery to cells in vitro, the biological consequences of agglomeration are not discernible from static measures of exposure concentration (μg/ml) alone, highlighting the central importance of integrated physical characterisation and quantitative dosimetry for in vitro studies. The combined experimental and computational approach provides a quantitative framework for evaluating relationships between the biocompatibility of nanoparticles and their

  8. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1995-01-01

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 mm) needed to achieve adequate liberation of the mineral matter from the coal matrix. It is generally recognized that surface-based separation processes such as froth flotation or selective agglomeration offer considerable potential for such applications but there remain many problems in obtaining the required selectivity with acceptable recovery of combustible matter. In froth flotation, selectivity is substantially reduced at fine sizes due, primarily, to overloading of the froth phase which leads to excessive carryover of water and entrained mineral matter. Oil agglomeration, on the other hand, can provide good selectivity at low levels of oil addition but the agglomerates tend to be too fragile for separation by the screening methods normally used. The addition of larger amounts of oil can yield large, strong agglomerates which are easily separated but the selectivity is reduced and reagent costs can become excessive. We are investigating the use of a hybrid process - micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30-50 mm in size) rather than individual coal particles (1-10 mm) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale.

  9. Reduced bed agglomeration by co-combustion biomass with peat fuels in a fluidized bed

    SciTech Connect

    Karin Lundholm; Anders Nordin; Marcus Oehman; Dan Bostroem

    2005-12-01

    Fluidized bed combustion is an energy conversion technology that is very suitable for biomass combustion because of its fuel flexibility and low process temperatures. However, agglomeration of bed material may cause severe operating problems. To prevent or at least reduce this, peat has been suggested as an additive to the main fuels. Nevertheless, the characteristics of peat fuels vary and there is limited information of the effect of different peat fuels and of the mechanisms behind the agglomeration prevention. The objectives of the present work were therefore to: (I) quantify the potential positive effect by co-combustion peat with forest fuels in terms of initial agglomeration temperatures; (ii) determine the amount of peat fuel that is needed to significantly reduce the agglomeration tendencies; and, if possible, (iii) elucidate the governing mechanisms. The results showed that all peat fuels prevented agglomeration in the studied interval of 760-1020{sup o}C and even as little as 5% peat fuel was found to have significant effects. The results also indicated that the mechanism of the agglomeration prevention varies between different peat fuels. Possible mechanisms are the minerals in the peat fuel retain alkali, which then is either elutriated up from the bed or captured in the bed; calcium and other refractory elements increase the melting temperature and thereby counteract the melting of alkali; and sulfur reacts with alkali metals and the alkali sulfates is either elutriated up from the bed or prevents agglomeration by increased melting temperature and lowered viscosity. Results from elemental analysis of the coating on bed particles showed that all mixtures with peat fuel resulted in a decreased or unchanged fraction of potassium and an increased fraction of aluminum in the coatings. The results also indicated a complex relationship between the fuel inorganic contents and the agglomeration process. 21 refs., 6 figs., 5 tabs.

  10. In-Situ Agglomeration and De-agglomeration by Milling of Nano-Engineered Lubricant Particulate Composites for Cold Spray Deposition

    NASA Astrophysics Data System (ADS)

    Neshastehriz, M.; Smid, I.; Segall, A. E.

    2014-10-01

    Nano-engineered self-lubricating particles comprised of hexagonal-boron-nitride powder (hBN) encapsulated in nickel have been developed for cold spray coating of aluminum components. The nickel encapsulant consists of several nano-sized layers, which are deposited on the hBN particles by electroless plating. In the cold spray deposition, the nickel becomes the matrix in which hBN acts as the lubricant. The coating demonstrated a very promising performance by reducing the coefficient of friction by almost 50% and increasing the wear resistance more than tenfold. The coatings also exhibited higher bond strength, which was directly related to the hardenability of the particles. During the encapsulation process, the hBN particles agglomerate and form large clusters. De-agglomeration has been studied through low- and high-energy ball milling to create more uniform and consistent particle sizes and to improve the cold spray deposition efficiency. The unmilled and milled particles were characterized with Scanning Electron Microscopy, Energy-Dispersive X-Ray Spectroscopy, BET, and hardness tests. It was found that in low-energy ball milling, the clusters were compacted to a noticeable extent. However, the high-energy ball milling resulted in breakup of agglomerations and destroyed the nickel encapsulant.

  11. Method of separating and de-watering fine particles

    DOEpatents

    Yoon, Roe-Hoan

    2016-12-13

    A process for cleaning and dewatering hydrophobic particulate materials is presented. The process is performed in two steps: 1) agglomeration of the hydrophobic particles in a first hydrophobic liquid/aqueous mixture; followed by 2) dispersion of the agglomerates in a second hydrophobic liquid to release the water trapped within the agglomerates along with the entrained hydrophilic particles.

  12. A discrete element and ray framework for rapid simulation of acoustical dispersion of microscale particulate agglomerations

    NASA Astrophysics Data System (ADS)

    Zohdi, T. I.

    2016-03-01

    In industry, particle-laden fluids, such as particle-functionalized inks, are constructed by adding fine-scale particles to a liquid solution, in order to achieve desired overall properties in both liquid and (cured) solid states. However, oftentimes undesirable particulate agglomerations arise due to some form of mutual-attraction stemming from near-field forces, stray electrostatic charges, process ionization and mechanical adhesion. For proper operation of industrial processes involving particle-laden fluids, it is important to carefully breakup and disperse these agglomerations. One approach is to target high-frequency acoustical pressure-pulses to breakup such agglomerations. The objective of this paper is to develop a computational model and corresponding solution algorithm to enable rapid simulation of the effect of acoustical pulses on an agglomeration composed of a collection of discrete particles. Because of the complex agglomeration microstructure, containing gaps and interfaces, this type of system is extremely difficult to mesh and simulate using continuum-based methods, such as the finite difference time domain or the finite element method. Accordingly, a computationally-amenable discrete element/discrete ray model is developed which captures the primary physical events in this process, such as the reflection and absorption of acoustical energy, and the induced forces on the particulate microstructure. The approach utilizes a staggered, iterative solution scheme to calculate the power transfer from the acoustical pulse to the particles and the subsequent changes (breakup) of the pulse due to the particles. Three-dimensional examples are provided to illustrate the approach.

  13. Orbital Debris: A Chronology

    NASA Technical Reports Server (NTRS)

    Portree, Davis S. F. (Editor); Loftus, Joseph P., Jr. (Editor)

    1999-01-01

    This chronology covers the 37-year history of orbital debris concerns. It tracks orbital debris hazard creation, research, observation, experimentation, management, mitigation, protection, and policy. Included are debris-producing, events; U.N. orbital debris treaties, Space Shuttle and space station orbital debris issues; ASAT tests; milestones in theory and modeling; uncontrolled reentries; detection system development; shielding development; geosynchronous debris issues, including reboost policies: returned surfaces studies, seminar papers reports, conferences, and studies; the increasing effect of space activities on astronomy; and growing international awareness of the near-Earth environment.

  14. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, 1 April--30 June 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1994-07-01

    The authors are investigating the use of a hybrid process--Micro-agglomerate flotation--which is a combination of oil-agglomeration and froth flotation. The basic concepts is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload water/mineral carryover should be significantly alleviated. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response. The research program has been organized into several specific tasks: Task 1, interfacial studies; Task 2, emulsification; Task 3, agglomerate growth and structure; and Task 4, agglomerate flotation. This report summarizes the status of Tasks 2, 3, and 4.

  15. Micro-agglomerate flotation for deep cleaning of coal. Final report

    SciTech Connect

    Chander, S.; Hogg, R.

    1997-01-15

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 {micro}m) needed to achieve adequate liberation of the mineral matter from the coal matrix. In this investigation a hybrid process--Micro-agglomerate flotation--which is a combination of oil-agglomeration and froth flotation was studied. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles and to use froth flotation to separate these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units will be relatively large agglomerates (30--50 {micro}m in size) rather than fine coal particles (1--10 {micro}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is demonstrated in this study that the process is very sensitive to fluctuations in operating parameters. It is necessary to maintain precise control over the chemistry of the liquid phases as well as the agitation conditions in order to promote selectivity. Both kinetics as well as thermodynamic factors play a critical role in determining overall system response.

  16. In Situ Observations of Interaction Between Particulate Agglomerates and an Advancing Planar Solid/Liquid Interface: Microgravity Experiments

    NASA Technical Reports Server (NTRS)

    Sen, S.; Juretzko, F.; Stafanescu, D. M.; Dhindaw, B. K.; Curreri, P. A.

    1999-01-01

    Results are reported of directional solidification experiments on particulate agglomerate pushing and engulfment by a planar solid/liquid (s/l) interface. These experiments were conducted on the Space Shuttle Columbia during the United States Microgravity Payload 4 (USMP-4) Mission. It was found that the pushing to engulfment transition velocity, V(sub cr) for agglomerates depends not only on their effective size but also their orientation with respect to the s,1 interface. The analytical model for predicting V(sub cr) of a single particle was subsequently enhanced to predict V(sub cr) of the agglomerates by considering their shape factor and orientation.

  17. In-Situ Observations of Interaction Between Particulate Agglomerates and an Advancing Planar Solid/Liquid Interface: Microgravity Experiments

    NASA Technical Reports Server (NTRS)

    Sen, S.; Juretzko, F.; Stefanescu, D. M.; Dhindaw, B. K.; Curreri, P. A.

    1999-01-01

    Results are reported of directional solidification experiments on particulate agglomerate pushing and engulfment by a planar solid/liquid (s/1) interface. These experiments were conducted on the Space Shuttle Columbia during the United States Microgravity Payload 4 (USMP-4) Mission. It was found that the pushing to engulfment transition velocity, V(sub ct),, for agglomerates depends not only on their effective size but also their orientation with respect to the s/l interface. The analytical model for predicting V(sub cr) of a single particle was subsequently enhanced to predict V(sub cr) of the agglomerates by considering their shape factor and orientation.

  18. Development of a gas-promoted oil agglomeration process. [Quarterly] technical progress report, September 1, 1993--November 30, 1993

    SciTech Connect

    Wheelock, T.D.

    1993-12-31

    The overall purpose of this research project is to carry out the preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal using model mixing systems. Previous research showed that having a gas present in an agitated system used for the agglomeration of an aqueous suspension of coal particles with oil would reduce greatly the required mixing shear rate and power input. To take advantage of this discovery, the present research project was initiated. The project will involve building and testing two model mixing systems which differ in scale but are representative of standard industrial mixing systems used for mixing solid particles, liquid, and gas. These systems will be tested by conducting oil agglomeration tests under various conditions and measuring agitator torque and power as well as agglomeration performance. Special attention will be given to the effects produced by having gas present in the system.

  19. Gravitational agglomeration of post-HCDA LMFBR nonspherical aerosols

    NASA Astrophysics Data System (ADS)

    Tuttle, R. F.

    1980-12-01

    A theoretical investigation of collisional dynamics of two particle interactions in a gravitational field is reported. This research is unique in that it is the first attempt at modeling the hydrodynamic interactions between a nonspherical particle and a spherical particle undergoing gravitational collisions in an LMFBR environment. Basic definitions and expressions are developed for nonspherical particles and related to spherical particles by means of shape factors. Using volume equivalent diameter as the defining length in the gravitational collision kernel, the aerodynamic shape factor, k, the density correction factor, alpha, and the gravitational collision shape factor, beta, are used to correct the collision kernel for the case of collisions between aerosol agglomerates. The Navier-Stokes equation in oblate spheroidal coordinates is solved to model a nonspherical particle and then the dynamic equations for two particle motions are developed. A computer program NGCEFF is constructed, the Navier-Stokes equation is solved by the finite difference method, and the dynamical equations are solved by Gear's method. It is concluded that the aerosol gravitational collision shape factor can be determined by further theoretical work based on the concepts and methods developed in this dissertation.

  20. Turbomachinery debris remover

    DOEpatents

    Krawiec, Donald F.; Kraf, Robert J.; Houser, Robert J.

    1988-01-01

    An apparatus for removing debris from a turbomachine. The apparatus includes housing and remotely operable viewing and grappling mechanisms for the purpose of locating and removing debris lodged between adjacent blades in a turbomachine.

  1. Report on orbital debris

    NASA Technical Reports Server (NTRS)

    1989-01-01

    The success of space endeavors depends upon a space environment sufficiently free of debris to enable the safe and dependable operation of spacecraft. An environment overly cluttered with debris would threaten the ability to utilize space for a wide variety of scientific, technological, military, and commercial purposes. Man made space debris (orbital debris) differs from natural meteoroids because it remains in earth orbit during its lifetime and is not transient through the space around the Earth. The orbital debris environment is considered. The space environment is described along with sources of orbital debris. The current national space policy is examined, along with ways to minimize debris generation and ways to survive the debris environment. International efforts, legal issues and commercial regulations are also examined.

  2. Visualizing powder de-agglomeration upon impact with simultaneous flowing charge behaviour

    NASA Astrophysics Data System (ADS)

    Kwek, Jin Wang; Heng, Desmond; Lee, Sie Huey; Ng, Wai Kiong; Chan, Hak-Kim; Heng, Jerry; Tan, Reginald

    2013-06-01

    The effectiveness of the dry powder inhaler (DPI) in treating respiratory diseases lies in its ability to deliver consistent and reliable drug dosage with each actuation. From aerosolization upon actuation to throat impaction, the deagglomeration with subsequent detachment of the drug from the carrier particles depend on the interaction forces, including electrostatic contributions, between the particles themselves or with the inhaler wall and the extent of which could depend on the surface roughness of the carrier particles. In this study, we have simultaneously investigated the contributions of the electrostatic forces while visualizing the de-agglomeration and impaction behaviours of carrier powders in an impaction throat model using a non-contact vibrating capacitive probe and a high speed camera respectively. Rough and smooth carrier particles were obtained by spray drying and then aerosolized at 60 L/min in the model. Higher flowing charges were observed for the rough aerosolized carrier particles while experiencing rebound or limited agglomerate fracture upon impaction. On the other hand, smooth particles were broken up upon impaction resulting in a 'plume-like' re-entrainment. Further analyses revealed that the increased moisture sorption on the larger specific surface area of the rough particles would have facilitated the accumulation of surface charges that could in turn contribute to the cohesiveness of the rough particles. Combined high speed imaging with electrostatic monitoring has proved to be useful in investigating the mechanisms of powder de-agglomeration upon impaction.

  3. Agglomeration of Celecoxib by Quasi Emulsion Solvent Diffusion Method: Effect of Stabilizer

    PubMed Central

    Maghsoodi, Maryam; Nokhodchi, Ali

    2016-01-01

    Purpose: The quasi-emulsion solvent diffusion (QESD) has evolved into an effective technique to manufacture agglomerates of API crystals. Although, the proposed technique showed benefits, such as cost effectiveness, that is considerably sensitive to the choice of a stabilizer, which agonizes from a absence of systemic understanding in this field. In the present study, the combination of different solvents and stabilizers were compared to investigate any connections between the solvents and stabilizers. Methods: Agglomerates of celecoxib were prepared by QESD method using four different stabilizers (Tween 80, HPMC, PVP and SLS) and three different solvents (methyl acetate, ethyl acetate and isopropyl acetate). The solid state of obtained particles was investigated by differential scanning calorimetry (DSC) and Fourier transform infrared (FT-IR) spectroscopy. The agglomerated were also evaluated in term of production yield, distribution of particles and dissolution behavior. Results: The results showed that the effectiveness of stabilizer in terms of particle size and particle size distribution is specific to each solvent candidate. A stabilizer with a lower HLB value is preferred which actually increased its effectiveness with the solvent candidates with higher lipophilicity. HPMC appeared to be the most versatile stabilizer because it showed a better stabilizing effect compared to other stabilizers in all solvents used. Conclusion: This study demonstrated that the efficiency of stabilizers in forming the celecoxib agglomerates by QESD was influenced by the HLB of the stabilizer and lipophilicity of the solvents. PMID:28101468

  4. Agglomeration of Celecoxib by Quasi Emulsion Solvent Diffusion Method: Effect of Stabilizer.

    PubMed

    Maghsoodi, Maryam; Nokhodchi, Ali

    2016-12-01

    Purpose: The quasi-emulsion solvent diffusion (QESD) has evolved into an effective technique to manufacture agglomerates of API crystals. Although, the proposed technique showed benefits, such as cost effectiveness, that is considerably sensitive to the choice of a stabilizer, which agonizes from a absence of systemic understanding in this field. In the present study, the combination of different solvents and stabilizers were compared to investigate any connections between the solvents and stabilizers. Methods: Agglomerates of celecoxib were prepared by QESD method using four different stabilizers (Tween 80, HPMC, PVP and SLS) and three different solvents (methyl acetate, ethyl acetate and isopropyl acetate). The solid state of obtained particles was investigated by differential scanning calorimetry (DSC) and Fourier transform infrared (FT-IR) spectroscopy. The agglomerated were also evaluated in term of production yield, distribution of particles and dissolution behavior. Results: The results showed that the effectiveness of stabilizer in terms of particle size and particle size distribution is specific to each solvent candidate. A stabilizer with a lower HLB value is preferred which actually increased its effectiveness with the solvent candidates with higher lipophilicity. HPMC appeared to be the most versatile stabilizer because it showed a better stabilizing effect compared to other stabilizers in all solvents used. Conclusion: This study demonstrated that the efficiency of stabilizers in forming the celecoxib agglomerates by QESD was influenced by the HLB of the stabilizer and lipophilicity of the solvents.

  5. A complex network approach for nanoparticle agglomeration analysis in nanoscale images

    NASA Astrophysics Data System (ADS)

    Machado, Bruno Brandoli; Scabini, Leonardo Felipe; Margarido Orue, Jonatan Patrick; de Arruda, Mauro Santos; Goncalves, Diogo Nunes; Goncalves, Wesley Nunes; Moreira, Raphaell; Rodrigues-Jr, Jose F.

    2017-02-01

    Complex networks have been widely used in science and technology because of their ability to represent several systems. One of these systems is found in Biochemistry, in which the synthesis of new nanoparticles is a hot topic. However, the interpretation of experimental results in the search of new nanoparticles poses several challenges. This is due to the characteristics of nanoparticle images and due to their multiple intricate properties; one property of recurrent interest is the agglomeration of particles. Addressing this issue, this paper introduces an approach that uses complex networks to detect and describe nanoparticle agglomerates so to foster easier and more insightful analyses. In this approach, each detected particle in an image corresponds to a vertice and the distances between the particles define a criterion for creating edges. Edges are created if the distance is smaller than a radius of interest. Once this network is set, we calculate several discrete measures able to reveal the most outstanding agglomerates in a nanoparticle image. Experimental results using images of scanning tunneling microscopy (STM) of gold nanoparticles demonstrated the effectiveness of the proposed approach over several samples, as reflected by the separability between particles in three usual settings. The results also demonstrated efficacy for both convex and non-convex agglomerates.

  6. On minimal energy dipole moment distributions in regular polygonal agglomerates

    NASA Astrophysics Data System (ADS)

    Rosa, Adriano Possebon; Cunha, Francisco Ricardo; Ceniceros, Hector Daniel

    2017-01-01

    Static, regular polygonal and close-packed clusters of spherical magnetic particles and their energy-minimizing magnetic moments are investigated in a two-dimensional setting. This study focuses on a simple particle system which is solely described by the dipole-dipole interaction energy, both without and in the presence of an in-plane magnetic field. For a regular polygonal structure of n sides with n ≥ 3 , and in the absence of an external field, it is proved rigorously that the magnetic moments given by the roots of unity, i.e. tangential to the polygon, are a minimizer of the dipole-dipole interaction energy. Also, for zero external field, new multiple local minima are discovered for the regular polygonal agglomerates. The number of found local extrema is proportional to [ n / 2 ] and these critical points are characterized by the presence of a pair of magnetic moments with a large deviation from the tangential configuration and whose particles are at least three diameters apart. The changes induced by an in-plane external magnetic field on the minimal energy, tangential configurations are investigated numerically. The two critical fields, which correspond to a crossover with the linear chain minimal energy and with the break-up of the agglomerate, respectively are examined in detail. In particular, the numerical results are compared directly with the asymptotic formulas of Danilov et al. (2012) [23] and a remarkable agreement is found even for moderate to large fields. Finally, three examples of close-packed structures are investigated: a triangle, a centered hexagon, and a 19-particle close packed cluster. The numerical study reveals novel, illuminating characteristics of these compact clusters often seen in ferrofluids. The centered hexagon is energetically favorable to the regular hexagon and the minimal energy for the larger 19-particle cluster is even lower than that of the close packed hexagon. In addition, this larger close packed agglomerate has two

  7. Debris exhaust system

    DOEpatents

    McBride, Donald D.; Bua, Dominic; Domankevitz, Yacov; Nishioka, Norman

    1998-01-01

    A debris removal system removes debris from a work site by flowing fluid away from the work site toward the periphery of a structure. The fluid flow can be kept constant around the periphery so that debris is removed evenly. The structure can have a reduced cross section between the fluid inlet and the work site so that the resulting increased fluid velocity works to prevent debris from escaping.

  8. Debris exhaust system

    DOEpatents

    McBride, D.D.; Bua, D.; Domankevitz, Y.; Nishioka, N.

    1998-06-23

    A debris removal system removes debris from a work site by flowing fluid away from the work site toward the periphery of a structure. The fluid flow can be kept constant around the periphery so that debris is removed evenly. The structure can have a reduced cross section between the fluid inlet and the work site so that the resulting increased fluid velocity works to prevent debris from escaping. 9 figs.

  9. Characterization of size, surface charge, and agglomeration state of nanoparticle dispersions for toxicological studies

    NASA Astrophysics Data System (ADS)

    Jiang, Jingkun; Oberdörster, Günter; Biswas, Pratim

    2009-01-01

    Characterizing the state of nanoparticles (such as size, surface charge, and degree of agglomeration) in aqueous suspensions and understanding the parameters that affect this state are imperative for toxicity investigations. In this study, the role of important factors such as solution ionic strength, pH, and particle surface chemistry that control nanoparticle dispersion was examined. The size and zeta potential of four TiO2 and three quantum dot samples dispersed in different solutions (including one physiological medium) were characterized. For 15 nm TiO2 dispersions, the increase of ionic strength from 0.001 M to 0.1 M led to a 50-fold increase in the hydrodynamic diameter, and the variation of pH resulted in significant change of particle surface charge and the hydrodynamic size. It was shown that both adsorbing multiply charged ions (e.g., pyrophosphate ions) onto the TiO2 nanoparticle surface and coating quantum dot nanocrystals with polymers (e.g., polyethylene glycol) suppressed agglomeration and stabilized the dispersions. DLVO theory was used to qualitatively understand nanoparticle dispersion stability. A methodology using different ultrasonication techniques (bath and probe) was developed to distinguish agglomerates from aggregates (strong bonds), and to estimate the extent of particle agglomeration. Probe ultrasonication performed better than bath ultrasonication in dispersing TiO2 agglomerates when the stabilizing agent sodium pyrophosphate was used. Commercially available Degussa P25 and in-house synthesized TiO2 nanoparticles were used to demonstrate identification of aggregated and agglomerated samples.

  10. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, July 1--September 30, 1994

    SciTech Connect

    Chander, S.; Hogg, R.

    1994-10-01

    The goals of this research program are to demonstrate the technical and economic feasibility of a micro-agglomerate flotation process and to establish the essential criteria for reagent selection and system design and operation. We are investigating the use of a hybrid process -- Micro-agglomerate flotation -- which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. The research program has been organized into several specific tasks : interfacial studies; emulsification; agglomerate growth and structure; and agglomerate flotation. Accomplishments are reported.

  11. The self-preserving size distribution theory. I. Effects of the Knudsen number on aerosol agglomerate growth.

    PubMed

    Dekkers, Petrus J; Friedlander, Sheldon K

    2002-04-15

    Gas-phase synthesis of fine solid particles leads to fractal-like structures whose transport and light scattering properties differ from those of their spherical counterparts. Self-preserving size distribution theory provides a useful methodology for analyzing the asymptotic behavior of such systems. Apparent inconsistencies in previous treatments of the self-preserving size distributions in the free molecule regime are resolved. Integro-differential equations for fractal-like particles in the continuum and near continuum regimes are derived and used to calculate the self-preserving and quasi-self-preserving size distributions for agglomerates formed by Brownian coagulation. The results for the limiting case (the continuum regime) were compared with the results of other authors. For these cases the finite difference method was in good in agreement with previous calculations in the continuum regime. A new analysis of aerosol agglomeration for the entire Knudsen number range was developed and compared with a monodisperse model; Higher agglomeration rates were found for lower fractal dimensions, as expected from previous studies. Effects of fractal dimension, pressure, volume loading and temperature on agglomerate growth were investigated. The agglomeration rate can be reduced by decreasing volumetric loading or by increasing the pressure. In laminar flow, an increase in pressure can be used to control particle growth and polydispersity. For D(f)=2, an increase in pressure from 1 to 4 bar reduces the collision radius by about 30%. Varying the temperature has a much smaller effect on agglomerate coagulation.

  12. Erosion of steepland valleys by debris flows

    USGS Publications Warehouse

    Stock, J.D.; Dietrich, W.E.

    2006-01-01

    Episodic debris flows scour the rock beds of many steepland valleys. Along recent debris-flow runout paths in the western United States, we have observed evidence for bedrock lowering, primarily by the impact of large particles entrained in debris flows. This evidence may persist to the point at which debris-flow deposition occurs, commonly at slopes of less than ???0.03-0.10. We find that debris-flow-scoured valleys have a topographic signature that is fundamentally different from that predicted by bedrock river-incision models. Much of this difference results from the fact that local valley slope shows a tendency to decrease abruptly downstream of tributaries that contribute throughgoing debris flows. The degree of weathering of valley floor bedrock may also decrease abruptly downstream of such junctions. On the basis of these observations, we hypothesize that valley slope is adjusted to the long-term frequency of debris flows, and that valleys scoured by debris flows should not be modeled using conventional bedrock river-incision laws. We use field observations to justify one possible debris-flow incision model, whose lowering rate is proportional to the integral of solid inertial normal stresses from particle impacts along the flow and the number of upvalley debris-flow sources. The model predicts that increases in incision rate caused by increases in flow event frequency and length (as flows gain material) downvalley are balanced by rate reductions from reduced inertial normal stress at lower slopes, and stronger, less weathered bedrock. These adjustments lead to a spatially uniform lowering rate. Although the proposed expression leads to equilibrium long-profiles with the correct topographic signature, the crudeness with which the debris-flow dynamics are parameterized reveals that we are far from a validated debris-flow incision law. However, the vast extent of steepland valley networks above slopes of ???0.03-0.10 illustrates the need to understand debris

  13. Geosynchronous Large Debris Reorbiter: Challenges and Prospects

    NASA Astrophysics Data System (ADS)

    Schaub, Hanspeter; Moorer, Daniel F.

    2012-06-01

    An elegant solution is proposed to an old problem of how to remove expired or malfunctioning satellites from the geosynchronous belt. Previous "space-tug" concepts describe a scenario where one craft (the tug) docks with another (debris) and then boosts that object to a super-synchronous orbit. The most challenging aspect of these concepts is the very complex proximity operations to an aging, possibly rotating and, probably, non-cooperative satellite. Instead, the proposed method uses an elegant blend of electrostatic charge control and low-thrust propulsion to avoid any contact requirement. The Geosynchronous Large Debris Reorbiter (GLiDeR) uses active charge emission to raise its own absolute potential to 10's of kilovolts and, in addition, directs a stream of charged particles at the debris to increase its absolute potential. In a puller configuration the opposite polarity of the debris creates an attractive force between the GLiDeR and the debris. Pusher configurations are feasible as well. Next, fuel-efficient micro-thrusters are employed to gently move the reorbiter relative to the debris, and then accelerate the debris out of its geosynchronous slot and deposit it in a disposal orbit. Preliminary analysis shows that a 1000 kg debris object can be re-orbited over two-four months. During the reorbit phase the separation distance is held nominally fixed without physical contact, even if the debris is tumbling, by actively controlling the charge transfer between the reorbiter and the debris. Numerical simulations are presented illustrating the expected performance, taking into account also the solar radiation pressure.

  14. Tracking Debris Shed by a Space-Shuttle Launch Vehicle

    NASA Technical Reports Server (NTRS)

    Stuart, Phillip C.; Rogers, Stuart E.

    2009-01-01

    The DEBRIS software predicts the trajectories of debris particles shed by a space-shuttle launch vehicle during ascent, to aid in assessing potential harm to the space-shuttle orbiter and crew. The user specifies the location of release and other initial conditions for a debris particle. DEBRIS tracks the particle within an overset grid system by means of a computational fluid dynamics (CFD) simulation of the local flow field and a ballistic simulation that takes account of the mass of the particle and its aerodynamic properties in the flow field. The computed particle trajectory is stored in a file to be post-processed by other software for viewing and analyzing the trajectory. DEBRIS supplants a prior debris tracking code that took .15 minutes to calculate a single particle trajectory: DEBRIS can calculate 1,000 trajectories in .20 seconds on a desktop computer. Other improvements over the prior code include adaptive time-stepping to ensure accuracy, forcing at least one step per grid cell to ensure resolution of all CFD-resolved flow features, ability to simulate rebound of debris from surfaces, extensive error checking, a builtin suite of test cases, and dynamic allocation of memory.

  15. Acoustic agglomeration of power plant fly ash for environmental and hot gas cleanup

    SciTech Connect

    Reethof, G.; Koopmann, G.H.

    1989-12-01

    This two year research program has the objectives of completing the several investigations associated with the use of high intensity acoustic energy to agglomerate micron and submicron sized particles in fly ash aerosols in order to provide the necessary scientific knowledge and design criteria for the specification of technically and economically viable intermediate flue gas treatment of coal fired power plants. Goals are to further the understanding of certain fundamental processes by means of theoretical and experimental investigations to include this knowledge in an advanced computerized model of the agglomeration processes. Tests with the acoustic agglomeration facilities available in Penn State's new High Intensity Acoustic Laboratory were to be used to verify the results from the acoustic agglomeration simulations. Research work continued on high power, high efficiency sirens with special emphasis on the nonlinear acoustic phenomena and novel means of significantly increasing siren efficiency. A study was carried out to evaluate the economics of conventional coal fired power plant clean-up systems using acoustic agglomeration as an intermediate flue gas treatment. 154 refs., 152 figs., 30 tabs.

  16. Debris dynamics under evection and inclination

    NASA Astrophysics Data System (ADS)

    Yokoyama, T.; Santos, M. T.; Celestino, C. C.; Winter, O. C.; Neto, E. V.; Cordeiro, R. R.

    The human activity in exploring the space has generated undesirable artificial debris Unfortunately the number of them is increasing so fast that a tremendous problem is arising The natural and artificial debris are distributed in a very large range of altitude and according to the semi major axis of the orbit the particle may survive for very long time For low altitude less than 200 km the life time of the particles is mostly dominated by the atmospheric drag while for more distant debris different disturbing forces should be considered and the dynamics is slight more complicated Although the maximum concentration of the debris is not at high altitude the problem at high altitudes is important since the mitigation mechanism to clean these regions is very slow Usually Poynting Robertson P-R effect and similar other forces are not efficient to remove rapidly the particles at high altitudes in opposition to human activities which are always feeding more rapidly almost any region of the space Therefore since the debris survive for very long time it is important to increase our theoretical knowledge on the dynamics of these regions In this work we show the existence of some important resonances which may give significant variations in the inclination and eccentricity of the particle In the case of the Earth they occur at about 10128 5 km and 12309 8 km and are related to a commensurability involving the mean longitude of the sun and

  17. Parametric analysis: SOC meteoroid and debris protection

    NASA Technical Reports Server (NTRS)

    Kowalski, R.

    1985-01-01

    The meteoroid and man made space debris environments of an Earth orbital manned space operations center are discussed. Protective shielding thickness and design configurations for providing given levels of no penetration probability were also calculated. Meteoroid/debris protection consists of a radiator/shield thickness, which is actually an outer skin, separated from the pressure wall, thickness by a distance. An ideal shield thickness, will, upon impact with a particle, cause both the particle and shield to vaporize, allowing a minimum amount of debris to impact the pressure wall itself. A shield which is too thick will crater on the outside, and release small particles of shield from the inside causing damage to the pressure wall. Inversely, if the shield is too thin, it will afford no protection, and the backup must provide all necessary protection. It was concluded that a double wall concept is most effective.

  18. Molecular mechanisms responsible for hydrate anti-agglomerant performance.

    PubMed

    Phan, Anh; Bui, Tai; Acosta, Erick; Krishnamurthy, Pushkala; Striolo, Alberto

    2016-09-28

    Steered and equilibrium molecular dynamics simulations were employed to study the coalescence of a sI hydrate particle and a water droplet within a hydrocarbon mixture. The size of both the hydrate particle and the water droplet is comparable to that of the aqueous core in reverse micelles. The simulations were repeated in the presence of various quaternary ammonium chloride surfactants. We investigated the effects due to different groups on the quaternary head group (e.g. methyl vs. butyl groups), as well as different hydrophobic tail lengths (e.g. n-hexadecyl vs. n-dodecyl tails) on the surfactants' ability to prevent coalescence. Visual inspection of sequences of simulation snapshots indicates that when the water droplet is not covered by surfactants it is more likely to approach the hydrate particle, penetrate the protective surfactant film, reach the hydrate surface, and coalesce with the hydrate than when surfactants are present on both surfaces. Force-distance profiles obtained from steered molecular dynamics simulations and free energy profiles obtained from umbrella sampling suggest that surfactants with butyl tripods on the quaternary head group and hydrophobic tails with size similar to the solvent molecules can act as effective anti-agglomerants. These results qualitatively agree with macroscopic experimental observations. The simulation results provide additional insights, which could be useful in flow assurance applications: the butyl tripod provides adhesion between surfactants and hydrates; when the length of the surfactant tail is compatible with that of the hydrocarbon in the liquid phase a protective film can form on the hydrate; however, once a molecularly thin chain of water molecules forms through the anti-agglomerant film, connecting the water droplet and the hydrate, water flows to the hydrate and coalescence is inevitable.

  19. Method for providing improved solid fuels from agglomerated subbituminous coal

    DOEpatents

    Janiak, Jerzy S.; Turak, Ali A.; Pawlak, Wanda; Ignasiak, Boleslaw L.

    1989-01-01

    A method is provided for separating agglomerated subbituminous coal and the heavy bridging liquid used to form the agglomerates. The separation is performed by contacting the agglomerates with inert gas or steam at a temperature in the range of 250.degree. to 350.degree. C. at substantially atmospheric pressure.

  20. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, January 1--March 31, 1993

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-04-01

    We are investigating the use of a hybrid process, Micro-agglomerate flotation, which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload and water/mineral carryover should be significantly alleviated.Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  1. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, September 30--December 31, 1992

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-01-01

    We are investigating the use of a hybrid process - Micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 {mu}m in size) rather than individual coal particles (1--10 {mu}m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  2. Get More Out of Your Data: A New Approach to Agglomeration and Aggregation Studies Using Nanoparticle Impact Experiments

    PubMed Central

    Ellison, Joanna; Tschulik, Kristina; Stuart, Emma J E; Jurkschat, Kerstin; Omanović, Dario; Uhlemann, Margitta; Crossley, Alison; Compton, Richard G

    2013-01-01

    Anodic particle coloumetry is used to size silver nanoparticles impacting a carbon microelectrode in a potassium chloride/citrate solution. Besides their size, their agglomeration state in solution is also investigated solely by electrochemical means and subsequent data analysis. Validation of this new approach to nanoparticle agglomeration studies is performed by comparison with the results of a commercially available nanoparticle tracking analysis system, which shows excellent agreement. Moreover, it is demonstrated that the electrochemical technique has the advantage of directly yielding the number of atoms per impacting nanoparticle irrespective of its shape. This is not true for the optical nanoparticle tracking system, which requires a correction for the nonspherical shape of agglomerated nanoparticles to derive reasonable information on the agglomeration state. PMID:24551537

  3. A proposed in situ debris measurement in GEO

    NASA Astrophysics Data System (ADS)

    Opiela, J.; Liou, J.; Stansbery, E.

    Unlike the low Earth o bit (LEO) region, the geosynchronous Earth orbit (GEO)r debris environment is not well characterized. Since there is no natural mechanism to remove debris from GEO, where atmospheric drag is negligible, the GEO debris population will continue to grow. A good environment definition is needed for GEO satellite designers and operators to have reliable debris impact risk assessments and protection for their satellites. The current, general debris mitigation and protection measures may be applied to GEO satellites, but characterizing the GEO debris environment (flux, size distribution, orbit distribution, sources) will also allow measures tailored specifically for that environment. Ground-based GEO optical measurements in general have been limited to objects greater than about 15 cm. It is highly unlikely that any ground-based telescope can detect GEO debris smaller than 1 cm. In situ measurements are required to characterize the particle environment below the threshold of remote sensors. Firsthand knowledge of the untrackable debris population is critical to GEO environment definition. Two specific issues need to be addressed for any effective in situ measurements in GEO: detector type and potential contamination from interplanetary and interstellar dust. In this paper, we will discuss why the polyvinylidene fluoride (PVDF) material makes an ideal GEO debris detector. We will also show that impacts from debris, interplanetary dust, and interstellar dust are very different in many ways (size, impact speed, flux, etc). Debris impacts can be easily distinguished from other impacts.

  4. The fast debris evolution model

    NASA Astrophysics Data System (ADS)

    Lewis, H. G.; Swinerd, G. G.; Newland, R. J.; Saunders, A.

    2009-09-01

    The 'particles-in-a-box' (PIB) model introduced by Talent [Talent, D.L. Analytic model for orbital debris environmental management. J. Spacecraft Rocket, 29 (4), 508-513, 1992.] removed the need for computer-intensive Monte Carlo simulation to predict the gross characteristics of an evolving debris environment. The PIB model was described using a differential equation that allows the stability of the low Earth orbit (LEO) environment to be tested by a straightforward analysis of the equation's coefficients. As part of an ongoing research effort to investigate more efficient approaches to evolutionary modelling and to develop a suite of educational tools, a new PIB model has been developed. The model, entitled Fast Debris Evolution (FADE), employs a first-order differential equation to describe the rate at which new objects ⩾10 cm are added and removed from the environment. Whilst Talent [Talent, D.L. Analytic model for orbital debris environmental management. J. Spacecraft Rocket, 29 (4), 508-513, 1992.] based the collision theory for the PIB approach on collisions between gas particles and adopted specific values for the parameters of the model from a number of references, the form and coefficients of the FADE model equations can be inferred from the outputs of future projections produced by high-fidelity models, such as the DAMAGE model. The FADE model has been implemented as a client-side, web-based service using JavaScript embedded within a HTML document. Due to the simple nature of the algorithm, FADE can deliver the results of future projections immediately in a graphical format, with complete user-control over key simulation parameters. Historical and future projections for the ⩾10 cm LEO debris environment under a variety of different scenarios are possible, including business as usual, no future launches, post-mission disposal and remediation. A selection of results is presented with comparisons with predictions made using the DAMAGE environment model

  5. Encapsulation of hazardous wastes into agglomerates

    SciTech Connect

    Guloy, A.

    1992-01-28

    The objective of this study was to investigate the feasibility of using the cementitious properties and agglomeration characteristics of coal conversion byproducts to encapsulate and immobilize hazardous waste materials. The intention was to establish an economical way of co-utilization and co-disposal of wastes. In addition, it may aid in the eradication of air pollution problems associated with the fine-powdery nature of fly ash. Encapsulation into agglomerates is a novel approach of treating toxic waste. Although encapsulation itself is not a new concept, existing methods employ high-cost resins that render them economically unfeasible. In this investigation, the toxic waste was contained in a concrete-like matrix whereby fly ash and other cementitious waste materials were utilized. The method incorporates the principles of solidification, stabilization and agglomeration. Another aspect of the study is the evaluation of the agglomeration as possible lightweight aggregates. Since fly ash is commercially used as an aggregate, it would be interesting to study the effect of incorporating toxic wastes in the strength development of the granules. In the investigation, the fly ash self-cementation process was applied to electroplating sludges as the toxic waste. The process hoped to provide a basis for delisting of the waste as hazardous and, thereby greatly minimize the cost of its disposal. Owing to the stringent regulatory requirements for hauling and disposal of hazardous waste, the cost of disposal is significant. The current practice for disposal is solidifying the waste with portland cement and dumping the hardened material in the landfill where the cost varies between $700--950/ton. Partially replacing portland cement with fly ash in concrete has proven beneficial, therefore applying the same principles in the treatment of toxic waste looked very promising.

  6. Orbital Debris and NASA's Measurement Program

    NASA Astrophysics Data System (ADS)

    Africano, J. L.; Stansbery, E. G.

    2002-05-01

    Since the launch of Sputnik in 1957, the number of manmade objects in orbit around the Earth has dramatically increased. The United States Space Surveillance Network (SSN) tracks and maintains orbits on over nine thousand objects down to a limiting diameter of about ten centimeters. Unfortunately, active spacecraft are only a small percentage ( ~ 7%) of this population. The rest of the population is orbital debris or ``space junk" consisting of expended rocket bodies, dead payloads, bits and pieces from satellite launches, and fragments from satellite breakups. The number of these smaller orbital debris objects increases rapidly with decreasing size. It is estimated that there are at least 130,000 orbital debris objects between one and ten centimeters in diameter. Most objects smaller than 10 centimeters go untracked! As the orbital debris population grows, the risk to other orbiting objects, most importantly manned space vehicles, of a collision with a piece of debris also grows. The kinetic energy of a solid 1 cm aluminum sphere traveling at an orbital velocity of 10 km/sec is equivalent to a 400 lb. safe traveling at 60 mph. Fortunately, the volume of space in which the orbiting population resides is large, collisions are infrequent, but they do occur. The Space Shuttle often returns to earth with its windshield pocked with small pits or craters caused by collisions with very small, sub-millimeter-size pieces of debris (paint flakes, particles from solid rocket exhaust, etc.), and micrometeoroids. To get a more complete picture of the orbital-debris environment, NASA has been using both radar and optical techniques to monitor the orbital debris environment. This paper gives an overview of the orbital debris environment and NASA's measurement program.

  7. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Chander, S.; Hogg, R.

    1995-04-01

    The development of practical technologies for the deep cleaning of coal has been seriously hampered by the problems of carrying out efficient coal/mineral separations at the very fine sizes (often finer than 10 mm) needed to achieve adequate liberation of the mineral matter from the coal matrix. In froth flotation, selectivity is substantially reduced at fine sizes due, primarily, to overloading of the froth phase which leads to excessive carryover of water and entrained mineral matter. Oil agglomeration, on the other hand, can provide good selectivity at low levels of oil addition but the agglomerates tend to be too fragile for separation by the screening methods normally used. The addition of larger amounts of oil can yield large, strong agglomerates which are easily separated but the selectivity is reduced and reagent costs can become excessive. We are investigating the use of a hybrid process - Micro-agglomerate flotation which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30-50 mm in size) rather than individual coal particles (1-10 mm) the problems of froth overload and water/mineral carryover should be significantly alleviated. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  8. Optical orbital debris spotter

    NASA Astrophysics Data System (ADS)

    Englert, Christoph R.; Bays, J. Timothy; Marr, Kenneth D.; Brown, Charles M.; Nicholas, Andrew C.; Finne, Theodore T.

    2014-11-01

    The number of man-made debris objects orbiting the Earth, or orbital debris, is alarmingly increasing, resulting in the increased probability of degradation, damage, or destruction of operating spacecraft. In part, small objects (<10 cm) in Low Earth Orbit (LEO) are of concern because they are abundant and difficult to track or even to detect on a routine basis. Due to the increasing debris population it is reasonable to assume that improved capabilities for on-orbit damage attribution, in addition to increased capabilities to detect and track small objects are needed. Here we present a sensor concept to detect small debris with sizes between approximately 1.0 and 0.01 cm in the vicinity of a host spacecraft for near real time damage attribution and characterization of dense debris fields and potentially to provide additional data to existing debris models.

  9. Agglomerating combustor-gasifier method and apparatus for coal gasification

    DOEpatents

    Chen, Joseph L. P.; Archer, David H.

    1976-09-21

    A method and apparatus for gasifying coal wherein the gasification takes place in a spout fluid bed at a pressure of about 10 to 30 atmospheres and a temperature of about 1800.degree. to 2200.degree.F and wherein the configuration of the apparatus and the manner of introduction of gases for combustion and fluidization is such that agglomerated ash can be withdrawn from the bottom of the apparatus and gas containing very low dust loading is produced. The gasification reaction is self-sustaining through the burning of a stoichiometric amount of coal with air in the lower part of the apparatus to form the spout within the fluid bed. The method and apparatus are particularly suitable for gasifying coarse coal particles.

  10. Investigations on Agglomeration and Haemocompatibility of Vitamin E TPGS Surface Modified Berberine Chloride Nanoparticles

    PubMed Central

    Vuddanda, Parameswara Rao; Rajamanickam, Vijayakumar Mahalingam; Yaspal, Madhu; Singh, Sanjay

    2014-01-01

    The objective of the present study is to investigate the influence of surface modification on systemic stability of NPs. Vitamin E TPGS (1% w/v) was used for surface modification of berberine chloride nanoparticles. Naked and surface modified NPs were incubated in different SBFs (pH 6.8 and 7.4) with or without bile salts and human plasma. NPs were observed for particle agglomeration and morphology by particle size analyzer and TEM, respectively. The haemocompatibility studies were conducted on developed NPs to evaluate their safety profile. The surface modified NPs were stable compared to naked NPs in different SBFs due to the steric stabilization property of vitamin E TPGS. Particle agglomeration was not seen when NPs were incubated in SBF (pH 6.8) with bile salts. No agglomeration was observed in NPs after their incubation in plasma but particle size of the naked NPs increased due to adhesion of plasma proteins. The TEM images confirmed the particle size results. DSC and FT-IR studies confirmed the coexistence of TPGS in surface modified NPs. The permissible haemolysis, LDH release, and platelet aggregation revealed that NPs were compatible for systemic administration. Thus, the study illustrated that the surface modification is helpful in the maintenance of stability of NPs in systemic conditions. PMID:25162037

  11. Control of nanoparticle agglomeration through variation of the time-temperature profile in chemical vapor synthesis

    NASA Astrophysics Data System (ADS)

    Djenadic, Ruzica; Winterer, Markus

    2017-02-01

    The influence of the time-temperature history on the characteristics of nanoparticles such as size, degree of agglomeration, or crystallinity is investigated for chemical vapor synthesis (CVS). A simple reaction-coagulation-sintering model is used to describe the CVS process, and the results of the model are compared to experimental data. Nanocrystalline titania is used as model material. Titania nanoparticles are generated from titanium-tetraisopropoxide (TTIP) in a hot-wall reactor. Pure anatase particles and mixtures of anatase, rutile (up to 11 vol.%), and brookite (up to 29 vol.%) with primary particle sizes from 1.7 nm to 10.5 nm and agglomerate particle sizes from 24.3 nm to 55.6 nm are formed depending on the particle time-temperature history. An inductively heated furnace with variable inductor geometry is used as a novel system to control the time-temperature profile in the reactor externally covering a large wall temperature range from 873 K to 2023 K. An appropriate choice of inductor geometry, i.e. time-temperature profile, can significantly reduce the degree of agglomeration. Other particle characteristics such as crystallinity are also substantially influenced by the time-temperature profile.

  12. Space debris detection and mitigation

    SciTech Connect

    Allahdadi, F.

    1993-01-01

    Space debris is defined as all useless man-made objects in space. This conference covers the following areas: debris detection, tracking, and surveillance; orbital debris analytical modeling; debris environment and safety issues; and orbital debris mitigation. Separate abstracts were prepared for 26 papers in this conference.

  13. Overview of the space debris environment

    NASA Astrophysics Data System (ADS)

    Meshishnek, M. J.

    1995-03-01

    There is a component of the space environment that is man-made pollution, termed 'space debris' it exists at all inclinations and, primarily, at altitudes of roughly 350 km to 2000 km. The size of this debris ranges from several meters to a fraction of a micrometer in diameter, and the particle distribution follows an inverse power law, with the smaller size component far exceeding that of the larger. Debris is composed primarily of alumina from solid rocket motor exhausts, aluminum from spacecraft structures, and zinc and titanium oxides from thermal control coatings. The accepted model of the space debris environment is that of Kessler et al., a complex model that predicts the number of particles that will impact a surface as a function of altitude, inclination, solar cycle, and particle diameter, as well as their collision velocities. Recent data from LDEF has demonstrated both the accuracy and shortcomings of the Kessler model. Measured debris impactor fluxes are in good agreement with the model for ram surfaces. However, predictions of the model for other surfaces of a spacecraft are less accurate, most notably for the wake or trailing side. While the Kessler model is appropriate for long-term, average flux predictions, spatial-temporal impact fluxes measured on LDEF dramatically illustrated the presence of strong debris clouds that do not dissipate quickly in space and will encounter an orbiting spacecraft cyclically and repeatedly over its lifetime. LDEF data has also indicated the presence of debris in elliptical orbits, a fact not predicted by the Kessler model. This fact is responsible for the discrepancy between measured impact fluxes and predictions on trailing edge surfaces.

  14. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.D.

    1993-04-01

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed boilers is in progress. Preliminary results indicate that at least five boilers were experiencing some form of bed material agglomeration. In these instances it was observed that large particles were forming within the bed which were larger that the feed. Four operators could confirm that the larger bed particles had formed due to bed particles sticking together or agglomerating. Deposit formation was reported at nine sites with these deposits being found most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Examples of these agglomerates and deposits have been received from five of the surveyed facilities. Also during this quarter, a bulk sample of Illinois No. 6 coal was obtained from the Fossil Energy Program at Ames Laboratory here at Iowa State University and prepared for combustion tests. This sample was first ground to a top-size of 3/8`` using a jaw crusher then a size fraction of 3/8`` {times} 8 (US mesh) was then obtained by sieving using a Gilson Test-Master. This size fraction was selected for the preliminary laboratory-scale experiments designed to simulate the dense bed conditions that exist in the bottom of CFB combustors. To ensure uniformity of fuel composition among combustion runs, the sized coal was riffled using, a cone and long row method and stored in bags for each experiment. During this quarter additional modifications were made to achieve better control of fluidization regimes and to aid in monitoring the hydrodynamic and chemical conditions within the reactor.

  15. Prospects for Observing Space Debris with Solar Coronagraphs

    DTIC Science & Technology

    1994-04-07

    mode designed to detect orbital debris . II 4- Coronagraph -2or -2- /• -. 0.001 s -4- -6. . . . . . -3 -2 -1 0 1 Log a (cm) Figure 1. Per-pixel signal...velocities of orbital debris and the typical direction and fast transit times of nearby particles under strong wind conditions, or random and nonlinear

  16. Basic principles and mechanisms of selective oil agglomeration. Fossil energy interim report, October 1, 1983--September 30, 1992

    SciTech Connect

    Wheelock, T.D.

    1992-12-31

    Numerous agglomeration tests were conducted with several types of low-ash coal and graphite, high grade mineral pyrite, and other materials. Relatively pure hydrocarbons, including heptane and hexadecane, were used as agglomerants. Access of air to the system was controlled. Particle recovery by agglomeration was observed to depend on a number of system parameters. Among the most important parameters are the hydrophobicity of the particles and the oil dosage, so that the, recovery of solids per unit of oil administered is proportional to the hydrophobicity. The pH and ionic strength of the aqueous suspension affect particle recovery in different ways depending on the surface properties of the particles. On the other hand, the presence of air in the system generally improves particle recovery. The greatest effect of air was observed in a closely related study which showed that air had to be present to produce good agglomerates from a moderately hydrophobic coal in a mixer producing a lower shear rate. The rate of agglomeration was found to be much greater for a strongly hydrophobic coal than for a moderately hydrophobic coal, and the rate was observed to be proportional to the oil dosage. Also the rate was enhanced by the presence of air in the, system. For hydrophobic coals, the rate increased with increasing ionic strength of the aqueous medium, but it was not affected greatly by pH over a wide range. The separation of coal and pyrite particles by selective agglomeration was found to depend on the relative hydrophobicity of the materials, the oil dosage, and the properties of the aqueous medium.

  17. Agglomeration in Stripper Ash Coolers and Its Possible Remedial Solutions: a Case Study

    NASA Astrophysics Data System (ADS)

    Singh, Ravi Inder

    2016-04-01

    The bottom ash of circulating fluidized bed (CFB) boiler contains large amounts of physical heat. When low quality coals are used in these types of boilers, the ash content is normally more than 40 % and the physical heat loss is approximately 3 % if the bottom ash is discharged without cooling. Bottom ash cooler (BAC) is often used to treat the high temperature bottom ash to reclaim heat, and to facilitate the easily handling and transportation of ash. The CFB boiler at BLA Power, Newari, MP (India) is facing problems of clinker formation in strip ash coolers of plant since the installation of unit. These clinkers are basically agglomerates, which leads to defluidization of stripper ash cooler (BAC) units. There are two strip ash coolers in unit. Each strip ash cooler is capable of working independently. The proper functioning of both strip coolers is very important as it is going to increase the combustion efficiency of boiler by stripping of fine unburnt coal particles from ash, which are injected into the furnace. In this paper causes, characterization of agglomerates, thermo gravimetric analysis of fuel used, particular size distribution of coal and sand and possible remedial solution to overcome these agglomerates in strip ash coolers has also been presented. High temperature in compact separators, non uniform supply of coal and not removing small agglomerates from stripper ash cooler are among main causes of agglomeration in stripper ash cooler. Control of compact separator temperature, replacing 10-12 % of bed material and cleaning stripper ash cooler periodically will decrease agglomeration in stripper ash cooler of unit.

  18. Procedures for analysis of debris relative to Space Shuttle systems

    NASA Technical Reports Server (NTRS)

    Kim, Hae Soo; Cummings, Virginia J.

    1993-01-01

    Debris samples collected from various Space Shuttle systems have been submitted to the Microchemical Analysis Branch. This investigation was initiated to develop optimal techniques for the analysis of debris. Optical microscopy provides information about the morphology and size of crystallites, particle sizes, amorphous phases, glass phases, and poorly crystallized materials. Scanning electron microscopy with energy dispersive spectrometry is utilized for information on surface morphology and qualitative elemental content of debris. Analytical electron microscopy with wavelength dispersive spectrometry provides information on the quantitative elemental content of debris.

  19. Intensive drying and the related microstructure features in agglomerate spheres

    NASA Astrophysics Data System (ADS)

    Kudlyk, Rostyslav

    Most metal ore concentrates are fine particulates with a wide particle-size distribution. Industrially they are pelletized by tumbling in balling discs or drums into spheres, an operation which requires the addition of typically up to 10% by weight of water. Further processing of these agglomerates involves first drying and then induration by heating up to 1250°C. The main objective of this thesis was the study of the interrelationship between the microstructure of the agglomerates with, on the one hand, the mechanical and physical properties of the pellets and their behaviour during intensive drying, on the other. The previously developed model of the drying process identified the loss of capillarity, resulting from the vapour lock, to be a critical component of the mechanism of intense as opposed to 'classical' drying. It was shown that the absence of the constant-rate drying period is a natural consequence of this effect. Several significant shortcomings of the previous model have been identified. This model treats the period of transition between surface- and shrinking-core drying as an instantaneous event. The new extended model, which overcomes the original model limitations, was developed in this project. In its formalism, the new model includes the pore-size distribution and thus simulates a gradual surface/shrinking-core transition. It was shown that the nature of the transition between the surface- and shrinking-core drying regimes during intensive drying is fundamentally different from that of classical drying, i.e. carried out at mild temperatures. In the latter case, liquid is being delivered to the surface through the network of interconnected small pores reaching the surface. The transition occurs when the larger pores, also reaching the surface, are being drained. On the other hand, under intense-drying conditions, the rate-limiting factor is the vapour lock. The latter phenomenon will occur in the smaller pores first, as they have smaller liquid

  20. Nucleocapsid Protein from Fig Mosaic Virus Forms Cytoplasmic Agglomerates That Are Hauled by Endoplasmic Reticulum Streaming

    PubMed Central

    Ishikawa, Kazuya; Miura, Chihiro; Maejima, Kensaku; Komatsu, Ken; Hashimoto, Masayoshi; Tomomitsu, Tatsuya; Fukuoka, Misato; Yusa, Akira; Yamaji, Yasuyuki

    2014-01-01

    ABSTRACT Although many studies have demonstrated intracellular movement of viral proteins or viral replication complexes, little is known about the mechanisms of their motility. In this study, we analyzed the localization and motility of the nucleocapsid protein (NP) of Fig mosaic virus (FMV), a negative-strand RNA virus belonging to the recently established genus Emaravirus. Electron microscopy of FMV-infected cells using immunogold labeling showed that NPs formed cytoplasmic agglomerates that were predominantly enveloped by the endoplasmic reticulum (ER) membrane, while nonenveloped NP agglomerates also localized along the ER. Likewise, transiently expressed NPs formed agglomerates, designated NP bodies (NBs), in close proximity to the ER, as was the case in FMV-infected cells. Subcellular fractionation and electron microscopic analyses of NP-expressing cells revealed that NBs localized in the cytoplasm. Furthermore, we found that NBs moved rapidly with the streaming of the ER in an actomyosin-dependent manner. Brefeldin A treatment at a high concentration to disturb the ER network configuration induced aberrant accumulation of NBs in the perinuclear region, indicating that the ER network configuration is related to NB localization. Dominant negative inhibition of the class XI myosins, XI-1, XI-2, and XI-K, affected both ER streaming and NB movement in a similar pattern. Taken together, these results showed that NBs localize in the cytoplasm but in close proximity to the ER membrane to form enveloped particles and that this causes passive movements of cytoplasmic NBs by ER streaming. IMPORTANCE Intracellular trafficking is a primary and essential step for the cell-to-cell movement of viruses. To date, many studies have demonstrated the rapid intracellular movement of viral factors but have failed to provide evidence for the mechanism or biological significance of this motility. Here, we observed that agglomerates of nucleocapsid protein (NP) moved rapidly

  1. Characterizing Secondary Debris Impact Ejecta

    NASA Technical Reports Server (NTRS)

    Schonberg, W. P.

    1999-01-01

    All spacecraft in low-Earth orbit are subject to high-speed impacts by meteoroids and orbital debris particles. These impacts can damage flight-critical systems which can in turn lead to catastrophic failure of the spacecraft. Therefore, the design of a spacecraft for an Earth-orbiting mission must take into account the possibility of such impacts and their effects on the spacecraft structure and on all of its exposed subsystem components. In addition to threatening the operation of the spacecraft itself, on-orbit impacts also generate a significant amount of ricochet particles. These high-speed particles can destroy critical external spacecraft subsystem and also increase the contamination of the orbital environment. This report presents a summary of the work performed towards the development of an empirical model that characterizes the secondary ejecta created by a high-speed impacta on a typical aerospace structural surface.

  2. BINARIES AMONG DEBRIS DISK STARS

    SciTech Connect

    Rodriguez, David R.; Zuckerman, B.

    2012-02-01

    We have gathered a sample of 112 main-sequence stars with known debris disks. We collected published information and performed adaptive optics observations at Lick Observatory to determine if these debris disks are associated with binary or multiple stars. We discovered a previously unknown M-star companion to HD 1051 at a projected separation of 628 AU. We found that 25% {+-} 4% of our debris disk systems are binary or triple star systems, substantially less than the expected {approx}50%. The period distribution for these suggests a relative lack of systems with 1-100 AU separations. Only a few systems have blackbody disk radii comparable to the binary/triple separation. Together, these two characteristics suggest that binaries with intermediate separations of 1-100 AU readily clear out their disks. We find that the fractional disk luminosity, as a proxy for disk mass, is generally lower for multiple systems than for single stars at any given age. Hence, for a binary to possess a disk (or form planets) it must either be a very widely separated binary with disk particles orbiting a single star or it must be a small separation binary with a circumbinary disk.

  3. Orbiting Space Debris: Dangers, Measurement and Mitigation

    DTIC Science & Technology

    1992-06-01

    sure how many undetectable particles the fragmentation of a satellite creates. Actual ground-based tesis have been conducted in an attempt to...conducted by the Jet Propulsion Laboratory lo measure the presence of 0.2 lo 0.5 cm and 0.5 to 2 cm sized debris. The Areclbo radar in Puerto Rico

  4. Chemiluminescence in the Agglomeration of Metal Clusters

    PubMed

    König; Rabin; Schulze; Ertl

    1996-11-22

    The agglomeration of copper or silver atoms in a matrix of noble gas atoms to form small clusters may be accompanied by the emission of visible light. Spectral analysis reveals the intermediate formation of electronically excited atoms and dimers as the source of the chemiluminescence. A mechanism is proposed, according to which the gain in binding energy upon cluster formation may even lead to the ejection of excited fragments as a result of unstable intermediate configurations. A similar concept was introduced in the field of nuclear reactions by Niels Bohr 60 years ago.

  5. Controlling Agglomeration of Protein Aggregates for Structure Formation in Liquid Oil: A Sticky Business

    PubMed Central

    2017-01-01

    Proteins are known to be effective building blocks when it comes to structure formation in aqueous environments. Recently, we have shown that submicron colloidal protein particles can also be used to provide structure to liquid oil and form so-called oleogels (de VriesA.J. Colloid Interface Sci.2017, 486, 75−83)27693552. To prevent particle agglomeration, a solvent exchange procedure was used to transfer the aggregates from water to the oil phase. The aim of the current paper was to elucidate on the enhanced stability against agglomeration of heat-set whey protein isolate (WPI) aggregates to develop an alternative for the solvent exchange procedure. Protein aggregates were transferred from water to several solvents differing in polarity to investigate the effect on agglomeration and changes in protein composition. We show that after drying protein aggregates by evaporation from solvents with a low polarity (e.g., hexane), the protein powder shows good dispersibility in liquid oil compared to powders dried from solvents with a high polarity. This difference in dispersibility could not be related to changes in protein composition or conformation but was instead related to the reduction of attractive capillary forces between the protein aggregates during drying. Following another route, agglomeration was also prevented by applying high freezing rates prior to freeze-drying. The rheological properties of the oleogels prepared with such freeze-dried protein aggregates were shown to be similar to that of oleogels prepared using a solvent exchange procedure. This Research Article provides valuable insights in how to tune the drying process to control protein agglomeration to allow for subsequent structure formation of proteins in liquid oil. PMID:28225592

  6. Controlling Agglomeration of Protein Aggregates for Structure Formation in Liquid Oil: A Sticky Business.

    PubMed

    de Vries, Auke; Lopez Gomez, Yuly; Jansen, Bas; van der Linden, Erik; Scholten, Elke

    2017-03-22

    Proteins are known to be effective building blocks when it comes to structure formation in aqueous environments. Recently, we have shown that submicron colloidal protein particles can also be used to provide structure to liquid oil and form so-called oleogels ( de Vries , A. J. Colloid Interface Sci. 2017 , 486 , 75 - 83 ) . To prevent particle agglomeration, a solvent exchange procedure was used to transfer the aggregates from water to the oil phase. The aim of the current paper was to elucidate on the enhanced stability against agglomeration of heat-set whey protein isolate (WPI) aggregates to develop an alternative for the solvent exchange procedure. Protein aggregates were transferred from water to several solvents differing in polarity to investigate the effect on agglomeration and changes in protein composition. We show that after drying protein aggregates by evaporation from solvents with a low polarity (e.g., hexane), the protein powder shows good dispersibility in liquid oil compared to powders dried from solvents with a high polarity. This difference in dispersibility could not be related to changes in protein composition or conformation but was instead related to the reduction of attractive capillary forces between the protein aggregates during drying. Following another route, agglomeration was also prevented by applying high freezing rates prior to freeze-drying. The rheological properties of the oleogels prepared with such freeze-dried protein aggregates were shown to be similar to that of oleogels prepared using a solvent exchange procedure. This Research Article provides valuable insights in how to tune the drying process to control protein agglomeration to allow for subsequent structure formation of proteins in liquid oil.

  7. Experimental Evaluation of the Effect of Pad Debris Size on Microscratches during CMP Process

    NASA Astrophysics Data System (ADS)

    Yang, Ji Chul; Kim, Hojoong; Oh, Dong Won; Won, Jai-Hyung; Lee, Chil-Gee; Kim, Taesung

    2013-01-01

    Polishing debris generated by pad surface conditioning has been suspected as a major source of microscratches in the chemical-mechanical planarization (CMP) process. In this study, we investigated the pad debris generated by an in situ conditioning process during oxide CMP as one of the major scratch sources. We evaluated the relationship between the size of pad debris and the shape of microscratches on a wafer to find the cause of scratches. Pad debris was gathered in real time during the polishing process. Then, by transmission electron microscopy we observed a mixed layer of pad material and abrasive particles on the surface of the pad debris and the pad surface, which hardened the pad debris and pad surface. The results reveal a size range of pad debris that led to a minimum scratch count. Pad debris size smaller or larger than the minimum scratch region seems to cause higher scratch count due to the hardened pad surface and pad debris.

  8. Spectroscopy of Non-Agglomerated Particles in the Condensed Phase

    DTIC Science & Technology

    1988-02-01

    monochromator passes through the cold ringer ofI the iford Instruments Corporation continuous-flow cryostat. which holds a saphire (or other) substrate...about 10 4, 44 S... ... • . .......... . . . i ....... • _ .. ... i " . % %"*’- . .... " : " - " "- ’ " . . K. argon gas is flowed onto the saphire

  9. Substructure of Titanium Dioxide Agglomerates from Dry Ball-milling Experiments

    NASA Astrophysics Data System (ADS)

    Gesenhues, Ulrich

    1999-06-01

    The calciner discharge of TiO2 white pigments from the sulphate process is ground batchwise in a planetary ball mill, varying the energy of comminution between 0 and 5.1 times the earth's gravitational constant. Particle sizes and specific surfaces of the ground products reveal that the calciner discharge consists of aggregates of 430 nm diameter built from 160-210 nm TiO2 crystals. The contact area of a primary particle in an aggregate is about 15% of its surface. The success in comminution of aggregates as a function of grinding energy follows Kick's law. The theory by Rose and Weichert is used to quantify the mechanical strength of the aggregates. Ca. 20% of the aggregates are further agglomerated to granules of ca. 35 µm. At all energy levels above a certain threshold, agglomerates break directly into aggregates.

  10. Apparatus and method for compacting, degassing and carbonizing carbonaceous agglomerates

    SciTech Connect

    Theodore, F.W.

    1980-08-19

    An apparatus for compacting, degassing and carbonizing carbonaceous agglomerates is described. The apparatus comprises a rotary kiln having an agglomerate inlet means for introducing green agglomerates into the kiln near the inlet of the kiln and a heating medium inlet for introducing a heating medium comprising a finely divided solid into the kiln at a preselected location intermediate the inlet end of the kiln and the outlet end of the kiln to produce a mixture at a temperature above the carbonizing temperature of the agglomerates and a sieve positioned to receive the products from the rotary kiln and separate the heating medium and the compacted, degassed, carbonized agglomerate product. A method for producing compacted, degassed, carbonized carbonaceous agglomerates by the use of the apparatus is also disclosed.

  11. Charging of Space Debris and Their Dynamical Consequences

    DTIC Science & Technology

    2016-01-08

    particle beams associated with solar flares. The PIC approach has also been used to study differential charging of debris objects that are composed of...gravitational and solar radiation pressure effects and hence may have a negligible influence on orbital calculations. However the debris charge can give...photoemission effects as well as due to the impact of energetic charged particle beams associated with solar flares. The PIC approach has also been

  12. New surfactant for hydrate anti-agglomeration in hydrocarbon flowlines and seabed oil capture.

    PubMed

    Sun, Minwei; Firoozabadi, Abbas

    2013-07-15

    Anti-agglomeration is a promising solution for gas hydrate risks in deepsea hydrocarbon flowlines and oil leak captures. Currently ineffectiveness at high water to oil ratios limits such applications. We present experimental results of a new surfactant in rocking cell tests, which show high efficiency at a full range of water to oil ratios; there is no need for presence of the oil phase. We find that our surfactant at a very low concentration (0.2 wt.% of water) keeps the hydrate particles in anti-agglomeration state. We propose a mechanism different from the established water-in-oil emulsion theory in the literature that the process is effective without the oil phase. There is no need to emulsify the water phase in the oil phase for hydrate anti-agglomeration; with oil-in-water emulsion and without emulsion hydrate anti-agglomeration is presented in our research. We expect our work to pave the way for broad applications in offshore natural gas production and seabed oil capture with very small quantities of an eco-friendly surfactant.

  13. Spherical agglomerates of pure drug nanoparticles for improved pulmonary delivery in dry powder inhalers

    NASA Astrophysics Data System (ADS)

    Hu, Jun; Dong, Yuancai; Pastorin, Giorgia; Ng, Wai Kiong; Tan, Reginald B. H.

    2013-04-01

    The aim of this study was to produce micron-sized spherical agglomerates of pure drug nanoparticles to achieve improved aerosol performance in dry powder inhalers (DPIs). Sodium cromoglicate was chosen as the model drug. Pure drug nanoparticles were prepared through a bottom-up particle formation process, liquid antisolvent precipitation, and then rapidly agglomerated into porous spherical microparticles by immediate (on-line) spray drying. Nonporous spherical drug microparticles with similar geometric size distribution were prepared by conventional spray drying of the aqueous drug solution, which together with the mechanically micronized drug particles were used as the control samples. The three samples were characterized by field emission scanning electron microscopy, laser diffraction, Brunauer-Emmett-Teller analysis, density measurement, powder X-ray diffraction, and in vitro aerosol deposition measurement with a multistage liquid impinger. It was found that drug nanoparticles with a diameter of 100 nm were precipitated and agglomerated into highly porous spherical microparticles with a volume median diameter ( D 50 %) of 2.25 ± 0.08 μm and a specific surface area of 158.63 ± 3.27 m2/g. In vitro aerosol deposition studies showed the fine particle fraction of such spherical agglomerates of drug nanoparticles was increased by more than 50 % in comparison with the control samples, demonstrating significant improvements in aerosol performance. The results of this study indicated the potential of the combined particle engineering process of liquid antisolvent precipitation followed by immediate (on-line) spray drying in the development of novel DPI drug products with improved aerosol performance.

  14. Modeling debris-covered glaciers: response to steady debris deposition

    NASA Astrophysics Data System (ADS)

    Anderson, Leif S.; Anderson, Robert S.

    2016-05-01

    Debris-covered glaciers are common in rapidly eroding alpine landscapes. When thicker than a few centimeters, surface debris suppresses melt rates. If continuous debris cover is present, ablation rates can be significantly reduced leading to increases in glacier length. In order to quantify feedbacks in the debris-glacier-climate system, we developed a 2-D long-valley numerical glacier model that includes englacial and supraglacial debris advection. We ran 120 simulations on a linear bed profile in which a hypothetical steady state debris-free glacier responds to a step increase of surface debris deposition. Simulated glaciers advance to steady states in which ice accumulation equals ice ablation, and debris input equals debris loss from the glacier terminus. Our model and parameter selections can produce 2-fold increases in glacier length. Debris flux onto the glacier and the relationship between debris thickness and melt rate strongly control glacier length. Debris deposited near the equilibrium-line altitude, where ice discharge is high, results in the greatest glacier extension when other debris-related variables are held constant. Debris deposited near the equilibrium-line altitude re-emerges high in the ablation zone and therefore impacts melt rate over a greater fraction of the glacier surface. Continuous debris cover reduces ice discharge gradients, ice thickness gradients, and velocity gradients relative to initial debris-free glaciers. Debris-forced glacier extension decreases the ratio of accumulation zone to total glacier area (AAR). Our simulations reproduce the "general trends" between debris cover, AARs, and glacier surface velocity patterns from modern debris-covered glaciers. We provide a quantitative, theoretical foundation to interpret the effect of debris cover on the moraine record, and to assess the effects of climate change on debris-covered glaciers.

  15. Method for recovering light hydrocarbons from coal agglomerates

    DOEpatents

    Huettenhain, Horst; Benz, August D.; Getsoian, John

    1991-01-01

    A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

  16. Development and Application of Agglomerated Multigrid Methods for Complex Geometries

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.

    2010-01-01

    We report progress in the development of agglomerated multigrid techniques for fully un- structured grids in three dimensions, building upon two previous studies focused on efficiently solving a model diffusion equation. We demonstrate a robust fully-coarsened agglomerated multigrid technique for 3D complex geometries, incorporating the following key developments: consistent and stable coarse-grid discretizations, a hierarchical agglomeration scheme, and line-agglomeration/relaxation using prismatic-cell discretizations in the highly-stretched grid regions. A signi cant speed-up in computer time is demonstrated for a model diffusion problem, the Euler equations, and the Reynolds-averaged Navier-Stokes equations for 3D realistic complex geometries.

  17. Experimental and numerical study on the optical properties and agglomeration of nanoparticle suspensions

    NASA Astrophysics Data System (ADS)

    Otanicar, Todd; Hoyt, Jordan; Fahar, Maryam; Jiang, Xuchuan; Taylor, Robert A.

    2013-11-01

    Nanoparticles have garnered significant interest because of their ability to enhance greatly the optical properties of the base fluid in which they are suspended. The optical properties of nanoparticles are sensitive to the materials used, as well as to the host medium. Most fluids exhibit refractive indices that are highly temperature-dependent, resulting in nanoparticle suspensions which also exhibit temperature-dependent optical properties. Previous work has shown that temperature increases result in decreased absorption in nanoparticle suspensions. Here, we expand previous work to include core-shell particles due to the potential spectral shifts in optical properties that will arise from the base fluid with temperature changes and the role of agglomeration under temperature cycling through both experimental and numerical efforts. Thermal cycling tests for silica and gold, the constituents of the core-shell nanoparticles used in this study, were tested to determine the extent of particle agglomeration resulting from up to 200 accelerated heating cycles. Optical properties were recorded after heating two base fluids (water and ethylene glycol) with multiple surfactants for silver nanospheres and silica-gold core-shell nanoparticles. It was found that the temperature results in a small increase in the transmittance for both particle types and a blue shift in the spectral transmittance for core-shell nanoparticles. Further, the coupling effect of temperature and agglomeration played a significant role in determining both the spectral properties—particularly the resulting transmittance—of the silver nanoparticle suspensions.

  18. Development of a gas-promoted oil agglomeration process. Quarterly technical progress report, October 1--December 31, 1995

    SciTech Connect

    Wheelock, T.D.

    1996-07-01

    The overall purpose of this research project is to carry out the preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal using model mixing systems. Specific objectives include determining the nature of the gas promotion mechanism, the effects of hydrodynamic factors and key parameters on process performance, and a suitable basis for size scale-up of the mixing system. An investigation of the phenomena which occur during the oil agglomeration of coal particle suspensions showed that the process of agglomeration involves several step which can be identified by changes in agitator torque and by application of optical microscopy. During one of these steps, aggregation of hydrophobic particles and microflocs takes place on the surface of gas bubbles dispersed in the suspension with the result that large flocs or flakes are produced which subsequently evolve into agglomerates. The time required to produce spherical agglomerates appears to be a function of the power input per unit volume with the time decreasing as the power input increases.

  19. Assessment of methods for collecting fallout brake pad wear debris for environmental analysis.

    PubMed

    Sondhi, Akash; Imhoff, Paul T; Dentel, Steven K; Allen, Herbert E

    2010-01-01

    Three methods for collecting or generating fallout brake pad wear debris for environmental analysis were assessed: collection from wheels or hubs of automobiles (natural), generation from an inexpensive sanding process (sanded), and collection of fallout debris from dynamometer tests using the Los Angeles City Traffic protocol (LACT). Brake wear debris was collected from four automobiles with semimetalic brake pads and analyzed for physicochemical properties. For automobiles where all three types of debris were collected, bulk copper mass fractions ranged from 22-23% in sanded particles and 24-27% in LACTparticles, but were reduced to 1-6% in natural debris. The smaller copper mass fraction in natural debris was attributed to contamination with road dust, which was found to comprise 37-97% of the natural particles. The ratio of surface to bulk copper mass fraction was up to five times larger for natural than LACT debris, suggesting that copper may leach into stormwater faster and to a greater extent for natural particles. While the LACT method appears best for collecting only fallout particles, significant differences in copper distributions in the natural and LACT debris suggests that metal distribution in LACT debris may not be representative of fallout particles generated under actual driving conditions, where airborne road dust may play a role. Although dynamometer tests have been the preferred method for generating debris for assessment of metal dissolution from brake particles, data from this study indicate that such samples may result in biased estimates of metal leaching.

  20. Evaluating the accretion of meteoritic debris and interplanetary dust particles in the GPC-3 sediment core using noble gas and mineralogical tracers

    NASA Astrophysics Data System (ADS)

    Darrah, Thomas H.; Poreda, Robert J.

    2012-05-01

    Extraterrestrial (ET) noble gases (helium and neon) in 35 sediment samples from Central Pacific core LL-44 GPC-3 demonstrate the variable flux of interplanetary dust particles (IDPs) and major meteorite impacts over the past 70 Ma (21-72 Ma). Spinel mineralogical and chemical compositions clearly distinguish major impact events from the continuous flux of IDPs, including the well-established Cretaceous/Tertiary (K/T) and late Eocene (E/O) impact boundaries. No spinel grains with chemical or mineralogical evidence of a distinctly ET origin were found in an extensive survey of 'background' samples (i.e. non E/O or K/T boundary) suggesting that either the carrier grains for ET noble gas occur within the Fe-Ti oxide mineral fraction observed in this study (found to include ilmenite and ulvospinel) or are too small for identification by SEM. The presence of ilmenite and ulvospinel suggest lunar regolith is a potential source for ET noble gas-rich particles. Noble gas analysis on both the EMF (extractable magnetic fraction) and the Bulk minus EMF (Bulk - EMF) show that the He and Ne compositions are consistent with partially degassed noble gas signatures of zero-age magnetic grains (Z-MAG) and stratospheric interplanetary dust particles (IDPs). Conclusive evidence for a 'planetary' (Ne-A) noble gas signature is found only in the bulk sediments at the K/T boundary, although all GPC-3 K/T fractions (Bulk, EMF, and HF Digestion) plot along a mixing line between planetary (Ne-A) and solar wind (SW). Spinels from major impact boundaries (K/T; E/O) exhibit dendritic texture and elevated [Ni], consistent with previous reports. In contrast to the otherwise consistent [3He] signal from IDPs, the [3He] at the known impact boundaries (K/T and E/O) actually decreases. These anomalously low [3He] are accompanied by significantly elevated [Ne] and significantly lower (3He/20Ne)solar ratios (˜10× lower) produced by both preferentially degassing of He relative to Ne at times of

  1. Riding a Trail of Debris

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1

    This image taken by NASA's Spitzer Space Telescope shows the comet Encke riding along its pebbly trail of debris (long diagonal line) between the orbits of Mars and Jupiter. This material actually encircles the solar system, following the path of Encke's orbit. Twin jets of material can also be seen shooting away from the comet in the short, fan-shaped emission, spreading horizontally from the comet.

    Encke, which orbits the Sun every 3.3 years, is well traveled. Having exhausted its supply of fine particles, it now leaves a long trail of larger more gravel-like debris, about one millimeter in size or greater. Every October, Earth passes through Encke's wake, resulting in the well-known Taurid meteor shower.

    This image was captured by Spitzer's multiband imaging photometer when Encke was 2.6 times farther away than Earth is from the Sun. It is the best yet mid-infrared view of the comet at this great distance. The data are helping astronomers understand how rotating comets eject particles as they circle the Sun.

  2. Nearshore dynamics of artificial sand and oil agglomerates

    USGS Publications Warehouse

    Dalyander, P. Soupy; Plant, Nathaniel G.; Long, Joseph W.; McLaughlin, Molly R.

    2015-01-01

    Weathered oil can mix with sediment to form heavier-than-water sand and oil agglomerates (SOAs) that can cause beach re-oiling for years after a spill. Few studies have focused on the physical dynamics of SOAs. In this study, artificial SOAs (aSOAs) were created and deployed in the nearshore, and shear stress-based mobility formulations were assessed to predict SOA response. Prediction sensitivity to uncertainty in hydrodynamic conditions and shear stress parameterizations were explored. Critical stress estimates accounting for large particle exposure in a mixed bed gave the best predictions of mobility under shoaling and breaking waves. In the surf zone, the 10-cm aSOA was immobile and began to bury in the seafloor while smaller size classes dispersed alongshore. aSOAs up to 5 cm in diameter were frequently mobilized in the swash zone. The uncertainty in predicting aSOA dynamics reflects a broader uncertainty in applying mobility and transport formulations to cm-sized particles.

  3. Orbital debris: A technical assessment

    NASA Technical Reports Server (NTRS)

    Gleghorn, George; Asay, James; Atkinson, Dale; Flury, Walter; Johnson, Nicholas; Kessler, Donald; Knowles, Stephen; Rex, Dietrich; Toda, Susumu; Veniaminov, Stanislav

    1995-01-01

    To acquire an unbiased technical assessment of (1) the research needed to better understand the debris environment, (2) the necessity and means of protecting spacecraft against the debris environment, and (3) potential methods of reducing the future debris hazard, NASA asked the National Research Council to form an international committee to examine the orbital debris issue. The committee was asked to draw upon available data and analyses to: characterize the current debris environment, project how this environment might change in the absence of new measures to alleviate debris proliferation, examine ongoing alleviation activities, explore measures to address the problem, and develop recommendations on technical methods to address the problems of debris proliferation.

  4. Sonic enhanced ash agglomeration and sulfur capture. Quarterly report, July--September 1995

    SciTech Connect

    1995-10-01

    The major objective of the Phase I test program is to confirm the feasibility of the MTCI bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase I effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. Phase I tests are designed to cover the frequency range between 50 and 1400 Hz, establish monomodal baseline performance as a benchmark from which to measure the degree of enhancement expected from the bimodal approach, and, finally, to confirm the effectiveness of low-frequency fields over high-frequency fields for realistic particulate streams. The program will demonstrate the effectiveness of a unique approach which uses a bimodal distribution composed of large sorbent particles and fine fly ash particles to enhance ash agglomeration and sulfur capture at conditions found in direct coal-fired turbines. Under the impact of high-intensity sound waves, sorbent reactivity and utilization, it is theorized, will increase while agglomerates of fly ash and sorbents are formed which are readily collected in commercial cyclones. The work will extend the concept from the demonstration of feasibility (Phase I), through proof-of-concept (Phase II) to the construction (Phase III) of a coal-fired pulsed combustor with in-furnace sorbent injection. For Phase 1, Pennsylvania State University will conduct studies for enhanced sulfur capture in The Combustion Laboratory and agglomeration tests in the High Intensity Acoustic Laboratory. During this reporting period, design, design analysis and procurement proceeded as scheduled. An independent analysis of the structure was completed and the concrete pad was found to be inadequate so it will be re-designed.

  5. Disposal of Cleaning Debris

    DTIC Science & Technology

    1976-04-01

    trees. In addition, the debris contains some plastic bottles , balls, rubber items, and glass . The wood debris is in various stages of...the upper portion, which contains vegetation falls into the river. Plastic bottles and various other discarded objects periodically float into the...the reservoir includes tree stumps, tree branches, tree trunks, tires, oil drums, plastic bottles , signs from recreational areas in the White

  6. Orbital Debris Modeling

    NASA Technical Reports Server (NTRS)

    Liou, J. C.

    2012-01-01

    Presentation outlne: (1) The NASA Orbital Debris (OD) Engineering Model -- A mathematical model capable of predicting OD impact risks for the ISS and other critical space assets (2) The NASA OD Evolutionary Model -- A physical model capable of predicting future debris environment based on user-specified scenarios (3) The NASA Standard Satellite Breakup Model -- A model describing the outcome of a satellite breakup (explosion or collision)

  7. Space debris hazard to defense systems

    SciTech Connect

    Canavan, G.H.

    1996-05-01

    Natural and man-made debris are argued to present hazards to space systems, but recent data indicate that at low altitudes, the impact rates from small particles may have been overestimated by an order of magnitude. At high altitudes, small particles only present an impact hazard to large satellites; they would not support a cascade. Large particles would apparently produce a cascade only on time scales of centuries or millennia. Radar and optical data should be capable of resolving these uncertainties, but their observations are, as yet, inconsistent. While independent analytic and numerical estimates of collision and cascade rates agree, given consistent inputs, different groups produced significantly different estimates of debris growth rates. This note examines the basis for these discrepancies.

  8. Pulse combusted acoustic agglomeration apparatus and process

    DOEpatents

    Mansour, Momtaz N.; Chandran, Ravi

    1994-01-01

    An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance agglomeration of particulates which may be collected and removed using a conventional separation apparatus. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, added particulates may include a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

  9. Pulse combusted acoustic agglomeration apparatus and process

    DOEpatents

    Mansour, Momtaz N.

    1993-01-01

    An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance bimodal agglomeration of particulates which may be collected and removed using a conventional separation apparatus. A particulate having a size different from the size of the particulate in the gas stream to be cleaned is introduced into the system to effectuate the bimodal process. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, the added particulate may be a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

  10. Agglomeration multigrid for viscous turbulent flows

    NASA Technical Reports Server (NTRS)

    Mavriplis, D. J.; Venkatakrishnan, V.

    1994-01-01

    Agglomeration multigrid, which has been demonstrated as an efficient and automatic technique for the solution of the Euler equations on unstructured meshes, is extended to viscous turbulent flows. For diffusion terms, coarse grid discretizations are not possible, and more accurate grid transfer operators are required as well. A Galerkin coarse grid operator construction and an implicit prolongation operator are proposed. Their suitability is evaluated by examining their effect on the solution of Laplace's equation. The resulting strategy is employed to solve the Reynolds-averaged Navier-Stokes equations for aerodynamic flows. Convergence rates comparable to those obtained by a previously developed non-nested mesh multigrid approach are demonstrated, and suggestions for further improvements are given.

  11. Soot agglomeration in isolated, free droplet combustion

    NASA Technical Reports Server (NTRS)

    Choi, M. Y.; Dryer, F. L.; Green, G. J.; Sangiovanni, J. J.

    1993-01-01

    Under the conditions of an isolated, free droplet experiment, hollow, carbonaceous structures, called soot spheres, were observed to form during the atmospheric pressure, low Reynolds number combustion of 1-methylnaphthalene. These structures which are agglomerates composed of smaller spheroidal units result from both thermophoretic effects induced by the envelope flame surrounding each drop and aerodynamic effects caused by changes in the relative gas/drop velocities. A chemically reacting flow model was used to analyze the process of sootshell formation during microgravity droplet combustion. The time-dependent temperature and gas property field surrounding the droplet was determined, and the soot cloud location for microgravity combustion of n-heptane droplets was predicted. Experiments showed that the sooting propensity of n-alkane fuel droplets can be varied through diluent substitution, oxygen-index variations, and ambient pressure reductions.

  12. The Fast Debris Evolution Model

    NASA Astrophysics Data System (ADS)

    Lewis, Hugh G.; Swinerd, Graham; Newland, Rebecca; Saunders, Arrun

    The ‘Particles-in-a-box' (PIB) model introduced by Talent (1992) removed the need for computerintensive Monte Carlo simulation to predict the gross characteristics of an evolving debris environment. The PIB model was described using a differential equation that allows the stability of the low Earth orbit (LEO) environment to be tested by a straightforward analysis of the equation's coefficients. As part of an ongoing research effort to investigate more efficient approaches to evolutionary modelling and to develop a suite of educational tools, a new PIB model has been developed. The model, entitled Fast Debris Evolution (FaDE), employs a first-order differential equation to describe the rate at which new objects (˜ 10 cm) are added and removed from the environment. Whilst Talent (1992) based the collision theory for the PIB approach on collisions between gas particles and adopted specific values for the parameters of the model from a number of references, the form and coefficients of the FaDE model equations can be inferred from the outputs of future projections produced by high-fidelity models, such as the DAMAGE model. The FaDE model has been implemented as a client-side, web-based service using Javascript embedded within a HTML document. Due to the simple nature of the algorithm, FaDE can deliver the results of future projections immediately in a graphical format, with complete user-control over key simulation parameters. Historical and future projections for the ˜ 10 cm low Earth orbit (LEO) debris environment under a variety of different scenarios are possible, including business as usual, no future launches, post-mission disposal and remediation. A selection of results is presented with comparisons with predictions made using the DAMAGE environment model. The results demonstrate that the FaDE model is able to capture comparable time-series of collisions and number of objects as predicted by DAMAGE in several scenarios. Further, and perhaps more importantly

  13. Overpopulated, Underdeveloped Urban Agglomerations: Tomorrow’s Unstable Operating Environment

    DTIC Science & Technology

    2012-05-08

    DATES COVERED (From - To) 4. TITLE AND SUBTITLE Overpopulated , Underdeveloped Urban Agglomerations: Tomorrow’s 5a. CONTRACT NUMBER...ABSTRACT This paper asserts that a unique future operational environment is developing: overpopulated , underdeveloped urban agglomerations. A...proposed definition for this operating environment is (or would be) an overpopulated urban area which is located within a developing or underdeveloped

  14. The orbital debris detector consortium: Suppliers of instruments for in-situ measurements of small-particles in the space environment

    NASA Technical Reports Server (NTRS)

    Simon, C. G.; Muenzenmeyer, R.; Tanner, W. G., Jr.; Uy, O. M.; Skrivanek, R. A.; Tuzzolino, A. J.; Maag, C.; Wortman, J. J.

    1995-01-01

    Industry and university participants have joined together to form the IMPA:Ct consortium (In-situ Monitors of the Particulate Ambient: Circumterrestrial) which offers a broad range of flight qualified instruments for monitoring the small particle (0.1 micron to 10 cm) environment in space. Instruments are available in 12 months or less at costs ranging from 0.5 to 1.5 million dollars (US) for the total program. Detector technologies represented by these groups are: impact-induced capacitor-discharge (MOS, metal-oxide-silicon), cratering or penetration of electroactive thin film (polyvinylidene fluoride (PVDF)), impact-plasma detection, acoustic detection, CCD tracking of optical scatter of sunlight, and photodiode detection of optical scatter of laser light. The operational characteristics, general spacecraft interface and resource requirements (mass/power/telemetry), cost and delivery schedules, and points of contact for seven different instruments are presented.

  15. The orbital debris detector consortium: Suppliers of instruments for in-situ measurements of small-particles in the space environment

    SciTech Connect

    Simon, C.G.; Muenzenmeyer, R.; Tanner, W.G. Jr.; Uy, O.M.; Skrivanek, R.A.; Tuzzolino, A.J.; Maag, C.; Wortman, J.J. ||||||

    1995-02-01

    Industry and university participants have joined together to form the IMPA:Ct consortium (In-situ Monitors of the Particulate Ambient: Circumterrestrial) which offers a broad range of flight qualified instruments for monitoring the small particle (0.1 micron to 10 cm) environment in space. Instruments are available in 12 months or less at costs ranging from 0.5 to 1.5 million dollars (US) for the total program. Detector technologies represented by these groups are: impact-induced capacitor-discharge (MOS, metal-oxide-silicon), cratering or penetration of electroactive thin film (polyvinylidene fluoride (PVDF)), impact-plasma detection, acoustic detection, CCD tracking of optical scatter of sunlight, and photodiode detection of optical scatter of laser light. The operational characteristics, general spacecraft interface and resource requirements (mass/power/telemetry), cost and delivery schedules, and points of contact for seven different instruments are presented.

  16. Characterization of Debris from the DebriSat Hypervelocity Test

    NASA Technical Reports Server (NTRS)

    Rivero, M.; Kleespies, J.; Patankar, K.; Fitz-Coy, N.; Liou, J.-C.; Sorge, M.; Huynh, T.; Opiela, J.; Krisko, P.; Cowardin, H.

    2015-01-01

    The DebriSat project is an effort by NASA and the DoD to update the standard break-up model for objects in orbit. The DebriSat object, a 56 kg representative LEO satellite, was subjected to a hypervelocity impact in April 2014. For the hypervelocity test, the representative satellite was suspended within a "soft-catch" arena formed by polyurethane foam panels to minimize the interactions between the debris generated from the hypervelocity impact and the metallic walls of the test chamber. After the impact, the foam panels and debris not caught by the panels were collected and shipped to the University of Florida where the project has now advanced to the debris characterization stage. The characterization effort has been divided into debris collection, measurement, and cataloguing. Debris collection and cataloguing involves the retrieval of debris from the foam panels and cataloguing the debris in a database. Debris collection is a three-step process: removal of loose debris fragments from the surface of the foam panels; X-ray imaging to identify/locate debris fragments embedded within the foam panel; extraction of the embedded debris fragments identified during the X-ray imaging process. As debris fragments are collected, they are catalogued into a database specifically designed for this project. Measurement involves determination of size, mass, shape, material, and other physical properties and well as images of the fragment. Cataloguing involves a assigning a unique identifier for each fragment along with the characterization information.

  17. Agglomeration of alumina submicronparticles by silica nanoparticles: application to processing spheres by colloidal route.

    PubMed

    Garcia-Perez, P; Pagnoux, C; Pringuet, A; Videcoq, A; Baumard, J F

    2007-09-15

    In aqueous media, heterocoagulation between submicronic alumina (400 nm) and nanometric silica (25 nm) leads to the adsorption of silica on the alumina surface. By controlling the coverage rate of alumina particles, this adsorption destabilizes the suspension that leads to a very porous network of agglomerated particles. This work shows that the structure is all the more open as the density of charge carried by the two oxides is high and the ionic strength in the suspension low. From such a flocculated suspension, a new colloidal process to fabricate ceramic spheres is proposed which is based on a size increase of agglomerates. Under a controlled rotation of the vessel, electrostatic attraction between the surface charges of opposite polarity induces a size increase of agglomerates until the formation of spheres occurs. It has been shown that the mechanism of growth is poisoned by species adsorbed such as ions. Nevertheless, this new process proves very promising because it leads to a narrow size distribution of spheres by colloidal way, which can be subsequently consolidated by sintering, with a smooth surface.

  18. Bed material agglomeration during fluidized bed combustion. Final report

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Smeenk, J.L.

    1996-01-01

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion of coal and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed combustors (FBCs) indicate that at least five boilers were experiencing some form of bed material agglomeration. Deposit formation was reported at nine sites with deposits most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Three general types of mineralogic reactions were observed to occur in the agglomerates and deposits. Although alkalies may play a role with some {open_quotes}high alkali{close_quotes} lignites, we found agglomeration was initiated due to fluxing reactions between iron (II) from pyrites and aluminosilicates from clays. This is indicated by the high amounts of iron, silica, and alumina in the agglomerates and the mineralogy of the agglomerates. Agglomeration likely originated in the dense phase of the FBC bed within the volatile plume which forms when coal is introduced to the boiler. Secondary mineral reactions appear to occur after the agglomerates have formed and tend to strengthen the agglomerates. When calcium is present in high amounts, most of the minerals in the resulting deposits are in the melilite group (gehlenite, melilite, and akermanite) and pyroxene group (diopside and augite). During these solid-phase reactions, the temperature of formation of the melilite minerals can be lowered by a reduction of the partial pressure of CO{sub 2} (Diopside + Calcite {r_arrow}Akermanite).

  19. Diamond-like-carbon nanoparticle production and agglomeration following UV multi-photon excitation of static naphthalene/helium gas mixtures.

    PubMed

    Walsh, A J; Tielens, A G G M; Ruth, A A

    2016-07-14

    We report the formation of nanoparticles with significant diamond character after UV multi-photon laser excitation of gaseous naphthalene, buffered in static helium gas, at room temperature. The nanoparticles are identified in situ by their absorption and scattering spectra between 400 and 850 nm, which are modeled using Mie theory. Comparisons of the particles' spectroscopic and optical properties with those of carbonaceous materials indicate a sp(3)/sp(2) hybridization ratio of 8:1 of the particles formed. The particle extinction in the closed static (unstirred) gas-phase system exhibits a complex and quasi-oscillatory time dependence for the duration of up to several hours with periods ranging from seconds to many minutes. The extinction dynamics of the system is based on a combination of transport features and particle interaction, predominantly agglomeration. The relatively long period of agglomeration allows for a unique analysis of the agglomeration process of diamond-like carbon nanoparticles in situ.

  20. Debris flow deposition and reworking by the Colorado River in Grand Canyon, Arizona

    USGS Publications Warehouse

    Yanites, B.J.; Webb, R.H.; Griffiths, P.G.; Magirl, C.S.

    2006-01-01

    Flow regulation by large dams affects downstream flow competence and channel maintenance. Debris flows from 740 tributaries in Grand Canyon, Arizona, transport coarse-grained sediment onto debris fans adjacent to the Colorado River. These debris fans constrict the river to form rapids and are reworked during river flows that entrain particles and transport them downstream. Beginning in 1963, flood control operations of Glen Canyon Dam limited the potential for reworking of aggraded debris fans. We analyzed change in debris fans at the mouths of 75-Mile and Monument Creeks using photogrammetry of aerial photography taken from 1965 to 2000 and supplemented with ground surveys performed from 1987 to 2005. Our results quantify the debris fan aggradation that resulted from debris flows from 1984 to 2003. Volume, area, and river constriction increased at both debris fans. Profiles of the two debris fans show that net aggradation occurred in the middle of debris fans at stages above maximum dam releases, and surface shape shifted from concave to convex. Dam releases above power plant capacity partially reworked both debris fans, although reworking removed much less sediment than what was added by debris flow deposition. Large dam releases would be required to create additional reworking to limit the rate of debris fan aggradation in Grand Canyon.

  1. Debris flow deposition and reworking by the Colorado River in Grand Canyon, Arizona

    NASA Astrophysics Data System (ADS)

    Yanites, Brian J.; Webb, Robert H.; Griffiths, Peter G.; Magirl, Christopher S.

    2006-11-01

    Flow regulation by large dams affects downstream flow competence and channel maintenance. Debris flows from 740 tributaries in Grand Canyon, Arizona, transport coarse-grained sediment onto debris fans adjacent to the Colorado River. These debris fans constrict the river to form rapids and are reworked during river flows that entrain particles and transport them downstream. Beginning in 1963, flood control operations of Glen Canyon Dam limited the potential for reworking of aggraded debris fans. We analyzed change in debris fans at the mouths of 75-Mile and Monument Creeks using photogrammetry of aerial photography taken from 1965 to 2000 and supplemented with ground surveys performed from 1987 to 2005. Our results quantify the debris fan aggradation that resulted from debris flows from 1984 to 2003. Volume, area, and river constriction increased at both debris fans. Profiles of the two debris fans show that net aggradation occurred in the middle of debris fans at stages above maximum dam releases, and surface shape shifted from concave to convex. Dam releases above power plant capacity partially reworked both debris fans, although reworking removed much less sediment than what was added by debris flow deposition. Large dam releases would be required to create additional reworking to limit the rate of debris fan aggradation in Grand Canyon.

  2. Physical simulation of precipitation of radioactive element oxalates by using the harmless neodymium oxalate for studying the agglomeration phenomena

    NASA Astrophysics Data System (ADS)

    Lalleman, Sophie; Bertrand, Murielle; Plasari, Edouard

    2012-03-01

    Oxalic precipitation is usually applied in nuclear industry to process radioactive wastes or to recover actinides from a multicomponent solution. This paper deals with the development of methods adapted to a nuclear environment in order to study the agglomeration phenomena during actinide oxalic precipitation. These methods are previously setup with harmless elements that simulate the actinide behaviour: the lanthanides. A parametric study is carried out to quantify the influence of operating parameters on the agglomeration kernel and to determine a kinetic law for this mechanism. The experimental study is performed in a continuous-MSMPR precipitator at steady-state. The method is based on the resolution of two population balances using the moment approach, one for elementary crystals and the other for agglomerates. Provided that the kinetic rates of nucleation and growth are known, the agglomeration kernel can be obtained from a mathematical treatment of the experimental particle size distributions. Results point out that experimental crystal sizes are consistent with an independent kernel. It appears that the agglomeration kernel is directly proportional to supersaturation, increases with temperature but is limited by ionic strength and shear rate.

  3. Density Estimations in Laboratory Debris Flow Experiments

    NASA Astrophysics Data System (ADS)

    Queiroz de Oliveira, Gustavo; Kulisch, Helmut; Malcherek, Andreas; Fischer, Jan-Thomas; Pudasaini, Shiva P.

    2016-04-01

    Bulk density and its variation is an important physical quantity to estimate the solid-liquid fractions in two-phase debris flows. Here we present mass and flow depth measurements for experiments performed in a large-scale laboratory set up. Once the mixture is released and it moves down the inclined channel, measurements allow us to determine the bulk density evolution throughout the debris flow. Flow depths are determined by ultrasonic pulse reflection, and the mass is measured with a total normal force sensor. The data were obtained at 50 Hz. The initial two phase material was composed of 350 kg debris with water content of 40%. A very fine pebble with mean particle diameter of 3 mm, particle density of 2760 kg/m³ and bulk density of 1400 kg/m³ in dry condition was chosen as the solid material. Measurements reveal that the debris bulk density remains high from the head to the middle of the debris body whereas it drops substantially at the tail. This indicates lower water content at the tail, compared to the head and the middle portion of the debris body. This means that the solid and fluid fractions are varying strongly in a non-linear manner along the flow path, and from the head to the tail of the debris mass. Importantly, this spatial-temporal density variation plays a crucial role in determining the impact forces associated with the dynamics of the flow. Our setup allows for investigating different two phase material compositions, including large fluid fractions, with high resolutions. The considered experimental set up may enable us to transfer the observed phenomena to natural large-scale events. Furthermore, the measurement data allows evaluating results of numerical two-phase mass flow simulations. These experiments are parts of the project avaflow.org that intends to develop a GIS-based open source computational tool to describe wide spectrum of rapid geophysical mass flows, including avalanches and real two-phase debris flows down complex natural

  4. Operational source receptor calculations for large agglomerations

    NASA Astrophysics Data System (ADS)

    Gauss, Michael; Shamsudheen, Semeena V.; Valdebenito, Alvaro; Pommier, Matthieu; Schulz, Michael

    2016-04-01

    For Air quality policy an important question is how much of the air pollution within an urbanized region can be attributed to local sources and how much of it is imported through long-range transport. This is critical information for a correct assessment of the effectiveness of potential emission measures. The ratio between indigenous and long-range transported air pollution for a given region depends on its geographic location, the size of its area, the strength and spatial distribution of emission sources, the time of the year, but also - very strongly - on the current meteorological conditions, which change from day to day and thus make it important to provide such calculations in near-real-time to support short-term legislation. Similarly, long-term analysis over longer periods (e.g. one year), or of specific air quality episodes in the past, can help to scientifically underpin multi-regional agreements and long-term legislation. Within the European MACC projects (Monitoring Atmospheric Composition and Climate) and the transition to the operational CAMS service (Copernicus Atmosphere Monitoring Service) the computationally efficient EMEP MSC-W air quality model has been applied with detailed emission data, comprehensive calculations of chemistry and microphysics, driven by high quality meteorological forecast data (up to 96-hour forecasts), to provide source-receptor calculations on a regular basis in forecast mode. In its current state, the product allows the user to choose among different regions and regulatory pollutants (e.g. ozone and PM) to assess the effectiveness of fictive emission reductions in air pollutant emissions that are implemented immediately, either within the agglomeration or outside. The effects are visualized as bar charts, showing resulting changes in air pollution levels within the agglomeration as a function of time (hourly resolution, 0 to 4 days into the future). The bar charts not only allow assessing the effects of emission

  5. Micrometeoroids and debris on LDEF

    NASA Technical Reports Server (NTRS)

    Mandeville, Jean-Claude

    1993-01-01

    Two experiments within the French Cooperative Payload (FRECOPA) and devoted to the detection of cosmic dust were flown on the Long Duration Exposure Facility (LDEF). A variety of sensors and collecting devices have made possible the study of impact processes on dedicated sensors and on materials of technological interest. Examination of hypervelocity impact features on these experiments gives valuable information on the size distribution and nature of interplanetary dust particles in low-Earth orbit (LEO), within the 0.5-300 micrometer size range. However no crater smaller than 1.5 microns has been observed, thus suggesting a cut-off in the near Earth particle distribution. Chemical investigation of craters by EDX clearly shows evidence of elements (Na, Mg, Si, S, Ca, and Fe) consistent with cosmic origin. However, remnants of orbital debris have been found in a few craters; this can be the result of particles in eccentric orbits about the Earth and of the 8 deg offset in the orientation of LDEF. Crater size distribution is compared with results from other dust experiments flown on LDEF and with current models. Possible origin and orbital evolution of micrometeoroids is discussed. Use of thin foil detectors for the chemical study of particle remnants looks promising for future experiments.

  6. Dynamical Processes in Debris Disks

    NASA Astrophysics Data System (ADS)

    Beust, H.

    2010-01-01

    Debris disks are dusty and/or gasous disk that are viewed in scattered light and thermal emission around stars around 107-108 yr. It is well known that the dust in these system is not primodial. It is short lived and must be continuously replenished by colliding planetesimals. Most of them appear distorted by the gravitational pertubations by inner planets or stellar companions. This is why these systems are viewed today as young planetary systems. Debris disks are collisional systems. Thanks to collisional cascade towards smaller size, the dust particles are transported outwards by radiation or stellar wind pressure. Below a given blow-off size they escape the system. This model explains the radial density profiles observed. The various asymmetries, clumps and other dynamical structures such as spiral arms are though to originate in gravitational perturbations by planets and/or companions. Planets usually create gaps in disks, but they also sculpt disks via their mean-motion resonances. Clumpy structures are often invoked as resulting from such an interaction. Stellar companions usually truncate the disk, sometimes confining them to thin annular structures. They also help creating spiral patterns, either tidally or by secular interaction. In this context, the situation is different whether the perturbing companions are bound or just passing stars. In any case, dynamical studies (often specific to each system) can greatly help constraining the configuration and the past history of these systems.

  7. Benefits of Active Debris Removal on the LEO Debris Population

    NASA Astrophysics Data System (ADS)

    Maniwa, Kazuaki; Hanada, Toshiya; Kawamoto, Satomi

    Since the launch of Sputnik, orbital debris population continues to increase due to ongoing space activities, on-orbit explosions, and accidental collisions. In the future, a great deal of fragments can be expected to be created by explosions and collisions. In spite of prevention of satellite and rocket upper stage explosions and other mitigation measures, debris population in low Earth orbit may not be stabilized. To better limit the growth of the future debris population, it is necessary to remove the existing debris actively. This paper studies about the effectiveness of active debris removal in low Earth orbit where the collision rate with and between space debris is high. This study does not consider economic problems, but investigates removing debris which may stabilize well the current debris population based on the concept of Japan Aerospace Exploration Agency.

  8. Development of a Gas-Promoted Oil Agglomeration Process

    SciTech Connect

    M. Shen; R. Abbott; T. D. Wheelock

    1998-10-30

    Two series of agglomeration tests were conducted as part of an effort to find a suitable basis for size scale-up of the mixing system used for a gas-promoted oil agglomeration process. In the first series of tests the agitator impeller diameter and speed were varied among runs so as to vary impeller tip speed and agitator power independently while keeping other conditions constant. In the second series of tests the mixing tank size and agitator speed were varied while the ratio of tank diameter to impeller diameter were held constant. All tests were conducted with finely ground Pittsburgh No. 8 coal and with i-octane as the agglomerant. The results of these tests showed that the minimum time te required to produce spherical agglomerates was predominantly a function of the agitator power input per unit volume. In addition, the size of the agglomerates produced in a given time was also strongly dependent on power input. At lower power input levels, the mean size rose as power input increased until a point was reached where agglomerate breakage became important and the mean size decreased. The results also showed that the ash content of the agglomerates produced in a given time tended to decrease with increasing power input. On the other hand, the recovery of clean coal on a dry, ash-free basis was not greatly affected by power input.

  9. Crystal growth and agglomeration of calcium sulfite hemihydrate crystals

    SciTech Connect

    Tai, C.Y.; Chen, P.C.

    1995-04-01

    Flue gas desulfurization (FGD) processes are most commonly utilized to remove sulfur dioxide from stack gases of coal- or oil-fired plants. In the simple slurry technology, SO{sub 2} is absorbed by a slurry of lime/limestone to form calcium sulfite crystals of acicular habit and its strong agglomeration, requiring large clarifiers and filters to dewater the sludge to make an acceptable landfill. Crystal growth and agglomeration of calcium sulfite hemihydrate crystals from solution were studied by reacting Ca(OH){sub 2} with NaHSO{sub 3} in a pH-stat semibatch crystallizer. Single platelet crystals and agglomerates of platelet crystals were produced in the pH range from 5.80 to 6.80. The crystallization mechanism changed from primary nucleation to crystal growth in the progressive precipitation. Using the titration curves, the growth rate was calculated from the titration rate at the final stage of operation. The crystal growth rates of calcium sulfate hemihydrate crystals were found to obey the parabolic rate law in the low supersaturation range. Another point to be noted is that the precipitates of calcium sulfite hemihydrate in agitated suspensions have a tendency to form agglomerates. It was found that the degree of agglomeration is a weak function of relative supersaturation and magma density, while the pH value is a key factor that affects the degree of agglomeration. Addition of EDTA also has an effect on the agglomeration of calcium sulfite hemihydrates.

  10. Space debris detection

    NASA Astrophysics Data System (ADS)

    Eather, Robert H.

    1992-12-01

    A feasibility study on the possibility of detecting less than or = 10 cm space debris using a large-aperture ground-based telescope (with an intensified CCD detector) was completed, showing that detection should be possible. A detector system was designed and built, and installed on the 2.54 m WRDC telescope at Wright Patterson AFB. Bad seeing conditions in the Dayton area prevented the expected debris detection. Subsequently, a small 40 cm telescope was built and operated from the Haystack Observatory (Groton, MA). Known objects were used to test pointing and acquisition procedures, and the system was then shipped to Rattlesnake Observatory (Richland, WA) for participation in the ODERAC's debris calibration experiment from the Space Shuttle. This experiment failed, and our instrument has been stored at Rattlesnake in anticipation of a new ODERAC's flight in late 1993.

  11. Particle Sizing in Solid Rocket Motors

    DTIC Science & Technology

    1989-03-01

    reduced. A reduction in agglomeration can be expected due to the geometry of the closely packed AP particles. Tighter AP intersticial spacing reduces... intersticial "pockets" which enhanced agglomeration more than did the 4.69% aluminum content propellant matrix. * There was a large increase in quantities of

  12. Physical properties of soils in Rostov agglomeration

    NASA Astrophysics Data System (ADS)

    Gorbov, S. N.; Bezuglova, O. S.; Abrosimov, K. N.; Skvortsova, E. B.; Tagiverdiev, S. S.; Morozov, I. V.

    2016-08-01

    Physical properties of natural and anthropogenically transformed soils of Rostov agglomeration were examined. The data obtained by conventional methods and new approaches to the study of soil physical properties (in particular, tomographic study of soil monoliths) were used for comparing the soils of different functional zones of the urban area. For urban territories in the steppe zone, a comparison of humus-accumulative horizons (A, Asod, Ap, and buried [A] horizons) made it possible to trace tendencies of changes in surface soils under different anthropogenic impacts and in the buried and sealed soils. The microtomographic study demonstrated differences in the bulk density and aggregation of urban soils from different functional zones. The A horizon in the forest-park zone is characterized by good aggregation and high porosity, whereas buried humus-accumulative horizons of anthropogenically transformed soils are characterized by poor aggregation and low porosity. The traditional parameters of soil structure and texture also proved to be informative for the identification of urban pedogenesis.

  13. Meteoroid/Debris Shielding

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.

    2003-01-01

    This report provides innovative, low-weight shielding solutions for spacecraft and the ballistic limit equations that define the shield's performance in the meteoroid/debris environment. Analyses and hypervelocity impact testing results are described that have been used in developing the shields and equations. Spacecraft shielding design and operational practices described in this report are used to provide effective spacecraft protection from meteoroid and debris impacts. Specific shield applications for the International Space Station (ISS), Space Shuttle Orbiter and the CONTOUR (Comet Nucleus Tour) space probe are provided. Whipple, Multi-Shock and Stuffed Whipple shield applications are described.

  14. Contribution of secondary ejecta to the debris population

    NASA Astrophysics Data System (ADS)

    Mandeville, J.-C.; Bariteau, M.

    2004-01-01

    When a micro-debris or a micrometeoroid impacts a spacecraft surface, secondary particles, called ejecta, are produced. These ejecta can contribute to a modification of the debris environment: either locally by the occurrence of secondary impacts on the components of complex and large space structures, or at great distances by the formation of a population of small orbital debris. This paper describes the ejecta production mechanism, and shows their orbital evolution. Then, the distribution of ejecta in low earth orbits is given. Some results are presented describing the number of ejecta as a function of size and altitude.

  15. A modelling of ejecta as a space debris source

    NASA Astrophysics Data System (ADS)

    Bariteau, Muriel; Mandeville, Jean-Claude

    2001-10-01

    When a micro-debris or a micrometeoroid impacts a spacecraft surface, secondary particles, called ejecta, are produced. These ejecta can contributes to a modification of the debris environment: either locally by the occurrence of secondary impacts on the components of complex and large space structures, or at great distances by the formation of a population of small orbital debris. This paper describes, firstly, the ejecta production, and secondly, their lifetime and orbit propagation. Then, the repartition of ejecta in LEO is given. Results describing the ejecta number as a function of size and altitude are presented.

  16. Gravitational Agglomeration of Post-HCDA LMFBR Nonspherical Aerosols.

    DTIC Science & Technology

    1980-12-01

    AD-AIO6 766 AIR FORCE INST OF TECH WRIGHT-PATTERSON AFB OH F/B 13/7 GRAVITATIONAL AGGLOMERATION OF POST- HCDA LMF8R NONSPHFRICAL AER--ETC(U) DEC 80 R...OF REPORT & PERIOD COVERED i Gravitational Agglomeration of Post- HCDA TfIfM/DISSERTATION LMFBR Nonspherical Aerosols . ________O____O______________ S...it to: AFIT/NR Wright-Patterson AFB OH 45433 RESEARCH TITLE: Gravitational Agglomeration of Post- HCDA LMFBR Nonspherical Aerosols AUTHOR: Ronald

  17. Agglomeration-Free Distributor for Fluidized Beds

    NASA Technical Reports Server (NTRS)

    Ouyang, F.; Sinica, A.; Levenspiel, O.

    1986-01-01

    New gas distributor for fluidized beds prevents hot particles from reacting on it and forming hard crust. In reduction of iron ore in fluidized bed, ore particles do not sinter on distributor and perhaps clog it or otherwise interfere with gas flow. Distributor also relatively cool. In fluidized-bed production of silicon, inflowing silane does not decompose until within bed of hot silicon particles and deposits on them. Plates of spiral distributor arranged to direct incoming gas into spiral flow. Turbulence in flow reduces frequency of contact between fluidized-bed particles and distributor.

  18. Orbital Debris: A Policy Perspective

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2007-01-01

    A viewgraph presentation describing orbital debris from a policy perspective is shown. The contents include: 1) Voyage through near-Earth Space-animation; 2) What is Orbital Debris?; 3) Orbital Debris Detectors and Damage Potential; 4) Hubble Space Telescope; 5) Mir Space Station Solar Array; 6) International Space Station; 7) Space Shuttle; 8) Satellite Explosions; 9) Satellite Collisions; 10) NASA Orbital Debris Mitigation Guidelines; 11) International Space Station Jettison Policy; 12) Controlled/Uncontrolled Satellite Reentries; 13) Return of Space Objects; 14) Orbital Debris and U.S. National Space Policy; 15) U.S Government Policy Strategy; 16) Bankruptcy of the Iridium Satellite System; 17) Inter-Agency Space Debris Coordination Committee (IADC); 18) Orbital Debris at the United Nations; 19) Chinese Anti-satellite System; 20) Future Evolution of Satellite Population; and 21) Challenge of Orbital Debris

  19. Solid Hydrogen Particles Analyzed for Atomic Fuels

    NASA Technical Reports Server (NTRS)

    Palaszewski, Bryan A.

    2001-01-01

    Solid hydrogen particles have been selected as a means of storing atomic propellants in future launch vehicles (refs. 1 to 2). In preparation for this, hydrogen particle formation in liquid helium was tested experimentally. These experiments were conducted to visually characterize the particles and to observe their formation and molecular transformations (aging) while in liquid helium. The particle sizes, molecular transformations, and agglomeration times were estimated from video image analyses. The experiments were conducted at the NASA Glenn Research Center in the Supplemental Multilayer Insulation Research Facility (SMIRF, ref. 3). The facility has a vacuum tank, into which the experimental setup was placed. The vacuum tank prevented heat leaks and subsequent boiloff of the liquid helium, and the supporting systems maintained the temperature and pressure of the liquid helium bath where the solid particles were created. As the operation of the apparatus was developed, the hydrogen particles were easily visualized. The figures (ref. 1) show images from the experimental runs. The first image shows the initial particle freezing, and the second image shows the particles after the small particles have agglomerated. The particles finally all clump, but stick together loosely. The solid particles tended to agglomerate within a maximum of 11 min, and the agglomerate was very weak. Because the hydrogen particles are buoyant in the helium, the agglomerate tends to compact itself into a flat pancake on the surface of the helium. This pancake agglomerate is easily broken apart by reducing the pressure above the liquid. The weak agglomerate implies that the particles can be used as a gelling agent for the liquid helium, as well as a storage medium for atomic boron, carbon, or hydrogen. The smallest particle sizes that resulted from the initial freezing experiments were about 1.8 mm. About 50 percent of the particles formed were between 1.8 to 4.6 mm in diameter. These very

  20. Enhanced softgoods structures for spacesuit micrometeoroid/debris protective systems

    NASA Technical Reports Server (NTRS)

    Remington, Brian; Cadogan, David; Kosmo, Joseph

    1992-01-01

    A lightweight, flexible thermal micrometeoroid garment (TMG) design for enhanced space suit micrometeoroid/debris (M/D) protection is described. It will consist of an outer layer comprised of orthofabric, multilayers of aluminized Mylar, and a layer of silicone rubber loaded with micron sized particles of tungsten. The shield layers would fragment and/or vaporize the M/D projectile while the backup sheet would stop the resultant debris cloud.

  1. Diffusion mediated agglomeration of CdS nanoparticles via Langmuir–Blodgett technique

    SciTech Connect

    Das, Nayan Mani Roy, Dhrubojyoti; Gupta, P.S.

    2013-10-15

    Graphical abstract: - Highlights: • Diffusion mediated agglomeration of CdS nanoparticles are discussed. • Formation of CdS nanoparticles are confirmed by the change of chain length in XRD. • AFM shows the agglomeration of particles with a film swelling of about 5 Å. • UV–vis absorbance suggests that the grown particles show quantum confinement. • Hexagonal form of particle was confirmed by UV–vis reflectivity. - Abstract: We have reported a diffusion mediated agglomeration of cadmium sulphide (CdS) nanoparticles within cadmium arachidate (CdA{sub 2}) film matrix. The structural morphology and formation of CdS nanoparticles are characterized by X-ray diffraction (XRD), X-ray reflectivity (XRR), atomic force microscopy (AFM) and ultraviolet-visible spectroscopy techniques. X-ray diffraction (XRD) results show a change in bilayer difference from 53.04 Å to 43 Å after the sulphidation. An epitaxial growth of the films by ∼5 Å after sulphidation is confirmed from atomic force microscopy studies. The particle size calculated form UV–vis absorption edges are found to be varying from 2.6 nm to 3.3 nm for the different layers. A lateral dimension of 72–80 nm from AFM measurements and a size of 2.6–3.3 nm have confirmed one side flat pseudo two-dimensional disk-like nanoparticles. UV–vis reflectivity peak at E{sub 1} (A) confirms the formation of hexagonal CdS nanoparticles along the c-axis.

  2. Space Debris Mitigation CONOPS Development

    DTIC Science & Technology

    2013-06-01

    manmade orbital debris and that they existed in cloud clusters sometimes 1000 km along track (Mulholland and Veillet, 2004). 6 Although many...space debris. Orbital debris is herein defined as “any man-made Earth-orbiting object which is non-functional with no reasonable expectation of...Mission (SMM or Solar Max) and the Hubble Space Telescope (HST)…[and] Orbital Debris Collector (ODC) and the Momentum Stage Impact Detector (MOM

  3. Leukocyte Agglomeration Reaction in Diagnosis of Allergy Reactions from Antibiotics,

    DTIC Science & Technology

    tested in a clinic on 80 patients with serious allergic anamnesis . The results of the studies indicate that the leukocyte agglomeration reaction is a highly sensitive immunological indicator of hypersensitivity to antibiotics.

  4. An integrated ultrasonic-inductive pulse sensor for wear debris detection

    NASA Astrophysics Data System (ADS)

    Du, Li; Zhe, Jiang

    2013-02-01

    One approach to detect signs of potential machine failure is to detect wear debris in the lubrication oil of a rotating or reciprocating machine because the size and the concentration of wear debris particles in the oil show a direct relationship with the level of wear. In this article, a proof-of-principle integrated wear debris sensor consisting of an ultrasonic pulse sensor and an inductive pulse sensor for detecting wear debris in lubrication oil is presented. The ultrasonic pulse sensor detects all solid debris (metallic and non-metallic debris). A flow recess structure is utilized to ensure that all wear debris passes the acoustic focal region so that all debris can be accurately counted and sized. The inductive pulse sensor detects and counts all metallic debris (ferrous and non-ferrous) based on the inductive Coulter counting principle. By comparing the results from the two sensing components, the sensor is capable of differentiating and detecting non-metallic debris, ferrous metallic debris and non-ferrous metallic debris.

  5. Quantum dot agglomerates in biological media and their characterization by asymmetrical flow field-flow fractionation.

    PubMed

    Moquin, Alexandre; Neibert, Kevin D; Maysinger, Dusica; Winnik, Françoise M

    2015-01-01

    The molecular composition of the biological environment of nanoparticles influences their physical properties and changes their pristine physicochemical identity. In order to understand, or predict, the interactions of cells with specific nanoparticles, it is critical to know their size, shape, and agglomeration state not only in their nascent state but also in biological media. Here, we use asymmetrical flow field-flow fractionation (AF4) with on-line multiangle light scattering (MALS), dynamic light scattering (DLS) and UV-Visible absorption detections to determine the relative concentration of isolated nanoparticles and agglomerates in the case of three types of semi-conductor quantum dots (QDs) dispersed in Dulbecco's Modified Eagle Media (DMEM) containing 10% of fetal bovine serum (DMEM-FBS). AF4 analysis also yielded the size and size distribution of the agglomerates as a function of the time of QDs incubation in DMEM-FBS. The preferred modes of internalization of the QDs are assessed for three cell-types, N9 microglia, human hepatocellular carcinoma cells (HepG2) and human embryonic kidney cells (Hek293), by confocal fluorescence imaging of live cells, quantitative determination of the intracellular QD concentration, and flow cytometry. There is an excellent correlation between the agglomeration status of the three types of QDs in DMEM-FBS determined by AF4 analysis and their preferred mode of uptake by the three cell lines, which suggests that AF4 yields an accurate description of the nanoparticles as they encounter cells and advocates its use as a means to characterize particles under evaluation.

  6. Activities on space debris in U.S.

    NASA Astrophysics Data System (ADS)

    Johnson, Nicholas L.

    2001-10-01

    In the U.S. space debris activities are addressed at all government levels, from the Executive Office of the President to the individual federal agencies to specialized centers, laboratories, organizations, and research groups. U.S. Space Policy specifically challenges government agencies to seek to minimize the creation of space debris and to promote debris minimization practices, both domestically and internationally. A set of space debris mitigation standard practices has been developed and adopted by relevant U.S. government agencies, and their application by the commercial aerospace community is highly encouraged. A growing number of U.S. government agencies have issued their own space debris mitigation policies, directives, regulations, and standards. Space debris research, including the definition and modeling of the current and future near-Earth space environment and the development of debris protection technologies, is principally conducted by NASA and the Department of Defense. The U.S. Space Surveillance Network continues to provide the most complete and timely characterization of the population of space debris larger than 10 cm. During the past several years major advancements have been achieved in extending this environment definition in LEO to include particles as small as only a few millimeters. The inspection of returned spacecraft surfaces continues to shed light on the even smaller debris population. With improvements in computer technology, new and more capable programs have been and are being developed to solve a number of operational and research problems. Finally, the academic and industrial sectors of the U.S. are also increasing their participation in and contributions to space debris operations and research. The cooperation of spacecraft and launch vehicle developers and operators is essential to the U.S. objective of promoting the preservation of the space environment for future generations.

  7. Activities on Space Debris in U.S.

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2001-01-01

    In the U.S. space debris activities are addressed at all government levels, from the Executive Office of the President to the individual federal agencies to specialized centers, laboratories, organizations, and research groups. U.S. Space Policy specifically challenges government agencies to seek to minimize the creation of space debris and to promote debris minimization practices both domestically and internationally. A set of space debris mitigation standard practices has been developed and adopted by relevant US government agencies, and their application by the commercial aerospace community is highly encouraged. A growing number of US government agencies have issued their own space debris mitigation policies, directives, regulations, and standards. Space debris research, including the definition and modeling of the current and future near-Earth space environment and the development of debris protection technologies, is principally conducted by NASA and the Department of Defense. The U.S. Space Surveillance Network continues to provide the most complete and timely characterization of the population of space debris larger than 10 cm. During the past several years major advancements have been achieved in extending this environment definition in LEO to include particles as small as only a few millimeters. The inspection of returned spacecraft surfaces continues to shed light on the even smaller debris population. With improvements in computer technology, new and more capable programs have been and are being developed to solve a number of operational and research problems. Finally, the academic and industrial sectors of the U.S. are also increasing their participation in and contributions to space debris operations and research. The cooperation of satellite and launch vehicle developers and operators is essential to the U.S. objective of promoting the preservation of the space environment for future generations.

  8. Preparation of norfloxacin spherical agglomerates using the ammonia diffusion system.

    PubMed

    Puechagut, H G; Bianchotti, J; Chiale, C A

    1998-04-01

    Agglomerated crystals of norfloxacin were prepared by a spherical crystallization technique using the ammonia diffusion system (ADS). This technique makes it possible to agglomerate amphoteric drugs like norfloxacin, which cannot be agglomerated by conventional procedures. When an ammonia-water solution of norfloxacin is poured into an acetone dichloromethane mixture under agitation, a small amount of ammonia is liberated in the system. The ammonia-water solution plays a role both as a good solvent for norfloxacin and as a bridging liquid, allowing the crystals' collection to take place in one step. It has been proven that the agglomeration mechanism follows three steps: first acetone enters into the droplets of ammonia-water (this emulsion is formed because of the system characteristics); dissolved norfloxacin is consequently precipitated while the droplets collect the crystals; simultaneously, a part of the ammonia contained in the agglomerates diffuses to the outer organic solvent phase, thereby forming the norfloxacin spherical agglomerates. The correct selection of solvents has enabled us to obtain a suitable stable crystalline shape.

  9. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.; Potas, Todd A.; DeWall, Raymond A.; Musich, Mark A.

    1992-01-01

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  10. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  11. Development and Flight Demonstration of Space Debris Monitor (SDM)

    NASA Astrophysics Data System (ADS)

    Kitazawa, Yukihito; Hanada, Toshiya; Matsumoto, Haruhisa; Kobayashi, Masanori; Sakurai, Akira; Yasaka, Tetsuo; Funakoshi, Kunihiro; Hasegawa, Sunao; Akahoshi, Yasuhiro; Kimoto, Yugo; Okudaira, Osamu; Kamiya, Koki; Nakamura, Maki

    2016-07-01

    The space debris monitor (SDM) is a large-area impact sensor for in situ measurements of micro-meteoroids and space debris of the sub-millimeter to millimeter size in the near-Earth space environment. These meteoroid and debris particles are very small to be detected by ground-based observations (radars and optical telescopes) but are sufficiently large to cause serious damage to spacecraft equipment in the low Earth orbit region. The nominal detection area of the SDM is 0.1 m^2 (0.35 m × 0.3 m), but its dimensions can be easily modified to accommodate different SDM constraints. The SDM is made from a flexible printed circuit, which is produced from a thin film of a nonconductive material (such as polyimide) on which thin conductive stripes are formed in parallel. The stripe width is approximately 50 μm, and the spatial separation is approximately 100 μm, as shown in Figure 1. When a micro-debris particle with an effective diameter near to or larger than the spatial separation of the stripes (here approximately 100 μm) collides with the sensor film at a velocity sufficient to penetrate it, one or more of the stripes are cut and become nonconductive. Debris impacts can thus be detected by monitoring the electrical conductivity (resistivity) of the stripes. This sensor system can measure the size of the incident micro-debris particles by detecting the number of severed stripes. The measurement concept is registered as a patent in many countries. The first SDM was launched with HTV-5 on August 19, 2015 and represented the world's first micro-debris measurement demonstration experiment to be conducted on the ISS using the concept of conductive (resistive) strip lines for real-time debris detection.

  12. Interplanetary meteoroid debris in LDEF metal craters

    NASA Technical Reports Server (NTRS)

    Brownlee, D. E.; Joswiak, D.; Bradley, J.; Hoerz, Friedrich

    1993-01-01

    We have examined craters in Al and Au LDEF surfaces to determine the nature of meteoroid residue in the rare cases where projectile material is abundantly preserved in the crater floor. Typical craters contain only small amounts of residue and we find that less than 10 percent of the craters in Al have retained abundant residue consistent with survival of a significant fraction (greater than 20 percent) of the projectile mass. The residue-rich craters can usually be distinguished optically because their interiors are darker than ones with little or no apparent projectile debris. The character of the meteoroid debris in these craters ranges from thin glass liners, to thick vesicular glass containing unmelted mineral fragments, to debris dominated by unmelted mineral fragments. In the best cases of meteoroid survival, unmelted mineral fragments preserve both information on projectile mineralogy as well as other properties such as nuclear tracks caused by solar flare irradiation. The wide range of the observed abundance and alteration state of projectile residue is most probably due to differences in impact velocity. The crater liners are being studied to determine the composition of meteoroids reaching the Earth. The compositional types most commonly seen in the craters are: (1) chondritic (Mg, Si, S, Fe in approximately solar proportions), (2) Mg silicate. amd (3) iron sulfide. These are also the most common compositional types of extraterrestrial particle types collected in the stratosphere. The correlation between these compositions indicates that vapor fractionation was not a major process influencing residue composition in these craters. Although the biases involved with finding analyzable meteoroid debris in metal craters differ from those for extraterrestrial particles collected in and below the atmosphere, there is a common bias favoring particles with low entry velocity. For craters this is very strong and probably all of the metal craters with abundant

  13. Alumina-alumina artificial hip joints. Part I: a histological analysis and characterisation of wear debris by laser capture microdissection of tissues retrieved at revision.

    PubMed

    Hatton, A; Nevelos, J E; Nevelos, A A; Banks, R E; Fisher, J; Ingham, E

    2002-08-01

    The aims of this study were to investigate the tissues from uncemented Mittelmeier alumina ceramic-on-ceramic total hip replacements using histological methods and to isolate and characterise the ceramic wear debris using laser capture microdissection and electron microscopy. Tissues from around 10 non-cemented Mittelmeier alumina ceramic on ceramic THRs were obtained from patients undergoing revision surgery. Tissues were also obtained from six patients who were undergoing revisions for aseptic loosening of Charnley, metal-on-polyethylene prostheses. Tissue sections were analysed using light microscopy to determine histological reactions and also the location and content of alumina ceramic wear debris. Tissue samples were extracted from sections using laser capture microdissection and the characteristics of the particles subsequently analysed by TEM and SEM. The tissues from around the ceramic-on-ceramic prostheses all demonstrated the presence of particles, which could be seen as agglomerates inside cells or in distinct channels in the tissues. The tissues from the ceramic-on-ceramic retrievals had a mixed pathology with areas that had no obvious pathology, areas that were relatively rich in macrophages and over half of the tissues had in the region of 60% necrosis/necrobiosis. In comparison, the Charnley tissues showed a granulomatous cellular reaction involving a dense macrophage infiltrate and the presence of giant cells and < 30% necrosis/necrobiosis. The tissues from the ceramic prostheses also showed the presence of neutrophils and lymphocytes, which were not evident in the tissues from the Charnley retrievals. There were significantly more macrophages (p < 0.05), and giant cells (p < 0.01) in the Charnley tissues and significantly more neutrophils (p < 0.01) in the ceramic-on-ceramic tissues. TEM of the laser captured tissue revealed the presence of very small alumina wear debris in the size range 5-90 nm, mean size + SD of 24 +/- 19nm whereas SEM (lower

  14. Modeling the transport and accumulation floating debris generated by the 11 March 2011 Tohoku tsunami.

    PubMed

    Lebreton, Laurent C-M; Borrero, Jose C

    2013-01-15

    A global ocean circulation model is coupled to a particle-tracking model to simulate the transport of floating debris washed into the North Pacific Ocean by the Tohoku tsunami. A release scenario for the tsunami debris is based on coastal population and measured tsunami runup. Archived 2011/2012 hindcast current data is used to model the transport of debris since the tsunami, while data from 2008 to 2012 is used to investigate the distribution of debris on timescales up to 4years. The vast amount of debris pushed into ocean likely represents thousands of years worth of 'normal' litter flux from Japan's urbanized coastline. This is important since a significant fraction of the debris will be comprised of plastics, some of which will degrade into tiny particles and be consumed by marine organisms, thereby allowing adsorbed organic pollutants to enter our food supply in quantities much higher than present.

  15. Dynamics of nanoparticle agglomeration in a magnetic fluid in a varying magnetic field

    NASA Astrophysics Data System (ADS)

    Usanov, D. A.; Postel'ga, A. E.; Bochkova, T. S.; Gavrilin, V. N.

    2016-03-01

    It is found that the dependence of the magnetic nanoparticle agglomerate length in a magnetic fluid on the applied magnetic field has three characteristic segments: a substantial increase in the agglomerate length with the magnetic field in the range of weak fields, a segment with an insignificant increase in the average length of agglomerates upon an increase in the field, and a sharp increase in the agglomerate length with a further increase in the field. It is shown that the agglomerate length increases in the range of strong magnetic fields due to a decrease in the spacing between adjacent agglomerates down to their complete coalescence. The total number of agglomerates decreases thereby.

  16. Debris Characterization Diagnostic for the National Ignition Facility

    SciTech Connect

    Miller, M.C.; Celeste, J.R. Stoyer, M.A.; Suter, L.J.; Tobin, M.T.; Grun, J.; Davis, J.F.; Barnes, C.W.; Wilson, D.C.

    2000-06-07

    Generation of debris from targets and by x-ray ablation of surrounding materials will be a matter of concern for experimenters and the operations staff at the National Ignition Facility (NIF). Target chamber and final optics protection, for example debris shield damage, and efficient facility operation drive the interest for the NIF staff. Experimenters are primarily concerned with diagnostic survivability, separation of mechanical versus radiation induced test object response in the case of effects tests, and radiation transport through the debris field when the net radiation output is used to benchmark computer codes. In addition, radiochemical analysis of activated capsule debris during ignition shots can provide a measure of the ablator. Conceptual design of the Debris Monitor and Rad-Chem Station, one of the NIF core diagnostics, is presented. Methods of debris collection, particle size and mass analysis, impulse measurement, and radiochemical analysis are given. A description of recent experiments involving debris collection and impulse measurement on the OMEGA and Pharos lasers is also provided.

  17. Sonic enhanced ash agglomeration and sulfur capture: Quarterly report, October--December 1994

    SciTech Connect

    1995-01-01

    The major objective of the Phase 1 test program is to confirm the feasibility of the MTCI bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase 1 effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. The program will demonstrate the effectiveness of a unique approach which uses a bimodal distribution composed of large sorbent particles and fine fly ash particles to enhance ash agglomeration and sulfur capture at conditions found in direct coal-fired turbines. The work will extend the concept from the demonstration of feasibility (Phase 1), through proof-of-concept (Phase 2) to the construction (Phase 3) of a coal-fired pulsed combustor with in-furnace sorbent injection. In view of the potentially large repowering market in the US, several possible configurations were formulated and evaluated for application to the repowering market. Based on discussions between the DOE/METC team members and MTCI staff; seven different configuration were proposed for further evaluation. The technical and market issues associated with each of these configurations were identified and summarized. An initial system simulation test for the system operating at inlet air temperatures of 700--800 F as for a gas turbine application was conducted, indicating that acoustic performance can be further improved by modifying gas injectors. Development of the advanced vortex aerovalve continued.

  18. Q-space analysis of scattering by small irregular particles

    NASA Astrophysics Data System (ADS)

    Sorensen, C. M.; Zubko, E.; Heinson, W. R.; Chakrabarti, A.

    2014-01-01

    This paper applies the Q-space analysis method to the scattering phase function of small irregular particles. Q-space analysis involves plotting the scattered intensity versus the magnitude of the scattering wave vector q=(4π/λ) sin(θ/2) on a double log plot. Four types of irregularly shaped particles were studied: strongly damaged spheres, rough surface spheres, pocked spheres, and agglomerated debris particles. The angular scattering phase function was calculated using the discrete dipole approximation (DDA). The Q-space analysis uncovered power law descriptions of the scattering as it has previously for aggregates, spheres and dusts, although in some situations the description is marginal. It also showed that the forward scattering lobe has Rayleigh functionalities on size and refractive index. These results imply that Q-space analysis can yield a comprehensive description of scattering in terms of power laws with quantifiable exponents for a wide variety of particle shapes. However, a theoretical explanation of the power laws and the values of the numerical exponents is lacking.

  19. Orbital debris removal using ground-based lasers

    NASA Technical Reports Server (NTRS)

    Taylor, Charles R.

    1996-01-01

    Orbiting the Earth are spent rocket stages, non-functioning satellites, hardware from satellite deployment and staging, fragments of exploded spacecraft, and other relics of decades of space exploration: orbital debris. The United States Space Command tracks and maintains a catalog of the largest objects. The catalog contains over 7000 objects. Recent studies have assessed the debris environment in an effort to estimate the number of smaller particles and the probability of a collision causing catastrophic damage to a functioning spacecraft. The results of the studies can be used to show, for example, that the likelihood of a collision of a particle larger than about one centimeter in diameter with the International Space Station during a 10-year period is a few percent, roughly in agreement with earlier estimates for Space Station Freedom. Particles greater than about one centimeter in diameter pose the greatest risk to shielded spacecraft. There are on the order of 105 such particles in low Earth orbit. The United States National Space Policy, begun in 1988, is to minimize debris consistent with mission requirements. Measures such as venting unused fuel to prevent explosions, retaining staging and deployment hardware, and shielding against smaller debris have been taken by the U.S. and other space faring nations. There is at present no program to remove debris from orbit. The natural tendency for upper atmospheric drag to remove objects from low Earth orbit is more than balanced by the increase in the number of debris objects from new launches and fragmentation of existing objects. In this paper I describe a concept under study by the Program Development Laboratory of Marshall Space Flight Center and others to remove debris with a ground-based laser. A longer version of this report, including figures, is available from the author.

  20. Colloidal stability of coal-simulated suspensions in selective agglomeration

    SciTech Connect

    Schurger, M.L.

    1989-01-01

    A coal suspension was simulated by using graphite to simulate the carbonaceous fraction and kaolinite clay to simulate the ash fraction. Separate studies on each material established their response to additions of oxidized pyrite (ferrous sulfate) and a humic acid simulate (salicylic acid) in terms of zeta potentials profiles with pH and Ionic strength. Concentrations of iron and salicylic acid evaluated were 4.5 {times} 10{sup {minus}3} M and 2.0 {times} 10{sup {minus}4} M, respectively. The zeta potentials profiles of graphite, clay and hexadecane were negative throughout the pH ranges studied. The addition of iron lowered the zeta potentials all of the suspensions under all pH and ionic strength conditions. Salicylic acid decreased the graphite and hexadecane zeta potentials but had no effect on the clay zeta potential profiles. Agglomeration of graphite with bridging liquid shows distinct time dependent rate mechanisms, a initial growth of graphite agglomerates followed by consolidation phase. Graphite agglomeration was rapid with the maximum amount of agglomerate volume growth occurring in under 2-4 minutes. Agglomeration in the first two minutes was characterized by a 1st order rate mechanism. The presence of either Iron and salicylic acid generally improved the first order rates. The addition of clay also improved the first order rates except in the presence of salicylic acid. Heteroagglomeration of graphite with clay was found by hydrodynamic arguments to be unfavored. A multicomponent population balance model which had been developed for evaluating collision efficiencies of coal, ash and pyrite selective agglomeration was evaluated to explain these results. The growth and consolidation characteristics of graphite agglomeration for the experimental conditions examined herein revealed the limitations of such as model for this application.

  1. Powder fed sheared dispersal particle generator

    NASA Technical Reports Server (NTRS)

    Morrisette, E. L.; Bushnell, D. M. (Inventor)

    1984-01-01

    A particle generating system is described which is capable of breaking up agglomerations of particles and producing a cloud of uniform, submicron-sized particles at high pressure and high flow rates. This is achieved by utilizing a tubular structure which has injection microslits on is periphery to accept and disperse the desired particle feed. By suppling a carrying fluid at a pressure, of approximately twice the ambient pressure of the velocimeter's settling chamber, the microslits operate at choked flow conditions. The shearing action of this choked flow is sufficient to overcome interparticle bonding forces, thereby breaking up the agglomerates of the particles feed into individual particles.

  2. Orbital debris issues

    NASA Astrophysics Data System (ADS)

    Kessler, D. J.

    Orbital debris issues fall into three major topics: Environment Definition, Spacecraft Hazard, and Space Object Management. The major issue under Environment Definition is defining the debris flux for sizes smaller (10 cm in diameter) than those tracked by the North American Aerospace Defense Command (NORAD). Sources for this size debris are fragmentation of larger objects, either by explosion or collision, and solid rocket motor products. Modeling of these sources can predict fluxes in low Earth orbit which are greater than the meteoroid environment. Techniques to measure the environment in the size interval between 1 mm and 10 cm are being developed, including the use of telescopes and radar both on the ground and in space. Some impact sensors designed to detect meteoroids may have detected solid rocket motor products. Once the environment is defined, it can be combined with hypervelocity impact data and damage criteria to evaluate the Spacecraft Hazard. Shielding may be required to obtain an acceptable damage level. Space Object Management includes techniques to control the environment and the desired policy to effectively minimize the hazard to spacecraft. One control technique - reducing the likelihood of future explosions in space - has already been implemented by NASA. The effectiveness of other techniques has yet to be evaluated.

  3. Variation in initiation condition of debris flows in the mountain regions surrounding Beijing

    NASA Astrophysics Data System (ADS)

    Ma, Chao; Wang, Yu-jie; Du, Cui; Wang, Yun-qi; Li, Yun-peng

    2016-11-01

    Debris flows in the mountain regions surrounding Beijing have been occurring for a long time and have resulted in great economic losses. In this study, 23 rainstorm events, surficial sediments, and debris flow deposits were analyzed to quantify the area's rainfall threshold and to investigate how such conditions may be used to predict debris flow in this region. Rainfall threshold of intensity-duration (I-D) functions after vegetation recovery was higher than before recovery and also higher than I-D levels in other regions where debris flows are closely associated with runoff. Field investigations revealed that surficial sediments were characterized by coarse-grained sediments and that debris flow deposits lacked fine particles. Local debris flows can be triggered by runoff; however, no single standard equation is used to predict the conditions that lead to runoff-triggered debris flow; and commonly used equations give different values. Here, we propose an empirical function that takes into account peak discharge per width and particle diameter. This model should be verified with further investigations so that it can be used as a reference to analyze the conditions that lead to debris flow in the study area. Finally, debris flows may have been related to occasional storms in the study area, which has been experiencing substantially increased temperatures and decreased annual precipitation. This work provides important information about the conditions that initiated debris flow in the Beijing mountain regions in the last few decades.

  4. Formation of metal agglomerates during carbonisation of chromated copper arsenate (CCA) treated wood waste: Comparison between a lab scale and an industrial plant.

    PubMed

    Helsen, Lieve; Hacala, Amélie

    2006-10-11

    This paper compares the results obtained by scanning electron microscopy coupled to X-ray analysis (SEM-EDXA) of the solid product after carbonisation of treated wood waste in a lab scale and in an industrial installation. These setups (lab scale and industrial) are characterized by different operating conditions of the carbonisation process. Moreover, the wood waste input to the processes differs significantly. From this study, it is clear that some similarities but also some differences exist between the lab scale study and the study with the industrial Chartherm plant. In both reactors, a metal (and mineral) agglomeration process takes place, even in the case of untreated wood. The agglomerates initially present in the wood input may serve as a seed for the metal agglomeration process during "chartherisation". The industrial setup leads to a broader range of agglomerates' size (0.1-50 microm) and composition (all possible combinations of Cu, Cr, As and wood minerals). Some agglomerates contain the three metals but the major part is a combination of wood minerals and one or two of the three preservative metals, while all agglomerates analysed in the lab scale product contain the three metals. The separate influence of wood input characteristics and process conditions cannot be derived from these experiments, but the observations suggest that the higher the CCA retention in the wood input is, the easier is the metal agglomeration process during chartherisation of CCA treated wood waste. From the analyses performed in this study it seems that copper behaves differently in the sense that it agglomerates easily, but the resulting particles are small (<1 microm).

  5. Shields for Enhanced Protection Against High-Speed Debris

    NASA Technical Reports Server (NTRS)

    Christiansen, Eric L.; Kerr, Justin H.

    2003-01-01

    A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arises mainly from breakup of older spacecraft. The improved shields include exterior "bumper" layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cubic cm, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

  6. Design of orbital debris shields for oblique hypervelocity impact

    NASA Technical Reports Server (NTRS)

    Fahrenthold, Eric P.

    1994-01-01

    A new impact debris propagation code was written to link CTH simulations of space debris shield perforation to the Lagrangian finite element code DYNA3D, for space structure wall impact simulations. This software (DC3D) simulates debris cloud evolution using a nonlinear elastic-plastic deformable particle dynamics model, and renders computationally tractable the supercomputer simulation of oblique impacts on Whipple shield protected structures. Comparison of three dimensional, oblique impact simulations with experimental data shows good agreement over a range of velocities of interest in the design of orbital debris shielding. Source code developed during this research is provided on the enclosed floppy disk. An abstract based on the work described was submitted to the 1994 Hypervelocity Impact Symposium.

  7. Design of orbital debris shields for oblique hypervelocity impact

    NASA Astrophysics Data System (ADS)

    Fahrenthold, Eric P.

    1994-02-01

    A new impact debris propagation code was written to link CTH simulations of space debris shield perforation to the Lagrangian finite element code DYNA3D, for space structure wall impact simulations. This software (DC3D) simulates debris cloud evolution using a nonlinear elastic-plastic deformable particle dynamics model, and renders computationally tractable the supercomputer simulation of oblique impacts on Whipple shield protected structures. Comparison of three dimensional, oblique impact simulations with experimental data shows good agreement over a range of velocities of interest in the design of orbital debris shielding. Source code developed during this research is provided on the enclosed floppy disk. An abstract based on the work described was submitted to the 1994 Hypervelocity Impact Symposium.

  8. Extrinsic lactose fines improve dry powder inhaler formulation performance of a cohesive batch of budesonide via agglomerate formation and consequential co-deposition.

    PubMed

    Kinnunen, Hanne; Hebbink, Gerald; Peters, Harry; Huck, Deborah; Makein, Lisa; Price, Robert

    2015-01-15

    The aim of the study was to investigate how the fine particle content of lactose carriers prepared with different types of lactose fines regulates dry powder inhaler (DPI) formulation performance of a cohesive batch of micronised budesonide. Budesonide formulations (0.8 wt%) were prepared with three different lactose carriers (Lactohale (LH) LH100, 20 wt% LH210 in LH100 and 20 wt% LH300 in LH100). Fine particle fraction of emitted dose (FPFED) and mean mass aerodynamic diameter (MMAD) of budesonide was assessed with a Next Generation Impactor (NGI) using a Cyclohaler at 90 l/min. Morphological and chemical characteristics of particles deposited on Stage 2 were determined using a Malvern Morphologi G3-ID. The results indicate that increasing concentration of lactose fines (<4.5 μm) not only increased the FPFED but also the MMAD of budesonide, suggesting drug deposition in agglomerates. Presence of agglomerates on Stage 2 was confirmed by morphological analysis of particles. Raman analysis of material collected on Stage 2 indicated that the more fine lactose particles were available the more agglomerates of budesonide and lactose were delivered to Stage 2. These results suggest drug-fines agglomerate formation is an important mechanism for how lactose fines improve and regulate DPI formulation performance.

  9. A Critical Study of Agglomerated Multigrid Methods for Diffusion

    NASA Technical Reports Server (NTRS)

    Nishikawa, Hiroaki; Diskin, Boris; Thomas, James L.

    2011-01-01

    Agglomerated multigrid techniques used in unstructured-grid methods are studied critically for a model problem representative of laminar diffusion in the incompressible limit. The studied target-grid discretizations and discretizations used on agglomerated grids are typical of current node-centered formulations. Agglomerated multigrid convergence rates are presented using a range of two- and three-dimensional randomly perturbed unstructured grids for simple geometries with isotropic and stretched grids. Two agglomeration techniques are used within an overall topology-preserving agglomeration framework. The results show that multigrid with an inconsistent coarse-grid scheme using only the edge terms (also referred to in the literature as a thin-layer formulation) provides considerable speedup over single-grid methods but its convergence deteriorates on finer grids. Multigrid with a Galerkin coarse-grid discretization using piecewise-constant prolongation and a heuristic correction factor is slower and also grid-dependent. In contrast, grid-independent convergence rates are demonstrated for multigrid with consistent coarse-grid discretizations. Convergence rates of multigrid cycles are verified with quantitative analysis methods in which parts of the two-grid cycle are replaced by their idealized counterparts.

  10. A Critical Study of Agglomerated Multigrid Methods for Diffusion

    NASA Technical Reports Server (NTRS)

    Thomas, James L.; Nishikawa, Hiroaki; Diskin, Boris

    2009-01-01

    Agglomerated multigrid techniques used in unstructured-grid methods are studied critically for a model problem representative of laminar diffusion in the incompressible limit. The studied target-grid discretizations and discretizations used on agglomerated grids are typical of current node-centered formulations. Agglomerated multigrid convergence rates are presented using a range of two- and three-dimensional randomly perturbed unstructured grids for simple geometries with isotropic and highly stretched grids. Two agglomeration techniques are used within an overall topology-preserving agglomeration framework. The results show that multigrid with an inconsistent coarse-grid scheme using only the edge terms (also referred to in the literature as a thin-layer formulation) provides considerable speedup over single-grid methods but its convergence deteriorates on finer grids. Multigrid with a Galerkin coarse-grid discretization using piecewise-constant prolongation and a heuristic correction factor is slower and also grid-dependent. In contrast, grid-independent convergence rates are demonstrated for multigrid with consistent coarse-grid discretizations. Actual cycle results are verified using quantitative analysis methods in which parts of the cycle are replaced by their idealized counterparts.

  11. Advanced physical fine coal cleaning spherical agglomeration. Final report

    SciTech Connect

    Not Available

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  12. Development of a gas-promoted oil agglomeration process. Technical progress report, December 1, 1993--February 28, 1994

    SciTech Connect

    Wheelock, T.D.; Drzymala, J.; Zhang, F.

    1994-05-01

    The overall purpose of this research project is to carry out the preliminary laboratory-scale development of a gas-promoted, oil agglomeration process for cleaning coal using model mixing systems. A model mixing system has been previously designed and constructed for conducting oil agglomeration tests in such a way that agitator speed and torque can be measured as well as agglomeration performance. Equipment is also provided for monitoring the progress of agglomeration during a batch test. This equipment includes a photometric dispersion analyzer for measuring the turbidity of the particle suspension. In order to measure the turbidity a small stream of material is withdrawn from the mixing tank and conducted through an optical cell associated with the photometric dispersion analyzer. The material is then returned to the mixing tank. A peristaltic pump located between the optical cell and the mixing tank is used for circulating the material. During the past quarter a series of shakedown test were carried out to calibrate the equipment and to determine some of its operating characteristics. The accuracy of the agitator speed and torque measuring instrument was checked. Also the gas dispersing effectiveness of the mixing system was investigated. In addition, the effects of agitator speed and solids concentration on agitator torque and power requirements were studied.

  13. Signatures of planets in circumstellar debris disks

    NASA Astrophysics Data System (ADS)

    Moro-Martin, Maria Amaya

    2004-12-01

    Main sequence stars are commonly surrounded by debris disks, composed of cold dust continuously replenished by a reservoir of undetected dust-producing planetesimals. In the outer Solar System, Kuiper Belt (KB) objects produce dust by mutual or interstellar grain collisions. The orbital evolution of KB dust has been numerically modeled. Its equilibrium radial density distribution can be accurately estimated even though there are inherent uncertainties in the prediction of structure, owing to the chaotic dynamics of dust orbital evolution imposed by resonant gravitational perturbations of the planets. The particle size distribution of dust is greatly changed from the distribution at production, as a result of radiation forces and the perturbations of the planets. The contribution of KB dust to the population of interplanetary dust particles collected at Earth may be as low as a few percent. Gravitational scattering by giant planets creates an outflow of large grains. We quantify the characteristics of this large-particle outflow in different planetary architectures, discuss its implications for exo-planetary debris disks, and for the interpretation of in-situ dust detection experiments in space probes traveling in the outer Solar System. These outflows may contribute to the clearing of circumstellar debris in planetary systems, affecting the particle size distribution of their local ISM. In anticipation of future observations of unresolved debris disks with Spitzer , we are interested in studying how the structure carved by planets affects the shape of the disk's spectral energy distribution (SED), and consequently if the SED can be used to infer the presence of planets. We numerically calculate the equilibrium spatial density distributions and SEDs of dust disks originated by an outer belt of planetesimals (35-50 AU) in the presence of different planetary configurations, and for a representative sample of chemical compositions. The dynamical models are needed to

  14. Depositional processes in large-scale debris-flow experiments

    USGS Publications Warehouse

    Major, J.J.

    1997-01-01

    This study examines the depositional process and characteristics of deposits of large-scale experimental debris flows (to 15 m3) composed of mixtures of gravel (to 32 mm), sand, and mud. The experiments were performed using a 95-m-long, 2-m-wide debris-flow flume that slopes 31??. Following release, experimental debris flows invariably developed numerous shallow (???10 cm deep) surges. Sediment transported by surges accumulated abruptly on a 3?? runout slope at the mouth of the flume. Deposits developed in a complex manner through a combination of shoving forward and shouldering aside previously deposited debris and through progressive vertical accretion. Progressive accretion by the experimental flows is contrary to commonly assumed en masse sedimentation by debris flows. Despite progressive sediment emplacement, deposits were composed of unstratified accumulations of generally unsorted debris; hence massively textured, poorly sorted debris-flow deposits are not emplaced uniquely en masse. The depositional process was recorded mainly by deposit morphology and surface texture and was not faithfully registered by interior sedimentary texture; homogeneous internal textures could be misinterpreted as the result of en masse emplacement by a single surge. Deposition of sediment by similar, yet separate, debris flows produced a homogenous, massively textured composite deposit having little stratigraphic distinction. Similar deposit characteristics and textures are observed in natural debris-flow deposits. Experimental production of massively textured deposits by progressive sediment accretion limits interpretations that can be drawn from deposit characteristics and casts doubt on methods of estimating flow properties from deposit thickness or from relations between particle size and bed thickness.

  15. DEBRIS FLOWS AND HYPERCONCENTRATED STREAMFLOWS.

    USGS Publications Warehouse

    Wieczorek, Gerald F.

    1986-01-01

    Examination of recent debris-flow and hyperconcentrated-streamflow events in the western United States reveals (1) the topographic, geologic, hydrologic, and vegetative conditions that affect initiation of debris flows and (2) the wide ranging climatic conditions that can trigger debris flows. Recognition of these physiographic and climatic conditions has aided development of preliminary methods for hazard evaluation. Recent developments in the application of electronic data gathering, transmitting, and processing systems shows potential for real-time hazard warning.

  16. Effects of crossover hydrogen on platinum dissolution and agglomeration

    NASA Astrophysics Data System (ADS)

    Cheng, Tommy T. H.; Rogers, Erin; Young, Alan P.; Ye, Siyu; Colbow, Vesna; Wessel, Silvia

    2011-10-01

    The durability of catalysts in the polymer-electrolyte membrane fuel cell (PEMFC) is identified as a critical limiting factor for wide commercialization of fuel cells. Even though much progress has been made in understanding the degradation mechanisms, the phenomena of Pt dissolution and agglomeration and their contributing factors are not fully understood. In the present investigation, the effects of crossover hydrogen on Pt degradation are studied using an accelerated stress test (AST). The end-of-test (EOT) membrane-electrode-assemblies (MEAs) were characterized by X-ray diffraction (XRD), scanning-electron microscopy (SEM), and energy-dispersive X-ray (EDX). The results provided mechanistic understanding of Pt dissolution and agglomeration: Pt growth and agglomeration were found to be less severe with more crossover hydrogen due likely to the chemical reduction of Pt oxides by crossover hydrogen and the subsequently decrease in the amount of Pt ions formed via the oxide pathway.

  17. Hierarchical agglomerates of carbon nanotubes as high-pressure cushions.

    PubMed

    Liu, Yi; Qian, Weizhong; Zhang, Qiang; Cao, Anyuan; Li, Zhifei; Zhou, Weiping; Ma, Yang; Wei, Fei

    2008-05-01

    We report the cushioning behavior of highly agglomerated carbon nanotubes. The nanotube agglomerates can be repeatedly compacted to achieve large volume reduction (>50%) and expanded to nearly original volume without structural failure, like a robust porous cushion. At a higher pressure range (10-125 MPa), the energy absorbed per unit volume is 1 order of magnitude higher than conventional cushion materials such as foamy polystyrene. The structure of hierarchical agglomerates can be controlled for tailoring the cushioning properties and obtaining a lower cushioning coefficient (higher energy absorption) over a wide range of pressures (1-100 MPa). The mechanism was studied in terms of morphology evolution of the nanotube aggregates and pore size distribution during compression.

  18. Ferrographic analysis of wear debris generated in a sliding elastohydrodynamic contact

    NASA Technical Reports Server (NTRS)

    Jones, W. R., Jr.; Nagaraj, H. S.; Winer, W. O.

    1977-01-01

    The ferrograph was used to analyze wear debris generated in a sliding elastohydrodynamic contact. The amount of wear debris correlates well with the ratio of film thickness to composite surface roughness. Essentially all of the generated wear particles were of the normal rubbing wear type.

  19. Failure Analysis in Space: International Space Station (ISS) Starboard Solar Alpha Rotary Joint (SARJ) Debris Analysis

    NASA Technical Reports Server (NTRS)

    Long, V. S.; Wright, M. C.; McDanels, S. J.; Lubas, D.; Tucker, B.; Marciniak, P. J.

    2010-01-01

    This slide presentation reviews the debris analysis of the Starboard Solar Alpha Rotary Joint (SARJ), a mechanism that is designed to keep the solar arrays facing the sun. The goal of this was to identify the failure mechanism based on surface morphology and to determine the source of debris through elemental and particle analysis.

  20. The Physics of Protoplanetesimal Dust Agglomerates. VIII. Microgravity Collisions between Porous SiO_2 Aggregates and Loosely Bound Agglomerates

    NASA Astrophysics Data System (ADS)

    Whizin, Akbar D.; Blum, Jürgen; Colwell, Joshua E.

    2017-02-01

    We performed laboratory experiments colliding 0.8–1.0 mm and 1.0–1.6 mm SiO2 dust aggregates with loosely bound centimeter-sized agglomerates of those aggregates in microgravity. This work builds on previous microgravity laboratory experiments examining the collisional properties of porous loosely bound dust aggregates. In centimeter-sized aggregates, surface forces dominate self-gravity and may play a large role in aggregate growth beyond this size range. We characterize the properties of protoplanetary aggregate analogs to help place constraints on initial formation mechanisms and environments. We determined several important physical characteristics of these aggregates in a large number of low-velocity collisions. We observed low coefficients of restitution and fragmentation thresholds near 1 m s‑1 for 1–2 cm agglomerates, which are in good agreement with previous findings in the literature. We find the accretion efficiency for agglomerates of loosely bound aggregates to be higher than that for just aggregates themselves. We find sticking thresholds of 6.6 ± 2 cm s‑1, somewhat higher than those in similar studies, which have observed few aggregates stick at speeds of under 3 cm s‑1. Even with highly dissipative collisions, loosely bound agglomerates have difficulty accreting beyond centimeter-sized bodies at typical collision speeds in the disk. Our results indicate agglomerates of porous aggregates have slightly higher sticking thresholds than previously thought, allowing possible growth to decimeter-sized bodies if velocities are low enough.

  1. Agglomeration, isolation and dissolution of commercially manufactured silver nanoparticles in aqueous environments

    NASA Astrophysics Data System (ADS)

    Elzey, Sherrie; Grassian, Vicki H.

    2010-06-01

    The increasing use of manufactured nanoparticles ensures these materials will make their way into the environment. Silver nanoparticles in particular, due to use in a wide range of applications, have the potential to get into water systems, e.g., drinking water systems, ground water systems, estuaries, and/or lakes. One important question is what is the chemical and physical state of these nanoparticles in water? Are they present as isolated particles, agglomerates or dissolved ions, as this will dictate their fate and transport. Furthermore, does the chemical and physical state of the nanoparticles change as a function of size or differ from micron-sized particles of similar composition? In this study, an electrospray atomizer coupled to a scanning mobility particle sizer (ES-SMPS) is used to investigate the state of silver nanoparticles in water and aqueous nitric acid environments. Over the range of pH values investigated, 0.5-6.5, silver nanoparticles with a bimodal primary particle size distribution with the most intense peak at 5.0 ± 7.4 nm, as determined from transmission electron microscopy (TEM), show distinct size distributions indicating agglomeration between pH 6.5 and 3 and isolated nanoparticles at pH values from 2.5 to 1. At the lowest pH investigated, pH 0.5, there are no peaks detected by the SMPS, indicating complete nanoparticle dissolution. Further analysis of the solution shows dissolved Ag ions at a pH of 0.5. Interestingly, silver nanoparticle dissolution shows size dependent behavior as larger, micron-sized silver particles show no dissolution at this pH. Environmental implications of these results are discussed.

  2. Continuous air agglomeration method for high carbon fly ash beneficiation

    DOEpatents

    Gray, McMahon L.; Champagne, Kenneth J.; Finseth, Dennis H.

    2000-01-01

    The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

  3. Space Debris Hazard Evaluation

    NASA Technical Reports Server (NTRS)

    Davison, Elmer H.; Winslow, Paul C., Jr.

    1961-01-01

    The hazard to space vehicles from natural space debris has been explored. A survey of the available information pertinent to this problem is presented. The hope is that this presentation gives a coherent picture of the knowledge to date in terms of the topic covered. The conclusion reached is that a definite hazard exists but that it can only be poorly assessed on the basis of present information. The need for direct measurement of this hazard is obvious, and some of the problems involved in making these direct measurements have been explored.

  4. Microplastic debris in sandhoppers

    NASA Astrophysics Data System (ADS)

    Ugolini, A.; Ungherese, G.; Ciofini, M.; Lapucci, A.; Camaiti, M.

    2013-09-01

    Adults of the sandhopper Talitrus saltator were fed with dry fish food mixed with polyethylene microspheres (diameter 10-45 μm). Observations of homogenized guts revealed the presence of microspheres independently of their dimensions. The gut resident time (GRT) was recorded and most of the microspheres are expelled in 24 h. Microspheres are totally expelled in one week. Preliminary investigations did not show any consequence of microsphere ingestion on the survival capacity in the laboratory. FT-IR analyses carried out on faeces of freshly collected individuals revealed the presence of polyethylene and polypropylene. This confirms that microplastic debris could be swallowed by T. saltator in natural conditions.

  5. Initiation and Frequency of Debris Flows in Grand Canyon, Arizona

    USGS Publications Warehouse

    Griffiths, Peter G.; Webb, Robert H.; Melis, Theodore S.

    1996-01-01

    Debris flows occur in 600 tributaries of the Colorado River in Grand Canyon, Arizona when intense precipitation causes slope failures in bedrock or colluvium. These slurries transport poorly sorted sediment, including very large boulders that form rapids at the mouths of tributaries and control the longitudinal profile of the Colorado River. Although the amount of rainfall on the days of historic debris flows typically is not unusual, the storm rainfall on consecutive days before the debris flows typically had recurrence intervals greater than 10 yrs. Four types of failure mechanisms initiate debris flows: bedrock failure (12 percent), failure of colluvial wedges by rainfall (21 percent), failure of colluvial wedges by runoff (the ?firehose effect;? 36 percent), and combinations of these failure mechanisms (30 percent). Failure points are directly or indirectly associated with terrestrial shales, particularly the Permian Hermit Shale, shale units within the Permian Esplanade Sandstone of the Supai Group, and the Cambrian Bright Angel Shale. Shales either directly fail, produce colluvial wedges downslope that contain clay, or form benches that store poorly sorted colluvium in wedge-shaped deposits. Terrestrial shales provide the fine particles and clay minerals?particularly kaolinite and illite?essential to long-distance debris-flow transport, whereas marine shales mostly contain smectites, which inhibit debris-flow initiation. Using repeat photography, we determined whether or not a debris flow occurred in the last century in 164 of 600 tributaries in Grand Canyon. We used logistic regression to model the binomial frequency data using 21 morphometric and lithologic variables. The location of shale units, particularly the Hermit Shale, within the tributary is the most consistent variable related to debris-flow frequency in Grand Canyon. Other statistically significant variables vary with large scale changes in canyon morphology. Standard morphometric measures such

  6. Determination of the runoff threshold for triggering debris flows in the area affected by the Wenchuan Earthquake

    NASA Astrophysics Data System (ADS)

    Cui, P.; Guo, X. J.; Zhuang, J. Q.

    2014-07-01

    We constructed an experiment to determine the critical runoff discharge for debris flow initiation in Wenchuan Earthquake area. A single dimensionless discharge variable was integrated to incorporate influential parameters, including channel width, median particle diameter, and surface flow discharge. The results revealed that relationship with the debris flow density, slope and discharge required. Taking into account the behaviors of debris flow formation corresponding to different ranges of slopes, the critical runoff thresholds for debris flow initiation were calculated for three different scenarios. The thresholds were validated against actual debris flow events, and the use in this study is applicable.

  7. Microstructural evolution and macroscopic shrinkage in the presence of density gradients and agglomeration

    NASA Astrophysics Data System (ADS)

    Lu, Peizhen

    X-ray computed tomography (CT) can characterize internal density gradients. An in-situ laser dilatometry has been constructed to track dimensional change at different positions of a sample during binder removal and sintering. This combination of tools not only allows us to better understand how microscopic change affects macroscopic dimensions, but also provides guidance for a variety of ceramic processes. Non-uniform agglomerate packing and deformation provide density gradients which drive binder migration during binder removal. Simultaneously, density undergoes a slight decrease accompanied by a 1.0% loss in dimensional tolerance. This and CT difference images suggest that capillary forces generated during binder melting can change the density distribution. During sintering, nonuniformities present in the green state persist into the fired state and become exaggerated. Regions of different initial density can occupy different stages sintering. At ˜88% sintered density, CT clearly showed that open porosity follows the distribution of low density areas. Mercury porosimetry detected three distinct levels of porosity. Microstructural examination correlated the porosity level with the coordination of (i) two to three or (ii) multiple grains around pores. Microstructural packing controls both the observed macroscopic expansion at T ≤ 1000°C and the onset of shrinkage. Neck formation initiates during expansion and not exclusively during shrinkage. Inter- and intra-agglomerate expansion/shrinkage proceed simultaneously but the effective 'transmission' of particle-level behavior to the macroscopic level appears to be controlled by the initial agglomerate bonding and internal agglomerate densities. Discrete element modeling provides corroborating evidence regarding the importance of compact continuity. Following the expansion-shrinkage transition, the higher the zone density the faster the initial shrinkage. The 25% RH sample shrank more rapidly than the same zone in

  8. Carbon particles

    DOEpatents

    Hunt, Arlon J.

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  9. Space debris executive summary

    SciTech Connect

    Canavan, G.H.; Judd, O.; Naka, R.F.

    1996-09-01

    Spacecraft, boosters, and fragments are potential hazards to space vehicles, and it is argued that collisions between them could produce a cascade that could preclude activity in LEO in 25 to 50 years. That has generated pressure for constraints on military space operations, so the AF SAB performed a study of technical aspects of the debris problem. The Study was independent of the efforts of the Air Force Space Command (AFSPC) as well as those of and NASA Johnson Space Center (JSC), which is the principal advocate for cascades and constraints. Most work on space debris has been performed by AFSPC and JSC, so the Study was in part an assessment of their efforts, in which both have been cooperative. The Study identified the main disagreements and quantified their impacts. It resolved some issues and provided bounds for the rest. It treated radar and optical observations; launch, explosion, and decay rates; and the number and distribution of fragments from explosions and collisions. That made it possible to address hazard to manned spacecraft at low altitudes and the possibility of cascading at higher altitudes, both of which now appear less likely.

  10. Plastic debris in the open ocean.

    PubMed

    Cózar, Andrés; Echevarría, Fidel; González-Gordillo, J Ignacio; Irigoien, Xabier; Ubeda, Bárbara; Hernández-León, Santiago; Palma, Alvaro T; Navarro, Sandra; García-de-Lomas, Juan; Ruiz, Andrea; Fernández-de-Puelles, María L; Duarte, Carlos M

    2014-07-15

    There is a rising concern regarding the accumulation of floating plastic debris in the open ocean. However, the magnitude and the fate of this pollution are still open questions. Using data from the Malaspina 2010 circumnavigation, regional surveys, and previously published reports, we show a worldwide distribution of plastic on the surface of the open ocean, mostly accumulating in the convergence zones of each of the five subtropical gyres with comparable density. However, the global load of plastic on the open ocean surface was estimated to be on the order of tens of thousands of tons, far less than expected. Our observations of the size distribution of floating plastic debris point at important size-selective sinks removing millimeter-sized fragments of floating plastic on a large scale. This sink may involve a combination of fast nano-fragmentation of the microplastic into particles of microns or smaller, their transference to the ocean interior by food webs and ballasting processes, and processes yet to be discovered. Resolving the fate of the missing plastic debris is of fundamental importance to determine the nature and significance of the impacts of plastic pollution in the ocean.

  11. Plastic debris in the open ocean

    PubMed Central

    Cózar, Andrés; Echevarría, Fidel; González-Gordillo, J. Ignacio; Irigoien, Xabier; Úbeda, Bárbara; Hernández-León, Santiago; Palma, Álvaro T.; Navarro, Sandra; García-de-Lomas, Juan; Ruiz, Andrea; Fernández-de-Puelles, María L.; Duarte, Carlos M.

    2014-01-01

    There is a rising concern regarding the accumulation of floating plastic debris in the open ocean. However, the magnitude and the fate of this pollution are still open questions. Using data from the Malaspina 2010 circumnavigation, regional surveys, and previously published reports, we show a worldwide distribution of plastic on the surface of the open ocean, mostly accumulating in the convergence zones of each of the five subtropical gyres with comparable density. However, the global load of plastic on the open ocean surface was estimated to be on the order of tens of thousands of tons, far less than expected. Our observations of the size distribution of floating plastic debris point at important size-selective sinks removing millimeter-sized fragments of floating plastic on a large scale. This sink may involve a combination of fast nano-fragmentation of the microplastic into particles of microns or smaller, their transference to the ocean interior by food webs and ballasting processes, and processes yet to be discovered. Resolving the fate of the missing plastic debris is of fundamental importance to determine the nature and significance of the impacts of plastic pollution in the ocean. PMID:24982135

  12. Orbital debris removal and salvage system

    NASA Technical Reports Server (NTRS)

    1990-01-01

    Four Texas A&M University projects are discussed. The first project is a design to eliminate a majority of orbital debris. The Orbital Debris and Salvage System will push the smaller particles into lower orbits where their orbits will decay at a higher rate. This will be done by momentum transfer via laser. The salvageable satellites will be delivered to the Space Station by an Orbital Transfer Vehicle. The rest of the debris will be collected by Salvage I. The second project is the design of a space based satellite system to prevent the depletion of atmospheric ozone. The focus is on ozone depletion in the Antarctic. The plan is to use an orbiting solar array system designed to transmit microwaves at a frequency of 22 GHz over the region in order to dissipate polar stratospheric clouds that form during the months beginning in August and ending in October. The third project, Project Poseidon, involves a conceptual design of a space based hurricane control system consisting of a network of 21 low-orbiting laser platforms arranged in three rings designed to heat the upper atmosphere of a developing tropical depression. Fusion power plants are proposed to provide power for the lasers. The fourth project, Project Donatello, involves a proposed Mars exploration initiative for the year 2050. The project is a conceptual design for a futuristic superfreighter that will transport large numbers of people and supplies to Mars for the construction of a full scale scientific and manufacturing complex.

  13. Spatial patterns of plastic debris along Estuarine shorelines.

    PubMed

    Browne, Mark A; Galloway, Tamara S; Thompson, Richard C

    2010-05-01

    The human population generates vast quantities of waste material. Macro (>1 mm) and microscopic (<1 mm) fragments of plastic debris represent a substantial contamination problem. Here, we test hypotheses about the influence of wind and depositional regime on spatial patterns of micro- and macro-plastic debris within the Tamar Estuary, UK. Debris was identified to the type of polymer using Fourier-transform infrared spectroscopy (FT-IR) and categorized according to density. In terms of abundance, microplastic accounted for 65% of debris recorded and mainly comprised polyvinylchloride, polyester, and polyamide. Generally, there were greater quantities of plastic at downwind sites. For macroplastic, there were clear patterns of distribution for less dense items, while for microplastic debris, clear patterns were for denser material. Small particles of sediment and plastic are both likely to settle slowly from the water-column and are likely to be transported by the flow of water and be deposited in areas where the movements of water are slower. There was, however, no relationship between the abundance of microplastic and the proportion of clay in sediments from the strandline. These results illustrate how FT-IR spectroscopy can be used to identify the different types of plastic and in this case was used to indicate spatial patterns, demonstrating habitats that are downwind acting as potential sinks for the accumulation of debris.

  14. A Comparison of ESA and NASA Space Debris Models

    NASA Astrophysics Data System (ADS)

    Hauptmann, S.

    1996-12-01

    NASA recently developed a new orbital debris environment model for spacecraft design and observations in low earth orbit. This model has been implemented at ESA/ESTEC in an application which is able to assess debris flux distributions according to target and impactor orbital parameters as well as the directional dependencies of the impactor fluxes. In this paper, the following three models are compared: the above mentioned NASA model, the ESA MASTER Analyst Application, developed under ESA/ESOC contract in 1995 and the current NASA space debris reference model, which was developed in 1989. The conceptual designs of the three models are discussed and their quantitative predictions are compared for various target orbit characteristics, including more detailed analysis of the orbits of ERS-1, LDEF and ISSA (International Space Station Alpha). It is shown in particular that considerable discrepancies of more than one order of magnitude exist between the predictions of the different models in the region of sub-mm sized particles as well as for diameters greater than 1cm. Refined predictions of the debris flux given by the different models taking into account the orientation of the surface are investigated in the case of LDEF and ISSA. For further information on ESA and NASA space debris modelling activities have a look at the following sites:

    • Space Debris Activities at ESOC
    • Modelling the Space Environment at ESTEC
    • UNO Office of Outer Space Affairs
    • NASA-JSC Space Science Branch

  15. Summary of Disposable Debris Shields (DDS) Analysis for Development of Solid Debris Collection at NIF

    SciTech Connect

    Shaughnessy, D A; Moody, K J; Grant, P M; Lewis, L A; Hutcheon, I D; Lindvall, R; Gostic, J M

    2011-11-20

    is simply falling to the bottom of the chamber. In either case, it was determined that using the DDS, or fielding a debris collector at the chamber wall, was not feasible for solid debris collection at NIF due to the small amount of debris that had been collected. In addition, since the glass shields suffered quite a bit of damage from particles impacting the surface, glass was ruled out as a collection medium.

  16. On the effects of solar storms to the decaying orbital space debris

    SciTech Connect

    Herdiwijaya, Dhani; Rachman, Abdul

    2014-03-24

    Any man-made object in Earth's orbit that no longer serves a useful purpose is classified as orbital debris. Debris objects come from a variety of sources. The majority is related to satellite fragmentation. Other major sources of debris are propulsion systems, and fragmentation of spent upper stages, payload and mission related debris. Serious concern about orbital debris has been growing. Knowledge of the future debris environment is important to both satellite designers, and mission planners, who need to know what hazards a satellite might encounter during the course of its mission. Therefore, it is important to know how much debris is in orbit, where it is located, and when it will decay. The debris environment is complex and dynamically evolving. Objects of different shape and size behave differently in orbit. The geoeffectiveness space environments include solar flux at 10.7 cm, solar energetic particles flux or speed, solar wind flow pressure, electric field, and geomagnetic indices. We study the decaying orbital debris from Tracking and Impact Prediction (TIP) messages in conjuction with geoeffectiveness space environments through time epoch correlation. We found that the decaying and reentry orbital debris are triggered by space environment enhancement within at least one week before reentry. It is not necessary a transient or high energetic and severe solar storm events are needed in decaying processes. We propose that the gradual enhancement processes of space environment will cause satellite surface charging due to energetic electron and enhance drag force.

  17. Debris and meteoroid proportions deduced from impact crater residue analysis

    SciTech Connect

    Berthoud, L.; Mandeville, J.C.; Durin, C.; Borg, J. |

    1995-02-01

    This study is a further investigation of space-exposed samples recovered from the LDEF satellite and the Franco-Russian `Aragatz` dust collection experiment on the Mir Space Station. Impact craters with diameters ranging from 1 to 900 micron were found on the retrieved samples. Elemental analysis of residues found in the impact craters was carried out using Energy Dispersive X-ray spectrometry (EDX). The analyses show evidence of micrometeoroid and orbital debris origins for the impacts. The proportions of these two components vary according to particle size and experimental position with respect to the leading edge of the spacecraft. On the LDEF leading edge 17 percent of the impacts were apparently caused by micrometeoroids and 11 percent by debris; on the LDEF trailing edge 23 percent of the impacts are apparently caused by micrometeoroids and 4 percent consist of debris particles - mostly larger than 3 micron in diameter - in elliptical orbits around the Earth. For Mir, the analyses indicate that micrometeoroids form 23 percent of impacts and debris 9 percent. However, the authors note that 60-70 percent of the craters are unidentifiable, so the definitive proportions of natural vs. man-made particles are yet to be determined. Experiments carried out using a light gas gun to accelerate glass spheres and fragments demonstrate the influence of particle shape on crater morphology. The experiments also show that it is more difficult to analyze the residues produced by an irregular fragment than those produced by a spherical projectile. If the particle is travelling above a certain velocity, it vaporizes upon impact and no residues are left. Simulation experiments carried out with an electrostatic accelerator indicate that this limit is about 14 km/s for Fe particles impacting Al targets. This chemical analysis cut-off may bias interpretations of the relative populations of meteoroid and orbital debris.

  18. Debris and meteoroid proportions deduced from impact crater residue analysis

    NASA Technical Reports Server (NTRS)

    Berthoud, Lucinda; Mandeville, Jean-Claude; Durin, Christian; Borg, Janet

    1995-01-01

    This study is a further investigation of space-exposed samples recovered from the LDEF satellite and the Franco-Russian 'Aragatz' dust collection experiment on the Mir Space Station. Impact craters with diameters ranging from 1 to 900 micron were found on the retrieved samples. Elemental analysis of residues found in the impact craters was carried out using Energy Dispersive X-ray spectrometry (EDX). The analyses show evidence of micrometeoroid and orbital debris origins for the impacts. The proportions of these two components vary according to particle size and experimental position with respect to the leading edge of the spacecraft. On the LDEF leading edge 17 percent of the impacts were apparently caused by micrometeoroids and 11 percent by debris; on the LDEF trailing edge 23 percent of the impacts are apparently caused by micrometeoroids and 4 percent consist of debris particles - mostly larger than 3 micron in diameter - in elliptical orbits around the Earth. For Mir, the analyses indicate that micrometeoroids form 23 percent of impacts and debris 9 percent. However, we note that 60-70 percent of the craters are unidentifiable, so the definitive proportions of natural v. man-made particles are yet to be determined. Experiments carried out using a light gas gun to accelerate glass spheres and fragments demonstrate the influence of particle shape on crater morphology. The experiments also show that it is more difficult to analyze the residues produced by an irregular fragment than those produced by a spherical projectile. If the particle is travelling above a certain velocity, it vaporizes upon impact and no residues are left. Simulation experiments carried out with an electrostatic accelerator indicate that this limit is about 14 km/s for Fe particles impacting Al targets. This chemical analysis cut-off may bias interpretations of the relative populations of meteoroid and orbital debris. Oblique impacts and multiple foil detectors provide a higher likelihood

  19. Catalytic soot oxidation in microscale experiments: Simulation of interactions between co-deposited graphitic nanoparticle agglomerates and platinum nanoparticles

    NASA Astrophysics Data System (ADS)

    Seipenbusch, Martin; Friedlander, Sheldon K.

    2004-12-01

    Continuously regenerating catalytic soot traps are under development to reduce particulate emissions from diesel exhaust. A good understanding of the processes that take place during soot oxidation is needed to optimize diesel soot trap performance. To gain insight into these processes from the perspective of nanoparticle technology, the effects of catalyst particle size and the interparticle distance between soot and catalyst particles were measured. A model catalyst was prepared by depositing Pt nanoparticles on a SiO/SiO2-coated transmission electron microscope (TEM) grid. A soot surrogate composed of graphitic nanoparticle agglomerates generated by laser ablation was deposited on the same surface. This system simulates, morphologically, catalytic soot traps used in practice. The reaction was carried out in a tubular flow reactor in which the gas phase simulated diesel exhaust gas, composed of a mixture of 10% O2 and 1000 ppm NO with the remainder N2. The progress of the carbon nanoparticle oxidation was monitored off-line by analysis of electron microscopy images of the agglomerates before and after reaction. This experimental method permitted the correlation of reaction rate with particle sizes and separation distances as well as catalyst surface area in the direct environs of the soot particles. The experimental results revealed no effect of Pt catalyst particle size in the range 7-31 nm on the rate of reaction. Also observed were a decrease in the rate of reaction with increasing distance between carbon agglomerates and catalyst particles and a linear dependence of the reaction rate on the fractional catalyst surface area coverage.

  20. Space debris modeling at NASA

    NASA Astrophysics Data System (ADS)

    Johnson, Nicholas L.

    2001-10-01

    Since the Second European Conference on Space Debris in 1997, the Orbital Debris Program Office at the NASA Johnson Space Center has undertaken a major effort to update and improve the principal software tools employed to model the space debris environment and to evaluate mission risks. NASA's orbital debris engineering model, ORDEM, represents the current and near-term Earth orbital debris population from the largest spacecraft to the smallest debris in a manner which permits spacecraft engineers and experimenters to estimate the frequency and velocity with which a satellite may be struck by debris of different sizes. Using expanded databases and a new program design, ORDEM2000 provides a more accurate environment definition combined with a much broader array of output products in comparison with its predecessor, ORDEM96. Studies of the potential long-term space debris environment are now conducted with EVOVLE 4.0, which incorporates significant advances in debris characterization and breakup modeling. An adjunct to EVOLVE 4.0, GEO EVOLVE has been created to examine debris issues near the geosynchronous orbital regime. In support of NASA Safety Standard (NSS) 1740.14, which establishes debris mitigation guidelines for all NASA space programs, a set of evaluation tools called the Debris Assessment Software (DAS) is specifically designed for program offices to determine whether they are in compliance with NASA debris mitigation guidelines. DAS 1.5 has recently been completed with improved WINDOWS compatibility and graphics functions. DAS 2.0 will incorporate guideline changes in a forthcoming revision to NSS 1740.14. Whereas DAS contains a simplified model to calculate possible risks associated with satellite reentries, NASA's higher fidelity Object Reentry Survival Analysis Tool (ORSAT) has been upgraded to Version 5.0. With the growing awareness of the potential risks posed by uncontrolled satellite reentries to people and property on Earth, the application of

  1. Dust particles in controlled fusion devices: morphology, observations in the plasma and influence on the plasma performance

    NASA Astrophysics Data System (ADS)

    Rubel, M.; Cecconello, M.; Malmberg, J. A.; Sergienko, G.; Biel, W.; Drake, J. R.; Hedqvist, A.; Huber, A.; Philipps, V.

    2001-08-01

    The formation and release of particle agglomerates, i.e. debris and dusty objects, from plasma facing components and the impact of such materials on plasma operation in controlled fusion devices has been studied in the Extrap T2 reversed field pinch and the TEXTOR tokamak. Several plasma diagnostic techniques, camera observations and surface analysis methods were applied for in situ and ex situ investigation. The results are discussed in terms of processes that are decisive for dust transfer: localized power deposition connected with wall locked modes causing emission of carbon granules, brittle destruction of graphite and detachment of thick flaking co-deposited layers. The consequences for large next step devices are also addressed.

  2. The Challenge of Orbital Debris

    NASA Technical Reports Server (NTRS)

    Matney, Mark

    2012-01-01

    Since the dawn of the Space Age more than 50 years ago, humans have been launching objects into the space environment faster than they have been removed by active means or natural decay. This has led to a proliferation of debris -- derelict satellites, discarded rocket upper stages, and pieces from satellite breakups -- in Earth orbit, especially in well-used orbital regimes. This talk will summarize the current knowledge of the debris environment and describe plans to address the challenges orbital debris raises for the future usability of near-Earth space. The talk will be structured around 4 categories: Measurements, Modeling, Shielding, and Mitigation. This will include discussions of the long-term prognosis of debris growth (i.e., the "Kessler Syndrome") as well as plans for active debris removal.

  3. Vulnerability Assessment of Rainfall-Induced Debris Flow

    NASA Astrophysics Data System (ADS)

    Lu, G. Y.; Wong, D. W.; Chiu, L. S.

    2006-05-01

    Debris flow is a common hazard triggered by large amount of rainfall over mountainous areas. A debris flow event results from a complex interaction between rainfall and topographical properties of watersheds. Heavy rainfall facilitates this process by increasing pore water pressure, seepage force and reducing effective stress of soils (normal stress carried by soil particles at the points of contact). Since debris flow events are closely related to topography and rainfall, the goal of this research is to assess debris flow vulnerability related to these two factors. Objectives of this research are to: (1) examine new spatial interpolation techniques to estimate high spatial rainfall data relevant to debris flows. (2) develop topographical factors using Geography Information System (GIS) and remote sensing (RS) approaches and (3) combine the estimated rainfall and topographical factors to assess the vulnerability of debris flow. We examined three spatial interpolation techniques: adaptive inversed distance weight (AIDW), simple kriging and spatial disaggregation using wind induced-topographic effect that incorporates gauge measurements, satellite remote sensing data (TRMM). The topographical factors are derived from high resolution digital elevation model (DEM), and adopt fuzzy-based topographical models proposed by Tseng (2004). Estimated rainfall and topographical factors are processed by self-organizing maps (SOM) to provide vulnerability assessment. To demonstrate our technique, rainfall data collected by 39 rain gauges in the central part of Taiwan during the passage of Typhoon Tori-Ji around July 29, 2001 were used. Results indicate that the proposed spatial interpolation methods outperform existing methods (i.e. kriging, inverse distance weight, and co-kriging methods). The vulnerability assessment of 187 debris flows watersheds in the study area will be presented. Keyword: Debris flow, spatial interpolation, adaptive inverse distance weight, TRMM, self

  4. Universities' Entrepreneurial Performance: The Role of Agglomeration Economies

    ERIC Educational Resources Information Center

    Chen, Ping Penny

    2011-01-01

    In spite of the extensive research on universities' entrepreneurship, whether research strength fosters or dampens their entrepreneurial performance remains controversial. Much research claims an influential role of research universities in regional economy, however, little has been said about what a part that the agglomeration economies may play…

  5. Engineering development of selective agglomeration. Site closeout report

    SciTech Connect

    Not Available

    1993-04-01

    The Selective Agglomeration POC facility consisted of a coal crushing and grinding circuit, followed by an agglomeration circuit and product dewatering. (A plot plan of the facility is shown in Figure 1-2.) The coal crushing and grinding system consisted of a hammermill coal crusher, weigh-belt feeder, two ball mills (primary and secondary), and necessary hoppers, pumps, and conveyors. The mills were capable of providing coal over a range of grinds from a d{sub 50} of 125 to 25 microns. Slurry discharged from the ball mills was pumped to the agglomeration circuit. The agglomeration circuit began with a high-shear mixer, where diesel was added to the slurry to begin the formation of microagglomerates. The high-shear mixer was followed by two stages of conventional flotation cells for microagglomerate recovery. The second-stage-flotation-cell product was pumped to either a rotary-drum vacuum filter or a high-G centrifuge for dewatering. The dewatered product was then convoyed to the product pad from which dump trucks were used to transfer it to the utility plant located next to the facility. Plant tailings were pumped to the water clarifier for thickening and then dewatered in plate-and-frame filter presses. These dewatered tailings were also removed to the utility via dump truck. Clarified water (thickener overflow) was recycled to the process via a head tank.

  6. Micrometeoroids and debris on LDEF comparison with MIR data

    NASA Technical Reports Server (NTRS)

    Mandeville, Jean-Claude; Berthoud, Lucinda

    1995-01-01

    Part of the LDEF tray allocated to French experiments (FRECOPA) has been devoted to the study of dust particles. The tray was located on the face of LDEF directly opposed to the velocity vector. Crater size distributions have made possible the evaluation of the incident microparticle flux in the near-Earth environment. Comparisons are made with measurements obtained on the other faces of LDEF (tray clamps), on the leading edge (MAP) and with results of a similar experiment flown on the MIR space station. The geometry of impact craters, depth in particular, provides useful information on the nature of impacting particles and the correlation of geometry with the chemical analysis of projectile remnants inside craters make possible a discrimination between meteoroids and orbital debris. Emphasis has been laid on the size distribution of small craters in order to assess a cut-off in the distribution of particles in LEO. Special attention has been paid to the phenomenon of secondary impacts. A comparison of flight data with current models of meteoroids and space debris shows a fair agreement for LDEF, except for the smaller particles: the possible contribution of orbital debris in GTO orbits to the LDEF trailing edge flux is discussed. For MIR, flight results show differences with current modeling: the possible enhancement of orbital debris could be due to the contaminating presence of a permanently manned space station.

  7. Meteoroid/Orbital Debris Shield Engineering Development Practice and Procedure

    NASA Technical Reports Server (NTRS)

    Zwitter, James G.; Adams, Marc A.

    2011-01-01

    A document describes a series of models created for the determination of the probability of survival of critical spacecraft components from particle strike damage caused by hypervelocity impact of meteoroids and/or orbital debris. These models were integrated with both shield design and hypervelocity impact testing to develop adequate protection of said components to meet mission survivability requirements.

  8. Reverse micelle synthesis of oxide nanopowders: mechanisms of precipitate formation and agglomeration effects.

    PubMed

    Graeve, Olivia A; Fathi, Hoorshad; Kelly, James P; Saterlie, Michael S; Sinha, Kaustav; Rojas-George, Gabriel; Kanakala, Raghunath; Brown, David R; Lopez, Enrique A

    2013-10-01

    We present an analysis of reverse micelle stability in four model systems. The first two systems, composed of unstable microemulsions of isooctane, water, and Na-AOT with additions of either iron sulfate or yttrium nitrate, were used for the synthesis of iron oxide or yttrium oxide powders. These oxide powders were of nanocrystalline character, but with some level of agglomeration that was dependent on calcination temperature and cleaning procedures. Results show that even though the reverse micellar solutions were unstable, nanocrystalline powders with very low levels of agglomeration could be obtained. This effect can be attributed to the protective action of the surfactant on the surfaces of the powders that prevents neck formation until after all the surfactant has volatilized. A striking feature of the IR spectra collected on the iron oxide powders is the absence of peaks in the ~1715 cm(-1) to 1750 cm(-1) region, where absorption due to the symmetric C=O (carbonyl) stretching occurs. The lack of such peaks strongly suggests the carbonyl group is no longer free, but is actively participating in the surfactant-precipitate interaction. The final two microemulsion systems, containing CTAB as the surfactant, showed that loss of control of the reverse micelle synthesis process can easily occur when the amount of salt in the water domains exceeds a critical concentration. Both model systems eventually resulted in agglomerated powders of broad size distributions or particles that were large compared to the sizes of the reverse micelles, consistent with the notion that the microemulsions were not stable and the powders were precipitated in an uncontrolled fashion. This has implications for the synthesis of nanopowders by reverse micelle synthesis and provides a benchmark for process control if powders of the highest quality are desired.

  9. Orbital Debris Research at NASA

    NASA Technical Reports Server (NTRS)

    Stansbery, Eugene G.

    2009-01-01

    The United States has one of the most active programs of research of the orbital debris environment in the world. Much of the research is conducted by NASA s Orbital Debris Program Office at the Johnson Space Center. Past work by NASA has led to the development of national space policy which seeks to limit the growth of the debris population and limit the risk to spacecraft and humans in space and on the Earth from debris. NASA has also been instrumental in developing consistent international policies and standards. Much of NASA's efforts have been to measure and characterize the orbital debris population. The U.S. Department of Defense tracks and catalogs spacecraft and large debris with it's Space Surveillance Network while NASA concentrates on research on smaller debris. In low Earth orbit, NASA has utilized short wavelength radars such as Haystack, HAX, and Goldstone to statistically characterize the population in number, size, altitude, and inclination. For higher orbits, optical telescopes have been used. Much effort has gone into the understanding and removal of observational biases from both types of measurements. NASA is also striving to understand the material composition and shape characteristics of debris to assess these effects on the risk to operational spacecraft. All of these measurements along with data from ground tests provide the basis for near- and long-term modeling of the environment. NASA also develops tools used by spacecraft builders and operators to evaluate spacecraft and mission designs to assess compliance with debris standards and policies which limit the growth of the debris environment.

  10. An Introduction to Space Debris

    NASA Astrophysics Data System (ADS)

    Wright, David

    2008-04-01

    Space debris is any human-made object in orbit that no longer serves a useful purpose, including defunct satellites, discarded equipment and rocket stages, and fragments from the breakup of satellites and rocket stages. It is a concern because--due to its very high speed in orbit--even relatively small pieces can damage or destroy satellites in a collision. Since debris at high altitudes can stay in orbit for decades or longer, it accumulates as more is produced and the risk of collisions with satellites grows. Since there is currently no effective way to remove large amounts of debris from orbit, controlling the production of debris is essential for preserving the long-term use of space. Today there are 860 active satellites in orbit, supporting a wide range of civil and military uses. The 50 years of space activity since the launch of Sputnik 1 has also resulted in well over half a million pieces of orbiting debris larger than 1 cm in size. There are two main sources of space debris: (1) routine space activity and the accidental breakup of satellites and stages placed in orbit by such activity, and (2) the testing or use of destructive anti-satellite (ASAT) weapons that physically collide with satellites at high speed. The international community is attempting to reduce the first category by developing strict guidelines to limit the debris created as a result of routine space activities. However, the destruction of a single large spy satellite by an ASAT weapon could double the total amount of large debris in low earth orbit, and there are currently no international restrictions on these systems. This talk will give an introduction to what's in space, the origins of space debris, efforts to stem its growth, the threat it poses to satellites in orbit, and the long-term evolution of the debris population.

  11. Space debris: modeling and detectability

    NASA Astrophysics Data System (ADS)

    Wiedemann, C.; Lorenz, J.; Radtke, J.; Kebschull, C.; Horstmann, A.; Stoll, E.

    2017-01-01

    High precision orbit determination is required for the detection and removal of space debris. Knowledge of the distribution of debris objects in orbit is necessary for orbit determination by active or passive sensors. The results can be used to investigate the orbits on which objects of a certain size at a certain frequency can be found. The knowledge of the orbital distribution of the objects as well as their properties in accordance with sensor performance models provide the basis for estimating the expected detection rates. Comprehensive modeling of the space debris environment is required for this. This paper provides an overview of the current state of knowledge about the space debris environment. In particular non-cataloged small objects are evaluated. Furthermore, improvements concerning the update of the current space debris model are addressed. The model of the space debris environment is based on the simulation of historical events, such as fragmentations due to explosions and collisions that actually occurred in Earth orbits. The orbital distribution of debris is simulated by propagating the orbits considering all perturbing forces up to a reference epoch. The modeled object population is compared with measured data and validated. The model provides a statistical distribution of space objects, according to their size and number. This distribution is based on the correct consideration of orbital mechanics. This allows for a realistic description of the space debris environment. Subsequently, a realistic prediction can be provided concerning the question, how many pieces of debris can be expected on certain orbits. To validate the model, a software tool has been developed which allows the simulation of the observation behavior of ground-based or space-based sensors. Thus, it is possible to compare the results of published measurement data with simulated detections. This tool can also be used for the simulation of sensor measurement campaigns. It is

  12. Formulation effects on the release of silica dioxide nanoparticles from paint debris to water.

    PubMed

    Zuin, Stefano; Massari, Andrea; Ferrari, Arlen; Golanski, Luana

    2014-04-01

    Waterborne paints with integrated nanoparticles have been recently introduced into the market as nanoparticles offer improved or novel functionalities to paints. However, the release of nanoparticles during the life cycle of nano-enhanced paint has only been studied to a very limited extent. The paint composition could determine in what quantities and forms the nanoparticles are released. In this work, paint formulations containing the same amount of silicon dioxide (SiO2) nanoparticles but differing in the pigment volume concentration (PVC) and in amount and type of binder and pigment, were studied through leaching test to investigate the influence of these parameters on release of Si from paint. The results indicate greater release of Si, about 1.7 wt.% of the SiO2 nanoparticles in the paint, for paint formulated with higher PVC value (63%), suggesting that the PVC is a crucial factor for release of SiO2 nanoparticles from paints. This hypothesis was also based on the fact that agglomerates of SiO2 nanoparticles were only found in leachates from paint with higher PVC. A paint sample with the higher amount of binder and less calcite filler exhibited a lower release of Si among the paints with a low PVC value (35%), and no SiO2 particles were detected in leachates collected from this paint. This could be due to the fact that a high portion of binder forms a suitable matrix to hold the SiO2 ENPs in paint. The paint sample in which the amount of calcite was partially substituted with TiO2 pigment did not show an important reduction on Si release. Our work suggests that paint debris containing SiO2 nanoparticles may release a limited amount of Si into the environment, and that by adjusting the properties of the binder in combination with common pigments it is possible to reduce the release of SiO2 nanoparticles.

  13. Russian space agency activities on the problem of technogenic space debris

    NASA Astrophysics Data System (ADS)

    Blagun, V. P.; Kulik, S. V.; Lukyashchenko, V. I.

    1999-01-01

    In this paper the main directions and the major results of the activities on the problem of technogenic near-earth space (NES) orbital debris are discussed. With regard to monitoring the NES debris environment, the following issues are considered: the catalogue of space objects which includes objects in the geostationary ring, orbital debris models, and ground- and space-based observations. For the protection of spacecraft and Space Station from debris particles multilayer and other shields are used, as well as avoidance manoeuvres. Important issues are the determination of the location of impacts and restoration of the station wall tightness. The BUFFER program has been developed for the risk assessment of impacts of orbital debris particles with the Space Station. Measures are taken to reduce technogenic pollution of NES which include those to prevent launch vehicles and spacecraft explosions. Special attention is placed on the safe utilization of the geostationary orbit. From the results of these studies regulatory documents are issued.

  14. Space Shuttle and Launch Pad Lift-Off Debris Transport Analysis: SRB Plume-Driven

    NASA Technical Reports Server (NTRS)

    West, Jeff; Strutzenberg, Louis; Dougherty, Sam; Radke, Jerry; Liever, Peter

    2007-01-01

    This paper discusses the Space Shuttle Lift-Off model developed for potential Lift-Off Debris transport. A critical Lift-Off portion of the flight is defined from approximately 1.5 sec after SRB Ignition up to 'Tower Clear', where exhaust plume interactions with the Launch Pad occur. A CFD model containing the Space Shuttle and Launch Pad geometry has been constructed and executed. The CFD model works in conjunction with a debris particle transport model and a debris particle impact damage tolerance model. These models have been used to assess the effects of the Space Shuttle plumes, the wind environment, their interactions with the Launch Pad, and their ultimate effect on potential debris during Lift-Off. Emphasis in this paper is on potential debris that might be caught by the SRB plumes.

  15. Aerosol-Assisted Solid Debris Collection for the National Ignition Facility

    SciTech Connect

    Nelson, S L; Shaughnessy, D A; Moody, K J; Ivanov, V V; Astanovitskiy, A L; Lewis, L A; Rundberg, R S

    2010-05-21

    collection device entirely. Our goal is to use this primary ablation wave to our advantage, by the creation of ionized alkali metal halide salt aerosols. This technique is similar to that used by many particle accelerator groups for gas-jet transport. Ideally the salt would be ablated from a substrate, encounter the reaction debris, agglomerate, and be collected for further study. We have done studies at laser and pulsed-power facilities (Titan laser at LLNL, Trident laser at LANL, Zebra z-pinch at Nevada Terawatt Facility) evaluating the hardiness of materials for placement in the NIF target chamber, as well as testing aerosol generation by the incident x-rays generated in device shots. To test this method's potential success in the NIF environment, we have tested KCl, KI, RbI, and CsI films of 1 and 2 um linear thickness on aluminum and silicon wafer substrates in these aforementioned facilities, at varied distances. These salts do ablate in the presence of sufficient x-ray fluence. Further analysis to quantify the final ablation depth as a function of x-ray fluence is ongoing. Half of each sample was masked with a thick tungsten foil for photon opacity. KCl was the most difficult salt to ablate, from comparing the tungsten-masked side of the samples to the unmasked side of the samples. This is likely due to KCl's absorbance peak being at lower wavelengths than that of KI, {approx}160 nm vs. {approx}220 nm, respectively. Samples with and without collimation were tested to identify if any condensation of these ablated salts occurred after ablation. Visual inspection of the silicon wafer witness plates placed parallel to the direction of the incident photons showed that a vapor was deposited on the wafers next to the collimators. Further analysis with EDS in the case of the collimated samples conclusively identified the vapor as CsI. We also intend to examine samples of bare substrate exposed to the same experimental conditions for post-shot change via SEM images, optical

  16. Investigation of Orbital Debris: Mitigation, Removal, and Modeling the Debris Population

    NASA Astrophysics Data System (ADS)

    Slotten, Joel

    The population of objects in orbit around Earth has grown since the late 1950s. Today there are over 21,000 objects over 10 cm in length in orbit, and an estimated 500,000 more between 1 and 10 cm. Only a small fraction of these objects are operational satellites. The rest are debris: old derelict spacecraft or rocket bodies, fragments created as the result of explosions or collisions, discarded objects, slag from solid rockets, or even flaked off paint. Traveling at up to 7 km/s, a collision with even a 1 cm piece of debris could severely damage or destroy a satellite. This dissertation examines three aspects of orbital debris. First, the concept of a self-consuming satellite is explored. This nanosatellite would use its own external structure as propellant to execute a deorbit maneuver at the end of its operational life, thus allowing it to meet current debris mitigation standards. Results from lab experiments examining potential materials for this concept have shown favorable results. Second, Particle in Cell techniques are modified and used to model the plasma plume from a micro-cathode arc thruster. This model is then applied to the concept of an ion beam shepherd satellite. This satellite would use its plasma plume to deorbit another derelict satellite. Results from these simulations indicate the micro-cathode arc thruster could potentially deorbit a derelict CubeSat in a matter of a few weeks. Finally, the orbital debris population at geosynchronous orbit is examined, focusing on variations in the density of the population as a function of longitude. New insights are revealed demonstrating that the variation in population density is slightly less than previously reported.

  17. Implementation of the hazardous debris rule

    SciTech Connect

    Sailer, J.E.

    1993-01-05

    Hazardous debris includes objects contaminated with hazardous waste. Examples of debris include tree stumps, timbers, boulders, tanks, piping, crushed drums, personal protective clothing, etc. Most of the hazardous debris encountered comes from Superfund sites and other facility remediation, although generators and treaters of hazardous waste also generate hazardous debris. Major problems associated with disposal of debris includes: Inappropriateness of many waste treatments to debris; Difficulties in obtaining representative samples; Costs associated with applying waste specific treatments to debris; Subtitle C landfill space was being used for many low hazard debris types. These factors brought about the need for debris treatment technologies and regulations that addressed these issues. The goal of such regulation was to provide treatment to destroy or remove the contamination if possible and, if this is achieved, to dispose of the cleaned debris as a nonhazardous waste. EPA has accomplished this goal through promulgation of the Hazardous Debris Rule, August 18, 1992.

  18. OXIDATIVE STRESS AND LIPID MEDIATORS INDUCED IN ALVEOLAR MACHROPHAGES BY ULTRAFINE PARTICLES

    EPA Science Inventory

    In ambient aerosols, ultrafine particles (UFP) and their agglomerates are considered to be major factors contributing to adverse health effects. Reactivity of agglomerated UFP of elemental carbon (EC), Printex 90, Printex G, and diesel exhaust particles (DEP) was evaluated by the...

  19. Quantitative organic vapor-particle sampler

    DOEpatents

    Gundel, Lara; Daisey, Joan M.; Stevens, Robert K.

    1998-01-01

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  20. Electroless plating apparatus for discrete microsized particles

    DOEpatents

    Mayer, Anton

    1978-01-01

    Method and apparatus are disclosed for producing very uniform coatings of a desired material on discrete microsized particles by electroless techniques. Agglomeration or bridging of the particles during the deposition process is prevented by imparting a sufficiently random motion to the particles that they are not in contact with each other for a time sufficient for such to occur.

  1. JSC Orbital Debris Website Description

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2006-01-01

    Purpose: The website provides information about the NASA Orbital Debris Program Office at JSC, which is the lead NASA center for orbital debris research. It is recognized world-wide for its leadership in addressing orbital debris issues. The NASA Orbital Debris Program Office has taken the international lead in conducting measurements of the environment and in developing the technical consensus for adopting mitigation measures to protect users of the orbital environment. Work at the center continues with developing an improved understanding of the orbital debris environment and measures that can be taken to control its growth. Major Contents: Orbital Debris research is divided into the following five broad efforts. Each area of research contains specific information as follows: 1) Modeling - NASA scientists continue to develop and upgrade orbital debris models to describe and characterize the current and future debris environment. Evolutionary and engineering models are described in detail. Downloadable items include a document in PDF format and executable software. 2) Measurements - Measurements of near-Earth orbital debris are accomplished by conducting ground-based and space-based observations of the orbital debris environment. The data from these sources provide validation of the environment models and identify the presence of new sources. Radar, optical and surface examinations are described. External links to related topics are provided. 3) Protection - Orbital debris protection involves conducting hypervelocity impact measurements to assess the risk presented by orbital debris to operating spacecraft and developing new materials and new designs to provide better protection from the environment with less weight penalty. The data from this work provides the link between the environment defined by the models and the risk presented by that environment to operating spacecraft and provides recommendations on design and operations procedures to reduce the risk as

  2. The role of nanoparticulate agglomerates in TiO2 photocatalysis: degradation of oxalic acid

    NASA Astrophysics Data System (ADS)

    Ivanova, Irina; Mendive, Cecilia B.; Bahnemann, Detlef

    2016-07-01

    The simultaneous bimodal study of the photocatalytic oxalic acid degradation by aqueous TiO2 suspensions revealed that particular systems possess the capacity to protect a certain amount of oxalic acid from oxidation, thus hindering, to some extent, the photocatalytic reaction. While measurements of the oxalic acid concentration in the bulk liquid phase indicated full photocatalytic degradation; in situ pH-stat measurements allowed the quantification of the amount of oxalic acid remaining in the part of the nanoparticulate agglomerates where light could apparently not access. An explanation for this phenomenon takes into account the possibility of the formation of TiO2 agglomerates in which these molecules are hidden from the effect of the light, thus being protected from photocatalytic degradation. Studies of different TiO2 materials with different particle sizes allowed a deeper exploration of this phenomenon. In addition, because this property of encapsulating pollutant molecules by photocatalytic systems is found to be a reversible phenomenon, P25 appears to be more convenient and advantageous as compared to the use of large surface area photocatalysts.

  3. Occurrence of spherical ceramic debris in indentation and sliding contact

    NASA Technical Reports Server (NTRS)

    Miyoshi, K.; Buckley, D. H.

    1982-01-01

    Indenting experiments were conducted with the silicon carbide (0001) surface in contact with a spherical diamond indenter in air. Sliding friction experiments were also conducted with silicon carbide in contact with iron and iron-based binary alloys at room temperature and 800 C. Fracture pits with a spherical particle and spherical wear debris were observed as a result of indenting and sliding. Spherical debris may be produced by a mechanism that involves a spherical-shaped fracture along the circular or spherical stress trajectories under the inelastic deformation zone.

  4. Modeling collisions in circumstellar debris disks

    NASA Astrophysics Data System (ADS)

    Nesvold, Erika

    2015-10-01

    resonances near the chaotic zone. I investigate the effects of the initial eccentricity distribution of the disk particles and find a negligible effect on the gap size at Jovian planet masses, since collisions tend to erase memory of the initial particle eccentricity distributions. I also find that the presence of Trojan analogs is a potentially powerful diagnostic of planets in the mass range ˜1--10MJup. I apply my model to place new upper limits on planets around Fomalhaut, HR 4796 A, HD 202628, HD 181327, and beta Pictoris. Finally, to show how SMACK can be used to analyze a single debris disk in detail, I present a new model of the beta Pictoris disk and planet system that, for the first time, combines simulations of the colliding planetesimals and the dynamics of the dust grains, allowing me to model features and asymmetries in both submillimeter and scattered light images of the disk. I combine a 100,000 superparticle SMACK simulation with N-body integrations of the dust produced by the simulated collisions. I find that secular perturbations of the planet's measured inclination and eccentricity can explain the observed warp and planetesimal ring, while collisions between planetesimals shape the disk by eroding close-in material. The complex 3D structure of the disk due to the perturbations from the planet creates an azimuthally asymmetric spatial distribution of collisions, which could contribute to the observed azimuthal clump of CO gas seen with ALMA. My simulations of the small dust grains produced by collisions demonstrate that the "birth ring" approximation for beta Pictoris fails to account for the ˜54% of dust mass produced outside of the planetesimal ring. I also reproduce the gross morphology of high-resolution scattered light images of the disk, including the two-disk "x"-pattern seen in scattered light, which has not been replicated by previous dust dynamics models.

  5. Herschel DEBRIS survey of debris discs around A stars

    NASA Astrophysics Data System (ADS)

    Thureau, N.

    2014-11-01

    The Herschel DEBRIS survey (Disc Emission via a Bias-free Reconnaissance in the Infrared/Submillimetre) brings a unique perspective to the study of debris discs around main-sequence A-type stars. We have observed a sample of 89 A-stars with the Photodetector Array Camera and Spectrometer (PACS) on the Herschel space telescope at 100 and 160 μm. A statistical analysis of the data shows a lower debris disc rate than has previously been found. The drop is due in part to the fact that some excess sources were resolved as background objects by the superior angular resolution (a factor of 2.5) of PACS-100 relative to that of Spitzer (MIPS-70). We found a 3-σ detection rate of 23 myblue which is similar to the the detection rate around main-sequence F, G and K stars. Most of the debris discs were detected around the youngest and hottest stars in our sample. The incidence of discs in single and multiple systems was similar. The debris discs in multiple systems ware found either in tight binary systems (<1 AU) or wide ones (>100 AU). Debris discs in both tight and wide binary systems have physical properties that are statistically similar to those of discs around single stars. We did not detect any debris discs in binary systems with intermediate separation, in which the orbit and the debris disc would be on the same scale. One possible explanation is that discs in intermediate systems have evolved much faster owing to the disc-companion interactions and they are now undetectable.

  6. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris analysis... 14 Aeronautics and Space 4 2010-01-01 2010-01-01 false Debris analysis. 417.211 Section...

  7. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris analysis... 14 Aeronautics and Space 4 2013-01-01 2013-01-01 false Debris analysis. 417.211 Section...

  8. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris analysis... 14 Aeronautics and Space 4 2012-01-01 2012-01-01 false Debris analysis. 417.211 Section...

  9. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris analysis... 14 Aeronautics and Space 4 2011-01-01 2011-01-01 false Debris analysis. 417.211 Section...

  10. 14 CFR 417.211 - Debris analysis.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... TRANSPORTATION LICENSING LAUNCH SAFETY Flight Safety Analysis § 417.211 Debris analysis. (a) General. A flight safety analysis must include a debris analysis. For an orbital or suborbital launch, a debris analysis... 14 Aeronautics and Space 4 2014-01-01 2014-01-01 false Debris analysis. 417.211 Section...

  11. DIAGNOSING CIRCUMSTELLAR DEBRIS DISKS

    SciTech Connect

    Hahn, Joseph M.

    2010-08-20

    A numerical model of a circumstellar debris disk is developed and applied to observations of the circumstellar dust orbiting {beta} Pictoris. The model accounts for the rates at which dust is produced by collisions among unseen planetesimals, and the rate at which dust grains are destroyed due to collisions. The model also accounts for the effects of radiation pressure, which is the dominant perturbation on the disk's smaller but abundant dust grains. Solving the resulting system of rate equations then provides the dust abundances versus grain size and dust abundances over time. Those solutions also provide the dust grains' collisional lifetime versus grain size, and the debris disk's optical depth and surface brightness versus distance from the star. Comparison to observations then yields estimates of the unseen planetesimal disk's radius, and the rate at which the disk sheds mass due to planetesimal grinding. The model can also be used to measure or else constrain the dust grain's physical and optical properties, such as the dust grains' strength, their light-scattering asymmetry parameter, and the grains' efficiency of light scattering Q{sub s}. The model is then applied to optical observations of the edge-on dust disk orbiting {beta} Pictoris, and good agreement is achieved when the unseen planetesimal disk is broad, with 75 {approx}< r {approx}< 150 AU. If it is assumed that the dust grains are bright like Saturn's icy rings (Q{sub s} = 0.7), then the cross section of dust in the disk is A{sub d} {approx_equal} 2 x 10{sup 20} km{sup 2} and its mass is M{sub d} {approx_equal} 11 lunar masses. In this case, the planetesimal disk's dust-production rate is quite heavy, M-dot {sub d{approx}}9 M {sub +} Myr{sup -1}, implying that there is or was a substantial amount of planetesimal mass there, at least 110 Earth masses. If the dust grains are darker than assumed, then the planetesimal disk's mass-loss rate and its total mass are heavier. In fact, the apparent dearth

  12. Experimental investigation of sedimentation of LOCA - generated fibrous debris and sludge in BWR suppression pools

    SciTech Connect

    Souto, F.J.; Rao, D.V.

    1995-12-01

    Several tests were conducted in a 1:2.4 scale model of a Mark I suppression pool to investigate the behavior of fibrous insulation and sludge debris under LOCA conditions. NUKON{trademark} shreds, manually cut and tore up in a leaf shredder, and iron oxide particles were used to simulate fibrous and sludge debris, respectively. The suppression pool model included four downcomers fitted with pistons to simulate the steam-water oscillations during chugging expected during a LOCA. The study was conducted to provide debris settling velocity data for the models used in the BLOCKAGE computer code, developed to estimate the ECCS pump head loss due to clogging of the strainers with LOCA generated debris. The tests showed that the debris, both fibrous and particulate, remains fully mixed during chugging; they also showed that, during chugging, the fibrous debris underwent fragmentation into smaller sizes, including individual fibers. Measured concentrations showed that fibrous debris settled slower than the sludge, and that the settling behavior of each material is independent of the presence of the other material. Finally, these tests showed that the assumption of considering uniform debris concentration during strainer calculations is reasonable. The tests did not consider the effects of the operation of the ECCS on the transport of debris in the suppression pool.

  13. NASA Orbital Debris Baseline Populations

    NASA Technical Reports Server (NTRS)

    Krisko, Paula H.; Vavrin, A. B.

    2013-01-01

    The NASA Orbital Debris Program Office has created high fidelity populations of the debris environment. The populations include objects of 1 cm and larger in Low Earth Orbit through Geosynchronous Transfer Orbit. They were designed for the purpose of assisting debris researchers and sensor developers in planning and testing. This environment is derived directly from the newest ORDEM model populations which include a background derived from LEGEND, as well as specific events such as the Chinese ASAT test, the Iridium 33/Cosmos 2251 accidental collision, the RORSAT sodium-potassium droplet releases, and other miscellaneous events. It is the most realistic ODPO debris population to date. In this paper we present the populations in chart form. We describe derivations of the background population and the specific populations added on. We validate our 1 cm and larger Low Earth Orbit population against SSN, Haystack, and HAX radar measurements.

  14. Lightweight Shield Against Space Debris

    NASA Technical Reports Server (NTRS)

    Redmon, John W., Jr.; Lawson, Bobby E.; Miller, Andre E.; Cobb, W. E.

    1992-01-01

    Report presents concept for lightweight, deployable shield protecting orbiting spacecraft against meteoroids and debris, and functions as barrier to conductive and radiative losses of heat. Shield made in four segments providing 360 degree coverage of cylindrical space-station module.

  15. Debris about asteroids: Where and how much?

    NASA Technical Reports Server (NTRS)

    Burns, Joseph A.; Hamilton, Douglas P.

    1992-01-01

    We summarize several recent findings on the size and shape of the region within which material can stably orbit an asteroid. If the asteroid (with assumed density 2.38 g/cu cm) circles the Sun at 2.55 AU, co-planar prograde material will remain trapped whenever started on unperturbed circular orbits at less than about 220 R(sub A) (asteroid radii); co-planar retrograde particles are stable out twice as far. Our 3-D stability surface, which encloses several hundred numerically calculated orbits that start with various inclinations, is shaped like a sphere with its top and bottom sliced off; its dimensions scale like the Hill radius =(mu/3)(exp 1/3)R, where mu is the asteroid-to-solar mass ratio and R is the asteroid's orbital radius. If the asteroid moves along an elliptical orbit, a fairly reliable indicator of the dimensions of the hazard zone is the size of its Hill sphere at the orbit's pericenter. Grains with radii less than a few mm will be lost through the action of radiation forces which can induce escape or cause collisions with the asteroid on times scales of a few years; interplanetary micrometeoroids produce collisional break-up of these particles in approximately 10(exp 4) yrs. The effects of Jupiter and of asteroids that pass close to the target asteroid allow particles to diffuse from the system, again shrinking the hazard zone. None of the considered sources-primordial formation, debris spalled off the asteroid during micrometeoroid impact, captured interplanetary particles, feeder satellites, etc., seem capable of densely populating distant orbits from the asteroid. No certain detections of debris clouds or of binary asteroids have been made. Thus, it seems highly unlikely that a spacecraft fly-by targeted at 100 R(sub A) from the asteroid over its orbital pole would encounter any material.

  16. The impact of agglomeration economies on hospital input prices.

    PubMed

    Friedson, Andrew I; Li, Jing

    2015-12-01

    This paper examines the extent to which agglomeration of the hospital service industry enhances the productivity of producing health care. Specifically, we use a large set of private insurance claims from the FAIR Health database to show that an increasing spatial concentration of hospital services results in a decreased cost of obtaining intermediate medical services. We explicitly test whether the reduced cost at concentrated locations arises from the ability to share intermediate service providers. The identification relies on state variation in medical lab technician licensure requirements, which influence the cost of intermediate services only through the cost of running a lab. Our findings suggest that agglomeration of the hospital service industry attracts specialized medical labs, which in turn help to reduce the cost of producing laboratory tests.

  17. Engineering development of selective agglomeration: Trace element removal study

    SciTech Connect

    Not Available

    1993-09-01

    Southern Company Services, Inc., (SCS) was contracted in 1989 by the US Department of Energy (DOE) to develop a commercially acceptable selective agglomeration technology to enhance the use of high-sulfur coals by 1993. The project scope involved development of a bench-scale process and components, as well as the design, testing, and evaluation of a proof-of-concept (POC) facility. To that end, a two-ton-per-hour facility was constructed and tested near Wilsonville, Alabama. Although it was not the primary focus of the test program, SCS also measured the ability of selective agglomeration to remove trace elements from coal. This document describes the results of that program.

  18. Development of methods to predict agglomeration and disposition in FBCs

    SciTech Connect

    Mann, M.D.; Henderson, A.K.; Swanson, M.K.; Erickson, T.A.

    1995-11-01

    This 3-year, multiclient program is providing the information needed to determine the behavior of inorganic components in FBC units using advanced methods of analysis coupled with bench-scale combustion experiments. The major objectives of the program are as follows: (1) To develop further our advanced ash and deposit characterization techniques to quantify the effects of the liquid-phase components in terms of agglomerate formation and ash deposits, (2) To determine the mechanisms of inorganic transformations that lead to bed agglomeration and ash deposition in FBC systems, and (3) To develop a better means to predict the behavior of inorganic components as a function of coal composition, bed material characteristics, and combustion conditions.

  19. Preventing ash agglomeration during gasification of high-sodium lignite

    SciTech Connect

    Robert S. Dahlin; Johnny R. Dorminey; WanWang Peng; Roxann F. Leonard; Pannalal Vimalchand

    2009-01-15

    Various additives were evaluated to assess their ability to prevent ash agglomeration during the gasification of high-sodium lignite. Additives that showed promise in simple muffle furnace tests included meta-kaolin, vermiculite, two types of silica fume, and one type of bauxite. Additives that were tested and rejected included dolomite, calcite, sand flour, kaolinite, fine kaolin, and calcined bauxite. Based on the muffle furnace test results, the meta-kaolin was selected for a follow-on demonstration in a pilot-scale coal gasifier. Pilot-scale testing showed that the addition of coarse (minus 14-mesh, 920-{mu}m mean size) meta-kaolin at a feed rate roughly equivalent to the ash content of the lignite (10 wt %) successfully prevented agglomeration and deposition problems during gasification of high-sodium lignite at a maximum operating temperature of 927{sup o}C (1700{sup o}F). 13 refs., 24 figs., 1 tab.

  20. Numerical modelling of floating debris in the world's oceans.

    PubMed

    Lebreton, L C-M; Greer, S D; Borrero, J C

    2012-03-01

    A global ocean circulation model is coupled to a Lagrangian particle tracking model to simulate 30 years of input, transport and accumulation of floating debris in the world ocean. Using both terrestrial and maritime inputs, the modelling results clearly show the formation of five accumulation zones in the subtropical latitudes of the major ocean basins. The relative size and concentration of each clearly illustrate the dominance of the accumulation zones in the northern hemisphere, while smaller seas surrounded by densely populated areas are also shown to have a high concentration of floating debris. We also determine the relative contribution of different source regions to the total amount of material in a particular accumulation zone. This study provides a framework for describing the transport, distribution and accumulation of floating marine debris and can be continuously updated and adapted to assess scenarios reflecting changes in the production and disposal of plastic worldwide.

  1. The fate of debris in the Pluto-Charon system

    NASA Astrophysics Data System (ADS)

    Smullen, Rachel; Kratter, Kaitlin M.

    2016-05-01

    Pluto has recently been thrust into the spotlight with the fly-by of New Horizons. This dwarf planet and its moons provide an opportunity to study circumbinary dynamics close to home. We perform N-body simulations of a test-particle disk around the Pluto-Charon binary to study the fate of debris that should result from the formation of the Pluto-Charon binary. We not only investigate the stability and time evolution of debris within the Pluto system, but also track ejected debris to see where it may collect in the solar system. By studying the dynamics of the Pluto-Charon system, we may be able to place constraints on the cratering rates from its natal disk and identify tracers of the formation of this system.

  2. Bed Agglomeration During the Steam Gasification of a High Lignin Corn Stover Simultaneous Saccharification and Fermentation (SSF) Digester Residue

    SciTech Connect

    Howe, Daniel T.; Taasevigen, Danny J.; Gerber, Mark A.; Gray, Michel J.; Fernandez, Carlos A.; Saraf, Laxmikant; Garcia-Perez, Manuel; Wolcott, Michael P.

    2015-11-13

    This research investigates the bed agglomeration phenomena during the steam gasification of a high lignin residue produced from the simultaneous saccharification and fermentation (SSF) of corn stover in a bubbling fluidized bed. The studies were conducted at 895°C using alumina as bed material. Biomass was fed at 1.5 kg/hr, while steam was fed to give a velocity equal to 2.5 times the minimum fluidization velocity, with a steam/carbon ratio of 0.9. The pelletized feedstock was co-fed with a cooling nitrogen stream to mitigate feed line plugging issues. Tar production was high at 50.3 g/Nm3, and the fraction of C10+ compounds was greater than that seen in the gasification of traditional lignocellulosic feedstocks. Carbon closures over 94 % were achieved for all experiments. Bed agglomeration was found to be problematic, indicated by pressure drop increases observed below the bed and upstream of the feed line. Two size categories of solids were recovered from the reactor, +60 mesh and -60 mesh. After a 2.75-hour experiment, 61.7 wt % was recovered as -60 mesh particles and 38.2 wt% of the recovered reactor solids were +60 mesh. A sizeable percentage, 31.8 wt%, was +20 mesh. The -60 mesh particles were mainly formed by the initial bed material (Al2O3). Almost 50 wt. % of the + 20 mesh particles was found to be formed by organics. The unreacted carbon remaining in the reactor resulted in a low conversion rate to product gas. ICP-AES, SEM, SEM-EDS, and XRD confirmed that the large agglomerates (+ 20 mesh) were not encapsulated bed material but rather un-gasified feedstock pellets with sand particles attached to it.

  3. Debris flows from tributaries of the Colorado River, Grand Canyon National Park, Arizona

    USGS Publications Warehouse

    Webb, R.H.; Pringle, P.T.; Rink, G.R.

    1987-01-01

    A reconnaissance of 36 tributaries of the Colorado River indicates that debris flows are a major process by which sediment is transported to the Colorado River in Grand Canyon National Park. Debris flows are slurries of sediment and water that have a water content < 40% by volume. Debris flows occur frequently in arid and semiarid regions. Slope failures commonly trigger debris flows, which can originate from any rock formation in the Grand Canyon. The largest and most frequent flows originate from the Permian Hermit Shale, the underlying Esplanade Sandstone of the Supai Group, and other formations of the Permian and Pennsylvanian Supai Group. Debris flows have reached the Colorado River on an average of once every 20 to 30 yr in the Lava-Chuar Creek drainage since about 1916. Two debris flows have reached the Colorado River in the last 25 yr in Monument Creek. The Crystal Creek drainage has had an average of one debris flow reaching the Colorado River every 50 yr, although the debris flow of 1966 has been the only flow that reached the Colorado River since 1900. Debris flows may actually reach the Colorado River more frequently in these drainages because evidence for all debris flows may not have been preserved in the channel-margin stratigraphy. Discharges were estimated for the peak flow of three debris flows that reached the Colorado River. The debris flow of 1966 in the Lava-Chuar Creek drainage had an estimated discharge of 4,000 cu ft/sec. The debris flow of 1984 in the Monument Creek drainage had a discharge estimated between 3,600 and 4,200 cu ft/sec. The debris flow of 1966 in the Crystal Creek drainage had a discharge estimated between 9,200 and 14,000 cu ft/sec. Debris flows in the Grand Canyon generally are composed of 10 to 40% sand by weight and may represent a significant source of beach-building sand along the Colorado River. The particle size distributions are very poorly sorted and the largest transported boulders were in the Crystal Creek

  4. Debris flows as geomorphic agents in the Huachuca Mountains of southeastern Arizona

    USGS Publications Warehouse

    Wohl, E.E.; Pearthree, P.P.

    1991-01-01

    Numerous debris flows occurred in the Huachuca Mountains of southeastern Arizona during the summer rainy season of 1988 in areas that were burned by a forest fire earlier in the summer. Debris flows occurred following a major forest fire in 1977 as well, suggesting a causal link between fires and debris flows. Abundant evidence of older debris flows preserved along channels and in mountain front fans indicates that debris flows have occurred repeteadly during the late Quaternary in this environment. Soil development in sequences of debris-flow deposits indicates that debris flows probably recur over time intervals of several hundred to a thousand years in individual drainage basins in the study area. Surface runoff in the steep drainage basins of the Huachuca Mountains is greatly enhanced following forest fires, as the hillslopes are denuded of their vegetative cover. Water and sediment eroded from the hillslope regolith are rapidly introduced into the upper reaches of tributary channels by widespread rilling and slope wash during rainfall events. This influx of water and sediment destabilizes regolith previously accumulated in the channel, triggering debris flows that scour the channel to bedrock in the upper reaches. Following a debris flow, the scoured, trapezoidally-shaped channel gradually assumes a swale shape and the percentage of exposed bedrock declines, as material is introduced from the slopes. Debris flows do a tremendous amount of work in a very short time, however, and are the major channel-forming events. Where the tributary channels enter larger, trunk channels, the debris flows serve as the main source of very coarse sediment. The local slope and coarse particle distribution of the trunk channel depend on the competence of water flows in the channel to transport the material introduced by debris flows. Where the smaller channels drain directly to the mountain front, debris flows create extensive alluvial fans which dominate the morphology of the

  5. Hydraulic System Wear Debris Analysis.

    DTIC Science & Technology

    1982-08-03

    drawn. Each one-=L sample was drawn with a clean plastic pipette of one-mL capacity. The samples were placed in clean Ferrogram preparation bottles ...and from cavities in a block which held linear seals into sampling bottles . Several photographs of this debris , which was deposited on Ferro- grams...silicon in the glass overshadowed the elements of the wear debris . To overcome this difficulty, the Ferrogram should be pre- pared on a carbon-filled

  6. Parallel Element Agglomeration Algebraic Multigrid and Upscaling Library

    SciTech Connect

    2015-02-19

    ParFELAG is a parallel distributed memory C++ library for numerical upscaling of finite element discretizations. It provides optimal complesity algorithms ro build multilevel hierarchies and solvers that can be used for solving a wide class of partial differential equations (elliptic, hyperbolic, saddle point problems) on general unstructured mesh (under the assumption that the topology of the agglomerated entities is correct). Additionally, a novel multilevel solver for saddle point problems with divergence constraint is implemented.

  7. Development of a full scale selective oil agglomeration plant

    SciTech Connect

    Donnelly, J.C.; Cooney, B.; Hoare, I.; Waugh, B.; Robinson, R.

    1998-12-31

    A research and development program managed by Australian Mining Investments Limited (AMI) on behalf of an investment syndicate was conducted with the objective of improving the efficiency and economy of the Selective Oil Agglomeration Process (SOAP), and developing viable commercial sized operating plants. Fewer than half the coal preparation plants in Australia beneficiate fine coal by froth flotation, the only viable alternative to SOAP for the recovery of low ash, fine and ultra fine coal. Those plants without flotation generally dispose of the ultra fine material, approximately {minus}100{micro}m in size, as tailings to waste. In the majority of cases this ultra fine waste contains more than 50% relatively low ash coal of saleable quality. It is believed that this coal constitutes a loss of 8--10 million tonnes per annum and that the coal mining industry would welcome a recovery process which has low capital and operating costs and will function automatically with minimal operator attention. The authors carried out a comprehensive literature study of selective oil agglomeration in order to gain a full understanding of the process and to plan the research program. Extensive studies were then undertaken on oil dispersion in the water phase, formation of oil water emulsions with surfactants and the optimization of surfactant selection. Oil and emulsion properties were investigated including stability, viscosity, temperature, concentration of components, time of formation, and cost. This work was followed by characterization studies on coals from the Gunnedah Basin and agglomeration test work on these coals. These agglomeration studies were performed firstly at bench level and then by using a small, 200 kg/hr continuous process development unit. The results were sufficiently encouraging to justify the design and construction of a fully instrumented, PLC controlled, 2 tph pilot plant at Gunnedah Colliery Coal Preparation Plant. Extensive trials were carried out on

  8. Aluminum Agglomeration and Trajectory in Solid Rocket Motors

    DTIC Science & Technology

    2007-08-30

    cinematography data from China Lake. Task 2.2, Aluminum Agglomeration Model Selection (SEA/BYU/ATK Task) Part of the model selection task has already been... Manual . Software and Engineering Associates, Inc. 1802 N. Carson Street, Suite 200, Carson City, NV 89701. 2005. [DCF-2005b] S. S. Dunn, D. E. Coats, and J...C. French, SPP󈧈 Standard Stability Prediction Method for Solid Rocket Motors; Axial Mode Computer Program User’s Manual . Software and Engineering

  9. Optimizing Orbital Debris Monitoring with Optical Telescopes

    DTIC Science & Technology

    2010-09-01

    Continued growth in the orbital debris population has renewed concerns over the long-term use of space. Debris poses an increasing risk to manned...in a catalog. Passive optical systems hold great promise to provide a cost-effective means to monitor orbital debris . Recent advances in optical...non-tracking mode for uncued debris detection. The governing radiometric equations for sensing orbital debris are developed, illustrating the

  10. Contact mechanics of highly porous oxide nanoparticle agglomerates

    NASA Astrophysics Data System (ADS)

    Fabre, Andrea; Salameh, Samir; Ciacchi, Lucio Colombi; Kreutzer, Michiel T.; van Ommen, J. Ruud

    2016-07-01

    Efficient nanopowder processing requires knowledge of the powder's mechanical properties. Due to the large surface area to volume ratio, nanoparticles experience relatively strong attractive interactions, leading to the formation of micron-size porous structures called agglomerates. Significant effort has been directed towards the development of models and experimental procedures to estimate the elasticity of porous objects such as nanoparticle agglomerates; however, none of the existing models has been validated for solid fractions below 0.1. Here, we measure the elasticity of titania (TiO_2, 22 nm), alumina (Al_2O_3, 8 nm), and silica (SiO_2, 16 nm) nanopowder agglomerates by Atomic Force Microscopy, using a 3.75 μm glass colloid for the stress-strain experiments. Three sample preparations with varying degree of powder manipulation are assessed. The measured Young's moduli are in the same order of magnitude as those predicted by the model of Kendall et al., thus validating it for the estimation of the Young's modulus of structures with porosity above 90 %.

  11. Reflectance of micron-sized dust particles retrieved with the Umov law

    NASA Astrophysics Data System (ADS)

    Zubko, Evgenij; Videen, Gorden; Zubko, Nataliya; Shkuratov, Yuriy

    2017-03-01

    The maximum positive polarization Pmax that initially unpolarized light acquires when scattered from a particulate surface inversely correlates with its geometric albedo A. In the literature, this phenomenon is known as the Umov law. We investigate the Umov law in application to single-scattering submicron and micron-sized agglomerated debris particles, model particles that have highly irregular morphology. We find that if the complex refractive index m is constrained to Re(m)=1.4-1.7 and Im(m)=0-0.15, model particles of a given size distribution have a linear inverse correlation between log(Pmax) and log(A). This correlation resembles what is measured in particulate surfaces, suggesting a similar mechanism governing the Umov law in both systems. We parameterize the dependence of log(A) on log(Pmax) of single-scattering particles and analyze the airborne polarimetric measurements of atmospheric aerosols reported by Dolgos & Martins in [1]. We conclude that Pmax ≈ 50% measured by Dolgos & Martins corresponds to very dark aerosols having geometric albedo A=0.019 ± 0.005.

  12. Estimating Foreign-Object-Debris Density from Photogrammetry Data

    NASA Technical Reports Server (NTRS)

    Long, Jason; Metzger, Philip; Lane, John

    2013-01-01

    Within the first few seconds after launch of STS-124, debris traveling vertically near the vehicle was captured on two 16-mm film cameras surrounding the launch pad. One particular piece of debris caught the attention of engineers investigating the release of the flame trench fire bricks. The question to be answered was if the debris was a fire brick, and if it represented the first bricks that were ejected from the flame trench wall, or was the object one of the pieces of debris normally ejected from the vehicle during launch. If it was typical launch debris, such as SRB throat plug foam, why was it traveling vertically and parallel to the vehicle during launch, instead of following its normal trajectory, flying horizontally toward the north perimeter fence? By utilizing the Runge-Kutta integration method for velocity and the Verlet integration method for position, a method that suppresses trajectory computational instabilities due to noisy position data was obtained. This combination of integration methods provides a means to extract the best estimate of drag force and drag coefficient under the non-ideal conditions of limited position data. This integration strategy leads immediately to the best possible estimate of object density, within the constraints of unknown particle shape. These types of calculations do not exist in readily available off-the-shelf simulation software, especially where photogrammetry data is needed as an input.

  13. Evaluation of optical and electronic properties of silicon nano-agglomerates embedded in SRO: applying density functional theory

    PubMed Central

    2014-01-01

    In systems in atomic scale and nanoscale such as clusters or agglomerates constituted by particles from a few to less than 100 atoms, quantum confinement effects are very important. Their optical and electronic properties are often dependent on the size of the systems and the way in which the atoms in these clusters are bonded. Generally, these nanostructures display optical and electronic properties significantly different to those found in corresponding bulk materials. Silicon agglomerates embedded in silicon rich oxide (SRO) films have optical properties, which have been reported to be directly dependent on silicon nanocrystal size. Furthermore, the room temperature photoluminescence (PL) of SRO has repeatedly generated a huge interest due to its possible applications in optoelectronic devices. However, a plausible emission mechanism has not been widely accepted in the scientific community. In this work, we present a short review about the experimental results on silicon nanoclusters in SRO considering different techniques of growth. We focus mainly on their size, Raman spectra, and photoluminescence spectra. With this as background, we employed the density functional theory with a functional B3LYP and a basis set 6-31G* to calculate the optical and electronic properties of clusters of silicon (constituted by 15 to 20 silicon atoms). With the theoretical calculation of the structural and optical properties of silicon clusters, it is possible to evaluate the contribution of silicon agglomerates in the luminescent emission mechanism, experimentally found in thin SRO films. PMID:25276105

  14. Evaluation of optical and electronic properties of silicon nano-agglomerates embedded in SRO: applying density functional theory.

    PubMed

    Espinosa-Torres, Néstor D; la Luz, David Hernández-de; Flores-Gracia, José Francisco J; Luna-López, José A; Martínez-Juárez, Javier; Vázquez-Valerdi, Diana E

    2014-01-01

    In systems in atomic scale and nanoscale such as clusters or agglomerates constituted by particles from a few to less than 100 atoms, quantum confinement effects are very important. Their optical and electronic properties are often dependent on the size of the systems and the way in which the atoms in these clusters are bonded. Generally, these nanostructures display optical and electronic properties significantly different to those found in corresponding bulk materials. Silicon agglomerates embedded in silicon rich oxide (SRO) films have optical properties, which have been reported to be directly dependent on silicon nanocrystal size. Furthermore, the room temperature photoluminescence (PL) of SRO has repeatedly generated a huge interest due to its possible applications in optoelectronic devices. However, a plausible emission mechanism has not been widely accepted in the scientific community. In this work, we present a short review about the experimental results on silicon nanoclusters in SRO considering different techniques of growth. We focus mainly on their size, Raman spectra, and photoluminescence spectra. With this as background, we employed the density functional theory with a functional B3LYP and a basis set 6-31G* to calculate the optical and electronic properties of clusters of silicon (constituted by 15 to 20 silicon atoms). With the theoretical calculation of the structural and optical properties of silicon clusters, it is possible to evaluate the contribution of silicon agglomerates in the luminescent emission mechanism, experimentally found in thin SRO films.

  15. Effect of treatment media on the agglomeration of titanium dioxide nanoparticles: impact on genotoxicity, cellular interaction, and cell cycle.

    PubMed

    Prasad, Raju Y; Wallace, Kathleen; Daniel, Kaitlin M; Tennant, Alan H; Zucker, Robert M; Strickland, Jenna; Dreher, Kevin; Kligerman, Andrew D; Blackman, Carl F; Demarini, David M

    2013-03-26

    The widespread use of titanium dioxide (TiO2) nanoparticles in consumer products increases the probability of exposure to humans and the environment. Although TiO2 nanoparticles have been shown to induce DNA damage (comet assay) and chromosome damage (micronucleus assay, MN) in vitro, no study has systematically assessed the influence of medium composition on the physicochemical characteristics and genotoxicity of TiO2 nanoparticles. We assessed TiO2 nanoparticle agglomeration, cellular interaction, induction of genotoxicity, and influence on cell cycle in human lung epithelial cells using three different nanoparticle-treatment media: keratinocyte growth medium (KGM) plus 0.1% bovine serum albumin (KB); a synthetic broncheoalveolar lavage fluid containing PBS, 0.6% bovine serum albumin and 0.001% surfactant (DM); or KGM with 10% fetal bovine serum (KF). The comet assay showed that TiO2 nanoparticles induced similar amounts of DNA damage in all three media, independent of the amount of agglomeration, cellular interaction, or cell-cycle changes measured by flow cytometry. In contrast, TiO2 nanoparticles induced MN only in KF, which is the medium that facilitated the lowest amount of agglomeration, the greatest amount of nanoparticle cellular interaction, and the highest population of cells accumulating in S phase. These results with TiO2 nanoparticles in KF demonstrate an association between medium composition, particle uptake, and nanoparticle interaction with cells, leading to chromosomal damage as measured by the MN assay.

  16. Debris monitoring and minimization system for EUV sources

    NASA Astrophysics Data System (ADS)

    de Jong, Arjen T.; Jilisen, René T. M.; van de Kerkhof, Mark; van Putten, Arnold

    2015-03-01

    In NXE laser-produced-plasma (LPP) light sources, extreme-ultra-violet (EUV) light is created by exciting small droplets of Sn with a pre-pulse and main pulse laser. The Sn droplet is converted into plasma, which emits the desired light wavelength. Under non-optimal conditions, tin debris fragments can be created that can contaminate the light source optics. The current presentation describes experiments with a novel metrology technique that can detect and quantify debris in the source. The results can be used to optimize source settings to significantly reduce contamination and increase lifetime and availability. A novel optical technique uses a pulsed double cavity laser at 532 nm with beam-shaping optics that is fired at a synchronized time delay after the EUV burst. The light is converted to a thin light sheet that illuminates possible debris fragments in the direct region around the plasma. Mie scattering theory is applied to convert the intensity of the incoming individual particles to an estimated diameter estimation and the two frames are correlated with advanced particle tracking algorithms to capture the velocity and direction of each individual particle. Because light intensity is used for particle sizing, small individual particles can be detected. The technique provides particle count, diameter, direction and velocity information. This technique has successfully been applied on operating NXE test sources. It has proven to directly identify plasma conditions with significant debris reduction. Furthermore, it has potential to correlate the plasma settings to lifetime estimations and thus can be used for both source optimization and design.

  17. The role of agglomeration in the conductivity of carbon nanotube composites near percolation

    NASA Astrophysics Data System (ADS)

    Tarlton, Taylor; Sullivan, Ethan; Brown, Joshua; Derosa, Pedro A.

    2017-02-01

    A detailed study of agglomeration in composite materials containing carbon nanotubes (CNT) is presented. Three dimensional samples with different degrees of agglomeration were created in three different ways, leading to a wider range of geometries available to study. Virtual charges are injected into the computer-generated samples and move through these samples according to a Monte Carlo hopping algorithm. Results show that there is an optimal level of agglomeration that is actually beneficial for charge transport at low volume concentrations, lowering the percolation threshold. It is found that near percolation, a more uniform CNT distribution (less agglomeration) leads to more conductive paths, but with a lower mobility. The optimum level of agglomeration comes from a trade off between these two properties. Beyond this optimum agglomeration state, it is observed that conductivity tends to decrease as dispersion increases at all concentrations studied here. At high concentration (percolated samples), where CNT clumps merge, conductivity seems to be less sensitive to agglomeration.

  18. Gold, silver, and palladium nanoparticle/nano-agglomerate generation, collection, and characterization

    NASA Astrophysics Data System (ADS)

    Boddu, Sunita R.; Gutti, Veera R.; Ghosh, Tushar K.; Tompson, Robert V.; Loyalka, Sudarshan K.

    2011-12-01

    Generation, collection, and characterization of gold, silver, and palladium nanoparticles and nano-agglomerates (collectively "nanoparticles") have been explored. The nanoparticles were generated with a spark aerosol generator (Palas GFG-1000). They were collected using a deposition cell under diffusion and thermophoresis. The shapes and sizes of the deposited particles were measured using transmission electron microscopy (TEM). TEM images showed that the particles were in the range of 8-100 nm in diameter, and their shapes varied from nearly spherical to highly non-spherical. Thermophoresis enhanced the deposition of nanoparticles (over the diffusive or the isothermal deposition) in all cases. Further, the size distributions of the nanoparticles generated in the gas phase (aerosol) were measured using a scanning mobility particle sizer (SMPS 3080, TSI) spectrometer. The SMPS results show that an increase in the spark frequency of the generator shifted the size distributions of the nanoparticles to larger diameters, and the total particle mass production rate increased linearly with increase in the spark frequency. The computational fluid dynamics code Fluent (Ansys) was used to model the flow in the deposition cell, and the computed results conform to the observations.

  19. The physics of debris flows

    USGS Publications Warehouse

    Iverson, R.M.

    1997-01-01

    Recent advances in theory and experimentation motivate a thorough reassessment of the physics of debris flows. Analyses of flows of dry, granular solids and solid-fluid mixtures provide a foundation for a comprehensive debris flow theory, and experiments provide data that reveal the strengths and limitations of theoretical models. Both debris flow materials and dry granular materials can sustain shear stresses while remaining static; both can deform in a slow, tranquil mode characterized by enduring, frictional grain contacts; and both can flow in a more rapid, agitated mode characterized by brief, inelastic grain collisions. In debris flows, however, pore fluid that is highly viscous and nearly incompressible, composed of water with suspended silt and clay, can strongly mediate intergranular friction and collisions. Grain friction, grain collisions, and viscous fluid flow may transfer significant momentum simultaneously. Both the vibrational kinetic energy of solid grains (measured by a quantity termed the granular temperature) and the pressure of the intervening pore fluid facilitate motion of grains past one another, thereby enhancing debris flow mobility. Granular temperature arises from conversion of flow translational energy to grain vibrational energy, a process that depends on shear rates, grain properties, boundary conditions, and the ambient fluid viscosity and pressure. Pore fluid pressures that exceed static equilibrium pressures result from local or global debris contraction. Like larger, natural debris flows, experimental debris flows of ???10 m3 of poorly sorted, water-saturated sediment invariably move as an unsteady surge or series of surges. Measurements at the base of experimental flows show that coarse-grained surge fronts have little or no pore fluid pressure. In contrast, finer-grained, thoroughly saturated debris behind surge fronts is nearly liquefied by high pore pressure, which persists owing to the great compressibility and moderate

  20. Debris-flow observations in the Zermatt Valley

    NASA Astrophysics Data System (ADS)

    Graf, Christoph

    2015-04-01

    related slide and fall processes, increasingly large amounts of loose sediment are delivered into debris-flow systems. Extensive till, scree slopes and rock glaciers represent the principal and extensive sediment sources for debris flows which are commonly triggered at elevations between 2000 and 3000 m asl. Here, high annual and daily thermal ranges favour frost weathering and regolith production delivered to scree slopes. Slope angles in the initiation zones range from 27 to 41° and are dominated by permafrost in all of the catchments. Debris flows are triggered either through the wetting of material continuously delivered by the permafrost body to the channel or due to release at the rock glacier fronts during exceptional water input. The wetting typically occurs during rainstorms, but debris flows at these sites also happen when sediment shear resistance is reduced by the melting of ice particles, by snow melting and/or a combination of both. In the Dorfbach torrent near Randa, WSL operates an automated debris-flow observation station, measuring the typical parameters such as flow heights and velocities since several years. As part of an interdisciplinary project on data acquisition and numerical modelling of debris flows for hazard mapping, we monitor several other debris-flow prone torrents in the valley and combine these data with observations of ongoing processes in the headwater of the catchments. Several debris-flow events in some of the torrents could be observed and measured in the last years. Total volume, discharge per surge, frontal speed, run out length and impact on the inhabited fans varied considerably. Typically one first event cluster is dominated by snow melting controlled conditions starting late May until end of June and a second cluster are the rainstorm dominated events in midsummer. The largest events are expected in late summer or in fall, when long-lasting advective precipitation events over several days prevail.

  1. ORDEM 3.0 and the Risk of High-Density Debris

    NASA Technical Reports Server (NTRS)

    Matney, Mark; Anz-Meador, Philip

    2014-01-01

    NASA’s Orbital Debris Engineering Model was designed to calculate orbital debris fluxes on spacecraft in order to assess collision risk. The newest of these models, ORDEM 3.0, has a number of features not present in previous models. One of the most important is that the populations and fluxes are now broken out into material density groups. Previous models concentrated on debris size alone, but a particle’s mass and density also determine the amount of damage it can cause. ORDEM 3.0 includes a high-density component, primarily consisting of iron/steel particles that drive much of the risk to spacecraft. This paper will outline the methods that were used to separate and identify the different densities of debris, and how these new densities affect the overall debris flux and risk.

  2. Catastrophic failure of stored energy modules following orbital debris penetration

    NASA Astrophysics Data System (ADS)

    Williamsen, Joel E.; Goodwin, Charles J.

    1996-10-01

    The population of dangerous orbital debris particles in low Earth orbit is growing, resulting in a need for improved risk assessment and risk management of critical space station elements from this hypervelocity impact threat. The effects of micrometeoroid and orbital debris (M/OD) penetration on space station equipment can very from a local damage problem to a possible catastrophic system failure (i.e., crew or station loss). Given this possibility, a preliminary study was undertaken by Meyer Analytics and NASA-MSFC to quantify and reduce the likelihood of catastrophic failure following orbital debris penetration of two Russian supplied modules: the FGB Energy Block module and the SPP-1 gyrodyne module. Each of these modules contains stored energy in the form of chemical propellants (UDMH), high pressure tanks, or kinetic energy (gyrodynes) that may release energy and propagate damage to the rest of the space station if impacted by a sufficiently energetic orbital debris particle. The study recommended design improvements to lower these probabilities, including spall blankets around the gyrodynes to lower the probability of gyrodyne penetration and fragment damage given gyrodyne rupture.

  3. Surfactant protein A (SP-A) inhibits agglomeration and macrophage uptake of toxic amine modified nanoparticles

    PubMed Central

    McKenzie, Zofi; Kendall, Michaela; Mackay, Rose-Marie; Whitwell, Harry; Elgy, Christine; Ding, Ping; Mahajan, Sumeet; Morgan, Cliff; Griffiths, Mark; Clark, Howard; Madsen, Jens

    2015-01-01

    Abstract The lung provides the main route for nanomaterial exposure. Surfactant protein A (SP-A) is an important respiratory innate immune molecule with the ability to bind or opsonise pathogens to enhance phagocytic removal from the airways. We hypothesised that SP-A, like surfactant protein D, may interact with inhaled nanoparticulates, and that this interaction will be affected by nanoparticle (NP) surface characteristics. In this study, we characterise the interaction of SP-A with unmodified (U-PS) and amine-modified (A-PS) polystyrene particles of varying size and zeta potential using dynamic light scatter analysis. SP-A associated with both 100 nm U-PS and A-PS in a calcium-independent manner. SP-A induced significant calcium-dependent agglomeration of 100 nm U-PS NPs but resulted in calcium-independent inhibition of A-PS self agglomeration. SP-A enhanced uptake of 100 nm U-PS into macrophage-like RAW264.7 cells in a dose-dependent manner but in contrast inhibited A-PS uptake. Reduced association of A-PS particles in RAW264.7 cells following pre-incubation of SP-A was also observed with coherent anti-Stokes Raman spectroscopy. Consistent with these findings, alveolar macrophages (AMs) from SP-A−/− mice were more efficient at uptake of 100 nm A-PS compared with wild type C57Bl/6 macrophages. No difference in uptake was observed with 500 nm U-PS or A-PS particles. Pre-incubation with SP-A resulted in a significant decrease in uptake of 100 nm A-PS in macrophages isolated from both groups of mice. In contrast, increased uptake by AMs of U-PS was observed after pre-incubation with SP-A. Thus we have demonstrated that SP-A promotes uptake of non-toxic U-PS particles but inhibits the clearance of potentially toxic A-PS particles by blocking uptake into macrophages. PMID:25676620

  4. Recent Advances in the Development and Application of Power Plate Transducers in Dense Gas Extraction and Aerosol Agglomeration Processes

    NASA Astrophysics Data System (ADS)

    Riera, E.; Cardoni, A.; Gallego-Juárez, J. A.; Acosta, V. M.; Blanco, A.; Rodríguez, G.; Blasco, M.; Herranz, L. E.

    Power ultrasound (PU) is an emerging, innovative, energy saving and environmental friendly technology that is generating a great interest in sectors such as food and pharmaceutical industries, green chemistry, environmental pollution, and other processes, where sustainable and energy efficient methods are required to improve and/or produce specific effects. Two typical effects of PU are the enhancement of mass transfer in gases and liquids, and the induction of particle agglomeration in aerosols. These effects are activated by a variety of mechanisms associated to the nonlinear propagation of high amplitude ultrasonic waves such as diffusion, agitation, entrainment, turbulence, etc. During the last years a great effort has been jointly made by the Spanish National Research Council (CSIC) and the company Pusonics towards introducing novel processes into the market based on airborne ultrasonic plate transducers. This technology was specifically developed for the treatment of gas and multiphasic media characterized by low specific acoustic impedance and high acoustic absorption. Different strategies have been developed to mitigate the effects of the nonlinear dynamic behavior of such ultrasonic piezoelectric transducers in order to enhance and stabilize their response at operational power conditions. This work deals with the latter advances in the mitigation of nonlinear problems found in power transducers; besides it describes two applications assisted by ultrasound developed at semi-industrial and laboratory scales and consisting in extraction via dense gases and particle agglomeration. Dense Gas Extraction (DGE) assisted by PU is a new process with a potential to enhance the extraction kinetics with supercritical CO2. Acoustic agglomeration of fine aerosol particles has a great potential for the treatment of air pollution problems generated by particulate materials. Experimental and numerical results in both processes will be shown and discussed.

  5. Analysis of debris from Spacelab Space Life Sciences-1

    NASA Technical Reports Server (NTRS)

    Caruso, S. V.; Rodgers, E. B.; Huff, T. L.

    1992-01-01

    Airborne microbiological and particulate contamination generated aboard Spacelab modules is a potential safety hazard. In order to shed light on the characteristics of these contaminants, microbial and chemical/particulate analyses were performed on debris vacuumed from cabin and avionics air filters in the Space Life Sciences-1 (SLS-1) module of the Space Transportation System 40 (STS-40) mission 1 month after landing. The debris was sorted into categories (e.g., metal, nonmetal, hair/fur, synthetic fibers, food particles, insect fragments, etc.). Elemental analysis of particles was done by energy dispersive analysis of x rays (metals) and Fourier transform infrared spectroscopy (nonmetals). Scanning electron micrographs were done of most particles. Microbiological samples were grown on R2A culture medium and identified. Clothing fibers dominated the debris by volume. Other particles, all attributed to the crew, resulted from abrasions and impacts during missions operations (e.g., paint chips, plastic, electronic scraps and clothing fibers). All bacterial species identified are commonly found in the atmosphere or on the human body. Bacillus sp. was the most frequently seen bacterium. One of the bacterial species, Enterobacter agglomerans, could cause illness in crew members with depressed immune systems.

  6. Charging of space debris in the LEO and GEO regions

    NASA Astrophysics Data System (ADS)

    Sen, Abhijit; Tiwari, Sanat Kumar

    The near exponential rise of space debris at the satellite orbital altitudes (particularly in the low earth orbit (LEO) region) and the risk they pose for space assets is a source of major concern for all nations engaged in space activities. Considerable efforts are therefore being expended into accurate modeling and tracking of these objects and various ideas for the safe removal of these debris are being explored. The debris objects are likely to acquire a large amount of charge since they are typically found in a plasma environment - such as the earth’s ionospheric plasma in the LEO region (100 kms to 1000 kms) and the radiation belts in the geosynchronous orbit (GEO) region. The consequent flow of electron and ion currents on them lead to the accumulation of a large amount of surface charge and the development of a surface potential on these objects. The influence of the plasma environment on the dynamics and charging of the debris is a relatively unexplored area of Space Situational Awareness (SSA) and Space Debris (SD) research and can be potentially important for the accurate prediction of the long-term evolution of debris orbits and their collision probabilities with other space objects. In this paper we will report on the charging of space debris under a variety of orbital conditions in the LEO and GEO regions using both analytic and particle-in-cell (PIC) modeling. The analytic estimates are obtained using refined Orbit Motion Limited (OML) modeling while the simulation studies are carried out using the SPIS code [1]. In the GEO region account is taken of charging due to photoemission processes as well as energetic beam charging. The PIC approach enables us to study charging of irregularly shaped debris objects as well as differential charging on objects that are composed of patches of conducting and insulated regions. The dynamical consequences of the debris charging on their orbital trajectories and rotational characteristics will be discussed. [1] J

  7. Space Telescopes and Orbital Debris

    NASA Astrophysics Data System (ADS)

    Seitzer, Patrick

    2009-01-01

    Almost 12,000 artificial objects orbiting the Earth are currently in the public catalog of orbital elements maintained by the USAF. Only a small fraction of them are operational satellites. The remainder is satellites whose missions have ended, rocket bodies, and parts and debris from larger parent objects. And the catalog only contains the biggest and brightest of the objects in orbit. The Low Earth Orbit (LEO) regime where most of this population concentrates is also a regime of incredible interest to astronomers, since it is where flagship missions such as the Hubble Space Telescope and other Great Observatories operate. I'll review the current state of knowledge of the orbital debris population, how it has grown with time, and how this environment could affect current and future space telescopes. There are mitigation measures which many spacecraft operators have adopted which can control the growth of the debris population. Orbital debris research at the University of Michigan is funded by NASA's Orbital Debris Program Office, Johnson Space Center, Houston, Texas.

  8. Optical surveys for space debris

    NASA Astrophysics Data System (ADS)

    Schildknecht, Thomas

    2007-01-01

    Space debris—man-made non-functional objects of all sizes in near-Earth space—has been recognized as an increasing threat for current and future space operations. The debris population in near-Earth space has therefore been extensively studied during the last decade. Information on objects at altitudes higher than about 2,000 km is, however, still comparatively sparse. Debris in this region is best detected by surveys utilizing optical telescopes. Moreover, the instruments and the applied observation techniques, as well as the processing methods, have many similarities with those used in optical surveys for ‘astronomical’ objects like near-Earth objects (NEOs). The present article gives a general introduction to the problem of space debris, presents the used observation and processing techniques emphasizing the similarities and differences compared to optical surveys for NEOs, and reviews the results from optical surveys for space debris in high-altitude Earth orbits. Predictions on the influence of space debris on the future of space research and space astronomy in particular are reported as well.

  9. Geosynchronous Earth orbital debris campaign

    NASA Astrophysics Data System (ADS)

    Africano, John L.; Sydney, Paul F.; Talent, David L.; Stansbery, Eugene G.; Jarvis, Kandy S.; Monet, David G.; Seitzer, Patrick

    2000-10-01

    The National Aeronautics and Space Administration (NASA) Johnson Space Center (JSC) is conducting systematic searches of the Geosynchronous Earth Orbit (GEO) environment as part of an international measurement campaign under the auspices of the Inter-Agency Space Debris Coordination Committee (IADC). The objectives for this survey are to determine the extent and character of debris in GEO, buy obtaining distributions for the brightness, inclination, Right Ascension of Ascending Node (RAAN), and mean motion of the debris. The Charged Coupled Device (CCD) Debris Telescope (CDT), an automated 0.32 meter aperture, transportable Schmidt telescope presently located at Cloudcroft, New Mexico, is used nightly to monitor the GEO debris environment. The CDT is equipped with a CCD camera capable of detecting 17th magnitude objects in a 20 second exposure. This corresponds to a 0.6 meter diameter object having a 0.2 albedo at 36000 km. Two other larger telescopes have been used for this purpose, the United States Naval Observatory's new 1.3 meter telescope located in Flagstaff Arizona and a 0.6 m Schmidt telescope located at Cerro Tololo Inter-American Observatory (CTIO) near La Serena Chile. Data reduction and analysis software used to reduce this data exploit tools developed by both the astronomical and DoD communities. These tools and data results are presented.

  10. Contribution of Secondary Ejecta to the Debris Population

    NASA Astrophysics Data System (ADS)

    Mandeville, J.; Bariteau, M.

    When a micro-debris or a micrometeoroid impacts a spacecraft surface, a large number of secondary particles, called ejecta, are produced. These particles can contribute to a modification of the debris environment : either locally by the occurrence of secondary impacts on the components of complex and large space structures, or at great distance by the formation of a population of small orbital debris. This paper describes the ejecta overall production, the lifetime and the orbital evolution of the particles. Finally the repartition of ejecta in LEO and GEO is computed. By an extensive use of the spacecraft database DISCOS, satellites and rocket bodies currently in orbit have been identified. The surface area of solar arrays and painted surfaces currently in orbit is estimated, and the primary flux received is computed using the ORDEM 96 model for debris and the Grün model for meteoroids. Afterward, for each representative particle, its orbital evolution is computed. The ejecta are considered to be produced since 1960, and their spatial density is computed in 2000. It is assumed that the area of the primary surfaces increases at a rate of 2% a year. Small particles are ejected with a high velocity, so their initial orbit is very different from the one of the parent object and about 23% of them are ejected on a re-entering or a hyperbolic trajectory. On the other hand, spall and large particles are ejected with low velocity and their initial orbit is close to the parent body. The spatial density of ejected particles is maximum between 800 km and 1400 km of altitude. Below 800 km altitude, the spatial density decreases because of the increase of the atmospheric drag. Above, the spatial density diminishes, because primary surfaces are less numerous. The number of ejecta, in the millimetre size range, reaches 5% of the total debris density at 800 km altitude and about 1 % in GEO. To allows a faster computation, the ejecta number as a function of size, altitude and

  11. Non-agglomerated gold-PMMA nanocomposites by in situ-stabilized laser ablation in liquid monomer for optical applications

    NASA Astrophysics Data System (ADS)

    Schwenke, Andreas; Dalüge, Hauke; Kiyan, Roman; Sajti, C. Laszlo; Chichkov, Boris N.

    2013-05-01

    The main goal in the production of nanocomposites for optical applications is the uniform and non-agglomerated incorporation of nanoparticles into polymer matrices. Therefore, in this work gold nanoparticles have been generated by short-pulsed liquid phase laser ablation in methyl methacrylate (MMA) with or without dissolved poly(methyl methacrylate) (PMMA) followed by polymerization. The polymeric materials were then used in injection molding to form model nanocomposites for further analysis. It has been observed that the steric in situ-stabilization of nanoparticles by dissolved PMMA inhibits particle aggregation in MMA and due to particle quenching results in smaller nanoparticles than that achieved by working in pure MMA. Similar but even more pronounced stability issues have been highlighted on injection molded optical nanocomposites, revealing that the in situ-stabilization of nanoparticles with PMMA not only prevent an agglomeration in the colloidal state but could also prevent changes in particles dispersion along the entire processing chain ending in final 3D polymer samples. Besides the optical study of the characteristic plasmon peak of gold nanoparticles and the nonlinear absorption behavior for femtosecond laser pulses, XRD analysis revealed the appearance of atomic gold in a centrosymmetric Fm3m cubic structure.

  12. What is the velocity profile of debris flows?

    NASA Astrophysics Data System (ADS)

    Walter, Fabian; McArdell, Brian

    2015-04-01

    The distribution of flow velocity within a debris flow is difficult to determine at full scale in the field due to the large forces and inherently destructive nature of the flow. However, knowledge of the distribution of velocity within a flow would be helpful to constrain rheological models and to better understand the internal dynamics of such flows. Here we describe recent efforts to determine the velocity of debris flows as a function of distance from the channel bed. Measurements were made at the Illgraben, Switzerland, which exhibits a wide variety of flows, ranging from turbulent debris floods to flows which resemble laminar mud flows to more classical debris flows with a clear granular front. The Illgraben observation station is therefore an ideal location to investigate debris flow dynamics. Our measurements were made using sensors embedded on a 14 m long, 2.5 m tall steel-reinforced concrete wall constructed flush with the torrent channel walls. The main instrumentation consists of 18 geophones (10 Hz natural frequency) installed on square steel plates with a side length of 0.3 m. Each steel plate is acoustically isolated from the wall and the other plates through the use of elastomer elements. The geophone plates are arranged in six rows of three sensors with a dimension of 1.8 m in the vertical direction and 1.5 m in the horizontal direction (i.e. parallel to the flow direction). A sensorless plate separates each plate in the horizontal direction. The data are collected at 2 kHz using a high-speed (synchronous) capture card in a pc. The elevation of the flow surface is determined at a cross-stream distance 1 m away from the wall, using a laser sensor installed on a bridge above the wall. We present a processing approach for the geophone data with the goal to track particle sliding across the sensor plates. For signals near or above the sensors' natural frequency (10 Hz), the measured time series are poorly correlated between sensors. Therefore, we use a

  13. A review of the biologic effects of spine implant debris: Fact from fiction

    PubMed Central

    Hallab, Nadim James

    2009-01-01

    Background Biologic-reactivity to implant-debris is the primary determinant of long-term clinical performance. The following reviews: 1) the physical aspects of spinal-implant debris and 2) the local and systemic biologic responses to implant debris. Methods Methods included are: 1) gravimetric wear analysis; 2) SEM and LALLS; 3) metal-ion analysis; 4) ELISA, toxicity testing, patch testing; and 5) metal-lymphocyte transformation testing (metal-LTT). Results Wear and corrosion of spine-implants produce particles and ions. Particles (0.01–1000 μm) are generally submicron ( <1 µm). Wear rates of metal-on-polymer and metal-on-metal disc arthroplasties are approximately 2–20 and 1 mm3/yr, respectively. Metal-on-metal total disc replacement components have significant increases in circulating metal (less than 10-fold that of controls at 4 ppb-Co and 3 ppb-Cr or ng/mL). Debris reactivity is local and systemic. Local inflammation is caused primarily by ingestion of debris by local macrophages, which produce pro-inflammatory cytokines TNFα, IL-1β, IL-6, and PGE2. Systemic responses associated with implant-debris have been limited to hypersensitivity reactions. Elevated amounts of in the liver, spleen, etc of patients with failed TJA have not been associated with remote toxicological or carcinogenic pathology to date. Implant debris are differentially bioreactive. Greater numbers are pro-inflammatory; the smaller-sized debris are more bioreactive by virtue of their greater numbers (dose) for a given amount of implant mass loss (one 100-μm-diameter particle is equivalent in mass to 1 million 1-μm-diameter particles). Elongated particles are pro-inflammatory (ie, aspect ratio of greater than 3). Metal particles are more proinflammatory than polymers, ceteris paribus. Conclusion Spinal arthroplasty designs have been in use for more than 20 years internationally; therefore, concerns about neuropathology, toxicity, and carcinogenicity are mitigated. Debris

  14. An agglomeration induced glassy magnetic state in a carbon nanotube/NiO nanocomposite system.

    PubMed

    Chattopadhyay, S; Jana, S; Giri, S; Majumdar, S

    2012-10-31

    A series of nanocomposite materials were synthesized using multi-walled carbon nanotubes (MWCNTs) and NiO nanoparticles by varying the concentration of NiO in the MWCNT host matrix. Such an increment in the NiO particle density actually tunes the degree of isolation among the magnetic nanoparticles. Careful investigation by transmission electron microscopy shows that particle agglomeration increases substantially with NiO particle density. Field dependence of magnetization measurements depict a gradual enhancement of coercivity with increasing NiO concentration, signifying the enhancement of magnetic anisotropy in this nanocomposite system. Furthermore, field cooled and zero field cooled memory effect as well as magnetization relaxation measurements show that a glassy magnetic state gradually develops when the concentration increases. Analysis based on the result of high resolution transmission electron microscopy along with the magnetization data reveals that interparticle magnetic exchange interaction in the presence of interfacial disorders plays the major role in the emergence of the glassy magnetic state in this nanocomposite system.

  15. Field observations of artificial sand and oil agglomerates

    USGS Publications Warehouse

    Dalyander, Patricia (Soupy); Long, Joseph W.; Plant, Nathaniel G.; McLaughlin, Molly R.; Mickey, Rangley C.

    2015-01-01

    Oil that comes into the surf zone following spills, such as occurred during the 2010 Deepwater Horizon (DWH) blowout, can mix with local sediment to form heavier-than-water sand and oil agglomerates (SOAs), at times in the form of mats a few centimeters thick and tens of meters long. Smaller agglomerates that form in situ or pieces that break off of larger mats, sometimes referred to as surface residual balls (SRBs), range in size from sand-sized grains to patty-shaped pieces several centimeters (cm) in diameter. These mobile SOAs can cause beach oiling for extended periods following the spill, on the scale of years as in the case of DWH. Limited research, including a prior effort by the U.S. Geological Survey (USGS) investigating SOA mobility, alongshore transport, and seafloor interaction using numerical model output, focused on the physical dynamics of SOAs. To address this data gap, we constructed artificial sand and oil agglomerates (aSOAs) with sand and paraffin wax to mimic the size and density of genuine SOAs. These aSOAs were deployed in the nearshore off the coast of St. Petersburg, Florida, during a field experiment to investigate their movement and seafloor interaction. This report presents the methodology for constructing aSOAs and describes the field experiment. Data acquired during the field campaign, including videos and images of aSOA movement in the nearshore (1.5-meter and 0.5-meter water depth) and in the swash zone, are also presented in this report.

  16. Atomic gas in debris discs

    NASA Astrophysics Data System (ADS)

    Hales, Antonio S.; Barlow, M. J.; Crawford, I. A.; Casassus, S.

    2017-04-01

    We have conducted a search for optical circumstellar absorption lines in the spectra of 16 debris disc host stars. None of the stars in our sample showed signs of emission line activity in either Hα, Ca II or Na I, confirming their more evolved nature. Four stars were found to exhibit narrow absorption features near the cores of the photospheric Ca II and Na I D lines (when Na I D data were available). We analyse the characteristics of these spectral features to determine whether they are of circumstellar or interstellar origins. The strongest evidence for circumstellar gas is seen in the spectrum of HD 110058, which is known to host a debris disc observed close to edge-on. This is consistent with a recent ALMA detection of molecular gas in this debris disc, which shows many similarities to the β Pictoris system.

  17. Differentiation of debris-flow and flash-flood deposits: implications for paleoflood investigations

    USGS Publications Warehouse

    Waythomas, Christopher F.; Jarrett, Robert D.; ,

    1993-01-01

    Debris flows and flash floods are common geomorphic processes in the Colorado Rocky Mountain Front Range and foothills. Usually, debris flows and flash floods are associated with excess summer rainfall or snowmelt, in areas were unconsolidated surficial deposits are relatively thick and slopes are steep. In the Front Range and foothills, flash flooding is limited to areas below about 2300m whereas, debris flow activity is common throughout the foothill and alpine zones and is not necessarily elevation limited. Because flash floods and debris flows transport large quantities of bouldery sediment, the resulting deposits appear somewhat similar even though such deposits were produced by different processes. Discharge estimates based on debris-flow deposits interpreted as flash-flood deposits have large errors because techniques for discharge retrodiction were developed for water floods with negligible sediment concentrations. Criteria for differentiating between debris-flow and flash-flood deposits are most useful for deposits that are fresh and well-exposed. However, with the passage of time, both debris-flow and flash-flood deposits become modified by the combined effects of weathering, colluviation, changes in surface morphology, and in some instances removal of interstitial sediment. As a result, some of the physical characteristics of the deposits become more alike. Criteria especially applicable to older deposits are needed. We differentiate flash-flood from debris-flow and other deposits using clast fabric measurements and other morphologic and sedimentologic techniques (e.g., deposit morphology, clast lithology, particle size and shape, geomorphic setting).

  18. FracMAP: A user-interactive package for performing simulation and orientation-specific morphology analysis of fractal-like solid nano-agglomerates

    NASA Astrophysics Data System (ADS)

    Chakrabarty, Rajan K.; Garro, Mark A.; Chancellor, Shammah; Herald, Christopher; Moosmüller, Hans

    2009-08-01

    Computer simulation techniques have found extensive use in establishing empirical relationships between three-dimensional (3d) and two-dimensional (2d) projected properties of particles produced by the process of growth through the agglomeration of smaller particles (monomers). In this paper, we describe a package, FracMAP, that has been written to simulate 3d quasi-fractal agglomerates and create their 2d pixelated projection images by restricting them to stable orientations as commonly encountered for quasi-fractal agglomerates collected on filter media for electron microscopy. Resulting 2d images are analyzed for their projected morphological properties. Program summaryProgram title: FracMAP Catalogue identifier: AEDD_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEDD_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.: 4722 No. of bytes in distributed program, including test data, etc.: 27 229 Distribution format: tar.gz Programming language: C++ Computer: PC Operating system: Windows, Linux RAM: 2.0 Megabytes Classification: 7.7 Nature of problem: Solving for a suitable fractal agglomerate construction under constraints of typical morphological parameters. Solution method: Monte Carlo approximation. Restrictions: Problem complexity is not representative of run-time, since Monte Carlo iterations are of a constant complexity. Additional comments: The distribution file contains two versions of the FracMAP code, one for Windows and one for Linux. Running time: 1 hour for a fractal agglomerate of size 25 on a single processor.

  19. A computational model for assessing high-velocity debris impact in space applications

    NASA Astrophysics Data System (ADS)

    Bergh, M.; Garcia, V.

    2017-01-01

    Man-made space debris is dominating the background meteorite environment with a growing debris population leading to increased collision risks for satellites, especially in the low Earth orbit and geostationary orbit protected environments. Here we present a computational model for estimating the effect of hypervelocity impact from debris particles on non-shielded propellant and pressurant tanks. Eulerian hydrocode simulation is utilised to model firstly penetration and shock wave formation in the propellant and secondly subsequent detonation wave propagation and interaction with the tank wall. Furthermore, reactive molecular dynamics is used to estimate the risk of detonation in a liquid hydrazine layer. We present simulations of a 3.5 mm aluminium spherical debris particle at a velocity of 14 km/s relative to a hydrazine tank. We find that the degree of damage is strongly dependent on tank temperature and hence on the satellite thermal configuration at its end of life.

  20. Space Debris Environent Remediation Concepts

    NASA Astrophysics Data System (ADS)

    Klinkrad, H.; Johnson, N. L.

    2009-03-01

    Long-term projections of the space debris environment indicate that even drastic measures, such as an immediate, complete halt of launch and release activities, will not result in a stable environment of man-made space objects. Collision events between already existing space hardware will within a few decades start to dominate the debris population, and result in a net increase of the space debris population, also at sizes which may cause further catastrophic collisions. A collisional cascading may ultimately lead to a run-away situation ("Kessler syndrome"), with no further possibility of human intervention.The International Academy of Astronautics (IAA) has been investigating the status and the stability of the space debris environment in several studies by first looking into space traffic management possibilities, and then investigating means of mitigating the creation of space debris. In an on-going activity, an IAA study group looks into methods of active space debris environment remediation. In contrast to the former mitigation study, the current activity concentrates on the active removal of large objects, such as defunct spacecraft, orbital stages, and mission-related objects, which serve as a latent mass reservoir that fuels initial castastrophic collisions and later collisional cascading. The paper will outline different mass removal concepts, e.g. based on directed energy, tethers (momentum exchange or electro-dynamic), aerodynamic drag augmentation, solar sails, auxiliary propulsion units, retarding surfaces, or on-orbit capture. Apart from physical principles of the proposed concepts, their applicability to different orbital regimes, and their effectiveness concerning mass removal efficiency will be discussed.

  1. ORDEM 3.0 and MASTER-2009 Modeled Small Debris Population Comparison

    NASA Technical Reports Server (NTRS)

    Krisko, P. H.; Flegel, S.

    2014-01-01

    The latest versions of the two premier orbital debris engineering models, NASA's ORDEM 3.0 and ESA's MASTER-2009, have been publically released. Both models have gone through significant advancements since inception, and now represent the state-of-the-art in orbital debris knowledge of their respective agencies. The purpose of these models is to provide satellite designers/operators and debris researchers with reliable estimates of the artificial debris environment in low Earth orbit (LEO) to geosynchronous orbit (GEO). The small debris environment within the size range of 1 mm to 1 cm is of particular interest to both human and robotic spacecraft programs, particularly in LEO. These objects are much more numerous than larger trackable debris and can have enough momentum to cause significant, if not catastrophic, damage to spacecraft upon impact. They are also small enough to elude routine detection by existing observation systems (radar and telescope). Without reliable detection the modeling of these populations has always coupled theoretical origins with supporting observational data in different degrees. In this paper, we present and detail the 1 mm to 1 cm orbital debris populations from both ORDEM 3.0 and MASTER-2009 in LEO. We review population categories: particle sources for MASTER-2009, particle densities for ORDEM 3.0. We describe data sources and their uses, and supporting models. Fluxes on spacecraft for chosen orbits are also presented and discussed within the context of each model.

  2. Bed Stability and Debris Flow Erosion: A Dynamic "Shields Criterion" Associated with Bed Structure

    NASA Astrophysics Data System (ADS)

    Longjas, A.; Hill, K. M.

    2015-12-01

    Debris flows are mass movements that play an important role in transporting sediment from steep uplands to rivers at lower slopes. As the debris flow moves downstream, it entrains materials such as loose boulders, gravel, sand and mud deposited locally by shorter flows such as slides and rockfalls. To capture the conditions under which debris flows entrain bed sediment, some models use something akin to the Shields' criterion and an excess shear stress of the flow. However, these models typically neglect granular-scale effects in the bed which can modify the conditions under which a debris flow is erosional or depositional. For example, it is well known that repeated shearing causes denser packing in loose dry soils, which undoubtedly changes their resistance to shear. Here, we present laboratory flume experiments showing that the conditions for entrainment by debris flows is significantly dependent on the aging of an erodible bed even for narrowly distributed spherical particles. We investigate this quantitatively using particle tracking measurements to quantify instantaneous erosion rates and the evolving bed structure or "fabric". With progressive experiments we find a signature that emerges in the bed fabric that is correlated with an increasing apparent "fragility" of the bed. Specifically, a system that is originally depositional may become erosional after repeated debris flow events, and an erodible bed becomes increasingly erodible with repeated flows. We hypothesize that related effects of bed aging at the field scale may be partly responsible for the increasing destructiveness of secondary flows of landslides and debris flows.

  3. Is the Sky Really Falling? An Overview of Orbital Debris

    NASA Technical Reports Server (NTRS)

    Hull, Scott M.

    2015-01-01

    Orbital debris has been a prominent topic for a while, even before the movie Gravity came out. An anti-satellite test and a collision with an operational satellite both produced large highly-publicized debris clouds within recent years. While large objects like abandoned satellites and rocket bodies may be the most recognizable and identifiable concerns, a majority of the daily threat comes from the much more numerous smaller particles. In fact, small particle penetration continues to rank among the leading risks for manned space missions to the International Space Station and beyond. How much 'stuff' is up there, where did it come from, what harm can it do, and what is being done about it? These questions and more will be discussed.

  4. Laser-reactive protection of spacecraft from fine debris

    SciTech Connect

    Kuznetsov, L I; Savichev, V Yu; Tikhonov, N N

    1998-04-30

    An analysis is made of the optimal conditions for laser irradiation and of typical paths of man-made debris in laser-reactive protection of spacecraft. Protection is provided by the recoil momentum resulting from laser evaporation of the surface layers of a debris particle, which can change its path, thus avoiding an collision with a spacecraft. Estimates are obtained of changes in the paths of particles with a characteristic size 1 cm when they are irradiated by radiation from a laser located on the protected spacecraft moving along one of the circular orbits at altitudes of 200, 400, or 700 km above the Earth's surface. (laser applications and other topics in quantum electronics)

  5. Size-dependent cytotoxicity of silver nanoparticles in human lung cells: the role of cellular uptake, agglomeration and Ag release

    PubMed Central

    2014-01-01

    Background Silver nanoparticles (AgNPs) are currently one of the most manufactured nanomaterials. A wide range of toxicity studies have been performed on various AgNPs, but these studies report a high variation in toxicity and often lack proper particle characterization. The aim of this study was to investigate size- and coating-dependent toxicity of thoroughly characterized AgNPs following exposure of human lung cells and to explore the mechanisms of toxicity. Methods BEAS-2B cells were exposed to citrate coated AgNPs of different primary particle sizes (10, 40 and 75 nm) as well as to 10 nm PVP coated and 50 nm uncoated AgNPs. The particle agglomeration in cell medium was investigated by photon cross correlation spectroscopy (PCCS); cell viability by LDH and Alamar Blue assay; ROS induction by DCFH-DA assay; genotoxicity by alkaline comet assay and γH2AX foci formation; uptake and intracellular localization by transmission electron microscopy (TEM); and cellular dose as well as Ag release by atomic absorption spectroscopy (AAS). Results The results showed cytotoxicity only of the 10 nm particles independent of surface coating. In contrast, all AgNPs tested caused an increase in overall DNA damage after 24 h assessed by the comet assay, suggesting independent mechanisms for cytotoxicity and DNA damage. However, there was no γH2AX foci formation and no increased production of intracellular reactive oxygen species (ROS). The reasons for the higher toxicity of the 10 nm particles were explored by investigating particle agglomeration in cell medium, cellular uptake, intracellular localization and Ag release. Despite different agglomeration patterns, there was no evident difference in the uptake or intracellular localization of the citrate and PVP coated AgNPs. However, the 10 nm particles released significantly more Ag compared with all other AgNPs (approx. 24 wt% vs. 4–7 wt%) following 24 h in cell medium. The released fraction in cell medium did not induce any

  6. The debris disc around HIP 17439

    NASA Astrophysics Data System (ADS)

    Schüppler, Christian; Löhne, Torsten; Krivov, Alexander

    2013-07-01

    In the framework of the Herschel Open Time Key Programme DUNES the debris disc around the K2 V star HIP 17439 was observed. In PACS images the disc emission is spatially clearly extended. A simultaneous analysis of photometric observations and radial brightness profiles from the resolved images provides valuable hints for the disc structure. In an analytical model we adopted power laws for the size and radial distribution of the circumstellar dust and tested two different scenarios: (1) a broad dust ring with a radial extent of about 200AU, (2) two independent dust rings separated by a gap of several tens of AU. Both models fit the spectral energy distribution and the radial profiles quite well. In case (1) the parameters found are consistent with dust stemming from an outer planetesimal belt at ~140AU and strong transport mechanisms that drag the particles inward. Model (2) would imply two planetesimal belts, producing a narrow inner and wider outer distribution of dust.

  7. Orbital debris and meteoroid population as estimated from LDEF impact data

    SciTech Connect

    Zhang, J.; Kessler, D.J.

    1995-02-01

    Examination of LDEF`s various surfaces shows numerous craters and holes due to hypervelocity impacts of meteoroids and man-made orbital debris. In this paper, the crater numbers as reported by Humes have been analyzed in an effort to understand the orbital debris and natural meteoroid environment in LEO. To determine the fraction of man-made to natural impacts, the side to top ratio of impacts and results of the Chemistry of Micrometeoroids Experiment are used. For craters in the 100 micron to 500 micron size range, about 25 percent to 30 percent of the impacts on the forward-facing surfaces and about 10 percent of the impacts on the trailing surfaces were estimated due to man-made orbital debris. A technique has been developed to convert crater numbers to particle fluxes, taking the fact into account that the distributions of impact velocity and incidence angle vary over the different surfaces of LDEF, as well as the ratio of the surface area flux to the cross-sectional area flux. Applying this technique, Humes` data concerning craters with limiting lip diameters of 100 micron, 200 micron and 500 micron have been converted into orbital debris and meteoroid fluxes ranging from about 20 micron to 200 micron particle diameter. The results exhibit good agreement with orbital debris model and meteoroid model. The converted meteoroid flux is slightly larger than Grun`s model (by 40 to 70 percent). The converted orbital debris flux is slightly lower than Kessler`s model for particle diameter smaller than about 30 micron and slightly larger than the model for particle diameter larger than about 40 micron. Taking also into account the IDE data point at about 0.8 micron particle diameter, it suggests to change the slope log (flux) versus log (diameter) of orbital debris flux in the 1 micron to 100 micron particle diameter range from 2.5 to 1.9.

  8. DebriSat Project Update and Planning

    NASA Technical Reports Server (NTRS)

    Sorge, M.; Krisko, P. H.

    2016-01-01

    DebriSat Reporting Topics: DebriSat Fragment Analysis Calendar; Near-term Fragment Extraction Strategy; Fragment Characterization and Database; HVI (High-Velocity Impact) Considerations; Requirements Document.

  9. NASA Orbital Debris Requirements and Best Practices

    NASA Technical Reports Server (NTRS)

    Hull, Scott

    2014-01-01

    Limitation of orbital debris accumulation is an international and national concern, reflectedin NASA debris limitation requirements. These requirements will be reviewed, along with some practices that can be employed to achieve the requirements.

  10. Debris Detector Verification by Hvi-Tests

    NASA Astrophysics Data System (ADS)

    Bauer, Waldemar; Drolshagen, Gerhard; Vörsmann, Peter; Romberg, Oliver; Putzar, Robin

    Information regarding Space Debris (SD) or Micrometeoroids (MM) impacting on spacecraft (S/C) or payloads (P/L) can be obtained by using environmental models e.g. MASTER (ESA) or ORDEM (NASA). The validation of such models is performed by comparison of simulated results with measured or orbital observed data. The latter is utilised for large particles and can be obtained from ground based or space based radars or telescopes. Data regarding very small but abundant particles can also be gained by analysis of retrieved hardware (e.g. Hubble Space Telescope, Space Shuttle Windows), which are brought from orbit back to Earth. Furthermore, in-situ impact detectors are an essential source for information on small size meteoroids and space debris. These kind of detectors are placed in orbit and collect impact data regarding SD and MM, sending data near real time via telemetry. Compared to the impact data which is gained by analysis of retrieved surfaces, the detected data comprise additional information regarding exact impact time and, depending on the type of detector, on the orbit and particles composition. Nevertheless, existing detectors have limitations. Since the detection area is small, statistically meaningful number of impacts are obtained for very small particles only. Measurements of particles in the size range of hundreds of microns to mm which are potentially damaging to S/C require larger sensor areas. To make use of the advantages of in-situ impact detectors and to increase the amount of impact data an innovative impact detector concept is currently under development at DLR in Bremen. Different to all previous impact detectors the Solar Generator based Impact Detector (SOLID) is not an add-on component on the S/C. SOLID makes use of existing subsystems of the S/C and adopts them for impact detection purposes. Since the number of impacts on a target in space depends linearly on the exposed area, the S/C solar panels offer a unique opportunity to use them for

  11. Design of a shuttle-based space debris telescope

    NASA Technical Reports Server (NTRS)

    Richardson, E. H.; Talent, D. L.; Tritsch, C. L.; Vilas, F.

    1990-01-01

    A 1.6-meter diameter f/0.95 all-reflecting telescope was designed to observe orbital debris particles as small as 1 mm from the shuttle payload bay. The telescope was specified to have a flat focal surface without the imposition of refractive elements. Two design configurations involving three mirrors were evaluated - a reflective Schmidt-Cassegrain and a modified Paul corrector. The Paul system was found to be more compact and appropriate for this application.

  12. Influence of debris flow scale on equilibrium bed slope

    NASA Astrophysics Data System (ADS)

    Itoh, T.; Egashira, S.; Papa, M.; Miyamoto, K.

    2003-04-01

    Results obtained from both of flume tests and theory suggest that an equilibrium bed slope in flow over an erodible bed is determined only by sediment discharge rate when the movements of sediment particles are laminar and thus no suspended transportation take place. This means that the static friction force is dominant in debris flow and that sediment concentration is determined by shear stress balance on the bed surface; i.e., the external shear stress must be equal to the resisting static shear stress of sediment particles, as seen in our previous studies. On the other hand, if part of sediment particles in debris flow body is transported in suspension, sediment concentration will be larger in comparison with that in case of laminar motion of sediment particles and the equilibrium bed slope will decrease. These facts are supported Egashira et al.'s experimental data. The present study discusses an influence of flow scales on an equilibrium bed slope and flow structure experimentally and theoretically. Equilibrium bed slopes and velocity profiles are measured for many flow conditions in flume tests. Those results emphasize that the equilibrium bed slope decreases with increasing of flow scale if part of debris flow body is turbulent, and it is predicted corresponding to increase of mass density of fluid phase. Experimental data for velocity profiles are compared to the results predicted by authors' constitutive equations for non-cohesive sediment and water mixture. When no turbulent diffusions take place, flow characteristics such as velocity profiles and flow resistance are predicted very well by our equations. However, the equations will underestimate the flow resistance if a part of the flow body becomes turbulent because of increase of flow scale. These suggest that the changes of equilibrium bed slope and flow structure are caused by phase-shift from solid phase to fluid phase depending on debris flow scale.

  13. Debris and micrometeorite impact measurements in the laboratory

    NASA Technical Reports Server (NTRS)

    Resnick, J.; Grun, J.; Crawford, J.; Burris, R.; Manka, C. K.; Ford, J. L.; Ripin, B. H.

    1992-01-01

    A method was developed to simulate space debris in the laboratory. This method, which is an outgrowth of research in inertial confinement fusion (ICF), uses laser ablation to accelerate material. Using this method, single 60 micron aluminum spheres were accelerated to 15 km/sec and larger 500 micron aluminum spheres were accelerated to 2 km/sec. Also, many small (less than 10 micron diameter) irregularly shaped particles were accelerated to speeds of 100 km/sec.

  14. Signatures of Planets in Circumstellar Debris Disks

    NASA Astrophysics Data System (ADS)

    Moro-Martin, A.; Malhotra, R.

    2004-05-01

    In anticipation of Spitzer Space Telescope observations of unresolved debris disks, we are interested in studying how the structure carved by putative planets in circumstellar dust disks affects the shape of the disk's spectral energy distribution (SED), and consequently whether the disk SED can be used to infer the presence of planets. We use the Solar System Kuiper Belt dust disk as a case study to investigate the effects of giant planets on the dynamics of dust originating in an outer belt of planetesimals. Our main results are the following: (1) The trapping of dust particles in orbital resonances with the giant planets creates density structures in the dust disk. With present computational techniques, the equilibrium radial density distribution of dust can be accurately estimated, but the azimuthal structure is not predictable in detail because it depends sensitively on the times of residence in the various resonances; the latter are highly variable and unpredictable owing to the underlying strong chaotic dynamics. (2) The gravitational scattering of dust grains by massive planets launches a "wind'' of large dust grains that may contribute significantly to the clearing of cirumstellar debris in planetary systems; it may also significantly affect the particle size distribution of the local ISM of a planetary system. (3) The SED of a dust disk with embedded Solar-System-like planets is fundamentally different from that of one without planets, the former showing a significant decrease of the mid IR flux due to the clearing of dust from the inner 10 AU due to gravitational scattering by Jupiter and Saturn. We have calculated model SEDs (from 1 to 340 microns) and expected SPITZER colors, arising from different planetary systems consisting of an outer belt of planetesimals (similar to the Kuiper Belt) and a single planet with a mass of 1, 3 and 10 MJup and a semimajor axis of 1, 5 and 30 AU.

  15. Space Debris: Its Causes and Management

    NASA Technical Reports Server (NTRS)

    Johnson, Nicholas L.

    2002-01-01

    Orbital debris is internationally recognized as an environmental issue which needs to be addressed today to preserve near-Earth space for future generations. All major space agencies are committed to mitigating the growth of the debris environment. Many commercial space system operators have responded positively to orbital debris mitigation principles and recommendations. Orbital debris mitigation measures are most cost-effective if included in the design development phase.

  16. Orbital Debris: Cost Impact on Setting Policy.

    DTIC Science & Technology

    1996-06-01

    As the exploration of space increases, the problems associated with orbital debris also increase. 0rbital debris continues to grow at a linear rate...and at worst, unusable. When mitigating orbital debris , cost and policy issues must be addressed. Currently no policy exists that makes the mitigation...of orbital debris mandatory but it only strongly recommends mitigation as long as it is cost effective. This thesis addresses the cost impact of

  17. Modified MODFLOW-based model for simulating the agglomeration and transport of polymer-modified Fe(0) nanoparticles in saturated porous media.

    PubMed

    Babakhani, Peyman; Fagerlund, Fritjof; Shamsai, Abolfazl; Lowry, Gregory V; Phenrat, Tanapon

    2015-08-25

    The solute transport model MODFLOW has become a standard tool in risk assessment and remediation design. However, particle transport models that take into account both particle agglomeration and deposition phenomena are far less developed. The main objective of the present study was to evaluate the feasibility of adapting the standard code MODFLOW/MT3D to simulate the agglomeration and transport of three different types of polymer-modified nanoscale zerovalent iron (NZVI) in one-dimensional (1-D) and two-dimensional (2-D) saturated porous media. A first-order decay of the particle population was used to account for the agglomeration of particles. An iterative technique was used to optimize the model parameters. The model provided good matches to 1-D NZVI-breakthrough data sets, with R (2) values ranging from 0.96 to 0.99, and mass recovery differences between the experimental results and simulations ranged from 0.1 to 1.8 %. Similarly, simulations of NZVI transport in the heterogeneous 2-D model demonstrated that the model can be applied to more complicated heterogeneous domains. However, the fits were less good, with the R (2) values in the 2-D modeling cases ranging from 0.75 to 0.95, while the mass recovery differences ranged from 0.7 to 6.5 %. Nevertheless, the predicted NZVI concentration contours during transport were in good agreement with the 2-D experimental observations. The model provides insights into NZVI transport in porous media by mathematically decoupling agglomeration, attachment, and detachment, and it illustrates the importance of each phenomenon in various situations. Graphical Abstract ᅟ.

  18. Physics of debris clouds from hypervelocity impacts

    NASA Technical Reports Server (NTRS)

    Zee, Ralph

    1993-01-01

    The protection scheme developed for long duration space platforms relies primarily upon placing thin metal plates or 'bumpers' around flight critical components. The effectiveness of this system is highly dependent upon its ability to break up and redistribute the momentum of any particle which might otherwise strike the outer surface of the spacecraft. Therefore it is of critical importance to design the bumpers such that maximum dispersion of momentum is achieved. This report is devoted to an in-depth study into the design and development of a laboratory instrument which would permit the in-situ monitoring of the momentum distribution as the impact event occurs. A series of four designs were developed, constructed and tested culminating with the working instrument which is currently in use. Each design was individually tested using the Space Environmental Effects Facility (SEEF) at the Marshall Space Flight Center in Huntsville, Alabama. Along with the development of the device, an experimental procedure was developed to assist in the investigation of various bumper materials and designs at the SEEF. Preliminary results were used to compute data which otherwise were not experimentally obtainable. These results were shown to be in relative agreement with previously obtained values derived through other methods. The results of this investigation indicated that momentum distribution could in fact be measured in-situ as the impact event occurred thus giving a more accurate determination of the effects of experimental parameters on the momentum spread. Data produced by the instrument indicated a Gaussian-type momentum distribution. A second apparatus was developed and it was placed before the shield in the line of travel utilized a plate to collect impact debris scattered backwards. This plate had a passage hole in the center to allow the particle to travel through it and impact the proposed shield material. Applying the law of conservation of angular momentum a

  19. Operation of dry-cleaned and agglomerated precompaction system (DAPS)

    SciTech Connect

    Tanaka, Shigemi; Okanishi, Kazuya; Kikuchi, Akio; Yamamura, Yuichi

    1997-12-31

    In order to reduce the manufacturing cost of coke, it is necessary to reduce mainly (1) the material cost and (2) operating cost. Both of these costs can be reduced by lowering the moisture of charging coal. Because dust generation increases with decreasing moisture of charging coal, however, the lower limit of charging coal moisture in the existing coke-oven equipment was about 5%, which yielded good results in coal moisture control (CMC) equipment. Nippon Steel has furthered the development of techniques for lowering the moisture of charging coal as far as possible in the existing coke ovens and has recently succeeded in developing a dry-cleaned and agglomerated precompaction system (DAPS) and incorporating this system in commercial production equipment. In this system, a coal preparation process is undertaken that involves separating coal fines, which cause dust generation, from dried charging coal and agglomerating them. The equipment incorporating this system was installed in the No. 3 and No. 4 coke batteries at Oita Works and brought into full-scale operation in September 1992. The equipment has since been operating smoothly.

  20. Agglomeration of Luminescent Porous Silicon Nanoparticles in Colloidal Solutions

    NASA Astrophysics Data System (ADS)

    Herynková, Kateřina; Šlechta, Miroslav; Šimáková, Petra; Fučíková, Anna; Cibulka, Ondřej

    2016-08-01

    We have prepared colloidal solutions of clusters composed from porous silicon nanoparticles in methanol, water and phosphate-buffered saline (PBS). Even if the size of the nanoclusters is between 60 and 500 nm, due to their highly porous "cauliflower"-like structure, the porous silicon nanoparticles are composed of interconnected nanocrystals having around 2.5 nm in size and showing strong visible luminescence in the orange-red spectral region (centred at 600-700 nm). Hydrophilic behaviour and good solubility of the nanoclusters in water and water-based solutions were obtained by adding hydrogen peroxide into the etching solution during preparation and 16 min long after-bath in hydrogen peroxide. By simple filtration of the solutions with syringe filters, we have extracted smaller nanoclusters with sizes of approx. 60-70 nm; however, these nanoclusters in water and PBS solution (pH neutral) are prone to agglomeration, as was confirmed by zeta potential measurements. When the samples were left at ambient conditions for several weeks, the typical nanocluster size increased to approx. 330-400 nm and then remained stable. However, both freshly filtered and aged samples (with agglomerated porous silicon nanoparticles) of porous silicon in water and PBS solutions can be further used for biological studies or as luminescent markers in living cells.

  1. Applying Knowledge from Terrestrial Debris-Covered Glaciers to Constrain the Evolution of Martian Debris-Covered Ice

    NASA Astrophysics Data System (ADS)

    Koutnik, M. R.; Pathare, A. V.; Todd, C.; Waddington, E.; Christian, J. E.

    2016-09-01

    We will discuss the application of terrestrial knowledge on debris emplacement, the effects of debris on glacier-surface topography, debris transport by ice flow, deformation of debris-laden ice, and atmosphere-glacier feedbacks to Mars ice.

  2. Development in Wear Debris Morphological Analysis at RAF Early Failure Detection Centres

    DTIC Science & Technology

    1996-04-01

    previous program, CASPA (Computer-Aided Systematic Particle Analysis) which was established to assist in the analysis of wear debris extracted from oil...Luxmoore; ’The development of a computer- aided systematic particle analysis procedure - CASPA " Lubr. Eng., 48, 12 (1992), 940- 946. 7. Roylance, I.A

  3. Orbital Debris and Future Environment Remediation

    NASA Technical Reports Server (NTRS)

    Liou, Jer-Chyi

    2011-01-01

    This slide presentation is an overview of the historical and current orbital debris environment. Included is information about: Projected growth of the future debris population, The need for active debris removal (ADR), A grand challenge for the 21st century and The forward path

  4. Simulations of SSLV Ascent and Debris Transport

    NASA Technical Reports Server (NTRS)

    Rogers, Stuart; Aftosmis, Michael; Murman, Scott; Chan, William; Gomez, Ray; Gomez, Ray; Vicker, Darby; Stuart, Phil

    2006-01-01

    A viewgraph presentation on Computational Fluid Dynamic (CFD) Simulation of Space Shuttle Launch Vehicle (SSLV) ascent and debris transport analysis is shown. The topics include: 1) CFD simulations of the Space Shuttle Launch Vehicle ascent; 2) Debris transport analysis; 3) Debris aerodynamic modeling; and 4) Other applications.

  5. Space Debris Detection and Analysis

    DTIC Science & Technology

    1994-02-28

    7F AD-A282 012 PL.-TR-94-206 Space Debris Detection and Analysis Robert H. Eather Ron Siewert Keo Consultants 27 Irving St. Brookline MA 02146 28...PERFORMING ORGANIZATION REPORT NUMBER Keo Consultants 27 Irving St. Brookline MA 02146 9. SPONSORINGI MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSORING

  6. A Passive Nuclear Debris Collector.

    ERIC Educational Resources Information Center

    Griffin, John J.; And Others

    1979-01-01

    Describes a nuclear debris collector which removes trace substances from the lower atmosphere during rainfall. Suggests that the collector could be implemented into courses at various educational levels and could result in developing a network for monitoring the geographical extent of nuclear contamination. (Author/SA)

  7. Photometric Studies of GEO Debris

    NASA Technical Reports Server (NTRS)

    Seitzer, Patrick; Cowardin, Heather M.; Barker, Edwin; Abercromby, Kira J.; Foreman, Gary; Horstman, Matt

    2009-01-01

    The photometric signature of a debris object can be useful in determining what the physical characteristics of a piece of debris are. We report on optical observations in multiple filters of debris at geosynchronous Earth orbit (GEO). Our sample is taken from GEO objects discovered in a survey with the University of Michigan's 0.6-m aperture Schmidt telescope MODEST (for Michigan Orbital DEbris Survey Telescope), and then followed up in real-time with the SMARTS (Small and Medium Aperture Research Telescope System) 0.9-m at CTIO for orbits and photometry. Our goal is to determine 6 parameter orbits and measure colors for all objects fainter than R = 15 th magnitude that are discovered in the MODEST survey. At this magnitude the distribution of observed angular rates changes significantly from that of brighter objects. There are two objectives: 1. Estimate the orbital distribution of objects selected on the basis of two observational criteria: brightness (magnitude) and angular rates. 2. Obtain magnitudes and colors in standard astronomical filters (BVRI) for comparison with reflectance spectra of likely spacecraft materials. What is the faint debris likely to be? In this paper we report on the photometric results. For a sample of 50 objects, more than 90 calibrated sequences of R-B-V-I-R magnitudes have been obtained with the CTIO 0.9-m. For objects that do not show large brightness variations, the colors are largely redder than solar in both B-R and R-I. The width of the color distribution may be intrinsic to the nature of the surfaces, but also could be that we are seeing irregularly shaped objects and measuring the colors at different times with just one telescope. For a smaller sample of objects we have observed with synchronized CCD cameras on the two telescopes. The CTIO 0.9-m observes in B, and MODEST in R. The CCD cameras are electronically linked together so that the start time and duration of observations are the same to better than 50 milliseconds. Thus

  8. HEO space debris orbit predictions.

    NASA Astrophysics Data System (ADS)

    Gregorowicz, Dorota; Pospieszynski, Remigiusz; Golembiewska, Justyna; Wnuk, Edwin

    2012-07-01

    HEO (Highly Elliptical Orbit) satellites are objects with an elliptic orbit with a low-altitude perigee and a high-altitude apogee. Perigee mainly cross the LEO orbits and apogee reaches regions above GEO orbits. Number of satellites on the orbits are old racket bodies and other space debris. Most of HEO objects has the eccentricity more than 0.7. Many trackable objects are included in the NORAD TLE Catalogue but much more small debris exist which we could not track. Objects on as highly elliptical orbit are very danger for satellites in LEO region because of increasing velocity near the perigee. In order to calculate the trajectory of space debris we have to take into account force model consisting of geopotential, luni-solar effects, solar radiation pressure and for objects with low-altitude of perigee, atmospheric drag. This last perturbation is very important to calculate orbits with high accuracy but also one of the hardest to predict. Many atmospheric space debris objects parameters should be taken into account in this case, but we do not have sufficient data from observations, in particular S/M (area-to-mass) ratio. Fortunately we have some archival data for some debris included in TLE Catalogue, which are very helpful to estimate the approximate value of the parameter. In this paper we present the results of calculations of orbit predictions for short and medium time span (up to several weeks). We tried to designate the S/M parameter for some HEO objects from archival data from the TLE Catalogue and predict its orbital elements for several weeks. With better knowledge about approximate mean value of the S/M parameter we are able to improve the accuracy of predicted orbits.

  9. The Dynamical Structure of HR 8799's Inner Debris Disk.

    PubMed

    Contro, B; Wittenmyer, Robert A; Horner, J; Marshall, Jonathan P

    2015-06-01

    The HR 8799 system, with its four giant planets and two debris belts, has an architecture closely mirroring that of our Solar system where the inner, warm asteroid belt and outer, cool Edgeworth-Kuiper belt bracket the giant planets. As such, it is a valuable laboratory for examining exoplanetary dynamics and debris disk-exoplanet interactions. Whilst the outer debris belt of HR 8799 has been well resolved by previous observations, the spatial extent of the inner disk remains unknown. This leaves a significant question mark over both the location of the planetesimals responsible for producing the belt's visible dust and the physical properties of those grains. We have performed the most extensive simulations to date of the inner, unresolved debris belt around HR 8799, using UNSW Australia's Katana supercomputing facility to follow the dynamical evolution of a model inner disk comprising 300,298 particles for a period of 60 Ma. These simulations have enabled the characterisation of the extent and structure of the inner disk in detail, and will in future allow us to provide a first estimate of the small-body impact rate and water delivery prospects for possible (as-yet undetected) terrestrial planet (s) in the inner system.

  10. Debris-bed friction of hard-bedded glaciers

    NASA Astrophysics Data System (ADS)

    Cohen, D.; Iverson, N. R.; Hooyer, T. S.; Fischer, U. H.; Jackson, M.; Moore, P. L.

    2005-06-01

    Field measurements of debris-bed friction on a smooth rock tablet at the bed of Engabreen, a hard-bedded, temperate glacier in northern Norway, indicated that basal ice containing 10% debris by volume exerted local shear traction of up to 500 kPa. The corresponding bulk friction coefficient between the dirty basal ice and the tablet was between 0.05 and 0.08. A model of friction in which nonrotating spherical rock particles are held in frictional contact with the bed by bed-normal ice flow can account for these measurements if the power law exponent for ice flowing past large clasts is 1. A small exponent (n < 2) is likely because stresses in ice are small and flow is transient. Numerical calculations of the bed-normal drag force on a sphere in contact with a flat bed using n = 1 show that this force can reach values several hundred times that on a sphere isolated from the bed, thus drastically increasing frictional resistance. Various estimates of basal friction are obtained from this model. For example, the shear traction at the bed of a glacier sliding at 20 m a-1 with a geothermally induced melt rate of 0.006 m a-1 and an effective pressure of 300 kPa can exceed 100 kPa. Debris-bed friction can therefore be a major component of sliding resistance, contradicting the common assumption that debris-bed friction is negligible.

  11. Debris-Bed Friction of Hard-Bedded Glaciers

    NASA Astrophysics Data System (ADS)

    Cohen, D.; Iverson, N. R.; Hooyer, T. S.; Fischer, U. H.; Jackson, M.; Moore, P. L.

    2004-12-01

    Field measurements of debris-bed friction on a smooth rock tablet at the bed of Engabreen, a hard-bedded, temperate glacier in northern Norway, indicated that basal ice containing 10% debris by volume exerted local shear traction of up to 500~kPa. The corresponding bulk friction coefficient between the dirty basal ice and the tablet was between 0.05 and 0.08. A model of friction in which non-rotating spherical rock particles are held in frictional contact with the bed by bed-normal ice flow can account for these measurements if ice is Newtonian. Numerical calculations of the bed-normal drag force on a sphere in contact with a flat bed show that this force can reach values several hundred times that on a sphere isolated from the bed, thus drastically increasing frictional resistance. Various estimates of basal friction are obtained from this model. For example, the shear traction at the bed of a 200~m thick glacier sliding at 20~m a-1 with a geothermally induced melt rate of 0.006~m a-1 can exceed 100~kPa. Debris-bed friction can, therefore, be a major component of sliding resistance, contradicting the common assumption that debris-bed friction is negligible.

  12. Development of a gas-promoted oil agglomeration process. Quarterly technical progress report, July 1--September 30, 1996

    SciTech Connect

    Wheelock, T.D.

    1996-09-01

    The series of agglomeration tests designed to study the agglomeration characteristics of Pittsburgh No. 8 coal with i-octane was continued using a larger agitated tank. This series is designed to determine the effects of various parameters on the size and structure of the agglomerates formed, the rate of agglomeration, coal recovery, and ash rejection. The results reported here show that once spherical agglomerates are formed they continue to grow at almost a constant rate which is proportional to the concentration of i-octane. The constant growth rate is interrupted when spherical agglomerates combine to form large clusters. This only seems to occur with a large concentration of i-octane (e.g., 30 v/w%) and limited agitator power. The present results also show that coal recovery and ash rejection are highly dependent on agglomerate size when the mean agglomerate diameter is less than the size of the openings in the screen used for recovering the agglomerates.

  13. Orbital Debris Research in the United States

    NASA Technical Reports Server (NTRS)

    Stansbery, Gene

    2009-01-01

    The presentation includes information about growth of the satellite population, the U.S. Space Surveillance Network, tracking and catalog maintenance, Haystack and HAX radar observation, Goldstone radar, the Michigan Orbital Debris Survey Telescope (MODEST), spacecraft surface examinations and sample of space shuttle impacts. GEO/LEO observations from Kwajalein Atoll, NASA s Orbital Debris Engineering Model (ORDEM2008), a LEO-to-GEO Environment Debris Model (LEGEND), Debris Assessment Software (DAS) 2.0, the NASA/JSC BUMPER-II meteoroid/debris threat assessment code, satellite reentry risk assessment, optical size and shape determination, work on more complicated fragments, and spectral studies.

  14. Detecting debris flows using ground vibrations

    USGS Publications Warehouse

    LaHusen, Richard G.

    1998-01-01

    Debris flows are rapidly flowing mixtures of rock debris, mud, and water that originate on steep slopes. During and following volcanic eruptions, debris flows are among the most destructive and persistent hazards. Debris flows threaten lives and property not only on volcanoes but far downstream in valleys that drain volcanoes where they arrive suddenly and inundate entire valley bottoms. Debris flows can destroy vegetation and structures in their path, including bridges and buildings. Their deposits can cover roads and railways, smother crops, and fill stream channels, thereby reducing their flood-carrying capacity and navigability.

  15. An optimal trajectory design for debris deorbiting

    NASA Astrophysics Data System (ADS)

    Ouyang, Gaoxiang; Dong, Xin; Li, Xin; Zhang, Yang

    2016-01-01

    The problem of deorbiting debris is studied in this paper. As a feasible measure, a disposable satellite would be launched, attach to debris, and deorbit the space debris using a technology named electrodynamic tether (EDT). In order to deorbit multiple debris as many as possible, a suboptimal but feasible and efficient trajectory set has been designed to allow a deorbiter satellite tour the LEO small bodies per one mission. Finally a simulation given by this paper showed that a 600 kg satellite is capable of deorbiting 6 debris objects in about 230 days.

  16. Effects of meteoric debris on stratospheric aerosols and gases

    NASA Technical Reports Server (NTRS)

    Turco, R. P.; Toon, O. B.; Whitten, R. C.; Hamill, P.

    1981-01-01

    Characterizations of meteoric dust height and size distributions are obtained using Hunten's calculations of meteor ablation and recondensation rates. The contribution of meteor residues to aerosol composition, the role of meteoric dust as condensation nuclei, and the effects of meteor debris on aerosol size distributions are quantified, and particle surface areas are estimated. The potential importance of heterogeneous chemistry for stratospheric trace gases is discussed. The interaction between H2SO4 vapor and meteor metal vapors is investigated. It is concluded that meteoric particles may dominate the natural stratospheric aerosols at small (less than .01 micron radius) and large (greater than 1 micron radius) sizes under normal conditions.

  17. An online debris sensor system with vibration resistance for lubrication analysis

    NASA Astrophysics Data System (ADS)

    Ding, Yongbin; Wang, Yanxue; Xiang, Jiawei

    2016-02-01

    The health condition of the lubricated systems can be directly indicated by the concentration and material type of the abrasive particles, which may provide very early warnings of faults/failures and benefit the condition based maintenance. Oil debris particle detecting techniques are thus important for machinery condition monitoring and fault diagnosis. This work proposes a new structure of online debris sensor (ODS), which applies the radial magnetic field, different from the traditional axial magnetic field. The designed ODS can effectively reduce the interferences of the background noise and the vibration of the machine in operation. Moreover, in order to optimally determine the number of turns of an inductive coil and the current of the drive coils, two methods are developed respectively in this work which can ensure sensitivity and anti-vibration features of the ODS. The instrumentation circuit system for detecting debris particles and sensing signals has been also designed to extract and to record the signatures of particles. The designed ODS device is then applied to analyze micro debris particles in the lubricating system on a test rig. Experimental results have demonstrated that ODS can successfully detect the 120 μm(H) ferrous particles and 500 μm(H) non-ferrous particles under vibration conditions.

  18. An online debris sensor system with vibration resistance for lubrication analysis.

    PubMed

    Ding, Yongbin; Wang, Yanxue; Xiang, Jiawei

    2016-02-01

    The health condition of the lubricated systems can be directly indicated by the concentration and material type of the abrasive particles, which may provide very early warnings of faults/failures and benefit the condition based maintenance. Oil debris particle detecting techniques are thus important for machinery condition monitoring and fault diagnosis. This work proposes a new structure of online debris sensor (ODS), which applies the radial magnetic field, different from the traditional axial magnetic field. The designed ODS can effectively reduce the interferences of the background noise and the vibration of the machine in operation. Moreover, in order to optimally determine the number of turns of an inductive coil and the current of the drive coils, two methods are developed respectively in this work which can ensure sensitivity and anti-vibration features of the ODS. The instrumentation circuit system for detecting debris particles and sensing signals has been also designed to extract and to record the signatures of particles. The designed ODS device is then applied to analyze micro debris particles in the lubricating system on a test rig. Experimental results have demonstrated that ODS can successfully detect the 120 μm(H) ferrous particles and 500 μm(H) non-ferrous particles under vibration conditions.

  19. The Central Role of Wear Debris in Periprosthetic Osteolysis

    PubMed Central

    Koulouvaris, Panagiotis; Nestor, Bryan J.; Sculco, Thomas P.

    2006-01-01

    Periprosthetic osteolysis remains the leading complication of total hip arthroplasty, often resulting in aseptic loosening of the implant, and a requirement for revision surgery. Wear-generated particular debris is the main cause of initiating this destructive process. The purpose of this article is to review recent advances in our understanding of how wear debris causes osteolysis, and emergent strategies for the avoidance and treatment of this disease. The most important cellular target for wear debris is the macrophage, which responds to particle challenge in two distinct ways, both of which contribute to increased bone resorption. First, it is well known that wear debris activates proinflammatory signaling, which leads to increased osteoclast recruitment and activation. More recently, it has been established that wear also inhibits the protective actions of antiosteoclastogenic cytokines such as interferon gamma, thus promoting differentiation of macrophages to bone-resorbing osteoclasts. Osteoblasts, fibroblasts, and possibly lymphocytes may also be involved in responses to wear. At a molecular level, wear particles activate MAP kinase cascades, NFκB and other transcription factors, and induce expression of suppressors of cytokine signaling. Strategies to reduce osteolysis by choosing bearing surface materials with reduced wear properties (such as metal-on-metal) should be balanced by awareness that reducing particle size may increase biological activity. Finally, although therapeutic agents against proinflammatory mediators [such as tumor necrosis factor (TNF)] and osteoclasts (bisphosphonates and molecules blocking RANKL signaling) have shown promise in animal models, no approved treatments are yet available to osteolysis patients. Considerable efforts are underway to develop such therapies, and to identify novel targets for therapeutic intervention. PMID:18751821

  20. Orbiting space debris: Dangers, measurement and mitigation

    NASA Astrophysics Data System (ADS)

    McNutt, Ross T.

    1992-06-01

    Space debris is a growing environmental problem. Accumulation of objects in earth orbit threatens space systems through the possibility of collisions and runaway debris multiplication. The amount of debris in orbit is uncertain due to the lack of information on the population of debris between 1 and 10 centimeters diameter. Collisions with debris even smaller than 1 cm can be catastrophic due to the high orbital velocities involved. Research efforts are under way at NASA, United States Space Command and the Air Force Phillips Laboratory to detect and catalog the debris population in near-earth space. Current international and national laws are inadequate to control the proliferation of space debris. Space debris is a serious problem with large economic, military, technical and diplomatic components. Actions need to be taken now to: determine the full extent of the orbital debris problem; accurately predict the future evolution of the debris population; decide the extent of the debris mitigation procedures required; implement these policies on a global basis via an international treaty. Action must be initiated now, before the loss of critical space systems such as the space shuttle or the space station.

  1. Orbiting space debris: Dangers, measurement, and mitigation

    NASA Astrophysics Data System (ADS)

    McNutt, Ross T.

    1992-01-01

    Space debris is a growing environmental problem. Accumulation of objects in Earth orbit threatens space systems through the possibility of collisions and runaway debris multiplication. The amount of debris in orbit is uncertain due to the lack of information on the population of debris between 1 and 10 centimeters diameter. Collisions with debris even smaller than 1 cm can be catastrophic due to the high orbital velocities involved. Research efforts are under way at NASA, Unites States Space Command and the Air Force Phillips Laboratory to detect and catalog the debris population in near-Earth space. Current international and national laws are inadequate to control the proliferation of space debris. Space debris is a serious problem with large economic, military, technical, and diplomatic components. Actions need to be taken now for the following reasons: determine the full extent of the orbital debris problem; accurately predict the future evolution of the debris population; decide the extent of the debris mitigation procedures required; implement these policies on a global basis via an international treaty. Action must be initiated now, before the the loss of critical space systems such as the Space Shuttle or the Space Station.

  2. Meteoroid and space debris impacts in grazing-incidence telescopes

    NASA Astrophysics Data System (ADS)

    Carpenter, J. D.; Wells, A.; Abbey, A. F.; Ambrosi, R. M.

    2008-06-01

    Context: Micrometeoroid or space debris impacts have been observed in the focal planes of the XMM-Newton and Swift-XRT (X-ray Telescope) X-ray observatories. These impacts have resulted in damage to, and in one case the failure of, focal-plane Charge-Coupled Device (CCDs) detectors. Aims: We aim to quantify the future risks of focal-plane impacts in present and future X-ray observatories. Methods: We present a simple model for the propagation of micrometeoroids and space debris particles into telescopes with grazing-incidence X-ray optics, which is based on the results of previous investigations into grazing-incidence hypervelocity impacts by microscopic particles. We then calculate micrometeoroid and space debris fluxes using the Micrometeoroid and Space Debris Terrestrial Environment Reference model (MASTER2005). The risks of future focal-plane impact events in three present (Swift-XRT, XMM-Newton, and Chandra) and two future (SIMBOL-X and XEUS) X-ray observatories are then estimated on the basis of the calculated fluxes and the model for particle propagation. Results: The probabilities of at least one impact occurring in the Swift-XRT, XMM-Newton, and Chandra focal planes, in a one year period from the time of writing in November 2007 are calculated to be ~5% and ~50% and ~3%. First-order predictions of the impact rates expected for the future SIMBOL-X and XEUS X-ray observatories yield probabilities for at least one focal-plane impact, during nominal 5-year missions, of more than 94% and 99%, respectively. Conclusions: The propagation of micrometeoroids and space debris particles into the focal planes of X-ray telescopes is highest for Wolter optics with the largest collecting areas and the lowest grazing angles. Telescopes in low-Earth orbits encounter enhanced particle fluxes compared with those in higher orbits and a pointing avoidance strategy for certain directions can reduce the risk of impacts. Future X-ray observatories, with large collecting areas and

  3. Space Tourism: Orbital Debris Considerations

    NASA Astrophysics Data System (ADS)

    Mahmoudian, N.; Shajiee, S.; Moghani, T.; Bahrami, M.

    2002-01-01

    Space activities after a phase of research and development, political competition and national prestige have entered an era of real commercialization. Remote sensing, earth observation, and communication are among the areas in which this growing industry is facing competition and declining government money. A project like International Space Station, which draws from public money, has not only opened a window of real multinational cooperation, but also changed space travel from a mere fantasy into a real world activity. Besides research activities for sending man to moon and Mars and other outer planets, space travel has attracted a considerable attention in recent years in the form of space tourism. Four countries from space fairing nations are actively involved in the development of space tourism. Even, nations which are either in early stages of space technology development or just beginning their space activities, have high ambitions in this area. This is worth noting considering their limited resources. At present, trips to space are available, but limited and expensive. To move beyond this point to generally available trips to orbit and week long stays in LEO, in orbital hotels, some of the required basic transportations, living requirements, and technological developments required for long stay in orbit are already underway. For tourism to develop to a real everyday business, not only the price has to come down to meaningful levels, but also safety considerations should be fully developed to attract travelers' trust. A serious hazard to space activities in general and space tourism in particular is space debris in earth orbit. Orbiting debris are man-made objects left over by space operations, hazardous to space missions. Since the higher density of debris population occurs in low earth orbit, which is also the same orbit of interest to space tourism, a careful attention should be paid to the effect of debris on tourism activities. In this study, after a

  4. Remediation of Sucarnoochee soil by agglomeration with fine coal

    SciTech Connect

    Narayanan, P.S.; Arnold, D.W.; Rahnama, M.B. )

    1994-01-01

    Fine-sized Blue Creek coal was used to remove high molecular weight hydrocarbons from Sucarnoochee soil, a fine-sized high-organic soil. Fine coal in slurry form was blended with Sucarnoochee soil contaminated with 15.0% by wt of crude oil, and agglomerates were removed in a standard flotation cell. Crude oil in the remediated soil was reduced from the original 15.0% to less than a tenth of a wt% by a two-step process. Oil removal of approx. 99.3% was obtained. An added benefit was that the low-grade coal used in the process was simultaneously upgraded. The final level of cleaning was not affected by initial oil concentration. The process compared favorably with a hot water wash technique used to recovery oils from contaminated soil.

  5. Innovations in thermoelectric materials research: Compound agglomeration, testing and preselection

    NASA Astrophysics Data System (ADS)

    Lopez de Cardenas, Hugo Francisco Lopez

    Thermoelectric materials have the capacity to convert a temperature differential into electrical power and vice versa. They will represent the next revolution in alternative energies once their efficiencies are enhanced so they can complement other forms of green energies that depend on sources other than a temperature differential. Progress in materials science depends on the ability to discover new materials to eventually understand them and to finally improve their properties. The work presented here is aimed at dynamizing the screening of materials of thermoelectric interest. The results of this project will enable: theoretical preselection of thermoelectric compounds based on their bandgap and a rapid agglomeration method that does not require melting or sintering. A special interest will be given to Iodine-doped TiSe2 that generated extraordinary results and a new set of equations are proposed to accurately describe the dependence of the power factor and the figure of merit on the intrinsic properties of the materials.

  6. NASA Orbital Debris Large-Object Baseline Population in ORDEM 3.0

    NASA Technical Reports Server (NTRS)

    Krisco, Paula H.; Vavrin, A. B.; Anz-Meador, P. D.

    2013-01-01

    The NASA Orbital Debris Program Office (ODPO) has created and validated high fidelity populations of the debris environment for the latest Orbital Debris Engineering Model (ORDEM 3.0). Though the model includes fluxes of objects 10 um and larger, this paper considers particle fluxes for 1 cm and larger debris objects from low Earth orbit (LEO) through Geosynchronous Transfer Orbit (GTO). These are validated by several reliable radar observations through the Space Surveillance Network (SSN), Haystack, and HAX radars. ORDEM 3.0 populations were designed for the purpose of assisting, debris researchers and sensor developers in planning and testing. This environment includes a background derived from the LEO-to-GEO ENvironment Debris evolutionary model (LEGEND) with a Bayesian rescaling as well as specific events such as the FY-1C anti-satellite test, the Iridium 33/Cosmos 2251 accidental collision, and the Soviet/Russian Radar Ocean Reconnaissance Satellite (RORSAT) sodium-potassium droplet releases. The environment described in this paper is the most realistic orbital debris population larger than 1 cm, to date. We describe derivations of the background population and added specific populations. We present sample validation charts of our 1 cm and larger LEO population against Space Surveillance Network (SSN), Haystack, and HAX radar measurements.

  7. Debris flows from tributaries of the Colorado River, Grand Canyon National Park, Arizona

    USGS Publications Warehouse

    Webb, Robert H.; Pringle, Patrick T.; Rink, Glenn R.

    1989-01-01

    second. The debris flow of 1966 in the Crystal Creek drainage had a discharge estimated between 9,200 and 14,000 cubic feet per second. Determination of the effective cross-sectional area was a problem in all calculations involving superelevations on bends because areas near superelevation marks were 1.5 to 3.5 times larger than areas of upstream or downstream cross sections. Debris flows in the Grand Canyon generally are composed of 10 to 40 percent sand by weight and may represent a significant source of beach-building sand along the Colorado River. The particle-size distributions are very poorly sorted and the largest transported boulders were in the Crystal Creek drainage. The large boulders transported into the Colorado River by debris flows create or change hydraulic controls (rapids); these controls appear to be governed by the magnitude and frequency of tributary-flow events and the history of discharges on the Colorado River. Reworking of debris fans by the Colorado River creates debris bars that constrain the size of eddy systems and forms secondary rapids and riffles below tributary mouths.

  8. Debris Disks and Hidden Planets

    NASA Technical Reports Server (NTRS)

    Kuchner, Marc

    2008-01-01

    When a planet orbits inside a debris disk like the disk around Vega or Beta Pictoris, the planet may be invisible, but the patterns it creates in the disk may give it away. Observing and decoding these patterns may be the only way we can detect exo-Neptunes orbiting more than 20 AU from their stars, and the only way we can spot planets in systems undergoing the late stages of planet formation. Fortunately, every few months, a new image of a debris disk appears with curious structures begging for explanation. I'll describe some new ideas in the theory of these planet-disk interactions and provide a buyers guide to the latest models (and the planets they predict).

  9. Comparison of space debris estimates

    SciTech Connect

    Canavan, G.H.; Judd, O.P.; Naka, R.F.

    1996-10-01

    Debris is thought to be a hazard to space systems through impact and cascading. The current environment is assessed as not threatening to defense systems. Projected reductions in launch rates to LEO should delay concerns for centuries. There is agreement between AFSPC and NASA analyses on catalogs and collision rates, but not on fragmentation rates. Experiments in the laboratory, field, and space are consistent with AFSPC estimates of the number of fragments per collision. A more careful treatment of growth rates greatly reduces long-term stability issues. Space debris has not been shown to be an issue in coming centuries; thus, it does not appear necessary for the Air Force to take additional steps to mitigate it.

  10. Debris flow study in Malaysia

    NASA Astrophysics Data System (ADS)

    Bahrin Jaafar, Kamal

    2016-04-01

    The phenomenon of debris flow occurs in Malaysia occasionally. The topography of Peningsular Malysia is characterized by the central mountain ranges running from south to north. Several parts of hilly areas with steep slopes, combined with high saturation of soil strata that deliberately increase the pore water pressure underneath the hill slope. As a tropical country Malaysia has very high intensity rainfall which is triggered the landslide. In the study area where the debris flow are bound to occur, there are a few factors that contribute to this phenomenon such as high rainfall intensity, very steep slope which an inclination more than 35 degree and sandy clay soil type which is easily change to liquidity soil. This paper will discuss the study of rainfall, mechanism, modeling and design of mitigation measure to avoid repeated failure in future in same area.

  11. Momentum distribution in debris cloud during hypervelocity impact

    NASA Technical Reports Server (NTRS)

    Lemaster, P.; Mount, A.; Zee, R. H.

    1992-01-01

    The long term operation of the Space Station Freedom requires a scheme to protect it from high velocity impacts by both man-made particles and micrometeor fragments. One such scheme is the use of metal plates to serve as shields against such orbital debris. These 'bumper' plates, as they are referred to, serve to break up any incident particle and redistribute its momentum over a larger area. It is therefore necessary to determine the momentum distribution within the debris cloud produced by such collisions in order to evaluate a materials effectiveness at accomplishing this task. This paper details the design and development of an innovative device which has made this possible. Momentum profiles were obtained for a series of test conditions. Total momentum values in the debris cloud were then calculated from these profiles. These results indicated that a momentum amplification exists with a multiplication factor of between 2 and 3. Thus the role of the bumper to serve as a means for momentum redistribution and not reduction was verified.

  12. Improving The Near-Earth Meteoroid And Orbital Debris Environment Definition With LAD-C

    NASA Technical Reports Server (NTRS)

    Liou, J.-C.; Giovane, F. J.; Corsaro, R. C.; Burchell, M. J.; Drolshagen, G.; Kawai, H.; Tabata, M.; Stansbery, E. G.; Westphal, A. J.; Yano, H.

    2006-01-01

    To improve the near-Earth meteoroid and orbital debris environment definition, a large area particle sensor/collector is being developed to be placed on the International Space Station (ISS). This instrument, the Large Area Debris Collector (LAD-C), will attempt to record meteoroid and orbital debris impact flux, and capture the same particles with aerogel. After at least one year of deployment, the whole system will be brought back for additional laboratory analysis of the captured meteoroids and orbital debris. This project is led by the U.S. Naval Research Laboratory (NRL) while the U.S. Department of Defense (DoD) Space Test Program (STP) is responsible for the integration, deployment, and retrieval of the system. Additional contributing team members of the consortium include the NASA Orbital Debris Program Office, JAXA Institute of Space and Astronautical Science (ISAS), Chiba University (Japan), ESA Space Debris Office, University of Kent (UK), and University of California at Berkeley. The deployment of LAD-C on the ISS is planned for 2008, with the system retrieval in late 2009.

  13. Net Catches Debris From Explosion

    NASA Technical Reports Server (NTRS)

    Kahn, Jon B.; Schneider, William C.

    1992-01-01

    Device restrains fragments and absorbs their kinetic energy. Net of stitched webbing folds compactly over honeycomb plug. Attaches to frame mounted on wall around rectangular area to be cut out by explosion. Honeycomb panel absorbs debris from explosion and crumples into net. Dissipates energy by ripping about 9 in. of stitched net. Developed for emergency escape system in Space Shuttle, adaptable to restraint belts for vehicles; subjecting passengers to more gradual deceleration and less shock.

  14. Workers Search for Columbia's Debris

    NASA Technical Reports Server (NTRS)

    2003-01-01

    Members of a US Forest Service search team walk a grid during a Columbia recovery search near the Hemphill, Texas site. The group is accompanied by a space program worker able to identify potential hazards of Shuttle parts. Workers from every NASA Center and numerous federal, state, and local agencies searched for Columbia's debris in the recovery effort. For more information on STS-107, please see GRIN Columbia General Explanation

  15. DEBRIS sightings in the Kepler field

    NASA Astrophysics Data System (ADS)

    Witteborn, Fred C.; Van Cleve, Jeffrey; Borucki, William; Argabright, Vic; Hascall, Patrick

    2011-10-01

    A small fraction of Kepler telescope exposures are rejected because of transient, excess background in the field. The patterns of illumination vary from broad streaks to diffuse patches, sometimes filling the focal plane. Examination of such images and their temporal variation shows that they can be attributed to nearby particles crossing the field-of-view of the telescope. Most of the particles appear to be receding. The visual appearance and frequency are consistent with the "debris storms" reported by STEREO SECCHI observers and which they found to be coincident with meteoroid impacts. In addition, a few events, lasting several hours each, appear to be caused by more distant extended sources, possibly the remains of comet dust trails. The tracking cameras, located at the opposite end from the telescope's entrance, and pointed at roughly right angles to its line-of-sight, also detected moving light sources. Their behavior was consistent with the main telescope sightings. Future missions requiring precise, uninterrupted photometry and pointing may benefit from understanding this phenomenon and mitigating it by design and data analysis.

  16. Comparison of debris flux models

    NASA Astrophysics Data System (ADS)

    Sdunnus, H.; Beltrami, P.; Klinkrad, H.; Matney, M.; Nazarenko, A.; Wegener, P.

    The availability of models to estimate the impact risk from the man-made space debris and the natural meteoroid environment is essential for both, manned and unmanned satellite missions. Various independent tools based on different approaches have been developed in the past years. Due to an increased knowledge of the debris environment and its sources e.g. from improved measurement capabilities, these models could be updated regularly, providing more detailed and more reliable simulations. This paper addresses an in-depth, quantitative comparison of widely distributed debris flux models which were recently updated, namely ESA's MASTER 2001 model, NASA's ORDEM 2000 and the Russian SDPA 2000 model. The comparison was performed in the frame of the work of the 20t h Interagency Debris Coordination (IADC) meeting held in Surrey, UK. ORDEM 2000ORDEM 2000 uses careful empirical estimates of the orbit populations based onthree primary data sources - the US Space Command Catalog, the H ystackaRadar, and the Long Duration Exposure Facility spacecraft returned surfaces.Further data (e.g. HAX and Goldstone radars, impacts on Shuttle windows andradiators, and others) were used to adjust these populations for regions in time,size, and space not covered by the primary data sets. Some interpolation andextrapolation to regions with no data (such as projections into the future) wasprovided by the EVOLVE model. MASTER 2001The ESA MASTER model offers a full three dimensional description of theterrestrial debris distribution reaching from LEO up to the GEO region. Fluxresults relative to an orbiting target or to an inertial volume can be resolved intosource terms, impactor characteristics and orbit, as well as impact velocity anddirection. All relevant debris source terms are considered by the MASTERmodel. For each simulated source, a corresponding debris generation model interms of mass/diameter distribution, additional velocities, and directionalspreading has been developed. A

  17. Orbital Debris Observations with WFCAM

    NASA Astrophysics Data System (ADS)

    Kendrick, R.; Mann, B.; Read, M.; Kerr, T.; Irwin, M.; Cross, N.; Bold, M.,; Varricatt, W.; Madsen, G.

    2014-09-01

    The United Kingdom Infrared Telescope has been operating for 35 years on the summit of Mauna Kea as a premier Infrared astronomical facility. In its 35th year the telescope has been turned over to a new operating group consisting of University of Arizona, University of Hawaii and the LM Advanced Technology Center. UKIRT will continue its astronomical mission with a portion of observing time dedicated to orbital debris and Near Earth Object detection and characterization. During the past 10 years the UKIRT Wide Field CAMera (WFCAM) has been performing large area astronomical surveys in the J, H and K bands. The data for these surveys have been reduced by the Cambridge Astronomical Survey Unit in Cambridge, England and archived by the Wide Field Astronomy Unit in Edinburgh, Scotland. During January and February of 2014 the Wide Field CAMera (WFCAM) was used to scan through the geostationary satellite belt detecting operational satellites as well as nearby debris. Accurate photometric and astrometric parameters have been developed by CASU for each of the detections and all data has been archived by WFAU. This paper will present the January and February results of the orbital debris surveys with WFCAM.

  18. Lightcurves of Extreme Debris Disks

    NASA Astrophysics Data System (ADS)

    Rieke, George; Meng, Huan; Su, Kate

    2012-12-01

    We have recently discovered that some planetary debris disks with extreme fractional luminosities are variable on the timescale of a few years. This behavior opens a new possibility to understand planet building. Two of the known variable disks are around solar-like stars in the age range of 30 to 100+ Myr, which is the expected era of the final stages of terrestrial planet building. Such variability can be attributed to violent collisions (up to ones on the scale of the Moon-forming event between the proto-Earth and another proto-planet). The collisional cascades that are the aftermaths of these events can produce large clouds of tiny dust grains, possibly even condensed from silica vapor. A Spitzer pilot program has obtained the lightcurve of such a debris disk and caught two minor outbursts. Here we propose to continue the lightcurve monitoring with higher sampling rates and to expand it to more disks. The proposed time domain observations are a new dimension of debris disk studies that can bring unique insight to their evolution, providing important constraints on the collisional and dynamical models of terrestrial planet formation.

  19. Space Shuttle Solid Rocket Booster Debris Assessment

    NASA Technical Reports Server (NTRS)

    Kendall, Kristin; Kanner, Howard; Yu, Weiping

    2006-01-01

    The Space Shuttle Columbia Accident revealed a fundamental problem of the Space Shuttle Program regarding debris. Prior to the tragedy, the Space Shuttle requirement stated that no debris should be liberated that would jeopardize the flight crew and/or mission success. When the accident investigation determined that a large piece of foam debris was the primary cause of the loss of the shuttle and crew, it became apparent that the risk and scope of - damage that could be caused by certain types of debris, especially - ice and foam, were not fully understood. There was no clear understanding of the materials that could become debris, the path the debris might take during flight, the structures the debris might impact or the damage the impact might cause. In addition to supporting the primary NASA and USA goal of returning the Space Shuttle to flight by understanding the SRB debris environment and capability to withstand that environment, the SRB debris assessment project was divided into four primary tasks that were required to be completed to support the RTF goal. These tasks were (1) debris environment definition, (2) impact testing, (3) model correlation and (4) hardware evaluation. Additionally, the project aligned with USA's corporate goals of safety, customer satisfaction, professional development and fiscal accountability.

  20. Observing orbital debris using space-based telescopes. I - Mission orbit considerations

    NASA Technical Reports Server (NTRS)

    Reynolds, Robert C.; Talent, David L.; Vilas, Faith

    1989-01-01

    In this paper, mission orbit considerations are addressed for using the Space Shuttle as a telescope platform for observing man-made orbital debris. Computer modeling of various electrooptical systems predicts that such a space-borne system will be able to detect particles as small as 1-mm diameter. The research is meant to support the development of debris- collision warning sensors through the acquisition of spatial distribution and spectral characteristics for debris and testing of detector combinations on a shuttle-borne telescopic experiment. The technique can also be applied to low-earth-orbit-debris environment monitoring systems. It is shown how the choice of mission orbit, season of launch, and time of day of launch may be employed to provide extended periods of favorable observing conditions.

  1. Inventory and transport of plastic debris in the Laurentian Great Lakes.

    PubMed

    Hoffman, Matthew J; Hittinger, Eric

    2017-02-15

    Plastic pollution in the world's oceans has received much attention, but there has been increasing concern about the high concentrations of plastic debris in the Laurentian Great Lakes. Using census data and methodologies used to study ocean debris we derive a first estimate of 9887 metric tonnes per year of plastic debris entering the Great Lakes. These estimates are translated into population-dependent particle inputs which are advected using currents from a hydrodynamic model to map the spatial distribution of plastic debris in the Great Lakes. Model results compare favorably with previously published sampling data. The samples are used to calibrate the model to derive surface microplastic mass estimates of 0.0211 metric tonnes in Lake Superior, 1.44 metric tonnes in Huron, and 4.41 metric tonnes in Erie. These results have many applications, including informing cleanup efforts, helping target pollution prevention, and understanding the inter-state or international flows of plastic pollution.

  2. Modeling Collisional Cascades in Debris Disks: The Numerical Method

    NASA Astrophysics Data System (ADS)

    Gáspár, András; Psaltis, Dimitrios; Özel, Feryal; Rieke, George H.; Cooney, Alan

    2012-04-01

    We develop a new numerical algorithm to model collisional cascades in debris disks. Because of the large dynamical range in particle masses, we solve the integro-differential equations describing erosive and catastrophic collisions in a particle-in-a-box approach, while treating the orbital dynamics of the particles in an approximate fashion. We employ a new scheme for describing erosive (cratering) collisions that yields a continuous set of outcomes as a function of colliding masses. We demonstrate the stability and convergence characteristics of our algorithm and compare it with other treatments. We show that incorporating the effects of erosive collisions results in a decay of the particle distribution that is significantly faster than with purely catastrophic collisions.

  3. MODELING COLLISIONAL CASCADES IN DEBRIS DISKS: THE NUMERICAL METHOD

    SciTech Connect

    Gaspar, Andras; Psaltis, Dimitrios; Oezel, Feryal; Rieke, George H.; Cooney, Alan E-mail: dpsaltis@as.arizona.edu E-mail: grieke@as.arizona.edu

    2012-04-10

    We develop a new numerical algorithm to model collisional cascades in debris disks. Because of the large dynamical range in particle masses, we solve the integro-differential equations describing erosive and catastrophic collisions in a particle-in-a-box approach, while treating the orbital dynamics of the particles in an approximate fashion. We employ a new scheme for describing erosive (cratering) collisions that yields a continuous set of outcomes as a function of colliding masses. We demonstrate the stability and convergence characteristics of our algorithm and compare it with other treatments. We show that incorporating the effects of erosive collisions results in a decay of the particle distribution that is significantly faster than with purely catastrophic collisions.

  4. Characterizing Dusty Debris Disks with the Gemini Planet Imager

    NASA Astrophysics Data System (ADS)

    Chen, Christine; Arriaga, Pauline; Bruzzone, Sebastian; Choquet, Elodie; Debes, John H.; Donaldson, Jessica; Draper, Zachary; Duchene, Gaspard; Esposito, Thomas; Fitzgerald, Michael P.; Golimowski, David A.; Hines, Dean C.; Hinkley, Sasha; Hughes, A. Meredith; Kalas, Paul; Kolokolova, Ludmilla; Lawler, Samantha; Matthews, Brenda C.; Mazoyer, Johan; Metchev, Stanimir A.; Millar-Blanchaer, Max; Moro-Martin, Amaya; Nesvold, Erika; Padgett, Deborah; Patience, Jenny; Perrin, Marshall D.; Pueyo, Laurent; Rantakyro, Fredrik; Rodigas, Timothy; Schneider, Glenn; Soummer, Remi; Song, Inseok; Stark, Chris; Weinberger, Alycia J.; Wilner, David J.

    2017-01-01

    We have been awarded 87 hours of Gemini Observatory time to obtain multi-wavelength observations of HST resolved debris disks using the Gemini Planet Imager. We have executed ~51 hours of telescope time during the 2015B-2016B semesters observing 12 nearby, young debris disks. We have been using the GPI Spec and Pol modes to better constrain the properties of the circumstellar dust, specifically, measuring the near-infrared total intensity and polarization fraction colors, and searching for solid-state spectral features of nearby beta Pic-like disks. We expect that our observations will allow us to break the degeneracy among the particle properties such as composition, size, porosity, and shape. We present some early results from our observations.

  5. Debris Flow Distributed Propagation Model

    NASA Astrophysics Data System (ADS)

    Gregoretti, C.

    The debris flow distributed propagation model is a DEM-based model. The fan is dis- cretized by square cells and each cell is assigned an altitude on the sea level. The cells of the catchment are distinguished in two categories: the source cells and the stripe cells. The source cells receive the input hydograph: the cells close to the torrent which are flooded by the debris flow overflowing the torrent embankment are source cells. The stripes cells are the cells flooded by debris flow coming from the surrounding cells. At the first time step only the source cells are flooded by debris flow coming from the torrent. At the second time step a certain number of cells are flooded by de- bris flow coming from the source cells. These cells constitute a stripe of cells and are assigned order two. At the third time step another group of cells are flooded by the debris flow coming from the cells whose order is two. These cells constitute another stripe and are assigned order three. The cell order of a stripe is the time step number corresponding to the transition from dry to flooded state. The mass transfer or mo- mentum exchange between cells is governed by two different mechanisms. The mass transfer is allowed only by a positive or equal to zero flow level difference between the drained cell and the receiving cell. The mass transfer is limited by a not negative final flow level difference between the drained cell and the receiving cells. This limitation excludes the case of possible oscillations in the mass transfer. Another limitation is that the mass drained by a cell should be less than the available mass in that cell. This last condition provides the respect of mass conservation. The first mechanism of mass transfer is the gravity. The mass in a cell is transferred to the neighbouring cells with lower altitude and flow level according to an uniform flow law: The second mecha- nism of mass transfer is the broad crested weir. The mass in a cell is transferred to the

  6. A Single Step Lapping and Polishing Process for Achieving Surfaces of Compound Semiconductors with Atomic Flatness using a Sub-micron Agglomerate-free Alumina Slurry

    SciTech Connect

    P.S. Dutta; G. Rajagopalan; J.J. Gutmann; D. Keller; L. Sweet

    2002-08-29

    A novel approach for a single step lapping and final polishing of III-V and II-VI compounds using agglomerate-free alumina slurries has been developed. The agglomerate-free nature of the sub-micron slurry leads to removal rates comparable to conventional slurries (with larger particles of tens of microns) used for semiconductor lapping. Surfaces with minimal surface damage and extremely low surface roughness have been obtained using the sub-micron slurries and a soft pad. Strategies for post polishing surface cleaning have been discussed. The new methodology has been experimented on GaSb, InAs, GaAs, InP, InSb, CdTe, GaInSb, GaInAs, AlGaAsSb, GaInAsSb and HgCdTe. Selected results of surface analyses of GaSb and GaInSb using atomic force microscopy will be presented.

  7. The New NASA Orbital Debris Engineering Model ORDEM 3.0

    NASA Technical Reports Server (NTRS)

    Krisko, P. H.

    2014-01-01

    The NASA Orbital Debris Program Office (ODPO) has released its latest Orbital Debris Engineering Model, ORDEM 3.0. It supersedes ORDEM 2.0. This newer model encompasses the Earth satellite and debris flux environment from altitudes of low Earth orbit (LEO) through geosynchronous orbit (GEO). Debris sizes of 10 microns through 1 m in non-GEO and 10 cm through 1 m in GEO are modeled. The inclusive years are 2010 through 2035. The ORDEM model series has always been data driven. ORDEM 3.0 has the benefit of many more hours from existing data sources and from new sources that weren't available to past versions. Returned surfaces, ground tests, and remote sensors all contribute data. The returned surface and ground test data reveal material characteristics of small particles. Densities of fragmentation debris particles smaller than 10 cm are grouped in ORDEM 3.0 in terms of high-, medium-, and lowdensities, along with RORSAT sodium-potassium droplets. Supporting models have advanced significantly. The LEO-to-GEO ENvironment Debris model (LEGEND) includes an historical and a future projection component with yearly populations that include launched and maneuvered intacts, mission related debris (MRD), and explosion and col