Comparison of stationary and personal air sampling with an ...

EPA Pesticide Factsheets

Manganese (Mn) is ubiquitous in the environment and essential for normal growth and development, yet excessive exposure can lead to impairments in neurological function. This study modeled ambient Mn concentrations as an alternative to stationary and personal air sampling to assess exposure for children enrolled in the Communities Actively Researching Exposure Study in Marietta, OH. Ambient air Mn concentration values were modeled using US Environmental Protection Agency’s Air Dispersion Model AERMOD based on emissions from the ferromanganese refinery located in Marietta. Modeled Mn concentrations were compared with Mn concentrations from a nearby stationary air monitor. The Index of Agreement for modeled versus monitored data was 0.34 (48 h levels) and 0.79 (monthly levels). Fractional bias was 0.026 for 48 h levels and −0.019 for monthly levels. The ratio of modeled ambient air Mn to measured ambient air Mn at the annual time scale was 0.94. Modeled values were also time matched to personal air samples for 19 children. The modeled values explained a greater degree of variability in personal exposures compared with time-weighted distance from the emission source. Based on these results modeled Mn concentrations provided a suitable approach for assessing airborne Mn exposure in this cohort. The purpose of the study was to investigate the use of air-dispersion modeling as an approach to exposure assessment for ambient manganese.

AIR EMISSIONS FROM COMBUSTION OF SOLVENT REFINED COAL

EPA Science Inventory

The report gives details of a Solvent Refined Coal (SRC) combustion test at Georgia Power Company's Plant Mitchell, March, May, and June 1977. Flue gas samples were collected for modified EPA Level 1 analysis; analytical results are reported. Air emissions from the combustion of ...

Pacific Northwest National Laboratory Potential Impact Categories for Radiological Air Emission Monitoring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ballinger, Marcel Y.; Gervais, Todd L.; Barnett, J. Matthew

2012-06-05

In 2002, the EPA amended 40 CFR 61 Subpart H and 40 CFR 61 Appendix B Method 114 to include requirements from ANSI/HPS N13.1-1999 Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities for major emission points. Additionally, the WDOH amended the Washington Administrative Code (WAC) 246-247 Radiation protection-air emissions to include ANSI/HPS N13.1-1999 requirements for major and minor emission points when new permitting actions are approved. A result of the amended regulations is the requirement to prepare a written technical basis for the radiological air emission sampling and monitoring program. A keymore » component of the technical basis is the Potential Impact Category (PIC) assigned to an emission point. This paper discusses the PIC assignments for the Pacific Northwest National Laboratory (PNNL) Integrated Laboratory emission units; this revision includes five PIC categories.« less

Managing Air Quality - Emissions Inventories

EPA Pesticide Factsheets

This page describes the role of emission inventories in the air quality management process, a description of how emission inventories are developed, and where U.S. emission inventory information can be found.

Impact of air velocity, temperature, humidity, and air on long-term voc emissions from building products

NASA Astrophysics Data System (ADS)

Wolkoff, Peder

The emissions of two volatile organic compounds (VOCs) of concern from five building products (BPs) were measured in the field and laboratory emission cell (FLEC) up to 250 d. The BPs (VOCs selected on the basis of abundance and low human odor thresholds) were: nylon carpet with latex backing (2-ethylhexanol, 4-phenylcyclohexene), PVC flooring (2-ethylhexanol, phenol), floor varnish on pretreated beechwood parquet (butyl acetate, N-methylpyrrolidone), sealant (hexane, dimethyloctanols), and waterborne wall paint on gypsum board (1,2-propandiol, Texanol). Ten different climate conditions were tested: four different air velocities from ca. 1 cm s -1 to ca. 9 cm s -1, three different temperatures (23, 35, and 60°C), two different relative humidities (0% and 50% RH), and pure nitrogen instead of clean air supply. Additionally, two sample specimen and two different batches were compared for repeatability and homogeneity. The VOCs were sampled on Tenax TA and determined by thermal desorption and gas chromatography (FID). Quantification was carried out by individual calibration of each VOC of concern. Concentration/time profiles of the selected VOCs (i.e. their concentration decay curves over time) in a standard room were used for comparison. Primary source emissions were not affected by the air velocity after a few days to any great extent. Both the temperature and relative humidity affected the emission rates, but depended strongly on the type of BP and type of VOC. Secondary (oxidative) source emissions were only observed for the PVC and for dimethyloctanols from the sealant. The time to reach a given concentration (emission rate) appears to be a good approach for future interlaboratory comparisons of BP's VOC emissions.

Air Emissions Inventories

EPA Pesticide Factsheets

This site provides access to emissions data, regulations and guidance, electronic system access, resources and tools to support trends analysis, regional, and local scale air quality modeling, regulatory impact assessments.

77 FR 16508 - National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-21

... National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins; Pesticide... Hazardous Air Pollutant Emissions: Group IV Polymers and Resins; National Emission Standards for Hazardous... proposed rule titled, National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers...

Forced-air warming design: evaluation of intake filtration, internal microbial buildup, and airborne-contamination emissions.

PubMed

Reed, Mike; Kimberger, Oliver; McGovern, Paul D; Albrecht, Mark C

2013-08-01

Forced-air warming devices are effective for the prevention of surgical hypothermia. However, these devices intake nonsterile floor-level air, and it is unknown whether they have adequate filtration measures to prevent the internal buildup or emission of microbial contaminants. We rated the intake filtration efficiency of a popular current-generation forced-air warming device (Bair Hugger model 750, Arizant Healthcare) using a monodisperse sodium chloride aerosol in the laboratory. We further sampled 23 forced-air warming devices (same model) in daily hospital use for internal microbial buildup and airborne-contamination emissions via swabbing and particle counting. Laboratory testing found the intake filter to be 63.8% efficient. Swabbing detected microorganisms within 100% of the forced-air warming blowers sampled, with isolates of coagulase-negative staphylococci, mold, and micrococci identified. Particle counting showed 96% of forced-air warming blowers to be emitting significant levels of internally generated airborne contaminants out of the hose end. These findings highlight the need for upgraded intake filtration, preferably high-efficiency particulate air filtration (99.97% efficient), on current-generation forced-air warming devices to reduce contamination buildup and emission risks.

Constraining Microwave Emission from Extensive Air Showers via the MIDAS Experiment

NASA Astrophysics Data System (ADS)

Richardson, Matthew; Privitera, Paolo

2017-01-01

Ultra high energy cosmic rays (UHECRs) are accelerated by the most energetic processes in the universe. Upon entering Earth’s atmosphere they produce particle showers known as extensive air showers (EASs). Observatories like the Pierre Auger Observatory sample the particles and light produced by the EASs through large particle detector arrays or nitrogen fluorescence detectors to ascertain the fundamental properties of UHECRs. The large sample of high quality data provided by the Pierre Auger Observatory can be attributed to the hybrid technique which utilizes the two aforementioned techniques simultaneously; however, the limitation of only being able to observe nitrogen fluorescence from EASs on clear moonless nights yields a limited 10% duty cycle for the hybrid technique. One proposal for providing high quality data at increased statistics is the observation of isotropic microwave emission from EASs, as such emission would be observed with a 100% duty cycle. Measurements of microwave emission from laboratory air plasmas conducted by Gorham et al. (2008) produced promising results indicating that the microwave emission should be observable using inexpensive detectors. The Microwave Detection of Air Showers (MIDAS) experiment was built at the University of Chicago to characterize the isotropic microwave emission from EASs and has collected 359 days of observational data at the location of the Pierre Auger experiment. We have performed a time coincidence analysis between this data and data from Pierre Auger and we report a null result. This result places stringent limits on microwave emission from EASs and demonstrates that the laboratory measurements of Gorham et al. (2008) are not applicable to EASs, thus diminishing the feasibility of using isotropic microwave emission to detect EASs.

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Sampling and analytical procedures for measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 87.64 Section 87.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Sampling and analytical procedures for measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 87.64 Section 87.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

Impacts of Lowered Urban Air Temperatures on Precursor Emission and Ozone Air Quality.

PubMed

Taha, Haider; Konopacki, Steven; Akbari, Hashem

1998-09-01

Meteorological, photochemical, building-energy, and power plant simulations were performed to assess the possible precursor emission and ozone air quality impacts of decreased air temperatures that could result from implementing the "cool communities" concept in California's South Coast Air Basin (SoCAB). Two pathways are considered. In the direct pathway, a reduction in cooling energy use translates into reduced demand for generation capacity and, thus, reduced precursor emissions from electric utility power plants. In the indirect pathway, reduced air temperatures can slow the atmospheric production of ozone as well as precursor emission from anthropogenic and biogenic sources. The simulations suggest small impacts on emissions following implementation of cool communities in the SoCAB. In summer, for example, there can be reductions of up to 3% in NO x emissions from in-basin power plants. The photochemical simulations suggest that the air quality impacts of these direct emission reductions are small. However, the indirect atmospheric effects of cool communities can be significant. For example, ozone peak concentrations can decrease by up to 11% in summer and population-weighted exceedance exposure to ozone above the California and National Ambient Air Quality Standards can decrease by up to 11 and 17%, respectively. The modeling suggests that if these strategies are combined with others, such as mobile-source emission control, the improvements in ozone air quality can be substantial.

The national air pollutant emission trends, 1900-1998

DOT National Transportation Integrated Search

2000-03-01

The National Air Pollutant Emission Trends Report, 1900-1998 presents the most : recent estimate of national emissions of the criteria air pollutants. The : emissions of each pollutant are estimated for many different source categories, : which colle...

Quantification of variability and uncertainty for air toxic emission inventories with censored emission factor data.

PubMed

Frey, H Christopher; Zhao, Yuchao

2004-11-15

Probabilistic emission inventories were developed for urban air toxic emissions of benzene, formaldehyde, chromium, and arsenic for the example of Houston. Variability and uncertainty in emission factors were quantified for 71-97% of total emissions, depending upon the pollutant and data availability. Parametric distributions for interunit variability were fit using maximum likelihood estimation (MLE), and uncertainty in mean emission factors was estimated using parametric bootstrap simulation. For data sets containing one or more nondetected values, empirical bootstrap simulation was used to randomly sample detection limits for nondetected values and observations for sample values, and parametric distributions for variability were fit using MLE estimators for censored data. The goodness-of-fit for censored data was evaluated by comparison of cumulative distributions of bootstrap confidence intervals and empirical data. The emission inventory 95% uncertainty ranges are as small as -25% to +42% for chromium to as large as -75% to +224% for arsenic with correlated surrogates. Uncertainty was dominated by only a few source categories. Recommendations are made for future improvements to the analysis.

Air Contamination by Mercury, Emissions and Transformations-a Review.

PubMed

Gworek, Barbara; Dmuchowski, Wojciech; Baczewska, Aneta H; Brągoszewska, Paulina; Bemowska-Kałabun, Olga; Wrzosek-Jakubowska, Justyna

2017-01-01

The present and future air contamination by mercury is and will continue to be a serious risk for human health. This publication presents a review of the literature dealing with the issues related to air contamination by mercury and its transformations as well as its natural and anthropogenic emissions. The assessment of mercury emissions into the air poses serious methodological problems. It is particularly difficult to distinguish between natural and anthropogenic emissions and re-emissions from lands and oceans, including past emissions. At present, the largest emission sources include fuel combustion, mainly that of coal, and "artisanal and small-scale gold mining" (ASGM). The distinctly highest emissions can be found in South and South-East Asia, accounting for 45% of the global emissions. The emissions of natural origin and re-emissions are estimated at 45-66% of the global emissions, with the largest part of emissions originating in the oceans. Forecasts on the future emission levels are not unambiguous; however, most forecasts do not provide for reductions in emissions. Ninety-five percent of mercury occurring in the air is Hg 0 -GEM, and its residence time in the air is estimated at 6 to 18 months. The residence times of its Hg II -GOM and that in Hg p -TPM are estimated at hours and days. The highest mercury concentrations in the air can be found in the areas of mercury mines and those of ASGM. Since 1980 when it reached its maximum, the global background mercury concentration in the air has remained at a relatively constant level.

Autonomous mobile platform for monitoring air emissions from industrial and municipal wastewater ponds.

PubMed

Fu, Long; Huda, Quamrul; Yang, Zheng; Zhang, Lucas; Hashisho, Zaher

2017-11-01

Significant amounts of volatile organic compounds and greenhouse gases are generated from wastewater lagoons and tailings ponds in Alberta, Canada. Accurate measurements of these air pollutants and greenhouse gases are needed to support management and regulatory decisions. A mobile platform was developed to measure air emissions from tailings pond in the oil sands region of Alberta. The mobile platform was tested in 2015 in a municipal wastewater treatment lagoon. With a flux chamber and a CO 2 /CH 4 sensor on board, the mobile platform was able to measure CO 2 and CH 4 emissions over two days at two different locations in the pond. Flux emission rates of CO 2 and CH 4 that were measured over the study period suggest the presence of aerobic and anaerobic zones in the wastewater treatment lagoon. The study demonstrated the capabilities of the mobile platform in measuring fugitive air emissions and identified the potential for the applications in air and water quality monitoring programs. The Mobile Platform demonstrated in this study has the ability to measure greenhouse gas (GHG) emissions from fugitive sources such as municipal wastewater lagoons. This technology can be used to measure emission fluxes from tailings ponds with better detection of spatial and temporal variations of fugitive emissions. Additional air and water sampling equipment could be added to the mobile platform for a broad range of air and water quality studies in the oil sands region of Alberta.

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Dilution air background emission...

[Study on emission standard system of air pollutants].

PubMed

Jiang, Mei; Zhang, Guo-Ning; Zhang, Ming-Hui; Zou, Lan; Wei, Yu-Xia; Ren, Chun

2012-12-01

Scientific and reasonable emission standard system of air pollutants helps to systematically control air pollution, enhance the protection of the atmospheric environment effect and improve the overall atmospheric environment quality. Based on the study of development, situation and characteristics of national air pollutants emission standard system, the deficiencies of system were pointed out, which were not supportive, harmonious and perfect, and the improvement measures of emission standard system were suggested.

40 CFR 265.231 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator shall...

40 CFR 264.232 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all hazardous...

40 CFR 265.178 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner or...

40 CFR 265.231 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator shall...

40 CFR 265.178 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner or...

40 CFR 264.232 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all hazardous...

40 CFR 265.231 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator shall...

40 CFR 265.178 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner or...

40 CFR 264.232 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all hazardous...

40 CFR 265.178 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner or...

40 CFR 264.232 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all hazardous...

40 CFR 265.231 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator shall...

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) Definitions. Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 87.82 Sampling and analytical procedures for measuring smoke exhaust...

Verifying mixing in dilution tunnels How to ensure cookstove emissions samples are unbiased

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, Daniel L.; Rapp, Vi H.; Caubel, Julien J.

A well-mixed diluted sample is essential for unbiased measurement of cookstove emissions. Most cookstove testing labs employ a dilution tunnel, also referred to as a “duct,” to mix clean dilution air with cookstove emissions before sampling. It is important that the emissions be well-mixed and unbiased at the sampling port so that instruments can take representative samples of the emission plume. Some groups have employed mixing baffles to ensure the gaseous and aerosol emissions from cookstoves are well-mixed before reaching the sampling location [2, 4]. The goal of these baffles is to to dilute and mix the emissions stream withmore » the room air entering the fume hood by creating a local zone of high turbulence. However, potential drawbacks of mixing baffles include increased flow resistance (larger blowers needed for the same exhaust flow), nuisance cleaning of baffles as soot collects, and, importantly, the potential for loss of PM2.5 particles on the baffles themselves, thus biasing results. A cookstove emission monitoring system with baffles will collect particles faster than the duct’s walls alone. This is mostly driven by the available surface area for deposition by processes of Brownian diffusion (through the boundary layer) and turbophoresis (i.e. impaction). The greater the surface area available for diffusive and advection-driven deposition to occur, the greater the particle loss will be at the sampling port. As a layer of larger particle “fuzz” builds on the mixing baffles, even greater PM2.5 loss could occur. The micro structure of the deposited aerosol will lead to increased rates of particle loss by interception and a tendency for smaller particles to deposit due to impaction on small features of the micro structure. If the flow stream could be well-mixed without the need for baffles, these drawbacks could be avoided and the cookstove emissions sampling system would be more robust.« less

Air pollution response to changing weather and power plant emissions in the eastern United States

NASA Astrophysics Data System (ADS)

Bloomer, Bryan Jaye

Air pollution in the eastern United States causes human sickness and death as well as damage to crops and materials. NOX emission reduction is observed to improve air quality. Effectively reducing pollution in the future requires understanding the connections between smog, precursor emissions, weather, and climate change. Numerical models predict global warming will exacerbate smog over the next 50 years. My analysis of 21 years of CASTNET observations quantifies a climate change penalty. I calculate, for data collected prior to 2002, a climate penalty factor of ˜3.3 ppb O3/°C across the power plant dominated receptor regions in the rural, eastern U.S. Recent reductions in NOX emissions decreased the climate penalty factor to ˜2.2 ppb O3/°C. Prior to 1995, power plant emissions of CO2, SO2, and NOX were estimated with fuel sampling and analysis methods. Currently, emissions are measured with continuous monitoring equipment (CEMS) installed directly in stacks. My comparison of the two methods show CO 2 and SO2 emissions are ˜5% lower when inferred from fuel sampling; greater differences are found for NOX emissions. CEMS are the method of choice for emission inventories and commodity trading and should be the standard against which other methods are evaluated for global greenhouse gas trading policies. I used CEMS data and applied chemistry transport modeling to evaluate improvements in air quality observed by aircraft during the North American electrical blackout of 2003. An air quality model produced substantial reductions in O3, but not as much as observed. The study highlights weaknesses in the model as commonly used for evaluating a single day event and suggests areas for further investigation. A new analysis and visualization method quantifies local-daily to hemispheric-seasonal scale relationships between weather and air pollution, confirming improved air quality despite increasing temperatures across the eastern U.S. Climate penalty factors indicate

40 CFR 264.179 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall manage...

40 CFR 265.202 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage all...

40 CFR 264.179 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall manage...

40 CFR 264.200 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous waste...

40 CFR 265.202 - Air emission standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage all...

40 CFR 264.200 - Air emission standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous waste...

40 CFR 265.202 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage all...

40 CFR 264.200 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous waste...

40 CFR 265.202 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage all...

40 CFR 264.179 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall manage...

40 CFR 264.200 - Air emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous waste...

40 CFR 264.179 - Air emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall manage...

Fuel/air nonuniformity - Effect on nitric oxide emissions

NASA Technical Reports Server (NTRS)

Lyons, V. J.

1981-01-01

An analytical and experimental study was performed to determine the effect of inlet fuel/air profile nonuniformity on NO(x) emissions. The theoretical NO(x) levels were verified in a flame-tube rig at inlet air temperatures of 600, 700, and 800 K, 0.3 MPa rig pressure, 25 m/sec reference velocity, overall equivalence ratio of 0.6 and residence time near 0.002 sec. The theory predicts an increase in NO(x) emissions for increased fuel/air nonuniformity for average equivalence ratios less than 0.7, while for average equivalence ratios near stoichiometric, increasing the nonuniformity will decrease NO(x) emissions. The results can be used to predict the degree of uniformity of fuel/air profiles necessary to achieve NO(x) emissions goals for actual engines that use lean premixed, prevaporized combustion systems.

Emission of atmospheric pollutants out of Africa - Analysis of CARIBIC aircraft air samples

NASA Astrophysics Data System (ADS)

Thorenz, Ute R.; Baker, Angela K.; Schuck, Tanja; van Velthoven, Peter F. J.; Ziereis, Helmut; Brenninkmeijer, Carl A. M.

2014-05-01

Africa is the single largest continental source of biomass burning (BB) emissions. The burning African savannas and tropical forests are a source for a wide range of chemical species, which are important for global atmospheric chemistry, especially for the pristine Southern Hemisphere. Emitted compounds include carbon monoxide (CO), nitrogen oxides (NOx), hydrocarbons, oxygenated hydrocarbons and particles. Deep convection over Central Africa transports boundary layer emissions to the free troposphere making aircraft-based observations useful for investigation of surface emissions and examination of transport and chemistry processes over Africa The CARIBIC project (Civil Aircraft for the Regular Investigation of the Atmosphere Based on an Instrument Container, www.caribic-atmosphere.com part of IAGOS www.iagos.org) is a long term atmospheric measurement program using an instrument container deployed aboard a Lufthansa Airbus A340-600 for a monthly sequence of long-distance passenger flights. Besides the online measurements mixing ratios of greenhouse gases and a suite of C2-C8 non methane hydrocarbons (NMHCs) are measured from flask samples collected at cruise altitude. During northern hemispheric winter 2010/2011 CARIBIC flights took place from Frankfurt to Cape Town and Johannesburg in South Africa. Several BB tracers like methane, CO and various NMHCs were found to be elevated over tropical Africa. Using tracer-CO- and tracer-NOy-correlations emissions were characterized. The NMHC-CO correlations show monthly changing slopes, indicating a change in burned biomass, major fire stage, source region and/or other factors influencing NMHC emissions. To expand our analysis of emission sources a source region data filter was used, based on backward trajectories calculated along the flight tracks. Taking all CARIBIC samples into account having backward trajectories to the African boundary layer the dataset was enlarged from 77 to 168 samples. For both datasets tracer

Comparison of VOC emissions between air-dried and heat-treated Norway spruce ( Picea abies), Scots pine ( Pinus sylvesteris) and European aspen ( Populus tremula) wood

NASA Astrophysics Data System (ADS)

Hyttinen, Marko; Masalin-Weijo, Marika; Kalliokoski, Pentti; Pasanen, Pertti

2010-12-01

Heat-treated wood is an increasingly popular decoration material. Heat-treatment improves dimensional stability of the wood and also prevents rot fungus growth. Although production of heat-treated wood has been rapidly increasing, there is only little information about the VOC emissions of heat-treated wood and its possible influences on indoor air quality. In the present study, VOC emissions from three untreated (air-dried) and heat-treated wood species were compared during a four weeks test period. It appeared that different wood species had clearly different VOC emission profiles. Heat-treatment was found to decrease VOC emissions significantly and change their composition. Especially, emissions of terpenes decreased from softwood samples and aldehydes from European aspen samples. Emissions of total aldehydes and organic acids were at the same level or slightly higher from heat treated than air-dried softwood samples. In agreement with another recent study, the emissions of furfural were found to increase and those of hexanal to decrease from all the wood species investigated. In contrast to air-dried wood samples, emissions of VOCs were almost in steady state from heat treated wood samples even in the beginning of the test.

76 FR 22565 - National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-21

... National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins; Marine Tank...-AO91 National Emission Standards for Hazardous Air Pollutant Emissions: Group I Polymers and Resins... Emissions Standards for Group I Polymers and Resins (Butyl Rubber Production, Epichlorohydrin Elastomers...

Maximizing sinter plant operating flexibility through emissions trading and air modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schewe, G.J.; Wagner, J.A.; Heron, T.

1998-12-31

This paper provides details on the dispersion modeling analysis performed to demonstrate air quality impacts associated with an emission trading scheme for a sintering operation in Youngstown, Ohio. The emission trade was proposed to allow the sinter plant to expand its current allowable sulfur dioxide (SO2) emissions while being offset with SO{sub 2} emissions from boilers at a nearby shutdown steel mill. While the emission trade itself was feasible and the emissions required for the offset were available (the boiler shutdown and their subsequent SO{sub 2} emission credits were never claimed, banked, or used elsewhere), the second criteria for determiningmore » compliance was a demonstration of minimal air quality impact. The air analysis combined the increased ambient SO{sub 2} concentrations of the relaxed sinter plant emissions with the offsetting air quality of the shutdown boilers to yield the net air quality impacts. To test this net air impact, dispersion modeling was performed treating the sinter plant SO{sub 2} emissions as positive and the shutdown boiler SO{sub 2} emissions as negative. The results of the modeling indicated that the ambient air concentrations due to the proposed emissions increase will be offset by the nearby boiler emissions to levels acceptable under EPA`s offset policy Level 2 significant impact concentrations. Therefore, the dispersion modeling demonstrated that the emission trading scheme would not result in significant air quality impacts and maximum operating flexibility was provided to the sintering facility.« less

Aerostat-lofted instrument and sampling method for determination of emissions from open area sources

EPA Science Inventory

An aerostat-borne instrument and sampling method was developed to characterize air samples from area sources, such as emissions from open burning. The 10 kg battery-powered instrument system, termed "the Flyer," is lofted with a helium-filled aerostat of 4 m nominal diameter and ...

Noise Emission from Laboratory Air Blowers

ERIC Educational Resources Information Center

Rossing, Thomas D.; Windham, Betty

1978-01-01

Product noise ratings for a number of laboratory air blowers are reported and several recommendations for reducing laboratory noise from air blowers are given. Relevant noise ratings and methods for measuring noise emission of appliances are discussed. (BB)

Working Toward Policy-Relevant Air Quality Emissions Scenarios

NASA Astrophysics Data System (ADS)

Holloway, T.

2010-12-01

Though much work has been done to develop accurate chemical emission inventories, few publicly available inventories are appropriate for realistic policy analysis. Emissions from the electricity and transportation sectors, in particular, respond in complex ways to policy, technology, and energy use change. Many widely used inventories, such as the EPA National Emissions Inventory, are well-suited for modeling current air quality, but do not have the specificity needed to address "what if?" questions. Changes in electricity demand, fuel prices, new power sources, and emission controls all influence the emissions from regional power production, requiring a plant-by-plant assessment to capture the spatially explicit impacts. Similarly, land use, freight distribution, or driving behavior will yield differentiated transportation emissions for urban areas, suburbs, and rural highways. We here present results from three recent research projects at the University of Wisconsin—Madison, where bottom-up emission inventories for electricity, freight transport, and urban vehicle use were constructed to support policy-relevant air quality research. These three studies include: 1) Using the MyPower electricity dispatch model to calculate emissions and air quality impacts of Renewable Portfolio Standards and other carbon-management strategies; 2) Using advanced vehicle and commodity flow data from the Federal Highway Administration to evaluate the potential to shift commodities from truck to rail (assuming expanded infrastructure), and assess a range of alternative fuel suggestions; and 3) Working with urban planners to connect urban density with vehicle use to evaluate the air quality impacts of smart-growth in major Midwest cities. Drawing on the results of these three studies, and on challenges overcome in their execution, we discuss the current state of policy-relevant emission dataset generation, as well as techniques and attributes that need to be further refined in order

National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions, Calendar Year 2010

DOE Office of Scientific and Technical Information (OSTI.GOV)

NSTec Ecological and Environmental Monitoring

2011-06-30

NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations (U.S. Environmental Protection Agency [EPA] and DOE, 1995). This method was approved by the EPA for use on the NNSS in 2001(EPA, 2001a) and has been the sole method used since 2005. Six locations on the NNSS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo-critical receptor stations, because no member of the public actually resides at these onsite locations. Compliance is demonstrated if the measured annual average concentration is less than the NESHAP Concentration Levels (CLs) for Environmental Compliance listed in 40 CFR 61, Appendix E, Table 2 (CFR, 2010a). For multiple radionuclides, compliance is demonstrated when the sum of the fractions (determined by dividing each radionuclide's concentration by its CL and then adding the fractions together) is less than 1.0. In 2010, the potential dose from radiological emissions to air, resulting from both current and past NNSS activities, at onsite compliance monitoring stations was well below the 10 mrem/yr dose limit. Air sampling data collected at all air monitoring stations had average concentrations of radioactivity that were a fraction of the CL values. Concentrations ranged from less than 1 percent to a maximum of 17 percent of the allowed NESHAP limit. Because the nearest member of the public resides about 20 kilometers from potential release points on the NNSS, dose to the public would be only a small fraction of that measured on the NNSS. The potential dose to the public from NLVF emissions was also very low at 0.000032 mrem/yr, more than 300,000 times lower than the 10 mrem/yr limit.« less

Emission factors of air toxics from semiconductor manufacturing in Korea.

PubMed

Eom, Yun-Sung; Hong, Ji-Hyung; Lee, Suk-Jo; Lee, Eun-Jung; Cha, Jun-Seok; Lee, Dae-Gyun; Bang, Sun-Ae

2006-11-01

The development of local, accurate emission factors is very important for the estimation of reliable national emissions and air quality management. For that, this study is performed for pollutants released to the atmosphere with source-specific emission tests from the semiconductor manufacturing industry. The semiconductor manufacturing industry is one of the major sources of air toxics or hazardous air pollutants (HAPs); thus, understanding the emission characteristics of the emission source is a very important factor in the development of a control strategy. However, in Korea, there is a general lack of information available on air emissions from the semiconductor industry. The major emission sources of air toxics examined from the semiconductor manufacturing industry were wet chemical stations, coating applications, gaseous operations, photolithography, and miscellaneous devices in the wafer fabrication and semiconductor packaging processes. In this study, analyses of emission characteristics, and the estimations of emission data and factors for air toxics, such as acids, bases, heavy metals, and volatile organic compounds from the semiconductor manufacturing process have been performed. The concentration of hydrogen chloride from the packaging process was the highest among all of the processes. In addition, the emission factor of total volatile organic compounds (TVOCs) for the packaging process was higher than that of the wafer fabrication process. Emission factors estimated in this study were compared with those of Taiwan for evaluation, and they were found to be of similar level in the case of TVOCs and fluorine compounds.

76 FR 72049 - National Emission Standards for Hazardous Air Pollutant Emissions for Shipbuilding and Ship...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-21

...This action finalizes the residual risk and technology review conducted for two industrial source categories regulated by separate national emission standards for hazardous air pollutants. The two national emission standards for hazardous air pollutants are: National Emissions Standards for Shipbuilding and Ship Repair (Surface Coating) and National Emissions Standards for Wood Furniture Manufacturing Operations. This action also finalizes revisions to the regulatory provisions related to emissions during periods of startup, shutdown and malfunction.

Estimating air chemical emissions from research activities using stack measurement data.

PubMed

Ballinger, Marcel Y; Duchsherer, Cheryl J; Woodruff, Rodger K; Larson, Timothy V

2013-03-01

Current methods of estimating air emissions from research and development (R&D) activities use a wide range of release fractions or emission factors with bases ranging from empirical to semi-empirical. Although considered conservative, the uncertainties and confidence levels of the existing methods have not been reported. Chemical emissions were estimated from sampling data taken from four research facilities over 10 years. The approach was to use a Monte Carlo technique to create distributions of annual emission estimates for target compounds detected in source test samples. Distributions were created for each year and building sampled for compounds with sufficient detection frequency to qualify for the analysis. The results using the Monte Carlo technique without applying a filter to remove negative emission values showed almost all distributions spanning zero, and 40% of the distributions having a negative mean. This indicates that emissions are so low as to be indistinguishable from building background. Application of a filter to allow only positive values in the distribution provided a more realistic value for emissions and increased the distribution mean by an average of 16%. Release fractions were calculated by dividing the emission estimates by a building chemical inventory quantity. Two variations were used for this quantity: chemical usage, and chemical usage plus one-half standing inventory. Filters were applied so that only release fraction values from zero to one were included in the resulting distributions. Release fractions had a wide range among chemicals and among data sets for different buildings and/or years for a given chemical. Regressions of release fractions to molecular weight and vapor pressure showed weak correlations. Similarly, regressions of mean emissions to chemical usage, chemical inventory, molecular weight, and vapor pressure also gave weak correlations. These results highlight the difficulties in estimating emissions from R

Propane and butane emission sources to ambient air of Mexico City metropolitan area.

PubMed

Jaimes, L; Sandoval, J

2002-04-22

Samples of volatile organic compounds (VOCs) were collected in a smog chamber in order to determine whether automotive exhausts or LP Gas emissions play a greater role in the source of propane and butane, which affect ozone formation and other pollutants in the ambient air of the Mexico City metropolitan area (MCMA). These samples were collected in April 1995 during mornings and evenings. The testing methodology used for measuring exhaust emission were FTP or EPA-74 tests, and SHED type tests were also conducted in order to evaluate evaporative emissions. The finding from analysis of the VOCs collected in the morning demonstrate that in the atmosphere, propane concentrations are higher than that of butane but the reverse in evaporative and exhaust emissions, with the concentration of propane lower than that of butane. Our conclusion is that most of C3 and C4 in the ambient air comes from LP gas and not vehicle exhaust or evaporative emission, due to the higher levels of propane than butane in its formulation. The analysis of VOCs also indicates that although the conversion (in the smog chamber) of alkanes is low during the day, due to the high initial concentration, their contribution in the reaction mechanism to produce ozone can be appreciable.

Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1999 Emission Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zohner, S.K.

2000-05-30

This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1998 Emissions Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

S. K. Zohner

1999-10-01

This report presents the 1998 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradiological emissions estimates for stationary sources.

CRITERIA AND AIR TOXIC EMISSIONS FROM IN-USE, LOW EMISSION VEHICLES (LEVS)

EPA Science Inventory

The U.S. Environmental Protection Agency implemented a program to identify tailpipe emissions of criteria and air toxic contaminants from in-use, light-duty Low Emission Vehicles (LEVs). EPA recruited twenty-five LEVs in 2002, and measured emissions on a chassis dynamometer usin...

Direct measurements of sample heating by a laser-induced air plasma in pre-ablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS).

PubMed

Register, Janna; Scaffidi, Jonathan; Angel, S Michael

2012-08-01

Direct measurements of temperature changes were made using small thermocouples (TC), placed near a laser-induced air plasma. Temperature changes up to ~500 °C were observed. From the measured temperature changes, estimates were made of the amount of heat absorbed per unit area. This allowed calculations to be made of the surface temperature, as a function of time, of a sample heated by the air plasma that is generated during orthogonal pre-ablation spark dual-pulse (DP) LIBS measurements. In separate experiments, single-pulse (SP) LIBS emission and sample ablation rate measurements were performed on nickel at sample temperatures ranging from room temperature to the maximum surface temperature that was calculated using the TC measurement results (500 °C). A small, but real sample temperature-dependent increase in both SP LIBS emission and the rate of sample ablation was found for nickel samples heated up to 500 °C. Comparison of DP LIBS emission enhancement values for bulk nickel samples at room temperature versus the enhanced SP LIBS emission and sample ablation rates observed as a function of increasing sample temperature suggests that sample heating by the laser-induced air plasma plays only a minor role in DP LIBS emission enhancement.

Effect of fuel/air nonuniformity on nitric oxide emissions

NASA Technical Reports Server (NTRS)

Lyons, V. J.

1979-01-01

A flame tube combustor holding jet A fuel was used in experiments performed at a pressure of .3 Mpa and a reference velocity of 25 meters/second for three inlet air temperatures of 600, 700, and 800 K. The gas sample measurements were taken at locations 18 cm and 48 cm downstream of the perforated plate flameholder. Nonuniform fuel/air profiles were produced using a fuel injector by separately fueling the inner five fuel tubes and the outer ring of twelve fuel tubes. Six fuel/air profiles were produced for nominal overall equivalence ratios of .5 and .6. An example of three of three of these profiles and their resultant nitric oxide NOx emissions are presented. The uniform fuel/air profile cases produced uniform and relatively low profile levels. When the profiles were either center-peaked or edge-peaked, the overall mass-weighted nitric oxide levels increased.

What measurements tell us about air composition and emissions in three US oil and gas fields

NASA Astrophysics Data System (ADS)

Petron, G.; Miller, B. R.; Montzka, S. A.; Dlugokencky, E. J.; Kofler, J.; Sweeney, C.; Karion, A.; Frost, G. J.; Helmig, D.; Hueber, J.; Schnell, R. C.; Conley, S. A.; Tans, P. P.

2013-12-01

In 2012 and 2013, the NOAA Global Monitoring Division and several collaborators conducted intensive airborne and ground campaigns in three US oil and gas plays to study emissions of methane and surface ozone precursors. In this presentation we will focus on the multiple species analysis in discrete air samples collected with the NOAA Mobile Laboratory (ML) and the light aircraft in the Uinta Basin (Utah), Denver Julesburg Basin (Colorado) and Barnett Shale (Texas). Hydrocarbon ratios in samples collected with the ML downwind of specific sources show significantly more variability than the aircraft samples. These surface samples provide some useful information about the composition of various sources in each region. Ratios of the non-methane hydrocarbons on the ground and higher in the boundary layer show some differences between the plays, which could be explained by the different composition of the raw gas being produced or by different mixes of sources contributions. Understanding the speciation of atmospheric emissions is critical to identify emission vectors and to assess their potential air quality and climate impacts. Our measurement results will be compared with data from other studies, including emission inventories.

Volatile Organic Compound Emissions from Dairy Farming and their effect on San Joaquin Valley Air Quality

NASA Astrophysics Data System (ADS)

Blake, D. R.; Yang, M.; Meinardi, S.; Krauter, C.; Rowland, F. S.

2009-05-01

The San Joaquin Valley Air Pollution Control District of California issued a report identifying dairies as a main source of Volatile Organic Compounds (VOCs). A dairy study funded by the California Air Resources Board commenced shortly after the report was issued. Our University of California Irvine group teamed with California State University Fresno to determine the major sources of VOCs from various dairy operations and from a variety of dairy types. This study identified ethanol and methanol as two gases produced in major quantities throughout the dairies in the San Joaquin valley as by-products of yeast fermentation of silage. Three different types of sampling protocols were employed in order to determine the degree of enhancement of the target oxygenates in the valley air shed. Their sources, emission profiles, and emission rates were determined from whole air samples collected at various locations at the six dairies studied. An assessment of the impact of dairy emissions in the valley was achieved by using data obtained on low altitude NASA DC-8 flights through the valley, and from ground level samples collected though out the valley in a grid like design. Our data suggest that a significant amount of O3 production in the valley may come from methanol, ethanol, and acetaldehyde (a photochemical by-product ethanol oxidation). Our findings indicate that improvement to valley air quality may be obtained by focusing on instituting new silage containment practices and regulations.

Innovations in projecting emissions for air quality modeling

EPA Science Inventory

Air quality modeling is used in setting air quality standards and in evaluating their costs and benefits. Historically, modeling applications have projected emissions and the resulting air quality only 5 to 10 years into the future. Recognition that the choice of air quality mana...

Estimates of air emissions from asphalt storage tanks and truck loading

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trumbore, D.C.

1999-12-31

Title V of the 1990 Clean Air Act requires the accurate estimation of emissions from all US manufacturing processes, and places the burden of proof for that estimate on the process owner. This paper is published as a tool to assist in the estimation of air emission from hot asphalt storage tanks and asphalt truck loading operations. Data are presented on asphalt vapor pressure, vapor molecular weight, and the emission split between volatile organic compounds and particulate emissions that can be used with AP-42 calculation techniques to estimate air emissions from asphalt storage tanks and truck loading operations. Since currentmore » AP-42 techniques are not valid in asphalt tanks with active fume removal, a different technique for estimation of air emissions in those tanks, based on direct measurement of vapor space combustible gas content, is proposed. Likewise, since AP-42 does not address carbon monoxide or hydrogen sulfide emissions that are known to be present in asphalt operations, this paper proposes techniques for estimation of those emissions. Finally, data are presented on the effectiveness of fiber bed filters in reducing air emissions in asphalt operations.« less

40 CFR 267.204 - What air emission standards apply?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false What air emission standards apply? 267... PERMIT Tank Systems § 267.204 What air emission standards apply? You must manage all hazardous waste... incinerator, flame, boiler, process heater, condenser, and carbon absorption unit. ...

Cotton harvesting emission factors based on source sampling

USDA-ARS?s Scientific Manuscript database

Air quality regulation across the U.S. is intensifying due to increasing public concern for environmental protection. Non-attainment status with Federal particulate matter (PM) air quality standards has forced air pollution regulators in some states to focus emission reduction efforts on previously ...

Quantifying Uncontrolled Air Emissions from Two Florida Landfills

EPA Science Inventory

Landfill gas emissions, if left uncontrolled, contribute to air toxics, climate change, trospospheric ozone, and urban smog. Measuring emissions from landfills presents unique challenges due to the large and variable source area, spatial and temporal variability of emissions, and...

Can car air filters be useful as a sampling medium for air pollution monitoring purposes?

PubMed

Katsoyiannis, Athanasios; Birgul, Askin; Ratola, Nuno; Cincinelli, Alessandra; Sweetman, Andy J; Jones, Kevin C

2012-11-01

Urban air quality and real human exposure to chemical environmental stressors is an issue of high scientific and political interest. In an effort to find innovative and inexpensive means for air quality monitoring, the ability of car engine air filters (CAFs) to act as efficient samplers collecting street level air, to which people are exposed to, was tested. In particular, in the case of taxis, air filters are replaced after regular distances, the itineraries are almost exclusively urban, cruising mode is similar and, thus, knowledge of the air flow can provide with an integrated city air sample. The present pilot study focused on polycyclic aromatic hydrocarbons (PAHs), the most important category of organic pollutants associated with traffic emissions. Concentrations of ΣPAHs in CAFs ranged between 650 and 2900 μg CAF(-1), with benzo[b]fluoranthene, benzo[k]fluoranthene and indeno[123-cd]pyrene being the most abundant PAHs. Benzo[a]pyrene (BaP) ranged between 110 and 250 μg CAF(-1), accounting regularly for 5-15% of the total carcinogenic PAHs. The CAF PAH loads were used to derive road-level atmospheric PAH concentrations from a standard formula relating to the CAF air flow. Important parameters/assumptions for these estimates are the cruising speed and the exposure duration of each CAF. Based on information obtained from the garage experts, an average 'sampled air volume' of 48,750 m(3) per CAF was estimated, with uncertainty in this calculation estimated to be about a factor of 4 between the two extreme scenarios. Based on this air volume, ΣPAHs ranged between 13 and 56 ng m(-3) and BaP between 2.1 and 5.0 ng m(-3), suggesting that in-traffic BaP concentrations can be many times higher than the limit values set by the UK (0.25 ng m(-3)) and the European Union (1.0 ng m(-3)), or from active sampling stations normally cited on building roof tops or far from city centres. Notwithstanding the limitations of this approach, the very low cost, the continuous

Effect of fuel-air-ratio nonuniformity on emissions of nitrogen oxides

NASA Technical Reports Server (NTRS)

Lyons, V. J.

1981-01-01

The inlet fuel-air ratio nonuniformity is studied to deterine how nitrogen oxide (NOx) emissions are affected. An increase in NOx emissions with increased fuel-air ratio nonuniformity for average equivalence ratios less than 0.7 and a decrease in NOx emissions for average equivalence ratios near stoichiometric is predicted. The degree of uniformityy of fuel-air ratio profiles that is necessary to achieve NOx emissions goals for actual engines that use lean, premixed, prevaporized combustion systems is determined.

40 CFR 267.177 - What air emission standards apply?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false What air emission standards apply? 267... PERMIT Use and Management of Containers § 267.177 What air emission standards apply? You must manage all... incinerator, catalytic vapor incinerator, flame, boiler, process heater, condenser, and carbon absorption unit. ...

Measurement of air pollutant emissions from Lome, Cotonou and Accra

NASA Astrophysics Data System (ADS)

Lee, James; Vaughan, Adam; Nelson, Bethany; Young, Stuart; Evans, Mathew; Morris, Eleanor; Ladkin, Russel

2017-04-01

High concentrations of airborne pollutants (e.g. the oxides of nitrogen, sulphur dioxide and carbon monoxide) in existing and evolving cities along the Guinea Coast cause respiratory diseases with potentially large costs to human health and the economic capacity of the local workforce. It is important to understand the rate of emission of such pollutants in order to model current and future air quality and provide guidance to the potential outcomes of air pollution abatement strategies. Often dated technologies and poor emission control strategies lead to substantial uncertainties in emission estimates calculated from vehicle and population number density statistics. The unreliable electrical supply in cities in the area has led to an increased reliance on small-scale diesel powered generators and these potentially present a significant source of emissions. The uncontrolled open incineration of waste adds a further very poorly constrained emission source within the cities. The DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) project involved a field campaign which used highly instrumented aircraft capable of in situ measurements of a range of air pollutants. Seven flights using the UK British Antarctic Survey's Twin Otter aircraft specifically targeted air pollution emissions from cities in West Africa (4 x Accra, Ghana; 2 x Lome, Togo and 1 x Cotonou, Benin). Measurements of NO, NO2, SO2, CO, CH4 and CO2 were made at multiple altitudes upwind and downwind of the cities, with the mass balance technique used to calculate emission rates. These are then compared to the Emissions Database for Global Atmospheric Research (EDGAR) estimates. Ultimately the data will be used to inform on and potentially improve the emission estimates, which in turn should lead to better forecasting of air pollution in West African cities and help guide future air pollution abatement strategy.

Description of Latvian Metal Production and Processing Enterprises' Air Emissions

NASA Astrophysics Data System (ADS)

Pubule, Jelena; Zahare, Dace; Blumberga, Dagnija

2010-01-01

The metal production and processing sector in Latvia has acquired a stable position in the national economy. Smelting of ferrous and nonferrous metals, production of metalware, galvanisation, etc. are developed in Latvia. The metal production and processing sector has an impact on air quality due to polluting substances which are released in the air from metal treatment processes. Therefore it is necessary to determine the total volume of emissions produced by the metal production and processing sector in Latvia. This article deals with the air polluting emissions of the Latvian metal production and processing industry, and sets the optimum sector emission volumes using the emissions benchmark methodology.

Contribution of biomass combustion to air pollutant emissions =

NASA Astrophysics Data System (ADS)

Goncalves, Catia Vanessa Maio

In Portugal, it was estimated that around 1.95 Mton/year of wood is used in residential wood burning for heating and cooking. Additionally, in the last decades, burnt forest area has also been increasing. These combustions result in high levels of toxic air pollutants and a large perturbation of atmospheric chemistry, interfere with climate and have adverse effects on health. Accurate quantification of the amounts of trace gases and particulate matter emitted from residential wood burning, agriculture and garden waste burning and forest fires on a regional and global basis is essential for various purposes, including: the investigation of several atmospheric processes, the reporting of greenhouse gas emissions, and quantification of the air pollution sources that affect human health at regional scales. In Southern Europe, data on detailed emission factors from biomass burning are rather inexistent. Emission inventories and source apportionment, photochemical and climate change models use default values obtained for US and Northern Europe biofuels. Thus, it is desirable to use more specific locally available data. The objective of this study is to characterise and quantify the contribution of biomass combustion sources to atmospheric trace gases and aerosol concentrations more representative of the national reality. Laboratory (residential wood combustion) and field (agriculture/garden waste burning and experimental wildland fires) sampling experiments were carried out. In the laboratory, after the selection of the most representative wood species and combustion equipment in Portugal, a sampling program to determine gaseous and particulate matter emission rates was set up, including organic and inorganic aerosol composition. In the field, the smoke plumes from agriculture/garden waste and experimental wildland fires were sampled. The results of this study show that the combustion equipment and biofuel type used have an important role in the emission levels and

Source sampling of particulate matter emissions from cotton harvesting - System field testing and emission factor development

USDA-ARS?s Scientific Manuscript database

Emission factors are used in the air pollution regulatory process to quantify the mass of pollutants emitted from a source. Accurate emission factors must be used in the air pollution regulatory process to ensure fair and appropriate regulation for all sources. Agricultural sources, including cotton...

Aircraft trace gas measurements during the London 2012 Olympics: Air quality and emission fluxes derived from sampling upwind and downwind of a megacity

NASA Astrophysics Data System (ADS)

Allen, G.; O'Shea, S.; Muller, J.; Jones, B.; O'Sullivan, D.; Lee, J. D.; Bauguitte, S.; Gallagher, M. W.; Percival, C.; Barratt, B.; McQuaid, J. B.; Illingworth, S.

2013-12-01

This study presents airborne in situ and remote sensing measurements recorded during July and August 2012, across the period of the London 2012 Summer Olympics and simultaneous with the Clear air for London (ClearfLo) ground-based measurement and modelling campaign. Through long-term (2-year) and intensive observation periods (Winter 2011 and Summer 2012), the ClearfLo programme aims to better understand emissions, as well as the chemical, dynamical and micro-meteorological processes which modulate air quality in the London urban environment - an important risk factor for both acute and chronic health effects. The work presented here focuses on two contrasting case studies within the summer ClearfLo period: 30 July 2012 and 9 August 2012, representing relatively clean background and polluted background cases, respectively, and characterised by well-mixed Atlantic westerly maritime inflow in the former and stagnant air (high pressure) in the latter. Measurements of CO, CO2, CH4, N2O, O3, HCN, and other gases measured on board the UK Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 aircraft will be presented and interpreted, with emphasis on observed concentration gradients and tracer-tracer correlations as well as airmass vertical structure and airmass history upwind and downwind of central London in each case. By applying a simple advective model and making use of vertically resolved thermodynamic and composition data, we are able to derive emission strengths for these gases that are representative of the total enclosed surface area. Example emissions for these two cases range between 6x105 kg(C)/hr and 9x105 kg(C)/hr for CO2, and ~0.6x105 kg(C)/hr for CH4. This airborne sampling methodology highlights the unique utility of aircraft measurements to routinely and climatologically characterise emissions from area sources such as cities, and points to future missions to target localised hotspots and distributed point sources.

Mapping Emissions that Contribute to Air Pollution Using Adjoint Sensitivity Analysis

NASA Astrophysics Data System (ADS)

Bastien, L. A. J.; Mcdonald, B. C.; Brown, N. J.; Harley, R.

2014-12-01

The adjoint of the Community Multiscale Air Quality model (CMAQ) is used to map emissions that contribute to air pollution at receptors of interest. Adjoint tools provide an efficient way to calculate the sensitivity of a model response to a large number of model inputs, a task that would require thousands of simulations using a more traditional forward sensitivity approach. Initial applications of this technique, demonstrated here, are to benzene and directly-emitted diesel particulate matter, for which atmospheric reactions are neglected. Emissions of these pollutants are strongly influenced by light-duty gasoline vehicles and heavy-duty diesel trucks, respectively. We study air quality responses in three receptor areas where populations have been identified as especially susceptible to, and adversely affected by air pollution. Population-weighted air basin-wide responses for each pollutant are also evaluated for the entire San Francisco Bay area. High-resolution (1 km horizontal grid) emission inventories have been developed for on-road motor vehicle emission sources, based on observed traffic count data. Emission estimates represent diurnal, day of week, and seasonal variations of on-road vehicle activity, with separate descriptions for gasoline and diesel sources. Emissions that contribute to air pollution at each receptor have been mapped in space and time using the adjoint method. Effects on air quality of both relative (multiplicative) and absolute (additive) perturbations to underlying emission inventories are analyzed. The contributions of local versus upwind sources to air quality in each receptor area are quantified, and weekday/weekend and seasonal variations in the influence of emissions from upwind areas are investigated. The contribution of local sources to the total air pollution burden within the receptor areas increases from about 40% in the summer to about 50% in the winter due to increased atmospheric stagnation. The effectiveness of control

REGIONAL AIR POLLUTION STUDY: HEAT EMISSION INVENTORY

EPA Science Inventory

As part of the St. Louis Regional Air Pollution Study (RAPS), a heat emission inventory has been assembled. Heat emissions to the atmosphere originate, directly or indirectly, from the combustion of fossil fuels (there are no nuclear plants in the St. Louis AQCR). With the except...

Health effects of SRS non-radiological air emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stewart, J.

1997-06-16

This report examines the potential health effects of non radiological emissions to the air resulting from operations at the Savannah River Site (SRS). The scope of this study was limited to the 55 air contaminants for which the US Environmental Protection Agency (EPA) has quantified risk by determining unit risk factors (excess cancer risks) and/or reference concentrations (deleterious non cancer risks). Potential health impacts have been assessed in relation to the maximally exposed individual. This is a hypothetical person who resides for a lifetime at the SRS boundary. The most recent (1994) quality assured SRS emissions data available were used.more » Estimated maximum site boundary concentrations of the air contaminants were calculated using air dispersion modeling and 24-hour and annual averaging times. For the emissions studied, the excess cancer risk was found to be less than the generally accepted risk level of 1 in 100,000 and, in most cases, was less than 1 in 1,000,000. Deleterious non cancer effects were also found to be very unlikely.« less

Fuel-Air Mixing Effect on Nox Emissions for a Lean Premixed-Prevaporized Combustion System

NASA Technical Reports Server (NTRS)

Lee, Chi-Ming; Chun, Kue S.; Locke, Randy J.

1995-01-01

The lean premixed-prevaporized (LPP) concept effectively meets low nitrogen oxides (NOx) emission requirements for combustors with the high inlet temperature and pressure typical of the High-Speed Civil Transport (HSCT). For the LPP system fuel-air mixture uniformity is probably the most important factor for low NOx emissions. Previous studies have suggested that the fuel-air mixture uniformity can be severely affected by changing the number and configuration of fuel injection points. Therefore, an experimental study was performed to determine how the number of fuel injection points and their arrangement affect NOx emissions from an LPP system. The NOx emissions were measured by a gas-sampling probe in a flame-tube rig at the following conditions: inlet temperature of 810 K (1000 F), rig pressure of 10 atm, reference velocity of 150 ft/s, and residence time near 0.005 s. Additionally, a focused Schlieren diagnostic technique coupled with a high speed camera was used to provide a qualitative description of the spatial flow field.

Animals as indicators of ecosystem responses to air emissions

USGS Publications Warehouse

Newman, James R.; Schreiber, R. Kent

1984-01-01

With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to air-borne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.

Compliance Software for Radioactive Air Emissions

EPA Pesticide Factsheets

Atmospheric dispersion and transport models that are used to assess radiation dose and risk and to demonstrate compliance with certain radionuclide National Emission Standards for Hazardous Air Pollutants (NESHAPs) regulations.

Apparatus for Measuring Total Emissivity of Small, Low-Emissivity Samples

NASA Technical Reports Server (NTRS)

Tuttle, James; DiPirro, Michael J.

2011-01-01

An apparatus was developed for measuring total emissivity of small, lightweight, low-emissivity samples at low temperatures. The entire apparatus fits inside a small laboratory cryostat. Sample installation and removal are relatively quick, allowing for faster testing. The small chamber surrounding the sample is lined with black-painted aluminum honeycomb, which simplifies data analysis. This results in the sample viewing a very high-emissivity surface on all sides, an effect which would normally require a much larger chamber volume. The sample and chamber temperatures are individually controlled using off-the-shelf PID (proportional integral derivative) controllers, allowing flexibility in the test conditions. The chamber can be controlled at a higher temperature than the sample, allowing a direct absorptivity measurement. The lightweight sample is suspended by its heater and thermometer leads from an isothermal bar external to the chamber. The wires run out of the chamber through small holes in its corners, and the wires do not contact the chamber itself. During a steady-state measurement, the thermometer and bar are individually controlled at the same temperature, so there is zero heat flow through the wires. Thus, all of sample-temperature-control heater power is radiated to the chamber. Double-aluminized Kapton (DAK) emissivity was studied down to 10 K, which was about 25 K colder than any previously reported measurements. This verified a minimum in the emissivity at about 35 K and a rise as the temperature dropped to lower values.

Assessment of airborne bacteria and noroviruses in air emission from a new highly-advanced hospital wastewater treatment plant.

PubMed

Uhrbrand, K; Schultz, A C; Koivisto, A J; Nielsen, U; Madsen, A M

2017-04-01

Exposure to bioaerosols can pose a health risk to workers at wastewater treatment plants (WWTPs) and to habitants of their surroundings. The main objective of this study was to examine the presence of harmful microorganisms in the air emission from a new type of hospital WWTP employing advanced wastewater treatment technologies. Air particle measurements and sampling of inhalable bacteria, endotoxin and noroviruses (NoVs) were performed indoor at the WWTP and outside at the WWTP ventilation air exhaust, downwind of the air exhaust, and upwind of the WWTP. No significant differences were seen in particle and endotoxin concentrations between locations. Bacterial concentrations were comparable or significantly lower in the exhaust air than inside the WWTP and in the upwind reference. Bacterial isolates were identified using matrix-assisted laser desorption-ionization time-of-flight mass spectrometry. In total, 35 different bacterial genera and 64 bacterial species were identified in the air samples. Significantly higher genus and species richness was found with an Andersen Cascade Impactor compared with filter-based sampling. No pathogenic bacteria were found in the exhaust air. Streptomyces was the only bacterium found in the air both inside the WWTP and at the air emission, but not in the upwind reference. NoV genomes were detected in the air inside the WWTP and at the air exhaust, albeit in low concentrations. As only traces of NoV genomes could be detected in the exhaust air they are unlikely to pose a health risk to surroundings. Hence, we assess the risk of airborne exposure to pathogenic bacteria and NoVs from the WWTP air emission to surroundings to be negligible. However, as a slightly higher NoV concentration was detected inside the WWTP, we cannot exclude the possibility that exposure to airborne NoVs can pose a health risk to susceptible to workers inside the WWTP, although the risk may be low. Copyright © 2017 Elsevier Ltd. All rights reserved.

Profiling quinones in ambient air samples collected from the Athabasca region (Canada).

PubMed

Wnorowski, Andrzej; Charland, Jean-Pierre

2017-12-01

This paper presents new findings on polycyclic aromatic hydrocarbon oxidation products-quinones that were collected in ambient air samples in the proximity of oil sands exploration. Quinones were characterized for their diurnal concentration variability, phase partitioning, and molecular size distribution. Gas-phase (GP) and particle-phase (PM) ambient air samples were collected separately in the summer; a lower quinone content was observed in the PM samples from continuous 24-h sampling than from combined 12-h sampling (day and night). The daytime/nocturnal samples demonstrated that nighttime conditions led to lower concentrations and some quinones not being detected. The highest quinone levels were associated with wind directions originating from oil sands exploration sites. The statistical correlation with primary pollutants directly emitted from oil sands industrial activities indicated that the bulk of the detected quinones did not originate directly from primary emission sources and that quinone formation paralleled a reduction in primary source NO x levels. This suggests a secondary chemical transformation of primary pollutants as the origin of the determined quinones. Measurements of 19 quinones included five that have not previously been reported in ambient air or in Standard Reference Material 1649a/1649b and seven that have not been previously measured in ambient air in the underivatized form. This is the first paper to report on quinone characterization in secondary organic aerosols originating from oil sands activities, to distinguish chrysenequinone and anthraquinone positional isomers in ambient air, and to report the requirement of daylight conditions for benzo[a]pyrenequinone and naphthacenequinone to be present in ambient air. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

Unvented kerosene-heater emissions in mobile homes: Studies on indoor air particles, semivolatile organics, carbon monoxide, and mutagenicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumford, J.L.; Lewtas, J.; Burton, R.M.

1990-01-01

The study was conducted to assess human exposure to air pollutants resulting from the use of kerosene heaters in mobile homes. It has been estimated that 15-17 million unvented kerosene heaters have been sold in the United States, and 33% of these heaters have been sold to mobile home residents. The emissions from kerosene heaters can result in high pollutants levels in mobile homes that have a small air volume and low ventilation rate. Indoor air exchange rate, temperature, and humidity were measured. Chemical analyses, including polycyclic aromatic hydrocarbon (PAH) and nitro PAH, also were performed on the indoor airmore » samples from a selected home with the kerosene heater on and off. Increases in CO and organic concentrations resulting from the use of kerosene heaters were found in most homes monitored. Chemical analysis data also suggested the presence of evaporated, unburned kerosene fuel present in semivolatile organics collected in the XAD samples. When kerosene heaters were on, 56% of the sampling days (in all homes) showed dose-response mutagenic activity and 19% showed mutagenic activity on the heater-off days. In comparison with the U.S. national ambient air standards, four out of the eight heaters investigated in this study emitted pollutants that exceeded the ambient air standards some days. These data suggested that emissions from unvented kerosene heaters can significantly impact indoor air quality in mobile homes and that these emissions contain carcinogenic compounds and can be potentially carcinogenic in humans.« less

Spatial analysis on China's regional air pollutants and CO2 emissions: emission pattern and regional disparity

NASA Astrophysics Data System (ADS)

Dong, Liang; Liang, Hanwei

2014-08-01

China has suffered from serious air pollution and CO2 emission. Challenges of emission reduction policy not only come from technology advancement, but also generate from the fact that, China has pronounced disparity between regions, in geographical and socioeconomic. How to deal with regional disparity is important to achieve the reduction target effectively and efficiently. This research conducts a spatial analysis on the emission patterns of three air pollutants named SO2, NOx and PM2.5, and CO2, in China's 30 provinces, applied with spatial auto-correlation and multi regression modeling. We further analyze the regional disparity and inequity issues with the approach of Lorenz curve and Gini coefficient. Results highlight that: there is evident cluster effect for the regional air pollutants and CO2 emissions. While emission amount increases from western regions to eastern regions, the emission per GDP is in inverse trend. The Lorenz curve shows an even larger unequal distribution of GDP/emissions than GDP/capita in 30 regions. Certain middle and western regions suffers from a higher emission with lower GDP, which reveal the critical issue of emission leakage. Future policy making to address such regional disparity is critical so as to promote the emission control policy under the “equity and efficiency” principle.

40 CFR 204.52 - Portable air compressor noise emission standard.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Portable air compressor noise emission standard. 204.52 Section 204.52 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) NOISE ABATEMENT PROGRAMS NOISE EMISSION STANDARDS FOR CONSTRUCTION EQUIPMENT Portable Air Compressors § 204.52...

40 CFR 204.52 - Portable air compressor noise emission standard.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Portable air compressor noise emission standard. 204.52 Section 204.52 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) NOISE ABATEMENT PROGRAMS NOISE EMISSION STANDARDS FOR CONSTRUCTION EQUIPMENT Portable Air Compressors § 204.52...

Modeling Aircraft Emissions for Regional-scale Air Quality: Adapting a New Global Aircraft Emissions Database for the U.S

NASA Astrophysics Data System (ADS)

Arunachalam, S.; Baek, B. H.; Vennam, P. L.; Woody, M. C.; Omary, M.; Binkowski, F.; Fleming, G.

2012-12-01

Commercial aircraft emit substantial amounts of pollutants during their complete activity cycle that ranges from landing-and-takeoff (LTO) at airports to cruising in upper elevations of the atmosphere, and affect both air quality and climate. Since these emissions are not uniformly emitted over the earth, and have substantial temporal and spatial variability, it is vital to accurately evaluate and quantify the relative impacts of aviation emissions on ambient air quality. Regional-scale air quality modeling applications do not routinely include these aircraft emissions from all cycles. Federal Aviation Administration (FAA) has developed the Aviation Environmental Design Tool (AEDT), a software system that dynamically models aircraft performance in space and time to calculate fuel burn and emissions from gate-to-gate for all commercial aviation activity from all airports globally. To process in-flight aircraft emissions and to provide a realistic representation of these for treatment in grid-based air quality models, we have developed an interface processor called AEDTproc that accurately distributes full-flight chorded emissions in time and space to create gridded, hourly model-ready emissions input data. Unlike the traditional emissions modeling approach of treating aviation emissions as ground-level sources or processing emissions only from the LTO cycles in regional-scale air quality studies, AEDTproc distributes chorded inventories of aircraft emissions during LTO cycles and cruise activities into a time-variant 3-D gridded structure. We will present results of processed 2006 global emissions from AEDT over a continental U.S. modeling domain to support a national-scale air quality assessment of the incremental impacts of aircraft emissions on surface air quality. This includes about 13.6 million flights within the U.S. out of 31.2 million flights globally. We will focus on assessing spatio-temporal variability of these commercial aircraft emissions, and

Re-entrained road dust PM10 emission from selected streets of Krakow and its impact on air quality

NASA Astrophysics Data System (ADS)

Bogacki, Marek; Mazur, Marian; Oleniacz, Robert; Rzeszutek, Mateusz; Szulecka, Adriana

2018-01-01

Scientific research studies conducted in various parts of the world confirm that PM10 concentrations in urban air depend to a great extent on the resuspension processes of the dust deposited on the road surface. The paper presents the results of the study related to the determination of the re-entrained PM10 emissions from four selected streets of Krakow (Southern Poland) together with the assessment of its impact on air quality. Examined streets are characterised by different traffic intensity (from 500 to over 20 000 vehicles per day) and individual vehicle structure. Dust material sampling and estimation of the PM10 emission were conducted according to the U.S. EPA methodology (AP 42 Fifth Edition). Two variants of sample collection were applied: from the road surface including the area at the curb (4 streets) and from the road surface alone (1 street). The estimates of resuspended road dust emission as well as the reference values derived from the U.S. EPA guidelines were used to assess the impact of this emission on the PM10 levels in the air at the location of one of the analysed streets. This assessment was conducted using the CALINE4 mathematical model. The study showed that the PM10 emissions from the re-entrained road dust can be responsible for up to 25 % in the winter and 50 % in the summer of the total PM10 concentrations in the air near the roads.

Results of the air emission research study

USDA-ARS?s Scientific Manuscript database

Air quality was monitored in beef mono-slope barns. The objectives of the study were 1) to gather baseline data for the levels of gas emissions and particulate matter from beef mono-slope facilities, 2) evaluate the effect of two different manure handling systems on air quality, and 3) provide infor...

40 CFR 89.424 - Dilute emission sampling calculations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Dilute emission sampling calculations... Emission Test Procedures § 89.424 Dilute emission sampling calculations. (a) The final reported emission... concentration. For cases where exhaust sampling of CO2 is not performed, the following approximation is...

40 CFR 89.424 - Dilute emission sampling calculations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Dilute emission sampling calculations... Emission Test Procedures § 89.424 Dilute emission sampling calculations. (a) The final reported emission... concentration. For cases where exhaust sampling of CO2 is not performed, the following approximation is...

Effect of timed secondary-air injection on automotive emissions

NASA Technical Reports Server (NTRS)

Coffin, K. P.

1973-01-01

A single cylinder of an automotive V-8 engine was fitted with an electronically timed system for the pulsed injection of secondary air. A straight-tube exhaust minimized any mixing other than that produced by secondary-air pulsing. The device was operated over a range of engine loads and speeds. Effects attributable to secondary-air pulsing were found, but emission levels were generally no better than using the engine's own injection system. Under nontypical fast-idle, no-load conditions, emission levels were reduced by roughly a factor of 2.

Sorbent-based sampling methods for volatile and semi-volatile organic compounds in air Part 1: Sorbent-based air monitoring options.

PubMed

Woolfenden, Elizabeth

2010-04-16

Sorbent tubes/traps are widely used in combination with gas chromatographic (GC) analytical methods to monitor the vapour-phase fraction of organic compounds in air. Target compounds range in volatility from acetylene and freons to phthalates and PCBs and include apolar, polar and reactive species. Airborne vapour concentrations will vary depending on the nature of the location, nearby pollution sources, weather conditions, etc. Levels can range from low percent concentrations in stack and vent emissions to low part per trillion (ppt) levels in ultra-clean outdoor locations. Hundreds, even thousands of different compounds may be present in any given atmosphere. GC is commonly used in combination with mass spectrometry (MS) detection especially for environmental monitoring or for screening uncharacterised workplace atmospheres. Given the complexity and variability of organic vapours in air, no one sampling approach suits every monitoring scenario. A variety of different sampling strategies and sorbent media have been developed to address specific applications. Key sorbent-based examples include: active (pumped) sampling onto tubes packed with one or more sorbents held at ambient temperature; diffusive (passive) sampling onto sorbent tubes/cartridges; on-line sampling of air/gas streams into cooled sorbent traps; and transfer of air samples from containers (canisters, Tedlar) bags, etc.) into cooled sorbent focusing traps. Whichever sampling approach is selected, subsequent analysis almost always involves either solvent extraction or thermal desorption (TD) prior to GC(/MS) analysis. The overall performance of the air monitoring method will depend heavily on appropriate selection of key sampling and analytical parameters. This comprehensive review of air monitoring using sorbent tubes/traps is divided into 2 parts. (1) Sorbent-based air sampling option. (2) Sorbent selection and other aspects of optimizing sorbent-based air monitoring methods. The paper presents

Estimating Lightning NOx Emissions for Regional Air Quality Modeling

NASA Astrophysics Data System (ADS)

Holloway, T.; Scotty, E.; Harkey, M.

2014-12-01

Lightning emissions have long been recognized as an important source of nitrogen oxides (NOx) on a global scale, and an essential emission component for global atmospheric chemistry models. However, only in recent years have regional air quality models incorporated lightning NOx emissions into simulations. The growth in regional modeling of lightning emissions has been driven in part by comparisons with satellite-derived estimates of column NO2, especially from the Ozone Monitoring Instrument (OMI) aboard the Aura satellite. We present and evaluate a lightning inventory for the EPA Community Multiscale Air Quality (CMAQ) model. Our approach follows Koo et al. [2010] in the approach to spatially and temporally allocating a given total value based on cloud-top height and convective precipitation. However, we consider alternate total NOx emission values (which translate into alternate lightning emission factors) based on a review of the literature and performance evaluation against OMI NO2 for July 2007 conditions over the U.S. and parts of Canada and Mexico. The vertical distribution of lightning emissions follow a bimodal distribution from Allen et al. [2012] calculated over 27 vertical model layers. Total lightning NO emissions for July 2007 show the highest above-land emissions in Florida, southeastern Texas and southern Louisiana. Although agreement with OMI NO2 across the domain varied significantly depending on lightning NOx assumptions, agreement among the simulations at ground-based NO2 monitors from the EPA Air Quality System database showed no meaningful sensitivity to lightning NOx. Emissions are compared with prior studies, which find similar distribution patterns, but a wide range of calculated magnitudes.

AIR EMISSION INVENTORIES IN NORTH AMERICA: A CRITICAL ASSESSMENT

EPA Science Inventory

Although emission inventories are the foundation of air quality management and have supported substantial improvements in North American air quality, they have a number of shortcomings that can potentially lead to ineffective air quality management strategies. New technologies fo...

75 FR 9647 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-03

...EPA is promulgating national emission standards for hazardous air pollutants for existing stationary compression ignition reciprocating internal combustion engines that either are located at area sources of hazardous air pollutant emissions or that have a site rating of less than or equal to 500 brake horsepower and are located at major sources of hazardous air pollutant emissions. In addition, EPA is promulgating national emission standards for hazardous air pollutants for existing non-emergency stationary compression ignition engines greater than 500 brake horsepower that are located at major sources of hazardous air pollutant emissions. Finally, EPA is revising the provisions related to startup, shutdown, and malfunction for the engines that were regulated previously by these national emission standards for hazardous air pollutants.

Toluene diisocyanate emission to air and migration to a surface from a flexible polyurethane foam.

PubMed

Vangronsveld, Erik; Berckmans, Steven; Spence, Mark

2013-06-01

Flexible polyurethane foam (FPF) is produced from the reaction of toluene diisocyanate (TDI) and polyols. Because of the potential for respiratory sensitization following exposure to TDI, concerns have been raised about potential consumer exposure to TDI from residual 'free TDI' in FPF products. Limited and conflicting results exist in the literature concerning the presence of unreacted TDI remaining in FPF as determined by various solvent extraction and analysis techniques. Because residual TDI results are most often intended for application in assessment of potential human exposure to TDI from FPF products, testing techniques that more accurately simulated human contact with foam were designed. To represent inhalation exposure to TDI from polyurethane foam, a test that measured the emission of TDI to air was conducted. For simulation of human dermal exposure to TDI from polyurethane foam, a migration test technique was designed. Emission of TDI to air was determined for a representative FPF using three different emission test cells. Two were commercially available cells that employ air flow over the surface of the foam [the Field and Laboratory Emission Cell (FLEC®) and the Micro-Chamber/Thermal Extraction™ cell]. The third emission test cell was of a custom design and features air flow through the foam sample rather than over the foam surface. Emitted TDI in the air of the test cells was trapped using glass fiber filters coated with 1-(2-methoxyphenyl)-piperazine (MP), a commonly used derivatizing agent for diisocyanates. The filters were subsequently desorbed and analyzed by liquid chromatography/mass spectrometry. Measurement of TDI migration from representative foam was accomplished by placing glass fiber filters coated with MP on the outer surfaces of a foam disk and then compressing the filters against the disk using a clamping apparatus for periods of 8 and 24 h. The sample filters were subsequently desorbed and analyzed in the same manner as for the

Reducing ultrafine particle emissions using air injection in wood-burning cookstoves

DOE PAGES

Rapp, Vi H.; Caubel, Julien J.; Wilson, Daniel L.; ...

2016-06-27

In order to address the health risks and climate impacts associated with pollution from cooking on biomass fires, researchers have focused on designing new cookstoves that improve cooking performance and reduce harmful emissions, specifically particulate matter (PM). One method for improving cooking performance and reducing emissions is using air injection to increase turbulence of unburned gases in the combustion zone. Although air injection reduces total PM mass emissions, the effect on PM size-distribution and number concentration has not been thoroughly investigated. Using two new wood-burning cookstove designs from Lawrence Berkeley National Laboratory, this research explores the effect of air injectionmore » on cooking performance, PM and gaseous emissions, and PM size distribution and number concentration. Both cookstoves were created using the Berkeley-Darfur Stove as the base platform to isolate the effects of air injection. The thermal performance, gaseous emissions, PM mass emissions, and particle concentrations (ranging from 5 nm to 10 μm in diameter) of the cookstoves were measured during multiple high-power cooking tests. Finally, the results indicate that air injection improves cookstove performance and reduces total PM mass but increases total ultrafine (less than 100 nm in diameter) PM concentration over the course of high-power cooking.« less

Reducing ultrafine particle emissions using air injection in wood-burning cookstoves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rapp, Vi H.; Caubel, Julien J.; Wilson, Daniel L.

In order to address the health risks and climate impacts associated with pollution from cooking on biomass fires, researchers have focused on designing new cookstoves that improve cooking performance and reduce harmful emissions, specifically particulate matter (PM). One method for improving cooking performance and reducing emissions is using air injection to increase turbulence of unburned gases in the combustion zone. Although air injection reduces total PM mass emissions, the effect on PM size-distribution and number concentration has not been thoroughly investigated. Using two new wood-burning cookstove designs from Lawrence Berkeley National Laboratory, this research explores the effect of air injectionmore » on cooking performance, PM and gaseous emissions, and PM size distribution and number concentration. Both cookstoves were created using the Berkeley-Darfur Stove as the base platform to isolate the effects of air injection. The thermal performance, gaseous emissions, PM mass emissions, and particle concentrations (ranging from 5 nm to 10 μm in diameter) of the cookstoves were measured during multiple high-power cooking tests. Finally, the results indicate that air injection improves cookstove performance and reduces total PM mass but increases total ultrafine (less than 100 nm in diameter) PM concentration over the course of high-power cooking.« less

Polarized radio emission from extensive air showers measured with LOFAR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schellart, P.; Buitink, S.; Corstanje, A.

2014-10-01

We present LOFAR measurements of radio emission from extensive air showers. We find that this emission is strongly polarized, with a median degree of polarization of nearly 99%, and that the angle between the polarization direction of the electric field and the Lorentz force acting on the particles, depends on the observer location in the shower plane. This can be understood as a superposition of the radially polarized charge-excess emission mechanism, first proposed by Askaryan and the geomagnetic emission mechanism proposed by Kahn and Lerche. We calculate the relative strengths of both contributions, as quantified by the charge-excess fraction, formore » 163 individual air showers. We find that the measured charge-excess fraction is higher for air showers arriving from closer to the zenith. Furthermore, the measured charge-excess fraction also increases with increasing observer distance from the air shower symmetry axis. The measured values range from (3.3± 1.0)% for very inclined air showers at 25 m to (20.3± 1.3)% for almost vertical showers at 225 m. Both dependencies are in qualitative agreement with theoretical predictions.« less

40 CFR 61.34 - Air sampling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 8 2011-07-01 2011-07-01 false Air sampling. 61.34 Section 61.34... sampling. (a) Stationary sources subject to § 61.32(b) shall locate air sampling sites in accordance with a... concentrations calculated within 30 days after filters are collected. Records of concentrations at all sampling...

The identification of Volatile Organic Compound's emission sources in indoor air of living spaces, offices and laboratories

NASA Astrophysics Data System (ADS)

Kultys, Beata

2018-01-01

Indoor air quality is important because people spend most of their time in closed rooms. If volatile organic compounds (VOCs) are present at elevated concentrations, they may cause a deterioration in human well-being or health. The identification of indoor emission sources is carried out by comparison indoor and outdoor air composition. The aim of the study was to determinate the concentration of VOCs in indoor air, where there was a risk of elevated levels due to the kind of work type carried out or the users complained about the symptoms of a sick building followed by an appropriate interpretation of the results to determine whether the source of the emission in the tested room occurs. The air from residential, office and laboratory was tested in this study. The identification of emission sources was based on comparison of indoor and outdoor VOCs concentration and their correlation coefficients. The concentration of VOCs in all the rooms were higher or at a similar level to that of the air sampled at the same time outside the building. Human activity, in particular repair works and experiments with organic solvents, has the greatest impact on deterioration of air quality.

Criteria and air-toxic emissions from in-use automobiles in the National Low-Emission Vehicle program.

PubMed

Baldauf, Rich W; Gabele, Pete; Crews, William; Snow, Richard; Cook, J Rich

2005-09-01

The U.S. Environmental Protection Agency (EPA) implemented a program to identify tailpipe emissions of criteria and air-toxic contaminants from in-use, light-duty low-emission vehicles (LEVs). EPA recruited 25 LEVs in 2002 and measured emissions on a chassis dynamometer using the cold-start urban dynamometer driving schedule of the Federal Test Procedure. The emissions measured included regulated pollutants, particulate matter, speciated hydrocarbon compounds, and carbonyl compounds. The results provided a comparison of emissions from real-world LEVs with emission standards for criteria and air-toxic compounds. Emission measurements indicated that a portion of the in-use fleet tested exceeded standards for the criteria gases. Real-time regulated and speciated hydrocarbon measurements demonstrated that the majority of emissions occurred during the initial phases of the cold-start portion of the urban dynamometer driving schedule. Overall, the study provided updated emission factor data for real-world, in-use operation of LEVs for improved emissions modeling and mobile source inventory development.

Methane mole fraction and δ13C above and below the trade wind inversion at Ascension Island in air sampled by aerial robotics

NASA Astrophysics Data System (ADS)

Brownlow, R.; Lowry, D.; Thomas, R. M.; Fisher, R. E.; France, J. L.; Cain, M.; Richardson, T. S.; Greatwood, C.; Freer, J.; Pyle, J. A.; MacKenzie, A. R.; Nisbet, E. G.

2016-11-01

Ascension Island is a remote South Atlantic equatorial site, ideal for monitoring tropical background CH4. In September 2014 and July 2015, octocopters were used to collect air samples in Tedlar bags from different heights above and below the well-defined Trade Wind Inversion (TWI), sampling a maximum altitude of 2700 m above mean sea level. Sampling captured both remote air in the marine boundary layer below the TWI and also air masses above the TWI that had been lofted by convective systems in the African tropics. Air above the TWI was characterized by higher CH4, but no distinct shift in δ13C was observed compared to the air below. Back trajectories indicate that lofted CH4 emissions from Southern Hemisphere Africa have bulk δ13CCH4 signatures similar to background, suggesting mixed emissions from wetlands, agriculture, and biomass burning. The campaigns illustrate the usefulness of unmanned aerial system sampling and Ascension's value for atmospheric measurement in an understudied region.

Air sampling with solid phase microextraction

NASA Astrophysics Data System (ADS)

Martos, Perry Anthony

There is an increasing need for simple yet accurate air sampling methods. The acceptance of new air sampling methods requires compatibility with conventional chromatographic equipment, and the new methods have to be environmentally friendly, simple to use, yet with equal, or better, detection limits, accuracy and precision than standard methods. Solid phase microextraction (SPME) satisfies the conditions for new air sampling methods. Analyte detection limits, accuracy and precision of analysis with SPME are typically better than with any conventional air sampling methods. Yet, air sampling with SPME requires no pumps, solvents, is re-usable, extremely simple to use, is completely compatible with current chromatographic equipment, and requires a small capital investment. The first SPME fiber coating used in this study was poly(dimethylsiloxane) (PDMS), a hydrophobic liquid film, to sample a large range of airborne hydrocarbons such as benzene and octane. Quantification without an external calibration procedure is possible with this coating. Well understood are the physical and chemical properties of this coating, which are quite similar to those of the siloxane stationary phase used in capillary columns. The log of analyte distribution coefficients for PDMS are linearly related to chromatographic retention indices and to the inverse of temperature. Therefore, the actual chromatogram from the analysis of the PDMS air sampler will yield the calibration parameters which are used to quantify unknown airborne analyte concentrations (ppb v to ppm v range). The second fiber coating used in this study was PDMS/divinyl benzene (PDMS/DVB) onto which o-(2,3,4,5,6- pentafluorobenzyl) hydroxylamine (PFBHA) was adsorbed for the on-fiber derivatization of gaseous formaldehyde (ppb v range), with and without external calibration. The oxime formed from the reaction can be detected with conventional gas chromatographic detectors. Typical grab sampling times were as small as 5 seconds

Inertial impaction air sampling device

DOEpatents

Dewhurst, Katharine H.

1990-01-01

An inertial impactor to be used in an air sampling device for collection of respirable size particles in ambient air which may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry.

Temporalization of Electric Generation Emissions for Improved Representation of Peak Air Quality Episodes

NASA Astrophysics Data System (ADS)

Farkas, C. M.; Moeller, M.; Carlton, A. G.

2013-12-01

Photochemical transport models routinely under predict peak air quality events. This deficiency may be due, in part, to inadequate temporalization of emissions from the electric generating sector. The National Emissions Inventory (NEI) reports emissions from Electric Generating Units (EGUs) by either Continuous Emission Monitors (CEMs) that report hourly values or as an annual total. The Sparse Matrix Operator Kernel Emissions preprocessor (SMOKE), used to prepare emissions data for modeling with the CMAQ air quality model, allocates annual emission totals throughout the year using specific monthly, weekly, and hourly weights according to standard classification code (SCC) and location. This approach represents average diurnal and seasonal patterns of electricity generation but does not capture spikes in emissions due to episodic use as with peaking units or due to extreme weather events. In this project we use a combination of state air quality permits, CEM data, and EPA emission factors to more accurately temporalize emissions of NOx, SO2 and particulate matter (PM) during the extensive heat wave of July and August 2006. Two CMAQ simulations are conducted; the first with the base NEI emissions and the second with improved temporalization, more representative of actual emissions during the heat wave. Predictions from both simulations are evaluated with O3 and PM measurement data from EPA's National Air Monitoring Stations (NAMS) and State and Local Air Monitoring Stations (SLAMS) during the heat wave, for which ambient concentrations of criteria pollutants were often above NAAQS. During periods of increased photochemistry and high pollutant concentrations, it is critical that emissions are most accurately represented in air quality models.

AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

EPA Science Inventory

The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

Using metal ratios to detect emissions from municipal waste incinerators in ambient air pollution data

NASA Astrophysics Data System (ADS)

Font, Anna; de Hoogh, Kees; Leal-Sanchez, Maria; Ashworth, Danielle C.; Brown, Richard J. C.; Hansell, Anna L.; Fuller, Gary W.

2015-07-01

This study aimed to fingerprint emissions from six municipal waste incinerators (MWIs) and then test if these fingerprint ratios could be found in ambient air samples. Stack emissions tests from MWIs comprised As, Cd, Cr, Cu, Pb, Mn, Ni, V and Hg. Those pairs of metals showing good correlation (R > 0.75) were taken as tracers of MWI emissions and ratios calculated: Cu/Pb; Cd/Pb; Cd/Cu and Cr/Pb. Emissions ratios from MWIs differed significantly from those in ambient rural locations and those close to traffic. In order to identify MWI emissions in ambient air two analysis tests were carried out. The first, aimed to explore if MWI emissions dominate the ambient concentrations. The mean ambient ratio of each of the four metal ratios were calculated for six ambient sampling sites within 10 km from a MWI under stable meteorological conditions when the wind blew from the direction of the incinerator. Under these meteorological conditions ambient Cd/Pb was within the range of MWI emissions at one location, two monitoring sites measured mean Cr/Pb ratios representative of the MWI emissions and the four sites measured values of Cu/Pb within the range of MWI emissions. No ambient measurements had mean Cd/Cu ratios within the MWI values. Even though MWI was not the main source determining the ambient metal ratios, possible occasional plume grounding might have occurred. The second test then examined possible plume grounding by identifying the periods when all metal ratios differed from rural and traffic values at the same time and were consistent with MWI emissions. Metal ratios consistent with MWI emissions were found in ambient air within 10 km of one MWI for about 0.2% of study period. Emissions consistent with a second MWI were similarly detected at two ambient measurement sites about 0.1% and 0.02% of the time. Where plume grounding was detected, the maximum annual mean particulate matter (PM) from the MWI was estimated to be 0.03 μg m-3 to 0.12 μg m-3; 2-3 orders of

Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

NASA Astrophysics Data System (ADS)

Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

2017-12-01

Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

Shipping emissions and their impacts on air quality in China.

PubMed

Zhang, Yan; Yang, Xin; Brown, Richard; Yang, Liping; Morawska, Lidia; Ristovski, Zoran; Fu, Qingyan; Huang, Cheng

2017-03-01

China has >400 ports, is home to 7 of 10 biggest ports in the world and its waterway infrastructure construction has been accelerating over the past years. But the increasing number of ports and ships means increasing emissions, and in turn, increasing impact on local and regional air pollution. This paper presents an overview of the broad field of ship emissions in China and their atmospheric impacts, including topics of ship engine emissions and control, ship emission factors and their measurements, developing of ship emission inventories, shipping and port emissions of the main shipping areas in China, and quantitative contribution of shipping emissions to the local and regional air pollution. There have been an increasing number of studies published on all the above aspects, yet, this review identified some critical research gaps, filling of which is necessary for better control of ship emissions, and for lowering their impacts. In particular, there are very few studies on inland ports and river ships, and there are few national scale ship emission inventories available for China. While advanced method to estimate ship emission based on ship AIS activities makes it now possible to develop high spatial- and temporal-resolution emission inventories, the ship emission factors used in Chinese studies have been based mainly on foreign measurements. Further, the contribution of ship emissions to air pollution in coastal cities, the dispersion of pollution plumes emitted by ships, or the chemical evolution process along the transmission path, have so far not been systematically studied in China. Copyright © 2016 Elsevier B.V. All rights reserved.

Emission measurements for a lean premixed propane/air system at pressures up to 30 atmospheres

NASA Technical Reports Server (NTRS)

Roffe, G.; Venkataramani, K. S.

1978-01-01

The emissions of a lean premixed system of propane/air were measured in a flametube apparatus. Tests were conducted at inlet temperatures of 600K and 800K and pressures of 10 atm and 30 atm over a range of equivalence ratios. The data obtained were combined with previous data taken in the same apparatus to correlate nitrogen oxide emissions with operating conditions. Sampling probe design was found to have a pronounced effect on measured CO levels but did not influence measurements. The most effective probe tested was one which combined thermal and pressure quenching of the gas sample.

Biofuels, vehicle emissions, and urban air quality.

PubMed

Wallington, Timothy J; Anderson, James E; Kurtz, Eric M; Tennison, Paul J

2016-07-18

Increased biofuel content in automotive fuels impacts vehicle tailpipe emissions via two mechanisms: fuel chemistry and engine calibration. Fuel chemistry effects are generally well recognized, while engine calibration effects are not. It is important that investigations of the impact of biofuels on vehicle emissions consider the impact of engine calibration effects and are conducted using vehicles designed to operate using such fuels. We report the results of emission measurements from a Ford F-350 fueled with either fossil diesel or a biodiesel surrogate (butyl nonanoate) and demonstrate the critical influence of engine calibration on NOx emissions. Using the production calibration the emissions of NOx were higher with the biodiesel fuel. Using an adjusted calibration (maintaining equivalent exhaust oxygen concentration to that of the fossil diesel at the same conditions by adjusting injected fuel quantities) the emissions of NOx were unchanged, or lower, with biodiesel fuel. For ethanol, a review of the literature data addressing the impact of ethanol blend levels (E0-E85) on emissions from gasoline light-duty vehicles in the U.S. is presented. The available data suggest that emissions of NOx, non-methane hydrocarbons, particulate matter (PM), and mobile source air toxics (compounds known, or suspected, to cause serious health impacts) from modern gasoline and diesel vehicles are not adversely affected by increased biofuel content over the range for which the vehicles are designed to operate. Future increases in biofuel content when accomplished in concert with changes in engine design and calibration for new vehicles should not result in problematic increases in emissions impacting urban air quality and may in fact facilitate future required emissions reductions. A systems perspective (fuel and vehicle) is needed to fully understand, and optimize, the benefits of biofuels when blended into gasoline and diesel.

Inertial impaction air sampling device

DOEpatents

Dewhurst, K.H.

1990-05-22

An inertial impactor is designed which is to be used in an air sampling device for collection of respirable size particles in ambient air. The device may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

Inertial impaction air sampling device

DOEpatents

Dewhurst, K.H.

1987-12-10

An inertial impactor to be used in an air sampling device for collection of respirable size particles in ambient air which may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

Development and evaluation of a lightweight sensor system for emission sampling from open area sources

EPA Science Inventory

A new sensor system for mobile and aerial emission sampling was developed for open area sources, such as open burning. The sensor system, termed “Kolibri”, consists of multiple low-cost air quality sensors measuring CO2, CO, and black carbon, samplers for particulate matter with ...

EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN BURNING

EPA Science Inventory

A detailed literature search was performed to collect and collate available data reporting emissions of toxic organic substances into the air from open burning sources. Availability of data varied according to the source and the class of air toxics of interest. Volatile organic c...

Clean Air Markets - Part 75 Emissions Monitoring Policy Manual

EPA Pesticide Factsheets

Learn about monitoring mass sulfur dioxide and mass carbon dioxide emissions, nitrogen oxide emission rate, and heat input by units affected by the Acid Rain Program and the Clean Air Interstate Rule.

Hydrogen/Air Fuel Nozzle Emissions Experiments

NASA Technical Reports Server (NTRS)

Smith, Timothy D.

2001-01-01

The use of hydrogen combustion for aircraft gas turbine engines provides significant opportunities to reduce harmful exhaust emissions. Hydrogen has many advantages (no CO2 production, high reaction rates, high heating value, and future availability), along with some disadvantages (high current cost of production and storage, high volume per BTU, and an unknown safety profile when in wide use). One of the primary reasons for switching to hydrogen is the elimination of CO2 emissions. Also, with hydrogen, design challenges such as fuel coking in the fuel nozzle and particulate emissions are no longer an issue. However, because it takes place at high temperatures, hydrogen-air combustion can still produce significant levels of NOx emissions. Much of the current research into conventional hydrocarbon-fueled aircraft gas turbine combustors is focused on NOx reduction methods. The Zero CO2 Emission Technology (ZCET) hydrogen combustion project will focus on meeting the Office of Aerospace Technology goal 2 within pillar one for Global Civil Aviation reducing the emissions of future aircraft by a factor of 3 within 10 years and by a factor of 5 within 25 years. Recent advances in hydrocarbon-based gas turbine combustion components have expanded the horizons for fuel nozzle development. Both new fluid designs and manufacturing technologies have led to the development of fuel nozzles that significantly reduce aircraft emissions. The goal of the ZCET program is to mesh the current technology of Lean Direct Injection and rocket injectors to provide quick mixing, low emissions, and high-performance fuel nozzle designs. An experimental program is planned to investigate the fuel nozzle concepts in a flametube test rig. Currently, a hydrogen system is being installed in cell 23 at NASA Glenn Research Center's Research Combustion Laboratory. Testing will be conducted on a variety of fuel nozzle concepts up to combustion pressures of 350 psia and inlet air temperatures of 1200 F

Improving the City-scale Emission Inventory of Anthropogenic Air Pollutants: A Case Study of Nanjing

NASA Astrophysics Data System (ADS)

Qiu, L.; Zhao, Y.; Xu, R.; Xie, F.; Wang, H.; Qin, H.; Wu, X.; Zhang, J.

2014-12-01

To evaluate the improvement of city-scale emission inventory, a high-resolution emission inventory of air pollutants for Nanjing is first developed combining detailed source information, and then justified through quantitative analysis with observations. The best available domestic emission factors and unit-/facility-based activity level data were compiled based on a thorough field survey on major emission sources. Totally 1089 individual emission sources were identified as point sources and all the emission-related parameters including burner type, combustion technology, fuel quality, and removal efficiency of pollution control devices, are carefully investigated and analyzed. Some new data such as detailed information of city fueling-gas stations, construction sites, monthly activity level, data from continuous emission monitoring systems and traffic flow information were combined to improve spatiotemporal distribution of this inventory. For SO2, NOX and CO, good spatial correlations were found between ground observation (9 state controlling air sampling sites in Nanjing) and city-scale emission inventory (R2=0.34, 0.38 and 0.74, respectively). For TSP, PM10 and PM2.5, however, poorer correlation was found due to relatively weaker accuracy in emission estimation and spatial distribution of road dust. The mixing ratios between specific pollutants including OC/EC, BC/CO and CO2/CO, are well correlated between those from ground observation and emission. Compared to MEIC (Multi-resolution Emission Inventory for China), there is a better spatial consistence between this city-scale emission inventory and NO2 measured by OMI (Ozone Monitoring Instrument). In particular, the city-scale emission inventory still correlated well with satellite observations (R2=0.28) while the regional emission inventory showed little correlation with satellite observations (R2=0.09) when grids containing power plants are excluded. It thus confirms the improvement of city-scale emission

Air Sampling Filter

NASA Technical Reports Server (NTRS)

1980-01-01

General Metal Works' Accu-Vol is a high-volume air sampling system used by many government agencies to monitor air quality for pollution control purposes. Procedure prevents possible test-invalidating contamination from materials other than particulate pollutants, caused by manual handling or penetration of windblown matter during transit, a cassette was developed in which the filter is sealed within a metal frame and protected in transit by a snap-on aluminum cover, thus handled only under clean conditions in the laboratory.

Influence of Self-emissions on a Mobile Laboratory and Implications for Urban Sampling

NASA Astrophysics Data System (ADS)

Wendt, L. P.

2017-12-01

The importance of urban systems as a large source of greenhouse gases has led to an increase in ground-based campaigns designed to identify and quantify sources. However, plume emissions from vehicle tailpipes can affect emissions for a stationary vehicle or if a tailwind lofts the plume over the car particularly in an urban canyons where wind flow is constrained [1]. Advances in battery technology allow for electric vehicles to sample without self-emissions. Chevrolet has released the Bolt with an estimated range of 238 miles per charge. We are designing a mobile lab using a Chevrolet Bolt with the sensors 5 ft above the ground to reduce drag. Here we investigate the occurrence of self-emissions from a gasoline mobile laboratory set-up that has been optimized to reduce self-emissions and the potential benefits of switching to an electric vehicle for urban sampling. A 2002 Toyota Sienna van and a Licor 7500 CO2/H2O analyzer were deployed to quantify self-emissions. A custom-designed rack elevated the sensors to a height of 8 feet above the tailpipe to minimize self-emission samples [1]. Emissions were sampled over 5 intervals near a relatively isolated field with the van oriented in five directions. A south-easterly wind ( 131o) provided a self-sample opportunity by orienting the car with the tailpipe between the oncoming wind and the sensors. Over 1.5 hours of measurement, 7.8 % of CO2 measurements exceeded 420 ppmv. Of these, four possible self-sample events were observed, or less than 1% with other enhancements attributed to passing cars. These were observed in mild wind conditions averaging 2.8 m/s and only with the tail pipe directly facing into the wind. Results suggest that self-sampling is small in an environment with mild sustained winds and open surroundings. Given the challenge of identifying self-emissions in an isolated environment, urban self-sampling could impact the overall sample especially as these signals may be hard to distinguish from the

Dynamic Evaluation of Regional Air Quality Model's Response to Emission Reductions in the Presence of Uncertain Emission Inventories

EPA Science Inventory

A method is presented and applied for evaluating an air quality model’s changes in pollutant concentrations stemming from changes in emissions while explicitly accounting for the uncertainties in the base emission inventory. Specifically, the Community Multiscale Air Quality (CMA...

Extractive sampling and optical remote sensing of F100 aircraft engine emissions.

PubMed

Cowen, Kenneth; Goodwin, Bradley; Joseph, Darrell; Tefend, Matthew; Satola, Jan; Kagann, Robert; Hashmonay, Ram; Spicer, Chester; Holdren, Michael; Mayfield, Howard

2009-05-01

The Strategic Environmental Research and Development Program (SERDP) has initiated several programs to develop and evaluate techniques to characterize emissions from military aircraft to meet increasingly stringent regulatory requirements. This paper describes the results of a recent field study using extractive and optical remote sensing (ORS) techniques to measure emissions from six F-15 fighter aircraft. Testing was performed between November 14 and 16, 2006 on the trim-pad facility at Tyndall Air Force Base in Panama City, FL. Measurements were made on eight different F100 engines, and the engines were tested on-wing of in-use aircraft. A total of 39 test runs were performed at engine power levels that ranged from idle to military power. The approach adopted for these tests involved extractive sampling with collocated ORS measurements at a distance of approximately 20-25 nozzle diameters downstream of the engine exit plane. The emission indices calculated for carbon dioxide, carbon monoxide, nitric oxide, and several volatile organic compounds showed very good agreement when comparing the extractive and ORS sampling methods.

AIR TOXICS EMISSIONS FROM ELECTRONICS INCINERATION

EPA Science Inventory

The purpose of this project is to examine the emissions of air toxics from the combustion of electronics equipment, primarily personal computer components. Due to a shortage of recycling programs for personal computers and other personal electronics equipment, most of these mate...

High-performance liquid chromatographic determination of benzil in air as an indicator of emissions derived from polyester powder coatings.

PubMed

Pukkila, J; Kokotti, H; Peltonen, K

1989-10-06

A method to estimate occupational exposure to emissions from the curing of polyester powder paints was developed. The method is based on the monitoring only of a certain marker compound in workroom air in order to make the determinations easier. Benzil, reproducibly emitted from all the powders tested, was chosen as the indicator for curing (220 degrees C)-derived emissions. A method for the air sampling and high-performance liquid chromatographic benzil is described. Aspects of the use of marker compounds are discussed.

A STUDY OF EXTRACTIVE AND REMOTE-SENSING SAMPLING AND MEASUREMENT OF EMISSIONS FROM MILITARY AIRCRAFT ENGINES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn; Corporan, E.

2010-01-01

Aircraft emissions contribute to the increased atmospheric burden of particulate matter (e.g., black carbon and secondary organic compounds) that plays a role in air quality, contrail formation and climate change. Sampling and measurement of modern aircraft emissions at the engine exhaust plane (EEP) for to engine and fuel certification remains a daunting task, no agency-certified method is available for the task. In this paper we summarize the results of a recent study that was devoted to investigate both extractive and optical remote-sensing (ORS) technologies in sampling and measurement of gaseous and particulate matter (PM) emitted by a number of militarymore » aircraft engines operated with JP-8 and a Fischer-Tropsch (FT) fuel at various engine conditions. These engines include cargo, bomber, and helicopter types of military aircraft that consumes 70-80% of the military aviation fuel each year. The emission indices of selected pollutants are discussed as these data may be of interest for atmospheric modeling and for design of air quality control strategies around the airports and military bases. It was found that non-volatile particles in the engine emissions were all in the ultrafine range. The mean diameter of particles increased as the engine power increased; the mode diameters were in the 20nm range for the low power condition of a new helicopter engine to 80nm for the high power condition of a newly maintained bomber engine. Elemental analysis indicated little metals were present on particles in the exhaust, while most of the materials on the exhaust particles were based on carbon and sulfate. Carbon monoxide, carbon dioxide, nitrogen oxide, sulfur dioxide, formaldehyde, ethylene, acetylene, propylene, and alkanes were detected using both technologies. The last five species (in the air toxics category) were most noticeable only under the low engine power. The emission indices calculated based on the ORS data were however observed to differ significantly

Emission characteristics of kerosene-air spray combustion with plasma assistance

NASA Astrophysics Data System (ADS)

Liu, Xingjian; He, Liming; Zeng, Hao; Jin, Tao; Chen, Yi; Zhang, Yihan; Liu, Pengfei

2015-09-01

A plasma assisted combustion system for combustion of kerosene-air mixtures was developed to study emission levels of O2, CO2, CO, and NOx. The emission measurement was conducted by Testo 350-Pro Flue Gas Analyzer. The effect of duty ratio, feedstock gas flow rate and applied voltage on emission performance has been analyzed. The results show that O2 and CO emissions reduce with an increase of applied voltage, while CO2 and NOx emissions increase. Besides, when duty ratio or feedstock gas flow rate decreases, the same emission results would appear. The emission spectrum of the air plasma of plasma assisted combustion actuator was also registered to analyze the kinetic enhancement effect of plasma, and the generation of ozone was believed to be the main factor that plasma makes a difference in our experiment. These results are valuable for the future optimization of kerosene-fueled aircraft engine when using plasma assisted combustion devices to exert emission control.

Emission characteristics of harmful air pollutants from cremators in Beijing, China

PubMed Central

Xue, Yifeng; Cheng, Linglong; Chen, Xi; Zhai, Xiaoman; Wang, Wei; Zhang, Wenjie; Bai, Yan; Tian, Hezhong; Nie, Lei; Zhang, Shihao; Wei, Tong

2018-01-01

The process of corpse cremation generates numerous harmful air pollutants, including particulate matter (PM), sulfur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOCs), and heavy metals. These pollutants could have severe effects on the surrounding environment and human health. Currently, the awareness of the emission levels of harmful air pollutants from cremators and their emission characteristics is insufficient. In this study, we obtained the emission characteristics of flue gas from cremators in Beijing and determined the localized emission factors and emission levels of harmful air pollutants based on actual monitoring data from nine typical cremators. The results show that the emissions of air pollutants from the cremators that directly discharge flue gas exceed the emission standards of China and Beijing. The installation of a flue gas post-treatment system could effectively reduce gaseous pollutants and the emission levels of PM. After being equipped with a flue gas post-treatment system, the emission concentrations of PM10, PM2.5, CO, SO2 and VOCs from the cremators are reduced by 97.6, 99.2, 19.6, 85.2 and 70.7%, respectively. Moreover, the emission factors of TSP, PM10, PM2.5, CO, SO2 and VOCs are also reduced to 12.5, 9.3, 3.0, 164.1, 8.8 and 19.8 g/body. Although the emission concentration of VOCs from the cremators is not high, they are one of major sources of “odor” in the crematories and demand more attention. Benzene, a chemical that can seriously harm human health, constitutes the largest proportion (~50%) of the chemical components of VOCs in the flue gas from the cremators. PMID:29718907

Emission characteristics of harmful air pollutants from cremators in Beijing, China.

PubMed

Xue, Yifeng; Cheng, Linglong; Chen, Xi; Zhai, Xiaoman; Wang, Wei; Zhang, Wenjie; Bai, Yan; Tian, Hezhong; Nie, Lei; Zhang, Shihao; Wei, Tong

2018-01-01

The process of corpse cremation generates numerous harmful air pollutants, including particulate matter (PM), sulfur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOCs), and heavy metals. These pollutants could have severe effects on the surrounding environment and human health. Currently, the awareness of the emission levels of harmful air pollutants from cremators and their emission characteristics is insufficient. In this study, we obtained the emission characteristics of flue gas from cremators in Beijing and determined the localized emission factors and emission levels of harmful air pollutants based on actual monitoring data from nine typical cremators. The results show that the emissions of air pollutants from the cremators that directly discharge flue gas exceed the emission standards of China and Beijing. The installation of a flue gas post-treatment system could effectively reduce gaseous pollutants and the emission levels of PM. After being equipped with a flue gas post-treatment system, the emission concentrations of PM10, PM2.5, CO, SO2 and VOCs from the cremators are reduced by 97.6, 99.2, 19.6, 85.2 and 70.7%, respectively. Moreover, the emission factors of TSP, PM10, PM2.5, CO, SO2 and VOCs are also reduced to 12.5, 9.3, 3.0, 164.1, 8.8 and 19.8 g/body. Although the emission concentration of VOCs from the cremators is not high, they are one of major sources of "odor" in the crematories and demand more attention. Benzene, a chemical that can seriously harm human health, constitutes the largest proportion (~50%) of the chemical components of VOCs in the flue gas from the cremators.

OFFICE EQUIPMENT: DESIGN, INDOOR AIR EMISSIONS, AND POLLUTION PREVENTION OPPORTUNITIES

EPA Science Inventory

The report summarizes available information on office equipment design; indoor air emissions of organics, ozone, and particulates from office equipment; and pollution prevention approaches for reducing these emissions. Since much of the existing emissions data from office equipme...

Diagnosing AIRS Sampling with CloudSat Cloud Classes

NASA Technical Reports Server (NTRS)

Fetzer, Eric; Yue, Qing; Guillaume, Alexandre; Kahn, Brian

2011-01-01

AIRS yield and sampling vary with cloud state. Careful utilization of collocated multiple satellite sensors is necessary. Profile differences between AIRS and ECMWF model analyses indicate that AIRS has high sampling and excellent accuracy for certain meteorological conditions. Cloud-dependent sampling biases may have large impact on AIRS L2 and L3 data in climate research. MBL clouds / lower tropospheric stability relationship is one example. AIRS and CloudSat reveal a reasonable climatology in the MBL cloud regime despite limited sampling in stratocumulus. Thermodynamic parameters such as EIS derived from AIRS data map these cloud conditions successfully. We are working on characterizing AIRS scenes with mixed cloud types.

Development and evaluation of a lightweight sensor system for aerial emission sampling from open area sources

EPA Science Inventory

A new sensor system for mobile and aerial emission sampling was developed for open area pollutant sources, such as prescribed forest burns. The sensor system, termed “Kolibri”, consists of multiple low-cost air quality sensors measuring CO2, CO, samplers for particulate matter wi...

U.S. emissions of HFC-134a derived for 2008-2012 from an extensive flask-air sampling network

NASA Astrophysics Data System (ADS)

Hu, Lei; Montzka, Stephen A.; Miller, John B.; Andrews, Aryln E.; Lehman, Scott J.; Miller, Benjamin R.; Thoning, Kirk; Sweeney, Colm; Chen, Huilin; Godwin, David S.; Masarie, Kenneth; Bruhwiler, Lori; Fischer, Marc L.; Biraud, Sebastien C.; Torn, Margaret S.; Mountain, Marikate; Nehrkorn, Thomas; Eluszkiewicz, Janusz; Miller, Scot; Draxler, Roland R.; Stein, Ariel F.; Hall, Bradley D.; Elkins, James W.; Tans, Pieter P.

2015-01-01

national and regional emissions of HFC-134a are derived for 2008-2012 based on atmospheric observations from ground and aircraft sites across the U.S. and a newly developed regional inverse model. Synthetic data experiments were first conducted to optimize the model assimilation design and to assess model-data mismatch errors and prior flux error covariances computed using a maximum likelihood estimation technique. The synthetic data experiments also tested the sensitivity of derived national and regional emissions to a range of assumed prior emissions, with the goal of designing a system that was minimally reliant on the prior. We then explored the influence of additional sources of error in inversions with actual observations, such as those associated with background mole fractions and transport uncertainties. Estimated emissions of HFC-134a range from 52 to 61 Gg yr-1 for the contiguous U.S. during 2008-2012 for inversions using air transport from Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model driven by the 12 km resolution meteorogical data from North American Mesoscale Forecast System (NAM12) and all tested combinations of prior emissions and background mole fractions. Estimated emissions for 2008-2010 were 20% lower when specifying alternative transport from Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by the Weather Research and Forecasting (WRF) meteorology. Our estimates (for HYSPLIT-NAM12) are consistent with annual emissions reported by U.S. Environmental Protection Agency for the full study interval. The results suggest a 10-20% drop in U.S. national HFC-134a emission in 2009 coincident with a reduction in transportation-related fossil fuel CO2 emissions, perhaps related to the economic recession. All inversions show seasonal variation in national HFC-134a emissions in all years, with summer emissions greater than winter emissions by 20-50%.

Air sampling workshop: October 24-25, 1978

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-06-01

A two-day workshop was held in October 1978 on air sampling strategies for the occupational environment. Strategies comprise the elements of implementing an air sampling program including deciding on the extent of sampling, selecting appropriate types of measurement, placing sampling instruments properly, and interpreting sample results correctly. All of these elements are vital in the reliable assessment of occupational exposures yet their coverage in the industrial hygiene literature is meager. Although keyed to a few introductory topics, the agenda was sufficiently informal to accommodate extemporaneous discussion on any subject related to sampling strategies. Questions raised during the workshop mirror themore » status of air sampling strategy as much as the factual information that was presented. It may be concluded from the discussion and questions that air sampling strategy is an elementary state and urgently needs concerted attention from the industrial hygiene profession.« less

Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) Model-I: building an emissions data base

NASA Astrophysics Data System (ADS)

Smith, S. N.; Mueller, S. F.

2010-05-01

A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates non-methane volatile organic compound (NMVOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, windblown dust particulate, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (NMVOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere

Volcanic gas emissions and their impact on ambient air character at Kilauea Volcano, Hawaii

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sutton, A.J.; Elias, T.; Navarrete, R.

1994-12-31

Gas emissions from Kilauea occur from the summit caldera, along the middle East Rift Zone (ERZ), and where lava enters the ocean. We estimate that the current ERZ eruption of Kilauea releases between 400 metric tonnes of SO{sub 2} per day, during eruptive pauses, to as much as 1850 metric tonnes per day during actively erupting periods, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl and HF. In order to characterize gas emissions from Kilauea in a meaningful way for assessing environmental impact, we made a series of replicate grab-sample measurements of ambientmore » air and precipitation at the summit of Kilauea, along its ERZ, and at coastal sites where lava enters the ocean. The grab-sampling data combined with SO{sub 2} emission rates, and continuous air quality and meteorological monitoring at the summit of Kilauea show that the effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Prevailing tradewinds typically carry the gases and aerosols released to the southwest, where they are further distributed by the regional wind regime. Episodes of kona, or low speed variable winds sometimes disrupt this pattern, however, and allow the gases and their oxidation products to collect at the summit and eastern side of the island. Summit solfatara areas of Kilauea are distinguished by moderate to high ambient SO{sub 2}, high H{sub 2}S at one location, and low H{sub 2}S at all others, and negligible HCl concentrations, as measured 1 m from degassing point-sources. Summit solfatara rain water has high sulfate and low chloride ion concentrations, and low pH.« less

Assessing Potential Air Pollutant Emissions from Agricultural Feedstock Production using MOVES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eberle, Annika; Warner, Ethan; Zhang, Yi Min

Biomass feedstock production is expected to grow as demand for biofuels and bioenergy increases. The change in air pollutant emissions that may result from large-scale biomass supply has implications for local air quality and human health. We developed spatially explicit emissions inventories for corn grain and six cellulosic feedstocks through the extension of the National Renewable Energy Laboratory's Feedstock Production Emissions to Air Model (FPEAM). These inventories include emissions of seven pollutants (nitrogen oxides, ammonia, volatile organic compounds, particulate matter, sulfur oxides, and carbon monoxide) generated from biomass establishment, maintenance, harvest, transportation, and biofuel preprocessing activities. By integrating the EPA'smore » MOtor Vehicle Emissions Simulator (MOVES) into FPEAM, we created a scalable framework to execute county-level runs of the MOVES-Onroad model for representative counties (i.e., those counties with the largest amount of cellulosic feedstock production in each state) on a national scale. We used these results to estimate emissions from the on-road transportation of biomass and combined them with county-level runs of the MOVES-Nonroad model to estimate emissions from agricultural equipment. We also incorporated documented emission factors to estimate emissions from chemical application and the operation of drying equipment for feedstock processing, and used methods developed by the EPA and the California Air Resources Board to estimate fugitive dust emissions. The model developed here could be applied to custom equipment budgets and is extensible to accommodate additional feedstocks and pollutants. Future work will also extend this model to analyze spatial boundaries beyond the county-scale (e.g., regional or sub-county levels).« less

Innovations in projecting emissions for air quality modeling ...

EPA Pesticide Factsheets

Air quality modeling is used in setting air quality standards and in evaluating their costs and benefits. Historically, modeling applications have projected emissions and the resulting air quality only 5 to 10 years into the future. Recognition that the choice of air quality management strategy has climate change implications is encouraging longer modeling time horizons. However, for multi-decadal time horizons, many questions about future conditions arise. For example, will current population, economic, and land use trends continue, or will we see shifts that may alter the spatial and temporal pattern of emissions? Similarly, will technologies such as building-integrated solar photovoltaics, battery storage, electric vehicles, and CO2 capture emerge as disruptive technologies - shifting how we produce and use energy - or will these technologies achieve only niche markets and have little impact? These are some of the questions that are being evaluated by researchers within the U.S. EPA’s Office of Research and Development. In this presentation, Dr. Loughlin will describe a range of analytical approaches that are being explored. These include: (i) the development of alternative scenarios of the future that can be used to evaluate candidate management strategies over wide-ranging conditions, (ii) the application of energy system models to project emissions decades into the future and to assess the environmental implications of new technologies, (iii) and methodo

An exploratory study of air emissions associated with shale gas development and production in the Barnett Shale.

PubMed

Rich, Alisa; Grover, James P; Sattler, Melanie L

2014-01-01

Information regarding air emissions from shale gas extraction and production is critically important given production is occurring in highly urbanized areas across the United States. Objectives of this exploratory study were to collect ambient air samples in residential areas within 61 m (200 feet) of shale gas extraction/production and determine whether a "fingerprint" of chemicals can be associated with shale gas activity. Statistical analyses correlating fingerprint chemicals with methane, equipment, and processes of extraction/production were performed. Ambient air sampling in residential areas of shale gas extraction and production was conducted at six counties in the Dallas/Fort Worth (DFW) Metroplex from 2008 to 2010. The 39 locations tested were identified by clients that requested monitoring. Seven sites were sampled on 2 days (typically months later in another season), and two sites were sampled on 3 days, resulting in 50 sets of monitoring data. Twenty-four-hour passive samples were collected using summa canisters. Gas chromatography/mass spectrometer analysis was used to identify organic compounds present. Methane was present in concentrations above laboratory detection limits in 49 out of 50 sampling data sets. Most of the areas investigated had atmospheric methane concentrations considerably higher than reported urban background concentrations (1.8-2.0 ppm(v)). Other chemical constituents were found to be correlated with presence of methane. A principal components analysis (PCA) identified multivariate patterns of concentrations that potentially constitute signatures of emissions from different phases of operation at natural gas sites. The first factor identified through the PCA proved most informative. Extreme negative values were strongly and statistically associated with the presence of compressors at sample sites. The seven chemicals strongly associated with this factor (o-xylene, ethylbenzene, 1,2,4-trimethylbenzene, m- and p-xylene, 1

Impact of Trans-Boundary Emissions on Modelled Air Pollution in Canada

NASA Astrophysics Data System (ADS)

Pavlovic, Radenko; Moran, Mike; Zhang, Junhua; Zheng, Qiong; Menard, Sylvain; Anselmo, David; Davignon, Didier

2014-05-01

The operational air quality model GEM-MACH is run twice daily at the Canadian Meteorological Centre in Montreal, Quebec to produce 48-hour forecasts of hourly O3, NO2, and PM2.5 fields over a North American domain. The hourly gridded anthropogenic emissions fields needed by GEM-MACH are currently based on the 2006 Canadian emissions inventory, a 2012 projected U.S. inventory, and the 1999 Mexican inventory. The Sparse Matrix Operator Kernel Emissions (SMOKE) processing package was used to process these three national emissions inventories to create the GEM-MACH emissions fields. While Canada is the second-largest country in the world by total area, its population and its emissions of criteria contaminants are both only about one-tenth of U.S. values and roughly 80% of the Canadian population lives within 150 km of the international border with the U.S. As a consequence, transboundary transport of air pollution has a major impact on air quality in Canada. To quantify the impact of non-Canadian emissions on forecasted pollutant levels in Canada, the following two tests were performed: (a) all U.S. and Mexican anthropogenic emissions were switched off; and (b) anthropogenic emissions from the southernmost tier of U.S. states and Mexico were switched off. These sensitivity tests were performed for the summer and winter periods of 2012 or 2011. The results obtained show that the impact of non-Canadian sources on forecasted pollution is generally larger in summer than in winter, especially in south-eastern parts of Canada. For the three pollutants considered in the Canadian national Air Quality Health Index, PM2.5 is impacted the most (up to 80%) and NO2 the least (<10%). Emissions from the southern U.S. and Mexico do impact Canadian air quality, but the sign may change depending on the season (i.e., increase vs. decrease), reflecting chemical processing en route.

Comparison of emissions inventories of anthropogenic air pollutants and greenhouse gases in China

NASA Astrophysics Data System (ADS)

Saikawa, Eri; Kim, Hankyul; Zhong, Min; Avramov, Alexander; Zhao, Yu; Janssens-Maenhout, Greet; Kurokawa, Jun-ichi; Klimont, Zbigniew; Wagner, Fabian; Naik, Vaishali; Horowitz, Larry W.; Zhang, Qiang

2017-05-01

Anthropogenic air pollutant emissions have been increasing rapidly in China, leading to worsening air quality. Modelers use emissions inventories to represent the temporal and spatial distribution of these emissions needed to estimate their impacts on regional and global air quality. However, large uncertainties exist in emissions estimates. Thus, assessing differences in these inventories is essential for the better understanding of air pollution over China. We compare five different emissions inventories estimating emissions of carbon dioxide (CO2), carbon monoxide (CO), nitrogen oxides (NOx), sulfur dioxide (SO2), and particulate matter with an aerodynamic diameter of 10 µm or less (PM10) from China. The emissions inventories analyzed in this paper include the Regional Emission inventory in ASia v2.1 (REAS), the Multi-resolution Emission Inventory for China (MEIC), the Emission Database for Global Atmospheric Research v4.2 (EDGAR), the inventory by Yu Zhao (ZHAO), and the Greenhouse Gas and Air Pollution Interactions and Synergies (GAINS). We focus on the period between 2000 and 2008, during which Chinese economic activities more than doubled. In addition to national totals, we also analyzed emissions from four source sectors (industry, transport, power, and residential) and within seven regions in China (East, North, Northeast, Central, Southwest, Northwest, and South) and found that large disagreements exist among the five inventories at disaggregated levels. These disagreements lead to differences of 67 µg m-3, 15 ppbv, and 470 ppbv for monthly mean PM10, O3, and CO, respectively, in modeled regional concentrations in China. We also find that all the inventory emissions estimates create a volatile organic compound (VOC)-limited environment and MEIC emissions lead to much lower O3 mixing ratio in East and Central China compared to the simulations using REAS and EDGAR estimates, due to their low VOC emissions. Our results illustrate that a better

Analysis of enantiomeric and non-enantiomeric monoterpenes in plant emissions using portable dynamic air sampling/solid-phase microextraction (PDAS-SPME) and chiral gas chromatography/mass spectrometry

NASA Astrophysics Data System (ADS)

Yassaa, Noureddine; Williams, Jonathan

A portable dynamic air sampler (PDAS) using a porous polymer solid-phase microextraction (SPME) fibre has been validated for the determination of biogenic enantiomeric and non-enantiomeric monoterpenes in air. These compounds were adsorbed in the field, and then thermally desorbed at 250 °C in a gas chromatograph injector port connected via a β-cyclodextrin capillary separating column to a mass spectrometer. The optimized method has been applied for investigating the emissions of enantiomeric monoterpenes from Pseudotsuga menziesii (Douglas-fir), Rosmarinus officinalis (Rosemary) and Lavandula lanata (Lavender) which were selected as representative of coniferous trees and aromatic plants, respectively. The enantiomers of α-pinene, sabinene, camphene, δ-3-carene, β-pinene, limonene, β-phellandrene, 4-carene and camphor were successfully determined in the emissions from the three plants. While Douglas-fir showed a strong predominance toward (-)-enantiomers, Rosemary and Lavender demonstrated a large variation in enantiomeric distribution of monoterpenes. The simplicity, rapidity and sensitivity of dynamic sampling with porous polymer coated SPME fibres coupled to chiral capillary gas chromatography/mass spectrometry (GC/MS) makes this method potentially useful for in-field investigations of atmosphere-biosphere interactions and studies of optically explicit atmospheric chemistry.

HVAC SYSTEMS AS EMISSION SOURCES AFFECTING INDOOR AIR QUALITY: A CRITICAL REVIEW

EPA Science Inventory

The study evaluates heating, ventilating, and air-conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). Various literature sources and methods for characterizing HVAC emission sources are reviewed. Available methods include in situ test...

Regional emissions of air pollutants in China.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Streets, D. G.

1998-10-05

As part of the China-MAP program, sponsored by the US National Aeronautics and Space Administration, regional inventories of air pollutants emitted in China are being characterized, in order that the atmospheric chemistry over China can be more fully understood and the resulting ambient concentrations in Chinese cities and the deposition levels to Chinese ecosystems be determined with better confidence. In addition, the contributions of greenhouse gases from China and of acidic aerosols that counteract global warming are being quantified. This paper presents preliminary estimates of the emissions of some of the major air pollutants in China: sulfur dioxide (SO{sub 2}),more » nitrogen oxides (NO{sub x}), carbon monoxide (CO), and black carbon (C). Emissions are estimated for each of the 27 regions of China included in the RAINS-Asia simulation model and are subsequently distributed to a 1{degree} x 1{degree} grid using appropriate disaggregation factors. Emissions from all sectors of the Chinese economy are considered, including the combustion of biofuels in rural homes. Emissions from larger power plants are calculated individually and allocated to the grid accordingly. Data for the period 1990-1995 are being developed, as well as projections for the future under alternative assumptions about economic growth and environmental control.« less

Assessment of the emissions and air quality impacts of biomass and biogas use in California.

PubMed

Carreras-Sospedra, Marc; Williams, Robert; Dabdub, Donald

2016-02-01

It is estimated that there is sufficient in-state "technically" recoverable biomass to support nearly 4000 MW of bioelectricity generation capacity. This study assesses the emissions of greenhouse gases and air pollutants and resulting air quality impacts of new and existing bioenergy capacity throughout the state of California, focusing on feedstocks and advanced technologies utilizing biomass resources predominant in each region. The options for bioresources include the production of bioelectricity and renewable natural gas (NG). Emissions of criteria pollutants and greenhouse gases are quantified for a set of scenarios that span the emission factors for power generation and the use of renewable natural gas for vehicle fueling. Emissions are input to the Community Multiscale Air Quality (CMAQ) model to predict regional and statewide temporal air quality impacts from the biopower scenarios. With current technology and at the emission levels of current installations, maximum bioelectricity production could increase nitrogen oxide (NOx) emissions by 10% in 2020, which would cause increases in ozone and particulate matter concentrations in large areas of California. Technology upgrades would achieve the lowest criteria pollutant emissions. Conversion of biomass to compressed NG (CNG) for vehicles would achieve comparable emission reductions of criteria pollutants and minimize emissions of greenhouse gases (GHG). Air quality modeling of biomass scenarios suggest that applying technological changes and emission controls would minimize the air quality impacts of bioelectricity generation. And a shift from bioelectricity production to CNG production for vehicles would reduce air quality impacts further. From a co-benefits standpoint, CNG production for vehicles appears to provide the best benefits in terms of GHG emissions and air quality. This investigation provides a consistent analysis of air quality impacts and greenhouse gas emissions for scenarios examining

Air pollution in Latin America: Bottom-up Vehicular Emissions Inventory and Atmospheric Modeling

NASA Astrophysics Data System (ADS)

Ibarra Espinosa, S.; Vela, A. V.; Calderon, M. G.; Carlos, G.; Ynoue, R.

2016-12-01

Air pollution is a global environmental and health problem. Population of Latin America are facing air quality risks due to high level of air pollution. According to World Health Organization (WHO; 2016), several Latin American cities have high level of pollution. Emissions inventories are a key tool for air quality, however they normally present lack of quality and adequate documentation in developing countries. This work aims to develop air quality assessments in Latin American countries by 1) develop a high resolution emissions inventory of vehicles, and 2) simulate air pollutant concentrations. The bottom-up vehicular emissions inventory used was obtained with the REMI model (Ibarra et al., 2016) which allows to interpolate traffic over road network of Open Street Map to estimate vehicular emissions 24-h, each day of the week. REMI considers several parameters, among them the average age of fleet which was associated with gross domestic product (GDP) per capita. The estimated pollutants are CO, NOx, HC, PM2.5, NO, NO2, CO2, N2O, COV, NH3 and Fuel Consumption. The emissions inventory was performed at the biggest cities, including every capital of Latin America's countries. Initial results shows that the cities with most CO emissions are Buenos Aires 162800 (t/year), São Paulo 152061 (t/year), Campinas 151567 (t/year) and Brasilia 144332 (t/year). The results per capita shows that the city with most CO emissions per capita is Campinas, with 130 (kgCO/hab/year), showed in figure 1. This study also cover high resolution air quality simulations with WRF-Chem main cities in Latin America. Results will be assessed comparing: fuel estimates with local fuel sales, traffic count interpolation with available traffic data set at each city, and comparison between air pollutant simulations with air monitoring observation data. Ibarra, S., R. Ynoue, and S. Mhartain. 2016: "High Resolution Vehicular Emissions Inventory for the Megacity of São Paulo." Manuscript submitted to

76 FR 13514 - National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-14

... National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources AGENCY... Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources. Among the... Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources (CMAS) on October...

Active AirCore Sampling: Constraining Point Sources of Methane and Other Gases with Fixed Wing Unmanned Aerial Systems

NASA Astrophysics Data System (ADS)

Bent, J. D.; Sweeney, C.; Tans, P. P.; Newberger, T.; Higgs, J. A.; Wolter, S.

2017-12-01

Accurate estimates of point source gas emissions are essential for reconciling top-down and bottom-up greenhouse gas measurements, but sampling such sources is challenging. Remote sensing methods are limited by resolution and cloud cover; aircraft methods are limited by air traffic control clearances, and the need to properly determine boundary layer height. A new sampling approach leverages the ability of unmanned aerial systems (UAS) to measure all the way to the surface near the source of emissions, improving sample resolution, and reducing the need to characterize a wide downstream swath, or measure to the full height of the planetary boundary layer (PBL). The "Active-AirCore" sampler, currently under development, will fly on a fixed wing UAS in Class G airspace, spiraling from the surface to 1200 ft AGL around point sources such as leaking oil wells to measure methane, carbon dioxide and carbon monoxide. The sampler collects a 100-meter long sample "core" of air in an 1/8" passivated stainless steel tube. This "core" is run on a high-precision instrument shortly after the UAS is recovered. Sample values are mapped to a specific geographic location by cross-referencing GPS and flow/pressure metadata, and fluxes are quantified by applying Gauss's theorem to the data, mapped onto the spatial "cylinder" circumscribed by the UAS. The AirCore-Active builds off the sampling ability and analytical approach of the related AirCore sampler, which profiles the atmosphere passively using a balloon launch platform, but will add an active pumping capability needed for near-surface horizontal sampling applications. Here, we show design elements, laboratory and field test results for methane, describe the overall goals of the mission, and discuss how the platform can be adapted, with minimal effort, to measure other gas species.

HVAC SYSTEMS AS EMISSION SOURCES AFFECTING INDOOR AIR QUALITY: A CRITICAL REVIEW

EPA Science Inventory

The paper discusses results of an evaluation of literature on heating, ventilating, and air-conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). The various literature sources and methods for characterizing HVAC emission sources are re...

U.S. ozone air quality under changing climate and anthropogenic emissions.

PubMed

Racherla, Pavan N; Adams, Peter J

2009-02-01

We examined future ozone (O3) air quality in the United States (U.S.) under changing climate and anthropogenic emissions worldwide by performing global climate-chemistry simulations, utilizing various combinations of present (1990s) and future (Intergovernmental Panel on Climate Change (IPCC) Special Report on Emissions Scenarios (SRES) A2 2050s) climates, and present and future (2050s; IPCC SRES A2 and B1) anthropogenic emissions. The A2 climate scenario is employed here because it lies at the upper extreme of projected climate change for the 21st century. To examine the sensitivity of U.S. O3 to regional emissions increases (decreases), the IPCC SRES A2 and B1 scenarios, which have overall higher and lower O3-precursor emissions for the U.S., respectively, have been chosen. We find that climate change, by itself, significantly worsens the severity and frequency of high-O3 events ("episodes") over most locations in the U.S., with relatively small changes in average O3 air quality. These high-O3 increases due to climate change alone will erode moderately the gains made under a U.S. emissions reduction scenario (e.g., B1). The effect of climate change on high- and average-O3 increases with anthropogenic emissions. Insofar as average O3 air quality is concerned, changes in U.S. anthropogenic emissions will play the most important role in attaining (or not) near-term U.S. O3 air quality standards. However, policy makers must plan appropriately for O3 background increases due to projected increases in global CH4 abundance and non-U.S. anthropogenic emissions, as well as potential local enhancements that they could cause. These findings provide strong incentives for more-than-planned emissions reductions at locations that are currently O3-nonattainment.

Demonstration of Diesel Engine Air Emissions Reduction Technologies

DTIC Science & Technology

2008-12-01

16 Figure 5. Plots of Cheyenne Mountain Operating Cycle and Reference CBD Driving...Air Act CARB California Air Resources Board CBD Central Business District CCR California Code of Regulations CES Cummins Emissions Solutions CFR...matter ppb parts per billion ppm parts per million PuriNOx Proprietary Water / Diesel Emulsified Fuel RPF robust particulate filter THC total

Effect of low emission sources on air quality in Cracow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nedoma, J.

1995-12-31

The paper presents calculation of power engineering low emission and results of stimulation of the effect of this emission on air quality in Cracow, Poland. It has been stated that the segment of low emission in central areas of the town makes up ca. 40% of the observed concentration of sulfur dioxide. Furthermore it has been stated that the capital investment must be concentrated in the central part of the town in order to reach noticeable improvement of air quality in Cracow. Neither the output of a separate power source nor the emission level and its individual harmful effect, butmore » the location of the source and especially packing density of the sources must decide the priority of upgrading actions.« less

Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region

PubMed Central

Oikawa, P. Y.; Ge, C.; Wang, J.; Eberwein, J. R.; Liang, L. L.; Allsman, L. A.; Grantz, D. A.; Jenerette, G. D.

2015-01-01

Fertilized soils have large potential for production of soil nitrogen oxide (NOx=NO+NO2), however these emissions are difficult to predict in high-temperature environments. Understanding these emissions may improve air quality modelling as NOx contributes to formation of tropospheric ozone (O3), a powerful air pollutant. Here we identify the environmental and management factors that regulate soil NOx emissions in a high-temperature agricultural region of California. We also investigate whether soil NOx emissions are capable of influencing regional air quality. We report some of the highest soil NOx emissions ever observed. Emissions vary nonlinearly with fertilization, temperature and soil moisture. We find that a regional air chemistry model often underestimates soil NOx emissions and NOx at the surface and in the troposphere. Adjusting the model to match NOx observations leads to elevated tropospheric O3. Our results suggest management can greatly reduce soil NOx emissions, thereby improving air quality. PMID:26556236

Impacts of Energy Sector Emissions on PM2.5 Air Quality in Northern India

NASA Astrophysics Data System (ADS)

Karambelas, A. N.; Kiesewetter, G.; Heyes, C.; Holloway, T.

2015-12-01

India experiences high concentrations of fine particulate matter (PM2.5), and several Indian cities currently rank among the world's most polluted cities. With ongoing urbanization and a growing economy, emissions from different energy sectors remain major contributors to air pollution in India. Emission sectors impact ambient air quality differently due to spatial distribution (typical urban vs. typical rural sources) as well as source height characteristics (low-level vs. high stack sources). This study aims to assess the impacts of emissions from three distinct energy sectors—transportation, domestic, and electricity—on ambient PM2.5­­ in northern India using an advanced air quality analysis framework based on the U.S. EPA Community Multi-Scale Air Quality (CMAQ) model. Present air quality conditions are simulated using 2010 emissions from the Greenhouse Gas-Air Pollution Interaction and Synergies (GAINS) model. Modeled PM2.5 concentrations are compared with satellite observations of aerosol optical depth (AOD) from the Moderate Imaging Spectroradiometer (MODIS) for 2010. Energy sector emissions impacts on future (2030) PM2.5 are evaluated with three sensitivity simulations, assuming maximum feasible reduction technologies for either transportation, domestic, or electricity sectors. These simulations are compared with a business as usual 2030 simulation to assess relative sectoral impacts spatially and temporally. CMAQ is modeled at 12km by 12km and include biogenic emissions from the Community Land Model coupled with the Model of Emissions of Gases and Aerosols in Nature (CLM-MEGAN), biomass burning emissions from the Global Fires Emissions Database (GFED), and ERA-Interim meteorology generated with the Weather Research and Forecasting (WRF) model for 2010 to quantify the impact of modified anthropogenic emissions on ambient PM2.5 concentrations. Energy sector emissions analysis supports decision-making to improve future air quality and public health in

Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

NASA Technical Reports Server (NTRS)

Meng, P. R.; Skorobatckyi, M.; Cosgrove, D. V.; Kempke, E. E., Jr.

1976-01-01

A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

Evaluation of life-cycle air emission factors of freight transportation.

PubMed

Facanha, Cristiano; Horvath, Arpad

2007-10-15

Life-cycle air emission factors associated with road, rail, and air transportation of freight in the United States are analyzed. All life-cycle phases of vehicles, infrastructure, and fuels are accounted for in a hybrid life-cycle assessment (LCA). It includes not only fuel combustion, but also emissions from vehicle manufacturing, maintenance, and end of life, infrastructure construction, operation, maintenance, and end of life, and petroleum exploration, refining, and fuel distribution. Results indicate that total life-cycle emissions of freight transportation modes are underestimated if only tailpipe emissions are accounted for. In the case of CO2 and NOx, tailpipe emissions underestimate total emissions by up to 38%, depending on the mode. Total life-cycle emissions of CO and SO2 are up to seven times higher than tailpipe emissions. Sensitivity analysis considers the effects of vehicle type, geography, and mode efficiency on the final results. Policy implications of this analysis are also discussed. For example, while it is widely assumed that currently proposed regulations will result in substantial reductions in emissions, we find that this is true for NOx, emissions, because fuel combustion is the main cause, and to a lesser extent for SO2, but not for PM10 emissions, which are significantly affected by the other life-cycle phases.

75 FR 80833 - Shipboard Air Emission Reduction Technology Report

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-23

... Reduction Technology Report AGENCY: Coast Guard, DHS. ACTION: Notice and request for comments. SUMMARY: In... Protection Agency, on Ship Emission Reduction Technology for cargo and passenger vessels that operate in... will survey new technology and new applications of existing technology for reducing air emissions from...

Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) model - Part 1: Building an emissions data base

NASA Astrophysics Data System (ADS)

Smith, S. N.; Mueller, S. F.

2010-01-01

A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates volatile organic compound (VOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as windblown dust and sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (VOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere. The seasonality and

Air pollution radiative forcing from specific emissions sectors at 2030

NASA Astrophysics Data System (ADS)

Unger, Nadine; Shindell, Drew T.; Koch, Dorothy M.; Streets, David G.

2008-01-01

Reduction of short-lived air pollutants can contribute to mitigate global warming in the near-term with ancillary benefits to human health. However, the radiative forcings of short-lived air pollutants depend on the location and source type of the precursor emissions. We apply the Goddard Institute for Space Studies atmospheric composition-climate model to quantify near-future (2030 A1B) global annual mean radiative forcing by ozone (O3) and sulfate from six emissions sectors in seven geographic regions. At 2030 the net forcings from O3, sulfate, black and organic carbon, and indirect CH4 effects for each emission sector are (in mWm-2) biomass burning, +95; domestic, +68; transportation, +67; industry, -131; and power, -224. Biomass burning emissions in East Asia and central and southern Africa, domestic biofuel emissions in East Asia, south Asia, and central and southern Africa, and transportation emissions in Europe and North America have large net positive forcings and are therefore attractive targets to counter global warming. Power and industry emissions from East Asia, south Asia, and north Africa and the Middle East have large net negative forcings. Therefore air quality control measures that affect these regional sectors require offsetting climate measures to avoid a warming impact. Linear relationships exist between O3 forcing and biomass burning and domestic biofuel CO precursor emissions independent of region with sensitivity of +0.2 mWm-2/TgCO. Similarly, linear relationships exist between sulfate forcing and SO2 precursor emissions that depend upon region but are independent of sector with sensitivities ranging from -3 to -12 mWm-2/TgS.

Coupling passive air sampling with emission estimates and chemical fate modeling for persistent organic pollutants (POPs): a feasibility study for Northern Europe.

PubMed

Gioia, Rosalinda; Sweetman, Andy J; Jones, Kevin C

2007-04-01

Passive air samplers (polyurethane foam disks) were deployed at 23 background locations along a broadly west-east transect in 8 northern European countries and analyzed for PCBs, PBDEs, PAHs, and a range of organochlorine pesticides (HCB, DDTs, and DDEs). PCBs and PAHs were highest at the center of the transect (Denmark) and lowest in northern Norway. HCB was relatively uniformly distributed, reflecting its persistence and high degree of mixing in air. Higher DDE and DDT levels occurred in Eastern Europe and at several sites in Central Europe. PBDE levels were generally similar at all sites, but lower for some locations in Eastern Europe and Ireland. Emissions information for PCBs, HCB, and PBDEs was used as input for a multi-media chemical fate model, to generate predicted air concentrations and compare with these measured values. Different scenarios were highlighted by this exercise: (i) country and compound combinations where the national inventory gave predicted air concentrations in close agreement with those measured (e.g., PCBs in the UK); (ii) country and compound combinations where predicted concentrations were well below those measured, but where advection of emissions from elsewhere is likely to be important (e.g., PCBs in Norway); (iii) consistent underestimation of compound concentrations by the emissions modeling (i.e., HCB); and (iv) general overestimation of ambient concentrations (i.e., PBDEs). Air mass trajectory analysis showed the likely role of long-range atmospheric transport (LRAT) on national levels. In general, advection from the south and west of Europe appeared to contribute to ambient POPs levels for countries in the center and northeast of the transect. Guidelines are presented as to how countries that want to assess their POPs source inventories can do so with this relatively cheap initial screening approach.

Development and evaluation of a lightweight sensor system for aerial emission sampling from open area sources (Abstract)

EPA Science Inventory

A new sensor system for mobile and aerial emission sampling was developed for open area pollutant sources, such as prescribed forest burns. The sensor system, termed “Kolibri”, consists of multiple low-cost air quality sensors measuring CO2, CO, samplers for particulate matter wi...

Large Gain in Air Quality Compared to an Alternative Anthropogenic Emissions Scenario

NASA Technical Reports Server (NTRS)

Daskalakis, Nikos; Tsigaridis, Kostas; Myriokefalitakis, Stelios; Fanourgakis, George S.; Kanakidou, Maria

2016-01-01

During the last 30 years, significant effort has been made to improve air quality through legislation for emissions reduction. Global three-dimensional chemistrytransport simulations of atmospheric composition over the past 3 decades have been performed to estimate what the air quality levels would have been under a scenario of stagnation of anthropogenic emissions per capita as in 1980, accounting for the population increase (BA1980) or using the standard practice of neglecting it (AE1980), and how they compare to the historical changes in air quality levels. The simulations are based on assimilated meteorology to account for the yearto- year observed climate variability and on different scenarios of anthropogenic emissions of pollutants. The ACCMIP historical emissions dataset is used as the starting point. Our sensitivity simulations provide clear indications that air quality legislation and technology developments have limited the rapid increase of air pollutants. The achieved reductions in concentrations of nitrogen oxides, carbon monoxide, black carbon, and sulfate aerosols are found to be significant when comparing to both BA1980 and AE1980 simulations that neglect any measures applied for the protection of the environment. We also show the potentially large tropospheric air quality benefit from the development of cleaner technology used by the growing global population. These 30-year hindcast sensitivity simulations demonstrate that the actual benefit in air quality due to air pollution legislation and technological advances is higher than the gain calculated by a simple comparison against a constant anthropogenic emissions simulation, as is usually done. Our results also indicate that over China and India the beneficial technological advances for the air quality may have been masked by the explosive increase in local population and the disproportional increase in energy demand partially due to the globalization of the economy.

Reducing greenhouse gas emissions and improving air quality: Two global challenges.

PubMed

Erickson, Larry E

2017-07-01

There are many good reasons to promote sustainable development and reduce greenhouse gas emissions and other combustion emissions. The air quality in many urban environments is causing many premature deaths because of asthma, cardiovascular disease, chronic obstructive pulmonary disease, lung cancer, and dementia associated with combustion emissions. The global social cost of air pollution is at least $3 trillion/year; particulates, nitrogen oxides and ozone associated with combustion emissions are very costly pollutants. Better air quality in urban environments is one of the reasons for countries to work together to reduce greenhouse gas emissions through the Paris Agreement on Climate Change. There are many potential benefits associated with limiting climate change. In the recent past, the concentrations of greenhouse gases in the atmosphere have been increasing and the number of weather and climate disasters with costs over $1 billion has been increasing. The average global temperature set new record highs in 2014, 2015, and 2016. To reduce greenhouse gas emissions, the transition to electric vehicles and electricity generation using renewable energy must take place in accord with the goals of the Paris Agreement on Climate Change. This work reviews progress and identifies some of the health benefits associated with reducing combustion emissions. © 2017 American Institute of Chemical Engineers Environ Prog, 36: 982-988, 2017.

A new analysis system for whole air sampling: description and results from 2013 SENEX

NASA Astrophysics Data System (ADS)

Lerner, B. M.; Gilman, J.; Dumas, M.; Hughes, D.; Jaksich, A.; Hatch, C. D.; Graus, M.; Warneke, C.; Apel, E. C.; Hornbrook, R. S.; Holloway, J. S.; De Gouw, J. A.

2014-12-01

Accurate measurement of volatile organic compounds (VOCs) in the troposphere is critical for the understanding of emissions and physical and chemical processes that can impact both air quality and climate. Airborne VOC measurements have proven especially challenging due to the requirement of both high sensitivity (pptv) and short sample collection times (≤15 s) to maximize spatial resolution and sampling frequency for targeted plume analysis. The use of stainless steel canisters to collect whole air samples (WAS) for post-flight analysis has been pioneered by the groups of D. Blake and E. Atlas [Blake et al., 1992; Atlas et al., 1993]. For the 2013 Southeast Nexus Study (SENEX), the NOAA ESRL CSD laboratory undertook WAS measurements for the first time. This required the construction of three new, highly-automated, and field-portable instruments designed to sample, analyze, and clean the canisters for re-use. Analysis was performed with a new custom-built gas chromatograph-mass spectrometer system. The instrument pre-concentrates analyte cryostatically into two parallel traps by means of a Stirling engine, a novel technique which obviates the need for liquid nitrogen to reach trapping temperatures of -175C. Here we present an evaluation of the retrieval of target VOC species from WAS canisters. We discuss the effects of humidity and sample age on the analyte, particularly upon C8+ alkane and aromatic species and biogenic species. Finally, we present results from several research flights during SENEX that targeted emissions from oil/natural gas production.

VOCs Emissions from Multiple Wood Pellet Types and Concentrations in Indoor Air

PubMed Central

Soto-Garcia, Lydia; Ashley, William J.; Bregg, Sandar; Walier, Drew; LeBouf, Ryan; Hopke, Philip K.; Rossner, Alan

2016-01-01

Wood pellet storage safety is an important aspect for implementing woody biomass as a renewable energy source. When wood pellets are stored indoors in large quantities (tons) in poorly ventilated spaces in buildings, such as in basements, off-gassing of volatile organic compounds (VOCs) can significantly affect indoor air quality. To determine the emission rates and potential impact of VOC emissions, a series of laboratory and field measurements were conducted using softwood, hardwood, and blended wood pellets manufactured in New York. Evacuated canisters were used to collect air samples from the headspace of drums containing pellets and then in basements and pellet storage areas of homes and small businesses. Multiple peaks were identified during GC/MS and GC/FID analysis, and four primary VOCs were characterized and quantified: methanol, pentane, pentanal, and hexanal. Laboratory results show that total VOCs (TVOCs) concentrations for softwood (SW) were statistically (p < 0.02) higher than blended or hardwood (HW) (SW: 412 ± 25; blended: 203 ± 4; HW: 99 ± 8, ppb). The emission rate from HW was the fastest, followed by blended and SW, respectively. Emissions rates were found to range from 10−1 to 10−5 units, depending upon environmental factors. Field measurements resulted in airborne concentrations ranging from 67 ± 8 to 5000 ± 3000 ppb of TVOCs and 12 to 1500 ppb of aldehydes, with higher concentrations found in a basement with a large fabric bag storage unit after fresh pellet delivery and lower concentrations for aged pellets. These results suggest that large fabric bag storage units resulted in a substantial release of VOCs into the building air. Occupants of the buildings tested discussed concerns about odor and sensory irritation when new pellets were delivered. The sensory response was likely due to the aldehydes. PMID:27022205

Organochlorine pesticides in soils and air of southern Mexico: Chemical profiles and potential for soil emissions

NASA Astrophysics Data System (ADS)

Wong, Fiona; Alegria, Henry A.; Jantunen, Liisa M.; Bidleman, Terry F.; Salvador-Figueroa, Miguel; Gold-Bouchot, Gerardo; Ceja-Moreno, Victor; Waliszewski, Stefan M.; Infanzon, Raul

The extent of organochlorine pesticides (OCs) contamination in southern Mexico was investigated in this study. Biweekly air samplings were carried out in two sites in the state of Chiapas (during 2002-2003), and one in each state of Veracruz and Tabasco (during 2003-2004). Corresponding to the air sampling locations, soil samples were also collected to gauge the soil-air exchange of OCs in the region. ∑DDTs in soils ranged from 0.057 to 360 ng g -1 whereas those in air ranged from 240 to 2400 pg m -3. DDT and metabolite DDE were expressed as fractional values, FDDTe = p, p'-DDT/( p, p'-DDT + p, p'-DDE) and FDDTo = p,p'-DDT/( p,p'-DDT + o,p'-DDT). FDDTe in soils ranged from 0.30 to 0.69 while those in air ranged from 0.45 to 0.84. FDDTe in air at a farm in Chiapas (0.84) was closer to that of technical DDT (0.95) which is suggestive of fresh DDT input. Enantiomer fractions (EF) of o,p'-DDT in air were racemic at all locations (0.500-0.504). However, nonracemic o,p'-DDT was seen in the soils (EFs = 0.456-0.647). Fugacities of OCs in soil ( fs) and air ( fa) were calculated, and the fugacity fraction, ff = fs/( fs + fa) of DDTs ranged from 0.013 to 0.97 which indicated a mix of net deposition ( ff < 0.5) and volatilization ( ff > 0.5) from soil among the sites. It is suggested that DDTs in Mexico air are due to a combination of ongoing regional usage and re-emission of old DDT residues from soils. Total toxaphene in soils ranged from 0.066 to 69 ng g -1 while levels in air ranged from 6.2 to 230 pg m -3. Chromatographic profiles of toxaphenes in both air and soil showed depletion of Parlar congeners 39 and 42. Fugacity fractions of toxaphene were within the equilibrium range or above the upper equilibrium threshold boundary. These findings suggested that soil emission of old residues is the main source of toxaphenes to the atmosphere. Results from this study provide baseline data for establishing a long-term OC monitoring program in Mexico.

Impacts of Residential Biofuel Emissions on Air Quality and Climate

NASA Astrophysics Data System (ADS)

Huang, Y.; Unger, N.; Harper, K.; Storelvmo, T.

2016-12-01

The residential biofuel sector is defined as fuelwood, agricultural residues and dung used for household cooking and heating. Aerosol emissions from this human activity play an important role affecting local, regional and global air quality, climate and public health. However, there are only few studies available that evaluate the net impacts and large uncertainties persist. Here we use the Community Atmosphere Model version 5.3 (CAM v5.3) within the Community Earth System Model version 1.2.2, to quantify the impacts of cook-stove biofuel emissions on air quality and climate. The model incorporates a novel advanced treatment of black carbon (BC) effects on mixed-phase/ice clouds. We update the global anthropogenic emission inventory in CAM v5.3 to a state-of-the-art emission inventory from the Greenhouse Gas-Air Pollution Interactions and Synergies integrated assessment model. Global in-situ and aircraft campaign observations for BC and organic carbon are used to evaluate and validate the model performance. Sensitivity simulations are employed to assess the impacts of residential biofuel emissions on regional and global direct and indirect radiative forcings in the contemporary world. We focus the analyses on several key regions including India, China and Sub-Saharan Africa.

Sequim Site Radionuclide Air Emissions Report for Calendar Year 2012

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snyder, Sandra F.; Barnett, J. Matthew; Gervais, Todd L.

2013-04-01

This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and ashington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. This report meets the calendar year 2012 Sequim Site annual reporting requirement for its operations as a privately-owned facility as well as its federally-contracted status that began in October 2012. Compliance is indicated by comparing the estimated dose to the maximally exposedmore » individual (MEI) with the 10 mrem/yr Environmental Protection Agency (EPA) standard. The MSL contains only sources classified as fugitive emissions. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The dose to the Sequim Site MEI due to routine operations in 2012 was 9E-06 mrem (9E-08 mSv). No non-routine emissions occurred in 2012. The MSL is in compliance with the federal and state 10 mrem/yr standard.« less

[Air pollutant emissions of aircraft in China in recent 30 years].

PubMed

He, Ji-Cheng

2012-01-01

Although aircrafts are of great importance in transportation in China, there has been rare study on air pollutant emissions of aircrafts until now. Based on the annually statistical data collected by the Statistic Center of Civil Aviation of China, using the emission factor method derived from fuel consumption, the air pollutant emissions of aircrafts during 1980-2009 were calculated, and their emission intensities and dynamic characteristics were analyzed. The results show that the emissions of SO2, CO, NO(x) and HC from aircrafts of China Civil Aviation increased from 0.31 thousand, 1.89 thousand, 2.25 thousand and 3.14 thousand tons in 1980 to 11.83 thousand, 72.98 thousand, 87.05 thousand and 121.59 thousand tons in 2009, indicating a increase of 0.397 thousand, 2.45 thousand, 2.92 thousand and 4.08 thousand tons per year, respectively. The emission intensities of SO2, CO, NO(x) and HC decreased significantly from 0.624, 3.806, 4.53 and 6.322 g x (t x km)(-1) in 1980 to 0.275, 1.697, 2.025 and 2.828 g x (t x km)(-1) in 2009, respectively. SO2, CO, NO(x) emissions of aircrafts of China Civil Aviation accounted very little of each total emissions in China, and the air pollutant emissions from aircrafts of China Civil Aviation was less than those from other industries in China.

Biogenic organic emissions, air quality and climate

NASA Astrophysics Data System (ADS)

Guenther, A. B.

2015-12-01

Living organisms produce copious amounts of a diverse array of metabolites including many volatile organic compounds that are released into the atmosphere. These compounds participate in numerous chemical reactions that influence the atmospheric abundance of important air pollutants and short-lived climate forcers including organic aerosol, ozone and methane. The production and release of these organics are strongly influenced by environmental conditions including air pollution, temperature, solar radiation, and water availability and they are highly sensitive to stress and extreme events. As a result, releases of biogenic organics to the atmosphere have an impact on, and are sensitive to, air quality and climate leading to potential feedback couplings. Their role in linking air quality and climate is conceptually clear but an accurate quantitative representation is needed for predictive models. Progress towards this goal will be presented including numerical model development and assessments of the predictive capability of the Model of Emission of Gases and Aerosols from Nature (MEGAN). Recent studies of processes controlling the magnitude and variations in biogenic organic emissions will be described and observations of their impact on atmospheric composition will be shown. Recent advances and priorities for future research will be discussed including laboratory process studies, long-term measurements, multi-scale regional studies, global satellite observations, and the development of a next generation model for simulating land-atmosphere chemical exchange.

Carbon emission allowance allocation with a mixed mechanism in air passenger transport.

PubMed

Qiu, Rui; Xu, Jiuping; Zeng, Ziqiang

2017-09-15

Air passenger transport carbon emissions have become a great challenge for both governments and airlines because of rapid developments in the aviation industry in recent decades. In this paper, a mixed mechanism composed of a cap-and-trade mechanism and a carbon tax mechanism is developed to assist governments in allocating carbon emission allowances to airlines operating on the routes. Combined this mixed mechanism with an equilibrium strategy, a bi-level multi-objective model is proposed for an air passenger transport carbon emission allowance allocation problem, in which a government is considered as a leader and the airlines as the followers. An interactive solution approach integrating a genetic algorithm and an interactive evolutionary mechanism is designed to search for satisfactory solutions of the proposed model. A case study is then presented to show its practicality and efficiency in mitigating carbon emissions. Sensitivity analyses under different tradable and taxable levels are also conducted, which can give the government insights as to the tradeoffs between lowering carbon intensity and improving airlines' operations. The computational results demonstrate that the mixed mechanism can assist greatly in carbon emission mitigation for air passenger transport and therefore, it should be established as part of air passenger transport carbon emission policies. Copyright © 2017 Elsevier Ltd. All rights reserved.

A study of extractive and remote-sensing sampling and measurement of emissions from military aircraft engines

NASA Astrophysics Data System (ADS)

Cheng, Meng-Dawn; Corporan, Edwin

2010-12-01

Aircraft emissions contribute to the increased atmospheric burden of particulate matter (PM) that plays an important role in air quality, human health, visibility, contrail formation and climate change. Sampling and measurement of modern aircraft emissions at the engine exhaust plane (EEP) for engine and fuel certification remains challenging, as no agency-certified method is available. In this paper we summarize the results of three recent field studies devoted to investigate the consistency and applicability of "extractive" and "optical remote-sensing" (ORS) technologies in the sampling and measurement of gaseous and PM emitted by a number of military aircraft engines. Three classes of military engines were investigated; these include T56, TF33, and T700 & T701C types of engines, which consume 70-80% of the military aviation fuel each year. JP-8 and Fischer-Tropsch (FT)-derived paraffinic fuels were used to study the effect of fuels. It was found that non-volatile particles in the engine emissions were in the 20 nm range for the low power condition of new helicopter engines to 80 nm for the high power condition of legacy engines. Elemental analysis indicated little metals were present on particles, while most of the materials on the exhaust particles were carbon and sulfate based. Alkanes, carbon monoxide, carbon dioxide, nitrogen oxides, sulfur dioxide, formaldehyde, ethylene, acetylene and propylene were detected. The last five species were most noticeable only under low engine power. The emission indices calculated based on the ORS data deviate significantly from those based on the extractive data. Nevertheless, the ORS techniques were useful in the sense that it provided non-intrusive real-time detection of species in the exhaust plume, which warrants further development. The results obtained in this program help validate sampling methodology and measurement techniques used for non-volatile PM aircraft emissions as described in the SAE AIR6037 (2009).

Mercury emission trend influenced by stringent air pollutants regulation for coal-fired power plants in Korea

NASA Astrophysics Data System (ADS)

Pudasainee, Deepak; Kim, Jeong-Hun; Seo, Yong-Chil

2009-12-01

Regulatory control of mercury emission from anthropogenic sources has become a global concern in the recent past. Coal-fired power plants are one of the largest sources of anthropogenic mercury emission into the atmosphere. This paper summarizes the current reducing trend of mercury emission as co-beneficial effect by more stringent regulation changes to control primary air pollutants with introducing test results from the commercial coal-fired facilities and suggesting a guideline for future regulatory development in Korea. On average, mercury emission concentrations ranged 16.3-2.7 μg Sm -3, 2.4-1.1 μg Sm -3, 3.1-0.7 μg Sm -3 from anthracite coal-fired power plants equipped with electrostatic precipitator (ESP), bituminous coal-fired power plants with ESP + flue gas desulphurization (FGD) and bituminous coal-fired power plants with selective catalytic reactor (SCR) + cold side (CS) - ESP + wet FGD, respectively. Among the existing air pollution control devices, the best configuration for mercury removal in coal-fired power plants was SCR + CS - ESP + wet FGD, which were installed due to the stringent regulation changes to control primary air pollutants emission such as SO 2, NOx and dust. It was estimated that uncontrolled and controlled mercury emission from coal-fired power plants as 10.3 ton yr -1 and 3.2 ton yr -1 respectively. After the installation of ESP, FGD and SCR system, following the enforcement of the stringent regulation, 7.1 ton yr -1 of mercury emission has been reduced (nearly 69%) from coal-fired power plants as a co-benefit control. Based on the overall study, a sample guideline including emission limits were suggested which will be applied to develop a countermeasure for controlling mercury emission from coal-fired power plants.

Development of a 100 nmol mol(-1) propane-in-air SRM for automobile-exhaust testing for new low-emission requirements.

PubMed

Rhoderick, George C

2007-04-01

New US federal low-level automobile emission requirements, for example zero-level-emission vehicle (ZLEV), for hydrocarbons and other species, have resulted in the need by manufacturers for new certified reference materials. The new emission requirement for hydrocarbons requires the use, by automobile manufacturing testing facilities, of a 100 nmol mol(-1) propane in air gas standard. Emission-measurement instruments are required, by federal law, to be calibrated with National Institute of Standards and Technology (NIST) traceable reference materials. Because a NIST standard reference material (SRM) containing 100 nmol mol(-1) propane was not available, the US Environmental Protection Agency (EPA) and the Automobile Industry/Government Emissions Research Consortium (AIGER) requested that NIST develop such an SRM. A cylinder lot of 30 gas mixtures containing 100 nmol mol(-1) propane in air was prepared in 6-L aluminium gas cylinders by a specialty gas company and delivered to the Gas Metrology Group at NIST. Another mixture, contained in a 30-L aluminium cylinder and included in the lot, was used as a lot standard (LS). Using gas chromatography with flame-ionization detection all 30 samples were compared to the LS to obtain the average of six peak-area ratios to the LS for each sample with standard deviations of <0.31%. The average sample-to-LS ratio determinations resulted in a range of 0.9828 to 0.9888, a spread of 0.0060, which corresponds to a relative standard deviation of 0.15% of the average for all 30 samples. NIST developed its first set of five propane in air primary gravimetric standards covering a concentration range 91 to 103 nmol mol(-1) with relative uncertainties of 0.15%. This new suite of propane gravimetric standards was used to analyze and assign a concentration value to the SRM LS. On the basis of these data each SRM sample was individually certified, furnishing the desired relative expanded uncertainty of +/-0.5%. Because automobile companies

A new test chamber to measure material emissions under controlled air velocity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bortoli, M. de; Ghezzi, E.; Knoeppel, H.

1999-05-15

A new 20-L glass chamber for the determination of VOC emissions from construction materials and consumer products under controlled air velocity and turbulence is described. Profiles of air velocity and turbulence, obtained with precisely positioned hot wire anemometric probes, show that the velocity field is homogeneous and that air velocity is tightly controlled by the fan rotation speed; this overcomes the problem of selecting representative positions to measure air velocity above a test specimen. First tests on material emissions show that the influence of air velocity on the emission rate of VOCs is negligible for sources limited by internal diffusionmore » and strong for sources limited by evaporation. In a velocity interval from 0.15 to 0.30 m s{sup {minus}1}, an emission rate increase of 50% has been observed for pure n-decane and 1,4-dichlorobenzene and of 30% for 1,2-propanediol from a water-based paint. In contrast, no measurable influence of turbulence could be observed during vaporization of 1,4-dichlorobenzene within a 3-fold turbulence interval. Investigations still underway show that the chamber has a high recovery for the heavier VOC (TXIB), even at low concentrations.« less

Probing the radio emission from air showers with polarization measurements

NASA Astrophysics Data System (ADS)

Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; PeÂķala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcǎu, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Pierre Auger Collaboration

2014-03-01

The emission of radio waves from air showers has been attributed to the so-called geomagnetic emission process. At frequencies around 50 MHz this process leads to coherent radiation which can be observed with rather simple setups. The direction of the electric field induced by this emission process depends only on the local magnetic field vector and on the incoming direction of the air shower. We report on measurements of the electric field vector where, in addition to this geomagnetic component, another component has been observed that cannot be described by the geomagnetic emission process. The data provide strong evidence that the other electric field component is polarized radially with respect to the shower axis, in agreement with predictions made by Askaryan who described radio emission from particle showers due to a negative charge excess in the front of the shower. Our results are compared to calculations which include the radiation mechanism induced by this charge-excess process.

Electric discharges in air - Near infrared emission spectrum.

NASA Technical Reports Server (NTRS)

Benesch, W. M.; Saum, K. A.

1972-01-01

The emission from glow discharges in flowing air has been investigated in the 1- to 5-micron wavelength region with a vacuum spectrometer. Most of the spectral features observed in the pressure range of .5 to 10 torr are identified, including atomic lines of OI, NI, and HI and molecular bands of N2, NO, N2O, CO2, and CO. The spectra are presented as a function of pressure and a table compiled of the atomic lines. Of particular interest are the contrasts between the emission of the air discharge and that of the pure gases, nitrogen and oxygen. In addition, the results of studies of several discharge modes, employing steady voltages and pulsed, provide data on details of the energy flow within the plasma.

Impact of Marcellus Shale natural gas development in southwest Pennsylvania on volatile organic compound emissions and regional air quality.

PubMed

Swarthout, Robert F; Russo, Rachel S; Zhou, Yong; Miller, Brandon M; Mitchell, Brittney; Horsman, Emily; Lipsky, Eric; McCabe, David C; Baum, Ellen; Sive, Barkley C

2015-03-03

The Marcellus Shale is the largest natural gas deposit in the U.S. and rapid development of this resource has raised concerns about regional air pollution. A field campaign was conducted in the southwestern Pennsylvania region of the Marcellus Shale to investigate the impact of unconventional natural gas (UNG) production operations on regional air quality. Whole air samples were collected throughout an 8050 km(2) grid surrounding Pittsburgh and analyzed for methane, carbon dioxide, and C1-C10 volatile organic compounds (VOCs). Elevated mixing ratios of methane and C2-C8 alkanes were observed in areas with the highest density of UNG wells. Source apportionment was used to identify characteristic emission ratios for UNG sources, and results indicated that UNG emissions were responsible for the majority of mixing ratios of C2-C8 alkanes, but accounted for a small proportion of alkene and aromatic compounds. The VOC emissions from UNG operations accounted for 17 ± 19% of the regional kinetic hydroxyl radical reactivity of nonbiogenic VOCs suggesting that natural gas emissions may affect compliance with federal ozone standards. A first approximation of methane emissions from the study area of 10.0 ± 5.2 kg s(-1) provides a baseline for determining the efficacy of regulatory emission control efforts.

Reducing greenhouse gas emissions and improving air quality: Two global challenges

PubMed Central

2017-01-01

There are many good reasons to promote sustainable development and reduce greenhouse gas emissions and other combustion emissions. The air quality in many urban environments is causing many premature deaths because of asthma, cardiovascular disease, chronic obstructive pulmonary disease, lung cancer, and dementia associated with combustion emissions. The global social cost of air pollution is at least $3 trillion/year; particulates, nitrogen oxides and ozone associated with combustion emissions are very costly pollutants. Better air quality in urban environments is one of the reasons for countries to work together to reduce greenhouse gas emissions through the Paris Agreement on Climate Change. There are many potential benefits associated with limiting climate change. In the recent past, the concentrations of greenhouse gases in the atmosphere have been increasing and the number of weather and climate disasters with costs over $1 billion has been increasing. The average global temperature set new record highs in 2014, 2015, and 2016. To reduce greenhouse gas emissions, the transition to electric vehicles and electricity generation using renewable energy must take place in accord with the goals of the Paris Agreement on Climate Change. This work reviews progress and identifies some of the health benefits associated with reducing combustion emissions. © 2017 American Institute of Chemical Engineers Environ Prog, 36: 982–988, 2017 PMID:29238442

Sorbent-based sampling methods for volatile and semi-volatile organic compounds in air. Part 2. Sorbent selection and other aspects of optimizing air monitoring methods.

PubMed

Woolfenden, Elizabeth

2010-04-16

Sorbent tubes/traps are widely used in combination with gas chromatographic (GC) analytical methods to monitor the vapour-phase fraction of organic compounds in air. Applications range from atmospheric research and ambient air monitoring (indoor and outdoor) to occupational hygiene (personal exposure assessment) and measuring chemical emission levels. Part 1 of this paper reviewed the main sorbent-based air sampling strategies including active (pumped) tube monitoring, diffusive (passive) sampling onto sorbent tubes/cartridges plus sorbent trapping/focusing of whole air samples that are either collected in containers (such as canisters or bags) or monitored online. Options for subsequent extraction and transfer to GC(MS) analysis were also summarised and the trend to thermal desorption (TD)-based methods and away from solvent extraction was explained. As a result of this trend, demand for TD-compatible sorbents (alternatives to traditional charcoal) is growing. Part 2 of this paper therefore continues with a summary of TD-compatible sorbents, their respective advantages and limitations and considerations for sorbent selection. Other analytical considerations for optimizing sorbent-based air monitoring methods are also discussed together with recent technical developments and sampling accessories which have extended the application range of sorbent trapping technology generally. Copyright 2010 Elsevier B.V. All rights reserved.

Adaptive Sampling for Urban Air Quality through Participatory Sensing

PubMed Central

Zeng, Yuanyuan; Xiang, Kai

2017-01-01

Air pollution is one of the major problems of the modern world. The popularization and powerful functions of smartphone applications enable people to participate in urban sensing to better know about the air problems surrounding them. Data sampling is one of the most important problems that affect the sensing performance. In this paper, we propose an Adaptive Sampling Scheme for Urban Air Quality (AS-air) through participatory sensing. Firstly, we propose to find the pattern rules of air quality according to the historical data contributed by participants based on Apriori algorithm. Based on it, we predict the on-line air quality and use it to accelerate the learning process to choose and adapt the sampling parameter based on Q-learning. The evaluation results show that AS-air provides an energy-efficient sampling strategy, which is adaptive toward the varied outside air environment with good sampling efficiency. PMID:29099766

Updating Sea Spray Aerosol Emissions in the Community Multiscale Air Quality Model

NASA Astrophysics Data System (ADS)

Gantt, B.; Bash, J. O.; Kelly, J.

2014-12-01

Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions, include sea surface temperature (SST) dependency, and revise surf zone emissions. Based on evaluation with several regional and national observational datasets in the continental U.S., the updated emissions generally improve surface concentrations predictions of primary aerosols composed of sea-salt and secondary aerosols affected by sea-salt chemistry in coastal and near-coastal sites. Specifically, the updated emissions lead to better predictions of the magnitude and coastal-to-inland gradient of sodium, chloride, and nitrate concentrations at Bay Regional Atmospheric Chemistry Experiment (BRACE) sites near Tampa, FL. Including SST-dependency to the SSA emission parameterization leads to increased sodium concentrations in the southeast U.S. and decreased concentrations along the Pacific coast and northeastern U.S., bringing predictions into closer agreement with observations at most Interagency Monitoring of Protected Visual Environments (IMPROVE) and Chemical Speciation Network (CSN) sites. Model comparison with California Research at the Nexus of Air Quality and Climate Change (CalNex) observations will also be discussed, with particular focus on the South Coast Air Basin where clean marine air mixes with anthropogenic pollution in a complex environment. These SSA emission updates enable more realistic simulation of chemical processes in coastal environments, both in clean marine air masses and mixtures of clean marine and polluted conditions.

Strategies for emission reduction of air pollutants produced from a chemical plant.

PubMed

Lee, Byeong-Kyu; Cho, Sung-Woong

2003-01-01

Various air pollution control (APC) techniques were employed in order to reduce emissions of air pollutants produced from chemical plants, which have many different chemical production facilities. For an emission reduction of acid gases, this study employed a method to improve solubility of pollutants by decreasing the operating temperature of the scrubbers, increasing the surface area for effective contact of gas and liquid, and modifying processes in the acid scrubbers. To reduce emission of both amines and acid gases, pollutant gas components were first separated, then condensation and/or acid scrubbing, depending on the chemical and physical properties of pollutant components, were used. To reduce emission of solvents, condensation and activated carbon adsorption were employed. To reduce emission of a mixture gases containing acid gases and solvents, the mixed gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. As a strategy to reduce emission of pollutants at the source, this study also employed the simple pollution prevention concept of modification of the previously operating APC control device. Finally, air emissions of pollutants produced from the chemical plants were much more reduced by applying proper APC methods, depending upon the types (physical or chemical properties) and the specific emission situations of pollutants.

Effects of business-as-usual anthropogenic emissions on air quality

NASA Astrophysics Data System (ADS)

Pozzer, A.; Zimmermann, P.; Doering, U. M.; van Aardenne, J.; Tost, H.; Dentener, F.; Janssens-Maenhout, G.; Lelieveld, J.

2012-04-01

The atmospheric chemistry general circulation model EMAC has been used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050). The emission scenario assumes that population and economic growth largely determine energy and food consumption and consequent pollution sources with the current technologies ("business as usual"). This scenario is chosen to show the effects of not implementing legislation to prevent additional climate change and growing air pollution, other than what is in place for the base year 2005, representing a pessimistic (but feasible) future. By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecisions inherent to the coarse horizontal resolution (~100 km) and simplified bottom-up emission input. To identify possible future hot spots of poor air quality, a multi pollutant index (MPI), suited for global model output, has been applied. It appears that East and South Asia and the Middle East represent such hotspots due to very high pollutant concentrations, although a general increase of MPIs is observed in all populated regions in the Northern Hemisphere. In East Asia a range of pollutant gases and fine particulate matter (PM2.5) is projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Arabian Gulf, where natural PM2.5 concentrations are already high (desert dust), ozone levels are expected to increase strongly. The per capita MPI (PCMPI), which combines demographic and pollutants concentrations projections, shows that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. Following the business as usual scenario, it is projected that air quality for the global average

Effects of business-as-usual anthropogenic emissions on air quality

NASA Astrophysics Data System (ADS)

Pozzer, A.; Zimmermann, P.; Doering, U. M.; van Aardenne, J.; Tost, H.; Dentener, F.; Janssens-Maenhout, G.; Lelieveld, J.

2012-08-01

The atmospheric chemistry general circulation model EMAC has been used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050). The emission scenario assumes that population and economic growth largely determine energy and food consumption and consequent pollution sources with the current technologies ("business as usual"). This scenario is chosen to show the effects of not implementing legislation to prevent additional climate change and growing air pollution, other than what is in place for the base year 2005, representing a pessimistic (but plausible) future. By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecisions inherent to the coarse horizontal resolution (~100 km) and simplified bottom-up emission input. To identify possible future hot spots of poor air quality, a multi pollutant index (MPI), suited for global model output, has been applied. It appears that East and South Asia and the Middle East represent such hotspots due to very high pollutant concentrations, while a general increase of MPIs is observed in all populated regions in the Northern Hemisphere. In East Asia a range of pollutant gases and fine particulate matter (PM2.5) is projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Persian Gulf, where natural PM2.5 concentrations are already high (desert dust), ozone levels are expected to increase strongly. The population weighted MPI (PW-MPI), which combines demographic and pollutant concentration projections, shows that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. Following this business as usual scenario, it is projected that air quality for the global

Improving the indoor air quality by using a surface emissions trap

NASA Astrophysics Data System (ADS)

Markowicz, Pawel; Larsson, Lennart

2015-04-01

The surface emissions trap, an adsorption cloth developed for reducing emissions of volatile organic compounds and particulate matter from surfaces while allowing evaporation of moisture, was used to improve the indoor air quality of a school building with elevated air concentrations of 2-ethyl-1-hexanol. An improvement of the perceived air quality was noticed a few days after the device had been attached on the PVC flooring. In parallel, decreased air concentrations of 2-ethyl-1-hexanol were found as well as a linear increase of the amounts of the same compound adsorbed on the installed cloth as observed up to 13 months after installation. Laboratory studies revealed that the performance of the device is not affected by differences in RH (35-85%), temperature (30-40 °C) or by accelerated aging simulating up to 10 years product lifetime, and, from a blinded exposure test, that the device efficiently blocks chemical odors. This study suggests that the device may represent a fast and efficient means of restoring the indoor air quality in a building e.g. after water damage leading to irritating and potentially harmful emissions from building material surfaces indoors.

Energy and air emission effects of water supply.

PubMed

Stokes, Jennifer R; Horvath, Arpad

2009-04-15

Life-cycle air emission effects of supplying water are explored using a hybrid life-cycle assessment For the typically sized U.S. utility analyzed, recycled water is preferable to desalination and comparable to importation. Seawater desalination has an energy and air emission footprint that is 1.5-2.4 times larger than that of imported water. However, some desalination modes fare better; brackish groundwater is 53-66% as environmentally intensive as seawater desalination. The annual water needs (326 m3) of a typical Californian that is met with imported water requires 5.8 GJ of energy and creates 360 kg of CO2 equivalent emissions. With seawater desalination, energy use would increase to 14 GJ and 800 kg of CO2 equivalent emissions. Meeting the water demand of California with desalination would consume 52% of the state's electricity. Supply options were reassessed using alternative electricity mixes, including the average mix of the United States and several renewable sources. Desalination using solar thermal energy has lower greenhouse gas emissions than that of imported and recycled water (using California's electricity mix), but using the U.S. mix increases the environmental footprint by 1.5 times. A comparison with a more energy-intensive international scenario shows that CO2 equivalent emissions for desalination in Dubai are 1.6 times larger than in California. The methods, decision support tool (WEST), and results of this study should persuade decision makers to make informed water policy choices by including energy consumption and material use effects in the decision-making process.

Advanced emissions-speciation methodologies for the auto/oil air-quality improvement research program. 2. Aldehydes, ketones, and alcohols. SAE technical paper series

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swarin, S.J.; Loo, J.F.; Chladek, E.

1992-01-01

Analytical methods for determining individual aldehyde, ketone, and alcohol emissions from gasoline-, methanol-, and variable-fueled vehicles are described. These methods were used in the Auto/Oil Air Quality Improvement Research Program to provide emission data for comparison of individual reformulated fuels, individual vehicles, and for air modeling studies. The emission samples are collected in impingers which contain either 2,4-dinitrophenylhydrazine solution for the aldehydes and ketones or deionized water for the alcohols. Subsequent analyses by liquid chromatography for the aldehydes and ketones and gas chromatography for the alcohols utilized auto injectors and computerized data systems which permit high sample throughput with minimalmore » operator intervention. The quality control procedures developed and interlaboratory comparisons conducted as part of the program are also described. (Copyright (c) 1992 Society of Automotive Engineers, Inc.)« less

Indoor air pollutants from unvented kerosene-heater emissions in mobile homes: Studies on particles, semivolatile organics, carbon monoxide, and mutagenicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumford, J.L.; Williams, R.W.; Walsh, D.B.

1991-01-01

The study was conducted to assess human exposure to air pollutants resulting from the use of kerosene heaters in mobile homes. It has been estimated that 15-17 million unvented kerosene heaters have been sold in the United States, and 33% of these heaters have been sold to mobile home residents. The emissions from kerosene heaters can result in high pollutants levels in mobile homes that have a small air volume and low ventilation rate. Eight totally electric mobile homes with no smokers living in the homes were monitored for indoor air particles < 10 micrometer (PM10), semivolatile organics, carbon monoxidemore » (CO), and mutagenicity of semivolatile and particle-phase organics in Salmonella typhimurium TA98 without S9 using a microsuspension reverse-mutation assay. Each home was monitored for an average of 6.5 h/day, 3 days/week, for 4 weeks (2 weeks with the heater on and 2 weeks with the heater off) during the heating season of 1989. Indoor air exchange rate, temperature, and humidity were measured. Chemical analyses, including polycyclic aromatic hydrocarbon (PAH) and nitro PAH, also were performed on the indoor air samples from a selected home with the kerosene heater on and off. Increases in CO and organic concentrations resulting from the use of kerosene heaters were found in most homes monitored. Chemical analysis data also suggested the presence of evaporated, unburned kerosene fuel present in semivolatile organics collected in the XAD samples. In comparison with the U.S. national ambient air standards, four out of the eight heaters investigated in the study emitted pollutants that exceeded the ambient air standards some days. These data suggested that emissions from unvented kerosene heaters can significantly impact indoor air quality in mobile homes and that these emissions contain carcinogenic compounds and can be potentially carcinogenic in humans.« less

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2010 CFR

2010-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2013 CFR

2013-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2011 CFR

2011-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2012 CFR

2012-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2014 CFR

2014-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

PRELIMINARY ANALYSIS OF HAZARDOUS AIR POLLUTANT EMISSION INVENTORIES FROM THREE MAJOR URBAN AREAS

EPA Science Inventory

The paper reports EPA/AEERL's progress on emissions inventory evaluation and improvement under a hazardous air pollutant (HAP) emissions research program in support of the Urban Area Source Program required under Title III of the Clean Air Act Amendments of 1990 (CAAA). he paper ...

Spatially resolved air-water emissions tradeoffs improve regulatory impact analyses for electricity generation.

PubMed

Gingerich, Daniel B; Sun, Xiaodi; Behrer, A Patrick; Azevedo, Inês L; Mauter, Meagan S

2017-02-21

Coal-fired power plants (CFPPs) generate air, water, and solids emissions that impose substantial human health, environmental, and climate change (HEC) damages. This work demonstrates the importance of accounting for cross-media emissions tradeoffs, plant and regional emissions factors, and spatially variation in the marginal damages of air emissions when performing regulatory impact analyses for electric power generation. As a case study, we assess the benefits and costs of treating wet flue gas desulfurization (FGD) wastewater at US CFPPs using the two best available treatment technology options specified in the 2015 Effluent Limitation Guidelines (ELGs). We perform a life-cycle inventory of electricity and chemical inputs to FGD wastewater treatment processes and quantify the marginal HEC damages of associated air emissions. We combine these spatially resolved damage estimates with Environmental Protection Agency estimates of water quality benefits, fuel-switching benefits, and regulatory compliance costs. We estimate that the ELGs will impose average net costs of $3.01 per cubic meter for chemical precipitation and biological wastewater treatment and $11.26 per cubic meter for zero-liquid discharge wastewater treatment (expected cost-benefit ratios of 1.8 and 1.7, respectively), with damages concentrated in regions containing a high fraction of coal generation or a large chemical manufacturing industry. Findings of net cost for FGD wastewater treatment are robust to uncertainty in auxiliary power source, location of chemical manufacturing, and binding air emissions limits in noncompliant regions, among other variables. Future regulatory design will minimize compliance costs and HEC tradeoffs by regulating air, water, and solids emissions simultaneously and performing regulatory assessments that account for spatial variation in emissions impacts.

Spatially resolved air-water emissions tradeoffs improve regulatory impact analyses for electricity generation

PubMed Central

Gingerich, Daniel B.; Behrer, A. Patrick; Azevedo, Inês L.

2017-01-01

Coal-fired power plants (CFPPs) generate air, water, and solids emissions that impose substantial human health, environmental, and climate change (HEC) damages. This work demonstrates the importance of accounting for cross-media emissions tradeoffs, plant and regional emissions factors, and spatially variation in the marginal damages of air emissions when performing regulatory impact analyses for electric power generation. As a case study, we assess the benefits and costs of treating wet flue gas desulfurization (FGD) wastewater at US CFPPs using the two best available treatment technology options specified in the 2015 Effluent Limitation Guidelines (ELGs). We perform a life-cycle inventory of electricity and chemical inputs to FGD wastewater treatment processes and quantify the marginal HEC damages of associated air emissions. We combine these spatially resolved damage estimates with Environmental Protection Agency estimates of water quality benefits, fuel-switching benefits, and regulatory compliance costs. We estimate that the ELGs will impose average net costs of $3.01 per cubic meter for chemical precipitation and biological wastewater treatment and $11.26 per cubic meter for zero-liquid discharge wastewater treatment (expected cost-benefit ratios of 1.8 and 1.7, respectively), with damages concentrated in regions containing a high fraction of coal generation or a large chemical manufacturing industry. Findings of net cost for FGD wastewater treatment are robust to uncertainty in auxiliary power source, location of chemical manufacturing, and binding air emissions limits in noncompliant regions, among other variables. Future regulatory design will minimize compliance costs and HEC tradeoffs by regulating air, water, and solids emissions simultaneously and performing regulatory assessments that account for spatial variation in emissions impacts. PMID:28167772

76 FR 15607 - National Emission Standards for Hazardous Air Pollutants for Major Sources: Industrial...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-21

...On September 13, 2004, under authority of section 112 of the Clean Air Act, EPA promulgated national emission standards for hazardous air pollutants for new and existing industrial/commercial/ institutional boilers and process heaters. On June 19, 2007, the United States Court of Appeals for the District of Columbia Circuit vacated and remanded the standards. In response to the Court's vacatur and remand, EPA is, in this action, establishing emission standards that will require industrial/ commercial/institutional boilers and process heaters located at major sources to meet hazardous air pollutants standards reflecting the application of the maximum achievable control technology. This rule protects air quality and promotes public health by reducing emissions of the hazardous air pollutants listed in section 112(b)(1) of the Clean Air Act.

Characterization of outdoor air particles as source of impurities in supply air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pasanen, P.; Kalliokoski, P.; Tuomainen, A.

1997-12-31

Odor emission of supply air filters has proved to be a major source of stuffy odor of supply air. In this study, the odor emission characteristics of outdoor air particles and odor emissions of coarse prefilters and fine filters were studied. The outdoor air samples were collected by the aid of high volume impactor. Odor emissions of the size fractions, < 2.1 {micro}m , 2.1--10 {micro}m and >10 {micro}m were studied separately in laboratory with a trained olf panel: The odor emissions of the ventilation filters in real use were evaluated five times during the 14 month study period. Aftermore » the field evaluation the emissions of carbonyl compounds and other volatile organic compounds. The odor emissions of outdoor air particles were the highest during the heating season and lowest in the summer. The particles in the coarsest fraction had the most abundant emissions (1,200 olf/g) while the emissions from fine particles were lowest (100 olf/g). The odor emissions evaluated from the coarse and fine ventilation filters supported the finding that particles collected on coarse prefilter had the most abundant odor emission.« less

Economic development and multiple air pollutant emissions from the industrial sector.

PubMed

Fujii, Hidemichi; Managi, Shunsuke

2016-02-01

This study analyzed the relationship between economic growth and emissions of eight environmental air pollutants (carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), nitrogen oxide (NOx), sulfur oxide (SOx), carbon monoxide (CO), non-methane volatile organic compound (NMVOC), and ammonia (NH3)) in 39 countries from 1995 to 2009. We tested an environmental Kuznets curve (EKC) hypothesis for 16 individual industry sectors and for the total industrial sector. The results clarified that at least ten individual industries do not have an EKC relationship in eight air pollutants even though this relationship was observed in the country and total industrial sector level data. We found that the key industries that dictated the EKC relationship in the country and the total industrial sector existed in CO2, N2O, CO, and NMVOC emissions. Finally, the EKC turning point and the relationship between economic development and trends of air pollutant emissions differ among industries according to the pollution substances. These results suggest inducing new environmental policy design such as the sectoral crediting mechanism, which focuses on the industrial characteristics of emissions.

Trends of multiple air pollutants emissions from residential coal combustion in Beijing and its implication on improving air quality for control measures

NASA Astrophysics Data System (ADS)

Xue, Yifeng; Zhou, Zhen; Nie, Teng; Wang, Kun; Nie, Lei; Pan, Tao; Wu, Xiaoqing; Tian, Hezhong; Zhong, Lianhong; Li, Jing; Liu, Huanjia; Liu, Shuhan; Shao, Panyang

2016-10-01

Residential coal combustion is considered to be an important source of air pollution in Beijing. However, knowledge regarding the emission characteristics of residential coal combustion and the related impacts on the air quality is very limited. In this study, we have developed an emission inventory for multiple hazardous air pollutants (HAPs) associated with residential coal combustion in Beijing for the period of 2000-2012. Furthermore, a widely used regional air quality model, the Community Multi-Scale Air Quality model (CMAQ), is applied to analyze the impact of residential coal combustion on the air quality in Beijing in 2012. The results show that the emissions of primary air pollutants from residential coal combustion have basically remained the same levels during the past decade, however, along with the strict emission control imposed on major industrial sources, the contribution of residential coal combustion emissions to the overall emissions from anthropogenic sources have increased obviously. In particular, the contributions of residential coal combustion to the total air pollutants concentrations of PM10, SO2, NOX, and CO represent approximately 11.6%, 27.5%, 2.8% and 7.3%, respectively, during the winter heating season. In terms of impact on the spatial variation patterns, the distributions of the pollutants concentrations are similar to the distribution of the associated primary HAPs emissions, which are highly concentrated in the rural-urban fringe zones and rural suburb areas. In addition, emissions of primary pollutants from residential coal combustion are forecasted by using a scenario analysis. Generally, comprehensive measures must be taken to control residential coal combustion in Beijing. The best way to reduce the associated emissions from residential coal combustion is to use economic incentive means to promote the conversion to clean energy sources for residential heating and cooking. In areas with reliable energy supplies, the coal used

Identification of the odour and chemical composition of alumina refinery air emissions.

PubMed

Coffey, P S; Ioppolo-Armanios, M

2004-01-01

Alcoa World Alumina Australia has undertaken comprehensive air emissions monitoring aimed at characterising and quantifying the complete range of emissions to the atmosphere from Bayer refining of alumina at its Western Australian refineries. To the best of our knowledge, this project represents the most complete air emissions inventory of a Bayer refinery conducted in the worldwide alumina industry. It adds considerably to knowledge of air emission factors available for use in emissions estimation required under national pollutant release and transfer registers (NPRTs), such as the Toxic Releases Inventory, USA, and the National Pollutant Inventory, Australia. It also allows the preliminary identification of the key chemical components responsible for characteristic alumina refinery odours and the contribution of these components to the quality, or hedonic tone, of the odours. The strength and acceptability of refinery odours to employees and neighbours appears to be dependent upon where and in what proportion the odorous gases have been emitted from the refineries. This paper presents the results of the programme and develops a basis for classifying the odour properties of the key emission sources in the alumina-refining process.

Effects of future anthropogenic pollution emissions on global air quality

NASA Astrophysics Data System (ADS)

Pozzer, A.; Zimmermann, P.; Doering, U.; van Aardenne, J.; Dentener, F.; Lelieveld, J.

2012-04-01

The atmospheric chemistry general circulation model EMAC is used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050). The emission scenario assumes that population and economic growth largely determine energy consumption and consequent pollution sources ("business as usual"). By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecision inherent to the coarse horizontal resolution (around 100 km). To identify possible future hot spots of poor air quality, a multi pollutant index (MPI) has been applied. It appears that East and South Asia and the Arabian Gulf regions represent such hotspots due to very high pollutant concentrations. In East Asia a range of pollutant gases and particulate matter (PM2.5) are projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Arabian Gulf, where natural PM2.5 concentrations are already high (desert dust), ozone levels will increase strongly. By extending the MPI definition, we calculated a Per Capita MPI (PCMPI) in which we combined population projections with those of pollution emissions. It thus appears that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. It is projected that air quality for the global average citizen in 2050 will be comparable to the average in East Asia in the year 2005.

Temporal variability of air-sea CO2 exchange in a low-emission estuary

NASA Astrophysics Data System (ADS)

Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

2016-07-01

There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

Potential Air Pollutant Emissions and Permitting Classifications for Two Biorefinery Process Designs in the United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eberle, Annika; Bhatt, Arpit; Zhang, Yimin

Advanced biofuel production facilities (biorefineries), such as those envisioned by the United States (U.S.) Renewable Fuel Standard and U.S. Department of Energy's research and development programs, often lack historical air pollutant emissions data, which can pose challenges for obtaining air emission permits that are required for construction and operation. To help fill this knowledge gap, we perform a thorough regulatory analysis and use engineering process designs to assess the applicability of federal air regulations and quantify air pollutant emissions for two feasibility-level biorefinery designs. We find that without additional emission-control technologies both biorefineries would likely be required to obtain majormore » source permits under the Clean Air Act's New Source Review program. The permitting classification (so-called 'major' or 'minor') has implications for the time and effort required for permitting and therefore affects the cost of capital and the fuel selling price. Consequently, we explore additional technically feasible emission-control technologies and process modifications that have the potential to reduce emissions to achieve a minor source permitting classification. Finally, our analysis of air pollutant emissions and controls can assist biorefinery developers with the air permitting process and inform regulatory agencies about potential permitting pathways for novel biorefinery designs.« less

Potential Air Pollutant Emissions and Permitting Classifications for Two Biorefinery Process Designs in the United States

DOE PAGES

Eberle, Annika; Bhatt, Arpit; Zhang, Yimin; ...

2017-04-26

Advanced biofuel production facilities (biorefineries), such as those envisioned by the United States (U.S.) Renewable Fuel Standard and U.S. Department of Energy's research and development programs, often lack historical air pollutant emissions data, which can pose challenges for obtaining air emission permits that are required for construction and operation. To help fill this knowledge gap, we perform a thorough regulatory analysis and use engineering process designs to assess the applicability of federal air regulations and quantify air pollutant emissions for two feasibility-level biorefinery designs. We find that without additional emission-control technologies both biorefineries would likely be required to obtain majormore » source permits under the Clean Air Act's New Source Review program. The permitting classification (so-called 'major' or 'minor') has implications for the time and effort required for permitting and therefore affects the cost of capital and the fuel selling price. Consequently, we explore additional technically feasible emission-control technologies and process modifications that have the potential to reduce emissions to achieve a minor source permitting classification. Finally, our analysis of air pollutant emissions and controls can assist biorefinery developers with the air permitting process and inform regulatory agencies about potential permitting pathways for novel biorefinery designs.« less

Potential Air Pollutant Emissions and Permitting Classifications for Two Biorefinery Process Designs in the United States.

PubMed

Eberle, Annika; Bhatt, Arpit; Zhang, Yimin; Heath, Garvin

2017-06-06

Advanced biofuel production facilities (biorefineries), such as those envisioned by the United States (U.S.) Renewable Fuel Standard and U.S. Department of Energy's research and development programs, often lack historical air pollutant emissions data, which can pose challenges for obtaining air emission permits that are required for construction and operation. To help fill this knowledge gap, we perform a thorough regulatory analysis and use engineering process designs to assess the applicability of federal air regulations and quantify air pollutant emissions for two feasibility-level biorefinery designs. We find that without additional emission-control technologies both biorefineries would likely be required to obtain major source permits under the Clean Air Act's New Source Review program. The permitting classification (so-called "major" or "minor") has implications for the time and effort required for permitting and therefore affects the cost of capital and the fuel selling price. Consequently, we explore additional technically feasible emission-control technologies and process modifications that have the potential to reduce emissions to achieve a minor source permitting classification. Our analysis of air pollutant emissions and controls can assist biorefinery developers with the air permitting process and inform regulatory agencies about potential permitting pathways for novel biorefinery designs.

Measurement of Ozone Emission and Particle Removal Rates from Portable Air Purifiers

ERIC Educational Resources Information Center

Mang, Stephen A.; Walser, Maggie L.; Nizkorodov, Sergey A.; Laux, John M.

2009-01-01

Portable air purifiers are popular consumer items, especially in areas with poor air quality. Unfortunately, most users of these air purifiers have minimal understanding of the factors affecting their efficiency in typical indoor settings. Emission of the air pollutant ozone (O[subscript 3]) by certain air purifiers is of particular concern. In an…

Impact of air conditioning system operation on increasing gases emissions from automobile

NASA Astrophysics Data System (ADS)

Burciu, S. M.; Coman, G.

2016-08-01

The paper presents a study concerning the influence of air conditioning system operation on the increase of gases emissions from cars. The study focuses on urban operating regimes of the automobile, regimes when the engines have low loads or are operating at idling. Are presented graphically the variations of pollution emissions (CO, CO2, HC) depending of engine speed and the load on air conditioning system. Additionally are presented, injection duration, throttle position, the mechanical power required by the compressor of air conditioning system and the refrigerant pressure variation on the discharge path, according to the stage of charging of the air conditioning system.

Marine Sciences Laboratory Radionuclide Air Emissions Report for Calendar Year 2013

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snyder, Sandra F.; Barnett, J. Matthew; Ballinger, Marcel Y.

2014-05-01

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office (PNSO) has oversight and stewardship duties associated with the Pacific Northwest National Laboratory (PNNL) Marine Sciences Laboratory (MSL) located on Battelle Land – Sequim (Sequim). This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.” The EDE to the Sequimmore » MEI due to routine operations in 2013 was 5E-05 mrem (5E-07 mSv). No non-routine emissions occurred in 2013. The MSL is in compliance with the federal and state 10 mrem/yr standard.« less

Marine Sciences Laboratory Radionuclide Air Emissions Report for Calendar Year 2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snyder, Sandra F.; Barnett, J. Matthew

2015-05-04

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office (PNSO) has oversight and stewardship duties associated with the Pacific Northwest National Laboratory (PNNL) Marine Sciences Laboratory (MSL) located on Battelle Land – Sequim.This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.'' The EDE to the MSL MEI duemore » to routine operations in 2014 was 9E-05 mrem (9E-07 mSv). No non-routine emissions occurred in 2014. The MSL is in compliance with the federal and state 10 mrem/yr standard.« less

Examining air pollution in China using production- and consumption-based emissions accounting approaches.

PubMed

Huo, Hong; Zhang, Qiang; Guan, Dabo; Su, Xin; Zhao, Hongyan; He, Kebin

2014-12-16

Two important reasons for China's air pollution are the high emission factors (emission per unit of product) of pollution sources and the high emission intensity (emissions per unit of GDP) of the industrial structure. Therefore, a wide variety of policy measures, including both emission abatement technologies and economic adjustment, must be implemented. To support such measures, this study used the production- and consumption-based emissions accounting approaches to simulate the SO2, NOx, PM2.5, and VOC emissions flows among producers and consumers. This study analyzed the emissions and GDP performance of 36 production sectors. The results showed that the equipment, machinery, and devices manufacturing and construction sectors contributed more than 50% of air pollutant emissions, and most of their products were used for capital formation and export. The service sector had the lowest emission intensities, and its output was mainly consumed by households and the government. In China, the emission intensities of production activities triggered by capital formation and export were approximately twice that of the service sector triggered by final consumption expenditure. This study suggests that China should control air pollution using the following strategies: applying end-of-pipe abatement technologies and using cleaner fuels to further decrease the emission factors associated with rural cooking, electricity generation, and the transportation sector; continuing to limit highly emission-intensive but low value-added exports; developing a plan to reduce construction activities; and increasing the proportion of service GDP in the national economy.

Location of acoustic emission sources generated by air flow

PubMed

Kosel; Grabec; Muzic

2000-03-01

The location of continuous acoustic emission sources is a difficult problem of non-destructive testing. This article describes one-dimensional location of continuous acoustic emission sources by using an intelligent locator. The intelligent locator solves a location problem based on learning from examples. To verify whether continuous acoustic emission caused by leakage air flow can be located accurately by the intelligent locator, an experiment on a thin aluminum band was performed. Results show that it is possible to determine an accurate location by using a combination of a cross-correlation function with an appropriate bandpass filter. By using this combination, discrete and continuous acoustic emission sources can be located by using discrete acoustic emission sources for locator learning.

Study of the ambient air metallic elements Cr, Cu, Zn, Cd and Pb at HAF sampling sites.

PubMed

Fang, Guor-Cheng; Kuo, Yu-Chen; Zhuang, Yuan-Jie; Tsai, Kai-Hsiang; Huang, Wen-Chuan

2017-08-01

This study characterized diurnal variations in the compositions of total suspended particulates (TSP) and dry deposits of particulates from ambient air, and the metallic elements that are contained in them at harbor, airport and farmland (HAF) sampling sites from August, 2013 to July, 2014. Two-way ANOVA of the amounts of metallic elements in the TSP and dry deposits was carried out in all four seasons at the HAF sampling sites. The metallic elements Cr and Cu originated in local emission sources at the airport. Metallic elements Zn and Pb originated in local emission sources at the harbor. Finally, metallic element Cd originated in local emissions form farmland. The following results were also obtained. (1) The metallic composition of the TSP differed significantly from that of the dry deposits in all four seasons at the harbor and farmland sampling sites, but not at the airport sampling site. (2) High correlations coefficients were found between the amounts of metallic elements Cr and Cu in the TSP and those in the dry deposits at the airport sampling site. (3) Pb was present in the TSP and the dry deposits at the harbor sampling site.

Biofiltration: An innovative air pollution control technology for VOC emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leson, G.; Winer, A.M.

1991-08-01

Biofiltration is a relatively recent air pollution control (APC) technology in which off-gases containing biodegradable volatile organic compounds (VOC) or inorganic air toxics are vented through a biologically active material. This technology has been successfully applied in Germany and The Netherlands in many full-scale applications to control odors, VOC and air toxic emissions from a wide range of industrial and public sector sources. Control efficiencies of more than 90 percent have been achieved for many common air pollutants. Due to lower operating costs, biofiltration can provide significant economic advantages over other APC technologies if applied to off-gases that contain readilymore » biodegradable pollutants in low concentrations. Environmental benefits include low energy requirements and the avoidance of cross media transfer of pollutants. This paper reviews the history and current status of biofiltration, outlines its underlying scientific and engineering principles, and discusses the applicability of biofilters for a wide range of specific emission sources.« less

Biofiltration: an innovative air pollution control technology for VOC emissions.

PubMed

Leson, G; Winer, A M

1991-08-01

Biofiltration is a relatively recent air pollution control (APC) technology in which off-gases containing biodegradable volatile organic compounds (VOC) or inorganic air toxics are vented through a biologically active material. This technology has been successfully applied in Germany and The Netherlands in many full-scale applications to control odors, VOC and air toxic emissions from a wide range of industrial and public sector sources. Control efficiencies of more than 90 percent have been achieved for many common air pollutants. Due to lower operating costs, biofiltration can provide significant economic advantages over other APC technologies if applied to off-gases that contain readily biodegradable pollutants in low concentrations. Environmental benefits include low energy requirements and the avoidance of cross media transfer of pollutants. This paper reviews the history and current status of biofiltration, outlines its underlying scientific and engineering principles, and discusses the applicability of biofilters for a wide range of specific emission sources.

Day and night variation in chemical composition and toxicological responses of size segregated urban air PM samples in a high air pollution situation

NASA Astrophysics Data System (ADS)

Jalava, P. I.; Wang, Q.; Kuuspalo, K.; Ruusunen, J.; Hao, L.; Fang, D.; Väisänen, O.; Ruuskanen, A.; Sippula, O.; Happo, M. S.; Uski, O.; Kasurinen, S.; Torvela, T.; Koponen, H.; Lehtinen, K. E. J.; Komppula, M.; Gu, C.; Jokiniemi, J.; Hirvonen, M.-R.

2015-11-01

Urban air particulate pollution is a known cause for adverse human health effects worldwide. China has encountered air quality problems in recent years due to rapid industrialization. Toxicological effects induced by particulate air pollution vary with particle sizes and season. However, it is not known how distinctively different photochemical activity and different emission sources during the day and the night affect the chemical composition of the PM size ranges and subsequently how it is reflected to the toxicological properties of the PM exposures. The particulate matter (PM) samples were collected in four different size ranges (PM10-2.5; PM2.5-1; PM1-0.2 and PM0.2) with a high volume cascade impactor. The PM samples were extracted with methanol, dried and thereafter used in the chemical and toxicological analyses. RAW264.7 macrophages were exposed to the particulate samples in four different doses for 24 h. Cytotoxicity, inflammatory parameters, cell cycle and genotoxicity were measured after exposure of the cells to particulate samples. Particles were characterized for their chemical composition, including ions, element and PAH compounds, and transmission electron microscopy (TEM) was used to take images of the PM samples. Chemical composition and the induced toxicological responses of the size segregated PM samples showed considerable size dependent differences as well as day to night variation. The PM10-2.5 and the PM0.2 samples had the highest inflammatory potency among the size ranges. Instead, almost all the PM samples were equally cytotoxic and only minor differences were seen in genotoxicity and cell cycle effects. Overall, the PM0.2 samples had the highest toxic potential among the different size ranges in many parameters. PAH compounds in the samples and were generally more abundant during the night than the day, indicating possible photo-oxidation of the PAH compounds due to solar radiation. This was reflected to different toxicity in the PM

How do emission patterns in megacities affect regional air pollution?

NASA Astrophysics Data System (ADS)

Heil, A.; Richter, C.; Schroeder, S.; Schultz, M. G.

2010-12-01

Megacities around the world show distinctly different emission patterns in terms of absolute amounts and emission ratios of individual chemical compounds due to varying socio-economic developments and technological standards. The emission patterns influence the chemical reactivity of the urban pollution plume, and hence determine air quality in and around megacity areas. In this study, which is part of the European project CITYZEN (megaCITY - Zoom for the ENvironment), the effects of emission changes in four selected megacity areas on air pollution were investigated: BeNeLux (BNL), Istanbul (IST), Pearl River Delta (PRD) and Sao Paulo (SAP). The study aims at answering the question: how would air pollution in megacity X change if it had the same urban emissions per capita as megacity Y? Model simulations with the global chemistry climate model ECHAM5-MOZ were carried out for the year 2001 using a resolution of about 2 degrees in the horizontal and of 31 levels (surface to 10 hPa) in the vertical. The model was driven by meteorological input data from the ECMWF ERA Interim reanalysis. Emissions were taken from the gridded global ACCMIP emission inventory recently established for use in chemistry-climate simulations in connection to the IPCC-AR5 assessments (Lamarque et al. 2010). We carried out sensitivity simulations where emission patterns from each of the megacity areas were replaced by those from all others. This was done on the basis of the per capita emissions for each species and sector averaged over the respective region. Total per capita CO and NMVOC emissions are highest in PRD and lowest in SAP while total per capita NOx emissions are highest in BNL and lowest in SAP. There are strong differences in the relative contribution of the urban sectors to total emissions of individual compounds. As a result, each of the four megacity areas exhibits a very characteristic NMVOC speciation profile which determines the NMVOC-related photochemical ozone (O_3

Different methodologies to quantify uncertainties of air emissions.

PubMed

Romano, Daniela; Bernetti, Antonella; De Lauretis, Riccardo

2004-10-01

Characterization of the uncertainty associated with air emission estimates is of critical importance especially in the compilation of air emission inventories. In this paper, two different theories are discussed and applied to evaluate air emissions uncertainty. In addition to numerical analysis, which is also recommended in the framework of the United Nation Convention on Climate Change guidelines with reference to Monte Carlo and Bootstrap simulation models, fuzzy analysis is also proposed. The methodologies are discussed and applied to an Italian example case study. Air concentration values are measured from two electric power plants: a coal plant, consisting of two boilers and a fuel oil plant, of four boilers; the pollutants considered are sulphur dioxide (SO(2)), nitrogen oxides (NO(X)), carbon monoxide (CO) and particulate matter (PM). Monte Carlo, Bootstrap and fuzzy methods have been applied to estimate uncertainty of these data. Regarding Monte Carlo, the most accurate results apply to Gaussian distributions; a good approximation is also observed for other distributions with almost regular features either positive asymmetrical or negative asymmetrical. Bootstrap, on the other hand, gives a good uncertainty estimation for irregular and asymmetrical distributions. The logic of fuzzy analysis, where data are represented as vague and indefinite in opposition to the traditional conception of neatness, certain classification and exactness of the data, follows a different description. In addition to randomness (stochastic variability) only, fuzzy theory deals with imprecision (vagueness) of data. Fuzzy variance of the data set was calculated; the results cannot be directly compared with empirical data but the overall performance of the theory is analysed. Fuzzy theory may appear more suitable for qualitative reasoning than for a quantitative estimation of uncertainty, but it suits well when little information and few measurements are available and when

40 CFR 89.418 - Raw emission sampling calculations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw emission sampling calculations. 89... Test Procedures § 89.418 Raw emission sampling calculations. (a) The final test results shall be... measured on a wet basis. This section is applicable only for measurements made on raw exhaust gas...

40 CFR 89.418 - Raw emission sampling calculations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw emission sampling calculations. 89... Test Procedures § 89.418 Raw emission sampling calculations. (a) The final test results shall be... measured on a wet basis. This section is applicable only for measurements made on raw exhaust gas...

Passive air sampling theory for semivolatile organic compounds.

PubMed

Bartkow, Michael E; Booij, Kees; Kennedy, Karen E; Müller, Jochen F; Hawker, Darryl W

2005-07-01

The mathematical modelling underlying passive air sampling theory can be based on mass transfer coefficients or rate constants. Generally, these models have not been inter-related. Starting with basic models, the exchange of chemicals between the gaseous phase and the sampler is developed using mass transfer coefficients and rate constants. Importantly, the inter-relationships between the approaches are demonstrated by relating uptake rate constants and loss rate constants to mass transfer coefficients when either sampler-side or air-side resistance is dominating chemical exchange. The influence of sampler area and sampler volume on chemical exchange is discussed in general terms and as they relate to frequently used parameters such as sampling rates and time to equilibrium. Where air-side or sampler-side resistance dominates, an increase in the surface area of the sampler will increase sampling rates. Sampling rates are not related to the sampler/air partition coefficient (K(SV)) when air-side resistance dominates and increase with K(SV) when sampler-side resistance dominates.

Pacific Northwest National Laboratory Campus Radionuclide Air Emissions Report for Calendar Year 2015

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

This report documents radionuclide air emissions that result in the 2015 highest effective dose equivalent (EDE) to an offsite member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.” The dose to the PNNL Campus MEI from routine major and minormore » point source emissions in 2015 from PNNL Campus sources is 2.6E-4 mrem (2.6E-6 mSv) EDE. The dose from all fugitive sources is 1.8E-6 mrem (1.8E-8 mSv) EDE. The dose from radon emissions is 4.4E-8 mrem (4.4E-10 mSv) EDE. No nonroutine emissions occurred in 2015. The total radiological dose to the MEI from all PNNL Campus radionuclide emissions, including fugitive emissions and radon, is 2.6E-4 mrem (2.6E-6 mSv) EDE, or more than 10,000 times less than the federal and state standard of 10 mrem/yr, with which the PNNL Campus is in compliance.« less

WORKSHOP ON SOURCE EMISSION AND AMBIENT AIR MONITORING OF MERCURY

EPA Science Inventory

AN EPA/ORD Workshop on Source Emission and Ambient Air Monitoring of Mercury was held on 9/13-14/99, Bloomington, Minnesota. The purpose of the workshop was to discuss the state-of-the-science in source and ambient air mercury monitoring as well as mercury monitoring research and...

Mississippi SIP: Title 11, Part 2, Chapter 1 - Air Emission Regulations for the Prevention, Abatement and Control of Air Contaminents

EPA Pesticide Factsheets

Air Emission Regulations for the Prevention, Abatement and Control of Air Contaminents for areas involved in ambient air quality standards & regulations in MS + where to obtain copies of referenced federal regulations

EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN ...

EPA Pesticide Factsheets

A detailed literature search was performed to collect and collate available data reporting emissions of toxic organic substances into the air from open burning sources. Availability of data varied according to the source and the class of air toxics of interest. Volatile organic compound (VOC) and polycyclic aromatic hydrocarbon (PAH) data were available for many of the sources. Data on semivolatile organic compounds (SVOCs) that are not PAHs were available for several sources. Carbonyl and polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuran (PCDD/F) data were available for only a few sources. There were several sources for which no emissions data were available at all. Several observations were made including: 1) Biomass open burning sources typically emitted less VOCs than open burning sources with anthropogenic fuels on a mass emitted per mass burned basis, particularly those where polymers were concerned; 2) Biomass open burning sources typically emitted less SVOCs and PAHs than anthropogenic sources on a mass emitted per mass burned basis. Burning pools of crude oil and diesel fuel produced significant amounts of PAHs relative to other types of open burning. PAH emissions were highest when combustion of polymers was taking place; and 3) Based on very limited data, biomass open burning sources typically produced higher levels of carbonyls than anthropogenic sources on a mass emitted per mass burned basis, probably due to oxygenated structures r

MODELS TO ESTIMATE VOLATILE ORGANIC HAZARDOUS AIR POLLUTANT EMISSIONS FROM MUNICIPAL SEWER SYSTEMS

EPA Science Inventory

Emissions from municipal sewers are usually omitted from hazardous air pollutant (HAP) emission inventories. This omission may result from a lack of appreciation for the potential emission impact and/or from inadequate emission estimation procedures. This paper presents an analys...

Development of methodologies for identification and quantification of hazardous air pollutants from turbine engine emissions.

PubMed

Anneken, David; Striebich, Richard; DeWitt, Matthew J; Klingshirn, Christopher; Corporan, Edwin

2015-03-01

Aircraft turbine engines are a significant source of particulate matter (PM) and gaseous emissions in the vicinity of airports and military installations. Hazardous air pollutants (HAPs) (e.g., formaldehyde, benzene, naphthalene and other compounds) associated with aircraft emissions are an environmental concern both in flight and at ground level. Therefore, effective sampling, identification, and accurate measurement of these trace species are important to assess their environmental impact. This effort evaluates two established ambient air sampling and analysis methods, U.S. Environmental Protection Agency (EPA) Method TO-11A and National Institute for Occupational Safety and Health (NIOSH) Method 1501, for potential use to quantify HAPs from aircraft turbine engines. The techniques were used to perform analysis of the exhaust from a T63 turboshaft engine, and were examined using certified gas standards transferred through the heated sampling systems used for engine exhaust gaseous emissions measurements. Test results show that the EPA Method TO-11A (for aldehydes) and NIOSH Method 1501 (for semivolatile hydrocarbons) were effective techniques for the sampling and analysis of most HAPs of interest. Both methods showed reasonable extraction efficiencies of HAP species from the sorbent tubes, with the exception of acrolein, styrene, and phenol, which were not well quantified. Formaldehyde measurements using dinitrophenylhydrazine (DNPH) tubes (EPA method TO-11A) were accurate for gas-phase standards, and compared favorably to measurements using gas-phase Fourier-transform infrared (FTIR) spectroscopy. In general, these two standard methodologies proved to be suitable techniques for field measurement of turbine engine HAPs within a reasonable (5-10 minutes) sampling period. Details of the tests, the analysis methods, calibration procedures, and results from the gas standards and T63 engine tested using a conventional JP-8 jet fuel are provided. HAPs from aviation

Estimating emissions from fires in North America for air quality modeling.

Treesearch

Christine Wiedinmyer; Brad Quayle; Chris Geron; Angie Belote; Don McKenzie; Xiaoyang Zhang; Susan O' Neill; Kristina Klos Wynne

2006-01-01

Fires contribute substantial emissions of trace gases and particles to the atmosphere. These emissions can impact air quality and even climate. We have developed a modeling framework to estimate the emissions from fires in North and parts of Central America (10-71 ˚N and 55-175 ˚W) by taking advantage of a combination of complementary satellite and...

Year 2015 Aircraft Emission Scenario for Scheduled Air Traffic

NASA Technical Reports Server (NTRS)

Baughcum, Steven L.; Sutkus, Donald J.; Henderson, Stephen C.

1998-01-01

This report describes the development of a three-dimensional scenario of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons)for projected year 2015 scheduled air traffic. These emission inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxides, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

Influence of Ship Emissions on Urban Air Quality: A Comprehensive Study Using Highly Time-Resolved Online Measurements and Numerical Simulation in Shanghai.

PubMed

Liu, Zhanmin; Lu, Xiaohui; Feng, Junlan; Fan, Qianzhu; Zhang, Yan; Yang, Xin

2017-01-03

Shanghai has become an international shipping center in the world. In this study, the multiyear measurements and the high resolution air quality model with hourly ship emission inventory were combined to determine the influence of ship emissions on urban Shanghai. The aerosol time-of-flight mass spectrometer (ATOFMS) measurements were carried out at an urban site from April 2009 to January 2013. During the entire sampling time, most of the half-hourly averaged number fractions of primary ship emitted particles varied between 1.0-10.0%. However, the number fraction could reach up to 50% during the ship plume cases. Ship-plume-influenced periods usually occurred in spring and summer. The simulation of Weather Research and Forecasting/Community Multiscale Air Quality model (WRF/CMAQ) with hourly ship emission inventory provided the highly time-resolved concentrations of ship-related air pollutants during a ship plume case. It showed ships could contribute 20-30% (2-7 μg/m 3 ) of the total PM 2.5 within tens of kilometers of coastal and riverside Shanghai during ship-plume-influenced periods. Our results showed that ship emissions have substantial contribution to the air pollution in urban Shanghai. The control measures of ship emission should be taken considering its negative environment and human health effects.

Data Quality Objectives Supporting Radiological Air Emissions Monitoring for the PNNL Richland Campus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snyder, Sandra F.; Moleta, Donna Grace L.; Meier, Kirsten M.

This is the second revision of the DQO Supporting Radiological Air Emissions Monitoring for the Pacific Northwest National Laboratory Richland Campus. In January 2017, the PNNL Richland Campus expanded to the north by 0.35 km 2 (85.6 acres). Under the requirements of Washington State Department of Health Radioactive Air Emissions License (RAEL)-005, the PNNL Campus operates and maintains a radiological air monitoring program. This revision documents and evaluates the newly acquired acreage while also removing recreational land at the southwest, and also re-examines all active radioactive emission units on the PNNL Campus. No buildings are located on this new Campusmore » land, which was transferred from the U.S. DOE Hanford Site. Additionally, this revision includes information regarding the background monitoring station PNL-5 in Benton City, Washington, which became active in October 2016. The key purpose of this revision is to determine the adequacy of the existing environmental surveillance stations to monitor radiological air emissions in light of this northern boundary change.« less

Emissions reduction policies and recent trends in Southern California's ambient air quality.

PubMed

Lurmann, Fred; Avol, Ed; Gilliland, Frank

2015-03-01

To assess accountability and effectiveness of air regulatory policies, we reviewed more than 20 years of monitoring data, emissions estimates, and regulatory policies across several southern California communities participating in a long-term study of children's health. Between 1994 and 2011, air quality improved for NO2 and PM2.5 in virtually all the monitored communities. Average NO2 declined 28% to 53%, and PM2.5 decreased 13% to 54%. Year-to-year PM2.5 variability at lower pollution sites was large compared to changes in long-term trends. PM10 and O3 decreases were largest in communities that were initially among the most polluted. Trends in annual average NO2, PM2.5, and PM10 concentrations in higher pollution communities were generally consistent with NOx, ROG, SOx, PM2.5, and PM10 emissions decreases. Reductions observed at one of the higher PM2.5 sites, Mira Loma, were generally within the range expected from reductions observed in ROG, NOx, SOx, and PM2.5 emissions. Despite a 38% increase in regional motor vehicle activity, vigorous economic growth, and a 30% population increase, total estimated emissions of NOx, ROG, SOx, PM2.5, and PM10 decreased by 54%, 65%, 40%, 21%, and 15%, respectively, during the 20-year time period. Emission control strategies in California have achieved dramatic reductions in ambient NO2, O3, PM2.5, and PM10. However, additional reductions will still be needed to achieve current health-based clean air standards. For many cities facing the challenge of reducing air pollution to meet health-based standards, the emission control policies and pollution reduction programs adopted in southern California should serve as an example of the potential success of aggressive, comprehensive, and integrated approaches. Policies targeting on-road mobile emissions were the single most important element for observed improvements in the Los Angeles region. However, overall program success was the result of a much broader approach designed to

The 1977 emissions inventory for southeastern Virginia. [environment model of air quality based on exhaust emission from urban areas

NASA Technical Reports Server (NTRS)

Brewer, D. A.; Remsberg, E. E.; Woodbury, G. E.; Quinn, L. C.

1979-01-01

Regional tropospheric air pollution modeling and data compilation to simulate the time variation of species concentrations in and around an urban area is discussed. The methods used to compile an emissions inventory are outlined. Emissions factors for vehicular travel in the urban area are presented along with an analysis of the emission gases. Emission sources other than vehicular including industrial wastes, residential solid waste disposal, aircraft emissions, and emissions from the railroads are investigated.

A prescribed fire emission factors database for land management and air quality applications

Treesearch

E. Lincoln; WeiMin Hao; S. Baker; R. J. Yokelson; I. R. Burling; Shawn Urbanski; W. Miller; D. R. Weise; T. J. Johnson

2010-01-01

Prescribed fire is a significant emissions source in the U.S. and that needs to be adequately characterized in atmospheric transport/chemistry models. In addition, the Clean Air Act, its amendments, and air quality regulations require that prescribed fire managers estimate the quantity of emissions that a prescribed fire will produce. Several published papers contain a...

AIR EMISSIONS FROM THE TREATMENT OF SOILS CONTAMINATED WITH PETROLEUM FUELS AND OTHER SUBSTANCES

EPA Science Inventory

The report updates a 1992 report that summarizes available information on air emissions from the treatment of soils contaminated with fuels. Soils contaminated by leaks or spills of fuel products, such as gasoline or jet fuel, are a nationwide concern. Air emissions during remedi...

Air/Superfund national technical guidance study series, Volume 2. Estimation of baseline air emission at Superfund sites. Interim report(Final)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1989-01-01

This volume is one in a series of manuals prepared for EPA to assist its Remedial Project Managers in the assessment of the air contaminant pathway and developing input data for risk assessment. The manual provides guidance on developing baseline-emission estimates from hazardous waste sites. Baseline-emission estimates (BEEs) are defined as emission rates estimated for a site in its undisturbed state. Specifically, the manual is intended to: Present a protocol for selecting the appropriate level of effort to characterize baseline air emissions; Assist site managers in designing an approach for BEEs; Describe useful technologies for developing site-specific baseline emission estimatesmore » (BEEs); Help site managers select the appropriate technologies for generating site-specific BEEs.« less

Characterization of VOC Emissions from Various Components of Dairy Farming and their effect on San Joaquin Valley Air Quality

NASA Astrophysics Data System (ADS)

Yang, M. M.; Meinardi, S.; Krauter, C.; Blake, D.

2008-12-01

The San Joaquin Valley Air Basin in Central California is classified by the U.S. Environmental Protection Agency (EPA) as a serious non-attainment area for health-based eight-hour federal ozone (smog) standard (1). In August 2005, the San Joaquin Valley Air Pollution Control District issued a report identifying dairies as a main source of Volatile Organic Compounds (VOCs) and fine particulate matter in the valley (2). Among these compounds, we have found that ethanol, methanol, acetone and acetaldehyde are produced in major quantities throughout the San Joaquin valley as by-products of yeast fermentation of silage and photochemical oxidation. These oxygenates, especially ethanol, play an important role in ozone (O3) formation within the valley. Three different types of sampling protocols were employed in order to determine the degree of enhancement of the four oxygenates in the valley air shed, as well as to determine their sources, emission profiles and emission rates. An assessment of the emissions of these oxygenates in the valley was achieved using data obtained on low altitude flights through the valley and from ground level samples collected thoughout the valley. The photochemical production of ozone was calculated for each of the four oxygenates and approximately one hundred other quantified VOCs. Based on the Maximum Incremental Reactivity (MIR) scale and concentrations of each oxygenate in the atmosphere, as much as 20% of O3 production in the valley is from ethanol and its photochemical by-product acetaldehyde. Our findings suggest that improvement to the valley air quality may be obtained by focusing on instituting new silage containment practices and regulations. 1. Lindberg, J. "Analysis of the San Joaquin Valley 2007 Ozone Plan." State of California Air Resources Board. Final Draft Staff Report. 5/30/2007. 2. Crow, D., executive director/APCO. "Air Pollution Control Officer's Determination of VOC Emisison Factors for Dairies." San Joaquin Valley Air

Double-layer Tedlar bags: a means to limit humidity evolution of air samples and to dry humid air samples.

PubMed

Cariou, Stephane; Guillot, Jean-Michel

2006-01-01

Tedlar bags, which are widely used to collect air samples, especially VOCs and odorous atmospheres, can allow humidity to diffuse when relative humidity levels differ between the inside and outside. Starting with dry air inside the bag and humid air outside, we monitored equilibrium times under several conditions showing the evolution and influence of collected volumes and exposed surfaces. A double-film Tedlar bag was made, to limit the impact of external humidity on a sample at low humidity level. With the addition of a drying agent between both films, the evolution of humidity of a sample can be stopped for several hours. When a VOC mixture was monitored in a humid atmosphere, humidity was decreased but no significant evolution of VOC concentrations was observed.

30 CFR 550.249 - What air emissions information must accompany the DPP or DOCD?

Code of Federal Regulations, 2013 CFR

2013-07-01

... and Information Contents of Development and Production Plans (dpp) and Development Operations Coordination Documents (docd) § 550.249 What air emissions information must accompany the DPP or DOCD? The... 30 Mineral Resources 2 2013-07-01 2013-07-01 false What air emissions information must accompany...

30 CFR 550.249 - What air emissions information must accompany the DPP or DOCD?

Code of Federal Regulations, 2012 CFR

2012-07-01

... and Information Contents of Development and Production Plans (dpp) and Development Operations Coordination Documents (docd) § 550.249 What air emissions information must accompany the DPP or DOCD? The... 30 Mineral Resources 2 2012-07-01 2012-07-01 false What air emissions information must accompany...

30 CFR 550.249 - What air emissions information must accompany the DPP or DOCD?

Code of Federal Regulations, 2014 CFR

2014-07-01

... and Information Contents of Development and Production Plans (dpp) and Development Operations Coordination Documents (docd) § 550.249 What air emissions information must accompany the DPP or DOCD? The... 30 Mineral Resources 2 2014-07-01 2014-07-01 false What air emissions information must accompany...

75 FR 80761 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-23

... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines... March 3, 2010, final national emission standards for hazardous air pollutants for reciprocating internal... engines to allow emergency engines to operate for up to 15 hours per year as part of an emergency demand...

Integration of Linear Dynamic Emission and Climate Models with Air Traffic Simulations

NASA Technical Reports Server (NTRS)

Sridhar, Banavar; Ng, Hok K.; Chen, Neil Y.

2012-01-01

Future air traffic management systems are required to balance the conflicting objectives of maximizing safety and efficiency of traffic flows while minimizing the climate impact of aviation emissions and contrails. Integrating emission and climate models together with air traffic simulations improve the understanding of the complex interaction between the physical climate system, carbon and other greenhouse gas emissions and aviation activity. This paper integrates a national-level air traffic simulation and optimization capability with simple climate models and carbon cycle models, and climate metrics to assess the impact of aviation on climate. The capability can be used to make trade-offs between extra fuel cost and reduction in global surface temperature change. The parameters in the simulation can be used to evaluate the effect of various uncertainties in emission models and contrails and the impact of different decision horizons. Alternatively, the optimization results from the simulation can be used as inputs to other tools that monetize global climate impacts like the FAA s Aviation Environmental Portfolio Management Tool for Impacts.

[Implementation results of emission standards of air pollutants for thermal power plants: a numerical simulation].

PubMed

Wang, Zhan-Shan; Pan, Li-Bo

2014-03-01

The emission inventory of air pollutants from the thermal power plants in the year of 2010 was set up. Based on the inventory, the air quality of the prediction scenarios by implementation of both 2003-version emission standard and the new emission standard were simulated using Models-3/CMAQ. The concentrations of NO2, SO2, and PM2.5, and the deposition of nitrogen and sulfur in the year of 2015 and 2020 were predicted to investigate the regional air quality improvement by the new emission standard. The results showed that the new emission standard could effectively improve the air quality in China. Compared with the implementation results of the 2003-version emission standard, by 2015 and 2020, the area with NO2 concentration higher than the emission standard would be reduced by 53.9% and 55.2%, the area with SO2 concentration higher than the emission standard would be reduced by 40.0%, the area with nitrogen deposition higher than 1.0 t x km(-2) would be reduced by 75.4% and 77.9%, and the area with sulfur deposition higher than 1.6 t x km(-2) would be reduced by 37.1% and 34.3%, respectively.

Use of a land-use-based emissions inventory in delineating clean-air zones

Treesearch

Victor S. Fahrer; Howard A. Peters

1977-01-01

Use of a land-use-based emissions inventory from which air-pollution estimates can be projected was studied. First the methodology used to establish a land-use-based emission inventory is described. Then this inventory is used as input in a simple model that delineates clean air and buffer zones. The model is applied to the town of Burlington, Massachusetts....

Evaluating near highway air pollutant levels and estimating emission factors: Case study of Tehran, Iran.

PubMed

Nayeb Yazdi, Mohammad; Delavarrafiee, Maryam; Arhami, Mohammad

2015-12-15

A field sampling campaign was implemented to evaluate the variation in air pollutants levels near a highway in Tehran, Iran (Hemmat highway). The field measurements were used to estimate road link-based emission factors for average vehicle fleet. These factors were compared with results of an in tunnel measurement campaign (in Resalat tunnel). Roadside and in-tunnel measurements of carbon monoxide (CO) and size-fractionated particulate matter (PM) were conducted during the field campaign. The concentration gradient diagrams showed exponential decay, which represented a substantial decay, more than 50-80%, in air pollutants level in a distance between 100 and 150meters (m) of the highway. The changes in particle size distribution by distancing from highway were also captured and evaluated. The results showed particle size distribution shifted to larger size particles by distancing from highway. The empirical emission factors were obtained by using the roadside and in tunnel measurements with a hypothetical box model, floating machine model, CALINE4, CT-EMFAC or COPERT. Average CO emission factors were estimated to be in a range of 4 to 12g/km, and those of PM10 were 0.1 to 0.2g/km, depending on traffic conditions. Variations of these emission factors under real working condition with speeds were determined. Copyright © 2015 Elsevier B.V. All rights reserved.

Assessment of China's virtual air pollution transport embodied in trade by a consumption-based emission inventory

NASA Astrophysics Data System (ADS)

Zhao, H. Y.; Zhang, Q.; Davis, S. J.; Guan, D.; Liu, Z.; Huo, H.; Lin, J. T.; Liu, W. D.; He, K. B.

2014-10-01

High anthropogenic emissions from China have resulted in serious air pollution, and it has attracted considerable academic and public concern. The physical transport of air pollutants in the atmosphere has been extensively investigated, however, understanding the mechanisms how the pollutants were transferred through economic and trade activities remains challenge. In this work, we assessed China's virtual air pollutant transport embodied in trade, by using consumption-based accounting approach. We first constructed a consumption-based emission inventory for China's four key air pollutants (primary PM2.5, sulfur dioxide (SO2), nitrogen oxides (NOx) and non-methane volatile organic compounds (NMVOC)) in 2007, based on the bottom-up sectoral emission inventory concerning their production activities - a production-based inventory. We used a multiregional input-output (MRIO) model to integrate the sectoral production-based emissions and the associated economic and trade activities, and finally obtained consumption-based inventory. Unlike the production-based inventory, the consumption-based inventory tracked emissions throughout the supply chain related to the consumption of goods and services and hereby identified the emission flows followed the supply chains. From consumption-based perspective, emissions were significantly redistributed among provinces due to interprovincial trade. Large amount of emissions were embodied in the net imports of east regions from northern and central regions; these were determined by differences in the regional economic status and environmental policies. We also calculated the emissions embodied in exported and imported goods and services. It is found that 15-23% of China's pollutant emissions were related to exports for foreign consumption; that proportion was much higher for central and export-oriented coastal regions. It is suggested that measures should be introduced to reduce air pollution by integrating cross-regional consumers

EMISSIONS FROM THE BURNING OF VEGETATIVE DEBRIS IN AIR CURTAIN DESTRUCTORS

EPA Science Inventory

Although no data has been published on emissions from construction and demolition (C&D) debris burned in an air curtain destructor (ACD), a few studies provide information on emissions from combustion of vegetative debris. These results are compared to studies of open burning of...

“Exchanges of Aggregate Air Nitrogen Emissions and Watershed Nitrogen Loads”

EPA Science Inventory

An approach has been developed to define transfer coefficients that can be used to convert changes in air emissions to changes in air deposition and subsequently to changes in loads delivered to the Bay. This approach uses a special CMAQ version that quantitatively attributes wa...

EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN BURNING: A COMPREHENSIVE REVIEW

EPA Science Inventory

A detailed literature search was performed to collect and collate available data reporting emissions of organic air toxics from open burning sources. Availability of data varied according to the source and the class of air toxics of interest, and there were several sources for wh...

Clean Air Act, TRI drive emission reduction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heller, K.

1994-06-22

When asked to rank priority environmental engineering projects, many chemical firms put emissions reduction first. The chief motivators are the need to comply with rules governing major sources of hazardous air pollutants (HAPS) under the Clean Air Act Amendments of 1990 (CAA), along with the need to reduce the volumes of chemicals on EPA`s Toxics Release Inventory (TRI). Deep-welling of toxics is getting special attention as the practice adds considerably to TRI numbers. {open_quotes}We want to eliminate our air toxics so that we can get entirely out of the [CAA] Maximum Achievable Control Technology (MACT) requirements,{close_quotes} says Thomas Zosel, manager/pollutionmore » prevention programs for 3M (St. Paul, MN). He estimates that 3M`s 1993 total research expenditures for environmental improvements were at least $200 million, out of an annual research budget of a little more than $1 billion. And, he says, the spending level is not expected to drop. Among its many efforts, 3M is striving to move away from solvents in all of its processes. To help reach that goal, the company developed a {open_quotes}waste measurement metric{close_quotes} that calculates the wastes produced by each of the company`s 50 operating divisions. In the case of Magic Tape, the company eliminated solvent emission by switching to a water-based adhesive that does not require a solvent.« less

The Impact of Residential Combustion Emissions on Air Quality and Human Health in China

NASA Astrophysics Data System (ADS)

Archer-Nicholls, S.; Wiedinmyer, C.; Baumgartner, J.; Brauer, M.; Cohen, A.; Carter, E.; Frostad, J.; Forouzanfar, M.; Xiao, Q.; Liu, Y.; Yang, X.; Hongjiang, N.; Kun, N.

2015-12-01

Solid fuel cookstoves are used heavily in rural China for both residential cooking and heating purposes. Their use contributes significantly to regional emissions of several key pollutants, including carbon monoxide, volatile organic compounds, oxides of nitrogen, and aerosol particles. The residential sector was responsible for approximately 36%, 46% and 81% of China's total primary PM2.5, BC and OC emissions respectively in 2005 (Lei et al., 2011). These emissions have serious consequences for household air pollution, ambient air quality, tropospheric ozone formation, and the resulting population health and climate impacts. This paper presents initial findings from the modeling component of a multi-disciplinary energy intervention study currently being conducted in Sichuan, China. The purpose of this effort is to quantify the impact of residential cooking and heating emissions on regional air quality and human health. Simulations with varying levels of residential emissions have been carried out for the whole of 2014 using the Weather Research and Forecasting model with Chemistry (WRF-Chem), a fully-coupled, "online" regional chemical transport model. Model output is evaluated against surface air quality measurements across China and compared with seasonal (winter and summer) ambient air pollution measurements conducted at the Sichuan study site in 2014. The model output is applied to available exposure—response relationships between PM2.5 and cardiopulmonary health outcomes. The sensitivity in different regions across China to the different cookstove emission scenarios and seasonality of impacts are presented. By estimating the mortality and disease burden risk attributable to residential emissions we demonstrate the potential benefits from large-scale energy interventions. Lei Y, Zhang Q, He KB, Streets DG. 2011. Primary anthropogenic aerosol emission trends for China, 1990-2005. Atmos. Chem. Phys. 11:931-954.

The radio emission pattern of air showers as measured with LOFAR—a tool for the reconstruction of the energy and the shower maximum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelles, A.; Corstanje, A.; Enriquez, J.E.

2015-05-01

The pattern of the radio emission of air showers is finely sampled with the Low-Frequency ARray (LOFAR). A set of 382 measured air showers is used to test a fast, analytic parameterization of the distribution of pulse powers. Using this parameterization we are able to reconstruct the shower axis and give estimators for the energy of the air shower as well as the distance to the shower maximum.

Air Emissions Damages from Municipal Drinking Water Treatment Under Current and Proposed Regulatory Standards.

PubMed

Gingerich, Daniel B; Mauter, Meagan S

2017-09-19

Water treatment processes present intersectoral and cross-media risk trade-offs that are not presently considered in Safe Drinking Water Act regulatory analyses. This paper develops a method for assessing the air emission implications of common municipal water treatment processes used to comply with recently promulgated and proposed regulatory standards, including concentration limits for, lead and copper, disinfection byproducts, chromium(VI), strontium, and PFOA/PFOS. Life-cycle models of electricity and chemical consumption for individual drinking water unit processes are used to estimate embedded NO x , SO 2 , PM 2.5 , and CO 2 emissions on a cubic meter basis. We estimate air emission damages from currently installed treatment processes at U.S. drinking water facilities to be on the order of $500 million USD annually. Fully complying with six promulgated and proposed rules would increase baseline air emission damages by approximately 50%, with three-quarters of these damages originating from chemical manufacturing. Despite the magnitude of these air emission damages, the net benefit of currently implemented rules remains positive. For some proposed rules, however, the promise of net benefits remains contingent on technology choice.

Fluorescence emission induced by the femtosecond filament transmitting through the butane/air flame

NASA Astrophysics Data System (ADS)

Li, Suyu; Li, Yanhua; Shi, Zhe; Sui, Laizhi; Li, He; Li, Qingyi; Chen, Anmin; Jiang, Yuanfei; Jin, Mingxing

2018-01-01

We measure the backward fluorescence spectra generated by the femtosecond filament transmitting through the butane/air flame, and study the fluorescence emission from combustion intermediates (CN, CH and C2 radicals), air (mainly N2 and N2+). It is found that the fluorescence emission from combustion intermediates, N2 and N2+ shows difference when the femtosecond filament transmits through different parts of the butane/air flame, and we attempt to analyze it in this paper. This study demonstrates that the filament-induced fluorescence technique can be utilized to sense the combustion intermediates.

Atmospheric Ammonia Over China: Emission Estimates And Impact On Air Quality

NASA Astrophysics Data System (ADS)

Zhang, L.; Chen, Y.; Zhao, Y.; Henze, D. K.

2016-12-01

Ammonia (NH3) in the atmosphere is an important precursor of aerosols, and its deposition through wet and dry processes can cause adverse effects on ecosystems. The ammonia emissions over China are particularly large due to intensive agricultural activities, yet our current estimates of Chinese ammonia emissions and associated consequences on air quality are subject to large errors. We use the GEOS-Chem chemical transport model and its adjoint model to better quantify this issue. The TES satellite observations of ammonia concentrations and surface measurements of wet deposition fluxes are assimilated into the model to constrain the ammonia emissions over China. Optimized emissions show a strong seasonal variability with emissions in summer a factor of 3 higher than winter. This is consistent with an improved bottom-up estimate of Chinese ammonia emissions from fertilizer use by using more practical fertilizer application rates for different crop types. We further use the GEOS-Chem adjoint at 0.25x0.3125 degree resolution to examine the sources contributing to the PM2.5 air pollution over North China. We show that wintertime PM2.5 over Beijing is largely contributed by residential and industrial sources, and ammonia emissions from agriculture activities. PM2.5 concentrations over North China are particularly sensitive to emissions of ammonia and nitrogen oxides, reflecting strong formation of aerosol nitrate in the cold seasons.

76 FR 81327 - National Emission Standards for Hazardous Air Pollutants From the Pulp and Paper Industry

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-27

... for each emission unit type (e.g., gas- or oil-fired paper machine dryers) based on the most common... 63 National Emission Standards for Hazardous Air Pollutants From the Pulp and Paper Industry...-AQ41 National Emission Standards for Hazardous Air Pollutants From the Pulp and Paper Industry AGENCY...

Impacts of Future Climate and Emission Changes on U.S. Air Quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Penrod, Ashley; Zhang, Yang; Wang, K.

2014-06-01

Changes in climate and emissions will affect future air quality. In this work, simulations of present (2001-2005) and future (2026-2030) regional air quality are conducted with the newly released CMAQ version 5.0 to examine the individual and combined impacts of simulated future climate and anthropogenic emission projections on air quality over the U.S. Current (2001-2005) meteorological and chemical predictions are evaluated against observational data to assess the model’s capability in reproducing the seasonal differences. Overall, WRF and CMAQ perform reasonably well. Increased temperatures (up to 3.18 °C) and decreased ventilation (up to 157 m in planetary boundary layer height) aremore » found in both future winter and summer, with more prominent changes in winter. Increases in future temperatures result in increased isoprene and terpene emissions in winter and summer, driving the increase in maximum 8-h average O3 (up to 5.0 ppb) over the eastern U.S. in winter while decreases in NOx emissions drive the decrease in O3 over most of the U.S. in summer. Future concentrations of PM2.5 in winter and summer and many of its components including organic matter in winter, ammonium and nitrate in summer, and sulfate in winter and summer, decrease due to decreases in primary anthropogenic emissions and the concentrations of secondary anthropogenic pollutants and increased precipitation in winter. Future winter and summer dry and wet deposition fluxes are spatially variable and increase with increasing surface resistance and precipitation (e.g., NH4+ and NO3- dry and wet deposition fluxes increase in winter over much of the U.S.), respectively, and decrease with a decrease in ambient particulate concentrations (e.g., SO42- dry and wet deposition fluxes decrease over the eastern U.S. in summer and winter). Sensitivity simulations show that anthropogenic emission projections dominate over changes in climate in their impacts on the U.S. air quality in the near future

Air pollutant emissions from Chinese households: A major and underappreciated ambient pollution source.

PubMed

Liu, Jun; Mauzerall, Denise L; Chen, Qi; Zhang, Qiang; Song, Yu; Peng, Wei; Klimont, Zbigniew; Qiu, Xinghua; Zhang, Shiqiu; Hu, Min; Lin, Weili; Smith, Kirk R; Zhu, Tong

2016-07-12

As part of the 12th Five-Year Plan, the Chinese government has developed air pollution prevention and control plans for key regions with a focus on the power, transport, and industrial sectors. Here, we investigate the contribution of residential emissions to regional air pollution in highly polluted eastern China during the heating season, and find that dramatic improvements in air quality would also result from reduction in residential emissions. We use the Weather Research and Forecasting model coupled with Chemistry to evaluate potential residential emission controls in Beijing and in the Beijing, Tianjin, and Hebei (BTH) region. In January and February 2010, relative to the base case, eliminating residential emissions in Beijing reduced daily average surface PM2.5 (particulate mater with aerodynamic diameter equal or smaller than 2.5 micrometer) concentrations by 14 ± 7 μg⋅m(-3) (22 ± 6% of a baseline concentration of 67 ± 41 μg⋅m(-3); mean ± SD). Eliminating residential emissions in the BTH region reduced concentrations by 28 ± 19 μg⋅m(-3) (40 ± 9% of 67 ± 41 μg⋅m(-3)), 44 ± 27 μg⋅m(-3) (43 ± 10% of 99 ± 54 μg⋅m(-3)), and 25 ± 14 μg⋅m(-3) (35 ± 8% of 70 ± 35 μg⋅m(-3)) in Beijing, Tianjin, and Hebei provinces, respectively. Annually, elimination of residential sources in the BTH region reduced emissions of primary PM2.5 by 32%, compared with 5%, 6%, and 58% achieved by eliminating emissions from the transportation, power, and industry sectors, respectively. We also find air quality in Beijing would benefit substantially from reductions in residential emissions from regional controls in Tianjin and Hebei, indicating the value of policies at the regional level.

Air pollutant emissions from Chinese households: A major and underappreciated ambient pollution source

PubMed Central

Liu, Jun; Mauzerall, Denise L.; Chen, Qi; Zhang, Qiang; Song, Yu; Peng, Wei; Klimont, Zbigniew; Qiu, Xinghua; Zhang, Shiqiu; Hu, Min; Lin, Weili; Smith, Kirk R.; Zhu, Tong

2016-01-01

As part of the 12th Five-Year Plan, the Chinese government has developed air pollution prevention and control plans for key regions with a focus on the power, transport, and industrial sectors. Here, we investigate the contribution of residential emissions to regional air pollution in highly polluted eastern China during the heating season, and find that dramatic improvements in air quality would also result from reduction in residential emissions. We use the Weather Research and Forecasting model coupled with Chemistry to evaluate potential residential emission controls in Beijing and in the Beijing, Tianjin, and Hebei (BTH) region. In January and February 2010, relative to the base case, eliminating residential emissions in Beijing reduced daily average surface PM2.5 (particulate mater with aerodynamic diameter equal or smaller than 2.5 micrometer) concentrations by 14 ± 7 μg⋅m−3 (22 ± 6% of a baseline concentration of 67 ± 41 μg⋅m−3; mean ± SD). Eliminating residential emissions in the BTH region reduced concentrations by 28 ± 19 μg⋅m−3 (40 ± 9% of 67 ± 41 μg⋅m−3), 44 ± 27 μg⋅m−3 (43 ± 10% of 99 ± 54 μg⋅m−3), and 25 ± 14 μg⋅m−3 (35 ± 8% of 70 ± 35 μg⋅m−3) in Beijing, Tianjin, and Hebei provinces, respectively. Annually, elimination of residential sources in the BTH region reduced emissions of primary PM2.5 by 32%, compared with 5%, 6%, and 58% achieved by eliminating emissions from the transportation, power, and industry sectors, respectively. We also find air quality in Beijing would benefit substantially from reductions in residential emissions from regional controls in Tianjin and Hebei, indicating the value of policies at the regional level. PMID:27354524

Emissions of CO2 and criteria air pollutants from mobile sources: Insights from integrating real-time traffic data into local air quality models

NASA Astrophysics Data System (ADS)

Gately, Conor; Hutyra, Lucy

2016-04-01

In 2013, on-road mobile sources were responsible for over 26% of U.S. fossil fuel carbon dioxide (ffCO2) emissions, and over 34% of both CO and NOx emissions. However, accurate representations of these emissions at the scale of urban areas remains a difficult challenge. Quantifying emissions at the scale of local streets and highways is critical to provide policymakers with the information needed to develop appropriate mitigation strategies and to guide research into the underlying process that drive mobile emissions. Quantification of vehicle ffCO2 emissions at high spatial and temporal resolutions requires a detailed synthesis of data on traffic activity, roadway attributes, fleet characteristics and vehicle speeds. To accurately characterize criteria air pollutant emissions, information on local meteorology is also critical, as the temperature and relative humidity can affect emissions rates of these pollutants by as much as 400%. As the health impacts of air pollutants are more severe for residents living in close proximity (<500m) to road sources, it is critical that inventories of these emissions rely on highly resolved source data to locate potential hot-spots of exposure. In this study we utilize real-time GPS estimates of vehicle speeds to estimate ffCO2 and criteria air pollutant emissions at multiple spatial and temporal scales across a large metropolitan area. We observe large variations in emissions associated with diurnal activity patterns, congestion, sporting and civic events, and weather anomalies. We discuss the advantages and challenges of using highly-resolved source data to quantify emissions at a roadway scale, and the potential of this methodology for forecasting the air quality impacts of changes in infrastructure, urban planning policies, and regional climate.

Emissions of CO2 and criteria air pollutants from mobile sources: Insights from integrating real-time traffic data into local air quality models

NASA Astrophysics Data System (ADS)

Gately, C.; Hutyra, L.; Sue Wing, I.; Peterson, S.; Janetos, A.

2015-12-01

In 2013, on-road mobile sources were responsible for over 26% of U.S. fossil fuel carbon dioxide (ffCO2) emissions, and over 34% of both CO and NOx emissions. However, accurate representations of these emissions at the scale of urban areas remains a difficult challenge. Quantifying emissions at the scale of local streets and highways is critical to provide policymakers with the information needed to develop appropriate mitigation strategies and to guide research into the underlying process that drive mobile emissions. Quantification of vehicle ffCO2 emissions at high spatial and temporal resolutions requires a detailed synthesis of data on traffic activity, roadway attributes, fleet characteristics and vehicle speeds. To accurately characterize criteria air pollutant emissions, information on local meteorology is also critical, as the temperature and relative humidity can affect emissions rates of these pollutants by as much as 400%. As the health impacts of air pollutants are more severe for residents living in close proximity (<500m) to road sources, it is critical that inventories of these emissions rely on highly resolved source data to locate potential hot-spots of exposure. In this study we utilize real-time GPS estimates of vehicle speeds to estimate ffCO2 and criteria air pollutant emissions at multiple spatial and temporal scales across a large metropolitan area. We observe large variations in emissions associated with diurnal activity patterns, congestion, sporting and civic events, and weather anomalies. We discuss the advantages and challenges of using highly-resolved source data to quantify emissions at a roadway scale, and the potential of this methodology for forecasting the air quality impacts of changes in infrastructure, urban planning policies, and regional climate.

Portable air pollution control equipment for the control of toxic particulate emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chaurushia, A.; Odabashian, S.; Busch, E.

1997-12-31

Chromium VI (Cr VI) has been identified by the environmental regulatory agencies as a potent carcinogen among eleven heavy metals. A threshold level of 0.0001 lb/year for Cr VI emissions has been established by the California Air Resources Board for reporting under Assembly Bill 2588. A need for an innovative control technology to reduce fugitive emissions of Cr VI was identified during the Air Toxic Emissions Reduction Program at Northrop Grumman Military Aircraft Systems Division (NGMASD). NGMASD operates an aircraft assembly facility in El Segundo, CA. Nearly all of the aircraft components are coated with a protective coating (primer) priormore » to assembly. The primer has Cr VI as a component for its excellent corrosion resistance property. The complex assembly process requires fasteners which also need primer coating. Therefore, NGMASD utilizes High Volume Low Pressure (HVLP) guns for the touch-up spray coating operations. During the touch-up spray coating operations, Cr VI particles are atomized and transferred to the aircraft surface. The South Coast Air Quality Management District (SCAQMD) has determined that the HVLP gun transfers 65% of the paint particles onto the substrate and the remaining 35% are emitted as an overspray if air pollution controls are not applied. NGMASD has developed the Portable Air Pollution Control Equipment (PAPCE) to capture and control the overspray in order to reduce fugitive Cr VI emissions from the touch-up spray coating operations. A source test was performed per SCAQMD guidelines and the final report has been approved by the SCAQMD.« less

Assessment of China's virtual air pollution transport embodied in trade by using a consumption-based emission inventory

NASA Astrophysics Data System (ADS)

Zhao, H. Y.; Zhang, Q.; Guan, D. B.; Davis, S. J.; Liu, Z.; Huo, H.; Lin, J. T.; Liu, W. D.; He, K. B.

2015-05-01

Substantial anthropogenic emissions from China have resulted in serious air pollution, and this has generated considerable academic and public concern. The physical transport of air pollutants in the atmosphere has been extensively investigated; however, understanding the mechanisms how the pollutant was transferred through economic and trade activities remains a challenge. For the first time, we quantified and tracked China's air pollutant emission flows embodied in interprovincial trade, using a multiregional input-output model framework. Trade relative emissions for four key air pollutants (primary fine particle matter, sulfur dioxide, nitrogen oxides and non-methane volatile organic compounds) were assessed for 2007 in each Chinese province. We found that emissions were significantly redistributed among provinces owing to interprovincial trade. Large amounts of emissions were embodied in the imports of eastern regions from northern and central regions, and these were determined by differences in regional economic status and environmental policy. It is suggested that measures should be introduced to reduce air pollution by integrating cross-regional consumers and producers within national agreements to encourage efficiency improvement in the supply chain and optimize consumption structure internationally. The consumption-based air pollutant emission inventory developed in this work can be further used to attribute pollution to various economic activities and final demand types with the aid of air quality models.

3D Air Quality and the Clean Air Interstate Rule: Lagrangian Sampling of CMAQ Model Results to Aid Regional Accountability Metrics

NASA Technical Reports Server (NTRS)

Fairlie, T. D.; Szykman, Jim; Pierce, Robert B.; Gilliland, A. B.; Engel-Cox, Jill; Weber, Stephanie; Kittaka, Chieko; Al-Saadi, Jassim A.; Scheffe, Rich; Dimmick, Fred;

Potential air emission impacts of cellulosic ethanol production at seven demonstration refineries in the United States.

PubMed

Jones, Donna Lee

2010-09-01

This paper reports on the estimated potential air emissions, as found in air permits and supporting documentation, for seven of the first group of precommercial or "demonstration" cellulosic ethanol refineries (7CEDF) currently operating or planning to operate in the United States in the near future. These seven refineries are designed to produce from 330,000 to 100 million gal of ethanol per year. The overall average estimated air emission rates for criteria, hazardous, and greenhouse gas pollutants at the 7CEDF are shown here in terms of tons per year and pounds per gallon of ethanol produced. Water use rates estimated for the cellulosic ethanol refineries are also noted. The air emissions are then compared with similar estimates from a U.S. cellulosic ethanol pilot plant, a commercial Canadian cellulosic ethanol refinery, four commercial U.S. corn ethanol refineries, and U.S. petroleum refineries producing gasoline. The U.S. Environmental Protection Agency (EPA) air pollution rules that may apply to cellulosic ethanol refineries are also discussed. Using the lowest estimated emission rates from these cellulosic ethanol demonstration facilities to project air emissions, EPA's major source thresholds for criteria and hazardous air pollutants might not be exceeded by cellulosic ethanol refineries that produce as high as 25 million gal per year of ethanol (95 ML). Emissions are expected to decrease at cellulosic ethanol refineries as the process matures and becomes more commercially viable.

Regional air quality impacts of future fire emissions in Sumatra and Kalimantan

NASA Astrophysics Data System (ADS)

Marlier, Miriam E.; DeFries, Ruth S.; Kim, Patrick S.; Gaveau, David L. A.; Koplitz, Shannon N.; Jacob, Daniel J.; Mickley, Loretta J.; Margono, Belinda A.; Myers, Samuel S.

2015-05-01

Fire emissions associated with land cover change and land management contribute to the concentrations of atmospheric pollutants, which can affect regional air quality and climate. Mitigating these impacts requires a comprehensive understanding of the relationship between fires and different land cover change trajectories and land management strategies. We develop future fire emissions inventories from 2010-2030 for Sumatra and Kalimantan (Indonesian Borneo) to assess the impact of varying levels of forest and peatland conservation on air quality in Equatorial Asia. To compile these inventories, we combine detailed land cover information from published maps of forest extent, satellite fire radiative power observations, fire emissions from the Global Fire Emissions Database, and spatially explicit future land cover projections using a land cover change model. We apply the sensitivities of mean smoke concentrations to Indonesian fire emissions, calculated by the GEOS-Chem adjoint model, to our scenario-based future fire emissions inventories to quantify the different impacts of fires on surface air quality across Equatorial Asia. We find that public health impacts are highly sensitive to the location of fires, with emissions from Sumatra contributing more to smoke concentrations at population centers across the region than Kalimantan, which had higher emissions by more than a factor of two. Compared to business-as-usual projections, protecting peatlands from fires reduces smoke concentrations in the cities of Singapore and Palembang by 70% and 40%, and by 60% for the Equatorial Asian region, weighted by the population in each grid cell. Our results indicate the importance of focusing conservation priorities on protecting both forested (intact or logged) peatlands and non-forested peatlands from fire, even after considering potential leakage of deforestation pressure to other areas, in order to limit the impact of fire emissions on atmospheric smoke concentrations and

Report: EPA Needs to Improve Its Efforts to Reduce Air Emissions at U.S. Ports

EPA Pesticide Factsheets

Report #09-P-0125, March 23, 2009. While EPA has issued air emissions regulations for most port sources, EPA’s actions to address air emissions from large oceangoing vessels in U.S. ports have not yet achieved the goals for protecting human health.

77 FR 65135 - National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-25

.... On February 12, 2010, the American Chemistry Council and the Society of Chemical Manufacturers and... National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources AGENCY... Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources (CMAS) that was...

Secondary Aluminum Production: National Emission Standards for Hazardous Air Pollutants

EPA Pesticide Factsheets

National emission standards for hazardous air pollutants (NESHAP) for new and existing sources at secondary aluminum production facilities. Includes rule history, summary, federal register citations and implementation information.

Modelling of radio emission from cosmic ray air showers

NASA Astrophysics Data System (ADS)

Ludwig, Marianne

2011-06-01

Cosmic rays entering the Earth's atmosphere induce extensive air showers consisting of up to billions of secondary particles. Among them, a multitude of electrons and positrons are generated. These get deflected in the Earth's magnetic field, creating time-varying transverse currents. Thereby, the air shower emits coherent radiation in the MHz frequency range measured by radio antenna arrays on the ground such as LOPES at the KIT. This detection method provides a possibility to study cosmic rays with energies above 1017 eV. At this time, the radio technique undergoes the change from prototype experiments to large scale application. Thus, a detailed understanding of the radio emission process is needed more than ever. Before starting this work, different models made conflicting predictions on the pulse shape and the amplitude of the radio signal. It turned out that a radiation component caused by the variation of the number of charged particles within the air shower was missed in several models. The Monte Carlo code REAS2 superposing the radiation of the individual air shower electrons and positrons was one of those. At this time, it was not known how to take the missing component into account. For REAS3, we developed and implemented the endpoint formalism, a universal approach, to calculate the radiation from each single particle. For the first time, we achieve a good agreement between REAS3 and MGMR, an independent and completely different simulation approach. In contrast to REAS3, MGMR is based on a macroscopic approach and on parametrisations of the air shower. We studied the differences in the underlying air shower models to explain the remaining deviations. For comparisons with LOPES data, we developed a new method which allows "top-down" simulations of air showers. From this, we developed an air shower selection criterion based on the number of muons measured with KASCADE to take shower-to-shower fluctuations for a single event analysis into account. With

CHARACTERIZATION OF OZONE EMISSIONS FROM AIR CLEANERS EQUIPPED WITH OZONE GENERATORS AND SENSOR AND FEEDBACK CONTROL CIRCUITRY

EPA Science Inventory

The paper give results of a characterization of ozone emissions from air cleaners equipped with ozone generators and sensor and feedback control circuitry. Ozone emission rates of several consumer appliances, marketed as indoor air treatment or air purification systems, were det...

Understanding Potential Air Emissions from a Cellulosic Biorefinery Producing Renewable Diesel Blendstock.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yimin; Heath, Garvin A.; Renzaglia, Jason

2015-06-22

The Energy Independence and Security Act of 2007, through the Renewable Fuel Standard (RFS), mandates increased use of biofuels, including cellulosic biofuels. The RFS is expected to spur the development of advanced biofuel technologies (e.g., new and innovative biofuel conversion pathways) as well as the construction of biorefineries (refineries that produce biofuels) using these technologies. To develop sustainable cellulosic biofuels, one of the goals of the Bioenergy Technologies Office (BETO) at the Department of Energy is to minimize air pollutants from the entire biofuel supply chain, as stated in their 2014 Multi-Year Program Plan (2014). Although biofuels in general havemore » been found to have lower life cycle greenhouse gas (GHG) emissions compared to petroleum fuels on an energy basis, biomass feedstock production, harvesting, transportation, processing and conversion are expected to emit a wide range of other air pollutants (e.g., criteria air pollutants, hazardous air pollutants), which could affect the environmental benefits of biofuels when displacing petroleum fuels. While it is important for policy makers, air quality planners and regulators, biofuel developers, and investors to understand the potential implications on air quality from a growing biofuel industry, there is a general lack of information and knowledge about the type, fate and magnitude of potential air pollutant emissions from the production of cellulosic biofuels due to the nascent stage of this emerging industry. This analysis assesses potential air pollutant emissions from a hypothetical biorefinery, selected by BETO for further research and development, which uses a biological conversion process of sugars to hydrocarbons to produce infrastructural-compatible renewable diesel blendstock from cellulosic biomass.« less

Quantifying automobile refinishing VOC air emissions - a methodology with estimates and forecasts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, S.P.; Rubick, C.

1996-12-31

Automobile refinishing coatings (referred to as paints), paint thinners, reducers, hardeners, catalysts, and cleanup solvents used during their application, contain volatile organic compounds (VOCs) which are precursors to ground level ozone formation. Some of these painting compounds create hazardous air pollutants (HAPs) which are toxic. This paper documents the methodology, data sets, and the results of surveys (conducted in the fall of 1995) used to develop revised per capita emissions factors for estimating and forecasting the VOC air emissions from the area source category of automobile refinishing. Emissions estimates, forecasts, trends, and reasons for these trends are presented. Future emissionsmore » inventory (EI) challenges are addressed in light of data availability and information networks.« less

Air emissions assessment from offshore oil activities in Sonda de Campeche, Mexico.

PubMed

Schifter, I; González-Macías, C; Miranda, A; López-Salinas, E

2005-10-01

Air emission data from offshore oil platforms, gas and oil processing installations and contribution of marine activities at the Sonda de Campeche, located at the Gulf of Mexico, were compiled and integrated to facilitate the study of long range transport of pollutants into the region. From this important region, roughly 76% of the total Mexican oil and gas production is obtained. It was estimated that the total air emissions of all contaminants are approximately 821,000 tons per year. Hydrocarbons are the largest pollutant emissions with 277,590 tons per year, generated during flaring activities, and SOx in second place with 185,907 tons per year. Marine and aviation activities contribute with less than 2% of total emissions. Mass of pollutants emitted per barrel of petroleum produced calculated in this work, are in the range reported by similar oil companies.

Global Scenarios of Air Pollutant Emissions from Road Transport through to 2050

PubMed Central

Takeshita, Takayuki

2011-01-01

This paper presents global scenarios of sulphur dioxide (SO2), nitrogen oxides (NOx), and particulate matter (PM) emissions from road transport through to 2050, taking into account the potential impacts of: (1) the timing of air pollutant emission regulation implementation in developing countries; (2) global CO2 mitigation policy implementation; and (3) vehicle cost assumptions, on study results. This is done by using a global energy system model treating the transport sector in detail. The major conclusions are the following. First, as long as non-developed countries adopt the same vehicle emission standards as in developed countries within a 30-year lag, global emissions of SO2, NOx, and PM from road vehicles decrease substantially over time. Second, light-duty vehicles and heavy-duty trucks make a large and increasing contribution to future global emissions of SO2, NOx, and PM from road vehicles. Third, the timing of air pollutant emission regulation implementation in developing countries has a large impact on future global emissions of SO2, NOx, and PM from road vehicles, whereas there is a possibility that global CO2 mitigation policy implementation has a comparatively small impact on them. PMID:21845172

Development of probabilistic emission inventories of air toxics for Jacksonville, Florida, USA.

PubMed

Zhao, Yuchao; Frey, H Christopher

2004-11-01

Probabilistic emission inventories were developed for 1,3-butadiene, mercury (Hg), arsenic (As), benzene, formaldehyde, and lead for Jacksonville, FL. To quantify inter-unit variability in empirical emission factor data, the Maximum Likelihood Estimation (MLE) method or the Method of Matching Moments was used to fit parametric distributions. For data sets that contain nondetected measurements, a method based upon MLE was used for parameter estimation. To quantify the uncertainty in urban air toxic emission factors, parametric bootstrap simulation and empirical bootstrap simulation were applied to uncensored and censored data, respectively. The probabilistic emission inventories were developed based on the product of the uncertainties in the emission factors and in the activity factors. The uncertainties in the urban air toxics emission inventories range from as small as -25 to +30% for Hg to as large as -83 to +243% for As. The key sources of uncertainty in the emission inventory for each toxic are identified based upon sensitivity analysis. Typically, uncertainty in the inventory of a given pollutant can be attributed primarily to a small number of source categories. Priorities for improving the inventories and for refining the probabilistic analysis are discussed.

Dilution-based emissions sampling from stationary sources: Part 2--Gas-fired combustors compared with other fuel-fired systems.

PubMed

England, Glenn C; Watson, John G; Chow, Judith C; Zielinska, Barbara; Chang, M C Oliver; Loos, Karl R; Hidy, George M

2007-01-01

With the recent focus on fine particle matter (PM2.5), new, self-consistent data are needed to characterize emissions from combustion sources. Such data are necessary for health assessment and air quality modeling. To address this need, emissions data for gas-fired combustors are presented here, using dilution sampling as the reference. The dilution method allows for collection of emitted particles under conditions simulating cooling and dilution during entry from the stack into the air. The sampling and analysis of the collected particles in the presence of precursor gases, SO2 nitrogen oxide, volatile organic compound, and NH3 is discussed; the results include data from eight gas fired units, including a dual-fuel institutional boiler and a diesel engine powered electricity generator. These data are compared with results in the literature for heavy-duty diesel vehicles and stationary sources using coal or wood as fuels. The results show that the gas-fired combustors have very low PM2.5 mass emission rates in the range of approximately 10(-4) lb/million Btu (MMBTU) compared with the diesel backup generator with particle filter, with approximately 5 x 10(-3) lb/MMBTU. Even higher mass emission rates are found in coal-fired systems, with rates of approximately 0.07 lb/MMBTU for a bag-filter-controlled pilot unit burning eastern bituminous coal. The characterization of PM2.5 chemical composition from the gas-fired units indicates that much of the measured primary particle mass in PM2.5 samples is organic or elemental carbon and, to a much less extent, sulfate. Metal emissions are quite low compared with the diesel engines and the coal- or wood-fueled combustors. The metals found in the gas-fired combustor particles are low in concentration, similar in concentration to ambient particles. The interpretation of the particulate carbon emissions is complicated by the fact that an approximately equal amount of particulate carbon (mainly organic carbon) is found on the

40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

Code of Federal Regulations, 2014 CFR

2014-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Emissions Guidelines and Compliance Times for Commercial and Industrial Solid Waste Incineration Units Model Rule-Air...

IACP (INTEGRATED AIR CANCER PROJECT) EMISSIONS: TRANSFORMATIONS AND FATE

EPA Science Inventory

As part of the Integrated Air Cancer Project (IACP), diluted emissions from wood stoves and automobiles were injected into a Teflon smog chamber and irradiated to simulate their photochemical transformation in the atmosphere. Changes in the chemical composition and physical prope...

SEMINAR PUBLICATION: ORGANIC AIR EMISSIONS FROM WASTE MANAGEMENT FACILITIES

EPA Science Inventory

The organic chemicals contained in wastes processed during waste management operations can volatilize into the atmosphere and cause toxic or carcinogenic effects or contribute to ozone formation. Because air emissions from waste management operations pose a threat to human health...

EMISSIONS OF AIR TOXICS FROM A SIMULATED CHARCOAL KILN

EPA Science Inventory

The report gives results of experiments in a laboratory-scale charcoal kiln simulator to evaluate emissions of hazardous air pollutants from the production of charcoal in Missouri-type kilns. Fixed combustion gases were measured using continuous monitors. In Addition, other pollu...

Aerial Sampling of Emissions from Biomass Pile Burns in ...

EPA Pesticide Factsheets

Abstract (already cleared). Emissions from burning piles of post-harvest timber slash in Grande Ronde, Oregon were sampled using an instrument platform lofted into the plume using a tether-controlled aerostat or balloon. Emissions of carbon monoxide, carbon dioxide, methane, particulate matter (PM2.5 µm), black carbon, ultraviolet absorbing PM, elemental/organic carbon, semi-volatile organics (polycyclic aromatic hydrocarbons and polychlorinated dibenzodioxins/dibenzofurans), filter-based metals, and volatile organics were sampled for determination of emission factors. The effect on emissions from covering or not covering piles with polyethylene sheets to prevent fuel wetting was determined. Results showed that the uncovered (“wet”) piles burned with lower combustion efficiency and higher emissions of volatile organic compounds. Results for other pollutants will also be discussed. This work determines the first known in-field emission factors for burning of timber slash piles. The results also document the effect on emissions of covering the piles with polyethylene covers to reduce the moisture content of the biomass.

Review of Singapore's air quality and greenhouse gas emissions: current situation and opportunities.

PubMed

Velasco, Erik; Roth, Matthias

2012-06-01

Singapore has many environmental accomplishments to its credit. Accessible data on air quality indicates that all criteria pollutants satisfy both U.S. Environmental Protection Agency (EPA) and World Health Organization (WHO) air quality standards and guidelines, respectively. The exception is PM2.5 (particles with an aerodynamic diameter < or = 2.5 microm), which is not currently considered a criteria pollutant in Singapore but may potentially be the major local air pollution problem and cause for health concern. Levels of other airborne pollutants as well as their physical and chemical processes associated with local formation, transformation, dispersion, and deposition are not known. According to available emission inventories, Singapore contribution to the total atmospheric pollution and carbon budget at the regional and global scales is small. Emissions per unit gross domestic product (GDP) are low compared with other countries, although Singapore's per-capita GDP and per-capita emissions are among the highest in the world. Some information is available on health effects, but the impacts on the ecosystem and the complex interactions of air pollution and climate change at a regional level are also unknown. This article reviews existing available information on atmospheric pollution and greenhouse gas emissions and proposes a multipollutant approach to greenhouse gas mitigation and local air quality. Singapore, by reducing its per-capita emissions, increasing the availability of information (e.g., through regularly publishing hourly and/or daily PM2.5 concentrations) and developing a research agenda in this area, would likely be seen to be a model of a high-density, livable, and sustainable city in Southeast Asia and other tropical regions worldwide.

Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong.

PubMed

Yan, H H; Guo, H; Ou, J M

2014-08-15

During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO2-equivelant (CO2-eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10(5)tons CO2-eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong. Copyright © 2014 Elsevier B.V. All rights reserved.

Assessment of air pollutant emissions from the Akrotiri landfill site (Chania, Greece).

PubMed

Chalvatzaki, E; Lazaridis, M

2010-09-01

Air pollutants emitted from landfills affect air quality, contribute to the greenhouse effect and may cause serious problems to human health under certain circumstances. The current study was focused on the determination of air emissions from the Akrotiri landfill site which is located in the Akrotiri area (Chania, Greece). The landfill consists of two phases, phase A (first phase) which is currently closed (operational between 2003 and 2007) and phase B (second phase, operation between 2007 and (foreseen) 2013). Three different emission models (the EPA LandGEM model, the triangular model and the stoichiometric model) were used for the quantification of emissions. The LandGEM 3.02 software was further adopted and used in conjunction with the long-term dispersion model ISC3-LT for the evaluation of the dispersion of gaseous chemical components from the landfill. The emission and meteorological conditions under which the models were applied were based on the worst-case emission scenario. Furthermore, the concentration of hydrogen sulfide, vinyl chloride and benzene were determined in and around the landfill site. The concentrations of hydrogen sulfide and benzene were calculated to be far below the limit value proposed by the World Health Organization (WHO) for human health safety. However, the vinyl chloride concentrations were above the WHO reference lifetime exposure health criteria for the phase B area.

55 FR 14037 Correction to the National Emission Standards for Hazardous Air Pollutants

EPA Pesticide Factsheets

Correction to the National Emission Standards for Hazardous Air Pollutants; Benzene Emissions From Maleic Anhydride Plants, Ethylbenzene/Styrene Plants, Benzene Storage Vessels, Benzene Equipment Leaks, and Coke Byproduct Recovery Plants.

Transport and Environment Database System (TRENDS): Maritime air pollutant emission modelling

NASA Astrophysics Data System (ADS)

Georgakaki, Aliki; Coffey, Robert A.; Lock, Graham; Sorenson, Spencer C.

This paper reports the development of the maritime module within the framework of the Transport and Environment Database System (TRENDS) project. A detailed database has been constructed for the calculation of energy consumption and air pollutant emissions. Based on an in-house database of commercial vessels kept at the Technical University of Denmark, relationships between the fuel consumption and size of different vessels have been developed, taking into account the fleet's age and service speed. The technical assumptions and factors incorporated in the database are presented, including changes from findings reported in Methodologies for Estimating air pollutant Emissions from Transport (MEET). The database operates on statistical data provided by Eurostat, which describe vessel and freight movements from and towards EU 15 major ports. Data are at port to Maritime Coastal Area (MCA) level, so a bottom-up approach is used. A port to MCA distance database has also been constructed for the purpose of the study. This was the first attempt to use Eurostat maritime statistics for emission modelling; and the problems encountered, since the statistical data collection was not undertaken with a view to this purpose, are mentioned. Examples of the results obtained by the database are presented. These include detailed air pollutant emission calculations for bulk carriers entering the port of Helsinki, as an example of the database operation, and aggregate results for different types of movements for France. Overall estimates of SO x and NO x emission caused by shipping traffic between the EU 15 countries are in the area of 1 and 1.5 million tonnes, respectively.

77 FR 41146 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-12

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 63 [EPA-R09-OAR-2012-0286; FRL-9698-6] Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories; Gila River Indian Community... emission standards for hazardous air pollutants (NESHAP) to the Gila River Indian Community Department of...

Study on Emission Spectral Lines of Iron, Fe in Laser-Induced Breakdown Spectroscopy (LIBS) on Soil Samples

NASA Astrophysics Data System (ADS)

Idris, Nasrullah; Lahna, Kurnia; Fadhli; Ramli, Muliadi

2017-05-01

In this work, LIBS technique has been used for detection of heavy metal especially iron, Fe in soil sample. As there are a large number of emission spectral lines due to Fe and other constituents in soil, this study is intended to identify emission spectral lines of Fe and finally to find best fit emission spectral lines for carrying out a qualitative and quantitative analysis. LIBS apparatus used in this work consists of a laser system (Neodymium Yttrium Aluminum Garnet, Nd-YAG: Quanta Ray; LAB SERIES; 1,064 nm; 500 mJ; 8 ns) and an optical multichannel analyzer (OMA) system consisting of a spectrograph (McPherson model 2061; 1,000 mm focal length; f/8.6 Czerny- Turner) and an intensified charge coupled device (ICCD) 1024x256 pixels (Andor I*Star). The soil sample was collected from Banda Aceh city, Aceh, Indonesia. For spectral data acquisition, the soil sample has been prepared by a pressing machine in the form of pellet. The laser beam was focused using a high density lens (f=+150 mm) and irradiated on the surface of the pellet for generating luminous plasma under 1 atmosphere of air surrounding. The plasma emission was collected by an optical fiber and then sent to the optical multichannel analyzer (OMA) system for acquisition of the emission spectra. It was found that there are many Fe emission lines both atomic lines (Fe I) and ionic lines (Fe II) appeared in all detection windows in the wavelength regions, ranging from 200 nm to 1000 nm. The emission lines of Fe with strong intensities occurs together with emission lines due to other atoms such as Mg, Ca, and Si. Thus, the identification of emission lines from Fe is complicated by presence of many other lines due to other major and minor elements in soil. Considering the features of the detected emission lines, several emission spectral lines of Fe I (atomic emission line), especially Fe I 404.58 nm occurring at visible range are potential to be good candidate of analytical lines in relation to detection

Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland.

PubMed

Buser, Andreas M; Kierkegaard, Amelie; Bogdal, Christian; MacLeod, Matthew; Scheringer, Martin; Hungerbühler, Konrad

2013-07-02

Tens of thousands of tonnes of cyclic volatile methylsiloxanes (cVMS) are used each year globally, which leads to high and continuous cVMS emissions to air. However, field measurements of cVMS in air and empirical information about emission rates to air are still limited. Here we present measurements of decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6) in air for Zurich, Switzerland. The measurements were performed in January and February 2011 over a period of eight days and at two sites (city center and background) with a temporal resolution of 6-12 h. Concentrations of D5 and D6 are higher in the center of Zurich and range from 100 to 650 ng m(-3) and from 10 to 79 ng m(-3), respectively. These values are among the highest levels of D5 and D6 reported in the literature. In a second step, we used a multimedia environmental fate model parametrized for the region of Zurich to interpret the levels and time trends in the cVMS concentrations and to back-calculate the emission rates of D5 and D6 from the city of Zurich. The average emission rates obtained for D5 and D6 are 120 kg d(-1) and 14 kg d(-1), respectively, which corresponds to per-capita emissions of 310 mg capita(-1) d(-1) for D5 and 36 mg capita(-1) d(-1) for D6.

Air Toxics Emissions from Open Burning of Crop Residues in Southeast Asia

NASA Astrophysics Data System (ADS)

KIM Oanh, N. T.; Permadi, D. A.; Hopke, P. K.; Smith, K. R.; Nguyet, D. A.

2016-12-01

Agricultural crops production in Southeast Asia (SEA) increases annually to meet domestic consumption of growing population and also for export. Crop residue open burning (CROB) is commonly practiced by farmers to quickly dispose of huge amounts of the agricultural waste, such as rice straw, generated after each crop cycle. This CROB activity emits various toxic air pollutants as well as short-lived climate pollutants such as black carbon particles. Our study focused on quantifying the 2015 annual emissions of semi-volatile organic compounds including polycyclic aromatic hydrocarbons (PAHs), dioxins/furans (PCDD/PCDF), organochlorine pesticides (OCP), along with other conventional trace gases, particulate matter, and greenhouse gases from CROB in 10 major agricultural crop producing SEA countries. Crop production statistics and current field OB practices were gathered from our primary surveys and relevant secondary data sources. Emission factors for rice straw and maize residue burning were taken mainly from our measurements in Thailand while for other crops relevant published data were used. The best emission estimates of air toxics from CROB in SEA were 112 g-TEQ/yr of PCDD/PCDF, 33 t/yr of OCP, and 25 Gg/yr of total PAH of which the well-known carcinogenic benzo[a]pyrene was 0.3 Gg/yr. The CROB of rice production had the highest shares of emissions (33-95%) among considered 8 crop types. Indonesia was the top contributor to the total SEA emissions (30-45%) followed by Vietnam (16-26%), Thailand (6-22%) and Myanmar (5-18%). The spatial distributions of emissions, 0.1º x 0.1º, for each specie were prepared using MODIS land cover data. Temporally, higher emissions were observed in the harvesting months of the main rice crops. This emissions database can be used in regional air quality modeling studies to assess the impacts of CROB activity and to promote non-open burning alternatives.

Emissions from oil and gas operations in the United States and their air quality implications.

PubMed

Allen, David T

2016-06-01

The energy supply infrastructure in the United States has been changing dramatically over the past decade. Increased production of oil and natural gas, particularly from shale resources using horizontal drilling and hydraulic fracturing, made the United States the world's largest producer of oil and natural gas in 2014. This review examines air quality impacts, specifically, changes in greenhouse gas, criteria air pollutant, and air toxics emissions from oil and gas production activities that are a result of these changes in energy supplies and use. National emission inventories indicate that volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from oil and gas supply chains in the United States have been increasing significantly, whereas emission inventories for greenhouse gases have seen slight declines over the past decade. These emission inventories are based on counts of equipment and operational activities (activity factors), multiplied by average emission factors, and therefore are subject to uncertainties in these factors. Although uncertainties associated with activity data and missing emission source types can be significant, multiple recent measurement studies indicate that the greatest uncertainties are associated with emission factors. In many source categories, small groups of devices or sites, referred to as super-emitters, contribute a large fraction of emissions. When super-emitters are accounted for, multiple measurement approaches, at multiple scales, produce similar results for estimated emissions. Challenges moving forward include identifying super-emitters and reducing their emission magnitudes. Work done to date suggests that both equipment malfunction and operational practices can be important. Finally, although most of this review focuses on emissions from energy supply infrastructures, the regional air quality implications of some coupled energy production and use scenarios are examined. These case studies suggest that both

Innovations in air sampling to detect plant pathogens

PubMed Central

West, JS; Kimber, RBE

2015-01-01

Many innovations in the development and use of air sampling devices have occurred in plant pathology since the first description of the Hirst spore trap. These include improvements in capture efficiency at relatively high air-volume collection rates, methods to enhance the ease of sample processing with downstream diagnostic methods and even full automation of sampling, diagnosis and wireless reporting of results. Other innovations have been to mount air samplers on mobile platforms such as UAVs and ground vehicles to allow sampling at different altitudes and locations in a short space of time to identify potential sources and population structure. Geographical Information Systems and the application to a network of samplers can allow a greater prediction of airborne inoculum and dispersal dynamics. This field of technology is now developing quickly as novel diagnostic methods allow increasingly rapid and accurate quantifications of airborne species and genetic traits. Sampling and interpretation of results, particularly action-thresholds, is improved by understanding components of air dispersal and dilution processes and can add greater precision in the application of crop protection products as part of integrated pest and disease management decisions. The applications of air samplers are likely to increase, with much greater adoption by growers or industry support workers to aid in crop protection decisions. The same devices are likely to improve information available for detection of allergens causing hay fever and asthma or provide valuable metadata for regional plant disease dynamics. PMID:25745191

[Estimation of average traffic emission factor based on synchronized incremental traffic flow and air pollutant concentration].

PubMed

Li, Run-Kui; Zhao, Tong; Li, Zhi-Peng; Ding, Wen-Jun; Cui, Xiao-Yong; Xu, Qun; Song, Xian-Feng

2014-04-01

On-road vehicle emissions have become the main source of urban air pollution and attracted broad attentions. Vehicle emission factor is a basic parameter to reflect the status of vehicle emissions, but the measured emission factor is difficult to obtain, and the simulated emission factor is not localized in China. Based on the synchronized increments of traffic flow and concentration of air pollutants in the morning rush hour period, while meteorological condition and background air pollution concentration retain relatively stable, the relationship between the increase of traffic and the increase of air pollution concentration close to a road is established. Infinite line source Gaussian dispersion model was transformed for the inversion of average vehicle emission factors. A case study was conducted on a main road in Beijing. Traffic flow, meteorological data and carbon monoxide (CO) concentration were collected to estimate average vehicle emission factors of CO. The results were compared with simulated emission factors of COPERT4 model. Results showed that the average emission factors estimated by the proposed approach and COPERT4 in August were 2.0 g x km(-1) and 1.2 g x km(-1), respectively, and in December were 5.5 g x km(-1) and 5.2 g x km(-1), respectively. The emission factors from the proposed approach and COPERT4 showed close values and similar seasonal trends. The proposed method for average emission factor estimation eliminates the disturbance of background concentrations and potentially provides real-time access to vehicle fleet emission factors.

DEVELOPMENT OF HAZARDOUS AIR POLLUTANT EMISSION FACTORS FROM STATE SOURCE TEST PROGRAMS

EPA Science Inventory

The report gives results of a study in which emission factors were evolved from test data obtained from several Air Quality Management Districts in California and from state environmental agencies in Louisiana, Maryland, New Jersey, and Texas. The emission factors were developed...

Urban air chemistry and diesel vehicles emissions: Quantifying small and big hydrocarbons by CIMS to improve emission inventories

NASA Astrophysics Data System (ADS)

Jobson, B. T.; Derstroff, B.; Edtbauer, A.; VanderSchelden, G. S.; Williams, J.

2017-10-01

Emissions from vehicles are a major source of volatile organic compounds (VOCs) in urban environments. Photochemical oxidation of VOCs emitted from vehicle exhaust contributes to O3 and PM2.5 formation, harmful pollutants that major urban areas struggle to control. How will a shift to a diesel engine fleet impact urban air chemistry? Diesel vehicles are a growing fraction of the passenger vehicle fleet in Europe as a result of a deliberate policy to reduce energy consumption and CO2 emissions from the transportation sector (Sullivan et al., 2004). In countries such as France the diesel passenger fleet was already ∼50% of the total in 2009, up from 20% in 1995. Dunmore et al. (2015) have recently inferred that in London, HO radical loss rates to organic compounds is dominated by diesel engine emissions. In the US, increasingly more stringent vehicles emission standards and requirement for improved energy efficiency means spark ignition passenger vehicle emissions have declined significantly over the last 20 years, resulting in the urban diesel fleet traffic (freight trucks) having a growing importance as a source of vehicle pollution (McDonald et al., 2013). The recent scandal involving a major car manufacturer rigging emission controls for diesel passenger cars is a reminder that real world emissions of VOCs from diesel engines are not well understood nor thoroughly accounted for in air quality modeling.

Contribution of ship emissions to the concentration and deposition of air pollutants in Europe

NASA Astrophysics Data System (ADS)

Aksoyoglu, S.; Prévôt, A. S. H.; Baltensperger, U.

2015-11-01

Emissions from the marine transport sector are one of the least regulated anthropogenic emission sources and contribute significantly to air pollution. Although strict limits were introduced recently for the maximum sulfur content in marine fuels in the SECAs (sulfur emission control areas) and in the EU ports, sulfur emissions outside the SECAs and emissions of other components in all European maritime areas have continued to increase in the last two decades. We have used the air quality model CAMx with and without ship emissions for the year 2006 to determine the effects of international shipping on the annual as well as seasonal concentrations of ozone, primary and secondary components of PM2.5 and the dry and wet deposition of nitrogen and sulfur compounds in Europe. Our results suggest that emissions from international shipping affect the air quality in northern and southern Europe differently and their contributions to the air concentrations vary seasonally. The largest changes in pollutant concentrations due to ship emissions were predicted for summer. Increased concentrations of the primary particle mass were found only along the shipping routes whereas concentrations of the secondary pollutants were affected over a larger area. Concentrations of particulate sulfate increased due to ship emissions in the Mediterranean (up to 60 %), in the English Channel and the North Sea (30-35 %) while increases in particulate nitrate levels were found especially in the north, around the Benelux area (20 %) where there were high NH3 land-based emissions. Our model results showed that not only the atmospheric concentrations of pollutants are affected by ship emissions, but also depositions of nitrogen and sulfur compounds increase significantly along the shipping routes. NOx emissions from the ships especially in the English Channel and the North Sea, cause a decrease in the dry deposition of reduced nitrogen at source regions by moving it from the gas-phase to the

Gas and Particulate Aircraft Emissions Measurements: Impacts on local air quality.

NASA Astrophysics Data System (ADS)

Jayne, J. T.; Onasch, T.; Northway, M.; Canagaratna, M.; Worsnop, D.; Timko, M.; Wood, E.; Miake-Lye, R.; Herndon, S.; Knighton, B.; Whitefield, P.; Hagen, D.; Lobo, P.; Anderson, B.

2007-12-01

Air travel and freight shipping by air are becoming increasingly important and are expected to continue to expand. The resulting increases in the local concentrations of pollutants, including particulate matter (PM), volatile organic compounds (VOCs), and nitrogen oxides (NOX), can have negative impacts on regional air quality, human health and can impact climate change. In order to construct valid emission inventories, accurate measurements of aircraft emissions are needed. These measurements must be done both at the engine exit plane (certification) and downwind following the rapid cooling, dilution and initial atmospheric processing of the exhaust plume. We present here results from multiple field experiments which include the Experiment to Characterize Volatile Aerosol and Trace Species Emissions (EXCAVATE) and the four Aircraft Particle Emissions eXperiments (APEX- 1/Atlanta/2/3) which characterized gas and particle emissions from both stationary or in-use aircraft. Emission indices (EIs) for NOx and VOCs and for particle number concentration, refractory PM (black carbon soot) and volatile PM (primarily sulfate and organic) particles are reported. Measurements were made at the engine exit plane and at several downstream locations (10 and 30 meters) for a number of different engine types and engine thrust settings. A significant fraction of organic particle mass is composed of low volatility oil-related compounds and is not combustion related, potentially emitted by vents or heated surfaces within aircraft engines. Advected plumes measurements from in-use aircraft show that the practice of reduced thrust take-offs has a significant effect on total NOx and soot emitted in the vicinity of the airport. The measurements reported here represent a first observation of this effect and new insights have been gained with respect to the chemical processing of gases and particulates important to the urban airshed.

Characterization and comparison of emissions from rudimentary waste disposal technologies

EPA Science Inventory

Results from 2011 simulation of burn pit emissions and air curtain incinerator emissions, recent developments in methods for open air sampling, comparison of waste energy technologies, current SERDP programs in this area.

Analyzing Air Pollutant Emissions from the Biofuel Supply Chain | Energy

Science.gov Websites

biomass-to-biofuels life cycle - fast-growing trees, agricultural waste, storage silos, and a biorefinery published in Chapter 9-"Implications of Air Pollutant Emissions from Producing Agricultural and

Modeling to Evaluate Contribution of Oil and Gas Emissions to Air Pollution.

PubMed

Thompson, Tammy M; Shepherd, Donald; Stacy, Andrea; Barna, Michael G; Schichtel, Bret A

2017-04-01

Oil and gas production in the Western United States has increased considerably over the past 10 years. While many of the still limited oil and gas impact assessments have focused on potential human health impacts, the typically remote locations of production in the Intermountain West suggests that the impacts of oil and gas production on national parks and wilderness areas (Class I and II areas) could also be important. To evaluate this, we utilize the Comprehensive Air quality Model with Extensions (CAMx) with a year-long modeling episode representing the best available representation of 2011 meteorology and emissions for the Western United States. The model inputs for the 2011 episodes were generated as part of the Three State Air Quality Study (3SAQS). The study includes a detailed assessment of oil and gas (O&G) emissions in Western States. The year-long modeling episode was run both with and without emissions from O&G production. The difference between these two runs provides an estimate of the contribution of the O&G production to air quality. These data were used to assess the contribution of O&G to the 8 hour average ozone concentrations, daily and annual fine particulate concentrations, annual nitrogen deposition totals and visibility in the modeling domain. We present the results for the Class I and II areas in the Western United States. Modeling results suggest that emissions from O&G activity are having a negative impact on air quality and ecosystem health in our National Parks and Class I areas. In this research, we use a modeling framework developed for oil and gas evaluation in the western United States to determine the modeled impacts of emissions associated with oil and gas production on air pollution metrics. We show that oil and gas production may have a significant negative impact on air quality and ecosystem health in some national parks and other Class I areas in the western United States. Our findings are of particular interest to federal

Miscellaneous Coating Manufacturing: National Emission Standards for Hazardous Air Pollutants (NESHAP)

EPA Pesticide Factsheets

The national emission standards for hazardous air pollutants for miscellaneous coating manufacturing. Includes summary, rule history, compliance and implementation information, federal registry citations.

The Impact of Future Emissions Changes on Air Pollution Concentrations and Related Human Health Effects

NASA Astrophysics Data System (ADS)

Mikolajczyk, U.; Suppan, P.; Williams, M.

2015-12-01

Quantification of potential health benefits of reductions in air pollution on the local scale is becoming increasingly important. The aim of this study is to conduct health impact assessment (HIA) by utilizing regionally and spatially specific data in order to assess the influence of future emission scenarios on human health. In the first stage of this investigation, a modeling study was carried out using the Weather Research and Forecasting (WRF) model coupled with Chemistry to estimate ambient concentrations of air pollutants for the baseline year 2009, and for the future emission scenarios in southern Germany. Anthropogenic emissions for the baseline year 2009 are derived from the emission inventory provided by the Netherlands Organization of Applied Scientific Research (TNO) (Denier van der Gon et al., 2010). For Germany, the TNO emissions were replaced by gridded emission data with a high spatial resolution of 1/64 x 1/64 degrees. Future air quality simulations are carried out under different emission scenarios, which reflect possible energy and climate measures in year 2030. The model set-up included a nesting approach, where three domains with horizontal resolution of 18 km, 6 km and 2 km were defined. The simulation results for the baseline year 2009 are used to quantify present-day health burdens. Concentration-response functions (CRFs) for PM2.5 and NO2 from the WHO Health risks of air Pollution in Europe (HRAPIE) project were applied to population-weighted mean concentrations to estimate relative risks and hence to determine numbers of attributable deaths and associated life-years lost. In the next step, future health impacts of projected concentrations were calculated taking into account different emissions scenarios. The health benefits that we assume with air pollution reductions can be used to provide options for future policy decisions to protect public health.

40 CFR 61.44 - Stack sampling.

Code of Federal Regulations, 2013 CFR

2013-07-01

... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Beryllium Rocket Motor... within 30 days after samples are taken and before any subsequent rocket motor firing or propellant...

40 CFR 61.44 - Stack sampling.

Code of Federal Regulations, 2014 CFR

2014-07-01

... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Beryllium Rocket Motor... within 30 days after samples are taken and before any subsequent rocket motor firing or propellant...

40 CFR 61.44 - Stack sampling.

Code of Federal Regulations, 2012 CFR

2012-07-01

... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Beryllium Rocket Motor... within 30 days after samples are taken and before any subsequent rocket motor firing or propellant...

Emissions into the Air from Bitumen and Rubber Bitumen-Implications for Asphalt Workers' Exposure.

PubMed

Nilsson, Patrik T; Bergendorf, Ulf; Tinnerberg, Håkan; Nordin, Erik; Gustavsson, Mats; Strandberg, Bo; Albin, Maria; Gudmundsson, Anders

2018-06-21

The risk among asphalt workers of developing adverse health effects may increase due to their occupational exposure. One area of special concern arises when rubber granules are mixed into bitumen to enhance asphalt properties. This research characterizes and compares bitumen and rubber bitumen regarding the emissions of and workers' exposure to particulates, polycyclic aromatic hydrocarbons (PAHs) and benzothiazole. A laboratory and a field study were carried out. In the laboratory, two types of bitumen, one with and one without rubber, were heated up to two temperatures (140°C and 160°C). The concentrations and chemical compositions of the emissions were determined. In the field at asphalt work sites, both emissions and worker exposure measurements were performed. The methods applied included direct-reading sampling techniques next to the asphalt work area and personal sampling techniques on asphalt workers. The exposure measurements on asphalt workers for respirable dust, total dust, particle number and mass, and total PAH concentrations showed similar concentrations when both standard and rubber bitumen were used. The asphalt-surfacing machine operators were the workers with the highest observed exposure followed by the screed operators and roller drivers. Both laboratory and field measurements showed higher concentrations of benzothiazole when rubber bitumen was used, up to 7.5 times higher in the laboratory. The levels of naphthalene, benzo(a)pyrene, and total particles were lower for both types compared with the Swedish occupational exposure limits, 8-h time weighted average concentrations. Benzo(a)pyrene exceeded however the health-based guideline value given by the WHO for both types of bitumen. The study concludes that several air pollutants such as benzothiazole and PAHs are emitted into the air during asphalt work, but it is not evident if exposure to rubber bitumen possesses a higher risk than exposure to standard bitumen in terms of asphalt worker

Updated emission inventories of power plants in simulating air quality during haze periods over East China

NASA Astrophysics Data System (ADS)

Zhang, Lei; Zhao, Tianliang; Gong, Sunling; Kong, Shaofei; Tang, Lili; Liu, Duanyang; Wang, Yongwei; Jin, Lianji; Shan, Yunpeng; Tan, Chenghao; Zhang, Yingjie; Guo, Xiaomei

2018-02-01

Air pollutant emissions play a determinant role in deteriorating air quality. However, an uncertainty in emission inventories is still the key problem for modeling air pollution. In this study, an updated emission inventory of coal-fired power plants (UEIPP) based on online monitoring data in Jiangsu Province of East China for the year of 2012 was implemented in the widely used Multi-resolution Emission Inventory for China (MEIC). By employing the Weather Research and Forecasting model with Chemistry (WRF-Chem), two simulation experiments were executed to assess the atmospheric environment change by using the original MEIC emission inventory and the MEIC inventory with the UEIPP. A synthetic analysis shows that power plant emissions of PM2.5, PM10, SO2, and NOx were lower, and CO, black carbon (BC), organic carbon (OC) and NMVOCs (non-methane volatile organic compounds) were higher in UEIPP relative to those in MEIC, reflecting a large discrepancy in the power plant emissions over East China. In accordance with the changes in UEIPP, the modeled concentrations were reduced for SO2 and NO2, and increased for most areas of primary OC, BC, and CO. Interestingly, when the UEIPP was used, the atmospheric oxidizing capacity significantly reinforced. This was reflected by increased oxidizing agents, e.g., O3 and OH, thus directly strengthening the chemical production from SO2 and NOx to sulfate and nitrate, respectively, which offset the reduction of primary PM2.5 emissions especially on haze days. This study indicates the importance of updating air pollutant emission inventories in simulating the complex atmospheric environment changes with implications on air quality and environmental changes.

Contribution of ship emissions to the concentration and deposition of air pollutants in Europe

NASA Astrophysics Data System (ADS)

Aksoyoglu, Sebnem; Baltensperger, Urs; Prévôt, André S. H.

2016-02-01

Emissions from the marine transport sector are one of the least-regulated anthropogenic emission sources and contribute significantly to air pollution. Although strict limits were introduced recently for the maximum sulfur content in marine fuels in the SECAs (sulfur emission control areas) and in EU ports, sulfur emissions outside the SECAs and emissions of other components in all European maritime areas have continued to increase in the last two decades. We have used the air quality model CAMx (Comprehensive Air Quality Model with Extensions) with and without ship emissions for the year 2006 to determine the effects of international shipping on the annual as well as seasonal concentrations of ozone, primary and secondary components of PM2.5, and the dry and wet deposition of nitrogen and sulfur compounds in Europe. The largest changes in pollutant concentrations due to ship emissions were predicted for summer. Concentrations of particulate sulfate increased due to ship emissions in the Mediterranean (up to 60 %), the English Channel and the North Sea (30-35 %), while increases in particulate nitrate levels were found especially in the north, around the Benelux area (20 %), where there were high NH3 land-based emissions. Our model results showed that not only are the atmospheric concentrations of pollutants affected by ship emissions, but also depositions of nitrogen and sulfur compounds increase significantly along the shipping routes. NOx emissions from the ships, especially in the English Channel and the North Sea, cause a decrease in the dry deposition of reduced nitrogen at source regions by moving it from the gas phase to the particle phase which then contributes to an increase in the wet deposition at coastal areas with higher precipitation. In the western Mediterranean region, on the other hand, model results show an increase in the deposition of oxidized nitrogen (mostly HNO3) due to the ship traffic. Dry deposition of SO2 seems to be significant along

Pesticide Active Ingredient Production Industry: National Emission Standards for Hazardous Air Pollutants (NESHAP)

EPA Pesticide Factsheets

This action promulgates national emission standards for hazardous air pollutants (NESHAP) for the pesticide active ingredient (PAI) production source category under section 112 of the Clean Air Act as amended (CAA or Act).

Performance and emission characteristics of swirl-can combustors to near-stoichiometric fuel-air ratio

NASA Technical Reports Server (NTRS)

Diehl, L. A.; Trout, A. M.

1976-01-01

Emissions and performance characteristics were determined for two full annular swirl-can combustors operated to near stoichiometric fuel-air ratio. Test condition variations were as follows: combustor inlet-air temperatures, 589, 756, 839, and 894 K; reference velocities, 24 to 37 meters per second; inlet pressure, 62 newtons per square centimeter; and fuel-air ratios, 0.015 to 0.065. The combustor average exit temperature and combustor efficiency were calculated from the combustor exhaust gas composition. For fuel-air ratios greater than 0.04, the combustion efficiency decreased with increasing fuel-air ratios in a near-linear manner. Increasing the combustor inlet air temperature tended to offset this decrease. Maximum oxides of nitrogen emission indices occurred at intermediate fuel-air ratios and were dependent on combustor design. Carbon monoxide levels were extremely high and were the primary cause of poor combustion efficiency at the higher fuel-air ratios. Unburned hydrocarbons were low for all test conditions. For high fuel-air ratios SAE smoke numbers greater than 25 were produced, except at the highest inlet-air temperatures.

76 FR 17287 - Protocol Gas Verification Program and Minimum Competency Requirements for Air Emission Testing

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-28

...EPA is finalizing rule revisions that modify existing requirements for sources affected by the federally administered emission trading programs including the NOX Budget Trading Program, the Acid Rain Program, and the Clean Air Interstate Rule. EPA is amending its Protocol Gas Verification Program (PGVP) and the minimum competency requirements for air emission testing (formerly air emission testing body requirements) to improve the accuracy of emissions data. EPA is also amending other sections of the Acid Rain Program continuous emission monitoring system regulations by adding and clarifying certain recordkeeping and reporting requirements, removing the provisions pertaining to mercury monitoring and reporting, removing certain requirements associated with a class-approved alternative monitoring system, disallowing the use of a particular quality assurance option in EPA Reference Method 7E, adding two incorporation by references that were inadvertently left out of the January 24, 2008 final rule, adding two new definitions, revising certain compliance dates, and clarifying the language and applicability of certain provisions.

Presence of organophosphorus pesticide oxygen analogs in air samples

NASA Astrophysics Data System (ADS)

Armstrong, Jenna L.; Fenske, Richard A.; Yost, Michael G.; Galvin, Kit; Tchong-French, Maria; Yu, Jianbo

2013-02-01

A number of recent toxicity studies have highlighted the increased potency of oxygen analogs (oxons) of several organophosphorus (OP) pesticides. These findings were a major concern after environmental oxons were identified in environmental samples from air and surfaces following agricultural spray applications in California and Washington State. This paper reports on the validity of oxygen analog measurements in air samples for the OP pesticide, chlorpyrifos. Controlled environmental and laboratory experiments were used to examine artificial formation of chlorpyrifos-oxon using OSHA Versatile Sampling (OVS) tubes as recommended by NIOSH method 5600. Additionally, we compared expected chlorpyrifos-oxon attributable to artificial transformation to observed chlorpyrifos-oxon in field samples from a 2008 Washington State Department of Health air monitoring study using non-parametric statistical methods. The amount of artificially transformed oxon was then modeled to determine the amount of oxon present in the environment. Toxicity equivalency factors (TEFs) for chlorpyrifos-oxon were used to calculate chlorpyrifos-equivalent air concentrations. The results demonstrate that the NIOSH-recommended sampling matrix (OVS tubes with XAD-2 resin) was found to artificially transform up to 30% of chlorpyrifos to chlorpyrifos-oxon, with higher percentages at lower concentrations (<30 ng m-3) typical of ambient or residential levels. Overall, the 2008 study data had significantly greater oxon than expected by artificial transformation, but the exact amount of environmental oxon in air remains difficult to quantify with the current sampling method. Failure to conduct laboratory analysis for chlorpyrifos-oxon may result in underestimation of total pesticide concentration when using XAD-2 resin matrices for occupational or residential sampling. Alternative methods that can accurately measure both OP pesticides and their oxygen analogs should be used for air sampling, and a toxicity

Combustion and NOx emission characteristics with respect to staged-air damper opening in a 600 MWe down-fired pulverized-coal furnace under deep-air-staging conditions.

PubMed

Kuang, Min; Li, Zhengqi; Wang, Zhihua; Jing, Xinjing; Liu, Chunlong; Zhu, Qunyi; Ling, Zhongqian

2014-01-01

Deep-air-staging combustion conditions, widely used in tangential-fired and wall-arranged furnaces to significantly reduce NOx emissions, are premature up to now in down-fired furnaces that are designed especially for industry firing low-volatile coals such as anthracite and lean coal. To uncover combustion and NOx emission characteristics under deep-air-staging conditions within a newly operated 600 MWe down-fired furnace and simultaneously understand the staged-air effect on the furnace performance, full-load industrial-size measurements taken of gas temperatures and species concentrations in the furnace, CO and NOx emissions in flue gas, and carbon in fly ash were performed at various staged-air damper openings of 10%, 20%, 30%, and 50%. Increasing the staged-air damper opening, gas temperatures along the flame travel (before the flame penetrating the staged-air zone) increased initially but then decreased, while those in the staged-air zone and the upper part of the hopper continuously decreased and increased, respectively. On opening the staged-air damper to further deepen the air-staging conditions, O2 content initially decreased but then increased in both two near-wall regions affected by secondary air and staged air, respectively, whereas CO content in both two regions initially increased but then decreased. In contrast to the conventional understanding about the effects of deep-air-staging conditions, here increasing the staged-air damper opening to deepen the air-staging conditions essentially decreased the exhaust gas temperature and carbon in fly ash and simultaneously increased both NOx emissions and boiler efficiency. In light of apparently low NOx emissions and high carbon in fly ash (i.e., 696-878 mg/m(3) at 6% O2 and 9.81-13.05%, respectively) developing in the down-fired furnace under the present deep-air-staging conditions, further adjustments such as enlarging the staged-air declination angle to prolong pulverized-coal residence times in the

Research and development of a field-ready protocol for sampling of phosgene from stationary source emissions: Diethylamine reagent studies. Research report, 11 July 1995--30 September 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steger, J.L.; Bursey, J.T.; Merrill, R.G.

1999-03-01

This report presents the results of laboratory studies to develop and evaluate a method for the sampling and analysis of phosgene from stationary sources of air emissions using diethylamine (DEA) in toluene as the collection media. The method extracts stack gas from emission sources and stabilizes the reactive gas for subsequent analysis. DEA was evaluated both in a benchtop study and in a laboratory train spiking study. This report includes results for both the benchtop study and the train spiking study. Benchtop studies to evaluate the suitability of DEA for collecting and analyzing phosgene investigated five variables: storage time, DEAmore » concentration, moisture/pH, phosgene concentration, and sample storage temperature. Prototype sampling train studies were performed to determine if the benchtop chemical studies were transferable to a Modified Method 5 sampling train collecting phosgene in the presence of clean air mixed with typical stack gas components. Four conditions, which varied the moisture and phosgene spike were evaluated in triplicate. In addition to research results, the report includes a detailed draft method for sampling and analysis of phosgene from stationary source emissions.« less

International trade and air pollution: estimating the economic costs of air emissions from waterborne commerce vessels in the United States.

PubMed

Gallagher, Kevin P

2005-10-01

Although there is a burgeoning literature on the effects of international trade on the environment, relatively little work has been done on where trade most directly effects the environment: the transportation sector. This article shows how international trade is affecting air pollution emissions in the United States' shipping sector. Recent work has shown that cargo ships have been long overlooked regarding their contribution to air pollution. Indeed, ship emissions have recently been deemed "the last unregulated source of traditional air pollutants". Air pollution from ships has a number of significant local, national, and global environmental effects. Building on past studies, we examine the economic costs of this increasing and unregulated form of environmental damage. We find that total emissions from ships are largely increasing due to the increase in foreign commerce (or international trade). The economic costs of SO2 pollution range from dollars 697 million to dollars 3.9 billion during the period examined, or dollars 77 to dollars 435 million on an annual basis. The bulk of the cost is from foreign commerce, where the annual costs average to dollars 42 to dollars 241 million. For NOx emissions the costs are dollars 3.7 billion over the entire period or dollars 412 million per year. Because foreign trade is driving the growth in US shipping, we also estimate the effect of the Uruguay Round on emissions. Separating out the effects of global trade agreements reveals that the trade agreement-led emissions amounted to dollars 96 to dollars 542 million for SO2 between 1993 and 2001, or dollars 10 to dollars 60 million per year. For NOx they were dollars 745 million for the whole period or dollars 82 million per year. Without adequate policy responses, we predict that these trends and costs will continue into the future.

Aerial sampling of emissions from biomass pile burns in ...

EPA Pesticide Factsheets

Emissions from burning piles of post-harvest timber slash in Grande Ronde, Oregon were sampled using an instrument platform lofted into the plume using a tether-controlled aerostat or balloon. Emissions of carbon monoxide, carbon dioxide, methane, particulate matter (PM2.5 µm), black carbon, ultraviolet absorbing PM, elemental/organic carbon, semi-volatile organics (polycyclic aromatic hydrocarbons and polychlorinated dibenzodioxins/dibenzofurans), filter-based metals, and volatile organics were sampled for determination of emission factors. The effect on emissions from covering or not covering piles with polyethylene sheets to prevent fuel wetting was determined. Results showed that the uncovered (“wet”) piles burned with lower combustion efficiency and higher emissions of volatile organic compounds. Results for other pollutants will also be discussed. This work determined the emissions from open burning of forest slash wood, with and without plastic sheeting. The foresters advocate the use of plastic to keep the slash wood dry and aid in the controlled combustion of the slash to reduce fuel loading. Concerns about the emissions from the burning plastic prompted this work which conducted an extensive characterization of dry, wet, and dry with plastic slash pile emissions.

Quantifying Molecular Hydrogen Emissions and an Industrial Leakage Rate for the South Coast Air Basin of California

NASA Astrophysics Data System (ADS)

Irish, M. C.; Schroeder, J.; Beyersdorf, A. J.; Blake, D. R.

2015-12-01

The poorly understood atmospheric budget and distribution of molecular hydrogen (H2) have invited further research since the discovery that emissions from a hydrogen-based economy could have negative impacts on the global climate system and stratospheric ozone. The burgeoning fuel cell electric vehicle industry in the South Coast Air Basin of California (SoCAB) presents an opportunity to observe and constrain urban anthropogenic H2 emissions. This work presents the first H2 emissions estimate for the SoCAB and calculates an upper limit for the current rate of leakage from production and distribution infrastructure within the region. A top-down method utilized whole air samples collected during the Student Airborne Research Program (SARP) onboard the NASA DC-8 research aircraft from 23-25 June 2015 to estimate H2 emissions from combustion and non-combustion sources. H2:carbon monoxide (CO) and H2:carbon dioxide ratios from airborne observations were compared with experimentally established ratios from pure combustion source ratios and scaled with the well-constrained CO emissions inventory to yield H2 emissions of 24.9 ± 3.6 Gg a-1 (1σ) from combustion engines and 8.2 ± 4.7 Gg a-1 from non-combustion sources. Total daily production of H2 in the SoCAB was compared with the top-down results to estimate an upper limit leakage rate (5%) where all emissions not accounted for by incomplete combustion in engines were assumed to be emitted from H2 infrastructure. For bottom-up validation, the NOAA Hybrid Single Particle Lagrangian Integrated Trajectory dispersion model was run iteratively with all known stationary sources in attempt to constrain emissions. While this investigation determined that H2 emissions from non-combustion sources in the SoCAB are likely significant, more in-depth analysis is required to better predict the atmospheric implications of a hydrogen economy.

Industrial Process Cooling Towers: National Emission Standards for Hazardous Air Pollutants

EPA Pesticide Factsheets

Standards limiting discharge of chromium compound air emissions from industrial process cooling towers (IPCT's). Includes rule history, Federal Registry citations, implementation information and additional resources.

Organic Liquids Distribution: National Emission Standards for Hazardous Air Pollutants (NESHAP)

EPA Pesticide Factsheets

National emission standards for hazardous air pollutants (NESHAP) for organic liquidsdistribution (OLD) (non-gasoline) operations. Includes rule history, Federal Registry citations, implementation and compliance information.

Analysis of EPA and DOE WIPP Air Sampling Data

EPA Pesticide Factsheets

During the April 2014 EPA visit to WIPP, EPA co-located four ambient air samplers with existing Department of Energy (DOE) ambient air samplers to independently corroborate DOE's reported air sampling results.

Evaluation of speciated VOC emission factors for Air Force hush houses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sullivan, P.D.; Stevens, D.K.

1997-12-31

Data published in: ``Engine and Hush House Emissions from a TF30-P109 Jet Engine Tested at Cannon Air Force Base, NM`` by Radian Corporation and ``Aircraft Emissions. Characterization: TF41-A2, TF30-P103 , and TF30-P109 Engines`` by Battelle are reviewed and compared. Specifically CO, NO{sub x}, and VOC emission factors using EPA Method 19 are addressed, with comparisons between JP-4 and JP-8 jet fuels. CO and NO{sub x} emissions for JP-4 and JP-8 jet fuels were found to be essentially the same. VOC emission data exhibited high variability. Problems inherent in speciated VOC emission testing are discussed. A limiting of speciated VOC emissionmore » testing, with emission factor estimation based on fuel content is proposed.« less

[Microbial air monitoring in operating theatre: active and passive samplings].

PubMed

Pasquarella, C; Masia, M D; Nnanga, Nga; Sansebastiano, G E; Savino, A; Signorelli, C; Veronesi, L

2004-01-01

Microbial air contamination was evaluated in 11 operating theatres using active and passive samplings. SAS (Surface Air System) air sampling was used to evaluate cfu/m3 and settle plates were used to measure the index of microbial air contamination (IMA). Samplings were performed at the same time on three different days, at three different times (before, during and after the surgical activity). Two points were monitored (patient area and perimeter of the operating theatre). Moreover, the cfu/m3 were evaluated at the air inlet of the conditioner system. 74.7% of samplings performed at the air inlet and 66.7% of the samplings performed at the patient area before the beginning of the surgical activity (at rest) exceeded the 35 cfu/m3 used as threshold value. 100% of IMA values exceeded the threshold value of 5. Using both active and passive sampling, the microbial contamination was shown to increase significantly during activity. The cfu values were higher at the patient area than at the perimeter of the operating theatre. Mean values of the cfu/m3 during activity at the patient area ranged from a minimum of 61+/-41 cfu/m3 to a maximum of 242+/-136 cfu/m3; IMA values ranged from a minimum of 19+/-10 to a maximum of 129+/-60. 15.2% of samplings performed at the patient area using SAS and 75.8% of samplings performed using settle plates exceeded the threshold values of 180 cfu/m3 and 25 respectively, with a significant difference of the percentages. The highest values were found in the operating theatre with inadequate structural and managerial conditions. These findings confirm that the microbiological quality of air may be considered a mirror of the hygienic conditions of the operating theatre. Settle plates proved to be more sensitive in detecting the increase of microbial air contamination related to conditions that could compromise the quality of the air in operating theatres.

75 FR 31317 - National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Paints and...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-03

... National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Paints and Allied... when they should not be covered. This action clarifies text of the National Emission Standards for Hazardous Air Pollutants: Paints and Allied Products Manufacturing Area Source Standards which was published...

40 CFR 90.419 - Raw emission sampling calculations-gasoline fueled engines.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw emission sampling calculations... KILOWATTS Gaseous Exhaust Test Procedures § 90.419 Raw emission sampling calculations—gasoline fueled... selected as the basis for mass emission calculations using the raw gas method. ER03JY95.022 Where: WHC...

40 CFR 90.419 - Raw emission sampling calculations-gasoline fueled engines.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw emission sampling calculations... KILOWATTS Gaseous Exhaust Test Procedures § 90.419 Raw emission sampling calculations—gasoline fueled... selected as the basis for mass emission calculations using the raw gas method. ER03JY95.022 Where: WHC...

Pharmaceuticals Production Industry: National Emission Standards for Hazardous Air Pollutants (NESHAP)

EPA Pesticide Factsheets

National emission standards for hazardous air pollutants (NESHAP) from facilities that manufacture pharmaceutical products. Includes rule history, Federal Register citations, implementation and compliance information, and additional resources.

Ethanol emission from loose corn silage and exposed silage particles

NASA Astrophysics Data System (ADS)

Hafner, Sasha D.; Montes, Felipe; Rotz, C. Alan; Mitloehner, Frank

2010-11-01

Silage on dairy farms has been identified as a major source of volatile organic compound (VOC) emissions. However, rates of VOC emission from silage are not accurately known. In this work, we measured ethanol (a dominant silage VOC) emission from loose corn silage and exposed corn silage particles using wind tunnel systems. Flux of ethanol was highest immediately after exposing loose silage samples to moving air (as high as 220 g m -2 h -1) and declined by as much as 76-fold over 12 h as ethanol was depleted from samples. Emission rate and cumulative 12 h emission increased with temperature, silage permeability, exposed surface area, and air velocity over silage samples. These responses suggest that VOC emission from silage on farms is sensitive to climate and management practices. Ethanol emission rates from loose silage were generally higher than previous estimates of total VOC emission rates from silage and mixed feed. For 15 cm deep loose samples, mean cumulative emission was as high as 170 g m -2 (80% of initial ethanol mass) after 12 h of exposure to an air velocity of 5 m s -1. Emission rates measured with an emission isolation flux chamber were lower than rates measured in a wind tunnel and in an open setting. Results show that the US EPA emission isolation flux chamber method is not appropriate for estimating VOC emission rates from silage in the field.

Objective Measure of Nasal Air Emission Using Nasal Accelerometry

ERIC Educational Resources Information Center

Cler, Meredith J.; Lien, Yu-An, S.; Braden, Maia N.; Mittleman, Talia; Downing, Kerri; Stepp, Cara, E.

2016-01-01

Purpose: This article describes the development and initial validation of an objective measure of nasal air emission (NAE) using nasal accelerometry. Method: Nasal acceleration and nasal airflow signals were simultaneously recorded while an expert speech language pathologist modeled NAEs at a variety of severity levels. In addition, microphone and…

A simple novel device for air sampling by electrokinetic capture.

PubMed

Gordon, Julian; Gandhi, Prasanthi; Shekhawat, Gajendra; Frazier, Angel; Hampton-Marcell, Jarrad; Gilbert, Jack A

2015-12-27

A variety of different sampling devices are currently available to acquire air samples for the study of the microbiome of the air. All have a degree of technical complexity that limits deployment. Here, we evaluate the use of a novel device, which has no technical complexity and is easily deployable. An air-cleaning device powered by electrokinetic propulsion has been adapted to provide a universal method for collecting samples of the aerobiome. Plasma-induced charge in aerosol particles causes propulsion to and capture on a counter-electrode. The flow of ions creates net bulk airflow, with no moving parts. A device and electrode assembly have been re-designed from air-cleaning technology to provide an average air flow of 120 lpm. This compares favorably with current air sampling devices based on physical air pumping. Capture efficiency was determined by comparison with a 0.4 μm polycarbonate reference filter, using fluorescent latex particles in a controlled environment chamber. Performance was compared with the same reference filter method in field studies in three different environments. For 23 common fungal species by quantitative polymerase chain reaction (qPCR), there was 100 % sensitivity and apparent specificity of 87 %, with the reference filter taken as "gold standard." Further, bacterial analysis of 16S RNA by amplicon sequencing showed equivalent community structure captured by the electrokinetic device and the reference filter. Unlike other current air sampling methods, capture of particles is determined by charge and so is not controlled by particle mass. We analyzed particle sizes captured from air, without regard to specific analyte by atomic force microscopy: particles at least as low as 100 nM could be captured from ambient air. This work introduces a very simple plug-and-play device that can sample air at a high-volume flow rate with no moving parts and collect particles down to the sub-micron range. The performance of the device is

National Emission Standards for Hazardous Air Pollutants in Region 7

EPA Pesticide Factsheets

National Emission Standards for Hazardous Air Pollutants (NESHAPs) are applicable requirements under the Title V operating permit program. This is a resource for permit writers and reviewers to learn about the rules and explore other helpful tools.

Influence of Air Pollutant Emission Controls on the "Climate Penalty" in the United States

NASA Astrophysics Data System (ADS)

Feng, T.; Couzo, E. A.; Selin, N. E.; Garcia-Menendez, F.; Monier, E.

2016-12-01

Previous work has examined the so-called "climate penalty" (or benefit, where climate change leads to decreased pollutant concentrations) for the U.S. In particular, previous research has identified the role of changes in temperature, precipitation, relative humidity, and biogenic emissions, in altering concentrations of O3 and PM2.5, when emissions of air pollutant precursors are held constant. However, changes in emissions of those precursors can also affect the magnitude of climate penalty/benefit. The effect of changing air pollutant emissions on the climate penalty/benefit has not been systematically studied. Here, we estimate the U.S. climate penalty (for O3 and PM2.5) as a function of four different local (U.S.) non-GHG emissions scenarios using the GEOS-Chem chemical transport model coupled to the MIT Integrated Global System Model linked to the Community Atmosphere Model (IGSM-CAM). Our base case scenario includes global and regional emissions for 2006. We conduct three sensitivity scenarios that adjust U.S. air pollutant precursor (non-GHG) emissions by -50%, +50%, and +100%; global emissions are kept at 2006 levels. This allows us to quantify the avoided climate penalty achieved by non-GHG emissions reductions. To capture inter-annual meteorological variability, our climate penalty calculations use 20-year averages for the present (1991-2010) and future (2091-2110) climate under a no-policy scenario. Consistent with previous work, we find a "climate penalty" for O3 and PM2.5 in U.S. by 2100 across all four scenarios. We also find a climate-related decrease in the concentration of NOx and nitrate, and an increase in black carbon, organic carbon and sulfate. Changes in ammonium are spatially inhomogeneous, with an increase in eastern U.S. and a decrease in middle and western U.S. When air pollutant precursor emissions increase, we find that the O3 "climate penalty" is enhanced. However, the response of the PM2.5 "climate penalty" to changed emissions

Monitoring iodine-129 in air and milk samples collected near the Hanford Site: an investigation of historical iodine monitoring data.

PubMed

Fritz, Brad G; Patton, Gregory W

2006-01-01

While other research has reported on the concentrations of (129)I in the environment surrounding active nuclear fuel reprocessing facilities, there is a shortage of information regarding how the concentrations change once facilities close. At the Hanford Site, the Plutonium-Uranium Extraction (PUREX) chemical separation plant was operating between 1983 and 1990, during which time (129)I concentrations in air and milk were measured. After the cessation of chemical processing, plant emissions decreased 2.5 orders of magnitude over an 8-year period. An evaluation of (129)I and (127)I concentration data in air and milk spanning the PUREX operation and post-closure period was conducted to compare the changes in environmental levels. Measured concentrations over the monitoring period were below the levels that could result in a potential annual human dose greater than 1 mSv. There was a measurable difference in the measured air concentrations of (129)I at different distances from the source, indicating a distinct Hanford fingerprint. Correlations between stack emissions of (129)I and concentrations in air and milk indicate that atmospheric emissions were the major source of (129)I measured in environmental samples. The measured concentrations during PUREX operations were similar to observations made around a fuel reprocessing plant in Germany. After the PUREX Plant stopped operating, (129)I concentration measurements made upwind of Hanford were similar to the results from Seville, Spain.