Science.gov

Sample records for air emissions including

  1. Swozzle based burner tube premixer including inlet air conditioner for low emissions combustion

    DOEpatents

    Tuthill, Richard Sterling; Bechtel, II, William Theodore; Benoit, Jeffrey Arthur; Black, Stephen Hugh; Bland, Robert James; DeLeonardo, Guy Wayne; Meyer, Stefan Martin; Taura, Joseph Charles; Battaglioli, John Luigi

    2002-01-01

    A burner for use in a combustion system of a heavy-duty industrial gas turbine includes a fuel/air premixer having an air inlet, a fuel inlet, and an annular mixing passage. The fuel/air premixer mixes fuel and air into a uniform mixture for injection into a combustor reaction zone. The burner also includes an inlet flow conditioner disposed at the air inlet of the fuel/air premixer for controlling a radial and circumferential distribution of incoming air. The pattern of perforations in the inlet flow conditioner is designed such that a uniform air flow distribution is produced at the swirler inlet annulus in both the radial and circumference directions. The premixer includes a swozzle assembly having a series of preferably air foil shaped turning vanes that impart swirl to the airflow entering via the inlet flow conditioner. Each air foil contains internal fuel flow passages that introduce natural gas fuel into the air stream via fuel metering holes that pass through the walls of the air foil shaped turning vanes. By injecting fuel in this manner, an aerodynamically clean flow field is maintained throughout the premixer. By injecting fuel via two separate passages, the fuel/air mixture strength distribution can be controlled in the radial direction to obtain optimum radial concentration profiles for control of emissions, lean blow outs, and combustion driven dynamic pressure activity as machine and combustor load are varied.

  2. Compilation of air pollutant emission factors, third edition (including supplements 1-7) supplement 12

    SciTech Connect

    Not Available

    1981-04-01

    In this Supplement for AP-42, revised or updated emissions data are presented for Dry Cleaning; Surface Coating; Storage of Organic Liquids; Solvent Degreasing; Graphic Arts; Consumer/commercial Solvent Use; Sulfuric Acid; Beer Making; Ammonium Sulfate; Primary Aluminum; Secondary Aluminum; Gray Iron Foundries; Steel Foundries; Secondary Zinc; Asphaltic Concrete; Asphalt Roofing; NEDS Source Classification Codes and Emission Factor Listing; and Table of Lead Emission Factors.

  3. Air emissions inventory for the Idaho National Engineering Laboratory -- 1995 emissions report

    SciTech Connect

    1996-06-01

    This report presents the 1995 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources. The air contaminants reported include nitrogen oxides, sulfur oxides, carbon monoxide, volatile organic compounds, particulates, and hazardous air pollutants (HAPs).

  4. Air Emission Inventory for the INEEL -- 1999 Emission Report

    SciTech Connect

    Zohner, Steven K

    2000-05-01

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  5. Incinerator air emissions: Inhalation exposure perspectives

    SciTech Connect

    Rogers, H.W.

    1995-12-01

    Incineration is often proposed as the treatment of choice for processing diverse wastes, particularly hazardous wastes. Where such treatment is proposed, people are often fearful that it will adversely affect their health. Unfortunately, information presented to the public about incinerators often does not include any criteria or benchmarks for evaluating such facilities. This article describes a review of air emission data from regulatory trial burns in a large prototype incinerator, operated at design capacity by the US Army to destroy chemical warfare materials. It uses several sets of criteria to gauge the threat that these emissions pose to public health. Incinerator air emission levels are evaluated with respect to various toxicity screening levels and ambient air levels of the same pollutants. Also, emission levels of chlorinated dioxins and furans are compared with emission levels of two common combustion sources. Such comparisons can add to a community`s understanding of health risks associated with an incinerator. This article focuses only on the air exposure/inhalation pathway as related to human health. It does not address other potential human exposure pathways or the possible effects of emissions on the local ecology, both of which should also be examined during a complete analysis of any major new facility.

  6. Toxic effects of air freshener emissions.

    PubMed

    Anderson, R C; Anderson, J H

    1997-01-01

    To evaluate whether emissions of a commercial air freshener produced acute toxic effects in a mammalian species, the authors allowed male Swiss-Webster mice to breathe the emissions of one commercial-brand solid air freshener for 1 h. Sensory irritation and pulmonary irritation were evaluated with the ASTM-E-981 test. A computerized version of this test measured the duration of the break at the end of inspiration and the duration of the pause at the end of expiration--two parameters subject to alteration via respiratory effects of airborne toxins. Measurements of expiratory flow velocity indicated changes in airflow limitation. The authors then subjected mice to a functional observational battery, the purpose of which was to probe for changes in nervous system function. Emissions of this air freshener at several concentrations (including concentrations to which many individuals are actually exposed) caused increases in sensory and pulmonary irritation, decreases in airflow velocity, and abnormalities of behavior measured by the functional observational battery score. The test atmosphere was subjected to gas chromatography/mass spectroscopy, and the authors noted the presence of chemicals with known irritant and neurotoxic properties. The Material Safety Data Sheet for the air freshener indicated that there was a potential for toxic effects in humans. The air freshener used in the study did not diminish the effect of other pollutants tested in combination. The results demonstrated that the air freshener may have actually exacerbated indoor air pollution via addition of toxic chemicals to the atmosphere.

  7. Biogenic organic emissions, air quality and climate

    NASA Astrophysics Data System (ADS)

    Guenther, A. B.

    2015-12-01

    Living organisms produce copious amounts of a diverse array of metabolites including many volatile organic compounds that are released into the atmosphere. These compounds participate in numerous chemical reactions that influence the atmospheric abundance of important air pollutants and short-lived climate forcers including organic aerosol, ozone and methane. The production and release of these organics are strongly influenced by environmental conditions including air pollution, temperature, solar radiation, and water availability and they are highly sensitive to stress and extreme events. As a result, releases of biogenic organics to the atmosphere have an impact on, and are sensitive to, air quality and climate leading to potential feedback couplings. Their role in linking air quality and climate is conceptually clear but an accurate quantitative representation is needed for predictive models. Progress towards this goal will be presented including numerical model development and assessments of the predictive capability of the Model of Emission of Gases and Aerosols from Nature (MEGAN). Recent studies of processes controlling the magnitude and variations in biogenic organic emissions will be described and observations of their impact on atmospheric composition will be shown. Recent advances and priorities for future research will be discussed including laboratory process studies, long-term measurements, multi-scale regional studies, global satellite observations, and the development of a next generation model for simulating land-atmosphere chemical exchange.

  8. Locating and estimating air emissions from sources of nickel

    SciTech Connect

    Not Available

    1984-03-01

    To assist groups interested in inventorying air emissions of various potentially toxic substances, EPA is preparing a series of documents such as this to compile available information on sources and emissions of these substances. This document deals specifically with nickel. Its intended audience includes Federal, State and local air pollution personnel and others interested in locating potential emitters of nickel and in making gross estimates of air emissions therefrom. This document presents information on (1) the types of sources that may emit nickel, (2) process variations and release points that may be expected within these sources, and (3) available emissions information indicating the potential for nickel release into the air from each operation.

  9. Effects of air emissions on wildlife resources. Air pollution and acid rain report No. 1

    SciTech Connect

    Newman, J.R.

    1980-05-01

    This publication describes in general the pathways of contamination, direct and indirect effects of air emissions on wildlife resources, and the potential use of wildlife as biological indicators of air quality degradation. Also included in the report are summaries of air pollution incidents involving wildlife, responses of wildlife to air pollution, major target systems of selected air pollutants, and information on the capacity of some air pollutants to accumulate in body tissues.

  10. Regional emissions of air pollutants in China.

    SciTech Connect

    Streets, D. G.

    1998-10-05

    As part of the China-MAP program, sponsored by the US National Aeronautics and Space Administration, regional inventories of air pollutants emitted in China are being characterized, in order that the atmospheric chemistry over China can be more fully understood and the resulting ambient concentrations in Chinese cities and the deposition levels to Chinese ecosystems be determined with better confidence. In addition, the contributions of greenhouse gases from China and of acidic aerosols that counteract global warming are being quantified. This paper presents preliminary estimates of the emissions of some of the major air pollutants in China: sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), carbon monoxide (CO), and black carbon (C). Emissions are estimated for each of the 27 regions of China included in the RAINS-Asia simulation model and are subsequently distributed to a 1{degree} x 1{degree} grid using appropriate disaggregation factors. Emissions from all sectors of the Chinese economy are considered, including the combustion of biofuels in rural homes. Emissions from larger power plants are calculated individually and allocated to the grid accordingly. Data for the period 1990-1995 are being developed, as well as projections for the future under alternative assumptions about economic growth and environmental control.

  11. Air Emission Inventory for the Idaho National Engineering Laboratory: 1992 emissions report

    SciTech Connect

    Stirrup, T.S.

    1993-06-01

    This report presents the 1992 Air Emission Inventory for the Idaho National Engineering Laboratory. Originally, this report was in response to the Environmental Oversight and Monitoring Agreement in 1989 between the State of Idaho and the Department of Energy Idaho Field Office, and a request from the Idaho Air Quality Bureau. The current purpose of the Air Emission Inventory is to provide the basis for the preparation of the INEL Permit-to-Operate (PTO) an Air Emission Source Application, as required by the recently promulgated Title V regulations of the Clean Air Act. This report includes emissions calculations from 1989 to 1992. The Air Emission Inventory System, an ORACLE-based database system, maintains the emissions inventory.

  12. Projection of hazardous air pollutant emissions to future years.

    PubMed

    Strum, Madeleine; Cook, Rich; Thurman, James; Ensley, Darrell; Pope, Anne; Palma, Ted; Mason, Richard; Michaels, Harvey; Shedd, Stephen

    2006-08-01

    Projecting a hazardous air pollutant (HAP) emission inventory to future years can provide valuable information for air quality management activities such as prediction of program successes and helping to assess future priorities. We have projected the 1999 National Emission Inventory for HAPs to numerous future years up to 2020 using the following tools and data: the Emissions Modeling System for Hazardous Air Pollutants (EMS-HAP), the National Mobile Inventory Model (NMIM), emission reduction information resulting from national standards and economic growth data. This paper discusses these projection tools, the underlying data, limitations and the results. The results presented include total HAP emissions (sum of pollutants) and toxicity-weighted HAP emissions for cancer and respiratory noncancer effects. Weighting emissions by toxicity does not consider fate, transport, or location and behavior of receptor populations and can only be used to estimate relative risks of direct emissions. We show these projections, along with historical emission trends. The data show that stationary source programs under Section 112 of the Clean Air Act Amendments of 1990 and mobile source programs which reduce hydrocarbon and particulate matter emissions, as well as toxic emission performance standards for reformulated gasoline, have contributed to and are expected to continue to contribute to large declines in air toxics emissions, in spite of economic and population growth. We have also analyzed the particular HAPs that dominate the source sectors to better understand the historical and future year trends and the differences across sectors.

  13. Carbon dioxide emissions from international air freight

    NASA Astrophysics Data System (ADS)

    Howitt, Oliver J. A.; Carruthers, Michael A.; Smith, Inga J.; Rodger, Craig J.

    2011-12-01

    Greenhouse gas emissions from international air transport were excluded from reduction targets under the Kyoto Protocol, partly because of difficulties with quantifying and apportioning such emissions. Although there has been a great deal of recent research into calculating emissions from aeroplane operations globally, publicly available emissions factors for air freight emissions are scarce. This paper presents a methodology to calculate the amount of fuel burnt and the resulting CO 2 emissions from New Zealand's internationally air freighted imports and exports in 2007. This methodology could be applied to other nations and/or regions. Using data on fuel uplift, air freight and air craft movements, and assumptions on mean passenger loadings and the mass of passengers and air freight, CO 2 emissions factors of 0.82 kg CO 2 per t-km and 0.69 kg CO 2 per t-km for short-haul and long-haul journeys, respectively, were calculated. The total amount of fuel consumed for the international air transport of New Zealand's imports and exports was calculated to be 0.21 Mt and 0.17 Mt respectively, with corresponding CO 2 emissions of 0.67 Mt and 0.53 Mt.

  14. 2009 LANL radionuclide air emissions report

    SciTech Connect

    Fuehne, David P.

    2010-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2009. This report meets the reporting requirements established in the regulations.

  15. 2008 LANL radionuclide air emissions report

    SciTech Connect

    Fuehne, David P.

    2009-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2008. This report meets the reporting requirements established in the regulations.

  16. 2010 LANL radionuclide air emissions report /

    SciTech Connect

    Fuehne, David P.

    2011-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2010. This report meets the reporting requirements established in the regulations.

  17. Radionuclide Air Emission Report for 2009

    SciTech Connect

    Wahl, Linnea

    2010-06-01

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the EPA radioactive air emission regulations in 40CFR61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2009, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources included more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2009 is 7.0 x 10{sup -3} mrem/yr (7.0 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.5 x 10{sup -1} person-rem (1.5 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2009.

  18. Radionuclide Air Emission Report for 2008

    SciTech Connect

    Wahl, Linnea

    2009-05-21

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2008, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources include more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2008 is 5.2 x 10{sup -3} mrem/yr (5.2 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.1 x 10{sup -1} person-rem (1.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2008.

  19. Evaluating Radionuclide Air Emission Stack Sampling Systems

    SciTech Connect

    Ballinger, Marcel Y.

    2002-12-16

    The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R&D) facilities for the U.S. Department of Energy at the Hanford Site, Washington. These facilities are subject to Clean Air Act regulations that require sampling of radionuclide air emissions from some of these facilities. A revision to an American National Standards Institute (ANSI) standard on sampling radioactive air emissions has recently been incorporated into federal and state regulations and a re-evaluation of affected facilities is being performed to determine the impact. The revised standard requires a well-mixed sampling location that must be demonstrated through tests specified in the standard. It also carries a number of maintenance requirements, including inspections and cleaning of the sampling system. Evaluations were performed in 2000 – 2002 on two PNNL facilities to determine the operational and design impacts of the new requirements. The evaluation included inspection and cleaning maintenance activities plus testing to determine if the current sampling locations meet criteria in the revised standard. Results show a wide range of complexity in inspection and cleaning activities depending on accessibility of the system, ease of removal, and potential impact on building operations (need for outages). As expected, these High Efficiency Particulate Air (HEPA)-filtered systems did not show deposition significant enough to cause concerns with blocking of the nozzle or other parts of the system. The tests for sampling system location in the revised standard also varied in complexity depending on accessibility of the sample site and use of a scale model can alleviate many issues. Previous criteria to locate sampling systems at eight duct diameters downstream and two duct diameters upstream of the nearest disturbances is no guarantee of meeting criteria in the revised standard. A computational fluid dynamics model was helpful in understanding flow and

  20. Comparison of air emissions from waste management facilities

    SciTech Connect

    Licata, A.; Minott, D.H.

    1996-09-01

    Landfilling remains the predominate disposal method for managing municipal solid waste (MSW) in the US. According to the US EPA, in 1993 landfilling accounted for 62% of the management alternative for disposing of MSW while recycling and combustion account for 22% and 15% respectively. Recent actions such as limits on flow control and EPA`s proposed Most Achievable Control Technology (MACT) rules for Municipal Waste Combustors (MWCs) most likely will increase the amount of MSW that will be landfilled. The air emissions from landfill operations have in general been ignored and unregulated. This paper will make a comparison of air emissions from a landfill (Fresh Kills Landfill in NYC) and a modern MSW. The paper will present the emissions from landfill operations including uncontrolled emissions, residual and secondary emissions from gas control systems, and emissions from diesel equipment at the landfill. The MWC emissions will include boiler pollutants and a comparison to fossil-fuel fired power plants.

  1. Groundwater treatment with zero air emissions

    SciTech Connect

    Cheuvront, D.A. ); Giggy, C.L.; Loven, C.G. ); Swett, G.H. )

    1990-08-01

    Air emissions from the treatment of volatile organic compound (VOC) - contaminated groundwater are a growing problem in the US. Historically, air stripping has been used to remove VOCs from contaminated groundwater. Air stripping technology is a cross media treatment technique, i.e., it solves a groundwater problem by transferring contamination to the atmosphere. In response to the air pollution problem created by air stripping, the public, air quality regulatory agencies, the federal government and private industry are exerting pressure to eliminate and/or reduce air emissions from the clean-up of contaminated groundwater. These forces make it desirable to consider alternative and innovative technologies for the treatment of groundwater contaminated with VOCs.

  2. HVAC SYSTEMS AS EMISSION SOURCES AFFECTING INDOOR AIR QUALITY: A CRITICAL REVIEW

    EPA Science Inventory

    The study evaluates heating, ventilating, and air-conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). Various literature sources and methods for characterizing HVAC emission sources are reviewed. Available methods include in situ test...

  3. AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

    EPA Science Inventory

    The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

  4. Results of the air emission research study

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Air quality was monitored in beef mono-slope barns. The objectives of the study were 1) to gather baseline data for the levels of gas emissions and particulate matter from beef mono-slope facilities, 2) evaluate the effect of two different manure handling systems on air quality, and 3) provide infor...

  5. Controlling air emissions from incinerators

    SciTech Connect

    Foisy, M.B.; Li, R.; Chattapadhyay, A.

    1994-04-01

    Last year, EPA published final rules establishing technical standards for the use and disposal of wastewater biosolids (40 CFR, Part 503). Subpart E specifically regulates the operations of and emissions from municipal wastewater biosolids incinerators.

  6. 2014 LANL Radionuclide Air Emissions Report

    SciTech Connect

    Fuehne, David Patrick

    2015-07-21

    This report describes the emissions of airborne radionuclides from operations at Los Alamos National Laboratory (LANL) for calendar year 2014, and the resulting off-site dose from these emissions. This document fulfills the requirements established by the National Emissions Standards for Hazardous Air Pollutants in 40 CFR 61, Subpart H – Emissions of Radionuclides other than Radon from Department of Energy Facilities, commonly referred to as the Radionuclide NESHAP or Rad-NESHAP. Compliance with this regulation and preparation of this document is the responsibility of LANL’s RadNESHAP compliance program, which is part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being submitted to the U.S. Environmental Protection Agency (EPA) Region 6.

  7. Animals as indicators of ecosystem responses to air emissions

    NASA Astrophysics Data System (ADS)

    Newman, James R.; Schreiber, R. Kent

    1984-07-01

    With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to air-borne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.

  8. Radionuclide air emissions annual report for calendar year 1994

    SciTech Connect

    Not Available

    1995-04-04

    This report presents the results of the Pinellas Plant air sampling program for the year of 1994. Topics discussed include: site description; source description; air emissions data; dose assessments; description of dose model; summary of input parameters of dose model; unplanned releases; and diffuse emissions. Included in the attachments of this document are: non-radon individual dose assessment; non-radon population dose assessment; summary of stack flow rate measurements; HOTSPOT computer model run; and meteorological data for the Pinellas Plant for 1994.

  9. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  10. Probing the radio emission from air showers with polarization measurements

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; PeÂķala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcǎu, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Pierre Auger Collaboration

    2014-03-01

    The emission of radio waves from air showers has been attributed to the so-called geomagnetic emission process. At frequencies around 50 MHz this process leads to coherent radiation which can be observed with rather simple setups. The direction of the electric field induced by this emission process depends only on the local magnetic field vector and on the incoming direction of the air shower. We report on measurements of the electric field vector where, in addition to this geomagnetic component, another component has been observed that cannot be described by the geomagnetic emission process. The data provide strong evidence that the other electric field component is polarized radially with respect to the shower axis, in agreement with predictions made by Askaryan who described radio emission from particle showers due to a negative charge excess in the front of the shower. Our results are compared to calculations which include the radiation mechanism induced by this charge-excess process.

  11. Biofuels, vehicle emissions, and urban air quality.

    PubMed

    Wallington, Timothy J; Anderson, James E; Kurtz, Eric M; Tennison, Paul J

    2016-07-18

    Increased biofuel content in automotive fuels impacts vehicle tailpipe emissions via two mechanisms: fuel chemistry and engine calibration. Fuel chemistry effects are generally well recognized, while engine calibration effects are not. It is important that investigations of the impact of biofuels on vehicle emissions consider the impact of engine calibration effects and are conducted using vehicles designed to operate using such fuels. We report the results of emission measurements from a Ford F-350 fueled with either fossil diesel or a biodiesel surrogate (butyl nonanoate) and demonstrate the critical influence of engine calibration on NOx emissions. Using the production calibration the emissions of NOx were higher with the biodiesel fuel. Using an adjusted calibration (maintaining equivalent exhaust oxygen concentration to that of the fossil diesel at the same conditions by adjusting injected fuel quantities) the emissions of NOx were unchanged, or lower, with biodiesel fuel. For ethanol, a review of the literature data addressing the impact of ethanol blend levels (E0-E85) on emissions from gasoline light-duty vehicles in the U.S. is presented. The available data suggest that emissions of NOx, non-methane hydrocarbons, particulate matter (PM), and mobile source air toxics (compounds known, or suspected, to cause serious health impacts) from modern gasoline and diesel vehicles are not adversely affected by increased biofuel content over the range for which the vehicles are designed to operate. Future increases in biofuel content when accomplished in concert with changes in engine design and calibration for new vehicles should not result in problematic increases in emissions impacting urban air quality and may in fact facilitate future required emissions reductions. A systems perspective (fuel and vehicle) is needed to fully understand, and optimize, the benefits of biofuels when blended into gasoline and diesel. PMID:27112132

  12. Biofuels, vehicle emissions, and urban air quality.

    PubMed

    Wallington, Timothy J; Anderson, James E; Kurtz, Eric M; Tennison, Paul J

    2016-07-18

    Increased biofuel content in automotive fuels impacts vehicle tailpipe emissions via two mechanisms: fuel chemistry and engine calibration. Fuel chemistry effects are generally well recognized, while engine calibration effects are not. It is important that investigations of the impact of biofuels on vehicle emissions consider the impact of engine calibration effects and are conducted using vehicles designed to operate using such fuels. We report the results of emission measurements from a Ford F-350 fueled with either fossil diesel or a biodiesel surrogate (butyl nonanoate) and demonstrate the critical influence of engine calibration on NOx emissions. Using the production calibration the emissions of NOx were higher with the biodiesel fuel. Using an adjusted calibration (maintaining equivalent exhaust oxygen concentration to that of the fossil diesel at the same conditions by adjusting injected fuel quantities) the emissions of NOx were unchanged, or lower, with biodiesel fuel. For ethanol, a review of the literature data addressing the impact of ethanol blend levels (E0-E85) on emissions from gasoline light-duty vehicles in the U.S. is presented. The available data suggest that emissions of NOx, non-methane hydrocarbons, particulate matter (PM), and mobile source air toxics (compounds known, or suspected, to cause serious health impacts) from modern gasoline and diesel vehicles are not adversely affected by increased biofuel content over the range for which the vehicles are designed to operate. Future increases in biofuel content when accomplished in concert with changes in engine design and calibration for new vehicles should not result in problematic increases in emissions impacting urban air quality and may in fact facilitate future required emissions reductions. A systems perspective (fuel and vehicle) is needed to fully understand, and optimize, the benefits of biofuels when blended into gasoline and diesel.

  13. Animals as indicators of ecosystem responses to air emissions

    SciTech Connect

    Newman, J.R.; Schreiber, R.K.

    1984-07-01

    With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to airborne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.

  14. Characterization of air freshener emission: the potential health effects.

    PubMed

    Kim, Sanghwa; Hong, Seong-Ho; Bong, Choon-Keun; Cho, Myung-Haing

    2015-01-01

    Air freshener could be one of the multiple sources that release volatile organic compounds (VOCs) into the indoor environment. The use of these products may be associated with an increase in the measured level of terpene, such as xylene and other volatile air freshener components, including aldehydes, and esters. Air freshener is usually used indoors, and thus some compounds emitted from air freshener may have potentially harmful health impacts, including sensory irritation, respiratory symptoms, and dysfunction of the lungs. The constituents of air fresheners can react with ozone to produce secondary pollutants such as formaldehyde, secondary organic aerosol (SOA), oxidative product, and ultrafine particles. These pollutants then adversely affect human health, in many ways such as damage to the central nervous system, alteration of hormone levels, etc. In particular, the ultrafine particles may induce severe adverse effects on diverse organs, including the pulmonary and cardiovascular systems. Although the indoor use of air freshener is increasing, deleterious effects do not manifest for many years, making it difficult to identify air freshener-associated symptoms. In addition, risk assessment recognizes the association between air fresheners and adverse health effects, but the distinct causal relationship remains unclear. In this review, the emitted components of air freshener, including benzene, phthalate, and limonene, were described. Moreover, we focused on the health effects of these chemicals and secondary pollutants formed by the reaction with ozone. In conclusion, scientific guidelines on emission and exposure as well as risk characterization of air freshener need to be established. PMID:26354370

  15. Working Toward Policy-Relevant Air Quality Emissions Scenarios

    NASA Astrophysics Data System (ADS)

    Holloway, T.

    2010-12-01

    Though much work has been done to develop accurate chemical emission inventories, few publicly available inventories are appropriate for realistic policy analysis. Emissions from the electricity and transportation sectors, in particular, respond in complex ways to policy, technology, and energy use change. Many widely used inventories, such as the EPA National Emissions Inventory, are well-suited for modeling current air quality, but do not have the specificity needed to address "what if?" questions. Changes in electricity demand, fuel prices, new power sources, and emission controls all influence the emissions from regional power production, requiring a plant-by-plant assessment to capture the spatially explicit impacts. Similarly, land use, freight distribution, or driving behavior will yield differentiated transportation emissions for urban areas, suburbs, and rural highways. We here present results from three recent research projects at the University of Wisconsin—Madison, where bottom-up emission inventories for electricity, freight transport, and urban vehicle use were constructed to support policy-relevant air quality research. These three studies include: 1) Using the MyPower electricity dispatch model to calculate emissions and air quality impacts of Renewable Portfolio Standards and other carbon-management strategies; 2) Using advanced vehicle and commodity flow data from the Federal Highway Administration to evaluate the potential to shift commodities from truck to rail (assuming expanded infrastructure), and assess a range of alternative fuel suggestions; and 3) Working with urban planners to connect urban density with vehicle use to evaluate the air quality impacts of smart-growth in major Midwest cities. Drawing on the results of these three studies, and on challenges overcome in their execution, we discuss the current state of policy-relevant emission dataset generation, as well as techniques and attributes that need to be further refined in order

  16. The 1977 emissions inventory for southeastern Virginia. [environment model of air quality based on exhaust emission from urban areas

    NASA Technical Reports Server (NTRS)

    Brewer, D. A.; Remsberg, E. E.; Woodbury, G. E.; Quinn, L. C.

    1979-01-01

    Regional tropospheric air pollution modeling and data compilation to simulate the time variation of species concentrations in and around an urban area is discussed. The methods used to compile an emissions inventory are outlined. Emissions factors for vehicular travel in the urban area are presented along with an analysis of the emission gases. Emission sources other than vehicular including industrial wastes, residential solid waste disposal, aircraft emissions, and emissions from the railroads are investigated.

  17. U.S. DOE 2004 LANL Radionuclide Air Emissions

    SciTech Connect

    K.W. Jacobson

    2005-08-12

    Amendments to the Clean Air Act, which added radionuclides to the National Emissions Standards for Hazardous Air Pollutants (NESHAP), went into effect in 1990. Specifically, a subpart (H) of 40 CFR 61 established an annual limit on the impact to the public attributable to emissions of radionuclides from U.S. Department of Energy facilities, such as the Los Alamos National Laboratory (LANL). As part of the new NESHAP regulations, LANL must submit an annual report to the U.S. Environmental Protection Agency headquarters and the regional office in Dallas by June 30. This report includes results of monitoring at LANL and the dose calculations for the calendar year 2004.

  18. 40 CFR 60.37b - Emission guidelines for air curtain incinerators.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... incinerators. 60.37b Section 60.37b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... § 60.37b Emission guidelines for air curtain incinerators. For approval, a State plan shall include emission limits for opacity for air curtain incinerators at least as protective as those listed in §...

  19. 40 CFR 60.37b - Emission guidelines for air curtain incinerators.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... incinerators. 60.37b Section 60.37b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... § 60.37b Emission guidelines for air curtain incinerators. For approval, a State plan shall include emission limits for opacity for air curtain incinerators at least as protective as those listed in §...

  20. 40 CFR 60.37b - Emission guidelines for air curtain incinerators.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... incinerators. 60.37b Section 60.37b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... § 60.37b Emission guidelines for air curtain incinerators. For approval, a State plan shall include emission limits for opacity for air curtain incinerators at least as protective as those listed in §...

  1. 40 CFR 60.37b - Emission guidelines for air curtain incinerators.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... incinerators. 60.37b Section 60.37b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... § 60.37b Emission guidelines for air curtain incinerators. For approval, a State plan shall include emission limits for opacity for air curtain incinerators at least as protective as those listed in §...

  2. 40 CFR 60.37b - Emission guidelines for air curtain incinerators.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... incinerators. 60.37b Section 60.37b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... § 60.37b Emission guidelines for air curtain incinerators. For approval, a State plan shall include emission limits for opacity for air curtain incinerators at least as protective as those listed in §...

  3. 2006 LANL Radionuclide Air Emissions Report

    SciTech Connect

    David P. Fuehne

    2007-06-30

    This report describes the impacts from emissions of radionuclides at Los Alamos National Laboratory (LANL) for calendar year 2006. This report fulfills the requirements established by the Radionuclide National Emissions Standards for Hazardous Air Pollutants (Rad-NESHAP). This report is prepared by LANL's Rad-NESHAP compliance team, part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being reported to the U.S. Environmental Protection Agency (EPA). The highest effective dose equivalent (EDE) to an off-site member of the public was calculated using procedures specified by the EPA and described in this report. LANL's EDE was 0.47 mrem for 2006. The annual limit established by the EPA is 10 mrem per year. During calendar year 2006, LANL continuously monitored radionuclide emissions at 28 release points, or stacks. The Laboratory estimates emissions from an additional 58 release points using radionuclide usage source terms. Also, LANL uses a network of air samplers around the Laboratory perimeter to monitor ambient airborne levels of radionuclides. To provide data for dispersion modeling and dose assessment, LANL maintains and operates meteorological monitoring systems. From these measurement systems, a comprehensive evaluation is conducted to calculate the EDE for the Laboratory. The EDE is evaluated as any member of the public at any off-site location where there is a residence, school, business, or office. In 2006, this location was the Los Alamos Airport Terminal. The majority of this dose is due to ambient air sampling of plutonium emitted from 2006 clean-up activities at an environmental restoration site (73-002-99; ash pile). Doses reported to the EPA for the past 10 years are shown in Table E1.

  4. Sequim Site Radionuclide Air Emissions Report for Calendar Year 2012

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew; Gervais, Todd L.

    2013-04-01

    This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and ashington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. This report meets the calendar year 2012 Sequim Site annual reporting requirement for its operations as a privately-owned facility as well as its federally-contracted status that began in October 2012. Compliance is indicated by comparing the estimated dose to the maximally exposed individual (MEI) with the 10 mrem/yr Environmental Protection Agency (EPA) standard. The MSL contains only sources classified as fugitive emissions. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The dose to the Sequim Site MEI due to routine operations in 2012 was 9E-06 mrem (9E-08 mSv). No non-routine emissions occurred in 2012. The MSL is in compliance with the federal and state 10 mrem/yr standard.

  5. Radionuclide Air Emission Report for 2007

    SciTech Connect

    Wahl, Linnea; Wahl, Linnea

    2008-06-13

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). The EPA regulates radionuclide emissions that may be released from stacks or vents on buildings where radionuclide production or use is authorized or that may be emitted as diffuse sources. In 2007, all Berkeley Lab sources were minor stack or building emissions sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]), there were no diffuse emissions, and there were no unplanned emissions. Emissions from minor sources either were measured by sampling or monitoring or were calculated based on quantities received for use or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, Version 3.0, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2007 is 1.2 x 10{sup -2} mrem/yr (1.2 x 10{sup -4} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) EPA dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 3.1 x 10{sup -1} person-rem (3.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2007.

  6. AIR EMISSION INVENTORIES IN NORTH AMERICA: A CRITICAL ASSESSMENT

    EPA Science Inventory

    Although emission inventories are the foundation of air quality management and have supported substantial improvements in North American air quality, they have a number of shortcomings that can potentially lead to ineffective air quality management strategies. New technologies fo...

  7. Quantifying Uncontrolled Air Emissions from Two Florida Landfills

    EPA Science Inventory

    Landfill gas emissions, if left uncontrolled, contribute to air toxics, climate change, trospospheric ozone, and urban smog. Measuring emissions from landfills presents unique challenges due to the large and variable source area, spatial and temporal variability of emissions, and...

  8. OFFICE EQUIPMENT: DESIGN, INDOOR AIR EMISSIONS, AND POLLUTION PREVENTION OPPORTUNITIES

    EPA Science Inventory

    The report summarizes available information on office equipment design; indoor air emissions of organics, ozone, and particulates from office equipment; and pollution prevention approaches for reducing these emissions. Since much of the existing emissions data from office equipme...

  9. Hydrogen/Air Fuel Nozzle Emissions Experiments

    NASA Technical Reports Server (NTRS)

    Smith, Timothy D.

    2001-01-01

    The use of hydrogen combustion for aircraft gas turbine engines provides significant opportunities to reduce harmful exhaust emissions. Hydrogen has many advantages (no CO2 production, high reaction rates, high heating value, and future availability), along with some disadvantages (high current cost of production and storage, high volume per BTU, and an unknown safety profile when in wide use). One of the primary reasons for switching to hydrogen is the elimination of CO2 emissions. Also, with hydrogen, design challenges such as fuel coking in the fuel nozzle and particulate emissions are no longer an issue. However, because it takes place at high temperatures, hydrogen-air combustion can still produce significant levels of NOx emissions. Much of the current research into conventional hydrocarbon-fueled aircraft gas turbine combustors is focused on NOx reduction methods. The Zero CO2 Emission Technology (ZCET) hydrogen combustion project will focus on meeting the Office of Aerospace Technology goal 2 within pillar one for Global Civil Aviation reducing the emissions of future aircraft by a factor of 3 within 10 years and by a factor of 5 within 25 years. Recent advances in hydrocarbon-based gas turbine combustion components have expanded the horizons for fuel nozzle development. Both new fluid designs and manufacturing technologies have led to the development of fuel nozzles that significantly reduce aircraft emissions. The goal of the ZCET program is to mesh the current technology of Lean Direct Injection and rocket injectors to provide quick mixing, low emissions, and high-performance fuel nozzle designs. An experimental program is planned to investigate the fuel nozzle concepts in a flametube test rig. Currently, a hydrogen system is being installed in cell 23 at NASA Glenn Research Center's Research Combustion Laboratory. Testing will be conducted on a variety of fuel nozzle concepts up to combustion pressures of 350 psia and inlet air temperatures of 1200 F

  10. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1998 Emissions Report

    SciTech Connect

    S. K. Zohner

    1999-10-01

    This report presents the 1998 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradiological emissions estimates for stationary sources.

  11. Air emission inventory for the Idaho National Engineering Laboratory: 1994 emissions report

    SciTech Connect

    1995-07-01

    This report Presents the 1994 update of the Air Emission inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources.

  12. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1999 Emission Report

    SciTech Connect

    Zohner, S.K.

    2000-05-30

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  13. Air toxic emissions from snowmobiles in Yellowstone National Park.

    PubMed

    Zhou, Yong; Shively, David; Mao, Huiting; Russo, Rachel S; Pape, Bruce; Mower, Richard N; Talbot, Robert; Sive, Barkley C

    2010-01-01

    A study on emissions associated with oversnow travel in Yellowstone National Park (YNP) was conducted for the time period of February 13-16, 2002 and February 12-16, 2003. Whole air and exhaust samples were characterized for 85 volatile organic compounds using gas chromatography. The toxics including benzene, toluene, ethylbenzene, xylenes (p-, m-, and o-xylene), and n-hexane, which are major components of two-stroke engine exhaust, show large enhancements during sampling periods resulting from increased snowmobile traffic. Evaluation of the photochemical history of air masses sampled in YNP revealed that emissions of these air toxics were (i) recent, (ii) persistent throughout the region, and (iii) consistent with the two-stroke engine exhaust sample fingerprints. The annual fluxes were estimated to be 0.35, 1.12, 0.24, 1.45, and 0.36 Gg yr(-1) for benzene, toluene, ethylbenzene, xylenes, and n-hexane, respectively, from snowmobile usage in YNP. These results are comparable to the flux estimates of 0.23, 0.77, 0.17, and 0.70 Gg yr(-1) for benzene, toluene, ethylbenzene, and xylenes, respectively, that were derived on the basis of (i) actual snowmobile counts in the Park and (ii) our ambient measurements conducted in 2003. Extrapolating these results, annual emissions from snowmobiles in the U.S. appear to be significantly higher than the values from the EPA National Emissions Inventory (1999). Snowmobile emissions represent a significant fraction ( approximately 14-21%) of air toxics with respect to EPA estimates of emissions by nonroad vehicles. Further investigation is warranted to more rigorously quantify the difference between our estimates and emission inventories.

  14. Radioactive air emissions notice of construction portable temporary radioactive air emission units - August 1998

    SciTech Connect

    FRITZ, D.W.

    1999-07-22

    This notice of construction (NOC) requests a categorical approval for construction and operation of three types of portable/temporary radionuclide airborne emission units (PTRAEUs). These three types are portable ventilation-filter systems (Type I), mobile sample preparation facilities (Type II), and mobile sample screening and analysis facilities (Type 111). Approval of the NOC application is intended to allow construction and operation of the three types of PTRAEUs without prior project-specific approval. Environmental cleanup efforts on the Hanford Site often require the use of PTRAEUs. The PTRAEUs support site characterization activities, expedited response actions (ERAs), sampling and monitoring activities, and other routine activities. The PTRAEUs operate at various locations around the Hanford Site. Radiation Air Emissions Program, Washington Administrative Code (WAC) 246-247, requires that the Washington State Department of Health (WDOH) be notified before construction of any new emission that would release airborne radioactivity. The WDOH also must receive notification before any modification of an existing source. This includes changes in the source term or replacement of emission control equipment that might significantly contribute to the offsite maximum dose from a licensed facility. During site characterization activities, ERAs, sampling and monitoring activities, and other routine activities, the PTRAEUs might require startup immediately. The notification period hampers efforts to complete such activities in an effective and timely manner. Additionally, notification is to be submitted to the WDOH when the PTRAEUs are turned off. The U.S. Department of Energy, Richland Operations Office (DOE-RL) potentially could generate several notifications monthly. The WDOH would be required to review and provide approval on each NOC as well as review the notices of discontinued sources. The WDOH regulation also allows facilities the opportunity to request a

  15. Surveys of Microwave Emission from Air Showers

    NASA Astrophysics Data System (ADS)

    Kuramoto, Kazuyuki; Ogio, Shoichi; Iijima, Takashi; Yamamoto, Tokonatsu

    2011-09-01

    A possibility of detection of microwave molecular bremsstrahlung radiation from Extensive Air Showers was reported by AMBER group [1] [2]. This method has a potential to provide a high duty cycle and a new technique for measuring longitudinal profile of EAS. To survey this microwave emission from EAS, we built prototype detectors using parabolic antenna dishes for broadcasting satellites, and we are operating detectors with a small EAS array at Osaka City Univercity. Here, we report our detector configurations and the current experimental status.

  16. 40 CFR 1065.667 - Dilution air background emission correction.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Dilution air background...

  17. 40 CFR 1065.667 - Dilution air background emission correction.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Dilution air background...

  18. 40 CFR 1065.667 - Dilution air background emission correction.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Dilution air background...

  19. 40 CFR 1065.667 - Dilution air background emission correction.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Dilution air background...

  20. 40 CFR 1065.667 - Dilution air background emission correction.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Dilution air background...

  1. Emission of pesticides into the air

    USGS Publications Warehouse

    Van Den, Berg; Kubiak, R.; Benjey, W.G.; Majewski, M.S.; Yates, S.R.; Reeves, G.L.; Smelt, J.H.; Van Der Linden, A. M. A.

    1999-01-01

    During and after the application of a pesticide in agriculture, a substantial fraction of the dosage may enter the atmosphere and be transported over varying distances downwind of the target. The rate and extent of the emission during application, predominantly as spray particle drift, depends primarily on the application method (equipment and technique), the formulation and environmental conditions, whereas the emission after application depends primarily on the properties of the pesticide, soils, crops and environmental conditions. The fraction of the dosage that misses the target area may be high in some cases and more experimental data on this loss term are needed for various application types and weather conditions. Such data are necessary to test spray drift models, and for further model development and verification as well. Following application, the emission of soil fumigants and soil incorporated pesticides into the air can be measured and computed with reasonable accuracy, but further model development is needed to improve the reliability of the model predictions. For soil surface applied pesticides reliable measurement methods are available, but there is not yet a reliable model. Further model development is required which must be verified by field experiments. Few data are available on pesticide volatilization from plants and more field experiments are also needed to study the fate processes on the plants. Once this information is available, a model needs to be developed to predict the volatilization of pesticides from plants, which, again, should be verified with field measurements. For regional emission estimates, a link between data on the temporal and spatial pesticide use and a geographical information system for crops and soils with their characteristics is needed.

  2. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type.

    PubMed

    England, G C; McGrath, T P; Gilmer, L; Seebold, J G; Lev-On, M; Hunt, T

    2001-01-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NOx emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. PMID:11219701

  3. Improved Estimates of Air Pollutant Emissions from Biorefinery

    SciTech Connect

    Tan, Eric C. D.

    2015-11-13

    We have attempted to use detailed kinetic modeling approach for improved estimation of combustion air pollutant emissions from biorefinery. We have developed a preliminary detailed reaction mechanism for biomass combustion. Lignin is the only biomass component included in the current mechanism and methane is used as the biogas surrogate. The model is capable of predicting the combustion emissions of greenhouse gases (CO2, N2O, CH4) and criteria air pollutants (NO, NO2, CO). The results are yet to be compared with the experimental data. The current model is still in its early stages of development. Given the acknowledged complexity of biomass oxidation, as well as the components in the feed to the combustor, obviously the modeling approach and the chemistry set discussed here may undergo revision, extension, and further validation in the future.

  4. Modeling of Radio Emission from Saturn's Rings Including Wakes

    NASA Astrophysics Data System (ADS)

    Molnar, L. A.; Dunn, D. E.; Cully, J. C.; Young, D. J.

    2000-10-01

    We have extended the ``simrings" radiative transfer software package (Dunn, Molnar, and Fix 1999) to include idealized ring wakes. The package consists four principle, modular components: ``simprob," which computes Mie scattering functions for individual particles specified by size and composition; ``simrings," which uses a Monte Carlo simulation to compute the complete scattering function and thermal emission of a ring slab specified by particle size distribution and density (including the possibility of wake density enhancements); ``simplot," which uses these functions along with geometric information and a full description of the planet brightness to compute the ring brightness as a function of azimuth as viewed from Earth; and "simcoord", which combines this information for a series of rings to make a final model of the radio emission as viewed on the sky. We compare sample results from this package with those of a simple, analytic model that ignores multiple scattering. This allows us to show qualitatively under what conditions one might observe east-west asymmetry in the rings caused by multiple scattering off wakes (as we earlier suggested may be the case: Dunn, Molnar, and Fix 1996), and to quantitatively compare models with data maps. The principle advantage of our idealized wakes is the relative ease with which we can consider a wide range of parameter space. The utility of this depends on these wakes having net scattering properties resembling those of more realistic wakes. We compare our idealized wakes with the gravitational simulations of Daisaka and Ida (1999) and find that this is the case for directly transmitted flux as a function of azimuth and inclination. As complete scattering properties of realistic simulations become available, we can use them as alternative inputs to ``simplot," producing model radio maps for them. Finally, we compare preliminary runs of the ``simrings" package with radio data spanning a range of observing wavelengths and

  5. [Study on feasible emission control level of air pollutions for cement industry ].

    PubMed

    Ren, Chun; Jiang, Mei; Zou, Lan; Li, Xiao-qian; Wei, Yu-xia; Zhao, Guo-hua; Zhang, Guo-ning

    2014-09-01

    The revised National Emission Standard of Air Pollutions for Cement Industry has been issued, which will be effective for the new enterprises and the existing enterprises on Mar. 1st, 2014 and July 1st, 2015, respectively. In the process of revision, the key technical issues on determination of standard limits was how to determine the feasible emission control level of air pollutions. Feasible emission control requirements were put forward, according to air pollutants emission, technologies, environmental management requirements and foreign standards, etc. The main contents of the revised standard include expanding the scope of application, increasing the pollutants, improving the particulate and NO emissions control level, and increasing special emission limits applied to key areas of air pollutants. The standard will become the gripper of pollution prevention, total emission reduction, structural adjustment and optimization of the layout, and will promote scientific and technical progression for the cement industry.

  6. Recent Developments in the Quantification and Regulation of Air Emissions from Animal Feeding Operations.

    PubMed

    Heinzen, Tarah

    2015-03-01

    Animal feeding operations (AFOs) emit various air pollutants, including ammonia, hydrogen sulfide, particulate matter, volatile organic compounds, methane, and nitrous oxide. Several of these pollutants are regulated under federal clean air statutes, yet AFOs have largely escaped regulation under these laws because of challenges in accurately estimating the rate and quantity of emissions from various types of livestock operations. Recent Environmental Protection Agency (EPA) efforts to collect emissions data, develop an emissions model capable of estimating emissions at AFOs nationwide, and establish emissions estimating methodologies for certain key livestock air pollutants suffered from design flaws and omitted pollutants of concern. Moreover, this process seems to have stalled, delaying other regulatory reforms needed to increase transparency and increase regulation of these facilities. Until EPA establishes these methodologies, significant AFO pollution regulation under the Clean Air Act or emissions reporting statutes will be very difficult to achieve, and the public health and environmental impacts of these emissions will continue unabated. PMID:26231239

  7. Recent Developments in the Quantification and Regulation of Air Emissions from Animal Feeding Operations.

    PubMed

    Heinzen, Tarah

    2015-03-01

    Animal feeding operations (AFOs) emit various air pollutants, including ammonia, hydrogen sulfide, particulate matter, volatile organic compounds, methane, and nitrous oxide. Several of these pollutants are regulated under federal clean air statutes, yet AFOs have largely escaped regulation under these laws because of challenges in accurately estimating the rate and quantity of emissions from various types of livestock operations. Recent Environmental Protection Agency (EPA) efforts to collect emissions data, develop an emissions model capable of estimating emissions at AFOs nationwide, and establish emissions estimating methodologies for certain key livestock air pollutants suffered from design flaws and omitted pollutants of concern. Moreover, this process seems to have stalled, delaying other regulatory reforms needed to increase transparency and increase regulation of these facilities. Until EPA establishes these methodologies, significant AFO pollution regulation under the Clean Air Act or emissions reporting statutes will be very difficult to achieve, and the public health and environmental impacts of these emissions will continue unabated.

  8. Air Emission Inventory for the Idaho National Engineering Laboratory, 1993 emissions report

    SciTech Connect

    Not Available

    1994-06-01

    This report presents the 1993 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The purpose of the Air Emission Inventory is to commence the preparation of the permit to operate application for the INEL, as required by the recently promulgated Title V regulations of the Clean Air Act. The report describes the emission inventory process and all of the sources at the INEL and provides emissions estimates for both mobile and stationary sources.

  9. Air emissions assessment and air quality permitting for a municipal waste landfill treating municipal sewage sludge

    SciTech Connect

    Koehler, J.

    1998-12-31

    This paper presents a case study into the air quality permitting of a municipal solid waste (MSW) landfill in the San Francisco Bay Area undergoing a proposed expansion in operations to increase the life of the landfill. The operations of this facility include MSW landfilling, the treatment and disposal of municipal sewage sludge, the aeration of petroleum-contaminated soils, the construction of a new on-site plant to manufacture soil amendment products from waste wood and other organic material diverted from the landfill, and the installation of a vaporator to create steam from leachate for injection into the landfill gas flare. The emissions assessment for each project component relied upon interpretation of source tests from similar operations, incorporation of on-site measurements into emissions models and mass balances, and use of AP-42 procedures for emissions sources such as wind-blown dust, material handling and transfer operations, and fugitive landfill gas. Air permitting issues included best available control technology (BACT), emission offset thresholds, new source performance standards (NSPS), potential air toxics health risk impacts, and compliance with federal Title V operating permit requirements. With the increasing difficulties of siting new landfills, increasing pressures to reduce the rate of waste placement into existing landfills, and expanding regulatory requirements on landfill operations, experiences similar to those described in this paper are likely to increase in the future as permitting scenarios become more complex.

  10. 75 FR 43114 - Approval and Promulgation of Air Quality Implementation Plans; Texas; Revisions to Emissions...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-07-23

    ..., 1999 and February 26, 2007. The revisions pertain to regulations on reporting air pollution emissions (emission inventories), and conformity of general Federal actions to SIPs. EPA is proposing to approve the... Emissions Inventory Reporting Requirements and Conformity of General Federal Actions, Including...

  11. Energy and air emission effects of water supply.

    PubMed

    Stokes, Jennifer R; Horvath, Arpad

    2009-04-15

    Life-cycle air emission effects of supplying water are explored using a hybrid life-cycle assessment For the typically sized U.S. utility analyzed, recycled water is preferable to desalination and comparable to importation. Seawater desalination has an energy and air emission footprint that is 1.5-2.4 times larger than that of imported water. However, some desalination modes fare better; brackish groundwater is 53-66% as environmentally intensive as seawater desalination. The annual water needs (326 m3) of a typical Californian that is met with imported water requires 5.8 GJ of energy and creates 360 kg of CO2 equivalent emissions. With seawater desalination, energy use would increase to 14 GJ and 800 kg of CO2 equivalent emissions. Meeting the water demand of California with desalination would consume 52% of the state's electricity. Supply options were reassessed using alternative electricity mixes, including the average mix of the United States and several renewable sources. Desalination using solar thermal energy has lower greenhouse gas emissions than that of imported and recycled water (using California's electricity mix), but using the U.S. mix increases the environmental footprint by 1.5 times. A comparison with a more energy-intensive international scenario shows that CO2 equivalent emissions for desalination in Dubai are 1.6 times larger than in California. The methods, decision support tool (WEST), and results of this study should persuade decision makers to make informed water policy choices by including energy consumption and material use effects in the decision-making process.

  12. Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) Model-I: building an emissions data base

    NASA Astrophysics Data System (ADS)

    Smith, S. N.; Mueller, S. F.

    2010-05-01

    A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates non-methane volatile organic compound (NMVOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, windblown dust particulate, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (NMVOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere

  13. Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) model - Part 1: Building an emissions data base

    NASA Astrophysics Data System (ADS)

    Smith, S. N.; Mueller, S. F.

    2010-01-01

    A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates volatile organic compound (VOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as windblown dust and sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (VOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere. The seasonality and

  14. 40 CFR 264.179 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall...

  15. 40 CFR 264.232 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all...

  16. 40 CFR 265.178 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner...

  17. 40 CFR 265.231 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator...

  18. 40 CFR 265.178 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner...

  19. 40 CFR 264.200 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous...

  20. 40 CFR 264.179 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall...

  1. 40 CFR 264.200 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous...

  2. 40 CFR 264.179 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall...

  3. 40 CFR 265.202 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage...

  4. 40 CFR 265.178 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner...

  5. 40 CFR 264.232 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all...

  6. 40 CFR 265.231 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator...

  7. 40 CFR 264.200 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous...

  8. 40 CFR 265.202 - Air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage...

  9. 40 CFR 264.232 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all...

  10. 40 CFR 265.231 - Air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator...

  11. 40 CFR 265.202 - Air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage...

  12. 40 CFR 265.178 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.178 Section 265.178 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Use and Management of Containers § 265.178 Air emission standards. The owner...

  13. 40 CFR 264.232 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.232 Section 264.232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Surface Impoundments § 264.232 Air emission standards. The owner or operator shall manage all...

  14. 40 CFR 265.231 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.231 Section 265.231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Surface Impoundments § 265.231 Air emission standards. The owner or operator...

  15. 40 CFR 264.200 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.200 Section 264.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Tank Systems § 264.200 Air emission standards. The owner or operator shall manage all hazardous...

  16. 40 CFR 264.179 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 264.179 Section 264.179 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Use and Management of Containers § 264.179 Air emission standards. The owner or operator shall...

  17. 40 CFR 265.202 - Air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Air emission standards. 265.202 Section 265.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... DISPOSAL FACILITIES Tank Systems § 265.202 Air emission standards. The owner or operator shall manage...

  18. Radioactive air emissions notice of construction HEPA filtered vacuum radioactive air emission units

    SciTech Connect

    JOHNSON, R.E.

    1999-09-01

    This notice of construction (NOC) requests a categorical approval for construction and operation of certain portable high-efficiency particulate air (HEPA) filtered vacuum radionuclide airborne emission units (HVUs). Approval of this NOC application is intended to allow operation of the HVUs without prior project-specific approval. This NOC does not request replacement or supersedence of any previous agreements/approvals by the Washington State Department of Health for the use of vacuums on the Hanford Site. These previous agreement/approvals include the approved NOCs for the use of EuroClean HEPA vacuums at the T Plant Complex (routine technical meeting 12/10/96) and the Kelly Decontamination System at the Plutonium-Uranium Extraction (PUREX) Plant (routine technical meeting 06/25/96). Also, this NOC does not replace or supersede the agreement reached regarding the use of HEPA hand-held/shop-vacuum cleaners for routine cleanup activities conducted by the Environmental Restoration Project. Routine cleanup activities are conducted during the surveillance and maintenance of inactive waste sites (Radioactive Area Remedial Action Project) and inactive facilities. HEPA hand-held/shop-vacuum cleaners are used to clean up spot surface contamination areas found during outdoor radiological field surveys, and to clean up localized radiologically contaminated material (e.g., dust, dirt, bird droppings, animal feces, liquids, insects, spider webs, etc.). This agreement, documented in the October 12, 1994 Routine Meeting Minutes, is based on routine cleanup consisting of spot cleanup of low-level contamination provided that, in each case, the source term potential would be below 0.1 millirem per year.

  19. Radio Emission in Atmospheric Air Showers Measured by LOPES-30

    SciTech Connect

    Isar, P. G.

    2008-01-24

    When Ultra High Energy Cosmic Rays (UHECR) interact with particles in the Earth's atmosphere, they produce a shower of secondary particles propagating towards the ground. These relativistic particles emit synchrotron radiation in the radio frequency range when passing the Earth's magnetic field. The LOPES (LOFAR Prototype Station) experiment investigates the radio emission from these showers in detail and will pave the way to use this detection technique for large scale applications like in LOFAR (Low Frequency Array) and the Pierre Auger Observatory. The LOPES experiment is co-located and measures in coincidence with the air shower experiment KASCADE-Grande at Forschungszentrum Karlsruhe, Germany. LOPES has an absolute amplitude calibration array of 30 dipole antennas (LOPES-30). After one year of measurements of the single East-West polarization by all 30 antennas, recently, the LOPES-30 set-up was configured to perform dual-polarization measurements. Half of the antennas have been configured for measurements of the North-South polarization. Only by measuring at the same time both, the E-W and N-S polarization components of the radio emission, the geo-synchrotron effect as the dominant emission mechanism in air showers can be verified. The status of the measurements, including the absolute calibration procedure of the dual-polarized antennas as well as analysis of dual-polarized event examples are reported.

  20. Volcanic gas emissions and their effect on ambient air character

    SciTech Connect

    Sutton, A.J.; Elias, T.

    1994-01-01

    This bibliography was assembled to service an agreement between Department of Energy and the USGS to provide a body of references and useful annotations for understanding background gas emissions from Kilauea volcano. The current East Rift Zone (ERZ) eruption of Kilauea releases as much as 500,000 metric tonnes of SO{sub 2} annually, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl, and HF. Primary degassing locations on Kilauea are located in the summit caldera and along the middle ERZ. The effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Because of this complexity, we organized the bibliography into three main sections: (1) characterizing gases as they leave the edifice; (2) characterizing gases and chemical reaction products away from degassing sources; and (3) Hawaii Island meteorology.

  1. Examining air pollution in China using production- and consumption-based emissions accounting approaches.

    PubMed

    Huo, Hong; Zhang, Qiang; Guan, Dabo; Su, Xin; Zhao, Hongyan; He, Kebin

    2014-12-16

    Two important reasons for China's air pollution are the high emission factors (emission per unit of product) of pollution sources and the high emission intensity (emissions per unit of GDP) of the industrial structure. Therefore, a wide variety of policy measures, including both emission abatement technologies and economic adjustment, must be implemented. To support such measures, this study used the production- and consumption-based emissions accounting approaches to simulate the SO2, NOx, PM2.5, and VOC emissions flows among producers and consumers. This study analyzed the emissions and GDP performance of 36 production sectors. The results showed that the equipment, machinery, and devices manufacturing and construction sectors contributed more than 50% of air pollutant emissions, and most of their products were used for capital formation and export. The service sector had the lowest emission intensities, and its output was mainly consumed by households and the government. In China, the emission intensities of production activities triggered by capital formation and export were approximately twice that of the service sector triggered by final consumption expenditure. This study suggests that China should control air pollution using the following strategies: applying end-of-pipe abatement technologies and using cleaner fuels to further decrease the emission factors associated with rural cooking, electricity generation, and the transportation sector; continuing to limit highly emission-intensive but low value-added exports; developing a plan to reduce construction activities; and increasing the proportion of service GDP in the national economy.

  2. Emission estimates for air pollution transport models.

    SciTech Connect

    Streets, D. G.

    1998-10-09

    The results of studies of energy consumption and emission inventories in Asia are discussed. These data primarily reflect emissions from fuel combustion (both biofuels and fossil fuels) and were collected to determine emissions of acid-deposition precursors (SO{sub 2} and NO{sub x}) and greenhouse gases (CO{sub 2} CO, CH{sub 4}, and NMHC) appropriate to RAINS-Asia regions. Current work is focusing on black carbon (soot), volatile organic compounds, and ammonia.

  3. Quantifying the air pollutants emission reduction during the 2008 Olympic games in Beijing.

    PubMed

    Wang, Shuxiao; Zhao, Meng; Xing, Jia; Wu, Ye; Zhou, Yu; Lei, Yu; He, Kebin; Fu, Lixin; Hao, Jiming

    2010-04-01

    Air quality was a vital concern for the Beijing Olympic Games in 2008. To strictly control air pollutant emissions and ensure good air quality for the Games, Beijing municipal government announced an "Air Quality Guarantee Plan for the 29th Olympics in Beijing". In order to evaluate the effectiveness of the guarantee plan, this study analyzed the air pollutant emission reductions during the 29th Olympiad in Beijing. In June 2008, daily emissions of SO(2), NO(X), PM(10), and NMVOC in Beijing were 103.9 t, 428.5 t, 362.7 t, and 890.0 t, respectively. During the Olympic Games, the daily emissions of SO(2), NO(X), PM(10), and NMVOC in Beijing were reduced to 61.6 t, 229.1 t, 164.3 t, and 381.8 t -41%, 47%, 55%, and 57% lower than June 2008 emission levels. Closing facilities producing construction materials reduced the sector's SO(2) emissions by 85%. Emission control measures for mobile sources, including high-emitting vehicle restrictions, government vehicle use controls, and alternate day driving rules for Beijing's 3.3 million private cars, reduced mobile source NO(X) and NMVOC by 46% and 57%, respectively. Prohibitions on building construction reduced the sector's PM(10) emissions by approximately 90% or total PM(10) by 35%. NMVOC reductions came mainly from mobile source and fugitive emission reductions. Based on the emission inventories developed in this study, the CMAQ model was used to simulate Beijing's ambient air quality during the Olympic Games. The model results accurately reflect the environmental monitoring data providing evidence that the emission inventories in this study are reasonably accurate and quantitatively reflect the emission changes attributable to air pollution control measures taken during the 29th Olympic Games in 2008. PMID:20222727

  4. SEMINAR PUBLICATION: ORGANIC AIR EMISSIONS FROM WASTE MANAGEMENT FACILITIES

    EPA Science Inventory

    The organic chemicals contained in wastes processed during waste management operations can volatilize into the atmosphere and cause toxic or carcinogenic effects or contribute to ozone formation. Because air emissions from waste management operations pose a threat to human health...

  5. Pacific Northwest National Laboratory Potential Impact Categories for Radiological Air Emission Monitoring

    SciTech Connect

    Ballinger, Marcel Y.; Gervais, Todd L.; Barnett, J. Matthew

    2012-06-05

    In 2002, the EPA amended 40 CFR 61 Subpart H and 40 CFR 61 Appendix B Method 114 to include requirements from ANSI/HPS N13.1-1999 Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities for major emission points. Additionally, the WDOH amended the Washington Administrative Code (WAC) 246-247 Radiation protection-air emissions to include ANSI/HPS N13.1-1999 requirements for major and minor emission points when new permitting actions are approved. A result of the amended regulations is the requirement to prepare a written technical basis for the radiological air emission sampling and monitoring program. A key component of the technical basis is the Potential Impact Category (PIC) assigned to an emission point. This paper discusses the PIC assignments for the Pacific Northwest National Laboratory (PNNL) Integrated Laboratory emission units; this revision includes five PIC categories.

  6. Source Emissions in Multipollutant Air Quality Management

    EPA Science Inventory

    Human activities and natural processes that emit pollutants into the ambient atmosphere are the underlying cause of all air quality problems. In a technical sense, we refer to these activities and processes as pollutant sources. Although air quality management is usually concerne...

  7. EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN BURNING

    EPA Science Inventory

    A detailed literature search was performed to collect and collate available data reporting emissions of toxic organic substances into the air from open burning sources. Availability of data varied according to the source and the class of air toxics of interest. Volatile organic c...

  8. WORKSHOP ON SOURCE EMISSION AND AMBIENT AIR MONITORING OF MERCURY

    EPA Science Inventory

    AN EPA/ORD Workshop on Source Emission and Ambient Air Monitoring of Mercury was held on 9/13-14/99, Bloomington, Minnesota. The purpose of the workshop was to discuss the state-of-the-science in source and ambient air mercury monitoring as well as mercury monitoring research and...

  9. National Emission Standards for Hazardous Air Pollutants submittal -- 1997

    SciTech Connect

    Townsend, Y.E.; Black, S.C.

    1998-06-01

    Each potential source of Nevada Test Site (NTS) emissions was characterized by one of the following methods: (1) monitoring methods and procedures previously developed at the NTS; (2) a yearly radionuclide inventory of the source, assuming that volatile radionuclide are released to the environment; (3) the measurement of tritiated water (as HTO or T{sub 2}O) concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) using a combination of environmental measurements and CAP88-PC to calculate emissions. The emissions for National Emission Standards for Hazardous Air Pollutants (NESHAPs) reporting are listed. They are very conservative and are used in Section 3 to calculate the EDE to the maximally exposed individual offsite. Offsite environmental surveillance data, where available, are used to confirm that calculated emissions are, indeed, conservative.

  10. Impacts of Energy Sector Emissions on PM2.5 Air Quality in Northern India

    NASA Astrophysics Data System (ADS)

    Karambelas, A. N.; Kiesewetter, G.; Heyes, C.; Holloway, T.

    2015-12-01

    India experiences high concentrations of fine particulate matter (PM2.5), and several Indian cities currently rank among the world's most polluted cities. With ongoing urbanization and a growing economy, emissions from different energy sectors remain major contributors to air pollution in India. Emission sectors impact ambient air quality differently due to spatial distribution (typical urban vs. typical rural sources) as well as source height characteristics (low-level vs. high stack sources). This study aims to assess the impacts of emissions from three distinct energy sectors—transportation, domestic, and electricity—on ambient PM2.5­­ in northern India using an advanced air quality analysis framework based on the U.S. EPA Community Multi-Scale Air Quality (CMAQ) model. Present air quality conditions are simulated using 2010 emissions from the Greenhouse Gas-Air Pollution Interaction and Synergies (GAINS) model. Modeled PM2.5 concentrations are compared with satellite observations of aerosol optical depth (AOD) from the Moderate Imaging Spectroradiometer (MODIS) for 2010. Energy sector emissions impacts on future (2030) PM2.5 are evaluated with three sensitivity simulations, assuming maximum feasible reduction technologies for either transportation, domestic, or electricity sectors. These simulations are compared with a business as usual 2030 simulation to assess relative sectoral impacts spatially and temporally. CMAQ is modeled at 12km by 12km and include biogenic emissions from the Community Land Model coupled with the Model of Emissions of Gases and Aerosols in Nature (CLM-MEGAN), biomass burning emissions from the Global Fires Emissions Database (GFED), and ERA-Interim meteorology generated with the Weather Research and Forecasting (WRF) model for 2010 to quantify the impact of modified anthropogenic emissions on ambient PM2.5 concentrations. Energy sector emissions analysis supports decision-making to improve future air quality and public health in

  11. CRITERIA AND AIR TOXIC EMISSIONS FROM IN-USE, LOW EMISSION VEHICLES (LEVS)

    EPA Science Inventory

    The U.S. Environmental Protection Agency implemented a program to identify tailpipe emissions of criteria and air toxic contaminants from in-use, light-duty Low Emission Vehicles (LEVs). EPA recruited twenty-five LEVs in 2002, and measured emissions on a chassis dynamometer usin...

  12. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions, Calendar Year 2010

    SciTech Connect

    NSTec Ecological and Environmental Monitoring

    2011-06-30

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada National Security Site (NNSS, formerly the Nevada Test Site) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR, 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as those from the damaged Fukushima nuclear power plant in Japan. Because this report is intended to discuss radioactive air emissions during calendar year 2010, data on radionuclides in air from the 2011 Fukushima nuclear power plant releases are not presented but will be included in the report for calendar year 2011. The NNSS demonstrates compliance with the NESHAP

  13. National Emission Standards for Hazardous Air Pollutants submittal -- 1994

    SciTech Connect

    Townsend, Y.E.; Black, S.C.

    1995-06-01

    This report focuses on air quality at the Nevada Test Site (NTS) for 1994. A general description of the effluent sources are presented. Each potential source of NTS emissions was characterized by one of the following: (1) by monitoring methods and procedures previously developed at NTS; (2) by a yearly radionuclide inventory of the source, assuming that volatile radionuclides are released to the environment; (3) by the measurement of tritiated water concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) by using a combination of environmental measurements and CAP88-PC to calculate emissions. Appendices A through J describe the methods used to determine the emissions from the sources. These National Emission Standards for Hazardous Air Pollutants (NESHAP) emissions are very conservative, are used to calculate the effective dose equivalent to the Maximally Exposed Individual offsite, and exceed, in some cases, those reported in DOE`s Effluent Information System (EIS). The NESHAP`s worst-case emissions that exceed the EIS reported emissions are noted. Offsite environmental surveillance data are used to confirm that calculated emissions are, indeed, conservative.

  14. National Emission Standards for Hazardous Air Pollutants Submittal - 1995

    SciTech Connect

    Black, S.C.; Townsend, Y.E.

    1996-06-01

    This report contains National Emission Standards for Hazardous Air Pollutants at the Nevada Test Site (NTS). It provides lists of figures and tables related to the NTS and includes a Site Description. The Source Description includes current and previous activities conducted on the NTS. The Site has been the primary location for testing of nuclear explosives in the Continental U.S. since 1951. Historical testing has included (1) atmospheric testing in the 1950`s and early 1960s, (2) earth-cratering experiments, and (3) open-air nuclear reactor and rocket engine testing. At the North Las Vegas Facility, operated for DOE/NV by EG&G Energy Measurements, there was an Unusual Occurrence that led to an insignificant potential exposure to an offsite person. The incident involved the release of tritiated water (HTO), and a description of the incident and the method of calculating the effective dose equivalent for offsite exposure are described. The Source Description further describes Ground Seepage of Noble Gases, Radioactive Waste Management Sites, and Plutonium Contaminated Surface Areas.

  15. Pacific Northwest National Laboratory Campus Radionuclide Air Emissions Report for Calendar Year 2013

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

    2014-06-01

    This report documents radionuclide air emissions that result in the highest effective dose equivalent (EDE) to a member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and Washington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. The dose to the PNNL Site MEI due to routine major and minor point source emissions in 2013 from PNNL Site sources is 2E-05 mrem (2E-07 mSv) EDE. The dose from fugitive emissions (i.e., unmonitored sources) is 2E-6 mrem (2E-8 mSv) EDE. The dose from radon emissions is 1E-11 mrem (1E-13 mSv) EDE. No nonroutine emissions occurred in 2013. The total radiological dose for 2013 to the MEI from all PNNL Site radionuclide emissions, including fugitive emissions and radon, is 2E-5 mrem (2E-7 mSv) EDE, or 100,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Site is in compliance

  16. Pacific Northwest National Laboratory Site Radionuclide Air Emissions Report for Calendar Year 2012

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

    2013-06-06

    This report documents radionuclide air emissions that result in the highest effective dose equivalent (EDE) to a member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and Washington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. The dose to the PNNL Site MEI due to routine major and minor point source emissions in 2012 from PNNL Site sources is 9E-06 mrem (9E-08 mSv) EDE. The dose from fugitive emissions (i.e., unmonitored sources) is 1E-7 mrem (1E-9 mSv) EDE. The dose from radon emissions is 2E-6 mrem (2E-08 mSv) EDE. No nonroutine emissions occurred in 2012. The total radiological dose for 2012 to the MEI from all PNNL Site radionuclide emissions, including fugitive emissions and radon, is 1E-5 mrem (1E-7 mSv) EDE, or 100,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Site is in compliance.

  17. EMISSION OF PESTICIDES INTO THE AIR

    EPA Science Inventory

    During and after the application of pesticide in agriculture, a substantial fraction of the dosage may enter the atmosphere and be transported over varying distances downwind of the target. The rate and extent of the emission during application depends primarily on the applicat...

  18. The effects of energy paths and emission controls and standards on future trends in China's emissions of primary air pollutants

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Zhang, J.; Nielsen, C. P.

    2014-09-01

    To examine the efficacy of China's actions to control atmospheric pollution, three levels of growth of energy consumption and three levels of implementation of emission controls are estimated, generating a total of nine combined activity-emission control scenarios that are then used to estimate trends of national emissions of primary air pollutants through 2030. The emission control strategies are expected to have more effects than the energy paths on the future emission trends for all the concerned pollutants. As recently promulgated national action plans of air pollution prevention and control (NAPAPPC) are implemented, China's anthropogenic pollutant emissions should decline. For example, the emissions of SO2, NOx, total suspended particles (TSP), PM10, and PM2.5 are estimated to decline 7, 20, 41, 34, and 31% from 2010 to 2030, respectively, in the "best guess" scenario that includes national commitment of energy saving policy and implementation of NAPAPPC. Should the issued/proposed emission standards be fully achieved, a less likely scenario, annual emissions would be further reduced, ranging from 17 (for primary PM2.5) to 29% (for NOx) declines in 2015, and the analogue numbers would be 12 and 24% in 2030. The uncertainties of emission projections result mainly from the uncertain operational conditions of swiftly proliferating air pollutant control devices and lack of detailed information about emission control plans by region. The predicted emission trends by sector and chemical species raise concerns about current pollution control strategies: the potential for emissions abatement in key sectors may be declining due to the near saturation of emission control devices use; risks of ecosystem acidification could rise because emissions of alkaline base cations may be declining faster than those of SO2; and radiative forcing could rise because emissions of positive-forcing carbonaceous aerosols may decline more slowly than those of SO2 emissions and thereby

  19. The effects of energy paths and emission controls and standards on future trends in China's emissions of primary air pollutants

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Zhang, J.; Nielsen, C. P.

    2014-03-01

    To examine the efficacy of China's actions to control atmospheric pollution, three levels of growth of energy consumption and three levels of implementation of emission controls are estimated, generating a total of nine combined activity-emission control scenarios that are then used to estimate trends of national emissions of primary air pollutants through 2030. The emission control strategies are expected to have more effects than the energy paths on the future emission trends for all the concerned pollutants. As recently promulgated national action plans of air pollution prevention and control (NAPAPPC) are implemented, China's anthropogenic pollutant emissions should decline. For example, the emissions of SO2, NOx, total primary particulate matter (PM), PM10, and PM2.5 are estimated to decline 7%, 20%, 41%, 34%, and 31% from 2010 to 2030, respectively, in the "best guess" scenario that includes national commitment of energy saving policy and partial implementation of NAPAPPC. Should the issued/proposed emission standards be fully achieved, a less likely scenario, annual emissions would be further reduced, ranging from 17% (for primary PM2.5) to 29% (for NOx) declines in 2015, and the analogue numbers would be 12% and 24% in 2030. The uncertainties of emission projections result mainly from the uncertain operational conditions of swiftly proliferating air pollutant control devices and lack of detailed information about emission control plans by region. The predicted emission trends by sector and chemical species raise concerns about current pollution control strategies: the potential for emissions abatement in key sectors may be declining due to the near saturation of emission control devices use; risks of ecosystem acidification could rise because emissions of alkaline base cations may be declining faster than those of SO2; and radiative forcing could rise because emissions of positive-forcing carbonaceous aerosols may decline more slowly than those of SO2

  20. Modeling and Qualification of a Modified Emission Unit for Radioactive Air Emissions Stack Sampling Compliance.

    PubMed

    Barnett, J Matthew; Yu, Xiao-Ying; Recknagle, Kurtis P; Glissmeyer, John A

    2016-11-01

    A planned laboratory space and exhaust system modification to the Pacific Northwest National Laboratory Material Science and Technology Building indicated that a new evaluation of the mixing at the air sampling system location would be required for compliance to ANSI/HPS N13.1-2011. The modified exhaust system would add a third fan, thereby increasing the overall exhaust rate out the stack, thus voiding the previous mixing study. Prior to modifying the radioactive air emissions exhaust system, a three-dimensional computational fluid dynamics computer model was used to evaluate the mixing at the sampling system location. Modeling of the original three-fan system indicated that not all mixing criteria could be met. A second modeling effort was conducted with the addition of an air blender downstream of the confluence of the three fans, which then showed satisfactory mixing results. The final installation included an air blender, and the exhaust system underwent full-scale tests to verify velocity, cyclonic flow, gas, and particulate uniformity. The modeling results and those of the full-scale tests show agreement between each of the evaluated criteria. The use of a computational fluid dynamics code was an effective aid in the design process and allowed the sampling system to remain in its original location while still meeting the requirements for sampling at a well mixed location. PMID:27682902

  1. Emission inventories and modeling requirements for the development of air quality plans. Application to Madrid (Spain).

    PubMed

    Borge, Rafael; Lumbreras, Julio; Pérez, Javier; de la Paz, David; Vedrenne, Michel; de Andrés, Juan Manuel; Rodríguez, Ma Encarnación

    2014-01-01

    Modeling is an essential tool for the development of atmospheric emission abatement measures and air quality plans. Most often these plans are related to urban environments with high emission density and population exposure. However, air quality modeling in urban areas is a rather challenging task. As environmental standards become more stringent (e.g. European Directive 2008/50/EC), more reliable and sophisticated modeling tools are needed to simulate measures and plans that may effectively tackle air quality exceedances, common in large urban areas across Europe, particularly for NO₂. This also implies that emission inventories must satisfy a number of conditions such as consistency across the spatial scales involved in the analysis, consistency with the emission inventories used for regulatory purposes and versatility to match the requirements of different air quality and emission projection models. This study reports the modeling activities carried out in Madrid (Spain) highlighting the atmospheric emission inventory development and preparation as an illustrative example of the combination of models and data needed to develop a consistent air quality plan at urban level. These included a series of source apportionment studies to define contributions from the international, national, regional and local sources in order to understand to what extent local authorities can enforce meaningful abatement measures. Moreover, source apportionment studies were conducted in order to define contributions from different sectors and to understand the maximum feasible air quality improvement that can be achieved by reducing emissions from those sectors, thus targeting emission reduction policies to the most relevant activities. Finally, an emission scenario reflecting the effect of such policies was developed and the associated air quality was modeled.

  2. Air Emission, Liquid Effluent Inventory and Reporting

    SciTech Connect

    Chapman, Tina

    1998-08-18

    The IES maintains an inventory of radiological air and liquid effluents released to the atmosphere. The IES utilizes the official stack numbers. Data may be entered by generators for any monitoring time period. Waste volumes released as well as their radiological constituents are tracked. The IES provides data to produce a report for NESHAPS as well as several administrative action/anomaly reports. These reports flag unusual occurences (releases) that are above normal range releases.

  3. US Department of Energy radionuclide air emissions annual report (under Subpart H of 40 CFR Part 61) calendar year 1993

    SciTech Connect

    Not Available

    1993-12-31

    This report contains information collected by the Rocky Flats Plant concerning the emission of radionuclides into the air. Topics discussed include: Facility information, source description, air emissions data, dose assessments, point and non-point sources, and supplemental information on decontamination of concrete docks.

  4. Integrated assessment of brick kiln emission impacts on air quality.

    PubMed

    Le, Hoang Anh; Oanh, Nguyen Thi Kim

    2010-12-01

    This paper presents monitoring results of daily brick kiln stack emission and the derived emission factors. Emission of individual air pollutant varied significantly during a firing batch (7 days) and between kilns. Average emission factors per 1,000 bricks were 6.35-12.3 kg of CO, 0.52-5.9 kg of SO(2) and 0.64-1.4 kg of particulate matter (PM). PM emission size distribution in the stack plume was determined using a modified cascade impactor. Obtained emission factors and PM size distribution data were used in simulation study using the Industrial Source Complex Short-Term (ISCST3) dispersion model. The model performance was successfully evaluated for the local conditions using the simultaneous ambient monitoring data in 2006 and 2007. SO(2) was the most critical pollutant, exceeding the hourly National Ambient Air Quality Standards over 63 km(2) out of the 100-km(2) modelled domain in the base case. Impacts of different emission scenarios on the ambient air quality (SO(2), PM, CO, PM dry deposition flux) were assessed.

  5. 76 FR 12863 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-09

    ... that provided national emission standards for hazardous air pollutants for existing stationary spark... Docket Center (6102T), National Emission Standards for Hazardous Air Pollutant for Stationary... Standards for Hazardous Air Pollutant for Stationary Reciprocating Internal Combustion Engines...

  6. Emissions and Air Quality Impacts of Freight Transportation

    NASA Astrophysics Data System (ADS)

    Bickford, Erica

    Diesel freight vehicles (trucks + trains) are responsible for 20% of all U.S. nitrogen oxide (NOx) and 3% of fine particulate (PM2.5) emissions - pollutants that are harmful to human health. Freight tonnage is also projected to double over the next several decades, reaching 30 billion tons by 2050, increasing freight transport activity. Air quality impacts from increased activity, trade-offs between activity and vehicle technology improvements, as well as where to make infrastructure investments that encourage sustainable freight growth, are important considerations for transportation and air quality managers. To address these questions, we build a bottom-up roadway-by-roadway freight truck inventory (WIFE) and employ it to quantify emissions impacts of swapping biodiesel blends into the Midwest diesel freight truck fleet, and investigate emissions and air quality impacts of truck-to-rail freight modal shifts in the Midwest. We also evaluate the spatial and seasonal freight performance of WIFE modeled in a regional photochemical model (CMAQ) against satellite retrievals of nitrogen dioxide (NO2) from the Ozone Monitoring Instrument (OMI). Results show that spatial and seasonal distribution of biodiesel affects regional emissions impacts. Summer high-blend deployment yields a larger annual emissions reduction than year-round low-blend deployment, however, technological improvements in vehicle emissions controls between 2009 and 2018 dwarf the impacts of biodiesel. Truck-to-rail modal shift analysis found 40% of daily freight truck VMT could be shifted to rail freight, causing a 26% net reduction in NOx emissions, and 31% less carbon dioxide (CO2) emissions. Despite significant emissions impacts, air quality modeling results showed mostly localized near roadway air quality improvements, with small regional net changes; yet, federal regulation of CO2 emissions and/or rising costs of diesel fuel could motivate shifting freight to more fuel efficient rail. Evaluation of

  7. Feasibility of including fugitive PM-10 emissions estimates in the EPA emissions trends report

    SciTech Connect

    Barnard, W.; Carlson, P.

    1990-09-01

    The report describes the results of Part 2 of a two part study. Part 2 was to evaluate the feasibility of developing regional emission trends for PM-10. Part 1 was to evaluate the feasibility of developing VOC emission trends, on a regional and temporal basis. These studies are part of the effort underway to improve the national emission trends. Part 1 is presented in a separate report. The categories evaluated for the feasibility of developing regional emissions estimates were: unpaved roads, paved roads, wind erosion, agricultural tilling, construction activities, feedlots, burning, landfills, mining and quarrying unpaved parking lots, unpaved airstrips and storage piles.

  8. Impact of urban emission on air-quality over central Europe: present day and future emissions perspective

    NASA Astrophysics Data System (ADS)

    Huszar, Peter; Belda, Michal; Halenka, Tomas; Karlicky, Jan

    2016-04-01

    The purpose of the study is to quantify the impact of present-day and future urban emission from central European cities on the regional air-quality (AQ), based on a modeling couple of the regional climate model RegCM4.2 and the chemistry transport model CAMx, including two-way interactions. A series of simulations was carried out for the present (2001-2010) decade and two future decades (2026-2035 and 2046-2055) either with all urban emissions included (base case) or without considering urban emissions. As we are interested on the impact of emission changes only, the impact of different driving meteorological conditions in the future (due to climate change) are not considered. The emissions used is the TNO MEGAPOLI European emission database that includes country/sector based scenarios for years 2030 and 2050, which were used for the encompassing decades. Further, the sensitivity of ozone production to urban emissions was examined by performing reduction experiments with -20% emission perturbation of NOx and/or NMVOC. The model was also validated using surface measurements of key pollutants. Selected air-quality measures were used as metrics describing the cities emission impact on regional air pollution. Due to urban emissions, significant ozone titration occurs over cities while over rural areas further from, ozone production is modeled, mainly in terms of number of exceedances and accumulated exceedances over the threshold of 40 ppbv. Urban NOx, SO2 and PM2.5 emissions also significantly contribute to concentrations in the cities themselves (up to 50-70% for NOx and SO2 , and up to 55% for PM2.5), but the contribution is large over rural areas as well (10-20%). Although air pollution over cities is largely determined by the local urban emissions, considerable (often a few tens of %) fraction of the concentration is attributable to other sources from rural areas and minor cities. The future urban emission AQ fingerprint is, in general, slightly smaller than in

  9. Estimating Lightning NOx Emissions for Regional Air Quality Modeling

    NASA Astrophysics Data System (ADS)

    Holloway, T.; Scotty, E.; Harkey, M.

    2014-12-01

    Lightning emissions have long been recognized as an important source of nitrogen oxides (NOx) on a global scale, and an essential emission component for global atmospheric chemistry models. However, only in recent years have regional air quality models incorporated lightning NOx emissions into simulations. The growth in regional modeling of lightning emissions has been driven in part by comparisons with satellite-derived estimates of column NO2, especially from the Ozone Monitoring Instrument (OMI) aboard the Aura satellite. We present and evaluate a lightning inventory for the EPA Community Multiscale Air Quality (CMAQ) model. Our approach follows Koo et al. [2010] in the approach to spatially and temporally allocating a given total value based on cloud-top height and convective precipitation. However, we consider alternate total NOx emission values (which translate into alternate lightning emission factors) based on a review of the literature and performance evaluation against OMI NO2 for July 2007 conditions over the U.S. and parts of Canada and Mexico. The vertical distribution of lightning emissions follow a bimodal distribution from Allen et al. [2012] calculated over 27 vertical model layers. Total lightning NO emissions for July 2007 show the highest above-land emissions in Florida, southeastern Texas and southern Louisiana. Although agreement with OMI NO2 across the domain varied significantly depending on lightning NOx assumptions, agreement among the simulations at ground-based NO2 monitors from the EPA Air Quality System database showed no meaningful sensitivity to lightning NOx. Emissions are compared with prior studies, which find similar distribution patterns, but a wide range of calculated magnitudes.

  10. A continuous sampling air-ICP for metals emission monitoring

    SciTech Connect

    Baldwin, D.P.; Zamzow, D.S.; Eckels, D.E.; Miller, G.P.

    1999-09-19

    An air-inductively coupled plasma (air-ICP) system has been developed for continuous sampling and monitoring of metals as a continuous emission monitor (CEM). The plasma is contained in a metal enclosure to allow reduced-pressure operation. The enclosure and plasma are operated at a pressure slightly less than atmospheric using a Roots blower, so that sample gas is continuously drawn into the plasma. A Teflon sampling chamber, equipped with a sampling pump, is connected to the stack that is to be monitored to isokinetically sample gas from the exhaust line and introduce the sample into the air-ICP. Optical emission from metals in the sampled gas stream is detected and monitored using an acousto-optic tunable filter (AOTF)--echelle spectrometer system. A description of the continuous sampling air-ICP system is given, along with some preliminary laboratory data for continuous monitoring of metals.

  11. Effect of low emission sources on air quality in Cracow

    SciTech Connect

    Nedoma, J.

    1995-12-31

    The paper presents calculation of power engineering low emission and results of stimulation of the effect of this emission on air quality in Cracow, Poland. It has been stated that the segment of low emission in central areas of the town makes up ca. 40% of the observed concentration of sulfur dioxide. Furthermore it has been stated that the capital investment must be concentrated in the central part of the town in order to reach noticeable improvement of air quality in Cracow. Neither the output of a separate power source nor the emission level and its individual harmful effect, but the location of the source and especially packing density of the sources must decide the priority of upgrading actions.

  12. Polarized radio emission from extensive air showers measured with LOFAR

    SciTech Connect

    Schellart, P.; Buitink, S.; Corstanje, A.; Enriquez, J.E.; Falcke, H.; Hörandel, J.R.; Krause, M.; Nelles, A.; Rachen, J.P.; Veen, S. ter; Thoudam, S.

    2014-10-01

    We present LOFAR measurements of radio emission from extensive air showers. We find that this emission is strongly polarized, with a median degree of polarization of nearly 99%, and that the angle between the polarization direction of the electric field and the Lorentz force acting on the particles, depends on the observer location in the shower plane. This can be understood as a superposition of the radially polarized charge-excess emission mechanism, first proposed by Askaryan and the geomagnetic emission mechanism proposed by Kahn and Lerche. We calculate the relative strengths of both contributions, as quantified by the charge-excess fraction, for 163 individual air showers. We find that the measured charge-excess fraction is higher for air showers arriving from closer to the zenith. Furthermore, the measured charge-excess fraction also increases with increasing observer distance from the air shower symmetry axis. The measured values range from (3.3± 1.0)% for very inclined air showers at 25 m to (20.3± 1.3)% for almost vertical showers at 225 m. Both dependencies are in qualitative agreement with theoretical predictions.

  13. Physical Sciences Facility Air Emission Control Equivalency Evaluation

    SciTech Connect

    Brown, David M.; Belew, Shan T.

    2008-10-17

    This document presents the adequacy evaluation for the application of technology standards during design, fabrication, installation and testing of radioactive air exhaust systems at the Physical Sciences Facility (PSF), located on the Horn Rapids Triangle north of the Pacific Northwest National Laboratory (PNNL) complex. The analysis specifically covers the exhaust portion of the heating, ventilation and air conditioning (HVAC) systems associated with emission units EP-3410-01-S, EP-3420-01-S and EP 3430-01-S.

  14. Megacity and country emissions from combustion sources-Buenos Aires-Argentina

    NASA Astrophysics Data System (ADS)

    Dawidowski, L.; Gomez, D.; Matranga, M.; D'Angiola, A.; Oreggioni, G.

    2010-12-01

    Historic time series (1970-2006) emissions of greenhouse gases and air pollutants arising from stationary and mobile combustion sources were estimated at national level for Argentina and at regional level for the metropolitan area of Buenos Aires (MABA). All emissions were estimated using a bottom-up approach following the IPCC good practice guidance. For mobile sources, national emissions include all transport categories. Regional emissions account thus far only for on-road. For national emissions, methodologies and guidance by the IPCC were employed, applying the highest possible tier and using: i)country-specific emission factors for carbon and sulphur and technology-based information for other species, ii)activity data from energy balance series (1970-2007), and iii)complementary information concerning the non-energy use of fuels. Regional emissions in 2006 were estimated in-depth using a technology-based approach for the city of Buenos Aires (CBA) and the 24 neighboring districts composing the MABA. A regional emissions factors database was developed to better characterize Latin American fleets and driving conditions employing COPERT III-IV algorithms and emission factors measured in dynamometers and circulating vehicles in Argentina, Brazil, Chile and Colombia. Past emissions were back estimated from 2005 to 1970 using the best available information, which differs greatly among categories, spatial disaggregation and time periods. The time series of stationary and mobile combustion sources at the national and regional level allowed the identification of distinct patterns. National greenhouse gas emissions in 2006 amounted to ~ 150 million ton CO2-equivalent, 70% of which were contributed by stationary sources. On-road transport was the major contributor within mobile sources (28.1 %). The increasing emissions trends are dominated by on-road transport, agriculture and residential categories while the variability is largely associated with energy industries

  15. RADIONUCLIDE AIR EMISSIONS REPORT FOR THE HANFORD SITE CY2003

    SciTech Connect

    ROKKAN, D.J.

    2004-06-11

    This report documents radionuclide air emissions from the US Department of Energy (DOE) Hanford Site in 2003 and the resulting effective dose equivalent (EDE) to the maximally exposed individual (MEI) member of the public. The report has been prepared in accordance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities''; Washington Administrative Code (WAC) Chapter 246-247, ''Radiation Protection-Air Emissions''; 10 CFR 830.120, Quality Assurance; DOE Order 414.1B, Quality Assurance; NQA-1, Quality Assurance Requirements for Nuclear Facility Application; EPA QA/R-2, EPA Requirements for Quality Management Plans; and EPA QA/R-5, Requirements for Quality Assurance Project Plans. The federal regulations in Subpart H of 40 CFR 61 require the measurement and reporting of radionuclides emitted from DOE facilities and the resulting public dose from those emissions. A standard of 10 mrem/yr EDE is not to be exceeded. The EDE to the MEI due to routine and nonroutine emissions in 2003 from Hanford Site point sources was 0.022 mrem (0.00022 mSv), or 0.22 percent of the federal standard. The portions of the Hanford Site MEI dose attributable to individual point sources as listed in Section 2.0 are appropriate for use in demonstrating the compliance of abated stack emissions with applicable terms of the Hanford Site Air Operating Permit and of Notices of Construction. The state has adopted the 40 CFR 61 standard of 10 mrem/yr EDE into their regulations, yet further requires that the EDE to the MEI be calculated not only from point source emissions but also from diffuse and fugitive sources of emissions. WAC 246-247 also requires the reporting of radionuclide emissions from all Hanford Site sources during routine as well as nonroutine operations. The EDE from

  16. 77 FR 16508 - National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-21

    ..., was published on January 9, 2012 (77 FR 1268). EPA has established the public docket for the proposed...: Group IV Polymers and Resins; Pesticide Active Ingredient Production; and Polyether Polyols Production... pollutants: National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and...

  17. Evaluation of life-cycle air emission factors of freight transportation.

    PubMed

    Facanha, Cristiano; Horvath, Arpad

    2007-10-15

    Life-cycle air emission factors associated with road, rail, and air transportation of freight in the United States are analyzed. All life-cycle phases of vehicles, infrastructure, and fuels are accounted for in a hybrid life-cycle assessment (LCA). It includes not only fuel combustion, but also emissions from vehicle manufacturing, maintenance, and end of life, infrastructure construction, operation, maintenance, and end of life, and petroleum exploration, refining, and fuel distribution. Results indicate that total life-cycle emissions of freight transportation modes are underestimated if only tailpipe emissions are accounted for. In the case of CO2 and NOx, tailpipe emissions underestimate total emissions by up to 38%, depending on the mode. Total life-cycle emissions of CO and SO2 are up to seven times higher than tailpipe emissions. Sensitivity analysis considers the effects of vehicle type, geography, and mode efficiency on the final results. Policy implications of this analysis are also discussed. For example, while it is widely assumed that currently proposed regulations will result in substantial reductions in emissions, we find that this is true for NOx, emissions, because fuel combustion is the main cause, and to a lesser extent for SO2, but not for PM10 emissions, which are significantly affected by the other life-cycle phases.

  18. How big is big? How often is often? Characterizing Texas petroleum refining upset air emissions

    NASA Astrophysics Data System (ADS)

    McCoy, Britney J.; Fischbeck, Paul S.; Gerard, David

    2010-11-01

    This work examines the magnitude and frequency of Texas petroleum refineries upset air emissions over a 44-month period. Upset emissions occur during plant start-ups, shut-downs, maintenance, malfunctions and flaring incidents, and these emissions are typically exempt from regulation. These emissions contain a variety of chemicals, including benzene, nitrogen oxides, sulfur dioxide, and butadiene. Unlike other states, Texas has detailed reporting requirements, regulations in place, and an extensive upset emissions database. A key scientific and public policy question is whether upset emissions have significant impacts on local air quality and public health. However, it is not possible to address this question without first understanding the magnitude and properties of upsets. We merge related databases to examine over 3,900 upset emission events and find that upset emissions are significant in both size and occurrence when compared to routine operation emissions. It is determined that these events are not random, being more likely to occur during the summer, in the morning, and early in the workweek. A regional analysis of Port Arthur suggests that upset emissions from co-located refineries are equivalent to having an additional refinery within the region. Because of uncertainties within the reporting process and an obvious underestimation by some refineries, there is a need for better tracking of upset emissions.

  19. Air pollution radiative forcing from specific emissions sectors at 2030

    NASA Astrophysics Data System (ADS)

    Unger, Nadine; Shindell, Drew T.; Koch, Dorothy M.; Streets, David G.

    2008-01-01

    Reduction of short-lived air pollutants can contribute to mitigate global warming in the near-term with ancillary benefits to human health. However, the radiative forcings of short-lived air pollutants depend on the location and source type of the precursor emissions. We apply the Goddard Institute for Space Studies atmospheric composition-climate model to quantify near-future (2030 A1B) global annual mean radiative forcing by ozone (O3) and sulfate from six emissions sectors in seven geographic regions. At 2030 the net forcings from O3, sulfate, black and organic carbon, and indirect CH4 effects for each emission sector are (in mWm-2) biomass burning, +95; domestic, +68; transportation, +67; industry, -131; and power, -224. Biomass burning emissions in East Asia and central and southern Africa, domestic biofuel emissions in East Asia, south Asia, and central and southern Africa, and transportation emissions in Europe and North America have large net positive forcings and are therefore attractive targets to counter global warming. Power and industry emissions from East Asia, south Asia, and north Africa and the Middle East have large net negative forcings. Therefore air quality control measures that affect these regional sectors require offsetting climate measures to avoid a warming impact. Linear relationships exist between O3 forcing and biomass burning and domestic biofuel CO precursor emissions independent of region with sensitivity of +0.2 mWm-2/TgCO. Similarly, linear relationships exist between sulfate forcing and SO2 precursor emissions that depend upon region but are independent of sector with sensitivities ranging from -3 to -12 mWm-2/TgS.

  20. Year 2015 Aircraft Emission Scenario for Scheduled Air Traffic

    NASA Technical Reports Server (NTRS)

    Baughcum, Steven L.; Sutkus, Donald J.; Henderson, Stephen C.

    1998-01-01

    This report describes the development of a three-dimensional scenario of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons)for projected year 2015 scheduled air traffic. These emission inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxides, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

  1. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2012

    SciTech Connect

    Warren, R.

    2013-06-10

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan in 2011. NNSA/NFO demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations on the NNSS (U.S. Environmental Protection Agency [EPA] and DOE 1995). This method was approved by the EPA for use on the NNSS in 2001 (EPA 2001a) and has

  2. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions, Calendar Year 2011

    SciTech Connect

    NSTec Ecological and Environmental Monitoring

    2012-06-19

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan. Radionuclides from the Fukushima nuclear power plant were detected at the NNSS in March 2011 and are discussed further in Section III. The NNSS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the EPA for use on the

  3. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2013

    SciTech Connect

    Warren, R.

    2014-06-04

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitations to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan in 2011. NNSA/NFO demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations on the NNSS (U.S. Environmental Protection Agency [EPA] and DOE 1995). This method was approved by the EPA for use on the NNSS in 2001 (EPA 2001a) and has

  4. Method and apparatus for reducing cold-phase emissions by utilizing oxygen-enriched intake air

    DOEpatents

    Poola, Ramesh B.; Sekar, Ramanujam R.; Stork, Kevin C.

    1997-01-01

    An oxygen-enriched air intake control system for an internal combustion engine includes air directing apparatus to control the air flow into the intake of the engine. During normal operation of the engine, ambient air flowing from an air filter of the engine flows through the air directing apparatus into the intake of the engine. In order to decrease the amount of carbon monoxide (CO) and hydrocarbon (HC) emissions that tend to be produced by the engine during a short period of time after the engine is started, the air directing apparatus diverts for a short period of time following the start up of the engine at least a portion of the ambient air from the air filter through a secondary path. The secondary path includes a selectively permeable membrane through which the diverted portion of the ambient air flows. The selectively permeable membrane separates nitrogen and oxygen from the diverted air so that oxygen enriched air containing from about 23% to 25% oxygen by volume is supplied to the intake of the engine.

  5. AIR TOXICS EMISSIONS FROM A VINYL SHOWER CURTAIN

    EPA Science Inventory

    The paper reports results of both static and dynamic chamber tests conducted to evaluate emission characteristics of air toxics from a vinyl shower Curtain. (NOTE: Due to the relatively low price and ease of installation, vinyl shower curtains have been widely used in bathrooms i...

  6. EMISSIONS OF AIR TOXICS FROM A SIMULATED CHARCOAL KILN

    EPA Science Inventory

    The report gives results of experiments in a laboratory-scale charcoal kiln simulator to evaluate emissions of hazardous air pollutants from the production of charcoal in Missouri-type kilns. Fixed combustion gases were measured using continuous monitors. In Addition, other pollu...

  7. VOC EMISSIONS FROM AN AIR FRESHENER IN THE INDOOR ENVIRONMENT

    EPA Science Inventory

    The paper describes results of tests, conducted in the U.S. Environmental Protection Agency (EPA) large chamber facility, that investigated emissions of volatile organic compounds (VOCS) from one electrical plug-in type air freshener with pine-scented refills. VOCs were measured ...

  8. Improving ammonia emissions in air quality modelling for France

    NASA Astrophysics Data System (ADS)

    Hamaoui-Laguel, Lynda; Meleux, Frédérik; Beekmann, Matthias; Bessagnet, Bertrand; Génermont, Sophie; Cellier, Pierre; Létinois, Laurent

    2014-08-01

    We have implemented a new module to improve the representation of ammonia emissions from agricultural activities in France with the objective to evaluate the impact of such emissions on the formation of particulate matter modelled with the air quality model CHIMERE. A novel method has been set up for the part of ammonia emissions originating from mineral fertilizer spreading. They are calculated using the one dimensional 1D mechanistic model “VOLT'AIR” which has been coupled with data on agricultural practices, meteorology and soil properties obtained at high spatial resolution (cantonal level). These emissions display high spatiotemporal variations depending on soil pH, rates and dates of fertilization and meteorological variables, especially soil temperature. The emissions from other agricultural sources (animal housing, manure storage and organic manure spreading) are calculated using the national spatialised inventory (INS) recently developed in France. The comparison of the total ammonia emissions estimated with the new approach VOLT'AIR_INS with the standard emissions provided by EMEP (European Monitoring and Evaluation Programme) used currently in the CHIMERE model shows significant differences in the spatiotemporal distributions. The implementation of new ammonia emissions in the CHIMERE model has a limited impact on ammonium nitrate aerosol concentrations which only increase at most by 10% on the average for the considered spring period but this impact can be more significant for specific pollution episodes. The comparison of modelled PM10 (particulate matter with aerodynamic diameter smaller than 10 μm) and ammonium nitrate aerosol with observations shows that the use of the new ammonia emission method slightly improves the spatiotemporal correlation in certain regions and reduces the negative bias on average by 1 μg m-3. The formation of ammonium nitrate aerosol depends not only on ammonia concentrations but also on nitric acid availability, which

  9. Air quality improvements following implementation of Lisbon's Low Emission Zone

    NASA Astrophysics Data System (ADS)

    Ferreira, F.; Gomes, P.; Tente, H.; Carvalho, A. C.; Pereira, P.; Monjardino, J.

    2015-12-01

    Air pollution levels within Lisbon city limits have been exceeding the limit values established in European Union and national legislation since 2001, with the most problematic cases related to the levels of fine particles (PM10) and nitrogen dioxide (NO2), mainly originated by road traffic. With the objective of answering this public health issue, an Air Quality Action Plan was developed in 2006 and the respective Enforcement Plan was published in 2009. From the overall strategy, one of the major measures presented in this strategy was the creation of a Low Emission Zone (LEZ) in Lisbon, which has been operating since July 2011. Implemented at different stages it has progressively expanded its area, including more vehicle types and adopting more stringent requirements in terms of minimum emission standards (currently LEZ phase 2 with EURO 2 in the city center - zone 1 and EURO 1 in the rest of the LEZ area - zone 2). At the same time the road axis comprised of Marquês de Pombal square and Avenida da Liberdade was subjected to profound changes in its traffic circulation model, reducing road traffic volumes. The analysis of the air quality data before and after the LEZ phase 2 has shown positive evolution when comparing the period between 2011 (before measures) and 2013 (after measures). In 2013, there was a reduction in PM10 annual average concentration of 23% and NO2 annual average concentrations of 12%, compared with the year 2011. Although PM10 reductions were more significant inside the LEZ area, the same was not valid for NO2, suggesting that the implementation of these measures was not as effective in reducing NO2 levels as shown by results in other cities like Berlin and London. The results from road traffic characterization indicate a relevant effect on fleet renewal with an overall decrease in the relative weight of pre-EURO 2 vehicles in 2012/2013, compared with data from 2011. An important increase in the share of EURO 4 and EURO 5 vehicles was also

  10. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2009

    SciTech Connect

    NSTec Ecological and Environmental Monitoring

    2010-06-11

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada Test Site (NTS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NTS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NTS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NTS. After nuclear testing ended in 1992, NTS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium were also emitted to air at the NLVF, an NTS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) limits the release of radioactivity from a U.S. Department of Energy facility to 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation not related to NTS activities. Unrelated doses could come from naturally occurring radioactive elements or from sources such as medically or commercially used radionuclides. The NTS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the U.S. Environmental Protection Agency for use on the NTS in 2001 and has been the sole method used since 2005. Six locations on the NTS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo-critical receptor stations, because no

  11. Energy use, emissions and air pollution reduction strategies in Asia

    SciTech Connect

    Foell, W.; Green, C.; Sarkar, A.; Legler, J.

    1995-12-31

    The pace of economic progress and development experienced in many Asian countries has not occurred without costs to the natural environment. In particular, energy policies and technologies are a primary driving force behind air pollution problems arising from air pollution emissions in Asia. Economic growth, energy use, and reliance on fossil fuels are experiencing extremely high growth throughout most of the continent. Electric power expansion plans in many countries of Asia, particularly China and India, call for substantial increases in coal combustion. In the 1990`s, two-thirds of all power related investments in developing countries will be in Asia. In contrast to the situation in Europe and North America, emissions of air pollution species in Asia are increasing rapidly, resulting in both local air pollution problems and higher acidic deposition in many regions. In general, most Asian countries do not have a strong scientific nor public constituency for addressing potentially serious air pollution problems impacting important economic and cultural activities such as forestry, agriculture, and tourism. The complex political ramifications of trans-boundary air pollution in Asia have not yet begun to be addressed.

  12. Effect of fuel/air nonuniformity on nitric oxide emissions

    NASA Technical Reports Server (NTRS)

    Lyons, V. J.

    1979-01-01

    A flame tube combustor holding jet A fuel was used in experiments performed at a pressure of .3 Mpa and a reference velocity of 25 meters/second for three inlet air temperatures of 600, 700, and 800 K. The gas sample measurements were taken at locations 18 cm and 48 cm downstream of the perforated plate flameholder. Nonuniform fuel/air profiles were produced using a fuel injector by separately fueling the inner five fuel tubes and the outer ring of twelve fuel tubes. Six fuel/air profiles were produced for nominal overall equivalence ratios of .5 and .6. An example of three of three of these profiles and their resultant nitric oxide NOx emissions are presented. The uniform fuel/air profile cases produced uniform and relatively low profile levels. When the profiles were either center-peaked or edge-peaked, the overall mass-weighted nitric oxide levels increased.

  13. Health effects of SRS non-radiological air emissions

    SciTech Connect

    Stewart, J.

    1997-06-16

    This report examines the potential health effects of non radiological emissions to the air resulting from operations at the Savannah River Site (SRS). The scope of this study was limited to the 55 air contaminants for which the US Environmental Protection Agency (EPA) has quantified risk by determining unit risk factors (excess cancer risks) and/or reference concentrations (deleterious non cancer risks). Potential health impacts have been assessed in relation to the maximally exposed individual. This is a hypothetical person who resides for a lifetime at the SRS boundary. The most recent (1994) quality assured SRS emissions data available were used. Estimated maximum site boundary concentrations of the air contaminants were calculated using air dispersion modeling and 24-hour and annual averaging times. For the emissions studied, the excess cancer risk was found to be less than the generally accepted risk level of 1 in 100,000 and, in most cases, was less than 1 in 1,000,000. Deleterious non cancer effects were also found to be very unlikely.

  14. U.S. Department of Energy Report, 2005 LANL Radionuclide Air Emissions

    SciTech Connect

    Keith W. Jacobson, David P. Fuehne

    2006-09-01

    Amendments to the Clean Air Act, which added radionuclides to the National Emissions Standards for Hazardous Air Pollutants (NESHAP), went into effect in 1990. Specifically, a subpart (H) of 40 CFR 61 established an annual limit on the impact to the public attributable to emissions of radionuclides from U.S. Department of Energy facilities, such as the Los Alamos National Laboratory (LANL). As part of the new NESHAP regulations, LANL must submit an annual report to the U.S. Environmental Protection Agency headquarters and the regional office in Dallas by June 30. This report includes results of monitoring at LANL and the dose calculations for the calendar year 2006.

  15. Air pollutant emission rates for sources at the Deaf Smith County repository site

    SciTech Connect

    Not Available

    1985-11-01

    This document summarizes the air-quality source terms used for the Deaf Smith County, Texas environmental assessment report and explains their derivation. The engineering data supporting these source terms appear as appendixes to this report and include summary equipment lists for the repository and detailed equipment lists for the exploratory shaft. Although substantial work has been performed in establishing the current repository design, a greater effort will be required for the final design. Consequently, the repository emission rates presented here should be considered as preliminary estimates. Another set of air pollution emission rates will be calculated after design data are more firmly established. 18 refs., 15 tabs.

  16. Improving the City-scale Emission Inventory of Anthropogenic Air Pollutants: A Case Study of Nanjing

    NASA Astrophysics Data System (ADS)

    Qiu, L.; Zhao, Y.; Xu, R.; Xie, F.; Wang, H.; Qin, H.; Wu, X.; Zhang, J.

    2014-12-01

    To evaluate the improvement of city-scale emission inventory, a high-resolution emission inventory of air pollutants for Nanjing is first developed combining detailed source information, and then justified through quantitative analysis with observations. The best available domestic emission factors and unit-/facility-based activity level data were compiled based on a thorough field survey on major emission sources. Totally 1089 individual emission sources were identified as point sources and all the emission-related parameters including burner type, combustion technology, fuel quality, and removal efficiency of pollution control devices, are carefully investigated and analyzed. Some new data such as detailed information of city fueling-gas stations, construction sites, monthly activity level, data from continuous emission monitoring systems and traffic flow information were combined to improve spatiotemporal distribution of this inventory. For SO2, NOX and CO, good spatial correlations were found between ground observation (9 state controlling air sampling sites in Nanjing) and city-scale emission inventory (R2=0.34, 0.38 and 0.74, respectively). For TSP, PM10 and PM2.5, however, poorer correlation was found due to relatively weaker accuracy in emission estimation and spatial distribution of road dust. The mixing ratios between specific pollutants including OC/EC, BC/CO and CO2/CO, are well correlated between those from ground observation and emission. Compared to MEIC (Multi-resolution Emission Inventory for China), there is a better spatial consistence between this city-scale emission inventory and NO2 measured by OMI (Ozone Monitoring Instrument). In particular, the city-scale emission inventory still correlated well with satellite observations (R2=0.28) while the regional emission inventory showed little correlation with satellite observations (R2=0.09) when grids containing power plants are excluded. It thus confirms the improvement of city-scale emission

  17. Evaluating NOx emission inventories for regulatory air quality modeling using satellite and air quality model data

    NASA Astrophysics Data System (ADS)

    Kemball-Cook, Susan; Yarwood, Greg; Johnson, Jeremiah; Dornblaser, Bright; Estes, Mark

    2015-09-01

    The purpose of this study was to assess the accuracy of NOx emissions in the Texas Commission on Environmental Quality's (TCEQ) State Implementation Plan (SIP) modeling inventories of the southeastern U.S. We used retrieved satellite tropospheric NO2 columns from the Ozone Monitoring Instrument (OMI) together with NO2 columns from the Comprehensive Air Quality Model with Extensions (CAMx) to make top-down NOx emissions estimates using the mass balance method. Two different top-down NOx emissions estimates were developed using the KNMI DOMINO v2.0 and NASA SP2 retrievals of OMI NO2 columns. Differences in the top-down NOx emissions estimates made with these two operational products derived from the same OMI radiance data were sufficiently large that they could not be used to constrain the TCEQ NOx emissions in the southeast. The fact that the two available operational NO2 column retrievals give such different top-down NOx emissions results is important because these retrievals are increasingly being used to diagnose air quality problems and to inform efforts to solve them. These results reflect the fact that NO2 column retrievals are a blend of measurements and modeled data and should be used with caution in analyses that will inform policy development. This study illustrates both benefits and challenges of using satellite NO2 data for air quality management applications. Comparison with OMI NO2 columns pointed the way toward improvements in the CAMx simulation of the upper troposphere, but further refinement of both regional air quality models and the NO2 column retrievals is needed before the mass balance and other emission inversion methods can be used to successfully constrain NOx emission inventories used in U.S. regulatory modeling.

  18. Temporal and modal characterization of DoD source air toxic emission factors: final report

    EPA Science Inventory

    This project tested three, real-/near real-time monitoring techniques to develop air toxic emission factors for Department of Defense (DoD) platform sources. These techniques included: resonance enhanced multi photon ionization time of flight mass spectrometry (REMPI-TOFMS) for o...

  19. 75 FR 54969 - National Emission Standards for Hazardous Air Pollutants From the Portland Cement Manufacturing...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-09

    ... requirements through the Integrated Urban Air Toxics Strategy (64 FR 38715, July 19, 1999).\\2\\ \\1\\ An area... Industry (64 FR 31898, June 14, 1999) included emission limits based on performance of MACT for the control... of CAA section 112(c)(6), we set MACT standards for these pollutants. 63 FR 17838, 17848, April...

  20. Mode-selective terahertz emission from rippled air irradiated by femtosecond laser pulses

    NASA Astrophysics Data System (ADS)

    Shin, Junghun; Zhidkov, Alexei; Jin, Zhan; Hosokai, Tomonao; Kodama, Ryosuke

    2014-04-01

    Terahertz (THz) emission from rippled air is studied in multidimensional particle-in-cell simulations that include optical field ionization. The ionization modulation in a plasma channel produced by a laser pulse propagating along a ripple and the pulse self-focusing result in THz mode selection with the generation of intense signals having quasi-monochromatic spectral distributions.

  1. The Impact of Residential Combustion Emissions on Air Quality and Human Health in China

    NASA Astrophysics Data System (ADS)

    Archer-Nicholls, S.; Wiedinmyer, C.; Baumgartner, J.; Brauer, M.; Cohen, A.; Carter, E.; Frostad, J.; Forouzanfar, M.; Xiao, Q.; Liu, Y.; Yang, X.; Hongjiang, N.; Kun, N.

    2015-12-01

    Solid fuel cookstoves are used heavily in rural China for both residential cooking and heating purposes. Their use contributes significantly to regional emissions of several key pollutants, including carbon monoxide, volatile organic compounds, oxides of nitrogen, and aerosol particles. The residential sector was responsible for approximately 36%, 46% and 81% of China's total primary PM2.5, BC and OC emissions respectively in 2005 (Lei et al., 2011). These emissions have serious consequences for household air pollution, ambient air quality, tropospheric ozone formation, and the resulting population health and climate impacts. This paper presents initial findings from the modeling component of a multi-disciplinary energy intervention study currently being conducted in Sichuan, China. The purpose of this effort is to quantify the impact of residential cooking and heating emissions on regional air quality and human health. Simulations with varying levels of residential emissions have been carried out for the whole of 2014 using the Weather Research and Forecasting model with Chemistry (WRF-Chem), a fully-coupled, "online" regional chemical transport model. Model output is evaluated against surface air quality measurements across China and compared with seasonal (winter and summer) ambient air pollution measurements conducted at the Sichuan study site in 2014. The model output is applied to available exposure—response relationships between PM2.5 and cardiopulmonary health outcomes. The sensitivity in different regions across China to the different cookstove emission scenarios and seasonality of impacts are presented. By estimating the mortality and disease burden risk attributable to residential emissions we demonstrate the potential benefits from large-scale energy interventions. Lei Y, Zhang Q, He KB, Streets DG. 2011. Primary anthropogenic aerosol emission trends for China, 1990-2005. Atmos. Chem. Phys. 11:931-954.

  2. The Impact of Future Emissions Changes on Air Pollution Concentrations and Related Human Health Effects

    NASA Astrophysics Data System (ADS)

    Mikolajczyk, U.; Suppan, P.; Williams, M.

    2015-12-01

    Quantification of potential health benefits of reductions in air pollution on the local scale is becoming increasingly important. The aim of this study is to conduct health impact assessment (HIA) by utilizing regionally and spatially specific data in order to assess the influence of future emission scenarios on human health. In the first stage of this investigation, a modeling study was carried out using the Weather Research and Forecasting (WRF) model coupled with Chemistry to estimate ambient concentrations of air pollutants for the baseline year 2009, and for the future emission scenarios in southern Germany. Anthropogenic emissions for the baseline year 2009 are derived from the emission inventory provided by the Netherlands Organization of Applied Scientific Research (TNO) (Denier van der Gon et al., 2010). For Germany, the TNO emissions were replaced by gridded emission data with a high spatial resolution of 1/64 x 1/64 degrees. Future air quality simulations are carried out under different emission scenarios, which reflect possible energy and climate measures in year 2030. The model set-up included a nesting approach, where three domains with horizontal resolution of 18 km, 6 km and 2 km were defined. The simulation results for the baseline year 2009 are used to quantify present-day health burdens. Concentration-response functions (CRFs) for PM2.5 and NO2 from the WHO Health risks of air Pollution in Europe (HRAPIE) project were applied to population-weighted mean concentrations to estimate relative risks and hence to determine numbers of attributable deaths and associated life-years lost. In the next step, future health impacts of projected concentrations were calculated taking into account different emissions scenarios. The health benefits that we assume with air pollution reductions can be used to provide options for future policy decisions to protect public health.

  3. Characterization of process air emissions in automotive production plants.

    PubMed

    D'Arcy, J B; Dasch, J M; Gundrum, A B; Rivera, J L; Johnson, J H; Carlson, D H; Sutherland, J W

    2016-01-01

    During manufacturing, particles produced from industrial processes become airborne. These airborne emissions represent a challenge from an industrial hygiene and environmental standpoint. A study was undertaken to characterize the particles associated with a variety of manufacturing processes found in the auto industry. Air particulates were collected in five automotive plants covering ten manufacturing processes in the areas of casting, machining, heat treatment and assembly. Collection procedures provided information on air concentration, size distribution, and chemical composition of the airborne particulate matter for each process and insight into the physical and chemical processes that created those particles.

  4. Apparatus and method for burning a lean, premixed fuel/air mixture with low NOx emission

    DOEpatents

    Kostiuk, Larry W.; Cheng, Robert K.

    1996-01-01

    An apparatus for enabling a burner to stably burn a lean fuel/air mixture. The burner directs the lean fuel/air mixture in a stream. The apparatus comprises an annular flame stabilizer; and a device for mounting the flame stabilizer in the fuel/air mixture stream. The burner may include a body having an internal bore, in which case, the annular flame stabilizer is shaped to conform to the cross-sectional shape of the bore, is spaced from the bore by a distance greater than about 0.5 mm, and the mounting device mounts the flame stabilizer in the bore. An apparatus for burning a gaseous fuel with low NOx emissions comprises a device for premixing air with the fuel to provide a lean fuel/air mixture; a nozzle having an internal bore through which the lean fuel/air mixture passes in a stream; and a flame stabilizer mounted in the stream of the lean fuel/air mixture. The flame stabilizer may be mounted in the internal bore, in which case, it is shaped and is spaced from the bore as just described. In a method of burning a lean fuel/air mixture, a lean fuel/air mixture is provided, and is directed in a stream; an annular eddy is created in the stream of the lean fuel/air mixture; and the lean fuel/air mixture is ignited at the eddy.

  5. Supercontinuum Emission from Focused Femtosecond Laser Pulses in Air

    NASA Astrophysics Data System (ADS)

    Sreeja, S.; Rao, S. Venugopal; Bagchi, Suman; Sreedhar, S.; Prashant, T. Shuvan; Radhakrishnan, P.; Tewari, Surya P.; Kiran, P. Prem

    2011-10-01

    We present our experimental results from the measurements of Supercontinuum emission (SCE) from air resulting from propagation of tightly focused femtosecond (40 fs) laser pulses. The effect of linearly polarized (LP) and circularly polarized (CP) light pulses on the SCE in two different external focal geometries (f/6, f/15) is presented. A considerable shift in the minimum wavelength of SCE is observed with external tighter focusing.

  6. National Emission Standards for Hazardous Air Pollutants, June 2005

    SciTech Connect

    Robert F. Grossman

    2005-06-01

    The sources of radionuclides include current and previous activities conducted on the NTS. The NTS was the primary location for testing of nuclear explosives in the Continental U.S. between 1951 and 1992. Historical testing has included (1) atmospheric testing in the 1950s and early 1960s, (2) underground testing between 1951 and 1992, and (3) open-air nuclear reactor and rocket engine testing (DOE, 1996a). No nuclear tests have been conducted since September 23,1992 (DOE, 2000), however; radionuclides remaining on the soil surface in many NTS areas after several decades of radioactive decay are re-suspended into the atmosphere at concentrations that can be detected by air sampling. Limited non-nuclear testing includes spills of hazardous materials at the Non-Proliferation Test and Evaluation Complex (formerly called the Hazardous Materials Spill Center), private technology development, aerospace and demilitarization activities, and site remediating activities. Processing of radioactive materials is limited to laboratory analyses; handling, transport, storage, and assembly of nuclear explosive devices or radioactive targets for the Joint Actinide Shock Physics Experimental Research (JASPER) gas gun; and operation of radioactive waste management sites (RWMSs) for low-level radioactive and mixed waste (DOE, 1996a). Monitoring and evaluation of the various activities conducted onsite indicate that the potential sources of offsite radiation exposure in calendar year (CY) 2004 were releases from (1) evaporation of tritiated water (HTO) from containment ponds that receive drainage water from E Tunnel in Area 12 and water pumped from wells used to characterize the aquifers at the sites of past underground nuclear tests, (2) onsite radioanalytical laboratories, (3) the Area 3 and Area 5 RWMS facilities, and (4) diffuse sources of tritium (H{sup 3}) and re-suspension of plutonium ({sup 239+240}Pu) and americium ({sup 241}Am) at the sites of past nuclear tests. The following

  7. Emissions of air toxics from coal-fired boilers: Arsenic

    SciTech Connect

    Mendelsohn, M.H.; Huang, H.S.; Livengood, C.D.

    1994-08-01

    Concerns over emissions of hazardous air pollutants (air toxics) have emerged as a major environmental issue; the authority of the US Environmental Protection Agency to regulate such pollutants has been greatly expanded through passage of the Clean Air Act Amendments of 1990. Arsenic and arsenic compounds are of concern mainly because of their generally recognized toxicity. Arsenic is also regarded as one of the trace elements in coal subject to significant vaporization. This report summarizes and evaluates available published information on the arsenic content of coals mined in the United States, on arsenic emitted in coal combustion, and on the efficacy of various environmental control technologies for controlling airborne emissions. Bituminous and lignite coals have the highest mean arsenic concentrations, with subbituminous and anthracite coals having the lowest. However, all coal types show very significant variations in arsenic concentrations. Arsenic emissions from coal combustion are not well-characterized, particularly with regard to determination of specific arsenic compounds. Variations in emission, rates of more than an order of magnitude have been reported for some boiler types. Data on the capture of arsenic by environmental control technologies are available primarily for systems with cold electrostatic precipitators, where removals of approximately 50 to 98% have been reported. Limited data for wet flue-gas-desulfurization systems show widely varying removals of from 6 to 97%. On the other hand, waste incineration plants report removals in a narrow range of from 95 to 99%. This report briefly reviews several areas of research that may lead to improvements in arsenic control for existing flue-gas-cleanup technologies and summarizes the status of analytical techniques for measuring arsenic emissions from combustion sources.

  8. Using GIS to study the health impact of air emissions

    SciTech Connect

    Dent, A.L.; Fowler, D.A.; Kaplan, B.M.; Zarus, G.M.

    1999-07-01

    Geographical Information Systems (GIS) is a fast-developing technology with an ever-increasing number of applications. Air dispersion modeling is a well-established discipline that can produce results in a spatial context. The marriage of these two application is optimal because it leverages the predictive capacity of modeling with the data management, analysis, and display capabilities of GIS. In the public health arena, exposure estimation techniques are invaluable. The utilization of air emission data, such as US EPA Toxic Release Inventory (TRI) data, and air dispersion modeling with GIS enable public health professionals to identify and define the potentially exposed population, estimate the health risk burden of that population, and determine correlations between point-based health outcome results with estimated health risk.

  9. A Prescribed Fire Emission Factors Database for Land Management and Air Quality Applications

    NASA Astrophysics Data System (ADS)

    Lincoln, E.; Hao, W.; Baker, S.; Yokelson, R. J.; Burling, I. R.; Urbanski, S. P.; Miller, W.; Weise, D. R.; Johnson, T. J.

    2010-12-01

    Prescribed fire is a significant emissions source in the U.S. and that needs to be adequately characterized in atmospheric transport/chemistry models. In addition, the Clean Air Act, its amendments, and air quality regulations require that prescribed fire managers estimate the quantity of emissions that a prescribed fire will produce. Several published papers contain a few emission factors for prescribed fire and additional results are found in unpublished documents whose quality has to be assessed. In conjunction with three research projects developing detailed new emissions data and meteorological tools to assist prescribed fire managers, the Strategic Environmental Research and Development Program (SERDP) is supporting development of a database that contains emissions information related to prescribed burning. Ultimately, this database will be available on the Internet and will contain older emissions information that has been assessed and newer emissions information that has been developed from both laboratory-scale and field measurements. The database currently contains emissions information from over 300 burns of different wildland vegetation types, including grasslands, shrublands, woodlands, forests, and tundra over much of North America. A summary of the compiled data will be presented, along with suggestions for additional categories.

  10. 76 FR 42052 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-18

    ... AGENCY 40 CFR Parts 9 and 63 RIN 2060-AO55 National Emission Standards for Hazardous Air Pollutants From... portions of the final rule amending the National Emission Standards for Hazardous Air Pollutants From...) establishes a two-stage regulatory process to address emissions of hazardous air pollutants (HAP)...

  11. 76 FR 56750 - Agency Information Collection Activities; Proposed Collection; Comment Request; Air Emissions...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-14

    ... AGENCY Agency Information Collection Activities; Proposed Collection; Comment Request; Air Emissions... submitting comments. E-mail: a-and-r-docket@epa.gov . Fax: (202) 566-1741. Mail: Air Emissions Reporting... on that basis, are authorized to implement and enforce the Air Emissions Reporting Requirements...

  12. Air toxics emissions from gas-fired engines

    SciTech Connect

    Meeks, H.N. Jr. )

    1992-07-01

    In 1190, 14 natural-gas-fired internal combustion engines (ICE's) in oilfield service were tested in Santa Barbara County, CA, to satisfy California air toxics legislation. The combustion exhaust was tested for formaldehyde, acetaldehyde, acrolein, benzene, toluene, xylences, naphthalene, and polycyclic aromatic hydrocarbons. The fuel was tested for aromatics to enable calculation of destruction efficiencies. Two-stroke and four-stroke engines were tested. Four-stroke engines ranging from 39 to 208 hp were used in pumping unit and constant load service. Emissions from four-stroke engines were unrelated to size and service. The two-stroke engines produced considerably higher emissions than the four-stroke engines. This paper reports that test results indicate natural-gas-fired ICE's produce toxic substances in small amounts. Formaldehyde and benzene dominated the toxic emission profile.

  13. Satellite Characterization of Fire Emissions of Aerosols and Gases Relevant to Air-Quality Modeling

    NASA Astrophysics Data System (ADS)

    Ichoku, C. M.; Ellison, L.; Yue, Y.; Wang, J.

    2015-12-01

    Because of the transient and widespread nature of wildfires and other types of open biomass burning, satellite remote sensing has become an indispensable technique for characterizing their smoke emissions for modeling applications, especially at regional to global scales. Fire radiative energy (FRE), whose instantaneous rate of release or fire radiative power (FRP) is measurable from space, has been found to be proportional to both the biomass consumption and emission of aerosol particulate matter. We have leveraged this relationship to generate a global, gridded smoke-aerosol emission coefficients (Ce) dataset based on FRP and aerosol optical thickness (AOT) measurements from the MODIS sensors aboard the Terra and Aqua satellites. Ce is a simple coefficient to convert FRE to smoke aerosol emissions, in the same manner as traditional emission factors are used to convert burned biomass to emissions. The first version of this Fire Energetics and Emissions Research (FEER.v1) global gridded Ce product at 1°x1° resolution is available at http://feer.gsfc.nasa.gov/. Based on published emission ratios, the FEER.v1 Ce product for total smoke aerosol has also been used to generate similar products for specific fire-emitted aerosols and gases, including those that are regulated as 'criteria pollutants' under the US Environmental Protection Agency's National Ambient Air Quality Standards (NAAQS), such as particulate matter (PM) and carbon monoxide (CO). These gridded Ce products were used in conjunction with satellite measurements of FRP to derive emissions of several smoke constituents, which were applied to WRF-Chem fully coupled meteorology-chemistry-aerosol model simulations, with promising results. In this presentation, we analyze WRF-Chem simulations of surface-level concentrations of various pollutants based on FEER.v1 emission products to illustrate their value for air-quality modeling, particularly in parts of Africa and southeast Asia where ground-based air

  14. Data Quality Objectives for Regulatory Requirements for Hazardous and Radioactive Air Emissions Sampling and Analysis

    SciTech Connect

    MULKEY, C.H.

    1999-07-06

    This document describes the results of the data quality objective (DQO) process undertaken to define data needs for state and federal requirements associated with toxic, hazardous, and/or radiological air emissions under the jurisdiction of the River Protection Project (RPP). Hereafter, this document is referred to as the Air DQO. The primary drivers for characterization under this DQO are the regulatory requirements pursuant to Washington State regulations, that may require sampling and analysis. The federal regulations concerning air emissions are incorporated into the Washington State regulations. Data needs exist for nonradioactive and radioactive waste constituents and characteristics as identified through the DQO process described in this document. The purpose is to identify current data needs for complying with regulatory drivers for the measurement of air emissions from RPP facilities in support of air permitting. These drivers include best management practices; similar analyses may have more than one regulatory driver. This document should not be used for determining overall compliance with regulations because the regulations are in constant change, and this document may not reflect the latest regulatory requirements. Regulatory requirements are also expected to change as various permits are issued. Data needs require samples for both radionuclides and nonradionuclide analytes of air emissions from tanks and stored waste containers. The collection of data is to support environmental permitting and compliance, not for health and safety issues. This document does not address health or safety regulations or requirements (those of the Occupational Safety and Health Administration or the National Institute of Occupational Safety and Health) or continuous emission monitoring systems. This DQO is applicable to all equipment, facilities, and operations under the jurisdiction of RPP that emit or have the potential to emit regulated air pollutants.

  15. Effect of air preheat temperature and oxygen concentration on flame structure and emission

    SciTech Connect

    Bolz, S.; Gupta, A.K.

    1998-07-01

    The structure of turbulent diffusion flames with highly preheated combustion air (air preheat temperature in excess of 1,150 C) has been obtained using a specially designed regenerative combustion furnace. Propane gas was used as the fuel. Data have been obtained on the global flame features, spectral emission characteristics, spatial distribution of OH, CH and C{sub 2} species, and pollutants emission from the flames. The results have been obtained for various degrees of air preheat temperatures and O{sub 2} concentration in the air. The color of the flame was found to change from yellow to blue to bluish-green to green over the range of conditions examined. In some cases a hybrid color flame was also observed. The recorded images of the flame photographs were analyzed using color-analyzing software. The results show that thermal and chemical flame behavior strongly depends on the air preheat temperature and oxygen content in the air. The flame color was found to be bluish-green or green at very high air preheat temperatures and low-oxygen concentration. However, at high oxygen concentration the flame color was yellow. The flame volume was found to increase with increase in air-preheat temperature and decrease in oxygen concentration. The flame length showed a similar behavior. The concentrations of OH, CH and C{sub 2} increased with an increase in air preheat temperatures. These species exhibited a two-stage combustion behavior at low oxygen concentration and single stage combustion behavior at high oxygen concentration in the air. Stable flames were obtained for remarkably low equivalence ratios, which would not be possible with normal combustion air. Pollutants emission, including CO{sub 2} and NO{sub x} , was much lower with highly preheated combustion air at low O{sub 2} concentration than the normal air. The results also suggest uniform flow and flame thermal characteristics with conditioned highly preheated air. Highly preheated air combustion provides much

  16. Aromatic compound emissions from municipal solid waste landfill: Emission factors and their impact on air pollution

    NASA Astrophysics Data System (ADS)

    Liu, Yanjun; Lu, Wenjing; Guo, Hanwen; Ming, Zhongyuan; Wang, Chi; Xu, Sai; Liu, Yanting; Wang, Hongtao

    2016-08-01

    Aromatic compounds (ACs) are major components of volatile organic compounds emitted from municipal solid waste (MSW) landfills. The ACs emissions from the working face of a landfill in Beijing were studied from 2014 to 2015 using a modified wind tunnel system. Emission factors (EFs) of fugitive ACs emissions from the working face of the landfill were proposed according to statistical analyses to cope with their uncertainty. And their impacts on air quality were assessed for the first time. Toluene was the dominant AC with an average emission rate of 38.8 ± 43.0 μg m-2 s-1 (at a sweeping velocity of 0.26 m s-1). An increasing trend in AC emission rates was observed from 12:00 to 18:00 and then peaked at 21:00 (314.3 μg m-2 s-1). The probability density functions (PDFs) of AC emission rates could be classified into three distributions: Gaussian, log-normal, and logistic. EFs of ACs from the working face of the landfill were proposed according to the 95th percentile cumulative emission rates and the wind effects on ACs emissions. The annual ozone formation and secondary organic aerosol formation potential caused by AC emissions from landfills in Beijing were estimated to be 8.86 × 105 kg year-1 and 3.46 × 104 kg year-1, respectively. Toluene, m + p-xylene, and 1,3,5-trimethylbenzene were the most significant contributors to air pollution. Although ACs pollutions from landfills accounts for less percentage (∼0.1%) compared with other anthropogenic sources, their fugitive emissions which cannot be controlled efficiently deserve more attention and further investigation.

  17. 77 FR 75739 - National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-21

    ... Control Technology HAP Hazardous Air Pollutants HON National Emission Standards for Organic Hazardous Air Pollutants From the Synthetic Organic Chemical Manufacturing Industry ICR Information Collection Request lb... Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing MSDS Material Safety Data...

  18. 76 FR 14839 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-18

    ... AGENCY 40 CFR Part 63 Delegation of National Emission Standards for Hazardous Air Pollutants for Source... County Air Pollution Control District AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed... national emission standards for hazardous air pollutants (NESHAP) to the Maricopa County Air...

  19. Locating and estimating air emissions from sources of styrene. Interim report

    SciTech Connect

    Campbell, D.

    1991-10-01

    To assist groups interested in inventorying air emissions of various potentially toxic substances, EPA is preparing a series of documents such as this to compile available information on sources and emission of these substances. The document deals specifically with styrene. Its intended audience includes Federal, State and local air pollution personnel and others interested in locating potential emitters of styrene and in making gross estimates of air emissions therefrom. The document presents information on: (1) the types of sources that may emit styrene; (2) process variations and release points that may be emitted within these sources; and (3) available emissions information indicating the potential for styrene releases into the air from each operation. The document is being released as an interim document pending incorporation of testing results from the U.S. EPA. The EPA is currently testing several unsaturated polyester resin fabricators who produce cultured marble bathroom fixtures. When the test results are available, the EPA will publish a final report including these data.

  20. Multipathway human health risk assessment concerning air emissions from combustion of Orimulsion fuel

    SciTech Connect

    Teaf, C.M.; Coleman, R.M.; Manning, M.J.; Covert, D.J.; Phelps, J.L.

    1995-12-31

    A multipathway human health risk assessment was conducted concerning air emissions from the combustion of Orimulsion. Exposure was considered for nearby residents who might be exposed by oral, dermal or inhalation pathways, including ingestion of analytes that may be present in meat and agricultural products from nearby areas. Occupational exposure were evaluated via the same intake pathways, except for potential ingestion of food products. Pathways included airborne exposures, deposition on crops, exposures to soils, and uptake by livestock and plants. Livestock intake included ingestion of analytes retained by plants and inhalation of soil-bound particulates. Analytes of potential concern included compounds identified as combustion products of the orimulsion fuel. Air concentrations of analytes, and the areal distribution of these concentrations resulting from stack emissions, were predicted using transport and deposition models. A worst cast scenario for air and cumulative soil concentrations was considered to represent the entire facility project lifetime (20 years) for dry deposition as well as predicted air concentrations occurring at continuous 100% facility operating capacity. Potential exposures to sulfuric acid mist and lead were shown to be much less than levels protective of human populations. Based upon the airborne emissions estimates and the deposition estimates for other constituents of interest, as well as the strongly conservative estimates of the potential for human intake, local health risks contributed from the combustion of Orimulsion fuel at the facility were judged to be negligible.

  1. Air Monitoring of Emissions from the Fukushima Daiichi Reactor

    SciTech Connect

    McNaughton, Michael; Allen, Shannon P.; Archuleta, Debra C.; Brock, Burgandy; Coronado, Melissa A.; Dewart, Jean M.; Eisele, William F. Jr.; Fuehne, David P.; Gadd, Milan S.; Green, Andrew A.; Lujan, Joan J.; MacDonell, Carolyn; Whicker, Jeffrey J.

    2012-06-12

    In response to the disasters in Japan on March 11, 2011, and the subsequent emissions from Fukushima-Daiichi, we monitored the air near Los Alamos using four air-monitoring systems: the standard AIRNET samplers, the standard rad-NESHAP samplers, the NEWNET system, and high-volume air samplers. Each of these systems has advantages and disadvantages. In combination, they provide a comprehensive set of measurements of airborne radionuclides near Los Alamos during the weeks following March 11. We report air-monitoring measurements of the fission products released from the Fukushima-Daiichi nuclear-power-plant accident in 2011. Clear gamma-spectrometry peaks were observed from Cs-134, Cs-136, Cs-137, I-131, I132, Te-132, and Te-129m. These data, together with measurements of other radionuclides, are adequate for an assessment and assure us that radionuclides from Fukushima Daiichi did not present a threat to human health at or near Los Alamos. The data demonstrate the capabilities of the Los Alamos air-monitoring systems.

  2. Economically consistent long-term scenarios for air pollutant emissions

    SciTech Connect

    Smith, Steven J.; West, Jason; Kyle, G. Page

    2011-09-08

    Pollutant emissions such as aerosols and tropospheric ozone precursors substantially influence climate. While future century-scale scenarios for these emissions have become more realistic through the inclusion of emission controls, they still potentially lack consistency between surface pollutant concentrations and regional levels of affluence. We demonstrate a methodology combining use of an integrated assessment model and a three-dimensional atmospheric chemical transport model, whereby a reference scenario is constructed by requiring consistent surface pollutant levels as a function of regional income over the 21st century. By adjusting air pollutant emission control parameters, we improve agreement between modeled PM2.5 and economic income among world regions through time; agreement for ozone is also improved but is more difficult to achieve because of the strong influence of upwind world regions. The scenario examined here was used as the basis for one of the Representative Concentration Pathway (RCP) scenarios. This analysis methodology could also be used to examine the consistency of other pollutant emission scenarios.

  3. Inventory of pesticide emissions into the air in Europe

    NASA Astrophysics Data System (ADS)

    Sarigiannis, D. A.; Kontoroupis, P.; Solomou, E. S.; Nikolaki, S.; Karabelas, A. J.

    2013-08-01

    Creation of a reliable and comprehensive emission inventory of the pesticides used in Europe is a key step towards quantitatively assessing the link between actual pesticide exposure and adverse health effects. An inventory of pesticide emissions was generated at a 1 × 1 km grid, for the year 2000. The emission model comprises three components: estimates of active substance (AS) wind drift taking into account crop type, volatilization during pesticide application and volatilization from the crop canopy. Results show that atmospheric emission of pesticides varies significantly across Europe. Different pesticide families are emitted from different parts of Europe as a function of the main crop(s) cultivated, agro-climatic conditions and production intensity. The pesticide emission inventory methodology developed herein is a valuable tool for assessing air quality in rural and peri-urban Europe, furnishing the necessary input for atmospheric modelling at different scales. Its estimates have been tested using global sensitivity and Monte Carlo analysis for uncertainty assessment and they have been validated against national and local surveys in four European countries; the results demonstrate the robustness and reliability of the inventory. The latter may therefore be readily used for exposure and health risk assessment studies targeting farmers, applicators, but also bystanders and the general population in Europe.

  4. Aircraft engine exhaust emissions and other airport-related contributions to ambient air pollution: A review

    NASA Astrophysics Data System (ADS)

    Masiol, Mauro; Harrison, Roy M.

    2014-10-01

    Civil aviation is fast-growing (about +5% every year), mainly driven by the developing economies and globalisation. Its impact on the environment is heavily debated, particularly in relation to climate forcing attributed to emissions at cruising altitudes and the noise and the deterioration of air quality at ground-level due to airport operations. This latter environmental issue is of particular interest to the scientific community and policymakers, especially in relation to the breach of limit and target values for many air pollutants, mainly nitrogen oxides and particulate matter, near the busiest airports and the resulting consequences for public health. Despite the increased attention given to aircraft emissions at ground-level and air pollution in the vicinity of airports, many research gaps remain. Sources relevant to air quality include not only engine exhaust and non-exhaust emissions from aircraft, but also emissions from the units providing power to the aircraft on the ground, the traffic due to the airport ground service, maintenance work, heating facilities, fugitive vapours from refuelling operations, kitchens and restaurants for passengers and operators, intermodal transportation systems, and road traffic for transporting people and goods in and out to the airport. Many of these sources have received inadequate attention, despite their high potential for impact on air quality. This review aims to summarise the state-of-the-art research on aircraft and airport emissions and attempts to synthesise the results of studies that have addressed this issue. It also aims to describe the key characteristics of pollution, the impacts upon global and local air quality and to address the future potential of research by highlighting research needs.

  5. A search for microwave emission from cosmic ray air showers

    NASA Astrophysics Data System (ADS)

    Williams, Christopher Lee

    At the highest energies, the sources of cosmic rays should be among the most powerful extragalactic accelerators. Large observatories have revealed a flux suppression above a few 1019 eV, similar to the expected effect of the interaction of ultrahigh energy cosmic rays (UHECR) with the cosmic microwave background. The Pierre Auger Observatory has measured the largest sample of cosmic ray induced extensive air showers (EAS) at the highest energies leading to a precise measurement of the energy spectrum, hints of spatial anisotropy, and a surprising change in the chemical composition at the highest energies. To answer the question of the origin of UHECRs a larger sample of high quality data will be required to reach a statistically significant result. One of the possible techniques suggested to achieve this much larger data sample, in a cost effective way, is ultra-wide field of view microwave telescopes which would operate in an analogous way to the already successful fluorescence detection (FD) technique. Detecting EAS in microwaves could be done with 100% duty cycle and essentially no atmospheric effects. This presents many advantages over the FD which has a 10% duty cycle and requires extensive atmospheric monitoring for calibration. We have pursued both prototype detector designs and improved laboratory measurements, the results of which are reported herein, and published in (Alvarez-Muniz et al., 2013; Alvarez-Muniz et al., 2012a; Williams et al., 2013; Alvarez-Muniz et al., 2013). The Microwave Detection of Air Showers (MIDAS) experiment is the first ultra-wide field of view imaging telescope deployed to detect isotropic microwave emission from EAS. With 61 days of livetime data operating on the University of Chicago campus we were able to set new limits on isotropic microwave emission from extensive air showers. The new limits rule out current laboratory air plasma measurements (Gorham et al., 2008) by more than five sigma. The MIDAS experiment continues to

  6. Mobile Laboratory Measurements of On-Road Vehicle Air Toxics Emissions in Mexico City

    NASA Astrophysics Data System (ADS)

    Kolb, C. E.; Herndon, S. C.; Zavala, M.; Knighton, B.; Marr, L. C.; Zahniser, M. S.; Jayne, J. T.; Shorter, J. H.; Onasch, T. B.; Canagaratna, M. R.; Worsnop, D. R.; Molina, L. T.; Molina, M. J.

    2004-12-01

    The direct emission of toxic organic pollutants from mobile sources is an issue of growing concern. The U.S. Environmental Protection Agency (EPA) and the Federal Highway Administration (FHWA) have identified formaldehyde, acetaldehyde, benzene, acrolein, 1.3 butadiene, and diesel particulate matter (PM), including associated organic compounds, as mobile emissions of priority concern. Real-time trace gas and fine PM sensors deployed on the Aerodyne Research Mobile Laboratory have been used to characterize both fleet average and individual vehicle class on-road emissions of formaldehyde, acetaldehyde, benzene, and diesel particulate matter (PM), including associated organic compounds in the Mexico City Metropolitan Area (MCMA). Data for these air toxics emissions will be reviewed and compared to similar data taken in Boston and New York City, where available. The prospects for future on-road real-time monitoring of acroleinand1.3 butadiene will be discussed.

  7. Global emissions of trace gases, particulate matter, and hazardous air pollutants from open burning of domestic waste

    EPA Science Inventory

    The open burning of waste, whether at individual residences, businesses, or dump sites, is a large source of air pollutants. These emissions, however, are not included in many current emission inventories used in chemistry and climate modeling applications. This paper presents th...

  8. Greenhouse gas emissions for refrigerant choices in room air conditioner units.

    PubMed

    Galka, Michael D; Lownsbury, James M; Blowers, Paul

    2012-12-01

    In this work, potential replacement refrigerants for window-mounted room air conditioners (RACs) in the U.S. have been evaluated using a greenhouse gas (GHG) emissions analysis. CO(2)-equivalent emissions for several hydrofluoroethers (HFEs) and other potential replacements were compared to the most widely used refrigerants today. Included in this comparison are pure refrigerants that make up a number of hydrofluorocarbon (HFC) mixtures, pure hydrocarbons, and historically used refrigerants such as propane and ammonia. GHG emissions from direct and indirect sources were considered in this thermodynamic analysis. Propylene, dimethyl ether, ammonia, R-152a, propane, and HFE-152a all performed effectively in a 1 ton window unit and produced slightly lower emissions than the currently used R-22 and R-134a. The results suggest that regulation of HFCs in this application would have some effect on reducing emissions since end-of-life emissions remain at 55% of total refrigerant charge despite EPA regulations that mandate 80% recovery. Even so, offsite emissions due to energy generation dominate over direct GHG emissions and all the refrigerants perform similarly in totals of indirect GHG emissions. PMID:23136858

  9. Compilation and application of Japanese inventories for energy consumption and air pollutant emissions using input-output tables.

    PubMed

    Nansai, Keisuke; Moriguchi, Yuichi; Tohno, Susumu

    2003-05-01

    Preparing emission inventories is essential to the assessment and management of our environment. In this study, Japanese air pollutant emissions, energy consumption, and CO2 emissions categorized by approximately 400 sectors (as classified by Japanese input-output tables in 1995) were estimated, and the contributions of each sector to the total amounts were analyzed. The air pollutants examined were nitrogen oxides (NOx), sulfur oxides (SOx), and suspended particulate matter (SPM). Consumptions of about 20 fossil fuels and five other fuels were estimated according to sector. Air pollutant emission factors for stationary sources were calculated from the results of a survey on air pollution prevention in Japan. Pollutant emissions from mobile sources were estimated taking into consideration vehicle types, traveling speeds, and distances. This work also counted energy supply and emissions from seven nonfossil fuel sources, including nonthermal electric power, and CO2 emissions from limestone (for example, during cement production). The total energy consumption in 1995 was concluded to be 18.3 EJ, and the annual total emissions of CO2, NOx, SOx, and SPM were, respectively, 343 Mt-C, 3.51 Mt, 1.87 Mt, and 0.32 Mt. An input-output analysis of the emission inventories was used to calculate the amounts of energy consumption and emissions induced in each sector by the economic final demand. PMID:12775078

  10. HVAC systems as emission sources affecting indoor air quality: A critical review. Final report, September 1993-June 1994

    SciTech Connect

    Batterman, S.; Burge, H.

    1995-02-01

    The study evaluates heating, ventilating and air conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). Various literature sources and methods for characterizing HVAC emission sources are reviewed. Available methods include in situ tests, longitudinal and cross-sectional studies, and laboratory studies. Based on the available literature, several HVAC components are cited fairly frequently as emission sources, and there is broad agreement regarding their significance. IAQ problems appear to be exacerbated by dust accumulation and by the presence of fibrous insulation. Other problems include entrainment, migration, and infiltration of indoor and outdoor contaminants that are distributed to indoor spaces by the HVAC system.

  11. Overview of Megacity Air Pollutant Emissions and Impacts

    NASA Astrophysics Data System (ADS)

    Kolb, C. E.

    2013-05-01

    The urban metabolism that characterizes major cities consumes very large qualities of humanly produced and/or processed food, fuel, water, electricity, construction materials and manufactured goods, as well as, naturally provided sunlight, precipitation and atmospheric oxygen. The resulting urban respiration exhalations add large quantities of trace gas and particulate matter pollutants to urban atmospheres. Key classes of urban primary air pollutants and their sources will be reviewed and important secondary pollutants identified. The impacts of these pollutants on urban and downwind regional inhabitants, ecosystems, and climate will be discussed. Challenges in quantifying the temporally and spatially resolved urban air pollutant emissions and secondary pollutant production rates will be identified and possible measurement strategies evaluated.

  12. 76 FR 175 - Faurecia Emissions Control Technologies Including On-Site Leased Workers From Adecco Employment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-03

    ... Control Technologies, including on-site leased workers from Adecco Employment Services and Emcon... Employment and Training Administration TA-W-73,609 Faurecia Emissions Control Technologies Including On-Site Leased Workers From Adecco Employment Servcies and Emcon Technologies, Troy, MI; Amended...

  13. Effect of fuel-air-ratio nonuniformity on emissions of nitrogen oxides

    NASA Technical Reports Server (NTRS)

    Lyons, V. J.

    1981-01-01

    The inlet fuel-air ratio nonuniformity is studied to deterine how nitrogen oxide (NOx) emissions are affected. An increase in NOx emissions with increased fuel-air ratio nonuniformity for average equivalence ratios less than 0.7 and a decrease in NOx emissions for average equivalence ratios near stoichiometric is predicted. The degree of uniformityy of fuel-air ratio profiles that is necessary to achieve NOx emissions goals for actual engines that use lean, premixed, prevaporized combustion systems is determined.

  14. National emission standards for hazardous air pollutants submittal -- 1996

    SciTech Connect

    Townsend, Y.E.; Black, S.C.

    1997-06-01

    The Nevada Test Site (NTS) is operated by the US Department of Energy, Nevada Operations Office (DOE/NV) as the site for nuclear weapons testing. Monitoring and evaluation of the various activities conducted onsite indicate that the potential sources of offsite radiation exposure in 1996 were releases from the following: evaporation of tritiated water from containment ponds that receive drainage from E tunnel and from wells used for site characterization studies; onsite radioanalytical laboratories; the Area 5 RWMS facility; and diffuse sources of tritium and resuspension of plutonium. Section 1 describes these sources on the NTS. Section 2 tabulates the air emissions data for the NTS. These data are used to calculate the effective dose equivalents to offsite residents. Appendices describe the methods used to determine the emissions from the sources listed.

  15. Considerations on the radio emission from extended air showers

    NASA Astrophysics Data System (ADS)

    Conti, E.; Sartori, G.

    2016-05-01

    The process of radio emission from extended air showers produced by high energy cosmic rays has reached a good level of comprehension and prediction. It has a coherent nature, so the emitted power scales quadratically with the energy of the primary particle. Recently, a laboratory measurement has revealed that an incoherent radiation mechanism exists, namely, the bremsstrahlung emission. In this paper we expound why bremsstrahlung radiation, that should be present in showers produced by ultra high energy cosmic rays, has escaped detection so far, and why, on the other side, it could be exploited, in the 1-10 GHz frequency range, to detect astronomical γ-rays. We propose an experimental scheme to verify such hypothesis, which, if correct, would deeply impact on the observational γ-ray astronomy.

  16. Emissions of air pollutants from indoor charcoal barbecue.

    PubMed

    Huang, Hsiao-Lin; Lee, Whei-May Grace; Wu, Feng-Shu

    2016-01-25

    Ten types of commercial charcoal commonly used in Taiwan were investigated to study the potential health effects of air pollutants generated during charcoal combustion in barbecue restaurants. The charcoal samples were combusted in a tubular high-temperature furnace to simulate the high-temperature charcoal combustion in barbecue restaurants. The results indicated that traditional charcoal has higher heating value than green synthetic charcoal. The amount of PM10 and PM2.5 emitted during the smoldering stage increased when the burning temperature was raised. The EF for CO and CO2 fell within the range of 68-300 and 644-1225 g/kg, respectively. Among the charcoals, the lowest EF for PM2.5 and PM10 were found in Binchōtan (B1). Sawdust briquette charcoal (I1S) emitted the smallest amount of carbonyl compounds. Charcoal briquettes (C2S) emitted the largest amount of air pollutants during burning, with the EF for HC, PM2.5, PM10, formaldehyde, and acetaldehyde being the highest among the charcoals studied. The emission of PM2.5, PM10, formaldehyde, and acetaldehyde were 5-10 times those of the second highest charcoal. The results suggest that the adverse effects of the large amounts of air pollutants generated during indoor charcoal combustion on health and indoor air quality must not be ignored.

  17. Wind Energy and Air Emission Reduction Benefits: A Primer

    SciTech Connect

    Jacobson, D.; High, C.

    2008-02-01

    This document provides a summary of the impact of wind energy development on various air pollutants for a general audience. The core document addresses the key facts relating to the analysis of emission reductions from wind energy development. It is intended for use by a wide variety of parties with an interest in this issue, ranging from state environmental officials to renewable energy stakeholders. The appendices provide basic background information for the general reader, as well as detailed information for those seeking a more in-depth discussion of various topics.

  18. 1999 INEEL National Emission Standards for Hazardous Air Pollutants - Radionuclides

    SciTech Connect

    J. W. Tkachyk

    2000-06-01

    Under Section 61.94 of Title 40, Code of Federal Regulations (CFR), Part 61, Subpart H, ''National Emission Standards for Emission of Radionuclides Other Than Radon From Department of Energy Facilities,'' each Department of Energy (DOE) facility must submit an annual report documenting compliance. This report addresses the Section 61.94 reporting requirements for operations at the Idaho National Engineering and Environmental Laboratory (INEEL) for calendar year (CY) 1999. The Idaho Operations Office of the DOE is the primary contract concerning compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAPs) at the INEEL. For CY 1999, airborne radionuclide emissions from the INEEL operations were calculated to result in a maximum individual dose to a member of the public of 7.92E-03 mrem (7.92E-08 Sievert). This effective dose equivalent (EDE) is well below the 40 CFR 61, Subpart H, regulatory standard of 10 mrem per year (1.0E-04 Sievert per year).

  19. 1998 INEEL National Emission Standard for Hazardous Air Pollutants - Radionuclides

    SciTech Connect

    J. W. Tkachyk

    1999-06-01

    Under Section 61.94 of Title 40, Code of Federal Regulations (CFR), Part 61, Subpart H, ''National Emission Standards for Emission of Radionuclides Other Than Radon From Department of Energy Facilities,'' each Department of Energy (DOE) facility must submit an annual report documenting compliance. This report addresses the Section 61.94 reporting requirements for operations at the Idaho National Engineering and Environmental Laboratory (INEEL) for calendar year (CY) 1998. The Idaho Operations Office of the DOE is the primary contract concerning compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAPs) at the INEEL. For CY 1998, airborne radionuclide emissions from the INEEL operations were calculated to result in a maximum individual dose to a member of the public of 7.92E-03 mrem (7.92E-08 Sievert). This effective dose equivalent (EDE) is well below the 40 CFR 61, Subpart H, regulatory standard of 10 mrem per year (1.0E-04 Sievert per year).

  20. Air emission control equipment - the new challenge for equpiment suppliers

    SciTech Connect

    Lobb, F.H.

    1997-12-31

    The combination of Title V, the CAM Rule and the Credible Evidence Rule demand industrial sites view the selection and operation of emission control devices in a whole new light. No longer can users see these devices as detached end of pipe pieces of equipment essentially purchased off lowest bid. These regulatory changes force plants to fully integrate the operation of these devices into their process control systems and instrumentation. And this is specifically EPA`s stated intent. EPA believes that by forcing sites to exercise the same knowledge and attention to air emissions that they do to operate their production processes, emissions will undergo a natural reduction across the country. Process and operational data that historically has been the sole province of sites becomes public. And compliance with state defined requirements must be demonstrated essentially continuously. This paper explores the new approach to compliance and provides insight through specific field examples/installations of emission control equipment. The author seeks to promote understanding through discussion of these significant regulatory changes.

  1. Understanding Potential Air Emissions from a Cellulosic Biorefinery Producing Renewable Diesel Blendstock.

    SciTech Connect

    Zhang, Yimin; Heath, Garvin A.; Renzaglia, Jason; Thomas, Mae

    2015-06-22

    The Energy Independence and Security Act of 2007, through the Renewable Fuel Standard (RFS), mandates increased use of biofuels, including cellulosic biofuels. The RFS is expected to spur the development of advanced biofuel technologies (e.g., new and innovative biofuel conversion pathways) as well as the construction of biorefineries (refineries that produce biofuels) using these technologies. To develop sustainable cellulosic biofuels, one of the goals of the Bioenergy Technologies Office (BETO) at the Department of Energy is to minimize air pollutants from the entire biofuel supply chain, as stated in their 2014 Multi-Year Program Plan (2014). Although biofuels in general have been found to have lower life cycle greenhouse gas (GHG) emissions compared to petroleum fuels on an energy basis, biomass feedstock production, harvesting, transportation, processing and conversion are expected to emit a wide range of other air pollutants (e.g., criteria air pollutants, hazardous air pollutants), which could affect the environmental benefits of biofuels when displacing petroleum fuels. While it is important for policy makers, air quality planners and regulators, biofuel developers, and investors to understand the potential implications on air quality from a growing biofuel industry, there is a general lack of information and knowledge about the type, fate and magnitude of potential air pollutant emissions from the production of cellulosic biofuels due to the nascent stage of this emerging industry. This analysis assesses potential air pollutant emissions from a hypothetical biorefinery, selected by BETO for further research and development, which uses a biological conversion process of sugars to hydrocarbons to produce infrastructural-compatible renewable diesel blendstock from cellulosic biomass.

  2. Measurement of Ozone Emission and Particle Removal Rates from Portable Air Purifiers

    ERIC Educational Resources Information Center

    Mang, Stephen A.; Walser, Maggie L.; Nizkorodov, Sergey A.; Laux, John M.

    2009-01-01

    Portable air purifiers are popular consumer items, especially in areas with poor air quality. Unfortunately, most users of these air purifiers have minimal understanding of the factors affecting their efficiency in typical indoor settings. Emission of the air pollutant ozone (O[subscript 3]) by certain air purifiers is of particular concern. In an…

  3. Effect of air temperature and relative humidity at various fuel-air ratios on exhaust emissions on a per-mode basis of an Avco Lycoming 0-320 DIAD light aircraft engine. Volume 2: Individual data points

    NASA Technical Reports Server (NTRS)

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempke, E. R.

    1976-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions included carburetor lean-out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel-air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity. Volume II contains the data taken at each of the individual test points.

  4. Effect of Air Temperature and Relative Humidity at Various Fuel-Air Ratios on Exhaust Emissions on a Per-Mode Basis of an AVCO Lycoming 0-320 Diad Light Aircraft Engine: Volume 1: Results and Plotted Data

    NASA Technical Reports Server (NTRS)

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempe, E. E., Jr.

    1978-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions include carburetor lean out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity.

  5. Analysis of effect of flameholder characteristics on lean, premixed, partially vaporized fuel-air mixtures quality and nitrogen oxides emissions

    NASA Technical Reports Server (NTRS)

    Cooper, L. P.

    1981-01-01

    An analysis was conducted of the effect of flameholding devices on the precombustion fuel-air characteristics and on oxides of nitrogen (NOx) emissions for combustion of premixed partially vaporized mixtures. The analysis includes the interrelationships of flameholder droplet collection efficiency, reatomization efficiency and blockage, and the initial droplet size distribution and accounts for the contribution of droplet combustion in partially vaporized mixtures to NOx emissions. Application of the analytical procedures is illustrated and parametric predictions of NOx emissions are presented.

  6. Dynamic Evaluation of Regional Air Quality Model's Response to Emission Reductions in the Presence of Uncertain Emission Inventories

    EPA Science Inventory

    A method is presented and applied for evaluating an air quality model’s changes in pollutant concentrations stemming from changes in emissions while explicitly accounting for the uncertainties in the base emission inventory. Specifically, the Community Multiscale Air Quality (CMA...

  7. Nitrous oxide emissions from crop rotations including wheat, oilseed rape and dry peas

    NASA Astrophysics Data System (ADS)

    Jeuffroy, M. H.; Baranger, E.; Carrouée, B.; de Chezelles, E.; Gosme, M.; Hénault, C.; Schneider, A.; Cellier, P.

    2013-03-01

    Approximately 65% of anthropogenic emissions of N2O, a potent greenhouse gas (GHG), originate from soils at a global scale, and particularly after N fertilisation of the main crops in Europe. Thanks to their capacity to fix atmospheric N2 through biological fixation, legumes can reduce N fertilizer use, and possibly N2O emissions. Nevertheless, the decomposition of crop organic matter during the crop cycle and residue decomposition, and possibly the N fixation process itself, could lead to N2O emissions. The objective of this study was to quantify N2O emissions from a dry pea crop (Pisum sativum, harvested at maturity) and from the subsequent crops in comparison with N2O emissions from wheat and oilseed rape crops, fertilized or not, in various rotations. A field experiment was conducted over 4 consecutive years to compare the emissions during the pea crop, in comparison with those during the wheat (fertilized or not) or oilseed rape crops, and after the pea crop, in comparison with other preceding crops. N2O fluxes were measured using static chambers. In spite of low N2O fluxes, mainly due to the site's soil characteristics, fluxes during the crop were significantly lower for pea and unfertilized wheat than for fertilized wheat and oilseed rape. The effect of the preceding crop was not significant, while soil mineral N at harvest was higher after the pea crop. These results should be confirmed over a wider range of soil types. Nevertheless, they demonstrate the absence of N2O emissions linked to the symbiotic N fixation process, and allow us to estimate the decrease in N2O emissions by 20-25% through including one pea crop in a three-year rotation. On a larger scale, this reduction of GHG emissions at field level has to be added to the decrease due to the reduced production and transport of the N fertilizer not applied to the pea crop.

  8. Development of an air emissions inventory for Oak Ridge National Laboratory

    SciTech Connect

    Skipper, D.D.

    1996-08-01

    Accurate air emissions inventory is important in an effective Clean Air Act (CAA) compliance program; without it, a facility may have difficulty proving compliance with regulations or permit conditions. An emissions inventory can also serve for evaluating the applicability of new regulations (eg, Title V of CAA) and in complying with them. Therefore it is important for the inventory to be well-planned and comprehensive. Preparation of an emissions inventory for a large R&D facility such as ORNL can be a challenging task. ORNL, a government facility managed by Lockheed Martin Energy Research Corp. for US DOE, consists of more than 300 buildings on about 1,500 acres. It has several thousand diverse emission sources, including small laboratory hoods, several wastewater treatment facilities, and a steam plant. This paper describes the development of ORNL`s emissions inventory with emphasis on setting goals and identifying the scope of the inventory, identifying the emission points, developing/implementing the inventory methodology, compiling data, and evaluating the results.

  9. Urban scale air quality modelling using detailed traffic emissions estimates

    NASA Astrophysics Data System (ADS)

    Borrego, C.; Amorim, J. H.; Tchepel, O.; Dias, D.; Rafael, S.; Sá, E.; Pimentel, C.; Fontes, T.; Fernandes, P.; Pereira, S. R.; Bandeira, J. M.; Coelho, M. C.

    2016-04-01

    The atmospheric dispersion of NOx and PM10 was simulated with a second generation Gaussian model over a medium-size south-European city. Microscopic traffic models calibrated with GPS data were used to derive typical driving cycles for each road link, while instantaneous emissions were estimated applying a combined Vehicle Specific Power/Co-operative Programme for Monitoring and Evaluation of the Long-range Transmission of Air Pollutants in Europe (VSP/EMEP) methodology. Site-specific background concentrations were estimated using time series analysis and a low-pass filter applied to local observations. Air quality modelling results are compared against measurements at two locations for a 1 week period. 78% of the results are within a factor of two of the observations for 1-h average concentrations, increasing to 94% for daily averages. Correlation significantly improves when background is added, with an average of 0.89 for the 24 h record. The results highlight the potential of detailed traffic and instantaneous exhaust emissions estimates, together with filtered urban background, to provide accurate input data to Gaussian models applied at the urban scale.

  10. Emissions of air toxics from a simulated charcoal kiln. Final report, October 1997--September 1998

    SciTech Connect

    Lemieux, P.M.

    1999-06-01

    The report gives results of experiments in a laboratory-scale charcoal kiln simulator to evaluate emissions of hazardous air pollutants from the production of charcoal in Missouri-type kilns. Fixed combustion gases were measured using continuous monitors. In addition, other pollutants, including methanol, volatile organic compounds, semivolatile organic compounds, and particle emission rates and size distributions were measured using various techniques. Emissions of all pollutants are reported in units of grams emitted per unit mass of initial wood converted to charcoal. Two burn conditions--slow and fast--were examined. High levels of methanol, benzene, and fine particulate were emitted in all tests. The estimated emissions from the fast burn conditions were significantly higher than those from the slow burn conditions.

  11. Emissions of air toxics from the production of charcoal in a simulated Missouri charcoal kiln

    SciTech Connect

    Lemieux, P.M.; Kariher, P.H.; Fairless, B.J.; Tapp, J.A.

    1998-11-01

    The paper gives results of experiments in a laboratory-scale charcoal kiln simulator to evaluate emissions of hazardous air pollutant from the production of charcoal in Missouri-type kilns. Fixed combustion gases were measured using continuous monitors. In addition, other pollutants, including methanol, volatile organic compounds, semivolatile organic compounds, and particle emission rates and size distributions were measured using various techniques. Emissions of all pollutants are reported in grams emitted per unit mass of initial wood converted to charcoal. Two burn conditions--slow and fast burn--were examined. High levels of methanol, benzene, and fine particulate were emitted from all tests. The estimated emissions from the fast burn conditions were significantly higher than those from the slow burn conditions.

  12. Air emissions from Wagerup alumina refinery and community symptoms: an environmental case study.

    PubMed

    Donoghue, A Michael; Cullen, Mark R

    2007-09-01

    Commissioning of a liquor burner at Wagerup alumina refinery gave rise to complaints of malodor and irritation among employees. Subsequently, community members complained about odor and various health issues. Some employees and community members were diagnosed by general practitioners as having multiple chemical sensitivity. After implementation of emission controls, the situation improved; however, community concerns lingered. This paper describes this experience and summarizes several recent investigations including air dispersion modeling, health risk assessment, ambient air quality monitoring, and complaints analyses. It is concluded that refinery emissions currently present negligible risks of acute or chronic health effects including cancer. Communication of these findings has been generally well received, but modifying the perception of risk among some elements of the community has been difficult. Organizations need to effectively address both technical and perception of risk issues.

  13. Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region

    PubMed Central

    Oikawa, P. Y.; Ge, C.; Wang, J.; Eberwein, J. R.; Liang, L. L.; Allsman, L. A.; Grantz, D. A.; Jenerette, G. D.

    2015-01-01

    Fertilized soils have large potential for production of soil nitrogen oxide (NOx=NO+NO2), however these emissions are difficult to predict in high-temperature environments. Understanding these emissions may improve air quality modelling as NOx contributes to formation of tropospheric ozone (O3), a powerful air pollutant. Here we identify the environmental and management factors that regulate soil NOx emissions in a high-temperature agricultural region of California. We also investigate whether soil NOx emissions are capable of influencing regional air quality. We report some of the highest soil NOx emissions ever observed. Emissions vary nonlinearly with fertilization, temperature and soil moisture. We find that a regional air chemistry model often underestimates soil NOx emissions and NOx at the surface and in the troposphere. Adjusting the model to match NOx observations leads to elevated tropospheric O3. Our results suggest management can greatly reduce soil NOx emissions, thereby improving air quality. PMID:26556236

  14. Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region.

    PubMed

    Oikawa, P Y; Ge, C; Wang, J; Eberwein, J R; Liang, L L; Allsman, L A; Grantz, D A; Jenerette, G D

    2015-01-01

    Fertilized soils have large potential for production of soil nitrogen oxide (NOx=NO+NO2), however these emissions are difficult to predict in high-temperature environments. Understanding these emissions may improve air quality modelling as NOx contributes to formation of tropospheric ozone (O3), a powerful air pollutant. Here we identify the environmental and management factors that regulate soil NOx emissions in a high-temperature agricultural region of California. We also investigate whether soil NOx emissions are capable of influencing regional air quality. We report some of the highest soil NOx emissions ever observed. Emissions vary nonlinearly with fertilization, temperature and soil moisture. We find that a regional air chemistry model often underestimates soil NOx emissions and NOx at the surface and in the troposphere. Adjusting the model to match NOx observations leads to elevated tropospheric O3. Our results suggest management can greatly reduce soil NOx emissions, thereby improving air quality. PMID:26556236

  15. Unusually high soil nitrogen oxide emissions influence air quality in a high-temperature agricultural region.

    PubMed

    Oikawa, P Y; Ge, C; Wang, J; Eberwein, J R; Liang, L L; Allsman, L A; Grantz, D A; Jenerette, G D

    2015-11-10

    Fertilized soils have large potential for production of soil nitrogen oxide (NOx=NO+NO2), however these emissions are difficult to predict in high-temperature environments. Understanding these emissions may improve air quality modelling as NOx contributes to formation of tropospheric ozone (O3), a powerful air pollutant. Here we identify the environmental and management factors that regulate soil NOx emissions in a high-temperature agricultural region of California. We also investigate whether soil NOx emissions are capable of influencing regional air quality. We report some of the highest soil NOx emissions ever observed. Emissions vary nonlinearly with fertilization, temperature and soil moisture. We find that a regional air chemistry model often underestimates soil NOx emissions and NOx at the surface and in the troposphere. Adjusting the model to match NOx observations leads to elevated tropospheric O3. Our results suggest management can greatly reduce soil NOx emissions, thereby improving air quality.

  16. Impact of air traffic emissions on airport air quality. Multi-scale modeling, test bed and field measurements

    NASA Astrophysics Data System (ADS)

    Ramaroson, R.; Vuillot, F.; Durand, Y.; Courbet, B.; Janin, F.; Copalle, A.; Guin, C.; Paux, E.; Vannier, F.; Talbaut, M.; Weill, M.

    2004-12-01

    Air traffic emissions are playing a significant role in airport air quality. Engine emissions contribute to the ozone and PM formation. There is an emergence of a need to develop advanced numerical tools and airport emission databases for air pollution studies. Field monitoring at airports necessary to support model assessment is still limited in time and space. The French ONERA AIRPUR project has focused on three objectives: emission inventories; dispersion models; field measurements. Results are presented and discussed in this paper. The ground spatial distribution of LTO emissions using realistic aircraft trajectories, aircraft-engine classification by ICAO, fuel flow methodology and diurnal variations of fleet number, is presented and discussed. Exhaust species time evolution is simulated using a chemical-dispersion model. Results show high emissions of NOx during LTO, and a maximum of CO and Hydrocarbons during taxi. Depending on seasons, the NOx lifetime is varying differently; lower concentration is calculated far away from LTO emissions. Longer-lived pollutants such as ozone are formed downstream and require the use of advanced dispersion models. For this reason, two interactive models coupling the micro and the regional scales are developed and used in this work. A 3D CFD model (CEDRE) simulates the flow characteristics around buildings and the dispersion of emissions. CEDRE boundary conditions are provided by the 3D nested dispersion model MEDIUM/MM5, which includes a surface boundary layer chemistry and calculates the concentration of pollutants from the local to the airport vicinities. The CFD results show a tracer accumulation calculated downstream beside terminals, consistent with observations at some mega-airports. Sensibility studies are conducted to highlight the impact of emissions on ozone formation with MEDIUM. Results show that longer-lived species are produced downstream, their concentration depending on NOx, aromatics and VOC released by

  17. QA procedures and emissions from nonstandard sources in AQUIS, a PC-based emission inventory and air permit manager

    SciTech Connect

    Smith, A.E.; Tschanz, J.; Monarch, M.

    1996-05-01

    The Air Quality Utility Information System (AQUIS) is a database management system that operates under dBASE IV. It runs on an IBM-compatible personal computer (PC) with MS DOS 5.0 or later, 4 megabytes of memory, and 30 megabytes of disk space. AQUIS calculates emissions for both traditional and toxic pollutants and reports emissions in user-defined formats. The system was originally designed for use at 7 facilities of the Air Force Materiel Command, and now more than 50 facilities use it. Within the last two years, the system has been used in support of Title V permit applications at Department of Defense facilities. Growth in the user community, changes and additions to reference emission factor data, and changing regulatory requirements have demanded additions and enhancements to the system. These changes have ranged from adding or updating an emission factor to restructuring databases and adding new capabilities. Quality assurance (QA) procedures have been developed to ensure that emission calculations are correct even when databases are reconfigured and major changes in calculation procedures are implemented. This paper describes these QA and updating procedures. Some user facilities include light industrial operations associated with aircraft maintenance. These facilities have operations such as fiberglass and composite layup and plating operations for which standard emission factors are not available or are inadequate. In addition, generally applied procedures such as material balances may need special treatment to work in an automated environment, for example, in the use of oils and greases and when materials such as polyurethane paints react chemically during application. Some techniques used in these situations are highlighted here. To provide a framework for the main discussions, this paper begins with a description of AQUIS.

  18. Evaluation of European air quality modelled by CAMx including the volatility basis set scheme

    NASA Astrophysics Data System (ADS)

    Ciarelli, Giancarlo; Aksoyoglu, Sebnem; Crippa, Monica; Jimenez, Jose-Luis; Nemitz, Eriko; Sellegri, Karine; Äijälä, Mikko; Carbone, Samara; Mohr, Claudia; O'Dowd, Colin; Poulain, Laurent; Baltensperger, Urs; Prévôt, André S. H.

    2016-08-01

    Four periods of EMEP (European Monitoring and Evaluation Programme) intensive measurement campaigns (June 2006, January 2007, September-October 2008 and February-March 2009) were modelled using the regional air quality model CAMx with VBS (volatility basis set) approach for the first time in Europe within the framework of the EURODELTA-III model intercomparison exercise. More detailed analysis and sensitivity tests were performed for the period of February-March 2009 and June 2006 to investigate the uncertainties in emissions as well as to improve the modelling of organic aerosol (OA). Model performance for selected gas phase species and PM2.5 was evaluated using the European air quality database AirBase. Sulfur dioxide (SO2) and ozone (O3) were found to be overestimated for all the four periods, with O3 having the largest mean bias during June 2006 and January-February 2007 periods (8.9 pbb and 12.3 ppb mean biases respectively). In contrast, nitrogen dioxide (NO2) and carbon monoxide (CO) were found to be underestimated for all the four periods. CAMx reproduced both total concentrations and monthly variations of PM2.5 for all the four periods with average biases ranging from -2.1 to 1.0 µg m-3. Comparisons with AMS (aerosol mass spectrometer) measurements at different sites in Europe during February-March 2009 showed that in general the model overpredicts the inorganic aerosol fraction and underpredicts the organic one, such that the good agreement for PM2.5 is partly due to compensation of errors. The effect of the choice of VBS scheme on OA was investigated as well. Two sensitivity tests with volatility distributions based on previous chamber and ambient measurements data were performed. For February-March 2009 the chamber case reduced the total OA concentrations by about 42 % on average. In contrast, a test based on ambient measurement data increased OA concentrations by about 42 % for the same period bringing model and observations into better agreement

  19. Monitoring plan for routine organic air emissions at the Radioactive Waste Management Complex Waste Storage Facilities

    SciTech Connect

    Galloway, K.J.; Jolley, J.G.

    1994-06-01

    This monitoring plan provides the information necessary to perform routine organic air emissions monitoring at the Waste Storage Facilities located at the Transuranic Storage Area of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. The Waste Storage Facilities include both the Type I and II Waste Storage Modules. The plan implements a dual method approach where two dissimilar analytical methodologies, Open-Path Fourier Transform Infrared Spectroscopy (OP-FTIR) and ancillary SUMMA{reg_sign} canister sampling, following the US Environmental Protection Agency (EPA) analytical method TO-14, will be used to provide qualitative and quantitative volatile organic concentration data. The Open-Path Fourier Transform Infrared Spectroscopy will provide in situ, real time monitoring of volatile organic compound concentrations in the ambient air of the Waste Storage Facilities. To supplement the OP-FTIR data, air samples will be collected using SUMMA{reg_sign}, passivated, stainless steel canisters, following the EPA Method TO-14. These samples will be analyzed for volatile organic compounds with gas chromatograph/mass spectrometry analysis. The sampling strategy, procedures, and schedules are included in this monitoring plan. The development of this monitoring plan is driven by regulatory compliance to the Resource Conservation and Recovery Act, State of Idaho Toxic Air Pollutant increments, Occupational Safety and Health Administration. The various state and federal regulations address the characterization of the volatile organic compounds and the resultant ambient air emissions that may originate from facilities involved in industrial production and/or waste management activities.

  20. Background information on sources of low-level radionuclide emissions to air

    SciTech Connect

    Corbit, C.D.; Herrington, W.N.; Higby, D.P.; Stout, L.A.; Corley, J.P.

    1983-09-01

    This report provides a general description and reported emissions for eight low-level radioactive source categories, including facilties that are licensed by the Nuclear Regulatory Commission (NRC) and Agreement States, and non-Department of Energy (DOE) federal facilities. The eight categories of low-level radioactive source facilities covered by this report are: research and test reactors, accelerators, the radiopharmaceutical industry, source manufacturers, medical facilities, laboratories, naval shipyards, and low-level commercial waste disposal sites. Under each category five elements are addressed: a general description, a facility and process description, the emission control systems, a site description, and the radionuclides released to air (from routine operations).

  1. STANDARDS CONTROLLING AIR EMISSIONS FOR THE SOIL DESICCATION PILOT TEST

    SciTech Connect

    BENECKE MW

    2010-09-08

    This air emissions document supports implementation of the Treatability Test Plan for Soil Desiccation as outlined in the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DOE/RL-2007-56). Treatability testing supports evaluation of remedial technologies for technetium-99 (Tc-99) contamination in the vadose zone at sites such as the BC Cribs and Trenches. Soil desiccation has been selected as the first technology for testing because it has been recommended as a promising technology in previous Hanford Site technology evaluations and because testing of soil desiccation will provide useful information to enhance evaluation of other technologies, in particular gas-phase remediation technologies. A soil desiccation pilot test (SDPT) will evaluate the desiccation process (e.g., how the targeted interval is dried) and the long-term performance for mitigation of contaminant transport. The SDPT will dry out a moist zone contaminated by Tc-99 and nitrate that has been detected at Well 299-E13-62 (Borehole C5923). This air emissions document applies to the activities to be completed to conduct the SDPT in the 200-BC-1 operable unit located in the 200 East Area of the Hanford Site. Well 299-E13-62 is planned to be used as an injection well. This well is located between and approximately equidistant from cribs 216-B-16, 216-B-17, 216-B-18. and 216-B-19. Nitrogen gas will be pumped at approximately 300 ft{sup 3}/min into the 299-EI3-62 injection well, located approximately 12 m (39 ft) away from extraction well 299-EI3-65. The soil gas extraction rate will be approximately 150 ft{sup 3}/min. The SDPT will be conducted continuously over a period of approximately six months. The purpose of the test is to evaluate soil desiccation as a potential remedy for protecting groundwater. A conceptual depiction is provided in Figure 1. The soil desiccation process will physically dry, or evaporate, some of the water from the moist zone of interest. As such, it is

  2. 77 FR 41146 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-12

    ... AGENCY 40 CFR Part 63 Delegation of National Emission Standards for Hazardous Air Pollutants for Source.... SUMMARY: Pursuant to section 112(l) of the Clean Air Act as amended in 1990, EPA is proposing to grant delegation of specific national emission standards for hazardous air pollutants (NESHAP) to the Gila...

  3. 75 FR 8888 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-26

    ... AGENCY 40 CFR Part 63 Delegation of National Emission Standards for Hazardous Air Pollutants for Source...). ACTION: Proposed rule. SUMMARY: Pursuant to section 112(l) of the 1990 Clean Air Act, EPA granted delegation of specific national emission standards for hazardous air pollutants (NESHAP) to the...

  4. 76 FR 81327 - National Emission Standards for Hazardous Air Pollutants From the Pulp and Paper Industry

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-27

    ... Hazardous Air Pollutants From the Pulp and Paper Industry; Proposed Rule #0;#0;Federal Register / Vol. 76... Part 63 RIN 2060-AQ41 National Emission Standards for Hazardous Air Pollutants From the Pulp and Paper... proposing amendments to the national emission standards for hazardous air pollutants for the pulp and...

  5. 40 CFR 63.2850 - How do I comply with the hazardous air pollutant emission standards?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 12 2011-07-01 2009-07-01 true How do I comply with the hazardous air pollutant emission standards? 63.2850 Section 63.2850 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National...

  6. 40 CFR 63.2850 - How do I comply with the hazardous air pollutant emission standards?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true How do I comply with the hazardous air pollutant emission standards? 63.2850 Section 63.2850 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED)...

  7. 76 FR 35806 - Amendments to National Emission Standards for Hazardous Air Pollutants for Area Sources: Plating...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-20

    ... AGENCY 40 CFR Part 63 RIN 2060-AM37 Amendments to National Emission Standards for Hazardous Air...: Proposed rule. SUMMARY: On June 12, 2008, EPA issued national emission standards for control of hazardous... Air Act (CAA). In today's action, EPA is proposing to amend the national emission standards...

  8. 77 FR 8575 - National Emissions Standards for Hazardous Air Pollutants: Secondary Aluminum Production

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-14

    ... February 14, 2012 Part V Environmental Protection Agency 40 CFR Part 63 National Emissions Standards for... 63 RIN 2060-AQ40 National Emissions Standards for Hazardous Air Pollutants: Secondary Aluminum... proposing amendments to the national emissions standards for hazardous air pollutants for Secondary...

  9. A zinc-air battery and flywheel zero emission vehicle

    SciTech Connect

    Tokarz, F.; Smith, J.R.; Cooper, J.; Bender, D.; Aceves, S.

    1995-10-03

    In response to the 1990 Clean Air Act, the California Air Resources Board (CARB) developed a compliance plan known as the Low Emission Vehicle Program. An integral part of that program was a sales mandate to the top seven automobile manufacturers requiring the percentage of Zero Emission Vehicles (ZEVs) sold in California to be 2% in 1998, 5% in 2001 and 10% by 2003. Currently available ZEV technology will probably not meet customer demand for range and moderate cost. A potential option to meet the CARB mandate is to use two Lawrence Livermore National Laboratory (LLNL) technologies, namely, zinc-air refuelable batteries (ZARBs) and electromechanical batteries (EMBs, i. e., flywheels) to develop a ZEV with a 384 kilometer (240 mile) urban range. This vehicle uses a 40 kW, 70 kWh ZARB for energy storage combined with a 102 kW, 0.5 kWh EMB for power peaking. These technologies are sufficiently near-term and cost-effective to plausibly be in production by the 1999-2001 time frame for stationary and initial vehicular applications. Unlike many other ZEVs currently being developed by industry, our proposed ZEV has range, acceleration, and size consistent with larger conventional passenger vehicles available today. Our life-cycle cost projections for this technology are lower than for Pb-acid battery ZEVs. We have used our Hybrid Vehicle Evaluation Code (HVEC) to simulate the performance of the vehicle and to size the various components. The use of conservative subsystem performance parameters and the resulting vehicle performance are discussed in detail.

  10. ElectroCore separator for particulate air emissions

    SciTech Connect

    Easom, B.H.; Smolensky, L.A.; Wysk, S.R.; Altman, R.F.; Olen, K.R.

    1998-07-01

    Coal combustion in fossil energy power systems releases trace amounts of chemical elements identified in the Clean Air Act Amendments of 1990 as hazardous air pollutants (HAPs). Most HAPs exist as solid phase particulate matter and are emitted to the atmosphere in this form. To reduce the emissions of these HAPs, a novel, high efficiency particle collection system known as the ElectroCore is being developed. The concept involves placing a high efficiency particle separator downstream of an underperforming electrostatic precipitator (ESP) that strips the particles from the incoming flow and returns them, along with a small amount of recirculation flow, back to the inlet of the ESP. The main component of the system is the ElectroCore separator. Its design is based on the mechanical Core Separator developed by LSR as a high efficiency centrifugal separator. Enhancing the Core Separator by adding an electrical field improves the separation efficiency of particles in the sub-micron range which is the range where centrifugal separation is ineffective. In the combined system, the centrifugal forces operating on the particles augmented by electrostatic forces so that the ElectroCore has high separation efficiency for particles of all sizes. Field tests have shown that the ElectroCore operating downstream of an underperforming ESP can reduce the particulate emission rate to below 4.3 ng/J (0.01 lb{sub m}/million Btu) even for ESPs with emission rates as high as 260 ng/J (0.6 lb{sub m}/million Btu). The ElectroCore system can perform with most all coal ranks or residual fuel oils (RFO) and has a potentially low capital cost.

  11. Collaborative Emission Reduction Model Based on Multi-Objective Optimization for Greenhouse Gases and Air Pollutants.

    PubMed

    Meng, Qing-chun; Rong, Xiao-xia; Zhang, Yi-min; Wan, Xiao-le; Liu, Yuan-yuan; Wang, Yu-zhi

    2016-01-01

    CO2 emission influences not only global climate change but also international economic and political situations. Thus, reducing the emission of CO2, a major greenhouse gas, has become a major issue in China and around the world as regards preserving the environmental ecology. Energy consumption from coal, oil, and natural gas is primarily responsible for the production of greenhouse gases and air pollutants such as SO2 and NOX, which are the main air pollutants in China. In this study, a mathematical multi-objective optimization method was adopted to analyze the collaborative emission reduction of three kinds of gases on the basis of their common restraints in different ways of energy consumption to develop an economic, clean, and efficient scheme for energy distribution. The first part introduces the background research, the collaborative emission reduction for three kinds of gases, the multi-objective optimization, the main mathematical modeling, and the optimization method. The second part discusses the four mathematical tools utilized in this study, which include the Granger causality test to analyze the causality between air quality and pollutant emission, a function analysis to determine the quantitative relation between energy consumption and pollutant emission, a multi-objective optimization to set up the collaborative optimization model that considers energy consumption, and an optimality condition analysis for the multi-objective optimization model to design the optimal-pole algorithm and obtain an efficient collaborative reduction scheme. In the empirical analysis, the data of pollutant emission and final consumption of energies of Tianjin in 1996-2012 was employed to verify the effectiveness of the model and analyze the efficient solution and the corresponding dominant set. In the last part, several suggestions for collaborative reduction are recommended and the drawn conclusions are stated.

  12. Collaborative Emission Reduction Model Based on Multi-Objective Optimization for Greenhouse Gases and Air Pollutants

    PubMed Central

    Zhang, Yi-min; Wan, Xiao-le; Liu, Yuan-yuan; Wang, Yu-zhi

    2016-01-01

    CO2 emission influences not only global climate change but also international economic and political situations. Thus, reducing the emission of CO2, a major greenhouse gas, has become a major issue in China and around the world as regards preserving the environmental ecology. Energy consumption from coal, oil, and natural gas is primarily responsible for the production of greenhouse gases and air pollutants such as SO2 and NOX, which are the main air pollutants in China. In this study, a mathematical multi-objective optimization method was adopted to analyze the collaborative emission reduction of three kinds of gases on the basis of their common restraints in different ways of energy consumption to develop an economic, clean, and efficient scheme for energy distribution. The first part introduces the background research, the collaborative emission reduction for three kinds of gases, the multi-objective optimization, the main mathematical modeling, and the optimization method. The second part discusses the four mathematical tools utilized in this study, which include the Granger causality test to analyze the causality between air quality and pollutant emission, a function analysis to determine the quantitative relation between energy consumption and pollutant emission, a multi-objective optimization to set up the collaborative optimization model that considers energy consumption, and an optimality condition analysis for the multi-objective optimization model to design the optimal-pole algorithm and obtain an efficient collaborative reduction scheme. In the empirical analysis, the data of pollutant emission and final consumption of energies of Tianjin in 1996–2012 was employed to verify the effectiveness of the model and analyze the efficient solution and the corresponding dominant set. In the last part, several suggestions for collaborative reduction are recommended and the drawn conclusions are stated. PMID:27010658

  13. Collaborative Emission Reduction Model Based on Multi-Objective Optimization for Greenhouse Gases and Air Pollutants.

    PubMed

    Meng, Qing-chun; Rong, Xiao-xia; Zhang, Yi-min; Wan, Xiao-le; Liu, Yuan-yuan; Wang, Yu-zhi

    2016-01-01

    CO2 emission influences not only global climate change but also international economic and political situations. Thus, reducing the emission of CO2, a major greenhouse gas, has become a major issue in China and around the world as regards preserving the environmental ecology. Energy consumption from coal, oil, and natural gas is primarily responsible for the production of greenhouse gases and air pollutants such as SO2 and NOX, which are the main air pollutants in China. In this study, a mathematical multi-objective optimization method was adopted to analyze the collaborative emission reduction of three kinds of gases on the basis of their common restraints in different ways of energy consumption to develop an economic, clean, and efficient scheme for energy distribution. The first part introduces the background research, the collaborative emission reduction for three kinds of gases, the multi-objective optimization, the main mathematical modeling, and the optimization method. The second part discusses the four mathematical tools utilized in this study, which include the Granger causality test to analyze the causality between air quality and pollutant emission, a function analysis to determine the quantitative relation between energy consumption and pollutant emission, a multi-objective optimization to set up the collaborative optimization model that considers energy consumption, and an optimality condition analysis for the multi-objective optimization model to design the optimal-pole algorithm and obtain an efficient collaborative reduction scheme. In the empirical analysis, the data of pollutant emission and final consumption of energies of Tianjin in 1996-2012 was employed to verify the effectiveness of the model and analyze the efficient solution and the corresponding dominant set. In the last part, several suggestions for collaborative reduction are recommended and the drawn conclusions are stated. PMID:27010658

  14. On the long term impact of emissions from central European cities on regional air-quality

    NASA Astrophysics Data System (ADS)

    Huszar, P.; Belda, M.; Halenka, T.

    2015-11-01

    For the purpose of qualifying and quantifying the impact of urban emission from Central European cities on the present-day regional air-quality, the regional climate model RegCM4.2 was coupled with the chemistry transport model CAMx, including two-way interactions. A series of simulations was carried out for the 2001-2010 period either with all urban emissions included (base case) or without considering urban emissions. Further, the sensitivity of ozone production to urban emissions was examined by performing reduction experiments with -20 % emission perturbation of NOx and/or NMVOC. The validation of the modeling system's air-quality related outputs using AirBase and EMEP surface measurements showed satisfactory reproduction of the monthly variation for ozone (O3), nitrogen dioxide (NO2) and sulfur dioxide (SO2). In terms of hourly correlations, reasonable values are achieved for ozone (r around 0.5-0.8) and for NO2 (0.4-0.6), but SO2 is poorly or not correlated at all with measurements (r around 0.2-0.5). The modeled fine particulates (PM2.5) are usually underestimated, especially in winter, mainly due to underestimation of nitrates and carbonaceous aerosols. EC air-quality measures were chosen as metrics describing the cities emission impact on regional air pollution. Due to urban emissions, significant ozone titration occurs over cities while over rural areas remote from cities, ozone production is modeled, mainly in terms of number of exceedances and accumulated exceedances over the threshold of 40 ppbv. Urban NOx, SO2 and PM2.5 emissions also significantly contribute to concentrations in the cities themselves (up to 50-70 % for NOx and SO2, and up to 60 % for PM2.5), but the contribution is large over rural areas as well (10-20 %). Although air pollution over cities is largely determined by the local urban emissions, considerable (often a few tens of %) fraction of the concentration is attributable to other sources from rural areas and minor cities. Further

  15. Quantitative comparisons of various air pollutant emission sources of ozone precursors in East Tennessee - a study evaluated from the emission inventory development

    SciTech Connect

    Bandyopadhyay, N.

    1996-12-31

    The United States Department of the Interior has raised concerns regarding air pollution impacts in the Great Smoky Mountains National Park (GSMNP). The formation of the Southern Appalachian Mountains Initiative (SAMI) is regional effort to understand the air quality impacts of emission sources upon the Appalachian Mountains. The Tennessee Division of Air Pollution Control (TDAPC) has recently committed additional resources for the analyses of proposals for increased emissions of air pollutants in East Tennessee. The TDAPC has planned to assess these effects by conducting an air quality modeling project. The United States Environmental Protection Agency`s (US EPA`s) Urban Airshed Model (UAM) has been used as the primary air quality model for this purpose. The purpose of this project will be to evaluate the expected impact of any major new or modified air pollution source located in Tennessee on ozone in the GSMNP. An accurate emission inventory is essential to any air quality modeling analysis. A modeling inventory has been developed by the TDAPC for the base year 1993. The modeling area includes 40 counties in East and Middle Tennessee and 42 counties in neighboring states. For the counties in Tennessee, a detailed inventory of the point sources was prepared. For the other states inside the modeling domain, the EPA`s Aerometric Information Retrieval System (AIRS)-AIRS Facility Subsystem (AFS) was used to obtain point source data, The accuracy of the AFS data for the other states was not addressed, A detailed quantitative analysis has been conducted with the emission inventory developed for Tennessee counties. The purpose of this study is to quantify the relative contributions of the emissions of Volatile Organic Compounds (VOCs) and Nitrogen Oxides (NO{sub x}) from different point, area, mobile and biogenic sources to ozone formation in the vicinity of the GSMNP.

  16. Nitrous oxide emissions from crop rotations including wheat, rapeseed and dry pea

    NASA Astrophysics Data System (ADS)

    Jeuffroy, M. H.; Baranger, E.; Carrouée, B.; de Chezelles, E.; Gosme, M.; Hénault, C.; Schneider, A.; Cellier, P.

    2012-07-01

    Approximately 65% of anthropogenic emissions of N2O, a potent greenhouse gas, originate from soils at global scale, and particularly after N fertilisation of the main crops in Europe. Thanks to their capacity to fix atmospheric N2 through biological fixation, legumes allow to reduce N fertilizer use, and possibly N2O emission. Nevertheless, the decomposition of crop organic matter during the crop cycle and during the residue decomposition, and possibly the N fixation process itself, could lead to N2O emissions. The objective of this study was to quantify N2O emissions from a dry pea crop (Pisum sativum, harvested at maturity) and from the subsequent crops in comparison with N2O emissions from wheat and oilseed-rape crops, fertilized or not, in various rotations. A field experiment was conducted during 4 consecutive years, aiming at comparing the emissions during the pea crop, in comparison with those during the wheat (fertilized or not) or oilseed rape crops, and after the pea crop, in comparison with other preceding crops. N2O fluxes were measured using static chambers. In spite of low N2O fluxes, mainly linked with the site soil characteristics, fluxes during the crop were significantly lower for pea and unfertilized wheat than for fertilized wheat and oilseed rape. The effect of the preceding crop was not significant, while soil mineral N at harvest was higher after pea. These results, combined with the emission reduction allowed by the production and transport of the N fertiliser not applied on the pea crop, should be confirmed in a larger range of soil types. Nevertheless, they demonstrate the absence of N2O emission linked to the symbiotic N fixation process, and allow us to estimate the decrease of N2O emissions to 20-25% by including one pea crop in a three-year rotation. At a larger scale, this reduction of GHG emissions at field level has to be cumulated with the reduction of GHG emissions linked with the lower level of production and transport of the N

  17. Influence of future anthropogenic emissions on climate, natural emissions, and air quality

    NASA Astrophysics Data System (ADS)

    Jacobson, Mark Z.; Streets, David G.

    2009-04-01

    This study examines the effects of future anthropogenic emissions on climate, and the resulting feedback to natural emissions and air quality. Speciated sector- and region-specific 2030 emission factors were developed to produce gas and particle emission inventories that followed Special Report on Emission Scenarios (SRES) A1B and B1 emission trajectories. Current and future climate model simulations were run, in which anthropogenic emission changes affected climate, which fed back to natural emissions from lightning (NO, NO2, HONO, HNO3, N2O, H2O2, HO2, CO), soils (dust, bacteria, NO, N2O, H2, CH4, H2S, DMS, OCS, CS2), the ocean (bacteria, sea spray, DMS, N2O, H2, CH4), vegetation (pollen, spores, isoprene, monoterpenes, methanol, other VOCs), and photosynthesis/respiration. New methods were derived to calculate lightning flash rates as a function of size-resolved collisions and other physical principles and pollen, spore, and bacteria emissions. Although the B1 scenario was "cleaner" than the A1B scenario, global warming increased more in the B1 scenario because much A1B warming was masked by additional reflective aerosol particles. Thus neither scenario is entirely beneficial from a climate and health perspective, and the best control measure is to reduce warming gases and warming/cooling particles together. Lightning emissions declined by ˜3% in the B1 scenario and ˜12% in the A1B scenario as the number of ice crystals, thus charge-separating bounceoffs, decreased. Net primary production increased by ˜2% in both scenarios. Emissions of isoprene and monoterpenes increased by ˜1% in the A1B scenario and 4-5% in the B1 scenario. Near-surface ozone increased by ˜14% in the A1B scenario and ˜4% in the B1 scenario, reducing ambient isoprene in the latter case. Gases from soils increased in both scenarios due to higher temperatures. Near-surface PM2.5 mass increased by ˜2% in the A1B scenario and decreased by ˜2% in the B1 scenario. The resulting 1.4% higher

  18. National Emission Standards for Hazardous Air Pollutants Calendar Year 2005

    SciTech Connect

    Bechtel Nevada

    2006-06-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO). From 1951 through 1992, the NTS was operated as the nation’s site for nuclear weapons testing. The release of man-made radionuclides from the NTS as a result of testing activities has been monitored since the first decade of atmospheric testing. After 1962, when nuclear tests were conducted only underground, the radiation exposure to the public surrounding the NTS was greatly reduced. After the 1992 moratorium on nuclear testing, radiation monitoring on the NTS focused on detecting airborne radionuclides that are resuspended into the air (e.g., by winds, dust-devils) along with historically-contaminated soils on the NTS. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (40 Code of Federal Regulations 61 Subpart H) limits the release of radioactivity from a U. S. Department of Energy (DOE) facility (e.g., the NTS) to 10 millirem per year (mrem/yr) effective dose equivalent (EDE) to any member of the public. This is the dose limit established for someone living off of the NTS for inhaling radioactive particles that may be carried by wind off of the NTS. This limit assumes that members of the public surrounding the NTS may also inhale “background levels” or radioactive particles unrelated to NTS activities that come from naturally-occurring elements in the environment (e.g., radon gas from the earth or natural building materials) or from other man-made sources (e.g., cigarette smoke). The U. S. Environmental Protection Agency (EPA) requires DOE facilities (e.g., the NTS) to demonstrate compliance with the NESHAP dose limit by annually estimating the dose to a hypothetical member of the public, referred to as the maximally exposed individual (MEI), or the member of the public who resides within an 80-kilometer (50-mile

  19. Cyclic siloxanes in air, including identification of high levels in Chicago and distinct diurnal variation.

    PubMed

    Yucuis, Rachel A; Stanier, Charles O; Hornbuckle, Keri C

    2013-08-01

    The organosilicon compounds octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) are high production volume chemicals that are widely used in household goods and personal care products. Due to their prevalence and chemical characteristics, cyclic siloxanes are being assessed as possible persistent organic pollutants. D4, D5, and D6 were measured in indoor and outdoor air to quantify and compare siloxane concentrations and compound ratios depending on location type. Indoor air samples had a median concentration of 2200 ng m(-3) for the sum of D4, D5, and D6. Outdoor sampling locations included downtown Chicago, Cedar Rapids, IA, and West Branch, IA, and had median sum siloxane levels of 280, 73, and 29 ng m(-3) respectively. A diurnal trend is apparent in the samples taken in downtown Chicago. Nighttime samples had a median 2.7 times higher on average than daytime samples, which is due, in part, to the fluctuations of the planetary boundary layer. D5 was the dominant siloxane in both indoor and outdoor air. Ratios of D5 to D4 averaged 91 and 3.2 for indoor and outdoor air respectively.

  20. Cyclic siloxanes in air, including identification of high levels in Chicago and distinct diurnal variation

    PubMed Central

    Yucuis, Rachel A.; Stanier, Charles O.; Hornbuckle, Keri C.

    2014-01-01

    The organosilicon compounds octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) are high production volume chemicals that are widely used in household goods and personal care products. Due to their prevalence and chemical characteristics, cyclic siloxanes are being assessed as possible persistent organic pollutants. D4, D5, and D6 were measured in indoor and outdoor air to quantify and compare siloxane concentrations and compound ratios depending on location type. Indoor air samples had a median concentration of 2200 ng m−3 for the sum of D4, D5, and D6. Outdoor sampling locations included downtown Chicago, Cedar Rapids, IA, and West Branch, IA, and had median sum siloxane levels of 280, 73, and 29 ng m−3 respectively. A diurnal trend is apparent in the samples taken in downtown Chicago. Nighttime samples had a median 2.7 times higher on average than daytime samples, which is due, in part, to the fluctuations of the planetary boundary layer. D5 was the dominant siloxane in both indoor and outdoor air. Ratios of D5 to D4 averaged 91 and 3.2 for indoor and outdoor air respectively. PMID:23541357

  1. On the long-term impact of emissions from central European cities on regional air quality

    NASA Astrophysics Data System (ADS)

    Huszar, P.; Belda, M.; Halenka, T.

    2016-02-01

    For the purpose of qualifying and quantifying the impact of urban emission from Central European cities on the present-day regional air quality, the regional climate model RegCM4.2 was coupled with the chemistry transport model CAMx, including two-way interactions. A series of simulations was carried out for the 2001-2010 period either with all urban emissions included (base case) or without considering urban emissions. Further, the sensitivity of ozone production to urban emissions was examined by performing reduction experiments with -20 % emission perturbation of NOx and/or non-methane volatile organic compounds (NMVOC). The modeling system's air quality related outputs were evaluated using AirBase, and EMEP surface measurements showed reasonable reproduction of the monthly variation for ozone (O3), but the annual cycle of nitrogen dioxide (NO2) and sulfur dioxide (SO2) is more biased. In terms of hourly correlations, values achieved for ozone and NO2 are 0.5-0.8 and 0.4-0.6, but SO2 is poorly or not correlated at all with measurements (r around 0.2-0.5). The modeled fine particulates (PM2.5) are usually underestimated, especially in winter, mainly due to underestimation of nitrates and carbonaceous aerosols. European air quality measures were chosen as metrics describing the cities emission impact on regional air pollution. Due to urban emissions, significant ozone titration occurs over cities while over rural areas remote from cities, ozone production is modeled, mainly in terms of number of exceedances and accumulated exceedances over the threshold of 40 ppbv. Urban NOx, SO2 and PM2.5 emissions also significantly contribute to concentrations in the cities themselves (up to 50-70 % for NOx and SO2, and up to 60 % for PM2.5), but the contribution is large over rural areas as well (10-20 %). Although air pollution over cities is largely determined by the local urban emissions, considerable (often a few tens of %) fraction of the concentration is attributable to

  2. Impacts of Regional Climate Change on Biogenic Emissions and Air Quality

    SciTech Connect

    Zhang, Yang; Hu, X.-M.; Leung, Lai R.; Gustafson, William I.

    2008-09-25

    Regional air quality simulations are conducted for four summers (2001, 2002, 2051, and 2052) to examine the sensitivity of air quality to potential regional climate change in the U.S. In response to the predicted warmer climate in 2051/2052, emissions of isoprene and terpene increase by 20-92.1% and 20-56%, respectively, over most of the domain. Surface O3, which is sensitive to changes in temperature and solar radiation but relatively insensitive to changes in PBL height and cloud fraction, increase by up to 19-20%. PM2.5, its compositions, and visibility exhibit an overall negative sensitivity (decrease by up to 40%), resulting from the competition of the negative temperature effect and positive emission/temperature effects. While the response of dry deposition is governed by the negative sensitivity of surface resistances, that of wet deposition is either positive or negative, depending on the relative dominancy of changes in PM2.5 and precipitation. Overall the net climatic effect dominates changes in O3, PM2.5, wet and total deposition, and the net biogenic emission effect is important for isoprene, organic matter, visibility, and dry deposition over several regions. Models that do not include secondary organic aerosol formation from isoprene photooxidation may underestimate by at least 20% the air quality responses to future climate changes over many areas of the modeling domain. Both regional climate and air quality exhibit interannual variability, particularly in temperature, isoprene emissions, and PM2.5 concentrations, indicating a need for long-term simulations to predict future air quality.

  3. 30 CFR 285.659 - What requirements must I include in my SAP, COP, or GAP regarding air quality?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What requirements must I include in my SAP, COP, or GAP regarding air quality? 285.659 Section 285.659 Mineral Resources MINERALS MANAGEMENT SERVICE... must I include in my SAP, COP, or GAP regarding air quality? (a) You must comply with the Clean Air...

  4. Impact of ship emissions on air pollution and AOD over North Atlantic and European Arctic

    NASA Astrophysics Data System (ADS)

    Kaminski, Jacek W.; Struzewska, Joanna; Jefimow, Maciej; Durka, Pawel

    2016-04-01

    The iAREA project is combined of experimental and theoretical research in order to contribute to the new knowledge on the impact of absorbing aerosols on the climate system in the European Arctic (http://www.igf.fuw.edu.pl/iAREA). A tropospheric chemistry model GEM-AQ (Global Environmental Multiscale Air Quality) was used as a computational tool. The core of the model is based on a weather prediction model with environmental processes (chemistry and aerosols) implanted on-line and are interactive (i.e. providing feedback of chemistry on radiation and dynamics). The numerical grid covered the Euro-Atlantic region with the resolution of 50 km. Emissions developed by NILU in the ECLIPSE project was used (Klimont et al., 2013). The model was run for two 1-year scenarios. 2014 was chosen as a base year for simulations and analysis. Scenarios include a base run with most up-to-date emissions and a run without maritime emissions. The analysis will focus on the contribution of maritime emissions on levels of particulate matter and gaseous pollutants over the European Arctic, North Atlantic and coastal areas. The annual variability will be assessed based on monthly mean near-surface concentration fields. Analysis of shipping transport on near-surface air pollution over the Euro-Atlantic region will be assessed for ozone, NO2, SO2, CO, PM10, PM2.5. Also, a contribution of ship emissions to AOD will be analysed.

  5. Development of On-line Wildfire Emissions for the Operational Canadian Air Quality Forecast System

    NASA Astrophysics Data System (ADS)

    Pavlovic, R.; Menard, S.; Chen, J.; Anselmo, D.; Paul-Andre, B.; Gravel, S.; Moran, M. D.; Davignon, D.

    2013-12-01

    An emissions processing system has been developed to incorporate near-real-time emissions from wildfires and large prescribed burns into Environment Canada's real-time GEM-MACH air quality (AQ) forecast system. Since the GEM-MACH forecast domain covers Canada and most of the USA, including Alaska, fire location information is needed for both of these large countries. Near-real-time satellite data are obtained and processed separately for the two countries for organizational reasons. Fire location and fuel consumption data for Canada are provided by the Canadian Forest Service's Canadian Wild Fire Information System (CWFIS) while fire location and emissions data for the U.S. are provided by the SMARTFIRE (Satellite Mapping Automated Reanalysis Tool for Fire Incident Reconciliation) system via the on-line BlueSky Gateway. During AQ model runs, emissions from individual fire sources are injected into elevated model layers based on plume-rise calculations and then transport and chemistry calculations are performed. This 'on the fly' approach to the insertion of emissions provides greater flexibility since on-line meteorology is used and reduces computational overhead in emission pre-processing. An experimental wildfire version of GEM-MACH was run in real-time mode for the summers of 2012 and 2013. 48-hour forecasts were generated every 12 hours (at 00 and 12 UTC). Noticeable improvements in the AQ forecasts for PM2.5 were seen in numerous regions where fire activity was high. Case studies evaluating model performance for specific regions, computed objective scores, and subjective evaluations by AQ forecasters will be included in this presentation. Using the lessons learned from the last two summers, Environment Canada will continue to work towards the goal of incorporating near-real-time intermittent wildfire emissions within the operational air quality forecast system.

  6. Emission inventory of anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China

    NASA Astrophysics Data System (ADS)

    Huang, C.; Chen, C. H.; Li, L.; Cheng, Z.; Wang, H. L.; Huang, H. Y.; Streets, D. G.; Wang, Y. J.; Zhang, G. F.; Chen, Y. R.

    2011-05-01

    The purpose of this study is to develop an emission inventory for major anthropogenic air pollutants and VOC species in the Yangtze River Delta (YRD) region for the year 2007. A "bottom-up" methodology was adopted to compile the inventory based on major emission sources in the sixteen cities of this region. Results show that the emissions of SO2, NOx, CO, PM10, PM2.5, VOCs, and NH3 in the YRD region for the year 2007 are 2392 kt, 2293 kt, 6697 kt, 3116 kt, 1511 kt, 2767 kt, and 459 kt, respectively. Ethylene, mp-xylene, o-xylene, toluene, 1,2,4-trimethylbenzene, 2,4-dimethylpentane, ethyl benzene, propylene, 1-pentene, and isoprene are the key species contributing 77 % to the total ozone formation potential (OFP). The spatial distribution of the emissions shows the emissions and OFPs are mainly concentrated in the urban and industrial areas along the Yangtze River and around Hangzhou Bay. The industrial sources, including power plants other fuel combustion facilities, and non-combustion processes contribute about 97 %, 86 %, 89 %, 91 %, and 69 % of the total SO2, NOx, PM10, PM2.5, and VOC emissions. Vehicles take up 12.3 % and 12.4 % of the NOx and VOC emissions, respectively. Regarding OFPs, the chemical industry, domestic use of paint & printing, and gasoline vehicles contribute 38 %, 24 %, and 12 % to the ozone formation in the YRD region.

  7. IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGEMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    EPA Science Inventory

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  8. IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    EPA Science Inventory

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  9. (AWMA) IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGEMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    EPA Science Inventory

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  10. AIR EMISSIONS FROM RESIDENTIAL HEATING: THE WOOD HEATING OPTION PUT INTO ENVIRONMENTAL PERSPECTIVE

    EPA Science Inventory

    The paper compares the national scale (rather than local) air quality impacts of the various residential space heating options. Specifically, it compares the relative contribution of the space heating options to fine particulate emissions, greenhouse gas emissions, and acid preci...

  11. 76 FR 20536 - Protocol Gas Verification Program and Minimum Competency Requirements for Air Emission Testing

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-13

    ... for Air Emission Testing Correction In rule document 2011-6216 appearing on pages 17288-17325 in the... heading of Appendix D is corrected to read: ] Appendix D to Part 75--Optional SO 2 Emissions Data...

  12. Evaluation and quantification of the impact of cooling tower emissions on indoor air quality

    SciTech Connect

    Vanderheyden, M.D.; Schuyler, G.D.

    1994-12-31

    Assessment of the potential impact of outdoor pollutant sources on indoor air quality through the reentrainment of pollutants vis-a-vis air-handling units, doorways, and windows has mainly focused on the evaluation of fume hood, boiler, diesel generator, and vehicular pollutant emissions. In recent years, however, gaseous and waterborne pollutants emitted from cooling towers have become an increasing source of concern. Chemicals such as biocides and corrosion and scale inhibitors are used to reduce and/or eliminate algae blooms, decrease bacterial and fungal growth, and reduce the corrosion of equipment. When added to the water used in cooling towers, these chemicals are emitted in both the gaseous phase and as pollutants dissolved in or suspended in water droplets. A qualitative evaluation of exhaust dispersion and droplet deposition rates associated with cooling towers is necessary when conducting an overall review of the environmental impact on indoor air quality. This paper identifies source emission rates to be used in assessing emissions of chemical additives in cooling towers, presents provisional design criteria for evaluating the impact of the chemical additives, and evaluates alternative methodologies for quantifying impact concentrations. These alternative assessment methodologies include numerical models, physical wind tunnel simulations, and computational fluid dynamics (CFD) simulations. Parameters used in comparing the methodologies include relative accuracy (order of magnitude) and modeling and simulation limitations.

  13. 40 CFR 60.2250 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... air curtain incinerators? 60.2250 Section 60.2250 Protection of Environment ENVIRONMENTAL PROTECTION... 1, 2001 Air Curtain Incinerators § 60.2250 What are the emission limitations for air curtain incinerators? (a) Within 60 days after your air curtain incinerator reaches the charge rate at which it...

  14. 40 CFR 60.2250 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... air curtain incinerators? 60.2250 Section 60.2250 Protection of Environment ENVIRONMENTAL PROTECTION... 1, 2001 Air Curtain Incinerators § 60.2250 What are the emission limitations for air curtain incinerators? (a) Within 60 days after your air curtain incinerator reaches the charge rate at which it...

  15. 40 CFR 60.2250 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... air curtain incinerators? 60.2250 Section 60.2250 Protection of Environment ENVIRONMENTAL PROTECTION... 1, 2001 Air Curtain Incinerators § 60.2250 What are the emission limitations for air curtain incinerators? (a) Within 60 days after your air curtain incinerator reaches the charge rate at which it...

  16. Should Title 24 Ventilation Requirements Be Amended to include an Indoor Air Quality Procedure?

    SciTech Connect

    Dutton, Spencer M.; Mendell, Mark J.; Chan, Wanyu R.

    2013-05-13

    Minimum outdoor air ventilation rates (VRs) for buildings are specified in standards, including California?s Title 24 standards. The ASHRAE ventilation standard includes two options for mechanically-ventilated buildings ? a prescriptive ventilation rate procedure (VRP) that specifies minimum VRs that vary among occupancy classes, and a performance-based indoor air quality procedure (IAQP) that may result in lower VRs than the VRP, with associated energy savings, if IAQ meeting specified criteria can be demonstrated. The California Energy Commission has been considering the addition of an IAQP to the Title 24 standards. This paper, based on a review of prior data and new analyses of the IAQP, evaluates four future options for Title 24: no IAQP; adding an alternate VRP, adding an equivalent indoor air quality procedure (EIAQP), and adding an improved ASHRAE-like IAQP. Criteria were established for selecting among options, and feedback was obtained in a workshop of stakeholders. Based on this review, the addition of an alternate VRP is recommended. This procedure would allow lower minimum VRs if a specified set of actions were taken to maintain acceptable IAQ. An alternate VRP could also be a valuable supplement to ASHRAE?s ventilation standard.

  17. MODELS TO ESTIMATE VOLATILE ORGANIC HAZARDOUS AIR POLLUTANT EMISSIONS FROM MUNICIPAL SEWER SYSTEMS

    EPA Science Inventory

    Emissions from municipal sewers are usually omitted from hazardous air pollutant (HAP) emission inventories. This omission may result from a lack of appreciation for the potential emission impact and/or from inadequate emission estimation procedures. This paper presents an analys...

  18. Including carbon emissions from deforestation in the carbon footprint of Brazilian beef.

    PubMed

    Cederberg, Christel; Persson, U Martin; Neovius, Kristian; Molander, Sverker; Clift, Roland

    2011-03-01

    Effects of land use changes are starting to be included in estimates of life-cycle greenhouse gas (GHG) emissions, so-called carbon footprints (CFs), from food production. Their omission can lead to serious underestimates, particularly for meat. Here we estimate emissions from the conversion of forest to pasture in the Legal Amazon Region (LAR) of Brazil and present a model to distribute the emissions from deforestation over products and time subsequent to the land use change. Expansion of cattle ranching for beef production is a major cause of deforestation in the LAR. The carbon footprint of beef produced on newly deforested land is estimated at more than 700 kg CO(2)-equivalents per kg carcass weight if direct land use emissions are annualized over 20 years. This is orders of magnitude larger than the figure for beef production on established pasture on non-deforested land. While Brazilian beef exports have originated mainly from areas outside the LAR, i.e. from regions not subject to recent deforestation, we argue that increased production for export has been the key driver of the pasture expansion and deforestation in the LAR during the past decade and this should be reflected in the carbon footprint attributed to beef exports. We conclude that carbon footprint standards must include the more extended effects of land use changes to avoid giving misleading information to policy makers, retailers, and consumers.

  19. Emissions and ambient air monitoring trends of lower olefins across Texas from 2002 to 2012.

    PubMed

    Myers, Jessica L; Phillips, Tracie; Grant, Roberta L

    2015-11-01

    Texas has the largest ambient air monitoring network in the country with approximately 83 monitoring sites that measure ambient air concentrations of volatile organic compounds (VOCs). The lower olefins, including 1,3-butadiene, ethylene, isoprene, and propylene, are a group of VOCs that can be measured in both 24h/every sixth-day canister samples and continuous 1-h Automated Gas Chromatography (AutoGC) samples. Based on 2012 Toxics Release Inventory data, the total reported industrial air emissions in Texas for these olefins, as compared to total national reported air emissions, were 79% for 1,3-butadiene, 62% for ethylene, 76% for isoprene, and 54% for propylene, illustrating that Texas industries are some of the major emitters for these olefins. The purpose of this study was to look at the patterns of annual average air monitoring data from 2002 to 2012 using Texas Commission on Environmental Quality (TCEQ) data for these four lower olefins. It should be emphasized that monitors may not be located close to or downwind of the highest emitters of these lower olefins. In addition, air monitors only provide a snapshot in time of air concentrations for their respective locations, and may not be able to discriminate emissions between specific sources. In 2012, the highest annual average air concentration for 1,3-butadiene was 1.28 ppb by volume (ppbv), which was measured at the Port Neches monitoring site in Region 10-Beaumont. For ethylene, the highest 2012 annual average air concentration was 5.77 ppbv, which was measured at the Dona Park monitoring site in TCEQ Region 14-Corpus Christi. Although reported industrial emissions of isoprene are predominantly from the Houston and Beaumont regions, trees are natural emitters of isoprene, and the highest ambient air concentrations tend to be from regions with large areas of coniferous and hardwood forests. This was observed with TCEQ Region 5-Tyler, which had the two highest isoprene annual average air concentrations for

  20. Emissions and ambient air monitoring trends of lower olefins across Texas from 2002 to 2012.

    PubMed

    Myers, Jessica L; Phillips, Tracie; Grant, Roberta L

    2015-11-01

    Texas has the largest ambient air monitoring network in the country with approximately 83 monitoring sites that measure ambient air concentrations of volatile organic compounds (VOCs). The lower olefins, including 1,3-butadiene, ethylene, isoprene, and propylene, are a group of VOCs that can be measured in both 24h/every sixth-day canister samples and continuous 1-h Automated Gas Chromatography (AutoGC) samples. Based on 2012 Toxics Release Inventory data, the total reported industrial air emissions in Texas for these olefins, as compared to total national reported air emissions, were 79% for 1,3-butadiene, 62% for ethylene, 76% for isoprene, and 54% for propylene, illustrating that Texas industries are some of the major emitters for these olefins. The purpose of this study was to look at the patterns of annual average air monitoring data from 2002 to 2012 using Texas Commission on Environmental Quality (TCEQ) data for these four lower olefins. It should be emphasized that monitors may not be located close to or downwind of the highest emitters of these lower olefins. In addition, air monitors only provide a snapshot in time of air concentrations for their respective locations, and may not be able to discriminate emissions between specific sources. In 2012, the highest annual average air concentration for 1,3-butadiene was 1.28 ppb by volume (ppbv), which was measured at the Port Neches monitoring site in Region 10-Beaumont. For ethylene, the highest 2012 annual average air concentration was 5.77 ppbv, which was measured at the Dona Park monitoring site in TCEQ Region 14-Corpus Christi. Although reported industrial emissions of isoprene are predominantly from the Houston and Beaumont regions, trees are natural emitters of isoprene, and the highest ambient air concentrations tend to be from regions with large areas of coniferous and hardwood forests. This was observed with TCEQ Region 5-Tyler, which had the two highest isoprene annual average air concentrations for

  1. National Emission Standards for Hazardous Air Pollutants—Calendar Year 2010 INL Report for Radionuclides (2011)

    SciTech Connect

    Mark Verdoorn; Tom Haney

    2011-06-01

    This report documents the calendar Year 2010 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy's Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, 'Protection of the Environment,' Part 61, 'National Emission Standards for Hazardous Air Pollutants,' Subpart H, 'National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.'

  2. Radionuclide air emissions report for the Hanford site, Calendar year 1994

    SciTech Connect

    Gleckler, B.P.; Diediker, L.P.; Jette, S.J.; Rhoads, K.; Soldat, S.K.

    1995-06-01

    This report documents radionuclide air emissions from the Hanford Site in 1994, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the ``MEI.`` The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, title 40, Protection of the Environment, Part 61, ``National Emissions Standards for Hazardous Air Pollutants,`` Subpart H, ``National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.``

  3. Radionuclide air emissions report for the Hanford Site, calendar year 1992

    SciTech Connect

    Diediker, L.P.; Johnson, A.R.; Rhoads, K.; Klages, D.L.; Soldat, J.K.; Rokkan, D.J.

    1993-06-01

    This report documents radionuclide air emissions from the Hanford Site in 1992 and the resulting effective dose equivalent to an member of the public. The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, ``National Emissions Standards for Hazardous Air Pollutants,`` Subpart H, ``National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.``

  4. Uncertainty for data with non-detects: Air toxic emissions from combustion

    SciTech Connect

    Zhao, Y.C.; Frey, H.C.

    2006-12-15

    Air toxic emission factor datasets often contain one or more points below a single or multiple detection limits and such datasets are referred to as 'censored.' Conventional methods used to deal with censored datasets include removing non-detects, replacing the censored points with zero, half of the detection limit, or the detection limit. However, the estimated means of the censored dataset by conventional methods are usually biased. Maximum likelihood estimation (MLE) and bootstrap simulation have been demonstrated as a statistically robust method to quantify variability and uncertainty of censored datasets and can provide asymptotically unbiased mean estimates. The MLE/bootstrap method is applied to 16 cases of censored air toxic emission factors, including benzene, formaldehyde, benzo(a)pyrene, mercury, arsenic, cadmium, total chromium, chromium VI and lead from coal, fuel oil, and/or wood waste external combustion sources. The proportion of censored values in the emission factor data ranges from 4 to 80%. Key factors that influence the estimated uncertainty in the mean of censored data are sample size and inter-unit variability. The largest range of uncertainty in the mean was obtained for the external coal combustion benzene emission factor, with 95 confidence interval of the mean equal to minus 93 to plus 411%.

  5. Impacts of Future Climate and Emission Changes on U.S. Air Quality

    SciTech Connect

    Penrod, Ashley; Zhang, Yang; Wang, K.; Wu, Shiang Yuh; Leung, Lai-Yung R.

    2014-06-01

    Changes in climate and emissions will affect future air quality. In this work, simulations of present (2001-2005) and future (2026-2030) regional air quality are conducted with the newly released CMAQ version 5.0 to examine the individual and combined impacts of simulated future climate and anthropogenic emission projections on air quality over the U.S. Current (2001-2005) meteorological and chemical predictions are evaluated against observational data to assess the model’s capability in reproducing the seasonal differences. Overall, WRF and CMAQ perform reasonably well. Increased temperatures (up to 3.18 °C) and decreased ventilation (up to 157 m in planetary boundary layer height) are found in both future winter and summer, with more prominent changes in winter. Increases in future temperatures result in increased isoprene and terpene emissions in winter and summer, driving the increase in maximum 8-h average O3 (up to 5.0 ppb) over the eastern U.S. in winter while decreases in NOx emissions drive the decrease in O3 over most of the U.S. in summer. Future concentrations of PM2.5 in winter and summer and many of its components including organic matter in winter, ammonium and nitrate in summer, and sulfate in winter and summer, decrease due to decreases in primary anthropogenic emissions and the concentrations of secondary anthropogenic pollutants and increased precipitation in winter. Future winter and summer dry and wet deposition fluxes are spatially variable and increase with increasing surface resistance and precipitation (e.g., NH4+ and NO3- dry and wet deposition fluxes increase in winter over much of the U.S.), respectively, and decrease with a decrease in ambient particulate concentrations (e.g., SO42- dry and wet deposition fluxes decrease over the eastern U.S. in summer and winter). Sensitivity simulations show that anthropogenic emission projections dominate over changes in climate in their impacts on the U.S. air quality in the near future. Changes

  6. Transport and Environment Database System (TRENDS): Maritime air pollutant emission modelling

    NASA Astrophysics Data System (ADS)

    Georgakaki, Aliki; Coffey, Robert A.; Lock, Graham; Sorenson, Spencer C.

    This paper reports the development of the maritime module within the framework of the Transport and Environment Database System (TRENDS) project. A detailed database has been constructed for the calculation of energy consumption and air pollutant emissions. Based on an in-house database of commercial vessels kept at the Technical University of Denmark, relationships between the fuel consumption and size of different vessels have been developed, taking into account the fleet's age and service speed. The technical assumptions and factors incorporated in the database are presented, including changes from findings reported in Methodologies for Estimating air pollutant Emissions from Transport (MEET). The database operates on statistical data provided by Eurostat, which describe vessel and freight movements from and towards EU 15 major ports. Data are at port to Maritime Coastal Area (MCA) level, so a bottom-up approach is used. A port to MCA distance database has also been constructed for the purpose of the study. This was the first attempt to use Eurostat maritime statistics for emission modelling; and the problems encountered, since the statistical data collection was not undertaken with a view to this purpose, are mentioned. Examples of the results obtained by the database are presented. These include detailed air pollutant emission calculations for bulk carriers entering the port of Helsinki, as an example of the database operation, and aggregate results for different types of movements for France. Overall estimates of SO x and NO x emission caused by shipping traffic between the EU 15 countries are in the area of 1 and 1.5 million tonnes, respectively.

  7. Assessment of Air Pollutants and Greenhouse Gases Emission Over East Asia : A Bottom-up Inventory Perspective

    NASA Astrophysics Data System (ADS)

    Woo, J. H.; Kim, Y.; Lee, Y. M.; Choi, K. C.; Zhang, Q.; Kurokawa, J. I.; Lee, J. B.; Song, C. K.; Kim, S.

    2014-12-01

    Air pollutants (SLCPs) such as tropospheric ozone and aerosols are mainly affected by meteorological variables and emissions. East Asia is one of important source regions of both anthropogenic and natural air pollutants and GHGs. Therefore, significant environmental changes are expected in the future and air quality modeling is the important methodology to quantitatively evaluate them. Multiple emission inventories with various spatio-temporal resolutions are necessary in support of many different air quality modeling and future climate chage researches. Many emission inventories have been developed for Asia and for Globe, such as TRACE-P, INTEX, REAS, CREATE, MICS-Asia, HTAP, SRES, RCP. Those inventories have been successfully used for many international researches, but also have several limitations including relatively old base year, limited number of pollutants/types, and low transparency of sector/fuel information. Understanding discrepancies and similarities among those intentories would give us a better insights to understand not only present status regional emissions amounts but structures of society and policy that link to the future emissions. To understand these, we; 1) selected several base-year bottom-up anthropogenic emission inventories over East Asia, 2) inter-compare emission inventories with more comprehensive sector/fuel classification, 3) explorer emissions change with more updated acvities, emission factors, and control options. The tentative results show that more than 50% of emission amount could be differ by inventory selection and more than 30% of emissions could be changed by emissions factor and/or control options. More findings regarding to these objectives will be presented on site

  8. 78 FR 29815 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-21

    ... from inventories developed for the Final Cross-State Air Pollution Rule (76 FR 48208, August 8, 2011... reductions. \\7\\ 65 FR 6698 (February 10, 2000). The proposed Tier 3 standards include new light- and heavy... emissions standards.\\10\\ \\8\\ 77 FR 62623 (October 15, 2012). \\9\\ These states include Connecticut,...

  9. The Clean Air Act strictly regulates electric utility emissions and utilities are reducing their emissions significantly

    SciTech Connect

    Kinsman, J.D.

    1998-12-31

    Electric utility SO{sub 2} and NO{sub x} emissions have been reduced tremendously, beginning before the first deadlines (1995 for SO{sub 2} and 1996 for NO{sub x}) of the 1990 Clean Air Act Amendments. For the Acid Rain Program, EPA reports that: (1) all 445 affected facilities demonstrated 100 percent compliance for both pollutants and even exceeded the compliance targets; (2) the Acid Rain Program has been very successful; and (3) due to these and other controls, air quality has improved in the United States. Furthermore, the new 8-hour ozone standard, the new PM2.5 standards, the EPA`s 22-state regional NO{sub x} program, the Northeast state petitions for upwind NO{sub x} reductions and EPA`s regional haze proposal will likely lead to substantially greater reductions of utility SO{sub 2} and NO{sub x}.

  10. An analysis of air-turborocket engine performance including effects of component changes

    NASA Technical Reports Server (NTRS)

    Luidens, Roger W; Weber, Richard J

    1956-01-01

    An analytical study of the air-turborocket engine is presented, showing both full-power operation over a range of flight speeds and part-power operation at several supersonic speeds. Engine weight, drag, and area variations are calculated in addition to the internal thrust coefficient and specific impulse. Tehe effects of changes in the component designs and efficiencies are indicated. Maximum specific impulse (including nacelle drag and using gasoline - nitric acid propellants) at Mach 2.3 is 1500 lb/(lb/sec). The performance is compared with that of a typical turbojet engine.

  11. The challenges of reducing greenhouse gas emissions and air pollution through energy sources: evidence from a panel of developed countries.

    PubMed

    Akhmat, Ghulam; Zaman, Khalid; Shukui, Tan; Sajjad, Faiza; Khan, Muhammad Azhar; Khan, Muhammad Zahir

    2014-06-01

    The objective of the study is to investigate the long-run relationship between climatic factors (i.e., greenhouse gas emissions, agricultural methane emissions, and industrial nitrous oxide emission), air pollution (i.e., carbon dioxide emissions), and energy sources (i.e., nuclear energy; oil, gas, and coal energy; and fossil fuel energy) in the panel of 35 developed countries (including EU-15, new EU member states, G-7, and other countries) over a period of 1975-2012. In order to achieve this objective, the present study uses sophisticated panel econometric techniques including panel cointegration, panel fully modified OLS (FMOLS), and dynamic OLS (DOLS). The results show that there is a long-run relationship between the variables. Nuclear energy reduces greenhouse gases and carbon emissions; however, the other emissions, i.e., agricultural methane emissions and industrial nitrous oxide, are still to increase during the study period. Electricity production from oil, gas, and coal sources increases the greenhouse gases and carbon emissions; however, the intensity to increase emissions is far less than the intensity to increase emissions through fossil fuel. Policies that reduce emissions of greenhouse gases can simultaneously alter emissions of conventional pollutants that have deleterious effects on human health and the environment.

  12. The challenges of reducing greenhouse gas emissions and air pollution through energy sources: evidence from a panel of developed countries.

    PubMed

    Akhmat, Ghulam; Zaman, Khalid; Shukui, Tan; Sajjad, Faiza; Khan, Muhammad Azhar; Khan, Muhammad Zahir

    2014-06-01

    The objective of the study is to investigate the long-run relationship between climatic factors (i.e., greenhouse gas emissions, agricultural methane emissions, and industrial nitrous oxide emission), air pollution (i.e., carbon dioxide emissions), and energy sources (i.e., nuclear energy; oil, gas, and coal energy; and fossil fuel energy) in the panel of 35 developed countries (including EU-15, new EU member states, G-7, and other countries) over a period of 1975-2012. In order to achieve this objective, the present study uses sophisticated panel econometric techniques including panel cointegration, panel fully modified OLS (FMOLS), and dynamic OLS (DOLS). The results show that there is a long-run relationship between the variables. Nuclear energy reduces greenhouse gases and carbon emissions; however, the other emissions, i.e., agricultural methane emissions and industrial nitrous oxide, are still to increase during the study period. Electricity production from oil, gas, and coal sources increases the greenhouse gases and carbon emissions; however, the intensity to increase emissions is far less than the intensity to increase emissions through fossil fuel. Policies that reduce emissions of greenhouse gases can simultaneously alter emissions of conventional pollutants that have deleterious effects on human health and the environment. PMID:24584642

  13. Air quality in China from 1850 to 2050 simulated using the IPCC AR5 emissions inventories

    NASA Astrophysics Data System (ADS)

    Chang, W.; Liao, H.

    2011-12-01

    Understanding the changes in regional air quality is central for air quality planning and for understanding the climatic effects of air pollutants. This study applies a fully coupled global chemistry-aerosol-climate model to investigate the interdecadal changes in air pollutants in China from 1850 to 2050. The model includes a detailed simulation of tropospheric O3-NOx-hydrocarbon chemistry, as well as sulfate, nitrate, ammonium, black carbon (BC), primary organic aerosol (POA), and secondary organic aerosol (SOA). The simulations are performed based on the IPCC AR5 historical emissions inventories and four future scenarios (RCP2.6, RCP4.5, RCP6.0, and RCP8.5). Model results show that the global mean surface-layer PM2.5 aerosol concentration peaked in 1980 with a global mean value of 2.61μg m-3, and then has been decreasing afterwards. A large fraction of the decrease can be explained by the reductions in sulfate aerosol over Europe and North America. The surface-layer PM2.5 concentration in China, however, showed monotonous increase since the preindustrial time. Averaged over eastern China, sulfate aerosol is found to have a relatively stable concentration of 5.5μg m-3 after 1980, whereas the year 2000 concentrations of nitrate, ammonium, BC, POA, and SOA are, respectively, 3.0, 1.6, 1.8, 1.4, and 1.5 times the 1980 values. As a result, the ratio of sulfate to PM2.5 in eastern China decreased from 49% in 1980 to 37% in 2000. These preliminary results indicate that, besides the emission control for SO2, a complex emission reduction strategy targeting other aerosol species is necessary for improving air quality in China.

  14. Modeling VOC emissions and air concentrations from the Exxon Valdez oil spill

    SciTech Connect

    Hanna, S.R. ); Drivas, P.J. )

    1993-03-01

    During the two-week period following the Exxon Valdez oil spill in March 1989 in Prince William Sound, Alaska, toxic volatile organic compounds (VOCs) evaporated from the surface of the oil spill and were transported and dispersed throughout the region. To estimate the air concentrations of these VOCs, emissions and dispersion modeling was conducted for each hour during the first two weeks of the spill. A multicomponent evaporative emissions model was developed and applied to the oil spill; the model considered the evaporation of 15 specific compounds, including benzene and toluene. Both mass transfer from the surface of the spill and diffusion through the oil layer were considered in the emissions model. Maximum emissions of toluene were calculated to equal about 20,000 kg/hr, or about 5 g/m[sup 2] hr, at a time of eight hours after the initial oil spill. Meteorological data were acquired from sources and used to estimate hourly-averaged wind velocity over the spill. Air concentrations of specific components were calculated using the ATDL area source diffusion model and the Offshore and Coastal Dispersion (OCD) model. Maximum hourly-averaged concentrations were predicted not to exceed 10 ppmv for any compound. 24 refs., 6 figs., 4 tabs.

  15. The impact of shipping emissions on air pollution in the greater North Sea region - Part 1: Current emissions and concentrations

    NASA Astrophysics Data System (ADS)

    Aulinger, A.; Matthias, V.; Zeretzke, M.; Bieser, J.; Quante, M.; Backes, A.

    2016-01-01

    The North Sea is one of the areas with the highest ship traffic densities worldwide. At any time, about 3000 ships are sailing its waterways. Previous scientific publications have shown that ships contribute significantly to atmospheric concentrations of NOx, particulate matter and ozone. Especially in the case of particulate matter and ozone, this influence can even be seen in regions far away from the main shipping routes. In order to quantify the effects of North Sea shipping on air quality in its bordering states, it is essential to determine the emissions from shipping as accurately as possible. Within Interreg IVb project Clean North Sea Shipping (CNSS), a bottom-up approach was developed and used to thoroughly compile such an emission inventory for 2011 that served as the base year for the current emission situation. The innovative aspect of this approach was to use load-dependent functions to calculate emissions from the ships' current activities instead of averaged emission factors for the entire range of the engine loads. These functions were applied to ship activities that were derived from hourly records of Automatic Identification System signals together with a database containing the engine characteristics of the vessels that traveled the North Sea in 2011. The emission model yielded ship emissions among others of NOx and SO2 at high temporal and spatial resolution that were subsequently used in a chemistry transport model in order to simulate the impact of the emissions on pollutant concentration levels. The total emissions of nitrogen reached 540 Gg and those of sulfur oxides 123 Gg within the North Sea - including the adjacent western part of the Baltic Sea until 5° W. This was about twice as much of those of a medium-sized industrialized European state like the Netherlands. The relative contribution of ships to, for example, NO2 concentration levels ashore close to the sea can reach up to 25 % in summer and 15 % in winter. Some hundred kilometers

  16. Effects of business-as-usual anthropogenic emissions on air quality

    NASA Astrophysics Data System (ADS)

    Pozzer, A.; Zimmermann, P.; Doering, U. M.; van Aardenne, J.; Tost, H.; Dentener, F.; Janssens-Maenhout, G.; Lelieveld, J.

    2012-08-01

    The atmospheric chemistry general circulation model EMAC has been used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050). The emission scenario assumes that population and economic growth largely determine energy and food consumption and consequent pollution sources with the current technologies ("business as usual"). This scenario is chosen to show the effects of not implementing legislation to prevent additional climate change and growing air pollution, other than what is in place for the base year 2005, representing a pessimistic (but plausible) future. By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecisions inherent to the coarse horizontal resolution (~100 km) and simplified bottom-up emission input. To identify possible future hot spots of poor air quality, a multi pollutant index (MPI), suited for global model output, has been applied. It appears that East and South Asia and the Middle East represent such hotspots due to very high pollutant concentrations, while a general increase of MPIs is observed in all populated regions in the Northern Hemisphere. In East Asia a range of pollutant gases and fine particulate matter (PM2.5) is projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Persian Gulf, where natural PM2.5 concentrations are already high (desert dust), ozone levels are expected to increase strongly. The population weighted MPI (PW-MPI), which combines demographic and pollutant concentration projections, shows that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. Following this business as usual scenario, it is projected that air quality for the global

  17. Effects of business-as-usual anthropogenic emissions on air quality

    NASA Astrophysics Data System (ADS)

    Pozzer, A.; Zimmermann, P.; Doering, U. M.; van Aardenne, J.; Tost, H.; Dentener, F.; Janssens-Maenhout, G.; Lelieveld, J.

    2012-04-01

    The atmospheric chemistry general circulation model EMAC has been used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050). The emission scenario assumes that population and economic growth largely determine energy and food consumption and consequent pollution sources with the current technologies ("business as usual"). This scenario is chosen to show the effects of not implementing legislation to prevent additional climate change and growing air pollution, other than what is in place for the base year 2005, representing a pessimistic (but feasible) future. By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecisions inherent to the coarse horizontal resolution (~100 km) and simplified bottom-up emission input. To identify possible future hot spots of poor air quality, a multi pollutant index (MPI), suited for global model output, has been applied. It appears that East and South Asia and the Middle East represent such hotspots due to very high pollutant concentrations, although a general increase of MPIs is observed in all populated regions in the Northern Hemisphere. In East Asia a range of pollutant gases and fine particulate matter (PM2.5) is projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Arabian Gulf, where natural PM2.5 concentrations are already high (desert dust), ozone levels are expected to increase strongly. The per capita MPI (PCMPI), which combines demographic and pollutants concentrations projections, shows that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. Following the business as usual scenario, it is projected that air quality for the global average

  18. Air emission from the co-combustion of alternative derived fuels within cement plants: Gaseous pollutants.

    PubMed

    Richards, Glen; Agranovski, Igor E

    2015-02-01

    Cement manufacturing is a resource- and energy-intensive industry, utilizing 9% of global industrial energy use while releasing more than 5% of global carbon dioxide (CO₂) emissions. With an increasing demand of production set to double by 2050, so too will be its carbon footprint. However, Australian cement plants have great potential for energy savings and emission reductions through the substitution of combustion fuels with a proportion of alternative derived fuels (ADFs), namely, fuels derived from wastes. This paper presents the environmental emissions monitoring of 10 cement batching plants while under baseline and ADF operating conditions, and an assessment of parameters influencing combustion. The experiential runs included the varied substitution rates of seven waste streams and the monitoring of seven target pollutants. The co-combustion tests of waste oil, wood chips, wood chips and plastic, waste solvents, and shredded tires were shown to have the minimal influence when compared to baseline runs, or had significantly reduced the unit mass emission factor of pollutants. With an increasing ADF% substitution, monitoring identified there to be no subsequent emission effects and that key process parameters contributing to contaminant suppression include (1) precalciner and kiln fuel firing rate and residence time; (2) preheater and precalciner gas and material temperature; (3) rotary kiln flame temperature; (4) fuel-air ratio and percentage of excess oxygen; and (5) the rate of meal feed and rate of clinker produced. PMID:25947054

  19. Air emission from the co-combustion of alternative derived fuels within cement plants: Gaseous pollutants.

    PubMed

    Richards, Glen; Agranovski, Igor E

    2015-02-01

    Cement manufacturing is a resource- and energy-intensive industry, utilizing 9% of global industrial energy use while releasing more than 5% of global carbon dioxide (CO₂) emissions. With an increasing demand of production set to double by 2050, so too will be its carbon footprint. However, Australian cement plants have great potential for energy savings and emission reductions through the substitution of combustion fuels with a proportion of alternative derived fuels (ADFs), namely, fuels derived from wastes. This paper presents the environmental emissions monitoring of 10 cement batching plants while under baseline and ADF operating conditions, and an assessment of parameters influencing combustion. The experiential runs included the varied substitution rates of seven waste streams and the monitoring of seven target pollutants. The co-combustion tests of waste oil, wood chips, wood chips and plastic, waste solvents, and shredded tires were shown to have the minimal influence when compared to baseline runs, or had significantly reduced the unit mass emission factor of pollutants. With an increasing ADF% substitution, monitoring identified there to be no subsequent emission effects and that key process parameters contributing to contaminant suppression include (1) precalciner and kiln fuel firing rate and residence time; (2) preheater and precalciner gas and material temperature; (3) rotary kiln flame temperature; (4) fuel-air ratio and percentage of excess oxygen; and (5) the rate of meal feed and rate of clinker produced.

  20. 40 CFR 63.2850 - How do I comply with the hazardous air pollutant emission standards?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false How do I comply with the hazardous air pollutant emission standards? 63.2850 Section 63.2850 Protection of Environment ENVIRONMENTAL PROTECTION... air pollutant emission standards? (a) General requirements. The requirements in paragraphs...

  1. AIR EMISSIONS FROM THE TREATMENT OF SOILS CONTAMINATED WITH PETROLEUM FUELS AND OTHER SUBSTANCES

    EPA Science Inventory

    The report updates a 1992 report that summarizes available information on air emissions from the treatment of soils contaminated with fuels. Soils contaminated by leaks or spills of fuel products, such as gasoline or jet fuel, are a nationwide concern. Air emissions during remedi...

  2. 40 CFR 204.52 - Portable air compressor noise emission standard.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Portable air compressor noise emission standard. 204.52 Section 204.52 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) NOISE ABATEMENT PROGRAMS NOISE EMISSION STANDARDS FOR CONSTRUCTION EQUIPMENT Portable Air Compressors §...

  3. 40 CFR 204.52 - Portable air compressor noise emission standard.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Portable air compressor noise emission standard. 204.52 Section 204.52 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) NOISE ABATEMENT PROGRAMS NOISE EMISSION STANDARDS FOR CONSTRUCTION EQUIPMENT Portable Air Compressors §...

  4. 77 FR 11476 - Delegation of National Emission Standards for Hazardous Air Pollutants for Source Categories; Nevada

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-27

    ... section 112(l) of the 1990 Clean Air Act, EPA granted ] delegation of specific national emission standards... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 63 Delegation of National Emission Standards for Hazardous Air Pollutants for...

  5. 40 CFR 265.1082 - Schedule for implementation of air emission standards.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1082 Schedule for implementation of air emission standards. (a) Owners or operators of... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Schedule for implementation of...

  6. 40 CFR 265.1082 - Schedule for implementation of air emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1082 Schedule for implementation of air emission standards. (a) Owners or operators of... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Schedule for implementation of...

  7. 40 CFR 265.1082 - Schedule for implementation of air emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1082 Schedule for implementation of air emission standards. (a) Owners or operators of... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Schedule for implementation of...

  8. 40 CFR 265.1082 - Schedule for implementation of air emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1082 Schedule for implementation of air emission standards. (a) Owners or operators of... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Schedule for implementation of...

  9. 40 CFR 265.1082 - Schedule for implementation of air emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Air Emission Standards for Tanks, Surface Impoundments, and Containers § 265.1082 Schedule for implementation of air emission standards. (a) Owners or operators of... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Schedule for implementation of...

  10. HVAC SYSTEMS AS EMISSION SOURCES AFFECTING INDOOR AIR QUALITY: A CRITICAL REVIEW

    EPA Science Inventory

    The paper discusses results of an evaluation of literature on heating, ventilating, and air-conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). The various literature sources and methods for characterizing HVAC emission sources are re...

  11. 40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What are the emission limitations for air curtain incinerators? 60.2860 Section 60.2860 Protection of Environment ENVIRONMENTAL PROTECTION... Curtain Incinerators § 60.2860 What are the emission limitations for air curtain incinerators? After...

  12. 40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What are the emission limitations for air curtain incinerators? 60.2860 Section 60.2860 Protection of Environment ENVIRONMENTAL PROTECTION... Curtain Incinerators § 60.2860 What are the emission limitations for air curtain incinerators? After...

  13. Biofuels that cause land-use change may have much larger non-GHG air quality emissions than fossil fuels.

    PubMed

    Tsao, C-C; Campbell, J E; Mena-Carrasco, M; Spak, S N; Carmichael, G R; Chen, Y

    2012-10-01

    Although biofuels present an opportunity for renewable energy production, significant land-use change resulting from biofuels may contribute to negative environmental, economic, and social impacts. Here we examined non-GHG air pollution impacts from both indirect and direct land-use change caused by the anticipated expansion of Brazilian biofuels production. We synthesized information on fuel loading, combustion completeness, and emission factors, and developed a spatially explicit approach with uncertainty and sensitivity analyses to estimate air pollution emissions. The land-use change emissions, ranging from 6.7 to 26.4 Tg PM(2.5), were dominated by deforestation burning practices associated with indirect land-use change. We also found Brazilian sugar cane ethanol and soybean biodiesel including direct and indirect land-use change effects have much larger life-cycle emissions than conventional fossil fuels for six regulated air pollutants. The emissions magnitude and uncertainty decrease with longer life-cycle integration periods. Results are conditional to the single LUC scenario employed here. After LUC uncertainty, the largest source of uncertainty in LUC emissions stems from the combustion completeness during deforestation. While current biofuels cropland burning policies in Brazil seek to reduce life-cycle emissions, these policies do not address the large emissions caused by indirect land-use change.

  14. Biofuels that cause land-use change may have much larger non-GHG air quality emissions than fossil fuels.

    PubMed

    Tsao, C-C; Campbell, J E; Mena-Carrasco, M; Spak, S N; Carmichael, G R; Chen, Y

    2012-10-01

    Although biofuels present an opportunity for renewable energy production, significant land-use change resulting from biofuels may contribute to negative environmental, economic, and social impacts. Here we examined non-GHG air pollution impacts from both indirect and direct land-use change caused by the anticipated expansion of Brazilian biofuels production. We synthesized information on fuel loading, combustion completeness, and emission factors, and developed a spatially explicit approach with uncertainty and sensitivity analyses to estimate air pollution emissions. The land-use change emissions, ranging from 6.7 to 26.4 Tg PM(2.5), were dominated by deforestation burning practices associated with indirect land-use change. We also found Brazilian sugar cane ethanol and soybean biodiesel including direct and indirect land-use change effects have much larger life-cycle emissions than conventional fossil fuels for six regulated air pollutants. The emissions magnitude and uncertainty decrease with longer life-cycle integration periods. Results are conditional to the single LUC scenario employed here. After LUC uncertainty, the largest source of uncertainty in LUC emissions stems from the combustion completeness during deforestation. While current biofuels cropland burning policies in Brazil seek to reduce life-cycle emissions, these policies do not address the large emissions caused by indirect land-use change. PMID:22924498

  15. Incinerator performance: effects of changes in waste input and furnace operation on air emissions and residues.

    PubMed

    Astrup, Thomas; Riber, Christian; Pedersen, Anne Juul

    2011-10-01

    Waste incineration can be considered a robust technology for energy recovery from mixed waste. Modern incinerators are generally able to maintain relatively stable performance, but changes in waste input and furnace operation may affect emissions. This study investigated how inorganic air emissions and residue composition at a full-scale incinerator were affected by known additions of specific waste materials to the normal municipal solid waste (MSW) input. Six individual experiments were carried out (% ww of total waste input): NaCl (0.5%), shoes (1.6%), automobile shredder waste (14%), batteries (0.5%), poly(vinyl chloride) (5.5%) and chromate-cupper-arsenate impregnated wood (11%). Materials were selected based on chemical composition and potential for being included or excluded from the waste mix. Critical elements in the waste materials were identified based on comparison with six experiments including 'as-large-as-possible' changes in furnace operation (oxygen levels, air supply and burnout level) only using normal MSW as input. The experiments showed that effects from the added waste materials were significant in relation to: air emissions (in particular As, Cd, Cr, Hg, Sb), element transfer coefficients, and residue composition (As, Cd, Cl, Cr, Cu, Hg, Mo, Ni, Pb, S, Sb, Zn). Changes in furnace operation could not be directly linked to changes in emissions and residues. The results outlined important elements in waste which should be addressed in relation to waste incinerator performance. Likely ranges of element transfer coefficients were provided as the basis for sensitivity analysis of life-cycle assessment (LCA) results involving waste incinerator technologies.

  16. Incinerator performance: effects of changes in waste input and furnace operation on air emissions and residues.

    PubMed

    Astrup, Thomas; Riber, Christian; Pedersen, Anne Juul

    2011-10-01

    Waste incineration can be considered a robust technology for energy recovery from mixed waste. Modern incinerators are generally able to maintain relatively stable performance, but changes in waste input and furnace operation may affect emissions. This study investigated how inorganic air emissions and residue composition at a full-scale incinerator were affected by known additions of specific waste materials to the normal municipal solid waste (MSW) input. Six individual experiments were carried out (% ww of total waste input): NaCl (0.5%), shoes (1.6%), automobile shredder waste (14%), batteries (0.5%), poly(vinyl chloride) (5.5%) and chromate-cupper-arsenate impregnated wood (11%). Materials were selected based on chemical composition and potential for being included or excluded from the waste mix. Critical elements in the waste materials were identified based on comparison with six experiments including 'as-large-as-possible' changes in furnace operation (oxygen levels, air supply and burnout level) only using normal MSW as input. The experiments showed that effects from the added waste materials were significant in relation to: air emissions (in particular As, Cd, Cr, Hg, Sb), element transfer coefficients, and residue composition (As, Cd, Cl, Cr, Cu, Hg, Mo, Ni, Pb, S, Sb, Zn). Changes in furnace operation could not be directly linked to changes in emissions and residues. The results outlined important elements in waste which should be addressed in relation to waste incinerator performance. Likely ranges of element transfer coefficients were provided as the basis for sensitivity analysis of life-cycle assessment (LCA) results involving waste incinerator technologies. PMID:21930520

  17. Impact of an improved Cuban emissions inventory on air quality simulations

    NASA Astrophysics Data System (ADS)

    Sanchez Gacita, M.; Alonso, M. F.; Longo, K. M.; de Freitas, S. R.

    2010-12-01

    The energy sector in the Central America and Caribbean regions is primarily fossil fuel based and one of the major sources of air pollution in the region. In Cuba, energy production is responsible for 99% of SO2 emissions, 98% of NOX and 94% of CO, with emissions in 2000 of 588.59 Gg, 149.57 Gg and 536.42 Gg, respectively, according to the Cuban National Inventory - CNI. Electric power generation plants, the most important sub-sector, are highlighted as point sources of high emissions, in particular, SO2. Global inventories are shown to be inaccurate for Cuba. RETRO has non-zero data for just one cell, over the city of Havana. EDGAR has deficiencies in its geographical distribution, with no emissions over the city of Havana, and the distribution of emissions by sectors is unrealistic according to the CNI: for instance, in the case of SO2, it distributes emissions nearly equally between electricity generation and the remaining sectors, which is inaccurate. More importantly, emissions are overestimated, with the notable exception of SO2 and NMVOC. The most important reasons are the particularities of Cuba, including the extensive employ of fossil fuels with little refining and high sulfur content in energy production and industrial processes such as asphalt production, and the use of low efficiency technologies. This work presents an improved emissions inventory with CNI data and detailed emissions for all major power generation plants. The impact of this improvement was assessed through numerical air quality simulations of the transport and transformation of these emissions from a regional perspective, conducted with the CCATT-BRAMS 3D atmospheric chemical transport model, developed and maintained by INPE, Brazil. Boundary conditions were supplied by global model MOCAGE with chemistry scheme RELACS. Simulations with the new inventory were conducted with CATT-BRAMS using chemical mechanism RELACS, incorporated as part of this work, for two months (January and August

  18. Locating and estimating air emissions from sources of arsenic and arsenic compounds. Final report

    SciTech Connect

    1998-06-01

    This document describes the properties of arsenic and arsenic compounds as air pollutants, defines production and use patterns, identifies source categories of air emissions, and provides emission factors. Arsenic is emitted as an air pollutant from external combustion boilers, municipal and hazardous waste incineration, primary copper and zinc smelting, glass manufacturing, copper ore mining, and primary and secondary lead smelting. Emissions of arsenic from these activities are due to the presence of trace amounts of arsenic in fuels and materials being processed. In such cases, the emissions may be quite variable because the trace presence of arsenic is not constant. Arsenic emissions also occur from agricultural chemical production and application, and also from metal processing due to the use of arsenic in these activities. In addition to the arsenic source information, information is provided that specifies how individual sources of arsenic may be tested to quantify air emissions.

  19. Volatile organic chemical emissions from structural insulated panel (SIP) materials and implications for indoor air quality

    SciTech Connect

    Hodgson, Alfred T.

    2003-09-01

    The emissions of volatile organic compounds (VOCs) from structural insulated panel (SIP) materials were investigated. Specimens of newly produced SIPs and associated panel adhesives were obtained from two relatively large manufacturers. Additionally, specimens of the oriented strand board (OSB) used as the inner and outer sheathing and the extruded polystyrene core for the SIP were obtained from one manufacturer. Using small-scale chambers, emissions of formaldehyde, acetaldehyde, acetic acid and other VOCs from SIPs, OSB and polystyrene were measured over a period of four months and from the adhesives over two months. SIP specimens overlaid by gypsum board panels were also tested over four months. The predominant VOCs emitted by the SIPs included acetic acid, pentanal, hexanal and styrene. The emissions of formaldehyde and acetaldehyde were relatively low. Acetic acid and the aldehydes derived from the OSB, while styrene derived from the polystyrene. One of the SIPs emitted toluene and methyl acetate. The adhesives primarily emitted a mixture of hydrocarbons. The emission rates of most VOCs from the SIP/gypsum board assemblies were approximately the same or higher than their respective emission rates from the unfinished SIPs. Modeling using VOC emission factors obtained for the SIP/gypsum board assemblies demonstrated the potential for SIP materials to degrade indoor air quality in houses. A field study to investigate VOC concentrations and emission rates in SIP houses relative to closely matched conventionally constructed houses is necessary to determine the actual impacts of SIPs. If significant impacts are observed, to it may be desirable to develop control measures to reduce the emissions of VOCs from SIPs, such as the substitution of lower emitting materials or the use of vapor diffusion barriers.

  20. VOC and hazardous air pollutant emission factors for military aircraft fuel cell inspection, maintenance, and repair operations

    SciTech Connect

    Nand, K.; Sahu, R.

    1997-12-31

    Accurate emission estimation is one of the key aspects of implementation of any air quality program. The Federal Title 5 program, specially requires an accurate and updated inventory of criteria as well hazardous air pollutants (HAPs) from all facilities. An overestimation of these two categories of pollutants, may cause the facility to be classified as a major source, when in fact it may actually be a minor source, and may also trigger unnecessary compliance requirements. A good example of where overestimation of volatile organic compounds (VOCs) and HAPs is easily possible are military aircraft fuel cells inspection, maintenance, and repair operations. The military aircraft fuel tanks, which are commonly identified as fuel cells, are routinely inspected for maintenance and repairs at military aircraft handling facilities. Prior to entry into the fuel cell by an inspector, fuel cells are first drained into bowsers and then purged with fresh air; the purged air is generally released without any controls to the atmosphere through a stack. The VOC and HAPs emission factors from these operations are not available in the literature for JP-8 fuel, which is being used increasingly by military aircraft. This paper presents two methods for estimating emissions for this source type, which are based on engineering calculations and professional judgment. This paper presents several methods for estimating emissions for this source type, which are based on engineering calculations and professional judgment. There are three emission producing phases during the draining and purging operations: (1) emissions during splash loading of bowsers (unloading of fuel cells), (2) emissions from spillage of fuel during loading of bowsers, and (3) emissions from fuel cell purging operations. Results of the emission estimation, including a comparison of the two emission estimation methods are presented in this paper.

  1. Air emissions from the incineration of hazardous waste.

    PubMed

    Oppelt, E T

    1990-10-01

    In the United States over the last ten years, concern over important disposal practices of the past has manifested itself in the passage of a series of federal and state-level hazardous waste clean-up and control statutes of unprecedented scope. The impact of these various statutes will be a significant modification of waste management practices. The more traditional and lowest cost methods of direct landfilling, storage in surface impoundments and deep-well injection will be replaced, in large measure, by waste minimization at the source of generation, waste reuse, physical/chemical/biological treatment, incineration and chemical stabilization/solidification methods. Of all of the "terminal" treatment technologies, properly-designed incineration systems are capable of the highest overall degree of destruction and control for the broadest range of hazardous waste streams. Substantial design and operational experience exists and a wide variety of commercial systems are available. Consequently, significant growth is anticipated in the use of incineration and other thermal destruction methods. The objective of this paper is to examine the current state of knowledge regarding air emissions from hazardous waste incineration in an effort to put the associated technological and environmental issues into perspective.

  2. The effects of oxygen-enriched intake air on FFV exhaust emissions using M85

    SciTech Connect

    Poola, R.B.; Sekar, R.; Ng, H.K.; Baudino, J.H.; Colucci, C.P.

    1996-05-01

    This paper presents results of emission tests of a flexible fuel vehicle (FFV) powered by an SI engine, fueled by M85 (methanol), and supplied with oxygen-enriched intake air containing 21, 23, and 25 vol% O2. Engine-out total hydrocarbons (THCs) and unburned methanol were considerably reduced in the entire FTP cycle when the O2 content of the intake air was either 23 or 25%. However, CO emissions did not vary much, and NOx emissions were higher. HCHO emissions were reduced by 53% in bag 1, 84% in bag 2, and 59% in bag 3 of the FTP cycle with 25% oxygen-enriched intake air. During cold-phase FTP,reductions of 42% in THCs, 40% in unburned methanol, 60% in nonmethane hydrocarbons, and 45% in nonmethane organic gases (NMOGs) were observed with 25% enriched air; NO{sub x} emissions increased by 78%. Converter-out emissions were also reduced with enriched air but to a lesser degree. FFVs operating on M85 that use 25% enriched air during only the initial 127 s of cold-phase FTP or that use 23 or 25% enriched air during only cold-phase FTP can meet the reactivity-adjusted NMOG, CO, NO{sub x}, and HCHO emission standards of the transitional low-emission vehicle.

  3. 76 FR 57913 - Amendments to National Emission Standards for Hazardous Air Pollutants for Area Sources: Plating...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-19

    ... Air Pollutants for Area Sources: Plating and Polishing'' which was published on June 20, 2011 (76 FR... AGENCY 40 CFR Part 63 RIN 2060-AQ74 Amendments to National Emission Standards for Hazardous Air... standards for hazardous air pollutants (NESHAP) for the plating and polishing area source category...

  4. 40 CFR 86.166-12 - Method for calculating emissions due to air conditioning leakage.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... to air conditioning leakage. 86.166-12 Section 86.166-12 Protection of Environment ENVIRONMENTAL... for calculating emissions due to air conditioning leakage. This section describes procedures used to determine a refrigerant leakage rate in grams per year from vehicle-based air conditioning units....

  5. 40 CFR 86.166-12 - Method for calculating emissions due to air conditioning leakage.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... to air conditioning leakage. 86.166-12 Section 86.166-12 Protection of Environment ENVIRONMENTAL... for calculating emissions due to air conditioning leakage. This section describes procedures used to determine a refrigerant leakage rate in grams per year from vehicle-based air conditioning units....

  6. 40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... air curtain incinerators? 60.2860 Section 60.2860 Protection of Environment ENVIRONMENTAL PROTECTION... Construction On or Before November 30, 1999 Model Rule-Air Curtain Incinerators § 60.2860 What are the emission limitations for air curtain incinerators? (a) After the date the initial stack test is required or...

  7. 40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... air curtain incinerators? 60.2860 Section 60.2860 Protection of Environment ENVIRONMENTAL PROTECTION... Construction On or Before November 30, 1999 Model Rule-Air Curtain Incinerators § 60.2860 What are the emission limitations for air curtain incinerators? (a) After the date the initial stack test is required or...

  8. 40 CFR 60.2860 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... air curtain incinerators? 60.2860 Section 60.2860 Protection of Environment ENVIRONMENTAL PROTECTION... Curtain Incinerators § 60.2860 What are the emission limitations for air curtain incinerators? (a) After... for air curtain incinerators? After the date the initial stack test is required or...

  9. 40 CFR 60.2250 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... air curtain incinerators? 60.2250 Section 60.2250 Protection of Environment ENVIRONMENTAL PROTECTION... of Performance for Commercial and Industrial Solid Waste Incineration Units Air Curtain Incinerators § 60.2250 What are the emission limitations for air curtain incinerators? Within 60 days after your...

  10. 40 CFR 60.2250 - What are the emission limitations for air curtain incinerators?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... air curtain incinerators? 60.2250 Section 60.2250 Protection of Environment ENVIRONMENTAL PROTECTION... of Performance for Commercial and Industrial Solid Waste Incineration Units Air Curtain Incinerators § 60.2250 What are the emission limitations for air curtain incinerators? Within 60 days after your...

  11. [Estimation of average traffic emission factor based on synchronized incremental traffic flow and air pollutant concentration].

    PubMed

    Li, Run-Kui; Zhao, Tong; Li, Zhi-Peng; Ding, Wen-Jun; Cui, Xiao-Yong; Xu, Qun; Song, Xian-Feng

    2014-04-01

    On-road vehicle emissions have become the main source of urban air pollution and attracted broad attentions. Vehicle emission factor is a basic parameter to reflect the status of vehicle emissions, but the measured emission factor is difficult to obtain, and the simulated emission factor is not localized in China. Based on the synchronized increments of traffic flow and concentration of air pollutants in the morning rush hour period, while meteorological condition and background air pollution concentration retain relatively stable, the relationship between the increase of traffic and the increase of air pollution concentration close to a road is established. Infinite line source Gaussian dispersion model was transformed for the inversion of average vehicle emission factors. A case study was conducted on a main road in Beijing. Traffic flow, meteorological data and carbon monoxide (CO) concentration were collected to estimate average vehicle emission factors of CO. The results were compared with simulated emission factors of COPERT4 model. Results showed that the average emission factors estimated by the proposed approach and COPERT4 in August were 2.0 g x km(-1) and 1.2 g x km(-1), respectively, and in December were 5.5 g x km(-1) and 5.2 g x km(-1), respectively. The emission factors from the proposed approach and COPERT4 showed close values and similar seasonal trends. The proposed method for average emission factor estimation eliminates the disturbance of background concentrations and potentially provides real-time access to vehicle fleet emission factors.

  12. Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

    NASA Technical Reports Server (NTRS)

    Meng, P. R.; Skorobatckyi, M.; Cosgrove, D. V.; Kempke, E. E., Jr.

    1976-01-01

    A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

  13. Air quality forecast of PM10 in Beijing with Community Multi-scale Air Quality Modeling (CMAQ) system: emission and improvement

    NASA Astrophysics Data System (ADS)

    Wu, Q.; Xu, W.; Shi, A.; Li, Y.; Zhao, X.; Wang, Z.; Li, J.; Wang, L.

    2014-10-01

    The MM5-SMOKE-CMAQ model system, which was developed by the United States Environmental Protection Agency (US EPA) as the MODELS-3 system, has been used for daily air quality forecasts in the Beijing Municipal Environmental Monitoring Center (Beijing MEMC), as a part of the Ensemble air quality Modeling forecast System for Beijing (EMS-Beijing) since the 2008 Olympic Games. According to the daily forecast results for the entire duration of 2010, the model shows good performance in the PM10 forecast on most days but clearly underestimates PM10 concentration during some air pollution episodes. A typical air pollution episode from 11-20 January 2010 was chosen, in which the observed air pollution index of particulate matter (PM10-API) reached 180 while the forecast PM10-API was about 100. In this study, three numerical methods are used for model improvement: first, by enhancing the inner domain with 3 km resolution grids, and expanding the coverage from only Beijing to an area including Beijing and its surrounding cities; second, by adding more regional point source emissions located at Baoding, Landfang and Tangshan, to the south and east of Beijing; third, by updating the area source emissions, including the regional area source emissions in Baoding and Tangshan and the local village/town-level area source emissions in Beijing. The last two methods are combined as the updated emissions method. According to the model sensitivity testing results by the CMAQ model, the updated emissions method and expanded model domain method can both improve the model performance separately. But the expanded model domain method has better ability to capture the peak values of PM10 than the updated emissions method due to better reproduction of the pollution transport process in this episode. As a result, the hindcast results ("New(CMAQ)"), which are driven by the updated emissions in the expanded model domain, show a much better model performance in the national standard station

  14. A simple method for screening emission sources of carbonyl compounds in indoor air.

    PubMed

    Yamashita, Shohei; Kume, Kazunari; Horiike, Toshiyuki; Honma, Nobuyuki; Fusaya, Masahiro; Ohura, Takeshi; Amagai, Takashi

    2010-06-15

    Volatile organic compounds (VOCs) emitted from building and furnishing materials are frequently observed in high concentrations in indoor air. Nondestructive analytical methods that determine the main parameters influencing concentration of the chemical substances are necessary to screen for sources of VOC emissions. Toward this goal, we have developed a new flux sampler, referred to herein as an emission cell for simultaneous multi-sampling (ECSMS), that is used for screening indoor emission sources of VOCs and for determining the emission rates of these sources. Because the ECSMS is based on passive sampling, it can be easily used on-site at a low cost. Among VOCs, low-molecular-weight carbonyl compounds including formaldehyde are frequently detected at high concentrations in indoor environments. In this study, we determined the reliability of the ECSMS for the collection of formaldehyde and other carbonyl compounds emitted from wood-based composites of medium density fiberboards and particleboards. We then used emission rates determined by the ECSMS to predict airborne concentrations of formaldehyde emitted from a bookshelf in a large chamber, and these data were compared to formaldehyde concentrations that were acquired simultaneously by means of an active sampling method. The values obtained from the two methods were quite similar, suggesting that ECSMS measurement is an effective method for screening primary sources influencing indoor concentrations of formaldehyde. PMID:20149530

  15. 30 CFR 585.659 - What requirements must I include in my SAP, COP, or GAP regarding air quality?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... implementing regulations as promulgated by the EPA under 40 CFR part 55. (b) For air quality modeling that you... 30 Mineral Resources 2 2014-07-01 2014-07-01 false What requirements must I include in my SAP, COP... What requirements must I include in my SAP, COP, or GAP regarding air quality? (a) You must comply...

  16. 30 CFR 585.659 - What requirements must I include in my SAP, COP, or GAP regarding air quality?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... implementing regulations as promulgated by the EPA under 40 CFR part 55. (b) For air quality modeling that you... 30 Mineral Resources 2 2013-07-01 2013-07-01 false What requirements must I include in my SAP, COP... What requirements must I include in my SAP, COP, or GAP regarding air quality? (a) You must comply...

  17. 30 CFR 585.659 - What requirements must I include in my SAP, COP, or GAP regarding air quality?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... implementing regulations as promulgated by the EPA under 40 CFR part 55. (b) For air quality modeling that you... 30 Mineral Resources 2 2012-07-01 2012-07-01 false What requirements must I include in my SAP, COP... What requirements must I include in my SAP, COP, or GAP regarding air quality? (a) You must comply...

  18. 30 CFR 285.659 - What requirements must I include in my SAP, COP, or GAP regarding air quality?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What requirements must I include in my SAP, COP, or GAP regarding air quality? 285.659 Section 285.659 Mineral Resources BUREAU OF OCEAN ENERGY... Pipeline Deviations § 285.659 What requirements must I include in my SAP, COP, or GAP regarding air...

  19. Volcanic gas emissions and their impact on ambient air character at Kilauea Volcano, Hawaii

    SciTech Connect

    Sutton, A.J.; Elias, T.; Navarrete, R.

    1994-12-31

    Gas emissions from Kilauea occur from the summit caldera, along the middle East Rift Zone (ERZ), and where lava enters the ocean. We estimate that the current ERZ eruption of Kilauea releases between 400 metric tonnes of SO{sub 2} per day, during eruptive pauses, to as much as 1850 metric tonnes per day during actively erupting periods, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl and HF. In order to characterize gas emissions from Kilauea in a meaningful way for assessing environmental impact, we made a series of replicate grab-sample measurements of ambient air and precipitation at the summit of Kilauea, along its ERZ, and at coastal sites where lava enters the ocean. The grab-sampling data combined with SO{sub 2} emission rates, and continuous air quality and meteorological monitoring at the summit of Kilauea show that the effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Prevailing tradewinds typically carry the gases and aerosols released to the southwest, where they are further distributed by the regional wind regime. Episodes of kona, or low speed variable winds sometimes disrupt this pattern, however, and allow the gases and their oxidation products to collect at the summit and eastern side of the island. Summit solfatara areas of Kilauea are distinguished by moderate to high ambient SO{sub 2}, high H{sub 2}S at one location, and low H{sub 2}S at all others, and negligible HCl concentrations, as measured 1 m from degassing point-sources. Summit solfatara rain water has high sulfate and low chloride ion concentrations, and low pH.

  20. MODELING ASSESSMENT OF TRANSPORT AND DEPOSITION PATTERNS OF MERCURY AIR EMISSIONS FROM THE U.S. AND CANADA

    EPA Science Inventory

    In December 1997, the U.S. EPA submitted the Mercury Study Report to Congress which included a regional-scale modeling assessment of the transport and deposition of U.S. air emissions of mercury. This modeling was performed with a modified version of the Regional Lagrangian Mode...

  1. MEMLS3&a: Microwave Emission Model of Layered Snowpacks adapted to include backscattering

    NASA Astrophysics Data System (ADS)

    Proksch, M.; Mätzler, C.; Wiesmann, A.; Lemmetyinen, J.; Schwank, M.; Löwe, H.; Schneebeli, M.

    2015-08-01

    The Microwave Emission Model of Layered Snowpacks (MEMLS) was originally developed for microwave emissions of snowpacks in the frequency range 5-100 GHz. It is based on six-flux theory to describe radiative transfer in snow including absorption, multiple volume scattering, radiation trapping due to internal reflection and a combination of coherent and incoherent superposition of reflections between horizontal layer interfaces. Here we introduce MEMLS3&a, an extension of MEMLS, which includes a backscatter model for active microwave remote sensing of snow. The reflectivity is decomposed into diffuse and specular components. Slight undulations of the snow surface are taken into account. The treatment of like- and cross-polarization is accomplished by an empirical splitting parameter q. MEMLS3&a (as well as MEMLS) is set up in a way that snow input parameters can be derived by objective measurement methods which avoid fitting procedures of the scattering efficiency of snow, required by several other models. For the validation of the model we have used a combination of active and passive measurements from the NoSREx (Nordic Snow Radar Experiment) campaign in Sodankylä, Finland. We find a reasonable agreement between the measurements and simulations, subject to uncertainties in hitherto unmeasured input parameters of the backscatter model. The model is written in Matlab and the code is publicly available for download through the following website: http://www.iapmw.unibe.ch/research/projects/snowtools/memls.html.

  2. DIESEL TRUCK IDLING EMISSIONS - MOBILE SOURCE AIR TOXICS MEASURED AT A HOT SPOT

    SciTech Connect

    Parks, II, James E; Storey, John Morse; Miller, Terry L.; Fu, Joshua S.; Hromis, Boris

    2007-01-01

    Mobile Source Air Toxics (MSATs) are of growing concern due to recent studies linking health risk to residency near heavily traveled roadways. Few research studies on MSAT emissions have been performed due to several factors; those factors include: the difficulty of measuring MSATs due to their semi-volatile nature, lower relative concentration in comparison to NOx and other criteria emissions, and fewer regulations on MSATs. In this paper, measurements of MSATs at a "hot spot" of poor air quality created by a high population of idling heavy-duty trucks are presented. The study area was the Watt Road-Interstate-40/75 interchange just west of Knoxville, TN where approximately 20,000 heavy-duty trucks travel along the interstate each day and hundreds of heavy-duty trucks idle at three large truck stops near the interchange. The air quality in the local area surrounding the interchange is affected negatively by the high number of mobile sources as well as geographic and meteorological conditions; the interchange lies in a valley between two ridges which slows long range transport of pollutants especially in winter months when temperature inversion occurs frequently. Ambient air quality was measured during summer and winter months of two separate years at three sites: a site in one of the truckstops, a site near the interstate roadway, and a site on top of one of the surrounding ridges chosen as a background site for comparison. Results of criteria pollutants measured at these sites are reported in a companion paper by Miller et. al.; the results presented here include measurements of MSATs such as formaldehyde, acetaldehyde, acrolein, and other species obtained via collection on di-nitrophenyl hydrazine (DNPH) filters. Also, preliminary measurements of poly-aromatic hydrocarbons are presented. The results indicate that emissions from idling heavy-duty trucks are a primary contributor of MSATs to local air quality near areas of high static truck traffic; furthermore

  3. Assessment of Air Emissions at the U S Liquids Exploration and Production Land Treatment Facility

    SciTech Connect

    John H. Pardue; K.T. Valsaraj

    2000-12-01

    of E&P wastes. Additional emission measurements were made at the Bateman Island facility within cells over a range of ''ages'', from those most recently loaded with E&P wastes to cells that have not received wastes for 9 months or more. As expected the greatest chance for emissions when the cell is most recently loaded. Again, measured fluxes did not produce air concentrations that were of concern. As expected, the highest fluxes were observed in the cells that had recently received wastes and older cells had very low emissions. Measurements of emissions of hydrogen sulfide (H{sub 2}S) were also conducted at these two facilities. Levels of emissions were similar to the xange observed in the literature for natural salt marshes that surround these facilities. Production of sulfide within the cells was also measured by the most sensitive techniques available and measured sulfide production rates were low in the samples tested. The only potential concern at the facility with regards to sulfide was the levels of sulfide emitted from the sumps. The facility logbook at Bourg was analyzed to determine a time sequence of activities over 1998-1999. The Louisiana Department of Environmental Quality conducted a time-series of air concentrations for hazardous air pollutants during this period at the fenceline of the Bourg facility. These data were characterized by periods of static concentrations interspersed with peaks. A series of peaks were analyzed and compared with logbook records for the activities occurring at the time. In reverse fashion, a set of activities documented by the logbook was examined and the concentrations of benzene that developed from these activities were documented. No direct correlation could be made with the observed peaks and any activities suggesting that concentrations of benzene at the fenceline may be the result of a complex suite of activities including onsite activities not documented in the logbook (loading of the cells by truck haulers) and

  4. Development of the GEM-MACH-FireWork System: An Air Quality Model with On-line Wildfire Emissions within the Canadian Operational Air Quality Forecast System

    NASA Astrophysics Data System (ADS)

    Pavlovic, Radenko; Chen, Jack; Beaulieu, Paul-Andre; Anselmp, David; Gravel, Sylvie; Moran, Mike; Menard, Sylvain; Davignon, Didier

    2014-05-01

    A wildfire emissions processing system has been developed to incorporate near-real-time emissions from wildfires and large prescribed burns into Environment Canada's real-time GEM-MACH air quality (AQ) forecast system. Since the GEM-MACH forecast domain covers Canada and most of the U.S.A., including Alaska, fire location information is needed for both of these large countries. During AQ model runs, emissions from individual fire sources are injected into elevated model layers based on plume-rise calculations and then transport and chemistry calculations are performed. This "on the fly" approach to the insertion of the fire emissions provides flexibility and efficiency since on-line meteorology is used and computational overhead in emissions pre-processing is reduced. GEM-MACH-FireWork, an experimental wildfire version of GEM-MACH, was run in real-time mode for the summers of 2012 and 2013 in parallel with the normal operational version. 48-hour forecasts were generated every 12 hours (at 00 and 12 UTC). Noticeable improvements in the AQ forecasts for PM2.5 were seen in numerous regions where fire activity was high. Case studies evaluating model performance for specific regions and computed objective scores will be included in this presentation. Using the lessons learned from the last two summers, Environment Canada will continue to work towards the goal of incorporating near-real-time intermittent wildfire emissions into the operational air quality forecast system.

  5. Constraints on sea to air emissions from methane clathrates in the vicinity of Svalbard

    NASA Astrophysics Data System (ADS)

    Pisso, Ignacio; Vadakkepuliyambatta, Sunil; Platt, Stephen Matthew; Eckhardt, Sabine; Allen, Grant; Pitt, Joseph; Silyakova, Anna; Hermansen, Ove; Schmidbauer, Norbert; Mienert, Jurgen; Myhre, Cathrine Lund; Stohl, Andreas

    2016-04-01

    Methane stored in the seabed in the form of clathrates has the potential to be released into the atmosphere due to ongoing ocean warming. The Methane Emissions from Arctic Ocean to Atmosphere (MOCA, http://moca.nilu.no/) proje sct conducted measurement campaigns in the vicinity of Svalbard during the summers of 2014 and 2015 in collaboration with the Centre for Arctic Gas Hydrate, Environment and Climate (CAGE, https://cage.uit.no/) and the MAMM (https://arcticmethane.wordpress.com) project . The extensive set of measurements includes air (BAe 146) and ship (RV Helmer Hansen) borne methane concentrations, complemented with the nearby monitoring site at Zeppelin mountain. In order to assess the atmospheric impact of emissions from seabed methane hydrates, we characterised the local and long range atmospheric transport during the aircraft campaign and different scenarios for the emission sources. We present a range of upper bounds for the CH4 emissions during the campaign period as well as the methodologies used to obtain them. The methodologies include a box model, Lagrangian transport and elementary inverse modelling. We emphasise the analysis of the aircraft data. We discuss in detail the different methodologies used for determining the upper flux bounds as well as its uncertainties and limitations. The additional information provided by the ship and station observations will be briefly mentioned.

  6. Nature of air pollution, emission sources, and management in the Indian cities

    NASA Astrophysics Data System (ADS)

    Guttikunda, Sarath K.; Goel, Rahul; Pant, Pallavi

    2014-10-01

    The global burden of disease study estimated 695,000 premature deaths in 2010 due to continued exposure to outdoor particulate matter and ozone pollution for India. By 2030, the expected growth in many of the sectors (industries, residential, transportation, power generation, and construction) will result in an increase in pollution related health impacts for most cities. The available information on urban air pollution, their sources, and the potential of various interventions to control pollution, should help us propose a cleaner path to 2030. In this paper, we present an overview of the emission sources and control options for better air quality in Indian cities, with a particular focus on interventions like urban public transportation facilities; travel demand management; emission regulations for power plants; clean technology for brick kilns; management of road dust; and waste management to control open waste burning. Also included is a broader discussion on key institutional measures, like public awareness and scientific studies, necessary for building an effective air quality management plan in Indian cities.

  7. Impacts of flare emissions from an ethylene plant shutdown to regional air quality

    NASA Astrophysics Data System (ADS)

    Wang, Ziyuan; Wang, Sujing; Xu, Qiang; Ho, Thomas

    2016-08-01

    Critical operations of chemical process industry (CPI) plants such as ethylene plant shutdowns could emit a huge amount of VOCs and NOx, which may result in localized and transient ozone pollution events. In this paper, a general methodology for studying dynamic ozone impacts associated with flare emissions from ethylene plant shutdowns has been developed. This multi-scale simulation study integrates process knowledge of plant shutdown emissions in terms of flow rate and speciation together with regional air-quality modeling to quantitatively investigate the sensitivity of ground-level ozone change due to an ethylene plant shutdown. The study shows the maximum hourly ozone increments can vary significantly by different plant locations and temporal factors including background ozone data and solar radiation intensity. It helps provide a cost-effective air-quality control strategy for industries by choosing the optimal starting time of plant shutdown operations in terms of minimizing the induced ozone impact (reduced from 34.1 ppb to 1.2 ppb in the performed case studies). This study provides valuable technical supports for both CPI and environmental policy makers on cost-effective air-quality controls in the future.

  8. Assessment of 2012 on-road mobile source episode specific emissions on air quality in Houston

    NASA Astrophysics Data System (ADS)

    Zhang, H.; Shen, X.; Sarker, S.; Du, H.; Huque, Z.; Kommalapati, R. R.

    2015-12-01

    Houston has long been known to suffer from poor air quality, especially ground ozone level produced from photochemical reactions between nitrogen oxides (NOx) and Volatile Organic Compounds (VOC) in the presence of sunlight. In order to investigate impact of various emissions on air quality in Houston, combination of biogenic emissions with anthropogenic emissions were simulated for 2012 ozone episode. In this research, impact of on-road mobile source emissions on air quality in Houston were assessed. On-road mobile source inventories were developed using the EPA's MOVES (MOtor Vehicle Emission Simulator) model. Emissions Preprocessor System was used to convert the developed on-road mobile source inventories to suitable format. The converted on-road mobile source inventories were combined with biogenic emissions as the air quality model input. CAMx (Comprehensive Air quality Model with extensions) model was used to simulate various air pollutants concentrations for 2012 ozone episode. Simulation results showed that various transportation patterns have quite different influences on the air quality in this region.

  9. Cleaning Products and Air Fresheners: Emissions and ResultingConcentrations of Glycol Ethers and Terpenoids

    SciTech Connect

    Singer, Brett C.; Destaillat, Hugo; Hodgson, Alfred T.; Nazaroff,William W.

    2005-08-01

    Experiments were conducted to quantify emissions and concentrations of glycol ethers and terpenoids from cleaning product and air freshener use in a 50-m{sup 3} room ventilated at {approx}0.5 h{sup -1}. Five cleaning products were applied full-strength (FS); three were additionally used in dilute solution. FS application of pine-oil cleaner (POC) yielded 1-h concentrations of 10-1300 {micro}g m{sup -3} for individual terpenoids, including {alpha}-terpinene (90-120), d-limonene (1000-1100), terpinolene (900-1300), and {alpha}-terpineol (260-700). One-hour concentrations of 2-butoxyethanol and/or dlimonene were 300-6000 {micro}g m{sup -3} after FS use of other products. During FS application including rinsing with sponge and wiping with towels, fractional emissions (mass volatilized/dispensed) of 2-butoxyethanol and d-limonene were 50-100% with towels retained, {approx}25-50% when towels were removed after cleaning. Lower fractions (2-11%) resulted from dilute use. Fractional emissions of terpenes from FS use of POC were {approx}35-70% with towels retained, 20-50% with towels removed. During floor cleaning with dilute solution of POC, 7-12% of dispensed terpenes were emitted. Terpene alcohols were emitted at lower fractions: 7-30% (FS, towels retained), 2-9% (FS, towels removed), and 2-5% (dilute). During air-freshener use, d-limonene, dihydromyrcenol, linalool, linalyl acetate, and {beta}-citronellol were emitted at 35-180 mg d{sup -1} over three days while air concentrations averaged 30-160 {micro}g m{sup -3}.

  10. Progress made towards including wildfires in real-time cloud resolving forecasts at NOAA/ESRL and examining its impact upon weather and air quality

    NASA Astrophysics Data System (ADS)

    Grell, G. A.; Peckham, S.; Smirnova, T.; Benjamin, S.; McKeen, S. A.; Stuefer, M.; Freitas, S. R.; Longo, K.

    2009-12-01

    The growing influence of biomass burning emissions on air quality, human health, and feedbacks to the climate system has become undeniable in recent years. Recognized impacts include enhanced emissions of greenhouse gases changes in atmospheric chemistry, deposition of trace gases and particles onto Arctic surfaces, and altered patterns of precipitation. Chemical Transport Models use a variety of methods to include emissions from fires, and different applications and results can vary significantly. Variability in emission estimates can result from selection of area burned products, ecosystem types, fuel contained in ecosystems and the amount of fuel consumed, which is directly related to weather and climate. Each of these can differ by an order of magnitude, which can significantly influence the simulated radiation and chemistry products produced. From the ground up through the fire column, assumptions in fire behavior (i.e. level of severity, energy release rate, flaming versus smoldering combustion) and injection height can lead to a variety of emission estimations . The focus of this session is on the distinct assumptions that are made to estimate bottom-up fire emissions for use in regional and global models. Defining methodologies and the unique contribution of the variety of model assumptions will be a major goal of this session. We are particularly interested in the differences that result from the variety of assumptions and the disparity in model simulations that stem from these distinctions, because this is where we will find the interesting science questions and where we can begin to move more closely towards approximating reality.

  11. Mapping Emissions that Contribute to Air Pollution Using Adjoint Sensitivity Analysis

    NASA Astrophysics Data System (ADS)

    Bastien, L. A. J.; Mcdonald, B. C.; Brown, N. J.; Harley, R.

    2014-12-01

    The adjoint of the Community Multiscale Air Quality model (CMAQ) is used to map emissions that contribute to air pollution at receptors of interest. Adjoint tools provide an efficient way to calculate the sensitivity of a model response to a large number of model inputs, a task that would require thousands of simulations using a more traditional forward sensitivity approach. Initial applications of this technique, demonstrated here, are to benzene and directly-emitted diesel particulate matter, for which atmospheric reactions are neglected. Emissions of these pollutants are strongly influenced by light-duty gasoline vehicles and heavy-duty diesel trucks, respectively. We study air quality responses in three receptor areas where populations have been identified as especially susceptible to, and adversely affected by air pollution. Population-weighted air basin-wide responses for each pollutant are also evaluated for the entire San Francisco Bay area. High-resolution (1 km horizontal grid) emission inventories have been developed for on-road motor vehicle emission sources, based on observed traffic count data. Emission estimates represent diurnal, day of week, and seasonal variations of on-road vehicle activity, with separate descriptions for gasoline and diesel sources. Emissions that contribute to air pollution at each receptor have been mapped in space and time using the adjoint method. Effects on air quality of both relative (multiplicative) and absolute (additive) perturbations to underlying emission inventories are analyzed. The contributions of local versus upwind sources to air quality in each receptor area are quantified, and weekday/weekend and seasonal variations in the influence of emissions from upwind areas are investigated. The contribution of local sources to the total air pollution burden within the receptor areas increases from about 40% in the summer to about 50% in the winter due to increased atmospheric stagnation. The effectiveness of control

  12. RCRA/UST, superfund, and EPCRA hotline training module. Introduction to: Air emissions standards, updated as of July 1995

    SciTech Connect

    1995-11-01

    The module provides a regulatory overview of the RCRA air emission standards as they apply to hazardous waste facilities. It outlines the history of RCRA air emission standards as well as the air emission controls required by the standards. It explains the differences between the parts 264/265, Subpart AA BB, CC, air emission standards and summarizes the requirements of each of these Subparts. It identifies the types of units subject to these requirements as well as specific exemptions.

  13. Estimates of air emissions from asphalt storage tanks and truck loading

    SciTech Connect

    Trumbore, D.C.

    1999-12-31

    Title V of the 1990 Clean Air Act requires the accurate estimation of emissions from all US manufacturing processes, and places the burden of proof for that estimate on the process owner. This paper is published as a tool to assist in the estimation of air emission from hot asphalt storage tanks and asphalt truck loading operations. Data are presented on asphalt vapor pressure, vapor molecular weight, and the emission split between volatile organic compounds and particulate emissions that can be used with AP-42 calculation techniques to estimate air emissions from asphalt storage tanks and truck loading operations. Since current AP-42 techniques are not valid in asphalt tanks with active fume removal, a different technique for estimation of air emissions in those tanks, based on direct measurement of vapor space combustible gas content, is proposed. Likewise, since AP-42 does not address carbon monoxide or hydrogen sulfide emissions that are known to be present in asphalt operations, this paper proposes techniques for estimation of those emissions. Finally, data are presented on the effectiveness of fiber bed filters in reducing air emissions in asphalt operations.

  14. Air Dispersion Modeling for the INL Application for a Synthetic Minor Sitewide Air Quality Permit to Construct with a Facility Emission Cap Component

    SciTech Connect

    Sondrup, Andrus Jeffrey

    2015-10-01

    .e., land use data that defines roughness, albedo, Bowen ratio, and other parameters) were processed using the AERSURFACE utility (Version 13016) (EPA 2013). Emission sources were modeled as point sources using actual stack locations and dimensions. Emissions, flow rates and exit temperatures were based on the design operating capacity of each source. All structures close enough to produce an area of wake effect were included for all sources. For multi-tiered structures, the heights of the tiers were included or the entire building height was assumed to be equal to the height of the tallest tier. Concentrations were calculated at 1,352 receptor locations provided by DEQ. All receptors were considered for each pollutant and averaging period. Maximum modeled CAP concentrations summed with average background concentration values were presented and compared to National Ambient Air Quality Standards (NAAQS). The background concentration values used were obtained using the Washington State University’s Laboratory for Atmospheric Research North West Airquest web-based retrieval tool (http://lar.wsu.edu/nw airquest/lookup.html). The air dispersion modeling results show the maximum impacts for CAPs are less than applicable standards and demonstrate the INL will not cause a violation of any ambient air quality standards.

  15. Effects of future climate and land cover changes on biogenic emissions and air quality in the US

    NASA Astrophysics Data System (ADS)

    Chung, S. H.; Gonzalez Abraham, R.; Arroyo, A.; Lamb, B. K.; Duhl, T.; Wiedinmyer, C.; Guenther, A. B.; Zhang, Y.; Salathe, E. P.

    2009-12-01

    Biogenic volatile organic compounds (BVOCs) emitted from vegetations are highly reactive in the atmosphere and contribute to ozone and secondary organic aerosol formation. Climate change influences vegetation distributions and emissions of BVOCs and thereby affects air quality. As part of a comprehensive investigation of the effects of global change on regional air quality in the US, this study examines the effects of future climate and land cover changes on emissions of BVOCs into the atmosphere and air quality in the US. The mesoscale WRF (Weather Research and Forecasting) model is applied at hemispheric (220 km grid cells) and continental US (36 km grid cells) scales for current (1995-2004) and future (2045-2054) decades to downscale climate results from the ECHAM5 global climate model for IPCC SRES scenario A1B. The MEGAN (Model of Emissions of Gases and Aerosols from Nature) model is driven by WRF meteorological results to predict biogenic emissions of VOCs and NOx. MEGAN accounts for vegetation species distributions and environmental factors such as temperature and light. Current decade vegetation distributions are derived from satellite observations. Future vegetation distributions are predicted from MAPSS (Mapped Atmosphere-Plant-Soil System) and the land cover model of IMAGE 2.0 (Integrated Model to Assess the Global Environment). Future land cover changes include the expansion of croplands so that land management changes can also be examined. The CMAQ (Community Multiscale Air Quality Modeling) chemical transport model is used to simulate O3 and aerosol concentrations using current- and future-decade biogenic emissions but with anthropogenic emissions held constant at current-decade levels. Results showing the changes in US air quality due to climate- and landuse-driven changes in biogenic emissions will be presented. These results are compared to previous simulations derived from the IPCC SRES scenario A1 scenario with the PCM (Parallel Climate Model

  16. Impact of air conditioning system operation on increasing gases emissions from automobile

    NASA Astrophysics Data System (ADS)

    Burciu, S. M.; Coman, G.

    2016-08-01

    The paper presents a study concerning the influence of air conditioning system operation on the increase of gases emissions from cars. The study focuses on urban operating regimes of the automobile, regimes when the engines have low loads or are operating at idling. Are presented graphically the variations of pollution emissions (CO, CO2, HC) depending of engine speed and the load on air conditioning system. Additionally are presented, injection duration, throttle position, the mechanical power required by the compressor of air conditioning system and the refrigerant pressure variation on the discharge path, according to the stage of charging of the air conditioning system.

  17. National Emission Standards for Hazardous Air Pollutants—Calendar Year 2011 INL Report for Radionuclides (2012)

    SciTech Connect

    Mark Verdoorn; Tom Haney

    2012-06-01

    This report documents the calendar year 2011 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy's Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, 'Protection of the Environment,' Part 61, 'National Emission Standards for Hazardous Air Pollutants,' Subpart H, 'National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.' The effective dose equivalent to the maximally exposed individual member of the public was 4.58E-02 mrem per year, 0.46 percent of the 10 mrem standard.

  18. National Emission Standards for Hazardous Air Pollutants. Calendar Year 2012 INL Report for Radionuclides (2013)

    SciTech Connect

    Verdoorn, Mark; Haney, Tom

    2013-06-01

    This report documents the calendar year 2011 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy’s Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, ''Protection of the Environment,'' Part 61, ''National Emission Standards for Hazardous Air Pollutants,'' Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.'' The effective dose equivalent to the maximally exposed individual member of the public was 4.58E-02 mrem per year, 0.46 percent of the 10 mrem standard.

  19. National Emission Standards for Hazardous Air Pollutants. Calendar Year 2013 INL Report for Radionuclides [2014

    SciTech Connect

    Verdoorn, Mark; Haney, Tom

    2014-06-01

    This report documents the calendar year 2013 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy’s Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, ''Protection of the Environment,'' Part 61, ''National Emission Standards for Hazardous Air Pollutants,'' Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.'' The effective dose equivalent to the maximally exposed individual member of the public was 3.02 E-02 mrem per year, 0.30 percent of the 10 mrem standard.

  20. Radionuclide air emission report for the Hanford Site Calendar Year 1993

    SciTech Connect

    Diediker, L.P.; Curn, B.L.; Rhoads, K.; Damberg, E.G.; Soldat, J.K.; Jette, S.J.

    1994-08-01

    This report documents radionuclide air emissions from the Hanford Site in 1993 and the resulting effective dose equivalent to any member of the public. The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, {open_quotes}National Emissions Standards for Hazardous Air Pollutants,{close_quotes} Subpart H, {open_quotes}National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.{close_quotes}

  1. Comparing the VOC emissions between air-dried and heat-treated Scots pine wood

    NASA Astrophysics Data System (ADS)

    Manninen, Anne-Marja; Pasanen, Pertti; Holopainen, Jarmo K.

    The emissions of volatile organic compounds (VOCs) from air-dried Scots pine wood and from heat-treated Scots pine wood were compared with GC-MS analysis. Air-dried wood blocks released about 8 times more total VOCs than heat-treated (24 h at 230°C) ones. Terpenes were clearly the main compound group in the air-dried wood samples, whereas aldehydes and carboxylic acids and their esters dominated in the heat-treated wood samples. Only 14 compounds out of 41 identified individual compounds were found in both wood samples indicating considerable changes in VOC emission profile during heat-treatment process. Of individual compounds α-pinene, 3-carene and hexanal were the most abundant ones in the air-dried wood. By contrast, in the heat-treated wood 2-furancarboxaldehyde, acetic acid and 2-propanone were the major compounds of VOC emission. Current emission results reveal that significant chemical changes have occurred, and volatile monoterpenes and other low-molecular-weight compounds have evaporated from the wood during the heat-treatment process when compared to air-dried wood. Major chemical changes detected in VOC emissions are explained by the thermal degradation and oxidation of main constituents in wood. The results suggest that if heat-treated wood is used in interior carpentry, emissions of monoterpenes are reduced compared to air-dried wood, but some irritating compounds might be released into indoor air.

  2. Importance of transboundary transport of biomass burning emissions to regional air quality in Southeast Asia

    NASA Astrophysics Data System (ADS)

    Aouizerats, B.; van der Werf, G. R.; Balasubramanian, R.; Betha, R.

    2014-05-01

    Smoke from biomass and peat burning has a notable impact on ambient air quality and climate in the Southeast Asia (SEA) region. We modeled the largest fire-induced haze episode in the past decade (2006) in Indonesia using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem). We focused mainly on the evolution of the fire plume composition and its interaction with the urbanized area of the city-state of Singapore, and on comparisons of modeled and measured aerosol and CO concentrations. Two simulations were run with the model using the complex Volatility Basis Set (VBS) scheme to reproduce primary and secondary aerosol evolution and concentration. The first simulation referred to as WRF-FIRE included anthropogenic, biogenic, and b iomass burning emissions from the Global Fire Emissions Database (GFED3) while the second simulation referred to as WRF-NOFIRE was run without emissions from biomass burning. To test model performance, we used three independent datasets for comparison including airborne measurements of Particulate Matter with a diameter of 10 μm or less (PM10) in Singapore, CO measurements in Sumatra, and Aerosol Optical Depth (AOD) column observations from 4 satellite-based sensors. We found reasonable agreement of the model runs with both ground-based measurements of CO and PM10. The comparison with AOD was less favorable and indicated the model underestimated AOD, although the degree of mismatch varied between different satellite data sets. During our study period, forest and peat fires in Sumatra were the main cause of enhanced aerosol concentrations from regional transport over Singapore. Analysis of the biomass burning plume showed high concentrations of primary organic aerosols (POA) with values up to 600 μg m-3 over the fire locations. The concentration of POA remained quite stable within the plume between the main burning region and Singapore while secondary organic aerosol (SOA) concentration slightly increased. The

  3. Impacts of reductions in emissions of multipollutants over 2005-2030 on regional air quality and climate

    NASA Astrophysics Data System (ADS)

    Liao, H.; Yang, Y.; Chang, W.; Shindell, D. T.; Faluvegi, G.

    2011-12-01

    Many societal activities lead to emissions to the atmosphere that affect both air quality and climate. We examine how particular policies may be able to provide benefits in both these areas using three coupled global chemistry-climate models (CACTUS, GISS-PUCCINI, and NCAR-CESM). The anthropogenic emissions for years 2005 and 2030 are taken from the datasets generated by the International Institute for Applied Systems Analysis (IIASA) GAINS (Greenhouse gas-Air pollution Interactions and Synergies) model. The 2030 emissions scenarios include (1) a reference scenario, (2) a low GWP scenario, and (3) the lowest emissions scenario. The reference scenario assumes that all agreed air pollution policies are being implemented, and the other two scenarios have additional reductions in emissions based on a selected set of measures. We firstly evaluate the model predictions for 2005, and then investigate the simulated year 2030 concentrations of ozone, sulfate, black carbon, and organic carbon, aerosol optical depth, as well as year 2030 radiative forcing relative to 2005. Both direct and indirect radiative forcings of aerosols are considered. Our model results suggest that taking measures to reduce emissions in China can reduce year 2030 PM2.5 concentrations in China by 20-60% and help to mitigate near-term regional climate change.

  4. Characterization of Early Stage Marcellus Shale Development Atmospheric Emissions and Regional Air Quality Impacts using Fast Mobile Measurements

    NASA Astrophysics Data System (ADS)

    Goetz, J. D.; Floerchinger, C. R.; Fortner, E.; Wormhoult, J.; Massoli, P.; Herndon, S. C.; Kolb, C. E., Jr.; Knighton, W. B.; Shaw, S. L.; Knipping, E. M.; DeCarlo, P. F.

    2014-12-01

    The Marcellus shale is the largest shale gas resource in the United States and is found in the Appalachian region. Rapid large-scale development, and the scarcity of direct air measurements make the impact of Marcellus shale development on local and regional air quality and the global climate highly uncertain. Air pollutant and greenhouse gas emission sources include transitory emission from well pad development as well as persistent sources including the processing and distribution of natural gas. In 2012, the Aerodyne Inc. Mobile Laboratory was equipped with a suite of real-time (~ 1 Hz) instrumentation to measure source emissions associated with Marcellus shale development and to characterize regional air quality in the Marcellus basin. The Aerodyne Inc. Mobile Laboratory was equipped to measure methane, ethane, N2O (tracer gas), C2H2 (tracer gas), CO2, CO, NOx, aerosols (number, mass, and composition), and VOC including light aromatic compounds and constituents of natural gas. Site-specific emissions from Marcellus shale development were quantified using tracer release ratio methods. Emissions of sub-micron aerosol mass and VOC were generally not observed at any tracer release site, although particle number concentrations were often enhanced. Compressor stations were found to have the largest emission rates of combustion products with NOx emissions ranging from 0.01 to 1.6 tons per day (tpd) and CO emissions ranging from 0.03 to 0.42 tpd. Transient sources, including a well site in the drill phase, were observed to be large emitters of natural gas. The largest methane emissions observed in the study were at a flowback well completion with a value of 7.7 tpd. Production well pads were observed to have the lowest emissions of natural gas and the emission of combustion products was only observed at one of three well pads investigated. Regional background measurements of all measured species were made while driving between tracer release sites and while stationary

  5. Characteristics of emissions of air pollutants from burning of incense in temples, Hong Kong.

    PubMed

    Wang, B; Lee, S C; Ho, K F; Kang, Y M

    2007-05-01

    Field investigations of target air pollutants at two of the most famous temples in Hong Kong were conducted. The air pollution problems in these two temples during peak and non-peak periods were characterized. The target air pollutants included particulate matters (PM(10), PM(2.5)), volatile organic compounds (VOCs), carbonyl compounds, carbon monoxide (CO), nitrogen oxides (NO(x)), methane (CH(4)), non-methane hydrocarbons (NMHC), organic carbon (OC), elemental carbon (EC), and inorganic ions (Cl(-), NO(3)(-), SO(4)(2-), Na(+), NH(4)(+), and K(+)). The pollutant levels of the two temples during peak period were shown to be significantly higher than those during non-peak period. The highest average CO level was obtained at Temple 1 during peak period, which exceeded IAQO 8-h Good Class criteria. In general, the average PM(2.5)/PM(10) ratios were approximately 82%. The results revealed that the fine particulates (PM(2.5)) constituted the majority of suspended particulates at both temples. It was noted that formaldehyde was the most abundant carbonyl compounds, followed by acetaldehyde. At Temple 1 during peak period, the average benzene concentration exceeded almost 8 times more than Indoor Air Quality Objectives for Office Buildings and Public Places (IAQO) [HKEPD, 2003. Guidance notes for the management of indoor air quality in offices and public places. Indoor air quality management group, The Government of the Hong Kong Special Administrative Region.] Good Class criteria. The average OC/EC ratios ranged from 2.6 to 17 in PM(10) and from 4.2 to 18 in PM(2.5) at two temples, which suggested that OC measured in these two temple areas may be due to both direct emission from incense burning and secondary formation by chemical reactions. The total mass of inorganic ions, organic carbon, and elemental carbon accounted for about 71% in PM(2.5) and 72% in PM(10).

  6. Fuel Savings and Emission Reductions from Next-Generation Mobile Air Conditioning Technology in India: Preprint

    SciTech Connect

    Chaney, L.; Thundiyil, K.; Chidambaram, S.; Abbi, Y. P.; Anderson, S.

    2007-05-01

    This paper quantifies the mobile air-conditioning fuel consumption of the typical Indian vehicle, exploring potential fuel savings and emissions reductions these systems for the next generation of vehicles.

  7. 77 FR 60341 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-03

    ... Source Performance Standards for Stationary Internal Combustion Engines'' (77 FR 33812). The June 7, 2012... Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion... Emission Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal......

  8. 75 FR 10184 - National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Paints and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-05

    ..., and binders into paints and other coatings, such as stains, varnishes, lacquers, enamels, shellacs... Standards for Paints and Allied Products Manufacturing-- Technical Amendment AGENCY: Environmental...; National Emission Standards for Hazardous Air Pollutants: Paints and Allied Products Manufacturing...

  9. CAPSULE REPORT: SOURCES AND AIR EMISSION CONTROL TECHNOLOGIES AT WASTE MANAGEMENT FACILITIES

    EPA Science Inventory

    The chemicals processed during waste management operations can volatilize into the atmosphere and cause carcinogenic or other toxic effects or contribute to ozone formation. Regulations have been developed to control air emissions from these operations. The EPA has promulgated st...

  10. Establishment of a high-resolution emission inventory and its impact assessment on air quality modeling in Jiangsu Province, China

    NASA Astrophysics Data System (ADS)

    Zhou, Y.; Zhao, Y.

    2015-12-01

    A high-resolution emission inventory of Jiangsu Province was developed for 2012, using the bottom-up method with the best available domestic emission factors and activity data incorporated. Information of over 6,000 point sources including geographical location, fuel type, burner type and removal efficiency were investigated from various available data sources. The point sources were estimated to account for 83.9%, 71.2%, 63.7% and 54.5% of the total SO2, NOx, PM2.5 and VOCs emissions respectively. Improvement of this provincial emission inventory was assessed by comparisons with emission estimation at national level. For SO2 from power plants, NOx from transportation and PM2.5 from industry, correlation coefficients were 0.703, 0.814 and 0.335, indicated other than power plants and transportation, there was an improvement in estimation of small industrial pollution sources which were usually estimated as area sources in national emission inventory. Correlation analysis of NOx emission and tropospheric NO2 vertical column density measured by Ozone Monitoring Instrument (OMI) were also conducted. The correlation coefficient rose from 0.52 to 0.57 after revisions on geographical locations of 20 large point sources. Such result indicated the local source information from Environmental Statistics should be carefully examined before it can be applied for emission inventory development. In order to assess the improvement in spatial distribution and emission estimation on air quality modeling, the provincial and national emission inventory were input to Community Multi-scale Air Quality Model (CMAQ) simulations. Simulations performed better when emissions were updated from Multi-resolution Emission Inventory for China (MEIC) to provincial inventory, indicating the necessity of improved spatial and temporal distribution of emissions on air quality modeling, especially for gaseous pollutants. For SO2, the normalized mean bias (NMB) and normalized mean error (NME) decreased

  11. Radioactive air emissions notice of construction for the Waste Receiving And Processing facility

    SciTech Connect

    Not Available

    1993-02-01

    The mission of the Waste Receiving And Processing (WRAP) Module 1 facility (also referred to as WRAP 1) includes: examining, assaying, characterizing, treating, and repackaging solid radioactive and mixed waste to enable permanent disposal of the wastes in accordance with all applicable regulations. The solid wastes to be handled in the WRAP 1 facility include low-level waste (LLW), transuranic (TRU) waste, TRU mixed wastes, and low-level mixed wastes (LLMW). Airborne releases from the WRAP 1 facility will be primarily in particulate forms (99.999 percent of total unabated emissions). The release of two volatilized radionuclides, tritium and carbon-14 will contribute less than 0.001 percent of the total unabated emissions. Table 2-1 lists the radionuclides which are anticipated to be emitted from WRAP 1 exhaust stack. The Clean Air Assessment Package 1988 (CAP-88) computer code (WHC 1991) was used to calculate effective dose equivalent (EDE) from WRAP 1 to the maximally exposed offsite individual (MEI), and thus demonstrate compliance with WAC 246-247. Table 4-1 shows the dose factors derived from the CAP-88 modeling and the EDE for each radionuclide. The source term (i.e., emissions after abatement in curies per year) are multiplied by the dose factors to obtain the EDE. The total projected EDE from controlled airborne radiological emissions to the offsite MEI is 1.31E-03 mrem/year. The dose attributable to radiological emissions from WRAP 1 will, then, constitute 0.013 percent of the WAC 246-247 EDE regulatory limit of 10 mrem/year to the offsite MEI.

  12. Radionuclide air emissions report for the Hanford site calendar year 1995

    SciTech Connect

    Gleckler, B.P., Westinghouse Hanford

    1996-06-26

    This report documents radionuclide air emissions from the Hanford Site in 1995, and the resulting effective dose equivalent (FDE) to the maximally exposed member of the public, referred to as the `MEI.` The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, `National Emissions Standards for Hazardous Air Pollutants,` Subpart H, `National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.` This report has also been prepared for and will be submitted in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, `Radiation Protection-Air Emissions.`

  13. Mercury emission trend influenced by stringent air pollutants regulation for coal-fired power plants in Korea

    NASA Astrophysics Data System (ADS)

    Pudasainee, Deepak; Kim, Jeong-Hun; Seo, Yong-Chil

    2009-12-01

    Regulatory control of mercury emission from anthropogenic sources has become a global concern in the recent past. Coal-fired power plants are one of the largest sources of anthropogenic mercury emission into the atmosphere. This paper summarizes the current reducing trend of mercury emission as co-beneficial effect by more stringent regulation changes to control primary air pollutants with introducing test results from the commercial coal-fired facilities and suggesting a guideline for future regulatory development in Korea. On average, mercury emission concentrations ranged 16.3-2.7 μg Sm -3, 2.4-1.1 μg Sm -3, 3.1-0.7 μg Sm -3 from anthracite coal-fired power plants equipped with electrostatic precipitator (ESP), bituminous coal-fired power plants with ESP + flue gas desulphurization (FGD) and bituminous coal-fired power plants with selective catalytic reactor (SCR) + cold side (CS) - ESP + wet FGD, respectively. Among the existing air pollution control devices, the best configuration for mercury removal in coal-fired power plants was SCR + CS - ESP + wet FGD, which were installed due to the stringent regulation changes to control primary air pollutants emission such as SO 2, NOx and dust. It was estimated that uncontrolled and controlled mercury emission from coal-fired power plants as 10.3 ton yr -1 and 3.2 ton yr -1 respectively. After the installation of ESP, FGD and SCR system, following the enforcement of the stringent regulation, 7.1 ton yr -1 of mercury emission has been reduced (nearly 69%) from coal-fired power plants as a co-benefit control. Based on the overall study, a sample guideline including emission limits were suggested which will be applied to develop a countermeasure for controlling mercury emission from coal-fired power plants.

  14. Theoretical and Experimental Investigation of Heat Conduction in Air, Including Effects of Oxygen Dissociation

    NASA Technical Reports Server (NTRS)

    Hansen, C. Frederick; Early, Richard A.; Alzofon, Frederick E.; Witteborn, Fred C.

    1959-01-01

    Solutions are presented for the conduction of beat through a semi-infinite gas medium having a uniform initial temperature and a constant boundary temperature. The coefficients of thermal conductivity and diffusivity are treated as variables, and the solutions are extended to the case of air at temperatures where oxygen dissociation occurs. These solutions are used together with shock-tube measurements to evaluate the integral of thermal conductivity for air as a function of temperature.

  15. EMISSIONS PROCESSING FOR THE ETA/ CMAQ AIR QUALITY FORECAST SYSTEM

    EPA Science Inventory

    NOAA and EPA have created an Air Quality Forecast (AQF) system. This AQF system links an adaptation of the EPA's Community Multiscale Air Quality Model with the 12 kilometer ETA model running operationally at NOAA's National Center for Environmental Predication (NCEP). One of the...

  16. EDGAR_v4.3: a global air pollutant emission inventory from 1970 to 2010

    NASA Astrophysics Data System (ADS)

    Crippa, M.; Janssens-Maenhout, G.; Guizzardi, D.; Muntean, M.; Schaaf, E.; Olivier, J. G.; Denier Van Der Gon, H.; Dentener, F. J.

    2014-12-01

    The Emission Database for Global Atmospheric Research (EDGAR) provides consistent gridded anthropogenic emissions of greenhouse gases, precursor gases and aerosols from 1970 to 2010. Since EDGAR's first release in 1996 (EDGARv2), a continuous improvement and upgrade of the emission data resulted in a sequence of releases. Here we present EDGAR_v4.3 (2014), which features new information on emission factors and an extension to 2009-2010 data compared to EDGAR_v4.2. EDGAR_v4.2 was used in many inverse modeling studies in EU, US, Africa and Asia yielding regional refinement of emission factors and adjustments of technology penetration (e.g. coal mining, power plants) and proxy data for geospatial distribution (e.g. passenger car transport). We focus on SO2, NOx, CO, NMVOC, NH3, PM10, PM2.5, BC and OC emissions for the most recent year (2010), and compare them to two global inventories used in global modeling, as well as the regional inventories included in them. HTAP_v2 is a harmonized, global, gridded, emission database for 2010, developed for global and regional model tasks within the Task Force Hemispheric Transport Air pollution. It uses officially reported, gridded national inventories, complemented with science based data, partly gap-filled with EDGAR. However, since HTAP_v2 is relying on (sub-)national statistics, it may not be as consistent across countries and regions, as a globally calculated inventory using international statistics and global geospatial distributions. Another available global inventory is MACCity, covering the years 1980-2010. We compare EDGAR_v4.3 with HTAP_v2 and MACCity in order to explain differences from national estimates and address emission inventory uncertainties, indicating weaknesses and strengths of these databases. We present the geospatial distribution of emissions at 0.1x0.1 degree resolution, comparing the contribution of developing and emerging countries with industrialized regions, both as absolute and per capita data.

  17. Compilation of air pollutant emission factors, supplement 12

    SciTech Connect

    Not Available

    1981-04-01

    Revised or updated data are presented for dry cleaning: surface coating, storage of organic liquids, solvent degreasing, graphic arts, consumer/commercial solvent use, sulfuric acid, beer making, ammonium sulfate, primary aluminum, secondary aluminum, gray iron foundries, steel foundries, secondary zinc, asphaltic concrete, asphalt roofing, NEDS source classification codes and emission factor listing, and table of lead emission factors.

  18. Research Spotlight: Satellites monitor air pollutant emissions in China

    NASA Astrophysics Data System (ADS)

    Tretkoff, Ernie

    A new satellite study verifies that Chinese emission control efforts did reduce power plant emissions of sulfur dioxide (SO2), a harmful gas that causes acid rain and can form sulfate aerosols; these aerosols play an important role in the climate system by affecting clouds and precipitation patterns and altering the amount of sunlight that is reflected away from Earth.

  19. Effects of Coaxial Air on Nitrogen-Diluted Hydrogen Jet Diffusion Flame Length and NOx Emission

    SciTech Connect

    Weiland, N.T.; Chen, R.-H.; Strakey, P.A.

    2007-10-01

    Turbulent nitrogen-diluted hydrogen jet diffusion flames with high velocity coaxial air flows are investigated for their NOx emission levels. This study is motivated by the DOE turbine program’s goal of achieving 2 ppm dry low NOx from turbine combustors running on nitrogen-diluted high-hydrogen fuels. In this study, effects of coaxial air velocity and momentum are varied while maintaining low overall equivalence ratios to eliminate the effects of recirculation of combustion products on flame lengths, flame temperatures, and resulting NOx emission levels. The nature of flame length and NOx emission scaling relationships are found to vary, depending on whether the combined fuel and coaxial air jet is fuel-rich or fuel-lean. In the absence of differential diffusion effects, flame lengths agree well with predicted trends, and NOx emissions levels are shown to decrease with increasing coaxial air velocity, as expected. Normalizing the NOx emission index with a flame residence time reveals some interesting trends, and indicates that a global flame strain based on the difference between the fuel and coaxial air velocities, as is traditionally used, is not a viable parameter for scaling the normalized NOx emissions of coaxial air jet diffusion flames.

  20. Estimation of monetary values of air pollutant emissions in various US areas

    SciTech Connect

    Wang, M.Q.; Santini, D.J.

    1994-08-17

    Two general methods of estimating monetary values of air pollutants are presented in this paper. The damage estimate method directly estimated, air pollutant by simulating air quality, identifying health and other welfare impacts damage values and valuing the identified impacts of air pollution, and valuing the identified impacts. Although the method is theoretically sound, many assumptions are involved in each of its estimation steps, and uncertainty exists in each step. The control cost estimate method estimates the marginal emission control cost, which represents the opportunity cost offset by emission reductions from some given control measures. Studies conducted to estimate emission values in US regions used either the damage estimate method or the control cost estimate method. Taking emission values estimated for some US air basins, this paper establishes regression relationships between emission values and total population and air pollutant concentrations. On the basis of the established relationships, both damage-based and control-cost-based emission values are estimated for 17 major US urban areas.

  1. Air emissions from exposed contaminated sediments and dredged material

    SciTech Connect

    Valsaraj, K.T.; Ravikrishna, R.; Reible, D.D.; Thibodeaux, L.J.; Choy, B.; Price, C.B.; Brannon, J.M.; Myers, T.E.; Yost, S.

    1999-01-01

    The sediment-to-air fluxes of two polycyclic aromatic hydrocarbons (phenanthrene and pyrene) and a heterocyclic aromatic hydrocarbon (dibenzofuran) from a laboratory-contaminated sediment and those of three polycyclic aromatic hydrocarbons (naphthalene, phenanthrene, and pyrene) from three field sediments were investigated in experimental microcosms. The flux was dependent on the sediment moisture content, air-filled porosity, and the relative humidity of the air flowing over the sediment surface. The mathematical model predictions of flux from the laboratory-spiked sediment agreed with observed values. The fluxes of compounds with higher hydrophobicity were more air-side resistance controlled. Conspicuous differences were observed between the fluxes from the laboratory-spiked and two of the three field sediments. Two field sediments showed dramatic increases in mass-transfer resistances with increasing exposure time and had significant fractions of oil and grease. The proposed mathematical model was inadequate for predicting the flux from the latter field sediments. Sediment reworking enhanced the fluxes from the field sediments due to exposure of fresh solids to the air. Variations in flux from the lab-spiked sediment as a result of change in air relative humidity were due to differences in retardation of chemicals on a dry or wet surface sediment. High moisture in the air over the dry sediment increased the competition for sorption sites between water and contaminant and increased the contaminant flux.

  2. “Exchanges of Aggregate Air Nitrogen Emissions and Watershed Nitrogen Loads”

    EPA Science Inventory

    An approach has been developed to define transfer coefficients that can be used to convert changes in air emissions to changes in air deposition and subsequently to changes in loads delivered to the Bay. This approach uses a special CMAQ version that quantitatively attributes wa...

  3. 78 FR 59317 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Revision to Emission...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-26

    ... Implementation Plan (SIP). The revision pertains to revised emission limitations for the R. Paul Smith Power... section 110 of the Clean Air Act. DATES: The proposed rule published on June 18, 2010 (75 FR 34670), is... AGENCY 40 CFR Part 52 Approval and Promulgation of Air Quality Implementation Plans; Maryland;...

  4. 75 FR 34670 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Revision to Emission...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-18

    ... Smith Power Station located in Washington County. This action is being taken under the Clean Air Act... AGENCY 40 CFR Part 52 Approval and Promulgation of Air Quality Implementation Plans; Maryland; Revision to Emission Limitations for R. Paul Smith Power Station AGENCY: Environmental Protection Agency...

  5. Dynamic Evaluation of a Regional Air Quality Model: Assessing the Emissions-Induced Weekly Ozone Cycle

    EPA Science Inventory

    Air quality models are used to predict changes in pollutant concentrations resulting from envisioned emission control policies. Recognizing the need to assess the credibility of air quality models in a policy-relevant context, we perform a dynamic evaluation of the community Mult...

  6. EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN BURNING: A COMPREHENSIVE REVIEW

    EPA Science Inventory

    A detailed literature search was performed to collect and collate available data reporting emissions of organic air toxics from open burning sources. Availability of data varied according to the source and the class of air toxics of interest, and there were several sources for wh...

  7. 76 FR 38591 - National Emission Standards for Hazardous Air Pollutants: Secondary Lead Smelting; Extension of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-01

    ... the National Emissions Standards for Hazardous Air Pollutants for Secondary Lead Smelting (76 FR 29032... Standards for Hazardous Air Pollutants: Secondary Lead Smelting, was published May 19, 2011 (76 FR 29032... current rule. DATES: Comments on the proposed rule published May 19, 2011 (76 FR 29032) must be...

  8. 40 CFR 86.166-12 - Method for calculating emissions due to air conditioning leakage.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... determine a refrigerant leakage rate in grams per year from vehicle-based air conditioning units. The... using the following equation: Grams/YRTOT = Grams/YRRP + Grams/YRSP + Grams/YRFH + Grams/YRMC + Grams/YRC Where: Grams/YRTOT = Total air conditioning system emission rate in grams per year and rounded...

  9. 40 CFR 62.14107 - Emission limits for air curtain incinerators.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... incinerators. 62.14107 Section 62.14107 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... 20, 1994 § 62.14107 Emission limits for air curtain incinerators. The owner or operator of an air curtain incinerator with the capacity to combust greater than 250 tons per day of municipal solid...

  10. 40 CFR 62.14107 - Emission limits for air curtain incinerators.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... incinerators. 62.14107 Section 62.14107 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... 20, 1994 § 62.14107 Emission limits for air curtain incinerators. The owner or operator of an air curtain incinerator with the capacity to combust greater than 250 tons per day of municipal solid...

  11. 40 CFR 62.14107 - Emission limits for air curtain incinerators.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... incinerators. 62.14107 Section 62.14107 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... 20, 1994 § 62.14107 Emission limits for air curtain incinerators. The owner or operator of an air curtain incinerator with the capacity to combust greater than 250 tons per day of municipal solid...

  12. 40 CFR 62.14107 - Emission limits for air curtain incinerators.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... incinerators. 62.14107 Section 62.14107 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... 20, 1994 § 62.14107 Emission limits for air curtain incinerators. The owner or operator of an air curtain incinerator with the capacity to combust greater than 250 tons per day of municipal solid...

  13. 40 CFR 62.14107 - Emission limits for air curtain incinerators.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... incinerators. 62.14107 Section 62.14107 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... 20, 1994 § 62.14107 Emission limits for air curtain incinerators. The owner or operator of an air curtain incinerator with the capacity to combust greater than 250 tons per day of municipal solid...

  14. Air emissions due to wind and solar power.

    PubMed

    Katzenstein, Warren; Apt, Jay

    2009-01-15

    Renewables portfolio standards (RPS) encourage large-scale deployment of wind and solar electric power. Their power output varies rapidly, even when several sites are added together. In many locations, natural gas generators are the lowest cost resource available to compensate for this variability, and must ramp up and down quickly to keep the grid stable, affecting their emissions of NOx and CO2. We model a wind or solar photovoltaic plus gas system using measured 1-min time-resolved emissions and heat rate data from two types of natural gas generators, and power data from four wind plants and one solar plant. Over a wide range of renewable penetration, we find CO2 emissions achieve approximately 80% of the emissions reductions expected if the power fluctuations caused no additional emissions. Using steam injection, gas generators achieve only 30-50% of expected NOx emissions reductions, and with dry control NOx emissions increase substantially. We quantify the interaction between state RPSs and NOx constraints, finding that states with substantial RPSs could see significant upward pressure on NOx permit prices, if the gas turbines we modeled are representative of the plants used to mitigate wind and solar power variability.

  15. 18Fluorodeoxyglucose positron emission tomography studies in presumed Alzheimer cases, including 13 serial scans.

    PubMed

    McGeer, E G; Peppard, R P; McGeer, P L; Tuokko, H; Crockett, D; Parks, R; Akiyama, H; Calne, D B; Beattie, B L; Harrop, R

    1990-02-01

    Positron emission tomographic (PET) data on local cerebral metabolic rates for glucose (LCMR) are reported for 32 regions of interest (ROI)s in cross-sectional studies on 57 patients with clinically diagnosed Alzheimer's disease (AD) and 20 neurologically normal controls, and in serial studies on 13 of the AD cases, including a familial, young-onset case where the diagnosis has been confirmed at autopsy. Extensive psychological testing was done on all the AD cases. Almost all cortical regions showed a significant decline in LCMR with age in the control subjects. There were the expected cortical metabolic deficits in AD and the serial studies showed a general increase in such deficits over time in 12 of the 13 cases. The regions showing the greatest declines with time in serial studies are the same as those showing the most severe deficiencies in cross-sectional studies. The young-onset case did not show a greater rate of metabolic decline than many of the older cases studied. Results on individual psychological tests tended to correlate with metabolic rates in multiple, rather than single, cortical regions, suggesting intact neuronal networks are required for good performance. The correlations with cortical metabolic activity found were of a sign indicating that the higher the metabolic rates and the better the left:right asymmetry index, the better was the performance.

  16. DEVELOPMENT OF HAZARDOUS AIR POLLUTANT EMISSION FACTORS FROM STATE SOURCE TEST PROGRAMS

    EPA Science Inventory

    The report gives results of a study in which emission factors were evolved from test data obtained from several Air Quality Management Districts in California and from state environmental agencies in Louisiana, Maryland, New Jersey, and Texas. The emission factors were developed...

  17. EMISSIONS FROM THE BURNING OF VEGETATIVE DEBRIS IN AIR CURTAIN DESTRUCTORS

    EPA Science Inventory

    Although no data has been published on emissions from construction and demolition (C&D) debris burned in an air curtain destructor (ACD), a few studies provide information on emissions from combustion of vegetative debris. These results are compared to studies of open burning of...

  18. Emissions of greenhouse gases and air pollutants from commercial aircraft at international airports in Korea

    NASA Astrophysics Data System (ADS)

    Song, Sang-Keun; Shon, Zang-Ho

    2012-12-01

    The emissions of greenhouse gases (GHGs) and air pollutants from aircraft in the boundary layer at four major international airports in Korea over a two-year period (2009-2010) were estimated using the Emissions and Dispersion Modeling System (EDMS) (i.e. activity-based (Landing/Take-Off (LTO) cycle) methodology). Both domestic and international LTOs and ground support equipment at the airports were considered. The average annual emissions of GHGs (CO2, N2O, CH4 and H2O) at all four airports during the study period were 1.11 × 103, 1.76 × 10-2, -1.85 × 10-3 and 3.84 × 108 kt yr-1, respectively. The emissions of air pollutants (NOx, CO, VOCs and particulate matter) were 5.20, 4.12, 7.46 × 10-1 and 3.37 × 10-2 kt yr-1, respectively. The negative CH4 emission indicates the consumption of atmospheric CH4 in the engine. The monthly and daily emissions of GHGs and air pollutants showed no significant variations at all airports examined. The emissions of GHGs and air pollutants for each aircraft operational mode differed considerably, with the largest emission observed in taxi-out mode.

  19. 78 FR 25242 - Delegation of New Source Performance Standards and National Emission Standards for Hazardous Air...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-30

    ... AGENCY 40 CFR Parts 60 and 61 Delegation of New Source Performance Standards and National Emission... Source Performance Standards (NSPS) and National Emission Standards for Hazardous Air Pollutants (NESHAP... identity or contact information unless you provide it in the body of your comment. If you send...

  20. [Implementation results of emission standards of air pollutants for thermal power plants: a numerical simulation].

    PubMed

    Wang, Zhan-Shan; Pan, Li-Bo

    2014-03-01

    The emission inventory of air pollutants from the thermal power plants in the year of 2010 was set up. Based on the inventory, the air quality of the prediction scenarios by implementation of both 2003-version emission standard and the new emission standard were simulated using Models-3/CMAQ. The concentrations of NO2, SO2, and PM2.5, and the deposition of nitrogen and sulfur in the year of 2015 and 2020 were predicted to investigate the regional air quality improvement by the new emission standard. The results showed that the new emission standard could effectively improve the air quality in China. Compared with the implementation results of the 2003-version emission standard, by 2015 and 2020, the area with NO2 concentration higher than the emission standard would be reduced by 53.9% and 55.2%, the area with SO2 concentration higher than the emission standard would be reduced by 40.0%, the area with nitrogen deposition higher than 1.0 t x km(-2) would be reduced by 75.4% and 77.9%, and the area with sulfur deposition higher than 1.6 t x km(-2) would be reduced by 37.1% and 34.3%, respectively.

  1. National Emission Standards for Hazardous Air Pollutants Calendar Year 2001

    SciTech Connect

    Y. E. Townsend

    2002-06-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Operations Office (NNSA/NV) as the site for nuclear weapons testing, now limited to readiness activities, experiments in support of the national Stockpile Stewardship Program, and the activities listed below. Located in Nye County, Nevada, the site's southeast corner is about 88 km (55 mi) northwest of the major population center, Las Vegas, Nevada. The NTS covers about 3,561 km2 (1,375 mi2), an area larger than Rhode Island. Its size is 46 to 56 km (28 to 35 mi) east to west and from 64 to 88 km (40 to 55 mi) north to south. The NTS is surrounded, except on the south side, by public exclusion areas (Nellis Air Force Range [NAFR]) that provide another 24 to 104 km (15 to 65 mi) between the NTS and public lands (Figure 1.0). The NTS is characterized by desert valley and Great Basin mountain topography, with a climate, flora, and fauna typical of the southwest deserts. Population density within 150 km (93 mi) of the NTS is only about 0.2 persons per square kilometer, excluding the Las Vegas area. Restricted access, low population density in the surrounding area, and extended wind transport times are advantageous factors for the activities conducted at the NTS. Surface waters are scarce on the NTS, and slow-moving groundwater is present hundreds to thousands of feet below the land surface. The sources of radionuclides include current and previous activities conducted on the NTS (Figure 2.0). The NTS was the primary location for testing of nuclear explosives in the Continental U.S. between 1951 and 1992. Historical testing above or at ground surface has included (1) atmospheric testing in the 1950s and early 1960s, (2) earth-cratering experiments, and (3) open-air nuclear reactor and rocket engine testing. Since the mid-1950s, testing of nuclear explosive devices has occurred underground in drilled vertical holes or in mined tunnels (DOE 1996a

  2. Study of air emissions related to aircraft deicing

    SciTech Connect

    Zarubiak, D.C.Z.; DeToro, J.A.; Menon, R.P.

    1997-12-31

    This paper outlines the results of a study that was conducted by Trinity Consultants Incorporated (Trinity) to estimate the airborne emissions of glycol from Type 1 Deicer fluid and potential exposure of ground personnel during routine deicing of aircraft. The study involved the experimental measurement of Type 1 Deicer fluid vapor emissions by Southern Research Institute (SRI, Research Triangle Park, NC). An open path Fourier Transform Infrared (FTIR) spectroscopic technique developed by SRI was used during a simulated airplane deicing event. The emissions measurement data are analyzed to obtain appropriate emission rates for an atmospheric dispersion modeling analysis. The modeled gaseous Type 1 Deicer fluid concentrations are determined from calculated emission rates and selected meteorological conditions. A propylene glycol (PG)-based Type 1 Deicer fluid was used. In order to examine the effects of the assumptions that are made for the development of the emission quantification and dispersion modeling methodologies, various scenarios are evaluated. A parametric analysis evaluates the effect of variations in the following parameters on the results of the study: glycol concentrations in deicing fluids, error limits of emission measurements, emission source heights, evaporation rate for various wind speeds, wind directions over typical physical layouts, and background (ambient) Type 1 Deicer fluid concentrations. The emissions for an EG based Type 1 Deicing fluid are expected to be between 80 and 85% of the reported data. In general, the model shows the region of maximum concentrations is located between 20 and 50 meters downwind from the trailing edge of the wing. This range is consistent with experimental findings. Depending on the specific modeled scenarios, maximum glycol concentrations are found to generally range between 50 and 500 milligrams per cubic meter.

  3. Modelling the emissions from ships in ports and their impact on air quality in the metropolitan area of Hamburg

    NASA Astrophysics Data System (ADS)

    Ramacher, Martin; Karl, Matthias; Aulinger, Armin; Bieser, Johannes; Matthias, Volker; Quante, Markus

    2016-04-01

    Exhaust emissions from shipping contribute significantly to the anthropogenic burden of air pollutants such as nitrogen oxides (NOX) and particulate matter (PM). Ships emit not only when sailing on open sea, but also when approaching harbors, during port manoeuvers and at berth to produce electricity and heat for the ship's operations. This affects the population of harbor cities because long-term exposure to PM and NOX has significant effects on human health. The European Union has therefore has set air quality standards for air pollutants. Many port cities have problems meeting these standards. The port of Hamburg with around 10.000 ship calls per year is Germany's largest seaport and Europe's second largest container port. Air quality standard reporting in Hamburg has revealed problems in meeting limits for NO2 and PM10. The amount and contribution of port related ship emissions (38% for NOx and 17% for PM10) to the overall emissions in the metropolitan area in 2005 [BSU Hamburg (2012): Luftreinhalteplan für Hamburg. 1. Fortschreibung 2012] has been modelled with a bottom up approach by using statistical data of ship activities in the harbor, technical vessel information and specific emission algorithms [GAUSS (2008): Quantifizierung von gasförmigen Emissionen durch Maschinenanlagen der Seeschiffart an der deutschen Küste]. However, knowledge about the spatial distribution of the harbor ship emissions over the city area is crucial when it comes to air quality standards and policy decisions to protect human health. Hence, this model study examines the spatial distribution of harbor ship emissions (NOX, PM10) and their deposition in the Hamburg metropolitan area. The transport and chemical transformation of atmospheric pollutants is calculated with the well-established chemistry transport model TAPM (The Air Pollution Model). TAPM is a three-dimensional coupled prognostic meteorological and air pollution model with a condensed chemistry scheme including

  4. Nonlinear air-coupled emission: The signature to reveal and image microdamage in solid materials

    SciTech Connect

    Solodov, Igor; Busse, Gerd

    2007-12-17

    It is shown that low-frequency elastic vibrations of near-surface planar defects cause high-frequency ultrasonic radiation in surrounding air. The frequency conversion mechanism is concerned with contact nonlinearity of the defect vibrations and provides efficient generation of air-coupled higher-order ultraharmonics, ultrasubharmonics, and combination frequencies. The nonlinear air-coupled ultrasonic emission is applied for location and high-resolution imaging of damage-induced defects in a variety of solid materials.

  5. Evaluation of speciated VOC emission factors for Air Force hush houses

    SciTech Connect

    Sullivan, P.D.; Stevens, D.K.

    1997-12-31

    Data published in: ``Engine and Hush House Emissions from a TF30-P109 Jet Engine Tested at Cannon Air Force Base, NM`` by Radian Corporation and ``Aircraft Emissions. Characterization: TF41-A2, TF30-P103 , and TF30-P109 Engines`` by Battelle are reviewed and compared. Specifically CO, NO{sub x}, and VOC emission factors using EPA Method 19 are addressed, with comparisons between JP-4 and JP-8 jet fuels. CO and NO{sub x} emissions for JP-4 and JP-8 jet fuels were found to be essentially the same. VOC emission data exhibited high variability. Problems inherent in speciated VOC emission testing are discussed. A limiting of speciated VOC emission testing, with emission factor estimation based on fuel content is proposed.

  6. The AMY experiment: Microwave emission from air shower plasmas

    NASA Astrophysics Data System (ADS)

    Alvarez-Muñiz, J.; Blanco, M.; Boháčová, M.; Buonomo, B.; Cataldi, G.; Coluccia, M. R.; Creti, P.; De Mitri, I.; Di Giulio, C.; Facal San Luis, P.; Foggetta, L.; Gaïor, R.; Garcia-Fernandez, D.; Iarlori, M.; Le Coz, S.; Letessier-Selvon, A.; Louedec, K.; Maris, I. C.; Martello, D.; Mazzitelli, G.; Monasor, M.; Perrone, L.; Petrera, S.; Privitera, P.; Rizi, V.; Rodriguez Fernandez, G.; Salamida, F.; Salina, G.; Settimo, M.; Valente, P.; Vazquez, J. R.; Verzi, V.; Williams, C.

    2016-07-01

    You The Air Microwave Yield (AMY) experiment investigate the molecular bremsstrahlung radiation emitted in the GHz frequency range from an electron beam induced air-shower. The measurements have been performed at the Beam Test Facility (BTF) of Frascati INFN National Laboratories with a 510 MeV electron beam in a wide frequency range between 1 and 20 GHz. We present the apparatus and the results of the tests performed.

  7. Assessment of air pollutant emissions from brick kilns

    NASA Astrophysics Data System (ADS)

    Rajarathnam, Uma; Athalye, Vasudev; Ragavan, Santhosh; Maithel, Sameer; Lalchandani, Dheeraj; Kumar, Sonal; Baum, Ellen; Weyant, Cheryl; Bond, Tami

    2014-12-01

    India has more than 100,000 brick kilns producing around 250 billion bricks annually. Indian brick industry is often a small scale industry and third largest consumer of coal in the country. With the growing demand for building materials and characterised by lack of pollution control measures the brick industry has a potential to cause adverse effects on the environment. This paper presents assessment of five brick making technologies based on the measurements carried out at seventeen individual brick kilns. Emissions of PM, SO2, CO and CO2 were measured and these emissions were used to estimate the emission factors for comparing the emissions across different fuel or operating conditions. Estimated emission from brick kilns in South Asia are about 0.94 million tonnes of PM; 3.9 million tonnes of CO and 127 million tonnes of CO2 per year. Among various technologies that are widely used in India, Zig zag and vertical shaft brick kilns showed better performance in terms of emissions over the traditional fixed chimney Bull's trench kilns. This suggests that the replacement of traditional technologies with Zig zag, vertical shaft brick kilns or other cleaner kiln technologies will contribute towards improvements in the environmental performance of brick kiln industry in the country. Zig zag kilns appear to be the logical replacement because of low capital investment, easy integration with the existing production process, and the possibility of retrofitting fixed chimney Bull's trench kilns into Zig zag firing.

  8. Dynamic evaluation of regional air quality model’s response to emission reductions in the presence of uncertain emission inventories

    NASA Astrophysics Data System (ADS)

    Napelenok, Sergey L.; Foley, Kristen M.; Kang, Daiwen; Mathur, Rohit; Pierce, Thomas; Rao, S. Trivikrama

    2011-08-01

    A method is presented and applied for evaluating an air quality model's changes in pollutant concentrations stemming from changes in emissions while explicitly accounting for the uncertainties in the base emission inventory. Specifically, the Community Multiscale Air Quality (CMAQ) model is evaluated for its ability to simulate the change in ozone (O 3) levels in response to significant reductions in nitric oxide (NO x = NO + NO 2) emissions from the NO x State Implementation Plan (SIP) Call and vehicle fleet turnover between the years of 2002 and 2005. The dynamic model evaluation (i.e., the evaluation of a model's ability to predict changes in pollutant levels given changes in emissions) differs from previous approaches by explicitly accounting for known uncertainties in the NO x emissions inventories. Uncertainty in three sectors of NO x emissions is considered - area sources, mobile sources, and point sources - and is propagated using sensitivity coefficients calculated by the decoupled direct method in three dimensions (DDM-3D). The change in O 3 levels between 2002 and 2005 is estimated based on differences in the empirical distributions of the modeled and observed data during the two years. Results indicate that the CMAQ model is able to reproduce the observed change in daily maximum 8-hr average O 3 levels at more than two-thirds of Air Quality System (AQS) monitoring locations when a relatively moderate amount of uncertainty (50%) is assumed in area and mobile emissions of NO x together with a low amount of uncertainty (3%) in the utility sector (elevated point sources) emissions. The impact of other sources of uncertainty in the model is also briefly explored.

  9. International trade and air pollution: estimating the economic costs of air emissions from waterborne commerce vessels in the United States.

    PubMed

    Gallagher, Kevin P

    2005-10-01

    Although there is a burgeoning literature on the effects of international trade on the environment, relatively little work has been done on where trade most directly effects the environment: the transportation sector. This article shows how international trade is affecting air pollution emissions in the United States' shipping sector. Recent work has shown that cargo ships have been long overlooked regarding their contribution to air pollution. Indeed, ship emissions have recently been deemed "the last unregulated source of traditional air pollutants". Air pollution from ships has a number of significant local, national, and global environmental effects. Building on past studies, we examine the economic costs of this increasing and unregulated form of environmental damage. We find that total emissions from ships are largely increasing due to the increase in foreign commerce (or international trade). The economic costs of SO2 pollution range from dollars 697 million to dollars 3.9 billion during the period examined, or dollars 77 to dollars 435 million on an annual basis. The bulk of the cost is from foreign commerce, where the annual costs average to dollars 42 to dollars 241 million. For NOx emissions the costs are dollars 3.7 billion over the entire period or dollars 412 million per year. Because foreign trade is driving the growth in US shipping, we also estimate the effect of the Uruguay Round on emissions. Separating out the effects of global trade agreements reveals that the trade agreement-led emissions amounted to dollars 96 to dollars 542 million for SO2 between 1993 and 2001, or dollars 10 to dollars 60 million per year. For NOx they were dollars 745 million for the whole period or dollars 82 million per year. Without adequate policy responses, we predict that these trends and costs will continue into the future.

  10. Biomass burning emissions of trace gases and particles in marine air at Cape Grim, Tasmania

    NASA Astrophysics Data System (ADS)

    Lawson, S. J.; Keywood, M. D.; Galbally, I. E.; Gras, J. L.; Cainey, J. M.; Cope, M. E.; Krummel, P. B.; Fraser, P. J.; Steele, L. P.; Bentley, S. T.; Meyer, C. P.; Ristovski, Z.; Goldstein, A. H.

    2015-12-01

    Biomass burning (BB) plumes were measured at the Cape Grim Baseline Air Pollution Station during the 2006 Precursors to Particles campaign, when emissions from a fire on nearby Robbins Island impacted the station. Measurements made included non-methane organic compounds (NMOCs) (PTR-MS), particle number size distribution, condensation nuclei (CN) > 3 nm, black carbon (BC) concentration, cloud condensation nuclei (CCN) number, ozone (O3), methane (CH4), carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2), nitrous oxide (N2O), halocarbons and meteorology. During the first plume strike event (BB1), a 4 h enhancement of CO (max ~ 2100 ppb), BC (~ 1400 ng m-3) and particles > 3 nm (~ 13 000 cm-3) with dominant particle mode of 120 nm were observed overnight. A wind direction change lead to a dramatic reduction in BB tracers and a drop in the dominant particle mode to 50 nm. The dominant mode increased in size to 80 nm over 5 h in calm sunny conditions, accompanied by an increase in ozone. Due to an enhancement in BC but not CO during particle growth, the presence of BB emissions during this period could not be confirmed. The ability of particles > 80 nm (CN80) to act as CCN at 0.5 % supersaturation was investigated. The ΔCCN / ΔCN80 ratio was lowest during the fresh BB plume (56 ± 8 %), higher during the particle growth period (77 ± 4 %) and higher still (104 ± 3 %) in background marine air. Particle size distributions indicate that changes to particle chemical composition, rather than particle size, are driving these changes. Hourly average CCN during both BB events were between 2000 and 5000 CCN cm-3, which were enhanced above typical background levels by a factor of 6-34, highlighting the dramatic impact BB plumes can have on CCN number in clean marine regions. During the 29 h of the second plume strike event (BB2) CO, BC and a range of NMOCs including acetonitrile and hydrogen cyanide (HCN) were clearly enhanced and some enhancements in O3 were observed

  11. Scavenging of urban air emissions by Fog at Delhi, India

    NASA Astrophysics Data System (ADS)

    Saxena, P.; Kulshrestha, U. C.

    2015-12-01

    The present study focuses upon the understanding of fog water chemistry in Delhi city. Total seventy fog water samples were collected at two different sites in Delhi during December 2014 to March 2015. Selected parameters such as pH, major anions (Cl-, F-, NO3- and SO42-) and major cations (NH4+, K+, Ca2+, Mg2+, Na+) were determined in the samples. The pH of the fog water collected during the monitoring period at Site I (traffic intersection) varied from 4.68 to 5.58 indicating the acidic nature of fog water while at the site II (green cover area), it ranged from 6.11 to 6.88 having slightly lower acidity. At the Site I, the average concentration of Cl-, Na+, SO42-, NH4+ was recorded as 1.5 X 10-2, 8 X 10-3, 4 X 10-3 and 1 X 10-2 μEqu/L respectively. Such values of ionic species may be attributed to the local sources, including factories, motor vehicle emissions and civil construction etc. However, non-local sources such as moderate- and long-range transport of sea salt also had significant influence on ionic content of fog water. In general the Na+ ratio values were found to be higher side suggesting the influence of non-marine sources. Extremely high values of Cl-/ Na+ ratios indicated the contribution from combustion of organochlorine compounds. Hence, the higher ratios of inorganic ions and acidic pH revealed that fog is an effective mechanism for the scavenging of various pollutants emitted by different sources in the city.

  12. Microbial community analysis in biotrickling filters treating isopropanol air emissions.

    PubMed

    Pérez, M Carmen; Alvarez-Hornos, F Javier; San-Valero, Pau; Marzal, Paula; Gabaldón, Carmen

    2013-01-01

    The evolution of the microbial community was analysed over one year in two biotrickling filters operating under intermittent feeding conditions and treating isopropanol emissions, a pollutant typically found in the flexography sector. Each reactor was packed with one media: plastic cross-flow-structured material or polypropylene rings. The communities were monitored by fluorescence in situ hybridization (FISH) and denaturing gradient gel electrophoresis (DGGE) analysis of the 16S rRNA region. After inoculation with activated sludge, the biotrickling filters were operated using inlet loads (ILs) from 20 to 65 g C m(-3) h(-1) and empty-bed residence times (EBRTs) from 14 to 160 s. Removal efficiencies higher than 80% were obtained with ILs up to 35 g C m(-3) h(-1) working at EBRTs as low as 24 s. There was an increase in the total percentage of the target domains of up to around 80% at the end of the experiment. Specifically, the Gammaproteobacteria domain group, which includes the well-known volatile organic compound (VOC)-degrading species such as Pseudomonas putida, showed a noticeable rise in the two biotrickling filters of 26% and 27%, respectively. DGGE pattern band analysis revealed a stable band of Pseudomonas putida in all the samples monitored, even in the lower diversity communities. In addition, at similar operational conditions, the biotrickling filter with a greater relative abundance of Pseudomonas sp. (19.2% vs. 8%) showed higher removal efficiency (90% vs. 79%). Results indicate the importance of undertaking a further in-depth study of the involved species in the biofiltration process and their specific function.

  13. Radionuclide air emissions report for the Hanford Site -- calendar year 1997

    SciTech Connect

    Gleckler, B.P.; Rhoads, K.

    1998-06-17

    This report documents radionuclide air emission from the Hanford Site in 1997, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the MEI. The report has been prepared in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emissions Standards for Hazardous Air Pollutants, Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities. This report has also been prepared in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, Radiation Protection-Air Emissions. The effective dose equivalent to the MEI from the Hanford Site`s 1997 point source emissions was 1.2 E-03 mrem (1.2 E-05 mSv), which is well below the 40 CFR 61 Subpart H regulatory limit of 10 mrem/yr. Radon and thoron emissions, exempted from 40 CFR 61 Subpart H, resulted in an effective dose equivalent to the MEI of 2.5 E-03 mrem (2.5 E-05 mSv). The effective dose equivalent to the MEI attributable to diffuse and fugitive emissions was 2.2 E-02 mrem (2.2 E-04 mSv). The total effective dose equivalent from all of the Hanford Site`s air emissions was 2.6 E-02 mrem (2.6 E-04 mSv). The effective dose equivalent from all of the Hanford Site`s air emissions is well below the Washington Administrative Code, Chapter 246-247, regulatory limit of 10 mrem/yr.

  14. Impact of Trans-Boundary Emissions on Modelled Air Pollution in Canada

    NASA Astrophysics Data System (ADS)

    Pavlovic, Radenko; Moran, Mike; Zhang, Junhua; Zheng, Qiong; Menard, Sylvain; Anselmo, David; Davignon, Didier

    2014-05-01

    The operational air quality model GEM-MACH is run twice daily at the Canadian Meteorological Centre in Montreal, Quebec to produce 48-hour forecasts of hourly O3, NO2, and PM2.5 fields over a North American domain. The hourly gridded anthropogenic emissions fields needed by GEM-MACH are currently based on the 2006 Canadian emissions inventory, a 2012 projected U.S. inventory, and the 1999 Mexican inventory. The Sparse Matrix Operator Kernel Emissions (SMOKE) processing package was used to process these three national emissions inventories to create the GEM-MACH emissions fields. While Canada is the second-largest country in the world by total area, its population and its emissions of criteria contaminants are both only about one-tenth of U.S. values and roughly 80% of the Canadian population lives within 150 km of the international border with the U.S. As a consequence, transboundary transport of air pollution has a major impact on air quality in Canada. To quantify the impact of non-Canadian emissions on forecasted pollutant levels in Canada, the following two tests were performed: (a) all U.S. and Mexican anthropogenic emissions were switched off; and (b) anthropogenic emissions from the southernmost tier of U.S. states and Mexico were switched off. These sensitivity tests were performed for the summer and winter periods of 2012 or 2011. The results obtained show that the impact of non-Canadian sources on forecasted pollution is generally larger in summer than in winter, especially in south-eastern parts of Canada. For the three pollutants considered in the Canadian national Air Quality Health Index, PM2.5 is impacted the most (up to 80%) and NO2 the least (<10%). Emissions from the southern U.S. and Mexico do impact Canadian air quality, but the sign may change depending on the season (i.e., increase vs. decrease), reflecting chemical processing en route.

  15. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

    NASA Astrophysics Data System (ADS)

    Gantt, B.; Kelly, J. T.; Bash, J. O.

    2015-11-01

    Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are also important due to the localized impact of SSAs on atmospheric chemistry near the coast. In this study, SSA emissions in the Community Multiscale Air Quality (CMAQ) model were updated to enhance the fine-mode size distribution, include sea surface temperature (SST) dependency, and reduce surf-enhanced emissions. Predictions from the updated CMAQ model and those of the previous release version, CMAQv5.0.2, were evaluated using several coastal and national observational data sets in the continental US. The updated emissions generally reduced model underestimates of sodium, chloride, and nitrate surface concentrations for coastal sites in the Bay Regional Atmospheric Chemistry Experiment (BRACE) near Tampa, Florida. Including SST dependency to the SSA emission parameterization led to increased sodium concentrations in the southeastern US and decreased concentrations along parts of the Pacific coast and northeastern US. The influence of sodium on the gas-particle partitioning of nitrate resulted in higher nitrate particle concentrations in many coastal urban areas due to increased condensation of nitric acid in the updated simulations, potentially affecting the predicted nitrogen deposition in sensitive ecosystems. Application of the updated SSA emissions to the California Research at the Nexus of Air Quality and Climate Change (CalNex) study period resulted in a modest improvement in the predicted surface concentration of sodium and nitrate at several central and southern California coastal sites. This update of SSA emissions enabled a more realistic simulation of the atmospheric chemistry in coastal environments where marine air mixes with urban pollution.

  16. Reducing Ultrafine Particle Emissions Using Air Injection in Wood-Burning Cookstoves.

    PubMed

    Rapp, Vi H; Caubel, Julien J; Wilson, Daniel L; Gadgil, Ashok J

    2016-08-01

    In order to address the health risks and climate impacts associated with pollution from cooking on biomass fires, researchers have focused on designing new cookstoves that improve cooking performance and reduce harmful emissions, specifically particulate matter (PM). One method for improving cooking performance and reducing emissions is using air injection to increase turbulence of unburned gases in the combustion zone. Although air injection reduces total PM mass emissions, the effect on PM size distribution and number concentration has not been thoroughly investigated. Using two new wood-burning cookstove designs from Lawrence Berkeley National Laboratory, this research explores the effect of air injection on cooking performance, PM and gaseous emissions, and PM size distribution and number concentration. Both cookstoves were created using the Berkeley-Darfur Stove as the base platform to isolate the effects of air injection. The thermal performance, gaseous emissions, PM mass emissions, and particle concentrations (ranging from 5 nm to 10 μm in diameter) of the cookstoves were measured during multiple high-power cooking tests. The results indicate that air injection improves cookstove performance and reduces total PM mass but increases total ultrafine (less than 100 nm in diameter) PM concentration over the course of high-power cooking.

  17. Reducing Ultrafine Particle Emissions Using Air Injection in Wood-Burning Cookstoves.

    PubMed

    Rapp, Vi H; Caubel, Julien J; Wilson, Daniel L; Gadgil, Ashok J

    2016-08-01

    In order to address the health risks and climate impacts associated with pollution from cooking on biomass fires, researchers have focused on designing new cookstoves that improve cooking performance and reduce harmful emissions, specifically particulate matter (PM). One method for improving cooking performance and reducing emissions is using air injection to increase turbulence of unburned gases in the combustion zone. Although air injection reduces total PM mass emissions, the effect on PM size distribution and number concentration has not been thoroughly investigated. Using two new wood-burning cookstove designs from Lawrence Berkeley National Laboratory, this research explores the effect of air injection on cooking performance, PM and gaseous emissions, and PM size distribution and number concentration. Both cookstoves were created using the Berkeley-Darfur Stove as the base platform to isolate the effects of air injection. The thermal performance, gaseous emissions, PM mass emissions, and particle concentrations (ranging from 5 nm to 10 μm in diameter) of the cookstoves were measured during multiple high-power cooking tests. The results indicate that air injection improves cookstove performance and reduces total PM mass but increases total ultrafine (less than 100 nm in diameter) PM concentration over the course of high-power cooking. PMID:27348315

  18. Air Sample Conditioner Helps the Waste Treatment Plant Meet Emissions Standards

    SciTech Connect

    Glissmeyer, John A.; Flaherty, Julia E.; Pekour, Mikhail S.

    2014-12-02

    The air in three of the Hanford Site Waste Treatment and Immobilization Plant (WTP) melter off-gas discharge stacks will be hot and humid after passing through the train of emission abatement equipment. The off-gas temperature and humidity levels will be incompatible with the airborne emissions monitoring equipment required for this type of stack. To facilitate sampling from these facilities, an air sample conditioner system will be installed to introduce cool, dry air into the sample stream to reduce the temperature and dew point. This will avoid thermal damage to the instrumentation and problematic condensation. The complete sample transport system must also deliver at least 50% of the particles in the sample airstream to the sample collection and on-line analysis equipment. The primary components of the sample conditioning system were tested in a laboratory setting. The sample conditioner itself is based on a commercially-available porous tube filter design. It consists of a porous sintered metal tube inside a coaxial metal jacket. The hot gas sample stream passes axially through the porous tube, and the dry, cool air is injected into the jacket and through the porous wall of the inner tube, creating an effective sample diluter. The dilution and sample air mix along the entire length of the porous tube, thereby simultaneously reducing the dew point and temperature of the mixed sample stream. Furthermore, because the dilution air enters through the porous tube wall, the sample stream does not come in contact with the porous wall and particle deposition is reduced in this part of the sampling system. Tests were performed with an environmental chamber to supply air with the temperature and humidity needed to simulate the off-gas conditions. Air from the chamber was passed through the conditioning system to test its ability to reduce the temperature and dew point of the sample stream. To measure particle deposition, oil droplets in the range of 9 to 11 micrometer

  19. Evaluation of emission control strategies to reduce ozone pollution in the Paso del Norte region using a photochemical air quality modeling system

    NASA Astrophysics Data System (ADS)

    Valenzuela, Victor Hugo

    Air pollution emissions control strategies to reduce ozone precursor pollutants are analyzed by applying a photochemical modeling system. Simulations of air quality conditions during an ozone episode which occurred in June, 2006 are undertaken by increasing or reducing area source emissions in Ciudad Juarez, Chihuahua, Mexico. Two air pollutants are primary drivers in the formation of tropospheric ozone. Oxides of nitrogen (NOx) and volatile organic compounds (VOC) undergo multiple chemical reactions under favorable meteorological conditions to form ozone, which is a secondary pollutant that irritates respiratory systems in sensitive individuals especially the elderly and young children. The U.S. Environmental Protection Agency established National Ambient Air Quality Standards (NAAQS) to limit ambient air pollutants such as ozone by establishing an 8-hour average concentration of 0.075 ppm as the threshold at which a violation of the standard occurs. Ozone forms primarily due reactions in the troposphere of NOx and VOC emissions generated primarily by anthropogenic sources in urban regions. Data from emissions inventories indicate area sources account for ˜15 of NOx and ˜45% of regional VOC emissions. Area sources include gasoline stations, automotive paint bodyshops and nonroad mobile sources. Multiplicity of air pollution emissions sources provides an opportunity to investigate and potentially implement air quality improvement strategies to reduce emissions which contribute to elevated ozone concentrations. A baseline modeling scenario was established using the CAMx photochemical air quality model from which a series of sensitivity analyses for evaluating air quality control strategies were conducted. Modifications to area source emissions were made by varying NOx and / or VOC emissions in the areas of particular interest. Model performance was assessed for each sensitivity analysis. Normalized bias (NB) and normalized error (NE) were used to identify

  20. Air Quality and Road Emission Results for Fort Stewart, Georgia

    SciTech Connect

    Kirkham, Randy R.; Driver, Crystal J.; Chamness, Mickie A.; Barfuss, Brad C.

    2004-02-02

    The Directorate of Public Works Environmental & Natural Resources Division (Fort Stewart /Hunter Army Airfield) contracted with the Pacific Northwest National Laboratory (PNNL) to monitor particulate matter (PM) concentrations on Fort Stewart, Georgia. The purpose of this investigation was to establish a PM sampling network using monitoring equipment typically used in U.S. Environmental Protection Agency (EPA) ''saturation sampling'', to determine air quality on the installation. In this initial study, the emphasis was on training-generated PM, not receptor PM loading. The majority of PM samples were 24-hr filter-based samples with sampling frequency ranging from every other day, to once every six days synchronized with the EPA 6th day national sampling schedule. Eight measurement sites were established and used to determine spatial variability in PM concentrations and evaluate whether fluctuations in PM appear to result from training activities and forest management practices on the installation. Data collected to date indicate the average installation PM2.5 concentration is lower than that of nearby urban Savannah, Georgia. At three sites near the installation perimeter, analyses to segregate PM concentrations by direction of air flow across the installation boundary indicate that air (below 80 ft) leaving the installation contains less PM2.5 than that entering the installation. This is reinforced by the observation that air near the ground is cleaner on average than the air at the top of the canopy.

  1. Measurements of air pollution emission factors for marine transportation

    NASA Astrophysics Data System (ADS)

    Alföldy, B.; Balzani Lööv, J.; Lagler, F.; Mellqvist, J.; Berg, N.; Beecken, J.; Weststrate, H.; Duyzer, J.; Bencs, L.; Horemans, B.; Cavalli, F.; Putaud, J.-P.; Janssens-Maenhout, G.; Pintér Csordás, A.; Van Grieken, R.; Borowiak, A.; Hjorth, J.

    2012-12-01

    The chemical composition of the plumes of seagoing ships was investigated during a two weeks long measurement campaign in the port of Rotterdam, Hoek van Holland, The Netherlands, in September 2009. Altogether, 497 ships were monitored and a statistical evaluation of emission factors (g kg-1 fuel) was provided. The concerned main atmospheric components were SO2, NO2, NOx and the aerosol particle number. In addition, the elemental and water-soluble ionic composition of the emitted particulate matter was determined. Emission factors were expressed as a function of ship type, power and crankshaft rotational speed. The average SO2 emission factor was found to be roughly half of what is allowed in sulphur emission control areas (16 vs. 30 g kg-1 fuel), and exceedances of this limit were rarely registered. A significant linear relationship was observed between the SO2 and particle number emission factor. The intercept of the regression line, 0.5 × 1016 (kg fuel)-1, gives the average number of particles formed during the burning of 1 kg zero sulphur content fuel, while the slope, 2 × 1018, provides the average number of particles formed with 1 kg sulphur burnt with the fuel. Water-soluble ionic composition analysis of the aerosol samples from the plumes showed that ~144 g of particulate sulphate was emitted from 1 kg sulphur burnt with the fuel. The mass median diameter of sulphate particles estimated from the measurements was ~42 nm.

  2. The influence of surface sorption and air flow rate on phthalate emissions from vinyl flooring: Measurement and modeling

    NASA Astrophysics Data System (ADS)

    Liang, Yirui; Xu, Ying

    2015-02-01

    This study investigated the influences of surface sorption and air flow rate on the emission of phthalates from building materials. Controlled tests were conducted in specially designed stainless steel and wood chambers, and the steady-state concentration in the stainless steel chamber was about 2-3 times higher than that in the wood chamber for di(2-ethylhexyl) phthalate (DEHP) and diisononyl phthalate (DINP). The emission rate of phthalates increased in the wood chamber due to the diffusion mass flow through the chamber wall (i.e., surface absorption). The adsorption isotherm of phthalates on the stainless steel surface and the absorption parameters (i.e., diffusion and partition coefficients) of phthalates on the wood surface were determined experimentally, and the values were comparable to those in the literature. The equilibration time scale for phthalates absorbed to the sink reservoir in actual indoor environments was estimated and can be substantial (approximately 80 years), indicating that surface absorption may continuously drive phthalates from their indoor sources to various sinks and thus significantly increase the emission rate of phthalates. The gas-phase concentration of DEHP was measured in two stainless steel chambers operated at flow rates of 300 mL/min and 3000 mL/min, respectively, which were both adjusted to 1000 mL/min after steady state was reached. The gas-phase concentration of DEHP in the chamber was very sensitive to the chamber air flow rate, and higher air flow rates resulted in lower concentration levels. However, the increased emission rate compensated for the dilution in the gas phase and made the DEHP concentration not drop substantially with an increase in the air flow rate. Independently measured or calculated parameters were used to validate a semi-volatile organic compounds (SVOCs) emission model that included absorptive surfaces and for a range of air flow rates, with excellent agreement between the model predictions and the

  3. Large gain in air quality compared to an alternative anthropogenic emissions scenario

    NASA Astrophysics Data System (ADS)

    Daskalakis, Nikos; Tsigaridis, Kostas; Myriokefalitakis, Stelios; Fanourgakis, George S.; Kanakidou, Maria

    2016-08-01

    During the last 30 years, significant effort has been made to improve air quality through legislation for emissions reduction. Global three-dimensional chemistry-transport simulations of atmospheric composition over the past 3 decades have been performed to estimate what the air quality levels would have been under a scenario of stagnation of anthropogenic emissions per capita as in 1980, accounting for the population increase (BA1980) or using the standard practice of neglecting it (AE1980), and how they compare to the historical changes in air quality levels. The simulations are based on assimilated meteorology to account for the year-to-year observed climate variability and on different scenarios of anthropogenic emissions of pollutants. The ACCMIP historical emissions dataset is used as the starting point. Our sensitivity simulations provide clear indications that air quality legislation and technology developments have limited the rapid increase of air pollutants. The achieved reductions in concentrations of nitrogen oxides, carbon monoxide, black carbon, and sulfate aerosols are found to be significant when comparing to both BA1980 and AE1980 simulations that neglect any measures applied for the protection of the environment. We also show the potentially large tropospheric air quality benefit from the development of cleaner technology used by the growing global population. These 30-year hindcast sensitivity simulations demonstrate that the actual benefit in air quality due to air pollution legislation and technological advances is higher than the gain calculated by a simple comparison against a constant anthropogenic emissions simulation, as is usually done. Our results also indicate that over China and India the beneficial technological advances for the air quality may have been masked by the explosive increase in local population and the disproportional increase in energy demand partially due to the globalization of the economy.

  4. Large Gain in Air Quality Compared to an Alternative Anthropogenic Emissions Scenario

    NASA Technical Reports Server (NTRS)

    Daskalakis, Nikos; Tsigaridis, Kostas; Myriokefalitakis, Stelios; Fanourgakis, George S.; Kanakidou, Maria

    2016-01-01

    During the last 30 years, significant effort has been made to improve air quality through legislation for emissions reduction. Global three-dimensional chemistrytransport simulations of atmospheric composition over the past 3 decades have been performed to estimate what the air quality levels would have been under a scenario of stagnation of anthropogenic emissions per capita as in 1980, accounting for the population increase (BA1980) or using the standard practice of neglecting it (AE1980), and how they compare to the historical changes in air quality levels. The simulations are based on assimilated meteorology to account for the yearto- year observed climate variability and on different scenarios of anthropogenic emissions of pollutants. The ACCMIP historical emissions dataset is used as the starting point. Our sensitivity simulations provide clear indications that air quality legislation and technology developments have limited the rapid increase of air pollutants. The achieved reductions in concentrations of nitrogen oxides, carbon monoxide, black carbon, and sulfate aerosols are found to be significant when comparing to both BA1980 and AE1980 simulations that neglect any measures applied for the protection of the environment. We also show the potentially large tropospheric air quality benefit from the development of cleaner technology used by the growing global population. These 30-year hindcast sensitivity simulations demonstrate that the actual benefit in air quality due to air pollution legislation and technological advances is higher than the gain calculated by a simple comparison against a constant anthropogenic emissions simulation, as is usually done. Our results also indicate that over China and India the beneficial technological advances for the air quality may have been masked by the explosive increase in local population and the disproportional increase in energy demand partially due to the globalization of the economy.

  5. Emissions and transport of air pollutants from China to the Pacific: Major findings from the EAST-AIRE air campaign

    NASA Astrophysics Data System (ADS)

    Li, C.; Li, Z.; Dickerson, R. R.; Chen, H.

    2007-12-01

    Accompanying economic boom over the past few decades, pollutant emissions from China have increased dramatically and raised growing concerns regarding their large-scale impact. Observations over the Pacific Ocean and numerical simulations generally identify mid-latitude cyclones as the major mechanism driving the long-range transport of pollutants off the Chinese coast to downwind areas. Here we present results from the first aircraft campaign of EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment), carried out over an industrialized region in Northeast China in spring 2005. Prefrontal and postfrontal flights provide vertical distribution of pollutants within different sectors of two mid-latitude cyclones traveling through the area. In consistence with previous studies, both cyclones feature abundant anthropogenic pollutants ahead of cold fronts, and much lower pollutant levels (but with dust) behind cold fronts. Pollutant levels above the planetary boundary layer (PBL) were found substantial in one prefrontal flight (April 5) but low in the other (April 11), showing different potentials for long-range transport. Backward trajectories suggest that in both cases, isentropic upward motions associated with the SW flows in the warm sector were weak and largely constrained within PBL. Synoptic analysis and satellite observations further indicate that upwind dry (non- precipitating) convection may explain the pollutants observed above PBL on the 5th. With the assistance of forward trajectory analysis and chemical transport models, two satellite sensors (OMI and MODIS) successfully tracked the pollution plume associated with the April 5 cyclone, as it propagated into the North Pacific on the next few days. Satellite observed changes in SO2 and aerosol content within the plume are used to qualitatively estimate the conversion from aerosol precursor gases to secondary aerosols, in a semi-Lagrangian way.

  6. Including greenhouse gas emissions during benchmarking of wastewater treatment plant control strategies.

    PubMed

    Flores-Alsina, Xavier; Corominas, Lluís; Snip, Laura; Vanrolleghem, Peter A

    2011-10-15

    The main objective of this paper is to demonstrate how greenhouse gas (GHG) emissions can be quantified during the evaluation of control strategies in wastewater treatment plants (WWTP). A modified version of the IWA Benchmark Simulation Model No 2 (BSM2G) is hereby used as a simulation case study. Thus, the traditional effluent quality index (EQI), operational cost index (OCI) and time in violation (TIV) used to evaluate control strategies in WWTP are complemented with a new dimension dealing with GHG emissions. The proposed approach is based on a set of comprehensive models that estimate all potential on-site and off-site sources of GHG emissions. The case study investigates the overall performance of several control strategies and demonstrates that substantial reductions in effluent pollution, operating costs and GHG emissions can be achieved when automatic control is implemented. Furthermore, the study is complemented with a scenario analysis that examines the role of i) the dissolved oxygen (DO) set-point, ii) the sludge retention time (SRT) and iii) the organic carbon/nitrogen ratio (COD/N) as promoters of GHG emissions. The results of this study show the potential mechanisms that promote the formation of CO2, CH4 and N2O when different operational strategies are implemented, the existing synergies and trade-offs amongst the EQI, the OCI and TIV criteria and finally the need to reach a compromise solution to achieve an optimal plant performance.

  7. Marine Sciences Laboratory Radionuclide Air Emissions Report for Calendar Year 2014

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew

    2015-05-04

    The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office (PNSO) has oversight and stewardship duties associated with the Pacific Northwest National Laboratory (PNNL) Marine Sciences Laboratory (MSL) located on Battelle Land – Sequim.This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.'' The EDE to the MSL MEI due to routine operations in 2014 was 9E-05 mrem (9E-07 mSv). No non-routine emissions occurred in 2014. The MSL is in compliance with the federal and state 10 mrem/yr standard.

  8. Marine Sciences Laboratory Radionuclide Air Emissions Report for Calendar Year 2013

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew; Ballinger, Marcel Y.

    2014-05-01

    The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office (PNSO) has oversight and stewardship duties associated with the Pacific Northwest National Laboratory (PNNL) Marine Sciences Laboratory (MSL) located on Battelle Land – Sequim (Sequim). This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.” The EDE to the Sequim MEI due to routine operations in 2013 was 5E-05 mrem (5E-07 mSv). No non-routine emissions occurred in 2013. The MSL is in compliance with the federal and state 10 mrem/yr standard.

  9. Emission of air pollutants from burning candles with different composition in indoor environments.

    PubMed

    Derudi, Marco; Gelosa, Simone; Sliepcevich, Andrea; Cattaneo, Andrea; Cavallo, Domenico; Rota, Renato; Nano, Giuseppe

    2014-03-01

    Candle composition is expected to influence the air pollutants emissions, possibly leading to important differences in the emissions of volatile organic compounds and polycyclic aromatic hydrocarbons. In this regard, the purity of the raw materials and additives used can play a key role. Consequently, in this work emission factors for some polycyclic aromatic hydrocarbons, aromatic species, short-chain aldehydes and particulate matter have been determined for container candles constituted by different paraffin waxes burning in a test chamber. It has been found that wax quality strongly influences the air pollutant emissions. These results could be used, at least at a first glance, to foresee the expected pollutant concentration in a given indoor environment with respect to health safety standards, while the test chamber used for performing the reported results could be useful to estimate the emission factors of any other candle in an easy-to-build standardised environment. PMID:24318837

  10. Quantifying architectural painting VOC air emissions - a methodology with estimates and forecasts

    SciTech Connect

    Anderson, S.P.; Rubick, C.

    1996-12-31

    Architectural coatings (referred to as paints), with the thinners/reducers and cleanup solvents used during their application, contain volatile organic compounds (VOCs) which are precursors to ground level ozone formation. Some of these paint compounds create hazardous air pollutants (HAPs) which are toxic. The nationally recommended emission factor (EF) of 4.6 lbs/year per capita is based on data from the 1970s. This paper documents the methodologies and the National Paint & Coatings Association sets used to develop revised per capita emissions factors (e.g. 3.6 lbs/year per capita for 1993) for estimating and forecasting the VOC air emissions from the area source category of architectural coatings. Emissions estimates, forecasts, trends and reasons for these trends are presented. Future emissions inventory (EI) challenges are addressed in light of data availability, information networks and the proposed category of Architectural and Industrial Maintenance (AIM) coatings.

  11. Pacific Northwest National Laboratory Site Radionuclide Air Emissions Report for Calendar Year 2011

    SciTech Connect

    Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

    2012-06-12

    This report documents radionuclide air emissions that result in the highest effective dose equivalent (EDE) to a member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and Washington Administrative Code (WAC) Chapter 246-247, Radiation ProtectionAir Emissions. The EDE to the PNNL Site MEI due to routine emissions in 2011 from PNNL Site sources was 1.7E 05 mrem (1.7E-7 mSv) EDE. No nonroutine emissions occurred in 2011. The total radiological dose for 2011 to the MEI from all PNNL Site radionuclide emissions was more than 10,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Site is in compliance.

  12. Strategies for emission reduction of air pollutants produced from a chemical plant.

    PubMed

    Lee, Byeong-Kyu; Cho, Sung-Woong

    2003-01-01

    Various air pollution control (APC) techniques were employed in order to reduce emissions of air pollutants produced from chemical plants, which have many different chemical production facilities. For an emission reduction of acid gases, this study employed a method to improve solubility of pollutants by decreasing the operating temperature of the scrubbers, increasing the surface area for effective contact of gas and liquid, and modifying processes in the acid scrubbers. To reduce emission of both amines and acid gases, pollutant gas components were first separated, then condensation and/or acid scrubbing, depending on the chemical and physical properties of pollutant components, were used. To reduce emission of solvents, condensation and activated carbon adsorption were employed. To reduce emission of a mixture gases containing acid gases and solvents, the mixed gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. As a strategy to reduce emission of pollutants at the source, this study also employed the simple pollution prevention concept of modification of the previously operating APC control device. Finally, air emissions of pollutants produced from the chemical plants were much more reduced by applying proper APC methods, depending upon the types (physical or chemical properties) and the specific emission situations of pollutants. PMID:12447574

  13. 40 CFR 49.138 - Rule for the registration of air pollution sources and the reporting of emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 10 § 49.138 Rule for the registration of air pollution sources and the reporting of emissions. (a... maintain a current and accurate record of air pollution sources and their emissions within the Indian... part 71 source or an air pollution source that is subject to a standard established under section...

  14. CHARACTERIZATION OF OZONE EMISSIONS FROM AIR CLEANERS EQUIPPED WITH OZONE GENERATORS AND SENSOR AND FEEDBACK CONTROL CIRCUITRY

    EPA Science Inventory

    The paper give results of a characterization of ozone emissions from air cleaners equipped with ozone generators and sensor and feedback control circuitry. Ozone emission rates of several consumer appliances, marketed as indoor air treatment or air purification systems, were det...

  15. Radionuclide Air Emissions Report for the Hanford Site Calendar Year 1999

    SciTech Connect

    ROKKAN, D.J.

    2000-06-01

    This report documents radionuclide air emissions from the US. Department of Energy (DOE) Hanford Site in 1999 and the resulting effective dose equivalent to the maximally exposed individual (MEI) member of the public. The report has been prepared in accordance with the Code of Federal Regulations (CFR). Title 40, Protection of the Environment, Part 61. National Emission Standards for Hazardous Air Pollutants, Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities'', and with the Washington Administrative Code (WAC) Chapter 246-247. Radiation Protection-Air Emissions. The federal regulations in Subpart H of 40 CFR 61 require the measurement and reporting of radionuclides emitted from US. Department of Energy (DOE) facilities and the resulting offsite dose from those emissions. A standard of 10 mrem/yr effective dose equivalent (EDE) is imposed on them. The EDE to the MEI due to routine emissions in 1999 from Hanford Site point sources was 0.029 mrem (2.9 E-04 mSv), which is less than 0.3 percent of the federal standard. WAC 246-247 requires the reporting of radionuclide emissions from all Hanford Site sources, during routine as well as nonroutine operations. The state has adopted the 40 CFR 61 standard of 10 mrem/yr EDE into their regulations. The state further requires that the EDE to the MEI be calculated not only from point source emissions but also from diffuse and fugitive sources of emissions. The EDE from diffuse and fugitive emissions at the Hanford Site in 1999 was 0.039 mrem (3.9 E-04 mSv) EDE. The total dose from point sources and from diffuse and fugitive sources of radionuclide emissions during all operating conditions in 1999 was 0.068 mrem (6.8 E-04 mSv) EDE, which is less than 0.7 percent of the state standard.

  16. Sensitivity of hazardous air pollutant emissions to the combustion of blends of petroleum diesel and biodiesel fuel

    NASA Astrophysics Data System (ADS)

    Magara-Gomez, Kento T.; Olson, Michael R.; Okuda, Tomoaki; Walz, Kenneth A.; Schauer, James J.

    2012-04-01

    Emission rates and composition of known hazardous air pollutants in the exhaust gas from a commercial agriculture tractor, burning a range of biodiesel blends operating at two different load conditions were investigated to better understand the emission characteristics of biodiesel fuel. Ultra-Low Sulfur Petroleum Diesel (ULSD) fuel was blended with soybean oil and beef tallow based biodiesel to examine fuels containing 0% (B0), 50% (B50) and 100% (B100) soybean oil based biodiesel, and 50% (B50T) and 100% (B100T) beef tallow biodiesel. Samples were collected using a dilution source sampler to simulate atmospheric dilution. Particulate matter and exhaust gases were analyzed for carbonyls, Volatile Organic Compounds (VOCs), and Polycyclic Aromatic Hydrocarbons (PAHs) to determine their respective emission rates. This analysis is focused on the emissions of organic compounds classified by the US EPA as air toxics and include 2,2,4 trimethylpentane, benzene, toluene, ethylbenzene, m-, p- and o-xylene, formaldehyde, acetaldehyde and methylethyl ketone. Emission rates of 2,2,4 trimethylpentane, toluene, ethylbenzene, m-, p- and o-xylene decreased more than 90% for B50, B100 and B100T blends; decreases in emission rates of benzene, formaldehyde and acetaldehyde were more modest, producing values between 23 and 67%, and methyl ethyl ketone showed decreases not exceeding 7% for the studied biodiesel blends. PAHs emission rates were reduced by 66% for B50, 84% for B100, and by 89% for B100T. The overall emissions of toxic organic compounds were calculated and expressed as benzene equivalents. The largest contributors of toxic risk were found to be formaldehyde and acetaldehyde. Reductions in formaldehyde emissions were 23% for B50 and 42% for B100 soybean, and 40% for B100T beef tallow compared to B0. Similarly, acetaldehyde reductions were 34% for B50 and 53% for B100 soybean biodiesel and 42% for B100T beef tallow biodiesel.

  17. Texas refinery air pollution emissions are being severely underestimated

    NASA Astrophysics Data System (ADS)

    Schultz, Colin

    2014-06-01

    The Houston-Galveston-Brazoria region of southeastern Texas is home to heavy industrial investment in oil refining and petrochemical production. Pollutants emanating from the factories and refineries have repeatedly caused the region to fail national and state-level tests for air quality and ground-level ozone.

  18. Air Permit Compliance for Hanford Waste Retrieval Operations Involving Multi-Unit Emissions

    SciTech Connect

    Faulk, D.E.; Simmons, F.M.

    2008-07-01

    Since 1970, approximately 38,000 suspect-transuranic and transuranic waste containers have been placed in retrievable storage on the Hanford Site in the 200 Areas burial grounds. Hanford's Waste Retrieval Project is retrieving these buried containers and processing them for safe storage and disposition. Container retrieval activities require an air emissions permit to account for potential emissions of radionuclides. The air permit covers the excavation activities as well as activities associated with assaying containers and installing filters in the retrieved transuranic containers lacking proper venting devices. Fluor Hanford, Inc. is required to track radioactive emissions resulting from the retrieval activities. Air, soil, and debris media contribute to the emissions and enabling assumptions allow for calculation of emissions. Each of these activities is limited to an allowed annual emission (per calendar year) and contributes to the overall total emissions allowed for waste retrieval operations. Tracking these emissions is required to ensure a permit exceedance does not occur. A tracking tool was developed to calculate potential emissions in real time sense. Logic evaluations are established within the tracking system to compare real time data against license limits to ensure values are not exceeded for either an individual activity or the total limit. Data input are based on field survey and workplace air monitoring activities. This tracking tool is used monthly and quarterly to verify compliance to the license limits. Use of this tool has allowed Fluor Hanford, Inc. to successfully retrieve a significant number of containers in a safe manner without any exceedance of emission limits. (authors)

  19. Radionuclide air emissions. Annual report for calendar year 1997

    SciTech Connect

    1997-08-01

    A description is provided of radioactive effluent releases from the Pinellas Plant. The DOE sold the Pinellas Plant in March 1995. A portion of the plant was backed by DOE until September 1997 to facilitate a safe transition to commercial ventures.The plant`s radiological processing equipment was cleaned from past DOE operations. Emissions from the cleanup activity were monitored.

  20. Advantages of city-scale emission inventory for urban air quality research and policy: the case of Nanjing, a typical industrial city in the Yangtze River Delta, China

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Qiu, L.; Xu, R.; Xie, F.; Zhang, Q.; Yu, Y.; Nielsen, C. P.; Qin, H.; Wang, H.; Wu, X.; Li, W.; Zhang, J.

    2015-07-01

    With most eastern Chinese cities facing major air quality challenges, there is a strong need for city-scale emission inventories for use in both chemical transport modeling and the development of pollution control policies. In this paper, a high-resolution emission inventory of air pollutants and CO2 for Nanjing, a typical large city in the Yangtze River Delta, is developed incorporating the best available information on local sources. Emission factors and activity data at the unit or facility level are collected and compiled using a thorough onsite survey of major sources. Over 900 individual plants, which account for 97 % of the city's total coal consumption, are identified as point sources, and all of the emission-related parameters including combustion technology, fuel quality, and removal efficiency of air pollution control devices (APCD) are analyzed. New data-collection approaches including continuous emission monitoring systems and real-time monitoring of traffic flows are employed to improve spatiotemporal distribution of emissions. Despite fast growth of energy consumption between 2010 and 2012, relatively small inter-annual changes in emissions are found for most air pollutants during this period, attributed mainly to benefits of growing APCD deployment and the comparatively strong and improving regulatory oversight of the large point sources that dominate the levels and spatial distributions of Nanjing emissions overall. The improvement of this city-level emission inventory is indicated by comparisons with observations and other inventories at larger spatial scale. Relatively good spatial correlations are found for SO2, NOx, and CO between the city-scale emission estimates and concentrations at 9 state-opertated monitoring sites (R = 0.58, 0.46, and 0.61, respectively). The emission ratios of specific pollutants including BC to CO, OC to EC, and CO2 to CO compare well to top-down constraints from ground observations. The inter-annual variability and

  1. [A comparative study on domestic and foreign emission standards of air pollutants for cement industry].

    PubMed

    Jiang, Mei; Li, Xiao-Qian; Ji, Liang; Zou, Lan; Wei, Yu-Xia; Zhao, Guo-Hua; Che, Fei; Li, Gang; Zhang, Guo-Ning

    2014-12-01

    The new National Emission Standard of Air Pollutants for Cement Industry (GB 4915-2013) becomes effective on Mar. 1st, 2014. It will play an important role in pollution prevention, total emission reduction, structure adjustment, and layout optimization for cement industry. Based on the research of emission standard in China, U. S., EU and Japan, the similarities and differences in the pollutant projects, control indicators, limits and means of implementation were discussed and advice was proposed, with the purpose to provide a reference for revision of emission standard, and to improve the level of environmental management and pollution control.

  2. Source-emissions testing of the air-stripping process, Vance Air Force Base, Oklahoma. Final report, 21 May-25 May 1990

    SciTech Connect

    Binovi, R.D.; Vaughn, R.W.

    1990-08-01

    At the request of HQ ATC/DEEV through HQ ATC/SGPB, source emissions testing for methylene chloride emissions in the air stripping tower vent and tower influent and effluent was performed at the pretreatment facility at Vance AFB on 21-25 May 90. Testing was conducted to provide data for the air quality permit to operate the pretreatment facility's air stripping tower as required by the Oklahoma State Department of Health. Results show the plant has operational problems, based on the percent removal calculations from the wastewater stream. The pretreatment plant is also not meeting the Federal pretreatment standard limits for methylene chloride from a new facility treating metal finishing waste (40 CFR 433.17). Recommendations included: (1) optimizing the plant operations by determining proper coagulant dosage and cleaning the stripping tower; (2) contacting the manufacturer to determine the design efficiency of the stripping tower; if not efficient enough, additional treatment such as carbon absorption needs to be added; and (3) completing another round of emissions testing after the plant's operation has been optimized.

  3. Climate-forced air-quality modeling at the urban scale: sensitivity to model resolution, emissions and meteorology

    NASA Astrophysics Data System (ADS)

    Markakis, K.; Valari, M.; Perrussel, O.; Sanchez, O.; Honore, C.

    2015-07-01

    While previous research helped to identify and prioritize the sources of error in air-quality modeling due to anthropogenic emissions and spatial scale effects, our knowledge is limited on how these uncertainties affect climate-forced air-quality assessments. Using as reference a 10-year model simulation over the greater Paris (France) area at 4 km resolution and anthropogenic emissions from a 1 km resolution bottom-up inventory, through several tests we estimate the sensitivity of modeled ozone and PM2.5 concentrations to different potentially influential factors with a particular interest over the urban areas. These factors include the model horizontal and vertical resolution, the meteorological input from a climate model and its resolution, the use of a top-down emission inventory, the resolution of the emissions input and the post-processing coefficients used to derive the temporal, vertical and chemical split of emissions. We show that urban ozone displays moderate sensitivity to the resolution of emissions (~ 8 %), the post-processing method (6.5 %) and the horizontal resolution of the air-quality model (~ 5 %), while annual PM2.5 levels are particularly sensitive to changes in their primary emissions (~ 32 %) and the resolution of the emission inventory (~ 24 %). The air-quality model horizontal and vertical resolution have little effect on model predictions for the specific study domain. In the case of modeled ozone concentrations, the implementation of refined input data results in a consistent decrease (from 2.5 up to 8.3 %), mainly due to inhibition of the titration rate by nitrogen oxides. Such consistency is not observed for PM2.5. In contrast this consistency is not observed for PM2.5. In addition we use the results of these sensitivities to explain and quantify the discrepancy between a coarse (~ 50 km) and a fine (4 km) resolution simulation over the urban area. We show that the ozone bias of the coarse run (+9 ppb) is reduced by ~ 40 % by adopting

  4. Contribution of ship emissions to the concentration and deposition of air pollutants in Europe

    NASA Astrophysics Data System (ADS)

    Aksoyoglu, S.; Prévôt, A. S. H.; Baltensperger, U.

    2015-11-01

    Emissions from the marine transport sector are one of the least regulated anthropogenic emission sources and contribute significantly to air pollution. Although strict limits were introduced recently for the maximum sulfur content in marine fuels in the SECAs (sulfur emission control areas) and in the EU ports, sulfur emissions outside the SECAs and emissions of other components in all European maritime areas have continued to increase in the last two decades. We have used the air quality model CAMx with and without ship emissions for the year 2006 to determine the effects of international shipping on the annual as well as seasonal concentrations of ozone, primary and secondary components of PM2.5 and the dry and wet deposition of nitrogen and sulfur compounds in Europe. Our results suggest that emissions from international shipping affect the air quality in northern and southern Europe differently and their contributions to the air concentrations vary seasonally. The largest changes in pollutant concentrations due to ship emissions were predicted for summer. Increased concentrations of the primary particle mass were found only along the shipping routes whereas concentrations of the secondary pollutants were affected over a larger area. Concentrations of particulate sulfate increased due to ship emissions in the Mediterranean (up to 60 %), in the English Channel and the North Sea (30-35 %) while increases in particulate nitrate levels were found especially in the north, around the Benelux area (20 %) where there were high NH3 land-based emissions. Our model results showed that not only the atmospheric concentrations of pollutants are affected by ship emissions, but also depositions of nitrogen and sulfur compounds increase significantly along the shipping routes. NOx emissions from the ships especially in the English Channel and the North Sea, cause a decrease in the dry deposition of reduced nitrogen at source regions by moving it from the gas-phase to the

  5. Influence of population density and temporal variations in emissions on the air duality benefits of NOx emission trading.

    PubMed

    Nobel, Carolyn E; McDonald-Buller, Elena C; Kimura, Yosuke; Lumbley, Katherine E; Allen, David T

    2002-08-15

    Ozone formation is a complex function of local hydrocarbon and nitrogen oxide emissions. Therefore, trading of NOx emissions among geographically distributed facilities can lead to more or less ozone formation than across-the-board reductions. Monte Carlo simulations of trading scenarios involving 51 large NOx point sources in eastern Texas were used in a previous study by the authors to assess the effects of trading on air quality benefits, as measured by changes in ozone concentrations. The results indicated that 12% of trading scenarios would lead to greater than a 25% variation from conventional across-the-board reductions when air quality benefits are based only on changes in ozone concentration. The current study found that when benefits are based on a metric related to population exposure to ozone, two-thirds of the trading scenarios lead to changes in air quality benefits of approximately 25%. Variability in air quality benefits is not as strongly dependent on the temporal distribution of NOx emissions.

  6. Fort Hall air emissions study, Fort Hall Indian Reservation, Fort Hall, Idaho

    SciTech Connect

    Metcalf, S.W.; Sonnenfeld, N.L.; Rolka, D.L.; Kaye, W.E.

    1995-11-01

    The Agency for Toxic Substances and Disease Registry (ATSDR) conducted a cross-sectional health study at the Fort Hall Indian Reservation in Idaho to investigate concerns about the health effects on reservation residents that might be attributed to two phosphate-processing plants located near the reservation`s southern border. In addition to increased particulates, air emissions from these plants included phosphorus pentoxide, cadmium, chromium, fluoride, uranium, and its daughter radionuclides. A total of 515 participants -- 229 from Fort Hall and 286 from a comparison group at the Duck Valley Indian Reservation -- were interviewed in person by trained American Indian interviewers. Approximately 100 residents of each reservation performed pulmonary function tests and provided urine specimens that were analyzed for cadmium, chromium, fluoride, and several renal biomarkers.

  7. Monitoring of atmospheric aerosol emissions using a remotely piloted air vehicle (RPV)-Borne Sensor Suite

    SciTech Connect

    1996-05-01

    We have developed a small sensor system, the micro-atmospheric measurement system ({mu}-AMS), to monitor and track aerosol emissions. The system was developed to fly aboard a remotely piloted air vehicle, or other mobile platform, to provide real-time particle measurements in effluent plumes and to collect particles for chemical analysis. The {mu}-AMS instrument measures atmospheric parameters including particle mass concentration and size distribution, temperature, humidity, and airspeed, altitude and position (by GPS receiver) each second. The sensor data are stored onboard and are also down linked to a ground station in real time. The {mu}-AMS is battery powered, small (8 in. dia x 36 in.), and lightweight (15 pounds). Aerosol concentrations and size distributions from above ground explosive tests, airbone urban pollution, and traffic-produced particulates are presented.

  8. Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals

    SciTech Connect

    Szpunar, C.B.

    1992-09-01

    This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions).

  9. Direct calculation of acoustic streaming including the boundary layer phenomena in an ultrasonic air pump

    NASA Astrophysics Data System (ADS)

    Wada, Yuji; Koyama, Daisuke; Nakamura, Kentaro

    2012-05-01

    Direct finite difference fluid simulation of acoustic streaming on the fine-meshed three-dimensiona model by graphics processing unit (GPU)-oriented calculation array is discussed. Airflows due to the acoustic traveling wave are induced when an intense sound field is generated in a gap between a bending transducer and a reflector. Calculation results showed good agreement with the measurements in the pressure distribution. In addition to that, several flow-vortices were observed near the boundary of the reflector and the transducer, which have been often discussed in acoustic tube near the boundary, and have never been observed in the calculation in the ultrasonic air pump of this type.

  10. [Impact of heavy-duty diesel vehicles on air quality and control of their emissions].

    PubMed

    Zhou, Lei; Wang, Bo-Guang; Tang, Da-Gang

    2011-08-01

    Through an analysis of the characteristics of diesel vehicle emissions and motor vehicle emissions inventories, this paper examines the impact of heavy-duty diesel vehicles on air quality in China as well as issues related to the control of their emissions. Heavy-duty diesel vehicles emit large amounts of nitrogen oxides and particulate matter. Nitrogen oxides is one of the important precursors for the formation of secondary particles and ozone in the atmosphere, causing regional haze. Diesel particulate matter is a major toxic air pollutant with adverse effect on human health, and in particular, the ultrafine particles in 30-100 nm size range can pose great health risks because of its extremely small sizes. Motor vehicles have become a major source of air pollution in many metropolitan areas and city cluster in China, and among them the heavy-duty diesel vehicles are a dominant contributor of nitrogen oxides and particulate matter emissions. Hence, controlling heavy-duty diesel vehicle emissions should be a key component of an effective air quality management plan, and a number of issues related to heavy-duty diesel vehicle emissions need to be addressed.

  11. Various Perspectives of Mitigating Fossil Fuel Use and Air Pollutant Emissions in China's Megacity

    NASA Astrophysics Data System (ADS)

    Wang, H.

    2014-12-01

    It is critical to reduce energy use and air pollutions in metropolitan areas because these areas usually serve as economic engines and have large, dense populations. Fossil fuel use and air-polluting emissions were analyzed in Beijing between 1997 and 2010 from both a bottom-up and a top-down perspective. From a bottom-up perspective, the key energy-intensive industrial sectors directly caused changes in Beijing's air pollution by means of a series of energy and economic policies. From a top-down perspective, variation in industrial production caused increases in most emissions between 2000 and 2010, however, there were decreases in PM10 and PM2.5 emissions during 2005-2010. Population growth was found to be the largest driver of energy consumption and emissions between1997 and 2010. Energy use and air pollutant emissions were also found to outsource from Beijing to other regions in China. Policies for reducing urban energy consumption and emissions should consider not only the key industrial sectors but also socioeconomic drivers.

  12. A Variational Inverse Model Study of Amazonian Methane Emissions including Observations from the AMAZONICA campaign

    NASA Astrophysics Data System (ADS)

    Wilson, C. J.; Gloor, M.; Chipperfield, M.; Miller, J. B.; Gatti, L.

    2013-12-01

    Methane (CH4) is a greenhouse gas which is emitted from a range of anthropogenic and natural sources, and since the industrial revolution its mean atmospheric concentration has climbed dramatically, reaching values unprecedented in at least the past 650,000 years. CH4 produces a relatively high radiative forcing effect upon the Earth's climate, and its atmospheric lifetime of approximately 10 years makes it a more appealing target for the mitigation of climate change over short timescales than long-lived greenhouse gases such as carbon dioxide. However, the spatial and temporal variation of CH4 emissions are still not well understood, though in recent years a number of top-down and bottom-up studies have attempted to construct improved emission budgets. Some top-down studies may suffer from poor observational coverage in tropical regions, however, especially in the planetary boundary layer, where the atmosphere is highly sensitive to emissions. For example, although satellite observations often take a large volume of measurements in tropical regions, these retrievals are not usually sensitive to concentrations at the planet's surface. Methane emissions from Amazon region, in particular, are often poorly constrained. Since emissions form this region, coming mainly from wetland and biomass burning sources, are thought to be relatively high, additional observations in this region would greatly help to constrain the geographical distribution of the global CH4 emission budget. In order to provide such measurements, the AMAZONICA project began to take regular flask measurements of CH4 and other trace gases from aircraft over four Amazonian sites from the year 2010 onwards. We first present a forward modelling study of these observations of Amazonian methane for the year 2010 using the TOMCAT Chemical Transport Model. The model is used to attribute variations at each site to a source type and region, and also to assess the ability of our current CH4 flux estimates to

  13. New Directions: GEIA’s 2020 Vision for Better Air Emissions Information

    SciTech Connect

    Frost, G. J.; Middleton, Paulette; Tarrason, Leonor; Granier, Claire; Guenther, Alex B.; Cardenas, B.; Denier van der Gon, Hugo; Janssens-Maenhout, Greet; Kaiser, Johannes W.; Keating, Terry; Klimont, Z.; Lamarque, Jean-Francois; Liousse, Catherine; Nickovic, S.; Ohara, Toshimasa; Schultz, Martin; Skiba, Ute; Wang, Y.

    2013-12-01

    We are witnessing a crucial change in how we quantify and understand emissions of greenhouse gases and air pollutants, with an increasing demand for science-based transparent emissions information produced by robust community efforts. Today’s scientific capabilities, with near-real-time in-situ and remote sensing observations combined with forward and inverse models and a better understanding of the controlling processes, are contributing to this transformation and providing new approaches to derive, verify, and forecast emissions (Tong et al., 2011; Frost et al., 2012) and to quantify their impacts on the environment (e.g., Bond et al., 2013). At the same time, the needs for emissions information and the demands for their accuracy and consistency have grown. Changing economies, demographics, agricultural practices, and energy sources, along with mandates to evaluate emissions mitigation efforts, demonstrate compliance with legislation, and verify treaties, are leading to new challenges in emissions understanding. To quote NOAA Senior Technical Scientist David Fahey, "We are in the Century of Accountability. Emissions information is critical not only for environmental science and decision-making, but also as an instrument of foreign policy and international diplomacy." Emissions quantification represents a key step in explaining observed variability and trends in atmospheric composition and in attributing these observed changes to their causes. Accurate emissions data are necessary to identify feasible controls that reduce adverse impacts associated with air quality and climate and to track the success of implemented policies. To progress further, the international community must improve the understanding of drivers and contributing factors to emissions, and it must strengthen connections among and within different scientific disciplines that characterize our environment and entities that protect the environment and influence further emissions. The Global

  14. National estimates of residential firewood and air pollution emissions

    SciTech Connect

    Lipfert, F. W.; Dungan, J. L.

    1981-01-01

    Estimates are presented for the distribution and quantity of recent (1978-1979) use of residential firewood in the United States, based on a correlation of survey data from 64 New England counties. The available survey data from other states are in agreement with the relationship derived from New England; no constraints due to wood supply are apparent. This relationship indicates that the highest density of wood usage (Kg/ha) occurs in urban areas; thus exacerbation of urban air quality problems is a matter of some concern. The data presentation used here gives an upper limit to this density of firewood usage which will allow realistic estimates of air quality impact to be made.

  15. National Emission Standards for Hazardous Air Pollutants Calendar Year 2006

    SciTech Connect

    NSTec Environmental Technical Services

    2007-06-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO). From 1951 through 1992, the NTS was operated as the nation's site for nuclear weapons testing. The release of man-made radionuclides from the NTS as a result of testing activities has been monitored since the first decade of atmospheric testing. After 1962, when nuclear tests were conducted only underground, the radiation exposure to the public surrounding the NTS was greatly reduced. After the 1992 moratorium on nuclear testing, radiation monitoring on the NTS focused on detecting airborne radionuclides which come from historically-contaminated soils resuspended into the air (e.g., by winds) and tritium-contaminated soil moisture emitted to the air from soils through evapotranspiration.

  16. IES. Air Emission, Liquid Effluent Inventory and Reporting

    SciTech Connect

    Chapman, T.

    1996-10-01

    The IES maintains an inventory of radiological air and liquid effluents released to the atmosphere. The IES utilizes the official stack numbers. Data may be entered by generators for any monitoring time period. Waste volumes released as well as their radiological constituents are tracked. The IES provides data to produce a report for NESHAPS as well as several administrative action/anomaly reports. These reports flag unusual occurences (releases) that are above normal range releases.

  17. Air pollution combustion emissions: characterization of causative agents and mechanisms associated with cancer, reproductive, and cardiovascular effects.

    PubMed

    Lewtas, Joellen

    2007-01-01

    Combustion emissions account for over half of the fine particle (PM(2.5)) air pollution and most of the primary particulate organic matter. Human exposure to combustion emissions including the associated airborne fine particles and mutagenic and carcinogenic constituents (e.g., polycyclic aromatic compounds (PAC), nitro-PAC) have been studied in populations in Europe, America, Asia, and increasingly in third-world counties. Bioassay-directed fractionation studies of particulate organic air pollution have identified mutagenic and carcinogenic polycyclic aromatic hydrocarbons (PAH), nitrated PAH, nitro-lactones, and lower molecular weight compounds from cooking. A number of these components are significant sources of human exposure to mutagenic and carcinogenic chemicals that may also cause oxidative and DNA damage that can lead to reproductive and cardiovascular effects. Chemical and physical tracers have been used to apportion outdoor and indoor and personal exposures to airborne particles between various combustion emissions and other sources. These sources include vehicles (e.g., diesel and gasoline vehicles), heating and power sources (e.g., including coal, oil, and biomass), indoor sources (e.g., cooking, heating, and tobacco smoke), as well as secondary organic aerosols and pollutants derived from long-range transport. Biomarkers of exposure, dose and susceptibility have been measured in populations exposed to air pollution combustion emissions. Biomarkers have included metabolic genotype, DNA adducts, PAH metabolites, and urinary mutagenic activity. A number of studies have shown a significant correlation of exposure to PM(2.5) with these biomarkers. In addition, stratification by genotype increased this correlation. New multivariate receptor models, recently used to determine the sources of ambient particles, are now being explored in the analysis of human exposure and biomarker data. Human studies of both short- and long-term exposures to combustion

  18. Air stripping of contaminated water sources - air emissions and controls. Final report

    SciTech Connect

    Vancit, M.A.; Howle, R.H.; Herndon, D.J.; Shareef, S.A.

    1987-08-01

    Air-stripping towers are being used to remove low concentrations of organic contaminants from water. The report describes the technology and methods used to control air pollution resulting from this procedure. The cost of the controls is presented along with other positive and negative impacts of the technology.

  19. Air pollution response to changing weather and power plant emissions in the eastern United States

    NASA Astrophysics Data System (ADS)

    Bloomer, Bryan Jaye

    Air pollution in the eastern United States causes human sickness and death as well as damage to crops and materials. NOX emission reduction is observed to improve air quality. Effectively reducing pollution in the future requires understanding the connections between smog, precursor emissions, weather, and climate change. Numerical models predict global warming will exacerbate smog over the next 50 years. My analysis of 21 years of CASTNET observations quantifies a climate change penalty. I calculate, for data collected prior to 2002, a climate penalty factor of ˜3.3 ppb O3/°C across the power plant dominated receptor regions in the rural, eastern U.S. Recent reductions in NOX emissions decreased the climate penalty factor to ˜2.2 ppb O3/°C. Prior to 1995, power plant emissions of CO2, SO2, and NOX were estimated with fuel sampling and analysis methods. Currently, emissions are measured with continuous monitoring equipment (CEMS) installed directly in stacks. My comparison of the two methods show CO 2 and SO2 emissions are ˜5% lower when inferred from fuel sampling; greater differences are found for NOX emissions. CEMS are the method of choice for emission inventories and commodity trading and should be the standard against which other methods are evaluated for global greenhouse gas trading policies. I used CEMS data and applied chemistry transport modeling to evaluate improvements in air quality observed by aircraft during the North American electrical blackout of 2003. An air quality model produced substantial reductions in O3, but not as much as observed. The study highlights weaknesses in the model as commonly used for evaluating a single day event and suggests areas for further investigation. A new analysis and visualization method quantifies local-daily to hemispheric-seasonal scale relationships between weather and air pollution, confirming improved air quality despite increasing temperatures across the eastern U.S. Climate penalty factors indicate

  20. Emission Measurements from Natural Gas Development and Regional Background Characterization of Ambient Air Quality in the Marcellus Shale Region

    NASA Astrophysics Data System (ADS)

    DeCarlo, P. F.; Goetz, J.; Shaw, S. L.; Knipping, E. M.; Fortner, E.; Wormhoudt, J.; Massoli, P.; Floerchinger, C.; Brooks, B.; Herndon, S. C.; Kolb, C. E.; Knighton, W. B.

    2012-12-01

    Production of natural gas in the Marcellus shale formation is increasing rapidly due to the vast quantities of natural gas in the formation. Natural gas is liberated from the Marcellus Shale using horizontal drilling techniques, followed by hydraulic fracturing. Activities associated with preparation of a well pad, drilling of a well pad, fracturing of a well, and transport of materials (e.g. water, drilling equipment) to and from a well site, all have associated air emissions. Steady state gas production at well sites may also have additional contribution to air emissions of methane and NOx from gas transport infrastructure. A joint study with the Drexel University, Aerodyne Research and the Electric Power Research institute was conducted in the summer of 2012 to measure both the emissions from various stages of well development and to characterize current levels of air pollutants in the Marcellus Region. To achieve this, the Aerodyne mobile laboratory was deployed and measured in situ concentrations of a multitude of gas-phase and aerosol chemical components with state of the art instrumentation including quantum cascade laser systems, proton transfer mass spectrometry, tunable diode lasers and a soot particle aerosol mass spectrometer. Species quantified include CH4, C2H6, NO, NO2, CO, CO2, SO2, HONO, HOCO, HCOOH and many volatile organic compounds, and aerosol size and chemical composition. Real-time characterization of the air emissions from hydraulic fracturing and other shale gas operations allow for the estimation of emission factors that can be used in predictive air quality modeling for the region. Within the Marcellus Shale both areas of dry gas (>95% methane) and wet gas (contains higher levels of ethane and propane) are found. Measurements were conducted in two regions of Pennsylvania: the NE region that is predominantly dry gas, and the SW region where wet gas is found. A comparison of these two regions and associated impacts will be discussed

  1. Nevada Test Site National Emission Standards for Hazardous Air Pollutants Calendar Year 2007

    SciTech Connect

    Robert Grossman; Ronald Warren

    2008-06-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office. From 1951 through 1992, the NTS was operated as the nation's site for nuclear weapons testing. The release of man-made radionuclides from the NTS as a result of testing activities has been monitored since the first decade of atmospheric testing. After 1962, when nuclear tests were conducted only underground, the radiation exposure to the public surrounding the NTS was greatly reduced. After the 1992 moratorium on nuclear testing, radiation monitoring on the NTS focused on detecting airborne radionuclides which come from historically contaminated soils resuspended into the air (e.g., by winds) and tritium-contaminated soil moisture emitted to the air from soils through evapotranspiration. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) limits the release of radioactivity from a U.S. Department of Energy facility (e.g., the NTS) to 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This is the dose limit established for someone living off of the NTS from radionuclides emitted to air from the NTS. This limit does not include the radiation doses that members of the public may receive through the intake of radioactive particles unrelated to NTS activities, such as those that come from naturally occurring elements in the environment (e.g., naturally occurring radionuclides in soil or radon gas from the earth or natural building materials), or from other man-made sources (e.g., medical treatments). The NTS demonstrates compliance using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the U.S. Environmental Protection Agency for use on the NTS in 2001 and has been the sole

  2. The air quality forecast of PM10 in Beijing with Community Multi-scale Air Quality Modeling (CMAQ) system: emission and improvement

    NASA Astrophysics Data System (ADS)

    Wu, Q.; Xu, W.; Shi, A.; Li, Y.; Zhao, X.; Wang, Z.; Li, J.; Wang, L.

    2014-05-01

    The MM5-SMOKE-CMAQ model system, which was developed by the United States Environmental Protection Agency (US EPA) as the Models-3 system, has been used for daily air quality forecasts in the Beijing Municipal Environmental Monitoring Center (Beijing MEMC), as a part of the Ensemble Air Quality Forecast System for Beijing (EMS-Beijing) since the Olympic Games 2008. According to the daily forecast results for the entire duration of 2010, the model shows good model performances in the PM10 forecast on most days but clearly underestimates some air pollution episodes. A typical air pollution episode from 11-20 January 2010 was chosen, where the observed air pollution index of particulate matter (PM10-API) reached to 180 while the forecast's PM10-API was about 100. In this study, three numerical methods are used for model improvement: first, enhance the inner domain with 3 km resolution grids: the coverage is expanded from only Beijing to the area including Beijing and its surrounding cities; second, add more regional point source emissions located at Baoding, Landfang and Tangshan, which is to the south and east of Beijing; third, update the area source emissions, which includes the regional area source emissions in Baoding and Tangshan and the local village-town level area source emissions in Beijing. As a result, the hindcast shows a much better model performance in the national standard station-averaged PM10-API, whereas the daily hindcast PM10-API reaches 180 and is much closer to the observation and has a correlation coefficient of 0.93. The correlation coefficient of the PM10-API in all Beijing MEMC stations between the hindcast and observation is 0.82, obviously higher than the forecast's 0.54, and the FAC2 increases from 56% in the forecast to 84% in the hindcast, while the NMSE decreases from 0.886 to 0.196. The hindcast also has better model performance in PM10 hourly concentrations during the typical air pollution episode, the correlation coefficient

  3. Long-term trends in nitrogen oxide emissions from motor vehicles at national, state, and air basin scales

    NASA Astrophysics Data System (ADS)

    McDonald, Brian C.; Dallmann, Timothy R.; Martin, Elliot W.; Harley, Robert A.

    2011-11-01

    A fuel-based approach is used to estimate nitrogen oxides (NOx = NO + NO2) emissions from gasoline- and diesel-powered motor vehicles. Estimates are made at the national level for the period 1990-2010. Vehicle emissions are also estimated at the state level for California, and for the South Coast (Los Angeles) and San Joaquin Valley air basins. Fuel-based emission estimates are compared with predictions from widely used emission inventory models. Changes in diesel NOxemissions vary over time: increasing between 1990 and 1997, stable between 1997 and 2007, and decreasing since 2007. In contrast, gasoline engine-related NOxemissions have decreased steadily, by ˜65% overall between 1990 and 2010, except in the San Joaquin Valley, where reductions were not as large due to faster population growth. In the San Joaquin Valley, diesel engines were the dominant on-road NOxsource in all years considered (reaching ˜70% in 2010). In the urbanized South Coast air basin, gasoline engine emissions dominated in the past and have been comparable to on-road diesel sources since 2007 (down from ˜75% in 1990). Other major anthropogenic sources of NOxare added to compare emission trends with trends in surface pollutant observations and satellite-derived data. When all major anthropogenic NOx sources are included, the overall emission trend is downward in all cases (-45% to -60%). Future reductions in motor vehicle NOxwill depend on the effectiveness of new exhaust after-treatment controls on heavy-duty trucks, as well as further improvements todurabilityof emission control systems on light-duty vehicles.

  4. Long-term trends in nitrogen oxide emissions from motor vehicles at national, state, and air basin scales

    NASA Astrophysics Data System (ADS)

    McDonald, Brian C.; Dallmann, Timothy R.; Martin, Elliot W.; Harley, Robert A.

    2012-09-01

    A fuel-based approach is used to estimate nitrogen oxides (NOx = NO + NO2) emissions from gasoline- and diesel-powered motor vehicles. Estimates are made at the national level for the period 1990-2010. Vehicle emissions are also estimated at the state level for California, and for the South Coast (Los Angeles) and San Joaquin Valley air basins. Fuel-based emission estimates are compared with predictions from widely used emission inventory models. Changes in diesel NOxemissions vary over time: increasing between 1990 and 1997, stable between 1997 and 2007, and decreasing since 2007. In contrast, gasoline engine-related NOxemissions have decreased steadily, by ˜65% overall between 1990 and 2010, except in the San Joaquin Valley, where reductions were not as large due to faster population growth. In the San Joaquin Valley, diesel engines were the dominant on-road NOxsource in all years considered (reaching ˜70% in 2010). In the urbanized South Coast air basin, gasoline engine emissions dominated in the past and have been comparable to on-road diesel sources since 2007 (down from ˜75% in 1990). Other major anthropogenic sources of NOxare added to compare emission trends with trends in surface pollutant observations and satellite-derived data. When all major anthropogenic NOx sources are included, the overall emission trend is downward in all cases (-45% to -60%). Future reductions in motor vehicle NOxwill depend on the effectiveness of new exhaust after-treatment controls on heavy-duty trucks, as well as further improvements todurabilityof emission control systems on light-duty vehicles.

  5. Modeling indoor air pollution from cookstove emissions in developing countries using a Monte Carlo single-box model

    NASA Astrophysics Data System (ADS)

    Johnson, Michael; Lam, Nick; Brant, Simone; Gray, Christen; Pennise, David

    2011-06-01

    A simple Monte Carlo single-box model is presented as a first approach toward examining the relationship between emissions of pollutants from fuel/cookstove combinations and the resulting indoor air pollution (IAP) concentrations. The model combines stove emission rates with expected distributions of kitchen volumes and air exchange rates in the developing country context to produce a distribution of IAP concentration estimates. The resulting distribution can be used to predict the likelihood that IAP concentrations will meet air quality guidelines, including those recommended by the World Health Organization (WHO) for fine particulate matter (PM 2.5) and carbon monoxide (CO). The model can also be used in reverse to estimate the probability that specific emission factors will result in meeting air quality guidelines. The modeled distributions of indoor PM 2.5 concentration estimated that only 4% of homes using fuelwood in a rocket-style cookstove, even under idealized conditions, would meet the WHO Interim-1 annual PM 2.5 guideline of 35 μg m -3. According to the model, the PM 2.5 emissions that would be required for even 50% of homes to meet this guideline (0.055 g MJ-delivered -1) are lower than those for an advanced gasifier fan stove, while emissions levels similar to liquefied petroleum gas (0.018 g MJ-delivered -1) would be required for 90% of homes to meet the guideline. Although the predicted distribution of PM concentrations (median = 1320 μg m -3) from inputs for traditional wood stoves was within the range of reported values for India (108-3522 μg m -3), the model likely overestimates IAP concentrations. Direct comparison with simultaneously measured emissions rates and indoor concentrations of CO indicated the model overestimated IAP concentrations resulting from charcoal and kerosene emissions in Kenyan kitchens by 3 and 8 times respectively, although it underestimated the CO concentrations resulting from wood-burning cookstoves in India by

  6. Quantification of emission reduction potentials of primary air pollutants from residential solid fuel combustion by adopting cleaner fuels in China.

    PubMed

    Shen, Guofeng

    2015-11-01

    Residential low efficient fuel burning is a major source of many air pollutants produced during incomplete combustions, and household air pollution has been identified as one of the top environmental risk factors. Here we compiled literature-reported emission factors of pollutants including carbon monoxide (CO), total suspended particles (TSPs), PM2.5, organic carbon (OC), elemental carbon (EC) and polycyclic aromatic hydrocarbons (PAHs) for different household energy sources, and quantified the potential for emission reduction by clean fuel adoption. The burning of crop straws, firewood and coal chunks in residential stoves had high emissions per unit fuel mass but lower thermal efficiencies, resulting in high levels of pollution emissions per unit of useful energy, whereas pelletized biofuels and coal briquettes had lower pollutant emissions and higher thermal efficiencies. Briquetting coal may lead to 82%-88% CO, 74%-99% TSP, 73%-76% PM2.5, 64%-98% OC, 92%-99% EC and 80%-83% PAH reductions compared to raw chunk coal. Biomass pelletizing technology would achieve 88%-97% CO, 73%-87% TSP, 79%-88% PM2.5, 94%-96% OC, 91%-99% EC and 63%-96% PAH reduction compared to biomass burning. The adoption of gas fuels (i.e., liquid petroleum gas, natural gas) would achieve significant pollutant reduction, nearly 96% for targeted pollutants. The reduction is related not only to fuel change, but also to the usage of high efficiency stoves.

  7. Nevada Test Site National Emission Standards for Hazardous Air Pollutants Calendar Year 2008

    SciTech Connect

    Ronald Warren and Robert F. Grossman

    2009-06-30

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office. From 1951 through 1992, the NTS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NTS activities has been monitored since the initiation of atmospheric testing. Limitation to under-ground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NTS. After nuclear testing ended in 1992, NTS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by winds) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium were also emitted to air at the North Las Vegas Facility (NLVF), an NTS support complex in the city of North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR, 2008a) limits the release of radioactivity from a U.S. Department of Energy facility (e.g., the NTS) to 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation not related to NTS activities. Unrelated doses could come from naturally occurring radioactive elements or from other man-made sources such as medical treatments. The NTS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the U.S. Environmental Protection Agency for use on the NTS in 2001 and has been the sole method used since 2005. Six locations on the NTS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo

  8. Model study of the ship emissions impact on the air quality in the Adriatic/Ionian area

    NASA Astrophysics Data System (ADS)

    Karagiannidis, Athanasios; Poupkou, Anastasia; Liora, Natalia; Dimopoulos, Spiros; Giannaros, Christos; Melas, Dimitrios; Argiriou, Athanassios

    2015-04-01

    The increase of the ship traffic for touristic and commercial purposes is one of the EU Blue Growth targets. The Adriatic/Ionian is one of the sea-basin strategic areas for this target. The purpose of the study is the examination of the impact of the ship emissions on the gaseous and particulate pollutants concentrations in the Adriatic/Ionian area for which the current scientific knowledge is limited. The impact is simulated over a domain covering the Central and Eastern Mediterranean in 10 km resolution during a summer period (July) and a winter period (January) of the year 2012. The modeling system used consists of the photochemical model CAMx off line coupled with the meteorological model WRF. The zero-out modeling method is implemented involving CAMx simulations performed while including and omitting the ship emission data. The simulations are based on the European scale anthropogenic emission inventory of The Netherlands Organisation (TNO) for the reference year 2009. Natural emissions (NMVOCs from the vegetation, sea salt, wind-blown dust), estimated with the use of the Natural Emission MOdel (NEMO) developed by the Aristotle University of Thessaloniki, are accounted for in the photochemical model runs. The spatial distribution of the resulting differences in the gaseous and particulate pollutant concentration fields for both emission scenarios are presented and discussed, providing an estimation of the contribution of ship emissions on the determination of the air quality in the Adriatic/Ionian countries

  9. Metallic layer-by-layer photonic crystals for linearly-polarized thermal emission and thermophotovoltaic device including same

    DOEpatents

    Lee, Jae-Hwang; Ho, Kai-Ming; Constant, Kristen P.

    2016-07-26

    Metallic thermal emitters consisting of two layers of differently structured nickel gratings on a homogeneous nickel layer are fabricated by soft lithography and studied for polarized thermal radiation. A thermal emitter in combination with a sub-wavelength grating shows a high extinction ratio, with a maximum value close to 5, in a wide mid-infrared range from 3.2 to 7.8 .mu.m, as well as high emissivity up to 0.65 at a wavelength of 3.7 .mu.m. All measurements show good agreement with theoretical predictions. Numerical simulations reveal that a high electric field exists within the localized air space surrounded by the gratings and the intensified electric-field is only observed for the polarizations perpendicular to the top sub-wavelength grating. This result suggests how the emissivity of a metal can be selectively enhanced at a certain range of wavelengths for a given polarization.

  10. ( RTP, NC ) IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGEMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    EPA Science Inventory

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  11. (NEW YORK) IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGEMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    EPA Science Inventory

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  12. Impact of aviation emissions on UTLS and air quality in current and future climate - GEM-AC model simulations

    NASA Astrophysics Data System (ADS)

    Kaminski, J. W.

    2015-12-01

    The objective of this study is to investigate the potential impacts of aviation emissions on the upper troposphere and lower stratosphere (UTLS) and surface air quality. The tool that was used in our study is the GEM-AC (Global Environmental Multiscale with Atmospheric Chemistry) chemical weather model where air quality, free tropospheric and stratospheric chemistry processes are on-line and interactive in a weather forecast model of Environment Canada. In vertical, the model domain is defined on 70 hybrid levels from the surface to ~60km. The gas-phase chemistry includes a comprehensive set of reactions for Ox, NOx, HOx, CO, CH4, NMVOCs, halocarbons, ClOx and BrO. Also, the model can address aerosol microphysics and gas-aerosol partitioning. Aircraft emissions are provided by the AEDT 2006 database developed by the Federal Aviation Administration. Results from model simulations on a global variable grid with 1 degree uniform resolution in the northern hemisphere will be presented.

  13. Contemplations on air emission standards for wood waste fuels

    SciTech Connect

    Jamison, R.L.; Karch, K.M.; Junge, D.C.

    1981-08-01

    Surplus wood wastes and forest residuals are a significant renewable energy resource that could reduce U.S. oil imports one million barrels per day or lessen depletion of nonrenewable fossil fuel resources. The forest products industry currently supplies 50% of its energy requirements from internally generated wood and bark residue fuels. Energy derived from such renewable fuels totals approximately 1.2 quads at present, and there is opportunity to increase this to 2.2 quads. However, progress would be impeded if the new industrial boiler New Source Performance Standards for emissions soon to be proposed by the Environmental Protection Agency are unnecessarily stringent. 4 refs.

  14. Hawaii Energy Resource Overviews. Volume 4. Impact of geothermal resource development in Hawaii (including air and water quality)

    SciTech Connect

    Siegel, S.M.; Siegel, B.Z.

    1980-06-01

    The environmental consequences of natural processes in a volcanic-fumerolic region and of geothermal resource development are presented. These include acute ecological effects, toxic gas emissions during non-eruptive periods, the HGP-A geothermal well as a site-specific model, and the geothermal resources potential of Hawaii. (MHR)

  15. Comment on ‘Energy and air emission implications of a decentralized wastewater system’

    NASA Astrophysics Data System (ADS)

    Vedachalam, Sridhar; Riha, Susan J.

    2013-03-01

    In the article ‘Energy and air emission implications of a decentralized wastewater system’ published in Environmental Research Letters (2012 Environ. Res. Lett. 7 024007), Shehabi et al compared a decentralized and a centralized system on the basis of energy use, greenhouse gas emissions and air pollutants, and claimed that economies of scale lower the environmental impacts from a centralized system on a per-volume basis. In this comment, we present literature and data from New York State, USA to argue that the authors’ comparison between a small decentralized system (0.015 MGD) and a large centralized system (66.5 MGD) is unconventional and inappropriate.

  16. Fog Induced Aerosol Modification Observed by AERONET, Including Occurrences During Major Air Pollution Events

    NASA Astrophysics Data System (ADS)

    Eck, T. F.; Holben, B. N.; Reid, J. S.; Giles, D. M.; Rivas, M.; Singh, R. P.; Tripathi, S. N.; Bruegge, C. J.; Li, Z.; Platnick, S. E.; Arnold, T.; Ferrare, R. A.; Hostetler, C. A.; Burton, S. P.; Kim, J.; Kim, Y. J.; Sinyuk, A.; Dubovik, O.; Arola, A. T.; Schafer, J.; Artaxo, P.; Smirnov, A.; Chen, H.; Goloub, P.

    2014-12-01

    The modification of aerosol optical properties due to interaction with fog is examined from measurements made by sun/sky radiometers at several AERONET sites. Retrieved total column volume size distributions for cases identified as aerosol modified by fog often show very a large 'middle mode' submicron radius (~0.4 to 0.5 microns), which is typically seen as a component of a bimodal sub-micron distribution. These middle mode sized particles are often called cloud-processed or residual aerosol. This bimodal accumulation mode distribution may be due to one mode (the larger one) from fog-processed aerosol and the other from interstitial aerosol, or possibly from two different aerosol species (differing chemical composition) with differing hygroscopic growth factors. The size of the fine mode particles from AERONET retrieved for these cases exceeds the size of sub-micron sized particles retrieved for nearly all other aerosol types, suggesting significant modification of aerosols within the fog or cloud environment. In-situ measured aerosol size distributions made during other fog events are compared to the AERONET retrievals, and show close agreement in the residual mode particle size. Almucantar retrievals are analyzed from the Kanpur site in the Indo-Gangetic Plain in India (fog in January), Beijing (fog in winter), Fresno, CA in the San Joaquin Valley (fog in winter), South Korea (Yellow Sea fog in spring), Arica on the northern coast of Chile (stratocumulus), and several other sites with aerosol observations made after fog dissipated. Additionally, several major air pollution events are discussed where extremely high aerosol concentrations were measured at the surface and during which fog also occurred, resulting in the detection very large fine mode aerosols (residual mode) from AERONET retrievals in some of these events. Low wind speeds that occurred during these events were conducive to both pollutant accumulation and also fog formation. The presence of fog then

  17. Fog Induced Aerosol Modification Observed by AERONET, Including Occurrences During Major Air Pollution Events

    NASA Astrophysics Data System (ADS)

    Eck, T. F.; Holben, B. N.; Reid, J. S.; Giles, D. M.; Rivas, M.; Singh, R. P.; Tripathi, S. N.; Bruegge, C. J.; Li, Z.; Platnick, S. E.; Arnold, T.; Ferrare, R. A.; Hostetler, C. A.; Burton, S. P.; Kim, J.; Kim, Y. J.; Sinyuk, A.; Dubovik, O.; Arola, A. T.; Schafer, J.; Artaxo, P.; Smirnov, A.; Chen, H.; Goloub, P.

    2015-12-01

    The modification of aerosol optical properties due to interaction with fog is examined from measurements made by sun/sky radiometers at several AERONET sites. Retrieved total column volume size distributions for cases identified as aerosol modified by fog often show very a large 'middle mode' submicron radius (~0.4 to 0.5 microns), which is typically seen as a component of a bimodal sub-micron distribution. These middle mode sized particles are often called cloud-processed or residual aerosol. This bimodal accumulation mode distribution may be due to one mode (the larger one) from fog-processed aerosol and the other from interstitial aerosol, or possibly from two different aerosol species (differing chemical composition) with differing hygroscopic growth factors. The size of the fine mode particles from AERONET retrieved for these cases exceeds the size of sub-micron sized particles retrieved for nearly all other aerosol types, suggesting significant modification of aerosols within the fog or cloud environment. In-situ measured aerosol size distributions made during other fog events are compared to the AERONET retrievals, and show close agreement in the residual mode particle size. Almucantar retrievals are analyzed from the Kanpur site in the Indo-Gangetic Plain in India (fog in January), Beijing (fog in winter), Fresno, CA in the San Joaquin Valley (fog in winter), South Korea (Yellow Sea fog in spring), Arica on the northern coast of Chile (stratocumulus), and several other sites with aerosol observations made after fog dissipated. Additionally, several major air pollution events are discussed where extremely high aerosol concentrations were measured at the surface and during which fog also occurred, resulting in the detection very large fine mode aerosols (residual mode) from AERONET retrievals in some of these events. Low wind speeds that occurred during these events were conducive to both pollutant accumulation and also fog formation. The presence of fog then

  18. Reduction in air emissions attainable through implementation of district heating and cooling

    SciTech Connect

    Bloomquist, R.G.

    1996-12-31

    District heating and cooling (DHC) can provide multiple opportunities to reduce air emissions associated with space conditioning and electricity generation, which contribute 30% to 50% of all such emissions. When DHC is combined with cogeneration (CHP), maximum reductions in sulfur oxides (SO{sub x}), nitrogen oxides (NO{sub x}), carbon dioxide (CO{sub 2}), particulates, and ozone-depleting chlorofluorocarbon (CFC) refrigerants can most effectively be achieved. Although significant improvements in air quality have been documented in Europe and Scandinavia due to DHC and CHP implementation, accurately predicting such improvements has been difficult. Without acceptable quantification methods, regulatory bodies are reluctant to grant air emissions credits, and local community leaders are unwilling to invest in DHC and CHP as preferred methods of providing energy or strategies for air quality improvement. The recent development and release of a number of computer models designed specifically to provide quantification of air emissions that can result from DHC and CHP implementation should help provide local, state, and national policymakers with information vital to increasing support and investment in DHC development.

  19. Portable air pollution control equipment for the control of toxic particulate emissions

    SciTech Connect

    Chaurushia, A.; Odabashian, S.; Busch, E.

    1997-12-31

    Chromium VI (Cr VI) has been identified by the environmental regulatory agencies as a potent carcinogen among eleven heavy metals. A threshold level of 0.0001 lb/year for Cr VI emissions has been established by the California Air Resources Board for reporting under Assembly Bill 2588. A need for an innovative control technology to reduce fugitive emissions of Cr VI was identified during the Air Toxic Emissions Reduction Program at Northrop Grumman Military Aircraft Systems Division (NGMASD). NGMASD operates an aircraft assembly facility in El Segundo, CA. Nearly all of the aircraft components are coated with a protective coating (primer) prior to assembly. The primer has Cr VI as a component for its excellent corrosion resistance property. The complex assembly process requires fasteners which also need primer coating. Therefore, NGMASD utilizes High Volume Low Pressure (HVLP) guns for the touch-up spray coating operations. During the touch-up spray coating operations, Cr VI particles are atomized and transferred to the aircraft surface. The South Coast Air Quality Management District (SCAQMD) has determined that the HVLP gun transfers 65% of the paint particles onto the substrate and the remaining 35% are emitted as an overspray if air pollution controls are not applied. NGMASD has developed the Portable Air Pollution Control Equipment (PAPCE) to capture and control the overspray in order to reduce fugitive Cr VI emissions from the touch-up spray coating operations. A source test was performed per SCAQMD guidelines and the final report has been approved by the SCAQMD.

  20. Assessing the potential visibility benefits of Clean Air Act Title IV emission reductions

    SciTech Connect

    Trexler, E.C. Jr.; Shannon, J.D.

    1995-06-01

    Assessments are made of the benefits of the 1990 Clean Air Act Title IV (COVE), Phase 2, SO2 and NOX reduction provisions, to the visibility in typical eastern and western Class 1 areas. Probable bands of visibility impairment distribution curves are developed for Shenandoah National Park, Smoky Mountain National Park and the Grand Canyon National Park, based on the existing emissions, ``Base Case``, and for the COVE emission reductions, ``CAAA Case``. Emission projections for 2010 are developed with improved versions of the National Acid Precipitation Assessment Program emission projection models. Source-receptor transfer matrices created with the Advanced Statistical Trajectory Regional Air Pollution (ASTRAP) model are used with existing emission inventories and with the emission projections to calculate atmospheric concentrations of sulfate and nitrate at the receptors of interest for existing and projected emission scenarios. The Visibility Assessment Scoping Model (VASM) is then used to develop distributions of visibility impairment. VASM combines statistics of observed concentrations of particulate species and relative humidity with ASTRAP calculations of the relative changes in atmospheric sulfate and nitrate particulate concentrations in a Monte Carlo approach to produce expected distributions of hourly particulate concentrations and RH. Light extinction relationships developed in theoretical and field studies are then used to calculate the resulting distribution of visibility impairment. Successive Monte Carlo studies are carried out to develop sets of visibility impairment distributions with and without the COVE emission reductions to gain insight into the detectability of expected visibility improvements.

  1. Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong.

    PubMed

    Yan, H H; Guo, H; Ou, J M

    2014-08-15

    During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO2-equivelant (CO2-eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10(5)tons CO2-eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong.

  2. Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong.

    PubMed

    Yan, H H; Guo, H; Ou, J M

    2014-08-15

    During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO2-equivelant (CO2-eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10(5)tons CO2-eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong. PMID:24997256

  3. Consequential life cycle air emissions externalities for plug-in electric vehicles in the PJM interconnection

    NASA Astrophysics Data System (ADS)

    Weis, Allison; Jaramillo, Paulina; Michalek, Jeremy

    2016-02-01

    We perform a consequential life cycle analysis of plug-in electric vehicles (PEVs), hybrid electric vehicles (HEVs), and conventional gasoline vehicles in the PJM interconnection using a detailed, normative optimization model of the PJM electricity grid that captures the change in power plant operations and related emissions due to vehicle charging. We estimate and monetize the resulting human health and environmental damages from life cycle air emissions for each vehicle technology. We model PJM using the most recent data available (2010) as well as projections of the PJM grid in 2018 and a hypothetical scenario with increased wind penetration. We assess a range of sensitivity cases to verify the robustness of our results. We find that PEVs have higher life cycle air emissions damages than gasoline HEVs in the recent grid scenario, which has a high percentage of coal generation on the margin. In particular, battery electric vehicles with large battery capacity can produce two to three times as much air emissions damage as gasoline HEVs, depending on charge timing. In our future 2018 grid scenarios that account for predicted coal plant retirements, PEVs would produce air emissions damages comparable to or slightly lower than HEVs.

  4. Air quality impacts of European wildfire emissions in a changing climate

    NASA Astrophysics Data System (ADS)

    Knorr, Wolfgang; Dentener, Frank; Hantson, Stijn; Jiang, Leiwen; Klimont, Zbigniew; Arneth, Almut

    2016-05-01

    Wildfires are not only a threat to human property and a vital element of many ecosystems, but also an important source of air pollution. In this study, we first review the available evidence for a past or possible future climate-driven increase in wildfire emissions in Europe. We then introduce an ensemble of model simulations with a coupled wildfire-dynamic-ecosystem model, which we combine with published spatial maps of both wildfire and anthropogenic emissions of several major air pollutants to arrive at air pollutant emission projections for several time slices during the 21st century. The results indicate moderate wildfire-driven emission increases until 2050, but there is a possibility of large increases until the last decades of this century at high levels of climate change. We identify southern and north-eastern Europe as potential areas where wildfires may surpass anthropogenic pollution sources during the summer months. Under a scenario of high levels of climate change (Representative Concentration Pathway, RCP, 8.5), emissions from wildfires in central and northern Portugal and possibly southern Italy and along the west coast of the Balkan peninsula are projected to reach levels that could affect annual mean particulate matter concentrations enough to be relevant for meeting WHO air quality targets.

  5. ESP 2.0: Improved method for projecting U.S. GHG and air pollution emissions through 2055

    EPA Science Inventory

    The Emission Scenario Projection (ESP) method is used to develop multi-decadal projections of U.S. Greenhouse Gas (GHG) and criteria pollutant emissions. The resulting future-year emissions can then translated into an emissions inventory and applied in climate and air quality mod...

  6. Probing Atmospheric Electric Fields in Thunderstorms through Radio Emission from Cosmic-Ray-Induced Air Showers.

    PubMed

    Schellart, P; Trinh, T N G; Buitink, S; Corstanje, A; Enriquez, J E; Falcke, H; Hörandel, J R; Nelles, A; Rachen, J P; Rossetto, L; Scholten, O; Ter Veen, S; Thoudam, S; Ebert, U; Koehn, C; Rutjes, C; Alexov, A; Anderson, J M; Avruch, I M; Bentum, M J; Bernardi, G; Best, P; Bonafede, A; Breitling, F; Broderick, J W; Brüggen, M; Butcher, H R; Ciardi, B; de Geus, E; de Vos, M; Duscha, S; Eislöffel, J; Fallows, R A; Frieswijk, W; Garrett, M A; Grießmeier, J; Gunst, A W; Heald, G; Hessels, J W T; Hoeft, M; Holties, H A; Juette, E; Kondratiev, V I; Kuniyoshi, M; Kuper, G; Mann, G; McFadden, R; McKay-Bukowski, D; McKean, J P; Mevius, M; Moldon, J; Norden, M J; Orru, E; Paas, H; Pandey-Pommier, M; Pizzo, R; Polatidis, A G; Reich, W; Röttgering, H; Scaife, A M M; Schwarz, D J; Serylak, M; Smirnov, O; Steinmetz, M; Swinbank, J; Tagger, M; Tasse, C; Toribio, M C; van Weeren, R J; Vermeulen, R; Vocks, C; Wise, M W; Wucknitz, O; Zarka, P

    2015-04-24

    We present measurements of radio emission from cosmic ray air showers that took place during thunderstorms. The intensity and polarization patterns of these air showers are radically different from those measured during fair-weather conditions. With the use of a simple two-layer model for the atmospheric electric field, these patterns can be well reproduced by state-of-the-art simulation codes. This in turn provides a novel way to study atmospheric electric fields.

  7. Probing Atmospheric Electric Fields in Thunderstorms through Radio Emission from Cosmic-Ray-Induced Air Showers.

    PubMed

    Schellart, P; Trinh, T N G; Buitink, S; Corstanje, A; Enriquez, J E; Falcke, H; Hörandel, J R; Nelles, A; Rachen, J P; Rossetto, L; Scholten, O; Ter Veen, S; Thoudam, S; Ebert, U; Koehn, C; Rutjes, C; Alexov, A; Anderson, J M; Avruch, I M; Bentum, M J; Bernardi, G; Best, P; Bonafede, A; Breitling, F; Broderick, J W; Brüggen, M; Butcher, H R; Ciardi, B; de Geus, E; de Vos, M; Duscha, S; Eislöffel, J; Fallows, R A; Frieswijk, W; Garrett, M A; Grießmeier, J; Gunst, A W; Heald, G; Hessels, J W T; Hoeft, M; Holties, H A; Juette, E; Kondratiev, V I; Kuniyoshi, M; Kuper, G; Mann, G; McFadden, R; McKay-Bukowski, D; McKean, J P; Mevius, M; Moldon, J; Norden, M J; Orru, E; Paas, H; Pandey-Pommier, M; Pizzo, R; Polatidis, A G; Reich, W; Röttgering, H; Scaife, A M M; Schwarz, D J; Serylak, M; Smirnov, O; Steinmetz, M; Swinbank, J; Tagger, M; Tasse, C; Toribio, M C; van Weeren, R J; Vermeulen, R; Vocks, C; Wise, M W; Wucknitz, O; Zarka, P

    2015-04-24

    We present measurements of radio emission from cosmic ray air showers that took place during thunderstorms. The intensity and polarization patterns of these air showers are radically different from those measured during fair-weather conditions. With the use of a simple two-layer model for the atmospheric electric field, these patterns can be well reproduced by state-of-the-art simulation codes. This in turn provides a novel way to study atmospheric electric fields. PMID:25955053

  8. Comparing three vegetation monoterpene emission models to measured gas concentrations with a model of meteorology, air chemistry and chemical transport

    NASA Astrophysics Data System (ADS)

    Smolander, S.; He, Q.; Mogensen, D.; Zhou, L.; Bäck, J.; Ruuskanen, T.; Noe, S.; Guenther, A.; Aaltonen, H.; Kulmala, M.; Boy, M.

    2013-11-01

    Biogenic volatile organic compounds (BVOCs) are essential in atmospheric chemistry because of their chemical reactions that produce and destroy tropospheric ozone, their effects on aerosol formation and growth, and their potential influence on global warming. As one of the important BVOC groups, monoterpenes have been a focus of scientific attention in atmospheric research. Detailed regional measurements and model estimates are needed to study emission potential and the monoterpene budget on a global scale. Since the use of empirical measurements for upscaling is limited by many physical and biological factors such as genetic variation, temperature and light, water availability, seasonal changes, and environmental stresses, comprehensive inventories over larger areas are difficult to obtain. We applied the boundary layer-chemistry-transport model SOSA to investigate Scots pine (Pinus sylvestris) monoterpene emissions in a boreal coniferous forest at the SMEAR II site, Southern Finland. SOSA was applied to simulate monoterpene emissions with three different emission modules: the semi-empirical G95, MEGAN 2.04 with improved descriptions of temperature and light responses and including also carbonyl emissions, and a process-based model SIM-BIM. For the first time, the emission models included seasonal and diurnal variations in both quantity and chemical species of emitted monoterpenes, based on parameterizations obtained from field measurements. Results indicate that modelling and observations agreed reasonably well, and that the model can be used for investigating regional air chemistry questions related to monoterpenes. The predominant modelled monoterpene concentrations, α-pinene and Δ3-carene, are consistent with observations.

  9. Air pollutant emissions from Chinese households: A major and underappreciated ambient pollution source.

    PubMed

    Liu, Jun; Mauzerall, Denise L; Chen, Qi; Zhang, Qiang; Song, Yu; Peng, Wei; Klimont, Zbigniew; Qiu, Xinghua; Zhang, Shiqiu; Hu, Min; Lin, Weili; Smith, Kirk R; Zhu, Tong

    2016-07-12

    As part of the 12th Five-Year Plan, the Chinese government has developed air pollution prevention and control plans for key regions with a focus on the power, transport, and industrial sectors. Here, we investigate the contribution of residential emissions to regional air pollution in highly polluted eastern China during the heating season, and find that dramatic improvements in air quality would also result from reduction in residential emissions. We use the Weather Research and Forecasting model coupled with Chemistry to evaluate potential residential emission controls in Beijing and in the Beijing, Tianjin, and Hebei (BTH) region. In January and February 2010, relative to the base case, eliminating residential emissions in Beijing reduced daily average surface PM2.5 (particulate mater with aerodynamic diameter equal or smaller than 2.5 micrometer) concentrations by 14 ± 7 μg⋅m(-3) (22 ± 6% of a baseline concentration of 67 ± 41 μg⋅m(-3); mean ± SD). Eliminating residential emissions in the BTH region reduced concentrations by 28 ± 19 μg⋅m(-3) (40 ± 9% of 67 ± 41 μg⋅m(-3)), 44 ± 27 μg⋅m(-3) (43 ± 10% of 99 ± 54 μg⋅m(-3)), and 25 ± 14 μg⋅m(-3) (35 ± 8% of 70 ± 35 μg⋅m(-3)) in Beijing, Tianjin, and Hebei provinces, respectively. Annually, elimination of residential sources in the BTH region reduced emissions of primary PM2.5 by 32%, compared with 5%, 6%, and 58% achieved by eliminating emissions from the transportation, power, and industry sectors, respectively. We also find air quality in Beijing would benefit substantially from reductions in residential emissions from regional controls in Tianjin and Hebei, indicating the value of policies at the regional level. PMID:27354524

  10. Air pollutant emissions from Chinese households: A major and underappreciated ambient pollution source

    PubMed Central

    Liu, Jun; Mauzerall, Denise L.; Chen, Qi; Zhang, Qiang; Song, Yu; Peng, Wei; Klimont, Zbigniew; Qiu, Xinghua; Zhang, Shiqiu; Hu, Min; Lin, Weili; Smith, Kirk R.; Zhu, Tong

    2016-01-01

    As part of the 12th Five-Year Plan, the Chinese government has developed air pollution prevention and control plans for key regions with a focus on the power, transport, and industrial sectors. Here, we investigate the contribution of residential emissions to regional air pollution in highly polluted eastern China during the heating season, and find that dramatic improvements in air quality would also result from reduction in residential emissions. We use the Weather Research and Forecasting model coupled with Chemistry to evaluate potential residential emission controls in Beijing and in the Beijing, Tianjin, and Hebei (BTH) region. In January and February 2010, relative to the base case, eliminating residential emissions in Beijing reduced daily average surface PM2.5 (particulate mater with aerodynamic diameter equal or smaller than 2.5 micrometer) concentrations by 14 ± 7 μg⋅m−3 (22 ± 6% of a baseline concentration of 67 ± 41 μg⋅m−3; mean ± SD). Eliminating residential emissions in the BTH region reduced concentrations by 28 ± 19 μg⋅m−3 (40 ± 9% of 67 ± 41 μg⋅m−3), 44 ± 27 μg⋅m−3 (43 ± 10% of 99 ± 54 μg⋅m−3), and 25 ± 14 μg⋅m−3 (35 ± 8% of 70 ± 35 μg⋅m−3) in Beijing, Tianjin, and Hebei provinces, respectively. Annually, elimination of residential sources in the BTH region reduced emissions of primary PM2.5 by 32%, compared with 5%, 6%, and 58% achieved by eliminating emissions from the transportation, power, and industry sectors, respectively. We also find air quality in Beijing would benefit substantially from reductions in residential emissions from regional controls in Tianjin and Hebei, indicating the value of policies at the regional level. PMID:27354524

  11. Air pollutant emissions from Chinese households: A major and underappreciated ambient pollution source.

    PubMed

    Liu, Jun; Mauzerall, Denise L; Chen, Qi; Zhang, Qiang; Song, Yu; Peng, Wei; Klimont, Zbigniew; Qiu, Xinghua; Zhang, Shiqiu; Hu, Min; Lin, Weili; Smith, Kirk R; Zhu, Tong

    2016-07-12

    As part of the 12th Five-Year Plan, the Chinese government has developed air pollution prevention and control plans for key regions with a focus on the power, transport, and industrial sectors. Here, we investigate the contribution of residential emissions to regional air pollution in highly polluted eastern China during the heating season, and find that dramatic improvements in air quality would also result from reduction in residential emissions. We use the Weather Research and Forecasting model coupled with Chemistry to evaluate potential residential emission controls in Beijing and in the Beijing, Tianjin, and Hebei (BTH) region. In January and February 2010, relative to the base case, eliminating residential emissions in Beijing reduced daily average surface PM2.5 (particulate mater with aerodynamic diameter equal or smaller than 2.5 micrometer) concentrations by 14 ± 7 μg⋅m(-3) (22 ± 6% of a baseline concentration of 67 ± 41 μg⋅m(-3); mean ± SD). Eliminating residential emissions in the BTH region reduced concentrations by 28 ± 19 μg⋅m(-3) (40 ± 9% of 67 ± 41 μg⋅m(-3)), 44 ± 27 μg⋅m(-3) (43 ± 10% of 99 ± 54 μg⋅m(-3)), and 25 ± 14 μg⋅m(-3) (35 ± 8% of 70 ± 35 μg⋅m(-3)) in Beijing, Tianjin, and Hebei provinces, respectively. Annually, elimination of residential sources in the BTH region reduced emissions of primary PM2.5 by 32%, compared with 5%, 6%, and 58% achieved by eliminating emissions from the transportation, power, and industry sectors, respectively. We also find air quality in Beijing would benefit substantially from reductions in residential emissions from regional controls in Tianjin and Hebei, indicating the value of policies at the regional level.

  12. Ecological risk assessment of landfill air emissions from a hazardous waste management facility in Ontario

    SciTech Connect

    Durda, J.L.; Suit-Kowalski, L.; Preziosi, D.; Chrostowski, P.C.

    1997-12-31

    An ecological risk assessment was conducted to evaluate the potential for adverse environmental impacts associated with chemicals released to air as a result of a proposed expansion of a hazardous waste landfill in Ontario. The purpose of the risk assessment was to characterize ecological risks associated with the proposed expansion relative to those associated with the existing landfill and those that would exist if the current landfill was completely closed and background conditions prevailed. The ecological risk assessment was one part of a comprehensive environmental impact assessment of the proposed landfill continuation that was being performed under the requirements of Ontario`s Environmental Assessment Act. Air monitoring data from the facility were used to identify a list of 141 chemicals potentially released during landfill continuation, as well as to characterize current emissions and background chemical levels. An ecological risk-based chemical screening process that considered background concentration, source strength, environmental partitioning, bioaccumulation potential, and toxicity was used to select a group of 23 chemicals for detailed evaluation in the ecological risk assessment. Dispersion, deposition, partitioning and bioaccumulation modeling were used to predict potential exposures in ecological receptors. Receptors were selected for evaluation based on regional habitat characteristics, exposure potential, toxicant sensitivity, ecological significance, population status, and societal value. Livestock and agricultural crop and pasture species were key receptors for the assessment, given the highly agricultural nature of the study area. In addition, native wildlife species, including the endangered Henslow`s sparrow and the regionally vulnerable pugnose minnow, also were considered.

  13. Emission of linalool from Valencia orange blossoms and its observation in ambient air

    NASA Astrophysics Data System (ADS)

    Arey, Janet; Corchnoy, Stephanie B.; Atkinson, Roger

    Emission measurements made over a 5-month period of a Valencia orange tree showed the significant emission of the terpenoid linalool (C 10H 18O) from Valencia orange blossoms. The average annual emission rate of this Olinda Valencia orange, derived from emission measurements which include the blossoming season, is a factor of ˜10 higher than the average annual emission rate derived from measurements taken outside of the blossom season. Ambient monoterpene and linalool concentrations were measured in Riverside, California, in the spring and supported the chamber plant emissions data, with linalool concentrations as high as 17 μg m -3 being observed in an orange grove. These results show that current biogenic emission inventories which are formulated from limited survey data, generally not including seasonal variations in the vegetative emissions, can be subject to large uncertainties.

  14. Contribution of ship emissions to the concentration and deposition of air pollutants in Europe

    NASA Astrophysics Data System (ADS)

    Aksoyoglu, Sebnem; Baltensperger, Urs; Prévôt, André S. H.

    2016-02-01

    Emissions from the marine transport sector are one of the least-regulated anthropogenic emission sources and contribute significantly to air pollution. Although strict limits were introduced recently for the maximum sulfur content in marine fuels in the SECAs (sulfur emission control areas) and in EU ports, sulfur emissions outside the SECAs and emissions of other components in all European maritime areas have continued to increase in the last two decades. We have used the air quality model CAMx (Comprehensive Air Quality Model with Extensions) with and without ship emissions for the year 2006 to determine the effects of international shipping on the annual as well as seasonal concentrations of ozone, primary and secondary components of PM2.5, and the dry and wet deposition of nitrogen and sulfur compounds in Europe. The largest changes in pollutant concentrations due to ship emissions were predicted for summer. Concentrations of particulate sulfate increased due to ship emissions in the Mediterranean (up to 60 %), the English Channel and the North Sea (30-35 %), while increases in particulate nitrate levels were found especially in the north, around the Benelux area (20 %), where there were high NH3 land-based emissions. Our model results showed that not only are the atmospheric concentrations of pollutants affected by ship emissions, but also depositions of nitrogen and sulfur compounds increase significantly along the shipping routes. NOx emissions from the ships, especially in the English Channel and the North Sea, cause a decrease in the dry deposition of reduced nitrogen at source regions by moving it from the gas phase to the particle phase which then contributes to an increase in the wet deposition at coastal areas with higher precipitation. In the western Mediterranean region, on the other hand, model results show an increase in the deposition of oxidized nitrogen (mostly HNO3) due to the ship traffic. Dry deposition of SO2 seems to be significant along

  15. Trans-boundary Air Quality and Health Impacts of Emissions in Various Regions in China

    NASA Astrophysics Data System (ADS)

    Gu, Y.; Yim, S. H. L.

    2015-12-01

    In last few decades, China has gone through a rapid development, resulting in urbanization and industrialization. However, the abundant economic achievements were gained at the cost of a sharp deterioration of air quality. Previous research has reported the adverse health outcome from outdoor air pollution in China. Nevertheless, the trans-boundary air quality and health impacts due to emissions in various regions in China have yet fully understood. Our study aims to comprehensively apportion the attribution of emissions in seven regions in China, which are defined based on their geographical locations, to air pollutions, as well as the resultant health impacts in their local areas and other regions, provinces, and cities in China. A regional air quality model is applied to simulate the physical and chemical processes of various pollutants in the atmosphere. The resultant health outcome, such as premature death, is estimated by using the concentration-response functions reported in the literature. We anticipate that our results would serve as a critical reference for research community and policy makers to mitigate the air quality and health impacts of emissions in China.

  16. Identification of the odour and chemical composition of alumina refinery air emissions.

    PubMed

    Coffey, P S; Ioppolo-Armanios, M

    2004-01-01

    Alcoa World Alumina Australia has undertaken comprehensive air emissions monitoring aimed at characterising and quantifying the complete range of emissions to the atmosphere from Bayer refining of alumina at its Western Australian refineries. To the best of our knowledge, this project represents the most complete air emissions inventory of a Bayer refinery conducted in the worldwide alumina industry. It adds considerably to knowledge of air emission factors available for use in emissions estimation required under national pollutant release and transfer registers (NPRTs), such as the Toxic Releases Inventory, USA, and the National Pollutant Inventory, Australia. It also allows the preliminary identification of the key chemical components responsible for characteristic alumina refinery odours and the contribution of these components to the quality, or hedonic tone, of the odours. The strength and acceptability of refinery odours to employees and neighbours appears to be dependent upon where and in what proportion the odorous gases have been emitted from the refineries. This paper presents the results of the programme and develops a basis for classifying the odour properties of the key emission sources in the alumina-refining process.

  17. Increased estimates of air-pollution emissions from Brazilian sugar-cane ethanol

    NASA Astrophysics Data System (ADS)

    Tsao, C.-C.; Campbell, J. E.; Mena-Carrasco, M.; Spak, S. N.; Carmichael, G. R.; Chen, Y.

    2012-01-01

    Accelerating biofuel production has been promoted as an opportunity to enhance energy security, offset greenhouse-gas emissions and support rural economies. However, large uncertainties remain in the impacts of biofuels on air quality and climate. Sugar-cane ethanol is one of the most widely used biofuels, and Brazil is its largest producer. Here we use a life-cycle approach to produce spatially and temporally explicit estimates of air-pollutant emissions over the whole life cycle of sugar-cane ethanol in Brazil. We show that even in regions where pre-harvest field burning has been eliminated on half the croplands, regional emissions of air pollutants continue to increase owing to the expansion of sugar-cane growing areas, and burning continues to be the dominant life-cycle stage for emissions. Comparison of our estimates of burning-phase emissions with satellite estimates of burning in São Paulo state suggests that sugar-cane field burning is not fully accounted for in satellite-based inventories, owing to the small spatial scale of individual fires. Accounting for this effect leads to revised regional estimates of burned area that are four times greater than some previous estimates. Our revised emissions maps thus suggest that biofuels may have larger impacts on regional climate forcing and human health than previously thought.

  18. Quantifying the emissions and air quality co-benefits of lower-carbon electricity production

    NASA Astrophysics Data System (ADS)

    Plachinski, Steven D.; Holloway, Tracey; Meier, Paul J.; Nemet, Gregory F.; Rrushaj, Arber; Oberman, Jacob T.; Duran, Phillip L.; Voigt, Caitlin L.

    2014-09-01

    The impact of air emissions from electricity generation depends on the spatial distribution of power plants and electricity dispatch decisions. Thus, any realistic evaluation of the air quality impacts of lower-carbon electricity must account for the spatially heterogeneous changes in associated emissions. Here, we present an analysis of the changes in fine particulate matter (PM2.5) associated with current, expected, and proposed energy efficiency and renewable energy policies in Wisconsin. We simulate the state's electricity system and its potential response to policies using the MyPower electricity-sector model, which calculates plant-by-plant reductions in NOx and SO2 emissions. We find that increased efficiency and renewable generation in a 2024 policy scenario substantially reduce statewide emissions of NOx and SO2 (55% and 59% compared to 2008, 32% and 33% compared to 2024 business-as-usual, BAU). PM2.5 is quantified across the Great Lakes region using the EPA Community Multiscale Air Quality (CMAQ) model for some emissions scenarios. We find that summer mean surface concentrations of sulfate and PM2.5 are less sensitive to policy changes than emissions. In the 2024 policy scenario, sulfate aerosol decreases less than 3% over most of the region relative to BAU and 3-13% relative to 2008 over most of Wisconsin. The lower response of these secondary aerosols arises from chemical and meteorological processing of electricity emissions, and mixing with other emission sources. An analysis of model performance and response to emission reduction at five sites in Wisconsin shows good model agreement with observations and a high level of spatial and temporal variability in sulfate and PM2.5 reductions. In this case study, the marginal improvements in emissions and air quality associated with carbon policies were less than the technology, renewable, and conservation assumptions under a business-as-usual scenario. However, this analysis for Wisconsin shows how

  19. Factorization of air pollutant emissions: projections versus observed trends in Europe.

    PubMed

    Rafaj, Peter; Amann, Markus; Siri, José G

    2014-10-01

    This paper revisits the emission scenarios of the European Commission's 2005 Thematic Strategy on Air Pollution (TSAP) in light of today's knowledge. We review assumptions made in the past on the main drivers of emission changes, i.e., demographic trends, economic growth, changes in the energy intensity of GDP, fuel-switching, and application of dedicated emission control measures. Our analysis shows that for most of these drivers, actual trends have not matched initial expectations. Observed ammonia and sulfur emissions in European Union in 2010 were 10% to 20% lower than projected, while emissions of nitrogen oxides and particulate matter exceeded estimates by 8% to 15%. In general, a higher efficiency of dedicated emission controls compensated for a lower-than-expected decline in total energy consumption as well as a delay in the phase-out of coal. For 2020, updated projections anticipate lower sulfur and nitrogen oxide emissions than those under the 2005 baseline, whereby the degree to which these emissions are lower depends on what assumptions are made for emission controls and new vehicle standards. Projected levels of particulates are about 10% higher, while smaller differences emerge for other pollutants. New emission projections suggest that environmental targets established by the TSAP for the protection of human health, eutrophication and forest acidification will not be met without additional measures. PMID:25058894

  20. Factorization of air pollutant emissions: projections versus observed trends in Europe.

    PubMed

    Rafaj, Peter; Amann, Markus; Siri, José G

    2014-10-01

    This paper revisits the emission scenarios of the European Commission's 2005 Thematic Strategy on Air Pollution (TSAP) in light of today's knowledge. We review assumptions made in the past on the main drivers of emission changes, i.e., demographic trends, economic growth, changes in the energy intensity of GDP, fuel-switching, and application of dedicated emission control measures. Our analysis shows that for most of these drivers, actual trends have not matched initial expectations. Observed ammonia and sulfur emissions in European Union in 2010 were 10% to 20% lower than projected, while emissions of nitrogen oxides and particulate matter exceeded estimates by 8% to 15%. In general, a higher efficiency of dedicated emission controls compensated for a lower-than-expected decline in total energy consumption as well as a delay in the phase-out of coal. For 2020, updated projections anticipate lower sulfur and nitrogen oxide emissions than those under the 2005 baseline, whereby the degree to which these emissions are lower depends on what assumptions are made for emission controls and new vehicle standards. Projected levels of particulates are about 10% higher, while smaller differences emerge for other pollutants. New emission projections suggest that environmental targets established by the TSAP for the protection of human health, eutrophication and forest acidification will not be met without additional measures.

  1. Present-day and future global bottom-up ship emission inventories including polar routes.

    PubMed

    Paxian, Andreas; Eyring, Veronika; Beer, Winfried; Sausen, Robert; Wright, Claire

    2010-02-15

    We present a global bottom-up ship emission algorithm that calculates fuel consumption, emissions, and vessel traffic densities for present-day (2006) and two future scenarios (2050) considering the opening of Arctic polar routes due to projected sea ice decline. Ship movements and actual ship engine power per individual ship from Lloyd's Marine Intelligence Unit (LMIU) ship statistics for six months in 2006 and further mean engine data from literature serve as input. The developed SeaKLIM algorithm automatically finds the most probable shipping route for each combination of start and destination port of a certain ship movement by calculating the shortest path on a predefined model grid while considering land masses, sea ice, shipping canal sizes, and climatological mean wave heights. The resulting present-day ship activity agrees well with observations. The global fuel consumption of 221 Mt in 2006 lies in the range of previously published inventories when undercounting of ship numbers in the LMIU movement database (40,055 vessels) is considered. Extrapolated to 2007 and ship numbers per ship type of the recent International Maritime Organization (IMO) estimate (100,214 vessels), a fuel consumption of 349 Mt is calculated which is in good agreement with the IMO total of 333 Mt. The future scenarios show Arctic polar routes with regional fuel consumption on the Northeast and Northwest Passage increasing by factors of up to 9 and 13 until 2050, respectively. PMID:20088494

  2. Present-day and future global bottom-up ship emission inventories including polar routes.

    PubMed

    Paxian, Andreas; Eyring, Veronika; Beer, Winfried; Sausen, Robert; Wright, Claire

    2010-02-15

    We present a global bottom-up ship emission algorithm that calculates fuel consumption, emissions, and vessel traffic densities for present-day (2006) and two future scenarios (2050) considering the opening of Arctic polar routes due to projected sea ice decline. Ship movements and actual ship engine power per individual ship from Lloyd's Marine Intelligence Unit (LMIU) ship statistics for six months in 2006 and further mean engine data from literature serve as input. The developed SeaKLIM algorithm automatically finds the most probable shipping route for each combination of start and destination port of a certain ship movement by calculating the shortest path on a predefined model grid while considering land masses, sea ice, shipping canal sizes, and climatological mean wave heights. The resulting present-day ship activity agrees well with observations. The global fuel consumption of 221 Mt in 2006 lies in the range of previously published inventories when undercounting of ship numbers in the LMIU movement database (40,055 vessels) is considered. Extrapolated to 2007 and ship numbers per ship type of the recent International Maritime Organization (IMO) estimate (100,214 vessels), a fuel consumption of 349 Mt is calculated which is in good agreement with the IMO total of 333 Mt. The future scenarios show Arctic polar routes with regional fuel consumption on the Northeast and Northwest Passage increasing by factors of up to 9 and 13 until 2050, respectively.

  3. Emission of bisphenol analogues including bisphenol A and bisphenol F from wastewater treatment plants in Korea.

    PubMed

    Lee, Sunggyu; Liao, Chunyang; Song, Geum-Ju; Ra, Kongtae; Kannan, Kurunthachalam; Moon, Hyo-Bang

    2015-01-01

    Due to the regulation on bisphenol A (BPA) in several industrialized countries, the demand for other bisphenol analogues (BPs) as substitutes for BPA is growing. Eight BPs were determined in sludge from 40 representative wastewater treatment plants (WWTPs) in Korea. Total concentrations of BPs (ΣBP) in sludge ranged from emissions of BPs ranged from 0.04 (BPP) to 886 g capita(-1) d (BPA) through WWTP discharges. The emission fluxes of ΣBP through industrial WWTPs were 2-3 orders of magnitudes higher than those calculated for domestic WWTPs, indicating that industrial discharges are the major source of BPs into the Korean environment. This is the first nationwide survey of BPs in sludge from Korean WWTPs.

  4. Regional air quality impacts of future fire emissions in Sumatra and Kalimantan

    NASA Astrophysics Data System (ADS)

    Marlier, Miriam E.; DeFries, Ruth S.; Kim, Patrick S.; Gaveau, David L. A.; Koplitz, Shannon N.; Jacob, Daniel J.; Mickley, Loretta J.; Margono, Belinda A.; Myers, Samuel S.

    2015-05-01

    Fire emissions associated with land cover change and land management contribute to the concentrations of atmospheric pollutants, which can affect regional air quality and climate. Mitigating these impacts requires a comprehensive understanding of the relationship between fires and different land cover change trajectories and land management strategies. We develop future fire emissions inventories from 2010-2030 for Sumatra and Kalimantan (Indonesian Borneo) to assess the impact of varying levels of forest and peatland conservation on air quality in Equatorial Asia. To compile these inventories, we combine detailed land cover information from published maps of forest extent, satellite fire radiative power observations, fire emissions from the Global Fire Emissions Database, and spatially explicit future land cover projections using a land cover change model. We apply the sensitivities of mean smoke concentrations to Indonesian fire emissions, calculated by the GEOS-Chem adjoint model, to our scenario-based future fire emissions inventories to quantify the different impacts of fires on surface air quality across Equatorial Asia. We find that public health impacts are highly sensitive to the location of fires, with emissions from Sumatra contributing more to smoke concentrations at population centers across the region than Kalimantan, which had higher emissions by more than a factor of two. Compared to business-as-usual projections, protecting peatlands from fires reduces smoke concentrations in the cities of Singapore and Palembang by 70% and 40%, and by 60% for the Equatorial Asian region, weighted by the population in each grid cell. Our results indicate the importance of focusing conservation priorities on protecting both forested (intact or logged) peatlands and non-forested peatlands from fire, even after considering potential leakage of deforestation pressure to other areas, in order to limit the impact of fire emissions on atmospheric smoke concentrations and

  5. Effects of reducing SO2 and NOx emission from ships on air quality in Alaska

    NASA Astrophysics Data System (ADS)

    Tran, T. T.; Mölders, N.

    2011-12-01

    We performed simulations with the Alaska-adapted WRF/Chem using the same meteorological conditions of January 2000, but alternatively applying the emissions of 2000 (REF), emissions of 2000 with the ship-emission reductions for the planned North American Emission Contral Area (ECA) for SO2 only (ECA1) and SO2 and NOx (ECA2) that have been proposed by the International Maritime Organization for 2015. The analysis focused on the air quality along the international shipping lanes (ISL), in the ECA and over Alaska (AK). Our goal is to examine how the decreases in ship emissions in the ISL and ECA affect to air quality in Alaska. Our model results show that reducing SO2 and NOx ship-emissions reduces the concentration of sulfur and nitrogen compounds over Alaska despite of no changes in Alaska emissions. The reductions of pollutants over the ISL, ECA and AK stemming from concurrent SO2-NOx ship emission reductions are an order of magnitude of those stemming from SO2 reduction in ship emissions only. Reductions in sulfur compounds reach up to 14km while reductions of nitrogen compounds reach to only about 7km. Reductions of sulfate and nitrate in clouds are highest at the top of the boundary layer. Among the three regions of interest, strongest reductions occur over the ECA and ISL for sulfur and nitrogen compounds, respectively, since the ECA (ISL) has highest reductions of SO2 (NOx). The PM2.5 speciation partitioning over all three regions marginally changes when the ship emissions change. Sulfate is the major component of PM2.5 in all regions. Closer to the land, organic carbon (OC) partitioning is higher indicating the enhancing impacts of inland anthropogenic emissions to total PM2.5 concentrations over land.

  6. Advanced Remote-Sensing Imaging Emission Spectrometer (ARIES): AIRS Spectral Resolution with MODIS Spatial Resolution

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Chahine, Moustafa T.; Aumann, Hartmut H.; OCallaghan, Fred

    2006-01-01

    The Advanced Remote-sensing Imaging Emission Spectrometer (ARIES) will measure a wide range of earth quantities fundamental to the study of global climate change. It will build upon the success of the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Atmospheric Infrared Sounder (AIRS) instruments currently flying on the EOS Aqua Spacecraft. Both instruments are facility instruments for NASA providing data to thousands of scientists investigating land, ocean and atmospheric Earth System processes. ARIES will meet all the requirements of AIRS and MODIS in a single compact instrument, while providing the next-generation capability of improved spatial resolution for AIRS and improved spectral resolution for MODIS.

  7. Characteristics of emissions of air pollutants from mosquito coils and candles burning in a large environmental chamber

    NASA Astrophysics Data System (ADS)

    Lee, S. C.; Wang, B.

    The objective of this study was to characterize the emissions of air pollutants from mosquito coils and candles burning in a large environmental test chamber. The target pollutants included particulate matters (PM 10, PM 2.5), carbon monoxide (CO), nitrogen oxides (NO x), methane (CH 4), non-methane hydrocarbons (NMHC), volatile organic compounds (VOCs) and carbonyl compounds. The average PM 10 concentrations for all tested mosquito coils exceeded Excellent and Good Classes objectives specified by Indoor Air Quality Objectives for Office Buildings and Public Places (IAQO) [ HKEPD, 2003. Guidance Notes for the Management of Indoor Air Quality in Offices and Public Places. Indoor Air Quality Management Group, The Government of the Hong Kong Special Administrative Region]. The emission factors (mg g -1 mosquito coil) of mosquito coils combustion were: PM 2.5, 20.3-47.8; PM 10, 15.9-50.8; CO, 74.6-89.1; NO, 0.1-0.5; NO 2, n.d.-0.1; NO x, 0.1-0.5; CH 4, n.d.-4.7; NMHC, 0.1-5.7. Formaldehyde and acetaldehyde were the most abundant carbonyls species in the coil smoke. The average concentrations of formaldehyde and benzene of all tested mosquito coils exceeded Good Class of IAQO. Nitrogen oxides were the most abundant gas pollutants relating to candle burning among all target air pollutants. The candle made of gel (CAN 4) would emit more air pollutants than the paraffin candles (CAN 1, 2 and 3) and beeswax candle (CAN 5). Among five candles tested, CAN 5, the one made of beeswax, generated relatively smaller amount of air pollutants. It was noted that the concentrations of most VOCs from candles combustion were below the detection limit.

  8. Influence of specimen size, tray inclination and air flow rate on the emission of gases from biomass combustion

    NASA Astrophysics Data System (ADS)

    Amorim, E. B.; Carvalho, J. A.; Soares Neto, T. G.; Anselmo, E.; Saito, V. O.; Dias, F. F.; Santos, J. C.

    2013-08-01

    Experiments of biomass combustion were performed to determine whether specimen size, tray inclination, or combustion air flow rate was the factor that most affects the emission of carbon dioxide, carbon monoxide, and methane. The chosen biomass was Eucalyptus citriodora, a very abundant species in Brazil, utilized in many industrial applications, including combustion for energy generation. Analyses by gas chromatograph and specific online instruments were used to determine the concentrations of the main emitted gases, and the following figures were found for the emission factors: 1400 ± 101 g kg-1 of CO2, 50 ± 13 g kg-1 of CO, and 3.2 ± 0.5 g kg-1 of CH4, which agree with values published in the literature for biomass from the Amazon rainforest. Statistical analysis of the experiments determined that specimen size most significantly affected the emission of gases, especially CO2 and CO.

  9. [Situation and Characteristics of Air Pollutants Emission from Crematories in Beijing, China].

    PubMed

    Xue, Yi-feng; Yan, Jing; Tian, He-zhong; Xiong, Cheng-cheng; Li, Jing-dong; Wu, Xiao-ing; Wang, Wei

    2015-06-01

    Hazardous Air Pollutants (HAPs) such as exhaust particulate matter (PM), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen oxide (NOx), mercury (Hg) and polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-furans ( PCDD/Fs) are emitted by the process of cremation and the burning of oblation. Risks to health posed by emissions of hazardous air pollutants from crematories are emerging concerns. Through field investigation and data collection, we obtained the related activity levels and monitored the concentrations of air pollutants from typical cremators, so as to better understand the current pollutants emission levels for crematory. Using the emission factor method, we calculated the emission inventory of HAPs for crematory of Beijing in 2012 and quantified the range of uncertainty. Using atmospheric diffusion model ADMS, we evaluated the influence of crematories on the surrounding environment, and identified the characteristics of air pollution. The results showed that: for the cremators installed with flue gas purification system, the emission concentration of exhaust PM was rather low, and the CO emission concentration fluctuated greatly. However, relative high emission concentrations of PCDD/Fs were detected mainly due to insufficient combustion. Exhaust PM, CO, SO2, NOx, Hg and PCDD/Fs emitted by crematory of Beijing in 2012 were estimated at about 11. 5 tons, 41.25 tons, 2.34 tons, 7.65 tons, 13.76 kg and 0.88 g, respectively; According to the results of dispersion model simulation, the concentration contributions of exhaust PM, CO, SO2, NOx, Hg, PCDD/Fs from crematories were 0.05947 microg x m(-3), 0.2009 microg x m(-3) and 0.0126 microg x m(-3), 0.03667 microg x m(-3) and 0.06247 microg x m(-3), 0.004213 microg x m(-3), respectively.

  10. [Situation and Characteristics of Air Pollutants Emission from Crematories in Beijing, China].

    PubMed

    Xue, Yi-feng; Yan, Jing; Tian, He-zhong; Xiong, Cheng-cheng; Li, Jing-dong; Wu, Xiao-ing; Wang, Wei

    2015-06-01

    Hazardous Air Pollutants (HAPs) such as exhaust particulate matter (PM), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen oxide (NOx), mercury (Hg) and polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-furans ( PCDD/Fs) are emitted by the process of cremation and the burning of oblation. Risks to health posed by emissions of hazardous air pollutants from crematories are emerging concerns. Through field investigation and data collection, we obtained the related activity levels and monitored the concentrations of air pollutants from typical cremators, so as to better understand the current pollutants emission levels for crematory. Using the emission factor method, we calculated the emission inventory of HAPs for crematory of Beijing in 2012 and quantified the range of uncertainty. Using atmospheric diffusion model ADMS, we evaluated the influence of crematories on the surrounding environment, and identified the characteristics of air pollution. The results showed that: for the cremators installed with flue gas purification system, the emission concentration of exhaust PM was rather low, and the CO emission concentration fluctuated greatly. However, relative high emission concentrations of PCDD/Fs were detected mainly due to insufficient combustion. Exhaust PM, CO, SO2, NOx, Hg and PCDD/Fs emitted by crematory of Beijing in 2012 were estimated at about 11. 5 tons, 41.25 tons, 2.34 tons, 7.65 tons, 13.76 kg and 0.88 g, respectively; According to the results of dispersion model simulation, the concentration contributions of exhaust PM, CO, SO2, NOx, Hg, PCDD/Fs from crematories were 0.05947 microg x m(-3), 0.2009 microg x m(-3) and 0.0126 microg x m(-3), 0.03667 microg x m(-3) and 0.06247 microg x m(-3), 0.004213 microg x m(-3), respectively. PMID:26387295

  11. Global Scenarios of Air Pollutant Emissions from Road Transport through to 2050

    PubMed Central

    Takeshita, Takayuki

    2011-01-01

    This paper presents global scenarios of sulphur dioxide (SO2), nitrogen oxides (NOx), and particulate matter (PM) emissions from road transport through to 2050, taking into account the potential impacts of: (1) the timing of air pollutant emission regulation implementation in developing countries; (2) global CO2 mitigation policy implementation; and (3) vehicle cost assumptions, on study results. This is done by using a global energy system model treating the transport sector in detail. The major conclusions are the following. First, as long as non-developed countries adopt the same vehicle emission standards as in developed countries within a 30-year lag, global emissions of SO2, NOx, and PM from road vehicles decrease substantially over time. Second, light-duty vehicles and heavy-duty trucks make a large and increasing contribution to future global emissions of SO2, NOx, and PM from road vehicles. Third, the timing of air pollutant emission regulation implementation in developing countries has a large impact on future global emissions of SO2, NOx, and PM from road vehicles, whereas there is a possibility that global CO2 mitigation policy implementation has a comparatively small impact on them. PMID:21845172

  12. Modelling the impacts of ammonia emissions reductions on North American air quality

    NASA Astrophysics Data System (ADS)

    Makar, P. A.; Moran, M. D.; Zheng, Q.; Cousineau, S.; Sassi, M.; Duhamel, A.; Besner, M.; Davignon, D.; Crevier, L.-P.; Bouchet, V. S.

    2009-09-01

    A unified regional air-quality modelling system (AURAMS) was used to investigate the effects of reductions in ammonia emissions on regional air quality, with a focus on particulate-matter formation. Three simulations of one-year duration were performed for a North American domain: (1) a base-case simulation using 2002 Canadian and US national emissions inventories augmented by a more detailed Canadian emissions inventory for agricultural ammonia; (2) a 30% North-American-wide reduction in agricultural ammonia emissions; and (3) a 50% reduction in Canadian beef-cattle ammonia emissions. The simulations show that a 30% continent-wide reduction in agricultural ammonia emissions lead to reductions in median hourly PM2.5 mass of <1 μg m-3 on an annual basis. The atmospheric response to these emission reductions displays marked seasonal variations, and on even shorter time scales, the impacts of the emissions reductions are highly episodic: 95th-percentile hourly PM2.5 mass decreases can be up to a factor of six larger than the median values. A key finding of the modelling work is the linkage between gas and aqueous chemistry and transport; reductions in ammonia emissions affect gaseous ammonia concentrations close to the emissions site, but substantial impacts on particulate matter and atmospheric deposition often occur at considerable distances downwind, with particle nitrate being the main vector of ammonia/um transport. Ammonia emissions reductions therefore have trans-boundary consequences downwind. Calculations of critical-load exceedances for sensitive ecosystems in Canada suggest that ammonia emission reductions will have a minimal impact on current ecosystem acidification within Canada, but may have a substantial impact on future ecosystem acidification. The 50% Canadian beef-cattle ammonia emissions reduction scenario was used to examine model sensitivity to uncertainties in the new Canadian agricultural ammonia emissions inventory, and the simulation results

  13. Traffic source emission and street level air pollution in urban areas of Guangzhou, South China (P.R.C.)

    NASA Astrophysics Data System (ADS)

    Qin, Y.; Chan, L. Y.

    Street level air pollution due to traffic emission is a cause of concern in Guangzhou City. During the winter and summer of 1988, the traffic-related air pollutant concentrations, wind field, traffic volume and vehicle speed were measured extensively in three types of street canyons in Guangzhou City. Various types of motor vehicle emission in idle condition were measured and the composite emission factors of vehicles were derived. The variation of traffic volume and vehicle speed in 223 mainstreets were also investigated. The annual air pollutant concentration levels of traffic source emission were calculated. Using CO as a traffic emission tracer for air pollution on the street, the contributions of traffic emission to street level air pollution were determined by the receptor method. Ground level air pollution in Guangzhou has changed from coal combustion emission type into traffic source emission type. The average contributions of traffic source emission to the concentration of CO and NO x on the street in 1988 are about 87% and 67%. The most significant pollutant of ambient air quality that traffic source emission influences in NO x.

  14. Development of a speciated, hourly, and gridded air pollutants emission modeling system--a case study on the precursors of photochemical smog in the Seoul metropolitan area, Korea.

    PubMed

    Kim, D Y; Kim, J W

    2000-03-01

    A speciated, hourly, and gridded air pollutants emission modeling system (SHEMS) was developed and applied in predicting hourly nitrogen dioxide (NO2) and ozone (O3) levels in the Seoul Metropolitan Area (SMA). The primary goal of the SHEMS was to produce a systemized emission inventory for air pollutants including ozone precursors for modeling air quality in urban areas. The SHEMS is principally composed of three parts: (1) a pre-processor to process emission factors, activity levels, and spatial and temporal information using a geographical information system; (2) an emission model for each source type; and (3) a post-processor to produce report and input data for air quality models through database modeling. The source categories in SHEMS are point, area, mobile, natural, and other sources such as fugitive emissions. The emission database produced by SHEMS contains 22 inventoried compounds: sulfur dioxide, NO2, carbon monoxide, and 19 speciated volatile organic compounds. To validate SHEMS, the emission data were tested with the Urban Airshed Model to predict NO2 and O3 concentrations in the SMA during selected episode days in 1994. The results turned out to be reliable in describing temporal variation and spatial distribution of those pollutants.

  15. Research on the Emission Inventory of Major Air Pollutants in 2012 for the Sichuan City Cluster in China

    NASA Astrophysics Data System (ADS)

    Qian, J.; He, Q.

    2014-12-01

    This paper developed a high resolution emission inventory of major pollutants in city cluster of Sichuan Basin, one of the most polluted regions in China. The city cluster included five cities, which were Chengdu, Deyang, Mianyang, Meishan and Ziyang. Pollution source census and field measurements were conducted for the major emission sources such as the industry sources, on-road mobile sources, catering sources and the dust sources. The inventory results showed that in the year of 2012, the emission of SO2、NOX、CO、PM10、PM2.5、VOCs and NH3 in the region were 143.5、251.9、1659.9、299.3、163.5、464.1 and 995kt respectively. Chengdu, the provincial capital city, had the largest emission load of every pollutant among the cities. The industry sources, including power plants, fuel combustion facilities and non-combustion processes were the largest emission sources for SO2、NOX and CO, contributing to 84%, 46.5%, 35% of total SO2, NOX and CO emissions. On-road mobile sources accounted for 46.5%, 33%, 16% of the total NOx, CO, PM2.5 emissions and 28% of the anthropogenic VOCs emission. Dust and industry sources contributed to 42% and 23% of the PM10 emission with the dust sources also as the largest source of PM2.5, contributing to 27%. Anthropogenic and biogenic sources took 75% and 25% of the total VOCs emission while 36% of anthropogenic VOCs emission was owing to solvent use. Livestock contributed to 62% of NH3 emissions, followed by nitrogen fertilizer application whose contribution was 23%. Based on the developed emission inventory and local meteorological data, the regional air quality modeling system WRF-CMAQ was applied to simulate the status of PM2.5 pollution in a regional scale. The results showed that high PM2.5 concentration was distributed over the urban area of Chengdu and Deyang. On-road mobile sources and dust sources were two major contributors to the PM2.5 pollution in Chengdu, both had an contribution ratio of 27%. In Deyang, Mianyang

  16. National Emission Standards for Hazardous Air Pollutants Submittal - 1998

    SciTech Connect

    Stuart Black; Yvonne Townsend

    1999-06-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy Nevada Operations Office (DOE/NV) as the site for nuclear weapons testing, now limited to readiness activities and experiments in support of the national Stockpile Stewardship Management Program. It is located in Nye County, Nevada, with the southeast corner about 105 km (65 mi) northwest of Las Vegas, Nevada. The NTS covers about 3,500 km2 (1,350 mi2), an area larger than Rhode Island. Its size is about 46 to 56 km (28 to 35 mi) east to west and from 64 to 88 km (40 to 55 mi)north to south. The NTS is surrounded, except on the south side, by public exclusion areas (Nellis Air Force Range) that provide another 24 to 104 km (15 to 65 mi) between the NTS and public lands. The NTS is characterized by desert valley and Great Basin mountain topography, with a climate, flora, and fauna typical of the southwest deserts. Surface waters are scarce on the NTS and there is great depth to slow-moving groundwater.

  17. National Emission Standards for Hazardous Air Pollutants Calendar Year 1999

    SciTech Connect

    R. F. Grossman

    2000-06-01

    The Nevada Test Site (NTS) is operated by the US Department of Energy's Nevada Operations Office (DOE/NV) as the site for nuclear weapons testing, now limited to readiness activities and experiments in support of the national Stockpile Stewardship Management Program. It is located in Nye County, Nevada, with the southeast corner about 105 km (65 mi) northwest of Las Vegas, Nevada. The NTS covers about 3,561 km{sup 2} (1,375 mi{sup 2}), an area larger than Rhode Island. Its size is about 46 to 56 km (28 to 35 mi) east to west and from 64 to 88 km (40 to 55 mi) north to south. The NTS is surrounded, except on the south side, by public exclusion areas (Nellis Air Force Range [NAFR]) that provide another 24 to 104 km (15 to 65 mi) between the NTS and public lands. The NTS is characterized by desert valley and Great Basin mountain topography, with a climate, flora, and fauna typical of the southwest deserts. Population density within 150 km (93 mi) of the NTS is only about 0.2 persons per square kilometer, excluding the Las Vegas area. Restricted access, low population density in the surrounding area, and extended wind transport times are advantageous factors for the activities conducted at the NTS. Surface waters are scarce on the NTS and there is great depth to slow-moving groundwater.

  18. 30 CFR 250.218 - What air emissions information must accompany the EP?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the EP? 250.218 Section 250.218 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION, AND... SHELF Plans and Information Contents of Exploration Plans (ep) § 250.218 What air emissions information... volatile organic compounds (VOC) that will be generated by your proposed exploration activities. (1)...

  19. 30 CFR 550.218 - What air emissions information must accompany the EP?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... the EP? 550.218 Section 550.218 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, DEPARTMENT OF THE... Contents of Exploration Plans (ep) § 550.218 What air emissions information must accompany the EP? The... will be generated by your proposed exploration activities. (1) For each source on or associated...

  20. 30 CFR 550.218 - What air emissions information must accompany the EP?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the EP? 550.218 Section 550.218 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, DEPARTMENT OF THE... Contents of Exploration Plans (ep) § 550.218 What air emissions information must accompany the EP? The... will be generated by your proposed exploration activities. (1) For each source on or associated...