Science.gov

Sample records for air ions generated

  1. Trial of a negative ion generator device in remediating problems related to indoor air quality

    SciTech Connect

    Daniell, W.; Camp, J.; Horstman, S. )

    1991-06-01

    It has been suggested that supplementation of indoor air with negative ions can improve air quality. This study examined the effects of a negative ion-generator device on air contaminants and symptom reporting in two office buildings. Separate sets of functional and nonfunctional negative ion generators were monitored using a double blind, crossover design involving two 5-week exposure periods. There were no detectable direct or residual effects of negative ion generator use on air ion levels, airborn particulates, carbon dioxide levels, or symptom reporting. Symptom reporting declined at both sites initially and appeared to be consistent with placebo effect. Job dissatisfaction was an apparent contributor to symptom reporting, with a magnitude comparable to presumed effects of air quality. Further testing of such devices is needed before they should be considered for office air quality problems.

  2. Air Purification Effect of Positively and Negatively Charged Ions Generated by Discharge Plasma at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Nishikawa, Kazuo; Nojima, Hideo

    2001-08-01

    In this paper, the air purification effect of positively and negatively charged ions generated by discharge plasma at atmospheric pressure is reported. We have developed a novel ion generation device which consists of a cylindrical glass tube and attached inner and outer mesh electrodes. With the application of AC voltage between the electrodes, positively charged ions and negatively charged ions have been generated at atmospheric pressure. The ion densities of 3.0× 104--7.0× 104 counts/cm3 have been obtained with the AC voltage of 1.8-2.3 kV (effective value). We have examined the air purification properties of this device. By the operation of this device, the initial oxygen nitride (NO) density of 10 ppm in 1 m3 (in cigarette smoke) was decreased to 1 ppm after 30 min. The number of suspended germs in air has been significantly reduced by the use of this type of ion generation device.

  3. Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

    PubMed

    Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

    2007-10-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented.

  4. [Negative air ions generated by plants upon pulsed electric field stimulation applied to soil].

    PubMed

    Wu, Ren-ye; Deng, Chuan-yuan; Yang, Zhi-jian; Weng, Hai-yong; Zhu, Tie-jun-rong; Zheng, Jin-gui

    2015-02-01

    This paper investigated the capacity of plants (Schlumbergera truncata, Aloe vera var. chinensis, Chlorophytum comosum, Schlumbergera bridgesii, Gymnocalycium mihanovichii var. friedrichii, Aspidistra elatior, Cymbidium kanran, Echinocactus grusonii, Agave americana var. marginata, Asparagus setaceus) to generate negative air ions (NAI) under pulsed electric field stimulation. The results showed that single plant generated low amounts of NAI in natural condition. The capacity of C. comosum and G. mihanovichii var. friedrichii generated most NAI among the above ten species, with a daily average of 43 ion · cm(-3). The least one was A. americana var. marginata with the value of 19 ion · cm(-3). When proper pulsed electric field stimulation was applied to soil, the NAI of ten plant species were greatly improved. The effect of pulsed electric field u3 (average voltage over the pulse period was 2.0 x 10(4) V, pulse frequency was 1 Hz, and pulse duration was 50 ms) was the greatest. The mean NAI concentration of C. kanran was the highest 1454967 ion · cm(-3), which was 48498.9 times as much as that in natural condition. The lowest one was S. truncata with the value of 34567 ion · cm(-3), which was 843.1 times as much as that in natural condition. The capacity of the same plants to generate negative air ion varied extremely under different intensity pulsed electric fields.

  5. Air ion exposure system for plants.

    PubMed

    Morrow, R C; Tibbitts, T W

    1987-02-01

    A system was developed for subjecting plants to elevated air ion levels. This system consisted of a rectangular Plexiglas chamber lined with a Faraday cage. Air ions were generated by corona discharge from frayed stainless steel fibers placed at one end of the chamber. This source was capable of producing varying levels of either positive or negative air ions. During plant exposures, environmental conditions were controlled by operating the unit in a growth chamber.

  6. Air ion exposure system for plants

    NASA Technical Reports Server (NTRS)

    Morrow, R. C.; Tibbitts, T. W.

    1987-01-01

    A system was developed for subjecting plants to elevated air ion levels. This system consisted of a rectangular Plexiglas chamber lined with a Faraday cage. Air ions were generated by corona discharge from frayed stainless steel fibers placed at one end of the chamber. This source was capable of producing varying levels of either positive or negative air ions. During plant exposures, environmental conditions were controlled by operating the unit in a growth chamber.

  7. Negative ion generator

    DOEpatents

    Stinnett, Regan W.

    1984-01-01

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions.

  8. Negative ion generator

    DOEpatents

    Stinnett, R.W.

    1984-05-08

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions. 8 figs.

  9. Ion beam generating apparatus

    DOEpatents

    Brown, Ian G.; Galvin, James

    1987-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  10. ION PULSE GENERATION

    DOEpatents

    King, R.F.; Moak, C.D.; Parker, V.E.

    1960-10-11

    A device for generating ions in an ion source, forming the ions into a stream, deflecting the stream rapidly away from and back to its normal path along the axis of a cylindrical housing, and continually focusing the stream by suitable means into a sharp, intermittent beam along the axis is described. The beam exists through an axial aperture into a lens which focuses it into an accelerator tube. The ions in each burst are there accelerated to very high energies and are directed against a target placed in the high-energy end of the tube. Radiations from the target can then be analyzed in the interval between incidence of the bursts of ions on the target.

  11. Air ions and aerosol science

    SciTech Connect

    Tammet, H.

    1996-03-01

    Collaboration between Gas Discharge and Plasma Physics, Atmospheric Electricity, and Aerosol Science is a factor of success in the research of air ions. The concept of air ion as of any carrier of electrical current through the air is inherent to Atmospheric Electricity under which a considerable statistical information about the air ion mobility spectrum is collected. A new model of air ion size-mobility correlation has been developed proceeding from Aerosol Science and joining the methods of neighboring research fields. The predicted temperature variation of the mobility disagrees with the commonly used Langevin rule for the reduction of air ion mobilities to the standard conditions. Concurrent errors are too big to be neglected in applications. The critical diameter distinguishing cluster ions and charged aerosol particles has been estimated to be 1.4{endash}1.8 nm. {copyright} {ital 1996 American Institute of Physics.}

  12. Intense ion beam generator

    DOEpatents

    Humphries, Jr., Stanley; Sudan, Ravindra N.

    1977-08-30

    Methods and apparatus for producing intense megavolt ion beams are disclosed. In one embodiment, a reflex triode-type pulsed ion accelerator is described which produces ion pulses of more than 5 kiloamperes current with a peak energy of 3 MeV. In other embodiments, the device is constructed so as to focus the beam of ions for high concentration and ease of extraction, and magnetic insulation is provided to increase the efficiency of operation.

  13. Next-generation air monitoring

    EPA Science Inventory

    Air pollution measurement technology is advancing rapidly towards smaller-scale and wireless devices, with a potential to significantly change the landscape of air pollution monitoring. EPA is evaluating and developing a range of next-generation air monitoring (NGAM) technologie...

  14. Next Generation Air Monitoring

    EPA Science Inventory

    Abstract. Air pollution measurement technology is advancing rapidly towards smaller-scale and wireless devices, with a potential to significantly change the landscape of air pollution monitoring. The U.S. EPA Office of Research and Development is evaluating and developing a rang...

  15. Electrets to measure ion concentration in air.

    PubMed

    Kotrappa, P

    2005-08-01

    Positive and negative ions are produced in air, mainly due to radon and terrestrial/cosmic radiation sources. Measuring ion concentration in air indirectly provides a measure of these sources. Electrets (electrically charged pieces of Teflon), when exposed in the environment, collect ions of opposite sign leading to a measurable decrease in charge, depending upon the exposure time and ion concentration. This work describes a method of correlating electret discharge rate to the ion concentration as measured by a calibrated ion density meter. Once calibrated, electrets can then be used to measure ion concentration of either sign. The ion concentration in ambient air was measured to be about 200 ions mL(-1), measured over several hours. Both positive and negative ion concentrations were similar. In a typical room, negative ion concentration was about 3,500 ions mL(-1), and, surprisingly, there were no positive ions at all in that room. Being an integrating passive device, the method provides the unique possibility of measuring low or high concentrations of positive or negative ions over extended periods, which is difficult to do with other ion concentration measuring instruments.

  16. Ultrafine particle removal and generation by portable air cleaners

    NASA Astrophysics Data System (ADS)

    Waring, Michael S.; Siegel, Jeffrey A.; Corsi, Richard L.

    Portable air cleaners can both remove and generate pollutants indoors. To investigate these phenomena, we conducted a two-phase investigation in a 14.75 m 3 stainless steel chamber. In the first phase, particle size-resolved (12.6-514 nm diameter) clean air delivery rates (CADR) and efficiencies were determined, as were ozone emission rates, for two high-efficiency particle arresting (HEPA) filters, one electrostatic precipitator with a fan, and two ion generators without fans. The two HEPA air cleaners had count average CADR (standard deviation) of 188 (30) and 324 (44) m 3 h -1; the electrostatic precipitator 284 (62) m 3 h -1; and the two ion generators 41 (11) and 35 (13) m 3 h -1. The electrostatic precipitator emitted ozone at a rate of 3.8±0.2 mg h -1, and the two ion generators 3.3±0.2 and 4.3±0.2 mg h -1. Ozone initiates reactions with certain unsaturated organic compounds that produce ultrafine and fine particles, carbonyls, other oxidized products, and free radicals. During the second phase, five different ion generators were operated separately in the presence of a plug-in liquid or solid air freshener, representing a strong terpene source. For air exchange rates of between 0.49 and 0.96 h -1, three ion generators acted as steady-state net particle generators in the entire measured range of 4.61-157 nm, and two generated particles in the range of approximately 10 to 39-55 nm. Terpene and aldehyde concentrations were also sampled for one ion generator, and concentrations of terpenes decreased and formaldehyde increased. Given these results, the pollutant removal benefits of ozone-generating air cleaners may be outweighed by the generation of indoor pollution.

  17. Negative air ion effects on human performance and physiological condition.

    PubMed

    Buckalew, L W; Rizzuto, A P

    1984-08-01

    Beneficial effects of exposure to negative air ions have been suggested, to include improved performance, mood, attention, and physiological condition. Existing support is clouded by methodological problems of control and standardization in treatment and equipment. This study investigated effects of negative ions produced by a commercially marketed air purification device on grip magnitude, coding, motor dexterity, reaction time, tracking, pulse, blood pressure, and temperature. Two groups of 12 males were exposed to 6 continuous h of either negative or "normal" ion environments under a double blind condition. Repeated measures (0,3,6 h) on each variable were obtained. MANOVA applied to change scores revealed no differences between groups, and 0 vs. 3 and 0 vs. 6-h group differences showed no significant alteration in any measure. Negative ions generated by an air purification device were concluded to produce no general or specific alteration of cognitive or psychomotor performance or physiological condition.

  18. Ion Engine With Solid-Electrolyte Ion Generator

    NASA Technical Reports Server (NTRS)

    Richter, R.

    1984-01-01

    Working fluid utilized efficiently. Working fluid positive ions conducted through solid electrolyte to outside, then accelerated in external electric field. While in solid-electrolyte material, ions do not recombine with electrons: transported to surface with high ionization efficiency. Provides new way to generate beam of ions for implantation in semiconductors or other applications.

  19. Research report on the physiological effects of air ions and their significance as environmental factors

    NASA Technical Reports Server (NTRS)

    Varga, A.

    1978-01-01

    The series of experiments performed have shown that small air ions generated artificially using radioactive materials produced physiological effects in all test subjects, which are described. These results show that the air ions were important climatic factors in the production of comfortable and healthy room climates.

  20. Pesticide Registration: Clarification for Ion Generating Equipment

    EPA Pesticide Factsheets

    EPA issued a Federal Register Notice that clarifies the Agency's position on the distinction between devices and pesticides with regard to ion-generating equipment and explains why such equipment will now be regulated as a pesticide.

  1. Air To Air Helicopter Fire Control Equations and Software Generation.

    DTIC Science & Technology

    1979-11-01

    FORM I. REPORT NUMBER 12. GOVT ACCE NO S.SCIP1INTIS CATALOG NUMBER Air To Air Helicop~ter Fire Control 1I t 31Au Equations and Software Generation oN.m...differentiator in order to model the way that they are added in the track loop before the capacitor coupled tachometer feedback. AIRSIM Data Representative output

  2. High frequency plasma generator for ion thrusters

    NASA Technical Reports Server (NTRS)

    Goede, H.; Divergilio, W. F.; Fosnight, V. V.; Komatsu, G.

    1984-01-01

    The results of a program to experimentally develop two new types of plasma generators for 30 cm electrostatic argon ion thrusters are presented. The two plasma generating methods selected for this study were by radio frequency induction (RFI), operating at an input power frequency of 1 MHz, and by electron cyclotron heating (ECH) at an operating frequency of 5.0 GHz. Both of these generators utilize multiline cusp permanent magnet configurations for plasma confinement and beam profile optimization. The program goals were to develop a plasma generator possessing the characteristics of high electrical efficiency (low eV/ion) and simplicity of operation while maintaining the reliability and durability of the conventional hollow cathode plasma sources. The RFI plasma generator has achieved minimum discharge losses of 120 eV/ion while the ECH generator has obtained 145 eV/ion, assuming a 90% ion optical transparency of the electrostatic acceleration system. Details of experimental tests with a variety of magnet configurations are presented.

  3. Compact ion source neutron generator

    SciTech Connect

    Schenkel, Thomas; Persaud, Arun; Kapadia, Rehan; Javey, Ali; Chang-Hasnain, Constance; Rangelow, Ivo; Kwan, Joe

    2015-10-13

    A neutron generator includes a conductive substrate comprising a plurality of conductive nanostructures with free-standing tips and a source of an atomic species to introduce the atomic species in proximity to the free-standing tips. A target placed apart from the substrate is voltage biased relative to the substrate to ionize and accelerate the ionized atomic species toward the target. The target includes an element capable of a nuclear fusion reaction with the ionized atomic species to produce a one or more neutrons as a reaction by-product.

  4. Ion beams from laser-generated plasmas

    NASA Technical Reports Server (NTRS)

    Hughes, R. H.; Anderson, R. J.; Gray, L. G.; Rosenfeld, J. P.; Manka, C. K.; Carruth, M. R.

    1980-01-01

    The paper describes the space-charge-limited beams produced by the plasma blowoffs generated by 20-MW bursts of 1.06-micron radiation from an active Q-switched Nd:YAG laser. Laser power densities near 10 to the 11th/sq cm on solid targets generate thermalized plasma plumes which drift to a 15-kV gridded extraction gap where the ions are extracted, accelerated, and electrostatically focused; the spatially defined ion beams are then magnetically analyzed to determine the charge state content in the beams formed from carbon, aluminum, copper, and lead targets. This technique preserves time-of-flight (TOF) information in the plasma drift region, which permits plasma ion temperatures and mass flow velocities to be determined from the Maxwellian ion curve TOF shapes for the individual charge species.

  5. Secondary electron ion source neutron generator

    DOEpatents

    Brainard, J.P.; McCollister, D.R.

    1998-04-28

    A neutron generator employing an electron emitter, an ion source bombarded by the electrons from the electron emitter, a plasma containment zone, and a target situated between the plasma containment zone and the electron emitter is disclosed. The target contains occluded deuterium, tritium, or a mixture thereof. 4 figs.

  6. Secondary electron ion source neutron generator

    DOEpatents

    Brainard, John P.; McCollister, Daryl R.

    1998-01-01

    A neutron generator employing an electron emitter, an ion source bombarded by the electrons from the electron emitter, a plasma containment zone, and a target situated between the plasma containment zone and the electron emitter. The target contains occluded deuterium, tritium, or a mixture thereof

  7. Antifungal Properties of Electrically Generated Metallic Ions

    PubMed Central

    Berger, T. J.; Spadaro, J. A.; Bierman, Richard; Chapin, S. E.; Becker, R. O.

    1976-01-01

    A qualitative and quantitative investigation was undertaken to study the susceptibility of unicellular eucaryotic organisms (yeasts) to metallic cations generated by low levels of direct current. Results were characteristic of effects obtained previously using clinical and standard bacteria test organisms. The present study demonstrated that anodic silver (Ag+) at low direct currents had inhibitory and fungicidal properties. Broth dilution susceptibility tests were made on several species of Candida and one species of Torulopsis. Growth in all isolates was inhibited by concentrations of electrically generated silver ions between 0.5 and 4.7 μg/ml, and silver exhibited fungicidal properties at concentrations as low as 1.9 μg/ml. The inhibitory and fungicidal concentrations of electrically generated silver ions are lower than those reported for other silver compounds. Images PMID:1034467

  8. Exposure to Air Ions in Indoor Environments: Experimental Study with Healthy Adults

    PubMed Central

    Wallner, Peter; Kundi, Michael; Panny, Michael; Tappler, Peter; Hutter, Hans-Peter

    2015-01-01

    Since the beginning of the 20th century there has been a scientific debate about the potential effects of air ions on biological tissues, wellbeing and health. Effects on the cardiovascular and respiratory system as well as on mental health have been described. In recent years, there has been a renewed interest in this topic. In an experimental indoor setting we conducted a double-blind cross-over trial to determine if higher levels of air ions, generated by a special wall paint, affect cognitive performance, wellbeing, lung function, and cardiovascular function. Twenty healthy non-smoking volunteers (10 female, 10 male) participated in the study. Levels of air ions, volatile organic compounds and indoor climate factors were determined by standardized measurement procedures. Air ions affected the autonomous nervous system (in terms of an increase of sympathetic activity accompanied by a small decrease of vagal efferent activity): In the test room with higher levels of air ions (2194/cm3 vs. 1038/cm3) a significantly higher low to high frequency ratio of the electrocardiography (ECG) beat-to-beat interval spectrogram was found. Furthermore, six of nine subtests of a cognitive performance test were solved better, three of them statistically significant (verbal factor, reasoning, and perceptual speed), in the room with higher ion concentration. There was no influence of air ions on lung function and on wellbeing. Our results indicate slightly activating and cognitive performance enhancing effects of a short-term exposure to higher indoor air ion concentrations. PMID:26569277

  9. Exposure to Air Ions in Indoor Environments: Experimental Study with Healthy Adults.

    PubMed

    Wallner, Peter; Kundi, Michael; Panny, Michael; Tappler, Peter; Hutter, Hans-Peter

    2015-11-10

    Since the beginning of the 20th century there has been a scientific debate about the potential effects of air ions on biological tissues, wellbeing and health. Effects on the cardiovascular and respiratory system as well as on mental health have been described. In recent years, there has been a renewed interest in this topic. In an experimental indoor setting we conducted a double-blind cross-over trial to determine if higher levels of air ions, generated by a special wall paint, affect cognitive performance, wellbeing, lung function, and cardiovascular function. Twenty healthy non-smoking volunteers (10 female, 10 male) participated in the study. Levels of air ions, volatile organic compounds and indoor climate factors were determined by standardized measurement procedures. Air ions affected the autonomous nervous system (in terms of an increase of sympathetic activity accompanied by a small decrease of vagal efferent activity): In the test room with higher levels of air ions (2194/cm³ vs. 1038/cm³) a significantly higher low to high frequency ratio of the electrocardiography (ECG) beat-to-beat interval spectrogram was found. Furthermore, six of nine subtests of a cognitive performance test were solved better, three of them statistically significant (verbal factor, reasoning, and perceptual speed), in the room with higher ion concentration. There was no influence of air ions on lung function and on wellbeing. Our results indicate slightly activating and cognitive performance enhancing effects of a short-term exposure to higher indoor air ion concentrations.

  10. High Frequency Plasma Generators for Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Divergilio, W. F.; Goede, H.; Fosnight, V. V.

    1981-01-01

    The results of a one year program to experimentally adapt two new types of high frequency plasma generators to Argon ion thrusters and to analytically study a third high frequency source concept are presented. Conventional 30 cm two grid ion extraction was utilized or proposed for all three sources. The two plasma generating methods selected for experimental study were a radio frequency induction (RFI) source, operating at about 1 MHz, and an electron cyclotron heated (ECH) plasma source operating at about 5 GHz. Both sources utilize multi-linecusp permanent magnet configurations for plasma confinement. The plasma characteristics, plasma loading of the rf antenna, and the rf frequency dependence of source efficiency and antenna circuit efficiency are described for the RFI Multi-cusp source. In a series of tests of this source at Lewis Research Center, minimum discharge losses of 220+/-10 eV/ion were obtained with propellant utilization of .45 at a beam current of 3 amperes. Possible improvement modifications are discussed.

  11. Ions in oceanic and continental air masses

    SciTech Connect

    Tanner, D.J.; Eisele, F.L. )

    1991-01-20

    Measurements of tropospheric ions and several trace atmospheric neutral species have been performed at Cheeka Peak Research Station and at Mauna Loa Observatory. Two new positive ion species at masses 114 and 102 have been identified as protonated caprolactam and a saturated 6-carbon primary amine, respectively. In the negative ion spectrum, methane sulfonic acid (MSA) has been identified as the parent species responsible for an ion commonly observed at mass 95 during these two studies. The diurnal variations of gas phase H{sub 2}SO{sub 4} and MSA were also measured at Cheeka Peak and have typically been found to be present in the sub-ppt range. Ion assisted measurements at Mauna Loa Observatory of pyridine and ammonia indicate concentrations of 2.5 and 70 ppt, respectively, with at least a factor of 2 uncertainty. Interesting variations and potential sources of several of the observed ions are also discussed.

  12. Intense Pulsed Ion Beams: Their Generation and Applications.

    DTIC Science & Technology

    1980-10-03

    on the acceleration of ions within vacuum diode-like sources. The ions originate in a plasma which is produced on the surface of the ,inode and are... flashover discharges on the anode surfaces . Ions extracted from these plasmas are accelerated toward both the cathode and the virtual cathode. ThC ions... pulse generator. For most of these experiments , the ratio of the extracted proton current I to the total current I i.e., the proton generation effici,ncyp

  13. Air ions and respiratory function outcomes: a comprehensive review

    PubMed Central

    2013-01-01

    Background From a mechanistic or physical perspective there is no basis to suspect that electric charges on clusters of air molecules (air ions) would have beneficial or deleterious effects on respiratory function. Yet, there is a large lay and scientific literature spanning 80 years that asserts exposure to air ions affects the respiratory system and has other biological effects. Aims This review evaluates the scientific evidence in published human experimental studies regarding the effects of exposure to air ions on respiratory performance and symptoms. Methods We identified 23 studies (published 1933–1993) that met our inclusion criteria. Relevant data pertaining to study population characteristics, study design, experimental methods, statistical techniques, and study results were assessed. Where relevant, random effects meta-analysis models were utilized to quantify similar exposure and outcome groupings. Results The included studies examined the therapeutic benefits of exposure to negative air ions on respiratory outcomes, such as ventilatory function and asthmatic symptoms. Study specific sample sizes ranged between 7 and 23, and studies varied considerably by subject characteristics (e.g., infants with asthma, adults with emphysema), experimental method, outcomes measured (e.g., subjective symptoms, sensitivity, clinical pulmonary function), analytical design, and statistical reporting. Conclusions Despite numerous experimental and analytical differences across studies, the literature does not clearly support a beneficial role in exposure to negative air ions and respiratory function or asthmatic symptom alleviation. Further, collectively, the human experimental studies do not indicate a significant detrimental effect of exposure to positive air ions on respiratory measures. Exposure to negative or positive air ions does not appear to play an appreciable role in respiratory function. PMID:24016271

  14. Inductively generated streaming plasma ion source

    DOEpatents

    Glidden, Steven C.; Sanders, Howard D.; Greenly, John B.

    2006-07-25

    A novel pulsed, neutralized ion beam source is provided. The source uses pulsed inductive breakdown of neutral gas, and magnetic acceleration and control of the resulting plasma, to form a beam. The beam supplies ions for applications requiring excellent control of ion species, low remittance, high current density, and spatial uniformity.

  15. Ion trap mass spectrometry of externally generated ions

    SciTech Connect

    McLuckey, S.A.; Van Berkel, G.J.; Georinger, D.E. ); Glish, G.L.

    1994-07-01

    This discussion provides background for consideration of the merits of ion trap MS in conjunction with an external ion source relative to a scanning beam-type form of mass analysis. Emphasis has been placed primarily on efficiency. However, a variety of other factors can be major considerations, depending upon the application. For example, the ion trap has clear advantages over most other forms of MS in terms of size, weight, and pumping requirements. These advantages make the ion trap attractive for field applications, particularly because the performance characteristics of the ion trap need not be compromised in a compact system. One of the most significant advantages is the high efficiency obtainable with tandem MS experiments by using collisional activation via resonance excitation. Under favorable conditions, the conversion of 100% of the parent ions to product ions can be achieved, although 10-50% conversions are more typical. The analogous conversion in most beam-type tendem MS experiments is typically 1-3 orders of magnitude lower; thus, significant reductions in detection limits by use of the ion trap can be anticipated in analyses requiring two or more stages of MS. 61 refs., 3 figs.

  16. Vertical hydraulic generators experience with dynamic air gap monitoring

    SciTech Connect

    Pollock, G.B.; Lyles, J.F )

    1992-12-01

    Until recently, dynamic monitoring of the rotor to stator air gap of hydraulic generators was not practical. Cost effective and reliable dyamic air gap monitoring equipment has been developed in recent years. Dynamic air gap monitoring was originally justified because of the desire of the owner to minimize the effects of catastrophic air gap failure. However, monitoring air gaps on a time basis has been shown to be beneficial by assisting in the assessment of hydraulic generator condition. The air gap monitor provides useful information on rotor and stator condition and generator vibration. The data generated by air gap monitors will assist managers in the decision process with respect to the timing and extent of required maintenance for a particular generating unit.

  17. Measuring Light Air Ions in a Speleotherapeutic Cave

    NASA Astrophysics Data System (ADS)

    Roubal, Z.; Bartušek, K.; Szabó, Z.; Drexler, P.; Überhuberová, J.

    2017-02-01

    The paper deals with a methodology proposed for measuring the concentration of air ions in the environment of speleotherapeutic caves, and with the implementation of the AK-UTEE-v2 ionmeter. Speleotherapy, in the context of its general definition, is the medical therapy that utilizes the climate of selected caves to treat patients with health problems such as asthma. These spaces are characterized by the presence of high air humidity and they make extreme demands on the execution of the measuring device, the Gerdien tube (GT in the following) in particular, and on the amplifier electronics. The result is an automated measuring system using a GT with low-volume air flow, enabling long-term measuring of air ion concentration and determination of spectral ion characteristics. Interesting from the instrumentation viewpoint are the GT design, active shielding, and execution of the electrometric amplifier. A specific method for the calculation of spectral ion characteristics and the mode of automatic calibration were proposed and a procedure of automatic measurement in the absence of attendants was set up. The measuring system is designed for studying and long-term monitoring of the concentration of light negative ions in dependence on climatic conditions and on the mobility of ions occurring in the cave.

  18. Variability of air ion concentrations in urban Paris

    NASA Astrophysics Data System (ADS)

    Dos Santos, V. N.; Herrmann, E.; Manninen, H. E.; Hussein, T.; Hakala, J.; Nieminen, T.; Aalto, P. P.; Merkel, M.; Wiedensohler, A.; Kulmala, M.; Petäjä, T.; Hämeri, K.

    2015-12-01

    Air ion concentrations influence new particle formation and consequently the global aerosol as potential cloud condensation nuclei. We aimed to evaluate air ion concentrations and characteristics of new particle formation events (NPF) in the megacity of Paris, France, within the MEGAPOLI (Megacities: Emissions, urban, regional and Global Atmospheric Pollution and climate effects, and Integrated tools for assessment and mitigation) project. We measured air ion number size distributions (0.8-42 nm) with an air ion spectrometer and fine particle number concentrations (> 6 nm) with a twin differential mobility particle sizer in an urban site of Paris between 26 June 2009 and 4 October 2010. Air ions were size classified as small (0.8-2 nm), intermediate (2-7 nm), and large (7-20 nm). The median concentrations of small and large ions were 670 and 680 cm-3, respectively, (sum of positive and negative polarities), whereas the median concentration of intermediate ions was only 20 cm-3, as these ions were mostly present during new particle formation bursts, i.e. when gas-to-particle conversion produced fresh aerosol particles from gas phase precursors. During peaks in traffic-related particle number, the concentrations of small and intermediate ions decreased, whereas the concentrations of large ions increased. Seasonal variations affected the ion population differently, with respect to their size and polarity. NPF was observed in 13 % of the days, being most frequent in spring and late summer (April, May, July, and August). The results also suggest that NPF was favoured on the weekends in comparison to workdays, likely due to the lower levels of condensation sinks in the mornings of weekends (CS weekdays 09:00: 18 × 10-3 s-1; CS weekend 09:00: 8 × 10-3 s-1). The median growth rates (GR) of ions during the NPF events varied between 3 and 7 nm h-1, increasing with the ion size and being higher on workdays than on weekends for intermediate and large ions. The median GR of

  19. Ion creation, ion focusing, ion/molecule reactions, ion separation, and ion detection in the open air in a small plastic device.

    PubMed

    Baird, Zane; Wei, Pu; Cooks, R Graham

    2015-02-07

    A method is presented in which ions are generated and manipulated in the ambient environment using polymeric electrodes produced with a consumer-grade 3D printer. The ability to focus, separate, react, and detect ions in the ambient environment is demonstrated and the data agree well with simulated ion behaviour.

  20. Generation of pulsed ion beams by an inductive storage pulsed power generator

    NASA Astrophysics Data System (ADS)

    Katsuki, Sunao; Akiyama, Hidenori; Maeda, Sadao

    1990-10-01

    A pulsed power generator by an inductive energy storage system is extremely compact and light in comparison with a conventional pulsed power generator, which consists of a Marx bank and a water pulse forming line. A compact and light pulse power generator is applied to the generation of pulsed ion beams. A thin copper fuse is used an an opening switch, which is necessary in the inductive storage pulsed power generator. A magnetically insulated diode is used for the generation of ion beams. The pulsed ion beams are successfully generated by the inductive storage pulsed power generator for the first time.

  1. Potato slab dehydration by air ions from corona discharge

    NASA Astrophysics Data System (ADS)

    Chen, Y. H.; Barthakur, N. N.

    1991-06-01

    Space charge (air ions) produced by single corona electrodes was used to enhance drying rates from fresh slabs of potato. The drying path was traced by a beta-ray gauge which provided both sensitivity and reproducibility to the measurements of drying time. The rate of evaporation was increased 2.2 to 3.0 times when subjected to fluxes of 3.02×1012 positive ions alone or in combination with 7.31×1012 negative air ions/cm2 per s compared to that from an air-drying control slab. Electric wind caused by an ionic drag force seems to be the principal driving force for the observed enhancement in drying rates.

  2. Next-generation air measurement technologies | Science ...

    EPA Pesticide Factsheets

    This is a presentation at a workshop in Chicago on emerging air monitoring technologies, hosted by a local nonprofit. The audience is composed of a mixture of technical backgrounds. This presentation will be part of an opening panel and the goal is to give an overview of the state of science on emerging air sensor technology. This is a presentation at a workshop in Chicago on emerging air monitoring technologies, hosted by a local nonprofit. The audience is composed of a mixture of technical backgrounds. This presentation will be part of an opening panel and the goal is to give an overview of the state of science on emerging air sensor technology.

  3. Generation of intense negative ion beams

    NASA Technical Reports Server (NTRS)

    Chutjian, Ara (Inventor); Orient, Otto J. (Inventor); Aladzhadzhyan, Samuel H. (Inventor)

    1987-01-01

    An electron gun is used with a mirror electrostatic field to produce zero or near zero velocity electrons by forming a turning point in their trajectories. A gas capable of attaching zero or near zero velocity is introduced at this turning point, and negative ions are produced by the attachment or dissociative attachment process. Operation may be continuous or pulsed. Ions thus formed are extracted by a simple lens system and suitable biasing of grids.

  4. Ions Generated on or Near Satellite Surfaces

    DTIC Science & Technology

    1988-06-01

    Tascione, T.F., Introduction to the Space Environment. Orbit Book Co., Malabar, FL, 1988, pp.33-57 7. Balsiger , H.,"Composition of Hot Ions (0.1-16keV/e...Research, Vl, 289, 1981 8. Balsiger , H., P. Eberhardt, J. Geiss, and D. Young, "Magnetic Storm Injection of 0.9 to 16 keV/e Solar and Terrestrial Ions into

  5. Graphene Visualizes the Ion Distribution on Air-Cleaved Mica.

    PubMed

    Bampoulis, Pantelis; Sotthewes, Kai; Siekman, Martin H; Zandvliet, Harold J W; Poelsema, Bene

    2017-03-06

    The distribution of potassium (K(+)) ions on air-cleaved mica is important in many interfacial phenomena such as crystal growth, self-assembly and charge transfer on mica. However, due to experimental limitations to nondestructively probe single ions and ionic domains, their exact lateral organization is yet unknown. We show, by the use of graphene as an ultra-thin protective coating and scanning probe microscopies, that single potassium ions form ordered structures that are covered by an ice layer. The K(+) ions prefer to minimize the number of nearest neighbour K(+) ions by forming row-like structures as well as small domains. This trend is a result of repulsive ionic forces between adjacent ions, weakened due to screening by the surrounding water molecules. Using high resolution conductive atomic force microscopy maps, the local conductance of the graphene is measured, revealing a direct correlation between the K(+) distribution and the structure of the ice layer. Our results shed light on the local distribution of ions on the air-cleaved mica, solving a long-standing enigma. They also provide a detailed understanding of charge transfer from the ionic domains towards graphene.

  6. Graphene Visualizes the Ion Distribution on Air-Cleaved Mica

    NASA Astrophysics Data System (ADS)

    Bampoulis, Pantelis; Sotthewes, Kai; Siekman, Martin H.; Zandvliet, Harold J. W.; Poelsema, Bene

    2017-03-01

    The distribution of potassium (K+) ions on air-cleaved mica is important in many interfacial phenomena such as crystal growth, self-assembly and charge transfer on mica. However, due to experimental limitations to nondestructively probe single ions and ionic domains, their exact lateral organization is yet unknown. We show, by the use of graphene as an ultra-thin protective coating and scanning probe microscopies, that single potassium ions form ordered structures that are covered by an ice layer. The K+ ions prefer to minimize the number of nearest neighbour K+ ions by forming row-like structures as well as small domains. This trend is a result of repulsive ionic forces between adjacent ions, weakened due to screening by the surrounding water molecules. Using high resolution conductive atomic force microscopy maps, the local conductance of the graphene is measured, revealing a direct correlation between the K+ distribution and the structure of the ice layer. Our results shed light on the local distribution of ions on the air-cleaved mica, solving a long-standing enigma. They also provide a detailed understanding of charge transfer from the ionic domains towards graphene.

  7. Graphene Visualizes the Ion Distribution on Air-Cleaved Mica

    PubMed Central

    Bampoulis, Pantelis; Sotthewes, Kai; Siekman, Martin H.; Zandvliet, Harold J. W.; Poelsema, Bene

    2017-01-01

    The distribution of potassium (K+) ions on air-cleaved mica is important in many interfacial phenomena such as crystal growth, self-assembly and charge transfer on mica. However, due to experimental limitations to nondestructively probe single ions and ionic domains, their exact lateral organization is yet unknown. We show, by the use of graphene as an ultra-thin protective coating and scanning probe microscopies, that single potassium ions form ordered structures that are covered by an ice layer. The K+ ions prefer to minimize the number of nearest neighbour K+ ions by forming row-like structures as well as small domains. This trend is a result of repulsive ionic forces between adjacent ions, weakened due to screening by the surrounding water molecules. Using high resolution conductive atomic force microscopy maps, the local conductance of the graphene is measured, revealing a direct correlation between the K+ distribution and the structure of the ice layer. Our results shed light on the local distribution of ions on the air-cleaved mica, solving a long-standing enigma. They also provide a detailed understanding of charge transfer from the ionic domains towards graphene. PMID:28262710

  8. UCAV - The Next Generation Air-Superiority Fighter?

    DTIC Science & Technology

    2002-06-01

    number. 1. REPORT DATE 00 JUN 2002 2. REPORT TYPE N/A 3. DATES COVERED - 4. TITLE AND SUBTITLE UCAV - The Next Generation Air-Superiority...next- generation air-superiority fighter is entering development. Unmanned aircraft must be considered as an alternative to manned aircraft for this

  9. Results of the first air ion spectrometer calibration and intercomparison workshop

    NASA Astrophysics Data System (ADS)

    Asmi, E.; Sipilä, M.; Manninen, H. E.; Vanhanen, J.; Lehtipalo, K.; Gagné, S.; Neitola, K.; Mirme, A.; Mirme, S.; Tamm, E.; Uin, J.; Komsaare, K.; Attoui, M.; Kulmala, M.

    2008-09-01

    The air ion spectrometer (AIS) measures mobility and size distributions of atmospheric ions. The neutral air ion spectrometer (NAIS) can additionally measure neutral particles. The number of the (N)AIS instruments in the world is only 11. Nevertheless, they are already widely used in atmospheric ion studies, particularly related to the initial steps of new particle formation. There is no standard method applicable for calibrating the ion spectrometers in the sub-3 nm ion range. However, recent development of high resolution DMAs has enabled the size separation of small ions with good mobility resolution. For the first time, the ion spectrometers were intercompared and calibrated in a workshop, held in January February 2008 in Helsinki, Finland. The overall goal was to experimentally determine the (N)AIS transfer functions. Monomobile mobility standards, 241-Am charger ions and silver particles were generated and used as calibration aerosols. High resolution DMAs were used to size-separate the smaller (1 10 nm) ions, while at bigger diameters (4 40 nm) the size was selected with a HAUKE-type DMA. Differences between the (N)AISs were small. Positive ion mobilities were detected by (N)AISs with better accuracy than negative, nonetheless, both were somewhat overestimated. The completely monomobile mobility standards were measured with the best accuracy. The (N)AIS concentrations were compared with an aerosol electrometer (AE) and a condensation particle counter (CPC). At sizes below 1.5 nm (positive) and 3 nm (negative) the ion spectrometers detected higher concentrations while at bigger sizes they showed similar concentrations as the reference instruments. The total particle concentrations measured by NAISs were ±50% of the reference CPC concentration at 4 40 nm sizes. The lowest cut-off size of the NAIS in neutral particle measurements was determined to be between 1.5 and 3 nm, depending on the measurement conditions and the polarity.

  10. Next-Generation Ion Thruster Design Tool

    NASA Technical Reports Server (NTRS)

    Stolz, Peter

    2015-01-01

    Computational tools that accurately predict the performance of electric propulsion devices are highly desirable and beneficial to NASA and the broader electric propulsion community. The current state of the art in electric propulsion modeling relies heavily on empirical data and numerous computational "knobs." In Phase I of this project, Tech-X Corporation developed the most detailed ion engine discharge chamber model that currently exists. This kinetic model simulates all particles in the discharge chamber along with a physically correct simulation of the electric fields. In addition, kinetic erosion models are included for modeling the ion-impingement effects on thruster component erosion. In Phase II, Tech-X developed a user-friendly computer program for NASA and other governmental and industry customers. Tech-X has implemented a number of advanced numerical routines to bring the computational time down to a commercially acceptable level. NASA now has a highly sophisticated, user-friendly ion engine discharge chamber modeling tool.

  11. Generation of three-mode nonclassical vibrational states of ions

    SciTech Connect

    Nguyen Ba An; Truong Minh Duc

    2002-12-01

    We propose using eight lasers with appropriate orientations and conditions to generate stable trio coherent states of an ion in a three-dimensional isotropic trap. Seven lasers whose orientations are important should be detuned to the third lower sideband of the ion vibrational motion. The eighth laser whose direction is not important should be in resonance with the ionic transition.

  12. Dispensing targets for ion beam particle generators

    NASA Technical Reports Server (NTRS)

    Miller, C. G. (Inventor)

    1974-01-01

    A target for dispensing high energy protons or neutrons or ionized atoms or ionized molecules is provided which comprises a container for the target gas, which is at atmospheric or higher pressure. The container material can release the target gas in the spot where the container is heated above a predetermined temperature by the impact of an ion beam where protons or neutrons are desired, or by electrons where ionized atoms or molecules are desired. On the outside of the container, except for the region where the beam is to impact, there is deposited a layer of a metal which is imperious to gaseous diffusion. A further protective coating of a material is placed over the layer of metal, except at the region of the ion impact area in order to adsorb any unreacted gas in the vacuum in which the target is placed, to thereby prevent reduction of the high vacuum, as well as contamination of the interior of the vacuum chamber.

  13. Design of a fifth generation air superiority fighter

    NASA Astrophysics Data System (ADS)

    Atique, Md. Saifuddin Ahmed; Barman, Shuvrodeb; Nafi, Asif Shahriar; Bellah, Masum; Salam, Md. Abdus

    2016-07-01

    Air Superiority Fighter is considered to be an effective dogfighter which is stealthy & highly maneuverable to surprise enemy along with improve survivability against the missile fire. This new generation fighter aircraft requires fantastic aerodynamics design, low wing loading (W/S), high thrust to weight ratio (T/W) with super cruise ability. Conceptual design is the first step to design an aircraft. In this paper conceptual design of an Air Superiority Fighter Aircraft is proposed to carry 1 crew member (pilot) that can fly at maximum Mach No of 2.3 covering a range of 1500 km with maximum ceiling of 61,000 ft. Payload capacity of this proposed aircraft is 6000 lb that covers two advanced missiles & one advanced gun. The Air Superiority Fighter Aircraft was designed to undertake all the following missions like: combat air petrol, air to air combat, maritime attack, close air support, suppression, destruction of enemy air defense and reconnaissance.

  14. Fast ion generation and bulk plasma heating with three-ion ICRF scenarios

    NASA Astrophysics Data System (ADS)

    Kazakov, Ye. O.; Van Eester, D.; Dumont, R.; Ongena, J.; Lerche, E.; Messiaen, A.

    2015-12-01

    Launching electromagnetic waves in the ion cyclotron range of frequencies (ICRF) is an efficient method of plasma heating, actively employed in most of fusion machines. ICRF has a number of important supplementary applications, including the generation of high-energy ions. In this paper, we discuss a new set of three-ion ICRF scenarios and the prospect of their use as a dedicated tool for fast ion generation in tokamaks and stellarators. A distinct feature of these scenarios is a strong absorption efficiency possible at very low concentrations of resonant minority ions (˜ 1% or even below). Such concentration levels are typical for impurities contaminating fusion plasmas. An alternative ICRF scenario for maximizing the efficiency of bulk D-T ion heating is suggested for JET and ITER tokamaks, which is based on three-ion ICRF heating of intrinsic Beryllium impurities.

  15. Fast ion generation and bulk plasma heating with three-ion ICRF scenarios

    SciTech Connect

    Kazakov, Ye. O. Van Eester, D.; Ongena, J.; Lerche, E.; Messiaen, A.

    2015-12-10

    Launching electromagnetic waves in the ion cyclotron range of frequencies (ICRF) is an efficient method of plasma heating, actively employed in most of fusion machines. ICRF has a number of important supplementary applications, including the generation of high-energy ions. In this paper, we discuss a new set of three-ion ICRF scenarios and the prospect of their use as a dedicated tool for fast ion generation in tokamaks and stellarators. A distinct feature of these scenarios is a strong absorption efficiency possible at very low concentrations of resonant minority ions (∼ 1% or even below). Such concentration levels are typical for impurities contaminating fusion plasmas. An alternative ICRF scenario for maximizing the efficiency of bulk D-T ion heating is suggested for JET and ITER tokamaks, which is based on three-ion ICRF heating of intrinsic Beryllium impurities.

  16. Next-generation air measurement technologies

    EPA Science Inventory

    This is a presentation at a workshop in Chicago on emerging air monitoring technologies, hosted by a local nonprofit. The audience is composed of a mixture of technical backgrounds. This presentation will be part of an opening panel and the goal is to give an overview of the st...

  17. Negative ion-driven associated particle neutron generator

    SciTech Connect

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  18. Negative ion-driven associated particle neutron generator

    NASA Astrophysics Data System (ADS)

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2016-01-01

    An associated particle neutron generator is described that employs a negative ion source to produce high neutron flux from a small source size. Negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). The neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to ~108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  19. Negative ion-driven associated particle neutron generator

    DOE PAGES

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; ...

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in eithermore » pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.« less

  20. A Public Health Approach to Evaluating the Significance of Air Ions

    DTIC Science & Technology

    2011-07-28

    nearly a century. Claims for their effects on everything from mood and alertness to asthma and allergies have been made. Ion generating devices for...over cancer, infectious disease, allergy and irritation have all been ascribed to indoor air pollution. A wide range of allergens, pathogens, irritants...the proliferation of these devices and with their thinly-veiled claims for improving health conditions (including allergies , asthma, fatigue, symptoms

  1. Next Generation Air Monitoring (NGAM) VOC Sensor Evaluation Report

    EPA Science Inventory

    This report summarizes the results of next generation air monitor (NGAM) volatile organic compound (VOC) evaluations performed using both laboratory as well as field scale settings. These evaluations focused on challenging lower cost (<$2500) NGAM technologies to either controlle...

  2. BMEWS Radar Beam Generation and Projection Clear Air Force ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    BMEWS Radar Beam Generation and Projection - Clear Air Force Station, Ballistic Missile Early Warning System Site II, One mile west of mile marker 293.5 on Parks Highway, 5 miles southwest of Anderson, Anderson, Denali Borough, AK

  3. Highbay Generator Room, looking northwest Beale Air Force Base, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Highbay Generator Room, looking northwest - Beale Air Force Base, Perimeter Acquisition Vehicle Entry Phased-Array Warning System, Power Plant, End of Spencer Paul Road, north of Warren Shingle Road (14th Street), Marysville, Yuba County, CA

  4. 14. VIEW OF AIR COMPRESSOR. 1500 kw Westinghouse AC generator ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. VIEW OF AIR COMPRESSOR. 1500 kw Westinghouse AC generator steam-turbine unit; beyond is air compressor of Chicago Pneumatic Tool Company, 1920, engineered by Earl E. Know Company, Erie, Pennsylvania. - Juniata Shops, Power Plant & Boiler House, East of Fourth Avenue at Second Street, Altoona, Blair County, PA

  5. OZONE GENERATORS IN INDOOR AIR SETTINGS

    EPA Science Inventory

    The report gives information on home/office ozone generators. It discusses their current uses as amelioratives for environmental tobacco smoke, biocontaminants, volatile organic compounds, and odors and details the advantages and disadvantages of each. Ozone appears to work well ...

  6. Monitoring Trace Contaminants in Air Via Ion Trap Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Palmer, Peter T.; Karr, Dane; Pearson, Richard; Valero, Gustavo; Wong, Carla

    1995-01-01

    Recent passage of the Clean Air Act with its stricter regulation of toxic gas emissions, and the ever-growing number of applications which require faster turnaround times between sampling and analysis are two major factors which are helping to drive the development of new instrument technologies for in-situ, on-line, real-time monitoring. The ion trap, with its small size, excellent sensitivity, and tandem mass spectrometry capability is a rapidly evolving technology which is well-suited for these applications. In this paper, we describe the use of a commercial ion trap instrument for monitoring trace levels of chlorofluorocarbons (CFCs) and volatile organic compounds (VOCs) in air. A number of sample introduction devices including a direct transfer line interface, short column GC, and a cryotrapping interface are employed to achieve increasing levels of sensitivity. MS, MS/MS, and MS/MS/MS methods are compared to illustrate trade-offs between sensitivity and selectivity. Filtered Noise Field (FNF) technology is found to be an excellent means for achieving lower detection limits through selective storage of the ion(s) of interest during ionization. Figures of merit including typical sample sizes, detection limits, and response times are provided. The results indicate the potential of these techniques for atmospheric assessments, the High Speed Research Program, and advanced life support monitoring applications for NASA.

  7. The Next-Generation Expeditionary Air Force

    DTIC Science & Technology

    2012-02-01

    Journal, which was selected as the journal’s second-best article for 2010 and was published in the Spanish, Portuguese , and Chinese editions of ASPJ...literature review and personal interviews provided the core research methodology for this study. A literature review identi- fied current AEF policy and...comments: Thank you for your assistance. C u t al o n g d o tt ed li n e Place Stamp Here AFRI/DE Dean, Air Force Research Institute 155 N

  8. Thermal characteristics of air flow cooling in the lithium ion batteries experimental chamber

    SciTech Connect

    Lukhanin A.; Rohatgi U.; Belyaev, A.; Fedorchenko, D.; Khazhmuradov, M.; Lukhanin, O; Rudychev, I.

    2012-07-08

    A battery pack prototype has been designed and built to evaluate various air cooling concepts for the thermal management of Li-ion batteries. The heat generation from the Li-Ion batteries was simulated with electrical heat generation devices with the same dimensions as the Li-Ion battery (200 mm x 150 mm x 12 mm). Each battery simulator generates up to 15W of heat. There are 20 temperature probes placed uniformly on the surface of the battery simulator, which can measure temperatures in the range from -40 C to +120 C. The prototype for the pack has up to 100 battery simulators and temperature probes are recorder using a PC based DAQ system. We can measure the average surface temperature of the simulator, temperature distribution on each surface and temperature distributions in the pack. The pack which holds the battery simulators is built as a crate, with adjustable gap (varies from 2mm to 5mm) between the simulators for air flow channel studies. The total system flow rate and the inlet flow temperature are controlled during the test. The cooling channel with various heat transfer enhancing devices can be installed between the simulators to investigate the cooling performance. The prototype was designed to configure the number of cooling channels from one to hundred Li-ion battery simulators. The pack is thermally isolated which prevents heat transfer from the pack to the surroundings. The flow device can provide the air flow rate in the gap of up to 5m/s velocity and air temperature in the range from -30 C to +50 C. Test results are compared with computational modeling of the test configurations. The present test set up will be used for future tests for developing and validating new cooling concepts such as surface conditions or heat pipes.

  9. Thermal analysis and two-directional air flow thermal management for lithium-ion battery pack

    NASA Astrophysics Data System (ADS)

    Yu, Kuahai; Yang, Xi; Cheng, Yongzhou; Li, Changhao

    2014-12-01

    Thermal management is a routine but crucial strategy to ensure thermal stability and long-term durability of the lithium-ion batteries. An air-flow-integrated thermal management system is designed in the present study to dissipate heat generation and uniformize the distribution of temperature in the lithium-ion batteries. The system contains of two types of air ducts with independent intake channels and fans. One is to cool the batteries through the regular channel, and the other minimizes the heat accumulations in the middle pack of batteries through jet cooling. A three-dimensional anisotropic heat transfer model is developed to describe the thermal behavior of the lithium-ion batteries with the integration of heat generation theory, and validated through both simulations and experiments. Moreover, the simulations and experiments show that the maximum temperature can be decreased to 33.1 °C through the new thermal management system in comparison with 42.3 °C through the traditional ones, and temperature uniformity of the lithium-ion battery packs is enhanced, significantly.

  10. Ion Beam Analysis applied to laser-generated plasmas

    NASA Astrophysics Data System (ADS)

    Cutroneo, M.; Macková, A.; Havranek, V.; Malinsky, P.; Torrisi, L.; Kormunda, M.; Barchuk, M.; Ullschmied, J.; Dudzak, R.

    2016-04-01

    This paper presents the research activity on Ion Beam Analysis methods performed at Tandetron Laboratory (LT) of the Institute of Nuclear Physics AS CR, Rez, Czech Republic. Recently, many groups are paying attention to implantation by laser generated plasma. This process allows to insert a controllable amount of energetic ions into the surface layers of different materials modifying the physical and chemical properties of the surface material. Different substrates are implanted by accelerated ions from plasma through terawatt iodine laser, at nominal intensity of 1015 W/cm2, at the PALS Research Infrastructure AS CR, in the Czech Republic. This regime of the laser matter interaction generates, multi-MeV proton beams, and multi-charged ions that are tightly confined in time (hundreds ps) and space (source radius of a few microns). These ion beams have a much lower transverse temperature, a much shorter duration and a much higher current than those obtainable from conventional accelerators. The implementation of protons and ions acceleration driven by ultra-short high intensity lasers is exhibited by adopting suitable irradiation conditions as well as tailored targets. An overview of implanted targets and their morphological and structural characterizations is presented and discussed.

  11. Wave generation by contaminant ions near a large spacecraft

    NASA Technical Reports Server (NTRS)

    Singh, N.

    1993-01-01

    Measurements from the space shuttle flights have revealed that a large spacecraft in a low earth orbit is accompanied by an extensive gas cloud which is primarily made up of water. The charge exchange between the water molecule and the ionospheric O(+) ions produces a water ion beam traversing downstream of the spacecraft. In this report we present results from a study on the generation of plasma waves by the interaction of the water ion beams with the ionospheric plasma. Since velocity distribution function is key to the understanding of the wave generation process, we have performed a test particle simulation to determine the nature of H2O(+) ions velocity distribution function. The simulations show that at the time scales shorter than the ion cyclotron period tau(sub c), the distribution function can be described by a beam. On the other hand, when the time scales are larger than tau(sub c), a ring distribution forms. A brief description of the linear instabilities driven by an ion beam streaming across a magnetic field in a plasma is presented. We have identified two types of instabilities occurring in low and high frequency bands; the low-frequency instability occurs over the frequency band from zero to about the lower hybrid frequency for a sufficiently low beam density. As the beam density increases, the linear instability occurs at decreasing frequencies below the lower-hybrid frequency. The high frequency instability occurs near the electron cyclotron frequency and its harmonics.

  12. Generating High-Brightness Ion Beams for Inertial Confinement Fusion

    NASA Astrophysics Data System (ADS)

    Cuneo, M. E.

    1997-11-01

    The generation of high current density ion beams with applied-B ion diodes showed promise in the late-1980's as an efficient, rep-rate, focusable driver for inertial confinement fusion. These devices use several Tesla insulating magnetic fields to restrict electron motion across anode-cathode gaps of order 1-2 cm, while accelerating ions to generate ≈ 1 kA/cm^2, 5 - 15 MeV beams. These beams have been used to heat hohlraums to about 65 eV. However, meeting the ICF driver requirements for low-divergence and high-brightness lithium ion beams has been more technically challenging than initially thought. Experimental and theoretical work over the last 5 years shows that high-brightness beams meeting the requirements for inertial confinement fusion are possible. The production of these beams requires the simultaneous integration of at least four conditions: 1) rigorous vacuum cleaning techniques for control of undesired anode, cathode, ion source and limiter plasma formation from electrode contaminants to control impurity ions and impedance collapse; 2) carefully tailored insulating magnetic field geometry for uniform beam generation; 3) high magnetic fields (V_crit/V > 2) and other techniques to control the electron sheath and the onset of a high divergence electromagnetic instability that couples strongly to the ion beam; and 4) an active, pre-formed, uniform lithium plasma for low source divergence which is compatible with the above electron-sheath control techniques. These four conditions have never been simultaneously present in any lithium beam experiment, but simulations and experimental tests of individual conditions have been done. The integration of these conditions is a goal of the present ion beam generation program at Sandia. This talk will focus on the vacuum cleaning techniques for ion diodes and pulsed power devices in general, including experimental results obtained on the SABRE and PBFA-II accelerators over the last 3 years. The current status of

  13. Carbon Nanotube Based Deuterium Ion Source for Improved Neutron Generators

    SciTech Connect

    Fink, R. L.; Jiang, N.; Thuesen, L.; Leung, K. N.; Antolak, A. J.

    2009-03-10

    Field ionization uses high electric fields to cause the ionization and emission of ions from the surface of a sharp electrode. We are developing a novel field ionization neutron generator using carbon nanotubes (CNT) to produce the deuterium ion current. The generator consists of three major components: a deuterium ion source made of carbon nanotubes, a smooth negatively-biased target electrode, and a secondary electron suppression system. When a negative high voltage is applied on the target electrode, a high gradient electric field is formed at the tips of the carbon nanotubes. This field is sufficiently strong to create deuterium (D) ions at or near the nanotubes which are accelerated to the target causing D-D reactions to occur and the production of neutrons. A cross magnetic field is used to suppress secondary emission electrons generated on the target surface. We have demonstrated field ionization currents of 70 nA (1 {mu}A/cm{sup 2}) at hydrogen gas pressure of 10 mTorr. We have found that the current scales proportionally with CNT area and also with the gas pressure in the range of 1 mTorr to 10 mTorr. We have demonstrated pulse cut-off times as short as 2 {mu}sec. Finally, we have shown the feasibility of generating neutrons using deuterium gas.

  14. Results of the first air ion spectrometer calibration and intercomparison workshop

    NASA Astrophysics Data System (ADS)

    Asmi, E.; Sipilä, M.; Manninen, H. E.; Vanhanen, J.; Lehtipalo, K.; Gagné, S.; Neitola, K.; Mirme, A.; Mirme, S.; Tamm, E.; Uin, J.; Komsaare, K.; Attoui, M.; Kulmala, M.

    2009-01-01

    The Air Ion Spectrometer (AIS) measures mobility and size distributions of atmospheric ions. The Neutral cluster and Air Ion Spectrometer (NAIS) can additionally measure neutral particles. The number of the (N)AIS instruments in the world is only 11. Nevertheless, they are already widely used in atmospheric ion studies, particularly related to the initial steps of new particle formation. There is no standard method applicable for calibrating the ion spectrometers in the sub-3 nm ion range. However, recent development of high resolution DMAs has enabled the size separation of small ions with good mobility resolution. For the first time, the ion spectrometers were intercompared and calibrated in a workshop, held in January-February 2008 in Helsinki, Finland. The overall goal was to experimentally determine the (N)AIS transfer functions. Monomobile mobility standards, 241-Am charger ions and silver particles were generated and used as calibration aerosols. High resolution DMAs were used to size-separate the smaller (1-10 nm) ions, while at bigger diameters (4-40 nm) the size was selected with a HAUKE-type DMA. Negative ion mobilities were detected by (N)AISs with slightly better accuracy than positive, nonetheless, both were somewhat overestimated. A linear fit of slope of one to the whole dataset of mobilities suggested that (N)AISs measured the negative mobilities 1.36±0.16 times larger compared with the reference instruments. Similarly, positive mobilities were measured 1.39±0.15 times larger compared with the reference instruments. The completely monomobile mobility standards were measured with the best accuracy. The (N)AIS concentrations were compared with an aerosol electrometer (AE) and a condensation particle counter (CPC). At sizes below 1.5 nm (positive) and 3 nm (negative) the ion spectrometers detected higher concentrations while at bigger sizes they showed similar concentrations as the reference instruments. The total particle concentrations measured by

  15. Cardiovascular Outcomes and the Physical and Chemical Properties of Metal Ions Found in Particulate Matter Air Pollution: A QICAR Study

    PubMed Central

    Meng, Qingyu; Lu, Shou-En; Buckley, Barbara; Welsh, William J.; Whitsel, Eric A.; Hanna, Adel; Yeatts, Karin B.; Warren, Joshua; Herring, Amy H.; Xiu, Aijun

    2013-01-01

    Background: This paper presents an application of quantitative ion character–activity relationships (QICAR) to estimate associations of human cardiovascular (CV) diseases (CVDs) with a set of metal ion properties commonly observed in ambient air pollutants. QICAR has previously been used to predict ecotoxicity of inorganic metal ions based on ion properties. Objectives: The objective of this work was to examine potential associations of biological end points with a set of physical and chemical properties describing inorganic metal ions present in exposures using QICAR. Methods: Chemical and physical properties of 17 metal ions were obtained from peer-reviewed publications. Associations of cardiac arrhythmia, myocardial ischemia, myocardial infarction, stroke, and thrombosis with exposures to metal ions (measured as inference scores) were obtained from the Comparative Toxicogenomics Database (CTD). Robust regressions were applied to estimate the associations of CVDs with ion properties. Results: CVD was statistically significantly associated (Bonferroni-adjusted significance level of 0.003) with many ion properties reflecting ion size, solubility, oxidation potential, and abilities to form covalent and ionic bonds. The properties are relevant for reactive oxygen species (ROS) generation, which has been identified as a possible mechanism leading to CVDs. Conclusion: QICAR has the potential to complement existing epidemiologic methods for estimating associations between CVDs and air pollutant exposures by providing clues about the underlying mechanisms that may explain these associations. PMID:23462649

  16. Sealed operation of a rf driven ion source for a compact neutron generator to be used for associated particle imaging.

    PubMed

    Wu, Y; Hurley, J P; Ji, Q; Kwan, J W; Leung, K N

    2010-02-01

    We present the recent development of a prototype compact neutron generator to be used in conjunction with the method of associated particle imaging for the purpose of active neutron interrogation. In this paper, the performance and device specifications of these compact generators that employ rf driven ion sources will be discussed. Initial measurements of the generator performance include a beam spot size of 1 mm in diameter and a neutron yield of 2x10(5) n/s with air cooling.

  17. High average power second harmonic generation in air

    SciTech Connect

    Beresna, Martynas; Kazansky, Peter G.; Svirko, Yuri; Barkauskas, Martynas; Danielius, Romas

    2009-09-21

    We demonstrate second harmonic vortex generation in atmospheric pressure air using tightly focused femtosecond laser beam. The circularly polarized ring-shaped beam of the second harmonic is generated in the air by fundamental beam of the same circular polarization, while the linear polarized beam produces two-lobe beam at the second harmonic frequency. The achieved normalized conversion efficiency and average second harmonic power are two orders of magnitude higher compared to those previously reported and can be increased up to 20 times by external gas flow. We demonstrate that the frequency doubling originates from the gradient of photoexcited free electrons created by pondermotive force.

  18. Ion reflection by shock waves and pulse generation by cross-field ion beams

    NASA Astrophysics Data System (ADS)

    Ohsawa, Yukiharu

    2017-02-01

    Comparisons are made of two different particle simulations: one for the study of plasma-based accelerators (Gueroult & Fisch, Phys. Plasmas, vol. 23, 2016, 032113) and the other for the study of shock formation in the interstellar medium (Yamauchi & Ohsawa, Phys. Plasmas, vol. 14, 2007, 053110). In the former, shock waves used for plasma density control create ion beams by reflection. In the latter, a fast and dense beam of exploding ions penetrates a surrounding plasma. In both simulations, magnetic bumps are generated from the motion of ion beams perpendicular to a magnetic field. Despite the apparent differences of their purposes, configurations and spatial scales, the two simulations show strong similarities in the generation processes and effects of the bumps, suggesting that these are not rare plasma phenomena. The bump created by the exploding ions develops into backward and forward magnetosonic pulses.

  19. Generation of high pressure homogeneous dielectric barrier discharge in air

    NASA Astrophysics Data System (ADS)

    Osawa, Naoki; Takashi, Ami; Yoshioka, Yoshio; Hanaoka, Ryoichi

    2013-02-01

    We succeeded in generating an atmospheric pressure Townsend discharge (APTD) in air by using a simple DBD device that consists of alumina barriers and plane electrodes. So far, we applied the APTD to an ozonizer and found that the ozone generation efficiency was higher by the APTD mode than by the conventional DBD mode in larger specific input energy region. It is well known that an operation under an optimized high gas pressure is advantageous for efficient ozone generation from air. In this paper, we investigated whether the Townsend discharge (TD) in dry air in high pressure up to 0.17 MPa can be generated or not. From the observation results of current waveforms and discharge photographs, we found that (1) the discharge currents flow continuously and have only one peak in every half cycle in all gas pressure and (2) filamentary discharges are not recognized between barriers in all gas pressure. These features completely agree with the features of the APTD we reported. Therefore, we concluded that our TD can be generated even in dry air in the pressure range of 0.1 and 0.17 MPa. Contribution to the Topical Issue "13th International Symposium on High Pressure Low Temperature Plasma Chemistry (Hakone XIII)", Edited by Nicolas Gherardi, Henryca Danuta Stryczewska and Yvan Ségui.

  20. Third harmonic generation in air ambient and laser ablated carbon plasma

    SciTech Connect

    Singh, Ravi Pratap Gupta, Shyam L.; Thareja, Raj K.

    2015-12-15

    We report the third harmonic generation of a nanosecond laser pulse (1.06 μm) in air ambient and in the presence of nanoparticles from laser ablated carbon plasma. Significant decrease in the threshold of third harmonic generation and multi-fold increment in the intensity of generated third harmonic is observed in presence of carbon plasma. The third harmonic in air is due to the quasi-resonant four photon process involving vibrationally excited states of molecular ion of nitrogen due to electron impact ionization and laser pulse. Following optical emission spectroscopic observations we conclude that the presence of C{sub 2} and CN in the ablated plume play a vital role in the observed third harmonic signals.

  1. Ion Beam Analysis of Targets Used in Controlatron Neutron Generators

    SciTech Connect

    Banks, James C.; Doyle, Barney L.; Walla, Lisa A.; Walsh, David S.

    2009-03-10

    Controlatron neutron generators are used for testing neutron detection systems at Sandia National Laboratories. To provide for increased tube lifetimes for the moderate neutron flux output of these generators, metal hydride (ZrT{sub 2}) target fabrication processes have been developed. To provide for manufacturing quality control of these targets, ion beam analysis techniques are used to determine film composition. The load ratios (i.e. T/Zr concentration ratios) of ZrT{sub 2} Controlatron neutron generator targets have been successfully measured by simultaneously acquiring RBS and ERD data using a He{sup ++} beam energy of 10 MeV. Several targets were measured and the film thicknesses obtained from RBS measurements agreed within {+-}2% with Dektak profilometer measurements. The target fabrication process and ion beam analysis techniques will be presented.

  2. Studies of Next Generation Air Traffic Control Specialists: Why Be an Air Traffic Controller?

    DTIC Science & Technology

    2011-08-01

    Millennials ” (Gimbel, 2007), descriptions of generational differences are a staple in the human resources (HR) trade press and corporate training. The...controllers, recruited from Gen-X and Millennials , than to the “Post-Strike” generation (largely Baby Boomers) and non-material factors such as the...air traffic coNtrol SpecialiStS: Why Be aN air traffic coNtroller? “Gen-X,” “Gen-Y,” “Baby Boomer,” “ Millennial ,” “The Greatest Generation ”: Labels

  3. Guiding supersonic projectiles using optically generated air density channels

    NASA Astrophysics Data System (ADS)

    Johnson, Luke A.; Sprangle, Phillip

    2015-09-01

    We investigate the feasibility of using optically generated channels of reduced air density to provide trajectory correction (guiding) for a supersonic projectile. It is shown that the projectile experiences a force perpendicular to its direction of motion as one side of the projectile passes through a channel of reduced air density. A single channel of reduced air density can be generated by the energy deposited from filamentation of an intense laser pulse. We propose changing the laser pulse energy from shot-to-shot to build longer effective channels. Current femtosecond laser systems with multi-millijoule pulses could provide trajectory correction of several meters on 5 km trajectories for sub-kilogram projectiles traveling at Mach 3.

  4. Electrodialytic membrane suppressors for ion chromatography make programmable buffer generators.

    PubMed

    Chen, Yongjing; Srinivasan, Kannan; Dasgupta, Purnendu K

    2012-01-03

    The use of buffer solutions is immensely important in a great variety of disciplines. The generation of continuous pH gradients in flow systems plays an important role in the chromatographic separation of proteins, high-throughput pK(a) determinations, etc. We demonstrate here that electrodialytic membrane suppressors used in ion chromatography can be used to generate buffers. The generated pH, computed from first principles, agrees well with measured values. We demonstrate the generation of phosphate and citrate buffers using a cation-exchange membrane (CEM) -based anion suppressor and Tris and ethylenediamine buffers using an anion-exchange membrane (AEM) -based cation suppressor. Using a mixture of phosphate, citrate, and borate as the buffering ions and using a CEM suppressor, we demonstrate the generation of a highly reproducible (avg RSD 0.20%, n = 3), temporally linear (pH 3.0-11.9, r(2) > 0.9996), electrically controlled pH gradient. With butylamine and a large concentration (0.5 M) of added NaCl, we demonstrate a similar linear pH gradient of large range with a near-constant ionic strength. We believe that this approach will be of value for the generation of eluents in the separation of proteins and other biomolecules and in online process titrations.

  5. Generation of low-temperature air plasma for food processing

    NASA Astrophysics Data System (ADS)

    Stepanova, Olga; Demidova, Maria; Astafiev, Alexander; Pinchuk, Mikhail; Balkir, Pinar; Turantas, Fulya

    2015-11-01

    The project is aimed at developing a physical and technical foundation of generating plasma with low gas temperature at atmospheric pressure for food industry needs. As known, plasma has an antimicrobial effect on the numerous types of microorganisms, including those that cause food spoilage. In this work an original experimental setup has been developed for the treatment of different foods. It is based on initiating corona or dielectric-barrier discharge in a chamber filled with ambient air in combination with a certain helium admixture. The experimental setup provides various conditions of discharge generation (including discharge gap geometry, supply voltage, velocity of gas flow, content of helium admixture in air and working pressure) and allows for the measurement of the electrical discharge parameters. Some recommendations on choosing optimal conditions of discharge generation for experiments on plasma food processing are developed.

  6. Charge-exchange plasma generated by an ion thruster

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.

    1977-01-01

    The charge exchange plasma generated by an ion thruster was investigated experimentally using both 5 cm and 15 cm thrusters. Results are shown for wide ranges of radial distance from the thruster and angle from the beam direction. Considerations of test environment, as well as distance from the thruster, indicate that a valid simulation of a thruster on a spacecraft was obtained. A calculation procedure and a sample calculation of charge exchange plasma density and saturation electron current density are included.

  7. Generation of subnanosecond electron beams in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Kostyrya, I. D.; Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Lomaev, M. I.; Rybka, D. V.

    2009-11-01

    Optimum conditions for the generation of runaway electron beams with maximum current amplitudes and densities in nanosecond pulsed discharges in air at atmospheric pressure are determined. A supershort avalanche electron beam (SAEB) with a current amplitude of ˜30 A, a current density of ˜20 A/cm2, and a pulse full width at half maximum (FWHM) of ˜100 ps has been observed behind the output foil of an air-filled diode. It is shown that the position of the SAEB current maximum relative to the voltage pulse front exhibits a time shift that varies when the small-size collector is moved over the foil surface.

  8. Toward the Next Generation of Air Quality Monitoring Indicators

    NASA Technical Reports Server (NTRS)

    Hsu, Angel; Reuben, Aaron; Shindell, Drew; deSherbinin, Alex; Levy, Marc

    2013-01-01

    This paper introduces an initiative to bridge the state of scientific knowledge on air pollution with the needs of policymakers and stakeholders to design the "next generation" of air quality indicators. As a first step this initiative assesses current monitoring and modeling associated with a number of important pollutants with an eye toward identifying knowledge gaps and scientific needs that are a barrier to reducing air pollution impacts on human and ecosystem health across the globe. Four outdoor air pollutants were considered e particulate matter, ozone, mercury, and Persistent Organic Pollutants (POPs) e because of their clear adverse impacts on human and ecosystem health and because of the availability of baseline data for assessment for each. While other papers appearing in this issue will address each pollutant separately, this paper serves as a summary of the initiative and presents recommendations for needed investments to provide improved measurement, monitoring, and modeling data for policyrelevant indicators. The ultimate goal of this effort is to enable enhanced public policy responses to air pollution by linking improved data and measurement methods to decision-making through the development of indicators that can allow policymakers to better understand the impacts of air pollution and, along with source attribution based on modeling and measurements, facilitate improved policies to solve it. The development of indicators represents a crucial next step in this process.

  9. Navajo Generating Station and Air Visibility Regulations: Alternatives and Impacts

    SciTech Connect

    Hurlbut, D. J.; Haase, S.; Brinkman, G.; Funk, K.; Gelman, R.; Lantz, E.; Larney, C.; Peterson, D.; Worley, C.; Liebsch, E.

    2012-01-01

    Pursuant to the Clean Air Act, the U.S. Environmental Protection Agency (EPA) announced in 2009 its intent to issue rules for controlling emissions from Navajo Generating Station that could affect visibility at the Grand Canyon and at several other national parks and wilderness areas. The final rule will conform to what EPA determines is the best available retrofit technology (BART) for the control of haze-causing air pollutants, especially nitrogen oxides. While EPA is ultimately responsible for setting Navajo Generating Station's BART standards in its final rule, it will be the U.S. Department of the Interior's responsibility to manage compliance and the related impacts. This study aims to assist both Interior and EPA by providing an objective assessment of issues relating to the power sector.

  10. Charge-exchange plasma generated by an ion thruster

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.

    1975-01-01

    The use of high voltage solar arrays greatly reduces or eliminates power processing requirements in space electric propulsion systems. This use also requires substantial areas of solar array to be at high positive potential relative to space and most of the spacecraft. The charge exchange plasma conducts electrons from the ion beam to such positive surfaces, and thereby electrically load the high voltage solar array. To evaluate this problem, the charge-exchange plasma generated by an ion beam was investigated experimentally. Based upon the experimental data, a simple model was derived for the charge-exchange plasma. This model is conservative in the sense that both the electron/ion density and the electron current density should be equal to, or less than, the preducted value for all directions in the hemisphere upstream of the ion beam direction. Increasing the distance between a positive potential surface (such as a high voltage solar array) and the thruster is the simplest way to control interactions. Both densities and currents vary as the inverse square of this distance.

  11. Combined fuel and air staged power generation system

    DOEpatents

    Rabovitser, Iosif K; Pratapas, John M; Boulanov, Dmitri

    2014-05-27

    A method and apparatus for generation of electric power employing fuel and air staging in which a first stage gas turbine and a second stage partial oxidation gas turbine power operated in parallel. A first portion of fuel and oxidant are provided to the first stage gas turbine which generates a first portion of electric power and a hot oxidant. A second portion of fuel and oxidant are provided to the second stage partial oxidation gas turbine which generates a second portion of electric power and a hot syngas. The hot oxidant and the hot syngas are provided to a bottoming cycle employing a fuel-fired boiler by which a third portion of electric power is generated.

  12. The ASAC Air Carrier Investment Model (Second Generation)

    NASA Technical Reports Server (NTRS)

    Wingrove, Earl R., III; Johnson, Jesse P.; Sickles, Robin C.; Good, David H.

    1997-01-01

    To meet its objective of assisting the U.S. aviation industry with the technological challenges of the future, NASA must identify research areas that have the greatest potential for improving the operation of the air transportation system. To accomplish this, NASA is building an Aviation System Analysis Capability (ASAC). The ASAC differs from previous NASA modeling efforts in that the economic behavior of buyers and sellers in the air transportation and aviation industries is central to its conception. To link the economics of flight with the technology of flight, ASAC requires a parametrically based mode with extensions that link airline operations and investments in aircraft with aircraft characteristics. This model also must provide a mechanism for incorporating air travel demand and profitability factors into the airlines' investment decisions. Finally, the model must be flexible and capable of being incorporated into a wide-ranging suite of economic and technical models that are envisioned for ASAC. We describe a second-generation Air Carrier Investment Model that meets these requirements. The enhanced model incorporates econometric results from the supply and demand curves faced by U.S.-scheduled passenger air carriers. It uses detailed information about their fleets in 1995 to make predictions about future aircraft purchases. It enables analysts with the ability to project revenue passenger-miles flown, airline industry employment, airline operating profit margins, numbers and types of aircraft in the fleet, and changes in aircraft manufacturing employment under various user-defined scenarios.

  13. Design and construction of cage environments for air ion and electric field research

    NASA Astrophysics Data System (ADS)

    Yost, M. G.; Kellogg, E. W.

    1987-06-01

    This report describes the design and construction of cage environments suitable for chronic exposures of large groups of mice to air ions and electric fields. These environments provide defined and reproducible ion densities, ion flux, DC electric fields, sound levels, air temperature and air quality. When used during a 2 year study, these cage environments served as a durable and reliable continuous exposure system. Three environmental chambers (cubicles) housed a total of 12 cages and provided control of air temperature, air purity and lighting. Exposure cages had grounded metal exterior walls, a plexiglass door and interior walls lined with formica. An internal isolated field plate supplemented with guard wires, energized with ca 1000 VDC, created about a 2 kV/m electric field at the grounded cage floor. Air ions resulted from the beta emission of sealed tritium foils mounted on the field plate. Cages provided high ion (1.3×105 ions/cc), low ion (1.6×103 ions/cc) and field only (ion depleted < 50 ions/cc) conditions for both polarities with similar electric fields in ionized and field only cages. Detailed mapping of the floor level ion flux using 100 cm2 flat probes gave average fluxes of 880 fA cm-2 in high ion cages and 10 fA cm-2 in low ion cages. Whole body currents measured using live anesthethized mice in high ion cages averaged 104±63 pA. Both ion flux and whole body currents remained constant over time, indicating no charge accumulation on body fur or cage wall surfaces in this exposure system.

  14. Electrostatic precipitator apparatus having an improved ion generating means

    SciTech Connect

    Fitch, R.A.; Roe, J.T.

    1982-12-21

    A system is disclosed for removing particles from a gaseous medium and comprises an upstream precipitating stage followed by a downstream precipitating stage having one or more electrically charged shells with corona discharge apparatuses therein which produce ions at predictable, generally uniformly spaced locations. The shells have flat sides and openings at the upstream and downstream ends so as to permit a portion of the gaseous medium to flow through the interior of the shell and flat sides which act as collecting means. The flat sides of the shells are generally parallel to collecting side plates for providing a uniform electric field between the shells and collecting plates, the sides of the shells having openings to permit the passage of ions generated in the interior of the shell.

  15. Spectroscopic measurement of ion temperature and ion velocity distributions in the flux-coil generated FRC.

    PubMed

    Gupta, D; Bolte, N; Gota, H; Hayashi, R; Kiyashko, V; Marsili, P; Morehouse, M; Primavera, S; Roche, T; Wessel, F

    2010-10-01

    One aim of the flux-coil generated field reversed configuration at Tri Alpha Energy (TAE) is to establish the plasma where the ion rotational energy is greater than the ion thermal energy. To verify this, an optical diagnostic was developed to simultaneously measure the Doppler velocity-shift and line-broadening using a 0.75 m, 1800 groves/mm, spectrometer. The output spectrum is magnified and imaged onto a 16-channel photomultiplier tube (PMT) array. The individual PMT outputs are coupled to high-gain, high-frequency, transimpedance amplifiers, providing fast-time response. The Doppler spectroscopy measurements, along with a survey spectrometer and photodiode-light detector, form a suite of diagnostics that provide insights into the time evolution of the plasma-ion distribution and current when accelerated by an azimuthal-electric field.

  16. Spectroscopic measurement of ion temperature and ion velocity distributions in the flux-coil generated FRC

    SciTech Connect

    Gupta, D.; Gota, H.; Hayashi, R.; Kiyashko, V.; Morehouse, M.; Primavera, S.; Bolte, N.; Marsili, P.; Roche, T.; Wessel, F.

    2010-10-15

    One aim of the flux-coil generated field reversed configuration at Tri Alpha Energy (TAE) is to establish the plasma where the ion rotational energy is greater than the ion thermal energy. To verify this, an optical diagnostic was developed to simultaneously measure the Doppler velocity-shift and line-broadening using a 0.75 m, 1800 groves/mm, spectrometer. The output spectrum is magnified and imaged onto a 16-channel photomultiplier tube (PMT) array. The individual PMT outputs are coupled to high-gain, high-frequency, transimpedance amplifiers, providing fast-time response. The Doppler spectroscopy measurements, along with a survey spectrometer and photodiode-light detector, form a suite of diagnostics that provide insights into the time evolution of the plasma-ion distribution and current when accelerated by an azimuthal-electric field.

  17. Demand response, behind-the-meter generation and air quality.

    PubMed

    Zhang, Xiyue; Zhang, K Max

    2015-02-03

    We investigated the implications of behind-the-meter (BTM) generation participating in demand response (DR) programs. Specifically, we evaluated the impacts of NOx emissions from BTM generators enrolled in the New York Independent System Operator (NYISO)'s reliability-based DR programs. Through analyzing the DR program enrollment data, DR event records, ozone air quality monitoring data, and emission characteristics of the generators, we found that the emissions from BTM generators very likely contribute to exceedingly high ozone concentrations in the Northeast Corridor region, and very likely account for a substantial fraction of total NOx emissions from electricity generation. In addition, a companion study showed that the emissions from BTM generators could also form near-source particulate matter (PM) hotspots. The important policy implications are that the absence of up-to-date regulations on BTM generators may offset the current efforts to reduce the emissions from peaking power plants, and that there is a need to quantify the environmental impacts of DR programs in designing sound policies related to demand-side resources. Furthermore, we proposed the concept of "Green" DR resources, referring to those that not only provide power systems reliability services, but also have verifiable environmental benefits or minimal negative environmental impacts. We argue that Green DR resources that are able to maintain resource adequacy and reduce emissions at the same time are key to achieving the cobenefits of power system reliability and protecting public health during periods with peak electricity demand.

  18. Air spark-like plasma source for antimicrobial NOx generation

    NASA Astrophysics Data System (ADS)

    Pavlovich, M. J.; Ono, T.; Galleher, C.; Curtis, B.; Clark, D. S.; Machala, Z.; Graves, D. B.

    2014-12-01

    We demonstrate and analyse the generation of nitrogen oxides and their antimicrobial efficacy using atmospheric air spark-like plasmas. Spark-like discharges in air in a 1 L confined volume are shown to generate NOx at an initial rate of about 1.5  ×  1016 NOx molecules/J dissipated in the plasma. Such a discharge operating in this confined volume generates on the order of 6000 ppm NOx in 10 min. Around 90% of the NOx is in the form of NO2 after several minutes of operation in the confined volume, suggesting that NO2 is the dominant antimicrobial component. The strong antimicrobial action of the NOx mixture after several minutes of plasma operation is demonstrated by measuring rates of E. coli disinfection on surfaces and in water exposed to the NOx mixture. Some possible applications of plasma generation of NOx (perhaps followed by dissolution in water) include disinfection of surfaces, skin or wound antisepsis, and sterilization of medical instruments at or near room temperature.

  19. [Spatiotemporal distribution of negative air ion concentration in urban area and related affecting factors: a review].

    PubMed

    Huang, Xiang-Hua; Wang, Jian; Zeng, Hong-Da; Chen, Guang-Shui; Zhong, Xian-Fang

    2013-06-01

    Negative air ion (NAI) concentration is an important indicator comprehensively reflecting air quality, and has significance to human beings living environment. This paper summarized the spatiotemporal distribution features of urban NAI concentration, and discussed the causes of these features based on the characteristics of the environmental factors in urban area and their effects on the physical and chemical processes of NAI. The temporal distribution of NAI concentration is mainly controlled by the periodic variation of solar radiation, while the spatial distribution of NAI concentration along the urban-rural gradient is mainly affected by the urban aerosol distribution, underlying surface characters, and urban heat island effect. The high NAI concentration in urban green area is related to the vegetation life activities and soil radiation, while the higher NAI concentration near the water environment is attributed to the water molecules that participate in the generation of NAI through a variety of ways. The other environmental factors can also affect the generation, life span, component, translocation, and distribution of NAI to some extent. To increase the urban green space and atmospheric humidity and to maintain the soil natural attributes of underlying surface could be the effective ways to increase the urban NAI concentration and improve the urban air quality.

  20. Targets for ion sources for RIB generation at the Holifield Radioactive Ion Beam Facility

    SciTech Connect

    Alton, G.D.

    1995-12-31

    The Holifield Radioactive Ion Beam Facility (HRIBF), now under construction at the Oak Ridge National Laboratory, is based on the use of the well-known on-line isotope separator (ISOL) technique in which radioactive nuclei are produced by fusion type reactions in selectively chosen target materials by high-energy proton, deuteron, or He ion beams from the Oak Ridge Isochronous Cyclotron (ORIC). Among several major challenges posed by generating and accelerating adequate intensities of radioactive ion beams (RIBs), selection of the most appropriate target material for production of the species of interest is, perhaps, the most difficult. In this report, we briefly review present efforts to select target materials and to design composite target matrix/heat-sink systems that simultaneously incorporate the short diffusion lengths, high permeabilities, and controllable temperatures required to effect maximum diffusion release rates of the short-lived species that can be realized at the temperature limits of specific target materials. We also describe the performance characteristics for a selected number of target ion sources that will be employed for initial use at the HRIBF as well as prototype ion sources that show promise for future use for RIB applications.

  1. Air Quality Impact of Distributed Generation of Electricity

    NASA Astrophysics Data System (ADS)

    Jing, Qiguo

    This dissertation summarizes the results of a five-year investigation of the impact of distributed generation (DG) of electricity on air quality in urban areas. I focused on the impact of power plants with capacities of less than 50 MW, which is typical of DG units in urban areas. These power plants are modeled as buoyant emissions from stacks less than 10 m situated in the midst of urban buildings. Because existing dispersion models are not designed for such sources, the first step of the study involved the evaluation of AERMOD, USEPA's state-of-the art dispersion model, with data collected in a tracer study conducted in the vicinity of a DG unit. The second step of the study consisted of using AERMOD to compare the impact of DG penetration in the South Coast Air Basin of Los Angeles with the impact of replacing DG generation with expansion of current central power plant capacity. The third topic of my investigation is the development and application of a model to examine the impact of non-power plant sources in a large urban area such as Los Angeles. This model can be used to estimate the air quality impact of DG relative to other sources in an urban area. The first part of this dissertation describes a tracer study conducted in Palm Springs, CA. Concentrations observed during the nighttime experiments are generally higher than those measured during the daytime experiments. They fall off less rapidly with distance than during the daytime. AERMOD provides an adequate description of concentrations associated with the buoyant releases from the DG during the daytime when turbulence is controlled by convection induced by solar heating. However, AERMOD underestimates concentrations during the night when turbulence is generated by wind shear. Also, AERMOD predicts a decrease in concentrations with distance that is much more rapid than the relatively flat observed decrease. I have suggested modifications to AERMOD to improve the agreement between model estimates and

  2. Transforming the NAS: The Next Generation Air Traffic Control System

    NASA Technical Reports Server (NTRS)

    Erzberger, Heinz

    2004-01-01

    The next-generation air traffic control system must be designed to safely and efficiently accommodate the large growth of traffic expected in the near future. It should be sufficiently scalable to contend with the factor of 2 or more increase in demand expected by the year 2020. Analysis has shown that the current method of controlling air traffic cannot be scaled up to provide such levels of capacity. Therefore, to achieve a large increase in capacity while also giving pilots increased freedom to optimize their flight trajectories requires a fundamental change in the way air traffic is controlled. The key to achieving a factor of 2 or more increase in airspace capacity is to automate separation monitoring and control and to use an air-ground data link to send trajectories and clearances directly between ground-based and airborne systems. In addition to increasing capacity and offering greater flexibility in the selection of trajectories, this approach also has the potential to increase safety by reducing controller and pilot errors that occur in routine monitoring and voice communication tasks.

  3. Heavy ion event generator HYDJET++ (HYDrodynamics plus JETs)

    NASA Astrophysics Data System (ADS)

    Lokhtin, I. P.; Malinina, L. V.; Petrushanko, S. V.; Snigirev, A. M.; Arsene, I.; Tywoniuk, K.

    2009-05-01

    HYDJET++ is a Monte Carlo event generator for simulation of relativistic heavy ion AA collisions considered as a superposition of the soft, hydro-type state and the hard state resulting from multi-parton fragmentation. This model is the development and continuation of HYDJET event generator (Lokhtin and Snigirev, EPJC 45 (2006) 211). The main program is written in the object-oriented C++ language under the ROOT environment. The hard part of HYDJET++ is identical to the hard part of Fortran-written HYDJET and it is included in the generator structure as a separate directory. The soft part of HYDJET++ event is the "thermal" hadronic state generated on the chemical and thermal freeze-out hypersurfaces obtained from the parameterization of relativistic hydrodynamics with preset freeze-out conditions. It includes the longitudinal, radial and elliptic flow effects and the decays of hadronic resonances. The corresponding fast Monte Carlo simulation procedure, C++ code FAST MC (Amelin et al., PRC 74 (2006) 064901; PRC 77 (2008) 014903) is adapted to HYDJET++. It is designed for studying the multi-particle production in a wide energy range of heavy ion experimental facilities: from FAIR and NICA to RHIC and LHC. Program summaryProgram title: HYDJET++, version 2 Catalogue identifier: AECR_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AECR_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.: 100 387 No. of bytes in distributed program, including test data, etc.: 797 019 Distribution format: tar.gz Programming language: C++ (however there is a Fortran-written part which is included in the generator structure as a separate directory) Computer: Hardware independent (both C++ and Fortran compilers and ROOT environment [1] ( http://root.cern.ch/) should be installed

  4. Design studies for the next generation electron ion colliders

    NASA Astrophysics Data System (ADS)

    Sayed, Hisham Kamal; Bogacz, S. A.; Krafft, G.

    2014-04-01

    The next generation Electron Ion Collider (EIC) at Thomas Jefferson National Accelerator Facility (JLAB) utilizes a figure-8 shaped ion and electron rings. EIC has the ability to preserve the ion polarization during acceleration, where the electron ring matches in footprint with a figure-8 ion ring. The electron ring is designed to deliver a highly polarized high luminous electron beam at interaction point (IP). The main challenges of the electron ring design are the chromaticity compensation and maintaining high beam polarization of 70% at all energies 3-11 GeV without introducing transverse orbital coupling before the IP. The very demanding detector design limits the minimum distance between the final focus quadrupole and the interaction point to 3.5 m which results in a large β function inside the final focus quadrupoles leading to increased beam chromaticity. In this paper, we present a novel chromaticity compensation scheme that mitigates IP chromaticity by a compact chromaticity compensation section with multipole magnet components. In addition, a set of spin rotators are utilized to manipulate the polarization vector of the electron beam in order to preserve the beam polarization. The spin rotator solenoids introduce undesired coupling between the horizontal and vertical betatron motion of the beam. We introduce a compact and modular orbit decoupling insert that can fit in the limited space of the straight section in the figure-8 ring. We show a numerical study of the figure-8 ring design with the compact straight section, which includes the interaction region, chromaticity compensation section, and the spin rotators, the figure-8 design performance is evaluated with particle tracking.

  5. Design studies for the next generation electron ion colliders

    SciTech Connect

    Sayed, Hisham Kamal; Bogacz, Slawomir A.; Krafft, Geoffrey A.

    2014-04-01

    The next generation Electron Ion Collider (EIC) at Thomas Jefferson National Accelerator Facility (JLAB) utilizes a figure-8 shaped ion and electron rings. EIC has the ability to preserve the ion polarization during acceleration, where the electron ring matches in footprint with a figure-8 ion ring. The electron ring is designed to deliver a highly polarized high luminous electron beam at interaction point (IP). The main challenges of the electron ring design are the chromaticity compensation and maintaining high beam polarization of 70% at all energies 3–11 GeV without introducing transverse orbital coupling before the IP. The very demanding detector design limits the minimum distance between the final focus quadrupole and the interaction point to 3.5 m which results in a large β function inside the final focus quadrupoles leading to increased beam chromaticity. In this paper, we present a novel chromaticity compensation scheme that mitigates IP chromaticity by a compact chromaticity compensation section with multipole magnet components. In addition, a set of spin rotators are utilized to manipulate the polarization vector of the electron beam in order to preserve the beam polarization. The spin rotator solenoids introduce undesired coupling between the horizontal and vertical betatron motion of the beam. We introduce a compact and modular orbit decoupling insert that can fit in the limited space of the straight section in the figure-8 ring. We show a numerical study of the figure-8 ring design with the compact straight section, which includes the interaction region, chromaticity compensation section, and the spin rotators, the figure-8 design performance is evaluated with particle tracking.

  6. Initial results from the operation of two argon ion generators in the auroral ionosphere

    NASA Technical Reports Server (NTRS)

    Erlandson, R. E.; Cahill, L. J., Jr.; Pollock, C. J.; Arnoldy, R. L.; Scales, W. A.

    1987-01-01

    Two argon ion generators have been lofted by sounding rockets in order to investigate ion beam dynamics and beam effects on the ionosphere, and auroral electrodynamics during rocket passage over auroral arcs. The ion generators were on a subpayload that was separated from the main payload early in the flight. The main payload conducted the diagnostic measurements during ion beam operations. Evidence of heating of the ionosphere around the subpayload during each ion beam emission is noted.

  7. Response of air-filled ion chambers to high-intensity radiation pulses

    SciTech Connect

    Plum, M.; Brown, D.

    1993-06-01

    Ion chambers are one of the most popular types of detectors used for beam loss-monitor systems. To provide a foundation for the development of future loss-monitor systems, and to fully characterize the ion chambers in use at LAMPF, we have studied the response of air-filled cylindrical ion chambers to high-intensity, short-duration radiation pulses. The most intense pulses were about 180 rad in 250 ns (the equivalent steady-state dose rate was about 700 Mrad/h). We filled our chambers with nitrogen gas at 760 Torr and air at 600 Torr. The ion chambers were driven into extreme nonlinear response. We hope these data will be used to design loss-monitor systems based on air-filled ion chambers, thus eliminating the need for gas-flow systems and/or airtight ion chambers.

  8. Response of air-filled ion chambers to high-intensity radiation pulses

    SciTech Connect

    Plum, M.; Brown, D.

    1993-01-01

    Ion chambers are one of the most popular types of detectors used for beam loss-monitor systems. To provide a foundation for the development of future loss-monitor systems, and to fully characterize the ion chambers in use at LAMPF, we have studied the response of air-filled cylindrical ion chambers to high-intensity, short-duration radiation pulses. The most intense pulses were about 180 rad in 250 ns (the equivalent steady-state dose rate was about 700 Mrad/h). We filled our chambers with nitrogen gas at 760 Torr and air at 600 Torr. The ion chambers were driven into extreme nonlinear response. We hope these data will be used to design loss-monitor systems based on air-filled ion chambers, thus eliminating the need for gas-flow systems and/or airtight ion chambers.

  9. Air-borne sound generated by sea waves.

    PubMed

    Bolin, Karl; Åbom, Mats

    2010-05-01

    This paper describes a semi-empiric model and measurements of air-borne sound generated by breaking sea waves. Measurements have been performed at the Baltic Sea. Shores with different slopes and sediment types have been investigated. Results showed that the sound pressure level increased from 60 dB at 0.4 m wave height to 78 dB at 2.0 m wave height. The 1/3 octave spectrum was dependent on the surf type. A scaling model based on the dissipated wave power and a surf similarity parameter is proposed and compared to measurements. The predictions show satisfactory agreement to the measurements.

  10. The 28 GHZ, 10 KW, CW Gyrotron Generator for the VENUS ECR Ion Source at LBNL

    SciTech Connect

    Marks, M.; Evans, S.; Jory, H.; Holstein, D.; Rizzo, R.; Beck, P.; Cisto, B.; Leitner, D.; Lyneis, C.M.; Collins, D.; Dwinell, R.D.

    2005-03-15

    The VIA-301 Heatwave{sup TM} gyrotron generator was specifically designed to meet the requirements of the Venus ECR Ion Source at the Lawrence Berkeley National Laboratory (LBNL). VENUS (Versatile ECR ion source for NUclear Science) is a next generation superconducting ECR ion source, designed to produce high current, high charge state ions for the 88-Inch Cyclotron at the Lawrence Berkeley National Laboratory. VENUS also serves as the prototype ion source for the RIA (Rare Isotope Accelerator) front end].This VIA-301 Heatwave{sup TM} gyrotron system provides 100 watts to 10 kW continuous wave (CW) RF output at 28 GHz. The RF output level is smoothly controllable throughout this entire range. The power can be set and maintained to within 10 watts at the higher power end of the power range and to within 30 watts at the lower power end of the power range. A dual directional coupler, analog conditioning circuitry, and a 12-bit analog input to the embedded controller are used to provide a power measurement accurate to within 2%. The embedded controller completes a feedback loop using an external command set point for desired power output. Typical control-loop-time is on the order of 500 mS. Hard-wired interlocks are provided for personnel safety and for protection of the generator system. In addition, there are software controlled interlocks for protection of the generator from high ambient temperature, high water temperature, and other conditions that would affect the performance of the generator or reduce the lifetime of the gyrotron. Cooling of the gyrotron and power supply is achieved using both water and forced circulation of ambient air. Water-cooling provides about 80% of the cooling requirement. Input power to the generator from the prime power line is less than 60 kW at full power. The Heatwave{sup TM} may be operated locally via its front panel or remotely via either RS-232 and/or Ethernet connections. Through the RS-232 the forward power, the reflected power

  11. The 28 GHZ, 10 KW, CW Gyrotron Generator for the VENUS ECR Ion Source at LBNL

    NASA Astrophysics Data System (ADS)

    Marks, M.; Evans, S.; Jory, H.; Holstein, D.; Rizzo, R.; Beck, P.; Cisto, B.; Leitner, D.; Lyneis, C. M.; Collins, D.; Dwinell, R. D.

    2005-03-01

    The VIA-301 Heatwave™ gyrotron generator was specifically designed to meet the requirements of the Venus ECR Ion Source at the Lawrence Berkeley National Laboratory (LBNL). VENUS (Versatile ECR ion source for NUclear Science) is a next generation superconducting ECR ion source, designed to produce high current, high charge state ions for the 88-Inch Cyclotron at the Lawrence Berkeley National Laboratory. VENUS also serves as the prototype ion source for the RIA (Rare Isotope Accelerator) front end [1]. This VIA-301 Heatwave™ gyrotron system provides 100 watts to 10 kW continuous wave (CW) RF output at 28 GHz. The RF output level is smoothly controllable throughout this entire range. The power can be set and maintained to within 10 watts at the higher power end of the power range and to within 30 watts at the lower power end of the power range. A dual directional coupler, analog conditioning circuitry, and a 12-bit analog input to the embedded controller are used to provide a power measurement accurate to within 2%. The embedded controller completes a feedback loop using an external command set point for desired power output. Typical control-loop-time is on the order of 500 mS. Hard-wired interlocks are provided for personnel safety and for protection of the generator system. In addition, there are software controlled interlocks for protection of the generator from high ambient temperature, high water temperature, and other conditions that would affect the performance of the generator or reduce the lifetime of the gyrotron. Cooling of the gyrotron and power supply is achieved using both water and forced circulation of ambient air. Water-cooling provides about 80% of the cooling requirement. Input power to the generator from the prime power line is less than 60 kW at full power. The Heatwave™ may be operated locally via its front panel or remotely via either RS-232 and/or Ethernet connections. Through the RS-232 the forward power, the reflected power, the

  12. Ozone Generation in Air during Electron Beam Processing

    NASA Astrophysics Data System (ADS)

    Cleland, Marshall R.; Galloway, Richard A.

    Ozone, the triatomic form of oxygen, can be generated by exposing normal diatomic oxygen gas to energetic electrons, X-rays, nuclear gamma rays, short-wavelength ultraviolet radiation (UV) and electrical discharges. Ozone is toxic to all forms of life, and governmental regulations have been established to protect people from excessive exposures to this gas. The human threshold limit values (TLV) vary from 60 to 100 parts per billion (ppb) in air, depending on the agency or country involved. Much higher concentrations can be produced inside industrial electron beam (EB) facilities, so methods for ozone removal must be provided. Equations for calculating the ozone yield vs absorbed energy, the production rate vs absorbed power, and the concentration in the air of an EB facility are presented in this paper. Since the production rate and concentration are proportional to the EB power dissipated in air, they are dependent on the design and application of the irradiation facility. Examples of these calculations are given for a typical EB process to cross-link insulated electrical wire or plastic tubing. The electron energy and beam power are assumed to be 1.5 MeV and 75 kW.

  13. Stress and physiological, behavioral and performance patterns of children under varied air ion levels

    NASA Astrophysics Data System (ADS)

    Fornof, K. T.; Gilbert, G. O.

    1988-12-01

    The possibility that individual differences in reactivity to stressors are a major factor underlying discordant results reported for air ion studies prompted an investigation of response patterns in school children under both normal indoor air ion levels and moderately increased negative air ion levels (4000±500/cm3). It was hypothesized that the impact of stressors is reduced with high negative air ionization, and that resultant changes in stress effects would be differentially exhibited according to the children's normal degree of stimulus reactivity. A counter-balanced, replicative, withinssubject design was selected, and the subjects were 12 environmentally sensitive, 1st 4th grade school children. In addition to monitoring stress effects on activity level, attention span, concentration to task and conceptual performance, measures were also made of urinary 5-hydroxyindole acetic acid levels and skin resistance response (SRR) to determine if changes extended to the physiological state. The cold water test was used to add physical stress and enable calculations of Lacey's autonomic lability scores (ALS) as indicators of individual reactivity. The results show main effects for air ions on both physiological parameters, with 48% less change in %SRR ( P<0.01) and 46% less change in urinary 5-HIAA levels ( P<0.055) during negative air ions, indicating increased stress tolerance. Strong interactive effects for ALS x air ion condition appeared, with high and low ALS children reacting oppositely to negative air ions in measures of skin resistance level ( P<0.01), wrist activity ( P<0.01) and digit span backwards ( P<0.004). Thus individual differences in autonomic reactivity and the presence or absence of stressors appear as critical elements for internal validity, and in preventing consequent skewed results from obscuring progress in air ion research.

  14. Secondary particle tracks generated by ion beam irradiation

    NASA Astrophysics Data System (ADS)

    García, Gustavo

    2015-05-01

    The Low Energy Particle Track Simulation (LEPTS) procedure is a powerful complementary tool to include the effect of low energy electrons and positrons in medical applications of radiation. In particular, for ion-beam cancer treatments provides a detailed description of the role of the secondary electrons abundantly generated around the Bragg peak as well as the possibility of using transmuted positron emitters (C11, O15) as a complement for ion-beam dosimetry. In this study we present interaction probability data derived from IAM-SCAR corrective factors for liquid environments. Using these data, single electron and positron tracks in liquid water and pyrimidine have been simulated providing information about energy deposition as well as the number and type of interactions taking place in any selected ``nanovolume'' of the irradiated area. In collaboration with Francisco Blanco, Universidad Complutense de Madrid; Antonio Mu noz, Centro de Investigaciones Energéticas Medioambientales y Tecnológicas and Diogo Almeida, Filipe Ferreira da Silva, Paulo Lim ao-Vieira, Universidade Nova de Lisboa. Supported by the Spanish and Portuguese governments.

  15. Next Generation H- Ion Sources for the SNS

    NASA Astrophysics Data System (ADS)

    Welton, R. F.; Stockli, M. P.; Murray, S. N.; Crisp, D.; Carmichael, J.; Goulding, R. H.; Han, B.; Tarvainen, O.; Pennisi, T.; Santana, M.

    2009-03-01

    The U.S. Spallation Neutron Source (SNS) is the leading accelerator-based, pulsed neutron-scattering facility, currently in the process of ramping up neutron production. In order to insure meeting operational requirements as well as providing for future facility beam power upgrades, a multifaceted H- ion source development program is ongoing. This work discusses several aspects of this program, specifically the design and first beam measurements of an RF-driven, external antenna H- ion source based on an A1N ceramic plasma chamber, elemental and chromate Cs-systems, and plasma ignition gun. Unanalyzed beam currents of up to ˜100 mA (60 Hz, 1 ms) have been observed and sustained currents >60 mA (60 Hz, 1 ms) have been demonstrated on the test stand. Accelerated beam currents of ˜40 mA have also been demonstrated into the SNS front end. Data are also presented describing the first H- beam extraction experiments from a helicon plasma generator based on the Variable Specific Impulse Magnetoplasma Rocket (VASIMR) engine design.

  16. Next Generation H{sup -} Ion Sources for the SNS

    SciTech Connect

    Welton, R. F.; Stockli, M. P.; Murray, S. N.; Crisp, D.; Carmichael, J.; Goulding, R. H.; Han, B.; Pennisi, T.; Santana, M.; Tarvainen, O.

    2009-03-12

    The U.S. Spallation Neutron Source (SNS) is the leading accelerator-based, pulsed neutron-scattering facility, currently in the process of ramping up neutron production. In order to insure meeting operational requirements as well as providing for future facility beam power upgrades, a multifaceted H- ion source development program is ongoing. This work discusses several aspects of this program, specifically the design and first beam measurements of an RF-driven, external antenna H- ion source based on an A1N ceramic plasma chamber, elemental and chromate Cs-systems, and plasma ignition gun. Unanalyzed beam currents of up to {approx}100 mA(60 Hz, 1 ms) have been observed and sustained currents >60 mA(60 Hz, 1 ms) have been demonstrated on the test stand. Accelerated beam currents of {approx}40 mA have also been demonstrated into the SNS front end. Data are also presented describing the first H- beam extraction experiments from a helicon plasma generator based on the Variable Specific Impulse Magnetoplasma Rocket (VASIMR) engine design.

  17. Next Generation H- Ion Sources for the SNS

    SciTech Connect

    Welton, Robert F; Carmichael, Justin R; Carr, Jr, Jerry; Crisp, Danny W; Goulding, Richard Howell; Han, Baoxi; Pennisi, Terry R; Murray Jr, S N; Stockli, Martin P; Tarvainen, Olli A; Santana, Manuel

    2009-01-01

    The U.S. Spallation Neutron Source (SNS) is the leading accelerator-based, pulsed neutron-scattering facility, currently in the process of ramping up neutron production. In order to insure meeting operational requirements as well as providing for future facility beam power upgrades, a multifaceted H{sup -} ion source development program is ongoing. This work discusses several aspects of this program, specifically the design and first beam measurements of an RF-driven, external antenna H{sup -} ion source based on an AlN ceramic plasma chamber, elemental and chromate Cs-systems, and plasma ignition gun. Unanalyzed beam currents of up to {approx}100 mA (60Hz, 1ms) have been observed and sustained currents >60 mA (60Hz, 1ms) have been demonstrated on the test stand. Accelerated beam currents of {approx}40 mA have also been demonstrated into the SNS front end. Data are also presented describing the first H{sup -} beam extraction experiments from a helicon plasma generator based on the Variable Specific Impulse Magnetoplasma Rocket (VASIMR) engine design.

  18. Evaluating and mapping of spatial air ion quality patterns in a residential garden using a geostatistic method.

    PubMed

    Wu, Chen-Fa; Lai, Chun-Hsien; Chu, Hone-Jay; Lin, Wen-Huang

    2011-06-01

    Negative air ions (NAI) produce biochemical reactions that increase the levels of the mood chemical serotonin in the environment. Moreover, they benefit both the psychological well being and the human body's physiological condition. The aim of this research was to estimate and measure the spatial distributions of negative and positive air ions in a residential garden in central Taiwan. Negative and positive air ions were measured at thirty monitoring locations in the study garden from July 2009 to June 2010. Moreover, Kriging was applied to estimate the spatial distribution of negative and positive air ions, as well as the air ion index in the study area. The measurement results showed that the numbers of NAI and PAI differed greatly during the four seasons, the highest and the lowest negative and positive air ion concentrations were found in the summer and winter, respectively. Moreover, temperature was positively affected negative air ions concentration. No matter what temperature is, the ranges of variogram in NAI/PAI were similar during four seasons. It indicated that spatial patterns of NAI/PAI were independent of the seasons and depended on garden elements and configuration, thus the NAP/PAI was a good estimate of the air quality regarding air ions. Kriging maps depicted that the highest negative and positive air ion concentration was next to the waterfall, whereas the lowest air ions areas were next to the exits of the garden. The results reveal that waterscapes are a source of negative and positive air ions, and that plants and green space are a minor source of negative air ions in the study garden. Moreover, temperature and humidity are positively and negatively affected negative air ions concentration, respectively. The proposed monitoring and mapping approach provides a way to effectively assess the patterns of negative and positive air ions in future landscape design projects.

  19. Ozone Generators That Are Sold as Air Cleaners

    MedlinePlus

    ... United States Environmental Protection Agency Search Search Indoor Air Quality (IAQ) Share Facebook Twitter Google+ Pinterest Contact Us ... question, provide feedback, or report a problem. Indoor Air Quality (IAQ) Indoor Air Quality Home IAQ by Building ...

  20. The effects of negative air ions on various physiological functions during work in a hot environment

    NASA Astrophysics Data System (ADS)

    Inbar, O.; Rotstein, A.; Dlin, R.; Dotan, R.; Sulman, F. G.

    1982-06-01

    The effects of negative air-ions on human physical performance has been investigated. Twenty-one healthy males, 20 25 years old (X=23.6±2.6) were exposed to two 180-min rest and exercise sessions two weeks apart. The subjects were randomly assigned into either an experimental group (n=12) or to a control group (n=9). The experimental group performed the first session in neutral air conditions and the second one in air containing 1.36 to 1.90×105 negative air ions and 1.40 to 1.66×102 positive air ions/ml. The control group performed both sessions under neutral air conditions. All sessions were held at Ta=40±1‡C and 25±5% RH. Each session included one hour of resting under the respective ionization conditions, followed by 3 30-min cycle ergometer work bouts, separated by 7-min rest periods. The mechanical work-load during the bicycle exercise was 1.64±0.6 W/kg BW. The experimental group showed a significant reduction with negative air-ions in heart rate (HR), in rectal temperature, and in the rating of perceived exertion (RPE), all when compared with their own neutral session. The control group showed no significant changes between the first and the second exposure. Although not statistically significant, being exposed to negative air-ions seems also to reduce total sweat rate and minute ventilation (VE), and to increase O2 pulse. It is suggested that under the conditions of this study negative air ions can improve various cardiovascular and thermoregulatory functions as well as subjective feelings during physical effort. It is felt that such positive influences may be augmented by increasing the exposure time to negative ionized air and/or prolonging the stressful conditions.

  1. Positive and negative ions by air purifier have no effects on embryo-fetal development in rats.

    PubMed

    Yamamoto, Dai; Wako, Kiyoshi; Sato, Yukari; Fujishiro, Mayumi; Matsuura, Ikuo; Ohnishi, Yasuyuki

    2014-06-01

    Air purifiers, which release positive and negative ions generated by an electric discharge into the air, have been widely used in common households. In this study, the developmental toxicity potential of the ionized air containing positive and negative ions was evaluated in SD rats [Crl:CD(SD)] following whole-body inhalation to obtain preliminary information for the definitive study. Two groups of 10 pregnant female rats were exposed to the ionized air at concentrations of 0 and 7,000,000 ions/cm(3) for 6 hr per day from Days 6 to 19 of gestation. All dams underwent a cesarean section on Day 20 of gestation and their fetuses were examined externally, viscerally, and skeletally for morphological changes. The ionized air had no effects on dams in terms of clinical signs, body weight, food consumption, gravid uterine weights, corrected body weight by gravid uterine weight, or necropsy findings. In addition, there were no effects on the maintenance of pregnancy, including abortion or premature delivery. No exposure-related changes were detected in the number of corpora lutea, implantations, dead embryos, or live fetuses, implantation loss, live fetal weights, sex ratio, or placental weight or features. Fetal examination revealed no external, visceral, or skeletal anomalies or variations caused by the ionized air, nor were there any changes in degree of ossification. Although this study did not fully adhere to the current guidelines because of a smaller number of animals per group, it was suggested that the ionized air has no maternal toxicity or embryo-fetal toxicity in rats.

  2. Optical emission spectroscopy of nanosecond repetitively pulsed microplasmas generated in air at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Orriere, Thomas; Moreau, Eric; Benard, Nicolas; Pai, David

    2015-09-01

    Nanosecond repetitively pulsed (NRP) microplasmas are generated in room temperature air at atmospheric pressure, in order to investigate the enhanced control of discharge properties via the combined effects of spatial confinement and nanosecond repetitive pulsing. Discharges were generated using high-voltage pulses of 15-ns duration applied to a tungsten pin-to-pin reactor, with inter-electrode gap distances (d) from 2 mm down to 0.2 mm. Optical emission spectroscopy and electrical characterization performed on the discharge indicate that heat transfer and plasma chemistry are influenced by the microplasma geometry. Ultrafast gas heating is observed upon deducing the rotational temperature of N2 from the measured emission spectrum of the N2 (C -->B) (0, 2) and (1, 3) transition bands, but use of the microplasma geometry (d = 0.2 mm) results in lower gas temperatures than in larger discharge gaps (d = 2 mm), including at high pulse repetition frequency (30 kHz) where substantial steady-state gas heating can occur. The measured Stark broadening of the Hα transition is significantly greater than for previously studied NRP discharges in air at atmospheric pressure, indicating that the maximum electron number density may be correspondingly much greater, up to 1018 cm-3. Furthermore, for NRP microplasmas, the intensities of emission from excited atomic ions (O+ and N+) are much higher than those of excited neutral atoms (O and N), in contrast to NRP discharges generated in larger discharge gaps.

  3. Multi-layered, chemically bonded lithium-ion and lithium/air batteries

    DOEpatents

    Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

    2014-05-13

    Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

  4. Long-term biological effects of air ions and D.C. electric fields on Namru mice: First year report

    NASA Astrophysics Data System (ADS)

    Kellogg, E. W.; Yost, M. G.; Reed, E. J.; Krueger, A. P.

    1985-09-01

    This report describes for the first time the effects of long-term continuous exposures of animals to small air ions and D.C. electric fields. In this study we exposed 200 female NAMRU mice (25/cage) to the following conditions: ± high ions (2×105/cm3), ± low ions (2×103/cm3), ± field only and ground (ion depleted, no field). Specially designed cages provided a defined D.C. field of about 2 kV/meter in ionized environments, with somewhat lower values in the field only cages. Detailed mapping of ion flux originating from a tritium foil generating system (multiple sources in an overhead plate) indicated a well defined, but heterogenous pattern with eight peak areas. Using a 100 cm2 probe, ion flux values ranged from 10-12 10-14 A/cm2, with an average flux of 8.7±6.8×10-13 A/cm2 in high negative ion cages, with good reproducibility between cages. Measurements of serum glucose, cholesterol, and urea nitrogen (samples taken every three months) showed a number of small but consistent and statistically significant differences between animals maintained in different environments during the first year of exposure. Serum globulin and whole blood serotonin, however, did not show any significant environmental effects. Interestingly, pairwise comparisons between high negative and low negative ion conditions, or between high positive and low positive ion conditions, or between the two ground conditions, revealed no significant differences between cages. This argues for a similarity of environmental responses for the mice maintained in each of the compared conditions. The results of a multiple classification analysis for the entire first year showed a preponderence of effects for the ionized cages, although other conditions also had highly significant differences as compared to the grand mean value. While this study has shown effects of only small magnitude (compared to normal physiological variations) in the female NAMRU mice studied here, the significance of these results

  5. Generating Breathable Air Through Dissociation of N2O

    NASA Technical Reports Server (NTRS)

    Zubrin, Robert; Frankie, Brian

    2006-01-01

    A nitrous oxide-based oxygen-supply system (NOBOSS) is an apparatus in which a breathable mixture comprising 2/3 volume parts of N2 and 1/3 volume part of O2 is generated through dissociation of N2O. The NOBOSS concept can be adapted to a variety of applications in which there are requirements for relatively compact, lightweight systems to supply breathable air. These could include air-supply systems for firefighters, divers, astronauts, and workers who must be protected against biological and chemical hazards. A NOBOSS stands in contrast to compressed-gas and cryogenic air-supply systems. Compressed-gas systems necessarily include massive tanks that can hold only relatively small amounts of gases. Alternatively, gases can be stored compactly in greater quantities and at low pressures when they are liquefied, but then cryogenic equipment is needed to maintain them in liquid form. Overcoming the disadvantages of both compressed-gas and cryogenic systems, the NOBOSS exploits the fact that N2O can be stored in liquid form at room temperature and moderate pressure. The mass of N2O that can be stored in a tank of a given mass is about 20 times the mass of compressed air that can be stored in a tank of equal mass. In a NOBOSS, N2O is exothermically dissociated to N2 and O2 in a main catalytic reactor. In order to ensure the dissociation of N2O to the maximum possible extent, the temperature of the reactor must be kept above 400 C. At the same time, to minimize concentrations of nitrogen oxides (which are toxic), it is necessary to keep the reactor temperature at or below 540 C. To keep the temperature within the required range throughout the reactor and, in particular, to prevent the formation of hot spots that would be generated by local concentrations of the exothermic dissociation reaction, the N2O is introduced into the reactor through an injector tube that features carefully spaced holes to distribute the input flow of N2O widely throughout the reactor. A NOBOSS

  6. Neutron generators with size scalability, ease of fabrication and multiple ion source functionalities

    DOEpatents

    Elizondo-Decanini, Juan M

    2014-11-18

    A neutron generator is provided with a flat, rectilinear geometry and surface mounted metallizations. This construction provides scalability and ease of fabrication, and permits multiple ion source functionalities.

  7. Laboratory air bubble generation of various size distributions

    SciTech Connect

    Puleo, Jack A.; Johnson, Rex V.; Kooney, Tim N.

    2004-11-01

    Air bubble size in aqueous environments is an important factor governing natural processes ranging from fluid/atmosphere gas transfer to noise production. Bubbles are also known to affect various scientific instruments. In this study we investigate the production capability of eight inexpensive bubble generators using optical imaging techniques. Specific emphasis is directed towards determining bubble size and distribution for a given device, flow conditions, and type of water used (fresh vs salt). In almost all cases tested here, bubbles produced in salt water were more numerous, and smaller than for the same bubbler and conditions in fresh water. For porous media, the finer the pore size, the smaller the bubble produced with some variation depending on thickness of material containing the pore and water type. While no single generator tested was capable of spanning all the bubble sizes observed (100 to 6000 microns), the data contained herein will enable proper choice of bubbler or combinations thereof for future studies depending on the size and distribution of bubbles required.

  8. A carbon-air battery for high power generation.

    PubMed

    Yang, Binbin; Ran, Ran; Zhong, Yijun; Su, Chao; Tadé, Moses O; Shao, Zongping

    2015-03-16

    We report a carbon-air battery for power generation based on a solid-oxide fuel cell (SOFC) integrated with a ceramic CO2-permeable membrane. An anode-supported tubular SOFC functioned as a carbon fuel container as well as an electrochemical device for power generation, while a high-temperature CO2-permeable membrane composed of a CO3(2-) mixture and an O(2-) conducting phase (Sm(0.2)Ce(0.8)O(1.9)) was integrated for in situ separation of CO2 (electrochemical product) from the anode chamber, delivering high fuel-utilization efficiency. After modifying the carbon fuel with a reverse Boudouard reaction catalyst to promote the in situ gasification of carbon to CO, an attractive peak power density of 279.3 mW cm(-2) was achieved for the battery at 850 °C, and a small stack composed of two batteries can be operated continuously for 200 min. This work provides a novel type of electrochemical energy device that has a wide range of application potentials.

  9. [The investigation of air ion and particulates condition in Tianzhu Mountain].

    PubMed

    Xiu, Y L

    1990-05-01

    In order to monitor the distribution of atmospheric air ion and particulates in Tianzhu Mountain region, two observation points were established in Tianzhu Mountain in April, 1989. The results showed that the average concentration of air anode ion was 680/cm3, cathode ion 650/cm3. the range of single electrode coefficient is comfortable feeling, air quality index is 0.71 up to standard B grade (clean air), Total average concentration of suspended particulates was 0.242 mg/m3, average concentration of inhalation particulates was 0.168 mg/m3. Seventy percent particulates had diameters less than 10 microns, and thirty percent greater than 10 microns in total suspended particulates.

  10. Next Generation Air Measurements for Fugitive, Area Source, and Fence Line Applications

    EPA Science Inventory

    Next generation air measurements (NGAM) is an EPA term for the advancing field of air pollutant sensor technologies, data integration concepts, and geospatial modeling strategies. Ranging from personal sensors to satellite remote sensing, NGAM systems may provide revolutionary n...

  11. Continuum Generation of the Third-Harmonic Pulse Generated by an Intense Femtosecond IR Laser Pulse in Air

    DTIC Science & Technology

    2003-06-06

    c.m. bowden3 Continuum generation of the third-harmonic pulse generated by an intense femtosecond IR laser pulse in air 1 Time Domain Corporation...picosecond high-peak-power laser pulses are propagated in air. The supercontinuum generated during the filamentation process has been used for time ...collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources

  12. Application of Coaxial Ion Gun for Film Generation and Ion Implantation

    NASA Astrophysics Data System (ADS)

    Takatsu, Mikio; Asai, Tomohiko; Kurumi, Satoshi; Suzuki, Kaoru; Hirose, Hideharu; Masutani, Shigeyuki

    A magnetized coaxial plasma gun (MCPG) is here utilized for deposition on high-melting-point metals. MCPGs have hitherto been studied mostly in the context of nuclear fusion research, for particle and magnetic helicity injection and spheromak formation. During spheromak formation, the electrode materials are ionized and mixed into the plasmoid. In this study, this ablation process by gun-current sputtering is enhanced for metallic thin-film generation. In the proposed system geometry, only ionized materials are electromagnetically accelerated by the self-Lorentz force, with ionized operating gas as a magnetized thermal plasmoid, contributing to the thin-film deposition. This reduces the impurity and non-uniformity of the deposited thin-film. Furthermore, as the ions are accelerated in a parallel direction to the injection axis, vertical implantation of the ions into the substrate surface is achieved. To test a potential application of the developed system, experiments were conducted involving the formation of a buffer layer on hard ceramics, for use in dental materials.

  13. Generating and controlling homogeneous air turbulence using random jet arrays

    NASA Astrophysics Data System (ADS)

    Carter, Douglas; Petersen, Alec; Amili, Omid; Coletti, Filippo

    2016-12-01

    The use of random jet arrays, already employed in water tank facilities to generate zero-mean-flow homogeneous turbulence, is extended to air as a working fluid. A novel facility is introduced that uses two facing arrays of individually controlled jets (256 in total) to force steady homogeneous turbulence with negligible mean flow, shear, and strain. Quasi-synthetic jet pumps are created by expanding pressurized air through small straight nozzles and are actuated by fast-response low-voltage solenoid valves. Velocity fields, two-point correlations, energy spectra, and second-order structure functions are obtained from 2D PIV and are used to characterize the turbulence from the integral-to-the Kolmogorov scales. Several metrics are defined to quantify how well zero-mean-flow homogeneous turbulence is approximated for a wide range of forcing and geometric parameters. With increasing jet firing time duration, both the velocity fluctuations and the integral length scales are augmented and therefore the Reynolds number is increased. We reach a Taylor-microscale Reynolds number of 470, a large-scale Reynolds number of 74,000, and an integral-to-Kolmogorov length scale ratio of 680. The volume of the present homogeneous turbulence, the largest reported to date in a zero-mean-flow facility, is much larger than the integral length scale, allowing for the natural development of the energy cascade. The turbulence is found to be anisotropic irrespective of the distance between the jet arrays. Fine grids placed in front of the jets are effective at modulating the turbulence, reducing both velocity fluctuations and integral scales. Varying the jet-to-jet spacing within each array has no effect on the integral length scale, suggesting that this is dictated by the length scale of the jets.

  14. Metal-air cell with ion exchange material

    DOEpatents

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2015-08-25

    Embodiments of the invention are related to anion exchange membranes used in electrochemical metal-air cells in which the membranes function as the electrolyte material, or are used in conjunction with electrolytes such as ionic liquid electrolytes.

  15. The effect of positive air ions on reproduction and growth in laboratory rats

    NASA Astrophysics Data System (ADS)

    Hinsull, S. M.; Head, E. L.

    1986-03-01

    The aim of the present investigation was to determine the growth rates, reproductive success and early mortality of laboratory rats maintained at 10,000 positive ions/ml over two generations. These findings were compared with those from animals maintained at ambient ion levels. The present work indicates that positive ions do not have any adverse effects on the reproductive capabilities or the growth of laboratory rats. In contrast it is shown that exposure to elevated levels of positive ions promotes overall growth, particularly in male rats. This action of positive ions increases with each successive generation exposed to the ions. It is suggested that the growth promoting effect of positive ions may be mediated via some modulation of the endocrine system.

  16. Dynamic airspace configuration algorithms for next generation air transportation system

    NASA Astrophysics Data System (ADS)

    Wei, Jian

    The National Airspace System (NAS) is under great pressure to safely and efficiently handle the record-high air traffic volume nowadays, and will face even greater challenge to keep pace with the steady increase of future air travel demand, since the air travel demand is projected to increase to two to three times the current level by 2025. The inefficiency of traffic flow management initiatives causes severe airspace congestion and frequent flight delays, which cost billions of economic losses every year. To address the increasingly severe airspace congestion and delays, the Next Generation Air Transportation System (NextGen) is proposed to transform the current static and rigid radar based system to a dynamic and flexible satellite based system. New operational concepts such as Dynamic Airspace Configuration (DAC) have been under development to allow more flexibility required to mitigate the demand-capacity imbalances in order to increase the throughput of the entire NAS. In this dissertation, we address the DAC problem in the en route and terminal airspace under the framework of NextGen. We develop a series of algorithms to facilitate the implementation of innovative concepts relevant with DAC in both the en route and terminal airspace. We also develop a performance evaluation framework for comprehensive benefit analyses on different aspects of future sector design algorithms. First, we complete a graph based sectorization algorithm for DAC in the en route airspace, which models the underlying air route network with a weighted graph, converts the sectorization problem into the graph partition problem, partitions the weighted graph with an iterative spectral bipartition method, and constructs the sectors from the partitioned graph. The algorithm uses a graph model to accurately capture the complex traffic patterns of the real flights, and generates sectors with high efficiency while evenly distributing the workload among the generated sectors. We further improve

  17. Carbon nanowires generated by ion irradiation of hydrocarbon ices

    NASA Astrophysics Data System (ADS)

    Puglisi, O.; Compagnini, G.; D'Urso, L.; Baratta, G. A.; Palumbo, M. E.; Strazzulla, G.

    2014-05-01

    In this paper we present the formation of carbon nanowires (polyynes and polycumulenes) in the solid state by ion irradiation of frozen hydrocarbons (C6H6 and C2H2). Irradiations have been performed using H+ ions in the 100's keV energy regime using fluences up to 5 × 1014 ions/cm2. Beyond the intrinsic significance of these results in the field of material science, this work has been motivated by the fact that ion beam irradiation of hydrocarbon ices is one of the most important process thought to happen in several extraterrestrial environments where many spectroscopic features of polyyne molecules have been identified.

  18. IMPACT OF AN OZONE GENERATOR AIR CLEANER ON STYRENE CONCENTRATIONS IN AN INDOOR AIR QUALITY RESEARCH CHAMBER

    EPA Science Inventory

    The paper gives results of an investigation of the impact of an ozone generator air cleaner on vapor-phase styrene concentrations in a full-scale indoor air quality test chamber. The time history of the concentrations of styrene and ozone is well predicted by a simulation model u...

  19. Integrated air separation plant-integrated gasification combined cycle power generator

    SciTech Connect

    Allam, R.J.; Topham, A.

    1992-01-21

    This patent describes an integrated gasification combined cycle power generation system, comprising an air separation unit wherein air is compressed, cooled, and separated into an oxygen and nitrogen enriched fractions, a gasification system for generating a fuel gas, an air compressor system for supplying compressed air for use in combusting the fuel gas, a combustion zone for effecting combustion of the compressed air and the fuel gas, and a gas turbine for effecting the generation of power from the resulting combusted gases from the combustion zone in the combined cycle power generation system. It comprises independently compressing feed air to the air separation unit to pressures of from 8 to 20 bar from the compressor system used to compress air for the combustion zone; cryogenically separating the air in the air separation unit having at least one distillation column operating at pressures of between 8 and 20 bar and producing an oxygen enriched fraction consisting of low purity oxygen, and; utilizing at least a portion of the low purity oxygen for effecting gasification of a carbon containing fuel source by partial oxidation in the gasification system and thereby generating a fuel gas stream; removing at least a portion of a nitrogen enriched fraction from the air separation unit and boosting its pressures to a pressure substantially equal to that of the fuel gas stream; and expanding at least another portion of the nitrogen enriched fraction in an expansion engine.

  20. Multistaged acceleration of ions by circularly polarized laser pulse: Monoenergetic ion beam generation

    SciTech Connect

    Zhang Xiaomei; Shen Baifei; Li Xuemei; Jin Zhangying; Wang Fengchao

    2007-07-15

    A multiple-staged ion acceleration mechanism in the interaction of a circularly polarized laser pulse with a solid target is studied by one-dimensional particle-in-cell simulation. The ions are accelerated from rest to several MeV monoenergetically at the front surface of the target. After all the plasma ions are accelerated, the acceleration process is repeated on the resulting monoenergetic ions. Under suitable conditions multiple repetitions can be realized and a high-energy quasi-monoenergetic ion beam can be obtained.

  1. Ion beam enhancement in magnetically insulated ion diodes for high-intensity pulsed ion beam generation in non-relativistic mode

    SciTech Connect

    Zhu, X. P.; Zhang, Z. C.; Lei, M. K.; Pushkarev, A. I.

    2016-01-15

    High-intensity pulsed ion beam (HIPIB) with ion current density above Child-Langmuir limit is achieved by extracting ion beam from anode plasma of ion diodes with suppressing electron flow under magnetic field insulation. It was theoretically estimated that with increasing the magnetic field, a maximal value of ion current density may reach nearly 3 times that of Child-Langmuir limit in a non-relativistic mode and close to 6 times in a highly relativistic mode. In this study, the behavior of ion beam enhancement by magnetic insulation is systematically investigated in three types of magnetically insulated ion diodes (MIDs) with passive anode, taking into account the anode plasma generation process on the anode surface. A maximal enhancement factor higher than 6 over the Child-Langmuir limit can be obtained in the non-relativistic mode with accelerating voltage of 200–300 kV. The MIDs differ in two anode plasma formation mechanisms, i.e., surface flashover of a dielectric coating on the anode and explosive emission of electrons from the anode, as well as in two insulation modes of external-magnetic field and self-magnetic field with either non-closed or closed drift of electrons in the anode-cathode (A-K) gap, respectively. Combined with ion current density measurement, energy density characterization is employed to resolve the spatial distribution of energy density before focusing for exploring the ion beam generation process. Consistent results are obtained on three types of MIDs concerning control of neutralizing electron flows for the space charge of ions where the high ion beam enhancement is determined by effective electron neutralization in the A-K gap, while the HIPIB composition of different ion species downstream from the diode may be considerably affected by the ion beam neutralization during propagation.

  2. Ion beam enhancement in magnetically insulated ion diodes for high-intensity pulsed ion beam generation in non-relativistic mode

    NASA Astrophysics Data System (ADS)

    Zhu, X. P.; Zhang, Z. C.; Pushkarev, A. I.; Lei, M. K.

    2016-01-01

    High-intensity pulsed ion beam (HIPIB) with ion current density above Child-Langmuir limit is achieved by extracting ion beam from anode plasma of ion diodes with suppressing electron flow under magnetic field insulation. It was theoretically estimated that with increasing the magnetic field, a maximal value of ion current density may reach nearly 3 times that of Child-Langmuir limit in a non-relativistic mode and close to 6 times in a highly relativistic mode. In this study, the behavior of ion beam enhancement by magnetic insulation is systematically investigated in three types of magnetically insulated ion diodes (MIDs) with passive anode, taking into account the anode plasma generation process on the anode surface. A maximal enhancement factor higher than 6 over the Child-Langmuir limit can be obtained in the non-relativistic mode with accelerating voltage of 200-300 kV. The MIDs differ in two anode plasma formation mechanisms, i.e., surface flashover of a dielectric coating on the anode and explosive emission of electrons from the anode, as well as in two insulation modes of external-magnetic field and self-magnetic field with either non-closed or closed drift of electrons in the anode-cathode (A-K) gap, respectively. Combined with ion current density measurement, energy density characterization is employed to resolve the spatial distribution of energy density before focusing for exploring the ion beam generation process. Consistent results are obtained on three types of MIDs concerning control of neutralizing electron flows for the space charge of ions where the high ion beam enhancement is determined by effective electron neutralization in the A-K gap, while the HIPIB composition of different ion species downstream from the diode may be considerably affected by the ion beam neutralization during propagation.

  3. Dynamic Characteristics of Positive Pulsed Dielectric Barrier Discharge for Ozone Generation in Air

    NASA Astrophysics Data System (ADS)

    Wei, Linsheng; Peng, Bangfa; Li, Ming; Zhang, Yafang; Hu, Zhaoji

    2016-02-01

    A comprehensive dynamic model consisting of 66 reactions and 24 species is developed to investigate the dynamic characteristics of ozone generation by positive pulsed dielectric barrier discharge (DBD) using parallel-plate reactor in air. The electron energy conservation equation is coupled to the electron continuity equation, the heavy species continuity equation, and Poisson's equation for a better description. The reliability of the model is experimentally confirmed. The model can be used to predict the temporal and spatial evolution of species, as well as streamer propagation. The simulation results show that electron density increases nearly exponentially in the direction to the anode at the electron avalanche. Streamer propagation velocity is about 5.26 × 104 m/s from anode to cathode in the simulated condition. The primary positive ion, negative ion, and excited species are O2+, O3- and O2(1Δg) in pulsed DBD in air, respectively. N2O has the largest density among nitrogen oxides. e and N2+ densities in the streamer head increase gradually to maximum values with the development of the streamer. Meanwhile, the O2+, O, O3, N2(A3Σ) and N2O densities reach maximum values in the vicinity of the anode. supported by National Natural Science Foundation of China (Nos. 51366012 and 11105067), Jiangxi Province Young Scientists (Jinggang Star) Cultivation Plan of China (No. 20133BCB23008), Natural Science Foundation of Jiangxi, China (No. 20151BAB206047) and Jiangxi Province Higher School Science and Technology Landing Plan of China (No. KJLD-14015)

  4. Effect of plasma temperature on electrostatic shock generation and ion acceleration by laser

    SciTech Connect

    Zhang Xiaomei; Shen Baifei; Yu, M. Y.; Li Xuemei; Jin Zhangying; Wang Fengchao; Wen Meng

    2007-11-15

    The effect of plasma temperature on electrostatic shock generated by a circularly polarized laser pulse in overdense plasma is studied by particle-in-cell simulation. Ion reflection and transmission in the collisionless electrostatic shock (CES) are investigated analytically. As the initial ion temperature is varied, a distinct transition from the laser-driven piston scenario with all ions being reflected to the CES scenario with partial ion reflection is found. The results show that at low but finite temperatures the ions are much more accelerated than if they were cold.

  5. Generation of quasi-monoenergetic carbon ions accelerated parallel to the plane of a sandwich target

    SciTech Connect

    Wang, J. W.; Murakami, M.; Weng, S. M.; Xu, H.; Ju, J. J.; Luan, S. X.; Yu, W.

    2014-12-15

    A new ion acceleration scheme, namely, target parallel Coulomb acceleration, is proposed in which a carbon plate sandwiched between gold layers is irradiated with intense linearly polarized laser pulses. The high electrostatic field generated by the gold ions efficiently accelerates the embedded carbon ions parallel to the plane of the target. The ion beam is found to be collimated by the concave-shaped Coulomb potential. As a result, a quasi-monoenergetic and collimated C{sup 6+}-ion beam with an energy exceeding 10 MeV/nucleon is produced at a laser intensity of 5 × 10{sup 19} W/cm{sup 2}.

  6. Enhancement of the deposition of ultrafine secondary organic aerosols by the negative air ion and the effect of relative humidity.

    PubMed

    Yu, Kuo-Pin

    2012-11-01

    Deposition is an important process for the removal of aerosol particles. Negative air ion (NAI) generators can charge the ultrafine airborne particles and enhance their deposition rate. However, many NAI generators may also emit ozone and increase the concentration of particles in the presence of biogenic volatile organic compounds owing to the secondary organic aerosol (SOA) production. To validate the effectiveness of NAI generator the authors investigated the enhancement effect of an NAI generator on the deposition of the ultrafine SOAs generated from the ozonolysis of d-limonene in a test chamber under controlled ventilation rate and relative humidity (RH). The experimental results demonstrated that compared with other effects, including the gravity, particle eddy diffusion, and the Brownian diffusion, the effect of NAIs is the most dominate one on the deposition of SOA particles onto the wall surface in the near-wall region (<1 cm away from the wall). According to these experiments, the tested NAI generator could efficiently enhance the deposition rate by an enhancement factor ranging from 8.17 +/- 0.38 to 25.3 +/- 1.1, with a low ozone production rate. This NAI generator had better performance on the deposition of the SOAs with smaller particle sizes and it performed even better under higher RH. The enhancement effect of the NAI generator was related to its high NAI production and electric field strength.

  7. Foam Generation and Air Entrainment Near a Free Surface

    DTIC Science & Technology

    1987-09-30

    plunging jets and by the action of turbulent eddies in water flowing over spillways has been discussed by several authors. Data for the entrained air flow...r = mean jet radius. 1 They determined the size of the region in the liquid which was affected by air entrainment and mea- sured the...Spilling Breaker," J. Fluid Mech., Vol. 63, 1. E.J. McKeogh and D.A. Ervine, 1981, " Air Entrainment Rate and Diffusion Pattern of Plunging Liquid

  8. Use of ozone generating devices to improve indoor air quality.

    PubMed

    Boeniger, M F

    1995-06-01

    Room ozonization has been in widespread use to "freshen" indoor air for more than 100 years. This use is sometimes promoted with the claim that ozone can oxidize airborne gases, and even particulates, to simple carbon dioxide and water vapor. Aside from whether ozone can improve indoor air quality, the potentially deleterious consequences to public health of overexposure to ozone are of concern. The literature on both allegations is reviewed. It indicates that ozone is not a practical and effective means of improving indoor air quality, especially in light of its potentially serious risk to health.

  9. Next Generation JPL Ultra-Stable Trapped Ion Atomic Clocks

    NASA Technical Reports Server (NTRS)

    Burt, Eric; Tucker, Blake; Larsen, Kameron; Hamell, Robert; Tjoelker, Robert

    2013-01-01

    Over the past decade, trapped ion atomic clock development at the Jet Propulsion Laboratory (JPL) has focused on two directions: 1) new atomic clock technology for space flight applications that require strict adherence to size, weight, and power requirements, and 2) ultra-stable atomic clocks, usually for terrestrial applications emphasizing ultimate performance. In this paper we present a new ultra-stable trapped ion clock designed, built, and tested in the second category. The first new standard, L10, will be delivered to the Naval Research Laboratory for use in characterizing DoD space clocks.

  10. State-selective generation of molecular ions via Rydberg states

    NASA Astrophysics Data System (ADS)

    Grimes, David; Zhou, Yan; Barnum, Timothy; Coy, Stephen; Kay, Jeffrey; Field, Robert

    2014-05-01

    Autoionizing Rydberg states of molecules in the range n = 30-50 have the potential to enable the production of single quantum state selected ensembles of molecular ions, which have uses from spectroscopy to high precision measurements of fundamental constants. Multichannel Quantum Defect Theory (MQDT) fully describes the Rydberg states of molecules and the dynamics of autoionization. We have used our full MQDT description of CaF to determine optimal autoionizing resonances for producing a variety of selected rotation-vibration states of the ion. Progress towards experimental demonstrations in BaF will also be discussed. This work was supported by the NSF and an NDSEG Fellowship

  11. The third generation superconducting 28 GHz electron cyclotron resonance ion source VENUS (invited)

    SciTech Connect

    Lyneis, C.; Leitner, D.; Leitner, M.; Taylor, C.; Abbott, S.

    2010-02-15

    VENUS is a third generation electron cyclotron resonance (ECR) ion source, which incorporates a high field superconducting NbTi magnet structure, a 28 GHz gryotron microwave source and a state of the art closed cycle cryosystem. During the decade from initial concept to regular operation, it has demonstrated both the feasibility and the performance levels of this new generation of ECR ion sources and required innovation on magnet construction, plasma chamber design, and beam transport. In this paper, the development, performance, and major innovations are described as well as a look to the potential to construct a fourth generation ECR ion source.

  12. Generation of reactive oxygen species by interaction between antioxidants used as food additive and metal ions.

    PubMed

    Iwasaki, Yusuke; Oda, Momoko; Tsukuda, Yuri; Nagamori, Yuki; Nakazawa, Hiroyuki; Ito, Rie; Saito, Koichi

    2014-01-01

    Food additives, such as preservatives, sweeteners, coloring agents, and flavoring agents, are widely used in food manufacturing. However, their combined effects on the human body are not known. The purpose of this study was to examine whether combinations of antioxidants and metal ions generate reactive oxygen species (ROS) under in vitro conditions using electron spin resonance (ESR). Among the metal ions examined, only iron and copper generated ROS in the presence of antioxidants. Moreover, certain phenolic antioxidants having pro-oxidant activity induced DNA oxidation and degradation via the generation of high levels of ROS in the presence of copper ion, resulting in complete degradation of DNA in vitro.

  13. What is in my air? Feds facilitating citizen science in the EPA Next Generation Air Monitoring Program

    NASA Astrophysics Data System (ADS)

    French, R. A.; Preuss, P.

    2013-12-01

    Recent advances in the development of small-scale and inexpensive air pollutant sensors, coupled with the ubiquitous use of wireless and mobile technology, will transform the field of air quality monitoring. For the first time, the general public may purchase air monitors, which can measure their personal exposure to NOx, Ozone, black carbon, and VOCs for a few hundred dollars. Concerned citizens may now gather the data for themselves to answer questions such as, ';what am I breathing?' and ';is my air clean?' The research and policy community will have access to real-time air quality data collected at the local and regional scale, making targeted protection of environmental health possible. With these benefits come many questions from citizen scientists, policymakers, and researchers. These include, what is the quality of the data? How will the public interpret data from the air sensors and are there guidelines to interpret that data? How do you know if the air sensor is trustworthy? Recognizing that this revolution in air quality monitoring will proceed regardless of the involvement of the government, the Innovation Team at the EPA Office of Research and Development, in partnership with the Office of Enforcement and Compliance Assistance and the Office of Air and Radiation, seized the opportunity to ensure that users of next generation air sensors can realize the full potential benefits of these innovative technologies. These efforts include releasing an EPA Draft Roadmap for Next Generation Air Monitoring, testing air sensors under laboratory and field conditions, field demonstrations of new air sensor technology for the public, and building a community of air sensor developers, researchers, local, state and federal officials, and community members through workshops and a website. This presentation will review the status of those programs, highlighting the particular programs of interest to citizen scientists. The Next Generation Air Monitoring program may serve

  14. Observation of ions and particles near busy roads using a neutral cluster and air ion spectrometer (NAIS)

    NASA Astrophysics Data System (ADS)

    Jayaratne, E. R.; Ling, X.; Morawska, L.

    2014-02-01

    Motor vehicles emit large quantities of ions in the form of both charged particles and molecular cluster ions. While, the health effects of inhalation of charged particles is largely unexplored, the concentrations near busy roads and the distance to which these particles and ions are carried have important implications for the exposure of the large percentage of the population that lives close to such roadways. We measured ion concentrations using a neutral cluster and air ion spectrometer (NAIS) near seven busy roads carrying on the average approximately 7000 vehicles h-1 including about 15% heavy duty diesel vehicles. In this study, charged particle concentrations were measured as a function of downwind distance from the road for the first time. We show that, at a moderate wind speed of 2.0 m s-1, mean charged particle concentrations at the kerb were of the order of 2 × 104 cm-3 and, more importantly, decreased as d-0.6 where d is the distance from the road. While cluster ions were rapidly depleted by attachment to particles and were not carried to more than about 20 m from the road, elevated concentrations of charged particle were detected up to at least 400 m from the road. Most of the charge on the downwind side was carried on the larger particles, with no excess charge on particles smaller than about 10 nm. At 30 nm, particles carried more than double the charge they would normally carry in equilibrium. There are very few measurements of ions near road traffic and this is the first study of the spatial dispersion of charged particles from a road.

  15. An Inexpensive Autosampler to Maximize Throughput for an Ion Source that Samples Surfaces in Open Air

    EPA Science Inventory

    An autosampler was built to pull cotton swab heads mounted into a 3-foot long, square Al rod in ambient air through the He ionizing beam of a Direct Analysis in Real Time (DART) ion source interfaced to an orthogonal acceleration, time-of-flight mass spectrometer. The cost of th...

  16. Toward the next generation of air quality monitoring indicators

    NASA Astrophysics Data System (ADS)

    Hsu, Angel; Reuben, Aaron; Shindell, Drew; de Sherbinin, Alex; Levy, Marc

    2013-12-01

    This paper introduces an initiative to bridge the state of scientific knowledge on air pollution with the needs of policymakers and stakeholders to design the “next generation” of air quality indicators. As a first step this initiative assesses current monitoring and modeling associated with a number of important pollutants with an eye toward identifying knowledge gaps and scientific needs that are a barrier to reducing air pollution impacts on human and ecosystem health across the globe. Four outdoor air pollutants were considered - particulate matter, ozone, mercury, and Persistent Organic Pollutants (POPs) - because of their clear adverse impacts on human and ecosystem health and because of the availability of baseline data for assessment for each. While other papers appearing in this issue will address each pollutant separately, this paper serves as a summary of the initiative and presents recommendations for needed investments to provide improved measurement, monitoring, and modeling data for policy-relevant indicators. The ultimate goal of this effort is to enable enhanced public policy responses to air pollution by linking improved data and measurement methods to decision-making through the development of indicators that can allow policymakers to better understand the impacts of air pollution and, along with source attribution based on modeling and measurements, facilitate improved policies to solve it. The development of indicators represents a crucial next step in this process.

  17. Harmonic generation of ion waves due to Brillouin backscattering

    SciTech Connect

    Estabrook, K.; Kruer, W.L.; Haines, M.G.

    1985-05-22

    We report results of simulations of stimulated Brillouin backscatter in which we see the second spatial harmonic of the ion density fluctuation and compare with linear, fluid theory. We also describe examples of the competition between Raman and Brillouin backscatter. 21 refs., 3 figs.

  18. Influence of air ions on brain activity induced by electrical stimulation in the rat

    NASA Astrophysics Data System (ADS)

    Olivereau, J. M.; Lambert, J. F.; Truong-Ngoc, A.

    1981-03-01

    The brain induced activity was studied in 18 rats wearing chronically skull implanted electrodes. The stimulating factor was various electrical stimulations of the mesencephalic reticular activating formation, given during the slow wave state of sleep. The results of 300 stimulations were measured by amplitude and frequency changes in the EEG simultaneously recorded. Animals previously exposed to positive air ions (3 weeks 80,000 ions/ml) exhibited lowered excitability of the reticulocortical system. Significantly higher stimulations were necessary to induce arousal. Negative air ions induced more intricate effects: brain excitability was lowered when tested with weak stimulations, but normal when evaluated with medium high level stimilations. Sleep seems first more stable but as stimulation increases, arousal is soon as effective as in controls. These results are in agreement with others findings in behavioral fields and partly explains them.

  19. Pulsed, Inductively Generated, Streaming Plasma Ion Source for Heavy Ion Fusion Linacs

    SciTech Connect

    Steven C. Glidden; Howard D Sanders; John B. Greenly; Daniel L. Dongwoo

    2006-04-28

    This report describes a compact, high current density, pulsed ion source, based on electrodeless, inductively driven gas breakdown, developed to meet the requirements on normalized emittance, current density, uniformity and pulse duration for an ion injector in a heavy-ion fusion driver. The plasma source produces >10 μs pulse of Argon plasma with ion current densities >100 mA/cm2 at 30 cm from the source and with strongly axially directed ion energy of about 80 eV, and sub-eV transverse temperature. The source has good reproducibility and spatial uniformity. Control of the current density during the pulse has been demonstrated with a novel modulator coil method which allows attenuation of the ion current density without significantly affecting the beam quality. This project was carried out in two phases. Phase 1 used source configurations adapted from light ion sources to demonstrate the feasibility of the concept. In Phase 2 the performance of the source was enhanced and quantified in greater detail, a modulator for controlling the pulse shape was developed, and experiments were conducted with the ions accelerated to >40 kV.

  20. Charge dependent condensation of macro-ions at air-water interfaces

    NASA Astrophysics Data System (ADS)

    Bera, Mrinal; Antonio, Mark

    2015-03-01

    Ordering of ions at and near air-water interfaces is a century old problem for researchers and has implications on a host of physical, chemical and biological processes. The dynamic nature of water surface and the surface fluctuations created by thermally excited capillary waves have always limited measurement of near surface ionic-distributions. We demonstrate that this limitation can be overcome by using macro-ions of sizes larger than the capillary wave roughness ~3Å. Our attempts to measure distributions of inorganic macro-ions in the form of Keggin heteropolyanions (HPAs) of sizes ~10Å have unraveled novel charge-dependent condensation of macro-ions beneath air-water interfaces. Our results demonstrate that HPAs with -3 charges condense readily beneath air-water interfaces. This is in contrast to the absence of surface preference for HPAs with -4 charges. The similarity of HPA-HPA separations near air-water interfaces and in bulk crystal structures suggests the presence of the planar Zundel ions (H5O2+), which interact with HPAs and the water surface to facilitate the charge dependent condensation beneath the air-water interfaces.This work and the use of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility at Argonne National Laboratory, is based upon work supported by the U.S. DOE, Office of Science, Office of Basic Energy Science, Division of Chemical Sciences, Biosciences and Geosciences, under contract No DE-AC02-06CH11357.

  1. Ionic wind generation by a wire-cylinder-plate corona discharge in air at atmospheric pressure

    SciTech Connect

    Colas, Dorian F.; Ferret, Antoine; Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-11-15

    A wire-cylinder-plate electrode configuration is presented to generate ionic wind with a dc corona discharge in air at atmospheric pressure. The objective of the work is to maximize the power supplied to the flow in order to increase acceleration while avoiding breakdown. Thus, the proposed experimental setup addresses the problem of decoupling the mechanism of ion generation from that of ion acceleration. Using a wire-plate configuration as a reference, we have focused on improving the topography of the electric field to (1) separate the ionization and acceleration zones in space, and (2) guide the trajectory of charged particles as parallel to the median axis as possible. In the proposed wire-cylinder-plate setup, a dc corona discharge is generated in the space between a wire and two cylinders. The ions produced by the corona then drift past the cylinders and into a channel between two plates, where they undergo acceleration. To maximize the ionic wind it is found that the geometric configuration must be as compact as possible and that the voltage applied must be right below breakdown. Experimentally, the optimized wire-plate reference setup provides a maximum flow velocity of 8 m s{sup -1}, a flow rate per unit electrode length of 0.034 m{sup 2} s{sup -1}, and a thrust per unit electrode length of 0.24 N m{sup -1}. The wire-cylinder-plate configuration provides a maximum flow velocity of 10 m s{sup -1}, a flow rate per unit electrode length of 0.041 m{sup 2} s{sup -1}, and a thrust per unit electrode length of 0.35 N m{sup -1}. This 46% increase in thrust is obtained by increasing the electric power per unit electrode length by only 16% (from 175 to 210 W m{sup -1}), which confirms the gain in efficiency obtained with the decoupled system. In comparison with a simple wire-wire corona configuration, the wire-cylinder-plate configuration increases the ionic wind velocity by up to a factor of 3, and the thrust by an order of magnitude.

  2. Effect of vehicle type on the performance of second generation air bags for child occupants.

    PubMed

    Arbogast, Kristy B; Durbin, Dennis R; Kallan, Michael J; Winston, Flaura K

    2003-01-01

    Passenger air bags experienced considerable design modification in the late 1990s, principally to mitigate risks to child passengers. This study utilized Data from the Partners for Child Passenger Safety study, a large-scale child-focused crash surveillance system, to examine the effect of vehicle type on the differential performance of first and second generation air bags on injuries to restrained children in frontal impact crashes. Our results show that the benefit of second-generation air bags was seen in passenger cars - those children exposed to second-generation air bags were half as likely to sustain a serious injury - and minivans. However, in SUVs the data suggest no reduction in injury risk with the new designs. This field data provides crucial real-world experience to the automotive industry as they work towards the next generation of air bag designs.

  3. Electron beam ion sources for use in second generation synchrotrons for medical particle therapy.

    PubMed

    Zschornack, G; Ritter, E; Schmidt, M; Schwan, A

    2014-02-01

    Cyclotrons and first generation synchrotrons are the commonly applied accelerators in medical particle therapy nowadays. Next generation accelerators such as Rapid Cycling Medical Synchrotrons (RCMS), direct drive accelerators, or dielectric wall accelerators have the potential to improve the existing accelerator techniques in this field. Innovative accelerator concepts for medical particle therapy can benefit from ion sources which meet their special requirements. In the present paper we report on measurements with a superconducting Electron Beam Ion Source, the Dresden EBIS-SC, under the aspect of application in combination with RCMS as a well proven technology. The measurements indicate that this ion source can offer significant advantages for medical particle therapy. We show that a superconducting EBIS can deliver ion pulses of medically relevant ions such as protons, C(4 +) and C(6 +) ions with intensities and frequencies required for RCMS [S. Peggs and T. Satogata, "A survey of Hadron therapy accelerator technology," in Proceedings of PAC07, BNL-79826- 2008-CP, Albuquerque, New Mexico, USA, 2007; A. Garonna, U. Amaldi et al., "Cyclinac medical accelerators using pulsed C(6 +)/H2(+) ion sources," in Proceedings of EBIST 2010, Stockholm, Sweden, July 2010]. Ion extraction spectra as well as individual ion pulses have been measured. For example, we report on the generation of proton pulses with up to 3 × 10(9) protons per pulse and with frequencies of up to 1000 Hz at electron beam currents of 600 mA.

  4. The quantification of carbon dioxide in humid air and exhaled breath by selected ion flow tube mass spectrometry.

    PubMed

    Smith, David; Pysanenko, Andriy; Spanel, Patrik

    2009-05-01

    The reactions of carbon dioxide, CO(2), with the precursor ions used for selected ion flow tube mass spectrometry, SIFT-MS, analyses, viz. H(3)O(+), NO(+) and O(2) (+), are so slow that the presence of CO(2) in exhaled breath has, until recently, not had to be accounted for in SIFT-MS analyses of breath. This has, however, to be accounted for in the analysis of acetaldehyde in breath, because an overlap occurs of the monohydrate of protonated acetaldehyde and the weakly bound adduct ion, H(3)O(+)CO(2), formed by the slow association reaction of the precursor ion H(3)O(+) with CO(2) molecules. The understanding of the kinetics of formation and the loss rates of the relevant ions gained from experimentation using the new generation of more sensitive SIFT-MS instruments now allows accurate quantification of CO(2) in breath using the level of the H(3)O(+)CO(2) adduct ion. However, this is complicated by the rapid reaction of H(3)O(+)CO(2) with water vapour molecules, H(2)O, that are in abundance in exhaled breath. Thus, a study has been carried out of the formation of this adduct ion by the slow three-body association reaction of H(3)O(+) with CO(2) and its rapid loss in the two-body reaction with H(2)O molecules. It is seen that the signal level of the H(3)O(+)CO(2) adduct ion is sensitively dependent on the humidity (H(2)O concentration) of the sample to be analysed and a functional form of this dependence has been obtained. This has resulted in an appropriate extension of the SIFT-MS software and kinetics library that allows accurate measurement of CO(2) levels in air samples, ranging from very low percentage levels (0.03% typical of tropospheric air) to the 6% level that is about the upper limit in exhaled breath. Thus, the level of CO(2) can be traced through single time exhalation cycles along with that of water vapour, also close to the 6% level, and of trace gas metabolites that are present at only a few parts-per-billion. This has added a further dimension to

  5. Ion Beam Generation from an Electrolyte Solution Containing Polyatomic Cations and Anions for Secondary Ion Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Fujiwara, Yukio; Watanabe, Kouji; Saito, Naoaki; Nonaka, Hidehiko; Suzuki, Atsushi; Nakanaga, Taisuke; Fujimoto, Toshiyuki; Kurokawa, Akira; Ichimura, Shingo; Tomita, Mitsuhiro

    2009-12-01

    A solution-type ion beam source was fabricated to utilize polyatomic anions as well as polyatomic cations that are stable in solutions. The ion source consists of an electrospray section at atmospheric pressure and a vacuum section with a differential pumping system. To demonstrate the beam generation of cations or anions, ethanol solution containing a room-temperature molten salt (i.e., an ionic liquid) was tested. The ionic liquid, N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide, consists of a polyatomic cation, [C8H20ON]+, and a polyatomic anion, [C2F6NO4S2]-. Ions produced at atmospheric pressure were passed through an aperture into a vacuum chamber and then transported to a target. The effects of the aperture dimensions were investigated in the range from 50 to 200 µm in diameter and 0.25 to 1 mm in thickness. The ratio of current passing through the aperture into the vacuum chamber to the total electrosprayed current was on the order of 10-3 to 10-5. The ratio increased with increasing aperture diameter. A reduction in the aperture thickness also improved the ratio. Beam current increased with applied voltage in both positive-ion and negative-ion modes. It was demonstrated that stable negative-ion beams as well as positive-ion beams on the order of pA were produced.

  6. Aqueous cathode for next-generation alkali-ion batteries.

    PubMed

    Lu, Yuhao; Goodenough, John B; Kim, Youngsik

    2011-04-20

    The lithium-ion batteries that ushered in the wireless revolution rely on electrode strategies that are being stretched to power electric vehicles. Low-cost, safe electrical-energy storage that enables better use of alternative energy sources (e.g., wind, solar, and nuclear) requires an alternative strategy. We report a demonstration of the feasibility of a battery having a thin, solid alkali-ion electrolyte separating a water-soluble redox couple as the cathode and lithium or sodium in a nonaqueous electrolyte as the anode. The cell operates without a catalyst and has high storage efficiency. The possibility of a flow-through mode for the cathode allows flexibility of the cell design for safe, large-capacity electrical-energy storage at an acceptable cost.

  7. The ASAC Air Carrier Investment Model (Third Generation)

    NASA Technical Reports Server (NTRS)

    Wingrove, Earl R., III; Gaier, Eric M.; Santmire, Tara E.

    1998-01-01

    To meet its objective of assisting the U.S. aviation industry with the technological challenges of the future, NASA must identify research areas that have the greatest potential for improving the operation of the air transportation system. To accomplish this, NASA is building an Aviation System Analysis Capability (ASAC). The ASAC differs from previous NASA modeling efforts in that the economic behavior of buyers and sellers in the air transportation and aviation industries is central to its conception. To link the economics of flight with the technology of flight, ASAC requires a parametrically based model with extensions that link airline operations and investments in aircraft with aircraft characteristics. This model also must provide a mechanism for incorporating air travel demand and profitability factors into the airlines' investment decisions. Finally, the model must be flexible and capable of being incorporated into a wide-ranging suite of economic and technical models flat are envisioned for ASAC.

  8. The effect of negative air ionization on the growth of four generations of laboratory rats

    NASA Astrophysics Data System (ADS)

    Hinsull, S. M.; Bellamy, D.; Head, E. L.

    1984-06-01

    Initial work indicated an inhibition of pre-weaning growth in the first generation of rats born and raised at high negative ion levels. This effect, however, was not carried through to the successive generations. Negative ionization had little apparent effect on post-weaning growth throughout the four generations studied.

  9. Enantiospecific bromonium ion generation and intramolecular capture: a model system for asymmetric bromonium ion-induced polyene cyclisations.

    PubMed

    Braddock, D Christopher; Marklew, Jared S; Thomas, Alexander J F

    2011-08-28

    Scalemic bromonium ions generated enantiospecifically by the action of catalytic triflic acid on scalemic regioisomeric bromohydrin derivatives are trapped intramolecularly, enantiospecifically and regioselectively to give bicyclic brominated carbocycles in excellent yield and high enantiomeric excess. This enantiospecific pathway is not significantly perturbed by the addition of a trisubstituted alkene.

  10. Development and Application of a Next Generation Air Sensor Network for the Hong Kong Marathon 2015 Air Quality Monitoring

    PubMed Central

    Sun, Li; Wong, Ka Chun; Wei, Peng; Ye, Sheng; Huang, Hao; Yang, Fenhuan; Westerdahl, Dane; Louie, Peter K.K.; Luk, Connie W.Y.; Ning, Zhi

    2016-01-01

    This study presents the development and evaluation of a next generation air monitoring system with both laboratory and field tests. A multi-parameter algorithm was used to correct for the impact of environmental conditions on the electrochemical sensors for carbon monoxide (CO) and nitrogen dioxide (NO2) pollutants. The field evaluation in an urban roadside environment in comparison to designated monitors showed good agreement with measurement error within 5% of the pollutant concentrations. Multiple sets of the developed system were then deployed in the Hong Kong Marathon 2015 forming a sensor-based network along the marathon route. Real-time air pollution concentration data were wirelessly transmitted and the Air Quality Health Index (AQHI) for the Green Marathon was calculated, which were broadcast to the public on an hourly basis. The route-specific sensor network showed somewhat different pollutant patterns than routine air monitoring, indicating the immediate impact of traffic control during the marathon on the roadside air quality. The study is one of the first applications of a next generation sensor network in international sport events, and it demonstrated the usefulness of the emerging sensor-based air monitoring technology in rapid network deployment to supplement existing air monitoring. PMID:26861336

  11. Development and Application of a Next Generation Air Sensor Network for the Hong Kong Marathon 2015 Air Quality Monitoring.

    PubMed

    Sun, Li; Wong, Ka Chun; Wei, Peng; Ye, Sheng; Huang, Hao; Yang, Fenhuan; Westerdahl, Dane; Louie, Peter K K; Luk, Connie W Y; Ning, Zhi

    2016-02-05

    This study presents the development and evaluation of a next generation air monitoring system with both laboratory and field tests. A multi-parameter algorithm was used to correct for the impact of environmental conditions on the electrochemical sensors for carbon monoxide (CO) and nitrogen dioxide (NO2) pollutants. The field evaluation in an urban roadside environment in comparison to designated monitors showed good agreement with measurement error within 5% of the pollutant concentrations. Multiple sets of the developed system were then deployed in the Hong Kong Marathon 2015 forming a sensor-based network along the marathon route. Real-time air pollution concentration data were wirelessly transmitted and the Air Quality Health Index (AQHI) for the Green Marathon was calculated, which were broadcast to the public on an hourly basis. The route-specific sensor network showed somewhat different pollutant patterns than routine air monitoring, indicating the immediate impact of traffic control during the marathon on the roadside air quality. The study is one of the first applications of a next generation sensor network in international sport events, and it demonstrated the usefulness of the emerging sensor-based air monitoring technology in rapid network deployment to supplement existing air monitoring.

  12. Dithionite/air direct ion liquid fuel cell

    NASA Astrophysics Data System (ADS)

    Noack, Jens; Tübke, Jens; Pinkwart, Karsten

    2015-07-01

    The feasibility of an alkaline S2O42-/air-fuel cell was evaluated at room temperature, using a cell with an anion exchange membrane and a platinum oxygen reduction reaction catalyst. The tests performed were open circuit voltage analysis, linear sweep voltammetry, discharge analysis and electrochemical impedance spectroscopy (EIS) with registration of anode half-cell potential. With 0.85 M Na2S2O4 in 2 M KOH, the cell achieved a maximum power density of 2 mW cm-2, and the open circuit cell voltage was about 0.9 V. In a potentiostatic discharging at 0.2 V cell voltage, an energy efficiency of 12.3% was achieved at an energy density of 8.6 Wh L-1. The low power density was mainly due to the low reaction kinetics of dithionite oxidation at graphite electrodes. The low energy efficiency was mainly caused by a low cathode potential, which probably resulted from mixed potential formation and the low anode kinetics.

  13. High-velocity, multistage, nozzled, ion driven wind generator and method of operation of the same adaptable to mesoscale realization

    NASA Technical Reports Server (NTRS)

    Dunn-Rankin, Derek (Inventor); Rickard, Matthew J. A. (Inventor)

    2011-01-01

    Gas flows of modest velocities are generated when an organized ion flux in an electric field initiates an ion-driven wind of neutral molecules. When a needle in ambient air is electrically charged to a potential sufficient to produce a corona discharge near its tip, such a gas flow can be utilized downstream of a ring-shaped or other permeable earthed electrode. In view of the potential practical applications of such devices, as they represent blowers with no moving parts, a methodology for increasing their flow velocities includes exploitation of the divergence of electric field lines, avoidance of regions of high curvature on the second electrode, control of atmospheric humidity, and the use of linear arrays of stages, terminating in a converging nozzle. The design becomes particularly advantageous when implemented in mesoscale domains.

  14. Effects of energetic heavy ions on electromagnetic ion cyclotron wave generation in the plasmapause region

    NASA Technical Reports Server (NTRS)

    Kozyra, J. U.; Cravens, T. E.; Nagy, A. F.; Fontheim, E. G.; Ong, R. S. B.

    1984-01-01

    An expression for electromagnetic ion cyclotron convective growth rates is derived. The derivation of the dispersion relation and convective growth rates in the presence of a multicomponent energetic and cold plasma is presented. The effects that multiple heavy ions in the ring current and cold plasma produce in the growth and propagation characteristics of ion cyclotron waves are explored. Results of growth rate calculations using parameters consistent with conditions in the plasmapause region during the early recovery phase of geomagnetic storms are presented and compared with ground-based and satellite observations of waves in this region. The geophysical implications of the results are discussed.

  15. Selection of targets and ion sources for RIB generation at the Holifield Radioactive Ion Beam Facility

    SciTech Connect

    Alton, G.D.

    1995-12-31

    In this report, the authors describe the performance characteristics for a selected number of target ion sources that will be employed for initial use at the Holifield Radioactive Ion Beam Facility (HRIBF) as well as prototype ion sources that show promise for future use for RIB applications. A brief review of present efforts to select target materials and to design composite target matrix/heat-sink systems that simultaneously incorporate the short diffusion lengths, high permeabilities, and controllable temperatures required to effect fast and efficient diffusion release of the short-lived species is also given.

  16. Simulating Negative Pickup Ions and Ion Cyclotron Wave Generation at Europa (Invited)

    NASA Astrophysics Data System (ADS)

    Desai, R. T.; Cowee, M.; Gary, S. P.; Wei, H.; Coates, A. J.; Kataria, D. O.; Fu, X.

    2015-12-01

    The mass loading of space environments through the ionisation of planetary atmospheres is a fundamental process governing the plasma interactions and long term evolution of celestial bodies across the solar system. Regions containing significant pickup ion populations have been observed to exhibit a rich variety of electromagnetic plasma wave phenomena, the characteristics and properties of which can be used to infer the ion species present, their spatial and temporal distributions, and the global ionisation rates of the neutral material. In this study we present hybrid (kinetic ion, massless fluid electron) simulations of ion pickup and Ion Cyclotron (IC) waves observed in the Jovian magnetosphere and draw comparisons to sub-alfvénic pickup observed by Cassini in the Saturnian system, and also to supra-alfvénic pickup at planetary bodies immersed directly in the solar wind. At Jupiter, Europa has been identified as the secondary mass loader in the magnetosphere, orbiting within a neutral gas torus at ~9.38 Rj. Near Europa, Galileo magnetometer observations displayed bursty IC wave characteristics at the gyrofrequency of a number of species including SO2, K, Cl, O2, and Na, suggesting a complex mass loading environment. A particular deduction from the dataset was the presence of both positively and negatively charged pickup ions, inferred from the left and right hand polarisations of the transverse waves. Using hybrid simulations for both positively and negatively charged Cl pickup ions we are able to self-consistently reproduce the growth of both right and left hand near-circularly polarised waves in agreement with linear theory and, using the observed wave amplitudes, estimate Cl pickup ion densities at Europa.

  17. Toward the next generation of air quality monitoring: Particulate Matter

    NASA Astrophysics Data System (ADS)

    Engel-Cox, Jill; Kim Oanh, Nguyen Thi; van Donkelaar, Aaron; Martin, Randall V.; Zell, Erica

    2013-12-01

    Fine particulate matter is one of the key global pollutants affecting human health. Satellite and ground-based monitoring technologies as well as chemical transport models have advanced significantly in the past 50 years, enabling improved understanding of the sources of fine particles, their chemical composition, and their effect on human and environmental health. The ability of air pollution to travel across country and geographic boundaries makes particulate matter a global problem. However, the variability in monitoring technologies and programs and poor data availability make global comparison difficult. This paper summarizes fine particle monitoring, models that integrate ground-based and satellite-based data, and communications, then recommends steps for policymakers and scientists to take to expand and improve local and global indicators of particulate matter air pollution. One of the key set of recommendations to improving global indicators is to improve data collection by basing particulate matter monitoring design and stakeholder communications on the individual country, its priorities, and its level of development, while at the same time creating global data standards for inter-country comparisons. When there are good national networks that produce consistent quality data that is shared openly, they serve as the foundation for better global understanding through data analysis, modeling, health impact studies, and communication. Additionally, new technologies and systems should be developed to expand personal air quality monitoring and participation of non-specialists in crowd-sourced data collections. Finally, support to the development and improvement of global multi-pollutant indicators of the health and economic effects of air pollution is essential to addressing improvement of air quality around the world.

  18. Electric power generating plant having direct coupled steam and compressed air cycles

    DOEpatents

    Drost, Monte K.

    1982-01-01

    An electric power generating plant is provided with a Compressed Air Energy Storage (CAES) system which is directly coupled to the steam cycle of the generating plant. The CAES system is charged by the steam boiler during off peak hours, and drives a separate generator during peak load hours. The steam boiler load is thereby levelized throughout an operating day.

  19. Electric power generating plant having direct-coupled steam and compressed-air cycles

    DOEpatents

    Drost, M.K.

    1981-01-07

    An electric power generating plant is provided with a Compressed Air Energy Storage (CAES) system which is directly coupled to the steam cycle of the generating plant. The CAES system is charged by the steam boiler during off peak hours, and drives a separate generator during peak load hours. The steam boiler load is thereby levelized throughout an operating day.

  20. Compact 180-kV Marx generator triggered in atmospheric air by femtosecond laser filaments

    NASA Astrophysics Data System (ADS)

    Arantchouk, L.; Point, G.; Brelet, Y.; Larour, J.; Carbonnel, J.; André, Y.-B.; Mysyrowicz, A.; Houard, A.

    2014-03-01

    We developed a compact Marx generator triggered in atmospheric air by a single femtosecond laser beam undergoing filamentation. Voltage pulses of 180 kV could be generated with a subnanosecond jitter. The same laser beam was also used to initiate simultaneously guided discharges up to 21 cm long at the output of the generator.

  1. Compact 180-kV Marx generator triggered in atmospheric air by femtosecond laser filaments

    SciTech Connect

    Arantchouk, L. Larour, J.; Point, G.; Brelet, Y.; Carbonnel, J.; André, Y.-B.; Mysyrowicz, A.; Houard, A.

    2014-03-10

    We developed a compact Marx generator triggered in atmospheric air by a single femtosecond laser beam undergoing filamentation. Voltage pulses of 180 kV could be generated with a subnanosecond jitter. The same laser beam was also used to initiate simultaneously guided discharges up to 21 cm long at the output of the generator.

  2. New insights into the decay of ion waves to turbulence, ion heating, and soliton generation

    SciTech Connect

    Chapman, T. Banks, J. W.; Berger, R. L.; Cohen, B. I.; Williams, E. A.; Brunner, S.

    2014-04-15

    The decay of a single-frequency, propagating ion acoustic wave (IAW) via two-ion wave decay to a continuum of IAW modes is found to result in a highly turbulent plasma, ion soliton production, and rapid ion heating. Instability growth rates, thresholds, and sensitivities to plasma conditions are studied via fully kinetic Vlasov simulations. The decay rate of IAWs is found to scale linearly with the fundamental IAW potential amplitude ϕ{sub 1} for ZT{sub e}/T{sub i}≲20, beyond which the instability is shown to scale with a higher power of ϕ{sub 1}, where Z is the ion charge number and T{sub e} (T{sub i}) is the electron (ion) thermal temperature. The threshold for instability is found to be smaller by an order of magnitude than linear theory estimates. Achieving a better understanding of the saturation of stimulated Brillouin scatter levels observed in laser-plasma interaction experiments is part of the motivation for this study.

  3. Third-harmonic-generation of a diode laser for quantum control of beryllium ions

    NASA Astrophysics Data System (ADS)

    Carollo, Ryan A.; Lane, David A.; Kleiner, Edward K.; Kyaw, Phyo Aung; Teng, Chu C.; Ou, Celia Y.; Qiao, Shenglan; Hanneke, David

    2017-04-01

    We generate coherent ultraviolet radiation at 313 nm as the third harmonic of an external-cavity diode laser. We use this radiation for laser cooling of trapped beryllium atomic ions and sympathetic cooling of co-trapped beryllium-hydride molecular ions. An LBO crystal in an enhancement cavity generates the second harmonic, and a BBO crystal in a doubly resonant enhancement cavity mixes this second harmonic with the fundamental to produce the third harmonic. Each enhancement cavity is preceded by a tapered amplifier to increase the fundamental light. The 36-mW output power of this all-semiconductor-gain system will enable quantum control of the beryllium ions' motion.

  4. High frequency plasma generators for ion thruster applications

    NASA Technical Reports Server (NTRS)

    Divergilio, W. F.; Goede, H.; Komatsu, G. K.; Christensen, T.

    1981-01-01

    Two concepts for high frequency discharge ion thrusters are described. Both sources are designed for use with 30 cm grid sets and argon propellant and utilize multi-cusp permanent magnet geometries for plasma confinement. The RF induction source is a conventional design representing a synthesis of the RIT and multi-cusp concepts. The preliminary data (without system optimization) indicate a discharge efficiency comparable to that obtained in 30 cm hollow cathode multi-cusp argon thrusters. The electron cyclotron heating source is electrodeless and exhibits plasma characteristics which should lead to greatly reduced discharge chamber and screen sputter rates with the optimization of the magnetic fields, microwave frequency, and feed configuration.

  5. Generation and reactivity of yttrium-carbon cluster ions

    SciTech Connect

    Kan, S.Z.; Lee, S.A.; Freiser, B.S.

    1995-12-31

    In 1992, Castleman and coworkers reported the production of the ionic transition metal-carbon clusters, M{sub 8}C{sub 12}{sup +} (M=Ti,V, Zr and Hf). Like the observations of pure carbon clusters such as C{sub 60} and C{sub 70}, these metal-carbon clusters were observed as {open_quotes}magic{close_quotes} peaks in the mass spectra obtained from a supersonic expansion ion source. These intense peaks are indicative of the high stability of these clusters which are proposed to have symmetrical, cagelike structures with the geometry of a pentagonal dodecahedron. M{sub 8}C{sub 12}{sup +} species are thus termed metallo-carbohedrenes, or met-cars for short. Like fullerenes, met-cars are of both fundamental interest and hold promise as a new class of important materials and, hence, have become the focus of both theoretical and experimental investigations. Along with these species, metal-carbon clusters of other stoichiometries such as Ti{sub 8}C{sub 11}{sup +}, Ti{sub 8}C{sub 13}{sup +}, Ti{sub 7}C{sub 12}, V{sub 14}C{sub 13}{sup +}, V{sub 14}C{sub 12}{sup +}, and Nb{sub 4}C{sub 4}{sup +} have also been examined. Here, the authors report on the yttrium-carb system in which a broad range of metal-carbon cluster ions are observed.

  6. Radiofrequency plasma antenna generated by femtosecond laser filaments in air

    SciTech Connect

    Brelet, Y.; Houard, A.; Point, G.; Prade, B.; Carbonnel, J.; Andre, Y.-B.; Mysyrowicz, A.; Arantchouk, L.; Pellet, M.

    2012-12-24

    We demonstrate tunable radiofrequency emission from a meter-long linear plasma column produced in air at atmospheric pressure. A short-lived plasma column is initially produced by femtosecond filamentation and subsequently converted into a long-lived discharge column by application of an external high voltage field. Radiofrequency excitation is fed to the plasma by induction and detected remotely as electromagnetic radiation by a classical antenna.

  7. Scaled-Up Nonequilibrium Air Plasmas Generated by DC and Pulsed Discharges

    DTIC Science & Technology

    2010-09-08

    scalability of nonequilibrium plasmas produced by electrical discharges in atmospheric pressure air. Both DC and repetitively pulsed discharges ...Key results demonstrate that both DC glow discharge and pulsed transient spark generate air plasmas of required parameters. Glow discharge is easier...Corona discharge as a temperature probe was developed to diagnose the microwave torch preheated air. A new concept of the DC-driven pulsed

  8. Electro-hydrodynamic force field and flow patterns generated by a DC corona discharge in the air

    NASA Astrophysics Data System (ADS)

    Monrolin, Nicolas; Plouraboue, Franck; Praud, Olivier

    2016-11-01

    Ionic wind refers to the electro-convection of ionised air between high voltage electrodes. Microscopic ion-neutral collisions are responsible for momentum transfer from accelerated ions, subjected to the electric field, to the neutral gas molecules resulting in a macroscopic airflow acceleration. In the past decades it has been investigated for various purposes from food drying through aerodynamic flow control and eventually laptop cooling. One consequence of air acceleration between the electrodes is thrust generation, often referred to as the Biefeld-Brown effect or electro-hydrodynamic thrust. In this experimental study, the ionic wind velocity field is measured with the PIV method. From computing the acceleration of the air we work out the electrostatic force field for various electrodes configurations. This enables an original direct evaluation of the force distribution as well as the influence of electrodes shape and position. Thrust computation based on the flow acceleration are compared with digital scale measurements. Complex flow features are highlighted such as vortex shedding, indicating that aerodynamic effects may play a significant role. Furthermore, the aerodynamic drag force exerted on the electrodes is quantified by choosing an appropriate control volume. Authors thank Region Midi-Pyrenee and CNES Launcher Directorate for financial support.

  9. Approaches for controlling air pollutants and their environmental impacts generated from coal-based electricity generation in China.

    PubMed

    Xu, Changqing; Hong, Jinglan; Ren, Yixin; Wang, Qingsong; Yuan, Xueliang

    2015-08-01

    This study aims at qualifying air pollutants and environmental impacts generated from coal-based power plants and providing useful information for decision makers on the management of coal-based power plants in China. Results showed that approximately 9.03, 54.95, 62.08, and 12.12% of the national carbon dioxide, sulfur dioxide, nitrogen oxides, and particulate matter emissions, respectively, in 2011were generated from coal-based electricity generation. The air pollutants were mainly generated from east China because of the well-developed economy and energy-intensive industries in the region. Coal-washing technology can simply and significantly reduce the environmental burden because of the relativity low content of coal gangue and sulfur in washed coal. Optimizing the efficiency of raw materials and energy consumption is additional key factor to reduce the potential environmental impacts. In addition, improving the efficiency of air pollutants (e.g., dust, mercury, sulfur dioxide, nitrogen oxides) control system and implementing the strict requirements on air pollutants for power plants are important ways for reducing the potential environmental impacts of coal-based electricity generation in China.

  10. Ions at the air-water interface: an end to a hundred-year-old mystery?

    PubMed

    Levin, Yan; dos Santos, Alexandre P; Diehl, Alexandre

    2009-12-18

    Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this Letter a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry--the Hofmeister effect.

  11. Ambient air particles: effects on cellular oxidant radical generation in relation to particulate elemental chemistry.

    PubMed

    Prahalad, A K; Soukup, J M; Inmon, J; Willis, R; Ghio, A J; Becker, S; Gallagher, J E

    1999-07-15

    Epidemiologic studies have reported causal relationships between exposures to high concentrations of ambient air particles (AAP) and increased morbidity in individuals with underlying respiratory problems. Polymorphonuclear leukocytes (PMN) are frequently present in the airways of individuals exposed to particles. Upon particulate stimulation the PMN may release reactive oxygen species (ROS), which can result in tissue damage and injury. In this study a wide range of AAP samples from divergent sources (1, natural dust; 2, oil fly ash; 2, coal fly ash; 5, ambient air; and 1, carbon black) were analyzed for elemental content and solubility in relation to their ability to generate ROS. Elemental analyses were carried out in AAP and dH(2)O-washed AAP using energy dispersive x-ray fluorescence (XRF). Percent of sample mass accounted for by XRF-detectable elements was 1.2% (carbon black); 22-29% (natural dust and ambient air particles); 13-22% (oil fly ash particles); 28-49% (coal fly ash particles). The major proportion of elements in most of these particles were aluminosilicates and insoluble iron, except oil-derived fly ash particles in which soluble vanadium and nickel were in highest concentrations, consistent with particle acidity as measured in the supernatants. Human blood-derived monocytes and PMN were exposed to AAP and dH(2)O-washed particles, and generation of ROS was determined using luminol-enhanced chemiluminescence (LCL) assay. All the particles induced chemiluminescence response in the cells, except carbon black. The oxidant response of monocytes induced by AAP (with the exception of oil fly ash particles) was less than the response elicited by PMN. The LCL response of PMN in general increased with all washed particles, with oil fly ash (OFA) and one urban air particle showing statistically significant (p < 0. 05) differences between dH(2)O-washed and unwashed particles. The LCL activity in PMN induced by both particles and dH(2)O-washed particles was

  12. Fuel Savings and Emission Reductions from Next-Generation Mobile Air Conditioning Technology in India: Preprint

    SciTech Connect

    Chaney, L.; Thundiyil, K.; Chidambaram, S.; Abbi, Y. P.; Anderson, S.

    2007-05-01

    This paper quantifies the mobile air-conditioning fuel consumption of the typical Indian vehicle, exploring potential fuel savings and emissions reductions these systems for the next generation of vehicles.

  13. Kinetic analysis of competition between aerosol particle removal and generation by ionization air purifiers.

    PubMed

    Alshawa, Ahmad; Russell, Ashley R; Nizkorodov, Sergey A

    2007-04-01

    Ionization air purifiers are increasingly used to remove aerosol particles from indoor air. However, certain ionization air purifiers also emit ozone. Reactions between the emitted ozone and unsaturated volatile organic compounds (VOC) commonly found in indoor air produce additional respirable aerosol particles in the ultrafine (<0.1 microm) and fine (<2.5 microm) size domains. A simple kinetic model is used to analyze the competition between the removal and generation of particulate matter by ionization air purifiers under conditions of a typical residential building. This model predicts that certain widely used ionization air purifiers may actually increase the mass concentration of fine and ultrafine particulates in the presence of common unsaturated VOC, such as limonene contained in many household cleaning products. This prediction is supported by an explicit observation of ultrafine particle nucleation events caused by the addition of D-limonene to a ventilated office room equipped with a common ionization air purifier.

  14. Evaluation of the commercial bacterial air samplers by the new bacterial aerosol generator.

    PubMed

    Furuhashi, M; Miyamae, T

    1981-03-01

    Of late microbiological air samplers of various types have been developed in monitoring the critical areas in the hospitals and pharmaceutical plants. It has not been clarified, however, that a commercial air sampler is the most suitable for such a purpose. The present studies were conducted to investigate the bacterial collection efficiency of these air samplers. The new experimental apparatus basically consists of a bacterial aerosol generator and an isokinetic sampling steel air duct. Serratia marcescens was used as the test bacteria, and then the bacterial collection efficiency of the three kinds of commercial air samplers (Andersen air sampler, Pin-hole air sampler and M/G air sampler) was examined. It was found that in these experiments these three air samplers had a high bacterial collection efficiency. All except 0.3 to 2.0% of the small bacterial particles (1 to 5 micrometer) were trapped by these tested air samplers. Furthermore, in these three air samplers it was also confirmed that for collecting the hospital airborne bacteria the bacterial collection efficiency was more than 99.9%. The authors' findings showed that these three air samplers were designed according to Ranz and Wong's theoretical and experimental results.

  15. Diffusion of Innovation: Factors Promoting Interest in Solar Photovoltaic Generation Systems Within Air Force Installations

    DTIC Science & Technology

    2007-03-01

    Q42c. How likely is it that your base will request funding in these systems in the next 10 years? (large scale) Q43a.How beneficial do you think it...DIFFUSION OF INNOVATION: FACTORS PROMOTING INTEREST IN SOLAR PHOTOVOLTAIC GENERATION SYSTEMS WITHIN AIR...SOLAR PHOTOVOLTAIC GENERATION SYSTEMS WITHIN AIR FORCE INSTALLATIONS THESIS Presented to the Faculty Department of Systems and Engineering

  16. Impact of air pollution on vegetation near the Columbia Generating Station - Wisconsin power plant impact study

    SciTech Connect

    Tibbitts, T.W.; Will-Wolf, S.; Karnowsky, D.F.; Olszyk, D.M.

    1982-06-01

    The impact of air pollution from the coal-fired Columbia Generating Station upon vegetation was investigated. Air monitoring of 03 and 02 documented levels that occurred before and with operation of the generating station. Field sampling of alfalfa, lichens, and white pines was undertaken before and after initiation of generating station operations. Controlled environmental exposures were undertaken with separate cultivars of crop species grown in the vicinity of the generating station. Alfalfa, carrots, mint, peas, beans, and trembling aspen were exposed to SO2 and O3 to establish minimum threshold pollutant levels for injury from these pollutants.

  17. Ion mobility-mass spectrometry of phosphorylase B ions generated with supercharging reagents but in charge-reducing buffer.

    PubMed

    Hogan, Christopher J; Ogorzalek Loo, Rachel R; Loo, Joseph A; de la Mora, Juan Fernandez

    2010-11-07

    We investigate whether "supercharging" reagents able to shift the charge state distributions (CSDs) of electrosprayed protein ions upward also influence gas-phase protein structure. A differential mobility analyzer and a mass spectrometer are combined in series (DMA-MS) to measure the mass and mobility of monomer and multimeric phosphorylase B ions (monomer molecular weight ∼97 kDa) in atmospheric pressure air. Proteins are electrosprayed from charge-reducing triethylammonium formate in water (pH = 6.8) with and without the addition of the supercharging reagent tetramethylene sulfone (sulfolane). Because the DMA measures ion mobility prior to collisional heating or declustering, it probes the structure of supercharged protein ions immediately following solvent (water) evaporation. As in prior studies, the addition of sulfolane is found to drastically increase both the mean and maximum charge state of phosphorylase B ions. Ions from all protein n-mers were found to yield mobilities that, for a given charge state, were ∼6-10% higher in the absence of sulfolane. We find that the mobility decrease which arises with sulfolane is substantially smaller than that typically observed for folded-to-unfolded transitions in protein ions (where a ∼60% decrease in mobility is typical), suggesting that supercharging reagents do not cause structural protein modifications in solution as large as noted recently by Williams and colleagues [E. R. Williams et al., J. Am. Soc. Mass Spectrom., 2010, 21, 1762-1774]. In fact, the measurements described here indicate that the modest mobility decrease observed can be partly attributed to sulfolane trapping within the protein ions during DMA measurements, and probably also in solution. As the most abundant peaks in measured mass-mobility spectra for ions produced with and without sulfolane correspond to non-covalently bound phosphorylase B dimers, we find that in spite of a change in mobility/cross section, sulfolane addition does not

  18. Development of cooling strategy for an air cooled lithium-ion battery pack

    NASA Astrophysics Data System (ADS)

    Sun, Hongguang; Dixon, Regan

    2014-12-01

    This paper describes a cooling strategy development method for an air cooled battery pack with lithium-ion pouch cells used in a hybrid electric vehicle (HEV). The challenges associated with the temperature uniformity across the battery pack, the temperature uniformity within each individual lithium-ion pouch cell, and the cooling efficiency of the battery pack are addressed. Initially, a three-dimensional battery pack thermal model developed based on simplified electrode theory is correlated to physical test data. An analytical design of experiments (DOE) approach using Optimal Latin-hypercube technique is then developed by incorporating a DOE design model, the correlated battery pack thermal model, and a morphing model. Analytical DOE studies are performed to examine the effects of cooling strategies including geometries of the cooling duct, cooling channel, cooling plate, and corrugation on battery pack thermal behavior and to identify the design concept of an air cooled battery pack to maximize its durability and its driving range.

  19. Simultaneous Filtered and Unfiltered Light Scattering Measurements in Laser Generated Air Sparks

    NASA Astrophysics Data System (ADS)

    Limbach, Christopher; Miles, Richard

    2013-09-01

    Elastic laser light scattering may be used to measure the thermofluidic properties of gases and plasmas, including but not limited to density, temperature and velocity. Most of this information is contained within the spectra of the scattered radiation. This may be measured directly through dispersion or indirectly, by passing the light through an atomic or molecular vapor filter with known absorption features. In this work, filtered and unfiltered laser light scattering is used to diagnose air sparks generated by a 1064 nm Q-switched laser. The probe laser consists of a second Q-switched Nd:YAG laser frequency doubled to 532 nm. Simultaneous unfiltered and filtered images of the scattering are captured by a Princeton Instruments ICCD camera by using a 50 mm diameter concave re-imaging mirror. The filter consists of a well-characterized molecular Iodine cell. In the shock wave formed by the laser spark, spatially resolved measurements of density, temperature and radial velocity are extracted and compared with theory and models. Measurements in the spark core probe the ion feature of the electron Thomson scattering, from which ne and T can be extracted with the assumption Te =Ti . Partial funding was provided by General Electric Global Research Center: Niskayuna, New York. The first author is also supported by a National Defense Science and Engineering Graduate Fellowship.

  20. Appeal of Air Permit for New Harquahala Generating Company

    EPA Pesticide Factsheets

    This document may be of assistance in applying the Title V air operating permit regulations. This document is part of the Title V Petition Database available at www2.epa.gov/title-v-operating-permits/title-v-petition-database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

  1. Electrostatic Wave Generation and Transverse Ion Acceleration by Alfvenic Wave Components of BBELF Turbulence

    NASA Technical Reports Server (NTRS)

    Singh, Nagendra; Khazanov, George; Mukhter, Ali

    2007-01-01

    We present results here from 2.5-D particle-in-cell simulations showing that the electrostatic (ES) components of broadband extremely low frequency (BBELF) waves could possibly be generated by cross-field plasma instabilities driven by the relative drifts between the heavy and light ion species in the electromagnetic (EM) Alfvenic component of the BBELF waves in a multi-ion plasma. The ES components consist of ion cyclotron as well as lower hybrid modes. We also demonstrate that the ES wave generation is directly involved in the transverse acceleration of ions (TAI) as commonly measured with the BBELF wave events. The heating is affected by ion cyclotron resonance in the cyclotron modes and Landau resonance in the lower hybrid waves. In the simulation we drive the plasma by the transverse electric field, E(sub y), of the EM waves; the frequency of E(sub y), omega(sub d), is varied from a frequency below the heavy ion cyclotron frequency, OMEGA(sub h), to below the light ion cyclotron frequency, OMEGA(sub i). We have also performed simulations for E(sub y) having a continuous spectrum given by a power law, namely, |Ey| approx. omega(sub d) (exp -alpha), where the exponent alpha = _, 1, and 2 in three different simulations. The driving electric field generates polarization and ExB drifts of the ions and electrons. When the interspecies relative drifts are sufficiently large, they drive electrostatic waves, which cause perpendicular heating of both light and heavy ions. The transverse ion heating found here is discussed in relation to observations from Cluster, FAST and Freja.

  2. Ion mobility spectrometry of hydrazine, monomethylhydrazine, and ammonia in air with 5-nonanone reagent gas

    NASA Technical Reports Server (NTRS)

    Eiceman, G. A.; Salazar, M. R.; Rodriguez, M. R.; Limero, T. F.; Beck, S. W.; Cross, J. H.; Young, R.; James, J. T.

    1993-01-01

    Hydrazine (HZ) and monomethylhydrazine (MMH) in air were monitored continuously using a hand-held ion mobility spectrometer equipped with membrane inlet, 63Ni ion source, acetone reagent gas, and ambient temperature drift tube. Response characteristics included detection limit, 6 ppb; linear range, 10-600 ppb; saturated response, >2 ppm; and stable response after 15-30 min. Ammonia interfered in hydrazines detection through a product ion with the same drift time as that for MMH and HZ. Acetone reagent gas was replaced with 5-nonanone to alter drift times of product ions and separate ammonia from MMH and HZ. Patterns in mobility spectra, ion identifications from mass spectra, and fragmentation cross-sections from collisional-induced dissociations suggest that drift times are governed by ion-cluster equilibria in the drift region of the mobility spectrometer. Practical aspects including calibration, stability, and reproducibility are reported from the use of a hand-held mobility spectrometer on the space shuttle Atlantis during mission STS-37.

  3. Lifetime of anode polymer in magnetically insulated ion diodes for high-intensity pulsed ion beam generation

    SciTech Connect

    Zhu, X. P.; Dong, Z. H.; Han, X. G.; Xin, J. P.; Lei, M. K.

    2007-02-15

    Generation of high-intensity pulsed ion beam (HIPIB) has been studied experimentally using polyethylene as the anode polymer in magnetically insulated ion diodes (MIDs) with an external magnetic field. The HIPIB is extracted from the anode plasma produced during the surface discharging process on polyethylene under the electrical and magnetic fields in MIDs, i.e., high-voltage surface breakdown (flashover) with bombardments by electrons. The surface morphology and the microstructure of the anode polymer are characterized using scanning electron microscopy and differential scanning calorimetry, respectively. The surface roughening of the anode polymer results from the explosive release of trapped gases or newly formed gases under the high-voltage discharging, leaving fractured surfaces with bubble formation. The polyethylene in the surface layer degrades into low-molecular-weight polymers such as polyethylene wax and paraffin under the discharging process. Both the surface roughness and the fraction of low molecular polymers apparently increase as the discharging times are prolonged for multipulse HIPIB generation. The changes in the surface morphology and the composition of anode polymer lead to a noticeable decrease in the output of ion beam intensity, i.e., ion current density and diode voltage, accompanied with an increase in instability of the parameters with the prolonged discharge times. The diode voltage (or surface breakdown voltage of polymer) mainly depends on the surface morphology (or roughness) of anode polymers, and the ion current density on the composition of anode polymers, which account for the two stages of anode polymer degradation observed experimentally, i.e., stage I which has a steady decrease of the two parameters and stage II which shows a slow decrease, but with an enhanced fluctuation of the two parameters with increasing pulses of HIPIB generation.

  4. Simulation and Theory of Ions at Atmospherically Relevant Aqueous Liquid-Air Interfaces

    SciTech Connect

    Tobias, Douglas J.; Stern, Abraham C.; Baer, Marcel D.; Levin, Yan; Mundy, Christopher J.

    2013-04-01

    Chemistry occurring at or near the surfaces of aqueous droplets and thin films in the atmosphere influences air quality and climate. Molecular dynamics simulations are becoming increasingly useful for gaining atomic-scale insight into the structure and reactivity of aqueous interfaces in the atmosphere. Here we review simulation studies of atmospherically relevant aqueous liquid-air interfaces, with an emphasis on ions that play important roles in the chemistry of atmospheric aerosols. In addition to surveying results from simulation studies, we discuss challenges to the refinement and experimental validation of the methodology for simulating ion adsorption to the air-water interface, and recent advances in elucidating the driving forces for adsorption. We also review the recent development of a dielectric continuum theory that is capable of reproducing simulation and experimental data on ion behavior at aqueous interfaces. MDB and CJM acknowledge support from the US Department of Energy's Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory (PNNL) is operated for the Department of Energy by Battelle. MDB is supported by the Linus Pauling Distinguished Postdoctoral Fellowship Program at PNNL.

  5. Plasma generation near an Ion thruster disharge chamber hollow cathode

    NASA Technical Reports Server (NTRS)

    Katz, Ira; Anderson, John R.; Goebel, Dan M.; Wirz, Richard; Sengupta, Anita

    2003-01-01

    In gridded electrostatic thrusters, ions are produced by electron bombardment in the discharge chamber. In most of these thrusters, a single, centrally located hollow cathode supplies the ionizing electrons. An applied magnetic field in the discharge chamber restricts the electrons leaving the hollow cathode to a very narrow channel. In this channel, the high electron current density ionizes both propellant gas flowing from the hollow cathode, and other neutrals from the main propellant flow from the plenum. The processes that occur just past the hollow cathode exit are very important. In recent engine tests, several cases of discharge cathode orifice place and keeper erosion have been reported. In this paper we present results from a new 1-D, variable area model of the plasma processes in the magnetized channel just downstream of the hollow cathode keeper. The model predicts plasma densities, and temperatures consistent with those reported in the literature for the NSTAR engine, and preliminary results from the model show a potential maximum just downstream of the cathode.

  6. Neoclassical transport of energetic minority tail ions generated by ion-cyclotron resonance heating in tokamak geometry

    SciTech Connect

    Chang, C.S. . Courant Inst. of Mathematical Sciences); Hammett, G.W.; Goldston, R.J. . Plasma Physics Lab.)

    1990-01-01

    Neoclassical transport of energetic minority tail ions, which are generated by high powered electromagnetic waves of the Ion Cyclotron Range of Frequencies (ICRF) at the fundamental harmonic resonance, is studied analytically in tokamak geometry. The effect of Coulomb collisions on the tail ion transport is investigated in the present work. The total tail ion transport will be the sum of the present collision-driven transport and the wave-driven transport, which is due to the ICRF-wave scattering of the tail particles as reported in the literature. The transport coefficients have been calculated kinetically, and it is found that the large tail ion viscosity, driven by the localized ICRF-heating and Coulomb slowing-down collisions, induces purely convective particle transport of the tail species, while the energy transport is both convective and diffusive. The rate of radial particle transport is shown to be usually small, but the rate of radial energy transport is larger and may not be negligible compared to the Coulomb slowing-down rate. 18 refs., 2 figs.

  7. Quantification of ozone levels in indoor environments generated by ionization and ozonolysis air purifiers.

    PubMed

    Britigan, Nicole; Alshawa, Ahmad; Nizkorodov, Sergey A

    2006-05-01

    Indoor air purifiers are advertised as safe household products for health-conscious individuals, especially for those suffering from allergies and asthma. However, certain air purifiers produce ozone (O3) during operation, either intentionally or as a byproduct of air ionization. This is a serious concern, because O3 is a criteria air pollutant regulated by health-related federal and state standards. Several types of air purifiers were tested for their ability to produce ozone in various indoor environments at 40-50% relative humidity, including office rooms, bathrooms, bedrooms, and cars. O3 levels generated by personal wearable air purifiers were also tested. In many cases, O3 concentrations were well in excess of public and/or industrial safety levels established by U.S. Environmental Protection Agency, California Air Resources Board, and Occupational Safety and Health Administration. Simple kinetic equations were obtained that can predict the steady-state level of O3 in a room from the O3 emission rate of the air purifier and the first-order decay rate of O3 in the room. The additivity of O3 levels generated by independent O3 generators was experimentally demonstrated.

  8. Air supply using an ionic wind generator in a proton exchange membrane fuel cell

    NASA Astrophysics Data System (ADS)

    Kwon, Kilsung; Li, Longnan; Park, Byung Ho; Lee, Seung Jun; Kim, Daejoong

    2015-06-01

    A new air supply is demonstrated for a portable polymer electrolyte membrane fuel cell (PEMFC). The air supply is an ionic wind generator (IWG) with a needle-to-cylinder configuration. The IWG supplies air to the portable PEMFC owing to momentum transfer to the air by charged molecules generated by the corona discharge from a high applied potential. There is no difference in the performance of the PEMFC when compressed air and the IWG are used as the air supply. For the varying interelectrode distance, IWG performance is varied and measured in terms of the flow rate and current. At the interelectrode distance of 9.0 mm, the air flow rate is a suitable for the portable PEMFC with low power consumption. When the IWG is used to supply air to the portable PEMFC, it is found that the flow rate per unit power consumed decreases with the applied voltage, the gross power generation monotonously increases with the applied voltage, and the highest net power (268 mW) is obtained at the applied voltage of 8.5 kV. The parasitic power ratio reaches a minimum value of ∼0.06 with the applied IWG voltage of 5.5 kV.

  9. Chemical kinetics and relaxation of non-equilibrium air plasma generated by energetic photon and electron beams

    NASA Astrophysics Data System (ADS)

    Maulois, Melissa; Ribière, Maxime; Eichwald, Olivier; Yousfi, Mohammed; Azaïs, Bruno

    2016-04-01

    The comprehension of electromagnetic perturbations of electronic devices, due to air plasma-induced electromagnetic field, requires a thorough study on air plasma. In the aim to understand the phenomena at the origin of the formation of non-equilibrium air plasma, we simulate, using a volume average chemical kinetics model (0D model), the time evolution of a non-equilibrium air plasma generated by an energetic X-ray flash. The simulation is undertaken in synthetic air (80% N2 and 20% O2) at ambient temperature and atmospheric pressure. When the X-ray flash crosses the gas, non-relativistic Compton electrons (low energy) and a relativistic Compton electron beam (high energy) are simultaneously generated and interact with the gas. The considered chemical kinetics scheme involves 26 influent species (electrons, positive ions, negative ions, and neutral atoms and molecules in their ground or metastable excited states) reacting following 164 selected reactions. The kinetics model describing the plasma chemistry was coupled to the conservation equation of the electron mean energy, in order to calculate at each time step of the non-equilibrium plasma evolution, the coefficients of reactions involving electrons while the energy of the heavy species (positive and negative ions and neutral atoms and molecules) is assumed remaining close to ambient temperature. It has been shown that it is the relativistic Compton electron beam directly created by the X-ray flash which is mainly responsible for the non-equilibrium plasma formation. Indeed, the low energy electrons (i.e., the non-relativistic ones) directly ejected from molecules by Compton collisions contribute to less than 1% on the creation of electrons in the plasma. In our simulation conditions, a non-equilibrium plasma with a low electron mean energy close to 1 eV and a concentration of charged species close to 1013 cm-3 is formed a few nanoseconds after the peak of X-ray flash intensity. 200 ns after the flash

  10. Development of compact size penning ion source for compact neutron generator.

    PubMed

    Das, Basanta Kumar; Shyam, Anurag

    2008-12-01

    For long-life operation, easy to mount and compact in size penning type ion sources are widely used in different fields of research such as neutron generators, material research, and surface etching. One penning type ion source has been developed in our laboratory. Applying high voltage of 2 kV between two oppositely biased electrodes and using permanent magnet of 500 gauss magnetic field along the axis, we had produced the glow discharge in the plasma region. The performance of this source was investigated using nitrogen gas. Deuterium ions were produced and extracted on the basis of chosen electrodes and the angle of extraction. Using a single aperture plasma electrode, the beam was extracted along the axial direction. The geometry of plasma electrode is an important factor for the efficient extraction of the ions from the plasma ion source. The extracted ion current depends upon the shape of the plasma meniscus. A concave shaped plasma meniscus produces converged ion beam. The convergence of extracted ions is related to the extraction electrode angle. The greater the angle, the more the beam converges. We had studied experimentally this effect with a compact size penning ion source. The detailed comparison among the different extraction geometry and different electrode angle are discussed in this paper.

  11. Development of compact size penning ion source for compact neutron generator

    SciTech Connect

    Das, Basanta Kumar; Shyam, Anurag

    2008-12-15

    For long-life operation, easy to mount and compact in size penning type ion sources are widely used in different fields of research such as neutron generators, material research, and surface etching. One penning type ion source has been developed in our laboratory. Applying high voltage of 2 kV between two oppositely biased electrodes and using permanent magnet of 500 gauss magnetic field along the axis, we had produced the glow discharge in the plasma region. The performance of this source was investigated using nitrogen gas. Deuterium ions were produced and extracted on the basis of chosen electrodes and the angle of extraction. Using a single aperture plasma electrode, the beam was extracted along the axial direction. The geometry of plasma electrode is an important factor for the efficient extraction of the ions from the plasma ion source. The extracted ion current depends upon the shape of the plasma meniscus. A concave shaped plasma meniscus produces converged ion beam. The convergence of extracted ions is related to the extraction electrode angle. The greater the angle, the more the beam converges. We had studied experimentally this effect with a compact size penning ion source. The detailed comparison among the different extraction geometry and different electrode angle are discussed in this paper.

  12. Aircraft Weather Mitigation for the Next Generation Air Transportation System

    NASA Technical Reports Server (NTRS)

    Stough, H. Paul, III

    2007-01-01

    Atmospheric effects on aviation are described by Mahapatra (1999) as including (1) atmospheric phenomena involving air motion - wind shear and turbulence; (2) hydrometeorological phenomena - rain, snow and hail; (3) aircraft icing; (4) low visibility; and (5) atmospheric electrical phenomena. Aircraft Weather Mitigation includes aircraft systems (e.g. airframe, propulsion, avionics, controls) that can be enacted (by a pilot, automation or hybrid systems) to suppress and/or prepare for the effects of encountered or unavoidable weather or to facilitate a crew operational decision-making process relative to weather. Aircraft weather mitigation can be thought of as a continuum (Figure 1) with the need to avoid all adverse weather at one extreme and the ability to safely operate in all weather conditions at the other extreme. Realistic aircraft capabilities fall somewhere between these two extremes. The capabilities of small general aviation aircraft would be expected to fall closer to the "Avoid All Adverse Weather" point, and the capabilities of large commercial jet transports would fall closer to the "Operate in All Weather Conditions" point. The ability to safely operate in adverse weather conditions is dependent upon the pilot s capabilities (training, total experience and recent experience), the airspace in which the operation is taking place (terrain, navigational aids, traffic separation), the capabilities of the airport (approach guidance, runway and taxiway lighting, availability of air traffic control), as well as the capabilities of the airplane. The level of mitigation may vary depending upon the type of adverse weather. For example, a small general aviation airplane may be equipped to operate "in the clouds" without outside visual references, but not be equipped to prevent airframe ice that could be accreted in those clouds.

  13. Generation of circularly polarized attosecond pulses by intense ultrashort laser pulses from extended asymmetric molecular ions

    SciTech Connect

    Yuan, Kai-Jun; Bandrauk, Andre D.

    2011-08-15

    We present a method for generation of single circularly polarized attosecond pulses in extended asymmetric HHe{sup 2+} molecular ions. By employing an intense ultrashort circularly polarized laser pulse with intensity 4.0x10{sup 14} W/cm{sup 2}, wavelength 400 nm, and duration 10 optical cycles, molecular high-order-harmonic generation (MHOHG) spectra with multiple plateaus exhibit characters of circular polarization. Using a classical laser-induced collision model, double collisions of continuum electrons first with neighboring ions and then second with parent ions are presented at a particular internuclear distance and confirmed from numerical solutions of a time-dependent Schroedinger equation. We analyze the MHOHG spectra with a Gabor time window and find that, due to the asymmetry of HHe{sup 2+}, a single collision trajectory of continuum electrons with ions can produce circularly polarized harmonics, leading to single circularly polarized attosecond pulses for specific internuclear distances.

  14. Simulation Study of Toroidal Flow Generation of Minority Ions by Local ICRF Heating

    NASA Astrophysics Data System (ADS)

    Murakami, Sadayoshi; Itoh, Kimitaka; Zheng, Linjin; Van Dam, James W.; Fukuyama, Atsushi

    2015-12-01

    The toroidal flow generation of minority ions by the local ion cyclotron range of frequencies (ICRF) heating is investigated in a tokamak plasma by applying the GNET code, which can solve the drift kinetic equation in the 5-D phase space. An asymmetry of velocity distribution function in the parallel direction is found and two types of toroidal averaged flow of minority ions are observed. One is the sheared flow near the RF power absorption region depending on the sign of k||, and the other is the toroidal flow, which is larger than the previous one, independent of the sign of k||. It is found that the k||-sign-independent toroidal flow is generated by the net toroidal motion of energetic tail ions and that the k||-sign-dependent flow is related to the mechanism proposed by Ohkawa [http://dx.doi.org/10.1063/1.2047629, Phys. Plasmas 12, 094506 (2005)].

  15. Generation of macroscopic magnetic-field-aligned electric fields by the convection surge ion acceleration mechanism

    NASA Technical Reports Server (NTRS)

    Mauk, B. H.

    1989-01-01

    The 'convection surge' model for ion acceleration, designed by Mauk (1986) to explain the observed ion distributions and the field-aligned character of middle magnetospheric ion distributions during the expansion phase of a substorm, was extended to include the self-consistent generation of magnetic-field-aligned electric fields. Results from the modified model show that the convection surge mechanism leads to the generation of dynamical macroscopic magnetic field-aligned electric fields that begin their strongest developments very near the magnetic equator and then propagate to higher latitudes. Potential drops as high as 1 to 10 kV might be expected, depending on the mass species of the ions and on the electron temperatures. It is speculated that the convection surge mechanism could be a key player in the transient field-aligned electromagnetic processes observed to operate within the middle magnetosphere.

  16. Generation of waves in the Venus mantle by the ion acoustic beam instability

    NASA Technical Reports Server (NTRS)

    Huba, J. D.

    1993-01-01

    The ion acoustic beam instability is suggested as a mechanism to produce wave turbulence observed in the Venus mantle at frequencies 100 Hz and 730 Hz. The plasma is assumed to consist of a stationary cold O(+) ion plasma and a flowing, shocked solar wind plasma. The O(+) ions appear as a beam relative to the flowing ionosheath plasma which provides the free energy to drive the instability. The plasma is driven unstable by inverse electron Landau damping of an ion acoustic wave associated with the cold ionospheric O(+) ions. The instability can directly generate the observed 100 Hz waves in the Venus mantle as well as the observed 730 Hz waves through the Doppler shift of the frequency caused by the satellite motion.

  17. Wakefields generated by collisional neutrinos in neutral-electron-positron-ion plasma

    SciTech Connect

    Tinakiche, Nouara

    2015-12-15

    A classical fluid description is adopted to investigate nonlinear interaction between an electron-type neutrino beam and a relativistic collisionless unmagnetized neutral-electron-positron-ion plasma. In this work, we consider the collisions of the neutrinos with neutrals in the plasma and study their effect on the generation of wakefields in presence of a fraction of ions in a neutral-electron-positron plasma. The results obtained in the present work are interpreted and compared with previous studies.

  18. Optimization of ultrafast laser generated low-energy ion beams from silicon targets

    SciTech Connect

    Stoian, R.; Mermillod-Blondin, A.; Bulgakova, N.M.; Rosenfeld, A.; Hertel, I.V.; Spyridaki, M.; Koudoumas, E.; Tzanetakis, P.; Fotakis, C.

    2005-09-19

    We demonstrate the possibility to manipulate the kinetic properties of ion beams generated by ultrafast laser ablation of silicon. The versatility in regulating the sub-keV ion flux is achieved by implementing adaptive control of the temporal shape of incident laser pulses. Tunable characteristics for the charged beams are obtained using excitation synchronized with the phase-transformation dynamics, exploiting transitions to volatile fluid states with minimal energetic expenses.

  19. An Autosampler and Field Sample Carrier for Maximizing Throughput Using an Open-Air, Surface Sampling Ion Source for MS

    EPA Science Inventory

    A recently developed, commercially available, open-air, surface sampling ion source for mass spectrometers provides individual analyses in several seconds. To realize its full throughput potential, an autosampler and field sample carrier were designed and built. The autosampler ...

  20. Comparison of Single Event Transients Generated by Short Pulsed X-Rays, Lasers and Heavy Ions

    SciTech Connect

    Cardoza, David; LaLumondiere, Stephen D.; Tockstein, Michael A.; Brewe, Dale L.; Wells, Nathan P.; Koga, Rokutaro; Gaab, K. M.; Lotshaw, William T.; Moss, Steven C.

    2014-12-01

    We report an experimental study of the transients generated by pulsed x-rays, heavy ions, and different laser wavelengths in a Si p-i-n photodiode. We compare the charge collected by all of the excitation methods to determine the equivalent LET for pulsed x-rays relative to heavy ions. Our comparisons show that pulsed x-rays from synchrotron sources can generate a large range of equivalent LET and generate transients similar to those excited by laser pulses and heavy ion strikes. We also look at how the pulse width of the transients changes for the different excitation methods. We show that the charge collected with pulsed x-rays is greater than expected as the x-ray photon energy increases. Combined with their capability of focusing to small spot sizes and of penetrating metallization, pulsed x-rays are a promising new tool for high resolution screening of SEE susceptibility

  1. Conditions for Debris-Background Ion Interactions and Collisionless Shock Wave Generation

    SciTech Connect

    Winske, Dan; Cowee, Misa

    2012-07-10

    We use hybrid simulations and simple theoretical arguments to determine when debris ions streaming relative to background ions in a collisionless, magnetized plasma couple strongly enough to generate a magnetosonic shock wave. We consider three types of configurations: one-dimensional, the two-dimensional extension of the 1-D case, and a more complex 2-D geometry that contains some effects that would be found in a laser-produced, laboratory plasma. We show that the simulation results as well as previous Russian and LLNL results reduce to a simple condition (R{sub m}/{rho}{sub d} = equal mass radius/debris ion gyroradius {ge} 0.7) for the generation of a shock wave. Strong debris interaction with the background is characterized by the formation of a magnetic pulse that steepens and speeds up as it encounters the debris ions deflected by the magnetic field. The pulse further evolves into a shock. As the earlier work has indicated, the process also involves the generation of a transverse electric field perpendicular to the flow and the magnetic field that accelerates the background ions radially outward, which in turn causes the speedup of the pulse. With electric and magnetic field probes, the UCLA laser experiments should be able to detect these signatures of coupling as well as the generation of the shock wave.

  2. Experimental observation of gravity-capillary solitary waves generated by a moving air-suction

    NASA Astrophysics Data System (ADS)

    Park, Beomchan; Cho, Yeunwoo

    2016-11-01

    Gravity-capillary solitary waves are generated by a moving "air-suction" forcing instead of a moving "air-blowing" forcing. The air-suction forcing moves horizontally over the surface of deep water with speeds close to the minimum linear phase speed cmin = 23 cm/s. Three different states are observed according to forcing speed below cmin. At relatively low speeds below cmin, small-amplitude linear circular depressions are observed, and they move steadily ahead of and along with the moving forcing. As the forcing speed increases close to cmin, however, nonlinear 3-D gravity-capillary solitary waves are observed, and they move steadily ahead of and along with the moving forcing. Finally, when the forcing speed is very close to cmin, oblique shedding phenomena of 3-D gravity-capillary solitary waves are observed ahead of the moving forcing. We found that all the linear and nonlinear wave patterns generated by the air-suction forcing correspond to those generated by the air-blowing forcing. The main difference is that 3-D gravity-capillary solitary waves are observed "ahead of" the air-suction forcing, whereas the same waves are observed "behind" the air-blowing forcing. This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (NRF-2014R1A1A1002441).

  3. Downhole steam generator using low pressure fuel and air supply

    DOEpatents

    Fox, Ronald L.

    1983-01-01

    An apparatus for generation of steam in a borehole for penetration into an earth formation wherein a spiral, tubular heat exchanger is used in the combustion chamber to isolate the combustion process from the water being superheated for conversion into steam. The isolation allows combustion of a relatively low pressure oxidant and fuel mixture for generating high enthalpy steam. The fuel is preheated by feedback of combustion gases from the top of the combustion chamber through a fuel preheater chamber. The hot exhaust gases of combustion at the bottom of the combustion chamber, after flowing over the heat exchanger enter an exhaust passage and pipe. The exhaust pipe is mounted inside the water supply line heating the water flowing into the heat exchanger. After being superheated in the heat exchanger, the water is ejected through an expansion nozzle and converts into steam prior to penetration into the earth formation. Pressure responsive doors are provided at a steam outlet downstream of the nozzle and close when the steam pressure is lost due to flameout.

  4. Fast ion generation and runaway through magnetic reconnection events in MST

    NASA Astrophysics Data System (ADS)

    Kim, Jungha; Anderson, Jay; Capecchi, William; Bonofiglo, Phillip; Sears, Stephanie

    2016-10-01

    Fokker-Planck and full orbit modeling are used to investigate how global reconnection events in MST plasmas generate an anisotropic fast ion distribution. A multi-step process is hypothesized. First, thermal ions are heated by a perpendicular heating mechanism, possibly a stochastic process that relies on turbulent diffusion and strong radial electric fields, or ion cyclotron damping in the tearing-driven turbulent cascade. Second, a small fraction of the heated ions have sufficient speed to develop substantial guiding center drifts that are relatively immune to stochastic magnetic transport. In the RFP, these fast ion drift orbits are favorable to confinement. Finally, these fast ions are accelerated by a parallel inductive electric field (up to 80 V/m) associated with the abruptly changing magnetic equilibrium. This strong impulsive field does not include any magnetic-fluctuation-based contribution as experienced by thermal particles or electrons, which do not run away like fast ions. CQL3D, a Fokker-Planck solver, and RIO, a full orbit tracing code, are used to model this multi-step process that is responsible for anisotropy in fast ion distribution in MST. Work supported by US DOE. Supported by US DOE.

  5. Boron ion beam generation utilizing lanthanum hexaboride cathodes: Comparison of vacuum arc and planar magnetron glow

    SciTech Connect

    Nikolaev, A. G.; Vizir, A. V.; Yushkov, G. Yu. Frolova, V. P.; Oks, E. M.

    2016-02-15

    Boron ion beams are widely used for semiconductor ion implantation and for surface modification for improving the operating parameters and increasing the lifetime of machine parts and tools. For the latter application, the purity requirements of boron ion beams are not as stringent as for semiconductor technology, and a composite cathode of lanthanum hexaboride may be suitable for the production of boron ions. We have explored the use of two different approaches to boron plasma production: vacuum arc and planar high power impulse magnetron in self-sputtering mode. For the arc discharge, the boron plasma is generated at cathode spots, whereas for the magnetron discharge, the main process is sputtering of cathode material. We present here the results of comparative test experiments for both kinds of discharge, aimed at determining the optimal discharge parameters for maximum yield of boron ions. For both discharges, the extracted ion beam current reaches hundreds of milliamps and the fraction of boron ions in the total extracted ion beam is as high as 80%.

  6. Positive and negative gas-phase ion chemistry of chlorofluorocarbons in air at atmospheric pressure.

    PubMed

    Bosa, Elisabetta; Paradisi, Cristina; Scorrano, Gianfranco

    2003-01-01

    This paper presents a report on the ionization/dissociation of some representative chlorofluorocarbons (CFCs) induced by corona discharges in air at atmospheric pressure. Both positive and negative ions formed from Freons 1,1,1-trichlorotrifluoroethane (CFC 113a), 1,1,2-trichlorotrifluoroethane (CFC 113), and 1,1,1,2-tetrachlorodifluoroethane (CFC 112a) were analyzed using an atmospheric pressure chemical ionization mass spectrometry (APCI-MS) instrument. Energy-resolved mass spectra were obtained by modulating the kinetic energy of the ions via adjustment of the sampling cone potential (V(cone)). Positive ion spectra of the CFCs (M) at low V(cone) show no signals due to either M(+)* or MH(+) but only those due to species [M - Cl](+) and CX(3)(+) (X = Cl, F), likely formed via C-Cl and C-C bond cleavages following ionization via charge exchange. Charge localization in the products of C-C bond cleavage in M(+)* is driven by the stability of the neutral fragment. At low V(cone) the hydrates [M - Cl](+)(H(2)O) are also observed. In the case of 1,1,2,-trichlorotrifluoroethane, [M - F](+) species also form as a result of ion-molecule reactions. As V(cone) is increased collision-induced dissociation of [M - Cl](+) and [M - F](+), i.e., the perhalogenated cations C(2)X(5)(+) (X = Cl, F), takes place via carbene elimination. In some cases such elimination is preceded or accompanied by rearrangements involving transfer of halogen from one carbon to the other. Evidence is also presented for the occurrence of a condensation reaction of C(2)Cl(3)F(2)(+) with water to form a C(2)Cl(2)F(2)HO(+) species via elimination of HCl. Negative ion spectra are dominated by Cl(-) and its ion-neutral complexes with M and with water. Additional components of the plasma include ion-neutral complexes O(3)(-)(M), the molecular anion M(-) (observed only with 1,1,2-trichlorotrifluoroethane), and an interesting species corresponding to [M - Cl + O](-). The origin and structure of these [M - Cl + O

  7. Characterizing the resolution and accuracy of a second-generation traveling-wave ion mobility separator for biomolecular ions.

    PubMed

    Zhong, Yueyang; Hyung, Suk-Joon; Ruotolo, Brandon T

    2011-09-07

    High-accuracy, high-resolution ion mobility measurements enable a vast array of important contemporary applications in biological chemistry. With the recent advent of both new, widely available commercial instrumentation and also new calibration datasets tailored for the aforementioned commercial instrumentation, the possibilities for extending such high performance measurements to a diverse set of applications have never been greater. Here, we assess the performance characteristics of a second-generation traveling-wave ion mobility separator, focusing on those figures of merit that lead to making measurements of collision cross-section having both high precision and high accuracy. Through performing a comprehensive survey of instrument parameters and settings, we find instrument conditions for optimized drift time resolution, cross-section resolution, and cross-section accuracy for a range of peptide, protein and multi-protein complex ions. Moreover, the conditions for high accuracy IM results are significantly different from those optimized for separation resolution, indicating that a balance between these two metrics must be attained for traveling wave IM separations of biomolecules. We also assess the effect of ion heating during IM separation on instrument performance.

  8. Modeling of a second-generation solar-driven Rankine air conditioner

    NASA Astrophysics Data System (ADS)

    Denius, M. W.; Batton, W. D.

    1984-07-01

    Ten configurations of a second-generation, solar-powered, Rankine-driven air conditioner were simulated and the data presented for use in companion studies. The results of the analysis show that the boiling-in-collector (BIC) configuration generates more power per collector area than the other configurations. The models used to simulate the configuration are presented. The generated data are also presented. Experimental work was done to both improve a novel refrigerant and oil lubrication system for the centrifugal compressor and investigate the aerodynamic unloading characteristics of the centrifugal compressor. The information generated was used to define possible turbo-gearbox configurations for use in the second generation computer simulation.

  9. Impact of air ions of both polarity on evaporation of certain organic and inorganic liquids

    NASA Astrophysics Data System (ADS)

    Barthakur, N. N.; Al-Kanani, T.

    1989-06-01

    Air ions of both polarity, produced by corona electrodes, were used to evaporate to dryness liquid samples of ethyl alcohol (EA), water (W), and carbon tetrachloride (CTC). Drying times were determined with a beta-ray gauge. Ion exposed samples of EA, W, and CTC dried, respectively, 2.3, 3.2, and 5.4 times faster than the corresponding control samples when exposed simultaneously to 0.94×1012 positive and 1.83×1012 negative air ions cm-2s-1 under the same laboratory conditions. Drying by corona discharge could be explained by three different mechanisms. Electric wind caused by the ionic drag is proposed as the principal driving force for the observed enhancement of evaporation. The decrease in free energy of a dielectric in the presence of an electric field compared to its absence may have increased the escaping tendency of the molecules of the treated liquids. The turbulence in the liquids created by the rotational effect on the dielectric molecules by the electric field may also be a factor in further enhancing the mass transfer rates from the samples.

  10. Collection of ethanolamines in air and determination by mobile phase ion chromatography

    SciTech Connect

    Bouyoucos, S.A.; Melcher, R.G.

    1986-03-01

    A method is described for the collection and determination of monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA) in air. Samples were collected by pulling air through a glass tube containing alumina, cleaned especially to remove interfering inorganic ions. The ethanolamines were desorbed with water and determined by Mobile Phase Ion Chromatography (MPIC). The recovery and total relative precision for MEA, DEA, and TEA - all collected from air at a flow rate of 100 mL/min for 7 hr - was 93.1 +/- 17%, 92.7 +/- 15% and 89.4 +/- 21%, respectively (95% confidence level). The method was validated for all three compounds from approximately the limit of detection (3 x noise) to ten times the limit of detection. Based on a sample size of 42 L, MEA was validated over the range from 0.12 to 3.0 ppm v/v (TLV=3), DEA over the range from 0.25 to 3.3 ppm v/v (TLV=3) and TEA from 0.31 to 3.7 ppm v/v (no TLV assigned). No effect on recovery was observed when sampling at high humidity or on storage of the samples for up to 31 days.

  11. GENERATION OF ELECTRIC CURRENTS IN THE CHROMOSPHERE VIA NEUTRAL-ION DRAG

    SciTech Connect

    Krasnoselskikh, V.; Vekstein, G.; Hudson, H. S.; Bale, S. D.; Abbett, W. P.

    2010-12-01

    We consider the generation of electric currents in the solar chromosphere where the ionization level is typically low. We show that ambient electrons become magnetized even for weak magnetic fields (30 G); that is, their gyrofrequency becomes larger than the collision frequency while ion motions continue to be dominated by ion-neutral collisions. Under such conditions, ions are dragged by neutrals, and the magnetic field acts as if it is frozen-in to the dynamics of the neutral gas. However, magnetized electrons drift under the action of the electric and magnetic fields induced in the reference frame of ions moving with the neutral gas. We find that this relative motion of electrons and ions results in the generation of quite intense electric currents. The dissipation of these currents leads to resistive electron heating and efficient gas ionization. Ionization by electron-neutral impact does not alter the dynamics of the heavy particles; thus, the gas turbulent motions continue even when the plasma becomes fully ionized, and resistive dissipation continues to heat electrons and ions. This heating process is so efficient that it can result in typical temperature increases with altitude as large as 0.1-0.3 eV km{sup -1}. We conclude that this process can play a major role in the heating of the chromosphere and corona.

  12. Determination of ion mobility in EHD flow zone of plasma generator

    NASA Astrophysics Data System (ADS)

    Sumariyah, Kusminarto, Hermanto, Arief; Nuswantoro, Pekik

    2015-12-01

    Determination has been carried out for ion mobility in EHD flow zone generated using a pin-concentric multiple ring electrodes and a pin-single ring electrode used as a comparator. The pin needle was made from stainless steel with a tip diameter of 0.18 mm. The concentris multiple ring electrode in form three/two concentric ring electrodes which made of metal material connected to each other. Each ring of three concentric ring electrode has a diameter of 24 mm, 16 mm and 8 mm. And each ring of two concentric ring electrode has a diameter of 24 mm and 16 mm. Single ring electrode has a diameter24 mm. The all ring has same of width and thickness were 2 mm and 3 mm. EHD was generated by using a DC high voltage of 10 kV. Pin functional as an active electrode of corona discharge while the all ring electrodes acted as ions collector and passive electrodes. The experimental results show that the ion current is proportional to V2 according to calculations by Chouelo for hyperbolic-field approach. Ion mobility obtained from the quadratic polynomial fitting of experimental data were current and voltage as well as Choelo formulation. The results showed that the mobility of ions in the EHD flow zones utilizing pin-consentric multiple ring electrode larger than utilizing pin-single ring electrode. Pin-three Consentic ring electrode has the largest of ion mobility

  13. Toward the next generation of air quality monitoring: Mercury

    NASA Astrophysics Data System (ADS)

    Pirrone, Nicola; Aas, Wenche; Cinnirella, Sergio; Ebinghaus, Ralf; Hedgecock, Ian M.; Pacyna, Jozef; Sprovieri, Francesca; Sunderland, Elsie M.

    2013-12-01

    understanding the link between the magnitude of mercury emissions and the concentrations found in the fish that we consume. For air quality monitoring, priorities include expanding the existing data collection network and widening the scope of atmospheric mercury measurements (elemental, oxidised, and particulate species as well as mercury in precipitation). Presently, the only accurate indicators of mercury impacts on human and biological health are methylmercury concentrations in biota. However, recent advances in analytical techniques (stable mercury isotopes) and integrated modelling tools are allowing greater understanding of the relationship between atmospheric deposition, concentrations in water, methylation and uptake by biota. This article recommends an expansion of the current atmospheric monitoring network and the establishment of new coordinated measurements of total mercury and methylmercury concentrations in seawater and concurrent concentrations and trends in marine fish.

  14. Future's operation areas: new-generation suppression enemy air defence (SEAD) elements

    NASA Astrophysics Data System (ADS)

    Hazinedar, Ä.°lker

    2015-05-01

    Since air vehicles took place in the theater of operations, they have become the indispensable elements and the strongest attack power of armed forces. In the following period, with technological development, supersonic aircrafts took place in the operation area and this increased effectiveness of air vehicles much more. Air forces have used these aircrafts during important missions like strategic attack and air defense operations. On the other hand, decision makers understood that it was not feasible to intercept fighter aircrafts by executing combat air patrol flight missions. Since there is not enough reaction time to intercept the high speed aircrafts, ground stationed Surface to Air Missiles (SAM) system requirement has emerged. Therefore, SAM systems took place in the operation scene as well. Due to the fact that SAM systems emerged against the attack power, the attack aircrafts are to keep away from the fire of the ground stationed SAM systems. Hence, the requirement of Suppression Enemy Air Defense (SEAD) arose. SEAD elements take under suppression the radar of the SAM systems. In this way, attack aircrafts are able to attack without the risk of SAM systems. The purpose of this study is to find new methods or concepts in order to protect friendly attack aircrafts against ground based surface to air missiles' fires. Modernization of SAM systems and new generation SAM system producing activities have proceeded with positive acceleration. So, current SEAD elements and concepts are not able to cover the requirements due to the increased SAM system ranges. According to the concepts, SEAD weapons` ranges must be longer than the SAM weapons' ranges to protect friendly aircrafts. In this study, new concept was offered to overcome the deficiencies of current SEAD concept. The elements of new concepts were put forward. Classic SEAD concept and new generation concepts were assessed by using SWOT analysis technique. As a result, this study has revealed that, air forces

  15. Development of a plasma generator for a long pulse ion source for neutral beam injectors

    SciTech Connect

    Watanabe, K.; Dairaku, M.; Tobari, H.; Kashiwagi, M.; Inoue, T.; Hanada, M.; Jeong, S. H.; Chang, D. H.; Kim, T. S.; Kim, B. R.; Seo, C. S.; Jin, J. T.; Lee, K. W.; In, S. R.; Oh, B. H.; Kim, J.; Bae, Y. S.

    2011-06-15

    A plasma generator for a long pulse H{sup +}/D{sup +} ion source has been developed. The plasma generator was designed to produce 65 A H{sup +}/D{sup +} beams at an energy of 120 keV from an ion extraction area of 12 cm in width and 45 cm in length. Configuration of the plasma generator is a multi-cusp bucket type with SmCo permanent magnets. Dimension of a plasma chamber is 25 cm in width, 59 cm in length, and 32.5 cm in depth. The plasma generator was designed and fabricated at Japan Atomic Energy Agency. Source plasma generation and beam extraction tests for hydrogen coupling with an accelerator of the KSTAR ion source have been performed at the KSTAR neutral beam test stand under the agreement of Japan-Korea collaborative experiment. Spatial uniformity of the source plasma at the extraction region was measured using Langmuir probes and {+-}7% of the deviation from an averaged ion saturation current density was obtained. A long pulse test of the plasma generation up to 200 s with an arc discharge power of 70 kW has been successfully demonstrated. The arc discharge power satisfies the requirement of the beam production for the KSTAR NBI. A 70 keV, 41 A, 5 s hydrogen ion beam has been extracted with a high arc efficiency of 0.9 -1.1 A/kW at a beam extraction experiment. A deuteron yield of 77% was measured even at a low beam current density of 73 mA/cm{sup 2}.

  16. Novel methods for improvement of a Penning ion source for neutron generator applications.

    PubMed

    Sy, A; Ji, Q; Persaud, A; Waldmann, O; Schenkel, T

    2012-02-01

    Penning ion source performance for neutron generator applications is characterized by the atomic ion fraction and beam current density, providing two paths by which source performance can be improved for increased neutron yields. We have fabricated a Penning ion source to investigate novel methods for improving source performance, including optimization of wall materials and electrode geometry, advanced magnetic confinement, and integration of field emitter arrays for electron injection. Effects of several electrode geometries on discharge characteristics and extracted ion current were studied. Additional magnetic confinement resulted in a factor of two increase in beam current density. First results indicate unchanged proton fraction and increased beam current density due to electron injection from carbon nanofiber arrays.

  17. Anomalous electron heating and energy balance in an ion beam generated plasma

    SciTech Connect

    Guethlein, G.

    1987-04-01

    The plasma described in this report is generated by a 15 to 34 kV ion beam, consisting primarily of protons, passing through an H/sub 2/ gas cell neutralizer. Plasma ions (or ion-electron pairs) are produced by electron capture from (or ionization of) gas molecules by beam ions and atoms. An explanation is provided for the observed anomalous behavior of the electron temperature (T/sub e/): a step-lite, nearly two-fold jump in T/sub e/ as the beam current approaches that which minimizes beam angular divergence; insensitivity of T/sub e/ to gas pressure; and the linear relation of T/sub e/ to beam energy.

  18. Femtosecond-laser-induced shockwaves in water generated at an air-water interface.

    PubMed

    Strycker, B D; Springer, M M; Traverso, A J; Kolomenskii, A A; Kattawar, G W; Sokolov, A V

    2013-10-07

    We report generation of femtosecond-laser-induced shockwaves at an air-water interface by millijoule femtosecond laser pulses. We document and discuss the main processes accompanying this phenomenon, including light emission, development of the ablation plume in the air, formation of an ablation cavity, and, subsequently, a bubble developing in water. We also discuss the possibility of remotely controlling the characteristics of laser-induced sound waves in water through linear acoustic superposition of sound waves that results from millijoule femtosecond laser-pulse interaction with an air-water interface, thus opening up the possibility of remote acoustic applications in oceanic and riverine environments.

  19. Relative Stability of Peptide Sequence Ions Generated by Tandem Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Bythell, Benjamin J.; Hendrickson, Christopher L.; Marshall, Alan G.

    2012-04-01

    We report the use of unimolecular dissociation by infrared radiation for gaseous multiphoton energy transfer to determine relative activation energy (Ea,laser) for dissociation of peptide sequence ions. The sequence ions of interest are mass-isolated; the entire ion cloud is then irradiated with a continuous wave CO2 laser, and the first order rate constant, kd, is determined for each of a series of laser powers. Provided these conditions are met, a plot of the natural logarithm of kd versus the natural logarithm of laser power yields a straight line, whose slope provides a measure of Ea,laser. This method reproduces the Ea values from blackbody radiative dissociation (BIRD) for the comparatively large, singly and doubly protonated bradykinin ions (nominally y 9 and y 9 2+ ). The comparatively small sequence ion systems produce Ea,laser values that are systematic underestimates of theoretical barriers calculated with density functional theory (DFT). However, the relative Ea,laser values are in qualitative agreement with the mobile proton model and available theory. Additionally, novel protonated cyclic-dipeptide (diketopiperazine) fragmentation reactions are analyzed with DFT. FT-ICR MS provides access to sequence ions generated by electron capture dissociation, infrared multiphoton dissociation, and collisional activation methods (i.e., b n , y m , c n , z m • ions).

  20. Ion chemistry for the detection of isoprene and other volatile organic compounds in ambient air

    NASA Astrophysics Data System (ADS)

    Leibrock, Edeltraud; Huey, L. Gregory

    2000-06-01

    A chemical ionization mass spectrometer (CIMS) and a flowing afterglow apparatus were used to study reactions of benzene cations (C6H6+ and (C6H6)2+) with a series of volatile organic compounds (VOCs). Both cations react at the collision rate with compounds of lower ionization potential than benzene, such as isoprene (C5H8), other conjugated dienes, and aromatics. These ions are generally unreactive with substances of higher ionization potential such as alkanes, simple alcohols, simple carbonyls, etc. The results demonstrate that C6H6+ and (C6H6)2+ are excellent reagent ions for the sensitive detection of isoprene in air with a CIMS. However, 2-methyl-3-buten-2-ol (MBO) and C5H8 conjugated dienes were identified as potential interferences to this technique. This indicates that the selectivity of the CIMS isoprene measurement must be tested by intercomparison with well-established methods, e.g. gas chromatography techniques.

  1. High-resolution ion pulse ionization chamber with air filling for the 222Rn decays detection

    NASA Astrophysics Data System (ADS)

    Gavrilyuk, Yu. M.; Gangapshev, A. M.; Gezhaev, A. M.; Etezov, R. A.; Kazalov, V. V.; Kuzminov, V. V.; Panasenko, S. I.; Ratkevich, S. S.; Tekueva, D. A.; Yakimenko, S. P.

    2015-11-01

    The construction and characteristics of the cylindrical ion pulse ionization chamber (CIPIC) with a working volume of 3.2 L are described. The chamber is intended to register α-particles from the 222Rn and its daughter's decays in the filled air sample. The detector is less sensitive to electromagnetic pick-ups and mechanical noises. The digital pulse processing method is proposed to improve the energy resolution of the ion pulse ionization chamber. An energy resolution of 1.6% has been achieved for the 5.49 MeV α-line. The dependence of the energy resolution on high voltage and working media pressure has been investigated and the results are presented.

  2. Field Observation of the Green Ocean Amazon. Neutral Cluster Air Ion Spectrometer (NAIS) Final Campaign Summary

    SciTech Connect

    Petaja, T.; Backman, J.; Manninen, H. E.; Wimmer, D.

    2016-03-01

    The neutral cluster and air ion spectrometer (NAIS) was deployed to the T3 site for Intensive Operations Periods 1 and 2 (IOP1 and IOP2). The NAIS is an instrument that measures aerosol particle and ion number size distributions in the mobility diameter range of 0.8 to 42 nm, corresponding to electrical mobility range between 3.2 and 0.0013 cm2 V-1 s-1. New particle formation (NPF) events were detected using the NAIS at the T3 field site during IOP1 and IOP2. Secondary NPF is a globally important source of aerosol number. To fully explain atmospheric NPF and subsequent growth, we need to directly measure the initial steps of the formation processes in different environments, including rain forest. Particle formation characteristics, such as formation and growth rates, were used as indicators of the relevant processes and participating compounds in the initial formation. In a case of parallel ion and neutral cluster measurements, we estimated the relative contribution of ion-induced and neutral nucleation to the total particle formation.

  3. Generation 6 Li-Ion Cell Vibration Testing at ABSL Space Products

    NASA Astrophysics Data System (ADS)

    Defer, M.; Borthomieu, Y.; Ligneel, E.; Badet, S.

    2014-08-01

    This paper presents the design of Saft's Generation6 Li-Ion cell, the main challenges in the course of the development, the main BOL characteristics and performances achieved during the development program. Finally, it also describes how this cell fits in Saft's battery range and the benefits of it.

  4. Design, simulation and evaluation of improved air amplifier incorporating an ion funnel for nano-ESI MS.

    PubMed

    Jurcicek, Petr; Liu, Lingpeng; Zou, Helin; An, Zhiqi; Xiao, Hongbin

    2014-01-01

    An improved air amplifier design that takes advantage of the combined effects of aerodynamic and electrodynamic focusing was developed to couple a nanoelectrospray ionisation (nano-ESI) source and the heated mass spectrometer inlet to improve the sensitivity of a mass spectrometer. The new design comprises an electrodynamic ion funnel integrated into the main air pathway of the air amplifier to more effectively focus and transmit gas-phase ions from the nano-ESI source into the heated mass spectrometer inlet. Numerical computational fluid dynamics simulations were carried out using a commercial software package, ANSYS FLUENT, to provide more detailed information about the device's performance. The gas flow field as well as the electric field patterns and the Lagrangian ion motion were conveniently simulated using this single package and custom-written, user-defined functions. Experimental results show a nearly five-fold improvement in reserpine ion intensity with the air amplifier operated at a nitrogen gauge pressure of 40 kPa and no direct current (DC) or radiofrequency (RF) potentials applied to the ion funnel when the distance between the electrospray emitter and sampling inlet tube was 24 mm, as compared to direct sample infusion from the same distance without the air amplifier. More importantly, a nearly three-fold additional gain in ion intensity was measured when both DC and RF potentials were co-applied, resulting in more than a 13-fold overall ion intensity gain which could be attributed to the combined air amplifier aerodynamic and ion funnel electrodynamic focusing effect.

  5. Research progress on ionic plasmas generated in an intense hydrogen negative ion source

    SciTech Connect

    Takeiri, Y. Tsumori, K.; Nagaoka, K.; Kaneko, O.; Ikeda, K.; Nakano, H.; Kisaki, M.; Tokuzawa, T.; Osakabe, M.; Kondo, T.; Sato, M.; Shibuya, M.; Komada, S.; Sekiguchi, H.; Geng, S.

    2015-04-08

    Characteristics of ionic plasmas, observed in a high-density hydrogen negative ion source, are investigated with a multi-diagnostics system. The ionic plasma, which consists of hydrogen positive- and negative-ions with a significantly low-density of electrons, is generated in the ion extraction region, from which the negative ions are extracted through the plasma grid. The negative ion density, i.e., the ionic plasma density, as high as the order of 1×10{sup 17}m{sup −3}, is measured with cavity ring-down spectroscopy, while the electron density is lower than 1×10{sup 16}m{sup −3}, which is confirmed with millimeter-wave interferometer. Reduction of the negative ion density is observed at the negative ion extraction, and at that time the electron flow into the ionic plasma region is observed to conserve the charge neutrality. Distribution of the plasma potential is measured in the extraction region in the direction normal to the plasma grid surface with a Langmuir probe, and the results suggest that the sheath is formed at the plasma boundary to the plasma grid to which the bias voltage is applied. The beam extraction should drive the negative ion transport in the ionic plasma across the sheath formed on the extraction surface. Larger reduction of the negative ions at the beam extraction is observed in a region above the extraction aperture on the plasma grid, which is confirmed with 2D image measurement of the Hα emission and cavity ring-down spectroscopy. The electron distribution is also measured near the plasma grid surface. These various properties observed in the ionic plasma are discussed.

  6. The role of high Rydberg states in the generation of negative ions in negative-ion discharges

    SciTech Connect

    Hiskes, J.R.

    1995-11-28

    The generation of substantial yields of H{sup {minus}} ions in a laser excited H{sub 2} gas has been reported by Pinnaduwage and Christoforu. These H{sup {minus}} yields have been attributed to (2 + 1) REMP photoexcitation processes leading to dissociative attachment of doubly-excited or superexcited states (SES), or dissociative attachment of high Rydberg product states. The new feature of these experiments is the implied large dissociative attachment rates, of order 10{sup {minus}6} cm{sup 3} sec{sup {minus}1}, values that are orders-of-magnitude larger than the dissociative attachment of the vibrationally excited levels of the ground electronic state. While these laser excitations are not directly applicable to a hydrogen negative-ion discharge, the implication of large dissociative attachment rates to the high Rydberg states may affect both the total negative-ion density and the interpretation of discharge performance. Within the discharge energetic electrons will collisionally excite the higher Rydberg states, and the relative contribution of the dissociative attachment of these states when compared with the dissociative attachment to the ground state vibrational levels, is the topic of this paper.

  7. A Permanent-Magnet Microwave Ion Source for a Compact High-Yield Neutron Generator

    SciTech Connect

    Waldmann, Ole; Ludewigt, Bernhard

    2010-10-11

    We present recent work on the development of a microwave ion source that will be used in a high-yield compact neutron generator for active interrogation applications. The sealed tube generator will be capable of producing high neutron yields, 5x1011 n/s for D-T and ~;;1x1010 n/s for D-D reactions, while remaining transportable. We constructed a microwave ion source (2.45 GHz) with permanent magnets to provide the magnetic field strength of 87.5 mT necessary for satisfying the electron cyclotron resonance (ECR) condition. Microwave ion sources can produce high extracted beam currents at the low gas pressures required for sealed tube operation and at lower power levels than previously used RF-driven ion sources. A 100 mA deuterium/tritium beam will be extracted through a large slit (60x6 mm2) to spread the beam power over a larger target area. This paper describes the design of the permanent-magnet microwave ion source and discusses the impact of the magnetic field design on the source performance. The required equivalent proton beam current density of 40 mA/cm2 was extracted at a moderate microwave power of 400 W with an optimized magnetic field.

  8. A new-generation 3D ozone FACE (Free Air Controlled Exposure).

    PubMed

    Paoletti, Elena; Materassi, Alessandro; Fasano, Gianni; Hoshika, Yasutomo; Carriero, Giulia; Silaghi, Diana; Badea, Ovidiu

    2017-01-01

    To artificially simulate the impacts of ground-level ozone (O3) on vegetation, ozone FACE (Free Air Controlled Exposure) systems are increasingly recommended. We describe here a new-generation, three-dimensional ozone FACE, with O3 diffusion through laser-generated micro-holes, pre-mixing of air and O3, O3 generator with integral oxygen generator, continuous (day/night) exposure and full replication. Based on three O3 levels and assumptions on the pre-industrial O3 levels, we describe principles to calculate relative yield/biomass and estimate impacts even at lower-than-ambient O3 levels. The case study is called FO3X, and is at present the only ozone FACE in Mediterranean climate and one of the very few ozone FACEs investigating more than one stressor at a time. The results presented here will give further impulse to the research on O3 impacts on vegetation all over the world.

  9. Second-generation sequencing of forensic STRs using the Ion Torrent™ HID STR 10-plex and the Ion PGM™.

    PubMed

    Fordyce, Sarah L; Mogensen, Helle Smidt; Børsting, Claus; Lagacé, Robert E; Chang, Chien-Wei; Rajagopalan, Narasimhan; Morling, Niels

    2015-01-01

    Second-generation sequencing (SGS) using Roche/454 and Illumina platforms has proved capable of sequencing the majority of the key forensic genetic STR systems. Given that Roche has announced that the 454 platforms will no longer be supported from 2015, focus should now be shifted to competing SGS platforms, such as the MiSeq (Illumina) and the Ion Personal Genome Machine (Ion PGM™; Thermo Fisher). There are currently several challenges faced with amplicon-based SGS STR typing in forensic genetics, including current lengths of amplicons for CE-typing and lack of uniform data analysis between laboratories. Thermo Fisher has designed a human identification (HID) short tandem repeat (STR) 10-plex panel including amelogenin, CSF1PO, D16S539, D3S1358, D5S818, D7S820, D8S1179, TH01, TPOX and vWA, where the primers have been designed specifically for the purpose of SGS and the data analysis is supported by Ion Torrent™ software. Hence, the combination of the STR 10-plex and the Ion PGM™ represents the first fully integrated SGS STR typing solution from PCR to data analysis. In this study, four experiments were performed to evaluate the alpha-version of the STR 10-plex: (1) typing of control samples; (2) analysis of sensitivity; (3) typing of mixtures; and (4) typing of biological crime case samples. Full profiles and concordant results between replicate SGS runs and CE-typing were observed for all control samples. Full profiles were seen with DNA input down to 50 pg, with the exception of a single locus drop-out in one of the 100 pg dilutions. Mixtures were easily deconvoluted down to 20:1, although alleles from the minor contributor had to be identified manually as some signals were not called by the Ion Torrent™ software. Interestingly, full profiles were obtained for all biological samples from real crime and identification cases, in which only partial profiles were obtained with PCR-CE assays. In conclusion, the Ion Torrent™ HID STR 10-plex panel offers an

  10. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  11. Detection and removal of impurities in nitric oxide generated from air by pulsed electrical discharge.

    PubMed

    Yu, Binglan; Blaesi, Aron H; Casey, Noel; Raykhtsaum, Grigory; Zazzeron, Luca; Jones, Rosemary; Morrese, Alexander; Dobrynin, Danil; Malhotra, Rajeev; Bloch, Donald B; Goldstein, Lee E; Zapol, Warren M

    2016-11-30

    Inhalation of nitric oxide (NO) produces selective pulmonary vasodilation without dilating the systemic circulation. However, the current NO/N2 cylinder delivery system is cumbersome and expensive. We developed a lightweight, portable, and economical device to generate NO from air by pulsed electrical discharge. The objective of this study was to investigate and optimize the purity and safety of NO generated by this device. By using low temperature streamer discharges in the plasma generator, we produced therapeutic levels of NO with very low levels of nitrogen dioxide (NO2) and ozone. Despite the low temperature, spark generation eroded the surface of the electrodes, contaminating the gas stream with metal particles. During prolonged NO generation there was gradual loss of the iridium high-voltage tip (-90 μg/day) and the platinum-nickel ground electrode (-55 μg/day). Metal particles released from the electrodes were trapped by a high-efficiency particulate air (HEPA) filter. Quadrupole mass spectroscopy measurements of effluent gas during plasma NO generation showed that a single HEPA filter removed all of the metal particles. Mice were exposed to breathing 50 parts per million of electrically generated NO in air for 28 days with only a scavenger and no HEPA filter; the mice did not develop pulmonary inflammation or structural changes and iridium and platinum particles were not detected in the lungs of these mice. In conclusion, an electric plasma generator produced therapeutic levels of NO from air; scavenging and filtration effectively eliminated metallic impurities from the effluent gas.

  12. A study of single and binary ion plasma expansion into laboratory-generated plasma wakes

    NASA Technical Reports Server (NTRS)

    Wright, Kenneth Herbert, Jr.

    1988-01-01

    Plasma expansion into the wake of a large rectangular plate immersed in a collisionless, supersonic plasma was investigated in laboratory experiments. The experimental conditions address both single ion and binary ion plasma flows for the case of a body whose size is large in comparison with the Debye length, when the potential difference between the body and the plasma is relatively small. A new plasma source was developed to generate equi-velocity, binary ion plasma flows, which allows access to new parameter space that have previously been unavailable for laboratory studies. Specifically, the new parameters are the ionic mass ratio and the ionic component density ratio. In a series of experiments, a krypton-neon plasma is employed where the ambient density ratio of neon to krypton is varied more than an order of magnitude. The expansion in both the single ion and binary ion plasma cases is limited to early times, i.e., a few ion plasma periods, by the combination of plasma density, plasma drift speed, and vacuum chamber size, which prevented detailed comparison with self-similar theory.

  13. Intense ion beam generation, plasma radiation source and plasma opening switch research

    NASA Astrophysics Data System (ADS)

    Hammer, D. A.; Coleman, M. D.; Qi, N.; Similon, P. L.; Sudan, R. N.

    1989-04-01

    This report describes research on intense ion beam diodes, plasma opening switches and dense z-pinch plasma radiators. Laser induced fluorescence spectroscopy has been used to map the electrostatic potential profile in a plasma-prefilled magnetically insulated ion diode. In a simple planar diode, the measured profile is inconsistent with the electrons being confined in a sheath near the cathode by the magnetic field. Rather, the profile implies the presence of electrons throughout the accelerating gap. A theoretical model of the penetration of current and magnetic field into a plasma, and of the current-driven effective collision frequency has been developed. The snowplow action of the rising magnetic field causes a steep rise in the plasma density at the leading edge. The subsequent multistreaming of the ions caused by ion reflection at the current layer could lead to ion heating through collective effects. The two-dimensional electron flow in the plasma cathode vacuum gap is also treated. Dense z-pinch plasma radiation source experiments have been initiated on the LION accelerator using gas puff and fine wire loads. The x-pinch was found to be a more effective way to generate soft x-rays than a single wire pinch or a gas puff implosion. Plasma opening switch experiments being initiated, and plasma anode ion diode development work being terminated are also briefly described.

  14. Direct Depth- and Lateral- Imaging of Nanoscale Magnets Generated by Ion Impact

    PubMed Central

    Röder, Falk; Hlawacek, Gregor; Wintz, Sebastian; Hübner, René; Bischoff, Lothar; Lichte, Hannes; Potzger, Kay; Lindner, Jürgen; Fassbender, Jürgen; Bali, Rantej

    2015-01-01

    Nanomagnets form the building blocks for a variety of spin-transport, spin-wave and data storage devices. In this work we generated nanoscale magnets by exploiting the phenomenon of disorder-induced ferromagnetism; disorder was induced locally on a chemically ordered, initially non-ferromagnetic, Fe60Al40 precursor film using  nm diameter beam of Ne+ ions at 25 keV energy. The beam of energetic ions randomized the atomic arrangement locally, leading to the formation of ferromagnetism in the ion-affected regime. The interaction of a penetrating ion with host atoms is known to be spatially inhomogeneous, raising questions on the magnetic homogeneity of nanostructures caused by ion-induced collision cascades. Direct holographic observations of the flux-lines emergent from the disorder-induced magnetic nanostructures were made in order to measure the depth- and lateral- magnetization variation at ferromagnetic/non-ferromagnetic interfaces. Our results suggest that high-resolution nanomagnets of practically any desired 2-dimensional geometry can be directly written onto selected alloy thin films using a nano-focussed ion-beam stylus, thus enabling the rapid prototyping and testing of novel magnetization configurations for their magneto-coupling and spin-wave properties. PMID:26584789

  15. Direct patterning of vortex generators on a fiber tip using a focused ion beam.

    PubMed

    Vayalamkuzhi, Pramitha; Bhattacharya, Shanti; Eigenthaler, Ulrike; Keskinbora, Kahraman; Samlan, C T; Hirscher, Michael; Spatz, Joachim P; Viswanathan, Nirmal K

    2016-05-15

    The realization of spiral phase optical elements on the cleaved end of an optical fiber by focused ion beam milling is presented. A focused Ga+ ion beam with an acceleration voltage of 30 keV is used to etch continuous spiral phase plates and fork gratings directly on the tip of the fiber. The phase characteristics of the output beam generated by the fabricated structures measured via an interference experiment confirmed the presence of phase singularity in the output beam. The devices are expected to be promising candidates for all-fiber beam shaping and optical trapping applications.

  16. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    SciTech Connect

    Johnson, Michael J.; Go, David B.

    2015-12-28

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ∼30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (<30 V) to generate breakdown in air without the need for conventional high-voltage electrical equipment. Piezoelectric transformers (PTs) use their inherent electromechanical resonance to produce a voltage amplification, such that the surface of the piezoelectric exhibits a large surface voltage that can generate corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  17. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    NASA Astrophysics Data System (ADS)

    Johnson, Michael J.; Go, David B.

    2015-12-01

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ˜30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (<30 V) to generate breakdown in air without the need for conventional high-voltage electrical equipment. Piezoelectric transformers (PTs) use their inherent electromechanical resonance to produce a voltage amplification, such that the surface of the piezoelectric exhibits a large surface voltage that can generate corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  18. The effect of exposure to negative air ions on the recovery of physiological responses after moderate endurance exercise

    NASA Astrophysics Data System (ADS)

    Ryushi, T.; Kita, Ichirou; Sakurai, Tomonobu; Yasumatsu, Mikinobu; Isokawa, Masanori; Aihara, Yasutugu; Hama, Kotaro

    This study examined the effects of negative air ion exposure on the human cardiovascular and endocrine systems during rest and during the recovery period following moderate endurance exercise. Ten healthy adult men were studied in the presence (8,000-10,000 cm-3) or absence (200-400 cm-3) of negative air ions (25° C, 50% humidity) after 1 h of exercise. The level of exercise was adjusted to represent a 50-60% load compared with the subjects' maximal oxygen uptake, which was determined using a bicycle ergometer in an unmodified environment (22-23° C, 30-35% humidity, 200-400 negative air ions.cm-3). The diastolic blood pressure (DBP) values during the recovery period were significantly lower in the presence of negative ions than in their absence. The plasma levels of serotonin (5-HT) and dopamine (DA) were significantly lower in the presence of negative ions than in their absence. These results demonstrated that exposure to negative air ions produced a slow recovery of DBP and decreases in the levels of 5-HT and DA in the recovery period after moderate endurance exercise. 5-HT is thought to have contributed to the slow recovery of DBP.

  19. Effects of impregnated metal ions on air/CO2-gasification of woody biomass.

    PubMed

    Hurley, Scott; Li, Hanning; Xu, Chunbao Charles

    2010-12-01

    Several impregnated metal ions (Fe (III), Co (II), Ni (II), and Ru (IV)) and a raw iron ore (natural limonite) were examined as catalysts for gasification of pine sawdust in air/CO(2) at 700 and 800 degrees C. The yields of char and tar both increased with increasing CO(2) content in the feed gas. All the impregnated metal ions, in particular Ni (II), Co (II) and Ru (IV), were very effective for promoting biomass gasification in CO(2), leading to greatly reduced yields of tar and char accompanied by significantly enhanced formation of CO and H(2). At 800 degrees C, the impregnation of Fe (III), Ni (II), Co (II) or Ru (IV) led to almost complete conversion of the solid biomass into gas/liquid products, producing an extremely low char yield (<1-4 wt.%), and a very high yield of combustible gas (from 51.7 wt.% for Fe to 84 wt.% for Ru). The tar yield reduced from 32.1 wt.% without catalyst to 19-27 wt.% with the impregnated metal ions.

  20. Development of a Permanent-Magnet Microwave Ion Source for a Sealed-Tube Neutron Generator

    SciTech Connect

    Waldmann, Ole; Ludewigt, Bernhard

    2011-03-31

    A microwave ion source has been designed and constructed for use with a sealed-tube, high-yield neutron generator. When operated with a tritium-deuterium gas mixture the generator will be capable of producing 5*1011 n/s in non-proliferation applications. Microwave ion sources are well suited for such a device because they can produce high extracted beam currents with a high atomic fraction at low gas pressures of 0.2-0.3 Pa required for sealed tube operation. The magnetic field strength for achieving electron cyclotron resonance (ECR) condition, 87.5 mT at 2.45 GHz microwave frequency, was generated and shaped with permanent magnets surrounding the plasma chamber and a ferromagnetic plasma electrode. This approach resulted in a compact ion source that matches the neutron generator requirements. The needed proton-equivalent extracted beam current density of 40 mA/cm^2 was obtained at moderate microwave power levels of 400 W. Results on magnetic field design, pressure dependency and atomic fraction measured for different wall materials are presented.

  1. Formation of Langmuir Monolayers of Titanium Dioxide Nanoparticles at Air/Aqueous Interfaces by the Addition of Ions to the Subphase: Effect of Ion Concentration and Type.

    PubMed

    Iwafuji, Yuya; McNamee, Cathy E

    2015-09-17

    A Langmuir monolayer of bare, hydrophilic TiO2 nanoparticles (diameter = 75 nm) was formed at an air/pH 5.8 aqueous interface by adding salt to the subphase. The effect of the concentration and type of salt in the subphase on the surface pressure-area per particle isotherms was determined. Increasing the concentration of NaCl from 0 to 3.8 M increased the maximum surface pressure (Πmax) and shifted the isotherms to a larger area per particle. The ion type also affected the area at which the close packing commenced and the value of Πmax. The presence of salt in the subphase also stabilized SiO2 nanoparticles, suggesting that the ions in the subphase interacted with the dioxide groups on the particles. The combination of structure making or borderline ions with structure breaking ions (LiCl, MgCl2, NaCl, and CaCl2) appeared to stabilize the particulate monolayers more than the combination of structure breaking ions (KBr and KCl). These results suggested that the particles were stabilized by a hydrogen bond network between the particles or the formation of a salt bridge between the particles. Attractions between particles at the air/aqueous interface caused the particles to aggregate, resulting in the particles becoming more stable at the air/aqueous interface.

  2. Are clusters important in understanding the mechanisms in atmospheric pressure ionization? Part 1: Reagent ion generation and chemical control of ion populations.

    PubMed

    Klee, Sonja; Derpmann, Valerie; Wißdorf, Walter; Klopotowski, Sebastian; Kersten, Hendrik; Brockmann, Klaus J; Benter, Thorsten; Albrecht, Sascha; Bruins, Andries P; Dousty, Faezeh; Kauppila, Tiina J; Kostiainen, Risto; O'Brien, Rob; Robb, Damon B; Syage, Jack A

    2014-08-01

    It is well documented since the early days of the development of atmospheric pressure ionization methods, which operate in the gas phase, that cluster ions are ubiquitous. This holds true for atmospheric pressure chemical ionization, as well as for more recent techniques, such as atmospheric pressure photoionization, direct analysis in real time, and many more. In fact, it is well established that cluster ions are the primary carriers of the net charge generated. Nevertheless, cluster ion chemistry has only been sporadically included in the numerous proposed ionization mechanisms leading to charged target analytes, which are often protonated molecules. This paper series, consisting of two parts, attempts to highlight the role of cluster ion chemistry with regard to the generation of analyte ions. In addition, the impact of the changing reaction matrix and the non-thermal collisions of ions en route from the atmospheric pressure ion source to the high vacuum analyzer region are discussed. This work addresses such issues as extent of protonation versus deuteration, the extent of analyte fragmentation, as well as highly variable ionization efficiencies, among others. In Part 1, the nature of the reagent ion generation is examined, as well as the extent of thermodynamic versus kinetic control of the resulting ion population entering the analyzer region.

  3. Ion beam-generated surface ripples: new insight in the underlying mechanism

    NASA Astrophysics Data System (ADS)

    Kumar, Tanuj; Kumar, Ashish; Agarwal, Dinesh Chander; Lalla, Nirnajan Prasad; Kanjilal, Dinakar

    2013-07-01

    A new hydrodynamic mechanism is proposed for the ion beam-induced surface patterning on solid surfaces. Unlike the standard mechanisms based on the ion beam impact-generated erosion and mass redistribution at the free surface (proposed by Bradley-Harper and its extended theories), the new mechanism proposes that the incompressible solid flow in amorphous layer leads to the formation of ripple patterns at the amorphous-crystalline (a/c) interface and hence at the free surface. Ion beam-stimulated solid flow inside the amorphous layer probably controls the wavelength, whereas the amount of material transported and re-deposited at a/c interface control the amplitude of ripples.

  4. Energy distribution of runaway electrons generated by a nanosecond discharge in atmospheric-pressure air

    NASA Astrophysics Data System (ADS)

    Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Kostyrya, I. D.; Lomaev, M. I.; Petin, V. K.; Rybka, D. V.; Shlyakhtun, S. V.

    2008-12-01

    The spectra of an ultrashort avalanche electron beam generated by a nanosecond discharge in atmospheric-pressure air were investigated. The temporal characteristics of the beam current pulses, gap voltage, and discharge current in a gas diode were measured with a time resolution of ˜0.1 ns. A simple technique was developed for recovering electron spectra from the curves of beam attenuation by aluminum foils. The effect of the cathode design, electrode gap length, and generator parameters on the electron spectra were studied using seven setups. It is shown that generation of electrons with anomalously high energies requires the use of cathodes with increased curvature radius.

  5. Energy distribution of runaway electrons generated by a nanosecond discharge in atmospheric-pressure air

    SciTech Connect

    Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Kostyrya, I. D.; Lomaev, M. I.; Petin, V. K.; Rybka, D. V.; Shlyakhtun, S. V.

    2008-12-15

    The spectra of an ultrashort avalanche electron beam generated by a nanosecond discharge in atmospheric-pressure air were investigated. The temporal characteristics of the beam current pulses, gap voltage, and discharge current in a gas diode were measured with a time resolution of {approx}0.1 ns. A simple technique was developed for recovering electron spectra from the curves of beam attenuation by aluminum foils. The effect of the cathode design, electrode gap length, and generator parameters on the electron spectra were studied using seven setups. It is shown that generation of electrons with anomalously high energies requires the use of cathodes with increased curvature radius.

  6. Ion beam generated modes in the lower hybrid frequency range in a laboratory magnetoplasma

    NASA Astrophysics Data System (ADS)

    Van Compernolle, B.; Tripathi, S.; Gekelman, W. N.; Colestock, P. L.; Pribyl, P.

    2012-12-01

    The generation of waves by ion ring distributions is of great importance in many instances in space plasmas. They occur naturally in the magnetosphere through the interaction with substorms, or they can be man-made in ionospheric experiments by photo-ionization of neutral atoms injected perpendicular to the earth's magnetic field. The interaction of a fast ion beam with a low β plasma has been studied in the laboratory. Experiments were performed at the LArge Plasma Device (LAPD) at UCLA. The experiments were done in a Helium plasma (n ≃ 1012 \\ cm-3, B0 = 1000 G - 1800 G, fpe}/f{ce ≃ 1 - 5, Te = 0.25\\ eV, vte ≤ vA). The ion beam \\cite{Tripathi_ionbeam} is a Helium beam with energies ranging from 5 keV to 18 keV. The fast ion velocity is on the order of the Alfvén velocity. The beam is injected from the end of the machine, and spirals down the linear device. Waves were observed below fci in the shear Alfvén wave regime, and in a broad spectrum above fci in the lower hybrid frequency range, the focus of this paper. The wave spectra have distinct peaks close to ion cyclotron harmonics, extending out to the 100th harmonic in some cases. The wave generation was studied for various magnetic fields and background plasma densities, as well as for different beam energies and pitch angles. The waves were measured with 3-axis electric and magnetic probes. Detailed measurements of the perpendicular mode structure will be shown. Langmuir probes were used to measure density and temperature evolution due to the beam-plasma interaction. Retarding field energy analyzers captured the ion beam profiles. The work was performed at the LArge Plasma Device at the Basic Plasma Science Facility (BaPSF) at UCLA, funded by DOE/NSF.

  7. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    SciTech Connect

    Tarasenko, V. F.

    2011-05-15

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches {approx}5 Multiplication-Sign 10{sup 10} are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU{sub m}, where U{sub m} is the maximum gap voltage, is relatively small.

  8. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    NASA Astrophysics Data System (ADS)

    Tarasenko, V. F.

    2011-05-01

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches ˜5 × 1010 are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU m , where U m is the maximum gap voltage, is relatively small.

  9. Phase Space Generation for Proton and Carbon Ion Beams for External Users’ Applications at the Heidelberg Ion Therapy Center

    PubMed Central

    Tessonnier, Thomas; Marcelos, Tiago; Mairani, Andrea; Brons, Stephan; Parodi, Katia

    2016-01-01

    In the field of radiation therapy, accurate and robust dose calculation is required. For this purpose, precise modeling of the irradiation system and reliable computational platforms are needed. At the Heidelberg Ion Therapy Center (HIT), the beamline has been already modeled in the FLUKA Monte Carlo (MC) code. However, this model was kept confidential for disclosure reasons and was not available for any external team. The main goal of this study was to create efficiently phase space (PS) files for proton and carbon ion beams, for all energies and foci available at HIT. PSs are representing the characteristics of each particle recorded (charge, mass, energy, coordinates, direction cosines, generation) at a certain position along the beam path. In order to achieve this goal, keeping a reasonable data size but maintaining the requested accuracy for the calculation, we developed a new approach of beam PS generation with the MC code FLUKA. The generated PSs were obtained using an infinitely narrow beam and recording the desired quantities after the last element of the beamline, with a discrimination of primaries or secondaries. In this way, a unique PS can be used for each energy to accommodate the different foci by combining the narrow-beam scenario with a random sampling of its theoretical Gaussian beam in vacuum. PS can also reproduce the different patterns from the delivery system, when properly combined with the beam scanning information. MC simulations using PS have been compared to simulations, including the full beamline geometry and have been found in very good agreement for several cases (depth dose distributions, lateral dose profiles), with relative dose differences below 0.5%. This approach has also been compared with measured data of ion beams with different energies and foci, resulting in a very satisfactory agreement. Hence, the proposed approach was able to fulfill the different requirements and has demonstrated its capability for application to

  10. Fast ion generation in the cathode plasma jet of a multipicosecond laser-triggered vacuum discharge

    SciTech Connect

    Moorti, A.; Naik, P. A.; Gupta, P. D.

    2010-03-15

    Ion generation in the cathode plasma jet of a moderate-current ({approx}2.3 kA), low-energy ({<=}20 J) vacuum spark discharge triggered by {approx}27 ps, 10 mJ laser pulses is studied using time of flight technique. Fastest ion velocity and velocity corresponding to the peak of the time of flight signals for Al cathode were measured to be {approx}5.25x10{sup 8} cm/s (energy of {approx}143 keV/u) and {approx}8.1x10{sup 7} cm/s (energy of {approx}3.4 keV/u), respectively. Corresponding velocities in the case of ions generated from laser-produced Al plasma (energy of {approx}550 mJ, intensity of {approx}10{sup 14} W/cm{sup 2}) were found to be much smaller, viz., {approx}1.05x10{sup 8} cm/s (energy of {approx}5.75 keV/u) and {approx}2.63x10{sup 7} cm/s (energy of {approx}0.36 keV/u), respectively. Study shows efficient acceleration of ions in a current-carrying cathode plasma jet of a small-energy multipicosecond laser-triggered spark discharge as compared with that in a high-energy multipicosecond laser-produced plasma plume.

  11. Ion beam generated modes in the lower hybrid frequency range in a laboratory magnetoplasma

    NASA Astrophysics Data System (ADS)

    van Compernolle, Bart; Tripathi, Shreekrishna; Gekelman, Walter; Pribyl, Patrick

    2013-10-01

    The interaction of a fast ion beam with a low β plasma has been studied in the laboratory. Experiments were performed at the LArge Plasma Device (LAPD) at UCLA. The experiments were done in a Helium plasma (n ~=1012cm-3 , B0 = 1000 G - 1800 G, fpe /fce ~= 1 - 5 , Te ~= 4eV , vte <ion beam is either a Helium beam or Hydrogen beam with energies ranging from 5 keV to 18 keV. The fast ion velocity is on the order of the Alfvén velocity. The beam is injected from the end of the machine, and spirals down the linear device. Waves were observed below fci in the shear Alfvén wave regime, and in a broad spectrum above fci in the lower hybrid frequency range. The wave generation was studied for various plasma parameters, as well as for different beam energies and pitch angles. The waves were measured with 3-axis electric and magnetic probes. Detailed measurements of the 2D perpendicular mode structure will be shown. Progress on a theoretical framework of the wave generation by the ion beam will be presented along with comparisons to the measured wave properties. The work was performed at the LArge Plasma Device at the Basic Plasma Science Facility (BaPSF) at UCLA, funded by DOE/NSF.

  12. A Negative-Surface Ionization for Generation of Halogen Radioactive Ion Beams

    SciTech Connect

    Zaim, H.

    2001-04-16

    A simple and efficient negative surface ionization source has been designed, fabricated and initially tested for on-line generation of radioactive ion beams of the halogens (Cl, Br, I, and At) for use in the nuclear-structure and nuclear-astrophysics research programs at the Holifield Radioactive Ion Beam Facility. The source utilizes a solid, spherical geometry LaB{sub 6} surface ionizer for forming highly electronegative atoms and molecules. Despite its widely publicized propensity for being easily poisoned, no evidences of this effect were experienced during testing of the source. Nominal efficiencies of 15% for Br{sup {minus}} beam generation were obtained during off-line evaluation of the source with AlBr3 feed material when account is taken of the fractional dissociation of the molecule. Principles of operation, design features, operational parameter data, initial performance results, and beam quality data (emittance) are presented in this article.

  13. A selected ion flow tube study of the reactions of NO + and O + 2 ions with some organic molecules: The potential for trace gas analysis of air

    NASA Astrophysics Data System (ADS)

    Španěl, Patrik; Smith, David

    1996-02-01

    A study has been carried out using our selected ion flow tube apparatus of the reactions of NO+ and O+2 ions in their vibronic ground states with ten organic species: the hydrocarbons, benzene, toluene, isoprene, cyclopropane, and n-pentane; the oxygen-containing organics, methanol, ethanol, acetaldehyde, acetone, and diethyl ether. The major objectives of this work are, on the one hand, to fully understand the processes involved in these reactions and, on the other hand, to explore the potential of NO+ and O+2 as chemical ionization agents for the analysis of trace gases in air and on human breath. Amongst the NO+ reactions, charge transfer, hydride-ion transfer, and termolecular association occur, and the measured rate coefficients, k, for the reactions vary from immeasurably small to the maximum value, collisional rate coefficient, kc. The O+2 reactions are all fast, in each case the k being equal to or an appreciable fraction of kc, and charge transfer producing the parent organic ion or dissociative charge transfer resulting in two or three fragments of the parent ion are the reaction processes that occur. We conclude from these studies, and from previous studies, that NO+ ions and O+2 ions can be used to great effect as chemical ionization agents for trace gas analysis, especially in combination with H3O+ ions which we now routinely use for this purpose.

  14. Ion beam generated modes in the lower hybrid frequency range in a laboratory magnetoplasma

    NASA Astrophysics Data System (ADS)

    van Compernolle, Bart; Tripathi, Shreekrishna Kp; Gekelman, Walter; Pribyl, Patrick; Colestock, Patrick

    2012-10-01

    The interaction of a fast ion beam with a low β plasma has been studied in the laboratory. Experiments were performed at the LArge Plasma Device (LAPD) at UCLA. The experiments were done in a Helium plasma (n ˜10^12 cm-3, B0 = 1000 G - 1800 G, fpe/fce˜1 - 5, Te= 0.25 eV, vtevA). The ion beam is a Helium beam with energies ranging from 5 keV to 18 keV. The fast ion velocity is on the order of the Alfv'en velocity. The beam is injected from the end of the machine, and spirals down the linear device. Waves were observed below fci in the shear Alfv'en wave regime, and in a broad spectrum above fci in the lower hybrid frequency range, the focus of this paper. The wave spectra have distinct peaks close to ion cyclotron harmonics, extending out to the 100th harmonic in some cases. The wave generation was studied for various plasma parameters, as well as for different beam energies and pitch angles. The waves were measured with 3-axis electric and magnetic probes. Detailed measurements of the perpendicular mode structure will be shown. Langmuir probes were used to measure density and temperature evolution due to the beam-plasma interaction. Retarding field energy analyzers captured the ion beam profiles.

  15. [Involvement of carbonate/bicarbonate ions in the superoxide-generating reaction of adrenaline autoxidation].

    PubMed

    Sirota, T V

    2015-01-01

    An important role of carbonate/bicarbonate ions has been recognized in the superoxide generating reaction of adrenaline autooxidation in an alkaline buffer (a model of quinoid adrenaline oxidation in the body). It is suggested that these ions are directly involved not only in formation of superoxide anion radical (О(2)(-)) but also other radicals derived from the carbonate/bicarbonate buffer. Using various buffers it was shown that the rate of accumulation of adrenochrome, the end product of adrenaline oxidation, and the rate of О(2)(-)· formation depend on concentration of carbonate/bicarbonate ions in the buffer and that these ions significantly accelerate adrenaline autooxidation thus demonstrating prooxidant properties. The detectable amount of diformazan, the product of nitro blue tetrazolium (NBT) reduction, was significantly higher than the amount of adrenochrome formed; taking into consideration the literature data on О(2)(-)· detection by NBT it is suggested that adrenaline autooxidation is accompanied by one-electron reduction not only of oxygen dissolved in the buffer and responsible for superoxide formation but possible carbon dioxide also dissolved in the buffer as well as carbonate/bicarbonate buffer components leading to formation of corresponding radicals. The plots of the dependence of the inhibition of adrenochrome and diformazan formation on the superoxide dismutase concentration have shown that not only superoxide radicals are formed during adrenaline autooxidation. Since carbonate/bicarbonate ions are known to be universally present in the living nature, their involvement in free radical processes proceeding in the organism is discussed.

  16. Temporalization of Electric Generation Emissions for Improved Representation of Peak Air Quality Episodes

    NASA Astrophysics Data System (ADS)

    Farkas, C. M.; Moeller, M.; Carlton, A. G.

    2013-12-01

    Photochemical transport models routinely under predict peak air quality events. This deficiency may be due, in part, to inadequate temporalization of emissions from the electric generating sector. The National Emissions Inventory (NEI) reports emissions from Electric Generating Units (EGUs) by either Continuous Emission Monitors (CEMs) that report hourly values or as an annual total. The Sparse Matrix Operator Kernel Emissions preprocessor (SMOKE), used to prepare emissions data for modeling with the CMAQ air quality model, allocates annual emission totals throughout the year using specific monthly, weekly, and hourly weights according to standard classification code (SCC) and location. This approach represents average diurnal and seasonal patterns of electricity generation but does not capture spikes in emissions due to episodic use as with peaking units or due to extreme weather events. In this project we use a combination of state air quality permits, CEM data, and EPA emission factors to more accurately temporalize emissions of NOx, SO2 and particulate matter (PM) during the extensive heat wave of July and August 2006. Two CMAQ simulations are conducted; the first with the base NEI emissions and the second with improved temporalization, more representative of actual emissions during the heat wave. Predictions from both simulations are evaluated with O3 and PM measurement data from EPA's National Air Monitoring Stations (NAMS) and State and Local Air Monitoring Stations (SLAMS) during the heat wave, for which ambient concentrations of criteria pollutants were often above NAAQS. During periods of increased photochemistry and high pollutant concentrations, it is critical that emissions are most accurately represented in air quality models.

  17. Targeting cancer cells with reactive oxygen and nitrogen species generated by atmospheric-pressure air plasma.

    PubMed

    Ahn, Hak Jun; Kim, Kang Il; Hoan, Nguyen Ngoc; Kim, Churl Ho; Moon, Eunpyo; Choi, Kyeong Sook; Yang, Sang Sik; Lee, Jong-Soo

    2014-01-01

    The plasma jet has been proposed as a novel therapeutic method for cancer. Anticancer activity of plasma has been reported to involve mitochondrial dysfunction. However, what constituents generated by plasma is linked to this anticancer process and its mechanism of action remain unclear. Here, we report that the therapeutic effects of air plasma result from generation of reactive oxygen/nitrogen species (ROS/RNS) including H2O2, Ox, OH-, •O2, NOx, leading to depolarization of mitochondrial membrane potential and mitochondrial ROS accumulation. Simultaneously, ROS/RNS activate c-Jun NH2-terminal kinase (JNK) and p38 kinase. As a consequence, treatment with air plasma jets induces apoptotic death in human cervical cancer HeLa cells. Pretreatment of the cells with antioxidants, JNK and p38 inhibitors, or JNK and p38 siRNA abrogates the depolarization of mitochondrial membrane potential and impairs the air plasma-induced apoptotic cell death, suggesting that the ROS/RNS generated by plasma trigger signaling pathways involving JNK and p38 and promote mitochondrial perturbation, leading to apoptosis. Therefore, administration of air plasma may be a feasible strategy to eliminate cancer cells.

  18. Neutron generator for BNCT based on high current ECR ion source with gyrotron plasma heating.

    PubMed

    Skalyga, V; Izotov, I; Golubev, S; Razin, S; Sidorov, A; Maslennikova, A; Volovecky, A; Kalvas, T; Koivisto, H; Tarvainen, O

    2015-12-01

    BNCT development nowadays is constrained by a progress in neutron sources design. Creation of a cheap and compact intense neutron source would significantly simplify trial treatments avoiding use of expensive and complicated nuclear reactors and accelerators. D-D or D-T neutron generator is one of alternative types of such sources for. A so-called high current quasi-gasdynamic ECR ion source with plasma heating by millimeter wave gyrotron radiation is suggested to be used in a scheme of D-D neutron generator in the present work. Ion source of that type was developed in the Institute of Applied Physics of Russian Academy of Sciences (Nizhny Novgorod, Russia). It can produce deuteron ion beams with current density up to 700-800 mA/cm(2). Generation of the neutron flux with density at the level of 7-8·10(10) s(-1) cm(-2) at the target surface could be obtained in case of TiD2 target bombardment with deuteron beam accelerated to 100 keV. Estimations show that it is enough for formation of epithermal neutron flux with density higher than 10(9) s(-1) cm(-2) suitable for BNCT. Important advantage of described approach is absence of Tritium in the scheme. First experiments performed in pulsed regime with 300 mA, 45 kV deuteron beam directed to D2O target demonstrated 10(9) s(-1) neutron flux. This value corresponds to theoretical estimations and proofs prospects of neutron generator development based on high current quasi-gasdynamic ECR ion source.

  19. CHARACTERIZATION OF OZONE EMISSIONS FROM AIR CLEANERS EQUIPPED WITH OZONE GENERATORS AND SENSOR AND FEEDBACK CONTROL CIRCUITRY

    EPA Science Inventory

    The paper give results of a characterization of ozone emissions from air cleaners equipped with ozone generators and sensor and feedback control circuitry. Ozone emission rates of several consumer appliances, marketed as indoor air treatment or air purification systems, were det...

  20. Air feed tube support system for a solid oxide fuel cell generator

    DOEpatents

    Doshi, Vinod B.; Ruka, Roswell J.; Hager, Charles A.

    2002-01-01

    A solid oxide fuel cell generator (12), containing tubular fuel cells (36) with interior air electrodes (18), where a supporting member (82) containing a plurality of holes (26) supports oxidant feed tubes (51), which pass from an oxidant plenum (52") into the center of the fuel cells, through the holes (26) in the supporting member (82), where a compliant gasket (86) around the top of the oxidant feed tubes and on top (28) of the supporting member (82) helps support the oxidant feed tubes and center them within the fuel cells, and loosen the tolerance for centering the air feed tubes.

  1. Development and study of aluminum-air electrochemical generator and its main components

    NASA Astrophysics Data System (ADS)

    Ilyukhina, A. V.; Kleymenov, B. V.; Zhuk, A. Z.

    2017-02-01

    Aluminum-air power sources are receiving increased attention for applications in portable electronic devices, transportation, and energy systems. This study reports on the development of an aluminum-air electrochemical generator (AA ECG) and provides a technical foundation for the selection of its components, i.e., aluminum anode, gas diffusion cathode, and alkaline electrolyte. A prototype 1.5 kW AA ECG with specific energy of 270 Wh kg-1 is built and tested. The results of this study demonstrate the feasibility of AA ECGs as portable reserve and emergency power sources, as well as power sources for electric vehicles.

  2. Evaluating the Environmental Performance of the U.S. Next Generation Air Transportation System

    NASA Technical Reports Server (NTRS)

    Graham, Michael; Augustine, Stephen; Ermatinger, Christopher; Difelici, John; Thompson, Terence R.; Marcolini, Michael A.; Creedon, Jeremiah F.

    2009-01-01

    The environmental impacts of several possible U.S. Next Generation Air Transportation scenarios have been quantitatively evaluated for noise, air-quality, fuel-efficiency, and CO2 impacts. Three principal findings have emerged. (1) 2025 traffic levels about 30% higher than 2006 are obtained by increasing traffic according to FAA projections while also limiting traffic at each airport using reasonable ratios of demand to capacity. NextGen operational capabilities alone enable attainment of an additional 10-15% more flights beyond that 2025 baseline level with negligible additional noise, air-quality, and fuel-efficiency impacts. (2) The addition of advanced engine and airframe technologies provides substantial additional reductions in noise and air-quality impacts, and further improves fuel efficiency. 2025 environmental goals based on projected system-wide improvement rates of about 1% per year for noise and fuel-efficiency (an air-quality goal is not yet formulated) are achieved using this new vehicle technology. (3) Overall air-transport "product", as measured by total flown distance or total payload distance, increases by about 50% relative to 2006, but total fuel consumption and CO2 production increase by only about 40% using NextGen operational capabilities. With the addition of advanced engine/airframe technologies, the increase in total fuel consumption and CO2 production can be reduced to about 30%.

  3. Fabrication and evaluation of an electrodialytic carbonate eluent generator for ion chromatography.

    PubMed

    Shen, Guobin; Lu, Yifei; Chen, Feifei; Zhang, Feifang; Yang, Bingcheng

    2016-10-01

    An electrodialytic potassium carbonate eluent generator and its associated potassium bicarbonate eluent generator have been fabricated for ion chromatography (IC). The device can withstand high backpressure up to ∼32MPa and no observable leakage under such pressure is found during 2h. In the range of 0-13.7mM, potassium carbonate concentration can be generated linearly with the applied current with a slope that is essentially Faradaic. At least 10mM potassium carbonate can be online changed into 10mM potassium bicarbonate via a potassium bicarbonate eluent generator, which offers an easy way to manipulate the separation selectivity. When coupled with IC system, the device demonstrated good reproducibility indicated by less than 0.52% of the relative standard deviation of the retention times.

  4. Influence of Water and Ion Diffusion on Generation and Progress of Bow-tie Tree

    NASA Astrophysics Data System (ADS)

    Kumazawa, Takao; Nakagawa, Wataru; Tsurumaru, Hidekazu

    Bow-tie tree(BTT) generated from contaminant, e.g., metal, carbon, amber(over cured resin) or void is a deterioration factor of XLPE cable. In particular, BTT in contact with inner or outer semi-conductive shield could significantly lower residual AC breakdown voltage of HV power cable. To evaluate influence of water and ion diffusion on generation and progress of BTT, we investigated relationship between water content of XLPE and the generation of BTT by various accelerated aging. The number of BTT in XLPE samples with accelerated aging under open condition, involving evaporation of water in which samples were immersed, was very large compared with closed condition. Furthermore, when samples were intermittently immersed in water, the number of BTT in samples was large compared with samples immersed continuously. In these experiments the generation of BTT seemed to have nothing to do with changes in water content before and after accelerated aging. Therefore, it was suggested that diffusion of ions rather than water in XLPE played an important role in the generation of BTT.

  5. Arc plasma generator of atomic driver for steady-state negative ion source

    SciTech Connect

    Ivanov, A. A.; Belchenko, Yu. I.; Davydenko, V. I.; Ivanov, I. A.; Kolmogorov, V. V.; Listopad, A. A. Mishagin, V. V.; Shulzhenko, G. I.; Putvinsky, S. V.; Smirnov, A.

    2014-02-15

    The paper reviews the results of development of steady-state arc-discharge plasma generator with directly heated LaB{sub 6} cathode. This arc-discharge plasma generator produces a plasma jet which is to be converted into an atomic one after recombination on a metallic plate. The plate is electrically biased relative to the plasma in order to control the atom energies. Such an intensive jet of hydrogen atoms can be used in negative ion sources for effective production of negative ions on a cesiated surface of plasma grid. All elements of the plasma generator have an augmented water cooling to operate in long pulse mode or in steady state. The thermo-mechanical stresses and deformations of the most critical elements of the plasma generator were determined by simulations. Magnetic field inside the discharge chamber was optimized to reduce the local power loads. The first tests of the steady-state arc plasma generator prototype have performed in long-pulse mode.

  6. Arc plasma generator of atomic driver for steady-state negative ion source.

    PubMed

    Ivanov, A A; Belchenko, Yu I; Davydenko, V I; Ivanov, I A; Kolmogorov, V V; Listopad, A A; Mishagin, V V; Putvinsky, S V; Shulzhenko, G I; Smirnov, A

    2014-02-01

    The paper reviews the results of development of steady-state arc-discharge plasma generator with directly heated LaB6 cathode. This arc-discharge plasma generator produces a plasma jet which is to be converted into an atomic one after recombination on a metallic plate. The plate is electrically biased relative to the plasma in order to control the atom energies. Such an intensive jet of hydrogen atoms can be used in negative ion sources for effective production of negative ions on a cesiated surface of plasma grid. All elements of the plasma generator have an augmented water cooling to operate in long pulse mode or in steady state. The thermo-mechanical stresses and deformations of the most critical elements of the plasma generator were determined by simulations. Magnetic field inside the discharge chamber was optimized to reduce the local power loads. The first tests of the steady-state arc plasma generator prototype have performed in long-pulse mode.

  7. Modeling of a second-generation solar-driven Rankine air conditioner. Final report

    SciTech Connect

    Denius, M.W.; Batton, W.D.

    1984-07-01

    Ten configurations of a second-generation (2G), solar-powered, Rankine-driven air conditioner were simulated and the data presented for use in companion studies. The results of the analysis show that the boiling-in-collector (BIC) configuration generates more power per collector area than the other configurations. The models used to simulate the configuration are presented in this report. The generated data are also presented. Experimental work was done under this study to both improve a novel refrigerant and oil lubrication system for the centrifugal compressor and investigate the aerodynamic unloading characteristics of the centrifugal compressor. The information generated was used to define possible turbo-gearbox configurations for use in the second generation computer simulation.

  8. Low-Resistance Dual-Purpose Air Filter Releasing Negative Ions and Effectively Capturing PM2.5.

    PubMed

    Zhao, Xinglei; Li, Yuyao; Hua, Ting; Jiang, Pan; Yin, Xia; Yu, Jianyong; Ding, Bin

    2017-04-05

    The fatal danger of pollution due to particulate matter (PM) calls for both high-efficiency and low-resistance air purification materials, which also provide healthcare. This is however still a challenge. Herein, a low-resistance air filter capable of releasing negative ions (NIs) and efficiently capturing PM2.5 was prepared by electrospinning polyvinylidene fluoride (PVDF) fibers doped with negative ions powder (NIPs). The air-resistance of fibrous membranes decreased from 9.5 to 6 Pa (decrease of 36%) on decreasing the average fiber diameter from 1.16 to 0.41 μm. Moreover, the lower rising rate of air-resistance with reduction in pore size, for fibrous membranes with thinner fiber diameter was verified. In addition, a single PVDF/NIPs fiber was provided with strong surface potentials, due to high fluorine electronegativity, and tested using atomic force microscopy. This strong surface potential resulted in higher releasing amounts of NIs (RANIs). Interestingly, reduction of fiber diameter favored the alleviation of the shielding effects on electric field around fibers and promoted the RANIs from 798 to 1711 ions cc(-1). Moreover, by regulating the doping contents of NIPs, the RANIs increased from 1711 to 2818 ions cc(-1). The resultant fibrous membranes showed low air resistance of 40.5 Pa. Field-tests conducted in Shanghai showed stable PM2.5 purification efficiency of 99.99% at high RANIs, in the event of haze.

  9. Modeling breathing-zone concentrations of airborne contaminants generated during compressed air spray painting.

    PubMed

    Flynn, M R; Gatano, B L; McKernan, J L; Dunn, K H; Blazicko, B A; Carlton, G N

    1999-01-01

    This paper presents a mathematical model to predict breathing-zone concentrations of airborne contaminants generated during compressed air spray painting in cross-flow ventilated booths. The model focuses on characterizing the generation and transport of overspray mist. It extends previous work on conventional spray guns to include exposures generated by HVLP guns. Dimensional analysis and scale model wind-tunnel studies are employed using non-volatile oils, instead of paint, to produce empirical equations for estimating exposure to total mass. Results indicate that a dimensionless breathing zone concentration is a nonlinear function of the ratio of momentum flux of air from the spray gun to the momentum flux of air passing through the projected area of the worker's body. The orientation of the spraying operation within the booth is also very significant. The exposure model requires an estimate of the contaminant generation rate, which is approximated by a simple impactor model. The results represent an initial step in the construction of more realistic models capable of predicting exposure as a mathematical function of the governing parameters.

  10. How do air ions reflect variations in ionising radiation in the lower atmosphere in a boreal forest?

    NASA Astrophysics Data System (ADS)

    Chen, Xuemeng; Kerminen, Veli-Matti; Paatero, Jussi; Paasonen, Pauli; Manninen, Hanna E.; Nieminen, Tuomo; Petäjä, Tuukka; Kulmala, Markku

    2016-11-01

    Most of the ion production in the atmosphere is attributed to ionising radiation. In the lower atmosphere, ionising radiation consists mainly of the decay emissions of radon and its progeny, gamma radiation of the terrestrial origin as well as photons and elementary particles of cosmic radiation. These types of radiation produce ion pairs via the ionisation of nitrogen and oxygen as well as trace species in the atmosphere, the rate of which is defined as the ionising capacity. Larger air ions are produced out of the initial charge carriers by processes such as clustering or attachment to pre-existing aerosol particles. This study aimed (1) to identify the key factors responsible for the variability in ionising radiation and in the observed air ion concentrations, (2) to reveal the linkage between them and (3) to provide an in-depth analysis into the effects of ionising radiation on air ion formation, based on measurement data collected during 2003-2006 from a boreal forest site in southern Finland. In general, gamma radiation dominated the ion production in the lower atmosphere. Variations in the ionising capacity came from mixing layer dynamics, soil type and moisture content, meteorological conditions, long-distance transportation, snow cover attenuation and precipitation. Slightly similar diurnal patterns to variations in the ionising capacity were observed in air ion concentrations of the cluster size (0.8-1.7 nm in mobility diameters). However, features observed in the 0.8-1 nm ion concentration were in good connection to variations of the ionising capacity. Further, by carefully constraining perturbing variables, a strong dependency of the cluster ion concentration on the ionising capacity was identified, proving the functionality of ionising radiation in air ion production in the lower atmosphere. This relationship, however, was only clearly observed on new particle formation (NPF) days, possibly indicating that charges after being born underwent different

  11. Resolution improvement and pattern generator development for the maskless micro-ion-beam reduction lithography system

    NASA Astrophysics Data System (ADS)

    Jiang, Ximan

    have been studied. The dependence of the throughput with the exposure field size and the speed of the mechanical stage has been investigated. In order to perform maskless lithography, different micro-fabricated pattern generators have been developed for the MMRL system. Ion beamlet switching has been successfully demonstrated on the MMRL system. A positive bias voltage around 10 volts is sufficient to switch off the ion current on the micro-fabricated pattern generators. Some unexpected problems, such as the high-energy secondary electron radiations, have been discovered during the experimental investigation. Thermal and structural analysis indicates that the aperture displacement error induced by thermal expansion can satisfy the 3delta CD requirement for lithography nodes down to 25 nm. The cross-talking effect near the surface and inside the apertures of the pattern generator has been simulated in a 3-D ray-tracing code. New pattern generator design has been proposed to reduce the cross-talking effect. In order to eliminate the surface charging effect caused by the secondary electrons, a new beam-switching scheme in which the switching electrodes are immersed in the plasma has been demonstrated on a mechanically fabricated pattern generator.

  12. Effects of negative air ions on oxygen uptake kinetics, recovery and performance in exercise: a randomized, double-blinded study

    NASA Astrophysics Data System (ADS)

    Nimmerichter, Alfred; Holdhaus, Johann; Mehnen, Lars; Vidotto, Claudia; Loidl, Markus; Barker, Alan R.

    2014-09-01

    Limited research has suggested that acute exposure to negatively charged ions may enhance cardio-respiratory function, aerobic metabolism and recovery following exercise. To test the physiological effects of negatively charged air ions, 14 trained males (age: 32 ± 7 years; : 57 ± 7 mL min-1 kg-1) were exposed for 20 min to either a high-concentration of air ions (ION: 220 ± 30 × 103 ions cm-3) or normal room conditions (PLA: 0.1 ± 0.06 × 103 ions cm-3) in an ionization chamber in a double-blinded, randomized order, prior to performing: (1) a bout of severe-intensity cycling exercise for determining the time constant of the phase II response ( τ) and the magnitude of the slow component (SC); and (2) a 30-s Wingate test that was preceded by three 30-s Wingate tests to measure plasma [adrenaline] (ADR), [nor-adrenaline] (N-ADR) and blood [lactate] (BLac) over 20 min during recovery in the ionization chamber. There was no difference between ION and PLA for the phase II τ (32 ± 14 s vs. 32 ± 14 s; P = 0.7) or SC (404 ± 214 mL vs 482 ± 217 mL; P = 0.17). No differences between ION and PLA were observed at any time-point for ADR, N-ADR and BLac as well as on peak and mean power output during the Wingate tests (all P > 0.05). A high-concentration of negatively charged air ions had no effect on aerobic metabolism during severe-intensity exercise or on performance or the recovery of the adrenergic and metabolic responses after repeated-sprint exercise in trained athletes.

  13. Particle simulations of ion generation and transport in microelectromechanical systems and microthrusters

    NASA Astrophysics Data System (ADS)

    Ayyaswamy, Venkattraman

    Field emission and evaporation are processes of electron and ion generation due to intense electric fields. This work presents a particle-based computational approach using the particle-in-cell/Monte Carlo collisions (PIC/MCC) and the direct simulation Monte Carlo (DSMC) method to study ion generation and transport in microelectromechanical systems (MEMS) and field emission electric propulsion (FEEP) microthrusters. Electrostatically actuated MEMS operate in intense electric fields > 107 V/m thereby resulting in electron emission from the cathode that has important implications on reliability and performance of these devices. The PIC/MCC method is used to develop compact models to provide closure to a mathematical model for the modified Paschen law which bridges breakdown in macroscale gaps with field emission driven breakdown at nano/microscales. The models have the capability to account for the influence of operating parameters including pressure, composition and cathode properties making it suitable for the analysis and design of electrostatic MEMS. This work also deals with the modeling of field emission ion thrusters used for in-space propulsion. Particle simulations are used to study performance parameters such as thrust and plume characteristics by comparison with experiments. While PIC simulations predict thrust values in excellent agreement with measurements, comparisons with measurements of current distribution in the plume indicate that ion-neutral collisions become increasingly important as the current increases. Good agreement for current distribution is obtained if the elastic scattering of ions by background neutrals in the vacuum chamber is included thereby providing a numerical framework for the design and optimization of these thrusters.

  14. Flammability limits of lithium-ion battery thermal runaway vent gas in air and the inerting effects of halon 1301

    NASA Astrophysics Data System (ADS)

    Karp, Matthew Eugene

    Lithium-ion (rechargeable) and lithium-metal (non-rechargeable) battery cells put aircraft at risk of igniting and fueling fires. Lithium batteries can be packed in bulk and shipped in the cargo holds of freighter aircraft; currently lithium batteries are banned from bulk shipment on passenger aircraft [1]. The federally regulated Class C cargo compartment extinguishing system's utilization of a 5 %vol Halon 1301 knockdown concentration and a sustained 3 %vol Halon 1301 may not be sufficient at inerting lithium-ion battery vent gas and air mixtures [2]. At 5 %vol Halon 1301 the flammability limits of lithium-ion premixed battery vent gas (Li-Ion pBVG) in air range from 13.80 %vol to 26.07 %vol Li-Ion pBVG. Testing suggests that 8.59 %vol Halon 1301 is required to render all ratios of the Li-Ion pBVG in air inert. The lower flammability limit (LFL) and upper flammability limit (UFL) of hydrogen and air mixtures are 4.95 %vol and 76.52 %vol hydrogen, respectively. With the addition of 10 %vol and 20 %vol Halon 1301 the LFL is 9.02 %vol and 11.55 %vol hydrogen, respectively, and the UFL is 45.70 %vol and 28.39 %vol hydrogen, respectively. The minimum inerting concentration (MIC) of Halon 1301 in hydrogen and air mixtures is 26.72 %vol Halon 1301 at 16.2 %vol hydrogen. The LFL and UFL of Li-Ion pBVG and air mixtures are 7.88 %vol and 37.14 %vol Li-Ion pBVG, respectively. With the addition of 5 %vol, 7 %vol, and 8 %vol Halon 1301 the LFL is 13.80 %vol, 16.15 %vol, and 17.62 % vol Li-Ion pBVG, respectively, and the UFL is 26.07 %vol, 23.31 %vol, and 21.84 %vol Li- Ion pBVG, respectively. The MIC of Halon 1301 in Li-Ion pBVG and air mixtures is 8.59 %vol Halon 1301 at 19.52 %vol Li-Ion pBVG. Le Chatelier's mixing rule has been shown to be an effective measure for estimating the flammability limits of Li-Ion pBVGes. The LFL has a 1.79 % difference while the UFL has a 4.53 % difference. The state of charge (SOC) affects the flammability limits in an apparent parabolic

  15. Ionization of large homogeneous and heterogeneous clusters generated in acetylene-Ar expansions: cluster ion polymerization.

    PubMed

    Kočišek, J; Lengyel, J; Fárník, M

    2013-03-28

    Pure acetylene and mixed Ar-acetylene clusters are formed in supersonic expansions of acetylene/argon mixtures and analysed using reflectron time-of-flight mass spectrometer with variable electron energy ionization source. Acetylene clusters composed of more than a hundred acetylene molecules are generated at the acetylene concentration of ≈8%, while mixed species are produced at low concentrations (≈0.7%). The electron energy dependence of the mass spectra revealed the ionization process mechanisms in clusters. The ionization above the threshold for acetylene molecule of 11.5 eV results in the main ionic fragment progression (C2H2)n(+). At the electron energies ≥21.5 eV above the CH+CH(+) dissociative ionization limit of acetylene the fragment ions nominally labelled as (C2H2)nCH(+), n ≥ 2, are observed. For n ≤ 7 these fragments correspond to covalently bound ionic structures as suggested by the observed strong dehydrogenation [(C2H2)n - k × H](+) and [(C2H2)nCH - k × H](+). The dehydrogenation is significantly reduced in the mixed clusters where evaporation of Ar instead of hydrogen can stabilize the nascent molecular ion. The C3H3(+) ion was previously assigned to originate from the benzene molecular ion; however, the low appearance energy of ≈13.7 eV indicates that a less rigid covalently bound structure of C6H6(+) ion must also be formed upon the acetylene cluster electron ionization. The appearance energy of Arn(C2H2)(+) fragments above ≈15.1 eV indicates that the argon ionization is the first step in the fragment ion production, and the appearance energy of Arn≥2(C2H2)m≥2(+) at ≈13.7 eV is discussed in terms of an exciton transfer mechanism.

  16. Ionization of large homogeneous and heterogeneous clusters generated in acetylene-Ar expansions: Cluster ion polymerization

    NASA Astrophysics Data System (ADS)

    Kočišek, J.; Lengyel, J.; Fárník, M.

    2013-03-01

    Pure acetylene and mixed Ar-acetylene clusters are formed in supersonic expansions of acetylene/argon mixtures and analysed using reflectron time-of-flight mass spectrometer with variable electron energy ionization source. Acetylene clusters composed of more than a hundred acetylene molecules are generated at the acetylene concentration of ≈8%, while mixed species are produced at low concentrations (≈0.7%). The electron energy dependence of the mass spectra revealed the ionization process mechanisms in clusters. The ionization above the threshold for acetylene molecule of 11.5 eV results in the main ionic fragment progression (C_2H_2)_n^+. At the electron energies ⩾21.5 eV above the CH+CH+ dissociative ionization limit of acetylene the fragment ions nominally labelled as (C2H2)nCH+, n ⩾ 2, are observed. For n ⩽ 7 these fragments correspond to covalently bound ionic structures as suggested by the observed strong dehydrogenation [(C2H2)n - k × H]+ and [(C2H2)nCH - k × H]+. The dehydrogenation is significantly reduced in the mixed clusters where evaporation of Ar instead of hydrogen can stabilize the nascent molecular ion. The C3 H_3^+ ion was previously assigned to originate from the benzene molecular ion; however, the low appearance energy of ≈13.7 eV indicates that a less rigid covalently bound structure of C6 H_6^+ ion must also be formed upon the acetylene cluster electron ionization. The appearance energy of Arn(C2H2)+ fragments above ≈15.1 eV indicates that the argon ionization is the first step in the fragment ion production, and the appearance energy of Ar_{n ≥ 2}(C2 H2)_{m≥ 2}^+ at ≈13.7 eV is discussed in terms of an exciton transfer mechanism.

  17. On the physics of ion ring generation for the stabilization of FRX discharges. Final report

    SciTech Connect

    Fleischmann, H.

    1995-02-01

    As envisioned in the respective proposals, the author`s work over the final periods of this contract centered on experimental and related theoretical investigations of the physics of the generation of ion rings which might be used for a tilt stabilization of FRX rings, with experiments centering around the new MICE equipment constructed during the earlier parts of the work. In particular, the work mainly consisted of the following: (i) investigations concerning the operation of the ion beam driver constructed earlier, especially of the magnetically insulated ion diode and possible improvements of that diode; (ii) theoretical analyses on the propagation and neutralization of the ion beam during its injection into the confinement tank; and (iii) experimental investigations on the physics of ion beam injection and ring formation in the MICE device; in these latter experiments very significant discrepancies of various observed data and those predicted from single-particle orbit calculations were found. Unfortunately, the work could not be completed due to stop in funding, but a semiquantitative analysis of these discrepancies indicated insufficient space charge neutralization of the ion beam in the tank and/or charge-exchange effects in the diode are considered the most likely reasons. In contrast to claims by its authors, a similar discrepancy also was found in the published data of the earlier IREX experiment. The results of their investigations, which together with the design and construction of the equipment provided the basis for two PhD theses, will be briefly described in this report; the full details can be obtained from the two theses.

  18. Spatially resolved air-water emissions tradeoffs improve regulatory impact analyses for electricity generation.

    PubMed

    Gingerich, Daniel B; Sun, Xiaodi; Behrer, A Patrick; Azevedo, Inês L; Mauter, Meagan S

    2017-02-21

    Coal-fired power plants (CFPPs) generate air, water, and solids emissions that impose substantial human health, environmental, and climate change (HEC) damages. This work demonstrates the importance of accounting for cross-media emissions tradeoffs, plant and regional emissions factors, and spatially variation in the marginal damages of air emissions when performing regulatory impact analyses for electric power generation. As a case study, we assess the benefits and costs of treating wet flue gas desulfurization (FGD) wastewater at US CFPPs using the two best available treatment technology options specified in the 2015 Effluent Limitation Guidelines (ELGs). We perform a life-cycle inventory of electricity and chemical inputs to FGD wastewater treatment processes and quantify the marginal HEC damages of associated air emissions. We combine these spatially resolved damage estimates with Environmental Protection Agency estimates of water quality benefits, fuel-switching benefits, and regulatory compliance costs. We estimate that the ELGs will impose average net costs of $3.01 per cubic meter for chemical precipitation and biological wastewater treatment and $11.26 per cubic meter for zero-liquid discharge wastewater treatment (expected cost-benefit ratios of 1.8 and 1.7, respectively), with damages concentrated in regions containing a high fraction of coal generation or a large chemical manufacturing industry. Findings of net cost for FGD wastewater treatment are robust to uncertainty in auxiliary power source, location of chemical manufacturing, and binding air emissions limits in noncompliant regions, among other variables. Future regulatory design will minimize compliance costs and HEC tradeoffs by regulating air, water, and solids emissions simultaneously and performing regulatory assessments that account for spatial variation in emissions impacts.

  19. Differential negative air ion effects on learning disabled and normal-achieving children

    NASA Astrophysics Data System (ADS)

    Morton, L. L.; Kershner, J. R.

    1990-03-01

    Forty normal-achieving and 33 learning disabled (LD) children were assigned randomly to either a negative ion or placebo test condition. On a dichotic listening task using consonant-vowel (CV) combinations, both groups showed an ioninduced increase in the normal right ear advantage (REA). However, the mechanisms for this effect were different for each group. The LDs showed the effect at the right ear/left hemisphere (enhancement). The normal achievers showed the effect at the left ear/right hemisphere (inhibition). The results are consistent with an activation-inhibition model of cerebral function and suggest a functional relationship between arousal, interhemispheric activation-inhibition, and learning disabilities. The LDs may have an interhemispheric dysfunction. Both groups showed superior right ear report and the normal achiever showed overall superiority. Normal achievers showed higher consonant intrusion scores, probably due to a greater cognitive capacity. Age was a significant covariate reflecting developmental capacity changes. Negative air ions are seen to be a tool with potential theoretical and remedial applications.

  20. Design of a Nb3Sn Magnet for a 4th Generation ECR Ion Source

    SciTech Connect

    Prestemon, S,; Trillaud, F.; Caspi, S.; Ferracin, P.; Sabbi, G. L.; Lyneis, C. M.; Leitner, D.; Todd, D. S.; Hafalia, R.

    2008-08-17

    The next generation of Electron Cyclotron Resonant (ECR) ion sources are expected to operate at a heating radio frequency greater than 40 GHz. The existing 3rd generation systems, exemplified by the state of the art system VENUS, operate in the 10-28 GHz range, and use NbTi superconductors for the confinement coils. The magnetic field needed to confine the plasma scales with the rf frequency, resulting in peak fields on the magnets of the 4th generation system in excess of 10 T. High field superconductors such as Nb{sub 3}Sn must therefore be considered. The magnetic design of a 4th. generation ECR ion source operating at an rf frequency of 56 GHz is considered. The analysis considers both internal and external sextupole configurations, assuming commercially available Nb{sub 3}Sn material properties. Preliminary structural design issues are discussed based on the forces and margins associated with the coils in the different configurations, leading to quantitative data for the determination of a final magnet design.

  1. Modeling and Simulation of the Second-Generation Orion Crew Module Air Bag Landing System

    NASA Technical Reports Server (NTRS)

    Timmers, Richard B.; Welch, Joseph V.; Hardy, Robin C.

    2009-01-01

    Air bags were evaluated as the landing attenuation system for earth landing of the Orion Crew Module (CM). An important element of the air bag system design process is proper modeling of the proposed configuration to determine if the resulting performance meets requirements. Analysis conducted to date shows that airbags are capable of providing a graceful landing of the CM in nominal and off-nominal conditions such as parachute failure, high horizontal winds, and unfavorable vehicle/ground angle combinations. The efforts presented here surround a second generation of the airbag design developed by ILC Dover, and is based on previous design, analysis, and testing efforts. In order to fully evaluate the second generation air bag design and correlate the dynamic simulations, a series of drop tests were carried out at NASA Langley's Landing and Impact Research (LandIR) facility. The tests consisted of a full-scale set of air bags attached to a full-scale test article representing the Orion Crew Module. The techniques used to collect experimental data, construct the simulations, and make comparisons to experimental data are discussed.

  2. Next Generation Tanker: Optimizing Air Refueling Capabilities in 2030 with a Divested KC-10 Fleet

    DTIC Science & Technology

    2015-06-19

    BCA-level funding would have similar impacts for non - defense programs, and any increase in defense discretionary caps should be matched by an...equivalent increase in the non -defense caps. For defense, the Estimated Impacts of Sequestration-Level Funding Report illustrates the additional warfighting...and Acquisition of Our Next Generation Tanker (No. AFIT/ GMO /ENS/02E-15). 33 Appendix A: Advanced Air Refueling Capability Concepts Standard

  3. Photonics aided ultra-wideband W-band signal generation and air space transmission

    NASA Astrophysics Data System (ADS)

    Li, Xinying; Yu, Jianjun

    2016-02-01

    We achieve several field trial demonstrations of ultra-wideband W-band millimeter-wave (mm-wave) signal generation and its long-distance air space transmission based on some enabling technologies and advanced devices. First, we demonstrated photonics generation and up to 1.7-km wireless delivery of 20-Gb/s polarization division multiplexing quadrature phase shift keying (PDM-QPSK) signal at W-band, adopting both optical and antenna polarization multiplexing. Then, we demonstrated photonics generation and up to 300-m wireless delivery of 80-Gb/s PDM-QPSK signal at W-band, adopting both optical and antenna polarization multiplexing as well as multi-band multiplexing. We also demonstrated photonics generation and up to 100-m wireless delivery of 100-Gb/s QPSK signal at W-band, adopting antenna polarization multiplexing.

  4. On the generation of double layers from ion- and electron-acoustic instabilities

    NASA Astrophysics Data System (ADS)

    Fu, Xiangrong; Cowee, Misa M.; Gary, S. Peter; Winske, Dan

    2016-03-01

    A plasma double layer (DL) is a nonlinear electrostatic structure that carries a uni-polar electric field parallel to the background magnetic field due to local charge separation. Past studies showed that DLs observed in space plasmas are mostly associated with the ion acoustic instability. Recent Van Allen Probes observations of parallel electric field structures traveling much faster than the ion acoustic speed have motivated a computational study to test the hypothesis that a new type of DLs—electron acoustic DLs—generated from the electron acoustic instability are responsible for these electric fields. Nonlinear particle-in-cell simulations yield negative results, i.e., the hypothetical electron acoustic DLs cannot be formed in a way similar to ion acoustic DLs. Linear theory analysis and the simulations show that the frequencies of electron acoustic waves are too high for ions to respond and maintain charge separation required by DLs. However, our results do show that local density perturbations in a two-electron-component plasma can result in unipolar-like electric field structures that propagate at the electron thermal speed, suggesting another potential explanation for the observations.

  5. After Boyle and the Leviathan: the second generation of British air pumps.

    PubMed

    Brundtland, Terje

    2011-01-01

    This paper examines the second generation of British air pumps, covering the period 1700-1750. The air pump originated in the 1650s and 1660s thanks to the work of Otto von Guericke in Magdeburg, Robert Boyle in Oxford and London, and Accademia del Cimento in Florence. While these first models were often seen as unreliable and temperamental, and available to a small group only, the next period saw the air pump transformed into a publicly accessible device for use in public and private demonstrations, in practical applications, as well as in the production of new knowledge. In England, the instrument maker Francis Hauksbee and his followers played a decisive role in this process, which was connected, among other things, to popular medicine, anatomy and health. In this period, pneumatics (the field of air pumps and air-pump practice) reached a state where the pump came to be regarded as an unproblematic tool; and where a vacuum' came to be thought of and handled as an object.

  6. Composite mixed ion-electron conducting (MIEC) membranes for hydrogen generation and separation

    NASA Astrophysics Data System (ADS)

    Wang, Haibing

    Decomposition of steam under a chemical driving force at moderate temperatures (˜900°C) offers a convenient and economical way to generate hydrogen. A significant amount of hydrogen can be generated and separated by splitting steam and removing oxygen using a mixed ion-electron conducting (MIEC) membrane. In this work, Gd0.2Ce0.8O1.9-deltaGd 0.08Sr0.88Ti0.95Al0.05O3+/-delta MIEC membranes have been explored in which, Gd0.2Ce 0.8O1.9-delta (GDC) functions as a predominantly oxygen ionic conductor, and Gd0.08Sr0.88Ti0.95Al 0.05O3+/-delta (GSTA) functions as a predominantly n-type electronic conductor under the process conditions. During the hydrogen generation process, oxygen transports from the feed side to the permeate side through coupled diffusion of oxygen ions and electrons under an oxygen partial pressure gradient across membranes. This process results in a H2-rich product on the feed side and depleted fuel gases on the permeate side. In this work, membrane architectures comprising self-supported thick membranes and thin membranes supported on porous supports of the same composition have been studied. The effect of membrane thickness on hydrogen generation has been studied by measuring the area-specific hydrogen generation rates at different experimental conditions. Experimental results have shown that the hydrogen generation process for the thick membranes was controlled by the oxygen bulk diffusion through membranes, while the hydrogen generation process for the dense thin membranes was controlled by both the surface exchange reactions and oxygen bulk diffusion process. The area-specific hydrogen generation rates of the supported dense thin membranes were significantly enhanced by applying a porous catalytic layer onto the surface of the membrane. Experimental results showed that the area-specific hydrogen generation rates were higher when the surface catalytic layer was exposed to the feed side rather than the permeate side. A mathematical model for

  7. Optical Measurements of Air Plasma

    DTIC Science & Technology

    2008-05-05

    generated in air by means of an electron beam is highly efficient. Fast electrons propagating through air result in production of electron- ion pairs...through the mechanism of impact ionization, which requires 33.7 eV per electron- ion pair. The air pressure, concentration of variable species, such as...and polyatomic species. Because our time scales are in the 1 ms to 10 ms range, there is a strong possibility of obtaining real-time absorption

  8. Evidence for electron-based ion generation in radio-frequency ionization.

    PubMed

    Olaitan, Abayomi D; Zekavat, Behrooz; Solouki, Touradj

    2016-01-01

    Radio-frequency ionization (RFI) is a novel ionization method coupled to mass spectrometry (MS) for analysis of semi-volatile and volatile organic compounds (VOCs). Despite the demonstrated capabilities of RFI MS for VOC analysis in both positive- and negative-ion modes, mechanism of RFI is not completely understood. Improved understanding of the ion generation process in RFI should expand its utility in MS. Here, we studied the possibility of electron emission in RFI using both direct charged particle current measurements and indirect electron detection in a 9.4-T Fourier transform-ion cyclotron resonance (FT-ICR) mass spectrometer. We show that RF-generated electrons can be trapped in the ICR cell and, subsequently, reacted with neutral hexafluorobenzene (C6 F6 ) molecules to generate C6 F6 (●-) . Intensity of observed C6 F6 (●-) species correlated with the number of trapped electrons and decreased as a function of electron quenching period. We also measured the electron attachment rate constant of hexafluorobenzene using a post-RF electron trapping experiment. Measured electron attachment rate constant of hexafluorobenzene (1.19 (±0.53) × 10(-9)  cm(3)  molecule(-1)  s(-1) ) for post-RF FT-ICR MS agreed with the previously reported value (1.60 (±0.30) × 10(-9)  cm(3)  molecule(-1)  s(-1) ) from low-pressure ICR MS measurements. Experimental results from direct and indirect electron measurements suggest that RFI process involves RF-generated electrons under ultrahigh vacuum conditions.

  9. Modeling and Simulation of the Second-Generation Orion Crew Module Air Bag Landing System

    NASA Technical Reports Server (NTRS)

    Timmers, Richard B.; Hardy, Robin C.; Willey, Cliff E.; Welch, Joseph V.

    2009-01-01

    Air bags were evaluated as the landing attenuation system for earth landing of the Orion Crew Module (CM). Analysis conducted to date shows that airbags are capable of providing a graceful landing of the CM in nominal and off-nominal conditions such as parachute failure, high horizontal winds, and unfavorable vehicle/ground angle combinations, while meeting crew and vehicle safety requirements. The analyses and associated testing presented here surround a second generation of the airbag design developed by ILC Dover, building off of relevant first-generation design, analysis, and testing efforts. In order to fully evaluate the second generation air bag design and correlate the dynamic simulations, a series of drop tests were carried out at NASA Langley s Landing and Impact Research (LandIR) facility in Hampton, Virginia. The tests consisted of a full-scale set of air bags attached to a full-scale test article representing the Orion Crew Module. The techniques used to collect experimental data, develop the simulations, and make comparisons to experimental data are discussed.

  10. [Air negative charge ion concentration and its relationships with meteorological factors in different ecological functional zones of Hefei City].

    PubMed

    Wei, Chaoling; Wang, Jingtao; Jiang, Yuelin; Zhang, Qingguo

    2006-11-01

    Air negative charge ion concentration (ANCIC) has a close relationship with air quality. The observations on the ANCIC, sunlight intensity, air temperature, and air relative humidity in different ecological functional zones of Hefei City from 2003 to 2004 showed that the diurnal change pattern of ANCIC was of single peak in sightseeing and habitation zones, dual peak in industrial zone, and complicated in commercial zone. Different ecological functional zones had different appearance time of their daily ANCIC extremum. The diurnal fluctuation of ANCIC was in the order of commercial zone > industrial zone > habitation zone and sightseeing zone. The annual change pattern of ANCIC in these zones was similar, being the highest in summer and lowest in winter, and the mean annual ANCIC was 819, 340, 149 and 126 ions x cm(-3), respectively. The most important meteorological factor affecting the ANCIC in Hefei City was air relative humidity, followed by sunlight intensity and air temperature. There was an exponential relationship between ANCIC and air relative humidity.

  11. Ultraweak emission of the Eu(III) ions in cathodic generated electrochemiluminescence

    NASA Astrophysics Data System (ADS)

    Staninski, K.; Lis, S.

    2011-08-01

    High voltage cathodic generated electrochemiluminescence (ECL) of selected systems generating weak photon emission was studied. The investigated systems contained europium salts, and co-reactants: H 2O 2 and K 2S 2O 8. During the cathodic pulse polarization of an oxide-covered working aluminum electrode, hot electrons in metal may enter the conduction band of water through the oxide layer/solution interface and turn into hydrated electron after salvation. The ECL intensity and spectra was measured though a suitable cut-off filters, with a photon counting unit attached to a PC computer. On the basis of the analysis of the spectra in particular systems, emitters were identified and simplified scheme of the processes was proposed. The Eu(III)-specific electro generated luminescence is produced via several parallel mechanisms, which usually involve a type of the co-reactant, oxidation state changes of europium ions in aqueous solution and the influence of working electrode surface emission.

  12. The generation, detection and measurement of laser-induced carbon plasma ions and their implantation effects on brass substrate

    NASA Astrophysics Data System (ADS)

    Ahmad, Shahbaz; Bashir, Shazia; Shahid Rafique, M.; Yousaf, Daniel; Ahmad, Riaz

    2016-05-01

    The generation, detection and measurement of laser-induced carbon plasma ions and their implantation effects on brass substrate have been investigated. Thomson parabola technique was employed to measure the energy and flux of carbon ions. The magnetic field of strength 80 mT was applied on the graphite plasma plume to provide an appropriate trajectory to the generated ions. The energy of carbon ions is 678 KeV for laser fluence of 5.1 J/cm2 which was kept constant for all exposures. The flux of ions varies from 32 × 1011 to 72 × 1014 ions/cm2 for varying numbers of laser pulses from 3000 to 12,000. In order to explore the ion irradiation effects on brass, four brass substrates were irradiated by carbon ions of different flux. Scanning electron microscope (SEM) and X-ray diffractometer (XRD) are used to analyze the surface morphology and crystallographic structure of ion-implanted brass, respectively. SEM analysis reveals the formation and growth of nano-/micro-sized cavities, pores and pits for the various ion flux for varying numbers of laser pulses from 3000 to 12,000. By increasing ion flux by increasing the number of pulses up to 9000 shots, the dendritic structures initiate to grow along with cavities and pores. At the maximum ion flux for 12,000 shots, the unequiaxed dendritic structures become distinct and the distance between the dendrites is decreased, whereas cavities, pores and pits are completely finished. The XRD analysis reveals that a new phase of ZnC (0012) is formed in the brass substrate after ion implantation. Universal tensile testing machine and Vickers microhardness tester are used to explore the yield stress, ultimate tensile strength and microhardness of ion-implanted brass substrate. The mechanical properties monotonically increase by increasing the ion flux. Variations in mechanical properties are correlated with surface and structural modifications of brass.

  13. Association of first- and second-generation air bags with front occupant death in car crashes: a matched cohort study.

    PubMed

    Olson, Carin M; Cummings, Peter; Rivara, Frederick P

    2006-07-15

    First-generation air bags entail a decreased risk of death for most front seat occupants in car crashes but an increased risk for children. Second-generation air bags were developed to reduce the risks for children, despite the possibility of decreasing protection for others. Using a matched cohort design, the authors estimated risk ratios for death for use of each generation of air bag versus no air bag, adjusted for seat position, restraint use, sex, age, and all vehicle and crash characteristics, among 128,208 automobile occupants involved in fatal crashes on US roadways during 1990-2002. The authors then compared adjusted risk ratios (aRRs) between the two generations of air bags. Among front seat occupants, the aRR for death with a first-generation air bag was 0.90 (95% confidence interval (CI): 0.86, 0.94); the aRR with a second-generation air bag was 0.89 (95% CI: 0.79, 1.00) (p = 0.83 for comparison of aRRs). Among children under age 6 years, the aRR with a first-generation air bag was 1.66 (95% CI: 1.20, 2.30), while the aRR with a second-generation air bag was 1.10 (95% CI: 0.63, 1.93) (p = 0.20 for comparison of aRRs). The differences in aRRs between first- and second-generation air bags among other subgroups were small and not statistically significant.

  14. Two-photon physics and the coming generation of heavy ion colliders

    SciTech Connect

    Rhoades-Brown, M.J.

    1992-01-01

    The possibilities for two-photon physics at the coming generation of heavy ion colliders is discussed. Particular attention is given to both e{sup +}, e{sup {minus}} production and resonance production of the Higgs particle. For e{sup +},e{sup {minus}} production the inadequacy of traditional perturbation theory is outlined, and through of the introduction of approximations valid for heavy ions it is shown how to sum a class of non-perturbative diagrams. The role of the nuclear form factor in suppressing the cross section for the heaviest resonances is also discussed. It is shown how this latter point affects the two-photon cross sections for W{sup +},W{sup {minus}} and Higgs production at RHIC, LHC and SSC energies.

  15. Two-photon physics and the coming generation of heavy ion colliders

    SciTech Connect

    Rhoades-Brown, M.J.

    1992-07-01

    The possibilities for two-photon physics at the coming generation of heavy ion colliders is discussed. Particular attention is given to both e{sup +}, e{sup {minus}} production and resonance production of the Higgs particle. For e{sup +},e{sup {minus}} production the inadequacy of traditional perturbation theory is outlined, and through of the introduction of approximations valid for heavy ions it is shown how to sum a class of non-perturbative diagrams. The role of the nuclear form factor in suppressing the cross section for the heaviest resonances is also discussed. It is shown how this latter point affects the two-photon cross sections for W{sup +},W{sup {minus}} and Higgs production at RHIC, LHC and SSC energies.

  16. Visualization of expanding warm dense gold and diamond heated uniformly by laser-generated ion beams

    NASA Astrophysics Data System (ADS)

    Bang, W.; Albright, B. J.; Bradley, P. A.; Gautier, D. C.; Palaniyappan, S.; Vold, E. L.; Santiago Cordoba, M. A.; Hamilton, C. E.; Fernández, J. C.

    2015-11-01

    With a laser-generated beam of quasi-monoenergetic ions, a solid density target can be heated uniformly and isochorically. On the LANL Trident laser facility, we have used a beam of quasi-monoenergetic aluminum ions to heat gold and diamond foils. We visualized directly the expanding warm dense gold and diamond with an optical streak camera. Furthermore, we present a new technique to determine the initial temperatures of these heated samples from the measured expansion speeds of gold and diamond into vacuum. These temperatures are in good agreement with the expected temperatures calculated using the total deposited energy into the cold targets and SESAME equation-of-state tables at solid densities. We anticipate the uniformly heated solid density target will allow for direct quantitative measurements of equation-of-state, conductivity, opacity, and stopping power of warm dense matter, benefiting plasma physics, astrophysics, and nuclear physics. *This work is sponsored by the LANL LDRD Program.

  17. Ion-scale secondary flux ropes generated by magnetopause reconnection as resolved by MMS

    NASA Astrophysics Data System (ADS)

    Eastwood, J. P.; Phan, T. D.; Cassak, P. A.; Gershman, D. J.; Haggerty, C.; Malakit, K.; Shay, M. A.; Mistry, R.; Øieroset, M.; Russell, C. T.; Slavin, J. A.; Argall, M. R.; Avanov, L. A.; Burch, J. L.; Chen, L. J.; Dorelli, J. C.; Ergun, R. E.; Giles, B. L.; Khotyaintsev, Y.; Lavraud, B.; Lindqvist, P. A.; Moore, T. E.; Nakamura, R.; Paterson, W.; Pollock, C.; Strangeway, R. J.; Torbert, R. B.; Wang, S.

    2016-05-01

    New Magnetospheric Multiscale (MMS) observations of small-scale (~7 ion inertial length radius) flux transfer events (FTEs) at the dayside magnetopause are reported. The 10 km MMS tetrahedron size enables their structure and properties to be calculated using a variety of multispacecraft techniques, allowing them to be identified as flux ropes, whose flux content is small (~22 kWb). The current density, calculated using plasma and magnetic field measurements independently, is found to be filamentary. Intercomparison of the plasma moments with electric and magnetic field measurements reveals structured non-frozen-in ion behavior. The data are further compared with a particle-in-cell simulation. It is concluded that these small-scale flux ropes, which are not seen to be growing, represent a distinct class of FTE which is generated on the magnetopause by secondary reconnection.

  18. Ion-scale secondary flux ropes generated by magnetopause reconnection as resolved by MMS.

    PubMed

    Eastwood, J P; Phan, T D; Cassak, P A; Gershman, D J; Haggerty, C; Malakit, K; Shay, M A; Mistry, R; Øieroset, M; Russell, C T; Slavin, J A; Argall, M R; Avanov, L A; Burch, J L; Chen, L J; Dorelli, J C; Ergun, R E; Giles, B L; Khotyaintsev, Y; Lavraud, B; Lindqvist, P A; Moore, T E; Nakamura, R; Paterson, W; Pollock, C; Strangeway, R J; Torbert, R B; Wang, S

    2016-05-28

    New Magnetospheric Multiscale (MMS) observations of small-scale (~7 ion inertial length radius) flux transfer events (FTEs) at the dayside magnetopause are reported. The 10 km MMS tetrahedron size enables their structure and properties to be calculated using a variety of multispacecraft techniques, allowing them to be identified as flux ropes, whose flux content is small (~22 kWb). The current density, calculated using plasma and magnetic field measurements independently, is found to be filamentary. Intercomparison of the plasma moments with electric and magnetic field measurements reveals structured non-frozen-in ion behavior. The data are further compared with a particle-in-cell simulation. It is concluded that these small-scale flux ropes, which are not seen to be growing, represent a distinct class of FTE which is generated on the magnetopause by secondary reconnection.

  19. Rare earth ions block the ion pores generated by the class II fusion proteins of alphaviruses and allow analysis of the biological functions of these pores.

    PubMed

    Koschinski, Andreas; Wengler, Gerd; Wengler, Gisela; Repp, Holger

    2005-12-01

    Recently, class II fusion proteins have been identified on the surface of alpha- and flaviviruses. These proteins have two functions besides membrane fusion: they generate an isometric lattice on the viral surface and they form ion-permeable pores at low pH. An attempt was made to identify inhibitors for the ion pores generated by the fusion proteins of the alphaviruses Semliki Forest virus and Sindbis virus. These pores can be detected and analysed in three situations: (i) in the target membrane during virus entry, by performing patch-clamp measurements of membrane currents; (ii) in the virus particle, by studying the entry of propidium iodide; and (iii) in the plasma membrane of infected cells, by Fura-2 fluorescence imaging of Ca2+ entry into infected cells. It is shown here that, at a concentration of 0.1 mM, rare earth ions block the ion permeability of alphavirus ion pores in all three situations. Even at a concentration of 0.5 mM, these ions do not block formation of the viral fusion pore, as they do not inhibit entry or multiplication of alphaviruses. The data indicate that ions flow through the ion pores into the virus particle in the endosome and from the endosome into the cytoplasm after fusion of the viral envelope with the endosomal membrane. These ion flows, however, are not necessary for productive infection. The possibility that the ability of class II fusion proteins to form ion-permeable pores reflects their origin from protein toxins that form ion-permeable pores, and that entry via class II fusion proteins may resemble the entry of non-enveloped viruses, is discussed.

  20. Real-time monitoring of bioaerosols via cell-lysis by air ion and ATP bioluminescence detection.

    PubMed

    Park, Chul Woo; Park, Ji-Woon; Lee, Sung Hwa; Hwang, Jungho

    2014-02-15

    In this study, we introduce a methodology for disrupting cell membranes with air ions coupled with ATP bioluminescence detection for real-time monitoring of bioaerosol concentrations. A carbon fiber ionizer was used to extract ATP from bacterial cells for generating ATP bioluminescence. Our methodology was tested using Staphylococcus epidermidis and Escherichia coli, which were aerosolized with an atomizer, and then indoor bioaerosols were also used for testing the methodology. Bioaerosol concentrations were estimated without culturing which requires several days for colony formation. Correlation equations were obtained for results acquired using our methodology (Relative Luminescent Unit (RLU)/m(3)) and a culture-based (Colony Forming Unit (CFU)/m(3)) method; CFU/m(3)=1.8 × measured RLU/m(3) for S. epidermidis and E. coli, and CFU/m(3)=1.1 × measured RLU/m(3) for indoor bioaerosols under the experimental conditions. Our methodology is an affordable solution for rapidly monitoring bioaerosols due to rapid detection time (cell-lysis time: 3 min; bioluminescence detection time: <1 min) and easy operation.

  1. Effect of air gap variation on the performance of single stator single rotor axial flux permanent magnet generator

    NASA Astrophysics Data System (ADS)

    Kasim, Muhammad; Irasari, Pudji; Hikmawan, M. Fathul; Widiyanto, Puji; Wirtayasa, Ketut

    2017-02-01

    The axial flux permanent magnet generator (AFPMG) has been widely used especially for electricity generation. The effect of the air gap variation on the characteristic and performances of single rotor - single stator AFPMG has been described in this paper. Effect of air gap length on the magnetic flux distribution, starting torque and MMF has been investigated. The two dimensional finite element magnetic method has been deployed to model and simulated the characteristics of the machine which is based on the Maxwell equation. The analysis has been done for two different air gap lengths which were 2 mm and 4 mm using 2D FEMM 4.2 software at no load condition. The increasing of air gap length reduces the air-gap flux density. For air gap 2 mm, the maximum value of the flux density was 1.04 T while 0.73 T occured for air gap 4 mm.. Based on the experiment result, the increasing air gap also reduced the starting torque of the machine with 39.2 Nm for air gap 2 mm and this value decreased into 34.2 Nm when the air gap increased to 4 mm. Meanwhile, the MMF that was generated by AFPMG decreased around 22% at 50 Hz due to the reduction of magnetic flux induced on stator windings. Overall, the research result showed that the variation of air gap has significant effect on the machine characteristics.

  2. NADPH oxidases as electrochemical generators to produce ion fluxes and turgor in fungi, plants and humans

    PubMed Central

    2016-01-01

    The NOXs are a family of flavocytochromes whose basic structure has been largely conserved from algae to man. This is a very simple system. NADPH is generally available, in plants it is a direct product of photosynthesis, and oxygen is a largely ubiquitous electron acceptor, and the electron-transporting core of an FAD and two haems is the minimal required to pass electrons across the plasma membrane. These NOXs have been shown to be essential for diverse functions throughout the biological world and, lacking a clear mechanism of action, their effects have generally been attributed to free radical reactions. Investigation into the function of neutrophil leucocytes has demonstrated that electron transport through the prototype NOX2 is accompanied by the generation of a charge across the membrane that provides the driving force propelling protons and other ions across the plasma membrane. The contention is that the primary function of the NOXs is to supply the driving force to transport ions, the nature of which will depend upon the composition and characteristics of the local ion channels, to undertake a host of diverse functions. These include the generation of turgor in fungi and plants for the growth of filaments and invasion by appressoria in the former, and extension of pollen tubes and root hairs, and stomatal closure, in the latter. In neutrophils, they elevate the pH in the phagocytic vacuole coupled to other ion fluxes. In endothelial cells of blood vessels, they could alter luminal volume to regulate blood pressure and tissue perfusion. PMID:27249799

  3. Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids

    SciTech Connect

    Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

    2012-03-14

    Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X− = Cl−, Br−) generates ethyl halides via halogen atom abstraction from FeXn3−n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ≥0.05 M X−. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M−1 s−1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M−1 s−1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

  4. Generation of multi-charged high current ion beams using the SMIS 37 gas-dynamic electron cyclotron resonance (ECR) ion source

    SciTech Connect

    Dorf, M. A.; Zorin, V. G.; Sidorov, A. V.; Bokhanov, A. F.; Izotov, I. V.; Razin, S. V.; Skalyga, V. A.

    2013-06-02

    A gas-dynamic ECR ion source (GaDIS) is distinguished by its ability to produce high current and high brightness beams of moderately charged ions. Contrary to a classical ECR ion source where the plasma confinement is determined by the slow electron scattering into an empty loss-cone, the higher density and lower electron temperature in a GaDIS plasma lead to an isotropic electron distribution with the confinement time determined by the prompt gas-dynamic flow losses. As a result, much higher ion fluxes are available, however a decrease in the confinement time of the GaDIS plasma lowers the ion charge state. The gas-dynamic ECR ion source concept has been successfully realized in the SMIS 37 experimental facility operated at the Institute of Applied Physics, Russia. The use of high-power (~100 kW) microwave (37.5 GHz) radiation provides a dense plasma (~1013 cm-3) with a relatively low electron temperature (~50- 100 eV) and allows for the generation of high current (~1 A/cm2) beams of multi-charged ions. In this work we report on the present status of the SMIS 37 ion source and discuss the advanced numerical modeling of ion beam extraction using the particle-in-cell code WARP

  5. Comparison of negative-ion proton-transfer with iodide ion chemical ionization mass spectrometry for quantification of isocyanic acid in ambient air

    NASA Astrophysics Data System (ADS)

    Woodward-Massey, Robert; Taha, Youssef M.; Moussa, Samar G.; Osthoff, Hans D.

    2014-12-01

    Isocyanic acid (HNCO) is a trace gas pollutant of potential importance to human health whose measurement has recently become possible through the development of negative-ion proton-transfer chemical ionization mass spectrometry (NI-PT-CIMS) with acetate reagent ion. In this manuscript, an alternative ionization and detection scheme, in which HNCO is quantified by iodide CIMS (iCIMS) as a cluster ion at m/z 170, is described. The sensitivity was inversely proportional to water vapor concentration but could be made independent of humidity changes in the sampled air by humidifying the ion-molecule reaction (IMR) region of the CIMS. The performance of the two ionization schemes was compared and contrasted using ambient air measurements of HNCO mixing ratios in Calgary, AB, Canada, by NI-PT-CIMS with acetate reagent ion from Dec 16 to 20, 2013, and by the same CIMS operated in iCIMS mode from Feb 3 to 7, 2014. The iCIMS exhibited a greater signal-to-noise ratio than the NI-PT-CIMS, not because of its sensitivity, which was lower (˜0.083 normalized counts per second (NCPS) per parts-per-trillion by volume (pptv) compared to ˜9.7 NCPS pptv-1), but because of a much lower and more stable background (3 ± 4 compared to a range of ˜2 × 103 to ˜6 × 103 NCPS). For the Feb 2014 data set, the HNCO mixing ratios in Calgary air ranged from <12 to 94 pptv (median 34 pptv), were marginally higher at night than during day, and correlated with nitrogen oxide (NOx = NO + NO2) mixing ratios and submicron particle volume. The ratios of HNCO to NOx observed are within the range of emission ratios reported for gasoline-powered motor vehicles.

  6. Innovative open air brayton combined cycle systems for the next generation nuclear power plants

    NASA Astrophysics Data System (ADS)

    Zohuri, Bahman

    The purpose of this research was to model and analyze a nuclear heated multi-turbine power conversion system operating with atmospheric air as the working fluid. The air is heated by a molten salt, or liquid metal, to gas heat exchanger reaching a peak temperature of 660 0C. The effects of adding a recuperator or a bottoming steam cycle have been addressed. The calculated results are intended to identify paths for future work on the next generation nuclear power plant (GEN-IV). This document describes the proposed system in sufficient detail to communicate a good understanding of the overall system, its components, and intended uses. The architecture is described at the conceptual level, and does not replace a detailed design document. The main part of the study focused on a Brayton --- Rankine Combined Cycle system and a Recuperated Brayton Cycle since they offer the highest overall efficiencies. Open Air Brayton power cycles also require low cooling water flows relative to other power cycles. Although the Recuperated Brayton Cycle achieves an overall efficiency slightly less that the Brayton --- Rankine Combined Cycle, it is completely free of a circulating water system and can be used in a desert climate. Detailed results of modeling a combined cycle Brayton-Rankine power conversion system are presented. The Rankine bottoming cycle appears to offer a slight efficiency advantage over the recuperated Brayton cycle. Both offer very significant advantages over current generation Light Water Reactor steam cycles. The combined cycle was optimized as a unit and lower pressure Rankine systems seem to be more efficient. The combined cycle requires a lot less circulating water than current power plants. The open-air Brayton systems appear to be worth investigating, if the higher temperatures predicted for the Next Generation Nuclear Plant do materialize.

  7. Time-of-flight secondary ion mass spectroscopy with bismuth primary ions of clean and air-exposed surfaces of tellurium.

    PubMed

    Trzyna, Malgorzata; Berchenko, Nicolas; Rading, Derk; Cebulski, Jozef

    2014-01-01

    The regularity of Bi(+), Bi(3+) and Bi(3++) primary ions in the time- of-flight secondary ion mass spectroscopy fragment pattern of air oxidized Te and Bi(+) direct-current scan cleaned Te is discussed. The most intensive fragments for a cleaned Te surface are positive and negative Tex and BiTex clusters. The sequence of secondary ion cluster formation is Bi-Te alloying followed by sputtering and ionization. For oxidized Te the chemical composition of the produced TexOy fragments satisfies the relation y=2x for positive fragments and y=2x+1 for negative ones. Experimental findings are in a good agreement with the results predicted by Plog's model for TeO2.

  8. Enhancement of ion generation in femtosecond ultraintense laser-foil interactions by defocusing

    SciTech Connect

    Xu, M. H.; Li, Y. T.; Liu, F.; Carroll, D. C.; McKenna, P.; Foster, P. S.; Hawkes, S.; Streeter, M. J. V.; Spindloe, C.; Neely, D.; Kar, S.; Markey, K.; Zepf, M.; Sheng, Z. M.; Zhang, J.; Wahlstroem, C.-G.; Zheng, J.

    2012-02-20

    A simple method to enhance ion generation with femtosecond ultraintense lasers is demonstrated experimentally by defocusing laser beams on target surface. When the laser is optimally defocused, we find that the population of medium and low energy protons from ultra-thin foils is increased significantly while the proton cutoff energy is almost unchanged. In this way, the total proton yield can be enhanced by more than 1 order, even though the peak laser intensity drops. The depression of the amplified spontaneous emission (ASE) effect and the population increase of moderate-energy electrons are believed to be the main reasons for the effective enhancement.

  9. Intense Ion Beam Generation, Plasma Radiation Source and Plasma Opening Switch Research

    DTIC Science & Technology

    1989-04-01

    ion source on the 150 kV, ls pulse , ifl LONG- SHOT pulsed power generator under NRL support. The completion of this task 2 will demonstrate both higher...following paragraph. This research is continuing under a new NRL-supported grant. 3 The POS system is pulsed by a 1.9MAF Scyllac capacitor charged to 50 kV...electric field measurements made in a surface flashover MID using emission spectroscopy by Maron et al.’ This LIF potential measuring technique could

  10. Silicon-Copper Helical Arrays for New Generation Lithium Ion Batteries

    SciTech Connect

    Polat, B. D.; Keles, O; Amine, K

    2015-09-22

    The helical array (with 10 atom % Cu) exhibits 3130 mAh g–1 with 83% columbic efficiency and retains 83% of its initial discharge capacity after 100th cycle. Homogeneously distributed interspaces between the helical arrays accommodate high volumetric changes upon cycling and copper atoms form a conductive network to buffer the mechanical stress generated in the electrode while minimizing electrochemical agglomeration of Si. Also, ion assistance is believed to enhance the density of the helices at the bottom thus increasing the adhesion

  11. Radio-frequency ion source generating beams with an increased proton content

    NASA Astrophysics Data System (ADS)

    Ivanov, A. A.; Podyminogin, A. A.; Shikhovtsev, I. V.

    2007-01-01

    The results of experiments with an rf ion source generating a beam with an improved mass composition are reported. The proton content in the beam is increased by raising the rf power density in the discharge under the antenna and installing a magnetic filter near the plasma grid. Additional steps are taken to prevent the earlier observed degradation of the beam composition because of aluminum reduction on the inner surface of the ceramic discharge chamber and water release. Specifically, the chamber is lined with pyrolytic boron nitride sheets.

  12. Quantitative comparison of a flared and a standard heated metal capillary inlet with a voltage-assisted air amplifier on an electrospray ionization linear ion trap mass spectrometer.

    PubMed

    Dixon, R Brent; Muddiman, David C

    2007-01-01

    The performance characteristics (i.e., ion abundance and electrospray ion current) of a flared and blunt-ended heated metal capillary were evaluated with a voltage-assisted air amplifier on a linear ion trap mass spectrometer (LTQ-MS). The results demonstrated that a standard capillary afforded higher ion abundance than a flared capillary, thus further work is necessary to investigate conditions for which significant benefits with the flared capillary will be observed. The compatibility of a voltage-assisted air amplifier is explored for both types of capillaries and in all cases resulted in improved ion abundance and spray current.

  13. Evaluation of ozone generation and indoor organic compounds removal by air cleaners based on chamber tests

    NASA Astrophysics Data System (ADS)

    Yu, Kuo-Pin; Lee, Grace Whei-May; Hsieh, Ching-Pei; Lin, Chi-Chi

    2011-01-01

    Ozone can cause many health problems, including exacerbation of asthma, throat irritation, cough, chest ache, shortness of breath, and respiratory infections. Air cleaners are one of the sources of indoor ozone, and thus the evaluation of ozone generated by air cleaners is desired significant issue. Most evaluation methods proposed are based on chamber tests. However, the adsorption and desorption of ozone on the wall of test chamber and the deposition of ozone resulted from the surface reaction can influence the evaluation results. In this study, we developed a mass balance model that took the adsorption, desorption and deposition of ozone into consideration to evaluate the effective ozone emission rates of six selected air cleaners. The experiments were conducted in a stainless steel chamber with a volume of 11.3 m 3 at 25 °C and 60% relative humidity. The adsorption, desorption and deposition rate constants of ozone obtained by fitting the model to the experimental data were k a = 0.149 ± 0.052 m h -1, k d = 0.013 ± 0.007 h -1, and k r = 0.050 ± 0.020 h -1, respectively. The effective ozone emission rates of Air Cleaners No. 1, 2, and 3 ranged between 13,400-24,500 μg h -1, 7190-10,400 μg h -1, and 4880-6560 μg h -1, respectively, which were more stable than those of No.4, 5, and 6. The effective ozone emission rates of Air Cleaners No. 4, 5, and 6 increased with the time of operation which might be relevant to the decrease of ozone removal by the "aging" filter installed in these cleaners. The removal of toluene and formaldehyde by these six air cleaners were also evaluated and the clean air delivery rates (CADRs) of these two pollutants ranged from non-detectable to 0.42 ± 0.08 m 3 h -1, and from non-detectable to 0.75 ± 0.07 m 3 h -1, respectively. The CADRs showed an insignificant relationship with the effective ozone emission rates. Thus, the removal of toluene and formaldehyde might be resulted from the adsorption on the filters and the

  14. Slow Dynamics Model of Compressed Air Energy Storage and Battery Storage Technologies for Automatic Generation Control

    SciTech Connect

    Krishnan, Venkat; Das, Trishna

    2016-05-01

    Increasing variable generation penetration and the consequent increase in short-term variability makes energy storage technologies look attractive, especially in the ancillary market for providing frequency regulation services. This paper presents slow dynamics model for compressed air energy storage and battery storage technologies that can be used in automatic generation control studies to assess the system frequency response and quantify the benefits from storage technologies in providing regulation service. The paper also represents the slow dynamics model of the power system integrated with storage technologies in a complete state space form. The storage technologies have been integrated to the IEEE 24 bus system with single area, and a comparative study of various solution strategies including transmission enhancement and combustion turbine have been performed in terms of generation cycling and frequency response performance metrics.

  15. Enhanced third harmonic generation in air by two-colour ultrashort laser pulses

    NASA Astrophysics Data System (ADS)

    Nath, Arpita; Dharmadhikari, J. A.; Mathur, D.; Dharmadhikari, A. K.

    2016-09-01

    We report on third harmonic generation in air in a non-filamentation regime using tightly focused, ultrashort laser pulses (1-2 µm wavelength). Enhancement in the third harmonic efficiency is observed from co-propagating laser pulses of two different wavelengths which emanate from the same source—an optical parametric amplifier—and are spatially and temporally overlapped. The third harmonic efficiency for signal wavelength (1.35 µm) is measured to be 4 × 10-3 %; in the presence of idler wavelength (2.09 µm), the corresponding value becomes 1.6 × 10-2 %—a fourfold enhancement in efficiency. The pulse duration of the generated third harmonic is measured to be 37 fs. We examine the possible role of plasma to account for the observed enhancement in third harmonic generation.

  16. Trajectory Assessment and Modification Tools for Next Generation Air Traffic Management Operations

    NASA Technical Reports Server (NTRS)

    Brasil, Connie; Lee, Paul; Mainini, Matthew; Lee, Homola; Lee, Hwasoo; Prevot, Thomas; Smith, Nancy

    2011-01-01

    This paper reviews three Next Generation Air Transportation System (NextGen) based high fidelity air traffic control human-in-the-loop (HITL) simulations, with a focus on the expected requirement of enhanced automated trajectory assessment and modification tools to support future air traffic flow management (ATFM) planning positions. The simulations were conducted at the National Aeronautics and Space Administration (NASA) Ames Research Centers Airspace Operations Laboratory (AOL) in 2009 and 2010. The test airspace for all three simulations assumed the mid-term NextGenEn-Route high altitude environment utilizing high altitude sectors from the Kansas City and Memphis Air Route Traffic Control Centers. Trajectory assessment, modification and coordination decision support tools were developed at the AOL in order to perform future ATFM tasks. Overall tool usage results and user acceptability ratings were collected across three areas of NextGen operatoins to evaluate the tools. In addition to the usefulness and usability feedback, feasibility issues, benefits, and future requirements were also addressed. Overall, the tool sets were rated very useful and usable, and many elements of the tools received high scores and were used frequently and successfully. Tool utilization results in all three HITLs showed both user and system benefits including better airspace throughput, reduced controller workload, and highly effective communication protocols in both full Data Comm and mixed-equipage environments.

  17. Generation of highly charged peptide and protein ions by atmospheric pressure matrix-assisted infrared laser desorption/ionization ion trap mass spectrometry.

    PubMed

    König, Simone; Kollas, Oliver; Dreisewerd, Klaus

    2007-07-15

    We show that highly charged ions can be generated if a pulsed infrared laser and a glycerol matrix are employed for atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry with a quadrupole ion trap. Already for small peptides like bradykinin, doubly protonated ions form the most abundant analyte signal in the mass spectra. The center of the charge-state distribution increases with the size of the analyte. For example, insulin is detected with a most abundant ion signal corresponding to a charge state of four, whereas for cytochrome c, the 10 times protonated ion species produces the most intense signal. Myoglobin is observed with up to 13 charges. The high m/z ratios allow us to use the Paul trap for the detection of MALDI-generated protein ions that are, owing to their high molecular weight, not amenable in their singly protonated charge state. Formation of multiple charges critically depends on the addition of diluted acid to the analyte-matrix solution. Tandem mass spectra generated by collision-induced dissociation of doubly charged peptides are also presented. The findings allow speculations about the involvement of electrospray ionization processes in these MALDI experiments.

  18. Phytic acid suppresses 1-methyl-4-phenylpyridinium ion-induced hydroxyl radical generation in rat striatum.

    PubMed

    Obata, Toshio

    2003-07-18

    The present study examined the antioxidant effect of phytic acid on iron (II)-enhanced hydroxyl radical (*OH) generation induced by 1-methyl-4-phenylpyridinium ion (MPP(+)) in the extracellular fluid of rat striatum. Rats were anesthetized, and sodium salicylate in Ringer's solution (0.5 nmol/microl/min) was infused through a microdialysis probe to detect the generation of *OH as reflected by the non-enzymatic formation of 2,3-dihydroxybenzoic acid (DHBA) in the striatum. Phytic acid (100 microM) did not significantly decrease the levels of MPP(+)-induced *OH formation trapped as 2,3-DHBA. To confirm the generation of *OH by the Fenton-type reaction, iron (II) was infused through a microdialysis probe. Introduction of iron (II) (10 microM) enhanced MPP(+) induced *OH generation. However, phytic acid significantly suppressed iron (II)-enhanced *OH formation after MPP(+) treatment (n=6, P<0.05). These results suggest that the antiradical effect of phytic acid occurs by chelating iron required for the MPP(+)-enhanced *OH generation via the Fenton-type reaction.

  19. Energetic negative ion and neutral atom beam generation at passage of laser accelerated high energy positive ions through a liquid spray

    NASA Astrophysics Data System (ADS)

    Abicht, F.; Prasad, R.; Priebe, G.; Braenzel, J.; Ehrentraut, L.; Andreev, A.; Nickles, P. V.; Schnürer, M.; Tikhonchuk, V.; Ter-Avetisyan, Sargis

    2013-05-01

    Beams of energetic negative ions and neutral atoms are obtained from water and ethanol spray targets irradiated by high intensity (5×1019 W/cm2) and ultrashort (50 fs) laser pulses. The resulting spectra were measured with the Thomson parabola spectrometer, which enabled absolute measurements of both: positive and negative ions. The generation of a beam of energetic neutral hydrogen atoms was confirmed with CR-39 track detectors and their spectral characteristics have been measured using time of flight technique. Generation is ascribed to electron-capture and -loss processes in the collisions of laser-accelerated high-energy protons with spray of droplets. The same method can be applied to generate energetic negative ions and neutral atoms of different species.

  20. The initial generation of waves in an accelerated coupled air-water flow.

    NASA Astrophysics Data System (ADS)

    Veron, Fabrice; Ierley, Glenn; Melville, Ken

    2001-11-01

    The initial generation of surface waves over the ocean has a long been a problem of great interest. With the globally averaged wind speed in the range 6-7 m/s, and 40 % of the time below 6 m/s, much of the air-sea interface is in a low wind speed regime, and therefore the initial generation of waves under these conditions is of special interest. There is also a transition in the surface heat flux and surface cool skin at these low wind speeds when gravity capillary waves are first generated. We present the results of laboratory and field experiments, and numerical studies, on the stability of a wind-driven water surface to the initial generation of surface waves. Using modern quantitative flow visualization techniques, we show that the classical wave generation problem, where the wind is linearly accelerated over a still water surface, leads to the generation of a two-dimensional wave field. At this stage, the flow in the water phase has been observed to be sub-critical. These results are compared with numerical solutions of the stability of the coupled air-water problem obtained by solving both the linear and non-linear Orr-Sommerfeld coupled equations. The effects of non-linearity will be discussed. In addition, we show that the wave generation problem is accompanied by the turbulent transition of the water surface boundary layer through the formation and dislocation of Langmuir circulations. Field data suggest that this transition, rather than microscale breaking waves, first disrupt the cool skin. We show that this turbulent transition also marks the change from a two- to three-dimensional surface wave field as the coherent sub-surface velocities modulate the waves. This rapid evolution from 2D to 3D surface wave patterns in the early stages of the wave generation implies that 2D models for wind-wave generation might only apply in the very early stages of wave growth. This will be discussed in light of linear and non-linear wave generation models.

  1. Li-ion microbatteries generated by a laser direct-write method

    NASA Astrophysics Data System (ADS)

    Wartena, Ryan; Curtright, Aimee E.; Arnold, Craig B.; Piqué, Alberto; Swider-Lyons, Karen E.

    A laser-based direct-write process is demonstrated as a method to fabricate Li-ion microbatteries. The battery electrodes are made by the laser-induced forward transfer of inks of charge-storage materials (composites of carbon/binder and LiCoO 2/carbon/binder) onto micromachined metal-foil current collectors to form 40-60 μm thick electrodes with 16 mm 2(4 mm×4 mm) footprints. Both half cells and packaged microbatteries display capacities of approximately 155 μAh or 100 mAh/g, as normalized to the amount of LiCoO 2, and are comparable to the capacities of control electrodes that have been stenciled and pressed. The electrode capacities are not compromised when they are assembled into microbatteries, packaged and tested in air. The density and volumetric capacity of the laser-transferred electrodes are lower than those reported for sputtered thin-film microbatteries, yet the former electrodes can be made thicker and therefore deliver the same amount of charge from a smaller footprint. The data indicate that this laser direct-write method may be a viable approach for developing Li-ion microbattery systems for autonomous microelectronic devices and microsensors.

  2. Generation of ion-acoustic waves in an inductively coupled, low-pressure discharge lamp

    SciTech Connect

    Camparo, J. C.; Klimcak, C. M.

    2006-04-15

    For a number of years it has been known that the alkali rf-discharge lamps used in atomic clocks can exhibit large amplitude intensity oscillations. These oscillations arise from ion-acoustic plasma waves and have typically been associated with erratic clock behavior. Though large amplitude ion-acoustic plasma waves are clearly deleterious for atomic clock operation, it does not follow that small amplitude oscillations have no utility. Here, we demonstrate two easily implemented methods for generating small amplitude ion-acoustic plasma waves in alkali rf-discharge lamps. Furthermore, we demonstrate that the frequency of these waves is proportional to the square root of the rf power driving the lamp and therefore that their examination can provide an easily accessible parameter for monitoring and controlling the lamp's plasma conditions. This has important consequences for precise timekeeping, since the atomic ground-state hyperfine transition, which is the heart of the atomic clock signal, can be significantly perturbed by changes in the lamp's output via the ac-Stark shift.

  3. Quantum entanglement generation in trapped ions using coherent and dissipative methods

    NASA Astrophysics Data System (ADS)

    Lin, Yiheng

    Entangled states are a key resource in fundamental quantum physics, quantum cryptography, and quantum computation. In this thesis, we focus on the demonstrations of two novel methods to generate entanglement. First, we implement dissipative production of a maximally entangled steady state on two trapped ions. Dissipative and coherent processes are combined and implemented in a continuous time-independent fashion, analogous to optical pumping of atomic states, continuously driving the system towards the steady entangled state. With this method, we obtain a Bell state fidelity up to 0.89(2). Second, we propose and demonstrate a novel coherent process to confine quantum evolution in a subspace between an initial separable state and the target entangled state. We demonstrate this scheme on two and three ions obtaining a Bell state fidelity up to 0.992(2). Both of these methods are robust against certain types of experimental noise and decoherence. Additionally, we demonstrate sympathetic cooling of ion chains to near the ground state of motion with an electromagnetically-induced-transparency (EIT) method. This results in roughly an order of magnitude faster cooling time while using significantly lower laser power compared to the conventional resolved sideband cooling method. These techniques may be helpful for scaled-up quantum computing.

  4. Generation of large coherent states by bang–bang control of a trapped-ion oscillator

    PubMed Central

    Alonso, J.; Leupold, F. M.; Solèr, Z. U.; Fadel, M.; Marinelli, M.; Keitch, B. C.; Negnevitsky, V.; Home, J. P.

    2016-01-01

    Fast control of quantum systems is essential to make use of quantum properties before they degrade by decoherence. This is important for quantum-enhanced information processing, as well as for pushing quantum systems towards the boundary between quantum and classical physics. ‘Bang–bang' control attains the ultimate speed limit by making large changes to control fields much faster than the system can respond, but is often challenging to implement experimentally. Here we demonstrate bang–bang control of a trapped-ion oscillator using nanosecond switching of the trapping potentials. We perform controlled displacements with which we realize coherent states with up to 10,000 quanta of energy. We use these displaced states to verify the form of the ion-light interaction at high excitations far outside the usual regime of operation. These methods provide new possibilities for quantum-state manipulation and generation, alongside the potential for a significant increase in operational clock speed for trapped-ion quantum information processing. PMID:27046513

  5. Event Generators for Simulating Heavy Ion Interactions of Interest in Evaluating Risks in Human Spaceflight

    NASA Technical Reports Server (NTRS)

    Wilson, Thomas L.; Pinsky, Lawrence; Andersen, Victor; Empl, Anton; Lee, Kerry; Smirmov, Georgi; Zapp, Neal; Ferrari, Alfredo; Tsoulou, Katerina; Roesler, Stefan; Vlachoudis, Vasilis

    2005-01-01

    Simulating the Space Radiation environment with Monte Carlo Codes, such as FLUKA, requires the ability to model the interactions of heavy ions as they penetrate spacecraft and crew member's bodies. Monte-Carlo-type transport codes use total interaction cross sections to determine probabilistically when a particular type of interaction has occurred. Then, at that point, a distinct event generator is employed to determine separately the results of that interaction. The space radiation environment contains a full spectrum of radiation types, including relativistic nuclei, which are the most important component for the evaluation of crew doses. Interactions between incident protons with target nuclei in the spacecraft materials and crew member's bodies are well understood. However, the situation is substantially less comfortable for incident heavier nuclei (heavy ions). We have been engaged in developing several related heavy ion interaction models based on a Quantum Molecular Dynamics-type approach for energies up through about 5 GeV per nucleon (GeV/A) as part of a NASA Consortium that includes a parallel program of cross section measurements to guide and verify this code development.

  6. Antimicrobial action of essential oil vapours and negative air ions against Pseudomonas fluorescens.

    PubMed

    Tyagi, A K; Malik, A

    2010-10-15

    The aim of this study was to investigate the antibacterial activity of essential oil (in liquid as well as in vapour phase) and negative air ions (NAI) against Pseudomonas fluorescens. The combined effect of NAI with essential oil vapour was also investigated to determine kill time and morphological changes in bacterial cells. The MIC of Cymbopogon citratus (0.567 mg/ml), Mentha arvensis (0.567 mg/ml), Mentha piperita (1.125 mg/ml) and Eucalyptus globulus (2.25 mg/ml) was studied via the agar dilution method. To estimate the antibacterial activity of essential oils in the vapour phase, agar plates inoculated with P. fluorescens were incubated with various concentrations of each essential oil vapour and zone of inhibition was recorded. Further, in order to assess the kill time, P. fluorescens inoculated agar plates were exposed to selected bactericidal essential oil vapour and NAI, separately, in an air-tight chamber. A continuous decrease in bacterial count was observed over time. A significant enhancement in the bactericidal action was observed by exposure to the combination of essential oil vapour and NAI as compared to their individual action. Scanning electron microscopy was used to study the alteration in morphology of P. fluorescens cells after exposure to C. citratus oil vapour, NAI, and combination of C. citratus oil vapour and NAI. Maximum morphological deformation was found due to the combined effect of C. citratus oil vapour and NAI. This study demonstrates that the use of essential oils in the vapour phase is more advantageous than the liquid phase. Further the antibacterial effect of the essential oil vapours can be significantly enhanced by the addition of NAI. The work described here offers a novel and efficient approach for control of bacterial contamination that could be applied for food stabilization practices.

  7. Dynamical properties of breaking waves: dissipation, air entrainment and spray generation

    NASA Astrophysics Data System (ADS)

    Deike, Luc; Melville, W. Kendall; Popinet, Stephane

    2016-11-01

    Wave breaking in the ocean is of fundamental importance in order to quantify wave dissipation and air-sea interaction, including gas and momentum exchange, and to improve parametrization for ocean-atmosphere exchange in weather and climate models. Here, we present 2D and 3D direct numerical simulations of breaking waves, compared with laboratory measurements. The dissipation due to breaking in the 2D and 3D simulations is found to be in good agreement with experimental observations and inertial-scaling arguments. We discuss the transition from a 2D to a 3D flow during breaking. We present a model for air entrainment and bubble statistics that describes well the experimental and numerical data, and is based on turbulent fragmentation of the bubbles and a balance between buoyancy forces and viscous dissipation. Finally we discuss the generation of large drops during the impact and splashing process.

  8. Ionization of large homogeneous and heterogeneous clusters generated in acetylene-Ar expansions: Cluster ion polymerization

    SciTech Connect

    Kocisek, J.; Lengyel, J.; Farnik, M.

    2013-03-28

    Pure acetylene and mixed Ar-acetylene clusters are formed in supersonic expansions of acetylene/argon mixtures and analysed using reflectron time-of-flight mass spectrometer with variable electron energy ionization source. Acetylene clusters composed of more than a hundred acetylene molecules are generated at the acetylene concentration of Almost-Equal-To 8%, while mixed species are produced at low concentrations ( Almost-Equal-To 0.7%). The electron energy dependence of the mass spectra revealed the ionization process mechanisms in clusters. The ionization above the threshold for acetylene molecule of 11.5 eV results in the main ionic fragment progression (C{sub 2}H{sub 2}){sub n}{sup +}. At the electron energies Greater-Than-Or-Slanted-Equal-To 21.5 eV above the CH+CH{sup +} dissociative ionization limit of acetylene the fragment ions nominally labelled as (C{sub 2}H{sub 2}){sub n}CH{sup +}, n Greater-Than-Or-Slanted-Equal-To 2, are observed. For n Less-Than-Or-Slanted-Equal-To 7 these fragments correspond to covalently bound ionic structures as suggested by the observed strong dehydrogenation [(C{sub 2}H{sub 2}){sub n}-k Multiplication-Sign H]{sup +} and [(C{sub 2}H{sub 2}){sub n}CH -k Multiplication-Sign H]{sup +}. The dehydrogenation is significantly reduced in the mixed clusters where evaporation of Ar instead of hydrogen can stabilize the nascent molecular ion. The C{sub 3}H{sub 3}{sup +} ion was previously assigned to originate from the benzene molecular ion; however, the low appearance energy of Almost-Equal-To 13.7 eV indicates that a less rigid covalently bound structure of C{sub 6}H{sub 6}{sup +} ion must also be formed upon the acetylene cluster electron ionization. The appearance energy of Ar{sub n}(C{sub 2}H{sub 2}){sup +} fragments above Almost-Equal-To 15.1 eV indicates that the argon ionization is the first step in the fragment ion production, and the appearance energy of Ar{sub n{>=}2}(C{sub 2}H{sub 2}){sub m{>=}2}{sup +} at Almost-Equal-To 13

  9. Modelling and simulation of wood chip combustion in a hot air generator system.

    PubMed

    Rajika, J K A T; Narayana, Mahinsasa

    2016-01-01

    This study focuses on modelling and simulation of horizontal moving bed/grate wood chip combustor. A standalone finite volume based 2-D steady state Euler-Euler Computational Fluid Dynamics (CFD) model was developed for packed bed combustion. Packed bed combustion of a medium scale biomass combustor, which was retrofitted from wood log to wood chip feeding for Tea drying in Sri Lanka, was evaluated by a CFD simulation study. The model was validated by the experimental results of an industrial biomass combustor for a hot air generation system in tea industry. Open-source CFD tool; OpenFOAM was used to generate CFD model source code for the packed bed combustion and simulated along with an available solver for free board region modelling in the CFD tool. Height of the packed bed is about 20 cm and biomass particles are assumed to be spherical shape with constant surface area to volume ratio. Temperature measurements of the combustor are well agreed with simulation results while gas phase compositions have discrepancies. Combustion efficiency of the validated hot air generator is around 52.2 %.

  10. Systematic generation of buffer systems for pH gradient ion exchange chromatography and their application.

    PubMed

    Kröner, Frieder; Hubbuch, Jürgen

    2013-04-12

    pH gradient protein separations are widely used techniques in the field of protein analytics, of which isoelectric focusing is the most well known application. The chromatographic variant, based on the formation of pH gradients in ion exchange columns is only rarely applied due to the difficulties to form controllable, linear pH gradients over a broad pH range. This work describes a method for the systematic generation of buffer compositions with linear titration curves, resulting in well controllable pH gradients. To generate buffer compositions with linear titration curves an in silico method was successfully developed. With this tool, buffer compositions for pH gradient ion exchange chromatography with pH ranges spanning up to 7.5 pH units were established and successfully validated. Subsequently, the buffer systems were used to characterize the elution behavior of 22 different model proteins in cation and anion exchange pH gradient chromatography. The results of both chromatographic modes as well as isoelectric focusing were compared to describe differences in between the methods.

  11. Thermal behavior and electrochemical heat generation in a commercial 40 Ah lithium ion pouch cell

    NASA Astrophysics Data System (ADS)

    Schuster, Elke; Ziebert, Carlos; Melcher, Andreas; Rohde, Magnus; Seifert, Hans Jürgen

    2015-07-01

    Quantitative data on the thermal behavior of lithium ion batteries under charging and discharging conditions are essential for designing thermal management systems and improving battery safety. In this work, commercial 40 Ah lithium ion pouch cells with Li(Ni1/3Mn1/3Co1/3)O2 cathodes were tested under isoperibolic and adiabatic conditions in an Accelerating Rate Calorimeter at different charging/discharging currents from 5 A to 40 A. Adiabatic tests simulate the worst-case scenario of a battery pack without cooling. For charging and discharging an overall exothermic behavior was found and a total temperature increase for one half cycle between 3 and 11 K. Isoperibolic tests simulate a single cell under constant environmental temperature. Here an exothermic behavior for discharging and an endothermic behavior for charging were observed. To transfer the measured temperature changes into heat data, the effective specific heat capacity and the heat transfer coefficient were determined. For the first time the heat generation data for a large format pouch cell have been determined using both isoperibolic and adiabatic conditions. These data were compared with the total heat data calculated as the sum of reversible and irreversible heat that were measured by potentiometric and current interruption techniques respectively. A good agreement was found between all three heat generation determination methods.

  12. Gyrotron-driven high current ECR ion source for boron-neutron capture therapy neutron generator

    NASA Astrophysics Data System (ADS)

    Skalyga, V.; Izotov, I.; Golubev, S.; Razin, S.; Sidorov, A.; Maslennikova, A.; Volovecky, A.; Kalvas, T.; Koivisto, H.; Tarvainen, O.

    2014-12-01

    Boron-neutron capture therapy (BNCT) is a perspective treatment method for radiation resistant tumors. Unfortunately its development is strongly held back by a several physical and medical problems. Neutron sources for BNCT currently are limited to nuclear reactors and accelerators. For wide spread of BNCT investigations more compact and cheap neutron source would be much more preferable. In present paper an approach for compact D-D neutron generator creation based on a high current ECR ion source is suggested. Results on dense proton beams production are presented. A possibility of ion beams formation with current density up to 600 mA/cm2 is demonstrated. Estimations based on obtained experimental results show that neutron target bombarded by such deuteron beams would theoretically yield a neutron flux density up to 6·1010 cm-2/s. Thus, neutron generator based on a high-current deuteron ECR source with a powerful plasma heating by gyrotron radiation could fulfill the BNCT requirements significantly lower price, smaller size and ease of operation in comparison with existing reactors and accelerators.

  13. Programmable ion-sensitive transistor interfaces. III. Design considerations, signal generation, and sensitivity enhancement

    NASA Astrophysics Data System (ADS)

    Jayant, Krishna; Auluck, Kshitij; Rodriguez, Sergio; Cao, Yingqiu; Kan, Edwin C.

    2014-05-01

    We report on factors that affect DNA hybridization detection using ion-sensitive field-effect transistors (ISFETs). Signal generation at the interface between the transistor and immobilized biomolecules is widely ascribed to unscreened molecular charges causing a shift in surface potential and hence the transistor output current. Traditionally, the interaction between DNA and the dielectric or metal sensing interface is modeled by treating the molecular layer as a sheet charge and the ionic profile with a Poisson-Boltzmann distribution. The surface potential under this scenario is described by the Graham equation. This approximation, however, often fails to explain large hybridization signals on the order of tens of mV. More realistic descriptions of the DNA-transistor interface which include factors such as ion permeation, exclusion, and packing constraints have been proposed with little or no corroboration against experimental findings. In this study, we examine such physical models by their assumptions, range of validity, and limitations. We compare simulations against experiments performed on electrolyte-oxide-semiconductor capacitors and foundry-ready floating-gate ISFETs. We find that with weakly charged interfaces (i.e., low intrinsic interface charge), pertinent to the surfaces used in this study, the best agreement between theory and experiment exists when ions are completely excluded from the DNA layer. The influence of various factors such as bulk pH, background salinity, chemical reactivity of surface groups, target molecule concentration, and surface coatings on signal generation is studied. Furthermore, in order to overcome Debye screening limited detection, we suggest two signal enhancement strategies. We first describe frequency domain biosensing, highlighting the ability to sort short DNA strands based on molecular length, and then describe DNA biosensing in multielectrolytes comprising trace amounts of higher-valency salt in a background of

  14. Development of a high brightness, ohmically generated thin film lithium ion source

    SciTech Connect

    Menge, P.R.; Cuneo, M.E.; Bernard, M.A.; Fowler, W.E.

    1997-12-31

    A pure lithium ion source with low source divergence capable of generating high current density beams ({approx}1,000 A/cm{sup 2}) is required for pursuing the goal of light ion inertial confinement fusion using pulsed power. It is believed that a uniform fully ionized lithium plasma at the anode surface ({approx}100 cm{sup 2}) created just before arrival of the main power pulse (5--30 MV, 0.1--1 MA, 40--60 ns) will be superior to flashover or field-threshold lithium sources. One method being pursued at Sandia is the development of an ohmically driven thin film lithium source, often termed EMFAPS. The EMFAPS process consists of an electrical pulse driven through a thin film coated with or bearing lithium in alloy or compound. The high current flowing through a thin film coated with or bearing lithium in alloy or compound. The high current flowing through the film increases its temperature and resistivity until the lithium is driven off as vapor. The resistive voltage drop across the film generates a plasma by a gas discharge. Low impedance, fast risetime pulsers provided by NRL and Pulse Sciences Inc. are being assembled and evaluated as film current drivers for full scale anodes ({approx}70 cm{sup 2}). Smaller scale ({approx}1 cm{sup 2}) tests are underway to optimize film composition, current contact engineering, anode construction, impedance dynamics, and energy disposition. Plasma discharge cleaning, bakeouts, film design and material selection issues are also being characterized to improve ion purity.

  15. The novel selected-ion flow tube approach to trace gas analysis of air and breath.

    PubMed

    Smith, D; Spanel, P

    1996-01-01

    We present an overview of the development and use of our selected-ion flow tube (SIFT) technique as a sensitive, quantitative method for the rapid, real-time analysis of the trace gas content of atmospheric air and human breath, presenting some pilot data from various research areas in which this method will find valuable application. We show that it is capable of detecting and quantifying trace gases, in complex mixtures such as breath, which are present at partial pressures down to about 10 parts per billion. Following discussions of the principles involved in this SIFT method of analysis, of the experiments which we have carried out to establish its quantitative validity, and of the air and breath sampling techniques involved, we present sample data on the detection and quantification of trace gases on the breath of healthy people and of patients suffering from renal failure and diabetes. We also show how breath ammonia can be accurately quantified from a single breath exhalation and used as an indicator of the presence in the stomach of the bacterium Helicobacter pylori. Health and safety applications are exemplified by analyses of the gases of the gases of cigarette smoke and on the breath of smokers. The value of this analytical method in environmental science is demonstrated by the analyses of petrol vapour, car exhaust emissions and the trace organic vapours detected in town air near a busy road. Final examples of the value of this analytical method are the detection and quantification of the gases emitted from crushed garlic and from breath following the chewing of a mint, which demonstrate its potential in food and flavour research. Throughout the paper we stress the advantages of this SIFT method compared to conventional mass spectrometry for trace gas analysis of complex mixtures, emphasizing its selectivity, sensitivity and real-time analysis capability. Finally, we note that whilst the current SIFT is strictly laboratory based, both transportable and

  16. The spatial relationship between traffic-generated air pollution and noise in 2 US cities.

    PubMed

    Allen, Ryan W; Davies, Hugh; Cohen, Martin A; Mallach, Gary; Kaufman, Joel D; Adar, Sara D

    2009-04-01

    Traffic-generated air pollution and noise have both been linked to cardiovascular morbidity. Since traffic is a shared source, there is potential for correlated exposures that may lead to confounding in epidemiologic studies. As part of the Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air), 2-week NO and NO(2) concentrations were measured at up to 105 locations, selected primarily to characterize gradients near major roads, in each of 9 US communities. We measured 5-min A-weighted equivalent continuous sound pressure levels (L(eq)) and ultrafine particle (UFP) counts at a subset of these NO/NO(2) monitoring locations in Chicago, IL (N=69 in December 2006; N=36 in April 2007) and Riverside County, CA (N=46 in April 2007). L(eq) and UFP were measured during non-"rush hour" periods (10:00-16:00) to maximize comparability between measurements. We evaluated roadway proximity exposure surrogates in relation to the measured levels, estimated noise-air pollution correlation coefficients, and evaluated the impact of regional-scale pollution gradients, wind direction, and roadway proximity on the correlations. Five-minute L(eq) measurements in December 2006 and April 2007 were highly correlated (r=0.84), and measurements made at different times of day were similar (coefficients of variation: 0.5-13%), indicating that 5-min measurements are representative of long-term L(eq). Binary and continuous roadway proximity metrics characterized L(eq) as well or better than NO or NO(2). We found strong regional-scale gradients in NO and NO(2), particularly in Chicago, but only weak regional-scale gradients in L(eq) and UFP. L(eq) was most consistently correlated with NO, but the correlations were moderate (0.20-0.60). After removing the influence of regional-scale gradients the correlations generally increased (L(eq)-NO: r=0.49-0.62), and correlations downwind of major roads (L(eq)-NO: r=0.53-0.74) were consistently higher than those upwind (0.35-0.65). There was not a

  17. Impacts of Air Pollution on Solar Photovoltaic Electricity Generation in China

    NASA Astrophysics Data System (ADS)

    Li, X.; Mauzerall, D. L.; Wagner, F.; Yang, J.

    2015-12-01

    Solar photovoltaic (PV) electricity generation has been expanding rapidly in China with total capacity quadrupled from 8 to 32 GW between 2012 and 2014. Studies find that China has the potential to increase solar PV in total energy generation up towards 10% (about 300 GW in total capacity) by 2030. However, severe air pollution in China reduces the productivity of solar PV panels by scattering and absorbing sunlight before it reaches the surface. In this study, we first calculate the surface radiative forcing of anthropogenic aerosols (considering only the direct effect) over China from 2003 to 2013 using the Monitoring Atmospheric Composition and Climate (MACC) reanalysis dataset constrained by satellite derived greenhouse gas, reactive gases and aerosols. Our results indicate that, from 2003-2013, the attenuation of sunlight by aerosols over Eastern China averaged about -25 W m-2 compared with the global mean effect of -4.4 W m-2. The largest attenuation is found in Northern China in spring when mean attenuation reached as high as -57 W m-2. This attenuation reduced surface radiative flux by approximately 10%. In Southeastern China, maximum attenuation also occurred in spring, but had a smaller -40 W m-2 monthly mean. Western China is pristine in comparison, featuring no more than a -15 W m-2 monthly mean attenuation. These results imply a potentially large benefit for solar PV efficiency of improving air quality in eastern regions of China. We estimate that, if anthropogenic aerosols were entirely removed in China, solar PV generation would (1) increase 4.5-6.7% (varying among provinces) in Northeastern China where there is abundant solar resource,; (2) reduce the payback period by up to 1 year, increasing investment incentives particularly for distributed PV in Eastern China; and (3) increase total electricity generation in China in 2030 by up to 34 TWh/yr if the total capacity reaches 480 GW, equivalent to one-third of current annual electricity generation

  18. Photovoltaic power generation for air-conditioning system based on predictive control

    SciTech Connect

    Kim, S.; Choi, J.; Park, G.; Yoo Jiyoon

    1995-12-31

    In this paper an auxiliary power supply scheme using photovoltaic power generation for air-conditioning system and its novel control strategy are proposed. The proposed auxiliary power supply system employs a boost converter, a bidirectional power converter and photovoltaic arrays. The boost converter controlled by a predictive control strategy provides maximum power track (MPT) state on the photovoltaic (PV) arrays as well as power generation facility function on the ac utility grid. Furthermore the bidirectional power converter controls the power flow balance between the loads and two different power sources according to the condition of the load power and the supplied power from photovoltaic arrays. It is shown that the maximum power tracking of the PV arrays, the unit power factor of ac utility grid and the descent input dc voltage regulation of the air-conditioning system are achieved by the proposed predictive control strategy. The proposed switching strategy for the boost converter and the bidirectional power converter are based on the predictive control with ac line current and output voltage of the PV arrays. The bidirectional power converter is suitably modulation controlled to rectify the ac source during the power shortage under the poor power generation of PV arrays or over load conditions of air conditioner. During the opposite state, the bidirectional power converter is gated to function as a regeneration inverter. Controller design procedure for the proposed approach to achieve near sinusoidal input currents under the inverter mode and the rectifier mode is detailed. Simulation results on a laboratory prototype system are discussed. Experimental results from the laboratory prototype system will be presented in the near future.

  19. Effects of negative air ions on activity of neural substrates involved in autonomic regulation in rats

    NASA Astrophysics Data System (ADS)

    Suzuki, Satoko; Yanagita, Shinya; Amemiya, Seiichiro; Kato, Yumi; Kubota, Natsuko; Ryushi, Tomoo; Kita, Ichiro

    2008-07-01

    The neural mechanism by which negative air ions (NAI) mediate the regulation of autonomic nervous system activity is still unknown. We examined the effects of NAI on physiological responses, such as blood pressure (BP), heart rate (HR), and heart rate variability (HRV) as well as neuronal activity, in the paraventricular nucleus of the hypothalamus (PVN), locus coeruleus (LC), nucleus ambiguus (NA), and nucleus of the solitary tract (NTS) with c-Fos immunohistochemistry in anesthetized, spontaneously breathing rats. In addition, we performed cervical vagotomy to reveal the afferent pathway involved in mediating the effects of NAI on autonomic regulation. NAI significantly decreased BP and HR, and increased HF power of the HRV spectrum. Significant decreases in c-Fos positive nuclei in the PVN and LC, and enhancement of c-Fos expression in the NA and NTS were induced by NAI. After vagotomy, these physiological and neuronal responses to NAI were not observed. These findings suggest that NAI can modulate autonomic regulation through inhibition of neuronal activity in PVN and LC as well as activation of NA neurons, and that these effects of NAI might be mediated via the vagus nerves.

  20. Spectrum of the Runaway Electron Beam Generated During a Nanosecond Discharge in Air at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.

    2016-04-01

    The spectrum of supershort avalanche runaway electron beam generated in air at atmospheric pressure is experimentally investigated using a time-of-flight spectrometer and attenuation curves. It is shown that the maximum of the electron energy distribution for the main (second) group of electrons is less than the energy eUm, where Um is the maximal voltage across the gap, and the difference between these energies depends on the design of the cathode and the interelectrode gap in a gas diode. It is confirmed that there are three groups of electrons with different energies in the runaway electron beam spectrum.

  1. Trace elements and common ions in southeastern Idaho snow: Regional air pollutant tracers for source area emissions

    USGS Publications Warehouse

    Abbott, M.; Einerson, J.; Schuster, P.; Susong, D.; Taylor, H.E.; ,

    2004-01-01

    Snow sampling and analysis methods which produce accurate and ultra-low measurements of trace elements and common ion concentration in southeastern Idaho snow, were developed. Snow samples were collected over two winters to assess trace elements and common ion concentrations in air pollutant fallout across the southeastern Idaho. The area apportionment of apportionment of fallout concentrations measured at downwind location were investigated using pattern recognition and multivariate statistical technical techniques. Results show a high level of contribution from phosphates processing facilities located outside Pocatello in the southern portion of the Eastern Snake River Plain, and no obvious source area profiles other than at Pocatello.

  2. High-Frequency Electrostatic Wave Generation and Transverse Ion Acceleration by Low Alfvenic Wave Components of BBELF Turbulence

    NASA Technical Reports Server (NTRS)

    Singh, Nagendra; Khazanov, George; Mukhter, Ali

    2006-01-01

    Satellite observations in the auroral plasma have revealed that extremely low frequency (ELF) waves play a dominant role in the acceleration of electrons and ions in the auroral plasma. The electromagnetic components of the ELF (EMELF) waves are the electromagnetic ion cyclotron (EMIC) waves below the cyclotron frequency of the lightest ion species in a multi-ion plasma. Shear Alfv6n waves (SAWS) constitute the lowest frequency components of the ELF waves below the ion cyclotron frequency of the heaviest ion. The -2 mechanism for the transfer of energy from such EMELF waves to ions affecting transverse ion heating still remains a matter of debate. A very ubiquitous fe8ture of ELF waves now observed in several rocket and satellite experiments is that they occur in conjunction with high-frequency electrostatic waves. The frequency spectrum of the composite wave turbulence extends from the low frequency of the Alfvenic waves to the high frequency of proton plasma frequency and/or the lower hybrid frequency. The spectrum does not show any feature organized by the ion cyclotron frequencies and their harmonics. Such broadband waves consisting of both the EM and ES waves are now popularly referred as BBELF waves. We present results here from 2.5-D particle-in-cell simulations showing that the ES components are directly generated by cross- field plasma instabilities driven by the drifts of the ions and electrons in the EM component of the BBELF waves.

  3. The collision cross sections of iodide salt cluster ions in air via differential mobility analysis-mass spectrometry.

    PubMed

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R; Hogan, Christopher J

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M(+)]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5%) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  4. The Collision Cross Sections of Iodide Salt Cluster Ions in Air via Differential Mobility Analysis-Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R.; Hogan, Christopher J.

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M+]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5 %) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  5. Ultrabroad Terahertz Spectrum Generation from an Air-Based Filament Plasma

    NASA Astrophysics Data System (ADS)

    Andreeva, V. A.; Kosareva, O. G.; Panov, N. A.; Shipilo, D. E.; Solyankin, P. M.; Esaulkov, M. N.; González de Alaiza Martínez, P.; Shkurinov, A. P.; Makarov, V. A.; Bergé, L.; Chin, S. L.

    2016-02-01

    We have solved the long-standing problem of the mechanism of terahertz (THz) generation by a two-color filament in air and found that both neutrals and plasma contribute to the radiation. We reveal that the contribution from neutrals by four-wave mixing is much weaker and higher in frequency than the distinctive plasma lower-frequency contribution. The former is in the forward direction while the latter is in a cone and reveals an abrupt down-shift to the plasma frequency. Ring-shaped spatial distributions of the THz radiation are shown to be of universal nature and they occur in both collimated and focusing propagation geometries. Experimental measurements of the frequency-angular spectrum generated by 130-fs laser pulses agree with numerical simulations based on a unidirectional pulse propagation model.

  6. A series wound air core homopolar generator - SWAC for tactical armor applications

    NASA Astrophysics Data System (ADS)

    Ohst, David; Pavlik, Dennis

    1989-01-01

    The results of a study on generator design for a pulsed electromagnetic (EM) railgun launcher for a 10-shot low-repetition-rate mobile tactical system are presented. A novel design for a series-wound air-core (SWAC) homopolar generator is discussed. A number approaches to the problems associated with multiple-shot operation and high power density are presented. Specifically, designs for a spiral coil group, segmented current collection, active cooling and optimized rotor kinetic energy are addressed. The most significant features of the design are conventional water cooling, low rotational stored energy, and demonstrated materials and fabrication techniques. The resulting power supply consists of two counterrotating SWAC machines with a net energy density of 10 kJ/kg, 60-MJ total stored energy per shot, 2.50 mA peak current at 320 V, and significantly reduced eddy current losses.

  7. Effect of excess air on second-generation PFB combustion plant performance and economics

    SciTech Connect

    Robertson, A. ); Garland, R. ); Newby, R. ); Rehmat, A. ); Rubow, L. ); Bonk, D. )

    1990-01-01

    This paper presents a conceptual design of a 1.4-MPa (14-atm) coal-fired second-generation pressurized fluidized bed (PFB) combustion plant and identifies the performance and economic changes that result as the excess air and thus gas turbine-to-steam turbine power ratio, is changed. The performance of these plants, another second- generation PFB combustion plant, and a conventional pulverized-coal (PC)-fired plant with wet limestone flue gas desulfurization is compared. Depending upon the conditions selected, the PFB combustion plant can achieve a 45 percent efficiency (based on the higher heating value of the coal used as fuel) and a cost of electricity at least 20 percent lower than that of the conventional PC-fired plant.

  8. Conical third-harmonic generation of optical vortex through ultrashort laser filamentation in air.

    PubMed

    Lin, Yu-Chieh; Nabekawa, Yasuo; Midorikawa, Katsumi

    2016-06-27

    We experimentally generate third-harmonic (TH) vortex beams in air by the filamentation of femtosecond pulses produced in a lab-built Ti:sapphire chirped pulse amplifier. The generated TH beam profile is shown to evolve with increasing pump energy. At a sufficiently high pump energy, we observe a conical TH emission of the fundamental vortex and confirm that the conical radiation follows the conservation law for orbital angular momentum. We further investigate the far-field angularly resolved spectra of the TH wave to analyze the conical emission angle. We theoretically verify that the formation of the conical TH vortex results from the phase-matching between the fundamental and TH waves during the filamentation process.

  9. Diagnostic examination of Generation 2 lithium-ion cells and assessment ofperformance degradation mechanisms.

    SciTech Connect

    Abraham, D. P.; Dees, D. W.; Knuth, J.; Reynolds, E.; Gerald, R.; Hyung,Y.-E.; Belharouak, I.; Stoll, M.; Sammann, E.; MacLaren, S.; Haasch, R.; Twesten,R.; Sardela, M.; Battaglia, V.; Cairns, E.; Kerr, J.; Kerlau, M.; Kostecki, R.; Lei,J.; McCarthy, K.; McLarnon, F.; Reimer, J.; Richardson, T.; Ross, P.; Sloop,S.; Song, X.; Zhuang, V.; Balasubramanian, M.; McBreen, J.; Chung, K.-Y.; Yang, X.Q.; Yoon, W.-S.; Norin, L.

    2005-07-15

    The Advanced Technology Development (ATD) Program is a multilaboratory effort to assist industrial developers of high-power lithium-ion batteries overcome the barriers of cost, calendar life, abuse tolerance, and low-temperature performance so that this technology may be rendered practical for use in hybrid electric vehicles (HEVs). Included in the ATD Program is a comprehensive diagnostics effort conducted by researchers at Argonne National Laboratory (ANL), Brookhaven National Laboratory (BNL), and Lawrence Berkeley National Laboratory (LBNL). The goals of this effort are to identify and characterize processes that limit lithium-ion battery performance and calendar life, and ultimately to describe the specific mechanisms that cause performance degradation. This report is a compilation of the diagnostics effort conducted since spring 2001 to characterize Generation 2 ATD cells and cell components. The report is divided into a main body and appendices. Information on the diagnostic approach, details from individual diagnostic techniques, and details on the phenomenological model used to link the diagnostic data to the loss of 18650-cell electrochemical performance are included in the appendices. The main body of the report includes an overview of the 18650-cell test data, summarizes diagnostic data and modeling information contained in the appendices, and provides an assessment of the various mechanisms that have been postulated to explain performance degradation of the 18650 cells during accelerated aging. This report is intended to serve as a ready reference on ATD Generation 2 18650-cell performance and provide information on the tools for diagnostic examination and relevance of the acquired data. A comprehensive account of our experimental procedures and resulting data may be obtained by consulting the various references listed in the text. We hope that this report will serve as a roadmap for the diagnostic analyses of other lithium-ion technologies being

  10. Time and species dependent ambient air's effects on carbon clusters generated during femtosecond laser ablation of highly oriented pyrolytic graphite

    NASA Astrophysics Data System (ADS)

    Bao, Wenxia; Zhang, Nan; Feng, Peipei; Wu, Han; Zhu, Xiaonong

    2015-12-01

    Near infrared femtosecond laser is employed to ablate highly oriented pyrolytic graphite (HOPG) in ambient air and in vacuum respectively. The recorded transient emission spectra of the ablated plume with a time resolution of 2 ns indicate that the effects of air on the plume are dependent on both time and species. This finding provides important insights into the generation and decay mechanisms of different carbon radicals or clusters. At 1 or 2 ns after the laser pulse strikes the target, air weakens the Swan bands of C2 compared with the case in vacuum, an effect that may be caused by the quenching collisions between air molecules and C2 radicals. This result shows that C2 may be mainly generated by direct spallation from the target surface at the early stage of ablation. Emission spectra at large time delays present that the existence time of the Swan bands in air is longer than the lifetime of the upper electronic state of the Swan system, suggesting that the air-involved three-body recombination and collisional excitation that enhance the generation of emitting C2 overcome quenching collisions at large time delays. A spectral band at ~416 nm assigned to the transition from 1Σ u + to X 1Σ g + of C15 is more intense in air than in vacuum, indicating that C15 clusters are generated at least partially by the combination of smaller clusters in air. It is also found that air-assisted heat transfer makes the temperature of carbon clusters decrease more quickly in air than in vacuum, leading to a much shorter lifetime of the continuum in air.

  11. The Next Generation Air Particle Detectors for the United States Navy

    SciTech Connect

    Robert Hayes and Craig Marianno

    2007-06-24

    Design and testing of the United States Navy’s next generation air particle detector (NGAPD) is presently underway. The NGAPD is intended for use in nuclear applications for the United States Navy and is being designed to detect airborne Co-60 with a reduction in false alarms and improved ease of use. Features being developed include gamma compensation, low maintenance, commercial off-the-shelf electronics, and spectrum simulation for quality assurance and functional testing applications. By supplying a spectrum simulator, the radon stripping algorithm can be running when a simulated anthropogenic source spectrum (e.g., from Co-60 or transuranics) is superimposed on the radon progeny spectrum. This will allow alarm levels to be tested when the air flow is running and the radon stripping algorithm is providing the instrument response output. Modern units evaluate source spectra with the air flow off and the radon spectrum absent thereby not testing the true system performance which comes out of the radon stripping algorithm. Testing results of the preliminary prototype show promise along with computer simulations of source spectra. Primary testing results taken to date include gamma compensation, thermal insults, vibration and spectrum simulation.

  12. Plasma heating and generation of energetic ions with novel three-ion ICRF scenarios on Alcator C-Mod and JET tokamak facilities

    NASA Astrophysics Data System (ADS)

    Kazakov, Yevgen

    2016-10-01

    This talk will report the first experimental results of novel three-ion ICRF scenarios (two or more majority ion species and one minority) for plasma heating and generating energetic ions in fusion facilities. The key feature of these scenarios is strong absorption of RF power possible at lower concentrations of minority ions than in two-ion plasmas. Effective plasma heating by injecting a small amount of 3He ions into H-D plasma mixtures with nH /ne 70 % has been successfully demonstrated in Alcator C-Mod and JET tokamaks. In C-Mod, efficient plasma heating was observed for 3He concentrations from 0.4-2%. During the discharges, a strong increase in Alfvén eigenmode activity was found to coincide with the addition of 3He to the H-D plasmas. Even lower 3He concentrations ( 0.2 %) were utilized in recent JET experiments. The potential of the D-(3He) -H scenario for plasma heating and generating MeV-range ions in JET plasmas was confirmed by a set of independent measurements, including stabilization of sawteeth, characteristic γ-ray emission, fast-ion loss detector. Furthermore, toroidal Alfvén eigenmodes with a range of toroidal mode numbers n were detected, which is another indication for the presence of significant population of high-energy 3He ions in a plasma. The discussed mechanism of resonant wave-particle interaction opens up various unexplored opportunities for ICRF system, including new scenarios for plasma heating. Three-ion ICRF scenarios are also relevant for the experimental programme of ITER. The possibility of using intrinsic 9Be impurities as the minority (instead of 3He) was suggested for heating bulk ions in D-T plasmas of JET and ITER, as well as heating trace amounts of 3He and 4He ions in H majority plasmas of ITER. The latest results and simulation comparisons will be presented. On behalf of Alcator C-Mod Team (MIT-PSFC, US) and JET Contributors (Culham, UK). Work supported by the US DOE (C-Mod DE-FC02-99ER54512 and SciDAC DE-FC02-01ER54648

  13. Generating Monoenergetic Heavy-Ion Bunches with Laser-Induced Electrostatic Shocks

    SciTech Connect

    Ji Liangliang; Shen Baifei; Zhang Xiaomei; Wang Fengchao; Jin Zhangyin; Li Xuemei; Wen Meng; Cary, John R.

    2008-10-17

    A method for efficient laser acceleration of heavy ions by electrostatic shock is investigated using particle-in-cell (PIC) simulation and analytical modeling. When a small number of heavy ions are mixed with light ions, the heavy ions can be accelerated to the same velocity as the light ions so that they gain much higher energy because of their large mass. Accordingly, a sandwich target design with a thin compound ion layer between two light-ion layers and a micro-structured target design are proposed for obtaining monoenergetic heavy-ion beams.

  14. Visible to near-infrared supercontinuum generation in yttrium orthosilicate bulk crystal and ion implanted planar waveguide.

    PubMed

    Xiang, Bingxi; Ren, Xikui; Ruan, Shuangchen; Wang, Lei; Yan, Peiguang; Han, Huangpu; Wang, Meng; Yin, Jinde

    2016-08-16

    This paper reports on the supercontinuum generation in yttrium orthosilicate bulk crystal and 6-mm-long ion implanted planar waveguide. The waveguide is fabricated by 6 MeV oxygen ions implantation with fluence of 5 × 10(14) ions/cm(2) at room temperature. The yttrium orthosilicate bulk crystal and waveguide are pumped using a mode-locked Ti:Sapphire laser with a center wavelength of 800 nm. The generated broadest supercontinuum spans 720 nm (at -30 dB points) from 380 to 1100 nm in bulk crystal and 510 nm (at -30 dB points) from 490 to 1000 nm in ion implanted waveguide, respectively. Compared to the bulk crystal, the ion implanted waveguide requires almost three orders of magnitude lower pump power to achieve a similar level of broadening. The supercontinuum is generated in the normal dispersion regime and exhibits a relatively smooth spectral shape. Our research findings indicate that ion implantation is an efficient method to produce waveguide in yttrium orthosilicate crystal for low-threshold supercontinuum generation.

  15. Visible to near-infrared supercontinuum generation in yttrium orthosilicate bulk crystal and ion implanted planar waveguide

    NASA Astrophysics Data System (ADS)

    Xiang, Bingxi; Ren, Xikui; Ruan, Shuangchen; Wang, Lei; Yan, Peiguang; Han, Huangpu; Wang, Meng; Yin, Jinde

    2016-08-01

    This paper reports on the supercontinuum generation in yttrium orthosilicate bulk crystal and 6-mm-long ion implanted planar waveguide. The waveguide is fabricated by 6 MeV oxygen ions implantation with fluence of 5 × 1014 ions/cm2 at room temperature. The yttrium orthosilicate bulk crystal and waveguide are pumped using a mode-locked Ti:Sapphire laser with a center wavelength of 800 nm. The generated broadest supercontinuum spans 720 nm (at ‑30 dB points) from 380 to 1100 nm in bulk crystal and 510 nm (at ‑30 dB points) from 490 to 1000 nm in ion implanted waveguide, respectively. Compared to the bulk crystal, the ion implanted waveguide requires almost three orders of magnitude lower pump power to achieve a similar level of broadening. The supercontinuum is generated in the normal dispersion regime and exhibits a relatively smooth spectral shape. Our research findings indicate that ion implantation is an efficient method to produce waveguide in yttrium orthosilicate crystal for low-threshold supercontinuum generation.

  16. Visible to near-infrared supercontinuum generation in yttrium orthosilicate bulk crystal and ion implanted planar waveguide

    PubMed Central

    Xiang, Bingxi; Ren, Xikui; Ruan, Shuangchen; Wang, Lei; Yan, Peiguang; Han, Huangpu; Wang, Meng; Yin, Jinde

    2016-01-01

    This paper reports on the supercontinuum generation in yttrium orthosilicate bulk crystal and 6-mm-long ion implanted planar waveguide. The waveguide is fabricated by 6 MeV oxygen ions implantation with fluence of 5 × 1014 ions/cm2 at room temperature. The yttrium orthosilicate bulk crystal and waveguide are pumped using a mode-locked Ti:Sapphire laser with a center wavelength of 800 nm. The generated broadest supercontinuum spans 720 nm (at −30 dB points) from 380 to 1100 nm in bulk crystal and 510 nm (at −30 dB points) from 490 to 1000 nm in ion implanted waveguide, respectively. Compared to the bulk crystal, the ion implanted waveguide requires almost three orders of magnitude lower pump power to achieve a similar level of broadening. The supercontinuum is generated in the normal dispersion regime and exhibits a relatively smooth spectral shape. Our research findings indicate that ion implantation is an efficient method to produce waveguide in yttrium orthosilicate crystal for low-threshold supercontinuum generation. PMID:27527662

  17. Influence on the generation of disinfection byproducts in a tannic acid solution by aluminum ions.

    PubMed

    Shen, Hong; Chen, Xin; Chen, Hongbin

    2016-08-17

    Aluminum (Al) commonly exists in natural waters, and its salts are often used as coagulants in drinking water treatment. Therefore, associated with the security of drinking water, functions of Al ions (Al(3+)) on generation of disinfection byproducts (DBPs) should not be ignored. This study focuses on DBPs and the carcinogenic factor of chlorinated water samples after the addition of Al(3+) with different Al(3+)/initial tannic acid molar ratios. The results imply that Al(3+) acts as a promoter of haloacetic acids (HAAs) and an inhibitor of trihalomethanes (THMs) when tannic acid is selected as model compound of natural organic matter during chlorination. Depending on the results of size exclusion chromatography and ultraviolet spectrophotometer, an equilibrium system can be assumed between hydrolysis and flocculation in tannic acid solution with Al(3+). Furthermore, influences on the equilibrium system for Al(3+) addition may result in various effects on generation and distribution ratios of THMs and HAAs during chlorination. Finally, according to the analyses of a fluorescence spectrophotometer, it is demonstrated that the presence of Al(3+) helps to increase precursors of DBPs (humic acid-like organics) and then improve the generation of DBPs.

  18. Generation of continuous-wave 194 nm laser for mercury ion optical frequency standard

    NASA Astrophysics Data System (ADS)

    Zou, Hongxin; Wu, Yue; Chen, Guozhu; Shen, Yong; Liu, Qu; Precision measurement; atomic clock Team

    2015-05-01

    194 nm continuous-wave (CW) laser is an essential part in mercury ion optical frequency standard. The continuous-wave tunable radiation sources in the deep ultraviolet (DUV) region of the spectrum is also serviceable in high-resolution spectroscopy with many atomic and molecular lines. We introduce a scheme to generate continuous-wave 194 nm radiation with SFM in a Beta Barium Borate (BBO) crystal here. The two source beams are at 718 nm and 266 nm, respectively. Due to the property of BBO, critical phase matching (CPM) is implemented. One bow-tie cavity is used to resonantly enhance the 718 nm beam while the 266 nm makes a single pass, which makes the configuration easy to implement. Considering the walk-off effect in CPM, the cavity mode is designed to be elliptical so that the conversion efficiency can be promoted. Since the 266 nm radiation is generated by a 532 nm laser through SHG in a BBO crystal with a large walk-off angle, the output mode is quite non-Gaussian. To improve mode matching, we shaped the 266 nm beam into Gaussian modes with a cylindrical lens and iris diaphragm. As a result, 2.05 mW 194 nm radiation can be generated. As we know, this is the highest power for 194 nm CW laser using SFM in BBO with just single resonance. The work is supported by the National Natural Science Foundation of China (Grant No. 91436103 and No. 11204374).

  19. Analyses of an air conditioning system with entropy generation minimization and entransy theory

    NASA Astrophysics Data System (ADS)

    Yan-Qiu, Wu; Li, Cai; Hong-Juan, Wu

    2016-06-01

    In this paper, based on the generalized heat transfer law, an air conditioning system is analyzed with the entropy generation minimization and the entransy theory. Taking the coefficient of performance (denoted as COP) and heat flow rate Q out which is released into the room as the optimization objectives, we discuss the applicabilities of the entropy generation minimization and entransy theory to the optimizations. Five numerical cases are presented. Combining the numerical results and theoretical analyses, we can conclude that the optimization applicabilities of the two theories are conditional. If Q out is the optimization objective, larger entransy increase rate always leads to larger Q out, while smaller entropy generation rate does not. If we take COP as the optimization objective, neither the entropy generation minimization nor the concept of entransy increase is always applicable. Furthermore, we find that the concept of entransy dissipation is not applicable for the discussed cases. Project supported by the Youth Programs of Chongqing Three Gorges University, China (Grant No. 13QN18).

  20. Autonomous generation of a thermoacoustic solitary wave in an air-filled tube

    NASA Astrophysics Data System (ADS)

    Shimizu, Dai; Sugimoto, Nobumasa

    2016-10-01

    Experiments are performed to demonstrate the autonomous generation of an acoustic solitary wave in an air-filled, looped tube with an array of Helmholtz resonators. The solitary wave is generated spontaneously due to thermoacoustic instability by a pair of stacks installed in the tube and subject to a temperature gradient axially. No external drivers are used to create initial disturbances. Once the solitary wave is generated, it keeps on propagating to circulate along the loop endlessly. The stacks, which are made of ceramics and of many pores of square cross section, are placed in the tube diametrically on exactly the opposite side of the loop, and they are sandwiched by hot and cold (ambient) heat exchangers. When the temperature gradient along both stacks is appropriate, pulses of smooth profiles are generated and propagated in both directions of the tube. From good agreements of not only the pressure profile measured but also the propagation speed with the theory, the pulse is identified as the acoustic solitary wave, and it can be called thermoacoustic solitary wave or thermoacoustic soliton corresponding to the soliton solution of the K-dV equation in one limit.

  1. Cancer Therapy by Catechins Involves Redox Cycling of Copper Ions and Generation of Reactive Oxygen species.

    PubMed

    Farhan, Mohd; Khan, Husain Yar; Oves, Mohammad; Al-Harrasi, Ahmed; Rehmani, Nida; Arif, Hussain; Hadi, Sheikh Mumtaz; Ahmad, Aamir

    2016-02-04

    Catechins, the dietary phytochemicals present in green tea and other beverages, are considered to be potent inducers of apoptosis and cytotoxicity to cancer cells. While it is believed that the antioxidant properties of catechins and related dietary agents may contribute to lowering the risk of cancer induction by impeding oxidative injury to DNA, these properties cannot account for apoptosis induction and chemotherapeutic observations. Catechin (C), epicatechin (EC), epigallocatechin (EGC) and epigallocatechin-3-gallate (EGCG) are the four major constituents of green tea. In this article, using human peripheral lymphocytes and comet assay, we show that C, EC, EGC and EGCG cause cellular DNA breakage and can alternatively switch to a prooxidant action in the presence of transition metals such as copper. The cellular DNA breakage was found to be significantly enhanced in the presence of copper ions. Catechins were found to be effective in providing protection against oxidative stress induced by tertbutylhydroperoxide, as measured by oxidative DNA breakage in lymphocytes. The prooxidant action of catechins involved production of hydroxyl radicals through redox recycling of copper ions. We also determined that catechins, particularly EGCG, inhibit proliferation of breast cancer cell line MDA-MB-231 leading to a prooxidant cell death. Since it is well established that tissue, cellular and serum copper levels are considerably elevated in various malignancies, cancer cells would be more subject to redox cycling between copper ions and catechins to generate reactive oxygen species (ROS) responsible for DNA breakage. Such a copper dependent prooxidant cytotoxic mechanism better explains the anticancer activity and preferential cytotoxicity of dietary phytochemicals against cancer cells.

  2. Cancer Therapy by Catechins Involves Redox Cycling of Copper Ions and Generation of Reactive Oxygen Species

    PubMed Central

    Farhan, Mohd; Khan, Husain Yar; Oves, Mohammad; Al-Harrasi, Ahmed; Rehmani, Nida; Arif, Hussain; Hadi, Sheikh Mumtaz; Ahmad, Aamir

    2016-01-01

    Catechins, the dietary phytochemicals present in green tea and other beverages, are considered to be potent inducers of apoptosis and cytotoxicity to cancer cells. While it is believed that the antioxidant properties of catechins and related dietary agents may contribute to lowering the risk of cancer induction by impeding oxidative injury to DNA, these properties cannot account for apoptosis induction and chemotherapeutic observations. Catechin (C), epicatechin (EC), epigallocatechin (EGC) and epigallocatechin-3-gallate (EGCG) are the four major constituents of green tea. In this article, using human peripheral lymphocytes and comet assay, we show that C, EC, EGC and EGCG cause cellular DNA breakage and can alternatively switch to a prooxidant action in the presence of transition metals such as copper. The cellular DNA breakage was found to be significantly enhanced in the presence of copper ions. Catechins were found to be effective in providing protection against oxidative stress induced by tertbutylhydroperoxide, as measured by oxidative DNA breakage in lymphocytes. The prooxidant action of catechins involved production of hydroxyl radicals through redox recycling of copper ions. We also determined that catechins, particularly EGCG, inhibit proliferation of breast cancer cell line MDA-MB-231 leading to a prooxidant cell death. Since it is well established that tissue, cellular and serum copper levels are considerably elevated in various malignancies, cancer cells would be more subject to redox cycling between copper ions and catechins to generate reactive oxygen species (ROS) responsible for DNA breakage. Such a copper dependent prooxidant cytotoxic mechanism better explains the anticancer activity and preferential cytotoxicity of dietary phytochemicals against cancer cells. PMID:26861392

  3. Validation of a CFD Model by Using 3D Sonic Anemometers to Analyse the Air Velocity Generated by an Air-Assisted Sprayer Equipped with Two Axial Fans

    PubMed Central

    García-Ramos, F. Javier; Malón, Hugo; Aguirre, A. Javier; Boné, Antonio; Puyuelo, Javier; Vidal, Mariano

    2015-01-01

    A computational fluid dynamics (CFD) model of the air flow generated by an air-assisted sprayer equipped with two axial fans was developed and validated by practical experiments in the laboratory. The CFD model was developed by considering the total air flow supplied by the sprayer fan to be the main parameter, rather than the outlet air velocity. The model was developed for three air flows corresponding to three fan blade settings and assuming that the sprayer is stationary. Actual measurements of the air velocity near the sprayer were taken using 3D sonic anemometers. The workspace sprayer was divided into three sections, and the air velocity was measured in each section on both sides of the machine at a horizontal distance of 1.5, 2.5, and 3.5 m from the machine, and at heights of 1, 2, 3, and 4 m above the ground The coefficient of determination (R2) between the simulated and measured values was 0.859, which demonstrates a good correlation between the simulated and measured data. Considering the overall data, the air velocity values produced by the CFD model were not significantly different from the measured values. PMID:25621611

  4. Generation of plasma rotation in a tokamak by ion-cyclotron absorption of fast Alfven waves

    SciTech Connect

    F.W. Perkins; R.B. White; P. Bonoli

    2000-06-13

    Control of rotation in tokamak plasmas provides a method for suppressing fine-scale turbulent transport by velocity shear and for stabilizing large-scale magnetohydrodynamic instabilities via a close-fitting conducting shell. The experimental discovery of rotation in a plasma heated by the fast-wave minority ion cyclotron process is important both as a potential control method for a fusion reactor and as a fundamental issue, because rotation arises even though this heating process introduces negligible angular momentum. This paper proposes and evaluates a mechanism which resolves this apparent conflict. First, it is assumed that angular momentum transport in a tokamak is governed by a diffusion equation with a no-slip boundary condition at the plasma surface and with a torque-density source that is a function of radius. When the torque density source consists of two separated regions of positive and negative torque density, a non-zero central rotation velocity results, even when the total angular momentum input vanishes. Secondly, the authors show that localized ion-cyclotron heating can generate regions of positive and negative torque density and consequently central plasma rotation.

  5. The Next Generation of Heavy Ion Sources (447th Brookhaven Lecture)

    SciTech Connect

    Okamura, Masahiro

    2009-03-04

    Imagine if, by staying in your lane when driving on the expressway, you could help fight cancer or provide a new, clean energy source. You would clench the steering wheel with both hands and stay in your lane, right? Unlike driving on the expressway where you intentionally avoid hitting other cars, scientists sometimes work to steer particle beams into head-on collisions with other oncoming particle beams. However, the particles must be kept "in their lanes" for cleaner, more frequent collisions. Some scientists propose starting the whole process by using lasers to heat a fixed target as a way to get particles with higher charge, which are more steerable. These scientists believe the new methods could be used to develop particle beams for killing cancer cells or creating usable energy from fusion. Join Masahiro Okamura of Brookhaven's Collider-Accelerator Department for the 447th Brookhaven Lecture, titled "The Next Generation of Heavy Ion Sources." Okamura will explain how lasers can be used to create plasma, neutral mixtures of positive ions and negative electrons, from different materials, and how using this plasma leads to beams with higher charge states and currents. He will also discuss how this efficient, simpler method of producing particle beams might be used for cancer therapy, to develop new energy sources, or in synchrotrons.

  6. Fourth-generation plasma immersion ion implantation and deposition facility for hybrid surface modification layer fabrication

    SciTech Connect

    Wang Langping; Huang Lei; Xie Zhiwen; Wang Xiaofeng; Tang Baoyin

    2008-02-15

    The fourth-generation plasma immersion ion implantation and deposition (PIIID) facility for hybrid and batch treatment was built in our laboratory recently. Comparing with our previous PIIID facilities, several novel designs are utilized. Two multicathode pulsed cathodic arc plasma sources are fixed on the chamber wall symmetrically, which can increase the steady working time from 6 h (the single cathode source in our previous facilities) to about 18 h. Meanwhile, the inner diameter of the pulsed cathodic arc plasma source is increased from the previous 80 to 209 mm, thus, large area metal plasma can be obtained by the source. Instead of the simple sample holder in our previous facility, a complex revolution-rotation sample holder composed of 24 shafts, which can rotate around its axis and adjust its position through revolving around the center axis of the vacuum chamber, is fixed in the center of the vacuum chamber. In addition, one magnetron sputtering source is set on the chamber wall instead of the top cover in the previous facility. Because of the above characteristic, the PIIID hybrid process involving ion implantation, vacuum arc, and magnetron sputtering deposition can be acquired without breaking vacuum. In addition, the PIIID batch treatment of cylinderlike components can be finished by installing these components on the rotating shafts on the sample holder.

  7. Ion channels generating complex spikes in cartwheel cells of the dorsal cochlear nucleus.

    PubMed

    Kim, Yuil; Trussell, Laurence O

    2007-02-01

    Cartwheel cells are glycinergic interneurons that modify somatosensory input to the dorsal cochlear nucleus. They are characterized by firing of mixtures of both simple and complex action potentials. To understand what ion channels determine the generation of these two types of spike waveforms, we recorded from cartwheel cells using the gramicidin perforated-patch technique in brain slices of mouse dorsal cochlear nucleus and applied channel-selective blockers. Complex spikes were distinguished by whether they arose directly from a negative membrane potential or later during a long depolarization. Ca(2+) channels and Ca(2+)-dependent K(+) channels were major determinants of complex spikes. Onset complex spikes required T-type and possibly R-type Ca(2+) channels and were shaped by BK and SK K(+) channels. Complex spikes arising later in a depolarization were dependent on P/Q- and L-type Ca(2+) channels as well as BK and SK channels. BK channels also contributed to fast repolarization of simple spikes. Simple spikes featured an afterdepolarization that is probably the trigger for complex spiking and is shaped by T/R-type Ca(2+) and SK channels. Fast spikes were dependent on Na(+) channels; a large persistent Na(+) current may provide a depolarizing drive for spontaneous activity in cartwheel cells. Thus the diverse electrical behavior of cartwheel cells is determined by the interaction of a wide variety of ion channels with a prominent role played by Ca(2+).

  8. Seasonal variability of tritium and ion concentrations in rain at Kumamoto, Japan and back-trajectory analysis of air mass

    SciTech Connect

    Momoshima, N.; Sugihara, S.; Toyoshima, T.; Nagao, Y.; Takahashi, M.; Nakamura, Y.

    2008-07-15

    Tritium and major ion concentrations in rain were analyzed in Kumamoto (Japan)) between 2001 and 2006 to examine present tritium concentration and seasonal variation. The average tritium concentration was 0.36 {+-} 0.19 Bq/L (n=104) and higher tritium concentrations were observed in spring than the other seasons. Among the ions, non-sea-salt (nss) SO{sub 4}{sup 2}'- showed higher concentration in winter while other ions did not show marked increase in winter. Based on the back-trajectory analyses of air masses, the increase in tritium concentrations in spring arises from downward movement of naturally produced tritium from stratosphere to troposphere, while the increase of the nss-SO{sub 4}{sup 2-} concentrations in winter is due to long range transport of pollutants from China to Japan. (authors)

  9. Rf sheaths and impurity generation by ICRF (ion cyclotron range of frequencies) antennas

    SciTech Connect

    Perkins, F.W.

    1988-11-01

    In general, Faraday screen elements in an ICRF antenna are not aligned precisely along the combined toroidal and poloidal magnetic fields. When plasma of density n > 2epsilon/sub 0/V/eg/sup 2/ /approximately/ 10/sup 9/cm/sup -3/ is present in the gap between elements, electron response to the parallel electric field shorts out the electric field over most of the gap, leaving a narrow sheath of positive space charge and intense electric field. Here V denotes the voltage across the gap and g the gap spacing. This intense electric field accelerates ions up to an appreciable fraction of the gap voltage (/approximately/ 1 kV), sufficient to cause physical sputtering of the screen material. Impurities so generated constitute the principal limitation on power density (kW/cm/sup 2/) for ICRF antennas. ICRF antenna and Faraday screen design principles which minimize sputtering are discussed. 24 refs., 9 figs., 1 tab.

  10. Effects of laser polarizations on shock generation and shock ion acceleration in overdense plasmas

    NASA Astrophysics Data System (ADS)

    Kim, Young-Kuk; Kang, Teyoun; Jung, Moon Youn; Hur, Min Sup

    2016-09-01

    The effects of laser-pulse polarization on the generation of an electrostatic shock in an overdense plasma were investigated using particle-in-cell simulations. We found, from one-dimensional simulations, that total and average energies of reflected ions from a circular polarization- (CP) driven shock front are a few times higher than those from a linear polarization- (LP) driven one for a given pulse energy. Moreover, it was discovered that the pulse transmittance is the single dominant factor for determining the CP-shock formation, while the LP shock is affected by the plasma scale length as well as the transmittance. In two-dimensional simulations, it is observed that the transverse instability, such as Weibel-like instability, can be suppressed more efficiently by CP pulses.

  11. Contribution of ion beam analysis methods to the development of second generation high temperature superconducting wires

    NASA Astrophysics Data System (ADS)

    Usov, I. O.; Arendt, P. N.; Foltyn, S. R.; Stan, L.; DePaula, R. F.; Holesinger, T. G.

    2010-06-01

    One of the crucial steps in the second generation high temperature superconducting wire program was development of the buffer-layer architecture. The architecture designed at the Superconductivity Technology Center at Los Alamos National Laboratory consists of several oxide layers wherein each layer plays a specific role, namely: nucleation layer, diffusion barrier, biaxially textured template, and intermediate layer providing a suitable lattice match to the superconducting Y 1Ba 2Cu 3O 7 (YBCO) compound. This report demonstrates how a wide range of ion beam analysis techniques (SIMS, RBS, channeling, PIXE, PIGE, NRA and ERD) was employed for analysis of each buffer layer and the YBCO film. These results assisted in understanding of a variety of physical processes occurring during the buffer layer fabrication and helped to optimize the buffer-layer architecture as a whole.

  12. High-efficiency particulate air filter test stand and aerosol generator for particle loading studies.

    PubMed

    Arunkumar, R; Hogancamp, Kristina U; Parsons, Michael S; Rogers, Donna M; Norton, Olin P; Nagel, Brian A; Alderman, Steven L; Waggoner, Charles A

    2007-08-01

    This manuscript describes the design, characterization, and operational range of a test stand and high-output aerosol generator developed to evaluate the performance of 30 x 30 x 29 cm(3) nuclear grade high-efficiency particulate air (HEPA) filters under variable, highly controlled conditions. The test stand system is operable at volumetric flow rates ranging from 1.5 to 12 standard m(3)/min. Relative humidity levels are controllable from 5%-90% and the temperature of the aerosol stream is variable from ambient to 150 degrees C. Test aerosols are produced through spray drying source material solutions that are introduced into a heated stainless steel evaporation chamber through an air-atomizing nozzle. Regulation of the particle size distribution of the aerosol challenge is achieved by varying source solution concentrations and through the use of a postgeneration cyclone. The aerosol generation system is unique in that it facilitates the testing of standard HEPA filters at and beyond rated media velocities by consistently providing, into a nominal flow of 7 standard m(3)/min, high mass concentrations (approximately 25 mg/m(3)) of dry aerosol streams having count mean diameters centered near the most penetrating particle size for HEPA filters (120-160 nm). Aerosol streams that have been generated and characterized include those derived from various concentrations of KCl, NaCl, and sucrose solutions. Additionally, a water insoluble aerosol stream in which the solid component is predominantly iron (III) has been produced. Multiple ports are available on the test stand for making simultaneous aerosol measurements upstream and downstream of the test filter. Types of filter performance related studies that can be performed using this test stand system include filter lifetime studies, filtering efficiency testing, media velocity testing, evaluations under high mass loading and high humidity conditions, and determination of the downstream particle size distributions.

  13. Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

    PubMed

    Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

    2014-01-01

    A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future.

  14. On the possibility of spontaneous generation of turbulent Alfvén waves in solar plasma by heavy ions

    SciTech Connect

    Wu, C. S.; Zhao, G. Q.; Chen, L.; Wu, D. J.

    2013-08-15

    In this paper, we discuss spontaneous generation of Alfvén waves. The discussion is motivated by the study of the solar transition region. We show that the heavy ions in this region can play critical roles. A quasilinear theory is derived. On the basis of this theory, we can discuss the saturation level of the wave spectral energy associated with each species of ions. Several essential issues relevant to the transition region are also discussed.

  15. Simultaneous Exposure to Multiple Air Pollutants Influences Alveolar Epithelial Cell Ion Transport

    EPA Science Inventory

    Purpose. Air pollution sources generally release multiple pollutants simultaneously and yet, research has historically focused on the source-to-health linkages of individual air pollutants. We recently showed that exposure of alveolar epithelial cells to a combination of particul...

  16. Extrusion of transmitter, water and ions generates forces to close fusion pore.

    PubMed

    Tajparast, M; Glavinović, M I

    2009-05-01

    During exocytosis the fusion pore opens rapidly, then dilates gradually, and may subsequently close completely, but what controls its dynamics is not well understood. In this study we focus our attention on forces acting on the pore wall, and which are generated solely by the passage of transmitter, ions and water through the open fusion pore. The transport through the charged cylindrical nano-size pore is simulated using a coupled system of Poisson-Nernst-Planck and Navier-Stokes equations and the forces that act radially on the wall of the fusion pore are then estimated. Four forces are considered: a) inertial force, b) pressure, c) viscotic force, and d) electrostatic force. The inertial and viscotic forces are small, but the electrostatic force and the pressure are typically significant. High vesicular pressure tends to open the fusion pore, but the pressure induced by the transport of charged particles (glutamate, ions), which is predominant when the pore wall charge density is high tends to close the pore. The electrostatic force, which also depends on the charge density on the pore wall, is weakly repulsive before the pore dilates, but becomes attractive and pronounced as the pore dilates. Given that the vesicular concentration of free transmitter can change rapidly due to the release, or owing to the dissociation from the gel matrix, we evaluated how much and how rapidly a change of the vesicular K(+)-glutamate(-) concentration affects the concentration of glutamate(-) and ions in the pore and how such changes alter the radial force on the wall of the fusion pore. A step-like rise of the vesicular K(+)-glutamate(-) concentration leads to a chain of events. Pore concentration (and efflux) of both K(+) and glutamate(-) rise reaching their new steady-state values in less than 100 ns. Interestingly within a similar time interval the pore concentration of Na(+) also rises, whereas that of Cl(-) diminishes, although their extra-cellular concentration does not

  17. Helicon plasma generator-assisted surface conversion ion source for the production of H(-) ion beams at the Los Alamos Neutron Science Center.

    PubMed

    Tarvainen, O; Rouleau, G; Keller, R; Geros, E; Stelzer, J; Ferris, J

    2008-02-01

    The converter-type negative ion source currently employed at the Los Alamos Neutron Science Center (LANSCE) is based on cesium enhanced surface production of H(-) ion beams in a filament-driven discharge. In this kind of an ion source the extracted H(-) beam current is limited by the achievable plasma density which depends primarily on the electron emission current from the filaments. The emission current can be increased by increasing the filament temperature but, unfortunately, this leads not only to shorter filament lifetime but also to an increase in metal evaporation from the filament, which deposits on the H(-) converter surface and degrades its performance. Therefore, we have started an ion source development project focused on replacing these thermionic cathodes (filaments) of the converter source by a helicon plasma generator capable of producing high-density hydrogen plasmas with low electron energy. In our studies which have so far shown that the plasma density of the surface conversion source can be increased significantly by exciting a helicon wave in the plasma, and we expect to improve the performance of the surface converter H(-) ion source in terms of beam brightness and time between services. The design of this new source and preliminary results are presented, along with a discussion of physical processes relevant for H(-) ion beam production with this novel design. Ultimately, we perceive this approach as an interim step towards our long-term goal, combining a helicon plasma generator with an SNS-type main discharge chamber, which will allow us to individually optimize the plasma properties of the plasma cathode (helicon) and H(-) production (main discharge) in order to further improve the brightness of extracted H(-) ion beams.

  18. Air quality impacts of distributed power generation in the South Coast Air Basin of California 1: Scenario development and modeling analysis

    NASA Astrophysics Data System (ADS)

    Rodriguez, M. A.; Carreras-Sospedra, M.; Medrano, M.; Brouwer, J.; Samuelsen, G. S.; Dabdub, D.

    Distributed generation (DG) is generally defined as the operation of many small stationary power generators throughout an urban air basin. Although DG has the potential to supply a significant portion of the increased power demands in California and the rest of the United States, it may lead to increased levels of in-basin pollutants and adversely impact urban air quality. This study focuses on two main objectives: (1) the systematic characterization of DG installation in urban air basins, and (2) the simulation of potential air quality impacts using a state-of-the-art three-dimensional computational model. A general and systematic approach is devised to construct five realistic and 21 spanning scenarios of DG implementation in the South Coast Air Basin (SoCAB) of California. Realistic scenarios reflect an anticipated level of DG deployment in the SoCAB by the year 2010. Spanning scenarios are developed to determine the potential impacts of unexpected outcomes. Realistic implementations of DG in the SoCAB result in small differences in ozone and particulate matter concentrations in the basin compared to the baseline simulations. The baseline accounts for population increase, but does not consider any future emissions control measures. Model results for spanning implementations with extra high DG market penetration show that domain-wide ozone peak concentrations increase significantly. Also, air quality impacts of spanning implementations when DG operate during a 6-h period are larger than when the same amount of emissions are introduced during a 24-h period.

  19. Time-dependent modeling of field-aligned current-generated ion transients in the polar wind

    NASA Technical Reports Server (NTRS)

    Gombosi, T. I.; Nagy, A. F.

    1989-01-01

    The time evolution of field-aligned current-generated transient features in the high-latitude ionosphere is investigated. Ionospheric return currents generate significant downward heavy ion flows in the topside ionosphere with peak values well exceeding 10 to the 8th sq cm/s. When the return current ceases, the polar ionosphere rapidly returns to its previous equilibrium state. During the recovery phase of the return current event, an upward propagating heavy ion transient is formed, which is mainly characterized by a relatively short O(+) upwelling event. On the other hand, the H(+) escape flux remains relatively constant (within 10-20 percent) during field-aligned current events. It is also found that upward currents generate a transient heavy ion outflow, which exceeds the ambient H(+) escape flux by a factor of 3 to 5, depending on the duration and strength of the field-aligned current event.

  20. The study of gas species on THz generation from laser-induced air plasma

    NASA Astrophysics Data System (ADS)

    Zhao, Ji; Zhang, LiangLiang; Wu, YiJian; Wu, Tong; Yuan, Hui; Zhang, CunLin; Zhao, YueJin

    2015-08-01

    Intense Terahertz waves generated from air-induced plasma and serving as broadband THz source provide a promising broadband source for innovative technology. Terahertz generation in selected gases has attracted more and more researchers' interests in recent years. In this research, the THz emission from different atoms is described, such as nitrogen, argon and helium in Michelson. The THz radiation is detected by a Golay Cell equipped with a 6-mm-diameter diamond-inputting window. It can be seen in the first time that when the pump power lies at a stable level, the THz generation created by the femtosecond laser focusing on the nitrogen is higher than which focusing on the helium, and lower than that produced in the argon gas environment. We believe that the THz intensity is Ar > N > Ne because of its atomic mass, which is Ar > N > Ne as well. It is clear that the Gas molecular decides the release of free electrons ionized from ultra short femtosecond laser through the electronic dynamic analysis. The higher the gas mass is, the stronger the terahertz emission will be. We further explore the THz emission at the different laser power levels, and the experimental results can be commendably quadratic fitted. It can be inferred that THz emission under different gas medium environment still complies with the law of four-wave mixing (FWM) process and has nothing to do with the gas environment: the radiation energy is proportional to the quadratic of incident laser power.

  1. Directions in US Air Force space power energy generation and distribution technology

    NASA Astrophysics Data System (ADS)

    Reinhardt, Kitt; Keener, Dave; Schuller, Mike

    1997-01-01

    Recent trends in the development of high efficiency, light-weight, reliable and cost-effective space power technologies needed to support the development of near-term, next-generation government and commercial satellites will be discussed. Significant advancements in light-weight and reduced volume electrical power system (EPS) components are required to enable the design of future smallsats with power requirements of less than 1000 W to monster-sats having projected power demands ranging from 10-50 kW for civilian and military communications and space based radar needs. For these missions increased emphasis is placed on reducing total satellite mass to enable use of smaller, less costly, and easier to deploy launch vehicles. In support of these requirements a complement of power generation, power management and distribution, and energy storage technologies are under development at the Air Force Phillips Laboratory Space and Missiles Technology Directorate. Specific technologies presented in this paper include high efficiency multijunction solar cells, low-cost thin-film solar cells, ultra light-weight flexible solar arrays, solar electric thermal converters, and high-voltage (70-130 V) and high-efficiency power management and distribution (PMAD) electronics. The projected impact of EPS subsystem performance on existing, near-term, and next-generation 10-50 kW military satellites will be discussed, along with technical issues and status of EPS component development.

  2. Analysis of the air flow generated by an air-assisted sprayer equipped with two axial fans using a 3D sonic anemometer.

    PubMed

    García-Ramos, F Javier; Vidal, Mariano; Boné, Antonio; Malón, Hugo; Aguirre, Javier

    2012-01-01

    The flow of air generated by a new design of air assisted sprayer equipped with two axial fans of reversed rotation was analyzed. For this goal, a 3D sonic anemometer has been used (accuracy: 1.5%; measurement range: 0 to 45 m/s). The study was divided into a static test and a dynamic test. During the static test, the air velocity in the working vicinity of the sprayer was measured considering the following machine configurations: (1) one activated fan regulated at three air flows (machine working as a traditional sprayer); (2) two activated fans regulated at three air flows for each fan. In the static test 72 measurement points were considered. The location of the measurement points was as follow: left and right sides of the sprayer; three sections of measurement (A, B and C); three measurement distances from the shaft of the machine (1.5 m, 2.5 m and 3.5 m); and four measurement heights (1 m, 2 m, 3 m and 4 m). The static test results have shown significant differences in the module and the vertical angle of the air velocity vector in function of the regulations of the sprayer. In the dynamic test, the air velocity was measured at 2.5 m from the axis of the sprayer considering four measurement heights (1 m, 2 m, 3 m and 4 m). In this test, the sprayer regulations were: one or two activated fans; one air flow for each fan; forward speed of 2.8 km/h. The use of one fan (back) or two fans (back and front) produced significant differences on the duration of the presence of wind in the measurement point and on the direction of the air velocity vector. The module of the air velocity vector was not affected by the number of activated fans.

  3. Air ion mobility spectra and concentrations upwind and downwind of overhead AC high voltage power lines

    NASA Astrophysics Data System (ADS)

    Wright, Matthew D.; Buckley, Alison J.; Matthews, James C.; Shallcross, Dudley E.; Henshaw, Denis L.

    2014-10-01

    Corona ions produced by high-voltage power lines (HVPLs) can alter the nearby electrical environment, potentially increasing aerosol charge levels downwind. However, there is a lack of knowledge concerning the concentration and mobility of ions from AC HVPLs and their dispersion away from the line. We present ion concentration and mobility measurements made near AC HVPLs in South-West England. Examples of typical mobility spectra are shown highlighting features commonly observed. Corona was observed during 33 of 46 measurements, at 9 of 11 sites, with positive or ‘bipolar' (both polarities) ion production commonly seen. Ion production usually increases atmospheric concentrations by only a modest amount, but extreme cases can enhance concentration by an order of magnitude or more. A polarity imbalance is required to increase aerosol charge via ion attachment; this was observed on 15 of 24 days when positive corona was observed, but was not seen for negative ions. Ion mobility was higher downwind compared with upwind for both ion polarities, but the increase was not statistically significant. Future work should focus on identifying and characterising ‘heavy-producing' HVPLs, and obtaining results in conditions which may favour negative ion production e.g. high humidity, inclement weather or during nighttime.

  4. High yield neutron generator based on a high-current gasdynamic electron cyclotron resonance ion source

    SciTech Connect

    Skalyga, V.; Sidorov, A.; Izotov, I.; Golubev, S.; Razin, S.; Strelkov, A.; Tarvainen, O.; Koivisto, H.; Kalvas, T.

    2015-09-07

    In present paper, an approach for high yield compact D-D neutron generator based on a high current gasdynamic electron cyclotron resonance ion source is suggested. Results on dense pulsed deuteron beam production with current up to 500 mA and current density up to 750 mA/cm{sup 2} are demonstrated. Neutron yield from D{sub 2}O and TiD{sub 2} targets was measured in case of its bombardment by pulsed 300 mA D{sup +} beam with 45 keV energy. Neutron yield density at target surface of 10{sup 9} s{sup −1} cm{sup −2} was detected with a system of two {sup 3}He proportional counters. Estimations based on obtained experimental results show that neutron yield from a high quality TiD{sub 2} target bombarded by D{sup +} beam demonstrated in present work accelerated to 100 keV could reach 6 × 10{sup 10} s{sup −1} cm{sup −2}. It is discussed that compact neutron generator with such characteristics could be perspective for a number of applications like boron neutron capture therapy, security systems based on neutron scanning, and neutronography.

  5. Impact of cercal air currents on singing motor pattern generation in the cricket (Gryllus bimaculatus DeGeer).

    PubMed

    Jacob, Pedro F; Hedwig, Berthold

    2015-11-01

    The cercal system of crickets detects low-frequency air currents produced by approaching predators and self-generated air currents during singing, which may provide sensory feedback to the singing motor network. We analyzed the effect of cercal stimulation on singing motor pattern generation to reveal the response of a singing interneuron to predator-like signals and to elucidate the possible role of self-generated air currents during singing. In fictive singing males, we recorded an interneuron of the singing network while applying air currents to the cerci; additionally, we analyzed the effect of abolishing the cercal system in freely singing males. In fictively singing crickets, the effect of short air stimuli is either to terminate prematurely or to lengthen the interchirp interval, depending on their phase in the chirp cycle. Within our stimulation paradigm, air stimuli of different velocities and durations always elicited an inhibitory postsynaptic potential in the singing interneuron. Current injection in the singing interneuron elicited singing motor activity, even during the air current-evoked inhibitory input from the cercal pathway. The disruptive effects of air stimuli on the fictive singing pattern and the inhibitory response of the singing interneuron point toward the cercal system being involved in initiating avoidance responses in singing crickets, according to the established role of cerci in a predator escape pathway. After abolishing the activity of the cercal system, the timing of natural singing activity was not significantly altered. Our study provides no evidence that self-generated cercal sensory activity has a feedback function for singing motor pattern generation.

  6. Impact of cercal air currents on singing motor pattern generation in the cricket (Gryllus bimaculatus DeGeer)

    PubMed Central

    2015-01-01

    The cercal system of crickets detects low-frequency air currents produced by approaching predators and self-generated air currents during singing, which may provide sensory feedback to the singing motor network. We analyzed the effect of cercal stimulation on singing motor pattern generation to reveal the response of a singing interneuron to predator-like signals and to elucidate the possible role of self-generated air currents during singing. In fictive singing males, we recorded an interneuron of the singing network while applying air currents to the cerci; additionally, we analyzed the effect of abolishing the cercal system in freely singing males. In fictively singing crickets, the effect of short air stimuli is either to terminate prematurely or to lengthen the interchirp interval, depending on their phase in the chirp cycle. Within our stimulation paradigm, air stimuli of different velocities and durations always elicited an inhibitory postsynaptic potential in the singing interneuron. Current injection in the singing interneuron elicited singing motor activity, even during the air current-evoked inhibitory input from the cercal pathway. The disruptive effects of air stimuli on the fictive singing pattern and the inhibitory response of the singing interneuron point toward the cercal system being involved in initiating avoidance responses in singing crickets, according to the established role of cerci in a predator escape pathway. After abolishing the activity of the cercal system, the timing of natural singing activity was not significantly altered. Our study provides no evidence that self-generated cercal sensory activity has a feedback function for singing motor pattern generation. PMID:26334014

  7. Prediction of thermal behaviors of an air-cooled lithium-ion battery system for hybrid electric vehicles

    NASA Astrophysics Data System (ADS)

    Choi, Yong Seok; Kang, Dal Mo

    2014-12-01

    Thermal management has been one of the major issues in developing a lithium-ion (Li-ion) hybrid electric vehicle (HEV) battery system since the Li-ion battery is vulnerable to excessive heat load under abnormal or severe operational conditions. In this work, in order to design a suitable thermal management system, a simple modeling methodology describing thermal behavior of an air-cooled Li-ion battery system was proposed from vehicle components designer's point of view. A proposed mathematical model was constructed based on the battery's electrical and mechanical properties. Also, validation test results for the Li-ion battery system were presented. A pulse current duty and an adjusted US06 current cycle for a two-mode HEV system were used to validate the accuracy of the model prediction. Results showed that the present model can give good estimations for simulating convective heat transfer cooling during battery operation. The developed thermal model is useful in structuring the flow system and determining the appropriate cooling capacity for a specified design prerequisite of the battery system.

  8. Ambient ion soft landing.

    PubMed

    Badu-Tawiah, Abraham K; Wu, Chunping; Cooks, R Graham

    2011-04-01

    Ambient ion soft landing, a process in which polyatomic ions are deposited from air onto a surface at a specified location under atmospheric pressure, is described. Ions generated by electrospray ionization are passed pneumatically through a heated metal drying tube, their ion polarity is selected using ion deflectors, and the dry selected ions are soft-landed onto a selected surface. Unlike the corresponding vacuum soft-landing experiment, where ions are mass-selected and soft-landed within a mass spectrometer, here the ions to be deposited are selected through the choice of a compound that gives predominantly one ionic species upon ambient ionization; no mass analysis is performed during the soft landing experiment. The desired dry ions, after electrical separation from neutrals and counterions, are deposited on a surface. Characterization of the landed material was achieved by dissolution and analysis using mass spectrometry or spectrofluorimetry. The treated surface was also characterized using fluorescence microscopy, which allowed surfaces patterned with fluorescent compounds to be imaged. The pure dry ions were used as reagents in heterogeneous ion/surface reactions including the reaction of pyrylium cations with d-lysine to form the N-substituted pyridinium cation. The charged microdroplets associated with incompletely dried ions could be selected for soft landing or surface reaction by choice of the temperature of a drying tube inserted between the ion source and the electrical ion deflectors.

  9. Better-Than-Visual Technologies for Next Generation Air Transportation System Terminal Maneuvering Area Operations

    NASA Technical Reports Server (NTRS)

    Prinzel, Lawrence J., III; Bailey, Randall E.; Shelton, Kevin J.; Jones, Denise R.; Kramer, Lynda J.; Arthur, Jarvis J., III; Williams, Steve P.; Barmore, Bryan E.; Ellis, Kyle E.; Rehfeld, Sherri A.

    2011-01-01

    A consortium of industry, academia and government agencies are devising new concepts for future U.S. aviation operations under the Next Generation Air Transportation System (NextGen). Many key capabilities are being identified to enable NextGen, including the concept of Equivalent Visual Operations (EVO) replicating the capacity and safety of today's visual flight rules (VFR) in all-weather conditions. NASA is striving to develop the technologies and knowledge to enable EVO and to extend EVO towards a Better-Than-Visual (BTV) operational concept. The BTV operational concept uses an electronic means to provide sufficient visual references of the external world and other required flight references on flight deck displays that enable VFR-like operational tempos and maintain and improve the safety of VFR while using VFR-like procedures in all-weather conditions. NASA Langley Research Center (LaRC) research on technologies to enable the concept of BTV is described.

  10. Magnetic-field generation by pulsed irradiation of aluminium in air

    SciTech Connect

    Chumakov, A N; Chekan, P V

    2015-03-31

    Magnetic-field generation arising under irradiation of an aluminium barrier in the air by a series of laser pulses is studied experimentally. It is found that the magnetic field increases nonlinearly from 10{sup -5} to 10{sup -3} T with increasing laser power density from 10{sup 7} to 10{sup 9} W cm{sup -2}, the degree of nonlinearity being different for single nanosecond pulses, for a series of such pulses with a repetition rate of 100 – 150 μs and for a combination of a millisecond laser pulse and a series of nanosecond laser pulses. The dependences of the magnetic-field induction on the power density of laser radiation in the above-mentioned regimes are established. (interaction of laser radiation with matter)

  11. Dimensional analysis of detrimental ozone generation by positive wire-to-plate corona discharge in air

    NASA Astrophysics Data System (ADS)

    Bo, Z.; Chen, J. H.

    2010-02-01

    The dimensional analysis technique is used to formulate a correlation between ozone generation rate and various parameters that are important in the design and operation of positive wire-to-plate corona discharges in indoor air. The dimensionless relation is determined by linear regression analysis based on the results from 36 laboratory-scale experiments. The derived equation is validated by experimental data and a numerical model published in the literature. Applications of such derived equation are illustrated through an example selection of the appropriate set of operating conditions in the design/operation of a photocopier to follow the federal regulations of ozone emission. Finally, a new current-voltage characteristic equation is proposed for positive wire-to-plate corona discharges based on the derived dimensionless equation.

  12. Monitoring trace elements generated by automobiles: air pollutants with possible health impacts.

    PubMed

    Anwar, Khaleeq; Ejaz, Sohail; Ashraf, Muhammad; Ahmad, Nisar; Javeed, Aqeel

    2013-07-01

    Major transformations in the environmental composition are principally attributable to the combustion of fuels by automobiles. Motorized gasoline-powered two-stroke auto-rickshaws (TSA) and compressed natural gas (CNG)-powered four-stroke auto-rickshaws (FSA) are potential source of air pollution in south Asia and produce toxic amount of particulate matter (PM) to the environment. In this study, we attempted to characterize elemental pollutants from the PM of TSA and FSA using proton-induced X-ray emission (PIXE) analysis. The observations of the existing investigation recognized significant increase in Al (P < 0.05), P (P < 0.01), and Zn (P < 0.01) from the PM samples of FSA. In addition, the concentrations of Cu, Fe, K, Mg, Na and S were also observed exceeding the recommended National Institute for Environmental Studies limits. On the contrary, increased concentration of Sr and V were observed in the PM samples from TSA. It is generally believed that FSA generates smaller amount of PM but data obtained from FSA are clearly describing that emissions from FSA comprised potentially more toxic substances than TSA. The current research is specific to metropolitan population and has evidently revealed an inconsistent burden of exposure to air pollutants engendered by FSA in urban communities, which could lead to the disruption of several biological activities and may cause severe damage to entire ecological system.

  13. Assimilation of next generation geostationary aerosol optical depth retrievals to improve air quality simulations

    NASA Astrophysics Data System (ADS)

    Saide, Pablo E.; Kim, Jhoon; Song, Chul H.; Choi, Myungje; Cheng, Yafang; Carmichael, Gregory R.

    2014-12-01

    Planned geostationary satellites will provide aerosol optical depth (AOD) retrievals at high temporal and spatial resolution which will be incorporated into current assimilation systems that use low-Earth orbiting (e.g., Moderate Resolution Imaging Spectroradiometer (MODIS)) AOD. The impacts of such additions are explored in a real case scenario using AOD from the Geostationary Ocean Color Imager (GOCI) on board of the Communication, Ocean, and Meteorology Satellite, a geostationary satellite observing northeast Asia. The addition of GOCI AOD into the assimilation system generated positive impacts, which were found to be substantial in comparison to only assimilating MODIS AOD. We found that GOCI AOD can help significantly to improve surface air quality simulations in Korea for dust, biomass burning smoke, and anthropogenic pollution episodes when the model represents the extent of the pollution episodes and retrievals are not contaminated by clouds. We anticipate future geostationary missions to considerably contribute to air quality forecasting and provide better reanalyses for health assessments and climate studies.

  14. Interim Report: Air-Cooled Condensers for Next Generation Geothermal Power Plants Improved Binary Cycle Performance

    SciTech Connect

    Daniel S. Wendt; Greg L. Mines

    2010-09-01

    As geothermal resources that are more expensive to develop are utilized for power generation, there will be increased incentive to use more efficient power plants. This is expected to be the case with Enhanced Geothermal System (EGS) resources. These resources will likely require wells drilled to depths greater than encountered with hydrothermal resources, and will have the added costs for stimulation to create the subsurface reservoir. It is postulated that plants generating power from these resources will likely utilize the binary cycle technology where heat is rejected sensibly to the ambient. The consumptive use of a portion of the produced geothermal fluid for evaporative heat rejection in the conventional flash-steam conversion cycle is likely to preclude its use with EGS resources. This will be especially true in those areas where there is a high demand for finite supplies of water. Though they have no consumptive use of water, using air-cooling systems for heat rejection has disadvantages. These systems have higher capital costs, reduced power output (heat is rejected at the higher dry-bulb temperature), increased parasitics (fan power), and greater variability in power generation on both a diurnal and annual basis (larger variation in the dry-bulb temperature). This is an interim report for the task ‘Air-Cooled Condensers in Next- Generation Conversion Systems’. The work performed was specifically aimed at a plant that uses commercially available binary cycle technologies with an EGS resource. Concepts were evaluated that have the potential to increase performance, lower cost, or mitigate the adverse effects of off-design operation. The impact on both cost and performance were determined for the concepts considered, and the scenarios identified where a particular concept is best suited. Most, but not all, of the concepts evaluated are associated with the rejection of heat. This report specifically addresses three of the concepts evaluated: the use of

  15. Association between Local Traffic-Generated Air Pollution and Preeclampsia and Preterm Delivery in the South Coast Air Basin of California

    PubMed Central

    Wu, Jun; Ren, Cizao; Delfino, Ralph J.; Chung, Judith; Wilhelm, Michelle; Ritz, Beate

    2009-01-01

    Background Preeclampsia is a major complication of pregnancy that can lead to substantial maternal and perinatal morbidity, mortality, and preterm birth. Increasing evidence suggests that air pollution adversely affects pregnancy outcomes. Yet few studies have examined how local traffic-generated emissions affect preeclampsia in addition to preterm birth. Objectives We examined effects of residential exposure to local traffic-generated air pollution on preeclampsia and preterm delivery (PTD). Methods We identified 81,186 singleton birth records from four hospitals (1997–2006) in Los Angeles and Orange Counties, California (USA). We used a line-source dispersion model (CALINE4) to estimate individual exposure to local traffic-generated nitrogen oxides (NOx) and particulate matter < 2.5 μm in aerodynamic diameter (PM2.5) across the entire pregnancy. We used logistic regression to estimate effects of air pollution exposures on preeclampsia, PTD (gestational age < 37 weeks), moderate PTD (MPTD; gestational age < 35 weeks), and very PTD (VPTD; gestational age < 30 weeks). Results We observed elevated risks for preeclampsia and preterm birth from maternal exposure to local traffic-generated NOx and PM2.5. The risk of preeclampsia increased 33% [odds ratio (OR) = 1.33; 95% confidence interval (CI), 1.18–1.49] and 42% (OR = 1.42; 95% CI, 1.26–1.59) for the highest NOx and PM2.5 exposure quartiles, respectively. The risk of VPTD increased 128% (OR = 2.28; 95% CI, 2.15–2.42) and 81% (OR = 1.81; 95% CI, 1.71–1.92) for women in the highest NOx and PM2.5 exposure quartiles, respectively. Conclusion Exposure to local traffic-generated air pollution during pregnancy increases the risk of preeclampsia and preterm birth in Southern California women. These results provide further evidence that air pollution is associated with adverse reproductive outcomes. PMID:20049131

  16. Determination of volatile organic compounds in ambient air with gas chromatograph-flame ionization and ion trap detection

    SciTech Connect

    Liu, S.; Carley, R.J.; Kang, J.; Chen, J.; Stuart, J.D.

    1994-12-31

    Two new techniques are utilized to integrate the following three equipments: an Entech 2000 automated air concentrator, a Hewlett Packard gas chromatograph (GC) with flame ionization detector (FID) and an ion trap mass spectrometer detector (ITD). This combined analytical system is used to determine low ppb level volatile organic compounds (VOC) in ambient air. The first technique is to configure the inlet system of the GC, so that the pressure regulated flow control system of the GC injection port is used to control the flow of both the desorb gas of the automated air concentrator and the carrier gas of the GC column. The injection port still can be used to inject gas and liquid samples directly. The second technique is to split the effluent of GC column at a 1:1 ratio to the ITD and the FID. In this way, both FID and ITD data can be obtained for each analysis. For ambient air non-methane hydrocarbons monitoring, the FID detector is widely used. Oxygen containing and halogenated organic compounds cannot be differentiated by FID detector and would be quantified as coeluting hydrocarbons. However, volatile organic compounds other than target hydrocarbons can be identified by ITD. This analytical system is very valuable research tool for non-methane hydrocarbons and urban air toxic monitoring. The performances of this developed system have been presented.

  17. Generation of ion temperature anisotropy in kinetic hybrid-Vlasov simulations (Invited)

    NASA Astrophysics Data System (ADS)

    Perrone, D.; Valentini, F.; Servidio, S.; Dalena, S.; Veltri, P.

    2013-12-01

    The interplanetary medium is a multi-component and weakly collisional system generally observed to be in a fully turbulent regime [1,2]. The system dynamics at short spatial scales appears to be dominated by kinetic effects that drive the interstellar gas far from the configuration of thermodynamic equilibrium [3-5]. We present a numerical analysis of a turbulent plasma composed of kinetic ions (protons and alpha particles) and fluid electrons in the typical conditions of the solar-wind environment, developed by using a low-noise hybrid Vlasov-Maxwell code [6,7] in a five dimensional phase space configuration (two dimensions in physical space and three dimensions in velocity space) [8]. The ion dynamics at short spatial scales (shorter than the proton skin depth) display several interesting aspects, mainly consisting in the departure of the distribution functions from the typical Maxwellian configuration, which has been systematically quantified through the evalutation of the temperature anisotropy ratio (perpendicular to parallel temperature ratio) with respect to the local magnetic field. This temperature anisotropy appears to be a direct effect of the turbulent nature of the system dynamics. Moreover, the turbulent activity leads to the generation of coherent structures, such as vortices and current sheets. Conditioned ion temperature distributions suggest heating associated with coherent structures; the distribution of ion temperatures moves towards higher values with increasing PVI threshold for the upper inertial range in the turbulent spectra. This behavior is more evident for alpha particles than for protons. The physical phenomenology recovered in these numerical simulations reproduces very common features recovered in 'in situ' measurements in the turbulent solar wind [9-11], suggesting that the multi-ion Vlasov model represents a valid approach to the understanding of the nature of complex kinetic effects in astrophysical plasmas. [1] R. Bruno and V

  18. Inertial confinement fusion using hohlraum radiation generated by heavy-ion clusters

    SciTech Connect

    Tahir, N.A.; Lutz, K.; Geb, O.; Maruhn, J.A.; Deutsch, C.; Hoffmann, D.H.

    1997-03-01

    This paper discusses the feasibility of employing heavy-ion cluster beams to generate thermal radiation that can be used to drive inertial fusion capsules. The low charge-to-mass ratio of a cluster may allow the driver beam to be focused to a very small spot size with a radius of the order of 100 {mu}m, while the low energy per nucleon (of the order of 10 keV) may lead to a very short range of the driver particles in the converter material. This would result in high specific power deposition that may lead to a very high conversion efficiency. The problem of cluster stopping in cold matter, as well as in hot dense plasmas has been thoroughly investigated. The conversion efficiency of cluster ions using a low-density gold converter has also been calculated over a wide range of parameters including converter density, converter geometry, and specific power deposition. These calculations have been carried out using a one-dimensional hydrodynamic computer code that includes a multigroup radiation transport scheme [Ramis {ital et al.}, Comput. Phys. Commun. {bold 49}, 475 (1988)]. The problem of symmetrization of this radiation field in a hohlraum with solid gold walls has also been thoroughly investigated using a three-dimensional view factor code. The characteristics of the radiation field obtained by this study are used as input to capsule implosion calculations that are done with a three-temperature radiation-hydrodynamic computer code MEDUSA-KAT [Tahir {ital et al.}, J. Appl. Phys. {bold 60}, 898 (1986)]. A reactor-size capsule which contains 5 mg deuterium{endash}tritium (DT) fuel is used in these calculations. The problem of using a fuel mixture with a substantially reduced tritium content has also been discussed. {copyright} {ital 1997 American Institute of Physics.}

  19. Interfacial Processes in Model Lithium Ion Systems Probed with Vibrational Sum Frequency Generation Spectroscopy

    NASA Astrophysics Data System (ADS)

    Nicolau, Bruno G.; Garcia Rey, Natalia; Dlott, Dana

    2014-06-01

    Vibrational sum frequency generation (SFG) spectroscopy was used to probe electrochemical processes taking place at the interface between metal anodes and the liquid phase in model lithium ion systems. Lithium ion batteries have been extensively studied and characterized by numerous techniques. However, the mechanisms behind many properties are still unclear due to the lack of techniques that can directly probe them in situ. The formation of the electrode passivating layer known as solid-electrolyte interphase (SEI) is one such example. During the first charging cycle of a battery, some of the electrolyte undergoes reduction at the electrode surface forming an electrically isolating barrier that prevents the subsequent reduction of more electrolyte molecules. The SFG selection rules suppress signals from molecules in centrosymmetric environments such as electrolyte layers, so SFG is a selective probe of interfacial environments such as the SEI. In this study, ethylene carbonate's (EC) response to potential cycling was observed. EC is commonly used as a high permittivity solvent in batteries and is widely believed to be the main component of the SEI in its reduced form, lithium ethylene dicarbonyl. EC's carbonyl stretch (1850 cm-1) was measured in conjunction with cyclic voltammetry experiments. The SFG intensity showed remarkable agreement with the changing potential, as seen in the figure below. The shoulders on each side of the peaks in (a) are especially interesting, as they correspond to the potentials where lithium metal is oxidized and reduced. Vibrational modes found at 1300-1400 cm-1, usually assigned to the reduced form of EC, are also being studied in order to provide more information on the nature of the SEI.

  20. Next-Generation Electrochemical Energy Materials for Intermediate Temperature Molten Oxide Fuel Cells and Ion Transport Molten Oxide Membranes.

    PubMed

    Belousov, Valery V

    2017-02-21

    oxygen ion transport in potential MOM materials and MOFC electrolytes. In addition, we consider the rapid oxygen transport in a molten oxide scale formed on a metal surface during catastrophic oxidation and show that the same transport could be used beneficially in MOMs and MOFCs. A polymer model explaining the oxygen transport in molten oxides is also considered. Understanding the oxygen transport mechanisms in oxide melts is important for the development of new generation energy materials, which will contribute to more efficient operation of electrochemical devices at intermediate temperatures. Here we highlight the progress made in developing this understanding. We also show the latest advances made in search of alternative molten oxide materials having high mixed ion electronic and ionic conductivities for use in MOMs and MOFCs, respectively. Prospects for further research are presented.

  1. Removal and Recovery of Toxic Silver Ion Using Deep-Sea Bacterial Generated Biogenic Manganese Oxides

    PubMed Central

    Pei, Yuanjun; Chen, Xiao; Xiong, Dandan; Liao, Shuijiao; Wang, Gejiao

    2013-01-01

    Products containing silver ion (Ag+) are widely used, leading to a large amount of Ag+-containing waste. The deep-sea manganese-oxidizing bacterium Marinobacter sp. MnI7-9 efficiently oxidizes Mn2+ to generate biogenic Mn oxide (BMO). The potential of BMO for recovering metal ions by adsorption has been investigated for some ions but not for Ag+. The main aim of this study was to develop effective methods for adsorbing and recovering Ag using BMO produced by Marinobacter sp. MnI7-9. In addition, the adsorption mechanism was determined using X-ray photoelectron spectroscopy analysis, specific surface area analysis, adsorption kinetics and thermodynamics. The results showed that BMO had a higher adsorption capacity for Ag+ compared to the chemical synthesized MnO2 (CMO). The isothermal absorption curves of BMO and CMO both fit the Langmuir model well and the maximum adsorption capacities at 28°C were 8.097 mmol/g and 0.787 mmol/g, for BMO and CMO, respectively. The change in enthalpy (ΔHθ) for BMO was 59.69 kJ/mol indicating that it acts primarily by chemical adsorption. The change in free energy (ΔGθ) for BMO was negative, which suggests that the adsorption occurs spontaneously. Ag+ adsorption by BMO was driven by entropy based on the positive ΔSθ values. The Ag+ adsorption kinetics by BMO fit the pseudo-second order model and the apparent activation energy of Ea is 21.72 kJ/mol. X-ray photoelectron spectroscopy analysis showed that 15.29% Ag+ adsorbed by BMO was transferred to Ag(0) and meant that redox reaction had happened during the adsorption. Desorption using nitric acid and Na2S completely recovered the Ag. The results show that BMO produced by strain MnI7-9 has potential for bioremediation and reutilization of Ag+-containing waste. PMID:24312566

  2. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses.

  3. Lower hybrid frequency range waves generated by ion polarization drift due to electromagnetic ion cyclotron waves: Analysis of an event observed by the Van Allen Probe B

    NASA Astrophysics Data System (ADS)

    Khazanov, G. V.; Boardsen, S.; Krivorutsky, E. N.; Engebretson, M. J.; Sibeck, D.; Chen, S.; Breneman, A.

    2017-01-01

    We analyze a wave event that occurred near noon between 07:03 and 07:08 UT on 23 February 2014 detected by the Van Allen Probes B spacecraft, where waves in the lower hybrid frequency range (LHFR) and electromagnetic ion cyclotron (EMIC) waves are observed to be highly correlated, with Pearson correlation coefficient of 0.86. We assume that the correlation is the result of LHFR wave generation by the ions' polarization drift in the electric field of the EMIC waves. To check this assumption the drift velocities of electrons and H+, He+, and O+ ions in the measured EMIC wave electric field were modeled. Then the LHFR wave linear instantaneous growth rates for plasma with these changing drift velocities and different plasma compositions were calculated. The time distribution of these growth rates, their frequency distribution, and the frequency dependence of the ratio of the LHFR wave power spectral density (PSD) parallel and perpendicular to the ambient magnetic field to the total PSD were found. These characteristics of the growth rates were compared with the corresponding characteristics of the observed LHFR activity. Reasonable agreement between these features and the strong correlation between EMIC and LHFR energy densities support the assumption that the LHFR wave generation can be caused by the ions' polarization drift in the electric field of an EMIC wave.

  4. A multichannel time-of-flight system for observation of energetic ions of multispecies generated from relativistic laser plasma

    SciTech Connect

    Matsukado, K.; Fujimoto, M.; Takahashi, H.; Kawada, Y.; Ohsuka, S.; Aoshima, S.

    2010-02-15

    A multichannel time-of-flight (TOF) system was constructed to observe the ions generated from relativistic laser plasma, where the ions have polychromatic energies and multiple species. The TOF system is composed of a ten-channel scintillation detector array and an electromagnet that generates a magnetic field of 0-1.24 T. The magnet field enables us to analyze protons, deuterons, and full-stripped carbon ions to 50, 25, and 150 MeV, respectively. The system experimentally identified protons of 0.27-1.6 MeV energy and ions of a half specific charge (deuterons of 0.3-0.8 MeV and full-stripped carbons of 1.8-4.8 MeV). The measured TOF values agree well with the calculated values within the designed accuracy; {+-}2.5 ns for protons and {+-}5 ns for the others (d or C{sup 6+}) on each detector channel. Comparison of ion numbers detected by a track detector (CR-39) and the TOF system enabled us to obtain the number of ions detected on each scintillation counter with less than 16% error.

  5. Thermal management improvement of an air-cooled high-power lithium-ion battery by embedding metal foam

    NASA Astrophysics Data System (ADS)

    Mohammadian, Shahabeddin K.; Rassoulinejad-Mousavi, Seyed Moein; Zhang, Yuwen

    2015-11-01

    Effect of embedding aluminum porous metal foam inside the flow channels of an air-cooled Li-ion battery module was studied to improve its thermal management. Four different cases of metal foam insert were examined using three-dimensional transient numerical simulations. The effects of permeability and porosity of the porous medium as well as state of charge were investigated on the standard deviation of the temperature field and maximum temperature inside the battery in all four cases. Compared to the case of no porous insert, embedding aluminum metal foam in the air flow channel significantly improved the thermal management of Li-ion battery cell. The results also indicated that, decreasing the porosity of the porous structure decreases both standard deviation of the temperature field and maximum temperature inside the battery. Moreover, increasing the permeability of the metal foam drops the maximum temperature inside the battery while decreasing this property leads to improving the temperature uniformity. Our results suggested that, among the all studied cases, desirable temperature uniformity and maximum temperature were achieved when two-third and the entire air flow channel is filled with aluminum metal foam, respectively.

  6. Terahertz-pulse generation by photoionization of air with laser pulses composed of both fundamental and second-harmonic waves.

    PubMed

    Kress, Markus; Löffler, Torsten; Eden, Susanne; Thomson, Mark; Roskos, Hartmut G

    2004-05-15

    Intense radiation in the terahertz (THz) frequency range can be generated by focusing of an ultrashort laser pulse composed of both a fundamental wave and its second-harmonic field into air, as reported previously by Cook et al. [Opt. Lett. 25, 1210 (2000)]. We identify a threshold for THz generation that proves that generation of a plasma is required and that the nonlinearity of air is insufficient to explain our measurements. An additional THz field component generated in the type I beta-barium borate crystal used for second-harmonic generation has to be considered if one is to avoid misinterpretation of this kind of experiment. We conclude with a comparison that shows that the plasma emitter is competitive with other state-of-the-art THz emitters.

  7. Ion specific effects: decoupling ion-ion and ion-water interactions

    PubMed Central

    Song, Jinsuk; Kang, Tae Hui; Kim, Mahn Won; Han, Songi

    2015-01-01

    Ion-specific effects in aqueous solution, known as the Hofmeister effect is prevalent in diverse systems ranging from pure ionic to complex protein solutions. The objective of this paper is to explicitly demonstrate how complex ion-ion and ion-water interactions manifest themselves in the Hofmeister effects, based on a series of recent experimental observation. These effects are not considered in the classical description of ion effects, such as the Deryaguin-Landau-Verwey-Overbeek (DLVO) theory that, likely for that reason, fail to describe the origin of the phenomenological Hofmeister effect. However, given that models considering the basic forces of electrostatic and van der Waals interactions can offer rationalization for the core experimental observations, a universal interaction model stands a chance to be developed. In this perspective, we separately derive the contribution from ion-ion electrostatic interaction and ion-water interaction from second harmonic generation (SHG) data at the air-ion solution interface, which yields an estimate of ion-water interactions in solution. Hofmeister ion effects observed on biological solutes in solution should be similarly influenced by contributions from ion-ion and ion-water interactions, where the same ion-water interaction parameters derived from SHG data at the air-ion solution interface could be applicable. A key experimental data set available from solution systems to probe ion-water interaction is the modulation of water diffusion dynamics near ions in bulk ion solution, as well as near biological liposome surfaces. It is obtained from Overhauser dynamic nuclear polarization (ODNP), a nuclear magnetic resonance (NMR) relaxometry technique. The surface water diffusivity is influenced by the contribution from ion-water interactions, both from localized surface charges and adsorbed ions, although the relative contribution of the former is larger on liposome surfaces. In this perspective, ion-water interaction

  8. CW/Pulsed H- ion beam generation with PKU Cs-free 2.45 GHz microwave driven ion source

    NASA Astrophysics Data System (ADS)

    Peng, S. X.; Ren, H. T.; Xu, Y.; Zhang, T.; Zhang, A. L.; Zhang, J. F.; Zhao, J.; Guo, Z. Y.; Chen, J. E.

    2015-04-01

    Circular accelerators used for positron emission tomography (PET, i.e. accelerator used for make radio isotopes) need several mA of CW H- ion beam for their routine operation. Other facilities, like Space Radio-Environment Simulate Assembly (SPRESA), require less than 10 mA pulsed mode H- beam. Caesium free negative hydrogen ion source is a good choice for those facilities because of its compact structure, easy operation and low cost. Up to now, there is no H- source able to produce very intense H- beams with important variation of the duty factor[1]. Recently, a new version of 2.45 GHz microwave H- ion source was designed at PKU, based on lessons learnt from the previous one. This non cesiated source is very compact thanks to its permanent magnet configuration. Special attention was paid on the design of the discharge chamber structure, electron dumping and extraction system. Source test to produce H- ion beams in pulsed and CW mode was carried out on PKU ion source test bench. In CW mode, a 10.8 mA/30keV H- beam with rms emittance about 0.16 π.mm.mrad has been obtained with only 500 W rf power. The power efficiency reaches 21 mA/kW. In pulsed mode with duty factor of 10% (100Hz/1ms), this compact source can easily deliver 20 mA H- ion beam at 35 keV with rms emittance about 0.2 π.mm.mrad when RF power is set at 2.2 kW (peak power). Several hour successive running operation in both modes and totaling more than 200 hours proves its high quality. The outside dimension of this new H- source body is ϕ116 mm × 124 mm, and the entire H- source infrastructure, including rf matching section, plasma chamber and extraction system, is ϕ310 × 180 mm. The high voltage region is limited with in a ϕ310 mm × 230 mm diagram. Details are given in this paper.

  9. Highly efficient generation of ultraintense high-energy ion beams using laser-induced cavity pressure acceleration

    SciTech Connect

    Badziak, J.; Jablonski, S.; Raczka, P.

    2012-08-20

    Results of particle-in-cell (PIC) simulations of fast ion generation in the recently proposed laser-induced cavity pressure acceleration (LICPA) scheme in which a picosecond circularly polarized laser pulse of intensity {approx}10{sup 21} W/cm{sup 2} irradiates a carbon target placed in a cavity are presented. It is shown that due to circulation of the laser pulse in the cavity, the laser-ions energy conversion efficiency in the LICPA scheme is more than twice as high as that for the conventional (without a cavity) radiation pressure acceleration scheme and a quasi-monoenergetic carbon ion beam of the mean ion energy {approx}0.5 GeV and the energy fluence {approx}0.5 GJ/cm{sup 2} is produced with the efficiency {approx}40%. The results of PIC simulations are found to be in fairly good agreement with the predictions of the generalized light-sail model.

  10. Influence of grid control on beam quality in laser ion source generating high-current low-charged copper ions

    SciTech Connect

    Hasegawa, J.; Yoshida, M.; Ogawa, M.; Oguri, Y.; Nakajima, M.; Horioka, K.; Kwan, J.

    2003-08-01

    We examined grid-controlled extraction for a laser ion source using a KrF laser. By using grid-controlled extraction in the over-dense regime, we found that the ion beam current waveforms were stabilized more significantly as the grid bias raised from -90 V to -280 V. The normalized emittance of 0.08 {pi}mm-mrad measured without the grid control was improved to 0.06 {pi}mm-mrad with the grid control. In contrast to this observation, the grid bias disturbed the pattern of the beam extracted in the source-limited regime. Fast extraction was carried out using a high-voltage pulse with a rise time of {approx} 100 ns. The grid control suppressed successfully the beam pedestal originating from the plasma pre-filled in the extraction gap.

  11. Reaction of carbon nucleophiles with alkylideneindazolium and alkylideneindolium ions generated from their 3-(1-arylsulfonylalkyl) indazole and indole precursors.

    PubMed

    Marsili, Laura; Palmieri, Alessandro; Petrini, Marino

    2010-02-07

    Lewis acid promoted elimination of p-toluenesulfinc acid from sulfonyl indazoles and sulfonyl indoles generates the corresponding iminium ion that reacts with allyltin reagents, silyl enol ethers, silyl ketene acetals and electron-rich aromatics leading to functionalized indazole and indole derivatives.

  12. High-energy ion generation in interaction. of short laser pulse with high-density plasma

    NASA Astrophysics Data System (ADS)

    Sentoku, Y.; Bychenkov, V. Y.; Flippo, K.; Maksimchuk, A.; Mima, K.; Mourou, G.; Sheng, Z. M.; Umstadter, D.

    2002-03-01

    Multi-MeV ion production from the interaction of a short laser pulse with a high-density plasma, accompanied by an underdense preplasma, has been studied with a particle-in-cell simulation and good agreement is found with experiment. The mechanism primarily responsible for the acceleration of ions is identified. Comparison with experiments sheds light on the ion-energy dependence on laser intensity, preplasma scale length, and relative ion energies for a multi-species plasma. Two regimes of maximum ion-energy dependence on laser intensity, I, have been identified: subrelativistic, ∝I; and relativistic, ∝. Simulations show that the energy of the accelerated ions versus the preplasma scale length increases linearly and then saturates. In contrast, the ion energy decreases with the thickness of the solid-density plasma.

  13. Generation of heavy ion beams using high-intensity short pulse lasers

    NASA Astrophysics Data System (ADS)

    Petrov, George; McGuffey, Chris; Thomas, Alec; Krushelnick, Karl; Beg, Farhat

    2016-10-01

    A theoretical study of ion acceleration from high-Z material irradiated by intense sub-picosecond lasers is presented. The underlying physics of beam formation and acceleration is similar for light and heavy ions, however, nuances of the acceleration process make the heavy ions more challenging. At least four technical hurdles have been identified: low charge-to-mass ratio, limited number of ions amenable to acceleration, delayed acceleration and poor energy coupling due to high reflectivity of the plasma. Using two dimensional particle-in-cell (PIC) simulations, we observed transitions from Radiation Pressure Acceleration (RPA) to the Breakout Afterburner regime (BoA) and to Target Normal Sheath Acceleration (TNSA) akin to light ions. The numerical simulations predict gold ions beams with high directionality (<10 degrees half-angle), high fluxes (>1011 ions/sr) and energy (>10 MeV/nucleon) from laser systems delivering >20 J of energy on target.

  14. Generation of light-induced electrical potential from ion exchange membranes containing 4,4{prime}-bipyridine moiety

    SciTech Connect

    Sata, Toshikatsu

    1996-07-15

    Ion exchange membranes, which are some of the most advanced separation membranes, are widely used in industry, i.e., in electrodialysis processes, diffusion dialysis processes, as separators for electrolysis, solid polyelectrolytes for fuel cells, etc. Generation of photovoltage and photocurrent from ion exchange membranes containing a viologen moiety was examined, cation exchange membranes ion-exchanged with methyl viologen and anion exchange membranes to which a viologen moiety was bonded. After the membrane, swelled with ethylene glycol, had been clamped between two ITO electrodes and sealed, it was irradiated with a xenon lamp. In the case of the cation exchange membranes ion-exchanged with methyl viologen, 155.3 mV of photo-voltage was observed immediately after photoirradiation, and the voltage decreased and attained almost a constant value. The photovoltage of anion exchange membranes with the viologen moiety increased very slowly (maximum 81 mV, 405 nA; load resistance 200 K{Omega}) after beginning the irradiation. However, when the light was irradiated again on the membrane after interruption of the irradiation, almost the same photovoltage was generated immediately after the irradiation. Though the anion exchange membrane showed absorbance only at 320 nm in the UV-VIS spectrum, wavelengths between 300 and 400 nm were active to reduce the viologen moiety of the membrane. This might be due to a polymer effect. On the other hand, the electrical resistance between the ITO electrodes decreased upon photoirradiation because of radical formation. In order to accelerate generation of the voltage, an oxidative agent (ferric ions) or a reductive agent (triethanolamine) was added to the system. The photovoltage was generated immediately after irradiation in both cases. Ferric ions act as an electron acceptor and triethanolamine forms cation radicals in the membrane before the irradiation.

  15. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li–air batteries

    DOE PAGES

    Wang, Qiang; Zheng, Dong; McKinnon, Meaghan E.; ...

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. As a result, the reactions are found to be first order and the rate constants aremore » 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.« less

  16. Failure to produce taste-aversion learning in rats exposed to static electric fields and air ions

    SciTech Connect

    Creim, J.A.; Lovely, R.H.; Weigel, R.J.; Forsythe, W.C.; Anderson, L.E.

    1995-12-01

    Taste-aversion (TA) learning was measured to determine whether exposure to high-voltage direct current (HVdc) static electric fields can produce TA learning in male Long Evans rats. Fifty-six rats were randomly distributed into four groups of 14 rats each. All rats were placed on a 20 min/day drinking schedule for 12 consecutive days prior to receiving five conditioning trials. During the conditioning trials, access to 0.1% sodium saccharin-flavored water was given for 20 min, followed 30 min later by one of four treatments. Two groups of 14 rats each were individually exposed to static electric fields and air ions, one group to +75 kV/m (+2 {times} 10{sup 5} air ions/cm{sup 3}) and the other group to {minus}75 kV/m ({minus}2 {times} 10{sup 5} air ions/cm{sup 3}). Two other groups of 14 rats each served as sham-exposed controls, with the following variation in one of the sham-exposed groups: this group was subdivided into two subsets of seven rats each, so that a positive control group could be included to validate the experimental design. The positive control group (n = 7) was injected with cyclophosphamide 25 mg/kg, i.p., 30 min after access to saccharin-flavored water on conditioning days, whereas the other subset of seven rats was similarly injected with an equivalent volume of saline. Access to saccharin-flavored water on conditioning days was followed by the treatments described above and was alternated daily with water recovery sessions in which the rats received access to water for 20 min in the home cage without further treatment. Following the last water-recovery session, a 20 min, two-bottle preference test (between water and saccharin-flavored water) was administered to each group. The positive control group did show TA learning, thus validating the experimental protocol.

  17. Ion Composition of Fog Water and Its Relation to Air Pollutants during Winter Fog Events in Nanjing, China

    NASA Astrophysics Data System (ADS)

    Yang, Jun; Xie, Yu-Jing; Shi, Chun-E.; Liu, Duan-Yang; Niu, Sheng-Jie; Li, Zi-Hua

    2012-05-01

    Intensive field experiments focused on fog chemistry were carried out in the northern suburb of Nanjing during the winters of 2006 and 2007. Thirty-seven fog water samples were collected in nine fog events. Based on the chemical analysis results of those samples and the simultaneous measurements of air pollution gases and atmospheric aerosols, the chemical characteristics of fog water and their relations with air pollutants during fog evolution were investigated. The results revealed an average total inorganic ionic concentration TIC = 21.18 meq/L, and the top three ion concentrations were those of SO4 2-, NH4 + and Ca2+ (average concentrations 6.99, 5.95, 3.77 meq/L, respectively). However, the average pH value of fog water was 5.85, which is attributable to neutralization by basic ions (NH4 + and Ca2+). The average TIC value of fog water measured in advection-radiation fog was around 2.2 times that in radiation fog, and the most abundant cation was NH4 + in advection-radiation fog and Ca2+ in radiation fog. In dense fog episodes, the concentration variations of primary inorganic pollution gases showed a "V"-shaped pattern, while those of volatile organic compounds (VOCs) displayed a "Λ"-shaped pattern. The dense fog acted as both the source and sink of atmospheric aerosol particles; fog processes enhanced particle formation, leading to the phenomenon that the aerosol concentration after fog dissipation was higher than that before the fog, and at the same time, mass concentration of PM10 reached the lowest value in the late stage of extremely dense fog episodes because of the progressive accumulated effect of wet deposition of large fog droplets. Both air pollution gases and aerosols loading controlled the ion compositions of fog water. The Ca2+ in fog water originated from airborne particles, while SO4 2- and NH4 + were from both heterogeneous production and soluble particulate species.

  18. The Qualification of a Next Generation Li-Ion Cell- The ABSL 18650NL

    NASA Astrophysics Data System (ADS)

    Simmons, Nick; Thwaite, Carl; Presvytis, Dimitris

    2014-08-01

    This paper describes ABSL's programme to qualify a next generation Li-ion cell - the ABSL 18650NL cell (the NL cell). The qualification of this cell will introduce a product to the market with a 40% capacity benefit when compared to ABSL's current heritage offering with the 18650HC cell.Space qualification was initially started in 2009 and the cell was used for a series of space programmes. Due to a change in manufacturing location and a change in anode material, the qualification required updating.ABSL initiated a full requalification effort and in addition improved the cell supply agreement to ensure that ABSL batches will be made to order with additional manufacturing controls and traceability for each batch.ABSL's qualification described in this paper is intended to meet the following objectives: * Physical Tests - to enable battery modules to be manufactured, and give data for batch comparison * Environmental Tests - to ensure the cell can survive the space environment * Safety - to ensure the safety mechanisms work consistently * Characterisation and Lifetests - to provide detailed performance information for use in battery sizing

  19. Application of Laser-Generated Ion Beams for Isochoric Heating to Study Plasma Mix at Interfaces

    NASA Astrophysics Data System (ADS)

    Albright, B. J.; Fernández, J. C.; Bang, W.; Bradley, P. A.; Gautier, D. C.; Hamilton, C. E.; Palaniyappan, S.; Santiago Cordoba, M. A.; Vold, E. L.; Yin, L.; Hegelich, B. M.; Dyer, G.; Roycroft, R.

    2015-11-01

    The evolution and mixing of high-Z/low-Z interfaces in plasma media is of profound importance to high energy density physics and inertial fusion experiments. Recent experiments performed at the LANL Trident laser facility as part of the Plasma Interfacial Mix project have applied novel, laser-generated ion beams created under conditions of relativistic induced transparency to the heating of solid-density, multi-material targets isochorically and uniformly (over a few tens of ps), attaining plasma temperatures of several eV. Measurements have been made of the evolving plasma, including location of the material interface and the time-history of the temperature of the medium. Recent data and associated radiation hydrodynamic modeling from our Trident campaigns will be reported. Complementary kinetic simulations of interface evolution, showing anomalously rapid atomic mixing under conditions relevant to ICF experiments, will also be discussed. Work performed under the auspices of the U.S. DOE by the LANS, LLC, Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396. Funding provided by the Los Alamos National Laboratory Directed Research and Development Program.

  20. Determination of mercury(II) ion by electrochemical cold vapor generation atomic absorption spectrometry.

    PubMed

    Arbab-Zavar, M Hosein; Rounaghi, G Hosein; Chamsaz, Mahmoud; Masrournia, Mahboube

    2003-05-01

    A technique for determination of mercury is described; it is based on electrolytic reduction of Hg(II) ion on a graphite cathode, the trapping of mercury vapor and its volatilization into a quartz tube aligned in the optical path of an atomic absorption spectrometer. The electrochemical cell consisted of a graphite cathode and an anode operating with constant direct current for the production of mercury atoms. A pre-activated graphite rod was used as the cathode material. The optimum conditions for electrochemical generation of mercury cold vapor (the electrolysis time and current, the flow rate, the type of electrode and electrolyte) were investigated. The characteristic electrochemical data with chemical cold vapor using NaBH4-acid were compared. The presence of cadmium(II), arsenic(III), antimony(III), selenium(IV), bismuth(III), silver(I), lead(II), lithium(I), sodium(I) and potassium(I) showed interference effects which were eliminated by suitable separation techniques. The calibration curve is linear over the range of 5-90 ng ml(-1) mercury(II). The detection limit is 2 ng ml(-1) of Hg(II) and the RSD is 2.5% (n = 10) for 40 ng ml(-1). The accuracy and recovery of the method were investigated by analyzing spiked tap water and river water.

  1. A novel method for the multiplexed target enrichment of MinION next generation sequencing libraries using PCR-generated baits.

    PubMed

    Karamitros, Timokratis; Magiorkinis, Gkikas

    2015-12-15

    The enrichment of targeted regions within complex next generation sequencing libraries commonly uses biotinylated baits to capture the desired sequences. This method results in high read coverage over the targets and their flanking regions. Oxford Nanopore Technologies recently released an USB3.0-interfaced sequencer, the MinION. To date no particular method for enriching MinION libraries has been standardized. Here, using biotinylated PCR-generated baits in a novel approach, we describe a simple and efficient way for multiplexed enrichment of MinION libraries, overcoming technical limitations related with the chemistry of the sequencing-adapters and the length of the DNA fragments. Using Phage Lambda and Escherichia coli as models we selectively enrich for specific targets, significantly increasing the corresponding read-coverage, eliminating unwanted regions. We show that by capturing genomic fragments, which contain the target sequences, we recover reads extending targeted regions and thus can be used for the determination of potentially unknown flanking sequences. By pooling enriched libraries derived from two distinct E. coli strains and analyzing them in parallel, we demonstrate the efficiency of this method in multiplexed format. Crucially we evaluated the optimal bait size for large fragment libraries and we describe for the first time a standardized method for target enrichment in MinION platform.

  2. Static and Hypersonic Experimental Analysis of Impulse Generation in Air-Breathing Laser-Thermal Propulsion

    NASA Astrophysics Data System (ADS)

    Salvador, Israel Irone

    The present research campaign centered on static and hypersonic experiments performed with a two-dimensional, repetitively-pulsed (RP) laser Lightcraft model. The future application of interest for this basic research endeavor is the laser launch of nano- and micro-satellites (i.e., 1-100 kg payloads) into Low Earth Orbit (LEO), at low-cost and "on-demand". This research began with an international collaboration on Beamed Energy Propulsion between the United States Air Force and Brazilian Air Force to conduct experiments at the Henry T. Nagamatsu Laboratory of Aerothermodynamics and Hypersonics (HTN-LAH). The laser propulsion (LP) experiments employed the T3 Hypersonic Shock Tunnel (HST), integrated with twin gigawatt pulsed Lumonics 620-TEA CO2 lasers to produce the required test conditions. Following an introduction of the pulsed laser thermal propulsion concept and a state-of-the-art review of the topic, the principal physical processes are outlined starting from the onset of the laser pulse and subsequent laser-induced air-breakdown, to the expansion and exhaust of the resulting blast wave. After installation of the 254 mm wide, 2D Lightcraft model into the T3 tunnel, static LP tests were performed under quiescent (no-flow) conditions at ambient pressures of 0.06, 0.15, 0.3 and 1 bar, using the T3 test-section/dump-tank as a vacuum chamber. Time-dependent surface pressure distributions were measured over the engine thrust-generating surfaces following laser energy deposition; the delivered impulse and momentum coupling coefficients (Cm) were calculated from that pressure data. A Schlieren visualization system (using a high-speed Cordin digital camera) captured the laser breakdown and blast wave expansion process. The 2D model's Cm performance of 600 to 3000 N/MW was 2.5-5x higher than theoretical projections available in the literature, but indeed in the realm of feasibility for static conditions. Also, these Cm values exceed that for smaller Lightcraft models

  3. [Characteristics of aerosol water-soluble inorganic ions in three types air-pollution incidents of Nanjing City].

    PubMed

    Zhang, Qiu-Chen; Zhu, Bin; Su, Ji-Feng; Wang, Hong-Lei

    2012-06-01

    In order to compare aerosol water-soluble inorganic species in different air-pollution periods, samples of PM10, PM2.1, PM1.1 and the main water-soluble ions (NH4+, Mg2+, Ca2+, Na+, K+, NO2(-), F(-), NO3(-), Cl(-), SO4(2-)) were measured, which were from 3 air-pollution incidents (continued pollution in October 16-30 of 2009, sandstorm pollution in April 27-30 of 2010, and crop burning pollution in June 14 of 2010. The results show that aerosol pollution of 3 periods is serious. The lowest PM2.1/PM10 is only 0.27, which is from sandstorm pollution period, while the largest is 0. 7 from crop burning pollution period. In continued pollution periods, NO3(-) and SO4(2-) are the dominant ions, and the total anions account for an average of 18.62%, 32.92% and 33.53% of PM10, PM2.1 and PM1.1. Total water-soluble ions only account for 13.36%, 23.72% and 28.54% of PM10, PM2.1 and PM1.1 due to the insoluble species is increased in sandstorm pollution period. The mass concentration of Ca2+ in sandstorm pollution period is higher than the other two pollution periods, and which is mainly in coarse particles with diameter larger than 1 microm. All the ten water-soluble ions are much higher in crop burning pollution especially K+ which is the tracer from crop burning. The peak mass concentrations of NO3(-), SO4(2-) and NH4+ are in 0.43-0.65 microm.

  4. Effects of air ions on the neonatal growth of laboratory rats

    NASA Astrophysics Data System (ADS)

    Hinsull, S. M.; Bellamy, D.; Head, E. L.

    1981-12-01

    The effect of continuous positive and negative ionization on the growth of rats during the pre and post natal period, up to 10 weeks of age was investigated. It was found that continuous exposure to 1.0×104 pos. ions/ml had no detrimental effect on the animals at any stage of their development. In contrast, exposure to 1.0×104 neg. ions/ml, during gestation and the early post natal period, resulted in some adverse effects on growth and development. However, when exposure to this level of negative ions began at the time of weaning, no adverse effects were observed.

  5. Grain Boundary Engineering of Lithium-Ion-Conducting Lithium Lanthanum Titanate for Lithium-Air Batteries

    DTIC Science & Technology

    2015-01-01

    Tojo T, Sakurai Y. Synthesis and lithium - ion conductivity for perovskite-type Li3/8Sr7/16Ta3/4Zr1/4O3 solid electrolyte by powder-bed sintering...battery performance is limited by the electrolytic membrane, which needs high Li-ionic conductivity. Lithium lanthanum titanate (Li3xLa(2/3)-xTiO3, or...of the A-site ions and lithium ion conductivity in the perovskite solid solution La0.67-xLi3xTiO3 (x=0.11). Journal of Solid State Ionics. 1999;121

  6. Failure to produce taste-aversion learning in rats exposed to static electric fields and air ions.

    PubMed

    Creim, J A; Lovely, R H; Weigel, R J; Forsythe, W C; Anderson, L E

    1995-01-01

    Taste-aversion (TA) learning was measured to determine whether exposure to high-voltage direct current (HVdc) static electric fields can produce TA learning in male Long Evans rats. Fifty-six rats were randomly distributed into four groups of 14 rats each. All rats were placed on a 20 min/day drinking schedule for 12 consecutive days prior to receiving five conditioning trials. During the conditioning trials, access to 0.1% sodium saccharin-flavored water was given for 20 min, followed 30 min later by one of four treatments. Two groups of 14 rats each were individually exposed to static electric fields and air ions, one group to +75 kV/m (+2 x 10(5) air ions/cm3) and the other group to -75 kV/m (-2 x 10(5) air ions/cm3). Two other groups of 14 rats each served as sham-exposed controls, with the following variation in one of the sham-exposed groups: This group was subdivided into two subsets of seven rats each, so that a positive control group could be included to validate the experimental design. The positive control group (n = 7) was injected with cyclophosphamide 25 mg/kg, i.p., 30 min after access to saccharin-flavored water on conditioning days, whereas the other subset of seven rats was similarly injected with an equivalent volume of saline. Access to saccharin-flavored water on conditioning days was followed by the treatments described above and was alternated daily with water "recovery" sessions in which the rats received access to water for 20 min in the home cage without further treatment. Following the last water-recovery session, a 20 min, two-bottle preference test (between water and saccharin-flavored water) was administered to each group. The positive control group did show TA learning, thus validating the experimental protocol. No saccharin-flavored water was consumed in the two-bottle preference test by the cyclophosphamide-injected, sham-exposed group compared to 74% consumed by the saline-injected sham-exposed controls (P < .0001). Saccharin

  7. Application of ion chemistry and the SIFT technique to the quantitative analysis of trace gases in air and on breath

    NASA Astrophysics Data System (ADS)

    Smith, David; Španěl, Patrik

    Our major objective in this paper is to describe a new method we have developed for the analysis of trace gases at partial pressures down to the ppb level in atmospheric air, with special emphasis on the detection and quantification of trace gases on human breath. It involves the use of our selected ion flow tube (Sift) technique which we previously developed and used extensively for the study of gas phase ionic reactions occurring in ionized media such as the terrestrial atmosphere and interstellar gas clouds. Before discussing this analytical technique we describe the results of our very recent Sift and flowing afterglow (FA) studies of the reactions of the H3O+ and OH- ions, of their hydrates H3O+(H2O)1,2,3 and OH- (H2O)1,2, and of NO+ and O2+, with several hydrocarbons and oxygen-bearing organic molecules, studies that are very relevant to our trace gas analytical studies. Then follows a detailed discussion of the application of our Sift technique to trace gas analysis, after which we present some results obtained for the analyses of laboratory air, the breath of a healthy non-smoking person, the breath of a person who regularly smokes cigarettes, the complex vapours emitted by banana and onion, and the molecules present in a butane/air flame. We show how the quantitative analysis of breath can be achieved from only a single exhalation and in real time (the time response of the instrument is only about 20 ms). We also show how the time variation of breath gases over long time periods can be followed, using the decay of ethanol on the breath after the ingestion of distilled liquor as an example, yet simultaneously following several other trace gases including acetone and isoprene which are very easily detected on the breath of all individuals because of their relatively high partial pressures (typically 100 to 1000 ppb). The breath of a smoker is richer in complex molecules, some nitrogen containing organics apparently being very evident at the 5 to 50 ppb level

  8. External CO2 and water supplies for enhancing electrical power generation of air-cathode microbial fuel cells.

    PubMed

    Ishizaki, So; Fujiki, Itto; Sano, Daisuke; Okabe, Satoshi

    2014-10-07

    Alkalization on the cathode electrode limits the electrical power generation of air-cathode microbial fuel cells (MFCs), and thus external proton supply to the cathode electrode is essential to enhance the electrical power generation. In this study, the effects of external CO2 and water supplies to the cathode electrode on the electrical power generation were investigated, and then the relative contributions of CO2 and water supplies to the total proton consumption were experimentally evaluated. The CO2 supply decreased the cathode pH and consequently increased the power generation. Carbonate dissolution was the main proton source under ambient air conditions, which provides about 67% of total protons consumed for the cathode reaction. It is also critical to adequately control the water content on the cathode electrode of air-cathode MFCs because the carbonate dissolution was highly dependent on water content. On the basis of these experimental results, the power density was increased by 400% (143.0 ± 3.5 mW/m(2) to 575.0 ± 36.0 mW/m(2)) by supplying a humid gas containing 50% CO2 to the cathode chamber. This study demonstrates that the simultaneous CO2 and water supplies to the cathode electrode were effective to increase the electrical power generation of air-cathode MFCs for the first time.

  9. Scripted drives: A robust protocol for generating exposures to traffic-related air pollution

    NASA Astrophysics Data System (ADS)

    Patton, Allison P.; Laumbach, Robert; Ohman-Strickland, Pamela; Black, Kathy; Alimokhtari, Shahnaz; Lioy, Paul J.; Kipen, Howard M.

    2016-10-01

    Commuting in automobiles can contribute substantially to total traffic-related air pollution (TRAP) exposure, yet measuring commuting exposures for studies of health outcomes remains challenging. To estimate real-world TRAP exposures, we developed and evaluated the robustness of a scripted drive protocol on the NJ Turnpike and local roads between April 2007 and October 2014. Study participants were driven in a car with closed windows and open vents during morning rush hours on 190 days. Real-time measurements of PM2.5, PNC, CO, and BC, and integrated samples of NO2, were made in the car cabin. Exposure measures included in-vehicle concentrations on the NJ Turnpike and local roads and the differences and ratios of these concentrations. Median in-cabin concentrations were 11 μg/m3 PM2.5, 40 000 particles/cm3, 0.3 ppm CO, 4 μg/m3 BC, and 20.6 ppb NO2. In-cabin concentrations on the NJ Turnpike were higher than in-cabin concentrations on local roads by a factor of 1.4 for PM2.5, 3.5 for PNC, 1.0 for CO, and 4 for BC. Median concentrations of NO2 for full rides were 2.4 times higher than ambient concentrations. Results were generally robust relative to season, traffic congestion, ventilation setting, and study year, except for PNC and PM2.5, which had secular and seasonal trends. Ratios of concentrations were more stable than differences or absolute concentrations. Scripted drives can be used to generate reasonably consistent in-cabin increments of exposure to traffic-related air pollution.

  10. Scripted drives: A robust protocol for generating exposures to traffic-related air pollution.

    PubMed

    Patton, Allison P; Laumbach, Robert; Ohman-Strickland, Pamela; Black, Kathy; Alimokhtari, Shahnaz; Lioy, Paul; Kipen, Howard M

    2016-10-01

    Commuting in automobiles can contribute substantially to total traffic-related air pollution (TRAP) exposure, yet measuring commuting exposures for studies of health outcomes remains challenging. To estimate real-world TRAP exposures, we developed and evaluated the robustness of a scripted drive protocol on the NJ Turnpike and local roads between April 2007 and October 2014. Study participants were driven in a car with closed windows and open vents during morning rush hours on 190 days. Real-time measurements of PM2.5, PNC, CO, and BC, and integrated samples of NO2, were made in the car cabin. Exposure measures included in-vehicle concentrations on the NJ Turnpike and local roads and the differences and ratios of these concentrations. Median in-cabin concentrations were 11 μg/m(3) PM2.5, 40 000 particles/cm(3), 0.3 ppm CO, 4 μg/m(3) BC, and 20.6 ppb NO2. In-cabin concentrations on the NJ Turnpike were higher than in-cabin concentrations on local roads by a factor of 1.4 for PM2.5, 3.5 for PNC, 1.0 for CO, and 4 for BC. Median concentrations of NO2 for full rides were 2.4 times higher than ambient concentrations. Results were generally robust relative to season, traffic congestion, ventilation setting, and study year, except for PNC and PM2.5, which had secular and seasonal trends. Ratios of concentrations were more stable than differences or absolute concentrations. Scripted drives can be used for generating reasonably consistent in-cabin increments of exposure to traffic-related air pollution.

  11. Generating High-Brightness Light Ion Beams for Inertial Fusion Energy

    SciTech Connect

    Adams, R.G.; Bailey, J.E.; Cuneno, M.E.; Desjarlais, M.P.; Filuk, A.B.; Hanson, D.L.; Johnson, D.J.; Mehlohorn, T.A.; Menge, P.R.; Olson, C.L.; Pointon, T.D. Slutz, S.A.; Vesey, R.A.; Welch, D.R.; Wenger, D.F.

    1998-10-22

    Light ion beams may be the best option for an Inertial Fusion Energy (IFE) driver from the standpoint of ei%ciency, standoff, rep-rate operation and cost. This approach uses high-energy-density pulsed power to efficiently accelerate ions in one or two stages at fields of 0.5 to 1.0 GV/m to produce a medium energy (30 MeV), high-current (1 MA) beam of light ions, such as lithium. Ion beams provide the ability for medium distance transport (4 m) of the ions to the target, and standofl of the driver from high- yield implosions. Rep-rate operation of' high current ion sources has ako been demonstrated for industrial applications and couId be applied to IFE. Although (hese factors make light ions the best Iong-teml pulsed- power approach to IFE, light-ion research is being suspended this year in favor of a Z-pinch-driven approach which has the best opport lnity to most-rapidly achieve the U.S. Department of Energy sponsor's goal of high-yield fusion. This paper will summarize the status and most recent results of the light-ion beam program at Sandia National Laboratories (SNL), and document the prospects of light ions for future IFE driver development.

  12. NASA Langley's Formal Methods Research in Support of the Next Generation Air Transportation System

    NASA Technical Reports Server (NTRS)

    Butler, Ricky W.; Munoz, Cesar A.

    2008-01-01

    This talk will provide a brief introduction to the formal methods developed at NASA Langley and the National Institute for Aerospace (NIA) for air traffic management applications. NASA Langley's formal methods research supports the Interagency Joint Planning and Development Office (JPDO) effort to define and develop the 2025 Next Generation Air Transportation System (NGATS). The JPDO was created by the passage of the Vision 100 Century of Aviation Reauthorization Act in Dec 2003. The NGATS vision calls for a major transformation of the nation s air transportation system that will enable growth to 3 times the traffic of the current system. The transformation will require an unprecedented level of safety-critical automation used in complex procedural operations based on 4-dimensional (4D) trajectories that enable dynamic reconfiguration of airspace scalable to geographic and temporal demand. The goal of our formal methods research is to provide verification methods that can be used to insure the safety of the NGATS system. Our work has focused on the safety assessment of concepts of operation and fundamental algorithms for conflict detection and resolution (CD&R) and self- spacing in the terminal area. Formal analysis of a concept of operations is a novel area of application of formal methods. Here one must establish that a system concept involving aircraft, pilots, and ground resources is safe. The formal analysis of algorithms is a more traditional endeavor. However, the formal analysis of ATM algorithms involves reasoning about the interaction of algorithmic logic and aircraft trajectories defined over an airspace. These trajectories are described using 2D and 3D vectors and are often constrained by trigonometric relations. Thus, in many cases it has been necessary to unload the full power of an advanced theorem prover. The verification challenge is to establish that the safety-critical algorithms produce valid solutions that are guaranteed to maintain separation

  13. Comparison of Experimental and Calculated Ion Mobilities of Small Molecules in Air

    PubMed Central

    2016-01-01

    Ion mobility spectrometry is a well-known technique for analyzing gases. Examples are military applications, but also safety related applications, for example, for protection of employees in industries working with hazardous gases. In the last 15 years, this technique has been further developed as a tool for structural analysis, for example, in pharmaceutical applications. In particular, the collision cross section, which is related to the mobility, is of interest here. With help of theoretic principles, it is possible to develop molecular models that can be verified by the comparison of their calculated cross sections with experimental data. In this paper, it is analyzed how well the ion trajectory method is suitable to reproduce the measured ion mobility of small organic molecules such as the water clusters forming the positively charged reactant ions, simple aromatic substances, and n-alkanes. PMID:27298751

  14. Effects of negative air ions on growth and regeneration in the Indian stick insect

    NASA Astrophysics Data System (ADS)

    Hinsull, S. M.; Evans, G. S.; Bellamy, D.; Head, E. L.

    1983-06-01

    Nymphs of the Indian stick insect Carausius morosus, Brunner were maintained at ambient or 4.2×104 negative ions per c.c. Regenerative processes were initiated in each nymph by stimulation of the leg autotomy reflex. Aspects of growth, the moulting cycles and leg renewal were studied. Few significant weight differences were found between the insects growing in the control and ionized environments. However, the growth curve of the ion treated insects was irregular, unlike that of the control group which increased smoothly. Slight delays in the intermoult period and in the rate of leg regeneration were also noted in those insects exposed to negative ions. Previous workers have shown significant increases in the growth of some insects exposed to negative ions. These new results show no significant effects but suggest growth may be inhibited.

  15. Diagnostics of ion beam generated from a Mather type plasma focus device

    SciTech Connect

    Lim, L. K. Ngoi, S. K. Wong, C. S. Yap, S. L.

    2014-03-05

    Diagnostics of ion beam emission from a 3 kJ Mather-type plasma focus device have been performed for deuterium discharge at low pressure regime. Deuterium plasma focus was found to be optimum at pressure of 0.2 mbar. The energy spectrum and total number of ions per shot from the pulsed ion beam are determined by using biased ion collectors, Faraday cup, and solid state nuclear track detector CR-39. Average energy of the ion beam obtained is about 60 keV. Total number of the ions has been determined to be in the order of 10{sup 11} per shot. Solid state nuclear track detectors (SSNTD) CR39 are employed to measure the particles at all angular direction from end on (0°) to side on (90°). Particle tracks are registered by SSNTD at 30° to 90°, except the one at the end-on 0°.

  16. Helical Explosive Flux Compression Generator Research at the Air Force Research Laboratory

    DTIC Science & Technology

    1999-06-01

    Air Force Research Laboratory Kirtland AFB...ORGANIZATION NAME(S) AND ADDRESS(ES) Directed Energy Directorate, Air Force Research Laboratory Kirtland AFB, NM 8. PERFORMING ORGANIZATION REPORT...in support of the Air Force Research Laboratory ( AFRL ) explosive pulsed power program. These include circuit codes such as Microcap and

  17. Monte Carlo modeling of large-scale ion-conic generation

    NASA Technical Reports Server (NTRS)

    Retterer, J. M.; Chang, T.; Crew, G. B.; Jasperse, J. R.; Winningham, J. D.

    1988-01-01

    Cyclotron resonance with observed electric field fluctuations is demonstrated to be responsible for production of the oxygen ion conics that are observed by the Dynamics Explorer 1 satellite in the central plasma sheet region of the earth's auroral zone. The ion velocity distribution is described by a quasi-linear diffusion equation which is solved using the Monte Carlo technique. The acceleration produced by the observed wave spectrum agrees well with the ion observations, in both form and magnitude.

  18. Ion and electron dynamics generating the Hall current in the exhaust far downstream of the reconnection x-line

    SciTech Connect

    Fujimoto, Keizo; Takamoto, Makoto

    2016-01-15

    We have investigated the ion and electron dynamics generating the Hall current in the reconnection exhaust far downstream of the x-line where the exhaust width is much larger than the ion gyro-radius. A large-scale particle-in-cell simulation shows that most ions are accelerated through the Speiser-type motion in the current sheet formed at the center of the exhaust. The transition layers formed at the exhaust boundary are not identified as slow mode shocks. (The layers satisfy mostly the Rankine-Hugoniot conditions for a slow mode shock, but the energy conversion hardly occurs there.) We find that the ion drift velocity is modified around the layer due to a finite Larmor radius effect. As a result, the ions are accumulated in the downstream side of the layer, so that collimated ion jets are generated. The electrons experience two steps of acceleration in the exhaust. The first is a parallel acceleration due to the out-of-plane electric field E{sub y} which has a parallel component in most area of the exhaust. The second is a perpendicular acceleration due to E{sub y} at the center of the current sheet and the motion is converted to the parallel direction. Because of the second acceleration, the electron outflow velocity becomes almost uniform over the exhaust. The difference in the outflow profile between the ions and electrons results in the Hall current in large area of the exhaust. The present study demonstrates the importance of the kinetic treatments for collisionless magnetic reconnection even far downstream from the x-line.

  19. Role of ion density in growth, transport, and morphology of nanoparticles generated in plasmas

    NASA Astrophysics Data System (ADS)

    Chai, Kil Byoung; Choe, Wonho

    2012-08-01

    Spatial distribution, growth, and morphology of the nanoparticle were investigated in the plasmas with relatively low and high ion densities. Our experimental results reveal that cauliflower-shaped amorphous nanoparticles are dominantly distributed throughout the entire plasma in the low ion density plasma while spherical crystalline particles are spread near the plasma edge in the high ion density plasma. Only agglomeration growth step of the nanoparticles was observed without molecular accretion growth step in the high density plasma. Based on the experimental and numerical results, the role of ion density in the growth mechanism and transport of the nanoparticles is discussed.

  20. Generation of high charge state metal ion beams by electron cyclotron resonance heating of vacuum arc plasma in cusp trap

    SciTech Connect

    Nikolaev, A. G.; Savkin, K. P.; Oks, E. M.; Vizir, A. V.; Yushkov, G. Yu.; Vodopyanov, A. V.; Izotov, I. V.; Mansfeld, D. A.

    2012-02-15

    A method for generating high charge state heavy metal ion beams based on high power microwave heating of vacuum arc plasma confined in a magnetic trap under electron cyclotron resonance conditions has been developed. A feature of the work described here is the use of a cusp magnetic field with inherent ''minimum-B'' structure as the confinement geometry, as opposed to a simple mirror device as we have reported on previously. The cusp configuration has been successfully used for microwave heating of gas discharge plasma and extraction from the plasma of highly charged, high current, gaseous ion beams. Now we use the trap for heavy metal ion beam generation. Two different approaches were used for injecting the vacuum arc metal plasma into the trap - axial injection from a miniature arc source located on-axis near the microwave window, and radial injection from sources mounted radially at the midplane of the trap. Here, we describe preliminary results of heating vacuum arc plasma in a cusp magnetic trap by pulsed (400 {mu}s) high power (up to 100 kW) microwave radiation at 37.5 GHz for the generation of highly charged heavy metal ion beams.

  1. Generation of high charge state metal ion beams by electron cyclotron resonance heating of vacuum arc plasma in cusp trap.

    PubMed

    Nikolaev, A G; Savkin, K P; Oks, E M; Vizir, A V; Yushkov, G Yu; Vodopyanov, A V; Izotov, I V; Mansfeld, D A

    2012-02-01

    A method for generating high charge state heavy metal ion beams based on high power microwave heating of vacuum arc plasma confined in a magnetic trap under electron cyclotron resonance conditions has been developed. A feature of the work described here is the use of a cusp magnetic field with inherent "minimum-B" structure as the confinement geometry, as opposed to a simple mirror device as we have reported on previously. The cusp configuration has been successfully used for microwave heating of gas discharge plasma and extraction from the plasma of highly charged, high current, gaseous ion beams. Now we use the trap for heavy metal ion beam generation. Two different approaches were used for injecting the vacuum arc metal plasma into the trap--axial injection from a miniature arc source located on-axis near the microwave window, and radial injection from sources mounted radially at the midplane of the trap. Here, we describe preliminary results of heating vacuum arc plasma in a cusp magnetic trap by pulsed (400 μs) high power (up to 100 kW) microwave radiation at 37.5 GHz for the generation of highly charged heavy metal ion beams.

  2. Generation of high charge state metal ion beams by electron cyclotron resonance heating of vacuum arc plasma in cusp trapa)

    NASA Astrophysics Data System (ADS)

    Nikolaev, A. G.; Savkin, K. P.; Oks, E. M.; Vizir, A. V.; Yushkov, G. Yu.; Vodopyanov, A. V.; Izotov, I. V.; Mansfeld, D. A.

    2012-02-01

    A method for generating high charge state heavy metal ion beams based on high power microwave heating of vacuum arc plasma confined in a magnetic trap under electron cyclotron resonance conditions has been developed. A feature of the work described here is the use of a cusp magnetic field with inherent "minimum-B" structure as the confinement geometry, as opposed to a simple mirror device as we have reported on previously. The cusp configuration has been successfully used for microwave heating of gas discharge plasma and extraction from the plasma of highly charged, high current, gaseous ion beams. Now we use the trap for heavy metal ion beam generation. Two different approaches were used for injecting the vacuum arc metal plasma into the trap - axial injection from a miniature arc source located on-axis near the microwave window, and radial injection from sources mounted radially at the midplane of the trap. Here, we describe preliminary results of heating vacuum arc plasma in a cusp magnetic trap by pulsed (400 μs) high power (up to 100 kW) microwave radiation at 37.5 GHz for the generation of highly charged heavy metal ion beams.

  3. Study of toroidal flow generation by ion cyclotron range of frequency minority heating in the Alcator C-Mod plasma

    NASA Astrophysics Data System (ADS)

    Murakami, S.; Itoh, K.; Zheng, L. J.; Van Dam, J. W.; Bonoli, P.; Rice, J. E.; Fiore, C. L.; Gao, C.; Fukuyama, A.

    2016-01-01

    The averaged toroidal flow of energetic minority ions during ICRF (ion cyclotron range of frequencies) heating is investigated in the Alcator C-Mod plasma by applying the GNET code, which can solve the drift kinetic equation with complicated orbits of accelerated energetic particles. It is found that a co-directional toroidal flow of the minority ions is generated in the region outside of the resonance location, and that the toroidal velocity reaches more than 40% of the central ion thermal velocity (Vtor ˜ 300 km/s with PICRF ˜ 2 MW). When we shift the resonance location to the outside of |r /a |˜0.5 , the toroidal flow immediately inside of the resonance location is reduced to 0 or changes to the opposite direction, and the toroidal velocity shear is enhanced at r/a ˜ 0.5. A radial diffusion equation for toroidal flow is solved by assuming a torque profile for the minority ion mean flow, and good agreements with experimental radial toroidal flow profiles are obtained. This suggests that the ICRF driven minority ion flow is related to the experimentally observed toroidal rotation during ICRF heating in the Alcator C-Mod plasma.

  4. Inhibition effect of chlorine ion on hydroxyl radical generation in UV-H2O2 process.

    PubMed

    Tsuneda, S; Ishihara, Y; Hamachi, M; Hirata, A

    2002-01-01

    UV-H2O2 process is widely used as an advanced oxidation process (AOP) for the treatment of chlorine volatile organic compounds (CVOCs) such as dichloromethane (DCM) with strong oxidativity of hydroxyl radical generated from photolysis of H2O2. The result of DCM degradation rate at different initial concentrations in UV-H2O2 processes indicated the inhibition effect of produced chlorine ions on DCM oxidation processes, because the first-order degradation rate constant increased with lower initial concentrations. A spin trapping adduct of hydroxyl radical with 5,5-dimethyl-1-pyrroline-n-oxide (DMPO) was quantified by ESR spectrometer after UV irradiation in the presence of different amounts of chlorine ion, and as a result, the chlorine ion was found to act as a hydroxyl radical scavenger, which resulted in decreasing DCM degradation rate. An UV-H2O2 reactor equipped with ion exchangers for removing chlorine ion achieved higher DCM degradation rate than that without ion exchangers.

  5. The costs, air quality, and human health effects of meeting peak electricity demand with installed backup generators.

    PubMed

    Gilmore, Elisabeth A; Lave, Lester B; Adams, Peter J

    2006-11-15

    Existing generators installed for backup during blackouts could be operated during periods of peak electricity demand, increasing grid reliability and supporting electricity delivery. Many generators, however, have non-negligible air emissions and may potentially damage air quality and harm human health. To evaluate using these generators, we compare the levelized private and social (health) costs of diesel internal combustion engines (ICE) with and without diesel particulate filters (DPF), natural gas ICEs, and microturbines to a new peaking plant in New York, NY. To estimate the social cost, first we calculate the upper range emissions for each generator option from producing 36,000 megawatt-hours (MWh) of electricity over 3 days. We then convert the emissions into ambient concentrations with a 3-D chemical transport model, PMCAMx, and Gaussian dispersion plumes. Using a Monte Carlo approach to incorporate the uncertainties, we calculate the health endpoints using concentration-response functions and multiply the response by its economic value. While uncontrolled diesel ICEs would harm air quality and health, a generator with a DPF has a social cost, comparable to natural gas options. We conclude on a full cost basis that backup generators, including controlled diesel ICEs, are a cost-effective method of meeting peak demand.

  6. Wet air oxidation as a pretreatment option for selective biodegradability enhancement and biogas generation potential from complex effluent.

    PubMed

    Padoley, K V; Tembhekar, P D; Saratchandra, T; Pandit, A B; Pandey, R A; Mudliar, S N

    2012-09-01

    This study looks at the possibility of wet air oxidation (WAO) based pretreatment of complex effluent to selectively enhance the biodegradability (without substantial COD destruction) and facilitate biogas generation potential. A lab-scale wet air oxidation reactor with biomethanated distillery wastewater (B-DWW) as a model complex effluent (COD 40,000 mg L(-1)) was used to demonstrate the proof-of-concept. The studies were conducted using a designed set of experiments and reaction temperature (150-200°C), air pressure (6-12 bar) and reaction time (15-120 min) were the main process variables of concern for WAO process optimization. WAO pretreatment of B-DWW enhanced the biodegradability of the complex wastewater by the virtue of enhancing its biodegradability index (BI) from 0.2 to 0.88, which indicate favorable Biochemical Methane Potential (BMP) for biogas generation. The kinetics of COD destruction and BI enhancement has also been reported.

  7. Performance analysis of small capacity liquid nitrogen generator based on Joule-Thomson refrigerator coupled with air separation membrane

    NASA Astrophysics Data System (ADS)

    Piotrowska-Hajnus, Agnieszka; Chorowski, Maciej

    2012-06-01

    Joule - Thomson small capacity refrigerators supplied with gas mixture are studied theoretically and experimentally for a variety of applications. They can be especially promising when coupled with membrane air separators. We present liquid nitrogen generation system based on Joule - Thomson cooler joined with air separation membrane. Hollow fiber membrane is used for nitrogen separation from compressed and purified atmospheric air. Joule-Thomson refrigerator operates with a dedicated nitrogen - hydrocarbons mixture and provides a cooling power used for the separated nitrogen liquefaction. Special attention has been paid to a heat exchanger coupling the Joule- Thomson refrigerator with the membrane air separator. This paper describes the system design, the procedure of its working parameters optimization and tests results.

  8. Three-Centimeter Doppler Radar Observations of Wingtip-Generated Wake Vortices in Clear Air

    NASA Technical Reports Server (NTRS)

    Marshall, Robert E.; Mudukutore, Ashok; Wissel, Vicki L. H.; Myers, Theodore

    1997-01-01

    This report documents a high risk, high pay-off experiment with the objective of detecting, for the first time, the presence of aircraft wake vortices in clear air using X-band Doppler radar. Field experiments were conducted in January 1995 at the Wallops Flight Facility (WFF) to demonstrate the capability of the 9.33 GHz (I=3 cm) radar, which was assembled using an existing nine-meter parabolic antenna reflector at VVTT and the receiver/transmitter from the NASA Airborne Windshear Radar-Program. A C-130-aircraft, equipped with wingtip smoke generators, created visually marked wake vortices, which were recorded by video cameras. A C-band radar also observed the wake vortices during detection attempts with the X-band radar. Rawinsonde data was used to calculate vertical soundings of wake vortex decay time, cross aircraft bearing wind speed, and water vapor mixing ratio for aircraft passes over the radar measurement range. This experiment was a pathfinder in predicting, in real time, the location and persistence of C-130 vortices, and in setting the flight path of the aircraft to optimize X-band radar measurement of the wake vortex core in real time. This experiment was conducted in support of the NASA Aircraft Vortex Spacing System (AVOSS).

  9. New data for aerosols generated by releases of pressurized powders and solutions in static air

    SciTech Connect

    Ballinger, M.Y.; Sutter, S.L.; Hodgson, W.H.

    1987-05-01

    Safety assessments and environmental impact statements for nuclear fuel cycle facilities require an estimate of potential airborne releases. Aerosols generated by accidents are being investigated by Pacific Northwest Laboratory to develop radioactive source-term estimation methods. Experiments measuring the mass airborne and particle size distribution of aerosols produced by pressurized releases were run. Carbon dioxide was used to pressurize uranine solutions to 50, 250, and 500 psig before release. The mass airborne from these experiments was higher than for comparable air-pressurized systems, but not as great as expected based on the amount of gas dissolved in the liquid and the volume of liquid ejected from the release equipment. Flashing sprays of uranine at 60, 125, and 240 psig produced a much larger source term than all other pressurized releases performed under this program. Low-pressure releases of depleted uranium dioxide at 9, 17.5, and 24.5 psig provided data in the energy region between 3-m spills and 50-psig pressurized releases.

  10. An Assessment of Civil Tiltrotor Concept of Operations in the Next Generation Air Transportation System

    NASA Technical Reports Server (NTRS)

    Chung, William W.; Salvano, Dan; Rinehart, David; Young, Ray; Cheng, Victor; Lindsey, James

    2012-01-01

    Based on a previous Civil Tiltrotor (CTR) National Airspace System (NAS) performance analysis study, CTR operations were evaluated over selected routes and terminal airspace configurations assuming noninterference operations (NIO) and runway-independent operations (RIO). This assessment aims to further identify issues associated with these concepts of operations (ConOps), and their dependency on the airspace configuration and interaction with conventional fixed-wing traffic. Safety analysis following a traditional Safety Management System (SMS) methodology was applied to CTR-unique departure and arrival failures in the selected airspace to identify any operational and certification issues. Additional CTR operational cases were then developed to get a broader understanding of issues and gaps that will need to be addressed in future CTR operational studies. Finally, needed enhancements to National Airspace System performance analysis tools were reviewed, and recommendations were made on improvements in these tools that are likely to be required to support future progress toward CTR fleet operations in the Next Generation Air Transportation System (NextGen).

  11. Quantitative Determination of the Breakdown Field of Air from Van de Graaff Generator Discharge

    NASA Astrophysics Data System (ADS)

    Beach, John; Chartrand, Bridget; Gallagher, Hugh

    2016-03-01

    The Van de Graaff generator (VG) is ubiquitous in electrostatic demonstrations because of the large static charge and dramatic sparks produced. We have developed a novel technique for determining the breakdown field of air using the VG. When a spark occurs, the force of attraction between the VG and a discharge sphere suspended above it is measured by a Pasco force sensor. At this time the charge is not symmetric but pulled towards the near side of the spheres by mutual attraction. In order to interpret the measured force in terms of the breakdown field, an accurate model of the charge distribution is needed. Using the method of images for a spherical conductor in an iterative fashion we can provide this model. The electric field in the vicinity of the spheres is then calculated from the charge distribution and its maximum value is the breakdown field. In preliminary work, we determined the breakdown field to be 3.1x106 N/C at 24.9 C and 18% relative humidity. We will report our most recent determination of the breakdown field using this method and discuss the validity of the results in terms of accepted values, experimental limitations and sensitivity to the charge distribution model.

  12. Vertical Navigation Control Laws and Logic for the Next Generation Air Transportation System

    NASA Technical Reports Server (NTRS)

    Hueschen, Richard M.; Khong, Thuan H.

    2013-01-01

    A vertical navigation (VNAV) outer-loop control system was developed to capture and track the vertical path segments of energy-efficient trajectories that are being developed for high-density operations in the evolving Next Generation Air Transportation System (NextGen). The VNAV control system has a speed-on-elevator control mode to pitch the aircraft for tracking a calibrated airspeed (CAS) or Mach number profile and a path control mode for tracking the VNAV altitude profile. Mode control logic was developed for engagement of either the speed or path control modes. The control system will level the aircraft to prevent it from flying through a constraint altitude. A stability analysis was performed that showed that the gain and phase margins of the VNAV control system significantly exceeded the design gain and phase margins. The system performance was assessed using a six-deg-of-freedom non-linear transport aircraft simulation and the performance is illustrated with time-history plots of recorded simulation data.

  13. Measurement of gas-phase ammonia and amines in air by collection onto an ion exchange resin and analysis by ion chromatography

    NASA Astrophysics Data System (ADS)

    Dawson, M. L.; Perraud, V.; Gomez, A.; Arquero, K. D.; Ezell, M. J.; Finlayson-Pitts, B. J.

    2014-02-01

    Ammonia and amines are common trace gases in the atmosphere and have a variety of both biogenic and anthropogenic sources, with a major contribution coming from agricultural sites. In addition to their malodorous nature, both ammonia and amines have been shown to enhance particle formation from acids such as nitric, sulfuric and methanesulfonic acids, which has implications for visibility, human health and climate. A key component of quantifying the effects of these species on particle formation is accurate gas-phase measurements in both laboratory and field studies. However, these species are notoriously difficult to measure as they are readily taken up on surfaces, including onto glass surfaces from aqueous solution as established in the present studies. We describe here a novel technique for measuring gas-phase ammonia and amines that involves uptake onto a weak cation exchange resin followed by extraction and analysis using ion chromatography. Two variants, one for ppb concentrations in air and the second with lower (ppt) detection limits, are described. The latter involves the use of a custom-designed high-pressure cartridge to hold the resin for in-line extraction. These methods avoid the use of sampling lines, which can lead to significant inlet losses of these compounds. They also have the advantages of being relatively simple and inexpensive. The applicability of this technique to ambient air is demonstrated in measurements made near a cattle farm in Chino, CA.

  14. Measurement of gas-phase ammonia and amines in air by collection onto an ion exchange resin and analysis by ion chromatography

    NASA Astrophysics Data System (ADS)

    Dawson, M. L.; Perraud, V.; Gomez, A.; Arquero, K. D.; Ezell, M. J.; Finlayson-Pitts, B. J.

    2014-08-01

    Ammonia and amines are common trace gases in the atmosphere and have a variety of both biogenic and anthropogenic sources, with a major contribution coming from agricultural sites. In addition to their malodorous nature, both ammonia and amines have been shown to enhance particle formation from acids such as nitric, sulfuric and methanesulfonic acids, which has implications for visibility, human health and climate. A key component of quantifying the effects of these species on particle formation is accurate gas-phase measurements in both laboratory and field studies. However, these species are notoriously difficult to measure as they are readily taken up on surfaces, including onto glass surfaces from aqueous solution as established in the present studies. We describe here a novel technique for measuring gas-phase ammonia and amines that involves uptake onto a weak cation exchange resin followed by extraction and analysis using ion chromatography. Two variants - one for parts per billion concentrations in air and the second with lower (parts per trillion) detection limits - are described. The latter involves the use of a custom-designed high-pressure cartridge to hold the resin for in-line extraction. These methods avoid the use of sampling lines, which can lead to significant inlet losses of these compounds. They also have the advantages of being relatively simple and inexpensive. The applicability of this technique to ambient air is demonstrated in measurements made near a cattle farm in Chino, CA.

  15. Efficient GeV ion generation by ultraintense circularly polarized laser pulse

    SciTech Connect

    Zhang Xiaomei; Shen Baifei; Li Xuemei; Jin Zhangying; Wang Fengchao; Wen Meng

    2007-12-15

    The interaction of an ultraintense circularly polarized laser pulse and a solid target is studied by one-dimensional particle-in-cell simulations. Ions at the front of the target are reflected by a moving quasisteady electrostatic field and obtain a relativistic velocity. At a laser intensity of 10{sup 22} W/cm{sup 2}, almost half of the laser energy is transferred to ions and GeV ions are obtained. Effects of laser polarization state and target thickness on the laser energy conversion are investigated. It is found that a circularly polarized laser pulse can accelerate ions more efficiently than a linearly polarized laser pulse at the same laser and target parameters. A monoenergetic ion bunch is obtained for the ultrathin target, which is accelerated as a single entity.

  16. Ion Content of Moist Atmospheric Air and the Molecular Structure of Water Vapor Thus Inferred

    DTIC Science & Technology

    1988-07-01

    Nucleation 04 02 Water VaporP Hydrogen~bonding, Evaporation. 20 05 I Ions , Eletrical Conductivity Infrared.(-R) ASTRACT (Continue on reverse If necessary... eletrical charges are liberated by evaporating water. Fard a! . :;44 that jets of escaping wet steam can produce strong Inc t w n jO 1:o92, Lenard 22...I to the right as the ions are swept away in the vapor, forcing neutral clusters to be dissociated at a faster rate in an attempt to maintain the

  17. An Integrated Microfabricated Chip with Double Functions as an Ion Source and Air Pump Based on LIGA Technology

    PubMed Central

    Li, Hua; Jiang, Linxiu; Guo, Chaoqun; Zhu, Jianmin; Jiang, Yongrong; Chen, Zhencheng

    2017-01-01

    The injection and ionization of volatile organic compounds (VOA) by an integrated chip is experimentally analyzed in this paper. The integrated chip consists of a needle-to-cylinder electrode mounting on the Polymethyl Methacrylate (PMMA) substrate. The needle-to-cylinder electrode is designed and fabricated by Lithographie, Galvanoformung and Abformung (LIGA) technology. In this paper, the needle is connected to a negative power supply of −5 kV and used as the cathode; the cylinder electrodes are composed of two arrays of cylinders and serve as the anode. The ionic wind is produced based on corona and glow discharges of needle-to-cylinder electrodes. The experimental setup is designed to observe the properties of the needle-to-cylinder discharge and prove its functions as an ion source and air pump. In summary, the main results are as follows: (1) the ionic wind velocity produced by the chip is about 0.79 m/s at an applied voltage of −3300 V; (2) acetic acid and ammonia water can be injected through the chip, which is proved by pH test paper; and (3) the current measured by a Faraday cup is about 10 pA for acetic acid and ammonia with an applied voltage of −3185 V. The integrated chip is promising for portable analytical instruments, such as ion mobility spectrometry (IMS), field asymmetric ion mobility spectrometry (FAIMS), and mass spectrometry (MS). PMID:28054980

  18. An Integrated Microfabricated Chip with Double Functions as an Ion Source and Air Pump Based on LIGA Technology.

    PubMed

    Li, Hua; Jiang, Linxiu; Guo, Chaoqun; Zhu, Jianmin; Jiang, Yongrong; Chen, Zhencheng

    2017-01-04

    The injection and ionization of volatile organic compounds (VOA) by an integrated chip is experimentally analyzed in this paper. The integrated chip consists of a needle-to-cylinder electrode mounting on the Polymethyl Methacrylate (PMMA) substrate. The needle-to-cylinder electrode is designed and fabricated by Lithographie, Galvanoformung and Abformung (LIGA) technology. In this paper, the needle is connected to a negative power supply of -5 kV and used as the cathode; the cylinder electrodes are composed of two arrays of cylinders and serve as the anode. The ionic wind is produced based on corona and glow discharges of needle-to-cylinder electrodes. The experimental setup is designed to observe the properties of the needle-to-cylinder discharge and prove its functions as an ion source and air pump. In summary, the main results are as follows: (1) the ionic wind velocity produced by the chip is about 0.79 m/s at an applied voltage of -3300 V; (2) acetic acid and ammonia water can be injected through the chip, which is proved by pH test paper; and (3) the current measured by a Faraday cup is about 10 pA for acetic acid and ammonia with an applied voltage of -3185 V. The integrated chip is promising for portable analytical instruments, such as ion mobility spectrometry (IMS), field asymmetric ion mobility spectrometry (FAIMS), and mass spectrometry (MS).

  19. Generation of coherent ion acoustic solitary waves in inhomogeneous plasmas by an odd eigenmode of electron holes

    NASA Astrophysics Data System (ADS)

    Dokgo, Kyunghwan; Woo, Minho; Choi, Cheong-Rim; Min, Kyoung-Wook; Hwang, Junga

    2016-09-01

    Generation of coherent ion acoustic solitary waves (IASWs) in inhomogeneous plasmas by an odd eigenmode (OEM) of electron holes (EHs) is investigated using 1D electrostatic particle-in-cell (PIC) simulations. The OEM oscillates at a frequency comparable to the trapped electron bouncing frequency, as also demonstrated by Lewis' theoretical formalism about the linear eigenmode in Bernstein-Greene-Kruskal (BGK) equilibrium. The density gradient in the inhomogeneous plasmas causes asymmetry in the EH potential structure associated with the OEM, whose amplitude grows rapidly as it propagates through the density gradient region. As the ions interact with this asymmetric potential, which oscillates slowly enough for the ions to respond, they are ejected to the lower density side with a larger potential amplitude, forming a chain of IASWs coherently with the oscillation of the OEM.

  20. Vertically oriented MoS2 nanoflakes coated on 3D carbon nanotubes for next generation Li-ion batteries.

    PubMed

    Patel, Mumukshu D; Cha, Eunho; Choudhary, Nitin; Kang, Chiwon; Lee, Wonki; Hwang, Jun Yeon; Choi, Wonbong

    2016-12-09

    The advent of advanced electrode materials has led to performance enhancement of traditional lithium ion batteries (LIBs). We present novel binder-free MoS2 coated three-dimensional carbon nanotubes (3D CNTs) as an anode in LIBs. Scanning transmission electron microscopy analysis shows that vertically oriented MoS2 nanoflakes are strongly bonded to CNTs, which provide a high surface area and active electrochemical sites, and enhanced ion conductivity at the interface. The electrochemical performance shows a very high areal capacity of ~1.65 mAh cm(-2) with an areal density of ~0.35 mg cm(-2) at 0.5 C rate and coulombic efficiency of ~99% up to 50 cycles. The unique architecture of 3D CNTs-MoS2 is indicative to be a promising anode for next generation Li-ion batteries with high capacity and long cycle life.

  1. Large diameter permanent-magnets-expanded plasma source for spontaneous generation of low-energy ion beam.

    PubMed

    Takahashi, Kazunori; Suzuki, Tatsuya; Ando, Akira

    2014-02-01

    Diameter of a permanent-magnets-expanded, radiofrequency (rf) plasma source is enlarged up to ∼13 cm for an application to a space propulsion device and tested with being attached to a diffusion chamber. The source is operated at 13.56 MHz 300 W rf power in low-pressure (40 mPa) argon. Measurement of ion energy distribution functions downstream of the source exit shows generation of a supersonic ion beam of about 20 eV. The detailed radial measurements demonstrate that the diameter and energy of the ion beam corresponds to the source tube diameter and the potential difference between the source and downstream plasmas, and that the radial profile of the beam flux is similar to the plasma density profile in the source cavity.

  2. Generation of plane shocks using intense heavy ion beams: Application to Richtmyer-Meshkov instability growth studies

    SciTech Connect

    Tahir, N. A.; Stoehlker, Th.; Shutov, A.; Zharkov, A. P.; Piriz, A. R.

    2011-03-15

    A design of a novel experiment that allows the generation of a well defined, steady, and strong plane shock wave employing an intense uranium ion beam that is incident on a wedge shaped compound target is presented. This technique will open up the possibility of carrying out unique high energy density physics experiments using these shock waves. One such experiment is to study the growth of Richtmyer-Meshkov instability in fluids as well as in solids, both in the linear and nonlinear regimes, as shown by detailed numerical simulations presented in this paper. The ion beam parameters used in this study correspond to those that will be available at the Facility for Antiprotons and Ion Research (FAIR) at Darmstadt.

  3. Vertically oriented MoS2 nanoflakes coated on 3D carbon nanotubes for next generation Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Patel, Mumukshu D.; Cha, Eunho; Choudhary, Nitin; Kang, Chiwon; Lee, Wonki; Hwang, Jun Yeon; Choi, Wonbong

    2016-12-01

    The advent of advanced electrode materials has led to performance enhancement of traditional lithium ion batteries (LIBs). We present novel binder-free MoS2 coated three-dimensional carbon nanotubes (3D CNTs) as an anode in LIBs. Scanning transmission electron microscopy analysis shows that vertically oriented MoS2 nanoflakes are strongly bonded to CNTs, which provide a high surface area and active electrochemical sites, and enhanced ion conductivity at the interface. The electrochemical performance shows a very high areal capacity of ~1.65 mAh cm-2 with an areal density of ~0.35 mg cm-2 at 0.5 C rate and coulombic efficiency of ~99% up to 50 cycles. The unique architecture of 3D CNTs-MoS2 is indicative to be a promising anode for next generation Li-ion batteries with high capacity and long cycle life.

  4. Large diameter permanent-magnets-expanded plasma source for spontaneous generation of low-energy ion beam

    NASA Astrophysics Data System (ADS)

    Takahashi, Kazunori; Suzuki, Tatsuya; Ando, Akira

    2014-02-01

    Diameter of a permanent-magnets-expanded, radiofrequency (rf) plasma source is enlarged up to ˜13 cm for an application to a space propulsion device and tested with being attached to a diffusion chamber. The source is operated at 13.56 MHz 300 W rf power in low-pressure (40 mPa) argon. Measurement of ion energy distribution functions downstream of the source exit shows generation of a supersonic ion beam of about 20 eV. The detailed radial measurements demonstrate that the diameter and energy of the ion beam corresponds to the source tube diameter and the potential difference between the source and downstream plasmas, and that the radial profile of the beam flux is similar to the plasma density profile in the source cavity.

  5. Octave-spanning mid-infrared pulses by plasma generation in air pumped with an Yb:KGW source

    PubMed Central

    Huang, Jinqing; Parobek, Alexander; Ganim, Ziad

    2016-01-01

    Femtosecond mid-infrared (IR) supercontinuum generation in gas media provides a broadband source suited for time-domain spectroscopies and microscopies. This technology has largely utilized <100 fs Ti:sapphire pump lasers. In this Letter, we describe the first plasma generation mid-IR source based on a 1030 nm, 171 fs Yb:KGW laser system; when its first three harmonics are focused in air, a conical mode supercontinuum is generated that spans <1000 to 2700 cm−1 with a 190 pJ pulse energy and 0.5% RMS stability. PMID:27805634

  6. Octave-spanning mid-infrared pulses by plasma generation in air pumped with an Yb:KGW source.

    PubMed

    Huang, Jinqing; Parobek, Alexander; Ganim, Ziad

    2016-11-01

    Femtosecond mid-infrared (IR) supercontinuum generation in gas media provides a broadband source suited for time-domain spectroscopies and microscopies. This technology has largely utilized <100  fs Ti:sapphire pump lasers. In this Letter, we describe the first plasma generation mid-IR source based on a 1030 nm, 171 fs Yb:KGW laser system; when its first three harmonics are focused in air, a conical mode supercontinuum is generated that spans <1000 to 2700  cm-1 with a 190 pJ pulse energy and 0.5% RMS stability.

  7. Diagnosis of high-intensity pulsed heavy ion beam generated by a novel magnetically insulated diode with gas puff plasma gun.

    PubMed

    Ito, H; Miyake, H; Masugata, K

    2008-10-01

    Intense pulsed heavy ion beam is expected to be applied to materials processing including surface modification and ion implantation. For those applications, it is very important to generate high-purity ion beams with various ion species. For this purpose, we have developed a new type of a magnetically insulated ion diode with an active ion source of a gas puff plasma gun. When the ion diode was operated at a diode voltage of about 190 kV, a diode current of about 15 kA, and a pulse duration of about 100 ns, the ion beam with an ion current density of 54 A/cm(2) was obtained at 50 mm downstream from the anode. By evaluating the ion species and the energy spectrum of the ion beam via a Thomson parabola spectrometer, it was confirmed that the ion beam consists of nitrogen ions (N(+) and N(2+)) of energy of 100-400 keV and the proton impurities of energy of 90-200 keV. The purity of the beam was evaluated to be 94%. The high-purity pulsed nitrogen ion beam was successfully obtained by the developed ion diode system.

  8. Impacts of anthropogenic emissions and cold air pools on urban to montane gradients of snowpack ion concentrations in the Wasatch Mountains, Utah

    NASA Astrophysics Data System (ADS)

    Hall, Steven J.; Maurer, Gregory; Hoch, Sebastian W.; Taylor, Raili; Bowling, David R.

    2014-12-01

    Urban montane valleys are often characterized by periodic wintertime temperature inversions (cold air pools) that increase atmospheric particulate matter concentrations, potentially stimulating the deposition of major ions to these snow-covered ecosystems. We assessed spatial and temporal patterns of ion concentrations in snow across urban to montane gradients in Salt Lake City, Utah, USA, and the adjacent Wasatch Mountains during January 2011, a period of several persistent cold air pools. Ion concentrations in fresh snow samples were greatest in urban sites, and were lower by factors of 4-130 in a remote high-elevation montane site. Adjacent undeveloped canyons experienced significant incursions of particulate-rich urban air during stable atmospheric conditions, where snow ion concentrations were lower but not significantly different from urban sites. Surface snow ion concentrations on elevation transects in and adjacent to Salt Lake City varied with temporal and spatial trends in aerosol concentrations, increasing following exposure to particulate-rich air as cold air pools developed, and peaking at intermediate elevations (1500-1600 m above sea level, or 200-300 m above the valley floor). Elevation trends in ion concentrations, especially NH4+ and NO3-, corresponded with patterns of aerosol exposure inferred from laser ceilometer data, suggesting that high particulate matter concentrations stimulated fog or dry ion deposition to snow-covered surfaces at the top of the cold air pools. Fog/dry deposition inputs were similar to wet deposition at mid-elevation montane sites, but appeared negligible at lower and higher-elevation sites. Overall, snow ion concentrations in our urban and adjacent montane sites exceeded many values reported from urban precipitation in North America, and greatly exceeded those reported for remote snowpacks. Sodium, Cl-, NH4+, and NO3- concentrations in fresh snow were high relative to previously measured urban precipitation, with means

  9. Reorientation of the ‘free OH’ group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy

    SciTech Connect

    Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

    2014-09-17

    Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called ‘free O-H’ group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the ‘free O-H’ group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the ‘free O-H’ changes from about 35.3 degrees ± 0.5 degrees to 43.4 degrees ± 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

  10. Pressurized air cathodes for enhanced stability and power generation by microbial fuel cells

    NASA Astrophysics Data System (ADS)

    He, Weihua; Yang, Wulin; Tian, Yushi; Zhu, Xiuping; Liu, Jia; Feng, Yujie; Logan, Bruce E.

    2016-11-01

    Large differences between the water and air pressure in microbial fuel cells (MFCs) can deform and damage cathodes. To avoid deformation, the cathode air pressure was controlled to balance pressure differences between the air and water. Raising the air pressures from 0 to 10 kPa at a set cathode potential of -0.3 V (versus Ag/AgCl) enhanced cathode performance by 17%, but pressures ≥25 kPa decreased current and resulted in air leakage into the solution. Matching the air pressure with the water pressure avoided cathode deformation and improved performance. The maximum power density increased by 15%, from 1070 ± 20 to 1230 ± 70 mW m-2, with balanced air and water pressures of 10-25 kPa. Oxygen partial pressures ≥12.5 kPa in the cathode compartment maintained the oxygen reduction rate to be within 92 ± 1% of that in ambient air. The use of pressurized air flow through the cathode compartments can enable closer spacing of the cathodes compared to passive gas transfer systems, which could make the reactor design more compact. The energy cost of pressurizing the cathodes was estimated to be smaller than the increase in power that resulted from the use of pressurized cathodes.

  11. Perspectives on Li and transition metal fluoride phosphates as cathode materials for a new generation of Li-ion batteries

    PubMed Central

    Antipov, Evgeny V.; Khasanova, Nellie R.; Fedotov, Stanislav S.

    2015-01-01

    To satisfy the needs of rapidly growing applications, Li-ion batteries require further significant improvements of their key properties: specific energy and power, cyclability, safety and costs. The first generation of cathode materials for Li-ion batteries based on mixed oxides with either spinel or rock-salt derivatives has already been widely commercialized, but the potential to improve the performance of these materials further is almost exhausted. Li and transition metal inorganic compounds containing different polyanions are now considered as the most promising cathode materials for the next generation of Li-ion batteries. Further advances in cathode materials are considered to lie in combining different anions [such as (XO4)n− and F−] in the anion sublattice, which is expected to enhance the specific energy and power of these materials. This review focuses on recent advances related to the new class of cathode materials for Li-ion batteries containing phosphate and fluoride anions. Special attention is given to their crystal structures and the relationships between structure and properties, which are important for their possible practical applications. PMID:25610630

  12. Perspectives on Li and transition metal fluoride phosphates as cathode materials for a new generation of Li-ion batteries.

    PubMed

    Antipov, Evgeny V; Khasanova, Nellie R; Fedotov, Stanislav S

    2015-01-01

    To satisfy the needs of rapidly growing applications, Li-ion batteries require further significant improvements of their key properties: specific energy and power, cyclability, safety and costs. The first generation of cathode materials for Li-ion batteries based on mixed oxides with either spinel or rock-salt derivatives has already been widely commercialized, but the potential to improve the performance of these materials further is almost exhausted. Li and transition metal inorganic compounds containing different polyanions are now considered as the most promising cathode materials for the next generation of Li-ion batteries. Further advances in cathode materials are considered to lie in combining different anions [such as (XO4) (n-) and F(-)] in the anion sublattice, which is expected to enhance the specific energy and power of these materials. This review focuses on recent advances related to the new class of cathode materials for Li-ion batteries containing phosphate and fluoride anions. Special attention is given to their crystal structures and the relationships between structure and properties, which are important for their possible practical applications.

  13. Helium ion microscope generated nitrogen-vacancy centres in type Ib diamond

    NASA Astrophysics Data System (ADS)

    McCloskey, D.; Fox, D.; O'Hara, N.; Usov, V.; Scanlan, D.; McEvoy, N.; Duesberg, G. S.; Cross, G. L. W.; Zhang, H. Z.; Donegan, J. F.

    2014-01-01

    We report on position and density control of nitrogen-vacancy (NV) centres created in type Ib diamond using localised exposure from a helium ion microscope and subsequent annealing. Spatial control to <380 nm has been achieved. We show that the fluorescence lifetime of the created centres decreases with increasing ion dose. Furthermore, we show that for doses >1 × 1017 ion/cm2, significant damage of the diamond lattice occurs resulting in fluorescence quenching and amorphization. This places an upper limit on the density of NV centres that can be created using this method.

  14. Generation of superparamagnetism in metallic α-iron by swift heavy ion irradiation

    NASA Astrophysics Data System (ADS)

    Kuzmann, E.; Stichleutner, S.; Homonnay, Z.; Havancsák, K.; Chisholm, C. U.; El-Sharif, M.; Skuratov, V. A.; Nakanishi, A.; Nomura, K.

    2016-10-01

    57Fe conversion electron Mössbauer spectroscopy was used to study the effect of swift heavy ion irradiation on electrochemically deposited metallic pure α-iron. We succeeded in preparing superparamagnetic iron by irradiating the electrochemically prepared thin α-iron films using 247 MeV Kr ions with a fluence of 1×1013 ion cm-2 which converted 50% of crystalline α-iron into amorphous and superparamagnetic phases, the latter being >20%. The results are discussed in terms of the thermal spike model for the formation of the amorphous phase which could be essential for the formation of superparamagnetic iron.

  15. Two-species ion arrays for quantum logic spectroscopy and entanglement generation

    NASA Astrophysics Data System (ADS)

    Hume, David B.

    The quantum states of trapped atomic ions can be highly isolated from external perturbation, and precisely manipulated with applied laser fields. This makes them an excellent medium for quantum-limited experiments such as quantum information processing and precision spectroscopy. A relatively small number of ion species have been used for these types of experiments because most species are difficult to laser cool and detect directly. This thesis demonstrates a way to overcome this limitation by use of sympathetic cooling and state detection based on quantum logic. We apply these techniques to mixed-species arrays of 27Al+ and 9Be + ions. A mathematical model for the motion of such a two-species array is presented in order to explore some features of the ion dynamics that are relevant for the experiments. Repetitive quantum nondemolition measurements of the electronic states of a 27Al+ ion show detection fidelities as high as 99.94%. We also demonstrate the simultaneous detection of two 27Al+ ions and observe a detection fidelity of 99.8%. The basic ideas behind the detection strategy are extended to potentially enable similar experiments on a more general class of atomic and molecular ions. We have also investigated, theoretically and experimentally, a method for preparing entangled Dicke states in trapped atomic ions. We consider a linear chain of N ion qubits that is prepared in a particular Fock state of motion, |m>. The m phonons are removed by applying a laser pulse globally to the N qubits, and converting the motional excitation to m flipped spins. The global nature of this pulse ensures that the m flipped spins are shared by all the target ions in a state that is a close approximation to the Dicke state | DmN >. We calculate numerically the fidelity limits of the protocol and find small deviations from the ideal state for m = 1 and m = 2. We have demonstrated the basic features of this protocol by preparing the Bell state | D1 2 > in two 25Mg+ target ions

  16. Signal generator exciting an electromagnetic field for ion beam transport to the vacuum chamber of a mass spectrometer

    NASA Astrophysics Data System (ADS)

    Tubol'tsev, Yu. V.; Kogan, V. T.; Bogdanov, A. A.; Chichagov, Yu. V.; Antonov, A. S.

    2015-02-01

    A high-voltage high-frequency signal generator is described that excites an electric field for ion beam transport from an ion source to the vacuum chamber of a mass spectrometer. Excitation signals to the number of two are high-frequency sine-wave out-of-phase signals with the same amplitudes. The amplitude and phase of the signals vary from 20 to 100 V and from 10 kHz to 1 MHz, respectively. The generator also produces a controlled bias voltage in the interval 50-200 V. The frequency and amplitude of the signals, as well as the bias voltage, are computer-controlled via the USB interface.

  17. Air blasts generated by rockfall impacts: Analysis of the 1996 Happy Isles event in Yosemite National Park

    USGS Publications Warehouse

    Morrissey, M.M.; Savage, W.Z.; Wieczorek, G.F.

    1999-01-01

    The July 10, 1996, Happy Isles rockfall in Yosemite National Park, California, released 23,000 to 38,000 m3 of granite in four separate events. The impacts of the first two events which involved a 550-m free fall, generated seismic waves and atmospheric pressure waves (air blasts). We focus on the dynamic behavior of the second air blast that downed over 1000 trees, destroyed a bridge, demolished a snack bar, and caused one fatality and several injuries. Calculated velocities for the air blast from a two-phase, finite difference model are compared to velocities estimated from tree damage. From tornadic studies of tree damage, the air blast is estimated to have traveled <108-120 m/s within 50 m from the impact and decreased to <10-20 m/s within 500 m from the impact. The numerical model simulates the two-dimensional propagation of an air blast through a dusty atmosphere with initial conditions defined by the impact velocity and pressure. The impact velocity (105-107 m/s) is estimated from the Colorado Rockfall Simulation Program that simulates rockfall trajectories. The impact pressure (0.5 MPa) is constrained by the kinetic energy of the impact (1010-1012 J) estimated from the seismic energy generated by the impact. Results from the air blast simulations indicate that the second Happy Isles air blast (weak shock wave) traveled with an initial velocity above the local sound speed. The size and location of the first impact are thought to have injected <50 wt % dust into the atmosphere. This amount of dust lowered the local atmospheric sound speed to ???220 m/s. The discrepancy between calculated velocity data and field estimated velocity data (???220 m/s versus ???110 m/s) is attributed to energy dissipated by the downing of trees and additional entrainment of debris into the atmosphere not included in the calculations. Copyright 1999 by the American Geophysical Union.

  18. Air blasts generated by rockfall impacts: Analysis of the 1996 Happy Isles event in Yosemite National Park

    NASA Astrophysics Data System (ADS)

    Morrissey, M. M.; Savage, W. Z.; Wieczorek, G. F.

    1999-10-01

    The July 10, 1996, Happy Isles rockfall in Yosemite National Park, California, released 23,000 to 38,000 m3 of granite in four separate events. The impacts of the first two events which involved a 550-m free fall, generated seismic waves and atmospheric pressure waves (air blasts). We focus on the dynamic behavior of the second air blast that downed over 1000 trees, destroyed a bridge, demolished a snack bar, and caused one fatality and several injuries. Calculated velocities for the air blast from a two-phase, finite difference model are compared to velocities estimated from tree damage. From tornadic studies of tree damage, the air blast is estimated to have traveled <108-120 m/s within 50 m from the impact and decreased to <10-20 m/s within 500 m from the impact. The numerical model simulates the two-dimensional propagation of an air blast through a dusty atmosphere with initial conditions defined by the impact velocity and pressure. The impact velocity (105-107 m/s) is estimated from the Colorado Rockfall Simulation Program that simulates rockfall trajectories. The impact pressure (0.5 MPa) is constrained by the kinetic energy of the impact (1010-1012 J) estimated from the seismic energy generated by the impact. Results from the air blast simulations indicate that the second Happy Isles air blast (weak shock wave) traveled with an initial velocity above the local sound speed. The size and location of the first impact are thought to have injected <50 wt% dust into the atmosphere. This amount of dust lowered the local atmospheric sound speed to ˜220 m/s. The discrepancy between calculated velocity data and field estimated velocity data (˜220 m/s versus ˜110 m/s) is attributed to energy dissipated by the downing of trees and additional entrainment of debris into the atmosphere not included in the calculations.

  19. Generation of metal ions in the beam plasma produced by a forevacuum-pressure electron beam source

    SciTech Connect

    Tyunkov, A. V.; Yushkov, Yu. G. Zolotukhin, D. B.; Klimov, A. S.; Savkin, K. P.

    2014-12-15

    We report on the production of metal ions of magnesium and zinc in the beam plasma formed by a forevacuum-pressure electron source. Magnesium and zinc vapor were generated by electron beam evaporation from a crucible and subsequently ionized by electron impact from the e-beam itself. Both gaseous and metallic plasmas were separately produced and characterized using a modified RGA-100 quadrupole mass-spectrometer. The fractional composition of metal isotopes in the plasma corresponds to their fractional natural abundance.

  20. Proposed double-layer target for the generation of high-quality laser-accelerated ion beams.

    PubMed

    Esirkepov, T Zh; Bulanov, S V; Nishihara, K; Tajima, T; Pegoraro, F; Khoroshkov, V S; Mima, K; Daido, H; Kato, Y; Kitagawa, Y; Nagai, K; Sakabe, S

    2002-10-21

    In order to achieve a high-quality, i.e., monoenergetic, intense ion beam, we propose the use of a double-layer target. The first layer, at the target front, consists of high-Z atoms, while the second (rear) layer is a thin coating of low-Z atoms. The generation of high-quality proton beams from the double-layer target, irradiated by an ultraintense laser pulse, is demonstrated with three-dimensional particle-in-cell simulations.