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Sample records for air mass back-trajectory

  1. A Comparison of Two Methods for Initiating Air Mass Back Trajectories

    NASA Astrophysics Data System (ADS)

    Putman, A.; Posmentier, E. S.; Faiia, A. M.; Sonder, L. J.; Feng, X.

    2014-12-01

    Lagrangian air mass tracking programs in back cast mode are a powerful tool for estimating the water vapor source of precipitation events. The altitudes above the precipitation site where particle's back trajectories begin influences the source estimation. We assume that precipitation comes from water vapor in condensing regions of the air column, so particles are placed in proportion to an estimated condensation profile. We compare two methods for estimating where condensation occurs and the resulting evaporation sites for 63 events at Barrow, AK. The first method (M1) uses measurements from a 35 GHz vertically resolved cloud radar (MMCR), and algorithms developed by Zhao and Garrett1 to calculate precipitation rate. The second method (M2) uses the Global Data Assimilation System reanalysis data in a lofting model. We assess how accurately M2, developed for global coverage, will perform in absence of direct cloud observations. Results from the two methods are statistically similar. The mean particle height estimated by M2 is, on average, 695 m (s.d. = 1800 m) higher than M1. The corresponding average vapor source estimated by M2 is 1.5⁰ (s.d. = 5.4⁰) south of M1. In addition, vapor sources for M2 relative to M1 have ocean surface temperatures averaging 1.1⁰C (s.d. = 3.5⁰C) warmer, and reported ocean surface relative humidities 0.31% (s.d. = 6.1%) drier. All biases except the latter are statistically significant (p = 0.02 for each). Results were skewed by events where M2 estimated very high altitudes of condensation. When M2 produced an average particle height less than 5000 m (89% of events), M2 estimated mean particle heights 76 m (s.d. = 741 m) higher than M1, corresponding to a vapor source 0.54⁰ (s.d. = 4.2⁰) south of M1. The ocean surface at the vapor source was an average of 0.35⁰C (s.d. = 2.35⁰C) warmer and ocean surface relative humidities were 0.02% (s.d. = 5.5%) wetter. None of the biases was statistically significant. If the vapor source

  2. Seasonal variability of tritium and ion concentrations in rain at Kumamoto, Japan and back-trajectory analysis of air mass

    SciTech Connect

    Momoshima, N.; Sugihara, S.; Toyoshima, T.; Nagao, Y.; Takahashi, M.; Nakamura, Y.

    2008-07-15

    Tritium and major ion concentrations in rain were analyzed in Kumamoto (Japan)) between 2001 and 2006 to examine present tritium concentration and seasonal variation. The average tritium concentration was 0.36 {+-} 0.19 Bq/L (n=104) and higher tritium concentrations were observed in spring than the other seasons. Among the ions, non-sea-salt (nss) SO{sub 4}{sup 2}'- showed higher concentration in winter while other ions did not show marked increase in winter. Based on the back-trajectory analyses of air masses, the increase in tritium concentrations in spring arises from downward movement of naturally produced tritium from stratosphere to troposphere, while the increase of the nss-SO{sub 4}{sup 2-} concentrations in winter is due to long range transport of pollutants from China to Japan. (authors)

  3. Identifying tropospheric baseline air masses at Mauna Loa Observatory between 2004 and 2010 using Radon-222 and back trajectories

    NASA Astrophysics Data System (ADS)

    Chambers, Scott D.; Zahorowski, Wlodek; Williams, Alastair G.; Crawford, Jagoda; Griffiths, Alan D.

    2013-01-01

    We use 7 years of hourly radon observations at Mauna Loa Observatory (MLO), together with 10-day back trajectories, to identify baseline air masses at the station. The amplitude of the annual MLO radon cycle, based on monthly means, was 98 mBq m-3 (39 -137 mBq m-3), with maximum values in February (90th percentile 330 mBq m-3) and minimum values in August (10th percentile 8.1 mBq m-3). The composite diurnal radon cycle (amplitude 49 mBq m-3) is discussed with reference to the influences of local flow features affecting the site, and a 3-hour diurnal sampling window (0730-1030 HST) is proposed for observing the least terrestrially influenced tropospheric air masses. A set of 763 baseline events is selected, using the proposed sampling window together with trajectory information, and presented along with measured radon concentrations as a supplement. This data set represents a resource for the selection of baseline events at MLO for use with a range of trace species. A reduced set of 196 "deep baseline" events occurring in the July-September window is also presented and discussed. The distribution (10th/50th/90th percentile) of radon in deep-baseline events (8.7/29.2/66.1 mBq m-3) was considerably lower than that for the overall set of 763 baseline events (12.3/40.8/104.1 mBq m-3). Results from a simple budget calculation, using sonde-derived mixing depths and literature-based estimates of oceanic radon flux and radon concentrations in the marine boundary layer, indicate that the main source of residual radon in the lower troposphere under baseline conditions at MLO is downward mixing from aged terrestrial air masses in the upper troposphere.

  4. Air mass origin signals in δ 18O of tree-ring cellulose revealed by back-trajectory modeling at the monsoonal Tibetan plateau

    NASA Astrophysics Data System (ADS)

    Wernicke, Jakob; Hochreuther, Philipp; Grießinger, Jussi; Zhu, Haifeng; Wang, Lily; Bräuning, Achim

    2016-12-01

    A profound consideration of stable oxygen isotope source water origins is a precondition for an unambiguous palaeoenvironmental interpretation of terrestrial δ 18O archives. To stress the influence of air mass origins on widely used δ 18O tree-ring chronologies, we conducted correlation analyses between six annually resolved δ 18O tree-ring cellulose ( δ ^{18}O_{TC}) chronologies and mean annual air package origins obtained from backward trajectory modeling. This novel approach has been tested for a transect at the southeastern Tibetan plateau (TP), where air masses with different isotopic composition overlap. Detailed examinations of daily precipitation amounts and monthly precipitation δ 18O values ( δ ^{18}OP) were conducted with the ERA Interim and Laboratoire de Météorologie Dynamique General Circulation Model (LMDZiso) data, respectively. Particularly the southernmost study sites are influenced by a distinct amount effect. Here, air package origin δ ^{18}O_{TC} relations are generally weaker in contrast to our northern located study sites. We found that tree-ring isotope signatures at dry sites with less rain days per year tend to be influenced stronger by air mass origin than tree-ring isotope values at semi-humid sites. That implies that the local hydroclimate history inferred from δ ^{18}O_{TC} archives is better recorded at semi-humid sites.

  5. PM2.5 chemical composition at a rural background site in Central Europe, including correlation and air mass back trajectory analysis

    NASA Astrophysics Data System (ADS)

    Schwarz, Jaroslav; Cusack, Michael; Karban, Jindřich; Chalupníčková, Eva; Havránek, Vladimír; Smolík, Jiří; Ždímal, Vladimír

    2016-07-01

    of fresh, local aerosol and aged, long-range transport aerosol. The influences of different air masses were also investigated. The lowest concentrations of PM2.5 were recorded under the influence of marine air masses from the NW, which were also marked by increased concentrations of marine aerosol. In contrast, the highest concentrations of PM2.5 and most major chemical components were measured during periods when continental easterly air masses were dominant.

  6. Tracking hazardous air pollutants from a refinery fire by applying on-line and off-line air monitoring and back trajectory modeling.

    PubMed

    Shie, Ruei-Hao; Chan, Chang-Chuan

    2013-10-15

    The air monitors used by most regulatory authorities are designed to track the daily emissions of conventional pollutants and are not well suited for measuring hazardous air pollutants that are released from accidents such as refinery fires. By applying a wide variety of air-monitoring systems, including on-line Fourier transform infrared spectroscopy, gas chromatography with a flame ionization detector, and off-line gas chromatography-mass spectrometry for measuring hazardous air pollutants during and after a fire at a petrochemical complex in central Taiwan on May 12, 2011, we were able to detect significantly higher levels of combustion-related gaseous and particulate pollutants, refinery-related hydrocarbons, and chlorinated hydrocarbons, such as 1,2-dichloroethane, vinyl chloride monomer, and dichloromethane, inside the complex and 10 km downwind from the fire than those measured during the normal operation periods. Both back trajectories and dispersion models further confirmed that high levels of hazardous air pollutants in the neighboring communities were carried by air mass flown from the 22 plants that were shut down by the fire. This study demonstrates that hazardous air pollutants from industrial accidents can successfully be identified and traced back to their emission sources by applying a timely and comprehensive air-monitoring campaign and back trajectory air flow models.

  7. Cluster analysis of the impact of air back-trajectories on aerosol optical properties at Hornsund, Spitsbergen

    NASA Astrophysics Data System (ADS)

    Rozwadowska, A.; Zieliński, T.; Petelski, T.; Sobolewski, P.

    2010-02-01

    In this paper, spectra of aerosol optical thickness from the AERONET (AErosol RObotic NETwork) station at Hornsund in the southern part of Spitsbergen were employed to study the impact of air mass history on aerosol optical thickness for wavelength λ=500 nm - AOT(500) - and the Ångström exponent. Backward trajectories computed, using the NOAA HYSPLIT model, were used to trace air history. It was found that in spring, the changes in AOT values over the Hornsund station were strongly influenced by air mass trajectories 8 days or longer in duration, arriving both in the free troposphere and at an altitude of 1 km above sea level. Nevertheless, free tropospheric advection was dominant. AOT variability in summer was best explained by the local direction and speed of advection (1-day trajectories) and was dominated by the effectiveness of cleansing processes. During the ASTAR 2007 campaign, the aerosols near Hornsund displayed low AOT values ranging from 0.06 to 0.09, which is lower than the mean AOT(500) for spring seasons from 2005 to 2007 (0.110±0.007; mean ± standard deviation of mean). 9 April 2007 with AOT(500)=0.147 was exceptional. The back-trajectories belonged to clusters with low and average cluster mean AOT. Apart from the maximum AOT of 9 April 2007, the observed AOT values were close to or lower than the means for the clusters to which they belonged.

  8. Seasonal variations and sources study by way of back trajectories and ANOVA for ambient air pollutants (particulates and metallic elements) within a mixed area at Longjing, central Taiwan: 1-year observation.

    PubMed

    Fang, Guor-Cheng; Lo, Chaur-Tsuen; Zhuang, Yuan-Jie; Cho, Meng-Hsien; Huang, Chao-Yang; Xiao, You-Fu; Tsai, Kai-Hsiang

    2017-02-01

    This study measured the concentrations of particulates and metallic elements in ambient air by using PS-1 sampler (TSP) at Longjing area. And this study focuses on the collection of ambient air particulates, metallic elements, particulate-bound mercury Hg(p), concentrations. In addition, the sources of ambient pollutants by way of back trajectory analysis are found. Moreover, test mean concentration variance differences for metallic elements (PM, Hg(p), Mn, Fe, Zn, Cr, Cu, and Pb) among the four seasons (spring, summer, autumn and winter) through ANOVA are calculated. The result indicates that the average highest particulate concentration occurred in winter season, and the order was winter > spring > autumn > summer, and the mostly highest average metallic element (Mn, Fe, Zn, Cr, Cu, Pb) concentrations occurred in autumn. Moreover, the mostly average lowest metallic element concentrations occurred in summer. In addition, the above results of backward trajectories that the major particulate pollutants parcel mainly come from northeastern Taiwan. Moreover, when comparing the results of the first half year to that of the second half year, the they indicated that all metallic elements displayed significant differences in concentrations except those of Hg(p), Mn, Fe, Zn. Finally, metallic element Hg(p) is the only one which showed no significant concentration difference from either seasonal variations or half-year observations.

  9. Back-trajectory Analyses of Water Vapor in Northern Mongolia

    NASA Astrophysics Data System (ADS)

    Koike, Y.; Asanuma, J.

    2012-12-01

    Knowledge of precipitation sources is indispensable for prediction of extreme events as droughts and flood [Dirmeyer and Brubaker, 1999]. In this paper, the transport pathways of water vapor that precipitates in northern Mongolia were identified using back-trajectory analyses in order to find out factors causing such events in arid/semi-arid area. First, a back-trajectory model of atmospheric water vapor was developed. An air parcel is placed on an isentropic plane over the target site at each time of precipitation. Then, back trajectories was calculated with a kinematic method following the implicit technique [Merrill et al., 1986; Merrill, 1989]. Each of the air parcels was tagged with the precipitation time and the altitude, and then tracked back in time for 5 days on the isentropic surface. Japanese 25-year Reanalysis/JMA Climate Data Assimilation System (JRA-25/JCDAS) of Japan Meteorological Agency [Onogi et al., 2007] was used for 3D field of meteorological variables for the calculation. As a validation, the model was compared with two others, namely, Meteorological Data Explorer of the Center for Global Environmental Reserch (METEX/CGER) [Zeng et al., 2003], and the trajectory model of the National Institute of Polar Research (NIPR) [Tomikawa and Sato, 2005]. The comparison found that model results are fairly robust within 5 days from the computational start, i.e., the end of the trajectory, regardless of different datasets and different schemes employed in these models. Then, the back-trajectory model was applied to the observed precipitation at the target site, a surface station in northern Mongolia called Kherlenbayan-Ulaan(KBU), where highly accurate and temporarily dense precipitation measurements are available. Back trajectory lines were calculated for each of the observed precipitation during the warm season of the years 2003 to 2009, on the isentropic surfaces of 300K, 310K and 320K where the highest value of water vapor is observed. The results show

  10. Relationships between submicrometer particulate air pollution and air mass history in Beijing, China, 2004 2006

    NASA Astrophysics Data System (ADS)

    Wehner, B.; Birmili, W.; Ditas, F.; Wu, Z.; Hu, M.; Liu, X.; Mao, J.; Sugimoto, N.; Wiedensohler, A.

    2008-10-01

    The Chinese capital Beijing is one of the global megacities where the effects of rapid economic growth have led to complex air pollution problems that are not well understood. In this study, ambient particle number size distributions in Beijing between 2004 and 2006 are analysed as a function of regional meteorological transport. An essential result is that the particle size distribution in Beijing depends to large extent on the history of the synoptic scale air masses. A first approach based on manual back trajectory classification yielded differences in particulate matter mass concentration by a factor of two between four different air mass categories, including three main wind directions plus the case of stagnant air masses. A back trajectory cluster analysis refined these results, yielding a total of six trajectory clusters. Besides the large scale wind direction, the transportation speed of an air mass was found to play an essential role on the PM concentrations in Beijing. Slow-moving air masses were shown to be associated with an effective accumulation of surface-based anthropogenic emissions due to both, an increased residence time over densely populated land, and their higher degree of vertical stability. For the six back trajectory clusters, differences in PM1 mass concentrations by a factor of 3.5, in the mean air mass speed by a factor of 6, and in atmospheric visibility by a factor of 4 were found. The main conclusion is that the air quality in Beijing is not only degraded by anthropogenic aerosol sources from within the megacity, but also by sources across the entire Northwest China plain depending on the meteorological situation.

  11. Relationships between submicrometer particulate air pollution and air mass history in Beijing, China, 2004-2006

    NASA Astrophysics Data System (ADS)

    Wehner, B.; Birmili, W.; Ditas, F.; Wu, Z.; Hu, M.; Liu, X.; Mao, J.; Sugimoto, N.; Wiedensohler, A.

    2008-06-01

    The Chinese capital Beijing is one of the global megacities where the effects of rapid economic growth have led to complex air pollution problems that are not well understood. In this study, ambient particle number size distributions in Beijing between 2004 and 2006 are analysed as a function of regional meteorological transport. An essential result is that the particle size distribution in Beijing depends to large extent on the history of the synoptic scale air masses. A first approach based on manual back trajectory classification yielded differences in particulate matter mass concentration (PM1 and PM10) by a factor of two between four different air mass categories, including three main wind directions plus the case of stagnant air masses. A back trajectory cluster analysis refined these results, yielding a total of six trajectory clusters. Besides the large scale wind direction, the transportation speed of an air mass was found to play an essential role on the PM concentrations in Beijing. Slow-moving air masses were shown to be associated with an effective accumulation of surface-based anthropogenic emissions due to both, an increased residence time over densely populated land, and their higher degree of vertical stability. For the six back trajectory clusters, differences in PM1 mass concentrations by a factor of 3.5, in the mean air mass speed by a factor of 6, and in atmospheric visibility by a factor of 4 were found. The main conclusion is that the air quality in Beijing is not only degraded by anthropogenic aerosol sources from within the megacity, but also by sources across the entire Northwest China plain depending on the meteorological situation.

  12. Back-trajectory analysis of African dust outbreaks at a coastal city in southern Spain: Selection of starting heights and assessment of African and concurrent Mediterranean contributions

    NASA Astrophysics Data System (ADS)

    Cabello, M.; Orza, J. A. G.; Dueñas, C.; Liger, E.; Gordo, E.; Cañete, S.

    2016-09-01

    The present study uses a back-trajectory analysis at multiple heights for better interpretation of the impact of the African dust outbreaks in the coastal Mediterranean city of Málaga (Spain), the southernmost large city in Europe. Throughout a 3-year period, 363 days were identified as dusty days by atmospheric transport models. During these events, PM10, SO2, O3, temperature, AOD and Ångström exponent showed statistically significant differences compared to days with no African dust. It was found that under African dust events, the study site was influenced by Mediterranean air masses at the lowermost heights and by Atlantic advections at high altitudes, while African air masses mostly reached Málaga at intermediate levels. Specifically, the lowest heights at which air masses reached the study site after having resided over Africa are confined into the 1000-2000 m range. The decoupling between the lowest heights and the ones for dust transport may explain the presence of aged air masses at the time of the African outbreak. Additionally, with the aim of studying the influence of the air mass origin and history on air quality, a new procedure based on Principal component analysis (PCA) is proposed to determine which altitudes are best suited as starting points for back-trajectory calculations, as they maximize the differences in residence time over different areas. Its application to Málaga identifies three altitudes (750, 2250 and 4500 m) and a subsequent analysis of back-trajectories for African dust days provided the main source areas over Africa as well as further insight on the Mediterranean contribution.

  13. Characterizing the Atmospheric Circulation over the Colombian Orinoquia through Lagrangian Back-Trajectory Analysis

    NASA Astrophysics Data System (ADS)

    Orjuela, H. R.; Leon, G. E.; Jimenez-Pizarro, R.

    2012-12-01

    The ongoing transformation of the Colombian Orinoquia (Eastern Plains) due to the rapid expansion of the agricultural frontier and oil production implies a series of new atmospheric emissions, which might negatively impact human health and ecosystems in different ways. Some air pollutants have already been detected in the region. This is the case of Persistent Organic Pollutants (POPs), which are sampled in a site of the Global Atmospheric Passive Sampling (GAPS) network located in Arauca, Colombia. The current understanding on the origin and transport of pollutants is limited due to the lack of information on the atmospheric circulation in the Colombian Orinoquia. This research aims at generating new knowledge on the meteorology of this region mainly for weather forecasting and atmospheric pollution impact assessment. We present a conceptual model of the atmospheric circulation in the Colombian Orinoquia, including the main synoptic and mesoscale factors governing its meteorology. In order to identify the source of air masses and synoptic scale disturbances, we used Lagrangian back trajectories obtained with the model HYSPLIT 4.9 over the period 2000-2010. NCEP/NCAR and Global Data Assimilation System (GDAS) reanalysis results were used as meteorological input to HYSPLIT. Prior to the Lagrangian simulation, these global datasets were evaluated for their capability to reproduce meteorological observations in the region, particularly for rain and flood-triggering conditions. The observational data included satellite images and ground level network measurements by the Colombian Institute of Hydrology, Meteorology and Environmental Research (IDEAM). Windgridds and other data analysis tools were used.

  14. A tracer calibration of back trajectory analysis at the Grand Canyon

    NASA Astrophysics Data System (ADS)

    Vasconcelos, Luis A. de P.; Kahl, Jonathan D. W.; Liu, Desong; Macias, Edward S.; White, Warren H.

    1996-08-01

    The potential of routine back trajectory analyses to locate sources of contaminants in air at Grand Canyon is investigated with data on methylchloroform (CH3CCl3) concentrations collected during the Subregional Cooperative Electric Utility, Department of Defense, National Park Service, and Environmental Protection Agency Study (SCENES). Following a now-standard approach, the distribution of back trajectory segment endpoints over a latitude longitude grid is examined as a function of measured concentrations at the fixed monitoring site. Grid cells in which segment endpoints are preferentially associated with high concentrations are then identified as candidate emissions sources. The method correctly identifies southern California as a source of CH3CCl3. An objective rationale is developed for screening out chance associations, attributable to statistical fluctuations, and the results are evaluated for real and hypothetical tracers with known, simple distributions.

  15. Regional Influences of Marcellus Shale Natural Gas Activity: Back-trajectory Analysis of Baltimore/Washington Ethane Concentrations

    NASA Astrophysics Data System (ADS)

    Vinciguerra, T.; Chittams, A.; Dadzie, J.; Deskins, T.; Goncalves, V.; M'Bagui Matsanga, C.; Zakaria, R.; Ehrman, S.; Dickerson, R. R.

    2015-12-01

    Over the past several years, the combined utilization of hydraulic fracturing and horizontal drilling has led to a rapid increase in natural gas production, especially from the Marcellus Shale. To explore the impact of this activity downwind on regions with no natural gas production, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) Model was used to generate 48-hour back-trajectories for summer, daytime hours from the years 2007-2014 in the Baltimore, MD and Washington, D.C. areas where hourly ethane measurements are available from Photochemical Assessment Monitoring Stations (PAMS). For each of the years investigated, unconventional well counts were obtained for counties in the surrounding states of Pennsylvania, Ohio, West Virginia, and Virginia, and counties exceeding a threshold of 0.05 wells/km2 were designated as counties with a high density of wells. The back-trajectories for each year were separated into two groups: those which passed through counties containing a high density of wells, and those which did not. Back-trajectories passing through high-density counties were further screened by applying a height criterion where trajectories beyond 10% above the mixing layer were excluded. Preliminary results indicate that air parcels with back-trajectories passing within the boundary layer of counties with a high density of unconventional natural gas wells correspond to significantly greater concentrations of observed ethane at these downwind monitors.

  16. Exploring the impacts of land-use change on tropical rainfall using satellite remote sensing and atmospheric back trajectories

    NASA Astrophysics Data System (ADS)

    Spracklen, Dominick; Arnold, Stephen; Taylor, Christopher

    2013-04-01

    Vegetation affects precipitation patterns through altering moisture, energy and trace-gas fluxes between the surface and atmosphere. Here we explore the effect of tropical vegetation and land-use change on precipitation using satellite remote sensed observations of precipitation from the tropical Rainfall Measuring Mission and other satellites combined (TRMM3B42) and leaf area index (LAI) from the Moderate Resolution Imaging Spectroradiometer (MODIS). We combine these observations with a Lagrangian atmospheric transport model which we use to describe daily variability in atmospheric transport patterns. We calculate cumulative exposure of air masses to tropical vegetation and explore relationships between this exposure and observed precipitation. We use remote sensed observations of land-use change that has occurred over recent decades to explore how exposure of air masses to vegetation has changed. We find that for more than 60% of the tropical land surface, air that has experienced a large cumulative exposure to vegetation in the preceding few days produces at least twice as much rain as air that has little exposure to vegetation. To understand potential mechanisms behind this relationship we explore the atmospheric water budget along analysed back trajectories using specific humidity from analysed meteorological fields combined with global land-surface model output of evapotranspiration (ET). We find that ET in air masses with large exposure to vegetation maintains atmospheric moisture sufficiently to explain observed relationships with precipitation. We estimate the impact of 2000-2010 land-use change on the exposure of air masses to vegetation. We focus on regions of rapid-land use change and explore how these changes have altered air mass exposure to vegetation. We attempt to identify locations where large enough changes may have already occurred to allow an observable impact on precipitation. Finally we use a business-as-usual scenario of Amazonian

  17. Low-CCN concentration air masses over the eastern North Atlantic: Seasonality, meteorology, and drivers

    NASA Astrophysics Data System (ADS)

    Wood, Robert; Stemmler, Jayson D.; Rémillard, Jasmine; Jefferson, Anne

    2017-01-01

    A 20 month cloud condensation nucleus concentration (NCCN) data set from Graciosa Island (39°N, 28°W) in the remote North Atlantic is used to characterize air masses with low cloud condensation nuclei (CCN) concentrations. Low-CCN events are defined as 6 h periods with mean NCCN<20 cm-3 (0.1% supersaturation). A total of 47 low-CCN events are identified. Surface, satellite, and reanalysis data are used to explore the meteorological and cloud context for low-CCN air masses. Low-CCN events occur in all seasons, but their frequency was 3 times higher in December-May than during June-November. Composites show that many of the low-CCN events had a common meteorological basis that involves southerly low-level flow and rather low wind speeds at Graciosa. Anomalously low pressure is situated to the west of Graciosa during these events, but back trajectories and lagged SLP composites indicate that low-CCN air masses often originate as cold air outbreaks to the north and west of Graciosa. Low-CCN events were associated with low cloud droplet concentrations (Nd) at Graciosa, but liquid water path (LWP) during low-CCN events was not systematically different from that at other times. Satellite Nd and LWP estimates from MODIS collocated with Lagrangian back trajectories show systematically lower Nd and higher LWP several days prior to arrival at Graciosa, consistent with the hypothesis that observed low-CCN air masses are often formed by coalescence scavenging in thick warm clouds, often in cold air outbreaks.

  18. Retrieval of spatial field of atmospheric aerosol concentration according to data from local measurements: A modification of the method of back trajectory statistics

    NASA Astrophysics Data System (ADS)

    Poddubny, V. A.; Nagovitsyna, E. S.

    2013-07-01

    The well-known method of the back trajectory statistics (BTS) is used to develop a new approach to estimating atmospheric pollution fields according to local measurements. On the basis of instrumental measurements at one or a few monitoring points and information on atmospheric dynamics (in this work, back trajectories of the motion of air particles), the BTS method makes it possible to estimate the spatial structure of fields of a measured quantity. Results from solving a simplified demonstration of estimating the spatial distribution of the volume concentration of a fine aerosol fraction are presented; these results were obtained on the basis of an analysis of photometric measurements in the period of 2004-2010 at six AERO-NET monitoring sites on the territory of Russia: Zvenigorod, Moscow, Yekaterinburg, Tomsk, Yakutsk, and Ussuriisk.

  19. Elemental composition of different air masses over Jeju Island, South Korea

    NASA Astrophysics Data System (ADS)

    Kang, Jeongwon; Choi, Man-Sik; Yi, Hi-Il; Jeong, Kap-Sik; Chae, Jung-Sun; Cheong, Chang-Sik

    2013-03-01

    We investigated the characteristics (concentrations and compositional changes) of atmospheric elements in total suspended particulates through source-receptor relationships using cluster analyses to classify air mass back-trajectories arriving at Gosan, Jeju Island, South Korea, from October 2003 to December 2008. Five trajectory clusters were chosen to explain the transport regimes. Continental outflows of natural and anthropogenic aerosols from Asian dust source regions and eastern China during the colder period could increase element concentrations at Gosan. Elemental levels at Gosan decreased in air masses that passed over marine regions (East China Sea, Pacific Ocean/southern side of Kyushu Island in Japan, and East Sea/southern side of South Korea) during the warmer rainy period due to lower source intensity and dilution by the marine air mass. Anthropogenic pollutants were often major components in air masses passing over marine regions. Air mass characterization by elemental concentration and composition revealed that enrichment by non-sea-salt sulfur in the air mass originated from eastern China, indicative of the main sulfur emitter in northeast Asia. The apportionment of V and Ni by principal component analysis as a marker of heavy oil combustion suggested different residence times and deposition rates from other anthropogenic components in the air. Regionally intermediate concentrations of pollutants were found in the atmosphere over the Korean peninsula.

  20. Sahara's dust transport from Bodele to French Guiana by dust characteristic and Back Trajectories

    NASA Astrophysics Data System (ADS)

    Gobinddass, M.; Molinie, J.; Panechou-Pulcherie, K.; Roussas, A.

    2013-12-01

    Desert dust particles present the ability to be transported over far distances and impact large regions of the earth. Back trajectories analysis and ground validations allow us to approach the dust physical characteristics on a large scale. Here we were interested to the Saharan dust transport event in 2010 to the Amazonian Bassin and in particular French Guiana. The dust particles were collected at ground level and have been analyzed by the SEM. First results point out a valley in a central Region of Bodele in the oldest Tchad's Lake. In fact, diatoms (Bacillariophyta) presence and their particular physical aspect seem to correspond to Bodele Lakes. We compared the ground based results and back trajectories to try to determine the exact origin of these aerosols. The Bodele is known as the major source of dust for Amazonian Bassin, however the back trajectories identified don't really show a departure of the dust from this site. A discussion about links between uplift of the dust and the specific settlement in Africa and resuspension of these particles will be drawn. The few sample of diatome obtained in 2010 will be described and an experiment on Bodele site will be proposed to confirm our hypotesis.

  1. Polycyclic Aromatic Hydrocarbon and Polychlorinated Biphenyl Trends and Source Apportionment in Europe Using Back Trajectories

    NASA Astrophysics Data System (ADS)

    Reimer, E.; Lammel, G.; Jarkovský, J.; Dvorská, A.

    2009-04-01

    Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) are classes of organic substances with most of the individual substances being semivolatile and to some degree resisting degradation in the environment (persistent), hence, undergo long-range transport and reach pristine areas in high altitudes and latitudes. PCBs and even more so PAHs pose significant human health hazards in Europe (WHO, 2003). PAHs are emitted especially in incomplete combustion processes in both the gaseous and particulate phases (sorbed to soot). PCBs have been banned from most uses, such that re-emission and volatilization from old urban and industrial materials are prevailing atmospheric sources. As a consequence of fuel, combustion technology and legislative changes sources are changing in strength, substance pattern, and geographic distribution. Monitoring data in air at a central European continental background station, Košetice, Czech Republic, of 1997-2007 (Holoubek et al., 2007) were used in combination with back-trajectories to localize sources of selected PAHs and PCBs in central, western, eastern and southeastern Europe. The trajectory scheme uses the isentropic coordinate with some diabatic components and a special boundary layer modelling (Reimer & Scherer, 1992). Areal contact matrices over Europe are obtained by integration in time of the contacts of the backward trajectories with the ground (1x1 km2 grid) and weighting by the observed concentrations (or fictive concentrations of factors). Positive matrix factorization (Paatero, 1997) was used to infer the substance patterns of the sources (so-called factors) which most significantly contributed to PAH levels at Košetice and a second site, Leipzig, Germany. The interpretation of the results is based on matrices of transport to up to three receptor sites in central Europe. Potential source distributions are presented and discussed. The analysis of air pollution in Košetice in the periods 1997-99 and

  2. Total-reflection X-ray fluorescence — a tool to obtain information about different air masses and air pollution

    NASA Astrophysics Data System (ADS)

    Schmeling, Martina

    2001-11-01

    Atmospheric aerosols are solid particles dissolved in air and change their chemical composition frequently depending on various parameters. In order to identify regional air circulation atmospheric aerosol filter samples were taken at Loyola University Chicago's Lake Shore Campus during the months of July and August 2000 with sampling times ranging between 1 and 2 h. The samples were digested in a microwave oven and analyzed by total-reflection X-ray fluorescence (TXRF) spectrometry. One diurnal variation comprising five consecutive sampling events was selected and discussed as well as 4 days experiencing different meteorology were compared to exemplify the variation in trace elemental concentration according to air mass movements and highlight the capability of total-reflection X-ray fluorescence analysis. It was found that due to changes in meteorological conditions particularly wind direction and wind speed, trace elemental compositions varied rapidly and could be used to distinguish between 'Lake Michigan air' and 'metropolitan Chicago air' on such short-term time scale like one hour. Back trajectory analysis was applied to support and corroborate the results. The outcome of this study clearly shows that total-reflection X-ray fluorescence is an optimal tool for analysis of atmospheric aerosols.

  3. Application of positive matrix factorization, multi-linear engine and back trajectory techniques to the quantification of coal-fired power station pollution in metropolitan Sydney

    NASA Astrophysics Data System (ADS)

    Cohen, David D.; Crawford, Jagoda; Stelcer, Eduard; Atanacio, Armand J.

    2012-12-01

    Over 900 fine particle Teflon filters were collected within the Sydney Basin between 1 January 2001 and 31 December 2011 and analyzed using simultaneous PIXE, PIGE, RBS and PESA techniques to determine 21 different elements between hydrogen and lead. These elements were used in positive matrix factorization (PMF) and multi-linear engine (ME) techniques together with HYSPLIT wind back trajectory techniques to quantitatively determine source fingerprints and their contributions from coal-fired power stations. The power stations were many kilometers outside the greater Sydney metropolitan area but still had a significant impact on the fine particle mass loadings measured at the sampling site within this metropolitan area. The PM2.5 eleven year average mass at the sampling site was 6.48 μg m-3. The corresponding ammonium sulfate estimate was 1.65 μg m-3 or 26% of the PM2.5 mass. By applying back trajectory data and (ME) analysis methods, two power related fingerprints, secondary sulfate (2ndrySPower) and aged industrial sulfur (IndSagedPower) were determined. These two power related fingerprints were responsible for between 14 and 18% of the total PM2.5 mass and 34-47% of the total sulfate measured at the sampling site. That is on average somewhere between a third and a half of all the sulfate measured in the greater Sydney region could be attributed to coal-fired power station emissions.

  4. Interaction of mid-latitude air masses with the polar dome area during RACEPAC and NETCARE

    NASA Astrophysics Data System (ADS)

    Bozem, Heiko; Hoor, Peter; Koellner, Franziska; Kunkel, Daniel; Schneider, Johannes; Schulz, Christiane; Herber, Andreas; Borrmann, Stephan; Wendisch, Manfred; Ehrlich, Andre; Leaitch, Richard; Willis, Megan; Burkart, Julia; Thomas, Jennie; Abbatt, Jon

    2016-04-01

    We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories as well as Flexpart particle dispersion modeling we analyze the transport regimes of mid-latitude air masses traveling to the high Arctic prevalent during spring (RACEPAC 2014, NETCARE 2015) and summer (NETCARE 2014). In general more northern parts of the high Arctic (Lat > 75°N) were relatively unaffected from mid-latitude air masses. In contrast, regions further south are influenced by air masses from Asia and Russia (eastern part of Canadian Arctic and European Arctic) as well as from North America (central and western parts of Canadian Arctic). The transition between the mostly isolated high Arctic and more southern regions indicated by tracer gradients is remarkably sharp. This allows for a chemical definition of the Polar dome based on the variability of CO and CO2 as a marker. Isentropic surfaces that slope from the surface to higher altitudes in the high Arctic form the polar dome that represents a transport barrier for mid-latitude air masses to enter the lower troposphere in the high Arctic. Synoptic-scale weather systems frequently disturb this transport barrier and foster the exchange between air masses from the mid-latitudes and polar regions. This can finally lead to enhanced pollution levels in the lower polar troposphere. Mid-latitude pollution plumes from biomass burning or flaring entering the polar dome area lead to an enhancement of 30% of the observed CO mixing ratio within the polar dome area.

  5. Biomass Burning versus Fossil Fuel Combustion Signatures of Air Masses Transported from Asia to the U.S. West Coast during ITCT2k2

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Cooper, O.; Warneke, C.; Hudson, P.; Brock, C.; Fehsenfeld, F.; Holloway, J.; Huebler, G.; Murphy, D.; Nowak, J.; Parrish, D.; Ryerson, T.; Trainer, M.; Atlas, E.

    2003-12-01

    The goal of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT2k2) was to study the transport of air pollution from Asia across the Pacific Ocean, and the implications for the background atmospheric composition at the surface in North America. During research flights of the NOAA WP-3 research aircraft on May 5 and 17, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia in the free troposphere to North America. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on May 5, 17 and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) versus propane (C3H8), and the percentage of particles measured by the PALMS (particle analysis by laser mass spectrometry) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast at various latitudes and pressures during the entire ITCT2k2 period, showed that air masses from South-East Asia and China were generally transported at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for South-East Asia. Combined with the origin of the air masses versus altitude determined by the back-trajectories, this explains the measured altitude profiles of the biomass burning indicators.

  6. The impact of air mass advection on aerosol optical properties over Gotland (Baltic Sea)

    NASA Astrophysics Data System (ADS)

    Zdun, Agnieszka; Rozwadowska, Anna; Kratzer, Susanne

    2016-12-01

    In the present paper, measurements of aerosol optical properties from the Gotland station of the AERONET network, combined with a two-stage cluster analysis of back trajectories of air masses moving over Gotland, were used to identify the main paths of air mass advection to the Baltic Sea and to relate them to aerosol optical properties, i.e. the aerosol optical thickness at the wavelength λ = 500 nm, AOT (500) and the Ångström exponent for the spectral range from 440 to 870 nm, α(440,870). One- to six-day long back trajectories ending at 300, 500 and 3000 m above the station were computed using the HYSPLIT model. The study shows that in the Gotland region, variability in aerosol optical thickness AOT(500) is more strongly related to advections in the boundary layer than to those in the free troposphere. The observed variability in AOT(500) was best explained by the advection speeds and directions given by clustering of 4-day backward trajectories of air arriving in the boundary layer at 500 m above the station. 17 clusters of 4-day trajectories arriving at altitude 500 m above the Gotland station (sea level) derived using two-stage cluster analysis differ from each other with respect to trajectory length, the speed of air mass movement and the direction of advection. They also show different cluster means of AOT(500) and α(440,870). The cluster mean AOT(500) ranges from 0.342 ± 0.012 for the continental clusters M2 (east-southeast advection with moderate speed) and 0.294 ± 0.025 for S5 (slow south-southeast advection) to 0.064 ± 0.002 and 0.069 ± 0.002 for the respective marine clusters L3 (fast west-northwest advection) and M3 (north-northwest advection with moderate speed). The cluster mean α(440,870) varies from 1.65-1.70 for the short-trajectory clusters to 0.98 ± 0.03 and 1.06 ± 0.03 for the Arctic marine cluster L4 (fast inflow from the north) and marine cluster L5 (fast inflow from the west) respectively.

  7. The effects of air mass transport, seasonality, and meteorology on pollutant levels at the Iskrba regional background station (1996-2014)

    NASA Astrophysics Data System (ADS)

    Poberžnik, Matevž; Štrumbelj, Erik

    2016-06-01

    Our main goal was to estimate the effects of long-range air transport on pollutant concentrations measured at the Iskrba regional background station (Slovenia). We cluster back-trajectories into categories and simultaneously model the effects of meteorology, seasonality, trends, and air mass trajectory clusters using a Bayesian statistical approach. This simplifies the interpretation of results and allows us to better identify the effects of individual variables, which is important, because pollutant concentrations, meteorology, and trajectories are seasonal and correlated. Similar to related work from other European sites, we find that slow and faster moving trajectories from eastern Europe and the northern part of the Balkan peninsula are associated with higher pollutant levels, while fast-moving trajectories from the Atlantic are associated with lower pollutant concentration. Overall, pollutant concentrations have decreased in the studied period.

  8. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  9. Measurement and analysis of aerosol and black carbon in the southwestern United States and Panama and their dependence on air mass origin

    NASA Astrophysics Data System (ADS)

    Junker, C.; Sheahan, J. N.; Jennings, S. G.; O'Brien, P.; Hinds, B. D.; Martinez-Twary, E.; Hansen, A. D. A.; White, C.; Garvey, D. M.; Pinnick, R. G.

    2004-07-01

    Total aerosol mass loading, aerosol absorption, and black carbon (BC) content were determined from aerosol collected on 598 quartz fiber filters at a remote, semiarid site near Orogrande, New Mexico from December 1989 to October 1995. Aerosol mass was determined by weighing filters before and after exposure, and aerosol absorption was determined by measuring the visible light transmitted through loaded filter samples and converting these measurements to aerosol absorption. BC content was determined by measuring visible light transmitted through filter samples before and after firing and converting the absorption to BC mass, assuming a BC absorption cross section of 19 m2/g in the fiber filter medium. Two analyses were then performed on each of the logged variables: an autoregressive integrating moving average (ARIMA) analysis and a decomposition analysis using an autoregressive model to accommodate first-order autocorrelation. The two analyses reveal that BC mass has no statistically significant seasonal dependence at the 5% level of significance but only random fluctuations varying around an average annual value that has a long-term decreasing trend (from 0.16 to 0.11 μg/m3 during 1990-1995). Aerosol absorption, which is dominated by BC, also displays random fluctuations about an average value, and decreases from 1.9 Mm-1 to 1.3 Mm-1 during the same period. Unlike BC, aerosol mass at the Orogrande site displays distinctly different character. The analyses reveal a pronounced seasonal dependence, but no long-term trend for aerosol mass. The seasonal indices resulting from the autoregression analysis have a minimum in January (-0.78) and maximum in June (+0.58). The geometric mean value over the 1990-1995 period for aerosol mass is 16.0 μg/m3. Since BC aerosol at the Orogrande site is a product of long-range atmospheric transport, a back trajectory analysis of air masses was conducted. Back trajectory analyses indicate that air masses traversing high population

  10. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean.

    PubMed

    Garrison, V H; Majewski, M S; Foreman, W T; Genualdi, S A; Mohammed, A; Massey Simonich, S L

    2014-01-15

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9-126 ng/m(3) (mean = 25 ± 34) at source and 0.05-0.71 ng/m(3) (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1-3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  11. Chemical composition of air masses transported from Asia to the U.S. West Coast during ITCT 2K2: Fossil fuel combustion versus biomass-burning signatures

    NASA Astrophysics Data System (ADS)

    de Gouw, J. A.; Cooper, O. R.; Warneke, C.; Hudson, P. K.; Fehsenfeld, F. C.; Holloway, J. S.; Hübler, G.; Nicks, D. K., Jr.; Nowak, J. B.; Parrish, D. D.; Ryerson, T. B.; Atlas, E. L.; Donnelly, S. G.; Schauffler, S. M.; Stroud, V.; Johnson, K.; Carmichael, G. R.; Streets, D. G.

    2004-12-01

    As part of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT 2K2), a National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft was used to study the long-range transport of Asian air masses toward the west coast of North America. During research flights on 5 and 17 May, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on 5 and 17 May and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) to propane (C3H8), and, on May 5, the percentage of particles measured by the particle analysis by laser mass spectrometry (PALMS) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast over a range of latitudes and altitudes for the entire ITCT 2K2 period, showed that air masses from Southeast Asia and China were generally observed at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for Southeast Asia. Combined with the origin of the air masses versus altitude, this qualitatively explains the increase with altitude, averaged over the whole ITCT 2K2 period, of the different biomass-burning indicators.

  12. Observation of the transport of polluted air masses from the northeastern United States to Cape Sable Island, Nova Scotia, Canada, during the 1993 NARE summer intensive

    NASA Astrophysics Data System (ADS)

    Knapp, K. G.; Balsley, B. B.; Jensen, M. L.; Hanson, H. P.; Birks, J. W.

    1998-06-01

    Vertical profiles of ozone, temperature, pressure, and water vapor mass mixing ratio obtained using a parafoil kite platform during the North Atlantic Regional Experiment (NARE) 1993 summer intensive at Cape Sable Island, Nova Scotia, Canada, demonstrate the of use of kite platforms for the collection of vertically and temporally resolved data over a fixed location. During the period August 8-28, 1993, 39 profiles of the lower atmosphere were collected. Data collected as part of this field campaign illustrate the complex vertical stratification and temporal variability of pollutants transported into the Maritime Provinces of Canada. Transport phenomena resulted in pollution events in which ozone at the ground level remained in the 20-40 parts per billion by volume (ppbv) range, while mixing ratios of 90-130 ppbv were observed above ˜300 m. Back trajectories indicate that these highly elevated levels of ozone are attributable to source regions in the heavily industrialized northeastern United States. Vertical stratification of the lower atmosphere was also present during transport of Canadian air to the sampling site, with layers of both elevated and diminished ozone observed, while marine air did not exhibit layering characteristic of air masses originating from continental source regions.

  13. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean

    USGS Publications Warehouse

    Garrison, Virginia H.; Majewski, Michael S.; Foreman, William T.; Genualdi, Susan A.; Mohammed, Azad; Massey Simonich, Stacy L.

    2014-01-01

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9–126 ng/m3 (mean = 25 ± 34) at source and 0.05–0.71 ng/m3 (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1–3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  14. PMF receptor modelling of fine and coarse PM 10 in air masses governing monsoon conditions in Hanoi, northern Vietnam

    NASA Astrophysics Data System (ADS)

    Hien, P. D.; Bac, V. T.; Thinh, N. T. H.

    Fine and coarse PM 10 samples collected in Hanoi in 1999-2001 were analysed for black carbon (BC) and water soluble ions (WSI) and measured data were disaggregated according to three types of back trajectories, namely (1) northerly, over inland China, (2) northeasterly, over East China Sea and, (3) southwesterly over Indochina peninsula. Trajectories of types 1, 2 and 3 prevail in September/October-December, January-March/April and May-August, respectively. A source-receptor modelling was performed for each type of trajectories individually using the Positive Matrix Factorisation (PMF) technique. Six or seven sources were extracted for each trajectory type, including soil dust, primary and secondary emissions from local burning (LB), vehicle/road dust, sea salt, Cl-depleted marine aerosols and long-range transport (LRT). LRT contributes little to the coarse mass, but accounts for 50%, 34% and 33% of the fine mass in trajectories of types 1, 2 and 3, respectively. More than two-thirds of the fine mode sulphate are attributed to LRT and associated with ammonium. The comparison of LRT and LB source profiles suggests that air masses arriving from north-northeasterly trajectories are more polluted than those coming from the southwest. Therefore the contribution of LRT's aerosols further enhances the seasonal contrast in the particulate concentration with maximum in winter and minimum in summer. Various mechanisms of sulphate formation in LRT and LB were suggested based on the concentration ratios of [SO 42-]/[K +], [SO 42-]/[BC] and [NH 4+]/[SO 42-] for the two sources.

  15. Recent trends of persistent organic pollutants in air in central Europe - Air monitoring in combination with air mass trajectory statistics as a tool to study the effectivity of regional chemical policy

    NASA Astrophysics Data System (ADS)

    Dvorská, A.; Lammel, G.; Holoubek, I.

    We use air mass back trajectory analysis of persistent organic pollutant (POP) levels monitored at a regional background site, Košetice, Czech Republic, as a tool to study the effectiveness of emission reduction measures taken in the last decade in the region. The representativity of the chosen trajectory starting height for air sampling near ground was ensured by excluding trajectories starting at time of inversions lower than their starting height. As the relevant pollutant sources are exclusively located in the atmospheric boundary layer, trajectory segments above this layer were also excluded from the analysis. We used a linear time weight to account for the influence of dispersion and deposition on trace components abundances and to quantify the ground source loading, a continuous measure for the influence of surface emissions. Hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), DDT, and two time periods, the years 1997-1999 and 2004-2006, were studied. The pollutant levels transported to Košetice decreased for all substances except HCB. Except for lindane seasonal emissions were insignificant. Increasing emissions of HCB were at least partly linked to the 2002 floods in the Danube basin. Major emissions of 1997-1999 which decreased significantly were in France (lindane), western Poland, Hungary and northern ex-Yugoslavia (technical HCH), and the Czech Republic (DDT). Emissions remaining in 2004-2006 include HCB and DDT in the northern Czech Republic, HCB and PCBs in Germany. Besides changes in emission strength meteorological factors influence the level of transported pollutant concentrations. The prevailing air flow pattern limits the geographic coverage of this analysis to central Europe and parts of western Europe. However, no POP monitoring stations exist in areas suitable for a possible extension of the study area.

  16. The Effective Mass of a Ball in the Air

    ERIC Educational Resources Information Center

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  17. Evolution of Southern Hemisphere spring air masses observed by HALOE

    NASA Technical Reports Server (NTRS)

    Pierce, R. Bradley; Grose, William L.; Russell, James M., III; Tuck, Adrian F.

    1994-01-01

    The evolution of Southern Hemisphere air masses observed by the Halogen Occultation Experiment (HALOE) during September 21 through October 15, 1992, is investigated using isentropic trajectories computed from United Kingdom Meteorological Office (UKMO) assimilated winds and temperatures. Maps of constituent concentrations are obtained by accumulation of air masses from previous HALOE occultations. Lagged correlations between initial and subsequent HALOE observations of the same air mass are used to validate the air mass trajectories. High correlations are found for lag times as large as 10 days. Frequency distributions of the air mass constituent concentrations are used to examine constituent distributions in and around the Southern Hemisphere polar vortex.

  18. Transport Regimes of Air Masses Affecting the Tropospheric Composition of the Canadian and European Arctic During RACEPAC 2014 and NETCARE 2014/2015

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Hoor, P. M.; Koellner, F.; Kunkel, D.; Schneider, J.; Schulz, C.; Herber, A. B.; Borrmann, S.; Wendisch, M.; Ehrlich, A.; Leaitch, W. R.; Willis, M. D.; Burkart, J.; Thomas, J. L.; Abbatt, J.

    2015-12-01

    The Arctic is warming much faster than any other place in the world and undergoes a rapid change dominated by a changing climate in this region. The impact of polluted air masses traveling to the Arctic from various remote sources significantly contributes to the observed climate change, in contrast there are additional local emission sources contributing to the level of pollutants (trace gases and aerosol). Processes affecting the emission and transport of these pollutants are not well understood and need to be further investigated. We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories we analyze the transport regimes prevalent during spring (RACEPAC 2014 and NETCARE 2015) and summer (NETCARE 2014) in the observed region. Whereas the eastern part of the Canadian Arctic is affected by air masses with their origin in Asia, in the central and western parts of the Canadian and European Arctic air masses from North America are predominant at the time of the measurement. In general the more northern parts of the Arctic were relatively unaffected by pollution from mid-latitudes since air masses mostly travel within the polar dome, being quite isolated. Associated mixing ratios of CO and CO2 fit into the seasonal cycle observed at NOAA ground stations throughout the Arctic, but show a more mid-latitudinal characteristic at higher altitudes. The transition is remarkably sharp and allows for a chemical definition of the polar dome. At low altitudes, synoptic disturbances transport polluted air masses from mid-latitudes into regions of the polar dome. These air masses contribute to the Arctic pollution background, but also

  19. Isentropic analysis of polar cold air mass streams

    NASA Astrophysics Data System (ADS)

    Iwasaki, Toshiki; Kanno, Yuki

    2015-04-01

    1. Introduction A diagnostic method is presented of polar cold air mass streams defined below a threshold potential temperature. The isentropic threshold facilitates a Lagrangian view of the cold air mass streams from diabatic generation to disappearance. 2. Mass-weighted isentropic zonal mean (MIM) cold air streams In winter hemispheres, MIM's mass stream functions show a distinct extratropical direct (ETD) cell in addition to the Hadley cell. The mass stream functions have local maxima at around (280K, 45N) for NH winter and, around (280K, 50S) for SH winter. Thus, =280K may be appropriate to a threshold of the polar cold air mass for both hemispheres. The high-latitude downward motion indicates the diabatic generation of cold air mass, whereas the mid-latitude equatorward flow does its outbreak. The strength of equatorward flow is under significant control of wave-mean flow interactions. 3. Geographical distribution of the cold air mass streams in the NH winter In the NH winter, the polar cold air mass flux has two distinct mainstreams, hereafter called as East Asian (EA) stream and the North American (NA) stream. The former grows over the northern part of the Eurasian continent, turns down southeastward toward East Asia and disappears over the western North Pacific Ocean. The latter grows over the Arctic Ocean, flows toward the East Coast of North America and disappears over the western North Atlantic Ocean. These coincide well with main routes of cold surges. 4. Comparison between NH and SH winter streams The cold air mass streams in NH winter are more asymmetric than those in SH winter. The NH total cold air mass below =280K is about 1.5 times greater than the SH one. These come mainly from the topography and land-sea distribution. The mid-latitude mountains steer the cold air mass streams on the northern sides and enhance the residence time over its genesis region.

  20. Large-scale European source and flow patterns retrieved from back-trajectory interpretations of CO2 at the high alpine research station Jungfraujoch

    NASA Astrophysics Data System (ADS)

    Uglietti, C.; Leuenberger, M.; Brunner, D.

    2011-01-01

    The University of Bern monitors carbon dioxide (CO2) and oxygen (CO2) at the High Altitude Research Station Jungfraujoch since the year 2000 by means of flasks sampling and since 2005 using a continuous in situ measurement system. This study investigates the transport of CO2 and O2 towards Jungfraujoch using backward trajectories to classify the air masses with respect to their CO2 and O2 signatures. By investigating trajectories associated with distinct CO2 concentrations it is possible to decipher different source and sink areas over Europe. The highest CO2 concentrations, for example, were observed in winter during pollution episodes when air was transported from Northeastern Europe towards the Alps, or during south Foehn events with rapid uplift of polluted air from Northern Italy, as demonstrated in two case studies. To study the importance of air-sea exchange for variations in O2 concentrations at Jungfraujoch the correlation between CO2 and APO (Atmospheric Potential Oxygen) deviations from a seasonally varying background was analyzed. Anomalously high APO concentrations were clearly associated with air masses originating from the Atlantic Ocean, whereas low APO concentrations were found in air masses advected either from the east from the Eurasian continent in summer, or from the Eastern Mediterranean in winter. Those air masses with low APO in summer were also strongly depleted in CO2 suggesting a combination of CO2 uptake by vegetation and O2 uptake by dry summer soils. Other clusters of points in the APO-CO2 scatter plot investigated with respect to air mass origin included CO2 and APO background values and points with regular APO but anomalous CO2 concentrations. Background values were associated with free tropospheric air masses with little contact with the boundary layer during the last few days, while high or low CO2 concentrations reflect the various levels of influence of anthropogenic emissions and the biosphere. The pronounced cycles of CO2 and O

  1. Influence of seasonality, air mass origin and particulate matter chemical composition on airborne bacterial community structure in the Po Valley, Italy.

    PubMed

    Innocente, Elena; Squizzato, Stefania; Visin, Flavia; Facca, Chiara; Rampazzo, Giancarlo; Bertolini, Valentina; Gandolfi, Isabella; Franzetti, Andrea; Ambrosini, Roberto; Bestetti, Giuseppina

    2017-03-28

    The integration of chemical and biological data in aerosol studies represents a new challenge in atmospheric science. In this perspective it will be possible to gain a clearer and deeper comprehension of biogeochemical cycles in the atmosphere. In this view, this study aimed to investigate the relationships occurring between bacterial populations and PM chemical composition in one of the most polluted and urbanized areas in Europe: the Po Valley (Italy). Moreover, seasonality, long- and short-range transports were also evaluated to investigate the influence on airborne bacterial communities. PM samples were collected in two cities of the Po Valley (Milan and Venice) characterized by different meteorological conditions and atmospheric pollutant sources. Samples were analysed for water-soluble inorganic ions (WSIIs) and bacterial community structure. Chemical and biological data were jointly processed by using redundancy discriminate analysis (RDA), while the influence of atmospheric circulation was evaluated by using wind ground data and back-trajectories analysis. Results showed strong seasonal shifts of bacterial community structure in both cities, while a different behaviour was observed for air mass circulation at Milan ad Venice sites: long-range transport significantly affected bacterial populations in Milan whereas local ground wind had more influence in the Venice area. Moreover, difference in taxonomic composition can be mostly addressed to the characteristics of sampling sites. This evidence could suggest that, while PM composition is influenced by long-range transport, bacterial populations are affected, besides transport, by other factors (i.e., season and sampling site location). This perspective allow to better understand and explain airborne bacterial community behaviour.

  2. Ions in oceanic and continental air masses

    SciTech Connect

    Tanner, D.J.; Eisele, F.L. )

    1991-01-20

    Measurements of tropospheric ions and several trace atmospheric neutral species have been performed at Cheeka Peak Research Station and at Mauna Loa Observatory. Two new positive ion species at masses 114 and 102 have been identified as protonated caprolactam and a saturated 6-carbon primary amine, respectively. In the negative ion spectrum, methane sulfonic acid (MSA) has been identified as the parent species responsible for an ion commonly observed at mass 95 during these two studies. The diurnal variations of gas phase H{sub 2}SO{sub 4} and MSA were also measured at Cheeka Peak and have typically been found to be present in the sub-ppt range. Ion assisted measurements at Mauna Loa Observatory of pyridine and ammonia indicate concentrations of 2.5 and 70 ppt, respectively, with at least a factor of 2 uncertainty. Interesting variations and potential sources of several of the observed ions are also discussed.

  3. Characterization of Pollution Transport into Texas Using OMI and TES Satellite and In Situ data, and HYSPLIT Back Trajectory Analyses: implications for TCEQ State Implementation Plans and High School/Undergraduate STEM Education

    NASA Astrophysics Data System (ADS)

    Boxe, C.; Bella, D.; Khaimova, J.; Culpepper, J.; Ahmed, N.; Belkalai, A.; Ealy, J.; Arroyo, I.; Lahoumh, M.; Jenkins, O.; Emmanuel, S.; Andrews, J.; Fu, D.; Wu, L.; Choi, Y.; Morris, G.; Osterman, G. B.; Johnson, L. P.; Austin, S. A.

    2014-12-01

    Using an online trajectory analysis tool NASA, ArcGIS, Satellite and EPA in situ data, we assess whether high pollution events in Texas are primarily sourced locally or remotely. We focus satellite data that exemplify high O3 and NO2 over Texas's lower troposphere. Four day back trajectory analyses of all dates show that upper-, mid-, and lower-tropospheric air over Texas, containing high O3, is transported from the Gulf of Mexico, Southeast USA, Midwest USA, Northeast USA, the Atlantic Ocean, Pacific Ocean, Mexico, etc. Only day showed air at 1 km is sourced within Texas. Satellite data show O3 enhancements in the boundary layer and O3 and NO2 enhancements via tropospheric column profiles. These enhancements complement four-day trajectory analysis. This study provides a viable basis for more quantifiable and accurate information for developing effective air quality State Implementation Plans. STEM Impact: (i) D. Bella was an NSF-LSAMP undergraduate research mentee with me at Medgar Evers College-CUNY; she received a B.S. in Environmental Science (and a Chemistry Minor) and is now a Ph.D. graduate student at University at Albany's School of Public Health. (ii) J. Khaimova is an undergraduate Geology and Planetary Science B.S. major at Brooklyn College-CUNY. I have supported Jessica's summer internship in summer 2013 as a CUNY Summer Research Fellow, where she is currently an NSF-REU research mentee at Pennsylvania State University's Meteorology Department. (iii) J. Culpepper received his B.S. in Environmental Science from MEC-CUNY and will be a Ph.D. student, Fall 2014 at University of Iowa's Civil and Environmental Engineering Department. (iv) S. Gentle was a high school researcher with me within ACS's Project SEED Program for high school students. S. Gentle will start her undergraduate career Fall 2014 at Pennsylvania State University and seeks to attain a B.S. in Chemistry. (v). All parties, including high school and undergraduate researchers seek to attend

  4. Where do the air masses between double tropopauses come from?

    NASA Astrophysics Data System (ADS)

    Parracho, A. C.; Marques, C. A. F.; Castanheira, J. M.

    2014-01-01

    An analysis of the origin of air masses that end up between double tropopauses (DT) in the subtropics and midlatitudes is presented. The double tropopauses were diagnosed in the ERA-Interim reanalysis (1979-2010), and the origin of air masses was analysed using the Lagrangian model FLEXPART. Different processes for the formation of double tropopauses (DT) have been suggested in the literature. Some studies have suggested that double tropopauses may occur as a response to the vertical profile of adiabatic heating, due to the residual meridional circulation, while others have put forward contradicting explanations. Whereas some studies have suggested that double tropopauses result from poleward excursions of the tropical tropopause over the extratropical one, others have argued that DTs develop in baroclinic unstable processes involving transport of air from high latitudes. In some regions, the DT structure has a semipermanent character which cannot be explained by excursions of the tropical tropopause alone. However, the results presented in this paper confirm that processes involving excursions of the tropical tropopause over the extratropical tropopause, which are therefore accompanied by intrusions of air from the tropical troposphere into the lower extratropical stratosphere, make a significant contribution for the occurrence of DTs in the subtropics and midlatitudes. Specifically, it is shown that the air between double tropopauses comes from equatorward regions, and has a higher percentage of tropospheric particles and a lower mean potential vorticity.

  5. The mass and speed dependence of meteor air plasma temperatures

    NASA Technical Reports Server (NTRS)

    Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  6. The mass and speed dependence of meteor air plasma temperatures.

    PubMed

    Jenniskens, Peter; Laux, Christophe O; Wilson, Michael A; Schaller, Emily L

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  7. Assessing levels and seasonal variations of current-use pesticides (CUPs) in the Tuscan atmosphere, Italy, using polyurethane foam disks (PUF) passive air samplers.

    PubMed

    Estellano, Victor H; Pozo, Karla; Efstathiou, Christos; Pozo, Katerine; Corsolini, Simonetta; Focardi, Silvano

    2015-10-01

    Polyurethane foam disks (PUF) passive air samplers (PAS) were deployed over 4 sampling periods of 3-5-months (≥ 1 year) at ten urban and rural locations throughout the Tuscany Region. The purpose was to assess the occurrence and seasonal variations of ten current-use pesticides (CUPs). PUF disk extracts were analyzed using GC-MS. The organophosphates insecticides; chlorpyrifos (3-580 pg m(-3)) and chlorpyrifos-methyl (below detection limit - to 570 pg m(-3)) presented the highest levels in air, and showed seasonal fluctuation coinciding with the growing seasons. The relative proportion urban/(urban + rural) ranged from 0.4 to 0.7 showing no differences between urban and rural concentrations. Air back trajectories analysis showed air masses passing over agricultural fields and potentially enhancing the drift of pesticides into the urban sites. This study represents the first information regarding CUPs in the atmosphere of Tuscany region using PAS-PUF disk.

  8. Rural southeast Texas air quality measurements during the 2006 Texas Air Quality Study.

    PubMed

    Schade, Gunnar W; Khan, Siraj; Park, Changhyoun; Boedeker, Ian

    2011-10-01

    The authors conducted air quality measurements of the criteria pollutants carbon monoxide, nitrogen oxides, and ozone together with meteorological measurements at a park site southeast of College Station, TX, during the 2006 Texas Air Quality Study II (TexAQS). Ozone, a primary focus of the measurements, was above 80 ppb during 3 days and above 75 ppb during additional 8 days in summer 2006, suggestive of possible violations of the ozone National Ambient Air Quality Standard (NAAQS) in this area. In concordance with other air quality measurements during the TexAQS II, elevated ozone mixing ratios coincided with northerly flows during days after cold front passages. Ozone background during these days was as high as 80 ppb, whereas southerly air flows generally provided for an ozone background lower than 40 ppb. Back trajectory analysis shows that local ozone mixing ratios can also be strongly affected by the Houston urban pollution plume, leading to late afternoon ozone increases of as high as 50 ppb above background under favorable transport conditions. The trajectory analysis also shows that ozone background increases steadily the longer a southern air mass resides over Texas after entering from the Gulf of Mexico. In light of these and other TexAQS findings, it appears that ozone air quality is affected throughout east Texas by both long-range and regional ozone transport, and that improvements therefore will require at least a regionally oriented instead of the current locally oriented ozone precursor reduction policies.

  9. Spatial and temporal variability in air concentrations of short-chain (C10-C13) and medium-chain (C14-C17) chlorinated n-alkanes measured in the U.K. atmosphere.

    PubMed

    Barber, Jonathan L; Sweetman, Andy J; Thomas, Gareth O; Braekevelt, Eric; Stern, Gary A; Jones, Kevin C

    2005-06-15

    Two studies were carried out on short-chain (C10-C13) and medium-chain (C14-C17) polychlorinated n-alkanes (sPCAs and mPCAs) in U.K. air samples. The first study entailed taking 20 24-h air samples with a pair of Hi-Vol air samplers at the Hazelrigg field station, near Lancaster University. These samples were carefully selected to coincide with times when air masses were predicted to have a fairly constant back trajectory for 24 h and to give a broad spectrum of different origins. The second study was a spatial survey of PCAs in the air at 20 outdoor sites in northern England and four indoor locations in Lancaster, using polyurethane foam (PUF) disk passive air samplers. Levels of the sPCAs in the Hi-Vol samples ranged from <185 to 3430 pg m(-3) (average 1130 pg m(-3)) and were higher than those previously measured at this site in 1997. Levels of the mPCAs ranged from <811 to 14500 pg m(-3) (average 3040 pg m(-3)); that is, they were higher than sPCAs. Both sPCA and mPCA air concentrations are of the same order of magnitude as PAH at this site. Back trajectory analysis showed that the history of the air mass in the 48 h prior to sampling had an important effect on the concentrations observed, with overland samples having higher levels than oceanic, implying that the U.K. is probably responsible for most of the PCAs measured in the U.K. atmosphere. Amounts of both sPCAs and mPCAs in the passive air samples followed a rural-urban gradient. PCAs appear to be released from multiple sources around the country, as a result of the diffusive, open industrial and construction use of the technical mixtures.

  10. Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

    NASA Astrophysics Data System (ADS)

    Dugaria, S.; Moro, L.; Del, D., Col

    2015-11-01

    The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

  11. High-Altitude Air Mass Zero Calibration of Solar Cells

    NASA Technical Reports Server (NTRS)

    Woodyard, James R.; Snyder, David B.

    2005-01-01

    Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

  12. Monitoring Trace Contaminants in Air Via Ion Trap Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Palmer, Peter T.; Karr, Dane; Pearson, Richard; Valero, Gustavo; Wong, Carla

    1995-01-01

    Recent passage of the Clean Air Act with its stricter regulation of toxic gas emissions, and the ever-growing number of applications which require faster turnaround times between sampling and analysis are two major factors which are helping to drive the development of new instrument technologies for in-situ, on-line, real-time monitoring. The ion trap, with its small size, excellent sensitivity, and tandem mass spectrometry capability is a rapidly evolving technology which is well-suited for these applications. In this paper, we describe the use of a commercial ion trap instrument for monitoring trace levels of chlorofluorocarbons (CFCs) and volatile organic compounds (VOCs) in air. A number of sample introduction devices including a direct transfer line interface, short column GC, and a cryotrapping interface are employed to achieve increasing levels of sensitivity. MS, MS/MS, and MS/MS/MS methods are compared to illustrate trade-offs between sensitivity and selectivity. Filtered Noise Field (FNF) technology is found to be an excellent means for achieving lower detection limits through selective storage of the ion(s) of interest during ionization. Figures of merit including typical sample sizes, detection limits, and response times are provided. The results indicate the potential of these techniques for atmospheric assessments, the High Speed Research Program, and advanced life support monitoring applications for NASA.

  13. Air Mass Frequency during Precipitation Events in the United States Northern Plains

    NASA Astrophysics Data System (ADS)

    Loveless, D. M.; Sharr, N. J.; Baum, A.; Contract, J. S.; DePasquale, R.; Godek, M. L.

    2013-12-01

    Since 1980, numerous billion-dollar disasters have affected the Northern Plains of the United States, including nine droughts and four floods. Given the region's large agricultural sector, the ability to accurately forecast the frequency and quantity of precipitation events here is imperative as it has a major impact on the economy of states in the region. The atmospheric environment present during precipitation events can largely be described by the presiding air mass conditions since air masses characterize a multitude of meteorological variables at one time over a large region. Therefore, understanding the relationship between air masses and rainfall episodes can contribute to improved precipitation forecasts. The goal of this research is to add knowledge to current understandings of the factors responsible for precipitation in the Northern Plains through an assessment of synoptic air mass conditions. The Spatial Synoptic Classification is used to categorize 30 years of daily air mass types across the region and daily precipitation is acquired from the United States Historical Climatological Network at stations in close proximity. Air mass frequencies are then analyzed for all regional precipitation events and rainfall categories are developed based on precipitation quantity. Both annual and seasonal air mass frequencies are assessed at the time of precipitation events. Additionally, air mass frequencies are obtained for positive and negative phases of the Pacific/North American Pattern to examine the influence of a teleconnection forcing factor on the air mass types responsible for producing precipitation quantities. Results indicate that the Transitional (TR) air mass, associated with changing air mass conditions commonly related to passing fronts, is not the leading producer of rainfall in the region. The TR is generally responsible for only 10-20% of regional precipitation, which often is classed in a heavy rainfall category. All moist air mass varieties are

  14. A determination of character and frequency changes in air masses using a spatial synoptic classification

    NASA Astrophysics Data System (ADS)

    Kalkstein, Laurence S.; Sheridan, Scott C.; Graybeal, Daniel Y.

    1998-09-01

    Of the numerous climate change studies which have been performed, few of these have analyzed recent trends using an air mass-based approach. The air mass approach is superior to simple trend analysis, as it can identify patterns which may be too subtle to influence the entire climate record. The recently-developed spatial synoptic classification (SSC) is thus used to identify trends over the contiguous United States for summer and winter seasons from 1948 to 1993. Both trends in air mass frequency and character have been assessed.The most noteworthy trend in frequency is a decline in air mass transitional days (TR) during both seasons. In winter, decreases of up to 1% per decade are noted in parts of the central U.S. Other notable trends include a decrease in moist tropical (MT) air in winter, and an increase in MT in summer over the southeastern states.Numerous national and local air mass character changes have been uncovered. A large overall upward trend in cloudiness is noted in summer. All air masses feature an overnight increase, yet afternoon cloudiness increases are generally limited to the three dry air masses. Also in summer, a significant warming and increase in dew point of MT air has occurred at many locales. The most profound winter trend is a large decrease in dew point (up to 1.5°C per decade) in the dry polar (DP) air mass over much of the eastern states.

  15. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    PubMed

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  16. Mathematical modeling of heat exchange between mine air and rock mass during fire

    SciTech Connect

    A.E. Krasnoshtein; B.P. Kazakov; A.V. Shalimov

    2006-05-15

    Solution of problems on heat exchange between ventilating air and rock mass and on gas admixture propagation in mine workings serve as a base for considering changes in heat-gas-air state at a mine after inflammation. The presented mathematical relations allow calculation of a varied velocity and movement direction of air flows, their temperatures and smoking conditions during fire.

  17. Polychlorinated naphthalenes and coplanar polychlorinated biphenyls in arctic air

    SciTech Connect

    Harner, T.; Kylin, H.; Bidleman, T.F.; Barrie, L.A.; Halsall, C.; Strachan, W.M.J.; Fellin, P.

    1998-11-01

    Concentrations of polychlorinated naphthalenes (PCNs) are reported for the first time in arctic air. The data represent combined air samples from the Barents Sea, eastern Arctic Ocean, Norwegian Sea, and two land-based monitoring stations at Alert, Canada, and Dunai Island in eastern Siberia, Russia. Values for {Sigma}PCN were 6--49 for shipboard samples and 0.3--8 for land-based stations and were dominated by the 3-Cl and 4-Cl homologues, which accounted for 90--95% of the total mass. Average values for {Sigma}PCB for the shipboard samples were 126, 24, and 75 for the Barents Sea, eastern Arctic, and Norwegian Sea, respectively. Three-dimensional 5-day air parcel back-trajectories arriving at the ship at 850 and 925 hPa suggested that elevated PCB and PCN concentrations for shipboard samples originated in Europe. Concentrations (fg m{sup {minus}3}) of coplanar PCBs in arctic air were 3--40 (PCB 77) and 0.3--8 (PCB 126) -- about an order of magnitude lower than in urban air. Higher concentrations of PCB 77 and PCB 126, 347 and 5.0 (fg m{sup {minus}3}), respectively, were found in the Barents Sea for two samples with elevated {Sigma}PCBs.

  18. An objective definition of air mass types affecting Athens, Greece; the corresponding atmospheric pressure patterns and air pollution levels.

    PubMed

    Sindosi, O A; Katsoulis, B D; Bartzokas, A

    2003-08-01

    This work aims at defining characteristic air mass types that dominate in the region of Athens, Greece during the cold (November-March) and the warm (May-September) period of the year and also at evaluating the corresponding concentration levels of the main air pollutants. For each air mass type, the mean atmospheric pressure distribution (composite maps) over Europe and the Mediterranean is estimated in order to reveal the association of atmospheric circulation with air pollution levels in Athens. The data basis for this work consists of daily values of thirteen meteorological and six pollutant parameters covering the period 1993-97. The definition of the characteristic air mass types is attempted objectively by using the methods of Factor Analysis and Cluster Analysis. The results show that during the cold period of the year there are six prevailing air mass types (at least 3% of the total number of days) and six infrequent ones. The examination of the corresponding air pollution concentration levels shows that the primary air pollutants appear with increased concentrations when light or southerly winds prevail. This is usually the case when a high pressure system is located over the central Mediterranean or a low pressure system lays over south Italy, respectively. Low levels of the primary pollutants are recorded under northeasterly winds, mainly caused by a high pressure system over Ukraine. During the warm period of the year, the southwestern Asia thermal low and the subtropical anticyclone of the Atlantic Ocean affect Greece. Though these synoptic systems cause almost stagnant conditions, four main air mass types are dominant and ten others, associated with extreme weather, are infrequent. Despite the large amounts of total solar radiation characterizing this period, ozone concentrations remain at low levels in central Athens because of its destruction by nitric oxide.

  19. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  20. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Technical Reports Server (NTRS)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  1. A Study of the Ozone Formation by Ensemble Back Trajectory-process Analysis Using the Eta-CMAQ Forecast Model over the Northeastern U.S. During the 2004 ICARTT Period

    EPA Science Inventory

    The integrated process rates (IPR) estimated by the Eta-CMAQ model at grid cells along the trajectory of the air mass transport path were analyzed to quantitatively investigate the relative importance of physical and chemical processes for O3 formation and evolution ov...

  2. Air quality impact and physicochemical aging of biomass burning aerosols during the 2007 San Diego wildfires.

    PubMed

    Zauscher, Melanie D; Wang, Ying; Moore, Meagan J K; Gaston, Cassandra J; Prather, Kimberly A

    2013-07-16

    Intense wildfires burning >360000 acres in San Diego during October, 2007 provided a unique opportunity to study the impact of wildfires on local air quality and biomass burning aerosol (BBA) aging. The size-resolved mixing state of individual particles was measured in real-time with an aerosol time-of-flight mass spectrometer (ATOFMS) for 10 days after the fires commenced. Particle concentrations were high county-wide due to the wildfires; 84% of 120-400 nm particles by number were identified as BBA, with particles <400 nm contributing to mass concentrations dangerous to public health, up to 148 μg/m(3). Evidence of potassium salts heterogeneously reacting with inorganic acids was observed with continuous high temporal resolution for the first time. Ten distinct chemical types shown as BBA factors were identified through positive matrix factorization coupled to single particle analysis, including particles comprised of potassium chloride and organic nitrogen during the beginning of the wildfires, ammonium nitrate and amines after an increase of relative humidity, and sulfate dominated when the air mass back trajectories passed through the Los Angeles port region. Understanding BBA aging processes and quantifying the size-resolved mass and number concentrations are important in determining the overall impact of wildfires on air quality, health, and climate.

  3. The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

    ERIC Educational Resources Information Center

    Driscoll, John N.; Warneck, Peter

    1973-01-01

    Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

  4. On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Perliski, Lori M.; Solomon, Susan

    1993-01-01

    The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

  5. Experimental Determination of the Mass of Air Molecules from the Law of Atmospheres.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Galvin, Vincent, Jr.

    1979-01-01

    A gas pressure gauge has been constructed for use in a student experiment involving the law of atmospheres. From pressure data obtained at selected elevations the average mass of air molecules is determined and compared to that calculated from the molecular weights and percentages of constituents to the air. (Author/BB)

  6. DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

    EPA Science Inventory

    The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

  7. Aerosol properties and radiative forcing for three air masses transported in Summer 2011 to Sopot, Poland

    NASA Astrophysics Data System (ADS)

    Rozwadowska, Anna; Stachlewska, Iwona S.; Makuch, P.; Markowicz, K. M.; Petelski, T.; Strzałkowska, A.; Zieliński, T.

    2013-05-01

    Properties of atmospheric aerosols and solar radiation reaching the Earth's surface were measured during Summer 2011 in Sopot, Poland. Three cloudless days, characterized by different directions of incoming air-flows, which are typical transport pathways to Sopot, were used to estimate a radiative forcing due to aerosols present in each air mass.

  8. Improving microbial air quality in air-conditioned mass transport buses by opening the bus exhaust ventilation fans.

    PubMed

    Luksamijarulkul, Pipat; Arunchai, Nongphon; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2005-07-01

    The air quality in air-conditioned mass transport buses may affect bus drivers' health. In-bus air quality improvement with the voluntary participation of bus drivers by opening the exhaust ventilation fans in the bus was implemented in the Seventh Bus Zone of Bangkok Mass Transit Authority. Four bus numbers, including bus numbers 16, 63, 67 and 166, were randomly selected to investigate microbial air quality and to observe the effect of opening the exhaust ventilation fans in the bus. With each bus number, 9 to 10 air-conditioned buses (total, 39 air-conditioned buses) were included. In-bus air samples were collected at 5 points in each studied bus using the Millipore Air Tester. A total of 195 air samples were cultured for bacterial and fungal counts. The results reveal that the exhaust ventilation fans of 17 air-conditioned buses (43.6%) were opened to ventilate in-bus air during the cycle of the bus route. The means +/- SD of bacterial counts and fungal counts in the studied buses with opened exhaust ventilation fans (83.8 +/- 70.7 and 38.0 +/- 42.8 cfu/m3) were significantly lower than those in the studied buses without opened exhaust ventilation fans (199.6 +/- 138.8 and 294.1 +/- 178.7 cfu/m3), p < 0.0005. All the air samples collected from the studied buses with opened exhaust ventilation fans were at acceptable levels (< 500 cfu/m3) compared with 4.6% of the air samples collected from the studied buses without opened exhaust ventilation fans, which had high levels (> 500 cfu/m3). Of the studied buses with opened exhaust ventilation fans (17 buses), the bacterial and fungal counts after opening the exhaust ventilation fans (68.3 +/- 33.8 and 28.3 +/- 19.3 cfu/m3) were significantly lower than those before opening the exhaust ventilation fans (158.3 +/- 116.9 and 85.3 +/- 71.2 cfu/m3), p < 0.005.

  9. Erroneous mass transit system and its tended relationship with motor vehicular air pollution (An integrated approach for reduction of urban air pollution in Lahore).

    PubMed

    Aziz, Amer; Bajwa, Ihsan Ullah

    2008-02-01

    Air pollution is threat to the lives of people living in big cities of Pakistan. In Lahore 1,250 people die annually because of air pollution. Mass transit system that can be put forth as solution to urban air pollution is contingent with right choice of system and its affiliation with motorized vehicles and nature of urban air pollution. Existing mass transit system in Lahore due to untrue operation causes surfeit discharge of motor vehicular carbon monoxide. Tended relationships of mass transit system with motorized vehicles and urban air pollution are quite noteworthy. The growing motor vehicles (a consequence of flawed public mass transit system) are potential source of urban air pollution. This paper attempts to highlight correlations and regression curves of existing mass transit system. Further it recommends a two facet approach for reduction of motor vehicular air pollution in Lahore.

  10. Pesticides in western Canadian mountain air and soil.

    PubMed

    Daly, Gillian L; Lei, Ying D; Teixeira, Camilla; Muir, Derek C G; Wania, Frank

    2007-09-01

    The distribution of organochlorine pesticides (OCP; in past and current use) in the mountains of western Canada was determined by sampling air, soil, and lichen along three elevational transects in 2003-2004. Two transects west of the Continental Divide were located in Mount Revelstoke and Yoho National Park, while the Observation Peak transect in Banff National Park is east of the divide. XAD-based passive air samplers, yielding annually averaged air concentrations, were deployed, and soils were collected at all 22 sampling sites, whereas lichen were only sampled in Revelstoke. Back trajectory analysis showed limited air mass transport from the Prairies to the east, but a high frequency of air arriving from the southwest, which includes agricultural regions in British Columbia and Washington State. Endosulfan, dieldrin, and a-hexachlorocyclohexane were the most prevalent OCPs in air and soil; hexachlorobenzene was only abundant in air; chlorothalonil, dacthal, and pentachloronitrobenzene were also consistently present. OCP air concentrations were similar across the three transects, suggesting efficient atmospheric mixing on a local and regional scale. Soil concentrations and soil/air concentration ratios of many OCPs were significantly higher west of the Continental Divide. The soil and lichen concentrations of most OCPs increased with altitude in Revelstoke, and displayed maxima at intermediate elevations at Yoho and Observation Peak. These distribution patterns can be understood as being determined by the balance between atmospheric deposition to, and retention within, the soils. Higher deposition, due to more precipitation falling at lower temperatures, likely occurs west of the divide and at higher elevations. Higher retention, due to higher soil organic matter content, is believed to occur in soils below the tree line. Highest pesticide concentrations are thus found intemperate mountain soils that are rich in organic matter and receive large amounts of cold

  11. Monolithic mass sensor fabricated using a conventional technology with attogram resolution in air conditions

    NASA Astrophysics Data System (ADS)

    Verd, J.; Uranga, A.; Abadal, G.; Teva, J.; Torres, F.; Pérez-Murano, F.; Fraxedas, J.; Esteve, J.; Barniol, N.

    2007-07-01

    Monolithic mass sensors for ultrasensitive mass detection in air conditions have been fabricated using a conventional 0.35μm complementary metal-oxide-semiconductor (CMOS) process. The mass sensors are based on electrostatically excited submicrometer scale cantilevers integrated with CMOS electronics. The devices have been calibrated obtaining an experimental sensitivity of 6×10-11g/cm2Hz equivalent to 0.9ag/Hz for locally deposited mass. Results from time-resolved mass measurements are also presented. An evaluation of the mass resolution have been performed obtaining a value of 2.4×10-17g in air conditions, resulting in an improvement of these devices from previous works in terms of sensitivity, resolution, and fabrication process complexity.

  12. Peroxy radicals and ozone photochemistry in air masses undergoing long-range transport

    NASA Astrophysics Data System (ADS)

    Parker, A. E.; Monks, P. S.; Jacob, M. J.; Penkett, S. A.; Lewis, A. C.; Stewart, D. J.; Whalley, L. K.; Methven, J.; Stohl, A.

    2009-09-01

    Concentrations of peroxy radicals (HO2+ΣiRiO2) in addition to other trace gases were measured onboard the UK Meteorological Office/Natural Environment Research Council British Aerospace 146-300 atmospheric research aircraft during the Intercontinental Transport of Ozone and Precursors (ITOP) campaign based at Horta Airport, Faial, Azores (38.58° N, 28.72° W) in July/August 2004. The overall peroxy radical altitude profile displays an increase with altitude that is likely to have been impacted by the effects of long-range transport. The peroxy radical altitude profile for air classified as of marine origin shows no discernable altitude profile. A range of air-masses were intercepted with varying source signatures, including those with aged American and Asian signatures, air-masses of biomass burning origin, and those that originated from the east coast of the United States. Enhanced peroxy radical concentrations have been observed within this range of air-masses indicating that long-range transported air-masses traversing the Atlantic show significant photochemical activity. The net ozone production at clear sky limit is in general negative, and as such the summer mid-Atlantic troposphere is at limit net ozone destructive. However, there is clear evidence of positive ozone production even at clear sky limit within air masses undergoing long-range transport, and during ITOP especially between 5 and 5.5 km, which in the main corresponds to a flight that extensively sampled air with a biomass burning signature. Ozone production was NOx limited throughout ITOP, as evidenced by a good correlation (r2=0.72) between P(O3) and NO. Strong positive net ozone production has also been seen in varying source signature air-masses undergoing long-range transport, including but not limited to low-level export events, and export from the east coast of the United States.

  13. A Synoptic Air Mass Approach to Defining Southwest U.S. Summer Duration and Change

    NASA Astrophysics Data System (ADS)

    Morrill, C.; Wachtel, C. J.; Godek, M. L.

    2015-12-01

    As the past decade was the warmest in the 110-year active record, and future Southwest warming is expected to be most intense in the summer season, it is important to have an updated atmospheric definition of what constitutes a Southwest summer. This is particularly true given the intensity of current drought conditions and that summers may be changing. Using weather-type data from the Spatial Synoptic Classification, this research aims to synoptically define the summer season in the Southwest since 1950. The Southwest is spatially described here by sub-region and 28 air mass stations within are chosen for air mass analysis. Daily air mass frequencies are examined to determine the dominant and less prevalent types annually and seasonally, from May to September. Then, frequencies in the middle of summer are compared to those in the seasonal fringe months to explore the possibility of a synoptic shift in the timing of the region's summer season. Finally, to further scrutinize how regional air mass frequencies have changed with time, the data are subdivided and evaluated for the 'Early record' (years prior to 1975) and 'Modern record' (post 1975). Frequency departures are tested for practical and statistical significance to characterize the strength of summer season variability. Results indicate that Dry Moderate air masses are the most common annually and in summer. Moist and transitional air masses tend to less frequent throughout the Southwest; however, frequencies vary greatly by sub-region. Wet and dry conditions are observed in accordance with the monsoon in some sub-regions, but not throughout the region. Significant changes in sub-regional air mass tendencies are identified that show the Early record experienced cooler air mass conditions (fewer tropical types and more moderate and cool types) than the Modern record. From a long-term synoptic air mass perspective, typical Southwest summers likely last from May to August. However, in the Modern record May

  14. Analysis of major air pollutants and submicron particles in New York City and Long Island

    NASA Astrophysics Data System (ADS)

    Masiol, M.; Hopke, P. K.; Felton, H. D.; Frank, B. P.; Rattigan, O. V.; Wurth, M. J.; LaDuke, G. H.

    2017-01-01

    A year-long sampling campaign of major air pollutants and submicron particle number size distributions was conducted at two sites taken as representative of city-wide air quality in New York City and Long Island, respectively. A number of species were quantified with hourly time resolution, including particle number concentrations in 6 size ranges (20-30 nm, 30-50 nm, 50-70 nm, 70-100 nm, 100-200 nm, and >200 nm), nitrogen oxides, sulfur dioxide, ozone, carbon monoxide, methane, non-methane hydrocarbons, PM2.5 mass concentration and some PM major components (sulfate, organic and elemental carbon). Hourly concentrations of primary and secondary organic carbon were estimated using the EC tracer method. Data were matched with weather parameters and air parcel back-trajectories. A series of tools were thus applied to: (i) study the seasonal, weekly, diurnal cycles of pollutants; (ii) investigate the relationships amongst pollutants through correlation and lagged correlation analyses; (iii) depict the role of atmospheric photochemical processes; (iv) examine the location of the potential sources by mean of conditional bivariate probability function analysis and (v) investigate the role of regional transport of air masses to the concentrations of analyzed species. Results indicate that concentrations of NOx, SO2, CO, non-methane hydrocarbons, primary OC and EC are predominantly determined by local sources, but are also affected by regional transports of polluted air masses. On the contrary, the transport of continental polluted air masses has a main effect in raising the concentrations of secondary PM2.5 (sulfate and secondary organic carbon). By providing direct information on the concentrations and trends of key pollutants and submicron particle number concentrations, this study finally enables some general considerations about air quality status and atmospheric processes over the New York City metropolitan area.

  15. Thin-Film Air-Mass-Flow Sensor of Improved Design Developed

    NASA Technical Reports Server (NTRS)

    Fralick, Gustave C.; Wrbanek, John D.; Hwang, Danny P.

    2003-01-01

    Researchers at the NASA Glenn Research Center have developed a new air-mass-flow sensor to solve the problems of existing mass flow sensor designs. NASA's design consists of thin-film resistors in a Wheatstone bridge arrangement. The resistors are fabricated on a thin, constant-thickness airfoil to minimize disturbance to the airflow being measured. The following photograph shows one of NASA s prototype sensors. In comparison to other air-mass-flow sensor designs, NASA s thin-film sensor is much more robust than hot wires, causes less airflow disturbance than pitot tubes, is more accurate than vane anemometers, and is much simpler to operate than thermocouple rakes. NASA s thin-film air-mass-flow sensor works by converting the temperature difference seen at each leg of the thin-film Wheatstone bridge into a mass-flow rate. The following figure shows a schematic of this sensor with air flowing around it. The sensor operates as follows: current is applied to the bridge, which increases its temperature. If there is no flow, all the arms are heated equally, the bridge remains in balance, and there is no signal. If there is flow, the air passing over the upstream legs of the bridge reduces the temperature of the upstream legs and that leads to reduced electrical resistance for those legs. After the air has picked up heat from the upstream legs, it continues and passes over the downstream legs of the bridge. The heated air raises the temperature of these legs, increasing their electrical resistance. The resistance difference between the upstream and downstream legs unbalances the bridge, causing a voltage difference that can be amplified and calibrated to the airflow rate. Separate sensors mounted on the airfoil measure the temperature of the airflow, which is used to complete the calculation for the mass of air passing by the sensor. A current application for air-mass-flow sensors is as part of the intake system for an internal combustion engine. A mass-flow sensor is

  16. Passive air sampling of organochlorine pesticides in a northeastern state of India, Manipur.

    PubMed

    Devi, Ningombam Linthoingambi; Qi, Shihua; Chakraborty, Paromita; Zhang, Gan; Yadav, Ishwar Chandra

    2011-01-01

    Thirty-six polyurethane foam disk passive air samplers (PUF-PAS) were deployed over a year during January to December, 2009 at three locations, i.e., Imphal (urban site), Thoubal (rural site) and Waithou (alpine site) of Manipur, to assess the seasonal local atmospheric emission of selected organochlorine pesticides (OCPs). The average concentration of HCHs monitored at mountain site during hot season (Mar, Apr, and May) and rainy seasons (Jun, Jul, Aug, and Sep) were 403 and 349 pg/m3, respectively. DDTs had a high concentration with 384 pg/m3 at rural site and 379 pg/m3 at urban site during hot seasons. Endosulfans and chlordane were found high in concentration during hot seasons (260 pg/m3) and low during retreating monsoon seasons (44 pg/m3) at rural site. Most of the OCPs concentrations were high during cultivation period. The OCP concentrations of rainy season were highly correlated (p < 0.01) with OCPs of hot seasons. Further, positive correlation (p < 0.05) was also obtained between cold seasons and retreating monsoon. Principal component analysis showed a significant correlation among the four seasons and distribution pattern of OCPs in air. Back trajectory analysis by using HYPSLIT model showed a long range air transport of OCPs to the present study area. Present OCP levels at Manipur is an outcome of both local emission and also movement of air mass by long range atmospheric transport.

  17. The Use of Red Green Blue (RGB) Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Zavodsky, Bradley; Molthan, Andrew; Jedlovec, Gary

    2013-01-01

    AIRS ozone and model PV analysis confirm the stratospheric air in RGB Air Mass imagery. Trajectories confirm winds south of the low were distinct from CCB driven winds. Cross sections connect the tropopause fold, downward motion, and high nearsurface winds. Comparison to conceptual models show Shapiro-Keyser features and sting jet characteristics were observed in a storm that impacted the U.S. East Coast. RGB Air Mass imagery can be used to identify stratospheric air and regions susceptible to tropopause folding and attendant non-convective winds.

  18. Technical note: Air compared to nitrogen as nebulizing and drying gases for electrospray ionization mass spectrometry.

    PubMed

    Mielczarek, P; Silberring, J; Smoluch, M

    2016-01-01

    In the present study we tested the application of compressed air instead of pure nitrogen as the nebulizing and drying gas, and its influence on the quality of electrospray ionization (ESI) mass spectra. The intensities of the signals corresponding to protonated molecules were significantly (twice) higher when air was used. Inspection of signal-to-noise (S/N) ratios revealed that, in both cases, sensitivity was comparable. A higher ion abundance after the application of compressed air was followed by a higher background. Another potential risk of using air in the ESI source is the possibility for sample oxidation due to the presence of oxygen. To test this, we selected five easily oxidizing compounds to verify their susceptibility to oxidation. In particular, the presence of methionine was of interest. For all the compounds studied, no oxidation was observed. Amodiaquine oxidizes spontaneously in water solutions and its oxidized form can be detected a few hours after preparation. Direct comparison of the spectra where nitrogen was used with the corresponding spectra obtained when air was applied did not show significant differences. The only distinction was slightly different patterns of adducts when air was used. The difference concerns acetonitrile, which forms higher signals when air is the nebulizing gas. It is also important that the replacement of nitrogen with air does not affect quantitative data. The prepared calibration curves also visualize an intensity twice as high (independent of concentration within tested range) of the signal where air was applied. We have used our system continuously for three months with air as the nebulizing and drying gas and have not noticed any unexpected signal deterioration caused by additional source contamination from the air. Moreover, compressed air is much cheaper and easily available using oil-free compressors or pumps.

  19. Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

    PubMed

    Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

    2007-10-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented.

  20. Detection of Hydrazine in Air Using Electron Transfer Ionization Mass Spectrometry.

    DTIC Science & Technology

    1981-02-15

    is in tI qualitative agreement with American Petroleum Institute (API) 6 data. Unequivocal identification and monitoring of N2H4 fuels at the launch...N2H4 in air. At even lower concentrations, the delay time 61ndex of Mass Spectral Data, American Petroleum Institute , Research Project 44, NBS

  1. Toward a better understanding of the impact of mass transit air pollutants on human health

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Modern mass transit systems, based on roads, rail, water, and air, generate toxic airborne pollutants throughout the developed world. This has become one of the leading concerns about the use of modern transportation, particularly in densely-populated urban areas where their use is enormous and inc...

  2. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general.

  3. Turbulent heat and mass transfers across a thermally stratified air-water interface

    NASA Technical Reports Server (NTRS)

    Papadimitrakis, Y. A.; Hsu, Y.-H. L.; Wu, J.

    1986-01-01

    Rates of heat and mass transfer across an air-water interface were measured in a wind-wave research facility, under various wind and thermal stability conditions (unless otherwise noted, mass refers to water vapor). Heat fluxes were obtained from both the eddy correlation and the profile method, under unstable, neutral, and stable conditions. Mass fluxes were obtained only under unstable stratification from the profile and global method. Under unstable conditions the turbulent Prandtl and Schmidt numbers remain fairly constant and equal to 0.74, whereas the rate of mass transfer varies linearly with bulk Richardson number. Under stable conditions the turbulent Prandtl number rises steadily to a value of 1.4 for a bulk Richardson number of about 0.016. Results of heat and mass transfer, expressed in the form of bulk aerodynamic coefficients with friction velocity as a parameter, are also compared with field data.

  4. Measuring Air-water Interfacial Area for Soils Using the Mass Balance Surfactant-tracer Method

    PubMed Central

    Araujo, Juliana B.; Mainhagu, Jon; Brusseau, Mark L.

    2015-01-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. PMID:25950136

  5. Lead-210 concentration in the air at Mt. Zeppelin, Ny-Ålesund, Svalbard

    NASA Astrophysics Data System (ADS)

    Paatero, Jussi; Hatakka, Juha; Holmén, Kim; Eneroth, Kristina; Viisanen, Yrjö

    High-volume aerosol particle samples have been collected onto glass fibre filters at Ny-Ålesund, Svalbard. The filters have been assayed for 210Pb by measuring the alpha particles of its in-grown daughter nuclide 210Po. The observed 210Pb activity concentrations at Mt. Zeppelin, Ny-Ålesund, Svalbard vary between 11 and 620 μBq/m 3 in 2001. The 25%, 50%, and 75% percentiles of the 210Pb activity concentrations at Mt. Zeppelin are 42, 83, and 220 μBq/m 3. The values are clearly lower than at Sodankylä, northern Finland with corresponding values of 100, 170, and 270 μBq/m 3. The arithmetic mean concentrations in 2001 were 144 and 245 μBq/m 3 at Ny-Ålesund and Sodankylä, respectively. The lowest 210Pb activity concentrations are found during summer both at Svalbard and in Finland. The highest concentrations occur in March-April at Svalbard. This differs from the seasonal behaviour of 210Pb in Finland, where the highest concentrations are usually observed in February-March. This 1-month difference between Svalbard and Finland may be related to the strength of solar radiation and its capability to cause vertical mixing of the air. Air mass back trajectory analysis shows that the lowest concentrations found at Svalbard are associated with air masses coming from the North Atlantic Ocean, Greenland and the Canadian Arctic. The highest concentrations are associated with air masses originating from northern Europe and Siberia, and during winter also in air masses coming from the central Arctic Ocean.

  6. Transport of semivolatile organic compounds to the Tibetan Plateau: Monthly resolved air concentrations at Nam Co

    NASA Astrophysics Data System (ADS)

    Xiao, Hang; Kang, Shichang; Zhang, Qianggong; Han, Wenwu; Loewen, Mark; Wong, Fiona; Hung, Hayley; Lei, Ying D.; Wania, Frank

    2010-08-01

    A flow-through sampler was deployed to record the seasonal variability of the atmospheric concentrations of semivolatile organic compounds (SOCs) at a remote research station located close to Nam Co Lake on the Tibetan plateau. Between October 2006 and February 2008, fifteen consecutive one month-long samples, with air volumes ranging from 4,500 to 16,000 m3, were taken and analyzed for polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs). Separate analysis of three polyurethane plugs in series in combination with frontal chromatographic theory allows for the correction of the break-through observed for the most volatile SOCs. The concentrations of Σ56PCB in air range from 0.10 to 2.6 pg·m-3 and are among the lowest values ever reported. Levels of OCPs at Nam Co are generally also very low, particularly during wintertime. The concentrations of hexachlorocyclohexanes (HCHs), endosulfans, and various dichlorodiphenyltrichloroethane (DDT) related substances display a distinct seasonal variability consistent with the monsoon. Back-trajectory analysis reveals that higher OCP levels during summer correlate with air mass origin south of the Himalayas. A high α/γ-HCH ratio and a non-racemic composition of α-HCH during July/August suggest that evaporation from Nam Co Lake contributes to the relatively high concentrations of α-HCH (averaging ca. 91 pg·m-3) recorded in the summertime atmosphere.

  7. Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

    NASA Technical Reports Server (NTRS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.; Schlager, H.; Atlas, E.; Blake, D.; Coe, H.; Cohen, R. C.; Crosier, J.; Flocke, F.; Holloway, J. S.; Hopkins, J. R.; Huber, G.; McQuaid, J.; Purvis, R.; Rappengluck, B.; Ryerson, T. B.; Sachse, G. W.

    2006-01-01

    The International Consortium for Atmospheric Research on Transport and Transformation (ICARTT)-Lagrangian experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts using two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique is then used to identify Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these coincident matches is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown and the downwind minus upwind differences in tracers are discussed.

  8. MISR Aerosol Air Mass Type Mapping over Mega-City: Validation and Applications

    NASA Astrophysics Data System (ADS)

    Patadia, F.; Kahn, R. A.

    2010-12-01

    Most aerosol air-quality monitoring in mega-city environments is done from scattered ground stations having detailed chemical and optical sampling capabilities. Satellite instruments such as the Multi-angle Imaging SpectroRadiometer (MISR) can retrieve total-column Aerosol Optical Depth (AOD), along with some information about particle microphysical properties. Although the particle property information from MISR is much less detailed than that obtained from the ground sampling stations, the coverage is extensive, making it possible to put individual surface observations into the context of regional aerosol air mass types. This paper presents an analysis of MISR aerosol observations made coincident with aircraft and ground-based instruments during the INTEX-B field campaign. These detailed comparisons of satellite aerosol property retrievals against dedicated field measurements provide the opportunity to validate the retrievals quantitatively at a regional level, and help to improve aerosol representation in retrieval algorithms. Validation of MISR retrieved AOD and other aerosol properties over the INTEX-B study region in and around Mexico City will be presented. MISR’s ability to distinguish among aerosol air mass types will be discussed. The goal of this effort is to use the MISR aerosol property retrievals for mapping both aerosol air mass type and AOD gradients in mega-city environments over the decade-plus that MISR has made global observations.

  9. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    USGS Publications Warehouse

    Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

    2002-01-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  10. Source areas and trajectories of nucleating air masses within and near the Carpathian Basin

    NASA Astrophysics Data System (ADS)

    Németh, Z.; Salma, I.

    2014-04-01

    Particle number size distributions were measured by differential mobility particle sizer in the diameter range of 6-1000 nm in the near-city background and city centre of Budapest continuously for two years. The city is situated in the middle part of the Carpathian Basin, which is a topographically discrete unit in the southeast Central Europe. Yearly mean nucleation frequencies and uncertainties for the near-city background and city centre were (28+6/-4) % and (27+9/-4) %, respectively. Total numbers of days with continuous and uninterrupted growth process were 43 and 31, respectively. These events and their properties were utilised to investigate if there are any specific tracks and/or separable source regions for the nucleating air masses within or near the basin. Local wind speed and direction data indicated that there seem to be differences between the nucleation and growth intervals and non-nucleation days. For further analysis, backward trajectories were generated by a simple air parcel trajectory model. Start and end time parameters of the nucleation, and end time parameter of the particle growth were derived by a standardized procedure based on examining the channel contents of the contour plots. These parameters were used to specify a segment on each air mass trajectory that is associated with the track of the nucleating air mass. The results indicated that the nucleation events happened in the continental boundary layer mostly within the Carpathian Basin but the most distant trajectories originated outside of the basin. The tracks of the nucleating air masses were predominantly associated with NW and SE geographical fields, while the source areas that could be separated were frequently situated in the NW and NE quarters. Many of them were within or close to large forested territories. The results also emphasize that the new particle formation and growth phenomenon that occurs in the region influences larger territories than the Carpathian Basin.

  11. Seasonal air and water mass redistribution effects on LAGEOS and Starlette

    NASA Technical Reports Server (NTRS)

    Gutierrez, Roberto; Wilson, Clark R.

    1987-01-01

    Zonal geopotential coefficients have been computed from average seasonal variations in global air and water mass distribution. These coefficients are used to predict the seasonal variations of LAGEOS' and Starlette's orbital node, the node residual, and the seasonal variation in the 3rd degree zonal coefficient for Starlette. A comparison of these predictions with the observed values indicates that air pressure and, to a lesser extent, water storage may be responsible for a large portion of the currently unmodeled variation in the earth's gravity field.

  12. Methane mole fraction and δ13C above and below the trade wind inversion at Ascension Island in air sampled by aerial robotics

    NASA Astrophysics Data System (ADS)

    Brownlow, R.; Lowry, D.; Thomas, R. M.; Fisher, R. E.; France, J. L.; Cain, M.; Richardson, T. S.; Greatwood, C.; Freer, J.; Pyle, J. A.; MacKenzie, A. R.; Nisbet, E. G.

    2016-11-01

    Ascension Island is a remote South Atlantic equatorial site, ideal for monitoring tropical background CH4. In September 2014 and July 2015, octocopters were used to collect air samples in Tedlar bags from different heights above and below the well-defined Trade Wind Inversion (TWI), sampling a maximum altitude of 2700 m above mean sea level. Sampling captured both remote air in the marine boundary layer below the TWI and also air masses above the TWI that had been lofted by convective systems in the African tropics. Air above the TWI was characterized by higher CH4, but no distinct shift in δ13C was observed compared to the air below. Back trajectories indicate that lofted CH4 emissions from Southern Hemisphere Africa have bulk δ13CCH4 signatures similar to background, suggesting mixed emissions from wetlands, agriculture, and biomass burning. The campaigns illustrate the usefulness of unmanned aerial system sampling and Ascension's value for atmospheric measurement in an understudied region.

  13. Improving Hydrological Models by Applying Air Mass Boundary Identification in a Precipitation Phase Determination Scheme

    NASA Astrophysics Data System (ADS)

    Feiccabrino, James; Lundberg, Angela; Sandström, Nils

    2013-04-01

    Many hydrological models determine precipitation phase using surface weather station data. However, there are a declining number of augmented weather stations reporting manually observed precipitation phases, and a large number of automated observing systems (AOS) which do not report precipitation phase. Automated precipitation phase determination suffers from low accuracy in the precipitation phase transition zone (PPTZ), i.e. temperature range -1° C to 5° C where rain, snow and mixed precipitation is possible. Therefore, it is valuable to revisit surface based precipitation phase determination schemes (PPDS) while manual verification is still widely available. Hydrological and meteorological approaches to PPDS are vastly different. Most hydrological models apply surface meteorological data into one of two main PPDS approaches. The first is a single rain/snow threshold temperature (TRS), the second uses a formula to describe how mixed precipitation phase changes between the threshold temperatures TS (below this temperature all precipitation is considered snow) and TR (above this temperature all precipitation is considered rain). However, both approaches ignore the effect of lower tropospheric conditions on surface precipitation phase. An alternative could be to apply a meteorological approach in a hydrological model. Many meteorological approaches rely on weather balloon data to determine initial precipitation phase, and latent heat transfer for the melting or freezing of precipitation falling through the lower troposphere. These approaches can improve hydrological PPDS, but would require additional input data. Therefore, it would be beneficial to link expected lower tropospheric conditions to AOS data already used by the model. In a single air mass, rising air can be assumed to cool at a steady rate due to a decrease in atmospheric pressure. When two air masses meet, warm air is forced to ascend the more dense cold air. This causes a thin sharp warming (frontal

  14. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  15. Mixing of stratospheric and tropospheric air-masses detected with CRISTA-NF during AMMA

    NASA Astrophysics Data System (ADS)

    Weigel, K.; Guenther, G.; Hoffmann, L.; Konopka, P.; Riese, M.

    2009-04-01

    CRISTA-NF (CRyogenic Infrared Spectrometers and Telescopes for the Atmosphere - New Frontiers) is an infrared limb sounding instrument installed onbord the high-flying research aircraft M55-Geophysica and took part in the AMMA-SCOUT measurement campaign in Summer 2006. During the test flight on 29th of July 2006, CRISTA-NF detected a sharp boundary between ozone rich air over northernItaly and ozone poor air over southern Italy and the Mediterranean Sea. The structure is also clearly visible in the HNO3 distribution. The air mass boundary extends from about 10km altitude to the thermal tropopause at about 16km altitude with indication for mixing in the lower part of this altitude range. This is supported by enhanced values of PAN and water vapour found. The observed structure is also visible in the CLaMS (Chemical Lagrangian Model of the Stratosphere) ozone distribution but hardly resolved in ECMWF forecast data. Backward trajectories show that the ozone rich air is originated westwards, between 40 and 60oN while the ozone poor air is coming from the south-east, at about 0-20oN and has a younger age of air. In the presentation details of the CRISTA-NF measurements and retrieval procedures as well as the origin of the trace gas structures will be discussed.

  16. Comparative chemical mass closure of fine and coarse aerosols at two sites in south and west Europe: Implications for EU air pollution policies

    NASA Astrophysics Data System (ADS)

    Viana, M.; Maenhaut, W.; Chi, X.; Querol, X.; Alastuey, A.

    The chemical composition of PM10 and PM2.5 was studied during summer and winter sampling campaigns in South and West Europe (Barcelona, Spain, and Ghent, Belgium). The chemical composition of the PM10 aerosol was markedly different in the two regions, even at similar PM10 levels. The chemical composition of PM2.5 showed more similarities. The contribution of mineral matter was higher in Barcelona (on average 12% of the PM2.5 mass), whereas the contribution from sea salt was higher in Ghent (4% of PM2.5). Volatilisation of NH 4+ from the filters (negative artefact) was observed in both regions, although the extent of this artefact showed regional differences (0-4% and 22-38% of the NH 4+ mass in Ghent and Barcelona, respectively) and had no impact on the compliance with EU limit values. The number of exceedances of the PM10 limit value and an arbitrary PM2.5 limit of 25 μg m -3 was calculated by subtracting the mineral fraction (natural or anthropogenic in origin) from the bulk PM load, and this resulted in the elimination of the PM10 exceedances in Barcelona, and a reduction of one out of three exceedances in Ghent. The subtraction of sea-salt aerosol had no effect in Barcelona, and it removed one exceedance in each size fraction in Ghent. Exceedances of the PM10 daily limit value in Ghent coincided with back-trajectories originating from Eastern and Southern European regions. The origin of the exceedances in Barcelona during the campaigns was mostly local.

  17. Overview of aerosol properties associated with air masses sampled by the ATR-42 during the EUCAARI campaign (2008)

    NASA Astrophysics Data System (ADS)

    Crumeyrolle, S.; Schwarzenboeck, A.; Sellegri, K.; Burkhart, J. F.; Stohl, A.; Gomes, L.; Quennehen, B.; Roberts, G.; Weigel, R.; Roger, J. C.; Villani, P.; Pichon, J. M.; Bourrianne, T.; Laj, P.

    2012-04-01

    Within the frame of the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) project the Météo-France aircraft ATR-42 performed 22 research flights, over central Europe and the North Sea during the intensive observation period in May 2008. For the campaign, the ATR-42 was equipped in order to study aerosol physical, chemical and optical properties, as well as cloud microphysics. During the campaign, continental air masses from Eastern and Western Europe were encountered, along with polar and Scandinavian air masses. For the 22 research flights, retroplume analyses along the flight tracks were performed with FLEXPART in order to classify air masses into five sectors of origin which allows for a qualitative evaluation of emission influence on the respective air parcel. In the polluted boundary layer (BL), typical concentrations of particles with diameters larger than 10 nm (N10) are of the order of 5000-6000 cm-3, whereas N10 concentrations of clean air masses were lower than 1300 cm-3. The detection of the largest particle number concentrations occurred in air masses coming from Polar and Scandinavian regions for which an elevated number of nucleation mode (25-28 nm) particles was observed and attributed to new particle formation over open sea. In the free troposphere (FT), typical observed N10 are of the order of 900 cm-3 in polluted air masses and 400-600 cm-3 in clean air masses, respectively. In both layers, the chemical composition of submicron aerosol particles is dominated by organic matter and nitrate in polluted air masses, while, sulphate and ammonium followed by organics dominate the submicron aerosols in clean air masses. The highest CCN/CN ratios were observed within the polar air masses while the CCN concentration values are the highest within the polluted air masses. Within the five air mass sectors defined and the two layers (BL and FT), observations have been distinguished into anticyclonic (first half of May 2008) and cyclonic

  18. Enhancement of acidic gases in biomass burning impacted air masses over Canada

    NASA Technical Reports Server (NTRS)

    Lefer, B. L.; Talbot, R. W.; Harriss, R. C.; Bradshaw, J. D.; Sandholm, S. T.; Olson, J. O.; Sachse, G. W.; Collins, J.; Shipham, M. A.; Blake, D. R.

    1994-01-01

    Biomass-burning impacted air masses sampled over central and eastern Canada during the summer of 1990 as part of ABLE 3B contained enhanced mixing ratios of gaseous HNO3, HCOOH, CH3COOH, and what appears to be (COOH)2. These aircraft-based samples were collected from a variety of fresh burning plumes and more aged haze layers from different source regions. Values of the enhancement factor, delta X/delta CO, where X represents an acidic gas, for combustion-impacted air masses sampled both near and farther away from the fires, were relatively uniform. However, comparison of carboxylic acid emission ratios measured in laboratory fires to field plume enhancement factors indicates significant in-plume production of HCOOH. Biomass-burning appears to be an important source of HNO3, HCOOH, and CH3COOH to the troposphere over subarctic Canada.

  19. Ozone and Trace Gas Trends in the UK and Links to Changing Air Mass Pathways

    NASA Astrophysics Data System (ADS)

    Fleming, Z.; Monks, P. S.; Reeves, C.; Bohnenstengel, S.

    2014-12-01

    Trace gas measurements from UK measurement sites on the North Sea coast and in central London reveal a complicated relationship between NO2, CO, hydrocarbons and ozone. Due to the location of the sites, they receive air masses from the UK, Europe, the North sea, Scandinavia and the Arctic and Atlantic Seas and any seasonality is hard to discern. The transport pathway of air masses that can change on an hourly timescale clearly influences the trace gas levels. Investigations into how the transport pathways have changed over the years, using the NAME dispersion model try to elucidate whether it is the 'where' (transport pathway) or the 'what' (trace gas emissions) that is leading to the ozone trends recorded over the past few years.

  20. Toward a better understanding of the impact of mass transit air pollutants on human health.

    PubMed

    Kim, Ki-Hyun; Kumar, Pawan; Szulejko, Jan E; Adelodun, Adedeji A; Junaid, Muhammad Faisal; Uchimiya, Minori; Chambers, Scott

    2017-05-01

    Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments.

  1. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  2. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    NASA Astrophysics Data System (ADS)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  3. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  4. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity.

    PubMed

    Bugbee, B; Monje, O; Tanner, B

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  5. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    NASA Technical Reports Server (NTRS)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  6. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    NASA Astrophysics Data System (ADS)

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-04-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2- and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios.

  7. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    PubMed Central

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2− and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  8. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2016-10-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  9. Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

    NASA Astrophysics Data System (ADS)

    Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

    2015-10-01

    We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

  10. On the Origin of Polar Vortex Air

    NASA Technical Reports Server (NTRS)

    Rosenfield, J. E.; Schoeberl, M. R.; Einaudi, Franco (Technical Monitor)

    2001-01-01

    The existence of the multi-year HALOE CH4 data set, together with some comparisons of forward with back trajectory calculations which we have carried out, has motivated us to reexamine the question of polar vortex descent. Three-dimensional diabatic trajectory calculations have been carried out for the seven month fall to spring period in both the northern hemisphere (NH) and southern hemisphere (SH) polar stratosphere for the years 1992-1999. These computations are compared to fixed descent computations where the parcels were fixed at their latitude-longitude locations and allowed to descend without circulating. The forward trajectory computed descent is always less than the fixed descent due to horizontal parcel motions and variations in heating rates with latitude and longitude. Although the forward calculations estimate the maximum amount of descent that can occur, they do not necessarily indicate the actual origin of springtime vortex air. This is because more equator-ward air can be entrained within the vortex during its formation. To examine the origin of the springtime vortex air, the trajectory model was run backward for seven months from spring to fall. The back trajectories show a complex distribution of parcels in which one population originates in the upper stratosphere and mesosphere and experiences considerable descent in the polar regions, while the remaining parcels originate at lower altitudes of the middle and lower stratosphere and are mixed into the polar regions during vortex formation without experiencing as much vertical transport. The amount of descent experienced by the first population shows little variability from year to year, while the computed descent and mixing of the remaining parcels show considerable interannual variability due to the varying polar meteorology. Because of this complex parcel distribution it is not meaningful to speak of a net amount of descent experienced over the entire winter period. Since the back trajectories

  11. Chemical characterization of submicron aerosol particles during wintertime in a northwest city of China using an Aerodyne aerosol mass spectrometry.

    PubMed

    Zhang, Xinghua; Zhang, Yangmei; Sun, Junying; Yu, Yangchun; Canonaco, Francesco; Prévôt, Andre S H; Li, Gang

    2017-03-01

    An Aerodyne quadrupole aerosol mass spectrometry (Q-AMS) was utilized to measure the size-resolved chemical composition of non-refractory submicron particles (NR-PM1) from October 27 to December 3, 2014 at an urban site in Lanzhou, northwest China. The average NR-PM1 mass concentration was 37.3 μg m(-3) (ranging from 2.9 to 128.2 μg m(-3)) under an AMS collection efficiency of unity and was composed of organics (48.4%), sulfate (17.8%), nitrate (14.6%), ammonium (13.7%), and chloride (5.7%). Positive matrix factorization (PMF) with the multi-linear engine (ME-2) solver identified six organic aerosol (OA) factors, including hydrocarbon-like OA (HOA), coal combustion OA (CCOA), cooking-related OA (COA), biomass burning OA (BBOA) and two oxygenated OA (OOA1 and OOA2), which accounted for 8.5%, 20.2%, 18.6%, 12.4%, 17.8% and 22.5% of the total organics mass on average, respectively. Primary emissions were the major sources of fine particulate matter (PM) and played an important role in causing high chemically resolved PM pollution during wintertime in Lanzhou. Back trajectory analysis indicated that the long-range regional transport air mass from the westerly was the key factor that led to severe submicron aerosol pollution during wintertime in Lanzhou.

  12. Open air mineral treatment operations and ambient air quality: assessment and source apportionment.

    PubMed

    Escudero, M; Alastuey, A; Moreno, T; Querol, X; Pérez, P

    2012-11-01

    We present a methodology for evaluating and quantifying the impact of inhalable mineral dust resuspension close to a potentially important industrial point source, in this case an open air plant producing sand, flux and kaolin in the Capuchinos district of Alcañiz (Teruel, NE Spain). PM(10) levels at Capuchinos were initially high (42 μg m(-3) as the annual average with 91 exceedances of the EU daily limit value during 2007) but subsequently decreased (26 μg m(-3) with 16 exceedances in 2010) due to a reduced demand for minerals from the ceramic industry and construction sector during the first stages of the economic crisis. Back trajectory and local wind pattern analyses revealed only limited contribution from exotic PM sources such as African dust intrusions whereas there was clearly a strong link with the mineral stockpiles of the local industry. This link was reinforced by chemical and mineral speciation and source apportionment analysis which showed a dominance of mineral matter (sum of CO(3)(2-), SiO(2), Al(2)O(3), Ca, Fe, K, Mg, P, and Ti: mostly aluminosilicates) which in 2007 contributed 76% of the PM(10) mass (44 μg m(-3) on average). The contribution from Secondary Inorganic Aerosols (SIA, sum of SO(4)(2-), NO(3)(-) and NH(4)(+)) reached 8.4 μg m(-3), accounting for 14% of the PM(10) mass, similar to the amount of calcareous road dust estimated to be present (8 μg m(-3); 13%). Organic matter and elemental carbon contributed 5.3 μg m(-3) (9%) whereas marine aerosol (Na + Cl) levels were minor with an average concentration of 0.4 μg m(-3) (1% of the PM(10) mass). Finally, chemical and mineralogical analysis of stockpile samples and comparison with filter samples confirmed the local industry to be the major source of ambient PM(10) in the area.

  13. Distant evaluation of the influence of air pollution on remote areas

    NASA Astrophysics Data System (ADS)

    Vinogradova, A. A.

    2015-12-01

    This paper presents a back-trajectory approach to evaluating and forecasting the influence of different atmospheric emissions on the environment of Russia's remote and hard-to-reach regions. Air-mass trajectories are derived from the HYSPLIT4 model, which is presented on the NOAA Atmospheric Research Laboratory website. Mean concentrations of anthropogenic heavy metals (HMs) in the air, snow, and rainfall and their total fluxes onto the surface for the 2000s are calculated for the Nenetskii, Gydanskii, and Ust'Lenskii State Nature reserves on the coast of the Russian Arctic Ocean. Data on anthropogenic atmospheric emissions of heavy metals (Ni, Cu, Pb, Cd, Zn, Cr, and As) and their annual fluxes for Russian cities and regions are provided by the State Roshydromet Service. The mean deposition velocities of anthropogenic HMs transported on submicron aerosol particles are calculated from the literature data and weather information taking into account climatic distinctions. Spatial distributions of potential anthropogenic HM source functions are presented on maps. These maps are used to estimate the impact of existing and designed pollution sources, including extended ones (forest and grass fires), and to determine the most important sources for the Russian Arctic. Seasonal and spatial variations in the anthropogenic impact through the atmosphere on the Russian Arctic coast are analyzed.

  14. Cluster analysis of passive air sampling data based on the relative composition of persistent organic pollutants.

    PubMed

    Liu, Xiande; Wania, Frank

    2014-03-01

    The development of passive air samplers has allowed the measurement of time-integrated concentrations of persistent organic pollutants (POPs) within spatial networks on a variety of scales. Cluster analysis of POP composition may enhance the interpretation of such spatial data. Several methodological aspects of the application of cluster analysis are discussed, including the influence of a dominant pollutant, the role of PAS duplication, and comparison of regional studies. Relying on data from six regional studies in North and South America, Africa, and Asia, we illustrate here how cluster analysis can be used to extract information and gain insights into POP sources and atmospheric transport contributions. Cluster analysis allows classification of PAS samples into those with significant local source contributions and those that represent regional fingerprints. Local emissions, atmospheric transport, and seasonal cycles are identified as being among the major factors determining the variation in POP composition at many sites. By complementing cluster analysis with meteorological data such as air mass back-trajectories, terrain, as well as geographical and socio-economic aspects, a comprehensive picture of the atmospheric contamination of a region by POPs emerges.

  15. Characterization of organic aerosols in Beijing using an aerodyne high-resolution aerosol mass spectrometer

    NASA Astrophysics Data System (ADS)

    Zhang, Junke; Wang, Yuesi; Huang, Xiaojuan; Liu, Zirui; Ji, Dongsheng; Sun, Yang

    2015-06-01

    Fine particle of organic aerosol (OA), mostly arising from pollution, are abundant in Beijing. To achieve a better understanding of the difference in OA in summer and autumn, a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS, Aerodyne Research Inc., USA) was deployed in urban Beijing in August and October 2012. The mean OA mass concentration in autumn was 30±30 μg m-3, which was higher than in summer (13±6.9 μg m-3). The elemental analysis found that OA was more aged in summer (oxygen-to-carbon (O/C) ratios were 0.41 and 0.32 for summer and autumn, respectively). Positive matrix factorization (PMF) analysis identified three and five components in summer and autumn, respectively. In summer, an oxygenated OA (OOA), a cooking-emission-related OA (COA), and a hydrocarbon-like OA (HOA) were indentified. Meanwhile, the OOA was separated into LV-OOA (low-volatility OOA) and SV-OOA (semi-volatile OOA); and in autumn, a nitrogen-containing OA (NOA) was also found. The SOA (secondary OA) was always the most important OA component, accounting for 55% of the OA in the two seasons. Back trajectory clustering analysis found that the origin of the air masses was more complex in summer. Southerly air masses in both seasons were associated with the highest OA loading, while northerly air masses were associated with the lowest OA loading. A preliminary study of OA components, especially the POA (primary OA), in different periods found that the HOA and COA all decreased during the National Day holiday period, and HOA decreased at weekends compared with weekdays.

  16. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  17. Influence of air mass origin on aerosol properties at a remote Michigan forest site

    NASA Astrophysics Data System (ADS)

    VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; Pressley, S. N.; Erickson, M. H.; Jobson, B. T.; Lamb, B. K.

    2015-04-01

    The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere-Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ∼60% of the study period, air was transported from sparsely populated regions to the northwest. During these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm-3 and 1.91 μm3 cm-3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (∼29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean k = 0.24 at s = 0.3%). These trends are have the potential to influence forest-atmosphere interactions and should be targeted for future study.

  18. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 2

    NASA Technical Reports Server (NTRS)

    Hovel, H.; Woodall, J. M.

    1976-01-01

    Crystal growth procedures, fabrication techniques, and theoretical analysis were developed in order to make GaAlAs-GaAs solar cell structures which exhibit high performance at air mass 0 illumination and high temperature conditions.

  19. Calibration of Dissolved Noble Gas Mass Spectrometric Measurements by an Air-Water Equilibration System

    NASA Astrophysics Data System (ADS)

    Hillegonds, Darren; Matsumoto, Takuya; Jaklitsch, Manfred; Han, Liang-Feng; Klaus, Philipp; Wassenaar, Leonard; Aggarwal, Pradeep

    2013-04-01

    Precise measurements by mass spectrometry of dissolved noble gases (He, Ar, Ne, Kr, Xe) in water samples require careful calibration against laboratory standards with known concentrations. Currently, air pipettes are used for day-to-day calibrations, making estimation of overall analytical uncertainties for dissolved noble gas measurements in water difficult. Air equilibrated water (AEW) is often used as a matrix-equivalent laboratory standard for dissolved gases in groundwater, because of the well-known and constant fractions of noble gases in the atmosphere. AEW standards, however, are only useful if the temperature and pressure of the gas-water equilibrium can be controlled and measured precisely (i.e., to better than 0.5%); contamination and partial sample degassing must also be prevented during sampling. Here we present the details of a new custom air-water equilibration system which consists of an insulated 600 liter tank filled with deionized water, held isothermally at a precise target temperature (<0.05 °C) through the use of a heat exchanger. The temperature and total dissolved gas of the water in the tank are monitored continually, as are atmospheric pressure and air temperature in the laboratory. Different noble gas concentration standards can be reliably produced by accurately controlling the water temperature of the equilibration system. Equilibration characteristics and reproducibility of this system for production of copper tubes containing known amounts of noble gases will be presented.

  20. Determination of the effect of transfer between vacuum and air on mass standards of platinum-iridium and stainless steel

    NASA Astrophysics Data System (ADS)

    Davidson, Stuart

    2010-08-01

    This paper reports work undertaken to assess the change in the mass values of stainless steel and platinum-iridium weights transferred between air and vacuum and to determine the repeatability of this change. Sets of kilogram transfer standards, manufactured from stainless steel and platinum-iridium and with different surface areas, were used to determine the effect of transfer between air and vacuum on the values of the mass standards. The SI unit of mass is the only unit of the seven base SI quantities which is still defined in terms of an artefact rather than by relation to a fundamental physical constant. Work is underway to identify a means of deriving the SI unit of mass from fundamental constants and at present the two principal approaches are the International Avogadro Coordination and the watt balance projects. Both of these approaches involve realizing a kilogram in vacuum and therefore the traceability from a kilogram realized in vacuum to mass standards in air is crucial to the effective dissemination of the mass scale. The work reported here characterizes the changes in mass values of standards on transfer between air and vacuum and thus will enable traceability to be established for an in-air mass scale based on a definition of the unit in vacuum.

  1. Effect of the relative optical air mass and the clearness index on solar erythemal UV irradiance.

    PubMed

    Moreno, J C; Serrano, M A; Cañada, J; Gurrea, G; Utrillas, M P

    2014-09-05

    This paper analyses the effects of the clearness index (Kt) and the relative optical air mass (mr) on erythemal UV irradiance (UVER). The UVER measurements were made in Valencia (Spain) from 6:00 am to 6:00 pm between June 2003 and December 2012 and (140,000 data points). Firstly, two models were used to calculate values for the erythemal ultraviolet irradiance clearness index (KtUVER) as a function of the global irradiance clearness index (Kt). Secondly, a potential regression model to measure the KtUVER as a function of the relative optical air mass was studied. The coefficients of this regression were evaluated for clear and cloudy days, as well as for days with high and low ozone levels. Thirdly, an analysis was made of the relationship between the two effects in the experimental database, with it being found that the highest degree of agreement, or the joint highest frequencies, are located in the optical mass range mr∈[1.0, 1.2] and the clearness index range of Kt∈[0.8, 1.0]. This is useful for establishing the ranges of parameters where models are more efficient. Simple equations have been tested that can provide additional information for the engineering projects concerning thermal installations. Fourthly, a high dispersion of radiation data was observed for intermediate values of the clearness for UV and UVER.

  2. Visual Steering and Verification of Mass Spectrometry Data Factorization in Air Quality Research.

    PubMed

    Engel, D; Greff, K; Garth, C; Bein, K; Wexler, A; Hamann, B; Hagen, H

    2012-12-01

    The study of aerosol composition for air quality research involves the analysis of high-dimensional single particle mass spectrometry data. We describe, apply, and evaluate a novel interactive visual framework for dimensionality reduction of such data. Our framework is based on non-negative matrix factorization with specifically defined regularization terms that aid in resolving mass spectrum ambiguity. Thereby, visualization assumes a key role in providing insight into and allowing to actively control a heretofore elusive data processing step, and thus enabling rapid analysis meaningful to domain scientists. In extending existing black box schemes, we explore design choices for visualizing, interacting with, and steering the factorization process to produce physically meaningful results. A domain-expert evaluation of our system performed by the air quality research experts involved in this effort has shown that our method and prototype admits the finding of unambiguous and physically correct lower-dimensional basis transformations of mass spectrometry data at significantly increased speed and a higher degree of ease.

  3. Observations of Processed Asian Pollution with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) from the C-130 Aircraft During the INTEX-B Field Campaign

    NASA Astrophysics Data System (ADS)

    Dunlea, E.; Decarlo, P.; Aiken, A.; Kimmel, J.; Bahreini, R.; Peltier, R.; Weber, R.; Tomlinson, J.; Collins, D.; Shinozuka, Y.; Howell, S.; Clarke, A.; Emmons, L.; Apel, E.; Pfister, G.; van Donkelaar, A.; Millet, D.; Jimenez, J.

    2007-12-01

    Measurements of submicron, non-refractory aerosol mass were made from the NCAR/NSF C-130 aircraft using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) during the spring 2006 INTEX-B field campaign based in Seattle. We intercepted numerous Asian pollution layers, some after rapid transport across the Pacific and others after slower transport which had reduced aerosol concentrations and were depleted of short-lived tracers. The aerosol in Asian pollution layers intercepted over the Eastern Pacific Ocean was shown to have a predominance of sulfate over organic material, the latter being highly oxidized. Measurements and back trajectory calculations are consistent with the following sequence: (a) relatively more rapid conversion of organic precursors to organic aerosol compared to conversion of SO2 to sulfate just downwind of Asian urban centers and pollution sources, (b) uplift and transport of air masses resulting in washout of most aerosol material leaving relatively more SO2 available, and (c) subsequent SO2 to sulfate conversion as air masses are transported across the Pacific. This is consistent with Brock et al., JGR, 2004. Two case studies will be presented to describe this evolution of aerosol chemical composition during transport from Asia. Overall correlations of several tracers will be shown for comparing MOZART and GEOS-Chem model outputs with the measurements. Also, comparisons of AMS measurements with other aerosol instruments will be shown.

  4. Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Shirley, John A.; Winter, Michael

    1993-01-01

    An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

  5. Ozone Modulation/Membrane Introduction Mass Spectrometry for Analysis of Hydrocarbon Pollutants in Air

    NASA Astrophysics Data System (ADS)

    Atkinson, D. B.

    2001-12-01

    Modulation of volatile hydrocarbons in two-component mixtures is demonstrated using an ozonolysis pretreatment with membrane introduction mass spectrometry (MIMS). The MIMS technique allows selective introduction of volatile and semivolatile analytes into a mass spectrometer via processes known collectively as pervaporation [Kotiaho and Cooks, 1992]. A semipermeable polymer membrane acts as an interface between the sample (vapor or solution) and the vacuum of the mass spectrometer. This technique has been demonstrated to allow for sensitive analysis of hydrocarbons and other non-polar volatile organic compounds (VOC`s) in air samples[Cisper et al., 1995] . The methodology has the advantages of no sample pretreatment and short analysis time, which are promising for online monitoring applications but the chief disadvantage of lack of a separation step for the different analytes in a mixture. Several approaches have been investigated to overcome this problem including use of selective chemical ionization [Bier and Cooks, 1987] and multivariate calibration techniques[Ketola et al., 1999] . A new approach is reported for the quantitative measurement of VOCs in complex matrices. The method seeks to reduce the complexity of mass spectra observed in hydrocarbon mixture analysis by selective pretreatment of the analyte mixture. In the current investigation, the rapid reaction of ozone with alkenes is used, producing oxygenated compounds which are suppressed by the MIMS system. This has the effect of removing signals due to unsaturated analytes from the compound mass spectra, and comparison of the spectra before and after the ozone treatment reveals the nature of the parent compounds. In preliminary investigations, ozone reacted completely with cyclohexene from a mixture of cylohexene and cyclohexane, and with β -pinene from a mixture of toluene and β -pinene, suppressing the ion signals from the olefins. A slight attenuation of the cyclohexane and toluene in those

  6. Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

    NASA Astrophysics Data System (ADS)

    Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

    2015-04-01

    While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

  7. Satellite and ground observations of the severe air pollution episode in North China in the winter of 2013

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Wang, Z.; Ma, Z.; Li, S.

    2013-12-01

    After two decades of rapid economic growth and urban sprawl, Beijing, China has become one of the most polluted megacities in the world. Severe air pollution has become a serious concern of both the general public and the central government. A prolonged severe fine particle pollution episode in January 2013 attracted nationwide and even worldwide attention. In this study, we describe the spatial and temporal characteristics of PM2.5 levels using ground measurements and remote sensing data. Mean PM2.5 concentrations in Beijing measured by the newly established national monitoring network exceeded 150 microgram/m3 and the maximum daily level reached 420 microgram/m3. High-resolution custom retrieval of AOD showed good correlations (r = 0.79) to the ground monitoring PM2.5 concentrations , and were then used together with ground PM2.5 to develop PM2.5 concentration contours over the North China Plain. From regional concentration contours, we found that Beijing was not the epicenter of the haze episodes, but located at northern edge of a large polluted air mass. Analysis of the temperature and power generation data suggests that these severe haze episodes were partly caused by a very cold winter and resulting significant increases (>20%) of daily power consumption. Back trajectory analysis showed air mass movement into Beijing from major power plants south of the city. Our results suggested regional transportation of fine particles significantly contributed to the air pollution in Beijing, therefore emission reduction in Beijing alone will not be sufficient to significantly improve air quality. Satellite remote sensing data can be used to supplement ground monitors for quantitative air quality assessment at urban to national scale in order to develop effective pollution mitigation policy. Distribution of Ground Monitoring Stations in the Study Region.

  8. Measurement and modeling of diel variability of polybrominated diphenyl ethers and chlordanes in air.

    PubMed

    Moeckel, Claudia; Macleod, Matthew; Hungerbühler, Konrad; Jones, Kevin C

    2008-05-01

    Short-term variability of concentrations of polybrominated diphenyl ethers (PBDEs) and chlordanes in air at a semirural site in England over a 5 day period is reported. Four-hour air samples were collected during a period dominated by a high pressure system that produced stable diel (24-h) patterns of meteorological conditions such as temperature and atmospheric boundary layer height. PBDE and chlordane concentrations showed clear diel variability with concentrations in the afternoon and evening being 1.9 - 2.7 times higher than in the early morning. The measurements are interpreted using a multimedia mass balance model parametrized with forcing functions representing local temperature, atmospheric boundary layer height, wind speed and hydroxyl radical concentrations. Model results indicate that reversible, temperature-controlled air-surface exchange is the primary driver of the diel concentration pattern observed for chlordanes and PBDE 28. For higher brominated PBDE congeners (47, 99 and 100), the effect of variable atmospheric mixing height in combination with irreversible deposition on aerosol particles is dominant and explains the diel patterns almost entirely. Higher concentrations of chlordanes and PBDEs in air observed at the end of the study period could be related to likely source areas using back trajectory analysis. This is the first study to clearly document diel variability in concentrations of PBDEs in air over a period of several days. Our model analysis indicates that high daytime and low nighttime concentrations of semivolatile organic chemicals can arise from different underlying driving processes, and are not necessarily evidence of reversible air-surface exchange on a 24-h time scale.

  9. VOC Composition of Air Masses Transported from Asia to the U.S. West Coast

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Warneke, C.; Kuster, B.; Parrish, D.; Holloway, J.; Huebler, G.; Fehsenfeld, F.

    2002-12-01

    Airborne measurements of volatile organic compounds (VOCs) were performed using a proton-transfer-reaction mass spectrometer (PTR-MS) operated onboard a NOAA WP-3 aircraft during the Intercontinental Transport and Chemical Transformation (ITCT) experiment in 2002. Enhancements of acetone (CH3COCH3), methanol (CH3OH), acetonitrile (CH3CN) and in some cases benzene were observed in air masses that were impacted by outflow from Asia. The enhancement ratios with respect to carbon monoxide are compared to emission factors for fossil fuel combustion and biomass burning, which gives some insight into the sources responsible for the pollution. The observed mixing ratios for acetone, methanol and in particular acetonitrile were generally reduced in the marine boundary layer, suggesting the presence of an ocean uptake sink. The ocean uptake of acetonitrile was found to be particularly efficient in a zone with upwelling water off of the U.S. west coast. Reduced mixing ratios of acetone and methanol were observed in a stratospheric intrusion. This observation gives some information about the lifetime of these VOCs in the stratosphere. Enhanced concentrations of aromatic hydrocarbons were observed in air masses that were impacted by urban sources in California. The ratio between the concentrations of benzene, toluene and higher aromatics indicated the degree of photochemical oxidation. PTR-MS only gives information about the mass of the ions produced by proton-transfer reactions between H3O+ and VOCs in the instrument. The identification of VOCs was confirmed by coupling a gas-chromatographic (GC) column to the instrument and post-flight GC-PTR-MS analyses of canister samples collected during the flights.

  10. Air pollution from gas flaring: new emission factor estimates and detection in a West African aerosol remote-sensing climatology

    NASA Astrophysics Data System (ADS)

    MacKenzie, Rob; Fawole, Olusegun Gabriel; Levine, James; Cai, Xiaoming

    2016-04-01

    Gas flaring, the disposal of gas through stacks in an open-air flame, is a common feature in the processing of crude oil, especially in oil-rich regions of the world. Gas flaring is a prominent source of volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAH), CO, CO2, nitrogen oxides (NOx), SO2 (in "sour" gas only), and soot (black carbon), as well as the release of locally significant amounts of heat. The rates of emission of these pollutants from gas flaring depend on a number of factors including, but not limited to, fuel composition and quantity, stack geometry, flame/combustion characteristics, and prevailing meteorological conditions. Here, we derive new estimated emission factors (EFs) for carbon-containing pollutants (excluding PAH). The air pollution dispersion model, ADMS5, is used to simulate the dispersion of the pollutants from flaring stacks in the Niger delta. A seasonal variation of the dispersion pattern of the pollutant within a year is studied in relation to the movements of the West Africa Monsoon (WAM) and other prevailing meteorological factors. Further, we have clustered AERONET aerosol signals using trajectory analysis to identify dominant aerosol sources at the Ilorin site in West Africa (4.34 oE, 8.32 oN). A 10-year trajectory-based analysis was undertaken (2005-2015, excluding 2010). Of particular interest are air masses that have passed through the gas flaring region in the Niger Delta area en-route the AERONET site. 7-day back trajectories were calculated using the UK Universities Global Atmospheric Modelling Programme (UGAMP) trajectory model which is driven by analyses from the European Centre for Medium-Range Weather Forecasts (ECMWF). From the back-trajectory calculations, dominant sources are identified, using literature classifications: desert dust (DD); Biomass burning (BB); and Urban-Industrial (UI). We use a combination of synoptic trajectories and aerosol optical properties to distinguish a fourth source

  11. Air mass characterization during the DAURE field campaign by PTR-TOF

    NASA Astrophysics Data System (ADS)

    Metzger, Axel; Schallhart, Simon; Müller, Markus; Hansel, Armin

    2010-05-01

    Volatile organic compounds (VOCs) are emitted into the atmosphere from a wide variety of biogenic and anthropogenic sources. Although some of the sources are well characterized, many uncertainties remain about the fate of these compounds in the atmosphere and their role in organic aerosol formation. Here we present measurements using Proton Transfer Reaction Time-of-Flight (PTR-TOF) Mass Spectrometry during the DAURE field campaign ("Determination of the sources of atmospheric Aerosols in Urban and Rural Environments in the western Mediterranean") obtained during February and March 2009. Measurements were performed at a rural mountain site located in the Montseny Natural Park 40 km to the NNE of the city of Barcelona, and 25 km from the Mediterranean coast. Volatile organic compounds where identified and quantified using PTR-TOF with 1 minute time resolution. The instruments mass resolving power of 4000 - 5000 and a mass accuracy of 5 ppm allows for the unambiguous sum-formula identification of e.g. hydrocarbons (HCs) or oxygenated VOCs (OVOCs). The high time resolution allows separating out on site pollution events. Air masses impacted by biomass-burning, urban, marine and vegetation emissions are characterized using tracers like acetonitrile, aromatics, dimethyl sulfide or biogenic compounds (terpenoids) and the degree of photochemical processing is inferred from the data.

  12. Air mass distribution and the heterogeneity of the climate change signal in the Hudson Bay/Foxe Basin region, Canada

    NASA Astrophysics Data System (ADS)

    Leung, Andrew; Gough, William

    2016-08-01

    The linkage between changes in air mass distribution and temperature trends from 1971 to 2010 is explored in the Hudson Bay/Foxe Basin region. Statistically significant temperature increases were found of varying spatial and temporal magnitude. Concurrent statistically significant changes in air mass frequency at the same locations were also detected, particularly in the declining frequency of dry polar (DP) air. These two sets of changes were found to be linked, and we thus conclude that the heterogeneity of the climatic warming signal in the region is at least partially the result of a fundamental shift in the concurrent air mass frequency in addition to global and regional changes in radiative forcing due to increases in long-lived greenhouse gases.

  13. Mixture model-based atmospheric air mass classification: a probabilistic view of thermodynamic profiles

    NASA Astrophysics Data System (ADS)

    Pernin, Jérôme; Vrac, Mathieu; Crevoisier, Cyril; Chédin, Alain

    2016-10-01

    Air mass classification has become an important area in synoptic climatology, simplifying the complexity of the atmosphere by dividing the atmosphere into discrete similar thermodynamic patterns. However, the constant growth of atmospheric databases in both size and complexity implies the need to develop new adaptive classifications. Here, we propose a robust unsupervised and supervised classification methodology of a large thermodynamic dataset, on a global scale and over several years, into discrete air mass groups homogeneous in both temperature and humidity that also provides underlying probability laws. Temperature and humidity at different pressure levels are aggregated into a set of cumulative distribution function (CDF) values instead of classical ones. The method is based on a Gaussian mixture model and uses the expectation-maximization (EM) algorithm to estimate the parameters of the mixture. Spatially gridded thermodynamic profiles come from ECMWF reanalyses spanning the period 2000-2009. Different aspects are investigated, such as the sensitivity of the classification process to both temporal and spatial samplings of the training dataset. Comparisons of the classifications made either by the EM algorithm or by the widely used k-means algorithm show that the former can be viewed as a generalization of the latter. Moreover, the EM algorithm delivers, for each observation, the probabilities of belonging to each class, as well as the associated uncertainty. Finally, a decision tree is proposed as a tool for interpreting the different classes, highlighting the relative importance of temperature and humidity in the classification process.

  14. Impact of maritime air mass trajectories on the Western European coast urban aerosol.

    PubMed

    Almeida, S M; Silva, A I; Freitas, M C; Dzung, H M; Caseiro, A; Pio, C A

    2013-01-01

    Lisbon is the largest urban area in the Western European coast. Due to this geographical position the Atlantic Ocean serves as an important source of particles and plays an important role in many atmospheric processes. The main objectives of this study were to (1) perform a chemical characterization of particulate matter (PM2.5) sampled in Lisbon, (2) identify the main sources of particles, (3) determine PM contribution to this urban area, and (4) assess the impact of maritime air mass trajectories on concentration and composition of respirable PM sampled in Lisbon. During 2007, PM2.5 was collected on a daily basis in the center of Lisbon with a Partisol sampler. The exposed Teflon filters were measured by gravimetry and cut into two parts: one for analysis by instrumental neutron activation analysis (INAA) and the other by ion chromatography (IC). Principal component analysis (PCA) and multilinear regression analysis (MLRA) were used to identify possible sources of PM2.5 and determine mass contribution. Five main groups of sources were identified: secondary aerosols, traffic, calcium, soil, and sea. Four-day backtracking trajectories ending in Lisbon at the starting sampling time were calculated using the HYSPLIT model. Results showed that maritime transport scenarios were frequent. These episodes were characterized by a significant decrease of anthropogenic aerosol concentrations and exerted a significant role on air quality in this urban area.

  15. Precipitation chemistry and corresponding transport patterns of influencing air masses at Huangshan Mountain in East China

    NASA Astrophysics Data System (ADS)

    Shi, ChunE; Deng, Xueliang; Yang, Yuanjian; Huang, Xiangrong; Wu, Biwen

    2014-09-01

    One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean (VWM) pH for the whole sampling period was 5.03. SO{4/2-} and Ca2+ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO{4/2-}]/[NO{3/-}] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.

  16. Source and meteorological influences on air quality (CO, CH4 & CO2) at a Southern Hemisphere urban site

    NASA Astrophysics Data System (ADS)

    Buchholz, R. R.; Paton-Walsh, C.; Griffith, D. W. T.; Kubistin, D.; Caldow, C.; Fisher, J. A.; Deutscher, N. M.; Kettlewell, G.; Riggenbach, M.; Macatangay, R.; Krummel, P. B.; Langenfelds, R. L.

    2016-02-01

    Wollongong, Australia is an urban site at the intersection of anthropogenic, biomass burning, biogenic and marine sources of atmospheric trace gases. The location offers a valuable opportunity to study drivers of atmospheric composition in the Southern Hemisphere. Here, a record of surface carbon monoxide (CO), methane (CH4) and carbon dioxide (CO2) was measured with an in situ Fourier transform infrared trace gas analyser between April 2011 and August 2014. Clean air was found to arrive at Wollongong in approximately 10% of air masses. Biomass burning influence was evident in the average annual cycle of clean air CO during austral spring. A significant negative short-term trend was found in clean air CO (-1.5 nmol mol-1 a-1), driven by a reduction in northern Australian biomass burning. Significant short-term positive trends in clean air CH4 (5.4 nmol mol-1 a-1) and CO2 (1.9 μmol mol-1 a-1) were consistent with the long-term global average trends. Polluted Wollongong air was investigated using wind-direction/wind-speed clustering, which revealed major influence from local urban and industrial sources from the south. High values of CH4, with anthropogenic ΔCH4/ΔCO2 enhancement ratio signatures, originated from the northwest, in the direction of local coal mining. A pollution climatology was developed for the region using back trajectory analysis and ΔO3/ΔCO enhancement ratios. Ozone production environments in austral spring and summer were associated with anticyclonic meteorology on the east coast of Australia, while ozone depletion environments in autumn and winter were associated with continental transport, or fast moving trajectories from southern latitudes. This implies the need to consider meteorological conditions when developing policies for controlling air quality.

  17. The measurement of Peroxyacetyl nitrate (PAN) in the regional background marine boundary air, Baengyeong Island, South Korea

    NASA Astrophysics Data System (ADS)

    Lee, G.; Choi, H.; Lee, T.; Lee, D.; Park, J.; Jang, S.

    2010-12-01

    Concurrent measurements of Peroxyacetyl nitrate (PAN), other photochemically reactive species including O3, CO, NO, NOy, selected species of non-methane hydrocarbons (NMHCs), and aerosol chemical (water soluble ionic species, OC/EC, trace metals) compositions were made in an atmospheric monitoring station in Baengyeong Island from Aug. 2nd to 14th of 2010. This island is located at the far western part of Korea in the middle of Yellow Sea between China and Korea. PAN was determined every 3 minutes by a fast chromatograph with luminol-based chemiluminescence detection. Mixing ratios of PAN ranged from the below the detection limit of 0.005 to 1.04 ppb with an average of 0.09 ppb. Over the same period, hourly averaged O3 ranged from 0 to 63 ppb (average of 32 ppb). Although our measurements were made over the relatively clean marine boundary air, significant and rapid increases of PAN were frequently observed. These increases of PAN were coincided with increases of its precursors and wind pattern changes. After detailed analysis of aerosol compositions using local wind variation, back-trajectory and synoptic analysis of air masses, the degree of influences and chemistry related with PAN from surrounding land areas, China, South Korea and North Korea will be identified. Also, the role of PAN and other reactive nitrogen species to ozone formation and its transport over the Yellow Sea are planned to be addressed.

  18. A paradox for air pollution controlling in China revealed by “APEC Blue” and “Parade Blue”

    NASA Astrophysics Data System (ADS)

    Liu, Haoran; Liu, Cheng; Xie, Zhouqing; Li, Ying; Huang, Xin; Wang, Shanshan; Xu, Jin; Xie, Pinhua

    2016-09-01

    A series of strict emission control measures were implemented in Beijing and surrounding regions to ensure good air quality during the 2014 Asia-Pacific Economic Cooperation (APEC) summit and 2015 Grand Military Parade (Parade), which led to blue sky days during these two events commonly referred to as “APEC Blue” and “Parade Blue”. Here we calculated Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) and Ozone Monitoring Instrument (OMI) NO2 and HCHO results based on well known DOAS trace gas fitting algorithm and WRF-Chem model (with measured climatology parameter and newest emission inventor) simulated trace gases profiles. We found the NO2 columns abruptly decreased both Parade (43%) and APEC (21%) compared with the periods before these two events. The back-trajectory cluster analysis and the potential source contribution function (PSCF) proved regional transport from southern peripheral cities plays a key role in pollutants observed at Beijing. The diminishing transport contribution from southern air mass during Parade manifests the real effect of emission control measures on NO2 pollution. Based on the ratios of HCHO over NO2 we found there were not only limited the NO2 pollutant but also suppress the O3 contaminant during Parade, while O3 increased during the APEC.

  19. A paradox for air pollution controlling in China revealed by “APEC Blue” and “Parade Blue”

    PubMed Central

    Liu, Haoran; Liu, Cheng; Xie, Zhouqing; Li, Ying; Huang, Xin; Wang, Shanshan; Xu, Jin; Xie, Pinhua

    2016-01-01

    A series of strict emission control measures were implemented in Beijing and surrounding regions to ensure good air quality during the 2014 Asia-Pacific Economic Cooperation (APEC) summit and 2015 Grand Military Parade (Parade), which led to blue sky days during these two events commonly referred to as “APEC Blue” and “Parade Blue”. Here we calculated Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) and Ozone Monitoring Instrument (OMI) NO2 and HCHO results based on well known DOAS trace gas fitting algorithm and WRF-Chem model (with measured climatology parameter and newest emission inventor) simulated trace gases profiles. We found the NO2 columns abruptly decreased both Parade (43%) and APEC (21%) compared with the periods before these two events. The back-trajectory cluster analysis and the potential source contribution function (PSCF) proved regional transport from southern peripheral cities plays a key role in pollutants observed at Beijing. The diminishing transport contribution from southern air mass during Parade manifests the real effect of emission control measures on NO2 pollution. Based on the ratios of HCHO over NO2 we found there were not only limited the NO2 pollutant but also suppress the O3 contaminant during Parade, while O3 increased during the APEC. PMID:27680499

  20. Use of stable lead isotopes and trace metals to characterize air mass sources into the eastern North Atlantic

    NASA Astrophysics Data System (ADS)

    VéRon, Alain J.; Church, Thomas M.

    1997-12-01

    Stable lead isotopes (204Pb, 206Pb, 207Pb, 208Pb) and trace metals (Mn, Al, Fe, Ni, Cu, Cd, Zn, Pb) have been analyzed in aerosol collected during the Atlantic Stratocumulus Transition Experiment-Marine Aerosol and Gas Exchange (ASTEX-MAGE) cruise that transited between Miami and the Azores from May to July 1992. Our goal was to define the continental signatures of the air masses encountered between the Azores and the subtropical regions. The combination of air mass trajectories, trace metal concentrations and stable lead isotopes allowed us to characterize the anthropogenic character of encountered air masses. The average 206Pb/207Pb ratio was 1.148±0.021 and corresponded to a mixing between well defined European (such as Great Britain with 1.115<206Pb/207Pb<1.125 and France with 206Pb/207Pb=1.141±0.000) and North American sources (with 206Pb/207Pb=1.184±0.000). On the basis of air mass trajectories and trace metal concentrations, the background isotopic signature associated with the trade winds (206Pb/207Pb=1.161±0.004) is consistent with previous reports by Church et al. [1990] such as 206Pb/207Pb=1.154±0.004 in 1988, (Véron et al., 1993), 206Pb/207Pb=1.155±0.004 in 1989, and Hamelin et al. [1996] (206Pb/207Pb=1.158±0.006) in 1991. Short-term variations of continental air mass sources was particularly investigated by considering the anthropogenic character of aerosols collected during two Lagrangian experiments conducted as part of the ASTEX-MAGE cruise. We demonstrated the utility of stable lead isotopes to assign a "continental source signature" (or mixture thereof) to air masses beyond that normally possible by conventional air mass trajectory analysis in remote oceanic regions.

  1. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins.

  2. Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-01-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  3. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

    2014-01-01

    The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

  4. An effective indicator of continental scale cold air outbreaks in northern winter: the intensity variation of the meridional mass circulation

    NASA Astrophysics Data System (ADS)

    Ren, R.; Yu, Y.; Cai, M.

    2015-12-01

    This study reports that the intensity variation of the meridional mass circulation can be an effective leading indicator of cold air outbreaks (CAOs) over midlatitudes in northern winter. It is found that continental-scale coldness by cold air outbreaks (CAOs) tend to preferentially occur within a week after stronger mass circulation events defined as the peak time when the net mass transport across 60°N in the upper warm or the lower cold air branch exceeds ~88×109 kg s-1. During weaker mass circulation events when the net mass transport across 60°N is below ~71.6×109 kg s-1, most areas of the mid-latitudes are generally in mild condition except the northern part of Western Europe. Composite pattern of circulation anomalies during stronger mass circulation events greatly resemble that of the winter-mean, with the two main routes of anomalous cold air outbreaks being along the climatological routes of polar cold air, namely, via East Asia and North America. The Siberian High shifts westward during stronger mass circulation events, opening up a third route of cold air outbreaks through Eastern Europe. The relationship of CAOs with Arctic Oscillation (AO) is less robust because temporal changes of AO are resulted from a small imbalance between the poleward and equatorward branches of the mass circulation. Only when the poleward branch leads the equatorward branch (44% of all cases), CAOs tend to take place within a week after a negative phase of AO. The daily ERA-Interim reanalysis data set for the 32 winters in 1979-2011 were used in this study.

  5. Air mass modification over Europe: EARLINET aerosol observations from Wales to Belarus

    NASA Astrophysics Data System (ADS)

    Wandinger, Ulla; Mattis, Ina; Tesche, Matthias; Ansmann, Albert; BöSenberg, Jens; Chaikovski, Anatoly; Freudenthaler, Volker; Komguem, Leonce; Linné, Holger; Matthias, Volker; Pelon, Jacques; Sauvage, Laurent; Sobolewski, Piotr; Vaughan, Geraint; Wiegner, Matthias

    2004-12-01

    For the first time, the vertically resolved aerosol optical properties of western and central/eastern European haze are investigated as a function of air mass transport. Special emphasis is put on clean maritime air masses that cross the European continent from the west and become increasingly polluted on their way into the continent. The study is based on observations at seven lidar stations (Aberystwyth, Paris, Hamburg, Munich, Leipzig, Belsk, and Minsk) of the European Aerosol Research Lidar Network (EARLINET) and on backward trajectory analysis. For the first time, a lidar network monitored continent-scale haze air masses for several years (since 2000). Height profiles of the particle backscatter coefficient and the particle optical depth of the planetary boundary layer (PBL) at 355-nm wavelength are analyzed for the period from May 2000 to November 2002. From the observations at Aberystwyth, Wales, the aerosol reference profile for air entering Europe from pristine environments was determined. A mean 355-nm optical depth of 0.05 and a mean PBL height of 1.5 km was found for clean maritime summer conditions. The particle optical depth and PBL height increased with increasing distance from the North Atlantic. Mean summer PBL heights were 1.9-2.8 km at the continental sites of Leipzig, Belsk, and Minsk. Winter mean PBL heights were mostly between 0.7 and 1.3 km over the seven EARLINET sites. Summer mean 355-nm optical depths increased from 0.17 (Hamburg, northwesterly airflow from the North Sea) and 0.21 (Paris, westerly flow from the Atlantic) over 0.33 (Hamburg, westerly flow) and 0.35 (Leipzig, westerly flow) to 0.59 (Belsk, westerly flow), and decreased again to 0.37 (westerly flow) at Minsk. Winter mean optical depths were, on average, 10-30% lower than the respective summer values. PBL-mean extinction coefficients were of the order of 200 Mm-1 at 355 nm at Hamburg and Leipzig, Germany, and close to 600 Mm-1 at Belsk, Poland, in winter for westerly flows

  6. An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

    NASA Astrophysics Data System (ADS)

    Zander, R.; Messina, A.; Godek, M. L.

    2012-12-01

    The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

  7. Using Lidar, in-situ measurements and Trajectory Analysis to observe air pollution in Beijing, 2014

    NASA Astrophysics Data System (ADS)

    Chen, Zhenyi; Liu, Wenqing; Liu, Jianguo; Zhang, Tianshu; Dong, Yunsheng

    2016-06-01

    We present combined Mie lidar, ozone lidar and wide-range particle spectrometer observations that were carried out in Beijing, north China during two periods—one haze period before the Asia-Pacific Economic Cooperation (APEC) meeting and one moderate pollution period during the meeting in 2014. High extinction coefficient, moderate ozone concentration and variable particle number concentration were obtained throughout the first haze observation period. The mean extinction coefficients in the two pollution periods were 0.52 km-1 and 0.23 km-1, respectively, at 532 nm. The ozone concentration during the first haze phase was more various with higher average value of 49 ppb compared to that in the second pollution observations (32 ppb). The comparison of aerosols and ozone in different heights indicate different pollution sources and complicated ozone process of generation and disappearance. The four-day back trajectories from a HYSPLIT model indicate that the air masses in the lower boundary layer were advected from the densely populated south regions of China and the long pollution transportation passing through northern China.

  8. AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

    EPA Science Inventory

    Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

  9. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  10. Composition of air masses in Fuerteventura (Canary Islands) according to their origins

    SciTech Connect

    Patier, R.F.; Diez Hernandez, P.; Diaz Ramiro, E.; Ballesteros, J.S.; Santos-Alves, S.G. dos

    1994-12-31

    The Centro Nacional de Sanidad Ambiental has among their duties the background atmospheric pollution monitoring in Spain. To do so, the laboratory has set up 6 field stations in the Iberian Peninsula. In these stations, both gaseous and particulate pollutants are currently analyzed. However, there is a lack of data about the atmospheric pollution in the Canary, where they are a very strong influence of natural emissions from sea and the Saharan desert, mixed with anthropogenic ones. Therefore, during the ASTEX/MAGE project the CNSA established a station in Fuerteventura island, characterized by the nonexistence of man-made emissions, to measure some atmospheric pollutants, in order to foresee their origins. In this study, the authors analyzed some pollutants that are used to obtain a clue about the sources of air masses such as gaseous ozone and metallic compounds (vanadium, iron and manganese) in the atmospheric aerosol fractionated by size.

  11. Selected current-use and historic-use pesticides in air and seawater of the Bohai and Yellow Seas, China

    NASA Astrophysics Data System (ADS)

    Zhong, Guangcai; Tang, Jianhui; Xie, Zhiyong; Möller, Axel; Zhao, Zhen; Sturm, Renate; Chen, Yingjun; Tian, Chongguo; Pan, Xiaohui; Qin, Wei; Zhang, Gan; Ebinghaus, Ralf

    2014-01-01

    Consumption of pesticides in China has increased rapidly in recent years; however, occurrence and fate of current-use pesticides (CUPs) in China coastal waters are poorly understood. Globally banned pesticides, so-called historic-use pesticides (HUPs), are still commonly observed in the environment. In this work, air and surface seawater samples taken from the Bohai and Yellow Seas in May 2012 were analyzed for CUPs including trifluralin, quintozene, chlorothalonil, dicofol, chlorpyrifos, and dacthal, as well as HUPs (hexachlorobenzene (HCB), hexachlorocyclohexanes (HCHs), and endosulfan). CUP profile in both air and seawater samples generally reflected their consumption patterns in China. HUPs in the air and seawater samples were in comparable levels as those of CUPs with high concentrations. α-Endosulfan, dicofol, and chlorothalonil showed strong net deposition likely resulting from their intensive use in recent years, while CUPs with low consumption amount (quintozene and dacthal) were close to equilibrium at most samplings sites. Another CUP with high usage amout (i.e., chlorpyrifos) underwent volatilization possibly due to its longer half-life in seawater than that in air. α-HCH and γ-HCH were close to equilibrium in the Bohai Sea, but mainly underwent net deposition in the Yellow Sea. The net deposition of α-HCH could be attributed to polluted air pulses from the East China identified by air mass back trajectories. β-HCH showed net volatilization in the Bohai Sea, which was driven by its relative enrichment in seawater. HCB either slightly favored net volatilization or was close to equilibrium in the Bohai and Yellow Seas.

  12. The influence of polarization on box air mass factors for UV/vis nadir satellite observations

    NASA Astrophysics Data System (ADS)

    Hilboll, Andreas; Richter, Andreas; Rozanov, Vladimir V.; Burrows, John P.

    2015-04-01

    Tropospheric abundances of pollutant trace gases like, e.g., NO2, are often derived by applying the differential optical absorption spectroscopy (DOAS) method to space-borne measurements of back-scattered and reflected solar radiation. The resulting quantity, the slant column density (SCD), subsequently has to be converted to more easily interpretable vertical column densities by means of the so-called box air mass factor (BAMF). The BAMF describes the ratio of SCD and VCD within one atmospheric layer and is calculated by a radiative transfer model. Current operational and scientific data products of satellite-derived trace gas VCDs do not include the effect of polarization in their radiative transfer models. However, the various scattering processes in the atmosphere do lead to a distinctive polarization pattern of the observed Earthshine spectra. This study investigates the influence of these polarization patterns on box air mass factors for satellite nadir DOAS measurements of NO2 in the UV/vis wavelength region. NO2 BAMFs have been simulated for a multitude of viewing geometries, surface albedos, and surface altitudes, using the radiative transfer model SCIATRAN. The results show a potentially large influence of polarization on the BAMF, which can reach 10% and more close to the surface. A simple correction for this effect seems not to be feasible, as it strongly depends on the specific measurement scenario and can lead to both high and low biases of the resulting NO2 VCD. We therefore conclude that all data products of NO2 VCDs derived from space-borne DOAS measurements should include polarization effects in their radiative transfer model calculations, or at least include the errors introduced by using linear models in their uncertainty estimates.

  13. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    SciTech Connect

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  14. Study Case of Air-Mass Modification over Poland and Romania Observed by the Means of Multiwavelength Raman Depolarization Lidars

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Janicka, Lucja; Stachlewska, Iwona S.; Nemuc, Anca; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2016-06-01

    An air-mass modification, on its way from Poland to Romania, observed between 19-21 July 2014 is discussed. The air-mass was investigated using data of two multi-wavelength lidars capable of performing regular elastic, depolarization and Raman measurements in Warsaw, Poland, and in Magurele, Romania. The analysis was focused on evaluating optical properties of aerosol in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations within given period.

  15. Large-scale transport of a CO-enhanced air mass from Europe to the Middle East

    NASA Technical Reports Server (NTRS)

    Connors, V. S.; Miles, T.; Reichle, H. G., Jr.

    1989-01-01

    On November 14, 1981, the shuttle-borne Measurement of Air Pollution from Satellites (MAPS) experiment observed a carbon monoxide (CO) enhanced air mass in the middle troposphere over the Middle East. The primary source of this polluted air was estimated by constructing adiabatic isentropic trajectories backwards from the MAPS measurement location over a 36 h period. The isentropic diagnostics indicate that CO-enhanced air was transported southeastward over the Mediterranean from an organized synoptic-scale weather regime, albeit of moderate intensity, influencing central Europe on November 12. Examination of the evolving synoptic scale vertical velocity and precipitation patterns during this period, in conjuction with Meteosat visible, infrared, and water vapor imagery, suggests that the presence of this disturbed weather system over Europe may have created upward transport of CO-enhanced air between the boundary-layer and midtropospheric levels, and subsequent entrainment in the large-scale northwesterly jet stream flow over Europe and the Mediterranean.

  16. Numerical Simulation of Air Mass Modification Over the East China Sea during the Winter Season

    NASA Astrophysics Data System (ADS)

    Hsu, Wu-Ron

    Air mass modification over the East China Sea during cold air outbreaks in the winter season was simulated by utilizing a high-resolution numerical model. The model includes most of the major physical processes, such as, surface exchange of heat and moisture between water and air; condensation and evaporation; and vertical turbulent transfer of heat, moisture, and momentum. The simulated convective boundary layer (CBL) consists of a surface layer, a subcloud layer, and a cloud layer. It is capped by an inversion with strong temperature and moisture gradients. Mesoscale cellular convection (MCC) embedded within the convective layer moves along with the mean wind. The average aspect ratio of the cells is 17.5, which agrees with observed aspect ratios for convective cells over the East China Sea. The upward convective motion correlates very well with the appearance of clouds, higher temperature, and higher moisture content in the CBL. The effects of diabatic heating were found to be very important in driving the thermal convection. Without the release of latent heat, the convective layer would be very shallow, and the convective motion would be greatly suppressed. Even though the formulation and dissipation of a cloud is associated with the movement of the resolvable scale MCC, the vertical transport of heat and moisture is achieved mainly by the unresolvable turbulent eddies. The distribution of specific humidity during the passage of the surface front reveals the moisture being pushed upward along the frontal surface as observed. The cold and dry air behind the cold front is quickly modified by strong convection over the warm water surface, especially over the Kuroshio Current. A cloud-free region exists near the coast where the CBL is too shallow for clouds to develop. A layer of stratocumulus forms downstream from the cloud-free region. The depth of the CBL increases toward the Kuroshio Current due to strong heat and moisture fluxes from the water surface. The CBL

  17. Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)

    NASA Astrophysics Data System (ADS)

    Dall'Osto, Manuel; Beddows, David C. S.; Gietl, Johanna K.; Olatunbosun, Oluremi A.; Yang, Xiaoguang; Harrison, Roy M.

    2014-09-01

    There is a paucity of quantitative knowledge on the contributions of non-exhaust (abrasion and re-suspension) sources to traffic emissions. Abrasive emissions can be broadly categorised as tyre wear, brake wear and road dust/road surface wear. Current research often considers road dust and tyre dust as externally mixed particles, the former mainly composed of mineral matter and the latter solely composed of mainly organic matter and some trace elements. The aim of this work was to characterise tyre wear from both laboratory and field studies by using Aerosol Time-Of-Flight Mass Spectrometry (ATOFMS). Real-time single particle chemical composition was obtained from a set of rubber tyres rotating on a metal surface. Bimodal particle number size distributions peaking at 35 nm and 85 nm were obtained from SMPS/APS measurements over the range 6-20,000 nm. ATOFMS mass spectra of tyre wear in the particle size range 200-3000 nm diameter show peaks due to exo-sulphur compounds, nitrate, Zn and ions of high molecular weight (m/z > 100) attributed to organic polymers. Two large ATOFMS datasets collected from a number of outdoor studies were examined. The former was constituted of 48 road dust samples collected on the roads of London. The latter consisted of ATOFMS ambient air field studies from Europe, overall composed of more than 2,000,000 single particle mass spectra. The majority (95%) of tyre wear particles present in the road dust samples and atmospheric samples are internally mixed with metals (Li, Na, Ca, Fe, Ti), as well as phosphate. It is concluded that the interaction of tyres with the road surface creates particles internally mixed from two sources: tyre rubber and road surface materials. Measurements of the tyre rubber component alone may underestimate the contribution of tyre wear to concentrations of airborne particulate matter. The results presented are especially relevant for urban aerosol source apportionment and PM2.5 exposure assessment.

  18. Air/water subchannel measurements of the equilibrium quality and mass-flux distribution in a rod bundle. [BWR

    SciTech Connect

    Sterner, R.W.; Lahey, R.T. Jr.

    1983-07-01

    Subchannel measurements were performed in order to determine the equilibrium quality and mass flux distribution in a four rod bundle, using air/water flow. An isokinetic technique was used to sample the flow in the center, side and corner subchannels of this test section. Flow rates of the air and water in each sampled subchannel were measured. Experiments were performed for two test-section-average mass fluxes (0.333x10/sup 6/ and 0.666x10/sup 6/ lb/sub m//h-ft/sup 2/), and the test-section-average quality was varied from 0% to 0.54% for each mass flux. Single-phase liquid, bubbly, slug and churn-turbulent two-phase flow regimes were achieved. The observed data trends agreed with previous diabatic measurements in which the center subchannel had the highest quality and mass flux, while the corner subchannel had the lowest.

  19. Chemical trends in background air quality and the ionic composition of precipitation for the period 1980-2004 from samples collected at Valentia Observatory, Co. Kerry, Ireland.

    PubMed

    Bashir, Wasim; McGovern, Frank; O'Brien, Phillip; Ryan, Margaret; Burke, Liam; Paull, Brett

    2008-06-01

    A major Irish study, based upon more than 8000 samples collected over the measurement period of 22 years, for sulfur dioxide (SO2-S), sulfate (SO4-S) and nitrogen dioxide (NO2-N) concentrations (microg m(-3)) within air, and the ionic composition of precipitation samples based on sodium (Na+), potassium (K+), magnesium (Mg2+), calcium (Ca2+), chloride (Cl-), sulfate (SO4-S), non-sea salt sulfate (nssSO4-S), ammonium (NH4-N), and nitrate (NO3-N) weighted mean concentrations (mg l(-1)), has been completed. For the air samples, the sulfur dioxide and sulfate concentrations decreased over the sampling period (1980-2004) by 75% and 45%, respectively, whereas no significant trend was observed for nitrogen dioxide. The highest concentrations for sulfur dioxide, sulfate and nitrogen dioxide were associated with wind originating from the easterly and northeasterly directions i.e. those influenced by Irish and European sources. The lowest concentrations were associated with the westerly directions i.e. for air masses originating in the North Atlantic region. This was further verified with the use of backward (back) trajectory analysis, which allowed tracing the movement of air parcels using the European Centre for Medium range Weather Forecasting (ECMWF) ERA-40 re-analysis data. High non-sea salt sulfate levels were being associated with air masses originating from Europe (easterlies) with lower levels from the Atlantic (westerlies). With the precipitation data, analysis of the non-sea salt sulfate concentrations showed a decrease by 47% since the measurements commenced.

  20. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 3

    NASA Technical Reports Server (NTRS)

    Blakeslee, A. E.; Hovel, H. J.; Woodall, J. M.

    1977-01-01

    The etch-back epitaxy process is described for producing thin, graded composition GaAlAs layers. The palladium-aluminum contact system is discussed along with its associated problems. Recent solar cell results under simulated air mass zero light and at elevated temperatures are reported and the growth of thin polycrystalline GaAs films on foreign substrates is developed.

  1. On the association between daily mortality and air mass types in Athens, Greece during winter and summer.

    PubMed

    Kassomenos, Pavlos A; Gryparis, Alexandros; Katsouyanni, Klea

    2007-03-01

    In this study, we examined the short-term effects of air mass types on mortality in Athens, Greece. An objective air mass types classification was used, based on meteorological parameters measured at the surface. Mortality data were treated with generalized additive models (GAM) and extending Poisson regression, using a LOESS smoother to control for the confounding effects of seasonal patterns, adjusting also for temperature, long-term trends, day of the week, and ambient particle concentrations. The introduced air mass classification explains the daily variation of mortality to a statistically significant degree. The highest daily mortality was observed on days characterized by southerly flow conditions for both the cold (increase in relative risk for mortality 9%; with a 95% confidence interval: 3-14%), and the warm period (7%; with a 95% confidence interval: 2-13%) of the year. The northeasterly flow is associated with the lowest mortality. Effects on mortality, independent of temperature, are observed mainly for lag 0 during the cold period, but persist longer during the warm period. Not adjusting for temperature and/or ambient particle levels slightly alters the results, which then reflect the known temperature and particle effects, already reported in the literature. In conclusion, we find that air mass types have independent effects on mortality for both the cold and warm season and may be used to predict weather-related adverse health effects.

  2. Quantifying the contribution of long-range transport to Particulate Matter (PM) mass loadings at a suburban site in the North-Western Indo Gangetic Plain (IGP)

    NASA Astrophysics Data System (ADS)

    Pawar, H.; Garg, S.; Kumar, V.; Sachan, H.; Arya, R.; Sarkar, C.; Chandra, B. P.; Sinha, B.

    2015-04-01

    Many sites in the densely populated Indo Gangetic Plain (IGP) frequently exceed the national ambient air quality standard (NAAQS) of 100 μg m-3 for 24 h average PM10 and 60 μg m-3 for 24 h average PM2.5 mass loadings, exposing residents to hazardous levels of PM throughout the year. We quantify the contribution of long range transport to elevated PM levels and the number of exceedance events through a back trajectory climatology analysis of air masses arriving at the IISER Mohali Atmospheric Chemistry facility (30.667° N, 76.729° E; 310 m a.m.s.l.) for the period August 2011-June 2013. Air masses arriving at the receptor site were classified into 6 clusters, which represent synoptic scale air mass transport patterns and the average PM mass loadings and number of exceedance events associated with each air mass type were quantified for each season. Long range transport from the west leads to significant enhancements in the average coarse mode PM mass loadings during all seasons. The contribution of long range transport from the west and south west (Source region: Arabia, Thar desert, Middle East and Afghanistan) to coarse mode PM varied between 9 and 57% of the total PM10-2.5 mass. Local pollution episodes (wind speed < 1 m s-1) contributed to enhanced coarse mode PM only during winter season. South easterly air masses (Source region: Eastern IGP) were associated with significantly lower coarse mode PM mass loadings during all seasons. For fine mode PM too, transport from the west usually leads to increased mass loadings during all seasons. Local pollution episodes contributed to enhanced PM2.5 mass loadings during winter and summer season. South easterly air masses were associated with significantly lower PM2.5 mass loadings during all seasons. Using simultaneously measured gas phase tracers we demonstrate that most PM2.5 originated from combustion sources. The fraction of days in each season during which the PM mass loadings exceeded the national ambient air

  3. The impact of mass flow and masking on the pressure drop of air filter in heavy-duty diesel engine

    NASA Astrophysics Data System (ADS)

    Hoseeinzadeh, Sepideh; Gorji-Bandpy, Mofid

    2012-04-01

    This paper presents a computational fluid dynamics (CFD) calculation approach to predict and evaluate the impact of the mass-flow inlet on the pressure drop of turbocharger`s air filtfer in heavy-duty diesel engine. The numerical computations were carried out using a commercial CFD program whereas the inlet area of the air filter consisted of several holes connected to a channel. After entering through the channel, the air passes among the holes and enters the air filter. The effect of masking holes and hydraulic diameter is studied and investigated on pressure drop. The results indicate that pressure drop increase with decreasing of hydraulic diameter and masking of the holes has considerable affect on the pressure drop.

  4. Background NO/sub x/ mixing ratios in air masses over the North Atlantic ocean

    SciTech Connect

    Helas, G.; Warneck, P.

    1981-08-20

    A chemiluminescence analyzer was used to measure NO/sub x/ mixing ratios at the west coast of Ireland. Two measurement modes allowed the determination of NO and NO/sub x/ = NO+NO/sub 2/. In a third mode using a molybdenum converter, higher signals were observed than was in the second mode indicating that nitrogen compounds other than NO+NO/sub 2/ are registered. They are denoted 'excess NO/sub x/'. The average NO/sub 2/ mixing ratio for a week period was 101 +- 87 pptv. In pure marine air masses identified by means of trajectory calculations, the NO/sub 2/ mixing ratios were lower and exhibited in addition a diurnal variation with nighttime values of 37 +- 6 pptv and average values of 87 +- 47 pptv. Possible origins of the diurnal variation are discussed. For such conditions, the NO mixing ratio generally was unmeasurably small, certainly less than 10 pptv. The excess NO/sub x/ is also higher during the day compared with nighttime values of about 70 pptv. Further studies are required to identify the compounds involved.

  5. Northern East Asian Monsoon Precipitation Revealed by Air Mass Variability and Its Prediction

    NASA Astrophysics Data System (ADS)

    Son, J. H.; Seo, K. H.

    2015-12-01

    This work provides a new perspective on the major factors controlling the East Asian summer monsoon (EASM) in July, and a promising physical-statistical forecasting of the EASM ahead of summer. Dominant modes of the EASM are revealed from the variability of large-scale air masses discerned by equivalent potential temperature, and are found to be dynamically connected with the anomalous sea surface temperatures (SSTs) over the three major oceans of the world and their counterparts of prevailing atmospheric oscillation or teleconnection patterns. Precipitation over Northeast Asia (NEA) during July is enhanced by the tropical central Indian Ocean warming and central Pacific El Niño-related SST warming, the northwestern Pacific cooling off the coast of NEA, and the North Atlantic Ocean warming. Using these factors and data from the preceding spring seasons, the authors build a multiple linear regression model for seasonal forecasting. The cross-validated correlation skill predicted for the period 1994 to 2012 is up to 0.84, which far exceeds the skill level of contemporary climate models.

  6. Inverse Estimation of SO2 Emissions over China with Local Air Mass Factor Applied

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Wang, J.; Xu, X.; Henze, D. K.

    2015-12-01

    Sulfur dioxide (SO2) has significant impacts on human health as it forms sulfate aerosols in the atmosphere. Widespread uncertainty in the magnitude of SO2 emissions hinders efforts to address this issue. In this work we use Ozone Monitoring Instrument (OMI) slant column SO2 observations as constraints to conduct inversion of SO2 emissions over China for April 2008. Local air mass factors are formulated as the integral of the relative vertical distribution of SO2 simulated from GEOS-Chem, weighted by scattering weights computed from VLIDORT. They are applied to convert slant column to vertical column GEOS-Chem SO2. After data assimilation SO2 emissions decrease in Sichuan Basin, South China, and most areas of North China. The posterior SO2 emissions are evaluated with in situ SO2 observation. Besides, we apply the posterior SO2 emissions of April 2008 to April 2009, and it leads to improved agreement of modeled SO2 to the OMI observations. This offers potential to update SO2 emissions in real time.

  7. Variations of the glacio-marine air mass front in West Greenland through water vapor isotopes

    NASA Astrophysics Data System (ADS)

    Kopec, B. G.; Lauder, A. M.; Posmentier, E. S.; Feng, X.

    2012-12-01

    While the isotopic distribution of precipitation has been widely used for research in hydrology, paleoclimatology, and ecology for decades, intensive isotopic studies of atmospheric water vapor has only recently been made possible by spectral-based technology. New instrumentation based on this technology opens up many opportunities to investigate short-term atmospheric dynamics involving the water cycle and moisture transport. We deployed a Los Gatos Water Vapor Isotope Analyzer (WVIA) at Kangerlussuaq, Greenland from July 21 to August 15, and measured the water vapor concentration and its isotopic ratios continuously at 10s intervals. A Danish Meteorological Institute site is located about 1 km from the site of the deployment, and meteorological data is collected at 30 min intervals. During the observation period, the vapor concentration of the ambient air ranges from 5608.4 to 11189.4 ppm; dD and d18O range from -254.5 to -177.7 ‰ and -34.2 to -23.2 ‰, respectively. The vapor content (dew point) and the isotopic ratios are both strongly controlled by the wind direction. The easterly winds are associated with dry, isotopically depleted air masses formed over the glacier, while westerly winds are associated with moist and isotopically enriched air masses from the marine/fjord surface. This region typically experiences katabatic winds off of the ice sheet to the east. However, during some afternoons, the wind shifts 180 degrees, blowing off the fjord to the west. This wind switch marks the onset of a sea breeze, and significant isotopic enrichment results. Enrichment in deuterium is up to 60 ‰ with a mean of 15‰, and oxygen-18 is enriched by 3‰ on average and up to 8 ‰. Other afternoons have no change in wind, and only small changes in humidity and vapor isotopic ratios. The humidity and isotopic variations suggest the local atmosphere circulation is dominated by relatively high-pressure systems above the cold glaciers and cool sea surface, and diurnal

  8. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    SciTech Connect

    Morrison, Glenn Charles

    1999-12-01

    -7, 10-5, and 10-5 respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10-5, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.

  9. Change of microbial communities in glaciers along a transition of air masses in western China

    NASA Astrophysics Data System (ADS)

    Xiang, Shu-Rong; Chen, Yong; Shang, Tian-Cui; Jing, Ze-Fan; Wu, Guangjian

    2010-12-01

    Microbial community dynamics across glaciers in different climatic zones provide important information about the sources, transportation pathways, and deposition of microorganisms. To better understand the possible driving forces of microbial community shifts in glacier ice at a large spatial scale, 16S rRNA gene amplification was used to establish clone libraries containing 95 bacterial sequences from three different habitats in the Qiangyong Gacier in 2005. The libraries were used in phylogenetic comparison with 149 previously reported sequences from the surface samples collected from the Kuytun 51, and East Rongbuk glaciers in the same year. The results showed the presence of cosmopolitan and endemic species, and displayed a tendency of zonal distribution of bacterial communities at genera and community levels, corresponding to the geographic placement of the three glaciers. Data also showed a significant difference in the proportion of dominant phylogenetic groups in the three glaciers. Comamonadaceae/Polaromonas (Betaproteobacteria) and Flexibacteraceae (Bacteroidetes) were dominant in the Qiangyong Glacier, Cyanobacteria, Comamonadaceae/Polaromonas, and Rhodoferax (Betaproteobacteria) were dominant in the Kuytun 51 Glacier, and Acinetobacteria (Gammaproteobacteria) were dominant in the Rongbuk Glacier. In conclusion, the current study provides evidence of microbial biogeography in glacier ice at both the fine lineage and whole community levels. The biogeographical patterns were generally associated with the hydrological transition over the glaciers in the northern periphery and southern part of the Tibetan plateau. This supports our hypothesis of air mass behavior being one of the main drivers determining the zonal distribution of microbial communities across the mountain glaciers in western China.

  10. Climatology of wintertime long-distance transport of surface-layer air masses arriving urban Beijing in 2001-2012

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xiang-De, XU

    2017-02-01

    In this study, the FLEXPART-WRF coupled modeling system is used to conduct 12-year Lagrangian modeling over Beijing, China, for the winters of 2001-2012. Based on large trajectory tracking ensembles, the long-range air transport properties, in terms of geographic source regions within the atmospheric planetary boundary layer (PBL) and large-scale ventilation, and its association with air quality levels were quantified from a climatological perspective. The results show the following: (1) The air masses residing in the near-surface layer over Beijing potentially originate from broader atmospheric boundary-layer regions, which cover vast areas with the backward tracking time elapsed. However, atmospheric transport from northeastern China and, to a lesser extent, from the surrounding regions of Beijing is important. (2) The evolution of air quality over Beijing is negatively correlated with large-scale ventilation conditions, particularly at a synoptic timescale. Thus, the simple but robust backward-trajectory ventilation (BV) index defined in this study could facilitate operational forecasting of severe air pollution events. (3) By comparison, the relatively short-range transport occurring over transport timescales of less than 3 days from southern and southeastern Beijing and its surrounding areas plays a vital role in the formation of severe air pollution events during the wintertime. (4) Additionally, an interannual trend analysis suggests that the geographic sources and ventilation conditions also changed, at least over the last decade, corresponding to the strength variability of the winter East Asian monsoon.

  11. Study of the Tropospheric Aerosol Structure Under Changing of the Air Mass Type from Lidar Observations in Tomsk

    NASA Astrophysics Data System (ADS)

    Samoilova, S. V.; Balin, Yu. S.; Kokhanenko, G. P.; Penner, I. É.

    2016-04-01

    The aerosol optical characteristics in the main tropospheric layers are investigated based on joint interpretation of data of multi-frequency lidar sensing (110 sessions) and results of modeling of back air mass trajectories. Methodical problems for separating layers with different scattering properties and estimating their vertical boundaries are considered. Three optical criteria are simultaneously used to distinguish aerosol layers from cloud formations, including the gradient of the backscattering coefficient, optical depth, and the depolarization ratio. High values of the lidar ratio (66 sr) and of the Angstrom exponent (1.62) in the shortwavelength spectral range are observed in the boundary layer for Arctic transport. At the same time, low values of these optical parameters are characteristic for Asian transport: the lidar ratio is 54 sr and the Angstrom exponent is 1.1, which is explained by different relative contributions of the coarse and fine aerosol fractions to the air mass.

  12. Simultaneous determination of aliphatic and aromatic amines in ambient air and airborne particulate matters by gas chromatography-mass spectrometry

    NASA Astrophysics Data System (ADS)

    Akyüz, Mehmet

    2008-05-01

    A gas chromatography-mass spectrometry (GC-MS) method has been proposed for the simultaneous determination of aliphatic and aromatic amines in ambient air and airborne particulate matters (PMs). The method includes collection of the particulate matters (PM2.5 and PM10) using dichotomous Partisol 2025 sampler followed by extraction of the compounds into acidic solution, and pre-concentration of the compounds by percolating the air samples through the acidic solution, then ion-pair extraction of amines with bis-2-ethylhexylphosphate and derivatisation with isobutyl chloroformate prior to their GC-MS analysis in both electron impact and positive and negative ion chemical ionisation mode as their isobutyloxycarbonyl (isoBOC) derivatives. In the present study, ambient air and airborne particulate samples collected in Zonguldak province during summer and winter times of 2006-2007 were analysed for aliphatic and aromatic amines by the proposed method and the method was shown to be suitable for the simultaneous determination of these compounds at the levels of pg m-3 in air and airborne particulate samples. The seasonal distributions of bioactive amines in concentrations in ambient air and airborne PMs were evaluated as they are significant for the estimation of their effects on the environment and human health. The concentration levels of water soluble amines fluctuate significantly within a year with higher means and peak concentrations, probably due to the increased emissions from coal-fired domestic and central heating, in the winter times compared to the summer times. The results indicated that the relative amine content in particulates modulates with molecular mass and time of the year and the relative amine content especially in fine fractions of inhalable airborne particulates increases with the molecular mass of species but decreases with temperature.

  13. Calculations of relative optical air masses for various aerosol types and minor gases in Arctic and Antarctic atmospheres

    NASA Astrophysics Data System (ADS)

    Tomasi, Claudio; Petkov, Boyan H.

    2014-02-01

    The dependence functions of relative optical air mass on apparent solar zenith angle θ have been calculated over the θ < 87° range for the vertical profiles of wet-air molecular number density in the Arctic and Antarctic atmospheres, extinction coefficients of different aerosol types, and molecular number density of water vapor, ozone, nitrogen dioxide, and oxygen dimer. The calculations were made using as weight functions the seasonal average vertical profiles of (i) pressure and temperature derived from multiyear sets of radiosounding measurements performed at Ny-Ålesund, Alert, Mario Zucchelli, and Neumayer stations; (ii) volume extinction coefficients of background summer aerosol, Arctic haze, and Kasatochi and Pinatubo volcanic aerosol measured with lidars or balloon-borne samplings; and (iii) molecular number concentrations of the above minor gases, derived from radiosonde, ozonesonde, and satellite-based observations. The air mass values were determined using a formula based on a realistic atmospheric air-refraction model. They were systematically checked by comparing their mutual differences with the uncertainties arising from the seasonal and daily variations in pressure and temperature conditions within the various ranges, where aerosol and gases attenuate the solar radiation most efficiently. The results provide evidence that secant-approximated and midlatitude air mass values are inappropriate for analyzing the Sun photometer measurements performed at polar sites. They indicate that the present evaluations can be reliably used to estimate the aerosol optical depth from the Arctic and Antarctic measurements of total optical depth, after appropriate corrections for the Rayleigh scattering and gaseous absorption optical depths.

  14. Screening for sarin in air and water by solid-phase microextraction-gas chromatography-mass spectrometry.

    PubMed

    Schneider, J F; Boparai, A S; Reed, L L

    2001-10-01

    A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 microg/mL or higher. This method is ideal for screening samples for quick response situations.

  15. Screening for sarin in air and water by solid-phase microextraction-gas chromatography/mass spectrometry.

    SciTech Connect

    Schneider, J. F.; Boparai, A. S.; Reed, L. L.

    2001-10-01

    A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 {mu}g/mL or higher. This method is ideal for screening samples for quick response situations.

  16. Mass

    SciTech Connect

    Quigg, Chris

    2007-12-05

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  17. On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2013-02-01

    Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

  18. On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2014-02-01

    Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

  19. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

    PubMed Central

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-01-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

  20. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

    PubMed

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-11-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

  1. Constraining aerosol optical models using ground-based, collocated particle size and mass measurements in variable air mass regimes during the 7-SEAS/Dongsha experiment

    NASA Astrophysics Data System (ADS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Hsu, N. Christina; Lin, Neng-Huei; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2013-10-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment (λ = 550 nm) for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulfate, nitrate, and elemental carbon. Achieving full optical closure is hampered by limitations in accounting for the role of water vapor in the system, uncertainties in the instruments and the need for further knowledge in the source apportionment of the model's major chemical components. Nonetheless, our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulfate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Consistency between the measured and modeled optical parameters serves as an

  2. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  3. New air Cherenkov light detectors to study mass composition of cosmic rays with energies above knee region

    NASA Astrophysics Data System (ADS)

    Tsunesada, Yoshiki; Katsuya, Ryoichi; Mitsumori, Yu; Nakayama, Keisuke; Kakimoto, Fumio; Tokuno, Hisao; Tajima, Norio; Miranda, Pedro; Salinas, Juan; Tavera, Wilfredo

    2014-11-01

    We have installed a hybrid detection system for air showers generated by cosmic rays with energies greater than 3 ×1015 eV at Mount Chacaltaya (5200 m above the sea level), in order to study the mass composition of cosmic rays above the knee region. This detection system comprises an air shower array with 49 scintillation counters in an area of 500 m×650 m, and seven new Cherenkov light detectors installed in a radial direction from the center of the air shower array with a separation of 50 m. It is known that the longitudinal development of a particle cascade in the atmosphere strongly depends on the type of the primary nucleus, and an air shower initiated by a heavier nucleus develops faster than that by a lighter primary of the same energy, because of the differences in the interaction cross-section and the energy per nucleon. This can be measured by detecting the Cherenkov radiation emitted from charged particles in air showers at higher altitudes. In this paper we describe the design and performance of our new non-imaging Cherenkov light detectors at Mount Chacaltaya that are operated in conjunction with the air shower array. The arrival directions and energies of air showers are determined by the shower array, and information about the primary masses is obtained from the Cherenkov light data including the time profiles and lateral distributions. The detector consists of photomultiplier tube (PMT), high-speed ADCs, other control modules, and data storage device. The Cherenkov light signals from an air shower are typically 10-100 ns long, and the waveforms are digitized with a sampling frequency of 1 GHz and recorded in situ without long-distance analog signal transfers. All the Cherenkov light detectors record their time-series data by receiving a triggering signal transmitted from the trigger module of the air shower array, which is fired by a coincidence of shower signals in four neighboring scintillation counters. The optical characteristics of the

  4. Linear and cyclic methylsiloxanes in air by concurrent solvent recondensation-large volume injection-gas chromatography-mass spectrometry.

    PubMed

    Companioni-Damas, E Y; Santos, F J; Galceran, M T

    2014-01-01

    In the present work, a simple and fast method for the analysis of linear and cyclic methylsiloxanes in ambient air based on active sampling combined with gas chromatography - mass spectrometry (GC-MS) was developed. The retention efficiency of five sampling sorbents (activated coconut charcoal, Carbopack B, Cromosorb 102, Cromosorb 106 and Isolute ENV+) was evaluated and Isolute ENV+ was found to be the most effective. A volume of 2700 L of air can be sampled without significant losses of the most volatile methylsiloxanes. To improve the sensitivity of the GC-MS method, concurrent solvent recondensation - large volume injection (CSR-LVI), using volumes up to 30 µl of sample extract, is proposed and limits of quantification down to 0.03-0.45 ng m(-3), good linearity (r>0.999) and precision (RSD %<9%) were obtained. The developed method was applied to the analysis of ambient air. Concentrations of linear and cyclic methylsiloxanes in indoor air ranging from 3.9 to 319 ng m(-3) and between 48 and 292668 ng m(-3), were obtained, respectively, while levels from 6 to 22 ng m(-3) for linear and between 2.2 and 439 ng m(-3) for cyclic methylsiloxanes in outdoor air from Barcelona (Spain), were found.

  5. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-03-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. OMI observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the tropospheric NO2 AMF calculation by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model for cloud-free scenes. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation (SD) of the difference was 0.6 ± 8%. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 72% of the daily OMAERUV AOD observations were within 0.3 of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10% higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30%, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and explicit aerosol parameters is on average 6 and 3

  6. Structural uncertainty in air mass factor calculation for NO2 and HCHO satellite retrievals

    NASA Astrophysics Data System (ADS)

    Lorente, Alba; Folkert Boersma, K.; Yu, Huan; Dörner, Steffen; Hilboll, Andreas; Richter, Andreas; Liu, Mengyao; Lamsal, Lok N.; Barkley, Michael; De Smedt, Isabelle; Van Roozendael, Michel; Wang, Yang; Wagner, Thomas; Beirle, Steffen; Lin, Jin-Tai; Krotkov, Nickolay; Stammes, Piet; Wang, Ping; Eskes, Henk J.; Krol, Maarten

    2017-03-01

    Air mass factor (AMF) calculation is the largest source of uncertainty in NO2 and HCHO satellite retrievals in situations with enhanced trace gas concentrations in the lower troposphere. Structural uncertainty arises when different retrieval methodologies are applied within the scientific community to the same satellite observations. Here, we address the issue of AMF structural uncertainty via a detailed comparison of AMF calculation methods that are structurally different between seven retrieval groups for measurements from the Ozone Monitoring Instrument (OMI). We estimate the escalation of structural uncertainty in every sub-step of the AMF calculation process. This goes beyond the algorithm uncertainty estimates provided in state-of-the-art retrievals, which address the theoretical propagation of uncertainties for one particular retrieval algorithm only. We find that top-of-atmosphere reflectances simulated by four radiative transfer models (RTMs) (DAK, McArtim, SCIATRAN and VLIDORT) agree within 1.5 %. We find that different retrieval groups agree well in the calculations of altitude resolved AMFs from different RTMs (to within 3 %), and in the tropospheric AMFs (to within 6 %) as long as identical ancillary data (surface albedo, terrain height, cloud parameters and trace gas profile) and cloud and aerosol correction procedures are being used. Structural uncertainty increases sharply when retrieval groups use their preference for ancillary data, cloud and aerosol correction. On average, we estimate the AMF structural uncertainty to be 42 % over polluted regions and 31 % over unpolluted regions, mostly driven by substantial differences in the a priori trace gas profiles, surface albedo and cloud parameters. Sensitivity studies for one particular algorithm indicate that different cloud correction approaches result in substantial AMF differences in polluted conditions (5 to 40 % depending on cloud fraction and cloud pressure, and 11 % on average) even for low

  7. International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

    PubMed

    Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

    2014-08-05

    Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

  8. Stability of reference masses: VII. Cleaning methods in air and vacuum applied to a platinum mass standard similar to the international and national kilogram prototypes

    NASA Astrophysics Data System (ADS)

    Cumpson, Peter J.; Sano, Naoko; Barlow, Anders J.; Portoles, Jose F.

    2013-10-01

    Mercury contamination and the build-up of carbonaceous contamination are two contributing factors to the instability observed in kilogram prototype masses. The kilogram prototypes that lie at the core of the dissemination of the SI base unit were manufactured in the late 19th century, and have polished surfaces. In papers IV and V of this series we developed a method for cleaning noble metal mass standards in air to remove carbonaceous contamination. At the core of this ‘UVOPS’ protocol is the application of UV light and ozone gas generated in situ in air. The precise nature of the carbonaceous contamination that builds up on such surfaces is difficult to mimic demonstrably or quickly on new test surfaces, yet data from such tests are needed to provide the final confidence to allow UVOPS to be applied to a real 19th century kilogram prototype. Therefore, in the present work we have applied the UVOPS method to clean a platinum avoirdupois pound mass standard, ‘RS2’, manufactured in the mid-19th century. This is thought to have been polished in a similar manner to the kilogram prototypes. To our knowledge this platinum surface has not previously been cleaned by any method. We used x-ray photoelectron spectroscopy to identify organic contamination, and weighing to quantify the mass lost at each application of the UVOPS procedure. The UVOPS procedure is shown to be very effective. It is likely that the redefinition of the kilogram will require mass comparisons in vacuum in the years to come. Therefore, in addition to UVOPS a cleaning method for use in vacuum will also be needed. We introduce and evaluate gas cluster ion-beam (GCIB) treatment as a potential method for cleaning reference masses in vacuum. Again, application of this GCIB cleaning to a real artefact, RS2, allows us to make a realistic evaluation of its performance. While it has some attractive features, we cannot recommend it for cleaning mass standards in its present form.

  9. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  10. Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

    NASA Astrophysics Data System (ADS)

    Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

    2012-06-01

    The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

  11. Impact of secondary inorganic aerosol and road traffic at a suburban air quality monitoring station.

    PubMed

    Megido, L; Negral, L; Castrillón, L; Fernández-Nava, Y; Suárez-Peña, B; Marañón, E

    2017-03-15

    PM10 from a suburban site in the northwest of Spain was assessed using data from chemical determinations, meteorological parameters, aerosol maps and five-day back trajectories of air masses. Temporal variations in the chemical composition of PM10 were subsequently related to stationary/mobile local sources and long-range transport stemming from Europe and North Africa. The presence of secondary inorganic species (sulphates, nitrates and ammonium) in airborne particulate matter constituted one of the main focuses of this study. These chemical species formed 16.5% of PM10 on average, in line with other suburban background sites in Europe. However, a maximum of 47.8% of PM10 were recorded after several days under the influence of European air masses. Furthermore, the highest values of these three chemical species coincided with episodes of poor air circulation and influxes of air masses from Europe. The relationship between SO4(2-) and NH4(+) (R(2) = 0.57, p-value<0.01) was found to improve considerably in summer and spring (R(2) = 0.88 and R(2) = 0.87, respectively, p-value<0.01), whereas NO3(-) and NH4(+) (R(2) = 0.55, p-value<0.01) reproduced this pattern in winter (R(2) = 0.91, p-value<0.01). The application of a receptor model to the dataset led to the identification of notable apportionments due to road traffic and other types of combustion processes. In fact, large amounts of particulate matter were released to the atmosphere during episodes of biomass burning in forest fires. On isolated days, combustion was estimated to contribute up to 21.0 μg PM/m(3) (50.8% of PM10). The contribution from industrial processes to this source is also worth highlighting given the presence of Ni and Co in its profile. Furthermore, African dust outbreaks at the sampling site, characterised by an arc through the Atlantic Ocean, were usually associated with a higher concentration of Al2O3 in PM10. Results evidenced the relevance of stationary (i.e., steelworks and

  12. Effect of humidity and particle hygroscopicity on the mass loading capacity of high efficiency particulate air (HEPA) filters

    SciTech Connect

    Gupta, A.; Biswas, P. ); Monson, P.R. ); Novick, V.J. )

    1993-07-01

    The effect of humidity, particle hygroscopicity, and size on the mass loading capacity of glass fiber high efficiency particulate air filters was studied. Above the deliquescent point, the pressure drop across the filter increased nonlinearly with areal loading density (mass collected/filtration area) of a NaCl aerosol, thus significantly reducing the mass loading capacity of the filter compared to dry hygroscopic or nonhygroscopic particle mass loadings. The specific cake resistance K[sub 2] was computed for different test conditions and used as a measure of the mass loading capacity. K[sub 2] was found to decrease with increasing humidity for nonhygroscopic aluminum oxide particles and for hygroscopic NaCl particles (at humidities below the deliquescent point). It is postulated that an increase in humidity leads to the formation of a more open particulate cake which lowers the pressure drop for a given mass loading. A formula for predicting K[sub 2] for lognormally distributed aerosols (parameters obtained from impactor data) was derived. The resistance factor, R, calculated using this formula was compared to the theoretical R calculated using the Rudnick-Happel expression. For the nonhygroscopic aluminum oxide, the agreement was good but for the hygroscopic sodium chloride, due to large variation in the cake porosity estimates, the agreement was poor. 17 refs., 6 figs., 3 tabs.

  13. Air Superiority at Red Flag: Mass, Technology, and Winning the Next War

    DTIC Science & Technology

    2009-10-01

    improved their estimate. In The Art of Wargaming, Peter Perla suggests that adding exercise analysis could help. He recommends a “continuous cycle...Survey, 44. 45. Ibid., 27–28. 46. “Desert Shield Tactical Air Force Combat Losses, Damage, and Muni- tions Consumption.” 47. Ibid. 48. Perla , Art of...Williamson. Strategy for Defeat: The Luftwaffe, 1933– 1945, 1983. Reprint. Maxwell AFB, AL: Air University Press, 2007. Perla , Peter P. The Art of Wargaming

  14. Micrometeorological Measurement of Fetch- and Atmospheric Stability-Dependent Air- Water Exchange of Legacy Semivolatile Organic Contaminants in Lake Superior

    NASA Astrophysics Data System (ADS)

    Perlinger, J. A.; Tobias, D. E.; Rowe, M. D.

    2008-12-01

    one of the four trajectories and stable for the other three trajectories. Two of three transects carried out under stable conditions are complicated because, as revealed by back-trajectory analysis, different air masses were sampled at each station, and, for one of these transects, the air masses spent significant portions of time over land. Analyses of legacy pesticide concentrations carried out to date suggest that under stable and unstable conditions, fluxes were out of the lake. We present and compare micrometeorological measurements and two-film estimates of fluxes of legacy pesticides and PCBs.

  15. EPA Air Method, Toxic Organics - 15 (TO-15): Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)

    EPA Pesticide Factsheets

    Method T)-15 describes procedures for for preparation and analysis of air samples containing volatile organic compounds collected in specially-prepared canisters, using gas chromatography-mass spectrometry.

  16. Air mass origin and its influence on radionuclide activities ( 7Be and 210Pb) in aerosol particles at a coastal site in the western Mediterranean

    NASA Astrophysics Data System (ADS)

    Dueñas, C.; Orza, J. A. G.; Cabello, M.; Fernández, M. C.; Cañete, S.; Pérez, M.; Gordo, E.

    2011-07-01

    Studies of radionuclide activities in aerosol particles provide a means for evaluating the integrated effects of transport and meteorology on the atmospheric loadings of substances with different sources. Measurements of aerosol mass concentration and specific activities of 7Be and 210Pb in aerosols at Málaga (36° 43' 40″ N; 4° 28' 8″ W) for the period 2000-2006 were used to obtain the relationships between radionuclide activities and airflow patterns by comparing the data grouped by air mass trajectory clusters. The average concentration values of 7Be and 210Pb over the 7 year period have been found to be 4.6 and 0.58 mBq m -3, respectively, with mean aerosol mass concentration of 53.6 μg m -3. The identified air flow types arriving at Málaga reflect the transitional location of the Iberian Peninsula and show significant differences in radionuclide activities. Air concentrations of both nuclides and the aerosol mass concentration are controlled predominantly by the synoptic scenarios leading to the entrance of dust-laden continental flows from northern Africa and the arrival of polar maritime air masses, as implied by the strong correlations found between the monthly frequencies of the different air masses and the specific activities of both radionuclides. Correlations between activity concentrations and precipitation are significant though lower than with air masses.

  17. Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

    NASA Astrophysics Data System (ADS)

    Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

    2014-08-01

    Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

  18. Thermal desorption-gas chromatography-mass spectrometry method to determine phthalate and organophosphate esters from air samples.

    PubMed

    Aragón, M; Borrull, F; Marcé, R M

    2013-08-16

    A method based on thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed to determine four organophosphate esters, seven phthalate esters, and bis(2-ethylhexyl) adipate in the gas phase from harbour and urban air samples. The method involves the sampling of 1.5L of air in a Tenax TA sorbent tube followed by thermal desorption (using a Tenax TA cryogenic trap) coupled to gas chromatography-mass spectrometry. The repeatability of the method expressed as %RSD (n=3) is less than 15% and the MQLs are between 0.007μgm(-3) (DMP, TBP, BBP, TPP and DnOP) and 6.7μgm(-3) (DEHP). The method was successfully applied in two areas (urban and harbour) testing two and three points in each one, respectively. Some of these compounds were found in both urban and harbour samples. Di-(2-ethylhexyl)phthalate was the most abundant compound found in both areas at concentration levels between 6.7μgm(-3) and 136.4μgm(-3). This study demonstrates that thermal desorption is an efficient method for the determination of these semi-volatile compounds in the gas phase fraction of air samples.

  19. Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; Pȩkala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcău, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Curci, G.

    2014-11-01

    The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth τa(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean τa(3.5 km) ∼ 0.04 - and shows a seasonal trend with a winter minimum - τa(3.5 km) ∼ 0.03 -, and a summer maximum - τa(3.5 km) ∼ 0.06 -, and an unexpected increase from August to September - τa(3.5 km) ∼ 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. Average concentrations are affected by continental sources (wind-blown dust and urban pollution), whilst the peak observed in September and October could be linked to biomass burning in the northern part of Argentina or air pollution coming from surrounding urban areas.

  20. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2012-04-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean, a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol (NR-PM1) was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition, small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions, could be identified in the particle phase

  1. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-09-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. Satellite observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the Ozone Monitoring Instrument (OMI) tropospheric NO2 AMF calculation for cloud-free scenes. We do so by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation of the difference was 0.6 ± 8 %. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 68 % of the daily OMAERUV AOD observations were within 30 % of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10 % higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30 %, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and

  2. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

  3. Numerical study of coupled transfer of heat and mass between air and water inside a geothermal water cooling tower

    NASA Astrophysics Data System (ADS)

    Bassem, Mohamed Mehdi; Bourouni, Karim; Thameur Chaibi, Mohamed

    2006-11-01

    In the south of Tunisia, geothermal water is used to irrigate cultures. Since its temperature is very high (70 C), geothermal water is cooled by cooling towers. These towers are sized empirically and present many operating problems such as excessive energy consumption, big loss of vapour and low cooling efficiency. The aim of our work is modelling the coupled heat and mass transfer between air and water inside the cooling tower. The most important results obtained are that the evaporative potential is dominating the convective one in the cooling process. That's why the cooling is more efficient in summer than in hibernal period when humidity of ambient air reaches high values. In other hand, the negative convective phenomenon is illustrated. In fact, at the bottom of the tower, water temperature reaches the air one; the two fluids begin to cooling simultaneously. Air is cooled by convection and water by evaporation. We demonstrate also that there is no point in putting fans in working during cold weather. We studied also the effect of the variation of heat transfer coefficient on the efficiency of cooling.

  4. Petroleum mass removal from low permeability sediment using air sparging/soil vapor extraction: impact of continuous or pulsed operation

    NASA Astrophysics Data System (ADS)

    Kirtland, Brian C.; Aelion, C. Marjorie

    2000-02-01

    Air sparging and soil vapor extraction (AS/SVE) are innovative remediation techniques that utilize volatilization and microbial degradation to remediate petroleum spills from soils and groundwater. This in situ study investigated the use of AS/SVE to remediate a gasoline spill from a leaking underground storage tank (UST) in the low permeability, clayey soil of the Appalachian Piedmont. The objectives of this study were to evaluate AS/SVE in low permeability soils by quantifying petroleum mass removal rates, monitoring vadose zone contaminant levels, and comparing the mass extraction rates of continuous AS/SVE to 8 and 24 h pulsed operation. The objectives were met by collecting AS/SVE exhaust gas samples and vadose zone air from multi-depth soil vapor probes. Samples were analyzed for O 2, CO 2, BTEX (benzene, toluene, ethylbenzene, xylene), and total combustible hydrocarbon (TCH) concentrations using portable hand meters and gas chromatography. Continuous AS/SVE was effective in removing 608 kg of petroleum hydrocarbons from low permeability soil in 44 days (14.3 kg day -1). Mass removal rates ranged from 2.6 times higher to 5.1 times lower than other AS/SVE studies performed in sandy sediments. BTEX levels in the vadose zone were reduced from about 5 ppm to 1 ppm. Ten pulsed AS/SVE tests removed 78 kg in 23 days and the mean mass removal rate (17.6 kg day -1) was significantly higher than the last 15 days of continuous extraction. Pulsed operation may be preferable to continuous operation because of increased mass removal and decreased energy consumption.

  5. Characteristics of individual particles in the atmosphere of Guangzhou by single particle mass spectrometry

    NASA Astrophysics Data System (ADS)

    Zhang, Guohua; Han, Bingxue; Bi, Xinhui; Dai, Shouhui; Huang, Wei; Chen, Duohong; Wang, Xinming; Sheng, Guoying; Fu, Jiamo; Zhou, Zhen

    2015-02-01

    Continuous ambient measurement of atmospheric aerosols was performed with a single particle aerosol mass spectrometer (SPAMS) in Guangzhou during summer of 2012. The aerosols mainly consisted of carbonaceous particles as major compositions in submicrometer range, including K-rich (29.8%), internally mixed organics and elemental carbon (ECOC, 13.5%), organic carbon-rich (OC, 18.5%), elemental carbon (EC, 12.3%) and high molecular OC (HMOC, 3.2%), and inorganic types (e.g., Na-rich Na-K, Fe-rich, V-rich, and Cu-rich) as major ones in supermicrometer range. Results show that carbonaceous particles were commonly internally mixed with sulfate and nitrate through atmospheric processing, in particular, with sulfate; inorganic types were dominantly internally mixed with nitrate rather than sulfate, indicative of different evolution processes for carbonaceous and inorganic particles in the atmosphere. It was observed that variations of these particle types were significantly influenced by air mass back trajectories (BTs). Under the influence of continental BTs, carbonaceous types were prevalent, while Na-K and Na-rich types considerably increased when the BTs originated from south marine regions. Number fraction of carbonaceous types exhibited obvious diurnal variation throughout the sampling period, which reflects their relatively stable emission and atmospheric processes. Two EC particle types LC-EC and NaK-EC showed different diurnal distributions, suggesting their different origins. The obtained information on the mixing state and the temporal variation of particle types is essential for developing an understanding on the origin and evolution processes of atmospheric aerosols.

  6. Ambient air analyses using nonspecific flame ionization and electron capture detection compared to specific detection by mass spectroscopy

    SciTech Connect

    Pleil, J.D.; Oliver, K.D.; McClenny, W.A.

    1988-08-01

    Ambient air samples from various studies were analyzed for a specific set of trace-level volatile organic compounds by using a gas chromatograph (GC) equipped with a flame ionization detector (FID) in parallel with an electron capture detector (ECD). The samples were then reanalyzed on a second GC system equipped with a mass selective detector (MSD). GC-FID/ECD data were compared to the nominally correct GC-MSD data to determine the accuracy of the nonspecific detectors, which often do not differentiate the targeted compound from interfering compounds. Qualitative accuracy (capability for correctly identifying compounds on the basis of retention time only) and quantitative accuracy (capability for correctly measuring the concentration of an identified compound on the basis of peak area) were evaluated. Data are presented on a per-compound basis to provide the combined typical results from air samples collected in three geographic regions: Kanawha Valley, WV; Los Angeles, CA, area; and Houston, TX.

  7. Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

    NASA Astrophysics Data System (ADS)

    Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

    2017-01-01

    A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

  8. Continental Land Mass Air Traffic Control (COLM ATC). [using three artificial satellite configurations

    NASA Technical Reports Server (NTRS)

    Pecar, J. A.; Henrich, J. E.

    1973-01-01

    The application of various satellite systems and techniques relative to providing air traffic control services for the continental United States was studied. Three satellite configurations were reviewed. The characteristics and capabilities of the satellites are described. The study includes consideration for the various ranging waveforms, multiple access alternatives, and the power and bandwidth required as a function of the number of users.

  9. Polyfluorinated compounds in ambient air from ship- and land-based measurements in northern Germany

    NASA Astrophysics Data System (ADS)

    Dreyer, Annekatrin; Ebinghaus, Ralf

    Neutral volatile and semi-volatile polyfluorinated organic compounds (PFC) and ionic perfluorinated compounds were determined in air samples collected at two sites in the vicinity of Hamburg, Germany, and onboard the German research vessel Atair during a cruise in the German Bight, North Sea, in early November 2007. PUF/XAD-2/PUF cartridges and glass fiber filters as sampling media were applied to collect several fluorotelomer alcohols (FTOH), fluorotelomer acrylates (FTA), perfluoroalkyl sulfonamides (FASA), and perfluoroalkyl sulfonamido ethanols (FASE) in the gas- and particle-phase as well as a set of perfluorinated carboxylates (PFCA) and sulfonates (PFSA) in the particle-phase. This study presents the distribution of PFC in ambient air of the German North Sea and in the vicinity of Hamburg for the first time. Average total PFC concentrations in and around Hamburg (180 pg m -3) were higher than those observed in the German Bight (80 pg m -3). In the German Bight, minimum-maximum gas-phase concentrations of 17-82 pg m -3 for ΣFTOH, 2.6-10 pg m -3 for ΣFTA, 10-15 pg m -3 for ΣFASA, and 2-4.4 pg m -3 for ΣFASE were determined. In the vicinity of Hamburg, minimum-maximum gas-phase concentrations of 32-204 pg m -3 for ΣFTOH, 3-26 pg m -3 for ΣFTA, 3-18 pg m -3 for ΣFASA, and 2-15 pg m -3 for ΣFASE were detected. Concentrations of perfluorinated acids were in the range of 1-11 pg m -3. FTOH clearly dominated the substance spectrum; 8:2 FTOH occurred in maximum proportions. Air mass back trajectories, cluster, and correlation analyses revealed that the air mass origin and thus medium to long range atmospheric transport was the governing parameter for the amount of PFC in ambient air. Southwesterly located source regions seemed to be responsible for elevated PFC concentrations, local sources appeared to be of minor importance.

  10. Air quality during the 2008 Beijing Olympics: secondary pollutants and regional impact

    NASA Astrophysics Data System (ADS)

    Wang, T.; Nie, W.; Gao, J.; Xue, L. K.; Gao, X. M.; Wang, X. F.; Qiu, J.; Poon, C. N.; Meinardi, S.; Blake, D.; Wang, S. L.; Ding, A. J.; Chai, F. H.; Zhang, Q. Z.; Wang, W. X.

    2010-08-01

    This paper presents the first results of the measurements of trace gases and aerosols at three surface sites in and outside Beijing before and during the 2008 Olympics. The official air pollution index near the Olympic Stadium and the data from our nearby site revealed an obvious association between air quality and meteorology and different responses of secondary and primary pollutants to the control measures. Ambient concentrations of vehicle-related nitrogen oxides (NOx) and volatile organic compounds (VOCs) at an urban site dropped by 25% and 20-45% in the first two weeks after full control was put in place, but the levels of ozone, sulfate and nitrate in PM2.5 increased by 16%, 64%, 37%, respectively, compared to the period prior to the full control; wind data and back trajectories indicated the contribution of regional pollution from the North China Plain. Air quality (for both primary and secondary pollutants) improved significantly during the Games, which were also associated with the changes in weather conditions (prolonged rainfall, decreased temperature, and more frequent air masses from clean regions). A comparison of the ozone data at three sites on eight ozone-pollution days, when the air masses were from the southeast-south-southwest sector, showed that regional pollution sources contributed >34-88% to the peak ozone concentrations at the urban site in Beijing. Regional sources also contributed significantly to the CO concentrations in urban Beijing. Ozone production efficiencies at two sites were low (~3 ppbv/ppbv), indicating that ozone formation was being controlled by VOCs. Compared with data collected in 2005 at a downwind site, the concentrations of ozone, sulfur dioxide (SO2), total sulfur (SO2+PM2.5 sulfate), carbon monoxide (CO), reactive aromatics (toluene and xylenes) sharply decreased (by 8-64%) in 2008, but no significant changes were observed for the concentrations of PM2.5, fine sulfate, total odd reactive nitrogen (NOy), and longer

  11. Detection of biological particles in ambient air using Bio-Aerosol Mass Spectrometry

    SciTech Connect

    McJimpsey, E L; Steele, P T; Coffee, K R; Fergenson, D P; Riot, V J; Woods, B W; Gard, E E; Frank, M; Tobias, H J; Lebrilla, C

    2006-03-16

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described.

  12. Facility monitoring of chemical warfare agent simulants in air using an automated, field-deployable, miniature mass spectrometer.

    PubMed

    Smith, Jonell N; Noll, Robert J; Cooks, R Graham

    2011-05-30

    Vapors of four chemical warfare agent (CWA) stimulants, 2-chloroethyl ethyl sulfide (CEES), diethyl malonate (DEM), dimethyl methylphosphonate (DMMP), and methyl salicylate (MeS), were detected, identified, and quantitated using a fully automated, field-deployable, miniature mass spectrometer. Samples were ionized using a glow discharge electron ionization (GDEI) source, and ions were mass analyzed with a cylindrical ion trap (CIT) mass analyzer. A dual-tube thermal desorption system was used to trap compounds on 50:50 Tenax TA/Carboxen 569 sorbent before their thermal release. The sample concentrations ranged from low parts per billion [ppb] to two parts per million [ppm]. Limits of detection (LODs) ranged from 0.26 to 5.0 ppb. Receiver operating characteristic (ROC) curves are presented for each analyte. A sample of CEES at low ppb concentration was combined separately with two interferents, bleach (saturated vapor) and diesel fuel exhaust (1%), as a way to explore the capability of detecting the simulant in an environmental matrix. Also investigated was a mixture of the four CWA simulants (at concentrations in air ranging from 270 to 380 ppb). Tandem mass (MS/MS) spectral data were used to identify and quantify the individual components.

  13. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    SciTech Connect

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-18

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22 cm diameter and 30 cm length, purifies an airflow rate of 5000 lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  14. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    NASA Astrophysics Data System (ADS)

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-01

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22cm diameter and 30cm length, purifies an airflow rate of 5000lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  15. Identification of European Air Masses Using an Interactive Computer Technique for Separating Mixed Normal Distributions.

    DTIC Science & Technology

    1982-01-01

    classifying a maritime surface, he refers to the Pacific, Atlantic, or Gulf of Mexico using the general term "maritime" only when the exact origin is...portions of North Atlantic NPA PA air modified over warm North Atlantic TC Southern U.S. and Northern Mexico TG Gulf of Mexico and Caribbean NTG TG...Bergeron, T., 1928: " Uber Die Dreidimensional Verknupfende Wetteranalyse, Teil I." Geofys. Pub!., Vol. 5, No. 6. Berggren, R., 1953: "On Temperature

  16. Measurement of aerosol particles, gases and flux radiation in the Pico de Orizaba National Park, and its relationship to air pollution transport

    NASA Astrophysics Data System (ADS)

    Márquez, C.; Castro, T.; Muhlia, A.; Moya, M.; Martínez-Arroyo, A.; Báez, A.

    Continuous atmospheric measurements were carried out at the Pico de Orizaba National Park (PONP), Mexico, in order to evaluate the characteristics and sources of air quality. This action allowed one to identify specific threats for the effective protection of natural resources and biodiversity. Results show the presence of particles and polluted gases transported by winds from the urban zones nearby (cities of Mexico, Puebla and Tlaxcala), as well as their measurable influence on the optical properties of the park environment. Nitrogen dioxide, carbon monoxide and sulfur dioxide show a daily pattern suggesting an influence of pollution generated by anthropogenic processes. Average concentration of SO 2 was higher than recorded at the southern part of Mexico City. Ozone concentrations ranging from 0.035 to 0.06 ppm suggest residual or background ozone character. Back trajectory analysis of air parcels arriving at the site confirm pollution caused by biomass burning and mass transport from urban zones. The SO 42-/TC ratio exhibited values (0.88±0.33) similar to urban areas. Ratios BC/TC and OC/BC for PONP are similar to those reported as influenced by burning emissions of fossil fuels. Typical rural aerosols were also found at the site, and sulfate and ammonium concentrations were correlated. The most predominating mode in surface particles size distribution was at 0.32 μm with no significant presence of coarse particles. Total carbon (OC+BC) content of fine particle mass (PM less than 1 μm) comprised, on average, 75%. Optical properties retrieved from photometric data show intermittent influence from urban pollution. Time periods with low absorbing particles, great visibility and abundance of small particles alternating with short times with bigger particles and high turbidity indicated by the optical depth.

  17. Properties of individual aerosol particles and their relation to air mass origins in a south China coastal city

    NASA Astrophysics Data System (ADS)

    Shi, Zongbo; He, Kebin; Xue, Zhigang; Yang, Fumo; Chen, Yanju; Ma, Yongliang; Luo, Jiaojiao

    2009-05-01

    Atmospheric particles in urban and rural areas in Shenzhen city were collected in summer and winter 2004. The particles were analyzed using a scanning electron microscope equipped with an energy dispersive X-ray spectrometer. The fine particles (<1 μm) were categorized into chain-like, elongated, rounded, and others on the basis of their morphology. Chain-like particles were likely soot aggregates. In summer and winter, chain-like particles accounted for 43% and 42% of total particles in the urban area, and 22% and 43% in the rural area, respectively. The elongated particles were mixtures of aged sea salts and ammonium sulfate, suggesting an aqueous phase reaction mechanism, i.e., in-cloud sulfate formation. Such particles occupied 12% of total particles in the urban area in the summer and were rarely observed in the wintertime samples. The rounded particles were mainly composed of sulfate and/or carbon. Their number concentration in the urban area was more than three times higher in the winter. In addition, we found that air masses from northern inland contained much higher concentrations of particles than those from the ocean. This was particularly evident in the rural area, where concentrations of chain-like and rounded particles were eight times higher in the continental air masses. These results suggest the strong influence of regional pollution on the particle number concentrations in the coastal city.

  18. An improved, automated whole air sampler and gas chromatography mass spectrometry analysis system for volatile organic compounds in the atmosphere

    NASA Astrophysics Data System (ADS)

    Lerner, Brian M.; Gilman, Jessica B.; Aikin, Kenneth C.; Atlas, Elliot L.; Goldan, Paul D.; Graus, Martin; Hendershot, Roger; Isaacman-VanWertz, Gabriel A.; Koss, Abigail; Kuster, William C.; Lueb, Richard A.; McLaughlin, Richard J.; Peischl, Jeff; Sueper, Donna; Ryerson, Thomas B.; Tokarek, Travis W.; Warneke, Carsten; Yuan, Bin; de Gouw, Joost A.

    2017-01-01

    Volatile organic compounds were quantified during two aircraft-based field campaigns using highly automated, whole air samplers with expedited post-flight analysis via a new custom-built, field-deployable gas chromatography-mass spectrometry instrument. During flight, air samples were pressurized with a stainless steel bellows compressor into electropolished stainless steel canisters. The air samples were analyzed using a novel gas chromatograph system designed specifically for field use which eliminates the need for liquid nitrogen. Instead, a Stirling cooler is used for cryogenic sample pre-concentration at temperatures as low as -165 °C. The analysis system was fully automated on a 20 min cycle to allow for unattended processing of an entire flight of 72 sample canisters within 30 h, thereby reducing typical sample residence times in the canisters to less than 3 days. The new analytical system is capable of quantifying a wide suite of C2 to C10 organic compounds at part-per-trillion sensitivity. This paper describes the sampling and analysis systems, along with the data analysis procedures which include a new peak-fitting software package for rapid chromatographic data reduction. Instrument sensitivities, uncertainties and system artifacts are presented for 35 trace gas species in canister samples. Comparisons of reported mixing ratios from each field campaign with measurements from other instruments are also presented.

  19. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J. C.; Sodeau, J. R.; Healy, R. M.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; O'Dowd, C. D.

    2009-12-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the NE Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Black carbon concentrations in polluted air were between 300-400 ng m-3, and in clean marine air were less than 50 ng m-3. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water

  20. Identification of oxidation products of solanesol produced during air sampling for tobacco smoke by electrospray mass spectrometry and HPLC.

    PubMed

    Tucker, Samuel P; Pretty, Jack R

    2005-10-01

    Solanesol, a 45-carbon, trisesquiterpenoid alcohol found in tobacco leaves and tobacco smoke, has been used as a quantitative marker for tobacco smoke for years. However, solanesol appears to be unreliable as a quantitative marker for tobacco smoke during environmental air sampling because it can be degraded substantially when present as a component of tobacco smoke and by as much as 100% when present as pure solanesol on fortified filters during air sampling. Since there is strong evidence that ozone is the agent responsible for the degradation, solanesol appears to be unreliable as a quantitative marker during indoor air sampling when indoor levels of ozone are greater than about 15 ppb. The degree of loss of pure solanesol is directly proportional to the concentration of ozone and the length of the sampling period and depends on the type of 37 mm membrane filter used for air sampling (PTFE or quartz fiber). While the degree of loss of solanesol is inversely proportional to the relative humidity of the air at a sampling rate of 1.7 L min(-1), the degree of loss is virtually independent of relative humidity at a lower sampling rate; i.e., 0.25 L min(-1). A curve of loss of solanesol on a filter versus concentration of ozone from an ozone generator is virtually identical to a curve segment based on atmospheric ozone under the same conditions of air sampling. Oxidation of solanesol by ozone to approximately 25 to 60% completion produces at least three series of products for a total of at least 26 compounds: (1) isoprenoid acetones, (2)omega-hydroxyisoprenoid acetaldehydes, and (3) isoprenoid oxoaldehydes. All products in each series were tentatively identified as their derivatives with 2-(p-aminophenyl)ethanol (APE) by electrospray mass spectrometry (ES-MS). Ten ozonation products were detected as their 2,4-dinitrophenylhydrazine derivatives by HPLC at 360 nm: 4-oxopentanal and nine isoprenoid acetones (acetone, 6-methyl-5-hepten-2-one, geranylacetone

  1. Characterization of submicron aerosols during a serious pollution month in Beijing (2013) using an aerodyne high-resolution aerosol mass spectrometer

    NASA Astrophysics Data System (ADS)

    Zhang, J. K.; Sun, Y.; Liu, Z. R.; Ji, D. S.; Hu, B.; Liu, Q.; Wang, Y. S.

    2013-07-01

    In January 2013, Beijing experienced several serious haze events. To achieve a better understanding of the characteristics, sources and processes of aerosols during this month, an Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) was deployed at an urban site between 1 January and 1 February 2013 to obtain the size-resolved chemical composition of non-refractory submicron particles (NR-PM1). During this period, the mean measured NR-PM1 mass concentration was 87.4 μg m-3 and was composed of organics (49.8%), sulfate (21.4%), nitrate (14.6%), ammonium (10.4%), and chloride (3.8%). Moreover, inorganic matter, such as sulfate and nitrate comprised an increasing fraction of the NR-PM1 load as NR-PM1 loading increased, denoting their key roles in particulate pollution during this month. The average size distributions of the species were all dominated by an accumulation mode peaking at approximately 600 nm in vacuum aerodynamic diameter and organics characterized by an additional smaller size (∼200 nm). Elemental analyses showed that the average O/C, H/C, and N/C (molar ratio) of organic matter were 0.34, 1.44 and 0.015, respectively, corresponding to an OM/OC ratio (mass ratio of organic matter to organic carbon) of 1.60. Positive matrix factorization (PMF) analyses of the high-resolution organic mass spectral dataset differentiated the organic aerosol into four components, i.e., oxygenated organic aerosols (OOA), cooking-related (COA), nitrogen-containing (NOA) and hydrocarbon-like (HOA), which on average accounted for 40.0, 23.4, 18.1 and 18.5% of the total organic mass, respectively. Back trajectory clustering analyses indicated that the WNW air masses were associated with the highest NR-PM1 pollution during the campaign. Aerosol particles in southern air masses were especially rich in inorganic and oxidized organic species, whereas northern air masses contained a large fraction of primary species.

  2. Ozone concentrations in air flowing into New York State

    NASA Astrophysics Data System (ADS)

    Aleksic, Nenad; Kent, John; Walcek, Chris

    2016-09-01

    Ozone (O3) concentrations measured at Pinnacle State Park (PSPNY), very close to the southern border of New York State, are used to estimate concentrations in air flowing into New York. On 20% of the ozone season (April-September) afternoons from 2004 to 2015, mid-afternoon 500-m back trajectories calculated from PSPNY cross New York border from the south and spend less than three hours in New York State, in this area of negligible local pollution emissions. One-hour (2p.m.-3p.m.) O3 concentrations during these inflowing conditions were 46 ± 13 ppb, and ranged from a minimum of 15 ppb to a maximum of 84 ppb. On average during 2004-2015, each year experienced 11.8 days with inflowing 1-hr O3 concentrations exceeding 50 ppb, 4.3 days with O3 > 60 ppb, and 1.5 days had O3 > 70 ppb. During the same period, 8-hr average concentrations (10a.m. to 6p.m.) exceeded 50 ppb on 10.0 days per season, while 3.9 days exceeded 60 ppb, and 70 ppb was exceeded 1.2 days per season. Two afternoons of minimal in-state emission influences with high ozone concentrations were analyzed in more detail. Synoptic and back trajectory analysis, including comparison with upwind ozone concentrations, indicated that the two periods were characterized as photo-chemically aged air containing high inflowing O3 concentrations most likely heavily influenced by pollution emissions from states upwind of New York including Pennsylvania, Tennessee, West Virginia, and Ohio. These results suggest that New York state-level attempts to comply with National Ambient Air Quality Standards by regulating in-state O3 precursor NOx and organic emissions would be very difficult, since air frequently enters New York State very close to or in excess of Federal Air Quality Standards.

  3. Upper air relaxation in regional climate model improves resolved interannual variability of the surface mass balance of Antarctica

    NASA Astrophysics Data System (ADS)

    van de Berg, Willem Jan; Medley, Brooke; van Meijgaard, Erik

    2015-04-01

    The surface mass balance (SMB) determines the variability of the mass balance of the Antarctic Ice sheet on sub-decadal timescales. Since continent-wide SMB cannot be measured, it must be modeled and regional climate models (RCMs) generally outperform global reanalyses in the representation of total mass flux and the spatial distribution of SMB. However, if RCMs are only forced with reanalysis on their lateral boundaries, the representation of the interannual variability of SMB deteriorates significantly. In this study we show how to improve the resolved interannual variability in RCM modeled SMB. For this purpose we use annual SMB observations in the Thwaites drainage basin in Antarctica derived from airborne radar reflections and the RCM RACMO2. RACMO2, driven by ERA-Interim, better represents the mean spatial SMB pattern in this basin than ERA-Interim. However, without relaxation in the interior, RACMO2 poorly resolves the observed interannual SMB variability. If we gently relax the temperature and wind field in the upper atmosphere in RACMO2 to ERA-Interim, RACMO2 gets the best of both. Upper air relaxation little changes the mean SMB and spatial pattern compared to the original RACMO2 output, but allows RACMO2 to resolve the observed interannual SMB as good as ERA-Interim.

  4. Decomposing the profile of PM in two low polluted German cities--mapping of air mass residence time, focusing on potential long range transport impacts.

    PubMed

    Dimitriou, Konstantinos; Kassomenos, Pavlos

    2014-07-01

    This paper aims to decompose the profile of particulates in Karlsruhe and Potsdam (Germany), focusing on the localization of PM potential transboundary sources. An air mass cluster analysis was implemented, followed by a study of air mass residence time on a grid of a 0.5° × 0.5° resolution. Particulate/gaseous daily air pollution and meteorological data were used to indicate PM local sources. Four Principal Component Analysis (PCA) components were produced: traffic, photochemical, industrial/domestic and particulate. PM2.5/PM10 ratio seasonal trends, indicated production of PMCOARSE (PM10-PM2.5) from secondary sources in Potsdam during warm period (WP). The residing areas of incoming slow moving air masses are potential transboundary PM sources. For Karlsruhe those areas were mainly around the city. An air mass residence time secondary peak was observed over Stuttgart. For Potsdam, areas with increased dwelling time of the arriving air parcels were detected particularly above E/SE Germany.

  5. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  6. Differential optical absorption spectroscopy (DOAS) and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    NASA Astrophysics Data System (ADS)

    Rozanov, V. V.; Rozanov, A. V.

    2010-06-01

    The Differential Optical Absorption Spectroscopy (DOAS) technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering. Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS), the modified (MDOAS), and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption. The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as well as of the relationship between

  7. Differential optical absorption spectroscopy (DOAS) and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    NASA Astrophysics Data System (ADS)

    Rozanov, V. V.; Rozanov, A. V.

    2010-02-01

    The Differential Optical Absorption Spectroscopy (DOAS) technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering. Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS), the modified (MDOAS), and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption. The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as well as of the relationship between

  8. Methyl chloride in the UT/LS observed by CARIBIC: global distribution, Asian summer monsoon outflow, and use as a tracer for tropical air

    NASA Astrophysics Data System (ADS)

    Baker, A. K.; Umezawa, T.; Oram, D.; Sauvage, C.; Rauthe-Schoech, A.; Montzka, S. A.; Zahn, A.; Brenninkmeijer, C. A. M.

    2014-12-01

    We present spatiotemporal variations of methyl chloride (CH3Cl) in the UT/LS observed mainly by the CARIBIC passenger aircraft for the years 2005-2011. The CH3Cl mixing ratio in the UT over Europe was higher than that observed at a European surface baseline station year-round, indicative of a persistent positive vertical gradient at NH mid latitudes. A series of flights over Africa and South Asia show that CH3Cl mixing ratios increase toward tropical latitudes, and the observed UT CH3Cl level over these two regions and the Atlantic was higher than that measured at remote surface sites. Strong emissions of CH3Cl in the tropics combined with meridional transport through the UT may explain such vertical and latitudinal gradients. Comparisons with CO data indicate that non-combustion sources in the tropics dominantly contribute to forming the latitudinal gradient of CH3Cl in the UT. We also observed elevated CH3Cl and CO in air influenced by biomass burning in South America and Africa, and the enhancement ratios derived for CH3Cl to CO in those regions agree with previous observations. In contrast, correlations indicate a high CH3Cl to CO ratio of 2.9±0.5 ppt ppb-1 in the Asian summer monsoon anticyclone and domestic biofuel emissions in South Asia are inferred to be responsible. We estimated CH3Cl emissions from South Asia to be 134±23 Gg Cl yr-1, which is higher than a previous estimate due to the higher CH3Cl to CO ratio observed in this study. We also examine the use of CH3Cl as a tracer of tropical tropospheric air in the LMS, where we identified air masses with elevated CH3Cl that were however stratospheric in terms of N2O. Back trajectories suggest recent low-latitude origins of such air masses in early summer. In this season, high CH3Cl LMS air shows a clear branch connecting stratospheric and tropical tropospheric air on N2O-CH3Cl scatterplots. This distinct feature vanishes in late summer when the LMS is ventilated by tropospheric air.

  9. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J.; Healy, R.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; Ehn, M.; Mikkilä, J.; Kulmala, M.; O'Dowd, C. D.

    2010-09-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June, 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the N. E. Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water soluble organic carbon, which, in turn, was dominated by methanesulphonic acid (MSA). Sulphate concentrations were

  10. Distinct synoptic patterns and air masses responsible for long-range desert dust transport and sea spray in Palermo, Italy

    NASA Astrophysics Data System (ADS)

    Dimitriou, K.; Paschalidou, A. K.; Kassomenos, P. A.

    2016-09-01

    Undoubtedly, anthropogenic emissions carry a large share of the risk posed on public health by particles exposure in urban areas. However, natural emissions, in the form of desert dust and sea spray, are well known to contribute significantly to the PM load recorded in many Mediterranean environments, posing an extra risk burden on public health. In the present paper, we examine the synoptic climatology in a background station in Palermo, Italy, through K-means clustering of the mean sea-level pressure (MSLP) maps, in an attempt to associate distinct synoptic patterns with increased PM10 levels. Four-day backward trajectory analysis is then applied, in order to study the origins and pathways of air masses susceptible of PM10 episodes. It is concluded that a number of atmospheric patterns result in several kind of flows, namely south, west, and slow-moving/stagnant flows, associated with long-range dust transport and sea spray.

  11. Characterisation of a smartphone image sensor response to direct solar 305nm irradiation at high air masses.

    PubMed

    Igoe, D P; Amar, A; Parisi, A V; Turner, J

    2017-06-01

    This research reports the first time the sensitivity, properties and response of a smartphone image sensor that has been used to characterise the photobiologically important direct UVB solar irradiances at 305nm in clear sky conditions at high air masses. Solar images taken from Autumn to Spring were analysed using a custom Python script, written to develop and apply an adaptive threshold to mitigate the effects of both noise and hot-pixel aberrations in the images. The images were taken in an unobstructed area, observing from a solar zenith angle as high as 84° (air mass=9.6) to local solar maximum (up to a solar zenith angle of 23°) to fully develop the calibration model in temperatures that varied from 2°C to 24°C. The mean ozone thickness throughout all observations was 281±18 DU (to 2 standard deviations). A Langley Plot was used to confirm that there were constant atmospheric conditions throughout the observations. The quadratic calibration model developed has a strong correlation between the red colour channel from the smartphone with the Microtops measurements of the direct sun 305nm UV, with a coefficient of determination of 0.998 and very low standard errors. Validation of the model verified the robustness of the method and the model, with an average discrepancy of only 5% between smartphone derived and Microtops observed direct solar irradiances at 305nm. The results demonstrate the effectiveness of using the smartphone image sensor as a means to measure photobiologically important solar UVB radiation. The use of ubiquitous portable technologies, such as smartphones and laptop computers to perform data collection and analysis of solar UVB observations is an example of how scientific investigations can be performed by citizen science based individuals and groups, communities and schools.

  12. The collision cross sections of iodide salt cluster ions in air via differential mobility analysis-mass spectrometry.

    PubMed

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R; Hogan, Christopher J

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M(+)]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5%) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  13. Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

    PubMed

    Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

    2014-01-01

    A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future.

  14. The Collision Cross Sections of Iodide Salt Cluster Ions in Air via Differential Mobility Analysis-Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R.; Hogan, Christopher J.

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M+]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5 %) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  15. Identification of water-soluble polar organics in air and vehicular emitted particulate matter using ultrahigh resolution mass spectrometry and Capillary electrophoresis - mass spectrometry.

    NASA Astrophysics Data System (ADS)

    Schmitt-Kopplin, P.; Yassine, M.; Gebefugi, I.; Hertkorn, N.; Dabek-Zlotorzynska, E.

    2009-04-01

    The effects of aerosols on human health, atmospheric chemistry, and climate are among the central topics in current environmental health research. Detailed and accurate measurements of the chemical composition of air particulate matter (PM) represent a challenging analytical task. Minute sample amounts are usually composed of several main constituents and hundreds of minor and trace constituents. Moreover, the composition of individual particles can be fairly uniform or very different (internally or externally mixed aerosols), depending on their origin and atmospheric aging processes (coagulation, condensation / evaporation, chemical reaction). The aim of the presentation was the characterization of the organic matter (OM) fraction of environmental aerosols which is not accessible by GC-methods, either because of their high molecular weight, their polarity or due to thermal instability. We also describe the main chemical characteristics of complexe oligomeric organic fraction extracted from different aerosols collected in urban and rural area in Germany and Canada. Mass spectrometry (MS) became an essential tool used by many prominent leaders of the biological research community and the importance of MS to the future of biological research is now clearly evident as in the fields of Proteomics and Metabolomics. Especially Fourier Transform Ion Cyclotron Mass Spectrometry (ICR-FT/MS) is an ultrahigh resolution MS that allows new approach in the analysis of complex mixtures. The mass resolution (< 200 ppb) allowed assigning the elemental composition (C, H, O, N, S…) to each of the obtained mass peaks and thus already a description of the mixture in terms of molecular composition. This possibility is used by the authors together with a high resolution separation method of charged compounds: capillary electrophoresis. A CE-ESI-MS method using an ammonium acetate based background electrolyte (pH 4.7) was developed for the determination of isomeric benzoic acids in

  16. Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

    NASA Technical Reports Server (NTRS)

    Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Grant, William B.; Ismail, Syed; Ferrare, Richard A.; Kooi, Susan A.; Brackett, Vincent G.; Clayton, Marian B.; Avery, Melody A.

    2001-01-01

    Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The

  17. Development of a thermal desorption-gas chromatography-mass spectrometry method for determining personal care products in air.

    PubMed

    Ramírez, Noelia; Marcé, Rosa Maria; Borrull, Francesc

    2010-06-25

    This study describes the development of a new analytical method for determining 14 personal care products (PCPs) - nine synthetic musks, four parabens and one insect repellent - in air samples. The method is based on active sampling on sorbent tubes and thermal desorption-gas chromatography-mass spectrometry analysis, and is rapid, sensitive and drastically reduces the risk of sample contamination. Three kinds of tubes and traps were tested, those filled with Tenax TA being the most suitable for this study. Method validation showed good repeatability and reproducibility, low detection limits (between 0.03 ng m(-3) for DPMI and 12.5 ng m(-3) for propyl paraben) and good linearity for all compounds. Stability during storage indicated that samples must be kept refrigerated at 4 degrees C and analysed within 1 week of collection. The applicability of the technique to real samples was tested in different indoor and outdoor atmospheres. The total PCP values for indoor air ranged from 135 ng m(-3) in a pharmacy to 2838 ng m(-3) in a hairdresser's, whereas the values for outdoor air ranged from 14 ng m(-3) for a suburban environment to 26 ng m(-3) for an urban environment. In general, the most abundant synthetic musks were galaxolide (5.9-1256 ng m(-3)), musk xylene (1.6-766 ng m(-3)) and tonalide (1.1-138 ng m(-3)). Methyl and ethyl paraben (2.4-313 ng m(-3) and 1.8-117 ng m(-3), respectively) were the most abundant parabens. Although thermal desorption methods have been widely used for determining volatile organic compounds, they are rarely used with semi-volatile compounds. This study thus demonstrates that the thermal desorption method performs well with semi-volatile compounds and, for the first time, that it can be used for determining PCPs.

  18. Association between indoor air pollutant exposure and blood pressure and heart rate in subjects according to body mass index.

    PubMed

    Jung, Chien-Cheng; Su, Huey-Jen; Liang, Hsiu-Hao

    2016-01-01

    This study investigates the effects of high body mass index (BMI) of subjects on individual who exhibited high cardiovascular disease indexes with blood pressure (BP) and heart rate (HR) when exposed to high levels of indoor air pollutants. We collected 115 office workers, and measured their systolic blood pressure (SBP), diastolic blood pressure (DBP) and HR at the end of the workday. The subjects were divided into three groups according to BMI: 18-24 (normal weight), 24-27 (overweight) and >27 (obese). This study also measured the levels of carbon dioxide (CO2), total volatile organic compounds (TVOC), particulate matter with an aerodynamic diameter less than 2.5μm (PM2.5), as well as the bacteria and fungi in the subjects' work-places. The pollutant effects were divided by median. Two-way analysis of variance (ANOVA) was used to analyze the health effects of indoor air pollution exposure according to BMI. Our study showed that higher levels of SBP, DBP and HR occurred in subjects who were overweight or obese as compared to those with normal weight. Moreover, there was higher level of SBP in subjects who were overweight or obese when they were exposed to higher levels of TVOC and fungi (p<0.05). We also found higher value for DBP and HR with increasing BMI to be associated with exposure to higher TVOC levels. This study suggests that individuals with higher BMI have higher cardiovascular disease risk when they are exposed to poor indoor air quality (IAQ), and specifically in terms of TVOC.

  19. Air flow-assisted ionization imaging mass spectrometry method for easy whole-body molecular imaging under ambient conditions.

    PubMed

    Luo, Zhigang; He, Jiuming; Chen, Yi; He, Jingjing; Gong, Tao; Tang, Fei; Wang, Xiaohao; Zhang, Ruiping; Huang, Lan; Zhang, Lianfeng; Lv, Haining; Ma, Shuanggang; Fu, Zhaodi; Chen, Xiaoguang; Yu, Shishan; Abliz, Zeper

    2013-03-05

    Whole-body molecular imaging is able to directly map spatial distribution of molecules and monitor its biotransformation in intact biological tissue sections. Imaging mass spectrometry (IMS), a label-free molecular imaging method, can be used to image multiple molecules in a single measurement with high specificity. Herein, a novel easy-to-implement, whole-body IMS method was developed with air flow-assisted ionization in a desorption electrospray ionization mode. The developed IMS method can effectively image molecules in a large whole-body section in open air without sample pretreatment, such as chemical labeling, section division, or matrix deposition. Moreover, the signal levels were improved, and the spatial assignment errors were eliminated; thus, high-quality whole-body images were obtained. With this novel IMS method, in situ mapping analysis of molecules was performed in adult rat sections with picomolar sensitivity under ambient conditions, and the dynamic information of molecule distribution and its biotransformation was provided to uncover molecular events at the whole-animal level. A global view of the differential distribution of an anticancer agent and its metabolites was simultaneously acquired in whole-body rat and model mouse bearing neuroglioma along the administration time. The obtained drug distribution provided rich information for identifying the targeted organs and predicting possible tumor spectrum, pharmacological activity, and potential toxicity of drug candidates.

  20. Simulation of solid oxide iron-air battery: Effects of heat and mass transfer on charge/discharge characteristics

    NASA Astrophysics Data System (ADS)

    Ohmori, Hiroko; Iwai, Hiroshi

    2015-07-01

    A time-dependent 2-D numerical simulation was performed on a solid oxide iron-air battery (SOIAB) to reveal the fundamental characteristics of this new system. The SOIAB is a rechargeable battery consisting of a solid oxide electrochemical cell (SOEC) and iron as a redox metal. A simple battery configuration was employed assuming a system with a small capacity. A simulation model for a unit element was developed considering heat and mass transfer in the system, taking both electrochemical and redox reactions into account. The numerical results showed the spatial and temporal changes in the temperature field in the charge and discharge operations, which were due to the combined effects of heat generation/absorption by the electrochemical and redox reactions and heat exchange with the air supplied through convective heat transfer. As the reaction rates are functions of the local temperature, the predicted results show the importance of considering the heat transfer phenomena in this system. It was also found that the active reaction region in the redox metal evolves with time. The nonuniform distribution of iron utilization is affected by the effective gas diffusion coefficients in the porous redox metal, and consequently the change in the current density distribution in the SOEC.

  1. Comparison of sampling methods for radiocarbon dating of carbonyls in air samples via accelerator mass spectrometry

    NASA Astrophysics Data System (ADS)

    Schindler, Matthias; Kretschmer, Wolfgang; Scharf, Andreas; Tschekalinskij, Alexander

    2016-05-01

    Three new methods to sample and prepare various carbonyl compounds for radiocarbon measurements were developed and tested. Two of these procedures utilized the Strecker synthetic method to form amino acids from carbonyl compounds with either sodium cyanide or trimethylsilyl cyanide. The third procedure used semicarbazide to form crystalline carbazones with the carbonyl compounds. The resulting amino acids and semicarbazones were then separated and purified using thin layer chromatography. The separated compounds were then combusted to CO2 and reduced to graphite to determine 14C content by accelerator mass spectrometry (AMS). All of these methods were also compared with the standard carbonyl compound sampling method wherein a compound is derivatized with 2,4-dinitrophenylhydrazine and then separated by high-performance liquid chromatography (HPLC).

  2. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses.

  3. Measurement error models in chemical mass balance analysis of air quality data

    NASA Astrophysics Data System (ADS)

    Christensen, William F.; Gunst, Richard F.

    The chemical mass balance (CMB) equations have been used to apportion observed pollutant concentrations to their various pollution sources. Typical analyses incorporate estimated pollution source profiles, estimated source profile error variances, and error variances associated with the ambient measurement process. Often the CMB model is fit to the data using an iteratively re-weighted least-squares algorithm to obtain the effective variance solution. We consider the chemical mass balance model within the framework of the statistical measurement error model (e.g., Fuller, W.A., Measurement Error Models, Wiley, NewYork, 1987), and we illustrate that the models assumed by each of the approaches to the CMB equations are in fact special cases of a general measurement error model. We compare alternative source contribution estimators with the commonly used effective variance estimator when standard assumptions are valid and when such assumptions are violated. Four approaches for source contribution estimation and inference are compared using computer simulation: weighted least squares (with standard errors adjusted for source profile error), the effective variance approach of Watson et al. (Atmos, Environ., 18, 1984, 1347), the Britt and Luecke (Technometrics, 15, 1973, 233) approach, and a method of moments approach given in Fuller (1987, p. 193). For the scenarios we consider, the simplistic weighted least-squares approach performs as well as the more widely used effective variance solution in most cases, and is slightly superior to the effective variance solution when source profile variability is large. The four estimation approaches are illustrated using real PM 2.5 data from Fresno and the conclusions drawn from the computer simulation are validated.

  4. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with continental, urban and marine air masses at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2011-12-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions could be identified in the particle phase. In all

  5. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    SciTech Connect

    Mernild, Sebastian Haugard; Liston, Glen

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  6. Ice core sulfur and methanesulfonic acid (MSA) records from southern Greenland document North American and European air pollution and suggest a decline in regional biogenic sulfur emissions.

    NASA Astrophysics Data System (ADS)

    Pasteris, D. R.; McConnell, J. R.; Burkhart, J. F.; Saltzman, E. S.

    2014-12-01

    Sulfate aerosols have an important cooling effect on the Earth because they scatter sunlight back to space and form cloud condensation nuclei. However, understanding of the atmospheric sulfur cycle is incomplete, leading to uncertainty in the assessment of past, present and future climate forcing. Here we use annually resolved observations of sulfur and methanesulfonic acid (MSA) concentration in an array of precisely dated Southern Greenland ice cores to assess the history of sulfur pollution emitted from North America and Europe and the history of biogenic sulfate aerosol derived from the North Atlantic Ocean over the last 250 years. The ice core sulfur time series is found to closely track sulfur concentrations in North American and European precipitation since records began in 1965, and also closely tracks estimated sulfur emissions since 1850 within the air mass source region as determined by back trajectory analysis. However, a decline to near-preindustrial sulfur concentrations in the ice cores after 1995 that is not so extensive in the source region emissions indicates that there has been a change in sulfur cycling over the last 150 years. The ice core MSA time series shows a decline of 60% since the 1860s, and is well correlated with declining sea ice concentrations around Greenland, suggesting that the phytoplankton source of biogenic sulfur has declined due to a loss of marginal sea ice zone habitat. Incorporating the implied decrease in biogenic sulfur in our analysis improves the match between the ice core sulfur record and the source region emissions throughout the last 150 years, and solves the problem of the recent return to near-preindustrial levels in the Greenland ice. These findings indicate that the transport efficiency of sulfur air pollution has been relatively stable through the industrial era and that biogenic sulfur emissions in the region have declined.

  7. Air mass 1.5 global and direct solar simulation and secondary reference cell calibration using a filtered large area pulsed solar simulator

    NASA Technical Reports Server (NTRS)

    Mueller, Robert L.

    1985-01-01

    Spectral mismatch between a solar simulator and a desired spectrum can result in nearly 20 percent measurement error in the output of photovoltaic devices. This occurs when a crystalline silicon cell monitors the intensity of an unfiltered large area pulsed solar simulator (LAPSS) simulating the ASTM air mass 1.5 direct spectrum and the test device is amorphous silicon. The LAPSS spectral irradiance is modified with readily available glass UV filters to closely match either the ASTM air mass 1.5 direct or global spectrum. Measurement error is reduced to about 1 percent when using either filter if the reference cell and test device are the same general type.

  8. First day of an oil spill on the open sea: early mass transfers of hydrocarbons to air and water.

    PubMed

    Gros, Jonas; Nabi, Deedar; Würz, Birgit; Wick, Lukas Y; Brussaard, Corina P D; Huisman, Johannes; van der Meer, Jan R; Reddy, Christopher M; Arey, J Samuel

    2014-08-19

    During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m(3) oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km(2) area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models.

  9. Polycyclic aromatic hydrocarbons in air on small spatial and temporal scales - II. Mass size distributions and gas-particle partitioning

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Klánová, Jana; Ilić, Predrag; Kohoutek, Jiří; Gasić, Bojan; Kovacić, Igor; Škrdlíková, Lenka

    2010-12-01

    Polycyclic aromatic hydrocarbons (PAHs) were measured together with inorganic air pollutants at two urban sites and one rural background site in the Banja Luka area, Bosnia and Hercegovina, during 72 h in July 2008 using a high time resolution (5 samples per day) with the aim to study gas-particle partitioning, aerosol mass size distributions and to explore the potential of a higher time resolution (4 h-sampling). In the particulate phase the mass median diameters of the PAHs were found almost exclusively in the accumulation mode (0.1-1.0 μm of size). These were larger for semivolatile PAHs than for non-volatile PAHs. Gas-particle partitioning of semivolatile PAHs was strongly influenced by temperature. The results suggest that the Junge-Pankow model is inadequate to explain the inter-species variation and another process must be significant for phase partitioning which is less temperature sensitive than adsorption. Care should be taken when interpreting slopes m of plots of the type log K p = m log p L0 + b based on 24 h means, as these are found sensitive to the time averaging, i.e. tend to be higher than when based on 12 h-mean samples.

  10. Analysis of Ozone Transportation in Tlaxcala-Puebla Mexico Air Basin

    NASA Astrophysics Data System (ADS)

    Barrera-Huertas, H.; Torres, R.; Ruiz-Suárez, L. G.; Garcia, J.; Gutierrez, W.; Torres, A.

    2014-12-01

    Preliminary results of an investigation conducted between March and April 2012 on the influence of air pollutants transport in the Puebla-Tlaxcala Valley airshed are presented. The campaign included ozone (O3), nitrogen dioxide (NO2) and meteorological variables monitoring at surface in Huaquechula, Chipilo and Amozoc rural sites, and measurements of O3 vertical profile O3 and meteorology in Chipilo. The synoptic conditions during the campaign showed dominance of "Norte" conditions favoring air masses circulation from Pacific Ocean crossing southern Mexican Plateau to the Gulf of Mexico that influences the establishment of evening southeasterly winds in the Puebla-Tlaxcala Valley. Wind roses and contaminants analysis in surface for O3 during entire campaign indicates that before noon the movement of air masses was dominated by runoff of Malinche toward the southeast and south of the valley; and in the afternoon a regional pattern of winds from southwest Valley prevails coming from Cuautla Valley and south of Morelos State. The analysis of three representative days of atmospheric circulation in the valley as well as anthropogenic diurnal activity, a rate of morning increase in O3 concentrations similar at all three sites was observed, even in the absence of precursors such as NO2 during some weekends. By analyzing and engage data from O3 vertical profile and surface meteorology data, we could infer that there are minimal ozone contributions from local sources, but important from regional origin, and even O3 entrainment in height brought to the surface when mixing layer is growing. The back trajectory analysis from Chipilo at noon indicates that could be additional contributions of O3 from both Cuautla Valley and other areas of pollutants emission such as Tula, (in the north of Mexico City), and that weekend effect with the occurrence of high O3 levels observed there extends to this region. Although interbasin exchange of pollutants between the Puebla-Tlaxcala Valley

  11. Observations of acyl peroxy nitrates during the front range air pollution and photochemistry experiment (FRAPPE)

    NASA Astrophysics Data System (ADS)

    Zaragoza, Jake

    The Colorado Front Range is an ozone (O3) nonattainment region. The photochemistry of the region is influenced by emissions from the urban and oil and gas sectors, the complex terrain, and the meteorology. The Front Range Air Pollution and Photochemistry Experiment (FRAPPE) was a field intensive carried out in the Colorado Front Range during summer 2014 to characterize the regional chemical environment. Acyl peroxy nitrates (PANs) play important roles in atmospheric chemistry, acting as either sinks or sources for nitrogen oxides (NOx) depending on conditions. PANs and other trace gas species were measured at the Boulder Atmospheric Observatory (BAO) during FRAPPE. Situated at the southwestern edge of the Denver-Julesburg Basin and 35 km north of Denver, BAO has been the site of multiple field studies aiming to characterize the influence of emissions from the oil and gas sector. Here we focus on an analysis of the PANs measurements from BAO during FRAPPE. In particular, we focus on peroxyacetic nitric anhydride (PAN, CH3C(O)O2NO2), peroxymethacrylic nitric anhydride (MPAN, CH2C(CH3)C(O)O2NO2) and peroxypropionic nitric anhydride (PPN, CH3CH2C(O)O 2NO2). Mean and maximum PAN mixing ratios (5-minute point) were 275 and 1519 pptv respectively. There were four days during FRAPPE where the observed PAN abundance exceeded 1 ppbv. These days were examined using FLEXible PARTicle dispersion model (FLEXPART) back trajectories in order to determine air mass origin. The high PAN days occurred when air masses were recirculating in the region, often under Denver Cyclones. However, a visual inspection of FLEXPART trajectories throughout FRAPPE showed that recirculation events in the region occurred on days with high (>1 ppbv), moderate (500 pptv - 1 ppbv), and low (<500 pptv) afternoon PAN mixing ratios. The PPN/PAN ratio observed at the BAO tower during the summer of 2014 was 21%, which suggests anthropogenically enhanced photochemical activity. The ratio was very consistent (R

  12. Air quality during the 2008 Beijing Olympics: secondary pollutants and regional impact

    NASA Astrophysics Data System (ADS)

    Wang, T.; Nie, W.; Gao, J.; Xue, L. K.; Gao, X. M.; Wang, X. F.; Qiu, J.; Poon, C. N.; Meinardi, S.; Blake, D.; Ding, A. J.; Chai, F. H.; Zhang, Q. Z.; Wang, W. X.

    2010-05-01

    This paper presents the first results of the atmospheric measurements of trace gases and aerosols at three surface sites in and around Beijing before and during the 2008 Olympics. We focus on secondary pollutants including ozone, fine sulfate and nitrate, and the contribution of regional sources in summer 2008. The results reveal different responses of secondary pollutants to the control measures from primary pollutants. Ambient concentrations of vehicle-related nitrogen oxides (NOx) and volatile organic compounds (VOCs) at an urban site dropped by 25% and 20-45% in the first two weeks after full control was put in place, but the levels of ozone, sulfate and nitrate in PM2.5 increased by 16%, 64%, 37%, respectively, compared to the period prior to the full control; wind data and back trajectories indicated the contribution of regional pollution from the North China Plain. Air quality (for both primary and secondary pollutants) improved significantly during the Games, which were also associated with the changes in weather conditions (prolonged rainfall, decreased temperature, and more frequent air masses from clean regions). A comparison of the ozone data at three sites on eight ozone-pollution days, when the air masses were from the southeast-south-southwest sector, showed that regional pollution sources contributed 34%-88% to the peak ozone concentrations in urban Beijing. Ozone production efficiencies at two sites were low (~3 ppbv/ppbv), indicating that ozone formation was being controlled by VOCs. Compared with data collected in 2005 at a downwind site, the concentrations of ozone, sulfur dioxide (SO2), total sulfur (SO2+PM2.5 sulfate), carbon monoxide (CO), reactive aromatics (toluene and xylenes) sharply decreased (by 8-64%) in 2008, but no significant changes were observed for the concentrations of PM2.5, fine sulfate, total odd reactive nitrogen (NOy), and longer lived alkanes and benzene. We suggest that these results indicate the success of the government

  13. Quantifying the contribution of long-range transport to particulate matter (PM) mass loadings at a suburban site in the north-western Indo-Gangetic Plain (NW-IGP)

    NASA Astrophysics Data System (ADS)

    Pawar, H.; Garg, S.; Kumar, V.; Sachan, H.; Arya, R.; Sarkar, C.; Chandra, B. P.; Sinha, B.

    2015-08-01

    Many sites in the densely populated Indo-Gangetic Plain (IGP) frequently exceed the national ambient air quality standard (NAAQS) of 100 μg m-3 for 24 h average PM10 and 60 μg m-3 for 24 h average PM2.5 mass loadings, exposing residents to hazardous levels of particulate matter (PM) throughout the year. We quantify the contribution of long-range transport to elevated PM levels and the number of exceedance events through a back-trajectory climatology analysis of air masses arriving at the IISER Mohali Atmospheric Chemistry facility (30.667° N, 76.729° E; 310 m a.m.s.l.) for the period August 2011-June 2013. Air masses arriving at the receptor site were classified into six clusters, which represent synoptic-scale air-mass transport patterns. Long-range transport from the west leads to significant enhancements in the average fine- and coarse-mode PM mass loadings during all seasons. The contribution of long-range transport from the west and south-west (source regions: Arabia, Thar Desert, Middle East and Afghanistan) to coarse-mode PM varied between 9 and 57 % of the total PM10-2.5 mass. Local pollution episodes (wind speed < 1 m s-1) contributed to enhanced PM2.5 mass loadings during both the winter and summer seasons and to enhanced coarse-mode PM only during the winter season. South-easterly air masses (source region: eastern IGP) were associated with significantly lower fine- and coarse-mode PM mass loadings during all seasons. The fraction of days in each season during which the PM mass loadings exceeded the national ambient air quality standard was controlled by long-range transport to a much lesser degree. For the local cluster, which represents regional air masses (source region: NW-IGP), the fraction of days during which the national ambient air quality standard (NAAQS) of 60 μg m-3 for 24 h average PM2.5 was exceeded varied between 36 % of the days associated with this synoptic-scale transport during the monsoon, and 95 % during post-monsoon and winter

  14. Cyclic organic peroxides identification and trace analysis by Raman microscopy and open-air chemical ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Pena-Quevedo, Alvaro Javier

    The persistent use of cyclic organic peroxides in explosive devices has increased the interest in study these compounds. Development of methodologies for the detection of triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) has become an urgent priority. However, differences in physical properties between cyclic organic peroxides make difficult the development of a general method for peroxide analysis and detection. Following this urgency, the first general technique for the analysis of any peroxide, regarding its structural differences is reported. Characterization and detection of TATP and HMTD was performed using an Open-Air Chemical Ionization High-Resolution Time-of-Flight Mass Spectrometer. The first spectrometric analysis for tetramethylene diperoxide dicarbamide (TMDD) and other nitrogen based peroxides using Raman Microscopy and Mass Spectrometry is reported. Analysis of cyclic peroxides by GC-MS was also conducted to compare results with OACI-HRTOF data. In the OACI mass spectrum, HMTD showed a clear signal at m/z 209 MH + and a small adduct peak at m/z 226 [M+NH4]+ that allowed its detection in commercial standard solutions and lab made standards. TMDD presented a molecular peak of m/z 237 MH+ and an adduct peak of m/z 254 [M+NH4]+. TATP showed a single peak at m/z 240 [M+NH4]+, while the peak of m/z 223 or 222 was completely absent. This evidence suggests that triperoxides are stabilized by the ammonium ion. TATP samples with deuterium enrichment were analyzed to compare results that could differentiate from HMTD. Raman microscopy was used as a complementary characterization method and was an essential tool for cyclic peroxides identification, particularly for those which could not be extensively purified. All samples were characterized by Raman spectroscopy to confirm the Mass Spectrometry results. Peroxide O-O vibrations were observed around 750-970 cm-1. D18-TATP studies had identified ketone triperoxide nu(O-O) vibration around

  15. The potential of LIRIC to validate the vertical profiles of the aerosol mass concentration estimated by an air quality model

    NASA Astrophysics Data System (ADS)

    Siomos, Nikolaos; Filoglou, Maria; Poupkou, Anastasia; Liora, Natalia; Dimopoulos, Spyros; Melas, Dimitris; Chaikovsky, Anatoli; Balis, Dimitris

    2015-04-01

    Vertical profiles of the aerosol mass concentration derived by a retrieval algorithm that uses combined sunphotometer and LIDAR data (LIRIC) were used in order to validate the mass concentration profiles estimated by the air quality model CAMx. LIDAR and CIMEL measurements of the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki were used for this validation.The aerosol mass concentration profiles of the fine and coarse mode derived by CAMx were compared with the respective profiles derived by the retrieval algorithm. For the coarse mode particles, forecasts of the Saharan dust transportation model BSC-DREAM8bV2 were also taken into account. Each of the retrieval algorithm's profiles were matched to the models' profile with the best agreement within a time window of four hours before and after the central measurement. OPAC, a software than can provide optical properties of aerosol mixtures, was also employed in order to calculate the angstrom exponent and the lidar ratio values for 355nm and 532nm for each of the model's profiles aiming in a comparison with the angstrom exponent and the lidar ratio values derived by the retrieval algorithm for each measurement. The comparisons between the fine mode aerosol concentration profiles resulted in a good agreement between CAMx and the retrieval algorithm, with the vertical mean bias error never exceeding 7 μgr/m3. Concerning the aerosol coarse mode concentration profiles both CAMx and BSC-DREAM8bV2 values are severely underestimated, although, in cases of Saharan dust transportation events there is an agreement between the profiles of BSC-DREAM8bV2 model and the retrieval algorithm.

  16. The Potential of The Synergy of Sunphotometer and Lidar Data to Validate Vertical Profiles of The Aerosol Mass Concentration Estimated by An Air Quality Model

    NASA Astrophysics Data System (ADS)

    Siomos, N.; Filioglou, M.; Poupkou, A.; Liora, N.; Dimopoulos, S.; Melas, D.; Chaikovsky, A.; Balis, D. S.

    2016-06-01

    Vertical profiles of the aerosol mass concentration derived by the Lidar/Radiometer Inversion Code (LIRIC), that uses combined sunphotometer and lidar data, were used in order to validate the aerosol mass concentration profiles estimated by the air quality model CAMx. Lidar and CIMEL measurements performed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece (40.5N, 22.9E) from the period 2013-2014 were used in this study.

  17. Characterization of key aerosol, trace gas and meteorological properties and particle formation and growth processes dependent on air mass origins in coastal Southern Spain

    NASA Astrophysics Data System (ADS)

    Diesch, J.; Drewnick, F.; Sinha, V.; Williams, J.; Borrmann, S.

    2011-12-01

    The chemical composition and concentration of aerosols at a certain site can vary depending on season, the air mass source region and distance from sources. Regardless of the environment, new particle formation (NPF) events are one of the major sources for ultrafine particles which are potentially hazardous to human health. Grown particles are optically active and efficient CCN resulting in important implications for visibility and climate (Zhang et al., 2004). The study presented here is intended to provide information about various aspects of continental, urban and marine air masses reflected by wind patterns of the air arriving at the measurement site. Additionally we will be focusing on NPF events associated with different types of air masses affecting their emergence and temporal evolution. Measurements of the ambient aerosol, various trace gases and meteorological parameters were performed within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from mid-November to mid-December 2008 at the atmospheric research station "El Arenosillo" located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean. Number and mass as well as PAH and black carbon concentrations were measured in PM1 and size distribution instruments covered the size range 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (AMS). In order to evaluate the characteristics of different air masses linking local and regional sources as well as NPF processes, characteristic air mass types were classified dependent on backwards trajectory pathways and local meteorology. Large nuclei mode concentrations in the number size distribution were found within continental and urban influenced air mass types due to frequently occurring NPF events. Exploring individual production and sink variables, sulfuric

  18. Satellite-based identification of tropopause folding signatures along air mass boundaries

    NASA Astrophysics Data System (ADS)

    Wimmers, Anthony James

    Tropopause folding is a significant though frequently underestimated source of mass exchange between the stratosphere and the troposphere. Although tropopause folds are inherently three-dimensional phenomena, empirical evidence shows that certain signature features in two-dimensional satellite products that are sensitive to tropopause height can be used to infer the vertical layering that characterizes tropopause folds. Both Altered Water Vapor (AWV) imagery and Total Ozone Mapping Spectrometer (TOMS) total ozone reveal significant gradients at the "openings" of tropopause folds, and the direction of the gradient indicates the direction of the intrusion. This is demonstrated empirically with a comparison of the satellite imagery to a data set of aircraft-based ozone lidar transects from the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiment. Using the data set to optimize the parameters of this empirical relationship, a statistical model is developed to predict the location of tropopause folds based solely on the properties of AWV imagery, which operates on a hemispheric-scale domain and at the approximately 10-km resolution of the GOES water vapor channel. Validation of this model with evidence of tropopause folding from operational radiosonde data was only partially successful; the validation was not reliable enough to provide precise confirmation of the model parameter values, but it did provide some confirmation that the model was well calibrated. Application of this model over a February to May, 2000 time period provides a four-month "climatology" of tropopause folding activity around North America. During this time period, tropopause folding activity was strongest over the northeast Pacific and northwest Atlantic, and at a minimum in the high latitudes around Hudson Bay. Over the entire domain (25--63° N, 40--165° W), tropopause folding activity was greatest in March. This result does not prove that downward vertical transport from

  19. Validation and Application of the Mass Balance Model To Determine the Effectiveness of Portable Air Purifiers in Removing Ultrafine and Submicrometer Particles in an Apartment.

    PubMed

    Lee, Wan-Chen; Catalano, Paul J; Yoo, Jun Young; Park, Chan Jung; Koutrakis, Petros

    2015-08-18

    We validated the use of the mass balance model to determine the effectiveness of portable air purifiers in removing ultrafine (<0.10 μm) and submicrometer particles (0.10-0.53 μm) in an apartment. We evaluated two identical portable air purifiers, equipped with high efficiency particulate air filters, for their performance under three different air flow settings and three target air exchange rates: 0.60, 0.90, and 1.20 h(-1). We subsequently used a mixed effects model to estimate the slope between the measured and modeled effectiveness by particle size. Our study showed that effectiveness was highly particle size-dependent. For example, at the lowest target air exchange rate, it ranged from 0.33 to 0.56, 0.51 to 0.75, and 0.60 to 0.81 for the three air purifier flow settings, respectively. Our findings suggested that filtration was the dominant removal mechanism for submicrometer particles, whereas deposition could play a more important role in ultrafine particle removal. We found reasonable agreement between measured and modeled effectiveness with size-resolved slopes ranging from 1.11 ± 0.06 to 1.25 ± 0.07 (mean ± SE), except for particles <35 nm. Our study design can be applied to investigate the performances of other portable air purifiers as well as the influences of various parameters on effectiveness in different residential settings.

  20. Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH

    ERIC Educational Resources Information Center

    Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P.

    2011-01-01

    Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various…

  1. REAL TIME, ON-LINE CHARACTERIZATION OF DIESEL GENERATOR AIR TOXIC EMISSIONS BY RESONANCE ENHANCED MULTI-PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY

    EPA Science Inventory

    The laser based resonance, enhanced multi-photon ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds ...

  2. Determination of trichloroanisole and trichlorophenol in wineries' ambient air by passive sampling and thermal desorption-gas chromatography coupled to tandem mass spectrometry.

    PubMed

    Camino-Sánchez, F J; Bermúdez-Peinado, R; Zafra-Gómez, A; Ruíz-García, J; Vílchez-Quero, J L

    2015-02-06

    The present paper describes the calibration of selected passive samplers used in the quantitation of trichlorophenol and trichloroanisole in wineries' ambient air, by calculating the corresponding sampling rates. The method is based on passive sampling with sorbent tubes and involves thermal desorption-gas chromatography-triple quadrupole mass spectrometry analysis. Three commercially available sorbents were tested using sampling cartridges with a radial design instead of axial ones. The best results were found for Tenax TA™. Sampling rates (R-values) for the selected sorbents were determined. Passive sampling was also used for accurately determining the amount of compounds present in the air. Adequate correlation coefficients between the mass of the target analytes and exposure time were obtained. The proposed validated method is a useful tool for the early detection of trichloroanisole and its precursor trichlorophenol in wineries' ambient air while avoiding contamination of wine or winery facilities.

  3. Determination of benzene at trace levels in air by a novel method based on solid-phase microextraction gas chromatography/mass spectrometry.

    PubMed

    Saba, A; Cuzzola, A; Raffaelli, A; Pucci, S; Salvadori, P

    2001-01-01

    A new method for the determination of benzene at trace levels in air is presented. The method consists of the collection of air samples on adsorbent cartridges with simultaneous adsorption of pre-established amounts of D6-labeled internal standard. Desorption from the cartridge is performed by solid-phase microextraction (SPME) with analysis by gas chromatography/mass spectrometry (GC/MS) using an ion trap mass spectrometer. The influence of several parameters (type of SPME fiber, temperature, time, for example) was investigated, and good linearity in the range 10-400 ng of C6D6, with a coefficient of variance (CV) around 3-5%, was obtained. The method was tested by sampling air in a town center in Italy, and a benzene concentration of approximately 50 microg/m(3) was determined. The maximum limit recommended by the European Community is 10 microg/m(3).

  4. Formic and Acetic Acid Observations over Colorado by Chemical Ionization Mass Spectrometry and Organic Acids' Role in Air Quality

    NASA Astrophysics Data System (ADS)

    Treadaway, V.; O'Sullivan, D. W.; Heikes, B.; Silwal, I.; McNeill, A.

    2015-12-01

    Formic acid (HFo) and acetic acid (HAc) have both natural and anthropogenic sources and a role in the atmospheric processing of carbon. These organic acids also have an increasing importance in setting the acidity of rain and snow as precipitation nitrate and sulfate concentrations have decreased. Primary emissions for both organic acids include biomass burning, agriculture, and motor vehicle emissions. Secondary production is also a substantial source for both acids especially from biogenic precursors, secondary organic aerosols (SOAs), and photochemical production from volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs). Chemical transport models underestimate organic acid concentrations and recent research has sought to develop additional production mechanisms. Here we report HFo and HAc measurements during two campaigns over Colorado using the peroxide chemical ionization mass spectrometer (PCIMS). Iodide clusters of both HFo and HAc were recorded at mass-to-charge ratios of 173 and 187, respectively. The PCIMS was flown aboard the NCAR Gulfstream-V platform during the Deep Convective Clouds and Chemistry Experiment (DC3) and aboard the NCAR C-130 during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE). The DC3 observations were made in May and June 2012 extending from the surface to 13 km over the central and eastern United States. FRAPPE observations were made in July and August 2014 from the surface to 7 km over Colorado. DC3 measurements reported here are focused over the Colorado Front Range and complement the FRAPPE observations. DC3 HFo altitude profiles are characterized by a decrease up to 6 km followed by an increase either back to boundary layer mixing ratio values or higher (a "C" shape). Organic acid measurements from both campaigns are interpreted with an emphasis on emission sources (both natural and anthropogenic) over Colorado and in situ photochemical production especially ozone precursors.

  5. Elemental composition and radical formation potency of PM10 at an urban background station in Germany in relation to origin of air masses

    NASA Astrophysics Data System (ADS)

    Hellack, Bryan; Quass, Ulrich; Beuck, Henning; Wick, Gabriele; Kuttler, Wilhelm; Schins, Roel P. F.; Kuhlbusch, Thomas A. J.

    2015-03-01

    At an urban background station in Mülheim-Styrum, North Rhine Westphalia, Germany, a set of 75 PM10 samples was collected over a one year period, followed by analyses for mass, chemical composition and hydroxyl radical (OHrad) formation potency. Additionally, the origin of air masses for the sampling days was calculated by 48-h backward trajectories, subdivided into the four cardinal sectors. Significant lower PM10 mass concentrations were observed for summertime air masses from the west compared to the other seasons and cardinal sectors. For the OHrad formation potency higher values were detected if air masses originate from east and south, thus predominantly being of continental origin. From the elevated OHrad formation potencies in fall and winter a seasonal trend with low potencies in summers is assumed. Furthermore, source apportionment was performed by a positive matrix factor analysis, separating seven plausible factors which could be attributed to mineral dust, secondary nitrate, industry, non-exhaust traffic, fossil fuel combustion, marine aerosol and secondary aerosol factors. The intrinsic OHrad formation potency was found to be associated mainly with the fossil fuel combustion factor (45%) and industry factor (22%).

  6. Optimization of automated gas sample collection and isotope ratio mass spectrometric analysis of delta(13)C of CO(2) in air.

    PubMed

    Zeeman, Matthias J; Werner, Roland A; Eugster, Werner; Siegwolf, Rolf T W; Wehrle, Günther; Mohn, Joachim; Buchmann, Nina

    2008-12-01

    The application of (13)C/(12)C in ecosystem-scale tracer models for CO(2) in air requires accurate measurements of the mixing ratios and stable isotope ratios of CO(2). To increase measurement reliability and data intercomparability, as well as to shorten analysis times, we have improved an existing field sampling setup with portable air sampling units and developed a laboratory setup for the analysis of the delta(13)C of CO(2) in air by isotope ratio mass spectrometry (IRMS). The changes consist of (a) optimization of sample and standard gas flow paths, (b) additional software configuration, and (c) automation of liquid nitrogen refilling for the cryogenic trap. We achieved a precision better than 0.1 per thousand and an accuracy of 0.11 +/- 0.04 per thousand for the measurement of delta(13)C of CO(2) in air and unattended operation of measurement sequences up to 12 h.

  7. Student understanding of the volume, mass, and pressure of air within a sealed syringe in different states of compression

    NASA Astrophysics Data System (ADS)

    de Berg, Kevin Charles

    Problem-solving strategies in the physical sciences have been characterized by a dependence on algorithmic techniques often devoid of any reasoning skills. The purpose of this study was to examine student responses to a task relating to Boyle's Law for gases, which did not demand the use of a mathematical equation for its solution. Students (17- to 18-year-olds) in lower sixth form from two colleges in the Leeds district of Yorkshire in England were asked to respond to a task relating to pressure and volume measurements of air within a sealed syringe in different states of compression. Both qualitative and quantitative tasks for the sealed syringe system were examined. It was found that 34% to 38% of students did not understand the concepts of volume and mass, respectively, of a gas under such circumstances. Performance on an inverse ratio (2:1) task was shown to depend on gender and those students who performed well on the 2:1 inverse ratio task did not necessarily perform well on a different inverse ratio task when an arithmetic averaging principle was present. Tasks which draw upon qualitative knowledge as well as quantitative knowledge have the potential to reduce dependence on algorithms, particularly equation substitution and solution. The implications for instructional design are discussed.Received: 14 April 1993; Revised: 29 June 1994;

  8. The Effect of Isotopic Composition on the Uncertainty of Routine Metal Mass Concentration Measurements in Ambient Air

    PubMed Central

    Brown, Richard J. C.; Goddard, Sharon L.; Brown, Andrew S.; Yardley, Rachel E.

    2008-01-01

    The main sources of uncertainty encountered during the analysis of the mass concentration of metals in ambient air as part of the operation of the UK Heavy Metals Monitoring Network are presented. It is observed that the uncertainty contribution from possible variation in the isotopic composition of the sample depends on the element in question, but can be significant (e.g., for Pb, Cd, and Hg). The working curve method for the ICP-MS analysis of metals in solution, with a low resolution, high throughput instrument measuring at one m/z ratio per element, relies on the relative abundance of the isotopes under consideration being the same in both the sample and the calibration solution. Calculation of the uncertainty in this analysis assumes that the isotopic composition variation within the sample and calibration solution is limited to a defined range. Therefore, in order to confirm the validity of this quantification methodology and its uncertainty budget, the isotopic composition of the calibration standards used for quantification has been determined. The results of this analysis are presented here. PMID:19223968

  9. Total ozone seasonal and interannual variations in the principal air masses of the Northern Hemisphere in 1975-1990

    NASA Technical Reports Server (NTRS)

    Karol, Igor L.; Klyagina, L. P.; Shalamyansky, A. M.; Jagovkina, S. V.

    1994-01-01

    The diurnally mean total ozone X from the Northern Hemisphere ground based 90 stations for 1975-1990 are averaged over the Arctic (bar X (sub A)) Intermediate (bar X (sub I)) and Tropical (bar X (sub T)) air mass areas, divided by the jet stream axes on the isobaric surfaces 300 and 200 mb. The mean square variations of the so averaged X are considerably smaller than of the X, averaged over the corresponding zonal belts. This property allows one to improve considerably the statistical significance of X trends and changes over various time periods, taking into account the time correlation of data for adjacent time intervals. Bar X (sub A), bar X (sub I), and bar X (sub T) trends are estimated over the periods of solar activity rise and fall in its 21st and rise in its 22nd 11 year cycles and over the periods of west and east phases of the known over the periods of west and east phases of the known quasibiennial oscillation (QBO). Solar activity variations affect mostly bar X (sub T), bar X (sub I) trends in summer months, while QBO phases influence the X changes mostly during the cold half year. X are lower in the west QBO phase and their trend is negative during almost all periods considered. The anthropogenic effects on the X is also estimated.

  10. Identification of Candidate Clean Air Corridors for the Colorado Plateau.

    PubMed

    Gratn, M C; Pitchford, M L; Ashbaugh, L

    1996-05-01

    The U.S. Clean Air Act, amended in 1990, mandated the establishment of the Grand Canyon Visibility Transport Commission (GCVTC). The commission is required to submit a report to the U.S. Environmental Protection Agency addressing visibility issues in the region, including "the establishment of clean air corridors, in which additional restrictions on increases in emissions may be appropriate to protect visibility in affected Class I areas." This paper presents a methodology to identify candidate geographic areas for consideration for Clean Air Corridor (CAC) status for Colorado Plateau Class I areas. The methodology uses thousands of model determined trajectories over a five year period (1988 to 1992) to indicate the paths taken by air that arrives during clean air conditions at Class I areas. These clean air back-trajectories identify upwind areas where pollution emissions could jeopardize currently pristine visibility. Using this methodology, six candidate areas are identified, ranging in size from 75,000 to 506,000 square miles, and permitting varying levels of visibility protection for clean air days at Grand Canyon, Canyonlands, and Petrified Forest National Parks. Assuming effective emissions management of the CAC, the larger the CAC, the greater the visibility protection during clean air conditions.

  11. Size-Segregated Aerosol Composition and Mass Loading of Atmospheric Particles as Part of the Pacific Northwest 2001(PNW2001) Air Quality Study In Puget Sound

    NASA Astrophysics Data System (ADS)

    Disselkamp, R. S.; Barrie, L. A.; Shutthanadan, S.; Cliff, S.; Cahill, T.

    2001-12-01

    In mid-August, 2001, an aircraft-based air-quality study was performed in the Puget Sound, WA, area entitled PNW2001 (http://www.pnl.gov/pnw2001). The objectives of this field campaign were the following: 1. reveal information about the 3-dimensional distribution of ozone, its gaseous precursors and fine particulate matter during weather conditions favoring air pollution; 2. derive information about the accuracy of urban and biogenic emissions inventories that are used to drive the air quality forecast models; and 3. examine the accuracy of modeled ozone concentration with that observed. In support of these efforts, we collected time-averaged ( { ~}10 minute averages), size-segregated, aerosol composition and mass-loading information using ex post facto analysis techniques of synchrotron x-ray fluorescence (s-XRF), proton induced x-ray emissions(PIXE), proton elastic scattering (PESA), and scanning transmission ion microscopy (STIM). This is the first time these analysis techniques have been used together on samples collected from aircraft using an optimized 3-stage rotating drum impactor. In our presentation, we will discuss the aerosol components in three aerosol size fractions as identified by statistical analysis of multielemental data (including total mass, H, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Pb) and relate variations in these components to physical aerosol properties, other gaseous trace constituents and to air mass origin.

  12. Measurements of δ13C in CH4 and using particle dispersion modeling to characterize sources of Arctic methane within an air mass

    NASA Astrophysics Data System (ADS)

    France, J. L.; Cain, M.; Fisher, R. E.; Lowry, D.; Allen, G.; O'Shea, S. J.; Illingworth, S.; Pyle, J.; Warwick, N.; Jones, B. T.; Gallagher, M. W.; Bower, K.; Le Breton, M.; Percival, C.; Muller, J.; Welpott, A.; Bauguitte, S.; George, C.; Hayman, G. D.; Manning, A. J.; Myhre, C. Lund; Lanoisellé, M.; Nisbet, E. G.

    2016-12-01

    A stratified air mass enriched in methane (CH4) was sampled at 600 m to 2000 m altitude, between the north coast of Norway and Svalbard as part of the Methane in the Arctic: Measurements and Modelling campaign on board the UK's BAe-146-301 Atmospheric Research Aircraft. The approach used here, which combines interpretation of multiple tracers with transport modeling, enables better understanding of the emission sources that contribute to the background mixing ratios of CH4 in the Arctic. Importantly, it allows constraints to be placed on the location and isotopic bulk signature of the emission source(s). Measurements of δ13C in CH4 in whole air samples taken while traversing the air mass identified that the source(s) had a strongly depleted bulk δ13C CH4 isotopic signature of -70 (±2.1)‰. Combined Numerical Atmospheric-dispersion Modeling Environment and inventory analysis indicates that the air mass was recently in the planetary boundary layer over northwest Russia and the Barents Sea, with the likely dominant source of methane being from wetlands in that region.

  13. A methodology study to define pathways and heights to calculate backtrajectories at near coastal Continental Antarctica station (Belgrano)

    NASA Astrophysics Data System (ADS)

    Adame, J. A.; Yela, M.; Navarro, M.; Parrondo, M. C.; Gil, M.

    2012-04-01

    Within the framework of the VIOLIN (Extended Vertical Investigation of the Ozone Layer In ANtarctica) project, different atmospheric components are measured in the Antarctica station of Belgrano (77.87S, 34.62W) such as surface ozone. In order to investigate the origin of the observed chemical species, a study to identify the features and variability of air masses impacting the area has been carried out. The pathways of the air masses are determined through back trajectories calculated with the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) model. As a first step of this study it is necessary to define duration and heights for which the back trajectories will be obtained. The NCEP-GDAS meteorological data with a 1°x1° spatial resolution and 14 vertical levels from surface to 500 mb have been used as input. The years 2009 and 2010 have been used to perform this study which will be expanded in the future. To determinate the optimal duration of the back trajectories daily back trajectories starting at 12:00 UTC for starting altitudes of 500 and 1500 m, with durations of 120, 168, 240 and 360 hours. A cluster methodology has been used to group the back trajectories. An optimal cluster number between 4 and 6 has been obtained. The back trajectories corresponding to 120 and 168 hours show pathways covering half of the Antarctic continent while the ones obtained with 240 and 360 hours travel across all continent. The back trajectories lasting168 hours have been selected as optimal. To study optimum heights and using duration of 168 hours we calculated daily back trajectories starting at 100, 500, 1000, 1500, 2000, 2500, 3000, 3500, and 4000 m. The typologies and path of air masses increase with height. The results obtained in this work identify five groups that represent the lowest 4000 m which are the back trajectories of 100, 500, 1000-1500, 2000-2500 and 3500-4000 m. As conclusion, to perform a study of air masses origin in Belgrano which will help

  14. Spatial and Temporal Changes in Air Pollution Along the Gulf Coast Observed During BRACE: A Case Study of the Land-Sea Breeze

    NASA Astrophysics Data System (ADS)

    Wellman, D.; Luke, W.; Arnold, J.; Watson, T.; Gunter, L.

    2003-12-01

    NOAA's Air Resources Laboratory conducted airborne measurements of trace gases and aerosols in the Bay Region Atmospheric Chemistry Experiment (BRACE) using the NOAA Twin Otter. The Twin Otter flew more than 90 hours in 21 flights in and around the Tampa metropolitan region in May, 2002, at altitudes of 60-3000 m MSL. Flights were conducted over rural and suburban areas, over the centers of Tampa and St. Petersburg, and over Tampa Bay and the Gulf of Mexico. One objective of the aircraft flights was to investigate the role of the sea breeze circulation in determining patterns of nutrient deposition and pollutant loads in the Tampa Bay watershed. Results will be presented from a May 8 flight designed to investigate the effect of the sea breeze recirculation upon Tampa's air quality. The Twin Otter took off at 1425 UTC and after performing a spiral ascent over the Sydney ground site, proceeded to fly north, at 200 feet above mean sea level (MSL) just off the Gulf coast, west of St. Petersburg. Back trajectory analysis suggested the dominance of a northerly rotation in the sea breeze; thus, air sampled over the Gulf passed some hours earlier to the south of the Tampa metropolitan area, in an area largely devoid of major pollution sources, before being advected eastward in the afternoon return flow. Ozone levels in this air mass ranged from 40 to 50 ppbv. Farther north the Twin Otter encountered the advected urban plume from Tampa, displaced to the north by the combination of southeasterly sea breeze flow and westerly return flow, and tracked this plume inland. Ozone levels quickly jumped to 60 ppbv, and increased to as high as 90 ppbv as photochemical processing continued in the advected plume. Nitric acid levels, which approached 4 ppbv in the aged urban air at the coast, dropped rapidly to as low as 1 ppbv inland. A final flight leg to the east of downtown Tampa encountered fresh anthropogenic pollution from the afternoon rush hour; ozone was rapidly produced in the

  15. The quantification of carbon dioxide in humid air and exhaled breath by selected ion flow tube mass spectrometry.

    PubMed

    Smith, David; Pysanenko, Andriy; Spanel, Patrik

    2009-05-01

    The reactions of carbon dioxide, CO(2), with the precursor ions used for selected ion flow tube mass spectrometry, SIFT-MS, analyses, viz. H(3)O(+), NO(+) and O(2) (+), are so slow that the presence of CO(2) in exhaled breath has, until recently, not had to be accounted for in SIFT-MS analyses of breath. This has, however, to be accounted for in the analysis of acetaldehyde in breath, because an overlap occurs of the monohydrate of protonated acetaldehyde and the weakly bound adduct ion, H(3)O(+)CO(2), formed by the slow association reaction of the precursor ion H(3)O(+) with CO(2) molecules. The understanding of the kinetics of formation and the loss rates of the relevant ions gained from experimentation using the new generation of more sensitive SIFT-MS instruments now allows accurate quantification of CO(2) in breath using the level of the H(3)O(+)CO(2) adduct ion. However, this is complicated by the rapid reaction of H(3)O(+)CO(2) with water vapour molecules, H(2)O, that are in abundance in exhaled breath. Thus, a study has been carried out of the formation of this adduct ion by the slow three-body association reaction of H(3)O(+) with CO(2) and its rapid loss in the two-body reaction with H(2)O molecules. It is seen that the signal level of the H(3)O(+)CO(2) adduct ion is sensitively dependent on the humidity (H(2)O concentration) of the sample to be analysed and a functional form of this dependence has been obtained. This has resulted in an appropriate extension of the SIFT-MS software and kinetics library that allows accurate measurement of CO(2) levels in air samples, ranging from very low percentage levels (0.03% typical of tropospheric air) to the 6% level that is about the upper limit in exhaled breath. Thus, the level of CO(2) can be traced through single time exhalation cycles along with that of water vapour, also close to the 6% level, and of trace gas metabolites that are present at only a few parts-per-billion. This has added a further dimension to

  16. Characterization of ion processes in a GC/DMS air quality monitor by integration of the instrument to a mass spectrometer.

    PubMed

    Limero, T F; Nazarov, E G; Menlyadiev, M; Eiceman, G A

    2015-02-07

    The air quality monitor (AQM), which included a portable gas chromatograph (GC) and a detector was interfaced to a mass spectrometer (MS) by introducing flow from the GC detector to the atmospheric pressure ion source of the MS. This small GC system, with a gas recirculation loop for carrier and detector make-up gases, comprised an inlet to preconcentrate volatile organic compounds (VOCs) in air, a thermal desorber before the GC column, a differential mobility spectrometer (DMS), and another DMS as an atmospheric pressure ionization source for the MS. Return flow to the internally recirculated air system of the AQM's DMS was replenished using purified air. Although ions and unreacted neutral vapors flowed from the detector through Viton® tubing into the source of the MS, ions were not detected in the MS without the auxillary ion source, (63)Ni as in the mobility detector. The GC-DMS-MS instrument provided a 3-D measurement platform (GC, DMS, and MS analysis) to explore the gas composition inside the GC-DMS recirculation loop and provide DMS-MS measurement of the components of a complex VOC mixture with performance significantly enhanced by mass-analysis, either with mass spectral scans or with an extracted ion chromatogram. This combination of a mobility spectrometer and a mass spectrometer was possible as vapors and ions are carried together through the DMS analyzer, thereby preserving the chromatographic separation efficiency. The critical benefit of this instrument concept is that all flows in and through the thoroughly integrated GC-DMS analyzer are kept intact allowing a full measure of the ion and vapor composition in the complete system. Performance has been evaluated using a synthetic air sample and a sample of airborne vapors in a laboratory. Capabilities and performance values are described using results from AQM-MS analysis of purified air, ambient air from a research laboratory in a chemistry building, and a sample of synthetic air of known composition

  17. Quantitative comparison of a flared and a standard heated metal capillary inlet with a voltage-assisted air amplifier on an electrospray ionization linear ion trap mass spectrometer.

    PubMed

    Dixon, R Brent; Muddiman, David C

    2007-01-01

    The performance characteristics (i.e., ion abundance and electrospray ion current) of a flared and blunt-ended heated metal capillary were evaluated with a voltage-assisted air amplifier on a linear ion trap mass spectrometer (LTQ-MS). The results demonstrated that a standard capillary afforded higher ion abundance than a flared capillary, thus further work is necessary to investigate conditions for which significant benefits with the flared capillary will be observed. The compatibility of a voltage-assisted air amplifier is explored for both types of capillaries and in all cases resulted in improved ion abundance and spray current.

  18. Interlaboratory evaluation of trace element determination in workplace air filter samples by inductively coupled plasma mass spectrometry†‡

    PubMed Central

    Shulman, Stanley A.; Brisson, Michael J.; Howe, Alan M.

    2015-01-01

    Inductively coupled plasma mass spectrometry (ICP-MS) is becoming more widely used for trace elemental analysis in the occupational hygiene field, and consequently new ICP-MS international standard procedures have been promulgated by ASTM International and ISO. However, there is a dearth of interlaboratory performance data for this analytical methodology. In an effort to fill this data void, an interlaboratory evaluation of ICP-MS for determining trace elements in workplace air samples was conducted, towards fulfillment of method validation requirements for international voluntary consensus standard test methods. The study was performed in accordance with applicable statistical procedures for investigating interlaboratory precision. The evaluation was carried out using certified 37-mm diameter mixed-cellulose ester (MCE) filters that were fortified with 21 elements of concern in occupational hygiene. Elements were spiked at levels ranging from 0.025 to 10 μg filter−1, with three different filter loadings denoted “Low”, “Medium” and “High”. Participating laboratories were recruited from a pool of over fifty invitees; ultimately twenty laboratories from Europe, North America and Asia submitted results. Triplicates of each certified filter with elemental contents at three different levels, plus media blanks spiked with reagent, were conveyed to each volunteer laboratory. Each participant was also provided a copy of the test method which each participant was asked to follow; spiking levels were unknown to the participants. The laboratories were requested to prepare the filters by one of three sample preparation procedures, i.e., hotplate digestion, microwave digestion or hot block extraction, which were described in the test method. Participants were then asked to analyze aliquots of the prepared samples by ICP-MS, and to report their data in units of μg filter−1. Most interlaboratory precision estimates were acceptable for medium- and high

  19. Retrieval of vertical columns of sulfur dioxide from SCIAMACHY and OMI: Air mass factor algorithm development, validation, and error analysis

    NASA Astrophysics Data System (ADS)

    Lee, Chulkyu; Martin, Randall V.; van Donkelaar, Aaron; O'Byrne, Gray; Krotkov, Nickolay; Richter, Andreas; Huey, L. Gregory; Holloway, John S.

    2009-11-01

    We develop an improved retrieval of sulfur dioxide (SO2) vertical columns from two satellite instruments (SCIAMACHY and OMI) that measure ultraviolet solar backscatter. For each SCIAMACHY and OMI observation, a local air mass factor (AMF) algorithm converts line-of-sight "slant" columns to vertical columns using altitude-dependent scattering weights computed with a radiative transfer model (LIDORT), weighted by relative vertical SO2 profile (shape factor) determined locally with a global atmospheric chemistry model (GEOS-Chem). The scattering weights account for viewing geometry, surface albedo, cloud scattering, absorption by ozone, and scattering and absorption by aerosols. Absorption of radiation by mineral dust can reduce seasonal mean instrument sensitivity by 50%. Mean SO2 shape factors simulated with GEOS-Chem and used in the AMF calculation are highly consistent with airborne in situ measurements (INTEX-A and INTEX-B); differences would affect the retrieved SO2 columns by 10%. The retrieved vertical columns are validated with coincident airborne in situ measurements (INTEX-A, INTEX-B, and a campaign over east China). The annual mean AMF errors are estimated to be 35-70% in polluted regions (e.g., East Asia and the eastern United States) and less than 10% over clear ocean regions. The overall SO2 error assessment is 45-80% for yearly averages over polluted regions. Seasonal mean SO2 columns retrieved from SCIAMACHY and OMI for 2006 are significantly spatially correlated with those from GEOS-Chem, in particular over the United States (r = 0.85 for SCIAMACHY and 0.82 for OMI). A sensitivity study confirms the sensitivity of SCIAMACHY and OMI to anthropogenic SO2 emissions.

  20. sup 222 Rn, sup 222 Rn progeny and sup 220 Rn progeny as atmospheric tracers of air masses at the Mauno Loa Observatory

    SciTech Connect

    Hutter, A.R.; George, A.C.; Maiello, M.L.; Fisenne, I.M.; Larsen, R.J.; Beck, H.L.; Wilson, F.C.

    1990-03-01

    {sup 222}Rn, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations in air were measured at the Mauna Loa Observatory (MLO) in Hawaii during March 1989 in order to investigate the feasibility of using them as atmospheric tracers to help determine local air mass flow patterns. Charcoal traps, cooled to dry ice temperatures, were used to collect {sup 222}Rn, which was subsequently measured in pulse ionization chambers at the Environmental Measurements Laboratory (EML). {sup 222}Rn progeny and {sup 220}Rn progeny for 37 samples were measured at the Observatory by sampling high volumes of air through filters, which were counted for up to 11 h in alpha scintillation counters. Individual progeny concentrations were calculated using both least squares and maximum likelihood techniques. In general, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations were low when free tropospheric air was present (downslope and tradewind conditions), and consistently higher when surface air from the island broke through the trade wind inversion layer (upslope conditions). The data suggest that {sup 222}Rn, {sup 222}Rn progeny, or {sup 220}Rn progeny monitoring may provide new and useful information to help indicate the different air flow patterns present at MLO. 17 refs., 5 figs., 2 tabs.

  1. Mobile selected ion flow tube mass spectrometry (SIFT-MS) devices and their use for pollution exposure monitoring in breath and ambient air-pilot study.

    PubMed

    Storer, Malina; Salmond, Jennifer; Dirks, Kim N; Kingham, Simon; Epton, Michael

    2014-09-01

    Studies of health effects of air pollution exposure are limited by inability to accurately determine dose and exposure of air pollution in field trials. We explored the feasibility of using a mobile selected ion flow tube mass spectrometry (SIFT-MS) device, housed in a van, to determine ambient air and breath levels of benzene, xylene and toluene following exercise in areas of high motor vehicle traffic. The breath toluene, xylene and benzene concentration of healthy subjects were measured before and after exercising close to a busy road. The concentration of the volatile organic compounds (VOCs), in ambient air were also analysed in real time. Exercise close to traffic pollution is associated with a two-fold increase in breath VOCs (benzene, xylene and toluene) with levels returning to baseline within 20 min. This effect is not seen when exercising away from traffic pollution sources. Situating the testing device 50 m from the road reduced any confounding due to VOCs in the inspired air prior to the breath testing manoeuvre itself. Real-time field testing for air pollution exposure is possible using a mobile SIFT-MS device. This device is suitable for exploring exposure and dose relationships in a number of large scale field test scenarios.

  2. Characteristics of particle number and mass emissions during heavy-duty diesel truck parked active DPF regeneration in an ambient air dilution tunnel

    NASA Astrophysics Data System (ADS)

    Yoon, Seungju; Quiros, David C.; Dwyer, Harry A.; Collins, John F.; Burnitzki, Mark; Chernich, Donald; Herner, Jorn D.

    2015-12-01

    Diesel particle number and mass emissions were measured during parked active regeneration of diesel particulate filters (DPF) in two heavy-duty diesel trucks: one equipped with a DPF and one equipped with a DPF + SCR (selective catalytic reduction), and compliant with the 2007 and 2010 emission standards, respectively. The emission measurements were conducted using an ambient air dilution tunnel. During parked active regeneration, particulate matter (PM) mass emissions measured from a 2007 technology truck were significantly higher than the emissions from a 2010 technology truck. Particle number emissions from both trucks were dominated by nucleation mode particles having a diameter less than 50 nm; nucleation mode particles were orders of magnitude higher than accumulation mode particles having a diameter greater than 50 nm. Accumulation mode particles contributed 77.8 %-95.8 % of the 2007 truck PM mass, but only 7.3 %-28.2 % of the 2010 truck PM mass.

  3. Characterizing the chemical evolution of air masses via multi-platform measurements of volatile organic compounds (VOCs) during CalNEX: Composition, OH reactivity, and potential SOA formation

    NASA Astrophysics Data System (ADS)

    Gilman, J. B.; Kuster, W. C.; Bon, D.; Warneke, C.; Lerner, B. M.; Williams, E. J.; Holloway, J. S.; Pollack, I. B.; Ryerson, T. B.; Atlas, E. L.; Blake, D. R.; Herndon, S. C.; Zahniser, M. S.; Vlasenko, A. L.; Li, S.; Alvarez, S. L.; Rappenglueck, B.; Flynn, J. H.; Grossberg, N.; Lefer, B. L.; De Gouw, J. A.

    2011-12-01

    Volatile organic compounds (VOCs) are critical components in the photochemical production of ozone (O3) and secondary organic aerosol (SOA). During the CalNex 2010 field campaign, an extensive set of VOCs were measured at the Pasadena ground site, and aboard the NOAA WP-3D aircraft and the WHOI Research Vessel Atlantis. The measurements from each platform provide a unique perspective into the emissions, transport, and atmospheric processing of VOCs within the South Coast Air Basin (SoCAB). The observed enhancement ratios of the hydrocarbons measured on all three platforms are in good agreement and are generally well correlated with carbon monoxide (CO), indicating the prevalence of on-road VOC emission sources throughout the SoCAB. Offshore measurements aboard the ship and aircraft are used to characterize the air mass composition as a function of the land/sea-breeze effect. VOC ratios and other trace gases are used to identify air masses containing relatively fresh emissions that were often associated with offshore flow and re-circulated continental air associated with onshore flow conditions. With the prevailing southwesterly airflow pattern in the LAB throughout the daytime, the Pasadena ground site effectively functions as a receptor site and is used to characterize primary VOC emissions from downtown Los Angeles and to identify the corresponding secondary oxidation products. The chemical evolution of air masses as a function of the time of day is investigated in order to determine the relative impacts of primary emissions vs. secondary VOC products on OH reactivity and potential SOA formation. The reactivity of VOCs with the hydroxyl radical (OH) at the Pasadena site was dominated by the light hydrocarbons, isoprene, and oxygenated VOCs including aldehydes (secondary products) and alcohols (primary anthropogenic emissions). Toluene and benzaldehyde, both of which are associated with primary anthropogenic emissions, are the predominant VOC precursors to the

  4. Organochlorine pesticides and PCBs in air of southern Mexico (2002-2004)

    NASA Astrophysics Data System (ADS)

    Alegria, Henry A.; Wong, Fiona; Jantunen, Liisa M.; Bidleman, Terry F.; Figueroa, Miguel Salvador; Bouchot, Gerardo Gold; Moreno, Victor Ceja; Waliszewski, Stefan M.; Infanzon, Raul

    Air samples were collected in southern Mexico in 2002-2004 to determine the extent of contamination with organochlorine (OC) pesticides and polychlorinated biphenyls (PCBs). The ΣDDTs ranged from 239 to 2360 pg m -3. Other prominent OC pesticides were endosulfans, toxaphene and lindane. Pesticides detected in lower concentrations include chlordanes, dieldrin, and heptachlor. Proportions of DDT compounds suggested fresh use of DDT in some locations and a mix of fresh and aged residues at others. Ratios of trans-chlordane/ cis-chlordane were consistent with fresh chlordane usage or emission of residues from former termiticide applications. The ΣPCBs was relatively low at all sites. Concentrations of OC pesticides measured with passive samplers agreed well with those measured using high-volume samplers. Air back trajectory analysis suggests a complex pattern of regional atmospheric transport.

  5. Measurement of the mass energy-absorption coefficient of air for x-rays in the range from 3 to 60 keV.

    PubMed

    Buhr, H; Büermann, L; Gerlach, M; Krumrey, M; Rabus, H

    2012-12-21

    For the first time the absolute photon mass energy-absorption coefficient of air in the energy range of 10 to 60 keV has been measured with relative standard uncertainties below 1%, considerably smaller than those of up to 2% assumed for calculated data. For monochromatized synchrotron radiation from the electron storage ring BESSY II both the radiant power and the fraction of power deposited in dry air were measured using a cryogenic electrical substitution radiometer and a free air ionization chamber, respectively. The measured absorption coefficients were compared with state-of-the art calculations and showed an average deviation of 2% from calculations by Seltzer. However, they agree within 1% with data calculated earlier by Hubbell. In the course of this work, an improvement of the data analysis of a previous experimental determination of the mass energy-absorption coefficient of air in the range of 3 to 10 keV was found to be possible and corrected values of this preceding study are given.

  6. Who should take responsibility for decisions on internationally recommended datasets? The case of the mass concentration of mercury in air at saturation

    NASA Astrophysics Data System (ADS)

    Brown, Richard J. C.; Brewer, Paul J.; Ent, Hugo; Fisicaro, Paola; Horvat, Milena; Kim, Ki-Hyun; Quétel, Christophe R.

    2015-10-01

    This paper considers how decisions on internationally recommended datasets are made and implemented and, further, how the ownership of these decisions comes about. Examples are given of conventionally agreed data and values where the responsibility is clear and comes about through official designation or by common usage and practice over long time periods. The example of the dataset describing the mass concentration of mercury in air at saturation is discussed in detail. This is a case where there are now several competing datasets that are in disagreement with each other, some with historical authority and some more recent but, arguably, with more robust metrological traceability to the SI. Further, it is elaborated that there is no body charged with the responsibility to make a decision on an international recommendation for such a dataset. This has led to the situation where several competing datasets are in use simultaneously. Close parallels are drawn with the current debate over changes to the ozone absorption cross section, which has equal importance to the measurement of ozone amount fraction in air and to subsequent compliance with air quality legislation. It is noted that in the case of the ozone cross section there is already a committee appointed to deliberate over any change. We make the proposal that a similar committee, under the auspices of IUPAC or the CIPM’s CCQM (if it adopted a reference data function) could be formed to perform a similar role for the mass concentration of mercury in air at saturation.

  7. Variation in airborne 137Cs peak levels with altitude from high-altitude locations across Europe after the arrival of Fukushima-labeled air masses

    NASA Astrophysics Data System (ADS)

    Masson, Olivier; Bieringer, Jacqueline; Dalheimer, Axel; Estier, Sybille; Evrard, Olivier; Penev, Ilia; Ringer, Wolfgang; Schlosser, Clemens; Steinkopff, Thomas; Tositti, Laura; de Vismes-Ott, Anne

    2015-04-01

    During the Fukushima Daiichi nuclear power plant (FDNPP) accident, a dozen of high-altitude aerosol sampling stations, located between 850 and 3,454 m above sea level (a.s.l.), provided airborne activity levels across Europe (Fig. 1). This represents at most 5% of the total number of aerosol sampling locations that delivered airborne activity levels (at least one result) in Europe, in connection with this nuclear accident. High altitude stations are typically equipped with a high volume sampler that collects aerosols on filters. The Fukushima-labeled air mass arrival and the peak of airborne cesium-137 (137Cs) activity levels were registered in Europe at different dates depending on the location, with differences up to a factor of six on a regional scale. Besides this statement related to lowland areas, we have compared the maximum airborne levels registered at high-altitude European locations (850 m < altitudes < 3450 m) with what was observed at the closest lowland location. The vertical distribution of 137Cs peak level was not uniform even after a long travel time/distance from Japan. This being true at least in the atmospheric boundary layer and in the lower free troposphere. Moreover the relation '137Csmax vs. altitude' shows a decreasing trend (Fig. 2). Results and discussion : Comparison of 137Cs and 7Be levels shows simultaneous increases at least when the 137Cs airborne level rose for the first time (Fig. 3). Zugspitze and Jungfraujoch stations attest of a time shift between 7Be and 137Cs peak that can be due to the particular dynamic of air movements at such high altitudes. After the 137Cs peak value, the plume concentration decreased whatever the 7Be level. Due to the cosmogenic origin of 7Be, its increase in the ground-level air is usually associated with downwind air movements, i.e. stratospheric air intrusions or at least air from high-tropospheric levels, into lower atmospheric layers. This means that Fukushima-labeled air masses registered at ground

  8. The effect of long-range air mass transport pathways on PM10 and NO2 concentrations at urban and rural background sites in Ireland: Quantification using clustering techniques.

    PubMed

    Donnelly, Aoife A; Broderick, Brian M; Misstear, Bruce D

    2015-01-01

    The specific aims of this paper are to: (i) quantify the effects of various long range transport pathways nitrogen dioxide (NO2) and particulate matter with diameter less than 10μm (PM10) concentrations in Ireland and identify air mass movement corridors which may lead to incidences poor air quality for application in forecasting; (ii) compare the effects of such pathways at various sites; (iii) assess pathways associated with a period of decreased air quality in Ireland. The origin of and the regions traversed by an air mass 96h prior to reaching a receptor is modelled and k-means clustering is applied to create air-mass groups. Significant differences in air pollution levels were found between air mass cluster types at urban and rural sites. It was found that easterly or recirculated air masses lead to higher NO2 and PM10 levels with average NO2 levels varying between 124% and 239% of the seasonal mean and average PM10 levels varying between 103% and 199% of the seasonal mean at urban and rural sites. Easterly air masses are more frequent during winter months leading to higher overall concentrations. The span in relative concentrations between air mass clusters is highest at the rural site indicating that regional factors are controlling concentration levels. The methods used in this paper could be applied to assist in modelling and forecasting air quality based on long range transport pathways and forecast meteorology without the requirement for detailed emissions data over a large regional domain or the use of computationally demanding modelling techniques.

  9. Measurement of the x-ray mass energy-absorption coefficient of air using 3 keV to 10 keV synchrotron radiation.

    PubMed

    Büermann, L; Grosswendt, B; Kramer, H-M; Selbach, H-J; Gerlach, M; Hoffmann, M; Krumrey, M

    2006-10-21

    For the first time absolute photon mass energy-absorption coefficients of air in the energy range 3 keV to 10 keV have been measured with relative standard uncertainties less than 1%, significantly smaller than those of up to 5% assumed hitherto for calculated data. Monochromatized synchrotron radiation was used to measure both the total radiant energy by means of silicon photodiodes calibrated against a cryogenic radiometer and the fraction of radiant energy that is deposited in dry air by means of a free air ionization chamber. The measured ionization charge was converted into energy absorbed in air by calculated effective W values of photons as a function of their energy based on new measurements of the W values in dry air for electron kinetic energies between 1 keV and 7 keV, also presented in this work. The measured absorption coefficients were compared with state-of-the art calculations and found to agree within 0.7% with data calculated earlier by Hubbell at energies above 4 keV but were found to differ by values up to 2.1% at 10 keV from more recent calculations of Seltzer.

  10. Intercomparison of OMI NO2 and HCHO air mass factor calculations: recommendations and best practices for retrievals

    NASA Astrophysics Data System (ADS)

    Lorente Delgado, Alba; Klaas Boersma, Folkert; Hilboll, Andreas; Richter, Andreas; Yu, Huan; van Roozendael, Michel; Dörner, Steffen; Wagner, Thomas; Barkley, Michael; Lamsal, Lok; Lin, Jintai; Liu, Mengyao

    2016-04-01

    We present a detailed comparison of the air mass factor (AMF) calculation process used by various research groups for OMI satellite retrievals of NO2 and HCHO. Although satellite retrievals have strongly improved over the last decades, there is still a need to better understand and reduce the uncertainties associated with every retrieval step of satellite data products, such as the AMF calculation. Here we compare and evaluate the different approaches used to calculate AMFs by several scientific groups (KNMI (WUR), IASB-BIRA, IUP-UNI. BREMEN, MPI-C, NASA GSFC, LEICESTER UNI. and PEKING UNI.). Each group calculated altitude dependent (box-) AMFs and clear sky and total tropospheric AMFs for several OMI orbits. First, European groups computed AMFs for one OMI orbit using common settings for the choice of surface albedo data, terrain height, cloud treatment and a priori vertical profile. Second, every group computed AMFs for two complete days in different seasons using preferred settings for the ancillary data and cloud treatment as a part of a Round Robin exercise. Box-AMFs comparison showed good consistency and underlined the importance of a correct treatment of the physical processes affecting the effective light path and the vertical discretization of the atmosphere. Using common settings, tropospheric NO2 AMFs in polluted pixels on average agreed within 4.7% whereas in remote pixels agreed within 3.5%. Using preferred settings relative differences between AMFs increase up to 15-30%. This increase is traced back to the different choices and assumptions made throughout the AMF calculation, which affect the final AMF values and thus the uncertainty in the AMF calculation. Differences between state of the art cloud treatment approaches highlight the importance of an accurate cloud correction: total and clear sky AMFs in polluted conditions differ by up to 40% depending on the retrieval scenario. Based on the comparison results, specific recommendations on best

  11. Retrieval of Vertical Columns of Sulfur Dioxide From SCIAMACHY and OMI: Air Mass Factor Algorithm Development and Validation

    NASA Astrophysics Data System (ADS)

    Lee, C.; Martin, R. V.; Donkelaar, A. V.; O'Byrne, G.; Krotkov, N.; Richter, A.; Huey, G.; Holloway, J. S.

    2009-05-01

    Sulfur dioxide (SO2) is released into the atmosphere as a result of both anthropogenic activities and natural phenomena. SO2 oxidizes rapidly in the atmosphere, leading to aerosol formation and acid deposition. Outstanding questions exist about SO2 emissions and its atmospheric chemistry. Global mapping of atmospheric SO2 concentrations can provide critical information on its emissions and transport and generally improve scientific understanding of its atmospheric chemistry. Here, we present an improved retrieval of sulfur dioxide (SO2) vertical columns from satellite instruments (SCIAMACHY and OMI) that measure solar backscattered UV radiance. Particular attention is devoted to development of a local air mass factor (AMF) algorithm to convert slant columns to vertical columns. For each SCIAMACHY and OMI observation, we calculate an AMF from the relative vertical SO2 distribution (shape factor) determined locally with a 3-D global model of atmospheric chemistry (GEOS-Chem), weighted by altitude-dependent scattering weights computed with a radiative transfer model (LIDORT). Seasonal mean instrument sensitivity to SO2 (AMF) is generally twice as high over ocean than land. Mineral dust can reduce seasonal mean instrument sensitivity by 50%. Mean relative vertical profiles of SO2 simulated with GEOS-Chem and used in the AMF calculation are highly consistent with airborne in situ measurements (INTEX-A and INTEX-B); differences would affect the retrieved SO2 columns by 10%. The retrieved vertical columns are validated (r = 0.9) with coincident airborne in-situ measurements (INTEX-A, INTEX-B, and a campaign over East China). A global uniform AMF would reduce the correlation with aircraft measurements by 0.1 - 0.2. The overall error assessment leads to 45 - 80% errors for yearly averages over the polluted regions. Seasonal mean SO2 columns retrieved from SCIAMACHY and OMI for 2006 are significantly spatially correlated with those from GEOS-Chem, in particular over the

  12. Effects of Thermal Mass, Window Size, and Night-Time Ventilation on Peak Indoor Air Temperature in the Warm-Humid Climate of Ghana

    PubMed Central

    Amos-Abanyie, S.; Akuffo, F. O.; Kutin-Sanwu, V.

    2013-01-01

    Most office buildings in the warm-humid sub-Saharan countries experience high cooling load because of the predominant use of sandcrete blocks which are of low thermal mass in construction and extensive use of glazing. Relatively, low night-time temperatures are not harnessed in cooling buildings because office openings remain closed after work hours. An optimization was performed through a sensitivity analysis-based simulation, using the Energy Plus (E+) simulation software to assess the effects of thermal mass, window size, and night ventilation on peak indoor air temperature (PIAT). An experimental system was designed based on the features of the most promising simulation model, constructed and monitored, and the experimental data used to validate the simulation model. The results show that an optimization of thermal mass and window size coupled with activation of night-time ventilation provides a synergistic effect to obtain reduced peak indoor air temperature. An expression that predicts, indoor maximum temperature has been derived for models of various thermal masses. PMID:23878528

  13. Particulate and Gaseous Species in fog and Clear air in Highly Polluted Urban Region of South Asia

    NASA Astrophysics Data System (ADS)

    Farhana, B.; Husain, L.

    2007-12-01

    An extensive study of PM2.5 composition was conducted in Lahore, Pakistan during winter of 2005-2006 that included both clear air and periods of fog. We deployed a low-volume sampler connected with an annular denuder system, which consisted of two diffusion denuders and a filter pack consisting of Teflon and nylon filters in series, to sample acidic gases, ammonia, and PM2.5. Teflon filter samples were used to determine PM2.5 mass, anions (F-, BrO3-, Cl-, NO2-, Br-, NO3-, SO42- and C2O42-), cations (Na+, NH4+, K+, Mg2+ and Ca2+) and elements (Be, Na, Mg, Al, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Sr, Mo, Ag, Cd, Sn, Sb, Ba, Tl and Pb). Denuder samples were used to measure selected gaseous species; HCl, HONO, HNO3, SO2 and NH3. Exceedingly high concentrations of all species, relative to major urban areas of US and Europe, were observed. Mean concentrations of the PM2.5 mass, Pb, HONO and NH3 were 191, 96, 19.6 and 50 μg m-3, respectively, which are exceptionally high even at the polluted atmospheric context. Concentrations of most species showed a distinct diurnal variation. Mixing heights, sun index and wind speed played a major role in defining the diurnal pattern. Our data showed a distinct enhancement in the oxidation of SO2 with duration of fog. We use air parcel back trajectories, intercomponent relationships and meteorological observations to explain the sources and the impacts of fog chemistry and mixing heights on atmospheric processing of the chemical constituents. Aerosols were found to carry the signatures of emissions from coal and oil combustion, industrial processes, construction activities and biomass burning in North and Central Pakistan, North India and West Afghanistan, in addition to the local pollution sources. Source apportionment based on positive matrix factorization is in progress. Findings of our study will improve the understanding of the critical roles and interactions between chemical composition and size of atmospheric particles

  14. Detection of Free Tropospheric Air Masses With High So2 and Aerosol Concentrations: Evidence For New Aerosol Particle Formation By H2so4/h2o Nucleation

    NASA Astrophysics Data System (ADS)

    Katragkou, E.; Wilhelm, S.; Kiendler, A.; Arnold, F.; Minikin, A.; Schlager, H.; van Velthoven, P.

    Sulfur dioxide and aerosol measurements were performed in the free troposphere (FT) and the Planetary Boundary Layer (PBL) above continental Europe. The measure- ments took place on board of the German research aircraft "Falcon" in 18 April 2001 as a part of the SCAVEX campaign. A novel aircraft based CIMS (Chemical Ion- ization Mass Spectrometry) instrument equipped with an ion trap mass spectrometer (ITMS) with a low detection limit (50pptv) and a high time resolution (1.3s) operated by MPI-K was used to perform the SO2 measurements. For the aerosol measurements DLR-IPA operated a Condensation Particle Size Analyzer, detecting particles with diameters d > 4, 7, 9 and 20nm and a PCASP-100X aerosol spectrometer probe (d > 100nm). In the measurements made mostly around 5000m altitude SO2 rich air masses were occasionally observed with SO2 VMR of up to 2900pptv. The strong SO2 pollu- tion was due to fast vertical transport of polluted continental PBL air and small-scale deep convection, as indicated by the 5-day backward 3D trajectories. These observa- tions of strong SO2 pollution have interesting implications for aerosol processes, in- cluding efficient formation of gaseous sulfuric acid (GSA) and new aerosol particles. They also imply fast growth of freshly nucleated aerosol particles, which increases the chance for new particles to grow to the size of a CCN. Our analysis indicates the occurrence of new particle formation by H2SO4/H2O nucleation and fast new particle growth by H2SO4/H2O condensation and self-coagulation in the different air masses encountered during the flight.

  15. Operational Use of the AIRS Total Column Ozone Retrievals Along with the RGB Air Mass Product as Part of the GOES-R Proving Ground

    NASA Technical Reports Server (NTRS)

    Folmer, Michael; Zavodsky, Bradley; Molthan, Andrew

    2012-01-01

    The National Oceanic and Atmospheric Administration (NOAA) National Centers for Environmental Prediction (NCEP) Hydrometeorological Prediction Center (HPC) and Ocean Prediction Center (OPC) provide short-term and medium-range forecast guidance of heavy precipitation, strong winds, and other features often associated with mid-latitude cyclones over both land and ocean. As a result, detection of factors that lead to rapid cyclogenesis and high wind events is key to improving forecast skill. One phenomenon that has been identified with these events is the stratospheric intrusion that occurs near tropopause folds. This allows for deep mixing near the top of the atmosphere where dry air high in ozone concentrations and potential vorticity descends (sometimes rapidly) deep into the mid-troposphere. Observations from satellites can aid in detection of these stratospheric air intrusions (SAI) regions. Specifically, multispectral composite imagery assign a variety of satellite spectral bands to the red, green, and blue (RGB) color components of imagery pixels and result in color combinations that can assist in the detection of dry stratospheric air associated with PV advection, which in turn may alert forecasters to the possibility of a rapidly strengthening storm system. Single channel or RGB satellite imagery lacks quantitative information about atmospheric moisture unless the sampled brightness temperatures or other data are converted to estimates of moisture via a retrieval process. Thus, complementary satellite observations are needed to capture a complete picture of a developing storm system. Here, total column ozone retrievals derived from a hyperspectral sounder are used to confirm the extent and magnitude of SAIs. Total ozone is a good proxy for defining locations and intensity of SAIs and has been used in studies evaluating that phenomenon (e.g. Tian et al. 2007, Knox and Schmidt 2005). Steep gradients in values of total ozone seen by satellites have been linked

  16. Seasonal origins of air masses transported to Mount Wrangell, Alaska, and comparison with the past atmospheric dust and tritium variations in its ice core

    NASA Astrophysics Data System (ADS)

    Yasunari, T. J.; Shiraiwa, T.; Kanamori, S.; Fujii, Y.; Igarashi, M.; Yamazaki, K.; Benson, C. S.; Hondoh, T.

    2006-12-01

    The North Pacific region is subject to various climatic phenomena such as the Pacific Decadal Oscillation (PDO), the El Niño-Southern Oscillation (ENSO), and the Arctic Oscillation (AO), significantly affecting the ocean and the atmosphere. Additionally, material circulation is also very active in this region such as spring dust storms in the desert and arid regions of East Asia and forest fires in Siberia and Alaska. Understanding the complex connections among the climatic phenomena and the material circulation would help in attempts to predict future climate changes. For this subject, we drilled a 50-m ice core at the summit of Mount Wrangell, which is located near the coast of Alaska (62°162'170"162°171'N, 144°162'170"162;°171'W, and 4100-m). We analyzed dust particle number density, tritium concentration, and 171 171 171 171 170 162 171 D in the core. The ice core spanned the years from 1992 to 2002 and we finally divided the years into five parts (early-spring; late-spring; summer; fall; winter). Dust and tritium amounts varied annually and intra-annually. For further understanding of the factors on those variations, we should know the origins of the seasonal dust and tritium. Hence, we examined their origins by the calculation of everyday 10-days backward trajectory analysis from January 1992 to August 2002 with 3-D wind data of the European Center for Medium-Range Weather Forecast (ECMWF). In early spring, the air mass from East Asia increased and it also explained dust increases in springtime, although the air contribution in winter increased too. In late spring, the air mass from the stratosphere increased, and it also corresponded to the stratospheric tritium increase in the ice core. The air masses from Siberia and the North Pacific in the mid-latitude always significantly contributed to Mount Wrangell, although those maximum contributions were fall and summer, respectively. The air mass originating in the interior of Alaska and North America did

  17. Development of a thermal desorption gas chromatography-mass spectrometry method for quantitative determination of haloanisoles and halophenols in wineries' ambient air.

    PubMed

    Camino-Sánchez, F J; Ruiz-García, J; Zafra-Gómez, A

    2013-08-30

    An analytical method for the detection and quantification of haloanisoles and their corresponding halophenols in wineries' ambient air was developed. The target analytes were haloanisoles and halophenols, reported by previous scientific literature as responsible for wine taint. A calibrated pump and active tubes filled with Tenax GR™ were used for sampling. These tubes were thermally desorbed and analyzed using gas chromatography-triple quadrupole mass spectrometry in the selected reaction monitoring mode. The adsorption efficiencies of five commercial sampling tubes filled with different materials were evaluated. The efficiencies of the selected adsorbent were close to 100% for all sampled compounds. Desorption, chromatographic and mass spectrometric conditions were accurately optimized allowing very low limits of quantification and wide linear ranges. The limits of quantification in ambient air ranged from 0.8pgtube(-1) for 2,4,6-trichlorophenol, to 28pgtube(-1) for pentachlorophenol. These results are of great importance because human sensory threshold for haloanisoles is very low. The chromatographic method was also validated and the instrumental precision and trueness were established, a maximum RSD of 9% and a mean recovery of 91-106% were obtained. The proposed method involves an easy and sensitive technique for the early detection of haloanisoles and their precursor halophenols in ambient air avoiding contamination of wine or winery facilities.

  18. Ambient air particle transport into the effluent of a cold atmospheric-pressure argon plasma jet investigated by molecular beam mass spectrometry

    NASA Astrophysics Data System (ADS)

    Dünnbier, M.; Schmidt-Bleker, A.; Winter, J.; Wolfram, M.; Hippler, R.; Weltmann, K.-D.; Reuter, S.

    2013-10-01

    Ambient air species, which are transported into the active effluent of an atmospheric-pressure plasma jet result in highly reactive oxygen and nitrogen species (RONS). Especially for the envisaged application field of plasma medicine, these RONS are responsible for strong biological responses. In this work, the effect of ambient air transport into the effluent of an atmospheric-pressure plasma argon jet on the on-axis densities of nitrogen, oxygen and argon was investigated by means of absolutely calibrated molecular beam mass spectrometry (MBMS). According to biomedical experiments a (bottomless) Petri dish was installed in front of the MBMS. In the following, the near flow field is referring to the region close to the nozzle exit and the far flow field is referring to the region beyond that. The absolute on-axis densities were obtained by three different methods, for the near flow field with VUV-absorption technique, for the far flow field with the MBMS and the total flow field was calculated with a computational fluid dynamics (CFD) simulation. The results of the ambient air particle densities of all independent methods were compared and showed an excellent agreement. Therefore the transport processes of ambient air species can be measured for the whole effluent of an atmospheric-pressure plasma jet. Additionally, with the validation of the simulation it is possible in future to calculate the ambient species transport for various gas fluxes in the same turbulent flow regime. Comparing the on-axis densities obtained with an ignited and with a non-ignited plasma jet shows that for the investigated parameters, the main influence on the ambient air species transport is due to the increased temperature in the case when the jet is switched on. Moreover, the presence of positive ions (e.g. ArN_{2}^{+} ) formed due to the interaction of plasma-produced particles and ambient air species, which are transported into the effluent, is shown.

  19. Highly sensitive determination of polycyclic aromatic hydrocarbons in ambient air dust by gas chromatography-mass spectrometry after molecularly imprinted polymer extraction.

    PubMed

    Krupadam, Reddithota J; Bhagat, Bhagyashree; Khan, Muntazir S

    2010-08-01

    A method based on solid--phase extraction with a molecularly imprinted polymer (MIP) has been developed to determine five probable human carcinogenic polycyclic aromatic hydrocarbons (PAHs) in ambient air dust by gas chromatography-mass spectrometry (GC-MS). Molecularly imprinted poly(vinylpyridine-co-ethylene glycol dimethacrylate) was chosen as solid-phase extraction (SPE) material for PAHs. The conditions affecting extraction efficiency, for example surface properties, concentration of PAHs, and equilibration times were evaluated and optimized. Under optimum conditions, pre-concentration factors for MIP-SPE ranged between 80 and 93 for 10 mL ambient air dust leachate. PAHs recoveries from MIP-SPE after extraction from air dust were between 85% and 97% and calibration graphs of the PAHs showed a good linearity between 10 and 1000 ng L(-1) (r = 0.99). The extraction efficiency of MIP for PAHs was compared with that of commercially available SPE materials--powdered activated carbon (PAC) and polystyrene-divinylbenzene resin (XAD)--and it was shown that the extraction capacity of the MIP was better than that of the other two SPE materials. Organic matter in air dust had no effect on MIP extraction, which produced a clean extract for GC-MS analysis. The detection limit of the method proposed in this article is 0.15 ng L(-1) for benzo[a]pyrene, which is a marker molecule of air pollution. The method has been applied to the determination of probable carcinogenic PAHs in air dust of industrial zones and satisfactory results were obtained.

  20. Seasonal, anthropogenic, air mass, and meteorological influences on the atmospheric concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs): Evidence for the importance of diffuse combustion sources

    SciTech Connect

    Lee, R.G.M.; Green, N.J.L.; Lohmann, R.; Jones, K.C.

    1999-09-01

    Sampling programs were undertaken to establish air polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) concentrations at a semirural site on the northwest coast of England in autumn and summer and to investigate factors causing their variability. Changing source inputs, meteorological parameters, air masses, and the impact of a festival when it is customary to light fireworks and bonfires were investigated. Various lines of evidence from the study point to diffuse, combustion-related sources being a major influence on ambient air concentrations. Higher PCDD/F concentrations were generally associated with air masses that had originated and moved over land, particularly during periods of low ambient temperature. Low concentrations were associated with air masses that had arrived from the Atlantic Ocean/Irish Sea to the west of the sampling site and had little or no contact with urban/industrialized areas. Concentrations in the autumn months were 2 to 10 times higher than those found in the summer.

  1. Sensitive and comprehensive detection of chemical warfare agents in air by atmospheric pressure chemical ionization ion trap tandem mass spectrometry with counterflow introduction.

    PubMed

    Seto, Yasuo; Sekiguchi, Hiroshi; Maruko, Hisashi; Yamashiro, Shigeharu; Sano, Yasuhiro; Takayama, Yasuo; Sekioka, Ryoji; Yamaguchi, Shintaro; Kishi, Shintaro; Satoh, Takafumi; Sekiguchi, Hiroyuki; Iura, Kazumitsu; Nagashima, Hisayuki; Nagoya, Tomoki; Tsuge, Kouichiro; Ohsawa, Isaac; Okumura, Akihiko; Takada, Yasuaki; Ezawa, Naoya; Watanabe, Susumu; Hashimoto, Hiroaki

    2014-05-06

    A highly sensitive and specific real-time field-deployable detection technology, based on counterflow air introduction atmospheric pressure chemical ionization, has been developed for a wide range of chemical warfare agents (CWAs) comprising gaseous (two blood agents, three choking agents), volatile (six nerve gases and one precursor agent, five blister agents), and nonvolatile (three lachrymators, three vomiting agents) agents in air. The approach can afford effective chemical ionization, in both positive and negative ion modes, for ion trap multiple-stage mass spectrometry (MS(n)). The volatile and nonvolatile CWAs tested provided characteristic ions, which were fragmented into MS(3) product ions in positive and negative ion modes. Portions of the fragment ions were assigned by laboratory hybrid mass spectrometry (MS) composed of linear ion trap and high-resolution mass spectrometers. Gaseous agents were detected by MS or MS(2) in negative ion mode. The limits of detection for a 1 s measurement were typically at or below the microgram per cubic meter level except for chloropicrin (submilligram per cubic meter). Matrix effects by gasoline vapor resulted in minimal false-positive signals for all the CWAs and some signal suppression in the case of mustard gas. The moisture level did influence the measurement of the CWAs.

  2. Improved detection of low vapor pressure compounds in air by serial combination of single-sided membrane introduction with fiber introduction mass spectrometry (SS-MIMS-FIMS).

    PubMed

    Cotte-Rodríguez, Ismael; Handberg, Eric; Noll, Robert J; Kilgour, David P A; Cooks, R Graham

    2005-05-01

    The use of two methods in tandem, single-sided membrane introduction mass spectrometry (SS-MIMS) and fiber introduction mass spectrometry (FIMS), is presented as a technique for field analysis. The combined SS-MIMS-FIMS technique was employed in both a modified commercial mass spectrometer and a miniature mass spectrometer for the selective preconcentration of the explosive simulant o-nitrotoluene (ONT) and the chemical warfare agent simulant, methyl salicylate (MeS), in air. A home-built FIMS inlet was fabricated to allow introduction of the solid-phase microextraction (SPME) fiber into the mass spectrometer chamber and subsequent desorption of the trapped compounds using resistive heating. The SS-MIMS preconcentration system was also home-built from commercial vacuum parts. Optimization experiments were done separately for each preconcentration system to achieve the best extraction conditions prior to use of the two techniques in combination. Improved limits of detection, in the low ppb range, were observed for the combination compared to FIMS alone, using several SS-MIMS preconcentration cycles. The SS-MIMS-FIMS response for both instruments was found to be linear over the range 50 to 800 ppb. Other parameters studied were absorption time profiles, effects of sample flow rate, desorption temperature, fiber background, memory effects, and membrane fatigue. This simple, sensitive, accurate, robust, selective, and rapid sample preconcentration and introduction technique shows promise for field analysis of low vapor pressure compounds, where analyte concentrations will be extremely low and the compounds are difficult to extract from a matrix like air.

  3. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Jedlovec, G. J.; Molthan, A. L.

    2013-01-01

    Non-convective wind events commonly occur with passing extratropical cyclones and have significant societal and economic impacts. Since non-convective winds often occur in the absence of specific phenomena such as a thunderstorm, tornado, or hurricane, the public are less likely to heed high wind warnings and continue daily activities. Thus non-convective wind events result in as many fatalities as straight line thunderstorm winds. One physical explanation for non-convective winds includes tropopause folds. Improved model representation of stratospheric air and associated non-convective wind events could improve non-convective wind forecasts and associated warnings. In recent years, satellite data assimilation has improved skill in forecasting extratropical cyclones; however errors still remain in forecasting the position and strength of extratropical cyclones as well as the tropopause folding process. The goal of this study is to determine the impact of assimilating satellite temperature and moisture retrieved profiles from hyperspectral infrared (IR) sounders (i.e. Atmospheric Infrared Sounder (AIRS), Cross-track Infrared and Microwave Sounding Suite (CrIMSS), and Infrared Atmospheric Sounding Interferometer (IASI)) on the model representation of the tropopause fold and an associated high wind event that impacted the Northeast United States on 09 February 2013. Model simulations using the Advanced Research Weather Research and Forecasting Model (ARW) were conducted on a 12-km grid with cycled data assimilation mimicking the operational North American Model (NAM). The results from the satellite assimilation run are compared to a control experiment (without hyperspectral IR retrievals), Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis, and Rapid Refresh analyses.

  4. Simulation of heat and mass transfer processes in the experimental section of the air-condensing unit of Scientific Production Company "Turbocon"

    NASA Astrophysics Data System (ADS)

    Artemov, V. I.; Minko, K. B.; Yan'kov, G. G.; Kiryukhin, A. V.

    2016-05-01

    A mathematical model was developed to be used for numerical analysis of heat and mass transfer processes in the experimental section of the air condenser (ESAC) created in the Scientific Production Company (SPC) "Turbocon" and mounted on the territory of the All-Russia Thermal Engineering Institute. The simulations were performed using the author's CFD code ANES. The verification of the models was carried out involving the experimental data obtained in the tests of ESAC. The operational capability of the proposed models to calculate the processes in steam-air mixture and cooling air and algorithms to take into account the maldistribution in the various rows of tube bundle was shown. Data on the influence of temperature and flow rate of the cooling air on the pressure in the upper header of ESAC, effective heat transfer coefficient, steam flow distribution by tube rows, and the dimensions of the ineffectively operating zones of tube bundle for two schemes of steam-air mixture flow (one-pass and two-pass ones) were presented. It was shown that the pressure behind the turbine (in the upper header) increases significantly at increase of the steam flow rate and reduction of the flow rate of cooling air and its temperature rise, and the maximum value of heat transfer coefficient is fully determined by the flow rate of cooling air. Furthermore, the steam flow rate corresponding to the maximum value of heat transfer coefficient substantially depends on the ambient temperature. The analysis of the effectiveness of the considered schemes of internal coolant flow was carried out, which showed that the two-pass scheme is more effective because it provides lower pressure in the upper header, despite the fact that its hydraulic resistance at fixed flow rate of steam-air mixture is considerably higher than at using the one-pass schema. This result is a consequence of the fact that, in the two-pass scheme, the condensation process involves the larger internal surface of tubes

  5. Application of high performance liquid chromatography with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) for determination of chromium compounds in the air at the workplace.

    PubMed

    Stanislawska, Magdalena; Janasik, Beata; Wasowicz, Wojciech

    2013-12-15

    The toxicity and bioavailability of chromium species are highly dependable on the form or species, therefore determination of total chromium is insufficient for a complete toxicological evaluation and risk assessment. An analytical method for determination of soluble and insoluble Cr (III) and Cr (VI) compounds in welding fume at workplace air has been developed. The total chromium (Cr) was determined by using quadruple inductively coupled plasma mass spectrometry (ICP-MS) equipped with a dynamic reaction cell (DRC(®)). Soluble trivalent and hexavalent chromium compounds were determined by high performance liquid chromatography with inductively coupled plasma mass spectrometry (HPLC-ICP-MS). A high-speed, reversed-phase CR C8 column (PerkinElmer, Inc., Shelton, CT, USA) was used for the speciation of soluble Cr (III) and soluble Cr (VI). The separation was accomplished by interaction of the chromium species with the different components of the mobile phase. Cr (III) formed a complex with EDTA, i.e. retained on the column, while Cr (VI) existed in the solutions as dichromate. Alkaline extraction (2% KOH and 3% Na2CO3) and anion exchange column (PRP-X100, PEEK, Hamilton) were used for the separation of the total Cr (VI). The results of the determination of Cr (VI) were confirmed by the analysis of the certified reference material BCR CRM 545 (Cr (VI) in welding dust). The results obtained for the certified material (40.2±0.6 g kg(-1)) and the values recorded in the examined samples (40.7±0.6 g kg(-1)) were highly consistent. This analytical method was applied for the determination of chromium in the samples in the workplace air collected onto glass (Whatman, Ø 37 mm) and membrane filters (Sartorius, 0.8 μm, Ø 37 mm). High performance liquid chromatography with inductively coupled plasma mass spectrometry is a remarkably powerful and versatile technique for determination of chromium species in welding fume at workplace air.

  6. Chemical composition and mass size distribution of PM1 at an elevated site in central east China

    NASA Astrophysics Data System (ADS)

    Zhang, Y. M.; Zhang, X. Y.; Sun, J. Y.; Hu, G. Y.; Shen, X. J.; Wang, Y. Q.; Wang, T. T.; Wang, D. Z.; Zhao, Y.

    2014-11-01

    contributed 70% to the whole size range dominated by sulfate, which contributed 40% to small particles (100-200 nm), while organics occupied 20%, indicating that sulfate is a critical chemical component in cloud formation. Seven clusters of air masses were classified based on 72 h back-trajectory analysis. The majority of the regionally dispersed aerosols were found to be contributed from short distance mixed aerosols, mostly originated from the south with organics and sulfate as major components. Air masses from long range transport always brought clean and dry aerosols which resulted in low concentrations at Mt. Tai. AMS-PMF (positive matrix factorization) was employed to resolve the subtype of organics. Oxygenic organics aerosols (OAs) occupied 49, 56, 51, and 41% of OAs in the four seasons respectively, demonstrating that most OA were oxidized in summer due to strong photochemical reactions. Biomass burning OAs (BBOAs) accounted for 34% of OA in summer, mainly from field burning of agriculture residues, and coal combustion OAs (CCOAs) accounted for 22% of OA in winter from heating.

  7. Dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, fatty acids and benzoic acid in PM2.5 aerosol collected during CAREBeijing-2007: an effect of traffic restriction on air quality

    NASA Astrophysics Data System (ADS)

    Ho, K. F.; Huang, R.-J.; Kawamura, K.; Tachibana, E.; Lee, S. C.; Ho, S. S. H.; Zhu, T.; Tian, L.

    2014-06-01

    Thirty water-soluble organic species, including dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, fatty acids, and benzoic acid were determined as well as organic carbon (OC), elemental carbon (EC) and water-soluble organic carbon (WSOC) in PM2.5 samples collected during the Campaign of Air Quality Research in Beijing 2007 (CAREBeijing-2007) in the urban and suburban areas of Beijing. The objective of this study is to identify the influence of traffic emissions and regional transport to the atmosphere in Beijing during summer. PM2.5 samples collected with or without traffic restriction in Beijing are selected to evaluate the effectiveness of local traffic restriction measure on air pollution reduction. The average concentrations of the total quantified bifunctional organic compounds (TQBOC), total fatty acids and benzoic acid during the entire sampling period were 1184 ± 241 ng m-3, 597 ± 159 ng m-3 and 1496 ± 511ng m-3 in PKU, and 1050 ± 303 ng m-3, 475 ± 114 ng m-3 and 1278 ± 372 ng m-3 in Yufa. Oxalic acid (C2) was found as the most abundant dicarboxylic acid at PKU and Yufa, followed by phthalic acid (Ph). A strong even carbon number predominance with the highest level at palmitic acid (C16:0), followed by stearic acid (C18:0) was found for fatty acids. According to the back trajectories modeling results, the air masses were found to originate mainly from northeast, passing over southeast or south of Beijing (heavily populated, urbanized and industrialized areas), during heavier pollution events, whereas they are mainly from north or northwest sector (mountain areas without serious anthropogenic pollution sources) during cleaner events. The data with wind only from the same sector (minimizing the difference from regional contribution) but with and without traffic restriction in Beijing were analyzed to evaluate the effectiveness of local traffic restriction measure on the reduction of local air pollution in Beijing. The results suggested that the

  8. Dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, fatty acids and benzoic acid in PM2.5 aerosol collected during CAREBeijing-2007: an effect of traffic restriction on air quality

    NASA Astrophysics Data System (ADS)

    Ho, K. F.; Huang, R.-J.; Kawamura, K.; Tachibana, E.; Lee, S. C.; Ho, S. S. H.; Zhu, T.; Tian, L.

    2015-03-01

    Thirty water-soluble organic species, including dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, fatty acids and benzoic acid were determined as well as organic carbon (OC), elemental carbon (EC) and water-soluble organic carbon (WSOC) in PM2.5 samples collected during the Campaign of Air Quality Research in Beijing 2007 (CAREBeijing-2007) in the urban and suburban areas of Beijing. The objective of this study is to identify the influence of traffic emissions and regional transport to the atmosphere in Beijing during summer. PM2.5 samples collected with or without traffic restriction in Beijing are selected to evaluate the effectiveness of local traffic restriction measures on air pollution reduction. The average concentrations of the total quantified bifunctional organic compounds (TQBOCs), total fatty acids and benzoic acid during the entire sampling period were 1184±241, 597±159 and 1496±511 ng m-3 in Peking University (PKU), and 1050±303, 475±114 and 1278±372 ng m-3 in Yufa, Beijing. Oxalic acid (C2) was found as the most abundant dicarboxylic acid at PKU and Yufa followed by phthalic acid (Ph). A strong even carbon number predominance with the highest level at stearic acid (C18:0), followed by palmitic acid (C16:0) was found for fatty acids. According to the back trajectories modeling results, the air masses were found to originate mainly from the northeast, passing over the southeast or south of Beijing (heavily populated, urbanized and industrialized areas), during heavier pollution events, whereas they are mainly from the north or northwest sector (mountain areas without serious anthropogenic pollution sources) during less pollution events. The data with wind only from the same sector (minimizing the difference from regional contribution) but with and without traffic restriction in Beijing were analyzed to evaluate the effectiveness of local traffic restriction measures on the reduction of local air pollution in Beijing. The results suggested

  9. Heat and mass transfer in a dissociated laminar boundary layer of air with consideration of the finite rate of chemical reaction

    NASA Technical Reports Server (NTRS)

    Oyegbesan, A. O.; Algermissen, J.

    1986-01-01

    A numerical investigation of heat and mass transfer in a dissociated laminar boundary layer of air on an isothermal flat plate is carried out for different degrees of cooling of the wall. A finite-difference chemical model is used to study elementary reactions involving NO2 and N2O. The analysis is based on equations of continuity, momentum, energy, conservation and state for the two-dimensional viscous flow of a reacting multicomponent mixtures. Attention is given to the effects of both catalyticity and noncatalyticity of the wall.

  10. Design and preliminary tests of a blade tip air mass injection system for vortex modification and possible noise reduction on a full-scale helicopter rotor

    NASA Technical Reports Server (NTRS)

    Pegg, R. J.; Hosier, R. N.; Balcerak, J. C.; Johnson, H. K.

    1975-01-01

    Full-scale tests were conducted on the Langley helicopter rotor test facility as part of a study to evaluate the effectiveness of a turbulent blade tip air mass injection system in alleviating the impulsive noise (blade slap) caused by blade-vortex interaction. Although blade-slap conditions could not be induced during these tests, qualitative results from flow visualization studies using smoke showed that the differential velocity between the jet velocity and the rotor tip speed was a primary parameter controlling the vortex modification.

  11. Determination of Hazardous Air Pollutant Surrogates Using Resonance Enhanced Multi Photon Ionization - Time of Flight Mass Spectrometry

    EPA Science Inventory

    EPA?s preferred approach for regulatory emissions compliance is based upon real-time monitoring of individual hazardous air pollutants (HAPs). Real-time, continuous monitoring not only provides the most comprehensive assurance of emissions compliance, but also can serve as a pro...

  12. Monitoring of Hazardous Air Pollutant Surrogates Using Resonance Enhanced Multiphoton Ionization/Time of Flight Mass Spectrometry

    EPA Science Inventory

    EPA’s preferred approach for regulatory emissions compliance is based upon real-time monitoring of individual hazardous air pollutants (HAPs). Real-time, continuous monitoring not only provides the most comprehensive assurance of emissions compliance, but also can serve as...

  13. Inter-annual variability of air mass and acidified pollutants transboundary exchange in the north-eastern part of the EANET region

    NASA Astrophysics Data System (ADS)

    Gromov, Sergey A.; Trifonova-Yakovleva, Alisa; Gromov, Sergey S.

    2016-04-01

    Anthropogenic emissions, be it exhaust gases or aerosols, stem from multitude of sources and may survive long-range transport within the air masses they were emitted into. So they follow regional and global transport pathways varying under different climatological regimes. Transboundary transfer of pollutants occurs this way and has a significant impact on the ecological situation of the territories neighbouring those of emission sources, as found in a few earlier studies examining the environmental monitoring data [1]. In this study, we employ a relatively facile though robust technique for estimating the transboundary air and concomitant pollutant fluxes using actual or climatological meteorological and air pollution monitoring data. Practically, we assume pollutant transfer being proportional to the horizontal transport of air enclosed in the lower troposphere and to the concentration of the pollutant of interest. The horizontal transport, in turn, is estimated using the mean layer wind direction and strength, or their descriptive statistics at the individual transects of the boundary of interest. The domain of our interest is the segment of Russian continental border in East Asia spanning from 88° E (southern Middle Siberia) to 135° E (Far East at Pacific shore). The data on atmospheric pollutants concentration are available from the Russian monitoring sites of the region-wide Acid Deposition Monitoring Network in East Asia (EANET, http://www.eanet.asia/) Mondy (Baikal area) and Primorskaya (near Vladivostok). The data comprises multi-year continuous measurement of gas-phase and particulate species abundances in air with at least biweekly sampling rate starting from 2000. In the first phase of our study, we used climatological dataset on winds derived from the aerological soundings at Russian stations along the continental border for the 10-year period (1961-1970) by the Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) [3

  14. On the possibility to discriminate the mass of the primary cosmic ray using the muon arrival times from extensive air showers: Application for Pierre Auger Observatory

    SciTech Connect

    Arsene, N.; Rebel, H.; Sima, O.

    2012-11-20

    In this paper we study the possibility to discriminate the mass of the primary cosmic ray by observing the muon arrival times in ground detectors. We analyzed extensive air showers (EAS) induced by proton and iron nuclei with the same energy 8 Multiplication-Sign 10{sup 17} eV simulated with CORSIKA, and analyzed the muon arrival times at ground measured by the infill array detectors of the Pierre Auger Observatory (PAO). From the arrival times of the core and of the muons the atmospheric depth of muon generation locus is evaluated. The results suggest a potential mass discrimination on the basis of muon arrival times and of the reconstructed atmospheric depth of muon production. An analysis of a larger set of CORSIKA simulations carried out for primary energies above 10{sup 18} eV is in progress.

  15. [Analysis of the impact of two typical air pollution events on the air quality of Nanjing].

    PubMed

    Wang, Fei; Zhu, Bin; Kang, Han-Qing; Gao, Jin-Hui; Wang, Yin; Jiang, Qi

    2012-10-01

    Nanjing and the surrounding area have experienced two consecutive serious air pollution events from late October to early November in 2009. The first event was long-lasting haze pollution, and the second event was resulted from the mixed impact of crop residue burning and local transportation. The effects of regional transport and local sources on the two events were discussed by cluster analysis, using surface meteorological observations, air pollution index, satellite remote sensing of fire hot spots data and back trajectory model. The results showed that the accumulation-mode aerosol number concentrations were higher than those of any other aerosol modes in the two pollution processes. The peak value of aerosol particle number concentrations shifted to large particle size compare with the previous studies in this area. The ratio of SO4(2-)/NO3(-) was 1.30 and 0.99, indicating that stationary sources were more important than traffic sources in the first event and the reverse in the second event. Affected by the local sources from east and south, the particle counts below 0.1 microm gradually accumulated in the first event. The second event was mainly affected by a short-distance transport from northeast and local sources from southwest, especially south, the concentration of aerosol particles was higher than those in other directions, indicating that the sources of crop residue burning were mainly in this direction.

  16. Indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Point Arena, California

    NASA Technical Reports Server (NTRS)

    Parrish, D. D.; Hahn, C. J.; Williams, E. J.; Norton, R. B.; Fehsenfeld, F. C.; Singh, H. B.; Shetter, J. D.; Gandrud, B. W.; Ridley, B. A.

    1992-01-01

    Measurements were made of a suite of photochemically active trace species (including light hydrocarbons, ozone, peroxyacetyl nitrate, HNO3, NO3(-), NO(x), and NO(y)) in marine air collected during a 10-day period in April and May 1985 at Point Arena (California), a coastal inflow site. It was found that the mixing ratios of the alkanes, ozone, peroxyacetyl nitrate, and HNO3 correlated with variations in the origins of calculated air parcel trajectories and with variations in the ratios of the light alkanes. The highest levels of alkanes and the photochemical products were found in parcels that had been rapidly transported across the North Pacific Ocean from near the 600-mbar level above the east Asian coast. It is suggested that production over the continents, transport to the marine areas, and parallel removal processes account for much of the observed correlation.

  17. Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area

    PubMed Central

    Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

    2016-01-01

    Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose–response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m−3, range <0.023–3.0mg m−3) and below the present Swedish occupational exposure limit (OEL) of 10mg m−3. The cobalt levels were low as well (AM 0.0030mg m−3, range 0.000028–0.056mg m−3) and only 6% of the samples exceeded the Swedish OEL of 0.02mg m−3. For continuous personal monitoring of dust exposure, the peaks ranged from 0.001 to 83mg m−3 by work task. Stationary measurements showed lower average levels both for inhalable and total dust and cobalt. The particle number concentration of fine particles (AM 3000 p·cm−3) showed the highest levels at the departments of powder production, pressing and storage, and for the particle surface area concentrations (AM 7.6 µm2·cm−3) similar results were found. Correlating cobalt mass-based exposure measurements to cobalt stationary mass-based, particle area, and particle number concentrations by rank and department showed significant correlations for all measures except for particle

  18. Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area.

    PubMed

    Klasson, Maria; Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

    2016-07-01

    Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose-response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m(-3), range <0.023-3.0mg m(-3)) and below the present Swedish occupational exposure limit (OEL) of 10mg m(-3) The cobalt levels were low as well (AM 0.0030mg m(-3), range 0.000028-0.056mg m(-3)) and only 6% of the samples exceeded the Swedish OEL of 0.02mg m(-3) For continuous personal monitoring of dust exposure, the peaks ranged from 0.001 to 83mg m(-3) by work task. Stationary measurements showed lower average levels both for inhalable and total dust and cobalt. The particle number concentration of fine particles (AM 3000 p·cm(-3)) showed the highest levels at the departments of powder production, pressing and storage, and for the particle surface area concentrations (AM 7.6 µm(2)·cm(-3)) similar results were found. Correlating cobalt mass-based exposure measurements to cobalt stationary mass-based, particle area, and particle number concentrations by rank and department showed significant correlations for all measures except for particle number

  19. Measuring the temporal evolution of aerosol composition in a remote marine environment influenced by Saharan dust outflow using a new single particle mass spectrometer.

    NASA Astrophysics Data System (ADS)

    Marsden, Nicholas; Williams, Paul; Flynn, Michael; Taylor, Jonathan; Liu, Dantong; Allan, James; Coe, Hugh

    2016-04-01

    Refractory material constitutes a significant fraction of the atmospheric aerosol burden and has a strong influence on climate through the direct radiative effect and aerosol-cloud interactions, particularly in cold and mixed phase clouds. Composition of refractory aerosols is traditionally measured using off-line analytical techniques such as filter analyses. However, when using off-line techniques the temporal evolution of the data set is lost, meaning the measurements are difficult to relate to atmospheric processes. Recently, single particle mass spectrometry (SPMS) has proven a useful tool for the on-line study of refractory aerosols with the ability to probe size resolved chemical composition with high temporal resolution on a particle by particle basis. A new Laser Ablation Aerosol Time-of-Flight (LAAP-TOF) SPMS instrument with a modified optical detection system was deployed for ground based measurements at Praia, Cape Verde during the Ice in Cloud - Dust (ICE-D) multi-platform campaign in August 2015. A primary aim of the project was to evaluate the impact of Saharan dust on ice nucleation in mixed phase clouds. The instrument was operated over a 16 day period in which several hundred thousand single particle mass spectra were obtained from air masses with back trajectories traversing the Mid-Atlantic, Sahara Desert and West Africa. The data presented indicate external mixtures of sea salt and silicate mineral dust internally mixed with secondary species that are consistent with long range transport to a remote marine environment. The composition and size distributions measured with the LAAP-TOF are compared with measurements from an aerodynamic particle sizer (APS), Single Particle Soot Photometer (SP2), and data from SEM-EDX analysis of filter samples. The particle number fraction identified as silicate mineral from the mass spectra correlates with a fraction of the incandescent particles measured with the SP2. We discuss the suitability of the modified

  20. Desert dust aerosol air mass mapping in the western Sahara, using particle properties derived from space-based multi-angle imaging

    NASA Astrophysics Data System (ADS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Esselborn, Michael; Fiebig, Marcus; Heese, Birgit; Knippertz, Peter; Müller, Detlef; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

    2009-02-01

    ABSTRACT Coincident observations made over the Moroccan desert during the Sahara mineral dust experiment (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from multi-angle imaging spectroradiometer (MISR) observations, and to place the suborbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days during which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05-0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape and single-scattering albedo. For the three study days, the satellite observations (1) highlight regional gradients in the mix of dust and background spherical particles, (2) identify a dust plume most likely part of a density flow and (3) show an aerosol air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometres away.

  1. Desert Dust Air Mass Mapping in the Western Sahara, using Particle Properties Derived from Space-based Multi-angle Imaging

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Fiebig, Marcus; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

    2008-01-01

    Coincident observations made over the Moroccan desert during the SAhara Mineral dUst experiMent (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from Multi-angle Imaging SpectroRadiometer (MISR) observations, and to place the sub-orbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days for which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 to 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape, and single-scattering albedo. For the three study days, the satellite observations (a) highlight regional gradients in the mix of dust and background spherical particles, (b) identify a dust plume most likely part of a density flow, and (c) show an air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometers away.

  2. Desert Dust Aerosol Air Mass Mapping in the Western Sahara, Using Particle Properties Derived from Space-Based Multi-Angle Imaging

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Esselborn, Michael; Fiebig, Marcus; Heese, Birgit; Knippertz, Peter; Mueller, Detlef; Schladitz, Alexander; Von Hoyningen-Huene, Wolfgang

    2008-01-01

    Coincident observations made over the Moroccan desert during the Sahara mineral dust experiment (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from multi-angle imaging spectroradiometer (MISR) observations, and to place the suborbital aerosol measurements into the satellite s larger regional context. On three moderately dusty days during which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR s ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape and single-scattering albedo. For the three study days, the satellite observations (1) highlight regional gradients in the mix of dust and background spherical particles, (2) identify a dust plume most likely part of a density flow and (3) show an aerosol air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometres away.

  3. Determination of volatile organic compounds in urban and industrial air from Tarragona by thermal desorption and gas chromatography-mass spectrometry.

    PubMed

    Ras-Mallorquí, Maria Rosa; Marcé-Recasens, Rosa Maria; Borrull-Ballarín, Francesc

    2007-05-15

    This study describes the optimisation of an analytical method to determine 54 volatile organic compounds (VOCs) in air samples by active collection on multisorbent tubes, followed by thermal desorption and gas chromatography-mass spectrometry. Two multisorbent beds, Carbograph 1/Carboxen 1000 and Tenax/Carbograph 1TD, were tested. The latter gave better results, mainly in terms of the peaks that appeared in blank chromatograms. Temperatures, times and flow desorption were optimised. Recoveries were higher than 98.9%, except methylene dichloride, for which the recovery was 74.9%. The method's detection limits were between 0.01 and 1.25mugm(-3) for a volume sample of 1200ml, and the repeatability on analysis of 100ng of VOCs, expressed as relative standard deviation for n=3, was lower than 4% for all compounds. Urban and industrial air samples from the Tarragona region were analysed. Benzene, toluene, ethylbenzene and xylenes (BTEX) were found to be the most abundant VOCs in urban air. Total VOCs in urban samples ranged between 18 and 307mugm(-3). Methylene chloride, 1,4-dichlorobenzene, chloroform and styrene were the most abundant VOCs in industrial samples, and total VOCs ranged between 19 and 85mugm(-3).

  4. Quantification of VX vapor in ambient air by liquid chromatography isotope dilution tandem mass spectrometric analysis of glass bead filled sampling tubes.

    PubMed

    Evans, Ronald A; Smith, Wendy L; Nguyen, Nam-Phuong; Crouse, Kathy L; Crouse, Charles L; Norman, Steven D; Jakubowski, E Michael

    2011-02-15

    An analysis method has been developed for determining low parts-per-quadrillion by volume (ppqv) concentrations of nerve agent VX vapor actively sampled from ambient air. The method utilizes glass bead filled depot area air monitoring system (DAAMS) sampling tubes with isopropyl alcohol extraction and isotope dilution using liquid chromatography coupled with a triple-quadrupole mass spectrometer (LC/MS/MS) with positive ion electrospray ionization for quantitation. The dynamic range was from one-tenth of the worker population limit (WPL) to the short-term exposure limit (STEL) for a 24 L air sample taken over a 1 h period. The precision and accuracy of the method were evaluated using liquid-spiked tubes, and the collection characteristics of the DAAMS tubes were assessed by collecting trace level vapor generated in a 1000 L continuous flow chamber. The method described here has significant improvements over currently employed thermal desorption techniques that utilize a silver fluoride pad during sampling to convert VX to a higher volatility G-analogue for gas chromatographic analysis. The benefits of this method are the ability to directly analyze VX with improved selectivity and sensitivity, the injection of a fraction of the extract, quantitation using an isotopically labeled internal standard, and a short instrument cycle time.

  5. In-Line Ozonation for Sensitive Air-Monitoring of a Mustard-Gas Simulant by Atmospheric Pressure Chemical Ionization Mass Spectrometry.

    PubMed

    Okumura, Akihiko

    2015-09-01

    A highly sensitive method for real-time air-monitoring of mustard gas (bis(2-chloroethyl) sulfide, HD), which is a lethal blister agent, is proposed. Humidified air containing a HD simulant, 2-chloroethyl ethyl sulfide (2CEES), was mixed with ozone and then analyzed by using an atmospheric pressure chemical ionization ion trap tandem mass spectrometer. Mass-spectral ion peaks attributable to protonated molecules of intact, monooxygenated, and dioxygenated 2CEES (MH(+), MOH(+), and MO(2)H(+), respectively) were observed. As ozone concentration was increased from zero to 30 ppm, the signal intensity of MH(+) sharply decreased, that of MOH(+) increased once and then decreased, and that of MO(2)H(+) sharply increased until reaching a plateau. The signal intensity of MO(2)H(+) at the plateau was 40 times higher than that of MH(+) and 100 times higher than that of MOH(+) in the case without in-line ozonation. Twenty-ppm ozone gas was adequate to give a linear calibration curve for 2CEES obtained by detecting the MO(2)H(+) signal in the concentration range up to 60 μg/m(3), which is high enough for hygiene management. In the low concentration range lower than 3 μg/m(3), which is equal to the short-term exposure limit for HD, calibration plots unexpectedly fell off the linear calibration curve, but 0.6-μg/m(3) vapor was actually detected with the signal-to-noise ratio of nine. Ozone was generated from instrumentation air by using a simple and inexpensive home-made generator. 2CEES was ozonated in 1-m extended sampling tube in only 1 s.

  6. In-Line Ozonation for Sensitive Air-Monitoring of a Mustard-Gas Simulant by Atmospheric Pressure Chemical Ionization Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Okumura, Akihiko

    2015-09-01

    A highly sensitive method for real-time air-monitoring of mustard gas (bis(2-chloroethyl) sulfide, HD), which is a lethal blister agent, is proposed. Humidified air containing a HD simulant, 2-chloroethyl ethyl sulfide (2CEES), was mixed with ozone and then analyzed by using an atmospheric pressure chemical ionization ion trap tandem mass spectrometer. Mass-spectral ion peaks attributable to protonated molecules of intact, monooxygenated, and dioxygenated 2CEES (MH+, MOH+, and MO2H+, respectively) were observed. As ozone concentration was increased from zero to 30 ppm, the signal intensity of MH+ sharply decreased, that of MOH+ increased once and then decreased, and that of MO2H+ sharply increased until reaching a plateau. The signal intensity of MO2H+ at the plateau was 40 times higher than that of MH+ and 100 times higher than that of MOH+ in the case without in-line ozonation. Twenty-ppm ozone gas was adequate to give a linear calibration curve for 2CEES obtained by detecting the MO2H+ signal in the concentration range up to 60 μg/m3, which is high enough for hygiene management. In the low concentration range lower than 3 μg/m3, which is equal to the short-term exposure limit for HD, calibration plots unexpectedly fell off the linear calibration curve, but 0.6-μg/m3 vapor was actually detected with the signal-to-noise ratio of nine. Ozone was generated from instrumentation air by using a simple and inexpensive home-made generator. 2CEES was ozonated in 1-m extended sampling tube in only 1 s.

  7. Quantification of the sources and composition of particulate matter by field-deployable mass spectrometry: implications for air quality and public health.

    PubMed

    Hayes, Patrick L

    2017-02-27

    Airborne particulate matter less than 2.5 μm in diameter (PM2.5) negatively impacts air quality in cities throughout the world where it has been linked to increased cardiac and respiratory morbidity and mortality. For this reason PM2.5 standards have been established by many countries and the World Health Organization. However, these guidelines are regularly exceeded in North America, Europe and East Asia. While PM2.5 is often reported as a single atmospheric species, it is actually a mixture of organic and inorganic compounds. The organic fraction, termed organic aerosol (OA), contributes approximately 20-70% of the PM2.5 mass globally, and OA itself is a complex mixture of thousands of compounds. Characterizing the chemical properties of OA represents a major analytical challenge that has motivated the development of a range of new instruments. The focus of this perspective is the use of field-deployable mass spectrometers and in particular the Aerodyne Aerosol Mass Spectrometer (AMS) for chemically characterizing submicron particles. Field measurements of the composition of PM2.5 are directly relevant to evaluating its health impact because reductions in life expectancy due to PM2.5 vary according to composition. In addition, AMS measurements are especially useful for characterizing OA. The sources of OA are not well understood as evidenced by the performance of many air quality models, including those run by government agencies, which lack accurate and well constrained parameterizations for simulating secondary OA concentrations in urban regions. Given that OA is an important component of the total PM2.5 mass, this uncertainty makes accurate evaluation of the impact of PM2.5 on public health difficult, especially when evaluating future mitigation strategies. The development of the AMS has been a critical step towards addressing this public health challenge in that it provides quantitative data regarding particulate matter and OA concentration and composition

  8. Student Understanding of the Volume, Mass, and Pressure of Air within a Sealed Syringe in Different States of Compression.

    ERIC Educational Resources Information Center

    de Berg, Kevin Charles

    1995-01-01

    Investigation of (n=101) 17- to 18-year-old students' responses to a task relating to Boyle's Law for gases found that 34% to 38% of students did not understand the concepts of volume and mass, respectively, of a gas under the given circumstances. (Author/MKR)

  9. Mass of chlorinated volatile organic compounds removed by Pump-and-Treat, Naval Air Warfare Center, West Trenton, New Jersey, 1996-2010

    USGS Publications Warehouse

    Lacombe, Pierre J.

    2011-01-01

    Pump and Treat (P&T) remediation is the primary technique used to contain and remove trichloroethylene (TCE) and its degradation products cis 1-2,dichloroethylene (cDCE) and vinyl chloride (VC) from groundwater at the Naval Air Warfare Center (NAWC), West Trenton, NJ. Three methods were used to determine the masses of TCE, cDCE, and VC removed from groundwater by the P&T system since it became fully operational in 1996. Method 1, is based on the flow volume and concentrations of TCE, cDCE, and VC in groundwater that entered the P&T building as influent. Method 2 is based on withdrawal volume from each active recovery well and the concentrations of TCE, cDCE, and VC in the water samples from each well. Method 3 compares the maximum monthly amount of TCE, cDCE, and VC from Method 1 and Method 2. The greater of the two values is selected to represent the masses of TCE, cDCE and VC removed from groundwater each month. Previously published P&T monthly reports used Method 1 to determine the mass of TCE, cDCE, and VC removed. The reports state that 8,666 pounds (lbs) of TCE, 13,689 lbs of cDCE, and 2,455 lbs of VC were removed by the P&T system during 1996-2010. By using Method 2, the mass removed was determined to be 8,985 lbs of TCE, 17,801 lbs of cDCE, and 3,056 lbs of VC removed, and Method 3, resulted in 10,602 lbs of TCE, 21,029 lbs of cDCE, and 3,496 lbs of VC removed. To determine the mass of original TCE removed from groundwater, the individual masses of TCE, cDCE, and VC (determined using Methods 1, 2, and 3) were converted to numbers of moles, summed, and converted to pounds of original TCE. By using the molar conversion the mass of original TCE removed from groundwater by Methods 1, 2, and 3 was 32,381 lbs, 39,535 lbs, and 46,452 lbs, respectively, during 1996-2010. P&T monthly reports state that 24,805 lbs of summed TCE, cDCE, and VC were removed from groundwater. The simple summing method underestimates the mass of original TCE removed by the P&T system.

  10. Relationship between maternal pre‐pregnancy body mass index, gestational weight gain and childhood fatness at 6–7 years by air displacement plethysmography

    PubMed Central

    Santos, Iná S.; Matijasevich, Alicia

    2015-01-01

    Abstract This study aims to investigate the effect of maternal pre‐pregnancy body mass index (BMI) and gestational weight gain (GWG) on offspring body composition. In this prospective cohort study, offspring body composition at 6 years of age was obtained through air displacement plethysmography. Linear regression was used to obtain crude and adjusted coefficients. Information regarding offspring body composition and maternal pre‐pregnancy BMI was available for 3156 children and on offspring body composition and GWG for 3129 children. There was a direct association of maternal pre‐pregnancy BMI and GWG with offspring's fat mass (FM), fat‐free mass (FFM), fat mass index (FMI), fat‐free mass index (FFMI) and body fat percent (BF%) in crude and adjusted analyses. After adjustment for co‐variables, for each kg m−2 of maternal pre‐pregnancy BMI increase, there was a mean increment of 0.13 kg in the offspring FFM, 0.06 kg m−2 in FFMI, 0.11 kg in FM, 0.07 kg m−2 in FMI and 0.18% in BF%. For each kilogram of maternal GWG increase, there was a mean increment of 0.08 kg in offspring's FM, 0.05 kg m−2 in FMI, 0.04 kg in FFM, 0.01 kg m−2 in FFMI and 0.18 % in BF%. Mothers with a higher pre‐pregnancy BMI or GWG tend to have children with greater adiposity at age 6 years. Fetal overnutrition is more likely among mothers with greater BMI during pregnancy; as a consequence, it can accelerate the childhood obesity epidemic. PMID:25850519

  11. Dynamic behavior of air lubricated pivoted-pad journal-bearing, rotor system. 2: Pivot consideration and pad mass

    NASA Technical Reports Server (NTRS)

    Nemeth, Z. N.

    1972-01-01

    Rotor bearing dynamic tests were conducted with tilting-pad journal bearings having three different pad masses and two different pivot geometries. The rotor was vertically mounted and supported by two three-pad tilting-pad gas journal bearings and a simple externally pressurized thrust bearing. The bearing pads were 5.1 cm (2.02 in.) in diameter and 2.8 cm (1.5 in.) long. The length to diameter ratio was 0.75. One pad was mounted on a flexible diaphragm. The bearing supply pressure ranged from 0 to 690 kilonewtons per square meter (0 to 100 psig), and speeds ranged to 38,500 rpm. Heavy mass pad tilting-pad assemblies produced three rotor-bearing resonances above the first two rotor critical speeds. Lower supply pressure eliminated the resonances. The resonances were oriented primarily in the direction normal to the diaphragm.

  12. Assessment of the Losses Due to Self Absorption by Mass Loading on Radioactive Particulate Air Stack Sample Filters

    SciTech Connect

    Smith, Brian M.; Barnett, J. Matthew; Ballinger, Marcel Y.

    2011-01-18

    This report discusses the effect of mass loading of a membrane filter on the self absorption of radioactive particles. A relationship between mass loading and percent loss of activity is presented. Sample filters were collected from Pacific Northwest National Laboratory (PNNL) facilities in order to analyze the current self absorption correction factor of 0.85 that is being used for both alpha and beta particles. Over an eighteen month period from February 2009 to July 2010, 116 samples were collected and analyzed from eight different building stacks in an effort coordinated by the Effluent Management group. Eleven unused filters were also randomly chosen to be analyzed in order to determine background radiation. All of these samples were collected and analyzed in order to evaluate the current correction factor being used.

  13. Proton transfer reaction mass spectrometry for the sensitive and rapid real-time detection of solid high explosives in air and water.

    PubMed

    Jürschik, S; Sulzer, P; Petersson, F; Mayhew, C A; Jordan, A; Agarwal, B; Haidacher, S; Seehauser, H; Becker, K; Märk, T D

    2010-12-01

    Relying on recent developments in proton transfer reaction mass spectrometry (PTR-MS), we demonstrate here the capability of detecting solid explosives in air and in water in real time. Two different proton transfer reaction mass spectrometers have been used in this study. One is the PTR-TOF 8000, which has an enhanced mass resolution (m/Δm up to 8,000) and high sensitivity (~50 cps/ppbv). The second is the high-sensitivity PTR-MS, which has an improved limit of detection of about several hundreds of parts per quadrillion by volume and is coupled with a direct aqueous injection device. These instruments have been successfully used to identify and monitor the solid explosive 2,4,6-trinitrotoluene (TNT) by analysing on the one hand the headspace above small quantities of samples at room temperature and from trace quantities not visible to the naked eye placed on surfaces (also demonstrating the usefulness of a simple pre-concentration and thermal desorption technique) and by analysing on the other hand trace compounds in water down to a level of about 100 pptw. The ability to identify even minute amounts of threat compounds, such as explosives, particularly within a complex chemical environment, is vital to the fight against crime and terrorism and is of paramount importance for the appraisal of the fate and harmful effects of TNT at marine ammunition dumping sites and the detection of buried antipersonnel and antitank landmines.

  14. Estimation of air-water gas exchange coefficient in a shallow lagoon based on 222Rn mass balance.

    PubMed

    Cockenpot, S; Claude, C; Radakovitch, O

    2015-05-01

    The radon-222 mass balance is now commonly used to quantify water fluxes due to Submarine Groundwater Discharge (SGD) in coastal areas. One of the main loss terms of this mass balance, the radon evasion to the atmosphere, is based on empirical equations. This term is generally estimated using one among the many empirical equations describing the gas transfer velocity as a function of wind speed that have been proposed in the literature. These equations were, however, mainly obtained from areas of deep water and may be less appropriate for shallow areas. Here, we calculate the radon mass balance for a windy shallow coastal lagoon (mean depth of 6m and surface area of 1.55*10(8) m(2)) and use these data to estimate the radon loss to the atmosphere and the corresponding gas transfer velocity. We present new equations, adapted to our shallow water body, to express the gas transfer velocity as a function of wind speed at 10 m height (wind range from 2 to 12.5 m/s). When compared with those from the literature, these equations fit particularly well with the one of Kremer et al. (2003). Finally, we emphasize that some gas transfer exchange may always occur, even for conditions without wind.

  15. Turbulent mass flux closure modeling for variable density turbulence in the wake of an air-entraining transom stern

    NASA Astrophysics Data System (ADS)

    Hendrickson, Kelli; Yue, Dick

    2016-11-01

    This work presents the development and a priori testing of closure models for the incompressible highly-variable density turbulent (IHVDT) flow in the near wake region of a transom stern. This complex, three-dimensional flow includes three regions with distinctly different flow behavior: (i) the convergent corner waves that originate from the body and collide on the ship center plane; (ii) the "rooster tail" that forms from the collision; and (iii) the diverging wave train. The characteristics of these regions involve violent free-surface flows and breaking waves with significant turbulent mass flux (TMF) at Atwood number At = (ρ2 -ρ1) / (ρ2 +ρ1) 1 for which there is little guidance in turbulence closure modeling for the momentum and scalar transport along the wake. Utilizing datasets from high-resolution simulations of the near wake of a canonical three-dimensional transom stern using conservative Volume-of-Fluid (cVOF), implicit Large Eddy Simulation (iLES), and Boundary Data Immersion Method (BDIM), we develop explicit algebraic turbulent mass flux closure models that incorporate the most relevant physical processes. Performance of these models in predicting the turbulent mass flux in all three regions of the wake will be presented. Office of Naval Research.

  16. Flapping Wing Micro Air Vehicles: An Analysis of the Importance of the Mass of the Wings to Flight Dynamics, Stability, and Control

    NASA Astrophysics Data System (ADS)

    Orlowski, Christopher T.

    The flight dynamics, stability, and control of a model flapping wing micro air vehicle are analyzed with a focus on the inertial and mass effects of the wings on the position and Orientation of the body. A multi-body, flight dynamics model is derived from first principles. The multi-body model predicts significant differences in the position and orientation of the flapping wing micro air vehicle, when compared to a flight dynamics model based on the standard aircraft, or six degree of freedom, equations of motion. The strongly coupled, multi-body equations of motion are transformed into first order form using an approximate inverse and appropriate assumptions. Local (naive) averaging of the first order system does not produce an accurate result and a new approximation technique named 'quarter-cycle' averaging is proposed. The technique is effective in reducing the error by at least an order of magnitude for three reference flight conditions. A stability analysis of the local averaged equations of motions, in the vicinity of a hover condition, produces a modal structure consist with the most common vertical takeoff or landing structure and independent stability analyses of the linearized flight dynamics of insect models. The inclusion of the wing effects produces a non-negligible change in the linear stability of a hawkmoth-sized model. The hovering solution is shown, under proper control, to produce a limit cycle. The control input to achieve a limit cycle is different if the flight dynamics model includes the wing effects or does not include the wing effects. Improper control input application will not produce the desired limit cycle effects. A scaling analysis is used to analyze the relative importance of the mass of the wings, based on the quarter-cycle approximation. The conclusion of the scaling analysis is that the linear momentum effects of the wings are always important in terms of the inertial position of the flapping wing micro air vehicle. Above a

  17. Evidence from catch-up growth and hoarding behavior of rats that exposure to hypobaric air lowers the body-mass set point.

    PubMed

    Bozzini, Carlos E; Lezón, Christian E; Norese, María F; Conti, María I; Martínez, María P; Olivera, María I; Alippi, Rosa M

    2005-01-01

    The depression of body growth rate and the reduction of body mass for chronological age and gender in growing experimental animals exposed to hypobaric air (simulated high altitude = SHA) have been associated with hypophagia because of reduced appetite. Catch-up growth during protein recovery after a short period of protein restriction only occurs if food intake becomes super-normal, which should not be possible under hypoxic conditions if the set-point for appetite is adjusted by the level of SHA. The present investigation was designed to test the hypothesis that growth retardation during exposure to SHA is due to an alteration of the neural mechanism for setting body mass size rather than a primary alteration of the central set-point for appetite. One group of female rats aged 35 d were exposed to SHA (5460m) in a SHA chamber for 27 d (HX rats). Other group was maintained under local barometric pressure conditions (NX rats). One half of both NX and HX rats were fed a protein-free diet for the initial 9 d of the experimental period. From this time on, they were fed a diet containing 20% protein, as were the remaining rats of both groups during the entire experimental period. The growth rates of both mass and length of the body were significantly depressed in well-nourished rats exposed to SHA during the entire observation period when compared to normoxic ones. At its end, body mass and body length were 24% and 21% less in HX than in NX rats. Growth rates were negatively affected by protein restriction in both NX and HX rats. During protein recovery, they reached supernormal values in response to supernormal levels of energy intake that allowed a complete catch-up of both body mass and length. The finding that energy intake during the period of protein rehabilitation in HX rats previously stunted by protein restriction was markedly higher than in HX control ones at equal levels of hypoxia demonstrates that the degree of hypoxia does not determine directly the

  18. Remote sensing observations for monitoring and mathematical simulations of transboundary air pollutants migration from Siberian mass wildfires to Kazakhstan

    NASA Astrophysics Data System (ADS)

    Kaipov, I. V.

    2017-03-01

    Anthropogenic and natural factors have increased the power of wildfires in massive Siberian woodlands. As a consequence, the expansion of burned areas and increase in the duration of the forest fire season have led to the release of significant amounts of gases and aerosols. Therefore, it is important to understand the impact of wildland fires on air quality, atmospheric composition, climate and accurately describe the distribution of combustion products in time and space. The most effective research tool is the regional hydrodynamic model of the atmosphere, coupled with the model of pollutants transport and chemical interaction. Taking into account the meteorological parameters and processes of chemical interaction of impurities, complex use of remote sensing techniques for monitoring massive forest fires and mathematical modeling of long-range transport of pollutants in the atmosphere, allow to evaluate spatial and temporal scale of the phenomenon and calculate the quantitative characteristics of pollutants depending on the height and distance of migration.

  19. Development and Evaluation of an Externally Air-Cooled Low-Flow torch and the Attenuation of Space Charge and Matrix Effects in Inductively Coupled Plasma Mass Spectrometry

    SciTech Connect

    Praphairaksit, Narong

    2000-09-12

    An externally air-cooled low-flow torch has been constructed and successfully demonstrated for applications in inductively coupled plasma mass spectrometry (ICP-MS). The torch is cooled by pressurized air flowing at ~70 L/min through a quartz air jacket onto the exterior of the outer tube. The outer gas flow rate and operating RF forward power are reduced considerably. Although plasmas can be sustained at the operating power as low as 400 W with a 2 L/min of outer gas flow, somewhat higher power and outer gas flows are advisable. A stable and analytical useful plasma can be obtained at 850 W with an outer gas flow rate of ~4 L/min. Under these conditions, the air-cooled plasma produces comparable sensitivities, doubly charged ion ratios, matrix effects and other analytical merits as those produced by a conventional torch while using significantly less argon and power requirements. Metal oxide ion ratios are slightly higher with the air-cooled plasma but can be mitigated by reducing the aerosol gas flow rate slightly with only minor sacrifice in analyte sensitivity. A methodology to alleviate the space charge and matrix effects in ICP-MS has been developed. A supplemental electron source adapted from a conventional electron impact ionizer is added to the base of the skimmer. Electrons supplied from this source downstream of the skimmer with suitable amount and energy can neutralize the positive ions in the beam extracted from the plasma and diminish the space charge repulsion between them. As a result, the overall ion transmission efficiency and consequent analyte ion sensitivities are significantly improved while other important analytical aspects, such as metal oxide ion ratio, doubly charged ion ratio and background ions remain relatively unchanged with the operation of this electron source. This technique not only improves the ion transmission efficiency but also minimizes the matrix effects drastically. The matrix-induced suppression of signal for even the most

  20. Time-of-flight secondary ion mass spectroscopy with bismuth primary ions of clean and air-exposed surfaces of tellurium.

    PubMed

    Trzyna, Malgorzata; Berchenko, Nicolas; Rading, Derk; Cebulski, Jozef

    2014-01-01

    The regularity of Bi(+), Bi(3+) and Bi(3++) primary ions in the time- of-flight secondary ion mass spectroscopy fragment pattern of air oxidized Te and Bi(+) direct-current scan cleaned Te is discussed. The most intensive fragments for a cleaned Te surface are positive and negative Tex and BiTex clusters. The sequence of secondary ion cluster formation is Bi-Te alloying followed by sputtering and ionization. For oxidized Te the chemical composition of the produced TexOy fragments satisfies the relation y=2x for positive fragments and y=2x+1 for negative ones. Experimental findings are in a good agreement with the results predicted by Plog's model for TeO2.

  1. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery. part I: Bridging mass transport and charge transfer with redox cycle kinetics

    NASA Astrophysics Data System (ADS)

    Jin, Xinfang; Zhao, Xuan; Huang, Kevin

    2015-04-01

    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JMAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H2/H2O-concentration across various components of the battery are also systematically investigated.

  2. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery part I: Bridging mass transport and charge transfer with redox cycle kinetics

    SciTech Connect

    Jin, XF; Zhao, X; Huang, K

    2015-04-15

    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JIVIAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H-2/H2O-concentration across various components of the battery are also systematically investigated. (C) 2015 Elsevier B.V. All rights reserved.

  3. Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Rosner, D. E.

    1984-01-01

    A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

  4. Application of proton-transfer-reaction mass spectrometry to the assessment of odorant removal in a biological air cleaner for pig production.

    PubMed

    Hansen, Michael J; Liu, Dezhao; Guldberg, Lise Bonne; Feilberg, Anders

    2012-03-14

    There is an urgent need to develop odor reduction technologies for animal production facilities, and this requires a reliable measurement technique for estimating the removal of odorants. The purpose of the present experiment was to investigate the application of proton-transfer-reaction mass spectrometry (PTR-MS) for continuous measurements at a biofilter from SKOV A/S installed at a pig production facility. PTR-MS was able to handle the harsh conditions with high humidity and dust load in a biofilter and provide reliable data for the removal of odorants, including the highly odorous sulfur compounds. The biofilter removed 80-99% of carboxylic acids, aldehydes, ketones, phenols, and indoles and ca. 75% of hydrogen sulfide. However, only ~0-15% of methanethiol and dimethyl sulfide was removed. In conclusion, PTR-MS is a promising tool that can be used to improve the development of biological air cleaning and other odor reduction technologies toward significant odorants.

  5. Photochemistry of the indoor air pollutant acetone on Degussa P25 TiO2 studied by chemical ionization mass spectrometry.

    PubMed

    Schmidt, Catherine M; Buchbinder, Avram M; Weitz, Eric; Geiger, Franz M

    2007-12-20

    We have used chemical ionization mass spectrometry (CIMS) to study the adsorption and photochemistry of several oxygenated organic species adsorbed to Degussa P25 TiO2, an inexpensive catalyst that can be used to mineralize volatile organic compounds. The molecules examined in this work include the common indoor air pollutant acetone and several of its homologs and possible oxidation and condensation products that may be formed during the adsorption and/or photocatalytic degradation of acetone on titanium dioxide catalysts. We report nonreactive uptake coefficients for acetone, formic acid, acetic acid, mesityl oxide, and diacetone alcohol, and results from photochemical studies that quantify, on a per-molecule basis, the room-temperature photocatalytic conversion of the species under investigation to CO2 and related oxidation products. The data presented here imply that catalytic surfaces that enhance formate and acetate production from acetone precursors will facilitate the photocatalytic remediation of acetone in indoor environments, even at room temperature.

  6. Distortion of thermospheric air masses by horizontal neutral winds over Poker Flat Alaska measured using an all-sky scanning Doppler imager

    NASA Astrophysics Data System (ADS)

    Dhadly, M. S.; Conde, M.

    2016-01-01

    An air mass transported by a wind field will become distorted over time by any gradients present in the wind field. To study this effect in Earth's thermosphere, we examine the behavior of a simple parameter that we describe here as the "distortion gradient." It incorporates all of the wind field's departures from uniformity and is thus capable of representing all contributions to the distortion or mixing of air masses. The distortion gradient is defined such that it is always positive, so averaging over time and/or space does not suppress small-scale features. Conventional gradients, by contrast, are signed quantities that would often average to zero. To analyze the climatological behavior of this distortion gradient, we used three years (2010, 2011, and 2012) of thermospheric F region wind observations from a high-latitude ground-based all-sky wavelength scanning Doppler Fabry-Perot interferometer located at Poker Flat Alaska. Climatological averaging of the distortion gradient allowed us to investigate its diurnal and seasonal (annual) behaviors at our observing location. Distortion was observed to be higher before local magnetic midnight and to be seasonally dependent. While maximum distortion occurred before local magnetic midnight under all geomagnetic conditions, the peak distortion occurred earlier under moderate geomagnetic conditions as compared to the quiet geomagnetic conditions and even earlier still when geomagnetic conditions were active. Peak distortion was stronger and appeared earlier when interplanetary magnetic field (IMF) was southward compared to northward. By contrast, we could not resolve any time-shift effect due to the IMF component tangential to Earth's orbit.

  7. Thermally-driven advections of aerosol-rich air masses to an Alpine valley: Theoretical considerations and experimental evidences

    NASA Astrophysics Data System (ADS)

    Diémoz, Henri; Magri, Tiziana; Pession, Giordano; Zublena, Manuela; Campanelli, Monica; Gobbi, Gian Paolo; Barnaba, Francesca; Di Liberto, Luca; Dionisi, Davide

    2016-04-01

    A CHM-15k laser radar (lidar) was installed in April 2015 at the solar observatory of the Environmental Protection Agency (ARPA) of the Aosta Valley (Northern Italy, 45.74N, 7.36E, 560 m a.s.l.). The instrument operates at 1064 nm, is capable of mapping the vertical profile of aerosols and clouds up to the tropopause and is part of the Alice-net ceilometers network (www.alice-net.eu). The site is in a large Alpine valley floor, in a semi-rural context. Among the most interesting cases observed in the first months of operation, several days characterised by weak synoptic circulation and well-developed, thermally-driven up-valley winds are accompanied by the appearance of a thick aerosol layer in the afternoon. The phenomenon is frequent in Spring and Summer and is likely to be related to easterly airmass advections from polluted sites (e.g., the Po basin) rather than to local emissions. To test this hypothesis, the following method was adopted. First, some case studies were selected and the respective meteorological fields were analysed based on both observations at ground and the high-resolution output of the nonhydrostatic limited-area atmospheric prediction model maintained by the COnsortium for Small-scale MOdelling (COSMO) over the complex orography of the domain. Then, to evaluate the dynamics of the aerosol diffusion in the valley, the chemical transport 2D/3D eulerian Flexible Air quality Regional Model (FARM) was run. Finally, the three-dimensional output of the model was compared to the vertically-resolved aerosol field derived from the lidar-ceilometer soundings. The effects of up-slope winds, and the resulting subsidence along the main axis of the valley, is hypothesised to break up the aerosol layer close to the ground in the middle of the day and to drag the residual layer down into the mixing layer. The measurements by a co-located sun/sky photometer operating in the framework of the EuroSkyRad (ESR) network were additionally analysed to detect any

  8. Comparison of negative-ion proton-transfer with iodide ion chemical ionization mass spectrometry for quantification of isocyanic acid in ambient air

    NASA Astrophysics Data System (ADS)

    Woodward-Massey, Robert; Taha, Youssef M.; Moussa, Samar G.; Osthoff, Hans D.

    2014-12-01

    Isocyanic acid (HNCO) is a trace gas pollutant of potential importance to human health whose measurement has recently become possible through the development of negative-ion proton-transfer chemical ionization mass spectrometry (NI-PT-CIMS) with acetate reagent ion. In this manuscript, an alternative ionization and detection scheme, in which HNCO is quantified by iodide CIMS (iCIMS) as a cluster ion at m/z 170, is described. The sensitivity was inversely proportional to water vapor concentration but could be made independent of humidity changes in the sampled air by humidifying the ion-molecule reaction (IMR) region of the CIMS. The performance of the two ionization schemes was compared and contrasted using ambient air measurements of HNCO mixing ratios in Calgary, AB, Canada, by NI-PT-CIMS with acetate reagent ion from Dec 16 to 20, 2013, and by the same CIMS operated in iCIMS mode from Feb 3 to 7, 2014. The iCIMS exhibited a greater signal-to-noise ratio than the NI-PT-CIMS, not because of its sensitivity, which was lower (˜0.083 normalized counts per second (NCPS) per parts-per-trillion by volume (pptv) compared to ˜9.7 NCPS pptv-1), but because of a much lower and more stable background (3 ± 4 compared to a range of ˜2 × 103 to ˜6 × 103 NCPS). For the Feb 2014 data set, the HNCO mixing ratios in Calgary air ranged from <12 to 94 pptv (median 34 pptv), were marginally higher at night than during day, and correlated with nitrogen oxide (NOx = NO + NO2) mixing ratios and submicron particle volume. The ratios of HNCO to NOx observed are within the range of emission ratios reported for gasoline-powered motor vehicles.

  9. Measurement of toxic volatile organic compounds in indoor air of semiconductor foundries using multisorbent adsorption/thermal desorption coupled with gas chromatography-mass spectrometry.

    PubMed

    Wu, Chien-Hou; Lin, Ming-Nan; Feng, Chien-Tai; Yang, Kuang-Ling; Lo, Yu-Shiu; Lo, Jiunn-Guang

    2003-05-09

    A method for the qualitative and quantitative analysis of volatile organic compounds (VOCs) in the air of class-100 clean rooms at semiconductor fabrication facilities was developed. Air samples from two semiconductor factories were collected each hour on multisorbent tubes (including Carbopack B, Carbopack C, and Carbosieve SIII) with a 24-h automatic active sampling system and analyzed using adsorption/thermal desorption coupled with gas chromatography-mass spectrometry. Experimental parameters, including thermal desorption temperature, desorption time, and cryofocusing temperature, were optimized. The average recoveries and the method detection limits for the target compounds were in the range 94-101% and 0.31-0.89 ppb, respectively, under the conditions of a 1 L sampling volume and 80% relative humidity. VOCs such as acetone, isopropyl alcohol, 2-heptanone, and toluene, which are commonly used in the semiconductor and electronics industries, were detected and accurately quantified with the established method. Temporal variations of the analyte concentrations observed were attributed to the improper use of organic solvents during operation.

  10. Molecular characterisation of organic material in air fine particles (PM10) using conventional and reactive pyrolysis-gas chromatography-mass spectrometry.

    PubMed

    Fabbri, Daniele; Prati, Silvia; Vassura, Ivano

    2002-04-01

    Pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) was applied to study the composition of organic constituents in air particulate matter (PM10) collected inside an industrial area. A few milligrams of sampling filters containing air particles were pyrolysed at 700 degrees C directly (conventional) or after the addition of a derivatising reagent (tetramethylammonium hydroxide, TMAH, for pyrolysis-methylation; hexamethyldisilazane, HMDS, for pyrolysis-silylation). Py-GC-MS was also applied to synthetic polymers (poly(styrene-co-isoprene), polylimonene and polypinene) and vegetation samples (coniferous pollen, bark and resin) to identify markers indicative of possible precursors. Pyrolysates of PM10 showed the same suite of compounds in all the four seasons, dominated by hydrocarbons like styrene, limonene and clusters of isomeric alkenes with 14, 15 and 16 carbon atoms. Pyrolysis products of natural origin, including furaldehyde, benzeneacetonitrile, dehydroabietin and other diterpenoids were found, while no specific markers of synthetic rubbers were detected. The principal products released from reactive pyrolysis of PM10 were methyl or trimethylsilyl (TMS) derivatives of 1,6-anhydroglucose (levoglucosan), fatty acids, dehydroabietic acid and other resin acids along with hydroxy (di)carboxylic acids. Possible sources of the detected products (e.g. pine forest, biomass combustion) are discussed.

  11. 3D Air Quality and the Clean Air Interstate Rule: Lagrangian Sampling of CMAQ Model Results to Aid Regional Accountability Metrics

    NASA Technical Reports Server (NTRS)

    Fairlie, T. D.; Szykman, Jim; Pierce, Robert B.; Gilliland, A. B.; Engel-Cox, Jill; Weber, Stephanie; Kittaka, Chieko; Al-Saadi, Jassim A.; Scheffe, Rich; Dimmick, Fred; Tikvart, Joe

    2008-01-01

    The Clean Air Interstate Rule (CAIR) is expected to reduce transport of air pollutants (e.g. fine sulfate particles) in nonattainment areas in the Eastern United States. CAIR highlights the need for an integrated air quality observational and modeling system to understand sulfate as it moves in multiple dimensions, both spatially and temporally. Here, we demonstrate how results from an air quality model can be combined with a 3d monitoring network to provide decision makers with a tool to help quantify the impact of CAIR reductions in SO2 emissions on regional transport contributions to sulfate concentrations at surface monitors in the Baltimore, MD area, and help improve decision making for strategic implementation plans (SIPs). We sample results from the Community Multiscale Air Quality (CMAQ) model using ensemble back trajectories computed with the NASA Langley Research Center trajectory model to provide Lagrangian time series and vertical profile information, that can be compared with NASA satellite (MODIS), EPA surface, and lidar measurements. Results are used to assess the regional transport contribution to surface SO4 measurements in the Baltimore MSA, and to characterize the dominant source regions for low, medium, and high SO4 episodes.

  12. Design, Modeling, Fabrication, and Evaluation of the Air Amplifier for Improved Detection of Biomolecules by Electrospray Ionization Mass Spectrometry

    PubMed Central

    Robichaud, Guillaume; Dixon, R. Brent; Potturi, Amarnatha S.; Cassidy, Dan; Edwards, Jack R.; Sohn, Alex; Dow, Thomas A.; Muddiman, David C.

    2010-01-01

    Through a multi-disciplinary approach, the air amplifier is being evolved as a highly engineered device to improve detection limits of biomolecules when using electrospray ionization. Several key aspects have driven the modifications to the device through experimentation and simulations. We have developed a computer simulation that accurately portrays actual conditions and the results from these simulations are corroborated by the experimental data. These computer simulations can be used to predict outcomes from future designs resulting in a design process that is efficient in terms of financial cost and time. We have fabricated a new device with annular gap control over a range of 50 to 70 μm using piezoelectric actuators. This has enabled us to obtain better aerodynamic performance when compared to the previous design (2× more vacuum) and also more reproducible results. This is allowing us to study a broader experimental space than the previous design which is critical in guiding future directions. This work also presents and explains the principles behind a fractional factorial design of experiments methodology for testing a large number of experimental parameters in an orderly and efficient manner to understand and optimize the critical parameters that lead to obtain improved detection limits while minimizing the number of experiments performed. Preliminary results showed that several folds of improvements could be obtained for certain condition of operations (up to 34 folds). PMID:21499524

  13. Mass loading of size-segregated atmospheric aerosols in the ambient air during fireworks episodes in eastern Central India.

    PubMed

    Nirmalkar, Jayant; Deb, Manas K; Deshmukh, Dhananjay K; Verma, Santosh K

    2013-04-01

    The effects of combustion of the fire crackers on the air quality in eastern Central India were studied for the first time during Diwali festival. This case study analyzes the size distribution and temporal variation of aerosols collected in the rural area of eastern Central India during pre-diwali, Diwali and post-diwali period for the year of 2011. Fifteen aerosol samples were collected during the special case study of Diwali period using Andersen sampler. The mean concentrations of PM10 (respirable particulate matter) were found to be 212.8 ± 4.2, 555.5 ± 20.2 and 284.4 ± 5.8 during pre-diwali, Diwali and post-diwali period, respectively. During Diwali festival PM10 concentration was about 2.6 and 1.9 times higher than pre-diwali and post-diwali period, respectively. PM2.5 (fine) and PM1 (submicron) concentrations during Diwali festival were more than 2 times higher than pre-diwali and post-diwali.

  14. Design, Modeling, Fabrication, and Evaluation of the Air Amplifier for Improved Detection of Biomolecules by Electrospray Ionization Mass Spectrometry.

    PubMed

    Robichaud, Guillaume; Dixon, R Brent; Potturi, Amarnatha S; Cassidy, Dan; Edwards, Jack R; Sohn, Alex; Dow, Thomas A; Muddiman, David C

    2011-03-01

    Through a multi-disciplinary approach, the air amplifier is being evolved as a highly engineered device to improve detection limits of biomolecules when using electrospray ionization. Several key aspects have driven the modifications to the device through experimentation and simulations. We have developed a computer simulation that accurately portrays actual conditions and the results from these simulations are corroborated by the experimental data. These computer simulations can be used to predict outcomes from future designs resulting in a design process that is efficient in terms of financial cost and time. We have fabricated a new device with annular gap control over a range of 50 to 70 μm using piezoelectric actuators. This has enabled us to obtain better aerodynamic performance when compared to the previous design (2× more vacuum) and also more reproducible results. This is allowing us to study a broader experimental space than the previous design which is critical in guiding future directions. This work also presents and explains the principles behind a fractional factorial design of experiments methodology for testing a large number of experimental parameters in an orderly and efficient manner to understand and optimize the critical parameters that lead to obtain improved detection limits while minimizing the number of experiments performed. Preliminary results showed that several folds of improvements could be obtained for certain condition of operations (up to 34 folds).

  15. Assessing Patterns in the Surface Electric Field Prior to First CG Flashes and After Last CG Flashes in Air-Mass Thunderstorms

    NASA Astrophysics Data System (ADS)

    Williams, D. E.; Beasley, W. H.; Hyland, P. T.

    2007-12-01

    In an effort to elicit patterns in the temporal and spatial evolution of the contours of surface electric field relevant to the occurrence of cloud-to-ground (CG) lightning, we have analyzed data from the network of 31 electric-field mills jointly operated by the John F. Kennedy Space Center (KSC) and Cape Canaveral Air Force Station (CCAFS). To identify cases of interest, we used lightning ground-strike data, maps of in-cloud lightning discharges, rainfall data, and radar data. In particular, we have focused on two critical problems: 1) estimation of when and where the first CG flash in a storm might occur and 2) assessment of the likelihood of CG flashes occurring late in a storm after a long period without a CG flash. Our long-term goal is to understand the evolution of surface contours of electric field for periods of 30 minutes or more before the first flash of any kind and 30 minutes or more before and after the last flash of any kind. For practical reasons, we are reporting here on analysis of data for periods of 30 minutes before the first CG flash and 30 minutes after the last CG flash in each storm of interest. We have analyzed electric-field data from isolated air-mass convective storms that developed over KSC/CCAFS from late May through early September, 2004-2006. To identify thunderstorms that fit the air-mass, or "pop-up" criteria, we started by examining rainfall and CG lightning data, then looked at radar data. Then, for the storms selected, we performed a two-pass Barnes objective analysis on the electric-field data. Each analysis cycle resulted in one contour plot of 20-second averaged data, yielding 90 plots for each 30 minute interval, which we then animated. This resulted in 58 animations of the field contours prior to first CG flashes and 62 animations of the field contours after last CG flashes. Preliminary impressions from examinations of these cases suggest that the electric-field contours before the first flash exhibit a smooth transition

  16. Analysis of air-mass modification over Poland and Romania by means of multiwavelength lidars - a case study 19-21/07/2014

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Stachlewska, Iwona S.; Nicolae, Doina; Nemuc, Anca; Janicka, Lucja; Markowicz, Krzysztof M.; Belegante, Livio; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2015-04-01

    A case study of air-mass modification over Poland and Romania, assessing the role of the Carpathian Mountains, during 19-21/07/2014 is analyzed. The study is based mainly on measurements taken by two multiwavelength Raman lidars at two different sites: the Radiative Transfer Laboratory (RT-Lab) at the Faculty of Physics of the University of Warsaw in Warsaw (Poland) and at the RADO site of the National Institute of R&D in Optoelectronics in Magurele (Romania). These data were complemented with meteorological data collected at two other sites: SolarAOT in Strzyżów (Poland) - equipped also with AERONET photometer and CHM15k ceilometer, and in Cluj (Romania). The RADO site, with its 7-wavelength aerosol-Raman-depolarization lidar (RALi) is integrated into EARLINET network. The RT-Lab site, with its 8-wavelength aerosol-Raman-depolarization (PollyXT-type) lidar, started the procedure to join in EARLINET last year. Moreover, RT-Lab and SolarAOT sites are part of the Poland AOD network. The analysis is focused on evaluating both multi-wavelength lidar data sets in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations. Accordingly to GDAS Hysplit 4-days backward trajectory ending up in Magurele at 0.5, 1.5 and 3 km an air-mass from western Europe entered Poland from the north-west on 19/07/2014, descended on the following day over the Poland AOD station in Strzyżów, followed by Cluj and end up at Magurele on 21/07/2014. As the four stations are located along a north-west to south-east line the objective was to evaluate the aerosol properties of the air flow transported over Poland and further to Romania. At both sites, backscatter profiles at 355, 532 and 1064nm, extinction profiles at 355 and 532nm, and depolarization profiles at 532nm and 355nm, show distinctly layered structure in the atmosphere. Along with these we used data from stations in Strzyżów and Cluj as well as information

  17. Impact of northern and southern air mass transport on the temporal distribution of atmospheric (210)Po and (210)Pb in the east coast of Johor, Malaysia.

    PubMed

    Sabuti, Asnor Azrin; Mohamed, Che Abd Rahim

    2016-09-01

    Concentration activities of (210)Pb and (210)Po in the PM10 were determined to discuss their distribution and chemical behavior in relation to meteorological parameters especially in air mass transport during monsoon events. Marine aerosol samples were collected between January 2009 and December 2010 at the coastal region of Mersing, which is located in the southern South China Sea and is about 160 km northeast of Johor Bahru, as part of the atmosphere-ocean interaction program in Malaysia. About 47 PM10 samples were collected using the Sierra-Andersen model 1200 PM10 sampler over a 2-year sampling campaign between January 2009 and December 2010. Samples were processed using acid digestion sequential extraction techniques to analyze various fractions such as Fe and Mn oxides, organic matter, and residual fractions. While, (210)Pb and (210)Po activities were measured with the Gross Alpha/Beta Counting System model XLB-5 Tennelec® Series 5 and the Alpha Spectrometry (model Alpha Analyst Spectroscopy system with a silicon-surface barrier detector), respectively. The distribution activities of (210)Pb and (210)Po in the PM10 samples were varied from 162 to 881 μBq/m(3) with mean value of 347 ± 170 μBq/m(3) and from 85 to 1009 μBq/m(3) with mean value of 318 ± 202 μBq/m(3), respectively. The analysis showed that (210)Po activity in our samples lies in a border and higher range than global distribution values due to contributions from external sources injected to the atmosphere. The speciation of (210)Pb and (210)Po in marine aerosol corresponds to transboundary haze; e.g., biomass burning especially forest fires and long-range air mass transport of terrestrial dust has enriched concentrations of particle mass in the local atmosphere. The monsoon seems to play an important role in transporting terrestrial dust from Indo-China and northern Asia especially during the northeast monsoon, as well as biogenic pollutants originating from Sumatra and the southern

  18. ARL Support and Analysis to the Army Public Health Command Kabul Air Quality Data Collection (Spring 2014)

    DTIC Science & Technology

    2016-05-01

    5 Fig. 4 HYSPLIT back trajectory 01 MAR 2014 ..................................7 Fig. 5...309 Fig. D-3 Aethalometer measured black carbon: 28 Feb 2014.................. 310 Fig. D-4 Kabul weather summary: 01 Mar 2014...312 Fig. D-5 HYSPLIT back trajectory 01 Mar 2014 ................................ 313 Fig. D-6 Aethalometer measured black carbon: 01 Mar

  19. Structure and Composition of Air-Plane Soots and Surrogates Analyzed by Raman Spectroscopy and Laser/Ions Desorption Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Ortega, Ismael; Chazallon, Bertrand; Carpentier, Yvain; Irimiea, Cornelia; Focsa, Cristian; Ouf, François-Xavier; Salm, François; Delhaye, David; Gaffié, Daniel; Yon, Jérôme

    2015-04-01

    Aviation alters the composition of the atmosphere globally and can thus drive climate change and ozone depletion [1]. An aircraft exhaust plume contains species emitted by the engines, species formed in the plume from the emitted species and atmospheric species that become entrained into the plume. The majority of emitted species (gases and soot particles) are produced by the combustion of kerosene with ambient air in the combustion chamber of the engine. Emissions of soot particles by air-planes produce persistent contrails in the upper troposphere in ice-supersaturated air masses that contribute to cloudiness and impact the radiative properties of the atmosphere. These aerosol-cloud interactions represent one of the largest sources of uncertainty in global climate models [2]. Though the formation of atmospheric ice particles has been studied since many years [3], there are still numerous opened questions on nucleation properties of soot particles [4], as the ice nucleation experiments showed a large spread in results depending on the nucleation mode chosen and origin of the soot produced. Most likely one of the reasons behind these discrepancies resides in the different physico-chemical properties (composition, structure) of soot particles produced in different conditions, e.g. with respect to fuel or combustion techniques. In this work, we use Raman microscopy (266, 514 and 785 nm excitation) and ablation techniques (SIMS, Secondary Ions Mass Spectrometry, and Laser Desorption Mass Spectrometry) to characterize soot particles produced from air-plane at different engine regimes simulating a landing and taking-off (LTO) cycle. First, the spectral parameters of the first-order Raman band of various soot samples, collected from three different sources in the frame of the MERMOSE project (http://mermose.onera.fr/): PowerJet SaM-146 turbofan (four engine regimes), CAST generator (propane fuel, four different global equivalence ratios), and Kerosene laboratory flame

  20. Concentrations of Semivolatile Organic Compounds Associated with African Dust Air Masses in Mali, Cape Verde, Trinidad and Tobago, and the U.S. Virgin Islands, 2001-2008

    USGS Publications Warehouse

    Garrison, Virginia H.; Foreman, William T.; Genualdi, Susan A.; Majewski, Michael S.; Mohammed, Azad; Simonich, Staci Massey

    2011-01-01

    Every year, billions of tons of fine particles are eroded from the surface of the Sahara Desert and the Sahel of West Africa, lifted into the atmosphere by convective storms, and transported thousands of kilometers downwind. Most of the dust is carried west to the Americas and the Caribbean in the Saharan Air Layer (SAL). Dust air masses predominately impact northern South America during the Northern Hemisphere winter and the Caribbean and Southeastern United States in summer. Dust concentrations vary considerably temporally and spatially. In a dust source region (Mali), concentrations range from background levels of 575 micrograms per cubic meter (mu/u g per m3) to 13,000 mu/u g per m3 when visibility degrades to a few meters (Gillies and others, 1996). In the Caribbean, concentrations of 200 to 600 mu/u g per m3 in the mid-Atlantic and Barbados (Prospero and others, 1981; Talbot and others, 1986), 3 to 20 mu/u g per m3 in the Caribbean (Prospero and Nees, 1986; Perry and others, 1997); and >100 mu/u g per m3 in the Virgin Islands (this dataset) have been reported during African dust conditions. Mean dust particle size decreases as the SAL traverses from West Africa to the Caribbean and Americas as a result of gravitational settling. Mean particle size reaching the Caribbean is <1 micrometer (mu/u m) (Perry and others, 1997), and even finer particles are carried into Central America, the Southeastern United States, and maritime Canada. Particles less than 2.5 mu/u m diameter (termed PM2.5) can be inhaled deeply into human lungs. A large body of literature has shown that increased PM2.5 concentrations are linked to increased cardiovascular/respiratory morbidity and mortality (for example, Dockery and others, 1993; Penn and others, 2005).

  1. Determination of a wide range of volatile organic compounds in ambient air using multisorbent adsorption/thermal desorption and gas chromatography/mass spectrometry

    USGS Publications Warehouse

    Pankow, J.F.; Luo, W.; Isabelle, L.M.; Bender, D.A.; Baker, R.J.

    1998-01-01

    Adsorption/thermal desorption with multisorbent air-sampling cartridges was developed for the determination of 87 method analytes including halogenated alkanes, halogenated alkenes, ethers, alcohols, nitriles, esters, ketones, aromatics, a disulfide, and a furan. The volatilities of the compounds ranged from that of dichlorofluoromethane (CFC12) to that of 1,2,3- trichlorobenzene. The eight most volatile compounds were determined using a 1.5-L air sample and a sample cartridge containing 50 mg of Carbotrap B and 280 mg of Carboxen 1000; the remaining 79 compounds were determined using a 5-L air sample and a cartridge containing 180 mg of Carbotrap B and 70 mg of Carboxen 1000. Analysis and detection were by gas chromatography/mass spectrometry. The minimum detectable level (MDL) concentration values ranged from 0.01 parts per billion by volume (ppbv) for chlorobenzene to 0.4 ppbv for bromomethane; most of the MDL values were in the range 0.02-0.06 ppbv. No breakthrough was detected with the prescribed sample volumes. Analyte stability on the cartridges was very good. Excellent recoveries were obtained with independent check standards. Travel spike recoveries ranged from 90 to 110% for 72 of the 87 compounds. The recoveries were less than 70% for bromomethane and chloroethene and for a few compounds such as methyl acetate that are subject to losses by hydrolysis; the lowest travel spike recovery was obtained for bromomethane (62%). Blank values for all compounds were either below detection or very low. Ambient atmospheric sampling was conducted in New Jersey from April to December, 1997. Three sites characterized by low, moderate, and high densities of urbanization/traffic were sampled. The median detected concentrations of the compounds were either similar at all three sites (as with the chlorofluorocarbon compounds) or increased with the density of urbanization/traffic (as with dichloromethane, MTBE, benzene, and toluene). For toluene, the median detected

  2. Volatile organic compounds in air at urban and industrial areas in the Tarragona region by thermal desorption and gas chromatography-mass spectrometry.

    PubMed

    Ras, Maria Rosa; Marcé, Rosa Maria; Borrull, Francesc

    2010-02-01

    Annual trends of a group of 66 volatile organic compounds (VOCs), containing 20 ozone precursors, were the aim of a sampling campaign carried out for a year in air at urban and industrial areas from Tarragona region. VOCs were determined by active collection on multisorbent tubes, followed by thermal desorption and gas chromatography-mass spectrometry. The analytical method was developed and validated, showing good levels of detection and quantification, recoveries, precision, and linearity for all the compounds in the range being studied. All the industrial and urban samples taken during the sampling campaign were similar in their qualitative composition. The most abundant compound in all urban and industrial sites was i-pentane, with concentrations between 15.2 and 202.1 microg m(-3) in urban sites and between 1.3 and 98.6 microg m(-3) in industrial sites. In urban sites, the following compounds in order of abundance were toluene, n-pentane, m,p-xylene, and o-xylene, with maximum levels of 150.6, 45.8, 42.3, and 31.7 microg m(-3), respectively. In industrial sites, the most abundant compounds depended on the sampled site.

  3. Interaction of the indoor air pollutant acetone with Degussa P25 TiO2 studied by chemical ionization mass spectrometry.

    PubMed

    Schmidt, Catherine M; Weitz, Eric; Geiger, Franz M

    2006-11-07

    Preventing a build-up of indoor pollutant concentrations has emerged as a major goal in environmental chemistry. Here, we have applied chemical ionization mass spectrometry to study the interaction of acetone, a common indoor air pollutant, with Degussa P25 TiO2, an inexpensive catalyst that is widely used for the degradation of volatile organic compounds into CO2 and water. To better understand the adsorption of acetone onto Degussa P25, the necessary first step for its degradation, the experiments were carried out at room temperature in the absence of UV light. This allowed for the deconvolution of the nonreactive and reactive thermal binding processes on Degussa P25 at acetone partial pressures (10(-7)-10(-4) Torr) commonly found in indoor environments. On average, 30% of the adsorbed acetone is bound irreversibly, resulting in a surface coverage of irreversibly bound acetone of approximately 1 x 10(12) molecules/cm2 at 3-4 x 10(-5) Torr. Equilibrium and dynamic experiments yield a sticking coefficient of approximately 1 x 10(-4) that is independent of the acetone partial pressures examined here. Equilibrium binding constants and free energies of adsorption are reported.

  4. Urban air quality assessment using monitoring data of fractionized aerosol samples, chemometrics and meteorological conditions.

    PubMed

    Yotova, Galina I; Tsitouridou, Roxani; Tsakovski, Stefan L; Simeonov, Vasil D

    2016-01-01

    The present article deals with assessment of urban air by using monitoring data for 10 different aerosol fractions (0.015-16 μm) collected at a typical urban site in City of Thessaloniki, Greece. The data set was subject to multivariate statistical analysis (cluster analysis and principal components analysis) and, additionally, to HYSPLIT back trajectory modeling in order to assess in a better way the impact of the weather conditions on the pollution sources identified. A specific element of the study is the effort to clarify the role of outliers in the data set. The reason for the appearance of outliers is strongly related to the atmospheric condition on the particular sampling days leading to enhanced concentration of pollutants (secondary emissions, sea sprays, road and soil dust, combustion processes) especially for ultra fine and coarse particles. It is also shown that three major sources affect the urban air quality of the location studied-sea sprays, mineral dust and anthropogenic influences (agricultural activity, combustion processes, and industrial sources). The level of impact is related to certain extent to the aerosol fraction size. The assessment of the meteorological conditions leads to defining of four downwind patterns affecting the air quality (Pelagic, Western and Central Europe, Eastern and Northeastern Europe and Africa and Southern Europe). Thus, the present study offers a complete urban air assessment taking into account the weather conditions, pollution sources and aerosol fractioning.

  5. Comparisons of cirrus cloud properties between polluted and pristine air based on in-situ observations from the NSF HIPPO, EU INCA and NASA ATTREX campaigns

    NASA Astrophysics Data System (ADS)

    Diao, M.; Schumann, U.; Jensen, J. B.; Minikin, A.

    2015-12-01

    The radiative forcing of cirrus clouds is influenced by microphysical (e.g., ice crystal number concentration and size distribution) and macroscopic properties. Currently it is still unclear how the formation of cirrus clouds and their microphysical properties are influenced by anthropogenic emissions. In this work, we use airborne in-situ observations to compare cirrus cloud properties between polluted and pristine regions. Our dataset includes: the NSF HIAPER Pole-to-Pole Observations (HIPPO) Global campaign (2009-2011), the EU Interhemispheric Differences In Cirrus Properties from Anthropogenic Emissions (INCA) campaign (2000) and the NASA Airborne Tropical Tropopause Experiment (ATTREX) campaign (2014). The combined dataset include observations of both extratropical (HIPPO and INCA) and tropical (ATTREX) cirrus, over the Northern and Southern Hemispheres. We use the in-situ measured carbon monoxide (CO) mixing ratio as a pollution indicator, and compare ice microphysical properties (i.e., ice crystal number concentration (Nc) and number-weighted mean diameter (Dc)) between air masses with higher and lower CO. All analyses are restricted to T ≤ -40°C. By analyzing ice crystals (Fast-2DC, 87.5-1600 µm) in HIPPO, we found that Dc decreases with increasing CO concentration at multiple constant pressure levels. In addition, analysis of INCA data shows that Nc and extinction of small ice particles (FSSP 3-20 µm) increases with increasing CO. Particles < 87.5 µm in Fast-2DC data are not considered due to uncertainty in sample volume, and the FSSP measurements are subject to possible shattering. We further analyze the ice crystals (SPEC FCDP, 1-50 µm) in the tropical tropopause layer in ATTREX. At -70°C to -90°C, we found that the average Nc (Dc) increases (decreases) at higher CO. Overall, our results suggest that extratropical and tropical cirrus are likely to have more numerous small ice particles, when sampled in the more polluted background. Back

  6. A hypothetical model of organic matter sea-to-air exchange processes based on stable carbon fractionation in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    Ceburnis, D.; Masalaite, A.; Garbaras, A.; Ovadnevaite, J.; Maenhaut, W.; Claeys, M.; Sciare, J.; O'Dowd, C. D. D.; Remeikis, V.

    2015-12-01

    Marine aerosol contributes significantly to the global aerosol loading and consequently has a significant impact on both the Earth's albedo and climate. Biological productivity in the global ocean is often resulting in significant amounts of primary organic matter in the aerosol phase. The North Atlantic Ocean is among the most productive oceanic regions and is the most studied ocean on Earth. The Southern Ocean, on the other hand, has been far less studied, even though similar organic matter enrichment patterns have been observed in marine aerosol. While numerous processes can contribute to organic matter in marine aerosols, carbon isotope analysis offers the most unambiguous estimates of the contributing sources. The stable carbon isotope ratios in marine aerosol samples collected during austral summer of 2007 at Amsterdam Island (Southern Indian Ocean) were examined. The measured δ13C values in the fine (Da <2.5µm) and coarse (Da >2.5µm) particle fractions were found to be evenly distributed between -28.2‰ and -20.0‰. These values are far lower than the previously reported ones as typical of unperturbed marine aerosol (-20‰). The δ13C values in the fine and coarse particle fractions were correlated with organic matter enrichment in sea spray. It was attempted to explain the variation of the δ13C values by the competition of the "fresh" and "old" organic matter pools in sea water during transfer into the aerosol phase, thereby implicating trophic level interactions. The hypothetical model suggests that fresh organic matter readily results in organic matter enrichment in sea spray particles and likely contains fresh colloidal and nanogel particulate matter, while the old organic matter is largely dissolved and unable to significantly enrich sea spray. Air mass back trajectory analysis suggests that the most productive regions, where sea spray particles are the most enriched in organic matter, are associated with low sea-water temperatures around the

  7. Analysis on seasonal retreat of Siberian high in association with that of the extremely cold Siberian air mass from winter to spring

    NASA Astrophysics Data System (ADS)

    Hamaki, Tatsuya; Haga, Yuichi; Kato, Kuranoshin

    2014-05-01

    According to Kato et al.(2009), the seasonal increase in surface air temperature in the Japan Islands area attains the maximum due to the rapid weakening of the winter time large-scale circulation pattern from late March to early April. Although the rapid decrease in the appearance frequency of the daily Siberian high at that time was pointed out by them, seasonal retreat process of the the Siberian high and the Siberian air mass including in the their day-to-day variations from winter to spring have not been systematically understood yet. Thus the present study will examine the above phenomena by using mainly the NCEP/NCAR reanalysis data and the daily weather maps at the surface level provided by JMA. Although the climatological analyses are need in the future, the present study will perform a case study for the several years, 1984(cold winter), 2007(warm winter) and 2011(normal winter). The area with high appearance frequency of the surface anticyclone with its center pressure more than 1032hPa (roughly corresponding to the Siberian high) was found around 40N~60N/90~120E (including Lake Baykal area (50~55N/105~110E)) in January and February. Interestingly, the latitude of that high appearance area was not so changed in March. Furthermore its frequency decreased rapidly with its maximum latitude unchanged in April. However, while the high frequency area was mainly located in the colder region with 850hPa temperature (T850) lower than -15 degrees Celsius in January and February wider part of the area with high appearance frequency of the intense anticyclone distributed in the baroclinic zone with T850 higher than -15 degrees Celsius. In April, the -15 degrees Celsius isotherm of T850 moved further northward to ~60N, although the maximum frequency of the anticyclone was seen along ~50N. In addition, although the anticyclone associated with the daily Siberian high showed rather quasi-stationary-like character also in March (as well as in midwinter), the storm track

  8. Emission rates of particle number, mass and black carbon by the Los Angeles International Airport (LAX) and its impact on air quality in Los Angeles

    NASA Astrophysics Data System (ADS)

    Shirmohammadi, Farimah; Sowlat, Mohammad H.; Hasheminassab, Sina; Saffari, Arian; Ban-Weiss, George; Sioutas, Constantinos

    2017-02-01

    This study describes a series of air monitoring measurements of particle number (PN), black carbon (BC) and PM2.5 mass concentrations in the vicinity of the Los Angeles International Airport (LAX) (roughly 150 m downwind of the LAX's south runways) as well as on-road measurements of the aforementioned pollutants using a mobile platform on three major freeways (i.e., I-110, I-105, and I-405) during May-July 2016. All measurements were performed in the "impact zone" of LAX with the predominant westerly winds from coast to inland. The overall impact of aircraft emissions from the LAX airport and its facilities in comparison to vehicular emissions from freeways on air quality was evaluated on a local scale (i.e. areas in the vicinity of the airport). PN concentration was, on average, 4.1 ± 1.2 times greater at the LAX site than on the studied freeways. Particle number emission factors for takeoffs and landings were comparable, with average values of 8.69 ×1015 particles/kg fuel and 8.16 ×1015 particles/kg fuel, respectively, and indicated a nearly 4-fold statistically significant reduction in PN emission factors for takeoffs during the past decade. BC emission factors were 0.12 ± 0.02 and 0.11 ± 0.01 g/kg fuel during takeoffs and landings, respectively. Additionally, the mean PM2.5 emission factor values for takeoffs and landings were also comparable, with values of 0.38 ± 0.04 and 0.40 ± 0.05 g/kg fuel, respectively. Within the impact zone of the airport, an area of roughly 100 km2 downwind of the LAX, measurements indicated that the LAX daily contributions to PN, BC, and PM2.5 were approximately 11, 2.5, and 1.4 times greater than those from the three surrounding freeways. These results underscore the significance of the LAX airport as a major source of pollution within its zone of impact comparing to freeway emissions.

  9. Interlaboratory evaluation of a standardized inductively coupled plasma mass spectrometry method for the determination of trace beryllium in air filter samples.

    PubMed

    Ashley, Kevin; Brisson, Michael J; Howe, Alan M; Bartley, David L

    2009-12-01

    A collaborative interlaboratory evaluation of a newly standardized inductively coupled plasma mass spectrometry (ICP-MS) method for determining trace beryllium in workplace air samples was carried out toward fulfillment of method validation requirements for ASTM International voluntary consensus standard test methods. The interlaboratory study (ILS) was performed in accordance with an applicable ASTM International standard practice, ASTM E691, which describes statistical procedures for investigating interlaboratory precision. Uncertainty was also estimated in accordance with ASTM D7440, which applies the International Organization for Standardization Guide to the Expression of Uncertainty in Measurement to air quality measurements. Performance evaluation materials (PEMs) used consisted of 37 mm diameter mixed cellulose ester filters that were spiked with beryllium at levels of 0.025 (low loading), 0.5 (medium loading), and 10 (high loading) microg Be/filter; these spiked filters were prepared by a contract laboratory. Participating laboratories were recruited from a pool of over 50 invitees; ultimately, 20 laboratories from Europe, North America, and Asia submitted ILS results. Triplicates of each PEM (blanks plus the three different loading levels) were conveyed to each volunteer laboratory, along with a copy of the draft standard test method that each participant was asked to follow; spiking levels were unknown to the participants. The laboratories were requested to prepare the PEMs by one of three sample preparation procedures (hotplate or microwave digestion or hotblock extraction) that were described in the draft standard. Participants were then asked to analyze aliquots of the prepared samples by ICP-MS and to report their data in units of mu g Be/filter sample. Interlaboratory precision estimates from participating laboratories, computed in accordance with ASTM E691, were 0.165, 0.108, and 0.151 (relative standard deviation) for the PEMs spiked at 0.025, 0

  10. Physical and Radiative Properties of Aerosol Particles across the Caribbean Basin: A Comparison between Clean and Perturbed African Dust and Volcanic Ash Air Masses

    NASA Astrophysics Data System (ADS)

    Rivera, H.; Ogren, J. A.; Sheridan, P. J.; Mayol-Bracero, O.

    2009-12-01

    Aerosol’s optical and physical properties were measured during year 2007 at Cape San Juan, a ground-based station located at the northeastern tip of Puerto Rico. The three cases investigated were classified according to the origin of the air masses: clean (C), African dust (AD), and volcanic ash (VA). The instrumentation used included a sunphotometer to determine volume size distributions and aerosol optical thickness (AOT), a 3-wavelength nephelometer to determine the scattering coefficient (σsp), and a 3-wavelength particle/soot absorption photometer (PSAP) to measure the absorption coefficient (σap). The average volume size distributions were trimodal for the C (peaks at 0.14, 0.99 and 4.25 µm radius) and AD (peaks at 0.11, 1.30 and 2.00 µm radius) cases and bimodal for the VA (peaks at 0.19 and 2.75 µm radius) case. Fine and coarse modes maxima for AD occurred at radii smaller than for VA, confirming the different origins of those particles. The average values for the total σsp were higher for AD (82.9 Mm-1) and VA (33.7 Mm-1) compared to C (16.6 Mm-1). The same happened for the AOT maximum values at 500 nm with 0.92, 0.30, and 0.06 for AD, VA, and C, respectively. The observed increase in the values of the Angstrom exponent (å) is indicative of a decrease in the size of the particles associated to VA (å= 0.27) and AD (å =0.89) when compared to C (å =0.24). The volume size distributions and thus the mass were dominated by the coarse mode (> 1.0 µm) especially for the AD case. Results have shown that AD as well as VA has a significant impact on the physical and radiative properties across Puerto Rico and the Caribbean. Additional results on the AOT wavelength dependence and on the annual variability of the properties under study will be presented.

  11. Sensitive monitoring of volatile chemical warfare agents in air by atmospheric pressure chemical ionization mass spectrometry with counter-flow introduction.

    PubMed

    Seto, Yasuo; Kanamori-Kataoka, Mieko; Tsuge, Koichiro; Ohsawa, Isaac; Iura, Kazumitsu; Itoi, Teruo; Sekiguchi, Hiroyuki; Matsushita, Koji; Yamashiro, Shigeharu; Sano, Yasuhiro; Sekiguchi, Hiroshi; Maruko, Hisashi; Takayama, Yasuo; Sekioka, Ryoji; Okumura, Akihiko; Takada, Yasuaki; Nagano, Hisashi; Waki, Izumi; Ezawa, Naoya; Tanimoto, Hiroyuki; Honjo, Shigeru; Fukano, Masumi; Okada, Hidehiro

    2013-03-05

    A new method for sensitively and selectively detecting chemical warfare agents (CWAs) in air was developed using counter-flow introduction atmospheric pressure chemical ionization mass spectrometry (MS). Four volatile and highly toxic CWAs were examined, including the nerve gases sarin and tabun, and the blister agents mustard gas (HD) and Lewisite 1 (L1). Soft ionization was performed using corona discharge to form reactant ions, and the ions were sent in the direction opposite to the airflow by an electric field to eliminate the interfering neutral molecules such as ozone and nitrogen oxide. This resulted in efficient ionization of the target CWAs, especially in the negative ionization mode. Quadrupole MS (QMS) and ion trap tandem MS (ITMS) instruments were developed and investigated, which were movable on the building floor. For sarin, tabun, and HD, the protonated molecular ions and their fragment ions were observed in the positive ion mode. For L1, the chloride adduct ions of L1 hydrolysis products were observed in negative ion mode. The limit of detection (LOD) values in real-time or for a 1 s measurement monitoring the characteristic ions were between 1 and 8 μg/m(3) in QMS instrument. Collision-induced fragmentation patterns for the CWAs were observed in an ITMS instrument, and optimized combinations of the parent and daughter ion pairs were selected to achieve real-time detection with LOD values of around 1 μg/m(3). This is a first demonstration of sensitive and specific real-time detection of both positively and negatively ionizable CWAs by MS instruments used for field monitoring.

  12. Online volatile organic compound measurements using a newly developed proton-transfer ion-trap mass spectrometry instrument during New England Air Quality Study--Intercontinental Transport and Chemical Transformation 2004: performance, intercomparison, and compound identification.

    PubMed

    Warneke, Carsten; Kato, Shuji; De Gouw, Joost A; Goldan, Paul D; Kuster, William C; Shao, Min; Lovejoy, Edward R; Fall, Ray; Fehsenfeld, Fred C

    2005-07-15

    We have used a newly developed proton-transfer ion-trap mass spectrometry (PIT-MS) instrument for online trace gas analysis of volatile organic compounds (VOCs) during the 2004 New England Air Quality Study-Intercontinental Transport and Chemical Transformation study. The PIT-MS instrument uses proton-transfer reactions with H3O+ ions to ionize VOCs, similarto a PTR-MS (proton-transfer reaction mass spectrometry) instrument but uses an ion trap mass spectrometer to analyze the product ions. The advantages of an ion trap are the improved identification of VOCs and a near 100% duty cycle. During the experiment, the PIT-MS instrument had a detection limit between 0.05 and 0.3 pbbv (S/N = 3 (signal-to-noise ratio)) for 2-min integration time for most tested VOCs. PIT-MS was used for ambient air measurements onboard a research ship and agreed well with a gas chromatography mass spectrometer). The comparison included oxygenated VOCs, aromatic compounds, and others such as isoprene, monoterpenes, acetonitrile, and dimethyl sulfide. Automated collision-induced dissociation measurements were used to determine the contributions of acetone and propanal to the measured signal at 59 amu; both species are detected at this mass and are thus indistinguishable in conventional PTR-MS.

  13. Episodic Impacts from California Wildfires Identified in Las Vegas Near-Road Air Quality Monitoring.

    PubMed

    Kimbrough, Sue; Hays, Michael; Preston, Bill; Vallero, Daniel A; Hagler, Gayle S W

    2016-01-05

    Air pollutant concentrations near major highways are usually attributed to a combination of nearby traffic emissions and regional background, and generally presumed to be additive in nature. During a near-road measurement study conducted in Las Vegas, NV, the effects of distant wildfires on regional air quality were indicated over a several day period in the summer of 2009. Area-wide elevated particulate levoglucosan (maximum of 0.83 μg/m(3)) and roadside measurements of ultraviolet light-absorbing particulate matter (UVPM) in comparison to black carbon (Delta-C) were apparent over the three-day period. Back-trajectory modeling and satellite images supported the measurement results and indicated the transport of air pollutants from wildfires burning in southern California. Separating roadside measurements under apparent biomass burning event (Delta-C > 1000 ng m(-3)) and nonevent (Delta-C < 1000 ng m(-3)) periods, and constraining to specific days of week, wind speed range, wind direction from the road and traffic volume range, roadside carbon monoxide, black carbon, total particle number count (20-200 nm), and accumulation mode particle number count (100-200 nm) increased by 65%, 146%, 58%, and 366%, respectively, when biomass smoke was indicated. Meanwhile, ultrafine particles (20-100 nm) decreased by 35%. This episode indicates that the presence of aged wildfire smoke may interact with freshly emitted ultrafine particles, resulting in a decrease of particles in the ultrafine mode.

  14. Submicron aerosol analysis and organic source apportionment in an urban atmosphere in Pearl River Delta of China using high-resolution aerosol mass spectrometry

    NASA Astrophysics Data System (ADS)

    He, Ling-Yan; Huang, Xiao-Feng; Xue, Lian; Hu, Min; Lin, Yun; Zheng, Jun; Zhang, Renyi; Zhang, Yuan-Hang

    2011-06-01

    The Pearl River Delta (PRD) region in South China is one of the most economically developed regions in China while also noted for its severe air pollution, especially in the urban environments. In order to understand in depth the aerosol chemistry and the emission sources in PRD, an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed at an urban site in the Hong Kong-Shenzhen metropolitan area between 25 October and 2 December 2009. Ten minute-resolved measurement data were analyzed, and an average mass concentration of 44.5 ± 34.0 μg m-3 was calculated for the entire campaign. On average, organic matter was the most abundant PM1 component accounting for 39.7% of the total mass, followed by sulfate (24.5%), black carbon (measured by aethalometer, 14.0%), ammonium (10.2%), nitrate (10.0%), and chloride (1.6%). Moreover, organic matter comprised an increasing fraction of the PM1 loading as the PM1 loading increased, denoting its key role in particulate pollution in this region. Calculations of organic elemental composition based on the high-resolution organic mass spectra obtained indicated that C, H, O, and N on average contributed 33.8%, 55.1%, 10.2%, and 0.9%, respectively, to the total atomic numbers of organic aerosol (OA), which corresponded to an OM/OC ratio (the ratio of organic matter mass/organic carbon mass) of 1.57 ± 0.08. Positive matrix factorization analysis was then conducted on the high-resolution organic mass spectral data set. Four OA components were identified, including a hydrocarbon-like (HOA), a biomass burning (BBOA), and two oxygenated (LV-OOA and SV-OOA) components, which on average accounted for 29.5%, 24.1%, 18.8%, and 27.6%, respectively, of the total organic mass. The HOA was found to have contributions from both fossil fuel combustion and cooking emissions, while the BBOA was well correlated with acetonitrile, a known biomass burning marker. The LV-OOA and SV-OOA corresponded to more aged and

  15. The effect of outdoor air and indoor human activity on mass concentrations of PM(10), PM(2.5), and PM(1) in a classroom.

    PubMed

    Branis, Martin; Rezácová, Pavla; Domasová, Markéta

    2005-10-01

    The 12-h mass concentration of PM(10), PM(2.5), and PM(1) was measured in a lecturing room by means of three co-located Harvard impactors. The filters were changed at 8 AM and at 8 PM to cover the periods of presence and absence of students. Concentrations were assessed by gravimetry. Ambient PM(10) data were available for corresponding 12-h intervals from the nearest state air-quality-monitoring network station. The data were pooled into four periods according to the presence and absence of students-Monday-Thursday day (workday daytime), Monday-Thursday night (workday night), Friday-Sunday day (weekend daytime), and Friday-Sunday night (weekend night). Average indoor workday daytime concentrations were 42.3, 21.9 and 13.7 microgm(-3), workday night were 20.9, 19.1 and 15.2 microgm(-3), weekend daytime were 21.9, 18.1 and 11.4 microgm(-3), and weekend night were 24.5, 21.3, and 15.6 microgm(-3) for PM(10), PM(2.5), and PM(1), respectively. The highest 12-h mean, median, and maximum (42.3, 43.0, and 76.2 microgm(-3), respectively) indoor concentrations were recorded on workdays during the daytime for PM(10). The statistically significant (r=0.68,P<0.0009) correlation between the number of students per hour per day and the indoor coarse fraction calculated as PM(10--2.5) during daytime on workdays indicates that the presence of people is an important source of coarse particles indoor. On workdays, the daytime PM(10) indoor/outdoor ratio was positively associated (r=0.93) with an increasing indoor coarse fraction (PM(10--2.5)), also indicating that an important portion of indoor PM(10) had its source inside the classroom. With the exception of the calculated coarse fraction (PM(10--2.5)), all of the measured indoor particulate matter fractions were significantly highly correlated with outdoor PM(10) and negatively correlated with wind velocity, showing that outdoor levels of particles influence their indoor concentrations.

  16. PM10-bound polycyclic aromatic hydrocarbons in Chiang Mai (Thailand): Seasonal variations, source identification, health risk assessment and their relationship to air-mass movement

    NASA Astrophysics Data System (ADS)

    Wiriya, Wan; Prapamontol, Tippawan; Chantara, Somporn

    2013-04-01

    found that vehicle emission and biomass burning were the main sources of PM10 and PAHs in this area. The high ratio value of benzo(a)anthracene/chrysene (BaA/CHR) in the dry season of 2010 indicated possible photochemical processes and long distance emissions. Findings on source identification of PM10 and PAHs were found to be relevant to the direction and speed of air mass movement run by backward trajectory.

  17. The environment of nature reserves under anthropogenic load: air transport of pollution to the North of European Russia

    NASA Astrophysics Data System (ADS)

    Vinogradova, A. A.; Ivanova, Yu. A.; Veremeychik, A. O.

    2012-04-01

    Nature reserves are created to keep in their original states natural environment, flora and fauna of various ecological systems, territories, climatic zones, etc. Now natural objects everywhere exist under anthropogenic loading from man-made activities. It is impossible to avoid atmospheric or river transport of pollution to the environment of reserved territories. The main idea of the work is to analyze atmospheric transport of anthropogenic metals (Ni, Cu, Pb, Fe, Al), as well as of soot (black carbon - BC) from Russian large industrial areas (source-regions) to the territories of nature reserves at the North of European Russia - the Kostomukshsky reserve (KR) in Karelia (64.57°N, 30.67°E) and the Nenetzky reserve (NR) at the Pechora River mouth (68,5°N, 53,5°E). The basic data for these 2 points were back trajectories of air mass transport calculated for every day of January, April, July, and October during 10 years from 2001 to 2010. We used NCEP/NCAR Reanalysis Data Files with HYSPLIT 4 model and two approaches for analyzing the trajectories. The main source-regions were chosen for each reserve. The annual source emissions for the last decade are generalized from the data published by Roshydromet of Russia (http://www.nii-atmosphere.ru/files/PUBL/Eg_2008.doc). The deposition velocity was a sum of dry and wet components. The equal values of deposition velocities onto the surface were assumed for all impurities because they are mainly on submicron aerosol particles under atmospheric transport for a long distance. The seasonal and spatial variations of averaged deposition velocity were accounted in accordance with surface properties and precipitation regimes. As a result, the maximal air concentrations of aerosol pollutants are observed in cold seasons, whereas the maximal fluxes onto the surface occur in warm period. Thus, it's possible that the cleanest air does not indicate the same surface. Fe and Al are the crust (dust or soil) elements. Thus, their main

  18. Elbow mass flow meter

    DOEpatents

    McFarland, Andrew R.; Rodgers, John C.; Ortiz, Carlos A.; Nelson, David C.

    1994-01-01

    Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

  19. Hygroscopic growth of particles nebulized from water-soluble extracts of PM2.5 aerosols over the Bay of Bengal: Influence of heterogeneity in air masses and formation pathways.

    PubMed

    Boreddy, S K R; Kawamura, Kimitaka; Bikkina, Srinivas; Sarin, M M

    2016-02-15

    Hygroscopic properties of water-soluble matter (WSM) extracted from fine-mode aerosols (PM2.5) in the marine atmospheric boundary layer of the Bay of Bengal (BoB) have been investigated during a cruise from 27th December 2008 to 30th January 2009. Hygroscopic growth factors were measured on particles generated from the WSM using an H-TDMA system with an initial dry size of 100 nm in the range of 5-95% relative humidity (RH). The measured hygroscopic growth of WSM at 90% RH, g(90%)WSM, were ranged from 1.11 to 1.74 (mean: 1.43 ± 0.19) over the northern BoB and 1.12 to 1.38 (mean: 1.25 ± 0.09) over the southern BoB. A key finding is that distinct hygroscopic growth factors are associated with the air masses from the Indo-Gangetic plains (IGP), which are clearly distinguishable from those associated with air masses from Southeast Asia (SEA). We found higher (lower) g(90%)WSM over the northern (southern) BoB, which were associated with an IGP (SEA) air masses, probably due the formation of high hygroscopic salts such as (NH4)2SO4. On the other hand, biomass burning influenced SEA air masses confer the low hygroscopic salts such as K2SO4, MgSO4, and organic salts over the southern BoB. Interestingly, mass fractions of water-soluble organic matter (WSOM) showed negative and positive correlations with g(90%)WSM over the northern and southern BoB, respectively, suggesting that the mixing state of organic and inorganic fractions could play a major role on the g(90%)WSM over the BoB. Further, WSOM/SO4(2-) mass ratios suggest that SO4(2-) dominates the g(90%)WSM over the northern BoB whereas WSOM fractions were important over the southern BoB. The present study also suggests that aging process could significantly alter the hygroscopic growth of aerosol particles over the BoB, especially over the southern BoB.

  20. Air Research

    EPA Pesticide Factsheets

    EPA's air research provides the critical science to develop and implement outdoor air regulations under the Clean Air Act and puts new tools and information in the hands of air quality managers and regulators to protect the air we breathe.

  1. Separating the air quality impact of a major highway and nearby sources by nonparametric trajectory analysis.

    PubMed

    Henry, Ronald C; Vette, Alan; Norris, Gary; Vedantham, Ram; Kimbrough, Sue; Shores, Richard C

    2011-12-15

    Nonparametric Trajectory Analysis (NTA), a receptor-oriented model, was used to assess the impact of local sources of air pollution at monitoring sites located adjacent to highway I-15 in Las Vegas, NV. Measurements of black carbon, carbon monoxide, nitrogen oxides, and sulfur dioxide concentrations were collected from December 2008 to December 2009. The purpose of the study was to determine the impact of the highway at three downwind monitoring stations using an upwind station to measure background concentrations. NTA was used to precisely determine the contribution of the highway to the average concentrations measured at the monitoring stations accounting for the spatially heterogeneous contributions of other local urban sources. NTA uses short time average concentrations, 5 min in this case, and constructed local back-trajectories from similarly short time average wind speed and direction to locate and quantify contributions from local source regions. Averaged over an entire year, the decrease of concentrations with distance from the highway was found to be consistent with previous studies. For this study, the NTA model is shown to be a reliable approach to quantify the impact of the highway on local air quality in an urban area with other local sources.

  2. Development and validation of a method for air-quality and nuisance odors monitoring of volatile organic compounds using multi-sorbent adsorption and gas chromatography/mass spectrometry thermal desorption system.

    PubMed

    Ribes, Alejandra; Carrera, Guillem; Gallego, Eva; Roca, Xavier; Berenguer, M A José; Guardino, Xavier

    2007-01-26

    An analytical method based on thermal desorption (TD) coupled to gas chromatography (GC) and mass spectrometry detection (MS) has been developed and validated for the determination of a wide range of odor nuisance and air-quality volatile organic compounds (VOC) in air. New generation isocyanates, isocyanato- and isothiocyanatocyclohexane, have been included for the first time as target compounds due to their high occurrence in air samples. A dynamic air sampling method to trap gas and vapor on multi-sorbent tubes using portable pump equipment has been also developed. Sorbent tubes were filled with Carbotrap (70mg), Carbopack X (100mg) and Carboxen-569 (90mg). Validation of the TD-GC-MS method showed good selectivity, sensibility and precision according to Compendium Method TO-17 (US Environment Protection Agency) criteria. Limits of detection (signal-to-noise=3, ng in tube) ranges were 0.004-0.03ng (alcanes), 0.001-0.1ng (aromatics), 0.03-14ng (aldehydes), 0.003-7ng (alcohols), 0.003-0.04ng (chlorides), 0.02-0.5ng (esters), 0.002-0.1ng (ketones), 0.01-0.53ng (terpenes), 14-97ng (amides), 0.2-10ng (isocyanates) and 0.001ng (carbon disulfide). The linear dynamic range was over 3-5 orders of magnitude, depending of the VOC. TD-GC-MS analysis was reproducible, with relative standard deviation (n=5) within 20%. VOCs breakthrough examination showed no significant losses when about 2000ng standard was prepared. In order to evaluate the performance of the developed method on real samples, several industrial and urban air samples were analysed. VOCs were found to be stable on the sorbent tubes for at least 1 week when stored at 4 degrees C.

  3. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, ... Ozone, a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  4. Investigating the Impact of Marine Ship Emissions on Regional Air Quality using OMI Satellite NO2 Observations and the CMAQ Model

    NASA Astrophysics Data System (ADS)

    Ring, A.; Canty, T. P.; He, H.; Vinciguerra, T.; Lamsal, L. N.; Dickerson, R. R.; Salawitch, R. J.; Cohen, M.; Montgomery, L. N.; Dreessen, J.

    2015-12-01

    Commercial marine vessels (CMVs) emit significant amounts of NOx, an ozone precursor, which may contribute to negative health consequences for people living in areas near shipping lanes. In coastal US states, many metropolitan areas such as Baltimore and New York City are located near ports with CMVs. Many studies estimate that ships account for ~15-30% of the global anthropogenic NOx emissions. EPA developed emissions inventories are widely used by states to construct model scenarios for testing air quality attainment strategies. Currently, CMV emissions are generated by simply applying growth factors to aggregated emissions data from much earlier years. Satellite retrievals from the Ozone Monitoring Instrument (OMI) have been successfully used to improve the veracity of marine emissions by incorporating observational data from the inventory year. In this study we use OMI NO2 observations and Community Multiscale Air Quality (CMAQ) model outputs to improve the EPA marine emission estimates for the Mid-Atlantic region. Back trajectories from the NOAA Air Resources Laboratory HYSPLIT model are used to identify days with minimal continental influence on OMI tropospheric column NO2 over shipping lanes. We perform sensitivity analyses to quantify the impact of marine emissions on air quality and suggest strategies to better meet the EPA mandated ozone standard.

  5. Analysis of long-range transport of particulate matters in connection with air circulation over Central and Eastern part of Europe

    NASA Astrophysics Data System (ADS)

    Stefan, Sabina; Necula, Cristian; Georgescu, Florinela

    The aim of this paper is to establish a practical methodology for examining the long-range transport of particulate matters (PM), named TSP. The daily concentration values of TSP from years 2001 and 2002, for three sites, Baia Mare (RO), Vienna (AU), Aosta (IT), were analyzed. In order to connect the main air circulation types with the aerosol concentrations at the selected sites, the catalogues of Circulation and Weather type Classification (COST733) were used. Spectral analysis was made using spectrum software based on Lomb-Scargle periodograms, and multiresolution analysis (MRA) technique based on Maximal Overlap Discrete Wavelet Transform (MODWT) with Fejer-Korovkin in 22 points wavelet filter (waveslim package). Spectral analysis shows a dominant one-year periodicity for all the time series with a variance around 22% for each time series. In addition, several winters TSP pollution episodes from each city were analyzed using a back trajectory model (HYSPLIT4), in order to compare with the resulted air circulation types. Two important concluding remarks emerge: (i) the Eastern part of Europe shows a dominant easterly air circulation and central Europe is characterized by south-west air circulations, which drive the maxima of pollutant concentrations; (ii) the choice of the domain for analysis of the circulation types is very important.

  6. Integrated sampling and analysis unit for the determination of sexual pheromones in environmental air using fabric phase sorptive extraction and headspace-gas chromatography-mass spectrometry.

    PubMed

    Alcudia-León, M Carmen; Lucena, Rafael; Cárdenas, Soledad; Valcárcel, Miguel; Kabir, Abuzar; Furton, Kenneth G

    2017-03-10

    This article presents a novel unit that integrates for the first time air sampling and preconcentration based on the use of fabric phase sorptive extraction principles. The determination of Tuta absoluta sexual pheromone traces in environmental air has been selected as analytical problem. For this aim, a novel laboratory-built unit made up of commercial brass elements as holder of the sol-gel coated fabric extracting phase has been designed and optimized. The performance of the integrated unit was evaluated analyzing environmental air sampled in tomato crops. The unit can work under sampling and analysis mode which eliminates any need for sorptive phase manipulation prior to instrumental analysis. In the sampling mode, the unit can be connected to a sampling pump to pass the air through the sorptive phase at a controlled flow-rate. In the analysis mode, it is placed in the gas chromatograph autosampler without any instrumental modification. It also diminishes the risk of cross contamination between sampling and analysis. The performance of the new unit has been evaluated using the main components of the sexual pheromone of Tuta absoluta [(3E,8Z,11Z)-tetradecatrien-1-yl acetate and (3E,8Z)-tetradecadien-1-yl acetate] as model analytes. The limits of detection for both compounds resulted to be 1.6μg and 0.8μg, respectively, while the precision (expressed as relative standard deviation) was better than 3.7%. Finally, the unit has been deployed in the field to analyze a number of real life samples, some of them were found positive.

  7. Analysis of enantiomeric and non-enantiomeric monoterpenes in plant emissions using portable dynamic air sampling/solid-phase microextraction (PDAS-SPME) and chiral gas chromatography/mass spectrometry

    NASA Astrophysics Data System (ADS)

    Yassaa, Noureddine; Williams, Jonathan

    A portable dynamic air sampler (PDAS) using a porous polymer solid-phase microextraction (SPME) fibre has been validated for the determination of biogenic enantiomeric and non-enantiomeric monoterpenes in air. These compounds were adsorbed in the field, and then thermally desorbed at 250 °C in a gas chromatograph injector port connected via a β-cyclodextrin capillary separating column to a mass spectrometer. The optimized method has been applied for investigating the emissions of enantiomeric monoterpenes from Pseudotsuga menziesii (Douglas-fir), Rosmarinus officinalis (Rosemary) and Lavandula lanata (Lavender) which were selected as representative of coniferous trees and aromatic plants, respectively. The enantiomers of α-pinene, sabinene, camphene, δ-3-carene, β-pinene, limonene, β-phellandrene, 4-carene and camphor were successfully determined in the emissions from the three plants. While Douglas-fir showed a strong predominance toward (-)-enantiomers, Rosemary and Lavender demonstrated a large variation in enantiomeric distribution of monoterpenes. The simplicity, rapidity and sensitivity of dynamic sampling with porous polymer coated SPME fibres coupled to chiral capillary gas chromatography/mass spectrometry (GC/MS) makes this method potentially useful for in-field investigations of atmosphere-biosphere interactions and studies of optically explicit atmospheric chemistry.

  8. Evaluating the Impacts of Transboundary Air pollution from China on Air Quality in the U.S. Using a Regression Framework

    NASA Astrophysics Data System (ADS)

    Ngo, N. S.; Bao, X.; Zhong, N.

    2014-12-01

    China is the largest emitter of anthropogenic air pollution in the world and previous work has shown the environmental impacts of the long-range transport (LRT) of air pollution from China to the U.S. via chemical transport models, in situ observations, isentropic back trajectories, and to a lesser extent statistical models. However, these studies generally focus on a narrow time period due to data constraints. In this study, we build upon the literature using econometric techniques to isolate the impacts on U.S. air quality from the LRT of air pollution from China. We use a unique daily data set of China's air pollution index (API) and PM10 concentrations at the city level and merge these information with daily monitor data in California (CA) between 2000 and 2013. We first employ a distributed lag model to examine daily patterns, and then exploit a "natural experiment." In the latter methodology, since air pollution is rarely randomly assigned, we examine the impacts of specific events that affect air quality in China, but are plausibly uncorrelated to factors affecting air pollution in CA. For example, Chinese New Year (CNY) is a major week-long holiday and we show pollution levels in China decrease during this time period, likely from reductions in industrial production. CNY varies each calendar year since it is based off the lunar new year, so the timing of this pollution reduction could be considered "as good as random" or exogenous to factors affecting air quality in CA. Using a regression framework including weather, seasonal and geographic controls, we can potentially isolate the impact of the LRT of air pollution to CA. First, results from the distributed lag model suggest that in the Spring, when LRT peaks, a 1 μg/m3 increase in daily PM10 from China between 10 and 14 days ago is associated with an increase in today's PM2.5 in CA of 0.022 μg/m3 (mean daily PM2.5 in CA is 12 μg/m3). Second, we find that if CNY occurred 5 to 9 days ago, today's PM2.5 in

  9. [Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolutimi gas chromatography-electron capture negative ion-low resolution mass spectrometry].

    PubMed

    Shi, Loimeng; Gao, Yuan; Hou, Xiaohong; Zhang, Haijun; Zhang, Yichi; Chen, Jiping

    2016-02-01

    An analytical method for quantifying short-chain chlorinated paraffins (SCCPs) in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry ( HRGC-ECNI-LRMS) was developed. An acidified silica gel column and a basic alumina column were used to optimize the cleanup procedures. The results showed a good linearity (R2>0. 99) between the total response factors and the degree of chlorination of SCCPs in the content range of 58. 1%-63. 3%. The limits of detection (S/N ≥3) and the limits of quantification (S/N ≥ 10) were 4. 2 and 12 µg, respectively. The method detection limit (MDL) for SCCPs was 0. 34 ng/m3 (n = 7). The recoveries of SCCPs in air samples were in the range of 81. 9% to 94. 2%. It is demonstrated that the method is suitable for the quantitative analysis of SCCPs in air samples.

  10. The impact of the Montreal Protocol on halocarbon concentrations in northern hemisphere baseline and European air masses at Mace Head, Ireland over a ten year period from 1987-1996

    NASA Astrophysics Data System (ADS)

    Derwent, R. G.; Simmonds, P. G.; O'Doherty, S.; Ryall, D. B.

    The international concern following the discovery of Antarctic stratospheric ozone depletion has prompted unprecedented international action by governments to control the production, sales and usage of a range of ozone-depleting chemicals. These international treaty obligations include the Montreal Protocol and its London and Copenhagen Amendments. They address, amongst many halocarbon species, the chlorofluorocarbons: CFC-11, -12 and -113 and the chlorocarbons: carbon tetrachloride and methyl chloroform. These chemicals have been routinely monitored at the remote, baseline monitoring station at Mace Head on the Atlantic Ocean coast of Ireland as part of the GAGE/AGAGE programme. The available monitoring data for the period 1987-1996 are presented here with a view to confirming the extent of compliance with the above Protocols on a global and European basis. Daily wind direction sectors provided by EMEP are used to sort the halocarbon data into northern hemisphere baseline air and European polluted air masses and trends have been determined for each wind direction sector. Evidence of the European phase-out of halocarbon usage is clearly apparent in the sorted halocarbon concentrations. A simple climatological long-range transport and a sophisticated Lagrangian air parcel dispersion model have been used to interpret the Mace Head halocarbon measurements and to derive estimates of European emission source strengths for each year. These emission source strengths confirm that the phase-out of halocarbon manufacture and sales is being followed in Europe.

  11. An unusual stratospheric ozone decrease linked to isentropic air-mass transport as observed over Irene (25.5° S, 28.1° E) in mid-May 2002

    NASA Astrophysics Data System (ADS)

    Semane, N.; Bencherif, H.; Morel, B.; Hauchecorne, A.; Diab, R. D.

    2005-12-01

    A prominent ozone minimum of less than 240 Dobson Units (DU) was observed over Irene (25.5° S, 28.1° E) by the Total Ozone Mapping Spectrometer (TOMS) during May 2002 with extremely low ozone value of less than 219 DU recorded on 12 May, as compared to a climatological mean of 249 DU for May between 1999 and 2005. In this study, the vertical structure of this ozone minimum is examined using ozonesonde measurements performed over Irene on 15 May 2002, when the total ozone (as given by TOMS) was about 226 DU. Indeed, it is found that the ozone minimum is of Antarctic polar origin with a low-ozone layer in the middle stratosphere above 625 K and of tropical origin with low-ozone layer between 400-K and 450-K isentropic levels in the lower stratosphere. The upper and lower depleted parts of the ozonesonde profile for 15 May, are respectively attributed to equatorward and poleward transport of low-ozone air toward the subtropics. The tropical air moving over Irene and the polar one passing over the same area associated with enhanced planetary-wave activity are simulated successfully using a high-resolution advection contour model (MIMOSA) of Potential Vorticity. Indeed, in mid-May 2002, MIMOSA maps show a polar vortex filament in the middle stratosphere above the 625-K isentropic level and they show also tropical air-masses moving southward (over Irene) in the lower stratosphere between 400-K and 450-K isentropic levels. The winter stratospheric wave driving and its associated localized isentropic mixing leading to the ozone minimum are investigated by means of two diagnostic tools: the Eliassen-Palm flux and the effective diffusivity computed from the European Center for Medium-range Weather Forecasts (ECMWF) fields. The unusual distribution of ozone over Irene during May 2002 in the middle stratosphere is closely connected to the anomalously pre-conditioned structure of the polar vortex at that time of the year. Indeed, the perturbed vortex was typically predisposed

  12. Rapid, Automated Determination of Elemental Compositions of Ions in Mass Spectra Obtained with an Open-Air Ion Source (2 of 2)

    EPA Science Inventory

    An inexpensive autosampler for a DART/TOFMS provides mass spectra from analytes absorbed on 76 cotton swab, wipe samples in 7.5 min. A field sample carrier simplifies sample collection and provides swabs nearly ready for analysis to the lab. Applications of the high throughput pr...

  13. Elbow mass flow meter

    DOEpatents

    McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

    1994-08-16

    The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

  14. Global pilot study for persistent organic pollutants (POPs) using PUF disk passive air samplers.

    PubMed

    Harner, Tom; Pozo, Karla; Gouin, Todd; Macdonald, Anne-Marie; Hung, Hayley; Cainey, Jill; Peters, Andrew

    2006-11-01

    Polyurethane foam (PUF) disks were deployed at global background sites, to test logistical issues associated with a global monitoring network for persistent organic pollutants (POPs). alpha-HCH, exhibited relatively high and uniform concentrations (17-150 pg/m3) at temperate and arctic sites with elevated concentrations associated with trans-Pacific inflow. Concentrations were much lower (<5 pg/m3) in Bermuda, Chile and Cape Grim. Concentrations for gamma-HCH, the main component of lindane, were spatially similar to the alpha-HCH pattern but lower in magnitude (typically, <10 pg/m3). Chlordane concentrations (sum of cis-chlordane, trans-chlordane and trans-nonachlor) were also low (<10 pg/m3). Dieldrin concentrations were in the range 2-25 pg/m3 at most sites but elevated in Bermuda. Back trajectories suggest that advection from Africa and the US may contribute. Endosulfan, a popular current-use pesticide, exhibited highest concentrations ranging from tens to hundreds of pg/m3. There was good agreement between duplicate samplers at each site and PUF disk-derived air concentrations agreed with high volume data. Few logistical/analytical problems were encountered in this pilot study.

  15. Changes in mass and energy transfer between the canopy and the atmosphere: model development and testing with a free-air CO2 enrichment (FACE) experiment

    NASA Astrophysics Data System (ADS)

    Manunta, Paolo; Grant, Robert F.; Feng, Yongshen; Kimball, Bruce A.; Pinter, Paul J.; La Morte, Robert L.; Hunsaker, Douglas J.; Wall, D.

    2002-02-01

    The rationale for this study is found in the probable higher temperatures and changes in rainfall patterns that are expected in the future as a result of increasing levels of CO2 in the atmosphere. In particular, higher air temperatures may cause an increase in evapotranspiration demand while a reduction in rainfall could increase the severity and duration of drought in arid and semi-arid regions. Representation of the water transfer scheme includes water uptake by roots and the interaction between evapotranspiration and CO2 enrichment. The predicted response of a spring wheat ( Triticum aestivum L. cv. Yecora rojo) canopy in terms of energy exchange processes to elevated atmospheric CO2 level was tested against measurements collected at the FACE (Free Air Enrichment Experiment) site in 1994. Simulated and measured canopy conductances were reduced by about 30% under elevated [CO2] under optimum conditions of water supply. Reductions in latent heat fluxes under elevated instead of ambient [CO2] caused reductions in both simulated and measured seasonal water use of 6% under optimum and 2% under suboptimum irrigation. The soil-plant-atmosphere water transfer scheme proposed here offers several advances in the simulation of land surface interactions. First, the stomatal resistance model minimizes assumptions in existing land surface schemes about the effects of interactions among environmental conditions (radiation, temperature, CO2) upon stomatal behavior. These interactions are resolved in the calculation of CO2 in which processes are already well understood.

  16. X{sub max}{sup μ} vs. N{sup μ} from extensive air showers as estimator for the mass of primary UHECR's. Application for the Pierre Auger Observatory

    SciTech Connect

    Arsene, Nicusor; Sima, Octavian

    2015-02-24

    We study the possibility of primary mass estimation for Ultra High Energy Cosmic Rays (UHECR's) using the X{sub max}{sup μ} (the height where the number of muons produced on the core of Extensive Air Showers (EAS) is maximum) and the number N{sup μ} of muons detected on ground. We use the 2D distribution - X{sub max}{sup μ} against N{sup μ} in order to find its sensitivity to the mass of the primary particle. For that, we construct a 2D Probability Function Prob(p,Fe | X{sub max}{sup μ}, N{sup μ}) which estimates the probability that a certain point from the plane (X{sub max}{sup μ}, N{sup μ}) corresponds to a shower induced by a proton, respectively an iron nucleus. To test the procedure, we analyze a set of simulated EAS induced by protons and iron nuclei at energies of 10{sup 19}eV and 20° zenith angle with CORSIKA. Using the Bayesian approach and taking into account the geometry of the infill detectors from the Pierre Auger Observatory, we observe an improvement in the accuracy of the primary mass reconstruction in comparison with the results obtained using only the X{sub max}{sup μ} distributions.

  17. Combined target and post-run target strategy for a comprehensive analysis of pesticides in ambient air using liquid chromatography-Orbitrap high resolution mass spectrometry.

    PubMed

    Coscollà, Clara; León, Nuria; Pastor, Agustín; Yusà, Vicent

    2014-11-14

    A comprehensive strategy for the analysis of current airborne pesticides has been developed using liquid chromatography coupled to high resolution mass spectrometry. The methodology includes both quantitative target analysis and post-run target screening analysis. The quantitative method was validated after a previous statistical optimisation of the main factors governing the ion source ionization and a study of the single-stage Orbitrap fragmentation through the HCD cell. The quantitative method presented recoveries ranging from 73 to 116%, with precision (RSD) lower than 20%, for the 35 substances in the scope of the target method. The full-scan accurate mass data were acquired with a resolving power of 50000 FWHM (scan speed, 2 Hz), and alternating two acquisition events, ESI+ without fragmentation and ESI+ with fragmentation. The method-LOQ was 6.5 pg m(-3) for most of the target pesticides. For post-target screening a customized theoretical database, that included pesticides, metabolites and other substances such as emerging flame retardants was built up. For identification, accurate exact mass with less than 5 ppm, and some diagnostic ions including isotopes and/or fragments were used. The strategy was applied to ten samples collected in a rural area of Valencia (Spain). Four pesticides, namely carbendazim, metalaxyl, myclobutanil and terbuthylazine, were detected in concentrations from 16 pg m(-3) to 174 pg m(-3). Some pesticides and metabolites (endothal, fenfuram, terbuthylazine-2-OH), in addition to two flame retardants were tentatively identified in the post-run target screening analysis.

  18. Modelling of heat and mass transfer in a granular medium during high-temperature air drying. Effect of the internal gas pressure

    NASA Astrophysics Data System (ADS)

    Othmani, Hammouda; Hassini, Lamine; Lamloumi, Raja; El Cafsi, Mohamed Afif

    2016-02-01

    A comprehensive internal heat and water transfer model including the gas pressure effect has been proposed in order to improve the industrial high-temperature air drying of inserts made of agglomerated sand. In this model, the internal gas phase pressure effect was made perfectly explicit, by considering the liquid and vapour transfer by filtration and the liquid expulsion at the surface. Wet sand enclosed in a tight cylindrical glass bottle dried convectively at a high temperature was chosen as an application case. The model was validated on the basis of the experimental average water content and core temperature curves for drying trials at different operating conditions. The simulations of the spatio-temporal distribution of internal gas pressure were performed and interpreted in terms of product potential damage. Based on a compromise between the drying time and the pressure increase, a simple drying cycle was implemented in order to optimize the drying process.

  19. Mass-dependent and mass-independent fractionation of mercury isotopes in precipitation from Guiyang, SW China

    NASA Astrophysics Data System (ADS)

    Wang, Zhuhong; Chen, Jiubin; Feng, Xinbin; Hintelmann, Holger; Yuan, Shengliu; Cai, Hongming; Huang, Qiang; Wang, Shuxiao; Wang, Fengyang

    2015-11-01

    The isotopic composition of mercury (Hg) is increasingly used to constrain the sources and pathways of this metal in the atmosphere. Though China has the highest Hg production, consumption and emission in the world, Hg isotope ratios are rarely reported for Chinese wet deposition. In this study, we examined, for the first time outside North America, both mass-dependent fractionation (MDF, expressed as δ202Hg) and mass-independent fractionation of odd (odd-MIF, Δ199Hg) and even (even-MIF, Δ200Hg) Hg isotopes in 15 precipitation samples collected from September 2012 to August 2013 in Guiyang (SW China). All samples displayed significant negative δ202Hg (-0.44 ∼ -4.27‰), positive Δ199Hg (+0.19 to +1.16‰) and slightly positive Δ200Hg (-0.01‰ to +0.20‰). Potential sources of Hg in precipitation were identified by coupling both MDF and MIF of Hg isotopes with a back-trajectory model. The results showed that local emission from coal-fired power plants and cement plants and western long-range transportation are two main contributing sources, while the contribution of Hg from south wind events would be very limited on an annual basis. The relatively lower Δ200Hg values in Guiyang precipitation may indicate a dilution effect by local sources and/or insignificant even-MIF in the tropopause contribution of this subtropical region. Our study demonstrates the usefulness of isotope fractionation, especially MIF for tracing sources and pathways of Hg in the atmosphere.

  20. Characterization of the NOx-Ox relationship in a mountain gap rural area of interchange of air masses southeast of the Metropolitan Area of Mexico City

    NASA Astrophysics Data System (ADS)

    Ruiz Suarez, L.; Garcia-Yee, J.; Torres-JArdon, R.; Barrera Huertas, H.; Torres-Jaramillo, A.; Ortinez, A.

    2013-05-01

    Varying levels of oxidants (Ox = O3 + NO2) with respect to NOx were registered at three sites in a mountain southeast of the Mexico City Metropolitan Area (MCMA) in February and March 2011. The Ox-NOx ratio was used to gain a better understanding of the photochemical and transport processes happening over this mountain pass. Relatively high concentrations of O3 (moving average concentrations of 8 hours) exceeded maximum levels of the World Health Organization, and the European Union. The cumulative exceedances above background level of O3 in the one month-long campaign also exceeded the three months accumulative UN-ECE AOT40 critical level for crop protection. It was observed that the level of Ox in the mountain gap sites consisted of two contributions: One, independent of NOx emissions, extremely dominant and considered equivalent to the regional background O3 concentration; the second and much smaller was dependent of NOx local concentrations. Evidence was found that the oxidation of NO provided the major contribution of NO2 to Ox, rather than direct NO2 emissions. The contribution of regional Ox dominated from midmorning to noon when the boundary layer height began to increase due to sunlight heating of the surface leading to the mixing of higher concentrations of O3 above the nighttime thermal inversion. After noon, when the ozone vertical distribution was uniform, the Ox and O3 concentrations reached their maximum; they were very similar with very low levels of NO2. The analysis of wind data collected at the monitoring sites showed that from mid-morning to early afternoon, a northerly weak flow was common. Afterwards stronger southerly winds became dominant bringing in O3 rich air parcels into the atmospheric basin where MCMA is located. The high regional ozone concentrations add evidence for the need of coordinated air quality management policies for the complete central part of Mexico. Keywords: mountain gap, oxidant, ground level ozone, Central Mexico

  1. Statistical exploration of gaseous elemental mercury (GEM) measured at Cape Point from 2007 to 2011

    NASA Astrophysics Data System (ADS)

    Venter, A. D.; Beukes, J. P.; van Zyl, P. G.; Brunke, E.-G.; Labuschagne, C.; Slemr, F.; Ebinghaus, R.; Kock, H.

    2015-02-01

    The authors evaluated continuous high resolution gaseous elemental mercury (GEM) data from the Cape Point Global Atmosphere Watch (CPT GAW) station with different statistical analysis techniques. GEM data was evaluated by cluster analysis and the results indicated that two clusters, separated at 0.904 ng m-3, existed. The air mass history for the two-cluster solution was investigated by means of back-trajectory analysis. The air mass back-trajectory net result showed lower GEM concentrations originating from the sparsely populated semi-arid interior of SA and the marine environment, whereas higher GEM concentrations originated predominately along the coast of SA that most likely coincide with trade routes and industrial activities in urban areas along the coast. Considering the net result from the air mass back-trajectories, it is evident that not all low GEM concentrations are from marine origin, and similarly, not all high GEM concentrations have a terrestrial origin. Equations were developed by means of multi-linear regression (MLR) analysis that allowed for the estimation/prediction of atmospheric GEM concentrations from other atmospheric parameters measured at the CPT GAW station. These equations also provided some insight into the relation and interaction of GEM with other atmospheric parameters. Both measured and MLR calculated data confirm a decline in GEM concentrations at CPT GAW over the period evaluated.

  2. Statistical exploration of gaseous elemental mercury (GEM) measured at Cape Point from 2007 to 2011

    NASA Astrophysics Data System (ADS)

    Venter, A. D.; Beukes, J. P.; van Zyl, P. G.; Brunke, E.-G.; Labuschagne, C.; Slemr, F.; Ebinghaus, R.; Kock, H.

    2015-09-01

    The authors evaluated continuous high-resolution gaseous elemental mercury (GEM) data from the Cape Point Global Atmosphere Watch (CPT GAW) station with different statistical analysis techniques. GEM data were evaluated by cluster analysis and the results indicated that two clusters, separated at 0.904 ng m-3, existed. The air mass history for the two-cluster solution was investigated by means of back-trajectory analysis. The air mass back-trajectory net result showed lower GEM concentrations originating from the sparsely populated semi-arid interior of South Africa and the marine environment, whereas higher GEM concentrations originated predominately along the coast of South Africa that most likely coincide with trade routes and industrial activities in urban areas along the coast. Considering the net result from the air mass back-trajectories, it is evident that not all low GEM concentrations are from marine origin, and similarly, not all high GEM concentrations have a terrestrial origin. Equations were developed by means of multi-linear regression (MLR) analysis that allowed for the estimation and/or prediction of atmospheric GEM concentrations from other atmospheric parameters measured at the CPT GAW station. These equations also provided some insight into the relation and interaction of GEM with other atmospheric parameters. Both measured and MLR calculated data confirm a decline in GEM concentrations at CPT GAW over the period evaluated.

  3. Mass Sensor

    SciTech Connect

    Adams, B.E.

    2001-01-18

    The purpose of this CRADA was to use Honeywell's experience in low temperature cofire ceramics and traditional ceramics to assemble a relatively low-cost, mass-producible miniature mass analyzer. The specific design, given to us by Mass Sensors, LLC, was used to test for helium. The direct benefit for the participant was to have a prototype unit assembled for the purpose of proof of concept and the ability to secure venture capital investors. From that, the company would begin producing their own product for sale. The consumer/taxpayer benefits come from the wide variety of industries that can utilize this technology to improve quality of life. Medical industry can use this technology to improve diagnostic ability; manufacturing industry can use it for improved air, water, and soil monitoring to minimize pollution; and the law enforcement community can use this technology for identification of substances. These are just a few examples of the benefit of this technology. The benefits to DOE were in the area of process improvement for cofire and ceramic materials. From this project we demonstrated nonlinear thickfilm fine lines and spaces that were 5-mil wide with 5-mil spaces; determined height-to diameter-ratios for punched and filled via holes; demonstrated the ability to punch and fill 5-mil microvias; developed and demonstrated the capability to laser cut difficult geometries in 40-mil ceramic; developed and demonstrated coupling LTCC with standard alumina and achieving hermetic seals; developed and demonstrated three-dimensional electronic packaging concepts; and demonstrated printing variable resistors within 1% of the nominal value and within a tightly defined ratio. The capability of this device makes it invaluable for many industries. The device could be used to monitor air samples around manufacturing plants. It also could be used for monitoring automobile exhaust, for doing blood gas analysis, for sampling gases being emitted by volcanoes, for studying

  4. Longitudinal bulk acoustic mass sensor

    SciTech Connect

    Hales, J. H.; Teva, J.; Boisen, A.; Davis, Z. J.

    2009-07-20

    A polycrystalline silicon longitudinal bulk acoustic cantilever is fabricated and operated in air at 51 MHz. A mass sensitivity of 100 Hz/fg (1 fg=10{sup -15} g) is obtained from the preliminary experiments where a minute mass is deposited on the device by means of focused ion beam. The total noise in the currently applied measurement system allows for a minimum detectable mass of 0.5 fg in air.

  5. Longitudinal bulk acoustic mass sensor

    NASA Astrophysics Data System (ADS)

    Hales, J. H.; Teva, J.; Boisen, A.; Davis, Z. J.

    2009-07-01

    A polycrystalline silicon longitudinal bulk acoustic cantilever is fabricated and operated in air at 51 MHz. A mass sensitivity of 100 Hz/fg (1 fg=10-15 g) is obtained from the preliminary experiments where a minute mass is deposited on the device by means of focused ion beam. The total noise in the currently applied measurement system allows for a minimum detectable mass of 0.5 fg in air.

  6. Variation of polycyclic aromatic hydrocarbons in atmospheric PM2.5 during winter haze period around 2014 Chinese Spring Festival at Nanjing: Insights of source changes, air mass direction and firework particle injection.

    PubMed

    Kong, Shaofei; Li, Xuxu; Li, Li; Yin, Yan; Chen, Kui; Yuan, Liang; Zhang, Yingjie; Shan, Yunpeng; Ji, Yaqin

    2015-07-01

    Daily PM2.5 samples were collected at a suburban site of Nanjing around 2014 Chinese Spring Festival (SF) and analyzed for 18 kinds of polycyclic aromatic hydrocarbons (PAHs) by GC-MS. Comparison of PAH concentrations during different periods, with different air mass origins and under different pollution situations was done. Sources were analyzed by diagnostics ratios and principal component analysis (PCA). The threat of PAHs was assessed by BaP equivalent concentrations (BaPeq) and incremental lifetime cancer risk (ILCR). The averaged PAHs for pre-SF, SF and after SF periods were 50.6, 17.2 and 29 ng m(-3), indicating the variations of PAH sources, with reduced traffic, industrial and construction activities during SF and gradually re-starting of them after-SF. According to PAH mass concentrations, their relative abundance to particles, ratio of PAHs (3-ring+4-ring)/PAHs(5-ring+6-ring), mass concentrations of combustion-derived and carcinogenic PAHs, fireworks burning is an important source for PAHs during SF. The ILCR values for Chinese New Year day were 0.68 and 3.3 per 100,000 exposed children and adults. It suggested the necessity of controlling fireworks burning during Chinese SF period which was always companied with serious regional haze pollution. PAH concentrations exhibited decreasing trend when air masses coming from the following directions as North China Plain (63.9 ng m(-3))>Central China (53.0 ng m(-3))>Shandong Peninsula (46.6 ng m(-3))>Northwest China (18.8 ng m(-3))>Sea (15.8 ng m(-3)). For different pollution situations, they decreased as haze (44.5 ng m(-3))>fog-haze (28.4 ng m(-3))>clear (12.2 ng m(-3))>fog day (9.2 ng m(-3)). Coal combustion, traffic emission, industrial processes and petroleum (only for non-SF holiday periodss) were the main sources of PM2.5 associated PAHs. Fireworks burning contributed 14.0% of PAHs during SF period. Directly measurement of PAHs from fireworks burning is urgently needed for source apportionment studies in

  7. An improved high performance liquid chromatography-photodiode array detection-atmospheric pressure chemical ionization-mass spectrometry method for determination of chlorophylls and their derivatives in freeze-dried and hot-air-dried Rhinacanthus nasutus (L.) Kurz.

    PubMed

    Kao, Tsai Hua; Chen, Chia Ju; Chen, Bing Huei

    2011-10-30

    Rhinacanthus nasutus (L.) Kurz, a traditional Chinese herb possessing antioxidant and anti-cancer activities, has been reported to contain functional components like carotenoids and chlorophylls. However, the variety and amount of chlorophylls remain uncertain. The objectives of this study were to develop a high performance liquid chromatography-photodiode array detection-atmospheric pressure chemical ionization-mass spectrometry (HPLC-DAD-APCI-MS) method for determination of chlorophylls and their derivatives in hot-air-dried and freeze-dried R. nasutus. An Agilent Eclipse XDB-C18 column and a gradient mobile phase composed of methanol/N,N-dimethylformamide (97:3, v/v), acetonitrile and acetone were employed to separate internal standard zinc-phthalocyanine plus 12 cholorophylls and their derivatives within 21 min, including chlorophyll a, chlorophyll a', hydroxychlorophyll a, 15-OH-lactone chlorophyll a, chlorophyll b, chlorophyll b', hydroxychlorophyll b, pheophytin a, pheophytin a', hydroxypheophytin a, hydroxypheophytin a' and pheophytin b in hot-air-dried R. nasutus with flow rate at 1 mL/min and detection at 660 nm. But, in freeze-dried R. nasutus, only 4 chlorophylls and their derivatives, including chlorophyll a, chlorophyll a', chlorophyll b and pheophytin a were detected. Zinc-phthalocyanine was found to be an appropriate internal standard to quantify all the chlorophyll compounds. After quantification by HPLC-DAD, both chlorophyll a and pheophytin a were the most abundant in hot-air-dried R. nasutus, while in freeze-dried R. nasutus, chlorophyll a and chlorophyll b dominated.

  8. Measurements of Background and Polluted Air in Rural Regions of Rwanda

    NASA Astrophysics Data System (ADS)

    DeWitt, L.; Gasore, J.; Prinn, R. G.; Potter, K. E.

    2015-12-01

    Rwanda, a mountainous nation in Equatorial East Africa, is one of the least-urbanized nations in Africa. The majority of the population are subsistence farmers, and major sources of air pollution (e.g., particulates, greenhouse gases) in Rwanda include agricultural burning and cookstoves in rural areas, and older diesel vehicles and mototaxis in cities. Currently, initiatives to supply efficient cookstoves, development of cleaner-burning fuel from recycled agricultural waste, and new regulations on vehicle emissions and importation are underway. These initiatives seek to help Rwanda grow in the greenest way possible, to mitigate negative health and climate effects of development; however, little ambient data on air quality is available in different regions of Rwanda for a baseline study before and benefits study after these initiatives. The Rwanda Climate Observatory, located on the summit of Mt. Mugogo (-1.5833°, 29.5667°), a 2.5 km peak, has recently begun measurements of black carbon (BC) aerosol concentration and O3 and CO gas concentrations. BC measurements were performed with a 7-wavelength Magee Scientific aethalometer and the aethalometer model was used to calculate the influence of fossil fuel and biomass burning sources on BC concentrations. CO and O3 measurements were used in conjunction with BC aerosol data, and HYSPLIT back trajectories were also used to help discriminate between periods of heavy burning and periods of regional influence from traffic and general cookfire emissions. Since Mt. Mugogo is in a rural area, this station captures a snapshot of regional background pollution away from high anthropogenic influence. The nearby households and fields also allow case studies of household and crop burning during localized events and help quanitfy potential daily exposure to particulates and climate-forcing emissions in remote areas of this developing country. We will present time series of the BC, O3, CO and insolation measurements at Mt. Mugogo

  9. Impact of external industrial sources on the regional and local air quality of Mexico Megacity

    NASA Astrophysics Data System (ADS)

    Almanza, Victor; Molina, Luisa T.; Li, Guohui; Fast, Jerome; Sosa, Gustavo

    2014-05-01

    The air quality of megacities can be influenced by external emissions sources on both regional and global scales. At the same time their outflow emissions can exert an important impact to the surrounding environment. The present study evaluates an SO2 peak observed on 24 March 2006 at the suburban supersite and ambient air quality monitoring stations located in the northern region of the Mexico City Metropolitan Area (MCMA) during MILAGRO campaign. We found that this peak could be related to an important episodic emission event coming from Tizayuca region, northeast of the MCMA. Back trajectories analyses suggest that the emission event started in the early morning at 04:00 LST and lasted for about 9 hours. The estimated emission rate is high, about 2 kg s-1. This finding suggests the possibility of 'overlooked' emission sources in Tizayuca region that could influence the air quality of the MCMA. This further motivated us to study the cement plants, including those in the State of Hidalgo and the State of Mexico. We found that they can also contribute SO2 in the NE region of the basin, at the suburban supersite and that at some monitoring stations; their contribution can be even higher than from the Tula Industrial Complex (TIC). The contribution of TIC to regional ozone levels is also estimated. The model suggests low contribution to the MCMA and slightly higher contribution at the suburban and rural supersites. However, the contribution could be high in the upper northwest region of the basin and in the southwest and south-southeast regions of the State of Hidalgo. In addition, a first estimate of the potential contribution from flaring activities to regional ozone levels is presented. Results suggest that part of the total regional ozone from TIC-generated precursors could be related to flaring activities.

  10. Impact of the 2002 Canadian forest fires on particulate matter air quality in Baltimore city.

    PubMed

    Sapkota, Amir; Symons, J Morel; Kleissl, Jan; Wang, Lu; Parlange, Marc B; Ondov, John; Breysse, Patrick N; Diette, Gregory B; Eggleston, Peyton A; Buckley, Timothy J

    2005-01-01

    With increasing evidence of adverse health effects associated with particulate matter (PM), the exposure impact of natural sources, such as forest fires, has substantial public health relevance. In addition to the threat to nearby communities, pollutants released from forest fires can travel thousands of kilometers to heavily populated urban areas. There was a dramatic increase in forest fire activity in the province of Quebec, Canada, during July 2002. The transport of PM released from these forest fires was examined using a combination of a moderate-resolution imaging spectroradiometer satellite image, back-trajectories using a hybrid single-particle Lagrangian integrated trajectory, and local light detection and ranging measurements. Time- and size-resolved PM was evaluated at three ambient and four indoor measurement sites using a combination of direct reading instruments (laser, time-of-flight aerosol spectrometer, nephelometer, and an oscillating microbalance). The transport and monitoring results consistently identified a forest fire related PM episode in Baltimore that occurred the first weekend of July 2002 and resulted in as much as a 30-fold increase in ambientfine PM. On the basis of tapered element oscillating microbalance measurements, the 24 h PM25 concentration reached 86 microg/m3 on July 7, 2002, exceeding the 24 h national ambient air quality standard. The episode was primarily comprised of particles less than 2.5 microm in aerodynamic diameter, highlighting the preferential transport of the fraction of PM that is of greatest health concern. Penetration of the ambient episode indoors was efficient (median indoor-to-outdoor ratio 0.91) such that the high ambient levels were similarly experienced indoors. These results are significant in demonstrating the impact of a natural source thousands of kilometers away on ambient levels of and potential exposures to air pollution within an urban center. This research highlights the significance of

  11. Air/light-free hyphenated extraction/analysis system: supercritical fluid extraction on-line coupled with liquid chromatography-UV absorbance/electrospray mass spectrometry for the determination of hyperforin and its degradation products in Hypericum pertoratum.

    PubMed

    Wang, Zhenyu; Ashraf-Khorassani, Mehdi; Taylor, Larry T

    2004-11-15

    Hyperforin, which is a major active constituent of the antidepression herbal medicine-Hypericum pertoratum (St. John's wort), is very sensitive to oxygen and light. Our paper reports for the first time an air/light-free extraction-separation-detection hyphenated system and its application to St. John's wort. It involves on-line coupling of supercritical fluid extraction with liquid chromatography-UV absorbance/electrospray ionization mass spectrometry (SFE-LC-UV/ESI-MS). Mass spectral data on the extract that was produced on-line suggested the presence of the major degradation compound of hyperforin-furohyperforin and two of its analogues. Thus, some degradation process must have already occurred in our sample during plant drying or storage. The feasibility of quantitative extraction and analysis of hyperforin by on-line SFE-LC was made possible by optimizing the extraction pressure, temperature, and CO(2) modifier content. High recovery ( approximately 90%) relative to liquid-solid extraction was achieved under optimized conditions.

  12. A snapshot of the UK net greenhouse gas flux using a mass balance approach with aircraft measurements

    NASA Astrophysics Data System (ADS)

    Allen, G.; Pitt, J. R.; Palmer, P. I.; Percival, C.; Mead, M. I.; Lee, J. D.; Le Breton, M. R.

    2015-12-01

    We present airborne observations of high-precision in-situ and remotely sensed CO2, CH4 and other trace gases made from the NERC Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 research aircraft during Spring and Summer months in 2014 and 2015. Measurements were recorded during the GAUGE (Greenhouse gAs Uk and Global Emissions) aircraft field campaign, based out of Cranfield, UK, with sampling around and over the UK Mainland and Ireland. We derive Lagrangian mass-balanced net surface fluxes of CO2, CH4, CO, and N2O from a large surface footprint of England based on data collected during a flight in May 2015 by combining in-situ and remote-sensed concentration measurements and measured boundary layer thermodynamic profiles. By employing an advective box model for the volume enclosed by the flight-tracks and combining aircraft-measured winds and along-track Lagrangian back-trajectory modelling, we examine the sensitivity of total flux uncertainty to atmospheric transport and measurement errors using error propagation implicit in the mass balancing method. Finally, we compare the measured snapshot net fluxes to those reported in the current UK emissions inventory (weighted for surface footprint) and to previous UK-regional greenhouse gas top-down assessments.

  13. Model Calculations of the Impact of NO(x) from Air Traffic, Lightning and Surface Emissions, Compared with Measurements

    NASA Technical Reports Server (NTRS)

    Meijer, E. W.; vanVelthoven, P. F. J.; Thompson, A. M.; Pfister, L.; Schlager, H.; Schulte, P.; Kelder, H.

    1999-01-01

    The impact of NO(x) from aircraft emissions, lightning and surface contributions on atmospheric nitrogen oxides and ozone has been investigated with the three-dimensional global chemistry transport model TM3 by partitioning the nitrogen oxides and ozone according to source category. The results have been compared with POLINAT II and SONEX airborne measurements in the North Atlantic flight corridor in 1997. Various cases have been investigated: measurements during a stagnant anti-cyclone and an almost cut-off low, both with expected high aircraft contributions, a southward bound flight with an expected strong flight corridor gradient and lightning contributions in the South, and a transatlantic flight with expected boundary layer pollution near the U.S. coast. The agreement between modeled results and measurements is reasonably good for NO and ozone. Also, the calculated impact of the three defined sources were consistent with the estimated exposure of the sampled air to these sources, obtained by specialized back-trajectory model products.

  14. Assessing levels of POPs in air over the South Atlantic Ocean off the coast of South America.

    PubMed

    Pegoraro, César N; Harner, Tom; Su, Ky; Chiappero, Malisa S

    2016-11-15

    The occurrence of persistent organic pollutants (POPs) in the atmosphere of the near-coast South Atlantic Ocean was studied. Air samples were collected using a high-volume air sampler (filter and polyurethane foam) on board the Argentinean research cruise R/V Puerto Deseado (CONICET). Samples were analyzed for 50 polychlorinated biphenyl (PCBs), 22 organochlorine pesticides (OCPs) and 14 polybrominated diphenyl ethers (PBDEs). These POPs classes showed a trend of decreasing levels from near-shore to open ocean sites. OCPs and PCBs were in the same order of magnitude (2.71-87.1pg/m(3) and 9.56-130pg/m(3), respectively) while PBDEs levels were significantly lower (0.69-2.58pg/m(3)). Dichlorodiphenyltrichloroethanes (DDTs), endosulfans, chlordanes, hexachlorocyclohexanes (HCHs) and heptachlors were between 0.20 and 17.8pg/m(3), while drines and hexachlorobenzene (HCB) were at lower levels (0.28-3.71pg/m(3)). The most frequently detected PCBs were congeners 32, 28, 44, 52, 95, representing >50% of the total. The PBDEs congener pattern was dominated by congener 209 (70%), followed by 47 and 99 (16% and 7%, respectively). Air parcel back trajectories for the study period provided few insights as trajectories mainly stemmed from the open ocean with limited inputs from continental sources. These results indicate that the concentration of POPs (namely PCBs, OCPs, and PBDEs) in air remain elevated in the near-shore environment and then drop-off substantially beyond a distance of about 400km. This has implications for the loading of POPs and delivery to the marine environment in the near coastal zone.

  15. Passive-sampler derived air concentrations of persistent organic pollutants on a north-south transect in Chile.

    PubMed

    Pozo, Karla; Harner, Tom; Shoeib, Mahiba; Urrutia, Roberto; Barra, Ricardo; Parra, Oscar; Focardi, Silvano

    2004-12-15

    Passive air samplers consisting of polyurethane foam (PUF) disks, were deployed in six locations in Chile along a north-south transect to investigate gas-phase concentrations of polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ethers (PBDEs). The study provides new information on air concentrations of these persistent organic pollutants (POPs) which is lacking in this region. It also provides insight into potential sources and long-range transport (LRT). The samplers were deployed for a 2-month period in five remote sites and one site in the city of Concepción. Mean concentrations (pg m(-3)) for sigmaPCB were 4.7 +/- 2.7 at remote sites and 53 +/- 13 in Concepción. PCB levels at remote sites were related to proximity to urban source regions and/or air back trajectories. With the exception of endosulfan I, mean concentrations (pg m(-3)) of OCPs at background sites were consistently low: 5.4 +/- 1.4 for alpha-HCH, 7.0 +/- 1.1 for gamma-HCH, 2.5 +/- 0.5 for TC, 2.5 +/- 0.6 for CC, 1.9 +/- 1.2 for dieldrin, and less than 3.5 for toxaphene. Endosulfan I showed a decreasing concentration gradient from 99 to 3.5 pg m(-3) from the north to south of Chile. Concentrations of OCPs in the Concepción City were generally 10-20 times higher than at the background sites suggesting continued usage and/or re-emission from past use. For instance, at remote sites, the alpha/gamma ratio (0.76) was typical of background air, while the ratio in Concepción (0.12) was consistent with fresh use of gamma-HCH. Levels of sigmaPBDEs were below the detection limit of 6 pg m(-3) at all sites.

  16. High-Compression-Ratio; Atkinson-Cycle Engine Using Low-Pressure Direct Injection and Pneumatic-Electronic Valve Actuation Enabled by Ionization Current and Foward-Backward Mass Air Flow Sensor Feedback

    SciTech Connect

    Harold Schock; Farhad Jaberi; Ahmed Naguib; Guoming Zhu; David Hung

    2007-12-31

    This report describes the work completed over a two and one half year effort sponsored by the US Department of Energy. The goal was to demonstrate the technology needed to produce a highly efficient engine enabled by several technologies which were to be developed in the course of the work. The technologies included: (1) A low-pressure direct injection system; (2) A mass air flow sensor which would measure the net airflow into the engine on a per cycle basis; (3) A feedback control system enabled by measuring ionization current signals from the spark plug gap; and (4) An infinitely variable cam actuation system based on a pneumatic-hydraulic valve actuation These developments were supplemented by the use of advanced large eddy simulations as well as evaluations of fuel air mixing using the KIVA and WAVE models. The simulations were accompanied by experimental verification when possible. In this effort a solid base has been established for continued development of the advanced engine concepts originally proposed. Due to problems with the valve actuation system a complete demonstration of the engine concept originally proposed was not possible. Some of the highlights that were accomplished during this effort are: (1) A forward-backward mass air flow sensor has been developed and a patent application for the device has been submitted. We are optimistic that this technology will have a particular application in variable valve timing direct injection systems for IC engines. (2) The biggest effort on this project has involved the development of the pneumatic-hydraulic valve actuation system. This system was originally purchased from Cargine, a Swedish supplier and is in the development stage. To date we have not been able to use the actuators to control the exhaust valves, although the actuators have been successfully employed to control the intake valves. The reason for this is the additional complication associated with variable back pressure on the exhaust valves when

  17. Distribution and mass loss of volatile organic compounds in the surficial aquifer at sites FT03, LF13, and WP14/LF15, Dover Air Force Base, Delaware, November 2000-February 2001

    USGS Publications Warehouse

    Barbaro, Jeffrey R.; Neupane, Pradumna P.

    2002-01-01

    Ground-water and surface-water sampling was conducted in the natural attenuation study area in the East Management Unit of Dover Air Force Base, Delaware to determine the distributions of volatile organic compounds in the vicinity of four sites?Fire Training Area Three, the Rubble Area Landfill, the Receiver Station Landfill, and the Liquid Waste Disposal Landfill. This work was done by the U.S. Geological Survey, in cooperation with the U.S. Air Force, as part of an ongoing assessment of the effectiveness of natural attenuation at these sites. The specific objectives of the study were to (1) determine the areal and vertical extent of the contaminant plumes and source areas, (2) measure volatile organic compound concentrations in ground-water discharge areas and in surface water under base-flow conditions, (3) evaluate the potential for off-site migration of the mapped plumes, and (4) estimate the amount of mass loss downgradient of the Liquid Waste Disposal and Receiver Station Landfills. A direct-push drill rig and previously installed multi-level piezometers were used to determine the three-dimensional distributions of volatile organic compounds in the 30?60-foot-thick surficial aquifer underlying the natural attenuation study area. A hand -driven mini-piezometer was used to collect ground-water samples in ground-water discharge areas. A total of 319 ground-water and 4 surface-water samples were collected from November 2000 to February 2001 and analyzed for chlorinated solvents and fuel hydrocarbons. The contaminant plumes migrating from Fire Training Area Three and the Rubble Area Landfill are approximately 500 feet and 800 feet, respectively, in length. These plumes consist predominantly of cis-1,2-dichloroethene, a daughter product, indicating that extensive dechlorination of tetrachloroethene and trichloroethene has occurred at these sites. With an approximate length of 2,200 feet, the plume migrating from the Receiver Station and Liquid Waste Disposal

  18. Relationship Between Precipitation Chemistry and Meteorological Parameters at a Urban Site in the North of Queretaro State

    NASA Astrophysics Data System (ADS)

    García Martínez, R.; Hernández, G.; Solis, S.; Torres, M. D.; Padilla, H.; Báez, A.

    2010-12-01

    A total of 50 wet precipitation samples were collected per event at the Juriquilla site from mid-May 2009 to the end of May 2010. The Juriquilla sampling site was located on the roof of the Geoscience Building, Universidad Nacional Autónoma de México, at the Juriquilla Campus in the city of Querétaro located at 20°41'58"N and 100°27'28" W, at 1920 meters above sea level (masl). Sampling was done in passive collectors that consisted of a high density polyethylene funnel connected to a 2-liter polyethylene bottle, supported by a rod 1.5 m above the roof. One of the collectors was used to take samples for trace metals. The analysis was done in soluble and insoluble fractions. Al, Ag, As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, V and Zn were analyzed by atomic absorption spectroscopy with a graphite furnace accessory. The other collector was used to measure pH and major ions (SO4-2, Cl-, NO3-, Ca2+, Mg2+, Na+, K+ and NH4+) in the soluble fractions, because it was assumed that these ions are completely soluble in rainwater. The major ions SO4-2, Cl-, and NO3-, were analyzed by a Varian Model 2010 ion chromatograph; Ca2+, Mg2+, Na+ and K+ were determined by flame atomic absorption spectrometry and NH4+ by a UV spectrophotometer. In this study, synoptic maps were used to analyze the transport of air masses before rainfall, enabling back trajectories to be used to estimate the source region of pollutants. To understand the variety of synoptic weather conditions, data were associated with the corresponding air mass back trajectories calculated by the NOAA HYSPLIT model (Hybrid Single-Particle Lagrangian Integrated Trajectory Model). Back trajectory models have very simple advection schemes to calculate the previous position of an air parcel by using estimated wind speed and direction for the time period prior to arrival at the selected site. In this study, the origin of the air mass for an event was evaluated by a three-day back-trajectory before arrival to Queretaro. Mass back

  19. Experimental Evaluation of the Effect of Angle-of-attack on the External Aerodynamics and Mass Capture of a Symmetric Three-engine Air-breathing Launch Vehicle Configuration at Supersonic Speeds

    NASA Technical Reports Server (NTRS)

    Kim, Hyun D.; Frate, Franco C.

    2001-01-01

    A subscale aerodynamic model of the GTX air-breathing launch vehicle was tested at NASA Glenn Research Center's 10- by 10-Foot Supersonic Wind Tunnel from Mach 2.0 to 3.5 at various angles-of-attack. The objective of the test was to investigate the effect of angle-of-attack on inlet mass capture, inlet diverter effectiveness, and the flowfield at the cowl lip plane. The flow-through inlets were tested with and without boundary-layer diverters. Quantitative measurements such as inlet mass flow rates and pitot-pressure distributions in the cowl lip plane are presented. At a 3deg angle-of-attack, the flow rates for the top and side inlets were within 8 percent of the zero angle-of-attack value, and little distortion was evident at the cowl lip plane. Surface oil flow patterns showing the shock/boundary-layer interaction caused by the inlet spikes are shown. In addition to inlet data, vehicle forebody static pressure distributions, boundary-layer profiles, and temperature-sensitive paint images to evaluate the boundary-layer transition are presented. Three-dimensional parabolized Navier-Stokes computational fluid dynamics calculations of the forebody flowfield are presented and show good agreement with the experimental static pressure distributions and boundary-layer profiles. With the boundary-layer diverters installed, no adverse aerodynamic phenomena were found that would prevent the inlets from operating at the required angles-of-attack. We recommend that phase 2 of the test program be initiated, where inlet contraction ratio and diverter geometry variations will be tested.

  20. Air Pollution.

    ERIC Educational Resources Information Center

    Gilpin, Alan

    A summary of one of our most pressing environmental problems, air pollution, is offered in this book by the Director of Air Pollution Control for the Queensland (Australia) State Government. Discussion of the subject is not restricted to Queensland or Australian problems and policies, however, but includes analysis of air pollution the world over.…

  1. Air Pollution

    MedlinePlus

    ... of Climate Change on Children's Health: Session Two: Air Quality Impacts MODERATOR: Susan Anenberg, EPA Meredith McCormack, Johns ... University • Effects of Climate Change on Children’s Health: Air Quality Impacts Frederica Perera, Columbia University • Air quality Impacts ...

  2. Variation in airborne (134)Cs, (137)Cs, particulate (131)I and (7)Be maximum activities at high-altitude European locations after the arrival of Fukushima-labeled air masses.

    PubMed

    Masson, Olivier; Bieringer, Jacqueline; Brattich, Erika; Dalheimer, Axel; Estier, Sybille; Penev, Ilia; Ringer, Wolfgang; Schlosser, Clemens; Steinkopff, Thomas; Steinmann, Philipp; Tositti, Laura; Van Beek, Pieter; Vismes-Ott, Anne de

    2016-10-01

    The Fukushima-labeled air mass arrival, and later the cesium-134 ((134)Cs), cesium-137 ((137)Cs) and particulate iodine-131 (hereafter noted (131)Ip) maximum levels were registered in Europe at different dates depending on the location. Most of those data were obtained at low-altitude sampling areas. Here, we compare the airborne levels registered at different high-altitude European locations (from 850 m to about 3500 m). The integrated (137)Cs activity concentration was not uniform with regard to the altitude even after a long travel time/distance from Japan. Moreover, the relation of integrated (137)Cs vs. altitude showed a linear decrease up to an altitude of about 3000 m. A similar trend was noticed for (131)Ip (particulate fraction) while it increased above 3000 m. Comparison with (7)Be activity concentration showed that, as far as the high altitude location is concerned, the (137)Cs and (134)Cs maximum concentrations corresponded to the (7)Be maximum, suggesting downdraft movements from high tropospheric or stratospheric layers to be responsible for (137,134)Cs increase and peak values. This was also confirmed by high potential vorticity and low relative humidity registered during the peak values.

  3. Simultaneous analysis of oxygenated and nitrated polycyclic aromatic hydrocarbons on standard reference material 1649a (urban dust) and on natural ambient air samples by gas chromatography-mass spectrometry with negative ion chemical ionisation.

    PubMed

    Albinet, A; Leoz-Garziandia, E; Budzinski, H; Viilenave, E

    2006-07-14

    This study deals with the development of a routine analytical method using gas chromatography-mass spectrometry with negative ion chemical ionisation (GC/NICI-MS) for the determination of 17 nitrated polycyclic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycyclic aromatic hydrocarbons (OPAHs) present at low concentrations in the atmosphere. This method includes a liquid chromatography purification procedure on solid-phase extraction (SPE) cartridge. Application of this analytical procedure has been performed on standard reference material (SRM 1649a: urban dust), giving results in good agreement with the few data available in the literature. The analytical method was also applied on ambient air samples (on both gas and particulate phases) from the French POVA program (POllution des Vallées Alpines). NPAHs concentrations observed for a rural site during the Winter period are about 0.2-100.0pgm(-3) in the particulate phase and about 0.0-20.0pgm(-3) in the gas phase. OPAHs present concentrations 10-100 times higher (0.1-2.0ngm(-3) and 0.0-1.4ngm(-3) for the particulate and the gas phases, respectively). These preliminary results show a good correlation between the characteristics of the sampling site and the compound origins (primary or secondary).

  4. An Elevated Reservoir of Air Pollutants over the Mid-Atlantic States During the 2011 DISCOVER-AQ Campaign: Airborne Measurements and Numerical Simulations

    NASA Technical Reports Server (NTRS)

    He, Hao; Loughner, Christopher P.; Stehr, Jeffrey W.; Arkinson, Heather L.; Brent, Lacey C.; Follette-Cook, Melanie B.; Tzortziou, Maria A.; Pickering, Kenneth E.; Thompson, Anne M.; Martins, Douglas K.; Diskin, Glenn S.; Anderson, Bruce E.; Crawford, James H.; Weinheimer, Andrew J.; Lee, Pius; Hains, Jennifer C.; Dickerson, Russell R.

    2013-01-01

    During a classic heat wave with record high temperatures and poor air quality from July 18 to 23, 2011, an elevated reservoir of air pollutants was observed over and downwind of Baltimore, MD, with relatively clean conditions near the surface. Aircraft and ozonesonde measurements detected approximately 120 parts per billion by volume ozone at 800 meters altitude, but approximately 80 parts per billion by volume ozone near the surface. High concentrations of other pollutants were also observed around the ozone peak: approximately 300 parts per billion by volume CO at 1200 meters, approximately 2 parts per billion by volume NO2 at 800 meters, approximately 5 parts per billion by volume SO2 at 600 meters, and strong aerosol optical scattering (2 x 10 (sup 4) per meter) at 600 meters. These results suggest that the elevated reservoir is a mixture of automobile exhaust (high concentrations of O3, CO, and NO2) and power plant emissions (high SO2 and aerosols). Back trajectory calculations show a local stagnation event before the formation of this elevated reservoir. Forward trajectories suggest an influence on downwind air quality, supported by surface ozone observations on the next day over the downwind PA, NJ and NY area. Meteorological observations from aircraft and ozonesondes show a dramatic veering of wind direction from south to north within the lowest 5000 meters, implying that the development of the elevated reservoir was caused in part by the Chesapeake Bay breeze. Based on in situ observations, Community Air Quality Multi-scale Model (CMAQ) forecast simulations with 12 kilometers resolution overestimated surface ozone concentrations and failed to predict this elevated reservoir; however, CMAQ research simulations with 4 kilometers and 1.33 kilometers resolution more successfully reproduced this event. These results show that high resolution is essential for resolving coastal effects and predicting air quality for cities near major bodies of water such as