Sample records for air mass boundaries

  1. Boundary layers at a dynamic interface: Air-sea exchange of heat and mass

    NASA Astrophysics Data System (ADS)

    Szeri, Andrew J.

    2017-04-01

    Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and anthropogenic gases involved in the study of climate. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble nonreactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity w' and gas concentration c' are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither w' nor c' can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from measurements that can be taken by an infrared (IR) camera. An equation is derived with inputs being the surface temperature and heat flux, and a solution method developed for the surface-normal strain experienced over time by boundary layers at the interface. Because the thermal and concentration boundary layers experience the same near-surface fluid motions, the solution for the surface-normal strain determines the gas flux or gas transfer velocity. Examples illustrate the approach in the cases of complete surface renewal, partial surface renewal, and insolation. The prospects for use of the approach in flows characterized by sheared interfaces or rapid boundary layer straining are explored.

  2. Boundary layers at a dynamic interface: air-sea exchange of heat and mass

    NASA Astrophysics Data System (ADS)

    Szeri, Andrew

    2017-11-01

    Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and man-made gases involved in climate change. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble non-reactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity and gas concentration differences are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither of these quantities can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from remote measurements, which allows one to determine the gas transfer velocity, or gas flux per unit area if overall concentration differences are known. The approach is illustrated with conceptual examples.

  3. Effect of real-time boundary wind conditions on the air flow and pollutant dispersion in an urban street canyon—Large eddy simulations

    NASA Astrophysics Data System (ADS)

    Zhang, Yun-Wei; Gu, Zhao-Lin; Cheng, Yan; Lee, Shun-Cheng

    2011-07-01

    Air flow and pollutant dispersion characteristics in an urban street canyon are studied under the real-time boundary conditions. A new scheme for realizing real-time boundary conditions in simulations is proposed, to keep the upper boundary wind conditions consistent with the measured time series of wind data. The air flow structure and its evolution under real-time boundary wind conditions are simulated by using this new scheme. The induced effect of time series of ambient wind conditions on the flow structures inside and above the street canyon is investigated. The flow shows an obvious intermittent feature in the street canyon and the flapping of the shear layer forms near the roof layer under real-time wind conditions, resulting in the expansion or compression of the air mass in the canyon. The simulations of pollutant dispersion show that the pollutants inside and above the street canyon are transported by different dispersion mechanisms, relying on the time series of air flow structures. Large scale air movements in the processes of the air mass expansion or compression in the canyon exhibit obvious effects on pollutant dispersion. The simulations of pollutant dispersion also show that the transport of pollutants from the canyon to the upper air flow is dominated by the shear layer turbulence near the roof level and the expansion or compression of the air mass in street canyon under real-time boundary wind conditions. Especially, the expansion of the air mass, which features the large scale air movement of the air mass, makes more contribution to the pollutant dispersion in this study. Comparisons of simulated results under different boundary wind conditions indicate that real-time boundary wind conditions produces better condition for pollutant dispersion than the artificially-designed steady boundary wind conditions.

  4. Grain Boundary Engineering and Air Oxidation Behavior of Alloy 690

    NASA Astrophysics Data System (ADS)

    Xu, Peng; Zhao, Liang Y.; Sridharan, Kumar; Allen, Todd R.

    Grain boundary engineering (GBE) was performed on nickel-based alloy 690 by thermomechanical processing (TMP) to alter the grain boundary character distribution (GBCD). It was found that 5% and 35% thickness reduction in single and multiple steps followed by solution annealing and water quench yielded a high fraction of special boundaries. The total length fraction of the low ∑ CSL (coincidence site lattice) was as high as 87.2%. The grain boundary network was disrupted after the TMP treatment, and the average grain size calculated after exclusion of special twin boundaries can be as much as 5 times larger than the as-received (AR) sample. The GBE sample showed better oxidation resistance compared to the AR sample during the long term air oxidation. In the cyclic oxidation test, both AR and GBE samples showed a mass gain at the beginning of the test which was then followed by a mass loss. The mass change of GBE samples oscillated after the first couple cycles, while the AR sample became relatively stable. The oxide film most likely consists of duplex structures with one stable layer that was formed inside and one unstable layer that was formed outside. The stable inner layer was the protective layer and prevented alloy 690 from further oxidation.

  5. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Technical Reports Server (NTRS)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  6. Heat and mass transfer in a dissociated laminar boundary layer of air with consideration of the finite rate of chemical reaction

    NASA Technical Reports Server (NTRS)

    Oyegbesan, A. O.; Algermissen, J.

    1986-01-01

    A numerical investigation of heat and mass transfer in a dissociated laminar boundary layer of air on an isothermal flat plate is carried out for different degrees of cooling of the wall. A finite-difference chemical model is used to study elementary reactions involving NO2 and N2O. The analysis is based on equations of continuity, momentum, energy, conservation and state for the two-dimensional viscous flow of a reacting multicomponent mixtures. Attention is given to the effects of both catalyticity and noncatalyticity of the wall.

  7. Air sparging: Air-water mass transfer coefficients

    NASA Astrophysics Data System (ADS)

    Braida, Washington J.; Ong, Say Kee

    1998-12-01

    Experiments investigating the mass transfer of several dissolved volatile organic compounds (VOCs) across the air-water interface were conducted using a single-air- channel air-sparging system. Three different porous media were used in the study. Air velocities ranged from 0.2 cm s-1 to 2.5 cm s-1. The tortuosity factor for each porous medium and the air-water mass transfer coefficients were estimated by fitting experimental data to a one-dimensional diffusion model. The estimated mass transfer coefficients KG ranged from 1.79 × 10-3 cm min-1 to 3.85 × 10-2 cm min-1. The estimated lumped gas phase mass transfer coefficients KGa were found to be directly related to the air diffusivity of the VOC, air velocity, and particle size, and inversely related to the Henry's law constant of the VOCs. Of the four parameters investigated, the parameter that controlled or had a dominant effect on the lumped gas phase mass transfer coefficient was the air diffusivity of the VOC. Two empirical models were developed by correlating the Damkohler and the modified air phase Sherwood numbers with the air phase Peclet number, Henry's law constant, and the reduced mean particle size of porous media. The correlation developed in this study may be used to obtain better predictions of mass transfer fluxes for field conditions.

  8. Clear-air radar observations of the atmospheric boundary layer

    NASA Astrophysics Data System (ADS)

    Ince, Turker

    2001-10-01

    This dissertation presents the design and operation of a high-resolution frequency-modulated continuous-wave (FM- CW) radar system to study the structure and dynamics of clear-air turbulence in the atmospheric boundary layer (ABL). This sensitive radar can image the vertical structure of the ABL with both high spatial and temporal resolutions, and provide both qualitative information about the morphology of clear-air structures and quantitative information on the intensity of fluctuations in refractive-index of air. The principles of operation and the hardware and data acquisition characteristics of the radar are described in the dissertation. In October 1999, the radar participated in the Cooperative Atmosphere-Surface Exchange Study (CASES'99) Experiment to characterize the temporal structure and evolution of the boundary-layer features in both convective and stable conditions. The observed structures include clear-air convection, boundary layer evolution, gravity waves, Kelvin-Helmholtz instabilities, stably stratified layers, and clear-air turbulence. Many of the S-band radar images also show high- reflectivity returns from Rayleigh scatterers such as insects. An adaptive median filtering technique based on local statistics has, therefore, been developed to discriminate between Bragg and Rayleigh scattering in clear-air radar observations. The filter is tested on radar observations of clear air convection with comparison to two commonly used image processing techniques. The dissertation also examines the statistical mean of the radar-measured C2n for clear-air convection, and compares it with the theoretical predictions. The study also shows that the inversion height, local thickness of the inversion layer, and the height of the elevated atmospheric layers can be estimated from the radar reflectivity measurements. In addition, comparisons to the radiosonde-based height estimates are made. To examine the temporal and spatial structure of C2n , the dissertation

  9. Numerical investigation of implementation of air-earth boundary by acoustic-elastic boundary approach

    USGS Publications Warehouse

    Xu, Y.; Xia, J.; Miller, R.D.

    2007-01-01

    The need for incorporating the traction-free condition at the air-earth boundary for finite-difference modeling of seismic wave propagation has been discussed widely. A new implementation has been developed for simulating elastic wave propagation in which the free-surface condition is replaced by an explicit acoustic-elastic boundary. Detailed comparisons of seismograms with different implementations for the air-earth boundary were undertaken using the (2,2) (the finite-difference operators are second order in time and space) and the (2,6) (second order in time and sixth order in space) standard staggered-grid (SSG) schemes. Methods used in these comparisons to define the air-earth boundary included the stress image method (SIM), the heterogeneous approach, the scheme of modifying material properties based on transversely isotropic medium approach, the acoustic-elastic boundary approach, and an analytical approach. The method proposed achieves the same or higher accuracy of modeled body waves relative to the SIM. Rayleigh waves calculated using the explicit acoustic-elastic boundary approach differ slightly from those calculated using the SIM. Numerical results indicate that when using the (2,2) SSG scheme for SIM and our new method, a spatial step of 16 points per minimum wavelength is sufficient to achieve 90% accuracy; 32 points per minimum wavelength achieves 95% accuracy in modeled Rayleigh waves. When using the (2,6) SSG scheme for the two methods, a spatial step of eight points per minimum wavelength achieves 95% accuracy in modeled Rayleigh waves. Our proposed method is physically reasonable and, based on dispersive analysis of simulated seismographs from a layered half-space model, is highly accurate. As a bonus, our proposed method is easy to program and slightly faster than the SIM. ?? 2007 Society of Exploration Geophysicists.

  10. Boundary layer flow of air over water on a flat plate

    NASA Technical Reports Server (NTRS)

    Nelson, John; Alving, Amy E.; Joseph, Daniel D.

    1993-01-01

    A non-similar boundary layer theory for air blowing over a water layer on a flat plate is formulated and studied as a two-fluid problem in which the position of the interface is unknown. The problem is considered at large Reynolds number (based on x), away from the leading edge. A simple non-similar analytic solution of the problem is derived for which the interface height is proportional to x(sub 1/4) and the water and air flow satisfy the Blasius boundary layer equations, with a linear profile in the water and a Blasius profile in the air. Numerical studies of the initial value problem suggests that this asymptotic, non-similar air-water boundary layer solution is a global attractor for all initial conditions.

  11. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Windows and air ports in fire control boundaries. 116... CONSTRUCTION AND ARRANGEMENT Fire Protection § 116.433 Windows and air ports in fire control boundaries. (a) Windows or air ports must be of tempered or laminated glass of at least 6.5 millimeters (0.25 inches) in...

  12. Experimental Investigation of Soil and Atmospheric Conditions on the Momentum, Mass, and Thermal Boundary Layers Above the Land Atmosphere Interface

    NASA Astrophysics Data System (ADS)

    Trautz, A.; Smits, K. M.; Illangasekare, T. H.; Schulte, P.

    2014-12-01

    The purpose of this study is to investigate the impacts of soil conditions (i.e. soil type, saturation) and atmospheric forcings (i.e. velocity, temperature, relative humidity) on the momentum, mass, and temperature boundary layers. The atmospheric conditions tested represent those typically found in semi-arid and arid climates and the soil conditions simulate the three stages of evaporation. The data generated will help identify the importance of different soil conditions and atmospheric forcings with respect to land-atmospheric interactions which will have direct implications on future numerical studies investigating the effects of turbulent air flow on evaporation. The experimental datasets generated for this study were performed using a unique climate controlled closed-circuit wind tunnel/porous media facility located at the Center for Experimental Study of Subsurface Environmental Processes (CESEP) at the Colorado School of Mines. The test apparatus consisting of a 7.3 m long porous media tank and wind tunnel, were outfitted with a sensor network to carefully measure wind velocity, air and soil temperature, relative humidity, soil moisture, and soil air pressure. Boundary layer measurements were made between the heights of 2 and 500 mm above the soil tank under constant conditions (i.e. wind velocity, temperature, relative humidity). The soil conditions (e.g. soil type, soil moisture) were varied between datasets to analyze their impact on the boundary layers. Experimental results show that the momentum boundary layer is very sensitive to the applied atmospheric conditions and soil conditions to a much less extent. Increases in velocity above porous media leads to momentum boundary layer thinning and closely reflect classical flat plate theory. The mass and thermal boundary layers are directly dependent on both atmospheric and soil conditions. Air pressure within the soil is independent of atmospheric temperature and relative humidity - wind velocity and soil

  13. An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

    NASA Astrophysics Data System (ADS)

    Zander, R.; Messina, A.; Godek, M. L.

    2012-12-01

    The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

  14. On the Influence of Air Mass Origin on Low-Cloud Properties in the Southeast Atlantic

    NASA Astrophysics Data System (ADS)

    Fuchs, Julia; Cermak, Jan; Andersen, Hendrik; Hollmann, Rainer; Schwarz, Katharina

    2017-10-01

    This study investigates the impact of air mass origin and dynamics on cloud property changes in the Southeast Atlantic (SEA) during the biomass burning season. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget and thus prominent in climate system research. In this study, the thermodynamically stable SEA stratocumulus cover is observed not only as the result of local environmental conditions but also as connected to large-scale meteorology by the often neglected but important role of spatial origins of air masses entering this region. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a Hybrid Single-Particle Lagrangian Integrated Trajectory cluster analysis is conducted linking satellite observations of cloud properties (Spinning-Enhanced Visible and Infrared Imager), information on aerosol species (Monitoring Atmospheric Composition and Climate), and meteorological context (ERA-Interim reanalysis) to air mass clusters. It is found that a characteristic pattern of air mass origins connected to distinct synoptical conditions leads to marked cloud property changes in the southern part of the study area. Long-distance air masses are related to midlatitude weather disturbances that affect the cloud microphysics, especially in the southwestern subdomain of the study area. Changes in cloud effective radius are consistent with a boundary layer deepening and changes in lower tropospheric stability (LTS). In the southeastern subdomain cloud cover is controlled by a generally higher LTS, while air mass origin plays a minor role. This study leads to a better understanding of the dynamical drivers behind observed stratocumulus cloud properties in the SEA and frames potentially interesting conditions for aerosol-cloud interactions.

  15. A study of tornadic thunderstorm interactions with thermal boundaries

    NASA Technical Reports Server (NTRS)

    Maddox, R. A.; Hoxit, L. R.; Chappell, C. F.

    1980-01-01

    A study of tornadic thunderstorm interactions with thermal boundaries using a model of subcloud wind profiles is presented. Within a hot, moist, and conditionally unstable air mass, warm thermal advection and surface friction cause the winds to veer and increase with height, while within a cool, moist air mass cool thermal advection and friction combine to produce a wind profile that has maximum speeds near the surface and veers little with height. The spatial distribution of different wind profiles and moisture contents within the boundary layer may act together to maximize mesoscale moisture contents, convergence, and cyclonic vorticity within a narrow mixing zone along the thermal boundary.

  16. The Permian-Triassic boundary & mass extinction in China

    USGS Publications Warehouse

    Metcalfe, I.; Nicoll, R.S.; Mundil, R.; Foster, C.; Glen, J.; Lyons, J.; Xiaofeng, W.; Cheng-Yuan, W.; Renne, P.R.; Black, L.; Xun, Q.; Xiaodong, M.

    2001-01-01

    The first appearance of Hindeodus parvus (Kozur & Pjatakova) at the Permian-Triassic (P-T) GSSP level (base of Bed 27c) at Meishan is here confirmed. Hindeodus changxingensis Wang occurs from Beds 26 to 29 at Meishan and appears to be restricted to the narrow boundary interval immediately above the main mass extinction level in Bed 25. It is suggested that this species is therefore a valuable P-T boundary interval index taxon. Our collections from the Shangsi section confirm that the first occurrence of Hindeodus parvus in that section is about 5 in above the highest level from which a typical Permian fauna is recovered. This may suggest that that some section may be missing at Meishan. The age of the currently defined Permian-Triassic Boundary is estimated by our own studies and a reassessment of previous worker's data at c. 253 Ma, slightly older than our IDTIMS 206Pb/238U age of 252.5 ??0.3 Ma for Bed 28, just 8 cm above the GSSP boundary (Mundil et al., 2001). The age of the main mass extinction, at the base of Bed 25 at Meishan, is estimated at slightly older than 254 Ma based on an age of >254 Ma for the Bed 25 ash. Regardless of the absolute age of the boundary, it is evident that the claimed <165,000 y short duration for the negative carbon isotope excursion at the P-T boundary (Bowring et al., 1998) cannot be confirmed. Purportedly extraterrestrial fullerenes at the boundary (Hecker et al., 2001) have equivocal significance due to their chronostratigraphic non-uniqueness and their occurrence in a volcanic ash.

  17. Air Pressure Controlled Mass Measurement System

    NASA Astrophysics Data System (ADS)

    Zhong, Ruilin; Wang, Jian; Cai, Changqing; Yao, Hong; Ding, Jin'an; Zhang, Yue; Wang, Xiaolei

    Mass measurement is influenced by air pressure, temperature, humidity and other facts. In order to reduce the influence, mass laboratory of National Institute of Metrology, China has developed an air pressure controlled mass measurement system. In this system, an automatic mass comparator is installed in an airtight chamber. The Chamber is equipped with a pressure controller and associate valves, thus the air pressure can be changed and stabilized to the pre-set value, the preferred pressure range is from 200 hPa to 1100 hPa. In order to keep the environment inside the chamber stable, the display and control part of the mass comparator are moved outside the chamber, and connected to the mass comparator by feed-throughs. Also a lifting device is designed for this system which can easily lift up the upper part of the chamber, thus weights can be easily put inside the mass comparator. The whole system is put on a marble platform, and the temperature and humidity of the laboratory is very stable. The temperature, humidity, and carbon dioxide content inside the chamber are measured in real time and can be used to get air density. Mass measurement cycle from 1100 hPa to 200 hPa and back to 1100 hPa shows the effective of the system.

  18. Calculation of eddy viscosity in a compressible turbulent boundary layer with mass injection and chemical reaction, volume 1. [theoretical analysis

    NASA Technical Reports Server (NTRS)

    Omori, S.

    1973-01-01

    The turbulent kinetic energy equation is coupled with boundary layer equations to solve the characteristics of compressible turbulent boundary layers with mass injection and combustion. The Reynolds stress is related to the turbulent kinetic energy using the Prandtl-Wieghardt formulation. When a lean mixture of hydrogen and nitrogen is injected through a porous plate into the subsonic turbulent boundary layer of air flow and ignited by external means, the turbulent kinetic energy increases twice as much as that of noncombusting flow with the same mass injection rate of nitrogen. The magnitudes of eddy viscosity between combusting and noncombusting flows with injection, however, are almost the same due to temperature effects, while the distributions are different. The velocity profiles are significantly affected by combustion; that is, combustion alters the velocity profile as if the mass injection rate is increased, reducing the skin-friction as a result of a smaller velocity gradient at the wall. If pure hydrogen as a transpiration coolant is injected into a rocket nozzle boundary layer flow of combustion products, the temperature drops significantly across the boundary layer due to the high heat capacity of hydrogen. At a certain distance from the wall, hydrogen reacts with the combustion products, liberating an extensive amount of heat. The resulting large increase in temperature reduces the eddy viscosity in this region.

  19. Enhanced air pollution via aerosol-boundary layer feedback in China.

    PubMed

    Petäjä, T; Järvi, L; Kerminen, V-M; Ding, A J; Sun, J N; Nie, W; Kujansuu, J; Virkkula, A; Yang, X-Q; Fu, C B; Zilitinkevich, S; Kulmala, M

    2016-01-12

    Severe air pollution episodes have been frequent in China during the recent years. While high emissions are the primary reason for increasing pollutant concentrations, the ultimate cause for the most severe pollution episodes has remained unclear. Here we show that a high concentration of particulate matter (PM) will enhance the stability of an urban boundary layer, which in turn decreases the boundary layer height and consequently cause further increases in PM concentrations. We estimate the strength of this positive feedback mechanism by combining a new theoretical framework with ambient observations. We show that the feedback remains moderate at fine PM concentrations lower than about 200 μg m(-3), but that it becomes increasingly effective at higher PM loadings resulting from the combined effect of high surface PM emissions and massive secondary PM production within the boundary layer. Our analysis explains why air pollution episodes are particularly serious and severe in megacities and during the days when synoptic weather conditions stay constant.

  20. A database and tool for boundary conditions for regional air quality modeling: description and evaluation

    NASA Astrophysics Data System (ADS)

    Henderson, B. H.; Akhtar, F.; Pye, H. O. T.; Napelenok, S. L.; Hutzell, W. T.

    2013-09-01

    Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available observations are too sparse vertically to provide boundary information, particularly for ozone precursors, but global simulations can be used to generate spatially and temporally varying Lateral Boundary Conditions (LBC). This study presents a public database of global simulations designed and evaluated for use as LBC for air quality models (AQMs). The database covers the contiguous United States (CONUS) for the years 2000-2010 and contains hourly varying concentrations of ozone, aerosols, and their precursors. The database is complimented by a tool for configuring the global results as inputs to regional scale models (e.g., Community Multiscale Air Quality or Comprehensive Air quality Model with extensions). This study also presents an example application based on the CONUS domain, which is evaluated against satellite retrieved ozone vertical profiles. The results show performance is largely within uncertainty estimates for the Tropospheric Emission Spectrometer (TES) with some exceptions. The major difference shows a high bias in the upper troposphere along the southern boundary in January. This publication documents the global simulation database, the tool for conversion to LBC, and the fidelity of concentrations on the boundaries. This documentation is intended to support applications that require representation of long-range transport of air pollutants.

  1. Planck scale boundary conditions and the Higgs mass

    NASA Astrophysics Data System (ADS)

    Holthausen, Martin; Lim, Kher Sham; Lindner, Manfred

    2012-02-01

    If the LHC does only find a Higgs boson in the low mass region and no other new physics, then one should reconsider scenarios where the Standard Model with three right-handed neutrinos is valid up to Planck scale. We assume in this spirit that the Standard Model couplings are remnants of quantum gravity which implies certain generic boundary conditions for the Higgs quartic coupling at Planck scale. This leads to Higgs mass predictions at the electroweak scale via renormalization group equations. We find that several physically well motivated conditions yield a range of Higgs masses from 127 - 142 GeV. We also argue that a random quartic Higgs coupling at the Planck scale favours M H > 150 GeV, which is clearly excluded. We discuss also the prospects for differentiating different boundary conditions imposed for λ( M pl) at the LHC. A striking example is M H = 127 ± 5 GeV corresponding to λ( M pl) = 0, which would imply that the quartic Higgs coupling at the electroweak scale is entirely radiatively generated.

  2. Effect of Dynamic Sector Boundary Changes on Air Traffic Controllers

    NASA Technical Reports Server (NTRS)

    Jung, Jaewoo; Lee, Paul; Kessell, Angela; Homola, Jeff; Zelinski, Shannon

    2010-01-01

    The effect of dynamic sector boundary changes on air traffic controller workload was investigated with data from a human-in-the-loop simulation. Multiple boundary changes were made during simulated operations, and controller rating of workload was recorded. Analysis of these data showed an increase of 16.9% in controller workload due to boundary changes. This increased workload was correlated with the number of aircraft handoffs and change in sector volume. There was also a 12.7% increase in average workload due to the changed sector design after boundary changes. This increase was correlated to traffic flow crossing points getting closer to sector boundaries and an increase in the number of flights with short dwell time in a sector. This study has identified some of the factors that affect controller workload when sector boundaries are changed, but more research is needed to better understand their relationships.

  3. Impact of Bay-Breeze Circulations on Surface Air Quality and Boundary Layer Export

    NASA Technical Reports Server (NTRS)

    Loughner, Christopher P.; Tzortziou, Maria; Follette-Cook, Melanie; Pickering, Kenneth E.; Goldberg, Daniel; Satam, Chinmay; Weinheimer, Andrew; Crawford, James H.; Knapp, David J.; Montzka, Denise D.; hide

    2014-01-01

    Meteorological and air-quality model simulations are analyzed alongside observations to investigate the role of the Chesapeake Bay breeze on surface air quality, pollutant transport, and boundary layer venting. A case study was conducted to understand why a particular day was the only one during an 11-day ship-based field campaign on which surface ozone was not elevated in concentration over the Chesapeake Bay relative to the closest upwind site and why high ozone concentrations were observed aloft by in situ aircraft observations. Results show that southerly winds during the overnight and early-morning hours prevented the advection of air pollutants from the Washington, D.C., and Baltimore, Maryland, metropolitan areas over the surface waters of the bay. A strong and prolonged bay breeze developed during the late morning and early afternoon along the western coastline of the bay. The strength and duration of the bay breeze allowed pollutants to converge, resulting in high concentrations locally near the bay-breeze front within the Baltimore metropolitan area, where they were then lofted to the top of the planetary boundary layer (PBL). Near the top of the PBL, these pollutants were horizontally advected to a region with lower PBL heights, resulting in pollution transport out of the boundary layer and into the free troposphere. This elevated layer of air pollution aloft was transported downwind into New England by early the following morning where it likely mixed down to the surface, affecting air quality as the boundary layer grew.

  4. Thickened boundary layer theory for air film drag reduction on a van body surface

    NASA Astrophysics Data System (ADS)

    Xie, Xiaopeng; Cao, Lifeng; Huang, Heng

    2018-05-01

    To elucidate drag reduction mechanism on a van body surface under air film condition, a thickened boundary layer theory was proposed and a frictional resistance calculation model of the van body surface was established. The frictional resistance on the van body surface was calculated with different parameters of air film thickness. In addition, the frictional resistance of the van body surface under the air film condition was analyzed by computational fluid dynamics (CFD) simulation and different air film states that influenced the friction resistance on the van body surface were discussed. As supported by the CFD simulation results, the thickened boundary layer theory may provide reference for practical application of air film drag reduction on a van body surface.

  5. Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

    NASA Astrophysics Data System (ADS)

    Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

    2014-08-01

    Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

  6. Influence of Boundary Conditions on Simulated U.S. Air Quality

    EPA Science Inventory

    One of the key inputs to regional-scale photochemical models frequently used in air quality planning and forecasting applications are chemical boundary conditions representing background pollutant concentrations originating outside the regional modeling domain. A number of studie...

  7. Influence of the characteristics of atmospheric boundary layer on the vertical distribution of air pollutant in China's Yangtze River Delta

    NASA Astrophysics Data System (ADS)

    Wang, Chenggang; Cao, Le

    2016-04-01

    Air pollution occurring in the atmospheric boundary layer is a kind of weather phenomenon which decreases the visibility of the atmosphere and results in poor air quality. Recently, the occurrence of the heavy air pollution events has become more frequent all over Asia, especially in Mid-Eastern China. In December 2015, the most severe air pollution in recorded history of China occurred in the regions of Yangtze River Delta and Beijing-Tianjin-Hebei. More than 10 days of severe air pollution (Air Quality Index, AQI>200) appeared in many large cities of China such as Beijing, Tianjin, Shijiazhuang and Baoding. Thus, the research and the management of the air pollution has attracted most attentions in China. In order to investigate the formation, development and dissipation of the air pollutions in China, a field campaign has been conducted between January 1, 2015 and January 28, 2015 in Yangtze River Delta of China, aiming at a intensive observation of the vertical structure of the air pollutants in the atmospheric boundary layer during the time period with heavy pollution. In this study, the observation data obtained in the field campaign mentioned above is analyzed. The characteristics of the atmospheric boundary layer and the vertical distribution of air pollutants in the city Dongshan located in the center of Lake Taihu are shown and discussed in great detail. It is indicated that the stability of the boundary layer is the strongest during the nighttime and the early morning of Dongshan. Meanwhile, the major air pollutants, PM2.5 and PM10 in the boundary layer, reach their maximum values, 177.1μg m-3 and 285μg m-3 respectively. The convective boundary layer height in the observations ranges from approximately 700m to 1100m. It is found that the major air pollutants tend to be confined in a relatively shallow boundary layer, which represents that the boundary layer height is the dominant factor for controlling the vertical distribution of the air pollutants. In

  8. The Effective Mass of a Ball in the Air

    ERIC Educational Resources Information Center

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  9. Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

    NASA Astrophysics Data System (ADS)

    Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

    2015-10-01

    We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

  10. Delimitation of air space and outer space - Is such a boundary needed now?

    NASA Technical Reports Server (NTRS)

    Hosenball, S. N.

    1983-01-01

    A discussion is presented of the question of establishing a boundary between air space and outer space. Four theories and approaches for establishing a delimitation between air space and outer space are examined. Spatial approaches include demarcation based on the division of the atmosphere into layers, demarcation based on aerodynamic characteristics of flight instrumentalities (von Karman Line), demarcation according to the lowest perigee of an orbiting satellite, and demarcation based upon the earth's gravitational effects. The functionalist approach is based on the delimitation or definition of the air space/outer space regime by the purpose and activities for which an object is designed in air space or outer space. The arbitrarist approach is supported by those who wish to draw an arbitrary line between air space and outer space. It is proposed that a pragmatist approach will be more useful than the other three approaches. The pragmatist approach advocates not establishing a boundary between air space and outer space at the present time or in the immediate future. It is argued that there are at present no serious problems that can be resolved by the definition/delimitation of air space and outer space.

  11. Sea-air boundary meteorological sensor

    NASA Astrophysics Data System (ADS)

    Barbosa, Jose G.

    2015-05-01

    The atmospheric environment can significantly affect radio frequency and optical propagation. In the RF spectrum refraction and ducting can degrade or enhance communications and radar coverage. Platforms in or beneath refractive boundaries can exploit the benefits or suffer the effects of the atmospheric boundary layers. Evaporative ducts and surface-base ducts are of most concern for ocean surface platforms and evaporative ducts are almost always present along the sea-air interface. The atmospheric environment also degrades electro-optical systems resolution and visibility. The atmospheric environment has been proven not to be uniform and under heterogeneous conditions substantial propagation errors may be present for large distances from homogeneous models. An accurate and portable atmospheric sensor to profile the vertical index of refraction is needed for mission planning, post analysis, and in-situ performance assessment. The meteorological instrument used in conjunction with a radio frequency and electro-optical propagation prediction tactical decision aid tool would give military platforms, in real time, the ability to make assessments on communication systems propagation ranges, radar detection and vulnerability ranges, satellite communications vulnerability, laser range finder performance, and imaging system performance predictions. Raman lidar has been shown to be capable of measuring the required atmospheric parameters needed to profile the atmospheric environment. The atmospheric profile could then be used as input to a tactical decision aid tool to make propagation predictions.

  12. Influence of trans-boundary air pollution from China on multi-day high PM10 episodes in Seoul, Korea

    NASA Astrophysics Data System (ADS)

    Oh, H. R.; Ho, C. H.; Kim, J.; Chen, D.; Lee, S.; Choi, Y. S.; Chang, L. S.; Song, C. K.

    2014-12-01

    Air quality problems have become a serious global issue as it causes over 3 million deaths per year all over the world. With generations of massive air pollutants in China, the effects of trans-boundary transports of air pollutants on human health have become a serious international concern in East Asia. However, only a limited number of studies are available for providing scientific evidences for quantifying the sources and transports of air pollutants over major countries in East Asia. Here, it is shown that particulate matters originated from China played major role in the occurrence of multi-day (≥ 4 days) severe air pollution episodes in Seoul, Korea, in which the concentration of particulate matter of diameters ≤ 10 μm exceeds 100 μg m-3. Observations show that these multi-day severe air quality episodes occur when a strong high-pressure system resides over the eastern China - Korea region. Such a weather condition confines air pollutants within the atmospheric boundary layer and spread them by slow westerlies within the boundary layer from China into the neighboring countries. Understanding such dynamical processes is a key for advancing the predictability of trans-boundary air pollutants and their health impacts in East Asia as well as developing international measures to improve air quality for the region.

  13. Extended period of K/T boundary mass extinction in the marine realm

    NASA Technical Reports Server (NTRS)

    Keller, G.

    1988-01-01

    The Cretaceous/Tertiary (K/T) boundary mass extinction has been widely recognized as a nearly instantaneous catastrophy among marine plankton such as foraminifera. However, the suddenness of this extinction event may have been overemphasized because most pelagic K/T boundary sequences are stratigraphically incomplete and generally lack the earliest Tertiary (Zones P0 and P1a) either due to carbonate dissolution and/or non-deposition. Stratigraphically complete sections appear to be restricted to continental shelf regions with high sedimentation rates and deposition well above the CCD. Such sections have been recovered from El Kef, Tunisia (1) and Brazos River, Texas. Quantitative foraminiferal analysis of these sections indicate an extinction pattern beginning below the K/T boundary and ending above the boundary. These data imply that the mass extinction event was not geologically instantaneous, but occurred over an extended period of time. Evidence supporting this conclusion is discussed.

  14. Dependence of air masses type on PBL vertical structure retrieved at the Mace Head station during EUCAARI campaign.

    NASA Astrophysics Data System (ADS)

    Milroy, Conor; Martucci, Giovanni; O'Dowd, Colin

    2010-05-01

    During the EUCAARI Intensive Observing Period held at the Mace Head GAW station from mid-May to mid-June, 2008, the PBL depth has been continuously measured by two ceilometers (Vaisala CL31 and Jenoptik CHM15K) and a microwave radiometer (RPG-HATPRO). The Lidar-Ceilometer, through the gradients in aerosol backscatter profiles, and the microwave profiler, through gradients in the specific humidity profiles, were used to remotely-sense the boundary layer structure. An automatic, newly developed Temporal Height-Tracking (THT) algorithm (Martucci et al., 2010) have been applied to both type of instruments data to retrieve the 2-layered structure of the local marine boundary layer. The two layers are defined as a lower, well mixed layer, i.e. the surface mixed layer, and the layer occupying the region below the free Troposphere inversion, i.e. the decoupled residual or convective layer. A categorization of the incoming air masses has been performed based on their origins and been used to asses the correlation with the PBL depths. The study confirmed the dependence of PBL vertical structure on different air masses and different type of advected aerosol.

  15. A database and tool for boundary conditions for regional air quality modeling: description and evaluation

    NASA Astrophysics Data System (ADS)

    Henderson, B. H.; Akhtar, F.; Pye, H. O. T.; Napelenok, S. L.; Hutzell, W. T.

    2014-02-01

    Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available observations are too sparse vertically to provide boundary information, particularly for ozone precursors, but global simulations can be used to generate spatially and temporally varying lateral boundary conditions (LBC). This study presents a public database of global simulations designed and evaluated for use as LBC for air quality models (AQMs). The database covers the contiguous United States (CONUS) for the years 2001-2010 and contains hourly varying concentrations of ozone, aerosols, and their precursors. The database is complemented by a tool for configuring the global results as inputs to regional scale models (e.g., Community Multiscale Air Quality or Comprehensive Air quality Model with extensions). This study also presents an example application based on the CONUS domain, which is evaluated against satellite retrieved ozone and carbon monoxide vertical profiles. The results show performance is largely within uncertainty estimates for ozone from the Ozone Monitoring Instrument and carbon monoxide from the Measurements Of Pollution In The Troposphere (MOPITT), but there were some notable biases compared with Tropospheric Emission Spectrometer (TES) ozone. Compared with TES, our ozone predictions are high-biased in the upper troposphere, particularly in the south during January. This publication documents the global simulation database, the tool for conversion to LBC, and the evaluation of concentrations on the boundaries. This documentation is intended to support applications that require representation of long-range transport of air pollutants.

  16. Atmospheric Boundary Layer Modeling for Combined Meteorology and Air Quality Systems

    EPA Science Inventory

    Atmospheric Eulerian grid models for mesoscale and larger applications require sub-grid models for turbulent vertical exchange processes, particularly within the Planetary Boundary Layer (PSL). In combined meteorology and air quality modeling systems consistent PSL modeling of wi...

  17. The inducement of planetary boundary layer mass convergence associated with varying vorticity beneath tropospheric wind maximum

    NASA Technical Reports Server (NTRS)

    Johnson, D. R.

    1984-01-01

    The effects of the vorticity distribution are applied to study planetary boundary layer mass convergence beneath free tropospheric wind maximum. For given forcing by viscous and pressure gradient forces beneath a wind maximum, boundary layer cross stream mass transport is increased by anticyclonic vorticity on the right flank and decreased by cyclonic vorticity on the left flank. Such frictionally forced mass transport induces boundary layer mass convergence beneath the relative wind maximum. This result is related to the empirical rule that the most intense convection and severe weather frequently develop beneath the 500 mb zero relative vorticity isopleth.

  18. Seismic Characterization of Oceanic Water Masses, Water Mass Boundaries, and Mesoscale Eddies SE of New Zealand

    NASA Astrophysics Data System (ADS)

    Gorman, Andrew R.; Smillie, Matthew W.; Cooper, Joanna K.; Bowman, M. Hamish; Vennell, Ross; Holbrook, W. Steven; Frew, Russell

    2018-02-01

    The Subtropical and Subantarctic Fronts, which separate Subtropical, Subantarctic, and Antarctic Intermediate Waters, are diverted to the south of New Zealand by the submerged continental landmass of Zealandia. In the upper ocean of this region, large volumes of dissolved or suspended material are intermittently transported across the Subtropical Front; however, the mechanisms of such transport processes are enigmatic. Understanding these oceanic boundaries in three dimensions generally depends on measurements collected from stationary vessels and moorings. The details of these data sets, which are critical for understanding how water masses interact and mix at the fine-scale (<10 m) to mesoscale (10-100 km), are inadequately constrained due to resolution considerations. Southeast of New Zealand, high-resolution seismic reflection images of oceanic water masses have been produced using petroleum industry data. These seismic sections clearly show three main water masses, the boundary zones (fronts) between them, and associated thermohaline fine structure that may be related to the mixing of water masses in this region. Interpretations of the data suggest that the Subtropical Front in this region is a landward-dipping zone, with a width that can vary between 20 and 40 km. The boundary zone between Subantarctic Waters and the underlying Antarctic Intermediate Waters is also observed to dip landward. Several isolated lenses have been identified on the three data sets, ranging in size from 9 to 30 km in diameter. These lenses are interpreted to be mesoscale eddies that form at relatively shallow depths along the south side of the Subtropical Front.

  19. A Database and Tool for Boundary Conditions for Regional Air Quality Modeling: Description and Evaluation

    EPA Science Inventory

    Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available ob...

  20. Influence of Boundary Conditions on Regional Air Quality Simulations—Analysis of AQMEII Phase 3 Results

    EPA Science Inventory

    Chemical boundary conditions are a key input to regional-scale photochemical models. In this study, performed during the third phase of the Air Quality Model Evaluation International Initiative (AQMEII3), we perform annual simulations over North America with chemical boundary con...

  1. Detecting kinematic boundary surfaces in phase space: particle mass measurements in SUSY-like events

    NASA Astrophysics Data System (ADS)

    Debnath, Dipsikha; Gainer, James S.; Kilic, Can; Kim, Doojin; Matchev, Konstantin T.; Yang, Yuan-Pao

    2017-06-01

    We critically examine the classic endpoint method for particle mass determination, focusing on difficult corners of parameter space, where some of the measurements are not independent, while others are adversely affected by the experimental resolution. In such scenarios, mass differences can be measured relatively well, but the overall mass scale remains poorly constrained. Using the example of the standard SUSY decay chain \\tilde{q}\\to {\\tilde{χ}}_2^0\\to \\tilde{ℓ}\\to {\\tilde{χ}}_1^0 , we demonstrate that sensitivity to the remaining mass scale parameter can be recovered by measuring the two-dimensional kinematical boundary in the relevant three-dimensional phase space of invariant masses squared. We develop an algorithm for detecting this boundary, which uses the geometric properties of the Voronoi tessellation of the data, and in particular, the relative standard deviation (RSD) of the volumes of the neighbors for each Voronoi cell in the tessellation. We propose a new observable, \\overline{Σ} , which is the average RSD per unit area, calculated over the hypothesized boundary. We show that the location of the \\overline{Σ} maximum correlates very well with the true values of the new particle masses. Our approach represents the natural extension of the one-dimensional kinematic endpoint method to the relevant three dimensions of invariant mass phase space.

  2. Crossing turbulent boundaries: interfacial flux in environmental flows.

    PubMed

    Grant, Stanley B; Marusic, Ivan

    2011-09-01

    Advances in the visualization and prediction of turbulence are shedding new light on mass transfer in the turbulent boundary layer. These discoveries have important implications for many topics in environmental science and engineering, from the transport of earth-warming CO2 across the sea-air interface, to nutrient processing and sediment erosion in rivers, lakes, and the ocean, to pollutant removal in water and wastewater treatment systems. In this article we outline current understanding of turbulent boundary layer flows, with particular focus on coherent turbulence and its impact on mass transport across the sediment-water interface in marine and freshwater systems.

  3. REDEFINING THE BOUNDARIES OF INTERPLANETARY CORONAL MASS EJECTIONS FROM OBSERVATIONS AT THE ECLIPTIC PLANE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cid, C.; Palacios, J.; Saiz, E.

    2016-09-01

    On 2015 January 6–7, an interplanetary coronal mass ejection (ICME) was observed at L1. This event, which can be associated with a weak and slow coronal mass ejection, allows us to discuss the differences between the boundaries of the magnetic cloud and the compositional boundaries. A fast stream from a solar coronal hole surrounding this ICME offers a unique opportunity to check the boundaries’ process definition and to explain differences between them. Using Wind and ACE data, we perform a complementary analysis involving compositional, magnetic, and kinematic observations providing relevant information regarding the evolution of the ICME as travelling awaymore » from the Sun. We propose erosion, at least at the front boundary of the ICME, as the main reason for the difference between the boundaries, and compositional signatures as the most precise diagnostic tool for the boundaries of ICMEs.« less

  4. Vehicle cabin cooling system for capturing and exhausting heated boundary layer air from inner surfaces of solar heated windows

    DOEpatents

    Farrington, Robert B.; Anderson, Ren

    2001-01-01

    The cabin cooling system includes a cooling duct positioned proximate and above upper edges of one or more windows of a vehicle to exhaust hot air as the air is heated by inner surfaces of the windows and forms thin boundary layers of heated air adjacent the heated windows. The cabin cooling system includes at least one fan to draw the hot air into the cooling duct at a flow rate that captures the hot air in the boundary layer without capturing a significant portion of the cooler cabin interior air and to discharge the hot air at a point outside the vehicle cabin, such as the vehicle trunk. In a preferred embodiment, the cooling duct has a cross-sectional area that gradually increases from a distal point to a proximal point to the fan inlet to develop a substantially uniform pressure drop along the length of the cooling duct. Correspondingly, this cross-sectional configuration develops a uniform suction pressure and uniform flow rate at the upper edge of the window to capture the hot air in the boundary layer adjacent each window.

  5. Detecting kinematic boundary surfaces in phase space: particle mass measurements in SUSY-like events

    DOE PAGES

    Debnath, Dipsikha; Gainer, James S.; Kilic, Can; ...

    2017-06-19

    We critically examine the classic endpoint method for particle mass determination, focusing on difficult corners of parameter space, where some of the measurements are not independent, while others are adversely affected by the experimental resolution. In such scenarios, mass differences can be measured relatively well, but the overall mass scale remains poorly constrained. Using the example of the standard SUSY decay chain q ~→χ ~ 0 2→ℓ ~→χ ~ 0 1 , we demonstrate that sensitivity to the remaining mass scale parameter can be recovered by measuring the two-dimensional kinematical boundary in the relevant three-dimensional phase space of invariant massesmore » squared. We develop an algorithm for detecting this boundary, which uses the geometric properties of the Voronoi tessellation of the data, and in particular, the relative standard deviation (RSD) of the volumes of the neighbors for each Voronoi cell in the tessellation. We propose a new observable, Σ¯ , which is the average RSD per unit area, calculated over the hypothesized boundary. We show that the location of the Σ¯ maximum correlates very well with the true values of the new particle masses. Our approach represents the natural extension of the one-dimensional kinematic endpoint method to the relevant three dimensions of invariant mass phase space.« less

  6. Detecting kinematic boundary surfaces in phase space: particle mass measurements in SUSY-like events

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Debnath, Dipsikha; Gainer, James S.; Kilic, Can

    We critically examine the classic endpoint method for particle mass determination, focusing on difficult corners of parameter space, where some of the measurements are not independent, while others are adversely affected by the experimental resolution. In such scenarios, mass differences can be measured relatively well, but the overall mass scale remains poorly constrained. Using the example of the standard SUSY decay chain q ~→χ ~ 0 2→ℓ ~→χ ~ 0 1 , we demonstrate that sensitivity to the remaining mass scale parameter can be recovered by measuring the two-dimensional kinematical boundary in the relevant three-dimensional phase space of invariant massesmore » squared. We develop an algorithm for detecting this boundary, which uses the geometric properties of the Voronoi tessellation of the data, and in particular, the relative standard deviation (RSD) of the volumes of the neighbors for each Voronoi cell in the tessellation. We propose a new observable, Σ¯ , which is the average RSD per unit area, calculated over the hypothesized boundary. We show that the location of the Σ¯ maximum correlates very well with the true values of the new particle masses. Our approach represents the natural extension of the one-dimensional kinematic endpoint method to the relevant three dimensions of invariant mass phase space.« less

  7. The air quality and health impacts of domestic trans-boundary pollution in various regions of China.

    PubMed

    Gu, Y; Yim, S H L

    2016-12-01

    Air pollution is one of the most pressing environmental problems in China. Literature has reported that outdoor air pollution leads to adverse health problems every year in China. Recent measurement studies found the important regional nature of particulates in China. Trans-boundary air pollution within China has yet to be fully understood. This study aimed to comprehensively understand the processes of domestic trans-boundary air pollution in China and to apportion the impacts of emissions in different regions on air quality and public health. We applied a state-of-the-art air quality model to simulate air quality in China and then adapted a form of integrated concentration-response function for China to estimate the resultant amount of premature mortality due to exposures to PM 2.5 . Our findings show that domestic trans-boundary impacts (TBI), on average, account for 27% of the total PM 2.5 in China. We estimated that outdoor air pollution caused ~870,000 (95% CI: 130,000-1500,000) premature mortalities in China in 2010, of which on average 18% are attributed to TBI. Among all the regions, North China is the largest contributor to TBI due to 41% of the health impacts of its emissions occurring in other regions. Taiwan (TW) is the smallest contributor to TBI occurring in China, contributing 2% of the national TBI, while TBI causes 22% of the premature mortalities due to outdoor air pollution in TW. Our findings pinpoint the significant impacts of TBI on public health in China, indicating the need for cross-region cooperation to mitigate the air quality impacts and the nation's resultant health problems. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Localised boundary air layer and clothing evaporative resistances for individual body segments.

    PubMed

    Wang, Faming; del Ferraro, Simona; Lin, Li-Yen; Sotto Mayor, Tiago; Molinaro, Vincenzo; Ribeiro, Miguel; Gao, Chuansi; Kuklane, Kalev; Holmér, Ingvar

    2012-01-01

    Evaporative resistance is an important parameter to characterise clothing thermal comfort. However, previous work has focused mainly on either total static or dynamic evaporative resistance. There is a lack of investigation of localised clothing evaporative resistance. The objective of this study was to study localised evaporative resistance using sweating thermal manikins. The individual and interaction effects of air and body movements on localised resultant evaporative resistance were examined in a strict protocol. The boundary air layer's localised evaporative resistance was investigated on nude sweating manikins at three different air velocity levels (0.18, 0.48 and 0.78 m/s) and three different walking speeds (0, 0.96 and 1.17 m/s). Similarly, localised clothing evaporative resistance was measured on sweating manikins at three different air velocities (0.13, 0.48 and 0.70 m/s) and three walking speeds (0, 0.96 and 1.17 m/s). Results showed that the wind speed has distinct effects on local body segments. In contrast, walking speed brought much more effect on the limbs, such as thigh and forearm, than on body torso, such as back and waist. In addition, the combined effect of body and air movement on localised evaporative resistance demonstrated that the walking effect has more influence on the extremities than on the torso. Therefore, localised evaporative resistance values should be provided when reporting test results in order to clearly describe clothing local moisture transfer characteristics. Localised boundary air layer and clothing evaporative resistances are essential data for clothing design and assessment of thermal comfort. A comprehensive understanding of the effects of air and body movement on localised evaporative resistance is also necessary by both textile and apparel researchers and industry.

  9. Impact of chemical lateral boundary conditions in a regional air quality forecast model on surface ozone predictions during stratospheric intrusions

    NASA Astrophysics Data System (ADS)

    Pendlebury, Diane; Gravel, Sylvie; Moran, Michael D.; Lupu, Alexandru

    2018-02-01

    A regional air quality forecast model, GEM-MACH, is used to examine the conditions under which a limited-area air quality model can accurately forecast near-surface ozone concentrations during stratospheric intrusions. Periods in 2010 and 2014 with known stratospheric intrusions over North America were modelled using four different ozone lateral boundary conditions obtained from a seasonal climatology, a dynamically-interpolated monthly climatology, global air quality forecasts, and global air quality reanalyses. It is shown that the mean bias and correlation in surface ozone over the course of a season can be improved by using time-varying ozone lateral boundary conditions, particularly through the correct assignment of stratospheric vs. tropospheric ozone along the western lateral boundary (for North America). Part of the improvement in surface ozone forecasts results from improvements in the characterization of near-surface ozone along the lateral boundaries that then directly impact surface locations near the boundaries. However, there is an additional benefit from the correct characterization of the location of the tropopause along the western lateral boundary such that the model can correctly simulate stratospheric intrusions and their associated exchange of ozone from stratosphere to troposphere. Over a three-month period in spring 2010, the mean bias was seen to improve by as much as 5 ppbv and the correlation by 0.1 depending on location, and on the form of the chemical lateral boundary condition.

  10. Air Entrainment and Surface Ripples in a Turbulent Ship Hull Boundary Layer

    NASA Astrophysics Data System (ADS)

    Masnadi, Naeem; Erinin, Martin; Duncan, James H.

    2017-11-01

    The air entrainment and free-surface fluctuations caused by the interaction of a free surface and the turbulent boundary layer of a vertical surface-piercing plate is studied experimentally. In this experiment, a meter-wide stainless steel belt travels horizontally in a loop around two rollers with vertically oriented axes. This belt device is mounted inside a large water tank with the water level set just below the top edge of the belt. The belt, rollers, and supporting frame are contained within a sheet metal box to keep the device dry except for one 6-meter-long straight test section. The belt is accelerated suddenly from rest until reaching constant speed in order to create a temporally evolving boundary layer analogous to the spatially evolving boundary layer that would exist along a surface-piercing towed flat plate. Surface ripples are measured using a cinematic laser-induced fluorescence technique with the laser sheet oriented parallel or normal to the belt surface. Air entrainment events and bubble motions are recorded from underneath the water surface using a stereo imaging system. Measurements of small bubbles, that tend to stay submerged for a longer time, are planned via a high-speed digital in-line holographic system. The support of the Office of Naval Research is gratefully acknowledged.

  11. Deriving realistic source boundary conditions for a CFD simulation of concentrations in workroom air.

    PubMed

    Feigley, Charles E; Do, Thanh H; Khan, Jamil; Lee, Emily; Schnaufer, Nicholas D; Salzberg, Deborah C

    2011-05-01

    Computational fluid dynamics (CFD) is used increasingly to simulate the distribution of airborne contaminants in enclosed spaces for exposure assessment and control, but the importance of realistic boundary conditions is often not fully appreciated. In a workroom for manufacturing capacitors, full-shift samples for isoamyl acetate (IAA) were collected for 3 days at 16 locations, and velocities were measured at supply grills and at various points near the source. Then, velocity and concentration fields were simulated by 3-dimensional steady-state CFD using 295K tetrahedral cells, the k-ε turbulence model, standard wall function, and convergence criteria of 10(-6) for all scalars. Here, we demonstrate the need to represent boundary conditions accurately, especially emission characteristics at the contaminant source, and to obtain good agreement between observations and CFD results. Emission rates for each day were determined from six concentrations measured in the near field and one upwind using an IAA mass balance. The emission was initially represented as undiluted IAA vapor, but the concentrations estimated using CFD differed greatly from the measured concentrations. A second set of simulations was performed using the same IAA emission rates but a more realistic representation of the source. This yielded good agreement with measured values. Paying particular attention to the region with highest worker exposure potential-within 1.3 m of the source center-the air speed and IAA concentrations estimated by CFD were not significantly different from the measured values (P = 0.92 and P = 0.67, respectively). Thus, careful consideration of source boundary conditions greatly improved agreement with the measured values.

  12. Sorption-induced effects of humic substances on mass transfer of organic pollutants through aqueous diffusion boundary layers: the example of water/air exchange.

    PubMed

    Ramus, Ksenia; Kopinke, Frank-Dieter; Georgi, Anett

    2012-02-21

    This study examines the effect of dissolved humic substances (DHS) on the rate of water-gas exchange of organic compounds under conditions where diffusion through the aqueous boundary layer is rate-determining. A synthetic surfactant was applied for comparison. Mass-transfer coefficients were determined from the rate of depletion of the model compounds by means of an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution. In addition, experiments with continuous passive dosing of analytes into the water phase were conducted to simulate a system where thermodynamic activity of the chemical in the aqueous phase is identical in the presence and absence of DHS. The experimental results show that DHS and surfactants can affect water-gas exchange rates by the superposition of two mechanisms: (1) hydrodynamic effects due to surface film formation ("surface smoothing"), and (2) sorption-induced effects. Whether sorption accelerates or retards mass transfer depends on its effect on the thermodynamic activity of the pollutant in the aqueous phase. Mass transfer will be retarded if the activity (or freely dissolved concentration) of the pollutant is decreased due to sorption. If it remains unchanged (e.g., due to fast equilibration with a sediment acting as a large source phase), then DHS and surfactant micelles can act as an additional shuttle for the pollutants, enhancing the flux through the boundary layer.

  13. Air Quality and Meteorological Boundary Conditions during the MCMA-2003 Field Campaign

    NASA Astrophysics Data System (ADS)

    Sosa, G.; Arriaga, J.; Vega, E.; Magaña, V.; Caetano, E.; de Foy, B.; Molina, L. T.; Molina, M. J.; Ramos, R.; Retama, A.; Zaragoza, J.; Martínez, A. P.; Márquez, C.; Cárdenas, B.; Lamb, B.; Velasco, E.; Allwine, E.; Pressley, S.; Westberg, H.; Reyes, R.

    2004-12-01

    A comprehensive field campaign to characterize photochemical smog in the Mexico City Metropolitan Area (MCMA) was conducted during April 2003. An important number of equipment was deployed all around the urban core and its surroundings to measure gas and particles composition from the various sources and receptor sites. In addition to air quality measurements, meteorology variables were also taken by regular weather meteorological stations, tethered balloons, radiosondes, sodars and lidars. One important issue with regard to the field campaign was the characterization of the boundary conditions in order to feed meteorological and air quality models. Four boundary sites were selected to measure continuously criteria pollutants, VOC and meteorological variables at surface level. Vertical meteorological profiles were measured at three other sites : radiosondes in Tacubaya site were launched every six hours daily; tethered balloons were launched at CENICA and FES-Cuautitlan sites according to the weather conditions, and one sodar was deployed at UNAM site in the south of the city. Additionally to these measurements, two fixed meteorological monitoring networks deployed along the city were available to complement these measurements. In general, we observed that transport of pollutants from the city to the boundary sites changes every day, according to the coupling between synoptic and local winds. This effect were less important at elevated sites such as Cerro de la Catedral and ININ, where synoptic wind were more dominant during the field campaign. Also, local sources nearby boundary sites hide the influence of pollution coming from the city some days, particularly at the La Reforma site.

  14. Boundary element analyses for sound transmission loss of panels.

    PubMed

    Zhou, Ran; Crocker, Malcolm J

    2010-02-01

    The sound transmission characteristics of an aluminum panel and two composite sandwich panels were investigated by using two boundary element analyses. The effect of air loading on the structural behavior of the panels is included in one boundary element analysis, by using a light-fluid approximation for the eigenmode series to evaluate the structural response. In the other boundary element analysis, the air loading is treated as an added mass. The effect of the modal energy loss factor on the sound transmission loss of the panels was investigated. Both boundary element analyses were used to study the sound transmission loss of symmetric sandwich panels excited by a random incidence acoustic field. A classical wave impedance analysis was also used to make sound transmission loss predictions for the two foam-filled honeycomb sandwich panels. Comparisons between predictions of sound transmission loss for the two foam-filled honeycomb sandwich panels excited by a random incidence acoustic field obtained from the wave impedance analysis, the two boundary element analyses, and experimental measurements are presented.

  15. CFD study on the effects of boundary conditions on air flow through an air-cooled condenser

    NASA Astrophysics Data System (ADS)

    Sumara, Zdeněk; Šochman, Michal

    2018-06-01

    This study focuses on the effects of boundary conditions on effectiveness of an air-cooled condenser (ACC). Heat duty of ACC is very often calculated for ideal uniform velocity field which does not correspond to reality. Therefore, this study studies the effect of wind and different landscapes on air flow through ACC. For this study software OpenFOAM was used and the flow was simulated with the use of RANS equations. For verification of numerical setup a model of one ACC cell with dimensions of platform 1.5×1.5 [m] was used. In this experiment static pressures behind fan and air flows through a model of surface of condenser for different rpm of fan were measured. In OpenFOAM software a virtual clone of this experiment was built and different meshes, turbulent models and numerical schemes were tested. After tuning up numerical setup virtual model of real ACC system was built. Influence of wind, landscape and height of ACC on air flow through ACC has been investigated.

  16. Geographic boundaries in breast, lung and colorectal cancers in relation to exposure to air toxics in Long Island, New York

    PubMed Central

    Jacquez, Geoffrey M; Greiling, Dunrie A

    2003-01-01

    Background This two-part study employs several statistical techniques to evaluate the geographic distribution of breast cancer in females and colorectal and lung cancers in males and females in Nassau, Queens, and Suffolk counties, New York, USA. In this second paper, we compare patterns in standardized morbidity ratios (SMR values), calculated from New York State Department of Health (NYSDOH) data, to geographic patterns in overall predicted risk (OPR) from air toxics using exposures estimated in the USEPA National Air Toxics Assessment database. Results We identified significant geographic boundaries in SMR and OPR. We found little or no association between the SMR of colorectal and breast cancers and the OPR for each cancer from exposure to the air toxics. We did find boundaries in male and female lung cancer SMR and boundaries in lung cancer OPR to be closer to one another than expected. Conclusion While consistent with a causal relationship between air toxics and lung cancer incidence, the boundary analysis does not demonstrate the existence of a causal relationship. However, now that the areas of overlap between boundaries in lung cancer incidence and potential airborne exposures have been identified, we can begin to evaluate local- as well as large-scale determinants of lung cancer. PMID:12633502

  17. The Coupled Boundary Layers and Air-Sea Transfer (CBLAST) Experiments at the Martha's Vineyard Coastal Observatory

    NASA Astrophysics Data System (ADS)

    Edson, J. B.

    2001-12-01

    The Woods Hole Oceanographic Institution (WHOI) completed the initial phase of the Martha's Vineyard Coastal Observatory (MVCO) in July of 2001. The MVCO is being using to monitor coastal atmospheric and oceanic processes. Specifically, the observatory is expected to: - Provide continuous long-term observations for climate studies. - Provide a reliable system and rugged sensors that allow opportunistic sampling of extreme events. - Provide a local climatology for intensive, short duration field campaigns. - Further facilitate regional studies of coastal processes by providing infrastructure that supports easy access to power and data. This talk provides an example of the last two objectives using the low wind component of the Office of Naval Research's (ONR) Coupled Boundary Layers and Air-Sea Transfer (CBLAST) program. CBLAST-LOW has been designed to investigate air-sea interaction and coupled atmospheric and oceanic boundary layer dynamics at low wind speeds where the dynamic processes are driven and/or strongly modulated by thermal forcing. This effort is being carried out by scientists at WHOI, NPS, NOAA, NRL, Rutgers, UW/APL, JH/APL, OSU, NCAR, and other institutions, and includes observational and modeling components. The MVCO is providing observations and infrastructure in support of several intensive operating periods in the summers of 2001, 2002, and possibly 2003. During these periods, the observational network around the observatory was and will be greatly expanded using traditional oceanographic moorings and bottom mounted instrumentation, innovative 2- and 3-D moored and drifting arrays, survey ships, AUVs, satellite remote sensing, and heavily instrumented aircraft. In addition, the MVCO cabled components will be extended out to the 20-m isobath where we plan to deploy a 35-m tower. The tower will be instrumented from 15-m above the ocean surface to the ocean bottom with instruments capable of directly measuring the momentum, heat, and radiative

  18. Subtropical air masses over eastern Canada: Their links to extreme precipitation

    NASA Astrophysics Data System (ADS)

    Gyakum, John; Wood, Alice; Milrad, Shawn; Atallah, Eyad

    2017-04-01

    We investigate extremely warm, moist air masses with an analysis of 850-hPa equivalent potential temperature (θe) extremes at Montreal, Quebec. The utility of using this metric is that it represents the thermodynamic property of air that ascends during a precipitation event. We produce an analysis of the 40 most extreme cases of positive θe, 10 for each season, based upon standardized anomalies from the 33-year climatology. The analysis shows the cases to be characterized by air masses with distinct subtropical traits for all seasons: reduced static stability, anomalously high precipitable water, and anomalously elevated dynamic tropopause heights. Persistent, slow moving upper- and lower-level features were essential in the build up of high- θe air encompassing much of eastern Canada. The trajectory analysis also showed anticyclonic curvature to all paths in all seasons, implying that the subtropical anticyclone is crucial in the transport of high- θe air. These atmospheric rivers during the winter are characterized by trajectories from the subtropical North Atlantic, and over the Gulf Stream current, northward into Montreal. In contrast, the summer anticyclonic trajectories are primarily continental, traveling from Texas north-northeastward into the Great Lakes, and then eastward into Montreal. The role of the air mass in modulating the strength of a precipitation event is addressed with an analysis of the expression, P = RD, where P is the total precipitation, and R is the precipitation rate, averaged through the duration, D, of the event. Though appearing simple, this expression includes R, (assumed to be same as condensation, with an efficiency of 1), which may be expressed as the product of vertical motion and the change of saturation mixing ratio following a moist adiabat, through the troposphere. This expression for R includes the essential ingredients of lift, air mass temperature, and static stability (implicit in vertical motion). We use this

  19. Mass-conserved volumetric lattice Boltzmann method for complex flows with willfully moving boundaries.

    PubMed

    Yu, Huidan; Chen, Xi; Wang, Zhiqiang; Deep, Debanjan; Lima, Everton; Zhao, Ye; Teague, Shawn D

    2014-06-01

    In this paper, we develop a mass-conserved volumetric lattice Boltzmann method (MCVLBM) for numerically solving fluid dynamics with willfully moving arbitrary boundaries. In MCVLBM, fluid particles are uniformly distributed in lattice cells and the lattice Boltzmann equations deal with the time evolution of the particle distribution function. By introducing a volumetric parameter P(x,y,z,t) defined as the occupation of solid volume in the cell, we distinguish three types of lattice cells in the simulation domain: solid cell (pure solid occupation, P=1), fluid cell (pure fluid occupation, P=0), and boundary cell (partial solid and partial fluid, 0boundary and the flow; (2) streaming accompanying a volumetric bounce-back procedure in boundary cells; and (3) boundary-induced volumetric fluid migration moving the residual fluid particles into the flow domain when the boundary swipes over a boundary cell toward a solid cell. The MCVLBM strictly satisfies mass conservation and can handle irregular boundary orientation and motion with respect to the mesh. Validation studies are carried out in four cases. The first is to simulate fluid dynamics in syringes focusing on how MCVLBM captures the underlying physics of flow driven by a willfully moving piston. The second and third cases are two-dimensional (2D) peristaltic flow and three-dimensional (3D) pipe flow, respectively. In each case, we compare the MCVLBM simulation result with the analytical solution and achieve quantitatively good agreements. The fourth case is to simulate blood flow in human aortic arteries with a very complicated irregular boundary. We study steady flow in two dimensions and unsteady flow via the pulsation of the cardiac cycle in three dimensions. In the 2D case, both vector (velocity) and

  20. Design of an air ejector for boundary-layer bleed of an acoustically treated turbofan engine inlet during ground testing

    NASA Technical Reports Server (NTRS)

    Stakolich, E. G.

    1978-01-01

    An air ejector was designed and built to remove the boundary-layer air from the inlet a turbofan engine during an acoustic ground test program. This report describes; (1) how the ejector was sized; (2) how the ejector performed; and (3) the performance of a scale model ejector built and tested to verify the design. With proper acoustic insulation, the ejector was effective in reducing boundary layer thickness in the inlet of the turbofan engine while obtaining the desired acoustic test conditions.

  1. Settlement with Amherst, Mass., Company Reduces Emissions to Air

    EPA Pesticide Factsheets

    Under the terms of a recent settlement with the U.S. Environmental Protection Agency (EPA), John S. Lane and Son, Inc. (JS Lane), a sand and gravel company in Amherst, Mass., has taken steps to reduce air pollution, as required by the Clean Air Act (CAA).

  2. Numerical study of shock-wave/boundary layer interactions in premixed hydrogen-air hypersonic flows

    NASA Technical Reports Server (NTRS)

    Yungster, Shaye

    1991-01-01

    A computational study of shock wave/boundary layer interactions involving premixed combustible gases, and the resulting combustion processes is presented. The analysis is carried out using a new fully implicit, total variation diminishing (TVD) code developed for solving the fully coupled Reynolds-averaged Navier-Stokes equations and species continuity equations in an efficient manner. To accelerate the convergence of the basic iterative procedure, this code is combined with vector extrapolation methods. The chemical nonequilibrium processes are simulated by means of a finite-rate chemistry model for hydrogen-air combustion. Several validation test cases are presented and the results compared with experimental data or with other computational results. The code is then applied to study shock wave/boundary layer interactions in a ram accelerator configuration. Results indicate a new combustion mechanism in which a shock wave induces combustion in the boundary layer, which then propagates outwards and downstream. At higher Mach numbers, spontaneous ignition in part of the boundary layer is observed, which eventually extends along the entire boundary layer at still higher values of the Mach number.

  3. Numerical study of shock-wave/boundary layer interactions in premixed hydrogen-air hypersonic flows

    NASA Technical Reports Server (NTRS)

    Yungster, Shaye

    1990-01-01

    A computational study of shock wave/boundary layer interactions involving premixed combustible gases, and the resulting combustion processes is presented. The analysis is carried out using a new fully implicit, total variation diminishing (TVD) code developed for solving the fully coupled Reynolds-averaged Navier-Stokes equations and species continuity equations in an efficient manner. To accelerate the convergence of the basic iterative procedure, this code is combined with vector extrapolation methods. The chemical nonequilibrium processes are simulated by means of a finite-rate chemistry model for hydrogen-air combustion. Several validation test cases are presented and the results compared with experimental data or with other computational results. The code is then applied to study shock wave/boundary layer interactions in a ram accelerator configuration. Results indicate a new combustion mechanism in which a shock wave induces combustion in the boundary layer, which then propagates outwards and downstream. At higher Mach numbers, spontaneous ignition in part of the boundary layer is observed, which eventually extends along the entire boundary layer at still higher values of the Mach number.

  4. Experimental Determination of Air Density Using a 1 kg Mass Comparator in Vacuum

    NASA Astrophysics Data System (ADS)

    Gläser, M.; Schwartz, R.; Mecke, M.

    1991-01-01

    The density of ambient air has been determined by a straightforward experimental method. The apparent masses of two artefacts having about the same mass and surface, but different well-known volumes, have been compared by using a 1 kg balance in vacuum and in air. The differences of apparent masses and volumes yield the air density with a relative uncertainty (1σ) of 5 × 10-5. From measurements made using a third artefact, surface sorption effects caused by the change between vacuum and air conditions gave a coefficient of about 0,2 μg cm-2.

  5. The fabrication of plastic cages for suspension in mass air flow racks.

    PubMed

    Nielsen, F H; Bailey, B

    1979-08-01

    A cage for suspension in mass air flow racks was constructed of plastic and used to house rats. Little or no difficulty was encountered with the mass air flow rack-suspended cage system during the 4 years it was used for the study of trace elements.

  6. LINKING ETA MODEL WITH THE COMMUNITY MULTISCALE AIR QUALITY (CMAQ) MODELING SYSTEM: OZONE BOUNDARY CONDITIONS

    EPA Science Inventory

    A prototype surface ozone concentration forecasting model system for the Eastern U.S. has been developed. The model system is consisting of a regional meteorological and a regional air quality model. It demonstrated a strong prediction dependence on its ozone boundary conditions....

  7. Boundary Layer Control for Hypersonic Airbreathing Vehicles

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; Nowak, Robert J.; Horvath, Thomas J.

    2004-01-01

    Active and passive methods for tripping hypersonic boundary layers have been examined in NASA Langley Research Center wind tunnels using a Hyper-X model. This investigation assessed several concepts for forcing transition, including passive discrete roughness elements and active mass addition (or blowing), in the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air Tunnels. Heat transfer distributions obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the Hyper-X nominal Mach 7 flight test-point of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For passive roughness, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The passive roughness study resulted in a swept ramp configuration, scaled to be roughly 0.6 of the calculated boundary layer thickness, being selected for the Mach 7 flight vehicle. For the active blowing study, the manifold pressure was systematically varied (while monitoring the mass flow) for each configuration to determine the jet penetration height, with schlieren, and transition movement, with the phosphor system, for comparison to the passive results. All the blowing concepts tested, which included various rows of sonic orifices (holes), two- and three-dimensional slots, and random porosity, provided transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model surface static pressure, which is adequate to ensure sonic jets. The present results indicate that the jet penetration height for blowing was roughly half the height required with passive roughness elements for an equivalent amount of transition movement.

  8. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  9. Trans-boundary air pollution in a city under various atmospheric conditions.

    PubMed

    Luo, Ming; Hou, Xiangting; Gu, Yefu; Lau, Ngar-Cheung; Yim, Steve Hung-Lam

    2018-03-15

    Trans-boundary air pollution (TAP) is a crucial factor affecting air quality, and its contribution may vary over time and differ under various atmospheric conditions. This study firstly applies an integrated statistical scheme to estimate the contributions of TAP and local sources to air pollutants in a city, and then investigate the influences of tropical cyclones (TC) on TAP. Hong Kong is chosen as an example because of its significant and special TAP characteristics. This study focuses on four major air pollutants, namely, respirable and fine suspended particulates (RSP/PM 10 and FSP/PM 2.5 ), sulfur dioxide (SO 2 ), and nitrogen dioxide (NO 2 ), from 2002 to 2013. Our results show that, on average, TAP is the major contributor of the annual RSP, FSP, SO 2 , and NO 2 in Hong Kong. We estimate that when a TC is approaching, the increase in pollutant concentration in Hong Kong is mainly due to the increase in TAP contribution by the strengthened northerly wind at higher level of atmosphere (≥900hPa). These changes are accompanied by decreases in precipitation and increases in northerly/north-easterly wind, which may prolong the lifetime of pollutants, enhancing pollutant transport from mainland China to Hong Kong. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Boundary-layer exchange by bubble: A novel method for generating transient nanofluidic layers

    NASA Astrophysics Data System (ADS)

    Jennissen, Herbert P.

    2005-10-01

    Unstirred layers (i.e., Nernst boundary layers) occur on every dynamic solid-liquid interface, constituting a diffusion barrier, since the velocity of a moving liquid approaches zero at the surface (no slip). If a macromolecule-surface reaction rate is higher than the diffusion rate, the Nernst layer is solute depleted and the reaction rate becomes mass-transport limited. The thickness of a Nernst boundary layer (δN) generally lies between 5 and 50μm. In an evanescent wave rheometer, measuring fibrinogen adsorption to fused silica, we made the fundamental observation that an air bubble preceding the sample through the flow cell abolishes the mass-transport limitation of the Nernst diffusion layer. Instead exponential kinetics are found. Experimental and simulation studies strongly indicate that these results are due to the elimination of the Nernst diffusion layer and its replacement by a dynamic nanofluidic layer (δν) maximally 200-300nm thick. It is suggested that the air bubble leads to a transient boundary-layer separation into a novel nanoboundary layer on the surface and the bulk fluid velocity profile separated by a vortex sheet with an estimated lifetime of 30-60s. A bubble-induced boundary-layer exchange from the Nernst to the nanoboundary layer and back is obtained, giving sufficient time for the measurement of unbiased exponential surface kinetics. Noteworthy is that the nanolayer can exist at all and displays properties such as (i) a long persistence and resistance to dissipation by the bulk liquid (boundary-layer-exchange-hysteresis) and (ii) a lack of solute depletion in spite of boundary-layer separation. The boundary-layer-exchange by bubble (BLEB) method therefore appears ideal for enhancing the rates of all types of diffusion-limited macromolecular reactions on surfaces with contact angles between 0° and 90° and only appears limited by slippage due to nanobubbles or an air gap beneath the nanofluidic layer on very hydrophobic surfaces. The

  11. Modeling of Trans-boundary Transport of Air Pollutants in the California-Mexico Border Region during Cal-Mex 2010

    NASA Astrophysics Data System (ADS)

    Bei, N.; Zavala, M. A.; Lei, W.; Li, G.; Molina, L. T.

    2010-12-01

    The US and Mexico share a common air basin along the ~200 km border between California and Baja California. The economical activities in this region are heavily influenced by the international trade and commerce between Mexico and the US that mainly occurs through the borders of the sister cities of San Diego-Tijuana and Calexico-Mexicali. The diversity and differences in the characteristics of emissions sources of air pollutants in the California-Mexico border region make this an important area for the study of the chemistry and trans-boundary transport of air pollutants. During May-June of 2010, the Cal-Mex 2010 field campaign included a series of measurements aimed at characterizing the emissions from major sources in the California-Mexico border region and assessing the possible impacts of these emissions on local and regional air quality. In this work we will present the results of the use of the Comprehensive Air quality model with extensions (CAMx) in a modeling domain that includes the sister cities of San Diego-Tijuana and Calexico-Mexicali for studying events of trans-boundary transport of air pollutants during Cal-Mex 2010. The measurements obtained during the Cal-Mex 2010 field campaign are used in the evaluation of the model performance and in the design of air quality improvement policies in the California-Mexico border region.

  12. Water vapor mass balance method for determining air infiltration rates in houses

    Treesearch

    David R. DeWalle; Gordon M. Heisler

    1980-01-01

    A water vapor mass balance technique that includes the use of common humidity-control equipment can be used to determine average air infiltration rates in buildings. Only measurements of the humidity inside and outside the home, the mass of vapor exchanged by a humidifier/dehumidifier, and the volume of interior air space are needed. This method gives results that...

  13. Experimental evaluation of refrigerant mass charge and ambient air temperature effects on performance of air-conditioning systems

    NASA Astrophysics Data System (ADS)

    Deymi-Dashtebayaz, Mahdi; Farahnak, Mehdi; Moraffa, Mojtaba; Ghalami, Arash; Mohammadi, Nima

    2018-03-01

    In this paper the effects of refrigerant charge amount and ambient air temperature on performance and thermodynamic condition of refrigerating cycle in the split type air-conditioner have been investigated. Optimum mass charge is the point at which the energy efficiency ratio (EER) of refrigeration cycle becomes the maximum. Experiments have been conducted over a range of refrigerant mass charge from 540 to 840 g and a range of ambient temperature from 27 to 45 °C, in a 12,000 Btu/h split air-conditioner as case study. The various parameters have been considered to evaluate the cooling rate, energy efficiency ratio (EER), mass charge effect and thermodynamic cycle of refrigeration system with R22 refrigerant gas. Results confirmed that the lack of appropriate refrigerant mass charge causes the refrigeration system not to reach its maximum cooling capacity. The highest cooling capacity achieved was 3.2 kW (11,000 Btu/h). The optimum mass charge and corresponding EER of studied system have been obtained about 640 g and 2.5, respectively. Also, it is observed that EER decreases by 30% as ambient temperature increases from 27 °C to 45 °C. By optimization of the refrigerant mass charge in refrigerating systems, about 785 GWh per year of electric energy can be saved in Iran's residential sector.

  14. Influence of the boundary conditions on heat and mass transfer in spacer-filled channels

    NASA Astrophysics Data System (ADS)

    Ciofalo, M.; La Cerva, M. F.; Di Liberto, M.; Tamburini, A.

    2017-11-01

    The purpose of this study is to discuss some problems which arise in heat or mass transfer in complex channels, with special reference to the spacer-filled channels adopted in membrane processes. Among the issues addressed are the consistent definition of local and mean heat or mass transfer coefficients; the influence of the wall boundary conditions; the influence of one-side versus two-side heat/mass transfer. Most of the results discussed were obtained by finite volume CFD simulations concerning heat transfer in Membrane Distillation or mass transfer in Electrodialysis and Reverse Electrodialysis, but many of the conclusions apply also to different processes involving geometrically complex channels

  15. Acoustic explorations of the upper ocean boundary layer

    NASA Astrophysics Data System (ADS)

    Vagle, Svein

    2005-04-01

    The upper ocean boundary layer is an important but difficult to probe part of the ocean. A better understanding of small scale processes at the air-sea interface, including the vertical transfer of gases, heat, mass and momentum, are crucial to improving our understanding of the coupling between atmosphere and ocean. Also, this part of the ocean contains a significant part of the total biomass at all trophic levels and is therefore of great interest to researchers in a range of different fields. Innovative measurement plays a critical role in developing our understanding of the processes involved in the boundary layer, and the availability of low-cost, compact, digital signal processors and sonar technology in self-contained and cabled configurations has led to a number of exciting developments. This talk summarizes some recent explorations of this dynamic boundary layer using both active and passive acoustics. The resonant behavior of upper ocean bubbles combined with single and multi-frequency broad band active and passive devices are now giving us invaluable information on air-sea gas transfer, estimation of biological production, marine mammal behavior, wind speed and precipitation, surface and internal waves, turbulence, and acoustic communication in the surf zone.

  16. Effects of air pollution on thermal structure and dispersion in an urban planetary boundary layer

    NASA Technical Reports Server (NTRS)

    Viskanta, R.; Johnson, R. O.; Bergstrom, R. W.

    1977-01-01

    The short-term effects of urbanization and air pollution on the transport processes in the urban planetary boundary layer (PBL) are studied. The investigation makes use of an unsteady two-dimensional transport model which has been developed by Viskanta et al., (1976). The model predicts pollutant concentrations and temperature in the PBL. The potential effects of urbanization and air pollution on the thermal structure in the urban PBL are considered, taking into account the results of numerical simulations modeling the St. Louis, Missouri metropolitan area.

  17. The Role of Wave Cyclones in Transporting Boundary Layer Air to the Free Troposphere During the Spring 2001 NASA / TRACE-P Experiment

    NASA Technical Reports Server (NTRS)

    Fuelberg, Henry E.; Hannan, J. R.; Crawford, J. H.; Sachse, G. W.; Blake, D. R.

    2003-01-01

    Transport of boundary layer air to the free troposphere by cyclones during NASA's Transport and Chemical Evolution over the Pacific (TRACE-P) experiment is investigated. Airstreams responsible for boundary layer venting are diagnosed using results from a high-resolution meteorological model (MM5) together with in situ and remotely sensed chemical data. Hourly wind data from the MM5 are used to calculate three-dimensional grids of backward air trajectories. A reverse domain filling (RDF) technique then is employed to examine the characteristics of airstreams over the computational domain, and to isolate airstreams ascending from the boundary layer to the free troposphere during the previous 36 hours. Two cases are examined in detail. Results show that airstreams responsible for venting the boundary layer differ considerably from those described by classic conceptual models and in the recent literature. In addition, airstreams sampled by the TRACE-P aircraft are found to exhibit large variability in chemical concentrations. This variability is due to differences in the boundary layer histories of individual airstreams with respect to anthropogenic sources over continental Asia and Japan. Complex interactions between successive wave cyclones also are found to be important in determining the chemical composition of the airstreams. Particularly important is the process of post-cold frontal boundary layer air being rapidly transported offshore and recirculated into ascending airstreams of upstream cyclones.

  18. The mass and speed dependence of meteor air plasma temperatures

    NASA Technical Reports Server (NTRS)

    Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  19. The mass and speed dependence of meteor air plasma temperatures.

    PubMed

    Jenniskens, Peter; Laux, Christophe O; Wilson, Michael A; Schaller, Emily L

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  20. Null boundary controllability of a one-dimensional heat equation with an internal point mass and variable coefficients

    NASA Astrophysics Data System (ADS)

    Ben Amara, Jamel; Bouzidi, Hedi

    2018-01-01

    In this paper, we consider a linear hybrid system which is composed by two non-homogeneous rods connected by a point mass with Dirichlet boundary conditions on the left end and a boundary control acts on the right end. We prove that this system is null controllable with Dirichlet or Neumann boundary controls. Our approach is mainly based on a detailed spectral analysis together with the moment method. In particular, we show that the associated spectral gap in both cases (Dirichlet or Neumann boundary controls) is positive without further conditions on the coefficients other than the regularities.

  1. Estimation of air-to-grass mass interception factors for iodine.

    PubMed

    Karunakara, N; Ujwal, P; Yashodhara, I; Sudeep Kumara, K; Mohan, M P; Bhaskar Shenoy, K; Geetha, P V; Dileep, B N; James, Joshi P; Ravi, P M

    2018-06-01

    Air-to-grass mass interception factors for radionuclide are important basic input parameter for the estimation of radiation dose to the public around a nuclear power plant. In this paper, we present the determination of air-to- grass mass interception factors for iodine using a 2 m × 2 m × 2 m (l × b × h) size environmental chamber. The temperature, humidity, and rainfall inside the environmental chamber was controlled to required values to simulate different environmental conditions. Grass (Pennisetum purpureum, Schum), grown in pots, was kept inside the environmental chamber and stable iodine in elemental form was sublimed quickly inside the chamber to simulate an accidental release of iodine to the environment. The concentration of iodine in the air was measured periodically by drawing air through a bubbling setup, containing 1% sodium carbonate solution. The mass interception factor for dry deposition varied in the range of 0.25-7.7 m 2  kg -1 with mean value of 2.2 m 2  kg -1 with respect to fresh weight of grass, and that due to wet deposition varied in the range of 0.6-4.8 m 2  kg -1 with mean value of 2.3 m 2  kg -1 . The mass interception factor was inversely correlated with the total iodine deposited through dry deposition as well as with the rainfall. Copyright © 2017. Published by Elsevier Ltd.

  2. Evolutionary and Ecological Sequelae of Mass Extinctions: Examples From the Continental Triassic-Jurassic Boundary

    NASA Astrophysics Data System (ADS)

    Olsen, P. E.; Whiteside, J. H.

    2003-12-01

    The Triassic-Jurassic boundary at ˜200 Ma marks one of the five major mass-extinctions of the Phanerozoic and, depending on the metrics used, was similar in magnitude to the K-T mass extinction. In continental environments about 50% of all tetrapod families are eliminated and although floral diversity change is difficult to gauge, a similar proportion of palynomorph taxa disappear at the boundary. The extinction event appears to have been very abrupt, followed by a roughly 900 ky super-greenhouse period characterized by increased precipitation. We hypothesize a series of biological consequences of the drop in diversity and associated super-greenhouse based on observations of the earliest Jurassic assemblages, largely from eastern North America. 1) The drop in diversity results in a collapse of ecological interactions that tend to stabilize the composition of regional biotas and buffer them from invading forms. Triassic assemblages show considerable biogeographic provinciality despite the existence of Pangea, but the earliest Jurassic assemblages were extraordinarily homogenous with many vertebrate genera being essentially global in distribution. 2) Initially the post-boundary terrestrial assemblages were comprised of eurytopic trophic generalists, with animal communities with few herbivores, but abundant carnivores and detritivores subsisting on aquatic-based food webs. The earliest Jurassic tetrapod footprint record is overwhelmingly dominated by the footprints of ceratosaurian theropod dinosaurs, the latter having skull characteristics usually associated at least in part with piscivory. 3) The dramatic size changes over very short periods of time were likely due to an absence of competition (i.e., ecological release). The maximum size of theropod dinosaur footprints increased by about 25% within 10 ky following the boundary, corresponding to a doubling of mass. 4) Representatives of clades with intrinsically high rates of speciation tend to form species flocks

  3. Grain Boundary Engineering of Lithium-Ion-Conducting Lithium Lanthanum Titanate for Lithium-Air Batteries

    DTIC Science & Technology

    2016-01-01

    release; distribution is unlimited. 1 1. Introduction Lithium (Li)- ion batteries are currently one of the leading energy storage device technologies...ARL-TR-7584 ● JAN 2016 US Army Research Laboratory Grain Boundary Engineering of Lithium - Ion - Conducting Lithium Lanthanum...Titanate for Lithium -Air Batteries by Victoria L Blair, Claire V Weiss Brennan, and Joseph M Marsico Approved for public

  4. High-Reynolds-number turbulent-boundary-layer wall pressure fluctuations with skin-friction reduction by air injection.

    PubMed

    Winkel, Eric S; Elbing, Brian R; Ceccio, Steven L; Perlin, Marc; Dowling, David R

    2008-05-01

    The hydrodynamic pressure fluctuations that occur on the solid surface beneath a turbulent boundary layer are a common source of flow noise. This paper reports multipoint surface pressure fluctuation measurements in water beneath a high-Reynolds-number turbulent boundary layer with wall injection of air to reduce skin-friction drag. The experiments were conducted in the U.S. Navy's Large Cavitation Channel on a 12.9-m-long, 3.05-m-wide hydrodynamically smooth flat plate at freestream speeds up to 20 ms and downstream-distance-based Reynolds numbers exceeding 200 x 10(6). Air was injected from one of two spanwise slots through flush-mounted porous stainless steel frits (approximately 40 microm mean pore diameter) at volume flow rates from 17.8 to 142.5 l/s per meter span. The two injectors were located 1.32 and 9.78 m from the model's leading edge and spanned the center 87% of the test model. Surface pressure measurements were made with 16 flush-mounted transducers in an "L-shaped" array located 10.7 m from the plate's leading edge. When compared to no-injection conditions, the observed wall-pressure variance was reduced by as much as 87% with air injection. In addition, air injection altered the inferred convection speed of pressure fluctuation sources and the streamwise coherence of pressure fluctuations.

  5. Dusty air masses transport between Amazon Basin and Caribbean Islands

    NASA Astrophysics Data System (ADS)

    Euphrasie-Clotilde, Lovely; Molinie, Jack; Prospero, Joseph; Feuillard, Tony; Brute, Francenor; Jeannot, Alexis

    2015-04-01

    Depend on the month, African desert dust affect different parts of the North Atlantic Ocean. From December to April, Saharan dust outbreaks are often reported over the amazon basin and from May to November over the Caribbean islands and the southern regions of USA. This annual oscillation of Saharan dust presence, related to the ITCZ position, is perturbed some time, during March. Indeed, over Guadeloupe, the air quality network observed between 2007 and 2012 several dust events during March. In this paper, using HISPLIT back trajectories, we analyzed air masses trajectories for March dust events observed in Guadeloupe, from 2007 to 2012.We observed that the high pressure positions over the Atlantic Ocean allow the transport of dusty air masses from southern region of West Africa to the Caribbean Sea with a path crossing close to coastal region of French Guyana. Complementary investigations including the relationship between PM10 concentrations recorded in two sites Pointe-a-Pitre in the Caribbean, and Cayenne in French Guyana, have been done. Moreover we focus on the mean delay observed between the times arrival. All the results show a link between pathway of dusty air masses present over amazon basin and over the Caribbean region during several event of March. The next step will be the comparison of mineral dust composition for this particular month.

  6. Influence of the relative optical air mass on ultraviolet erythemal irradiance

    NASA Astrophysics Data System (ADS)

    Antón, M.; Serrano, A.; Cancillo, M. L.; García, J. A.

    2009-12-01

    The main objective of this article is to analyze the relationship between the transmissivity for ultraviolet erythemal irradiance (UVER) and the relative optical air mass at Badajoz (Southwestern Spain). Thus, a power expression between both variables is developed, which analyses in detail how atmospheric transmission is influenced by the total ozone column (TOC) and the atmospheric clearness. The period of analysis extends from 2001 to 2005. The experimental results indicate that clearness conditions play an important role in the relationship between UVER transmissivity and the relative optical air mass, while the effect of TOC is much smaller for this data set. In addition, the results show that UVER transmissivity is more sensitive to changes in atmospheric clearness than to TOC variability. Changes in TOC values higher than 15% cause UVER trasnmissivity to vary between 14% and 22%, while changes between cloud-free and overcast conditions produce variations in UVER transmissivity between 68% and 74% depending on the relative optical air mass.

  7. Defining Winter and Identifying Synoptic Air Mass Change in the Northeast and Northern Plains U.S. since 1950

    NASA Astrophysics Data System (ADS)

    Chapman, C. J.; Pennington, D.; Beitscher, M. R.; Godek, M. L.

    2017-12-01

    Understanding and forecasting the characteristics of winter weather change in the northern U.S. is vital to regional economy, agriculture, tourism and resident life. This is especially true in the Northeast and Northern Plains where substantial changes to the winter season have already been documented in the atmospheric science and biological literature. As there is no single established definition of `winter', this research attempts to identify the winter season in both regions utilizing a synoptic climatological approach with air mass frequencies. The Spatial Synoptic Classification is used to determine the daily air mass/ weather type conditions since 1950 at 40 locations across the two regions. Annual frequencies are first computed as a baseline reference. Then winter air mass frequencies and departures from normal are calculated to define the season along with the statistical significance. Once the synoptic winter is established, long-term regional changes to the season and significance are explored. As evident global changes have occurred after 1975, an Early period of years prior to 1975 and a Late set for all years following this date are compared. Early and Late record synoptic changes are then examined to assess any thermal and moisture condition changes of the regional winter air masses over time. Cold to moderately dry air masses dominate annually in both regions. Northeast winters are also characterized by cold to moderate dry air masses, with coastal locations experiencing more Moist Polar types. The Northern Plains winters are dominated by cold, dry air masses in the east and cold to moderate dry air masses in the west. Prior to 1975, Northeast winters are defined by an increase in cooler and wetter air masses. Dry Tropical air masses only occur in this region after 1975. Northern Plains winters are also characterized by more cold, dry air masses prior to 1975. More Dry Moderate and Moist Moderate air masses have occurred since 1975. These results

  8. Mathematical model of one-man air revitalization system

    NASA Technical Reports Server (NTRS)

    1976-01-01

    A mathematical model was developed for simulating the steady state performance in electrochemical CO2 concentrators which utilize (NMe4)2 CO3 (aq.) electrolyte. This electrolyte, which accommodates a wide range of air relative humidity, is most suitable for one-man air revitalization systems. The model is based on the solution of coupled nonlinear ordinary differential equations derived from mass transport and rate equations for the processes which take place in the cell. The boundary conditions are obtained by solving the mass and energy transport equations. A shooting method is used to solve the differential equations.

  9. Winter air-mass-based synoptic climatological approach and hospital admissions for myocardial infarction in Florence, Italy.

    PubMed

    Morabito, Marco; Crisci, Alfonso; Grifoni, Daniele; Orlandini, Simone; Cecchi, Lorenzo; Bacci, Laura; Modesti, Pietro Amedeo; Gensini, Gian Franco; Maracchi, Giampiero

    2006-09-01

    The aim of this study was to evaluate the relationship between the risk of hospital admission for myocardial infarction (MI) and the daily weather conditions during the winters of 1998-2003, according to an air-mass-based synoptic climatological approach. The effects of time lag and 2-day sequences with specific air mass types were also investigated. Studies concerning the relationship between atmospheric conditions and human health need to take into consideration simultaneous effects of many weather variables. At the moment few studies have surveyed these effects on hospitalizations for MI. Analyses were concentrated on winter, when the maximum peak of hospitalization occurred. An objective daily air mass classification by means of statistical analyses based on ground meteorological data was carried out. A comparison between air mass classification and hospital admissions was made by the calculation of a MI admission index, and to detect significant relationships the Mann-Whitney U test, the analysis of variance, and the Bonferroni test were used. Significant increases in hospital admissions for MI were evident 24h after a day characterized by an anticyclonic continental air mass and 6 days after a day characterized by a cyclonic air mass. Increased risk of hospitalization was found even when specific 2-day air mass sequences occurred. These results represent an important step in identifying reliable linkages between weather and health.

  10. DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

    EPA Science Inventory

    The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

  11. The Use of Red Green Blue (RGB) Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Zavodsky, Bradley; Molthan, Andrew; Jedlovec, Gary

    2013-01-01

    AIRS ozone and model PV analysis confirm the stratospheric air in RGB Air Mass imagery. Trajectories confirm winds south of the low were distinct from CCB driven winds. Cross sections connect the tropopause fold, downward motion, and high nearsurface winds. Comparison to conceptual models show Shapiro-Keyser features and sting jet characteristics were observed in a storm that impacted the U.S. East Coast. RGB Air Mass imagery can be used to identify stratospheric air and regions susceptible to tropopause folding and attendant non-convective winds.

  12. Trace gases and air mass origin at Kaashidhoo, Indian Ocean

    NASA Astrophysics Data System (ADS)

    Lobert, Jürgen M.; Harris, Joyce M.

    2002-10-01

    Carbon monoxide (CO) was measured at the Kaashidhoo Climate Observatory (KCO, Republic of Maldives) between February 1998 and March 2000 to assess the regional pollution of the remote atmosphere in the northern Indian Ocean. CO showed a distinct annual cycle with maximum daily mixing ratios of around 240 parts per billion (ppb), a seasonal difference of about 200 ppb, and high variability during the dry seasons. Detailed air mass trajectory analysis for 1998, 1999, and 2000 was used to identify source regions and to associate them with various levels of pollution encountered at KCO. We conclude that most significant changes in local pollution throughout the year are caused by changes in air masses. Air at KCO generally originated from three main regions with decreasing pollution: India and southeast Asia, the Arabian Sea, and the Southern Hemisphere. We show that isentropic air mass trajectories can be used to predict CO pollution levels at KCO to a certain extent and vice versa. Nitrous oxide, CFC-11, CFC-12, CCI4, and SF6 were measured during the Indian Ocean Experiment (February to March 1999) to support pollution analysis and to confirm that India is the main source for heavy pollution measured at KCO. Correlations between CO and other gases and aerosol properties measured at the surface illustrate that CO may also be used as a proxy for aerosol loading and general pollution at the surface.

  13. Climatic changes resulting from mass extinctions at the K-T boundary (and other bio-events)

    NASA Technical Reports Server (NTRS)

    Rampino, Michael R.; Volk, Tyler

    1988-01-01

    The mass extinctions at the Cretaceous-Tertiary (K-T) boundary include about 90 percent of marine calcareous nannoplankton (coccoliths), and carbon-isotope data show that marine primary productivity was drastically reduced for about 500,000 years after the boundary event, the so-called Strangelove Ocean effect. One result of the elimination of most marine phytoplankton would have been a severe reduction in production of dimethyl sulfide (DMS), a biogenic gas that is believed to be the major precursor of cloud condensation nuclei (CCN) over the oceans. A drastic reduction in marine CCN should lead to a cloud canopy with significantly lower reflectivity, and hence cause a significant warming at the earth's surface. Calculations suggest that, all other things being held constant, a reduction in CCN of more than 80 percent (a reasonable value for the K-T extinctions) could have produced a rapid global warming of 6 C or more. Oxygen-isotope analyses of marine sediments, and other kinds of paleoclimatic data, have provided for a marked warming, and a general instability of climate coincident with the killoff of marine plankton at the K-T boundary. Similar reductions in phytoplankton abundance at other boundaries, as indicated by marked shifts in carbon-isotope curves, suggest that severe temperature changes may have accompanied other mass extinctions, and raises the intriguing possibility that the extinction events themselves could have contributed to the climatic instabilities at critical bio-events in the geologic record.

  14. Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus.

    PubMed

    Lichtenberg, Mads; Nørregaard, Rasmus Dyrmose; Kühl, Michael

    2017-03-01

    The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O 2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O 2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O 2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O 2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant-microbe interactions. © 2017 The Author(s).

  15. Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus

    PubMed Central

    Nørregaard, Rasmus Dyrmose

    2017-01-01

    The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant–microbe interactions. PMID:28330986

  16. An Examination of the Effect of Boundary Layer Ingestion on Turboelectric Distributed Propulsion Systems

    NASA Technical Reports Server (NTRS)

    Felder, James L.; Kim, Huyn Dae; Brown, Gerald V.; Chu, Julio

    2011-01-01

    A Turboelectric Distributed Propulsion (TeDP) system differs from other propulsion systems by the use of electrical power to transmit power from the turbine to the fan. Electrical power can be efficiently transmitted over longer distances and with complex topologies. Also the use of power inverters allows the generator and motors speeds to be independent of one another. This decoupling allows the aircraft designer to place the core engines and the fans in locations most advantageous for each. The result can be very different installation environments for the different devices. Thus the installation effects on this system can be quite different than conventional turbofans where the fan and core both see the same installed environments. This paper examines a propulsion system consisting of two superconducting generators, each driven by a turboshaft engine located so that their inlets ingest freestream air, superconducting electrical transmission lines, and an array of superconducting motor driven fan positioned across the upper/rear fuselage area of a hybrid wing body aircraft in a continuous nacelle that ingests all of the upper fuselage boundary layer. The effect of ingesting the boundary layer on the design of the system with a range of design pressure ratios is examined. Also the impact of ingesting the boundary layer on off-design performance is examined. The results show that when examining different design fan pressure ratios it is important to recalculate of the boundary layer mass-average Pt and MN up the height for each inlet height during convergence of the design point for each fan design pressure ratio examined. Correct estimation of off-design performance is dependent on the height of the column of air measured from the aircraft surface immediately prior to any external diffusion that will flow through the fan propulsors. The mass-averaged Pt and MN calculated for this column of air determine the Pt and MN seen by the propulsor inlet. Since the height

  17. Role of the boundary layer dynamics effects on an extreme air pollution event in Paris

    NASA Astrophysics Data System (ADS)

    Dupont, J.-C.; Haeffelin, M.; Badosa, J.; Elias, T.; Favez, O.; Petit, J. E.; Meleux, F.; Sciare, J.; Crenn, V.; Bonne, J. L.

    2016-09-01

    The physical and chemical aerosol properties are explored here based on ground-based observations in the Paris region to better understand the role of clouds, radiative fluxes and dynamics on aerosol loading during a heavy regional air pollution that occurred in March 2014 over North-Western Europe. This event is primarily characterized by a fine particle mass (PM2.5) increase from 10 to more than 120 μg m-3 and a simultaneous decrease of the horizontal visibility from 40 to 1 km, mainly due to significant formation of ammonium nitrate particles. The aerosol optical depth (AOD) at 550 nm increased steadily from about 0.06 on March 6 to more than 0.9 five days later. The scattering of the solar radiation by polluted particles induced, at the peak of the heavy pollution event, an instantaneous shortwave flux decrease of about 300 W m-2 for direct irradiance and an increase of about 150 W m-2 for diffuse irradiance (only scattering). The mean surface aerosol effect efficiency (effect per unit optical depth) is of about -80 W m-2 with a mean aerosol direct radiative effect of -23 W m-2. The dynamical and radiative processes that can be responsible for the diurnal cycle of PM2.5 in terms of amplitude and timing are investigated. A comparative analysis is performed for 4 consecutive days (between March 11 and 14), showing that the PM2.5 diurnal cycle can be modulated in time and amplitude by local processes such as the boundary layer depth development (ranging from 100 m to 1350 m), surface relative humidity (100%-35%), thermal structure (10 °C-16 °C for day/night amplitude), dynamics (wind speed ranging from 4 m s-1 to 1.5 m s-1) and turbulence (turbulent kinetic energy reaching 2 m2 s-2) near the surface and wind shear along the vertical. Finally, modeled and measured surface PM2.5 loadings are also compared here, notably illustrating the need of accurate boundary layer depth data for efficient air quality forecasts.

  18. Relationship between air mass type and emergency department visits for migraine headache across the Triangle region of North Carolina

    NASA Astrophysics Data System (ADS)

    Elcik, Christopher; Fuhrmann, Christopher M.; Mercer, Andrew E.; Davis, Robert E.

    2017-12-01

    An estimated 240 million people worldwide suffer from migraines. Because migraines are often debilitating, understanding the mechanisms that trigger them is crucial for effective prevention and treatment. Synoptic air mass types and emergency department (ED) visits for migraine headaches were examined over a 7-year period within a major metropolitan area of North Carolina to identify potential relationships between large-scale meteorological conditions and the incidence of migraine headaches. Barometric pressure changes associated with transitional air masses, or changing weather patterns, were also analyzed for potential relationships. Bootstrapping analysis revealed that tropical air masses (moist and dry) resulted in the greatest number of migraine ED visits over the study period, whereas polar air masses led to fewer. Moist polar air masses in particular were found to correspond with the fewest number of migraine ED visits. On transitional air mass days, the number of migraine ED visits fell between those of tropical air mass days and polar air mass days. Transitional days characterized by pressure increases exhibited a greater number of migraine ED visits than days characterized by pressure decreases. However, no relationship was found between migraine ED visits and the magnitude of barometric pressure changes associated with transitional air masses.

  19. Microgravity Effects on Plant Boundary Layers

    NASA Technical Reports Server (NTRS)

    Stutte, Gary; Monje, Oscar

    2005-01-01

    The goal of these series of experiment was to determine the effects of microgravity conditions on the developmental boundary layers in roots and leaves and to determine the effects of air flow on boundary layer development. It is hypothesized that microgravity induces larger boundary layers around plant organs because of the absence of buoyancy-driven convection. These larger boundary layers may affect normal metabolic function because they may reduce the fluxes of heat and metabolically active gases (e.g., oxygen, water vapor, and carbon dioxide. These experiments are to test whether there is a change in boundary layer associated with microgravity, quantify the change if it exists, and determine influence of air velocity on boundary layer thickness under different gravity conditions.

  20. On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Perliski, Lori M.; Solomon, Susan

    1993-01-01

    The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

  1. Boundaries of mass resolution in native mass spectrometry.

    PubMed

    Lössl, Philip; Snijder, Joost; Heck, Albert J R

    2014-06-01

    Over the last two decades, native mass spectrometry (MS) has emerged as a valuable tool to study intact proteins and noncovalent protein complexes. Studied experimental systems range from small-molecule (drug)-protein interactions, to nanomachineries such as the proteasome and ribosome, to even virus assembly. In native MS, ions attain high m/z values, requiring special mass analyzers for their detection. Depending on the particular mass analyzer used, instrumental mass resolution does often decrease at higher m/z but can still be above a couple of thousand at m/z 5000. However, the mass resolving power obtained on charge states of protein complexes in this m/z region is experimentally found to remain well below the inherent instrument resolution of the mass analyzers employed. Here, we inquire into reasons for this discrepancy and ask how native MS would benefit from higher instrumental mass resolution. To answer this question, we discuss advantages and shortcomings of mass analyzers used to study intact biomolecules and biomolecular complexes in their native state, and we review which other factors determine mass resolving power in native MS analyses. Recent examples from the literature are given to illustrate the current status and limitations.

  2. Effects of future land use and ecosystem changes on boundary-layer meteorology and air quality

    NASA Astrophysics Data System (ADS)

    Tai, A. P. K.; Wang, L.; Sadeke, M.

    2017-12-01

    Land vegetation plays key roles shaping boundary-layer meteorology and air quality via various pathways. Vegetation can directly affect surface ozone via dry deposition and biogenic emissions of volatile organic compounds (VOCs). Transpiration from land plants can also influence surface temperature, soil moisture and boundary-layer mixing depth, thereby indirectly affecting surface ozone. Future changes in the distribution, density and physiology of vegetation are therefore expected to have major ramifications for surface ozone air quality. In our study, we examine two aspects of potential vegetation changes using the Community Earth System Model (CESM) in the fully coupled land-atmosphere configuration, and evaluate their implications on meteorology and air quality: 1) land use change, which alters the distribution of plant functional types and total leaf density; and 2) ozone damage on vegetation, which alters leaf density and physiology (e.g., stomatal resistance). We find that, following the RCP8.5 scenario for 2050, global cropland expansion induces only minor changes in surface ozone in tropical and subtropical regions, but statistically significant changes by up to +4 ppbv in midlatitude North America and East Asia, mostly due to higher surface temperature that enhances biogenic VOC emissions, and reduced dry deposition to a lesser degree. These changes are in turn to driven mostly by meteorological changes that include a shift from latent to sensible heat in the surface energy balance and reduced soil moisture, reflecting not only local responses but also a northward expansion of the Hadley Cell. On the other hand, ozone damage on vegetation driven by rising anthropogenic emissions is shown to induce a further enhancement of ozone by up to +6 ppbv in midlatitude regions by 2050. This reflects a strong localized positive feedback, with severe ozone damage in polluted regions generally inducing stomatal closure, which in turn reduces transpiration, increases

  3. Particle growth in an isoprene-rich forest: Influences of urban, wildfire, and biogenic air masses

    NASA Astrophysics Data System (ADS)

    Gunsch, Matthew J.; Schmidt, Stephanie A.; Gardner, Daniel J.; Bondy, Amy L.; May, Nathaniel W.; Bertman, Steven B.; Pratt, Kerri A.; Ault, Andrew P.

    2018-04-01

    Growth of freshly nucleated particles is an important source of cloud condensation nuclei (CCN) and has been studied within a variety of environments around the world. However, there remains uncertainty regarding the sources of the precursor gases leading to particle growth, particularly in isoprene-rich forests. In this study, particle growth events were observed from the 14 total events (31% of days) during summer measurements (June 24 - August 2, 2014) at the Program for Research on Oxidants PHotochemistry, Emissions, and Transport (PROPHET) tower within the forested University of Michigan Biological Station located in northern Michigan. Growth events were observed within long-range transported air masses from urban areas, air masses impacted by wildfires, as well as stagnant, forested/regional air masses. Growth events observed during urban-influenced air masses were prevalent, with presumably high oxidant levels, and began midday during periods of high solar radiation. This suggests that increased oxidation of biogenic volatile organic compounds (BVOCs) likely contributed to the highest observed particle growth in this study (8 ± 2 nm h-1). Growth events during wildfire-influenced air masses were observed primarily at night and had slower growth rates (3 ± 1 nm h-1). These events were likely influenced by increased SO2, O3, and NO2 transported within the smoke plumes, suggesting a role of NO3 oxidation in the production of semi-volatile compounds. Forested/regional air mass growth events likely occurred due to the oxidation of regionally emitted BVOCs, including isoprene, monoterpenes, and sesquiterpenes, which facilitated multiday growth events also with slower rates (3 ± 2 nm h-1). Intense sulfur, carbon, and oxygen signals in individual particles down to 20 nm, analyzed by transmission electron microscopy with energy dispersive X-ray spectroscopy (TEM-EDX), suggest that H2SO4 and secondary organic aerosol contributed to particle growth. Overall, aerosol

  4. A Numerical Model of Anisotropic Mass Transport Through Grain Boundary Networks

    NASA Astrophysics Data System (ADS)

    Wang, Yibo

    Tin (Sn) thin films are commonly used in electronic circuit applications as coatings on contacts and solders for joining components. It is widely observed, for some such system, that whiskers---long, thin crystalline structures---emerge and grow from the film. The Sn whisker phenomenon has become a highly active research area since Sn whiskers have caused a large amount of damage and loss in manufacturing, military, medical and power industries. Though lead (Pb) addition to Sn has been used to solve this problem for over five decades, the adverse environmental and health effects of Pb have motivated legislation to severely constrain Pb use in society. People are researching and seeking the reasons which cause whiskers and corresponding methods to solve the problem. The contributing factors to cause a Sn whisker are potentially many and much still remains unknown. Better understanding of fundamental driving forces should point toward strategies to improve (a) the accuracy with which we can predict whisker formation, and (b) our ability to mitigate the phenomenon. This thesis summarizes recent important research achievements in understanding Sn whisker formation and growth, both experimentally and theoretically. Focus is then placed on examining the role that anisotropy in grain boundary diffusivity plays in determining whisker characteristics (specifically, whether they form and, if so, where on a surface). To study this aspect of the problem and to enable future studies on stress driven grain boundary diffusion, this thesis presents a numerical anisotropic mass transport model. In addition to presenting details of the model and implementation, model predictions for a set of increasingly complex grain boundary networks are discussed. Preliminary results from the model provide evidence that anisotropic grain boundary diffusion may be a primary driving mechanism in whisker formation.

  5. The Atmospheric Boundary Layer

    ERIC Educational Resources Information Center

    Tennekes, Hendrik

    1974-01-01

    Discusses some important parameters of the boundary layer and effects of turbulence on the circulation and energy dissipation of the atmosphere. Indicates that boundary-layer research plays an important role in long-term forecasting and the study of air-pollution meteorology. (CC)

  6. Experimental Evaluation of the Effect of Angle-of-attack on the External Aerodynamics and Mass Capture of a Symmetric Three-engine Air-breathing Launch Vehicle Configuration at Supersonic Speeds

    NASA Technical Reports Server (NTRS)

    Kim, Hyun D.; Frate, Franco C.

    2001-01-01

    A subscale aerodynamic model of the GTX air-breathing launch vehicle was tested at NASA Glenn Research Center's 10- by 10-Foot Supersonic Wind Tunnel from Mach 2.0 to 3.5 at various angles-of-attack. The objective of the test was to investigate the effect of angle-of-attack on inlet mass capture, inlet diverter effectiveness, and the flowfield at the cowl lip plane. The flow-through inlets were tested with and without boundary-layer diverters. Quantitative measurements such as inlet mass flow rates and pitot-pressure distributions in the cowl lip plane are presented. At a 3deg angle-of-attack, the flow rates for the top and side inlets were within 8 percent of the zero angle-of-attack value, and little distortion was evident at the cowl lip plane. Surface oil flow patterns showing the shock/boundary-layer interaction caused by the inlet spikes are shown. In addition to inlet data, vehicle forebody static pressure distributions, boundary-layer profiles, and temperature-sensitive paint images to evaluate the boundary-layer transition are presented. Three-dimensional parabolized Navier-Stokes computational fluid dynamics calculations of the forebody flowfield are presented and show good agreement with the experimental static pressure distributions and boundary-layer profiles. With the boundary-layer diverters installed, no adverse aerodynamic phenomena were found that would prevent the inlets from operating at the required angles-of-attack. We recommend that phase 2 of the test program be initiated, where inlet contraction ratio and diverter geometry variations will be tested.

  7. Ecological response to collapse of the biological pump following the mass extinction at the Cretaceous-Paleogene boundary

    NASA Astrophysics Data System (ADS)

    Vellekoop, Johan; Woelders, Lineke; Açikalin, Sanem; Smit, Jan; van de Schootbrugge, Bas; Yilmaz, Ismail Ö.; Brinkhuis, Henk; Speijer, Robert P.

    2017-02-01

    It is commonly accepted that the mass extinction associated with the Cretaceous-Paleogene (K-Pg) boundary (˜ 66 Ma) is related to the environmental effects of a large extraterrestrial impact. The biological and oceanographic consequences of the mass extinction are, however, still poorly understood. According to the Living Ocean model, the biological crisis at the K-Pg boundary resulted in a long-term reduction of export productivity in the early Paleocene. Here, we combine organic-walled dinoflagellate cyst (dinocyst) and benthic foraminiferal analyses to provide new insights into changes in the coupling of pelagic and benthic ecosystems. To this end, we perform dinocyst and benthic foraminiferal analyses on the recently discovered Tethyan K-Pg boundary section at Okçular, Turkey, and compare the results with other K-Pg boundary sites in the Tethys. The post-impact dominance of epibenthic morphotypes and an increase of inferred heterotrophic dinocysts in the early Paleocene at Okçular are consistent with published records from other western Tethyan sites. Together, these records indicate that during the early Paleocene more nutrients remained available for the Tethyan planktonic community, whereas benthic communities were deprived of food. Hence, in the post-impact phase the reduction of export productivity likely resulted in enhanced recycling of nutrients in the upper part of the water column, all along the western Tethyan margins.

  8. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Role of mixed boundaries on flow in open capillary channels with curved air-water interfaces.

    PubMed

    Zheng, Wenjuan; Wang, Lian-Ping; Or, Dani; Lazouskaya, Volha; Jin, Yan

    2012-09-04

    Flow in unsaturated porous media or in engineered microfluidic systems is dominated by capillary and viscous forces. Consequently, flow regimes may differ markedly from conventional flows, reflecting strong interfacial influences on small bodies of flowing liquids. In this work, we visualized liquid transport patterns in open capillary channels with a range of opening sizes from 0.6 to 5.0 mm using laser scanning confocal microscopy combined with fluorescent latex particles (1.0 μm) as tracers at a mean velocity of ∼0.50 mm s(-1). The observed velocity profiles indicate limited mobility at the air-water interface. The application of the Stokes equation with mixed boundary conditions (i.e., no slip on the channel walls and partial slip or shear stress at the air-water interface) clearly illustrates the increasing importance of interfacial shear stress with decreasing channel size. Interfacial shear stress emerges from the velocity gradient from the adjoining no-slip walls to the center where flow is trapped in a region in which capillary forces dominate. In addition, the increased contribution of capillary forces (relative to viscous forces) to flow on the microscale leads to increased interfacial curvature, which, together with interfacial shear stress, affects the velocity distribution and flow pattern (e.g., reverse flow in the contact line region). We found that partial slip, rather than the commonly used stress-free condition, provided a more accurate description of the boundary condition at the confined air-water interface, reflecting the key role that surface/interface effects play in controlling flow behavior on the nanoscale and microscale.

  10. Utilization of satellite observation of ozone and aerosols in providing initial and boundary condition for regional air quality studies

    NASA Astrophysics Data System (ADS)

    Pour-Biazar, Arastoo; Khan, Maudood; Wang, Lihua; Park, Yun-Hee; Newchurch, Mike; McNider, Richard T.; Liu, Xiong; Byun, Daewon W.; Cameron, Robert

    2011-09-01

    To demonstrate the efficacy of satellite observations in the realization of the background and transboundary transport of pollution in regional air quality modeling practices, satellite observations of ozone and aerosol optical depth were incorporated in the EPA Models-3 Community Multiscale Air Quality (CMAQ) model (http://www.cmascenter.org). Observations from Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite and AOD products from the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Terra (EOS AM) and Aqua (EOS PM) satellites were used to specify initial and lateral boundary conditions (IC/BC) for a simulation that spanned over August 2006. The tools and techniques using the satellite data were tested in the context of current regulatory air quality modeling practices. Daily satellite observations were remapped onto the modeling domain and used as IC/BC for daily segments of a month-long simulation and the results were evaluated against surface and ozonesonde observations. Compared to the standard application of CMAQ, OMI O3 profiles significantly improved model performance in the free troposphere and MODIS aerosol products substantially improved PM2.5 predictions in the boundary layer. The utilization of satellite data for BC helped in the realization of transboundary transport of pollution and was able to explain the recirculation of pollution from Northeast Corridor to the southeastern region. Ozone in the mid- to upper-troposphere was largely dominated by transport and thus benefited most from satellite provided BC. The ozone within the boundary layer was mostly affected by fast production/loss mechanisms that are impacted by surface emissions, chemistry and removal processes and was not impacted as much. A case study for August 18-22 demonstrated that model errors in the placement of a stationary front were the main reason for errors in PM2.5 predictions as the front acted as a boundary between high and low PM2.5 concentrations.

  11. Development of an effusive inlet for mass spectrometric gas analysis of hypersonic boundary layer

    NASA Technical Reports Server (NTRS)

    Brown, Kenneth G.; Fishel, Charles E.; Brown, David R.; Lewis, Beverley W.; Wood, George M., Jr.

    1987-01-01

    The use of a microchannel plate (MCP) as a mass spectrometer inlet device to allow nonintrusive sampling of flight vehicle boundary layers is investigated. Two possible configurations for mounting the inlet are studied: (1) flow coaxial with the channels; and (2) flow perpendicular to the channel axis. The test gases are pure Kr; pure Ne; and a mixture of 10 pct Kr, 10 pct Ne, and 80 pct N2. The pressure ranges studied vary from 500 to 10 microns. A mass discrimination at the quadrupole mass spectrometer is observed, indicating an enrichment in the heavier gas. Possible explanations for this enrichment are discussed. It is shown that an MCP is capable of acting as a nonintrusive sampling device. Further work that will enable quantitative determination of the species at the surface is discussed.

  12. Finite-Difference Solution for Laminar or Turbulent Boundary Layer Flow over Axisymmetric Bodies with Ideal Gas, CF4, or Equilibrium Air Chemistry

    NASA Technical Reports Server (NTRS)

    Hamilton, H. Harris, II; Millman, Daniel R.; Greendyke, Robert B.

    1992-01-01

    A computer code was developed that uses an implicit finite-difference technique to solve nonsimilar, axisymmetric boundary layer equations for both laminar and turbulent flow. The code can treat ideal gases, air in chemical equilibrium, and carbon tetrafluoride (CF4), which is a useful gas for hypersonic blunt-body simulations. This is the only known boundary layer code that can treat CF4. Comparisons with experimental data have demonstrated that accurate solutions are obtained. The method should prove useful as an analysis tool for comparing calculations with wind tunnel experiments and for making calculations about flight vehicles where equilibrium air chemistry assumptions are valid.

  13. Finite-difference solution for laminar or turbulent boundary layer flow over axisymmetric bodies with ideal gas, CF4, or equilibrium air chemistry

    NASA Astrophysics Data System (ADS)

    Hamilton, H. Harris, II; Millman, Daniel R.; Greendyke, Robert B.

    1992-12-01

    A computer code was developed that uses an implicit finite-difference technique to solve nonsimilar, axisymmetric boundary layer equations for both laminar and turbulent flow. The code can treat ideal gases, air in chemical equilibrium, and carbon tetrafluoride (CF4), which is a useful gas for hypersonic blunt-body simulations. This is the only known boundary layer code that can treat CF4. Comparisons with experimental data have demonstrated that accurate solutions are obtained. The method should prove useful as an analysis tool for comparing calculations with wind tunnel experiments and for making calculations about flight vehicles where equilibrium air chemistry assumptions are valid.

  14. Low-CCN concentration air masses over the eastern North Atlantic: Seasonality, meteorology, and drivers

    NASA Astrophysics Data System (ADS)

    Wood, Robert; Stemmler, Jayson D.; Rémillard, Jasmine; Jefferson, Anne

    2017-01-01

    A 20 month cloud condensation nucleus concentration (NCCN) data set from Graciosa Island (39°N, 28°W) in the remote North Atlantic is used to characterize air masses with low cloud condensation nuclei (CCN) concentrations. Low-CCN events are defined as 6 h periods with mean NCCN<20 cm-3 (0.1% supersaturation). A total of 47 low-CCN events are identified. Surface, satellite, and reanalysis data are used to explore the meteorological and cloud context for low-CCN air masses. Low-CCN events occur in all seasons, but their frequency was 3 times higher in December-May than during June-November. Composites show that many of the low-CCN events had a common meteorological basis that involves southerly low-level flow and rather low wind speeds at Graciosa. Anomalously low pressure is situated to the west of Graciosa during these events, but back trajectories and lagged SLP composites indicate that low-CCN air masses often originate as cold air outbreaks to the north and west of Graciosa. Low-CCN events were associated with low cloud droplet concentrations (Nd) at Graciosa, but liquid water path (LWP) during low-CCN events was not systematically different from that at other times. Satellite Nd and LWP estimates from MODIS collocated with Lagrangian back trajectories show systematically lower Nd and higher LWP several days prior to arrival at Graciosa, consistent with the hypothesis that observed low-CCN air masses are often formed by coalescence scavenging in thick warm clouds, often in cold air outbreaks.

  15. Effects of partial slip boundary condition and radiation on the heat and mass transfer of MHD-nanofluid flow

    NASA Astrophysics Data System (ADS)

    Abd Elazem, Nader Y.; Ebaid, Abdelhalim

    2017-12-01

    In this paper, the effect of partial slip boundary condition on the heat and mass transfer of the Cu-water and Ag-water nanofluids over a stretching sheet in the presence of magnetic field and radiation. Such partial slip boundary condition has attracted much attention due to its wide applications in industry and chemical engineering. The flow is basically governing by a system of partial differential equations which are reduced to a system of ordinary differential equations. This system has been exactly solved, where exact analytical expression has been obtained for the fluid velocity in terms of exponential function, while the temperature distribution, and the nanoparticles concentration are expressed in terms of the generalized incomplete gamma function. In addition, explicit formulae are also derived from the rates of heat transfer and mass transfer. The effects of the permanent parameters on the skin friction, heat transfer coefficient, rate of mass transfer, velocity, the temperature profile, and concentration profile have been discussed through tables and graphs.

  16. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2016-10-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  17. Identification of free tropospheric air masses at the new Mt. Bachelor, Oregon observatory

    NASA Astrophysics Data System (ADS)

    Swarzendruber, P.; Weiss-Penzias, P.; Dennison, J.; Prestbo, E.; Jaffe, D.

    2004-12-01

    In February 2004, we established a new atmospheric observatory on the summit of Mt. Bachelor, Oregon in order to better understand the long range transport of chemicals and anthropogenic pollutants to North America. Previous work on the inflow to the Pacific Northwest (Weiss-Penzias 2004, 2003, Jaffe 2003) has been able to identify Asian influence on a costal site, but aircraft observations (Price et al. 2003, Kotchenruther et al 2001) and modeling work (Jaegle et al. 2003) have shown that transport events are much more frequent in the free troposphere. The detection of these pollution plumes in the planetary boundary layer is greatly complicated by the turbulent meteorology and complex chemistry of the boundary layer. The Mt. Bachelor Observatory (MBO) ( 2.7 km a.s.l.) was established to allow for continuous sampling at a site that likely experiences free tropospheric air a majority of the time. In order to help understand the influence of the boundary layer on the spring 2004 MBO observations, we have conducted a meteorological analysis for this period using several measured and modeled parameters. Our initial analysis of virtual soundings generated by the mesoscale NWP model, MM5 (University of Washington, Seattle), and of measured water vapor content, indicate that during the spring campaign (Mar-May), on at least 50% of the days, the daytime mixed layer height did not reach MBO before beginning to collapse at sunset into a shallow night time boundary layer. Thus, for the spring of 2004, we conclude that MBO experienced free-tropospheric air for more than 50% of the time; however, this is likely a lower limit. An objective analysis of water vapor and wind measurements with the goal of further improving the diagnosis of boundary layer influence will be presented along with their application to several long-range transport episodes at MBO. Additional measurements to be made at the site will hopefully allow us to make a more accurate assessment of the boundary

  18. The influence of continental air masses on the aerosols and nutrients deposition over the western North Pacific

    NASA Astrophysics Data System (ADS)

    Fu, Jiangping; Wang, Bo; Chen, Ying; Ma, Qingwei

    2018-01-01

    The air masses transported from East Asia have a strong impact on the aerosol properties and deposition in the marine boundary layer of the western North Pacific (WNP) during winter and spring. We joined a cruise between 17 Mar. and 22 Apr. 2014 and investigated the changes of aerosol composition and size distribution over the remote WNP and marginal seas. Although the secondary aerosol species (SO42-, NO3- and NH4+) in remote WNP were influenced significantly by the continental transport, NH4+ concentrations were lower than 2.7 μg m-3 in most sampling days and not correlated with non-sea-salt (nss)-SO42- suggesting that the ocean could be a primary source of NH4+. Moderate Cl- depletion (23%) was observed in remote WNP, and the inverse relationship between Cl- depletion percentages and nss-K+ in aerosols suggested that the transport of biomass burning smoke from East Asia might be a vital extra source of Cl-. Both Asian dust and haze events were encountered during the cruise. Asian dust carried large amounts of crustal elements such as Al and Ti to the WNP, and the dusty Fe deposition may double its background concentration in seawater. Differently, a dramatic increase of dry deposition flux of dissolved particulate inorganic nitrogen was observed during the haze event. Our study reveals that the transport of different continental air masses may have distinct biogeochemical impacts on the WNP by increasing the fluxes of different nutrient elements and potentially changing the nutrient stoichiometry.

  19. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    PubMed

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  20. Exposure chamber measurements of mass transfer and partitioning at the plant/air interface.

    PubMed

    Maddalena, Randy L; McKone, Thomas E; Kado, Norman Y

    2002-08-15

    Dynamic measures of air and vegetation concentrations in an exposure chamber and a two-box mass balance model are used to quantify factors that control the rate and extent of chemical partitioning between vegetation and the atmosphere. A continuous stirred flow-through exposure chamber was used to investigate the gas-phase transfer of pollutants between air and plants. A probabilistic two-compartment mass balance model of plant/air exchange within the exposure chamber was developed and used with measured concentrations from the chamber to simultaneously evaluate partitioning (Kpa), overall mass transfer across the plant/air interface (Upa), and loss rates in the atmosphere (Ra) and aboveground vegetation (Rp). The approach is demonstrated using mature Capsicum annuum (bell pepper) plants exposed to phenanthrene (PH), anthracene (AN), fluoranthene (FL) and pyrene (PY). Measured values of log Kpa (V[air]/V[fresh plant]) were 5.7, 5.7, 6.0, and 6.2 for PH, AN, FL, and PY, respectively. Values of Upa (m d(-1)) under the conditions of this study ranged from 42 for PH to 119 for FL. After correcting for wall effects, the estimated reaction half-lives in air were 3, 9, and 25 h for AN, FL and PY. Reaction half-lives in the plant compartment were 17, 6, 17, and 5 d for PH, AN, FL, and PY, respectively. The combined use of exposure chamber measurements and models provides a robust tool for simultaneously measuring several different transfer factors that are important for modeling the uptake of pollutants into vegetation.

  1. A Wind-Tunnel Parametric Investigation of Tiltrotor Whirl-Flutter Stability Boundaries

    NASA Technical Reports Server (NTRS)

    Piatak, David J.; Kvaternik, Raymond G.; Nixon, Mark W.; Langston, Chester W.; Singleton, Jeffrey D.; Bennett, Richard L.; Brown, Ross K.

    2001-01-01

    A wind-tunnel investigation of tiltrotor whirl-flutter stability boundaries has been conducted on a 1/5-size semispan tiltrotor model known as the Wing and Rotor Aeroelastic Test System (WRATS) in the NASA-Langley Transonic Dynamics Tunnel as part of a joint NASA/Army/Bell Helicopter Textron, Inc. (BHTI) research program. The model was first developed by BHTI as part of the JVX (V-22) research and development program in the 1980's and was recently modified to incorporate a hydraulically-actuated swashplate control system for use in active controls research. The modifications have changed the model's pylon mass properties sufficiently to warrant testing to re-establish its baseline stability boundaries. A parametric investigation of the effect of rotor design variables on stability was also conducted. The model was tested in both the on-downstop and off-downstop configurations, at cruise flight and hover rotor rotational speeds, and in both air and heavy gas (R-134a) test mediums. Heavy gas testing was conducted to quantify Mach number compressibility effects on tiltrotor stability. Experimental baseline stability boundaries in air are presented with comparisons to results from parametric variations of rotor pitch-flap coupling and control system stiffness. Increasing the rotor pitch-flap coupling (delta(sub 3) more negative) was found to have a destabilizing effect on stability, while a reduction in control system stiffness was found to have little effect on whirl-flutter stability. Results indicate that testing in R-134a, and thus matching full-scale tip Mach number, has a destabilizing effect, which demonstrates that whirl-flutter stability boundaries in air are unconservative.

  2. Variation of turbulence in a coastal thermal internal boundary layer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    SethuRaman, S.; Raynor, G.S.; Brown, R.M.

    1981-01-01

    Internal boundary layers (IBL) form when an air mass encounters a change in surface characteristics. There are essentially two types of internal boundary layers - one caused by the change in surface roughness and the other by the variation in surface heating. The former is known as the aerodynamic internal boundary layer (AIBL) and the latter the thermal internal boundary layer (TIBL). Change in shear stress generally characterizes the AIBL and change in turbulence the TIBL. Results of some observations of the vertical component of turbulence made in a coastal TIBL over Long Island, New York from 1974 to 1978more » are reported. Vertical turbulence measured by a simple sail plane variometer in a thermal internal boundary layer over Long Island with onshore flows indicates the structure to depend significantly on the land-water temperature difference. The position of the vertical velocity fluctuation maximum seems to vary from one test to another but its variation could not be correlated to other parameters due to lack of a sufficient number of tests. The structure of vertical turbulence was found to be different for sea breeze flows as compared to gradient winds.« less

  3. Shuttle Damage/Repair from the Perspective of Hypersonic Boundary Layer Transition - Experimental Results

    NASA Technical Reports Server (NTRS)

    Horvath, Thomas J.; Berry, Scott A.; Merski, N. Ronald; Berger, Karen T.; Buck, Gregory M.; Liechty, Derek S.; Schneider, Steven P.

    2006-01-01

    An overview is provided of the experimental wind tunnel program conducted at the NASA Langley Research Center Aerothermodynamics Laboratory in support of an agency-wide effort to prepare the Shuttle Orbiter for Return-to-Flight. The effect of an isolated protuberance and an isolated rectangular cavity on hypersonic boundary layer transition onset on the windward surface of the Shuttle Orbiter has been experimentally characterized. These experimental studies were initiated to provide a protuberance and cavity effects database for developing hypersonic transition criteria to support on-orbit disposition of thermal protection system damage or repair. In addition, a synergistic experimental investigation was undertaken to assess the impact of an isolated mass-flow entrainment source (simulating pyrolysis/outgassing from a proposed tile repair material) on boundary layer transition. A brief review of the relevant literature regarding hypersonic boundary layer transition induced from cavities and localized mass addition from ablation is presented. Boundary layer transition results were obtained using 0.0075-scale Orbiter models with simulated tile damage (rectangular cavities) of varying length, width, and depth and simulated tile damage or repair (protuberances) of varying height. Cavity and mass addition effects were assessed at a fixed location (x/L = 0.3) along the model centerline in a region of near zero pressure gradient. Cavity length-to-depth ratio was systematically varied from 2.5 to 17.7 and length-to-width ratio of 1 to 8.5. Cavity depth-to-local boundary layer thickness ranged from 0.5 to 4.8. Protuberances were located at several sites along the centerline and port/starboard attachment lines along the chine and wing leading edge. Protuberance height-to-boundary layer thickness was varied from approximately 0.2 to 1.1. Global heat transfer images and heating distributions of the Orbiter windward surface using phosphor thermography were used to infer the

  4. A model of the planetary boundary layer over a snow surface

    NASA Technical Reports Server (NTRS)

    Halberstam, I.; Melendez, R.

    1979-01-01

    A model of the planetary boundary layer over a snow surface has been developed. It contains the vertical heat exchange processes due to radiation, conduction, and atmospheric turbulence. Parametrization of the boundary layer is based on similarity functions developed by Hoffert and Sud (1976), which involve a dimensionless variable, dependent on boundary-layer height and a localized Monin-Obukhov length. The model also contains the atmospheric surface layer and the snowpack itself, where snowmelt and snow evaporation are calculated. The results indicate a strong dependence of surface temperatures, especially at night, on the bursts of turbulence which result from the frictional damping of surface-layer winds during periods of high stability, as described by Businger (1973). The model also shows the cooling and drying effect of the snow on the atmosphere, which may be the mechanism for air mass transformation in sub-Arctic regions.

  5. Analytic prediction of unconfined boundary layer flashback limits in premixed hydrogen-air flames

    NASA Astrophysics Data System (ADS)

    Hoferichter, Vera; Hirsch, Christoph; Sattelmayer, Thomas

    2017-05-01

    Flame flashback is a major challenge in premixed combustion. Hence, the prediction of the minimum flow velocity to prevent boundary layer flashback is of high technical interest. This paper presents an analytic approach to predicting boundary layer flashback limits for channel and tube burners. The model reflects the experimentally observed flashback mechanism and consists of a local and global analysis. Based on the local analysis, the flow velocity at flashback initiation is obtained depending on flame angle and local turbulent burning velocity. The local turbulent burning velocity is calculated in accordance with a predictive model for boundary layer flashback limits of duct-confined flames presented by the authors in an earlier publication. This ensures consistency of both models. The flame angle of the stable flame near flashback conditions can be obtained by various methods. In this study, an approach based on global mass conservation is applied and is validated using Mie-scattering images from a channel burner test rig at ambient conditions. The predicted flashback limits are compared to experimental results and to literature data from preheated tube burner experiments. Finally, a method for including the effect of burner exit temperature is demonstrated and used to explain the discrepancies in flashback limits obtained from different burner configurations reported in the literature.

  6. Markers for Chinese and Korean Air Masses: Halocarbons and Other Trace Gases Measured During KORUS-AQ

    NASA Astrophysics Data System (ADS)

    Blake, N. J.; Blake, D. R.; Meinardi, S.; Simpson, I. J.; Hughes, S.; Barletta, B.; Fleming, L.; Vizenor, N.; Schroeder, J.; Emmons, L. K.; Knote, C. J.

    2017-12-01

    The UC-Irvine Whole Air Sampler (WAS) collected a total of 2650 samples aboard the NASA DC-8 aircraft in support of the May-June 2016 field deployment phase of the KORUS-AQ mission: An International Cooperative Air Quality Field Study in Korea. Here we employ our trace gas measurements, along with CAM-chem tracers and back-trajectories to identify source regions during KORUS-AQ, with a focus on air masses which indicate Chinese and/or Korean origin. During KORUS-AQ we flew mostly over and around the Korean Peninsula with the intent of characterising Korean sources, but Chinese influence was observed offshore near the surface of the West Sea during several KORUS-AQ flights - in accord with forecast predictions from CAM-chem model runs. Unlike previous missions in the Asian region such as TRACE-P (2001), we found that halon-1211 (H-1211) is no longer a useful indicator of air masses from China because of production decline. By contrast, mixing ratios of the long-lived halocarbons carbon tetrachloride (CCl4) and chlorofluorocarbon-113 (CFC-113) were more strongly enhanced in air masses intercepted from China compared to Korea. We will use these tracers, the shorter-lived halocarbons, dichloromethane (CH2Cl2) and methyl chloride (CH3Cl), as well as the sulfur gas carbonyl sulfide (COS) and others, to characterize different regional air mass origins and their sources.

  7. Influence of relative air/water flow velocity on oxygen mass transfer in gravity sewers.

    PubMed

    Carrera, Lucie; Springer, Fanny; Lipeme-Kouyi, Gislain; Buffiere, Pierre

    2017-04-01

    Problems related to hydrogen sulfide may be serious for both network stakeholders and the public in terms of health, sustainability of the sewer structure and urban comfort. H 2 S emission models are generally theoretical and simplified in terms of environmental conditions. Although air transport characteristics in sewers must play a role in the fate of hydrogen sulfide, only a limited number of studies have investigated this issue. The aim of this study was to better understand H 2 S liquid to gas transfer by highlighting the link between the mass transfer coefficient and the turbulence in the air flow and the water flow. For experimental safety reasons, O 2 was taken as a model compound. The oxygen mass transfer coefficients were obtained using a mass balance in plug flow. The mass transfer coefficient was not impacted by the range of the interface air-flow velocity values tested (0.55-2.28 m·s -1 ) or the water velocity values (0.06-0.55 m·s -1 ). Using the ratio between k L,O 2 to k L,H 2 S , the H 2 S mass transfer behavior in a gravity pipe in the same hydraulic conditions can be predicted.

  8. Nine years of mass transport data in the eastern boundary of the North Atlantic Subtropical Gyre

    NASA Astrophysics Data System (ADS)

    Fraile-Nuez, Eugenio; MachíN, Francisco; VéLez-Belchí, Pedro; López-Laatzen, Federico; Borges, Rafael; BeníTez-Barrios, Verónica; HernáNdez-Guerra, Alonso

    2010-09-01

    One of the longest current meter time series in the Lanzarote Passage in the eastern boundary of the North Atlantic Subtropical Gyre has been used to determine and quantify the 9-year mean transport, the inter-annual and seasonal mass transport variability for the three water masses present in the area. Results show North Atlantic Central Water (NACW) flowing southward in the upper levels with a mean mass transport of -0.81 ± 1.48 Sv, Antarctic Intermediate Water (AAIW) flowing northward at intermediate levels with a mean transport of +0.09 ± 0.57 Sv and Mediterranean Water (MW) flowing southward in the deep part of the passage with a mean transport of -0.05 ± 0.17 Sv. Harmonic and wavelet analysis show the presence of a seasonal pattern in the passage for the three water masses. A maximum southward transport in winter and spring has been observed for the NACW followed by a minimum in summer and fall. Near zero values during winter and spring are found for AAIW, with a maximum northward value in summer and a negative value in fall, when this water mass reverses its flow. MW has a similar seasonal pattern to NACW. The vertical structure in the Lanzarote Passage can be approximated by four significant oscillatory modes which cumulatively explain 86.4% of the variance. The strong transport fluctuation found at the seasonal and inter-annual timescales demonstrates that the Eastern Boundary Current transport has a strong impact on meridional overturning estimates, thus indicating that to understand Meridional Overturning Circulation variability, these transport estimates at the eastern Atlantic margin are necessary.

  9. Vertical structure of boundary layer convection during cold-air outbreaks at Barrow, Alaska

    NASA Astrophysics Data System (ADS)

    Wang, Yonggang; Geerts, Bart; Chen, Yaosheng

    2016-01-01

    Boundary layer convection (BLC) is common over high-latitude oceans and adjacent coastal regions when a cold airmass becomes exposed to a sufficient fetch of open water. The vertical structure of mixed-phase BLC clouds and precipitation is examined using the Atmospheric Radiation Measurement Program data set collected at the North Slope of Alaska (NSA) site at Barrow, Alaska. BLC may occur at this location in autumn, when cold air masses originating at higher latitudes advect southward over the still ice-free coastal waters north of Alaska. This study identifies such BLC and documents its occurrence and characteristics. Instruments used for this study include profiling Ka band radars, a depolarization backscatter profiling lidar, a scanning X band radar, a microwave radiometer, a ceilometer, surface meteorological probes, and radiosondes. Six criteria are applied to objectively identify the BLC events, using data collected between 2004 and 2013. BLC episodes are relatively common at the NSA site, but almost exclusively in the month of October, and most episodes are relatively short, less than 10 h in duration. Liquid water is commonly found in these mixed-phase BLC clouds, with a typical liquid water path of 150 g/m2, and snowfall rates average ~3 mm h-1 (water equivalent), in some cases over 10 mm h-1, notwithstanding the low cloud echo tops (~1.0-1.5 km). In one rather weak but persistent episode fall speed estimates derived from the profiling Ka band radar indicates the presence of rimed particles, confirming the convective nature of this precipitation.

  10. Relating Aerosol Mass and Optical Depth in the Summertime Continental Boundary Layer

    NASA Astrophysics Data System (ADS)

    Brock, C. A.; Wagner, N.; Middlebrook, A. M.; Attwood, A. R.; Washenfelder, R. A.; Brown, S. S.; McComiskey, A. C.; Gordon, T. D.; Welti, A.; Carlton, A. G.; Murphy, D. M.

    2014-12-01

    Aerosol optical depth (AOD), the column-integrated ambient aerosol light extinction, is determined from satellite and ground-based remote sensing measurements. AOD is the parameter most often used to validate earth system model simulations of aerosol mass. Relating aerosol mass to AOD, however, is problematic due to issues including aerosol water uptake as a function of relative humidity (RH) and the complicated relationship between aerosol physicochemical properties and light extinction. Measurements of aerosol microphysical, chemical, and optical properties help to constrain the relationship between aerosol mass and optical depth because aerosol extinction at ambient RH is a function of the abundance, composition and size distribution of the aerosol. We use vertical profiles of humidity and dry aerosol extinction observed in the southeastern United States (U.S.) to examine the relationship between submicron aerosol mass concentration and extinction at ambient RH. We show that the κ-Köhler parameterization directly, and without additional Mie calculations, describes the change in extinction with varying RH as a function of composition for both aged aerosols typical of the polluted summertime continental boundary layer and the biomass burning aerosols we encountered. We calculate how AOD and the direct radiative effect in the eastern U.S. have likely changed due to trends in aerosol composition in recent decades. We also examine the sensitivity of AOD to the RH profile and to aerosol composition, size distribution and abundance.

  11. Impacts of synoptic condition and planetary boundary layer structure on the trans-boundary aerosol transport from Beijing-Tianjin-Hebei region to northeast China

    NASA Astrophysics Data System (ADS)

    Miao, Yucong; Guo, Jianping; Liu, Shuhua; Zhao, Chun; Li, Xiaolan; Zhang, Gen; Wei, Wei; Ma, Yanjun

    2018-05-01

    The northeastern China frequently experiences severe aerosol pollution in winter under unfavorable meteorological conditions. How and to what extent the meteorological factors affect the air quality there are not yet clearly understood. Thus, this study investigated the impacts of synoptic patterns on the aerosol transport and planetary boundary layer (PBL) structure in Shenyang from 1 to 3 December 2016, using surface observations, sounding measurements, satellite data, and three-dimensional simulations. Results showed that the aerosol pollution occurred in Shenyang was not only related to the local emissions, but also contributed by trans-boundary transport of aerosols from the Beiijng-Tianjin-Hebei (BTH) region. In the presence of the westerly and southwesterly synoptic winds, the aerosols emitted from BTH could be brought to Shenyang. From December 2 to 3, the aerosols emitted from BTH accounted for ∼20% of near-surface PM2.5 in Shenyang. In addition, the large-scale synoptic forcings could affect the vertical mixing of pollutants through modulating the PBL structure in Shenyang. The westerly and southwesterly synoptic winds not only brought the aerosols but also the warmer air masses from the southwest regions to Shenyang. The strong warm advections above PBL could enhance the already existing thermal inversion layers capping over PBL in Shenyang, leading to the suppressions of PBL. Both the trans-boundary transport of aerosols and the suppressions of PBL caused by the large-scale synoptic forcings should be partly responsible for the poor air quality in Shenyang, in addition to the high pollutant emissions. The present study revealed the physical mechanisms underlying the aerosol pollution in Shenyang, which has important implications for better forecasting and controlling the aerosols pollution.

  12. On optical imaging through aircraft turbulent boundary layers

    NASA Technical Reports Server (NTRS)

    Sutton, G. W.

    1980-01-01

    Optical resolution quality as affected by aircraft turbulent boundary layers is analyzed. Wind-tunnel data was analyzed to obtained the variation of boundary layer turbulence scale length and mass density rms fluctuations with Mach number. The data gave good agreement with a mass density fluctuation turbulence spectrum that is either isotropic of orthogonally anisotropic. The data did not match an isotropic turbulence velocity spectrum which causes an anisotropic non-orthogonal mass density fluctuation spectrum. The results indicate that the average mass density rms fluctuation is about 10% of the maximum mass density across the boundary layer and that the transverse turbulence scale size is about 10% of the boundary layer thickness. The results indicate that the effect of the turbulent boundary layer is large angle scattering which decreases contrast but not resolution. Using extinction as a criteria the range of acceptable aircraft operating conditions are given.

  13. Latex paint as a delivery vehicle for diethylphthalate and di-n-butylphthalate: predictable boundary layer concentrations and emission rates.

    PubMed

    Schripp, Tobias; Salthammer, Tunga; Fauck, Christian; Bekö, Gabriel; Weschler, Charles J

    2014-10-01

    The description of emission processes of volatile and semi-volatile organic compounds (VOCs and SVOCs) from building products requires a detailed understanding of the material and the air flow conditions at the surface boundary. The mass flux between the surface of the material and air depends on the mass transfer coefficient (hm) through the boundary layer, the gas phase concentration of the target compound immediately adjacent to the material (y0), and the gas-phase concentration in bulk air (y(t)). In the present study emission experiments were performed in two chambers of quite different sizes (0.25 m(3) and 55 m(3)), and, in the larger chamber, at two different temperatures (23°C and 30°C). The emitting material was latex wall paint that had been doped with two plasticizers, diethylphthalate (DEP) and di-n-butylphthalate (DnBP). The phthalate content in the paint was varied in the small chamber experiment to evaluate the impact of the initial concentration in the bulk material (C0) on the emission rate. Boundary layer theory was applied to calculate hm for the specific phthalates from the Sherwood number (Sh) and the diffusion coefficient (Dair). Then y0 was determined based on the bulk gas-phase concentration at steady state (y¯). For both, DEP and DnBP, the y0 obtained was lower than the respective saturation vapor pressure (Ps). Furthermore, for both phthalates in latex paint, the material/air partition coefficient (C0/y0) was close in value to the octanol/air partition coefficient (KOA). This study provides a basis for designing phthalate emitting reference materials that mimic the emission behavior of common building materials. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Measurement of the oxygen mass transfer through the air-water interface.

    PubMed

    Mölder, Erik; Mashirin, Alelxei; Tenno, Toomas

    2005-01-01

    Gas mass transfer through the liquid-gas interface has enormous importance in various natural and industrial processes. Surfactants or insoluble compounds adsorbed onto an interface will inhibit the gas mass transfer through the liquid-gas surface. This study presents a technique for measuring the oxygen mass transfer through the air-water interface. Experimental data obtained with the measuring device were incorporated into a novel mathematical model, which allowed one to calculate diffusion conduction of liquid surface layer and oxygen mass transfer coefficient in the liquid surface layer. A special measurement cell was constructed. The most important part of the measurement cell is a chamber containing the electrochemical oxygen sensor inside it. Gas exchange between the volume of the chamber and the external environment takes place only through the investigated surface layer. Investigated liquid was deoxygenated, which triggers the oxygen mass transfer from the chamber through the liquid-air interface into the liquid phase. The decrease of oxygen concentration in the cell during time was measured. By using this data it is possible to calculate diffusional parameters of the water surface layer. Diffusion conduction of oxygen through the air-water surface layer of selected wastewaters was measured. The diffusion conduction of different wastewaters was about 3 to 6 times less than in the unpolluted water surface. It was observed that the dilution of wastewater does not have a significant impact on the oxygen diffusion conduction through the wastewater surface layer. This fact can be explained with the presence of the compounds with high surface activity in the wastewater. Surfactants achieved a maximum adsorption and, accordingly, the maximum decrease of oxygen permeability already at a very low concentration of surfactants in the solution. Oxygen mass transfer coefficient of the surface layer of the water is found to be Ds/ls = 0.13 x 10(-3) x cm/s. A simple

  15. Combined effect of boundary layer recirculation factor and stable energy on local air quality in the Pearl River Delta over southern China.

    PubMed

    Li, Haowen; Wang, Baomin; Fang, Xingqin; Zhu, Wei; Fan, Qi; Liao, Zhiheng; Liu, Jian; Zhang, Asi; Fan, Shaojia

    2018-03-01

    Atmospheric boundary layer (ABL) has a significant impact on the spatial and temporal distribution of air pollutants. In order to gain a better understanding of how ABL affects the variation of air pollutants, atmospheric boundary layer observations were performed at Sanshui in the Pearl River Delta (PRD) region over southern China during the winter of 2013. Two types of typical ABL status that could lead to air pollution were analyzed comparatively: weak vertical diffusion ability type (WVDAT) and weak horizontal transportation ability type (WHTAT). Results show that (1) WVDAT was featured by moderate wind speed, consistent wind direction, and thick inversion layer at 600~1000 m above ground level (AGL), and air pollutants were restricted in the low altitudes due to the stable atmospheric structure; (2) WHTAT was characterized by calm wind, varied wind direction, and shallow intense ground inversion layer, and air pollutants accumulated in locally because of strong recirculation in the low ABL; (3) recirculation factor (RF) and stable energy (SE) were proved to be good indicators for horizontal transportation ability and vertical diffusion ability of the atmosphere, respectively. Combined utilization of RF and SE can be very helpful in the evaluation of air pollution potential of the ABL. Air quality data from ground and meteorological data collected from radio sounding in Sanshui in the Pearl River Delta showed that local air quality was poor when wind reversal was pronounced or temperature stratification state was stable. The combination of horizontal and vertical transportation ability of the local atmosphere should be taken into consideration when evaluating local environmental bearing capacity for air pollution.

  16. Numerical analysis of heat and mass transfer for water recovery in an evaporative cooling tower

    NASA Astrophysics Data System (ADS)

    Lee, Hyunsub; Son, Gihun

    2017-11-01

    Numerical analysis is performed for water recovery in an evaporative cooling tower using a condensing heat exchanger, which consists of a humid air channel and an ambient dry air channel. The humid air including water vapor produced in an evaporative cooling tower is cooled by the ambient dry air so that the water vapor is condensed and recovered to the liquid water. The conservation equations of mass, momentum, energy and vapor concentration in each fluid region and the energy equation in a solid region are simultaneously solved with the heat and mass transfer boundary conditions coupled to the effect of condensation on the channel surface of humid air. The present computation demonstrates the condensed water film distribution on the humid air channel, which is caused by the vapor mass transfer between the humid air and the colder water film surface, which is coupled to the indirect heat exchange with the ambient air. Computations are carried out to predict water recovery rate in parallel, counter and cross-flow type heat exchangers. The effects of air flow rate and channel interval on the water recovery rate are quantified.

  17. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

    2014-01-01

    The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

  18. A Comparison of Active and Passive Methods for Control of Hypersonic Boundary Layers on Airbreathing Configurations

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; Nowak, Robert J.

    2003-01-01

    Active and passive methods for control of hypersonic boundary layers have been experimentally examined in NASA Langley Research Center wind tunnels on a Hyper-X model. Several configurations for forcing transition using passive discrete roughness elements and active mass addition, or blowing, methods were compared in two hypersonic facilities, the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air tunnels. Heat transfer distributions, obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the nominal Mach 7 flight trajectory of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For the passive roughness examination, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The prior passive roughness study resulted in a swept ramp configuration being selected for the Mach 7 flight vehicle that was scaled to be roughly 0.6 of the calculated boundary layer thickness. For the active jet blowing study, the blowing manifold pressure was systematically varied for each configuration, while monitoring the mass flow, to determine the jet penetration height with schlieren and transition movement with the phosphor system for comparison to the passive results. All the blowing concepts tested were adequate for providing transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model static pressure or higher.

  19. Characterising terrestrial influences on Antarctic air masses using Radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-09-01

    We report on one year of high-precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late-summer to 44 mBq m-3 in late winter and early spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  20. Characterising terrestrial influences on Antarctic air masses using radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-05-01

    We report on one year of high precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late summer to 44 mBq m-3 in late-winter and early-spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  1. An efficient strongly coupled immersed boundary method for deforming bodies

    NASA Astrophysics Data System (ADS)

    Goza, Andres; Colonius, Tim

    2016-11-01

    Immersed boundary methods treat the fluid and immersed solid with separate domains. As a result, a nonlinear interface constraint must be satisfied when these methods are applied to flow-structure interaction problems. This typically results in a large nonlinear system of equations that is difficult to solve efficiently. Often, this system is solved with a block Gauss-Seidel procedure, which is easy to implement but can require many iterations to converge for small solid-to-fluid mass ratios. Alternatively, a Newton-Raphson procedure can be used to solve the nonlinear system. This typically leads to convergence in a small number of iterations for arbitrary mass ratios, but involves the use of large Jacobian matrices. We present an immersed boundary formulation that, like the Newton-Raphson approach, uses a linearization of the system to perform iterations. It therefore inherits the same favorable convergence behavior. However, we avoid large Jacobian matrices by using a block LU factorization of the linearized system. We derive our method for general deforming surfaces and perform verification on 2D test problems of flow past beams. These test problems involve large amplitude flapping and a wide range of mass ratios. This work was partially supported by the Jet Propulsion Laboratory and Air Force Office of Scientific Research.

  2. Installation Boundary Fence Replacement: Upland Areas: Environmental Assessment

    DTIC Science & Technology

    2004-05-27

    Moody Air Force Base, GA Environmental Assessment Installation Boundary Fence Replacement INSTALLATION BOUNDARY...347 CES/CEV),3485 Georgia Street,Moody AFB, GA ,31699 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES...Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18 Moody Air Force Base, GA Environmental Assessment

  3. Boundary layer analysis in turbulent Rayleigh-Bénard convection in air: experiment versus simulation.

    PubMed

    Li, Ling; Shi, Nan; du Puits, Ronald; Resagk, Christian; Schumacher, Jörg; Thess, André

    2012-08-01

    We report measurements and numerical simulations of the three-dimensional velocity and temperature fields in turbulent Rayleigh-Bénard convection in air. Highly resolved velocity and temperature measurements inside and outside the boundary layers have been directly compared with equivalent data obtained in direct numerical simulations (DNSs). This comparison comprises a set of two Rayleigh numbers at Ra=3×10(9) and 3×10(10) and a fixed aspect ratio; this is the ratio between the diameter and the height of the Rayleigh-Bénard cell of Γ=1. We find that the measured velocity data are in excellent agreement with the DNS results while the temperature data slightly differ. In particular, the measured mean temperature profile does not show the linear trend as seen in the DNS data, and the measured gradients at the wall are significantly higher than those obtained from the DNS. Both viscous and thermal boundary layer thickness scale with respect to the Rayleigh number as δ(v)~Ra(-0.24) and δ(θ)~Ra(-0.24), respectively.

  4. Seasonal air and water mass redistribution effects on LAGEOS and Starlette

    NASA Technical Reports Server (NTRS)

    Gutierrez, Roberto; Wilson, Clark R.

    1987-01-01

    Zonal geopotential coefficients have been computed from average seasonal variations in global air and water mass distribution. These coefficients are used to predict the seasonal variations of LAGEOS' and Starlette's orbital node, the node residual, and the seasonal variation in the 3rd degree zonal coefficient for Starlette. A comparison of these predictions with the observed values indicates that air pressure and, to a lesser extent, water storage may be responsible for a large portion of the currently unmodeled variation in the earth's gravity field.

  5. Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

    NASA Astrophysics Data System (ADS)

    Dugaria, S.; Moro, L.; Del, D., Col

    2015-11-01

    The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

  6. The role of boundary variability in polycrystalline grain-boundary diffusion

    NASA Astrophysics Data System (ADS)

    Moghadam, M. M.; Rickman, J. M.; Harmer, M. P.; Chan, H. M.

    2015-01-01

    We investigate the impact of grain-boundary variability on mass transport in a polycrystal. More specifically, we perform both numerical and analytical studies of steady-state diffusion in prototypical microstructures in which there is either a discrete spectrum of grain-boundary activation energies or else a complex distribution of grain-boundary character, and hence a continuous spectrum of boundary activation energies. An effective diffusivity is calculated for these structures using simplified multi-state models and, for the case of a continuous spectrum, employing experimentally obtained grain-boundary energy data. We identify different diffusive regimes for these cases and quantify deviations from Arrhenius behavior using effective medium theory. Finally, we examine the diffusion kinetics of a simplified model of an interfacial layering (i.e., complexion) transition.

  7. Photochemical aging of aerosol particles in different air masses arriving at Baengnyeong Island, Korea

    NASA Astrophysics Data System (ADS)

    Kang, Eunha; Lee, Meehye; Brune, William H.; Lee, Taehyoung; Park, Taehyun; Ahn, Joonyoung; Shang, Xiaona

    2018-05-01

    Atmospheric aerosol particles are a serious health risk, especially in regions like East Asia. We investigated the photochemical aging of ambient aerosols using a potential aerosol mass (PAM) reactor at Baengnyeong Island in the Yellow Sea during 4-12 August 2011. The size distributions and chemical compositions of aerosol particles were measured alternately every 6 min from the ambient air or through the highly oxidizing environment of a potential aerosol mass (PAM) reactor. Particle size and chemical composition were measured by using the combination of a scanning mobility particle sizer (SMPS) and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). Inside the PAM reactor, O3 and OH levels were equivalent to 4.6 days of integrated OH exposure at typical atmospheric conditions. Two types of air masses were distinguished on the basis of the chemical composition and the degree of aging: air transported from China, which was more aged with a higher sulfate concentration and O : C ratio, and the air transported across the Korean Peninsula, which was less aged with more organics than sulfate and a lower O : C ratio. For both episodes, the particulate sulfate mass concentration increased in the 200-400 nm size range when sampled through the PAM reactor. A decrease in organics was responsible for the loss of mass concentration in 100-200 nm particles when sampled through the PAM reactor for the organics-dominated episode. This loss was especially evident for the m/z 43 component, which represents less oxidized organics. The m/z 44 component, which represents further oxidized organics, increased with a shift toward larger sizes for both episodes. It is not possible to quantify the maximum possible organic mass concentration for either episode because only one OH exposure of 4.6 days was used, but it is clear that SO2 was a primary precursor of secondary aerosol in northeast Asia, especially during long-range transport from China. In addition

  8. Computational Study of Surface Tension and Wall Adhesion Effects on an Oil Film Flow Underneath an Air Boundary Layer

    NASA Technical Reports Server (NTRS)

    Celic, Alan; Zilliac, Gregory G.

    1998-01-01

    The fringe-imaging skin friction (FISF) technique, which was originally developed by D. J. Monson and G. G. Mateer at Ames Research Center and recently extended to 3-D flows, is the most accurate skin friction measurement technique currently available. The principle of this technique is that the skin friction at a point on an aerodynamic surface can be determined by measuring the time-rate-of-change of the thickness of an oil drop placed on the surface under the influence of the external air boundary layer. Lubrication theory is used to relate the oil-patch thickness variation to shear stress. The uncertainty of FISF measurements is estimated to be as low as 4 percent, yet little is known about the effects of surface tension and wall adhesion forces on the measured results. A modified version of the free-surface Navier-Stokes solver RIPPLE, developed at Los Alamos National Laboratories, was used to compute the time development of an oil drop on a surface under a simulated air boundary layer. RIPPLE uses the volume of fluid method to track the surface and the continuum surface force approach to model surface tension and wall adhesion effects. The development of an oil drop, over a time period of approximately 4 seconds, was studied. Under the influence of shear imposed by an air boundary layer, the computed profile of the drop rapidly changes from its initial circular-arc shape to a wedge-like shape. Comparison of the time-varying oil-thickness distributions computed using RIPPLE and also computed using a greatly simplified numerical model of an oil drop equation which does not include surface tension and wall adhesion effects) was used to evaluate the effects of surface tension on FISF measurement results. The effects of surface tension were found to be small but not necessarily negligible in some cases.

  9. Synthetic optimization of air turbine for dental handpieces.

    PubMed

    Shi, Z Y; Dong, T

    2014-01-01

    A synthetic optimization of Pelton air turbine in dental handpieces concerning the power output, compressed air consumption and rotation speed in the mean time is implemented by employing a standard design procedure and variable limitation from practical dentistry. The Pareto optimal solution sets acquired by using the Normalized Normal Constraint method are mainly comprised of two piecewise continuous parts. On the Pareto frontier, the supply air stagnation pressure stalls at the lower boundary of the design space, the rotation speed is a constant value within the recommended range from literature, the blade tip clearance insensitive to while the nozzle radius increases with power output and mass flow rate of compressed air to which the residual geometric dimensions are showing an opposite trend within their respective "pieces" compared to the nozzle radius.

  10. Measurements in the near-wall region of a relaxing three-dimensional low speed turbulent air boundary layer

    NASA Technical Reports Server (NTRS)

    Hebbar, K. S.; Melnik, W. L.

    1976-01-01

    An experimental investigation was conducted at selected locations of the near-wall region of a three dimensional turbulent air boundary layer relaxing in a nominally zero external pressure gradient behind a transverse hump (in the form of a 30 deg swept, 5-foot chord wing-type model) faired into the side wall of a low speed wind tunnel. Wall shear stresses measured with a flush-mounted hot-film gage and a sublayer fence were in very good agreement with experimental data obtained with two Preston probes. With the upstream unit Reynolds number held constant at 325,000/ft. approximately one-fourth of the boundary layer thickness adjacent to the wall was surveyed with a single rotated hot-wire probe mounted on a specially designed minimum interference traverse mechanism. The boundary layer (approximately 3.5 in thick near the first survey station where the length Reynolds number was 5.5 million) had a maximum crossflow velocity ratio of 0.145 and a maximum crossflow angle of 21.875 deg close to the wall.

  11. Select strengths and biases of models in representing the Arctic winter boundary layer over sea ice: the Larcform 1 single column model intercomparison

    DOE PAGES

    Pithan, Felix; Ackerman, Andrew; Angevine, Wayne M.; ...

    2016-08-27

    We struggle to represent lower tropospheric temperature and moisture profiles and surface fluxes in Artic winter using weather and climate models, partly because they lack or misrepresent physical processes that are specific to high latitudes. Observations have revealed two preferred states of the Arctic winter boundary layer. In the cloudy state, cloud liquid water limits surface radiative cooling, and temperature inversions are weak and elevated. In the radiatively clear state, strong surface radiative cooling leads to the build-up of surface-based temperature inversions. Many large-scale models lack the cloudy state, and some substantially underestimate inversion strength in the clear state. Themore » transformation from a moist to a cold dry air mass is modeled using an idealized Lagrangian perspective. The trajectory includes both boundary layer states, and the single-column experiment is the first Lagrangian Arctic air formation experiment (Larcform 1) organized within GEWEX GASS (Global atmospheric system studies). The intercomparison reproduces the typical biases of large-scale models: some models lack the cloudy state of the boundary layer due to the representation of mixed-phase microphysics or to the interaction between micro- and macrophysics. In some models, high emissivities of ice clouds or the lack of an insulating snow layer prevent the build-up of surface-based inversions in the radiatively clear state. Models substantially disagree on the amount of cloud liquid water in the cloudy state and on turbulent heat fluxes under clear skies. Finally, observations of air mass transformations including both boundary layer states would allow for a tighter constraint of model behavior.« less

  12. Select strengths and biases of models in representing the Arctic winter boundary layer over sea ice: the Larcform 1 single column model intercomparison

    PubMed Central

    Pithan, Felix; Ackerman, Andrew; Angevine, Wayne M.; Hartung, Kerstin; Ickes, Luisa; Kelley, Maxwell; Medeiros, Brian; Sandu, Irina; Steeneveld, Gert-Jan; Sterk, HAM; Svensson, Gunilla; Vaillancourt, Paul A.; Zadra, Ayrton

    2017-01-01

    Weather and climate models struggle to represent lower tropospheric temperature and moisture profiles and surface fluxes in Arctic winter, partly because they lack or misrepresent physical processes that are specific to high latitudes. Observations have revealed two preferred states of the Arctic winter boundary layer. In the cloudy state, cloud liquid water limits surface radiative cooling, and temperature inversions are weak and elevated. In the radiatively clear state, strong surface radiative cooling leads to the build-up of surface-based temperature inversions. Many large-scale models lack the cloudy state, and some substantially underestimate inversion strength in the clear state. Here, the transformation from a moist to a cold dry air mass is modelled using an idealized Lagrangian perspective. The trajectory includes both boundary layer states, and the single-column experiment is the first Lagrangian Arctic air formation experiment (Larcform 1) organized within GEWEX GASS (Global atmospheric system studies). The intercomparison reproduces the typical biases of large-scale models: Some models lack the cloudy state of the boundary layer due to the representation of mixed-phase micro-physics or to the interaction between micro-and macrophysics. In some models, high emissivities of ice clouds or the lack of an insulating snow layer prevent the build-up of surface-based inversions in the radiatively clear state. Models substantially disagree on the amount of cloud liquid water in the cloudy state and on turbulent heat fluxes under clear skies. Observations of air mass transformations including both boundary layer states would allow for a tighter constraint of model behaviour. PMID:28966718

  13. Select strengths and biases of models in representing the Arctic winter boundary layer over sea ice: the Larcform 1 single column model intercomparison

    NASA Astrophysics Data System (ADS)

    Pithan, Felix; Ackerman, Andrew; Angevine, Wayne M.; Hartung, Kerstin; Ickes, Luisa; Kelley, Maxwell; Medeiros, Brian; Sandu, Irina; Steeneveld, Gert-Jan; Sterk, H. A. M.; Svensson, Gunilla; Vaillancourt, Paul A.; Zadra, Ayrton

    2016-09-01

    Weather and climate models struggle to represent lower tropospheric temperature and moisture profiles and surface fluxes in Arctic winter, partly because they lack or misrepresent physical processes that are specific to high latitudes. Observations have revealed two preferred states of the Arctic winter boundary layer. In the cloudy state, cloud liquid water limits surface radiative cooling, and temperature inversions are weak and elevated. In the radiatively clear state, strong surface radiative cooling leads to the build-up of surface-based temperature inversions. Many large-scale models lack the cloudy state, and some substantially underestimate inversion strength in the clear state. Here, the transformation from a moist to a cold dry air mass is modeled using an idealized Lagrangian perspective. The trajectory includes both boundary layer states, and the single-column experiment is the first Lagrangian Arctic air formation experiment (Larcform 1) organized within GEWEX GASS (Global atmospheric system studies). The intercomparison reproduces the typical biases of large-scale models: some models lack the cloudy state of the boundary layer due to the representation of mixed-phase microphysics or to the interaction between micro- and macrophysics. In some models, high emissivities of ice clouds or the lack of an insulating snow layer prevent the build-up of surface-based inversions in the radiatively clear state. Models substantially disagree on the amount of cloud liquid water in the cloudy state and on turbulent heat fluxes under clear skies. Observations of air mass transformations including both boundary layer states would allow for a tighter constraint of model behavior.

  14. Select strengths and biases of models in representing the Arctic winter boundary layer over sea ice: the Larcform 1 single column model intercomparison.

    PubMed

    Pithan, Felix; Ackerman, Andrew; Angevine, Wayne M; Hartung, Kerstin; Ickes, Luisa; Kelley, Maxwell; Medeiros, Brian; Sandu, Irina; Steeneveld, Gert-Jan; Sterk, Ham; Svensson, Gunilla; Vaillancourt, Paul A; Zadra, Ayrton

    2016-09-01

    Weather and climate models struggle to represent lower tropospheric temperature and moisture profiles and surface fluxes in Arctic winter, partly because they lack or misrepresent physical processes that are specific to high latitudes. Observations have revealed two preferred states of the Arctic winter boundary layer. In the cloudy state, cloud liquid water limits surface radiative cooling, and temperature inversions are weak and elevated. In the radiatively clear state, strong surface radiative cooling leads to the build-up of surface-based temperature inversions. Many large-scale models lack the cloudy state, and some substantially underestimate inversion strength in the clear state. Here, the transformation from a moist to a cold dry air mass is modelled using an idealized Lagrangian perspective. The trajectory includes both boundary layer states, and the single-column experiment is the first L agrangian Arc tic air form ation experiment (Larcform 1) organized within GEWEX GASS (Global atmospheric system studies). The intercomparison reproduces the typical biases of large-scale models: Some models lack the cloudy state of the boundary layer due to the representation of mixed-phase micro-physics or to the interaction between micro-and macrophysics. In some models, high emissivities of ice clouds or the lack of an insulating snow layer prevent the build-up of surface-based inversions in the radiatively clear state. Models substantially disagree on the amount of cloud liquid water in the cloudy state and on turbulent heat fluxes under clear skies. Observations of air mass transformations including both boundary layer states would allow for a tighter constraint of model behaviour.

  15. Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

    NASA Technical Reports Server (NTRS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.; hide

    2006-01-01

    The International Consortium for Atmospheric Research on Transport and Transformation (ICARTT)-Lagrangian experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts using two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique is then used to identify Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these coincident matches is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown and the downwind minus upwind differences in tracers are discussed.

  16. Parallel Tracks as Quasi-steady States for the Magnetic Boundary Layers in Neutron-star Low-mass X-Ray Binaries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Erkut, M. Hakan; Çatmabacak, Onur, E-mail: mherkut@gmail.com

    The neutron stars in low-mass X-ray binaries (LMXBs) are usually thought to be weakly magnetized objects accreting matter from their low-mass companions in the form of a disk. Albeit weak compared to those in young neutron-star systems, the neutron-star magnetospheres in LMXBs can play an important role in determining the correlations between spectral and temporal properties. Parallel tracks appearing in the kilohertz (kHz) quasi-periodic oscillation (QPO) frequency versus X-ray flux plane can be used as a tool to study the magnetosphere–disk interaction in neutron-star LMXBs. For dynamically important weak fields, the formation of a non-Keplerian magnetic boundary layer at themore » innermost disk truncated near the surface of the neutron star is highly likely. Such a boundary region may harbor oscillatory modes of frequencies in the kHz range. We generate parallel tracks using the boundary region model of kHz QPOs. We also present the direct application of our model to the reproduction of the observed parallel tracks of individual sources such as 4U 1608–52, 4U 1636–53, and Aql X-1. We reveal how the radial width of the boundary layer must vary in the long-term flux evolution of each source to regenerate the parallel tracks. The run of the radial width looks similar for different sources and can be fitted by a generic model function describing the average steady behavior of the boundary region over the long term. The parallel tracks then correspond to the possible quasi-steady states the source can occupy around the average trend.« less

  17. Parallel Tracks as Quasi-steady States for the Magnetic Boundary Layers in Neutron-star Low-mass X-Ray Binaries

    NASA Astrophysics Data System (ADS)

    Erkut, M. Hakan; Çatmabacak, Onur

    2017-11-01

    The neutron stars in low-mass X-ray binaries (LMXBs) are usually thought to be weakly magnetized objects accreting matter from their low-mass companions in the form of a disk. Albeit weak compared to those in young neutron-star systems, the neutron-star magnetospheres in LMXBs can play an important role in determining the correlations between spectral and temporal properties. Parallel tracks appearing in the kilohertz (kHz) quasi-periodic oscillation (QPO) frequency versus X-ray flux plane can be used as a tool to study the magnetosphere-disk interaction in neutron-star LMXBs. For dynamically important weak fields, the formation of a non-Keplerian magnetic boundary layer at the innermost disk truncated near the surface of the neutron star is highly likely. Such a boundary region may harbor oscillatory modes of frequencies in the kHz range. We generate parallel tracks using the boundary region model of kHz QPOs. We also present the direct application of our model to the reproduction of the observed parallel tracks of individual sources such as 4U 1608-52, 4U 1636-53, and Aql X-1. We reveal how the radial width of the boundary layer must vary in the long-term flux evolution of each source to regenerate the parallel tracks. The run of the radial width looks similar for different sources and can be fitted by a generic model function describing the average steady behavior of the boundary region over the long term. The parallel tracks then correspond to the possible quasi-steady states the source can occupy around the average trend.

  18. Variation in airborne 137Cs peak levels with altitude from high-altitude locations across Europe after the arrival of Fukushima-labeled air masses

    NASA Astrophysics Data System (ADS)

    Masson, Olivier; Bieringer, Jacqueline; Dalheimer, Axel; Estier, Sybille; Evrard, Olivier; Penev, Ilia; Ringer, Wolfgang; Schlosser, Clemens; Steinkopff, Thomas; Tositti, Laura; de Vismes-Ott, Anne

    2015-04-01

    During the Fukushima Daiichi nuclear power plant (FDNPP) accident, a dozen of high-altitude aerosol sampling stations, located between 850 and 3,454 m above sea level (a.s.l.), provided airborne activity levels across Europe (Fig. 1). This represents at most 5% of the total number of aerosol sampling locations that delivered airborne activity levels (at least one result) in Europe, in connection with this nuclear accident. High altitude stations are typically equipped with a high volume sampler that collects aerosols on filters. The Fukushima-labeled air mass arrival and the peak of airborne cesium-137 (137Cs) activity levels were registered in Europe at different dates depending on the location, with differences up to a factor of six on a regional scale. Besides this statement related to lowland areas, we have compared the maximum airborne levels registered at high-altitude European locations (850 m < altitudes < 3450 m) with what was observed at the closest lowland location. The vertical distribution of 137Cs peak level was not uniform even after a long travel time/distance from Japan. This being true at least in the atmospheric boundary layer and in the lower free troposphere. Moreover the relation '137Csmax vs. altitude' shows a decreasing trend (Fig. 2). Results and discussion : Comparison of 137Cs and 7Be levels shows simultaneous increases at least when the 137Cs airborne level rose for the first time (Fig. 3). Zugspitze and Jungfraujoch stations attest of a time shift between 7Be and 137Cs peak that can be due to the particular dynamic of air movements at such high altitudes. After the 137Cs peak value, the plume concentration decreased whatever the 7Be level. Due to the cosmogenic origin of 7Be, its increase in the ground-level air is usually associated with downwind air movements, i.e. stratospheric air intrusions or at least air from high-tropospheric levels, into lower atmospheric layers. This means that Fukushima-labeled air masses registered at ground

  19. Contrasting microbial community changes during mass extinctions at the Middle/Late Permian and Permian/Triassic boundaries

    NASA Astrophysics Data System (ADS)

    Xie, Shucheng; Algeo, Thomas J.; Zhou, Wenfeng; Ruan, Xiaoyan; Luo, Genming; Huang, Junhua; Yan, Jiaxin

    2017-02-01

    Microbial communities are known to expand as a result of environmental deterioration during mass extinctions, but differences in microbial community changes between extinction events and their underlying causes have received little study to date. Here, we present a systematic investigation of microbial lipid biomarkers spanning ∼20 Myr (Middle Permian to Early Triassic) at Shangsi, South China, to contrast microbial changes associated with the Guadalupian-Lopingian boundary (GLB) and Permian-Triassic boundary (PTB) mass extinctions. High-resolution analysis of the PTB crisis interval reveals a distinct succession of microbial communities based on secular variation in moretanes, 2-methylhopanes, aryl isoprenoids, steranes, n-alkyl cyclohexanes, and other biomarkers. The first episode of the PTB mass extinction (ME1) was associated with increases in red algae and nitrogen-fixing bacteria along with evidence for enhanced wildfires and elevated soil erosion, whereas the second episode was associated with expansions of green sulfur bacteria, nitrogen-fixing bacteria, and acritarchs coinciding with climatic hyperwarming, ocean stratification, and seawater acidification. This pattern of microbial community change suggests that marine environmental deterioration was greater during the second extinction episode (ME2). The GLB shows more limited changes in microbial community composition and more limited environmental deterioration than the PTB, consistent with differences in species-level extinction rates (∼71% vs. 90%, respectively). Microbial biomarker records have the potential to refine our understanding of the nature of these crises and to provide insights concerning possible outcomes of present-day anthropogenic stresses on Earth's ecosystems.

  20. Ozone Laminae and Their Entrainment Into a Valley Boundary Layer, as Observed From a Mountaintop Monitoring Station, Ozonesondes, and Aircraft Over California's San Joaquin Valley

    NASA Astrophysics Data System (ADS)

    Faloona, I. C.; Conley, S. A.; Caputi, D.; Trousdell, J.; Chiao, S.; Eiserloh, A. J., Jr.; Clark, J.; Iraci, L. T.; Yates, E. L.; Marrero, J. E.; Ryoo, J. M.; McNamara, M. E.

    2016-12-01

    The San Joaquin Valley of California is wide ( 75 km) and long ( 400 km), and is situated under strong atmospheric subsidence due, in part, to the proximity of the midlatitude anticyclone of the Pacific High. The capping effect of this subsidence is especially prominent during the warm season when ground level ozone is a serious air quality concern across the region. While relatively clean marine boundary layer air is primarily funneled into the valley below the strong subsidence inversion at significant gaps in the upwind Coast Range mountains, airflow aloft also spills over these barriers and mixes into the valley from above. Because this transmountain flow occurs under the influence of synoptic subsidence it tends to present discrete, laminar sheets of differing air composition above the valley boundary layer. Meanwhile, although the boundary layers tend to remain shallow due to the prevailing subsidence, orographic and anabatic venting of valley boundary layer air around the basin whips up a complex admixture of regional air masses into a "buffer layer" just above the boundary layer (zi) and below the lower free troposphere. We present scalar data of widely varying lifetimes including ozone, methane, NOx, and thermodynamic observations from upwind and within the San Joaquin Valley to better explain this layering and its subsequent erosion into the valley boundary layer via entrainment. Data collected at a mountaintop monitoring station on Chews Ridge in the Coast Range, by coastal ozonesondes, and aircraft are analyzed to document the dynamic layering processes around the complex terrain surrounding the valley. Particular emphasis will be made on observational methods whereby distal ozone can be distinguished from the regional ozone to better understand the influence of exogenous sources on air quality in the valley.

  1. Repeated Carbon-Cycle Disturbances at the Permian-Triassic Boundary Separate two Mass Extinctions

    NASA Astrophysics Data System (ADS)

    Nicol, J. A.; Watson, L.; Claire, M.; Buick, R.; Catling, D. C.

    2004-12-01

    Non-marine organic matter in Permian-Triassic sediments from the Blue Mountains, eastern Australia shows seven negative δ13C excursions of up to 7%, terminating with a positive excursion of 4%. Fluctuations start at the late Permian Glossopteris floral extinction and continue until just above the palynological Permian-Triassic boundary, correlated with the peak of marine mass extinction. The isotopic fluctuations are not linked to changes in depositional setting, kerogen composition or plant community, so they evidently resulted from global perturbations in atmospheric δ13C and/or CO2. The pattern was not produced by a single catastrophe such as a meteorite impact, and carbon-cycle calculations indicate that gas release during flood-basalt volcanism was insufficient. Methane-hydrate melting can generate a single -7% shift, but cannot produce rapid multiple excursions without repeated reservoir regeneration and release. However, the data are consistent with repeated overturning of a stratified ocean, expelling toxic gases that promoted sequential mass extinctions in the terrestrial and marine realms.

  2. Turbulent boundary layer in high Rayleigh number convection in air.

    PubMed

    du Puits, Ronald; Li, Ling; Resagk, Christian; Thess, André; Willert, Christian

    2014-03-28

    Flow visualizations and particle image velocimetry measurements in the boundary layer of a Rayleigh-Bénard experiment are presented for the Rayleigh number Ra=1.4×1010. Our visualizations indicate that the appearance of the flow structures is similar to ordinary (isothermal) turbulent boundary layers. Our particle image velocimetry measurements show that vorticity with both positive and negative sign is generated and that the smallest flow structures are 1 order of magnitude smaller than the boundary layer thickness. Additional local measurements using laser Doppler velocimetry yield turbulence intensities up to I=0.4 as in turbulent atmospheric boundary layers. From our observations, we conclude that the convective boundary layer becomes turbulent locally and temporarily although its Reynolds number Re≈200 is considerably smaller than the value 420 underlying existing phenomenological theories. We think that, in turbulent Rayleigh-Bénard convection, the transition of the boundary layer towards turbulence depends on subtle details of the flow field and is therefore not universal.

  3. Hygroscopic growth of particles nebulized from water-soluble extracts of PM2.5 aerosols over the Bay of Bengal: Influence of heterogeneity in air masses and formation pathways.

    PubMed

    Boreddy, S K R; Kawamura, Kimitaka; Bikkina, Srinivas; Sarin, M M

    2016-02-15

    Hygroscopic properties of water-soluble matter (WSM) extracted from fine-mode aerosols (PM2.5) in the marine atmospheric boundary layer of the Bay of Bengal (BoB) have been investigated during a cruise from 27th December 2008 to 30th January 2009. Hygroscopic growth factors were measured on particles generated from the WSM using an H-TDMA system with an initial dry size of 100 nm in the range of 5-95% relative humidity (RH). The measured hygroscopic growth of WSM at 90% RH, g(90%)WSM, were ranged from 1.11 to 1.74 (mean: 1.43 ± 0.19) over the northern BoB and 1.12 to 1.38 (mean: 1.25 ± 0.09) over the southern BoB. A key finding is that distinct hygroscopic growth factors are associated with the air masses from the Indo-Gangetic plains (IGP), which are clearly distinguishable from those associated with air masses from Southeast Asia (SEA). We found higher (lower) g(90%)WSM over the northern (southern) BoB, which were associated with an IGP (SEA) air masses, probably due the formation of high hygroscopic salts such as (NH4)2SO4. On the other hand, biomass burning influenced SEA air masses confer the low hygroscopic salts such as K2SO4, MgSO4, and organic salts over the southern BoB. Interestingly, mass fractions of water-soluble organic matter (WSOM) showed negative and positive correlations with g(90%)WSM over the northern and southern BoB, respectively, suggesting that the mixing state of organic and inorganic fractions could play a major role on the g(90%)WSM over the BoB. Further, WSOM/SO4(2-) mass ratios suggest that SO4(2-) dominates the g(90%)WSM over the northern BoB whereas WSOM fractions were important over the southern BoB. The present study also suggests that aging process could significantly alter the hygroscopic growth of aerosol particles over the BoB, especially over the southern BoB. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Mass spectrometer characterization of halogen gases in air at atmospheric pressure.

    PubMed

    Ivey, Michelle M; Foster, Krishna L

    2005-03-01

    We have developed a new interface for a commercial ion trap mass spectrometer equipped with APCI capable of real-time measurements of gaseous compounds with limits of detection on the order of pptv. The new interface has been tested using the detection of Br2 and Cl2 over synthetic seawater ice at atmospheric pressure as a model system. A mechanical pump is used to draw gaseous mixtures through a glass manifold into the corona discharge area, where the molecules are ionized. Analysis of bromine and chlorine in dry air show that ion intensity is affected by the pumping rate and the position of the glass manifold. The mass spectrometer signals for Br2 are linear in the 0.1-10.6 ppbv range, and the estimated 3sigma detection limit is 20 pptv. The MS signals for Cl2 are linear in the 0.2-25 ppbv range, and the estimated 3sigma detection limit is 1 ppbv. This new interface advances the field of analytical chemistry by introducing a practical modification to a commercially available ion trap mass spectrometer that expands the available methods for performing highly specific and sensitive measurements of gases in air at atmospheric pressure.

  5. Enhancement of acidic gases in biomass burning impacted air masses over Canada

    NASA Technical Reports Server (NTRS)

    Lefer, B. L.; Talbot, R. W.; Harriss, R. C.; Bradshaw, J. D.; Sandholm, S. T.; Olson, J. O.; Sachse, G. W.; Collins, J.; Shipham, M. A.; Blake, D. R.

    1994-01-01

    Biomass-burning impacted air masses sampled over central and eastern Canada during the summer of 1990 as part of ABLE 3B contained enhanced mixing ratios of gaseous HNO3, HCOOH, CH3COOH, and what appears to be (COOH)2. These aircraft-based samples were collected from a variety of fresh burning plumes and more aged haze layers from different source regions. Values of the enhancement factor, delta X/delta CO, where X represents an acidic gas, for combustion-impacted air masses sampled both near and farther away from the fires, were relatively uniform. However, comparison of carboxylic acid emission ratios measured in laboratory fires to field plume enhancement factors indicates significant in-plume production of HCOOH. Biomass-burning appears to be an important source of HNO3, HCOOH, and CH3COOH to the troposphere over subarctic Canada.

  6. Impact of the Loess Plateau on the atmospheric boundary layer structure and air quality in the North China Plain: a case study.

    PubMed

    Hu, Xiao-Ming; Ma, ZhiQiang; Lin, Weili; Zhang, Hongliang; Hu, Jianlin; Wang, Ying; Xu, Xiaobin; Fuentes, Jose D; Xue, Ming

    2014-11-15

    The North China Plain (NCP), to the east of the Loess Plateau, experiences severe regional air pollution. During the daytime in the summer, the Loess Plateau acts as an elevated heat source. The impacts of such a thermal effect on meteorological phenomena (e.g., waves, precipitation) in this region have been discussed. However, its impacts on the atmospheric boundary layer structure and air quality have not been reported. It is hypothesized that the thermal effect of the Plateau likely modulates the boundary layer structure and ambient concentrations of pollutants over the NCP under certain meteorological conditions. Thus, this study investigates such effect and its impacts using measurements and three-dimensional model simulations. It is found that in the presence of daytime westerly wind in the lower troposphere (~1 km above the NCP), warmer air above the Loess Plateau was transported over the NCP and imposed a thermal inversion above the mixed boundary layer, which acted as a lid and suppressed the mixed layer growth. As a result, pollutants accumulated in the shallow mixed layer and ozone was efficiently produced. The downward branch of the thermally-induced Mountain-Plains Solenoid circulation over the NCP contributed to enhancing the capping inversion and exacerbating air pollution. Previous studies have reported that low mixed layer, a factor for elevated pollution in the NCP, may be caused by aerosol scattering and absorption of solar radiation, frontal inversion, and large scale subsidence. The present study revealed a different mechanism (i.e., westerly warm advection) for the suppression of the mixed layer in summer NCP, which caused severe O3 pollution. This study has important implications for understanding the essential meteorological factors for pollution episodes in this region and forecasting these severe events. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Modelling bioaccumulation of semi-volatile organic compounds (SOCs) from air in plants based on allometric principles.

    PubMed

    Steyaert, Nils L L; Hauck, Mara; Van Hulle, Stijn W H; Hendriks, A Jan

    2009-10-01

    A model was developed for gaseous plant-air exchange of semi-volatile organic compounds. Based on previous soil-plant modelling, uptake and elimination kinetics were scaled as a function of plant mass and octanol-air partition ratios. Exchange of chemicals was assumed to be limited by resistances encountered during diffusion through a laminar boundary layer of air and permeation through the cuticle of the leaf. The uptake rate constant increased and the elimination rate constant decreased with the octanol-air partition ratio both apparently levelling off at high values. Differences in kinetics between species could be explained by their masses. Validation on independent data showed that bio-concentration factors of PCBs, chlorobenzenes and other chemicals were predicted well by the model. For pesticides, polycyclic aromatic hydrocarbons and dioxins deviations occurred.

  8. The penalty immersed boundary method and its application to aerodynamics

    NASA Astrophysics Data System (ADS)

    Kim, Yongsam

    The Immersed Boundary (IB) method has been widely applied to problems involving a moving elastic boundary that is immersed in fluid and interacting with it. But most applications of the IB method have involved a massless elastic boundary. Extending the method to cover the case of a massive boundary has required spreading the boundary mass out onto the fluid grid and then solving the Navier-Stokes equations with a variable mass density. The variable mass density makes Fourier transform methods inapplicable, and requires a multigrid solver. Here we propose a new and simple way to give mass to the elastic boundary. The key idea of the method is to introduce two representations of each boundary: one is a massive boundary which does not interact with the fluid, and the other is messless and plays the same role as the boundary of the IB method with the massless assumption. Although they are almost the same, we allow these two representations of the boundary to be different as long as the gap between them is small. This can be ensured by connecting them with a stiff spring with a zero rest length which generates force acting on both boundaries and pulling them together. We call this the 'Penalty IB method'. It does not spread mass to the fluid grid, retains the use of Fourier transform methodology, and is easy to implement in the context of an existing IB method code for the massless case. This thesis introduces the Penalty IB method and applies it to several problems in which the mass of the boundary is important. These problems are filaments in a flowing soap film, flows past a cylinder, windsocks, flags, and parachutes.

  9. A one-dimensional sectional aerosol model integrated with mesoscale meteorological data to study marine boundary layer aerosol dynamics

    NASA Astrophysics Data System (ADS)

    Caffrey, Peter F.; Hoppel, William A.; Shi, Jainn J.

    2006-12-01

    The dynamics of aerosols in the marine boundary layer are simulated with a one-dimensional, multicomponent, sectional aerosol model using vertical profiles of turbulence, relative humidity, temperature, vertical velocity, cloud cover, and precipitation provided by 3-D mesoscale meteorological model output. The Naval Research Laboratory's (NRL) sectional aerosol model MARBLES (Fitzgerald et al., 1998a) was adapted to use hourly meteorological input taken from NRL's Coupled Ocean-Atmosphere Prediction System (COAMPS). COAMPS-generated turbulent mixing coefficients and large-scale vertical velocities determine vertical exchange within the marine boundary layer and exchange with the free troposphere. Air mass back trajectories were used to define the air column history along which the meteorology was retrieved for use with the aerosol model. Details on the integration of these models are described here, as well as a description of improvements made to the aerosol model, including transport by large-scale vertical motions (such as subsidence and lifting), a revised sea-salt aerosol source function, and separate tracking of sulfate mass from each of the five sources (free tropospheric, nucleated, condensed from gas phase oxidation products, cloud-processed, and produced from heterogeneous oxidation of S(IV) on sea-salt aerosol). Results from modeling air masses arriving at Oahu, Hawaii, are presented, and the relative contribution of free-tropospheric sulfate particles versus sea-salt aerosol from the surface to CCN concentrations is discussed. Limitations and benefits of the method are presented, as are sensitivity analyses of the effect of large-scale vertical motions versus turbulent mixing.

  10. Solar wind composition from sector boundary crossings and coronal mass ejections

    NASA Technical Reports Server (NTRS)

    Ogilvie, K. W.; Coplan, M. A.; Geiss, J.

    1992-01-01

    Using the Ion Composition Instrument (ICI) on board the ISEE-3/ICE spacecraft, average abundances of He-4, He-3, O, Ne, Si, and Fe have been determined over extended periods. In this paper the abundances of He-4, O, Ne, Si, and Mg obtained by the ICI in the region of sector boundary crossings (SBCs), magnetic clouds and bidirectional streaming events (BDSs) are compared with the average abundances. Both magnetic clouds and BDSs are associated with coronal mass ejections (CMEs). No variation of abundance is seen to occur at SBCs except for helium, as has already been observed. In CME-related material, the abundance of neon appears to be high and variable, in agreement with recent analysis of spectroscopic observations of active regions. We find that our observations can be correlated with the magnetic topology in the corona.

  11. Effect of particle momentum transfer on an oblique-shock-wave/laminar-boundary-layer interaction

    NASA Astrophysics Data System (ADS)

    Teh, E.-J.; Johansen, C. T.

    2016-11-01

    Numerical simulations of solid particles seeded into a supersonic flow containing an oblique shock wave reflection were performed. The momentum transfer mechanism between solid and gas phases in the shock-wave/boundary-layer interaction was studied by varying the particle size and mass loading. It was discovered that solid particles were capable of significant modulation of the flow field, including suppression of flow separation. The particle size controlled the rate of momentum transfer while the particle mass loading controlled the magnitude of momentum transfer. The seeding of micro- and nano-sized particles upstream of a supersonic/hypersonic air-breathing propulsion system is proposed as a flow control concept.

  12. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    USGS Publications Warehouse

    Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

    2002-01-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  13. Effects of heat and mass transfer on unsteady boundary layer flow of a chemical reacting Casson fluid

    NASA Astrophysics Data System (ADS)

    Khan, Kashif Ali; Butt, Asma Rashid; Raza, Nauman

    2018-03-01

    In this study, an endeavor is to observe the unsteady two-dimensional boundary layer flow with heat and mass transfer behavior of Casson fluid past a stretching sheet in presence of wall mass transfer by ignoring the effects of viscous dissipation. Chemical reaction of linear order is also invoked here. Similarity transformation have been applied to reduce the governing equations of momentum, energy and mass into non-linear ordinary differential equations; then Homotopy analysis method (HAM) is applied to solve these equations. Numerical work is done carefully with a well-known software MATHEMATICA for the examination of non-dimensional velocity, temperature, and concentration profiles, and then results are presented graphically. The skin friction (viscous drag), local Nusselt number (rate of heat transfer) and Sherwood number (rate of mass transfer) are discussed and presented in tabular form for several factors which are monitoring the flow model.

  14. Atmospheric tides on Venus. III - The planetary boundary layer

    NASA Technical Reports Server (NTRS)

    Dobrovolskis, A. R.

    1983-01-01

    Diurnal solar heating of Venus' surface produces variable temperatures, winds, and pressure gradients within a shallow layer at the bottom of the atmosphere. The corresponding asymmetric mass distribution experiences a tidal torque tending to maintain Venus' slow retrograde rotation. It is shown that including viscosity in the boundary layer does not materially affect the balance of torques. On the other hand, friction between the air and ground can reduce the predicted wind speeds from about 5 to about 1 m/sec in the lower atmosphere, more consistent with the observations from Venus landers and descent probes. Implications for aeolian activity on Venus' surface and for future missions are discussed.

  15. Aerosol concentration measurements and correlations with air mass trajectories at the Pierre Auger Observatory

    NASA Astrophysics Data System (ADS)

    Micheletti, M. I.; Louedec, K.; Freire, M.; Vitale, P.; Piacentini, R. D.

    2017-06-01

    Aerosols play an important role in radiative transfer processes involved in different fields of study. In particular, their influence is crucial in the attenuation of light at astronomical and astrophysical observatories, and has to be taken into account in light transfer models employed to reconstruct the signals. The Andean Argentinean region is increasingly being considered as a good candidate to host such facilities, as well as the ones for solar-energy resources, and an adequate knowledge of aerosols characteristics there is needed, but it is not always possible due to the vast area involved and the scarce atmospheric data at ground. The aim of this work is to find correlations between aerosol data and particle trajectories that can give an insight into the origin and behaviour of aerosols in this zone and can be employed in situations in which one does not have local aerosol measurements. For this purpose, an aerosol spectrometer and dust monitor (Grimm 1.109) was installed at the Pierre Auger Observatory of ultra-high-energy cosmic rays, to record aerosol concentrations in different size intervals, at surface level. These measurements are analysed and correlated with air mass trajectories obtained from HYSPLIT (NOAA) model calculations. High aerosol concentrations are registered predominantly when air masses have travelled mostly over continental areas, mainly from the NE direction, while low aerosol concentrations are found in correspondence with air masses coming from the Pacific Ocean, from the NW direction. Different size distribution patterns were found for the aerosols depending on their origin: marine or continental. This work shows for the first time the size distribution of aerosols registered at the Pierre Auger Observatory. The correlations found between mass and particle concentrations (total and for different size ranges) and HYSPLIT air mass trajectories, confirm that the latter can be employed as a useful tool to infer the sources, evolution

  16. An Ejector Air Intake Design Method for a Novel Rocket-Based Combined-Cycle Rocket Nozzle

    NASA Astrophysics Data System (ADS)

    Waung, Timothy S.

    Rocket-based combined-cycle (RBCC) vehicles have the potential to reduce launch costs through the use of several different air breathing engine cycles, which reduce fuel consumption. The rocket-ejector cycle, in which air is entrained into an ejector section by the rocket exhaust, is used at flight speeds below Mach 2. This thesis develops a design method for an air intake geometry around a novel RBCC rocket nozzle design for the rocket-ejector engine cycle. This design method consists of a geometry creation step in which a three-dimensional intake geometry is generated, and a simple flow analysis step which predicts the air intake mass flow rate. The air intake geometry is created using the rocket nozzle geometry and eight primary input parameters. The input parameters are selected to give the user significant control over the air intake shape. The flow analysis step uses an inviscid panel method and an integral boundary layer method to estimate the air mass flow rate through the intake geometry. Intake mass flow rate is used as a performance metric since it directly affects the amount of thrust a rocket-ejector can produce. The design method results for the air intake operating at several different points along the subsonic portion of the Ariane 4 flight profile are found to under predict mass flow rate by up to 8.6% when compared to three-dimensional computational fluid dynamics simulations for the same air intake.

  17. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    NASA Astrophysics Data System (ADS)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  18. Flame and Soot Boundaries of Laminar Jet Diffusion Flames. Appendix A

    NASA Technical Reports Server (NTRS)

    Xu, F.; Dai, Z.; Faeth, G. M.; Yuan, Z.-G. (Technical Monitor); Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

    2002-01-01

    The shapes (flame-sheet and luminous-flame boundaries) or steady weakly buoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue CO2 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K. ambient pressures of 4-50 kPa, jet-exit Reynolds numbers of 3-54, initial air/fuel velocity ratios of 0-9, and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at microgravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smoke-point conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smoke-point conditions. Flame-shape predictions were based on simplified analyses using the boundary-layer approximations along with empirical parameters to distinguish flame-sheet and luminous-flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 of the lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions because of the presence of luminous soot particles in the fuel-lean region of the flames.

  19. Implementation of Slater Boundary Condition into OVERFLOW

    NASA Astrophysics Data System (ADS)

    Duncan, Sean

    Bleed is one of the primary methods of controlling the flow within a mixed compression inlet. In this work the Slater boundary condition, first applied in WindUS, is implemented in OVERFLOW. Further, a simulation using discrete holes is run in order to show the differences between use of the boundary condition and use of the bleed hole geometry. Recent tests at Wright Patterson Air Force Base seek to provide a baseline for study of mixed compression inlets. The inlet used by the Air Force Research Laboratory is simulated in the modified OVERFLOW. The results from the experiment are compared to the CFD to qualitatively assess the accuracy of the simulations. The boundary condition is shown to be robust and viable in studying bleed.

  20. The Taurus Boundary of Stellar/Substellar (TBOSS) Survey. II. Disk Masses from ALMA Continuum Observations

    NASA Astrophysics Data System (ADS)

    Ward-Duong, K.; Patience, J.; Bulger, J.; van der Plas, G.; Ménard, F.; Pinte, C.; Jackson, A. P.; Bryden, G.; Turner, N. J.; Harvey, P.; Hales, A.; De Rosa, R. J.

    2018-02-01

    We report 885 μm ALMA continuum flux densities for 24 Taurus members spanning the stellar/substellar boundary with spectral types from M4 to M7.75. Of the 24 systems, 22 are detected at levels ranging from 1.0 to 55.7 mJy. The two nondetections are transition disks, though other transition disks in the sample are detected. Converting ALMA continuum measurements to masses using standard scaling laws and radiative transfer modeling yields dust mass estimates ranging from ∼0.3 to 20 M ⊕. The dust mass shows a declining trend with central object mass when combined with results from submillimeter surveys of more massive Taurus members. The substellar disks appear as part of a continuous sequence and not a distinct population. Compared to older Upper Sco members with similar masses across the substellar limit, the Taurus disks are brighter and more massive. Both Taurus and Upper Sco populations are consistent with an approximately linear relationship in M dust to M star, although derived power-law slopes depend strongly upon choices of stellar evolutionary model and dust temperature relation. The median disk around early-M stars in Taurus contains a comparable amount of mass in small solids as the average amount of heavy elements in Kepler planetary systems on short-period orbits around M-dwarf stars, with an order of magnitude spread in disk dust mass about the median value. Assuming a gas-to-dust ratio of 100:1, only a small number of low-mass stars and brown dwarfs have a total disk mass amenable to giant planet formation, consistent with the low frequency of giant planets orbiting M dwarfs.

  1. The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

    ERIC Educational Resources Information Center

    Driscoll, John N.; Warneck, Peter

    1973-01-01

    Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

  2. Lidar Measurements of Wind, Moisture and Boundary Layer Evolution in a Dryline During IHOP2002

    NASA Technical Reports Server (NTRS)

    Demoz, Belay; Evans, Keith; DiGirolamo, Paolo; Wang, Zhien; Whiteman, David; Schwemmer, Geary; Gentry, Bruce; Miller, David

    2003-01-01

    Variability in the convective boundary layer moisture, wind and temperature fields and their importance in the forecasting and understanding of storms have been discussed in the literature. These variations have been reported in relation to frontal zones, stationary boundaries and during horizontal convective rolls. While all three vary substantially in the convective boundary layer, moisture poses a particular challenge. Moisture or water vapor concentration (expressed as a mass mixing ratio, g/kg), is conserved in all meteorological processes except condensation and evaporation. The water vapor mixing ratio often remains distinct across an air -mass boundary even when the temperature difference is indistinct. These properties make it an ideal choice in visualizing and understanding many of the atmosphere's dynamic features. However, it also presents a unique measurement challenge because water vapor content can vary by more than three orders of magnitude in the troposphere. Characterization of the 3D-distribution of water vapor is also difficult as water vapor observations can suffer from large sampling errors and substantial variability both in the vertical and horizontal. This study presents groundbased measurements of wind, boundary layer structure and water vapor mixing ratio measurements observed by three co-located lidars. This presentation will focus on the evolution and variability of moisture and wind in the boundary layer during a dry line event that occurred on 22 May 2002. These data sets and analyses are unique in that they combine simultaneous measurements of wind, moisture and CBL structure to study the detailed thermal variability in and around clear air updrafts during a dryline event. It will quantify the variation caused by, in and around buoyant plumes and across a dryline. The data presented here were collected in the panhandle of Oklahoma as part of the International BO Project (IHOP-2002), a field experiment that took place over the

  3. Planetary boundary layer height retrieval at UMBC in the frame of NOAA/ARL campaign

    NASA Astrophysics Data System (ADS)

    Lolli, S.; Delgado, R.; Compton, J.; Hoff, R.

    2011-11-01

    The determination of the depth of daytime and nighttime Planetary Boundary Layer Height (PBLH) must be known very accurately to relate boundary layer concentrations of gases or particles to upstream fluxes. Moreover, the air quality forecasts rely upon semi-empirical parameterizations within numerical models for the description of dispersion, formation and fate of pollutants influenced by the spatial and temporal distribution of emissions in cities, topography, and weather. The particulate matter (PM) mass measured at the ground level is a common way to quantify the amount of aerosol particles in the atmosphere and is the standard used to evaluate air quality. Remote sensing of atmospheric aerosols in the lower troposphere that affect air quality is done at the University of Maryland, Baltimore County (UMBC) by the Atmospheric Lidar Group, that supported the joint NOAA/ARL and NCEP ad hoc field study. These campaigns launched radiosondes from Howard University (HU) (26.6km south of UMBC) and RFK Stadium (29.15 km south of UMBC) during September 14-22, 2009 to develop a database to investigate the evolution and spatial variability of the PBLH. In this paper, we examined the potential for continual observation of PBLH by performing a statistical comparison of the spatial and temporal resolution of PBLH from lidars, wind profiler, and radiosonde measurements

  4. THE KELVIN-HELMHOLTZ INSTABILITY AT CORONAL MASS EJECTION BOUNDARIES IN THE SOLAR CORONA: OBSERVATIONS AND 2.5D MHD SIMULATIONS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moestl, U. V.; Temmer, M.; Veronig, A. M., E-mail: ute.moestl@uni-graz.at

    2013-03-20

    The Atmospheric Imaging Assembly on board the Solar Dynamics Observatory observed a coronal mass ejection with an embedded filament on 2011 February 24, revealing quasi-periodic vortex-like structures at the northern side of the filament boundary with a wavelength of approximately 14.4 Mm and a propagation speed of about 310 {+-} 20 km s{sup -1}. These structures could result from the Kelvin-Helmholtz instability occurring on the boundary. We perform 2.5D numerical simulations of the Kelvin-Helmholtz instability and compare the simulated characteristic properties of the instability with the observations, where we obtain qualitative as well as quantitative accordance. We study the absencemore » of Kelvin-Helmholtz vortex-like structures on the southern side of the filament boundary and find that a magnetic field component parallel to the boundary with a strength of about 20% of the total magnetic field has stabilizing effects resulting in an asymmetric development of the instability.« less

  5. Diffusion of volatile organics through porous snow: impact of surface adsorption and grain boundaries

    NASA Astrophysics Data System (ADS)

    Bartels-Rausch, T.; Wren, S. N.; Schreiber, S.; Riche, F.; Schneebeli, M.; Ammann, M.

    2013-07-01

    Release of trace gases from surface snow on earth drives atmospheric chemistry, especially in the polar regions. The gas-phase diffusion of methanol and of acetone through the interstitial air of snow was investigated in a well-controlled laboratory study in the temperature range of 223 to 263 K. The aim of this study was to evaluate how the structure of the snowpack, the interaction of the trace gases with the snow surface, and the grain boundaries influence the diffusion on timescales up to 1 h. The diffusive loss of these two volatile organics into packed snow samples was measured using a chemical ionization mass spectrometer. The structure of the snow was analysed by means of X-ray-computed micro-tomography. The observed diffusion profiles could be well described based on gas-phase diffusion and the known structure of the snow sample at temperatures ≥ 253 K. At colder temperatures, surface interactions start to dominate the diffusive transport. Parameterizing these interactions in terms of adsorption to the solid ice surface, i.e. using temperature-dependent air-ice partitioning coefficients, better described the observed diffusion profiles than the use of air-liquid partitioning coefficients. No changes in the diffusive fluxes were observed by increasing the number of grain boundaries in the snow sample by a factor of 7, indicating that for these volatile organic trace gases, uptake into grain boundaries does not play a role on the timescale of diffusion through porous surface snow. For this, a snow sample with an artificially high amount of ice grains was produced and the grain boundary surface measured using thin sections. In conclusion, we have shown that the diffusivity can be predicted when the structure of the snowpack and the partitioning of the trace gas to solid ice is known.

  6. Boundary Layer

    NASA Technical Reports Server (NTRS)

    Loitsianskii. L. G.

    1956-01-01

    The fundamental, practically the most important branch of the modern mechanics of a viscous fluid or a gas, is that branch which concerns itself with the study of the boundary layer. The presence of a boundary layer accounts for the origin of the resistance and lift force, the breakdown of the smooth flow about bodies, and other phenomena that are associated with the motion of a body in a real fluid. The concept of boundary layer was clearly formulated by the founder of aerodynamics, N. E. Joukowsky, in his well-known work "On the Form of Ships" published as early as 1890. In his book "Theoretical Foundations of Air Navigation," Joukowsky gave an account of the most important properties of the boundary layer and pointed out the part played by it in the production of the resistance of bodies to motion. The fundamental differential equations of the motion of a fluid in a laminar boundary layer were given by Prandtl in 1904; the first solutions of these equations date from 1907 to 1910. As regards the turbulent boundary layer, there does not exist even to this day any rigorous formulation of this problem because there is no closed system of equations for the turbulent motion of a fluid. Soviet scientists have done much toward developing a general theory of the boundary layer, and in that branch of the theory which is of greatest practical importance at the present time, namely the study of the boundary layer at large velocities of the body in a compressed gas, the efforts of the scientists of our country have borne fruit in the creation of a new theory which leaves far behind all that has been done previously in this direction. We shall herein enumerate the most important results by Soviet scientists in the development of the theory of the boundary layer.

  7. The China Clipper - Fast advective transport of radon-rich air from the Asian boundary layer to the upper troposphere near California

    NASA Technical Reports Server (NTRS)

    Kritz, Mark A.; Le Roulley, Jean-Claude; Danielsen, Edwin F.

    1990-01-01

    A series of upper tropospheric radon concentration measurements made over the eastern Pacific and west coast of the U.S. during the summers of 1983 and 1984 has revealed the occurrence of unexpectedly high radon concentrations for 9 of the 61 measurements. A frequency distribution plot of the set of 61 observations shows a distinct bimodal distribution, with approximately 2/5 of the observations falling close to 1 pCi/SCM, and 3/5 falling in a high concentration mode centered at about 11 pCi/SCM. Trajectory and synoptic analyses for two of the flights on which such high radon concentrations were observed indicate that this radon-rich air originated in the Asian boundary layer, ascended in cumulus updrafts, and was carried eastward in the fast moving air on the anticyclonic side of the upper tropospheric jet. The results suggest that the combination of rapid vertical transport from the surface boundary layer to the upper troposphere, followed by rapid horizontal transport eastward represents an efficient mode of long-transport for other, chemically reactive atmospheric trace constituents.

  8. The China Clipper - Fast advective transport of radon-rich air from the Asian boundary layer to the upper troposphere near California

    NASA Astrophysics Data System (ADS)

    Kritz, Mark A.; Le Roulley, Jean-Claude; Danielsen, Edwin F.

    1990-02-01

    A series of upper tropospheric radon concentration measurements made over the eastern Pacific and west coast of the U.S. during the summers of 1983 and 1984 has revealed the occurrence of unexpectedly high radon concentrations for 9 of the 61 measurements. A frequency distribution plot of the set of 61 observations shows a distinct bimodal distribution, with approximately 2/5 of the observations falling close to 1 pCi/SCM, and 3/5 falling in a high concentration mode centered at about 11 pCi/SCM. Trajectory and synoptic analyses for two of the flights on which such high radon concentrations were observed indicate that this radon-rich air originated in the Asian boundary layer, ascended in cumulus updrafts, and was carried eastward in the fast moving air on the anticyclonic side of the upper tropospheric jet. The results suggest that the combination of rapid vertical transport from the surface boundary layer to the upper troposphere, followed by rapid horizontal transport eastward represents an efficient mode of long-transport for other, chemically reactive atmospheric trace constituents.

  9. Complex Wall Boundary Conditions for Modeling Combustion in Catalytic Channels

    NASA Astrophysics Data System (ADS)

    Zhu, Huayang; Jackson, Gregory

    2000-11-01

    Monolith catalytic reactors for exothermic oxidation are being used in automobile exhaust clean-up and ultra-low emissions combustion systems. The reactors present a unique coupling between mass, heat, and momentum transport in a channel flow configuration. The use of porous catalytic coatings along the channel wall presents a complex boundary condition when modeled with the two-dimensional channel flow. This current work presents a 2-D transient model for predicting the performance of catalytic combustion systems for methane oxidation on Pd catalysts. The model solves the 2-D compressible transport equations for momentum, species, and energy, which are solved with a porous washcoat model for the wall boundary conditions. A time-splitting algorithm is used to separate the stiff chemical reactions from the convective/diffusive equations for the channel flow. A detailed surface chemistry mechanism is incorporated for the catalytic wall model and is used to predict transient ignition and steady-state conversion of CH4-air flows in the catalytic reactor.

  10. Physical and chemical processes of air masses in the Aegean Sea during Etesians: Aegean-GAME airborne campaign.

    PubMed

    Tombrou, M; Bossioli, E; Kalogiros, J; Allan, J D; Bacak, A; Biskos, G; Coe, H; Dandou, A; Kouvarakis, G; Mihalopoulos, N; Percival, C J; Protonotariou, A P; Szabó-Takács, B

    2015-02-15

    High-resolution measurements of gas and aerosols' chemical composition along with meteorological and turbulence parameters were performed over the Aegean Sea (AS) during an Etesian outbreak in the framework of the Aegean-GAME airborne campaign. This study focuses on two distinct Etesian patterns, with similarities inside the Marine Atmospheric Boundary Layer (MABL) and differences at higher levels. Under long-range transport and subsidence the pollution load is enhanced (by 17% for CO, 11% for O3, 28% for sulfate, 62% for organic mass, 47% for elemental carbon), compared to the pattern with a weaker synoptic system. Sea surface temperature (SST) was a critical parameter for the MABL structure, turbulent fluxes and pollutants' distribution at lower levels. The MABL height was below 500 m asl over the eastern AS (favoring higher accumulation), and deeper over the western AS. The most abundant components of total PM1 were sulfate (40-50%) and organics (30-45%). Higher average concentrations measured over the eastern AS (131 ± 76 ppbv for CO, 62.5 ± 4.1 ppbv for O3, 5.0 ± 1.1 μg m(-3) for sulfate, 4.7 ± 0.9 μg m(-3) for organic mass and 0.5 ± 0.2 μg m(-3) for elemental carbon). Under the weaker synoptic system, cleaner but more acidic air masses prevailed over the eastern part, while distinct aerosol layers of different signature were observed over the western part. The Aitken and accumulation modes contributed equally during the long-range transport, while the Aitken modes dominated during local or medium range transport. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Numerical Investigation of PLIF Gas Seeding for Hypersonic Boundary Layer Flows

    NASA Technical Reports Server (NTRS)

    Johanson, Craig T.; Danehy, Paul M.

    2012-01-01

    Numerical simulations of gas-seeding strategies required for planar laser-induced fluorescence (PLIF) in a Mach 10 air flow were performed. The work was performed to understand and quantify adverse effects associated with gas seeding and to compare different flow rates and different types of seed gas. The gas was injected through a slot near the leading edge of a flat plate wedge model used in NASA Langley Research Center's 31- Inch Mach 10 Air Tunnel facility. Nitric oxide, krypton, and iodine gases were simulated at various injection rates. Simulation results showing the deflection of the velocity field for each of the cases are presented. Streamwise distributions of velocity and concentration boundary layer thicknesses as well as vertical distributions of velocity, temperature, and mass distributions are presented for each of the cases. Relative merits of the different seeding strategies are discussed.

  12. Discrete multi-physics simulations of diffusive and convective mass transfer in boundary layers containing motile cilia in lungs.

    PubMed

    Ariane, Mostapha; Kassinos, Stavros; Velaga, Sitaram; Alexiadis, Alessio

    2018-04-01

    In this paper, the mass transfer coefficient (permeability) of boundary layers containing motile cilia is investigated by means of discrete multi-physics. The idea is to understand the main mechanisms of mass transport occurring in a ciliated-layer; one specific application being inhaled drugs in the respiratory epithelium. The effect of drug diffusivity, cilia beat frequency and cilia flexibility is studied. Our results show the existence of three mass transfer regimes. A low frequency regime, which we called shielding regime, where the presence of the cilia hinders mass transport; an intermediate frequency regime, which we have called diffusive regime, where diffusion is the controlling mechanism; and a high frequency regime, which we have called convective regime, where the degree of bending of the cilia seems to be the most important factor controlling mass transfer in the ciliated-layer. Since the flexibility of the cilia and the frequency of the beat changes with age and health conditions, the knowledge of these three regimes allows prediction of how mass transfer varies with these factors. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. Boundary layers in turbulent convection for air, liquid gallium and liquid sodium

    NASA Astrophysics Data System (ADS)

    Scheel, Janet; Schumacher, Joerg

    2017-11-01

    The scaling of physical quantities that characterize the shape and dynamics of the viscous and thermal boundary layers with respect to the Rayleigh number will be presented for three series of three-dimensional high-resolution direct numerical simulations of Rayleigh-Benard convection (RBC) in a closed cylindrical cell of aspect ratio one. The simulations have been conducted for convection in air at a Prandtl number Pr = 0.7, in liquid gallium at Pr = 0.021 and in liquid sodium at Pr = 0.005. Then we discuss three statistical analysis methods which have been developed to predict the transition of turbulent RBC into the ultimate regime. The methods are based on the large-scale properties of the velocity profile. All three methods indicate that the range of critical Rayleigh numbers is shifted to smaller magnitudes as the Prandtl number becomes smaller. This work is supported by the Priority Programme SPP 1881 of the Deutsche Forschungsgemeinschaft.

  14. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2012-04-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean, a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol (NR-PM1) was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition, small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions, could be identified in the particle phase

  15. Doppler lidar characterization of the boundary layer for aircraft mass-balance estimates of greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Hardesty, R.; Brewer, A.; Banta, R. M.; Senff, C. J.; Sandberg, S. P.; Alvarez, R. J.; Weickmann, A. M.; Sweeney, C.; Karion, A.; Petron, G.; Frost, G. J.; Trainer, M.

    2012-12-01

    Aircraft-based mass balance approaches are often used to estimate greenhouse gas emissions from distributed sources such as urban areas and oil and gas fields. A scanning Doppler lidar, which measures range-resolved wind and aerosol backscatter information, can provide important information on mixing and transport processes in the planetary boundary layer for these studies. As part of the Uintah Basin Winter Ozone Study, we deployed a high resolution Doppler lidar to characterize winds and turbulence, atmospheric mixing, and mixing layer depth in the oil and gas fields near Vernal, Utah. The lidar observations showed evolution of the horizontal wind field, vertical mixing and aerosol structure for each day during the 5-week deployment. This information was used in conjunction with airborne in situ observations of methane and carbon dioxide to compute methane fluxes and estimate basin-wide methane emissions. A similar experiment incorporating a lidar along with a radar wind profiler and instrumented aircraft was subsequently carried out in the vicinity of the Denver-Julesburg Basin in Colorado. Using examples from these two studies we discuss the use of Doppler lidar in conjunction with other sources of wind information and boundary layer structure for mass-balance type studies. Plans for a one-year deployment of a Doppler lidar as part of the Indianapolis Flux experiment to estimate urban-scale greenhouse gas emissions near are also presented.

  16. Boundary layer height determination from Lidar for improving air pollution episode modelling: development of new algorithm and evaluation

    NASA Astrophysics Data System (ADS)

    Yang, T.; Wang, Z.; Zhang, W.; Gbaguidi, A.; Sugimoto, N.; Matsui, I.; Wang, X.; Yele, S.

    2017-12-01

    Predicting air pollution events in low atmosphere over megacities requires thorough understanding of the tropospheric dynamic and chemical processes, involving notably, continuous and accurate determination of the boundary layer height (BLH). Through intensive observations experimented over Beijing (China), and an exhaustive evaluation existing algorithms applied to the BLH determination, persistent critical limitations are noticed, in particular over polluted episodes. Basically, under weak thermal convection with high aerosol loading, none of the retrieval algorithms is able to fully capture the diurnal cycle of the BLH due to pollutant insufficient vertical mixing in the boundary layer associated with the impact of gravity waves on the tropospheric structure. Subsequently, a new approach based on gravity wave theory (the cubic root gradient method: CRGM), is developed to overcome such weakness and accurately reproduce the fluctuations of the BLH under various atmospheric pollution conditions. Comprehensive evaluation of CRGM highlights its high performance in determining BLH from Lidar. In comparison with the existing retrieval algorithms, the CRGM potentially reduces related computational uncertainties and errors from BLH determination (strong increase of correlation coefficient from 0.44 to 0.91 and significant decreases of the root mean square error from 643 m to 142 m). Such newly developed technique is undoubtedly expected to contribute to improve the accuracy of air quality modelling and forecasting systems.

  17. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  18. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  19. Analysis of volatile compounds by open-air ionization mass spectrometry.

    PubMed

    Meher, Anil Kumar; Chen, Yu-Chie

    2017-05-08

    This study demonstrates a simple method for rapid and in situ identification of volatile and endogenous compounds in culinary spice samples through mass spectrometry (MS). This method only requires a holder for solid spice sample (2-3 mm) that is placed close to a mass spectrometer inlet, which is applied with a high voltage. Volatile species responsible for the aroma of the spice samples can be readily detected by the mass spectrometer. Sample pretreatment is not required prior to MS analysis, and no solvent was used during MS analysis. The high voltage applied to the inlet of the mass spectrometer induces the ionization of volatile compounds released from the solid spice samples. Furthermore, moisture in the air also contributes to the ionization of volatile compounds. Dried spices including cinnamon and cloves are used as the model sample to demonstrate this straightforward MS analysis, which can be completed within few seconds. Furthermore, we also demonstrate the suitability of the current method for rapid screening of cinnamon quality through detection of the presence of a hepatotoxic agent, i.e. coumarin. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Forced Boundary-Layer Transition on X-43 (Hyper-X) in NASA LaRC 20-Inch Mach 6 Air Tunnel

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; DiFulvio, Michael; Kowalkowski, Matthew K.

    2000-01-01

    Aeroheating and boundary layer transition characteristics for the X-43 (Hyper-X) configuration have been experimentally examined in the Langley 20-Inch Mach 6 Air Tunnel. Global surface heat transfer distributions, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. Parametric variations include angles-of-attack of 0-deg, 2-deg, and 4-deg; Reynolds numbers based on model length of 1.2 to 15.4 million; and inlet cowl door both open and closed. The effects of discrete roughness elements on the forebody boundary layer, which included variations in trip configuration and height, were investigated. This document is intended to serve as a release of preliminary data to the Hyper-X program; analysis is limited to observations of the experimental trends in order to expedite dissemination.

  1. Transition within a Hypervelocity Boundary Layer on a 5-degree Half-Angle Cone in Freestream Air/CO2 Mixtures

    DTIC Science & Technology

    2013-01-01

    Pasadena, CA, 91125 Nomenclature A = amplitude of oscillation f = frequency hres = reservoir enthalpy Me = boundary layer edge Mach number Pres...showed an increase in the reference Reynolds number Re* at the point of transition as reservoir enthalpy hres increased. Germain and Adam also observed...that flows of CO2 transitioned at higher values of Re* than flows of air for the same hres and Pres. Johnson et al. (1998) studied this effect with a

  2. Boundary Layer Control on Airfoils.

    ERIC Educational Resources Information Center

    Gerhab, George; Eastlake, Charles

    1991-01-01

    A phenomena, boundary layer control (BLC), produced when visualizing the fluidlike flow of air is described. The use of BLC in modifying aerodynamic characteristics of airfoils, race cars, and boats is discussed. (KR)

  3. Assessment of the uncertainties in air mass and pollutants transboundary exchange over the continental part of the EANET region

    NASA Astrophysics Data System (ADS)

    Gromov, Sergey S.; Trifonova-Yakovleva, Alisa; Gromov, Sergey A.

    2017-04-01

    In this study, we attempt to quantify the uncertainties in air mass exchange in the lower troposphere across two regions of the Russian border in Eastern Siberia and the Russian Far East in 2000-2015. We use meteorological data from long-term air sound data (ASD) on mean layer winds [1] and from the ERA INTERIM re-analysis (EIR) project [2]. Using a transboundary exchange model, we estimate the total and net amounts of air crossing the boundary segments around Irkutsk (IR) and Vladivostok (VL) aerological stations. We compare transport terms derived (i) from the long-term wind statistics based on both ASD and EIR data, and (ii) from integrating 6h meteorological winds from EIR directly over the border segments cells. We find similar wind direction statistics in both meteorological datasets, however EIR favours stronger westerly winds at VL in summer, which results in more often air export from China to Russia in the Far East. There is less agreement on the wind strengths than wind directions between the datasets, with EIR often providing slower wind speeds. The resulting climatic (ASD) and directly (from EIR 6h terms) calculated non-equilibrium (net) transport terms are comparable in orders (tens of million km3/month), however may differ substantially in temporal evolution or/and magnitude. Thus, EIR net transport over the IR segment has similar annual dynamics but is higher by a factor of ˜ 4 (maxima of 3.6 vs. 12 of 106 km3/month in December, respectively). An opposite ratio is derived for the VL segment (average ˜ 6 vs. 13 of 106 km3/month), with a distinct seasonality in the ASD but not in the EIR data. We attribute this discrepancy to the variations in wind direction with altitude, which cannot be resolved in the model fed with the ASD data. Calculated transport in the boundary layer (BL, provided by the EIR) supports this inference. Thus, the BL net transport temporal dynamics differ substantially from that within the 3 km layer, owing to the BL diurnal

  4. Peroxyacetyl nitrate in the North Atlantic marine boundary layer (GBC #10)

    NASA Astrophysics Data System (ADS)

    Gallagher, Michael S.; Carsey, Thomas P.; Farmer, Michael L.

    1990-09-01

    An automated system utilizing packed column gas chromatography and electron capture detection for the determination of peroxyacetyl nitrate (PAN) is described. The system was calibrated with a cryogenic PAN sublimation device, a molybdenum catalyst, and a chemiluminescent nitric oxide detector. Computer control of the analysis resulted in an analytical precision level of ˜1%. A total of 1178 PAN measurements were made from August 6 to September 5, 1988, in the marine boundary layer during the GCE/CASE/WATOX cruise (66°N to 7°N). Overall, PAN concentrations were highest at high latitudes (up to 40 ppt); PAN levels in the lower latitudes of the cruise track were usually <10 ppt. A number of episodes of elevated PAN are described which were characterized by elevated radon concentrations and a discernible diurnal cycle in the PAN concentration. These higher PAN levels are attributed to air masses with some continental influence, and to the enhanced stability of PAN at the cooler temperatures characteristic of the sub-Arctic region. In aged air masses of marine origin, PAN concentrations were significantly less and did not display diel changes; this is interpreted as a measure of the "background" PAN signal.

  5. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with continental, urban and marine air masses at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2011-12-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions could be identified in the particle phase. In all

  6. Boundary-Layer-Ingesting Inlet Flow Control

    NASA Technical Reports Server (NTRS)

    Owens, Lewis R.; Allan, Brian G.; Gorton, Susan A.

    2008-01-01

    An experimental study was conducted to provide the first demonstration of an active flow control system for a flush-mounted inlet with significant boundary-layer-ingestion in transonic flow conditions. The effectiveness of the flow control in reducing the circumferential distortion at the engine fan-face location was assessed using a 2.5%-scale model of a boundary-layer-ingesting offset diffusing inlet. The inlet was flush mounted to the tunnel wall and ingested a large boundary layer with a boundary-layer-to-inlet height ratio of 35%. Different jet distribution patterns and jet mass flow rates were used in the inlet to control distortion. A vane configuration was also tested. Finally a hybrid vane/jet configuration was tested leveraging strengths of both types of devices. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow rates through the duct and the flow control actuators. The distortion and pressure recovery were measured at the aerodynamic interface plane. The data show that control jets and vanes reduce circumferential distortion to acceptable levels. The point-design vane configuration produced higher distortion levels at off-design settings. The hybrid vane/jet flow control configuration reduced the off-design distortion levels to acceptable ones and used less than 0.5% of the inlet mass flow to supply the jets.

  7. Southeast Atlantic Cloud Properties in a Multivariate Statistical Model - How Relevant is Air Mass History for Local Cloud Properties?

    NASA Astrophysics Data System (ADS)

    Fuchs, Julia; Cermak, Jan; Andersen, Hendrik

    2017-04-01

    This study aims at untangling the impacts of external dynamics and local conditions on cloud properties in the Southeast Atlantic (SEA) by combining satellite and reanalysis data using multivariate statistics. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget, and thus prominent in climate-system research. In this study, SEA stratocumulus cloud properties are observed not only as the result of local environmental conditions but also as affected by external dynamics and spatial origins of air masses entering the study area. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a multivariate approach is conducted using satellite observations of aerosol and cloud properties (MODIS, SEVIRI), information on aerosol species composition (MACC) and meteorological context (ERA-Interim reanalysis). To account for the often-neglected but important role of air mass origin, information on air mass history based on HYSPLIT modeling is included in the statistical model. This multivariate approach is intended to lead to a better understanding of the physical processes behind observed stratocumulus cloud properties in the SEA.

  8. Predictions and Verification of an Isotope Marine Boundary Layer Model

    NASA Astrophysics Data System (ADS)

    Feng, X.; Posmentier, E. S.; Sonder, L. J.; Fan, N.

    2017-12-01

    A one-dimensional (1D), steady state isotope marine boundary layer (IMBL) model is constructed. The model includes meteorologically important features absent in Craig and Gordon type models, namely height-dependent diffusion/mixing and convergence of subsiding external air. Kinetic isotopic fractionation results from this height-dependent diffusion which starts as pure molecular diffusion at the air-water interface and increases linearly with height due to turbulent mixing. The convergence permits dry, isotopically depleted air subsiding adjacent to the model column to mix into ambient air. In δD-δ18O space, the model results fill a quadrilateral, of which three sides represent 1) vapor in equilibrium with various sea surface temperatures (SSTs) (high d18O boundary of quadrilateral); 2) mixture of vapor in equilibrium with seawater and vapor in the subsiding air (lower boundary depleted in both D and 18O); and 3) vapor that has experienced the maximum possible kinetic fractionation (high δD upper boundary). The results can be plotted in d-excess vs. δ18O space, indicating that these processes all cause variations in d-excess of MBL vapor. In particular, due to relatively high d-excess in the descending air, mixing of this air into the MBL causes an increase in d-excess, even without kinetic isotope fractionation. The model is tested by comparison with seven datasets of marine vapor isotopic ratios, with excellent correspondence; >95% of observational data fall within the quadrilateral area predicted by the model. The distribution of observations also highlights the significant influence of vapor from the nearby converging descending air on isotopic variations in the MBL. At least three factors may explain the <5% of observations that fall slightly outside of the predicted region in both δD-δ18O and d-excess - δ18O space: 1) variations in seawater isotopic ratios, 2) variations in isotopic composition of subsiding air, and 3) influence of sea spray. The model

  9. Multiple sulfur-isotopic evidence for a shallowly stratified ocean following the Triassic-Jurassic boundary mass extinction

    NASA Astrophysics Data System (ADS)

    Luo, Genming; Richoz, Sylvain; van de Schootbrugge, Bas; Algeo, Thomas J.; Xie, Shucheng; Ono, Shuhei; Summons, Roger E.

    2018-06-01

    The cause of the Triassic-Jurassic (Tr-J) boundary biotic crisis, one of the 'Big Five' mass extinctions of the Phanerozoic, remains controversial. In this study, we analyzed multiple sulfur-isotope compositions (δ33S, δ34S and δ36S) of pyrite and Spy/TOC ratios in two Tr-J successions (Mariental, Mingolsheim) from the European Epicontinental Seaway (EES) in order to better document ocean-redox variations during the Tr-J transition. Our results show that upper Rhaetian strata are characterized by 34S-enriched pyrite, low Spy/TOC ratios, and values of Δ33Spy (i.e., the deviation from the mass-dependent array) lower than that estimated for contemporaneous seawater sulfate, suggesting an oxic-suboxic depositional environment punctuated by brief anoxic events. The overlying Hettangian strata exhibit relatively 34S-depleted pyrite, high Δ33Spy, and Spy/TOC values, and the presence of green sulfur bacterial biomarkers indicate a shift toward to euxinic conditions. The local development of intense marine anoxia thus postdated the Tr-J mass extinction, which does not provide support for the hypothesis that euxinia was the main killing agent at the Tr-J transition. Sulfur and organic carbon isotopic records that reveal a water-depth gradient (i.e., more 34S-, 13C-depleted with depth) in combination with Spy/TOC data suggest that the earliest Jurassic EES was strongly stratified, with a chemocline located at shallow depths just below storm wave base. Shallow oceanic stratification may have been a factor for widespread deposition of black shales, a large positive shift in carbonate δ13C values, and a delay in the recovery of marine ecosystems following the Tr-J boundary crisis.

  10. Boundary-Layer Transition on a Slender Cone in Hypervelocity Flow with Real Gas Effects

    NASA Astrophysics Data System (ADS)

    Jewell, Joseph Stephen

    The laminar to turbulent transition process in boundary layer flows in thermochemical nonequilibrium at high enthalpy is measured and characterized. Experiments are performed in the T5 Hypervelocity Reflected Shock Tunnel at Caltech, using a 1 m length 5-degree half angle axisymmetric cone instrumented with 80 fast-response annular thermocouples, complemented by boundary layer stability computations using the STABL software suite. A new mixing tank is added to the shock tube fill apparatus for premixed freestream gas experiments, and a new cleaning procedure results in more consistent transition measurements. Transition location is nondimensionalized using a scaling with the boundary layer thickness, which is correlated with the acoustic properties of the boundary layer, and compared with parabolized stability equation (PSE) analysis. In these nondimensionalized terms, transition delay with increasing CO2 concentration is observed: tests in 100% and 50% CO2, by mass, transition up to 25% and 15% later, respectively, than air experiments. These results are consistent with previous work indicating that CO2 molecules at elevated temperatures absorb acoustic instabilities in the MHz range, which is the expected frequency of the Mack second-mode instability at these conditions, and also consistent with predictions from PSE analysis. A strong unit Reynolds number effect is observed, which is believed to arise from tunnel noise. NTr for air from 5.4 to 13.2 is computed, substantially higher than previously reported for noisy facilities. Time- and spatially-resolved heat transfer traces are used to track the propagation of turbulent spots, and convection rates at 90%, 76%, and 63% of the boundary layer edge velocity, respectively, are observed for the leading edge, centroid, and trailing edge of the spots. A model constructed with these spot propagation parameters is used to infer spot generation rates from measured transition onset to completion distance. Finally, a novel

  11. Ozone Modulation/Membrane Introduction Mass Spectrometry for Analysis of Hydrocarbon Pollutants in Air

    NASA Astrophysics Data System (ADS)

    Atkinson, D. B.

    2001-12-01

    Modulation of volatile hydrocarbons in two-component mixtures is demonstrated using an ozonolysis pretreatment with membrane introduction mass spectrometry (MIMS). The MIMS technique allows selective introduction of volatile and semivolatile analytes into a mass spectrometer via processes known collectively as pervaporation [Kotiaho and Cooks, 1992]. A semipermeable polymer membrane acts as an interface between the sample (vapor or solution) and the vacuum of the mass spectrometer. This technique has been demonstrated to allow for sensitive analysis of hydrocarbons and other non-polar volatile organic compounds (VOC`s) in air samples[Cisper et al., 1995] . The methodology has the advantages of no sample pretreatment and short analysis time, which are promising for online monitoring applications but the chief disadvantage of lack of a separation step for the different analytes in a mixture. Several approaches have been investigated to overcome this problem including use of selective chemical ionization [Bier and Cooks, 1987] and multivariate calibration techniques[Ketola et al., 1999] . A new approach is reported for the quantitative measurement of VOCs in complex matrices. The method seeks to reduce the complexity of mass spectra observed in hydrocarbon mixture analysis by selective pretreatment of the analyte mixture. In the current investigation, the rapid reaction of ozone with alkenes is used, producing oxygenated compounds which are suppressed by the MIMS system. This has the effect of removing signals due to unsaturated analytes from the compound mass spectra, and comparison of the spectra before and after the ozone treatment reveals the nature of the parent compounds. In preliminary investigations, ozone reacted completely with cyclohexene from a mixture of cylohexene and cyclohexane, and with β -pinene from a mixture of toluene and β -pinene, suppressing the ion signals from the olefins. A slight attenuation of the cyclohexane and toluene in those

  12. Diode laser-based air mass flux sensor for subsonic aeropropulsion inlets

    NASA Astrophysics Data System (ADS)

    Miller, Michael F.; Kessler, William J.; Allen, Mark G.

    1996-08-01

    An optical air mass flux sensor based on a compact, room-temperature diode laser in a fiber-coupled delivery system has been tested on a full-scale gas turbine engine. The sensor is based on simultaneous measurements of O 2 density and Doppler-shifted velocity along a line of sight across the inlet duct. Extensive tests spanning engine power levels from idle to full afterburner demonstrate accuracy and precision of the order of 1 2 of full scale in density, velocity, and mass flux. The precision-limited velocity at atmospheric pressure was as low as 40 cm s. Multiple data-reduction procedures are quantitatively compared to suggest optimal strategies for flight sensor packages.

  13. A Simulation Study of the Overdetermined Geodetic Boundary Value Problem Using Collocation

    DTIC Science & Technology

    1989-03-01

    9 APPROVED FOR PUBLIC RELEASE; DISTRIBUTION UNLIMITED GEOPHYSICS LABORATORY AIR FORCE SYSTEMS COMMAND UNITED STATES AIR FORCE HANSCOM AIR FORCE BASE...linearized integral equation is obtained through an infinite system of integral equations which is solved step by step by means of Stokes’ function. The...computed. Since 9 and W = W(9) 4 are known on the boundary, then the boundary is known in the new coordinate system . The serious disadvantage of this

  14. Calculation methods for compressible turbulent boundary layers, 1976

    NASA Technical Reports Server (NTRS)

    Bushnell, D. M.; Cary, A. M., Jr.; Harris, J. E.

    1977-01-01

    Equations and closure methods for compressible turbulent boundary layers are discussed. Flow phenomena peculiar to calculation of these boundary layers were considered, along with calculations of three dimensional compressible turbulent boundary layers. Procedures for ascertaining nonsimilar two and three dimensional compressible turbulent boundary layers were appended, including finite difference, finite element, and mass-weighted residual methods.

  15. Influence of Evaporating Droplets in the Turbulent Marine Atmospheric Boundary Layer

    NASA Astrophysics Data System (ADS)

    Peng, Tianze; Richter, David

    2017-12-01

    Sea-spray droplets ejected into the marine atmospheric boundary layer take part in a series of complex transport processes. By capturing the air-droplet coupling and feedback, we focus on how droplets modify the total heat transfer across a turbulent boundary layer. We implement a high-resolution Eulerian-Lagrangian algorithm with varied droplet size and mass loading in a turbulent open-channel flow, revealing that the influence from evaporating droplets varies for different dynamic and thermodynamic characteristics of droplets. Droplets that both respond rapidly to the ambient environment and have long suspension times are able to modify the latent and sensible heat fluxes individually, however the competing signs of this modification lead to an overall weak effect on the total heat flux. On the other hand, droplets with a slower thermodynamic response to the environment are less subjected to this compensating effect. This indicates a potential to enhance the total heat flux, but the enhancement is highly dependent on the concentration and suspension time.

  16. Mass extinction of ocean organisms at the Paleozoic-Mesozoic boundary: Effects and causes

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2012-04-01

    At the end of the Permian, at the boundary between the Paleozoic and Mesozoic (251.0 ± 0.4 Ma), the largest mass extinction of organisms on the Earth occurred. Up to 96% of the species of marine invertebrates and ˜70% of the terrestrial vertebrates died off. A lot of factors were suggested and substantiated to explain this mass mortality, such as the disappearance of environmental niches in the course of the amalgamation of the continental plates into Pangea, sea level fluctuations, anoxia, an elevated CO2 content, H2S intoxication, volcanism, methane discharge from gas-hydrates, climate changes, impact events (collisions with large asteroids), or combinations of many of these reasons. Some of these factors are in subordination to others, while others are independent. Almost all of these factors developed relatively slowly and could not cause the sudden mass mortality of organisms globally. It could have happened when large asteroids, whose craters have been discovered lately, fell to the Earth. It is suggested that the impact events "finished off" the already suppressed biota. A simultaneous change in many of the factors responsible for the biodiversity, including those not connected in a cause-and-effect relationship, proves the existence of a common extrater-restrial cause that affected both the changes in the internal and external geospheres and the activation of asteroid attacks (the Sun's transit of spiral arms of our galaxy, the Sun's oscillations perpendicularly to the galactic plane, etc).

  17. Air-sea heat flux control on the Yellow Sea Cold Water Mass intensity and implications for its prediction

    NASA Astrophysics Data System (ADS)

    Zhu, Junying; Shi, Jie; Guo, Xinyu; Gao, Huiwang; Yao, Xiaohong

    2018-01-01

    The Yellow Sea Cold Water Mass (YSCWM), which occurs during summer in the central Yellow Sea, plays an important role in the hydrodynamic field, nutrient cycle and biological species. Based on water temperature observations during the summer from 1978 to 1998 in the western Yellow Sea, five specific YSCWM years were identified, including two strong years (1984 and 1985), two weak years (1989 and 1995) and one normal year (1992). Using a three-dimensional hydrodynamic model, the YSCWM formation processes in these five years were simulated and compared with observations. In general, the YSCWM began forming in spring, matured in summer and gradually disappeared in autumn of every year. The 8 °C isotherm was used to indicate the YSCWM boundary. The modelled YSCWM areas in the two strong years were approximately two times larger than those in the two weak years. Based on the simulations in the weak year of 1995, ten numerical experiments were performed to quantify the key factors influencing the YSCWM intensity by changing the initial water condition in the previous autumn, air-sea heat flux, wind, evaporation, precipitation and sea level pressure to those in the strong year of 1984, respectively. The results showed that the air-sea heat flux was the dominant factor influencing the YSCWM intensity, which contributed about 80% of the differences of the YSCWM average water temperature at a depth of 50 m. In addition, the air-sea heat flux in the previous winter had a determining effect, contributing more than 50% of the differences between the strong and weak YSCWM years. Finally, a simple formula for predicting the YSCWM intensity was established by using the key influencing factors, i.e., the sea surface temperature before the cooling season and the air-sea heat flux during the cooling season from the previous December to the current February. With this formula, instead of a complicated numerical model, we were able to roughly predict the YSCWM intensity for the

  18. Forced Boundary-Layer Transition on X-43 (Hyper-X) in NASA LaRC 31-Inch Mach 10 Air Tunnel

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; DiFulvio, Michael; Kowalkowski, Matthew K.

    2000-01-01

    Aeroheating and boundary layer transition characteristics for the X-43 (Hyper-X) configuration have been experimentally examined in the Langley 31-Inch Mach 10 Air Tunnel. Global surface heat transfer distributions, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. Parametric variations include angles-of-attack of 0-deg, 2-deg, 3-deg, and 4-deg; Reynolds numbers based on model length of 1.2 to 5.1 million; and inlet cowl door both open and closed. The effects of discrete roughness elements on the forebody boundary layer, which included variations in trip configuration and height, were investigated. This document is intended to serve as a release of preliminary data to the Hyper-X program; analysis is limited to observations of the experimental trends in order to expedite dissemination.

  19. Finite-Rate Ablation Boundary Conditions for Carbon-Phenolic Heat-Shield

    NASA Technical Reports Server (NTRS)

    Chen, Y.-K.; Milos, Frank S.

    2003-01-01

    A formulation of finite-rate ablation surface boundary conditions, including oxidation, nitridation, and sublimation of carbonaceous material with pyrolysis gas injection, has been developed based on surface species mass conservation. These surface boundary conditions are discretized and integrated with a Navier-Stokes solver. This numerical procedure can predict aerothermal heating, chemical species concentration, and carbonaceous material ablation rate over the heatshield surface of re-entry space vehicles. In this study, the gas-gas and gas-surface interactions are established for air flow over a carbon-phenolic heatshield. Two finite-rate gas-surface interaction models are considered in the present study. The first model is based on the work of Park, and the second model includes the kinetics suggested by Zhluktov and Abe. Nineteen gas phase chemical reactions and four gas-surface interactions are considered in the present model. There is a total of fourteen gas phase chemical species, including five species for air and nine species for ablation products. Three test cases are studied in this paper. The first case is a graphite test model in the arc-jet stream; the second is a light weight Phenolic Impregnated Carbon Ablator at the Stardust re-entry peak heating conditions, and the third is a fully dense carbon-phenolic heatshield at the peak heating point of a proposed Mars Sample Return Earth Entry Vehicle. Predictions based on both finite-rate gas- surface interaction models are compared with those obtained using B' tables, which were created based on the chemical equilibrium assumption. Stagnation point convective heat fluxes predicted using Park's finite-rate model are far below those obtained from chemical equilibrium B' tables and Zhluktov's model. Recession predictions from Zhluktov's model are generally lower than those obtained from Park's model and chemical equilibrium B' tables. The effect of species mass diffusion on predicted ablation rate is also

  20. Lidar Measurements of Wind, Moisture, and Boundary Layer Evolution in a Dry Line during 1HOP 2002

    NASA Technical Reports Server (NTRS)

    Demoz, Belay; Evans, Keith; DiGirolamo, Paolo; Wang, Zhe-In; Whiteman, David; Schwemmer, Geary; Gentry, Bruce; Miller, David; Palm, Stephen

    2002-01-01

    Variability in the convective boundary layer moisture, wind and temperature fields and their importance in the forecasting and understanding of storms have been discussed in the literature. These . variations have been reported in relation to frontal zones, stationary boundaries and during horizontal convective rolls. While all three vary substantially in the convective boundary layer, moisture poses a particular challenge. Moisture or water vapor concentration (expressed as a mass mixing ratio, g/kg), is conserved in all meteorological processes except condensation and evaporation. The water vapor mixing ratio often remains distinct across an air-mass boundary even when the temperature difference is indistinct. These properties make it an ideal choice in visualizing and understanding many of the atmosphere's dynamic features. However, it also presents a unique measurement challenge because water vapor content can vary by more than three orders of magnitude in the troposphere. Characterization of the 3D-distribution of water vapor is also difficult as water vapor observations can suffer from large sampling errors and substantial variability both in the vertical and horizontal. This study presents ground-based measurements of wind, boundary layer structure and water vapor mixing ratio measurements observed by three co-located lidars. This presentation will focus on the evolution and variability of moisture and wind in the boundary layer during a dry line event that occurred on 22 May 2002. These data sets and analyses are unique in that they combine simultaneous measurements of wind, moisture and CBL structure to study the detailed thermal variability in and around clear air updrafts during a dryline event. It will quantify the variation caused by, in and around buoyant plumes and across a dryline. The data presented here were collected in the panhandle of Oklahoma as part of the International H2O Project (MOP-2002), a field experiment that took place over the

  1. Entrainment of stratospheric air and Asian pollution by the convective boundary layer in the southwestern U.S.

    NASA Astrophysics Data System (ADS)

    Langford, A. O.; Alvarez, R. J.; Brioude, J.; Fine, R.; Gustin, M. S.; Lin, M. Y.; Marchbanks, R. D.; Pierce, R. B.; Sandberg, S. P.; Senff, C. J.; Weickmann, A. M.; Williams, E. J.

    2017-01-01

    A series of deep stratospheric intrusions in late May 2013 increased the daily maximum 8 h surface ozone (O3) concentrations to more than 70 parts per billion by volume (ppbv) at rural and urban surface monitors in California and Nevada. This influx of ozone-rich lower stratospheric air and entrained Asian pollution persisted for more than 5 days and contributed to exceedances of the 2008 8 h national ambient air quality standard of 75 ppbv on 21 and 25 May in Clark County, NV. Exceedances would also have occurred on 22 and 23 May had the new standard of 70 ppbv been in effect. In this paper, we examine this episode using lidar measurements from a high-elevation site on Angel Peak, NV, and surface measurements from NOAA, the Clark County, Nevada Department of Air Quality, the Environmental Protection Agency Air Quality System, and the Nevada Rural Ozone Initiative. These measurements, together with analyses from the National Centers for Environmental Prediction/North American Regional Reanalysis; NOAA Geophysical Fluid Dynamics Laboratory AM3 model; NOAA National Environmental Satellite, Data, and Information Service Real-time Air Quality Modeling System; and FLEXPART models, show that the exceedances followed entrainment of 20 to 40 ppbv of lower stratospheric ozone mingled with another 0 to 10 ppbv of ozone transported from Asia by the unusually deep convective boundary layers above the Mojave desert. Our analysis suggests that this vigorous mixing can affect both high and low elevations and help explain the springtime ozone maximum in the southwestern U.S.

  2. Prediction and rational correlation of thermophoretically reduced particle mass transfer to hot surfaces across laminar or turbulent forced-convection gas boundary layers

    NASA Technical Reports Server (NTRS)

    Gokoglu, Suleyman A.; Rosner, Daniel E.

    1986-01-01

    A formulation previously developed to predict and correlate the thermophoretically-augmented submicron particle mass transfer rate to cold surfaces is found to account for the thermophoretically reduced particle mass transfer rate to overheated surfaces such that thermophoresis brings about a 10-decade reduction below the convective mass transfer rate expected by pure Brownian diffusion and convection alone. Thermophoretic blowing is shown to produce effects on particle concentration boundary-layer (BL) structure and wall mass transfer rates similar to those produced by real blowing through a porous wall. The applicability of the correlations to developing BL-situations is demonstrated by a numerical example relevant to wet-steam technology.

  3. Time-dependent boundary conditions for hyperbolic systems. II

    NASA Technical Reports Server (NTRS)

    Thompson, Kevin W.

    1990-01-01

    A general boundary condition formalism is developed for all types of boundary conditions to which hyperbolic systems are subject; the formalism makes possible a 'cookbook' approach to boundary conditions, by means of which novel boundary 'recipes' may be derived and previously devised ones may be consulted as required. Numerous useful conditions are derived for such CFD problems as subsonic and supersonic inflows and outflows, nonreflecting boundaries, force-free boundaries, constant pressure boundaries, and constant mass flux. Attention is given to the computation and integration of time derivatives.

  4. Time-dependent boundary conditions for hyperbolic systems. II

    NASA Astrophysics Data System (ADS)

    Thompson, Kevin W.

    1990-08-01

    A general boundary condition formalism is developed for all types of boundary conditions to which hyperbolic systems are subject; the formalism makes possible a 'cookbook' approach to boundary conditions, by means of which novel boundary 'recipes' may be derived and previously devised ones may be consulted as required. Numerous useful conditions are derived for such CFD problems as subsonic and supersonic inflows and outflows, nonreflecting boundaries, force-free boundaries, constant pressure boundaries, and constant mass flux. Attention is given to the computation and integration of time derivatives.

  5. Uncertainty evaluation of mass values determined by electronic balances in analytical chemistry: a new method to correct for air buoyancy.

    PubMed

    Wunderli, S; Fortunato, G; Reichmuth, A; Richard, Ph

    2003-06-01

    A new method to correct for the largest systematic influence in mass determination-air buoyancy-is outlined. A full description of the most relevant influence parameters is given and the combined measurement uncertainty is evaluated according to the ISO-GUM approach [1]. A new correction method for air buoyancy using an artefact is presented. This method has the advantage that only a mass artefact is used to correct for air buoyancy. The classical approach demands the determination of the air density and therefore suitable equipment to measure at least the air temperature, the air pressure and the relative air humidity within the demanded uncertainties (i.e. three independent measurement tasks have to be performed simultaneously). The calculated uncertainty is lower for the classical method. However a field laboratory may not always be in possession of fully traceable measurement systems for these room climatic parameters.A comparison of three approaches applied to the calculation of the combined uncertainty of mass values is presented. Namely the classical determination of air buoyancy, the artefact method, and the neglecting of this systematic effect as proposed in the new EURACHEM/CITAC guide [2]. The artefact method is suitable for high-precision measurement in analytical chemistry and especially for the production of certified reference materials, reference values and analytical chemical reference materials. The method could also be used either for volume determination of solids or for air density measurement by an independent method.

  6. Diffusion of volatile organics through porous snow: impact of surface adsorption and grain boundaries

    NASA Astrophysics Data System (ADS)

    Bartels-Rausch, T.; Wren, S. N.; Schreiber, S.; Riche, F.; Schneebeli, M.; Ammann, M.

    2013-03-01

    Release of trace gases from surface snow on Earth drives atmospheric chemistry, especially in the polar regions. The gas-phase diffusion of methanol and of acetone through the interstitial air of snow was investigated in a well-controlled laboratory study in the temperature range of 223 to 263 K. The aim of this study was to evaluate how the structure of the snowpack, the interaction of the trace gases with the snow surface, and the grain boundaries influence the diffusion on timescales up to 1 h. The diffusive loss of these two volatile organics into packed snow samples was measured using a chemical ionization mass spectrometer. The structure of the snow was analyzed by means of X-ray computed micro-tomography. The observed diffusion profiles could be well described based on gas-phase diffusion and the known structure of the snow sample at temperatures ≥ 253 K. At colder temperatures surface interactions start to dominate the diffusive transport. Parameterizing these interactions in terms of adsorption to the solid ice surface, i.e. using temperature dependent air-ice partitioning coefficients, better described the observed diffusion profiles than the use of air-liquid partitioning coefficients. No changes in the diffusive fluxes were observed by increasing the number of grain boundaries in the snow sample by a factor of 7, indicating that for these volatile organic trace gases, uptake into grain boundaries does not play a role on the timescale of diffusion through porous surface snow. In conclusion, we have shown that the diffusivity can be predicted when the structure of the snowpack and the partitioning of the trace gas to solid ice is known.

  7. AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

    EPA Science Inventory

    Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

  8. Two-dimensional CFD modeling of the heat and mass transfer process during sewage sludge drying in a solar dryer

    NASA Astrophysics Data System (ADS)

    Krawczyk, Piotr; Badyda, Krzysztof

    2011-12-01

    The paper presents key assumptions of the mathematical model which describes heat and mass transfer phenomena in a solar sewage drying process, as well as techniques used for solving this model with the Fluent computational fluid dynamics (CFD) software. Special attention was paid to implementation of boundary conditions on the sludge surface, which is a physical boundary between the gaseous phase - air, and solid phase - dried matter. Those conditions allow to model heat and mass transfer between the media during first and second drying stages. Selection of the computational geometry is also discussed - it is a fragment of the entire drying facility. Selected modelling results are presented in the final part of the paper.

  9. Determination of 1-octanol-air partition coefficient using gaseous diffusion in the air boundary layer.

    PubMed

    Ha, Yeonjeong; Kwon, Jung-Hwan

    2010-04-15

    Exact determination of the partition coefficient between 1-octanol and air (K(OA)) is very important because it is a key descriptor for describing the thermodynamic partitioning between the air and organic phases. In spite of its importance, the number and quality of experimental K(OA) values for hydrophobic organic chemicals are limited because of experimental difficulties. Thus, to measure K(OA) values, a high-throughput method was developed that used liquid-phase extraction with 1-octanol drop at the tip of a microsyringe needle. The concentration in the headspace surrounding the 1 muL octanol drop was equilibrated with liquid octanol containing polycyclic aromatic hydrocarbons (PAHs). The change in concentrations of PAHs in the octanol drop was measured to obtain mass transfer rate constants, and these rate constants were then converted into K(OA) values using a film diffusion model. Thirteen polycyclic aromatic hydrocarbons with log K(OA) between 5 and 12 were chosen for the proof of the principle. Experimental determination of log K(OA) was accomplished in 30 h for PAHs with their log K(OA) less than 11. The measured log K(OA) values were very close to those obtained by various experimental and estimation methods in the literature, suggesting that this new method can provide a fast and easy determination of log K(OA) values for many chemicals of environmental interests. In addition, the applicability of the method can be extended to determine Henry's law constant for compounds with low vapor pressure and to estimate gaseous transfer rate of semivolatile compounds for environmental fate modeling.

  10. Comments on Hypersonic Boundary-Layer Transition

    DTIC Science & Technology

    1990-09-01

    mechanism by which boundary-layer disturbance growth is generally initiated and establishes the initial distur- banca amplitude at the onset of disturbance...Patankar, S. V., and Spalding, P. B., Heat and Mass Transfer in Boundary Lavers, CRC Press , Cleveland, Ohio, 1968. 87. Neumann, R. D., and Patterson, .J. 1

  11. Tropospheric ozone and aerosols measured by airborne lidar during the 1988 Arctic boundary layer experiment

    NASA Technical Reports Server (NTRS)

    Browell, Edward V.; Butler, Carolyn F.; Kooi, Susan A.

    1991-01-01

    Ozone (O3) and aerosol distributions were measured from an aircraft using a differential absorption lidar (DIAL) system as part of the 1988 NASA Global Tropospheric Experiment - Arctic Boundary Layer Experiment (ABLE-3A) to study the sources and sinks of gases and aerosols over the tundra regions of Alaska during the summer. The tropospheric O3 budget over the Arctic was found to be strongly influenced by stratospheric intrusions. Regions of low aerosol scattering and enhanced O3 mixing ratios were usually correlated with descending air from the upper troposphere or lower stratosphere. Several cases of continental polar air masses were examined during the experiment. The aerosol scattering associated with these air masses was very low, and the atmospheric distribution of aerosols was quite homogeneous for those air masses that had been transported over the ice for greater than or = 3 days. The transition in O3 and aerosol distributions from tundra to marine conditions was examined several times. The aerosol data clearly show an abrupt change in aerosol scattering properties within the mixed layer from lower values over the tundra to generally higher values over the water. The distinct differences in the heights of the mixed layers in the two regions was also readily apparent. Several cases of enhanced O3 were observed during ABLE-3 in conjunction with enhanced aerosol scattering in layers in the free atmosphere. Examples are presented of the large scale variations of O3 and aerosols observed with the airborne lidar system from near the surface to above the tropopause over the Arctic during ABLE-3.

  12. Contrasting cloud composition between coupled and decoupled marine boundary layer clouds

    NASA Astrophysics Data System (ADS)

    Wang, Zhen; Mora Ramirez, Marco; Dadashazar, Hossein; MacDonald, Alex B.; Crosbie, Ewan; Bates, Kelvin H.; Coggon, Matthew M.; Craven, Jill S.; Lynch, Peng; Campbell, James R.; Azadi Aghdam, Mojtaba; Woods, Roy K.; Jonsson, Haflidi; Flagan, Richard C.; Seinfeld, John H.; Sorooshian, Armin

    2016-10-01

    Marine stratocumulus clouds often become decoupled from the vertical layer immediately above the ocean surface. This study contrasts cloud chemical composition between coupled and decoupled marine stratocumulus clouds for dissolved nonwater substances. Cloud water and droplet residual particle composition were measured in clouds off the California coast during three airborne experiments in July-August of separate years (Eastern Pacific Emitted Aerosol Cloud Experiment 2011, Nucleation in California Experiment 2013, and Biological and Oceanic Atmospheric Study 2015). Decoupled clouds exhibited significantly lower air-equivalent mass concentrations in both cloud water and droplet residual particles, consistent with reduced cloud droplet number concentration and subcloud aerosol (Dp > 100 nm) number concentration, owing to detachment from surface sources. Nonrefractory submicrometer aerosol measurements show that coupled clouds exhibit higher sulfate mass fractions in droplet residual particles, owing to more abundant precursor emissions from the ocean and ships. Consequently, decoupled clouds exhibited higher mass fractions of organics, nitrate, and ammonium in droplet residual particles, owing to effects of long-range transport from more distant sources. Sodium and chloride dominated in terms of air-equivalent concentration in cloud water for coupled clouds, and their mass fractions and concentrations exceeded those in decoupled clouds. Conversely, with the exception of sea-salt constituents (e.g., Cl, Na, Mg, and K), cloud water mass fractions of all species examined were higher in decoupled clouds relative to coupled clouds. Satellite and Navy Aerosol Analysis and Prediction System-based reanalysis data are compared with each other, and the airborne data to conclude that limitations in resolving boundary layer processes in a global model prevent it from accurately quantifying observed differences between coupled and decoupled cloud composition.

  13. Atmospheric pollutants in Chiang Mai (Thailand) over a five-year period (2005-2009), their possible sources and relation to air mass movement

    NASA Astrophysics Data System (ADS)

    Chantara, Somporn; Sillapapiromsuk, Sopittaporn; Wiriya, Wan

    2012-12-01

    Monitoring and analysis of the chemical composition of air pollutants were conducted over a five-year period (2005-2009) in the sub-urban area of Chiang Mai, Thailand. This study aims to determine the seasonal variation of atmospheric ion species and gases, examine their correlations, identify possible sources and assess major air-flow patterns to the receptor. The dominant gas and particulate pollutants were NH3 (43-58%) and SO42- (39-48%), respectively. The annual mean concentrations of NH3 (μg m-3) in descending order were 4.08 (2009) > 3.32 (2007) > 2.68 (2008) > 2.47 (2006) and 1.87 (2005), while those of SO42- (μg m-3) were 2.60 (2007) > 2.20 (2006) > 1.95 (2009) > 1.75 (2008) and 1.26 (2005). Concentrations of particulate ions were analyzed by principle component analysis to find out the possible sources of air pollutants in this area. The first component of each year had a high loading of SO42- and NH4+, which probably came from fuel combustion and agricultural activity, respectively. K+, a tracer of biomass burning, also contributed to the first or the second components of each year. Concentrations of NH4+ and SO42- were well correlated (r > 0.777, p < 0.01), which lead to the conclusion that (NH4)2SO4 was a major compound present in this area. The 3-day backward trajectories of air mass arriving at Chiang Mai from 2005 to 2009 were analyzed using the hybrid single particle langrangian integrated trajectory (HYSPLIT) model and grouped by cluster analysis. The air mass data was analyzed for the dry season (n = 18; 100%). The trajectory of air mass in 2005 mainly originated locally (67%). In 2006, the recorded data showed that 56% of air mass was emitted from the western continental region of Thailand. In 2007, the percent ratios from the western and eastern continental areas were equal (39%). In 2008, 67% originated from the western continental area. In 2009, the recorded air mass mainly came from the western continental area (72%). In conclusion, the

  14. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general. Copyright 1999 John Wiley & Sons, Ltd.

  15. Identifying phase-space boundaries with Voronoi tessellations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Debnath, Dipsikha; Gainer, James S.; Kilic, Can

    Determining the masses of new physics particles appearing in decay chains is an important and longstanding problem in high energy phenomenology. Recently it has been shown that these mass measurements can be improved by utilizing the boundary of the allowed region in the fully differentiable phase space in its full dimensionality. Here in this paper we show that the practical challenge of identifying this boundary can be solved using techniques based on the geometric properties of the cells resulting from Voronoi tessellations of the relevant data. The robust detection of such phase-space boundaries in the data could also be usedmore » to corroborate a new physics discovery based on a cut-and-count analysis.« less

  16. Identifying phase-space boundaries with Voronoi tessellations

    DOE PAGES

    Debnath, Dipsikha; Gainer, James S.; Kilic, Can; ...

    2016-11-24

    Determining the masses of new physics particles appearing in decay chains is an important and longstanding problem in high energy phenomenology. Recently it has been shown that these mass measurements can be improved by utilizing the boundary of the allowed region in the fully differentiable phase space in its full dimensionality. Here in this paper we show that the practical challenge of identifying this boundary can be solved using techniques based on the geometric properties of the cells resulting from Voronoi tessellations of the relevant data. The robust detection of such phase-space boundaries in the data could also be usedmore » to corroborate a new physics discovery based on a cut-and-count analysis.« less

  17. Transitions of cloud-topped marine boundary layers characterized by AIRS, MODIS, and a large eddy simulation model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yue, Qing; Kahn, Brian; Xiao, Heng

    2013-08-16

    Cloud top entrainment instability (CTEI) is a hypothesized positive feedback between entrainment mixing and evaporative cooling near the cloud top. Previous theoretical and numerical modeling studies have shown that the persistence or breakup of marine boundary layer (MBL) clouds may be sensitive to the CTEI parameter. Collocated thermodynamic profile and cloud observations obtained from the Atmospheric Infrared Sounder (AIRS) and Moderate Resolution Imaging Spectroradiometer (MODIS) instruments are used to quantify the relationship between the CTEI parameter and the cloud-topped MBL transition from stratocumulus to trade cumulus in the northeastern Pacific Ocean. Results derived from AIRS and MODIS are compared withmore » numerical results from the UCLA large eddy simulation (LES) model for both well-mixed and decoupled MBLs. The satellite and model results both demonstrate a clear correlation between the CTEI parameter and MBL cloud fraction. Despite fundamental differences between LES steady state results and the instantaneous snapshot type of observations from satellites, significant correlations for both the instantaneous pixel-scale observations and the long-term averaged spatial patterns between the CTEI parameter and MBL cloud fraction are found from the satellite observations and are consistent with LES results. This suggests the potential of using AIRS and MODIS to quantify global and temporal characteristics of the cloud-topped MBL transition.« less

  18. A nonperturbing boundary-layer transition detector

    NASA Astrophysics Data System (ADS)

    Ohare, J. E.

    1985-11-01

    A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels. The boundary-layer transition detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Data which depict boundary-layer transition from laminar to turbulent flow are presented to provide comparisons of the BLTD with other measurement methods. Spectra from the BLTD reveals the presence of a high-frequency peak during transition which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

  19. An objective classification system of air mass types for Szeged, Hungary, with special attention to plant pollen levels.

    PubMed

    Makra, László; Juhász, Miklós; Mika, János; Bartzokas, Aristides; Béczi, Rita; Sümeghy, Zoltán

    2006-07-01

    This paper discusses the characteristic air mass types over the Carpathian Basin in relation to plant pollen levels over annual pollination periods. Based on the European Centre for Medium-Range Weather Forecasts dataset, daily sea-level pressure fields analysed at 00 UTC were prepared for each air mass type (cluster) in order to relate sea-level pressure patterns to pollen levels in Szeged, Hungary. The database comprises daily values of 12 meteorological parameters and daily pollen concentrations of 24 species for their pollination periods from 1997 to 2001. Characteristic air mass types were objectively defined via factor analysis and cluster analysis. According to the results, nine air mass types (clusters) were detected for pollination periods of the year corresponding to pollen levels that appear with higher concentration when irradiance is moderate while wind speed is moderate or high. This is the case when an anticyclone prevails in the region west of the Carpathian Basin and when Hungary is under the influence of zonal currents (wind speed is high). The sea level pressure systems associated with low pollen concentrations are mostly similar to those connected to higher pollen concentrations, and arise when wind speed is low or moderate. Low pollen levels occur when an anticyclone prevails in the region west of the Carpathian Basin, as well as when an anticyclone covers the region with Hungary at its centre. Hence, anticyclonic or anticyclonic ridge weather situations seem to be relevant in classifying pollen levels.

  20. Lidar observations of the planetary boundary layer during FASINEX

    NASA Technical Reports Server (NTRS)

    Melfi, S. H.; Boers, R.; Palm, S. P.

    1988-01-01

    Data are presented on the planetary boundary layer (PBL) over the ocean acquired with an airborne downward-looking lidar during the Frontal Air-Sea Interaction Experiment (FASINEX) with the purpose of studying the impact of an ocean front on air-sea interactions. No changes in the PBL structure were detected by lidar. Lidar data were then used along with other readily available remotely-sensed data and a one-dimensional boundary-layer-growth model to infer the mean PBL moisture and temperature structure and to estimate the surface fluxes of heat and moisture.

  1. Study of the effect of wind speed on evaporation from soil through integrated modeling of atmospheric boundary layer and shallow subsurface

    NASA Astrophysics Data System (ADS)

    Davarzani, Hossein; Smits, Kathleen; Tolene, Ryan; Illangasekare, Tissa

    2013-04-01

    The study of the interaction between the land and atmosphere is paramount to our understanding of many emerging problems to include climate change, the movement of green house gases such as possible leaking of sequestered CO2 and the accurate detection of buried objects such as landmines. Soil moisture distribution in the shallow subsurface becomes a critical factor in all these problems. The heat and mass flux in the form of soil evaporation across the land surface couples the atmospheric boundary layer to the shallow subsurface. The coupling between land and the atmosphere leads to highly dynamic interactions between the porous media properties, transport processes and boundary conditions, resulting in dynamic evaporative behavior. However, the coupling at the land-atmospheric interface is rarely considered in most current models and their validation for practical applications. This is due to the complexity of the problem in field scenarios and the scarcity of field or laboratory data capable of testing and refining coupled energy and mass transfer theories. In most efforts to compute evaporation from soil, only indirect coupling is provided to characterize the interaction between non-isothermal multiphase flows under realistic atmospheric conditions even though heat and mass flux are controlled by the coupled dynamics of the land and the atmospheric boundary layer. In earlier drying modeling concepts, imposing evaporation flux (kinetic of relative humidity) and temperature as surface boundary condition is often needed. With the goal of improving our understanding of the land/atmospheric coupling, we developed a model based on the coupling of Navier-Stokes free flow and Darcy flow in porous medium. The model consists of the coupled equations of mass conservation for the liquid phase (water) and gas phase (water vapor and air) in porous medium with gas phase (water vapor and air) in free flow domain under non-isothermal, non-equilibrium conditions. The boundary

  2. The stability of the boundary layer compressible gas with heat and mass transfer from the surface

    NASA Astrophysics Data System (ADS)

    Gaponov, S. A.; Terekhova, N. M.

    2016-10-01

    This work continues the research on modeling of the flow regime control in the compressible boundary layer. The effect of the distributed heat and mass transfer on the stability characteristics of the supersonic boundary layer at Mach number M = 5.35 is considered. The main attention is paid to modeling of acoustic disturbances both in conditions of a normal injection, when only the component of the average velocity V is nonzero, and the injection of other direction, including tangential one, when only the component U is nonzero at the wall. It is assumed that the effect of an injection of a homogeneous gas of the different temperature is similar to blowing of the gas of a different density, namely, blowing of the cold gas simulates blowing of the heavy gas and vice versa. Therefore in the present work this modeling is achieved by the change of a temperature factor (heating or cooling of the walls). There are the variant when the so-called locking regime when the velocity perturbations on the porous surface can be taken as zero.

  3. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  4. Tribal Boundaries, U.S., 2014, EPA/OAR/OAQPS/AQAD

    EPA Pesticide Factsheets

    This web service contains a layer depicting the union of TigerWEB AIANNHA map service layers 2 (Federal American Indian Reservations) and 3 (Off-Reservation Trust Lands) located at https://tigerweb.geo.census.gov/arcgis/rest/services/TIGERweb/AIANNHA/MapServerFederal (federal AIRs) are areas that have been set aside by the United States for the use of tribes, the exterior boundaries of which are more particularly defined in the final tribal treaties, agreements, executive orders, federal statutes, secretarial orders, or judicial determinations. The Bureau of Indian Affairs maintains a list of all federally recognized tribal governments and makes final determination of the inventory federal AIRs. The Census Bureau recognizes federal reservations (and associated off-reservation trust lands) as territory over which American Indian tribes have primary governmental authority. American Indian reservations can be legally described as colonies, communities, Indian colonies, Indian communities, Indian rancheria, Indian reservations, Indian villages, pueblos, rancherias, ranches, reservations, reserves, settlements, or villages. The Census Bureau contacts representatives of American Indian tribal governments to identify the boundaries for federal reservations through its annual Boundary and Annexation Survey. Federal reservations may cross state and all other area boundaries.State (state AIRs) are reservations established by some state governments for tribes recognized by

  5. A nonperturbing boundary-layer transition detection

    NASA Astrophysics Data System (ADS)

    Ohare, J. E.

    1985-01-01

    A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels in the von Karman Facility at Arnold Engineering Development Center (AEDC). The Boundary-Layer Transition Detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Model boundary-layer data are presented at Mach 8 and compared with data recorded using other methods during boundary-layer transition from laminar to turbulent flow. Spectra from the BLTD reveal the presence of a high-frequency peak during transition, which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

  6. A Nonperturbing Boundary-Layer Transition Detector

    NASA Astrophysics Data System (ADS)

    O'Hare, J. E.

    1986-01-01

    A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels in the von Kaman Facility at Arnold Engineering Development Center (AEDC). The Boundary-Layer Transition Detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Model boundary-layer data are presented at Mach 8 and compared with data recorded using other methods during boundary-layer transition from laminar to turbulent flow. Spectra from the BLTD reveal the presence of a high-frequency peak during transition, which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

  7. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J.; Healy, R.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; Ehn, M.; Mikkilä, J.; Kulmala, M.; O'Dowd, C. D.

    2010-09-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June, 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the N. E. Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water soluble organic carbon, which, in turn, was dominated by methanesulphonic acid (MSA). Sulphate concentrations were

  8. Decomposing the profile of PM in two low polluted German cities--mapping of air mass residence time, focusing on potential long range transport impacts.

    PubMed

    Dimitriou, Konstantinos; Kassomenos, Pavlos

    2014-07-01

    This paper aims to decompose the profile of particulates in Karlsruhe and Potsdam (Germany), focusing on the localization of PM potential transboundary sources. An air mass cluster analysis was implemented, followed by a study of air mass residence time on a grid of a 0.5° × 0.5° resolution. Particulate/gaseous daily air pollution and meteorological data were used to indicate PM local sources. Four Principal Component Analysis (PCA) components were produced: traffic, photochemical, industrial/domestic and particulate. PM2.5/PM10 ratio seasonal trends, indicated production of PMCOARSE (PM10-PM2.5) from secondary sources in Potsdam during warm period (WP). The residing areas of incoming slow moving air masses are potential transboundary PM sources. For Karlsruhe those areas were mainly around the city. An air mass residence time secondary peak was observed over Stuttgart. For Potsdam, areas with increased dwelling time of the arriving air parcels were detected particularly above E/SE Germany. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Liquid phase mass production of air-stable black phosphorus/phospholipids nanocomposite with ultralow tunneling barrier

    NASA Astrophysics Data System (ADS)

    Zhang, Qiankun; Liu, Yinan; Lai, Jiawei; Qi, Shaomian; An, Chunhua; Lu, Yao; Duan, Xuexin; Pang, Wei; Zhang, Daihua; Sun, Dong; Chen, Jian-Hao; Liu, Jing

    2018-04-01

    Few-layer black phosphorus (FLBP), a recently discovered two-dimensional semiconductor, has attracted substantial attention in the scientific and technical communities due to its great potential in electronic and optoelectronic applications. However, reactivity of FLBP flakes with ambient species limits its direct applications. Among various methods to passivate FLBP in ambient environment, nanocomposites mixing FLBP flakes with stable matrix may be one of the most promising approaches for industry applications. Here, we report a simple one-step procedure to mass produce air-stable FLBP/phospholipids nanocomposite in liquid phase. The resultant nanocomposite is found to have ultralow tunneling barrier for charge carriers which can be described by an Efros-Shklovskii variable range hopping mechanism. Devices made from such mass-produced FLBP/phospholipids nanocomposite show highly stable electrical conductivity and opto-electrical response in ambient conditions, indicating its promising applications in both electronic and optoelectronic applications. This method could also be generalized to the mass production of nanocomposites consisting of other air-sensitive 2D materials, such as FeSe, NbSe2, WTe2, etc.

  10. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J. C.; Sodeau, J. R.; Healy, R. M.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; O'Dowd, C. D.

    2009-12-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the NE Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Black carbon concentrations in polluted air were between 300-400 ng m-3, and in clean marine air were less than 50 ng m-3. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water

  11. Boundary lubrication of formulated C-ethers in air to 300 C. 2: Organic acid additives

    NASA Technical Reports Server (NTRS)

    Jones, W. R., Jr.

    1973-01-01

    Friction and wear measurements were made on CVM M-50 steel lubricated with three C-ether (modified polyphenyl ether) formulations in dry and moist air. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, a 17-meter/minute surface speed, and a 25 to 300 C (77 to 572 F) disk temperature range. The three C-ether formulations yielded better boundary lubricating characteristics than the Type 2 ester under most test conditions. All C-ether formulations exhibited higher friction coefficients than the ester from 150 to 300 C (302 to 572 F) and similar or lower values from 25 to 150 C (77 to 302 F).

  12. Formulation and Implementation of Inflow/Outflow Boundary Conditions to Simulate Propulsive Effects

    NASA Technical Reports Server (NTRS)

    Rodriguez, David L.; Aftosmis, Michael J.; Nemec, Marian

    2018-01-01

    Boundary conditions appropriate for simulating flow entering or exiting the computational domain to mimic propulsion effects have been implemented in an adaptive Cartesian simulation package. A robust iterative algorithm to control mass flow rate through an outflow boundary surface is presented, along with a formulation to explicitly specify mass flow rate through an inflow boundary surface. The boundary conditions have been applied within a mesh adaptation framework based on the method of adjoint-weighted residuals. This allows for proper adaptive mesh refinement when modeling propulsion systems. The new boundary conditions are demonstrated on several notional propulsion systems operating in flow regimes ranging from low subsonic to hypersonic. The examples show that the prescribed boundary state is more properly imposed as the mesh is refined. The mass-flowrate steering algorithm is shown to be an efficient approach in each example. To demonstrate the boundary conditions on a realistic complex aircraft geometry, two of the new boundary conditions are also applied to a modern low-boom supersonic demonstrator design with multiple flow inlets and outlets.

  13. Observations and Modeling of Turbulent Air-Sea Coupling in Coastal and Strongly Forced Condition

    NASA Astrophysics Data System (ADS)

    Ortiz-Suslow, David G.

    The turbulent fluxes of momentum, mass, and energy across the ocean-atmosphere boundary are fundamental to our understanding of a myriad of geophysical processes, such as wind-wave generation, oceanic circulation, and air-sea gas transfer. In order to better understand these fluxes, empirical relationships were developed to quantify the interfacial exchange rates in terms of easily observed parameters (e.g., wind speed). However, mounting evidence suggests that these empirical formulae are only valid over the relatively narrow parametric space, i.e. open ocean conditions in light to moderate winds. Several near-surface processes have been observed to cause significant variance in the air-sea fluxes not predicted by the conventional functions, such as a heterogeneous surfaces, swell waves, and wave breaking. Further study is needed to fully characterize how these types of processes can modulate the interfacial exchange; in order to achieve this, a broad investigation into air-sea coupling was undertaken. The primary focus of this work was to use a combination of field and laboratory observations and numerical modeling, in regimes where conventional theories would be expected to breakdown, namely: the nearshore and in very high winds. These seemingly disparate environments represent the marine atmospheric boundary layer at its physical limit. In the nearshore, the convergence of land, air, and sea in a depth-limited domain marks the transition from a marine to a terrestrial boundary layer. Under extreme winds, the physical nature of the boundary layer remains unknown as an intermediate substrate layer, sea spray, develops between the atmosphere and ocean surface. At these ends of the MABL physical spectrum, direct measurements of the near-surface processes were made and directly related to local sources of variance. Our results suggest that the conventional treatment of air-sea fluxes in terms of empirical relationships developed from a relatively narrow set of

  14. Influence of power ultrasound application on mass transport and microstructure of orange peel during hot air drying

    NASA Astrophysics Data System (ADS)

    Ortuño, Carmen; Pérez-Munuera, Isabel; Puig, Ana; Riera, Enrique; Garcia-Perez, J. V.

    2010-01-01

    Power ultrasound application on convective drying of foodstuffs may be considered an emergent technology. This work deals with the influence of power ultrasound on drying of natural materials addressing the kinetic as well as the product's microstructure. Convective drying kinetics of orange peel slabs (thickness 5.95±0.41 mm) were carried out at 40 ∘C and 1 m/s with (US) and without (AIR) power ultrasound application. A diffusion model considering external resistance to mass transfer was considered to describe drying kinetics. Fresh, US and AIR dried samples were analyzed using Cryo-SEM. Results showed that drying kinetics of orange peel were significantly improved by the application of power ultrasound. From modeling, it was observed a significant (p¡0.05) increase in both mass transfer coefficient and effective moisture diffusivity. The effects on mass transfer properties were confirmed from microestructural observations. In the cuticle surface, the pores were obstructed by wax components scattering, which evidence the ultrasonic effects on the interfaces. The cells of the flavedo were compressed and large intercellular air spaces were generated in the albedo facilitating water transfer through it.

  15. Characterization of key aerosol, trace gas and meteorological properties and particle formation and growth processes dependent on air mass origins in coastal Southern Spain

    NASA Astrophysics Data System (ADS)

    Diesch, J.; Drewnick, F.; Sinha, V.; Williams, J.; Borrmann, S.

    2011-12-01

    The chemical composition and concentration of aerosols at a certain site can vary depending on season, the air mass source region and distance from sources. Regardless of the environment, new particle formation (NPF) events are one of the major sources for ultrafine particles which are potentially hazardous to human health. Grown particles are optically active and efficient CCN resulting in important implications for visibility and climate (Zhang et al., 2004). The study presented here is intended to provide information about various aspects of continental, urban and marine air masses reflected by wind patterns of the air arriving at the measurement site. Additionally we will be focusing on NPF events associated with different types of air masses affecting their emergence and temporal evolution. Measurements of the ambient aerosol, various trace gases and meteorological parameters were performed within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from mid-November to mid-December 2008 at the atmospheric research station "El Arenosillo" located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean. Number and mass as well as PAH and black carbon concentrations were measured in PM1 and size distribution instruments covered the size range 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (AMS). In order to evaluate the characteristics of different air masses linking local and regional sources as well as NPF processes, characteristic air mass types were classified dependent on backwards trajectory pathways and local meteorology. Large nuclei mode concentrations in the number size distribution were found within continental and urban influenced air mass types due to frequently occurring NPF events. Exploring individual production and sink variables, sulfuric

  16. Energy- and wave-based beam-tracing prediction of room-acoustical parameters using different boundary conditions.

    PubMed

    Yousefzadeh, Behrooz; Hodgson, Murray

    2012-09-01

    A beam-tracing model was used to study the acoustical responses of three empty, rectangular rooms with different boundary conditions. The model is wave-based (accounting for sound phase) and can be applied to rooms with extended-reaction surfaces that are made of multiple layers of solid, fluid, or poroelastic materials-the acoustical properties of these surfaces are calculated using Biot theory. Three room-acoustical parameters were studied in various room configurations: sound strength, reverberation time, and RApid Speech Transmission Index. The main objective was to investigate the effects of modeling surfaces as either local or extended reaction on predicted values of these three parameters. Moreover, the significance of modeling interference effects was investigated, including the study of sound phase-change on surface reflection. Modeling surfaces as of local or extended reaction was found to be significant for surfaces consisting of multiple layers, specifically when one of the layers is air. For multilayers of solid materials with an air-cavity, this was most significant around their mass-air-mass resonance frequencies. Accounting for interference effects made significant changes in the predicted values of all parameters. Modeling phase change on reflection, on the other hand, was found to be relatively much less significant.

  17. Air permeability and trapped-air content in two soils

    USGS Publications Warehouse

    Stonestrom, David A.; Rubin, Jacob

    1989-01-01

    To improve understanding of hysteretic air permeability relations, a need exists for data on the water content dependence of air permeability, matric pressure, and air trapping (especially for wetting-drying cycles). To obtain these data, a special instrument was designed. The instrument is a combination of a gas permeameter (for air permeability determination), a suction plate apparatus (for retentivity curve determination), and an air pycnometer (for trapped-air-volume determination). This design allowed values of air permeability, matric pressure, and air trapping to be codetermined, i.e., determined at the same values of water content using the same sample and the same inflow-outflow boundaries. Such data were obtained for two nonswelling soils. The validity of the air permeability determinations was repeatedly confirmed by rigorous tests of Darcy's law. During initial drying from complete water saturation, supplementary measurements were made to assess the magnitude of gas slip. The extended Darcy equation accurately described the measured flux gradient relations for each condition of absolute gas pressure tested. Air permeability functions exhibited zero-permeability regions at high water contents as well as an abruptly appearing hysteresis at low water contents. Measurements in the zero-permeability regions revealed that the total amount of air in general exceeded the amount of trapped air. This indicates that the medium' s air space is partitioned into three measurable domains: through-flowing air, locally accessible air (i.e., air accessible from only one flow boundary), and trapped air. During repeated wetting and drying, the disappearance and reappearance of air permeability coincided closely with the reappearance and disappearance, respectively, of trapped air. The observed relation between critical features of the air permeability functions and those of the air-trapping functions suggest that water-based blockages play a significant role in the

  18. Characteristics of nocturnal coastal boundary layer in Ahtopol based on averaged SODAR profiles

    NASA Astrophysics Data System (ADS)

    Barantiev, Damyan; Batchvarova, Ekaterina; Novitzky, Mikhail

    2014-05-01

    The ground-based remote sensing instruments allow studying the wind regime and the turbulent characteristics of the atmosphere with height, achieving new knowledge and solving practical problems, such as air quality assessments, mesoscale models evaluation with high resolution data, characterization of the exchange processes between the surface and the atmosphere, the climate comfort conditions and the risk for extreme events, etc. Very important parameter in such studies is the height of the atmospheric boundary layer. Acoustic remote sensing data of the coastal atmospheric boundary layer were explored based on over 4-years continuous measurements at the meteorological observatory of Ahtopol (Bulgarian Southern Black Sea Coast) under Bulgarian - Russian scientific agreement. Profiles of 12 parameters from a mid-range acoustic sounding instrument type SCINTEC MFAS are derived and averaged up to about 600 m according filtering based on wind direction (land or sea type of night fowls). From the whole investigated period of 1454 days with 10-minute resolution SODAR data 2296 profiles represented night marine air masses and 1975 profiles represented the night flow from land during the months May to September. Graphics of averaged profiles of 12 SODAR output parameters with different availability of data in height are analyzed for both cases. A marine boundary-layer height of about 300 m is identified in the profiles of standard deviation of vertical wind speed (σw), Turbulent Kinetic Energy (TKE) and eddy dissipation rate (EDR). A nocturnal boundary-layer height of about 420 m was identified from the profiles of the same parameters under flows from land condition. In addition, the Buoyancy Production (BP= σw3/z) profiles were calculated from the standard deviation of the vertical wind speed and the height z above ground.

  19. The effect of long-range air mass transport pathways on PM10 and NO2 concentrations at urban and rural background sites in Ireland: Quantification using clustering techniques.

    PubMed

    Donnelly, Aoife A; Broderick, Brian M; Misstear, Bruce D

    2015-01-01

    The specific aims of this paper are to: (i) quantify the effects of various long range transport pathways nitrogen dioxide (NO2) and particulate matter with diameter less than 10μm (PM10) concentrations in Ireland and identify air mass movement corridors which may lead to incidences poor air quality for application in forecasting; (ii) compare the effects of such pathways at various sites; (iii) assess pathways associated with a period of decreased air quality in Ireland. The origin of and the regions traversed by an air mass 96h prior to reaching a receptor is modelled and k-means clustering is applied to create air-mass groups. Significant differences in air pollution levels were found between air mass cluster types at urban and rural sites. It was found that easterly or recirculated air masses lead to higher NO2 and PM10 levels with average NO2 levels varying between 124% and 239% of the seasonal mean and average PM10 levels varying between 103% and 199% of the seasonal mean at urban and rural sites. Easterly air masses are more frequent during winter months leading to higher overall concentrations. The span in relative concentrations between air mass clusters is highest at the rural site indicating that regional factors are controlling concentration levels. The methods used in this paper could be applied to assist in modelling and forecasting air quality based on long range transport pathways and forecast meteorology without the requirement for detailed emissions data over a large regional domain or the use of computationally demanding modelling techniques.

  20. Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.

    PubMed

    Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L

    2015-09-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. A theoretical study of mixing downstream of transverse injection into a supersonic boundary layer

    NASA Technical Reports Server (NTRS)

    Baker, A. J.; Zelazny, S. W.

    1972-01-01

    A theoretical and analytical study was made of mixing downstream of transverse hydrogen injection, from single and multiple orifices, into a Mach 4 air boundary layer over a flat plate. Numerical solutions to the governing three-dimensional, elliptic boundary layer equations were obtained using a general purpose computer program. Founded upon a finite element solution algorithm. A prototype three-dimensional turbulent transport model was developed using mixing length theory in the wall region and the mass defect concept in the outer region. Excellent agreement between the computed flow field and experimental data for a jet/freestream dynamic pressure ratio of unity was obtained in the centerplane region of the single-jet configuration. Poorer agreement off centerplane suggests an inadequacy of the extrapolated two-dimensional turbulence model. Considerable improvement in off-centerplane computational agreement occured for a multi-jet configuration, using the same turbulent transport model.

  2. Unexpected high 35S concentration revealing strong downward transport of stratospheric air during the monsoon transitional period in East Asia

    NASA Astrophysics Data System (ADS)

    Lin, Mang; Zhang, Zhisheng; Su, Lin; Su, Binbin; Liu, Lanzhong; Tao, Jun; Fung, Jimmy C. H.; Thiemens, Mark H.

    2016-03-01

    October is the monsoon transitional period in East Asia (EA) involving a series of synoptic activities that may enhance the downward transport of stratospheric air to the planetary boundary layer (PBL). Here we use cosmogenic 35S in sulfate aerosols (35SO42-) as a tracer for air masses originating from the stratosphere and transported downward to quantify these mixing processes. From 1 year 35SO42- measurements (March 2014 to February 2015) at a background station in EA we find remarkably enhanced 35SO42- concentration (3150 atoms m-3) in October, the highest value ever reported for natural sulfate aerosols. A four-box 1-D model and meteorological analysis reveal that strong downward transport from the free troposphere is a vital process entraining aged stratospheric air masses to the PBL. The aged stratospheric masses are accumulated in the PBL, accelerating the SO2 transformation to SO42-. Implications for the tropospheric O3 budget and the CO2 biogeochemical cycle are discussed.

  3. SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses.

    PubMed

    Kahn, Ralph A; Berkoff, Tim A; Brock, Charles; Chen, Gao; Ferrare, Richard A; Ghan, Steven; Hansico, Thomas F; Hegg, Dean A; Martins, J Vanderlei; McNaughton, Cameron S; Murphy, Daniel M; Ogren, John A; Penner, Joyce E; Pilewskie, Peter; Seinfeld, John H; Worsnop, Douglas R

    2017-10-01

    A modest operational program of systematic aircraft measurements can resolve key satellite-aerosol-data-record limitations. Satellite observations provide frequent, global aerosol-amount maps, but offer only loose aerosol property constraints needed for climate and air quality applications. We define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ . The flight program could characterize major aerosol air-mass types statistically, at a level-of-detail unobtainable from space. It would: (1) enhance satellite aerosol retrieval products with better climatology assumptions, and (2) improve translation between satellite-retrieved optical properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space, improve aerosol constraints on climate modeling , help interrelate remote-sensing, in situ, and modeling aerosol-type definitions , and contribute to future satellite aerosol missions. Fifteen Required Variables are identified, and four Payload Options of increasing ambition are defined, to constrain these quantities. "Option C" could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration, and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable , even if aerosol loading varies.

  4. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    NASA Technical Reports Server (NTRS)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  5. Transport Regimes of Air Masses Affecting the Tropospheric Composition of the Canadian and European Arctic During RACEPAC 2014 and NETCARE 2014/2015

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Hoor, P. M.; Koellner, F.; Kunkel, D.; Schneider, J.; Schulz, C.; Herber, A. B.; Borrmann, S.; Wendisch, M.; Ehrlich, A.; Leaitch, W. R.; Willis, M. D.; Burkart, J.; Thomas, J. L.; Abbatt, J.

    2015-12-01

    The Arctic is warming much faster than any other place in the world and undergoes a rapid change dominated by a changing climate in this region. The impact of polluted air masses traveling to the Arctic from various remote sources significantly contributes to the observed climate change, in contrast there are additional local emission sources contributing to the level of pollutants (trace gases and aerosol). Processes affecting the emission and transport of these pollutants are not well understood and need to be further investigated. We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories we analyze the transport regimes prevalent during spring (RACEPAC 2014 and NETCARE 2015) and summer (NETCARE 2014) in the observed region. Whereas the eastern part of the Canadian Arctic is affected by air masses with their origin in Asia, in the central and western parts of the Canadian and European Arctic air masses from North America are predominant at the time of the measurement. In general the more northern parts of the Arctic were relatively unaffected by pollution from mid-latitudes since air masses mostly travel within the polar dome, being quite isolated. Associated mixing ratios of CO and CO2 fit into the seasonal cycle observed at NOAA ground stations throughout the Arctic, but show a more mid-latitudinal characteristic at higher altitudes. The transition is remarkably sharp and allows for a chemical definition of the polar dome. At low altitudes, synoptic disturbances transport polluted air masses from mid-latitudes into regions of the polar dome. These air masses contribute to the Arctic pollution background, but also

  6. Comparisons of rational engineering correlations of thermophoretically-augmented particle mass transfer with STAN5-predictions for developing boundary layers

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Rosner, D. E.

    1984-01-01

    Modification of the code STAN5 to properly include thermophoretic mass transport, and examination of selected test cases developing boundary layers which include variable properties, viscous dissipation, transition to turbulence and transpiration cooling. Under conditions representative of current and projected GT operation, local application of St(M)/St(M),o correlations evidently provides accurate and economical engineering design predictions, especially for suspended particles characterized by Schmidt numbers outside of the heavy vapor range.

  7. Turbulence in a convective marine atmospheric boundary layer

    NASA Technical Reports Server (NTRS)

    Chou, S.-H.; Atlas, D.; Yeh, E.-N.

    1986-01-01

    The structure and kinetic energy budget of turbulence in the convective marine atmospheric boundary layer as observed by aircraft during a cold air outbreak have been studied using mixed layer scaling. The results are significantly different from those of previous studies under conditions closer to free convection. The normalized turbulent kinetic energy and turbulent transport are about twice those found during the Air Mass Transformation Experiment (AMTEX). This implies that for a given surface heating the present case is dynamically more active. The difference is mainly due to the greater importance of wind shear in the present case. This case is closer to the roll vortex regime, whereas AMTEX observed mesoscale cellular convection which is closer to free convection. Shear generation is found to provide a significant energy source, in addition to buoyancy production, to maintain a larger normalized turbulent kinetic energy and to balance a larger normalized dissipation. The interaction between turbulent pressure and divergence (i.e., pressure scrambling) is also found to transfer energy from the vertical to the horizontal components, and is expected to be stronger in roll vortices than in m esoscale cells. The sensible heat flux is found to fit well with a linear vertical profile in a clear or subcloud planetary boundary layer (PBL), in good agreement with the results of Lenschow et al., (1980). The heat flux ratio between the PBL top and the surface, derived from the linear fitted curve, is approximately -0.14, in good agreement with that derived from the lidar data for the same case. Near the PBL top, the heat flux profiles are consistent with those of Deardoff (1979) and Deardorff et al. (1980).

  8. Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

    PubMed

    Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

    2007-10-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented.

  9. The analysis of a nonsimilar laminar boundary layer

    NASA Technical Reports Server (NTRS)

    Stalmach, D. D.; Bertin, J. J.

    1978-01-01

    A computer code is described which yields accurate solutions for a broad range of laminar, nonsimilar boundary layers, providing the inviscid flow field is known. The boundary layer may be subject to mass injection for perfect-gas, nonreacting flows. If no mass injection is present, the code can be used with either perfect-gas or real-gas thermodynamic models. Solutions, ranging from two-dimensional similarity solutions to solutions for the boundary layer on the Space Shuttle Orbiter during reentry conditions, have been obtained with the code. Comparisons of these solutions, and others, with solutions presented in the literature; and with solutions obtained from other codes, demonstrate the accuracy of the present code.

  10. Observations and modelling of the boundary layer using remotely piloted aircraft

    NASA Astrophysics Data System (ADS)

    Cayez, Gregoire; Dralet, Jean-Philippe; Seity, Yann; Momboisse, Geraud; Hattenberger, Gautier; Bronz, Murat; Roberts, Greg

    2014-05-01

    Over the past decade, the scientific community considers the RPAS (remotely piloted aircraft system) as a tool which can help to improve their knowledge of climate and atmospheric phenomena. RPAS equipped with instruments can now conduct measurements in areas that are too hazardous or remote for a manned plane. RPAS are especially adapted system for observing the atmospheric boundary layer processes at high vertical and temporal resolution. The main objectives of VOLTIGE (Vecteur d'Observation de La Troposphère pour l'Investigation et la Gestion de l'Environnement) are to study the life cycle of fog with micro-RPAS, encourage direct participation of the students on the advancement and development of novel observing systems, and assess the feasibility of deploying RPAS in Météo-France's operational network. The instrumented RPAS flights successfully observed the evolution of small-scale meteorological events. Before the arrival of the warm pseudo-front, profiles show a temperature inversion of a hundred meters, which overlaps a cold and wet atmospheric layer. Subsequent profiles show the combination of the arrival of a marine air mass as well as the arrival of a higher level warm pseudo-front. A third case study characterizes the warm sector of the disturbance. Two distinct air masses are visible on the vertical profiles, and show a dry air above an air almost saturated and slightly colder. The temperature and the relative humidity profiles show < 1 meter vertical resolution with a difference between ascent and descent profiles within ± 0.5°C and ± 6 % RH. These results comply with the Météo-France standard limits of quality control. The RPAS profiles were compared with those of the Arome forecast model (an operational model at Météo France). The temperature and wind in the Arome model profiles generally agree with those of the RPAS (less for relative humidity profiles). The Arome model also suggests transitions between air masses occurred at a higher

  11. Boundary-Layer-Ingesting Inlet Flow Control

    NASA Technical Reports Server (NTRS)

    Owens, Lewis R.; Allan, Brian G.; Gorton, Susan A.

    2006-01-01

    This paper gives an overview of a research study conducted in support of the small-scale demonstration of an active flow control system for a boundary-layer-ingesting (BLI) inlet. The effectiveness of active flow control in reducing engine inlet circumferential distortion was assessed using a 2.5% scale model of a 35% boundary-layer-ingesting flush-mounted, offset, diffusing inlet. This experiment was conducted in the NASA Langley 0.3-meter Transonic Cryogenic Tunnel at flight Mach numbers with a model inlet specifically designed for this type of testing. High mass flow actuators controlled the flow through distributed control jets providing the active flow control. A vortex generator point design configuration was also tested for comparison purposes and to provide a means to examine a hybrid vortex generator and control jets configuration. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow through the duct and the actuators. The distortion and pressure recovery were determined by 40 total pressure measurements on 8 rake arms each separated by 45 degrees and were located at the aerodynamic interface plane. The test matrix was limited to a maximum free-stream Mach number of 0.85 with scaled mass flows through the inlet for that condition. The data show that the flow control jets alone can reduce circumferential distortion (DPCP(sub avg)) from 0.055 to about 0.015 using about 2.5% of inlet mass flow. The vortex generators also reduced the circumferential distortion from 0.055 to 0.010 near the inlet mass flow design point. Lower inlet mass flow settings with the vortex generator configuration produced higher distortion levels that were reduced to acceptable levels using a hybrid vortex generator/control jets configuration that required less than 1% of the inlet mass flow.

  12. Boundary-Layer-Ingesting Inlet Flow Control

    NASA Technical Reports Server (NTRS)

    Owens, Lewis R.; Allan, Brian G.; Gorton, Susan A.

    2006-01-01

    This paper gives an overview of a research study conducted in support of the small-scale demonstration of an active flow control system for a boundary-layer-ingesting (BLI) inlet. The effectiveness of active flow control in reducing engine inlet circumferential distortion was assessed using a 2.5% scale model of a 35% boundary-layer-ingesting flush-mounted, offset, diffusing inlet. This experiment was conducted in the NASA Langley 0.3-meter Transonic Cryogenic Tunnel at flight Mach numbers with a model inlet specifically designed for this type of testing. High mass flow actuators controlled the flow through distributed control jets providing the active flow control. A vortex generator point design configuration was also tested for comparison purposes and to provide a means to examine a hybrid vortex generator and control jets configuration. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow through the duct and the actuators. The distortion and pressure recovery were determined by 40 total pressure measurements on 8 rake arms each separated by 45 degrees and were located at the aerodynamic interface plane. The test matrix was limited to a maximum free-stream Mach number of 0.85 with scaled mass flows through the inlet for that condition. The data show that the flow control jets alone can reduce circumferential distortion (DPCPavg) from 0.055 to about 0.015 using about 2.5% of inlet mass flow. The vortex generators also reduced the circumferential distortion from 0.055 to 0.010 near the inlet mass flow design point. Lower inlet mass flow settings with the vortex generator configuration produced higher distortion levels that were reduced to acceptable levels using a hybrid vortex generator/control jets configuration that required less than 1% of the inlet mass flow.

  13. Boundary-Layer & health

    NASA Astrophysics Data System (ADS)

    Costigliola, V.

    2010-09-01

    It has long been known that specific atmospheric processes, such as weather and longer-term climatic fluctuations, affect human health. The biometeorological literature refers to this relationship as meteorotropism, defined as a change in an organism that is correlated with a change in atmospheric conditions. Plenty of (patho)physiological functions are affected by those conditions - like the respiratory diseases - and currently it is difficult to put any limits for pathologies developed in reply. Nowadays the importance of atmospheric boundary layer and health is increasingly recognised. A number of epidemiologic studies have reported associations between ambient concentrations of air pollution, specifically particulate pollution, and adverse health effects, even at the relatively low concentrations of pollution found. Since 1995 there have been over twenty-one studies from four continents that have explicitly examined the association between ambient air pollutant mixes and daily mortality. Statistically significant and positive associations have been reported in data from various locations around the world, all with varying air pollutant concentrations, weather conditions, population characteristics and public health policies. Particular role has been given to atmospheric boundary layer processes, the impact of which for specific patient-cohort is, however, not well understood till now. Assessing and monitoring air quality are thus fundamental to improve Europe's welfare. One of current projects run by the "European Medical Association" - PASODOBLE will develop and demonstrate user-driven downstream information services for the regional and local air quality sectors by combining space-based and in-situ data with models in 4 thematic service lines: - Health community support for hospitals, pharmacies, doctors and people at risk - Public information for regions, cities, tourist industry and sporting event organizers - Compliance monitoring support on particulate

  14. Possibilities for drag reduction by boundary layer control

    NASA Technical Reports Server (NTRS)

    Naiman, I.

    1946-01-01

    The mechanics of laminar boundary layer transition are reviewed. Drag possibilities for boundary layer control are analyzed using assumed conditions of transition Reynolds number, inlet loss, number of slots, blower efficiency, and duct losses. Although the results of such analysis are highly favorable, those obtained by experimental investigations yield conflicting results, showing only small gains, and sometimes losses. Reduction of this data indicates that there is a lower limit to the quantity of air which must be removed at the slot in order to stabilize the laminar flow. The removal of insufficient air permits transition to occur while the removal of excessive amounts of air results in high power costs, with a net drag increases. With the estimated value of flow coefficient and duct losses equal to half the dynamic pressure, drag reductions of 50% may be obtained; with twice this flow coefficient, the drag saving is reduced to 25%.

  15. Angularly symmetric splitting of a light beam upon reflection and refraction at an air-dielectric plane boundary.

    PubMed

    Azzam, R M A

    2015-12-01

    Conditions for achieving equal and opposite angular deflections of a light beam by reflection and refraction at an air-dielectric boundary are determined. Such angularly symmetric beam splitting (ASBS) is possible only if the angle of incidence is >60° by exactly one third of the angle of refraction. This simple law, plus Snell's law, leads to several analytical results that clarify all aspects of this phenomenon. In particular, it is shown that the intensities of the two symmetrically deflected beams can be equalized by proper choice of the prism refractive index and the azimuth of incident linearly polarized light. ASBS enables a geometrically attractive layout of optical systems that employ multiple prism beam splitters.

  16. A Study Of The Atmospheric Boundary Layer Using Radon And Air Pollutants As Tracers

    NASA Astrophysics Data System (ADS)

    Kataoka, Toshio; Yunoki, Eiji; Shimizu, Mitsuo; Mori, Tadashige; Tsukamoto, Osamu; Ohashi, Yukitaka, Sahashi, Ken; Maitani, Toshihiko; Miyashita, Koh'ichi; Iwata, Toru; Fujikawa, Yoko; Kudo, Akira; Shaw, Roger H.

    Concentrations of radon 222Rn andair pollutants, meteorological parametersnear the surface and vertical profiles of meteorological elements were measured atUchio (Okayama City, Okayama Prefecture, Japan) 12 km north from the coast ofthe Inland Sea of Japan. In the nighttime, the 222Rn concentration increased in the case of weak winds, but did not increase as much in the case of moderate or strong winds, as had been expected. In the daytime, the 222Rn concentrationheld at a slightly higher than average level for the period from sunrise to about 1100 JST. It is considered that this phenomenon is due to a period of morning calm, that is, a transition period from land breeze to sea breeze.NO, which is sensitive to traffic volume,brought information concerning advection.Oxidant concentrations,which reflect the availability of sunlight,acted in the reverse manner to 222Rnconcentrations. Thus, a set of 222Rn and air pollutants could provide useful information regarding the local conditions of the atmospheric boundary layer.

  17. Involution Requirement on a Boundary Makes Massless Fermions Compactified on a Finite Flat Disk Mass Protected

    NASA Astrophysics Data System (ADS)

    Mankoč Borštnik, N. S.; Nielsen, H. B.

    2006-12-01

    The genuine Kaluza-Klein-like theories--with no fields in addition to gravity--have difficulties with the existence of massless spinors after the compactification of some space dimensions \\cite{witten}. We proposed (Phys. Lett. B 633 (2006)771) such a boundary condition for spinors in 1+5 compactified on a flat disk that ensures masslessness of spinors in d=1+3 as well as their chiral coupling to the corresponding background gauge field (which solves equations of motion for a free field linear in the Riemann curvature). In this paper we study the same toy model: M^{(1+3)} x M^{(2)}, looking this time for an involution which transforms a space of solutions of Weyl equations in d=1+5 from the outside of the flat disk in x^5 and x^6 into its inside, allowing massless spinor of only one handedness--and accordingly assures mass protection--and of one charge--1/2--and infinitely many massive spinors of the same charge, chirally coupled to the corresponding background gauge field. We reformulate the operator of momentum so that it is Hermitean on the vector space of spinor states obeying the involution boundary condition.

  18. Exploring the Effects of Atmospheric Forcings on Evaporation: Experimental Integration of the Atmospheric Boundary Layer and Shallow Subsurface

    PubMed Central

    Smits, Kathleen; Eagen, Victoria; Trautz, Andrew

    2015-01-01

    Evaporation is directly influenced by the interactions between the atmosphere, land surface and soil subsurface. This work aims to experimentally study evaporation under various surface boundary conditions to improve our current understanding and characterization of this multiphase phenomenon as well as to validate numerical heat and mass transfer theories that couple Navier-Stokes flow in the atmosphere and Darcian flow in the porous media. Experimental data were collected using a unique soil tank apparatus interfaced with a small climate controlled wind tunnel. The experimental apparatus was instrumented with a suite of state of the art sensor technologies for the continuous and autonomous collection of soil moisture, soil thermal properties, soil and air temperature, relative humidity, and wind speed. This experimental apparatus can be used to generate data under well controlled boundary conditions, allowing for better control and gathering of accurate data at scales of interest not feasible in the field. Induced airflow at several distinct wind speeds over the soil surface resulted in unique behavior of heat and mass transfer during the different evaporative stages. PMID:26131928

  19. Influence of air mass origin on aerosol properties at a remote Michigan forest site

    NASA Astrophysics Data System (ADS)

    VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; Pressley, S. N.; Erickson, M. H.; Jobson, B. T.; Lamb, B. K.

    2015-04-01

    The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere-Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ∼60% of the study period, air was transported from sparsely populated regions to the northwest. During these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm-3 and 1.91 μm3 cm-3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (∼29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean к = 0.24 at s = 0.3%). These trends are have the potential to influence forest-atmosphere interactions and should be targeted for future study.

  20. Influence of air mass origin on aerosol properties at a remote Michigan forest site

    DOE PAGES

    VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; ...

    2015-02-10

    The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere–Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ~60% of the study period, air was transported from sparsely populated regions to the northwest. Duringmore » these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm -3 and 1.91 μm 3 cm -3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (~29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean к = 0.24 at s = 0.3%). Furthermore, these trends are have the potential to influence forest–atmosphere interactions and should be targeted for future study.« less

  1. Condensation of atmospheric moisture from tropical maritime air masses as a freshwater resource.

    PubMed

    Gerard, R D; Worzel, J L

    1967-09-15

    A method is proposed whereby potable water may be obtained by condensing moisture from the atmosphere in suitable seashore or island areas. Deep, cold, offshore seawater is used as a source of cold and is pumped to condensers set up on shore to intercept the flow of highly humid, tropical, maritime air masses. This air, when cooled, condenses moisture, which is conducted away and stored for use as a water supply. Windmill-driven generators would supply low-cost power for the operation. Side benefits are derived by using the nutritious deep water to support aquiculture in nearby lagoons or to enhance the productivity of the outfall area. Additional benefits are derived from the condenser as an air-conditioning device for nearby residents. The islands of the Caribbean are used as an example of a location in the trade-winds belt where nearly optimum conditions for the operation of this system can be found.

  2. Remote Mass Spectrometric Sampling of Electrospray- and Desorption Electrospray-Generated Ions Using an Air Ejector

    PubMed Central

    Dixon, R. Brent; Bereman, Michael S.; Muddiman, David C.; Hawkridge, Adam M.

    2007-01-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data is presented. PMID:17716909

  3. Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Shirley, John A.; Winter, Michael

    1993-01-01

    An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

  4. Process analysis of characteristics of the boundary layer during a heavy haze pollution episode in an inland megacity, China.

    PubMed

    Wang, Shan; Liao, Tingting; Wang, Lili; Sun, Yang

    2016-02-01

    Ground observation data from 8 meteorological stations in Xi'an, air mass concentration data from 13 environmental quality monitoring sites in Xi'an, as well as radiosonde observation and wind profile radar data, were used in this study. Thereby, the process, causes and boundary layer meteorological characteristics of a heavy haze episode occurring from 16 to 25 December 2013 in Xi'an were analyzed. Principal component analysis showed that this haze pollution was mainly caused by the high-intensity emission and formation of gaseous pollutants (NO2, CO and SO2) and atmospheric particles (PM2.5 (fine particles) and PM10 (respirable suspended particle). The second cause was the relative humidity and continuous low temperature. The third cause was the allocation of the surface pressure field. The presence of a near-surface temperature inversion at the boundary layer formed favorable stratification conditions for the formation and maintenance of heavy haze pollution. The persistent thick haze layer weakened the solar radiation. Meanwhile, a warming effect in the urban canopy layer and in the transition zone from the urban friction sublayer to the urban canopy was indicated. All these conditions facilitated the maintenance and reinforcement of temperature inversion. The stable atmospheric stratification finally acted on the wind field in the boundary layer, and further weakened the exchange capacity of vertical turbulence. The superposition of a wind field with the horizontal gentle wind induced the typical air stagnation and finally caused the deterioration of air quality during this haze event. Copyright © 2015. Published by Elsevier B.V.

  5. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  6. Influence of Dynamics and Chemistry on the Diurnal Variation of VOCs in the Planetary Boundary Layer above a Mixed Forest Canopy in the Southeastern United States

    NASA Astrophysics Data System (ADS)

    Guenther, A. B.; Su, L.; Patton, E. G.; Vila-Guerau Arellano, J.; Mak, J. E.

    2014-12-01

    The planetary boundary layer (PBL) is a region of inherent interest because reactive VOCs emitted from the forest canopy are mixed with the residual and free tropospheric air masses, oxidized, and/or otherwise removed in this region. The characterization of diurnal variation of VOCs in the PBL is limited due to the lack of appropriate sampling platforms that are able to probe all the regions of interest: from the surface to the entrainment zone. Here we present the application of the Whole Air Sample Profiler (WASP) system during the 2013 Southeast Atmosphere Study (SAS) campaign. A total of 41 research flights (RFs) were carried out during the 2013 SAS campaign between June 1 and June 14 over the Alabama Aquatic Biodiversity Center (AABC) site and the SEARCH site. During each RF, ambient air sampling started from 50-100 m above the canopy top and stopped at ~1200 m above the mean sea level (a.m.s.l). The air samples were subsequently analyzed by using a proton-transfer-reaction time-of-flight mass spectrometry (PTR-TOF-MS). Here we analyze the vertical profiles and averaged diurnal variation of the mixing ratios of several reactive VOC species, including isoprene, the sum of monoterpenes, and first generation oxidation products of isoprene: methyl vinyl ketone and methacrolein (MVK+MACR). A MiXed Layer Chemistry (MXLCH) model, guided by the meteorological and chemical observations during the SAS campaign, is used to study the influence of boundary layer dynamics and new isoprene oxidation mechanism on the diurnal variation of major biogenic VOCs emitted from the forest canopy. The new scheme includes OH recycling through two pathways under low-NOx regime: (1) hydroxyl peroxy radicals (HOC5H8OO•; ISOPO2) unimolecular isomerization, and (2) ISOPO2+HO2. The model is able to reproduce the evolution of the boundary layer dynamics (including potential temperature, and boundary layer height) during the selected simulation dates. Based on the model results, budget

  7. Flight-determined characteristics of an air intake system on an F-111A airplane

    NASA Technical Reports Server (NTRS)

    Hughes, D. L.; Johnson, H. J.

    1972-01-01

    Flow phenomena of the F-111A air intake system were investigated over a large range of Mach number, altitude, and angle of attack. Boundary-layer variations are shown for the fuselage splitter plate and inlet entrance stations. Inlet performance is shown in terms of pressure recovery, airflow, mass-flow ratio, turbulence factor, distortion factor, and power spectral density. The fuselage boundary layer was found to be not completely removed from the upper portion of the splitter plate at all Mach numbers investigated. Inlet boundary-layer ingestion started at approximately Mach 1.6 near the translating spike and cone. Pressure-recovery distribution at the compressor face showed increasing distortion with increasing angle of attack and increasing Mach number. The time-averaged distortion-factor value approached 1300, which is near the distortion tolerance of the engine at Mach numbers above 2.1.

  8. Heat and mass transfer boundary conditions at the surface of a heated sessile droplet

    NASA Astrophysics Data System (ADS)

    Ljung, Anna-Lena; Lundström, T. Staffan

    2017-12-01

    This work numerically investigates how the boundary conditions of a heated sessile water droplet should be defined in order to include effects of both ambient and internal flow. Significance of water vapor, Marangoni convection, separate simulations of the external and internal flow, and influence of contact angle throughout drying is studied. The quasi-steady simulations are carried out with Computational Fluid Dynamics and conduction, natural convection and Marangoni convection are accounted for inside the droplet. For the studied conditions, a noticeable effect of buoyancy due to evaporation is observed. Hence, the inclusion of moisture increases the maximum velocities in the external flow. Marangoni convection will, in its turn, increase the velocity within the droplet with up to three orders of magnitude. Results furthermore show that the internal and ambient flow can be simulated separately for the conditions studied, and the accuracy is improved if the internal temperature gradient is low, e.g. if Marangoni convection is present. Simultaneous simulations of the domains are however preferred at high plate temperatures if both internal and external flows are dominated by buoyancy and natural convection. The importance of a spatially resolved heat and mass transfer boundary condition is, in its turn, increased if the internal velocity is small or if there is a large variation of the transfer coefficients at the surface. Finally, the results indicate that when the internal convective heat transport is small, a rather constant evaporation rate may be obtained throughout the drying at certain conditions.

  9. Toward a better understanding of the impact of mass transit air pollutants on human health

    USDA-ARS?s Scientific Manuscript database

    Modern mass transit systems, based on roads, rail, water, and air, generate toxic airborne pollutants throughout the developed world. This has become one of the leading concerns about the use of modern transportation, particularly in densely-populated urban areas where their use is enormous and inc...

  10. Cluster Analysis of the Organic Peaks in Bulk Mass Spectra Obtained During the 2002 New England Air Quality Study with an Aerodyne Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M.; Bertman, S. B.; Middlebrook, A. M.

    2006-12-01

    We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel R. H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter probably originating from both anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent on average 17% of the total organic mass that stems likely from biogenic sources during the ship's cruise. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

  11. Characterization of ion processes in a GC/DMS air quality monitor by integration of the instrument to a mass spectrometer.

    PubMed

    Limero, T F; Nazarov, E G; Menlyadiev, M; Eiceman, G A

    2015-02-07

    The air quality monitor (AQM), which included a portable gas chromatograph (GC) and a detector was interfaced to a mass spectrometer (MS) by introducing flow from the GC detector to the atmospheric pressure ion source of the MS. This small GC system, with a gas recirculation loop for carrier and detector make-up gases, comprised an inlet to preconcentrate volatile organic compounds (VOCs) in air, a thermal desorber before the GC column, a differential mobility spectrometer (DMS), and another DMS as an atmospheric pressure ionization source for the MS. Return flow to the internally recirculated air system of the AQM's DMS was replenished using purified air. Although ions and unreacted neutral vapors flowed from the detector through Viton® tubing into the source of the MS, ions were not detected in the MS without the auxillary ion source, (63)Ni as in the mobility detector. The GC-DMS-MS instrument provided a 3-D measurement platform (GC, DMS, and MS analysis) to explore the gas composition inside the GC-DMS recirculation loop and provide DMS-MS measurement of the components of a complex VOC mixture with performance significantly enhanced by mass-analysis, either with mass spectral scans or with an extracted ion chromatogram. This combination of a mobility spectrometer and a mass spectrometer was possible as vapors and ions are carried together through the DMS analyzer, thereby preserving the chromatographic separation efficiency. The critical benefit of this instrument concept is that all flows in and through the thoroughly integrated GC-DMS analyzer are kept intact allowing a full measure of the ion and vapor composition in the complete system. Performance has been evaluated using a synthetic air sample and a sample of airborne vapors in a laboratory. Capabilities and performance values are described using results from AQM-MS analysis of purified air, ambient air from a research laboratory in a chemistry building, and a sample of synthetic air of known composition

  12. Cluster analysis of the organic peaks in bulk mass spectra obtained during the 2002 New England Air Quality Study with an Aerodyne aerosol mass spectrometer

    NASA Astrophysics Data System (ADS)

    Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M. L.; Bertman, S. B.; Middlebrook, A. M.

    2006-06-01

    We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel Ronald H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter most probably originating from both, anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent as much as 5 µg/m3 organic aerosol mass - 17% of the total organic mass - that can be attributed to biogenic sources. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

  13. Spatial and Temporal Patterns in the Carbon Isotopic Signal of Leaf Wax Aerosols in Continental Air Masses: Linkages with Ecosystem Discrimination

    NASA Astrophysics Data System (ADS)

    Weber, J.; Conte, M. H.

    2006-12-01

    Temporal and spatial variations in the concentration and isotopic composition of atmospheric carbon dioxide can be used to estimate the relative magnitudes of the terrestrial and oceanic carbon sinks. An important model parameter is the terrestrial photosynthetic carbon isotopic fractionation of CO2 (Δ), yet estimating Δ over the large spatial scales required by models remains problematic. Epiculticular leaf waxes appear to closely reflect the plant's carbon isotopic discrimination; therefore, the ablated wax aerosols present in well-mixed continental air masses may be used as a proxy to estimate the magnitude of Δ integrated over large (subcontinental) spatial scales. Over the last several years, we have been conducting time-series studies of wax aerosol molecular and isotopic composition at strategically located sites (Maine, northern Alaska, Florida, Bermuda, Barbados) which receive continental air masses passing over major terrestrial biomes (northern temperate/ecotonal boreal forests, tundra, southern US pine/hardwood forests, North American and north African). In this presentation, we describe and contrast patterns of wax aerosol-derived estimates of Δ at these sites. In North American air masses, estimates of Δ range from 14.5-20.5 using the concentration-weighted average δ13C of wax n-acids and from 13.5-19.5 for the wax n-alcohols. Seasonal trends observed in the Florida (southern US) and Bermuda samples (mixed North American air masses) indicate maximum discrimination in early spring and minimum discrimination during the summer dry season. In northern US and high latitude air masses, seasonal trends are less pronounced but in general temporally offset with highest discrimination occurring during late summer. At Barbados, which is dominated by north African air masses passing over regions largely comprised of arid C4 grasslands, estimated Δ for the wax n-acids is significantly lower (14.0-15.5 per mil), consistent with a higher predominance of C4

  14. Turbulence measurements in hypersonic boundary layers using constant-temperature anemometry and Reynolds stress measurements in hypersonic boundary layers

    NASA Technical Reports Server (NTRS)

    Spina, Eric F.

    1995-01-01

    The primary objective in the two research investigations performed under NASA Langley sponsorship (Turbulence measurements in hypersonic boundary layers using constant temperature anemometry and Reynolds stress measurements in hypersonic boundary layers) has been to increase the understanding of the physics of hypersonic turbulent boundary layers. The study began with an extension of constant-temperature thermal anemometry techniques to a Mach 11 helium flow, including careful examinations of hot-wire construction techniques, system response, and system calibration. This was followed by the application of these techniques to the exploration of a Mach 11 helium turbulent boundary layer (To approximately 290 K). The data that was acquired over the course of more than two years consists of instantaneous streamwise mass flux measurements at a frequency response of about 500 kHz. The data are of exceptional quality in both the time and frequency domain and possess a high degree of repeatability. The data analysis that has been performed to date has added significantly to the body of knowledge on hypersonic turbulence, and the data reduction is continuing. An attempt was then made to extend these thermal anemometry techniques to higher enthalpy flows, starting with a Mach 6 air flow with a stagnation temperature just above that needed to prevent liquefaction (To approximately 475 F). Conventional hot-wire anemometry proved to be inadequate for the selected high-temperature, high dynamic pressure flow, with frequent wire breakage and poor system frequency response. The use of hot-film anemometry has since been investigated for these higher-enthalpy, severe environment flows. The difficulty with using hot-film probes for dynamic (turbulence) measurements is associated with construction limitations and conduction of heat into the film substrate. Work continues under a NASA GSRP grant on the development of a hot film probe that overcomes these shortcomings for hypersonic

  15. Estimation of nocturnal CO2 and N2O soil emissions from changes in surface boundary layer mass storage

    NASA Astrophysics Data System (ADS)

    Grant, Richard H.; Omonode, Rex A.

    2018-04-01

    Annual budgets of greenhouse and other trace gases require knowledge of the emissions throughout the year. Unfortunately, emissions into the surface boundary layer during stable, calm nocturnal periods are not measurable using most micrometeorological methods due to non-stationarity and uncoupled flow. However, during nocturnal periods with very light winds, carbon dioxide (CO2) and nitrous oxide (N2O) frequently accumulate near the surface and this mass accumulation can be used to determine emissions. Gas concentrations were measured at four heights (one within and three above canopy) and turbulence was measured at three heights above a mature 2.5 m maize canopy from 23 July to 10 September 2015. Nocturnal CO2 and N2O fluxes from the canopy were determined using the accumulation of mass within a 6.3 m control volume and out the top of the control volume within the nocturnal surface boundary layer. Diffusive fluxes were estimated by flux gradient method. The total accumulative and diffusive fluxes during near-calm nights (friction velocities < 0.05 ms-1) averaged 1.16 µmol m-2 s-1 CO2 and 0.53 nmol m-2 s-1 N2O. Fluxes were also measured using chambers. Daily mean CO2 fluxes determined by the accumulation method were 90 to 130 % of those determined using soil chambers. Daily mean N2O fluxes determined by the accumulation method were 60 to 80 % of that determined using soil chambers. The better signal-to-noise ratios of the chamber method for CO2 over N2O, non-stationary flow, assumed Schmidt numbers, and anemometer tilt were likely contributing reasons for the differences in chambers versus accumulated nocturnal mass flux estimates. Near-surface N2O accumulative flux measurements in more homogeneous regions and with greater depth are needed to confirm the conclusion that mass accumulation can be effectively used to estimate soil emissions during nearly calm nights.

  16. Improved Specification of Transboundary Air Pollution over the Gulf of Mexico Using Satellite Observations

    NASA Astrophysics Data System (ADS)

    Pour Biazar, A.; Khan, M. N.; Park, Y. H.; McNider, R. T.; Cameron, B.

    2010-12-01

    model simulations showed evidence of such possibility. The episodic transport of pollution by easterlies over the GoM and the southeastern region suggests that in particular the specification of the lateral boundaries and the background air in modeling practices in this region is important. The use of MODIS aerosol products explained episodic transport of pollution from the domain boundary over the Gulf of Mexico. The incorporation of satellite data relied on a key assumption that the aerosol partitioning within the model is reliable. Therefore, while the prediction of PM2.5 total mass was substantially improved, aerosol speciation remains a challenge.

  17. Study of the Effect of Wind Speed on Evaporation from Soil Through Integrated Modeling of Atmospheric Boundary Layer and Shallow Subsurface

    NASA Astrophysics Data System (ADS)

    Smits, K. M.; Davarzani, H.; Illangasekare, T. H.

    2012-12-01

    The study of the interaction between the land and atmosphere is paramount to our understanding of many emerging problems to include climate change and the movement of green house gases such as possible leaking of sequestered CO2. Soil moisture distribution in the shallow subsurface becomes a critical factor in these problems. The heat and mass flux in the form of soil evaporation across the land surface couples the atmospheric boundary layer to the shallow subsurface. The coupling between land and the atmosphere leads to highly dynamic interactions between the porous media properties, transport processes and boundary conditions, resulting in dynamic evaporative behavior. However, the coupling at the land-atmospheric interface is rarely considered in most current models and their validation for practical applications. This is due to the complexity of the problem in field scenarios and the scarcity of field or laboratory data capable of testing and refining coupled energy and mass transfer theories. In most efforts to compute evaporation from soil, only indirect coupling is provided to characterize the interaction between non-isothermal multiphase flows under realistic atmospheric conditions even though heat and mass flux are controlled by the coupled dynamics of the land and the atmospheric boundary layer. In earlier drying modeling concepts, imposing evaporation flux (kinetic of relative humidity) and temperature as surface boundary condition is often needed. With the goal of improving our understanding of the land/atmospheric coupling, we developed a model based on the coupling of Navier-Stokes free flow and Darcy flow in porous medium. The model consists of the coupled equations of mass conservation for the liquid phase (water) and gas phase (water vapor and air) in porous medium with gas phase (water vapor and air) in free flow domain under non-isothermal, non-equilibrium conditions. The boundary conditions at the porous medium-free flow medium interface include

  18. Senstitivity analysis of horizontal heat and vapor transfer coefficients for a cloud-topped marine boundary layer during cold-air outbreaks. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Chang, Y. V.

    1986-01-01

    The effects of external parameters on the surface heat and vapor fluxes into the marine atmospheric boundary layer (MABL) during cold-air outbreaks are investigated using the numerical model of Stage and Businger (1981a). These fluxes are nondimensionalized using the horizontal heat (g1) and vapor (g2) transfer coefficient method first suggested by Chou and Atlas (1982) and further formulated by Stage (1983a). In order to simplify the problem, the boundary layer is assumed to be well mixed and horizontally homogeneous, and to have linear shoreline soundings of equivalent potential temperature and mixing ratio. Modifications of initial surface flux estimates, time step limitation, and termination conditions are made to the MABL model to obtain accurate computations. The dependence of g1 and g2 in the cloud topped boundary layer on the external parameters (wind speed, divergence, sea surface temperature, radiative sky temperature, cloud top radiation cooling, and initial shoreline soundings of temperature, and mixing ratio) is studied by a sensitivity analysis, which shows that the uncertainties of horizontal transfer coefficients caused by changes in the parameters are reasonably small.

  19. Boundary Layer Flow Control with a One Atmosphere Uniform Glow Discharge Surface Plasma

    NASA Technical Reports Server (NTRS)

    Roth, J. Reece; Sherman, Daniel M.; Wilkinson, Stephen P.

    1998-01-01

    Low speed wind tunnel data have been acquired for planar panels covered by a uniform, glow-discharge surface plasma in atmospheric pressure air known as the One Atmosphere Uniform Glow Discharge Plasma (OAUGDP). Streamwise and spanwise arrays of flush, plasma-generating surface electrodes have been studied in laminar, transitional, and fully turbulent boundary layer flow. Plasma between symmetric streamwise electrode strips caused large increases in panel drag, whereas asymmetric spanwise electrode configurations produced a significant thrust. Smoke wire flow visualization and mean velocity diagnostics show the primary cause of the phenomena to be a combination of mass transport and vortical structures induced by strong paraelectric ElectroHydroDynamic (EHD) body forces on the flow.

  20. Toward a better understanding of the impact of mass transit air pollutants on human health.

    PubMed

    Kim, Ki-Hyun; Kumar, Pawan; Szulejko, Jan E; Adelodun, Adedeji A; Junaid, Muhammad Faisal; Uchimiya, Minori; Chambers, Scott

    2017-05-01

    Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Generalized Couette Poiseuille flow with boundary mass transfer

    NASA Astrophysics Data System (ADS)

    Marques, F.; Sanchez, J.; Weidman, P. D.

    1998-11-01

    A generalized similarity formulation extending the work of Terrill (1967) for Couette Poiseuille flow in the annulus between concentric cylinders of infinite extent is given. Boundary conditions compatible with the formulation allow a study of the effects of inner and outer cylinder transpiration, rotation, translation, stretching and twisting, in addition to that of an externally imposed constant axial pressure gradient. The problem is governed by [eta], the ratio of inner to outer radii, a Poiseuille number, and nine Reynolds numbers. Single-cylinder and planar problems can be recovered in the limits [eta][rightward arrow]0 and [eta][rightward arrow]1, respectively. Two coupled primary nonlinear equations govern the meridional motion generated by uniform mass flux through the porous walls and the azimuthal motion generated by torsional movement of the cylinders; subsidiary equations linearly slaved to the primary flow govern the effects of cylinder translation, cylinder rotation, and an external pressure gradient. Steady solutions of the primary equations for uniform source/sink flow of strength F through the inner cylinder are reported for 0[less-than-or-eq, slant][eta][less-than-or-eq, slant]1. Asymptotic results corroborating the numerical solutions are found in different limiting cases. For F<0 fluid emitted through the inner cylinder fills the gap and flows uniaxially down the annulus; an asymptotic analysis leads to a scaling that removes the effect of [eta] in the pressure parameter [beta], namely [beta]=[pi]2R*2, where R*=F(1[minus sign][eta])/(1+[eta]). The case of sink flow for F>0 is more complex in that unique solutions are found at low Reynolds numbers, a region of triple solutions exists at moderate Reynolds numbers, and a two-cell solution prevails at large Reynolds numbers. The subsidiary linear equations are solved at [eta]=0.5 to exhibit the effects of cylinder translation, rotation, and an axial pressure gradient on the source/sink flows.

  2. Development of a particle-trap preconcentration-soft ionization mass spectrometric technique for the quantification of mercury halides in air.

    PubMed

    Deeds, Daniel A; Ghoshdastidar, Avik; Raofie, Farhad; Guérette, Élise-Andrée; Tessier, Alain; Ariya, Parisa A

    2015-01-01

    Measurement of oxidized mercury, Hg(II), in the atmosphere poses a significant analytical challenge as Hg(II) is present at ultra-trace concentrations (picograms per cubic meter air). Current technologies are sufficiently sensitive to measure the total Hg present as Hg(II) but cannot determine the chemical speciation of Hg(II). We detail here the development of a soft ionization mass spectrometric technique coupled with preconcentration onto nano- or microparticle-based traps prior to analysis for the measurement of mercury halides in air. The current methodology has comparable detection limits (4-11 pg m(-3)) to previously developed techniques for the measurement of total inorganic mercury in air while allowing for the identification of HgX2 in collected samples. Both mercury chloride and mercury bromide have been sporadically detected in Montreal urban and indoor air using atmospheric pressure chemical ionization-mass spectrometry (APCI-MS). We discuss limitations and advantages of the current technique and discuss potential avenues for future research including quantitative trace measurements of a larger range of mercury compounds.

  3. Seasonal and air mass trajectory effects on dissolved organic matter of bulk deposition at a coastal town in south-western Europe.

    PubMed

    Santos, Patrícia S M; Santos, Eduarda B H; Duarte, Armando C

    2013-01-01

    Rainwater contains a complex mixture of organic compounds which may influence climate, terrestrial and maritime ecosystems and thus human health. In this work, the characteristics of DOM of bulk deposition at a coastal town on the southwest of Europe were assessed by UV-visible and three-dimensional excitation-emission matrix fluorescence spectroscopies and by dissolved organic carbon (DOC) content. The seasonal and air mass trajectory effects on dissolved organic matter (DOM) of bulk deposition were evaluated. The absorbance at 250 nm (UV(250 nm)) and integrated fluorescence showed to be positively correlated with each other, and they were also positively correlated to the DOC in bulk deposition, which suggest that a constant fraction of DOM is likely to fluoresce. There was more chromophoric dissolved organic matter (CDOM) present in summer and autumn seasons than in winter and spring. Bulk deposition associated with terrestrial air masses contained a higher CDOM content than bulk deposition related to marine air masses, thus highlighting the contribution of terrestrial/anthropogenic sources.

  4. New Directions: Questions surrounding suspended particle mass used as a surrogate for air quality and for regulatory control of ambient urban air pollution

    NASA Astrophysics Data System (ADS)

    Hoare, John L.

    2014-07-01

    The original choice of particulate matter mass (PM) as a realistic surrogate for gross air pollution has gradually evolved into routine use nowadays of epidemiologically-based estimates of the monetary and other benefits expected from regulating urban air quality. Unfortunately, the statistical associations facilitating such calculations usually are based on single indices of air pollution whereas the health effects themselves are more broadly based causally. For this and other reasons the economic benefits of control tend to be exaggerated. Primarily because of their assumed inherently inferior respirability, particles ≥10 μm are generally excluded from such considerations. Where the particles themselves are chemically heterogeneous, as in an urban context, this may be inappropriate. Clearly all air-borne particles, whether coarse or fine, are susceptible to inhalation. Hence, the possibility exists for any adhering potentially harmful semi-volatile substances to be subsequently de-sorbed in vivo thereby facilitating their transport deeper into the lungs. Consequently, this alone may be a sufficient reason for including rather than rejecting during air quality monitoring the relatively coarse 10-100 μm particle fraction, ideally in conjunction with routine estimation of the gaseous co-pollutants thereby facilitating a multi-pollutant approach apropos regulation.

  5. Studies of acoustic effects on a flow boundary layer in air

    NASA Technical Reports Server (NTRS)

    Mechel, F.; Schilz, W.

    1986-01-01

    Effects of sound fields on the flow boundary layer on a flat plate subjected to a parallel flow are studied. The boundary layer is influenced by controlling the stagnation point flow at the front edge of the plate. Depending on the Reynolds number and sound frequency, excitation or suppression of turbulent is observed. Measurements were taken at wind velocities between 10 and 30 m/sec and sound frequencies between 0.2 and 3.0 kHz.

  6. Mass fluxes in the Canary Basin (eastern boundary of the North Atlantic subtropical gyre)

    NASA Astrophysics Data System (ADS)

    Burgoa, N.; Machin, F.; Marrero-Díaz, Á.; Rodríguez-Santana, Á.; Martínez-Marrero, A.

    2017-12-01

    The circulation patterns in the Canary Basin are examined with hydrographic data from two cruises carried out in 2002 and 2003 in the eastern boundary of the North Atlantic subtropical gyre (21-27.5ºN, 17.5-26ºW). These cruises were part of the COCA Project (Coastal-Ocean Carbon Exchange in the Canary Region). First we estimate the geostrophic flow within a closed box divided into 12 layers of neutral density surfaces using the thermal wind equation. The geostrophic velocities are initially referenced to a selected neutral surface previously analyzed in deep. Then, the divergence and the convergence of the flow are analyzed in the closed water volume considering the Ekman transport in the surface of this whole region. The accumulated mass transport along the perimeter of the box is estimated with the aim to study transport imbalances in the different water masses. In addition, variables like the anomalies in the transport of the salt and heat are also considered. In general, mass transport results show that more than 50% of this transport takes place in central waters and around 25% in intermediate waters. In the first cruise carried out in late summer, the circulation of the shallowest layers goes into the box along the north and south transects with values which can arrive to 2 Sv and 1 Sv respectively and it flows westward with a maximum value of 2 Sv. At intermediate levels the mass transport changes its direction going out to the north with 0.5 Sv. On the other hand, in the second cruise carried out in late spring, the transport in the shallowest layers also gets in the box through the north transect, but it goes out along the west and south transects with values which can arrive to 1 Sv and 2 Sv, respectively. At intermediate levels the transports are similar to those already described for the summer cruise. Finally, an inverse box model is applied to both datasets to obtain a solution consistent with both the thermal wind equation and with the mass and

  7. Cloud and boundary layer interactions over the Arctic sea ice in late summer

    NASA Astrophysics Data System (ADS)

    Shupe, M. D.; Persson, P. O. G.; Brooks, I. M.; Tjernström, M.; Sedlar, J.; Mauritsen, T.; Sjogren, S.; Leck, C.

    2013-09-01

    Observations from the Arctic Summer Cloud Ocean Study (ASCOS), in the central Arctic sea-ice pack in late summer 2008, provide a detailed view of cloud-atmosphere-surface interactions and vertical mixing processes over the sea-ice environment. Measurements from a suite of ground-based remote sensors, near-surface meteorological and aerosol instruments, and profiles from radiosondes and a helicopter are combined to characterize a week-long period dominated by low-level, mixed-phase, stratocumulus clouds. Detailed case studies and statistical analyses are used to develop a conceptual model for the cloud and atmosphere structure and their interactions in this environment. Clouds were persistent during the period of study, having qualities that suggest they were sustained through a combination of advective influences and in-cloud processes, with little contribution from the surface. Radiative cooling near cloud top produced buoyancy-driven, turbulent eddies that contributed to cloud formation and created a cloud-driven mixed layer. The depth of this mixed layer was related to the amount of turbulence and condensed cloud water. Coupling of this cloud-driven mixed layer to the surface boundary layer was primarily determined by proximity. For 75% of the period of study, the primary stratocumulus cloud-driven mixed layer was decoupled from the surface and typically at a warmer potential temperature. Since the near-surface temperature was constrained by the ocean-ice mixture, warm temperatures aloft suggest that these air masses had not significantly interacted with the sea-ice surface. Instead, back-trajectory analyses suggest that these warm air masses advected into the central Arctic Basin from lower latitudes. Moisture and aerosol particles likely accompanied these air masses, providing necessary support for cloud formation. On the occasions when cloud-surface coupling did occur, back trajectories indicated that these air masses advected at low levels, while mixing

  8. Tectonic activity evolution of the Scotia-Antarctic Plate boundary from mass transport deposit analysis

    NASA Astrophysics Data System (ADS)

    Pérez, Lara F.; Bohoyo, Fernando; Hernández-Molina, F. Javier; Casas, David; Galindo-Zaldívar, Jesús; Ruano, Patricia; Maldonado, Andrés.

    2016-04-01

    The spatial distribution and temporal occurrence of mass transport deposits (MTDs) in the sedimentary infill of basins and submerged banks near the Scotia-Antarctic plate boundary allowed us to decode the evolution of the tectonic activity of the relevant structures in the region from the Oligocene to present day. The 1020 MTDs identified in the available data set of multichannel seismic reflection profiles in the region are subdivided according to the geographic and chronological distributions of these features. Their spatial distribution reveals a preferential location along the eastern margins of the eastern basins. This reflects local deformation due to the evolution of the Scotia-Antarctic transcurrent plate boundary and the impact of oceanic spreading along the East Scotia Ridge (ESR). The vertical distribution of the MTDs in the sedimentary record evidences intensified regional tectonic deformation from the middle Miocene to Quaternary. Intensified deformation started at about 15 Ma, when the ESR progressively replaces the West Scotia Ridge (WSR) as the main oceanic spreading center in the Scotia Sea. Coevally with the WSR demise at about 6.5 Ma, increased spreading rates of the ESR and numerous MTDs were formed. The high frequency of MTDs during the Pliocene, mainly along the western basins, is also related to greater tectonic activity due to uplift of the Shackleton Fracture Zone by tectonic inversion and extinction of the Antarctic-Phoenix Ridge and involved changes at late Pliocene. The presence of MTDs in the southern Scotia Sea basins is a relevant indicator of the interplay between sedimentary instability and regional tectonics.

  9. Inter-annual variability of air mass and acidified pollutants transboundary exchange in the north-eastern part of the EANET region

    NASA Astrophysics Data System (ADS)

    Gromov, Sergey A.; Trifonova-Yakovleva, Alisa; Gromov, Sergey S.

    2016-04-01

    Anthropogenic emissions, be it exhaust gases or aerosols, stem from multitude of sources and may survive long-range transport within the air masses they were emitted into. So they follow regional and global transport pathways varying under different climatological regimes. Transboundary transfer of pollutants occurs this way and has a significant impact on the ecological situation of the territories neighbouring those of emission sources, as found in a few earlier studies examining the environmental monitoring data [1]. In this study, we employ a relatively facile though robust technique for estimating the transboundary air and concomitant pollutant fluxes using actual or climatological meteorological and air pollution monitoring data. Practically, we assume pollutant transfer being proportional to the horizontal transport of air enclosed in the lower troposphere and to the concentration of the pollutant of interest. The horizontal transport, in turn, is estimated using the mean layer wind direction and strength, or their descriptive statistics at the individual transects of the boundary of interest. The domain of our interest is the segment of Russian continental border in East Asia spanning from 88° E (southern Middle Siberia) to 135° E (Far East at Pacific shore). The data on atmospheric pollutants concentration are available from the Russian monitoring sites of the region-wide Acid Deposition Monitoring Network in East Asia (EANET, http://www.eanet.asia/) Mondy (Baikal area) and Primorskaya (near Vladivostok). The data comprises multi-year continuous measurement of gas-phase and particulate species abundances in air with at least biweekly sampling rate starting from 2000. In the first phase of our study, we used climatological dataset on winds derived from the aerological soundings at Russian stations along the continental border for the 10-year period (1961-1970) by the Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) [3

  10. On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2014-02-01

    Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

  11. High-Altitude Air Mass Zero Calibration of Solar Cells

    NASA Technical Reports Server (NTRS)

    Woodyard, James R.; Snyder, David B.

    2005-01-01

    Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

  12. A Resonant Pulse Detonation Actuator for High-Speed Boundary Layer Separation Control

    NASA Technical Reports Server (NTRS)

    Beck, B. T.; Cutler, A. D.; Drummond, J. P.; Jones, S. B.

    2004-01-01

    A variety of different types of actuators have been previously investigated as flow control devices. Potential applications include the control of boundary layer separation in external flows, as well as jet engine inlet and diffuser flow control. The operating principles for such devices are typically based on either mechanical deflection of control surfaces (which include MEMS flap devices), mass injection (which includes combustion driven jet actuators), or through the use of synthetic jets (diaphragm devices which produce a pulsating jet with no net mass flow). This paper introduces some of the initial flow visualization work related to the development of a relatively new type of combustion-driven jet actuator that has been proposed based on a pulse detonation principle. The device is designed to utilize localized detonation of a premixed fuel (Hydrogen)-air mixture to periodically inject a jet of gas transversely into the primary flow. Initial testing with airflow successfully demonstrated resonant conditions within the range of acoustic frequencies expected for the design. Schlieren visualization of the pulsating air jet structure revealed axially symmetric vortex flow, along with the formation of shocks. Flow visualization of the first successful sustained oscillation condition is also demonstrated for one configuration of the current test section. Future testing will explore in more detail the onset of resonant combustion and the approach to conditions of sustained resonant detonation.

  13. Measurement and modeling of diel variability of polybrominated diphenyl ethers and chlordanes in air.

    PubMed

    Moeckel, Claudia; Macleod, Matthew; Hungerbühler, Konrad; Jones, Kevin C

    2008-05-01

    Short-term variability of concentrations of polybrominated diphenyl ethers (PBDEs) and chlordanes in air at a semirural site in England over a 5 day period is reported. Four-hour air samples were collected during a period dominated by a high pressure system that produced stable diel (24-h) patterns of meteorological conditions such as temperature and atmospheric boundary layer height. PBDE and chlordane concentrations showed clear diel variability with concentrations in the afternoon and evening being 1.9 - 2.7 times higher than in the early morning. The measurements are interpreted using a multimedia mass balance model parametrized with forcing functions representing local temperature, atmospheric boundary layer height, wind speed and hydroxyl radical concentrations. Model results indicate that reversible, temperature-controlled air-surface exchange is the primary driver of the diel concentration pattern observed for chlordanes and PBDE 28. For higher brominated PBDE congeners (47, 99 and 100), the effect of variable atmospheric mixing height in combination with irreversible deposition on aerosol particles is dominant and explains the diel patterns almost entirely. Higher concentrations of chlordanes and PBDEs in air observed at the end of the study period could be related to likely source areas using back trajectory analysis. This is the first study to clearly document diel variability in concentrations of PBDEs in air over a period of several days. Our model analysis indicates that high daytime and low nighttime concentrations of semivolatile organic chemicals can arise from different underlying driving processes, and are not necessarily evidence of reversible air-surface exchange on a 24-h time scale.

  14. Convective Cold Pool Structure and Boundary Layer Recovery in DYNAMO

    NASA Astrophysics Data System (ADS)

    Savarin, A.; Chen, S. S.; Kerns, B. W.; Lee, C.; Jorgensen, D. P.

    2012-12-01

    One of the key factors controlling convective cloud systems in the Madden-Julian Oscillation (MJO) over the tropical Indian Ocean is the property of the atmospheric boundary layer. Convective downdrafts and precipitation from the cloud systems produce cold pools in the boundary layer, which can inhibit subsequent development of convection. The recovery time is the time it takes for the boundary layer to return to pre convective conditions. It may affect the variability of the convection on various time scales during the initiation of MJO. This study examines the convective cold pool structure and boundary layer recovery using the NOAA WP-3D aircraft observations, include the flight-level, Doppler radar, and GPS dropsonde data, collected during the Dynamics of MJO (DYNAMO) field campaign from November-December 2011. The depth and strength of convective cold pools are defined by the negative buoyancy, which can be computed from the dropsonde data. Convective downdraft can be affected by environmental water vapor due to entrainment. Mid-level dry air observed during the convectively suppressed phase of MJO seems to enhance convective downdraft, making the cold pools stronger and deeper. Recovery of the cold pools in the boundary layer is determined by the strength and depth of the cold pools and also the air-sea heat and moisture fluxes. Given that the water vapor and surface winds are distinct for the convectively active and suppressed phases of MJO over the Indian Ocean, the aircraft data are stratified by the two different large-scale regimes of MJO. Preliminary results show that the strength and depth of the cold pools are inversely correlated with the surrounding mid-level moisture. During the convectively suppressed phase, the recovery time is ~5-20 hours in relative weak wind condition with small air-sea fluxes. The recovery time is generally less than 6 hours during the active phase of MJO with moist mid-levels and stronger surface wind and air-sea fluxes.

  15. Gasdynamic simulations of the solar wind interaction with Venus - Boundary layer formation

    NASA Astrophysics Data System (ADS)

    McGary, J. E.

    1993-05-01

    A 2D gasdynamic simulation of the mass-loaded solar wind flow around the dayside of Venus is presented. For average ionopause conditions near 300 km, the simulations show that mass loading from the pickup of oxygen ions produces a boundary layer of finite thickness along the ionopause. Within this layer and toward the ionopause, the temperature decreases and the total mass density increases significantly. Furthermore, there is a shear in the bulk flow velocity across the boundary layer, such that the tangential flow decreases in speed as the ionopause is approached and remains low along the ionopause which is consistent with Pioneer Venus observations. Numerical simulations are carried out for various mass addition rates and demonstrate that the boundary layer develops when oxygen ion production exceeds approximately 2 x 10 exp 5/cu m per s.

  16. Mass casualty tracking with air traffic control methodologies.

    PubMed

    Hoskins, Jason D; Graham, Ross F; Robinson, Duane R; Lutz, Clifford C; Folio, Les R

    2009-06-01

    An intrahospital casualty throughput system modeled after air traffic control (ATC) tracking procedures was tested in mass casualty exercises. ATC uses a simple tactile process involving informational progress strips representing each aircraft, which are held in bays representing each stage of flight to prioritize and manage aircraft. These strips can be reordered within the bays to indicate a change in priority of aircraft sequence. In this study, a similar system was designed for patient tracking. We compared the ATC model and traditional casualty tracking methods of paper and clipboard in 18 four-hour casualty scenarios, each with 5 to 30 mock casualties. The experimental and control groups were alternated to maximize exposure and minimize training effects. Results were analyzed with Mann-Whitney statistical analysis with p value < 0.05 (two-sided). The ATC method had significantly (p = 0.017) fewer errors in critical patient data (eg, name, social security number, diagnosis). Specifically, the ATC method better tracked the mechanism of injury, working diagnosis, and disposition of patients. The ATC method also performed considerably better with patient accountability during mass casualty scenarios. Data strips were comparable with the control method in terms of ease of use. In addition, participants preferred the ATC method to the control (p = 0.003) and preferred using the ATC method (p = 0.003) to traditional methods in the future. The ATC model more effectively tracked patient data with fewer errors when compared with the clipboard method. Application of these principles can enhance trauma management and can have application in civilian and military trauma centers and emergency rooms.

  17. A boundary element method for Stokes flows with interfaces

    NASA Astrophysics Data System (ADS)

    Alinovi, Edoardo; Bottaro, Alessandro

    2018-03-01

    The boundary element method is a widely used and powerful technique to numerically describe multiphase flows with interfaces, satisfying Stokes' approximation. However, low viscosity ratios between immiscible fluids in contact at an interface and large surface tensions may lead to consistency issues as far as mass conservation is concerned. A simple and effective approach is described to ensure mass conservation at all viscosity ratios and capillary numbers within a standard boundary element framework. Benchmark cases are initially considered demonstrating the efficacy of the proposed technique in satisfying mass conservation, comparing with approaches and other solutions present in the literature. The methodology developed is finally applied to the problem of slippage over superhydrophobic surfaces.

  18. Simultaneous Heat and Mass Transfer Model for Convective Drying of Building Material

    NASA Astrophysics Data System (ADS)

    Upadhyay, Ashwani; Chandramohan, V. P.

    2018-04-01

    A mathematical model of simultaneous heat and moisture transfer is developed for convective drying of building material. A rectangular brick is considered for sample object. Finite-difference method with semi-implicit scheme is used for solving the transient governing heat and mass transfer equation. Convective boundary condition is used, as the product is exposed in hot air. The heat and mass transfer equations are coupled through diffusion coefficient which is assumed as the function of temperature of the product. Set of algebraic equations are generated through space and time discretization. The discretized algebraic equations are solved by Gauss-Siedel method via iteration. Grid and time independent studies are performed for finding the optimum number of nodal points and time steps respectively. A MATLAB computer code is developed to solve the heat and mass transfer equations simultaneously. Transient heat and mass transfer simulations are performed to find the temperature and moisture distribution inside the brick.

  19. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

    PubMed Central

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-01-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

  20. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

    PubMed

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-11-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

  1. Wire-Mesh-Based Sorber for Removing Contaminants from Air

    NASA Technical Reports Server (NTRS)

    Perry, Jay; Roychoudhury, Subir; Walsh, Dennis

    2006-01-01

    A paper discusses an experimental regenerable sorber for removing CO2 and trace components principally, volatile organic compounds, halocarbons, and NH3 from spacecraft cabin air. This regenerable sorber is a prototype of what is intended to be a lightweight alternative to activated-carbon and zeolite-pellet sorbent beds now in use. The regenerable sorber consists mainly of an assembly of commercially available meshes that have been coated with a specially-formulated washcoat containing zeolites. The zeolites act as the sorbents while the meshes support the zeolite-containing washcoat in a configuration that affords highly effective surface area for exposing the sorbents to flowing air. The meshes also define flow paths characterized by short channel lengths to prevent excessive buildup of flow boundary layers. Flow boundary layer resistance is undesired because it can impede mass and heat transfer. The total weight and volume comparison versus the atmosphere revitalization equipment used onboard the International Space Station for CO2 and trace-component removal will depend upon the design details of the final embodiment. However, the integrated mesh-based CO2 and trace-contaminant removal system is expected to provide overall weight and volume savings by eliminating most of the trace-contaminant control equipment presently used in parallel processing schemes traditionally used for spacecraft. The mesh-based sorbent media enables integrating the two processes within a compact package. For the purpose of regeneration, the sorber can be heated by passing electric currents through the metallic meshes combined with exposure to space vacuum. The minimal thermal mass of the meshes offers the potential for reduced regeneration-power requirements and cycle time required for regeneration compared to regenerable sorption processes now in use.

  2. A modeling study examining the impact of nutrient boundaries ...

    EPA Pesticide Factsheets

    A mass balance eutrophication model, Gulf of Mexico Dissolved Oxygen Model (GoMDOM), has been developed and applied to describe nitrogen, phosphorus and primary production in the Louisiana shelf of the Gulf of Mexico. Features of this model include bi-directional boundary exchanges, an empirical site-specific light attenuation equation, estimates of 56 river loads and atmospheric loads. The model was calibrated for 2006 by comparing model output to observations in zones that represent different locations in the Gulf. The model exhibited reasonable skill in simulating the phosphorus and nitrogen field data and primary production observations. The model was applied to generate a nitrogen mass balance estimate, to perform sensitivity analysis to compare the importance of the nutrient boundary concentrations versus the river loads on nutrient concentrations and primary production within the shelf, and to provide insight into the relative importance of different limitation factors on primary production. The mass budget showed the importance of the rivers as the major external nitrogen source while the atmospheric load contributed approximately 2% of the total external load. Sensitivity analysis showed the importance of accurate estimates of boundary nitrogen concentrations on the nitrogen levels on the shelf, especially at regions further away from the river influences. The boundary nitrogen concentrations impacted primary production less than nitrogen concent

  3. An anthropometric model to estimate neonatal fat mass using air displacement plethysmography

    PubMed Central

    2012-01-01

    Background Current validated neonatal body composition methods are limited/impractical for use outside of a clinical setting because they are labor intensive, time consuming, and require expensive equipment. The purpose of this study was to develop an anthropometric model to estimate neonatal fat mass (kg) using an air displacement plethysmography (PEA POD® Infant Body Composition System) as the criterion. Methods A total of 128 healthy term infants, 60 females and 68 males, from a multiethnic cohort were included in the analyses. Gender, race/ethnicity, gestational age, age (in days), anthropometric measurements of weight, length, abdominal circumference, skin-fold thicknesses (triceps, biceps, sub scapular, and thigh), and body composition by PEA POD® were collected within 1-3 days of birth. Backward stepwise linear regression was used to determine the model that best predicted neonatal fat mass. Results The statistical model that best predicted neonatal fat mass (kg) was: -0.012 -0.064*gender + 0.024*day of measurement post-delivery -0.150*weight (kg) + 0.055*weight (kg)2 + 0.046*ethnicity + 0.020*sum of three skin-fold thicknesses (triceps, sub scapular, and thigh); R2 = 0.81, MSE = 0.08 kg. Conclusions Our anthropometric model explained 81% of the variance in neonatal fat mass. Future studies with a greater variety of neonatal anthropometric measurements may provide equations that explain more of the variance. PMID:22436534

  4. THE PROCESS OF MASS TRANSFER ON THE SOLID-LIQUID BOUNDARY LAYER DURING THE RELEASE OF DICLOFENAC SODIUM AND PAPAVERINE HYDROCHLORIDE FROM TABLETS IN A PADDLE APPARATUS.

    PubMed

    Kasperek, Regina; Zimmer, Lukasz; Poleszak, Ewa

    2016-01-01

    The release study of diclofenac sodium (DIC) and papaverine hydrochloride (PAP) from two formulations of the tablets in the paddle apparatus using different rotation speeds to characterize the process of mass transfer on the solid-liquid boundary layer was carried out. The dissolution process of active substances was described by values of mass transfer coefficients, the diffusion boundary layer thickness and dimensionless numbers (Sh and Re). The values of calculated parameters showed that the release of DIC and PAP from tablets comprising potato starch proceeded faster than from tablets containing HPMC and microcrystalline cellulose. They were obtained by direct dependencies between Sh and Re in the range from 75 rpm to 125 rpm for both substances from all tablets. The description of the dissolution process with the dimensionless numbers make it possible to plan the drug with the required release profile under given in vitro conditions.

  5. Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

    NASA Astrophysics Data System (ADS)

    Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

    2012-06-01

    The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

  6. Measurement of the mass energy-absorption coefficient of air for x-rays in the range from 3 to 60 keV.

    PubMed

    Buhr, H; Büermann, L; Gerlach, M; Krumrey, M; Rabus, H

    2012-12-21

    For the first time the absolute photon mass energy-absorption coefficient of air in the energy range of 10 to 60 keV has been measured with relative standard uncertainties below 1%, considerably smaller than those of up to 2% assumed for calculated data. For monochromatized synchrotron radiation from the electron storage ring BESSY II both the radiant power and the fraction of power deposited in dry air were measured using a cryogenic electrical substitution radiometer and a free air ionization chamber, respectively. The measured absorption coefficients were compared with state-of-the art calculations and showed an average deviation of 2% from calculations by Seltzer. However, they agree within 1% with data calculated earlier by Hubbell. In the course of this work, an improvement of the data analysis of a previous experimental determination of the mass energy-absorption coefficient of air in the range of 3 to 10 keV was found to be possible and corrected values of this preceding study are given.

  7. Air flow in the boundary layer near a plate

    NASA Technical Reports Server (NTRS)

    Dryden, Hugh L

    1937-01-01

    The published data on the distribution of speed near a thin flat plate with sharp leading edge placed parallel to the flow (skin friction plate) are reviewed and the results of some additional measurements are described. The purpose of the experiments was to study the basic phenomena of boundary-layer flow under simple conditions.

  8. Alteration of the size distributions and mixing states of black carbon through transport in the boundary layer in east Asia

    NASA Astrophysics Data System (ADS)

    Miyakawa, Takuma; Oshima, Naga; Taketani, Fumikazu; Komazaki, Yuichi; Yoshino, Ayako; Takami, Akinori; Kondo, Yutaka; Kanaya, Yugo

    2017-05-01

    Ground-based measurements of black carbon (BC) were performed near an industrial source region in the early summer of 2014 and at a remote island in Japan in the spring of 2015. Here, we report the temporal variations in the transport, size distributions, and mixing states of the BC-containing particles. These particles were characterized using a continuous soot monitoring system, a single particle soot photometer, and an aerosol chemical speciation monitor. The effects of aging on the growth of BC-containing particles were examined by comparing the ground-based observations between the near-source and remote island sites. Secondary formation of sulfate and organic aerosols strongly affected the increases in BC coating (i.e., enhancement of cloud condensation nuclei activity) with air mass aging from the source to the outflow regions. The effects of wet removal on BC microphysics were elucidated by classifying the continental outflow air masses depending on the enhancement ratios of BC to CO (ΔBC / ΔCO), which were used as an indicator of the transport efficiency of BC. It was found that ΔBC / ΔCO ratios were controlled mainly by the wet removal during transport in the planetary boundary layer (PBL) on the timescale of 1-2 days. The meteorological conditions and backward trajectory analyses suggested that air masses strongly affected by wet removal originated mainly from a region in southern China (20-35° N) in the spring of 2015. Removal of large and thickly coated BC-containing particles was detected in the air masses that were substantially affected by the wet removal in the PBL, as predicted by Köhler theory. The size and water solubility of BC-containing particles in the PBL can be altered by the wet removal as well as the condensation of non-BC materials.

  9. On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2013-02-01

    Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

  10. Modeling evaporation using models that are not boundary-layer regulated.

    PubMed

    Fingas, Merv F

    2004-02-27

    Experimentation shows that oil is not strictly air boundary-layer regulated. The fact that oil evaporation is not strictly boundary-layer regulated implies that a simplistic evaporation equation suffices to describe the process. The following processes do not require consideration: wind velocity, turbulence level, area, thickness, and scale size. The factors important to evaporation are time and temperature. The equation parameters found experimentally for the evaporation of oils can be related to commonly available distillation data for the oil. Specifically, it has been found that the distillation percentage at 180 degrees C correlates well with the equation parameters. Relationships have been developed enabling calculation of evaporation equations directly from distillation data: percentage evaporated = 0.165 (%D)ln(t) where %D is the percentage (by weight) distilled at 180 degrees C and t is the time in minutes. These equations were combined with the equations generated to account for the temperature variations: percentage evaporated = [0.165(%D)+0.045(T-15))ln(t) The results have application in oil spill prediction and modeling. The simple equations can be applied using readily available data such as sea temperature and time. Old equations required oil vapour pressure, specialized distillation data, spill area, wind speed, and mass transfer coefficients, all of which are difficult to obtain.

  11. Comparison of secondary flows and boundary-layer accumulations in several turbine nozzles

    NASA Technical Reports Server (NTRS)

    Kofskey, Milton G; Allen, Hubert W; Herzig, Howard Z

    1953-01-01

    An investigation was made of losses and secondary flows in three different turbine nozzle configurations in annular cascade. Appreciable outer shroud loss cores (passage vortices) were found to exist at the discharge of blades which had thickened suction surface boundary layers near the outer shroud. Blade designs having thinner boundary layers did not show such outer shroud loss cores, but indicated greater inward radial flow of low momentum air, in the wake loss is to this extent an indication of the presence or absence of radial flow. The blade wake was a combination of profile loss and low momentum air from the outer shroud, and the magnitude of the wake loss is to this extent an indication of the presence or absence of radial flow. At a high Mach number, shock-boundary-layer thickening on the blade suction surfaces provided an additional radial flow path for low momentum air, which resulted in large inner shroud loss regions accompanied by large deviations from design values of discharge angle. (author)

  12. Stability of reference masses: VII. Cleaning methods in air and vacuum applied to a platinum mass standard similar to the international and national kilogram prototypes

    NASA Astrophysics Data System (ADS)

    Cumpson, Peter J.; Sano, Naoko; Barlow, Anders J.; Portoles, Jose F.

    2013-10-01

    Mercury contamination and the build-up of carbonaceous contamination are two contributing factors to the instability observed in kilogram prototype masses. The kilogram prototypes that lie at the core of the dissemination of the SI base unit were manufactured in the late 19th century, and have polished surfaces. In papers IV and V of this series we developed a method for cleaning noble metal mass standards in air to remove carbonaceous contamination. At the core of this ‘UVOPS’ protocol is the application of UV light and ozone gas generated in situ in air. The precise nature of the carbonaceous contamination that builds up on such surfaces is difficult to mimic demonstrably or quickly on new test surfaces, yet data from such tests are needed to provide the final confidence to allow UVOPS to be applied to a real 19th century kilogram prototype. Therefore, in the present work we have applied the UVOPS method to clean a platinum avoirdupois pound mass standard, ‘RS2’, manufactured in the mid-19th century. This is thought to have been polished in a similar manner to the kilogram prototypes. To our knowledge this platinum surface has not previously been cleaned by any method. We used x-ray photoelectron spectroscopy to identify organic contamination, and weighing to quantify the mass lost at each application of the UVOPS procedure. The UVOPS procedure is shown to be very effective. It is likely that the redefinition of the kilogram will require mass comparisons in vacuum in the years to come. Therefore, in addition to UVOPS a cleaning method for use in vacuum will also be needed. We introduce and evaluate gas cluster ion-beam (GCIB) treatment as a potential method for cleaning reference masses in vacuum. Again, application of this GCIB cleaning to a real artefact, RS2, allows us to make a realistic evaluation of its performance. While it has some attractive features, we cannot recommend it for cleaning mass standards in its present form.

  13. Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

    NASA Technical Reports Server (NTRS)

    Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Grant, William B.; Ismail, Syed; Ferrare, Richard A.; Kooi, Susan A.; Brackett, Vincent G.; Clayton, Marian B.; Avery, Melody A.

    2001-01-01

    Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The

  14. Neonatal Presentation of an Air-Filled Neck Mass that Enlarges with Valsalva: A Case Report

    PubMed Central

    Patel, Jasminkumar Bharatbhai; Kilbride, Howard; Paulson, Lorien

    2015-01-01

    Branchial cleft cysts are common causes of congenital neck masses in the pediatric population. However, neonatal presentation of branchial cleft cysts is uncommon, but recognizable secondary to acute respiratory distress from airway compression or complications secondary to infection. We report a 1-day-old infant presenting with an air-filled neck mass that enlarged with Valsalva and was not associated with respiratory distress. The infant was found to have a third branchial cleft cyst with an internal opening into the pyriform sinus. The cyst was conservatively managed with endoscopic surgical decompression and cauterization of the tract and opening. We review the embryology of branchial cleft cysts and current management. PMID:26495186

  15. Chemical-Specific Representation of Air-Soil Exchange and Soil Penetration in Regional Multimedia Models

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McKone, T.E.; Bennett, D.H.

    2002-08-01

    In multimedia mass-balance models, the soil compartment is an important sink as well as a conduit for transfers to vegetation and shallow groundwater. Here a novel approach for constructing soil transport algorithms for multimedia fate models is developed and evaluated. The resulting algorithms account for diffusion in gas and liquid components; advection in gas, liquid, or solid phases; and multiple transformation processes. They also provide an explicit quantification of the characteristic soil penetration depth. We construct a compartment model using three and four soil layers to replicate with high reliability the flux and mass distribution obtained from the exact analyticalmore » solution describing the transient dispersion, advection, and transformation of chemicals in soil with fixed properties and boundary conditions. Unlike the analytical solution, which requires fixed boundary conditions, the soil compartment algorithms can be dynamically linked to other compartments (air, vegetation, ground water, surface water) in multimedia fate models. We demonstrate and evaluate the performance of the algorithms in a model with applications to benzene, benzo(a)pyrene, MTBE, TCDD, and tritium.« less

  16. Enthalpy effects on hypervelocity boundary layers

    NASA Astrophysics Data System (ADS)

    Adam, Philippe H.

    Shots with air and carbon dioxide were carried out in the T5 shock tunnel at GALCIT to study enthalpy effects on hypervelocity boundary layers. The model tested was a 1-meter long, 5-deg half-angle cone. It was instrumented with 51 chromel-constantan coaxial thermocouples and the surface heat transfer rate was computed to deduce the state of the boundary layer. Transitional boundary layers obtained confirm the stabilizing effect of enthalpy. As the reservoir enthalpy is increased, the transition Reynolds number evaluated at the reference conditions increases. This stabilizing effect is more rapid in gases with lower dissociation energy and it seems to level off when no further dissociation can be achieved. Normalizing the reservoir enthalpy with the edge enthalpy appears to collapse the data for all gases onto a single curve. A similar collapse is obtained when normalizing both the transition location and the reservoir enthalpy with the maximum temperature conditions obtained with BLIMPK, a nonequilibrium boundary layer code. The observation that reference conditions are more appropriate to normalize high enthalpy transition data was taken a step further by comparing the tunnel data with results from a reentry experiment. When the edge conditions are used, the tunnel and flight data are around an order of magnitude apart. This is commonly attributed to high disturbance levels in tunnels that cause the boundary layer to transition early. However, when the reference conditions are used instead, the tunnel and flight data come within striking distance of one another although the trends with enthalpy are reversed. This difference could be due to the cone bending and nose blunting. Experimental laminar heat transfer levels were compared to numerical results obtained with BLIMPK. Results for air indicate that the reactions are probably in nonequilibrium and that the wall is catalytic. The catalycity is seen to yield higher surface heat transfer rates than the

  17. EPA Air Method, Toxic Organics - 15 (TO-15): Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)

    EPA Pesticide Factsheets

    Method T)-15 describes procedures for for preparation and analysis of air samples containing volatile organic compounds collected in specially-prepared canisters, using gas chromatography-mass spectrometry.

  18. Chemical composition of air masses transported from Asia to the U.S. West Coast during ITCT 2K2: Fossil fuel combustion versus biomass-burning signatures

    NASA Astrophysics Data System (ADS)

    de Gouw, J. A.; Cooper, O. R.; Warneke, C.; Hudson, P. K.; Fehsenfeld, F. C.; Holloway, J. S.; Hübler, G.; Nicks, D. K., Jr.; Nowak, J. B.; Parrish, D. D.; Ryerson, T. B.; Atlas, E. L.; Donnelly, S. G.; Schauffler, S. M.; Stroud, V.; Johnson, K.; Carmichael, G. R.; Streets, D. G.

    2004-12-01

    As part of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT 2K2), a National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft was used to study the long-range transport of Asian air masses toward the west coast of North America. During research flights on 5 and 17 May, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on 5 and 17 May and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) to propane (C3H8), and, on May 5, the percentage of particles measured by the particle analysis by laser mass spectrometry (PALMS) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast over a range of latitudes and altitudes for the entire ITCT 2K2 period, showed that air masses from Southeast Asia and China were generally observed at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for Southeast Asia. Combined with the origin of the air masses versus altitude, this qualitatively explains the increase with altitude, averaged over the whole ITCT 2K2 period, of the different biomass-burning indicators.

  19. Investigation of Gas Seeding for Planar Laser-Induced Fluorescence in Hypersonic Boundary Layers

    NASA Technical Reports Server (NTRS)

    Arisman, C. J.; Johansen, C. T.; Bathel, B. F.; Danehy, P. M.

    2015-01-01

    Numerical simulations of the gas-seeding strategies required for planar laser-induced fluorescence in a Mach 10 (approximately Mach 8.2 postshock) airflow were performed. The work was performed to understand and quantify the adverse effects associated with gas seeding and to assess various types of seed gas that could potentially be used in future experiments. In prior experiments, NO and NO2 were injected through a slot near the leading edge of a flatplate wedge model used in NASA Langley Research Center's 31 in. Mach 10 air tunnel facility. In this paper, nitric oxide, krypton, and iodine gases were simulated at various injection rates. Simulations showing the deflection of the velocity boundary layer for each of the cases are presented. Streamwise distributions of velocity and concentration boundary-layer thicknesses, as well as vertical distributions of velocity, temperature, and mass distributions, are presented for each of the cases. A comparison between simulated streamwise velocity profiles and experimentally obtained molecular tagging velocimetry profiles using a nitric oxide seeding strategy is performed to verify the influence of such a strategy on the boundary layer. The relative merits of the different seeding strategies are discussed. The results from a custom solver based on OpenFOAM version 2.2.1 are compared against results obtained from ANSYS® Fluent version 6.3.

  20. Technical note: Air compared to nitrogen as nebulizing and drying gases for electrospray ionization mass spectrometry.

    PubMed

    Mielczarek, P; Silberring, J; Smoluch, M

    In the present study we tested the application of compressed air instead of pure nitrogen as the nebulizing and drying gas, and its influence on the quality of electrospray ionization (ESI) mass spectra. The intensities of the signals corresponding to protonated molecules were significantly (twice) higher when air was used. Inspection of signal-to-noise (S/N) ratios revealed that, in both cases, sensitivity was comparable. A higher ion abundance after the application of compressed air was followed by a higher background. Another potential risk of using air in the ESI source is the possibility for sample oxidation due to the presence of oxygen. To test this, we selected five easily oxidizing compounds to verify their susceptibility to oxidation. In particular, the presence of methionine was of interest. For all the compounds studied, no oxidation was observed. Amodiaquine oxidizes spontaneously in water solutions and its oxidized form can be detected a few hours after preparation. Direct comparison of the spectra where nitrogen was used with the corresponding spectra obtained when air was applied did not show significant differences. The only distinction was slightly different patterns of adducts when air was used. The difference concerns acetonitrile, which forms higher signals when air is the nebulizing gas. It is also important that the replacement of nitrogen with air does not affect quantitative data. The prepared calibration curves also visualize an intensity twice as high (independent of concentration within tested range) of the signal where air was applied. We have used our system continuously for three months with air as the nebulizing and drying gas and have not noticed any unexpected signal deterioration caused by additional source contamination from the air. Moreover, compressed air is much cheaper and easily available using oil-free compressors or pumps.

  1. Boundary Layer Flow Over a Moving Wavy Surface

    NASA Astrophysics Data System (ADS)

    Hendin, Gali; Toledo, Yaron

    2016-04-01

    Boundary Layer Flow Over a Moving Wavy Surface Gali Hendin(1), Yaron Toledo(1) January 13, 2016 (1)School of Mechanical Engineering, Tel-Aviv University, Israel Understanding the boundary layer flow over surface gravity waves is of great importance as various atmosphere-ocean processes are essentially coupled through these waves. Nevertheless, there are still significant gaps in our understanding of this complex flow behaviour. The present work investigates the fundamentals of the boundary layer air flow over progressive, small-amplitude waves. It aims to extend the well-known Blasius solution for a boundary layer over a flat plate to one over a moving wavy surface. The current analysis pro- claims the importance of the small curvature and the time-dependency as second order effects, with a meaningful impact on the similarity pattern in the first order. The air flow over the ocean surface is modelled using an outer, inviscid half-infinite flow, overlaying the viscous boundary layer above the wavy surface. The assumption of a uniform flow in the outer layer, used in former studies, is now replaced with a precise analytical solution of the potential flow over a moving wavy surface with a known celerity, wavelength and amplitude. This results in a conceptual change from former models as it shows that the pressure variations within the boundary layer cannot be neglected. In the boundary layer, time-dependent Navier-Stokes equations are formulated in a curvilinear, orthogonal coordinate system. The formulation is done in an elaborate way that presents additional, formerly neglected first-order effects, resulting from the time-varying coordinate system. The suggested time-dependent curvilinear orthogonal coordinate system introduces a platform that can also support the formulation of turbulent problems for any surface shape. In order to produce a self-similar Blasius-type solution, a small wave-steepness is assumed and a perturbation method is applied. Consequently, a

  2. Choice of no-slip curved boundary condition for lattice Boltzmann simulations of high-Reynolds-number flows

    NASA Astrophysics Data System (ADS)

    Sanjeevi, Sathish K. P.; Zarghami, Ahad; Padding, Johan T.

    2018-04-01

    Various curved no-slip boundary conditions available in literature improve the accuracy of lattice Boltzmann simulations compared to the traditional staircase approximation of curved geometries. Usually, the required unknown distribution functions emerging from the solid nodes are computed based on the known distribution functions using interpolation or extrapolation schemes. On using such curved boundary schemes, there will be mass loss or gain at each time step during the simulations, especially apparent at high Reynolds numbers, which is called mass leakage. Such an issue becomes severe in periodic flows, where the mass leakage accumulation would affect the computed flow fields over time. In this paper, we examine mass leakage of the most well-known curved boundary treatments for high-Reynolds-number flows. Apart from the existing schemes, we also test different forced mass conservation schemes and a constant density scheme. The capability of each scheme is investigated and, finally, recommendations for choosing a proper boundary condition scheme are given for stable and accurate simulations.

  3. Choice of no-slip curved boundary condition for lattice Boltzmann simulations of high-Reynolds-number flows.

    PubMed

    Sanjeevi, Sathish K P; Zarghami, Ahad; Padding, Johan T

    2018-04-01

    Various curved no-slip boundary conditions available in literature improve the accuracy of lattice Boltzmann simulations compared to the traditional staircase approximation of curved geometries. Usually, the required unknown distribution functions emerging from the solid nodes are computed based on the known distribution functions using interpolation or extrapolation schemes. On using such curved boundary schemes, there will be mass loss or gain at each time step during the simulations, especially apparent at high Reynolds numbers, which is called mass leakage. Such an issue becomes severe in periodic flows, where the mass leakage accumulation would affect the computed flow fields over time. In this paper, we examine mass leakage of the most well-known curved boundary treatments for high-Reynolds-number flows. Apart from the existing schemes, we also test different forced mass conservation schemes and a constant density scheme. The capability of each scheme is investigated and, finally, recommendations for choosing a proper boundary condition scheme are given for stable and accurate simulations.

  4. Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

    NASA Astrophysics Data System (ADS)

    Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

    2015-04-01

    While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

  5. Relationship Between Chronic Obstructive Pulmonary Disease and Air Pollutants Depending on the Origin and Trajectory of Air Masses in the North of Spain.

    PubMed

    Santurtún, Ana; Rasilla, Domingo F; Riancho, Leyre; Zarrabeitia, María T

    2017-11-01

    Chronic obstructive pulmonary disease (COPD) is a common respiratory condition and one of the leading causes of death. Our aim was to analyze the association between emergency room visits due to this disease and meteorological variables and atmospheric contaminant levels in Santander, depending on the origin and trajectory of air masses. Data from emergency room visits at Hospital Marqués de Valdecilla were collected on a daily basis during an 8-year period. Data on concentrations of the main atmospheric pollutants and meteorological variables were also recorded.Retrotrajectories leading to Santander at a height of1,500 meters above sea level were then calculated. Finally, a correlation model was produced to evaluate the effect of the contaminants on emergency visitsdue to COPD. There is a direct association between PM 10 levels and the number of visits to the emergency room due to COPD. For every 10μg/m3 increase in pollutantlevels, emergency visitsincrease by3.34% (p=0.00005), and thiseffect is enhanced in individualsover 74 years of age. This effect is heightened when PM10 levels depend on air masses from the South and when air recirculation occurs. There is no association betweenother pollutants and the number of visits to the emergency room. Exposure to high levels of PM10 causes exacerbations in COPD patients. By studying the atmospheric circulation pattern, we can predict whether PM10 levels will be inappropriately high, and we can also obtain information about the particle components. Copyright © 2017 SEPAR. Publicado por Elsevier España, S.L.U. All rights reserved.

  6. 75 FR 55277 - Outer Continental Shelf Air Regulations; Consistency Update for California

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-10

    ... control air pollution from OCS sources located within 25 miles of States' seaward boundaries that are the... located within 25 miles of States' seaward boundaries must be updated periodically to remain consistent... FR 67845), EPA proposed to incorporate various South Coast AQMD air pollution control requirements...

  7. Establishing Lagrangian connections between observations within air masses crossing the Atlantic during the International Consortium for Atmospheric Research on Transport and Transformation experiment

    NASA Astrophysics Data System (ADS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D. D.; Reeves, C. E.; Schlager, H.; Atlas, E.; Blake, D. R.; Coe, H.; Crosier, J.; Flocke, F. M.; Holloway, J. S.; Hopkins, J. R.; McQuaid, J.; Purvis, R.; Rappenglück, B.; Singh, H. B.; Watson, N. M.; Whalley, L. K.; Williams, P. I.

    2006-12-01

    The ITCT-Lagrangian-2K4 (Intercontinental Transport and Chemical Transformation) experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end, attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts from two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique then identifies Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these "coincident matches" is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown, and the downwind minus upwind differences in tracers are discussed.

  8. Characteristics of Boundary Layer Structure during a Persistent Haze Event in the Central Liaoning City Cluster, Northeast China

    NASA Astrophysics Data System (ADS)

    Li, Xiaolan; Wang, Yangfeng; Shen, Lidu; Zhang, Hongsheng; Zhao, Hujia; Zhang, Yunhai; Ma, Yanjun

    2018-04-01

    The characteristics of boundary layer structure during a persistent regional haze event over the central Liaoning city cluster of Northeast China from 16 to 21 December 2016 were investigated based on the measurements of particulate matter (PM) concentration and the meteorological data within the atmospheric boundary layer (ABL). During the observational period, the maximum hourly mean PM2.5 and PM10 concentrations in Shenyang, Anshan, Fushun, and Benxi ranged from 276 to 355 μg m-3 and from 378 to 442 μg m-3, respectively, and the lowest hourly mean atmospheric visibility (VIS) in different cities ranged from 0.14 to 0.64 km. The central Liaoning city cluster was located in the front of a slowly moving high pressure and was mainly controlled by southerly winds. Wind speed (WS) within the ABL (< 2 km) decreased significantly and WS at 10-m height mostly remained below 2 m s-1 during the hazy episodes, which was favorable for the accumulation of air pollutants. A potential temperature inversion layer existed throughout the entire ABL during the earlier hazy episode [from 0500 Local Time (LT) 18 December to 1100 LT 19 December], and then a potential temperature inversion layer developed with the bottom gradually decreased from 900 m to 300 m. Such a stable atmospheric stratification further weakened pollutant dispersion. The atmospheric boundary layer height (ABLH) estimated based on potential temperature profiles was mostly lower than 400 m and varied oppositely with PM2.5 in Shenyang. In summary, weak winds due to calm synoptic conditions, strong thermal inversion layer, and shallow atmospheric boundary layer contributed to the formation and development of this haze event. The backward trajectory analysis revealed the sources of air masses and explained the different characteristics of the haze episodes in the four cities.

  9. Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-01-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  10. Gaseous elemental mercury in the marine boundary layer and air-sea flux in the Southern Ocean in austral summer.

    PubMed

    Wang, Jiancheng; Xie, Zhouqing; Wang, Feiyue; Kang, Hui

    2017-12-15

    Gaseous elemental mercury (GEM) in the marine boundary layer (MBL), and dissolved gaseous mercury (DGM) in surface seawater of the Southern Ocean were measured in the austral summer from December 13, 2014 to February 1, 2015. GEM concentrations in the MBL ranged from 0.4 to 1.9ngm -3 (mean±standard deviation: 0.9±0.2ngm -3 ), whereas DGM concentrations in surface seawater ranged from 7.0 to 75.9pgL -1 (mean±standard deviation: 23.7±13.2pgL -1 ). The occasionally observed low GEM in the MBL suggested either the occurrence of atmospheric mercury depletion in summer, or the transport of GEM-depleted air from the Antarctic Plateau. Elevated GEM concentrations in the MBL and DGM concentrations in surface seawater were consistently observed in the ice-covered region of the Ross Sea implying the influence of the sea ice environment. Diminishing sea ice could cause more mercury evasion from the ocean to the air. Using the thin film gas exchange model, the air-sea fluxes of gaseous mercury in non-ice-covered area during the study period were estimated to range from 0.0 to 6.5ngm -2 h -1 with a mean value of 1.5±1.8ngm -2 h -1 , revealing GEM (re-)emission from the East Southern Ocean in summer. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. The Interactions of a Flame and Its Self-Induced Boundary Layer

    NASA Technical Reports Server (NTRS)

    Ott, James D.; Oran, Elaine S.; Anderson, John D.

    1999-01-01

    The interaction of a laminar flame with its self-generated boundary layer in a rectangular channel was numerically simulated using the two-dimensional, reacting, Navier-Stokes equations. A two species chemistry model was implemented which simulates the stoichiometric reaction of acetylene and air. Calculations were performed to investigate the effects of altering the boundary condition of the wall temperature, the Lewis number, the dynamic viscosity, and the ignition method. The purpose of this study was to examine the fundamental physics of the formation of the boundary layer and the interaction of the flame as it propagates into the boundary layer that its own motion has created.

  12. Tangential blowing for control of strong normal shock - Boundary layer interactions on inlet ramps

    NASA Technical Reports Server (NTRS)

    Schwendemann, M. F.; Sanders, B. W.

    1982-01-01

    The use of tangential blowing from a row of holes in an aft facing step is found to provide good control of the ramp boundary layer, normal shock interaction on a fixed geometry inlet over a wide range of inlet mass flow ratios. Ramp Mach numbers of 1.36 and 1.96 are investigated. The blowing geometry is found to have a significant effect on system performance at the highest Mach number. The use of high-temperature air in the blowing system, however, has only a slight effect on performance. The required blowing rates are significantly high for the most severe test conditions. In addition, the required blowing coefficient is found to be proportional to the normal shock pressure rise.

  13. Formic and Acetic Acid Observations over Colorado by Chemical Ionization Mass Spectrometry and Organic Acids' Role in Air Quality

    NASA Astrophysics Data System (ADS)

    Treadaway, V.; O'Sullivan, D. W.; Heikes, B.; Silwal, I.; McNeill, A.

    2015-12-01

    Formic acid (HFo) and acetic acid (HAc) have both natural and anthropogenic sources and a role in the atmospheric processing of carbon. These organic acids also have an increasing importance in setting the acidity of rain and snow as precipitation nitrate and sulfate concentrations have decreased. Primary emissions for both organic acids include biomass burning, agriculture, and motor vehicle emissions. Secondary production is also a substantial source for both acids especially from biogenic precursors, secondary organic aerosols (SOAs), and photochemical production from volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs). Chemical transport models underestimate organic acid concentrations and recent research has sought to develop additional production mechanisms. Here we report HFo and HAc measurements during two campaigns over Colorado using the peroxide chemical ionization mass spectrometer (PCIMS). Iodide clusters of both HFo and HAc were recorded at mass-to-charge ratios of 173 and 187, respectively. The PCIMS was flown aboard the NCAR Gulfstream-V platform during the Deep Convective Clouds and Chemistry Experiment (DC3) and aboard the NCAR C-130 during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE). The DC3 observations were made in May and June 2012 extending from the surface to 13 km over the central and eastern United States. FRAPPE observations were made in July and August 2014 from the surface to 7 km over Colorado. DC3 measurements reported here are focused over the Colorado Front Range and complement the FRAPPE observations. DC3 HFo altitude profiles are characterized by a decrease up to 6 km followed by an increase either back to boundary layer mixing ratio values or higher (a "C" shape). Organic acid measurements from both campaigns are interpreted with an emphasis on emission sources (both natural and anthropogenic) over Colorado and in situ photochemical production especially ozone precursors.

  14. Wall Boundary Layer Measurements for the NASA Langley Transonic Dynamics Tunnel

    NASA Technical Reports Server (NTRS)

    Wieseman, Carol D.; Bennett, Robert M.

    2007-01-01

    Measurements of the boundary layer parameters in the NASA Langley Transonic Dynamics tunnel were conducted during extensive calibration activities following the facility conversion from a Freon-12 heavy-gas test medium to R-134a. Boundary-layer rakes were mounted on the wind-tunnel walls, ceiling, and floor. Measurements were made over the range of tunnel operation envelope in both heavy gas and air and without a model in the test section at three tunnel stations. Configuration variables included open and closed east sidewall wall slots, for air and R134a test media, reentry flap settings, and stagnation pressures over the full range of tunnel operation. The boundary layer thickness varied considerably for the six rakes. The thickness for the east wall was considerably larger that the other rakes and was also larger than previously reported. There generally was some reduction in thickness at supersonic Mach numbers, but the effect of stagnation pressure, and test medium were not extensive.

  15. A 16-yr Comparison of Fine Particle and Aerosol Strong Acidity at the Interface Zone (1,540 m) and Within (452 m) the Planetary Boundary Layer of the Great Gulf and Presidential-Dry River Class I Wildernesses on the Presidential Range, New Hampshire

    NASA Technical Reports Server (NTRS)

    Murray, Georgia L.; Kimball, Kenneth; Hill, Bruce; Allen, George A.; Wolfson, Jack M.; Seidel, Thomas M.; Doddridge, Bruce G.

    2009-01-01

    Mount Washington, NH in the White Mountain National Forest, is flanked to the north-northeast and south by two Class I Wilderness areas, the Great Gulf and Presidential Range-Dry River Wildernesses, respectively. The Clean Air Act protects Class I area natural resource values from air pollution. Aerosol sulfate, a fine particulate component that is often transported long distances, is a known contributor to visibility degradation and acidic deposition. We examined summertime fine particulate aerosol mass and sulfate, strong acidity and ammonium concentrations from 1988 to 2004 on Mount Washington at two elevations, 452 and 1,540 meters (msl). The former site is within, and the latter at the interface of, the planetary boundary layer. Comparisons of sampling interval durations (10 and 24 hours), site vs. site, and different sampling methods are made. We also examine the extent to which aerosol sulfate is neutralized. Ten hour (daytime) compared to 24 hour samples have higher mass and aerosol sulfate concentrations, however paired samples are well correlated. Fine mass concentrations compared between the 452 m and 1,540 m sites (standard temperature and pressure corrected) show a weak positive linear relationship with the later being approximately 34% lower. We attribute the lack of a strong correlation to the facts that the 1,540 m site is commonly at the interface of and even above the regional planetary boundary layer in summer and that it can intercept different air masses relative to the 452 m site. Sulfate is approximately 19% lower at the higher elevation site, but comprises a greater percentage of total fine mass; 42% compared to 35% for the high and low elevation site, respectively. Aerosol strong acidity was found to increase with increasing sulfate concentrations at both sites. At the high elevation site, elevated mass and sulfate concentrations are associated with westerly and southwesterly regional flows.

  16. Transport of contaminants in the planetary boundary layer

    NASA Technical Reports Server (NTRS)

    Lee, I. Y.; Swan, P. R.

    1978-01-01

    A planetary boundary layer model is described and used to simulate PBL phenomena including cloud formation and pollution transport in the San Francisco Bay Area. The effect of events in the PBL on air pollution is considered, and governing equations for the average momentum, potential temperature, water vapor mixing ratio, and air contaminants are presented. These equations are derived by integrating the basic equations vertically through the mixed layer. Characteristics of the day selected for simulation are reported, and the results suggest that the diurnally cyclic features of the mesoscale motion, including clouds and air pollution, can be simulated in a readily interpretable way with the model.

  17. Potential sources of the air masses leading to warm and cold anomalies in Moscow in summer

    NASA Astrophysics Data System (ADS)

    Shukurov, K. A.; Semenov, V. A.

    2017-11-01

    For summer (June-July-August) days in 1949-2016, using the NOAA trajectory model HYSPLIT_4, the 5-day backward trajectories of the air parcels (elementary air particles) were calculated. Using the daily surface air temperatures (SAT) in summer in Moscow in 1949-2016 and the results of the backward trajectories modeling by PSCF (potential source contribution function) and CWT (concentration weighted trajectories) methods the regions where the air masses most probably hit to before its arrive into the Moscow region at the days of 20%, 10%, 5% and 2% of the strongest positive and negative anomalies of SAT in summer in Moscow. For composites of days with SAT in summer in Moscow above 90th and below the 10th percentile of the distribution function of the SAT, the field of the anomaly of atmospheric pressure at sea level relative to 1981-2010 climatology and the field of average SAT in Eurasia north of 30° N are calculated. The peculiarities of the fields associated with the strong positive and negative anomalies of SAT in summer seasons in Moscow are identified. The fields of potential sources of air parcels, mean air temperature on the path of the movement of air parcels and the average height of the backward trajectory for days with strong anomalies of SAT in summer in Moscow are compared. Possible atmospheric circulation drivers of the highest and lowest anomalies of SAT in winter in Moscow are found out.

  18. Blowing Snow Sublimation at a High Altitude Alpine Site and Effects on the Surface Boundary Layer

    NASA Astrophysics Data System (ADS)

    Vionnet, V.; Guyomarc'h, G.; Sicart, J. E.; Deliot, Y.; Naaim-Bouvet, F.; Bellot, H.; Merzisen, H.

    2017-12-01

    In alpine terrain, wind-induced snow transport strongly influences the spatial and temporal variability of the snow cover. During their transport, blown snow particles undergo sublimation with an intensity depending on atmospheric conditions (air temperature and humidity). The mass loss due to blowing snow sublimation is a source of uncertainty for the mass balance of the alpine snowpack. Additionally, blowing snow sublimation modifies humidity and temperature in the surface boundary layer. To better quantify these effects in alpine terrain, a dedicated measurement setup has been deployed at the experimental site of Col du Lac Blanc (2720 m a.s.l., French Alps, Cryobs-Clim network) since winter 2015/2016. It consists in three vertical masts measuring the near-surface vertical profiles (0.2-5 m) of wind speed, air temperature and humidity and blowing snow fluxes and size distribution. Observations collected during blowing snow events without concurrent snowfall show only a slight increase in relative humidity (10-20%) and near-surface saturation is never observed. Estimation of blowing snow sublimation rates are then obtained from these measurements. They range between 0 and 5 mmSWE day-1 for blowing snow events without snowfall in agreement with previous studies in different environments (North American prairies, Antarctica). Finally, an estimation of the mass loss due to blowing snow sublimation at our experimental site is proposed for two consecutive winters. Future use of the database collected in this study includes the evaluation of blowing snow models in alpine terrain.

  19. Ground-water-level monitoring, basin boundaries, and potentiometric surfaces of the aquifer system at Edwards Air Force Base, California, 1992

    USGS Publications Warehouse

    Rewis, D.L.

    1995-01-01

    A ground-water-level monitoring program was implemented at Edwards Air Force Base, California, from January through December 1992 to monitor spatial and temporal changes in poten-tiometric surfaces that largely are affected by ground-water pumping. Potentiometric-surface maps are needed to determine the correlation between declining ground- water levels and the distribution of land subsidence. The monitoring program focused on areas of the base where pumping has occurred, especially near Rogers Lake, and involved three phases of data collection: (1) well canvassing and selection, (2) geodetic surveys, and (3) monthly ground-water-level measurements. Construction and historical water- level data were compiled for 118 wells and pi-ezometers on or near the base, and monthly ground-water-level measurements were made in 82 wells and piezometers on the base. The compiled water-level data were used in conjunction with previously collected geologic data to identify three types of no-flow boundaries in the aquifer system: structural boundaries, a principal-aquifer boundary, and ground-water divides. Heads were computed from ground-water-level measurements and land-surface altitudes and then were used to map seasonal potentiometric surfaces for the principal and deep aquifers underlying the base. Pumping has created a regional depression in the potentiometric surface of the deep aquifer in the South Track, South Base, and Branch Park well-field area. A 15-foot decline in the potentiometric surface from April to September 1992 and 20- to 30-foot drawdowns in the three production wells in the South Track well field caused locally unconfined conditions in the deep aquifer.

  20. Atmospheric boundary layer modification in the marginal ice zone

    NASA Technical Reports Server (NTRS)

    Bennett, Theodore J., Jr.; Hunkins, Kenneth

    1986-01-01

    A case study of the Andreas et al. (1984) data on atmospheric boundary layer modification in the marginal ice zone is made. The model is a two-dimensional, multilevel, linear model with turbulence, lateral and vertical advection, and radiation. Good agreement between observed and modeled temperature cross sections is obtained. In contrast to the hypothesis of Andreas et al., the air flow is found to be stable to secondary circulations. Adiabatic lifting and, at long fetches, cloud top longwave cooling, not an air-to-surface heat flux, dominate the cooling of the boundary layer. The accumulation with fetch over the ice of changes in the surface wind field is shown to have a large effect on estimates of the surface wind stress. It is speculated that the Andreas et al. estimates of the drag coefficient over the compact sea ice are too high.

  1. International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

    PubMed

    Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

    2014-08-05

    Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

  2. Operational performance of a low cost, air mass 2 solar simulator

    NASA Technical Reports Server (NTRS)

    Yass, K.; Curtis, H. B.

    1975-01-01

    Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.

  3. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  4. Aircraft observations of East-Asian cyclone induced uplift and long-range transport of polluted boundary layer air to the lowermost stratosphere

    NASA Astrophysics Data System (ADS)

    Schlager, Hans; Arnold, Frank; Aufmhoff, Heinrich; Baumann, Robert; Priola, Lisa; Roiger, Anke; Sailer, Tomas; Wirth, Martin; Schumann, Ulrich

    2013-04-01

    We report on the airborne detection of a large-scale stratified pollution layer in the lowermost stratosphere which contained increased concentrations of sulfur dioxide, reactive nitrogen, water vapour and sulfate aerosols. The measurements were performed over Central Europe with a chemical ionization mass spectrometer and a high spectral resolution Lidar on board the new German research aircraft HALO. Transport model simulations indicate the East-Asian planetary boundary layer (PBL) as the source region of this layer. The PBL air was uplifted by an East Asian warm conveyor belt (WCB) and thereafter experienced mostly horizontal transport and dispersion covering significant part of the northern hemisphere. The pollution layer extent up to 2 km above the thermal tropopause and appears to be trapped in the upper part of the tropopause inversion layer (TIL). Accompanying chemistry and aerosol model simulations indicate efficient SO2 conversion to sulfuric acid during the horizontal transport in the TIL, accelerated by increased OH resulting from the increased water vapour. Low temperature and increased water vapour led to efficient binary H2SO4/H2O nucleation. The uplifted anthropogenic nitrogen oxides experienced OH and particle mediated conversion to HNO3. The layer of sulfate particles formed in the upper part of the TIL was observed in the Lidar backscatter signal. Since mid-latitude East Asia is a region with very large SO2 emissions and a very high frequency of WCBs, SO2 uplift into the lowermost stratosphere from this region may occur frequently, eventually leading very often to corresponding pollution layers in the northern-hemisphere TIL.

  5. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  6. Human factors in aviation: Terminal control area boundary conflicts

    NASA Technical Reports Server (NTRS)

    Monan, William P.

    1989-01-01

    Air-to-air conflicts in the vicinity of Terminal Control Area (TCA) boundaries were studied to obtain a better understanding of the causal dynamics of these events with particular focus on human factor issues. The study dataset consisted of 381 Instrument Flight Rules/Visual Flight Rules (IFR/VFR) traffic conflicts in airspace layers above TCA ceiling and below TCA floors; 213 reports of incursions in TCA terminal airspace by VFR aircraft, of which 123 resulted in conflicts; and an additional set of reports describing problems with Air Traffic Control (ATC) services in and around TCAs. Results and conclusions are detailed.

  7. Air-sea fluxes of momentum and mass in the presence of wind waves

    NASA Astrophysics Data System (ADS)

    Zülicke, Christoph

    2010-05-01

    An air-sea interaction model (ASIM) is developed including the effect of wind waves on momentum and mass transfer. This includes the derivation of profiles of dissipation rate, flow speed and concentration from a certain height to a certain depth. Simplified assumptions on the turbulent closure, skin - bulk matching and the spectral wave model allow for an analytic treatment. Particular emphasis was put on the inclusion of primary (gravity) waves and secondary (capillary-gravity) waves. The model was tuned to match wall-flow theory and data on wave height and slope. Growing waves reduce the air-side turbulent stress and lead to an increasing drag coefficient. In the sea, breaking waves inject turbulent kinetic energy and accelerate the transfer. Cross-reference with data on wave-related momentum and energy flux, dissipation rate and transfer velocity was sufficient. The evaluation of ASIM allowed for the analytical calculation of bulk formulae for the wind-dependent gas transfer velocity including information on the air-side momentum transfer (drag coefficient) and the sea-side gas transfer (Dalton number). The following regimes have been identified: the smooth waveless regime with a transfer velocity proportional to (wind) × (diffusion)2-3, the primary wave regime with a wind speed dependence proportional to (wind)1-4 × (diffusion)1-2-(waveage)1-4 and the secondary wave regime including a more-than-linear wind speed dependence like (wind)15-8 × (diffusion)1-2 × (waveage)5-8. These findings complete the current understanding of air-sea interaction for medium winds between 2 and 20 m s^-1.

  8. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction

    NASA Astrophysics Data System (ADS)

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-07-01

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid-high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years.

  9. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction

    PubMed Central

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-01-01

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid–high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years. PMID:27414998

  10. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction.

    PubMed

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-07-14

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid-high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years.

  11. Planetary Boundary Layer Dynamics over Reno, Nevada in Summer

    NASA Astrophysics Data System (ADS)

    Liming, A.; Sumlin, B.; Loria Salazar, S. M.; Holmes, H.; Arnott, W. P.

    2014-12-01

    Quantifying the height of the planetary boundary layer (PBL) is important to understand the transport behavior, mixing, and surface concentrations of air pollutants. In Reno, NV, located in complex, mountainous terrain with high desert climate, the daytime boundary layer can rise to an estimated 3km or more on a summer day due to surface heating and convection. The nocturnal boundary layer, conversely, tends to be much lower and highly stable due to radiative cooling from the surface at night and downslope flow of cool air from nearby mountains. With limited availability of radiosonde data, current estimates of the PBL height at any given time or location are potentially over or underestimated. To better quantify the height and characterize the PBL physics, we developed portable, lightweight sensors that measure CO2 concentrations, temperature, pressure, and humidity every 5 seconds. Four of these sensors are used on a tethered balloon system to monitor CO2 concentrations from the surface up to 300m. We will combine this data with Radio Acoustic Sounding System (RASS) data that measures vertical profiles of wind speed, temperature, and humidity from 40m to 400m. This experiment will characterize the diurnal evolution of CO2 concentrations at multiple heights in the PBL, provide insight into PBL physics during stability transition periods at sunrise and sunset, and estimate the nighttime PBL depth during August in Reno. Further, we expect to gain a better understanding of the impact of mixing volume changes (i.e., PBL height) on air quality and pollution concentrations in Reno. The custom portable sensor design will also be presented. It is expected that these instruments can be used for indoor or outdoor air quality studies, where lightness, small size, and battery operation can be of benefit.

  12. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  13. The Western North American Cretaceous-Tertiary (K-T) boundary interval and its content of shock-metamorphosed minerals: Implications concerning the K-T boundary impact-extinction theory

    NASA Technical Reports Server (NTRS)

    Izett, G. A.

    1988-01-01

    At 20 sites in the Raton Basin of Colorado and New Mexico, and at several other sites in Wyoming, Montana, and Canada, a pair of claystone units, an Ir abundance anomaly, and a concentration of shock-metamorphosed minerals mark the palynological K-T boundary. The K-T boundary claystone, which is composed of kaolinite and small amounts of illite/smectite mixed-layer clay, is similar in most respects to kaolinite tonstein layers in coal beds. At some, but not all, K-T boundary localities, the boundary claystone contains solid kaolinite and hollow and solid goyazite spherules, 0.05 to 1.2 mm in diameter. The upper unit, the K-T boundary impact layer, consists chiefly of kaolinite and various amounts of illite/smectite mixed-layer clay. The impact layer and boundary claystone are similar chemically, except that the former has slightly more Fe, K, Ba, Cr, Cu, Li, V, and Zn than the latter. The facts that the boundary claystone and impact layer contain anomalous amounts of Ir, comprise a stratigraphic couplet at Western North American sites, and form thin, discrete layers, similar to air-fall units (volcanic or impact), suggest that the claystone units are of impact origin. Significantly, the impact layer contains as much as 2 percent clastic mineral grains, about 30 percent of which contain multiple sets of shock lamellae. Only one such concentration of shocked minerals has been found near the K-T boundary. The type of K-T boundary shock-metamorphosed materials (quartzite and metaquartzite) in the impact layer and the lack of shock lamellae in quartz and feldspar of pumice lapilli and granitic xenoliths in air-fall pumice units of silicic tuffs, such as the Bishop Tuff, eliminate the possibility that the shock-metamorphosed minerals in the K-T impact layer are of volcanic origin. The global size distribution and abundance of shock-metamorphosed mineral grains suggest that the K-T impact occurred in North America.

  14. Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; Pȩkala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcău, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Curci, G.

    2014-11-01

    The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth τa(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean τa(3.5 km) ∼ 0.04 - and shows a seasonal trend with a winter minimum - τa(3.5 km) ∼ 0.03 -, and a summer maximum - τa(3.5 km) ∼ 0.06 -, and an unexpected increase from August to September - τa(3.5 km) ∼ 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. Average concentrations are affected by continental sources (wind-blown dust and urban pollution), whilst the peak observed in September and October could be linked to biomass burning in the northern part of Argentina or air pollution coming from surrounding urban areas.

  15. Membrane-Mediated Extraction and Biodegradation of Volatile Organic Compounds From Air

    DTIC Science & Technology

    2005-01-01

    side boundary-layer mass transfer resistance is a significant fraction of the total mass transfer resistance ( Raghunath , 1992). In some cases where...Sci. 59: 53–72. Raghunath , B., and S.–T. Hwang (1992). “Effect of boundary layer mass transfer resistance in the pervaporation of dilute organics

  16. Non-proximate mass spectrometry using a heated 1-m long PTFE tube and an air-tight APCI ion source.

    PubMed

    Usmanov, Dilshadbek T; Hiraoka, Kenzo; Wada, Hiroshi; Matsumura, Masaya; Sanada-Morimura, Sachiyo; Nonami, Hiroshi; Yamabe, Shinichi

    2017-06-22

    Direct and rapid trace-level gas analysis is highly needed in various fields such as safety and security, quality control, food analysis, and forensic medicine. In many cases, the real samples are bulky and are not accessible to the space-limited ion source of the mass spectrometer. In order to circumvent this problem, we developed an airtight atmospheric-pressure chemical ionization (APCI) ion source equipped with a flexible 1-m-long, 2-mm-i.d. PTFE sniffing tube. The ambient air bearing sample gas was sucked into the heated PTFE tube (130 °C) and was transported to the air-tight ion source without using any extra pumping system or a Venturi device. Analytes were ionized by an ac corona discharge located at 1.5 mm from the inlet of the mass spectrometer. By using the airtight ion source, all the ionized gas in the ion source was introduced into the vacuum of the mass spectrometer via only the evacuation of the mass spectrometer (1.6 l min -1 ). Sub-pg limits of detection were obtained for carbaryl and trinitrotoluene. Owing to its flexibility and high sensitivity, the sniffing tube coupled with a mass spectrometer can be used as the stethoscope for the high-sensitive gas analysis. The experimental results obtained for drugs, hydrogen peroxide and small alkanes were discussed by DFT calculations. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Sound propagation in street canyons: comparison between diffusely and geometrically reflecting boundaries

    PubMed

    Kang

    2000-03-01

    This paper systematically compares the sound fields in street canyons with diffusely and geometrically reflecting boundaries. For diffuse boundaries, a radiosity-based theoretical/computer model has been developed. For geometrical boundaries, the image source method has been used. Computations using the models show that there are considerable differences between the sound fields resulting from the two kinds of boundaries. By replacing diffuse boundaries with geometrical boundaries, the sound attenuation along the length becomes significantly less; the RT30 is considerably longer; and the extra attenuation caused by air or vegetation absorption is reduced. There are also some similarities between the sound fields under the two boundary conditions. For example, in both cases the sound attenuation along the length with a given amount of absorption is the highest if the absorbers are arranged on one boundary and the lowest if they are evenly distributed on all boundaries. Overall, the results suggest that, from the viewpoint of urban noise reduction, it is better to design the street boundaries as diffusely reflective rather than acoustically smooth.

  18. Delay in convection in nocturnal boundary layer due to aerosol-induced cooling

    NASA Astrophysics Data System (ADS)

    Singh, Dhiraj Kumar; Ponnulakshmi, V. K.; Subramanian, G.; Sreenivas, K. R.

    2012-11-01

    Heat transfer processes in the nocturnal boundary layer (NBL) influence the surface energy budget, and play an important role in many micro-meteorological processes including the formation of inversion layers, radiation fog, and in the control of air-quality near the ground. Under calm clear-sky conditions, radiation dominates over other transport processes, and as a result, the air layers just above ground cool the fastest after sunset. This leads to an anomalous post-sunset temperature profile characterized by a minimum a few decimeters above ground (Lifted temperature minimum). We have designed a laboratory experimental setup to simulate LTM, involving an enclosed layer of ambient air, and wherein the boundary condition for radiation is decoupled from those for conduction and convection. The results from experiments involving both ambient and filtered air indicate that the high cooling rates observed are due to the presence of aerosols. Calculated Rayleigh number of LTM-type profiles is of the order 105-107 in the field and of order 103-105 in the laboratory. In the LTM region, there is convective motion when the Rayleigh number is greater than 104 rather than the critical Rayleigh number (Rac = 1709). The diameter of convection rolls is a function of height of minimum of LTM-type profiles. The results obtained should help in the parameterization of transport process in the nocturnal boundary layer, and highlight the need to accounting the effects of aerosols and ground emissivity in climate models.

  19. On the role of grain boundary character distribution in grain growth of Al-Mg alloys

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Matsumoto, K.; Shibayanagi, T.; Umakoshi, Y.

    1997-02-01

    Grain growth behavior of recrystallized Al-Mg alloys containing 0.3 and 2.7 mass% Mg was investigated, focusing on the interconnection between development of the texture and grain boundary character distribution. An Al-0.3 mass% Mg alloy showed two stages in the change of microstructure during grain growth: the frequency of cube oriented grains and the {Sigma}1 boundary significantly increased at an early stage and then decreased. In the second stage a small amount of isolated large grains with the non-cube component grew and consumed the surrounding cube grains. In contrast, the frequency of cube oriented grains and the grain boundary character distributionmore » showed no significant change during grain growth of Al-2.7 mass% Mg. Small clusters composed of several cube grains containing {Sigma}1 boundaries were formed and their spatial distribution played an important role in the change of microstructure during grain growth. The effect of the spatial distribution on the grain growth behavior was discussed considering the energy balance at triple junctions of grain boundaries.« less

  20. Boundary conditions in tunneling via quantum hydrodynamics

    NASA Technical Reports Server (NTRS)

    Nassar, Antonio B.

    1993-01-01

    Via the hydrodynamical formulation of quantum mechanics, an approach to the problem of tunneling through sharp-edged potential barriers is developed. Above all, it is shown how more general boundary conditions follow from the continuity of mass, momentum, and energy.

  1. A Comparison of Two Methods for Initiating Air Mass Back Trajectories

    NASA Astrophysics Data System (ADS)

    Putman, A.; Posmentier, E. S.; Faiia, A. M.; Sonder, L. J.; Feng, X.

    2014-12-01

    Lagrangian air mass tracking programs in back cast mode are a powerful tool for estimating the water vapor source of precipitation events. The altitudes above the precipitation site where particle's back trajectories begin influences the source estimation. We assume that precipitation comes from water vapor in condensing regions of the air column, so particles are placed in proportion to an estimated condensation profile. We compare two methods for estimating where condensation occurs and the resulting evaporation sites for 63 events at Barrow, AK. The first method (M1) uses measurements from a 35 GHz vertically resolved cloud radar (MMCR), and algorithms developed by Zhao and Garrett1 to calculate precipitation rate. The second method (M2) uses the Global Data Assimilation System reanalysis data in a lofting model. We assess how accurately M2, developed for global coverage, will perform in absence of direct cloud observations. Results from the two methods are statistically similar. The mean particle height estimated by M2 is, on average, 695 m (s.d. = 1800 m) higher than M1. The corresponding average vapor source estimated by M2 is 1.5⁰ (s.d. = 5.4⁰) south of M1. In addition, vapor sources for M2 relative to M1 have ocean surface temperatures averaging 1.1⁰C (s.d. = 3.5⁰C) warmer, and reported ocean surface relative humidities 0.31% (s.d. = 6.1%) drier. All biases except the latter are statistically significant (p = 0.02 for each). Results were skewed by events where M2 estimated very high altitudes of condensation. When M2 produced an average particle height less than 5000 m (89% of events), M2 estimated mean particle heights 76 m (s.d. = 741 m) higher than M1, corresponding to a vapor source 0.54⁰ (s.d. = 4.2⁰) south of M1. The ocean surface at the vapor source was an average of 0.35⁰C (s.d. = 2.35⁰C) warmer and ocean surface relative humidities were 0.02% (s.d. = 5.5%) wetter. None of the biases was statistically significant. If the vapor source

  2. Self-organized classification of boundary layer meteorology and associated characteristics of air quality in Beijing

    NASA Astrophysics Data System (ADS)

    Liao, Zhiheng; Sun, Jiaren; Yao, Jialin; Liu, Li; Li, Haowen; Liu, Jian; Xie, Jielan; Wu, Dui; Fan, Shaojia

    2018-05-01

    Self-organizing maps (SOMs; a feature-extracting technique based on an unsupervised machine learning algorithm) are used to classify atmospheric boundary layer (ABL) meteorology over Beijing through detecting topological relationships among the 5-year (2013-2017) radiosonde-based virtual potential temperature profiles. The classified ABL types are then examined in relation to near-surface pollutant concentrations to understand the modulation effects of the changing ABL meteorology on Beijing's air quality. Nine ABL types (i.e., SOM nodes) are obtained through the SOM classification technique, and each is characterized by distinct dynamic and thermodynamic conditions. In general, the self-organized ABL types are able to distinguish between high and low loadings of near-surface pollutants. The average concentrations of PM2.5, NO2 and CO dramatically increased from the near neutral (i.e., Node 1) to strong stable conditions (i.e., Node 9) during all seasons except for summer. Since extremely strong stability can isolate the near-surface observations from the influence of elevated SO2 pollution layers, the highest average SO2 concentrations are typically observed in Node 3 (a layer with strong stability in the upper ABL) rather than Node 9. In contrast, near-surface O3 shows an opposite dependence on atmospheric stability, with the lowest average concentration in Node 9. Analysis of three typical pollution months (i.e., January 2013, December 2015 and December 2016) suggests that the ABL types are the primary drivers of day-to-day variations in Beijing's air quality. Assuming a fixed relationship between ABL type and PM2.5 loading for different years, the relative (absolute) contributions of the ABL anomaly to elevated PM2.5 levels are estimated to be 58.3 % (44.4 µg m-3) in January 2013, 46.4 % (22.2 µg m-3) in December 2015 and 73.3 % (34.6 µg m-3) in December 2016.

  3. The inner core thermodynamics of the tropical cyclone boundary layer

    NASA Astrophysics Data System (ADS)

    Williams, Gabriel J.

    2016-10-01

    Although considerable progress has been made in understanding the inner-core dynamics of the tropical cyclone boundary layer (TCBL), our knowledge of the inner-core thermodynamics of the TCBL remains limited. In this study, the inner-core budgets of potential temperature (θ), specific humidity ( q), and reversible equivalent potential temperature (θ _e) are examined using a high-resolution multilevel boundary layer model. The potential temperature budgets show that the heat energy is dominated by latent heat release in the eyewall, evaporative cooling along the outer edge of the eyewall, and upward surface fluxes of sensible and latent heat from the underlying warm ocean. It is shown that the vertical θ advection overcompensates the sum of radial advective warming from the boundary layer outflow jet and latent heating for the development of cooling in the eyewall within the TCBL. The moisture budgets show the dominant upward transport of moisture in the eyewall updrafts, partly by the boundary-layer outflow jet from the bottom eye region, so that the eyewall remains nearly saturated. The θ _e budgets reveal that the TCBL is maintained thermodynamically by the upward surface flux of higher-θ _e air from the underlying warm ocean, the radial transport of low-θ _e air from the outer regions of the TCBL, and the dry adiabatic cooling associated by eyewall updrafts. These results underscore the significance of vertical motion and the location of the boundary layer outflow jet in maintaining the inner core thermal structure of the TCBL.

  4. Heat transfer optimization for air-mist cooling between a stack of parallel plates

    NASA Astrophysics Data System (ADS)

    Issa, Roy J.

    2010-06-01

    A theoretical model is developed to predict the upper limit heat transfer between a stack of parallel plates subject to multiphase cooling by air-mist flow. The model predicts the optimal separation distance between the plates based on the development of the boundary layers for small and large separation distances, and for dilute mist conditions. Simulation results show the optimal separation distance to be strongly dependent on the liquid-to-air mass flow rate loading ratio, and reach a limit for a critical loading. For these dilute spray conditions, complete evaporation of the droplets takes place. Simulation results also show the optimal separation distance decreases with the increase in the mist flow rate. The proposed theoretical model shall lead to a better understanding of the design of fins spacing in heat exchangers where multiphase spray cooling is used.

  5. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 2

    NASA Technical Reports Server (NTRS)

    Hovel, H.; Woodall, J. M.

    1976-01-01

    Crystal growth procedures, fabrication techniques, and theoretical analysis were developed in order to make GaAlAs-GaAs solar cell structures which exhibit high performance at air mass 0 illumination and high temperature conditions.

  6. Ring waves as a mass transport mechanism in air-driven core-annular flows.

    PubMed

    Camassa, Roberto; Forest, M Gregory; Lee, Long; Ogrosky, H Reed; Olander, Jeffrey

    2012-12-01

    Air-driven core-annular fluid flows occur in many situations, from lung airways to engineering applications. Here we study, experimentally and theoretically, flows where a viscous liquid film lining the inside of a tube is forced upwards against gravity by turbulent airflow up the center of the tube. We present results on the thickness and mean speed of the film and properties of the interfacial waves that develop from an instability of the air-liquid interface. We derive a long-wave asymptotic model and compare properties of its solutions with those of the experiments. Traveling wave solutions of this long-wave model exhibit evidence of different mass transport regimes: Past a certain threshold, sufficiently large-amplitude waves begin to trap cores of fluid which propagate upward at wave speeds. This theoretical result is then confirmed by a second set of experiments that show evidence of ring waves of annular fluid propagating over the underlying creeping flow. By tuning the parameters of the experiments, the strength of this phenomenon can be adjusted in a way that is predicted qualitatively by the model.

  7. Squeeze-Film Air Damping of a Five-Axis Electrostatic Bearing for Rotary Micromotors.

    PubMed

    Wang, Shunyue; Han, Fengtian; Sun, Boqian; Li, Haixia

    2017-05-13

    Air-film damping, which dominates over other losses, plays a significant role in the dynamic response of many micro-fabricated devices with a movable mass suspended by various bearing mechanisms. Modeling the damping characteristics accurately will be greatly helpful to the bearing design, control, and test in various micromotor devices. This paper presents the simulated and experimental squeeze-film air damping results of an electrostatic bearing for use in a rotary high-speed micromotor. It is shown that the boundary condition to solve the three-dimensional Reynolds equation, which governs the squeeze-film damping in the air gap between the rotor and its surrounding stator sealed in a three-layer evacuated cavity, behaves with strong cross-axis coupling characteristics. To accurately characterize the damping effect, a set of multiphysics finite-element simulations are performed by computing both the rotor velocity and the distribution of the viscous damping force acting on the rotor. The damping characteristics varying with several key structure parameters are simulated and discussed to optimize the device structure for desirable rotor dynamics. An electrical measurement method is also proposed and applied to validate the numerical results of the damping coefficients experimentally. Given that the frequency response of the electric bearing is critically dependent on the damping coefficients at atmospheric pressure, a solution to the air-film damping measurement problem is presented by taking approximate curve fitting of multi-axis experimental frequency responses. The measured squeeze-film damping coefficients for the five-axis electric bearing agrees well with the numerical solutions. This indicates that numerical multiphysics simulation is an effective method to accurately examine the air-film damping effect for complex device geometry and arbitrary boundary condition. The accurate damping coefficients obtained by FEM simulation will greatly simplify the design

  8. Flow unsteadiness effects on boundary layers

    NASA Technical Reports Server (NTRS)

    Murthy, Sreedhara V.

    1989-01-01

    The development of boundary layers at high subsonic speeds in the presence of either mass flux fluctuations or acoustic disturbances (the two most important parameters in the unsteadiness environment affecting the aerodynamics of a flight vehicle) was investigated. A high quality database for generating detailed information concerning free-stream flow unsteadiness effects on boundary layer growth and transition in high subsonic and transonic speeds is described. The database will be generated with a two-pronged approach: (1) from a detailed review of existing literature on research and wind tunnel calibration database, and (2) from detailed tests in the Boundary Layer Apparatus for Subsonic and Transonic flow Affected by Noise Environment (BLASTANE). Special instrumentation, including hot wire anemometry, the buried wire gage technique, and laser velocimetry were used to obtain skin friction and turbulent shear stress data along the entire boundary layer for various free stream noise levels, turbulence content, and pressure gradients. This database will be useful for improving the correction methodology of applying wind tunnel test data to flight predictions and will be helpful for making improvements in turbulence modeling laws.

  9. Enhanced Performance of non-PGM Catalysts in Air Operated PEM-Fuel Cells

    DOE PAGES

    Barkholtz, Heather M.; Chong, Lina; Kaiser, Zachary Brian; ...

    2016-10-13

    Here a non-platinum group metal (non-PGM) oxygen reduction catalyst was prepared from “support-free” zeolitic imidazolate framework (ZIF) precursor and tested in the proton exchange membrane fuel cell with air as the cathode feed. The iron nitrogen and carbon composite (FeeNeC) based catalyst has high specific surface area decorated uniformly with active sites, which redefines the triple phase boundary (TPB) and requires re-optimization of the cathodic membrane electrode fabrication to ensure efficient mass and charge transports to the catalyst surface. This study reports an effort in optimizing catalytic ink formulation for the membrane electrode preparation and its impact to the fuelmore » cell performance under air. Through optimization, the fuel cell areal current density as high as 115.2 mA/cm 2 at 0.8 V or 147.6 mA/cm 2 at 0.8 V iR-free has been achieved under one bar air. We also investigated impacts on fuel cell internal impedance and the water formation.« less

  10. Analytical and experimental investigation on transmission loss of clamped double panels: implication of boundary effects.

    PubMed

    Xin, F X; Lu, T J

    2009-03-01

    The air-borne sound insulation performance of a rectangular double-panel partition clamp mounted on an infinite acoustic rigid baffle is investigated both analytically and experimentally and compared with that of a simply supported one. With the clamped (or simply supported) boundary accounted for by using the method of modal function, a double series solution for the sound transmission loss (STL) of the structure is obtained by employing the weighted residual (Galerkin) method. Experimental measurements with Al double-panel partitions having air cavity are subsequently carried out to validate the theoretical model for both types of the boundary condition, and good overall agreement is achieved. A consistency check of the two different models (based separately on clamped modal function and simply supported modal function) is performed by extending the panel dimensions to infinite where no boundaries exist. The significant discrepancies between the two different boundary conditions are demonstrated in terms of the STL versus frequency plots as well as the panel deflection mode shapes.

  11. Inertia-Controlled Twinning in Ni-Mn-Ga Actuators: A Discrete Twin-Boundary Dynamics Study

    NASA Astrophysics Data System (ADS)

    Faran, Eilon; Riccardi, Leonardo; Shilo, Doron

    2017-09-01

    A discrete twin-boundary modeling approach is applied for simulating the dynamic magnetomechanical response of a Ni-Mn-Ga actuator over a wide frequency range. The model is based on experimentally measured kinetic relation of individual twin boundaries and takes into account inertial forces due to acceleration of the actuator's mass. The calculated results show good agreement with experimental measurements performed on a specially designed Ni-Mn-Ga linear spring-mass actuator. In addition, the simulation reveals several new effects that have not been considered before and can be applied to the design of improved actuators. It is identified that the demagnetization effect plays a role of an "effective spring" and results in a resonance-type response. The effects of the actuator's mass and the twin-boundary density on the resonance response and the actuator performance are explored numerically. In particular, it is shown that mass-inertia poses an inherent upper limit over the actuator's bandwidth, which is approximately constant and equals to about 200 Hz.

  12. Cooler winters as a possible cause of mass extinctions at the Eocene/Oligocene boundary

    NASA Astrophysics Data System (ADS)

    Ivany, Linda C.; Patterson, William P.; Lohmann, Kyger C.

    2000-10-01

    The Eocene/Oligocene boundary, at about 33.7Myr ago, marks one of the largest extinctions of marine invertebrates in the Cenozoic period. For example, turnover of mollusc species in the US Gulf coastal plain was over 90% at this time. A temperature change across this boundary-from warm Eocene climates to cooler conditions in the Oligocene-has been suggested as a cause of this extinction event, but climate reconstructions have not provided support for this hypothesis. Here we report stable oxygen isotope measurements of aragonite in fish otoliths-ear stones-collected across the Eocene/Oligocene boundary. Palaeotemperatures reconstructed from mean otolith oxygen isotope values show little change through this interval, in agreement with previous studies. From incremental microsampling of otoliths, however, we can resolve the seasonal variation in temperature, recorded as the otoliths continue to accrete new material over the life of the fish. These seasonal data suggest that winters became about 4°C colder across the Eocene/Oligocene boundary. We suggest that temperature variability, rather than change in mean annual temperature, helped to cause faunal turnover during this transition.

  13. Cross-scale modelling of transpiration from stomata via the leaf boundary layer

    PubMed Central

    Defraeye, Thijs; Derome, Dominique; Verboven, Pieter; Carmeliet, Jan; Nicolai, Bart

    2014-01-01

    Background and Aims Leaf transpiration is a key parameter for understanding land surface–climate interactions, plant stress and plant structure–function relationships. Transpiration takes place at the microscale level, namely via stomata that are distributed discretely over the leaf surface with a very low surface coverage (approx. 0·2–5 %). The present study aims to shed more light on the dependency of the leaf boundary-layer conductance (BLC) on stomatal surface coverage and air speed. Methods An innovative three-dimensional cross-scale modelling approach was applied to investigate convective mass transport from leaves, using computational fluid dynamics. The gap between stomatal and leaf scale was bridged by including all these scales in the same computational model (10−5–10−1 m), which implies explicitly modelling individual stomata. Key Results BLC was strongly dependent on stomatal surface coverage and air speed. Leaf BLC at low surface coverage ratios (CR), typical for stomata, was still relatively high, compared with BLC of a fully wet leaf (hypothetical CR of 100 %). Nevertheless, these conventional BLCs (CR of 100 %), as obtained from experiments or simulations on leaf models, were found to overpredict the convective exchange. In addition, small variations in stomatal CR were found to result in large variations in BLCs. Furthermore, stomata of a certain size exhibited a higher mass transfer rate at lower CRs. Conclusions The proposed cross-scale modelling approach allows us to increase our understanding of transpiration at the sub-leaf level as well as the boundary-layer microclimate in a way currently not feasible experimentally. The influence of stomatal size, aperture and surface density, and also flow-field parameters can be studied using the model, and prospects for further improvement of the model are presented. An important conclusion of the study is that existing measures of conductances (e.g. from artificial leaves) can be

  14. Cross-scale modelling of transpiration from stomata via the leaf boundary layer.

    PubMed

    Defraeye, Thijs; Derome, Dominique; Verboven, Pieter; Carmeliet, Jan; Nicolai, Bart

    2014-09-01

    Leaf transpiration is a key parameter for understanding land surface-climate interactions, plant stress and plant structure–function relationships. Transpiration takes place at the microscale level, namely via stomata that are distributed discretely over the leaf surface with a very low surface coverage (approx. 0·2-5%). The present study aims to shed more light on the dependency of the leaf boundary-layer conductance (BLC) on stomatal surface coverage and air speed. An innovative three-dimensional cross-scale modelling approach was applied to investigate convective mass transport from leaves, using computational fluid dynamics. The gap between stomatal and leaf scale was bridged by including all these scales in the same computational model (10⁻⁵-10⁻¹ m), which implies explicitly modelling individual stomata. BLC was strongly dependent on stomatal surface coverage and air speed. Leaf BLC at low surface coverage ratios (CR), typical for stomata, was still relatively high, compared with BLC of a fully wet leaf (hypothetical CR of 100%). Nevertheless, these conventional BLCs (CR of 100%), as obtained from experiments or simulations on leaf models, were found to overpredict the convective exchange. In addition, small variations in stomatal CR were found to result in large variations in BLCs. Furthermore, stomata of a certain size exhibited a higher mass transfer rate at lower CRs. The proposed cross-scale modelling approach allows us to increase our understanding of transpiration at the sub-leaf level as well as the boundary-layer microclimate in a way currently not feasible experimentally. The influence of stomatal size, aperture and surface density, and also flow-field parameters can be studied using the model, and prospects for further improvement of the model are presented. An important conclusion of the study is that existing measures of conductances (e.g. from artificial leaves) can be significantly erroneous because they do not account for microscopic

  15. Interrelationships Between Walkability, Air Pollution, Greenness, and Body Mass Index.

    PubMed

    James, Peter; Kioumourtzoglou, Marianthi-Anna; Hart, Jaime E; Banay, Rachel F; Kloog, Itai; Laden, Francine

    2017-11-01

    Recent studies have linked urban environmental factors and body mass index (BMI); however, such factors are often examined in isolation, ignoring correlations across exposures. Using data on Nurses' Health Study participants living in the Northeastern United States in 2006, we estimated associations between neighborhood walkability (a composite of population density, street connectivity, and business access), greenness (from satellite imagery), and ambient air pollution (from satellite-based spatiotemporally resolved PM2.5 predictions and weighted monthly average concentrations of NO2 from up to five nearest monitors) and self-reported BMI using generalized additive models, allowing for deviations from linearity using penalized splines. Among 23,435 women aged 60-87 years, we observed nonlinear associations between walkability and BMI and between PM2.5 and BMI in single-exposure models adjusted for age, race, and individual- and area-level socioeconomic status. When modeling all exposures simultaneously, only the association between walkability and BMI remained nonlinear and nonmonotonic. Increasing walkability was associated with increasing BMI at lower levels of walkability (walkability index <1.8), while increasing walkability was linked to lower BMI in areas of higher walkability (walkability index >1.8). A 10 percentile increase in walkability, right above 1.8 was associated with a 0.84% decrease in log BMI. The relationship between walkability and BMI existed only among younger participants (<71 years old). Neighborhood walkability was nonlinearly linked to lower BMI independent of air pollution and greenness. Our findings highlight the importance of accounting for nonlinear confounding by interrelated urban environmental factors when investigating associations between the environment and BMI.

  16. Time scales of critical events around the Cretaceous-Paleogene boundary.

    PubMed

    Renne, Paul R; Deino, Alan L; Hilgen, Frederik J; Kuiper, Klaudia F; Mark, Darren F; Mitchell, William S; Morgan, Leah E; Mundil, Roland; Smit, Jan

    2013-02-08

    Mass extinctions manifest in Earth's geologic record were turning points in biotic evolution. We present (40)Ar/(39)Ar data that establish synchrony between the Cretaceous-Paleogene boundary and associated mass extinctions with the Chicxulub bolide impact to within 32,000 years. Perturbation of the atmospheric carbon cycle at the boundary likely lasted less than 5000 years, exhibiting a recovery time scale two to three orders of magnitude shorter than that of the major ocean basins. Low-diversity mammalian fauna in the western Williston Basin persisted for as little as 20,000 years after the impact. The Chicxulub impact likely triggered a state shift of ecosystems already under near-critical stress.

  17. Observations of marine decoupled boundary layer during the ICOS campaign at the GAW Mace Head station, Ireland.

    NASA Astrophysics Data System (ADS)

    Milroy, Conor; Martucci, Giovanni; O'Dowd, Colin

    2010-05-01

    The planetary boundary layer (PBL) top height detections have been retrieved by two ceilometers (Vaisala CL31 and Jenoptik CHM15K) and a microwave radiometer (RPG-HATPRO) based at the Mace Head Research station, Ireland, from the 8th to the 28th of June 2009 during the ICOS Mace Head campaign. Characteristic of this region, with warm waters, the marine boundary layer is typically 2-layered with a surface mixed layer (SML) and a decoupled residual or convective layer (DRCL), above which is the free troposphere (Kunz et al. 2002). The PBL data have been analyzed using a newly developed Temporal Height-Tracking (THT) algorithm (Martucci et al., 2010) for automatic detection of the independent SML and DRCL tops. Daily and weekly averages of the PBL data have been performed to smooth out the short term variability and assess the dependence of the PBL depth on different air masses advected over the Mace Head station. Moreover, a qualitative comparison between the ceilometer and radiometer PBL top detected values has been done to assess their consistency.

  18. Contrasting sea-ice and open-water boundary layers during melt and freeze-up seasons: Some result from the Arctic Clouds in Summer Experiment.

    NASA Astrophysics Data System (ADS)

    Tjernström, Michael; Sotiropoulou, Georgia; Sedlar, Joseph; Achtert, Peggy; Brooks, Barbara; Brooks, Ian; Persson, Ola; Prytherch, John; Salsbury, Dominic; Shupe, Matthew; Johnston, Paul; Wolfe, Dan

    2016-04-01

    With more open water present in the Arctic summer, an understanding of atmospheric processes over open-water and sea-ice surfaces as summer turns into autumn and ice starts forming becomes increasingly important. The Arctic Clouds in Summer Experiment (ACSE) was conducted in a mix of open water and sea ice in the eastern Arctic along the Siberian shelf during late summer and early autumn 2014, providing detailed observations of the seasonal transition, from melt to freeze. Measurements were taken over both ice-free and ice-covered surfaces, offering an insight to the role of the surface state in shaping the lower troposphere and the boundary-layer conditions as summer turned into autumn. During summer, strong surface inversions persisted over sea ice, while well-mixed boundary layers capped by elevated inversions were frequent over open-water. The former were often associated with advection of warm air from adjacent open-water or land surfaces, whereas the latter were due to a positive buoyancy flux from the warm ocean surface. Fog and stratus clouds often persisted over the ice, whereas low-level liquid-water clouds developed over open water. These differences largely disappeared in autumn, when mixed-phase clouds capped by elevated inversions dominated in both ice-free and ice-covered conditions. Low-level-jets occurred ~20-25% of the time in both seasons. The observations indicate that these jets were typically initiated at air-mass boundaries or along the ice edge in autumn, while in summer they appeared to be inertial oscillations initiated by partial frictional decoupling as warm air was advected in over the sea ice. The start of the autumn season was related to an abrupt change in atmospheric conditions, rather than to the gradual change in solar radiation. The autumn onset appeared as a rapid cooling of the whole atmosphere and the freeze up followed as the warm surface lost heat to the atmosphere. While the surface type had a pronounced impact on boundary

  19. Direct measurements and analysis of skin friction and cooling downstream of multiple flush-slot injection into a turbulent Mach 6 boundary layer

    NASA Technical Reports Server (NTRS)

    Howard, F. G.; Strokowski, A. J.

    1978-01-01

    Experiments were conducted to determine the reduction in surface skin friction and the effectiveness of surface cooling downstream of one to four successive flush slots injecting cold air at an angle of 10 deg into a turbulent Mach 6 boundary layer. Data were obtained by direct measurement of surface shear and equilibrium temperatures, respectively. Increasing the number of slots decreased the skin friction, but the incremental improvement in skin-friction reduction decreased as the number of slots was increased. Cooling effectiveness was found to improve, for a given total mass injection, as the number of slots was increased from one to four. Comparison with previously reported step-slot data, however, indicated that step slots with tangential injection are more effective for both reducing skin friction and cooling than the present flush-slot configuration. Finite-difference predictions are in reasonable agreement with skin-friction data and with boundary-layer profile data.

  20. X-33 Hypersonic Boundary Layer Transition

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; Horvath, Thomas J.; Hollis, Brian R.; Thompson, Richard A.; Hamilton, H. Harris, II

    1999-01-01

    Boundary layer and aeroheating characteristics of several X-33 configurations have been experimentally examined in the Langley 20-Inch Mach 6 Air Tunnel. Global surface heat transfer distributions, surface streamline patterns, and shock shapes were measured on 0.013-scale models at Mach 6 in air. Parametric variations include angles-of-attack of 20-deg, 30-deg, and 40-deg; Reynolds numbers based on model length of 0.9 to 6.6 million; and body-flap deflections of 0, 10 and 20-deg. The effects of discrete and distributed roughness elements on boundary layer transition, which included trip height, size, location, and distribution, both on and off the windward centerline, were investigated. The discrete roughness results on centerline were used to provide a transition correlation for the X-33 flight vehicle that was applicable across the range of reentry angles of attack. The attachment line discrete roughness results were shown to be consistent with the centerline results, as no increased sensitivity to roughness along the attachment line was identified. The effect of bowed panels was qualitatively shown to be less effective than the discrete trips; however, the distributed nature of the bowed panels affected a larger percent of the aft-body windward surface than a single discrete trip.

  1. Impact of air temperature on physically-based maximum precipitation estimation through change in moisture holding capacity of air

    NASA Astrophysics Data System (ADS)

    Ishida, K.; Ohara, N.; Kavvas, M. L.; Chen, Z. Q.; Anderson, M. L.

    2018-01-01

    Impact of air temperature on the Maximum Precipitation (MP) estimation through change in moisture holding capacity of air was investigated. A series of previous studies have estimated the MP of 72-h basin-average precipitation over the American River watershed (ARW) in Northern California by means of the Maximum Precipitation (MP) estimation approach, which utilizes a physically-based regional atmospheric model. For the MP estimation, they have selected 61 severe storm events for the ARW, and have maximized them by means of the atmospheric boundary condition shifting (ABCS) and relative humidity maximization (RHM) methods. This study conducted two types of numerical experiments in addition to the MP estimation by the previous studies. First, the air temperature on the entire lateral boundaries of the outer model domain was increased uniformly by 0.0-8.0 °C with 0.5 °C increments for the two severest maximized historical storm events in addition to application of the ABCS + RHM method to investigate the sensitivity of the basin-average precipitation over the ARW to air temperature rise. In this investigation, a monotonous increase was found in the maximum 72-h basin-average precipitation over the ARW with air temperature rise for both of the storm events. The second numerical experiment used specific amounts of air temperature rise that is assumed to happen under future climate change conditions. Air temperature was increased by those specified amounts uniformly on the entire lateral boundaries in addition to application of the ABCS + RHM method to investigate the impact of air temperature on the MP estimate over the ARW under changing climate. The results in the second numerical experiment show that temperature increases in the future climate may amplify the MP estimate over the ARW. The MP estimate may increase by 14.6% in the middle of the 21st century and by 27.3% in the end of the 21st century compared to the historical period.

  2. Determination of trichloroanisole and trichlorophenol in wineries' ambient air by passive sampling and thermal desorption-gas chromatography coupled to tandem mass spectrometry.

    PubMed

    Camino-Sánchez, F J; Bermúdez-Peinado, R; Zafra-Gómez, A; Ruíz-García, J; Vílchez-Quero, J L

    2015-02-06

    The present paper describes the calibration of selected passive samplers used in the quantitation of trichlorophenol and trichloroanisole in wineries' ambient air, by calculating the corresponding sampling rates. The method is based on passive sampling with sorbent tubes and involves thermal desorption-gas chromatography-triple quadrupole mass spectrometry analysis. Three commercially available sorbents were tested using sampling cartridges with a radial design instead of axial ones. The best results were found for Tenax TA™. Sampling rates (R-values) for the selected sorbents were determined. Passive sampling was also used for accurately determining the amount of compounds present in the air. Adequate correlation coefficients between the mass of the target analytes and exposure time were obtained. The proposed validated method is a useful tool for the early detection of trichloroanisole and its precursor trichlorophenol in wineries' ambient air while avoiding contamination of wine or winery facilities. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Planetary Boundary Layer from AERI and MPL

    DOE Data Explorer

    Sawyer, Virginia

    2014-02-13

    The distribution and transport of aerosol emitted to the lower troposphere is governed by the height of the planetary boundary layer (PBL), which limits the dilution of pollutants and influences boundary-layer convection. Because radiative heating and cooling of the surface strongly affect the PBL top height, it follows diurnal and seasonal cycles and may vary by hundreds of meters over a 24-hour period. The cap the PBL imposes on low-level aerosol transport makes aerosol concentration an effective proxy for PBL height: the top of the PBL is marked by a rapid transition from polluted, well-mixed boundary-layer air to the cleaner, more stratified free troposphere. Micropulse lidar (MPL) can provide much higher temporal resolution than radiosonde and better vertical resolution than infrared spectrometer (AERI), but PBL heights from all three instruments at the ARM SGP site are compared to one another for validation. If there is agreement among them, the higher-resolution remote sensing-derived PBL heights can accurately fill in the gaps left by the low frequency of radiosonde launches, and thus improve model parameterizations and our understanding of boundary-layer processes.

  4. Extreme Vertical Gusts in the Atmospheric Boundary Layer

    DTIC Science & Technology

    2015-07-01

    significant effect on the statistics of the rare, extreme gusts. In the lowest 5,000 ft, boundary layer effects make small to moderate vertical...4 2.4 Effects of Gust Shape ............................................................................................... 5... Definitions Adiabatic Lapse Rate The rate of change of temperature with altitude that would occur if a parcel of air was transported sufficiently

  5. Inverse boundary-layer theory and comparison with experiment

    NASA Technical Reports Server (NTRS)

    Carter, J. E.

    1978-01-01

    Inverse boundary layer computational procedures, which permit nonsingular solutions at separation and reattachment, are presented. In the first technique, which is for incompressible flow, the displacement thickness is prescribed; in the second technique, for compressible flow, a perturbation mass flow is the prescribed condition. The pressure is deduced implicitly along with the solution in each of these techniques. Laminar and turbulent computations, which are typical of separated flow, are presented and comparisons are made with experimental data. In both inverse procedures, finite difference techniques are used along with Newton iteration. The resulting procedure is no more complicated than conventional boundary layer computations. These separated boundary layer techniques appear to be well suited for complete viscous-inviscid interaction computations.

  6. Internal loading of an inhomogeneous compressible Earth with phase boundaries

    NASA Technical Reports Server (NTRS)

    Defraigne, P.; Dehant, V.; Wahr, J. M.

    1996-01-01

    The geoid and the boundary topography caused by mass loads inside the earth were estimated. It is shown that the estimates are affected by compressibility, by a radially varying density distribution, and by the presence of phase boundaries with density discontinuities. The geoid predicted in the chemical boundary case is 30 to 40 percent smaller than that predicted in the phase case. The effects of compressibility and radially varying density are likely to be small. The inner core-outer core topography for loading inside the mantle and for loading inside the inner core were computed.

  7. Shooting method for solution of boundary-layer flows with massive blowing

    NASA Technical Reports Server (NTRS)

    Liu, T.-M.; Nachtsheim, P. R.

    1973-01-01

    A modified, bidirectional shooting method is presented for solving boundary-layer equations under conditions of massive blowing. Unlike the conventional shooting method, which is unstable when the blowing rate increases, the proposed method avoids the unstable direction and is capable of solving complex boundary-layer problems involving mass and energy balance on the surface.

  8. Fluorescence Visualization of Hypersonic Flow Past Triangular and Rectangular Boundary-layer Trips

    NASA Technical Reports Server (NTRS)

    Danehy, Paul M.; Garcia, A. P.; Borg, Stephen E.; Dyakonov, Artem A.; Berry, Scott A.; Inman, Jennifer A.; Alderfer, David W.

    2007-01-01

    Planar laser-induced fluorescence (PLIF) flow visualization has been used to investigate the hypersonic flow of air over surface protrusions that are sized to force laminar-to-turbulent boundary layer transition. These trips were selected to simulate protruding Space Shuttle Orbiter heat shield gap-filler material. Experiments were performed in the NASA Langley Research Center 31-Inch Mach 10 Air Wind Tunnel, which is an electrically-heated, blowdown facility. Two-mm high by 8-mm wide triangular and rectangular trips were attached to a flat plate and were oriented at an angle of 45 degrees with respect to the oncoming flow. Upstream of these trips, nitric oxide (NO) was seeded into the boundary layer. PLIF visualization of this NO allowed observation of both laminar and turbulent boundary layer flow downstream of the trips for varying flow conditions as the flat plate angle of attack was varied. By varying the angle of attack, the Mach number above the boundary layer was varied between 4.2 and 9.8, according to analytical oblique-shock calculations. Computational Fluid Dynamics (CFD) simulations of the flowfield with a laminar boundary layer were also performed to better understand the flow environment. The PLIF images of the tripped boundary layer flow were compared to a case with no trip for which the flow remained laminar over the entire angle-of-attack range studied. Qualitative agreement is found between the present observed transition measurements and a previous experimental roughness-induced transition database determined by other means, which is used by the shuttle return-to-flight program.

  9. Comparison of Methods for Determining Boundary Layer Edge Conditions for Transition Correlations

    NASA Technical Reports Server (NTRS)

    Liechty, Derek S.; Berry, Scott A.; Hollis, Brian R.; Horvath, Thomas J.

    2003-01-01

    Data previously obtained for the X-33 in the NASA Langley Research Center 20-Inch Mach 6 Air Tunnel have been reanalyzed to compare methods for determining boundary layer edge conditions for use in transition correlations. The experimental results were previously obtained utilizing the phosphor thermography technique to monitor the status of the boundary layer downstream of discrete roughness elements via global heat transfer images of the X-33 windward surface. A boundary layer transition correlation was previously developed for this data set using boundary layer edge conditions calculated using an inviscid/integral boundary layer approach. An algorithm was written in the present study to extract boundary layer edge quantities from higher fidelity viscous computational fluid dynamic solutions to develop transition correlations that account for viscous effects on vehicles of arbitrary complexity. The boundary layer transition correlation developed for the X-33 from the viscous solutions are compared to the previous boundary layer transition correlations. It is shown that the boundary layer edge conditions calculated using an inviscid/integral boundary layer approach are significantly different than those extracted from viscous computational fluid dynamic solutions. The present results demonstrate the differences obtained in correlating transition data using different computational methods.

  10. Porous and Microporous Honeycomb Composites as Potential Boundary-Layer Bleed Materials

    NASA Technical Reports Server (NTRS)

    Davis, D. O.; Willis, B. P.; Schoenenberger, M.

    1997-01-01

    Results of an experimental investigation are presented in which the use of porous and microporous honeycomb composite materials is evaluated as an alternate to perforated solid plates for boundary-layer bleed in supersonic aircraft inlets. The terms "porous" and "microporous," respectively, refer to bleed orifice diameters roughly equal to and much less than the displacement thickness of the approach boundary-layer. A Baseline porous solid plate, two porous honeycomb, and three microporous honeycomb configurations are evaluated. The performance of the plates is characterized by the flow coefficient and relative change in boundary-layer profile parameters across the bleed region. The tests were conducted at Mach numbers of 1.27 and 1.98. The results show the porous honeycomb is not as efficient at removing mass compared to the baseline. The microporous plates were about equal to the baseline with one plate demonstrating a significantly higher efficiency. The microporous plates produced significantly fuller boundary-layer profiles downstream of the bleed region for a given mass flow removal rate than either the baseline or the porous honeycomb plates.

  11. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

  12. Control of a shock wave-boundary layer interaction using localized arc filament plasma actuators

    NASA Astrophysics Data System (ADS)

    Webb, Nathan Joseph

    Supersonic flight is currently possible, but expensive. Inexpensive supersonic travel will require increased efficiency of high-speed air entrainment, an integral part of air-breathing propulsion systems. Although mixed compression inlet geometry can significantly improve entrainment efficiency, numerous Shock Wave-Boundary Layer Interactions (SWBLIs) are generated in this configuration. The boundary layer must therefore develop through multiple regions of adverse pressure gradient, causing it to thicken, and, in severe cases, separate. The associated increase in unsteadiness can have adverse effects on downstream engine hardware. The most severe consequence of these interactions is the increased aerodynamic blockage generated by the thickened boundary layer. If the increase is sufficient, it can choke the flow, causing inlet unstart, and resulting in a loss of thrust and high transient forces on the engine, airframe, and aircraft occupants. The potentially severe consequences associated with SWBLIs require flow control to ensure proper operation. Traditionally, boundary layer bleed has been used to control the interaction. Although this method is effective, it has inherent efficiency penalties. Localized Arc Filament Plasma Actuators (LAFPAs) are designed to generate perturbations for flow control. Natural flow instabilities act to amplify certain perturbations, allowing the LAFPAs to control the flow with minimal power input. LAFPAs also have the flexibility to maintain control over a variety of operating conditions. This work seeks to examine the effectiveness of LAFPAs as a separation control method for an oblique, impinging SWBLI. The low frequency unsteadiness in the reflected shock was thought to be the natural manifestation of a Kelvin-Helmholtz instability in the shear layer above the separation region. The LAFPAs were therefore placed upstream of the interaction to allow their perturbations to convect to the receptivity region (near the shear layer origin

  13. TURBULENCE PARAMETERS IMPACTING DISPERSION IN AN URBAN CONVECTIVE BOUNDARY LAYER

    EPA Science Inventory

    Turbulence measurements of the three dimensional wind components were collected by an instrumented research aircraft on 7 days in August 1976. These aircraft flights were conducted as part of the Regional Air Pollution Study (RAPS) urban boundary layer field program in St. Louis,...

  14. Wintertime Boundary Layer Structure in the Grand Canyon.

    NASA Astrophysics Data System (ADS)

    Whiteman, C. David; Zhong, Shiyuan; Bian, Xindi

    1999-08-01

    Wintertime temperature profiles in the Grand Canyon exhibit a neutral to isothermal stratification during both daytime and nighttime, with only rare instances of actual temperature inversions. The canyon warms during daytime and cools during nighttime more or less uniformly through the canyon's entire depth. This weak stability and temperature structure evolution differ from other Rocky Mountain valleys, which develop strong nocturnal inversions and exhibit convective and stable boundary layers that grow upward from the valley floor. Mechanisms that may be responsible for the different behavior of the Grand Canyon are discussed, including the possibility that the canyon atmosphere is frequently mixed to near-neutral stratification when cold air drains into the top of the canyon from the nearby snow-covered Kaibab Plateau. Another feature of canyon temperature profiles is the sharp inversions that often form near the canyon rims. These are generally produced when warm air is advected over the canyon in advance of passing synoptic-scale ridges.Wintertime winds in the main canyon are not classical diurnal along-valley wind systems. Rather, they are driven along the canyon axis by the horizontal synoptic-scale pressure gradient that is superimposed along the canyon's axis by passing synoptic-scale weather disturbances. They may thus bring winds into the canyon from either end at any time of day.The implications of the observed canyon boundary layer structure for air pollution dispersion are discussed.

  15. Oxidation behavior of grain boundary engineered alloy 690 in supercritical water environment

    NASA Astrophysics Data System (ADS)

    Xu, P.; Zhao, L. Y.; Sridharan, K.; Allen, T. R.

    2012-03-01

    Nickel-base alloy is an important structural material that is known for its exceptional high temperature oxidation resistance. Oxidation in this alloy at high temperatures occurs to a greater extent along the grain boundaries. Grain boundary engineering (GBE) was applied to modify the grain boundary characteristics of this alloy to affect its oxidation resistance. Specimens with both low level and high level cold works showed a high fraction of special grain boundaries, and were tested for supercritical water oxidation resistance at 500 °C and 24 MPa. Both GBE and as-received samples exhibited mass gain followed by mass loss during 10 weeks of exposure, but the normalized mass change was small and less than 0.12 mg/cm2. GBE samples showed better oxide layer retention compared to the as-received sample. XRD results indicate that nickel oxide, chromium oxide, and spinel oxide were the three main types of oxides that form on as-received and GBE alloy 690. Three distinct regions were identified on the oxidized surface: a flat region with oxide flakes aligning relatively parallel to the surface, a rough region with polygon-type oxide particles randomly distributed on the surface, and a region with aggregated oxide flakes perpendicular to the surface. The flat region of oxidation consisted of (1 1 1) orientated oxide spinel flakes formed on (1 1 1) oriented alloy 690 grains. The flat oxide region was thinner and showed better oxide adhesion compared to the rough region. Chromium oxidation was found only at random grain boundaries, leading to formation of thick Cr2O3 layer on the surface and chromium depletion underneath. None of this oxidation was found at low angle or special boundaries. The chromium oxidation was attributed to fast chromium diffusion through random boundaries and mechanically deformed regions such as scratches left after polishing. It is envisioned that the oxidation behavior of alloy 690 in supercritical water can be tailored by microstructure

  16. Validation of Test Methods for Air Leak Rate Verification of Spaceflight Hardware

    NASA Technical Reports Server (NTRS)

    Oravec, Heather Ann; Daniels, Christopher C.; Mather, Janice L.

    2017-01-01

    As deep space exploration continues to be the goal of NASAs human spaceflight program, verification of the performance of spaceflight hardware becomes increasingly critical. Suitable test methods for verifying the leak rate of sealing systems are identified in program qualification testing requirements. One acceptable method for verifying the air leak rate of gas pressure seals is the tracer gas leak detector method. In this method, a tracer gas (commonly helium) leaks past the test seal and is transported to the leak detector where the leak rate is quantified. To predict the air leak rate, a conversion factor of helium-to-air is applied depending on the magnitude of the helium flow rate. The conversion factor is based on either the molecular mass ratio or the ratio of the dynamic viscosities. The current work was aimed at validating this approach for permeation-level leak rates using a series of tests with a silicone elastomer O-ring. An established pressure decay method with constant differential pressure was used to evaluate both the air and helium leak rates of the O-ring under similar temperature and pressure conditions. The results from the pressure decay tests showed, for the elastomer O-ring, that neither the molecular flow nor the viscous flow helium-to-air conversion factors were applicable. Leak rate tests were also performed using nitrogen and argon as the test gas. Molecular mass and viscosity based helium-to-test gas conversion factors were applied, but did not correctly predict the measured leak rates of either gas. To further this study, the effect of pressure boundary conditions was investigated. Often, pressure decay leak rate tests are performed at a differential pressure of 101.3 kPa with atmospheric pressure on the downstream side of the test seal. In space applications, the differential pressure is similar, but with vacuum as the downstream pressure. The same O-ring was tested at four unique differential pressures ranging from 34.5 to 137.9 k

  17. Boundary streaming with Navier boundary condition.

    PubMed

    Xie, Jin-Han; Vanneste, Jacques

    2014-06-01

    In microfluidic applications involving high-frequency acoustic waves over a solid boundary, the Stokes boundary-layer thickness δ is so small that some non-negligible slip may occur at the fluid-solid interface. This paper assesses the impact of this slip by revisiting the classical problem of steady acoustic streaming over a flat boundary, replacing the no-slip boundary condition with the Navier condition u|_{y=0}=L_{s}∂_{y}u|_{y=0}, where u is the velocity tangent to the boundary y=0, and the parameter L_{s} is the slip length. A general expression is obtained for the streaming velocity across the boundary layer as a function of the dimensionless parameter L_{s}/δ. The limit outside the boundary layer provides an effective slip velocity satisfied by the interior mean flow. Particularizing to traveling and standing waves shows that the boundary slip respectively increases and decreases the streaming velocity.

  18. Continuous atmospheric boundary layer observations in the coastal urban area of Barcelona, Spain

    NASA Astrophysics Data System (ADS)

    Pandolfi, M.; Martucci, G.; Querol, X.; Alastuey, A.; Wilsenack, F.; Frey, S.; O'Dowd, C. D.; Dall'Osto, M.

    2013-01-01

    Continuous measurements of Surface Mixed Layer (SML), Decoupled Residual/Convective Layer (DRCL) and aerosol backscatter coefficient were performed within the Barcelona (NE Spain) boundary layer from September to October 2010 (30 days) in the framework of the SAPUSS (Solving Aerosol Problems Using Synergistic Strategies) field campaign. Two near-infrared ceilometers (Jenoptik CHM15K) vertically and horizontally-probing (only vertical profiles are discussed) were deployed during SAPUSS and compared with potential temperature profiles measured by daily radiosounding (midnight and midday) to interpret the boundary layer structure in the urban area of Barcelona. Ceilometer-based DRCL (1761±363 m a.g.l.) averaged over the campaign duration were twice as high as the mean SML (904±273 m a.g.l.) with a marked SML diurnal cycle. The overall agreement between the ceilometer-retrieved and radiosounding-based SML heights (R2=0.8) revealed overestimation of the SML by the ceilometer (Δh=145±145 m). After separating the data in accordance with different atmospheric scenarios, the lowest SML (736±183 m) and DRCL (1573±428 m) were recorded during warm North African (NAF) advected air mass. By contrast, higher SML and DRCL were observed during stagnant regional (REG) (911±234 m and 1769±314 m, respectively) and cold Atlantic (ATL) (965±222 m and 1878±290 m, respectively) air masses. The SML during the NAF scenario frequently showed a flat upper boundary throughout the day because of strong winds from the Mediterranean Sea that limit the midday SML convective growth observed during ATL and REG scenarios. The mean backscatter coefficients were calculated at two selected heights as representative of middle and top SML portions, i.e. β500=0.59±0.45 M m-1 sr-1 and β800=0.87±0.68 M m-1 sr-1 at 500 m and 800 m a.g.l., respectively. The highest backscatter coefficients were observed during NAF (β500=0.77±0.57 M m-1 sr-1) when compared with ATL (β500= 0.51±0.44 M m-1 sr-1

  19. Experimental investigation of the limits of ethanol combustion in the boundary layer behind an obstacle

    NASA Astrophysics Data System (ADS)

    Boyarshinov, B. F.

    2018-01-01

    Experimental data on the flow structure and mass transfer near the boundaries of the region existence of the laminar and turbulent boundary layers with combustion are considered. These data include the results of in-vestigation on reacting flow stability at mixed convection, mass transfer during ethanol evaporation "on the floor" and "on the ceiling", when the flame surface curves to form the large-scale cellular structures. It is shown with the help of the PIV equipment that when Rayleigh-Taylor instability manifests, the mushroom-like structures are formed, where the motion from the flame front to the wall and back alternates. The cellular flame exists in a narrow range of velocities from 0.55 to 0.65 m/s, and mass transfer is three times higher than its level in the standard laminar boundary layer.

  20. The effect of star-spots on the ages of low-mass stars determined from the lithium depletion boundary

    NASA Astrophysics Data System (ADS)

    Jackson, R. J.; Jeffries, R. D.

    2014-12-01

    In a coeval group of low-mass stars, the luminosity of the sharp transition between stars that retain their initial lithium and those at slightly higher masses in which Li has been depleted by nuclear reactions, the lithium depletion boundary (LDB), has been advanced as an almost model-independent means of establishing an age scale for young stars. Here, we construct polytropic models of contracting pre-main sequence stars (PMS) that have cool, magnetic star-spots blocking a fraction β of their photospheric flux. Star-spots slow the descent along Hayashi tracks, leading to lower core temperatures and less Li destruction at a given mass and age. The age, τLDB, determined from the luminosity of the LDB, LLDB, is increased by a factor of (1 - β)-E compared to that inferred from unspotted models, where E ≃ 1 + dlog τLDB/dlog LLDB and has a value ˜0.5 at ages <80 Myr, decreasing to ˜0.3 for older stars. Spotted stars have virtually the same relationship between K-band bolometric correction and colour as unspotted stars, so this relationship applies equally to ages inferred from the absolute K magnitude of the LDB. Low-mass PMS stars do have star-spots, but the appropriate value of β is highly uncertain with a probable range of 0.1 < β < 0.4. For the smaller β values, our result suggests a modest systematic increase in LDB ages that is comparable with the maximum levels of theoretical uncertainty previously claimed for the technique. The largest β values would however increase LDB ages by 20-30 per cent and demand a re-evaluation of other age estimation techniques calibrated using LDB ages.

  1. Adjoint-based constant-mass partial derivatives

    DOE PAGES

    Favorite, Jeffrey A.

    2017-09-01

    In transport theory, adjoint-based partial derivatives with respect to mass density are constant-volume derivatives. Likewise, adjoint-based partial derivatives with respect to surface locations (i.e., internal interface locations and the outer system boundary) are constant-density derivatives. This study derives the constant-mass partial derivative of a response with respect to an internal interface location or the outer system boundary and the constant-mass partial derivative of a response with respect to the mass density of a region. Numerical results are given for a multiregion two-dimensional (r-z) cylinder for three very different responses: the uncollided gamma-ray flux at an external detector point, k effmore » of the system, and the total neutron leakage. Finally, results from the derived formulas compare extremely well with direct perturbation calculations.« less

  2. Boundary-layer effects on cold fronts at a coastline

    NASA Astrophysics Data System (ADS)

    Garratt, J. R.

    1986-07-01

    The present note discusses one physical mechanism which may contribute to cold air channelling, manifest as a frontal bulge on a surface-analysis chart, in the coastal region of Victoria in southeast Australia. This involves the modification of boundary-layer air in both offshore (prefrontal) and onshore (postfrontal) flow, and the effect on cross-frontal thermal contrast. The problem is discussed in terms of a north-south-oriented cold front behaving as an atmospheric gravity current, propagating along an east-west-oriented coastline, in the presence of a prefrontal offshore stream.

  3. Further results related to the turbulent boundary layer with slot injection of helium

    NASA Technical Reports Server (NTRS)

    Larue, J. C.; Libby, P. A.

    1978-01-01

    Data from an experiment involving the slot injection of helium into a turbulent boundary layer in air are analyzed in terms of unconditioned and conditioned Favre-averages. The conditioning is based on two levels of helium concentration so that the contributions to the unconditioned statistics from air, helium, and mixture of these two gases can be determined. The distributions of intermittency associated with the two helium levels establish the domains of influence of air, helium, and mixture.

  4. Columnar aerosol optical and radiative properties according to season and air mass transport pattern over East Asia.

    PubMed

    Noh, Young M; Müller, Detlef; Lee, Hanlim; Lee, Kwonho; Kim, Young Joon

    2012-08-01

    The column-integrated optical and radiative properties of aerosols in the downwind area of East Asia were investigated based on sun/sky radiometer measurements performed from February 2004 to June 2005 at Gwangju (35.23° N, 126.84° E) and Anmyeon (36.54° N, 126.33° E), Korea. The observed aerosol data were analyzed for differences among three seasons: spring (March-May), summer (June-August), and autumn/winter (September-February). The data were also categorized into five types depending on the air mass origin in arriving in the measurement sites: (a) from a northerly direction in spring (S(N)), (b) from a westerly direction in spring (S(W)), (c) cases with a low Ångström exponent (<0.8) in spring (dust), (d) from a northerly direction in autumn/winter (AW(N)), and (e) from a westerly direction during other seasons (AW(W)). The highest Ångström exponents (α) at Gwangju and Anmyeon were 1.43 ± 0.30 and 1.49 ± 0.20, respectively, observed in summer. The lowest column-mean single-scattering albedo (ω) at 440 nm observed at Gwangju and Anmyeon were 0.89 ± 0.02 and 0.88 ± 0.02, respectively, during a period marked by the advection of dust from the Asian continent. The highest ω values at Gwangju and Anmyeon were 0.95 ± 0.02 and 0.96 ± 0.02, respectively, observed in summer. Variations in the aerosol radiative-forcing efficiency (β) were related to the conditions of the air mass origin. The forcing efficiency in summer was -131.7 and -125.6 W m(-2) at the surface in Gwangju and Anmyeon, respectively. These values are lower than those under the atmospheric conditions of spring and autumn/winter. The highest forcing efficiencies in autumn/winter were -214.3 and -255.9 W m(-2) at the surface in Gwangju and Anmyeon, respectively, when the air mass was transported from westerly directions.

  5. Heat and mass transfer analogy for condensation of humid air in a vertical channel

    NASA Astrophysics Data System (ADS)

    Desrayaud, G.; Lauriat, G.

    This study examines energy transport associated with liquid film condensation in natural convection flows driven by differences in density due to temperature and concentration gradients. The condensation problem is based on the thin-film assumptions. The most common compositional gradient, which is encountered in humid air at ambient temperature is considered. A steady laminar Boussinesq flow of an ideal gas-vapor mixture is studied for the case of a vertical parallel plate channel. New correlations for the latent and sensible Nusselt numbers are established, and the heat and mass transfer analogy between the sensible Nusselt number and Sherwood number is demonstrated.

  6. Edge states at phase boundaries and their stability

    NASA Astrophysics Data System (ADS)

    Asorey, M.; Balachandran, A. P.; Pérez-Pardo, J. M.

    2016-10-01

    We analyze the effects of Robin-like boundary conditions on different quantum field theories of spin 0, 1/2 and 1 on manifolds with boundaries. In particular, we show that these conditions often lead to the appearance of edge states. These states play a significant role in physical phenomena like quantum Hall effect and topological insulators. We prove in a rigorous way the existence of spectral lower bounds on the kinetic term of different Hamiltonians, even in the case of Abelian gauge fields where it is a non-elliptic differential operator. This guarantees the stability and consistency of massive field theories with masses larger than the lower bound of the kinetic term. Moreover, we find an upper bound for the deepest edge state. In the case of Abelian gauge theories, we analyze a generalization of Robin boundary conditions. For Dirac fermions, we analyze the cases of Atiyah-Patodi-Singer and chiral bag boundary conditions. The explicit dependence of the bounds on the boundary conditions and the size of the system is derived under general assumptions.

  7. Carbonaceous aerosols in the air masses transported from Indochina to Taiwan: Long-term observation at Mt. Lulin

    NASA Astrophysics Data System (ADS)

    Chuang, Ming-Tung; Lee, Chung-Te; Chou, Charles C.-K.; Lin, Neng-Huei; Sheu, Guey-Rong; Wang, Jia-Lin; Chang, Shuenn-Chin; Wang, Sheng-Hsiang; Chi, Kai Hsien; Young, Chea-Yuan; Huang, Hill; Chen, Horng-Wen; Weng, Guo-Hau; Lai, Sin-Yu; Hsu, Shao-Peng; Chang, Yu-Jia; Chang, Jia-Hon; Wu, Xyue-Chang

    2014-06-01

    Eight carbonaceous fractions from aerosols were resolved using the Interagency Monitoring of Protected Visual Environments (IMPROVE) protocol (Chow et al., 1993). The aerosols were collected at the Mountain Lulin Atmospheric Background Station (Mt. Lulin, 2862 m a.s.l.) in Central Taiwan from April 2003 to April 2012. The monthly and yearly levels of organic carbon (OC) and elemental carbon (EC) varied consistently with PM2.5 mass concentrations during biomass burning (BB) period. The highest monthly carbonaceous content was observed in March and the highest yearly carbonaceous concentration was observed in 2007. This finding is consistent with the BB activity in Indochina and indicates that carbonaceous content is a major component of BB aerosols. Lee et al. (2011) classified four trajectory groups from the air masses transported to Mt. Lulin during the aerosol collection period. For the air masses transported from the BB area (the BB group) in Indochina, the carbonaceous content was greater than the water-soluble ions in PM2.5, and the OC/EC ratio (4.8 ± 1.5) was high. With EC as the indicator of primary emission sources, the air masses of the BB group were found to contain more primary than secondary OC. The Anthropogenic group (from the local and free troposphere below the 700-hPa pressure level over the Asian continent) probably contained more secondary than primary OC or the sources of OC and EC could be quite diverse. The average char-EC/soot-EC (low-temperature EC/high-temperature EC) ratios were 3.9 ± 3.5, 0.4 ± 0.4, 0.9 ± 0.8, and 0.3 ± 0.4 for the trajectory groups BB, SNBB (from BB source areas during the non-BB period), Anthropogenic, and FT (from the oceanic area and the free troposphere above the 700-hPa pressure level over the Asian continent), respectively. The presence of a high char-EC/soot-EC ratio confirmed the correct classification of the BB group, whereas the low ratios from the other groups indicated the strong influence of vehicle

  8. Minimization of vibration in elastic beams with time-variant boundary conditions

    NASA Technical Reports Server (NTRS)

    Amirouche, F. M. L.; Xie, Mingjun

    1992-01-01

    This paper presents an innovative method for minimizing the vibration of structures with time-variant boundary conditions (supports). The elastic body is modeled in two ways: (1) the first model is a letter seven type beam with a movable mass not to exceed the lower tip; (2) the second model has an arm that is a hollow beam with an inside mass with adjustable position. The complete solutions to both problems are carried out where the body is undergoing large rotation. The quasi-static procedure is used for the time-variant boundary conditions. The method developed employs partial differential equations governing the motion of the beam, including the effects of rigid-body motion, time-variant boundary conditions, and calculus of variations. The analytical solution is developed using Laplace and Fourier transforms. Examples of elastic robotic arms are given to illustrate the effectiveness of the methods developed.

  9. High precision time calibration of the Permo-Triassic boundary mass extinction by U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Baresel, Björn; Bucher, Hugo; Brosse, Morgane; Schaltegger, Urs

    2014-05-01

    U-Pb dating using Chemical Abrasion, Isotope Dilution Thermal Ionization Mass Spectrometry (CA-ID-TIMS) is the analytical method of choice for geochronologists, who are seeking highest temporal resolution and a high degree of accuracy for single grains of zircon. The use of double-isotope tracer solutions, cross-calibrated and assessed in different EARTHTIME labs, coinciding with the reassessment of the uranium decay constants and further improvements in ion counting technology led to unprecedented precision better than 0.1% for single grain, and 0.05% for population ages, respectively. These analytical innovations now allow calibrating magmatic and biological timescales at resolution adequate for both groups of processes. To construct a revised and high resolution calibrated time scale for the Permian-Triassic boundary (PTB) we use (i) high-precision U-Pb zircon age determinations of a unique succession of volcanic ash beds interbedded with shallow to deep water fossiliferous sediments in the Nanpanjiang Basin (South China) combined with (ii) accurate quantitative biochronology based on ammonoids and conodonts and (iii) carbon isotope excursions across the PTB. Using these alignments allows (i) positioning the PTB in different depositional environments and (ii) solving age/stratigraphic contradictions generated by the index, water depth-controlled conodont Hindeodus parvus, whose diachronous first occurrences are arbitrarily used for placing the base of the Triassic. This new age framework provides the basis for a combined calibration of chemostratigraphic records with high-resolution biochronozones of the Late Permian and Early Triassic. Besides the general improvement of the radio-isotopic calibration of the PTB at the ±100 ka level, this will also lead to a better understanding of cause and effect relations involved in this mass extinction.

  10. Viscous drag reduction in boundary layers

    NASA Technical Reports Server (NTRS)

    Bushnell, Dennis M. (Editor); Hefner, Jerry N. (Editor)

    1990-01-01

    The present volume discusses the development status of stability theory for laminar flow control design, applied aspects of laminar-flow technology, transition delays using compliant walls, the application of CFD to skin friction drag-reduction, active-wave control of boundary-layer transitions, and such passive turbulent-drag reduction methods as outer-layer manipulators and complex-curvature concepts. Also treated are such active turbulent drag-reduction technique applications as those pertinent to MHD flow drag reduction, as well as drag reduction in liquid boundary layers by gas injection, drag reduction by means of polymers and surfactants, drag reduction by particle addition, viscous drag reduction via surface mass injection, and interactive wall-turbulence control.

  11. Methane mole fraction and δ13C above and below the trade wind inversion at Ascension Island in air sampled by aerial robotics

    NASA Astrophysics Data System (ADS)

    Brownlow, R.; Lowry, D.; Thomas, R. M.; Fisher, R. E.; France, J. L.; Cain, M.; Richardson, T. S.; Greatwood, C.; Freer, J.; Pyle, J. A.; MacKenzie, A. R.; Nisbet, E. G.

    2016-11-01

    Ascension Island is a remote South Atlantic equatorial site, ideal for monitoring tropical background CH4. In September 2014 and July 2015, octocopters were used to collect air samples in Tedlar bags from different heights above and below the well-defined Trade Wind Inversion (TWI), sampling a maximum altitude of 2700 m above mean sea level. Sampling captured both remote air in the marine boundary layer below the TWI and also air masses above the TWI that had been lofted by convective systems in the African tropics. Air above the TWI was characterized by higher CH4, but no distinct shift in δ13C was observed compared to the air below. Back trajectories indicate that lofted CH4 emissions from Southern Hemisphere Africa have bulk δ13CCH4 signatures similar to background, suggesting mixed emissions from wetlands, agriculture, and biomass burning. The campaigns illustrate the usefulness of unmanned aerial system sampling and Ascension's value for atmospheric measurement in an understudied region.

  12. Studying the Afternoon Transition of the Planetary Boundary Layer

    NASA Astrophysics Data System (ADS)

    Lothon, Marie; Lenschow, Donald H.

    2010-07-01

    The planetary boundary layer is the part of the atmosphere that interacts directly with the Earth's surface on a time scale of a few hours or less. In daytime, solar heating of the surface can generate buoyant turbulent eddies that efficiently mix the air through a depth of more than a kilometer. This convective boundary layer (CBL) is a conduit for trace gases such as water vapor and carbon dioxide that are emitted or absorbed by the surface (and surface vegetation) to be transported into or out of the layer nearest the surface. The CBL has been extensively observed and relatively successfully modeled. But the early morning transition—when the CBL emerges from the nocturnal boundary layer—and the late afternoon transition—when the CBL decays to an intermittently turbulent “residual layer” overlying a shallower, stably stratified boundary layer—are difficult to observe and model due to turbulence intermittency and anisotropy, horizontal heterogeneity, and rapid time changes. Even the definition of the boundary layer during these transitional periods is fuzzy; there is no consensus on what criteria to use and no simple scaling laws, as there are for the CBL, that apply during these transitions.

  13. Evaluating the impact of chemical boundary conditions on near surface ozone in regional climate-air quality simulations over Europe

    NASA Astrophysics Data System (ADS)

    Akritidis, D.; Zanis, P.; Katragkou, E.; Schultz, M. G.; Tegoulias, I.; Poupkou, A.; Markakis, K.; Pytharoulis, I.; Karacostas, Th.

    2013-12-01

    A modeling system based on the air quality model CAMx driven off-line by the regional climate model RegCM3 is used for assessing the impact of chemical lateral boundary conditions (LBCs) on near surface ozone over Europe for the period 1996-2000. The RegCM3 and CAMx simulations were performed on a 50 km × 50 km grid over Europe with RegCM3 driven by the NCEP meteorological reanalysis fields and CAMx with chemical LBCs from ECHAM5/MOZART global model. The recent past period (1996-2000) was simulated in three experiments. The first simulation was forced using time and space invariant LBCs, the second was based on ECHAM5/MOZART chemical LBCs fixed for the year 1996 and the third was based on ECHAM5/MOZART chemical LBCs with interannual variability. Anthropogenic and biogenic emissions were kept identical for the three sensitivity runs.

  14. Extratropical Stratosphere-Troposphere Mass Exchange

    NASA Technical Reports Server (NTRS)

    Schoeberl, Mark R.

    2004-01-01

    Understanding the exchange of gases between the stratosphere and the troposphere is important for determining how pollutants enter the stratosphere and how they leave. This study does a global analysis of that the exchange of mass between the stratosphere and the troposphere. While the exchange of mass is not the same as the exchange of constituents, you can t get the constituent exchange right if you have the mass exchange wrong. Thus this kind of calculation is an important test for models which also compute trace gas transport. In this study I computed the mass exchange for two assimilated data sets and a GCM. The models all agree that amount of mass descending from the stratosphere to the troposphere in the Northern Hemisphere extra tropics is approx. 10(exp 10) kg/s averaged over a year. The value for the Southern Hemisphere by about a factor of two. ( 10(exp 10) kg of air is the amount of air in 100 km x 100 km area with a depth of 100 m - roughly the size of the D.C. metro area to a depth of 300 feet.) Most people have the idea that most of the mass enters the stratosphere through the tropics. But this study shows that almost 5 times more mass enters the stratosphere through the extra-tropics. This mass, however, is quickly recycled out again. Thus the lower most stratosphere is a mixture of upper stratospheric air and tropospheric air. This is an important result for understanding the chemistry of the lower stratosphere.

  15. What is Wrong with the Boundary Conditions in Column Tracer Tests

    NASA Astrophysics Data System (ADS)

    Zhan, H.

    2007-12-01

    Solute transport in a column is probably one of the most fundamental problems investigated in contaminant hydrology and soil physics because it serves as a benchmark for testing transport theories, for measuring dispersivities, etc. Despite its importance, there are still dispute and inconsistency on how to deal with the boundary conditions involved in such problems. The boundary condition could impose great influence upon transport in a column, particularly when the length of the column is relatively short, or the so-called Peclet number is not large. There are three types of boundary conditions to choose for transport in a column. Among these three types of boundary conditions, only the third-type boundary satisfies the mass balance requirement rigorously. The first type boundary, despite its frequent use in previous studies, could lead to serious mass balance problems. The most serious problem is on how to deal with the outlet boundary. Some studies have used a zero concentration gradient at the outlet (the so-called Danckwerts' boundary condition). This is named the model A. Another idea is to treat the finite length column as a part of an infinitely long column and to calculate the concentration at the outlet based on a formula developed for an infinitely long column. This is named the model B. The model A satisfies the mass balance requirement but was found to fit with the experimental data poorly. The model B does not satisfy the mass balance requirement, but usually agree well with the experimental data. So, the dilemma is: which model to choose? At present, most investigators prefer to choose the model B because of its close agreement with the experimental data, despite of its violation of the mass balance requirement. But the question is: why the model A, which satisfies the mass balance requirement, does not fit with the experimental data? It turns out that the advection-dispersion equation (ADE) that uses the Fick's first law to describe the

  16. Dry intrusions: Lagrangian climatology and impact on the boundary layer

    NASA Astrophysics Data System (ADS)

    Raveh-Rubin, Shira; Wernli, Heini

    2017-04-01

    Dry air intrusions (DIs) are large-scale descending airstreams. A DI is typically referred to as a coherent airstream in the cold sector of an extratropical cyclone. Emerging evidence suggests that DIs are linked to severe surface wind gusts. However, there is yet no strict Lagrangian definition of DIs, and so their climatological frequency, dynamical characteristics as well as their seasonal and spatial distributions are unknown. Furthermore, the dynamical interaction between DIs and the planetary boundary layer is not fully understood. Here, we suggest a Lagrangian definition for DI air parcels, namely a minimum pressure increase along a trajectory of 400 hPa in 48 hours. Based on this criterion, the open questions are addressed by: (i) a novel global Lagrangian climatology for the ECMWF ERA-Interim reanalysis dataset for the years 1979-2014; (ii) a case study illustrating the interaction between DIs and the boundary layer. We find that DIs occur predominantly in winter. DIs coherently descend from the upper troposphere (their stratospheric origin is small), to the mid- and low levels, where they mix with their environment and diverge. Different physical characteristics typify DIs in the different regions and seasons. Finally, we demonstrate the different mechanisms by which DIs can destabilize the boundary layer and facilitate the formation of strong surface winds.

  17. Measurements of Skin Friction of the Compressible Turbulent Boundary Layer on a Cone with Foreign Gas Injection

    NASA Technical Reports Server (NTRS)

    Pappas, Constantine C.; Ukuno, Arthur F.

    1960-01-01

    Measurements of average skin friction of the turbulent boundary layer have been made on a 15deg total included angle cone with foreign gas injection. Measurements of total skin-friction drag were obtained at free-stream Mach numbers of 0.3, 0.7, 3.5, and 4.7 and within a Reynolds number range from 0.9 x 10(exp 6) to 5.9 x 10(exp 6) with injection of helium, air, and Freon-12 (CCl2F2) through the porous wall. Substantial reductions in skin friction are realized with gas injection within the range of Mach numbers of this test. The relative reduction in skin friction is in accordance with theory-that is, the light gases are most effective when compared on a mass flow basis. There is a marked effect of Mach number on the reduction of average skin friction; this effect is not shown by the available theories. Limited transition location measurements indicate that the boundary layer does not fully trip with gas injection but that the transition point approaches a forward limit with increasing injection. The variation of the skin-friction coefficient, for the lower injection rates with natural transition, is dependent on the flow Reynolds number and type of injected gas; and at the high injection rates the skin friction is in fair agreement with the turbulent boundary layer results.

  18. Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area

    PubMed Central

    Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

    2016-01-01

    Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose–response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m−3, range <0.023–3.0mg m−3) and below the present Swedish occupational exposure limit (OEL) of 10mg m−3. The cobalt levels were low as well (AM 0.0030mg m−3, range 0.000028–0.056mg m−3) and only 6% of the samples exceeded the Swedish OEL of 0.02mg m−3. For continuous personal monitoring of dust exposure, the peaks ranged from 0.001 to 83mg m−3 by work task. Stationary measurements showed lower average levels both for inhalable and total dust and cobalt. The particle number concentration of fine particles (AM 3000 p·cm−3) showed the highest levels at the departments of powder production, pressing and storage, and for the particle surface area concentrations (AM 7.6 µm2·cm−3) similar results were found. Correlating cobalt mass-based exposure measurements to cobalt stationary mass-based, particle area, and particle number concentrations by rank and department showed significant correlations for all measures except for particle

  19. Concentration and variability of ice nuclei in the subtropical maritime boundary layer

    NASA Astrophysics Data System (ADS)

    Welti, André; Müller, Konrad; Fleming, Zoë L.; Stratmann, Frank

    2018-04-01

    Measurements of the concentration and variability of ice nucleating particles in the subtropical maritime boundary layer are reported. Filter samples collected in Cabo Verde over the period 2009-2013 are analyzed with a drop freezing experiment with sensitivity to detect the few rare ice nuclei active at low supercooling. The data set is augmented with continuous flow diffusion chamber measurements at temperatures below -24 °C from a 2-month field campaign in Cabo Verde in 2016. The data set is used to address the following questions: what are typical concentrations of ice nucleating particles active at a certain temperature? What affects their concentration and where are their sources? Concentration of ice nucleating particles is found to increase exponentially by 7 orders of magnitude from -5 to -38 °C. Sample-to-sample variation in the steepness of the increase indicates that particles of different origin, with different ice nucleation properties (size, composition), contribute to the ice nuclei concentration at different temperatures. The concentration of ice nuclei active at a specific temperature varies over a range of up to 4 orders of magnitude. The frequency with which a certain ice nuclei concentration is measured within this range is found to follow a lognormal distribution, which can be explained by random dilution during transport. To investigate the geographic origin of ice nuclei, source attribution of air masses from dispersion modeling is used to classify the data into seven typical conditions. While no source could be attributed to the ice nuclei active at temperatures higher than -12 °C, concentrations at lower temperatures tend to be elevated in air masses originating from the Sahara.

  20. Turbulence measurements in high Reynolds number boundary layers

    NASA Astrophysics Data System (ADS)

    Vallikivi, Margit; Smits, Alexander

    2013-11-01

    Measurements are conducted in zero pressure gradient turbulent boundary layers for Reynolds numbers from Reθ = 9,000 to 225,000. The experiments were performed in the High Reynolds number Test Facility (HRTF) at Princeton University, which uses compressed air as the working fluid. Nano-Scale Thermal Anemometry Probes (NSTAPs) are used to acquire data with very high spatial and temporal precision. These new data are used to study the scaling behavior of the streamwise velocity fluctuations in the boundary layer and make comparisons with the scaling of other wall-bounded turbulent flows. Supported under ONR Grant N00014-09-1-0263 (program manager Ron Joslin) and NSF Grant CBET-1064257 (program manager Henning Winter).

  1. Gulf of Mexico Air/Sea Interaction: Measurements and Initial Data Characterization

    NASA Astrophysics Data System (ADS)

    MacDonald, C.; Huang, C. H.; Roberts, P. T.; Bariteau, L.; Fairall, C. W.; Gibson, W.; Ray, A.

    2011-12-01

    Corporate, government, and university researchers collaborated to develop an atmospheric boundary layer environmental observations program on an offshore platform in the Gulf of Mexico. The primary goals of this project were to provide data to (1) improve our understanding of boundary layer processes and air-sea interaction over the Gulf of Mexico; (2) improve regional-scale meteorological and air quality modeling; and (3) provide a framework for advanced offshore measurements to support future needs such as emergency response, exploration and lease decisions, wind energy research and development, and meteorological and air quality forecasting. In October 2010, meteorological and oceanographic sensors were deployed for an extended period (approximately 12 months) on a Chevron service platform (ST 52B, 90.5W, 29N) to collect boundary layer and sea surface data sufficient to support these objectives. This project has significant importance given the large industrial presence in the Gulf, sizeable regional population nearby, and the recognized need for precise and timely pollutant forecasts. Observations from this project include surface meteorology; sodar marine boundary layer winds; microwave radiometer profiles of temperature, relative humidity, and liquid water; ceilometer cloud base heights; water temperature and current profiles; sea surface temperature; wave height statistics; downwelling solar and infrared radiation; and air-sea turbulent momentum and heat fluxes. This project resulted in the collection of an unprecedented set of boundary layer measurements over the Gulf of Mexico that capture the range of meteorological and oceanographic interactions and processes that occur over an entire year. This presentation will provide insight into the logistical and scientific issues associated with the deployment and operations of unique measurements in offshore areas and provide results from an initial data analysis of boundary layer processes over the Gulf of

  2. Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms

    PubMed Central

    Baresel, Björn; Bucher, Hugo; Bagherpour, Borhan; Brosse, Morgane; Guodun, Kuang; Schaltegger, Urs

    2017-01-01

    New high-resolution U-Pb dates indicate a duration of 89 ± 38 kyr for the Permian hiatus and of 14 ± 57 kyr for the overlying Triassic microbial limestone in shallow water settings of the Nanpanjiang Basin, South China. The age and duration of the hiatus coincides with the Permian-Triassic boundary (PTB) and the extinction interval in the Meishan Global Stratotype Section and Point, and strongly supports a glacio-eustatic regression, which best explains the genesis of the worldwide hiatus straddling the PTB in shallow water records. In adjacent deep marine troughs, rates of sediment accumulation display a six-fold decrease across the PTB compatible with a dryer and cooler climate as indicated by terrestrial plants. Our model of the Permian-Triassic boundary mass extinction (PTBME) hinges on the synchronicity of the hiatus with the onset of the Siberian Traps volcanism. This early eruptive phase released sulfur-rich volatiles into the stratosphere, thus simultaneously eliciting a short-lived ice age responsible for the global regression and a brief but intense acidification. Abrupt cooling, shrunk habitats on shelves and acidification may all have synergistically triggered the PTBME. Subsequently, the build-up of volcanic CO2 induced a transient cool climate whose early phase saw the deposition of the microbial limestone. PMID:28262815

  3. Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms

    NASA Astrophysics Data System (ADS)

    Baresel, Björn; Bucher, Hugo; Bagherpour, Borhan; Brosse, Morgane; Guodun, Kuang; Schaltegger, Urs

    2017-03-01

    New high-resolution U-Pb dates indicate a duration of 89 ± 38 kyr for the Permian hiatus and of 14 ± 57 kyr for the overlying Triassic microbial limestone in shallow water settings of the Nanpanjiang Basin, South China. The age and duration of the hiatus coincides with the Permian-Triassic boundary (PTB) and the extinction interval in the Meishan Global Stratotype Section and Point, and strongly supports a glacio-eustatic regression, which best explains the genesis of the worldwide hiatus straddling the PTB in shallow water records. In adjacent deep marine troughs, rates of sediment accumulation display a six-fold decrease across the PTB compatible with a dryer and cooler climate as indicated by terrestrial plants. Our model of the Permian-Triassic boundary mass extinction (PTBME) hinges on the synchronicity of the hiatus with the onset of the Siberian Traps volcanism. This early eruptive phase released sulfur-rich volatiles into the stratosphere, thus simultaneously eliciting a short-lived ice age responsible for the global regression and a brief but intense acidification. Abrupt cooling, shrunk habitats on shelves and acidification may all have synergistically triggered the PTBME. Subsequently, the build-up of volcanic CO2 induced a transient cool climate whose early phase saw the deposition of the microbial limestone.

  4. PM2.5 chemical composition at a rural background site in Central Europe, including correlation and air mass back trajectory analysis

    NASA Astrophysics Data System (ADS)

    Schwarz, Jaroslav; Cusack, Michael; Karban, Jindřich; Chalupníčková, Eva; Havránek, Vladimír; Smolík, Jiří; Ždímal, Vladimír

    2016-07-01

    of fresh, local aerosol and aged, long-range transport aerosol. The influences of different air masses were also investigated. The lowest concentrations of PM2.5 were recorded under the influence of marine air masses from the NW, which were also marked by increased concentrations of marine aerosol. In contrast, the highest concentrations of PM2.5 and most major chemical components were measured during periods when continental easterly air masses were dominant.

  5. The Ascension Island Boundary Layer in the Remote Southeast Atlantic is Often Smoky

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zuidema, Paquita; Sedlacek, Arthur J.; Flynn, Connor

    Observations from June through October, 2016, from a surface-based ARM Mobile Facility deployment on Ascension Island (8°S, 14.5°W) indicate that refractory black carbon (rBC) is almost always present within the boundary layer. rBC mass concentrations, light absorption coefficients, and cloud condensation nuclei concentrations vary in concert and synoptically, peaking in August. Derived mass absorption cross-sections using light absorptioin coefficients at three wavelengths as a function of rBC mass indirectly indicate the presence of other light-absorbing organic aerosols (e.g., brown carbon), most pronounced in June. A filter-based estimate of single-scattering-albedo increases systematically from August to October, also apparent in 2017. Boundary-layermore » aerosol loadings are only loosely correlated with total aerosol optical depth, with smoke more likely to be present in the boundary layer earlier in the biomass-burning season, evolving to smoke predominantly present in the free-troposphere in September-October, typically resting upon the cloud-top inversion. The time period with the campaign-maximum near-surface light absorption and column aerosol optical depth, on 13-16 August of 2016, is investigated further. Back trajectories indicate the boundary layer transport was directly westward from the African continent, which is unusual in August.« less

  6. Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms

    NASA Astrophysics Data System (ADS)

    Baresel, Bjoern; Bucher, Hugo; Bagherpour, Borhan; Brosse, Morgane; Guodun, Kuang; Schaltegger, Urs

    2017-04-01

    High-precision U-Pb dating of single-zircon crystals by chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) is applied to volcanic beds that are intercalated in sedimentary sequences across the Permian-Triassic boundary (PTB). By assuming that the zircon crystallization age closely approximate that of the volcanic eruption and subsequent deposition, U-Pb zircon geochronology is the preferred approach for dating abiotic and biotic events, such as the formational PTB and the Permian-Triassic boundary mass extinction (PTBME). We will present new U-Pb zircon dates for a series of volcanic ash beds in shallow-marine Permian-Triassic sections in the Nanpanjiang Basin, South China. These high-resolution U-Pb dates indicate a duration of 90 ± 38 kyr for the Permian sedimentary hiatus and a duration of 13 ± 57 kyr for the overlying Triassic microbial limestone in the shallow water settings of the Nanpanjiang pull apart Basin. The age and duration of the hiatus coincides with the formational PTB and the extinction interval in the Meishan Global Stratotype Section and Point, thus strongly supporting a glacio-eustatic regression, which best explains the genesis of the worldwide hiatus straddling the PTB in shallow water records. In adjacent deep marine troughs, rates of sediment accumulation display a six-fold decrease across the PTB compatible with a dryer and cooler climate during the Griesbachian as indicated by terrestrial plants. Our model of the PTBME hinges on the synchronicity of the hiatus with the onset of the Siberian Traps volcanism. This early eruptive phase likely released sulfur-rich volatiles into the stratosphere, thus simultaneously eliciting a short-lived ice age responsible for the global regression and a brief but intense acidification. Abrupt cooling, shrunk habitats on shelves and acidification may all have synergistically triggered the PTBME. Subsequently, the build-up of volcanic CO2 induced this transient cool

  7. Open-Air Biowarfare Testing and the Evolution of Values

    PubMed Central

    2016-01-01

    The United States and the United Kingdom ended outdoor biological warfare testing in populated areas nearly half a century ago. Yet, the conduct, health effects, and propriety of those tests remain controversial. The varied views reflect the limits of currently available test information and evolving societal values on research involving human subjects. Western political culture has changed since the early days of the American and British testing programs. People have become less reluctant to question authority, and institutional review boards must now pre-approve research involving human subjects. Further, the heightened stringency of laboratory containment has accentuated the safety gap between a confined test space and one without physical boundaries. All this makes it less likely that masses of people would again be unwittingly subjected to secret open-air biological warfare tests. PMID:27564984

  8. Continuous atmospheric boundary layer observations in the coastal urban area of Barcelona during SAPUSS

    NASA Astrophysics Data System (ADS)

    Pandolfi, M.; Martucci, G.; Querol, X.; Alastuey, A.; Wilsenack, F.; Frey, S.; O'Dowd, C. D.; Dall'Osto, M.

    2013-05-01

    Continuous measurements of surface mixed layer (SML), decoupled residual/convective layer (DRCL) and aerosol backscatter coefficient were performed within the Barcelona (Spain) boundary layer from September to October 2010 (30 days) in the framework of the SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies) field campaign. Two near-infrared ceilometers (Jenoptik CHM15K), vertically and horizontally probing (only vertical profiles are herein discussed), were deployed. Ceilometer-based DRCLs (1761 ± 363 m a.g.l.) averaged over the campaign duration were twice as high as the mean SML (904 ± 273 m a.g.l.). Both DRCL and SML showed a marked SML diurnal cycle. Ceilometer data were compared with potential temperature profiles measured by daily radiosounding (twice a day, midnight and midday) to interpret the boundary layer structure in the coastal urban area of Barcelona. The overall agreement (R2 = 0.80) between the ceilometer-retrieved and radiosounding-based SML heights (h) revealed overestimation of the SML by the ceilometer (Δh=145 ± 145 m). After separating the data in accordance with different atmospheric scenarios, the lowest SML (736 ± 183 m) and DRCL (1573 ± 428 m) were recorded during warm North African (NAF) advected air mass. By contrast, higher SML and DRCL were observed during stagnant Regional (REG) (911 ± 234 m and 1769 ± 314 m, respectively) and cold Atlantic (ATL) (965 ± 222 m and 1878 ± 290 m, respectively) air masses. In addition to being the lowest, the SML during the NAF scenario frequently showed a flat upper boundary throughout the day possibly because of the strong winds from the Mediterranean Sea limiting the midday SML convective growth. The mean backscatter coefficients were calculated at two selected heights representative of middle and top SML portions, i.e. β500 = 0.59 ± 0.45 Mm-1 sr-1 and β800 = 0.87 ± 0.68 Mm-1 sr-1 at 500 m and 800 m a.g.l., respectively. The highest backscatter coefficients were observed

  9. Atmospheric dispersion of a heavier-than-air gas near a two-dimensional obstacle

    NASA Astrophysics Data System (ADS)

    Sutton, S. B.; Brandt, H.; White, B. R.

    1986-04-01

    Flow over a two-dimensional obstacle and dispersion of a heavier-than-air gas near the obstacle were studied. Two species, one representing air and the other representing the heavier-than-air gas were treated. Equations for mass and momentum were cast in mass-averaged form, with turbulent Reynolds stresses and mass fluxes modeled using eddy-viscosity and diffusivity hypotheses. A two-equation k-ɛ turbulence model was used to determine the effective turbulent viscosity. Streamline curvature and buoyancy corrections were added to the basic turbulence formulation. The model equations were solved using finite difference techniques. An alternating-direction-implicit (ADI) technique was used to solve the parabolic transport equations and a direct matrix solver was used to solve the elliptic pressure equation. Mesh sensitivities were investigated to determine the optimum mesh requirements for the final calculations. It was concluded that at least 10 grid spaces were required across the obstacle width and 15 across the obstacle height to obtain valid solutions. A non-uniform mesh was used to concentrate the grid points at the top of the obstacle. Experimental measurements were made with air flow over a 7.6 by 7.6 cm obstacle in a boundary-layer wind tunnel. Smoke visualization revealed a low-frequency oscillation of the bubble downstream of the obstacle. Hot-wire anemometer data are presented for the mean velocity and turbulent kinetic energy at the mid-plane of the obstacle and the mid-plane of the downstream recirculation bubble. A single hot-wire probe was found to be suitable for determining mean streamwise velocities with an accuracy of 11 %. The downstream recirculation bubble was unsteady and had a length range from 3 to 8 obstacle lengths. The experimental results for flow over the obstacle were compared with numerical calculations to validate the numerical solution procedure. A sensitivity study on the effect of curvature correction and variation of turbulence

  10. 40 CFR 81.95 - Central Florida Intrastate Air Quality Control Region.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Quality Control Regions § 81.95 Central Florida Intrastate Air Quality Control Region. The Central Florida Intrastate Air Quality Control Region consists of the territorial area encompassed by the boundaries of the... 40 Protection of Environment 17 2011-07-01 2011-07-01 false Central Florida Intrastate Air Quality...

  11. 40 CFR 81.95 - Central Florida Intrastate Air Quality Control Region.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Quality Control Regions § 81.95 Central Florida Intrastate Air Quality Control Region. The Central Florida Intrastate Air Quality Control Region consists of the territorial area encompassed by the boundaries of the... 40 Protection of Environment 17 2010-07-01 2010-07-01 false Central Florida Intrastate Air Quality...

  12. 40 CFR 81.202 - Northwest Ohio Intrastate Air Quality Control Region.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 17 2010-07-01 2010-07-01 false Northwest Ohio Intrastate Air Quality... Quality Control Regions § 81.202 Northwest Ohio Intrastate Air Quality Control Region. The Northwest Ohio Intrastate Air Quality Control Region (Ohio) consists of the territorial area encompassed by the boundaries...

  13. Control of shock wave-boundary layer interactions by bleed in supersonic mixed compression inlets

    NASA Technical Reports Server (NTRS)

    Fukuda, M. K.; Hingst, W. G.; Reshotko, E.

    1975-01-01

    An experimental investigation was conducted to determine the effect of bleed on a shock wave-boundary layer interaction in an axisymmetric mixed-compression supersonic inlet. The inlet was designed for a free-stream Mach number of 2.50 with 60-percent supersonic internal area contraction. The experiment was conducted in the NASA Lewis Research Center 10-Foot Supersonic Wind Tunnel. The effects of bleed amount and bleed geometry on the boundary layer after a shock wave-boundary layer interaction were studied. The effect of bleed on the transformed form factor is such that the full realizable reduction is obtained by bleeding of a mass flow equal to about one-half of the incident boundary layer mass flow. More bleeding does not yield further reduction. Bleeding upstream or downstream of the shock-induced pressure rise is preferable to bleeding across the shock-induced pressure rise.

  14. SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kahn, Ralph A.; Berkoff, Tim A.; Brock, Charles

    A modest operational program of systematic aircraft measurements can resolve key satellite aerosol data record limitations. Satellite observations provide frequent global aerosol amount maps but offer only loose aerosol property constraints needed for climate and air quality applications. In this paper, we define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ. The flight program could characterize major aerosol airmass types statistically, at a level of detail unobtainable from space. It would 1) enhance satellite aerosol retrieval products with better climatology assumptions and 2) improve translation between satellite-retrieved opticalmore » properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space; improve aerosol constraints on climate modeling; help interrelate remote sensing, in situ, and modeling aerosol-type definitions; and contribute to future satellite aerosol missions. Fifteen required variables are identified and four payload options of increasing ambition are defined to constrain these quantities. “Option C” could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. Finally, SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable, even if aerosol loading varies.« less

  15. SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses

    DOE PAGES

    Kahn, Ralph A.; Berkoff, Tim A.; Brock, Charles; ...

    2017-10-30

    A modest operational program of systematic aircraft measurements can resolve key satellite aerosol data record limitations. Satellite observations provide frequent global aerosol amount maps but offer only loose aerosol property constraints needed for climate and air quality applications. In this paper, we define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ. The flight program could characterize major aerosol airmass types statistically, at a level of detail unobtainable from space. It would 1) enhance satellite aerosol retrieval products with better climatology assumptions and 2) improve translation between satellite-retrieved opticalmore » properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space; improve aerosol constraints on climate modeling; help interrelate remote sensing, in situ, and modeling aerosol-type definitions; and contribute to future satellite aerosol missions. Fifteen required variables are identified and four payload options of increasing ambition are defined to constrain these quantities. “Option C” could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. Finally, SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable, even if aerosol loading varies.« less

  16. Size-Segregated Aerosol Composition and Mass Loading of Atmospheric Particles as Part of the Pacific Northwest 2001(PNW2001) Air Quality Study In Puget Sound

    NASA Astrophysics Data System (ADS)

    Disselkamp, R. S.; Barrie, L. A.; Shutthanadan, S.; Cliff, S.; Cahill, T.

    2001-12-01

    In mid-August, 2001, an aircraft-based air-quality study was performed in the Puget Sound, WA, area entitled PNW2001 (http://www.pnl.gov/pnw2001). The objectives of this field campaign were the following: 1. reveal information about the 3-dimensional distribution of ozone, its gaseous precursors and fine particulate matter during weather conditions favoring air pollution; 2. derive information about the accuracy of urban and biogenic emissions inventories that are used to drive the air quality forecast models; and 3. examine the accuracy of modeled ozone concentration with that observed. In support of these efforts, we collected time-averaged ( { ~}10 minute averages), size-segregated, aerosol composition and mass-loading information using ex post facto analysis techniques of synchrotron x-ray fluorescence (s-XRF), proton induced x-ray emissions(PIXE), proton elastic scattering (PESA), and scanning transmission ion microscopy (STIM). This is the first time these analysis techniques have been used together on samples collected from aircraft using an optimized 3-stage rotating drum impactor. In our presentation, we will discuss the aerosol components in three aerosol size fractions as identified by statistical analysis of multielemental data (including total mass, H, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Pb) and relate variations in these components to physical aerosol properties, other gaseous trace constituents and to air mass origin.

  17. Drop size distribution and air velocity measurements in air assist swirl atomizer sprays

    NASA Technical Reports Server (NTRS)

    Mao, C.-P.; Oechsle, V.; Chigier, N.

    1987-01-01

    Detailed measurements of mean drop size (SMD) and size distribution parameters have been made using a Fraunhofer diffraction particle sizing instrument in a series of sprays generated by an air assist swirl atomizer. Thirty-six different combinations of fuel and air mass flow rates were examined with liquid flow rates up to 14 lbm/hr and atomizing air flow rates up to 10 lbm/hr. Linear relationships were found between SMD and liquid to air mass flow rate ratios. SMD increased with distance downstream along the center line and also with radial distance from the axis. Increase in obscuration with distance downstream was due to an increase in number density of particles as the result of deceleration of drops and an increase in the exposed path length of the laser beam. Velocity components of the atomizing air flow field measured by a laser anemometer show swirling jet air flow fields with solid body rotation in the core and free vortex flow in the outer regions.

  18. On the symmetry of the boundary conditions of the volume potential

    NASA Astrophysics Data System (ADS)

    Kal'menov, Tynysbek Sh.; Arepova, Gaukhar; Suragan, Durvudkhan

    2017-09-01

    It is well known that the volume potential determines the mass or the charge distributed over the domain with density f. The volume potential is extensively used in function theory and embedding theorems. It is also well known that the volume potential gives a solution to an inhomogeneous equation. And it generates a linear self-adjoint operator. It is known that self-adjoint differential operators are generated by boundary conditions. In our previous papers for an arbitrary domain a boundary condition on the volume potential is given. In the past, it was not possible to prove the self-adjointness of these obtained boundary conditions. In the present paper, we prove the symmetry of boundary condition for the volume potential.

  19. Large-eddy simulations of a Salt Lake Valley cold-air pool

    NASA Astrophysics Data System (ADS)

    Crosman, Erik T.; Horel, John D.

    2017-09-01

    Persistent cold-air pools are often poorly forecast by mesoscale numerical weather prediction models, in part due to inadequate parameterization of planetary boundary-layer physics in stable atmospheric conditions, and also because of errors in the initialization and treatment of the model surface state. In this study, an improved numerical simulation of the 27-30 January 2011 cold-air pool in Utah's Great Salt Lake Basin is obtained using a large-eddy simulation with more realistic surface state characterization. Compared to a Weather Research and Forecasting model configuration run as a mesoscale model with a planetary boundary-layer scheme where turbulence is highly parameterized, the large-eddy simulation more accurately captured turbulent interactions between the stable boundary-layer and flow aloft. The simulations were also found to be sensitive to variations in the Great Salt Lake temperature and Salt Lake Valley snow cover, illustrating the importance of land surface state in modelling cold-air pools.

  20. Version 2 of the Protuberance Correlations for the Shuttle-Orbiter Boundary Layer Transition Tool

    NASA Technical Reports Server (NTRS)

    King, Rudolph A.; Kegerise, Michael A.; Berry, Scott A.

    2009-01-01

    Orbiter-specific transition data, acquired in four ground-based facilities (LaRC 20-Inch Mach 6 Air Tunnel, LaRC 31-Inch Mach 10 Air Tunnel, LaRC 20-Inch Mach 6 CF4 Tunnel, and CUBRC LENS-I Shock Tunnel) with three wind tunnel model scales (0.75, 0.90, and 1.8%) and from Orbiter historical flight data, have been analyzed to improve a pre-existing engineering tool for reentry transition prediction on the windward side of the Orbiter. Boundary layer transition (BLT) engineering correlations for transition induced by isolated protuberances are presented using a laminar Navier-Stokes (N-S) database to provide the relevant boundary-layer properties. It is demonstrated that the earlier version of the BLT correlation that had been developed using parameters derived from an engineering boundary-layer code has improved data collapse when developed with the N-S database. Of the new correlations examined, the proposed correlation 5, based on boundary-layer edge and wall properties, was found to provide the best overall correlation metrics when the entire database is employed. The second independent correlation (proposed correlation 7) selected is based on properties within the boundary layer at the protuberance height. The Aeroheating Panel selected a process to derive the recommended coefficients for Version 2 of the BLT Tool. The assumptions and limitations of the recommended protuberance BLT Tool V.2 are presented.

  1. Sound absorption and transmission through flexible micro-perforated panels backed by an air layer and a thin plate.

    PubMed

    Bravo, Teresa; Maury, Cédric; Pinhède, Cédric

    2012-05-01

    This paper describes theoretical and experimental investigations into the sound absorption and transmission properties of micro-perforated panels (MPP) backed by an air cavity and a thin plate. A fully coupled modal approach is proposed to calculate the absorption coefficient and the transmission loss of finite-sized micro-perforated panels-cavity-panel (MPPCP) partitions with conservative boundary conditions. It is validated against infinite partition models and experimental data. A practical methodology is proposed using collocated pressure-velocity sensors to evaluate in an anechoic environment the transmission and absorption properties of conventional MPPCPs. Results show under which conditions edge scattering effects should be accounted for at low frequencies. Coupled mode analysis is also performed and analytical approximations are derived from the resonance frequencies and mode shapes of a flexible MPPCP. It is found that the Helmholtz-type resonance frequency is deduced from the one associated to the rigidly backed MPPCP absorber shifted up by the mass-air mass resonance of the flexible non-perforated double-panel. Moreover, it is shown analytically and experimentally that the absorption mechanisms at the resonances are governed by a large air-frame relative velocity over the MPP surface, with either in-phase or out-of-phase relationships, depending on the MPPCP parameters.

  2. Analysis of air-, moisture- and solvent-sensitive chemical compounds by mass spectrometry using an inert atmospheric pressure solids analysis probe.

    PubMed

    Mosely, Jackie A; Stokes, Peter; Parker, David; Dyer, Philip W; Messinis, Antonis M

    2018-02-01

    A novel method has been developed that enables chemical compounds to be transferred from an inert atmosphere glove box and into the atmospheric pressure ion source of a mass spectrometer whilst retaining a controlled chemical environment. This innovative method is simple and cheap to implement on some commercially available mass spectrometers. We have termed this approach inert atmospheric pressure solids analysis probe ( iASAP) and demonstrate the benefit of this methodology for two air-/moisture-sensitive chemical compounds whose characterisation by mass spectrometry is now possible and easily achieved. The simplicity of the design means that moving between iASAP and standard ASAP is straightforward and quick, providing a highly flexible platform with rapid sample turnaround.

  3. Elucidating the relationship between aerosol concentration and summertime boundary layer structure in central China.

    PubMed

    Liu, Lin; Guo, Jianping; Miao, Yucong; Liu, Lin; Li, Jian; Chen, Dandan; He, Jing; Cui, Chunguang

    2018-06-11

    Wuhan, a megacity in central China, suffers from frequent aerosol pollution and is accompanied by meteorological factors at both synoptic and local scales. Partly due to the lack of appropriate observations of planetary boundary layer (PBL), the associations between synoptic conditions, PBL, and pollution there are not yet fully understood. Thus, systematic analyses were conducted using the fine-resolution soundings, surface meteorological measurements, and aerosol observations in Wuhan during summer for the period 2013-2016, in combination with T-mode principal component analysis and simulations of backward trajectory. The results showed that the variations of boundary layer height (BLH) not only modulated the diurnal variation of PM 2.5 concentration in Wuhan, but also the daily pollution level. Five different synoptic patterns during summer in Wuhan were identified from reanalysis geopotential height fields. Among these synoptic patterns, two types characterized by northeasterly prevailing winds, were found to be associated with heavy pollution in Wuhan. Driven by the northeasterly winds, the polluted air mass from the heavily polluted regions could be easily transported to Wuhan, such as North China Plain and Yangtze River Delta. Such regional transports of pollutants must be partly responsible for the aerosol pollution in Wuhan. In addition, these two synoptic patterns were also featured by the relatively high cloud cover and low boundary layer height in Wuhan, which would favor the occurrence of pollution there. Overall, this study has important implications for understanding the important roles of meteorological factors in modulating aerosol pollution in central China. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Cumulative ventilation air drying potential as an indication of dry mass content in wastewater sludge in a thin-layer solar drying facility

    NASA Astrophysics Data System (ADS)

    Krawczyk, Piotr

    2013-12-01

    Controlling low-temperature drying facilities which utilise nonprepared air is quite difficult, due to very large variability of ventilation air parameters - both in daily and seasonal cycles. The paper defines the concept of cumulative drying potential of ventilation air and presents experimental evidence that there is a relation between this parameter and condition of the dried matter (sewage sludge). Knowledge on current dry mass content in the dried matter (sewage sludge) provides new possibilities for controlling such systems. Experimental data analysed in the paper was collected in early 2012 during operation of a test solar drying facility in a sewage treatment plant in Błonie near Warsaw, Poland.

  5. Transparency of a magnetic cloud boundary for cosmic rays

    NASA Astrophysics Data System (ADS)

    Petukhov, I. S.; Petukhov, S. I.

    2013-02-01

    We have suggested a model of magnetic cloud presented as a torus with magnetic flux rope structure situated inside the interplanetary corona mass ejecta expanding radially away from the Sun through the interplanetary medium. The magnetic field of the torus changing during its propagation has been obtained. The magnetic cloud — solar wind boundary transparency for cosmic rays with different energies depending on the cloud orientation and properties of the torus magnetic field has been determined by means of calculation of the particle trajectories at the boundary.

  6. Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry.

    PubMed

    Hengel, Matt; Lee, P

    2014-03-01

    Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil, chlorthal-dimethyl, cycloate, dicloran, dicofol, EPTC, ethalfluralin, iprodione, mefenoxam, metolachlor, PCNB, permethrin, pronamide, simazine, trifluralin, and vinclozolin. A GC with a flame photometric detector was used to determine chlorpyrifos, chlorpyrifos oxon, diazinon, diazinon oxon, dimethoate, dimethoate oxon, fonophos, fonophos oxon, malathion, malathion oxon, naled, and oxydemeton. Trapping efficiencies ranged from 78 to 92 % for low level (0.5 μg) and 37-104 % for high level (50 and 100 μg) recoveries. Little to no degradation of compounds occurred over 31 days; recoveries ranged from 78 to 113 %. In the California Department of Food and Agriculture (CDFA) method, pesticides were detected by analyzing the extract by GC-MS to determine chlorothalonil, chlorpyrifos, cypermethrin, dichlorvos, dicofol, endosulfan 1, endosulfan sulfate, oxyfluorfen, permethrin, propargite, and trifluralin. A liquid chromatograph coupled to a MS was used to determine azinphos-methyl, chloropyrifos oxon, DEF, diazinon, diazinon oxon, dimethoate, dimethoate oxon, diuron, EPTC, malathion, malathion oxon, metolachlor, molinate, norflurazon, oryzalin, phosmet, propanil, simazine and thiobencarb. Trapping efficiencies for compounds determined by the CDFA method ranged from 10 to 113, 22 to 114, and 56 to 132 % for 10, 5, and 2 μg spikes, respectively. Storage tests yielded 70-170 % recovery for up to 28 days. These multiresidue methods represent flexible, sensitive, accurate, and cost-effective ways to determine residues of various pesticides in ambient air.

  7. Influence of the outer boundary condition on models of AGB stars

    NASA Astrophysics Data System (ADS)

    Wagstaff, G.; Weiss, A.

    2018-07-01

    Current implementations of the stellar atmosphere typically derive boundary conditions for the interior model from either grey plane-parallel atmospheres or scaled solar atmospheres, neither of which can be considered to have appropriate underlying assumptions for the Thermally Pulsing Asymptotic Giant Branch (TP-AGB). This paper discusses the treatment and influence of the outer boundary condition within stellar evolution codes, and the resulting effects on the AGB evolution. The complex interaction of processes, such as the third dredge up and mass-loss, governing the TP-AGB can be affected by varying the treatment of this boundary condition. Presented here are the results from altering the geometry, opacities, and the implementation of a grid of MARCS/COMARCS model atmospheres in order to improve this treatment. Although there are changes in the TP-AGB evolution, observable quantities, such as the final core mass, are not significantly altered as a result of the change of atmospheric treatment. During the course of the investigation, a previously unseen phenomenon in the AGB models was observed and further investigated. This is believed to be physical, although arising from specific conditions which make its presence unlikely. If it were present in stars, this phenomenon would increase the carbon-star lifetime above 10 Myr and increase the final core mass by ˜0.1 M⊙ in the narrow initial-mass range where it was observed (˜2-2.3 M⊙).

  8. Influence of the Outer Boundary Condition on models of AGB stars

    NASA Astrophysics Data System (ADS)

    Wagstaff, G.; Weiss, A.

    2018-04-01

    Current implementations of the stellar atmosphere typically derive boundary conditions for the interior model from either grey plane-parallel atmospheres or scaled solar atmospheres, neither of which can be considered to have appropriate underlying assumptions for the Thermally Pulsing Asymptotic Giant Branch (TP-AGB). This paper discusses the treatment and influence of the outer boundary condition within stellar evolution codes, and the resulting effects on the AGB evolution. The complex interaction of processes, such as the third dredge up and mass loss, governing the TP-AGB can be affected by varying the treatment of this boundary condition. Presented here are the results from altering the geometry, opacities and the implementation of a grid of MARCS/COMARCS model atmospheres in order to improve this treatment. Although there are changes in the TP-AGB evolution, observable quantities, such as the final core mass, are not significantly altered as a result of the change of atmospheric treatment. During the course of the investigation, a previously unseen phenomena in the AGB models was observed and further investigated. This is believed to be physical, although arising from specific conditions which make its presence unlikely. If it were present in stars, this phenomenon would increase the carbon-star lifetime above 10Myr and increase the final core mass by ˜0.1M⊙ in the narrow initial-mass range where it was observed (˜2 - 2.3M⊙).

  9. Meson effective mass in the isospin medium in hard-wall AdS/QCD model

    NASA Astrophysics Data System (ADS)

    Mamedov, Shahin

    2016-02-01

    We study a mass splitting of the light vector, axial-vector, and pseudoscalar mesons in the isospin medium in the framework of the hard-wall model. We write an effective mass definition for the interacting gauge fields and scalar field introduced in gauge field theory in the bulk of AdS space-time. Relying on holographic duality we obtain a formula for the effective mass of a boundary meson in terms of derivative operator over the extra bulk coordinate. The effective mass found in this way coincides with the one obtained from finding of poles of the two-point correlation function. In order to avoid introducing distinguished infrared boundaries in the quantization formula for the different mesons from the same isotriplet we introduce extra action terms at this boundary, which reduces distinguished values of this boundary to the same value. Profile function solutions and effective mass expressions were found for the in-medium ρ , a_1, and π mesons.

  10. Health effects of SRS non-radiological air emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stewart, J.

    1997-06-16

    This report examines the potential health effects of non radiological emissions to the air resulting from operations at the Savannah River Site (SRS). The scope of this study was limited to the 55 air contaminants for which the US Environmental Protection Agency (EPA) has quantified risk by determining unit risk factors (excess cancer risks) and/or reference concentrations (deleterious non cancer risks). Potential health impacts have been assessed in relation to the maximally exposed individual. This is a hypothetical person who resides for a lifetime at the SRS boundary. The most recent (1994) quality assured SRS emissions data available were used.more » Estimated maximum site boundary concentrations of the air contaminants were calculated using air dispersion modeling and 24-hour and annual averaging times. For the emissions studied, the excess cancer risk was found to be less than the generally accepted risk level of 1 in 100,000 and, in most cases, was less than 1 in 1,000,000. Deleterious non cancer effects were also found to be very unlikely.« less

  11. Einstein-Gauss-Bonnet theory of gravity: The Gauss-Bonnet-Katz boundary term

    NASA Astrophysics Data System (ADS)

    Deruelle, Nathalie; Merino, Nelson; Olea, Rodrigo

    2018-05-01

    We propose a boundary term to the Einstein-Gauss-Bonnet action for gravity, which uses the Chern-Weil theorem plus a dimensional continuation process, such that the extremization of the full action yields the equations of motion when Dirichlet boundary conditions are imposed. When translated into tensorial language, this boundary term is the generalization to this theory of the Katz boundary term and vector for general relativity. The boundary term constructed in this paper allows to deal with a general background and is not equivalent to the Gibbons-Hawking-Myers boundary term. However, we show that they coincide if one replaces the background of the Katz procedure by a product manifold. As a first application we show that this Einstein Gauss-Bonnet Katz action yields, without any extra ingredients, the expected mass of the Boulware-Deser black hole.

  12. The relation between air pollution data and planetary boundary layer quantities in a complex coastal industrial site nearby populated areas.

    NASA Astrophysics Data System (ADS)

    Mammarella, M. C.; Grandoni, G.; Fernando, J.; Cacciani, M.; di Sabatino, S.; Favaron, M.; Fedele, P.

    2010-09-01

    The connection among boundary layer phenomena, atmospheric pollutant dynamics and human health is an established fact, taking many different forms depending on local characteristics, including slope and position of relief and/or coastline, surface roughness, emission patterns. The problem is especially interesting in complex and coastal terrain, where concurrence of slope and sea induced local circulation interact reciprocally, yielding a complex pattern whose interpretation may go beyond pure modeling, and devise specific measurements among which the planetary boundary layer (PBL) height. An occasion for studying this important theme has been offered by Regione Molise and Valle del Biferno Consortium (COSIB), for the specific case of the industrial complex of Valle del Biferno, 3 km inland of Termoli, in Central Italy, on the Adriatic coast. The local government, sensitive to air quality and public health in the industrial area, together with COSIB has co-financed a research project aimed at gaining knowledge about local meteorology, PBL phenomena and atmospheric pollutant dispersion in the area. Expected results include new air quality monitoring and control methodologies in Valle del Biferno for a sustainable development in an environmentally respectful manner, at a site already characterized by a high environmental and landscape value. The research project, developed by ENEA, has began in 2007 and will conclude in December 2010. Project activities involve research group from Europe, the United States of America, and the Russian Federation. Scientific and practical results will be published and presented in occasion of the final workshop to be held on project conclusion. The scientific interest of Valle del Biferno case stems from the specific local characteristics at site. Given the valley orientation respect to mean synoptic circulation, local effects as sea and slope breezes are dominant, and a complex wind regime develops affecting local transport and

  13. Measurement of spatial and temporal variation in volatile hazardous air pollutants in Tacoma, Washington, using a mobile membrane introduction mass spectrometry (MIMS) system.

    PubMed

    Davey, Nicholas G; Fitzpatrick, Cole T E; Etzkorn, Jacob M; Martinsen, Morten; Crampton, Robert S; Onstad, Gretchen D; Larson, Timothy V; Yost, Michael G; Krogh, Erik T; Gilroy, Michael; Himes, Kathy H; Saganić, Erik T; Simpson, Christopher D; Gill, Christopher G

    2014-09-19

    The objective of this study was to use membrane introduction mass spectrometry (MIMS), implemented on a mobile platform, in order to provide real-time, fine-scale, temporally and spatially resolved measurements of several hazardous air pollutants. This work is important because there is now substantial evidence that fine-scale spatial and temporal variations of air pollutant concentrations are important determinants of exposure to air pollution and adverse health outcomes. The study took place in Tacoma, WA during periods of impaired air quality in the winter and summer of 2008 and 2009. Levels of fine particles were higher in winter compared to summer, and were spatially uniform across the study area. Concentrations of vapor phase pollutants measured by membrane introduction mass spectrometry (MIMS), notably benzene and toluene, had relatively uniform spatial distributions at night, but exhibited substantial spatial variation during the day-daytime levels were up to 3-fold higher at traffic-impacted locations compared to a reference site. Although no direct side-by-side comparison was made between the MIMS system and traditional fixed site monitors, the MIMS system typically reported higher concentrations of specific VOCs, particularly benzene, ethylbenzene and naphthalene, compared to annual average concentrations obtained from SUMA canisters and gas chromatographic analysis at the fixed sites.

  14. Squeeze-Film Air Damping of a Five-Axis Electrostatic Bearing for Rotary Micromotors

    PubMed Central

    Wang, Shunyue; Han, Fengtian; Sun, Boqian; Li, Haixia

    2017-01-01

    Air-film damping, which dominates over other losses, plays a significant role in the dynamic response of many micro-fabricated devices with a movable mass suspended by various bearing mechanisms. Modeling the damping characteristics accurately will be greatly helpful to the bearing design, control, and test in various micromotor devices. This paper presents the simulated and experimental squeeze-film air damping results of an electrostatic bearing for use in a rotary high-speed micromotor. It is shown that the boundary condition to solve the three-dimensional Reynolds equation, which governs the squeeze-film damping in the air gap between the rotor and its surrounding stator sealed in a three-layer evacuated cavity, behaves with strong cross-axis coupling characteristics. To accurately characterize the damping effect, a set of multiphysics finite-element simulations are performed by computing both the rotor velocity and the distribution of the viscous damping force acting on the rotor. The damping characteristics varying with several key structure parameters are simulated and discussed to optimize the device structure for desirable rotor dynamics. An electrical measurement method is also proposed and applied to validate the numerical results of the damping coefficients experimentally. Given that the frequency response of the electric bearing is critically dependent on the damping coefficients at atmospheric pressure, a solution to the air-film damping measurement problem is presented by taking approximate curve fitting of multi-axis experimental frequency responses. The measured squeeze-film damping coefficients for the five-axis electric bearing agrees well with the numerical solutions. This indicates that numerical multiphysics simulation is an effective method to accurately examine the air-film damping effect for complex device geometry and arbitrary boundary condition. The accurate damping coefficients obtained by FEM simulation will greatly simplify the design

  15. Mass predictions from the Garvey-Kelson mass relations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jaenecke, J.; Masson, P.J.

    Part A: The transverse Garvey-Kelson mass relation represents a homogeneous third-order partial difference equation. Procedures are described for estimating masses of nuclei with Ngreater than or equal toZ from the most general solution of this difference equation subject to a chi/sup 2/ minimization, using the recent atomic mass adjustment of Wapstra, Audi, and Hoekstra as a boundary condition. A judicious division of the input data in subsets of neutron-rich and proton-rich nuclei had to be introduced to reduce systematic errors in long-range extrapolations. Approximately 5600 mass-excess values for nuclei with 2less than or equal toZless than or equal to103, 4lessmore » than or equal toNless than or equal to157, and Ngreater than or equal toZ (except N = Z odd for A<40) have been calculated. The standard deviation for reproducing the known mass-excess values is sigma/sub m/approx. =103 keV.« less

  16. The dependence of carbide morphology on grain boundary character in the highly twinned Alloy 690

    NASA Astrophysics Data System (ADS)

    Li, Hui; Xia, Shuang; Zhou, Bangxin; Chen, Wenjue; Hu, Changliang

    2010-04-01

    The dependence of morphology of grain boundary carbides on grain boundary character in Alloy 690 (Ni-30Cr-10Fe, mass fraction, %) with high fraction of low Σ coincidence site lattice (CSL) grain boundaries was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Some of the surface grains were removed by means of deep etching. It was observed that carbides grow dendritically at grain boundaries. The carbide bars observed near incoherent twin boundaries and twin related Σ9 grain boundaries are actually secondary dendrites of the carbides on these boundaries. Higher order dendrites could be observed on random grain boundaries, however, no bar-like dendrites were observed near Σ27 grain boundaries and random grain boundaries. The morphology difference of carbides precipitated at grain boundaries with different characters is discussed based on the experimental results in this paper.

  17. Effects of mass on aircraft sidearm controller characteristics

    NASA Technical Reports Server (NTRS)

    Wagner, Charles A.

    1994-01-01

    When designing a flight simulator, providing a set of low mass variable-characteristic pilot controls can be very difficult. Thus, a strong incentive exists to identify the highest possible mass that will not degrade the validity of a simulation. The NASA Dryden Flight Research Center has conducted a brief flight program to determine the maximum acceptable mass (system inertia) of an aircraft sidearm controller as a function of force gradient. This information is useful for control system design in aircraft as well as development of suitable flight simulator controls. A modified Learjet with a variable-characteristic sidearm controller was used to obtain data. A boundary was defined between mass considered acceptable and mass considered unacceptable to the pilot. This boundary is defined as a function of force gradient over a range of natural frequencies. This investigation is limited to a study of mass-frequency characteristics only. Results of this investigation are presented in this paper.

  18. Performance analysis of an air drier for a liquid dehumidifier solar air conditioning system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Queiroz, A.G.; Orlando, A.F.; Saboya, F.E.M.

    1988-05-01

    A model was developed for calculating the operating conditions of a non-adiabatic liquid dehumidifier used in solar air conditioning systems. In the experimental facility used for obtaining the data, air and triethylene glycol circulate countercurrently outside staggered copper tubes which are the filling of an absorption tower. Water flows inside the copper tubes, thus cooling the whole system and increasing the mass transfer potential for drying air. The methodology for calculating the mass transfer coefficient is based on the Merkel integral approach, taking into account the lowering of the water vapor pressure in equilibrium with the water glycol solution.

  19. Simulations of QCD and QED with C* boundary conditions

    NASA Astrophysics Data System (ADS)

    Hansen, Martin; Lucini, Biagio; Patella, Agostino; Tantalo, Nazario

    2018-03-01

    We present exploratory results from dynamical simulations of QCD in isolation, as well as QCD coupled to QED, with C* boundary conditions. In finite volume, the use of C* boundary conditions allows for a gauge invariant and local formulation of QED without zero modes. In particular we show that the simulations reproduce known results and that masses of charged mesons can be extracted in a completely gauge invariant way. For the simulations we use a modified version of the HiRep code. The primary features of the simulation code are presented and we discuss some details regarding the implementation of C* boundary conditions and the simulated lattice action. Preprint: CP3-Origins-2017-046 DNRF90, CERN-TH-2017-214

  20. 40 CFR 81.241 - Southwestern Mountains-Augustine Plains Intrastate Air Quality Control Region.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Quality Control Region (New Mexico) consists of the territorial area encompassed by the boundaries of the... Plains Intrastate Air Quality Control Region. 81.241 Section 81.241 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) DESIGNATION OF AREAS FOR AIR QUALITY...

  1. 40 CFR 81.241 - Southwestern Mountains-Augustine Plains Intrastate Air Quality Control Region.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Quality Control Region (New Mexico) consists of the territorial area encompassed by the boundaries of the... Plains Intrastate Air Quality Control Region. 81.241 Section 81.241 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) DESIGNATION OF AREAS FOR AIR QUALITY...

  2. Kinetics and thermodynamics associated with Bi adsorption transitions at Cu and Ni grain boundaries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tai, Kaiping; Feng, Lin; Dillon, Shen J.

    The grain boundary diffusivity of Au in Cu and Cu-Bi, and Cu in Ni and Ni-Bi are characterized by secondary ion mass spectroscopy depth profiling. Samples are equilibrated in a Bi containing atmosphere at temperatures above and below the onset of grain boundary adsorption transitions, sometimes called complexion transitions. A simple thermo-kinetic model is used to estimate the relative entropic contributions to the grain boundary energies. The results indicate that the entropy term plays a major role in promoting thermally and chemically induced grain boundary complexion transition.

  3. 75 FR 3392 - Outer Continental Shelf Air Regulations Consistency Update for Alaska

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-21

    ... 40 CFR part 55,\\1\\ which established requirements to control air pollution from OCS sources in order... air pollution from OCS sources located within 25 miles of States' seaward boundaries that are the same... the Act requires that EPA establish requirements to control air pollution from OCS sources located...

  4. EM algorithm applied for estimating non-stationary region boundaries using electrical impedance tomography

    NASA Astrophysics Data System (ADS)

    Khambampati, A. K.; Rashid, A.; Kim, B. S.; Liu, Dong; Kim, S.; Kim, K. Y.

    2010-04-01

    EIT has been used for the dynamic estimation of organ boundaries. One specific application in this context is the estimation of lung boundaries during pulmonary circulation. This would help track the size and shape of lungs of the patients suffering from diseases like pulmonary edema and acute respiratory failure (ARF). The dynamic boundary estimation of the lungs can also be utilized to set and control the air volume and pressure delivered to the patients during artificial ventilation. In this paper, the expectation-maximization (EM) algorithm is used as an inverse algorithm to estimate the non-stationary lung boundary. The uncertainties caused in Kalman-type filters due to inaccurate selection of model parameters are overcome using EM algorithm. Numerical experiments using chest shaped geometry are carried out with proposed method and the performance is compared with extended Kalman filter (EKF). Results show superior performance of EM in estimation of the lung boundary.

  5. Impact of Trans-Boundary Emissions on Modelled Air Pollution in Canada

    NASA Astrophysics Data System (ADS)

    Pavlovic, Radenko; Moran, Mike; Zhang, Junhua; Zheng, Qiong; Menard, Sylvain; Anselmo, David; Davignon, Didier

    2014-05-01

    The operational air quality model GEM-MACH is run twice daily at the Canadian Meteorological Centre in Montreal, Quebec to produce 48-hour forecasts of hourly O3, NO2, and PM2.5 fields over a North American domain. The hourly gridded anthropogenic emissions fields needed by GEM-MACH are currently based on the 2006 Canadian emissions inventory, a 2012 projected U.S. inventory, and the 1999 Mexican inventory. The Sparse Matrix Operator Kernel Emissions (SMOKE) processing package was used to process these three national emissions inventories to create the GEM-MACH emissions fields. While Canada is the second-largest country in the world by total area, its population and its emissions of criteria contaminants are both only about one-tenth of U.S. values and roughly 80% of the Canadian population lives within 150 km of the international border with the U.S. As a consequence, transboundary transport of air pollution has a major impact on air quality in Canada. To quantify the impact of non-Canadian emissions on forecasted pollutant levels in Canada, the following two tests were performed: (a) all U.S. and Mexican anthropogenic emissions were switched off; and (b) anthropogenic emissions from the southernmost tier of U.S. states and Mexico were switched off. These sensitivity tests were performed for the summer and winter periods of 2012 or 2011. The results obtained show that the impact of non-Canadian sources on forecasted pollution is generally larger in summer than in winter, especially in south-eastern parts of Canada. For the three pollutants considered in the Canadian national Air Quality Health Index, PM2.5 is impacted the most (up to 80%) and NO2 the least (<10%). Emissions from the southern U.S. and Mexico do impact Canadian air quality, but the sign may change depending on the season (i.e., increase vs. decrease), reflecting chemical processing en route.

  6. YSZ thin films with minimized grain boundary resistivity

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mills, Edmund M.; Kleine-Boymann, Matthias; Janek, Juergen

    2016-03-31

    In recent years, interface engineering of solid electrolytes has been explored to increase their ionic conductivity and improve the performance of solid oxide fuel cells and other electrochemical power sources. It has been observed that the ionic conductivity of epitaxially grown thin films of some electrolytes is dramatically enhanced, which is often attributed to effects (e. g. strain-induced mobility changes) at the heterophase boundary with the substrate. Still largely unexplored is the possibility of manipulation of grain boundary resistivity in polycrystalline solid electrolyte films, clearly a limiting factor in their ionic conductivity. Here we report that the ionic conductivity ofmore » yttria stabilized zirconia thin films with nano-­ columnar grains grown on a MgO substrate nearly reaches that of the corresponding single crystal when the thickness of the films becomes less than roughly 8 nm (smaller by a factor of three at 500°C). Using impedance spectroscopy, the grain boundary resistivity was probed as a function of film thickness. The resistivity of the grain boundaries near the film- substrate interface and film surface (within 4 nm of each) was almost entirely eliminated. This minimization of grain boundary resistivity is attributed to Mg2+ diffusion from the MgO substrate into the YSZ grain boundaries, which is supported by time of flight secondary ion mass spectroscopy measurements. We suggest grain boundary “design” as an attractive method to obtain highly conductive solid electrolyte thin films.« less

  7. YSZ thin films with minimized grain boundary resistivity

    DOE PAGES

    Mills, Edmund M.; Kleine-Boymann, Matthias; Janek, Juergen; ...

    2016-03-31

    In recent years, interface engineering of solid electrolytes has been explored to increase their ionic conductivity and improve the performance of solid oxide fuel cells and other electrochemical power sources. It has been observed that the ionic conductivity of epitaxially grown thin films of some electrolytes is dramatically enhanced, which is often attributed to effects (e.g. strain-induced mobility changes) at the heterophase boundary with the substrate. Still largely unexplored is the possibility of manipulation of grain boundary resistivity in polycrystalline solid electrolyte films, clearly a limiting factor in their ionic conductivity. Here in this paper, we report that the ionicmore » conductivity of yttria stabilized zirconia thin films with nano-columnar grains grown on a MgO substrate nearly reaches that of the corresponding single crystal when the thickness of the films becomes less than roughly 8 nm (smaller by a factor of three at 500 °C). Using impedance spectroscopy, the grain boundary resistivity was probed as a function of film thickness. The resistivity of the grain boundaries near the film–substrate interface and film surface (within 4 nm of each) was almost entirely eliminated. This minimization of grain boundary resistivity is attributed to Mg 2+ diffusion from the MgO substrate into the YSZ grain boundaries, which is supported by time of flight secondary ion mass spectroscopy measurements. We suggest grain boundary “design” as an attractive method to obtain highly conductive solid electrolyte thin films.« less

  8. Sea spray contributions to the air-sea fluxes at moderate and hurricane wind speeds

    NASA Astrophysics Data System (ADS)

    Mueller, J. A.; Veron, F.

    2009-12-01

    At sufficiently high wind speed conditions, the surface of the ocean separates to form a substantial number of sea spray drops, which can account for a significant fraction of the total air-sea surface area and thus make important contributions to the aggregate air-sea momentum, heat and mass fluxes. Although consensus around the qualitative impacts of these drops has been building in recent years, the quantification of their impacts has remained elusive. Ultimately, the spray-mediated fluxes depend on three controlling factors: the number and size of drops formed at the surface, the duration of suspension within the atmospheric marine boundary layer, and the rate of momentum, heat and mass transfer between the drops and the atmosphere. While the latter factor can be estimated from an established, physically-based theory, the estimates for the former two are not well established. Using a recent, physically-based model of the sea spray source function along with the results from Lagrangian stochastic simulations of individual drops, we estimate the aggregate spray-mediated fluxes, finding reasonable agreement with existing models and estimates within the empirical range of wind speed conditions. At high wind speed conditions that are outside the empirical range, however, we find somewhat lower spray-mediated fluxes than previously reported in the literature, raising new questions about the relative air-sea fluxes at high wind speeds as well as the development and sustainment of hurricanes.

  9. Identification of aerosol types over an urban site based on air-mass trajectory classification

    NASA Astrophysics Data System (ADS)

    Pawar, G. V.; Devara, P. C. S.; Aher, G. R.

    2015-10-01

    Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18°32‧N; 73°49‧E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD500 nm) and Ångström exponent (AE, α). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD500 nm scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (τpλ = 0.43 ± 0.13) and high AE (α = 1.19 ± 0.15). These values imply the presence of accumulation/sub-micron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (τpλ = 0.61 ± 0.21), and low AE (α = 0.54 ± 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant.

  10. Wake Dynamics in the Atmospheric Boundary Layer Over Complex Terrain

    NASA Astrophysics Data System (ADS)

    Markfort, Corey D.

    The goal of this research is to advance our understanding of atmospheric boundary layer processes over heterogeneous landscapes and complex terrain. The atmospheric boundary layer (ABL) is a relatively thin (˜ 1 km) turbulent layer of air near the earth's surface, in which most human activities and engineered systems are concentrated. Its dynamics are crucially important for biosphere-atmosphere couplings and for global atmospheric dynamics, with significant implications on our ability to predict and mitigate adverse impacts of land use and climate change. In models of the ABL, land surface heterogeneity is typically represented, in the context of Monin-Obukhov similarity theory, as changes in aerodynamic roughness length and surface heat and moisture fluxes. However, many real landscapes are more complex, often leading to massive boundary layer separation and wake turbulence, for which standard models fail. Trees, building clusters, and steep topography produce extensive wake regions currently not accounted for in models of the ABL. Wind turbines and wind farms also generate wakes that combine in complex ways to modify the ABL. Wind farms are covering an increasingly significant area of the globe and the effects of large wind farms must be included in regional and global scale models. Research presented in this thesis demonstrates that wakes caused by landscape heterogeneity must be included in flux parameterizations for momentum, heat, and mass (water vapor and trace gases, e.g. CO2 and CH4) in ABL simulation and prediction models in order to accurately represent land-atmosphere interactions. Accurate representation of these processes is crucial for the predictions of weather, air quality, lake processes, and ecosystems response to climate change. Objectives of the research reported in this thesis are: 1) to investigate turbulent boundary layer adjustment, turbulent transport and scalar flux in wind farms of varying configurations and develop an improved

  11. Finite-element numerical modeling of atmospheric turbulent boundary layer

    NASA Technical Reports Server (NTRS)

    Lee, H. N.; Kao, S. K.

    1979-01-01

    A dynamic turbulent boundary-layer model in the neutral atmosphere is constructed, using a dynamic turbulent equation of the eddy viscosity coefficient for momentum derived from the relationship among the turbulent dissipation rate, the turbulent kinetic energy and the eddy viscosity coefficient, with aid of the turbulent second-order closure scheme. A finite-element technique was used for the numerical integration. In preliminary results, the behavior of the neutral planetary boundary layer agrees well with the available data and with the existing elaborate turbulent models, using a finite-difference scheme. The proposed dynamic formulation of the eddy viscosity coefficient for momentum is particularly attractive and can provide a viable alternative approach to study atmospheric turbulence, diffusion and air pollution.

  12. A second-order bulk boundary-layer model

    NASA Technical Reports Server (NTRS)

    Randall, David A.; Shao, Qingqiu; Moeng, Chin-Hoh

    1992-01-01

    Bulk mass-flux models represent the large eddies that are primarily responsible for the turbulent fluxes in the planetary boundary layer as convective circulations, with an associated convective mass flux. In order for such models to be useful, it is necessary to determine the fractional area covered by rising motion in the convective circulations. This fraction can be used as an estimate of the cloud amount, under certain conditions. 'Matching' conditions have been developed that relate the convective mass flux to the ventilation and entrainment mass fluxes. These are based on conservation equations for the scalar means and variances in the entrainment and ventilation layers. Methods are presented to determine both the fractional area covered by rising motion and the convective mass flux. The requirement of variance balance is used to relax the 'well-mixed' assumption. The vertical structures of the mean state and the turbulent fluxes are determined analytically. Several aspects of this simple model's formulation are evaluated using results from large-eddy simulations.

  13. Observed OH and HO2 concentrations in the upper troposphere inside and outside of Asian monsoon influenced air.

    NASA Astrophysics Data System (ADS)

    Marno, D. R.; Künstler, C.; Hens, K.; Tatum Ernest, C.; Broch, S.; Fuchs, H.; Martinez, M.; Bourtsoukidis, E.; Williams, J.; Holland, F.; Hofzumahaus, A.; Tomsche, L.; Fischer, H.; Klausner, T.; Schlager, H.; Eirenschmalz, L.; Stratmann, G.; Stock, P.; Ziereis, H.; Roiger, A.; Bohn, B.; Zahn, A.; Wahner, A.; Lelieveld, J.; Harder, H.

    2016-12-01

    The Asian monsoon convectively transports pollutants like volatile organic compounds (VOCs), NOx, and SO2 from the boundary layer over South Asia into the upper troposphere where they can potentially enter the stratosphere, or be dispersed globally. Therefore, it is crucial to understand the oxidizing capacity of this system regarding the rate of aerosol formation, and conversion of pollutants into compounds that have much shorter atmospheric lifetimes. OH plays a central role in this oxidation process. During the OMO-ASIA campaign in the summer of 2015, OH and HO2 were measured onboard the High Altitude Long-Range (HALO) Research Aircraft. Two laser-induced fluorescence instruments based on the fluorescence assay by gas expansion technique (LIF-FAGE) had been deployed, the AIR-LIF instrument from Forschungszentrum Jülich GmbH and the HORUS instrument from the Max Planck Institute for Chemistry, Mainz. To measure the chemical background of OH potentially produced inside the HORUS instrument from highly oxidized VOCs, atmospheric OH is scavenged by an Inlet Pre-injector (IPI) system. This was the first time an IPI system was implemented within an airborne LIF-FAGE instrument measuring OH and HO2. Throughout this campaign OH and HO2 were measured at 12 to 15km within the Asian monsoon anticyclone. These measurements have been contrasted by probing air outside the anticyclone in air masses influenced by North American emissions, and in very clean air masses originated from the southern hemisphere.

  14. The boundary layer moist static energy budget: Convection picks up moisture and leaves footprints in the marine boundary layer

    NASA Astrophysics Data System (ADS)

    de Szoeke, S. P.

    2017-12-01

    Averaged over the tropical marine boundary layer (BL), 130 W m-2 turbulent surface moist static energy (MSE) flux, 120 W m-2 of which is evaporation, is balanced by upward MSE flux at the BL top due to 1) incorporation of cold air by downdrafts from deep convective clouds, and 2) turbulent entrainment of dry air into the BL. Cold saturated downdraft air, and warm clear air entrained into the BL have distinct thermodynamic properties. This work observationally quantifies their respective MSE fluxes in the central Indian Ocean in 2011, under different convective conditions of the intraseasonal (40-90 day) Madden Julian oscillation (MJO). Under convectively suppressed conditions, entrainment and downdraft fluxes export equal shares (60 W m-2) of MSE from the BL. Downdraft fluxes are more variable, increasing for stronger convection. In the convectively active phase of the MJO, downdrafts export 90 W m-2 from the BL, compared to 40 W m-2 by entrainment. These processes that control the internal, latent (condensation), and MSE of the tropical marine atmospheric BL determine the parcel buoyancy and strength of tropical deep convection.

  15. Influence of electrical boundary conditions on molecular dynamics simulations of ionic liquid electrosprays.

    PubMed

    Borner, Arnaud; Wang, Pengxiang; Levin, Deborah A

    2014-12-01

    Molecular dynamics (MD) simulations are coupled to solutions of Poisson's equation to study the effects of the electrical boundary conditions on the emission modes of an electrospray thruster fed with an ionic liquid. A comparison of a new tip boundary condition with an analytical model based on a semihyperboloidal shape offers good agreement, although the analytical model overestimates the maximum value of the tangential electric field since it does not take into account the space charge that reduces the field at the liquid surface. It is found that a constant electric field model gives similar agreement to the more rigorous and computationally expensive tip boundary condition at lower flow rates. However, at higher mass flow rates the constant electric field produces extruded particles with higher Coulomb energy per ion, consistent with droplet formation. Furthermore, the MD simulations show that ion emission sites differ based on the boundary condition and snapshots offer an explanation as to why some boundary condition models will predict emission in a purely ionic mode, whereas others suggest a mixed ion-droplet regime. Finally, specific impulses and thrusts are compared for the different models and are found to vary up to 30% due to differences in the average charge to mass ratio.

  16. Influence of electrical boundary conditions on molecular dynamics simulations of ionic liquid electrosprays

    NASA Astrophysics Data System (ADS)

    Borner, Arnaud; Wang, Pengxiang; Levin, Deborah A.

    2014-12-01

    Molecular dynamics (MD) simulations are coupled to solutions of Poisson's equation to study the effects of the electrical boundary conditions on the emission modes of an electrospray thruster fed with an ionic liquid. A comparison of a new tip boundary condition with an analytical model based on a semihyperboloidal shape offers good agreement, although the analytical model overestimates the maximum value of the tangential electric field since it does not take into account the space charge that reduces the field at the liquid surface. It is found that a constant electric field model gives similar agreement to the more rigorous and computationally expensive tip boundary condition at lower flow rates. However, at higher mass flow rates the constant electric field produces extruded particles with higher Coulomb energy per ion, consistent with droplet formation. Furthermore, the MD simulations show that ion emission sites differ based on the boundary condition and snapshots offer an explanation as to why some boundary condition models will predict emission in a purely ionic mode, whereas others suggest a mixed ion-droplet regime. Finally, specific impulses and thrusts are compared for the different models and are found to vary up to 30% due to differences in the average charge to mass ratio.

  17. Nondestructive natural gas hydrate recovery driven by air and carbon dioxide.

    PubMed

    Kang, Hyery; Koh, Dong-Yeun; Lee, Huen

    2014-10-14

    Current technologies for production of natural gas hydrates (NGH), which include thermal stimulation, depressurization and inhibitor injection, have raised concerns over unintended consequences. The possibility of catastrophic slope failure and marine ecosystem damage remain serious challenges to safe NGH production. As a potential approach, this paper presents air-driven NGH recovery from permeable marine sediments induced by simultaneous mechanisms for methane liberation (NGH decomposition) and CH₄-air or CH₄-CO₂/air replacement. Air is diffused into and penetrates NGH and, on its surface, forms a boundary between the gas and solid phases. Then spontaneous melting proceeds until the chemical potentials become equal in both phases as NGH depletion continues and self-regulated CH4-air replacement occurs over an arbitrary point. We observed the existence of critical methane concentration forming the boundary between decomposition and replacement mechanisms in the NGH reservoirs. Furthermore, when CO₂ was added, we observed a very strong, stable, self-regulating process of exchange (CH₄ replaced by CO₂/air; hereafter CH₄-CO₂/air) occurring in the NGH. The proposed process will work well for most global gas hydrate reservoirs, regardless of the injection conditions or geothermal gradient.

  18. Late Maastrichtian pterosaurs from North Africa and mass extinction of Pterosauria at the Cretaceous-Paleogene boundary

    PubMed Central

    Martill, David M.; Andres, Brian

    2018-01-01

    Pterosaurs were the first vertebrates to evolve powered flight and the largest animals to ever take wing. The pterosaurs persisted for over 150 million years before disappearing at the end of the Cretaceous, but the patterns of and processes driving their extinction remain unclear. Only a single family, Azhdarchidae, is definitively known from the late Maastrichtian, suggesting a gradual decline in diversity in the Late Cretaceous, with the Cretaceous–Paleogene (K-Pg) extinction eliminating a few late-surviving species. However, this apparent pattern may simply reflect poor sampling of fossils. Here, we describe a diverse pterosaur assemblage from the late Maastrichtian of Morocco that includes not only Azhdarchidae but the youngest known Pteranodontidae and Nyctosauridae. With 3 families and at least 7 species present, the assemblage represents the most diverse known Late Cretaceous pterosaur assemblage and dramatically increases the diversity of Maastrichtian pterosaurs. At least 3 families—Pteranodontidae, Nyctosauridae, and Azhdarchidae—persisted into the late Maastrichtian. Late Maastrichtian pterosaurs show increased niche occupation relative to earlier, Santonian-Campanian faunas and successfully outcompeted birds at large sizes. These patterns suggest an abrupt mass extinction of pterosaurs at the K-Pg boundary. PMID:29534059

  19. REAL TIME, ON-LINE CHARACTERIZATION OF DIESEL GENERATOR AIR TOXIC EMISSIONS BY RESONANCE ENHANCED MULTI-PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY

    EPA Science Inventory

    The laser based resonance, enhanced multi-photon ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds ...

  20. Surface-slip equations for multicomponent nonequilibrium air flow

    NASA Technical Reports Server (NTRS)

    Gupta, R. N.; Scott, C. D.; Moss, J. N.

    1985-01-01

    Equations are presented for the surface-slip (or jump) values of species concentration, pressure, velocity, and temperature in the low-Reynolds number, high-altitude flight regime of a space vehicle. The equations are obtained from closed form solutions of the mass, momentum, and energy flux equations using the Chapman-Enskog velocity distribution function. This function represents a solution of the Boltzmann equation in the Navier-Stokes approximation. The analysis, obtained for nonequilibrium multicomponent air flow, includes the finite-rate surface catalytic recombination and changes in the internal energy during reflection from the surface. Expressions for the various slip quantities were obtained in a form which can be employed in flowfield computations. A consistent set of equations is provided for multicomponent, binary, and single species mixtures. Expression is also provided for the finite-rate, species-concentration boundary condition for a multicomponent mixture in absence of slip.