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Sample records for air mass boundaries

  1. Air-mass origin in the tropical lower stratosphere: The influence of Asian boundary layer air

    NASA Astrophysics Data System (ADS)

    Orbe, Clara; Waugh, Darryn W.; Newman, Paul A.

    2015-05-01

    A climatology of air-mass origin in the tropical lower stratosphere is presented for the Goddard Earth Observing System Chemistry Climate Model. During late boreal summer and fall, air-mass fractions reveal that as much as 20% of the air in the tropical lower stratosphere last contacted the planetary boundary layer (PBL) over Asia; by comparison, the air-mass fractions corresponding to last PBL contact over North America and over Europe are negligible. Asian air reaches the extratropical tropopause within a few days of leaving the boundary layer and is quasi-horizontally transported into the tropical lower stratosphere, where it persists until January. The rapid injection of Asian air into the lower stratosphere—and its persistence in the deep tropics through late (boreal) winter—is important as industrial emissions over East Asia continue to increase. Hence, the Asian monsoon may play an increasingly important role in shaping stratospheric composition.

  2. Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

    NASA Astrophysics Data System (ADS)

    Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

    2014-08-01

    Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

  3. Heat and mass transfer in a dissociated laminar boundary layer of air with consideration of the finite rate of chemical reaction

    NASA Technical Reports Server (NTRS)

    Oyegbesan, A. O.; Algermissen, J.

    1986-01-01

    A numerical investigation of heat and mass transfer in a dissociated laminar boundary layer of air on an isothermal flat plate is carried out for different degrees of cooling of the wall. A finite-difference chemical model is used to study elementary reactions involving NO2 and N2O. The analysis is based on equations of continuity, momentum, energy, conservation and state for the two-dimensional viscous flow of a reacting multicomponent mixtures. Attention is given to the effects of both catalyticity and noncatalyticity of the wall.

  4. Boundary Layers of Air Adjacent to Cylinders

    PubMed Central

    Nobel, Park S.

    1974-01-01

    Using existing heat transfer data, a relatively simple expression was developed for estimating the effective thickness of the boundary layer of air surrounding cylinders. For wind velocities from 10 to 1000 cm/second, the calculated boundary-layer thickness agreed with that determined for water vapor diffusion from a moistened cylindrical surface 2 cm in diameter. It correctly predicted the resistance for water vapor movement across the boundary layers adjacent to the (cylindrical) inflorescence stems of Xanthorrhoea australis R. Br. and Scirpus validus Vahl and the leaves of Allium cepa L. The boundary-layer thickness decreased as the turbulence intensity increased. For a turbulence intensity representative of field conditions (0.5) and for νwindd between 200 and 30,000 cm2/second (where νwind is the mean wind velocity and d is the cylinder diameter), the effective boundary-layer thickness in centimeters was equal to [Formula: see text]. PMID:16658855

  5. Biogeochemical modeling at mass extinction boundaries

    NASA Technical Reports Server (NTRS)

    Rampino, M. R.; Caldeira, K. G.

    1991-01-01

    The causes of major mass extinctions is a subject of considerable interest to those concerned with the history and evolution of life on earth. The primary objectives of the proposed plan of research are: (1) to develop quantitative time-dependent biogeochemical cycle models, coupled with an ocean atmosphere in order to improve the understanding of global scale physical, chemical, and biological processes that control the distribution of elements important for life at times of mass extinctions; and (2) to develop a comprehensive data base of the best available geochemical, isotopic, and other relevant geologic data from sections across mass extinction boundaries. These data will be used to constrain and test the biogeochemical model. These modeling experiments should prove useful in: (1) determining the possible cause(s) of the environmental changes seen at bio-event boundaries; (2) identifying and quantifying little-known feedbacks among the oceans, atmosphere, and biosphere; and (3) providing additional insights into the possible responses of the earth system to perturbations of various timescales. One of the best known mass extinction events marks the Cretaceous/Tertiary (K/T) boundary (66 Myr ago). Data from the K/T boundary are used here to constrain a newly developed time-dependent biogeochemical cycle model that is designed to study transient behavior of the earth system. Model results predict significant fluctuations in ocean alkalinity, atmospheric CO2, and global temperatures caused by extinction of calcareous plankton and reduction in the sedimentation rates of pelagic carbonates and organic carbon. Oxygen-isotome and other paleoclimatic data from K/T time provide some evidence that such climatic fluctuations may have occurred, but stabilizing feedbacks may have acted to reduce the ocean alkalinity and carbon dioxide fluctuations.

  6. Sea-air boundary meteorological sensor

    NASA Astrophysics Data System (ADS)

    Barbosa, Jose G.

    2015-05-01

    The atmospheric environment can significantly affect radio frequency and optical propagation. In the RF spectrum refraction and ducting can degrade or enhance communications and radar coverage. Platforms in or beneath refractive boundaries can exploit the benefits or suffer the effects of the atmospheric boundary layers. Evaporative ducts and surface-base ducts are of most concern for ocean surface platforms and evaporative ducts are almost always present along the sea-air interface. The atmospheric environment also degrades electro-optical systems resolution and visibility. The atmospheric environment has been proven not to be uniform and under heterogeneous conditions substantial propagation errors may be present for large distances from homogeneous models. An accurate and portable atmospheric sensor to profile the vertical index of refraction is needed for mission planning, post analysis, and in-situ performance assessment. The meteorological instrument used in conjunction with a radio frequency and electro-optical propagation prediction tactical decision aid tool would give military platforms, in real time, the ability to make assessments on communication systems propagation ranges, radar detection and vulnerability ranges, satellite communications vulnerability, laser range finder performance, and imaging system performance predictions. Raman lidar has been shown to be capable of measuring the required atmospheric parameters needed to profile the atmospheric environment. The atmospheric profile could then be used as input to a tactical decision aid tool to make propagation predictions.

  7. Fundamental mass transfer models for indoor air pollution sources

    SciTech Connect

    Tichenor, B.A.; Guo, Z.; Sparks, L.E.

    1993-01-01

    The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. While empirical approaches based on dynamic chamber data are useful, a more fundamental approach is needed to fully elucidate the relevant mass transfer processes). In the model, the mass transfer rate is assumed to be gas-phase limited and controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining. Results of static and dynamic chamber tests, as well as test house studies, are presented.

  8. Effect of Dynamic Sector Boundary Changes on Air Traffic Controllers

    NASA Technical Reports Server (NTRS)

    Jung, Jaewoo; Lee, Paul; Kessell, Angela; Homola, Jeff; Zelinski, Shannon

    2010-01-01

    The effect of dynamic sector boundary changes on air traffic controller workload was investigated with data from a human-in-the-loop simulation. Multiple boundary changes were made during simulated operations, and controller rating of workload was recorded. Analysis of these data showed an increase of 16.9% in controller workload due to boundary changes. This increased workload was correlated with the number of aircraft handoffs and change in sector volume. There was also a 12.7% increase in average workload due to the changed sector design after boundary changes. This increase was correlated to traffic flow crossing points getting closer to sector boundaries and an increase in the number of flights with short dwell time in a sector. This study has identified some of the factors that affect controller workload when sector boundaries are changed, but more research is needed to better understand their relationships.

  9. Air Pressure Controlled Mass Measurement System

    NASA Astrophysics Data System (ADS)

    Zhong, Ruilin; Wang, Jian; Cai, Changqing; Yao, Hong; Ding, Jin'an; Zhang, Yue; Wang, Xiaolei

    Mass measurement is influenced by air pressure, temperature, humidity and other facts. In order to reduce the influence, mass laboratory of National Institute of Metrology, China has developed an air pressure controlled mass measurement system. In this system, an automatic mass comparator is installed in an airtight chamber. The Chamber is equipped with a pressure controller and associate valves, thus the air pressure can be changed and stabilized to the pre-set value, the preferred pressure range is from 200 hPa to 1100 hPa. In order to keep the environment inside the chamber stable, the display and control part of the mass comparator are moved outside the chamber, and connected to the mass comparator by feed-throughs. Also a lifting device is designed for this system which can easily lift up the upper part of the chamber, thus weights can be easily put inside the mass comparator. The whole system is put on a marble platform, and the temperature and humidity of the laboratory is very stable. The temperature, humidity, and carbon dioxide content inside the chamber are measured in real time and can be used to get air density. Mass measurement cycle from 1100 hPa to 200 hPa and back to 1100 hPa shows the effective of the system.

  10. Columnar modelling of nucleation burst evolution in the convective boundary layer - first results from a feasibility study Part III: Preliminary results on physicochemical model performance using two "clean air mass" reference scenarios

    NASA Astrophysics Data System (ADS)

    Hellmuth, O.

    2006-09-01

    In Paper I of four papers, a revised columnar high-order model to investigate gas-aerosol-turbulence interactions in the convective boundary layer (CBL) was proposed. In Paper II, the model capability to predict first-, second- and third-order moments of meteorological variables in the CBL was demonstrated using available observational data. In the present Paper III, the high-order modelling concept is extended to sulphur and ammonia chemistry as well as to aerosol dynamics. Based on the previous CBL simulation, a feasibility study is performed using two "clean air mass" scenarios with an emission source at the ground but low aerosol background concentration. Such scenarios synoptically correspond to the advection of fresh post-frontal air in an anthropogenically influenced region. The aim is to evaluate the time-height evolution of ultrafine condensation nuclei (UCNs) and to elucidate the interactions between meteorological and physicochemical variables in a CBL column. The scenarios differ in the treatment of new particle formation (NPF), whereas homogeneous nucleation according to the classical nucleation theory (CNT) is considered. The first scenario considers nucleation of a binary system consisting of water vapour and sulphuric acid (H2SO4) vapour, the second one nucleation of a ternary system additionally involving ammonia (NH3). Here, the two synthetic scenarios are discussed in detail, whereas special attention is payed to the role of turbulence in the formation of the typical UCN burst behaviour, that can often be observed in the surface layer. The intercomparison of the two scenarios reveals large differences in the evolution of the UCN number concentration in the surface layer as well as in the time-height cross-sections of first-order moments and double correlation terms. Although in both cases the occurrence of NPF bursts could be simulated, the burst characteristics and genesis of the bursts are completely different. It is demonstrated, that

  11. Mass Media and Deviance: Exploring the Boundaries.

    ERIC Educational Resources Information Center

    Lentz, Richard

    Concurring that the more sociology and history draw upon each other's discipline, the better for both, this paper argues that the study of mass media presentations of deviance is one line of inquiry that lends itself to the realization of this dictum. The paper first explores some of the shortcomings that historians and sociologists share, noting…

  12. Brown Dwarfs at the Exoplanet Mass Boundary

    NASA Astrophysics Data System (ADS)

    Faherty, J. K.; Cruz, K. L.; Rice, E. L.; Riedel, A.

    2014-10-01

    Young brown dwarfs and directly-imaged exoplanets have enticingly similar photometric and spectroscopic characteristics, indicating that their cool, low gravity atmospheres should be studied in concert. Similarities between the peculiar shaped H band, near and mid-IR photometry as well as location on color magnitude diagrams provide important clues about how to extract physical properties of planets from current brown dwarf observations. Our team has assigned >30 brown dwarfs to 10-150 Myr nearby moving groups. In so doing, we have discovered important diversity among this extremely low-mass (10 - 30 M_{Jup}) age-calibrated sample indicating that cloud properties play a critical role in their observables.

  13. Numerical investigation of implementation of air-earth boundary by acoustic-elastic boundary approach

    USGS Publications Warehouse

    Xu, Y.; Xia, J.; Miller, R.D.

    2007-01-01

    The need for incorporating the traction-free condition at the air-earth boundary for finite-difference modeling of seismic wave propagation has been discussed widely. A new implementation has been developed for simulating elastic wave propagation in which the free-surface condition is replaced by an explicit acoustic-elastic boundary. Detailed comparisons of seismograms with different implementations for the air-earth boundary were undertaken using the (2,2) (the finite-difference operators are second order in time and space) and the (2,6) (second order in time and sixth order in space) standard staggered-grid (SSG) schemes. Methods used in these comparisons to define the air-earth boundary included the stress image method (SIM), the heterogeneous approach, the scheme of modifying material properties based on transversely isotropic medium approach, the acoustic-elastic boundary approach, and an analytical approach. The method proposed achieves the same or higher accuracy of modeled body waves relative to the SIM. Rayleigh waves calculated using the explicit acoustic-elastic boundary approach differ slightly from those calculated using the SIM. Numerical results indicate that when using the (2,2) SSG scheme for SIM and our new method, a spatial step of 16 points per minimum wavelength is sufficient to achieve 90% accuracy; 32 points per minimum wavelength achieves 95% accuracy in modeled Rayleigh waves. When using the (2,6) SSG scheme for the two methods, a spatial step of eight points per minimum wavelength achieves 95% accuracy in modeled Rayleigh waves. Our proposed method is physically reasonable and, based on dispersive analysis of simulated seismographs from a layered half-space model, is highly accurate. As a bonus, our proposed method is easy to program and slightly faster than the SIM. ?? 2007 Society of Exploration Geophysicists.

  14. Dynamical Simulation of Cloudy Boundary Layer Flow during Cold Air Outbreaks.

    NASA Astrophysics Data System (ADS)

    Yuen, Chiu-Wai

    A two-dimensional primitive equation planetary boundary layer model has been constructed and applied to simulate downwind evolution of coupled dynamical, thermodynamical and cloud properties in the planetary boundary layer (PBL) developed during cold air outbreaks over warm ocean. A layered parametric approach is adopted to model the inversion -capped convective boundary layer filled with shallow cumuli, or topped by stratocumulus or cloud free air. Turbulent and convective cloud fluxes are determined from modifications and generalizations of recent published parameterization schemes. A one-dimensional version of the model is first applied to a local simulation of trade wind flow. Vertical distributions of momentum flux and wind in the cumulus -filled baroclinic PBL are realistically simulated compared to observations, confirming the validity of the momentum flux parameterization scheme assembled in this research. A steady-state linear analysis for a cloud-free mixed layer flowing from land over a warm ocean clarifies the basic dynamical and thermodynamical adjustments to differential friction and heating. Downwind warming and deepening of PBL produces counteracting pressure gradient forces, while heating-induced subsidence occurs only in places where boundary layer baroclinity is strong. Comparative numerical experiments for moderate intensity air-sea interaction illustrate the importance of nonprecipitating cumulus convection and large scale environmental conditions. Such factors as baroclinity, static stability, moisture content, upwind inversion strength and height exert strong controls on the downwind evolution of PBL and clouds. Boundary layer flow is influenced by the basic geostrophic wind distribution and the PBL depth is also sensitive to large scale vertical velocity. The response of an advective boundary layer to stronger wind is different from that of a horizontally homogeneous boundary layer. In a simulation of an intense air mass transformation

  15. Infrared propagation in the air-sea boundary layer

    NASA Astrophysics Data System (ADS)

    Larsen, R.; Preedy, K. A.; Drake, G.

    1990-03-01

    Over the oceans and other large bodies of water the structure of the lowest layers of the atmosphere is often strongly modified by evaporation of water vapor from the water surface. At radio wavelengths this layer will usually be strongly refracting or ducting, and the layer is commonly known as the evaporation duct. However, the refractive index of air at infrared wavelengths differs from that at radio wavelengths, and the effects of the marine boundary layer on the propagation of infrared radiation are examined. Meteorological models of the air-sea boundary layer are used to compute vertical profiles of temperature and water-vapor pressure. From these are derived profiles of atmospheric refractive index at radio wavelengths and at infrared wavelengths in the window regions of low absorption. For duct propagation to occur it is necessary that the refractivity of air decreases rapidly with increasing height above the surface. At radio wavelengths this usually occurs when there is a strong lapse of water vapor pressure with increasing height. By contrast, at infrared wavelengths the refractive index is almost independent of water vapor pressure, and it is found that an infrared duct is formed only when there is a temperature inversion.

  16. Air Flow in a Separating Laminar Boundary Layer

    NASA Technical Reports Server (NTRS)

    Schubauer, G B

    1936-01-01

    The speed distribution in a laminar boundary layer on the surface of an elliptic cylinder, of major and minor axes 11.78 and 3.98 inches, respectively, has been determined by means of a hot-wire anemometer. The direction of the impinging air stream was parallel to the major axis. Special attention was given to the region of separation and to the exact location of the point of separation. An approximate method, developed by K. Pohlhausen for computing the speed distribution, the thickness of the layer, and the point of separation, is described in detail; and speed-distribution curves calculated by this method are presented for comparison with experiment.

  17. The Permian-Triassic boundary & mass extinction in China

    USGS Publications Warehouse

    Metcalfe, I.; Nicoll, R.S.; Mundil, R.; Foster, C.; Glen, J.; Lyons, J.; Xiaofeng, W.; Cheng-Yuan, W.; Renne, P.R.; Black, L.; Xun, Q.; Xiaodong, M.

    2001-01-01

    The first appearance of Hindeodus parvus (Kozur & Pjatakova) at the Permian-Triassic (P-T) GSSP level (base of Bed 27c) at Meishan is here confirmed. Hindeodus changxingensis Wang occurs from Beds 26 to 29 at Meishan and appears to be restricted to the narrow boundary interval immediately above the main mass extinction level in Bed 25. It is suggested that this species is therefore a valuable P-T boundary interval index taxon. Our collections from the Shangsi section confirm that the first occurrence of Hindeodus parvus in that section is about 5 in above the highest level from which a typical Permian fauna is recovered. This may suggest that that some section may be missing at Meishan. The age of the currently defined Permian-Triassic Boundary is estimated by our own studies and a reassessment of previous worker's data at c. 253 Ma, slightly older than our IDTIMS 206Pb/238U age of 252.5 ??0.3 Ma for Bed 28, just 8 cm above the GSSP boundary (Mundil et al., 2001). The age of the main mass extinction, at the base of Bed 25 at Meishan, is estimated at slightly older than 254 Ma based on an age of >254 Ma for the Bed 25 ash. Regardless of the absolute age of the boundary, it is evident that the claimed <165,000 y short duration for the negative carbon isotope excursion at the P-T boundary (Bowring et al., 1998) cannot be confirmed. Purportedly extraterrestrial fullerenes at the boundary (Hecker et al., 2001) have equivocal significance due to their chronostratigraphic non-uniqueness and their occurrence in a volcanic ash.

  18. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Technical Reports Server (NTRS)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  19. Chicxulub impact predates the K-T boundary mass extinction

    PubMed Central

    Keller, Gerta; Adatte, Thierry; Stinnesbeck, Wolfgang; Rebolledo-Vieyra, Mario; Urrutia Fucugauchi, Jaime; Kramar, Utz; Stüben, Doris

    2004-01-01

    Since the early l990s the Chicxulub crater on Yucatan, Mexico, has been hailed as the smoking gun that proves the hypothesis that an asteroid killed the dinosaurs and caused the mass extinction of many other organisms at the Cretaceous-Tertiary (K-T) boundary 65 million years ago. Here, we report evidence from a previously uninvestigated core, Yaxcopoil-1, drilled within the Chicxulub crater, indicating that this impact predated the K-T boundary by ≈300,000 years and thus did not cause the end-Cretaceous mass extinction as commonly believed. The evidence supporting a pre-K-T age was obtained from Yaxcopoil-1 based on five independent proxies, each with characteristic signals across the K-T transition: sedimentology, biostratigraphy, magnetostratigraphy, stable isotopes, and iridium. These data are consistent with earlier evidence for a late Maastrichtian age of the microtektite deposits in northeastern Mexico. PMID:15004276

  20. The Effective Mass of a Ball in the Air

    ERIC Educational Resources Information Center

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  1. Calculation of eddy viscosity in a compressible turbulent boundary layer with mass injection and chemical reaction

    NASA Technical Reports Server (NTRS)

    Omori, S.; Gross, K. W.

    1973-01-01

    The turbulent kinetic energy equation is coupled with boundary layer equations to solve the characteristics of compressible turbulent boundary layers with mass injection and combustion. The Reynolds stress is related to the turbulent kinetic energy using the Prandtl-Wieghardt formulation. When a lean mixture of hydrogen and nitrogen is injected through a porous plate into the subsonic turbulent boundary layer of air flow and ignited by external means, the turbulent kinetic energy increases twice as much as that of noncombusting flow with the same mass injection rate of nitrogen. The magnitudes of eddy viscosity between combusting and noncombusting flows with injection, however, are almost the same due to temperature effects, while the distributions are different. The velocity profiles are significantly affected by combustion. If pure hydrogen as a transpiration coolant is injected into a rocket nozzle boundary layer flow of combustion products, the temperature drops significantly across the boundary layer due to the high heat capacity of hydrogen. At a certain distance from the wall hydrogen reacts with the combustion products, liberating an extensive amount of heat.

  2. A Database and Tool for Boundary Conditions for Regional Air Quality Modeling: Description and Evaluation

    EPA Science Inventory

    Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available ob...

  3. Rotational hydrodynamic diffusion system to study mass transport across boundaries.

    PubMed

    Mamidi, Sai Sree; Meas, Bo; Farhat, Tarek R

    2008-11-01

    The design and operation of a new mass transport technique is presented. Rotational hydrodynamic diffusion system (RHDS) is a method that can be adapted for analytical laboratory analysis as well as industrial-scale separation and purification. Although RHDS is not an electrochemical technique, its concept is derived from hydrodynamic rotating disk electrode voltammetry. A diffusion advantage gained using the RHDS is higher flux of probe molecules across the boundary (e.g., membrane or porous media) with increased rotation rate compared to the static two-half-cell (THC) method. The separation concept of RHDS differs from pressurized, agitated, electrodialysis, and reversed osmosis systems in design and theory. The detection mechanism of the RHDS opens the possibility to study mass transport properties of a large variety of molecules using different types of ultrathin membranes. Therefore, the RHDS is a potential alternative to classical mass transport detection methods such as THC, impedance spectroscopy, and cyclic and rotating disk electrode voltammetry. Theoretical analysis on the rotational hydrodynamic flux is derived and compared to experimental flux measured using HCl, KCl, KNO 3, Ni(NO 3) 2, LiCl, camphor sulfonic acid, and K 3Fe(CN) 6 ionic solutions. Values of effective diffusion coefficients of salts across Nucleopore membranes of thickness 6.0 and 10 mum with pore size 0.1 and 0.2 mum, respectively, are presented and discussed. PMID:18844370

  4. Experimental Investigation of Soil and Atmospheric Conditions on the Momentum, Mass, and Thermal Boundary Layers Above the Land Atmosphere Interface

    NASA Astrophysics Data System (ADS)

    Trautz, A.; Smits, K. M.; Illangasekare, T. H.; Schulte, P.

    2014-12-01

    The purpose of this study is to investigate the impacts of soil conditions (i.e. soil type, saturation) and atmospheric forcings (i.e. velocity, temperature, relative humidity) on the momentum, mass, and temperature boundary layers. The atmospheric conditions tested represent those typically found in semi-arid and arid climates and the soil conditions simulate the three stages of evaporation. The data generated will help identify the importance of different soil conditions and atmospheric forcings with respect to land-atmospheric interactions which will have direct implications on future numerical studies investigating the effects of turbulent air flow on evaporation. The experimental datasets generated for this study were performed using a unique climate controlled closed-circuit wind tunnel/porous media facility located at the Center for Experimental Study of Subsurface Environmental Processes (CESEP) at the Colorado School of Mines. The test apparatus consisting of a 7.3 m long porous media tank and wind tunnel, were outfitted with a sensor network to carefully measure wind velocity, air and soil temperature, relative humidity, soil moisture, and soil air pressure. Boundary layer measurements were made between the heights of 2 and 500 mm above the soil tank under constant conditions (i.e. wind velocity, temperature, relative humidity). The soil conditions (e.g. soil type, soil moisture) were varied between datasets to analyze their impact on the boundary layers. Experimental results show that the momentum boundary layer is very sensitive to the applied atmospheric conditions and soil conditions to a much less extent. Increases in velocity above porous media leads to momentum boundary layer thinning and closely reflect classical flat plate theory. The mass and thermal boundary layers are directly dependent on both atmospheric and soil conditions. Air pressure within the soil is independent of atmospheric temperature and relative humidity - wind velocity and soil

  5. Turbulent Boundary Layer in High Rayleigh Number Convection in Air

    NASA Astrophysics Data System (ADS)

    du Puits, Ronald; Li, Ling; Resagk, Christian; Thess, André; Willert, Christian

    2014-03-01

    Flow visualizations and particle image velocimetry measurements in the boundary layer of a Rayleigh-Bénard experiment are presented for the Rayleigh number Ra =1.4×1010. Our visualizations indicate that the appearance of the flow structures is similar to ordinary (isothermal) turbulent boundary layers. Our particle image velocimetry measurements show that vorticity with both positive and negative sign is generated and that the smallest flow structures are 1 order of magnitude smaller than the boundary layer thickness. Additional local measurements using laser Doppler velocimetry yield turbulence intensities up to I=0.4 as in turbulent atmospheric boundary layers. From our observations, we conclude that the convective boundary layer becomes turbulent locally and temporarily although its Reynolds number Re ≈200 is considerably smaller than the value 420 underlying existing phenomenological theories. We think that, in turbulent Rayleigh-Bénard convection, the transition of the boundary layer towards turbulence depends on subtle details of the flow field and is therefore not universal.

  6. Influence of Boundary Conditions on Simulated U.S. Air Quality

    EPA Science Inventory

    One of the key inputs to regional-scale photochemical models frequently used in air quality planning and forecasting applications are chemical boundary conditions representing background pollutant concentrations originating outside the regional modeling domain. A number of studie...

  7. Atmospheric Boundary Layer Modeling for Combined Meteorology and Air Quality Systems

    EPA Science Inventory

    Atmospheric Eulerian grid models for mesoscale and larger applications require sub-grid models for turbulent vertical exchange processes, particularly within the Planetary Boundary Layer (PSL). In combined meteorology and air quality modeling systems consistent PSL modeling of wi...

  8. Influence of Baseline Air Masses and Wildland Fires on Air Quality in the Western United States

    NASA Astrophysics Data System (ADS)

    Wigder, Nicole L.

    This dissertation focuses on several key uncertainties related to particulate matter (PM) and O3 concentrations in the western U.S. Each analysis conducted for this dissertation centers on data collected at the Mount Bachelor Observatory (MBO, 2.8 km a.s.l., 43.98° N, 121.69° W), a mountaintop research site in central Oregon, U.S. The first component of this dissertation is an analysis of the contribution of baseline O3 to observed O3 concentrations in two western U.S. urban areas, Enumclaw, Washington (WA) and Boise, Idaho, during 2004 -- 2010. I compared O3 data from two baseline sites (MBO and Cheeka Peak, WA) to O3 concentrations in the two urban areas on days when backward air mass trajectories showed transport between the baseline and urban sites. I found that the urban areas studied had relatively low O3 on the days with a strong influence from baseline air masses (28.3 -- 48.3 ppbv). These data suggested that there was low production of O3 from urban emissions on these days, which allowed me to quantify the impact of baseline O3 on urban O3 concentrations. A regression of the Boise and MBO O3 observations showed that free tropospheric air masses were diluted by 50% as they were entrained into the boundary layer at Boise. These air masses can contain high O3 concentrations (>70 ppbv) from Asian pollution sources or stratospheric intrusions, indicating that these sources can greatly contribute to urban surface O 3 concentrations. In addition, I found that the elevation and surface temperature of the urban areas studied impacted baseline O3 concentrations in these areas, with higher elevation and greater surface temperatures leading to greater O3 concentrations. The second and third components of this dissertation are analyses of the impact of wildland fires on PM and O3 concentrations in the western U.S. For both of these analyses, I calculated pollutant enhancement ratios for PM, O3, and other species in wildland fire plumes observed at MBO during 2004

  9. Boundary undercurrent and water mass changes in the Lincoln Sea

    NASA Astrophysics Data System (ADS)

    Newton, John L.; Sotirin, Barbara J.

    1997-02-01

    Oceanographic measurements taken between 1989 and 1994 in the Lincoln Sea describe the currents and water mass structure along the continental slope of the Arctic Basin between the Canadian and Eurasian Basins. The measurements included periodic conductivity and temperature versus depth (CTD) profiles from ice camps, CTD cross sections normal to the slope, and year-round current measurements. Analysis of this data describes the hydrographic structure of the waters over the continental slope and identifies some significant interannual variations. An undercurrent, confined to the continental slope, with a width of about 50 km and speeds of 5-9 cm s-1 is shown in geostrophic current cross sections. The presence of this easterly flow at depth is confirmed by current meter measurements, and its existence has also been observed in the Beaufort Sea and the Barents Sea [Aagaard, 1989]. The waters within this undercurrent exhibit temperature-salinity (TS) characteristics similar to Canadian Basin waters, suggesting a boundary current system which is continuous along the continental slope north of Alaska and Canada. Significant interannual variations in temperature and salinity profiles may be related to variations in the large-scale circulation of the Arctic. Examination of the upper pycnocline waters over the slope between 1991 and 1994 indicated a relative temperature maximum overlying a minimum, TS characteristics similar to waters attributed to Bering Sea origin found in the Canadian Basin. These characteristics were not seen, however, during 1989 and 1990, suggesting a recent increase in the transport of surface waters from the Canadian Basin into the Eurasian Basin.

  10. Fundamental mass transfer model for indoor air emissions from surface coatings

    SciTech Connect

    Tichenor, B.A.; Guo, Z.; Sparks, L.E.

    1994-01-01

    The paper discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architectural coatings. As a first step, a simple model based on Fick's Law of Diffusion has been developed. In the model, the mass transfer rate is assumed to be controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining in the source at any point in time. Both static and dynamic chamber tests were conducted to obtain model validation data. Further validation experiments were conducted in a test house. Results of these tests are presented.

  11. Calculation of eddy viscosity in a compressible turbulent boundary layer with mass injection and chemical reaction, volume 1. [theoretical analysis

    NASA Technical Reports Server (NTRS)

    Omori, S.

    1973-01-01

    The turbulent kinetic energy equation is coupled with boundary layer equations to solve the characteristics of compressible turbulent boundary layers with mass injection and combustion. The Reynolds stress is related to the turbulent kinetic energy using the Prandtl-Wieghardt formulation. When a lean mixture of hydrogen and nitrogen is injected through a porous plate into the subsonic turbulent boundary layer of air flow and ignited by external means, the turbulent kinetic energy increases twice as much as that of noncombusting flow with the same mass injection rate of nitrogen. The magnitudes of eddy viscosity between combusting and noncombusting flows with injection, however, are almost the same due to temperature effects, while the distributions are different. The velocity profiles are significantly affected by combustion; that is, combustion alters the velocity profile as if the mass injection rate is increased, reducing the skin-friction as a result of a smaller velocity gradient at the wall. If pure hydrogen as a transpiration coolant is injected into a rocket nozzle boundary layer flow of combustion products, the temperature drops significantly across the boundary layer due to the high heat capacity of hydrogen. At a certain distance from the wall, hydrogen reacts with the combustion products, liberating an extensive amount of heat. The resulting large increase in temperature reduces the eddy viscosity in this region.

  12. Deriving realistic source boundary conditions for a CFD simulation of concentrations in workroom air.

    PubMed

    Feigley, Charles E; Do, Thanh H; Khan, Jamil; Lee, Emily; Schnaufer, Nicholas D; Salzberg, Deborah C

    2011-05-01

    Computational fluid dynamics (CFD) is used increasingly to simulate the distribution of airborne contaminants in enclosed spaces for exposure assessment and control, but the importance of realistic boundary conditions is often not fully appreciated. In a workroom for manufacturing capacitors, full-shift samples for isoamyl acetate (IAA) were collected for 3 days at 16 locations, and velocities were measured at supply grills and at various points near the source. Then, velocity and concentration fields were simulated by 3-dimensional steady-state CFD using 295K tetrahedral cells, the k-ε turbulence model, standard wall function, and convergence criteria of 10(-6) for all scalars. Here, we demonstrate the need to represent boundary conditions accurately, especially emission characteristics at the contaminant source, and to obtain good agreement between observations and CFD results. Emission rates for each day were determined from six concentrations measured in the near field and one upwind using an IAA mass balance. The emission was initially represented as undiluted IAA vapor, but the concentrations estimated using CFD differed greatly from the measured concentrations. A second set of simulations was performed using the same IAA emission rates but a more realistic representation of the source. This yielded good agreement with measured values. Paying particular attention to the region with highest worker exposure potential-within 1.3 m of the source center-the air speed and IAA concentrations estimated by CFD were not significantly different from the measured values (P = 0.92 and P = 0.67, respectively). Thus, careful consideration of source boundary conditions greatly improved agreement with the measured values. PMID:21422277

  13. Boundary layer flow of air over water on a flat plate

    NASA Technical Reports Server (NTRS)

    Nelson, John; Alving, Amy E.; Joseph, Daniel D.

    1993-01-01

    A non-similar boundary layer theory for air blowing over a water layer on a flat plate is formulated and studied as a two-fluid problem in which the position of the interface is unknown. The problem is considered at large Reynolds number (based on x), away from the leading edge. A simple non-similar analytic solution of the problem is derived for which the interface height is proportional to x(sub 1/4) and the water and air flow satisfy the Blasius boundary layer equations, with a linear profile in the water and a Blasius profile in the air. Numerical studies of the initial value problem suggests that this asymptotic, non-similar air-water boundary layer solution is a global attractor for all initial conditions.

  14. Formation of elevated refractive layers in the oceanic boundary layer by modification of land air flowing offshore

    NASA Astrophysics Data System (ADS)

    Gossard, Earl E.

    1982-03-01

    The usual picture of the development of temperature and humidity boundary layers in a land air mass that moves offshore is shown to be very wrong under one type of Foehn condition in southern California, and it is probable that similar conditions can prevail in widespread areas around the globe, notably the Mediterranean Sea and the monsoonal regions of the Near East and Southeast Asia. A formalism is developed for analyzing the modification that seems to represent the observations satisfactorily, and graphical solutions for radio and optical ducting are given. It is shown that offshore modification can lead to elevated layers rather than to surface based layers, and the height of the layer base is theoretically predicted. Values of evaporation and heat flux into such an air mass are calculated, and the distance offshore at which dew point depression becomes zero is predicted. A method for measuring the downward heat flux in elevated inversion layers is described and results are given.

  15. Ions in oceanic and continental air masses

    SciTech Connect

    Tanner, D.J.; Eisele, F.L. )

    1991-01-20

    Measurements of tropospheric ions and several trace atmospheric neutral species have been performed at Cheeka Peak Research Station and at Mauna Loa Observatory. Two new positive ion species at masses 114 and 102 have been identified as protonated caprolactam and a saturated 6-carbon primary amine, respectively. In the negative ion spectrum, methane sulfonic acid (MSA) has been identified as the parent species responsible for an ion commonly observed at mass 95 during these two studies. The diurnal variations of gas phase H{sub 2}SO{sub 4} and MSA were also measured at Cheeka Peak and have typically been found to be present in the sub-ppt range. Ion assisted measurements at Mauna Loa Observatory of pyridine and ammonia indicate concentrations of 2.5 and 70 ppt, respectively, with at least a factor of 2 uncertainty. Interesting variations and potential sources of several of the observed ions are also discussed.

  16. Aerosol chemical components in Alaska air masses: 1. Aged pollution

    NASA Astrophysics Data System (ADS)

    Shaw, Glenn E.

    1991-12-01

    A 4-year Alaska chemical data set of aerosols or "dust" in the air clearly reveals a mixture of distinct aerosol components with different and interesting chemical composition, one or two being ascribed to pollution imported to Alaska by winds all the way from other continents. Of particular note is a strong chemical contrast between what we imagine to be highly scavenged, orographically lifted, northern Pacific air (Pacific marine air mass) and stagnant Arctic air (polar air mass), the latter containing seasonal average concentrations of between 2-4 times the concentration of the former, at least for pollution markers noncrustal vanadium, noncrustal manganese, arsenic, selenium, bromine, and antimony. The findings concur our old discovery that Arctic air is persistently polluted (Arctic haze), but Pacific air is relatively clean, in spite of the fact that Alaska is downwind of major pollution sources in the Orient. This is remarkable. In this the first of a two-part paper, we concentrate on the pollution component found primarily during incursion of Arctic polar air. Two major occurrences of visual haze with optical depths of approximately 0.2 and elevated aerosol concentration lasting about a month (spring 1985 and 1986) were affiliated with strong incoming transport of polar air, temperatures ranging from 10° to 20°C below normal (polar air) and air trajectory hindcasts leading back to industrial pollution sources in Eurasia. These long-range transport pollution events brought metal-rich aerosol of removal-resistant submicron particles. The size, chemistry, and meteorology all strongly suggest the presence of a well-aged (10-100 day) polluted air mass. An important implication is that in spring a large fraction of the Arctic polar air mass becomes charged with by-products of industrial pollution. In this multiyear chemical data set one finds a notable summer-winter contrast, changing by factors of 2 to 4 for pollution markers As, Se, Sb, and noncrustal

  17. Impact of Bay-Breeze Circulations on Surface Air Quality and Boundary Layer Export

    NASA Technical Reports Server (NTRS)

    Loughner, Christopher P.; Tzortziou, Maria; Follette-Cook, Melanie; Pickering, Kenneth E.; Goldberg, Daniel; Satam, Chinmay; Weinheimer, Andrew; Crawford, James H.; Knapp, David J.; Montzka, Denise D.; Diskin, Glenn S.; Dickerson, Russell R.

    2014-01-01

    Meteorological and air-quality model simulations are analyzed alongside observations to investigate the role of the Chesapeake Bay breeze on surface air quality, pollutant transport, and boundary layer venting. A case study was conducted to understand why a particular day was the only one during an 11-day ship-based field campaign on which surface ozone was not elevated in concentration over the Chesapeake Bay relative to the closest upwind site and why high ozone concentrations were observed aloft by in situ aircraft observations. Results show that southerly winds during the overnight and early-morning hours prevented the advection of air pollutants from the Washington, D.C., and Baltimore, Maryland, metropolitan areas over the surface waters of the bay. A strong and prolonged bay breeze developed during the late morning and early afternoon along the western coastline of the bay. The strength and duration of the bay breeze allowed pollutants to converge, resulting in high concentrations locally near the bay-breeze front within the Baltimore metropolitan area, where they were then lofted to the top of the planetary boundary layer (PBL). Near the top of the PBL, these pollutants were horizontally advected to a region with lower PBL heights, resulting in pollution transport out of the boundary layer and into the free troposphere. This elevated layer of air pollution aloft was transported downwind into New England by early the following morning where it likely mixed down to the surface, affecting air quality as the boundary layer grew.

  18. Effects of boundary layer and liquid viscosity and compressible air on sloshing characteristics

    NASA Astrophysics Data System (ADS)

    Zou, Chang-Fang; Wang, De-Yu; Cai, Zhong-Hua

    2015-07-01

    In this paper, numerical investigations for tank sloshing, based on commercial CFD package FLUENT, are performed to study effects of boundary layer grid, liquid viscosity and compressible air on sloshing pressure, wave height and rising time of impact pressure. Also, sloshing experiments for liquids of different viscosity are carried out to validate the numerical results. Through comparison of numerical and experimental results, a computational model including boundary layer grid can predict the sloshing pressure more accurately. Energy dissipation due to viscous friction leads to reduction of sloshing pressure and wave elevation. Sloshing pressure is also reduced because of cushion effect of compressible air. Due to high viscosity damping effect and compressible air effect, the rising time of impact pressure becomes longer. It is also found that liquid viscosity and compressible air influence distribution of dynamic pressure along the vertical tank wall.

  19. Comment on "Improved ray tracing air mass numbers model"

    NASA Astrophysics Data System (ADS)

    van der Werf, Siebren Y.

    2008-01-01

    Air mass numbers have traditionally been obtained by techniques that use height as the integration variable. This introduces an inherent singularity at the horizon, and ad hoc solutions have been invented to cope with it. A survey of the possible options including integration by height, zenith angle, and horizontal distance or path length is presented. Ray tracing by path length is shown to avoid singularities both at the horizon and in the zenith. A fourth-order Runge-Kutta numerical integration scheme is presented, which treats refraction and air mass as path integrals. The latter may optionally be split out into separate contributions of the atmosphere's constituents.

  20. Warm-air advection, air mass transformation and fog causes rapid ice melt

    NASA Astrophysics Data System (ADS)

    Tjernström, Michael; Shupe, Matthew D.; Brooks, Ian M.; Persson, P. Ola G.; Prytherch, John; Salisbury, Dominic J.; Sedlar, Joseph; Achtert, Peggy; Brooks, Barbara J.; Johnston, Paul E.; Sotiropoulou, Georgia; Wolfe, Dan

    2015-07-01

    Direct observations during intense warm-air advection over the East Siberian Sea reveal a period of rapid sea-ice melt. A semistationary, high-pressure system north of the Bering Strait forced northward advection of warm, moist air from the continent. Air-mass transformation over melting sea ice formed a strong, surface-based temperature inversion in which dense fog formed. This induced a positive net longwave radiation at the surface while reducing net solar radiation only marginally; the inversion also resulted in downward turbulent heat flux. The sum of these processes enhanced the surface energy flux by an average of ~15 W m-2 for a week. Satellite images before and after the episode show sea-ice concentrations decreasing from > 90% to ~50% over a large area affected by the air-mass transformation. We argue that this rapid melt was triggered by the increased heat flux from the atmosphere due to the warm-air advection.

  1. A laser Doppler system for the remote sensing of boundary layer winds in clear air conditions

    NASA Technical Reports Server (NTRS)

    Lawrence, T. R.; Krause, M. C.; Craven, C. E.; Morrison, L. K.; Thomson, J. A. L.; Cliff, W. C.; Huffaker, R. M.

    1975-01-01

    The system discussed uses a laser Doppler radar in combination with a velocity azimuth display mode of scanning to determine the three-dimensional wind field in the atmospheric boundary layer. An attractive feature of this CW monostatic system is that the ambient aerosol provides a 'sufficient' scattering target to permit operation under clear air conditions. Spatial resolution is achieved by focusing.

  2. LINKING ETA MODEL WITH THE COMMUNITY MULTISCALE AIR QUALITY (CMAQ) MODELING SYSTEM: OZONE BOUNDARY CONDITIONS

    EPA Science Inventory

    A prototype surface ozone concentration forecasting model system for the Eastern U.S. has been developed. The model system is consisting of a regional meteorological and a regional air quality model. It demonstrated a strong prediction dependence on its ozone boundary conditions....

  3. Redefining the Boundaries of Interplanetary Coronal Mass Ejections from Observations at the Ecliptic Plane

    NASA Astrophysics Data System (ADS)

    Cid, C.; Palacios, J.; Saiz, E.; Guerrero, A.

    2016-09-01

    On 2015 January 6–7, an interplanetary coronal mass ejection (ICME) was observed at L1. This event, which can be associated with a weak and slow coronal mass ejection, allows us to discuss the differences between the boundaries of the magnetic cloud and the compositional boundaries. A fast stream from a solar coronal hole surrounding this ICME offers a unique opportunity to check the boundaries’ process definition and to explain differences between them. Using Wind and ACE data, we perform a complementary analysis involving compositional, magnetic, and kinematic observations providing relevant information regarding the evolution of the ICME as travelling away from the Sun. We propose erosion, at least at the front boundary of the ICME, as the main reason for the difference between the boundaries, and compositional signatures as the most precise diagnostic tool for the boundaries of ICMEs.

  4. Factors influencing the marine boundary layer during a cold-air outbreak

    NASA Technical Reports Server (NTRS)

    Stage, S. A.

    1983-01-01

    The model for the cloud-topped marine boundary layer during a cold air outbreak developed by Stage and Businger (1981a) is used in conjunction with a test profile based on a fall outbreak episode over Lake Ontario to study factors influencing marine boundary-layer evolution. Sensitivity tests are done which show changes in layer evolution resulting from variation of wind speed, radiative sky temperature, water surface temperature, humidity of the shoreline sounding and divergence. The behavior of the layer in the presence of a region of cold-water upwelling near the shore is also investigated. It is found that the main effect of the upwelling region is to delay modification of the boundary-layer air.

  5. Numerical model of boundary-layer control using air-jet generated vortices

    NASA Astrophysics Data System (ADS)

    Henry, F. S.; Pearcey, H. H.

    1994-12-01

    Numerical calculations of the three-dimensional flowfield generated by pitched and skewed air jets issuing into an otherwise undisturbed turbulent boundary layer are presented. It is demonstrated that each such jet produces a single strong longitudinal vortex. The strength of the vortex, as inferred from its effect on the development of skin friction, is shown to be influenced by pitch and skew angles, exit velocity, and downstream distance in ways which accord with published experimental results. The calculated beneficial effect that the longitudinal vortices have on the development of skin friction in an adverse pressure gradient demonstrates the mechanism by which vortex generators delay boundary-layer separation. It follows that the numerical model could be used to optimize arrays of air-jet vortex generators. Furthermore, the facility to quantify the interaction between the vortex and the boundary layer should also be valuable in the application of vane vortex generators, and possible even more generally.

  6. FUNDAMENTAL MASS TRANSFER MODELS FOR INDOOR AIR POLLUTION SOURCES

    EPA Science Inventory

    The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. hile empirical approaches based on dynamic chamber data are usef...

  7. Delimitation of air space and outer space - Is such a boundary needed now?

    NASA Technical Reports Server (NTRS)

    Hosenball, S. N.

    1983-01-01

    A discussion is presented of the question of establishing a boundary between air space and outer space. Four theories and approaches for establishing a delimitation between air space and outer space are examined. Spatial approaches include demarcation based on the division of the atmosphere into layers, demarcation based on aerodynamic characteristics of flight instrumentalities (von Karman Line), demarcation according to the lowest perigee of an orbiting satellite, and demarcation based upon the earth's gravitational effects. The functionalist approach is based on the delimitation or definition of the air space/outer space regime by the purpose and activities for which an object is designed in air space or outer space. The arbitrarist approach is supported by those who wish to draw an arbitrary line between air space and outer space. It is proposed that a pragmatist approach will be more useful than the other three approaches. The pragmatist approach advocates not establishing a boundary between air space and outer space at the present time or in the immediate future. It is argued that there are at present no serious problems that can be resolved by the definition/delimitation of air space and outer space.

  8. Aerial observations of air masses transported from East Asia to the Western Pacific: Vertical structure of polluted air masses

    NASA Astrophysics Data System (ADS)

    Hatakeyama, Shiro; Ikeda, Keisuke; Hanaoka, Sayuri; Watanabe, Izumi; Arakaki, Takemitsu; Bandow, Hiroshi; Sadanaga, Yasuhiro; Kato, Shungo; Kajii, Yoshizumi; Zhang, Daizhou; Okuyama, Kikuo; Ogi, Takashi; Fujimoto, Toshiyuki; Seto, Takafumi; Shimizu, Atsushi; Sugimoto, Nobuo; Takami, Akinori

    2014-11-01

    There has been only limited information about the vertical chemical structure of the atmosphere, so far. We conducted aerial observations on 11, 12, and 14 December 2010 over the northern part of the East China Sea to analyze the spatial distribution of atmospheric pollutants from East Asia and to elucidate transformation processes of air pollutants during the long-range transport. On 11 December, a day on which Asian dust created hazy conditions, the average PM10 concentration was 40.69 μg m-3, and we observed high concentrations of chemical components such as Ca2+, NO3-, SO42-, Al, Ca, Fe, and Zn. The height of the boundary layer was about 1200 m, and most species of pollutants (except for dust particles and SO2) had accumulated within the boundary layer. In contrast, concentrations of pollutants were low in the boundary layer (up to 1000 m) on 12 December because clean Pacific air from the southeast had diluted the haze. However, we observed natural chemical components (Na+, Cl-, Al, Ca, and Fe) at 3000 m, the indication being that dust particles, including halite, were present in the lower free troposphere. On 14 December, peak concentrations of SO2 and black carbon were measured within the boundary layer (up to 700 m) and at 2300 m. The concentrations of anthropogenic chemical components such as NO3-, NH4+, and Zn were highest at 500 m, and concentrations of both anthropogenic and natural chemical components (SO42-, Pb, Ca2+, Ca, Al, and Fe) were highest at 2000 m. Thus, it was clearly indicated that the air above the East China Sea had a well-defined, layered structure below 3000 m.

  9. A database and tool for boundary conditions for regional air quality modeling: description and evaluation

    NASA Astrophysics Data System (ADS)

    Henderson, B. H.; Akhtar, F.; Pye, H. O. T.; Napelenok, S. L.; Hutzell, W. T.

    2014-02-01

    Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available observations are too sparse vertically to provide boundary information, particularly for ozone precursors, but global simulations can be used to generate spatially and temporally varying lateral boundary conditions (LBC). This study presents a public database of global simulations designed and evaluated for use as LBC for air quality models (AQMs). The database covers the contiguous United States (CONUS) for the years 2001-2010 and contains hourly varying concentrations of ozone, aerosols, and their precursors. The database is complemented by a tool for configuring the global results as inputs to regional scale models (e.g., Community Multiscale Air Quality or Comprehensive Air quality Model with extensions). This study also presents an example application based on the CONUS domain, which is evaluated against satellite retrieved ozone and carbon monoxide vertical profiles. The results show performance is largely within uncertainty estimates for ozone from the Ozone Monitoring Instrument and carbon monoxide from the Measurements Of Pollution In The Troposphere (MOPITT), but there were some notable biases compared with Tropospheric Emission Spectrometer (TES) ozone. Compared with TES, our ozone predictions are high-biased in the upper troposphere, particularly in the south during January. This publication documents the global simulation database, the tool for conversion to LBC, and the evaluation of concentrations on the boundaries. This documentation is intended to support applications that require representation of long-range transport of air pollutants.

  10. A boundary element-Random walk model of mass transport in groundwater

    USGS Publications Warehouse

    Kemblowski, M.

    1986-01-01

    A boundary element solution to the convective mass transport in groundwater is presented. This solution produces a continuous velocity field and reduces the amount of data preparation time and bookkeeping. By combining this solution and the random walk procedure, a convective-dispersive mass transport model is obtained. This model may be easily used to simulate groundwater contamination problems. The accuracy of the boundary element model has been verified by reproducing the analytical solution to a two-dimensional convective mass transport problem. The method was also used to simulate a convective-dispersive problem. ?? 1986.

  11. Dusty air masses transport between Amazon Basin and Caribbean Islands

    NASA Astrophysics Data System (ADS)

    Euphrasie-Clotilde, Lovely; Molinie, Jack; Prospero, Joseph; Feuillard, Tony; Brute, Francenor; Jeannot, Alexis

    2015-04-01

    Depend on the month, African desert dust affect different parts of the North Atlantic Ocean. From December to April, Saharan dust outbreaks are often reported over the amazon basin and from May to November over the Caribbean islands and the southern regions of USA. This annual oscillation of Saharan dust presence, related to the ITCZ position, is perturbed some time, during March. Indeed, over Guadeloupe, the air quality network observed between 2007 and 2012 several dust events during March. In this paper, using HISPLIT back trajectories, we analyzed air masses trajectories for March dust events observed in Guadeloupe, from 2007 to 2012.We observed that the high pressure positions over the Atlantic Ocean allow the transport of dusty air masses from southern region of West Africa to the Caribbean Sea with a path crossing close to coastal region of French Guyana. Complementary investigations including the relationship between PM10 concentrations recorded in two sites Pointe-a-Pitre in the Caribbean, and Cayenne in French Guyana, have been done. Moreover we focus on the mean delay observed between the times arrival. All the results show a link between pathway of dusty air masses present over amazon basin and over the Caribbean region during several event of March. The next step will be the comparison of mineral dust composition for this particular month.

  12. Direct calculation of acoustic streaming including the boundary layer phenomena in an ultrasonic air pump

    NASA Astrophysics Data System (ADS)

    Wada, Yuji; Koyama, Daisuke; Nakamura, Kentaro

    2012-05-01

    Direct finite difference fluid simulation of acoustic streaming on the fine-meshed three-dimensiona model by graphics processing unit (GPU)-oriented calculation array is discussed. Airflows due to the acoustic traveling wave are induced when an intense sound field is generated in a gap between a bending transducer and a reflector. Calculation results showed good agreement with the measurements in the pressure distribution. In addition to that, several flow-vortices were observed near the boundary of the reflector and the transducer, which have been often discussed in acoustic tube near the boundary, and have never been observed in the calculation in the ultrasonic air pump of this type.

  13. Extended period of K/T boundary mass extinction in the marine realm

    NASA Technical Reports Server (NTRS)

    Keller, G.

    1988-01-01

    The Cretaceous/Tertiary (K/T) boundary mass extinction has been widely recognized as a nearly instantaneous catastrophy among marine plankton such as foraminifera. However, the suddenness of this extinction event may have been overemphasized because most pelagic K/T boundary sequences are stratigraphically incomplete and generally lack the earliest Tertiary (Zones P0 and P1a) either due to carbonate dissolution and/or non-deposition. Stratigraphically complete sections appear to be restricted to continental shelf regions with high sedimentation rates and deposition well above the CCD. Such sections have been recovered from El Kef, Tunisia (1) and Brazos River, Texas. Quantitative foraminiferal analysis of these sections indicate an extinction pattern beginning below the K/T boundary and ending above the boundary. These data imply that the mass extinction event was not geologically instantaneous, but occurred over an extended period of time. Evidence supporting this conclusion is discussed.

  14. Influence of the characteristics of atmospheric boundary layer on the vertical distribution of air pollutant in China's Yangtze River Delta

    NASA Astrophysics Data System (ADS)

    Wang, Chenggang; Cao, Le

    2016-04-01

    Air pollution occurring in the atmospheric boundary layer is a kind of weather phenomenon which decreases the visibility of the atmosphere and results in poor air quality. Recently, the occurrence of the heavy air pollution events has become more frequent all over Asia, especially in Mid-Eastern China. In December 2015, the most severe air pollution in recorded history of China occurred in the regions of Yangtze River Delta and Beijing-Tianjin-Hebei. More than 10 days of severe air pollution (Air Quality Index, AQI>200) appeared in many large cities of China such as Beijing, Tianjin, Shijiazhuang and Baoding. Thus, the research and the management of the air pollution has attracted most attentions in China. In order to investigate the formation, development and dissipation of the air pollutions in China, a field campaign has been conducted between January 1, 2015 and January 28, 2015 in Yangtze River Delta of China, aiming at a intensive observation of the vertical structure of the air pollutants in the atmospheric boundary layer during the time period with heavy pollution. In this study, the observation data obtained in the field campaign mentioned above is analyzed. The characteristics of the atmospheric boundary layer and the vertical distribution of air pollutants in the city Dongshan located in the center of Lake Taihu are shown and discussed in great detail. It is indicated that the stability of the boundary layer is the strongest during the nighttime and the early morning of Dongshan. Meanwhile, the major air pollutants, PM2.5 and PM10 in the boundary layer, reach their maximum values, 177.1μg m-3 and 285μg m-3 respectively. The convective boundary layer height in the observations ranges from approximately 700m to 1100m. It is found that the major air pollutants tend to be confined in a relatively shallow boundary layer, which represents that the boundary layer height is the dominant factor for controlling the vertical distribution of the air pollutants. In

  15. The Chicxulub asteroid impact and mass extinction at the Cretaceous-Paleogene boundary.

    PubMed

    Schulte, Peter; Alegret, Laia; Arenillas, Ignacio; Arz, José A; Barton, Penny J; Bown, Paul R; Bralower, Timothy J; Christeson, Gail L; Claeys, Philippe; Cockell, Charles S; Collins, Gareth S; Deutsch, Alexander; Goldin, Tamara J; Goto, Kazuhisa; Grajales-Nishimura, José M; Grieve, Richard A F; Gulick, Sean P S; Johnson, Kirk R; Kiessling, Wolfgang; Koeberl, Christian; Kring, David A; MacLeod, Kenneth G; Matsui, Takafumi; Melosh, Jay; Montanari, Alessandro; Morgan, Joanna V; Neal, Clive R; Nichols, Douglas J; Norris, Richard D; Pierazzo, Elisabetta; Ravizza, Greg; Rebolledo-Vieyra, Mario; Reimold, Wolf Uwe; Robin, Eric; Salge, Tobias; Speijer, Robert P; Sweet, Arthur R; Urrutia-Fucugauchi, Jaime; Vajda, Vivi; Whalen, Michael T; Willumsen, Pi S

    2010-03-01

    The Cretaceous-Paleogene boundary approximately 65.5 million years ago marks one of the three largest mass extinctions in the past 500 million years. The extinction event coincided with a large asteroid impact at Chicxulub, Mexico, and occurred within the time of Deccan flood basalt volcanism in India. Here, we synthesize records of the global stratigraphy across this boundary to assess the proposed causes of the mass extinction. Notably, a single ejecta-rich deposit compositionally linked to the Chicxulub impact is globally distributed at the Cretaceous-Paleogene boundary. The temporal match between the ejecta layer and the onset of the extinctions and the agreement of ecological patterns in the fossil record with modeled environmental perturbations (for example, darkness and cooling) lead us to conclude that the Chicxulub impact triggered the mass extinction. PMID:20203042

  16. Vertical structure of boundary layer convection during cold-air outbreaks at Barrow, Alaska

    NASA Astrophysics Data System (ADS)

    Wang, Yonggang; Geerts, Bart; Chen, Yaosheng

    2016-01-01

    Boundary layer convection (BLC) is common over high-latitude oceans and adjacent coastal regions when a cold airmass becomes exposed to a sufficient fetch of open water. The vertical structure of mixed-phase BLC clouds and precipitation is examined using the Atmospheric Radiation Measurement Program data set collected at the North Slope of Alaska (NSA) site at Barrow, Alaska. BLC may occur at this location in autumn, when cold air masses originating at higher latitudes advect southward over the still ice-free coastal waters north of Alaska. This study identifies such BLC and documents its occurrence and characteristics. Instruments used for this study include profiling Ka band radars, a depolarization backscatter profiling lidar, a scanning X band radar, a microwave radiometer, a ceilometer, surface meteorological probes, and radiosondes. Six criteria are applied to objectively identify the BLC events, using data collected between 2004 and 2013. BLC episodes are relatively common at the NSA site, but almost exclusively in the month of October, and most episodes are relatively short, less than 10 h in duration. Liquid water is commonly found in these mixed-phase BLC clouds, with a typical liquid water path of 150 g/m2, and snowfall rates average ~3 mm h-1 (water equivalent), in some cases over 10 mm h-1, notwithstanding the low cloud echo tops (~1.0-1.5 km). In one rather weak but persistent episode fall speed estimates derived from the profiling Ka band radar indicates the presence of rimed particles, confirming the convective nature of this precipitation.

  17. Effects of air pollution on thermal structure and dispersion in an urban planetary boundary layer

    NASA Technical Reports Server (NTRS)

    Viskanta, R.; Johnson, R. O.; Bergstrom, R. W.

    1977-01-01

    The short-term effects of urbanization and air pollution on the transport processes in the urban planetary boundary layer (PBL) are studied. The investigation makes use of an unsteady two-dimensional transport model which has been developed by Viskanta et al., (1976). The model predicts pollutant concentrations and temperature in the PBL. The potential effects of urbanization and air pollution on the thermal structure in the urban PBL are considered, taking into account the results of numerical simulations modeling the St. Louis, Missouri metropolitan area.

  18. Analytical model for contaminant mass removal by air sparging

    SciTech Connect

    Rabideau, A.J.; Blayden, J.M.

    1998-12-31

    An analytical model was developed to predict the removal of volatile organic compounds (VOCs) from ground water by air sparging (AS). The model treats the air sparging zone as a completely mixed reactor subject to the removal of dissolved contaminants by volatilization, advection, and first-order decay. Nonequilibrium desorption is approximated as a first-order mass transfer process. The model reproduces the tailing and rebound behavior often observed at AS sites, and would normally require the estimation of three site-specific parameters. Dimensional analysis demonstrates that predicting tailing can be interpreted in terms of kinetic desorption or diffusion of aqueous phase contaminants into discrete air channels. Related work is ongoing to test the model against field data.

  19. The mass and speed dependence of meteor air plasma temperatures

    NASA Technical Reports Server (NTRS)

    Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  20. Diffuse boundary extraction of breast masses on ultrasound by leak plugging

    SciTech Connect

    Cary, T.W.; Conant, E.F.; Arger, P.H.; Sehgal, C.M.

    2005-11-15

    We propose a semiautomated seeded boundary extraction algorithm that delineates diffuse region boundaries by finding and plugging their leaks. The algorithm not only extracts boundaries that are partially diffuse, but in the process finds and quantifies those parts of the boundary that are diffuse, computing local sharpness measurements for possible use in computer-aided diagnosis. The method treats a manually drawn seed region as a wellspring of pixel 'fluid' that flows from the seed out towards the boundary. At indistinct or porous sections of the boundary, the growing region will leak into surrounding tissue. By changing the size of structuring elements used for growing, the algorithm changes leak properties. Since larger elements cannot leak as far from the seed, they produce compact, less detailed boundary approximations; conversely, growing from smaller elements results in less constrained boundaries with more local detail. This implementation of the leak plugging algorithm decrements the radius of structuring disks and then compares the regions grown from them as they increase in both area and boundary detail. Leaks are identified if the outflows between grown regions are large compared to the areas of the disks. The boundary is plugged by masking out leaked pixels, and the process continues until one-pixel-radius resolution. When tested against manual delineation on scans of 40 benign masses and 40 malignant tumors, the plugged boundaries overlapped and correlated well in area with manual tracings, with mean overlap of 0.69 and area correlation R{sup 2} of 0.86, but the algorithm's results were more reproducible.

  1. Numerical study of shock-wave/boundary layer interactions in premixed hydrogen-air hypersonic flows

    NASA Technical Reports Server (NTRS)

    Yungster, Shaye

    1990-01-01

    A computational study of shock wave/boundary layer interactions involving premixed combustible gases, and the resulting combustion processes is presented. The analysis is carried out using a new fully implicit, total variation diminishing (TVD) code developed for solving the fully coupled Reynolds-averaged Navier-Stokes equations and species continuity equations in an efficient manner. To accelerate the convergence of the basic iterative procedure, this code is combined with vector extrapolation methods. The chemical nonequilibrium processes are simulated by means of a finite-rate chemistry model for hydrogen-air combustion. Several validation test cases are presented and the results compared with experimental data or with other computational results. The code is then applied to study shock wave/boundary layer interactions in a ram accelerator configuration. Results indicate a new combustion mechanism in which a shock wave induces combustion in the boundary layer, which then propagates outwards and downstream. At higher Mach numbers, spontaneous ignition in part of the boundary layer is observed, which eventually extends along the entire boundary layer at still higher values of the Mach number.

  2. Improving variational mass-consistent models of hydrodynamic flows via boundary conditions

    NASA Astrophysics Data System (ADS)

    Núñez, M. A.

    2012-04-01

    Variational mass-consistent models for the velocity field v have been used by mesoscale meteorological community to modeling the wind field from an observed field v 0 in a bounded region Ω with boundary Γ. Variational calculus reduces the problem to the solution of an elliptic equation for a Lagrange multiplier λ subject to Dirichlet Boundary Condition (DBC) on flow-through boundaries. In this work, it is shown that DBC decreases the regularity of λ and this in turn decreases the accuracy with which the velocity field satisfies the mass-balance. The boundary condition (BC) v · n = v T · ngiven by the true field v T on the whole boundary Γ, leads only to a Neumann boundary condition (NBC) for λ. Approximations of this BC are studied. Analytic and numerical results show that the velocity field U 0 obtained from v 0 by direct integration of the continuity equation, yields a NBC that improves significantly the fields obtained with DBC's.

  3. Comparison of boundary conditions from Global Chemistry Model (GCM) for regional air quality application

    NASA Astrophysics Data System (ADS)

    Lam, Yun Fat; Cheung, Hung Ming; Fu, Joshua; Huang, Kan

    2015-04-01

    Applying Global Chemistry Model (GCM) for regional Boundary Conditions (BC) has become a common practice to account for long-range transport of air pollutants in the regional air quality modeling. The limited domain model such as CMAQ and CAMx requires a global BC to prescribe the real-time chemical flux at the boundary grids, in order to give a realistic estimate of boundary impacts. Several GCMs have become available recently for use in regional air quality studies. In this study, three GCM models (i.e., GEOS-chem, CHASER and IFS-CB05 MACC provided by Seoul National University, Nagoya University and ECWMF, respectively) for the year of 2010 were applied in CMAQ for the East Asia domain under the framework of Model Inter-comparison Study Asia Phase III (MISC-Asia III) and task force on Hemispheric Transport of Air Pollution (HTAP) jointed experiments. Model performance evaluations on vertical profile and spatial distribution of O3 and PM2.5 have been made on those three models to better understand the model uncertainties from the boundary conditions. Individual analyses on various mega-cities (i.e., Hong Kong, Guangzhou, Taipei, Chongqing, Shanghai, Beijing, Tianjin, Seoul and Tokyo) were also performed. Our analysis found that the monthly estimates of O3 for CHASER were a bit higher than GEOS-Chem and IFS-CB05 MACC, particularly in the northern part of China in the winter and spring, while the monthly averages of PM2.5 in GEOS-Chem were the lowest among the three models. The hourly maximum values of PM2.5 from those three models (GEOS-Chem, CHASER and IFS-CB05 MACC are 450, 321, 331 μg/m3, while the maximum O3 are 158, 212, 380 ppbv, respectively. Cross-comparison of CMAQ results from the 45 km resolution were also made to investigate the boundary impacts from the global GCMs. The results presented here provide insight on how global GCM selection influences the regional air quality simulation in East Asia.

  4. Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

    NASA Astrophysics Data System (ADS)

    Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

    2015-10-01

    We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

  5. Developing mass spectrometric techniques for boundary layer measurement in hypersonic high enthalpy test facilities

    NASA Technical Reports Server (NTRS)

    Wood, G. M., Jr.; Lewis, B. W.; Nowak, R. J.; Eide, D. G.; Paulin, P. A.; Upchurch, B. T.

    1983-01-01

    Thermodynamic flow properties of gases in the boundary layer or the flowfield have been mainly deduced from pressures and temperatures measured on a model. However, further progress with respect to an understanding of these properties requires a more complete characterization of the layer including determination of the gas composition and chemistry. Most attempts to measure boundary layer chemistry involve the employment of a mass spectrometer and an associated gas sampling system. The three major limiting factors which must be addressed for species measurement in aerothermodynamic investigations on models at reentry stream velocities, are gas sampling effects, instrument limitations, and problems with data acquisition. The present investigation is concerned with a concentrated effort to quantitatively identify and correct for instrument and sampling system effects, and to develop a miniaturized high performance mass spectrometer for on-model real-time analysis of the boundary layer and its associated atmosphere.

  6. Study of the Tropospheric Aerosol Structure Under Changing of the Air Mass Type from Lidar Observations in Tomsk

    NASA Astrophysics Data System (ADS)

    Samoilova, S. V.; Balin, Yu. S.; Kokhanenko, G. P.; Penner, I. É.

    2016-04-01

    The aerosol optical characteristics in the main tropospheric layers are investigated based on joint interpretation of data of multi-frequency lidar sensing (110 sessions) and results of modeling of back air mass trajectories. Methodical problems for separating layers with different scattering properties and estimating their vertical boundaries are considered. Three optical criteria are simultaneously used to distinguish aerosol layers from cloud formations, including the gradient of the backscattering coefficient, optical depth, and the depolarization ratio. High values of the lidar ratio (66 sr) and of the Angstrom exponent (1.62) in the shortwavelength spectral range are observed in the boundary layer for Arctic transport. At the same time, low values of these optical parameters are characteristic for Asian transport: the lidar ratio is 54 sr and the Angstrom exponent is 1.1, which is explained by different relative contributions of the coarse and fine aerosol fractions to the air mass.

  7. An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

    NASA Astrophysics Data System (ADS)

    Zander, R.; Messina, A.; Godek, M. L.

    2012-12-01

    The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

  8. Large-scale transport of a CO-enhanced air mass from Europe to the Middle East

    NASA Technical Reports Server (NTRS)

    Connors, V. S.; Miles, T.; Reichle, H. G., Jr.

    1989-01-01

    On November 14, 1981, the shuttle-borne Measurement of Air Pollution from Satellites (MAPS) experiment observed a carbon monoxide (CO) enhanced air mass in the middle troposphere over the Middle East. The primary source of this polluted air was estimated by constructing adiabatic isentropic trajectories backwards from the MAPS measurement location over a 36 h period. The isentropic diagnostics indicate that CO-enhanced air was transported southeastward over the Mediterranean from an organized synoptic-scale weather regime, albeit of moderate intensity, influencing central Europe on November 12. Examination of the evolving synoptic scale vertical velocity and precipitation patterns during this period, in conjuction with Meteosat visible, infrared, and water vapor imagery, suggests that the presence of this disturbed weather system over Europe may have created upward transport of CO-enhanced air between the boundary-layer and midtropospheric levels, and subsequent entrainment in the large-scale northwesterly jet stream flow over Europe and the Mediterranean.

  9. An Immersed Boundary Method in WRF for High Resolution Urban Air Quality Modeling

    NASA Astrophysics Data System (ADS)

    Wiersema, D. J.; Lundquist, K. A.; Martien, P. T.; Rivard, T.; Chow, F. K.

    2013-12-01

    Urban air quality modeling at the neighborhood scale has potential to become an important tool for long term exposure studies, regulation, and urban planning. Current generation models for urban flow or air quality are limited by laborious mesh creation, terrain slope restrictions due to coordinate transformations, lack of atmospheric physics, and/or omission of regional meteorological effects. To avoid these limitations we have extended the functionality of an existing model, IBM-WRF, a modified version of the Weather Research and Forecasting model (WRF) which uses an immersed boundary method (IBM) (Lundquist et al. 2010, 2012). The immersed boundary method used in our model allows for the evaluation of flow over complex urban geometries including vertical surfaces, sharp corners, and local topographic variations. Lateral boundaries in IBM-WRF can be prescribed using output from the standard WRF model, allowing for realistic meteorological input. IBM-WRF is being used to investigate transport and trapping of vehicle emissions around a proposed affordable housing development located adjacent to a major freeway which transports 250,000+ vehicles per day. Urban topography is created using high-resolution airborne LIDAR building data combined with ground elevation data. Emission locations and strengths are assigned using data provided by the Bay Area Air Quality Management District. Development is underway to allow for meteorological input to be created using the WRF model configured to use nested domains. This will allow for synoptic scale phenomena to affect the neighborhood scale IBM-WRF domain, which has a horizontal resolution on the order of one meter. Initial results from IBM-WRF are presented here and will ultimately be used to assist planning efforts to reduce local air pollution exposure and minimize related associated adverse health effects. Lundquist, K., F. Chow, and J. Lundquist, 2010: An immersed boundary method for the weather research and forecasting

  10. Enhanced air pollution via aerosol-boundary layer feedback in China

    NASA Astrophysics Data System (ADS)

    Petäjä, T.; Järvi, L.; Kerminen, V.-M.; Ding, A. J.; Sun, J. N.; Nie, W.; Kujansuu, J.; Virkkula, A.; Yang, X.; Fu, C. B.; Zilitinkevich, S.; Kulmala, M.

    2016-01-01

    Severe air pollution episodes have been frequent in China during the recent years. While high emissions are the primary reason for increasing pollutant concentrations, the ultimate cause for the most severe pollution episodes has remained unclear. Here we show that a high concentration of particulate matter (PM) will enhance the stability of an urban boundary layer, which in turn decreases the boundary layer height and consequently cause further increases in PM concentrations. We estimate the strength of this positive feedback mechanism by combining a new theoretical framework with ambient observations. We show that the feedback remains moderate at fine PM concentrations lower than about 200 μg m-3, but that it becomes increasingly effective at higher PM loadings resulting from the combined effect of high surface PM emissions and massive secondary PM production within the boundary layer. Our analysis explains why air pollution episodes are particularly serious and severe in megacities and during the days when synoptic weather conditions stay constant.

  11. Enhanced air pollution via aerosol-boundary layer feedback in China

    PubMed Central

    Petäjä, T.; Järvi, L.; Kerminen, V.-M.; Ding, A.J.; Sun, J.N.; Nie, W.; Kujansuu, J.; Virkkula, A.; Yang, X.; Fu, C.B.; Zilitinkevich, S.; Kulmala, M.

    2016-01-01

    Severe air pollution episodes have been frequent in China during the recent years. While high emissions are the primary reason for increasing pollutant concentrations, the ultimate cause for the most severe pollution episodes has remained unclear. Here we show that a high concentration of particulate matter (PM) will enhance the stability of an urban boundary layer, which in turn decreases the boundary layer height and consequently cause further increases in PM concentrations. We estimate the strength of this positive feedback mechanism by combining a new theoretical framework with ambient observations. We show that the feedback remains moderate at fine PM concentrations lower than about 200 μg m−3, but that it becomes increasingly effective at higher PM loadings resulting from the combined effect of high surface PM emissions and massive secondary PM production within the boundary layer. Our analysis explains why air pollution episodes are particularly serious and severe in megacities and during the days when synoptic weather conditions stay constant. PMID:26753788

  12. Relationship between mass extinction and iridium across the Cretaceous-Paleogene boundary in New Jersey

    USGS Publications Warehouse

    Miller, K.G.; Sherrell, Robert M.; Browning, J.V.; Field, M.P.; Gallagher, W.; Olsson, R.K.; Sugarman, P.J.; Tuorto, S.; Wahyudi, H.

    2010-01-01

    We directly link iridium (Ir) anomalies in New Jersey to the mass extinction of marine plankton marking the Cretaceous-Paleogene (K-Pg) boundary. We confirm previous reports of an Ir anomaly 20 cm below the extinction of Cretaceous macrofauna (the "Pinna" bed) with new results from a muddy sand section from Tighe Park, Freehold, New Jersey (United States), but we also show that Ir anomalies correlate with marine mass extinctions at three other clay-rich New Jersey sections. Thus, we attribute the anomaly at Freehold to the downward movement of Ir and reaffirm the link between impact and mass extinction. ?? 2010 Geological Society of America.

  13. MHD simulations of boundary layer formation along the dayside Venus ionopause due to mass loading

    NASA Astrophysics Data System (ADS)

    McGary, J. E.; Pontius, D. H.

    1994-02-01

    A two-dimensional magnetohydrodynamic (MHD) simulation of mass-loaded solar wind flow around the dayside of Venus is presented. For conditions appropriate to a low-altitude ionopause the simulations show that mass loading from the pickup of oxygen ions produces a boundary layer of finite thickness along the ionopause. Within this layer the temperatures exhibit strong gradients normal to and away from the ionopause. Furthermore, there is a shear in the bulk flow velocity across the boundary layer, such that the (predominantly tangential) flow decreases in speed as the ionopause is approached and remains small along the ionopause, consistent with Pioneer Venus observations. The total mass density increases significantly as the flow approaches the ionopause, where the contribution of O(+) to the total number density is a few percent. Numerical simulations are carried out for various mass addition rates and demonstrate that the boundary layer develops when oxygen ion production exceeds approximately 2 x 105/cu m/s. For the upstream solar wind parameters and mass loading rates chosen for these simulations, the results are consistent with observations made on the dayside of Venus for average ionopause conditions near 300 km.

  14. Enantiomeric signatures of organochlorine pesticides in Asian, trans-Pacific, and western U.S. air masses.

    PubMed

    Genualdi, Susan A; Simonich, Staci L Massey; Primbs, Toby K; Bidleman, Terry F; Jantunen, Liisa M; Ryoo, Keon-Sang; Zhu, Tong

    2009-04-15

    The enantiomeric signatures of organochlorine pesticides were measured in air masses from Okinawa, Japan and three remote locations in the Pacific Northwestern United States: Cheeka Peak Observatory (CPO), a marine boundary layer site on the Olympic Peninsula of Washington at 500 m above sea level (m.a.s.l); Mary's Peak Observatory (MPO), a site at 1250 m.a.s.l in Oregon's Coast range; and Mt. Bachelor Observatory (MBO), a site at 2763 m.a.s.l in Oregon's Cascade range. The enantiomeric signatures of composite soil samples, collected from China, South Korea, and the western U.S. were also measured. The data from chiral analysis was expressed asthe enantiomeric fraction, defined as (+) enantiomer/(sum of the (+) and (-) enantiomers), where a racemic composition has EF = 0.5. Racemic alpha-hexachlorocyclohexane (alpha-HCH) was measured in Asian air masses at Okinawa and in Chinese and South Korean soils. Nonracemic alpha-HCH (EF = 0.528 +/- 0.0048) was measured in regional air masses at CPO, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the alpha-HCH EFs were significantly more racemic (EF = 0.513 +/- 0.0003, p < 0.001). Racemic alpha-HCH was consistently measured at MPO and MBO in trans-Pacific air masses that had spent considerable time in the free troposphere. The alpha-HCH EFs in CPO, MPO, and MBO air masses were negatively correlated (p = 0.0017) with the amount of time the air mass spent above the boundary layer, along the 10-day back air mass trajectory, prior to being sampled. This suggests that, on the West coast of the U.S., the alpha-HCH in the free troposphere is racemic. Racemic signatures of cis- and trans-chlordane were measured in air masses at all four air sampling sites, suggesting that Asian and U.S. urban areas continue to be sources of chlordane that has not yet been biotransformed. PMID:19475954

  15. The role of boundary layer schemes in meteorological and air quality simulations of the Taiwan area

    NASA Astrophysics Data System (ADS)

    Cheng, Fang-Yi; Chin, Shan-Chieh; Liu, Tsun-Hsien

    2012-07-01

    Adequate air quality modeling is reliant on accurate meteorological simulations especially in the planetary boundary layer (PBL). To understand how the boundary layer processes affect the mixing and transport of air pollutants, the sensitivity of Weather Research Forecasting (WRF) model with different PBL schemes (YSU and MYJ) is utilized. Community Multiscale Air Quality (CMAQ) modeling system is performed subsequently to study the effects of the PBL physical processes on the meteorological and air quality simulations. A comparison is made of two distinct atmospheric conditions. Case 1 considers the influence of the Asian continental outflow where air pollutants carried by long-range transport (LRT) to Taiwan. The variation in ozone (O3) concentration between the two sensitivity runs is mainly caused by the PBL height difference with WRF-MYJ predicts much deeper PBL height near the frontal low-pressure region than does the WRF-YSU. Case 2 is associated with the land-sea breeze flow. In this situation O3 is locally produced from the western side of the country where major metropolitan cities and highways are located. Distinctions in O3 are caused by difference in the strength of the land-sea breeze flow between the two runs. At night the WRF-YSU predicts a weaker offshore land breeze than does the WRF-MYJ near the western coastline. During the day, the WRF-YSU predicts a stronger sea breeze near the offshore area than does the WRF-MYJ, while over the landside, the WRF-YSU predicts a lower wind speed than does the WRF-MYJ.

  16. Current state and prospects of researches on the control of turbulent boundary layer by air blowing

    NASA Astrophysics Data System (ADS)

    Kornilov, V. I.

    2015-07-01

    The paper presents the analytical review of the current state of the investigations and development trends on the problem of turbulent friction and aerodynamic drag reduction in simple model configurations, which is among key ones in modern aeromechanics. Under consideration is the modern fast progressing method of the turbulent flow control by air- and other gases (micro)blowing through a permeable surface, which is utilized in incompressible and compressible turbulent boundary layers. Several computational results to understand the essential flow physics are also included. The problem of simulation of the flow over a perforated wall where some ambiguities, in particular, at the permeable/impermeable boundary being still remained is discussed. Special attention is paid to the analysis of most important experimental and numerical results obtained with the air blowing through a finely-perforated surface, analysis of the physical peculiarities and regularities of the flow with the blowing, probability to describe the properties of such a flow within simple approach frameworks, evaluation of the efficiency of this control method, as well as the trends and opportunities of this method progress in view of state-of-the-art achievements. Although this technology has a penalty for developing the effective turbulent-flow control method, some modifications of the air blowing are an attractive alternative for real applications.

  17. Low-speed Investigation of a Semisubmerged Air Scoop with and Without Boundary-layer Suction

    NASA Technical Reports Server (NTRS)

    Pierpont, P Kenneth; Howell, Robert R

    1951-01-01

    A preliminary low-speed investigation has been made of an air scoop submerged one-half the inlet height in a depression on the surface of a simulated fuselage. Boundary-layer suction was used on the steep approach ramp to improve the internal flow. A 6-degree-included-angle diffuser with an area ratio of 1.9:1 was located behind the inlet in the model. Most of the tests were conducted with an initial turbulent boundary layer believed to approximate that which would occur on the forward part of a fuselage. A few tests were made with a boundary layer about 2.5 times the thickness of the original boundary layer to determine the effect of moving the inlet further rearward on the fuselage. The effects of suction-slot location and slot width were determined and a few tests with area suction were made. The maximum quantity of suction flow was about 15 percent of the inlet flow at an inlet-velocity ratio of 0.6.

  18. Design of an air ejector for boundary-layer bleed of an acoustically treated turbofan engine inlet during ground testing

    NASA Technical Reports Server (NTRS)

    Stakolich, E. G.

    1978-01-01

    An air ejector was designed and built to remove the boundary-layer air from the inlet a turbofan engine during an acoustic ground test program. This report describes; (1) how the ejector was sized; (2) how the ejector performed; and (3) the performance of a scale model ejector built and tested to verify the design. With proper acoustic insulation, the ejector was effective in reducing boundary layer thickness in the inlet of the turbofan engine while obtaining the desired acoustic test conditions.

  19. High Resolution 2-D Fluoresd3nce Imaging of the Mass Boundary Layer Thickness at Free Water Surfaces

    NASA Astrophysics Data System (ADS)

    Kräuter, C.; Trofimova, D.; Kiefhaber, D.; Krah, N.; Jähne, B.

    2014-03-01

    A novel 2-D fluorescence imaging technique has been developed to visualize the thickness of the aqueous mass boundary layer at a free water surface. Fluorescence is stimulated by high-power LEDs and is observed from above with a low noise, high resolution and high-speed camera. The invasion of ammonia into water leads to an increase in pH (from a starting value of 4), which is visualized with the fluorescent dye pyranine. The flux of ammonia can be controlled by controlling its air side concentration. A higher flux leads to basic pH values (pH > 7) in a thicker layer at the water surface from which fluorescent light is emitted. This allows the investigation of processes affecting the transport of gases in different depths in the aqueous mass boundary layer. In this paper, the chemical system and optical components of the measurement method are presented and its applicability to a wind-wave tank experiment is demonstrated.

  20. Mass-conserved volumetric lattice Boltzmann method for complex flows with willfully moving boundaries

    NASA Astrophysics Data System (ADS)

    Yu, Huidan; Chen, Xi; Wang, Zhiqiang; Deep, Debanjan; Lima, Everton; Zhao, Ye; Teague, Shawn D.

    2014-06-01

    In this paper, we develop a mass-conserved volumetric lattice Boltzmann method (MCVLBM) for numerically solving fluid dynamics with willfully moving arbitrary boundaries. In MCVLBM, fluid particles are uniformly distributed in lattice cells and the lattice Boltzmann equations deal with the time evolution of the particle distribution function. By introducing a volumetric parameter P (x,y,z,t) defined as the occupation of solid volume in the cell, we distinguish three types of lattice cells in the simulation domain: solid cell (pure solid occupation, P =1), fluid cell (pure fluid occupation, P =0), and boundary cell (partial solid and partial fluid, 0boundary and the flow; (2) streaming accompanying a volumetric bounce-back procedure in boundary cells; and (3) boundary-induced volumetric fluid migration moving the residual fluid particles into the flow domain when the boundary swipes over a boundary cell toward a solid cell. The MCVLBM strictly satisfies mass conservation and can handle irregular boundary orientation and motion with respect to the mesh. Validation studies are carried out in four cases. The first is to simulate fluid dynamics in syringes focusing on how MCVLBM captures the underlying physics of flow driven by a willfully moving piston. The second and third cases are two-dimensional (2D) peristaltic flow and three-dimensional (3D) pipe flow, respectively. In each case, we compare the MCVLBM simulation result with the analytical solution and achieve quantitatively good agreements. The fourth case is to simulate blood flow in human aortic arteries with a very complicated irregular boundary. We study steady flow in two dimensions and unsteady flow via the pulsation of the cardiac cycle in three dimensions. In the 2D case, both vector (velocity) and

  1. Atmospheric Boundary Layer Height Evolution with Lidar in Buenos Aires from 2008 to 2011

    NASA Astrophysics Data System (ADS)

    Pawelko, Ezequiel Eduardo; Salvador, Jacobo Omar; Ristori, Pablo Roberto; Pallotta, Juan Vicente; Otero, Lidia Ana; Quel, Eduardo Jaime

    2016-06-01

    The analysis of the atmospheric boundary layer top height evolution is obtained from 2008 to 2011 in Buenos Aires using the multiwavelength lidar located at CEILAP (CITEDEF-CONICET) (34°33' S; 58°30' W; 17 m asl). Algorithms recognition based on covariance wavelet transform are applied to obtain seasonal statistics. This method is being evaluated for use in the Lidar Network in Argentina and it is being deployed in Patagonia region currently. The technique operates in real time in both low and high aerosol loads and with almost no human supervision.

  2. Heat transport in the marine atmospheric boundary layer during an intense cold air outbreak

    NASA Technical Reports Server (NTRS)

    Chou, Shu-Hsien; Zimmerman, Jeffrey

    1988-01-01

    The generation of the virtual heat flux in the convective MABL associated with the January 28, 1986 intense cold air airbreak offshore of the Carolinas is studied. A technique based on the joint frequency distribution of the virtual potential temperature and vertical motion (Mahrt and Paumier, 1984) is used. The results suggest that, if buoyancy is mainly driven by the temperature flux, the physical processes for generating buoyancy flux are about the same for boundary layers over land and ocean, even with different convective regimes.

  3. Simulation of pulmonary air flow with a subject-specific boundary condition

    PubMed Central

    Yin, Youbing; Choi, Jiwoong; Hoffman, Eric A.; Tawhai, Merryn H.; Lin, Ching-Long

    2011-01-01

    We present a novel image-based technique to estimate a subject-specific boundary condition (BC) for computational fluid dynamics (CFD) simulation of pulmonary air flow. The information of regional ventilation for an individual is derived by registering two computed tomography (CT) lung datasets and then passed to the CT-resolved airways as the flow BC. The CFD simulations show that the proposed method predicts lobar volume changes consistent with direct image-measured metrics, whereas the other two traditional BCs (uniform velocity or uniform pressure) yield lobar volume changes and regional pressure differences inconsistent with observed physiology. PMID:20483412

  4. Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

    NASA Astrophysics Data System (ADS)

    Dugaria, S.; Moro, L.; Del, D., Col

    2015-11-01

    The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

  5. Anoxia pre-dates Frasnian-Famennian boundary mass extinction horizon in the Great Basin, USA

    USGS Publications Warehouse

    Bratton, John F.; Berry, William B.N.; Morrow, Jared R.

    1999-01-01

    Major and trace metal results from three Great Basin stratigraphic sections with strong conodont biostratigraphy identify a distinct anoxic interval that precedes, but ends approximately 100 kyr before, the Frasnian–Famennian (F–F, mid-Late Devonian) boundary mass extinction horizon. This horizon corresponds to the final and most severe step of a more protracted extinction period. These results are inconsistent with data reported by others from the upper Kellwasser horizon in Europe, which show anoxia persisting up to the F–F boundary in most sections. Conditions returned to fully oxygenated prior to the F–F boundary in the study area. These data indicate that the worst part of the F–F extinction was not related directly to oceanic anoxia in this region and potentially globally.

  6. Distribution of natural halocarbons in marine boundary air over the Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Yokouchi, Yoko; Inoue, Jun; Toom-Sauntry, Desiree

    2013-08-01

    Ongoing environmental changes in the Arctic will affect the exchange of natural volatile organic compounds between the atmosphere and the Arctic Ocean. Among these compounds, natural halocarbons play an important role in atmospheric ozone chemistry. We measured the distribution of five major natural halocarbons (methyl iodide, bromoform, dibromomethane, methyl chloride, and methyl bromide) together with dimethyl sulfide and tetrachloroethylene in the atmosphere over the Arctic Ocean (from the Bering Strait to 79°N) and along the cruise path to and from Japan. Methyl iodide, bromoform, and dibromomethane were most abundant near perennial sea ice in air masses derived from coastal regions and least abundant in the northernmost Arctic, where the air masses had passed over the ice pack, whereas methyl chloride and methyl bromide showed the opposite distribution pattern. Factors controlling those distributions and future prospects for natural halocarbons in the Arctic are discussed.

  7. Evaluation of biological air filters for livestock ventilation air by membrane inlet mass spectrometry.

    PubMed

    Feilberg, Anders; Adamsen, Anders P S; Lindholst, Sabine; Lyngbye, Merete; Schäfer, Annette

    2010-01-01

    Biological air filters have been proposed as a cost-effective technology for reducing odor emissions from intensive swine production facilities. In this work we present results from the application of membrane inlet mass spectrometry (MIMS) for continuously monitoring the removal of odorous compounds in biological air filters. The sensitivity and selectivity were tested on synthetic samples of selected odorous compounds, and linearity and detection limits in the lower ppb range were demonstrated for all compounds tested (methanethiol, dimethyl sulfide, carboxylic acids, 4-methylphenol, aldehydes, indole, and skatole) except trimethylamine. The method was applied in situ at two full-scale filters installed at swine houses. The results have been compared with analyses by thermal desorption gas chromatography-mass spectrometry (TD-GC/MS), and odor was measured by olfactometry. By comparison with TD-GC/MS, observed MIMS signals were assigned to 4-methylphenol, 4-ethylphenol, indole, skatole, the sum of volatile reduced organic sulfur compounds (ROS), and three subgroups of carboxylic acids. The removal rates were observed to be related to air-water partitioning with removal efficiencies in the range of 0 to 50% for low-soluble organic sulfur compounds and high removal efficiencies (typically 80-100%) for more soluble phenols and carboxylic acids. Based on the results and published odor threshold values, it is estimated that the low removal efficiency of ROS is the main limitation for achieving a higher odor reduction. PMID:20400604

  8. Cold-air outbreak during GALE - Lidar observations and modeling of boundary layer dynamics

    NASA Technical Reports Server (NTRS)

    Boers, Reinout; Melfi, S. H.; Palm, Stephen P.

    1991-01-01

    Two cold-air outbreaks were studied during the Genesis of Atlantic Lows Experiment. A lidar system was operated to observe the boundary layer evolution and the development of clouds. On the first day (January 30, 1986) boundary layer rise was less than 50 percent of the value for the second day (March 2, 1986). On the first day only a thin broken cloud cover formed, while on the second day a thick solid cloud deck formed - although the average moisture content was 60 percent of that on the first day. A trajectory slab model was employed to simulate the evolution of the layer over the ocean near the east Atlantic shore. The model allows for vertical gradients in conservative variables under neutrally buoyant conditions. The primary effect of these assumptions, which are based on observed thermodynamic profiles, is to reduce cloudiness to be more in line with observations. Boundary-layer depth was reasonably well predicted as was sensible and latent heat flux.

  9. Effect on a shock wave boundary layer interaction of air jet vortex generators

    NASA Astrophysics Data System (ADS)

    Souverein, L. J.; Debiève, J.-F.

    2012-01-01

    The effect of upstream injection by means of continuous Air Jet Vortex Generators (AJVGs) on a shock wave turbulent boundary layer interaction is experimentally investigated. The baseline interaction is of the impinging type, with a flow deflection angle of 9.5° , a Mach number Me = 2.3, and a momentum thickness based Reynolds number of 5,000. Considered are the effects of the AJVGs on the upstream boundary layer flow topology and on the spatial and dynamical characteristics of the interaction. To this aim, Stereoscopic Particle Image Velocimetry has been employed, in addition to hot-wire anemometry (HWA) for the investigation of the dynamical characteristics of the reflected shock. It is shown that the AJVGs significantly modify the three-dimensionality of the upstream boundary layer. Overall, the AJVGs cause a reduction of the separation bubble length and height. In addition, the energetic frequency range of the reflected shock is increased by approximately 50%, which is in qualitative agreement with the smaller separation bubble size.

  10. The evolution of the boundary layer in turbulent Rayleigh-Bénard convection in air

    NASA Astrophysics Data System (ADS)

    du Puits, R.; Willert, C.

    2016-04-01

    We report measurements of the near-wall flow field in turbulent Rayleigh-Bénard convection in air (Pr = 0.7) using particle image velocimetry. The measurements were performed in a thin, rectangular sample at fixed Rayleigh number Ra = 1.45 × 1010. In particular, we focus on the evolution of the boundary layer that a single convection roll generates along its path at the lower horizontal plate. We identify three specific flow regions along this path: (i) a region of wall-normal impingement of the down flow close to one corner of the sample, (ii) a region where a shear layer with almost constant thickness evolves, and (iii) a region in which this boundary layer grows and eventually detaches from the plate surface at the opposite corner of the sample. Our measurements with a spatial resolution better than 1/500 of the total thickness of the boundary layer show that the typical velocity field as well as its statistics qualitatively varies between the three flow regions. In particular, it could be verified that the shear layer region covering about 75% of the total area of the plate is in transition to turbulence at the Rayleigh number as low as investigated in the present work.

  11. Mass transfer across combustion gas thermal boundary layers - Power production and materials processing implications

    NASA Technical Reports Server (NTRS)

    Rosner, D. E.

    1985-01-01

    The effects of Soret diffusion (for vapors) and thermophoresis (for particles) are illustrated using recent optical experiments and boundary layer computations. Mass transfer rate augmentations of up to a factor of 1000 were observed and predicted for submicron-particle capture by cooled solid surfaces, while mass transfer suppressions of more than 10 to the -10th-fold were predicted for 'overheated' surfaces. It is noted that the results obtained are of interest in connection with such technological applications as fly-ash capture in power generation equipment and glass droplet deposition in optical-waveguide manufacture.

  12. Mass extinction of lizards and snakes at the Cretaceous-Paleogene boundary

    NASA Astrophysics Data System (ADS)

    Longrich, Nicholas R.; Bhullar, Bhart-Anjan S.; Gauthier, Jacques A.

    2012-12-01

    The Cretaceous-Paleogene (K-Pg) boundary is marked by a major mass extinction, yet this event is thought to have had little effect on the diversity of lizards and snakes (Squamata). A revision of fossil squamates from the Maastrichtian and Paleocene of North America shows that lizards and snakes suffered a devastating mass extinction coinciding with the Chicxulub asteroid impact. Species-level extinction was 83%, and the K-Pg event resulted in the elimination of many lizard groups and a dramatic decrease in morphological disparity. Survival was associated with small body size and perhaps large geographic range. The recovery was prolonged; diversity did not approach Cretaceous levels until 10 My after the extinction, and resulted in a dramatic change in faunal composition. The squamate fossil record shows that the end-Cretaceous mass extinction was far more severe than previously believed, and underscores the role played by mass extinctions in driving diversification.

  13. Mass extinction of lizards and snakes at the Cretaceous–Paleogene boundary

    PubMed Central

    Longrich, Nicholas R.; Bhullar, Bhart-Anjan S.; Gauthier, Jacques A.

    2012-01-01

    The Cretaceous–Paleogene (K-Pg) boundary is marked by a major mass extinction, yet this event is thought to have had little effect on the diversity of lizards and snakes (Squamata). A revision of fossil squamates from the Maastrichtian and Paleocene of North America shows that lizards and snakes suffered a devastating mass extinction coinciding with the Chicxulub asteroid impact. Species-level extinction was 83%, and the K-Pg event resulted in the elimination of many lizard groups and a dramatic decrease in morphological disparity. Survival was associated with small body size and perhaps large geographic range. The recovery was prolonged; diversity did not approach Cretaceous levels until 10 My after the extinction, and resulted in a dramatic change in faunal composition. The squamate fossil record shows that the end-Cretaceous mass extinction was far more severe than previously believed, and underscores the role played by mass extinctions in driving diversification. PMID:23236177

  14. Profiling the PM2.5 mass concentration vertical distribution in the boundary layer

    NASA Astrophysics Data System (ADS)

    Tao, Z.; Wang, Z.; Yang, S.; Shan, H.; Ma, X.; Zhang, H.; Zhao, S.; Liu, D.; Xie, C.; Wang, Y.

    2015-12-01

    Fine particle (PM2.5) affects human life and activities directly; the detection of PM2.5 mass concentration profile is very essential due to its practical and scientific meanings (such as, quantifying of air quality and its variability, and improving air quality forecast and assessment). But so far, it is difficult to detect PM2.5 mass concentration profile. The proposed methodology to study the relationship between aerosol extinction coefficient and PM2.5 mass concentration is described, which indicates that the PM2.5 mass concentration profile could be retrieved by combining a charge-coupled device (CCD) side-scatter lidar and a PM2.5 sampling detector. When the relative humidity is less than 70 %, PM2.5 mass concentration is proportional to aerosol extinction coefficient, and then the specific coefficient can be calculated. Using this specific coefficient, aerosol extinction profile is converted to PM2.5 mass concentration profile. Three cases of clean night (on 21 September 2014), pollutant night (on 17 March 2014), and heavy pollutant night (on 13 February 2015) are studied. The characteristic of PM2.5 mass concentration profile in near-ground during these three nights' cases in the western suburb of Hefei city was discussed. The PM2.5 air pollutant concentration is comparatively large in close surface varying with time and altitude. The experiment results show that the CCD side-scatter lidar combined with a PM2.5 detector is an effective and new method to explore pollutant mass concentration profile in near-ground.

  15. Profiling the PM2.5 mass concentration vertical distribution in the boundary layer

    NASA Astrophysics Data System (ADS)

    Tao, Zongming; Wang, Zhenzhu; Yang, Shijun; Shan, Huihui; Ma, Xiaomin; Zhang, Hui; Zhao, Sugui; Liu, Dong; Xie, Chenbo; Wang, Yingjian

    2016-04-01

    Fine particles (PM2.5) affect human life and activities directly; the detection of PM2.5 mass concentration profile is very essential due to its practical and scientific significance (such as the quantification of air quality and its variability as well as the assessment of improving air quality forecast). But so far, it has been difficult to detect PM2.5 mass concentration profile. The proposed methodology to study the relationship between aerosol extinction coefficient and PM2.5 mass concentration is described, which indicates that the PM2.5 mass concentration profile could be retrieved by combining a charge-coupled device (CCD) side-scatter lidar with a PM2.5 sampling detector. When the relative humidity is less than 70 %, PM2.5, mass concentration is proportional to the aerosol extinction coefficient, and then the specific coefficient can be calculated. Through this specific coefficient, aerosol extinction profile is converted to PM2.5 mass concentration profile. Three cases of clean night (on 21 September 2014), pollutant night (on 17 March 2014), and heavy pollutant night (on 13 February 2015) are studied. The characteristics of PM2.5 mass concentration profile at the near-ground level during the cases of these 3 nights in the western suburb of Hefei city were discussed. The PM2.5 air pollutant concentration is comparatively large close to the surface and varies with time and altitude. The experiment results show that the CCD side-scatter lidar combined with a PM2.5 detector is an effective and new method to explore pollutant mass concentration profile at the near-ground level.

  16. Use of Chiral Signatures of Organochlorine Pesticides in Asian, Trans-Pacific, and Western U.S. Air Masses to Identify Source Regions

    NASA Astrophysics Data System (ADS)

    Simonich, S.; Genualdi, S.; Primbs, T.; Ryoo, K.; Bidleman, T.; Jantunen, L.

    2008-12-01

    Chiral signatures of organochlorine pesticides were measured in air masses on Okinawa Japan and three remote locations in the Pacific Northwestern U.S.: Cheeka Peak Observatory (CPO), a coastal site on the Olympic Peninsula of Washington at 500 m; Mary's Peak Observatory (MPO), a site at 1250 m in Oregon's Coast range; and Mt. Bachelor Observatory (MBO), a site at 2300 m in Oregon's Cascade range. The chiral signature of composite soil samples collected from agricultural areas in China and South Korea were also measured. Racemic alpha-HCH was measured in Asian air masses and soil from China and South Korea. Non-racemic (enantiomer fraction (EF) = 0.528 ± 0.0048) alpha-HCH was measured in regional air masses at CPO, a marine boundary layer site, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the EFs were significantly (p-value <0.001) more racemic (EF = 0.513 ± 0.0003). Racemic alpha-HCH was consistently measured in trans- Pacific air masses at MPO and MBO. The alpha-HCH EFs in CPO, MPO, and MBO air masses were positively correlated (p-value = 0.0017) with the amount of time the air mass spent above the boundary layer along the 10-day back air mass trajectory prior to being sampled. This suggests that the alpha-HCH in the free troposphere is racemic. The racemic signatures of cis and trans chlordane in air masses at all four air sampling sites suggest that Asian and U.S. urban areas continue to be sources of chlordanes that have not yet undergone biotransformation.

  17. High-Altitude Air Mass Zero Calibration of Solar Cells

    NASA Technical Reports Server (NTRS)

    Woodyard, James R.; Snyder, David B.

    2005-01-01

    Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

  18. Monitoring Trace Contaminants in Air Via Ion Trap Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Palmer, Peter T.; Karr, Dane; Pearson, Richard; Valero, Gustavo; Wong, Carla

    1995-01-01

    Recent passage of the Clean Air Act with its stricter regulation of toxic gas emissions, and the ever-growing number of applications which require faster turnaround times between sampling and analysis are two major factors which are helping to drive the development of new instrument technologies for in-situ, on-line, real-time monitoring. The ion trap, with its small size, excellent sensitivity, and tandem mass spectrometry capability is a rapidly evolving technology which is well-suited for these applications. In this paper, we describe the use of a commercial ion trap instrument for monitoring trace levels of chlorofluorocarbons (CFCs) and volatile organic compounds (VOCs) in air. A number of sample introduction devices including a direct transfer line interface, short column GC, and a cryotrapping interface are employed to achieve increasing levels of sensitivity. MS, MS/MS, and MS/MS/MS methods are compared to illustrate trade-offs between sensitivity and selectivity. Filtered Noise Field (FNF) technology is found to be an excellent means for achieving lower detection limits through selective storage of the ion(s) of interest during ionization. Figures of merit including typical sample sizes, detection limits, and response times are provided. The results indicate the potential of these techniques for atmospheric assessments, the High Speed Research Program, and advanced life support monitoring applications for NASA.

  19. Identification and Tracking of Polluted Air Masses in the South-Central Coast Air Basin.

    NASA Astrophysics Data System (ADS)

    Moore, G. E.; Douglas, S. G.; Kessler, R. C.; Killus, J. P.

    1991-05-01

    Canister samples of air taken during the South-Central Coast Cooperative Air Monitoring Program (SCCCAMP) 1985 field study program were analyzed for concentrations of over 50 hydrocarbons as well as chlorofluorocarbons (CFCs), carbon monoxide, hydrogen, and methane. Additional evidence of location and timing of airmass origin was obtained by utilizing long-lived halocarbons such as F-12 as `tracers of opportunity' in conjunction with known source profiles. Wind trajectories were developed from hourly gridded wind fields produced by a diagnostic wind model utilizing observed wind data. These wind trajectories were used to determine how pollutants from major source areas might be transported to sampling sites. Particulate lidar height-distance traverses were made from aircraft that provided a view of pollutant layering. Mixing height and vertical pollutant concentration distributions were obtained in order to determine if observed pollutant concentrations were consistent with the degree of stagnation present and hypothesized transport pathway.Analyses to track specific polluted air masses were conducted for the 13 September, 21 September, 23-24 September, and 2-3 October 1985 intensive study periods. The analyses find that elevated ozone concentrations during these periods are primarily attributed to transport and storage of ozone-enriched air from Los Angeles. During one type of episode (2-3 October) ozone and ozone precursors are stored near the surface over the Santa Barbara Channel overnight and transported into coastal areas on the following day. In another type of episode (23-24 September) ozone is transported into the study domain from the San Fernando Valley and Los Angeles via flow around the Santa Monica Hills. Transport of pollutant-enriched air takes place in a layer 200-500 m aloft, in many places overlaying cleaner marine-layer air. This advected ozone is mixed down to contribute to ground-level ozone concentrations over terrain where the marine layer

  20. Aerosol composition in a stagnant air mass impacted by dense fogs: preliminary results

    SciTech Connect

    Jacob, D.J.; Munger, J.W.; Waldman, J.M.; Hoffman, M.R.

    1984-01-01

    Over the last two winters, our research group has been investigating the chemical composition of fogwater and haze aerosol during wintertime stagnation episodes in the San Joaquin Valley of California. The valley is encompassed by mountain ranges. During the winter a strong subsidence inversion based below the natural boundaries of the valley restricts the ventilation of the air masses below the inversion. The residence time of an air parcel in the valley under these stagnation conditions is on the order of 8 days. Because the trapped air is very humid, stagnation episodes are associated with a persistent thick haze and frequent widespread nighttime fogs. During the winter 1982-1983 the authors sampled fog and haze at one site (Bakersfield); results from this preliminary study have been discussed in detail in a previous report. In the winter 1983-1984 the scale of the program was expanded in order to test hypotheses formulated as a result of first year data. The present paper first reports briefly on the 1982-1983 results and outlines the essential conclusions. They then describe the large-scale experiment conducted during the winter of 1983-1984, and discuss some preliminary fogwater data.

  1. VOC Composition of Air Masses Transported from Asia to the U.S. West Coast

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Warneke, C.; Kuster, B.; Parrish, D.; Holloway, J.; Huebler, G.; Fehsenfeld, F.

    2002-12-01

    Airborne measurements of volatile organic compounds (VOCs) were performed using a proton-transfer-reaction mass spectrometer (PTR-MS) operated onboard a NOAA WP-3 aircraft during the Intercontinental Transport and Chemical Transformation (ITCT) experiment in 2002. Enhancements of acetone (CH3COCH3), methanol (CH3OH), acetonitrile (CH3CN) and in some cases benzene were observed in air masses that were impacted by outflow from Asia. The enhancement ratios with respect to carbon monoxide are compared to emission factors for fossil fuel combustion and biomass burning, which gives some insight into the sources responsible for the pollution. The observed mixing ratios for acetone, methanol and in particular acetonitrile were generally reduced in the marine boundary layer, suggesting the presence of an ocean uptake sink. The ocean uptake of acetonitrile was found to be particularly efficient in a zone with upwelling water off of the U.S. west coast. Reduced mixing ratios of acetone and methanol were observed in a stratospheric intrusion. This observation gives some information about the lifetime of these VOCs in the stratosphere. Enhanced concentrations of aromatic hydrocarbons were observed in air masses that were impacted by urban sources in California. The ratio between the concentrations of benzene, toluene and higher aromatics indicated the degree of photochemical oxidation. PTR-MS only gives information about the mass of the ions produced by proton-transfer reactions between H3O+ and VOCs in the instrument. The identification of VOCs was confirmed by coupling a gas-chromatographic (GC) column to the instrument and post-flight GC-PTR-MS analyses of canister samples collected during the flights.

  2. Vehicle cabin cooling system for capturing and exhausting heated boundary layer air from inner surfaces of solar heated windows

    DOEpatents

    Farrington, Robert B.; Anderson, Ren

    2001-01-01

    The cabin cooling system includes a cooling duct positioned proximate and above upper edges of one or more windows of a vehicle to exhaust hot air as the air is heated by inner surfaces of the windows and forms thin boundary layers of heated air adjacent the heated windows. The cabin cooling system includes at least one fan to draw the hot air into the cooling duct at a flow rate that captures the hot air in the boundary layer without capturing a significant portion of the cooler cabin interior air and to discharge the hot air at a point outside the vehicle cabin, such as the vehicle trunk. In a preferred embodiment, the cooling duct has a cross-sectional area that gradually increases from a distal point to a proximal point to the fan inlet to develop a substantially uniform pressure drop along the length of the cooling duct. Correspondingly, this cross-sectional configuration develops a uniform suction pressure and uniform flow rate at the upper edge of the window to capture the hot air in the boundary layer adjacent each window.

  3. Development of an effusive inlet for mass spectrometric gas analysis of hypersonic boundary layer

    NASA Technical Reports Server (NTRS)

    Brown, Kenneth G.; Fishel, Charles E.; Brown, David R.; Lewis, Beverley W.; Wood, George M., Jr.

    1987-01-01

    The use of a microchannel plate (MCP) as a mass spectrometer inlet device to allow nonintrusive sampling of flight vehicle boundary layers is investigated. Two possible configurations for mounting the inlet are studied: (1) flow coaxial with the channels; and (2) flow perpendicular to the channel axis. The test gases are pure Kr; pure Ne; and a mixture of 10 pct Kr, 10 pct Ne, and 80 pct N2. The pressure ranges studied vary from 500 to 10 microns. A mass discrimination at the quadrupole mass spectrometer is observed, indicating an enrichment in the heavier gas. Possible explanations for this enrichment are discussed. It is shown that an MCP is capable of acting as a nonintrusive sampling device. Further work that will enable quantitative determination of the species at the surface is discussed.

  4. Characterization of a high pressure, chemical ionization time-of-flight mass spectrometer for the measurement of alkylamines in the marine boundary layer

    NASA Astrophysics Data System (ADS)

    Kim, M. J.; Bertram, T. H.

    2012-12-01

    Field observations, supported by laboratory studies have shown that alkylamines contribute significantly to submicron organic aerosol mass loadings in the marine boundary layer. Further, computational and laboratory work suggest alkylamines enhance particle nucleation rates particularly in pristine air masses. Gas-phase condensation has been suggested as a likely pathway with links to microbiological activity in the surface ocean, with its exact nature still unknown. To this end, we present observations of gaseous alkylamines from the Scripps Institution of Oceanography Pier during late summer of 2012. This location is influenced by marine air masses, local pollution and high biological activity in the surrounding surface waters which allows probing of the relative strength of each source in coastal regions. Herein, we discuss observations of alkylamines (e.g. methyl-, ethyl- and dimethyl-, trimethyl- and diethylamines) in addition to oxygenated organic species (e.g. acetone, DMSO) made with a high pressure chemical ionization time-of-flight mass spectrometer (CITOFMS) using protonated water cluster reagent ion chemistry. We demonstrate order of magnitude improvements in sensitivity (>2000 vs 64 ncps ppbv-1 for acetone) over traditional PTR-MS and efficient transmission of clustered reagent ions (H-(H2O)n+) and products ions. The short term precision and low detection thresholds achieved here will likely support simultaneous measurements of the air-sea flux of a host of alkylamines via eddy covariance. Keywords: alkylamines, chemical ionization, air-sea exchange, SOA

  5. Transport of Mass and Water Vapor in Cumulus Topped Boundary Layer: A Case-Study from Arm Darwin Facility

    NASA Astrophysics Data System (ADS)

    Ghate, V. P.; Jensen, M. P.

    2014-12-01

    Shallow cumulus clouds are intimately tied to the turbulence in the boundary layer and transport momentum and enthalpy upwards from the surface. These clouds have a significant impact on the Earth's radiation budget as they reflect more incoming solar radiation back to space compared to the underlying surface. They form when water vapor is transported upwards from the surface above the lifting condensation level at which point the water vapor condenses to form cloud droplets. These clouds typically have a life-time of less than an hour after which they evaporate, with the active cumuli venting the boundary layer moisture into the free troposphere. We use data collected during a 24-hour period at the Atmospheric Radiation Measurement (ARM) observing facility at Darwin, Australia to study the turbulent transport of mass and water vapor associated with shallow cumulus clouds. The instruments at the site include a vertically pointing Doppler cloud radar, Doppler Lidar, ceilometer among others. Three balloon borne radiosondes were also launched during the study period. Data from the cloud radar and Doppler Lidar were combined to retrieve the vertical velocity structure of the entire boundary layer at a high resolution (2 sec; 30 m). Additionally, high resolution (10 s; 37 m) retrievals of water vapor mixing ratio were also performed using the data collected by the collocated Raman Lidar. We will use the high resolution observations of vertical velocity and water vapor to characterize the second order turbulent transport terms of water vapor and vertical velocity. These turbulent transport terms will then be used together with a parcel model to calculate entrainment rates of individual cloud elements. The contrast in the entrainment rates of forced, active and passive cumuli will be presented together with the moisture and dynamic structure of surrounding environmental air.

  6. Mass transfer of VOCs in laboratory-scale air sparging tank.

    PubMed

    Chao, Keh-Ping; Ong, Say Kee; Huang, Mei-Chuan

    2008-04-15

    Volatilization of VOCs was investigated using a 55-gal laboratory-scale model in which air sparging experiments were conducted with a vertical air injection well. In addition, X-ray imaging of an air sparging sand box showed air flows were in the form of air bubbles or channels depending on the size of the porous media. Air-water mass transfer was quantified using the air-water mass transfer coefficient which was determined by fitting the experimental data to a two-zone model. The two-zone model is a one-dimensional lumped model that accounts for the effects of air flow type and diffusion of VOCs in the aqueous phase. The experimental air-water mass transfer coefficients, KGa, obtained from this study ranged from 10(-2) to 10(-3)1/min. From a correlation analysis, the air-water mass transfer coefficient was found to be directly proportional to the air flow rate and the mean particle size of soil but inversely proportional to Henry's constant. The correlation results implied that the air-water mass transfer coefficient was strongly affected by the size of porous media and the air flow rates. PMID:17804158

  7. Evolutionary and Ecological Sequelae of Mass Extinctions: Examples From the Continental Triassic-Jurassic Boundary

    NASA Astrophysics Data System (ADS)

    Olsen, P. E.; Whiteside, J. H.

    2003-12-01

    The Triassic-Jurassic boundary at ˜200 Ma marks one of the five major mass-extinctions of the Phanerozoic and, depending on the metrics used, was similar in magnitude to the K-T mass extinction. In continental environments about 50% of all tetrapod families are eliminated and although floral diversity change is difficult to gauge, a similar proportion of palynomorph taxa disappear at the boundary. The extinction event appears to have been very abrupt, followed by a roughly 900 ky super-greenhouse period characterized by increased precipitation. We hypothesize a series of biological consequences of the drop in diversity and associated super-greenhouse based on observations of the earliest Jurassic assemblages, largely from eastern North America. 1) The drop in diversity results in a collapse of ecological interactions that tend to stabilize the composition of regional biotas and buffer them from invading forms. Triassic assemblages show considerable biogeographic provinciality despite the existence of Pangea, but the earliest Jurassic assemblages were extraordinarily homogenous with many vertebrate genera being essentially global in distribution. 2) Initially the post-boundary terrestrial assemblages were comprised of eurytopic trophic generalists, with animal communities with few herbivores, but abundant carnivores and detritivores subsisting on aquatic-based food webs. The earliest Jurassic tetrapod footprint record is overwhelmingly dominated by the footprints of ceratosaurian theropod dinosaurs, the latter having skull characteristics usually associated at least in part with piscivory. 3) The dramatic size changes over very short periods of time were likely due to an absence of competition (i.e., ecological release). The maximum size of theropod dinosaur footprints increased by about 25% within 10 ky following the boundary, corresponding to a doubling of mass. 4) Representatives of clades with intrinsically high rates of speciation tend to form species flocks

  8. Geographic boundaries in breast, lung and colorectal cancers in relation to exposure to air toxics in Long Island, New York

    PubMed Central

    Jacquez, Geoffrey M; Greiling, Dunrie A

    2003-01-01

    Background This two-part study employs several statistical techniques to evaluate the geographic distribution of breast cancer in females and colorectal and lung cancers in males and females in Nassau, Queens, and Suffolk counties, New York, USA. In this second paper, we compare patterns in standardized morbidity ratios (SMR values), calculated from New York State Department of Health (NYSDOH) data, to geographic patterns in overall predicted risk (OPR) from air toxics using exposures estimated in the USEPA National Air Toxics Assessment database. Results We identified significant geographic boundaries in SMR and OPR. We found little or no association between the SMR of colorectal and breast cancers and the OPR for each cancer from exposure to the air toxics. We did find boundaries in male and female lung cancer SMR and boundaries in lung cancer OPR to be closer to one another than expected. Conclusion While consistent with a causal relationship between air toxics and lung cancer incidence, the boundary analysis does not demonstrate the existence of a causal relationship. However, now that the areas of overlap between boundaries in lung cancer incidence and potential airborne exposures have been identified, we can begin to evaluate local- as well as large-scale determinants of lung cancer. PMID:12633502

  9. Geographic boundaries in breast, lung and colorectal cancers in relation to exposure to air toxics in Long Island, New York.

    PubMed

    Jacquez, Geoffrey M; Greiling, Dunrie A

    2003-02-17

    BACKGROUND: This two-part study employs several statistical techniques to evaluate the geographic distribution of breast cancer in females and colorectal and lung cancers in males and females in Nassau, Queens, and Suffolk counties, New York, USA. In this second paper, we compare patterns in standardized morbidity ratios (SMR values), calculated from New York State Department of Health (NYSDOH) data, to geographic patterns in overall predicted risk (OPR) from air toxics using exposures estimated in the USEPA National Air Toxics Assessment database. RESULTS: We identified significant geographic boundaries in SMR and OPR. We found little or no association between the SMR of colorectal and breast cancers and the OPR for each cancer from exposure to the air toxics. We did find boundaries in male and female lung cancer SMR and boundaries in lung cancer OPR to be closer to one another than expected. CONCLUSION: While consistent with a causal relationship between air toxics and lung cancer incidence, the boundary analysis does not demonstrate the existence of a causal relationship. However, now that the areas of overlap between boundaries in lung cancer incidence and potential airborne exposures have been identified, we can begin to evaluate local- as well as large-scale determinants of lung cancer. PMID:12633502

  10. Turbulent Boundary Layer on a Finely Perforated Surface Under Conditions of Air Injection at the Expense of External Flow Resources

    NASA Astrophysics Data System (ADS)

    Kornilov, V. I.; Boiko, A. V.; Kavun, I. N.

    2015-11-01

    The characteristics of an incompressible turbulent boundary layer on a flat plate with air blown in though a finely perforated surface from an external confined flow through an input device, located on the "idle" side of the plate, have been investigated experimentally and numerically. A stable decrease in the local values of the coefficient of surface friction along the plate length that attains 85% at the end of the perforated portion is shown. The experimental and calculated data obtained point to the possibility of modeling, under earth conditions, the process of controlling a turbulent boundary layer with air injection by using the resources of an external confined flow.

  11. Three-dimensional flow of Powell–Eyring nanofluid with heat and mass flux boundary conditions

    NASA Astrophysics Data System (ADS)

    Tasawar, Hayat; Ikram, Ullah; Taseer, Muhammad; Ahmed, Alsaedi; Sabir, Ali Shehzad

    2016-07-01

    This article investigates the three-dimensional flow of Powell–Eyring nanofluid with thermophoresis and Brownian motion effects. The energy equation is considered in the presence of thermal radiation. The heat and mass flux conditions are taken into account. Mathematical formulation is carried out through the boundary layer approach. The governing partial differential equations are transformed into the nonlinear ordinary differential equations through suitable variables. The resulting nonlinear ordinary differential equations have been solved for the series solutions. Effects of emerging physical parameters on the temperature and nanoparticles concentration are plotted and discussed. Numerical values of local Nusselt and Sherwood numbers are computed and examined.

  12. Transport of polluted boundary layer air from the Po Valley to high-alpine sites

    NASA Astrophysics Data System (ADS)

    Seibert, Petra; Kromp-kolb, Helga; Kasper, Anne; Kalina, Michael; Puxbaum, Hans; Jost, Dieter T.; Schwikowski, Margit; Baltensperger, Urs

    Within the EUROTRAC subproject ALPTRAC the occurrence of reactive trace species at high-alpine sites was investigated. As a part of these studies, the transport of boundary layer air from the Po Valley, which is one potential major source region for air pollution in the Alps, to the high-mountain sites Sonnblick (3106 m) in Austria and Jungfraujoch (3579 m) in Switzerland was studied. A case study based on isentropic trajectories derived from a fine-mesh analysis showed the potential of such transports to cause substantial peaks in the aerosol concentration at Sonnblick. However, on a climatological basis the Po Valley does not seem to cause higher-than-average concentrations of species such as SO 2, SO 2-4, NH +4 and NO -3. Its contribution was estimated to be about 15% in summer and much less in winter. Indications of orographically induced, subgrid vertical transports were found which are important for the interpretation of data from pollution monitoring programmes at high-alpine sites.

  13. The Coupled Boundary Layers and Air-Sea Transfer (CBLAST) Experiments at the Martha's Vineyard Coastal Observatory

    NASA Astrophysics Data System (ADS)

    Edson, J. B.

    2001-12-01

    The Woods Hole Oceanographic Institution (WHOI) completed the initial phase of the Martha's Vineyard Coastal Observatory (MVCO) in July of 2001. The MVCO is being using to monitor coastal atmospheric and oceanic processes. Specifically, the observatory is expected to: - Provide continuous long-term observations for climate studies. - Provide a reliable system and rugged sensors that allow opportunistic sampling of extreme events. - Provide a local climatology for intensive, short duration field campaigns. - Further facilitate regional studies of coastal processes by providing infrastructure that supports easy access to power and data. This talk provides an example of the last two objectives using the low wind component of the Office of Naval Research's (ONR) Coupled Boundary Layers and Air-Sea Transfer (CBLAST) program. CBLAST-LOW has been designed to investigate air-sea interaction and coupled atmospheric and oceanic boundary layer dynamics at low wind speeds where the dynamic processes are driven and/or strongly modulated by thermal forcing. This effort is being carried out by scientists at WHOI, NPS, NOAA, NRL, Rutgers, UW/APL, JH/APL, OSU, NCAR, and other institutions, and includes observational and modeling components. The MVCO is providing observations and infrastructure in support of several intensive operating periods in the summers of 2001, 2002, and possibly 2003. During these periods, the observational network around the observatory was and will be greatly expanded using traditional oceanographic moorings and bottom mounted instrumentation, innovative 2- and 3-D moored and drifting arrays, survey ships, AUVs, satellite remote sensing, and heavily instrumented aircraft. In addition, the MVCO cabled components will be extended out to the 20-m isobath where we plan to deploy a 35-m tower. The tower will be instrumented from 15-m above the ocean surface to the ocean bottom with instruments capable of directly measuring the momentum, heat, and radiative

  14. Contributions of mass and bond energy difference and interface defects on thermal boundary conductance

    NASA Astrophysics Data System (ADS)

    Choi, ChangJin; Roberts, Nicholas

    2015-09-01

    The impact of mass and bond energy difference and interface defects on thermal boundary conductance (TBC) is investigated using non-equilibrium molecular dynamics (NEMD) with the Lennard-Jones (L-J) interatomic potential. Results show that the maximum TBC is achieved when the mass and bond energy of two dissimilar materials are matched, although the effective thermal conductivity is not necessarily a maximum due to the contributions of the thermal conductivity of the constituent materials. Mass and bond energy differences result in a mismatch between phonon dispersions, limiting high frequency phonon transport at the interface. This frequency mismatch is defined by a frequency ratio, which is a ratio of the characteristic frequencies of the two materials, presented in the discussion section, and is a reference of the level of phonon dispersion mismatch. Inelastic scattering may result at higher temperatures, especially when there exists a bond energy difference, resulting in strain in the lattice, which would allow phonons outside the allowable frequency range to contribute to transport. TBC decreases abruptly with small mass differences, but at which point larger differences in mass have no impact. In addition, interdiffusion across the interface further reduces the TBC between the frequency ratios of 0.79 and 1.26 while vacancies have negligible impact.

  15. Radiative and turbulent heating rates in the clear-air boundary layer

    NASA Astrophysics Data System (ADS)

    Savijärvi, Hannu

    2006-01-01

    The diurnal evolution of a clear-sky midlatitude summertime boundary layer (BL) was studied using a column model over smooth and homogeneous land, subject to weak, moderate, and strong winds. The high-resolution BL model (lowest point at 30 cm) was equipped with an adequate turbulence scheme and a narrow-band long-wave (LW) radiation scheme, the latter validated using data from the International Comparison of Radiation Codes in Climate Models (ICRCCM).In off-line ICRCCM experiments, ground emissivity ɛ < 1 led to extra LW cooling of air near the surface compared to ɛ = 1. However, much stronger LW cooling at heights of 1 3 m, and warming below 1 m, was obtained by setting the ground colder than air at screen height, a typical condition during clear nights. Conversely, a warm surface anomaly typical of sunny days leads to strong LW warming at 1 3 m, with LW cooling just above the ground. These ground temperature anomalies dominated the LW heating/cooling patterns at heights of up to 3 4 m, perhaps explaining controversies in the observed LW flux divergences close to the ground.Interactive model results indicate that the middle part of a windy clear-air nocturnal BL (NBL) is dominated by turbulent cooling, while the upper and lower NBL is dominated by LW cooling. Below about 1 m, a fourth layer is formed with LW warming and turbulent cooling, in agreement with the off-line experiments. When the surface winds fall below about 1 1.5 m s -1 LW cooling dominates in the whole NBL, except very near the surface. In these light wind conditions the Monin Obukhov theory should be revised to include radiative effects.In clear-air daytime conditions strong convective BL heating dominates over weak LW cooling except at 1 3 m heights where the cooler air absorbs the thermal emission of the hot ground. The subsequent LW warming of the superadiabatic surface layer appears to be strong enough to induce local turbulent cooling (despite the hot surface) in an 'hour glass' pattern

  16. Ocean Carbon Cycling and CO2 Air-Sea Exchange in Eastern Boundary Upwelling Systems

    NASA Astrophysics Data System (ADS)

    Plattner, G.; Gruber, N.; Lachkar, Z.; Frenzel, H.; Loher, D.

    2008-12-01

    Eastern boundary current (EBC) upwelling systems are regions of intense biogeochemical transformations and transports. Strong upwelling of nutrient- and carbon-rich waters tends to lead to CO2 outgassing nearshore and biologically-driven CO2 uptake offshore. Yet, the net air-sea CO2 balance of EBCs remains unknown. High near-shore productivity coupled with filaments and other meso- and submesoscale phenomena cause a substantial lateral export of organic carbon. We investigate these coastal processes in the California Current (CalCS) and the Canary Current Systems (CanCS), on the basis of the eddy-resolving, physical-biogeochemical model ROMS. Our results confirm the onshore-offshore trends in the air-sea fluxes, with substantial spatial and temporal differences due to topography, upwelling strength, and eddy activity. The CalCS is modeled to be, on average, a very small source of CO2 to the atmosphere, consistent with a recent data-based estimate by Chavez and Takahashi, while for the CanCS this is not clear yet. Regarding offshore transport, the CalCS appears to be stronger than the CanCS. Spatio-temporal variability of all carbon fluxes is substantial, particularly nearshore, posing a tremendous challenge for observing systems targeting e.g. air-sea CO2 fluxes in these dynamic regions. Further analyses of the processes that determine the mean carbon fluxes and their spatio-temporal variability will be presented. Characteristic differences and similarities between the two EBC systems will be discussed.

  17. Global iridium anomaly, mass extinction, and redox change at the Devonian-Carboniferous boundary

    SciTech Connect

    Wang, K. Univ. of Calgary, Alberta ); Attrep, M. Jr.; Orth, C.J. )

    1993-12-01

    Iridium abundance anomalies have been found on a global scale in the Devonian-Carboniferous (D-C) boundary interval, which records one of the largest Phanerozoic mass-extinction events, an event that devastated many groups of living organisms, such as plants, ammonoids, trilobites, conodonts, fish, foraminiferans, brachiopods, and ostracodes. At or very close to the D-C boundary, there exists a geographically widespread black-shale interval, and Ir abundances reach anomalous maxima of 0.148 ppb (Montagne Noire, France), 0.138 ppb (Alberta, Canada) 0.140 ppb (Carnic Alps, Austria), 0.156 ppb (Guangxi, China), 0.258 ppb (Guizhou, China), and 0.250 ppb (Oklahoma). The discovery of global D-C Ir anomalies argues for an impact-extinction model. However, nonchondritic ratios of Ir to other important elements and a lack of physical evidence (shocked quartz, microtektites) do not support such a scenario. The fact that all Ir abundance maxima are at sharp redox boundaries in these sections leads us to conclude that the Ir anomalies likely resulted from a sudden change in paleo-redox conditions during deposition and/or early diagenesis. 36 refs., 2 figs., 1 tab.

  18. Constraining mass accumulation rates across the Cretaceous-Paleogene boundary clay layer using extraterrestrial helium-3

    NASA Astrophysics Data System (ADS)

    Giron, M.; Sepulveda, J.; Mukhopadhyay, S.; Alegret, L.; Summons, R. E.

    2012-12-01

    The extended duration of the negative δ13C excursion observed in marine carbonates spanning the Cretaceous-Paleogene (K-Pg) mass extinction event has lead to two main hypothesized post-extinction models ("Strangelove" and "Living Ocean";[1, 2]) for the status of marine primary productivity and the global carbon cycle. However, these models are largely inconsistent with recent paleontological and geochemical evidence suggesting heterogeneous changes in marine productivity and carbon export [3, 4]. While the analysis of lipid biomarkers in the cosmopolitan boundary clay layer allows us to assess changes in primary production by non-calcifying organisms in the immediate aftermath of the mass extinction [4], our poor understanding of the deposition of the clay layer precludes a more detailed reconstruction of short-term variations in marine ecosystem resilience. Here, we present data on extraterrestrial 3He derived from interplanetary dust particles used as a constant flux proxy to constrain fluctuations in mass accumulation rates (MARs) [5] and the duration of the boundary clay deposition in three classic and expanded K-Pg boundary sections: El Kef (Tunisia), Caravaca (Spain), and Kulstirenden (Denmark). Our results from different depositional environments indicate average durations for the sedimentation of the clay layer that are comparable (~10 kyr) to other localities [5], thus confirming its globally brief deposition. Early Paleogene MARs vary among locations when compared to background Late Cretaceous values and do not strictly follow carbonate content as traditionally assumed, thus suggesting variable depositional conditions at different locations. Changes in sediment MARs across the K-Pg will be used to calculate MARs of algal- and bacterial-derived biomarkers, as well as benthic foraminifera, in order to assess the timing and global nature of the recovery of marine primary production and carbon export. 1. Hsu, K.J., He, Q., Mckenzie, J.A., Weissert, H

  19. A Numerical Model of Anisotropic Mass Transport Through Grain Boundary Networks

    NASA Astrophysics Data System (ADS)

    Wang, Yibo

    Tin (Sn) thin films are commonly used in electronic circuit applications as coatings on contacts and solders for joining components. It is widely observed, for some such system, that whiskers---long, thin crystalline structures---emerge and grow from the film. The Sn whisker phenomenon has become a highly active research area since Sn whiskers have caused a large amount of damage and loss in manufacturing, military, medical and power industries. Though lead (Pb) addition to Sn has been used to solve this problem for over five decades, the adverse environmental and health effects of Pb have motivated legislation to severely constrain Pb use in society. People are researching and seeking the reasons which cause whiskers and corresponding methods to solve the problem. The contributing factors to cause a Sn whisker are potentially many and much still remains unknown. Better understanding of fundamental driving forces should point toward strategies to improve (a) the accuracy with which we can predict whisker formation, and (b) our ability to mitigate the phenomenon. This thesis summarizes recent important research achievements in understanding Sn whisker formation and growth, both experimentally and theoretically. Focus is then placed on examining the role that anisotropy in grain boundary diffusivity plays in determining whisker characteristics (specifically, whether they form and, if so, where on a surface). To study this aspect of the problem and to enable future studies on stress driven grain boundary diffusion, this thesis presents a numerical anisotropic mass transport model. In addition to presenting details of the model and implementation, model predictions for a set of increasingly complex grain boundary networks are discussed. Preliminary results from the model provide evidence that anisotropic grain boundary diffusion may be a primary driving mechanism in whisker formation.

  20. Properties of air mass mixing and humidity in the subtropics from measurements of the D/H isotope ratio of water vapor at the Mauna Loa Observatory

    NASA Astrophysics Data System (ADS)

    Noone, David; Galewsky, Joseph; Sharp, Zachary D.; Worden, John; Barnes, John; Baer, Doug; Bailey, Adriana; Brown, Derek P.; Christensen, Lance; Crosson, Eric; Dong, Feng; Hurley, John V.; Johnson, Leah R.; Strong, Mel; Toohey, Darin; van Pelt, Aaron; Wright, Jonathon S.

    2011-11-01

    Water vapor in the subtropical troposphere plays an important role in the radiative balance, the distribution of precipitation, and the chemistry of the Earth's atmosphere. Measurements of the water vapor mixing ratio paired with stable isotope ratios provide unique information on transport processes and moisture sources that is not available with mixing ratio data alone. Measurements of the D/H isotope ratio of water vapor from Mauna Loa Observatory over 4 weeks in October-November 2008 were used to identify components of the regional hydrological cycle. A mixing model exploits the isotope information to identify water fluxes from time series data. Mixing is associated with exchange between marine boundary layer air and tropospheric air on diurnal time scales and between different tropospheric air masses with characteristics that evolve on the synoptic time scale. Diurnal variations are associated with upslope flow and the transition from nighttime air above the marine trade inversion to marine boundary layer air during daytime. During easterly trade wind conditions, growth and decay of the boundary layer are largely conservative in a regional context but contribute ˜12% of the nighttime water vapor at Mauna Loa. Tropospheric moisture is associated with convective outflow and exchange with drier air originating from higher latitude or higher altitude. During the passage of a moist filament, boundary layer exchange is enhanced. Isotopic data reflect the combination of processes that control the water balance, which highlights the utility for baseline measurements of water vapor isotopologues in monitoring the response of the hydrological cycle to climate change.

  1. Boundary-Layer Development and Low-level Baroclinicity during High-Latitude Cold-Air Outbreaks: A Simple Model

    NASA Astrophysics Data System (ADS)

    Chechin, Dmitry G.; Lüpkes, Christof

    2016-08-01

    A new quasi-analytical mixed-layer model is formulated describing the evolution of the convective atmospheric boundary layer (ABL) during cold-air outbreaks (CAO) over polar oceans downstream of the marginal sea-ice zones. The new model is superior to previous ones since it predicts not only temperature and mixed-layer height but also the height-averaged horizontal wind components. Results of the mixed-layer model are compared with dropsonde and aircraft observations carried out during several CAOs over the Fram Strait and also with results of a 3D non-hydrostatic (NH3D) model. It is shown that the mixed-layer model reproduces well the observed ABL height, temperature, low-level baroclinicity and its influence on the ABL wind speed. The mixed-layer model underestimates the observed ABL temperature only by about 10 %, most likely due to the neglect of condensation and subsidence. The comparison of the mixed-layer and NH3D model results shows good agreement with respect to wind speed including the formation of wind-speed maxima close to the ice edge. It is concluded that baroclinicity within the ABL governs the structure of the wind field while the baroclinicity above the ABL is important in reproducing the wind speed. It is shown that the baroclinicity in the ABL is strongest close to the ice edge and slowly decays further downwind. Analytical solutions demonstrate that the e -folding distance of this decay is the same as for the decay of the difference between the surface temperature of open water and of the mixed-layer temperature. This distance characterizing cold-air mass transformation ranges from 450 to 850 km for high-latitude CAOs.

  2. Relating Aerosol Mass and Optical Depth in the Summertime Continental Boundary Layer

    NASA Astrophysics Data System (ADS)

    Brock, C. A.; Wagner, N.; Middlebrook, A. M.; Attwood, A. R.; Washenfelder, R. A.; Brown, S. S.; McComiskey, A. C.; Gordon, T. D.; Welti, A.; Carlton, A. G.; Murphy, D. M.

    2014-12-01

    Aerosol optical depth (AOD), the column-integrated ambient aerosol light extinction, is determined from satellite and ground-based remote sensing measurements. AOD is the parameter most often used to validate earth system model simulations of aerosol mass. Relating aerosol mass to AOD, however, is problematic due to issues including aerosol water uptake as a function of relative humidity (RH) and the complicated relationship between aerosol physicochemical properties and light extinction. Measurements of aerosol microphysical, chemical, and optical properties help to constrain the relationship between aerosol mass and optical depth because aerosol extinction at ambient RH is a function of the abundance, composition and size distribution of the aerosol. We use vertical profiles of humidity and dry aerosol extinction observed in the southeastern United States (U.S.) to examine the relationship between submicron aerosol mass concentration and extinction at ambient RH. We show that the κ-Köhler parameterization directly, and without additional Mie calculations, describes the change in extinction with varying RH as a function of composition for both aged aerosols typical of the polluted summertime continental boundary layer and the biomass burning aerosols we encountered. We calculate how AOD and the direct radiative effect in the eastern U.S. have likely changed due to trends in aerosol composition in recent decades. We also examine the sensitivity of AOD to the RH profile and to aerosol composition, size distribution and abundance.

  3. Mathematical modeling of heat exchange between mine air and rock mass during fire

    SciTech Connect

    A.E. Krasnoshtein; B.P. Kazakov; A.V. Shalimov

    2006-05-15

    Solution of problems on heat exchange between ventilating air and rock mass and on gas admixture propagation in mine workings serve as a base for considering changes in heat-gas-air state at a mine after inflammation. The presented mathematical relations allow calculation of a varied velocity and movement direction of air flows, their temperatures and smoking conditions during fire.

  4. Vertical air mass exchange driven by the local circulation on the northern slope of Mount Everest

    NASA Astrophysics Data System (ADS)

    Zhou, Libo; Zou, Han; Ma, Shupo; Li, Peng; Zhu, Jinhuan; Huo, Cuiping

    2011-01-01

    To better understand vertical air mass exchange driven by local circulation in the Himalayas, the volume flux of air mass is estimated in the Rongbuk Valley on the northern slope of Mount Everest, based on a volume closure method and wind-profiler measurements during the HEST2006 campaign in June 2006. Vertical air mass exchange was found to be dominated by a strong downward mass transfer from the late morning to late night. The average vertical air volume flux was 0.09 m s-1, which could be equivalent to a daily ventilation of 30 times the enclosed valley volume. This vertical air mass exchange process was greatly affected by the evolution of the South Asian summer monsoon (SASM), with a strong downward transfer during the SASM break stage, and a weak transfer during the SASM active stage.

  5. Boundary layer stability acts to ballast the mass of the Greenland Ice Sheet

    NASA Astrophysics Data System (ADS)

    Berkelhammer, M. B.; Noone, D. C.; Steen-Larsen, H. C.; O'Neill, M.; Raudzens Bailey, A.; Cox, C.; Schneider, D. P.

    2014-12-01

    The mass of the Greenland Ice Sheet has been reduced over recent decades as a consequence of warming, the impact of which is already detectable on global sea level. However, temperature projections suggest that at interior high-altitude sites on the ice it could be decades or more before warming forces these regions to transition from a dry to wet snow facies. Shifts in boundary layer dynamics, including atmosphere-ice sheet hydrological exchange and cloud radiative forcing could expedite or delay this transition. These processes are important with respect to future ice sheet stability, yet they remain difficult to constrain. Using continuous in situ measurements of vertical profiles of the isotopic composition of water vapor at Summit Camp, the highest observatory on the ice sheet, we document the presence of a hydrologic balance between surface sublimation and condensation fluxes. This exists because of a nearly persistent temperature inversion, which hinders the efficiency with which surface water vapor mixes into the free atmosphere. In the presence of a strong temperature inversion, fog and ice particles form near the ice-atmosphere interface from surface moisture fluxes. When this condensate precipitates on or settles to the surface, it ballasts the ice sheet's mass. A decade-long trend towards lower annual accumulation at Summit may therefore reflect continuous replacement of the near surface atmosphere due to reduced atmospheric stability. If this tendency toward destabilization continues, it could accelerate mass loss at interior sites on the ice sheet. The role of boundary layer stability in ice sheet hydrological budgets discussed here is applicable beyond the accumulation zone of the Greenland Ice Sheet.

  6. Air-sea boundary layer dynamics in the presence of mesoscale surface currents

    NASA Astrophysics Data System (ADS)

    Rooth, Claes; Xie, Lian

    1992-09-01

    In the presence of surface currents, a shear stress at the air-sea interface is induced by the surface currents. In the case of a unidirectional current, a quadratic stress law leads to a stress curl proportional to and opposing the surface current vorticity even with a uniform wind. This causes a spindown effect on the surface vorticity field at a rate proportional to the wind speed. In the steady state, or in slowly varying processes which can be treated as parametrically developing quasi-steady states, the surface-layer potential vorticity modulation causes upwelling and downwelling patterns associated with the surface-current vorticity. These effects are analyzed for an idealized jet current, and for a physical situation characteristic of a Gulf Stream boundary ring along the Florida Keys, where the induced transport patterns may be important for onshore transport of fish and spiny lobster larvae, as well as for onshore transport to the Florida Keys of general flotsam transported past them by the Gulf Stream. The spindown time scale (t*) for a 1.5-layer system is H/( ρ'cdVa) for a surface jet on the deformation radius scale (where H is the thickness of the surface layer, Va the surface wind speed, ρ' the air to water density ratio and cd the surface drag coefficient) and increases for large horizontal scales in proportion to the current width squared. For a typical wind speed of 5 m/s and a density normalized drag coefficient ρ'cd= 2 × 10-6, t* is on the order of 1 month for a 30-m surface layer. In the more general case of a stratified interior water column, the vorticity spindown directly affects only the potential vorticity of the surface layer and generally leads to subsurface velocity and vorticity maxima for mesoscale eddies and jets.

  7. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  8. Mass extinction of ocean organisms at the Paleozoic-Mesozoic boundary: Effects and causes

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2012-04-01

    At the end of the Permian, at the boundary between the Paleozoic and Mesozoic (251.0 ± 0.4 Ma), the largest mass extinction of organisms on the Earth occurred. Up to 96% of the species of marine invertebrates and ˜70% of the terrestrial vertebrates died off. A lot of factors were suggested and substantiated to explain this mass mortality, such as the disappearance of environmental niches in the course of the amalgamation of the continental plates into Pangea, sea level fluctuations, anoxia, an elevated CO2 content, H2S intoxication, volcanism, methane discharge from gas-hydrates, climate changes, impact events (collisions with large asteroids), or combinations of many of these reasons. Some of these factors are in subordination to others, while others are independent. Almost all of these factors developed relatively slowly and could not cause the sudden mass mortality of organisms globally. It could have happened when large asteroids, whose craters have been discovered lately, fell to the Earth. It is suggested that the impact events "finished off" the already suppressed biota. A simultaneous change in many of the factors responsible for the biodiversity, including those not connected in a cause-and-effect relationship, proves the existence of a common extrater-restrial cause that affected both the changes in the internal and external geospheres and the activation of asteroid attacks (the Sun's transit of spiral arms of our galaxy, the Sun's oscillations perpendicularly to the galactic plane, etc).

  9. Modeling Arteriolar Flow and Mass Transport Using the Immersed Boundary Method

    NASA Astrophysics Data System (ADS)

    Arthurs, Kayne M.; Moore, Leon C.; Peskin, Charles S.; Pitman, E. Bruce; Layton, H. E.

    1998-12-01

    Flow in arterioles is determined by a number of interacting factors, including perfusion pressure, neural stimulation, vasoactive substances, the intrinsic contractility of arteriolar walls, and wall shear stress. We have developed a two-dimensional model of arteriolar fluid flow and mass transport. The model includes a phenomenological representation of the myogenic response of the arteriolar wall, in which an increase in perfusion pressure stimulates vasoconstriction. The model also includes the release, advection, diffusion, degradation, and dilatory action of nitric oxide (NO), a potent, but short-lived, vasodilatory agent. Parameters for the model were taken primarily from the experimental literature of the rat renal afferent arteriole. Solutions to the incompressible Navier-Stokes equations were approximated by means of a splitting that used upwind differencing for the inertial term and a spectral method for the viscous term and incompressibility condition. The immersed boundary method was used to include the forces arising from the arteriolar walls. The advection of NO was computed by means of a high-order flux-corrected transport scheme; the diffusion of NO was computed by a spectral solver. Simulations demonstrated the efficacy of the numerical methods employed, and grid refinement studies confirmed anticipated first-order temporal convergence and demonstrated second-order spatial convergence in key quantities. By providing information about the effective width of the immersed boundary and sheer stress magnitude near that boundary, the grid refinement studies indicate the degree of spatial refinement required for quantitatively reliable simulations. Owing to the dominating effect of NO advection, relative to degradation and diffusion, simulations indicate that NO has the capacity to produce dilation along the entire length of the arteriole.

  10. Abiotic causes of the great mass extinction of marine biota at the Triassic-Jurassic boundary

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2015-05-01

    In the interval of the Triassic-Jurassic boundary up to 80% of marine species became extinct. The main hypotheses on the causes of this mass extinction are reviewed. The extinction was triggered by a powerful eruption of basalts in the Central Atlantic Magmatic Province. In addition, several impact craters have been found. Extraterrestrial factors resulted in two main sequences of events: terrestrial, leading to strong volcanism, and extraterrestrial (impact events). They produced similar effects: emissions of harmful chemical compounds and aerosols. Consequences included the greenhouse effect, darkening of the atmosphere (which prevented photosynthesis), stagnation of the oceans, and anoxia. Biological productivity decreased; food chains collapsed. As a result, all vital processes were disturbed, and a large portion of the biota went extinct.

  11. New Evidence links Deccan Traps to the Cretaceous-Tertiary Boundary Mass Extinction

    NASA Astrophysics Data System (ADS)

    Adatte, T.; Keller, G.

    2012-04-01

    Recent studies indicate that Deccan Trap volcanism began with a relatively minor eruption phase (~6% of total volume) during the late Maastrichtian magnetic polarity C30n. The main eruption phase (~80%) occurred over a short period in C29r just below the Cretaceous-Tertiary boundary (KTB) and the last Deccan phase (~14%) erupted in the early Danian C29n. Multiproxy studies from sections in Meghalaya (NE India), Jhilmili in central India (Madhya Pradesh), 6 quarry outcrops from Rajahmundry (SE India), 10 deep wells from the Krishna-Godavari Basin (K-G) (Andhra Pradesh) place the KTB mass extinction near the end of the main Deccan phase coincident with the mass extinction. These studies show that the second and third phase of eruptions each produced the world's largest and longest lava megaflows ~1500 km across India through the K-G Basin into the Bay of Bengal. These megaflows are separated by sand, silt and shale which record the mass extinction across an interval that spans zones CF1-CF2 and most of the nannofossil Micula prinsii zone and is correlative with the rapid global warming and subsequent cooling near the end of the Maastrichtian. The mass extinction began preceding the first of the four mega-flows in C29r. Planktic foraminifera suffered a 50% drop in species richness. Survivors suffered another 50% drop after the first mega-flow, leaving just 7 to 8 survivor species. No recovery occurred between the next three mega-flows and the mass extinction was complete with the last phase-2 megaflow at the KTB. The last phase of Deccan volcanism and its 3 to 4 megaflows in the early Danian C29n (zone P1b) delayed biotic recovery of marine plankton. Correlative with these intense volcanic phases, climate changed from humid/tropical to arid conditions and returned to normal tropical humidity after the last phase of volcanism. Similar environmental conditions, mass extinction and delayed recovery patterns are observed in Meghalaya, NE India.The mass extinction was

  12. The Relation Between Wind Speed and Air-Sea Temperature Difference in the Marine Atmospheric Boundary Layer off Northwest Europe

    NASA Astrophysics Data System (ADS)

    Kettle, A. J.

    2014-12-01

    Wind speed and atmospheric stability have an important role in determining the turbulence in the marine atmospheric boundary layer (MABL) as well as the surface wave field. The understanding of MABL dynamics in northwest Europe is complicated by fetch effects, the proximity of coastlines, shallow topography, and larger scale circulation patterns (e.g., cold air outbreaks). Numerical models have difficulty simulating the marine atmospheric boundary layer in coastal areas and partially enclosed seas, and this is partly due to spatial resolution problems at coastlines. In these offshore environments, the boundary layer processes are often best understood directly from time series measurements from fixed platforms or buoys, in spite of potential difficulties from platform flow distortion as well as the spatial sparseness of the data sets. This contribution presents the results of time series measurements from offshore platforms in the North Sea and Norwegian Sea in terms of a summary diagnostic - wind speed versus air-sea temperature difference (U-ΔT) - with important implications for understanding atmospheric boundary layer processes. The U-ΔT diagram was introduced in earlier surveys of data from coastal (Sletringen; O.J. Andersen and J. Løvseth, J. Wind Eng. Ind. Aerodyn., 57, 97-109, 1995) and offshore (Statfjord A; K.J. Eidsvik, Boundary-Layer Meteorol., 32, 103-132, 1985) sites in northwest Europe to summarize boundary layer conditions at a given location. Additional information from a series of measurement purpose-built offshore measurement and oil/gas production platforms from the southern North Sea to the Norwegian Sea illustrates how the wind characteristics vary spatially over large distances, highlighting the influence of cold air outbreaks, in particular. The results are important for the offshore wind industry because of the way that wind turbines accrue fatigue damage in different conditions of atmospheric stability and wind speed.

  13. Ozone in the Boundary Layer air over the Arctic Ocean: Measurements During the TARA Expedition.

    NASA Astrophysics Data System (ADS)

    Bottenheim, J. W.; Netcheva, S.; Morin, S.; Gascard, J.; Weber, M.; de Marliave, C.; Trouble, R.

    2007-12-01

    It is now well established that after sunrise in polar regions, the atmospheric boundary layer experiences episodes where dramatic loss of ozone can be observed. Virtually all measurements in this respect have been made at coastal observatories on land, but there is strong evidence to surmise that such episodes originate over the frozen ocean. Satellite measurements (GOME, SCIAMACHY, OMI) invariably indicate large areas over the ocean with increased concentrations of BrO which can be interpreted as a smoking gun for ozone depletion processes, but no systematic in-situ measurements of ozone do exist to corroborate the satellite data. The TARA expedition (www.taraexpeditions.org) (IPY project # 238) has enabled us for the first time to make long term ozone measurements in the surface air over the Arctic Ocean, and we report here the first results. As expected ozone was found to be stable at approx. 35 ± 5 nmol~mol-1 during the winter, but shortly after local sunrise in mid March, large depletions of ozone were observed which lasted until well into June. A particularly long episode (> 15 days) of virtually no ozone (mole fraction below or near 1 nmol~mol-1) was experienced during late April. 10-day back trajectories were calculated in an attempt to obtain more insight into the potential origin of the depletion episodes. To place the TARA ozone data into context we will compare the data with land based and satellite observations in 2007 when they become available, as well as the limited record of previous observations made from ice islands. Taking all evidence together it is plausible to speculate that large areas over the Arctic Ocean are devoid of ozone in the atmospheric boundary layer in the first months after polar sunrise, and that if anything, this will increase in the coming years. We speculate what the implications might be. This work is a contribution to IPY project #038 (OASIS, Ocean Atmosphere Sea-Ice and Snow interactions in polar regions), sponsored by

  14. Dependence of air masses type on PBL vertical structure retrieved at the Mace Head station during EUCAARI campaign.

    NASA Astrophysics Data System (ADS)

    Milroy, Conor; Martucci, Giovanni; O'Dowd, Colin

    2010-05-01

    During the EUCAARI Intensive Observing Period held at the Mace Head GAW station from mid-May to mid-June, 2008, the PBL depth has been continuously measured by two ceilometers (Vaisala CL31 and Jenoptik CHM15K) and a microwave radiometer (RPG-HATPRO). The Lidar-Ceilometer, through the gradients in aerosol backscatter profiles, and the microwave profiler, through gradients in the specific humidity profiles, were used to remotely-sense the boundary layer structure. An automatic, newly developed Temporal Height-Tracking (THT) algorithm (Martucci et al., 2010) have been applied to both type of instruments data to retrieve the 2-layered structure of the local marine boundary layer. The two layers are defined as a lower, well mixed layer, i.e. the surface mixed layer, and the layer occupying the region below the free Troposphere inversion, i.e. the decoupled residual or convective layer. A categorization of the incoming air masses has been performed based on their origins and been used to asses the correlation with the PBL depths. The study confirmed the dependence of PBL vertical structure on different air masses and different type of advected aerosol.

  15. Chicxulub Impact Predates K-T Boundary in Texas and Caused no Mass Extinction

    NASA Astrophysics Data System (ADS)

    Fucugauchi, J. U.; Soler-Arechalde, A. M.; Rebolledo-Vieyra, M.; Keller, G.; Adatte, T.; Berner, Z.; Baum, G.; Stueben, D.

    2005-05-01

    In the Chicxulub crater and throughout NE Mexico the impact breccia and spherule ejecta layer, respectively, predate the K-T boundary by about 300,000 years (Keller et al., 2003, 2004). The stratigraphic separation between the K-T boundary and the Chicxulub impact ejecta varies from 50 cm in the Chicxulub crater, to over 14 m in NE Mexico, with the variation due to erosion, non-deposition and paloetopography. New studies from drilling and exposures along the Brazos River, Texas, confirm these findings based on biostratigraphy, paleomagnetic stratigraphy, geochemistry, stable isotopes, and faunal assemblages. In this area, the spherule ejecta is reworked near the base of a series of `event beds' representing variable storm deposits separated by repeated colonization of the ocean floor by invertebrates. The base of these storm beds overlies an undulating erosion surface of latest Maastrichtian claystone. The original spherule ejecta layer appears to be within the underlying claystone, in the lower part of chron 29R and near the base of biozone CF1, which marks the last 300,000 years of the Cretaceous. Above the `event beds' latest Maastrichtian claystone sedimentation continues up to the K-T boundary, which is characterized by a sharp (1.4 ng/g) iridium anomaly that marks the K-T as a second major impact. The distance between the top of the `event beds' and the K-T boundary varies from 20 cm to 1.6 m depending on local tectonics and erosion. Evaluation of the biotic effects of the Chicxulub and K-T impacts upon planktic foraminifera, which suffered most severely of all marine organisms, reveals no species extinctions associated with the Chicxulub impact and no significant species population changes, except for species dwarfing as a result of increased biotic stress. These Brazos results confirm the 65.3 Ma age for the Chicxulub impact determined from NE Mexico and the crater core Yaxcopoil-1. They also show that the Chicxulub impact did not cause a mass extinction

  16. Flow Structure and Mass Transfer Investigation of the Turbulized Boundary Layer with Ethanol Evaporation and Diffusion Combustion

    NASA Astrophysics Data System (ADS)

    Volchkov, E. P.; Boyarshinov, B. F.; Titkov, V. I.

    2002-07-01

    Uncertainty of evaluation of each factor (separation laminar-turbulent transition combustion and turbulization) hinders mathematical simulation of the joint effect on gas dynamic and thermal characteristics of the boundary layer. The characteristics may be most reliably determined experimentally. The work objective is the experimental study of the boundary layer structure comparison of the fields of temperature velocity and its pulsation with data on heat and mass transfer.

  17. Secondary Aerosol Formation in the planetary boundary layer observed by aerosol mass spectrometry on a Zeppelin NT

    NASA Astrophysics Data System (ADS)

    Rubach, Florian; Trimborn, Achim; Mentel, Thomas; Wahner, Andreas; Zeppelin Pegasos-Team 2012

    2014-05-01

    The airship Zeppelin NT is an airborne platform capable of flying at low speed throughout the entire planetary boundary layer (PBL). In combination with the high scientific payload of more than 1 ton, the Zeppelin is an ideal platform to study regional processes in the lowest layers of the atmosphere with high spatial resolution. Atmospheric aerosol as a medium long lived tracer substance is of particular interest due to its influence on the global radiation budget. Due its lifetime of up to several days secondaray aerosol at a certain location can result from local production or from transport processes. For aerosol measurements on a Zeppelin, a High-Resolution Time-of-Flight Aerosol Mass spectrometer (DeCarlo et al, 2006) was adapted to the requirements posed by an airborne platform. A weight reduction of over 20 % compared to the commercial instrument was achieved, while space occupation and footprint were each reduced by over 25 %. Within the PEGASOS project, the instrument was part of 10 measurement flight days over the course of seven weeks. Three flights were starting from Rotterdam, NL, seven flights were starting from Ozzano in the Po Valley, IT. Flight patterns included vertical profiles to study the dynamics of the PBL and cross sections through regions of interest to shed light on local production and transport processes. Analysis of data from transects between the Apennin and San Pietro Capofiume in terms of "residence time of air masses in the Po valley" indicates that aerosol nitrate has only local sources while aerosol sulfate is dominated by transport. The organic aerosol component has significant contributions of both processes. The local prodcution yields are commensurable with imultaneously observed precursor concentrations and oxidant levels. The PEGASOS project is funded by the European Commission under the Framework Programme 7 (FP7-ENV-2010-265148). DeCarlo, P.F. et al (2006), Anal. Chem., 78, 8281-8289.

  18. Late Quaternary behavior of the East African monsoon and the importance of the Congo Air Boundary

    NASA Astrophysics Data System (ADS)

    Tierney, Jessica E.; Russell, James M.; Sinninghe Damsté, Jaap S.; Huang, Yongsong; Verschuren, Dirk

    2011-04-01

    Both Atlantic and Indian Ocean climate dynamics exert influence over tropical African hydroclimate, producing complex patterns of convergence and precipitation. To isolate the Indian Ocean influence on African paleohydrology, we analyzed the deuterium/hydrogen ratio of higher plant leaf waxes ( δD wax) in a 25 000-year sediment record from Lake Challa (3° S, 38° E) in the easternmost area of the African tropics. Whereas both the seismic record of inferred lake level fluctuations and the Branched and Isoprenoidal Tetraether (BIT) index proxy record changes in hydrology within the Challa basin, δD wax, as a proxy for the isotopic composition of precipitation ( δD P) is interpreted as a tracer of large-scale atmospheric circulation that integrates the history of the moisture transported to the Lake Challa area. Specifically, based on modern-day isotope-rainfall relationships, we argue that Lake Challa δD wax reflects the intensity of East African monsoon circulation. The three hydrological proxy records show generally similar trends for the last 25 000 years, but there are important differences between them, primarily during the middle Holocene. We interpret this deviation of δD wax from local hydrological history as a decoupling of East African monsoon intensity - which heavily influences the isotopes of precipitation in East Africa today - from rainfall amount in the Challa basin. In combination, the hydrological proxy data from Lake Challa singularly highlight zonal gradients in tropical African climate that occur over a variety of timescales, suggesting that the Congo Air Boundary plays a fundamental role in controlling hydroclimate in the African tropics.

  19. Elemental composition of different air masses over Jeju Island, South Korea

    NASA Astrophysics Data System (ADS)

    Kang, Jeongwon; Choi, Man-Sik; Yi, Hi-Il; Jeong, Kap-Sik; Chae, Jung-Sun; Cheong, Chang-Sik

    2013-03-01

    We investigated the characteristics (concentrations and compositional changes) of atmospheric elements in total suspended particulates through source-receptor relationships using cluster analyses to classify air mass back-trajectories arriving at Gosan, Jeju Island, South Korea, from October 2003 to December 2008. Five trajectory clusters were chosen to explain the transport regimes. Continental outflows of natural and anthropogenic aerosols from Asian dust source regions and eastern China during the colder period could increase element concentrations at Gosan. Elemental levels at Gosan decreased in air masses that passed over marine regions (East China Sea, Pacific Ocean/southern side of Kyushu Island in Japan, and East Sea/southern side of South Korea) during the warmer rainy period due to lower source intensity and dilution by the marine air mass. Anthropogenic pollutants were often major components in air masses passing over marine regions. Air mass characterization by elemental concentration and composition revealed that enrichment by non-sea-salt sulfur in the air mass originated from eastern China, indicative of the main sulfur emitter in northeast Asia. The apportionment of V and Ni by principal component analysis as a marker of heavy oil combustion suggested different residence times and deposition rates from other anthropogenic components in the air. Regionally intermediate concentrations of pollutants were found in the atmosphere over the Korean peninsula.

  20. A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer

    SciTech Connect

    Mak, J. E.; Su, L.; Guenther, Alex B.; Karl, Thomas G.

    2013-10-16

    The emission and fate of reactive VOCs is of inherent interest to those studying chemical biosphere-atmosphere interactions. In-canopy VOC observations are obtainable using tower-based samplers, but the lack of suitable sampling systems for the full boundary 5 layer has limited the data characterizing the vertical structure of such gases above the canopy height and still in the boundary layer. This is the important region where many reactive VOCs are oxidized or otherwise removed. Here we describe an airborne sampling system designed to collect a vertical profile of air into a 3/800 OD tube 150m in length. The inlet ram air pressure is used to flow sampled air through the 10 tube, which results in a varying flow rate based on aircraft speed and altitude. Since aircraft velocity decreases during ascent, it is necessary to account for the variable flow rate into the tube. This is accomplished using a reference gas that is pulsed into the air stream so that the precise altitude of the collected air can be reconstructed post-collection. The pulsed injections are also used to determine any significant effect 15 from diffusion/mixing within the sampling tube, either during collection or subsequent extraction for gas analysis. This system has been successfully deployed, and we show some measured vertical profiles of isoprene and its oxidation products methacrolein and methyl vinyl ketone from a mixed canopy near Columbia, Missouri.

  1. Mass extinction of birds at the Cretaceous-Paleogene (K-Pg) boundary.

    PubMed

    Longrich, Nicholas R; Tokaryk, Tim; Field, Daniel J

    2011-09-13

    The effect of the Cretaceous-Paleogene (K-Pg) (formerly Cretaceous-Tertiary, K-T) mass extinction on avian evolution is debated, primarily because of the poor fossil record of Late Cretaceous birds. In particular, it remains unclear whether archaic birds became extinct gradually over the course of the Cretaceous or whether they remained diverse up to the end of the Cretaceous and perished in the K-Pg mass extinction. Here, we describe a diverse avifauna from the latest Maastrichtian of western North America, which provides definitive evidence for the persistence of a range of archaic birds to within 300,000 y of the K-Pg boundary. A total of 17 species are identified, including 7 species of archaic bird, representing Enantiornithes, Ichthyornithes, Hesperornithes, and an Apsaravis-like bird. None of these groups are known to survive into the Paleogene, and their persistence into the latest Maastrichtian therefore provides strong evidence for a mass extinction of archaic birds coinciding with the Chicxulub asteroid impact. Most of the birds described here represent advanced ornithurines, showing that a major radiation of Ornithurae preceded the end of the Cretaceous, but none can be definitively referred to the Neornithes. This avifauna is the most diverse known from the Late Cretaceous, and although size disparity is lower than in modern birds, the assemblage includes both smaller forms and some of the largest volant birds known from the Mesozoic, emphasizing the degree to which avian diversification had proceeded by the end of the age of dinosaurs. PMID:21914849

  2. Mass extinction of birds at the Cretaceous–Paleogene (K–Pg) boundary

    PubMed Central

    Longrich, Nicholas R.; Tokaryk, Tim; Field, Daniel J.

    2011-01-01

    The effect of the Cretaceous-Paleogene (K-Pg) (formerly Cretaceous–Tertiary, K–T) mass extinction on avian evolution is debated, primarily because of the poor fossil record of Late Cretaceous birds. In particular, it remains unclear whether archaic birds became extinct gradually over the course of the Cretaceous or whether they remained diverse up to the end of the Cretaceous and perished in the K–Pg mass extinction. Here, we describe a diverse avifauna from the latest Maastrichtian of western North America, which provides definitive evidence for the persistence of a range of archaic birds to within 300,000 y of the K–Pg boundary. A total of 17 species are identified, including 7 species of archaic bird, representing Enantiornithes, Ichthyornithes, Hesperornithes, and an Apsaravis-like bird. None of these groups are known to survive into the Paleogene, and their persistence into the latest Maastrichtian therefore provides strong evidence for a mass extinction of archaic birds coinciding with the Chicxulub asteroid impact. Most of the birds described here represent advanced ornithurines, showing that a major radiation of Ornithurae preceded the end of the Cretaceous, but none can be definitively referred to the Neornithes. This avifauna is the most diverse known from the Late Cretaceous, and although size disparity is lower than in modern birds, the assemblage includes both smaller forms and some of the largest volant birds known from the Mesozoic, emphasizing the degree to which avian diversification had proceeded by the end of the age of dinosaurs. PMID:21914849

  3. The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

    ERIC Educational Resources Information Center

    Driscoll, John N.; Warneck, Peter

    1973-01-01

    Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

  4. Tectonic activity evolution of the Scotia-Antarctic Plate boundary from mass transport deposit analysis

    NASA Astrophysics Data System (ADS)

    Pérez, Lara F.; Bohoyo, Fernando; Hernández-Molina, F. Javier; Casas, David; Galindo-Zaldívar, Jesús; Ruano, Patricia; Maldonado, Andrés.

    2016-04-01

    The spatial distribution and temporal occurrence of mass transport deposits (MTDs) in the sedimentary infill of basins and submerged banks near the Scotia-Antarctic plate boundary allowed us to decode the evolution of the tectonic activity of the relevant structures in the region from the Oligocene to present day. The 1020 MTDs identified in the available data set of multichannel seismic reflection profiles in the region are subdivided according to the geographic and chronological distributions of these features. Their spatial distribution reveals a preferential location along the eastern margins of the eastern basins. This reflects local deformation due to the evolution of the Scotia-Antarctic transcurrent plate boundary and the impact of oceanic spreading along the East Scotia Ridge (ESR). The vertical distribution of the MTDs in the sedimentary record evidences intensified regional tectonic deformation from the middle Miocene to Quaternary. Intensified deformation started at about 15 Ma, when the ESR progressively replaces the West Scotia Ridge (WSR) as the main oceanic spreading center in the Scotia Sea. Coevally with the WSR demise at about 6.5 Ma, increased spreading rates of the ESR and numerous MTDs were formed. The high frequency of MTDs during the Pliocene, mainly along the western basins, is also related to greater tectonic activity due to uplift of the Shackleton Fracture Zone by tectonic inversion and extinction of the Antarctic-Phoenix Ridge and involved changes at late Pliocene. The presence of MTDs in the southern Scotia Sea basins is a relevant indicator of the interplay between sedimentary instability and regional tectonics.

  5. Charge and discharge of polar cold air mass in northern hemispheric winter

    NASA Astrophysics Data System (ADS)

    Kanno, Yuki; Abdillah, Muhammad Rais; Iwasaki, Toshiki

    2015-09-01

    This study shows the variability of polar cold air mass amount below potential temperature of 280 K, and north of 45°N can be understood with a concept of charge and discharge, where anomalously large daily discharge indicates an intermittent occurrence of cold air outbreak. The polar cold air mass amount north of 45°N gradually charges up due to diabatic cooling but dramatically discharges due to cold air outbreak with a pulse width of about 5 days. Cold air outbreaks tend to bring colder winter in East Asia and the east coast of North America, while warmer winter prevails on the northern side of these regions. The cold air mass amount south of 45°N increases just after a cold air outbreak but returns to the normal level soon because of its life time of about 3 days. Therefore, monthly mean of total cold air mass amount in the Northern Hemisphere is negatively correlated with the monthly mean discharge.

  6. FUNDAMENTAL MASS TRANSFER MODEL FOR INDOOR AIR EMISSION FROM SURFACE COATINGS

    EPA Science Inventory

    The paper, discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architect...

  7. DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

    EPA Science Inventory

    The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

  8. Experimental Determination of the Mass of Air Molecules from the Law of Atmospheres.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Galvin, Vincent, Jr.

    1979-01-01

    A gas pressure gauge has been constructed for use in a student experiment involving the law of atmospheres. From pressure data obtained at selected elevations the average mass of air molecules is determined and compared to that calculated from the molecular weights and percentages of constituents to the air. (Author/BB)

  9. High-Reynolds-number turbulent-boundary-layer wall pressure fluctuations with skin-friction reduction by air injection.

    PubMed

    Winkel, Eric S; Elbing, Brian R; Ceccio, Steven L; Perlin, Marc; Dowling, David R

    2008-05-01

    The hydrodynamic pressure fluctuations that occur on the solid surface beneath a turbulent boundary layer are a common source of flow noise. This paper reports multipoint surface pressure fluctuation measurements in water beneath a high-Reynolds-number turbulent boundary layer with wall injection of air to reduce skin-friction drag. The experiments were conducted in the U.S. Navy's Large Cavitation Channel on a 12.9-m-long, 3.05-m-wide hydrodynamically smooth flat plate at freestream speeds up to 20 ms and downstream-distance-based Reynolds numbers exceeding 200 x 10(6). Air was injected from one of two spanwise slots through flush-mounted porous stainless steel frits (approximately 40 microm mean pore diameter) at volume flow rates from 17.8 to 142.5 l/s per meter span. The two injectors were located 1.32 and 9.78 m from the model's leading edge and spanned the center 87% of the test model. Surface pressure measurements were made with 16 flush-mounted transducers in an "L-shaped" array located 10.7 m from the plate's leading edge. When compared to no-injection conditions, the observed wall-pressure variance was reduced by as much as 87% with air injection. In addition, air injection altered the inferred convection speed of pressure fluctuation sources and the streamwise coherence of pressure fluctuations. PMID:18529171

  10. Critical Mass Academic Planning. AIR Forum Paper 1978.

    ERIC Educational Resources Information Center

    Jones, Larry R.

    Methods of academic resource planning for research-oriented colleges and universities are explored. Focus is on resource allocation that is not strictly related to overall institutional enrollment level, but with the desirability of maintaining a minimum or "critical mass" levels of program breadth and quality. The purpose of critical mass…

  11. Impact of mass and bond energy difference and interface defects on thermal boundary conductance

    NASA Astrophysics Data System (ADS)

    Choi, ChangJin

    The objective of this study is to use molecular dynamics simulation techniques in order to improve the understanding of phonon transport at the interface of dissimilar materials and the impact of different material properties on thermal boundary conductance (TBC). In order to achieve this goal, we investigated the contributions of mass and bond energy difference and interface defects on TBC at the interface of nanostructured materials using non-equilibrium molecular dynamics (NEMD) simulation and phonon wave-packet (PWP) simulation techniques. NEMD is used to distinguish relative and combined contributions of mass and bond energy difference on TBC. As a result, it is found that the mass has a stronger contribution than the bond energy on lowering the TBC and that the TBC is dependent on the length of interdiffusion region as well as temperature. In addition, evidence of inelastic scattering is observed with interdiffusion regions especially when two materials differ in the bond energy. A detailed description of phonon interactions at the interface is obtained performing PWP simulations. A frequency dependence of the TBC based on phonon dispersion relation is observed. As it is expected, minimum scattering occurs when there exists only vibrational mismatch at the interface and inelastic scattering is to take place at high frequency region when the bond energy of the two materials is different resulting in the strain at the interface. It is also shown that the level of inelastic scattering is dependent on the length of the interdiffusion region. In addition, the TBC calculated with the results of PWP simulations is compared with that of NEMD simulations as well as theoretical predictions from the acoustic mismatch model and the diffuse mismatch model. A simple analytical model, which utilizes knowledge of thermal interface resistance and the interface geometry for the prediction of effective thermal conductivity, is developed. This model is generated based on Si

  12. Anoxia, sealevel changes and mass extinctions at the Devonian/Carboniferous boundary

    NASA Astrophysics Data System (ADS)

    Kaiser, S. I.; Steuber, T.; Becker, R. T.

    2003-04-01

    During the Latest Devonian, the transition from global greenhouse to icehouse conditions began with a first glaciation pulse in SW Gondwana. Decisive palaeoclimatic and palaeoceanographic changes are reflected in the multiphase Late Devonian Hangenberg Event. Mass extinctions, blackshale and sandstone deposits in different palaeogeographical settings were the result of eustatic sea level changes, and probably also of variations in the composition and temperature of seawater during the Late Devonian -- Early Carboniferous. The investigated boundary sections from different palaeogeographical settings include localities in Europe and North Africa. Detailed bed-by-bed sampling of limestones, and field observations on the sedimentology of intercalated siliciclastics were considered important in order to achieve a high-resolution biostratigraphical zonation, precise records of biofacies evolution, and correlation of changes in sedimentary environments. The carbon isotopic composition of micritic limestones and the oxygen isotopic composition of conodont apatite provide important information about palaeoceanographic changes and perturbations in the global carbon cycle during the event interval. Detailed investigations of the sedimentology in Moroccan sections indicate significant variations of facies patterns over short distances. The Famennian pelagic carbonate platform of North-Gondwana was not re-established in the latest Famennian or in the post-event early Tournaisian, which yielded new rich goniatites from blackshales and sandstones. These observations and microfacies analyses from other sections of different palaeolatitudes are important for the reconstruction and correlation of global transgression-regression cycles. The first results of biostratigraphical correlations will be presented together with carbon isotope data of micritic limestone collected from boundary sections in the Rheinische Schiefergebirge and in the Carnic Alps. A slight but continuous decrease

  13. Modelling near subsurface temperature with mixed type boundary condition for transient air temperature and vertical groundwater flow

    NASA Astrophysics Data System (ADS)

    Kumar, Rajeev Ranjan; Ramana, D. V.; Singh, R. N.

    2012-10-01

    Near-subsurface temperatures have signatures of climate change. Thermal models of subsurface have been constructed by prescribing time dependent Dirichlet type boundary condition wherein the temperature at the soil surface is prescribed and depth distribution of temperature is obtained. In this formulation it is not possible to include the relationship between air temperatures and the temperature of soil surface. However, if one uses a Robin type boundary condition, a transfer coefficient relates the air and soil surface temperatures which helps to determine both the temperature at the surface and at depth given near surface air temperatures. This coefficient is a function of meteorological conditions and is readily available. We have developed such a thermal model of near subsurface region which includes both heat conduction and advection due to groundwater flows and have presented numerical results for changes in the temperature-depth profiles for different values of transfer coefficient and groundwater flux. There are significant changes in temperature and depth profiles due to changes in the transfer coefficient and groundwater flux. The analytical model will find applications in the interpretation of the borehole geothermal data to extract both climate and groundwater flow signals.

  14. Computational Study of Surface Tension and Wall Adhesion Effects on an Oil Film Flow Underneath an Air Boundary Layer

    NASA Technical Reports Server (NTRS)

    Celic, Alan; Zilliac, Gregory G.

    1998-01-01

    The fringe-imaging skin friction (FISF) technique, which was originally developed by D. J. Monson and G. G. Mateer at Ames Research Center and recently extended to 3-D flows, is the most accurate skin friction measurement technique currently available. The principle of this technique is that the skin friction at a point on an aerodynamic surface can be determined by measuring the time-rate-of-change of the thickness of an oil drop placed on the surface under the influence of the external air boundary layer. Lubrication theory is used to relate the oil-patch thickness variation to shear stress. The uncertainty of FISF measurements is estimated to be as low as 4 percent, yet little is known about the effects of surface tension and wall adhesion forces on the measured results. A modified version of the free-surface Navier-Stokes solver RIPPLE, developed at Los Alamos National Laboratories, was used to compute the time development of an oil drop on a surface under a simulated air boundary layer. RIPPLE uses the volume of fluid method to track the surface and the continuum surface force approach to model surface tension and wall adhesion effects. The development of an oil drop, over a time period of approximately 4 seconds, was studied. Under the influence of shear imposed by an air boundary layer, the computed profile of the drop rapidly changes from its initial circular-arc shape to a wedge-like shape. Comparison of the time-varying oil-thickness distributions computed using RIPPLE and also computed using a greatly simplified numerical model of an oil drop equation which does not include surface tension and wall adhesion effects) was used to evaluate the effects of surface tension on FISF measurement results. The effects of surface tension were found to be small but not necessarily negligible in some cases.

  15. Aerosol composition and properties variation at the ground and over the column under different air masses advection in South Italy.

    PubMed

    Pavese, G; Lettino, A; Calvello, M; Esposito, F; Fiore, S

    2016-04-01

    Aerosol composition and properties variation under the advection of different air masses were investigated, as case studies, by contemporary measurements over the atmospheric column and at the ground in a semi-rural site in South Italy. The absence of local strong sources in this area allowed to characterize background aerosol and to compare particle mixing effects under various atmospheric circulation conditions. Aerosol optical depth (AOD) and Ǻngström parameters from radiometric measurements allowed the detection and identification of polluted, dust, and volcanic atmospheric conditions. AODs were the input for a suitable model to evaluate the columnar aerosol composition, according to six main atmospheric components (water-soluble, soot, sea salt accumulation, sea salt coarse, mineral dus,t and biological). Scanning electron microscope (SEM) analysis of particulate sampled with a 13-stage impactor at the ground showed not only fingerprints typical of the different air masses but also the effects of transport and aging on atmospheric particles, suggesting processes that changed their chemical and optical properties. Background columnar aerosol was characterized by 72% of water-soluble and soot, in agreement with ground-based findings that highlighted 60% of contribution from anthropogenic carbonate particles and soot. In general, a good agreement between ground-based and columnar results was observed. Under the advection of trans-boundary air masses, water-soluble and soot were always present in columnar aerosol, whereas, in variable percentages, sea salt and mineral particles characterized both dust and volcanic conditions. At the ground, sulfates characterized the amorphous matrix produced in finer stages by the evaporation of solutions of organic and inorganic aerosols. Sulfates were also one of the key players involved in heterogeneous chemical reactions, producing complex secondary aerosol, as such clay-sulfate internally mixed particle externally mixed

  16. Air-Ice-Ocean Interaction: Turbulent Ocean Boundary Layer Exchange Processes

    NASA Astrophysics Data System (ADS)

    Weller, Robert

    2010-01-01

    This is a well-written book about the upper boundary layer of the ice-covered ocean. It combines a presentation of the physics and associated equations governing the structure of and mixing within the ice-ocean boundary layer (IOBL) with illustrative examples from fieldwork carried out during the author's career. The examples and good graphics do much to solidify the understanding the reader develops about these matters. Together with short summary glossaries of key quantities and parameters at the end of many chapters, the author's approach of weaving theory and observations together has resulted in an excellent text.

  17. Investigations of the boundary-layer control on a full scale swept wing with air bled off from the turbojet

    NASA Technical Reports Server (NTRS)

    Rebuffet, Pierre; Poisson-Quinton, PH

    1952-01-01

    The following account reviews the various stages of a research program relative to the high-lift devices on a swept wing by combined suction and blowing (jet action), with ejectors fed by air bled off (extracted) from the turbojet. After reviewing the essential principles of the boundary-layer control obtained by comparison with theory, the electric analogies and the wind-tunnel tests as well as the essential elements of ejector operations, the writers describe the tests made in the large tunnel at Chalais-Meudon on a full-scale model of the SO 6020 wing.

  18. THE IMPACT OF SHRINKING HANFORD BOUNDARIES ON PERMITS FOR TOXIC AIR POLLUTANT EMISSIONS FROM THE HANFORD 200 WEST AREA

    SciTech Connect

    JOHNSON, R.E.

    2005-11-09

    This presentation (CE-580. Graduate Seminar) presents a brief description of an approach to use a simpler dispersion modeling method (SCREEN3) in conjunction with joint frequency tables for Hanford wind conditions to evaluate the impacts of shrinking the Hanford boundaries on the current permits for facilities in the 200 West Area. To fulfill requirements for the graduate student project (CE-702. Master's Special Problems), this evaluation will be completed and published over the next two years. Air toxic emissions play an important role in environmental quality and require a state approved permit. One example relates to containers or waste that are designated as Transuranic Waste (TRU), which are required to have venting devices due to hydrogen generation. The Washington State Department of Ecology (Ecology) determined that the filters used did not meet the definition of a ''pressure relief device'' and that a permit application would have to be submitted by the Central Waste Complex (CWC) for criteria pollutant and toxic air pollutant (TAP) emissions in accordance with Washington Administrative Code (WAC) 173-400 and 173-460. The permit application submitted in 2000 to Ecology used Industrial Source Code III (ISCIII) dispersion modeling to demonstrate that it was not possible for CWC to release a sufficient quantity of fugitive Toxic Air Pollutant emissions that could exceed the Acceptable Source Impact Levels (ASILs) at the Hanford Site Boundary. The modeled emission rates were based on the diurnal breathing in and out through the vented drums (approximately 20% of the drums), using published vapor pressure, molecular weight, and specific gravity data for all 600+ compounds, with a conservative estimate of one exchange volume per day (208 liters per drum). Two permit applications were submitted also to Ecology for the Waste Receiving and Processing Facility and the T Plant Complex. Both permit applications were based on the Central Waste Complex approach, and

  19. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... (2) A frame of aluminum or other material with low melting point is used. (d) A window or air port... extend below a point 910 millimeters (36 inches) above the deck unless storm rails, that are...

  20. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... (2) A frame of aluminum or other material with low melting point is used. (d) A window or air port... extend below a point 910 millimeters (36 inches) above the deck unless storm rails, that are...

  1. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... (2) A frame of aluminum or other material with low melting point is used. (d) A window or air port... extend below a point 910 millimeters (36 inches) above the deck unless storm rails, that are...

  2. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... (2) A frame of aluminum or other material with low melting point is used. (d) A window or air port... extend below a point 910 millimeters (36 inches) above the deck unless storm rails, that are...

  3. 46 CFR 116.433 - Windows and air ports in fire control boundaries.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... (2) A frame of aluminum or other material with low melting point is used. (d) A window or air port... extend below a point 910 millimeters (36 inches) above the deck unless storm rails, that are...

  4. Thin-Film Air-Mass-Flow Sensor of Improved Design Developed

    NASA Technical Reports Server (NTRS)

    Fralick, Gustave C.; Wrbanek, John D.; Hwang, Danny P.

    2003-01-01

    Researchers at the NASA Glenn Research Center have developed a new air-mass-flow sensor to solve the problems of existing mass flow sensor designs. NASA's design consists of thin-film resistors in a Wheatstone bridge arrangement. The resistors are fabricated on a thin, constant-thickness airfoil to minimize disturbance to the airflow being measured. The following photograph shows one of NASA s prototype sensors. In comparison to other air-mass-flow sensor designs, NASA s thin-film sensor is much more robust than hot wires, causes less airflow disturbance than pitot tubes, is more accurate than vane anemometers, and is much simpler to operate than thermocouple rakes. NASA s thin-film air-mass-flow sensor works by converting the temperature difference seen at each leg of the thin-film Wheatstone bridge into a mass-flow rate. The following figure shows a schematic of this sensor with air flowing around it. The sensor operates as follows: current is applied to the bridge, which increases its temperature. If there is no flow, all the arms are heated equally, the bridge remains in balance, and there is no signal. If there is flow, the air passing over the upstream legs of the bridge reduces the temperature of the upstream legs and that leads to reduced electrical resistance for those legs. After the air has picked up heat from the upstream legs, it continues and passes over the downstream legs of the bridge. The heated air raises the temperature of these legs, increasing their electrical resistance. The resistance difference between the upstream and downstream legs unbalances the bridge, causing a voltage difference that can be amplified and calibrated to the airflow rate. Separate sensors mounted on the airfoil measure the temperature of the airflow, which is used to complete the calculation for the mass of air passing by the sensor. A current application for air-mass-flow sensors is as part of the intake system for an internal combustion engine. A mass-flow sensor is

  5. Interaction of mid-latitude air masses with the polar dome area during RACEPAC and NETCARE

    NASA Astrophysics Data System (ADS)

    Bozem, Heiko; Hoor, Peter; Koellner, Franziska; Kunkel, Daniel; Schneider, Johannes; Schulz, Christiane; Herber, Andreas; Borrmann, Stephan; Wendisch, Manfred; Ehrlich, Andre; Leaitch, Richard; Willis, Megan; Burkart, Julia; Thomas, Jennie; Abbatt, Jon

    2016-04-01

    We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories as well as Flexpart particle dispersion modeling we analyze the transport regimes of mid-latitude air masses traveling to the high Arctic prevalent during spring (RACEPAC 2014, NETCARE 2015) and summer (NETCARE 2014). In general more northern parts of the high Arctic (Lat > 75°N) were relatively unaffected from mid-latitude air masses. In contrast, regions further south are influenced by air masses from Asia and Russia (eastern part of Canadian Arctic and European Arctic) as well as from North America (central and western parts of Canadian Arctic). The transition between the mostly isolated high Arctic and more southern regions indicated by tracer gradients is remarkably sharp. This allows for a chemical definition of the Polar dome based on the variability of CO and CO2 as a marker. Isentropic surfaces that slope from the surface to higher altitudes in the high Arctic form the polar dome that represents a transport barrier for mid-latitude air masses to enter the lower troposphere in the high Arctic. Synoptic-scale weather systems frequently disturb this transport barrier and foster the exchange between air masses from the mid-latitudes and polar regions. This can finally lead to enhanced pollution levels in the lower polar troposphere. Mid-latitude pollution plumes from biomass burning or flaring entering the polar dome area lead to an enhancement of 30% of the observed CO mixing ratio within the polar dome area.

  6. Climatic changes resulting from mass extinctions at the K-T boundary (and other bio-events)

    NASA Technical Reports Server (NTRS)

    Rampino, Michael R.; Volk, Tyler

    1988-01-01

    The mass extinctions at the Cretaceous-Tertiary (K-T) boundary include about 90 percent of marine calcareous nannoplankton (coccoliths), and carbon-isotope data show that marine primary productivity was drastically reduced for about 500,000 years after the boundary event, the so-called Strangelove Ocean effect. One result of the elimination of most marine phytoplankton would have been a severe reduction in production of dimethyl sulfide (DMS), a biogenic gas that is believed to be the major precursor of cloud condensation nuclei (CCN) over the oceans. A drastic reduction in marine CCN should lead to a cloud canopy with significantly lower reflectivity, and hence cause a significant warming at the earth's surface. Calculations suggest that, all other things being held constant, a reduction in CCN of more than 80 percent (a reasonable value for the K-T extinctions) could have produced a rapid global warming of 6 C or more. Oxygen-isotope analyses of marine sediments, and other kinds of paleoclimatic data, have provided for a marked warming, and a general instability of climate coincident with the killoff of marine plankton at the K-T boundary. Similar reductions in phytoplankton abundance at other boundaries, as indicated by marked shifts in carbon-isotope curves, suggest that severe temperature changes may have accompanied other mass extinctions, and raises the intriguing possibility that the extinction events themselves could have contributed to the climatic instabilities at critical bio-events in the geologic record.

  7. Air mass flow estimation in turbocharged diesel engines from in-cylinder pressure measurement

    SciTech Connect

    Desantes, J.M.; Galindo, J.; Guardiola, C.; Dolz, V.

    2010-01-15

    Air mass flow determination is needed for the control of current internal combustion engines. Current methods are based on specific sensors (as hot wire anemometers) or indirect estimation through manifold pressure. With the availability of cylinder pressure sensors for engine control, methods based on them can be used for replacing or complementing standard methods. Present paper uses in cylinder pressure increase during the intake stroke for inferring the trapped air mass. The method is validated on two different turbocharged diesel engines and compared with the standard methods. (author)

  8. Comparisons of rational engineering correlations of thermophoretically-augmented particle mass transfer with STAN5-predictions for developing boundary layers

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Rosner, D. E.

    1984-01-01

    Modification of the code STAN5 to properly include thermophoretic mass transport, and examination of selected test cases developing boundary layers which include variable properties, viscous dissipation, transition to turbulence and transpiration cooling. Under conditions representative of current and projected GT operation, local application of St(M)/St(M),o correlations evidently provides accurate and economical engineering design predictions, especially for suspended particles characterized by Schmidt numbers outside of the heavy vapor range.

  9. A Sharp-Interface Immersed Boundary Method with Improved Mass Conservation and Reduced Spurious Pressure Oscillations.

    PubMed

    Seo, Jung Hee; Mittal, Rajat

    2011-08-10

    A method for reducing the spurious pressure oscillations observed when simulating moving boundary flow problems with sharp-interface immersed boundary methods (IBMs) is proposed. By first identifying the primary cause of these oscillations to be the violation of the geometric conservation law near the immersed boundary, we adopt a cut-cell based approach to strictly enforce geometric conservation. In order to limit the complexity associated with the cut-cell method, the cut-cell based discretization is limited only to the pressure Poisson and velocity correction equations in the fractional-step method and the small-cell problem tackled by introducing a virtual cell-merging technique. The method is shown to retain all the desirable properties of the original finite-difference based IBM while at the same time, reducing pressure oscillations for moving boundaries by roughly an order of magnitude. PMID:21857745

  10. Apparatus and method for generating large mass flow of high temperature air at hypersonic speeds

    NASA Technical Reports Server (NTRS)

    Sabol, A. P.; Stewart, R. B. (Inventor)

    1973-01-01

    High temperature, high mass air flow and a high Reynolds number test air flow in the Mach number 8-10 regime of adequate test flow duration is attained by pressurizing a ceramic-lined storage tank with air to a pressure of about 100 to 200 atmospheres. The air is heated to temperatures of 7,000 to 8,000 R prior to introduction into the tank by passing the air over an electric arc heater means. The air cools to 5,500 to 6,000 R while in the tank. A decomposable gas such as nitrous oxide or a combustible gas such as propane is injected into the tank after pressurization and the heated pressurized air in the tank is rapidly released through a Mach number 8-10 nozzle. The injected gas medium upon contact with the heated pressurized air effects an exothermic reaction which maintains the pressure and temperature of the pressurized air during the rapid release.

  11. Variability of local PM10 mass concentrations in connection with blocking air circulation

    NASA Astrophysics Data System (ADS)

    Ştefan, Sabina; Roman, Iuliana

    2015-06-01

    The aim of this paper is to analyze the temporal variability of Particulate Matter mass concentrations in connection with air circulation, for eight rural sites situated in the Central and Eastern parts of Europe. The stations from Poland, Hungary and Romania are rural stations without sources of pollutants. The analysis covers four winters, between December 2004 and February 2008. The pollution episodes were selected to explain air circulation influence. The results show that the causes of pollution were local, due to high mean sea level pressure and the blocking, as air circulation on large scale, was dominant in the cases of enhanced pollution in the selected area.

  12. The Use of Red Green Blue (RGB) Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Zavodsky, Bradley; Molthan, Andrew; Jedlovec, Gary

    2013-01-01

    AIRS ozone and model PV analysis confirm the stratospheric air in RGB Air Mass imagery. Trajectories confirm winds south of the low were distinct from CCB driven winds. Cross sections connect the tropopause fold, downward motion, and high nearsurface winds. Comparison to conceptual models show Shapiro-Keyser features and sting jet characteristics were observed in a storm that impacted the U.S. East Coast. RGB Air Mass imagery can be used to identify stratospheric air and regions susceptible to tropopause folding and attendant non-convective winds.

  13. The evolution of the boundary layer and its effect on air chemistry in the Phoenix area.

    SciTech Connect

    Fast, J. D.; Doran, J. C.; Shaw, W. J.; Coulter, R. L.; Martin, T. J.; Environmental Research; PNNL

    2000-09-27

    During a 4-week period in May and June of 1998, meteorological and chemical measurements were made as part of a field campaign carried out in the Phoenix area. Data from the field campaign provide the first detailed measurements of the properties of the convective boundary layer in this area and of the effects of these properties on ozone levels. The meteorological and chemical measurements have been combined with results from a set of meteorological, particle, and chemistry models to study ozone production, transport, and mixing in the vicinity of Phoenix. Good agreement between the simulations and observations was obtained, and the results have been used to illustrate several important factors affecting ozone patterns in the region. Heating of the higher terrain north and east of Phoenix regularly produced thermally driven circulations from the south and southwest through most of the boundary layer during the afternoon, carrying the urban ozone plume to the northeast. The combination of deep mixed layers and moderate winds aloft provided good ventilation of the Phoenix area on most days so that multiday buildups of locally produced ozone did not appear to contribute significantly to ozone levels during the study period. Sensitivity simulations determined that 20 to 40% of the afternoon surface ozone mixing ratios (corresponding to 15 to 35 ppb) were due to vertical mixing processes that entrained reservoirs of ozone into the growing convective boundary layer. The model results also indicated that ozone production in the region is volatile organic compound limited.

  14. Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

    PubMed

    Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

    2007-10-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented. PMID:17716909

  15. Remote Mass Spectrometric Sampling of Electrospray- and Desorption Electrospray-Generated Ions Using an Air Ejector

    PubMed Central

    Dixon, R. Brent; Bereman, Michael S.; Muddiman, David C.; Hawkridge, Adam M.

    2007-01-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data is presented. PMID:17716909

  16. Air temperature variations on the Atlantic - Arctic boundary since 1802: the low-frequency pattern and ocean teleconnections

    NASA Astrophysics Data System (ADS)

    Wood, K. R.; Overland, J. E.; Jónsson, T.; Smoliak, B. V.

    2010-12-01

    A two-hundred year instrumental record of annual surface air temperature (SAT) in the Atlantic - Arctic boundary region was reconstructed from four station-based composite time series (Fig. 1). Credibility is supported by ice core records, other temperature proxies, and historical evidence. This record (designated TNA) provides new perspective on past climate fluctuations in a region where pivotal climate system processes occur and where unexplained low-frequency variations were observed during the 20th century. TNA shows that the low-frequency pattern of the 20th century does not have a clear analog in the previous century. During the 19th century decadal-scale climate fluctuations occurred in irregular episodes; none were as distinctive as the early 20th century warming event (~1920 to mid-century), which is the most striking historical feature in the record. Evidence of a strong teleconnection between TNA and SST anomalies in the western boundary current - southern recirculation gyre (WBC) region of the North Atlantic Ocean provides an opportunity to reframe the problem of low-frequency variability in the region in terms tractable to theory and empirical investigation. Positive fluctuations in both TNA (and by extension other climate variables associated with it) and SST in the WBC region could be initiated by persistent variations in the large-scale atmospheric circulation that promote the advection of warm maritime air into the Atlantic - Arctic region and simultaneously limit flux-induced cooling in the Nordic Seas and the WBC/recirculation gyre region. This leads to enhanced ocean heat storage in both regions and may consequently reinforce anomalous atmospheric circulation patterns like those observed during the early 20th century warming event. Figure 1. Extended annual mean SAT record for the Atlantic - Arctic boundary region (TNA). The early 20th century warming (ETCW) episode is marked. Regions represented by station-based composite SAT records used in

  17. SIMULATING REGIONAL-SCALE AIR QUALITY WITH DYNAMIC CHANGES IN REGIONAL CLIMATE AND CHEMICAL BOUNDARY CONDITIONS

    EPA Science Inventory

    This poster compares air quality modeling simulations under current climate and a future (approximately 2050) climate scenario. Differences in predicted ozone episodes and daily average PM2.5 concentrations are presented, along with vertical ozone profiles. Modeling ...

  18. Efficiently solving morphodynamics in complex geometies using a mass conservative immersed boundary method on a structured grid.

    NASA Astrophysics Data System (ADS)

    Canestrelli, A.; Jagers, B.; Spruyt, A.; Borsboom, M.; Slingerland, R. L.

    2014-12-01

    In this work we propose an efficient approach to solve morphodynamics in complex river geometries, with a particular emphasis for river deltas. We use a novel immersed boundary method of solution in Delft3D, an open source hydrodynamic model that employs a Cartesian structured grid. Our approach employs a hybrid cut-cell/ghost-cell method: ghost cells are used for the flow momentum equations in order to prescribe the correct boundary condition at the immersed boundary, while cut-cells are used in the continuity equation in order to conserve mass. The resulting scheme is robust, does not suffer any time step limitation for small cut cells and conserves fluid mass up to machine precision. The model has been coupled with the existing Delft3D morphodynamic module, adapted for the presence of immersed irregular boundaries cutting through the regular grid. A cut-cell technique is proposed for both the bed-load and suspended load components. The bed-load component, without any modification, turns out to trigger bed instability in small cut-cells, especially for high values of the morphodynamic factor. We therefore propose a simple "virtual merging technique" that guarantees stability even for very high values of the morphodynamic factor. A bank erosion module provides for lateral displacement of the immersed boundaries in proportion to excess bank shear stress. The model has been tested against different analytical and reference solutions. Moreover, morphodynamic simulations of river deltas show that deltas with various channel networks arise as a consequence of jet momentum and stability, and sediment size and geotechnical properties.

  19. Carbon cycle perturbation and stabilization in the wake of the Triassic-Jurassic boundary mass-extinction event

    NASA Astrophysics Data System (ADS)

    van de Schootbrugge, B.; Payne, J. L.; Tomasovych, A.; Pross, J.; Fiebig, J.; Benbrahim, M.; FöLlmi, K. B.; Quan, T. M.

    2008-04-01

    The Triassic-Jurassic boundary mass-extinction event (T-J; 199.6 Ma) is associated with major perturbations in the carbon cycle recorded in stable carbon isotopes. Two rapid negative isotope excursions in bulk organic carbon (δ13Corg) occur within the immediate boundary interval at multiple locations and have been linked to the outgassing of 12C-enriched CO2 from the Central Atlantic Magmatic Province. In British Columbia, a positive δ13Corg excursion of +5‰ (Vienna Peedee belemnite (V-PDB)) spans part or all of the subsequent Hettangian stage. Here, we examine the significance of these carbon isotope excursions as records of global carbon cycle dynamics across the T-J boundary and test the link between carbon cycle perturbation-stabilization and biotic extinction-recovery patterns. A combination of δ13Corg and palynological analyses from the Late Triassic to Early Jurassic in the Mingolsheim core (Germany) suggests that organic carbon isotope variations are best explained as the result of both compositional changes in terrestrial versus marine input and disturbance and recovery patterns of major terrestrial plant groups across the T-J boundary. A new high-resolution δ13Ccarb record from the Val Adrara section in the Southern Alps (Italy) spanning from the uppermost Rhaetian through Lower Sinemurian does not exhibit a negative excursion at the T-J boundary but does record a large positive δ13Ccarb excursion of +4‰ (V-PDB) in bulk carbonate that begins at the T-J boundary and reaches a local maximum at the Early Late Hettangian boundary. Values then gradually decrease reaching +0.5‰ at the Hettangian-Sinemurian boundary and remain relatively constant into the Early Sinemurian. Complementary δ13Ccarb data from 4 more sections that span the Hettangian-Sinemurian boundary support carbon cycle stabilization within the Upper Hettangian. Our analyses suggest that isotope changes in organic carbon reservoirs do not necessarily require a shift in the global

  20. Transitions of cloud-topped marine boundary layers characterized by AIRS, MODIS, and a large eddy simulation model

    SciTech Connect

    Yue, Qing; Kahn, Brian; Xiao, Heng; Schreier, Mathias; Fetzer, E. J.; Teixeira, J.; Suselj, Kay

    2013-08-16

    Cloud top entrainment instability (CTEI) is a hypothesized positive feedback between entrainment mixing and evaporative cooling near the cloud top. Previous theoretical and numerical modeling studies have shown that the persistence or breakup of marine boundary layer (MBL) clouds may be sensitive to the CTEI parameter. Collocated thermodynamic profile and cloud observations obtained from the Atmospheric Infrared Sounder (AIRS) and Moderate Resolution Imaging Spectroradiometer (MODIS) instruments are used to quantify the relationship between the CTEI parameter and the cloud-topped MBL transition from stratocumulus to trade cumulus in the northeastern Pacific Ocean. Results derived from AIRS and MODIS are compared with numerical results from the UCLA large eddy simulation (LES) model for both well-mixed and decoupled MBLs. The satellite and model results both demonstrate a clear correlation between the CTEI parameter and MBL cloud fraction. Despite fundamental differences between LES steady state results and the instantaneous snapshot type of observations from satellites, significant correlations for both the instantaneous pixel-scale observations and the long-term averaged spatial patterns between the CTEI parameter and MBL cloud fraction are found from the satellite observations and are consistent with LES results. This suggests the potential of using AIRS and MODIS to quantify global and temporal characteristics of the cloud-topped MBL transition.

  1. Inert gas purgebox for Fourier transform ion cyclotron resonance mass spectrometry of air-sensitive solids

    NASA Astrophysics Data System (ADS)

    May, Michael A.; Marshall, Alan G.

    1994-03-01

    A sealed rigid ``purgebox'' makes it possible to load air- and/or moisture-sensitive solids into the solids probe inlet of a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer. A pelletized sample is transferred (in a sealed canister) from a commercial drybox to a Lucite(R) purgebox. After the box is purged with inert gas, an attached glove manipulator is used to transfer the sample from the canister to the solids probe of the mass spectrometer. Once sealed inside the inlet, the sample is pre-evacuated and then passed into the high vacuum region of the instrument at ˜10-7 Torr. The purgebox is transparent, portable, and readily assembled/disassembled. Laser desorption FT/ICR mass spectra of the air- and moisture-sensitive solids, NbCl5. NbCl2(C5H5)2, and Zr(CH3)2(C5H5)2 are obtained without significant oxidation. The residual water vapor concentration inside the purgebox was measured as 100±20 ppm after a 90-min purge with dry nitrogen gas. High-resolution laser desorption/ionization mass spectrometry of air-sensitive solids becomes feasible with the present purgebox interface. With minor modification of the purgebox geometry, the present method could be adapted to any mass spectrometer equipped with a solid sample inlet.

  2. Mass transfer through laminar boundary layer in 2-d microchannels with nonuniform cross section: the effect of wall curvature

    NASA Astrophysics Data System (ADS)

    Pedacchia, Augusta; Adrover, Alessandra

    2012-11-01

    We provide an analytical solution for the combined diffusive and convective 2-d mass transport from a surface film (of arbitrary shape at a given uniform concentration) to a pure solvent flowing in creeping flow conditions into a microchannel, delimited by a flat no-slip surface and by the releasing film itself. Such a problem arises in the study of swelling and dissolution of polimeric thin films under the action of a solvent tangential flow simulating the oral thin film dissolution for drug relase towards the buccal mucosa or oral cavity. We present a similarity solution for laminar forced convection mass (or heat) transfer that generalizes the classical boundary layer solution of the Graetz-Nusselt problem (valid for straight channels or pipes) to a solvent flowing in creeping flow conditions into a 2-d channel with cross-section continuously varying along the axial coordinate x. Close to the releasing boundary, parametrized by a curvilinear abscissa s, both tangential and normal velocity components play a role and their scaling behavior, as a function of wall distance r, should be taken into account in order to have an accurate description of the concentration profile in the boundary layer and of the dependence of the Sherwood number on the curvilinear abscissa s.

  3. Study of the extensive air shower mass sensitive parameters in prototype of ALBORZ array

    NASA Astrophysics Data System (ADS)

    Rastegarzadeh, G.; Nemati, M.

    2015-03-01

    In this work we have used muon production depth distribution as well as the lateral distribution of the secondary particles of Extensive Air Showers (EAS) as two main parameters to infer the mass composition of primary cosmic rays. In order to achieve a realistic estimate of the mass composition, a sample of showers initiated by proton and iron particles as primaries have been simulated by CORSIKA code with zenith angle between 0° and 18° and discrete energies in a range between 1014 and 1016 eV for ALBORZ (1200 m a.s.l, Tehran, Iran) and KASKADE (110 m a.s.l, Karlsruhe, Germany) observation levels. Moreover lateral density distribution functions of energy for charged particles of air showers have been proposed for both proton and Iron primaries. We have indicated that among these two EAS parameters, lateral distribution of secondary particles provides better mass discrimination.

  4. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general. PMID:10548806

  5. Compositional Variability of the Solar Wind: The Need for an Ultra-High Temporal Resolution Mass Spectrometer for Studies of Solar Wind and Coronal Mass Ejection Boundaries

    NASA Astrophysics Data System (ADS)

    Adrian, M. L.; Sheldon, R. B.; Vaisberg, O.; Suess, S. T.; Gallagher, D. L.; Craven, P. D.; Hamilton, D. C.

    2004-05-01

    Current state-of-the-art solar wind mass spectroscopy has clearly demonstrated the compositional uniqueness between slow/fast solar wind streams and slow/fast coronal mass ejections (CMEs). As such, solar wind composition measurements serve as an indicator of the sub-coronal and coronal processes responsible for the formation of these heliospheric features. While current instrumentation have identified temporal variations in solar wind/CME composition on the order of 10's of minutes, these detections have occurred during relatively quiescent periods, such as within the magnetic cloud portion of a CME, when temporal variations of the collective solar wind (including magnetic field variations) occur over periods in excess of the current minimum instrumental duty cycle of 5-minutes. Consequently, the compositional markers of the microphysics responsible for the formation of highly variable solar wind flows and for CME/prominence formation remain overlooked. To address the need for greater temporal resolution in solar wind compositional measurements, we have undertaken the development of a novel ultra-high temporal resolution ion mass spectrometer utilizing a helical ion path time-of-flight (TOF) system within a compact, low-mass, low-power instrument. The instrument is designed specifically to measure solar wind 3He+2 < M/q < 56Fe+6 ion plasmas from 0.3-20.0 keV/q with an order of magnitude greater geometric factor than current solar wind ion mass spectrometers, and produce 1-10 ms mass spectra with a mass resolution of M/Δ M ~ 200 or greater, all within a duty cycle of < 90-s. These characteristics achieve a resolution sufficient to probe spatial/temporal dimensions down to an ion gyroradius in solar wind flow boundaries at 1 AU. This paper presents an overview of solar wind mass spectroscopy results to date, justification for solar wind composition measurements of greater temporal resolution, and an introduction to the helical ion path mass spectrometer (HIPS

  6. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  7. Unsteady MHD boundary layer stagnation point flow with heat and mass transfer in nanofluid in the presence of mass fluid suction and thermal radiation

    NASA Astrophysics Data System (ADS)

    Salem, A. M.; Ismail, Galal; Fathy, Rania

    2015-06-01

    The unsteady boundary layer stagnation point flow of heat and mass transfer in a nanofluid with magnetic field and thermal radiation is theoretically investigated. The resulting governing equations are nondimensionalized and are transformed using a similarity transformation and then solved numerically by the shooting method. Comparison with the previously published work is presented and the results are found to be in good agreement. The effects of unsteadiness parameter A , solid volume fraction , magnetic field M, radiation parameter R, Schmidit number Sc and suction parameter w on the fluid flow, heat and mass transfer characteristic are discussed. Dual similarity solutions for the velocity, temperature and concentration profiles are obtained for some negative values of the unsteadiness parameter. It is found that the critical values of A for which the dual solution exists depend on the values of solid volume fraction parameter in the presence of the Schmidit number. Also, the magnetic field parameter as well as the mass fluid suction widen the range of A for which the solution exists. The results also indicate that momentum, thermal and concentration boundary layer thickness for the first solution are thinner than that of the second solution.

  8. Extreme Planet-Like Systems: Brown Dwarfs at the Exoplanet Mass Boundary

    NASA Astrophysics Data System (ADS)

    Faherty, Jacqueline Kelly

    2015-12-01

    Brown dwarfs have long been the observational anchors for our theoretical understanding of giant gas planets. Recent studies have uncovered a population of nearby young sources that rival the age and mass of many planetary mass companions. From detailed observations, we postulate that objects in this young population have dynamic atmospheres ripe with exotic, thick condensate cloud species that drive extreme photometric and spectroscopic characteristics. In this talk I will review how we are using these so-called exoplanet analogs to establish luminosity, temperature, age, and mass relations for brown dwarf into planetary mass objects.

  9. Measured and calculated wall temperatures on air-cooled turbine vanes with boundary layer transition

    NASA Astrophysics Data System (ADS)

    Liebert, C. H.; Gaugler, R. E.; Gladden, H. J.

    1982-11-01

    Convection cooled turbine vane metal wall temperatures experimentally obtained in a hot cascade for one vane design were compared with wall temperatures calculated with TACT1 and STAN5 computer codes which incorporated various models for predicting laminar-to-turbulent boundary layer transition. Favorable comparisons on both vane surface were obtained at high Reynolds number with only one of these transition models. When other models were used, temperature differences between calculated and experimental data obtained at the high Reynolds number were as much as 14 percent in the separation bubble region of the pressure surface. On the suction surface and at lower Reynolds number, predictions and data unsatisfactorily differed by as much as 22 percent. Temperature differences of this magnitude can represent orders of magnitude error in blade life prediction.

  10. Angularly symmetric splitting of a light beam upon reflection and refraction at an air-dielectric plane boundary.

    PubMed

    Azzam, R M A

    2015-12-01

    Conditions for achieving equal and opposite angular deflections of a light beam by reflection and refraction at an air-dielectric boundary are determined. Such angularly symmetric beam splitting (ASBS) is possible only if the angle of incidence is >60° by exactly one third of the angle of refraction. This simple law, plus Snell's law, leads to several analytical results that clarify all aspects of this phenomenon. In particular, it is shown that the intensities of the two symmetrically deflected beams can be equalized by proper choice of the prism refractive index and the azimuth of incident linearly polarized light. ASBS enables a geometrically attractive layout of optical systems that employ multiple prism beam splitters. PMID:26831398

  11. Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

    NASA Technical Reports Server (NTRS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.; Schlager, H.; Atlas, E.; Blake, D.; Coe, H.; Cohen, R. C.; Crosier, J.; Flocke, F.; Holloway, J. S.; Hopkins, J. R.; Huber, G.; McQuaid, J.; Purvis, R.; Rappengluck, B.; Ryerson, T. B.; Sachse, G. W.

    2006-01-01

    The International Consortium for Atmospheric Research on Transport and Transformation (ICARTT)-Lagrangian experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts using two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique is then used to identify Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these coincident matches is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown and the downwind minus upwind differences in tracers are discussed.

  12. Characterising terrestrial influences on Antarctic air masses using Radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-09-01

    We report on one year of high-precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late-summer to 44 mBq m-3 in late winter and early spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  13. Characterising terrestrial influences on Antarctic air masses using radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-05-01

    We report on one year of high precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late summer to 44 mBq m-3 in late-winter and early-spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  14. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    USGS Publications Warehouse

    Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

    2002-01-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  15. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    NASA Astrophysics Data System (ADS)

    Friedman, Irving; Harris, Joyce M.; Smith, George I.; Johnson, Craig A.

    2002-10-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (δD) and oxygen-18 (δ18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  16. DIRECT TRACE ANALYSIS OF VOLATILE ORGANIC COMPOUNDS IN AIR USING ION TRAP MASS SPECTROMETERS WITH FILTERED NOISE FIELDS

    EPA Science Inventory

    Two ion trap mass spectrometers and direct air sampling interfaces are being evaluated in the laboratory for monitoring toxic air pollutants in real time. he mass spectrometers are the large, laboratory-based Finnigan MAT ion trap (ITMS) and the compact, field-deployable Teledyne...

  17. Mild solutions to a measure-valued mass evolution problem with flux boundary conditions

    NASA Astrophysics Data System (ADS)

    Evers, Joep H. M.; Hille, Sander C.; Muntean, Adrian

    2015-08-01

    We investigate the well-posedness and approximation of mild solutions to a class of linear transport equations on the unit interval [ 0, 1 ] endowed with a linear discontinuous production term, formulated in the space M ([ 0, 1 ]) of finite Borel measures. Our working technique includes a detailed boundary layer analysis in terms of a semigroup representation of solutions in spaces of measures able to cope with the passage to the singular limit where thickness of the layer vanishes. We obtain not only a suitable concept of solutions to the chosen measure-valued evolution problem, but also derive convergence rates for the approximation procedure and get insight in the structure of flux boundary conditions for the limit problem.

  18. From pores to eddies - linking diffusion-based evaporative fluxes from porous surfaces with a turbulent air boundary layer

    NASA Astrophysics Data System (ADS)

    Haghighi, E.; Or, D.

    2012-04-01

    Evaporation affects hydration and energy balance of terrestrial surfaces. Evaporation rates exhibit complex dynamics reflecting interactions between external conditions and internal transport properties of a the drying porous surface Motivated by recent progress in estimating evaporative fluxes from isolated pores across laminar air sublayer, we seek to expand the description and quantify evaporation across a turbulent boundary layer. We adopt concepts from surface renewal (SR) theory focusing on turbulent exchange with individual eddies and linking eddies surface footprint and their local boundary layer over patches of a drying surface. The model resolves diffusive exchange during limited residence time and integrates fluxes over the entire surface to quantify mean evaporative fluxes from drying surfaces into turbulent airflows accounting for subsurface internal transport processes and diffusive exchanges. Input parameters and model evaluation would be based on data from spatially and temporally resolved Infrared (IR) thermography of drying surfaces under prescribe turbulent regimes conducted in a wind-tunnel experiment. The study provides basic ingredients and building blocks essential for upscaling the results to estimation of evaporative fluxes at the field and landscape scales. Keywords: Evaporation; Turbulent Coupling; Surface Renewal; Infrared Imaging.

  19. Laboratory investigations of the heat and momentum transfer in the stably stratified air turbulent boundary layer above the wavy surface

    NASA Astrophysics Data System (ADS)

    Sergeev, Daniil; Troitskaya, Yuliya; Vdovin, Maxim

    2015-04-01

    Investigation of small scale transfer processes between the ocean and atmosphere in the boundary and its parameterization on the meteorological conditions (wind and surface waves parameters) is very important for weather forecasts modeling [1]. The accuracy of the predictions taking in to account the so named bulk-formulas strongly depends on the quality empirical data. That is why the laboratory modeling sometimes is preferable (see [2]) then in situ measurements for obtaining enough ensembles of the data with a good accuracy in control conditions, first of all in a case of severe conditions (strong winds with intensive wave breaking and sprays generation). In this investigation laboratory modeling was performed on the Thermostratified Wind-Wave Channel of the IAP RAS (see. [3]). Experiments were carried out for the wind speeds up to 18.5 m/s (corresponding the equivalent 10-m wind speed 30 m/s). For the possibility of varying parameters of surface roughness independently on the wind flow a special system basing on the submerged mosquito mesh (cell of 2*2 mm) was used (see [4]). The roughness was controlled by the depth of the mesh installation under the free surface (no waves when the mesh was on the surface and maximum wave amplitude for the maximum depth). So, for each wind speed several cases of the waves parameters were investigated. During experiments a stable stratification of the boundary layer of air flow was obtained. Temperature of the heating air was 33-37 degrees (depending on the reference wind speed), and the water temperature was 14-16 degrees. The Pitote gauge and hotwire were used together for measuring velocity and temperature profiles. Also indirect estimations of the total volume of the phase of sprays were obtained by analyzing hotwire signals errors during droplets hits. Then aerodynamic drag CD and heat transfer Ch coefficients were obtained by profiling method. It was shown that that these parameters are very sensitive to the intensity of

  20. Intercomparison between satellite-derived aerosol optical thickness and PM2.5 mass: Implications for air quality studies

    NASA Astrophysics Data System (ADS)

    Wang, Jun; Christopher, Sundar A.

    2003-11-01

    We explore the relationship between column aerosol optical thickness (AOT) derived from the Moderate Resolution Imaging SpectroRadiometer (MODIS) on the Terra/Aqua satellites and hourly fine particulate mass (PM2.5) measured at the surface at seven locations in Jefferson county, Alabama for 2002. Results indicate that there is a good correlation between the satellite-derived AOT and PM2.5 (linear correlation coefficient, R = 0.7) indicating that most of the aerosols are in the well-mixed lower boundary layer during the satellite overpass times. There is excellent agreement between the monthly mean PM2.5 and MODIS AOT (R > 0.9), with maximum values during the summer months due to enhanced photolysis. The PM2.5 has a distinct diurnal signature with maxima in the early morning (6:00 ~ 8:00AM) due to increased traffic flow and restricted mixing depths during these hours. Using simple empirical linear relationships derived between the MODIS AOT and 24hr mean PM2.5 we show that the MODIS AOT can be used quantitatively to estimate air quality categories as defined by the U.S. Environmental Protection Agency (EPA) with an accuracy of more than 90% in cloud-free conditions. We discuss the factors that affect the correlation between satellite-derived AOT and PM2.5 mass, and emphasize that more research is needed before applying these methods and results over other areas.

  1. Boundary lubrication of formulated C-ethers in air to 300 C

    NASA Technical Reports Server (NTRS)

    Jones, W. R., Jr.

    1975-01-01

    Friction and wear measurements were made in dry and moist air on CVM M-50 steel lubricated with six C-ether formulations containing phosphorus ester and organic acid additives. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, 17 meter-per-minute (100 rpm) surface speed, and a 25 to 300 C disk temperature range. The C-ether base fluid and the C-ether formulations yielded lower wear than the ester under most test conditions. The C-ether formulations exhibited higher friction coefficients than the ester from 150 to 300 C and similar or lower values from 25 to 150 C.

  2. Explaining a Consistent Morning NOx Maximum in the Clean Air Forest Boundary Layer

    NASA Astrophysics Data System (ADS)

    Shepson, P. B.; Alaghmand, M.; Bertman, S. B.; Carroll, M.; Edburg, S. L.; Jobson, B. T.; Keutsch, F. N.; Lamb, B. K.; Starn, T.; Stevens, P. S.; Wallace, W.; Zhou, X.

    2010-12-01

    Measurements of nitrogen oxides (NOx) at continental surface sites have frequently revealed the presence of an early morning maximum in the NOx concentration. While this observation has most often been interpreted as the result of downward mixing associated with breakup of the nocturnal inversion, the morning NOx peak often occurs earlier than the NBL breakup. Given the importance of NOx to boundary layer photochemistry near forested environments, it is essential that this phenomenon be well understood. Here we examine a variety of measurements, including NOx measurements at various heights, during the 1998, 2001, 2008, and 2009 (CABINEX) summer intensives of the Program for Research on Oxidants: PHotochemistry, Emissions and Transport (PROPHET), at the University of Michigan Biological Station in Northern Michigan. We will discuss the results, in terms of the extent to which the observations support/refute each of the potential drivers of the morning NOx peak: 1) downward mixing, 2) photochemistry on the various surfaces present, 3) soil emissions, and 4) local and long range transport of anthropogenic NOx, and we will report on our conclusions as to the predominant/likely explanation(s) for this phenomenon.

  3. Finite-Difference Solution for Laminar or Turbulent Boundary Layer Flow over Axisymmetric Bodies with Ideal Gas, CF4, or Equilibrium Air Chemistry

    NASA Technical Reports Server (NTRS)

    Hamilton, H. Harris, II; Millman, Daniel R.; Greendyke, Robert B.

    1992-01-01

    A computer code was developed that uses an implicit finite-difference technique to solve nonsimilar, axisymmetric boundary layer equations for both laminar and turbulent flow. The code can treat ideal gases, air in chemical equilibrium, and carbon tetrafluoride (CF4), which is a useful gas for hypersonic blunt-body simulations. This is the only known boundary layer code that can treat CF4. Comparisons with experimental data have demonstrated that accurate solutions are obtained. The method should prove useful as an analysis tool for comparing calculations with wind tunnel experiments and for making calculations about flight vehicles where equilibrium air chemistry assumptions are valid.

  4. Single-particle detection efficiencies of aerosol time-of-flight mass spectrometry during the North Atlantic marine boundary layer experiment.

    PubMed

    Dall'Osto, Manuel; Harrison, Roy M; Beddows, David C S; Freney, Evelyn J; Heal, Mathew R; Donovan, Robert J

    2006-08-15

    During the North Atlantic marine boundary layer experiment (NAMBLEX) sampling campaign at Mace Head, Ireland, both continental and maritime air masses were sampled. Aerosol was characterized both with a TSI 3800 time-of-flight mass spectrometer (ATOFMS) and a MOUDI microorifice impactor, and particle number counts were measured independently with an aerodynamic particle sizer. The data have been analyzed in order to elucidate factors determining the particle detection efficiencies of the ATOFMS. These are broken down according to the efficiency of the inlet system, the hit efficiency on particles which enter the sensing zone of the instrument and the sensitivity of the measured ion signal to the chemical species. A substantial matrix effect depending on the chemical composition of the aerosol sampled at the time was found, which is reflected in variations in the hit efficiency of particles entering the sensing zone of the instrument with the main desorption-ionization laser. This is in addition to the strong inverse power-law dependence of inlet transmission efficiency on particle diameter. The variation in hit efficiency with particle type is likely attributable to differences in the energetics of laser energy absorption, ablation, and ion formation. However, once variations in both inlet transmission and hit efficiencies are taken into account, no additional matrix dependence of ATOFMS response is required to obtain a linear relationship between the ion signal and the concentration of a particular chemical species. The observations show that a constant mass of material is ionized from each particle, irrespective of size. Consequently the integrated ion signal for a given chemical component and particle size class needs to be increased by a factor related to the cube of particle diameter in order to correlate with the airborne mass of that component. PMID:16955903

  5. Study of single and combined mass-sensitive observables of cosmic ray induced extensive air showers

    NASA Astrophysics Data System (ADS)

    Rastegarzadeh, G.; Nemati, M.

    2016-03-01

    In this study, combinations of the global arrival time, (Δτ_{global}), pseudorapidity, and lateral density distribution (ρ_{μ}) of muons, which are three mass-sensitive observables of cosmic ray induced extensive air showers, have been used as new parameters to study the primary mass discrimination around the knee energies (100 TeV-10 PeV). This is a simulation-based study and the simulations have been performed for the KASCADE array at Karlsruhe and the Alborz-I array at Tehran to study the effect of the altitude on the quality of the primary mass discrimination. The merit factors of the single and combined three mass-sensitive observables have been calculated to compare the discrimination power of combined and single observables. We have used the CORSIKA 7.4 code to simulate the extensive air showers (EASs) sample sets. Considering all aspects of our study, it is found that the ratio of the global time to the lateral density distribution of the muons gives better results than other ratios; also in the case of single observables, the muon density gives better results compared with the other observables. Also it is shown that below 1 PeV primary energies, the ratio of the muon global time to the muon density (Δτ_{global}/ρ_{μ}) results in a better mass discrimination relative to the muon density only.

  6. Dynamics of the flammable plumes resulting from the convective dispersion of a fixed mass of the buoyant gaseous fuel, methane, into air.

    PubMed

    Fardisi, S; Karim, Ghazi A

    2009-08-15

    The dynamics of the dispersion of a fixed mass of the buoyant fuel, methane, when exposed with a negligible pressure difference to overlaying air within vertical cylindrical enclosures open to the atmosphere is investigated. Features of the formation and dispersion of flammable mixtures created by the gas dissipation were examined using a 3D CFD model. For the cases considered, the lean-flammable mixture boundary appears to travel mainly at a near constant rate while the rich limit front shows a more chaotic behaviour. The corresponding simulation using an axis-symmetrical 2D model tended to under-predict the dynamics of the lean and rich boundaries, for the cases considered. PMID:19237243

  7. Enhancement of acidic gases in biomass burning impacted air masses over Canada

    NASA Technical Reports Server (NTRS)

    Lefer, B. L.; Talbot, R. W.; Harriss, R. C.; Bradshaw, J. D.; Sandholm, S. T.; Olson, J. O.; Sachse, G. W.; Collins, J.; Shipham, M. A.; Blake, D. R.

    1994-01-01

    Biomass-burning impacted air masses sampled over central and eastern Canada during the summer of 1990 as part of ABLE 3B contained enhanced mixing ratios of gaseous HNO3, HCOOH, CH3COOH, and what appears to be (COOH)2. These aircraft-based samples were collected from a variety of fresh burning plumes and more aged haze layers from different source regions. Values of the enhancement factor, delta X/delta CO, where X represents an acidic gas, for combustion-impacted air masses sampled both near and farther away from the fires, were relatively uniform. However, comparison of carboxylic acid emission ratios measured in laboratory fires to field plume enhancement factors indicates significant in-plume production of HCOOH. Biomass-burning appears to be an important source of HNO3, HCOOH, and CH3COOH to the troposphere over subarctic Canada.

  8. A mass balance method for non-intrusive measurements of surface-air trace gas exchange

    NASA Astrophysics Data System (ADS)

    Denmead, O. T.; Harper, L. A.; Freney, J. R.; Griffith, D. W. T.; Leuning, R.; Sharpe, R. R.

    A mass balance method is described for calculating gas production from a surface or volume source in a small test plot from measurements of differences in the horizontal fluxes of the gas across upwind and downwind boundaries. It employs a square plot, 24 m×24 m, with measurements of gas concentration at four heights (up to 3.5 m) along each of the four boundaries. Gas concentrations are multiplied by the appropriate vector winds to yield the horizontal fluxes at each height on each boundary. The difference between these fluxes integrated over downwind and upwind boundaries represents production. Illustrations of the method, which involve exchanges of methane and carbon dioxide, are drawn from experiments with landfills, pastures and grazing animals. Tests included calculation of recovery rates from known gas releases and comparisons with a conventional micrometeorological approach and a backward dispersion model. The method performed satisfactorily in all cases. Its sensitivity for measuring exchanges of CO 2, CH 4 and N 2O in various scenarios was examined. As employed by us, the mass balance method can suffer from errors arising from the large number of gas analyses required for a flux determination, and becomes unreliable when there are light winds and variable wind directions. On the other hand, it is non-disturbing, has a simple theoretical basis, is independent of atmospheric stability or the shape of the wind profile, and is appropriate for flux measurement in situations where conventional micrometeorological methods can not be used, e.g. for small plots, elevated point sources, and heterogeneous surface sources.

  9. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  10. Ozone in the Boundary Layer air over the Arctic Ocean - measurements during the TARA expedition

    NASA Astrophysics Data System (ADS)

    Bottenheim, J. W.; Netcheva, S.; Morin, S.; Nghiem, S. V.

    2009-03-01

    A full year of measurements of surface ozone over the Arctic Ocean far removed from land is presented (81° N - 88° N latitude). The data were obtained during the drift of the French schooner TARA between September 2006 and January 2008, while frozen in the Arctic Ocean. The data confirm that long periods of virtually total absence of ozone occur in the spring (mid March to mid June) after Polar sunrise. At other times of the year ozone concentrations are comparable to other oceanic observations with winter mole fractions of ca. 30-40 nmol mol-1 and summer minima of ca. 20 nmol mol-1. Contrary to earlier observations from ozone sonde data obtained at Arctic coastal observatories, the ambient temperature was well above -20°C during most ODEs (ozone depletion episodes). Backwards trajectory calculations suggest that during these ODEs the air had previously been in contact with the frozen ocean surface for several days and originated largely from the Siberian coast where several large open flaw leads developed in the spring of 2007.

  11. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    NASA Astrophysics Data System (ADS)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  12. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  13. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    NASA Astrophysics Data System (ADS)

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-04-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2‑ and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios.

  14. Analysis of air mass trajectories in the northern plateau of the Iberian Peninsula

    NASA Astrophysics Data System (ADS)

    Pérez, Isidro A.; Sánchez, M. Luisa; García, M. Ángeles; Pardo, Nuria

    2015-11-01

    Air masses reaching the Iberian Peninsula, which is located between two continents and two seas, have been classified. 24-h backward air trajectories were calculated each hour for three years using the METEX model at a site in the centre of the northern plateau of the Iberian Peninsula where the air flow has scarcely been investigated to date. Rather than the usual Euclidean geometry, spherical trigonometry, together with the kernel regression method, was considered to calculate trajectory distances to the site. Numerical indicators allow for an accurate description of the results. Ranges surrounding the site from E to S evidenced a restriction in the movement of the arriving flow. However, the range to the N showed only a slight effect. A noticeable seasonal contrast was observed between winter, whose distances were the greatest, and summer, which displayed the shortest distances. Trajectory clusters, initially not considered in the METEX model, were obtained with different metrics to determine the air mass pathways reaching the site. Five clusters of trajectories were selected so as to easily explain the directions and distances covered. Regional and long range transport were observed in clusters from the NE, NW and SW. The NE cluster presented an orographic deviation and local processes were limited to the SE cluster. Finally, seasonal analysis revealed singular behaviour during autumn, when local processes centred on the N-S direction.

  15. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways.

    PubMed

    Liu, D X; Liu, Z C; Chen, C; Yang, A J; Li, D; Rong, M Z; Chen, H L; Kong, M G

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H(+), nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2(-) and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  16. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    NASA Technical Reports Server (NTRS)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  17. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    PubMed Central

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2− and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  18. Effects of tangential-type boundary condition discontinuities on the accuracy of the lattice Boltzmann method for heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Li, Like; AuYeung, Nick; Mei, Renwei; Klausner, James F.

    2016-08-01

    We present a systematic study on the effects of tangential-type boundary condition discontinuities on the accuracy of the lattice Boltzmann equation (LBE) method for Dirichlet and Neumann problems in heat and mass transfer modeling. The second-order accurate boundary condition treatments for continuous Dirichlet and Neumann problems are directly implemented for the corresponding discontinuous boundary conditions. Results from three numerical tests, including both straight and curved boundaries, are presented to show the accuracy and order of convergence of the LBE computations. Detailed error assessments are conducted for the interior temperature or concentration (denoted as a scalar ϕ) and the interior derivatives of ϕ for both types of boundary conditions, for the boundary flux in the Dirichlet problem and for the boundary ϕ values in the Neumann problem. When the discontinuity point on the straight boundary is placed at the center of the unit lattice in the Dirichlet problem, it yields only first-order accuracy for the interior distribution of ϕ, first-order accuracy for the boundary flux, and zeroth-order accuracy for the interior derivatives compared with the second-order accuracy of all quantities of interest for continuous boundary conditions. On the lattice scale, the LBE solution for the interior derivatives near the singularity is largely independent of the resolution and correspondingly the local distribution of the absolute errors is almost invariant with the changing resolution. For Neumann problems, when the discontinuity is placed at the lattice center, second-order accuracy is preserved for the interior distribution of ϕ; and a "superlinear" convergence order of 1.5 for the boundary ϕ values and first-order accuracy for the interior derivatives are obtained. For straight boundaries with the discontinuity point arbitrarily placed within the lattice and curved boundaries, the boundary flux becomes zeroth-order accurate for Dirichlet problems

  19. Influence of the added mass effect and boundary conditions on the dynamic response of submerged and confined structures

    NASA Astrophysics Data System (ADS)

    Valentín, D.; Presas, A.; Egusquiza, E.; Valero, C.

    2014-03-01

    The dynamic response of submerged and confined disk-like structures is of interest in the flied of hydraulic machinery, especially in hydraulic turbine runners. This response is difficult to be estimated with accuracy due to the strong influence of the boundary conditions. Small radial gaps as well as short axial distances to rigid surfaces greatly modify the dynamic response because the fact of the added mass and damping effects. Moreover, the effect of the shaft coupling is also important for certain mode-shapes of the structure. In the present study, the influence of the added mass effect and boundary conditions on the dynamic behavior of a submerged disk attached to a shaft is evaluated through experimental tests and structural- acoustic coupling numerical simulations. For the experimentation, a test rig has been developed. It consists of a confined disk attached to a shaft inside a cylindrical container full of water. The disk can be fixed at different axial positions along the shaft. Piezoelectric patches are used to excite the disk and the response is measured with submersible accelerometers. For each configuration tested, the natural frequencies of the disk and the shaft are studied. Numerical results have been compared with experimental results.

  20. Determination of structural domain boundaries in jointed rock masses: An example from the Songta dam site, China

    NASA Astrophysics Data System (ADS)

    Li, Yanyan; Wang, Qing; Chen, Jianping; Han, Lili; Zhang, Wen; Ruan, Yunkai

    2014-12-01

    This paper presents an application of the Kolmogorov-Smirnov and Wilcoxon rank sum nonparametric statistical tests for identifying structural domain boundaries in jointed rock masses. In the method, the upper hemispherical surface is divided into 100 nearly equal-area windows. The similarity between two samples of joint orientations is measured by comparing the frequencies or the number of joint poles occurring in the windows. Over 2400 joints collected from 8 adjacent exploration tunnels at the Songta dam site in southwest China are used to demonstrate the method. By applying the technique to the study area, structural domain boundaries in the rock mass are determined. Our results suggest that the study area, with an area of approximately 17,850 m2, can be classified into four structural domains. However, the traditional method with the correlation coefficient fails to reveal the structural changes. Since the correlation coefficient is only a measure of strength of the linear relation between two samples, it has limitations in measuring the similarity between joint orientation distributions. A comparison between the proposed method and previous methods indicates that the new technique could provide more reliable results. Besides, the new method can be applied to structural populations with small sample sizes.

  1. The marine boundary layer - new findings from the Östergarnsholm air-sea interaction site

    NASA Astrophysics Data System (ADS)

    Smedman, A.; Högström, U.

    2003-04-01

    From studies at the air-sea interaction site Östergarnsholm, a coherent picture of how waves interact with the atmosphere is now beginning to emerge. It is clear that the surface of the ocean behaves similar to that of a solid surface with regard to the turbulence structure in the surface layer only for conditions of pure wind sea, i.e. during the phase when waves are in the process of being built up by increasing wind. At that stage of wave development, the dominant waves are short and move slowly relative to the wind. Then the drag coefficient CDN is a function only of the wave age, expressed as u*/c_p (where u* is friction velocity and c_p is the phase velocity of the dominant waves). The relation obtained by us is identical to the corresponding expression obtained from several recent ocean experiments, Drennan et al. (2000). As soon as the wave field develops behind the "pure wind sea" stage towards conditions where relatively long waves start to gain importance, inter-actions caused by these longer waves are felt in the atmosphere at our lowest turbulence measuring height, 10 m. For example it is demonstrated that the logarithmic wind law is not valid in near-neutral conditions except when pure wind sea conditions prevail and, further that for mixed seas and swell conditions, CDN is a function not only of the wave age parameter u*/c_p but also of a second wave parameter E_1/E_2, which is a measure of the proportion of energy of relatively long waves to short waves. The neutral Stanton Number, CHN, is found to follow predictions from surface-renewal theory quite well for unstable conditions up to a wind speed of about 10 ms-1. For higher wind speed CHN increases with increasing wind speed and the interpretation is made that spray is the cause of the increase.

  2. Microwave and Electro-optical Transmission Experiments in the air-sea Boundary Layer

    NASA Astrophysics Data System (ADS)

    Anderson, K. D.

    2002-12-01

    , deployment, operation, and recovery of R/P FLIP. These problems ranged from the U.S.N.S. Sioux cutting a mooring line, which delayed deployment by more than 4 days, nearly loosing Tommy during the first attempt at deployment, inadequate air conditioning in the lab spaces, causing at least one instrument to temporarily fail, and problems associated with too many people and too many sensors on board. These issues will be discussed and recommendations will be made to improve future microwave and electro-optical experiments at sea.

  3. Heat and mass transfer at a free surface with diabatic boundaries in a single-species system under microgravity conditions

    NASA Astrophysics Data System (ADS)

    Fuhrmann, Eckart; Dreyer, Michael E.

    2014-06-01

    In this paper, we analyzed the heat and mass transfer at a free surface under microgravity conditions. The SOURCE-II (Sounding Rocket COMPERE Experiment) experiment was performed on a suborbital flight in February 2012 from Esrange in North Sweden. It provided representative data with respect to solid, liquid, and vapor temperatures as well as the visible surface position. The objectives were to quantify the deformation of the free liquid surface and to correlate the apparent contact angle to a characteristic temperature difference between subcooled liquid and superheated wall. Furthermore, the influence of evaporation and condensation at the liquid/vapor interface and at the superheated wall must be taken into account to analyze heat and mass fluxes due to a characteristic temperature difference. In the following, we show evidently that the magnitude of the apparent contact angle depends on the exerted specific pressurizations of the vapor phase during the experiment and hence on the change in the saturation temperature at the free surface. The characteristic temperature difference is defined with respect to the wall temperature in the vicinity of the contact line and the saturation temperature. Therefore, apparent contact angle and temperature difference can be correlated and indicate a specific characteristic. Concerning the heat and mass transfer at the free liquid surface and the contact line, two different methods are presented to evaluate the net mass due to phase change within a certain time interval. In the first approach, the mass flow rate is calculated by means of the ideal gas law and its derivatives with respect to temperature and pressure. The second approach calculates the heat flux as well as the mass flux at the wall and in the region of the free liquid surface. In these cases, a specific heat transfer coefficient and a thermal boundary layer thickness are used.

  4. Physical and chemical processes of air masses in the Aegean Sea during Etesians: Aegean-GAME airborne campaign.

    PubMed

    Tombrou, M; Bossioli, E; Kalogiros, J; Allan, J D; Bacak, A; Biskos, G; Coe, H; Dandou, A; Kouvarakis, G; Mihalopoulos, N; Percival, C J; Protonotariou, A P; Szabó-Takács, B

    2015-02-15

    High-resolution measurements of gas and aerosols' chemical composition along with meteorological and turbulence parameters were performed over the Aegean Sea (AS) during an Etesian outbreak in the framework of the Aegean-GAME airborne campaign. This study focuses on two distinct Etesian patterns, with similarities inside the Marine Atmospheric Boundary Layer (MABL) and differences at higher levels. Under long-range transport and subsidence the pollution load is enhanced (by 17% for CO, 11% for O3, 28% for sulfate, 62% for organic mass, 47% for elemental carbon), compared to the pattern with a weaker synoptic system. Sea surface temperature (SST) was a critical parameter for the MABL structure, turbulent fluxes and pollutants' distribution at lower levels. The MABL height was below 500 m asl over the eastern AS (favoring higher accumulation), and deeper over the western AS. The most abundant components of total PM1 were sulfate (40-50%) and organics (30-45%). Higher average concentrations measured over the eastern AS (131 ± 76 ppbv for CO, 62.5 ± 4.1 ppbv for O3, 5.0 ± 1.1 μg m(-3) for sulfate, 4.7 ± 0.9 μg m(-3) for organic mass and 0.5 ± 0.2 μg m(-3) for elemental carbon). Under the weaker synoptic system, cleaner but more acidic air masses prevailed over the eastern part, while distinct aerosol layers of different signature were observed over the western part. The Aitken and accumulation modes contributed equally during the long-range transport, while the Aitken modes dominated during local or medium range transport. PMID:25460953

  5. Mass extinctions, atmospheric sulphur and climatic warming at the K/T boundary

    NASA Technical Reports Server (NTRS)

    Rampino, Michael R.; Volk, Tyler

    1988-01-01

    The possible climatic effects of a drastic decrease in cloud condensation nuclei (CCN) associated with a severe reduction in the global marine phytoplankton abundance are investigated. Calculations suggest that a reduction in CCN of more than 80 percent and the resulting decrease in marine cloud albedo could have produced a rapid global warming of 6 C or more. Oxygen isotope analyses of marine sediments from many parts of the world have been interpreted as indicating a marked warming coincident with the demise of calcareous nannoplankton at the K/T boundary. Decreased marine cloud albedo and resulting high sea surface temperatures could have been a factor in the maintenance of low productivity in the 'Strangelove Ocean' period following the K/T extinctions.

  6. Recent trends of persistent organic pollutants in air in central Europe - Air monitoring in combination with air mass trajectory statistics as a tool to study the effectivity of regional chemical policy

    NASA Astrophysics Data System (ADS)

    Dvorská, A.; Lammel, G.; Holoubek, I.

    We use air mass back trajectory analysis of persistent organic pollutant (POP) levels monitored at a regional background site, Košetice, Czech Republic, as a tool to study the effectiveness of emission reduction measures taken in the last decade in the region. The representativity of the chosen trajectory starting height for air sampling near ground was ensured by excluding trajectories starting at time of inversions lower than their starting height. As the relevant pollutant sources are exclusively located in the atmospheric boundary layer, trajectory segments above this layer were also excluded from the analysis. We used a linear time weight to account for the influence of dispersion and deposition on trace components abundances and to quantify the ground source loading, a continuous measure for the influence of surface emissions. Hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), DDT, and two time periods, the years 1997-1999 and 2004-2006, were studied. The pollutant levels transported to Košetice decreased for all substances except HCB. Except for lindane seasonal emissions were insignificant. Increasing emissions of HCB were at least partly linked to the 2002 floods in the Danube basin. Major emissions of 1997-1999 which decreased significantly were in France (lindane), western Poland, Hungary and northern ex-Yugoslavia (technical HCH), and the Czech Republic (DDT). Emissions remaining in 2004-2006 include HCB and DDT in the northern Czech Republic, HCB and PCBs in Germany. Besides changes in emission strength meteorological factors influence the level of transported pollutant concentrations. The prevailing air flow pattern limits the geographic coverage of this analysis to central Europe and parts of western Europe. However, no POP monitoring stations exist in areas suitable for a possible extension of the study area.

  7. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2015-12-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  8. Measurements of CO in an aircraft experiment and their correlation with biomass burning and air mass origin in South America

    NASA Astrophysics Data System (ADS)

    Boian, C.; Kirchhoff, V. W. J. H.

    Carbon monoxide (CO) measurements are obtained in an aircraft experiment during 1-7 September 2000, conducted over Central Brazil in a special region of anticyclonic circulation. This is a typical transport regime during the dry season (July-September), when intense biomass burning occurs, and which gives origin to the transport of burning poluents from the source to distant regions. This aircraft experiment included in situ measurements of CO concentrations in three different scenarios: (1) areas of fresh biomass burning air masses, or source areas; (2) areas of aged biomass burning air masses; and (3) areas of clean air or pristine air masses. The largest CO concentrations were of the order of 450 ppbv in the source region near Conceicao do Araguaia (PA), and the smallest value near 100 ppbv, was found in pristine air masses, for example, near the northeast coastline (clean air, or background region). The observed concentrations were compared to the number of fire pixels seen by the AVHRR satellite instrument. Backward isentropic trajectories were used to determine the origin of the air masses at each sampling point. From the association of the observed CO mixing ratios, fire pixels and air mass trajectories, the previous scenarios may be subdivided as follows: (1a) source regions of biomass burning with large CO concentrations; (1b) regions with few local fire pixels and absence of contributions by transport. Areas with these characteristics include the northeast region of Brazil; (1c) regions close to the source region and strongly affected by transport (region of Para and Amazonas); (2) regions that have a consistent convergence of air masses, that have traveled over biomass burning areas during a few days (western part of the Cerrado region); (3a) Pristine air masses with origin from the ocean; (3b) regions with convergent transport that has passed over areas of no biomass burning, such as frontal weather systems in the southern regions.

  9. Combustion of a Methane-Air Mixture in a Slot Burner with an Inert Insert in Mass Transfer to the Environment

    NASA Astrophysics Data System (ADS)

    Krainov, A. Yu.; Moiseeva, K. M.

    2016-03-01

    A problem on combustion of a methane-air mixture in a slot burner with an internal insert in mass transfer from the burner's exterior wall to the environment has been solved. A mathematical formulation of the problem takes account of the dependence of the diffusion, thermal-conductivity, and heat-transfer coefficients on temperature, and also of the heat removal from the gas to the environment by convective and radiant heat transfer. A numerical investigation has been carried out in a one-dimensional mathematical formulation of the problem in dimensional variables. The boundary of existence of a stable high-temperature regime of combustion of the methane-air mixture has been determined as a function of the rate of feed of the gas, the environmental temperature, and the width of the flow area of the burner.

  10. Smart tetroons for Lagrangian air-mass tracking during ACE 1

    NASA Astrophysics Data System (ADS)

    Businger, Steven; Johnson, Randy; Katzfey, Jack; Siems, Steven; Wang, Qing

    1999-05-01

    A series of "smart" tetroons was released from shipboard during the recent ACE 1 field experiment designed to monitor changes in the sulfur budget in a remote marine boundary layer (MBL) south of Tasmania, Australia. The smart tetroons were designed at NOAA Air Resources Laboratory Field Research Division to provide air parcel tracking information. The adjective smart here refers here to the fact that the buoyancy of the tetroons automatically adjusts through the action of a pump and valves when the tetroon travels vertically outside a range of pressures set prior to tetroon release. The smart tetroon design provides GPS location, barometric pressure, temperature, relative humidity, and tetroon status data via a transponder to the NCAR C-130 research aircraft flying in the vicinity of the tetroons. In this paper we will describe (1) the design and capability of the smart tetroons and their performance during the two Lagrangian experiments conducted during ACE 1, (2) the synoptic context of the Lagrangians, including the origin of the air parcels being tracked, and (3) the results of trajectory predictions derived from the National Center for Environmental Prediction (NCEP) Global Spectral Model (GSM) and Australia's Commonwealth Scientific and Industrial Research Organization (CSIRO) Division of Atmospheric Research (DAR) limited-area model.

  11. The relation between air pollution data and planetary boundary layer quantities in a complex coastal industrial site nearby populated areas.

    NASA Astrophysics Data System (ADS)

    Mammarella, M. C.; Grandoni, G.; Fernando, J.; Cacciani, M.; di Sabatino, S.; Favaron, M.; Fedele, P.

    2010-09-01

    The connection among boundary layer phenomena, atmospheric pollutant dynamics and human health is an established fact, taking many different forms depending on local characteristics, including slope and position of relief and/or coastline, surface roughness, emission patterns. The problem is especially interesting in complex and coastal terrain, where concurrence of slope and sea induced local circulation interact reciprocally, yielding a complex pattern whose interpretation may go beyond pure modeling, and devise specific measurements among which the planetary boundary layer (PBL) height. An occasion for studying this important theme has been offered by Regione Molise and Valle del Biferno Consortium (COSIB), for the specific case of the industrial complex of Valle del Biferno, 3 km inland of Termoli, in Central Italy, on the Adriatic coast. The local government, sensitive to air quality and public health in the industrial area, together with COSIB has co-financed a research project aimed at gaining knowledge about local meteorology, PBL phenomena and atmospheric pollutant dispersion in the area. Expected results include new air quality monitoring and control methodologies in Valle del Biferno for a sustainable development in an environmentally respectful manner, at a site already characterized by a high environmental and landscape value. The research project, developed by ENEA, has began in 2007 and will conclude in December 2010. Project activities involve research group from Europe, the United States of America, and the Russian Federation. Scientific and practical results will be published and presented in occasion of the final workshop to be held on project conclusion. The scientific interest of Valle del Biferno case stems from the specific local characteristics at site. Given the valley orientation respect to mean synoptic circulation, local effects as sea and slope breezes are dominant, and a complex wind regime develops affecting local transport and

  12. An upper boundary in the mass-metallicity plane of exo-Neptunes

    NASA Astrophysics Data System (ADS)

    Courcol, Bastien; Bouchy, François; Deleuil, Magali

    2016-09-01

    With the progress of detection techniques, the number of low-mass and small-size exoplanets is increasing rapidly. However their characteristics and formation mechanisms are not yet fully understood. The metallicity of the host star is a critical parameter in such processes and can impact the occurrence rate or physical properties of these planets. While a frequency-metallicity correlation has been found for giant planets, this is still an ongoing debate for their smaller counterparts. Using the published parameters of a sample of 157 exoplanets lighter than 40 M⊕, we explore the mass-metallicity space of Neptunes and super-Earths. We show the existence of a maximal mass that increases with metallicity, that also depends on the period of these planets. This seems to favour in situ formation or alternatively a metallicity-driven migration mechanism. It also suggests that the frequency of Neptunes (between 10 and 40 M⊕) is, like giant planets, correlated with the host star metallicity, whereas no correlation is found for super-Earths (<10 M⊕).

  13. An upper boundary in the mass-metallicity plane of exo-Neptunes

    NASA Astrophysics Data System (ADS)

    Courcol, Bastien; Bouchy, François; Deleuil, Magali

    2016-05-01

    With the progress of detection techniques, the number of low-mass and small-size exoplanets is increasing rapidly. However their characteristics and formation mechanisms are not yet fully understood. The metallicity of the host star is a critical parameter in such processes and can impact the occurence rate or physical properties of these planets. While a frequency-metallicity correlation has been found for giant planets, this is still an ongoing debate for their smaller counterparts. Using the published parameters of a sample of 157 exoplanets lighter than 40 M⊕, we explore the mass-metallicity space of Neptunes and Super-Earths. We show the existence of a maximal mass that increases with metallicity, that also depends on the period of these planets. This seems to favor in situ formation or alternatively a metallicity-driven migration mechanism. It also suggests that the frequency of Neptunes (between 10 and 40 M⊕) is, like giant planets, correlated with the host star metallicity, whereas no correlation is found for Super-Earths (<10 M⊕).

  14. Modeling of Trans-boundary Transport of Air Pollutants in the California-Mexico Border Region during Cal-Mex 2010

    NASA Astrophysics Data System (ADS)

    Bei, N.; Zavala, M. A.; Lei, W.; Li, G.; Molina, L. T.

    2010-12-01

    The US and Mexico share a common air basin along the ~200 km border between California and Baja California. The economical activities in this region are heavily influenced by the international trade and commerce between Mexico and the US that mainly occurs through the borders of the sister cities of San Diego-Tijuana and Calexico-Mexicali. The diversity and differences in the characteristics of emissions sources of air pollutants in the California-Mexico border region make this an important area for the study of the chemistry and trans-boundary transport of air pollutants. During May-June of 2010, the Cal-Mex 2010 field campaign included a series of measurements aimed at characterizing the emissions from major sources in the California-Mexico border region and assessing the possible impacts of these emissions on local and regional air quality. In this work we will present the results of the use of the Comprehensive Air quality model with extensions (CAMx) in a modeling domain that includes the sister cities of San Diego-Tijuana and Calexico-Mexicali for studying events of trans-boundary transport of air pollutants during Cal-Mex 2010. The measurements obtained during the Cal-Mex 2010 field campaign are used in the evaluation of the model performance and in the design of air quality improvement policies in the California-Mexico border region.

  15. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  16. Octopods: Nude ammonoids that survived the Cretaceous-Tertiary boundary mass extinction

    NASA Astrophysics Data System (ADS)

    Lewy, Z.

    1996-07-01

    Certain ammonoids changed the mode of coiling or the growth angle of their last body chamber, constricted the terminal aperture, or developed apertural processes, which restricted all life functions. The modified terminal body chamber of macroconchs apparently functioned as a floating egg case for a single breeding phase. The young that hatched from tiny eggs fed on the enclosed female corpse. This same breeding strategy is executed by the extant octopod Argonauta. As a nude cephalopod, the sexually mature female secretes an egg case, which resembles Cretaceous ammonites, for the tiny eggs. The remarkable similarity in mode of breeding between Argonauta and ammonoids with modified terminal body chambers suggests that the ancestral argonautid was a nude ammonoid. Other octopods, which lay large, yolk-rich eggs attached onto substrates, likewise originate from ancestral nude ammonoids, which, however, did not breed in a floating egg case. Nude ammonoids crossed the Cretaceous-Tertiary boundary, as did the genuine coleoids comprising rudimentary endoskeletons.

  17. Influence of air mass origin on aerosol properties at a remote Michigan forest site

    NASA Astrophysics Data System (ADS)

    VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; Pressley, S. N.; Erickson, M. H.; Jobson, B. T.; Lamb, B. K.

    2015-04-01

    The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere-Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ∼60% of the study period, air was transported from sparsely populated regions to the northwest. During these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm-3 and 1.91 μm3 cm-3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (∼29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean k = 0.24 at s = 0.3%). These trends are have the potential to influence forest-atmosphere interactions and should be targeted for future study.

  18. A multivariate/chemical mass balance model for air pollution in China: A hybrid methodology

    SciTech Connect

    Zelenka, M.P.

    1992-01-01

    This research explores the possibility of using a two step method of identifying and quantifying air pollution emissions in an urban environment. The procedure uses a mathematical model called Target Transformation Factor Analysis (TTFA) to estimate source profiles using ambient trace element air concentration data. A source profile is analogous to a fingerprint since it is unique to each source of air pollution. It is important to use source profiles that are measured or estimated for the specific location under study. The profiles estimated by TTFA are then employed in a Chemical Mass Balance (CMB) source apportionment analysis for the airshed. Other known sources are estimated using source signatures from the literature. Applying the TTFA and CMB models in this fashion is called receptor modeling. Generically, a receptor model is the combination of measured air pollution concentration data with a numerical technique which apportions the measured air pollution among distinct source types. The results show that TTFA can be used to provide quantitative estimates of air pollution source profiles for an urban center in China. The number of profiles for unique source types was limited for this data set since emissions from certain types of sources co-varied during each sampling day. Consequently, the CMB analyses that applied the TTFA source profiles needed to be supplemented with standard US EPA source profiles. The application of TTFA for estimating source profiles from ambient data and the subsequent use of those profiles in CMB analyses with source profiles obtained from the EPA's source library can improve the statistical quality of the source apportionment analysis. TTFA can identify source categories of airborne pollution for specific cities, as well as give quantitative data on the composition of the emissions from those source types.

  19. Effect of the relative optical air mass and the clearness index on solar erythemal UV irradiance.

    PubMed

    Moreno, J C; Serrano, M A; Cañada, J; Gurrea, G; Utrillas, M P

    2014-09-01

    This paper analyses the effects of the clearness index (Kt) and the relative optical air mass (mr) on erythemal UV irradiance (UVER). The UVER measurements were made in Valencia (Spain) from 6:00 am to 6:00 pm between June 2003 and December 2012 and (140,000 data points). Firstly, two models were used to calculate values for the erythemal ultraviolet irradiance clearness index (KtUVER) as a function of the global irradiance clearness index (Kt). Secondly, a potential regression model to measure the KtUVER as a function of the relative optical air mass was studied. The coefficients of this regression were evaluated for clear and cloudy days, as well as for days with high and low ozone levels. Thirdly, an analysis was made of the relationship between the two effects in the experimental database, with it being found that the highest degree of agreement, or the joint highest frequencies, are located in the optical mass range mr∈[1.0, 1.2] and the clearness index range of Kt∈[0.8, 1.0]. This is useful for establishing the ranges of parameters where models are more efficient. Simple equations have been tested that can provide additional information for the engineering projects concerning thermal installations. Fourthly, a high dispersion of radiation data was observed for intermediate values of the clearness for UV and UVER. PMID:24911276

  20. Calibration of Dissolved Noble Gas Mass Spectrometric Measurements by an Air-Water Equilibration System

    NASA Astrophysics Data System (ADS)

    Hillegonds, Darren; Matsumoto, Takuya; Jaklitsch, Manfred; Han, Liang-Feng; Klaus, Philipp; Wassenaar, Leonard; Aggarwal, Pradeep

    2013-04-01

    Precise measurements by mass spectrometry of dissolved noble gases (He, Ar, Ne, Kr, Xe) in water samples require careful calibration against laboratory standards with known concentrations. Currently, air pipettes are used for day-to-day calibrations, making estimation of overall analytical uncertainties for dissolved noble gas measurements in water difficult. Air equilibrated water (AEW) is often used as a matrix-equivalent laboratory standard for dissolved gases in groundwater, because of the well-known and constant fractions of noble gases in the atmosphere. AEW standards, however, are only useful if the temperature and pressure of the gas-water equilibrium can be controlled and measured precisely (i.e., to better than 0.5%); contamination and partial sample degassing must also be prevented during sampling. Here we present the details of a new custom air-water equilibration system which consists of an insulated 600 liter tank filled with deionized water, held isothermally at a precise target temperature (<0.05 °C) through the use of a heat exchanger. The temperature and total dissolved gas of the water in the tank are monitored continually, as are atmospheric pressure and air temperature in the laboratory. Different noble gas concentration standards can be reliably produced by accurately controlling the water temperature of the equilibration system. Equilibration characteristics and reproducibility of this system for production of copper tubes containing known amounts of noble gases will be presented.

  1. Locking, mass flux and topographic response at convergent plate boundaries - the Chilean case

    NASA Astrophysics Data System (ADS)

    Oncken, Onno

    2016-04-01

    On the long term, convergent plate boundaries have been shown to be controlled by either accretion/underplating or by subduction erosion. Vertical surface motion is coupled to convergence rate - typically with an uplift rate of the coastal area ranging from 0 to +50% of convergence rate in accretive systems, and -20 to +30% in erosive systems. Vertical kinematics, however, are not necessarily linked to horizontal strain mode, i.e. upper plate shortening or extension, in a simple way. This range of kinematic behaviors - as well as their acceleration where forearcs collide with oceanic ridges/plateau - is well expressed along the Chilean plate margin. Towards the short end of the time scale, deformation appears to exhibit a close correlation with the frictional properties and geodetic locking at the plate interface. Corroborating analogue experiments of strain accumulation during multiple earthquake cycles, forearc deformation and uplift focus above the downdip and updip end of seismic coupling and slip and are each related to a particular stage of the seismic cycle, but with opposite trends for both domains. Similarly, barriers separating locked domains along strike appear to accumulate most upper plate faulting interseismically. Hence, locking patters are reflected in topography. From the long-term memory contained in the forearc topography the relief of the Chilean forearc seems to reflect long term stability of the observed heterogeneity of locking at the plate interface. This has fundamental implications for spatial and temporal distribution of seismic hazard. Finally, the nature of locking at the plate interface controlling the above kinematic behavior appears to be strongly controlled by the degree of fluid overpressuring at the plate interface suggesting that the hydraulic system at the interface takes a key role for the forearc response.

  2. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction

    PubMed Central

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-01-01

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid–high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years. PMID:27414998

  3. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction.

    PubMed

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-01-01

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid-high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years. PMID:27414998

  4. Global climate change driven by soot at the K-Pg boundary as the cause of the mass extinction

    NASA Astrophysics Data System (ADS)

    Kaiho, Kunio; Oshima, Naga; Adachi, Kouji; Adachi, Yukimasa; Mizukami, Takuya; Fujibayashi, Megumu; Saito, Ryosuke

    2016-07-01

    The mass extinction of life 66 million years ago at the Cretaceous/Paleogene boundary, marked by the extinctions of dinosaurs and shallow marine organisms, is important because it led to the macroevolution of mammals and appearance of humans. The current hypothesis for the extinction is that an asteroid impact in present-day Mexico formed condensed aerosols in the stratosphere, which caused the cessation of photosynthesis and global near-freezing conditions. Here, we show that the stratospheric aerosols did not induce darkness that resulted in milder cooling than previously thought. We propose a new hypothesis that latitude-dependent climate changes caused by massive stratospheric soot explain the known mortality and survival on land and in oceans at the Cretaceous/Paleogene boundary. The stratospheric soot was ejected from the oil-rich area by the asteroid impact and was spread globally. The soot aerosols caused sufficiently colder climates at mid–high latitudes and drought with milder cooling at low latitudes on land, in addition to causing limited cessation of photosynthesis in global oceans within a few months to two years after the impact, followed by surface-water cooling in global oceans in a few years. The rapid climate change induced terrestrial extinctions followed by marine extinctions over several years.

  5. Changes in environmental conditions as the cause of the marine biota Great Mass Extinction at the Triassic-Jurassic boundary

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2016-02-01

    In the interval of the Triassic-Jurassic boundary, 80% of the marine species became extinct. Four main hypotheses about the causes of this mass extinction are considered: volcanism, climatic oscillations, sea level variations accompanied by anoxia, and asteroid impact events. The extinction was triggered by an extensive flooding of basalts in the Central Atlantic Magmatic Province. Furthermore, a number of meteoritic craters have been found. Under the effect of cosmic causes, two main sequences of events developed on the Earth: terrestrial ones, leading to intensive volcanism, and cosmic ones (asteroid impacts). Their aftermaths, however, were similar in terms of the chemical compounds and aerosols released. As a consequence, the greenhouse effect, dimming of the atmosphere (impeding photosynthesis), ocean stagnation, and anoxia emerged. Then, biological productivity decreased and food chains were destroyed. Thus, the entire ecosystem was disturbed and a considerable part of the biota became extinct.

  6. Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry.

    PubMed

    Hengel, Matt; Lee, P

    2014-03-01

    Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil, chlorthal-dimethyl, cycloate, dicloran, dicofol, EPTC, ethalfluralin, iprodione, mefenoxam, metolachlor, PCNB, permethrin, pronamide, simazine, trifluralin, and vinclozolin. A GC with a flame photometric detector was used to determine chlorpyrifos, chlorpyrifos oxon, diazinon, diazinon oxon, dimethoate, dimethoate oxon, fonophos, fonophos oxon, malathion, malathion oxon, naled, and oxydemeton. Trapping efficiencies ranged from 78 to 92 % for low level (0.5 μg) and 37-104 % for high level (50 and 100 μg) recoveries. Little to no degradation of compounds occurred over 31 days; recoveries ranged from 78 to 113 %. In the California Department of Food and Agriculture (CDFA) method, pesticides were detected by analyzing the extract by GC-MS to determine chlorothalonil, chlorpyrifos, cypermethrin, dichlorvos, dicofol, endosulfan 1, endosulfan sulfate, oxyfluorfen, permethrin, propargite, and trifluralin. A liquid chromatograph coupled to a MS was used to determine azinphos-methyl, chloropyrifos oxon, DEF, diazinon, diazinon oxon, dimethoate, dimethoate oxon, diuron, EPTC, malathion, malathion oxon, metolachlor, molinate, norflurazon, oryzalin, phosmet, propanil, simazine and thiobencarb. Trapping efficiencies for compounds determined by the CDFA method ranged from 10 to 113, 22 to 114, and 56 to 132 % for 10, 5, and 2 μg spikes, respectively. Storage tests yielded 70-170 % recovery for up to 28 days. These multiresidue methods represent flexible, sensitive, accurate, and cost-effective ways to determine residues of various pesticides in ambient air. PMID:24370860

  7. Determination of the effect of transfer between vacuum and air on mass standards of platinum-iridium and stainless steel

    NASA Astrophysics Data System (ADS)

    Davidson, Stuart

    2010-08-01

    This paper reports work undertaken to assess the change in the mass values of stainless steel and platinum-iridium weights transferred between air and vacuum and to determine the repeatability of this change. Sets of kilogram transfer standards, manufactured from stainless steel and platinum-iridium and with different surface areas, were used to determine the effect of transfer between air and vacuum on the values of the mass standards. The SI unit of mass is the only unit of the seven base SI quantities which is still defined in terms of an artefact rather than by relation to a fundamental physical constant. Work is underway to identify a means of deriving the SI unit of mass from fundamental constants and at present the two principal approaches are the International Avogadro Coordination and the watt balance projects. Both of these approaches involve realizing a kilogram in vacuum and therefore the traceability from a kilogram realized in vacuum to mass standards in air is crucial to the effective dissemination of the mass scale. The work reported here characterizes the changes in mass values of standards on transfer between air and vacuum and thus will enable traceability to be established for an in-air mass scale based on a definition of the unit in vacuum.

  8. Ozone Modulation/Membrane Introduction Mass Spectrometry for Analysis of Hydrocarbon Pollutants in Air

    NASA Astrophysics Data System (ADS)

    Atkinson, D. B.

    2001-12-01

    Modulation of volatile hydrocarbons in two-component mixtures is demonstrated using an ozonolysis pretreatment with membrane introduction mass spectrometry (MIMS). The MIMS technique allows selective introduction of volatile and semivolatile analytes into a mass spectrometer via processes known collectively as pervaporation [Kotiaho and Cooks, 1992]. A semipermeable polymer membrane acts as an interface between the sample (vapor or solution) and the vacuum of the mass spectrometer. This technique has been demonstrated to allow for sensitive analysis of hydrocarbons and other non-polar volatile organic compounds (VOC`s) in air samples[Cisper et al., 1995] . The methodology has the advantages of no sample pretreatment and short analysis time, which are promising for online monitoring applications but the chief disadvantage of lack of a separation step for the different analytes in a mixture. Several approaches have been investigated to overcome this problem including use of selective chemical ionization [Bier and Cooks, 1987] and multivariate calibration techniques[Ketola et al., 1999] . A new approach is reported for the quantitative measurement of VOCs in complex matrices. The method seeks to reduce the complexity of mass spectra observed in hydrocarbon mixture analysis by selective pretreatment of the analyte mixture. In the current investigation, the rapid reaction of ozone with alkenes is used, producing oxygenated compounds which are suppressed by the MIMS system. This has the effect of removing signals due to unsaturated analytes from the compound mass spectra, and comparison of the spectra before and after the ozone treatment reveals the nature of the parent compounds. In preliminary investigations, ozone reacted completely with cyclohexene from a mixture of cylohexene and cyclohexane, and with β -pinene from a mixture of toluene and β -pinene, suppressing the ion signals from the olefins. A slight attenuation of the cyclohexane and toluene in those

  9. Accelerator Mass Spectrometric determination of radiocarbon in stratospheric CO2, retrieved from AirCore sampling.

    NASA Astrophysics Data System (ADS)

    Paul, Dipayan; Been, Henk A.; Chen, Huilin; Kivi, Rigel; Meijer, Harro A. J.

    2015-04-01

    In this decade, understanding the impact of human activities on climate is one of the key issues of discussion globally. The continuous rise in the concentration of greenhouse gases, e.g., CO2, CH4, etc. in the atmosphere, predominantly due to human activities, is alarming and requires continuous monitoring to understand the dynamics. Radiocarbon is an important atmospheric tracer and one of the many used in the understanding of the global carbon budget, which includes the greenhouse gases like CO2 and CH4. Measurement of 14C (or radiocarbon) in atmospheric CO2 generally requires collection of large air samples (few liters) from which CO2 is extracted and then the concentration of radiocarbon is determined. Currently, Accelerator Mass Spectrometry (AMS) is the most precise, reliable and widely used technique for atmospheric radiocarbon detection. However, the regular collection of air samples from troposphere and stratosphere, for example using aircraft, is prohibitively expensive. AirCore is an innovative atmospheric sampling system, developed by NOAA. It comprises of a long tube descending from a high altitude with one end open and the other closed, and has been demonstrated to be a reliable, cost-effective sampling system for high-altitude profile (up to ~ 30 km) measurements of CH4and CO2(Karion et al. 2010). In Europe, AirCore measurements are being performed on a regular basis near Sodankylä since September 2013. Here we describe the analysis of two such AirCore samples collected in July 2014, Finland, for determining the 14C concentration in stratospheric CO2. The two AirCore samples were collected on consecutive days. Each stratospheric AirCore sample was divided into six fractions, each containing ~ 35 μg CO2 (~9.5 μg C). Each fraction was separately trapped in 1 /4 inch coiled stainless steel tubing for radiocarbon measurements. The procedure for CO2 extraction from the stratospheric air samples; the sample preparation, with samples containing < 10

  10. The effect of star-spots on the ages of low-mass stars determined from the lithium depletion boundary

    NASA Astrophysics Data System (ADS)

    Jackson, R. J.; Jeffries, R. D.

    2014-12-01

    In a coeval group of low-mass stars, the luminosity of the sharp transition between stars that retain their initial lithium and those at slightly higher masses in which Li has been depleted by nuclear reactions, the lithium depletion boundary (LDB), has been advanced as an almost model-independent means of establishing an age scale for young stars. Here, we construct polytropic models of contracting pre-main sequence stars (PMS) that have cool, magnetic star-spots blocking a fraction β of their photospheric flux. Star-spots slow the descent along Hayashi tracks, leading to lower core temperatures and less Li destruction at a given mass and age. The age, τLDB, determined from the luminosity of the LDB, LLDB, is increased by a factor of (1 - β)-E compared to that inferred from unspotted models, where E ≃ 1 + dlog τLDB/dlog LLDB and has a value ˜0.5 at ages <80 Myr, decreasing to ˜0.3 for older stars. Spotted stars have virtually the same relationship between K-band bolometric correction and colour as unspotted stars, so this relationship applies equally to ages inferred from the absolute K magnitude of the LDB. Low-mass PMS stars do have star-spots, but the appropriate value of β is highly uncertain with a probable range of 0.1 < β < 0.4. For the smaller β values, our result suggests a modest systematic increase in LDB ages that is comparable with the maximum levels of theoretical uncertainty previously claimed for the technique. The largest β values would however increase LDB ages by 20-30 per cent and demand a re-evaluation of other age estimation techniques calibrated using LDB ages.

  11. A thunderstorm cell-lightning activity analysis: The new concept of air mass catchment

    NASA Astrophysics Data System (ADS)

    Mona, Tamás; Horváth, Ákos; Ács, Ferenc

    2016-03-01

    Thunderstorm cell-lightning activity is discussed in terms of analysing a thunderstorm's lightning frequency-equipotential temperature relationship. Thunderstorms were tracked using Doppler radars in five-minute time steps. Lightning is assigned to the nearest thunderstorm cell, it is characterised by lightning frequency data using LINET. Equipotential temperature is not directly estimated, instead the notion of air mass catchment is introduced to represent it. It is shown in this paper that the thunderstorm cell with maximum lightning frequency in the current time step is almost always the so-called leading storm cell. The lightning frequency activity of the non-leading storm cells is not significant.

  12. Formic and Acetic Acid Observations over Colorado by Chemical Ionization Mass Spectrometry and Organic Acids' Role in Air Quality

    NASA Astrophysics Data System (ADS)

    Treadaway, V.; O'Sullivan, D. W.; Heikes, B.; Silwal, I.; McNeill, A.

    2015-12-01

    Formic acid (HFo) and acetic acid (HAc) have both natural and anthropogenic sources and a role in the atmospheric processing of carbon. These organic acids also have an increasing importance in setting the acidity of rain and snow as precipitation nitrate and sulfate concentrations have decreased. Primary emissions for both organic acids include biomass burning, agriculture, and motor vehicle emissions. Secondary production is also a substantial source for both acids especially from biogenic precursors, secondary organic aerosols (SOAs), and photochemical production from volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs). Chemical transport models underestimate organic acid concentrations and recent research has sought to develop additional production mechanisms. Here we report HFo and HAc measurements during two campaigns over Colorado using the peroxide chemical ionization mass spectrometer (PCIMS). Iodide clusters of both HFo and HAc were recorded at mass-to-charge ratios of 173 and 187, respectively. The PCIMS was flown aboard the NCAR Gulfstream-V platform during the Deep Convective Clouds and Chemistry Experiment (DC3) and aboard the NCAR C-130 during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE). The DC3 observations were made in May and June 2012 extending from the surface to 13 km over the central and eastern United States. FRAPPE observations were made in July and August 2014 from the surface to 7 km over Colorado. DC3 measurements reported here are focused over the Colorado Front Range and complement the FRAPPE observations. DC3 HFo altitude profiles are characterized by a decrease up to 6 km followed by an increase either back to boundary layer mixing ratio values or higher (a "C" shape). Organic acid measurements from both campaigns are interpreted with an emphasis on emission sources (both natural and anthropogenic) over Colorado and in situ photochemical production especially ozone precursors.

  13. Nanoparticle volume fraction with heat and mass transfer on MHD mixed convection flow in a nanofluid in the presence of thermo-diffusion under convective boundary condition

    NASA Astrophysics Data System (ADS)

    Kandasamy, R.; Jeyabalan, C.; Sivagnana Prabhu, K. K.

    2016-02-01

    This article examines the influence of thermophoresis, Brownian motion of the nanoparticles with variable stream conditions in the presence of magnetic field on mixed convection heat and mass transfer in the boundary layer region of a semi-infinite porous vertical plate in a nanofluid under the convective boundary conditions. The transformed boundary layer ordinary differential equations are solved numerically using Maple 18 software with fourth-fifth order Runge-Kutta-Fehlberg method. Numerical results are presented both in tabular and graphical forms illustrating the effects of these parameters with magnetic field on momentum, thermal, nanoparticle volume fraction and solutal concentration boundary layers. The numerical results obtained for the velocity, temperature, volume fraction, and concentration profiles reveal interesting phenomenon, some of these qualitative results are presented through plots. It is interesting to note that the magnetic field plays a dominant role on nanofluid flow under the convective boundary conditions.

  14. Diode laser-based air mass flux sensor for subsonic aeropropulsion inlets.

    PubMed

    Miller, M F; Kessler, W J; Allen, M G

    1996-08-20

    An optical air mass flux sensor based on a compact, room-temperature diode laser in a fiber-coupled delivery system has been tested on a full-scale gas turbine engine. The sensor is based on simultaneous measurements of O(2) density and Doppler-shifted velocity along a line of sight across the inlet duct. Extensive tests spanning engine power levels from idle to full afterburner demonstrate accuracy and precision of the order of 1-2% of full scale in density, velocity, and mass flux. The precision-limited velocity at atmospheric pressure was as low as 40 cm/s. Multiple data-reduction procedures are quantitatively compared to suggest optimal strategies for flight sensor packages. PMID:21102916

  15. Diode laser-based air mass flux sensor for subsonic aeropropulsion inlets

    NASA Astrophysics Data System (ADS)

    Miller, Michael F.; Kessler, William J.; Allen, Mark G.

    1996-08-01

    An optical air mass flux sensor based on a compact, room-temperature diode laser in a fiber-coupled delivery system has been tested on a full-scale gas turbine engine. The sensor is based on simultaneous measurements of O 2 density and Doppler-shifted velocity along a line of sight across the inlet duct. Extensive tests spanning engine power levels from idle to full afterburner demonstrate accuracy and precision of the order of 1 2 of full scale in density, velocity, and mass flux. The precision-limited velocity at atmospheric pressure was as low as 40 cm s. Multiple data-reduction procedures are quantitatively compared to suggest optimal strategies for flight sensor packages.

  16. Abrupt ocean anoxia and mass extinction at the Hangenberg crisis, Devonian-Carboniferous boundary

    NASA Astrophysics Data System (ADS)

    Schmitz, M. D.; Davydov, V. I.

    2012-12-01

    The late Devonian period hosts a set of profound biotic crises accompanying episodes of tropical ocean anoxia, positive carbon isotope excursions, relative sea level rise and fall, and apparent global climatic cooling. The Hangenberg event, at the close of the Devonian, is the last of these crises which ushered in a new and long-lived icehouse climate regime spanning the Carboniferous and early Permian. New high-precision U-Pb zircon ages for bracketing volcanic tuffs constrain the timing and tempo of the Hangenberg biotic crisis. When combined with quantitative biostratigraphic analysis, these data constrain the duration of tropical ocean anoxia, mass extinction and carbon cycle perturbation to less than 100 thousand years. This rapidity and duration is consistent with a model of orbitally-forced cooling resulting in enhancement of oceanic circulation, in turn promoting catastrophic overturn, upwelling of anoxic bottom waters onto the tropical continental shelves, and consequent biotic reorganization. Enhanced organic carbon burial evidenced by a positive carbon isotope spike is also revealed as rapid and short-lived, but sufficient to draw down atmospheric CO2 and initiate a glacial pulse restricted to a single short period eccentricity cycle at the end-Devonian.

  17. Boundary Layer Vertical Exchange Processes and the Mass Budget of Ozone: Observations and Model Results

    SciTech Connect

    Berkowitz, Carl M.; Fast, Jerome D.; Easter, Richard C.

    2000-06-16

    An Eulerian chemical model is used to assess the relative importance of a variety of processes associated with producing high surface ozone episodes during selected periods of the NARSTO 1995 field campaign over the northeastern United States. A comparison of the observed and predicted hourly surface ozone mixing ratios showed that the model qualitatively reproduced the observed ozone trends over the northeastern U.S. The model, however, over-predicted the surface concentrations by 10 to 15 ppb. The simulated mass budget tendency terms are compared for days with low ozone values immediately followed by days with high values. The later days showed observed and simulated ozone mixing ratios aloft to be of order twice that found on preceding days, although the associated chemical mix appeared to have relatively little potential for the subsequent generation of "new" ozone. Under conditions of shallow mixing over urban regions, simulated surface ozone production rates were negative (a net loss) throughout much of the day with convective mixing bringing newly produced ozone from aloft to the surface. It is noted that surface ozone levels appeared to be relatively insensitive to mixing layer growth rates.

  18. Uncertainty evaluation of mass values determined by electronic balances in analytical chemistry: a new method to correct for air buoyancy.

    PubMed

    Wunderli, S; Fortunato, G; Reichmuth, A; Richard, Ph

    2003-06-01

    A new method to correct for the largest systematic influence in mass determination-air buoyancy-is outlined. A full description of the most relevant influence parameters is given and the combined measurement uncertainty is evaluated according to the ISO-GUM approach [1]. A new correction method for air buoyancy using an artefact is presented. This method has the advantage that only a mass artefact is used to correct for air buoyancy. The classical approach demands the determination of the air density and therefore suitable equipment to measure at least the air temperature, the air pressure and the relative air humidity within the demanded uncertainties (i.e. three independent measurement tasks have to be performed simultaneously). The calculated uncertainty is lower for the classical method. However a field laboratory may not always be in possession of fully traceable measurement systems for these room climatic parameters.A comparison of three approaches applied to the calculation of the combined uncertainty of mass values is presented. Namely the classical determination of air buoyancy, the artefact method, and the neglecting of this systematic effect as proposed in the new EURACHEM/CITAC guide [2]. The artefact method is suitable for high-precision measurement in analytical chemistry and especially for the production of certified reference materials, reference values and analytical chemical reference materials. The method could also be used either for volume determination of solids or for air density measurement by an independent method. PMID:12732918

  19. Characteristics of dimethylsulfide, ozone, aerosols, and cloud condensation nuclei in air masses over the northwestern Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Nagao, Ippei; Matsumoto, Kiyoshi; Tanaka, Hiroshi

    1999-05-01

    Long-term measurements of several trace gases and aerosols were carried out from December 1994 to October 1996 at Ogasawara Hahajima Island over the northwestern Pacific Ocean. The continental impact on the concentrations of sulfur compounds, ozone (O3), and cloud condensation nuclei (CCN) was estimated on the basis of the classification of air mass into seven types by isentropic trajectory analysis. From May to October, the air mass originating from the central North Pacific Ocean is predominant and regarded as the clean marine air for the concentrations of sulfur compounds and CCN. From the results of the molar ratio of methane sulfonic acid to non-sea-salt sulfate (NSS) and the positive correlation between dimethylsulfide (DMS) and CCN in this air mass it can be concluded that DMS largely contributes to the production of NSS and CCN. On the other hand, continental and anthropogenic substances are preferably transported to the northwestern Pacific Ocean by the predominant continental air mass from November to March. The enhancement of concentrations by the outflow from the Asian continent are estimated by a factor of 2.8 for O3, 3.9 for SO2, 3.5 for CCN activated at 0.5% supersaturation (0.5% CCN), 4.7 for 1.0% CCN, and 5.5 for NSS. Moreover, the CCN supersaturation spectra are also affected by the continental substances resulting in factor 2 of enhancement of cloud droplet number concentration. The diurnal variations of DMS and O3 for each air mass show a pattern of daytime minimum and nighttime maximum, which are typically found in remote ocean, even though those amplitudes are different for each air mass. Consequently, it can be concluded that the influence of nitric oxides (NOx) for the daytime O3 production and nitrate (NO3) radical for the nighttime oxidation of DMS are small even in the continental air mass.

  20. Impact of chemical and meteorological boundary and initial conditions on air quality modeling: WRF-Chem sensitivity evaluation for a European domain

    NASA Astrophysics Data System (ADS)

    Ritter, Mathias; Müller, Mathias D.; Jorba, Oriol; Parlow, Eberhard; Liu, L.-J. Sally

    2013-01-01

    This study evaluates the impact of different chemical and meteorological boundary and initial conditions on the state-of-the-art Weather Research and Forecasting (WRF) model with its chemistry extension (WRF-Chem). The evaluation is done for July 2005 with 50 km horizontal resolution. The effect of monthly mean chemical boundary conditions derived from the chemical transport model LMDZ-INCA on WRF-Chem is evaluated against the effect of the preset idealized profiles. Likewise, the impact of different meteorological initial and boundary conditions (GFS and Reanalysis II) on the model is evaluated. Pearson correlation coefficient between these different runs range from 0.96 to 1.00. Exceptions exists for chemical boundary conditions on ozone and for meteorological boundary conditions on PM10, where coefficients of 0.90 were obtained. Best results were achieved with boundary and initial conditions from LMDZ-INCA and GFS. Overall, the European simulations show encouraging results for observed air pollutant, with ozone being the most and PM10 being the least satisfying.

  1. Precipitation chemistry and corresponding transport patterns of influencing air masses at Huangshan Mountain in East China

    NASA Astrophysics Data System (ADS)

    Shi, ChunE; Deng, Xueliang; Yang, Yuanjian; Huang, Xiangrong; Wu, Biwen

    2014-09-01

    One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean (VWM) pH for the whole sampling period was 5.03. SO{4/2-} and Ca2+ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO{4/2-}]/[NO{3/-}] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.

  2. A study of tornadic thunderstorm interactions with thermal boundaries

    NASA Technical Reports Server (NTRS)

    Maddox, R. A.; Hoxit, L. R.; Chappell, C. F.

    1980-01-01

    A study of tornadic thunderstorm interactions with thermal boundaries using a model of subcloud wind profiles is presented. Within a hot, moist, and conditionally unstable air mass, warm thermal advection and surface friction cause the winds to veer and increase with height, while within a cool, moist air mass cool thermal advection and friction combine to produce a wind profile that has maximum speeds near the surface and veers little with height. The spatial distribution of different wind profiles and moisture contents within the boundary layer may act together to maximize mesoscale moisture contents, convergence, and cyclonic vorticity within a narrow mixing zone along the thermal boundary.

  3. Application of active optical sensors to probe the vertical structure of the urban boundary layer and assess anomalies in air quality model PM 2.5 forecasts

    NASA Astrophysics Data System (ADS)

    Gan, Chuen-Meei; Wu, Yonghua; Madhavan, B. L.; Gross, Barry; Moshary, Fred

    2011-12-01

    In this paper, the simulations of the Weather Research and Forecast (WRF) and Community Multiscale Air Quality (CMAQ) Models applied to the New York City (NYC) area are assessed with the aid of vertical profiling and column integrated remote sensing measurements. First, we find that when turbulent mixing processes are dominant, the WRF-derived planetary boundary layer (PBL) height exhibits a strong linear correlation ( R > 0.85) with lidar-derived PBL height. In these comparisons, we estimate the PBL height from the lidar measurements using a Wavelet Covariance Transform (WCT) approach that is modified to better isolate the convective layer from the residual layer (RL). Furthermore, the WRF-Lidar PBL height comparisons are made using different PBL parameterization schemes, including the Asymmetric Convective Model-version2 (ACM2) and the Modified Blackadar (BLK) scheme (which are both runs using hindcast data), as well as the Mellor-Yamada-Janjic (MYJ) scheme run in forecast mode. Our findings show that the correlations for these runs are high (>0.8), but the hindcast runs exhibit smaller overall dispersion (≈0.1) than the forecast runs. We also apply continuous 24-hour/7-day vertical ceilometer measurements to assess WRF-CMAQ model forecasts of surface PM 2.5 (particulate matter has aerodynamic diameter <2.5 μm). Strong overestimations in the surface PM 2.5 mass that are observed in the summer prior to sunrise are particularly shown to be strongly connected to underestimations of the PBL height and less to enhanced emissions. This interpretation is consistent with observations that TEOM (Tapered Element Oscillating MicroBalance) PM 2.5 measurements are better correlated to path-integrated CMAQ PM 2.5 than the near-surface measurements during these periods.

  4. Application of active optical sensors to probe the vertical structure of the urban boundary layer and assess anomalies in air quality model PM2.5forecasts

    NASA Astrophysics Data System (ADS)

    Gan, Chuen-Meei; Wu, Yonghua; Bomidi, L. M.; Gross, Barry; Moshary, Fred

    2011-11-01

    In this paper, the simulations of the Weather Research and Forecast (WRF) and Community Multiscale Air Quality (CMAQ) Models applied to the New York City (NYC) area are assessed with the aid of vertical profiling and column integrated remote sensing measurements. First, we find that when turbulent mixing processes are dominant, the WRFderived planetary boundary layer (PBL) height exhibits a strong linear correlation (R>0.85) with lidar-derived PBL height. In these comparisons, we estimate the PBL height from the lidar measurements using a Wavelet Covariance Transform (WCT) approach that is modified to better isolate the convective layer from the residual layer (RL). Furthermore, the WRF-Lidar PBL height comparisons are made using different PBL parameterization schemes, including the Asymmetric Convective Model-version2 (ACM2) and the Modified Blackadar (BLK) scheme (which are both runs using hindcast data), as well as the Mellor-Yamada-Janjic (MYJ) scheme run in forecast mode. Our findings show that the correlations for these runs are high (>0.8), but the hindcast runs exhibit smaller overall dispersion (~0.1) than the forecast runs. We also apply continuous 24-hour/7-day vertical ceilometer measurements to assess WRFCMAQ model forecasts of surface PM2.5 (particulate matter has aerodynamic diameter <2.5μm). Strong overestimations in the surface PM2.5 mass that are observed in the summer prior to sunrise are particularly shown to be strongly connected to underestimations of the PBL height and less to enhanced emissions. This interpretation is consistent with observations that TEOM (Tapered Element Oscillating MicroBalance) PM2.5 measurements are better correlated to pathintegrated CMAQ PM2.5 than the near-surface measurements during these periods.

  5. Air mass distribution and the heterogeneity of the climate change signal in the Hudson Bay/Foxe Basin region, Canada

    NASA Astrophysics Data System (ADS)

    Leung, Andrew; Gough, William

    2016-08-01

    The linkage between changes in air mass distribution and temperature trends from 1971 to 2010 is explored in the Hudson Bay/Foxe Basin region. Statistically significant temperature increases were found of varying spatial and temporal magnitude. Concurrent statistically significant changes in air mass frequency at the same locations were also detected, particularly in the declining frequency of dry polar (DP) air. These two sets of changes were found to be linked, and we thus conclude that the heterogeneity of the climatic warming signal in the region is at least partially the result of a fundamental shift in the concurrent air mass frequency in addition to global and regional changes in radiative forcing due to increases in long-lived greenhouse gases.

  6. Correlated terrestrial and marine evidence for global climate changes before mass extinction at the Cretaceous-Paleogene boundary.

    PubMed

    Wilf, Peter; Johnson, Kirk R; Huber, Brian T

    2003-01-21

    Terrestrial climates near the time of the end-Cretaceous mass extinction are poorly known, limiting understanding of environmentally driven changes in biodiversity that occurred before bolide impact. We estimate paleotemperatures for the last approximately 1.1 million years of the Cretaceous ( approximately 66.6-65.5 million years ago, Ma) by using fossil plants from North Dakota and employ paleomagnetic stratigraphy to correlate the results to foraminiferal paleoclimatic data from four middle- and high-latitude sites. Both plants and foraminifera indicate warming near 66.0 Ma, a warming peak from approximately 65.8 to 65.6 Ma, and cooling near 65.6 Ma, suggesting that these were global climate shifts. The warming peak coincides with the immigration of a thermophilic flora, maximum plant diversity, and the poleward range expansion of thermophilic foraminifera. Plant data indicate the continuation of relatively cool temperatures across the Cretaceous-Paleogene boundary; there is no indication of a major warming immediately after the boundary as previously reported. Our temperature proxies correspond well with recent pCO(2) data from paleosol carbonate, suggesting a coupling of pCO(2) and temperature. To the extent that biodiversity is correlated with temperature, estimates of the severity of end-Cretaceous extinctions that are based on occurrence data from the warming peak are probably inflated, as we illustrate for North Dakota plants. However, our analysis of climate and facies considerations shows that the effects of bolide impact should be regarded as the most significant contributor to these plant extinctions. PMID:12524455

  7. Correlated terrestrial and marine evidence for global climate changes before mass extinction at the Cretaceous–Paleogene boundary

    PubMed Central

    Wilf, Peter; Johnson, Kirk R.; Huber, Brian T.

    2003-01-01

    Terrestrial climates near the time of the end-Cretaceous mass extinction are poorly known, limiting understanding of environmentally driven changes in biodiversity that occurred before bolide impact. We estimate paleotemperatures for the last ≈1.1 million years of the Cretaceous (≈66.6–65.5 million years ago, Ma) by using fossil plants from North Dakota and employ paleomagnetic stratigraphy to correlate the results to foraminiferal paleoclimatic data from four middle- and high-latitude sites. Both plants and foraminifera indicate warming near 66.0 Ma, a warming peak from ≈65.8 to 65.6 Ma, and cooling near 65.6 Ma, suggesting that these were global climate shifts. The warming peak coincides with the immigration of a thermophilic flora, maximum plant diversity, and the poleward range expansion of thermophilic foraminifera. Plant data indicate the continuation of relatively cool temperatures across the Cretaceous–Paleogene boundary; there is no indication of a major warming immediately after the boundary as previously reported. Our temperature proxies correspond well with recent pCO2 data from paleosol carbonate, suggesting a coupling of pCO2 and temperature. To the extent that biodiversity is correlated with temperature, estimates of the severity of end-Cretaceous extinctions that are based on occurrence data from the warming peak are probably inflated, as we illustrate for North Dakota plants. However, our analysis of climate and facies considerations shows that the effects of bolide impact should be regarded as the most significant contributor to these plant extinctions. PMID:12524455

  8. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins. PMID:26930305

  9. Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-01-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  10. The effects of upstream mass injection by vortex generator jets on shock-induced turbulent boundary layer separation

    NASA Astrophysics Data System (ADS)

    Bueno, Pablo Cesar

    An experimental study was conducted to investigate the effects of upstream mass injection, by means of vortex generator jets (VGJs), on the shock wave/turbulent boundary layer interaction (SWTBLI) generated by cylinder in a Mach 2 flow. The objectives of the study were: (i) to characterize the changes to the global structure of the flowfield introduced by the VGJs, and (ii) to study how the injection affected the dynamics of the separation shock foot. The injection was provided by three high-speed valves, placed across the span of the test section, which generated underexpanded jets. Two jet orientations were studied: normal to the wall, and pitched at 60° and skewed at 90° with respect to the freestream. In addition, the effects of both continuous and pulsed injection were investigated. Velocity measurements of the upstream boundary layer, VGJs, and -shock system were made using a wide-field particle image velocimetry (PIV) system, and an array of fast-response pressure transducers was used to monitor the wall pressure under the intermittent region of the interaction. The velocity measurements of the baseline case captured nearly all the relevant flow structures including the -shock and primary and secondary vortices. However, neither mean supersonic reversed flow nor the supersonic jet that presumably exists downstream of the triple point were observed. When injection was applied, the scale of the separated flow changed considerably. For normal injection, the primary vortex was nearly suppressed, while for pitched/skewed injection, the secondary vortex increased in size. Mean streamwise and transverse velocity profiles upstream of the separation shock showed that, for both jet orientations, the VGJs caused the flow in the boundary layer to accelerate. However, for normal injection, the acceleration did not extend down to the wall. Phase-averaged velocity measurements of the opening phase of the valves indicated that there is a phase lag between the jets and the

  11. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  12. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

    2014-01-01

    The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

  13. Number size distribution of aerosols at Mt. Huang and Nanjing in the Yangtze River Delta, China: Effects of air masses and characteristics of new particle formation

    NASA Astrophysics Data System (ADS)

    Wang, Honglei; Zhu, Bin; Shen, Lijuan; An, Junlin; Yin, Yan; Kang, Hanqing

    2014-12-01

    Aerosol number spectra in the range of 10 nm-10 μm were observed at Mt. Huang (Aug. 15-Sep. 15) and Nanjing (Oct. 13-Nov. 15) by a wide-range particle spectrometer (WPS) in 2011. Based on the backward trajectories obtained using the HYSPLIT model, the transport pathways of observed air masses during the study periods were classified into the following four groups: maritime air mass, continental air mass, marine-continental mixed air mass and local air mass. The variations in the aerosol number spectrum and the new particle formation (NPF) events for various types of air masses were discussed, along with meteorological data. The results showed that the average number concentration was 12,540 cm- 3 at Nanjing and only 2791 cm- 3 at Mt. Huang. The aerosol number concentration in Nanjing was 3-7 times higher than that in Mt. Huang; the large discrepancy was in the range of 10-100 nm. Different types of air masses had different effects on number concentration distribution. The number concentration of aerosols was higher in marine air masses, continental air masses and continental-marine mixed air masses at 10-50 nm, 100-500 nm and 50-200 nm, respectively. Under the four types of air masses, the aerosol size spectra had bimodal distributions in Nanjing and unimodal distributions in Mt. Huang (except under continental air masses: HT1). The effects of the diverse air masses on aerosol size segments of the concentration peak in Mt. Huang were stronger than those in Nanjing. The local air masses were dominant at these two sites and accounted for 44% of the total air masses. However, the aerosol number concentration was the lowest in Mt. Huang and the highest in Nanjing when local air masses were present. The number concentrations for foreign air masses increased at Mt. Huang and decreased at Nanjing. Different types of air masses had greater effects on the aerosol spectrum distribution at Mt. Huang than at Nanjing. During the NPF events, the particle growth rates at Mt

  14. Internal Performance of Several Auxiliary Air Inlets Immersed in a Turbulent Boundary Layer at Mach Numbers of 1.3, 1.5, and 2.0

    NASA Technical Reports Server (NTRS)

    Huff, Ronald G; Anderson, Arthur R

    1957-01-01

    Internal performance of normal-shock rectangular, circular, and scoop inlets and of external-compression inlets experimentally obtained with varying immersion in a turbulent boundary layer. Recoveries varied from about 95 percent of theoretical in the free stream to 80 percent with complete immersion, while the corresponding mass flows were usually above 95 percent of theoretical. Turning of the flow through 10 degrees caused losses in pressure recovery of 0.03 to 0.07. External compression did not improve pressure recovery in the boundary layer. Average distortion at critical operation for all inlets was 5 percent.

  15. Variation in airborne 137Cs peak levels with altitude from high-altitude locations across Europe after the arrival of Fukushima-labeled air masses

    NASA Astrophysics Data System (ADS)

    Masson, Olivier; Bieringer, Jacqueline; Dalheimer, Axel; Estier, Sybille; Evrard, Olivier; Penev, Ilia; Ringer, Wolfgang; Schlosser, Clemens; Steinkopff, Thomas; Tositti, Laura; de Vismes-Ott, Anne

    2015-04-01

    During the Fukushima Daiichi nuclear power plant (FDNPP) accident, a dozen of high-altitude aerosol sampling stations, located between 850 and 3,454 m above sea level (a.s.l.), provided airborne activity levels across Europe (Fig. 1). This represents at most 5% of the total number of aerosol sampling locations that delivered airborne activity levels (at least one result) in Europe, in connection with this nuclear accident. High altitude stations are typically equipped with a high volume sampler that collects aerosols on filters. The Fukushima-labeled air mass arrival and the peak of airborne cesium-137 (137Cs) activity levels were registered in Europe at different dates depending on the location, with differences up to a factor of six on a regional scale. Besides this statement related to lowland areas, we have compared the maximum airborne levels registered at high-altitude European locations (850 m < altitudes < 3450 m) with what was observed at the closest lowland location. The vertical distribution of 137Cs peak level was not uniform even after a long travel time/distance from Japan. This being true at least in the atmospheric boundary layer and in the lower free troposphere. Moreover the relation '137Csmax vs. altitude' shows a decreasing trend (Fig. 2). Results and discussion : Comparison of 137Cs and 7Be levels shows simultaneous increases at least when the 137Cs airborne level rose for the first time (Fig. 3). Zugspitze and Jungfraujoch stations attest of a time shift between 7Be and 137Cs peak that can be due to the particular dynamic of air movements at such high altitudes. After the 137Cs peak value, the plume concentration decreased whatever the 7Be level. Due to the cosmogenic origin of 7Be, its increase in the ground-level air is usually associated with downwind air movements, i.e. stratospheric air intrusions or at least air from high-tropospheric levels, into lower atmospheric layers. This means that Fukushima-labeled air masses registered at ground

  16. High precision time calibration of the Permo-Triassic boundary mass extinction by U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Baresel, Björn; Bucher, Hugo; Brosse, Morgane; Schaltegger, Urs

    2014-05-01

    U-Pb dating using Chemical Abrasion, Isotope Dilution Thermal Ionization Mass Spectrometry (CA-ID-TIMS) is the analytical method of choice for geochronologists, who are seeking highest temporal resolution and a high degree of accuracy for single grains of zircon. The use of double-isotope tracer solutions, cross-calibrated and assessed in different EARTHTIME labs, coinciding with the reassessment of the uranium decay constants and further improvements in ion counting technology led to unprecedented precision better than 0.1% for single grain, and 0.05% for population ages, respectively. These analytical innovations now allow calibrating magmatic and biological timescales at resolution adequate for both groups of processes. To construct a revised and high resolution calibrated time scale for the Permian-Triassic boundary (PTB) we use (i) high-precision U-Pb zircon age determinations of a unique succession of volcanic ash beds interbedded with shallow to deep water fossiliferous sediments in the Nanpanjiang Basin (South China) combined with (ii) accurate quantitative biochronology based on ammonoids and conodonts and (iii) carbon isotope excursions across the PTB. Using these alignments allows (i) positioning the PTB in different depositional environments and (ii) solving age/stratigraphic contradictions generated by the index, water depth-controlled conodont Hindeodus parvus, whose diachronous first occurrences are arbitrarily used for placing the base of the Triassic. This new age framework provides the basis for a combined calibration of chemostratigraphic records with high-resolution biochronozones of the Late Permian and Early Triassic. Besides the general improvement of the radio-isotopic calibration of the PTB at the ±100 ka level, this will also lead to a better understanding of cause and effect relations involved in this mass extinction.

  17. Evidence of rapid production of organic acids in an urban air mass

    NASA Astrophysics Data System (ADS)

    Veres, Patrick R.; Roberts, James M.; Cochran, Anthony K.; Gilman, Jessica B.; Kuster, William C.; Holloway, John S.; Graus, Martin; Flynn, James; Lefer, Barry; Warneke, Carsten; de Gouw, Joost

    2011-09-01

    Gas-phase acids (nitric, formic, acrylic, methacrylic, propionic, and pyruvic/butryic acid) were measured using negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS) in Pasadena, CA as part of the CalNex 2010 (Research at the Nexus of Air Quality and Climate Change) study in May-June 2010. Organic acid concentrations ranged from a few parts per trillion by volume (pptv) to several parts per billion by volume (ppbv), with the largest concentrations observed for formic and propionic acids. Photochemically processed urban emissions transported from Los Angeles were frequently sampled during the day. Analysis of transported emissions demonstrates a strong correlation of organic acid concentrations with both nitric acid and odd oxygen (Ox = O3 + NO2) showing that the organic acids are photochemically and rapidly produced from urban emissions.

  18. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  19. Calculation of turbulent boundary layers with heat transfer and pressure gradient utilizing a compressibility transformation. Part 2: Constant property turbulent boundary layer flow with simultaneous mass transfer and pressure gradient

    NASA Technical Reports Server (NTRS)

    Boccio, J.; Economos, C.

    1972-01-01

    An analysis of the incompressible turbulent boundary layer, developing under the combined effects of mass transfer and pressure gradient, is presented in this paper. A strip-integral method is employed whereby two of the three governing equations are obtained by integrating the combined momentum and continuity equation to 50 percent and 100 percent, respectively, of the boundary-layer height. The latter equation is the usual momentum-integral equation; the former equation requires specification of shear. Accordingly, Clauser's equilibrium eddy-viscosity law is assumed valid at this point. The third and final equation is obtained by specifying that Stevenson's velocity profiles apply throughout the domain of interest, from which a skin-friction law can be derived. Comparisons of the numerical results with the experiments of McQuaid, which include combined effects of variable pressure gradient and mass transfer, show good agreement.

  20. Simultaneous heat and mass transfer inside a vertical tube in evaporating a heated falling alcohols liquid film into a stream of dry air

    NASA Astrophysics Data System (ADS)

    Senhaji, S.; Feddaoui, M.; Mediouni, T.; Mir, A.

    2009-03-01

    A numerical study of the evaporation in mixed convection of a pure alcohol liquid film: ethanol and methanol was investigated. It is a turbulent liquid film falling on the internal face of a vertical tube. A laminar flow of dry air enters the vertical tube at constant temperature in the downward direction. The wall of the tube is subjected to a constant and uniform heat flux. The model solves the coupled parabolic governing equations in both phases including turbulent liquid film together with the boundary and interfacial conditions. The systems of equations obtained by using an implicit finite difference method are solved by TDMA method. A Van Driest model is adopted to simulate the turbulent liquid film flow. The influence of the inlet liquid flow, Reynolds number in the gas flow and the wall heat flux on the intensity of heat and mass transfers are examined. A comparison between the results obtained for studied alcohols and water in the same conditions is made.

  1. Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Rosner, D. E.

    1984-01-01

    A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

  2. The influence of polarization on box air mass factors for UV/vis nadir satellite observations

    NASA Astrophysics Data System (ADS)

    Hilboll, Andreas; Richter, Andreas; Rozanov, Vladimir V.; Burrows, John P.

    2015-04-01

    Tropospheric abundances of pollutant trace gases like, e.g., NO2, are often derived by applying the differential optical absorption spectroscopy (DOAS) method to space-borne measurements of back-scattered and reflected solar radiation. The resulting quantity, the slant column density (SCD), subsequently has to be converted to more easily interpretable vertical column densities by means of the so-called box air mass factor (BAMF). The BAMF describes the ratio of SCD and VCD within one atmospheric layer and is calculated by a radiative transfer model. Current operational and scientific data products of satellite-derived trace gas VCDs do not include the effect of polarization in their radiative transfer models. However, the various scattering processes in the atmosphere do lead to a distinctive polarization pattern of the observed Earthshine spectra. This study investigates the influence of these polarization patterns on box air mass factors for satellite nadir DOAS measurements of NO2 in the UV/vis wavelength region. NO2 BAMFs have been simulated for a multitude of viewing geometries, surface albedos, and surface altitudes, using the radiative transfer model SCIATRAN. The results show a potentially large influence of polarization on the BAMF, which can reach 10% and more close to the surface. A simple correction for this effect seems not to be feasible, as it strongly depends on the specific measurement scenario and can lead to both high and low biases of the resulting NO2 VCD. We therefore conclude that all data products of NO2 VCDs derived from space-borne DOAS measurements should include polarization effects in their radiative transfer model calculations, or at least include the errors introduced by using linear models in their uncertainty estimates.

  3. Identification of aerosol types over an urban site based on air-mass trajectory classification

    NASA Astrophysics Data System (ADS)

    Pawar, G. V.; Devara, P. C. S.; Aher, G. R.

    2015-10-01

    Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18°32‧N; 73°49‧E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD500 nm) and Ångström exponent (AE, α). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD500 nm scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (τpλ = 0.43 ± 0.13) and high AE (α = 1.19 ± 0.15). These values imply the presence of accumulation/sub-micron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (τpλ = 0.61 ± 0.21), and low AE (α = 0.54 ± 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant.

  4. AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

    EPA Science Inventory

    Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

  5. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    SciTech Connect

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  6. A diagram of wind speed versus air-sea temperature difference to understand the dynamics of the marine atmospheric boundary layer off northwest Europe

    NASA Astrophysics Data System (ADS)

    Kettle, Anthony

    2015-04-01

    Wind speed and atmospheric stability have an important role in determining the turbulence in the marine atmospheric boundary layer (MABL) as well as the surface wave field. The understanding of MABL dynamics in northwest Europe is complicated by fetch effects, the proximity of coastlines, shallow topography, and larger scale circulation patterns (e.g., cold air outbreaks). Numerical models have difficulty simulating the marine atmospheric boundary layer in coastal areas and partially enclosed seas, and this is partly due to spatial resolution problems at land-sea coastline discontinuities. In these offshore environments, the boundary layer processes are often best understood directly from time series measurements from measurement platforms or buoys, in spite of potential difficulties from platform flow distortion as well as the spatial sparseness of the data sets. This contribution presents updated results of measurements from offshore platforms in the North Sea and Norwegian Sea in terms of a summary diagnostic - wind speed versus air-sea temperature difference (U-ΔT) - with important implications for understanding atmospheric boundary layer processes. The U-ΔT diagram was introduced in earlier surveys of data from coastal and offshore sites in northwest Europe to summarize boundary layer conditions at a given location. Additional information from a series of measurement purpose-built offshore measurement and oil/gas production platforms from the North Sea illustrates how the wind characteristics vary spatially over large distances. The results are important for the offshore wind industry because of the way that wind turbines accrue fatigue damage in different conditions of atmospheric stability and wind speed.

  7. Critical-Point Boundary for the Nuclear Quantum Phase Transition Near A=100 from Mass Measurements of {sup 96,97}Kr

    SciTech Connect

    Naimi, S.; Audi, G.; Lunney, D.; Beck, D.; Herfurth, F.; Blaum, K.; Boehm, Ch.; Borgmann, Ch.; George, S.; Kowalska, M.; Kreim, S.; Breitenfeldt, M.; Rosenbusch, M.; Schweikhard, L.; Herlert, A.; Neidherr, D.; Schwarz, S.; Zuber, K.

    2010-07-16

    Mass measurements of {sup 96,97}Kr using the ISOLTRAP Penning-trap spectrometer at CERN-ISOLDE are reported, extending the mass surface beyond N=60 for Z=36. These new results show behavior in sharp contrast to the heavier neighbors where a sudden and intense deformation is present. We interpret this as the establishment of a nuclear quantum phase transition critical-point boundary. The new masses confirm findings from nuclear mean-square charge-radius measurements up to N=60 but are at variance with conclusions from recent gamma-ray spectroscopy.

  8. Impact of the Loess Plateau on the atmospheric boundary layer structure and air quality in the North China Plain: a case study.

    PubMed

    Hu, Xiao-Ming; Ma, ZhiQiang; Lin, Weili; Zhang, Hongliang; Hu, Jianlin; Wang, Ying; Xu, Xiaobin; Fuentes, Jose D; Xue, Ming

    2014-11-15

    The North China Plain (NCP), to the east of the Loess Plateau, experiences severe regional air pollution. During the daytime in the summer, the Loess Plateau acts as an elevated heat source. The impacts of such a thermal effect on meteorological phenomena (e.g., waves, precipitation) in this region have been discussed. However, its impacts on the atmospheric boundary layer structure and air quality have not been reported. It is hypothesized that the thermal effect of the Plateau likely modulates the boundary layer structure and ambient concentrations of pollutants over the NCP under certain meteorological conditions. Thus, this study investigates such effect and its impacts using measurements and three-dimensional model simulations. It is found that in the presence of daytime westerly wind in the lower troposphere (~1 km above the NCP), warmer air above the Loess Plateau was transported over the NCP and imposed a thermal inversion above the mixed boundary layer, which acted as a lid and suppressed the mixed layer growth. As a result, pollutants accumulated in the shallow mixed layer and ozone was efficiently produced. The downward branch of the thermally-induced Mountain-Plains Solenoid circulation over the NCP contributed to enhancing the capping inversion and exacerbating air pollution. Previous studies have reported that low mixed layer, a factor for elevated pollution in the NCP, may be caused by aerosol scattering and absorption of solar radiation, frontal inversion, and large scale subsidence. The present study revealed a different mechanism (i.e., westerly warm advection) for the suppression of the mixed layer in summer NCP, which caused severe O3 pollution. This study has important implications for understanding the essential meteorological factors for pollution episodes in this region and forecasting these severe events. PMID:25192929

  9. Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)

    NASA Astrophysics Data System (ADS)

    Dall'Osto, Manuel; Beddows, David C. S.; Gietl, Johanna K.; Olatunbosun, Oluremi A.; Yang, Xiaoguang; Harrison, Roy M.

    2014-09-01

    There is a paucity of quantitative knowledge on the contributions of non-exhaust (abrasion and re-suspension) sources to traffic emissions. Abrasive emissions can be broadly categorised as tyre wear, brake wear and road dust/road surface wear. Current research often considers road dust and tyre dust as externally mixed particles, the former mainly composed of mineral matter and the latter solely composed of mainly organic matter and some trace elements. The aim of this work was to characterise tyre wear from both laboratory and field studies by using Aerosol Time-Of-Flight Mass Spectrometry (ATOFMS). Real-time single particle chemical composition was obtained from a set of rubber tyres rotating on a metal surface. Bimodal particle number size distributions peaking at 35 nm and 85 nm were obtained from SMPS/APS measurements over the range 6-20,000 nm. ATOFMS mass spectra of tyre wear in the particle size range 200-3000 nm diameter show peaks due to exo-sulphur compounds, nitrate, Zn and ions of high molecular weight (m/z > 100) attributed to organic polymers. Two large ATOFMS datasets collected from a number of outdoor studies were examined. The former was constituted of 48 road dust samples collected on the roads of London. The latter consisted of ATOFMS ambient air field studies from Europe, overall composed of more than 2,000,000 single particle mass spectra. The majority (95%) of tyre wear particles present in the road dust samples and atmospheric samples are internally mixed with metals (Li, Na, Ca, Fe, Ti), as well as phosphate. It is concluded that the interaction of tyres with the road surface creates particles internally mixed from two sources: tyre rubber and road surface materials. Measurements of the tyre rubber component alone may underestimate the contribution of tyre wear to concentrations of airborne particulate matter. The results presented are especially relevant for urban aerosol source apportionment and PM2.5 exposure assessment.

  10. Study Case of Air-Mass Modification over Poland and Romania Observed by the Means of Multiwavelength Raman Depolarization Lidars

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Janicka, Lucja; Stachlewska, Iwona S.; Nemuc, Anca; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2016-06-01

    An air-mass modification, on its way from Poland to Romania, observed between 19-21 July 2014 is discussed. The air-mass was investigated using data of two multi-wavelength lidars capable of performing regular elastic, depolarization and Raman measurements in Warsaw, Poland, and in Magurele, Romania. The analysis was focused on evaluating optical properties of aerosol in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations within given period.

  11. High precision time calibration of the Permian-Triassic boundary mass extinction event in a deep marine context

    NASA Astrophysics Data System (ADS)

    Baresel, Björn; Bucher, Hugo; Brosse, Morgane; Bagherpour, Borhan; Schaltegger, Urs

    2015-04-01

    To construct a revised and high resolution calibrated time scale for the Permian-Triassic boundary (PTB) we use (1) high-precision U-Pb zircon age determinations of a unique succession of volcanic ash layers interbedded with deep water fossiliferous sediments in the Nanpanjiang Basin (South China) combined with (2) accurate quantitative biochronology based on ammonoids, conodonts, radiolarians, and foraminifera and (3) tracers of marine bioproductivity (carbon isotopes) across the PTB. The unprecedented precision of the single grain chemical abrasion isotope-dilution thermal ionization mass spectrometry (CA-ID-TIMS) dating technique at sub-per mil level (radio-isotopic calibration of the PTB at the <100 ka level) now allows calibrating magmatic and biological timescales at resolution adequate for both groups of processes. Using these alignments allows (1) positioning the PTB in different depositional setting and (2) solving the age contradictions generated by the misleading use of the first occurrence (FO) of the conodont Hindeodus parvus, whose diachronous first occurrences are arbitrarily used for placing the base of the Triassic. This new age framework provides the basis for a combined calibration of chemostratigraphic records with high-resolution biochronozones of the Late Permian and Early Triassic. Here, we present new single grain U-Pb zircon data of volcanic ash layers from two deep marine sections (Dongpan and Penglaitan) revealing stratigraphic consistent dates over several volcanic ash layers bracketing the PTB. These analyses define weighted mean 206Pb/238U ages of 251.956±0.033 Ma (Dongpan) and 252.062±0.043 Ma (Penglaitan) for the last Permian ash bed. By calibration with detailed litho- and biostratigraphy new U-Pb ages of 251.953±0.038 Ma (Dongpan) and 251.907±0.033 Ma (Penglaitan) are established for the onset of the Triassic.

  12. Assessment of the MACC reanalysis and its influence as chemical boundary conditions for regional air quality modeling in AQMEII-2

    EPA Science Inventory

    The Air Quality Model Evaluation International Initiative (AQMEII) has now reached its second phase which is dedicated to the evaluation of online coupled chemistry-meteorology models. Sixteen modeling groups from Europe and five from North America have run regional air quality m...

  13. Boundary Layer

    NASA Technical Reports Server (NTRS)

    Loitsianskii. L. G.

    1956-01-01

    The fundamental, practically the most important branch of the modern mechanics of a viscous fluid or a gas, is that branch which concerns itself with the study of the boundary layer. The presence of a boundary layer accounts for the origin of the resistance and lift force, the breakdown of the smooth flow about bodies, and other phenomena that are associated with the motion of a body in a real fluid. The concept of boundary layer was clearly formulated by the founder of aerodynamics, N. E. Joukowsky, in his well-known work "On the Form of Ships" published as early as 1890. In his book "Theoretical Foundations of Air Navigation," Joukowsky gave an account of the most important properties of the boundary layer and pointed out the part played by it in the production of the resistance of bodies to motion. The fundamental differential equations of the motion of a fluid in a laminar boundary layer were given by Prandtl in 1904; the first solutions of these equations date from 1907 to 1910. As regards the turbulent boundary layer, there does not exist even to this day any rigorous formulation of this problem because there is no closed system of equations for the turbulent motion of a fluid. Soviet scientists have done much toward developing a general theory of the boundary layer, and in that branch of the theory which is of greatest practical importance at the present time, namely the study of the boundary layer at large velocities of the body in a compressed gas, the efforts of the scientists of our country have borne fruit in the creation of a new theory which leaves far behind all that has been done previously in this direction. We shall herein enumerate the most important results by Soviet scientists in the development of the theory of the boundary layer.

  14. Characterizing Air Masses in the Lower Troposphere (< 2 km) during the 2011 Student Airborne Program (SARP) Mission in Southern California

    NASA Astrophysics Data System (ADS)

    Lee, H.; Elder, C.; Kauffman, E. J.; Weathers, E.; Thomas, E.; Johnson, E.; Turrentine, H.; Saad, K.; Nighelli, K.; Burns, M.; Heath, N.; Shetter, R. E.; Schaller, E.; Webster, A.; Buzay, E.; Peterson, J.; Simpson, I. J.; Rowland, F. S.; Blake, D. R.

    2011-12-01

    During the NASA Student Airborne Program (SARP) mission, high frequency whole air sampling during a missed-approach to Los Angeles International airport (LAX) provided air mass signatures collected in close proximity to their urban and oceanic sources. Each whole air sample was analyzed for 80 halocarbons, hydrocarbons and organic nitrates. Unlike other airborne missions, high frequency whole air sampling of about 70 samples collected over a 20 minute period (15 second fill per sample) during a 150 km flight path at low altitude (< 2 km) provided a more detailed profile of the Los Angeles air shed than has been previously accomplished. Correlations between CH3I, CHBr3, and MeONO2 (marine tracers) versus C2Cl4 and HCFC-22 (anthropogenic tracers) were used to distinguish between purely marine air and air influenced by emissions from Los Angeles (Figure 1). Of the 80 C1-C10 volatile organic compounds that were measured, 60 were elevated in air from the Los Angeles air shed. These included C1-C10 alkanes, C6-C8 aromatics, C2-C3 alkenes, halons, HCFCs, HFCs, CH3CCl3, chlorinated solvents (e.g., C2Cl4, CHCl3, CH2Cl2), and organic nitrates. Marine species emitted in this region of the Pacific were found to include MeONO2, EtONO2, CH2Br2, CHBr3, CH3I and DMS. Note that the C3 organic nitrates were not enhanced in the marine influenced air, and instead they are attributed to urban photochemistry. Overall, high-frequency and low-altitude whole air sampling during the LAX missed-approach clearly distinguished urban and oceanic sources and allowed a detailed chemical signature for Los Angeles air to be determined.

  15. Reconstruction of the boundary between climate science and politics: the IPCC in the Japanese mass media, 1988-2007.

    PubMed

    Asayama, Shinichiro; Ishii, Atsushi

    2014-02-01

    The Intergovernmental Panel on Climate Change (IPCC) plays a significant role in bridging the boundary between climate science and politics. Media coverage is crucial for understanding how climate science is communicated and embedded in society. This study analyzes the discursive construction of the IPCC in three Japanese newspapers from 1988 to 2007 in terms of the science-politics boundary. The results show media discourses engaged in boundary-work which rhetorically separated science and politics, and constructed the iconic image of the IPCC as a pure scientific authority. In the linkages between the global and national arenas of climate change, the media "domesticate" the issue, translating the global nature of climate change into a discourse that suits the national context. We argue that the Japanese media's boundary-work is part of the media domestication that reconstructed the boundary between climate science and politics reflecting the Japanese context. PMID:23825249

  16. Forced Boundary-Layer Transition on X-43 (Hyper-X) in NASA LaRC 31-Inch Mach 10 Air Tunnel

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; DiFulvio, Michael; Kowalkowski, Matthew K.

    2000-01-01

    Aeroheating and boundary layer transition characteristics for the X-43 (Hyper-X) configuration have been experimentally examined in the Langley 31-Inch Mach 10 Air Tunnel. Global surface heat transfer distributions, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. Parametric variations include angles-of-attack of 0-deg, 2-deg, 3-deg, and 4-deg; Reynolds numbers based on model length of 1.2 to 5.1 million; and inlet cowl door both open and closed. The effects of discrete roughness elements on the forebody boundary layer, which included variations in trip configuration and height, were investigated. This document is intended to serve as a release of preliminary data to the Hyper-X program; analysis is limited to observations of the experimental trends in order to expedite dissemination.

  17. Forced Boundary-Layer Transition on X-43 (Hyper-X) in NASA LaRC 20-Inch Mach 6 Air Tunnel

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; DiFulvio, Michael; Kowalkowski, Matthew K.

    2000-01-01

    Aeroheating and boundary layer transition characteristics for the X-43 (Hyper-X) configuration have been experimentally examined in the Langley 20-Inch Mach 6 Air Tunnel. Global surface heat transfer distributions, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. Parametric variations include angles-of-attack of 0-deg, 2-deg, and 4-deg; Reynolds numbers based on model length of 1.2 to 15.4 million; and inlet cowl door both open and closed. The effects of discrete roughness elements on the forebody boundary layer, which included variations in trip configuration and height, were investigated. This document is intended to serve as a release of preliminary data to the Hyper-X program; analysis is limited to observations of the experimental trends in order to expedite dissemination.

  18. Artificial neural networks forecasting of PM2.5 pollution using air mass trajectory based geographic model and wavelet transformation

    NASA Astrophysics Data System (ADS)

    Feng, Xiao; Li, Qi; Zhu, Yajie; Hou, Junxiong; Jin, Lingyan; Wang, Jingjie

    2015-04-01

    In the paper a novel hybrid model combining air mass trajectory analysis and wavelet transformation to improve the artificial neural network (ANN) forecast accuracy of daily average concentrations of PM2.5 two days in advance is presented. The model was developed from 13 different air pollution monitoring stations in Beijing, Tianjin, and Hebei province (Jing-Jin-Ji area). The air mass trajectory was used to recognize distinct corridors for transport of "dirty" air and "clean" air to selected stations. With each corridor, a triangular station net was constructed based on air mass trajectories and the distances between neighboring sites. Wind speed and direction were also considered as parameters in calculating this trajectory based air pollution indicator value. Moreover, the original time series of PM2.5 concentration was decomposed by wavelet transformation into a few sub-series with lower variability. The prediction strategy applied to each of them and then summed up the individual prediction results. Daily meteorological forecast variables as well as the respective pollutant predictors were used as input to a multi-layer perceptron (MLP) type of back-propagation neural network. The experimental verification of the proposed model was conducted over a period of more than one year (between September 2013 and October 2014). It is found that the trajectory based geographic model and wavelet transformation can be effective tools to improve the PM2.5 forecasting accuracy. The root mean squared error (RMSE) of the hybrid model can be reduced, on the average, by up to 40 percent. Particularly, the high PM2.5 days are almost anticipated by using wavelet decomposition and the detection rate (DR) for a given alert threshold of hybrid model can reach 90% on average. This approach shows the potential to be applied in other countries' air quality forecasting systems.

  19. Dust and Pollution Aerosol Air Mass Mapping from Satellite Multi-angle Imaging

    NASA Astrophysics Data System (ADS)

    Kahn, R. A.; Nelson, D. L.; Yau, K. S.; Martonchik, J.; Diner, D. J.; Gaitley, B. J.; Russell, P.; Livingston, J.; Redemann, J.; Quinn, P. R.; Clarke, A. R.; Howell, S.; McNaughton, C.; Reid, J.; Holben, B.; Wendisch, M.; Petzold, A.

    2006-12-01

    One objective of the NASA Earth Observing System's Multi-angle Imaging SpectroRadiometer (MISR) is to map aerosol air mass types, based on retrieved column-average particle microphysical properties. Early results demonstrated the ability to distinguish three-to-five bins over the 0.1 to 2.5 micron aerosol size range, about two-to-four groupings of single-scattering albedo, and to separate spherical from randomly oriented non- spherical particles, under good but not ideal viewing conditions. These results relied heavily on the MISR Research Aerosol Retrieval algorithm, which allows flexibility in choosing retrieval patch size and location, component aerosol properties and mixtures, and mixture acceptance criteria, compared to early versions of the MISR Standard algorithm, designed to routinely process the entire global data set. Early mid-visible column aerosol optical depth results were validated against surface-based sun photometer measurements. The corresponding particle property results appeared qualitatively promising, but formal validation requires quantitative constraints on component particle properties and mixtures in a range of natural settings, available mainly from the combination of height-resolved and total column data collected by surface and airborne instruments during field campaigns. This presentation will highlight the latest detailed, multi-platform case studies, as well as MISR regional mapping, of smoke, Saharan dust, and mixtures of pollution aerosol and desert dust collected during the INTEX, SAMUM, and UAE-2 campaigns, respectively. The broader implications of these results for global, and especially regional, aerosol climate and air quality studies will also be discussed. This work is performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract with the National Aeronautics and Space Administration.

  20. Air temperature variability over three glaciers in the Ortles-Cevedale (Italian Alps): effects of glacier fragmentation, comparison of calculation methods, and impacts on mass balance modeling

    NASA Astrophysics Data System (ADS)

    Carturan, L.; Cazorzi, F.; De Blasi, F.; Dalla Fontana, G.

    2015-05-01

    Glacier mass balance models rely on accurate spatial calculation of input data, in particular air temperature. Lower temperatures (the so-called glacier cooling effect) and lower temperature variability (the so-called glacier damping effect) generally occur over glaciers compared to ambient conditions. These effects, which depend on the geometric characteristics of glaciers and display a high spatial and temporal variability, have been mostly investigated on medium to large glaciers so far, while observations on smaller ice bodies (< 0.5 km2) are scarce. Using a data set from eight on-glacier and four off-glacier weather stations, collected in the summers of 2010 and 2011, we analyzed the air temperature variability and wind regime over three different glaciers in the Ortles-Cevedale. The magnitude of the cooling effect and the occurrence of katabatic boundary layer (KBL) processes showed remarkable differences among the three ice bodies, suggesting the likely existence of important reinforcing mechanisms during glacier decay and fragmentation. The methods proposed by Greuell and Bohm (1998) and Shea and Moore (2010) for calculating on-glacier temperature from off-glacier data did not fully reproduce our observations. Among them, the more physically based procedure of Greuell and Bohm (1998) provided the best overall results where the KBL prevails, but it was not effective elsewhere (i.e., on smaller ice bodies and close to the glacier margins). The accuracy of air temperature estimations strongly impacted the results from a mass balance model which was applied to the three investigated glaciers. Most importantly, even small temperature deviations caused distortions in parameter calibration, thus compromising the model generalizability.

  1. Air temperature variability over three glaciers in the Ortles-Cevedale (Italian Alps): effects of glacier disintegration, intercomparison of calculation methods, and impacts on mass balance modeling

    NASA Astrophysics Data System (ADS)

    Carturan, L.; Cazorzi, F.; De Blasi, F.; Dalla Fontana, G.

    2014-12-01

    Glacier mass balance models rely on accurate spatial calculation of input data, in particular air temperature. Lower temperatures (the so-called glacier cooling effect), and lower temperature variability (the so-called glacier damping effect) generally occur over glaciers, compared to ambient conditions. These effects, which depend on the geometric characteristics of glaciers and display a high spatial and temporal variability, have been mostly investigated on medium- to large-size glaciers so far, while observations on smaller ice bodies are scarce. Using a dataset from 8 on-glacier and 4 off-glacier weather stations, collected in summer 2010 and 2011, we analyzed the air temperature variability and wind regime over three different glaciers in the Ortles-Cevedale. The magnitude of the cooling effect and the occurrence of katabatic boundary layer (KBL) processes showed remarkable differences among the three ice bodies, suggesting the likely existence of important reinforcing mechanisms during glacier decay and disintegration. None of the methods proposed in the literature for calculating on-glacier temperature from off-glacier data fully reproduced our observations. Among them, the more physically-based procedure of Greuell and Böhm (1998) provided the best overall results where the KBL prevail, but it was not effective elsewhere (i.e. on smaller ice bodies and close to the glacier margins). The accuracy of air temperature estimations strongly impacted the results from a mass balance model which was applied to the three investigated glaciers. Most importantly, even small temperature deviations caused distortions in parameter calibration, thus compromising the model generalizability.

  2. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 3

    NASA Technical Reports Server (NTRS)

    Blakeslee, A. E.; Hovel, H. J.; Woodall, J. M.

    1977-01-01

    The etch-back epitaxy process is described for producing thin, graded composition GaAlAs layers. The palladium-aluminum contact system is discussed along with its associated problems. Recent solar cell results under simulated air mass zero light and at elevated temperatures are reported and the growth of thin polycrystalline GaAs films on foreign substrates is developed.

  3. An objective classification system of air mass types for Szeged, Hungary, with special attention to plant pollen levels.

    PubMed

    Makra, László; Juhász, Miklós; Mika, János; Bartzokas, Aristides; Béczi, Rita; Sümeghy, Zoltán

    2006-07-01

    This paper discusses the characteristic air mass types over the Carpathian Basin in relation to plant pollen levels over annual pollination periods. Based on the European Centre for Medium-Range Weather Forecasts dataset, daily sea-level pressure fields analysed at 00 UTC were prepared for each air mass type (cluster) in order to relate sea-level pressure patterns to pollen levels in Szeged, Hungary. The database comprises daily values of 12 meteorological parameters and daily pollen concentrations of 24 species for their pollination periods from 1997 to 2001. Characteristic air mass types were objectively defined via factor analysis and cluster analysis. According to the results, nine air mass types (clusters) were detected for pollination periods of the year corresponding to pollen levels that appear with higher concentration when irradiance is moderate while wind speed is moderate or high. This is the case when an anticyclone prevails in the region west of the Carpathian Basin and when Hungary is under the influence of zonal currents (wind speed is high). The sea level pressure systems associated with low pollen concentrations are mostly similar to those connected to higher pollen concentrations, and arise when wind speed is low or moderate. Low pollen levels occur when an anticyclone prevails in the region west of the Carpathian Basin, as well as when an anticyclone covers the region with Hungary at its centre. Hence, anticyclonic or anticyclonic ridge weather situations seem to be relevant in classifying pollen levels. PMID:16575583

  4. Representing the Effects of Long-Range Transport and Lateral Boundary Conditions in Regional Air Pollution Models

    EPA Science Inventory

    The Community Multiscale Air Quality (CMAQ) modeling system was applied to a domain covering the northern hemisphere; meteorological information was derived from the Weather Research and Forecasting (WRF) model run on identical grid and projection configuration, while the emissio...

  5. THE PROCESS OF MASS TRANSFER ON THE SOLID-LIQUID BOUNDARY LAYER DURING THE RELEASE OF DICLOFENAC SODIUM AND PAPAVERINE HYDROCHLORIDE FROM TABLETS IN A PADDLE APPARATUS.

    PubMed

    Kasperek, Regina; Zimmer, Lukasz; Poleszak, Ewa

    2016-01-01

    The release study of diclofenac sodium (DIC) and papaverine hydrochloride (PAP) from two formulations of the tablets in the paddle apparatus using different rotation speeds to characterize the process of mass transfer on the solid-liquid boundary layer was carried out. The dissolution process of active substances was described by values of mass transfer coefficients, the diffusion boundary layer thickness and dimensionless numbers (Sh and Re). The values of calculated parameters showed that the release of DIC and PAP from tablets comprising potato starch proceeded faster than from tablets containing HPMC and microcrystalline cellulose. They were obtained by direct dependencies between Sh and Re in the range from 75 rpm to 125 rpm for both substances from all tablets. The description of the dissolution process with the dimensionless numbers make it possible to plan the drug with the required release profile under given in vitro conditions. PMID:27008811

  6. Background NO/sub x/ mixing ratios in air masses over the North Atlantic ocean

    SciTech Connect

    Helas, G.; Warneck, P.

    1981-08-20

    A chemiluminescence analyzer was used to measure NO/sub x/ mixing ratios at the west coast of Ireland. Two measurement modes allowed the determination of NO and NO/sub x/ = NO+NO/sub 2/. In a third mode using a molybdenum converter, higher signals were observed than was in the second mode indicating that nitrogen compounds other than NO+NO/sub 2/ are registered. They are denoted 'excess NO/sub x/'. The average NO/sub 2/ mixing ratio for a week period was 101 +- 87 pptv. In pure marine air masses identified by means of trajectory calculations, the NO/sub 2/ mixing ratios were lower and exhibited in addition a diurnal variation with nighttime values of 37 +- 6 pptv and average values of 87 +- 47 pptv. Possible origins of the diurnal variation are discussed. For such conditions, the NO mixing ratio generally was unmeasurably small, certainly less than 10 pptv. The excess NO/sub x/ is also higher during the day compared with nighttime values of about 70 pptv. Further studies are required to identify the compounds involved.

  7. Variations of the glacio-marine air mass front in West Greenland through water vapor isotopes

    NASA Astrophysics Data System (ADS)

    Kopec, B. G.; Lauder, A. M.; Posmentier, E. S.; Feng, X.

    2012-12-01

    While the isotopic distribution of precipitation has been widely used for research in hydrology, paleoclimatology, and ecology for decades, intensive isotopic studies of atmospheric water vapor has only recently been made possible by spectral-based technology. New instrumentation based on this technology opens up many opportunities to investigate short-term atmospheric dynamics involving the water cycle and moisture transport. We deployed a Los Gatos Water Vapor Isotope Analyzer (WVIA) at Kangerlussuaq, Greenland from July 21 to August 15, and measured the water vapor concentration and its isotopic ratios continuously at 10s intervals. A Danish Meteorological Institute site is located about 1 km from the site of the deployment, and meteorological data is collected at 30 min intervals. During the observation period, the vapor concentration of the ambient air ranges from 5608.4 to 11189.4 ppm; dD and d18O range from -254.5 to -177.7 ‰ and -34.2 to -23.2 ‰, respectively. The vapor content (dew point) and the isotopic ratios are both strongly controlled by the wind direction. The easterly winds are associated with dry, isotopically depleted air masses formed over the glacier, while westerly winds are associated with moist and isotopically enriched air masses from the marine/fjord surface. This region typically experiences katabatic winds off of the ice sheet to the east. However, during some afternoons, the wind shifts 180 degrees, blowing off the fjord to the west. This wind switch marks the onset of a sea breeze, and significant isotopic enrichment results. Enrichment in deuterium is up to 60 ‰ with a mean of 15‰, and oxygen-18 is enriched by 3‰ on average and up to 8 ‰. Other afternoons have no change in wind, and only small changes in humidity and vapor isotopic ratios. The humidity and isotopic variations suggest the local atmosphere circulation is dominated by relatively high-pressure systems above the cold glaciers and cool sea surface, and diurnal

  8. New Directions: Questions surrounding suspended particle mass used as a surrogate for air quality and for regulatory control of ambient urban air pollution

    NASA Astrophysics Data System (ADS)

    Hoare, John L.

    2014-07-01

    The original choice of particulate matter mass (PM) as a realistic surrogate for gross air pollution has gradually evolved into routine use nowadays of epidemiologically-based estimates of the monetary and other benefits expected from regulating urban air quality. Unfortunately, the statistical associations facilitating such calculations usually are based on single indices of air pollution whereas the health effects themselves are more broadly based causally. For this and other reasons the economic benefits of control tend to be exaggerated. Primarily because of their assumed inherently inferior respirability, particles ≥10 μm are generally excluded from such considerations. Where the particles themselves are chemically heterogeneous, as in an urban context, this may be inappropriate. Clearly all air-borne particles, whether coarse or fine, are susceptible to inhalation. Hence, the possibility exists for any adhering potentially harmful semi-volatile substances to be subsequently de-sorbed in vivo thereby facilitating their transport deeper into the lungs. Consequently, this alone may be a sufficient reason for including rather than rejecting during air quality monitoring the relatively coarse 10-100 μm particle fraction, ideally in conjunction with routine estimation of the gaseous co-pollutants thereby facilitating a multi-pollutant approach apropos regulation.

  9. Integral solutions to transient nonlinear heat (mass) diffusion with a power-law diffusivity: a semi-infinite medium with fixed boundary conditions

    NASA Astrophysics Data System (ADS)

    Hristov, Jordan

    2016-03-01

    Closed form approximate solutions to nonlinear heat (mass) diffusion equation with power-law nonlinearity of the thermal (mass) diffusivity have been developed by the integral-balance method avoiding the commonly used linearization by the Kirchhoff transformation. The main improvement of the solution is based on the double-integration technique and a new approach to the space derivative. Solutions to Dirichlet and Neumann boundary condition problems have been developed and benchmarked against exact numerical and approximate analytical solutions available in the literature.

  10. The impact of mass flow and masking on the pressure drop of air filter in heavy-duty diesel engine

    NASA Astrophysics Data System (ADS)

    Hoseeinzadeh, Sepideh; Gorji-Bandpy, Mofid

    2012-04-01

    This paper presents a computational fluid dynamics (CFD) calculation approach to predict and evaluate the impact of the mass-flow inlet on the pressure drop of turbocharger`s air filtfer in heavy-duty diesel engine. The numerical computations were carried out using a commercial CFD program whereas the inlet area of the air filter consisted of several holes connected to a channel. After entering through the channel, the air passes among the holes and enters the air filter. The effect of masking holes and hydraulic diameter is studied and investigated on pressure drop. The results indicate that pressure drop increase with decreasing of hydraulic diameter and masking of the holes has considerable affect on the pressure drop.

  11. Evaluation of regional climate - air quality simulations over Europe for the period 1996-2006 with emphasis on tropospheric ozone: The impact of chemical boundary conditions

    NASA Astrophysics Data System (ADS)

    Akritidis, D.; Zanis, P.; Katragkou, E.; Tegoulias, I.; Poupkou, A.; Markakis, K.; Karacostas, Th.; Pytharoulis, I.

    2012-04-01

    A modeling system based on the air quality model CAMx driven off-line by the regional climate model RegCM3 is used for assessing the impact of lateral boundary conditions on tropospheric ozone over Europe for the period 1996-2006. The RegCM3 and CAMx simulations were performed on a 50 km x 50 km grid over Europe with RegCM3 driven by NCEP reanalysis fields. Average monthly concentration values obtained from the global chemistry climate model ECHAM5-MOZ were used as chemical boundary conditions for the CAMx simulations. The present period (1996-2006) was simulated two times. The first run (clean) was forced from constant lateral chemical boundary conditions and constant emissions based on the EMEP emissions of the year 1996. The second simulation (run1) was based on ECHAM5-MOZ chemical boundary conditions and emissions fixed for the year 1996. In order to evaluate the ability of the RegCM3/CAMx modeling system, simulated ozone concentrations are compared against near surface ozone measurements from the EMEP network. Since many of the stations of the EMEP network were not operating continuously during the time period of our study (1996-2006), we have used in the evaluation analysis only those stations that fulfill the criteria of 75% data availability for near surface ozone, choosing 87 stations from 23 European countries. Various statistical metrics are used for the model evaluation, including correlation coefficient (R), normalized standard deviation (NSD) and modified normalized mean bias (MNMB). The different lateral boundary conditions forcing resulted in changes of near surface ozone concentrations and variability. Using lateral boundary conditions obtained from the global chemistry climate model ECHAM5-MOZ (run1), the RegCM3/CAMx modeling system is capturing in a much better way the ozone monthly variability than using constant lateral boundary conditions (clean), especially for stations of northern and northwestern Europe. Concerning the correlation between

  12. Inter-annual variability of air mass and acidified pollutants transboundary exchange in the north-eastern part of the EANET region

    NASA Astrophysics Data System (ADS)

    Gromov, Sergey A.; Trifonova-Yakovleva, Alisa; Gromov, Sergey S.

    2016-04-01

    Anthropogenic emissions, be it exhaust gases or aerosols, stem from multitude of sources and may survive long-range transport within the air masses they were emitted into. So they follow regional and global transport pathways varying under different climatological regimes. Transboundary transfer of pollutants occurs this way and has a significant impact on the ecological situation of the territories neighbouring those of emission sources, as found in a few earlier studies examining the environmental monitoring data [1]. In this study, we employ a relatively facile though robust technique for estimating the transboundary air and concomitant pollutant fluxes using actual or climatological meteorological and air pollution monitoring data. Practically, we assume pollutant transfer being proportional to the horizontal transport of air enclosed in the lower troposphere and to the concentration of the pollutant of interest. The horizontal transport, in turn, is estimated using the mean layer wind direction and strength, or their descriptive statistics at the individual transects of the boundary of interest. The domain of our interest is the segment of Russian continental border in East Asia spanning from 88° E (southern Middle Siberia) to 135° E (Far East at Pacific shore). The data on atmospheric pollutants concentration are available from the Russian monitoring sites of the region-wide Acid Deposition Monitoring Network in East Asia (EANET, http://www.eanet.asia/) Mondy (Baikal area) and Primorskaya (near Vladivostok). The data comprises multi-year continuous measurement of gas-phase and particulate species abundances in air with at least biweekly sampling rate starting from 2000. In the first phase of our study, we used climatological dataset on winds derived from the aerological soundings at Russian stations along the continental border for the 10-year period (1961-1970) by the Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) [3

  13. Cluster Analysis of the Organic Peaks in Bulk Mass Spectra Obtained During the 2002 New England Air Quality Study with an Aerodyne Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M.; Bertman, S. B.; Middlebrook, A. M.

    2006-12-01

    We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel R. H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter probably originating from both anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent on average 17% of the total organic mass that stems likely from biogenic sources during the ship's cruise. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

  14. The China Clipper - Fast advective transport of radon-rich air from the Asian boundary layer to the upper troposphere near California

    NASA Technical Reports Server (NTRS)

    Kritz, Mark A.; Le Roulley, Jean-Claude; Danielsen, Edwin F.

    1990-01-01

    A series of upper tropospheric radon concentration measurements made over the eastern Pacific and west coast of the U.S. during the summers of 1983 and 1984 has revealed the occurrence of unexpectedly high radon concentrations for 9 of the 61 measurements. A frequency distribution plot of the set of 61 observations shows a distinct bimodal distribution, with approximately 2/5 of the observations falling close to 1 pCi/SCM, and 3/5 falling in a high concentration mode centered at about 11 pCi/SCM. Trajectory and synoptic analyses for two of the flights on which such high radon concentrations were observed indicate that this radon-rich air originated in the Asian boundary layer, ascended in cumulus updrafts, and was carried eastward in the fast moving air on the anticyclonic side of the upper tropospheric jet. The results suggest that the combination of rapid vertical transport from the surface boundary layer to the upper troposphere, followed by rapid horizontal transport eastward represents an efficient mode of long-transport for other, chemically reactive atmospheric trace constituents.

  15. Senstitivity analysis of horizontal heat and vapor transfer coefficients for a cloud-topped marine boundary layer during cold-air outbreaks. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Chang, Y. V.

    1986-01-01

    The effects of external parameters on the surface heat and vapor fluxes into the marine atmospheric boundary layer (MABL) during cold-air outbreaks are investigated using the numerical model of Stage and Businger (1981a). These fluxes are nondimensionalized using the horizontal heat (g1) and vapor (g2) transfer coefficient method first suggested by Chou and Atlas (1982) and further formulated by Stage (1983a). In order to simplify the problem, the boundary layer is assumed to be well mixed and horizontally homogeneous, and to have linear shoreline soundings of equivalent potential temperature and mixing ratio. Modifications of initial surface flux estimates, time step limitation, and termination conditions are made to the MABL model to obtain accurate computations. The dependence of g1 and g2 in the cloud topped boundary layer on the external parameters (wind speed, divergence, sea surface temperature, radiative sky temperature, cloud top radiation cooling, and initial shoreline soundings of temperature, and mixing ratio) is studied by a sensitivity analysis, which shows that the uncertainties of horizontal transfer coefficients caused by changes in the parameters are reasonably small.

  16. The Turbulent Boundary Layer Near the Air-Water Interface on a Surface-Piercing Flat Plate

    NASA Astrophysics Data System (ADS)

    Washuta, Nathan; Masnadi, Naeem; Duncan, James H.

    2015-11-01

    Turbulent fluctuations in the vicinity of the water free surface along a flat, vertically oriented surface-piercing plate are studied experimentally using a laboratory-scale experiment. In this experiment, a meter-wide stainless steel belt travels horizontally in a loop around two rollers with vertically oriented axes, which are separated by 7.5 meters. This belt device is mounted inside a large water tank with the water level set just below the top edge of the belt. The belt, rollers, and supporting frame are contained within a sheet metal box to keep the device dry except for one 6-meter-long straight test section between rollers. The belt is launched from rest with a 3- g acceleration in order to quickly reach steady state velocity. This creates a temporally evolving boundary layer analogous to the spatially evolving boundary layer created along a flat-sided ship moving at the same velocity, with a length equivalent to the length of belt that has passed the measurement region since the belt motion began. Cinematic Stereo PIV measurements are performed in planes parallel to the free surface by imaging the flow from underneath the tank in order to study the modification of the boundary layer flow field due to the effects of the water free surface. The support of the Office of Naval Research under grant N000141110029 is gratefully acknowledged.

  17. Chiral Signatures of Anthropogenic Semi-Volatile Organic Compounds in Asian, trans- Pacific, and Pacific Northwestern Air Masses

    NASA Astrophysics Data System (ADS)

    Genualdi, S.; Primbs, T.; Bidleman, T.; Jantunen, L.; Simonich, S.

    2006-12-01

    The goal of this research is to use the chiral signatures of Semi-Volatile Organic Compounds (SOCs) to distinguish between new and old sources in Asian, trans-Pacific, and regional air masses. During 2004, a six week air sampling campaign was conducted at a remote site in Okinawa, Japan to determine the chemical composition of Eurasian air masses. During 2003 and 2004, high volume air samples were collected at three different locations in the Pacific Northwest of the United States. These sampling locations were; Mary's Peak Observatory (MPO) located at 1250m in the Oregon Coast Range, Mt. Bachelor located at 2800m in Oregon's Cascade Range, and Cheeka Peak Observatory (CPO) located at 500m in the state of Washington. The air samples consisted of both polyurethane foam and XAD-2 resin to collect the gas phase SOCs, and glass fiber filters to collect the particulate phase SOCs. The samples were extracted using accelerated solvent extraction and enantiomer fractions were determined using GCMS-ECNI with the use of a BGB Analytik chiral column. The chiral SOCs, á-Hexachlorocyclohexane, cis and trans chlordane, heptachlor epoxide, and o'p' DDT, were measured, the enantiomer ratios were determined, and potential new and historical sources of these compounds were identified.

  18. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    SciTech Connect

    Morrison, Glenn C.

    1999-12-01

    {sup {minus}7}, 10{sup {minus}5}, and 10{sup {minus}5} respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10{sup {minus}5}, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.

  19. Experimental Evaluation of the Effect of Angle-of-attack on the External Aerodynamics and Mass Capture of a Symmetric Three-engine Air-breathing Launch Vehicle Configuration at Supersonic Speeds

    NASA Technical Reports Server (NTRS)

    Kim, Hyun D.; Frate, Franco C.

    2001-01-01

    A subscale aerodynamic model of the GTX air-breathing launch vehicle was tested at NASA Glenn Research Center's 10- by 10-Foot Supersonic Wind Tunnel from Mach 2.0 to 3.5 at various angles-of-attack. The objective of the test was to investigate the effect of angle-of-attack on inlet mass capture, inlet diverter effectiveness, and the flowfield at the cowl lip plane. The flow-through inlets were tested with and without boundary-layer diverters. Quantitative measurements such as inlet mass flow rates and pitot-pressure distributions in the cowl lip plane are presented. At a 3deg angle-of-attack, the flow rates for the top and side inlets were within 8 percent of the zero angle-of-attack value, and little distortion was evident at the cowl lip plane. Surface oil flow patterns showing the shock/boundary-layer interaction caused by the inlet spikes are shown. In addition to inlet data, vehicle forebody static pressure distributions, boundary-layer profiles, and temperature-sensitive paint images to evaluate the boundary-layer transition are presented. Three-dimensional parabolized Navier-Stokes computational fluid dynamics calculations of the forebody flowfield are presented and show good agreement with the experimental static pressure distributions and boundary-layer profiles. With the boundary-layer diverters installed, no adverse aerodynamic phenomena were found that would prevent the inlets from operating at the required angles-of-attack. We recommend that phase 2 of the test program be initiated, where inlet contraction ratio and diverter geometry variations will be tested.

  20. Influence of the ozone profile above Madrid (Spain) on Brewer estimation of ozone air mass factor

    NASA Astrophysics Data System (ADS)

    Antón, M.; López, M.; Costa, M. J.; Serrano, A.; Bortoli, D.; Bañón, M.; Vilaplana, J. M.; Silva, A. M.

    2009-08-01

    The methodology used by Brewer spectroradiometers to estimate the ozone column is based on differential absorption spectroscopy. This methodology employs the ozone air mass factor (AMF) to derive the total ozone column from the slant path ozone amount. For the calculating the ozone AMF, the Brewer algorithm assumes that the ozone layer is located at a fixed height of 22 km. However, for a real specific site the ozone presents a certain profile, which varies spatially and temporally depending on the latitude, altitude and dynamical conditions of the atmosphere above the site of measurements. In this sense, this work address the reliability of the mentioned assumption and analyses the influence of the ozone profiles measured above Madrid (Spain) in the ozone AMF calculations. The approximated ozone AMF used by the Brewer algorithm is compared with simulations obtained using the libRadtran radiative transfer model code. The results show an excellent agreement between the simulated and the approximated AMF values for solar zenith angle lower than 75°. In addition, the relative differences remain lower than 2% at 85°. These good results are mainly due to the fact that the altitude of the ozone layer assumed constant by the Brewer algorithm for all latitudes notably can be considered representative of the real profile of ozone above Madrid (average value of 21.7±1.8 km). The operational ozone AMF calculations for Brewer instruments are limited, in general, to SZA below 80°. Extending the usable SZA range is especially relevant for Brewer instruments located at high mid-latitudes.

  1. Self-similar analysis of fluid flow and heat-mass transfer of nanofluids in boundary layer

    NASA Astrophysics Data System (ADS)

    Avramenko, A. A.; Blinov, D. G.; Shevchuk, I. V.

    2011-08-01

    Processes of heat, momentum, and concentration transport in a boundary layer of a nanofluid near a flat wall were studied. The study was performed by means of numerical analysis of boundary layer equations in a self-similar form. Self-similar forms of these equations were obtained based on symmetry properties (Lie groups). In doing so, dependence of physical properties (viscosity, thermal conductivity, and diffusion coefficient) on concentration of nanofluids and temperature were taken into account. Effects of concentration of the nano-particles on velocity and temperature profiles, as well as on the relative Nusselt numbers and skin-friction coefficients, were elucidated.

  2. Measurements of Pb-212 and Pb-214 in surface air around Lake Michigan and their implications for atmospheric boundary layer mixing

    NASA Astrophysics Data System (ADS)

    Aquino, Nadja Wackerling

    1997-10-01

    The dynamics of the atmospheric boundary layer are a result of turbulence generated at the Earth's surface. The extent of mixing in the boundary layer is studied by using radionuclides as tracers under different conditions such as: wind direction dependent on passing synoptic systems, upwind and downwind lake shore sites, urban versus rural setting, and urban setting at two different altitudes. Data were collected by high volume air samplers at each site, which filtered air for day and night intervals several days in a row. The filters were placed in a GeLe detector and gamma rays of 212Pb and 214Pb decays were counted. From these measurements, the concentrations of 212Pb and 214Pb in the sampled air were determined. Among the types of radionuclide behavior are diurnal variation in activities, synoptic-scale variation, variation due to different surface roughness characteristics and position with respect to the wind at the lake shore, and limited variation in activity at high altitude at the urban site. A series of one dimensional models were developed to interpret the data. The horizontal advection model predicted the effect on 212Pb and 214Pb activities of advecting air over a 100 km zero source region at constant velocity. 212Pb activities decrease substantially for velocities greater than 1 m/s, whereas 214Pb does not decrease much until velocities reach 100 m/s. The vertical diffusion model predicted 212Pb and 214Pb vertical profiles for different vertical diffusivities, κ z. A one order of magnitude change in κ z produces a /sqrt[10] change in activity in surface air. The results of both models are equivalent for 212Pb activities. Comparing 212Pb and 214Pb, vertical mixing affects both radionuclides similarly, but horizontal advection fractionates the two radionuclides. The diurnal box models predict activities an order of magnitude lower than the steady state models, in close agreement with observations. Furthermore, an order of magnitude increase can

  3. Thermophoretically enhanced mass transport rates to solid and transpiration-cooled walls across turbulent (law-of-the-wall) boundary layers

    NASA Technical Reports Server (NTRS)

    Gokoglu, Suleyman A.; Rosner, Daniel E.

    1985-01-01

    Convective-diffusion mass transfer rate predictions are made for both solid wall and transpiration-cooled 'law-of-the-wall' nonisothermal turbulent boundary layers (TBLs), including the mechanism of thermophoresis, i.e., small particle mass transport 'down a temperature gradient'. The present calculations are confined to low mass-loading situations but span the entire particle size range from vapor molecules to particles near the onset of inertial ('eddy') impaction. It is shown that, when Sc is much greater than 1, thermophoresis greatly increases particle deposition rates to internally cooled solid walls, but only partially offsets the appreciable reduction in deposition rates associated with dust-free gas-transpiration-cooled surfaces. Thus, efficient particle sampling from hot dusty gases can be carried out using transpiration 'shielded' probe surfaces.

  4. Angularly symmetric splitting of a light beam upon reflection and refraction at an air-dielectric plane boundary: reply.

    PubMed

    Azzam, R M A

    2016-05-01

    The simplified explicit expressions derived by Andersen [J. Opt. Soc. Am. A33, 984 (2016)JOAOD60740-323210.1364/JOSAA.32.000984], that relate to angularly symmetric beam splitting by reflection and refraction at an air-dielectric interface recently described by Azzam [J. Opt. Soc. Am. A32, 2436 (2015)JOAOD60740-323210.1364/JOSAA.32.002436], are welcome. A few additional remarks are also included in my reply to Andersen's comment. PMID:27140898

  5. Determination of respirable mass concentration using a high volume air sampler and a sedimentation method for fractionation

    SciTech Connect

    Johnson, J.

    1995-12-31

    A preliminary study of a new method for determining respirable mass concentration is described. This method uses a high volume air sampler and subsequent fractionation of the collected mass using a particle sedimentation technique. Side-by-side comparisons of this method with cyclones were made in the field and in the laboratory. There was good agreement among the samplers in the laboratory, but poor agreement in the field. The effect of wind on the samplers` capture efficiencies is the primary hypothesized source of error among the field results. The field test took place at the construction site of a hazardous waste landfill located on the Hanford Reservation.

  6. Boundary lubrication of formulated C-ether in air to 300 deg C. 1: Phosphorus ester additives

    NASA Technical Reports Server (NTRS)

    Jones, W. R., Jr.; Hady, W. F.

    1972-01-01

    Friction and wear measurements were made on CVM M-50 steel lubricated with three C-ether (modified polyphenyl ether) formulations in dry and wet air. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, a 17-meter-perminute (100-rpm) surface speed, and a 25 to 300 C (77 to 572 F) disk temperature range. The C-ether base fluid and the three formulated C-ether fluids yielded lower wear than the Type 2 ester over the entire temperature range. All C-ether fluids exhibited slightly higher friction coefficients than the ester from 150 to 300 C (302 to 572 F) and similar values from 25 to 150 C (77 to 302 F). In general, lower wear rates were observed with the C-ethers when tested in wet air as compared to a dry air atmosphere.

  7. Calculations of relative optical air masses for various aerosol types and minor gases in Arctic and Antarctic atmospheres

    NASA Astrophysics Data System (ADS)

    Tomasi, Claudio; Petkov, Boyan H.

    2014-02-01

    The dependence functions of relative optical air mass on apparent solar zenith angle θ have been calculated over the θ < 87° range for the vertical profiles of wet-air molecular number density in the Arctic and Antarctic atmospheres, extinction coefficients of different aerosol types, and molecular number density of water vapor, ozone, nitrogen dioxide, and oxygen dimer. The calculations were made using as weight functions the seasonal average vertical profiles of (i) pressure and temperature derived from multiyear sets of radiosounding measurements performed at Ny-Ålesund, Alert, Mario Zucchelli, and Neumayer stations; (ii) volume extinction coefficients of background summer aerosol, Arctic haze, and Kasatochi and Pinatubo volcanic aerosol measured with lidars or balloon-borne samplings; and (iii) molecular number concentrations of the above minor gases, derived from radiosonde, ozonesonde, and satellite-based observations. The air mass values were determined using a formula based on a realistic atmospheric air-refraction model. They were systematically checked by comparing their mutual differences with the uncertainties arising from the seasonal and daily variations in pressure and temperature conditions within the various ranges, where aerosol and gases attenuate the solar radiation most efficiently. The results provide evidence that secant-approximated and midlatitude air mass values are inappropriate for analyzing the Sun photometer measurements performed at polar sites. They indicate that the present evaluations can be reliably used to estimate the aerosol optical depth from the Arctic and Antarctic measurements of total optical depth, after appropriate corrections for the Rayleigh scattering and gaseous absorption optical depths.

  8. Screening for sarin in air and water by solid-phase microextraction-gas chromatography/mass spectrometry.

    SciTech Connect

    Schneider, J. F.; Boparai, A. S.; Reed, L. L.

    2001-10-01

    A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 {mu}g/mL or higher. This method is ideal for screening samples for quick response situations.

  9. On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2013-02-01

    Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

  10. On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2014-02-01

    Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

  11. On the Aerosol Particle Size Distribution Spectrum in Alaskan Air Mass Systems: Arctic Haze and Non-Haze Episodes.

    NASA Astrophysics Data System (ADS)

    Shaw, Glenn E.

    1983-05-01

    Aerosols in central Alaskan winter air mass system were classified according to size by diffusive separation and light-scattering spectrometry. Particles entering central Alaska from the Pacific Marine environment had number concentrations ranging from 300 to 2000 cm3 (geometric mean 685 cm3) and unimodal size spectra, with maximum in number concentration near 1 × 106 cm radius.Air masses entering Alaska from the Eurasian Arctic possessed a factor of two smaller aerosol number concentrations than Pacific Marine systems (e.g., 150-700 cm3; geometric mean 386 cm3) but contained a factor of two greater particle volume loading within the fine particle radius range 5 × 107 < r < 1 × 105 cm. The particles in Eurasian Arctic air masses were bimodally distributed, with maxima in the particle size spectra near r = 3 × 107 and 5 × 106 cm. Sulfur was the predominant element in all cases studied.A particle depleted region was present in the size spectra obtained for Eurasian Arctic air masses. The deficiency of particles in the 106 cm radius range is interpreted as being the result of thermal coagulation taking place between sulfur-rich nuclei (produced at a rate of 1020 to 1018 g cm3 s1 and in sizes r < 106 cm) and `large' (r 105 cm) imported primary particles. The primary particles are in the removal-resistant Greenfield Gap (r 105 cm) and seem to originate in the central Eurasian region.

  12. Influence of power ultrasound application on mass transport and microstructure of orange peel during hot air drying

    NASA Astrophysics Data System (ADS)

    Ortuño, Carmen; Pérez-Munuera, Isabel; Puig, Ana; Riera, Enrique; Garcia-Perez, J. V.

    2010-01-01

    Power ultrasound application on convective drying of foodstuffs may be considered an emergent technology. This work deals with the influence of power ultrasound on drying of natural materials addressing the kinetic as well as the product's microstructure. Convective drying kinetics of orange peel slabs (thickness 5.95±0.41 mm) were carried out at 40 ∘C and 1 m/s with (US) and without (AIR) power ultrasound application. A diffusion model considering external resistance to mass transfer was considered to describe drying kinetics. Fresh, US and AIR dried samples were analyzed using Cryo-SEM. Results showed that drying kinetics of orange peel were significantly improved by the application of power ultrasound. From modeling, it was observed a significant (p¡0.05) increase in both mass transfer coefficient and effective moisture diffusivity. The effects on mass transfer properties were confirmed from microestructural observations. In the cuticle surface, the pores were obstructed by wax components scattering, which evidence the ultrasonic effects on the interfaces. The cells of the flavedo were compressed and large intercellular air spaces were generated in the albedo facilitating water transfer through it.

  13. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

    PubMed Central

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-01-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

  14. Some Observational and Modeling Studies of the Atmospheric Boundary Layer at Mississippi Gulf Coast for Air Pollution Dispersion Assessment

    PubMed Central

    Yerramilli, Anjaneyulu; Challa, Venkata Srinivas; Indracanti, Jayakumar; Dasari, Hariprasad; Baham, Julius; Patrick, Chuck; Young, John; Hughes, Robert; White, Lorren D.; Hardy, Mark G.; Swanier, Shelton

    2008-01-01

    Coastal atmospheric conditions widely vary from those over inland due to the land-sea interface, temperature contrast and the consequent development of local circulations. In this study a field meteorological experiment was conducted to measure vertical structure of boundary layer during the period 25–29 June, 2007 at three locations Seabee base, Harrison and Wiggins sites in the Mississippi coast. A GPS Sonde along with slow ascent helium balloon and automated weather stations equipped with slow and fast response sensors were used in the experiment. GPS sonde were launched at three specific times (0700 LT, 1300 LT and 1800 LT) during the experiment days. The observations indicate shallow boundary layer near the coast which gradually develops inland. The weather research and forecasting (WRF) meso-scale atmospheric model and a Lagrangian particle dispersion model (HYSPLIT) are used to simulate the lower atmospheric flow and dispersion in a range of 100 km from the coast for 28–30 June, 2007. The simulated meteorological parameters were compared with the experimental observations. The meso-scale model results show significant temporal and spatial variations in the meteorological fields as a result of development of sea breeze flow, its coupling with the large scale flow field and the ensuing alteration in the mixing depth across the coast. Simulated ground-level concentrations of SO2 from four elevated point sources located along the coast indicate diurnal variation and impact of the local sea-land breeze on the direction of the plume. Model concentration levels were highest during the stable morning condition and during the sea-breeze time in the afternoon. The highest concentrations were found up to 40 km inland during sea breeze time. The study illustrates the application of field meteorological observations for the validation of WRF which is coupled to HYSPLIT for dispersion assessment in the coastal region. PMID:19151446

  15. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  16. Chemical compositions and radiative properties of dust and anthropogenic air masses study in Taipei Basin, Taiwan, during spring of 2004

    NASA Astrophysics Data System (ADS)

    Chang, Shih-Yu; Fang, Guor-Cheng; Chou, Charles C.-K.; Chen, Wei-Nai

    Asia is one of the major sources of not only mineral dust but also anthropogenic aerosols. Continental air masses associated with the East Asian winter monsoon always contain high contents of mineral dust and anthropogenic species and transported southeastward to Taiwan, which have significant influences on global atmospheric radiation transfer directly by scattering and absorbing solar radiation in each spring. However, few measurements for the long-range transported aerosol and its optical properties were announced in this area, between the Western Pacific and the southeastern coast of Mainland China. The overall objective of this work is to quantify the optical characteristics of different aerosol types in the Eastern Asian. In order to achieve this objective, meteorological parameters, concentrations of PM 10 and its soluble species, and optical property of atmospheric scattering coefficients were measured continuously with 1 h time-resolved from 11 February to 7 April 2004 in Taipei Basin (25°00'N, 121°32'E). In this work, the dramatic changes of meteorological parameters such as temperature and winds were used to determine the influenced period of each air mass. Continental, strong continental, marine, and stagnant air masses defined by the back-trajectory analysis and local meteorology were further characterized as long-range transport pollution, dust, clean marine, and local pollution aerosols, respectively, according to the diagnostic ratios. The aerosol mass scattering efficiency of continental pollution, dust, clean marine, and local pollution aerosols were ranged from 1.3 to 1.6, 0.7 to 1.0, 1.4 and 1.4 to 2.3 m 2 g -1, respectively. Overall, there are two distinct populations of aerosol mass scattering efficiencies, one for an aerosol chemical composition dominated by dust (<1.0 m 2 g -1) and the other for an aerosol chemical composition dominated by anthropogenic pollutants (1.3-2.3 m 2 g -1), which were similar to the previous measurements with

  17. Angularly symmetric splitting of a light beam upon reflection and refraction at an air-dielectric plane boundary: comment.

    PubMed

    Andersen, Torben B

    2016-05-01

    In a recent paper, conditions for achieving equal and opposite angular deflections of a light beam by reflection and refraction at an interface between air and a dielectric were determined [J. Opt. Soc. Am. A32, 2436 (2015)JOAOD60740-323210.1364/JOSAA.32.002436]. The paper gives plots of angles of incidence and refraction as a function of the prism refractive index as well as plots of reflectances and incident linear-polarization azimuth angles as functions of the refractive index. We show here that it is possible to express these quantities as simple algebraic functions of the refractive index. PMID:27140897

  18. Observation studies on the influence of atmospheric boundary layer characteristics associate with air quality in dry season over the Pearl River Delta, China

    NASA Astrophysics Data System (ADS)

    Fan, Shaojia; Wu, Meng; Li, Haowen; Liao, Zhiheng; Fan, Qi; Zhu, Wei

    2016-04-01

    The characteristics of atmospheric boundary layer (ABL) is the very important factors influence on air quality in dry season over the Pearl River Delta (PRD), China. Based on the sounding data at six stations (Xinken,Dongguan, Sanshui, Nanhai, Shunde, and Heshan) which obtained from three times ABL experiments carried in dry season over PRD, the influence of wind and temperature vertical structure to the air quality over PRD has been studied with wind and temperature profiles, inversion layer, recirculation factor (RF), atmospheric boundary layer height (ABLH) and ventilation index (VI). It was found that the vertical wind of PRD could be divided in typical three layers according two wind shears appeared in 800 m and 1300 m. The thickness of calm or lower wind speed layer in pollution days was 500-1000m thicker than that of clean days, and its last time also much longer than that of clean days. The frequency of surface inversion in pollution days was about 35%,the mean thickness was about 100 m. With the influence of sea breeze, the frequency and thickness of surface inversion layer at Xinken station was a little lower than that in inland. Influenced by sea-land breezes and urban heat-island circulation, the RF of pollution days in coastal and urban area was quite smaller than that of clean days. During sea-land breezes days, the pollutants would be transported back to inland in nighttime with the influence of sea breeze, and resulted in 72.7% sea-land breezes was pollution days. The evolution of ABL was very typical in PRD during dry season. In pollution days, daily ABLH in PRD was lower than 500 m, daily VI was about 500-1500 m2/s. In clean days, daily VI was much larger than 2500 m2/s. An improved conceptual model of ABL influence on poor air quality and the parameters of the ABL characteristics associate with poor air quality in dry season over PRD had been summarized.

  19. Calculation of eddy viscosity in a compressible turbulent boundary layer with mass injection and chemical reaction, volume 2. [computer programs

    NASA Technical Reports Server (NTRS)

    Omori, S.

    1973-01-01

    As described in Vol. 1, the eddy viscosity is calculated through the turbulent kinetic energy, in order to include the history of the flow and the effect of chemical reaction on boundary layer characteristics. Calculations can be performed for two different cooling concepts; that is, transpiration and regeneratively cooled wall cases. For the regenerative cooling option, coolant and gas side wall temperature and coolant bulk temperature in a rocket engine can be computed along the nozzle axis. Thus, this computer program is useful in designing coolant flow rate and cooling tube geometry, including the tube wall thickness as well as in predicting the effects of boundary layers along the gas side wall on thrust performances.

  20. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Meixner, Franz X.; Vrana, Branislav; Efstathiou, Christos I.; Kohoutek, Jiři; Kukučka, Petr; Mulder, Marie D.; Přibylová, Petra; Prokeš, Roman; Rusina, Tatsiana P.; Song, Guo-Zheng; Tsapakis, Manolis

    2016-05-01

    As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Δc/Δz > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8 µg m-2 day-1 for PAHs and -3.4 to +0.9 µg m-2 day-1 for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.

  1. International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

    PubMed

    Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

    2014-08-01

    Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

  2. Stability of reference masses: VII. Cleaning methods in air and vacuum applied to a platinum mass standard similar to the international and national kilogram prototypes

    NASA Astrophysics Data System (ADS)

    Cumpson, Peter J.; Sano, Naoko; Barlow, Anders J.; Portoles, Jose F.

    2013-10-01

    Mercury contamination and the build-up of carbonaceous contamination are two contributing factors to the instability observed in kilogram prototype masses. The kilogram prototypes that lie at the core of the dissemination of the SI base unit were manufactured in the late 19th century, and have polished surfaces. In papers IV and V of this series we developed a method for cleaning noble metal mass standards in air to remove carbonaceous contamination. At the core of this ‘UVOPS’ protocol is the application of UV light and ozone gas generated in situ in air. The precise nature of the carbonaceous contamination that builds up on such surfaces is difficult to mimic demonstrably or quickly on new test surfaces, yet data from such tests are needed to provide the final confidence to allow UVOPS to be applied to a real 19th century kilogram prototype. Therefore, in the present work we have applied the UVOPS method to clean a platinum avoirdupois pound mass standard, ‘RS2’, manufactured in the mid-19th century. This is thought to have been polished in a similar manner to the kilogram prototypes. To our knowledge this platinum surface has not previously been cleaned by any method. We used x-ray photoelectron spectroscopy to identify organic contamination, and weighing to quantify the mass lost at each application of the UVOPS procedure. The UVOPS procedure is shown to be very effective. It is likely that the redefinition of the kilogram will require mass comparisons in vacuum in the years to come. Therefore, in addition to UVOPS a cleaning method for use in vacuum will also be needed. We introduce and evaluate gas cluster ion-beam (GCIB) treatment as a potential method for cleaning reference masses in vacuum. Again, application of this GCIB cleaning to a real artefact, RS2, allows us to make a realistic evaluation of its performance. While it has some attractive features, we cannot recommend it for cleaning mass standards in its present form.

  3. Mass

    SciTech Connect

    Chris Quigg

    2007-12-05

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  4. Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

    NASA Astrophysics Data System (ADS)

    Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

    2012-06-01

    The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

  5. Chemical and Trajectory Analysis of an Air Mass Plume from Asia

    NASA Astrophysics Data System (ADS)

    Guo, J. J.; Marrero, J. E.; Blake, D. R.

    2014-12-01

    Tracking the source of pollution events is important in understanding the transport of pollution plumes and impact on areas far from the source. Previous studies have shown that the rising contribution of Asian air pollution to the US has increased the number of days that pollution events exceed National Ambient Air Quality Standards (NAAQS). Whole air samples collected over the Edwards Air Force Base during a June 2014 NASA Student Airborne Research Program (SARP) flight exhibited enhancements in the concentrations of several compounds between 23-32 thousand feet. Chemical tracer analysis of these high altitude samples reveal that the air does not correspond to California emitted air. Chemical signatures in the plume, including high levels of OCS, chloroform, and methyl chloride, and low levels of methyl bromide, indicate that the plume was most heavily influence by coal combustion with contributions from biomass burning events from Asia. Low concentrations of ethene at the high altitude despite enhanced concentrations of ethane and ethyne suggest that this plume was aged. Further analysis of the plume using meteorological wind trajectories reveal that the plume had originated in China approximately 4-5 days prior. This is faster than results from previous studies that had found a Spring transport time of approximately 6 days.

  6. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  7. On the validity of boundary layer analysis for flow and mass transfer caused by rotation during the solution growth of large, single crystals

    NASA Astrophysics Data System (ADS)

    Vartak, Bhushan; Yeckel, Andrew; Derby, Jeffrey J.

    2005-10-01

    The rate of growth of single crystals from liquid solutions depends on coupled kinetic and transport phenomena. However, when continuum transport is limiting, the maximum crystal growth rate is determined by the rate of solute transport through the liquid phase to the growing crystal. We examine the validity of simple scaling and boundary layer theories to assess the behavior of a model solution crystal growth system, namely the growth of potassium titanyl phosphate (KTP) from high-temperature solutions. The approximation of the transport to a crystal rotating steadily in a supersaturated solution is based on the classical analytical solution for flow driven by a semi-infinite rotating disk and associated mass transfer. Our results indicate that this boundary layer analysis is reasonable as long as the solution container is very large, the geometry of the system is nearly axisymmetric, and the imposed flows are predominantly steady. For many practical systems, these conditions do not hold and such boundary layer analyses are expected to be in considerable error.

  8. Comparison of experimental and fossil leaf morphospace occupation suggests a role for atmospheric composition in driving morphospace change across a mass extinction boundary

    NASA Astrophysics Data System (ADS)

    Bacon, Karen; McElwain, Jennifer

    2016-04-01

    The Triassic-Jurassic boundary (~201 mya) marks a period of intense climate change associated with a mass extinction event and major volcanism. The impact of these environmental stresses has been well-documented; however, a detailed analysis of the morphospace response of plants across the boundary has not been conducted. In order to determine the impact of changing atmospheric composition on leaf morphospace occupation, we compared a fossil flora to controlled environment experiments. We analysed morphometric data for over 2,000 well-preserved leaf fossils from nine plant beds across the TJ of Astartekløft, East Greenland. Data including leaf length, width, area, and shape were used to determine morphospace occupation for each bed at the site. In the lower Triassic beds, morphospace occupation is high compared to a severe reduction at and across the boundary, contemporaneous with peak reconstructed CO2 and hypothesised elevated SO2 and other volcanic gases. These findings were compared to controlled environment experiments, where the same measurements were made on leaves from nearest living equivalent taxa grown in simulated palaeoatmospheric conditions. These experiments revealed that exposure to SO2, but not to variations in either CO2 or O2, produced a similar sever reduction in morphospace occupation. These findings together suggest that atmospheric composition change across the TJ, and particularly an elevation in SO2, had a role in heavily disrupting the plant community morphospace of East Greenland.

  9. Thermal desorption-gas chromatography-mass spectrometry method to determine phthalate and organophosphate esters from air samples.

    PubMed

    Aragón, M; Borrull, F; Marcé, R M

    2013-08-16

    A method based on thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed to determine four organophosphate esters, seven phthalate esters, and bis(2-ethylhexyl) adipate in the gas phase from harbour and urban air samples. The method involves the sampling of 1.5L of air in a Tenax TA sorbent tube followed by thermal desorption (using a Tenax TA cryogenic trap) coupled to gas chromatography-mass spectrometry. The repeatability of the method expressed as %RSD (n=3) is less than 15% and the MQLs are between 0.007μgm(-3) (DMP, TBP, BBP, TPP and DnOP) and 6.7μgm(-3) (DEHP). The method was successfully applied in two areas (urban and harbour) testing two and three points in each one, respectively. Some of these compounds were found in both urban and harbour samples. Di-(2-ethylhexyl)phthalate was the most abundant compound found in both areas at concentration levels between 6.7μgm(-3) and 136.4μgm(-3). This study demonstrates that thermal desorption is an efficient method for the determination of these semi-volatile compounds in the gas phase fraction of air samples. PMID:23859797

  10. Retrospective screening of pesticide metabolites in ambient air using liquid chromatography coupled to high-resolution mass spectrometry.

    PubMed

    López, Antonio; Yusà, Vicent; Millet, Maurice; Coscollà, Clara

    2016-04-01

    A new methodology for the retrospective screening of pesticide metabolites in ambient air was developed, using liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (UHPLC-HRMS), including two systematic workflows (i) post-run target screening (suspect screening) and (ii) non-target screening. An accurate-mass database was built and used for the post-run screening analysis. The database contained 240 pesticide metabolites found in different matrixes such as air, soil, water, plants, animals and humans. For non-target analysis, a "fragmentation-degradation" relationship strategy was selected. The proposed methodology was applied to 31 air samples (PM10) collected in the Valencian Region (Spain). In the post-target analysis 34 metabolites were identified, of which 11 (3-ketocarburan, carbofuran-7-phenol, carbendazim, desmethylisoproturon, ethiofencarb-sulfoxide, malaoxon, methiocarb-sulfoxide, N-(2-ethyl-6-methylphenyl)-L-alanine, omethoate, 2-hydroxy-terbuthylazine, and THPAM) were confirmed using analytical standards. The semiquantitative estimated concentration ranged between 6.78 and 198.31 pg m(-3). Likewise, two unknown degradation products of malaoxon and fenhexamid were elucidated in the non-target screening. PMID:26838378

  11. A comparison between 2010 and 2006 air quality and meteorological conditions, and emissions and boundary conditions used in simulations of the AQMEII-2 North American domain

    NASA Astrophysics Data System (ADS)

    Stoeckenius, Till E.; Hogrefe, Christian; Zagunis, Justin; Sturtz, Timothy M.; Wells, Benjamin; Sakulyanontvittaya, Tanarit

    2015-08-01

    Several participants in Phase 2 of the Air Quality Model Evaluation International Initiative (AQMEII-2) who are applying coupled models to the North American domain are comparing model results for two years, 2006 and 2010, with the goal of performing dynamic model evaluation. From a modeling perspective, the differences of interest are the large reductions in domain total emissions of NOx (21%) and SO2 (37%) from 2006 to 2010 and significant differences in meteorological conditions between these two years. The emission reductions occurred mostly in the eastern U.S, with some reduction in emissions from western wildfires in 2010. Differences in meteorological conditions both confound the impact of emission reductions on ambient air quality and provide an opportunity to examine how models respond to changing meteorology. This study is aimed at documenting changes in emissions, modeled large-scale background concentrations used as boundary conditions for the regional models, and observed meteorology and air quality to provide a context for the dynamic model evaluation studies performed within AQMEII-2. In addition to warmer summer temperatures, conditions in the eastern U.S. summer of 2010 were characterized by less precipitation than in 2006, while western portions of the U.S. and Canada were much cooler in 2010 due to a strengthening of the thermal trough over the Southwest and associated onshore flow. Summer ozone levels in many portions of the Northeast and Midwest were largely unchanged in 2010 despite reductions in precursor emissions. Normalization of the ozone trend, to account for differences in meteorological conditions, including warmer summer temperatures in 2010, shows that the emission reductions would have resulted in lower ozone levels at these locations if not for the countervailing influence of meteorological conditions. Winter mean surface temperatures were generally above average in 2006 whereas below average temperatures were noted in the

  12. An automated gas chromatography time-of-flight mass spectrometry instrument for the quantitative analysis of halocarbons in air

    NASA Astrophysics Data System (ADS)

    Obersteiner, F.; Bönisch, H.; Engel, A.

    2016-01-01

    We present the characterization and application of a new gas chromatography time-of-flight mass spectrometry instrument (GC-TOFMS) for the quantitative analysis of halocarbons in air samples. The setup comprises three fundamental enhancements compared to our earlier work (Hoker et al., 2015): (1) full automation, (2) a mass resolving power R = m/Δm of the TOFMS (Tofwerk AG, Switzerland) increased up to 4000 and (3) a fully accessible data format of the mass spectrometric data. Automation in combination with the accessible data allowed an in-depth characterization of the instrument. Mass accuracy was found to be approximately 5 ppm in mean after automatic recalibration of the mass axis in each measurement. A TOFMS configuration giving R = 3500 was chosen to provide an R-to-sensitivity ratio suitable for our purpose. Calculated detection limits are as low as a few femtograms by means of the accurate mass information. The precision for substance quantification was 0.15 % at the best for an individual measurement and in general mainly determined by the signal-to-noise ratio of the chromatographic peak. Detector non-linearity was found to be insignificant up to a mixing ratio of roughly 150 ppt at 0.5 L sampled volume. At higher concentrations, non-linearities of a few percent were observed (precision level: 0.2 %) but could be attributed to a potential source within the detection system. A straightforward correction for those non-linearities was applied in data processing, again by exploiting the accurate mass information. Based on the overall characterization results, the GC-TOFMS instrument was found to be very well suited for the task of quantitative halocarbon trace gas observation and a big step forward compared to scanning, quadrupole MS with low mass resolving power and a TOFMS technique reported to be non-linear and restricted by a small dynamical range.

  13. Ozone in the boundary layer air over the Arctic Ocean: measurements during the TARA transpolar drift 2006-2008

    NASA Astrophysics Data System (ADS)

    Bottenheim, J. W.; Netcheva, S.; Morin, S.; Nghiem, S. V.

    2009-07-01

    A full year of measurements of surface ozone over the Arctic Ocean far removed from land is presented (81° N-88° N latitude). The data were obtained during the drift of the French schooner TARA between September 2006 and January 2008, while frozen in the Arctic Ocean. The data confirm that long periods of virtually total absence of ozone occur in the spring (mid March to mid June) after Polar sunrise. At other times of the year, ozone concentrations are comparable to other oceanic observations with winter mole fractions of ca. 30-40 nmol mol-1 and summer minima of ca. 20 nmol mol-1. Contrary to earlier observations from ozone sonde data obtained at Arctic coastal observatories, the ambient temperature was well above -20°C during most ODEs (ozone depletion episodes). Backwards trajectory calculations suggest that during these ODEs the air had previously been in contact with the frozen ocean surface for several days and originated largely from the Siberian coast where several large open flaw leads and polynyas developed in the spring of 2007.

  14. Air mass origin and its influence on radionuclide activities ( 7Be and 210Pb) in aerosol particles at a coastal site in the western Mediterranean

    NASA Astrophysics Data System (ADS)

    Dueñas, C.; Orza, J. A. G.; Cabello, M.; Fernández, M. C.; Cañete, S.; Pérez, M.; Gordo, E.

    2011-07-01

    Studies of radionuclide activities in aerosol particles provide a means for evaluating the integrated effects of transport and meteorology on the atmospheric loadings of substances with different sources. Measurements of aerosol mass concentration and specific activities of 7Be and 210Pb in aerosols at Málaga (36° 43' 40″ N; 4° 28' 8″ W) for the period 2000-2006 were used to obtain the relationships between radionuclide activities and airflow patterns by comparing the data grouped by air mass trajectory clusters. The average concentration values of 7Be and 210Pb over the 7 year period have been found to be 4.6 and 0.58 mBq m -3, respectively, with mean aerosol mass concentration of 53.6 μg m -3. The identified air flow types arriving at Málaga reflect the transitional location of the Iberian Peninsula and show significant differences in radionuclide activities. Air concentrations of both nuclides and the aerosol mass concentration are controlled predominantly by the synoptic scenarios leading to the entrance of dust-laden continental flows from northern Africa and the arrival of polar maritime air masses, as implied by the strong correlations found between the monthly frequencies of the different air masses and the specific activities of both radionuclides. Correlations between activity concentrations and precipitation are significant though lower than with air masses.

  15. Petroleum mass removal from low permeability sediment using air sparging/soil vapor extraction: impact of continuous or pulsed operation

    NASA Astrophysics Data System (ADS)

    Kirtland, Brian C.; Aelion, C. Marjorie

    2000-02-01

    Air sparging and soil vapor extraction (AS/SVE) are innovative remediation techniques that utilize volatilization and microbial degradation to remediate petroleum spills from soils and groundwater. This in situ study investigated the use of AS/SVE to remediate a gasoline spill from a leaking underground storage tank (UST) in the low permeability, clayey soil of the Appalachian Piedmont. The objectives of this study were to evaluate AS/SVE in low permeability soils by quantifying petroleum mass removal rates, monitoring vadose zone contaminant levels, and comparing the mass extraction rates of continuous AS/SVE to 8 and 24 h pulsed operation. The objectives were met by collecting AS/SVE exhaust gas samples and vadose zone air from multi-depth soil vapor probes. Samples were analyzed for O 2, CO 2, BTEX (benzene, toluene, ethylbenzene, xylene), and total combustible hydrocarbon (TCH) concentrations using portable hand meters and gas chromatography. Continuous AS/SVE was effective in removing 608 kg of petroleum hydrocarbons from low permeability soil in 44 days (14.3 kg day -1). Mass removal rates ranged from 2.6 times higher to 5.1 times lower than other AS/SVE studies performed in sandy sediments. BTEX levels in the vadose zone were reduced from about 5 ppm to 1 ppm. Ten pulsed AS/SVE tests removed 78 kg in 23 days and the mean mass removal rate (17.6 kg day -1) was significantly higher than the last 15 days of continuous extraction. Pulsed operation may be preferable to continuous operation because of increased mass removal and decreased energy consumption.

  16. [Determination of volatile organic compounds in ambient air by thermal desorption-gas chromatography-triple quadrupole tandem mass spectrometry].

    PubMed

    Feng, Lili; Hu, Xiaofang; Yu, Xiaojuan; Zhang, Wenying

    2016-02-01

    A method was established for the simultaneous determination of 23 volatile organic compounds (VOCs) in ambient air with combination of thermal desorption (TD) and gas chromatography-triple quadrupole tandem mass spectrometry (GC-MS/MS). The air samples were collected by active sampling method using Tenax-TA sorbent tubes, and desorbed by thermal desorption. The analytes were determined by GC-MS/MS in selected reaction monitoring (SRM) mode, and internal standard method was applied to quantify the VOCs. The results of all the 23 VOCs showed good linearities in low level (0. 01-1 ng) and high level (1-100 ng) with all the correlation coefficients (r2) more than 0. 99. The method quantification limits were between 0. 000 08-1 µg/m3. The method was validated by means of recovery experiments (n = 6) at three spiked levels of 2, 10 and 50 ng. The recoveries between 77% and 124% were generally obtained. The relative standard deviations (RSDs) in all cases were lower than 20%, except for chlorobenzene at the low spiked level. The developed method was applied to determine VOCs in ambient air collected at three sites in Shanghai. Several compounds, like benzene, toluene, ethylbenzene, m-xylenes, p-xylenes, styrene, 1, 2, 4-trimethylbenzene and hexachlorobutadiene were detected and confirmed in all the samples analyzed. The method is highly accurate, reliable and sensitive for monitoring the VOCs in ambient air. PMID:27382728

  17. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air. PMID:26493981

  18. Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

    NASA Astrophysics Data System (ADS)

    Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

    2016-03-01

    A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

  19. High precision dating of mass extinction events: a combined zircon geochronology, apatite tephrochronology, and Bayesian age modelling approach of the Permian-Triassic boundary extinction

    NASA Astrophysics Data System (ADS)

    Baresel, Björn; Bucher, Hugo; Brosse, Morgane; Bagherpour, Borhan; Schaltegger, Urs

    2016-04-01

    Chemical abrasion isotope dilution thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb dating of single-zircon crystals is preferably applied to tephra beds intercalated in sedimentary sequences. By assuming that the zircon crystallization age closely approximate that of the volcanic eruption and ash deposition, U-Pb zircon geochronology is the preferred approach for dating mass extinction events (such as the Permian-Triassic boundary mass extinction) in the sedimentary record. As tephra from large volcanic eruptions is often transported over long distances, it additionally provide an invaluable tool for stratigraphic correlation across distant geologic sections. Therefore, the combination of high-precision zircon geochronology with apatite chemistry of the same tephra bed (so called apatite tephrochronology) provides a robust fingerprint of one particular volcanic eruption. In addition we provide coherent Bayesian model ages for the Permian-Triassic boundary (PTB) mass extinction, then compare it with PTB model ages at Meishan after Burgess et al. (2014). We will present new high-precision U-Pb zircon dates for a series of volcanic ash beds in deep- and shallow-marine Permian-Triassic sections in the Nanpanjiang Basin, South China. In addition, apatite crystals out of the same ash beds were analysed focusing on their halogen (F, Cl) and trace-element (e.g. Fe, Mg, REE) chemistry. We also show that Bayesian age models produce reproducible results from different geologic sections. On the basis of these data, including litho- and biostratigraphic correlations, we can precisely and accurately constrain the Permian-Triassic boundary in an equatorial marine setting, and correlate tephra beds over different sections and facies in the Nanpanjiang Basin independently from litho-, bio- or chemostratigraphic criteria. The results evidence that data produced in laboratories associated to the global EARTHTIME consortium can provide age information at the 0.05% level of 206

  20. The Atmospheric Boundary Layer

    ERIC Educational Resources Information Center

    Tennekes, Hendrik

    1974-01-01

    Discusses some important parameters of the boundary layer and effects of turbulence on the circulation and energy dissipation of the atmosphere. Indicates that boundary-layer research plays an important role in long-term forecasting and the study of air-pollution meteorology. (CC)

  1. Continental Land Mass Air Traffic Control (COLM ATC). [using three artificial satellite configurations

    NASA Technical Reports Server (NTRS)

    Pecar, J. A.; Henrich, J. E.

    1973-01-01

    The application of various satellite systems and techniques relative to providing air traffic control services for the continental United States was studied. Three satellite configurations were reviewed. The characteristics and capabilities of the satellites are described. The study includes consideration for the various ranging waveforms, multiple access alternatives, and the power and bandwidth required as a function of the number of users.

  2. Resonance-mode effect on microcantilever mass-sensing performance in air.

    PubMed

    Xia, Xiaoyuan; Li, Xinxin

    2008-07-01

    This research investigates the air drag damping effect of the micromachined cantilevers in different resonance modes on the quality factor, which are operated in ambient air. Based on a simplified dish-string model for air drag force acting on the resonant cantilever, the air drag damping properties of the cantilevers vibrating in different modes are analyzed with theoretic vibration mechanics, which is complemented and further confirmed with finite-element simulation. Four kinds of integrated cantilevers, which resonate in the first flexural mode, the second flexural mode, the first torsional mode, and the second torsional mode, respectively, are designed and fabricated by using micromachining techniques. Finally, biomolecular sensing experiments are carried out to verify the theoretical results obtained before. From both the modeling and experimental results, it can be seen that damping characteristics of the torsional cantilever resonators are generally better than that of the flexural ones, and quality factor of the cantilever resonator in a higher-frequency mode is always superior to that in a lower-frequency one. Among the four kinds of microcantilever resonators operated in our experiments, the one operated in the second flexural modes exhibits the highest Q factor and the best biomass sensing performance. PMID:18681721

  3. Resonance-mode effect on microcantilever mass-sensing performance in air

    SciTech Connect

    Xia Xiaoyuan; Li Xinxin

    2008-07-15

    This research investigates the air drag damping effect of the micromachined cantilevers in different resonance modes on the quality factor, which are operated in ambient air. Based on a simplified dish-string model for air drag force acting on the resonant cantilever, the air drag damping properties of the cantilevers vibrating in different modes are analyzed with theoretic vibration mechanics, which is complemented and further confirmed with finite-element simulation. Four kinds of integrated cantilevers, which resonate in the first flexural mode, the second flexural mode, the first torsional mode, and the second torsional mode, respectively, are designed and fabricated by using micromachining techniques. Finally, biomolecular sensing experiments are carried out to verify the theoretical results obtained before. From both the modeling and experimental results, it can be seen that damping characteristics of the torsional cantilever resonators are generally better than that of the flexural ones, and quality factor of the cantilever resonator in a higher-frequency mode is always superior to that in a lower-frequency one. Among the four kinds of microcantilever resonators operated in our experiments, the one operated in the second flexural modes exhibits the highest Q factor and the best biomass sensing performance.

  4. Detection of biological particles in ambient air using bio-aerosol mass spectrometry

    NASA Astrophysics Data System (ADS)

    McJimpsey, Erica L.; Steele, Paul T.; Coffee, Keith R.; Fergenson, David P.; Riot, Vincent J.; Woods, Bruce W.; Gard, Eric E.; Frank, Matthias; Tobias, Herbert J.; Lebrilla, Carlito

    2006-05-01

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described.

  5. Detection of biological particles in ambient air using Bio-Aerosol Mass Spectrometry

    SciTech Connect

    McJimpsey, E L; Steele, P T; Coffee, K R; Fergenson, D P; Riot, V J; Woods, B W; Gard, E E; Frank, M; Tobias, H J; Lebrilla, C

    2006-03-16

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described.

  6. Elemental composition and oxidative properties of PM(2.5) in Estonia in relation to origin of air masses - results from the ECRHS II in Tartu.

    PubMed

    Orru, Hans; Kimmel, Veljo; Kikas, Ulle; Soon, Argo; Künzli, Nino; Schins, Roel P F; Borm, Paul J A; Forsberg, Bertil

    2010-03-01

    Fine particulate matter (PM(2.5)) was sampled at an urban background site in Tartu, Estonia over one-year period during the ECRHS II study. The elemental composition of 71 PM(2.5) samples was analyzed for different chemical elements using energy-dispersive X-ray fluorescence spectrometry (ED-XRF). The oxidative activity of 36 samples was assessed by measuring their ability to generate hydroxyl radicals in the presence of hydrogen peroxide. The origin of air masses was determined by computing 96-hour back trajectories of air masses with the HYSPLIT Model. The trajectories of air masses were divided into four sectors according to geographical patterns: "Russia," "Eastern Europe," "Western Europe," and "Scandinavia." During the study period, approximately 30% of air masses originated from "Scandinavia." The other three sectors had slightly lower values (between 18 and 22%). In spring, summer, and winter, higher total PM levels originated from air masses from continental areas, namely "Russia" and "Eastern Europe" (18.51+/-7.33 and 19.96+/-9.23microg m(-3), respectively). In autumn, the PM levels were highest in "Western Europe". High levels of Fe, Ti, and AlCaSi (Al, Ca, and Si) were also detected in air masses from the Eurasian continent. The oxidative properties were correlated to the origin of air masses. The OH values were approximately 1.5 times higher when air masses originated from the direction of "Eastern Europe" or "Russia." The origin of measured particles was evaluated using principal component factor analysis. When comparing the PM(2.5) elemental composition with seasonal variation, factor scores, and other studies, the factors represent: (1) combustion of biomass; (2) crustal dust; (3) traffic; and (4) power plants and industrial processes associated with oil burning. The total PM(2.5) is driven mainly by biomass and industrial combustion (63%) and other unidentified sources (23%). Other sources of PM, such as crustal dust and traffic, contribute a total

  7. Toward a Unified Parameterization of the Boundary Layer and Moist Convection. Part 1; A New Type of Mass-Flux Model

    NASA Technical Reports Server (NTRS)

    Lappen, Cara-Lyn; Randall, David A.

    2001-01-01

    Higher-order closure (HOC) models have been proposed for parameterization of the turbulent planetary boundary layer (PBL). HOC models must include closures for higher-order moments (e.g., fourth moments in third-order closure models), for pressure terms, and for dissipation terms. Mass-flux closure (MFC) models have been proposed for parameterization of cumulus convection and, more recently, the convective PBL. MFC models include closures for lateral mass exchanges and for pressure terms (which are usually ignored). The authors developed a new kind of model that combines HOC and MFC, which they hope will be useful for the parameterization of both the PBL and cumulus convection, in a unified framework. Such a model is particularly well suited to regimes in which the PBL turbulence and the cumulus convection are not well separated, for example, the broken stratocumulus and shallow cumulus regimes. The model makes use of an assumed joint probability distribution for the variables of interest, and the equations typically used in HOC models can be derived by integrating over the distribution. Accordingly, the model is called Assumed-Distribution Higher-Order Closure (ADHOC). The prognostic variables of ADHOC are the mean state, the second and third moments of the vertical velocity, and the vertical fluxes of other quantities of interest. All of the parameters of the distribution can be determined from the predicted moments, thereafter the joint distribution is effectively known, and so any and all moments can be constructed as needed. In this way, the usual closure problem of "higher moments" is avoided. The pressure-term parameterizations previously developed for HOC models are used to predict the convective fluxes and the moments of the vertical velocity. In companion papers, parameterizations of lateral mass exchanges and subplume-scale fluxes are presented, and then ADHOC is applied to several observationally based tropical, subtropical, and dry convective boundary

  8. The Guadalupian-Lopingian boundary mudstones at Chaotian (SW China) are clastic rocks rather than acidic tuffs: Implication for a temporal coincidence between the end-Guadalupian mass extinction and the Emeishan volcanism

    NASA Astrophysics Data System (ADS)

    He, Bin; Xu, Yi-Gang; Zhong, Yu-Ting; Guan, Jun-Peng

    2010-09-01

    Previous studies on the temporal link between the end-Guadalupian mass extinction event and Emeishan flood volcanism were mainly based on geochronological and bio- and chemostratigraphic correlation techniques (Wignall et al., 2009). The absence of material-based hard evidence that directly links the extinction with the Emeishan volcanism remains a major obstacle regardless of the indication of coincidence in timing (Isozaki et al., 2007). The Emeishan basalts overlie Permian platform carbonates that may contain a record of the end-Guadalupian mass extinction and erosional product of this province. This paper presents mineralogy and geochemistry of mudstones from the Guadalupian-Lopingian Boundary (G-LB) at Chaotian, SW China. Results indicate that these G-LB mudstones are not air-fall acidic tuff as previously thought, but likely represent clastic rocks derived from erosional deposits of the Emeishan large igneous province (ELIP). Mudstones of the lower part (Group 1) have a geochemical affinity to the Emeishan felsic volcanic rocks, whereas mudstones of the upper part (Group 2) are compositionally akin to mafic components of the Emeishan traps. This chemostratigraphic sequence resembles the Xuanwei Formation which sits on the Emeishan basalts (He et al., 2007). These data therefore indicate that the lower part of the mudstones at the Chaotian G-LB section, the lowermost part of Xuanwei and Longtan Formations and the Emeishan felsic extrusives broadly constitute an isochron horizon throughout the ELIP and adjacent region, suggesting a short duration for the Emeishan volcanism. A temporal coincidence between Emeishan volcanism and the end-Guadalupian mass extinction are therefore inferred thus providing support for a cause-and-effect relationship.

  9. High-efficiency, one-sun (22. 3% at air mass 0; 23. 9% at air mass 1. 5) monolithic two-junction cascade solar cell grown by metalorganic vapor phase epitaxy

    SciTech Connect

    Chung, B.; Virshup, G.F.; Werthen, J.G.

    1988-05-30

    A high-efficiency monolithic two-junction solar cell consisting of an Al/sub 0.37/Ga/sub 0.63/As (E/sub g/ = 1.93 eV) upper cell and a GaAs lower cell has been grown by metalorganic vapor phase epitaxy. Since both component cells have the n-on-p configuration, the unwanted p-n junction has been eliminated with the use of metal-interconnect contact during post-growth processing. As a two-terminal device, an efficiency of 22.3% has been achieved under 1 sun, air mass 0 illumination conditions, whereas an efficiency of 23.9% was obtained when the cascade cell was operated as a three-terminal device under 1 sun, air mass 1.5 illumination. This result represents the highest 1 sun efficiency ever reported. The advantages of utilizing this multijunction solar cell for terrestrial and space applications are also described.

  10. Effects of selected design variables on three ramp, external compression inlet performance. [boundary layer control bypasses, and mass flow rate

    NASA Technical Reports Server (NTRS)

    Kamman, J. H.; Hall, C. L.

    1975-01-01

    Two inlet performance tests and one inlet/airframe drag test were conducted in 1969 at the NASA-Ames Research Center. The basic inlet system was two-dimensional, three ramp (overhead), external compression, with variable capture area. The data from these tests were analyzed to show the effects of selected design variables on the performance of this type of inlet system. The inlet design variables investigated include inlet bleed, bypass, operating mass flow ratio, inlet geometry, and variable capture area.

  11. The Araguainha impact crater at the Permo-Triassic boundary: implications for the carbon isotope excursion and the mass extinction.

    NASA Astrophysics Data System (ADS)

    Lana, C.; Tohver, E.; Siret, D.; Cawood, P.; Sherlock, S.; Marangoni, Y. R.; Trindade, R. I.; Souza, R.

    2007-12-01

    The Araguainha crater is a complex crater with a diameter of 40 km exposed on the northern margin of the Parana Basin of central Brazil. This intracontinental basin, correlated to the Karoo Basin of southern Africa, was the locus of marine sedimentation over an area of 5 million km2 throughout the late Paleozoic. Carbonate sedimentation in the early Permian was marked by large accumulations of organic carbon in pyrite-bearing oil shales such as the Irati Fm, considered to be the world's second largest oil shale. Regional borehole data from outside the crater reveals a thickness of 40m for the oil shale horizon, which is partly to completely absent within the crater. Our structural and stratigraphic survey of the Araguainha crater reveal the post-impact rebound of the crater has removed ca. 2-2.5 km of sediments from the ca. 10 km diameter central uplift, with minimal subsequent erosion (<250m). Vaporization of the colliding body and the approximate shadowed target region are assumed, with energy models for impact craters suggesting a body of 2-3 km diameter. Ongoing radiogenic isotope dating of the impact melts and breccias is being undertaken by U-Pb SHRIMP analysis of shocked zircons and 40Ar/39Ar analysis of glassy vein material interpreted as pseudotachylite. Preliminary U-Pb age data yield an impact age of 252.7 +/- 3.8 Ma (2 sigma error), essentially synchronous with the Permo-Triassic boundary. The minimum amount of isotopically light carbon (-17 to -25 per mill PDB) available in the target rocks for release by the impact is estimated at 10 Gigatons, considering only the area of the central uplift. Possible sources of additional, isotopically-light carbon include the remainder of the 20-25 km transient crater, as well as methane clathrates released by impact-induced slope destabilization. We propose that the Araguainha impact could have been responsible for observed shifts shift in global carbon isotopes at the Permo-Triassic boundary. The possible effect of

  12. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    SciTech Connect

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-18

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22 cm diameter and 30 cm length, purifies an airflow rate of 5000 lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  13. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    NASA Astrophysics Data System (ADS)

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-01

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22cm diameter and 30cm length, purifies an airflow rate of 5000lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  14. Using Natural Boundary Conditions to Probe the Internal Dynamics of Pyroclastic Flows: Mass, Enthalpy and Momentum Transfer at the Flow-Bed Interface

    NASA Astrophysics Data System (ADS)

    Dufek, J.; Bergantz, G. W.; Manga, M.

    2006-12-01

    The interaction of pyroclastic density currents with their substrate plays a significant role in the transport and deposition of these flows. The basal particle concentration of these flows will ultimately determine the mechanism of mass, enthalpy and momentum transfer and the sensitivity of these flows to bed roughness, topography and even their ability to cross bodies of water. In order to probe the internal structure of these flows we used an Eulerian-Eulerian-Lagrangian (EEL) computational approach coupled with an examination of ignimbrite deposits of the Kos Plateau Tuff (KPT) and the near-shore deposits of the 2003 Montserrat dome collapse (Allen and Cas, 2001; Edmonds and Herd, 2005). In particular, the KPT eruption provides a unique opportunity to compare flows that have traversed a body of water (and thereby filtering out their bed-load) versus flows that have traveled over-land. The examined Montserrat pyroclastic flows also encounter the ocean, and comparison with observations of the recently produced near-shore deposits allow us to access the near-surface energy transfer required to produce the observed steam explosions and the mass transfer necessary to produce tsunami. This coupled deposit-driven and numerical investigation reveals that energy-dissipation at the basal boundary is one of the primary factors determining the run-out distance of pyroclastic flows. A significant portion of the momentum of over-land flows is transported in a bed-load region dominated by numerous particle-particle and particle-boundary interactions. Mass and energy transfer in the near shore environment produce tsunami and steam explosions, which result in preferential fining in the proximal deposits and a source of water vapor to the propagating currents. However, the simulations indicate the internal structure and head of the pyroclastic density current are not significantly impacted by the steam explosions after they have traveled several kilometers away from the shore as

  15. Facility monitoring of chemical warfare agent simulants in air using an automated, field-deployable, miniature mass spectrometer.

    PubMed

    Smith, Jonell N; Noll, Robert J; Cooks, R Graham

    2011-05-30

    Vapors of four chemical warfare agent (CWA) stimulants, 2-chloroethyl ethyl sulfide (CEES), diethyl malonate (DEM), dimethyl methylphosphonate (DMMP), and methyl salicylate (MeS), were detected, identified, and quantitated using a fully automated, field-deployable, miniature mass spectrometer. Samples were ionized using a glow discharge electron ionization (GDEI) source, and ions were mass analyzed with a cylindrical ion trap (CIT) mass analyzer. A dual-tube thermal desorption system was used to trap compounds on 50:50 Tenax TA/Carboxen 569 sorbent before their thermal release. The sample concentrations ranged from low parts per billion [ppb] to two parts per million [ppm]. Limits of detection (LODs) ranged from 0.26 to 5.0 ppb. Receiver operating characteristic (ROC) curves are presented for each analyte. A sample of CEES at low ppb concentration was combined separately with two interferents, bleach (saturated vapor) and diesel fuel exhaust (1%), as a way to explore the capability of detecting the simulant in an environmental matrix. Also investigated was a mixture of the four CWA simulants (at concentrations in air ranging from 270 to 380 ppb). Tandem mass (MS/MS) spectral data were used to identify and quantify the individual components. PMID:21504010

  16. Seasonal variation of local atmospheric circulations and boundary layer structure in the Beijing-Tianjin-Hebei region and implications for air quality

    NASA Astrophysics Data System (ADS)

    Miao, Yucong; Hu, Xiao-Ming; Liu, Shuhua; Qian, Tingting; Xue, Ming; Zheng, Yijia; Wang, Shu

    2015-12-01

    The Beijing-Tianjin-Hebei (BTH) region experiences frequent heavy haze pollution in fall and winter. Pollution was often exacerbated by unfavorable atmospheric boundary layer (BL) conditions. The topography in this region impacts the BL processes in complex ways. Such impacts and implications on air quality are not yet clearly understood. The BL processes in all four seasons in BTH are thus investigated in this study using idealized simulations with the WRF-Chem model. Results suggest that seasonal variation of thermal conditions and synoptic patterns significantly modulates BL processes. In fall, with a relatively weak northwesterly synoptic forcing, thermal contrast between the mountains and the plain leads to a prominent mountain-plain breeze circulation (MPC). In the afternoon, the downward branch of the MPC, in addition to northwesterly warm advection, suppresses BL development over the western side of BTH. In the eastern coastal area, a sea-breeze circulation develops late in the morning and intensifies during the afternoon. In summer, southeasterly BL winds allow the see-breeze front to penetrate farther inland (˜150 km from the coast), and the MPC is less prominent. In spring and winter, with strong northwesterly synoptic winds, the sea-breeze circulation is confined in the coastal area, and the MPC is suppressed. The BL height is low in winter due to strong near-surface stability, while BL heights are large in spring due to strong mechanical forcing. The relatively low BL height in fall and winter may have exacerbated the air pollution, thus contributing to the frequent severe haze events in the BTH region.

  17. A Variational Analysis of Divergence Profiles Based upon Column-Integrated Mass, Moisture and Energetic Constraints with Satellite-Derived Boundary Fluxes

    NASA Technical Reports Server (NTRS)

    Lu, Huei-Lin; Robertson, Franklin R.

    2003-01-01

    A diagnostic study is made of the mean global divergent circulation based upon a constrained least action principle that minimizes column-integrated divergent kinetic energy subject to constraints on mass, moisture, available potential energy (ape) and total kinetic energy. The concept of gross moist stability was incorporated in the prescription of Lagrange weight function associated with the ape constraint in order to simulate the net effects of cumulus convective heating in the tropics. The variational analyses were validated satisfactorily with the original NCEP/NCAR-reanalysis divergence fields for the Septembers of 1987 and 1988. Further analyses show that in the tropical ascending regions, the analyzed divergences are dominated by the mass and ape constraints; the moisture constraint is implicitly satisfied while the kinetic energy constraint is highly dependent on the ape constraint. In the subtropical descending regions, the analyzed divergences are dominated by the mass, moisture and kinetic energy constraints; the ape constraint is implicitly satisfied. When the constraint integrals were blended with the satellite-derived boundary flux data from GPCP precipitation and ERBE/SRB radiation estimates, the newly analyzed divergences are significantly stronger than the reanalysis divergences in the areas where the estimates of precipitation rates are higher. With few exceptions, the increases in upper-layer divergences are coupled with nearly equal increases in lower-layer convergences.

  18. Interaction of clothing and body mass index affects validity of air displacement plethysmography in adults

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Objective: Examine the effect of alternate clothing schemes on validity of Bod Pod to estimate percent body fat (BF) compared to dual x-ray absorptiometry (DXA), and determine if these effects differ by body mass index (BMI). Design: Cross-sectional Subjects: 132 healthy adults aged 19-81 classifi...

  19. Mass transfer coefficients developed from the air gasification of wood pellets

    SciTech Connect

    Botts, J.W.

    1998-07-01

    A convertible updraft/downdraft, fixed-bed gasifier was used in the gasification of 3/8-inch diameter wood pellets. The test data was used to develop mass transfer coefficients and describe the gasification process for each gasifier configuration. The results show that the production of the principal combustion gases, i.e., hydrogen (H{sub c}), carbon monozide (CO), and methane (CH{sub 4}), varies directly as to their mass transfer coefficient: H{sub 2}, CO, and CH{sub 4} = k h{sub DA}. Factoring the Reynolds (Re{sub d}) and Schmidt (Sc) numbers with the influence of the noncombustible gases, i.e., nitrogen (N{sub 2}), oxygen (O{sub 2}), and carbon dioxide (CO{sub 2}), is used to define the mass transfer coefficients. The general form describing this joint variation is: H{sub 2}, CO, and CH{sub 4} = kx (the effect of the noncombustible gases) x Re x Sc where Re = Reynolds number and Sc = Schmidt number. The developments of these mass transfer coefficients are shown for updraft and downdraft gasification.

  20. Quantifying Magnitude, Timing, And Distribution of Mass Flux at a River-Aquifer Boundary using Head and Temperature Response to Step and Seasonal Changes in River Stage and a Variable River Edge Boundary

    NASA Astrophysics Data System (ADS)

    Thoma, M. J.; Barrash, W.; Bradford, J. H.

    2012-12-01

    -year simulations were run to quantify mass and energy flux at the river-aquifer boundary. Physical changes in boundary conditions, particularly river bank position and river wetted perimeter, produce significant alterations to the flow regime and must be incorporated into the model to correctly estimate riverbed and aquifer parameters and to accurately evaluate river-aquifer fluxes.

  1. A distributed air index based on maximum boundary rectangle over grid-cells for wireless non-flat spatial data broadcast.

    PubMed

    Im, Seokjin; Choi, JinTak

    2014-01-01

    In the pervasive computing environment using smart devices equipped with various sensors, a wireless data broadcasting system for spatial data items is a natural way to efficiently provide a location dependent information service, regardless of the number of clients. A non-flat wireless broadcast system can support the clients in accessing quickly their preferred data items by disseminating the preferred data items more frequently than regular data on the wireless channel. To efficiently support the processing of spatial window queries in a non-flat wireless data broadcasting system, we propose a distributed air index based on a maximum boundary rectangle (MaxBR) over grid-cells (abbreviated DAIM), which uses MaxBRs for filtering out hot data items on the wireless channel. Unlike the existing index that repeats regular data items in close proximity to hot items at same frequency as hot data items in a broadcast cycle, DAIM makes it possible to repeat only hot data items in a cycle and reduces the length of the broadcast cycle. Consequently, DAIM helps the clients access the desired items quickly, improves the access time, and reduces energy consumption. In addition, a MaxBR helps the clients decide whether they have to access regular data items or not. Simulation studies show the proposed DAIM outperforms existing schemes with respect to the access time and energy consumption. PMID:24940864

  2. A Distributed Air Index Based on Maximum Boundary Rectangle over Grid-Cells for Wireless Non-Flat Spatial Data Broadcast

    PubMed Central

    Im, Seokjin; Choi, JinTak

    2014-01-01

    In the pervasive computing environment using smart devices equipped with various sensors, a wireless data broadcasting system for spatial data items is a natural way to efficiently provide a location dependent information service, regardless of the number of clients. A non-flat wireless broadcast system can support the clients in accessing quickly their preferred data items by disseminating the preferred data items more frequently than regular data on the wireless channel. To efficiently support the processing of spatial window queries in a non-flat wireless data broadcasting system, we propose a distributed air index based on a maximum boundary rectangle (MaxBR) over grid-cells (abbreviated DAIM), which uses MaxBRs for filtering out hot data items on the wireless channel. Unlike the existing index that repeats regular data items in close proximity to hot items at same frequency as hot data items in a broadcast cycle, DAIM makes it possible to repeat only hot data items in a cycle and reduces the length of the broadcast cycle. Consequently, DAIM helps the clients access the desired items quickly, improves the access time, and reduces energy consumption. In addition, a MaxBR helps the clients decide whether they have to access regular data items or not. Simulation studies show the proposed DAIM outperforms existing schemes with respect to the access time and energy consumption. PMID:24940864

  3. Crossing turbulent boundaries: interfacial flux in environmental flows.

    PubMed

    Grant, Stanley B; Marusic, Ivan

    2011-09-01

    Advances in the visualization and prediction of turbulence are shedding new light on mass transfer in the turbulent boundary layer. These discoveries have important implications for many topics in environmental science and engineering, from the transport of earth-warming CO2 across the sea-air interface, to nutrient processing and sediment erosion in rivers, lakes, and the ocean, to pollutant removal in water and wastewater treatment systems. In this article we outline current understanding of turbulent boundary layer flows, with particular focus on coherent turbulence and its impact on mass transport across the sediment-water interface in marine and freshwater systems. PMID:21793569

  4. The study of the effect of the surface wave on turbulent stably-stratified boundary layer air-flow by direct numerical simulation

    NASA Astrophysics Data System (ADS)

    Druzhinin, Oleg; Troitskaya, Yliya; Zilitinkevich, Sergej

    2015-04-01

    Detailed knowledge of the interaction of surface water waves with the wind flow is of primary importance for correct parameterization of turbulent momentum and heat fluxes which define the energy and momentum transfer between the atmosphere and hydrosphere. The objective of the present study is to investigate the properties of the stably stratified turbulent boundary-layer (BL) air-flow over waved water surface by direct numerical simulation (DNS) at a bulk Reynolds number varying from 15000 to 80000 and the surface-wave slope up to ka = 0.2. The DNS results show that the BL-flow remains in the statistically stationary, turbulent regime if the Reynolds number (ReL) based on the Obukhov length scale and friction velocity is sufficiently large (ReL > 100). In this case, mean velocity and temperature vertical profiles are well predicted by log-linear asymptotic solutions following from the Monin-Obukhov similarity theory provided the velocity and temperature roughness parameters, z0U and z0T, are appropriately prescribed. Both z0U and z0T increase for larger surface-wave slope. DNS results also show that turbulent momentum and heat fluxes and turbulent velocity and temperature fluctuations are increased for larger wave slope (ka) whereas the mean velocity and temperature derivatives remain practically the same for different ka. Thus, we conclude that the source of turbulence enhancement in BL-flow are perturbations induced by the surface wave, and not the shear instability of the bulk flow. On the other hand, if stratification is sufficiently strong, and the surface-wave slope is sufficiently small, the BL-flow over waved surface relaminarizes in the bulk of the domain. However, if the surface-wave slope exceeds a threshold value, the velocity and temperature fluctuations remain finite in the vicinity of the critical-layer level, where the surface-wave phase velocity coincides with the mean flow velocity. We call this new stably-stratified BL-flow regime observed in

  5. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  6. Mercury in the marine boundary layer and seawater of the South China Sea: Concentrations, sea/air flux, and implication for land outflow

    NASA Astrophysics Data System (ADS)

    Fu, Xuewu; Feng, Xinbin; Zhang, Gan; Xu, Weihai; Li, Xiangdong; Yao, Hen; Liang, Peng; Li, Jun; Sommar, Jonas; Yin, Runsheng; Liu, Na

    2010-03-01

    Using R/V Shiyan 3 as a sampling platform, measurements of gaseous elemental mercury (GEM), surface seawater total mercury (THg), methyl mercury (MeHg), and dissolved gaseous mercury (DGM) were carried out above and in the South China Sea (SCS). Measurements were collected for 2 weeks (10 to 28 August 2007) during an oceanographic expedition, which circumnavigated the northern SCS from Guangzhou (Canton), Hainan Inland, the Philippines, and back to Guangzhou. GEM concentrations over the northern SCS ranged from 1.04 to 6.75 ng m-3 (mean: 2.62 ng m-3, median: 2.24 ng m-3). The spatial distribution of GEM was characterized by elevated concentrations near the coastal sites adjacent to mainland China and lower concentrations at stations in the open sea. Trajectory analysis revealed that high concentrations of GEM were generally related to air masses from south China and the Indochina peninsula, while lower concentrations of GEM were related to air masses from the open sea area, reflecting great Hg emissions from south China and Indochina peninsula. The mean concentrations of THg, MeHg, and DGM in surface seawater were 1.2 ± 0.3 ng L-1, 0.12 ± 0.05 ng L-1, and 36.5 ± 14.9 pg L-1, respectively. In general, THg and MeHg levels in the northern SCS were higher compared to results reported from most other oceans/seas. Elevated THg levels in the study area were likely attributed to significant Hg delivery from surrounding areas of the SCS primarily via atmospheric deposition and riverine input, whereas other sources like in situ production by various biotic and abiotic processes may be important for MeHg. Average sea/air flux of Hg in the study area was estimated using a gas exchange method (4.5 ± 3.4 ng m-2 h-1). This value was comparable to those from other coastal areas and generally higher than those from open sea environments, which may be attributed to the reemission of Hg previously transported to this area.

  7. Influence of dissolved humic substances on the mass transfer of organic compounds across the air-water interface.

    PubMed

    Ramus, Ksenia; Kopinke, Frank-Dieter; Georgi, Anett

    2012-01-01

    The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal. PMID:22051345

  8. The analysis of heat and mass transfer during frying of food using a moving boundary solution procedure

    NASA Astrophysics Data System (ADS)

    Farid, M. M.; Chen, X. D.

    Heat and mass transfer during frying of food was analysed using the heat conduction equation. The model developed assumes the presence of two regions, the fried and the unfried regions. The heat convected from the oil to the surface of the food is transferred by conduction through the fried region to an evaporating interface. Most of the transferred heat is utilised to vaporise the water at the interface, while the remaining smaller amount is used for sensible heating. The generated water vapour at the interface was assumed to flow in the fried region with minimum resistance, exchanging heat with the solid. The model was tested against some experimental results available for frying of thick and thin potato chips. The agreement between the predicted and measured temperature distribution was reasonable except at the end of the frying period at which the bounded water may vaporise with a different mechanism and oil may penetrate deep into the potato chips. In all the experiments, the centre temperature of the potato chips remained constant at almost 100∘C for a long period which gave a good support to the model developed.

  9. What is the role of wind pumping on heat and mass transfer rates at the air-snow interface?

    NASA Astrophysics Data System (ADS)

    Helgason, W.; Pomeroy, J. W.

    2010-12-01

    Accurate prediction of the turbulent exchange of sensible heat and water vapour between the atmosphere and snowpack remains a challenging task under all but the most ideal conditions. Heat and mass transfer coefficients that recognize the unique properties of the snow surface are warranted. A particular area requiring improvement concerns the role of the porous nature of snow which provides a large surface area for heat and mass exchange with the atmosphere. Wind-pumping has long been considered as a viable mechanism for incorporating aerosols into snowpacks; however these processes are not considered in parameterization schemes for heat and mass transfer near the surface. This study attempts to determine the degree to which wind pumping can increase the rates of heat and mass transfer to snow, and to ascertain which structural properties of the snowpack are needed for inclusion in heat and mass transfer coefficients that reflect wind pumping processes. Based upon a review of recent geophysical and engineering literature where porous surfaces are exploited for their ability to augment heat and mass transfer rates, a technical analysis was conducted. Numerous conceptual mechanisms of wind pumping were considered: topographically-induced flow; barometric pressure changes; high frequency pressure fluctuations at the surface; and steady flow in the interfacial region. A sensitivity analysis was performed, subjecting each conceptual model to varying thermal and hydraulic conditions at the air-snow interface, as well as variable micro-structural properties of snow. It is shown that the rate of heat and mass exchange is most sensitive to the interfacial thermal conditions and factors controlling the energy balance of the uppermost snow grains. The effect upon the thermal regime of the snowpack was found to be most significant for mechanisms of wind pumping that result in shorter flow paths near the surface, rather than those caused by low frequency pressure changes. In

  10. Primary and secondary organic aerosols in urban air masses intercepted at a rural site

    NASA Astrophysics Data System (ADS)

    Liggio, John; Li, Shao-Meng; Vlasenko, Alexander; Sjostedt, Steve; Chang, Rachel; Shantz, Nicole; Abbatt, Jonathan; Slowik, J. G.; Bottenheim, J. W.; Brickell, P. C.; Stroud, C.; Leaitch, W. Richard

    2010-11-01

    Measurements made at a rural site in central Ontario during May-June 2007 are used to investigate the composition of organic aerosol (OA) downwind of an urban region. Observations of aerosol organic carbon and oxygen containing fragments from a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) are combined with toluene to benzene ratios to estimate the relative importance of secondary organic aerosol (SOA) and primary organic aerosol (POA) to the total OA at the site during periods of significant urban influence. We estimate that SOA formed within 1-2 days of the anthropogenic source regions was 40-50% of the measured OA and that POA was 5-16% of the OA. The remaining 35-45% of the OA is assumed to have been present in the aerosol upwind of the source regions prior to entering the study domain as defined by trajectories and estimates of the potential photochemical aging time. The apportionment results were also compared to that of positive matrix factorization analysis. In addition, the measurements of the molar oxygen to carbon ratio (O/C) in the OA demonstrates that SOA becomes progressively more oxygenated with increasing photochemical age and at low total OA mass.

  11. Interactions effectives, théories de champ moyen masses et rayons nucléaires

    NASA Astrophysics Data System (ADS)

    Meyer, J.

    2003-05-01

    Effective interactions, mean field theories, masses and nuclear radii A review of effective interactions used in mean field theories for the description of properties of atomic nuclei is presented. Relativistic as well as non relativistic theories are discussed with a special attention to the cases where their results are very different. We will concentrate on the effective forces built up to investigate the nuclear medium in extreme conditions. Masses and r.m.s. radii along long chain of isotopes will be discussed. Large deformations, as observed in the fission of heavy nuclei, and exotic neutron rich nuclei will be taken as examples of these extreme conditions. Le principal propos de cet ouvrage est : (i) de passer en revue les outils théoriques utilisés sous le sigle ”théories microscopiques de champ moyen ”. Sans entrer dans le détail des formalismes (le lecteur sera systématiquement renvoyé ”pour en savoir plus ” à des cours plus complets qui ont déjà été donnés dans le passé à l'École Joliot-Curie) il s'agira surtout de préciser le contexte, les hypothèses et les approximations qui se cachent sous les sigles : Hartree-Fock (HF), Hartree-Fock-Bogoliubov (HFB), Approximation BCS (HFBCS), Champ Moyen Relativiste (RMF), Approximations Hartree (RH), Hartree-Fock (RHF) et Hartree-Bogoliubov (RHB) Relativistes, ... ; (ii) de présenter la procédure générale et les ingrédients qui entrent dans la construction d'une interaction effective, élément de base de ces théories dont l'intérêt majeur est de livrer des résultats comparables à l'expérience sans paramètre ajustable ; (iii) de discuter des effets des différentes approximations ou interactions effectives sur des résultats expérimentaux pris dans diverses zones de noyaux. Ces discussions seront surtout centrées sur les masses et les rayons des noyaux mais aussi sur certaines quantités plus significatives que l'on peut en extraire : énergies de séparation de deux neutrons

  12. Chemical composition of tropospheric air masses encountered during high altitude flights (>11.5 km) during the 2009 fall Operation Ice Bridge field campaign

    NASA Astrophysics Data System (ADS)

    Yang, Mei Ying Melissa; Vay, Stephanie A.; Stohl, Andreas; Choi, Yonghoon; Diskin, Glenn S.; Sachse, Glen W.; Blake, Donald R.

    2012-09-01

    As part of the 2009 Operation Ice Bridge campaign, the NASA DC-8 aircraft was used to fill the data-time gap in laser observation of the changes in ice sheets, glaciers and sea ice between ICESat-I (Ice, Cloud, and land Elevation Satellite) and ICESat-II. Complementing the cryospheric instrument payload were four in situ atmospheric sampling instruments integrated onboard to measure trace gas concentrations of CO2, CO, N2O, CH4, water vapor and various VOCs (Volatile Organic Compounds). This paper examines two plumes encountered at high altitude (12 km) during the campaign; one during a southbound transit flight (13°S) and the other at 86°S over Antarctica. The data presented are especially significant as the Southern Hemisphere is heavily under-sampled during the austral spring, with few if any high-resolution airborne observations of atmospheric gases made over Antarctica. Strong enhancements of CO, CH4, N2O, CHCl3, OCS, C2H6, C2H2 and C3H8 were observed in the two intercepted air masses that exhibited variations in VOC composition suggesting different sources. The transport model FLEXPART showed that the 13°S plume contained predominately biomass burning emissions originating from Southeast Asia and South Africa, while both anthropogenic and biomass burning emissions were observed at 86°S with South America and South Africa as indicated source regions. The data presented here show evidence that boundary layer pollution is transported from lower latitudes toward the upper troposphere above the South Pole, which may not have been observed in the past.

  13. Brief Communication: Upper-air relaxation in RACMO2 significantly improves modelled interannual surface mass balance variability in Antarctica

    NASA Astrophysics Data System (ADS)

    van de Berg, Willem Jan; Medley, Brooke

    2016-03-01

    The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in contrast to ERA-Interim, which resolves this variability well. In an attempt to remedy RACMO2 performance, we included additional upper-air relaxation (UAR) in RACMO2. With UAR, the correlation to observations is similar for RACMO2 and ERA-Interim. The spatial SMB patterns and ice-sheet-integrated SMB modelled using UAR remain very similar to the estimates of RACMO2 without UAR. We only observe an upstream smoothing of precipitation in regions with very steep topography like the Antarctic Peninsula. We conclude that UAR is a useful improvement for regional climate model simulations, although results in regions with steep topography should be treated with care.

  14. Seasonal variability of tritium and ion concentrations in rain at Kumamoto, Japan and back-trajectory analysis of air mass

    SciTech Connect

    Momoshima, N.; Sugihara, S.; Toyoshima, T.; Nagao, Y.; Takahashi, M.; Nakamura, Y.

    2008-07-15

    Tritium and major ion concentrations in rain were analyzed in Kumamoto (Japan)) between 2001 and 2006 to examine present tritium concentration and seasonal variation. The average tritium concentration was 0.36 {+-} 0.19 Bq/L (n=104) and higher tritium concentrations were observed in spring than the other seasons. Among the ions, non-sea-salt (nss) SO{sub 4}{sup 2}'- showed higher concentration in winter while other ions did not show marked increase in winter. Based on the back-trajectory analyses of air masses, the increase in tritium concentrations in spring arises from downward movement of naturally produced tritium from stratosphere to troposphere, while the increase of the nss-SO{sub 4}{sup 2-} concentrations in winter is due to long range transport of pollutants from China to Japan. (authors)

  15. Triggers of Permo-Triassic boundary mass extinction in South China: The Siberian Traps or Paleo-Tethys ignimbrite flare-up?

    NASA Astrophysics Data System (ADS)

    He, Bin; Zhong, Yu-Ting; Xu, Yi-Gang; Li, Xian-Hua

    2014-09-01

    Assessment of the synchroneity between the Siberian Traps and the Permo-Triassic boundary (PTB) mass extinction has led to the proposition that the Siberian flood volcanism was responsible for the severest biotic crisis in the Phanerozoic. However, recent studies suggest that the Siberian Traps may have postdated the main extinction horizon. In this paper, we demonstrate, using stratigraphy, a time and intensity coincidence between PTB volcanic ash and the main extinction horizon. Geochemistry of the PTB volcanic ashes in five sections in South China indicates that they were derived from continental magmatic arc. Zircons extracted from the PTB volcanic ashes have negative εHf(t) (- 12.9 to - 2.0) and δ18O (6.8 to 10.9‰), consistent with an acidic volcanism and a crustal-derived origin, and therefore exclude a genetic link between the PTB mass extinction and the Siberian Traps. On the basis of spatial variation in the number of the PTB volcanic ash layers and the thickness of the ash layers in South China, we propose that the PTB volcanic ash may be related to Paleo-Tethys continental arc magmatism in the Kunlun area. Ignimbrite flare-up related to rapid plate subduction during the final assemblage of the Pangea super-continent may have generated a volcanic winter, which eventually triggered the collapse of ecosystem and ultimately mass extinction at the end of the Permian. The Siberian Traps may have been responsible for a greenhouse effect and so have been responsible for both a second pulse of the extinction event and Early Triassic ecological evolution.

  16. Comparison of sampling methods for radiocarbon dating of carbonyls in air samples via accelerator mass spectrometry

    NASA Astrophysics Data System (ADS)

    Schindler, Matthias; Kretschmer, Wolfgang; Scharf, Andreas; Tschekalinskij, Alexander

    2016-05-01

    Three new methods to sample and prepare various carbonyl compounds for radiocarbon measurements were developed and tested. Two of these procedures utilized the Strecker synthetic method to form amino acids from carbonyl compounds with either sodium cyanide or trimethylsilyl cyanide. The third procedure used semicarbazide to form crystalline carbazones with the carbonyl compounds. The resulting amino acids and semicarbazones were then separated and purified using thin layer chromatography. The separated compounds were then combusted to CO2 and reduced to graphite to determine 14C content by accelerator mass spectrometry (AMS). All of these methods were also compared with the standard carbonyl compound sampling method wherein a compound is derivatized with 2,4-dinitrophenylhydrazine and then separated by high-performance liquid chromatography (HPLC).

  17. Measurement error models in chemical mass balance analysis of air quality data

    NASA Astrophysics Data System (ADS)

    Christensen, William F.; Gunst, Richard F.

    The chemical mass balance (CMB) equations have been used to apportion observed pollutant concentrations to their various pollution sources. Typical analyses incorporate estimated pollution source profiles, estimated source profile error variances, and error variances associated with the ambient measurement process. Often the CMB model is fit to the data using an iteratively re-weighted least-squares algorithm to obtain the effective variance solution. We consider the chemical mass balance model within the framework of the statistical measurement error model (e.g., Fuller, W.A., Measurement Error Models, Wiley, NewYork, 1987), and we illustrate that the models assumed by each of the approaches to the CMB equations are in fact special cases of a general measurement error model. We compare alternative source contribution estimators with the commonly used effective variance estimator when standard assumptions are valid and when such assumptions are violated. Four approaches for source contribution estimation and inference are compared using computer simulation: weighted least squares (with standard errors adjusted for source profile error), the effective variance approach of Watson et al. (Atmos, Environ., 18, 1984, 1347), the Britt and Luecke (Technometrics, 15, 1973, 233) approach, and a method of moments approach given in Fuller (1987, p. 193). For the scenarios we consider, the simplistic weighted least-squares approach performs as well as the more widely used effective variance solution in most cases, and is slightly superior to the effective variance solution when source profile variability is large. The four estimation approaches are illustrated using real PM 2.5 data from Fresno and the conclusions drawn from the computer simulation are validated.

  18. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses. PMID:26583448

  19. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean

    USGS Publications Warehouse

    Garrison, Virginia H.; Majewski, Michael S.; Foreman, William T.; Genualdi, Susan A.; Mohammed, Azad; Massey Simonich, Stacy L.

    2014-01-01

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9–126 ng/m3 (mean = 25 ± 34) at source and 0.05–0.71 ng/m3 (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1–3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  20. Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

    PubMed

    Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

    2014-01-01

    A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future. PMID:24211802

  1. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean.

    PubMed

    Garrison, V H; Majewski, M S; Foreman, W T; Genualdi, S A; Mohammed, A; Massey Simonich, S L

    2014-01-15

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9-126 ng/m(3) (mean = 25 ± 34) at source and 0.05-0.71 ng/m(3) (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1-3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses. PMID:24055669

  2. Spectral effects on latitude-tilt and vertical PV modules as affected by latitude, air mass, and climate

    NASA Astrophysics Data System (ADS)

    Gueymard, Christian A.

    2007-09-01

    Using the same SMARTS radiative code as for the development of improved reference spectra for PV rating, an analysis of the spectral sensitivity of specific PV technologies to varying air mass and other factors is presented. To the difference of previous studies, the approach taken here considers realistic atmospheric conditions, as measured at five North- American sites from widely different climatic zones. Two different PV applications (latitude-tilted flat-plates and vertical building-integrated modules) are showcased with seven possible materials, including a-Si, m-Si, and triple junctions. Considering the most frequent clear-sky conditions around the summer solstice at the selected sites, the Spectral Enhancement Factor (SEF) is calculated both for a fixed air mass (1.5) and daily-average spectral conditions. This analysis provides a preliminary assessment of how latitude, local climatic conditions, and PV geometry affect the relative merits of different technologies relatively to standard rating conditions. In particular, it is shown that, in summer, latitude-tilt PV modules experience bluer incident spectra than the reference spectrum, therefore favoring the a-Si modules (SEF > 1). For vertical-tilt PV systems, the SEF is generally lower than for latitude-tilt systems, with the notable exception of m- Si. When considering daily-average results, the effective SEF can become extremely low in the case of a-Si (down to 0.65) and moderately high for m-Si (up to 1.09). It is concluded that the effects of location, season, and PV material on the spectral effect needs to be investigated in detail, particularly for applications involving vertical building-integrated systems.

  3. Atmospheric pollutants in Chiang Mai (Thailand) over a five-year period (2005-2009), their possible sources and relation to air mass movement

    NASA Astrophysics Data System (ADS)

    Chantara, Somporn; Sillapapiromsuk, Sopittaporn; Wiriya, Wan

    2012-12-01

    Monitoring and analysis of the chemical composition of air pollutants were conducted over a five-year period (2005-2009) in the sub-urban area of Chiang Mai, Thailand. This study aims to determine the seasonal variation of atmospheric ion species and gases, examine their correlations, identify possible sources and assess major air-flow patterns to the receptor. The dominant gas and particulate pollutants were NH3 (43-58%) and SO42- (39-48%), respectively. The annual mean concentrations of NH3 (μg m-3) in descending order were 4.08 (2009) > 3.32 (2007) > 2.68 (2008) > 2.47 (2006) and 1.87 (2005), while those of SO42- (μg m-3) were 2.60 (2007) > 2.20 (2006) > 1.95 (2009) > 1.75 (2008) and 1.26 (2005). Concentrations of particulate ions were analyzed by principle component analysis to find out the possible sources of air pollutants in this area. The first component of each year had a high loading of SO42- and NH4+, which probably came from fuel combustion and agricultural activity, respectively. K+, a tracer of biomass burning, also contributed to the first or the second components of each year. Concentrations of NH4+ and SO42- were well correlated (r > 0.777, p < 0.01), which lead to the conclusion that (NH4)2SO4 was a major compound present in this area. The 3-day backward trajectories of air mass arriving at Chiang Mai from 2005 to 2009 were analyzed using the hybrid single particle langrangian integrated trajectory (HYSPLIT) model and grouped by cluster analysis. The air mass data was analyzed for the dry season (n = 18; 100%). The trajectory of air mass in 2005 mainly originated locally (67%). In 2006, the recorded data showed that 56% of air mass was emitted from the western continental region of Thailand. In 2007, the percent ratios from the western and eastern continental areas were equal (39%). In 2008, 67% originated from the western continental area. In 2009, the recorded air mass mainly came from the western continental area (72%). In conclusion, the

  4. Evaluation of a regional air quality model using satellite column NO2: treatment of observation errors and model boundary conditions and emissions

    NASA Astrophysics Data System (ADS)

    Pope, R. J.; Chipperfield, M. P.; Savage, N. H.; Ordonez, C.; Neal, L. S.; Lee, L. A.; Dhomse, S. S.; Richards, N. A. D.; Keslake, T. D.

    2015-05-01

    We compare tropospheric column NO2 between the UK Met Office operational Air Quality in the Unified Model (AQUM) and satellite observations from the Ozone Monitoring Instrument (OMI) for 2006. Column NO2 retrievals from satellite instruments are prone to large uncertainty from random, systematic and smoothing errors. We present an algorithm to reduce the random error of time-averaged observations, once smoothing errors have been removed with application of satellite averaging kernels to the model data. This reduces the total error in seasonal mean columns by 10-70%, which allows critical evaluation of the model. The standard AQUM configuration evaluated here uses chemical lateral boundary conditions (LBCs) from the GEMS (Global and regional Earth-system Monitoring using Satellite and in situ data) reanalysis. In summer the standard AQUM overestimates column NO2 in northern England and Scotland, but underestimates it over continental Europe. In winter, the model overestimates column NO2 across the domain. We show that missing heterogeneous hydrolysis of N2O5 in AQUM is a significant sink of column NO2 and that the introduction of this process corrects some of the winter biases. The sensitivity of AQUM summer column NO2 to different chemical LBCs and NOx emissions data sets are investigated. Using Monitoring Atmospheric Composition and Climate (MACC) LBCs increases AQUM O3 concentrations compared with the default GEMS LBCs. This enhances the NOx-O3 coupling leading to increased AQUM column NO2 in both summer and winter degrading the comparisons with OMI. Sensitivity experiments suggest that the cause of the remaining northern England and Scotland summer column NO2 overestimation is the representation of point source (power station) emissions in the model.

  5. Evaluation of a regional air quality model using satellite column NO2: treatment of observation errors and model boundary conditions and emissions

    NASA Astrophysics Data System (ADS)

    Pope, R. J.; Chipperfield, M. P.; Savage, N. H.; Ordóñez, C.; Neal, L. S.; Lee, L. A.; Dhomse, S. S.; Richards, N. A. D.

    2014-08-01

    We compare tropospheric column NO2 between the UK Met Office operational Air Quality in the Unified Model (AQUM) and satellite observations from the Ozone Monitoring Instrument (OMI) for 2006. Column NO2 retrievals from satellite instruments are prone to large uncertainty from random, systematic and smoothing errors. We present an algorithm to reduce the random error of time-averaged observations, once smoothing errors have been removed with application of satellite averaging kernels to the model data. This reduces the total error in seasonal mean columns by 30-90%, which allows critical evaluation of the model. The standard AQUM configuration evaluated here uses chemical lateral boundary conditions (LBCs) from the GEMS (Global and regional Earth-system Monitoring using Satellite and in-situ data) reanalysis. In summer the standard AQUM overestimates column NO2 in northern England and Scotland, but underestimates it over continental Europe. In winter, the model overestimates column NO2 across the domain. We show that missing heterogeneous hydrolysis of N2O5 in AQUM is a significant sink of column NO2 and that the introduction of this process corrects some of the winter biases. The sensitivity of AQUM summer column NO2 to different chemical LBCs and NOx emissions datasets are investigated. Using Monitoring Atmospheric Composition and Climate (MACC) LBCs increases AQUM O3 concentrations compared with the default GEMS LBCs. This enhances the NOx-O3 coupling leading to increased AQUM column NO2 in both summer and winter degrading the comparisons with OMI. Sensitivity experiments suggest that the cause of the remaining northern England and Scotland summer column NO2 overestimation is the representation of point source (power station) emissions in the model.

  6. Identification of water-soluble polar organics in air and vehicular emitted particulate matter using ultrahigh resolution mass spectrometry and Capillary electrophoresis - mass spectrometry.

    NASA Astrophysics Data System (ADS)

    Schmitt-Kopplin, P.; Yassine, M.; Gebefugi, I.; Hertkorn, N.; Dabek-Zlotorzynska, E.

    2009-04-01

    The effects of aerosols on human health, atmospheric chemistry, and climate are among the central topics in current environmental health research. Detailed and accurate measurements of the chemical composition of air particulate matter (PM) represent a challenging analytical task. Minute sample amounts are usually composed of several main constituents and hundreds of minor and trace constituents. Moreover, the composition of individual particles can be fairly uniform or very different (internally or externally mixed aerosols), depending on their origin and atmospheric aging processes (coagulation, condensation / evaporation, chemical reaction). The aim of the presentation was the characterization of the organic matter (OM) fraction of environmental aerosols which is not accessible by GC-methods, either because of their high molecular weight, their polarity or due to thermal instability. We also describe the main chemical characteristics of complexe oligomeric organic fraction extracted from different aerosols collected in urban and rural area in Germany and Canada. Mass spectrometry (MS) became an essential tool used by many prominent leaders of the biological research community and the importance of MS to the future of biological research is now clearly evident as in the fields of Proteomics and Metabolomics. Especially Fourier Transform Ion Cyclotron Mass Spectrometry (ICR-FT/MS) is an ultrahigh resolution MS that allows new approach in the analysis of complex mixtures. The mass resolution (< 200 ppb) allowed assigning the elemental composition (C, H, O, N, S…) to each of the obtained mass peaks and thus already a description of the mixture in terms of molecular composition. This possibility is used by the authors together with a high resolution separation method of charged compounds: capillary electrophoresis. A CE-ESI-MS method using an ammonium acetate based background electrolyte (pH 4.7) was developed for the determination of isomeric benzoic acids in

  7. Combining airborne gas and aerosol measurements with HYSPLIT: a visualization tool for simultaneous evaluation of air mass history and back trajectory consistency

    NASA Astrophysics Data System (ADS)

    Freitag, S.; Clarke, A. D.; Howell, S. G.; Kapustin, V. N.; Campos, T.; Brekhovskikh, V. L.; Zhou, J.

    2014-01-01

    The history of air masses is often investigated using backward trajectories to gain knowledge about processes along the air parcel path as well as possible source regions. Here, we describe a refined approach that incorporates airborne gas, aerosol, and environmental data into back trajectories and show how this technique allows for simultaneous evaluation of air mass history and back trajectory reliability without the need to calculate trajectory errors. We use the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model and add a simple semi-automated computing routine to facilitate high-frequency coverage of back trajectories initiated along free tropospheric (FT) flight tracks and profiles every 10 s. We integrate our in situ physiochemical data by color-coding each of these trajectories with its corresponding in situ tracer values measured at the back trajectory start points along the flight path. The unique color for each trajectory aids assessment of trajectory reliability through the visual clustering of air mass pathways of similar coloration. Moreover, marked changes in trajectories associated with marked changes evident in measured physiochemical or thermodynamic properties of an air mass add credence to trajectories. This is particularly true when these air mass properties are linked to trajectory features characteristic of recognized sources or processes. This visual clustering of air mass pathways is of particular value for large-scale 3-D flight tracks common to aircraft experiments where air mass features of interest are often spatially distributed and temporally separated. The cluster-visualization tool used here reveals that most FT back trajectories with pollution signatures measured in the central equatorial Pacific reach back to sources on the South American continent over 10 000 km away and 12 days back in time, e.g., the Amazonian basin. We also demonstrate the distinctions in air mass properties between these and trajectories

  8. Magnetostratigraphy of a Marine Triassic-Jurassic Boundary Section, Kennecott Point, Queen Charlotte Islands: Implications for the Temporal Correlation of a 'Big Five' Mass Extinction Event.

    NASA Astrophysics Data System (ADS)

    Hilburn, I. A.; Kirschvink, J. L.; Ward, P. D.; Haggart, J. W.; Raub, T. D.

    2008-12-01

    Several causes have been proposed for Triassic-Jurassic (T-J) boundary extinctions, including global ocean anoxia/euxinia, an impact event, and/or eruption of the massive Central Atlantic Magmatic Province (CAMP), but poor intercontinental correlation makes testing these difficult. Sections at Kennecott Point, Queen Charlotte Islands, British Columbia span the late Norian through Rhaetian (Triassic) and into the earliest Hettangian (Jurassic) and provide the best integrated magneto- and chemostratigraphic framework for placing necessary temporal constraints upon the T-J mass extinctions. At Kennecott Point, turnover of radiolaria and ammonoids define the T-J boundary marine extinction and are coincident with a 2 ‰ negative excursion in δ13Corg similar in magnitude to that observed at Ferguson Hill (Muller Canyon), Nevada (1, 2). With Conodont Alteration Index values in the 1-2 range, Kennecott Point provides the ideal setting for use of magnetostratigraphy to tie the marine isotope excursion into the chronostratigraphic framework of the Newark, Hartford, and Fundy Basins. In the summer of 2005, we collected a ~1m resolution magnetostratigraphic section from 105 m of deep marine, silt- and sandstone turbidites and interbedded mudstones, spanning the T-J boundary at Kennecott Point. Hybrid progressive demagnetization - including zero-field, low-temperature cycling; low-field AF cleaning; and thermal demagnetization in ~25°C steps to 445°C under flowing N2 gas (3) - first removed a Northerly, steeply inclined component interpreted to be a Tertiary overprint, revealing an underlying dual-polarity component of moderate inclination. Five major polarity zones extend through our section, with several short, one-sample reversals interspersed amongst them. Comparison of this pattern with other T-J boundary sections (4-6) argues for a Northern hemisphere origin of our site, albeit with large vertical-axis rotations. A long normal chron bounds the T-J boundary punctuated

  9. Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

    NASA Technical Reports Server (NTRS)

    Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Grant, William B.; Ismail, Syed; Ferrare, Richard A.; Kooi, Susan A.; Brackett, Vincent G.; Clayton, Marian B.; Avery, Melody A.

    2001-01-01

    Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The

  10. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    SciTech Connect

    Mernild, Sebastian Haugard; Liston, Glen

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  11. Selective Mass Spectrometer Characterization of Halogen Gases in Air at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Dahl, S.; Ivey, M. M.; Foster, K. L.

    2004-12-01

    We have developed a new interface for use with a commercial ion-trap mass spectrometer equipped with atmospheric pressure chemical ionization (APCI-MS). The new interface uses a mechanical pump to draw gaseous analyte through a glass manifold and into the corona discharge area of the APCI-MS. This new method of delivering a gaseous sample at atmospheric pressure directly to the MS has been used to obtain real-time measurements of Br2 and Cl2 over synthetic seawater ice. The ion intensity of a halogen gas measured by the MS is affected by the pumping rate and the position of the glass manifold. The MS signals for Br2 are linear in the 0.1 to 10.6 ppbv range, and the estimated 3 sigma detection limit is 20.7 pptv. The MS signals for Cl2 are linear in the 0.2 to 25 ppbv range, and the estimated 3 sigma detection limit is 1.081 ppbv. This lab-based technique is suitable to be the basis for a portable field-based design. Such a design, a miniaturized instrument, will help elucidate the role of seawater snow and ice surfaces on the photochemical production of Br2 and Cl2 in the high Arctic.

  12. Long-term measurements of particle number size distributions and the relationships with air mass history and source apportionment in the summer of Beijing

    NASA Astrophysics Data System (ADS)

    Wang, Z. B.; Hu, M.; Wu, Z. J.; Yue, D. L.; He, L. Y.; Huang, X. F.; Liu, X. G.; Wiedensohler, A.

    2013-02-01

    A series of long-term and temporary measurements were conducted to study the improvement of air quality in Beijing during Olympic Games period (8-24 August 2008). To evaluate actions taken to improve the air quality, comparisons of particle number and volume size distributions of August 2008 and 2004-2007 were performed. The total particle number and volume concentrations were 14 000 cm-3 and 37 μm3 cm-3 in August of 2008, respectively. These were reductions of 41% and 35% compared with the mean values of August 2004-2007. A cluster analysis on air mass history and source apportionment were performed, exploring reasons of the reduction of particle concentrations. Back trajectories were classified into five major clusters. Air mass from south direction are always associated with pollution events during the summertime of Beijing. In August 2008, the frequency of air mass arriving from south has been twice higher compared to the average of the previous years, these southerly air masses did however not result in elevated particle volume concentrations in Beijing. This result implied that the air mass history was not the key factor, explaining reduced particle number and volume concentrations during the Beijing 2008 Olympic Games. Four factors were found influencing particle concentrations using a Positive matrix factorization (PMF) model. They were identified to local and remote traffic emissions, combustion sources as well as secondary transformation. The reductions of the four sources were calculated to 47%, 44%, 43% and 30%, respectively. The significant reductions of particle number and volume concentrations may attribute to actions taken, focusing on primary emissions, especially related to the traffic and combustion sources.

  13. Polycyclic aromatic hydrocarbons in air on small spatial and temporal scales - II. Mass size distributions and gas-particle partitioning

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Klánová, Jana; Ilić, Predrag; Kohoutek, Jiří; Gasić, Bojan; Kovacić, Igor; Škrdlíková, Lenka

    2010-12-01

    Polycyclic aromatic hydrocarbons (PAHs) were measured together with inorganic air pollutants at two urban sites and one rural background site in the Banja Luka area, Bosnia and Hercegovina, during 72 h in July 2008 using a high time resolution (5 samples per day) with the aim to study gas-particle partitioning, aerosol mass size distributions and to explore the potential of a higher time resolution (4 h-sampling). In the particulate phase the mass median diameters of the PAHs were found almost exclusively in the accumulation mode (0.1-1.0 μm of size). These were larger for semivolatile PAHs than for non-volatile PAHs. Gas-particle partitioning of semivolatile PAHs was strongly influenced by temperature. The results suggest that the Junge-Pankow model is inadequate to explain the inter-species variation and another process must be significant for phase partitioning which is less temperature sensitive than adsorption. Care should be taken when interpreting slopes m of plots of the type log K p = m log p L0 + b based on 24 h means, as these are found sensitive to the time averaging, i.e. tend to be higher than when based on 12 h-mean samples.

  14. First day of an oil spill on the open sea: early mass transfers of hydrocarbons to air and water.

    PubMed

    Gros, Jonas; Nabi, Deedar; Würz, Birgit; Wick, Lukas Y; Brussaard, Corina P D; Huisman, Johannes; van der Meer, Jan R; Reddy, Christopher M; Arey, J Samuel

    2014-08-19

    During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m(3) oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km(2) area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models. PMID:25103722

  15. The potential of LIRIC to validate the vertical profiles of the aerosol mass concentration estimated by an air quality model

    NASA Astrophysics Data System (ADS)

    Siomos, Nikolaos; Filoglou, Maria; Poupkou, Anastasia; Liora, Natalia; Dimopoulos, Spyros; Melas, Dimitris; Chaikovsky, Anatoli; Balis, Dimitris

    2015-04-01

    Vertical profiles of the aerosol mass concentration derived by a retrieval algorithm that uses combined sunphotometer and LIDAR data (LIRIC) were used in order to validate the mass concentration profiles estimated by the air quality model CAMx. LIDAR and CIMEL measurements of the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki were used for this validation.The aerosol mass concentration profiles of the fine and coarse mode derived by CAMx were compared with the respective profiles derived by the retrieval algorithm. For the coarse mode particles, forecasts of the Saharan dust transportation model BSC-DREAM8bV2 were also taken into account. Each of the retrieval algorithm's profiles were matched to the models' profile with the best agreement within a time window of four hours before and after the central measurement. OPAC, a software than can provide optical properties of aerosol mixtures, was also employed in order to calculate the angstrom exponent and the lidar ratio values for 355nm and 532nm for each of the model's profiles aiming in a comparison with the angstrom exponent and the lidar ratio values derived by the retrieval algorithm for each measurement. The comparisons between the fine mode aerosol concentration profiles resulted in a good agreement between CAMx and the retrieval algorithm, with the vertical mean bias error never exceeding 7 μgr/m3. Concerning the aerosol coarse mode concentration profiles both CAMx and BSC-DREAM8bV2 values are severely underestimated, although, in cases of Saharan dust transportation events there is an agreement between the profiles of BSC-DREAM8bV2 model and the retrieval algorithm.

  16. Cumulative ventilation air drying potential as an indication of dry mass content in wastewater sludge in a thin-layer solar drying facility

    NASA Astrophysics Data System (ADS)

    Krawczyk, Piotr

    2013-12-01

    Controlling low-temperature drying facilities which utilise nonprepared air is quite difficult, due to very large variability of ventilation air parameters - both in daily and seasonal cycles. The paper defines the concept of cumulative drying potential of ventilation air and presents experimental evidence that there is a relation between this parameter and condition of the dried matter (sewage sludge). Knowledge on current dry mass content in the dried matter (sewage sludge) provides new possibilities for controlling such systems. Experimental data analysed in the paper was collected in early 2012 during operation of a test solar drying facility in a sewage treatment plant in Błonie near Warsaw, Poland.

  17. The Potential of The Synergy of Sunphotometer and Lidar Data to Validate Vertical Profiles of The Aerosol Mass Concentration Estimated by An Air Quality Model

    NASA Astrophysics Data System (ADS)

    Siomos, N.; Filioglou, M.; Poupkou, A.; Liora, N.; Dimopoulos, S.; Melas, D.; Chaikovsky, A.; Balis, D. S.

    2016-06-01

    Vertical profiles of the aerosol mass concentration derived by the Lidar/Radiometer Inversion Code (LIRIC), that uses combined sunphotometer and lidar data, were used in order to validate the aerosol mass concentration profiles estimated by the air quality model CAMx. Lidar and CIMEL measurements performed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece (40.5N, 22.9E) from the period 2013-2014 were used in this study.

  18. Analysis of heat and mass transfer between air and falling film desiccant for different flow configurations in the presence of ultrafine particles

    NASA Astrophysics Data System (ADS)

    Ali, Ahmad A.

    This work focuses on the enhancement of heat and mass transfer between air and falling desiccant film for different flow channel configurations. Cu-Ultrafine particles are added to the desiccant film to investigate the enhancement in heat and mass transfer between air and desiccant film for dehumidification and cooling processes of the air and regeneration of desiccant film. A detailed comparative study between parallel and counter flow channels is performed using a parametric study to investigate the enhancements in dehumidification, cooling, and regeneration processes in terms of the pertinent parameters. The results reveal that the parallel flow arrangement provides better dehumidification and cooling for the air than the counter flow channel for a wide range of parameters. Next, the inclined parallel and counter flow configurations are investigated using an Alternating Direction Implicit (ADI) and successive over-relaxation methods to discretize the vorticity and stream-function equations, respectively. A parametric study is employed to investigate the inclination angle effects in enhancing the heat and mass transfer in terms of the controlling parameters. It is shown that inclination angle plays a significant role in enhancing the dehumidification, cooling, and regeneration processes. Finally, the enhancements in heat and mass transfer in cross flow channel between air and desiccant film is examined based on a parametric study to investigate the dehumidification and cooling processes of the air in terms of the pertinent controlling parameters. These parameters are air and desiccant Reynolds numbers, dimensions of the channel, volume fraction of Cu-ultrafine particles, and thermal dispersion effects. It is found that an increase in the Cu-volume fraction increases dehumidification and cooling capabilities and produce more stable Cu-desiccant film.

  19. Boundary Crossing and Boundary Objects

    ERIC Educational Resources Information Center

    Akkerman, Sanne F.; Bakker, Arthur

    2011-01-01

    Diversity and mobility in education and work present a paramount challenge that needs better conceptualization in educational theory. This challenge has been addressed by educational scholars with the notion of "boundaries", particularly by the concepts of "boundary crossing" and "boundary objects". Although studies on boundary crossing and…

  20. Characterization of key aerosol, trace gas and meteorological properties and particle formation and growth processes dependent on air mass origins in coastal Southern Spain

    NASA Astrophysics Data System (ADS)

    Diesch, J.; Drewnick, F.; Sinha, V.; Williams, J.; Borrmann, S.

    2011-12-01

    The chemical composition and concentration of aerosols at a certain site can vary depending on season, the air mass source region and distance from sources. Regardless of the environment, new particle formation (NPF) events are one of the major sources for ultrafine particles which are potentially hazardous to human health. Grown particles are optically active and efficient CCN resulting in important implications for visibility and climate (Zhang et al., 2004). The study presented here is intended to provide information about various aspects of continental, urban and marine air masses reflected by wind patterns of the air arriving at the measurement site. Additionally we will be focusing on NPF events associated with different types of air masses affecting their emergence and temporal evolution. Measurements of the ambient aerosol, various trace gases and meteorological parameters were performed within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from mid-November to mid-December 2008 at the atmospheric research station "El Arenosillo" located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean. Number and mass as well as PAH and black carbon concentrations were measured in PM1 and size distribution instruments covered the size range 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (AMS). In order to evaluate the characteristics of different air masses linking local and regional sources as well as NPF processes, characteristic air mass types were classified dependent on backwards trajectory pathways and local meteorology. Large nuclei mode concentrations in the number size distribution were found within continental and urban influenced air mass types due to frequently occurring NPF events. Exploring individual production and sink variables, sulfuric

  1. High-resolution distributed temperature sensing: a new tool to study the space-time dynamics of transient cold-air pools in the weak-wind stable boundary layer

    NASA Astrophysics Data System (ADS)

    Thomas, C. K.; Selker, J. S.; Zeeman, M. J.

    2011-12-01

    We present a novel approach to observing the two-dimensional thermal structure of atmospheric near-surface turbulent and non-turbulent flows by measuring air temperatures in a vertical plane at a high resolution (0.25 m, every approximately 2 s) using distributed temperature sensing (DTS). Air temperature observations obtained from a fiber optics array of approximate dimensions 8 by 8 m and sonic anemometer data from two levels were collected for a period of 23 days over a short grass field located in the flat bottom of a wide valley with moderate surface heterogeneity. In addition to evaluating the DTS technique to resolve the rapidly changing gradients and small-scale perturbations associated with turbulence in the atmosphere for convective and stable boundary layers, the objective was to analyze the space-time dynamics of transient cold-air pools in the stable boundary layer. The time response and precision of the fiber temperatures were adequate to resolve individual sub-meter sized turbulent and non-turbulent structures of time scales >= 3 s and enabled calculation of meaningful sensible heat fluxes when combined with vertical wind observations. The small turbulence scales associated with strong vertical shear and low measurement heights pose limitations to the technique. The top of the transient cold-air pool was highly non-stationary. The thermal structure of the near-surface air is generally a superposition of various perturbations of different time and length scales, whereas no preferred scales were identified. Vertical length scales for turbulence in the strongly stratified transient cold-air pool directly derived from the DTS data agreed well with buoyancy length scales parameterized using the vertical velocity variance and the Brunt-Vaisala frequency, while scales for weak stratification disagreed. The high-resolution DTS technique opens a new window into spatially sampling geophysical fluid flows including turbulent energy exchange with a broad

  2. Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH

    ERIC Educational Resources Information Center

    Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P.

    2011-01-01

    Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various…

  3. REAL TIME, ON-LINE CHARACTERIZATION OF DIESEL GENERATOR AIR TOXIC EMISSIONS BY RESONANCE ENHANCED MULTI-PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY

    EPA Science Inventory

    The laser based resonance, enhanced multi-photon ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds ...

  4. Deev Jahi Model of the Permian Triassic boundary mass extinction: a case for gas hydrates as the main cause of biological crisis on Earth

    NASA Astrophysics Data System (ADS)

    Heydari, E.; Hassanzadeh, J.

    2003-12-01

    The smoking gun revealing the secrets of the end-Permian mass mortality is a unique 1-2-m-thick layer consisting of 5-20-cm-long crystals of calcite that occurs precisely at the Permian-Triassic boundary (PTB) in Iran, Armenia, Turkey, and China. This layer is interpreted as synsedimentary, abiotic, seafloor cement indicative of precipitation from a highly carbonate supersaturated seawater. Its δ13C composition ( δ13C=0‰ PDB) is 4‰ to 5‰ PDB lower than the typical Upper Permian values (4‰ to 5‰ PDB), suggesting the involvement of massive amounts of gas hydrate CH 4 ( δ13C=-60‰ PDB). The temporal coincidence of the cement layer with the PTB suggests that the process that promoted seafloor cementation was also responsible for the biological crisis. A cementation model is developed based on accumulation-dissociation cycle of gas hydrates which also explains the mass extinction at the PTB. The Upper Permian accumulation period of gas hydrates ended abruptly adjacent to the PTB and the dissociation event began releasing 3.2 to 4.7×10 18 g CH 4 into the ocean. Oxidation of CH 4 in the water column created a seawater that was charged with CO 2 (an oceanic acid bath) and had lower than normal O 2 content (but not anoxic). This oceanic acid bath first dissolved suspended fine-grained carbonate particles and small calcareous organisms, followed by extensive dissolution of platform carbonates raising Ca 2+ and HCO 3- concentrations of seawater. When the release of CH 4 declined, the acid-bath ocean became a soda ocean precipitating massive amount of seafloor cements observed globally at the PTB. The study suggests that prior to cement precipitation, the PTB ocean was charged with CO 2, warm, had low oxygen, high Ca 2+, and high HCO 3- concentrations. These conditions collectively created stressful conditions causing the marine mass mortality. The leakage of CH 4 to the atmosphere produced a super-hot climate resulting in the biological devastation on land. The

  5. Determination of trichloroanisole and trichlorophenol in wineries' ambient air by passive sampling and thermal desorption-gas chromatography coupled to tandem mass spectrometry.

    PubMed

    Camino-Sánchez, F J; Bermúdez-Peinado, R; Zafra-Gómez, A; Ruíz-García, J; Vílchez-Quero, J L

    2015-02-01

    The present paper describes the calibration of selected passive samplers used in the quantitation of trichlorophenol and trichloroanisole in wineries' ambient air, by calculating the corresponding sampling rates. The method is based on passive sampling with sorbent tubes and involves thermal desorption-gas chromatography-triple quadrupole mass spectrometry analysis. Three commercially available sorbents were tested using sampling cartridges with a radial design instead of axial ones. The best results were found for Tenax TA™. Sampling rates (R-values) for the selected sorbents were determined. Passive sampling was also used for accurately determining the amount of compounds present in the air. Adequate correlation coefficients between the mass of the target analytes and exposure time were obtained. The proposed validated method is a useful tool for the early detection of trichloroanisole and its precursor trichlorophenol in wineries' ambient air while avoiding contamination of wine or winery facilities. PMID:25576042

  6. Assimilating airborne gas and aerosol measurements into HYSPLIT: a visualization tool for simultaneous assessment of air mass history and back trajectory reliability

    NASA Astrophysics Data System (ADS)

    Freitag, S.; Clarke, A. D.; Howell, S. G.; Kapustin, V. N.; Campos, T.; Brekhovskikh, V. L.; Zhou, J.

    2013-06-01

    Backward trajectories are commonly used to gain knowledge about the history of airborne observations in terms of possible processes along their path as well as feasible source regions. Here, we describe a refined approach that incorporates airborne gas, aerosol, and environmental data into back trajectories and show how this technique allows for simultaneous assessment of air mass history and back trajectory reliability without the need of calculating trajectory errors. We use the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model and add a simple semi-automated computing routine to facilitate high-frequency coverage of back trajectories initiated along the flight track every 10 s. We integrate our in-situ physiochemical data by color-coding each of these trajectories with its corresponding in-situ tracer values measured at the back trajectory start points along the flight path. The unique color for each trajectory aids assessment of trajectory reliability through the visual clustering of air mass pathways of similar coloration. Moreover, marked changes in trajectories associated with marked changes evident in measured physiochemical or thermodynamic properties of an air mass add credence to trajectories, particularly when these air mass properties are linked to trajectory features characteristic of recognized sources or processes. This visual clustering of air mass pathways is of particular value for large-scale 3-D flight tracks common to aircraft experiments where air mass features of interest are often spatially distributed and temporally separated. The cluster-visualization tool used here reveals most back trajectories with pollution signatures measured in the Central Equatorial Pacific reach back to sources on the South American continent over 10 000 km away and 12 days back in time, e.g. the Amazonian basin. We also demonstrate the distinctions in air mass properties between these and trajectories that penetrate deep convection in the

  7. Transport Regimes of Air Masses Affecting the Tropospheric Composition of the Canadian and European Arctic During RACEPAC 2014 and NETCARE 2014/2015

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Hoor, P. M.; Koellner, F.; Kunkel, D.; Schneider, J.; Schulz, C.; Herber, A. B.; Borrmann, S.; Wendisch, M.; Ehrlich, A.; Leaitch, W. R.; Willis, M. D.; Burkart, J.; Thomas, J. L.; Abbatt, J.

    2015-12-01

    The Arctic is warming much faster than any other place in the world and undergoes a rapid change dominated by a changing climate in this region. The impact of polluted air masses traveling to the Arctic from various remote sources significantly contributes to the observed climate change, in contrast there are additional local emission sources contributing to the level of pollutants (trace gases and aerosol). Processes affecting the emission and transport of these pollutants are not well understood and need to be further investigated. We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories we analyze the transport regimes prevalent during spring (RACEPAC 2014 and NETCARE 2015) and summer (NETCARE 2014) in the observed region. Whereas the eastern part of the Canadian Arctic is affected by air masses with their origin in Asia, in the central and western parts of the Canadian and European Arctic air masses from North America are predominant at the time of the measurement. In general the more northern parts of the Arctic were relatively unaffected by pollution from mid-latitudes since air masses mostly travel within the polar dome, being quite isolated. Associated mixing ratios of CO and CO2 fit into the seasonal cycle observed at NOAA ground stations throughout the Arctic, but show a more mid-latitudinal characteristic at higher altitudes. The transition is remarkably sharp and allows for a chemical definition of the polar dome. At low altitudes, synoptic disturbances transport polluted air masses from mid-latitudes into regions of the polar dome. These air masses contribute to the Arctic pollution background, but also

  8. Gas chromatographic-mass spectroscopic determination of benzene in indoor air during the use of biomass fuels in cooking time.

    PubMed

    Sinha, Sukesh Narayan; Kulkarni, P K; Desai, N M; Shah, S H; Patel, G M; Mansuri, M M; Parikh, D J; Saiyed, H N

    2005-02-18

    A gas chromatography-mass spectroscopic method in electron ionization (EI) mode with MS/MS ion preparation using helium at flow rate 1 ml min(-1) as carrier gas on DB-5 capillary column (30 m x 0.25 mm i.d. film thickness 0.25 microm) has been developed for the determination of benzene in indoor air. The detection limit for benzene was 0.002 microg ml(-1) with S/N: 4 (S: 66, N: 14). The benzene concentration for cooks during cooking time in indoor kitchen using dung fuel was 114.1 microg m(-3) while it was 6.6 microg m(-3) for open type kitchen. The benzene concentration was significantly higher (p < 0.01) in indoor kitchen with respect to open type kitchen using dung fuels. The wood fuel produces 36.5 microg m(-3) of benzene in indoor kitchen. The concentration of benzene in indoor kitchen using wood fuel was significantly (p < 0.01) lower in comparison to dung fuel. This method may be helpful for environmental analytical chemist dealing with GC-MS in confirmation and quantification of benzene in environmental samples with health risk exposure assessment. PMID:15782977

  9. Energetics and efficiency analysis of a cobaloxime-modified semiconductor under simulated air mass 1.5 illumination.

    PubMed

    Krawicz, Alexandra; Cedeno, Diana; Moore, Gary F

    2014-08-14

    We report on the energetics and efficiency of a p-type (100) gallium phosphide (GaP) semiconductor functionalized with molecular hydrogen production catalysts via polymer grafting. The catalysts belong to the cobaloxime class of compounds that have recently shown promise in electrocatalysis and solar-to-fuel applications. Attachment of the complex to a semiconductor surface allows direct photoelectrochemical (PEC) measurements of performance. Under simulated air mass 1.5 illumination, the catalyst-modified photocathode yields a 0.92 mA cm(-2) current density when operating at the equilibrium potential for the hydrogen production half reaction. The open circuit photovoltage (VOC) is 0.72 V vs. a reversible hydrogen electrode (RHE) and the fill factor (FF) is 0.33 (a 258% increase compared to polymer-modified electrodes, without cobaloxime treatment). The external quantum efficiency (EQE), measured under a reverse bias of +0.17 vs. RHE, shows a maximum of 67% under 310 nm illumination. Product analysis of the head-space gas yields a lower limit on the Faradaic efficiency of 88%. In addition, the near linear photoresponse of the current density upon increasing illumination indicates that photocarrier transport to the interface can limit performance. These results give insights into the design of improved photocatalytic constructs with additional performance gains. PMID:24619031

  10. Urban air pollution: a representative survey of PM(2.5) mass concentrations in six Brazilian cities.

    PubMed

    de Miranda, Regina Maura; de Fatima Andrade, Maria; Fornaro, Adalgiza; Astolfo, Rosana; de Andre, Paulo Afonso; Saldiva, Paulo

    2012-03-01

    In urban areas of Brazil, vehicle emissions are the principal source of fine particulate matter (PM(2.5)). The World Health Organization air quality guidelines state that the annual mean concentration of PM(2.5) should be below 10 μg m(-3). In a collaboration of Brazilian institutions, coordinated by the University of São Paulo School of Medicine and conducted from June 2007 to August 2008, PM(2.5) mass was monitored at sites with high traffic volumes in six Brazilian state capitals. We employed gravimetry to determine PM(2.5) mass concentrations, reflectance to quantify black carbon concentrations, X-ray fluorescence to characterize elemental composition, and ion chromatography to determine the composition and concentrations of anions and cations. Mean PM(2.5) concentrations and proportions of black carbon (BC) in the cities of São Paulo, Rio de Janeiro, Belo Horizonte, Curitiba, Recife, and Porto Alegre were 28.1 ± 13.6 μg m(-3) (38% BC), 17.2 ± 11.2 μg m(-3) (20% BC), 14.7 ± 7.7 μg m(-3) (31% BC), 14.4 ± 9.5 μg m(-3) (30% BC), 7.3 ± 3.1 μg m(-3) (26% BC), and 13.4 ± 9.9 μg m(-3) (26% BC), respectively. Sulfur and minerals (Al, Si, Ca, and Fe), derived from fuel combustion and soil resuspension, respectively, were the principal elements of the PM(2.5) mass. We discuss the long-term health effects for each metropolitan region in terms of excess mortality risk, which translates to greater health care expenditures. This information could prove useful to decision makers at local environmental agencies. PMID:22408694

  11. Elemental composition and radical formation potency of PM10 at an urban background station in Germany in relation to origin of air masses

    NASA Astrophysics Data System (ADS)

    Hellack, Bryan; Quass, Ulrich; Beuck, Henning; Wick, Gabriele; Kuttler, Wilhelm; Schins, Roel P. F.; Kuhlbusch, Thomas A. J.

    2015-03-01

    At an urban background station in Mülheim-Styrum, North Rhine Westphalia, Germany, a set of 75 PM10 samples was collected over a one year period, followed by analyses for mass, chemical composition and hydroxyl radical (OHrad) formation potency. Additionally, the origin of air masses for the sampling days was calculated by 48-h backward trajectories, subdivided into the four cardinal sectors. Significant lower PM10 mass concentrations were observed for summertime air masses from the west compared to the other seasons and cardinal sectors. For the OHrad formation potency higher values were detected if air masses originate from east and south, thus predominantly being of continental origin. From the elevated OHrad formation potencies in fall and winter a seasonal trend with low potencies in summers is assumed. Furthermore, source apportionment was performed by a positive matrix factor analysis, separating seven plausible factors which could be attributed to mineral dust, secondary nitrate, industry, non-exhaust traffic, fossil fuel combustion, marine aerosol and secondary aerosol factors. The intrinsic OHrad formation potency was found to be associated mainly with the fossil fuel combustion factor (45%) and industry factor (22%).

  12. Boundary layer aerosol size distribution, mass concentration and mineralogical composition in Morocco and at Cape Verde Islands during SAMUM I-II

    NASA Astrophysics Data System (ADS)

    Kandler, K.; Lieke, K.

    2009-04-01

    The Saharan Mineral Dust Experiment (SAMUM) is dedicated to the understanding of the radiative effects of mineral dust. Two major field experiments were performed: A first joint field campaign took place at Ouarzazate and near Zagora, southern Morocco, from May 13 to June 7, 2006. Aircraft and ground based measurements of aerosol physical and chemical properties were carried out to collect a data set of surface and atmospheric columnar information within a major dust source. This data set combined with satellite data provides the base of the first thorough columnar radiative closure tests in Saharan dust. A second field experiment was conducted during January-February 2008, in the Cape Verde Islands region, where about 300 Tg of mineral dust are transported annually from Western Africa across the Atlantic towards the Caribbean Sea and the Amazon basin. Along its transport path, the mineral dust is expected to influence significantly the radiation budget - by direct and indirect effects - of the subtropical North Atlantic. We are lacking a radiative closure in the Saharan air plume. One focus of the investigation within the trade wind region is the spatial distribution of mixed dust/biomass/sea salt aerosol and their physical and chemical properties, especially with regard to radiative effects. We report on measurements of size distributions, mass concentrations and mineralogical composition conducted at the Zagora (Morocco) and Praia (Cape Verde islands) ground stations. The aerosol size distribution was measured from 20 nm to 500

  13. If Dung Beetles (Scarabaeidae: Scarabaeinae) Arose in Association with Dinosaurs, Did They Also Suffer a Mass Co-Extinction at the K-Pg Boundary?

    PubMed Central

    Gunter, Nicole L.; Weir, Tom A.; Cameron, Stephen L.

    2016-01-01

    The evolutionary success of beetles and numerous other terrestrial insects is generally attributed to co-radiation with flowering plants but most studies have focused on herbivorous or pollinating insects. Non-herbivores represent a significant proportion of beetle diversity yet potential factors that influence their diversification have been largely unexamined. In the present study, we examine the factors driving diversification within the Scarabaeidae, a speciose beetle family with a range of both herbivorous and non-herbivorous ecologies. In particular, it has been long debated whether the key event in the evolution of dung beetles (Scarabaeidae: Scarabaeinae) was an adaptation to feeding on dinosaur or mammalian dung. Here we present molecular evidence to show that the origin of dung beetles occurred in the middle of the Cretaceous, likely in association with dinosaur dung, but more surprisingly the timing is consistent with the rise of the angiosperms. We hypothesize that the switch in dinosaur diet to incorporate more nutritious and less fibrous angiosperm foliage provided a palatable dung source that ultimately created a new niche for diversification. Given the well-accepted mass extinction of non-avian dinosaurs at the Cretaceous-Paleogene boundary, we examine a potential co-extinction of dung beetles due to the loss of an important evolutionary resource, i.e., dinosaur dung. The biogeography of dung beetles is also examined to explore the previously proposed “out of Africa” hypothesis. Given the inferred age of Scarabaeinae as originating in the Lower Cretaceous, the major radiation of dung feeders prior to the Cenomanian, and the early divergence of both African and Gondwanan lineages, we hypothesise that that faunal exchange between Africa and Gondwanaland occurred during the earliest evolution of the Scarabaeinae. Therefore we propose that both Gondwanan vicariance and dispersal of African lineages is responsible for present day distribution of

  14. If Dung Beetles (Scarabaeidae: Scarabaeinae) Arose in Association with Dinosaurs, Did They Also Suffer a Mass Co-Extinction at the K-Pg Boundary?

    PubMed

    Gunter, Nicole L; Weir, Tom A; Slipinksi, Adam; Bocak, Ladislav; Cameron, Stephen L

    2016-01-01

    The evolutionary success of beetles and numerous other terrestrial insects is generally attributed to co-radiation with flowering plants but most studies have focused on herbivorous or pollinating insects. Non-herbivores represent a significant proportion of beetle diversity yet potential factors that influence their diversification have been largely unexamined. In the present study, we examine the factors driving diversification within the Scarabaeidae, a speciose beetle family with a range of both herbivorous and non-herbivorous ecologies. In particular, it has been long debated whether the key event in the evolution of dung beetles (Scarabaeidae: Scarabaeinae) was an adaptation to feeding on dinosaur or mammalian dung. Here we present molecular evidence to show that the origin of dung beetles occurred in the middle of the Cretaceous, likely in association with dinosaur dung, but more surprisingly the timing is consistent with the rise of the angiosperms. We hypothesize that the switch in dinosaur diet to incorporate more nutritious and less fibrous angiosperm foliage provided a palatable dung source that ultimately created a new niche for diversification. Given the well-accepted mass extinction of non-avian dinosaurs at the Cretaceous-Paleogene boundary, we examine a potential co-extinction of dung beetles due to the loss of an important evolutionary resource, i.e., dinosaur dung. The biogeography of dung beetles is also examined to explore the previously proposed "out of Africa" hypothesis. Given the inferred age of Scarabaeinae as originating in the Lower Cretaceous, the major radiation of dung feeders prior to the Cenomanian, and the early divergence of both African and Gondwanan lineages, we hypothesise that that faunal exchange between Africa and Gondwanaland occurred during the earliest evolution of the Scarabaeinae. Therefore we propose that both Gondwanan vicariance and dispersal of African lineages is responsible for present day distribution of

  15. Boundary Stability of a Nematic Liquid Bridge

    NASA Astrophysics Data System (ADS)

    Barnes, William; Santangelo, Chris

    2014-03-01

    We consider a nematic liquid crystal droplet in air confined between two parallel plates with homeotropic boundary conditions. The boundary conditions at the nematic-plate and nematic-air interfaces induce either a hedgehog or planar ring disclination within the nematic bridge, depending on the plate separation and bridge radius. We study the stability of the liquid crystal-air boundary of a nearly cylindrical nematic bridge by minimizing the Frank elastic energy.

  16. Boundary Layer Control on Airfoils.

    ERIC Educational Resources Information Center

    Gerhab, George; Eastlake, Charles

    1991-01-01

    A phenomena, boundary layer control (BLC), produced when visualizing the fluidlike flow of air is described. The use of BLC in modifying aerodynamic characteristics of airfoils, race cars, and boats is discussed. (KR)

  17. Size-Segregated Aerosol Composition and Mass Loading of Atmospheric Particles as Part of the Pacific Northwest 2001(PNW2001) Air Quality Study In Puget Sound

    NASA Astrophysics Data System (ADS)

    Disselkamp, R. S.; Barrie, L. A.; Shutthanadan, S.; Cliff, S.; Cahill, T.

    2001-12-01

    In mid-August, 2001, an aircraft-based air-quality study was performed in the Puget Sound, WA, area entitled PNW2001 (http://www.pnl.gov/pnw2001). The objectives of this field campaign were the following: 1. reveal information about the 3-dimensional distribution of ozone, its gaseous precursors and fine particulate matter during weather conditions favoring air pollution; 2. derive information about the accuracy of urban and biogenic emissions inventories that are used to drive the air quality forecast models; and 3. examine the accuracy of modeled ozone concentration with that observed. In support of these efforts, we collected time-averaged ( { ~}10 minute averages), size-segregated, aerosol composition and mass-loading information using ex post facto analysis techniques of synchrotron x-ray fluorescence (s-XRF), proton induced x-ray emissions(PIXE), proton elastic scattering (PESA), and scanning transmission ion microscopy (STIM). This is the first time these analysis techniques have been used together on samples collected from aircraft using an optimized 3-stage rotating drum impactor. In our presentation, we will discuss the aerosol components in three aerosol size fractions as identified by statistical analysis of multielemental data (including total mass, H, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Pb) and relate variations in these components to physical aerosol properties, other gaseous trace constituents and to air mass origin.

  18. Development and characterisation of a state-of-the-art GOME-2 formaldehyde air-mass factor algorithm

    NASA Astrophysics Data System (ADS)

    Hewson, W.; Barkley, M. P.; Gonzalez Abad, G.; Bösch, H.; Kurosu, T.; Spurr, R.; Tilstra, L. G.

    2015-10-01

    Space-borne observations of formaldehyde (HCHO) are frequently used to derive surface emissions of isoprene, an important biogenic volatile organic compound. The conversion of retrieved HCHO slant column concentrations from satellite line-of-sight measurements to vertical columns is determined through application of an air mass factor (AMF), accounting for instrument viewing geometry, radiative transfer, and vertical profile of the absorber in the atmosphere. This step in the trace gas retrieval is subject to large errors. This work presents the AMF algorithm in use at the University of Leicester (UoL), which introduces scene-specific variables into a per-observation full radiative transfer AMF calculation, including increasing spatial resolution of key environmental parameter databases, input variable area weighting, instrument-specific scattering weight calculation, and inclusion of an ozone vertical profile climatology. Application of these updates to HCHO slant columns from the GOME-2 instrument is shown to typically adjust the AMF by ±20 %, compared to a reference algorithm without these advanced parameterisations. On average the GOME-2 AMFs increase by 4 %, with over 70 % of locations having an AMF of 0-20 % larger than originally, largely resulting from the use of the latest GOME-2 reflectance product. Furthermore, the new UoL algorithm also incorporates a full radiative transfer error calculation for each scene to help characterise AMF uncertainties. Global median AMF errors are typically 50-60 %, and are driven by uncertainties in the HCHO profile shape and its vertical distribution relative to clouds and aerosols. If uncertainty on the a priori HCHO profile is relatively small (< 10 %) then the median AMF total error decreases to about 30-40 %.

  19. Air Mass Factor Formulation for Spectroscopic Measurements from Satellites: Application to Formaldehyde Retrievals from the Global Ozone Monitoring Experiment

    NASA Technical Reports Server (NTRS)

    Palmer, Paul I.; Jacob, Daniel J.; Chance, Kelly; Martin, Randall V.; Spurr, Robert J. D.; Kurosu, Thomas P.; Bey, Isabelle; Yantosca, Robert; Fiore, Arlene; Li, Qinbin

    2004-01-01

    We present a new formulation for the air mass factor (AMF) to convert slant column measurements of optically thin atmospheric species from space into total vertical columns. Because of atmospheric scattering, the AMF depends on the vertical distribution of the species. We formulate the AMF as the integral of the relative vertical distribution (shape factor) of the species over the depth of the atmosphere, weighted by altitude-dependent coefficients (scattering weights) computed independently from a radiative transfer model. The scattering weights are readily tabulated, and one can then obtain the AMF for any observation scene by using shape factors from a three dimensional (3-D) atmospheric chemistry model for the period of observation. This approach subsequently allows objective evaluation of the 3-D model with the observed vertical columns, since the shape factor and the vertical column in the model represent two independent pieces of information. We demonstrate the AMF method by using slant column measurements of formaldehyde at 346 nm from the Global Ozone Monitoring Experiment satellite instrument over North America during July 1996. Shape factors are cumputed with the Global Earth Observing System CHEMistry (GEOS-CHEM) global 3-D model and are checked for consistency with the few available aircraft measurements. Scattering weights increase by an order of magnitude from the surface to the upper troposphere. The AMFs are typically 20-40% less over continents than over the oceans and are approximately half the values calculated in the absence of scattering. Model-induced errors in the AMF are estimated to be approximately 10%. The GEOS-CHEM model captures 50% and 60% of the variances in the observed slant and vertical columns, respectively. Comparison of the simulated and observed vertical columns allows assessment of model bias.

  20. Measurement and analysis of aerosol and black carbon in the southwestern United States and Panama and their dependence on air mass origin

    NASA Astrophysics Data System (ADS)

    Junker, C.; Sheahan, J. N.; Jennings, S. G.; O'Brien, P.; Hinds, B. D.; Martinez-Twary, E.; Hansen, A. D. A.; White, C.; Garvey, D. M.; Pinnick, R. G.

    2004-07-01

    Total aerosol mass loading, aerosol absorption, and black carbon (BC) content were determined from aerosol collected on 598 quartz fiber filters at a remote, semiarid site near Orogrande, New Mexico from December 1989 to October 1995. Aerosol mass was determined by weighing filters before and after exposure, and aerosol absorption was determined by measuring the visible light transmitted through loaded filter samples and converting these measurements to aerosol absorption. BC content was determined by measuring visible light transmitted through filter samples before and after firing and converting the absorption to BC mass, assuming a BC absorption cross section of 19 m2/g in the fiber filter medium. Two analyses were then performed on each of the logged variables: an autoregressive integrating moving average (ARIMA) analysis and a decomposition analysis using an autoregressive model to accommodate first-order autocorrelation. The two analyses reveal that BC mass has no statistically significant seasonal dependence at the 5% level of significance but only random fluctuations varying around an average annual value that has a long-term decreasing trend (from 0.16 to 0.11 μg/m3 during 1990-1995). Aerosol absorption, which is dominated by BC, also displays random fluctuations about an average value, and decreases from 1.9 Mm-1 to 1.3 Mm-1 during the same period. Unlike BC, aerosol mass at the Orogrande site displays distinctly different character. The analyses reveal a pronounced seasonal dependence, but no long-term trend for aerosol mass. The seasonal indices resulting from the autoregression analysis have a minimum in January (-0.78) and maximum in June (+0.58). The geometric mean value over the 1990-1995 period for aerosol mass is 16.0 μg/m3. Since BC aerosol at the Orogrande site is a product of long-range atmospheric transport, a back trajectory analysis of air masses was conducted. Back trajectory analyses indicate that air masses traversing high population

  1. Characteristics of particle number and mass emissions during heavy-duty diesel truck parked active DPF regeneration in an ambient air dilution tunnel

    NASA Astrophysics Data System (ADS)

    Yoon, Seungju; Quiros, David C.; Dwyer, Harry A.; Collins, John F.; Burnitzki, Mark; Chernich, Donald; Herner, Jorn D.

    2015-12-01

    Diesel particle number and mass emissions were measured during parked active regeneration of diesel particulate filters (DPF) in two heavy-duty diesel trucks: one equipped with a DPF and one equipped with a DPF + SCR (selective catalytic reduction), and compliant with the 2007 and 2010 emission standards, respectively. The emission measurements were conducted using an ambient air dilution tunnel. During parked active regeneration, particulate matter (PM) mass emissions measured from a 2007 technology truck were significantly higher than the emissions from a 2010 technology truck. Particle number emissions from both trucks were dominated by nucleation mode particles having a diameter less than 50 nm; nucleation mode particles were orders of magnitude higher than accumulation mode particles having a diameter greater than 50 nm. Accumulation mode particles contributed 77.8 %-95.8 % of the 2007 truck PM mass, but only 7.3 %-28.2 % of the 2010 truck PM mass.

  2. sup 222 Rn, sup 222 Rn progeny and sup 220 Rn progeny as atmospheric tracers of air masses at the Mauno Loa Observatory

    SciTech Connect

    Hutter, A.R.; George, A.C.; Maiello, M.L.; Fisenne, I.M.; Larsen, R.J.; Beck, H.L.; Wilson, F.C.

    1990-03-01

    {sup 222}Rn, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations in air were measured at the Mauna Loa Observatory (MLO) in Hawaii during March 1989 in order to investigate the feasibility of using them as atmospheric tracers to help determine local air mass flow patterns. Charcoal traps, cooled to dry ice temperatures, were used to collect {sup 222}Rn, which was subsequently measured in pulse ionization chambers at the Environmental Measurements Laboratory (EML). {sup 222}Rn progeny and {sup 220}Rn progeny for 37 samples were measured at the Observatory by sampling high volumes of air through filters, which were counted for up to 11 h in alpha scintillation counters. Individual progeny concentrations were calculated using both least squares and maximum likelihood techniques. In general, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations were low when free tropospheric air was present (downslope and tradewind conditions), and consistently higher when surface air from the island broke through the trade wind inversion layer (upslope conditions). The data suggest that {sup 222}Rn, {sup 222}Rn progeny, or {sup 220}Rn progeny monitoring may provide new and useful information to help indicate the different air flow patterns present at MLO. 17 refs., 5 figs., 2 tabs.

  3. Boundary Layer Control for Hypersonic Airbreathing Vehicles

    NASA Technical Reports Server (NTRS)

    Berry, Scott A.; Nowak, Robert J.; Horvath, Thomas J.

    2004-01-01

    Active and passive methods for tripping hypersonic boundary layers have been examined in NASA Langley Research Center wind tunnels using a Hyper-X model. This investigation assessed several concepts for forcing transition, including passive discrete roughness elements and active mass addition (or blowing), in the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air Tunnels. Heat transfer distributions obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the Hyper-X nominal Mach 7 flight test-point of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For passive roughness, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The passive roughness study resulted in a swept ramp configuration, scaled to be roughly 0.6 of the calculated boundary layer thickness, being selected for the Mach 7 flight vehicle. For the active blowing study, the manifold pressure was systematically varied (while monitoring the mass flow) for each configuration to determine the jet penetration height, with schlieren, and transition movement, with the phosphor system, for comparison to the passive results. All the blowing concepts tested, which included various rows of sonic orifices (holes), two- and three-dimensional slots, and random porosity, provided transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model surface static pressure, which is adequate to ensure sonic jets. The present results indicate that the jet penetration height for blowing was roughly half the height required with passive roughness elements for an equivalent amount of transition movement.

  4. Ground boundaries

    SciTech Connect

    Balluffi, R.W.; Bristowe, P.D.

    1990-01-01

    The present document is a progress report describing the work accomplished on the study of grain boundaries in Ag, Au, Ni, Si, and Ge. Research was focused on the following four major efforts: study of the atomic structure of grain boundaries by means of x-ray diffraction, transmission electron microscopy and computer modeling; grain boundary migration; short-circuit diffusion along grain boundaries; and development of Thin-Film Deposition/Bonding Apparatus for the manufacture of high purity bicrystals. 10 refs., 1 fig.

  5. Temperature Independent Differential Absorption Spectroscopy (tidas) and Simplified Atmospheric Air Mass Factor (samf) Techniques For The Measurement of Ozone Vertical Content From Gome Data

    NASA Astrophysics Data System (ADS)

    Zehner, C.; Casadio, S.; di Sarra, A.; Putz, E.

    A simple technique for the fast retrieval of ozone vertical amount from GOME (Global Ozone Monitoring Experiment) spectra is described in detail. The TIDAS (Tempera- ture Independent Differential Absorption Spectroscopy) technique uses GOME's ca- pability of measuring atmospheric spectra over a broad wavelength range with high spectral resolution. The ozone slant columns are retrieved by applying the Beer- Lambert law to two spectral windows where the ozone absorption cross sections show similar temperature dependence. A simple geometric air mass factor is computed for a fixed height spherical atmosphere (SAMF: Simplified Atmospheric air Mass Factor) to retrieve ozone vertical amounts. Vertical ozone values are compared to the GDP (GOME Data Processor), and to ground based ozone measurements.

  6. Long-term measurements of particle number size distributions and the relationships with air mass history and source apportionment in the summer of Beijing

    NASA Astrophysics Data System (ADS)

    Wang, Z. B.; Hu, M.; Wu, Z. J.; Yue, D. L.; He, L. Y.; Huang, X. F.; Liu, X. G.; Wiedensohler, A.

    2013-10-01

    A series of long-term and temporary measurements were conducted to study the improvement of air quality in Beijing during the Olympic Games period (8-24 August 2008). To evaluate actions taken to improve the air quality, comparisons of particle number and volume size distributions of August 2008 and 2004-2007 were performed. The total particle number and volume concentrations were 14 000 cm-3 and 37 μm-3 cm-3 in August of 2008, respectively. These were reductions of 41% and 35% compared with mean values of August 2004-2007. A cluster analysis on air mass history and source apportionment were performed, exploring reasons for the reduction of particle concentrations. Back trajectories were classified into five major clusters. Air masses from the south direction are always associated with pollution events during the summertime in Beijing. In August 2008, the frequency of air mass arriving from the south was 1.3 times higher compared to the average of the previous years, which however did not result in elevated particle volume concentrations in Beijing. Therefore, the reduced particle number and volume concentrations during the 2008 Beijing Olympic Games cannot be only explained by meteorological conditions. Four factors were found influencing particle concentrations using a positive matrix factorization (PMF) model. They were identified as local and remote traffic emissions, combustion sources as well as secondary transformation. The reductions of the four sources were calculated to 47%, 44%, 43% and 30%, respectively. The significant reductions of particle number and volume concentrations may attribute to actions taken, focusing on primary emissions, especially related to the traffic and combustion sources.

  7. The relationship between seasonal variations of total-nitrogen and total-phosphorus in rainfall and air mass advection paths in Matsue, Japan

    NASA Astrophysics Data System (ADS)

    Yoshioka, Katsuhiro; Kamiya, Hiroshi; Kano, Yoshihiro; Saki, Yukiko; Yamamuro, Masumi; Ishitobi, Yu

    We collected rainwater samples from every rainfall in Matsue, Japan in order to study variations of nitrogen and phosphorus concentrations over time. The seasonal average concentration by magnitude order of Total Nitrogen (here after T-N) was highest in winter, then in spring, fall, and summer and that of Total Phosphorus (here after T-P) was highest in spring, then in winter, fall, and summer. These seasonal variations were examined in relation to the transportation paths of arrived air masses by using a backward trajectory and rainfall patterns from a surface synoptic weather chart. In winter, continental air masses frequently flow from China or Siberia and the resultant winter rainfall is on many occasions of a continental type. In summer, maritime air masses frequently arrive from the Pacific Ocean and this resultant rainfall therefore was often of maritime type. Looking at average concentrations of T-N and T-P for each rainfall type, continental types were high range and maritime types were low. It was therefore concluded that the monthly average concentration of T-N was affected by continental air masses from northern China in winter and by maritime ones from the Pacific Ocean in summer. The maximum deposition of T-N was caused by this concentration in winter and rainfall depth in summer. Seasonal variation of T-P showed a different fluctuation tendency from T-N, with a maximum concentration in spring, and minimum in summer and fall. T-P was susceptible to the yellow sand phenomenon which maximised T-P deposition in spring.

  8. Development of a particle-trap preconcentration-soft ionization mass spectrometric technique for the quantification of mercury halides in air.

    PubMed

    Deeds, Daniel A; Ghoshdastidar, Avik; Raofie, Farhad; Guérette, Élise-Andrée; Tessier, Alain; Ariya, Parisa A

    2015-01-01

    Measurement of oxidized mercury, Hg(II), in the atmosphere poses a significant analytical challenge as Hg(II) is present at ultra-trace concentrations (picograms per cubic meter air). Current technologies are sufficiently sensitive to measure the total Hg present as Hg(II) but cannot determine the chemical speciation of Hg(II). We detail here the development of a soft ionization mass spectrometric technique coupled with preconcentration onto nano- or microparticle-based traps prior to analysis for the measurement of mercury halides in air. The current methodology has comparable detection limits (4-11 pg m(-3)) to previously developed techniques for the measurement of total inorganic mercury in air while allowing for the identification of HgX2 in collected samples. Both mercury chloride and mercury bromide have been sporadically detected in Montreal urban and indoor air using atmospheric pressure chemical ionization-mass spectrometry (APCI-MS). We discuss limitations and advantages of the current technique and discuss potential avenues for future research including quantitative trace measurements of a larger range of mercury compounds. PMID:25837315

  9. Who should take responsibility for decisions on internationally recommended datasets? The case of the mass concentration of mercury in air at saturation

    NASA Astrophysics Data System (ADS)

    Brown, Richard J. C.; Brewer, Paul J.; Ent, Hugo; Fisicaro, Paola; Horvat, Milena; Kim, Ki-Hyun; Quétel, Christophe R.

    2015-10-01

    This paper considers how decisions on internationally recommended datasets are made and implemented and, further, how the ownership of these decisions comes about. Examples are given of conventionally agreed data and values where the responsibility is clear and comes about through official designation or by common usage and practice over long time periods. The example of the dataset describing the mass concentration of mercury in air at saturation is discussed in detail. This is a case where there are now several competing datasets that are in disagreement with each other, some with historical authority and some more recent but, arguably, with more robust metrological traceability to the SI. Further, it is elaborated that there is no body charged with the responsibility to make a decision on an international recommendation for such a dataset. This has led to the situation where several competing datasets are in use simultaneously. Close parallels are drawn with the current debate over changes to the ozone absorption cross section, which has equal importance to the measurement of ozone amount fraction in air and to subsequent compliance with air quality legislation. It is noted that in the case of the ozone cross section there is already a committee appointed to deliberate over any change. We make the proposal that a similar committee, under the auspices of IUPAC or the CIPM’s CCQM (if it adopted a reference data function) could be formed to perform a similar role for the mass concentration of mercury in air at saturation.

  10. PM2.5 chemical composition at a rural background site in Central Europe, including correlation and air mass back trajectory analysis

    NASA Astrophysics Data System (ADS)

    Schwarz, Jaroslav; Cusack, Michael; Karban, Jindřich; Chalupníčková, Eva; Havránek, Vladimír; Smolík, Jiří; Ždímal, Vladimír

    2016-07-01

    of fresh, local aerosol and aged, long-range transport aerosol. The influences of different air masses were also investigated. The lowest concentrations of PM2.5 were recorded under the influence of marine air masses from the NW, which were also marked by increased concentrations of marine aerosol. In contrast, the highest concentrations of PM2.5 and most major chemical components were measured during periods when continental easterly air masses were dominant.

  11. Intercomparison of OMI NO2 and HCHO air mass factor calculations: recommendations and best practices for retrievals

    NASA Astrophysics Data System (ADS)

    Lorente Delgado, Alba; Klaas Boersma, Folkert; Hilboll, Andreas; Richter, Andreas; Yu, Huan; van Roozendael, Michel; Dörner, Steffen; Wagner, Thomas; Barkley, Michael; Lamsal, Lok; Lin, Jintai; Liu, Mengyao

    2016-04-01

    We present a detailed comparison of the air mass factor (AMF) calculation process used by various research groups for OMI satellite retrievals of NO2 and HCHO. Although satellite retrievals have strongly improved over the last decades, there is still a need to better understand and reduce the uncertainties associated with every retrieval step of satellite data products, such as the AMF calculation. Here we compare and evaluate the different approaches used to calculate AMFs by several scientific groups (KNMI (WUR), IASB-BIRA, IUP-UNI. BREMEN, MPI-C, NASA GSFC, LEICESTER UNI. and PEKING UNI.). Each group calculated altitude dependent (box-) AMFs and clear sky and total tropospheric AMFs for several OMI orbits. First, European groups computed AMFs for one OMI orbit using common settings for the choice of surface albedo data, terrain height, cloud treatment and a priori vertical profile. Second, every group computed AMFs for two complete days in different seasons using preferred settings for the ancillary data and cloud treatment as a part of a Round Robin exercise. Box-AMFs comparison showed good consistency and underlined the importance of a correct treatment of the physical processes affecting the effective light path and the vertical discretization of the atmosphere. Using common settings, tropospheric NO2 AMFs in polluted pixels on average agreed within 4.7% whereas in remote pixels agreed within 3.5%. Using preferred settings relative differences between AMFs increase up to 15-30%. This increase is traced back to the different choices and assumptions made throughout the AMF calculation, which affect the final AMF values and thus the uncertainty in the AMF calculation. Differences between state of the art cloud treatment approaches highlight the importance of an accurate cloud correction: total and clear sky AMFs in polluted conditions differ by up to 40% depending on the retrieval scenario. Based on the comparison results, specific recommendations on best

  12. Boundary-integral simulations of containerless solidification

    NASA Astrophysics Data System (ADS)

    Ajaev, Vladimir S.; Davis, Stephen H.

    2003-05-01

    We carry out boundary-integral simulations of a two-dimensional liquid droplet surrounded by air and solidified from a cool point on the boundary. There are three interfaces in the problem: solid-liquid, air-liquid, and air-solid. All three evolve in time in such a way that certain tri-junction conditions must be satisfied. Our numerical method describes the quasi-steady evolution of the interfaces in the limit of zero surface energy on the solidification front. A new iterative technique is developed to describe the interface evolution when mass and total energy are conserved and the local tri-junction conditions are satisfied at every instant in time. A method is also developed for efficient numerical integration over the interfaces by taking advantage of analytical formulas for Green's functions. We start the simulations by studying the case of equal densities of the solid and liquid. This allows us to verify the numerical method and obtain some estimates of the speed of the solidification front. Solid-liquid interface flattening is observed at the intermediate stages of solidification. When the densities of the two phases are different, elongated solidified particles are observed when the solid density is smaller than the liquid density. At the final stages of solidification, a corner is formed in agreement with observations in related experiments.

  13. Effects of Thermal Mass, Window Size, and Night-Time Ventilation on Peak Indoor Air Temperature in the Warm-Humid Climate of Ghana

    PubMed Central

    Amos-Abanyie, S.; Akuffo, F. O.; Kutin-Sanwu, V.

    2013-01-01

    Most office buildings in the warm-humid sub-Saharan countries experience high cooling load because of the predominant use of sandcrete blocks which are of low thermal mass in construction and extensive use of glazing. Relatively, low night-time temperatures are not harnessed in cooling buildings because office openings remain closed after work hours. An optimization was performed through a sensitivity analysis-based simulation, using the Energy Plus (E+) simulation software to assess the effects of thermal mass, window size, and night ventilation on peak indoor air temperature (PIAT). An experimental system was designed based on the features of the most promising simulation model, constructed and monitored, and the experimental data used to validate the simulation model. The results show that an optimization of thermal mass and window size coupled with activation of night-time ventilation provides a synergistic effect to obtain reduced peak indoor air temperature. An expression that predicts, indoor maximum temperature has been derived for models of various thermal masses. PMID:23878528

  14. The effect of long-range air mass transport pathways on PM10 and NO2 concentrations at urban and rural background sites in Ireland: Quantification using clustering techniques.

    PubMed

    Donnelly, Aoife A; Broderick, Brian M; Misstear, Bruce D

    2015-01-01

    The specific aims of this paper are to: (i) quantify the effects of various long range transport pathways nitrogen dioxide (NO2) and particulate matter with diameter less than 10μm (PM10) concentrations in Ireland and identify air mass movement corridors which may lead to incidences poor air quality for application in forecasting; (ii) compare the effects of such pathways at various sites; (iii) assess pathways associated with a period of decreased air quality in Ireland. The origin of and the regions traversed by an air mass 96h prior to reaching a receptor is modelled and k-means clustering is applied to create air-mass groups. Significant differences in air pollution levels were found between air mass cluster types at urban and rural sites. It was found that easterly or recirculated air masses lead to higher NO2 and PM10 levels with average NO2 levels varying between 124% and 239% of the seasonal mean and average PM10 levels varying between 103% and 199% of the seasonal mean at urban and rural sites. Easterly air masses are more frequent during winter months leading to higher overall concentrations. The span in relative concentrations between air mass clusters is highest at the rural site indicating that regional factors are controlling concentration levels. The methods used in this paper could be applied to assist in modelling and forecasting air quality based on long range transport pathways and forecast meteorology without the requirement for detailed emissions data over a large regional domain or the use of computationally demanding modelling techniques. PMID:25901845

  15. A Comparison between 2010 and 2006 Air Quality and Meteorological Conditions, andEmissions and Boundary Conditions used in Simulations of the AQMEII-2 North American Domain

    EPA Science Inventory

    Several participants in Phase 2 of the Air Quality Model Evaluation International Initiative (AQMEII-2) who are applying coupled models to the North American domain are comparing model results for two years: 2006 and 2010. While a key difference of interest between these two yea...

  16. Operational Use of the AIRS Total Column Ozone Retrievals Along with the RGB Air Mass Product as Part of the GOES-R Proving Ground

    NASA Technical Reports Server (NTRS)

    Folmer, Michael; Zavodsky, Bradley; Molthan, Andrew

    2012-01-01

    The National Oceanic and Atmospheric Administration (NOAA) National Centers for Environmental Prediction (NCEP) Hydrometeorological Prediction Center (HPC) and Ocean Prediction Center (OPC) provide short-term and medium-range forecast guidance of heavy precipitation, strong winds, and other features often associated with mid-latitude cyclones over both land and ocean. As a result, detection of factors that lead to rapid cyclogenesis and high wind events is key to improving forecast skill. One phenomenon that has been identified with these events is the stratospheric intrusion that occurs near tropopause folds. This allows for deep mixing near the top of the atmosphere where dry air high in ozone concentrations and potential vorticity descends (sometimes rapidly) deep into the mid-troposphere. Observations from satellites can aid in detection of these stratospheric air intrusions (SAI) regions. Specifically, multispectral composite imagery assign a variety of satellite spectral bands to the red, green, and blue (RGB) color components of imagery pixels and result in color combinations that can assist in the detection of dry stratospheric air associated with PV advection, which in turn may alert forecasters to the possibility of a rapidly strengthening storm system. Single channel or RGB satellite imagery lacks quantitative information about atmospheric moisture unless the sampled brightness temperatures or other data are converted to estimates of moisture via a retrieval process. Thus, complementary satellite observations are needed to capture a complete picture of a developing storm system. Here, total column ozone retrievals derived from a hyperspectral sounder are used to confirm the extent and magnitude of SAIs. Total ozone is a good proxy for defining locations and intensity of SAIs and has been used in studies evaluating that phenomenon (e.g. Tian et al. 2007, Knox and Schmidt 2005). Steep gradients in values of total ozone seen by satellites have been linked

  17. Characterization of particle cloud droplet activity and composition in the free troposphere and the boundary layer during INTEX-B

    SciTech Connect

    Roberts, G. C.; Day, D. A.; Russell, Lynn M.; Dunlea, E. J.; Jimenez, J. L.; Tomlinson, Jason M.; Collins, Donald R.; Shinozuka, Y.; Clarke, A. D.

    2010-07-20

    Measurements of cloud condensation nuclei (CCN), aerosol size distributions, and submicron aerosol composition were made as part of the Intercontinental Chemical Transport Experiment Phase B (INTEX-B) campaign during spring 2006. Measurements were conducted from an aircraft platform over the northeastern Pacific and western North America with a focus on how the transport and evolution of Asian pollution across the Pacific Ocean affected CCN properties. A broad range of air masses were sampled and here we focus on three distinct air mass types defined geographically: the Pacific free troposphere (FT), the marine boundary layer (MBL), and the polluted continental boundary layer in the California Central Valley (CCV). These observations add to the few observations of CCN in the FT. CCN concentrations showed a large range of concentrations between air masses, however CCN activity was similar for the MBL and CCV ({kappa} {approx} 0.2-0.25). FT air masses showed evidence of long-range transport from Asia and CCN activity was consistently higher than for the boundary layer air masses. Bulk chemical measurements predicted CCN activity reasonably well for the CCV and FT air masses. Decreasing trends in {kappa} with organic mass fraction were observed for the combination of the FT and CCV air masses and can be explained by the measured soluble inorganic chemical components. Changes in hygroscopicity associated with differences in the non-refractory organic composition were too small to be distinguished from the simultaneous changes in inorganic ion composition in the FT and MBL, although measurements for the large organic fractions (0.6-0.8) found in the CCV showed values of the organic fraction hygroscopicity consistent with other polluted regions ({kappa}{sub org} {approx} 0.1-0.2). A comparison of CCN-derived {kappa} (for particles at the critical diameter) to H-TDMA-derived {kappa} (for particles at 100 nm diameter) showed similar trends, however the CCN-derived {kappa

  18. Grain boundaries

    SciTech Connect

    Balluffi, R.W.; Bristowe, P.D.

    1991-01-01

    The present document is a progress report describing the work accomplished to date during the second year of our four-year grant (February 15, 1990--February 14, 1994) to study grain boundaries. The research was focused on the following three major efforts: Study of the atomic structure of grain boundaries by means of x-ray diffraction, transmission electron microscopy and computer modeling; study of short-circuit diffusion along grain boundaries; and development of a Thin-film Deposition/Bonding Apparatus for the manufacture of high purity bicrystals.

  19. Soot and radiation in combusting boundary layers

    SciTech Connect

    Beier, R.A.

    1981-12-01

    In most fires thermal radiation is the dominant mode of heat transfer. Carbon particles within the fire are responsible for most of this emitted radiation and hence warrant quantification. As a first step toward understanding thermal radiation in full scale fires, an experimental and theoretical study is presented for a laminar combusting boundary layer. Carbon particulate volume fraction profiles and approximate particle size distributions are experimentally determined in both free and forced flow for several hydrocarbon fuels and PMMA (polymethylmethacrylate). A multiwavelength laser transmission technique determines a most probable radius and a total particle concentration which are two unknown parameters in an assumed Gauss size distribution. A sooting region is observed on the fuel rich side of the main reaction zone. For free flow, all the flames are in air, but the free stream ambient oxygen mass fraction is a variable in forced flow. To study the effects of radiation heat transfer, a model is developed for a laminar combusting boundary layer over a pyrolyzing fuel surface. An optically thin approximation simplifies the calculation of the radiant energy flux at the fuel surface. For the free flames in air, the liquid fuel soot volume fractions, f/sub v/, range from f/sub v/ approx. 10/sup -7/ for n-heptane, a paraffin, to f/sub v/ approx. 10/sup -7/ for toluene, an aromatic. The PMMA soot volume fractions, f/sub v/ approx. 5 x 10/sup -7/, are approximately the same as the values previously reported for pool fires. Soot volume fraction increases monotonically with ambient oxygen mass fraction in the forced flow flames. For all fuels tested, a most probable radius between 20 nm and 80 nm is obtained which varies only slightly with oxygen mass fraction, streamwise position, or distance normal to the fuel surface. The theoretical analysis yields nine dimensionless parameters, which control the mass flux rate at the pyrolyzing fuel surface.

  20. Observation of the transport of polluted air masses from the northeastern United States to Cape Sable Island, Nova Scotia, Canada, during the 1993 NARE summer intensive

    NASA Astrophysics Data System (ADS)

    Knapp, K. G.; Balsley, B. B.; Jensen, M. L.; Hanson, H. P.; Birks, J. W.

    1998-06-01

    Vertical profiles of ozone, temperature, pressure, and water vapor mass mixing ratio obtained using a parafoil kite platform during the North Atlantic Regional Experiment (NARE) 1993 summer intensive at Cape Sable Island, Nova Scotia, Canada, demonstrate the of use of kite platforms for the collection of vertically and temporally resolved data over a fixed location. During the period August 8-28, 1993, 39 profiles of the lower atmosphere were collected. Data collected as part of this field campaign illustrate the complex vertical stratification and temporal variability of pollutants transported into the Maritime Provinces of Canada. Transport phenomena resulted in pollution events in which ozone at the ground level remained in the 20-40 parts per billion by volume (ppbv) range, while mixing ratios of 90-130 ppbv were observed above ˜300 m. Back trajectories indicate that these highly elevated levels of ozone are attributable to source regions in the heavily industrialized northeastern United States. Vertical stratification of the lower atmosphere was also present during transport of Canadian air to the sampling site, with layers of both elevated and diminished ozone observed, while marine air did not exhibit layering characteristic of air masses originating from continental source regions.

  1. Development of a thermal desorption gas chromatography-mass spectrometry method for quantitative determination of haloanisoles and halophenols in wineries' ambient air.

    PubMed

    Camino-Sánchez, F J; Ruiz-García, J; Zafra-Gómez, A

    2013-08-30

    An analytical method for the detection and quantification of haloanisoles and their corresponding halophenols in wineries' ambient air was developed. The target analytes were haloanisoles and halophenols, reported by previous scientific literature as responsible for wine taint. A calibrated pump and active tubes filled with Tenax GR™ were used for sampling. These tubes were thermally desorbed and analyzed using gas chromatography-triple quadrupole mass spectrometry in the selected reaction monitoring mode. The adsorption efficiencies of five commercial sampling tubes filled with different materials were evaluated. The efficiencies of the selected adsorbent were close to 100% for all sampled compounds. Desorption, chromatographic and mass spectrometric conditions were accurately optimized allowing very low limits of quantification and wide linear ranges. The limits of quantification in ambient air ranged from 0.8pgtube(-1) for 2,4,6-trichlorophenol, to 28pgtube(-1) for pentachlorophenol. These results are of great importance because human sensory threshold for haloanisoles is very low. The chromatographic method was also validated and the instrumental precision and trueness were established, a maximum RSD of 9% and a mean recovery of 91-106% were obtained. The proposed method involves an easy and sensitive technique for the early detection of haloanisoles and their precursor halophenols in ambient air avoiding contamination of wine or winery facilities. PMID:23891369

  2. Grain boundary segregation of boron in Inconel 718

    SciTech Connect

    Chen, W.; Chaturvedi, M.C.; Richards, N.L.

    1998-07-01

    The segregation behavior of boron at grain boundaries in two INCONEL 718+ based alloys with different B concentrations was studied. The alloys, one containing 11 ppm of B and the other 43 ppm, were homogenized at 1,200 C for 2 hours followed by water quenching and air cooling. A strong segregation of boron at grain boundaries was observed using secondary ion mass spectrometry after the heat treatment in both the alloys. The segregation was found mainly to be of nonequilibrium type. The homogenized samples were also annealed at 1050 C for various lengths of time. During annealing, boride particles were observed to first form at grain boundaries and then to dissolve on continued annealing at 1050 C. The mechanisms of segregation and desegregation of B are discussed.

  3. Grain boundary segregation of boron in INCONEL 718

    NASA Astrophysics Data System (ADS)

    Chen, W.; Chaturvedi, M. C.; Richards, N. L.; McMahon, G.

    1998-07-01

    The segregation behavior of boron at grain boundaries in two INCONEL 718+ based alloys with different B concentrations was studied. The alloys, one containing 11 ppm of B and the other 43 ppm, were homogenized at 1200 °C for 2 hours followed by water quenching and air cooling. A strong segregation of boron at grain boundaries was observed using secondary ion mass spectrometry after the heat treatment in both the alloys. The segregation was found mainly to be of nonequilibrium type. The homogenized samples were also annealed at 1050 °C for various lengths of time. During annealing, boride particles were observed to first form at grain boundaries and then to dissolve on continued annealing at 1050 °C. The mechanisms of segregation and desegregation of B are discussed.

  4. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Jedlovec, G. J.; Molthan, A. L.

    2013-01-01

    Non-convective wind events commonly occur with passing extratropical cyclones and have significant societal and economic impacts. Since non-convective winds often occur in the absence of specific phenomena such as a thunderstorm, tornado, or hurricane, the public are less likely to heed high wind warnings and continue daily activities. Thus non-convective wind events result in as many fatalities as straight line thunderstorm winds. One physical explanation for non-convective winds includes tropopause folds. Improved model representation of stratospheric air and associated non-convective wind events could improve non-convective wind forecasts and associated warnings. In recent years, satellite data assimilation has improved skill in forecasting extratropical cyclones; however errors still remain in forecasting the position and strength of extratropical cyclones as well as the tropopause folding process. The goal of this study is to determine the impact of assimilating satellite temperature and moisture retrieved profiles from hyperspectral infrared (IR) sounders (i.e. Atmospheric Infrared Sounder (AIRS), Cross-track Infrared and Microwave Sounding Suite (CrIMSS), and Infrared Atmospheric Sounding Interferometer (IASI)) on the model representation of the tropopause fold and an associated high wind event that impacted the Northeast United States on 09 February 2013. Model simulations using the Advanced Research Weather Research and Forecasting Model (ARW) were conducted on a 12-km grid with cycled data assimilation mimicking the operational North American Model (NAM). The results from the satellite assimilation run are compared to a control experiment (without hyperspectral IR retrievals), Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis, and Rapid Refresh analyses.

  5. Desiccant Enhanced Evaporative Air Conditioning: Parametric Analysis and Design; Preprint

    SciTech Connect

    Woods, J.; Kozubal, E.

    2012-10-01

    This paper presents a parametric analysis using a numerical model of a new concept in desiccant and evaporative air conditioning. The concept consists of two stages: a liquid desiccant dehumidifier and a dew-point evaporative cooler. Each stage consists of stacked air channel pairs separated by a plastic sheet. In the first stage, a liquid desiccant film removes moisture from the process (supply-side) air through a membrane. An evaporatively-cooled exhaust airstream on the other side of the plastic sheet cools the desiccant. The second-stage indirect evaporative cooler sensibly cools the dried process air. We analyze the tradeoff between device size and energy efficiency. This tradeoff depends strongly on process air channel thicknesses, the ratio of first-stage to second-stage area, and the second-stage exhaust air flow rate. A sensitivity analysis reiterates the importance of the process air boundary layers and suggests a need for increasing airside heat and mass transfer enhancements.

  6. Superfluidity of grain boundaries and supersolid behavior.

    PubMed

    Sasaki, S; Ishiguro, R; Caupin, F; Maris, H J; Balibar, S

    2006-08-25

    When two communicating vessels are filled to a different height with liquid, the two levels equilibrate because the liquid can flow. We have looked for such equilibration with solid (4)He. For crystals with no grain boundaries, we see no flow of mass, whereas for crystals containing several grain boundaries, we detect a mass flow. Our results suggest that the transport of mass is due to the superfluidity of grain boundaries. PMID:16873608

  7. Toward a Unified Parameterization of the Boundary Layer and Moist Convection. Part 2; Lateral Mass Exchanges and Subplume-Scale Fluxes

    NASA Technical Reports Server (NTRS)

    Lappan, Cara-Lyn; Randall, David A.

    2001-01-01

    The dissipation parameterizations developed for higher-order closure are used to parameterize lateral entrainment and detrainment in a mass-flux model. In addition, a subplume-scale turbulence scheme is included to represent fluxes not captured in the conventional mass-flux framework. These new parameterizations are tested by simulating trade wind cumulus from the Barbados Oceanographic and Meteorological Experiment (BOMEX).

  8. Numerical investigation of interfacial mass transport resistance and two-phase flow in PEM fuel cell air channels

    NASA Astrophysics Data System (ADS)

    Koz, Mustafa

    Proton exchange membrane fuel cells (PEMFCs) are efficient and environmentally friendly electrochemical engines. The performance of a PEMFC is adversely affected by oxygen (O2) concentration loss from the air flow channel to the cathode catalyst layer (CL). Oxygen transport resistance at the gas diffusion layer (GDL) and air channel interface is a non-negligible component of the O2 concentration loss. Simplified PEMFC performance models in the available literature incorporate the O2 resistance at the GDL-channel interface as an input parameter. However, this parameter has been taken as a constant so far in the available literature and does not reflect variable PEMFC operating conditions and the effect of two-phase flow in the channels. This study numerically calculates the O2 transport resistance at the GDL-air channel interface and expresses this resistance through the non-dimensional Sherwood number (Sh). Local Sh is investigated in an air channel with multiple droplets and films inside. These water features are represented as solid obstructions and only air flow is simulated. Local variations of Sh in the flow direction are obtained as a function of superficial air velocity, water feature size, and uniform spacing between water features. These variations are expressed with mathematical expressions for the PEMFC performance models to utilize and save computational resources. The resulting mathematical correlations for Sh can be utilized in PEMFC performance models. These models can predict cell performance more accurately with the help of the results of this work. Moreover, PEMFC performance models do not need to use a look-up table since the results were expressed through correlations. Performance models can be kept simplified although their predictions will become more realistic. Since two-phase flow in channels is experienced mostly at lower temperatures, performance optimization at low temperatures can be done easier.

  9. Improved detection of low vapor pressure compounds in air by serial combination of single-sided membrane introduction with fiber introduction mass spectrometry (SS-MIMS-FIMS).

    PubMed

    Cotte-Rodríguez, Ismael; Handberg, Eric; Noll, Robert J; Kilgour, David P A; Cooks, R Graham

    2005-05-01

    The use of two methods in tandem, single-sided membrane introduction mass spectrometry (SS-MIMS) and fiber introduction mass spectrometry (FIMS), is presented as a technique for field analysis. The combined SS-MIMS-FIMS technique was employed in both a modified commercial mass spectrometer and a miniature mass spectrometer for the selective preconcentration of the explosive simulant o-nitrotoluene (ONT) and the chemical warfare agent simulant, methyl salicylate (MeS), in air. A home-built FIMS inlet was fabricated to allow introduction of the solid-phase microextraction (SPME) fiber into the mass spectrometer chamber and subsequent desorption of the trapped compounds using resistive heating. The SS-MIMS preconcentration system was also home-built from commercial vacuum parts. Optimization experiments were done separately for each preconcentration system to achieve the best extraction conditions prior to use of the two techniques in combination. Improved limits of detection, in the low ppb range, were observed for the combination compared to FIMS alone, using several SS-MIMS preconcentration cycles. The SS-MIMS-FIMS response for both instruments was found to be linear over the range 50 to 800 ppb. Other parameters studied were absorption time profiles, effects of sample flow rate, desorption temperature, fiber background, memory effects, and membrane fatigue. This simple, sensitive, accurate, robust, selective, and rapid sample preconcentration and introduction technique shows promise for field analysis of low vapor pressure compounds, where analyte concentrations will be extremely low and the compounds are difficult to extract from a matrix like air. PMID:15852137

  10. Sensitive and comprehensive detection of chemical warfare agents in air by atmospheric pressure chemical ionization ion trap tandem mass spectrometry with counterflow introduction.

    PubMed

    Seto, Yasuo; Sekiguchi, Hiroshi; Maruko, Hisashi; Yamashiro, Shigeharu; Sano, Yasuhiro; Takayama, Yasuo; Sekioka, Ryoji; Yamaguchi, Shintaro; Kishi, Shintaro; Satoh, Takafumi; Sekiguchi, Hiroyuki; Iura, Kazumitsu; Nagashima, Hisayuki; Nagoya, Tomoki; Tsuge, Kouichiro; Ohsawa, Isaac; Okumura, Akihiko; Takada, Yasuaki; Ezawa, Naoya; Watanabe, Susumu; Hashimoto, Hiroaki

    2014-05-01

    A highly sensitive and specific real-time field-deployable detection technology, based on counterflow air introduction atmospheric pressure chemical ionization, has been developed for a wide range of chemical warfare agents (CWAs) comprising gaseous (two blood agents, three choking agents), volatile (six nerve gases and one precursor agent, five blister agents), and nonvolatile (three lachrymators, three vomiting agents) agents in air. The approach can afford effective chemical ionization, in both positive and negative ion modes, for ion trap multiple-stage mass spectrometry (MS(n)). The volatile and nonvolatile CWAs tested provided characteristic ions, which were fragmented into MS(3) product ions in positive and negative ion modes. Portions of the fragment ions were assigned by laboratory hybrid mass spectrometry (MS) composed of linear ion trap and high-resolution mass spectrometers. Gaseous agents were detected by MS or MS(2) in negative ion mode. The limits of detection for a 1 s measurement were typically at or below the microgram per cubic meter level except for chloropicrin (submilligram per cubic meter). Matrix effects by gasoline vapor resulted in minimal false-positive signals for all the CWAs and some signal suppression in the case of mustard gas. The moisture level did influence the measurement of the CWAs. PMID:24678766

  11. Seasonal, anthropogenic, air mass, and meteorological influences on the atmospheric concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs): Evidence for the importance of diffuse combustion sources