Science.gov

Sample records for air mass types

  1. An objective definition of air mass types affecting Athens, Greece; the corresponding atmospheric pressure patterns and air pollution levels.

    PubMed

    Sindosi, O A; Katsoulis, B D; Bartzokas, A

    2003-08-01

    This work aims at defining characteristic air mass types that dominate in the region of Athens, Greece during the cold (November-March) and the warm (May-September) period of the year and also at evaluating the corresponding concentration levels of the main air pollutants. For each air mass type, the mean atmospheric pressure distribution (composite maps) over Europe and the Mediterranean is estimated in order to reveal the association of atmospheric circulation with air pollution levels in Athens. The data basis for this work consists of daily values of thirteen meteorological and six pollutant parameters covering the period 1993-97. The definition of the characteristic air mass types is attempted objectively by using the methods of Factor Analysis and Cluster Analysis. The results show that during the cold period of the year there are six prevailing air mass types (at least 3% of the total number of days) and six infrequent ones. The examination of the corresponding air pollution concentration levels shows that the primary air pollutants appear with increased concentrations when light or southerly winds prevail. This is usually the case when a high pressure system is located over the central Mediterranean or a low pressure system lays over south Italy, respectively. Low levels of the primary pollutants are recorded under northeasterly winds, mainly caused by a high pressure system over Ukraine. During the warm period of the year, the southwestern Asia thermal low and the subtropical anticyclone of the Atlantic Ocean affect Greece. Though these synoptic systems cause almost stagnant conditions, four main air mass types are dominant and ten others, associated with extreme weather, are infrequent. Despite the large amounts of total solar radiation characterizing this period, ozone concentrations remain at low levels in central Athens because of its destruction by nitric oxide.

  2. MISR Aerosol Air Mass Type Mapping over Mega-City: Validation and Applications

    NASA Astrophysics Data System (ADS)

    Patadia, F.; Kahn, R. A.

    2010-12-01

    Most aerosol air-quality monitoring in mega-city environments is done from scattered ground stations having detailed chemical and optical sampling capabilities. Satellite instruments such as the Multi-angle Imaging SpectroRadiometer (MISR) can retrieve total-column Aerosol Optical Depth (AOD), along with some information about particle microphysical properties. Although the particle property information from MISR is much less detailed than that obtained from the ground sampling stations, the coverage is extensive, making it possible to put individual surface observations into the context of regional aerosol air mass types. This paper presents an analysis of MISR aerosol observations made coincident with aircraft and ground-based instruments during the INTEX-B field campaign. These detailed comparisons of satellite aerosol property retrievals against dedicated field measurements provide the opportunity to validate the retrievals quantitatively at a regional level, and help to improve aerosol representation in retrieval algorithms. Validation of MISR retrieved AOD and other aerosol properties over the INTEX-B study region in and around Mexico City will be presented. MISR’s ability to distinguish among aerosol air mass types will be discussed. The goal of this effort is to use the MISR aerosol property retrievals for mapping both aerosol air mass type and AOD gradients in mega-city environments over the decade-plus that MISR has made global observations.

  3. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  4. On the association between daily mortality and air mass types in Athens, Greece during winter and summer.

    PubMed

    Kassomenos, Pavlos A; Gryparis, Alexandros; Katsouyanni, Klea

    2007-03-01

    In this study, we examined the short-term effects of air mass types on mortality in Athens, Greece. An objective air mass types classification was used, based on meteorological parameters measured at the surface. Mortality data were treated with generalized additive models (GAM) and extending Poisson regression, using a LOESS smoother to control for the confounding effects of seasonal patterns, adjusting also for temperature, long-term trends, day of the week, and ambient particle concentrations. The introduced air mass classification explains the daily variation of mortality to a statistically significant degree. The highest daily mortality was observed on days characterized by southerly flow conditions for both the cold (increase in relative risk for mortality 9%; with a 95% confidence interval: 3-14%), and the warm period (7%; with a 95% confidence interval: 2-13%) of the year. The northeasterly flow is associated with the lowest mortality. Effects on mortality, independent of temperature, are observed mainly for lag 0 during the cold period, but persist longer during the warm period. Not adjusting for temperature and/or ambient particle levels slightly alters the results, which then reflect the known temperature and particle effects, already reported in the literature. In conclusion, we find that air mass types have independent effects on mortality for both the cold and warm season and may be used to predict weather-related adverse health effects.

  5. Calculations of relative optical air masses for various aerosol types and minor gases in Arctic and Antarctic atmospheres

    NASA Astrophysics Data System (ADS)

    Tomasi, Claudio; Petkov, Boyan H.

    2014-02-01

    The dependence functions of relative optical air mass on apparent solar zenith angle θ have been calculated over the θ < 87° range for the vertical profiles of wet-air molecular number density in the Arctic and Antarctic atmospheres, extinction coefficients of different aerosol types, and molecular number density of water vapor, ozone, nitrogen dioxide, and oxygen dimer. The calculations were made using as weight functions the seasonal average vertical profiles of (i) pressure and temperature derived from multiyear sets of radiosounding measurements performed at Ny-Ålesund, Alert, Mario Zucchelli, and Neumayer stations; (ii) volume extinction coefficients of background summer aerosol, Arctic haze, and Kasatochi and Pinatubo volcanic aerosol measured with lidars or balloon-borne samplings; and (iii) molecular number concentrations of the above minor gases, derived from radiosonde, ozonesonde, and satellite-based observations. The air mass values were determined using a formula based on a realistic atmospheric air-refraction model. They were systematically checked by comparing their mutual differences with the uncertainties arising from the seasonal and daily variations in pressure and temperature conditions within the various ranges, where aerosol and gases attenuate the solar radiation most efficiently. The results provide evidence that secant-approximated and midlatitude air mass values are inappropriate for analyzing the Sun photometer measurements performed at polar sites. They indicate that the present evaluations can be reliably used to estimate the aerosol optical depth from the Arctic and Antarctic measurements of total optical depth, after appropriate corrections for the Rayleigh scattering and gaseous absorption optical depths.

  6. Steps Toward an EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    We still have a way to go to develop a global climatology of aerosol type from the EOS-era satellite data record that currently spans more than 12 years of observations. We have demonstrated the ability to retrieve aerosol type regionally, providing a classification based on the combined constraints on particle size, shape, and single-scattering albedo (SSA) from the MISR instrument. Under good but not necessarily ideal conditions, the MISR data can distinguish three-to-five size bins, two-to-four bins in SSA, and spherical vs. non-spherical particles. However, retrieval sensitivity varies enormously with scene conditions. So, for example, there is less information about aerosol type when the mid-visible aerosol optical depth (AOD) is less that about 0.15 or 0.2.

  7. Study of the Tropospheric Aerosol Structure Under Changing of the Air Mass Type from Lidar Observations in Tomsk

    NASA Astrophysics Data System (ADS)

    Samoilova, S. V.; Balin, Yu. S.; Kokhanenko, G. P.; Penner, I. É.

    2016-04-01

    The aerosol optical characteristics in the main tropospheric layers are investigated based on joint interpretation of data of multi-frequency lidar sensing (110 sessions) and results of modeling of back air mass trajectories. Methodical problems for separating layers with different scattering properties and estimating their vertical boundaries are considered. Three optical criteria are simultaneously used to distinguish aerosol layers from cloud formations, including the gradient of the backscattering coefficient, optical depth, and the depolarization ratio. High values of the lidar ratio (66 sr) and of the Angstrom exponent (1.62) in the shortwavelength spectral range are observed in the boundary layer for Arctic transport. At the same time, low values of these optical parameters are characteristic for Asian transport: the lidar ratio is 54 sr and the Angstrom exponent is 1.1, which is explained by different relative contributions of the coarse and fine aerosol fractions to the air mass.

  8. The Effective Mass of a Ball in the Air

    ERIC Educational Resources Information Center

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  9. Evolution of Southern Hemisphere spring air masses observed by HALOE

    NASA Technical Reports Server (NTRS)

    Pierce, R. Bradley; Grose, William L.; Russell, James M., III; Tuck, Adrian F.

    1994-01-01

    The evolution of Southern Hemisphere air masses observed by the Halogen Occultation Experiment (HALOE) during September 21 through October 15, 1992, is investigated using isentropic trajectories computed from United Kingdom Meteorological Office (UKMO) assimilated winds and temperatures. Maps of constituent concentrations are obtained by accumulation of air masses from previous HALOE occultations. Lagged correlations between initial and subsequent HALOE observations of the same air mass are used to validate the air mass trajectories. High correlations are found for lag times as large as 10 days. Frequency distributions of the air mass constituent concentrations are used to examine constituent distributions in and around the Southern Hemisphere polar vortex.

  10. Air Mass Frequency during Precipitation Events in the United States Northern Plains

    NASA Astrophysics Data System (ADS)

    Loveless, D. M.; Sharr, N. J.; Baum, A.; Contract, J. S.; DePasquale, R.; Godek, M. L.

    2013-12-01

    Since 1980, numerous billion-dollar disasters have affected the Northern Plains of the United States, including nine droughts and four floods. Given the region's large agricultural sector, the ability to accurately forecast the frequency and quantity of precipitation events here is imperative as it has a major impact on the economy of states in the region. The atmospheric environment present during precipitation events can largely be described by the presiding air mass conditions since air masses characterize a multitude of meteorological variables at one time over a large region. Therefore, understanding the relationship between air masses and rainfall episodes can contribute to improved precipitation forecasts. The goal of this research is to add knowledge to current understandings of the factors responsible for precipitation in the Northern Plains through an assessment of synoptic air mass conditions. The Spatial Synoptic Classification is used to categorize 30 years of daily air mass types across the region and daily precipitation is acquired from the United States Historical Climatological Network at stations in close proximity. Air mass frequencies are then analyzed for all regional precipitation events and rainfall categories are developed based on precipitation quantity. Both annual and seasonal air mass frequencies are assessed at the time of precipitation events. Additionally, air mass frequencies are obtained for positive and negative phases of the Pacific/North American Pattern to examine the influence of a teleconnection forcing factor on the air mass types responsible for producing precipitation quantities. Results indicate that the Transitional (TR) air mass, associated with changing air mass conditions commonly related to passing fronts, is not the leading producer of rainfall in the region. The TR is generally responsible for only 10-20% of regional precipitation, which often is classed in a heavy rainfall category. All moist air mass varieties are

  11. Isentropic analysis of polar cold air mass streams

    NASA Astrophysics Data System (ADS)

    Iwasaki, Toshiki; Kanno, Yuki

    2015-04-01

    1. Introduction A diagnostic method is presented of polar cold air mass streams defined below a threshold potential temperature. The isentropic threshold facilitates a Lagrangian view of the cold air mass streams from diabatic generation to disappearance. 2. Mass-weighted isentropic zonal mean (MIM) cold air streams In winter hemispheres, MIM's mass stream functions show a distinct extratropical direct (ETD) cell in addition to the Hadley cell. The mass stream functions have local maxima at around (280K, 45N) for NH winter and, around (280K, 50S) for SH winter. Thus, =280K may be appropriate to a threshold of the polar cold air mass for both hemispheres. The high-latitude downward motion indicates the diabatic generation of cold air mass, whereas the mid-latitude equatorward flow does its outbreak. The strength of equatorward flow is under significant control of wave-mean flow interactions. 3. Geographical distribution of the cold air mass streams in the NH winter In the NH winter, the polar cold air mass flux has two distinct mainstreams, hereafter called as East Asian (EA) stream and the North American (NA) stream. The former grows over the northern part of the Eurasian continent, turns down southeastward toward East Asia and disappears over the western North Pacific Ocean. The latter grows over the Arctic Ocean, flows toward the East Coast of North America and disappears over the western North Atlantic Ocean. These coincide well with main routes of cold surges. 4. Comparison between NH and SH winter streams The cold air mass streams in NH winter are more asymmetric than those in SH winter. The NH total cold air mass below =280K is about 1.5 times greater than the SH one. These come mainly from the topography and land-sea distribution. The mid-latitude mountains steer the cold air mass streams on the northern sides and enhance the residence time over its genesis region.

  12. Ions in oceanic and continental air masses

    SciTech Connect

    Tanner, D.J.; Eisele, F.L. )

    1991-01-20

    Measurements of tropospheric ions and several trace atmospheric neutral species have been performed at Cheeka Peak Research Station and at Mauna Loa Observatory. Two new positive ion species at masses 114 and 102 have been identified as protonated caprolactam and a saturated 6-carbon primary amine, respectively. In the negative ion spectrum, methane sulfonic acid (MSA) has been identified as the parent species responsible for an ion commonly observed at mass 95 during these two studies. The diurnal variations of gas phase H{sub 2}SO{sub 4} and MSA were also measured at Cheeka Peak and have typically been found to be present in the sub-ppt range. Ion assisted measurements at Mauna Loa Observatory of pyridine and ammonia indicate concentrations of 2.5 and 70 ppt, respectively, with at least a factor of 2 uncertainty. Interesting variations and potential sources of several of the observed ions are also discussed.

  13. A Synoptic Air Mass Approach to Defining Southwest U.S. Summer Duration and Change

    NASA Astrophysics Data System (ADS)

    Morrill, C.; Wachtel, C. J.; Godek, M. L.

    2015-12-01

    As the past decade was the warmest in the 110-year active record, and future Southwest warming is expected to be most intense in the summer season, it is important to have an updated atmospheric definition of what constitutes a Southwest summer. This is particularly true given the intensity of current drought conditions and that summers may be changing. Using weather-type data from the Spatial Synoptic Classification, this research aims to synoptically define the summer season in the Southwest since 1950. The Southwest is spatially described here by sub-region and 28 air mass stations within are chosen for air mass analysis. Daily air mass frequencies are examined to determine the dominant and less prevalent types annually and seasonally, from May to September. Then, frequencies in the middle of summer are compared to those in the seasonal fringe months to explore the possibility of a synoptic shift in the timing of the region's summer season. Finally, to further scrutinize how regional air mass frequencies have changed with time, the data are subdivided and evaluated for the 'Early record' (years prior to 1975) and 'Modern record' (post 1975). Frequency departures are tested for practical and statistical significance to characterize the strength of summer season variability. Results indicate that Dry Moderate air masses are the most common annually and in summer. Moist and transitional air masses tend to less frequent throughout the Southwest; however, frequencies vary greatly by sub-region. Wet and dry conditions are observed in accordance with the monsoon in some sub-regions, but not throughout the region. Significant changes in sub-regional air mass tendencies are identified that show the Early record experienced cooler air mass conditions (fewer tropical types and more moderate and cool types) than the Modern record. From a long-term synoptic air mass perspective, typical Southwest summers likely last from May to August. However, in the Modern record May

  14. Relationships between submicrometer particulate air pollution and air mass history in Beijing, China, 2004 2006

    NASA Astrophysics Data System (ADS)

    Wehner, B.; Birmili, W.; Ditas, F.; Wu, Z.; Hu, M.; Liu, X.; Mao, J.; Sugimoto, N.; Wiedensohler, A.

    2008-10-01

    The Chinese capital Beijing is one of the global megacities where the effects of rapid economic growth have led to complex air pollution problems that are not well understood. In this study, ambient particle number size distributions in Beijing between 2004 and 2006 are analysed as a function of regional meteorological transport. An essential result is that the particle size distribution in Beijing depends to large extent on the history of the synoptic scale air masses. A first approach based on manual back trajectory classification yielded differences in particulate matter mass concentration by a factor of two between four different air mass categories, including three main wind directions plus the case of stagnant air masses. A back trajectory cluster analysis refined these results, yielding a total of six trajectory clusters. Besides the large scale wind direction, the transportation speed of an air mass was found to play an essential role on the PM concentrations in Beijing. Slow-moving air masses were shown to be associated with an effective accumulation of surface-based anthropogenic emissions due to both, an increased residence time over densely populated land, and their higher degree of vertical stability. For the six back trajectory clusters, differences in PM1 mass concentrations by a factor of 3.5, in the mean air mass speed by a factor of 6, and in atmospheric visibility by a factor of 4 were found. The main conclusion is that the air quality in Beijing is not only degraded by anthropogenic aerosol sources from within the megacity, but also by sources across the entire Northwest China plain depending on the meteorological situation.

  15. Relationships between submicrometer particulate air pollution and air mass history in Beijing, China, 2004-2006

    NASA Astrophysics Data System (ADS)

    Wehner, B.; Birmili, W.; Ditas, F.; Wu, Z.; Hu, M.; Liu, X.; Mao, J.; Sugimoto, N.; Wiedensohler, A.

    2008-06-01

    The Chinese capital Beijing is one of the global megacities where the effects of rapid economic growth have led to complex air pollution problems that are not well understood. In this study, ambient particle number size distributions in Beijing between 2004 and 2006 are analysed as a function of regional meteorological transport. An essential result is that the particle size distribution in Beijing depends to large extent on the history of the synoptic scale air masses. A first approach based on manual back trajectory classification yielded differences in particulate matter mass concentration (PM1 and PM10) by a factor of two between four different air mass categories, including three main wind directions plus the case of stagnant air masses. A back trajectory cluster analysis refined these results, yielding a total of six trajectory clusters. Besides the large scale wind direction, the transportation speed of an air mass was found to play an essential role on the PM concentrations in Beijing. Slow-moving air masses were shown to be associated with an effective accumulation of surface-based anthropogenic emissions due to both, an increased residence time over densely populated land, and their higher degree of vertical stability. For the six back trajectory clusters, differences in PM1 mass concentrations by a factor of 3.5, in the mean air mass speed by a factor of 6, and in atmospheric visibility by a factor of 4 were found. The main conclusion is that the air quality in Beijing is not only degraded by anthropogenic aerosol sources from within the megacity, but also by sources across the entire Northwest China plain depending on the meteorological situation.

  16. 3. AIR TO GROUND RADAR TYPE GT2122 & GRRR 2324, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. AIR TO GROUND RADAR TYPE GT2122 & GRRR 2324, CIRCA 1978, INTERIOR OF BUILDING 408, LOOKING WEST. - Mill Valley Air Force Station, Operations Building & Annex, East Ridgecrest Boulevard, Mount Tamalpais, Mill Valley, Marin County, CA

  17. Mass extinctions: Sensitivity of marine larval types.

    PubMed

    Valentine, J W; Jablonski, D

    1986-09-01

    Developmental types of marine invertebrates may be divided into planktotrophs, which feed on suspended food items, and nonplanktotrophs, which do not feed but are supplied with nutrients (yolk) parentally; these may represent high mortality-fecundity and low mortality-fecundity strategies, respectively. Most versions of the bolide impact hypothesis of mass extinction propose occlusion of the sun by dust or smoke and severance of planktonic food chains for months or a few years, and this should select preferentially against planktotrophs. Yet among fossil prosobranch gastropods, planktotrophs survived the end-Cretaceous extinction equally as well as nonplanktotrophs. Indirect evidence suggests that end-Permian extinctions may have selected against planktotrophs but that the effect was prolonged over millions of years.

  18. Field calibration of two types of microphones in hyperbaric air

    NASA Astrophysics Data System (ADS)

    Smith, Paul F.; Carpenter, Susan; Green, John

    1990-01-01

    The response of two microphones, one a condenser microphone and the other a diaphragm-activated piezoelectric ceramic microphone, were measured in compressed air at pressures as great as 810 kilopascals (8 atmospheres). The response of each microphone was compared to that of a hydrophone operated in air as a microphone. The results show that the two types of microphone respond similarly to high ambient pressure. Both types are less sensitive to sound pressure in compressed air than in air at normal pressures, and the frequency responses of both microphones are altered. The results are useful in the analyses of ambient noise measurements done during experiments in compressed air.

  19. Where do the air masses between double tropopauses come from?

    NASA Astrophysics Data System (ADS)

    Parracho, A. C.; Marques, C. A. F.; Castanheira, J. M.

    2014-01-01

    An analysis of the origin of air masses that end up between double tropopauses (DT) in the subtropics and midlatitudes is presented. The double tropopauses were diagnosed in the ERA-Interim reanalysis (1979-2010), and the origin of air masses was analysed using the Lagrangian model FLEXPART. Different processes for the formation of double tropopauses (DT) have been suggested in the literature. Some studies have suggested that double tropopauses may occur as a response to the vertical profile of adiabatic heating, due to the residual meridional circulation, while others have put forward contradicting explanations. Whereas some studies have suggested that double tropopauses result from poleward excursions of the tropical tropopause over the extratropical one, others have argued that DTs develop in baroclinic unstable processes involving transport of air from high latitudes. In some regions, the DT structure has a semipermanent character which cannot be explained by excursions of the tropical tropopause alone. However, the results presented in this paper confirm that processes involving excursions of the tropical tropopause over the extratropical tropopause, which are therefore accompanied by intrusions of air from the tropical troposphere into the lower extratropical stratosphere, make a significant contribution for the occurrence of DTs in the subtropics and midlatitudes. Specifically, it is shown that the air between double tropopauses comes from equatorward regions, and has a higher percentage of tropospheric particles and a lower mean potential vorticity.

  20. Air blast type coal slurry fuel injector

    DOEpatents

    Phatak, Ramkrishna G.

    1986-01-01

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  1. Air blast type coal slurry fuel injector

    DOEpatents

    Phatak, R.G.

    1984-08-31

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  2. Thin-Film Air-Mass-Flow Sensor of Improved Design Developed

    NASA Technical Reports Server (NTRS)

    Fralick, Gustave C.; Wrbanek, John D.; Hwang, Danny P.

    2003-01-01

    used to provide accurate information about the amount of air entering the engine so that the amount of fuel can be adjusted to give the most efficient combustion. The ideal mass-flow sensor would be a rugged design that minimizes the disturbance to the flow stream and provides an accurate reading of both smooth and turbulent flows; NASA's design satisfies these requirements better than any existing design. Most of the mass-flow sensors used today are the hot wire variety. Hot wires can be fragile and cannot accurately measure a turbulent or reversing flow, which is often encountered in an intake manifold. Other types of mass-flow sensors include pitot tubes, vane anemometers, and thermocouple rakes-all of which suffer from some type of performance problem. Because it solves these performance problems while maintaining a simple design that lends itself to low-cost manufacturing techniques, NASA s thin-film resistance temperature detector air-mass-flow sensor should lead to more widespread use of mass-flow sensors.

  3. The mass and speed dependence of meteor air plasma temperatures

    NASA Technical Reports Server (NTRS)

    Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  4. The mass and speed dependence of meteor air plasma temperatures.

    PubMed

    Jenniskens, Peter; Laux, Christophe O; Wilson, Michael A; Schaller, Emily L

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  5. Mass Media Types: Three Q-Analyses of Mass Media Exposure.

    ERIC Educational Resources Information Center

    Walker, James R.

    The purpose of a mass media study was to (l) identify mass media types (patterns of exposure to mass media content) among seventh graders, high school juniors, and adults in a given geographic area; (2) show similarities and differences in the mass media types isolated for these three age groups; (3) pinpoint demographic variables most strongly…

  6. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public....142 Air supply source; hand-operated or motor driven air blowers; Type A supplied-air...

  7. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public....142 Air supply source; hand-operated or motor driven air blowers; Type A supplied-air...

  8. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public....142 Air supply source; hand-operated or motor driven air blowers; Type A supplied-air...

  9. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public....142 Air supply source; hand-operated or motor driven air blowers; Type A supplied-air...

  10. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public....142 Air supply source; hand-operated or motor driven air blowers; Type A supplied-air...

  11. Air Pollution May Raise Risk of Type 2 Diabetes

    MedlinePlus

    ... Southern California's Diabetes and Obesity Research Institute. "Poor air quality appears to be a catalyst for obesity and ... Health Recent Health News Related MedlinePlus Health Topics Air Pollution Diabetes Type 2 Hispanic American Health ... Guidelines Viewers & Players MedlinePlus Connect for EHRs For ...

  12. Mass flow in loop type coronal transients

    NASA Technical Reports Server (NTRS)

    Anzer, U.; Poland, A. I.

    1979-01-01

    Coronal transients having characteristics of a well-defined loop structure are examined, particularly with respect to temporal changes in the density and mass per unit length along the loop over periods of several days after the initial eruption. Measurements of mass distributions as a function of time are presented for eight transients, and one particular transient with a fairly simple configuration is investigated in more detail. Theoretical calculations are combined with the masses and densities derived from the observations to obtain estimates of the material flow in the transients; this flow is modeled on the assumption that magnetic forces drive and confine the loop. The flow field is found to be diverging everywhere, indicating that the density decreases in time. It is inferred that the transient legs are approximately in hydrostatic equilibrium and that most of the mass of the transient is lost from the sun during the initial phase.

  13. Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

    NASA Astrophysics Data System (ADS)

    Dugaria, S.; Moro, L.; Del, D., Col

    2015-11-01

    The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

  14. Air-stable n-type colloidal quantum dot solids.

    PubMed

    Ning, Zhijun; Voznyy, Oleksandr; Pan, Jun; Hoogland, Sjoerd; Adinolfi, Valerio; Xu, Jixian; Li, Min; Kirmani, Ahmad R; Sun, Jon-Paul; Minor, James; Kemp, Kyle W; Dong, Haopeng; Rollny, Lisa; Labelle, André; Carey, Graham; Sutherland, Brandon; Hill, Ian; Amassian, Aram; Liu, Huan; Tang, Jiang; Bakr, Osman M; Sargent, Edward H

    2014-08-01

    Colloidal quantum dots (CQDs) offer promise in flexible electronics, light sensing and energy conversion. These applications rely on rectifying junctions that require the creation of high-quality CQD solids that are controllably n-type (electron-rich) or p-type (hole-rich). Unfortunately, n-type semiconductors made using soft matter are notoriously prone to oxidation within minutes of air exposure. Here we report high-performance, air-stable n-type CQD solids. Using density functional theory we identify inorganic passivants that bind strongly to the CQD surface and repel oxidative attack. A materials processing strategy that wards off strong protic attack by polar solvents enabled the synthesis of an air-stable n-type PbS CQD solid. This material was used to build an air-processed inverted quantum junction device, which shows the highest current density from any CQD solar cell and a solar power conversion efficiency as high as 8%. We also feature the n-type CQD solid in the rapid, sensitive, and specific detection of atmospheric NO2. This work paves the way for new families of electronic devices that leverage air-stable quantum-tuned materials.

  15. High-Altitude Air Mass Zero Calibration of Solar Cells

    NASA Technical Reports Server (NTRS)

    Woodyard, James R.; Snyder, David B.

    2005-01-01

    Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

  16. Monitoring Trace Contaminants in Air Via Ion Trap Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Palmer, Peter T.; Karr, Dane; Pearson, Richard; Valero, Gustavo; Wong, Carla

    1995-01-01

    Recent passage of the Clean Air Act with its stricter regulation of toxic gas emissions, and the ever-growing number of applications which require faster turnaround times between sampling and analysis are two major factors which are helping to drive the development of new instrument technologies for in-situ, on-line, real-time monitoring. The ion trap, with its small size, excellent sensitivity, and tandem mass spectrometry capability is a rapidly evolving technology which is well-suited for these applications. In this paper, we describe the use of a commercial ion trap instrument for monitoring trace levels of chlorofluorocarbons (CFCs) and volatile organic compounds (VOCs) in air. A number of sample introduction devices including a direct transfer line interface, short column GC, and a cryotrapping interface are employed to achieve increasing levels of sensitivity. MS, MS/MS, and MS/MS/MS methods are compared to illustrate trade-offs between sensitivity and selectivity. Filtered Noise Field (FNF) technology is found to be an excellent means for achieving lower detection limits through selective storage of the ion(s) of interest during ionization. Figures of merit including typical sample sizes, detection limits, and response times are provided. The results indicate the potential of these techniques for atmospheric assessments, the High Speed Research Program, and advanced life support monitoring applications for NASA.

  17. 42 CFR 84.155 - Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Airflow resistance test; Type C supplied-air... Respirators § 84.155 Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE supplied-air respirator; minimum requirements. The resistance to air flowing from the...

  18. 42 CFR 84.155 - Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Airflow resistance test; Type C supplied-air... Respirators § 84.155 Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE supplied-air respirator; minimum requirements. The resistance to air flowing from the...

  19. 42 CFR 84.155 - Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test; Type C supplied-air... Respirators § 84.155 Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE supplied-air respirator; minimum requirements. The resistance to air flowing from the...

  20. 42 CFR 84.155 - Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Airflow resistance test; Type C supplied-air... Respirators § 84.155 Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE supplied-air respirator; minimum requirements. The resistance to air flowing from the...

  1. 42 CFR 84.155 - Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test; Type C supplied-air... Respirators § 84.155 Airflow resistance test; Type C supplied-air respirator, continuous flow class and Type CE supplied-air respirator; minimum requirements. The resistance to air flowing from the...

  2. Improving Hydrological Models by Applying Air Mass Boundary Identification in a Precipitation Phase Determination Scheme

    NASA Astrophysics Data System (ADS)

    Feiccabrino, James; Lundberg, Angela; Sandström, Nils

    2013-04-01

    inversion) of air in the vertical profile between the lower cold air mass and the warm air mass above. The warm air forced up often cools to its condensation temperature, becoming the main cause of winter precipitation. A common exception comes with cold air mass boundaries (CAMB) not having a frontal inversion in the vertical profile. Therefore, CAMB precipitation occurs under very different lower tropospheric conditions, than other precipitation. Changes in continuous hourly AOS temperature and wind could be used to identify different types of surface air mass boundaries. When identified rain and snow observations occurring immediately before CAMB were separated from all other observations, the TS and TR values -1° C, 3° C respectively, were found to be 1° C cooler than the TS and TR for non-CAMB observations. Analyzing CAMB separately reduced total misclassified precipitation from 7.0% to 5.4% (23% improvement) in the PPTZ. However, this tool only allows a statistically better chance for correct precipitation phase determination; it is incapable of adjustments for deviations from an average vertical temperature lapse rate.

  3. An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

    NASA Astrophysics Data System (ADS)

    Zander, R.; Messina, A.; Godek, M. L.

    2012-12-01

    The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

  4. A determination of character and frequency changes in air masses using a spatial synoptic classification

    NASA Astrophysics Data System (ADS)

    Kalkstein, Laurence S.; Sheridan, Scott C.; Graybeal, Daniel Y.

    1998-09-01

    Of the numerous climate change studies which have been performed, few of these have analyzed recent trends using an air mass-based approach. The air mass approach is superior to simple trend analysis, as it can identify patterns which may be too subtle to influence the entire climate record. The recently-developed spatial synoptic classification (SSC) is thus used to identify trends over the contiguous United States for summer and winter seasons from 1948 to 1993. Both trends in air mass frequency and character have been assessed.The most noteworthy trend in frequency is a decline in air mass transitional days (TR) during both seasons. In winter, decreases of up to 1% per decade are noted in parts of the central U.S. Other notable trends include a decrease in moist tropical (MT) air in winter, and an increase in MT in summer over the southeastern states.Numerous national and local air mass character changes have been uncovered. A large overall upward trend in cloudiness is noted in summer. All air masses feature an overnight increase, yet afternoon cloudiness increases are generally limited to the three dry air masses. Also in summer, a significant warming and increase in dew point of MT air has occurred at many locales. The most profound winter trend is a large decrease in dew point (up to 1.5°C per decade) in the dry polar (DP) air mass over much of the eastern states.

  5. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    PubMed

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  6. Mathematical modeling of heat exchange between mine air and rock mass during fire

    SciTech Connect

    A.E. Krasnoshtein; B.P. Kazakov; A.V. Shalimov

    2006-05-15

    Solution of problems on heat exchange between ventilating air and rock mass and on gas admixture propagation in mine workings serve as a base for considering changes in heat-gas-air state at a mine after inflammation. The presented mathematical relations allow calculation of a varied velocity and movement direction of air flows, their temperatures and smoking conditions during fire.

  7. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins.

  8. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

    2014-01-01

    The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

  9. Development of an Air Transport Type A Fissile Package

    SciTech Connect

    Blanton, P.; Ebert, K.

    2011-07-13

    This paper presents the summary of testing by the Savannah River National Laboratory (SRNL) to support development of a light weight (<140 lbs) air transport qualified Type A Fissile Packaging. The package design incorporates features and materials specifically designed to minimize packaging weight. The light weight package is being designed to provide confinement to the contents when subjected to the normal and hypothetical conditions required of an air transportable Type A Fissile radioactive material shipping package. The objective of these tests was to provide design input to the final design for the LORX Type A Fissile Air Transport Packaging when subjected to the performance requirements of the drop, crush and puncture probe test of 10CFR71. The post test evaluation of the prototype packages indicates that all of the tested designs would satisfactorily confine the content within the packaging. The differences in the performance of the prototypes varied significantly depending on the core materials and their relative densities. Information gathered from these tests is being used to develop the final design for the Department of Homeland Security.

  10. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  11. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Technical Reports Server (NTRS)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  12. High Capacity Pouch-Type Li-air Batteries

    SciTech Connect

    Wang, Deyu; Xiao, Jie; Xu, Wu; Zhang, Jiguang

    2010-05-05

    The pouch-type Li-air batteries operated in ambient condition are reported in this work. The battery used a heat sealable plastic membrane as package material, O2¬ diffusion membrane and moisture barrier. The large variation in internal resistance of the batteries is minimized by a modified separator which can bind the cell stack together. The cells using the modified separators show improved and repeatable discharge performances. It is also found that addition of about 20% of 1,2-dimethoxyethane (DME) in PC:EC (1:1) based electrolyte solvent improves can improve the wetability of carbon electrode and the discharge capacities of Li-air batteries, but further increase in DME amount lead to a decreased capacity due to increase electrolyte loss during discharge process. The pouch-type Li-air batteries with the modified separator and optimized electrolyte has demonstrated a specific capacity of 2711 mAh g-1 based on carbon and a specific energy of 344 Wh kg-1 based on the complete batteries including package.

  13. Galaxy And Mass Assembly (GAMA): stellar mass functions by Hubble type

    NASA Astrophysics Data System (ADS)

    Kelvin, Lee S.; Driver, Simon P.; Robotham, Aaron S. G.; Taylor, Edward N.; Graham, Alister W.; Alpaslan, Mehmet; Baldry, Ivan; Bamford, Steven P.; Bauer, Amanda E.; Bland-Hawthorn, Joss; Brown, Michael J. I.; Colless, Matthew; Conselice, Christopher J.; Holwerda, Benne W.; Hopkins, Andrew M.; Lara-López, Maritza A.; Liske, Jochen; López-Sánchez, Ángel R.; Loveday, Jon; Norberg, Peder; Phillipps, Steven; Popescu, Cristina C.; Prescott, Matthew; Sansom, Anne E.; Tuffs, Richard J.

    2014-10-01

    We present an estimate of the galaxy stellar mass function and its division by morphological type in the local (0.025 < z < 0.06) Universe. Adopting robust morphological classifications as previously presented (Kelvin et al.) for a sample of 3727 galaxies taken from the Galaxy And Mass Assembly survey, we define a local volume and stellar mass limited sub-sample of 2711 galaxies to a lower stellar mass limit of {M}=10^{9.0} M_{{⊙}}. We confirm that the galaxy stellar mass function is well described by a double-Schechter function given by {M}^{*}=10^{10.64} M_{{⊙}}, α1 = -0.43, φ 1^{*}=4.18dex^{-1} Mpc^{-3}, α2 = -1.50 and φ 2^{*}=0.74dex^{-1} Mpc^{-3}. The constituent morphological-type stellar mass functions are well sampled above our lower stellar mass limit, excepting the faint little blue spheroid population of galaxies. We find approximately 71{}_{-4}^{+3} per cent of the stellar mass in the local Universe is found within spheroid-dominated galaxies; ellipticals and S0-Sas. The remaining 29{}_{-3}^{+4} per cent falls predominantly within late-type disc-dominated systems, Sab-Scds and Sd-Irrs. Adopting reasonable bulge-to-total ratios implies that approximately half the stellar mass today resides in spheroidal structures, and half in disc structures. Within this local sample, we find approximate stellar mass proportions for E : S0-Sa : Sab-Scd : Sd-Irr of 34 : 37 : 24 : 5.

  14. 42 CFR 84.153 - Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Airflow resistance test, Type A and Type AE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.153 Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements. (a) Airflow resistance will...

  15. 42 CFR 84.154 - Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Airflow resistance test; Type B and Type BE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.154 Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements. (a) Airflow resistance shall...

  16. 42 CFR 84.154 - Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Airflow resistance test; Type B and Type BE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.154 Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements. (a) Airflow resistance shall...

  17. 42 CFR 84.153 - Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Airflow resistance test, Type A and Type AE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.153 Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements. (a) Airflow resistance will...

  18. 42 CFR 84.153 - Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test, Type A and Type AE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.153 Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements. (a) Airflow resistance will...

  19. 42 CFR 84.154 - Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test; Type B and Type BE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.154 Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements. (a) Airflow resistance shall...

  20. 42 CFR 84.154 - Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test; Type B and Type BE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.154 Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements. (a) Airflow resistance shall...

  1. 42 CFR 84.153 - Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Airflow resistance test, Type A and Type AE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.153 Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements. (a) Airflow resistance will...

  2. 42 CFR 84.154 - Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Airflow resistance test; Type B and Type BE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.154 Airflow resistance test; Type B and Type BE supplied-air respirators; minimum requirements. (a) Airflow resistance shall...

  3. 42 CFR 84.153 - Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test, Type A and Type AE... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.153 Airflow resistance test, Type A and Type AE supplied-air respirators; minimum requirements. (a) Airflow resistance will...

  4. Elemental composition of different air masses over Jeju Island, South Korea

    NASA Astrophysics Data System (ADS)

    Kang, Jeongwon; Choi, Man-Sik; Yi, Hi-Il; Jeong, Kap-Sik; Chae, Jung-Sun; Cheong, Chang-Sik

    2013-03-01

    We investigated the characteristics (concentrations and compositional changes) of atmospheric elements in total suspended particulates through source-receptor relationships using cluster analyses to classify air mass back-trajectories arriving at Gosan, Jeju Island, South Korea, from October 2003 to December 2008. Five trajectory clusters were chosen to explain the transport regimes. Continental outflows of natural and anthropogenic aerosols from Asian dust source regions and eastern China during the colder period could increase element concentrations at Gosan. Elemental levels at Gosan decreased in air masses that passed over marine regions (East China Sea, Pacific Ocean/southern side of Kyushu Island in Japan, and East Sea/southern side of South Korea) during the warmer rainy period due to lower source intensity and dilution by the marine air mass. Anthropogenic pollutants were often major components in air masses passing over marine regions. Air mass characterization by elemental concentration and composition revealed that enrichment by non-sea-salt sulfur in the air mass originated from eastern China, indicative of the main sulfur emitter in northeast Asia. The apportionment of V and Ni by principal component analysis as a marker of heavy oil combustion suggested different residence times and deposition rates from other anthropogenic components in the air. Regionally intermediate concentrations of pollutants were found in the atmosphere over the Korean peninsula.

  5. The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

    ERIC Educational Resources Information Center

    Driscoll, John N.; Warneck, Peter

    1973-01-01

    Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

  6. On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Perliski, Lori M.; Solomon, Susan

    1993-01-01

    The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

  7. Experimental Determination of the Mass of Air Molecules from the Law of Atmospheres.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Galvin, Vincent, Jr.

    1979-01-01

    A gas pressure gauge has been constructed for use in a student experiment involving the law of atmospheres. From pressure data obtained at selected elevations the average mass of air molecules is determined and compared to that calculated from the molecular weights and percentages of constituents to the air. (Author/BB)

  8. DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

    EPA Science Inventory

    The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

  9. Aerosol properties and radiative forcing for three air masses transported in Summer 2011 to Sopot, Poland

    NASA Astrophysics Data System (ADS)

    Rozwadowska, Anna; Stachlewska, Iwona S.; Makuch, P.; Markowicz, K. M.; Petelski, T.; Strzałkowska, A.; Zieliński, T.

    2013-05-01

    Properties of atmospheric aerosols and solar radiation reaching the Earth's surface were measured during Summer 2011 in Sopot, Poland. Three cloudless days, characterized by different directions of incoming air-flows, which are typical transport pathways to Sopot, were used to estimate a radiative forcing due to aerosols present in each air mass.

  10. Membrane-type acoustic metamaterial with negative dynamic mass.

    PubMed

    Yang, Z; Mei, Jun; Yang, Min; Chan, N H; Sheng, Ping

    2008-11-14

    We present the experimental realization and theoretical understanding of a membrane-type acoustic metamaterial with very simple construct, capable of breaking the mass density law of sound attenuation in the 100-1000 Hz regime by a significant margin ( approximately 200 times). Owing to the membrane's weak elastic moduli, there can be low-frequency oscillation patterns even in a small elastic film with fixed boundaries defined by a rigid grid. The vibrational eigenfrequencies can be tuned by placing a small mass at the center of the membrane sample. Near-total reflection is achieved at a frequency between two eigenmodes where the in-plane average of normal displacement is zero. By using finite element simulations, negative dynamic mass is explicitly demonstrated at frequencies around the total reflection frequency. Excellent agreement between theory and experiment is obtained.

  11. Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-01-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  12. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  13. Improving microbial air quality in air-conditioned mass transport buses by opening the bus exhaust ventilation fans.

    PubMed

    Luksamijarulkul, Pipat; Arunchai, Nongphon; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2005-07-01

    The air quality in air-conditioned mass transport buses may affect bus drivers' health. In-bus air quality improvement with the voluntary participation of bus drivers by opening the exhaust ventilation fans in the bus was implemented in the Seventh Bus Zone of Bangkok Mass Transit Authority. Four bus numbers, including bus numbers 16, 63, 67 and 166, were randomly selected to investigate microbial air quality and to observe the effect of opening the exhaust ventilation fans in the bus. With each bus number, 9 to 10 air-conditioned buses (total, 39 air-conditioned buses) were included. In-bus air samples were collected at 5 points in each studied bus using the Millipore Air Tester. A total of 195 air samples were cultured for bacterial and fungal counts. The results reveal that the exhaust ventilation fans of 17 air-conditioned buses (43.6%) were opened to ventilate in-bus air during the cycle of the bus route. The means +/- SD of bacterial counts and fungal counts in the studied buses with opened exhaust ventilation fans (83.8 +/- 70.7 and 38.0 +/- 42.8 cfu/m3) were significantly lower than those in the studied buses without opened exhaust ventilation fans (199.6 +/- 138.8 and 294.1 +/- 178.7 cfu/m3), p < 0.0005. All the air samples collected from the studied buses with opened exhaust ventilation fans were at acceptable levels (< 500 cfu/m3) compared with 4.6% of the air samples collected from the studied buses without opened exhaust ventilation fans, which had high levels (> 500 cfu/m3). Of the studied buses with opened exhaust ventilation fans (17 buses), the bacterial and fungal counts after opening the exhaust ventilation fans (68.3 +/- 33.8 and 28.3 +/- 19.3 cfu/m3) were significantly lower than those before opening the exhaust ventilation fans (158.3 +/- 116.9 and 85.3 +/- 71.2 cfu/m3), p < 0.005.

  14. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2012-04-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean, a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol (NR-PM1) was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition, small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions, could be identified in the particle phase

  15. Air mass origin and its influence on radionuclide activities ( 7Be and 210Pb) in aerosol particles at a coastal site in the western Mediterranean

    NASA Astrophysics Data System (ADS)

    Dueñas, C.; Orza, J. A. G.; Cabello, M.; Fernández, M. C.; Cañete, S.; Pérez, M.; Gordo, E.

    2011-07-01

    Studies of radionuclide activities in aerosol particles provide a means for evaluating the integrated effects of transport and meteorology on the atmospheric loadings of substances with different sources. Measurements of aerosol mass concentration and specific activities of 7Be and 210Pb in aerosols at Málaga (36° 43' 40″ N; 4° 28' 8″ W) for the period 2000-2006 were used to obtain the relationships between radionuclide activities and airflow patterns by comparing the data grouped by air mass trajectory clusters. The average concentration values of 7Be and 210Pb over the 7 year period have been found to be 4.6 and 0.58 mBq m -3, respectively, with mean aerosol mass concentration of 53.6 μg m -3. The identified air flow types arriving at Málaga reflect the transitional location of the Iberian Peninsula and show significant differences in radionuclide activities. Air concentrations of both nuclides and the aerosol mass concentration are controlled predominantly by the synoptic scenarios leading to the entrance of dust-laden continental flows from northern Africa and the arrival of polar maritime air masses, as implied by the strong correlations found between the monthly frequencies of the different air masses and the specific activities of both radionuclides. Correlations between activity concentrations and precipitation are significant though lower than with air masses.

  16. Erroneous mass transit system and its tended relationship with motor vehicular air pollution (An integrated approach for reduction of urban air pollution in Lahore).

    PubMed

    Aziz, Amer; Bajwa, Ihsan Ullah

    2008-02-01

    Air pollution is threat to the lives of people living in big cities of Pakistan. In Lahore 1,250 people die annually because of air pollution. Mass transit system that can be put forth as solution to urban air pollution is contingent with right choice of system and its affiliation with motorized vehicles and nature of urban air pollution. Existing mass transit system in Lahore due to untrue operation causes surfeit discharge of motor vehicular carbon monoxide. Tended relationships of mass transit system with motorized vehicles and urban air pollution are quite noteworthy. The growing motor vehicles (a consequence of flawed public mass transit system) are potential source of urban air pollution. This paper attempts to highlight correlations and regression curves of existing mass transit system. Further it recommends a two facet approach for reduction of motor vehicular air pollution in Lahore.

  17. New Types of Ionization Sources for Mass Spectrometry

    SciTech Connect

    2008-12-01

    The purpose of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle (Contractor) and MDS Sciex (Participant) and ESA, Inc. (Participant) is to research, develop and apply new types of ionization sources and sampling/inlet systems for analytical mass spectrometry making use of the Participants state-of-the-art atmospheric sampling mass spectrometry electrochemical cell technology instrumentation and ancillary equipment. The two overriding goals of this research project are: to understand the relationship among the various instrumental components and operational parameters of the various ion sources and inlet systems under study, the chemical nature of the gases, solvents, and analytes in use, and the nature and abundances of the ions ultimately observed in the mass spectrometer; and to develop new and better analytical and fundamental applications of these ion sources and inlet systems or alternative sources and inlets coupled with mass spectrometry on the basis of the fundamental understanding obtained in Goal 1. The end results of this work are expected to be: (1) an expanded utility for the ion sources and inlet systems under study (such as the analysis of new types of analytes) and the control or alteration of the ionic species observed in the gas-phase; (2) enhanced instrument performance as judged by operational figures-of-merit such as dynamic range, detection limits, susceptibility to matrix signal suppression and sensitivity; and (3) novel applications (such as surface sampling with electrospray) in both applied and fundamental studies. The research projects outlined herein build upon work initiated under the previous CRADA between the Contractor and MDS Sciex on ion sources and inlet systems for mass spectrometry. Specific ion source and inlet systems for exploration of the fundamental properties and practical implementation of these principles are given.

  18. Monolithic mass sensor fabricated using a conventional technology with attogram resolution in air conditions

    NASA Astrophysics Data System (ADS)

    Verd, J.; Uranga, A.; Abadal, G.; Teva, J.; Torres, F.; Pérez-Murano, F.; Fraxedas, J.; Esteve, J.; Barniol, N.

    2007-07-01

    Monolithic mass sensors for ultrasensitive mass detection in air conditions have been fabricated using a conventional 0.35μm complementary metal-oxide-semiconductor (CMOS) process. The mass sensors are based on electrostatically excited submicrometer scale cantilevers integrated with CMOS electronics. The devices have been calibrated obtaining an experimental sensitivity of 6×10-11g/cm2Hz equivalent to 0.9ag/Hz for locally deposited mass. Results from time-resolved mass measurements are also presented. An evaluation of the mass resolution have been performed obtaining a value of 2.4×10-17g in air conditions, resulting in an improvement of these devices from previous works in terms of sensitivity, resolution, and fabrication process complexity.

  19. Peroxy radicals and ozone photochemistry in air masses undergoing long-range transport

    NASA Astrophysics Data System (ADS)

    Parker, A. E.; Monks, P. S.; Jacob, M. J.; Penkett, S. A.; Lewis, A. C.; Stewart, D. J.; Whalley, L. K.; Methven, J.; Stohl, A.

    2009-09-01

    Concentrations of peroxy radicals (HO2+ΣiRiO2) in addition to other trace gases were measured onboard the UK Meteorological Office/Natural Environment Research Council British Aerospace 146-300 atmospheric research aircraft during the Intercontinental Transport of Ozone and Precursors (ITOP) campaign based at Horta Airport, Faial, Azores (38.58° N, 28.72° W) in July/August 2004. The overall peroxy radical altitude profile displays an increase with altitude that is likely to have been impacted by the effects of long-range transport. The peroxy radical altitude profile for air classified as of marine origin shows no discernable altitude profile. A range of air-masses were intercepted with varying source signatures, including those with aged American and Asian signatures, air-masses of biomass burning origin, and those that originated from the east coast of the United States. Enhanced peroxy radical concentrations have been observed within this range of air-masses indicating that long-range transported air-masses traversing the Atlantic show significant photochemical activity. The net ozone production at clear sky limit is in general negative, and as such the summer mid-Atlantic troposphere is at limit net ozone destructive. However, there is clear evidence of positive ozone production even at clear sky limit within air masses undergoing long-range transport, and during ITOP especially between 5 and 5.5 km, which in the main corresponds to a flight that extensively sampled air with a biomass burning signature. Ozone production was NOx limited throughout ITOP, as evidenced by a good correlation (r2=0.72) between P(O3) and NO. Strong positive net ozone production has also been seen in varying source signature air-masses undergoing long-range transport, including but not limited to low-level export events, and export from the east coast of the United States.

  20. TYPE A FISSILE PACKAGING FOR AIR TRANSPORT PROJECT OVERVIEW

    SciTech Connect

    Eberl, K.; Blanton, P.

    2013-10-11

    This paper presents the project status of the Model 9980, a new Type A fissile packaging for use in air transport. The Savannah River National Laboratory (SRNL) developed this new packaging to be a light weight (<150-lb), drum-style package and prepared a Safety Analysis for Packaging (SARP) for submission to the DOE/EM. The package design incorporates unique features and engineered materials specifically designed to minimize packaging weight and to be in compliance with 10CFR71 requirements. Prototypes were fabricated and tested to evaluate the design when subjected to Normal Conditions of Transport (NCT) and Hypothetical Accident Conditions (HAC). An overview of the design details, results of the regulatory testing, and lessons learned from the prototype fabrication for the 9980 will be presented.

  1. Model-based flow rate control for an orfice-type low-volume air sampler

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The standard method of measuring air suspended particulate matter concentration per volume of air consists of continuously drawing a defined volume of air across a filter over an extended period of time, then measuring the mass of the filtered particles and dividing it by the total volume sampled ov...

  2. 7 CFR 30.38 - Class 3; air-cured types and groups.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... produced principally in the Green River section of Kentucky. (g) Type 37. That type of air-cured or sun-cured tobacco commonly known as Virginia Sun-cured, Virginia Sun and Air-cured, or Dark Air-cured...

  3. 7 CFR 30.38 - Class 3; air-cured types and groups.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... produced principally in the Green River section of Kentucky. (g) Type 37. That type of air-cured or sun-cured tobacco commonly known as Virginia Sun-cured, Virginia Sun and Air-cured, or Dark Air-cured...

  4. 7 CFR 30.38 - Class 3; air-cured types and groups.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... produced principally in the Green River section of Kentucky. (g) Type 37. That type of air-cured or sun-cured tobacco commonly known as Virginia Sun-cured, Virginia Sun and Air-cured, or Dark Air-cured...

  5. 7 CFR 30.38 - Class 3; air-cured types and groups.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... produced principally in the Green River section of Kentucky. (g) Type 37. That type of air-cured or sun-cured tobacco commonly known as Virginia Sun-cured, Virginia Sun and Air-cured, or Dark Air-cured...

  6. The Initial Mass Function of Early-Type Galaxies

    NASA Astrophysics Data System (ADS)

    Treu, Tommaso; Auger, Matthew W.; Koopmans, Léon V. E.; Gavazzi, Raphaël; Marshall, Philip J.; Bolton, Adam S.

    2010-02-01

    We determine an absolute calibration of the initial mass function (IMF) of early-type galaxies, by studying a sample of 56 gravitational lenses identified by the Sloan Lenses ACS Survey. Under the assumption of standard Navarro, Frenk, and White dark matter halos, a combination of lensing, dynamical, and stellar population synthesis models is used to disentangle the stellar and dark matter contribution for each lens. We define an "IMF mismatch" parameter α≡M LD *,Ein/M SPS *,Ein as the ratio of stellar mass inferred by a joint lensing and dynamical model (M LD *,Ein) to the current stellar mass inferred from stellar populations synthesis models (M SPS *,Ein). We find that a Salpeter IMF provides stellar masses in agreement with those inferred by lensing and dynamical models (langlog αrang = -0.00 ± 0.03 ± 0.02), while a Chabrier IMF underestimates them (langlog αrang = 0.25 ± 0.03 ± 0.02). A tentative trend is found, in the sense that α appears to increase with galaxy velocity dispersion. Taken at face value, this result would imply a non-universal IMF, perhaps dependent on metallicity, age, or abundance ratios of the stellar populations. Alternatively, the observed trend may imply non-universal dark matter halos with inner density slope increasing with velocity dispersion. While the degeneracy between the two interpretations cannot be broken without additional information, the data imply that massive early-type galaxies cannot have both a universal IMF and universal dark matter halos. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with programs 10174, 10587, 10886, 10494, 10798, and 11202.

  7. All-solid-state cable-type flexible zinc-air battery.

    PubMed

    Park, Joohyuk; Park, Minjoon; Nam, Gyutae; Lee, Jang-soo; Cho, Jaephil

    2015-02-25

    A cable-type flexible Zn-air battery with a spiral zinc anode, gel polymer electrolyte (GPE), and air cathode coated on a nonprecious metal catalyst is designed in order to extend its application area toward wearable electronic devices.

  8. Phenomenology of "bimaximal + Democratic" Type Neutrino Mass Matrix

    NASA Astrophysics Data System (ADS)

    Ghosal, Ambar; Majumdar, Debasish

    We demonstrate that "Bimaximal + Democratic" type neutrino mass matrix can accommodate the deviation of θ⊙ from its maximal value along with the other present-day neutrino experimental results, namely, atmospheric, CHOOZ, neutrinoless double beta decay (ββ0ν) and result obtained from WMAP experiment. We define a function χp in terms of solar and atmospheric neutrino mass squared differences and solar neutrino mixing angle (obtained from different experiments and our proposed texture). The masses and mixing angles are expressed in terms of three parameters in our proposed texture. The allowed region of the texture parameters is obtained through minimization of the above function. The proposed texture crucially depends on the value of the experimental results of ββ0ν experiment among all other above-mentioned experiments. If, in future, ββ0ν experiments, namely, MOON, EXO, GENIUS shift the lower bound on at the higher side by one order, the present texture will be ruled out.

  9. A TYPE II RADIO BURST WITHOUT A CORONAL MASS EJECTION

    SciTech Connect

    Su, W.; Cheng, X.; Ding, M. D.; Chen, P. F.; Sun, J. Q. E-mail: dmd@nju.edu.cn

    2015-05-10

    Type II radio bursts are thought to be a signature of coronal shocks. In this paper, we analyze a short-lived type II burst that started at 07:40 UT on 2011 February 28. By carefully checking white-light images, we find that the type II radio burst is not accompanied by a coronal mass ejection, only by a C2.4 class flare and narrow jet. However, in the EUV images provided by the Atmospheric Imaging Assembly on board the Solar Dynamics Observatory, we find a wave-like structure that propagated at a speed of ∼600 km s{sup −1} during the burst. The relationship between the type II radio burst and the wave-like structure is, in particular, explored. For this purpose, we first derive the density distribution under the wave by the differential emission measure method, which is used to restrict the empirical density model. We then use the restricted density model to invert the speed of the shock that produces the observed frequency drift rate in the dynamic spectrum. The inverted shock speed is similar to the speed of the wave-like structure. This implies that the wave-like structure is most likely a coronal shock that produces the type II radio burst. We also examine the evolution of the magnetic field in the flare-associated active region and find continuous flux emergence and cancellation taking place near the flare site. Based on these facts, we propose a new mechanism for the formation of the type II radio burst, i.e., the expansion of the strongly inclined magnetic loops after reconnecting with a nearby emerging flux acts as a piston to generate the shock wave.

  10. Interaction of mid-latitude air masses with the polar dome area during RACEPAC and NETCARE

    NASA Astrophysics Data System (ADS)

    Bozem, Heiko; Hoor, Peter; Koellner, Franziska; Kunkel, Daniel; Schneider, Johannes; Schulz, Christiane; Herber, Andreas; Borrmann, Stephan; Wendisch, Manfred; Ehrlich, Andre; Leaitch, Richard; Willis, Megan; Burkart, Julia; Thomas, Jennie; Abbatt, Jon

    2016-04-01

    We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories as well as Flexpart particle dispersion modeling we analyze the transport regimes of mid-latitude air masses traveling to the high Arctic prevalent during spring (RACEPAC 2014, NETCARE 2015) and summer (NETCARE 2014). In general more northern parts of the high Arctic (Lat > 75°N) were relatively unaffected from mid-latitude air masses. In contrast, regions further south are influenced by air masses from Asia and Russia (eastern part of Canadian Arctic and European Arctic) as well as from North America (central and western parts of Canadian Arctic). The transition between the mostly isolated high Arctic and more southern regions indicated by tracer gradients is remarkably sharp. This allows for a chemical definition of the Polar dome based on the variability of CO and CO2 as a marker. Isentropic surfaces that slope from the surface to higher altitudes in the high Arctic form the polar dome that represents a transport barrier for mid-latitude air masses to enter the lower troposphere in the high Arctic. Synoptic-scale weather systems frequently disturb this transport barrier and foster the exchange between air masses from the mid-latitudes and polar regions. This can finally lead to enhanced pollution levels in the lower polar troposphere. Mid-latitude pollution plumes from biomass burning or flaring entering the polar dome area lead to an enhancement of 30% of the observed CO mixing ratio within the polar dome area.

  11. Total-reflection X-ray fluorescence — a tool to obtain information about different air masses and air pollution

    NASA Astrophysics Data System (ADS)

    Schmeling, Martina

    2001-11-01

    Atmospheric aerosols are solid particles dissolved in air and change their chemical composition frequently depending on various parameters. In order to identify regional air circulation atmospheric aerosol filter samples were taken at Loyola University Chicago's Lake Shore Campus during the months of July and August 2000 with sampling times ranging between 1 and 2 h. The samples were digested in a microwave oven and analyzed by total-reflection X-ray fluorescence (TXRF) spectrometry. One diurnal variation comprising five consecutive sampling events was selected and discussed as well as 4 days experiencing different meteorology were compared to exemplify the variation in trace elemental concentration according to air mass movements and highlight the capability of total-reflection X-ray fluorescence analysis. It was found that due to changes in meteorological conditions particularly wind direction and wind speed, trace elemental compositions varied rapidly and could be used to distinguish between 'Lake Michigan air' and 'metropolitan Chicago air' on such short-term time scale like one hour. Back trajectory analysis was applied to support and corroborate the results. The outcome of this study clearly shows that total-reflection X-ray fluorescence is an optimal tool for analysis of atmospheric aerosols.

  12. The Use of Red Green Blue (RGB) Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Zavodsky, Bradley; Molthan, Andrew; Jedlovec, Gary

    2013-01-01

    AIRS ozone and model PV analysis confirm the stratospheric air in RGB Air Mass imagery. Trajectories confirm winds south of the low were distinct from CCB driven winds. Cross sections connect the tropopause fold, downward motion, and high nearsurface winds. Comparison to conceptual models show Shapiro-Keyser features and sting jet characteristics were observed in a storm that impacted the U.S. East Coast. RGB Air Mass imagery can be used to identify stratospheric air and regions susceptible to tropopause folding and attendant non-convective winds.

  13. On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2013-02-01

    Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

  14. On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2014-02-01

    Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

  15. Coronas Mass Ejections, Shocks, and Type II Radio Bursts

    NASA Technical Reports Server (NTRS)

    Gopalswamy, Natchimuthuk

    2010-01-01

    Coronal mass ejections (CMEs) are the most energetic phenomena in the interplanetary medium. Type II radio bursts are the earliest indicators of particle acceleration by CME-driven shocks. There is one-to-one correspondence between large solar energetic particle (SEP) events and long wavelength type II bursts because the same CME-driven shock is supposed to accelerate electrons and ions. However, there are some significant deviations: some CMEs lacking type II bursts (radio-quiet or RQ CMEs) are associated with small SEP events while some radioloud (RL) CMEs are not associated with SEP events, suggesting subtle differences in the acceleration of electrons and protons. Not all CME-driven shocks are radio loud: more than one third of the interplanetary shocks during solar cycle 23 were radio quiet. Some RQ shocks were associated with energetic storm particle (ESP) events, which are detected when the shocks arrive at the observing spacecraft. This paper attempts to explain these contradictory results in terms of the properties of CMEs, shocks, and the ambient medium.

  16. Technical note: Air compared to nitrogen as nebulizing and drying gases for electrospray ionization mass spectrometry.

    PubMed

    Mielczarek, P; Silberring, J; Smoluch, M

    2016-01-01

    In the present study we tested the application of compressed air instead of pure nitrogen as the nebulizing and drying gas, and its influence on the quality of electrospray ionization (ESI) mass spectra. The intensities of the signals corresponding to protonated molecules were significantly (twice) higher when air was used. Inspection of signal-to-noise (S/N) ratios revealed that, in both cases, sensitivity was comparable. A higher ion abundance after the application of compressed air was followed by a higher background. Another potential risk of using air in the ESI source is the possibility for sample oxidation due to the presence of oxygen. To test this, we selected five easily oxidizing compounds to verify their susceptibility to oxidation. In particular, the presence of methionine was of interest. For all the compounds studied, no oxidation was observed. Amodiaquine oxidizes spontaneously in water solutions and its oxidized form can be detected a few hours after preparation. Direct comparison of the spectra where nitrogen was used with the corresponding spectra obtained when air was applied did not show significant differences. The only distinction was slightly different patterns of adducts when air was used. The difference concerns acetonitrile, which forms higher signals when air is the nebulizing gas. It is also important that the replacement of nitrogen with air does not affect quantitative data. The prepared calibration curves also visualize an intensity twice as high (independent of concentration within tested range) of the signal where air was applied. We have used our system continuously for three months with air as the nebulizing and drying gas and have not noticed any unexpected signal deterioration caused by additional source contamination from the air. Moreover, compressed air is much cheaper and easily available using oil-free compressors or pumps.

  17. Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

    PubMed

    Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

    2007-10-01

    A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented.

  18. Gas diffusion-type oxygen electrode using perovskite-type oxides for metal-air batteries

    SciTech Connect

    Hyodo, Takeo; Miura, Norio; Yamazoe, Noboru

    1995-12-31

    In order to develop an air cathode of metal-air batteries, oxygen reduction behavior of gas diffusion-type carbon electrodes loaded with perovskite-type oxides, La{sub 1{minus}x}A{prime}{sub x}FeO{sub 3} (A{prime} = Ca, Sr, Ba, 0 {le} x {le} 1.0), was examined in 8 M KOH at 60 C. Among the oxide catalysts tested, La{sub 0.5}Sr{sub 0.5}FeO{sub 3} (specific surface area: 21.5 m{sup 2}{center_dot}g{sup {minus}1}) gave the highest electrode performance. On the basis of electrode reaction kinetics, H{sub 2}O{sub 2} decomposition rates, and temperature programmed desorption of oxygen, it was concluded that such a performance was attributable to the active sites of the oxide for the direct 4-electron reduction of oxygen. Moreover, the electrode using La{sub 0.5}Sr{sub 0.5}FeO{sub 3} was found to be rather stable in a short-term operation for 90 h at 300 mA{center_dot}cm{sup {minus}2}.

  19. The impact of Circulation Weather Types in Urban Air Quality in Portugal

    NASA Astrophysics Data System (ADS)

    Russo, Ana; Trigo, Ricardo

    2013-04-01

    It is now clear that emissions of the main air pollutants in Europe have declined significantly in recent decades (EEA, 2011). Nevertheless, many European countries (including Portugal) do not expect to comply with one (or more) pollutant emission ceilings and to air quality limit values, especially for particulate matter (PM), ground level ozone (O3) and nitrogen dioxide (NO2) (EEA, 2011). Consequently, and considering that air pollution (AP) plays a role as a major cause of human mortality and morbidity, exposure to pollutants remains a key environment-related health concern (EEA 2010). Thus, and to comply with the new limits, new strategies must be applied for air quality management. The main objective of this work is to present an objective classification of pre-defined and widely used CWTs affecting Portugal and, based on the most relevant patterns, provide a framework that is useful to characterise the occurrence of pollution episodes, namely its inter-annual and intra-annual variability, as well as the occurrence of extreme events. CWTs were determined using the simple Geostrophic approximation according to the methodology proposed by Trigo and DaCamara (2000). The interannual variability of the resulting CWTs was determined for the period with AP data (2002-2010) and the number of days for each CWT and season for the same period was accounted for. During this period, the most frequent CWTs were found to be the anticyclonic (A), the north (N) and the northeast (NE) types, accounting respectively for 34.7%, 10.9% and 14% of the days. However, higher-than average episodes tend to occur associated predominantly with situations characterized by a few less frequent CWTs, namely easterly (E), northeasterly (NE) and southeasterly (SE) types (that together contributed to less than one fourth of all observed days), are the ones which are associated to higher median and maximum concentrations of the three pollutants. Results obtained highlight the existence of strong

  20. Detection of Hydrazine in Air Using Electron Transfer Ionization Mass Spectrometry.

    DTIC Science & Technology

    1981-02-15

    is in tI qualitative agreement with American Petroleum Institute (API) 6 data. Unequivocal identification and monitoring of N2H4 fuels at the launch...N2H4 in air. At even lower concentrations, the delay time 61ndex of Mass Spectral Data, American Petroleum Institute , Research Project 44, NBS

  1. Toward a better understanding of the impact of mass transit air pollutants on human health

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Modern mass transit systems, based on roads, rail, water, and air, generate toxic airborne pollutants throughout the developed world. This has become one of the leading concerns about the use of modern transportation, particularly in densely-populated urban areas where their use is enormous and inc...

  2. New air Cherenkov light detectors to study mass composition of cosmic rays with energies above knee region

    NASA Astrophysics Data System (ADS)

    Tsunesada, Yoshiki; Katsuya, Ryoichi; Mitsumori, Yu; Nakayama, Keisuke; Kakimoto, Fumio; Tokuno, Hisao; Tajima, Norio; Miranda, Pedro; Salinas, Juan; Tavera, Wilfredo

    2014-11-01

    We have installed a hybrid detection system for air showers generated by cosmic rays with energies greater than 3 ×1015 eV at Mount Chacaltaya (5200 m above the sea level), in order to study the mass composition of cosmic rays above the knee region. This detection system comprises an air shower array with 49 scintillation counters in an area of 500 m×650 m, and seven new Cherenkov light detectors installed in a radial direction from the center of the air shower array with a separation of 50 m. It is known that the longitudinal development of a particle cascade in the atmosphere strongly depends on the type of the primary nucleus, and an air shower initiated by a heavier nucleus develops faster than that by a lighter primary of the same energy, because of the differences in the interaction cross-section and the energy per nucleon. This can be measured by detecting the Cherenkov radiation emitted from charged particles in air showers at higher altitudes. In this paper we describe the design and performance of our new non-imaging Cherenkov light detectors at Mount Chacaltaya that are operated in conjunction with the air shower array. The arrival directions and energies of air showers are determined by the shower array, and information about the primary masses is obtained from the Cherenkov light data including the time profiles and lateral distributions. The detector consists of photomultiplier tube (PMT), high-speed ADCs, other control modules, and data storage device. The Cherenkov light signals from an air shower are typically 10-100 ns long, and the waveforms are digitized with a sampling frequency of 1 GHz and recorded in situ without long-distance analog signal transfers. All the Cherenkov light detectors record their time-series data by receiving a triggering signal transmitted from the trigger module of the air shower array, which is fired by a coincidence of shower signals in four neighboring scintillation counters. The optical characteristics of the

  3. Air mass 1.5 global and direct solar simulation and secondary reference cell calibration using a filtered large area pulsed solar simulator

    NASA Technical Reports Server (NTRS)

    Mueller, Robert L.

    1985-01-01

    Spectral mismatch between a solar simulator and a desired spectrum can result in nearly 20 percent measurement error in the output of photovoltaic devices. This occurs when a crystalline silicon cell monitors the intensity of an unfiltered large area pulsed solar simulator (LAPSS) simulating the ASTM air mass 1.5 direct spectrum and the test device is amorphous silicon. The LAPSS spectral irradiance is modified with readily available glass UV filters to closely match either the ASTM air mass 1.5 direct or global spectrum. Measurement error is reduced to about 1 percent when using either filter if the reference cell and test device are the same general type.

  4. Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

    NASA Technical Reports Server (NTRS)

    Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Grant, William B.; Ismail, Syed; Ferrare, Richard A.; Kooi, Susan A.; Brackett, Vincent G.; Clayton, Marian B.; Avery, Melody A.

    2001-01-01

    Eighteen long-range flights over the Pacific Ocean between 38 S to 20 N and 166 E to 90 W were made by the NASA DC-8 aircraft during the NASA Pacific Exploratory Mission (PEM) Tropics B conducted from March 6 to April 18, 1999. Two lidar systems were flown on the DC-8 to remotely measure vertical profiles of ozone (O3), water vapor (H2O), aerosols, and clouds from near the surface to the upper troposphere along their flight track. In situ measurements of a wide range of gases and aerosols were made on the DC-8 for comprehensive characterization of the air and for correlation with the lidar remote measurements. The transition from northeasterly flow of Northern Hemispheric (NH) air on the northern side of the Intertropical Convergence Zone (ITCZ) to generally easterly flow of Southern Hemispheric (SH) air south of the ITCZ was accompanied by a significant decrease in O3, carbon monoxide, hydrocarbons, and aerosols and an increase in H2O. Trajectory analyses indicate that air north of the ITCZ came from Asia and/or the United States, while the air south of the ITCZ had a long residence time over the Pacific, perhaps originating over South America several weeks earlier. Air south of the South Pacific Convergence Zone (SPCZ) came rapidly from the west originating over Australia or Africa. This air had enhanced O3 and aerosols and an associated decrease in H2O. Average latitudinal and longitudinal distributions of O3 and H2O were constructed from the remote and in situ O3 and H2O data, and these distributions are compared with results from PEM-Tropics A conducted in August-October 1996. During PEM-Tropics B, low O3 air was found in the SH across the entire Pacific Basin at low latitudes. This was in strong contrast to the photochemically enhanced O3 levels found across the central and eastern Pacific low latitudes during PEM-Tropics A. Nine air mass types were identified for PEM-Tropics B based on their O3, aerosols, clouds, and potential vorticity characteristics. The

  5. Low-CCN concentration air masses over the eastern North Atlantic: Seasonality, meteorology, and drivers

    NASA Astrophysics Data System (ADS)

    Wood, Robert; Stemmler, Jayson D.; Rémillard, Jasmine; Jefferson, Anne

    2017-01-01

    A 20 month cloud condensation nucleus concentration (NCCN) data set from Graciosa Island (39°N, 28°W) in the remote North Atlantic is used to characterize air masses with low cloud condensation nuclei (CCN) concentrations. Low-CCN events are defined as 6 h periods with mean NCCN<20 cm-3 (0.1% supersaturation). A total of 47 low-CCN events are identified. Surface, satellite, and reanalysis data are used to explore the meteorological and cloud context for low-CCN air masses. Low-CCN events occur in all seasons, but their frequency was 3 times higher in December-May than during June-November. Composites show that many of the low-CCN events had a common meteorological basis that involves southerly low-level flow and rather low wind speeds at Graciosa. Anomalously low pressure is situated to the west of Graciosa during these events, but back trajectories and lagged SLP composites indicate that low-CCN air masses often originate as cold air outbreaks to the north and west of Graciosa. Low-CCN events were associated with low cloud droplet concentrations (Nd) at Graciosa, but liquid water path (LWP) during low-CCN events was not systematically different from that at other times. Satellite Nd and LWP estimates from MODIS collocated with Lagrangian back trajectories show systematically lower Nd and higher LWP several days prior to arrival at Graciosa, consistent with the hypothesis that observed low-CCN air masses are often formed by coalescence scavenging in thick warm clouds, often in cold air outbreaks.

  6. Constraining aerosol optical models using ground-based, collocated particle size and mass measurements in variable air mass regimes during the 7-SEAS/Dongsha experiment

    NASA Astrophysics Data System (ADS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Hsu, N. Christina; Lin, Neng-Huei; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2013-10-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment (λ = 550 nm) for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulfate, nitrate, and elemental carbon. Achieving full optical closure is hampered by limitations in accounting for the role of water vapor in the system, uncertainties in the instruments and the need for further knowledge in the source apportionment of the model's major chemical components. Nonetheless, our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulfate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Consistency between the measured and modeled optical parameters serves as an

  7. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  8. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general.

  9. Turbulent heat and mass transfers across a thermally stratified air-water interface

    NASA Technical Reports Server (NTRS)

    Papadimitrakis, Y. A.; Hsu, Y.-H. L.; Wu, J.

    1986-01-01

    Rates of heat and mass transfer across an air-water interface were measured in a wind-wave research facility, under various wind and thermal stability conditions (unless otherwise noted, mass refers to water vapor). Heat fluxes were obtained from both the eddy correlation and the profile method, under unstable, neutral, and stable conditions. Mass fluxes were obtained only under unstable stratification from the profile and global method. Under unstable conditions the turbulent Prandtl and Schmidt numbers remain fairly constant and equal to 0.74, whereas the rate of mass transfer varies linearly with bulk Richardson number. Under stable conditions the turbulent Prandtl number rises steadily to a value of 1.4 for a bulk Richardson number of about 0.016. Results of heat and mass transfer, expressed in the form of bulk aerodynamic coefficients with friction velocity as a parameter, are also compared with field data.

  10. Measuring Air-water Interfacial Area for Soils Using the Mass Balance Surfactant-tracer Method

    PubMed Central

    Araujo, Juliana B.; Mainhagu, Jon; Brusseau, Mark L.

    2015-01-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. PMID:25950136

  11. Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

    NASA Technical Reports Server (NTRS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.; Schlager, H.; Atlas, E.; Blake, D.; Coe, H.; Cohen, R. C.; Crosier, J.; Flocke, F.; Holloway, J. S.; Hopkins, J. R.; Huber, G.; McQuaid, J.; Purvis, R.; Rappengluck, B.; Ryerson, T. B.; Sachse, G. W.

    2006-01-01

    The International Consortium for Atmospheric Research on Transport and Transformation (ICARTT)-Lagrangian experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts using two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique is then used to identify Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these coincident matches is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown and the downwind minus upwind differences in tracers are discussed.

  12. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    USGS Publications Warehouse

    Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

    2002-01-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  13. Source areas and trajectories of nucleating air masses within and near the Carpathian Basin

    NASA Astrophysics Data System (ADS)

    Németh, Z.; Salma, I.

    2014-04-01

    Particle number size distributions were measured by differential mobility particle sizer in the diameter range of 6-1000 nm in the near-city background and city centre of Budapest continuously for two years. The city is situated in the middle part of the Carpathian Basin, which is a topographically discrete unit in the southeast Central Europe. Yearly mean nucleation frequencies and uncertainties for the near-city background and city centre were (28+6/-4) % and (27+9/-4) %, respectively. Total numbers of days with continuous and uninterrupted growth process were 43 and 31, respectively. These events and their properties were utilised to investigate if there are any specific tracks and/or separable source regions for the nucleating air masses within or near the basin. Local wind speed and direction data indicated that there seem to be differences between the nucleation and growth intervals and non-nucleation days. For further analysis, backward trajectories were generated by a simple air parcel trajectory model. Start and end time parameters of the nucleation, and end time parameter of the particle growth were derived by a standardized procedure based on examining the channel contents of the contour plots. These parameters were used to specify a segment on each air mass trajectory that is associated with the track of the nucleating air mass. The results indicated that the nucleation events happened in the continental boundary layer mostly within the Carpathian Basin but the most distant trajectories originated outside of the basin. The tracks of the nucleating air masses were predominantly associated with NW and SE geographical fields, while the source areas that could be separated were frequently situated in the NW and NE quarters. Many of them were within or close to large forested territories. The results also emphasize that the new particle formation and growth phenomenon that occurs in the region influences larger territories than the Carpathian Basin.

  14. Seasonal air and water mass redistribution effects on LAGEOS and Starlette

    NASA Technical Reports Server (NTRS)

    Gutierrez, Roberto; Wilson, Clark R.

    1987-01-01

    Zonal geopotential coefficients have been computed from average seasonal variations in global air and water mass distribution. These coefficients are used to predict the seasonal variations of LAGEOS' and Starlette's orbital node, the node residual, and the seasonal variation in the 3rd degree zonal coefficient for Starlette. A comparison of these predictions with the observed values indicates that air pressure and, to a lesser extent, water storage may be responsible for a large portion of the currently unmodeled variation in the earth's gravity field.

  15. Characterization of key aerosol, trace gas and meteorological properties and particle formation and growth processes dependent on air mass origins in coastal Southern Spain

    NASA Astrophysics Data System (ADS)

    Diesch, J.; Drewnick, F.; Sinha, V.; Williams, J.; Borrmann, S.

    2011-12-01

    The chemical composition and concentration of aerosols at a certain site can vary depending on season, the air mass source region and distance from sources. Regardless of the environment, new particle formation (NPF) events are one of the major sources for ultrafine particles which are potentially hazardous to human health. Grown particles are optically active and efficient CCN resulting in important implications for visibility and climate (Zhang et al., 2004). The study presented here is intended to provide information about various aspects of continental, urban and marine air masses reflected by wind patterns of the air arriving at the measurement site. Additionally we will be focusing on NPF events associated with different types of air masses affecting their emergence and temporal evolution. Measurements of the ambient aerosol, various trace gases and meteorological parameters were performed within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from mid-November to mid-December 2008 at the atmospheric research station "El Arenosillo" located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean. Number and mass as well as PAH and black carbon concentrations were measured in PM1 and size distribution instruments covered the size range 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (AMS). In order to evaluate the characteristics of different air masses linking local and regional sources as well as NPF processes, characteristic air mass types were classified dependent on backwards trajectory pathways and local meteorology. Large nuclei mode concentrations in the number size distribution were found within continental and urban influenced air mass types due to frequently occurring NPF events. Exploring individual production and sink variables, sulfuric

  16. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  17. Mixing of stratospheric and tropospheric air-masses detected with CRISTA-NF during AMMA

    NASA Astrophysics Data System (ADS)

    Weigel, K.; Guenther, G.; Hoffmann, L.; Konopka, P.; Riese, M.

    2009-04-01

    CRISTA-NF (CRyogenic Infrared Spectrometers and Telescopes for the Atmosphere - New Frontiers) is an infrared limb sounding instrument installed onbord the high-flying research aircraft M55-Geophysica and took part in the AMMA-SCOUT measurement campaign in Summer 2006. During the test flight on 29th of July 2006, CRISTA-NF detected a sharp boundary between ozone rich air over northernItaly and ozone poor air over southern Italy and the Mediterranean Sea. The structure is also clearly visible in the HNO3 distribution. The air mass boundary extends from about 10km altitude to the thermal tropopause at about 16km altitude with indication for mixing in the lower part of this altitude range. This is supported by enhanced values of PAN and water vapour found. The observed structure is also visible in the CLaMS (Chemical Lagrangian Model of the Stratosphere) ozone distribution but hardly resolved in ECMWF forecast data. Backward trajectories show that the ozone rich air is originated westwards, between 40 and 60oN while the ozone poor air is coming from the south-east, at about 0-20oN and has a younger age of air. In the presentation details of the CRISTA-NF measurements and retrieval procedures as well as the origin of the trace gas structures will be discussed.

  18. Variations of the glacio-marine air mass front in West Greenland through water vapor isotopes

    NASA Astrophysics Data System (ADS)

    Kopec, B. G.; Lauder, A. M.; Posmentier, E. S.; Feng, X.

    2012-12-01

    While the isotopic distribution of precipitation has been widely used for research in hydrology, paleoclimatology, and ecology for decades, intensive isotopic studies of atmospheric water vapor has only recently been made possible by spectral-based technology. New instrumentation based on this technology opens up many opportunities to investigate short-term atmospheric dynamics involving the water cycle and moisture transport. We deployed a Los Gatos Water Vapor Isotope Analyzer (WVIA) at Kangerlussuaq, Greenland from July 21 to August 15, and measured the water vapor concentration and its isotopic ratios continuously at 10s intervals. A Danish Meteorological Institute site is located about 1 km from the site of the deployment, and meteorological data is collected at 30 min intervals. During the observation period, the vapor concentration of the ambient air ranges from 5608.4 to 11189.4 ppm; dD and d18O range from -254.5 to -177.7 ‰ and -34.2 to -23.2 ‰, respectively. The vapor content (dew point) and the isotopic ratios are both strongly controlled by the wind direction. The easterly winds are associated with dry, isotopically depleted air masses formed over the glacier, while westerly winds are associated with moist and isotopically enriched air masses from the marine/fjord surface. This region typically experiences katabatic winds off of the ice sheet to the east. However, during some afternoons, the wind shifts 180 degrees, blowing off the fjord to the west. This wind switch marks the onset of a sea breeze, and significant isotopic enrichment results. Enrichment in deuterium is up to 60 ‰ with a mean of 15‰, and oxygen-18 is enriched by 3‰ on average and up to 8 ‰. Other afternoons have no change in wind, and only small changes in humidity and vapor isotopic ratios. The humidity and isotopic variations suggest the local atmosphere circulation is dominated by relatively high-pressure systems above the cold glaciers and cool sea surface, and diurnal

  19. Overview of aerosol properties associated with air masses sampled by the ATR-42 during the EUCAARI campaign (2008)

    NASA Astrophysics Data System (ADS)

    Crumeyrolle, S.; Schwarzenboeck, A.; Sellegri, K.; Burkhart, J. F.; Stohl, A.; Gomes, L.; Quennehen, B.; Roberts, G.; Weigel, R.; Roger, J. C.; Villani, P.; Pichon, J. M.; Bourrianne, T.; Laj, P.

    2012-04-01

    Within the frame of the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) project the Météo-France aircraft ATR-42 performed 22 research flights, over central Europe and the North Sea during the intensive observation period in May 2008. For the campaign, the ATR-42 was equipped in order to study aerosol physical, chemical and optical properties, as well as cloud microphysics. During the campaign, continental air masses from Eastern and Western Europe were encountered, along with polar and Scandinavian air masses. For the 22 research flights, retroplume analyses along the flight tracks were performed with FLEXPART in order to classify air masses into five sectors of origin which allows for a qualitative evaluation of emission influence on the respective air parcel. In the polluted boundary layer (BL), typical concentrations of particles with diameters larger than 10 nm (N10) are of the order of 5000-6000 cm-3, whereas N10 concentrations of clean air masses were lower than 1300 cm-3. The detection of the largest particle number concentrations occurred in air masses coming from Polar and Scandinavian regions for which an elevated number of nucleation mode (25-28 nm) particles was observed and attributed to new particle formation over open sea. In the free troposphere (FT), typical observed N10 are of the order of 900 cm-3 in polluted air masses and 400-600 cm-3 in clean air masses, respectively. In both layers, the chemical composition of submicron aerosol particles is dominated by organic matter and nitrate in polluted air masses, while, sulphate and ammonium followed by organics dominate the submicron aerosols in clean air masses. The highest CCN/CN ratios were observed within the polar air masses while the CCN concentration values are the highest within the polluted air masses. Within the five air mass sectors defined and the two layers (BL and FT), observations have been distinguished into anticyclonic (first half of May 2008) and cyclonic

  20. Enhancement of acidic gases in biomass burning impacted air masses over Canada

    NASA Technical Reports Server (NTRS)

    Lefer, B. L.; Talbot, R. W.; Harriss, R. C.; Bradshaw, J. D.; Sandholm, S. T.; Olson, J. O.; Sachse, G. W.; Collins, J.; Shipham, M. A.; Blake, D. R.

    1994-01-01

    Biomass-burning impacted air masses sampled over central and eastern Canada during the summer of 1990 as part of ABLE 3B contained enhanced mixing ratios of gaseous HNO3, HCOOH, CH3COOH, and what appears to be (COOH)2. These aircraft-based samples were collected from a variety of fresh burning plumes and more aged haze layers from different source regions. Values of the enhancement factor, delta X/delta CO, where X represents an acidic gas, for combustion-impacted air masses sampled both near and farther away from the fires, were relatively uniform. However, comparison of carboxylic acid emission ratios measured in laboratory fires to field plume enhancement factors indicates significant in-plume production of HCOOH. Biomass-burning appears to be an important source of HNO3, HCOOH, and CH3COOH to the troposphere over subarctic Canada.

  1. Ozone and Trace Gas Trends in the UK and Links to Changing Air Mass Pathways

    NASA Astrophysics Data System (ADS)

    Fleming, Z.; Monks, P. S.; Reeves, C.; Bohnenstengel, S.

    2014-12-01

    Trace gas measurements from UK measurement sites on the North Sea coast and in central London reveal a complicated relationship between NO2, CO, hydrocarbons and ozone. Due to the location of the sites, they receive air masses from the UK, Europe, the North sea, Scandinavia and the Arctic and Atlantic Seas and any seasonality is hard to discern. The transport pathway of air masses that can change on an hourly timescale clearly influences the trace gas levels. Investigations into how the transport pathways have changed over the years, using the NAME dispersion model try to elucidate whether it is the 'where' (transport pathway) or the 'what' (trace gas emissions) that is leading to the ozone trends recorded over the past few years.

  2. Toward a better understanding of the impact of mass transit air pollutants on human health.

    PubMed

    Kim, Ki-Hyun; Kumar, Pawan; Szulejko, Jan E; Adelodun, Adedeji A; Junaid, Muhammad Faisal; Uchimiya, Minori; Chambers, Scott

    2017-05-01

    Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments.

  3. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  4. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    NASA Astrophysics Data System (ADS)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  5. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  6. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity.

    PubMed

    Bugbee, B; Monje, O; Tanner, B

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  7. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    NASA Technical Reports Server (NTRS)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  8. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    NASA Astrophysics Data System (ADS)

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-04-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2- and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios.

  9. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    PubMed Central

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2− and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  10. Foliage response of young central European oaks to air warming, drought and soil type.

    PubMed

    Günthardt-Goerg, M S; Kuster, T M; Arend, M; Vollenweider, P

    2013-01-01

    Three Central European oak species, with four provenances each, were experimentally tested in 16 large model ecosystem chambers for their response to passive air warming (AW, ambient +1-2 °C), drought (D, -43 to -60% irrigation) and their combination (AWD) for 3 years on two forest soil types of pH 4 or 7. Throughout the entire experiment, the influence of the different ambient and experimental climates on the oak trees was strong. The morphological traits of the Quercus species were affected in opposing ways in AW and D treatments, with a neutral effect in the AWD treatment. Biochemical parameters and LMA showed low relative plasticity compared to the morphological and growth parameters. The high plasticity in physiologically important parameters of the three species, such as number of intercalary veins or leaf size, indicated good drought acclimation properties. The soil type influenced leaf chlorophyll concentration, C/N and area more than drought, whereas foliage mass was more dependent on drought than on soil type. Through comparison of visible symptom development with the water deficits, a drought tolerance threshold of -1.3 MPa was determined. Although Q. pubescens had xeromorphic leaf characteristics (small leaf size, lower leaf water content, high LMA, pilosity, more chlorophyll, higher C/N) and less response to the treatments than Q. petraea and Q. robur, it suffered more leaf drought injury and shedding of leaves than Q. petraea. However, if foliage mass were used as the criterion for sustainable performance under a future climate, Q. robur would be the most appropriate species.

  11. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with continental, urban and marine air masses at the SW Atlantic coast of Iberia

    NASA Astrophysics Data System (ADS)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2011-12-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions could be identified in the particle phase. In all

  12. PMF receptor modelling of fine and coarse PM 10 in air masses governing monsoon conditions in Hanoi, northern Vietnam

    NASA Astrophysics Data System (ADS)

    Hien, P. D.; Bac, V. T.; Thinh, N. T. H.

    Fine and coarse PM 10 samples collected in Hanoi in 1999-2001 were analysed for black carbon (BC) and water soluble ions (WSI) and measured data were disaggregated according to three types of back trajectories, namely (1) northerly, over inland China, (2) northeasterly, over East China Sea and, (3) southwesterly over Indochina peninsula. Trajectories of types 1, 2 and 3 prevail in September/October-December, January-March/April and May-August, respectively. A source-receptor modelling was performed for each type of trajectories individually using the Positive Matrix Factorisation (PMF) technique. Six or seven sources were extracted for each trajectory type, including soil dust, primary and secondary emissions from local burning (LB), vehicle/road dust, sea salt, Cl-depleted marine aerosols and long-range transport (LRT). LRT contributes little to the coarse mass, but accounts for 50%, 34% and 33% of the fine mass in trajectories of types 1, 2 and 3, respectively. More than two-thirds of the fine mode sulphate are attributed to LRT and associated with ammonium. The comparison of LRT and LB source profiles suggests that air masses arriving from north-northeasterly trajectories are more polluted than those coming from the southwest. Therefore the contribution of LRT's aerosols further enhances the seasonal contrast in the particulate concentration with maximum in winter and minimum in summer. Various mechanisms of sulphate formation in LRT and LB were suggested based on the concentration ratios of [SO 42-]/[K +], [SO 42-]/[BC] and [NH 4+]/[SO 42-] for the two sources.

  13. Determination of benzene at trace levels in air by a novel method based on solid-phase microextraction gas chromatography/mass spectrometry.

    PubMed

    Saba, A; Cuzzola, A; Raffaelli, A; Pucci, S; Salvadori, P

    2001-01-01

    A new method for the determination of benzene at trace levels in air is presented. The method consists of the collection of air samples on adsorbent cartridges with simultaneous adsorption of pre-established amounts of D6-labeled internal standard. Desorption from the cartridge is performed by solid-phase microextraction (SPME) with analysis by gas chromatography/mass spectrometry (GC/MS) using an ion trap mass spectrometer. The influence of several parameters (type of SPME fiber, temperature, time, for example) was investigated, and good linearity in the range 10-400 ng of C6D6, with a coefficient of variance (CV) around 3-5%, was obtained. The method was tested by sampling air in a town center in Italy, and a benzene concentration of approximately 50 microg/m(3) was determined. The maximum limit recommended by the European Community is 10 microg/m(3).

  14. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2016-10-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  15. Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

    NASA Astrophysics Data System (ADS)

    Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

    2015-10-01

    We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

  16. 42 CFR 84.143 - Terminal fittings or chambers; Type B supplied-air respirators; minimum requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Terminal fittings or chambers; Type B supplied-air... RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.143 Terminal fittings or chambers; Type B... positive pressures shall not be approved for use on Type B supplied-air respirators. (b) Terminal...

  17. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  18. Development of a large support surface for an air-bearing type zero-gravity simulator

    NASA Technical Reports Server (NTRS)

    Glover, K. E.

    1976-01-01

    The methods used in producing a large, flat surface to serve as the supporting surface for an air-bearing type zero-gravity simulator using low clearance, thrust-pad type air bearings are described. Major problems encountered in the use of self-leveled epoxy coatings in this surface are discussed and techniques are recommended which proved effective in overcoming these problems. Performance requirements of the zero-gravity simulator vehicle which were pertinent to the specification of the air-bearing support surface are also discussed.

  19. Influence of air mass origin on aerosol properties at a remote Michigan forest site

    NASA Astrophysics Data System (ADS)

    VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; Pressley, S. N.; Erickson, M. H.; Jobson, B. T.; Lamb, B. K.

    2015-04-01

    The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere-Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ∼60% of the study period, air was transported from sparsely populated regions to the northwest. During these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm-3 and 1.91 μm3 cm-3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (∼29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean k = 0.24 at s = 0.3%). These trends are have the potential to influence forest-atmosphere interactions and should be targeted for future study.

  20. Quantitative comparison of a flared and a standard heated metal capillary inlet with a voltage-assisted air amplifier on an electrospray ionization linear ion trap mass spectrometer.

    PubMed

    Dixon, R Brent; Muddiman, David C

    2007-01-01

    The performance characteristics (i.e., ion abundance and electrospray ion current) of a flared and blunt-ended heated metal capillary were evaluated with a voltage-assisted air amplifier on a linear ion trap mass spectrometer (LTQ-MS). The results demonstrated that a standard capillary afforded higher ion abundance than a flared capillary, thus further work is necessary to investigate conditions for which significant benefits with the flared capillary will be observed. The compatibility of a voltage-assisted air amplifier is explored for both types of capillaries and in all cases resulted in improved ion abundance and spray current.

  1. Quasi-perpetual discharge behaviour in p-type Ge-air batteries.

    PubMed

    Ocon, Joey D; Kim, Jin Won; Abrenica, Graniel Harne A; Lee, Jae Kwang; Lee, Jaeyoung

    2014-11-07

    Metal-air batteries continue to become attractive energy storage and conversion systems due to their high energy and power densities, safer chemistries, and economic viability. Semiconductor-air batteries - a term we first define here as metal-air batteries that use semiconductor anodes such as silicon (Si) and germanium (Ge) - have been introduced in recent years as new high-energy battery chemistries. In this paper, we describe the excellent doping-dependent discharge kinetics of p-type Ge anodes in a semiconductor-air cell employing a gelled KOH electrolyte. Owing to its Fermi level, n-type Ge is expected to have lower redox potential and better electronic conductivity, which could potentially lead to a higher operating voltage and better discharge kinetics. Nonetheless, discharge measurements demonstrated that this prediction is only valid at the low current regime and breaks down at the high current density region. The p-type Ge behaves extremely better at elevated currents, evident from the higher voltage, more power available, and larger practical energy density from a very long discharge time, possibly arising from the high overpotential for surface passivation. A primary semiconductor-air battery, powered by a flat p-type Ge as a multi-electron anode, exhibited an unprecedented full discharge capacity of 1302.5 mA h gGe(-1) (88% anode utilization efficiency), the highest among semiconductor-air cells, notably better than new metal-air cells with three-dimensional and nanostructured anodes, and at least two folds higher than commercial Zn-air and Al-air cells. We therefore suggest that this study be extended to doped-Si anodes, in order to pave the way for a deeper understanding on the discharge phenomena in alkaline metal-air conversion cells with semiconductor anodes for specific niche applications in the future.

  2. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 2

    NASA Technical Reports Server (NTRS)

    Hovel, H.; Woodall, J. M.

    1976-01-01

    Crystal growth procedures, fabrication techniques, and theoretical analysis were developed in order to make GaAlAs-GaAs solar cell structures which exhibit high performance at air mass 0 illumination and high temperature conditions.

  3. Calibration of Dissolved Noble Gas Mass Spectrometric Measurements by an Air-Water Equilibration System

    NASA Astrophysics Data System (ADS)

    Hillegonds, Darren; Matsumoto, Takuya; Jaklitsch, Manfred; Han, Liang-Feng; Klaus, Philipp; Wassenaar, Leonard; Aggarwal, Pradeep

    2013-04-01

    Precise measurements by mass spectrometry of dissolved noble gases (He, Ar, Ne, Kr, Xe) in water samples require careful calibration against laboratory standards with known concentrations. Currently, air pipettes are used for day-to-day calibrations, making estimation of overall analytical uncertainties for dissolved noble gas measurements in water difficult. Air equilibrated water (AEW) is often used as a matrix-equivalent laboratory standard for dissolved gases in groundwater, because of the well-known and constant fractions of noble gases in the atmosphere. AEW standards, however, are only useful if the temperature and pressure of the gas-water equilibrium can be controlled and measured precisely (i.e., to better than 0.5%); contamination and partial sample degassing must also be prevented during sampling. Here we present the details of a new custom air-water equilibration system which consists of an insulated 600 liter tank filled with deionized water, held isothermally at a precise target temperature (<0.05 °C) through the use of a heat exchanger. The temperature and total dissolved gas of the water in the tank are monitored continually, as are atmospheric pressure and air temperature in the laboratory. Different noble gas concentration standards can be reliably produced by accurately controlling the water temperature of the equilibration system. Equilibration characteristics and reproducibility of this system for production of copper tubes containing known amounts of noble gases will be presented.

  4. Determination of the effect of transfer between vacuum and air on mass standards of platinum-iridium and stainless steel

    NASA Astrophysics Data System (ADS)

    Davidson, Stuart

    2010-08-01

    This paper reports work undertaken to assess the change in the mass values of stainless steel and platinum-iridium weights transferred between air and vacuum and to determine the repeatability of this change. Sets of kilogram transfer standards, manufactured from stainless steel and platinum-iridium and with different surface areas, were used to determine the effect of transfer between air and vacuum on the values of the mass standards. The SI unit of mass is the only unit of the seven base SI quantities which is still defined in terms of an artefact rather than by relation to a fundamental physical constant. Work is underway to identify a means of deriving the SI unit of mass from fundamental constants and at present the two principal approaches are the International Avogadro Coordination and the watt balance projects. Both of these approaches involve realizing a kilogram in vacuum and therefore the traceability from a kilogram realized in vacuum to mass standards in air is crucial to the effective dissemination of the mass scale. The work reported here characterizes the changes in mass values of standards on transfer between air and vacuum and thus will enable traceability to be established for an in-air mass scale based on a definition of the unit in vacuum.

  5. The effect of long-range air mass transport pathways on PM10 and NO2 concentrations at urban and rural background sites in Ireland: Quantification using clustering techniques.

    PubMed

    Donnelly, Aoife A; Broderick, Brian M; Misstear, Bruce D

    2015-01-01

    The specific aims of this paper are to: (i) quantify the effects of various long range transport pathways nitrogen dioxide (NO2) and particulate matter with diameter less than 10μm (PM10) concentrations in Ireland and identify air mass movement corridors which may lead to incidences poor air quality for application in forecasting; (ii) compare the effects of such pathways at various sites; (iii) assess pathways associated with a period of decreased air quality in Ireland. The origin of and the regions traversed by an air mass 96h prior to reaching a receptor is modelled and k-means clustering is applied to create air-mass groups. Significant differences in air pollution levels were found between air mass cluster types at urban and rural sites. It was found that easterly or recirculated air masses lead to higher NO2 and PM10 levels with average NO2 levels varying between 124% and 239% of the seasonal mean and average PM10 levels varying between 103% and 199% of the seasonal mean at urban and rural sites. Easterly air masses are more frequent during winter months leading to higher overall concentrations. The span in relative concentrations between air mass clusters is highest at the rural site indicating that regional factors are controlling concentration levels. The methods used in this paper could be applied to assist in modelling and forecasting air quality based on long range transport pathways and forecast meteorology without the requirement for detailed emissions data over a large regional domain or the use of computationally demanding modelling techniques.

  6. Effect of the relative optical air mass and the clearness index on solar erythemal UV irradiance.

    PubMed

    Moreno, J C; Serrano, M A; Cañada, J; Gurrea, G; Utrillas, M P

    2014-09-05

    This paper analyses the effects of the clearness index (Kt) and the relative optical air mass (mr) on erythemal UV irradiance (UVER). The UVER measurements were made in Valencia (Spain) from 6:00 am to 6:00 pm between June 2003 and December 2012 and (140,000 data points). Firstly, two models were used to calculate values for the erythemal ultraviolet irradiance clearness index (KtUVER) as a function of the global irradiance clearness index (Kt). Secondly, a potential regression model to measure the KtUVER as a function of the relative optical air mass was studied. The coefficients of this regression were evaluated for clear and cloudy days, as well as for days with high and low ozone levels. Thirdly, an analysis was made of the relationship between the two effects in the experimental database, with it being found that the highest degree of agreement, or the joint highest frequencies, are located in the optical mass range mr∈[1.0, 1.2] and the clearness index range of Kt∈[0.8, 1.0]. This is useful for establishing the ranges of parameters where models are more efficient. Simple equations have been tested that can provide additional information for the engineering projects concerning thermal installations. Fourthly, a high dispersion of radiation data was observed for intermediate values of the clearness for UV and UVER.

  7. Visual Steering and Verification of Mass Spectrometry Data Factorization in Air Quality Research.

    PubMed

    Engel, D; Greff, K; Garth, C; Bein, K; Wexler, A; Hamann, B; Hagen, H

    2012-12-01

    The study of aerosol composition for air quality research involves the analysis of high-dimensional single particle mass spectrometry data. We describe, apply, and evaluate a novel interactive visual framework for dimensionality reduction of such data. Our framework is based on non-negative matrix factorization with specifically defined regularization terms that aid in resolving mass spectrum ambiguity. Thereby, visualization assumes a key role in providing insight into and allowing to actively control a heretofore elusive data processing step, and thus enabling rapid analysis meaningful to domain scientists. In extending existing black box schemes, we explore design choices for visualizing, interacting with, and steering the factorization process to produce physically meaningful results. A domain-expert evaluation of our system performed by the air quality research experts involved in this effort has shown that our method and prototype admits the finding of unambiguous and physically correct lower-dimensional basis transformations of mass spectrometry data at significantly increased speed and a higher degree of ease.

  8. Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Shirley, John A.; Winter, Michael

    1993-01-01

    An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

  9. Simulation du fonctionnement de capteurs solaires à air de type tôle et de type absorbeur poreux

    NASA Astrophysics Data System (ADS)

    Fournier, Michel; Maurissen, Yves

    1993-12-01

    The comparison between air-heated insolators, no porous and porous plate, often has been made experimentaly. The behaviour model of these insolators permit generalization of the study in the conditions where each insolator is the most performant. La comparaison des capteurs solaires à air à absorbeur de type tôle et de type poreux a été abordée le plus souvent de façon expérimentale. La modélisation du fonctionnement de ces types de capteur permet de généraliser cette comparaison et de définir les domaines de fonctionnement où un type de capteur se montre plus efficace que l'autre.

  10. Ozone Modulation/Membrane Introduction Mass Spectrometry for Analysis of Hydrocarbon Pollutants in Air

    NASA Astrophysics Data System (ADS)

    Atkinson, D. B.

    2001-12-01

    Modulation of volatile hydrocarbons in two-component mixtures is demonstrated using an ozonolysis pretreatment with membrane introduction mass spectrometry (MIMS). The MIMS technique allows selective introduction of volatile and semivolatile analytes into a mass spectrometer via processes known collectively as pervaporation [Kotiaho and Cooks, 1992]. A semipermeable polymer membrane acts as an interface between the sample (vapor or solution) and the vacuum of the mass spectrometer. This technique has been demonstrated to allow for sensitive analysis of hydrocarbons and other non-polar volatile organic compounds (VOC`s) in air samples[Cisper et al., 1995] . The methodology has the advantages of no sample pretreatment and short analysis time, which are promising for online monitoring applications but the chief disadvantage of lack of a separation step for the different analytes in a mixture. Several approaches have been investigated to overcome this problem including use of selective chemical ionization [Bier and Cooks, 1987] and multivariate calibration techniques[Ketola et al., 1999] . A new approach is reported for the quantitative measurement of VOCs in complex matrices. The method seeks to reduce the complexity of mass spectra observed in hydrocarbon mixture analysis by selective pretreatment of the analyte mixture. In the current investigation, the rapid reaction of ozone with alkenes is used, producing oxygenated compounds which are suppressed by the MIMS system. This has the effect of removing signals due to unsaturated analytes from the compound mass spectra, and comparison of the spectra before and after the ozone treatment reveals the nature of the parent compounds. In preliminary investigations, ozone reacted completely with cyclohexene from a mixture of cylohexene and cyclohexane, and with β -pinene from a mixture of toluene and β -pinene, suppressing the ion signals from the olefins. A slight attenuation of the cyclohexane and toluene in those

  11. Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

    NASA Astrophysics Data System (ADS)

    Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

    2015-04-01

    While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

  12. Does energy of type IIP supernovae depend on progenitor mass?

    NASA Astrophysics Data System (ADS)

    Chugai, Nikolai

    The oxygen [O I] 6300 A emission doublet, seen in nebular spectra of core-collapse supernovae, is used to obtain oxygen density in central zone of a sample of SN IIP. The inferred values of the oxygen density on day 300 turn out to fall into rather narrow range. This result does not depend on the distance, extinction, or model assumptions. The found density distribution led us to conclude that the SN IIP explosion energy monotonically increases with the progenitor mass.

  13. Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

    PubMed

    Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

    2014-01-01

    A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future.

  14. 7 CFR 30.38 - Class 3; air-cured types and groups.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ..., and length of Class 3, Type 31, air-cured tobacco, but which is a low-nicotine strain or variety... which in its cured state is found by an authorized representative of the Department to have a nicotine... be a suitable low-nicotine strain or variety for the production of Type 31-V, by an agency...

  15. VOC Composition of Air Masses Transported from Asia to the U.S. West Coast

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Warneke, C.; Kuster, B.; Parrish, D.; Holloway, J.; Huebler, G.; Fehsenfeld, F.

    2002-12-01

    Airborne measurements of volatile organic compounds (VOCs) were performed using a proton-transfer-reaction mass spectrometer (PTR-MS) operated onboard a NOAA WP-3 aircraft during the Intercontinental Transport and Chemical Transformation (ITCT) experiment in 2002. Enhancements of acetone (CH3COCH3), methanol (CH3OH), acetonitrile (CH3CN) and in some cases benzene were observed in air masses that were impacted by outflow from Asia. The enhancement ratios with respect to carbon monoxide are compared to emission factors for fossil fuel combustion and biomass burning, which gives some insight into the sources responsible for the pollution. The observed mixing ratios for acetone, methanol and in particular acetonitrile were generally reduced in the marine boundary layer, suggesting the presence of an ocean uptake sink. The ocean uptake of acetonitrile was found to be particularly efficient in a zone with upwelling water off of the U.S. west coast. Reduced mixing ratios of acetone and methanol were observed in a stratospheric intrusion. This observation gives some information about the lifetime of these VOCs in the stratosphere. Enhanced concentrations of aromatic hydrocarbons were observed in air masses that were impacted by urban sources in California. The ratio between the concentrations of benzene, toluene and higher aromatics indicated the degree of photochemical oxidation. PTR-MS only gives information about the mass of the ions produced by proton-transfer reactions between H3O+ and VOCs in the instrument. The identification of VOCs was confirmed by coupling a gas-chromatographic (GC) column to the instrument and post-flight GC-PTR-MS analyses of canister samples collected during the flights.

  16. Epidemiological typing of Klebsiella pneumoniae by pyrolysis mass spectrometry.

    PubMed

    Jackson, R M; Heginbothom, M L; Magee, J T

    1997-01-01

    Thirteen isolates of ceftazidime-resistant Klebsiella pneumoniae from a suspected cross-infection outbreak involving patients on an intensive care unit and a haematology ward were examined in pyrolysis-mass spectrometry (Py-MS), along with eight concurrent non-outbreak-associated clinical isolates of klebsiellae as controls. Py-MS showed tight clustering of the suspected outbreak isolates, suggesting cross-infection with a single strain. Non-outbreak isolates were clearly distinct from one another and from the outbreak strain. The results confirm that Py-MS is a powerful tool for rapid strain comparison in investigations of cross-infection incidents.

  17. Identification of oxidation products of solanesol produced during air sampling for tobacco smoke by electrospray mass spectrometry and HPLC.

    PubMed

    Tucker, Samuel P; Pretty, Jack R

    2005-10-01

    Solanesol, a 45-carbon, trisesquiterpenoid alcohol found in tobacco leaves and tobacco smoke, has been used as a quantitative marker for tobacco smoke for years. However, solanesol appears to be unreliable as a quantitative marker for tobacco smoke during environmental air sampling because it can be degraded substantially when present as a component of tobacco smoke and by as much as 100% when present as pure solanesol on fortified filters during air sampling. Since there is strong evidence that ozone is the agent responsible for the degradation, solanesol appears to be unreliable as a quantitative marker during indoor air sampling when indoor levels of ozone are greater than about 15 ppb. The degree of loss of pure solanesol is directly proportional to the concentration of ozone and the length of the sampling period and depends on the type of 37 mm membrane filter used for air sampling (PTFE or quartz fiber). While the degree of loss of solanesol is inversely proportional to the relative humidity of the air at a sampling rate of 1.7 L min(-1), the degree of loss is virtually independent of relative humidity at a lower sampling rate; i.e., 0.25 L min(-1). A curve of loss of solanesol on a filter versus concentration of ozone from an ozone generator is virtually identical to a curve segment based on atmospheric ozone under the same conditions of air sampling. Oxidation of solanesol by ozone to approximately 25 to 60% completion produces at least three series of products for a total of at least 26 compounds: (1) isoprenoid acetones, (2)omega-hydroxyisoprenoid acetaldehydes, and (3) isoprenoid oxoaldehydes. All products in each series were tentatively identified as their derivatives with 2-(p-aminophenyl)ethanol (APE) by electrospray mass spectrometry (ES-MS). Ten ozonation products were detected as their 2,4-dinitrophenylhydrazine derivatives by HPLC at 360 nm: 4-oxopentanal and nine isoprenoid acetones (acetone, 6-methyl-5-hepten-2-one, geranylacetone

  18. Air mass characterization during the DAURE field campaign by PTR-TOF

    NASA Astrophysics Data System (ADS)

    Metzger, Axel; Schallhart, Simon; Müller, Markus; Hansel, Armin

    2010-05-01

    Volatile organic compounds (VOCs) are emitted into the atmosphere from a wide variety of biogenic and anthropogenic sources. Although some of the sources are well characterized, many uncertainties remain about the fate of these compounds in the atmosphere and their role in organic aerosol formation. Here we present measurements using Proton Transfer Reaction Time-of-Flight (PTR-TOF) Mass Spectrometry during the DAURE field campaign ("Determination of the sources of atmospheric Aerosols in Urban and Rural Environments in the western Mediterranean") obtained during February and March 2009. Measurements were performed at a rural mountain site located in the Montseny Natural Park 40 km to the NNE of the city of Barcelona, and 25 km from the Mediterranean coast. Volatile organic compounds where identified and quantified using PTR-TOF with 1 minute time resolution. The instruments mass resolving power of 4000 - 5000 and a mass accuracy of 5 ppm allows for the unambiguous sum-formula identification of e.g. hydrocarbons (HCs) or oxygenated VOCs (OVOCs). The high time resolution allows separating out on site pollution events. Air masses impacted by biomass-burning, urban, marine and vegetation emissions are characterized using tracers like acetonitrile, aromatics, dimethyl sulfide or biogenic compounds (terpenoids) and the degree of photochemical processing is inferred from the data.

  19. Thermal analysis of HTS air-core transformer used in voltage compensation type active SFCL

    NASA Astrophysics Data System (ADS)

    Song, M.; Tang, Y.; Li, J.; Zhou, Y.; Chen, L.; Ren, L.

    2010-11-01

    The three-phase voltage compensation type active superconducting fault current limiter (SFCL) is composed of three HTS air-core transformers and a three-phase four-wire Pulse Width Modulation (PWM) converter. The primary winding of the each phase HTS air-core transformer is in series with the main system, and the second winding is connected with the PWM converter. The single-phase conduction-cooled HTS air-core transformer is consisting of four double-pancakes wound by the Bi2223/Ag tape. In this paper, according to the electromagnetic analysis on the single-phase HTS air-core transformer, its AC loss corresponding to different operation modes is calculated. Furthermore, the thermal behaviors are studied by the time-stepping numerical simulations. On the basis of the simulation results, the related problems with the HTS air-core transformer's thermal stability are discussed.

  20. Effect of vehicle type on the performance of second generation air bags for child occupants.

    PubMed

    Arbogast, Kristy B; Durbin, Dennis R; Kallan, Michael J; Winston, Flaura K

    2003-01-01

    Passenger air bags experienced considerable design modification in the late 1990s, principally to mitigate risks to child passengers. This study utilized Data from the Partners for Child Passenger Safety study, a large-scale child-focused crash surveillance system, to examine the effect of vehicle type on the differential performance of first and second generation air bags on injuries to restrained children in frontal impact crashes. Our results show that the benefit of second-generation air bags was seen in passenger cars - those children exposed to second-generation air bags were half as likely to sustain a serious injury - and minivans. However, in SUVs the data suggest no reduction in injury risk with the new designs. This field data provides crucial real-world experience to the automotive industry as they work towards the next generation of air bag designs.

  1. 42 CFR 84.156 - Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Airflow resistance test; Type C supplied-air... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.156 Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements. (a) Inhalation resistance shall...

  2. 42 CFR 84.156 - Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Airflow resistance test; Type C supplied-air... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.156 Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements. (a) Inhalation resistance shall...

  3. 42 CFR 84.156 - Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test; Type C supplied-air... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.156 Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements. (a) Inhalation resistance shall...

  4. 42 CFR 84.156 - Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test; Type C supplied-air... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.156 Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements. (a) Inhalation resistance shall...

  5. 42 CFR 84.156 - Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Airflow resistance test; Type C supplied-air... APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.156 Airflow resistance test; Type C supplied-air respirator, demand class; minimum requirements. (a) Inhalation resistance shall...

  6. Air mass distribution and the heterogeneity of the climate change signal in the Hudson Bay/Foxe Basin region, Canada

    NASA Astrophysics Data System (ADS)

    Leung, Andrew; Gough, William

    2016-08-01

    The linkage between changes in air mass distribution and temperature trends from 1971 to 2010 is explored in the Hudson Bay/Foxe Basin region. Statistically significant temperature increases were found of varying spatial and temporal magnitude. Concurrent statistically significant changes in air mass frequency at the same locations were also detected, particularly in the declining frequency of dry polar (DP) air. These two sets of changes were found to be linked, and we thus conclude that the heterogeneity of the climatic warming signal in the region is at least partially the result of a fundamental shift in the concurrent air mass frequency in addition to global and regional changes in radiative forcing due to increases in long-lived greenhouse gases.

  7. Mixture model-based atmospheric air mass classification: a probabilistic view of thermodynamic profiles

    NASA Astrophysics Data System (ADS)

    Pernin, Jérôme; Vrac, Mathieu; Crevoisier, Cyril; Chédin, Alain

    2016-10-01

    Air mass classification has become an important area in synoptic climatology, simplifying the complexity of the atmosphere by dividing the atmosphere into discrete similar thermodynamic patterns. However, the constant growth of atmospheric databases in both size and complexity implies the need to develop new adaptive classifications. Here, we propose a robust unsupervised and supervised classification methodology of a large thermodynamic dataset, on a global scale and over several years, into discrete air mass groups homogeneous in both temperature and humidity that also provides underlying probability laws. Temperature and humidity at different pressure levels are aggregated into a set of cumulative distribution function (CDF) values instead of classical ones. The method is based on a Gaussian mixture model and uses the expectation-maximization (EM) algorithm to estimate the parameters of the mixture. Spatially gridded thermodynamic profiles come from ECMWF reanalyses spanning the period 2000-2009. Different aspects are investigated, such as the sensitivity of the classification process to both temporal and spatial samplings of the training dataset. Comparisons of the classifications made either by the EM algorithm or by the widely used k-means algorithm show that the former can be viewed as a generalization of the latter. Moreover, the EM algorithm delivers, for each observation, the probabilities of belonging to each class, as well as the associated uncertainty. Finally, a decision tree is proposed as a tool for interpreting the different classes, highlighting the relative importance of temperature and humidity in the classification process.

  8. Impact of maritime air mass trajectories on the Western European coast urban aerosol.

    PubMed

    Almeida, S M; Silva, A I; Freitas, M C; Dzung, H M; Caseiro, A; Pio, C A

    2013-01-01

    Lisbon is the largest urban area in the Western European coast. Due to this geographical position the Atlantic Ocean serves as an important source of particles and plays an important role in many atmospheric processes. The main objectives of this study were to (1) perform a chemical characterization of particulate matter (PM2.5) sampled in Lisbon, (2) identify the main sources of particles, (3) determine PM contribution to this urban area, and (4) assess the impact of maritime air mass trajectories on concentration and composition of respirable PM sampled in Lisbon. During 2007, PM2.5 was collected on a daily basis in the center of Lisbon with a Partisol sampler. The exposed Teflon filters were measured by gravimetry and cut into two parts: one for analysis by instrumental neutron activation analysis (INAA) and the other by ion chromatography (IC). Principal component analysis (PCA) and multilinear regression analysis (MLRA) were used to identify possible sources of PM2.5 and determine mass contribution. Five main groups of sources were identified: secondary aerosols, traffic, calcium, soil, and sea. Four-day backtracking trajectories ending in Lisbon at the starting sampling time were calculated using the HYSPLIT model. Results showed that maritime transport scenarios were frequent. These episodes were characterized by a significant decrease of anthropogenic aerosol concentrations and exerted a significant role on air quality in this urban area.

  9. Precipitation chemistry and corresponding transport patterns of influencing air masses at Huangshan Mountain in East China

    NASA Astrophysics Data System (ADS)

    Shi, ChunE; Deng, Xueliang; Yang, Yuanjian; Huang, Xiangrong; Wu, Biwen

    2014-09-01

    One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean (VWM) pH for the whole sampling period was 5.03. SO{4/2-} and Ca2+ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO{4/2-}]/[NO{3/-}] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.

  10. The impact of air mass advection on aerosol optical properties over Gotland (Baltic Sea)

    NASA Astrophysics Data System (ADS)

    Zdun, Agnieszka; Rozwadowska, Anna; Kratzer, Susanne

    2016-12-01

    In the present paper, measurements of aerosol optical properties from the Gotland station of the AERONET network, combined with a two-stage cluster analysis of back trajectories of air masses moving over Gotland, were used to identify the main paths of air mass advection to the Baltic Sea and to relate them to aerosol optical properties, i.e. the aerosol optical thickness at the wavelength λ = 500 nm, AOT (500) and the Ångström exponent for the spectral range from 440 to 870 nm, α(440,870). One- to six-day long back trajectories ending at 300, 500 and 3000 m above the station were computed using the HYSPLIT model. The study shows that in the Gotland region, variability in aerosol optical thickness AOT(500) is more strongly related to advections in the boundary layer than to those in the free troposphere. The observed variability in AOT(500) was best explained by the advection speeds and directions given by clustering of 4-day backward trajectories of air arriving in the boundary layer at 500 m above the station. 17 clusters of 4-day trajectories arriving at altitude 500 m above the Gotland station (sea level) derived using two-stage cluster analysis differ from each other with respect to trajectory length, the speed of air mass movement and the direction of advection. They also show different cluster means of AOT(500) and α(440,870). The cluster mean AOT(500) ranges from 0.342 ± 0.012 for the continental clusters M2 (east-southeast advection with moderate speed) and 0.294 ± 0.025 for S5 (slow south-southeast advection) to 0.064 ± 0.002 and 0.069 ± 0.002 for the respective marine clusters L3 (fast west-northwest advection) and M3 (north-northwest advection with moderate speed). The cluster mean α(440,870) varies from 1.65-1.70 for the short-trajectory clusters to 0.98 ± 0.03 and 1.06 ± 0.03 for the Arctic marine cluster L4 (fast inflow from the north) and marine cluster L5 (fast inflow from the west) respectively.

  11. [Development of new type plastics air turbine handpiece for dental use].

    PubMed

    Kusano, M

    1989-06-01

    The noise generated by the metal air turbine handpiece employed in dental practice is considerable and attended with predominant high frequency components. Therefore, investigation of the noise generation mechanism and development of a silent air turbine handpiece was only a matter of course. In addition, the metal air turbine hardpiece is comparatively heavy and its production cost is high. From this point of view as well, production of a light air turbine handpiece at low cost is also desirable. In order to overcome the objections to the metal air turbine handpiece, appropriate plastics materials were employed wherever possible. In this study, the number of revolutions, noise level, frequency analysis, start pressure and weight of newly produced plastics handpieces and metal handpieces were examined and compared. The following results were obtained: 1. The number of revolutions of single-nozzle type air turbine handpieces encased in plastics housings and fitted with metal turbine rotors was higher than that of all-metal air turbine handpieces. The noise level of the former tended to be lower. 2. The number of revolutions of multi-nozzle type air turbine handpieces encased in plastics housings and fitted with turbine rotors with plastics turbine blades was almost equal to that of similar metal handpieces, with the noise level tending to be lower. 3. In the case of handpieces fitted with turbine rotors with dynamic balance, the number of revolutions was high and the noise level was low. This indicated that dynamic balance was a factor affecting the number of revolutions and noise level. 4. Narrow band sound frequency analysis of single-nozzle type air turbine handpieces showed a sharp peak at the fundamental frequency which was the same as the number of revolutions multiplied by the number of rotor turbine blades. It is thought that the noise from air turbine handpieces was aerodynamic in origin, being generated by the periodical interruption of steady air flow by

  12. Physical properties and evolutionary time scales of disks around solar-type and intermediate mass stars

    NASA Technical Reports Server (NTRS)

    Strom, Stephen E.; Edwards, Suzan

    1993-01-01

    Recent observations of circumstellar disks and their evolutionary timescales are reviewed. It is concluded that disks appear to be a natural outcome of the star-formation process. The disks surrounding young stars initially are massive, with optically thick structures comprised of gas and micron-sized grains. Disk masses are found to range from 0.01 to 0.2 solar masses for solar-type PMS stars, and from 0.01 to 6 solar masses for young, intermediate mass stars. Massive, optically thick accretion disks have accretion rates between 10 exp -8 and 10 exp -6 solar masses/yr for solar type PMS stars and between 10 exp -6 and 10 exp -4 solar masses/yr for intermediate stars. The results suggest that a significant fraction of the mass comprising the star may have passed through a circumstellar accretion disk.

  13. Use of stable lead isotopes and trace metals to characterize air mass sources into the eastern North Atlantic

    NASA Astrophysics Data System (ADS)

    VéRon, Alain J.; Church, Thomas M.

    1997-12-01

    Stable lead isotopes (204Pb, 206Pb, 207Pb, 208Pb) and trace metals (Mn, Al, Fe, Ni, Cu, Cd, Zn, Pb) have been analyzed in aerosol collected during the Atlantic Stratocumulus Transition Experiment-Marine Aerosol and Gas Exchange (ASTEX-MAGE) cruise that transited between Miami and the Azores from May to July 1992. Our goal was to define the continental signatures of the air masses encountered between the Azores and the subtropical regions. The combination of air mass trajectories, trace metal concentrations and stable lead isotopes allowed us to characterize the anthropogenic character of encountered air masses. The average 206Pb/207Pb ratio was 1.148±0.021 and corresponded to a mixing between well defined European (such as Great Britain with 1.115<206Pb/207Pb<1.125 and France with 206Pb/207Pb=1.141±0.000) and North American sources (with 206Pb/207Pb=1.184±0.000). On the basis of air mass trajectories and trace metal concentrations, the background isotopic signature associated with the trade winds (206Pb/207Pb=1.161±0.004) is consistent with previous reports by Church et al. [1990] such as 206Pb/207Pb=1.154±0.004 in 1988, (Véron et al., 1993), 206Pb/207Pb=1.155±0.004 in 1989, and Hamelin et al. [1996] (206Pb/207Pb=1.158±0.006) in 1991. Short-term variations of continental air mass sources was particularly investigated by considering the anthropogenic character of aerosols collected during two Lagrangian experiments conducted as part of the ASTEX-MAGE cruise. We demonstrated the utility of stable lead isotopes to assign a "continental source signature" (or mixture thereof) to air masses beyond that normally possible by conventional air mass trajectory analysis in remote oceanic regions.

  14. The Effects of Body Mass Composition and Cushion Type on Seat-Interface Pressure in Spinal Cord Injured Patients

    PubMed Central

    Cho, Kang Hee; Beom, Jaewon; Yuk, Jee Hyun

    2015-01-01

    Objective To investigate the effects of body mass composition and cushion type on seat-interface pressure in spinal cord injured (SCI) patients and healthy subjects. Methods Twenty SCI patients and control subjects were included and their body mass composition measured. Seat-interface pressure was measured with participants in an upright sitting posture on a wheelchair with three kinds of seat cushion and without a seat cushion. We also measured the pressure with each participant in three kinds of sitting postures on each air-filled cushion. We used repeated measure ANOVA, the Mann-Whitney test, and Spearman correlation coefficient for statistical analysis. Results The total skeletal muscle mass and body water in the lower extremities were significantly higher in the control group, whilst body fat was significantly higher in the SCI group. However, the seat-interface pressure and body mass composition were not significantly correlated in both groups. Each of the three types of seat cushion resulted in significant reduction in the seat-interface pressure. The SCI group had significantly higher seatinterface pressure than the control group regardless of cushion type or sitting posture. The three kinds of sitting posture did not result in a significant reduction of seat-interface pressure. Conclusion We confirmed that the body mass composition does not have a direct effect on seat-interface pressure. However, a reduction of skeletal muscle mass and body water can influence the occurrence of pressure ulcers. Furthermore, in order to minimize seat-interface pressure, it is necessary to apply a method fitted to each individual rather than a uniform method. PMID:26798612

  15. An effective indicator of continental scale cold air outbreaks in northern winter: the intensity variation of the meridional mass circulation

    NASA Astrophysics Data System (ADS)

    Ren, R.; Yu, Y.; Cai, M.

    2015-12-01

    This study reports that the intensity variation of the meridional mass circulation can be an effective leading indicator of cold air outbreaks (CAOs) over midlatitudes in northern winter. It is found that continental-scale coldness by cold air outbreaks (CAOs) tend to preferentially occur within a week after stronger mass circulation events defined as the peak time when the net mass transport across 60°N in the upper warm or the lower cold air branch exceeds ~88×109 kg s-1. During weaker mass circulation events when the net mass transport across 60°N is below ~71.6×109 kg s-1, most areas of the mid-latitudes are generally in mild condition except the northern part of Western Europe. Composite pattern of circulation anomalies during stronger mass circulation events greatly resemble that of the winter-mean, with the two main routes of anomalous cold air outbreaks being along the climatological routes of polar cold air, namely, via East Asia and North America. The Siberian High shifts westward during stronger mass circulation events, opening up a third route of cold air outbreaks through Eastern Europe. The relationship of CAOs with Arctic Oscillation (AO) is less robust because temporal changes of AO are resulted from a small imbalance between the poleward and equatorward branches of the mass circulation. Only when the poleward branch leads the equatorward branch (44% of all cases), CAOs tend to take place within a week after a negative phase of AO. The daily ERA-Interim reanalysis data set for the 32 winters in 1979-2011 were used in this study.

  16. Air mass modification over Europe: EARLINET aerosol observations from Wales to Belarus

    NASA Astrophysics Data System (ADS)

    Wandinger, Ulla; Mattis, Ina; Tesche, Matthias; Ansmann, Albert; BöSenberg, Jens; Chaikovski, Anatoly; Freudenthaler, Volker; Komguem, Leonce; Linné, Holger; Matthias, Volker; Pelon, Jacques; Sauvage, Laurent; Sobolewski, Piotr; Vaughan, Geraint; Wiegner, Matthias

    2004-12-01

    For the first time, the vertically resolved aerosol optical properties of western and central/eastern European haze are investigated as a function of air mass transport. Special emphasis is put on clean maritime air masses that cross the European continent from the west and become increasingly polluted on their way into the continent. The study is based on observations at seven lidar stations (Aberystwyth, Paris, Hamburg, Munich, Leipzig, Belsk, and Minsk) of the European Aerosol Research Lidar Network (EARLINET) and on backward trajectory analysis. For the first time, a lidar network monitored continent-scale haze air masses for several years (since 2000). Height profiles of the particle backscatter coefficient and the particle optical depth of the planetary boundary layer (PBL) at 355-nm wavelength are analyzed for the period from May 2000 to November 2002. From the observations at Aberystwyth, Wales, the aerosol reference profile for air entering Europe from pristine environments was determined. A mean 355-nm optical depth of 0.05 and a mean PBL height of 1.5 km was found for clean maritime summer conditions. The particle optical depth and PBL height increased with increasing distance from the North Atlantic. Mean summer PBL heights were 1.9-2.8 km at the continental sites of Leipzig, Belsk, and Minsk. Winter mean PBL heights were mostly between 0.7 and 1.3 km over the seven EARLINET sites. Summer mean 355-nm optical depths increased from 0.17 (Hamburg, northwesterly airflow from the North Sea) and 0.21 (Paris, westerly flow from the Atlantic) over 0.33 (Hamburg, westerly flow) and 0.35 (Leipzig, westerly flow) to 0.59 (Belsk, westerly flow), and decreased again to 0.37 (westerly flow) at Minsk. Winter mean optical depths were, on average, 10-30% lower than the respective summer values. PBL-mean extinction coefficients were of the order of 200 Mm-1 at 355 nm at Hamburg and Leipzig, Germany, and close to 600 Mm-1 at Belsk, Poland, in winter for westerly flows

  17. Polycyclic aromatic hydrocarbons in air on small spatial and temporal scales - II. Mass size distributions and gas-particle partitioning

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Klánová, Jana; Ilić, Predrag; Kohoutek, Jiří; Gasić, Bojan; Kovacić, Igor; Škrdlíková, Lenka

    2010-12-01

    Polycyclic aromatic hydrocarbons (PAHs) were measured together with inorganic air pollutants at two urban sites and one rural background site in the Banja Luka area, Bosnia and Hercegovina, during 72 h in July 2008 using a high time resolution (5 samples per day) with the aim to study gas-particle partitioning, aerosol mass size distributions and to explore the potential of a higher time resolution (4 h-sampling). In the particulate phase the mass median diameters of the PAHs were found almost exclusively in the accumulation mode (0.1-1.0 μm of size). These were larger for semivolatile PAHs than for non-volatile PAHs. Gas-particle partitioning of semivolatile PAHs was strongly influenced by temperature. The results suggest that the Junge-Pankow model is inadequate to explain the inter-species variation and another process must be significant for phase partitioning which is less temperature sensitive than adsorption. Care should be taken when interpreting slopes m of plots of the type log K p = m log p L0 + b based on 24 h means, as these are found sensitive to the time averaging, i.e. tend to be higher than when based on 12 h-mean samples.

  18. Thoron ( 220Rn) progeny reduction by an air cleaner of the polarized media filter type

    NASA Astrophysics Data System (ADS)

    Bigu, J.

    1993-02-01

    The effect of an air cleaner on 220Rn progeny atmospheres has been studied in a Radon/Thoron Test Facility (RTTF) of the walk-in type. The air cleaner consists basically of a fan and a special filter material sandwiched between two metal screens, to which an electric field is applied. The filter is of the polarized media type and uses fibreglass as material. The fan and filter system are housed in a metal case. Air is drawn from the back of the case by means of the fan and forced through the "electrical" filter where removal of the 220Rn progeny occurs. Radon-220 progeny "depleted" air is discharged at the top of the device. Tests were conducted in 220Rn/ 220Rn progeny atmospheres when the air cleaner was operating, and when it was turned off. Very pronounced effects were observed during the operation of the device, namely: a dramatic decrease in the 220Rn progeny concentrations and the total aerosol concentration, as well as a large increase in the 220Rn progeny unattached fractions and the plate-out of these radionuclides on the walls of the RTTF. The air cleaner has potential in industrial applications, which should be explored.

  19. AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

    EPA Science Inventory

    Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

  20. Mass disasters: rapid molecular screening of human remains by means of short tandem repeats typing.

    PubMed

    Corach, D; Sala, A; Penacino, G; Sotelo, A

    1995-09-01

    Human remains identification represents a challenging situation and constitutes a difficult task associated with mass disasters. The only highly efficient means for individual and family group reconstruction is that based on DNA typing. On July 18, 1994 an explosion destroyed the A.M.I.A. (Argentine Israeli Association). Over 100 people died; however, the exact number of victims is still being investigated. Our Service received over 70 remains to be characterized by DNA typing in order to determine the number of victims and to try to reconstruct the family groups to which they belonged. DNA was extracted by a cetyltrimethylammonium bromide (CTAB) based protocol, a rapid molecular screening of all samples was carried out by multiplex STR amplifications including HUMTH01, HUMFABP, HUMHPRTB, HUMRENA4, HUMVWA, HUMFES/FPS and Y27H39LR. Samples with identical genotypes were HaeIII-digested. Southern blotted and probed with YNH-24 (D2S44). PH-30 (D4S139). LH-1 (D5S110) and MS-1 (D1S7) for variable number of tandem repeats (VNTR) evaluation. The minisatellite variant repeat (MVR) approach was used in those cases in which band or profile shift were detected in Southern blot assays. Kinship between victims and putative relatives was initially evaluated by comparison of short tandem repeat (STR) profiles and then confirmed by VNTR with the above probes. The high identification efficiency attained in this case is, in part, supported by a previous experience, the DNA-based molecular characterization of human remains caused by the explosion of the Israeli Embassy in Buenos Aires, March 1992.

  1. Polyglandular autoimmune syndrome type I – a novel AIRE mutation in a North American patient

    PubMed Central

    Huibregtse, Kelly Egan; Wolfgram, Peter; Winer, Karen K.; Connor, Ellen L.

    2015-01-01

    Autoimmune polyglandular syndrome type 1 (APS-1), also referred to as autoimmune polyendocrinopathy-candidiasis-ectodermal dystrophy (APECED), is a rare autoimmune disease that results from autosomal recessive mutations of the human autoimmune regulatory (AIRE) gene. We present the case of a 17-year-old North American girl of primarily Norwegian descent with a novel AIRE gene mutation causing APS-1. In addition to the classic triad of chronic candidiasis, hypoparathyoidism and autoimmune adrenocortical insufficiency, she also has vitiligo, intestinal malabsorption, autoimmune hepatitis, autoimmune hypothyroidism, myositis, myalgias, chronic fatigue, and failure to thrive. Genetic testing revealed heterozygosity for c.20_115de196 and c.967_979del13 mutations in the AIRE gene. The AIRE gene c.20_115de196 mutation has not been previously reported. PMID:24945421

  2. Composition of air masses in Fuerteventura (Canary Islands) according to their origins

    SciTech Connect

    Patier, R.F.; Diez Hernandez, P.; Diaz Ramiro, E.; Ballesteros, J.S.; Santos-Alves, S.G. dos

    1994-12-31

    The Centro Nacional de Sanidad Ambiental has among their duties the background atmospheric pollution monitoring in Spain. To do so, the laboratory has set up 6 field stations in the Iberian Peninsula. In these stations, both gaseous and particulate pollutants are currently analyzed. However, there is a lack of data about the atmospheric pollution in the Canary, where they are a very strong influence of natural emissions from sea and the Saharan desert, mixed with anthropogenic ones. Therefore, during the ASTEX/MAGE project the CNSA established a station in Fuerteventura island, characterized by the nonexistence of man-made emissions, to measure some atmospheric pollutants, in order to foresee their origins. In this study, the authors analyzed some pollutants that are used to obtain a clue about the sources of air masses such as gaseous ozone and metallic compounds (vanadium, iron and manganese) in the atmospheric aerosol fractionated by size.

  3. Measurements of two types of dilatational waves in an air-filled unconsolidated sand

    SciTech Connect

    Hickey, C.J.; Sabatier, J.M.

    1997-07-01

    This study consists of laboratory measurements of dilatational waves propagating through an air-filled unconsolidated sand. One excitation technique consists of a loudspeaker suspended in the air above the packing of sand. A second excitation technique uses a mechanical shaker in contact with the sand. The transmitted signals are received using microphones and geophones located at various depths within the sand. An interpretation based on measured phase speeds indicates that the transmitted energy from the suspended loudspeaker source is partitioned primarily but not exclusively into the type-II dilatational wave. This wave attenuates rapidly and is only detected at depths of less than about 15 cm for this particular sample. At the deeper depths the detected signal is associated with the type-I dilatational wave. The mechanical shaker produces only a type-I dilatational wave. Both the geophone and microphone sensors can detect both types of dilatational waves. {copyright} {ital 1997 Acoustical Society of America.}

  4. Optimal design and selection of magneto-rheological brake types based on braking torque and mass

    NASA Astrophysics Data System (ADS)

    Nguyen, Q. H.; Lang, V. T.; Choi, S. B.

    2015-06-01

    In developing magnetorheological brakes (MRBs), it is well known that the braking torque and the mass of the MRBs are important factors that should be considered in the product’s design. This research focuses on the optimal design of different types of MRBs, from which we identify an optimal selection of MRB types, considering braking torque and mass. In the optimization, common types of MRBs such as disc-type, drum-type, hybrid-type, and T-shape types are considered. The optimization problem is to find an optimal MRB structure that can produce the required braking torque while minimizing its mass. After a brief description of the configuration of the MRBs, the MRBs’ braking torque is derived based on the Herschel-Bulkley rheological model of the magnetorheological fluid. Then, the optimal designs of the MRBs are analyzed. The optimization objective is to minimize the mass of the brake while the braking torque is constrained to be greater than a required value. In addition, the power consumption of the MRBs is also considered as a reference parameter in the optimization. A finite element analysis integrated with an optimization tool is used to obtain optimal solutions for the MRBs. Optimal solutions of MRBs with different required braking torque values are obtained based on the proposed optimization procedure. From the results, we discuss the optimal selection of MRB types, considering braking torque and mass.

  5. The influence of polarization on box air mass factors for UV/vis nadir satellite observations

    NASA Astrophysics Data System (ADS)

    Hilboll, Andreas; Richter, Andreas; Rozanov, Vladimir V.; Burrows, John P.

    2015-04-01

    Tropospheric abundances of pollutant trace gases like, e.g., NO2, are often derived by applying the differential optical absorption spectroscopy (DOAS) method to space-borne measurements of back-scattered and reflected solar radiation. The resulting quantity, the slant column density (SCD), subsequently has to be converted to more easily interpretable vertical column densities by means of the so-called box air mass factor (BAMF). The BAMF describes the ratio of SCD and VCD within one atmospheric layer and is calculated by a radiative transfer model. Current operational and scientific data products of satellite-derived trace gas VCDs do not include the effect of polarization in their radiative transfer models. However, the various scattering processes in the atmosphere do lead to a distinctive polarization pattern of the observed Earthshine spectra. This study investigates the influence of these polarization patterns on box air mass factors for satellite nadir DOAS measurements of NO2 in the UV/vis wavelength region. NO2 BAMFs have been simulated for a multitude of viewing geometries, surface albedos, and surface altitudes, using the radiative transfer model SCIATRAN. The results show a potentially large influence of polarization on the BAMF, which can reach 10% and more close to the surface. A simple correction for this effect seems not to be feasible, as it strongly depends on the specific measurement scenario and can lead to both high and low biases of the resulting NO2 VCD. We therefore conclude that all data products of NO2 VCDs derived from space-borne DOAS measurements should include polarization effects in their radiative transfer model calculations, or at least include the errors introduced by using linear models in their uncertainty estimates.

  6. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    SciTech Connect

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  7. 76 FR 62605 - Airworthiness Directives; Viking Air Limited Model DHC-3 (Otter) Airplanes With Supplemental Type...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-11

    ... Limited Model DHC-3 (Otter) Airplanes With Supplemental Type Certificate (STC) SA 09866SC AGENCY: Federal... DHC-3 (Otter) airplanes equipped with a Honeywell TPE331- 10 or -12JR turboprop engine installed per... for Viking Air Limited Model DHC-3 (Otter) airplanes equipped with a Honeywell TPE331-10 or...

  8. The Evaluation of Unitary & Central Type Air-Conditioning Systems in Selected Florida Schools.

    ERIC Educational Resources Information Center

    Bradley, William B.

    The study reported here was conducted in an effort to obtain data for comparing the combined owning and operating costs of two different types of air-conditioning systems in two elementary schools. Both schools were built during 1969-70 in the same geographical area along the southeast coast of Florida and are also served by the same electric…

  9. 42 CFR 84.148 - Type C supplied-air respirator, continuous flow class; minimum requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Type C supplied-air respirator, continuous flow class; minimum requirements. 84.148 Section 84.148 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF... flow class; minimum requirements. (a) Respirators tested under this section shall be approved only...

  10. A Comparison of Two Methods for Initiating Air Mass Back Trajectories

    NASA Astrophysics Data System (ADS)

    Putman, A.; Posmentier, E. S.; Faiia, A. M.; Sonder, L. J.; Feng, X.

    2014-12-01

    Lagrangian air mass tracking programs in back cast mode are a powerful tool for estimating the water vapor source of precipitation events. The altitudes above the precipitation site where particle's back trajectories begin influences the source estimation. We assume that precipitation comes from water vapor in condensing regions of the air column, so particles are placed in proportion to an estimated condensation profile. We compare two methods for estimating where condensation occurs and the resulting evaporation sites for 63 events at Barrow, AK. The first method (M1) uses measurements from a 35 GHz vertically resolved cloud radar (MMCR), and algorithms developed by Zhao and Garrett1 to calculate precipitation rate. The second method (M2) uses the Global Data Assimilation System reanalysis data in a lofting model. We assess how accurately M2, developed for global coverage, will perform in absence of direct cloud observations. Results from the two methods are statistically similar. The mean particle height estimated by M2 is, on average, 695 m (s.d. = 1800 m) higher than M1. The corresponding average vapor source estimated by M2 is 1.5⁰ (s.d. = 5.4⁰) south of M1. In addition, vapor sources for M2 relative to M1 have ocean surface temperatures averaging 1.1⁰C (s.d. = 3.5⁰C) warmer, and reported ocean surface relative humidities 0.31% (s.d. = 6.1%) drier. All biases except the latter are statistically significant (p = 0.02 for each). Results were skewed by events where M2 estimated very high altitudes of condensation. When M2 produced an average particle height less than 5000 m (89% of events), M2 estimated mean particle heights 76 m (s.d. = 741 m) higher than M1, corresponding to a vapor source 0.54⁰ (s.d. = 4.2⁰) south of M1. The ocean surface at the vapor source was an average of 0.35⁰C (s.d. = 2.35⁰C) warmer and ocean surface relative humidities were 0.02% (s.d. = 5.5%) wetter. None of the biases was statistically significant. If the vapor source

  11. Study Case of Air-Mass Modification over Poland and Romania Observed by the Means of Multiwavelength Raman Depolarization Lidars

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Janicka, Lucja; Stachlewska, Iwona S.; Nemuc, Anca; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2016-06-01

    An air-mass modification, on its way from Poland to Romania, observed between 19-21 July 2014 is discussed. The air-mass was investigated using data of two multi-wavelength lidars capable of performing regular elastic, depolarization and Raman measurements in Warsaw, Poland, and in Magurele, Romania. The analysis was focused on evaluating optical properties of aerosol in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations within given period.

  12. Large-scale transport of a CO-enhanced air mass from Europe to the Middle East

    NASA Technical Reports Server (NTRS)

    Connors, V. S.; Miles, T.; Reichle, H. G., Jr.

    1989-01-01

    On November 14, 1981, the shuttle-borne Measurement of Air Pollution from Satellites (MAPS) experiment observed a carbon monoxide (CO) enhanced air mass in the middle troposphere over the Middle East. The primary source of this polluted air was estimated by constructing adiabatic isentropic trajectories backwards from the MAPS measurement location over a 36 h period. The isentropic diagnostics indicate that CO-enhanced air was transported southeastward over the Mediterranean from an organized synoptic-scale weather regime, albeit of moderate intensity, influencing central Europe on November 12. Examination of the evolving synoptic scale vertical velocity and precipitation patterns during this period, in conjuction with Meteosat visible, infrared, and water vapor imagery, suggests that the presence of this disturbed weather system over Europe may have created upward transport of CO-enhanced air between the boundary-layer and midtropospheric levels, and subsequent entrainment in the large-scale northwesterly jet stream flow over Europe and the Mediterranean.

  13. Numerical Simulation of Air Mass Modification Over the East China Sea during the Winter Season

    NASA Astrophysics Data System (ADS)

    Hsu, Wu-Ron

    Air mass modification over the East China Sea during cold air outbreaks in the winter season was simulated by utilizing a high-resolution numerical model. The model includes most of the major physical processes, such as, surface exchange of heat and moisture between water and air; condensation and evaporation; and vertical turbulent transfer of heat, moisture, and momentum. The simulated convective boundary layer (CBL) consists of a surface layer, a subcloud layer, and a cloud layer. It is capped by an inversion with strong temperature and moisture gradients. Mesoscale cellular convection (MCC) embedded within the convective layer moves along with the mean wind. The average aspect ratio of the cells is 17.5, which agrees with observed aspect ratios for convective cells over the East China Sea. The upward convective motion correlates very well with the appearance of clouds, higher temperature, and higher moisture content in the CBL. The effects of diabatic heating were found to be very important in driving the thermal convection. Without the release of latent heat, the convective layer would be very shallow, and the convective motion would be greatly suppressed. Even though the formulation and dissipation of a cloud is associated with the movement of the resolvable scale MCC, the vertical transport of heat and moisture is achieved mainly by the unresolvable turbulent eddies. The distribution of specific humidity during the passage of the surface front reveals the moisture being pushed upward along the frontal surface as observed. The cold and dry air behind the cold front is quickly modified by strong convection over the warm water surface, especially over the Kuroshio Current. A cloud-free region exists near the coast where the CBL is too shallow for clouds to develop. A layer of stratocumulus forms downstream from the cloud-free region. The depth of the CBL increases toward the Kuroshio Current due to strong heat and moisture fluxes from the water surface. The CBL

  14. 42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Airflow resistance test; Type C supplied-air... ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.157 Airflow resistance... feet) per minute. (c) The exhalation resistance to a flow of air at a rate of 85 liters (3 cubic...

  15. 42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Airflow resistance test; Type C supplied-air... ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.157 Airflow resistance... feet) per minute. (c) The exhalation resistance to a flow of air at a rate of 85 liters (3 cubic...

  16. 42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test; Type C supplied-air... ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.157 Airflow resistance... feet) per minute. (c) The exhalation resistance to a flow of air at a rate of 85 liters (3 cubic...

  17. 42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test; Type C supplied-air... ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.157 Airflow resistance... feet) per minute. (c) The exhalation resistance to a flow of air at a rate of 85 liters (3 cubic...

  18. Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)

    NASA Astrophysics Data System (ADS)

    Dall'Osto, Manuel; Beddows, David C. S.; Gietl, Johanna K.; Olatunbosun, Oluremi A.; Yang, Xiaoguang; Harrison, Roy M.

    2014-09-01

    There is a paucity of quantitative knowledge on the contributions of non-exhaust (abrasion and re-suspension) sources to traffic emissions. Abrasive emissions can be broadly categorised as tyre wear, brake wear and road dust/road surface wear. Current research often considers road dust and tyre dust as externally mixed particles, the former mainly composed of mineral matter and the latter solely composed of mainly organic matter and some trace elements. The aim of this work was to characterise tyre wear from both laboratory and field studies by using Aerosol Time-Of-Flight Mass Spectrometry (ATOFMS). Real-time single particle chemical composition was obtained from a set of rubber tyres rotating on a metal surface. Bimodal particle number size distributions peaking at 35 nm and 85 nm were obtained from SMPS/APS measurements over the range 6-20,000 nm. ATOFMS mass spectra of tyre wear in the particle size range 200-3000 nm diameter show peaks due to exo-sulphur compounds, nitrate, Zn and ions of high molecular weight (m/z > 100) attributed to organic polymers. Two large ATOFMS datasets collected from a number of outdoor studies were examined. The former was constituted of 48 road dust samples collected on the roads of London. The latter consisted of ATOFMS ambient air field studies from Europe, overall composed of more than 2,000,000 single particle mass spectra. The majority (95%) of tyre wear particles present in the road dust samples and atmospheric samples are internally mixed with metals (Li, Na, Ca, Fe, Ti), as well as phosphate. It is concluded that the interaction of tyres with the road surface creates particles internally mixed from two sources: tyre rubber and road surface materials. Measurements of the tyre rubber component alone may underestimate the contribution of tyre wear to concentrations of airborne particulate matter. The results presented are especially relevant for urban aerosol source apportionment and PM2.5 exposure assessment.

  19. Air/water subchannel measurements of the equilibrium quality and mass-flux distribution in a rod bundle. [BWR

    SciTech Connect

    Sterner, R.W.; Lahey, R.T. Jr.

    1983-07-01

    Subchannel measurements were performed in order to determine the equilibrium quality and mass flux distribution in a four rod bundle, using air/water flow. An isokinetic technique was used to sample the flow in the center, side and corner subchannels of this test section. Flow rates of the air and water in each sampled subchannel were measured. Experiments were performed for two test-section-average mass fluxes (0.333x10/sup 6/ and 0.666x10/sup 6/ lb/sub m//h-ft/sup 2/), and the test-section-average quality was varied from 0% to 0.54% for each mass flux. Single-phase liquid, bubbly, slug and churn-turbulent two-phase flow regimes were achieved. The observed data trends agreed with previous diabatic measurements in which the center subchannel had the highest quality and mass flux, while the corner subchannel had the lowest.

  20. Vitamin E alters alveolar type II cell phospholipid synthesis in oxygen and air

    SciTech Connect

    Kennedy, K.A.; Snyder, J.M.; Stenzel, W.; Saito, K.; Warshaw, J.B. )

    1990-11-01

    Newborn rats were injected with vitamin E or placebo daily until 6 days after birth. The effect of vitamin E pretreatment on in vitro surfactant phospholipid synthesis was examined in isolated type II cells exposed to oxygen or air form 24 h in vitro. Type II cells were also isolated from untreated 6-day-old rats and cultured for 24 h in oxygen or air with control medium or vitamin E supplemented medium. These cells were used to examine the effect of vitamin E exposure in vitro on type II cell phospholipid synthesis and ultrastructure. Phosphatidylcholine (PC) synthesis was reduced in cells cultured in oxygen as compared with air. This decrease was not prevented by in vivo pretreatment or in vitro supplementation with vitamin E. Vitamin E pretreatment increased the ratio of disaturated PC to total PC and increased phosphatidylglycerol synthesis. The volume density of lamellar bodies in type II cells was increased in cells maintained in oxygen. Vitamin E did not affect the volume density of lamellar bodies. We conclude that in vitro hyperoxia inhibits alveolar type II cell phosphatidylcholine synthesis without decreasing lamellar body volume density and that supplemental vitamin E does not prevent hyperoxia-induced decrease in phosphatidylcholine synthesis.

  1. Development of 72/84kV Dry Air Insulated Dead Tank Type VCB

    NASA Astrophysics Data System (ADS)

    Saito, Hitoshi; Nagatake, Kazuhiro; Komatsu, Hideki; Takeshita, Yukihiro; Matsui, Yoshihiko; Katsumata, Kiyohito; Sakaki, Masayuki

    As a circuit breaker for over 84kV, SF6 gas circuit breaker (GCB) has been used for a long time, in virtue of its excellent characteristics as arc extinction and insulating medium. Although, SF6 gas has very high global warming potential (GWP) of 23,900, and it was designated to regulation object in COP3 in Kyoto in 1997. A lot of efforts have been done to reduce the amount of SF6 gas usage and emission from conventional equipments. On the other hand, SF6 gas free equipment has been researching and one strong candidate is air-insulated type switchgears with vacuum interrupters. In last few years, air-insulated switchgears, which include GIS, Cubicle type GIS (C-GIS) and dead tank type VCB, have been developed in succession. So far, we have already more than three years operation record for the air-insulated dead tank type VCB, and over 100 units is in-service in power systems. Recently, VCB technology, that is essential for SF6 gas-free equipments, has been advanced in the field of high-voltage, large current interruption and environment-conscious design. In this paper, the advanced dead tank type VCB and its technology is descried.

  2. Elbow mass flow meter

    DOEpatents

    McFarland, Andrew R.; Rodgers, John C.; Ortiz, Carlos A.; Nelson, David C.

    1994-01-01

    Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

  3. Further evidence for large central mass-to-light ratios in massive early-type galaxies

    NASA Astrophysics Data System (ADS)

    Corsini, E. M.; Wegner, G. A.; Thomas, J.; Saglia, R. P.; Bender, R.; Pu, S. B.

    2013-07-01

    We studied the stellar populations, distribution of dark matter, and dynamical structure of a sample of 25 early-type galaxies in the Coma and Abell~262 clusters. We derived dynamical mass-to-light ratios and dark matter densities from orbit-based dynamical models, complemented by the ages, metallicities, and α-element abundances of the galaxies from single stellar population models. Most of the galaxies have a significant detection of dark matter and their halos are about 10 times denser than in spirals of the same stellar mass. Calibrating dark matter densities to cosmological simulations we find assembly redshifts z DM ~ 1-3. The dynamical mass that follows the light is larger than expected for a Kroupa stellar initial mass function, especially in galaxies with high velocity dispersion σeff inside the effective radius r eff. We now have 5 of 25 galaxies where mass follows light to 1-3 r eff, the dynamical mass-to-light ratio of all the mass that follows the light is large (~ 8-10 in the Kron-Cousins R band), the dark matter fraction is negligible to 1-3 r eff. This could indicate a `massive' initial mass function in massive early-type galaxies. Alternatively, some of the dark matter in massive galaxies could follow the light very closely suggesting a significant degeneracy between luminous and dark matter.

  4. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 3

    NASA Technical Reports Server (NTRS)

    Blakeslee, A. E.; Hovel, H. J.; Woodall, J. M.

    1977-01-01

    The etch-back epitaxy process is described for producing thin, graded composition GaAlAs layers. The palladium-aluminum contact system is discussed along with its associated problems. Recent solar cell results under simulated air mass zero light and at elevated temperatures are reported and the growth of thin polycrystalline GaAs films on foreign substrates is developed.

  5. Dark matter inside early-type galaxies as function of mass and redshift

    NASA Astrophysics Data System (ADS)

    Nigoche-Netro, A.; Ramos-Larios, G.; Lagos, P.; Ruelas-Mayorga, A.; de la Fuente, E.; Kemp, S. N.; Navarro, S. G.; Corral, L. J.; Hidalgo-Gámez, A. M.

    2016-10-01

    We study the behaviour of the dynamical and stellar mass inside the effective radius (re) of early-type galaxies (ETGs). We use several samples of ETGs - ranging from 19 000 to 98 000 objects - from the ninth data release of the Sloan Digital Sky Survey. We consider Newtonian dynamics, different light profiles and different initial mass functions (IMF) to calculate the dynamical and stellar mass. We assume that any difference between these two masses is due to dark matter and/or a non-universal IMF. The main results for galaxies in the redshift range 0.0024 < z < 0.3500 and in the dynamical mass range 9.5 < log(M) < 12.5 are: (i) a significant part of the intrinsic dispersion of the distribution of dynamical versus stellar mass is due to redshift; (ii) the difference between dynamical and stellar mass increases as a function of dynamical mass and decreases as a function of redshift; (iii) the difference between dynamical and stellar mass goes from approximately 0 to 70 per cent of the dynamical mass depending on mass and redshift; (iv) these differences could be due to dark matter or a non-universal IMF or a combination of both; (v) the amount of dark matter inside ETGs would be equal to or less than the difference between dynamical and stellar mass depending on the impact of the IMF on the stellar mass estimation; (vi) the previous results go in the same direction of some results of the Fundamental Plane (FP) found in the literature in the sense that they could be interpreted as an increase of dark matter along the FP and a dependence of the FP on redshift.

  6. Nucleosynthesis Predictions for Intermediate-Mass AGB Stars: Comparison to Observations of Type I Planetary Nebulae

    NASA Technical Reports Server (NTRS)

    Karakas, Amanda I.; vanRaai, Mark A.; Lugaro, Maria; Sterling, Nicholas C.; Dinerstein, Harriet L.

    2008-01-01

    Type I planetary nebulae (PNe) have high He/H and N/O ratios and are thought to be descendants of stars with initial masses of approx. 3-8 Stellar Mass. These characteristics indicate that the progenitor stars experienced proton-capture nucleosynthesis at the base of the convective envelope, in addition to the slow neutron capture process operating in the He-shell (the s-process). We compare the predicted abundances of elements up to Sr from models of intermediate-mass asymptotic giant branch (AGB) stars to measured abundances in Type I PNe. In particular, we compare predictions and observations for the light trans-iron elements Se and Kr, in order to constrain convective mixing and the s-process in these stars. A partial mixing zone is included in selected models to explore the effect of a C-13 pocket on the s-process yields. The solar-metallicity models produce enrichments of [(Se, Kr)/Fe] less than or approx. 0.6, consistent with Galactic Type I PNe where the observed enhancements are typically less than or approx. 0.3 dex, while lower metallicity models predict larger enrichments of C, N, Se, and Kr. O destruction occurs in the most massive models but it is not efficient enough to account for the greater than or approx. 0.3 dex O depletions observed in some Type I PNe. It is not possible to reach firm conclusions regarding the neutron source operating in massive AGB stars from Se and Kr abundances in Type I PNe; abundances for more s-process elements may help to distinguish between the two neutron sources. We predict that only the most massive (M grester than or approx.5 Stellar Mass) models would evolve into Type I PNe, indicating that extra-mixing processes are active in lower-mass stars (3-4 Stellar Mass), if these stars are to evolve into Type I PNe.

  7. A comparison of measured radiances from AIRS and HIRS across different cloud types

    NASA Astrophysics Data System (ADS)

    Schreier, M. M.; Kahn, B. H.; Staten, P.

    2015-12-01

    The observation of Earth's atmosphere with passive remote sensing instruments is ongoing for decades and resulting in a long-term global dataset. Two prominent examples are operational satellite platforms from the National Oceanic and Atmospheric Administration (NOAA) or research platforms like NASA's Earth Observing System (EOS). The observed spectral ranges of these observations are often similar among the different platforms, but have large differences when it comes to resolution, accuracy and quality control. Our approach is to combine different kinds of instruments at the pixel-scale to improve the characterization of infrared radiances. We focus on data from the High-resolution Infrared Radiation Sounder (HIRS) and compare the observations to radiances from the Atmospheric Infrared Sounder (AIRS) on Aqua. The high spectral resolution of AIRS is used to characterize and possibly recalibrate the observed radiances from HIRS. Our approach is unique in that we use additional information from other passive instruments on the same platforms including the Advanced Very High Resolution Radiometer (AVHRR) and the MODerate resolution Imaging Spectroradiometer (MODIS). We will present comparisons of radiances from HIRS and AIRS within different types of clouds that are determined from the imagers. In this way, we can analyze and select the most homogeneous conditions for radiance comparisons and a possible re-calibration of HIRS. We hope to achieve a cloud-type-dependent calibration and quality control for HIRS, which can be extrapolated into the past via inter-calibration of the different HIRS instruments beyond the time of AIRS.

  8. Effects of Automation Types on Air Traffic Controller Situation Awareness and Performance

    NASA Technical Reports Server (NTRS)

    Sethumadhavan, A.

    2009-01-01

    The Joint Planning and Development Office has proposed the introduction of automated systems to help air traffic controllers handle the increasing volume of air traffic in the next two decades (JPDO, 2007). Because fully automated systems leave operators out of the decision-making loop (e.g., Billings, 1991), it is important to determine the right level and type of automation that will keep air traffic controllers in the loop. This study examined the differences in the situation awareness (SA) and collision detection performance of individuals when they worked with information acquisition, information analysis, decision and action selection and action implementation automation to control air traffic (Parasuraman, Sheridan, & Wickens, 2000). When the automation was unreliable, the time taken to detect an upcoming collision was significantly longer for all the automation types compared with the information acquisition automation. This poor performance following automation failure was mediated by SA, with lower SA yielding poor performance. Thus, the costs associated with automation failure are greater when automation is applied to higher order stages of information processing. Results have practical implications for automation design and development of SA training programs.

  9. Epidemiological and experimental links between air pollution and type 2 diabetes.

    PubMed

    Liu, Cuiqing; Ying, Zhekang; Harkema, Jack; Sun, Qinghua; Rajagopalan, Sanjay

    2013-02-01

    There is increasing evidence suggesting links between exposure to environmental toxins and susceptibility to type 2 diabetes mellitus (DM). In this review, we summarize the experimental evidence to support this association that has been noted in many epidemiologic studies. Inflammation in response to particulate matter (PM(2.5)) exposure in air pollution represents a common mechanism that may interact with other pro-inflammatory influences in diet and life style to modulate susceptibility to cardiometabolic diseases. The role of innate immune cytokines released from macrophages in the lung is well known. In addition, chemokine triggers in response to air-pollution exposure may mediate a cellular response from the bone marrow/spleen through toll-like receptors (TLRs) and Nucleotide Oligomerization Domain receptors (NLRs) pathways to mediate inflammatory response in organs. Emerging data also seem to support a role for PM(2.5) exposure in endoplasmic reticulum stress-induced apoptosis and in brown adipose tissue dysfunction. Decreased expression of UCP1 in brown adipose tissue may account for reduced thermogenesis providing another link between PM(2.5) and insulin resistance. The implications of an experimental link between air-pollution exposure and type 2 DM are profound as air pollution is a pervasive risk factor throughout the world and even modest alleviation in exposure may provide substantial public health benefits.

  10. Critical mass flux through short Borda type inlets of various cross sections

    NASA Technical Reports Server (NTRS)

    Hendricks, R. C.; Poolos, N. P.

    1979-01-01

    Mass flux measurements associated with chocked flows through four Borda type inlet geometries: circular, square, triangular and rectangular (two-dimensional) and two sharp edged geometries taken over a very wide range of inlet stagnation conditions. The measurements indicate that: (1) the mass flux is independent of the inlet cross-section geometry and (2) the mass flux is dependent only on the inlet stagnation conditions. Also by using choked flow results found in the literature, the reduced mass flux is independent of working fluid. Two implications are drawn which remain to be verified: (1) since seal leak rates are weakly dependent on geometry but pressure distribution is strongly dependent on geometry, seal design efforts should be directed more toward controlling the dynamics, and (2) high-L/D ducts of arbitrary cross section and Borda type inlets can possess free jets.

  11. The impact of mass flow and masking on the pressure drop of air filter in heavy-duty diesel engine

    NASA Astrophysics Data System (ADS)

    Hoseeinzadeh, Sepideh; Gorji-Bandpy, Mofid

    2012-04-01

    This paper presents a computational fluid dynamics (CFD) calculation approach to predict and evaluate the impact of the mass-flow inlet on the pressure drop of turbocharger`s air filtfer in heavy-duty diesel engine. The numerical computations were carried out using a commercial CFD program whereas the inlet area of the air filter consisted of several holes connected to a channel. After entering through the channel, the air passes among the holes and enters the air filter. The effect of masking holes and hydraulic diameter is studied and investigated on pressure drop. The results indicate that pressure drop increase with decreasing of hydraulic diameter and masking of the holes has considerable affect on the pressure drop.

  12. High resolution optical spectroscopy of air-induced electrical instabilities in n-type polymer semiconductors.

    PubMed

    Di Pietro, Riccardo; Sirringhaus, Henning

    2012-07-03

    We use high-resolution charge-accumulation optical spectroscopy to measure charge accumulation in the channel of an n-type organic field-effect transistor. We monitor the degradation of device performance in air, correlate the onset voltage shift with the reduction of charge accumulated in the polymer semiconductor, and explain the results in view of the redox reaction between the polymer, water and oxygen in the accumulation layer.

  13. Relationships of Type A Behavior with Biographical Characteristics and Training Performance of Air Traffic Controllers

    DTIC Science & Technology

    1994-07-01

    Helmreich, Beane , predictive of performance in the Academy screen and Lucker (1980), using the Jenkins Activity Survey, program. demonstrated that...Making it without losing it: Type A, achievement Matthews, K. A., Helmreich, R. L., Beane , W. F., & motivation, and scientific attainment revisited. Lucker...Aviation Medicine Report, the new aptitude testing procedures for selection DOT/ FAVA /A I-78-39. of FAA air traffic control specialists. In Schroeder, D. J

  14. The Black Hole Mass - Pitch Angle Relation of Type I AGN In Spiral Galaxies

    NASA Astrophysics Data System (ADS)

    Schilling, Amanda; Jones, Logan; Hughes, John A.; Barrows, R. Scott; Kennefick, Julia D.

    2017-01-01

    A relationship between the mass of supermassive black holes, M, at the center of galaxies and the pitch angle, P, a measure of tightness of spiral arms, was recently reported by Berrier, et al. (2013 ApJ 769, 132) for late type galaxies. The relationship, established for a local sample, shows that spiral galaxies with tighter pitch angles host higher mass black holes. In this work, we explore the M-P relation for a sample of 50 low to moderate redshift (0.04Type 1 Active Galactic Nuclei, AGN. These objects were selected from the SDSS quasar catalog and various studies involving HST imaging. Broad Hβ, Hα, and MgII and narrow [OIII]λ5007 emission lines were used with established mass scaling relations to estimate black-hole mass. Pitch angles were measured using a 2DFFT technique (Davis, et al., 2012 ApJS 199, 33). We find that the M-P relation for the higher redshift, AGN sample differs from that of the local sample and discuss the possibility of AGN feedback by looking at a proposed Fundamental Plane for late-type galaxies - a correlation between bulge mass, disk mass, and spiral-arm pitch angle (Davis, et al. 2015, ApJ 802, L13).

  15. Hole effective masses and subband splitting in type-II superlattice infrared detectors

    NASA Astrophysics Data System (ADS)

    Ting, David Z.; Soibel, Alexander; Gunapala, Sarath D.

    2016-05-01

    We explore band structure effects to help determine the suitability of n-type type-II superlattice (T2SL) absorbers for infrared detectors. It is often assumed that the exceedingly large growth-direction band-edge curvature hole effective mass in n-type long wavelength infrared (LWIR) T2SL would lead to low hole mobility and therefore low detector collection quantum efficiency. We computed the thermally averaged conductivity effective mass and show that the LWIR T2SL hole conductivity effective mass along the growth direction can be orders of magnitude smaller than the corresponding band-edge effective mass. LWIR InAs/GaSb T2SL can have significantly smaller growth-direction hole conductivity effective mass than its InAs/InAsSb counterpart. For the InAs/InAsSb T2SL, higher Sb fraction is more favorable for hole transport. Achieving long hole diffusion length becomes progressively more difficult for the InAs/InAsSb T2SL as the cutoff wavelength increases, since its growth-direction hole conductivity effective mass increases significantly with decreasing band gap. However, this is mitigated by the fact that the splitting between the top valence subbands also increases with the cutoff wavelength, leading to reduced inter-subband scattering and increased relaxation time.

  16. Effect of wheelchair mass, tire type and tire pressure on physical strain and wheelchair propulsion technique.

    PubMed

    de Groot, Sonja; Vegter, Riemer J K; van der Woude, Lucas H V

    2013-10-01

    The purpose of this study was to evaluate the effect of wheelchair mass, solid vs. pneumatic tires and tire pressure on physical strain and wheelchair propulsion technique. 11 Able-bodied participants performed 14 submaximal exercise blocks on a treadmill with a fixed speed (1.11 m/s) within 3 weeks to determine the effect of tire pressure (100%, 75%, 50%, 25% of the recommended value), wheelchair mass (0 kg, 5 kg, or 10 kg extra) and tire type (pneumatic vs. solid). All test conditions (except pneumatic vs. solid) were performed with and without instrumented measurement wheels. Outcome measures were power output (PO), physical strain (heart rate (HR), oxygen uptake (VO2), gross mechanical efficiency (ME)) and propulsion technique (timing, force application). At 25% tire pressure PO and subsequently VO2 were higher compared to 100% tire pressure. Furthermore, a higher tire pressure led to a longer cycle time and contact angle and subsequently lower push frequency. Extra mass did not lead to an increase in PO, physical strain or propulsion technique. Solid tires led to a higher PO and physical strain. The solid tire effect was amplified by increased mass (tire × mass interaction). In contrast to extra mass, tire pressure and tire type have an effect on PO, physical strain or propulsion technique of steady-state wheelchair propulsion. As expected, it is important to optimize tire pressure and tire type.

  17. Background NO/sub x/ mixing ratios in air masses over the North Atlantic ocean

    SciTech Connect

    Helas, G.; Warneck, P.

    1981-08-20

    A chemiluminescence analyzer was used to measure NO/sub x/ mixing ratios at the west coast of Ireland. Two measurement modes allowed the determination of NO and NO/sub x/ = NO+NO/sub 2/. In a third mode using a molybdenum converter, higher signals were observed than was in the second mode indicating that nitrogen compounds other than NO+NO/sub 2/ are registered. They are denoted 'excess NO/sub x/'. The average NO/sub 2/ mixing ratio for a week period was 101 +- 87 pptv. In pure marine air masses identified by means of trajectory calculations, the NO/sub 2/ mixing ratios were lower and exhibited in addition a diurnal variation with nighttime values of 37 +- 6 pptv and average values of 87 +- 47 pptv. Possible origins of the diurnal variation are discussed. For such conditions, the NO mixing ratio generally was unmeasurably small, certainly less than 10 pptv. The excess NO/sub x/ is also higher during the day compared with nighttime values of about 70 pptv. Further studies are required to identify the compounds involved.

  18. Northern East Asian Monsoon Precipitation Revealed by Air Mass Variability and Its Prediction

    NASA Astrophysics Data System (ADS)

    Son, J. H.; Seo, K. H.

    2015-12-01

    This work provides a new perspective on the major factors controlling the East Asian summer monsoon (EASM) in July, and a promising physical-statistical forecasting of the EASM ahead of summer. Dominant modes of the EASM are revealed from the variability of large-scale air masses discerned by equivalent potential temperature, and are found to be dynamically connected with the anomalous sea surface temperatures (SSTs) over the three major oceans of the world and their counterparts of prevailing atmospheric oscillation or teleconnection patterns. Precipitation over Northeast Asia (NEA) during July is enhanced by the tropical central Indian Ocean warming and central Pacific El Niño-related SST warming, the northwestern Pacific cooling off the coast of NEA, and the North Atlantic Ocean warming. Using these factors and data from the preceding spring seasons, the authors build a multiple linear regression model for seasonal forecasting. The cross-validated correlation skill predicted for the period 1994 to 2012 is up to 0.84, which far exceeds the skill level of contemporary climate models.

  19. Inverse Estimation of SO2 Emissions over China with Local Air Mass Factor Applied

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Wang, J.; Xu, X.; Henze, D. K.

    2015-12-01

    Sulfur dioxide (SO2) has significant impacts on human health as it forms sulfate aerosols in the atmosphere. Widespread uncertainty in the magnitude of SO2 emissions hinders efforts to address this issue. In this work we use Ozone Monitoring Instrument (OMI) slant column SO2 observations as constraints to conduct inversion of SO2 emissions over China for April 2008. Local air mass factors are formulated as the integral of the relative vertical distribution of SO2 simulated from GEOS-Chem, weighted by scattering weights computed from VLIDORT. They are applied to convert slant column to vertical column GEOS-Chem SO2. After data assimilation SO2 emissions decrease in Sichuan Basin, South China, and most areas of North China. The posterior SO2 emissions are evaluated with in situ SO2 observation. Besides, we apply the posterior SO2 emissions of April 2008 to April 2009, and it leads to improved agreement of modeled SO2 to the OMI observations. This offers potential to update SO2 emissions in real time.

  20. A SINGLE DEGENERATE PROGENITOR MODEL FOR TYPE Ia SUPERNOVAE HIGHLY EXCEEDING THE CHANDRASEKHAR MASS LIMIT

    SciTech Connect

    Hachisu, Izumi; Kato, Mariko; Saio, Hideyuki; Nomoto, Ken'ichi E-mail: mariko@educ.cc.keio.ac.jp E-mail: nomoto@astron.s.u-tokyo.ac.jp

    2012-01-01

    Recent observations of Type Ia supernovae (SNe Ia) suggest that some of the progenitor white dwarfs (WDs) had masses up to 2.4-2.8 M{sub Sun }, highly exceeding the Chandrasekhar mass limit. We present a new single degenerate model for SN Ia progenitors, in which the WD mass possibly reaches 2.3-2.7 M{sub Sun }. Three binary evolution processes are incorporated: optically thick winds from mass-accreting WDs, mass stripping from the binary companion star by the WD winds, and WDs being supported by differential rotation. The WD mass can increase by accretion up to 2.3 (2.7) M{sub Sun} from the initial value of 1.1 (1.2) M{sub Sun }, consistent with high-luminosity SNe Ia, such as SN 2003fg, SN 2006gz, SN 2007if, and SN 2009dc. There are three characteristic mass ranges of exploding WDs. In the extreme massive case, differentially rotating WDs explode as an SN Ia soon after the WD mass exceeds 2.4 M{sub Sun} because of a secular instability at T/|W| {approx} 0.14. For the mid-mass range of M{sub WD} = 1.5-2.4 M{sub Sun }, it takes some time (spinning-down time) until carbon is ignited to induce an SN Ia explosion after the WD mass has reached maximum, because it needs a loss or redistribution of angular momentum. For the lower mass case of rigidly rotating WDs, M{sub WD} = 1.38-1.5 M{sub Sun }, the spinning-down time depends on the timescale of angular momentum loss from the WD. The difference in the spinning-down time may produce the 'prompt' and 'tardy' components. We also suggest that the very bright super-Chandrasekhar mass SNe Ia are born in a low-metallicity environment.

  1. Systematic variation of the stellar initial mass function in early-type galaxies.

    PubMed

    Cappellari, Michele; McDermid, Richard M; Alatalo, Katherine; Blitz, Leo; Bois, Maxime; Bournaud, Frédéric; Bureau, M; Crocker, Alison F; Davies, Roger L; Davis, Timothy A; de Zeeuw, P T; Duc, Pierre-Alain; Emsellem, Eric; Khochfar, Sadegh; Krajnović, Davor; Kuntschner, Harald; Lablanche, Pierre-Yves; Morganti, Raffaella; Naab, Thorsten; Oosterloo, Tom; Sarzi, Marc; Scott, Nicholas; Serra, Paolo; Weijmans, Anne-Marie; Young, Lisa M

    2012-04-25

    Much of our knowledge of galaxies comes from analysing the radiation emitted by their stars, which depends on the present number of each type of star in the galaxy. The present number depends on the stellar initial mass function (IMF), which describes the distribution of stellar masses when the population formed, and knowledge of it is critical to almost every aspect of galaxy evolution. More than 50 years after the first IMF determination, no consensus has emerged on whether it is universal among different types of galaxies. Previous studies indicated that the IMF and the dark matter fraction in galaxy centres cannot both be universal, but they could not convincingly discriminate between the two possibilities. Only recently were indications found that massive elliptical galaxies may not have the same IMF as the Milky Way. Here we report a study of the two-dimensional stellar kinematics for the large representative ATLAS(3D) sample of nearby early-type galaxies spanning two orders of magnitude in stellar mass, using detailed dynamical models. We find a strong systematic variation in IMF in early-type galaxies as a function of their stellar mass-to-light ratios, producing differences of a factor of up to three in galactic stellar mass. This implies that a galaxy's IMF depends intimately on the galaxy's formation history.

  2. Disrupted Nitric Oxide Metabolism from Type II Diabetes and Acute Exposure to Particulate Air Pollution.

    PubMed

    Pettit, Ashley P; Kipen, Howard; Laumbach, Robert; Ohman-Strickland, Pamela; Kelly-McNeill, Kathleen; Cepeda, Clarimel; Fan, Zhi-Hua; Amorosa, Louis; Lubitz, Sara; Schneider, Stephen; Gow, Andrew

    2015-01-01

    Type II diabetes is an established cause of vascular impairment. Particulate air pollution is known to exacerbate cardiovascular and respiratory conditions, particularly in susceptible populations. This study set out to determine the impact of exposure to traffic pollution, with and without particle filtration, on vascular endothelial function in Type II diabetes. Endothelial production of nitric oxide (NO) has previously been linked to vascular health. Reactive hyperemia induces a significant increase in plasma nitrite, the proximal metabolite of NO, in healthy subjects, while diabetics have a lower and more variable level of response. Twenty type II diabetics and 20 controls (ages 46-70 years) were taken on a 1.5 hr roadway traffic air pollution exposure as passengers. We analyzed plasma nitrite, as a measure of vascular function, using forearm ischemia to elicit a reactive hyperemic response before and after exposure to one ride with and one without filtration of the particle components of pollution. Control subjects displayed a significant increase in plasma nitrite levels during reactive hyperemia. This response was no longer present following exposure to traffic air pollution, but did not vary with whether or not the particle phase was filtered out. Diabetics did not display an increase in nitrite levels following reactive hyperemia. This response was not altered following pollution exposure. These data suggest that components of acute traffic pollution exposure diminish vascular reactivity in non-diabetic individuals. It also confirms that type II diabetics have a preexisting diminished ability to appropriately respond to a vascular challenge, and that traffic pollution exposure does not cause a further measureable acute change in plasma nitrite levels in Type II diabetics.

  3. Disrupted Nitric Oxide Metabolism from Type II Diabetes and Acute Exposure to Particulate Air Pollution

    PubMed Central

    Pettit, Ashley P.; Kipen, Howard; Laumbach, Robert; Ohman-Strickland, Pamela; Kelly-McNeill, Kathleen; Cepeda, Clarimel; Fan, Zhi-Hua; Amorosa, Louis; Lubitz, Sara; Schneider, Stephen; Gow, Andrew

    2015-01-01

    Type II diabetes is an established cause of vascular impairment. Particulate air pollution is known to exacerbate cardiovascular and respiratory conditions, particularly in susceptible populations. This study set out to determine the impact of exposure to traffic pollution, with and without particle filtration, on vascular endothelial function in Type II diabetes. Endothelial production of nitric oxide (NO) has previously been linked to vascular health. Reactive hyperemia induces a significant increase in plasma nitrite, the proximal metabolite of NO, in healthy subjects, while diabetics have a lower and more variable level of response. Twenty type II diabetics and 20 controls (ages 46–70 years) were taken on a 1.5hr roadway traffic air pollution exposure as passengers. We analyzed plasma nitrite, as a measure of vascular function, using forearm ischemia to elicit a reactive hyperemic response before and after exposure to one ride with and one without filtration of the particle components of pollution. Control subjects displayed a significant increase in plasma nitrite levels during reactive hyperemia. This response was no longer present following exposure to traffic air pollution, but did not vary with whether or not the particle phase was filtered out. Diabetics did not display an increase in nitrite levels following reactive hyperemia. This response was not altered following pollution exposure. These data suggest that components of acute traffic pollution exposure diminish vascular reactivity in non-diabetic individuals. It also confirms that type II diabetics have a preexisting diminished ability to appropriately respond to a vascular challenge, and that traffic pollution exposure does not cause a further measureable acute change in plasma nitrite levels in Type II diabetics. PMID:26656561

  4. Identification and design principles of low hole effective mass p-type transparent conducting oxides

    PubMed Central

    Hautier, Geoffroy; Miglio, Anna; Ceder, Gerbrand; Rignanese, Gian-Marco; Gonze, Xavier

    2013-01-01

    The development of high-performance transparent conducting oxides is critical to many technologies from transparent electronics to solar cells. Whereas n-type transparent conducting oxides are present in many devices, their p-type counterparts are not largely commercialized, as they exhibit much lower carrier mobilities due to the large hole effective masses of most oxides. Here we conduct a high-throughput computational search on thousands of binary and ternary oxides and identify several highly promising compounds displaying exceptionally low hole effective masses (up to an order of magnitude lower than state-of-the-art p-type transparent conducting oxides), as well as wide band gaps. In addition to the discovery of specific compounds, the chemical rationalization of our findings opens new directions, beyond current Cu-based chemistries, for the design and development of future p-type transparent conducting oxides. PMID:23939205

  5. Computational model of collisional-radiative nonequilibrium plasma in an air-driven type laser propulsion

    SciTech Connect

    Ogino, Yousuke; Ohnishi, Naofumi

    2010-05-06

    A thrust power of a gas-driven laser-propulsion system is obtained through interaction with a propellant gas heated by a laser energy. Therefore, understanding the nonequilibrium nature of laser-produced plasma is essential for increasing available thrust force and for improving energy conversion efficiency from a laser to a propellant gas. In this work, a time-dependent collisional-radiative model for air plasma has been developed to study the effects of nonequilibrium atomic and molecular processes on population densities for an air-driven type laser propulsion. Many elementary processes are considered in the number density range of 10{sup 12}/cm{sup 3}<=N<=10{sup 19}/cm{sup 3} and the temperature range of 300 K<=T<=40,000 K. We then compute the unsteady nature of pulsively heated air plasma. When the ionization relaxation time is the same order as the time scale of a heating pulse, the effects of unsteady ionization are important for estimating air plasma states. From parametric computations, we determine the appropriate conditions for the collisional-radiative steady state, local thermodynamic equilibrium, and corona equilibrium models in that density and temperature range.

  6. FU Ori-type outburst of 2MASS J06593158-0405277

    NASA Astrophysics Data System (ADS)

    Maehara, Hiroyuki; Kojima, Tadashi; Fujii, Mitsugu

    2014-11-01

    We report the discovery of an FU Ori-type outburst of 2MASS J06593158-0405277. The outburst was discovered by T. Kojima from the survey image obtained with a 85mm f/2.8 lens and Canon EOS 60D DSLR camera on 2014-11-03.821 UT at mag 11.0.

  7. Near-IR photometric monitoring of FU Ori Type Object 2MASS J06593158-0405277

    NASA Astrophysics Data System (ADS)

    Varricatt, W. P.; Carroll, T.; Moore, E.; Benigni, S.

    2015-05-01

    Maehara, Kojima, and Fujii (ATel #6770) discovered a recent FU Ori-type outburst in 2MASS J06593158-0405277. High resolution spectroscopic follow up by Hillenbrand (ATel #6797) confirmed its FU Ori nature, and discovered P-Cygni profile for H alpha line and blue-shifted absorption for other hydrogen lines.

  8. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    SciTech Connect

    Morrison, Glenn Charles

    1999-12-01

    -7, 10-5, and 10-5 respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10-5, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.

  9. Formation and evolution of molecular hydrogen in disc galaxies with different masses and Hubble types

    NASA Astrophysics Data System (ADS)

    Bekki, Kenji

    2014-10-01

    We investigate the physical properties of molecular hydrogen (H2) in isolated and interacting disc galaxies with different masses and Hubble types by using chemodynamical simulations with H2 formation on dust grains and dust growth and destruction in interstellar medium. We particularly focus on the dependences of H2 gas mass fractions (f_H_2), spatial distributions of H I and H2, and local H2-scaling relations on initial halo masses (Mh), baryonic fractions (fbary), gas mass fractions (fg), and Hubble types. The principal results are as follows. The final f_H_2 can be larger in disc galaxies with higher Mh, fbary, and fg. Some low-mass disc models with Mh smaller than 1010 M⊙ show extremely low f_H_2 and thus no/little star formation, even if initial fg is quite large (>0.9). Big galactic bulges can severely suppress the formation of H2 from H I on dust grains whereas strong stellar bars cannot only enhance f_H_2 but also be responsible for the formation of H2-dominated central rings. The projected radial distributions of H2 are significantly more compact than those of H I and the simulated radial profiles of H2-to-H I-ratios (Rmol) follow roughly R-1.5 in Milky Way-type disc models. Galaxy interaction can significantly increase f_H_2 and total H2 mass in disc galaxies. The local surface mass densities of H2 can be correlated with those of dust in a galaxy. The observed correlation between Rmol and gas pressure (R_mol ∝ P_g^{0.92}) can be well reproduced in the simulated disc galaxies.

  10. Evolved Late-Type Star FUV Spectra: Mass Loss and Fluorescence

    NASA Technical Reports Server (NTRS)

    Harper, Graham M.

    2005-01-01

    This proposal was for a detailed analysis of the far ultraviolet (FUV) photoionizing radiation that provides crucial input physics for mass loss studies, e.g., observations of the flux below 10448, allow us to constrain the Ca II/Ca III balance and make significant progress beyond previous optical studies on stellar mass loss and circumstellar photochemistry. Our targets selection provided good spectral-type coverage required to help unravel the Ca II/Ca III balance as the mass-loss rates increase by over three orders of magnitude from K5 III to M5 III. We also explored the relationship between the FUV radiation field and other UV diagnostics to allow us to empirically estimate the FUV radiation field for the vast majority of stars which are too faint to be observed with FUSE, and to improve upon their uncertain mass-loss rates.

  11. Change of microbial communities in glaciers along a transition of air masses in western China

    NASA Astrophysics Data System (ADS)

    Xiang, Shu-Rong; Chen, Yong; Shang, Tian-Cui; Jing, Ze-Fan; Wu, Guangjian

    2010-12-01

    Microbial community dynamics across glaciers in different climatic zones provide important information about the sources, transportation pathways, and deposition of microorganisms. To better understand the possible driving forces of microbial community shifts in glacier ice at a large spatial scale, 16S rRNA gene amplification was used to establish clone libraries containing 95 bacterial sequences from three different habitats in the Qiangyong Gacier in 2005. The libraries were used in phylogenetic comparison with 149 previously reported sequences from the surface samples collected from the Kuytun 51, and East Rongbuk glaciers in the same year. The results showed the presence of cosmopolitan and endemic species, and displayed a tendency of zonal distribution of bacterial communities at genera and community levels, corresponding to the geographic placement of the three glaciers. Data also showed a significant difference in the proportion of dominant phylogenetic groups in the three glaciers. Comamonadaceae/Polaromonas (Betaproteobacteria) and Flexibacteraceae (Bacteroidetes) were dominant in the Qiangyong Glacier, Cyanobacteria, Comamonadaceae/Polaromonas, and Rhodoferax (Betaproteobacteria) were dominant in the Kuytun 51 Glacier, and Acinetobacteria (Gammaproteobacteria) were dominant in the Rongbuk Glacier. In conclusion, the current study provides evidence of microbial biogeography in glacier ice at both the fine lineage and whole community levels. The biogeographical patterns were generally associated with the hydrological transition over the glaciers in the northern periphery and southern part of the Tibetan plateau. This supports our hypothesis of air mass behavior being one of the main drivers determining the zonal distribution of microbial communities across the mountain glaciers in western China.

  12. Climatology of wintertime long-distance transport of surface-layer air masses arriving urban Beijing in 2001-2012

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xiang-De, XU

    2017-02-01

    In this study, the FLEXPART-WRF coupled modeling system is used to conduct 12-year Lagrangian modeling over Beijing, China, for the winters of 2001-2012. Based on large trajectory tracking ensembles, the long-range air transport properties, in terms of geographic source regions within the atmospheric planetary boundary layer (PBL) and large-scale ventilation, and its association with air quality levels were quantified from a climatological perspective. The results show the following: (1) The air masses residing in the near-surface layer over Beijing potentially originate from broader atmospheric boundary-layer regions, which cover vast areas with the backward tracking time elapsed. However, atmospheric transport from northeastern China and, to a lesser extent, from the surrounding regions of Beijing is important. (2) The evolution of air quality over Beijing is negatively correlated with large-scale ventilation conditions, particularly at a synoptic timescale. Thus, the simple but robust backward-trajectory ventilation (BV) index defined in this study could facilitate operational forecasting of severe air pollution events. (3) By comparison, the relatively short-range transport occurring over transport timescales of less than 3 days from southern and southeastern Beijing and its surrounding areas plays a vital role in the formation of severe air pollution events during the wintertime. (4) Additionally, an interannual trend analysis suggests that the geographic sources and ventilation conditions also changed, at least over the last decade, corresponding to the strength variability of the winter East Asian monsoon.

  13. SUPER-CHANDRASEKHAR-MASS LIGHT CURVE MODELS FOR THE HIGHLY LUMINOUS TYPE Ia SUPERNOVA 2009dc

    SciTech Connect

    Kamiya, Yasuomi; Tanaka, Masaomi; Nomoto, Ken'ichi; Blinnikov, Sergei I.; Sorokina, Elena I.; Suzuki, Tomoharu

    2012-09-10

    Several highly luminous Type Ia supernovae (SNe Ia) have been discovered. Their high luminosities are difficult to explain with the thermonuclear explosions of Chandrasekhar-mass white dwarfs (WDs). In the present study, we estimate the progenitor mass of SN 2009dc, one of the extremely luminous SNe Ia, using the hydrodynamical models as follows. Explosion models of super-Chandrasekhar-mass (super-Ch-mass) WDs are constructed, and multi-color light curves (LCs) are calculated. The comparison between our calculations and the observations of SN 2009dc suggests that the exploding WD has a super-Ch mass of 2.2-2.4 M{sub Sun }, producing 1.2-1.4 M{sub Sun} of {sup 56}Ni, if the extinction by its host galaxy is negligible. If the extinction is significant, the exploding WD is as massive as {approx}2.8 M{sub Sun }, and {approx}1.8 M{sub Sun} of {sup 56}Ni is necessary to account for the observations. Whether the host-galaxy extinction is significant or not, the progenitor WD must have a thick carbon-oxygen layer in the outermost zone (20%-30% of the WD mass), which explains the observed low expansion velocity of the ejecta and the presence of carbon. Our estimate of the mass of the progenitor WD, especially for the extinction-corrected case, is challenging to the current scenarios of SNe Ia. Implications for the progenitor scenarios are also discussed.

  14. Characteristics of flares producing metric type II bursts and coronal mass ejections

    NASA Technical Reports Server (NTRS)

    Kahler, S.; Sheeley, N. R., Jr.; Howard, R. A.; Michels, D. J.; Koomen, M. J.

    1984-01-01

    An attempt is made to study the origin of coronal shocks by comparing several flare characteristics for two groups of flares: those with associated metric type II bursts and coronal mass ejections (CMEs) and those with associated metric type II bursts but no CMEs. CMEs accompany about 60 percent of all flares with type II bursts for solar longitudes greater than 30 deg, where CMEs are well observed with the NRL Solwind coronagraph. H-alpha flare areas, 1-8 A X-ray fluxes, and impulsive 3-cm fluxes are all statistically smaller for events with no CMEs than for events with CMEs. It appears that both compact and large mass ejection flares are associated with type II bursts. The events with no CMEs imply that at least many type II shocks are not piston-driven, but the large number of events of both groups with small 3 cm bursts does not support the usual assumption that type II shocks are produced by large energy releases in flare impulsive phases. The poor correlation between 3 cm burst fluxes and the occurrence of type II bursts may be due to large variations in the coronal Alfven velocity.

  15. Simultaneous determination of aliphatic and aromatic amines in ambient air and airborne particulate matters by gas chromatography-mass spectrometry

    NASA Astrophysics Data System (ADS)

    Akyüz, Mehmet

    2008-05-01

    A gas chromatography-mass spectrometry (GC-MS) method has been proposed for the simultaneous determination of aliphatic and aromatic amines in ambient air and airborne particulate matters (PMs). The method includes collection of the particulate matters (PM2.5 and PM10) using dichotomous Partisol 2025 sampler followed by extraction of the compounds into acidic solution, and pre-concentration of the compounds by percolating the air samples through the acidic solution, then ion-pair extraction of amines with bis-2-ethylhexylphosphate and derivatisation with isobutyl chloroformate prior to their GC-MS analysis in both electron impact and positive and negative ion chemical ionisation mode as their isobutyloxycarbonyl (isoBOC) derivatives. In the present study, ambient air and airborne particulate samples collected in Zonguldak province during summer and winter times of 2006-2007 were analysed for aliphatic and aromatic amines by the proposed method and the method was shown to be suitable for the simultaneous determination of these compounds at the levels of pg m-3 in air and airborne particulate samples. The seasonal distributions of bioactive amines in concentrations in ambient air and airborne PMs were evaluated as they are significant for the estimation of their effects on the environment and human health. The concentration levels of water soluble amines fluctuate significantly within a year with higher means and peak concentrations, probably due to the increased emissions from coal-fired domestic and central heating, in the winter times compared to the summer times. The results indicated that the relative amine content in particulates modulates with molecular mass and time of the year and the relative amine content especially in fine fractions of inhalable airborne particulates increases with the molecular mass of species but decreases with temperature.

  16. Screening for sarin in air and water by solid-phase microextraction-gas chromatography-mass spectrometry.

    PubMed

    Schneider, J F; Boparai, A S; Reed, L L

    2001-10-01

    A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 microg/mL or higher. This method is ideal for screening samples for quick response situations.

  17. Screening for sarin in air and water by solid-phase microextraction-gas chromatography/mass spectrometry.

    SciTech Connect

    Schneider, J. F.; Boparai, A. S.; Reed, L. L.

    2001-10-01

    A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 {mu}g/mL or higher. This method is ideal for screening samples for quick response situations.

  18. NON-EQUIPARTITION OF ENERGY, MASSES OF NOVA EJECTA, AND TYPE Ia SUPERNOVAE

    SciTech Connect

    Shara, Michael M.; Yaron, Ofer; Prialnik, Dina; Kovetz, Attay

    2010-04-01

    The total masses ejected during classical nova (CN) eruptions are needed to answer two questions with broad astrophysical implications: can accreting white dwarfs be 'pushed over' the Chandrasekhar mass limit to yield type Ia supernovae? Are ultra-luminous red variables a new kind of astrophysical phenomenon, or merely extreme classical novae? We review the methods used to determine nova ejecta masses. Except for the unique case of BT Mon (nova 1939), all nova ejecta mass determinations depend on untested assumptions and multi-parameter modeling. The remarkably simple assumption of equipartition between kinetic and radiated energy (E {sub kin} and E {sub rad}, respectively) in nova ejecta has been invoked as a way around this conundrum for the ultra-luminous red variable in M31. The deduced mass is far larger than that produced by any CN model. Our nova eruption simulations show that radiation and kinetic energy in nova ejecta are very far from being in energy equipartition, with variations of 4 orders of magnitude in the ratio E {sub kin}/E {sub rad} being commonplace. The assumption of equipartition must not be used to deduce nova ejecta masses; any such 'determinations' can be overestimates by a factor of up to 10,000. We data-mined our extensive series of nova simulations to search for correlations that could yield nova ejecta masses. Remarkably, the mass ejected during a nova eruption is dependent only on (and is directly proportional to) E {sub rad}. If we measure the distance to an erupting nova and its bolometric light curve, then E {sub rad} and hence the mass ejected can be directly measured.

  19. Mass

    SciTech Connect

    Quigg, Chris

    2007-12-05

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  20. Endotoxins are associated with visceral fat mass in type 1 diabetes

    PubMed Central

    Lassenius, Mariann I.; Ahola, Aila J.; Harjutsalo, Valma; Forsblom, Carol; Groop, Per-Henrik; Lehto, Markku

    2016-01-01

    Bacterial lipopolysaccharides (LPS), potent inducers of inflammation, have been associated with chronic metabolic disturbances. Obesity is linked to dyslipidemia, increased body adiposity, and endotoxemia. We investigated the cross-sectional relationships between serum LPS activity and body adiposity as well as inflammation in 242 subjects with type 1 diabetes. Body fat distribution was measured by DXA and serum LPS activity by the limulus amebocyte lysate end-point assay. Since no interaction between visceral fat mass and sex was observed, data were pooled for the subsequent analyses. LPS was independently associated with visceral fat mass, when adjusted for traditional risk factors (age, sex, kidney status, hsCRP, insulin sensitivity). In the multivariate analysis, serum LPS activity and triglyceride concentrations had a joint effect on visceral fat mass, independent of these factors alone. A combination of high LPS and high hsCRP concentrations was also observed in those with the largest visceral fat mass. In conclusion, high serum LPS activity levels were associated with visceral fat mass in subjects with type 1 diabetes strengthening its role in the development of central obesity, inflammation and insulin resistance. PMID:27958332

  1. Water-Processable, Air-Stable Organic Nanoparticle-Carbon Nanotube Nanocomposites Exhibiting n-Type Thermoelectric Properties.

    PubMed

    Nonoguchi, Yoshiyuki; Tani, Atsushi; Ikeda, Tomohiro; Goto, Chigusa; Tanifuji, Naoki; Uda, Ryoko M; Kawai, Tsuyoshi

    2017-03-01

    Water-dispersed organic base nanoparticles are utilized for the highly stable n-type doping of single-walled carbon nanotubes in aqueous dispersion. Long-term stability is often a critical challenge in the application of n-type organic conductors. The present n-type organic materials exhibit almost no degradation in the thermoelectric properties over months, in air.

  2. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

    PubMed Central

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-01-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

  3. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

    PubMed

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-11-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

  4. 42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static...) per minute shall not exceed the static pressure in the facepiece by more than 51 mm. (2 inches)...

  5. Reduced bone mass and muscle strength in male 5α-reductase type 1 inactivated mice.

    PubMed

    Windahl, Sara H; Andersson, Niklas; Börjesson, Anna E; Swanson, Charlotte; Svensson, Johan; Movérare-Skrtic, Sofia; Sjögren, Klara; Shao, Ruijin; Lagerquist, Marie K; Ohlsson, Claes

    2011-01-01

    Androgens are important regulators of bone mass but the relative importance of testosterone (T) versus dihydrotestosterone (DHT) for the activation of the androgen receptor (AR) in bone is unknown. 5α-reductase is responsible for the irreversible conversion of T to the more potent AR activator DHT. There are two well established isoenzymes of 5α-reductase (type 1 and type 2), encoded by separate genes (Srd5a1 and Srd5a2). 5α-reductase type 2 is predominantly expressed in male reproductive tissues whereas 5α-reductase type 1 is highly expressed in liver and moderately expressed in several other tissues including bone. The aim of the present study was to investigate the role of 5α-reductase type 1 for bone mass using Srd5a1⁻/⁻ mice. Four-month-old male Srd5a1⁻/⁻ mice had reduced trabecular bone mineral density (-36%, p<0.05) and cortical bone mineral content (-15%, p<0.05) but unchanged serum androgen levels compared with wild type (WT) mice. The cortical bone dimensions were reduced in the male Srd5a1⁻/⁻ mice as a result of a reduced cortical periosteal circumference compared with WT mice. T treatment increased the cortical periosteal circumference (p<0.05) in orchidectomized WT mice but not in orchidectomized Srd5a1⁻/⁻ mice. Male Srd5a1⁻/⁻ mice demonstrated a reduced forelimb muscle grip strength compared with WT mice (p<0.05). Female Srd5a1⁻/⁻ mice had slightly increased cortical bone mass associated with elevated circulating levels of androgens. In conclusion, 5α-reductase type 1 inactivated male mice have reduced bone mass and forelimb muscle grip strength and we propose that these effects are due to lack of 5α-reductase type 1 expression in bone and muscle. In contrast, the increased cortical bone mass in female Srd5a1⁻/⁻ mice, is an indirect effect mediated by elevated circulating androgen levels.

  6. [Studies on the performance of the dental air turbine handpieces. (Part 1). Air pressure and bur length to be influenced over the rotational performance of the air bearing type handpieces (author's transl)].

    PubMed

    Miyairi, H; Muramatsu, A

    1979-07-01

    Air turbine handpieces are used as the dental cutting instruments for the clinical use and many appliances. But, there are no studies on the performance of air turbine handpieces. So, this paper shows the rotational performance of air turbine handpieces which are influenced over the supplying air pressure and cutting bur length. Experimentally used air turbine handpieces is air bearing type and it's set up air pressure to be supplied is 3.5 kg/cm2. So, in this experiments, the range of air pressure is 1.8 approximately 3.5 kg/cm2, which is established five stages. And the bur length of the rotational parts is 5 approximately 9 mm with five steps. As the results, the rotational performance of air handpieces are influenced over these factors of the air pressure and the bur length. And air pressure to be supplied are influenced to be not only over the rotational speed but the load for the putting a stop to the revolutions.

  7. Linear and cyclic methylsiloxanes in air by concurrent solvent recondensation-large volume injection-gas chromatography-mass spectrometry.

    PubMed

    Companioni-Damas, E Y; Santos, F J; Galceran, M T

    2014-01-01

    In the present work, a simple and fast method for the analysis of linear and cyclic methylsiloxanes in ambient air based on active sampling combined with gas chromatography - mass spectrometry (GC-MS) was developed. The retention efficiency of five sampling sorbents (activated coconut charcoal, Carbopack B, Cromosorb 102, Cromosorb 106 and Isolute ENV+) was evaluated and Isolute ENV+ was found to be the most effective. A volume of 2700 L of air can be sampled without significant losses of the most volatile methylsiloxanes. To improve the sensitivity of the GC-MS method, concurrent solvent recondensation - large volume injection (CSR-LVI), using volumes up to 30 µl of sample extract, is proposed and limits of quantification down to 0.03-0.45 ng m(-3), good linearity (r>0.999) and precision (RSD %<9%) were obtained. The developed method was applied to the analysis of ambient air. Concentrations of linear and cyclic methylsiloxanes in indoor air ranging from 3.9 to 319 ng m(-3) and between 48 and 292668 ng m(-3), were obtained, respectively, while levels from 6 to 22 ng m(-3) for linear and between 2.2 and 439 ng m(-3) for cyclic methylsiloxanes in outdoor air from Barcelona (Spain), were found.

  8. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-03-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. OMI observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the tropospheric NO2 AMF calculation by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model for cloud-free scenes. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation (SD) of the difference was 0.6 ± 8%. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 72% of the daily OMAERUV AOD observations were within 0.3 of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10% higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30%, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and explicit aerosol parameters is on average 6 and 3

  9. Structural uncertainty in air mass factor calculation for NO2 and HCHO satellite retrievals

    NASA Astrophysics Data System (ADS)

    Lorente, Alba; Folkert Boersma, K.; Yu, Huan; Dörner, Steffen; Hilboll, Andreas; Richter, Andreas; Liu, Mengyao; Lamsal, Lok N.; Barkley, Michael; De Smedt, Isabelle; Van Roozendael, Michel; Wang, Yang; Wagner, Thomas; Beirle, Steffen; Lin, Jin-Tai; Krotkov, Nickolay; Stammes, Piet; Wang, Ping; Eskes, Henk J.; Krol, Maarten

    2017-03-01

    Air mass factor (AMF) calculation is the largest source of uncertainty in NO2 and HCHO satellite retrievals in situations with enhanced trace gas concentrations in the lower troposphere. Structural uncertainty arises when different retrieval methodologies are applied within the scientific community to the same satellite observations. Here, we address the issue of AMF structural uncertainty via a detailed comparison of AMF calculation methods that are structurally different between seven retrieval groups for measurements from the Ozone Monitoring Instrument (OMI). We estimate the escalation of structural uncertainty in every sub-step of the AMF calculation process. This goes beyond the algorithm uncertainty estimates provided in state-of-the-art retrievals, which address the theoretical propagation of uncertainties for one particular retrieval algorithm only. We find that top-of-atmosphere reflectances simulated by four radiative transfer models (RTMs) (DAK, McArtim, SCIATRAN and VLIDORT) agree within 1.5 %. We find that different retrieval groups agree well in the calculations of altitude resolved AMFs from different RTMs (to within 3 %), and in the tropospheric AMFs (to within 6 %) as long as identical ancillary data (surface albedo, terrain height, cloud parameters and trace gas profile) and cloud and aerosol correction procedures are being used. Structural uncertainty increases sharply when retrieval groups use their preference for ancillary data, cloud and aerosol correction. On average, we estimate the AMF structural uncertainty to be 42 % over polluted regions and 31 % over unpolluted regions, mostly driven by substantial differences in the a priori trace gas profiles, surface albedo and cloud parameters. Sensitivity studies for one particular algorithm indicate that different cloud correction approaches result in substantial AMF differences in polluted conditions (5 to 40 % depending on cloud fraction and cloud pressure, and 11 % on average) even for low

  10. International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

    PubMed

    Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

    2014-08-05

    Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

  11. Stability of reference masses: VII. Cleaning methods in air and vacuum applied to a platinum mass standard similar to the international and national kilogram prototypes

    NASA Astrophysics Data System (ADS)

    Cumpson, Peter J.; Sano, Naoko; Barlow, Anders J.; Portoles, Jose F.

    2013-10-01

    Mercury contamination and the build-up of carbonaceous contamination are two contributing factors to the instability observed in kilogram prototype masses. The kilogram prototypes that lie at the core of the dissemination of the SI base unit were manufactured in the late 19th century, and have polished surfaces. In papers IV and V of this series we developed a method for cleaning noble metal mass standards in air to remove carbonaceous contamination. At the core of this ‘UVOPS’ protocol is the application of UV light and ozone gas generated in situ in air. The precise nature of the carbonaceous contamination that builds up on such surfaces is difficult to mimic demonstrably or quickly on new test surfaces, yet data from such tests are needed to provide the final confidence to allow UVOPS to be applied to a real 19th century kilogram prototype. Therefore, in the present work we have applied the UVOPS method to clean a platinum avoirdupois pound mass standard, ‘RS2’, manufactured in the mid-19th century. This is thought to have been polished in a similar manner to the kilogram prototypes. To our knowledge this platinum surface has not previously been cleaned by any method. We used x-ray photoelectron spectroscopy to identify organic contamination, and weighing to quantify the mass lost at each application of the UVOPS procedure. The UVOPS procedure is shown to be very effective. It is likely that the redefinition of the kilogram will require mass comparisons in vacuum in the years to come. Therefore, in addition to UVOPS a cleaning method for use in vacuum will also be needed. We introduce and evaluate gas cluster ion-beam (GCIB) treatment as a potential method for cleaning reference masses in vacuum. Again, application of this GCIB cleaning to a real artefact, RS2, allows us to make a realistic evaluation of its performance. While it has some attractive features, we cannot recommend it for cleaning mass standards in its present form.

  12. Compressed air demand-type firefighter's breathing system, volume 1. [design analysis and performance tests

    NASA Technical Reports Server (NTRS)

    Sullivan, J. L.

    1975-01-01

    The commercial availability of lightweight high pressure compressed air vessels has resulted in a lightweight firefighter's breathing apparatus. The improved apparatus, and details of its design and development are described. The apparatus includes a compact harness assembly, a backplate mounted pressure reducer assembly, a lightweight bubble-type facemask with a mask mounted demand breathing regulator. Incorporated in the breathing regulator is exhalation valve, a purge valve and a whistle-type low pressure warning that sounds only during inhalation. The pressure reducer assembly includes two pressure reducers, an automatic transfer valve and a signaling device for the low pressure warning. Twenty systems were fabricated, tested, refined through an alternating development and test sequence, and extensively examined in a field evaluation program. Photographs of the apparatus are included.

  13. DEVELOPMENT OF THE HS99 AIR TRANSPORT TYPE A FISSILE PACKAGE

    SciTech Connect

    Blanton, P.; Eberl, K.

    2012-07-10

    An air-transport Type A Fissile radioactive shipping package for the transport of special form uranium sources has been developed by the Savannah River National Laboratory (SRNL) for the Department of Homeland Security. The Package model number is HS99 for Homeland Security Model 99. This paper presents the major design features of the HS99 and highlights engineered materials necessary for meeting the design requirements for this light-weight Type AF packaging. A discussion is provided demonstrating how the HS99 complies with the regulatory safety requirements of the Nuclear Regulatory Commission. The paper summarizes the results of structural testing to specified in 10 CFR 71 for Normal Conditions of Transport and Hypothetical Accident Conditions events. Planned and proposed future missions for this packaging are also addressed.

  14. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  15. 42 CFR 84.162 - Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air respirators; test requirements. 84.162 Section 84.162 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES...

  16. 42 CFR 84.162 - Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air respirators; test requirements. 84.162 Section 84.162 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES...

  17. 42 CFR 84.162 - Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air respirators; test requirements. 84.162 Section 84.162 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES...

  18. 42 CFR 84.162 - Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air respirators; test requirements. 84.162 Section 84.162 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES...

  19. 42 CFR 84.162 - Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Man test for gases and vapors; Type C respirators, continuous-flow class and Type CE supplied-air respirators; test requirements. 84.162 Section 84.162 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES...

  20. Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

    NASA Astrophysics Data System (ADS)

    Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

    2012-06-01

    The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

  1. TYPE Ibc SUPERNOVAE IN DISTURBED GALAXIES: EVIDENCE FOR A TOP-HEAVY INITIAL MASS FUNCTION

    SciTech Connect

    Habergham, S. M.; James, P. A.; Anderson, J. P.

    2010-07-01

    We compare the radial locations of 178 core-collapse supernovae (CCSNe) to the R-band and H{alpha} light distributions of their host galaxies. When the galaxies are split into 'disturbed' and 'undisturbed' categories, a striking difference emerges. The disturbed galaxies have a central excess of CCSNe and this excess is almost completely dominated by supernovae of types Ib, Ic, and Ib/c, whereas type II supernovae dominate in all other environments. The difference cannot easily be explained by metallicity or extinction effects, and thus we propose that this is direct evidence for a stellar initial mass function that is strongly weighted toward high-mass stars, specifically in the central regions of disturbed galaxies.

  2. Desert dust aerosol air mass mapping in the western Sahara, using particle properties derived from space-based multi-angle imaging

    NASA Astrophysics Data System (ADS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Esselborn, Michael; Fiebig, Marcus; Heese, Birgit; Knippertz, Peter; Müller, Detlef; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

    2009-02-01

    ABSTRACT Coincident observations made over the Moroccan desert during the Sahara mineral dust experiment (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from multi-angle imaging spectroradiometer (MISR) observations, and to place the suborbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days during which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05-0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape and single-scattering albedo. For the three study days, the satellite observations (1) highlight regional gradients in the mix of dust and background spherical particles, (2) identify a dust plume most likely part of a density flow and (3) show an aerosol air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometres away.

  3. Desert Dust Air Mass Mapping in the Western Sahara, using Particle Properties Derived from Space-based Multi-angle Imaging

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Fiebig, Marcus; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

    2008-01-01

    Coincident observations made over the Moroccan desert during the SAhara Mineral dUst experiMent (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from Multi-angle Imaging SpectroRadiometer (MISR) observations, and to place the sub-orbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days for which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 to 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape, and single-scattering albedo. For the three study days, the satellite observations (a) highlight regional gradients in the mix of dust and background spherical particles, (b) identify a dust plume most likely part of a density flow, and (c) show an air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometers away.

  4. Desert Dust Aerosol Air Mass Mapping in the Western Sahara, Using Particle Properties Derived from Space-Based Multi-Angle Imaging

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Esselborn, Michael; Fiebig, Marcus; Heese, Birgit; Knippertz, Peter; Mueller, Detlef; Schladitz, Alexander; Von Hoyningen-Huene, Wolfgang

    2008-01-01

    Coincident observations made over the Moroccan desert during the Sahara mineral dust experiment (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from multi-angle imaging spectroradiometer (MISR) observations, and to place the suborbital aerosol measurements into the satellite s larger regional context. On three moderately dusty days during which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR s ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape and single-scattering albedo. For the three study days, the satellite observations (1) highlight regional gradients in the mix of dust and background spherical particles, (2) identify a dust plume most likely part of a density flow and (3) show an aerosol air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometres away.

  5. Effect of humidity and particle hygroscopicity on the mass loading capacity of high efficiency particulate air (HEPA) filters

    SciTech Connect

    Gupta, A.; Biswas, P. ); Monson, P.R. ); Novick, V.J. )

    1993-07-01

    The effect of humidity, particle hygroscopicity, and size on the mass loading capacity of glass fiber high efficiency particulate air filters was studied. Above the deliquescent point, the pressure drop across the filter increased nonlinearly with areal loading density (mass collected/filtration area) of a NaCl aerosol, thus significantly reducing the mass loading capacity of the filter compared to dry hygroscopic or nonhygroscopic particle mass loadings. The specific cake resistance K[sub 2] was computed for different test conditions and used as a measure of the mass loading capacity. K[sub 2] was found to decrease with increasing humidity for nonhygroscopic aluminum oxide particles and for hygroscopic NaCl particles (at humidities below the deliquescent point). It is postulated that an increase in humidity leads to the formation of a more open particulate cake which lowers the pressure drop for a given mass loading. A formula for predicting K[sub 2] for lognormally distributed aerosols (parameters obtained from impactor data) was derived. The resistance factor, R, calculated using this formula was compared to the theoretical R calculated using the Rudnick-Happel expression. For the nonhygroscopic aluminum oxide, the agreement was good but for the hygroscopic sodium chloride, due to large variation in the cake porosity estimates, the agreement was poor. 17 refs., 6 figs., 3 tabs.

  6. Characteristics of coronal mass ejections associated with solar frontside and backside metric Type II bursts

    NASA Technical Reports Server (NTRS)

    Kahler, S. W.; Cliver, E. W.; Sheeley, N. R.; Howard, R. A.; Michels, D. J.; Koomen, M. J.

    1985-01-01

    Fast velocities of 500 km/s or greater coronal mass ejections (CME's) are compared with reported metric type II bursts to study the properties of CME's associated with coronal shocks. An earlier report of fast frontside CME's with no associated metric type II bursts is confirmed, and it is calculated that 33 + or - 15 percent of all fast frontside CME's are not associated with such bursts. Faster CME's are more likely to be associated with type II bursts, as expected from the hypothesis of piston-driven shocks. However, CME brightness and associated peak 3-cm burst intensity are also important factors, as might be inferred from the Wagner and MacQueen (1983) view of type II shocks decoupled from associated CME's. The equal visibility of solar frontside and backside CME's is used to deduce the observability of backside type II bursts. It is calculated that 23 + or - 7 percent of all backside type II bursts associated with fast CME's can be observed at the earth and that 13 + or - 4 percent of all type II bursts originate in backside flares. CME speed again is the most important factor in the obervability of backside type II bursts.

  7. Rapid Bacterial Identification, Resistance, Virulence and Type Profiling using Selected Reaction Monitoring Mass Spectrometry

    PubMed Central

    Charretier, Yannick; Dauwalder, Olivier; Franceschi, Christine; Degout-Charmette, Elodie; Zambardi, Gilles; Cecchini, Tiphaine; Bardet, Chloe; Lacoux, Xavier; Dufour, Philippe; Veron, Laurent; Rostaing, Hervé; Lanet, Veronique; Fortin, Tanguy; Beaulieu, Corinne; Perrot, Nadine; Dechaume, Dominique; Pons, Sylvie; Girard, Victoria; Salvador, Arnaud; Durand, Géraldine; Mallard, Frédéric; Theretz, Alain; Broyer, Patrick; Chatellier, Sonia; Gervasi, Gaspard; Van Nuenen, Marc; Ann Roitsch, Carolyn; Van Belkum, Alex; Lemoine, Jérôme; Vandenesch, François; Charrier, Jean-Philippe

    2015-01-01

    Mass spectrometry (MS) in Selected Reaction Monitoring (SRM) mode is proposed for in-depth characterisation of microorganisms in a multiplexed analysis. Within 60–80 minutes, the SRM method performs microbial identification (I), antibiotic-resistance detection (R), virulence assessment (V) and it provides epidemiological typing information (T). This SRM application is illustrated by the analysis of the human pathogen Staphylococcus aureus, demonstrating its promise for rapid characterisation of bacteria from positive blood cultures of sepsis patients. PMID:26350205

  8. Air Superiority at Red Flag: Mass, Technology, and Winning the Next War

    DTIC Science & Technology

    2009-10-01

    improved their estimate. In The Art of Wargaming, Peter Perla suggests that adding exercise analysis could help. He recommends a “continuous cycle...Survey, 44. 45. Ibid., 27–28. 46. “Desert Shield Tactical Air Force Combat Losses, Damage, and Muni- tions Consumption.” 47. Ibid. 48. Perla , Art of...Williamson. Strategy for Defeat: The Luftwaffe, 1933– 1945, 1983. Reprint. Maxwell AFB, AL: Air University Press, 2007. Perla , Peter P. The Art of Wargaming

  9. DYNAMICAL MASSES OF EARLY-TYPE GALAXIES AT z approx 2: ARE THEY TRULY SUPERDENSE?

    SciTech Connect

    Cappellari, Michele; Di Serego Alighieri, S.; Cimatti, A.; Daddi, E.; Kurk, J. D.; Cassata, P.; Dickinson, M.; Franceschini, A.; Rodighiero, G.; Mignoli, M.; Pozzetti, L.; Zamorani, G.; Rosati, P.

    2009-10-10

    We measured stellar velocity dispersions sigma and derived dynamical masses of nine massive (M approx 10{sup 11} M{sub sun}) early-type galaxies (ETGs) from the Galaxy Mass Assembly ultra-deep Spectroscopic Survey (GMASS) sample at redshift 1.4 approx< z approx< 2.0. The sigma are based on individual spectra for two galaxies at z approx 1.4 and on a stacked spectrum for seven galaxies with 1.6 < z < 2.0, with 202 hr of exposure at the ESO Very Large Telescope. We constructed detailed axisymmetric dynamical models for the objects, based on the Jeans equations, taking the observed surface brightness (from deep HST/ACS observations), point-spread function, and slit effects into account. Our dynamical masses M{sub Jeans} agree within approx<30% with virial estimates M{sub vir} = 5 x R{sub e}sigma{sup 2}/G, although the latter tend to be smaller. Our M{sub Jeans} also agrees within a factor approx<2 with the M{sub pop} previously derived using stellar population models and 11 bands photometry. This confirms that the galaxies are intrinsically massive. The inferred mass-to-light ratios (M/L) {sub U} in the very age-sensitive rest-frame U band are consistent with passive evolution in the past approx1 Gyr (formation redshift z{sub f} approx 3). A 'bottom-light' stellar initial mass function appears to be required to ensure close agreement between M{sub Jeans} and M {sub pop} at z approx 2, as it does at z approx 0. The GMASS ETGs are on average more dense than their local counterpart. However, a few percent of local ETGs of similar dynamical masses also have comparable sigma and mass surface density SIGMA{sub 50} inside R{sub e}.

  10. COMPARING X-RAY AND DYNAMICAL MASS PROFILES IN THE EARLY-TYPE GALAXY NGC 4636

    SciTech Connect

    Johnson, Ria; Raychaudhury, Somak; Chakrabarty, Dalia; O'Sullivan, Ewan E-mail: D.Chakrabarty@warwick.ac.u

    2009-12-01

    We present the results of an X-ray mass analysis of the early-type galaxy NGC 4636, using Chandra data. We have compared the X-ray mass density profile with that derived from a dynamical analysis of the system's globular clusters (GCs). Given the observed interaction between the central active galactic nucleus and the X-ray emitting gas in NGC 4636, we would expect to see a discrepancy in the masses recovered by the two methods. Such a discrepancy exists within the central approx10 kpc, which we interpret as the result of non-thermal pressure support or a local inflow. However, over the radial range approx10-30 kpc, the mass profiles agree within the 1sigma errors, indicating that even in this highly disturbed system, agreement can be sought at an acceptable level of significance over intermediate radii, with both methods also indicating the need for a dark matter halo. However, at radii larger than 30 kpc, the X-ray mass exceeds the dynamical mass, by a factor of 4-5 at the largest disagreement. A Fully Bayesian Significance Test finds no statistical reason to reject our assumption of velocity isotropy, and an analysis of X-ray mass profiles in different directions from the galaxy center suggests that local disturbances at large radius are not the cause of the discrepancy. We instead attribute the discrepancy to the paucity of GC kinematics at large radius, coupled with not knowing the overall state of the gas at the radius where we are reaching the group regime (>30 kpc), or a combination of the two.

  11. EPA Air Method, Toxic Organics - 15 (TO-15): Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)

    EPA Pesticide Factsheets

    Method T)-15 describes procedures for for preparation and analysis of air samples containing volatile organic compounds collected in specially-prepared canisters, using gas chromatography-mass spectrometry.

  12. Elbow mass flow meter

    DOEpatents

    McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

    1994-08-16

    The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

  13. FURTHER DEFINING SPECTRAL TYPE 'Y' AND EXPLORING THE LOW-MASS END OF THE FIELD BROWN DWARF MASS FUNCTION

    SciTech Connect

    Davy Kirkpatrick, J.; Gelino, Christopher R.; Griffith, Roger L.; Marsh, Kenneth A.; Cushing, Michael C.; Mace, Gregory N.; Wright, Edward L.; McLean, Ian S.; Skrutskie, Michael F.; Eisenhardt, Peter R.; Mainzer, Amanda K.; Burgasser, Adam J.; Tinney, C. G.; Parker, Stephen; Salter, Graeme

    2012-07-10

    We present the discovery of another seven Y dwarfs from the Wide-field Infrared Survey Explorer (WISE). Using these objects, as well as the first six WISE Y dwarf discoveries from Cushing et al., we further explore the transition between spectral types T and Y. We find that the T/Y boundary roughly coincides with the spot where the J - H colors of brown dwarfs, as predicted by models, turn back to the red. Moreover, we use preliminary trigonometric parallax measurements to show that the T/Y boundary may also correspond to the point at which the absolute H (1.6 {mu}m) and W2 (4.6 {mu}m) magnitudes plummet. We use these discoveries and their preliminary distances to place them in the larger context of the solar neighborhood. We present a table that updates the entire stellar and substellar constituency within 8 pc of the Sun, and we show that the current census has hydrogen-burning stars outnumbering brown dwarfs by roughly a factor of six. This factor will decrease with time as more brown dwarfs are identified within this volume, but unless there is a vast reservoir of cold brown dwarfs invisible to WISE, the final space density of brown dwarfs is still expected to fall well below that of stars. We also use these new Y dwarf discoveries, along with newly discovered T dwarfs from WISE, to investigate the field substellar mass function. We find that the overall space density of late-T and early-Y dwarfs matches that from simulations describing the mass function as a power law with slope -0.5 < {alpha} < 0.0; however, a power law may provide a poor fit to the observed object counts as a function of spectral type because there are tantalizing hints that the number of brown dwarfs continues to rise from late-T to early-Y. More detailed monitoring and characterization of these Y dwarfs, along with dedicated searches aimed at identifying more examples, are certainly required.

  14. Genetic Effects of FTO and MC4R Polymorphisms on Body Mass in Constitutional Types.

    PubMed

    Cha, Seongwon; Koo, Imhoi; Park, Byung L; Jeong, Sangkyun; Choi, Sun M; Kim, Kil S; Shin, Hyoung D; Kim, Jong Y

    2011-01-01

    Sasang constitutional medicine (SCM), a Korean tailored medicine, categorizes human beings into four types through states of physiological imbalances and responsiveness to herbal medicine. One SCM type susceptible to obesity seems sensitive to energy intake due to an imbalance toward preserving energy. Common variants of fat mass and obesity associated (FTO) and melanocortin 4 receptor (MC4R) genes have been associated with increased body mass index (BMI) by affecting energy intake. Here, we statistically examined the association of FTO and MC4R polymorphisms with BMI in two populations with 1370 Koreans before and after SCM typing, and with the lowering of BMI in 538 individuals who underwent a 1-month lifestyle intervention. The increased BMI replicated the association with FTO haplotypes (effect size ≃ 1.1 kg/m(2)) and MC4R variants (effect size ≃ 0.64 kg/m(2)). After the lifestyle intervention, the carriers of the haplotype represented by the minor allele of rs1075440 had a tendency to lose more waist-to-hip ratio (0.76%) than non-carriers. The constitutional discrepancy for the accumulation of body mass by the effects of FTO and/or MC4R variants seemed to reflect the physique differences shown in each group of SCM constitutional types. In conclusion, FTO and MC4R polymorphisms appear to play an important role in weight gain, while only FTO variants play a role in weight loss after lifestyle intervention. Different trends were observed among individuals of SCM types, especially for weight gain. Therefore, classification of individuals based on physiological imbalance would offer a good genetic stratification system in assessing the effects of obesity genes.

  15. Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

    NASA Astrophysics Data System (ADS)

    Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

    2014-08-01

    Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

  16. Thermal desorption-gas chromatography-mass spectrometry method to determine phthalate and organophosphate esters from air samples.

    PubMed

    Aragón, M; Borrull, F; Marcé, R M

    2013-08-16

    A method based on thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed to determine four organophosphate esters, seven phthalate esters, and bis(2-ethylhexyl) adipate in the gas phase from harbour and urban air samples. The method involves the sampling of 1.5L of air in a Tenax TA sorbent tube followed by thermal desorption (using a Tenax TA cryogenic trap) coupled to gas chromatography-mass spectrometry. The repeatability of the method expressed as %RSD (n=3) is less than 15% and the MQLs are between 0.007μgm(-3) (DMP, TBP, BBP, TPP and DnOP) and 6.7μgm(-3) (DEHP). The method was successfully applied in two areas (urban and harbour) testing two and three points in each one, respectively. Some of these compounds were found in both urban and harbour samples. Di-(2-ethylhexyl)phthalate was the most abundant compound found in both areas at concentration levels between 6.7μgm(-3) and 136.4μgm(-3). This study demonstrates that thermal desorption is an efficient method for the determination of these semi-volatile compounds in the gas phase fraction of air samples.

  17. Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; Pȩkala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcău, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Curci, G.

    2014-11-01

    The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth τa(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean τa(3.5 km) ∼ 0.04 - and shows a seasonal trend with a winter minimum - τa(3.5 km) ∼ 0.03 -, and a summer maximum - τa(3.5 km) ∼ 0.06 -, and an unexpected increase from August to September - τa(3.5 km) ∼ 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. Average concentrations are affected by continental sources (wind-blown dust and urban pollution), whilst the peak observed in September and October could be linked to biomass burning in the northern part of Argentina or air pollution coming from surrounding urban areas.

  18. Insulitis and β-Cell Mass in the Natural History of Type 1 Diabetes

    PubMed Central

    Fu, Ann; Kaddis, John S.; Wasserfall, Clive; Schatz, Desmond A.; Pugliese, Alberto; Atkinson, Mark A.

    2016-01-01

    Descriptions of insulitis in human islets throughout the natural history of type 1 diabetes are limited. We determined insulitis frequency (the percent of islets displaying insulitis to total islets), infiltrating leukocyte subtypes, and β-cell and α-cell mass in pancreata recovered from organ donors with type 1 diabetes (n = 80), as well as from donors without diabetes, both with islet autoantibodies (AAb+, n = 18) and without islet autoantibodies (AAb−, n = 61). Insulitis was observed in four of four donors (100%) with type 1 diabetes duration of ≤1 year and two AAb+ donors (2 of 18 donors, 11%). Insulitis frequency showed a significant but limited inverse correlation with diabetes duration (r = −0.58, P = 0.01) but not with age at disease onset. Residual β-cells were observed in all type 1 diabetes donors with insulitis, while β-cell area and mass were significantly higher in type 1 diabetes donors with insulitis compared with those without insulitis. Insulitis affected 33% of insulin+ islets compared with 2% of insulin− islets in donors with type 1 diabetes. A significant correlation was observed between insulitis frequency and CD45+, CD3+, CD4+, CD8+, and CD20+ cell numbers within the insulitis (r = 0.53–0.73, P = 0.004–0.04), but not CD68+ or CD11c+ cells. The presence of β-cells as well as insulitis several years after diagnosis in children and young adults suggests that the chronicity of islet autoimmunity extends well into the postdiagnosis period. This information should aid considerations of therapeutic strategies seeking type 1 diabetes prevention and reversal. PMID:26581594

  19. Insulitis and β-Cell Mass in the Natural History of Type 1 Diabetes.

    PubMed

    Campbell-Thompson, Martha; Fu, Ann; Kaddis, John S; Wasserfall, Clive; Schatz, Desmond A; Pugliese, Alberto; Atkinson, Mark A

    2016-03-01

    Descriptions of insulitis in human islets throughout the natural history of type 1 diabetes are limited. We determined insulitis frequency (the percent of islets displaying insulitis to total islets), infiltrating leukocyte subtypes, and β-cell and α-cell mass in pancreata recovered from organ donors with type 1 diabetes (n = 80), as well as from donors without diabetes, both with islet autoantibodies (AAb(+), n = 18) and without islet autoantibodies (AAb(-), n = 61). Insulitis was observed in four of four donors (100%) with type 1 diabetes duration of ≤1 year and two AAb(+) donors (2 of 18 donors, 11%). Insulitis frequency showed a significant but limited inverse correlation with diabetes duration (r = -0.58, P = 0.01) but not with age at disease onset. Residual β-cells were observed in all type 1 diabetes donors with insulitis, while β-cell area and mass were significantly higher in type 1 diabetes donors with insulitis compared with those without insulitis. Insulitis affected 33% of insulin(+) islets compared with 2% of insulin(-) islets in donors with type 1 diabetes. A significant correlation was observed between insulitis frequency and CD45(+), CD3(+), CD4(+), CD8(+), and CD20(+) cell numbers within the insulitis (r = 0.53-0.73, P = 0.004-0.04), but not CD68(+) or CD11c(+) cells. The presence of β-cells as well as insulitis several years after diagnosis in children and young adults suggests that the chronicity of islet autoimmunity extends well into the postdiagnosis period. This information should aid considerations of therapeutic strategies seeking type 1 diabetes prevention and reversal.

  20. A new type of insect infrared organ of low thermal mass

    NASA Astrophysics Data System (ADS)

    Schmitz, Helmut; Schmitz, Anke; Trenner, Stefan; Bleckmann, Horst

    2002-03-01

    The Australian beetle Acanthocnemus nigricans is attracted by forest fires and has a pair of complex infrared (IR) receptor organs on the first thoracic segment. Each organ consists of a tiny sensory disc (diameter 120-130 µm) which serves as an absorbing structure for IR radiation. The disc is arranged above an air-filled cavity which is located just anteriorly to the coxae of the prothoracic legs. Inside the disc, about 30 multipolar thermoreceptors (warmth receptors) are tightly attached to the cuticle which is directed to the outside. The many dendrites of each multipolar neuron are tightly wrapped around the soma and contain a large number of mitochondria. Absorption of IR radiation by the disc causes an increase in temperature which is measured by the warmth receptors. Therefore, the IR receptors of A. nigricans can be classified as microbolometers with reduced thermal mass and in principle can be compared to the IR organs of pit vipers.

  1. Exposures to road traffic, noise, and air pollution as risk factors for type 2 diabetes: A feasibility study in Bulgaria

    PubMed Central

    Dzhambov, Angel M; Dimitrova, Donka D

    2016-01-01

    Type 2 diabetes mellitus (T2DM) is a growing public health problem in Bulgaria. While individual and lifestyle determinants have been researched; till date there has been no study on environmental risks such as road traffic, noise, and air pollution. As a first step toward designing a large-scale population-based survey, we aimed at exploring the overall associations of prevalent T2DM with exposures to road traffic, noise, and air pollution. A total of 513 residents of Plovdiv city, Bulgaria were recruited. Individual data on self-reported doctor-diagnosed T2DM and confounding factors were linked to objective and self-rated exposure indicators. Logistic and log-link Poisson regressions were conducted. In the fully adjusted logistic models, T2DM was positively associated with exposures to Lden 71-80 dB (odds ratio (OR) = 4.49, 95% confidence interval (CI): 1.38, 14.68), fine particulate matter (PM)2.5 25.0-66.8 μg/m3 (OR = 1.32, 95% CI: 0.28, 6.24), benzo alpha pyrene 6.0-14.02 ng/m3 (OR = 1.76, 95% CI: 0.52, 5.98) and high road traffic (OR = 1.40, 95% CI: 0.48, 4.07). Lden remained a significant risk factor in the: Poisson regression model. Other covariates with consistently high multivariate effects were age, gender, body mass index, family history of T2DM, subjective sleep disturbance, and especially bedroom location. We concluded that residential noise exposure might be associated with elevated risk of prevalent T2DM. The inferences made by this research and the lessons learned from its limitations could guide the designing of a longitudinal epidemiological survey in Bulgaria. PMID:27157686

  2. Exposures to road traffic, noise, and air pollution as risk factors for type 2 diabetes: A feasibility study in Bulgaria.

    PubMed

    Dzhambov, Angel M; Dimitrova, Donka D

    2016-01-01

    Type 2 diabetes mellitus (T2DM) is a growing public health problem in Bulgaria. While individual and lifestyle determinants have been researched; till date there has been no study on environmental risks such as road traffic, noise, and air pollution. As a first step toward designing a large-scale population-based survey, we aimed at exploring the overall associations of prevalent T2DM with exposures to road traffic, noise, and air pollution. A total of 513 residents of Plovdiv city, Bulgaria were recruited. Individual data on self-reported doctor-diagnosed T2DM and confounding factors were linked to objective and self-rated exposure indicators. Logistic and log-link Poisson regressions were conducted. In the fully adjusted logistic models, T2DM was positively associated with exposures to L(den) 71-80 dB (odds ratio (OR) = 4.49, 95% confidence interval (CI): 1.38, 14.68), fine particulate matter (PM) 2.5 25.0-66.8 μg/m 3 (OR = 1.32, 95% CI: 0.28, 6.24), benzo alpha pyrene 6.0-14.02 ng/m 3 (OR = 1.76, 95% CI: 0.52, 5.98) and high road traffic (OR = 1.40, 95% CI: 0.48, 4.07). L(den) remained a significant risk factor in the: Poisson regression model. Other covariates with consistently high multivariate effects were age, gender, body mass index, family history of T2DM, subjective sleep disturbance, and especially bedroom location. We concluded that residential noise exposure might be associated with elevated risk of prevalent T2DM. The inferences made by this research and the lessons learned from its limitations could guide the designing of a longitudinal epidemiological survey in Bulgaria.

  3. Fuel-air ratio (Lambda) correcting apparatus for a rotor-type carburetor for integral combustion engines

    SciTech Connect

    Diener, R.

    1988-02-23

    This patent describes a fuel-air ratio correcting apparatus in a rotor-type carburetor for internal combustion engines with spark ignition for producing ingestion air with fuel-air ratios within a predetermined range defined by lean and rich limits matched to the requirements of the various operational points of the internal combustion engine. The rotor-type carburetor has a rotating element including a turbine which is driven by a turbine driving airstream which is induced by the engine and which becomes at least a portion of the ingested air stream, the rotating element containing a centrifugal pump for delivering a quantity of fuel which is in a substantially constant ratio to the rotational velocity of the rotating element. The fuel is delivered to a coaxial atomization means on the rotating element for broad-casting atomized fuel into the driving airstream. The centrifugal pump is sized to deliver a quantity of fuel to the driving airstream to establish a fuel-air ratio at one limit of the predetermined range, and means for sensing one or more parameters(s) affecting operation of the internal combustion engine and for selectively varying the volume of at least one of the constituents of the fuel-air mixture ingested by the engine for establishing a predetermined fuel-air ratio variable over the remainder of the range of fuel-air ratios in dependence on one or more measured operating parameter(s) of the internal combustion engine. The rotor-type carburetor has a rotor driven via an impeller by the ingested air stream, the rotor containing a centrifugal pump for delivering via at least one lateral fuel discharge bore a qantity of fuel which is in a constant ratio to the ingested air and which is dimensioned for a lean mixture.

  4. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-09-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. Satellite observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the Ozone Monitoring Instrument (OMI) tropospheric NO2 AMF calculation for cloud-free scenes. We do so by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation of the difference was 0.6 ± 8 %. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 68 % of the daily OMAERUV AOD observations were within 30 % of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10 % higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30 %, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and

  5. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

  6. Numerical study of coupled transfer of heat and mass between air and water inside a geothermal water cooling tower

    NASA Astrophysics Data System (ADS)

    Bassem, Mohamed Mehdi; Bourouni, Karim; Thameur Chaibi, Mohamed

    2006-11-01

    In the south of Tunisia, geothermal water is used to irrigate cultures. Since its temperature is very high (70 C), geothermal water is cooled by cooling towers. These towers are sized empirically and present many operating problems such as excessive energy consumption, big loss of vapour and low cooling efficiency. The aim of our work is modelling the coupled heat and mass transfer between air and water inside the cooling tower. The most important results obtained are that the evaporative potential is dominating the convective one in the cooling process. That's why the cooling is more efficient in summer than in hibernal period when humidity of ambient air reaches high values. In other hand, the negative convective phenomenon is illustrated. In fact, at the bottom of the tower, water temperature reaches the air one; the two fluids begin to cooling simultaneously. Air is cooled by convection and water by evaporation. We demonstrate also that there is no point in putting fans in working during cold weather. We studied also the effect of the variation of heat transfer coefficient on the efficiency of cooling.

  7. Petroleum mass removal from low permeability sediment using air sparging/soil vapor extraction: impact of continuous or pulsed operation

    NASA Astrophysics Data System (ADS)

    Kirtland, Brian C.; Aelion, C. Marjorie

    2000-02-01

    Air sparging and soil vapor extraction (AS/SVE) are innovative remediation techniques that utilize volatilization and microbial degradation to remediate petroleum spills from soils and groundwater. This in situ study investigated the use of AS/SVE to remediate a gasoline spill from a leaking underground storage tank (UST) in the low permeability, clayey soil of the Appalachian Piedmont. The objectives of this study were to evaluate AS/SVE in low permeability soils by quantifying petroleum mass removal rates, monitoring vadose zone contaminant levels, and comparing the mass extraction rates of continuous AS/SVE to 8 and 24 h pulsed operation. The objectives were met by collecting AS/SVE exhaust gas samples and vadose zone air from multi-depth soil vapor probes. Samples were analyzed for O 2, CO 2, BTEX (benzene, toluene, ethylbenzene, xylene), and total combustible hydrocarbon (TCH) concentrations using portable hand meters and gas chromatography. Continuous AS/SVE was effective in removing 608 kg of petroleum hydrocarbons from low permeability soil in 44 days (14.3 kg day -1). Mass removal rates ranged from 2.6 times higher to 5.1 times lower than other AS/SVE studies performed in sandy sediments. BTEX levels in the vadose zone were reduced from about 5 ppm to 1 ppm. Ten pulsed AS/SVE tests removed 78 kg in 23 days and the mean mass removal rate (17.6 kg day -1) was significantly higher than the last 15 days of continuous extraction. Pulsed operation may be preferable to continuous operation because of increased mass removal and decreased energy consumption.

  8. Solar Flares, Type III Radio Bursts, Coronal Mass Ejections, and Energetic Particles

    NASA Technical Reports Server (NTRS)

    Cane, Hilary V.; Erickson, W. C.; Prestage, N. P.; White, Nicholas E. (Technical Monitor)

    2002-01-01

    In this correlative study between greater than 20 MeV solar proton events, coronal mass ejections (CMEs), flares, and radio bursts it is found that essentially all of the proton events are preceded by groups of type III bursts and all are preceded by CMEs. These type III bursts (that are a flare phenomenon) usually are long-lasting, intense bursts seen in the low-frequency observations made from space. They are caused by streams of electrons traveling from close to the solar surface out to 1 AU. In most events the type III emissions extend into, or originate at, the time when type II and type IV bursts are reported (some 5 to 10 minutes after the start of the associated soft X-ray flare) and have starting frequencies in the 500 to approximately 100 MHz range that often get lower as a function of time. These later type III emissions are often not reported by ground-based observers, probably because of undue attention to type II bursts. It is suggested to call them type III-1. Type III-1 bursts have previously been called shock accelerated (SA) events, but an examination of radio dynamic spectra over an extended frequency range shows that the type III-1 bursts usually start at frequencies above any type II burst that may be present. The bursts sometimes continue beyond the time when type II emission is seen and, furthermore, sometimes occur in the absence of any type II emission. Thus the causative electrons are unlikely to be shock accelerated and probably originate in the reconnection regions below fast CMEs. A search did not find any type III-1 bursts that were not associated with CMEs. The existence of low-frequency type III bursts proves that open field lines extend from within 0.5 radius of the Sun into the interplanetary medium (the bursts start above 100 MHz, and such emission originates within 0.5 solar radius of the solar surface). Thus it is not valid to assume that only closed field lines exist in the flaring regions associated with CMEs and some

  9. Effects of Outdoor Air Pollutants on Platelet Activation in People with Type 2 Diabetes

    PubMed Central

    Frampton, Mark W.; Bausch, Jan; Chalupa, David; Hopke, Philip K.; Little, Erika L.; Oakes, David; Stewart, Judith C.; Utell, Mark J.

    2013-01-01

    Exposure to air pollution is associated with increased morbidity and mortality from cardiovascular disease. We hypothesized that increases in exposure to ambient air pollution are associated with platelet activation and formation of circulating tissue-factor-expressing microparticles. We studied 19 subjects with type 2 diabetes, without clinical evidence of cardiovascular disease, who had previously participated in a human clinical study of exposure to ultrafine particles (UFP). Blood was obtained for measurements of platelet activation following an overnight stay in the Clinical Research Center, prior to each of their two pre-exposure visits. Air pollution and meteorological data, including UFP counts, were analyzed for the 5 days prior to the subjects’ arrival at the Clinical Research Center. Contrary to expectations, increases in UFP were associated with decreases in surface expression of platelet activation markers. The number of platelet-leukocyte conjugates decreased by −80 (95% confidence interval (CI) −123 to −37, p=0.001) on the first lag day (20–44 hours prior to the blood draw) and by −85 (CI −139 to −31, p=0.005) on combined lag days 1 to 5, per interquartile range (IQR) increase in UFP particle number (2482). However, levels of soluble CD40L increased 104 (CI 3 to 205, p=0.04) pg/ml per IQR increase in UFP on lag day 1, a finding consistent with prior platelet activation. We speculate that, in people with diabetes, exposure to UFP activates circulating platelets within hours of exposure, followed by an increase in soluble CD40L and a rebound reduction in circulating platelet surface markers. PMID:23033996

  10. Effects of outdoor air pollutants on platelet activation in people with type 2 diabetes.

    PubMed

    Frampton, Mark W; Bausch, Jan; Chalupa, David; Hopke, Philip K; Little, Erika L; Oakes, David; Stewart, Judith C; Utell, Mark J

    2012-10-01

    Exposure to air pollution is associated with increased morbidity and mortality from cardiovascular disease. We hypothesized that increases in exposure to ambient air pollution are associated with platelet activation and formation of circulating tissue factor-expressing microparticles. We studied 19 subjects with type 2 diabetes, without clinical evidence of cardiovascular disease, who had previously participated in a human clinical study of exposure to ultrafine particles (UFP). Blood was obtained for measurements of platelet activation following an overnight stay in the Clinical Research Center, prior to each of their two pre-exposure visits. Air pollution and meteorological data, including UFP counts, were analyzed for the 5 days prior to the subjects' arrival at the Clinical Research Center. Contrary to expectations, increases in UFP were associated with decreases in surface expression of platelet activation markers. The number of platelet-leukocyte conjugates decreased by -80 (95% confidence interval (CI) -123 to -37, p = 0.001) on the first lag day (20-44 h prior to the blood draw) and by -85 (CI -139 to -31, p = 0.005) on combined lag days 1 to 5, per interquartile range (IQR) increase in UFP particle number (2482). However, levels of soluble CD40L increased 104 (CI 3 to 205, p = 0.04) pg/ml per IQR increase in UFP on lag day 1, a finding consistent with prior platelet activation. We speculate that, in people with diabetes, exposure to UFP activates circulating platelets within hours of exposure, followed by an increase in soluble CD40L and a rebound reduction in circulating platelet surface markers.

  11. Solar gamma-ray-line flares, type II radio bursts, and coronal mass ejections

    NASA Technical Reports Server (NTRS)

    Cliver, E. W.; Cane, H. V.; Forrest, D. J.; Koomen, M. J.; Howard, R. A.; Wright, C. S.

    1991-01-01

    A Big Flare Syndrome (BFS) test is used to substantiate earlier reports of a statistically significant association between nuclear gamma-ray-line (GRL) flares and metric type II bursts from coronal shocks. The type II onset characteristically follows the onset of gamma-ray emission with a median delay of two minutes. It is found that 70-90 percent of GRL flares for which coronagraph data were available were associated with coronal mass ejections (CMEs). Gradual and impulsive GRL flares were equally well associated with CMEs. The CMEs were typically fast, with a median speed greater than 800 km/s. possible `non-BFS' explanations for the GRL-type II association are discussed.

  12. Ambient air analyses using nonspecific flame ionization and electron capture detection compared to specific detection by mass spectroscopy

    SciTech Connect

    Pleil, J.D.; Oliver, K.D.; McClenny, W.A.

    1988-08-01

    Ambient air samples from various studies were analyzed for a specific set of trace-level volatile organic compounds by using a gas chromatograph (GC) equipped with a flame ionization detector (FID) in parallel with an electron capture detector (ECD). The samples were then reanalyzed on a second GC system equipped with a mass selective detector (MSD). GC-FID/ECD data were compared to the nominally correct GC-MSD data to determine the accuracy of the nonspecific detectors, which often do not differentiate the targeted compound from interfering compounds. Qualitative accuracy (capability for correctly identifying compounds on the basis of retention time only) and quantitative accuracy (capability for correctly measuring the concentration of an identified compound on the basis of peak area) were evaluated. Data are presented on a per-compound basis to provide the combined typical results from air samples collected in three geographic regions: Kanawha Valley, WV; Los Angeles, CA, area; and Houston, TX.

  13. Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

    NASA Astrophysics Data System (ADS)

    Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

    2017-01-01

    A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

  14. Effects of sample mass and macrofossil type on radiocarbon dating of arctic and boreal lake sediments

    SciTech Connect

    Oswald, W W; Anderson, P M; Brown, T A; Brubaker, L B; Hu, F S; Lozhkin, A V; Tinner, W; Kaltenrieder, P

    2006-05-29

    Dating lake sediments by accelerator mass spectrometry (AMS) {sup 14}C analysis of plant macrofossils overcomes one of the main problems associated with dating bulk sediment samples, the presence of old organic matter. Even so, many AMS dates from arctic and boreal sites appear to misrepresent the age of the sediment. To understand the nature of these apparent dating anomalies better, we conducted a series of {sup 14}C dating experiments using samples from Alaskan and Siberian lake-sediment cores. First, to test whether our analytical procedures introduced a sample-mass bias, we obtained {sup 14}C dates for different-sized pieces of single woody macrofossils. In these sample-mass experiments, sized statistically equivalent ages were found for samples as small as 0.05 mg C. Second, to assess whether macrofossil type influenced dating results, we conducted sample-type experiments in which {sup 14}C dates were obtained for different macrofossil types sieved from the same depth in the sediment. We dated materials from multiple levels in sediment cores from Upper Capsule Lake (North Slope, northern Alaska) and Grizzly Lake (Copper River Basin, southern Alaska), and from single depths in other records from northern Alaska. In several of the experiments there were significant discrepancies between dates for different plant tissues, and in most cases wood and charcoal were older than other macrofossil types, usually by several hundred years. This pattern suggests that {sup 14}C dates for woody macrofossils may misrepresent the age of the sediment by centuries, perhaps due to their longer terrestrial residence time and the potential in-built age of long-lived plants. This study identifies why some {sup 14}C dates appear to be inconsistent with the overall age-depth trend of a lake-sediment record, and it may guide the selection of {sup 14}C samples in future studies.

  15. Differential effects of air conditioning type on residential endotoxin levels in a semi-arid climate.

    PubMed

    Johnston, J D; Kruman, B A; Nelson, M C; Merrill, R M; Graul, R J; Hoybjerg, T G; Tuttle, S C; Myers, S J; Cook, R B; Weber, K S

    2017-01-31

    Residential endotoxin exposure is associated with protective and pathogenic health outcomes. Evaporative coolers, an energy-efficient type of air conditioner used in dry climates, are a potential source of indoor endotoxins; however, this association is largely unstudied. We collected settled dust biannually from four locations in homes with evaporative coolers (n=18) and central air conditioners (n=22) in Utah County, Utah (USA), during winter (Jan-Apr) and summer (Aug-Sept), 2014. Dust samples (n=281) were analyzed by the Limulus amebocyte lysate test. Housing factors were measured by survey, and indoor temperature and relative humidity measures were collected during both seasons. Endotoxin concentrations (EU/mg) were significantly higher in homes with evaporative coolers from mattress and bedroom floor samples during both seasons. Endotoxin surface loads (EU/m(2) ) were significantly higher in homes with evaporative coolers from mattress and bedroom floor samples during both seasons and in upholstered furniture during winter. For the nine significant season-by-location comparisons, EU/mg and EU/m(2) were approximately three to six times greater in homes using evaporative coolers. A plausible explanation for these findings is that evaporative coolers serve as a reservoir and distribution system for Gram-negative bacteria or their cell wall components in homes.

  16. Air-water ‘tornado’-type microwave plasmas applied for sugarcane biomass treatment

    NASA Astrophysics Data System (ADS)

    Bundaleska, N.; Tatarova, E.; Dias, F. M.; Lino da Silva, M.; Ferreira, C. M.; Amorim, J.

    2014-02-01

    The production of cellulosic ethanol from sugarcane biomass is an attractive alternative to the use of fossil fuels. Pretreatment is needed to separate the cellulosic material, which is packed with hemicellulose and lignin in cell wall of sugarcane biomass. A microwave ‘tornado’-type air-water plasma source operating at 2.45 GHz and atmospheric pressure has been applied for this purpose. Samples of dry and wet biomass (˜2 g) have been exposed to the late afterglow plasma stream. The experiments demonstrate that the air-water highly reactive plasma environment provides a number of long-lived active species able to destroy the cellulosic wrapping. Scanning electron microscopy has been applied to analyse the morphological changes occurring due to plasma treatment. The effluent gas streams have been analysed by Fourier-transform infrared spectroscopy (FT-IR). Optical emission spectroscopy and FT-IR have been applied to determine the gas temperature in the discharge and late afterglow plasma zones, respectively. The optimal range of the operational parameters is discussed along with the main active species involved in the treatment process. Synergistic effects can result from the action of singlet O2(a 1Δg) oxygen, NO2, nitrous acid HNO2 and OH hydroxyl radical.

  17. Impact of bicycle route type on exposure to traffic-related air pollution.

    PubMed

    MacNaughton, Piers; Melly, Steven; Vallarino, Jose; Adamkiewicz, Gary; Spengler, John D

    2014-08-15

    Cyclists are exposed to traffic-related air pollution (TRAP) during their commutes due to their proximity to vehicular traffic. Two of the main components of TRAP are black carbon (BC) and nitrogen dioxide (NO2), which have both been causally associated with increased mortality. To assess the impact of cyclists' exposure to TRAP, a battery-powered mobile monitoring station was designed to sample air pollutants along five bike routes in Boston, Massachusetts. The bike routes were categorized into three types: bike paths, which are separated from vehicle traffic; bike lanes, which are adjacent to traffic; and designated bike lanes, which are shared traffic lanes for buses and cyclists. Bike lanes were found to have significantly higher concentrations of BC and NO2 than bike paths in both adjusted and unadjusted generalized linear models. Higher concentrations were observed in designated bike lanes than bike paths; however, this association was only significant for NO2. After adjusting for traffic density, background concentration, and proximity to intersections, bike lanes were found to have concentrations of BC and NO2 that were approximately 33% higher than bike paths. Distance from the road, vegetation barriers, and reduced intersection density appear to influence these variations. These findings suggest that cyclists can reduce their exposure to TRAP during their commute by using bike paths preferentially over bike lanes regardless of the potential increase of traffic near these routes.

  18. [Unusual and fatal type of burn injury: hot air sauna burn].

    PubMed

    García-Tutor, E; Koljonen, V

    2007-01-01

    Sauna bathing is a popular recreational activity in Finland and is generally considered safe even for pregnant women and patients suffering from heart problems; but mixing alcohol with sauna bathing can be hazardous. In the normal Finnish recreational sauna the temperature is usually between 80 and 90 degrees C. A wide variety of burn injuries, in all age groups, are related to sauna bathing; scalds and contact burns account for over 85% while hot air, steam and flame burns for only 15%. Dehydration in patients under the influence of alcohol heightens the risk of hypotension which impairs skin blood circulation. This increased warming of the skin is an effect that is more marked on the outer and upper parts of the body exposed to hot air. Such patients require intensive care on admission: fluid replacement according to the Parkland formula, forced diuresis and immediate correction of acidosis and myoglobinuria. These patients have significant rhabdomyolysis on admission. The best predictor of survival is the creatine kinase level on the second post-injury day. CT scans are necessary to diagnose the underlying conditions of unconsciousness. The necrotic area extends to subcutaneous fat tissue and even to the underlying muscles. The level of excision is typically fascial and, in some areas, layers of the muscle must be removed. Owing to the popularity of sauna bathing throughout the world, it is important to know the extent of damage in this type of injury, in order not to underestimate the severity of such lesions.

  19. The Critical Mass Ratio of Violent Merger-Induced Type Ia Supernovae

    NASA Astrophysics Data System (ADS)

    Sato, Yushi; Nakasato, Naohito; Tanikawa, Ataru; Nomoto, Ken'ichi; Maeda, Keiichi; Hachisu, Izumi

    Mergers of carbon-oxygen (CO) white dwarfs (WDs) are considered as one of the potential progenitors of type Ia supernovae (SNe Ia). Recent studies indicate that the less massive (secondary) WD violently accretes onto the more massive (primary) one, carbon detonation occurs. The detonation wave propagates through the primary, and an SN Ia explosion finally occurs. Such an explosion model is called the violent merger scenario. Based on the smoothed hydrodynamics (SPH) simulations of merging CO WDs, we derived the critical mass ratio (qcr) leading to the violent merger-induced SN Ia. As a result, we found that qcr ˜ 0.8 when the primary's mass is 1 solar mass (M ȯ ), in other words, the secondary WD of the binary system has to be larger than 0.8 M ȯ . Since such a massive CO WD is considered to be rare, the violent merger scenario might not be the dominant progenitors of normal SNe Ia. Using the results of this study and our previous one, we categolize the outcomes of CO WDs mergers into four scenarios. Recently, an observation found a super-Chandrasekhar mass double degenerate system in the center of Henize 2-428, a bipolar planetary nebula. We use our results to investigate the merger outcome of the system.

  20. Earthquake-induced collapse mechanism of two types of dangerous rock masses

    NASA Astrophysics Data System (ADS)

    Wang, Wei; Yuan, Wei; Wang, Qizhi; Xue, Kang

    2016-06-01

    As the economy of China develops, an increasing number of key traffic projects have been undertaken in the west of China, where there are high, steep rock slopes. The collapse of dangerous rock masses, especially following a strong earthquake, is one of common geological disasters known in rock slope engineering. Therefore, it is important to study the collapse mechanism of dangerous rock masses induced by an earthquake and the analysis approach of its stability. This study provides a simple and convenient method to determine the collapse mechanisms of two types of dangerous rock masses (i.e. cantilever and upright) associated with the definition and calculation of the safety factor, which is based on the flexure theory of a constant-section beam by combining with the maximum tensile-stress criterion to depict the process of crack propagation caused by seismic waves. The calculation results show that there are critical crack depths in each form of the dangerous rock masses. Once the accumulated depth of the crack growth during an earthquake exceeds the critical depth, the collapse will occur. It is also demonstrated that the crack extension amount of each step is not a constant value, and is closely associated with the current accumulated crack depth. The greater the cumulative crack depth, the more easily the crack propagates. Finally, the validity and applicability of the proposed method are verified through two actual engineering examples.

  1. BOREAS: Mass Loss Rate of a Cool, Late-type Star

    NASA Astrophysics Data System (ADS)

    Cranmer, Steven R.; Saar, Steven H.

    2011-08-01

    The basic mechanisms responsible for producing winds from cool, late-type stars are still largely unknown. We take inspiration from recent progress in understanding solar wind acceleration to develop a physically motivated model of the time-steady mass loss rates of cool main-sequence stars and evolved giants. This model follows the energy flux of magnetohydrodynamic turbulence from a subsurface convection zone to its eventual dissipation and escape through open magnetic flux tubes. We show how Alfven waves and turbulence can produce winds in either a hot corona or a cool extended chromosphere, and we specify the conditions that determine whether or not coronal heating occurs. These models do not utilize arbitrary normalization factors, but instead predict the mass loss rate directly from a star's fundamental properties. We take account of stellar magnetic activity by extending standard age-activity-rotation indicators to include the evolution of the filling factor of strong photospheric magnetic fields. We compared the predicted mass loss rates with observed values for 47 stars and found significantly better agreement than was obtained from the popular scaling laws of Reimers, Schroeder, and Cuntz. The algorithm used to compute cool-star mass loss rates is provided as a self-contained and efficient IDL computer code. We anticipate that the results from this kind of model can be incorporated straightforwardly into stellar evolution calculations and population synthesis techniques.

  2. Identifying tropospheric baseline air masses at Mauna Loa Observatory between 2004 and 2010 using Radon-222 and back trajectories

    NASA Astrophysics Data System (ADS)

    Chambers, Scott D.; Zahorowski, Wlodek; Williams, Alastair G.; Crawford, Jagoda; Griffiths, Alan D.

    2013-01-01

    We use 7 years of hourly radon observations at Mauna Loa Observatory (MLO), together with 10-day back trajectories, to identify baseline air masses at the station. The amplitude of the annual MLO radon cycle, based on monthly means, was 98 mBq m-3 (39 -137 mBq m-3), with maximum values in February (90th percentile 330 mBq m-3) and minimum values in August (10th percentile 8.1 mBq m-3). The composite diurnal radon cycle (amplitude 49 mBq m-3) is discussed with reference to the influences of local flow features affecting the site, and a 3-hour diurnal sampling window (0730-1030 HST) is proposed for observing the least terrestrially influenced tropospheric air masses. A set of 763 baseline events is selected, using the proposed sampling window together with trajectory information, and presented along with measured radon concentrations as a supplement. This data set represents a resource for the selection of baseline events at MLO for use with a range of trace species. A reduced set of 196 "deep baseline" events occurring in the July-September window is also presented and discussed. The distribution (10th/50th/90th percentile) of radon in deep-baseline events (8.7/29.2/66.1 mBq m-3) was considerably lower than that for the overall set of 763 baseline events (12.3/40.8/104.1 mBq m-3). Results from a simple budget calculation, using sonde-derived mixing depths and literature-based estimates of oceanic radon flux and radon concentrations in the marine boundary layer, indicate that the main source of residual radon in the lower troposphere under baseline conditions at MLO is downward mixing from aged terrestrial air masses in the upper troposphere.

  3. Catastrophic glacial multi-phase mass movements: a special type of glacial hazard

    NASA Astrophysics Data System (ADS)

    Petrakov, D. A.; Chernomorets, S. S.; Evans, S. G.; Tutubalina, O. V.

    2008-04-01

    Many glacier-related hazards are well typified and studied, but some events stand out from conventional classifications. The Kolka-Karmadon catastrophic event on 20 September 2002 in North Ossetia, North Caucasus, Russia is used as an example of a complex glacier failure exhibiting characteristics such as high mobility, long runout, ultrarapid movement and multiphase behaviour. We consider terminology protocol for glacier hazard classification and then, using the Kolka-Karmadon event and several other examples from around the world, we propose a new term for this family of events. Catastrophic glacier multi-phase mass movement (CGMM) is described and further illustrated by eight major events from Russia, Georgia, Peru, Chile, and Canada. CGMM have a combination of specific features: extraordinary velocities and long-distance runout despite low path angle; progressive fluidisation along travel path; superelevation and run-up of the moving mass, air blast wave in the avalanche flow phase; entrainment of available materials in its path, and the repeated nature of the event. CGMM events may affect areas remote from glaciers which were previously considered as safe.

  4. Investigation on Plasma Jet Flow Phenomena During DC Air Arc Motion in Bridge-Type Contacts

    NASA Astrophysics Data System (ADS)

    Zhai, Guofu; Bo, Kai; Chen, Mo; Zhou, Xue; Qiao, Xinlei

    2016-05-01

    Arc plasma jet flow in the air was investigated under a bridge-type contacts in a DC 270 V resistive circuit. We characterized the arc plasma jet flow appearance at different currents by using high-speed photography, and two polished contacts were used to search for the relationship between roughness and plasma jet flow. Then, to make the nature of arc plasma jet flow phenomena clear, a simplified model based on magnetohydrodynamic (MHD) theory was established and calculated. The simulated DC arc plasma was presented with the temperature distribution and the current density distribution. Furthermore, the calculated arc flow velocity field showed that the circular vortex was an embodiment of the arc plasma jet flow progress. The combined action of volume force and contact surface was the main reason of the arc jet flow. supported by National Natural Science Foundation of China (Nos. 51307030, 51277038)

  5. A genomics study of type 2 diabetes mellitus in U.S. Air Force personnel.

    PubMed

    Lott, Lisa

    2009-07-01

    The military community is at high risk for type 2 diabetes (T2D), especially as it relates to military beneficiaries, although preventive measures can be implemented to reduce disease onset. This study evaluates the prevalence of risk-associated single nucleotide polymorphisms in patients diagnosed with T2D within active duty, retired military, and military-dependent populations on Lackland Air Force Base compared to nondiabetic controls. Results will be used as a basis of comparison to analyze risk-conferring genotypes in the young, healthy active duty population to generate the prevalence of T2D risk-associated factors in our current and future war fighters. Identifying genetic markers of T2D prior to abnormal glucose control and insulin resistance may ultimately adjust future risk through early detection, healthy lifestyle modifications, and disease management programs.

  6. N-type doping of poly(p-phenylene vinylene) with air-stable dopants

    NASA Astrophysics Data System (ADS)

    Lu, Mingtao; Nicolai, Herman T.; Wetzelaer, Gert-Jan A. H.; Blom, Paul W. M.

    2011-10-01

    The electron transport in poly(p-phenylene vinylene) (PPV) derivatives blended with the air-stable n-type dopant (4-(1,3-dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)phenyl)dimethylamine (N-DMBI) is investigated. This dopant is activated after thin film deposition by annealing and strongly enhances the electron transport due to filling of electron traps as well as donation of free electrons to the lowest unoccupied molecular orbital (LUMO) of PPV. As a result, the electron current in a doped device exceeds the trap-free hole current. The total generated free electron density in the LUMO by the dopant typically amounts to 1023 m-3.

  7. Cost analysis of new and retrofit hot-air type solar assisted heating systems

    NASA Technical Reports Server (NTRS)

    Stewart, R. D.; Hawkins, B. J.

    1978-01-01

    A detailed cost analysis/cost improvement study was performed on two Department of Energy/National Aeronautics and Space Administration operational test sites to determine actual costs and potential cost improvements of new and retrofit hot air type, solar assisted heating and hot water systems for single family sized structures. This analysis concentrated on the first cost of a system which included procurement, installation, and integration of a solar assisted heating and hot water system on a new or retrofit basis; it also provided several cost projections which can be used as inputs to payback analyses, depending upon the degree of optimism or future improvements assumed. Cost definitions were developed for five categories of cost, and preliminary estimates were developed for each. The costing methodology, approach, and results together with several candidate low cost designs are described.

  8. Continental Land Mass Air Traffic Control (COLM ATC). [using three artificial satellite configurations

    NASA Technical Reports Server (NTRS)

    Pecar, J. A.; Henrich, J. E.

    1973-01-01

    The application of various satellite systems and techniques relative to providing air traffic control services for the continental United States was studied. Three satellite configurations were reviewed. The characteristics and capabilities of the satellites are described. The study includes consideration for the various ranging waveforms, multiple access alternatives, and the power and bandwidth required as a function of the number of users.

  9. Radio emission and mass loss rate limits of four young solar-type stars

    NASA Astrophysics Data System (ADS)

    Fichtinger, Bibiana; Güdel, Manuel; Mutel, Robert L.; Hallinan, Gregg; Gaidos, Eric; Skinner, Stephen L.; Lynch, Christene; Gayley, Kenneth G.

    2017-03-01

    Aims: Observations of free-free continuum radio emission of four young main-sequence solar-type stars (EK Dra, π1 UMa, χ1 Ori, and κ1 Cet) are studied to detect stellar winds or at least to place upper limits on their thermal radio emission, which is dominated by the ionized wind. The stars in our sample are members of The Sun in Time programme and cover ages of 0.1-0.65 Gyr on the main-sequence. They are similar in magnetic activity to the Sun and thus are excellent proxies for representing the young Sun. Upper limits on mass loss rates for this sample of stars are calculated using their observational radio emission. Our aim is to re-examine the faint young Sun paradox by assuming that the young Sun was more massive in its past, and hence to find a possible solution for this famous problem. Methods: The observations of our sample are performed with the Karl G. Jansky Very Large Array (VLA) with excellent sensitivity, using the C-band receiver from 4-8 GHz and the Ku-band from 12-18 GHz. Atacama Large Millimeter/Submillitmeter Array (ALMA) observations are performed at 100 GHz. The Common Astronomy Software Application (CASA) package is used for the data preparation, reduction, calibration, and imaging. For the estimation of the mass loss limits, spherically symmetric winds and stationary, anisotropic, ionized winds are assumed. We compare our results to 1) mass loss rate estimates of theoretical rotational evolution models; and 2) to results of the indirect technique of determining mass loss rates: Lyman-α absorption. Results: We are able to derive the most stringent direct upper limits on mass loss so far from radio observations. Two objects, EK Dra and χ1 Ori, are detected at 6 and 14 GHz down to an excellent noise level. These stars are very active and additional radio emission identified as non-thermal emission was detected, but limits for the mass loss rates of these objects are still derived. The emission of χ1 Ori does not come from the main target

  10. Dynamique de la désintégration pour trois types de processus nucléaires

    NASA Astrophysics Data System (ADS)

    Benfoughal, T.; Mirea, M.

    1995-07-01

    In order to study the dynamic behaviours of three disintegration modes (cold fission, alpha-decay and cluster radioactivities), we use a numerical method based on the Euler-Lagrange's equation of motion to obtain a constrained minimum of the WKB-integral in a tridimensional configuration space. The inertia is determined using the Werner-Wheeler approximation and the energy is computed in agreement with the Yukawa-plus-exponential model extended for binary systems with different charge densities. The degrees of freedom of the system are: elongation, necking-in and mass-asymmetry. Least-action trajectories are found for three decay-modes of ^{238}Pu. Afin d'étudier le comportement dynamique de trois modes de désintégration nucléaire (fission froide, désintégration alpha et radioactivité par émission d'ions lourd), nous utilisons une méthode numérique basée sur les équations d'Euler-Lagrange pour obtenir la trajectoire dynamique optimale dans un espace de configuration à trois dimensions. Les degrés de liberté du système retenus sont l'élongation, la taille du col et l'assymétrie de masse. Pour le calcul de l'intégrale d'action par la méthode WKB, l'inertie du système est déterminée dans l'approximation Werner-Wheeler, et l'énergie de déformation est calculée dans le cadre du modèle de la goutte liquide pour une interaction nucléaire de type Yukawa-plus-exponentielle, étendu aux systèmes binaires avec des densités de charge différentes. Cette méthode est appliquée à l'étude de trois modes de désintégration du Pu-238: désintégration alpha, radioactivité par émission du Si-32 et fission froide avec, pour fragment léger, le Mo-104.

  11. New mass limit for white dwarfs: super-Chandrasekhar type ia supernova as a new standard candle.

    PubMed

    Das, Upasana; Mukhopadhyay, Banibrata

    2013-02-15

    Type Ia supernovae, sparked off by exploding white dwarfs of mass close to the Chandrasekhar limit, play the key role in understanding the expansion rate of the Universe. However, recent observations of several peculiar type Ia supernovae argue for its progenitor mass to be significantly super-Chandrasekhar. We show that strongly magnetized white dwarfs not only can violate the Chandrasekhar mass limit significantly, but exhibit a different mass limit. We establish from a foundational level that the generic mass limit of white dwarfs is 2.58 solar mass. This explains the origin of overluminous peculiar type Ia supernovae. Our finding further argues for a possible second standard candle, which has many far reaching implications, including a possible reconsideration of the expansion history of the Universe.

  12. Detection of biological particles in ambient air using Bio-Aerosol Mass Spectrometry

    SciTech Connect

    McJimpsey, E L; Steele, P T; Coffee, K R; Fergenson, D P; Riot, V J; Woods, B W; Gard, E E; Frank, M; Tobias, H J; Lebrilla, C

    2006-03-16

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described.

  13. A reddening-free method to estimate the 56Ni mass of Type Ia supernovae

    NASA Astrophysics Data System (ADS)

    Dhawan, S.; Leibundgut, B.; Spyromilio, J.; Blondin, S.

    2016-04-01

    The increase in the number of Type Ia supernovae (SNe Ia) has demonstrated that the population shows greater diversity than has been assumed in the past. The reasons (e.g. parent population, explosion mechanism) for this diversity remain largely unknown. We investigated a sample of SNe Ia near-infrared light curves and correlated the phase of the second maximum with the bolometric peak luminosity. The peak bolometric luminosity is related to the time of the second maximum (relative to the B light curve maximum) as follows: Lmax(1043 erg s-1) = (0.039 ± 0.004) × t2(J)(days) + (0.013 ± 0.106). 56Ni masses can be derived from the peak luminosity based on Arnett's rule, which states that the luminosity at maximum is equal to the instantaneous energy generated by the nickel decay. We checked this assumption against recent radiative-transfer calculations of Chandrasekhar-mass delayed detonation models and find this assumption is valid to within 10% in recent radiative-transfer calculations of Chandrasekhar-mass delayed detonation models. The Lmax vs. t2 relation is applied to a sample of 40 additional SNe Ia with significant reddening (E(B - V) > 0.1 mag), and a reddening-free bolometric luminosity function of SNe Ia is established. The method is tested with the 56Ni mass measurement from the direct observation of γ-rays in the heavily absorbed SN 2014J and found to be fully consistent. Super-Chandrasekhar-mass explosions, in particular SN 2007if, do not follow the relations between peak luminosity and second IR maximum. This may point to an additional energy source contributing at maximum light. The luminosity function of SNe Ia is constructed and is shown to be asymmetric with a tail of low-luminosity objects and a rather sharp high-luminosity cutoff, although it might be influenced by selection effects.

  14. Systematic trends in total-mass profiles from dynamical models of early-type galaxies

    NASA Astrophysics Data System (ADS)

    Poci, Adriano; Cappellari, Michele; McDermid, Richard M.

    2017-01-01

    We study trends in the slope of the total mass profiles and dark matter fractions within the central half-light radius of 258 early-type galaxies, using data from the volume-limited ATLAS3D survey. We use three distinct sets of dynamical models, which vary in their assumptions and also allow for spatial variations in the stellar mass-to-light ratio, to test the robustness of our results. We confirm that the slopes of the total mass profiles are approximately isothermal, and investigate how the total-mass slope depends on various galactic properties. The most statistically-significant correlations we find are a function of either surface density, Σe, or velocity dispersion, σe. However there is evidence for a break in the latter relation, with a nearly universal logarithmic slope above log10[σe/(km s-1)] ˜ 2.1 and a steeper trend below this value. For the 142 galaxies above that critical σe value, the total mass-density logarithmic slopes have a mean value <γ'> = -2.193 ± 0.016 (1σ error) with an observed rms scatter of only σ _{γ ^' }= 0.168 ± 0.015. Considering the observational errors, we estimate an intrinsic scatter of σ _{γ ^' }^intr ≈ 0.15. These values are broadly consistent with those found by strong lensing studies at similar radii and agree, within the tight errors, with values recently found at much larger radii via stellar dynamics or HI rotation curves (using significantly smaller samples than this work).

  15. SOLAR RADIO TYPE-I NOISE STORM MODULATED BY CORONAL MASS EJECTIONS

    SciTech Connect

    Iwai, K.; Tsuchiya, F.; Morioka, A.; Misawa, H.; Miyoshi, Y.; Masuda, S.; Shimojo, M.; Shiota, D.; Inoue, S.

    2012-01-10

    The first coordinated observations of an active region using ground-based radio telescopes and the Solar Terrestrial Relations Observatory (STEREO) satellites from different heliocentric longitudes were performed to study solar radio type-I noise storms. A type-I noise storm was observed between 100 and 300 MHz during a period from 2010 February 6 to 7. During this period the two STEREO satellites were located approximately 65 Degree-Sign (ahead) and -70 Degree-Sign (behind) from the Sun-Earth line, which is well suited to observe the earthward propagating coronal mass ejections (CMEs). The radio flux of the type-I noise storm was enhanced after the preceding CME and began to decrease before the subsequent CME. This time variation of the type-I noise storm was directly related to the change of the particle acceleration processes around its source region. Potential-field source-surface extrapolation from the Solar and Heliospheric Observatory/Michelson Doppler Imager (SOHO/MDI) magnetograms suggested that there was a multipolar magnetic system around the active region from which the CMEs occurred around the magnetic neutral line of the system. From our observational results, we suggest that the type-I noise storm was activated at a side-lobe reconnection region that was formed after eruption of the preceding CME. This magnetic structure was deformed by a loop expansion that led to the subsequent CME, which then suppressed the radio burst emission.

  16. Modeling the competition between antenna size mutant and wild type microalgae in outdoor mass culture.

    PubMed

    de Mooij, Tim; Schediwy, Kira; Wijffels, René H; Janssen, Marcel

    2016-12-20

    Under high light conditions, microalgae are oversaturated with light which significantly reduces the light use efficiency. Microalgae with a reduced pigment content, antenna size mutants, have been proposed as a potential solution to increase the light use efficiency. The goal of this study was to investigate the competition between antenna size mutants and wild type microalgae in mass cultures. Using a kinetic model and literature-derived experimental data from wild type Chlorella sorokiniana, the productivity and competition of wild type cells and antenna size mutants were simulated. Cultivation was simulated in an outdoor microalgal raceway pond production system which was assumed to be limited by light only. Light conditions were based on a Mediterranean location (Tunisia) and a more temperate location (the Netherlands). Several wild type contamination levels were simulated in each mutant culture separately to predict the effect on the productivity over the cultivation time of a hypothetical summer season of 100days. The simulations demonstrate a good potential of antenna size reduction to increase the biomass productivity of microalgal cultures. However, it was also found that after a contamination with wild type cells the mutant cultures will be rapidly overgrown resulting in productivity loss.

  17. MASS AND DENSITY OF THE B-TYPE ASTEROID (702) ALAUDA

    SciTech Connect

    Rojo, P.; Margot, J. L. E-mail: jlm@astro.ucla.edu

    2011-02-01

    Observations with the adaptive optics system on the Very Large Telescope reveal that the outer main belt asteroid (702) Alauda has a small satellite with primary to secondary diameter ratio of {approx}56. The secondary revolves around the primary in 4.9143 {+-} 0.007 days at a distance of 1227 {+-} 24 km, yielding a total system mass of (6.057 {+-} 0.36) x 10{sup 18} kg. Combined with an IRAS size measurement, our data yield a bulk density of 1570 {+-} 500 kg m{sup -3} for this B-type asteroid.

  18. A comparison of solar helium-3-rich events with type II bursts and coronal mass ejections

    NASA Technical Reports Server (NTRS)

    Kahler, S.; Reames, D. V.; Sheeley, N. R., Jr.; Howard, R. A.; Michels, D. J.; Koomen, M. J.

    1985-01-01

    The acceleration process for energetic particles in He-3-rich events and for particles in normal-abundance events are compared. A list of 66 He-3-rich events observed with the Goddard Space Flight Center particle detector on ISEE 3 is presented, and it is shown that these events are not statistically associated with either of the two common signatures of normal-abundance events, metric type II and coronal mass ejections. This result indicates that enhanced abundance events may be produced only in the impulsive phases of flares, while normal abundance events are produced in subsequent flare shock waves.

  19. Probing mass transfer in mesoporous faujasite-type zeolite nanosheet assemblies.

    PubMed

    Mehlhorn, Dirk; Inayat, Alexandra; Schwieger, Wilhelm; Valiullin, Rustem; Kärger, Jörg

    2014-06-06

    Pulsed field gradient nuclear magnetic resonance (NMR) diffusion studies are performed by using cyclohexane to probe transport properties in a NaX-type zeolite with a hierarchical pore structure (house-of-cards-like assemblies of mesoporous nanosheets), which is compared with a purely microporous sample. With guest loadings chosen to ensure saturation of the micropores, and the meso- and macropores left essentially unoccupied, guest diffusion is shown to be enhanced by almost one order of magnitude, even at room temperature. Diffusivity enhancement is further increased with increasing temperature, which may, therefore, be unambiguously attributed to the contribution of mass transfer in the meso- and macropores.

  20. Facility monitoring of chemical warfare agent simulants in air using an automated, field-deployable, miniature mass spectrometer.

    PubMed

    Smith, Jonell N; Noll, Robert J; Cooks, R Graham

    2011-05-30

    Vapors of four chemical warfare agent (CWA) stimulants, 2-chloroethyl ethyl sulfide (CEES), diethyl malonate (DEM), dimethyl methylphosphonate (DMMP), and methyl salicylate (MeS), were detected, identified, and quantitated using a fully automated, field-deployable, miniature mass spectrometer. Samples were ionized using a glow discharge electron ionization (GDEI) source, and ions were mass analyzed with a cylindrical ion trap (CIT) mass analyzer. A dual-tube thermal desorption system was used to trap compounds on 50:50 Tenax TA/Carboxen 569 sorbent before their thermal release. The sample concentrations ranged from low parts per billion [ppb] to two parts per million [ppm]. Limits of detection (LODs) ranged from 0.26 to 5.0 ppb. Receiver operating characteristic (ROC) curves are presented for each analyte. A sample of CEES at low ppb concentration was combined separately with two interferents, bleach (saturated vapor) and diesel fuel exhaust (1%), as a way to explore the capability of detecting the simulant in an environmental matrix. Also investigated was a mixture of the four CWA simulants (at concentrations in air ranging from 270 to 380 ppb). Tandem mass (MS/MS) spectral data were used to identify and quantify the individual components.

  1. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    SciTech Connect

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-18

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22 cm diameter and 30 cm length, purifies an airflow rate of 5000 lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  2. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    NASA Astrophysics Data System (ADS)

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-01

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22cm diameter and 30cm length, purifies an airflow rate of 5000lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  3. Identification of European Air Masses Using an Interactive Computer Technique for Separating Mixed Normal Distributions.

    DTIC Science & Technology

    1982-01-01

    classifying a maritime surface, he refers to the Pacific, Atlantic, or Gulf of Mexico using the general term "maritime" only when the exact origin is...portions of North Atlantic NPA PA air modified over warm North Atlantic TC Southern U.S. and Northern Mexico TG Gulf of Mexico and Caribbean NTG TG...Bergeron, T., 1928: " Uber Die Dreidimensional Verknupfende Wetteranalyse, Teil I." Geofys. Pub!., Vol. 5, No. 6. Berggren, R., 1953: "On Temperature

  4. Properties of individual aerosol particles and their relation to air mass origins in a south China coastal city

    NASA Astrophysics Data System (ADS)

    Shi, Zongbo; He, Kebin; Xue, Zhigang; Yang, Fumo; Chen, Yanju; Ma, Yongliang; Luo, Jiaojiao

    2009-05-01

    Atmospheric particles in urban and rural areas in Shenzhen city were collected in summer and winter 2004. The particles were analyzed using a scanning electron microscope equipped with an energy dispersive X-ray spectrometer. The fine particles (<1 μm) were categorized into chain-like, elongated, rounded, and others on the basis of their morphology. Chain-like particles were likely soot aggregates. In summer and winter, chain-like particles accounted for 43% and 42% of total particles in the urban area, and 22% and 43% in the rural area, respectively. The elongated particles were mixtures of aged sea salts and ammonium sulfate, suggesting an aqueous phase reaction mechanism, i.e., in-cloud sulfate formation. Such particles occupied 12% of total particles in the urban area in the summer and were rarely observed in the wintertime samples. The rounded particles were mainly composed of sulfate and/or carbon. Their number concentration in the urban area was more than three times higher in the winter. In addition, we found that air masses from northern inland contained much higher concentrations of particles than those from the ocean. This was particularly evident in the rural area, where concentrations of chain-like and rounded particles were eight times higher in the continental air masses. These results suggest the strong influence of regional pollution on the particle number concentrations in the coastal city.

  5. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean.

    PubMed

    Garrison, V H; Majewski, M S; Foreman, W T; Genualdi, S A; Mohammed, A; Massey Simonich, S L

    2014-01-15

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9-126 ng/m(3) (mean = 25 ± 34) at source and 0.05-0.71 ng/m(3) (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1-3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  6. An improved, automated whole air sampler and gas chromatography mass spectrometry analysis system for volatile organic compounds in the atmosphere

    NASA Astrophysics Data System (ADS)

    Lerner, Brian M.; Gilman, Jessica B.; Aikin, Kenneth C.; Atlas, Elliot L.; Goldan, Paul D.; Graus, Martin; Hendershot, Roger; Isaacman-VanWertz, Gabriel A.; Koss, Abigail; Kuster, William C.; Lueb, Richard A.; McLaughlin, Richard J.; Peischl, Jeff; Sueper, Donna; Ryerson, Thomas B.; Tokarek, Travis W.; Warneke, Carsten; Yuan, Bin; de Gouw, Joost A.

    2017-01-01

    Volatile organic compounds were quantified during two aircraft-based field campaigns using highly automated, whole air samplers with expedited post-flight analysis via a new custom-built, field-deployable gas chromatography-mass spectrometry instrument. During flight, air samples were pressurized with a stainless steel bellows compressor into electropolished stainless steel canisters. The air samples were analyzed using a novel gas chromatograph system designed specifically for field use which eliminates the need for liquid nitrogen. Instead, a Stirling cooler is used for cryogenic sample pre-concentration at temperatures as low as -165 °C. The analysis system was fully automated on a 20 min cycle to allow for unattended processing of an entire flight of 72 sample canisters within 30 h, thereby reducing typical sample residence times in the canisters to less than 3 days. The new analytical system is capable of quantifying a wide suite of C2 to C10 organic compounds at part-per-trillion sensitivity. This paper describes the sampling and analysis systems, along with the data analysis procedures which include a new peak-fitting software package for rapid chromatographic data reduction. Instrument sensitivities, uncertainties and system artifacts are presented for 35 trace gas species in canister samples. Comparisons of reported mixing ratios from each field campaign with measurements from other instruments are also presented.

  7. Immunolocalization of choline acetyltransferase of common type in the central brain mass of Octopus vulgaris

    PubMed Central

    Casini, A.; Vaccaro, R.; D'Este, L.; Sakaue, Y.; Bellier, J.P.; Kimura, H.; Renda, T.G.

    2012-01-01

    Acetylcholine, the first neurotransmitter to be identified in the vertebrate frog, is widely distributed among the animal kingdom. The presence of a large amount of acetylcholine in the nervous system of cephalopods is well known from several biochemical and physiological studies. However, little is known about the precise distribution of cholinergic structures due to a lack of a suitable histochemical technique for detecting acetylcholine. The most reliable method to visualize the cholinergic neurons is the immunohistochemical localization of the enzyme choline acetyltransferase, the synthetic enzyme of acetylcholine. Following our previous study on the distribution patterns of cholinergic neurons in the Octopus vulgaris visual system, using a novel antibody that recognizes choline acetyltransferase of the common type (cChAT), now we extend our investigation on the octopus central brain mass. When applied on sections of octopus central ganglia, immunoreactivity for cChAT was detected in cell bodies of all central brain mass lobes with the notable exception of the subfrontal and subvertical lobes. Positive varicosed nerves fibers where observed in the neuropil of all central brain mass lobes. PMID:23027350

  8. Spreading out Muscle Mass within a Hill-Type Model: A Computer Simulation Study

    PubMed Central

    Günther, Michael; Röhrle, Oliver; Haeufle, Daniel F. B.; Schmitt, Syn

    2012-01-01

    It is state of the art that muscle contraction dynamics is adequately described by a hyperbolic relation between muscle force and contraction velocity (Hill relation), thereby neglecting muscle internal mass inertia (first-order dynamics). Accordingly, the vast majority of modelling approaches also neglect muscle internal inertia. Assuming that such first-order contraction dynamics yet interacts with muscle internal mass distribution, this study investigates two questions: (i) what is the time scale on which the muscle responds to a force step? (ii) How does this response scale with muscle design parameters? Thereto, we simulated accelerated contractions of alternating sequences of Hill-type contractile elements and point masses. We found that in a typical small muscle the force levels off after about 0.2 ms, contraction velocity after about 0.5 ms. In an upscaled version representing bigger mammals' muscles, the force levels off after about 20 ms, and the theoretically expected maximum contraction velocity is not reached. We conclude (i) that it may be indispensable to introduce second-order contributions into muscle models to understand high-frequency muscle responses, particularly in bigger muscles. Additionally, (ii) constructing more elaborate measuring devices seems to be worthwhile to distinguish viscoelastic and inertia properties in rapid contractile responses of muscles. PMID:23227110

  9. The Progenitor of the FUor-Type Young Eruptive Star 2MASS J06593158-0405277

    NASA Astrophysics Data System (ADS)

    Kóspál, Á.; Ábrahám, P.; Moór, A.; Haas, M.; Chini, R.; Hackstein, M.

    2015-03-01

    Only a dozen confirmed FU Orionis-type young outbursting stars (FUors) are known today; this explains the interest in the recent FUor eruption of 2MASS J06593158-0405277. Its outburst and expected decline will be subject to numerous studies in the future. Almost equally important for the understanding of the eruption mechanism, however, is the physical characterization of the FUor’s precursor. Here we analyze unpublished archival data and summarize—and partly revise—all relevant photometry from optical to submillimeter wavelengths. Our analysis implies that the FUor is possibly associated with eight T Tauri star candidates and a strong Class 0 source. Adopting a distance of 450 pc for the FUor, we derive a quiescent bolometric luminosity and temperature of {{L}bol} = 4.8 L ⊙ and {{T}bol} = 1190 K, typical for young Class II sources. The central star has a temperature of {{T}eff} = 4000 K, a mass of 0.75 M ⊙ , and an age of about 6 × 105 yr. The SED implies a circumstellar mass of 0.01-0.06 M ⊙ , and the system is surrounded by a faint infrared nebulosity. Our results provide an almost complete picture of a FUor progenitor, supporting the interpretation of future post-outburst studies. Based on observations made with the Herschel Space Observatory. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

  10. Immunolocalization of choline acetyltransferase of common type in the central brain mass of Octopus vulgaris.

    PubMed

    Casini, A; Vaccaro, R; D'Este, L; Sakaue, Y; Bellier, J P; Kimura, H; Renda, T G

    2012-07-19

    Acetylcholine, the first neurotransmitter to be identified in the vertebrate frog, is widely distributed among the animal kingdom. The presence of a large amount of acetylcholine in the nervous system of cephalopods is well known from several biochemical and physiological studies. However, little is known about the precise distribution of cholinergic structures due to a lack of a suitable histochemical technique for detecting acetylcholine. The most reliable method to visualize the cholinergic neurons is the immunohistochemical localization of the enzyme choline acetyltransferase, the synthetic enzyme of acetylcholine. Following our previous study on the distribution patterns of cholinergic neurons in the Octopus vulgaris visual system, using a novel antibody that recognizes choline acetyltransferase of the common type (cChAT), now we extend our investigation on the octopus central brain mass. When applied on sections of octopus central ganglia, immunoreactivity for cChAT was detected in cell bodies of all central brain mass lobes with the notable exception of the subfrontal and subvertical lobes. Positive varicosed nerves fibers where observed in the neuropil of all central brain mass lobes.

  11. Shotgun Analysis of Rough-Type Lipopolysaccharides Using Ultraviolet Photodissociation Mass Spectrometry.

    PubMed

    Klein, Dustin R; Holden, Dustin D; Brodbelt, Jennifer S

    2016-01-05

    Detailed structural characterization of intact rough-type lipopolysaccharides (R-LPS) was accomplished using a multi-stage mass spectrometry (MS(3)) strategy consisting of collision-induced dissociation (CID) followed by 193 ultraviolet photodissociation (UVPD) implemented on an Orbitrap Fusion mass spectrometer. Complex mixtures of R-LPS from either Escherichia coli or Salmonella enterica were directly infused into the mass spectrometer using static source nanoelectrospray ionization (nanoESI). An initial CID event performed on an R-LPS precursor produced spectra with abundant ions corresponding to the lipid A and core oligosaccharide (OS) substructures. Comparison of CID spectra of R-LPS ions with varying lipid A and core OS structures verifies that lipid A and core OS ions are consistently produced in high abundance. The resulting lipid A and core OS ions were subsequently activated by CID, high-energy collision-induced dissociation (HCD), or UVPD. For both the lipid A and core OS substructures, HCD and UVPD produced highly informative complementary spectra, with UVPD of the core OS producing an extensive array of cross-ring cleavage fragments. Successful discernment of E. coli R-LPS structures with isomeric core structures confirmed the degree to which subtle structural differences could be determined using this method.

  12. AN IMPROVED AIR-DRIVEN TYPE OF ULTRACENTRIFUGE FOR MOLECULAR SEDIMENTATION

    PubMed Central

    Bauer, Johannes H.; Pickels, Edward G.

    1937-01-01

    1. A description is given of the construction details and operation characteristics of an improved type of air-driven ultracentrifuge operating in vacuum and suitable for the determination of sedimentation constants of protein molecules. 2. The rotor of the centrifuge is made of a forged aluminum alloy; it is oval in shape, measures 185 mm. at its greatest diameter, and weighs 3,430 gm. It carries a transparent cell located at a distance of 65 mm. from the axis of rotation and designed to accommodate a fluid column 15 mm. high. 3. The rotor has been run repeatedly over long periods at a speed of 60,000 R.P.M., which corresponds to a centrifugal force of 260,000 times gravity in the center of the cell. At this speed no deformation of the rotor nor leakage of the cell has been observed. 4. The sharp definition of sedimentation photographs taken at high speed serves to indicate the absence of detectable vibrations in the centrifuge. 5. When a vacuum of less than 1 micron of mercury is maintained in the centrifuge chamber, the rise in the rotor temperature amounts to only 1 or 2°C. after several hours' run at high speed. 6. There has been no evidence of convection currents interfering with normal sedimentation of protein molecules in the centrifugal field. 7. A driving air pressure of about 18 pounds per square inch is sufficient to maintain the centrifuge at a steady speed of 60,000 R.P.M. With a driving pressure of 80 pounds per square inch, it can be accelerated to this speed in less than 20 minutes, and also brought to rest in about the same length of time by the application of the braking system. 8. The adaptation of Svedberg's optical systems to this centrifuge for photographically recording the movement of sedimentation boundaries is described. PMID:19870619

  13. Easily doped p-type, low hole effective mass, transparent oxides

    NASA Astrophysics Data System (ADS)

    Sarmadian, Nasrin; Saniz, Rolando; Partoens, Bart; Lamoen, Dirk

    2016-02-01

    Fulfillment of the promise of transparent electronics has been hindered until now largely by the lack of semiconductors that can be doped p-type in a stable way, and that at the same time present high hole mobility and are highly transparent in the visible spectrum. Here, a high-throughput study based on first-principles methods reveals four oxides, namely X2SeO2, with X = La, Pr, Nd, and Gd, which are unique in that they exhibit excellent characteristics for transparent electronic device applications – i.e., a direct band gap larger than 3.1 eV, an average hole effective mass below the electron rest mass, and good p-type dopability. Furthermore, for La2SeO2 it is explicitly shown that Na impurities substituting La are shallow acceptors in moderate to strong anion-rich growth conditions, with low formation energy, and that they will not be compensated by anion vacancies VO or VSe.

  14. The Relationship between Body Mass Index and Periodontitis in Arab Patients with Type 2 Diabetes Mellitus

    PubMed Central

    Awad, Manal; Rahman, Betul; Hasan, Haidar; Ali, Houssam

    2015-01-01

    Objective Our study sought to evaluate the association between periodontitis and body mass index (BMI) among patients with type 2 diabetes mellitus.  Methods In this cross-sectional case control study analysis of 186 diabetic patients, 112 patients had a body mass index ≥30kg/m2 and 74 control patients had BMI <30kg/m2. All participants underwent oral examinations including a full mouth recording of clinical attachment level (CAL). Information regarding HbA1c levels and high-sensitivity C-reactive protein (hs-CRP) were also gathered.  Results Over half (61%) of patients had a BMI ≥30. Of these 52% had CAL less than 2mm. Multivariate logistic regression analysis showed that there was no association between BMI and CAL. In addition, hs-CRP levels were significantly and positively associated with CAL (OR:1.06, 95% CI: 1.01, 1.12; p=0.007).  Conclusion Among patients with type 2 diabetes mellitus, there was no association between periodontitis and BMI. More studies are needed to further explore this relationship taking into consideration additional lifestyle factors. PMID:25829999

  15. Imaging of β-cell mass and insulitis in insulin-dependent (Type 1) diabetes mellitus.

    PubMed

    Di Gialleonardo, Valentina; de Vries, Erik F J; Di Girolamo, Marco; Quintero, Ana M; Dierckx, Rudi A J O; Signore, Alberto

    2012-12-01

    Insulin-dependent (type 1) diabetes mellitus is a metabolic disease with a complex multifactorial etiology and a poorly understood pathogenesis. Genetic and environmental factors cause an autoimmune reaction against pancreatic β-cells, called insulitis, confirmed in pancreatic samples obtained at autopsy. The possibility to noninvasively quantify β-cell mass in vivo would provide important biological insights and facilitate aspects of diagnosis and therapy, including follow-up of islet cell transplantation. Moreover, the availability of a noninvasive tool to quantify the extent and severity of pancreatic insulitis could be useful for understanding the natural history of human insulin-dependent (type 1) diabetes mellitus, to early diagnose children at risk to develop overt diabetes, and to select patients to be treated with immunotherapies aimed at blocking the insulitis and monitoring the efficacy of these therapies. In this review, we outline the imaging techniques currently available for in vivo, noninvasive detection of β-cell mass and insulitis. These imaging techniques include magnetic resonance imaging, ultrasound, computed tomography, bioluminescence and fluorescence imaging, and the nuclear medicine techniques positron emission tomography and single-photon emission computed tomography. Several approaches and radiopharmaceuticals for imaging β-cells and lymphocytic insulitis are reviewed in detail.

  16. Analysis of galanthamine-type alkaloids by capillary gas chromatography-mass spectrometry in plants.

    PubMed

    Berkov, Strahil; Bastida, Jaume; Viladomat, Francesc; Codina, Carles

    2008-01-01

    Galanthamine, an acetylcholinesterase inhibitor used for the treatment of Alzheimer's disease, and galanthamine-type alkaloids are synthesised in different plants of the family Amaryllidaceae. A capillary gas chromatographic-mass spectroscopic (CGC-MS) method for the separation of 7 galanthamine type alkaloids, including galanthamine and epigalanthamine, is described in the present paper. A simple method for the routine quantification of galanthamine in plants was developed using pre-packed columns with diatomaceous earth (Isolute HM-N), allowing simultaneous preparation of a large number of samples. Galanthamine showed excellent linearity in the range from 50 to 1000 microg/mL and the limit of quantification was 5 microg/mL in total ion current mode and 1.6 ng/mL in selected ion monitoring mode. The recovery of galanthamine was more than 90%. Interday reproducibility (RSD) of the extraction was 2.74%. A method to find and to microextract Amaryllidaceae alkaloids in low-mass plant samples is also described.

  17. Novel type of tuned mass damper with inerter which enables changes of inertance

    NASA Astrophysics Data System (ADS)

    Brzeski, P.; Kapitaniak, T.; Perlikowski, P.

    2015-08-01

    In this paper we propose the novel type of tuned mass damper and investigate its properties. Characteristic feature of the device is that it contains a special type of inerter equipped with a continuously variable transmission and gear-ratio control system which enables stepless and accurate changes of inertance. We examine the damping properties of the proposed tuned mass damper with respect to one-degree-of-freedom harmonically forced oscillator. To prove the potential of introduced device we test its four different embodiments characterized by four different sets of parameters. We generalize our investigation and show that proposed device has broad spectrum of applications, we consider three different stiffness characteristics of damped structure i.e. linear, softening and hardening. We use the frequency response curves to present how considered devices influence the dynamics of analyzed systems and demonstrate their capabilities. Moreover, we check how small perturbations introduced to the system by parametric and additive noise influence system's dynamics. Numerical results show excellent level of vibration reduction in an extremely wide range of forcing frequencies.

  18. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J. C.; Sodeau, J. R.; Healy, R. M.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; O'Dowd, C. D.

    2009-12-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the NE Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Black carbon concentrations in polluted air were between 300-400 ng m-3, and in clean marine air were less than 50 ng m-3. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water

  19. Mass spectrometric analysis and aerodynamic properties of various types of combustion-related aerosol particles

    NASA Astrophysics Data System (ADS)

    Schneider, J.; Weimer, S.; Drewnick, F.; Borrmann, S.; Helas, G.; Gwaze, P.; Schmid, O.; Andreae, M. O.; Kirchner, U.

    2006-12-01

    Various types of combustion-related particles in the size range between 100 and 850 nm were analyzed with an aerosol mass spectrometer and a differential mobility analyzer. The measurements were performed with particles originating from biomass burning, diesel engine exhaust, laboratory combustion of diesel fuel and gasoline, as well as from spark soot generation. Physical and morphological parameters like fractal dimension, effective density, bulk density and dynamic shape factor were derived or at least approximated from the measurements of electrical mobility diameter and vacuum aerodynamic diameter. The relative intensities of the mass peaks in the mass spectra obtained from particles generated by a commercial diesel passenger car, by diesel combustion in a laboratory burner, and by evaporating and re-condensing lubrication oil were found to be very similar. The mass spectra from biomass burning particles show signatures identified as organic compounds like levoglucosan but also others which are yet unidentified. The aerodynamic behavior yielded a fractal dimension (Df) of 2.09 +/- 0.06 for biomass burning particles from the combustion of dry beech sticks, but showed values around three, and hence more compact particle morphologies, for particles from combustion of more natural oak. Scanning electron microscope images confirmed the finding that the beech combustion particles were fractal-like aggregates, while the oak combustion particles displayed a much more compact shape. For particles from laboratory combusted diesel fuel, a Df value of 2.35 was found, for spark soot particles, Df [approximate] 2.10. The aerodynamic properties of fractal-like particles from dry beech wood combustion indicate an aerodynamic shape factor [chi] that increases with electrical mobility diameter, and a bulk density of 1.92 g cm-3. An upper limit of [chi] [approximate] 1.2 was inferred for the shape factor of the more compact particles from oak combustion.

  20. Ultraviolet observations of Super-Chandrasekhar mass type Ia supernova candidates with swift UVOT

    SciTech Connect

    Brown, Peter J.; Smitka, Michael T.; Krisciunas, Kevin; Wang, Lifan; Kuin, Paul; De Pasquale, Massimiliano; Scalzo, Richard; Holland, Stephen; Milne, Peter

    2014-05-20

    Among Type Ia supernovae (SNe Ia), a class of overluminous objects exist whose ejecta mass is inferred to be larger than the canonical Chandrasekhar mass. We present and discuss the UV/optical photometric light curves, colors, absolute magnitudes, and spectra of three candidate Super-Chandrasekhar mass SNe—2009dc, 2011aa, and 2012dn—observed with the Swift Ultraviolet/Optical Telescope. The light curves are at the broad end for SNe Ia, with the light curves of SN 2011aa being among the broadest ever observed. We find all three to have very blue colors which may provide a means of excluding these overluminous SNe from cosmological analysis, though there is some overlap with the bluest of 'normal' SNe Ia. All three are overluminous in their UV absolute magnitudes compared to normal and broad SNe Ia, but SNe 2011aa and 2012dn are not optically overluminous compared to normal SNe Ia. The integrated luminosity curves of SNe 2011aa and 2012dn in the UVOT range (1600-6000 Å) are only half as bright as SN 2009dc, implying a smaller {sup 56}Ni yield. While it is not enough to strongly affect the bolometric flux, the early time mid-UV flux makes a significant contribution at early times. The strong spectral features in the mid-UV spectra of SNe 2009dc and 2012dn suggest a higher temperature and lower opacity to be the cause of the UV excess rather than a hot, smooth blackbody from shock interaction. Further work is needed to determine the ejecta and {sup 56}Ni masses of SNe 2011aa and 2012dn and to fully explain their high UV luminosities.

  1. Upper air relaxation in regional climate model improves resolved interannual variability of the surface mass balance of Antarctica

    NASA Astrophysics Data System (ADS)

    van de Berg, Willem Jan; Medley, Brooke; van Meijgaard, Erik

    2015-04-01

    The surface mass balance (SMB) determines the variability of the mass balance of the Antarctic Ice sheet on sub-decadal timescales. Since continent-wide SMB cannot be measured, it must be modeled and regional climate models (RCMs) generally outperform global reanalyses in the representation of total mass flux and the spatial distribution of SMB. However, if RCMs are only forced with reanalysis on their lateral boundaries, the representation of the interannual variability of SMB deteriorates significantly. In this study we show how to improve the resolved interannual variability in RCM modeled SMB. For this purpose we use annual SMB observations in the Thwaites drainage basin in Antarctica derived from airborne radar reflections and the RCM RACMO2. RACMO2, driven by ERA-Interim, better represents the mean spatial SMB pattern in this basin than ERA-Interim. However, without relaxation in the interior, RACMO2 poorly resolves the observed interannual SMB variability. If we gently relax the temperature and wind field in the upper atmosphere in RACMO2 to ERA-Interim, RACMO2 gets the best of both. Upper air relaxation little changes the mean SMB and spatial pattern compared to the original RACMO2 output, but allows RACMO2 to resolve the observed interannual SMB as good as ERA-Interim.

  2. Decomposing the profile of PM in two low polluted German cities--mapping of air mass residence time, focusing on potential long range transport impacts.

    PubMed

    Dimitriou, Konstantinos; Kassomenos, Pavlos

    2014-07-01

    This paper aims to decompose the profile of particulates in Karlsruhe and Potsdam (Germany), focusing on the localization of PM potential transboundary sources. An air mass cluster analysis was implemented, followed by a study of air mass residence time on a grid of a 0.5° × 0.5° resolution. Particulate/gaseous daily air pollution and meteorological data were used to indicate PM local sources. Four Principal Component Analysis (PCA) components were produced: traffic, photochemical, industrial/domestic and particulate. PM2.5/PM10 ratio seasonal trends, indicated production of PMCOARSE (PM10-PM2.5) from secondary sources in Potsdam during warm period (WP). The residing areas of incoming slow moving air masses are potential transboundary PM sources. For Karlsruhe those areas were mainly around the city. An air mass residence time secondary peak was observed over Stuttgart. For Potsdam, areas with increased dwelling time of the arriving air parcels were detected particularly above E/SE Germany.

  3. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  4. Does body mass index matter while selecting the flap type for pharyngeal reconstructions?

    PubMed

    Calli, Caglar; Teknos, Theodoros N; Agrawal, Amit; Schuller, David E; Ozer, Enver; Songu, Murat

    2014-05-01

    The aim of our study was to investigate the effect of patient-related factors, such as the body mass index (BMI) and tumor size, in selecting the flap type for the reconstruction of pharyngeal defects. This retrospective review included 182 patients with pharyngeal defect reconstructions with free and pedicled flaps at the Ohio State University from January 2005 to December 2008. We conducted a retrospective comparison of variety of different flap reconstruction techniques. We compared different flap reconstruction with BMI and tumor size without functional outcome such as swallowing and speech data. Although there was no statistically significant correlation (P > 0.05) when comparing the free flaps with pedicled flaps according to the BMI and tumor size, there was an obvious tendency to prefer radial forearm free flap over anterolateral thigh free flap in patients who are overweight and those with obesity with a ratio of 32:3. In the same group of patients, a similar tendency was observed to prefer fibular free flap over iliac crest free flap with a ratio of 14:5, whereas the ratio was becoming 3:5 in favor of iliac crest free flap over fibular free flap in patients with BMI of 24 or lower. Despite the fact that surgeons' experience with a certain flap type is one of the most important factors while determining which flap to reconstruct, BMI might have a significant impact while selecting the free flap types for the reconstruction of pharyngeal defects.

  5. Impulsivity as a moderator of the associations between child maltreatment types and body mass index.

    PubMed

    Brown, Shaquanna; Mitchell, Tarrah B; Fite, Paula J; Bortolato, Marco

    2017-03-02

    Child maltreatment has emerged as an important risk factor for adult obesity (Danese & Tan, 2014; Hemmingsson et al., 2014). However, there is a need for research delineating the factors that play a role in this association. Impulsivity has been shown to be associated with both child maltreatment (Brodsky et al., 2001) and body mass index (BMI; Cortese et al., 2008; Thamotharan et al., 2013). Further, given previous research showing that adverse events interact with impulsivity to predict hazardous drinking behaviors (Fox et al., 2010), there is reason to hypothesize that child maltreatment might interact with impulsivity to predict other adverse health outcomes, such as elevated BMI. Accordingly, the current study examined whether impulsivity moderated the association between child maltreatment types (i.e., physical abuse, physical neglect, sexual abuse, emotional abuse, and emotional neglect) and BMI. The sample was comprised of 500 undergraduate students (49.6% male) between the ages of 18 and 25 years. Regression analyses suggested that maltreatment types and impulsivity were not uniquely associated with BMI. However, impulsivity moderated the association between childhood sexual abuse and adult BMI, such that BMI was highest at high levels of both sexual abuse and impulsivity. Impulsivity did not moderate the associations between the other child maltreatment types and BMI. Limitations, future directions, and clinical implications of this research are discussed.

  6. Measurement of breath acetone concentrations by selected ion flow tube mass spectrometry in type 2 diabetes.

    PubMed

    Storer, Malina; Dummer, Jack; Lunt, Helen; Scotter, Jenny; McCartin, Fiona; Cook, Julie; Swanney, Maureen; Kendall, Deborah; Logan, Florence; Epton, Michael

    2011-12-01

    Selected ion flow tube-mass spectrometry (SIFT-MS) can measure volatile compounds in breath on-line in real time and has the potential to provide accurate breath tests for a number of inflammatory, infectious and metabolic diseases, including diabetes. Breath concentrations of acetone in type 2 diabetic subjects undertaking a long-term dietary modification programme were studied. Acetone concentrations in the breath of 38 subjects with type 2 diabetes were determined by SIFT-MS. Anthropomorphic measurements, dietary intake and medication use were recorded. Blood was analysed for beta hydroxybutyrate (a ketone body), HbA1c (glycated haemoglobin) and glucose using point-of-care capillary (fingerprick) testing. All subjects were able to undertake breath manoeuvres suitable for analysis. Breath acetone varied between 160 and 862 ppb (median 337 ppb) and was significantly higher in men (median 480 ppb versus 296 ppb, p = 0.01). In this cross-sectional study, no association was observed between breath acetone and either dietary macronutrients or point-of-care capillary blood tests. Breath analysis by SIFT-MS offers a rapid, reproducible and easily performed measurement of acetone concentration in ambulatory patients with type 2 diabetes. The high inter-individual variability in breath acetone concentration may limit its usefulness in cross-sectional studies. Breath acetone may nevertheless be useful for monitoring metabolic changes in longitudinal metabolic studies, in a variety of clinical and research settings.

  7. Differential optical absorption spectroscopy (DOAS) and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    NASA Astrophysics Data System (ADS)

    Rozanov, V. V.; Rozanov, A. V.

    2010-06-01

    The Differential Optical Absorption Spectroscopy (DOAS) technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering. Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS), the modified (MDOAS), and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption. The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as well as of the relationship between

  8. Differential optical absorption spectroscopy (DOAS) and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    NASA Astrophysics Data System (ADS)

    Rozanov, V. V.; Rozanov, A. V.

    2010-02-01

    The Differential Optical Absorption Spectroscopy (DOAS) technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering. Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS), the modified (MDOAS), and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption. The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as well as of the relationship between

  9. Apparent contact angles induced by evaporation into air: interferometric measurements and lubrication-type modeling

    NASA Astrophysics Data System (ADS)

    Colinet, Pierre; Tsoumpas, Yannis; Dehaeck, Sam; Rednikov, Alexey

    2014-11-01

    For volatile liquids, finite contact angles on solid substrates can occur even in the case of perfect wetting, immobile contact lines and ideally smooth surfaces. This is a fluid-dynamic effect due to evaporation typically intensifying towards a small vicinity of the contact line. In the present talk, we first overview recent theoretical results on the subject, where we focus primarily on the case of diffusion-limited evaporation into air. The model is based upon the so-called de Gennes' paradigm, incorporating simultaneously the spreading coefficient and the disjoining pressure in the form of an inverse cubic law. Then we carry out comparison with experimental results for the contact angles of evaporating sessile drops of several perfectly-wetting HFE liquids of different volatility recently obtained by Mach-Zehnder interferometry. The scaling-type theoretical prediction for the apparent contact angle is found to be in good agreement with experimental measurements. Another model based upon the Kelvin effect (curvature dependence of the saturation conditions) is also briefly discussed, an important conceptual feature of which being that contact-line singularities (both evaporation- and motion-induced) can be fully regularized, in contrast with the first model. Support from ESA, BELSPO and FRS-FNRS is gratefully acknowledged.

  10. Complete Genome Sequence of Rothia aeria Type Strain JCM 11412, Isolated from Air in the Russian Space Laboratory Mir.

    PubMed

    Nambu, Takayuki; Tsuzukibashi, Osamu; Uchibori, Satoshi; Yamane, Kazuyoshi; Yamanaka, Takeshi; Maruyama, Hugo; Wang, Pao-Li; Mugita, Naho; Morioka, Hiroki; Takahashi, Kazuya; Komasa, Yutaka; Mashimo, Chiho

    2016-12-29

    Here, we present the complete genome sequence of Rothia aeria type strain JCM 11412, isolated from air in the Russian space laboratory Mir. Recently, there has been an increasing number of reports on infections caused by R. aeria The genomic information will enable researchers to identify the pathogenicity of this organism.

  11. [Aerodynamics study on pressure changes inside pressure-type whole-body plethysmograph produced by flowing air].

    PubMed

    Xu, Wei-Hua; Shen, Hua-Hao

    2010-02-25

    When using pressure-type plethysmography to test lung function of rodents, calculation of lung volume is always based on Boyle's law. The precondition of Boyle's law is that perfect air is static. However, air in the chamber is flowing continuously when a rodent breathes inside the chamber. Therefore, Boyle's law, a principle of air statics, may not be appropriate for measuring pressure changes of flowing air. In this study, we deduced equations for pressure changes inside pressure-type plethysmograph and then designed three experiments to testify the theoretic deduction. The results of theoretic deduction indicated that increased pressure was generated from two sources: one was based on Boyle's law, and the other was based on the law of conservation of momentum. In the first experiment, after injecting 0.1 mL, 0.2 mL, 0.4 mL of air into the plethysmograph, the pressure inside the chamber increased sharply to a peak value, then promptly decreased to horizontal pressure. Peak values were significantly higher than the horizontal values (P<0.001). This observation revealed that flowing air made an extra effect on air pressure in the plethysmograph. In the second experiment, the same volume of air was injected into the plethysmograph at different frequencies (0, 0.5, 1, 2, 3 Hz) and pressure changes inside were measured. The results showed that, with increasing frequencies, the pressure changes in the chamber became significantly higher (P<0.001). In the third experiment, small animal ventilator and pipette were used to make two types of airflow with different functions of time. The pressure changes produced by the ventilator were significantly greater than those produced by the pipette (P<0.001). Based on the data obtained, we draw the conclusion that, the flow of air plays a role in pressure changes inside the plethysmograph, and the faster the airflow is, the higher the pressure changes reach. Furthermore, the type of airflow also influences the pressure changes.

  12. DYNAMICAL VERSUS STELLAR MASSES IN COMPACT EARLY-TYPE GALAXIES: FURTHER EVIDENCE FOR SYSTEMATIC VARIATION IN THE STELLAR INITIAL MASS FUNCTION

    SciTech Connect

    Conroy, Charlie; Dutton, Aaron A.; Graves, Genevieve J.; Mendel, J. Trevor; Van Dokkum, Pieter G.

    2013-10-20

    Several independent lines of evidence suggest that the stellar initial mass function (IMF) in early-type galaxies becomes increasingly 'bottom-heavy' with increasing galaxy mass and/or velocity dispersion, σ. Here we consider evidence for IMF variation in a sample of relatively compact early-type galaxies drawn from the Sloan Digital Sky Survey. These galaxies are of sufficiently high stellar density that a dark halo likely makes a minor contribution to the total dynamical mass, M {sub dyn}, within one effective radius. We fit our detailed stellar population synthesis models to the stacked absorption line spectra of these galaxies in bins of σ and find evidence from IMF-sensitive spectral features for a bottom-heavy IMF at high σ. We also apply simple 'mass-follows-light' dynamical models to the same data and find that M {sub dyn} is significantly higher than what would be expected if these galaxies were stellar dominated and had a universal Milky Way IMF. Adopting M {sub dyn} ≈ M {sub *} therefore implies that the IMF is 'heavier' at high σ. Most importantly, the quantitative amount of inferred IMF variation is very similar between the two techniques, agreeing to within ∼< 0.1 dex in mass. The agreement between two independent techniques, when applied to the same data, provides compelling evidence for systematic variation in the IMF as a function of early-type galaxy velocity dispersion. Any alternative explanations must reproduce both the results from dynamical and stellar population-based techniques.

  13. Associations between size-fractionated particulate air pollution and blood pressure in a panel of type II diabetes mellitus patients.

    PubMed

    Zhao, Ang; Chen, Renjie; Wang, Cuicui; Zhao, Zhuohui; Yang, Changyuan; Lu, Jianxiong; Chen, Xuan; Kan, Haidong

    2015-07-01

    Little is known regarding how the size distribution of particulate matter (PM) air pollution influences its effect on blood pressure (BP), especially among patients with diabetes. The objective of this study was to explore the short-term associations between size-fractionated PM and BP among diabetes patients. We scheduled 6 repeated BP examinations every 2 weeks from 13 April 2013 to 30 June 2013 in a panel of 35 type 2 diabetes mellitus patients recruited from an urban community in Shanghai, China. We measured real-time PM concentrations in the size range of 0.25 to 10 μm. We used linear mixed-effect models to examine the short-term association of size-fractionated PM and BP after controlling for individual characteristics, mean temperature, relative humidity, day of the week, years with diabetes and use of antihypertensive medication. The association with systolic BP and pulse pressure strengthened with decreasing diameter. The size fractions with the strongest associations were 0.25 to 0.40 μm for number concentrations and ≤ 2.5 μm for mass concentrations. Furthermore, these effects occurred immediately even after 0-2h and lasted for up to 48 h following exposure. An interquartile range increase in 24-h average number concentrations of PM0.25-0.40 was associated with increases of 3.61 mmHg in systolic BP and 2.96 mmHg in pulse pressure. Females, patients younger than 65 years of age and patients without antihypertensive treatment were more susceptible to these effects. Our results revealed important size and temporal patterns of PM in elevating BP among diabetes patients in China.

  14. AN INVENTORY OF THE STELLAR INITIAL MASS FUNCTION IN EARLY-TYPE GALAXIES

    SciTech Connect

    Tortora, C.; Romanowsky, A. J.; Napolitano, N. R.

    2013-03-01

    Given a flurry of recent claims for systematic variations in the stellar initial mass function (IMF), we carry out the first inventory of the observational evidence using different approaches. This includes literature results, as well as our own new findings from combined stellar population synthesis (SPS) and Jeans dynamical analyses of data on {approx}4500 early-type galaxies (ETGs) from the SPIDER project. We focus on the mass-to-light ratio mismatch relative to the Milky Way IMF, {delta}{sub IMF}, correlated against the central stellar velocity dispersion, {sigma}{sub *}. We find a strong correlation between {delta}{sub IMF} and {sigma}{sub *}, for a wide set of dark matter (DM) model profiles. These results are robust if a uniform halo response to baryons is adopted across the sample. The overall normalization of {delta}{sub IMF} and the detailed DM profile are less certain, but the data are consistent with standard cold DM halos and a central DM fraction that is roughly constant with {sigma}{sub *}. For a variety of related studies in the literature, using SPS, dynamics, and gravitational lensing, similar results are found. Studies based solely on spectroscopic line diagnostics agree on a Salpeter-like IMF at high {sigma}{sub *} but differ at low {sigma}{sub *}. Overall, we find that multiple independent lines of evidence appear to be converging on a systematic variation in the IMF, such that high-{sigma}{sub *} ETGs have an excess of low-mass stars relative to spirals and low-{sigma}{sub *} ETGs. Robust verification of super-Salpeter IMFs in the highest-{sigma}{sub *} galaxies will require additional scrutiny of scatter and systematic uncertainties. The implications for the distribution of DM are still inconclusive.

  15. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J.; Healy, R.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; Ehn, M.; Mikkilä, J.; Kulmala, M.; O'Dowd, C. D.

    2010-09-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June, 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the N. E. Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water soluble organic carbon, which, in turn, was dominated by methanesulphonic acid (MSA). Sulphate concentrations were

  16. False sugar sequence ions in electrospray tandem mass spectrometry of underivatized sialyl-Lewis-type oligosaccharides

    NASA Astrophysics Data System (ADS)

    Ernst, Beat; Müller, Dieter R.; Richter, Wilhelm J.

    1997-01-01

    Formation of "false" sugar sequence ions from branched tetrasaccharides of the sialyl-Lewis-type by migration of fucose towards sialic acid residues is shown to occur in [M + H]+ and [M + NH4]+ ions produced by electrospray ionization and subjected to low energy collision induced dissociation (CID). For the verification of their composition and sequence, such irregular ions were produced in the orifice region of the ion source, mass selected in Q1, and subjected to a second CID step in Q2 of a triple quadrupole analyser. When produced and analysed in the same "double CID" fashion, the branched B3 ions still containing all four sugar subunits show such migration to only a minor extent. The analysis of Bn fragment ions with high numbers for n may thus have advantages over the analysis of M-like species

  17. Membrane-type resonator as an effective miniaturized tuned vibration mass damper

    NASA Astrophysics Data System (ADS)

    Sun, Liang; Au-Yeung, Ka Yan; Yang, Min; Tang, Suet To; Yang, Zhiyu; Sheng, Ping

    2016-08-01

    Damping of low frequency vibration by lightweight and compact devices has been a serious challenge in various areas of engineering science. Here we report the experimental realization of a type of miniature low frequency vibration dampers based on decorated membrane resonators. At frequency around 150 Hz, two dampers, each with outer dimensions of 28 mm in diameter and 5 mm in height, and a total mass of 1.78 g which is less than 0.6% of the host structure (a nearly free-standing aluminum beam), can reduce its vibrational amplitude by a factor of 1400, or limit its maximum resonance quality factor to 18. Furthermore, the conceptual design of the dampers lays the foundation and demonstrates the potential of further miniaturization of low frequency dampers.

  18. A progenitor binary and an ejected mass donor remnant of faint type Ia supernovae

    NASA Astrophysics Data System (ADS)

    Geier, S.; Marsh, T. R.; Wang, B.; Dunlap, B.; Barlow, B. N.; Schaffenroth, V.; Chen, X.; Irrgang, A.; Maxted, P. F. L.; Ziegerer, E.; Kupfer, T.; Miszalski, B.; Heber, U.; Han, Z.; Shporer, A.; Telting, J. H.; Gänsicke, B. T.; Østensen, R. H.; O'Toole, S. J.; Napiwotzki, R.

    2013-06-01

    Type Ia supernovae (SN Ia) are the most important standard candles for measuring the expansion history of the universe. The thermonuclear explosion of a white dwarf can explain their observed properties, but neither the progenitor systems nor any stellar remnants have been conclusively identified. Underluminous SN Ia have been proposed to originate from a so-called double-detonation of a white dwarf. After a critical amount of helium is deposited on the surface through accretion from a close companion, the helium is ignited causing a detonation wave that triggers the explosion of the white dwarf itself. We have discovered both shallow transits and eclipses in the tight binary system CD-30°11223 composed of a carbon/oxygen white dwarf and a hot helium star, allowing us to determine its component masses and fundamental parameters. In the future the system will transfer mass from the helium star to the white dwarf. Modelling this process we find that the detonation in the accreted helium layer is sufficiently strong to trigger the explosion of the core. The helium star will then be ejected at such high velocity that it will escape the Galaxy. The predicted properties of this remnant are an excellent match to the so-called hypervelocity star US 708, a hot, helium-rich star moving at more than 750 km s-1, sufficient for it to leave the Galaxy. The identification of both progenitor and remnant provides a consistent picture of the formation and evolution of underluminous SNIa.

  19. The Deflagration Stage of Chandrasekhar Mass Models for Type Ia Supernovae. I. Early Evolution

    NASA Astrophysics Data System (ADS)

    Malone, C. M.; Nonaka, A.; Woosley, S. E.; Almgren, A. S.; Bell, J. B.; Dong, S.; Zingale, M.

    2014-02-01

    We present high-resolution, full-star simulations of the post-ignition phase of Type Ia supernovae using the compressible hydrodynamics code Castro. Initial conditions, including the turbulent velocity field and ignition site, are imported directly from a simulation of the last few hours of presupernova convection using a low Mach number code, Maestro. Adaptive mesh refinement allows the initial burning front to be modeled with an effective resolution of 36,8643 zones (136 m zone-1). The initial rise and expansion of the deflagration front are tracked until burning reaches the star's edge and the role of the background turbulence on the flame is investigated. The effect of artificially moving the ignition location closer to the star's center is explored. The degree to which turbulence affects the burning front decreases with increasing ignition radius since the buoyancy force is stronger at larger radii. Even central ignition—in the presence of a background convective flow field—is rapidly carried off-center as the flame is carried by the flow field. We compare our results to analytic models for burning thermals, and find that they reproduce the general trends of the bubble's size and mass, but underpredict the amount of buoyant acceleration due to simplifying assumptions of the bubble's properties. Overall, we find that the amount of mass that burns prior to flame break out is small, consistent with a "gravitationally confined detonation" occurring at a later epoch, but additional burning will occur following breakout that may modify this conclusion.

  20. Correlation between y-type ions observed in ion trap and triple quadrupole mass spectrometers.

    PubMed

    Sherwood, Carly A; Eastham, Ashley; Lee, Lik Wee; Risler, Jenni; Vitek, Olga; Martin, Daniel B

    2009-09-01

    Multiple reaction monitoring mass spectrometry (MRM-MS) is a technique for high-sensitivity targeted analysis. In proteomics, MRM-MS can be used to monitor and quantify a peptide based on the production of expected fragment peaks from the selected peptide precursor ion. The choice of which fragment ions to monitor in order to achieve maximum sensitivity in MRM-MS can potentially be guided by existing MS/MS spectra. However, because the majority of discovery experiments are performed on ion trap platforms, there is concern in the field regarding the generalizability of these spectra to MRM-MS on a triple quadrupole instrument. In light of this concern, many operators perform an optimization step to determine the most intense fragments for a target peptide on a triple quadrupole mass spectrometer. We have addressed this issue by targeting, on a triple quadrupole, the top six y-ion peaks from ion trap-derived consensus library spectra for 258 doubly charged peptides from three different sample sets and quantifying the observed elution curves. This analysis revealed a strong correlation between the y-ion peak rank order and relative intensity across platforms. This suggests that y-type ions obtained from ion trap-based library spectra are well-suited for generating MRM-MS assays for triple quadrupoles and that optimization is not required for each target peptide.

  1. Correlation between y-Type Ions Observed in Ion Trap and Triple Quadrupole Mass Spectrometers

    PubMed Central

    Sherwood, Carly A.; Eastham, Ashley; Lee, Lik Wee; Risler, Jenni; Vitek, Olga; Martin, Daniel B.

    2009-01-01

    Multiple reaction monitoring mass spectrometry (MRM-MS) is a technique for high-sensitivity targeted analysis. In proteomics, MRM-MS can be used to monitor and quantify a peptide based on the production of expected fragment peaks from the selected peptide precursor ion. The choice of which fragment ions to monitor in order to achieve maximum sensitivity in MRM-MS can potentially be guided by existing MS/MS spectra. However, because the majority of discovery experiments are performed on ion trap platforms, there is concern in the field regarding the generalizability of these spectra to MRM-MS on a triple quadrupole instrument. In light of this concern, many operators perform an optimization step to determine the most intense fragments for a target peptide on a triple quadrupole mass spectrometer. We have addressed this issue by targeting, on a triple quadrupole, the top six y-ion peaks from ion trap-derived consensus library spectra for 258 doubly charged peptides from three different sample sets and quantifying the observed elution curves. This analysis revealed a strong correlation between the y-ion peak rank order and relative intensity across platforms. This suggests that y-type ions obtained from ion trap-based library spectra are well-suited for generating MRM-MS assays for triple quadrupoles and that optimization is not required for each target peptide. PMID:19603825

  2. Binary Stars with Components of Solar Type: 25 Orbits and System Masses

    NASA Astrophysics Data System (ADS)

    Docobo, J. A.; Ling, J. F.

    2009-10-01

    Revised orbits and system masses are presented for the following 25 visual double stars: WDS 00593-0040 (A 1902), WDS 00596-0111 (A 1903 AB), WDS 01023+0552 (A 2003), WDS 01049+3649 (A 1515), WDS 01234+5809 (STF 115 AB), WDS 02399+0009 (A 1928), WDS 03310+2937 (A 983), WDS 06573-3530 (I 65), WDS 07043-0303 (A 519), WDS 08267+2432 (A 1746 BC), WDS 10585+1711 (A 2375), WDS 11308+4117 (STT 234), WDS 15370+6426 (HU 1168), WDS 16044-1122 (STF 1998 AB), WDS 16283-1613 (RST 3950), WDS 17324+2848 (A 352), WDS 18466+3821 (HU 1191), WDS 19039+2642 (A 2992), WDS 19055+3352(HU 940), WDS 19282-1209 (SCJ 22), WDS 19487+1504 (A 1658), WDS 22400+0113 (A 2099), WDS 23506-5142 (SLR 14), WDS 23518-0637 (A 2700), and WDS 23529-0309 (FIN 359). In all of these systems, at least one component is of solar type. Total system masses were calculated in each case from the orbital period and semiaxis major together with the Hipparcos parallax, except in the cases for which there are no Hipparcos data or when these values are not precise. Other orbital and physical properties of these stars are also discussed. This paper is the second of three collating the revised double star orbits we have calculated in the past 15 yr.

  3. Distinct synoptic patterns and air masses responsible for long-range desert dust transport and sea spray in Palermo, Italy

    NASA Astrophysics Data System (ADS)

    Dimitriou, K.; Paschalidou, A. K.; Kassomenos, P. A.

    2016-09-01

    Undoubtedly, anthropogenic emissions carry a large share of the risk posed on public health by particles exposure in urban areas. However, natural emissions, in the form of desert dust and sea spray, are well known to contribute significantly to the PM load recorded in many Mediterranean environments, posing an extra risk burden on public health. In the present paper, we examine the synoptic climatology in a background station in Palermo, Italy, through K-means clustering of the mean sea-level pressure (MSLP) maps, in an attempt to associate distinct synoptic patterns with increased PM10 levels. Four-day backward trajectory analysis is then applied, in order to study the origins and pathways of air masses susceptible of PM10 episodes. It is concluded that a number of atmospheric patterns result in several kind of flows, namely south, west, and slow-moving/stagnant flows, associated with long-range dust transport and sea spray.

  4. Seasonal variability of tritium and ion concentrations in rain at Kumamoto, Japan and back-trajectory analysis of air mass

    SciTech Connect

    Momoshima, N.; Sugihara, S.; Toyoshima, T.; Nagao, Y.; Takahashi, M.; Nakamura, Y.

    2008-07-15

    Tritium and major ion concentrations in rain were analyzed in Kumamoto (Japan)) between 2001 and 2006 to examine present tritium concentration and seasonal variation. The average tritium concentration was 0.36 {+-} 0.19 Bq/L (n=104) and higher tritium concentrations were observed in spring than the other seasons. Among the ions, non-sea-salt (nss) SO{sub 4}{sup 2}'- showed higher concentration in winter while other ions did not show marked increase in winter. Based on the back-trajectory analyses of air masses, the increase in tritium concentrations in spring arises from downward movement of naturally produced tritium from stratosphere to troposphere, while the increase of the nss-SO{sub 4}{sup 2-} concentrations in winter is due to long range transport of pollutants from China to Japan. (authors)

  5. Characterisation of a smartphone image sensor response to direct solar 305nm irradiation at high air masses.

    PubMed

    Igoe, D P; Amar, A; Parisi, A V; Turner, J

    2017-06-01

    This research reports the first time the sensitivity, properties and response of a smartphone image sensor that has been used to characterise the photobiologically important direct UVB solar irradiances at 305nm in clear sky conditions at high air masses. Solar images taken from Autumn to Spring were analysed using a custom Python script, written to develop and apply an adaptive threshold to mitigate the effects of both noise and hot-pixel aberrations in the images. The images were taken in an unobstructed area, observing from a solar zenith angle as high as 84° (air mass=9.6) to local solar maximum (up to a solar zenith angle of 23°) to fully develop the calibration model in temperatures that varied from 2°C to 24°C. The mean ozone thickness throughout all observations was 281±18 DU (to 2 standard deviations). A Langley Plot was used to confirm that there were constant atmospheric conditions throughout the observations. The quadratic calibration model developed has a strong correlation between the red colour channel from the smartphone with the Microtops measurements of the direct sun 305nm UV, with a coefficient of determination of 0.998 and very low standard errors. Validation of the model verified the robustness of the method and the model, with an average discrepancy of only 5% between smartphone derived and Microtops observed direct solar irradiances at 305nm. The results demonstrate the effectiveness of using the smartphone image sensor as a means to measure photobiologically important solar UVB radiation. The use of ubiquitous portable technologies, such as smartphones and laptop computers to perform data collection and analysis of solar UVB observations is an example of how scientific investigations can be performed by citizen science based individuals and groups, communities and schools.

  6. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean

    USGS Publications Warehouse

    Garrison, Virginia H.; Majewski, Michael S.; Foreman, William T.; Genualdi, Susan A.; Mohammed, Azad; Massey Simonich, Stacy L.

    2014-01-01

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9–126 ng/m3 (mean = 25 ± 34) at source and 0.05–0.71 ng/m3 (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1–3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  7. The collision cross sections of iodide salt cluster ions in air via differential mobility analysis-mass spectrometry.

    PubMed

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R; Hogan, Christopher J

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M(+)]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5%) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  8. The Collision Cross Sections of Iodide Salt Cluster Ions in Air via Differential Mobility Analysis-Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Ouyang, Hui; Larriba-Andaluz, Carlos; Oberreit, Derek R.; Hogan, Christopher J.

    2013-12-01

    To date, most collision cross section (CCS) predictions have invoked gas molecule impingement-reemission rules in which specular and elastic scattering of spherical gas molecules from rigid polyatomic surfaces are assumed. Although such predictions have been shown to agree well with CCSs measured in helium bath gas, a number of studies reveal that these predictions do not agree with CCSs for ions in diatomic gases, namely, air and molecular nitrogen. To further examine the validity of specular-elastic versus diffuse-inelastic scattering models, we measured the CCSs of positively charged metal iodide cluster ions of the form [MI]n[M+]z, where M = Na, K, Rb, or Cs, n = 1 - 25, and z = 1 - 2. Measurements were made in air via differential mobility analysis mass spectrometry (DMA-MS). The CCSs measured are compared with specular-elastic as well as diffuse-inelastic scattering model predictions with candidate ion structures determined from density functional theory. It is found that predictions from diffuse-inelastic collision models agree well (within 5 %) with measurements from sodium iodide cluster ions, while specular-elastic collision model predictions are in better agreement with cesium iodide cluster ion measurements. The agreement with diffuse-inelastic and specular-elastic predictions decreases and increases, respectively, with increasing cation mass. However, even when diffuse-inelastic cluster ion predictions disagree with measurements, the disagreement is of a near-constant factor for all ions, indicating that a simple linear rescaling collapses predictions to measurements. Conversely, rescaling cannot be used to collapse specular-elastic predictions to measurements; hence, although the precise impingement reemission rules remain ambiguous, they are not specular-elastic.

  9. Identification of water-soluble polar organics in air and vehicular emitted particulate matter using ultrahigh resolution mass spectrometry and Capillary electrophoresis - mass spectrometry.

    NASA Astrophysics Data System (ADS)

    Schmitt-Kopplin, P.; Yassine, M.; Gebefugi, I.; Hertkorn, N.; Dabek-Zlotorzynska, E.

    2009-04-01

    The effects of aerosols on human health, atmospheric chemistry, and climate are among the central topics in current environmental health research. Detailed and accurate measurements of the chemical composition of air particulate matter (PM) represent a challenging analytical task. Minute sample amounts are usually composed of several main constituents and hundreds of minor and trace constituents. Moreover, the composition of individual particles can be fairly uniform or very different (internally or externally mixed aerosols), depending on their origin and atmospheric aging processes (coagulation, condensation / evaporation, chemical reaction). The aim of the presentation was the characterization of the organic matter (OM) fraction of environmental aerosols which is not accessible by GC-methods, either because of their high molecular weight, their polarity or due to thermal instability. We also describe the main chemical characteristics of complexe oligomeric organic fraction extracted from different aerosols collected in urban and rural area in Germany and Canada. Mass spectrometry (MS) became an essential tool used by many prominent leaders of the biological research community and the importance of MS to the future of biological research is now clearly evident as in the fields of Proteomics and Metabolomics. Especially Fourier Transform Ion Cyclotron Mass Spectrometry (ICR-FT/MS) is an ultrahigh resolution MS that allows new approach in the analysis of complex mixtures. The mass resolution (< 200 ppb) allowed assigning the elemental composition (C, H, O, N, S…) to each of the obtained mass peaks and thus already a description of the mixture in terms of molecular composition. This possibility is used by the authors together with a high resolution separation method of charged compounds: capillary electrophoresis. A CE-ESI-MS method using an ammonium acetate based background electrolyte (pH 4.7) was developed for the determination of isomeric benzoic acids in

  10. Development of a thermal desorption-gas chromatography-mass spectrometry method for determining personal care products in air.

    PubMed

    Ramírez, Noelia; Marcé, Rosa Maria; Borrull, Francesc

    2010-06-25

    This study describes the development of a new analytical method for determining 14 personal care products (PCPs) - nine synthetic musks, four parabens and one insect repellent - in air samples. The method is based on active sampling on sorbent tubes and thermal desorption-gas chromatography-mass spectrometry analysis, and is rapid, sensitive and drastically reduces the risk of sample contamination. Three kinds of tubes and traps were tested, those filled with Tenax TA being the most suitable for this study. Method validation showed good repeatability and reproducibility, low detection limits (between 0.03 ng m(-3) for DPMI and 12.5 ng m(-3) for propyl paraben) and good linearity for all compounds. Stability during storage indicated that samples must be kept refrigerated at 4 degrees C and analysed within 1 week of collection. The applicability of the technique to real samples was tested in different indoor and outdoor atmospheres. The total PCP values for indoor air ranged from 135 ng m(-3) in a pharmacy to 2838 ng m(-3) in a hairdresser's, whereas the values for outdoor air ranged from 14 ng m(-3) for a suburban environment to 26 ng m(-3) for an urban environment. In general, the most abundant synthetic musks were galaxolide (5.9-1256 ng m(-3)), musk xylene (1.6-766 ng m(-3)) and tonalide (1.1-138 ng m(-3)). Methyl and ethyl paraben (2.4-313 ng m(-3) and 1.8-117 ng m(-3), respectively) were the most abundant parabens. Although thermal desorption methods have been widely used for determining volatile organic compounds, they are rarely used with semi-volatile compounds. This study thus demonstrates that the thermal desorption method performs well with semi-volatile compounds and, for the first time, that it can be used for determining PCPs.

  11. Association between indoor air pollutant exposure and blood pressure and heart rate in subjects according to body mass index.

    PubMed

    Jung, Chien-Cheng; Su, Huey-Jen; Liang, Hsiu-Hao

    2016-01-01

    This study investigates the effects of high body mass index (BMI) of subjects on individual who exhibited high cardiovascular disease indexes with blood pressure (BP) and heart rate (HR) when exposed to high levels of indoor air pollutants. We collected 115 office workers, and measured their systolic blood pressure (SBP), diastolic blood pressure (DBP) and HR at the end of the workday. The subjects were divided into three groups according to BMI: 18-24 (normal weight), 24-27 (overweight) and >27 (obese). This study also measured the levels of carbon dioxide (CO2), total volatile organic compounds (TVOC), particulate matter with an aerodynamic diameter less than 2.5μm (PM2.5), as well as the bacteria and fungi in the subjects' work-places. The pollutant effects were divided by median. Two-way analysis of variance (ANOVA) was used to analyze the health effects of indoor air pollution exposure according to BMI. Our study showed that higher levels of SBP, DBP and HR occurred in subjects who were overweight or obese as compared to those with normal weight. Moreover, there was higher level of SBP in subjects who were overweight or obese when they were exposed to higher levels of TVOC and fungi (p<0.05). We also found higher value for DBP and HR with increasing BMI to be associated with exposure to higher TVOC levels. This study suggests that individuals with higher BMI have higher cardiovascular disease risk when they are exposed to poor indoor air quality (IAQ), and specifically in terms of TVOC.

  12. Air flow-assisted ionization imaging mass spectrometry method for easy whole-body molecular imaging under ambient conditions.

    PubMed

    Luo, Zhigang; He, Jiuming; Chen, Yi; He, Jingjing; Gong, Tao; Tang, Fei; Wang, Xiaohao; Zhang, Ruiping; Huang, Lan; Zhang, Lianfeng; Lv, Haining; Ma, Shuanggang; Fu, Zhaodi; Chen, Xiaoguang; Yu, Shishan; Abliz, Zeper

    2013-03-05

    Whole-body molecular imaging is able to directly map spatial distribution of molecules and monitor its biotransformation in intact biological tissue sections. Imaging mass spectrometry (IMS), a label-free molecular imaging method, can be used to image multiple molecules in a single measurement with high specificity. Herein, a novel easy-to-implement, whole-body IMS method was developed with air flow-assisted ionization in a desorption electrospray ionization mode. The developed IMS method can effectively image molecules in a large whole-body section in open air without sample pretreatment, such as chemical labeling, section division, or matrix deposition. Moreover, the signal levels were improved, and the spatial assignment errors were eliminated; thus, high-quality whole-body images were obtained. With this novel IMS method, in situ mapping analysis of molecules was performed in adult rat sections with picomolar sensitivity under ambient conditions, and the dynamic information of molecule distribution and its biotransformation was provided to uncover molecular events at the whole-animal level. A global view of the differential distribution of an anticancer agent and its metabolites was simultaneously acquired in whole-body rat and model mouse bearing neuroglioma along the administration time. The obtained drug distribution provided rich information for identifying the targeted organs and predicting possible tumor spectrum, pharmacological activity, and potential toxicity of drug candidates.

  13. Simulation of solid oxide iron-air battery: Effects of heat and mass transfer on charge/discharge characteristics

    NASA Astrophysics Data System (ADS)

    Ohmori, Hiroko; Iwai, Hiroshi

    2015-07-01

    A time-dependent 2-D numerical simulation was performed on a solid oxide iron-air battery (SOIAB) to reveal the fundamental characteristics of this new system. The SOIAB is a rechargeable battery consisting of a solid oxide electrochemical cell (SOEC) and iron as a redox metal. A simple battery configuration was employed assuming a system with a small capacity. A simulation model for a unit element was developed considering heat and mass transfer in the system, taking both electrochemical and redox reactions into account. The numerical results showed the spatial and temporal changes in the temperature field in the charge and discharge operations, which were due to the combined effects of heat generation/absorption by the electrochemical and redox reactions and heat exchange with the air supplied through convective heat transfer. As the reaction rates are functions of the local temperature, the predicted results show the importance of considering the heat transfer phenomena in this system. It was also found that the active reaction region in the redox metal evolves with time. The nonuniform distribution of iron utilization is affected by the effective gas diffusion coefficients in the porous redox metal, and consequently the change in the current density distribution in the SOEC.

  14. Comparative Evaluation of Dimensional Accuracy and Tensile Strength of a Type IV Gypsum Using Microwave and Air Drying Methods.

    PubMed

    Sharma, Anuraag; Shetty, Manoj; Hegde, Chethan; Shetty, N Sridhar; Prasad, D Krishna

    2013-12-01

    To evaluate dimensional accuracy and tensile strength of a type IV gypsum product, at different time intervals, dried in air or a microwave oven. Eighty specimens prepared from a cylindrical mould were used for measuring tensile strength (group A). Twenty specimens from a master die mould were used for determining dimensional accuracy (group B). In group A, 40 specimens were dried in open air at room temperature (A1). The other 40 were removed after 30 min and air dried for 20 min. These were subjected to microwave oven drying for 5 min (A2). Ten specimens each were tested under diametral compression at each of the following time periods: 1, 2, 4 and 24 h after drying. In group B, ten specimens were dried in open air at room temperature (B1). Ten specimens were removed from the mould after 30 min and air dried for 20 min. These were then dried in a microwave oven for 5 min (B2). The data was statistically analyzed using students unpaired "t" test. At all time intervals, diametral tensile strength (DTS) values for specimens dried in microwave oven were significantly higher than for those dried in open air. There were no significant differences between the dimensional accuracy of the two groups. In this study, microwave oven drying had a positive effect on the DTS of a type IV gypsum and the microwave oven dried specimens were as accurate as the air dried specimens over the same time period.

  15. Comparison of sampling methods for radiocarbon dating of carbonyls in air samples via accelerator mass spectrometry

    NASA Astrophysics Data System (ADS)

    Schindler, Matthias; Kretschmer, Wolfgang; Scharf, Andreas; Tschekalinskij, Alexander

    2016-05-01

    Three new methods to sample and prepare various carbonyl compounds for radiocarbon measurements were developed and tested. Two of these procedures utilized the Strecker synthetic method to form amino acids from carbonyl compounds with either sodium cyanide or trimethylsilyl cyanide. The third procedure used semicarbazide to form crystalline carbazones with the carbonyl compounds. The resulting amino acids and semicarbazones were then separated and purified using thin layer chromatography. The separated compounds were then combusted to CO2 and reduced to graphite to determine 14C content by accelerator mass spectrometry (AMS). All of these methods were also compared with the standard carbonyl compound sampling method wherein a compound is derivatized with 2,4-dinitrophenylhydrazine and then separated by high-performance liquid chromatography (HPLC).

  16. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses.

  17. Measurement error models in chemical mass balance analysis of air quality data

    NASA Astrophysics Data System (ADS)

    Christensen, William F.; Gunst, Richard F.

    The chemical mass balance (CMB) equations have been used to apportion observed pollutant concentrations to their various pollution sources. Typical analyses incorporate estimated pollution source profiles, estimated source profile error variances, and error variances associated with the ambient measurement process. Often the CMB model is fit to the data using an iteratively re-weighted least-squares algorithm to obtain the effective variance solution. We consider the chemical mass balance model within the framework of the statistical measurement error model (e.g., Fuller, W.A., Measurement Error Models, Wiley, NewYork, 1987), and we illustrate that the models assumed by each of the approaches to the CMB equations are in fact special cases of a general measurement error model. We compare alternative source contribution estimators with the commonly used effective variance estimator when standard assumptions are valid and when such assumptions are violated. Four approaches for source contribution estimation and inference are compared using computer simulation: weighted least squares (with standard errors adjusted for source profile error), the effective variance approach of Watson et al. (Atmos, Environ., 18, 1984, 1347), the Britt and Luecke (Technometrics, 15, 1973, 233) approach, and a method of moments approach given in Fuller (1987, p. 193). For the scenarios we consider, the simplistic weighted least-squares approach performs as well as the more widely used effective variance solution in most cases, and is slightly superior to the effective variance solution when source profile variability is large. The four estimation approaches are illustrated using real PM 2.5 data from Fresno and the conclusions drawn from the computer simulation are validated.

  18. Chemical composition of air masses transported from Asia to the U.S. West Coast during ITCT 2K2: Fossil fuel combustion versus biomass-burning signatures

    NASA Astrophysics Data System (ADS)

    de Gouw, J. A.; Cooper, O. R.; Warneke, C.; Hudson, P. K.; Fehsenfeld, F. C.; Holloway, J. S.; Hübler, G.; Nicks, D. K., Jr.; Nowak, J. B.; Parrish, D. D.; Ryerson, T. B.; Atlas, E. L.; Donnelly, S. G.; Schauffler, S. M.; Stroud, V.; Johnson, K.; Carmichael, G. R.; Streets, D. G.

    2004-12-01

    As part of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT 2K2), a National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft was used to study the long-range transport of Asian air masses toward the west coast of North America. During research flights on 5 and 17 May, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on 5 and 17 May and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) to propane (C3H8), and, on May 5, the percentage of particles measured by the particle analysis by laser mass spectrometry (PALMS) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast over a range of latitudes and altitudes for the entire ITCT 2K2 period, showed that air masses from Southeast Asia and China were generally observed at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for Southeast Asia. Combined with the origin of the air masses versus altitude, this qualitatively explains the increase with altitude, averaged over the whole ITCT 2K2 period, of the different biomass-burning indicators.

  19. Determination of solanidine- and tomatidine-type glycoalkaloid aglycons by gas Chromatography/Mass spectrometry.

    PubMed

    Laurila, J; Laakso, I; Väänänen, T; Kuronen, P; Huopalahti, R; Pehu, E

    1999-07-01

    A combined derivatization method for gas chromatographic/mass spectrometric (GC/MS) analysis of steroidal glycoalkaloid (SGA) aglycons was developed using both trimethylsilylation and pentafluoropropionylation. In comparison with underivatized or only silylated aglycons, the new technique produces more specific and abundant fragmentation for compounds with a tomatidine-type structure. For example, the difference between solasodine and tomatidine, the former containing a double bond at position 5,6 in the steroidal skeleton, can be observed by their base peak fragments at m/z 417 (C(24)H(41)O(2)Si(2)) and m/z 419 (C(24)H(43)O(2)Si(2)). The method is well suited for the simultaneous determination of both solanidane- and spirosolane-type SGA aglycons from Solanum species and hybrids. The reproducibility of the method, including SGA extraction, hydrolysis, derivatization, and quantitative GC/MS analysis, was <6% (CV) for the principal aglycons determined from a hybrid between a wild potato species, Solanum brevidens Phil., and a cultivated potato, S. tuberosum L. A single ion monitoring technique using specific fragments m/z 419 and 417 could be applied for the determination of minor stereoisomers, which are often overlapped by large amounts of tomatidine.

  20. Characteristics of coronal mass ejection associated with DH type II radio bursts (All and Limb events)

    NASA Astrophysics Data System (ADS)

    Pappa Kalaivani, P.; Umapathy, S.; Shanmugaraju, A.; Prakash, O.

    2010-12-01

    We have studied the characteristics of coronal mass ejections (CMEs) associated with Deca-Hectometric (DH) type II radio bursts (1-14 MHz) in the interplanetary medium during the year 1997-2005. The DH CMEs are divided into two parts: (i) DH CMEs (All) and (ii) DH CMEs (Limb). We found that 65% (177/273) of all events have the speed >900 km s-1 and the remaining 35% (96/273) events have the speed below 900 km s-1. The average speed of all and limb DH CMEs are 1230 and 1288 km s-1, respectively, which is nearly three times the average speed of general population of CMEs (473 km s-1). The average widths of all and limb DH CMEs are 105° and 106°, respectively, which is twice the average width (52°) of the general population of CMEs. We found a better correlation between the speed and width of limb DH CMEs ( R=-0.61) than all DH CMEs ( R=-0.53). Only 28% (177/637) of fast >900 km s-1 general population of CMEs are reported with DH type II bursts counterpart. The above results gives that the relation between the CME properties is better for limb events.

  1. Achilles tendon and plantar fascia in recently diagnosed type II diabetes: role of body mass index.

    PubMed

    Abate, Michele; Schiavone, Cosima; Di Carlo, Luigi; Salini, Vincenzo

    2012-07-01

    Previous research has shown that plantar fascia and Achilles tendon thickness is increased in diabetes. The aims of present study were to assess whether tendon changes can occur in the early stages of the disease and to evaluate the extent of the influence of body mass index (BMI). The study population included 51 recent-onset type II diabetic subjects, who were free from diabetic complications, divided according to BMI into three groups (normal weight, overweight, and obese). Eighteen non-diabetic, normal-weight subjects served as controls. Plantar fascia and Achilles tendon thickness was measured by means of sonography. The groups were well balanced for age and sex. In all the diabetic subjects, plantar fascia and Achilles tendon thickness was increased compared to the controls (p < 0.001, p = 0.01, p = 0.003, respectively). A significant relationship was found between plantar fascia thickness and BMI values (r = 0.749, p < 0.0001), while the correlation between BMI and Achilles tendon was weaker (r = 0.399, p = 0.004). This study shows that plantar fascia and Achilles tendon thickness is increased in the early stages of type II diabetes and that BMI is related more to plantar fascia than Achilles tendon thickness. Further longitudinal studies are needed to evaluate whether these early changes can overload the metatarsal heads and increase the stress transmitted to plantar soft tissues, thus representing an additional risk factor for foot ulcer development.

  2. An Investigation of the Effects of Density, Size and Shape Upon the Air Classification of Municipal Type Solid Waste.

    DTIC Science & Technology

    1977-06-01

    municipal solid waste type materials into more than two fractions by passing the material through a vertical air classifier. This feasibility was demonstrated by suspending specimens of varying densities, sizes, and shapes in a vertical air classifier and noting the terminal velocities of the materials. Since most shredded solid waste approximates flat plates of varying sizes and shapes, flat plates of six different materials in aspect ratios (length over width) from one to four and in four different sizes from 0.0625 to 1.000 square inches (0.4032 to 6.4516

  3. Analysis of air-mass modification over Poland and Romania by means of multiwavelength lidars - a case study 19-21/07/2014

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Stachlewska, Iwona S.; Nicolae, Doina; Nemuc, Anca; Janicka, Lucja; Markowicz, Krzysztof M.; Belegante, Livio; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2015-04-01

    A case study of air-mass modification over Poland and Romania, assessing the role of the Carpathian Mountains, during 19-21/07/2014 is analyzed. The study is based mainly on measurements taken by two multiwavelength Raman lidars at two different sites: the Radiative Transfer Laboratory (RT-Lab) at the Faculty of Physics of the University of Warsaw in Warsaw (Poland) and at the RADO site of the National Institute of R&D in Optoelectronics in Magurele (Romania). These data were complemented with meteorological data collected at two other sites: SolarAOT in Strzyżów (Poland) - equipped also with AERONET photometer and CHM15k ceilometer, and in Cluj (Romania). The RADO site, with its 7-wavelength aerosol-Raman-depolarization lidar (RALi) is integrated into EARLINET network. The RT-Lab site, with its 8-wavelength aerosol-Raman-depolarization (PollyXT-type) lidar, started the procedure to join in EARLINET last year. Moreover, RT-Lab and SolarAOT sites are part of the Poland AOD network. The analysis is focused on evaluating both multi-wavelength lidar data sets in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations. Accordingly to GDAS Hysplit 4-days backward trajectory ending up in Magurele at 0.5, 1.5 and 3 km an air-mass from western Europe entered Poland from the north-west on 19/07/2014, descended on the following day over the Poland AOD station in Strzyżów, followed by Cluj and end up at Magurele on 21/07/2014. As the four stations are located along a north-west to south-east line the objective was to evaluate the aerosol properties of the air flow transported over Poland and further to Romania. At both sites, backscatter profiles at 355, 532 and 1064nm, extinction profiles at 355 and 532nm, and depolarization profiles at 532nm and 355nm, show distinctly layered structure in the atmosphere. Along with these we used data from stations in Strzyżów and Cluj as well as information

  4. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    SciTech Connect

    Mernild, Sebastian Haugard; Liston, Glen

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  5. Search and characterization of T-type planetary mass candidates in the σ Orionis cluster

    NASA Astrophysics Data System (ADS)

    Peña Ramírez, K.; Zapatero Osorio, M. R.; Béjar, V. J. S.; Rebolo, R.; Bihain, G.

    2011-08-01

    Context. The proper characterization of the least massive population of the young σ Orionis star cluster is required to understand the form of the cluster mass function and its impact on our comprehension of the substellar formation processes. S Ori 70 (T5.5 ± 1) and 73, two T-type cluster member candidates, are likely to have masses between 3 and 7 MJup if their age is 3 Myr. It awaits confirmation whether S Ori 73 has a methane atmosphere. Aims: We aim to: i) confirm the presence of methane absorption in S Ori 73 by performing methane imaging; ii) study S Ori 70 and 73 cluster membership via photometric colors and accurate proper motion analysis; and iii) perform a new search to identify additional T-type σ Orionis member candidates. Methods: We obtained HAWK-I (VLT) J, H, and CH4off photometry of an area of 119.15 arcmin2 in σ Orionis down to Jcomp = 21.7 and Hcomp = 21 mag. S Ori 70 and 73 are contained in the explored area. Near-infrared data were complemented with optical photometry using images acquired with OSIRIS (GTC) and VISTA as part of the VISTA Orion survey. Color-magnitude and color-color diagrams were constructed to characterize S Ori 70 and 73 photometrically, and to identify new objects with methane absorption and masses below 7 MJup. We derived proper motions by comparing of the new HAWK-I and VISTA images with published near-infrared data taken 3.4 - 7.9 yr ago. Results.S Ori 73 has a red H - CH4off color indicating methane absorption in the H-band and a spectral type of T4 ± 1. S Ori 70 displays a redder methane color than S Ori 73 in agreement with its latter spectral classification. Our proper motion measurements (μα cos δ = 26.7 ± 6.1, μδ = 21.3 ± 6.1 mas yr-1 for S Ori 70, and μα cos δ = 46.7 ± 4.9, μδ = -6.3 ± 4.7 mas yr-1 for S Ori 73) are larger than the motion of σ Orionis, rendering S Ori 70 and 73 cluster membership uncertain. From our survey, we identified one new photometric candidate with J = 21.69 ± 0.12 mag

  6. First day of an oil spill on the open sea: early mass transfers of hydrocarbons to air and water.

    PubMed

    Gros, Jonas; Nabi, Deedar; Würz, Birgit; Wick, Lukas Y; Brussaard, Corina P D; Huisman, Johannes; van der Meer, Jan R; Reddy, Christopher M; Arey, J Samuel

    2014-08-19

    During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m(3) oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km(2) area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models.

  7. Effect of gender, facial dimensions, body mass index and type of functional occlusion on bite force

    PubMed Central

    KOÇ, Duygu; DOĞAN, Arife; BEK, Bülent

    2011-01-01

    Objective Some factors such as gender, age, craniofacial morphology, body structure, occlusal contact patterns may affect the maximum bite force. Thus, the purposes of this study were to determine the mean maximum bite force in individuals with normal occlusion, and to examine the effect of gender, facial dimensions, body mass index (BMI), type of functional occlusion (canine guidance and group function occlusion) and balancing side interferences on it. Material and Methods Thirty-four individuals aged 19-20 years-old were selected for this study. Maximum bite force was measured with strain-gauge transducers at first molar region. Facial dimensions were defined by standardized frontal photographs as follows: anterior total facial height (ATFH), bizygomathic facial width (BFW) and intergonial width (IGW). BMI was calculated using the equation weight/height2. The type of functional occlusion and the balancing side interferences of the subjects were identified by clinical examination. Results Bite force was found to be significantly higher in men than women (p<0.05). While there was a negative correlation between the bite force and ATFH/BFW, ATFH/IGW ratios in men (p<0.05), women did not show any statistically significant correlation (p>0.05). BMI and bite force correlation was not statistically significant (p>0.05). The average bite force did not differ in subjects with canine guidance or group function occlusion and in the presence of balancing side interferences (p>0.05). Conclusions Data suggest that bite force is affected by gender. However, BMI, type of functional occlusion and the presence of balancing side interferences did not exert a meaningful influence on bite force. In addition, transverse facial dimensions showed correlation with bite force in only men. PMID:21625746

  8. Characterization of B- and C-type low molecular weight glutenin subunits by electrospray ionization mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry.

    PubMed

    Muccilli, Vera; Cunsolo, Vincenzo; Saletti, Rosaria; Foti, Salvatore; Masci, Stefania; Lafiandra, Domenico

    2005-02-01

    Low molecular weight glutenin subunits (LMW-GS) are typically subdivided into three groups, according to their molecular weights and isoelectric points, namely the B-, C-, and D groups. Enriched B- and C-type LMW-GS fractions extracted from the bread wheat cultivar Chinese Spring were characterized using high performance liquid chromatography (HPLC) directly interfaced with electrospray ionization mass spectrometry and HPLC coupled off-line with matrix-assisted laser desorption/ionization mass spectrometry, in order to ascertain the number and relative molecular masses of the components present in each fraction and determine the number of cysteine residues. About 70 components were detected in each of the fractions examined by the combined use of these two techniques, with 18 components common to both fractions. Analysis of the fractions after alkylation with 4-vinylpyridine allowed determination of the number of the cysteines present in about 40 subunits. The proteins detected were tentatively classified based on the relative molecular masses and number of cysteine residues. Cross-contamination was found in both B- and C- fractions, along with the presence of D-type LMW-GS. The two fractions also contained unexpected components, probably lipid transfer proteins and omega-gliadins. The presence of extensive microheterogeneity was suggested by the detection of several co-eluting proteins with minor differences in their molecular masses.

  9. Air-Pollution and Cardiometabolic Diseases (AIRCMD): a prospective study investigating the impact of air pollution exposure and propensity for type II diabetes.

    PubMed

    Sun, Zhichao; Mukherjee, Bhramar; Brook, Robert D; Gatts, Geoffrey A; Yang, Fumo; Sun, Qinghua; Brook, Jeffrey R; Fan, Zhongjie; Rajagopalan, Sanjay

    2013-03-15

    There is a paucity of prospective cohort studies investigating the impact of environmental factors on the development of cardiometabolic (CM) disorders like type II diabetes (T2DM). The objective of the Air-Pollution and Cardiometabolic Diseases (AIRCMD) study is to investigate the impact of personal level air pollution measures [personal black carbon (BC)/sulfate measures] and ambient fine particulate matter [(PM2.5)/NO2] levels on propensity to type II diabetes in Beijing, China. Subjects with metabolic syndrome will undergo four repeated study visits within each season over a one year period following an initial screening visit. At each study visit, subjects will be monitored for sub-acute exposure to personal and ambient measures of air-pollution exposure and will undergo a series of functional CM outcomes. The primary endpoints include independent associations between integrated 5-day mean exposure to PM2.5 and BC and homeostasis model assessment of insulin resistance (HOMA-IR) measures, 24-hour mean diastolic and mean arterial pressure and endothelial-dependent vasodilatation. The secondary endpoints will explore the mechanistic explanation for a causal relationship between exposures and propensity for type II diabetes and will include additional functional outcomes such as arterial compliance, heart rate variability and plasma adipokines. The novel aspects of the study include the launch of infrastructure for future translational investigations in highly polluted urbanized environments and the creation of novel methodologies for linking personalized exposure measurements with functional CM outcomes. We believe that AIRCMD will allow for unprecedented new investigations into the association between environmental risk factors and CM disorders.

  10. Cyclic organic peroxides identification and trace analysis by Raman microscopy and open-air chemical ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Pena-Quevedo, Alvaro Javier

    The persistent use of cyclic organic peroxides in explosive devices has increased the interest in study these compounds. Development of methodologies for the detection of triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) has become an urgent priority. However, differences in physical properties between cyclic organic peroxides make difficult the development of a general method for peroxide analysis and detection. Following this urgency, the first general technique for the analysis of any peroxide, regarding its structural differences is reported. Characterization and detection of TATP and HMTD was performed using an Open-Air Chemical Ionization High-Resolution Time-of-Flight Mass Spectrometer. The first spectrometric analysis for tetramethylene diperoxide dicarbamide (TMDD) and other nitrogen based peroxides using Raman Microscopy and Mass Spectrometry is reported. Analysis of cyclic peroxides by GC-MS was also conducted to compare results with OACI-HRTOF data. In the OACI mass spectrum, HMTD showed a clear signal at m/z 209 MH + and a small adduct peak at m/z 226 [M+NH4]+ that allowed its detection in commercial standard solutions and lab made standards. TMDD presented a molecular peak of m/z 237 MH+ and an adduct peak of m/z 254 [M+NH4]+. TATP showed a single peak at m/z 240 [M+NH4]+, while the peak of m/z 223 or 222 was completely absent. This evidence suggests that triperoxides are stabilized by the ammonium ion. TATP samples with deuterium enrichment were analyzed to compare results that could differentiate from HMTD. Raman microscopy was used as a complementary characterization method and was an essential tool for cyclic peroxides identification, particularly for those which could not be extensively purified. All samples were characterized by Raman spectroscopy to confirm the Mass Spectrometry results. Peroxide O-O vibrations were observed around 750-970 cm-1. D18-TATP studies had identified ketone triperoxide nu(O-O) vibration around

  11. The potential of LIRIC to validate the vertical profiles of the aerosol mass concentration estimated by an air quality model

    NASA Astrophysics Data System (ADS)

    Siomos, Nikolaos; Filoglou, Maria; Poupkou, Anastasia; Liora, Natalia; Dimopoulos, Spyros; Melas, Dimitris; Chaikovsky, Anatoli; Balis, Dimitris

    2015-04-01

    Vertical profiles of the aerosol mass concentration derived by a retrieval algorithm that uses combined sunphotometer and LIDAR data (LIRIC) were used in order to validate the mass concentration profiles estimated by the air quality model CAMx. LIDAR and CIMEL measurements of the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki were used for this validation.The aerosol mass concentration profiles of the fine and coarse mode derived by CAMx were compared with the respective profiles derived by the retrieval algorithm. For the coarse mode particles, forecasts of the Saharan dust transportation model BSC-DREAM8bV2 were also taken into account. Each of the retrieval algorithm's profiles were matched to the models' profile with the best agreement within a time window of four hours before and after the central measurement. OPAC, a software than can provide optical properties of aerosol mixtures, was also employed in order to calculate the angstrom exponent and the lidar ratio values for 355nm and 532nm for each of the model's profiles aiming in a comparison with the angstrom exponent and the lidar ratio values derived by the retrieval algorithm for each measurement. The comparisons between the fine mode aerosol concentration profiles resulted in a good agreement between CAMx and the retrieval algorithm, with the vertical mean bias error never exceeding 7 μgr/m3. Concerning the aerosol coarse mode concentration profiles both CAMx and BSC-DREAM8bV2 values are severely underestimated, although, in cases of Saharan dust transportation events there is an agreement between the profiles of BSC-DREAM8bV2 model and the retrieval algorithm.

  12. Synoptic weather types and aeroallergens modify the effect of air pollution on hospitalisations for asthma hospitalisations in Canadian cities.

    PubMed

    Hebbern, Christopher; Cakmak, Sabit

    2015-09-01

    Pollution levels and the effect of air pollution on human health can be modified by synoptic weather type and aeroallergens. We investigated the effect modification of aeroallergens on the association between CO, O3, NO2, SO2, PM10, PM2.5 and asthma hospitalisation rates in seven synoptic weather types. We developed single air pollutant models, adjusted for the effect of aeroallergens and stratified by synoptic weather type, and pooled relative risk estimates for asthma hospitalisation in ten Canadian cities. Aeroallergens significantly modified the relative risk in 19 pollutant-weather type combinations, reducing the size and variance for each single pollutant model. However, aeroallergens did not significantly modify relative risk for any pollutant in the DT or MT weather types, or for PM10 in any weather type. Thus, there is a modifying effect of aeroallergens on the association between CO, O3, NO2, SO2, PM2.5 and asthma hospitalisations that differs under specific synoptic weather types.

  13. The deflagration stage of Chandrasekhar mass models for type Ia supernovae. I. Early evolution

    SciTech Connect

    Malone, C. M.; Woosley, S. E.; Dong, S.; Nonaka, A.; Almgren, A. S.; Bell, J. B.; Zingale, M.

    2014-02-10

    We present high-resolution, full-star simulations of the post-ignition phase of Type Ia supernovae using the compressible hydrodynamics code Castro. Initial conditions, including the turbulent velocity field and ignition site, are imported directly from a simulation of the last few hours of presupernova convection using a low Mach number code, Maestro. Adaptive mesh refinement allows the initial burning front to be modeled with an effective resolution of 36,864{sup 3} zones (136 m zone{sup –1}). The initial rise and expansion of the deflagration front are tracked until burning reaches the star's edge and the role of the background turbulence on the flame is investigated. The effect of artificially moving the ignition location closer to the star's center is explored. The degree to which turbulence affects the burning front decreases with increasing ignition radius since the buoyancy force is stronger at larger radii. Even central ignition—in the presence of a background convective flow field—is rapidly carried off-center as the flame is carried by the flow field. We compare our results to analytic models for burning thermals, and find that they reproduce the general trends of the bubble's size and mass, but underpredict the amount of buoyant acceleration due to simplifying assumptions of the bubble's properties. Overall, we find that the amount of mass that burns prior to flame break out is small, consistent with a gravitationally confined detonation' occurring at a later epoch, but additional burning will occur following breakout that may modify this conclusion.

  14. The Potential of The Synergy of Sunphotometer and Lidar Data to Validate Vertical Profiles of The Aerosol Mass Concentration Estimated by An Air Quality Model

    NASA Astrophysics Data System (ADS)

    Siomos, N.; Filioglou, M.; Poupkou, A.; Liora, N.; Dimopoulos, S.; Melas, D.; Chaikovsky, A.; Balis, D. S.

    2016-06-01

    Vertical profiles of the aerosol mass concentration derived by the Lidar/Radiometer Inversion Code (LIRIC), that uses combined sunphotometer and lidar data, were used in order to validate the aerosol mass concentration profiles estimated by the air quality model CAMx. Lidar and CIMEL measurements performed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece (40.5N, 22.9E) from the period 2013-2014 were used in this study.

  15. Biomass Burning versus Fossil Fuel Combustion Signatures of Air Masses Transported from Asia to the U.S. West Coast during ITCT2k2

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Cooper, O.; Warneke, C.; Hudson, P.; Brock, C.; Fehsenfeld, F.; Holloway, J.; Huebler, G.; Murphy, D.; Nowak, J.; Parrish, D.; Ryerson, T.; Trainer, M.; Atlas, E.

    2003-12-01

    The goal of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT2k2) was to study the transport of air pollution from Asia across the Pacific Ocean, and the implications for the background atmospheric composition at the surface in North America. During research flights of the NOAA WP-3 research aircraft on May 5 and 17, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia in the free troposphere to North America. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on May 5, 17 and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) versus propane (C3H8), and the percentage of particles measured by the PALMS (particle analysis by laser mass spectrometry) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast at various latitudes and pressures during the entire ITCT2k2 period, showed that air masses from South-East Asia and China were generally transported at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for South-East Asia. Combined with the origin of the air masses versus altitude determined by the back-trajectories, this explains the measured altitude profiles of the biomass burning indicators.

  16. A new precise mass for the progenitor of the Type IIP SN 2008bk

    NASA Astrophysics Data System (ADS)

    Maund, Justyn R.; Mattila, Seppo; Ramirez-Ruiz, Enrico; Eldridge, John J.

    2014-02-01

    The progenitor of the Type IIP supernova (SN) 2008bk was discovered in pre-explosion g'r'i'IYJHKs images, acquired with European Southern Observatory Very Large Telescope FOcal Reducer and low dispersion Spectrograph, High Acuity Wide field K-band Imager and Infrared Spectrometer and Array Camera instruments and the Gemini Multi-Object Spectrograph-South instrument. The wealth of pre-explosion observations makes the progenitor of this SN one of the best studied, since the detection of the progenitor of SN 1987A. Previous analyses of the properties of the progenitor were hampered by the limited quality of the photometric calibration of the pre-explosion images and the crowded nature of the field containing the SN. We present new late-time observations of the site of SN 2008bk acquired with identical instrument and filter configurations as the pre-explosion observations, and confirm that the previously identified red supergiant (RSG) star was the progenitor of this SN and has now disappeared. Image subtraction techniques were used to conduct precise photometry of the now missing progenitor, independently of blending from any nearby stars. The nature of the surrounding stellar population and their contribution to the flux attributed to the progenitor in the pre-explosion images are probed using Hubble Space Telescope Wide Field Camera 3 Ultraviolet-Visible/Infrared observations. In comparison with MARCS synthetic spectra, we find the progenitor was a highly reddened RSG with luminosity log (L/{L}_{{⊙}})=4.84^{+0.10}_{-0.12}, corresponding to an initial mass of M_init=12.9^{+1.6}_{-1.8} M_{{⊙}}. The temperature of the progenitor was hotter than previously expected for RSGs (T ˜ 4330 K), but consistent with new temperatures derived for RSGs using spectral energy distribution fitting techniques. We show that there is evidence for significant extinction of the progenitor, possibly arising in the circumstellar medium, but that this dust yields a similar reddening law

  17. Satellite-based identification of tropopause folding signatures along air mass boundaries

    NASA Astrophysics Data System (ADS)

    Wimmers, Anthony James

    Tropopause folding is a significant though frequently underestimated source of mass exchange between the stratosphere and the troposphere. Although tropopause folds are inherently three-dimensional phenomena, empirical evidence shows that certain signature features in two-dimensional satellite products that are sensitive to tropopause height can be used to infer the vertical layering that characterizes tropopause folds. Both Altered Water Vapor (AWV) imagery and Total Ozone Mapping Spectrometer (TOMS) total ozone reveal significant gradients at the "openings" of tropopause folds, and the direction of the gradient indicates the direction of the intrusion. This is demonstrated empirically with a comparison of the satellite imagery to a data set of aircraft-based ozone lidar transects from the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiment. Using the data set to optimize the parameters of this empirical relationship, a statistical model is developed to predict the location of tropopause folds based solely on the properties of AWV imagery, which operates on a hemispheric-scale domain and at the approximately 10-km resolution of the GOES water vapor channel. Validation of this model with evidence of tropopause folding from operational radiosonde data was only partially successful; the validation was not reliable enough to provide precise confirmation of the model parameter values, but it did provide some confirmation that the model was well calibrated. Application of this model over a February to May, 2000 time period provides a four-month "climatology" of tropopause folding activity around North America. During this time period, tropopause folding activity was strongest over the northeast Pacific and northwest Atlantic, and at a minimum in the high latitudes around Hudson Bay. Over the entire domain (25--63° N, 40--165° W), tropopause folding activity was greatest in March. This result does not prove that downward vertical transport from

  18. The Sloan Lens ACS Survey. X. Stellar, Dynamical, and Total Mass Correlations of Massive Early-type Galaxies

    NASA Astrophysics Data System (ADS)

    Auger, M. W.; Treu, T.; Bolton, A. S.; Gavazzi, R.; Koopmans, L. V. E.; Marshall, P. J.; Moustakas, L. A.; Burles, S.

    2010-11-01

    We use stellar masses, surface photometry, strong-lensing masses, and stellar velocity dispersions (σ e/2) to investigate empirical correlations for the definitive sample of 73 early-type galaxies (ETGs) that are strong gravitational lenses from the SLACS survey. The traditional correlations (fundamental plane (FP) and its projections) are consistent with those found for non-lens galaxies, supporting the thesis that SLACS lens galaxies are representative of massive ETGs (dimensional mass M dim = 1011-1012 M sun). The addition of high-precision strong-lensing estimates of the total mass allows us to gain further insights into their internal structure: (1) the average slope of the total mass-density profile ( ρ_tot∝ r^{-γ'}) is langγ'rang = 2.078 ± 0.027 with an intrinsic scatter of 0.16 ± 0.02; (2) γ' correlates with effective radius (re ) and central mass density, in the sense that denser galaxies have steeper profiles; (3) the dark matter (DM) fraction within re /2 is a monotonically increasing function of galaxy mass and size (due to a mass-dependent central cold DM distribution or due to baryonic DM—stellar remnants or low-mass stars—if the initial mass function is non-universal and its normalization increases with mass); (4) the dimensional mass M dim ≡ 5re σ2 e/2/G is proportional to the total (lensing) mass M _{r_{e}/2}, and both increase more rapidly than stellar mass M * (M _* ∝ {M}_{r_{e}/2}^{0.8}); (5) the mass plane (MP), obtained by replacing surface brightness with surface mass density in the FP, is found to be tighter and closer to the virial relation than the FP and the M*P, indicating that the scatter of those relations is dominated by stellar population effects; (6) we construct the fundamental hyper-plane by adding stellar masses to the MP and find the M * coefficient to be consistent with zero and no residual intrinsic scatter. Our results demonstrate that the dynamical structure of ETGs is not scale invariant and that it is

  19. Recent trends of persistent organic pollutants in air in central Europe - Air monitoring in combination with air mass trajectory statistics as a tool to study the effectivity of regional chemical policy

    NASA Astrophysics Data System (ADS)

    Dvorská, A.; Lammel, G.; Holoubek, I.

    We use air mass back trajectory analysis of persistent organic pollutant (POP) levels monitored at a regional background site, Košetice, Czech Republic, as a tool to study the effectiveness of emission reduction measures taken in the last decade in the region. The representativity of the chosen trajectory starting height for air sampling near ground was ensured by excluding trajectories starting at time of inversions lower than their starting height. As the relevant pollutant sources are exclusively located in the atmospheric boundary layer, trajectory segments above this layer were also excluded from the analysis. We used a linear time weight to account for the influence of dispersion and deposition on trace components abundances and to quantify the ground source loading, a continuous measure for the influence of surface emissions. Hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), DDT, and two time periods, the years 1997-1999 and 2004-2006, were studied. The pollutant levels transported to Košetice decreased for all substances except HCB. Except for lindane seasonal emissions were insignificant. Increasing emissions of HCB were at least partly linked to the 2002 floods in the Danube basin. Major emissions of 1997-1999 which decreased significantly were in France (lindane), western Poland, Hungary and northern ex-Yugoslavia (technical HCH), and the Czech Republic (DDT). Emissions remaining in 2004-2006 include HCB and DDT in the northern Czech Republic, HCB and PCBs in Germany. Besides changes in emission strength meteorological factors influence the level of transported pollutant concentrations. The prevailing air flow pattern limits the geographic coverage of this analysis to central Europe and parts of western Europe. However, no POP monitoring stations exist in areas suitable for a possible extension of the study area.

  20. Validation of keratan sulfate level in mucopolysaccharidosis type IVA by liquid chromatography-tandem mass spectrometry.

    PubMed

    Tomatsu, Shunji; Montaño, Adriana M; Oguma, Toshihiro; Dung, Vu Chi; Oikawa, Hirotaka; de Carvalho, Talita Giacomet; Gutiérrez, María L; Yamaguchi, Seiji; Suzuki, Yasuyuki; Fukushi, Masaru; Kida, Kazuhiro; Kubota, Mitsuru; Barrera, Luis; Orii, Tadao

    2010-12-01

    Mucopolysaccharidosis type IVA (MPS IVA, Morquio A disease), a progressive lysosomal storage disease, causes skeletal chondrodysplasia through excessive storage of keratan sulfate (KS). KS is synthesized mainly in cartilage and released to the circulation. The excess storage of KS disrupts cartilage, consequently releasing more KS into circulation, which is a critical biomarker for MPS IVA. Thus, assessment of KS level provides a potential screening strategy and determines clinical course and efficacy of therapies. We have recently developed a tandem mass spectrometry liquid chromatography [LC/MS/MS] method to assay KS levels in blood. Forty-nine blood specimens from patients with MPS IVA [severe (n = 33), attenuated (n = 11) and undefined (n = 5)] were analyzed for comparison of blood KS concentration with that of healthy subjects and for correlation with clinical severity. Plasma samples were digested by keratanase II to obtain disaccharides of KS. Digested samples were assayed by LC/MS/MS. We found that blood KS levels (0.4-26 µg/ml) in MPS IVA patients were significantly higher than those in age-matched controls (0.67-4.6 µg/ml; P < 0.0001). It was found that blood KS level varied with age and clinical severity in the patients. Blood KS levels in MPS IVA peaked between 2 years and 5 years of age (mean 11.4 µg/ml). Blood KS levels in severe MPS IVA (mean 7.3 µg/ml) were higher than in the attenuated form (mean 2.1 µg/ml) (P = 0.012). We also found elevated blood KS levels in other types of MPS. These findings indicate that the new KS assay for blood is suitable for early diagnosis and longitudinal assessment of disease severity in MPS IVA.

  1. Regional and local vegetation patterns: The responses of vegetation to subcontinental air masses

    SciTech Connect

    Neilson, R.P.; King, G.A.; DeVelice, R.L.; Lenihan, J.M.

    1990-03-01

    Spatial patterns of biodiversity in plants were examined through a range of scales from continental and biome to patterns of local habitat variation. The authors propose a hierarchy of constraints on these patterns. Large-scale climate is proposed to structure continental patterns of species richness and the diversity and distribution of physiognomic types in the form of biomes. Within biomes regional climatic gradients modulate the length scales of habitats and, hence, the amount of substrate variation within a grain that is perceived by an organism as homogeneous. Most resource variation in the core of biomes is within a given species range of tolerance and large areas of the landscape are perceived as essentially homogeneous. As one moves toward ecotones, the convergence of regional climatic stresses constrains the suitability of habitats to smaller scale variations in substrate and topography. Thus, the size of habitat grain declines, while the diversity of habitat grains increases toward biome ecotones. Biotic interactions form a third level of constraint, operating at yet a smaller spatial scale, to further modify local species associations. The regional gradients in habitat size and variability provide explanatory power of observed patterns in biodiversity and provide a monitoring tool for climate-induced changes in ecotones.

  2. Validation and Application of the Mass Balance Model To Determine the Effectiveness of Portable Air Purifiers in Removing Ultrafine and Submicrometer Particles in an Apartment.

    PubMed

    Lee, Wan-Chen; Catalano, Paul J; Yoo, Jun Young; Park, Chan Jung; Koutrakis, Petros

    2015-08-18

    We validated the use of the mass balance model to determine the effectiveness of portable air purifiers in removing ultrafine (<0.10 μm) and submicrometer particles (0.10-0.53 μm) in an apartment. We evaluated two identical portable air purifiers, equipped with high efficiency particulate air filters, for their performance under three different air flow settings and three target air exchange rates: 0.60, 0.90, and 1.20 h(-1). We subsequently used a mixed effects model to estimate the slope between the measured and modeled effectiveness by particle size. Our study showed that effectiveness was highly particle size-dependent. For example, at the lowest target air exchange rate, it ranged from 0.33 to 0.56, 0.51 to 0.75, and 0.60 to 0.81 for the three air purifier flow settings, respectively. Our findings suggested that filtration was the dominant removal mechanism for submicrometer particles, whereas deposition could play a more important role in ultrafine particle removal. We found reasonable agreement between measured and modeled effectiveness with size-resolved slopes ranging from 1.11 ± 0.06 to 1.25 ± 0.07 (mean ± SE), except for particles <35 nm. Our study design can be applied to investigate the performances of other portable air purifiers as well as the influences of various parameters on effectiveness in different residential settings.

  3. Molecular typing of Legionella pneumophila from air-conditioning cooling waters using mip gene, SBT, and FAFLP methods.

    PubMed

    Gong, Xiangli; Li, Juntao; Zhang, Ying; Hou, Shuiping; Qu, Pinghua; Yang, Zhicong; Chen, Shouyi

    2017-04-07

    Legionella spp. are important waterborne pathogens. Molecular typing has become an important method for outbreaks investigations and source tracking of Legionnaires. In a survey program conducted by the Guangzhou Center for Disease Control and Prevention, multiple serotypes Legionella pneumophila (L. pneumophila) were isolated from waters in air-conditioning cooling towers in urban Guangzhou region, China between 2008 and 2011. Three genotyping methods, mip (macrophage infectivity potentiator) genotyping, SBT (sequence-based typing), and FAFLP (fluorescent amplified fragment length polymorphism analysis) were used to type these waterborne L. pneumophila isolates. The three methods were capable of typing all the 134 isolates and a reference strain of L. pneumophila (ATCC33153), with discriminatory indices of 0.7034, 0.9218, and 0.9376, for the mip, SBT, and FAFLP methods respectively. Among the 9 serotypes of the 134 isolates, 10, 50, and 34 molecular types were detected by the mip, SBT, and FAFLP methods respectively. The mip genotyping and SBT typing are more feasible for inter-laboratory results sharing and comparison of different types of L. pneumophila. The SBT and FAFLP typing methods were rapid with higher discriminatory abilities. Combinations of two or more of the typing methods enables more accurate typing of Legionella isolates for outbreak investigations and source tracking of Legionnaires.

  4. Neutral losses: a type of important variables in prediction of branching degree for acyclic alkenes from mass spectra.

    PubMed

    Zhang, Liangxiao; Fan, Wei; Cao, Dongsheng; Zeng, Maomao; Xiao, Hongbin; Liang, Yizeng

    2012-03-30

    Neutral losses are a type of important variables in mass spectral interpretation. Since it is hard to calculate or extract neutral losses from mass spectra, they are usually discarded. In this study, dissimilarity analysis was employed to extract mass spectral characteristics for predicting branching degree of acyclic alkenes. The relationships between branching degree and neutral loss were constructed under direction of experimental observation and mass spectral fragmentations. A branching degree predictor of acyclic alkenes was subsequently built based on the above relationships. After tested by the experimental data in previous studies, the predictor could correctly provide the branching degree from abundant ions of mass spectra. More importantly, this predictor was able to point out which acyclic alkenes could be predicted correctly or not.

  5. FS CMa Type Objects - Products of Intermediate-Mass Non-Conservative Evolution

    NASA Astrophysics Data System (ADS)

    Miroshnichenko, A. S.

    2017-02-01

    The group of FS CMa type objects was formed nearly 10 years ago based on previously unclassified objects with the B[e] phenomenon. The main observational features of the group objects include strong emission-line spectra, typical of hot stars, and infrared excesses due to radiation of mostly hot circumstellar dust. Nearly one third of the group objects exhibit various signs of a cool stellar component that indicates a binary nature. The hot components have been shown to have nearly main sequence luminosities. However, mass loss rates that are much higher than those expected from single hot stars in this region of the Hertzsprung-Russell diagram are required to explain the observed emission-line strengths. Nevertheless, spectroscopic orbits have been determined only in two cases. The evolutionary state of the FS CMa objects is still not well constrained, although several possibilities, such as pre-main-sequence stars or proto-planetary nebulae, have been eliminated. I will review typical properties of the FS CMa objects and focus on a few well-studied examples. Possible evolutionary scenarios leading to the observed features will be discussed. Searching strategies for finding more group objects as well as their predecessor and successor objects will be outlined.

  6. Quantitation of the Noncovalent Cellular Retinol-Binding Protein, Type 1 Complex Through Native Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Li, Wenjing; Yu, Jianshi; Kane, Maureen A.

    2017-01-01

    Native mass spectrometry (MS) has become a valuable tool in probing noncovalent protein-ligand interactions in a sample-efficient way, yet the quantitative application potential of native MS has not been fully explored. Cellular retinol binding protein, type I (CrbpI) chaperones retinol and retinal in the cell, protecting them from nonspecific oxidation and delivering them to biosynthesis enzymes where the bound (holo-) and unbound (apo-) forms of CrbpI exert distinct biological functions. Using nanoelectrospray, we developed a native MS assay for probing apo- and holo-CrbpI abundance to facilitate exploring their biological functions in retinoid metabolism and signaling. The methods were developed on two platforms, an Orbitrap-based Thermo Exactive and a Q-IMS-TOF-based Waters Synapt G2S, where similar ion behaviors under optimized conditions were observed. Overall, our results suggested that within the working range ( 1-10 μM), gas-phase ions in the native state linearly correspond to solution concentration and relative ion intensities of the apo- and holo-protein ions can linearly respond to the solution ratios, suggesting native MS is a viable tool for relative quantitation in this system.

  7. FLARE-GENERATED TYPE II BURST WITHOUT ASSOCIATED CORONAL MASS EJECTION

    SciTech Connect

    Magdalenic, J.; Marque, C.; Zhukov, A. N.; Vrsnak, B.; Veronig, A.

    2012-02-20

    We present a study of the solar coronal shock wave on 2005 November 14 associated with the GOES M3.9 flare that occurred close to the east limb (S06 Degree-Sign E60 Degree-Sign ). The shock signature, a type II radio burst, had an unusually high starting frequency of about 800 MHz, indicating that the shock was formed at a rather low height. The position of the radio source, the direction of the shock wave propagation, and the coronal electron density were estimated using Nancay Radioheliograph observations and the dynamic spectrum of the Green Bank Solar Radio Burst Spectrometer. The soft X-ray, H{alpha}, and Reuven Ramaty High Energy Solar Spectroscopic Imager observations show that the flare was compact, very impulsive, and of a rather high density and temperature, indicating a strong and impulsive increase of pressure in a small flare loop. The close association of the shock wave initiation with the impulsive energy release suggests that the impulsive increase of the pressure in the flare was the source of the shock wave. This is supported by the fact that, contrary to the majority of events studied previously, no coronal mass ejection was detected in association with the shock wave, although the corresponding flare occurred close to the limb.

  8. Air mass origin signals in δ 18O of tree-ring cellulose revealed by back-trajectory modeling at the monsoonal Tibetan plateau

    NASA Astrophysics Data System (ADS)

    Wernicke, Jakob; Hochreuther, Philipp; Grießinger, Jussi; Zhu, Haifeng; Wang, Lily; Bräuning, Achim

    2016-12-01

    A profound consideration of stable oxygen isotope source water origins is a precondition for an unambiguous palaeoenvironmental interpretation of terrestrial δ 18O archives. To stress the influence of air mass origins on widely used δ 18O tree-ring chronologies, we conducted correlation analyses between six annually resolved δ 18O tree-ring cellulose ( δ ^{18}O_{TC}) chronologies and mean annual air package origins obtained from backward trajectory modeling. This novel approach has been tested for a transect at the southeastern Tibetan plateau (TP), where air masses with different isotopic composition overlap. Detailed examinations of daily precipitation amounts and monthly precipitation δ 18O values ( δ ^{18}OP) were conducted with the ERA Interim and Laboratoire de Météorologie Dynamique General Circulation Model (LMDZiso) data, respectively. Particularly the southernmost study sites are influenced by a distinct amount effect. Here, air package origin δ ^{18}O_{TC} relations are generally weaker in contrast to our northern located study sites. We found that tree-ring isotope signatures at dry sites with less rain days per year tend to be influenced stronger by air mass origin than tree-ring isotope values at semi-humid sites. That implies that the local hydroclimate history inferred from δ ^{18}O_{TC} archives is better recorded at semi-humid sites.

  9. Sub-luminous type Ia supernovae from the mergers of equal-mass white dwarfs with mass approximately 0.9M[symbol: see text].

    PubMed

    Pakmor, Rüdiger; Kromer, Markus; Röpke, Friedrich K; Sim, Stuart A; Ruiter, Ashley J; Hillebrandt, Wolfgang

    2010-01-07

    Type Ia supernovae are thought to result from thermonuclear explosions of carbon-oxygen white dwarf stars. Existing models generally explain the observed properties, with the exception of the sub-luminous 1991bg-like supernovae. It has long been suspected that the merger of two white dwarfs could give rise to a type Ia event, but hitherto simulations have failed to produce an explosion. Here we report a simulation of the merger of two equal-mass white dwarfs that leads to a sub-luminous explosion, although at the expense of requiring a single common-envelope phase, and component masses of approximately 0.9M[symbol: see text]. The light curve is too broad, but the synthesized spectra, red colour and low expansion velocities are all close to what is observed for sub-luminous 1991bg-like events. Although the mass ratios can be slightly less than one and still produce a sub-luminous event, the masses have to be in the range 0.83M[symbol: see text] to 0.9M[symbol: see text].

  10. The type Ia supernova SNLS-03D3bb from a super-Chandrasekhar-mass white dwarf star.

    PubMed

    Howell, D Andrew; Sullivan, Mark; Nugent, Peter E; Ellis, Richard S; Conley, Alexander J; Le Borgne, Damien; Carlberg, Raymond G; Guy, Julien; Balam, David; Basa, Stephane; Fouchez, Dominique; Hook, Isobel M; Hsiao, Eric Y; Neill, James D; Pain, Reynald; Perrett, Kathryn M; Pritchet, Christopher J

    2006-09-21

    The accelerating expansion of the Universe, and the need for dark energy, were inferred from observations of type Ia supernovae. There is a consensus that type Ia supernovae are thermonuclear explosions that destroy carbon-oxygen white dwarf stars that have accreted matter from a companion star, although the nature of this companion remains uncertain. These supernovae are thought to be reliable distance indicators because they have a standard amount of fuel and a uniform trigger: they are predicted to explode when the mass of the white dwarf nears the Chandrasekhar mass of 1.4 solar masses (M(o)). Here we show that the high-redshift supernova SNLS-03D3bb has an exceptionally high luminosity and low kinetic energy that both imply a super-Chandrasekhar-mass progenitor. Super-Chandrasekhar-mass supernovae should occur preferentially in a young stellar population, so this may provide an explanation for the observed trend that overluminous type Ia supernovae occur only in 'young' environments. As this supernova does not obey the relations that allow type Ia supernovae to be calibrated as standard candles, and as no counterparts have been found at low redshift, future cosmology studies will have to consider possible contamination from such events.

  11. Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH

    ERIC Educational Resources Information Center

    Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P.

    2011-01-01

    Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various…

  12. REAL TIME, ON-LINE CHARACTERIZATION OF DIESEL GENERATOR AIR TOXIC EMISSIONS BY RESONANCE ENHANCED MULTI-PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY

    EPA Science Inventory

    The laser based resonance, enhanced multi-photon ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds ...

  13. CO2 Fixation, Lipid Production, and Power Generation by a Novel Air-Lift-Type Microbial Carbon Capture Cell System.

    PubMed

    Hu, Xia; Liu, Baojun; Zhou, Jiti; Jin, Ruofei; Qiao, Sen; Liu, Guangfei

    2015-09-01

    An air-lift-type microbial carbon capture cell (ALMCC) was constructed for the first time by using an air-lift-type photobioreactor as the cathode chamber. The performance of ALMCC in fixing high concentration of CO2, producing energy (power and biodiesel), and removing COD together with nutrients was investigated and compared with the traditional microbial carbon capture cell (MCC) and air-lift-type photobioreactor (ALP). The ALMCC system produced a maximum power density of 972.5 mW·m(-3) and removed 86.69% of COD, 70.52% of ammonium nitrogen, and 69.24% of phosphorus, which indicate that ALMCC performed better than MCC in terms of power generation and wastewater treatment efficiency. Besides, ALMCC demonstrated 9.98- and 1.88-fold increases over ALP and MCC in the CO2 fixation rate, respectively. Similarly, the ALMCC significantly presented a higher lipid productivity compared to those control reactors. More importantly, the preliminary analysis of energy balance suggested that the net energy of the ALMCC system was significantly superior to other systems and could theoretically produce enough energy to cover its consumption. In this work, the established ALMCC system simultaneously achieved the high level of CO2 fixation, energy recycle, and municipal wastewater treatment effectively and efficiently.

  14. Determination of trichloroanisole and trichlorophenol in wineries' ambient air by passive sampling and thermal desorption-gas chromatography coupled to tandem mass spectrometry.

    PubMed

    Camino-Sánchez, F J; Bermúdez-Peinado, R; Zafra-Gómez, A; Ruíz-García, J; Vílchez-Quero, J L

    2015-02-06

    The present paper describes the calibration of selected passive samplers used in the quantitation of trichlorophenol and trichloroanisole in wineries' ambient air, by calculating the corresponding sampling rates. The method is based on passive sampling with sorbent tubes and involves thermal desorption-gas chromatography-triple quadrupole mass spectrometry analysis. Three commercially available sorbents were tested using sampling cartridges with a radial design instead of axial ones. The best results were found for Tenax TA™. Sampling rates (R-values) for the selected sorbents were determined. Passive sampling was also used for accurately determining the amount of compounds present in the air. Adequate correlation coefficients between the mass of the target analytes and exposure time were obtained. The proposed validated method is a useful tool for the early detection of trichloroanisole and its precursor trichlorophenol in wineries' ambient air while avoiding contamination of wine or winery facilities.

  15. Transport Regimes of Air Masses Affecting the Tropospheric Composition of the Canadian and European Arctic During RACEPAC 2014 and NETCARE 2014/2015

    NASA Astrophysics Data System (ADS)

    Bozem, H.; Hoor, P. M.; Koellner, F.; Kunkel, D.; Schneider, J.; Schulz, C.; Herber, A. B.; Borrmann, S.; Wendisch, M.; Ehrlich, A.; Leaitch, W. R.; Willis, M. D.; Burkart, J.; Thomas, J. L.; Abbatt, J.

    2015-12-01

    The Arctic is warming much faster than any other place in the world and undergoes a rapid change dominated by a changing climate in this region. The impact of polluted air masses traveling to the Arctic from various remote sources significantly contributes to the observed climate change, in contrast there are additional local emission sources contributing to the level of pollutants (trace gases and aerosol). Processes affecting the emission and transport of these pollutants are not well understood and need to be further investigated. We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories we analyze the transport regimes prevalent during spring (RACEPAC 2014 and NETCARE 2015) and summer (NETCARE 2014) in the observed region. Whereas the eastern part of the Canadian Arctic is affected by air masses with their origin in Asia, in the central and western parts of the Canadian and European Arctic air masses from North America are predominant at the time of the measurement. In general the more northern parts of the Arctic were relatively unaffected by pollution from mid-latitudes since air masses mostly travel within the polar dome, being quite isolated. Associated mixing ratios of CO and CO2 fit into the seasonal cycle observed at NOAA ground stations throughout the Arctic, but show a more mid-latitudinal characteristic at higher altitudes. The transition is remarkably sharp and allows for a chemical definition of the polar dome. At low altitudes, synoptic disturbances transport polluted air masses from mid-latitudes into regions of the polar dome. These air masses contribute to the Arctic pollution background, but also

  16. Formic and Acetic Acid Observations over Colorado by Chemical Ionization Mass Spectrometry and Organic Acids' Role in Air Quality

    NASA Astrophysics Data System (ADS)

    Treadaway, V.; O'Sullivan, D. W.; Heikes, B.; Silwal, I.; McNeill, A.

    2015-12-01

    Formic acid (HFo) and acetic acid (HAc) have both natural and anthropogenic sources and a role in the atmospheric processing of carbon. These organic acids also have an increasing importance in setting the acidity of rain and snow as precipitation nitrate and sulfate concentrations have decreased. Primary emissions for both organic acids include biomass burning, agriculture, and motor vehicle emissions. Secondary production is also a substantial source for both acids especially from biogenic precursors, secondary organic aerosols (SOAs), and photochemical production from volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs). Chemical transport models underestimate organic acid concentrations and recent research has sought to develop additional production mechanisms. Here we report HFo and HAc measurements during two campaigns over Colorado using the peroxide chemical ionization mass spectrometer (PCIMS). Iodide clusters of both HFo and HAc were recorded at mass-to-charge ratios of 173 and 187, respectively. The PCIMS was flown aboard the NCAR Gulfstream-V platform during the Deep Convective Clouds and Chemistry Experiment (DC3) and aboard the NCAR C-130 during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE). The DC3 observations were made in May and June 2012 extending from the surface to 13 km over the central and eastern United States. FRAPPE observations were made in July and August 2014 from the surface to 7 km over Colorado. DC3 measurements reported here are focused over the Colorado Front Range and complement the FRAPPE observations. DC3 HFo altitude profiles are characterized by a decrease up to 6 km followed by an increase either back to boundary layer mixing ratio values or higher (a "C" shape). Organic acid measurements from both campaigns are interpreted with an emphasis on emission sources (both natural and anthropogenic) over Colorado and in situ photochemical production especially ozone precursors.

  17. Elemental composition and radical formation potency of PM10 at an urban background station in Germany in relation to origin of air masses

    NASA Astrophysics Data System (ADS)

    Hellack, Bryan; Quass, Ulrich; Beuck, Henning; Wick, Gabriele; Kuttler, Wilhelm; Schins, Roel P. F.; Kuhlbusch, Thomas A. J.

    2015-03-01

    At an urban background station in Mülheim-Styrum, North Rhine Westphalia, Germany, a set of 75 PM10 samples was collected over a one year period, followed by analyses for mass, chemical composition and hydroxyl radical (OHrad) formation potency. Additionally, the origin of air masses for the sampling days was calculated by 48-h backward trajectories, subdivided into the four cardinal sectors. Significant lower PM10 mass concentrations were observed for summertime air masses from the west compared to the other seasons and cardinal sectors. For the OHrad formation potency higher values were detected if air masses originate from east and south, thus predominantly being of continental origin. From the elevated OHrad formation potencies in fall and winter a seasonal trend with low potencies in summers is assumed. Furthermore, source apportionment was performed by a positive matrix factor analysis, separating seven plausible factors which could be attributed to mineral dust, secondary nitrate, industry, non-exhaust traffic, fossil fuel combustion, marine aerosol and secondary aerosol factors. The intrinsic OHrad formation potency was found to be associated mainly with the fossil fuel combustion factor (45%) and industry factor (22%).

  18. Optimization of automated gas sample collection and isotope ratio mass spectrometric analysis of delta(13)C of CO(2) in air.

    PubMed

    Zeeman, Matthias J; Werner, Roland A; Eugster, Werner; Siegwolf, Rolf T W; Wehrle, Günther; Mohn, Joachim; Buchmann, Nina

    2008-12-01

    The application of (13)C/(12)C in ecosystem-scale tracer models for CO(2) in air requires accurate measurements of the mixing ratios and stable isotope ratios of CO(2). To increase measurement reliability and data intercomparability, as well as to shorten analysis times, we have improved an existing field sampling setup with portable air sampling units and developed a laboratory setup for the analysis of the delta(13)C of CO(2) in air by isotope ratio mass spectrometry (IRMS). The changes consist of (a) optimization of sample and standard gas flow paths, (b) additional software configuration, and (c) automation of liquid nitrogen refilling for the cryogenic trap. We achieved a precision better than 0.1 per thousand and an accuracy of 0.11 +/- 0.04 per thousand for the measurement of delta(13)C of CO(2) in air and unattended operation of measurement sequences up to 12 h.

  19. Impacts of grassland types and vegetation cover changes on surface air temperature in the regions of temperate grassland of China

    NASA Astrophysics Data System (ADS)

    Shen, Xiangjin; Liu, Binhui; Li, Guangdi; Yu, Pujia; Zhou, Daowei

    2016-10-01

    The sensitivity of surface air temperature response to different grassland types and vegetation cover changes in the regions of temperate grassland of China was analyzed by observation minus reanalysis (OMR) method. The basis of the OMR approach is that reanalysis data are insensitive to local surface properties, so the temperature differences between surface observations and reanalysis can be attributed to land effects. Results showed that growing-season air temperature increased by 0.592 °C/decade in the regions of temperate grassland of China, with about 31 % of observed warming associated with the effects of grassland types and vegetation cover changes. For different grassland types, the growing-season OMR trend was the strongest for temperate desert steppe (0.259 °C/decade) and the weakest for temperate meadow (0.114 °C/decade). Our results suggest that the stronger intraseasonal changes of grassland vegetation are present, the more sensitive the OMR trend responds to the intraseasonal vegetation cover changes. In August and September, the OMR of temperate meadow showed a weak cooling trend. For temperate meadow, about 72.2 and 72.6 % of surface cooling were explained by both grassland type and increase of vegetation cover for August and September, respectively. For temperate steppe and temperate desert steppe, due to the limited soil moisture and little evaporative cooling feedback, the vegetation changes have no significant effect on the surface air temperature. These results indicate that the impact of grassland types and vegetation cover changes should be considered when projecting further climate change in the temperate grassland region of China.

  20. Student understanding of the volume, mass, and pressure of air within a sealed syringe in different states of compression

    NASA Astrophysics Data System (ADS)

    de Berg, Kevin Charles

    Problem-solving strategies in the physical sciences have been characterized by a dependence on algorithmic techniques often devoid of any reasoning skills. The purpose of this study was to examine student responses to a task relating to Boyle's Law for gases, which did not demand the use of a mathematical equation for its solution. Students (17- to 18-year-olds) in lower sixth form from two colleges in the Leeds district of Yorkshire in England were asked to respond to a task relating to pressure and volume measurements of air within a sealed syringe in different states of compression. Both qualitative and quantitative tasks for the sealed syringe system were examined. It was found that 34% to 38% of students did not understand the concepts of volume and mass, respectively, of a gas under such circumstances. Performance on an inverse ratio (2:1) task was shown to depend on gender and those students who performed well on the 2:1 inverse ratio task did not necessarily perform well on a different inverse ratio task when an arithmetic averaging principle was present. Tasks which draw upon qualitative knowledge as well as quantitative knowledge have the potential to reduce dependence on algorithms, particularly equation substitution and solution. The implications for instructional design are discussed.Received: 14 April 1993; Revised: 29 June 1994;

  1. The Effect of Isotopic Composition on the Uncertainty of Routine Metal Mass Concentration Measurements in Ambient Air

    PubMed Central

    Brown, Richard J. C.; Goddard, Sharon L.; Brown, Andrew S.; Yardley, Rachel E.

    2008-01-01

    The main sources of uncertainty encountered during the analysis of the mass concentration of metals in ambient air as part of the operation of the UK Heavy Metals Monitoring Network are presented. It is observed that the uncertainty contribution from possible variation in the isotopic composition of the sample depends on the element in question, but can be significant (e.g., for Pb, Cd, and Hg). The working curve method for the ICP-MS analysis of metals in solution, with a low resolution, high throughput instrument measuring at one m/z ratio per element, relies on the relative abundance of the isotopes under consideration being the same in both the sample and the calibration solution. Calculation of the uncertainty in this analysis assumes that the isotopic composition variation within the sample and calibration solution is limited to a defined range. Therefore, in order to confirm the validity of this quantification methodology and its uncertainty budget, the isotopic composition of the calibration standards used for quantification has been determined. The results of this analysis are presented here. PMID:19223968

  2. Total ozone seasonal and interannual variations in the principal air masses of the Northern Hemisphere in 1975-1990

    NASA Technical Reports Server (NTRS)

    Karol, Igor L.; Klyagina, L. P.; Shalamyansky, A. M.; Jagovkina, S. V.

    1994-01-01

    The diurnally mean total ozone X from the Northern Hemisphere ground based 90 stations for 1975-1990 are averaged over the Arctic (bar X (sub A)) Intermediate (bar X (sub I)) and Tropical (bar X (sub T)) air mass areas, divided by the jet stream axes on the isobaric surfaces 300 and 200 mb. The mean square variations of the so averaged X are considerably smaller than of the X, averaged over the corresponding zonal belts. This property allows one to improve considerably the statistical significance of X trends and changes over various time periods, taking into account the time correlation of data for adjacent time intervals. Bar X (sub A), bar X (sub I), and bar X (sub T) trends are estimated over the periods of solar activity rise and fall in its 21st and rise in its 22nd 11 year cycles and over the periods of west and east phases of the known over the periods of west and east phases of the known quasibiennial oscillation (QBO). Solar activity variations affect mostly bar X (sub T), bar X (sub I) trends in summer months, while QBO phases influence the X changes mostly during the cold half year. X are lower in the west QBO phase and their trend is negative during almost all periods considered. The anthropogenic effects on the X is also estimated.

  3. Conjugate acene fused buckybowls: evaluating their suitability for p-type, ambipolar and n-type air stable organic semiconductors.

    PubMed

    Purushotham, Uppula; Sastry, G Narahari

    2013-04-14

    Elaborate and exhaustive first principles calculations were carried out to screen the novel properties of a series of acene fused buckybowls. The acene fused compounds exhibit hole transport property due to their higher electron injection and lower hole transport barrier relative to the work function potential of Au electrodes. The higher HOMO and lower LUMO energy levels suggest lower hole and electron injection barriers of F and CN substituted and boron doped bowls which indicates ambipolar property of these bowls. The dicyano substituted pentacene fused bowls show only electron transport property with lower LUMO (-4.26 eV to -4.27 eV) and higher HOMO (-5.56 eV to -5.90 eV) energy levels. High electron affinity (>2.80 eV) and low LUMO energy (< -4.00 eV) attributes air stability to these bowls. Curvature decreased frontier orbital energies and increased ionization energy and electron affinity of bowls. This study reveals substitution of electron withdrawing groups and boron doped acene fused bowls can be a prominent materials for ambipolar and electron transport organic semiconductors.

  4. 75 FR 70106 - Airworthiness Directives; Viking Air Limited (Type Certificate Previously Held by Bombardier, Inc...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-17

    ... fuel tank explosion. Viking Air Limited has revised Chapter 5 of the DHC-7 Maintenance Manual, PSM 1-7... (TR) listed in Chapter 5 of the Viking Dash 7 Series 1/100 Aircraft Maintenance Manual (AMM), PSM 1-7..., 2008, to Chapter 5 of the Viking Dash 7 Series 100 Maintenance Manual PSM 1-7-2. Note 1: This may...

  5. The interplay between surface micro-topography and -mechanics of type I collagen fibrils in air and aqueous media: An atomic force microscopy study

    NASA Astrophysics Data System (ADS)

    Kato, K.; Bar, G.; Cantow, H.-J.

    2001-09-01

    Calf skin type I collagen fibrils were regenerated from acidic solution and imaged with contact mode atomic force microscopy in air, water, and buffer solution. When imaged in air at a contact force of 20-150 nN, collagen fibrils exhibited a distinct transverse banding pattern with a period of 65 nm, consisting of high ridges and shallow grooves. The force dependence of the images suggests that such banding pattern is attributed to the transverse contraction of the fibril upon dehydration during sample preparation, which reflects the tangential mass density across the fibril. Imaging in water and phosphate buffer solution at a contact force of 15-80 nN revealed hydrated collagen fibrils with smooth surfaces. The rigidity of the collagen fibrils decreased considerably upon hydration. Scanning the cantilever tip in an aqueous medium at a contact force of 90-280 nN enabled us to probe subunit arrangement in the bulk region of the collagen fibril. The results indicate that the molecular assembly in the hydrated fibril is akin to that in the intact form. The image resolution was improved by stabilizing the collagen molecules through crosslinking with glutaraldehyde, which served to resolve microfibril-like structure on the fibril surface.

  6. Body mass index and glycemic control influences lipoproteins in children with type 1 diabetes

    PubMed Central

    Vaid, Shalini; Hanks, Lynae; Griffin, Russell; Ashraf, Ambika P.

    2017-01-01

    Background Patients with Type 1 Diabetes Mellitus (T1DM) have an extremely high risk of cardiovascular disease (CVD) morbidity and mortality. It is well-known that dyslipidemia is a subclinical manifestation of atherosclerosis. Objective To analyze presence and predicting factors of lipoprotein abnormalities prevalent in children with T1DM and whether race specific differences exists between non-Hispanic White (NHW) and non-Hispanic Black (NHB) in the lipoprotein characteristics. Methods A retrospective electronic chart review including 600 (123 NHB and 477 NHW ) T1DM patients, ages 7.85 ± 3.75 years who underwent lipoprotein analysis. Results Relative to NHW counterparts, NHB T1DM subjects had a higher HbA1c, total cholesterol (TC), low density lipoprotein cholesterol (LDL), apoB 100, lipoprotein (a), and high density lipoprotein cholesterol (HDL), HDL-2 and -3. Body mass index (BMI) was positively associated with TC, LDL, apoB 100, and non-HDL and inversely associated with HDL, HDL-2, and HDL-3. HbA1c was positively associated with TC, LDL, apoB100, non-HDL, and HDL-3. Multilinear regression analysis demonstrated that HbA1c was positively associated with apoB 100 in both NHB and NHW, and BMI was a positive determinant of apoB 100 in NHW only. Conclusion Poor glycemic control and high BMI may contribute to abnormal lipoprotein profiles. Glycemic control (in NHB and NHW) and weight management (in NHW) may have significant implications in T1DM. ApoB100 concentrations in subjects with T1DM were determined by modifiable risk factors, BMI, HbA1C, and blood pressure, indicating the importance of adequate weight-, glycemic-, and blood pressure control for better diabetes care, and likely lower CVD risk. PMID:27678442

  7. Thermal imaging of the FU Ori type object 2MASS J06593158-0405277 = V960 Mon

    NASA Astrophysics Data System (ADS)

    Varricatt, W. P.; Kerr, T. H.; Carroll, T.; Moore, E.; Milne, P.

    2015-10-01

    A FU Ori-type outburst of 2MASS J06593158-0405277 (V960 Mon) was discovered by Maehara, Kojima and Fujii (ATel #6770). Further observational studies (ATel #6797, #6838, #6862, #6901, #7025, #7578) and archival data research (Jurdana- & #138;epi & #263; & Munari, 2016, NewA, 43, 87) confirmed the FU Ori nature of this object.

  8. Fat mass and obesity-associated gene rs11642015 polymorphism is significantly associated with prediabetes and type 2 diabetes subsequent to adjustment for body mass index.

    PubMed

    Han, Liyuan; Tang, Linlin; Wang, Changyi; Chen, Zhongwei; Zhang, Tao; Chen, Sihan; Liu, Shengyuan; Peng, Xiaolin; Mai, Yifeng; Duan, Shiwei

    2014-09-01

    The association of the fat mass and obesity-associated gene (FTO) rs11642015 polymorphism with prediabetes, type 2 diabetes and obesity in certain populations has not been previously reported. A population-based study was conducted that included 490 type 2 diabetic, 471 prediabetic and 575 normal subjects. The main outcomes of the study were prediabetes, type 2 diabetes and obesity. Binary logistic regression was performed to estimate the association of FTO rs11642015 with the risk of prediabetes, type 2 diabetes and obesity following adjustment for the corresponding confounders. A meta-analysis was also conducted to evaluate the association between FTO rs11642015 and obesity. FTO rs11642015 was significantly associated with prediabetes in the whole sample under the additive model [odds ratio (OR), 1.50; 95% confidence interval (CI), 1.17-1.93; P=0.002], particularly in females. The polymorphism remained consistently significant following adjustment for age and body mass index (BMI), showing an increased prediabetes risk with an additive effect (OR, 1.55; 95% CI, 1.19-2.01; P=0.001). In addition, a significant association was found for rs11642015 with prediabetes and type 2 diabetes under the dominant model. However, under the stringent Bonferroni's correction there was no evidence of positive associations for FTO rs11642015 with obesity in the whole sample, females or males. Findings of the meta-analysis showed that FTO rs11642015 was not predisposed to obesity. In conclusion, the T allele of FTO rs11642015 is positively associated with an increased risk of prediabetes, even after adjustment for age and BMI, particularly in females. Subjects carrying the CT + TT genotype are predisposed to prediabetes and type 2 diabetes. Therefore, results of the population-based study and follow-up meta-analysis suggested that FTO rs11642015 is not significantly associated with susceptibility to obesity.

  9. Fat mass and obesity-associated gene rs11642015 polymorphism is significantly associated with prediabetes and type 2 diabetes subsequent to adjustment for body mass index

    PubMed Central

    HAN, LIYUAN; TANG, LINLIN; WANG, CHANGYI; CHEN, ZHONGWEI; ZHANG, TAO; CHEN, SIHAN; LIU, SHENGYUAN; PENG, XIAOLIN; MAI, YIFENG; DUAN, SHIWEI

    2014-01-01

    The association of the fat mass and obesity-associated gene (FTO) rs11642015 polymorphism with prediabetes, type 2 diabetes and obesity in certain populations has not been previously reported. A population-based study was conducted that included 490 type 2 diabetic, 471 prediabetic and 575 normal subjects. The main outcomes of the study were prediabetes, type 2 diabetes and obesity. Binary logistic regression was performed to estimate the association of FTO rs11642015 with the risk of prediabetes, type 2 diabetes and obesity following adjustment for the corresponding confounders. A meta-analysis was also conducted to evaluate the association between FTO rs11642015 and obesity. FTO rs11642015 was significantly associated with prediabetes in the whole sample under the additive model [odds ratio (OR), 1.50; 95% confidence interval (CI), 1.17–1.93; P=0.002], particularly in females. The polymorphism remained consistently significant following adjustment for age and body mass index (BMI), showing an increased prediabetes risk with an additive effect (OR, 1.55; 95% CI, 1.19–2.01; P=0.001). In addition, a significant association was found for rs11642015 with prediabetes and type 2 diabetes under the dominant model. However, under the stringent Bonferroni’s correction there was no evidence of positive associations for FTO rs11642015 with obesity in the whole sample, females or males. Findings of the meta-analysis showed that FTO rs11642015 was not predisposed to obesity. In conclusion, the T allele of FTO rs11642015 is positively associated with an increased risk of prediabetes, even after adjustment for age and BMI, particularly in females. Subjects carrying the CT + TT genotype are predisposed to prediabetes and type 2 diabetes. Therefore, results of the population-based study and follow-up meta-analysis suggested that FTO rs11642015 is not significantly associated with susceptibility to obesity. PMID:25054011

  10. Size-Segregated Aerosol Composition and Mass Loading of Atmospheric Particles as Part of the Pacific Northwest 2001(PNW2001) Air Quality Study In Puget Sound

    NASA Astrophysics Data System (ADS)

    Disselkamp, R. S.; Barrie, L. A.; Shutthanadan, S.; Cliff, S.; Cahill, T.

    2001-12-01

    In mid-August, 2001, an aircraft-based air-quality study was performed in the Puget Sound, WA, area entitled PNW2001 (http://www.pnl.gov/pnw2001). The objectives of this field campaign were the following: 1. reveal information about the 3-dimensional distribution of ozone, its gaseous precursors and fine particulate matter during weather conditions favoring air pollution; 2. derive information about the accuracy of urban and biogenic emissions inventories that are used to drive the air quality forecast models; and 3. examine the accuracy of modeled ozone concentration with that observed. In support of these efforts, we collected time-averaged ( { ~}10 minute averages), size-segregated, aerosol composition and mass-loading information using ex post facto analysis techniques of synchrotron x-ray fluorescence (s-XRF), proton induced x-ray emissions(PIXE), proton elastic scattering (PESA), and scanning transmission ion microscopy (STIM). This is the first time these analysis techniques have been used together on samples collected from aircraft using an optimized 3-stage rotating drum impactor. In our presentation, we will discuss the aerosol components in three aerosol size fractions as identified by statistical analysis of multielemental data (including total mass, H, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Pb) and relate variations in these components to physical aerosol properties, other gaseous trace constituents and to air mass origin.

  11. Measurements of δ13C in CH4 and using particle dispersion modeling to characterize sources of Arctic methane within an air mass

    NASA Astrophysics Data System (ADS)

    France, J. L.; Cain, M.; Fisher, R. E.; Lowry, D.; Allen, G.; O'Shea, S. J.; Illingworth, S.; Pyle, J.; Warwick, N.; Jones, B. T.; Gallagher, M. W.; Bower, K.; Le Breton, M.; Percival, C.; Muller, J.; Welpott, A.; Bauguitte, S.; George, C.; Hayman, G. D.; Manning, A. J.; Myhre, C. Lund; Lanoisellé, M.; Nisbet, E. G.

    2016-12-01

    A stratified air mass enriched in methane (CH4) was sampled at 600 m to 2000 m altitude, between the north coast of Norway and Svalbard as part of the Methane in the Arctic: Measurements and Modelling campaign on board the UK's BAe-146-301 Atmospheric Research Aircraft. The approach used here, which combines interpretation of multiple tracers with transport modeling, enables better understanding of the emission sources that contribute to the background mixing ratios of CH4 in the Arctic. Importantly, it allows constraints to be placed on the location and isotopic bulk signature of the emission source(s). Measurements of δ13C in CH4 in whole air samples taken while traversing the air mass identified that the source(s) had a strongly depleted bulk δ13C CH4 isotopic signature of -70 (±2.1)‰. Combined Numerical Atmospheric-dispersion Modeling Environment and inventory analysis indicates that the air mass was recently in the planetary boundary layer over northwest Russia and the Barents Sea, with the likely dominant source of methane being from wetlands in that region.

  12. A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion

    SciTech Connect

    Grcar, Joseph F; Grcar, Joseph F

    2008-06-30

    Ultra-lean, hydrogen-air mixtures are found to support another kind of laminar flame that is steady and stable beside flat flames and flame balls. Direct numerical simulations are performed of flames that develop into steadily and stably propagating cells. These cells were the original meaning of the word"flamelet'' when they were observed in lean flammability studies conducted early in the development of combustion science. Several aspects of these two-dimensional flame cells are identified and are contrasted with the properties of one-dimensional flame balls and flat flames. Although lean hydrogen-air flames are subject to thermo-diffusive effects, in this case the result is to stabilize the flame rather than to render it unstable. The flame cells may be useful as basic components of engineering models for premixed combustion when the other types of idealized flames are inapplicable.

  13. Type of wear for the pair Ti6Al4V/PCTFE in ambient air and in liquid nitrogen

    NASA Astrophysics Data System (ADS)

    Bozet, J.-L.

    1993-04-01

    The pair Ti6Al4V/polychlorotrifluoroethylene (PCTFE) on a pin-on-disk tribometer in ambient air and liquid nitrogen with the contact pressure and sliding speed ranging from 3 to 9 MPa and 0.03 to 0.05 m/s, respectively, is evaluated within the framework of a high pressure valves for cryogenic rocket engines project. Results show that an abrasion wear process, which is closely connected with a tribochemical wear process producing fluorides and an abrasive form of carbon, exists when PCTFE is continuously rubbed against Ti6Al4V in ambient air, liquid nitrogen, and gaseous argon. Degradations detected on the Ti6Al4V surface are found to be unacceptable in most cases, but in the real cryotechnic valves this type of wear was not observed. The latter is attributed to the great dwell time between actuations and the low speed of the reciprocating movements which considerably limit the heating.

  14. The quantification of carbon dioxide in humid air and exhaled breath by selected ion flow tube mass spectrometry.

    PubMed

    Smith, David; Pysanenko, Andriy; Spanel, Patrik

    2009-05-01

    The reactions of carbon dioxide, CO(2), with the precursor ions used for selected ion flow tube mass spectrometry, SIFT-MS, analyses, viz. H(3)O(+), NO(+) and O(2) (+), are so slow that the presence of CO(2) in exhaled breath has, until recently, not had to be accounted for in SIFT-MS analyses of breath. This has, however, to be accounted for in the analysis of acetaldehyde in breath, because an overlap occurs of the monohydrate of protonated acetaldehyde and the weakly bound adduct ion, H(3)O(+)CO(2), formed by the slow association reaction of the precursor ion H(3)O(+) with CO(2) molecules. The understanding of the kinetics of formation and the loss rates of the relevant ions gained from experimentation using the new generation of more sensitive SIFT-MS instruments now allows accurate quantification of CO(2) in breath using the level of the H(3)O(+)CO(2) adduct ion. However, this is complicated by the rapid reaction of H(3)O(+)CO(2) with water vapour molecules, H(2)O, that are in abundance in exhaled breath. Thus, a study has been carried out of the formation of this adduct ion by the slow three-body association reaction of H(3)O(+) with CO(2) and its rapid loss in the two-body reaction with H(2)O molecules. It is seen that the signal level of the H(3)O(+)CO(2) adduct ion is sensitively dependent on the humidity (H(2)O concentration) of the sample to be analysed and a functional form of this dependence has been obtained. This has resulted in an appropriate extension of the SIFT-MS software and kinetics library that allows accurate measurement of CO(2) levels in air samples, ranging from very low percentage levels (0.03% typical of tropospheric air) to the 6% level that is about the upper limit in exhaled breath. Thus, the level of CO(2) can be traced through single time exhalation cycles along with that of water vapour, also close to the 6% level, and of trace gas metabolites that are present at only a few parts-per-billion. This has added a further dimension to

  15. Development of the RAQM2 aerosol chemical transport model and predictions of the Northeast Asian aerosol mass, size, chemistry, and mixing type

    NASA Astrophysics Data System (ADS)

    Kajino, M.; Inomata, Y.; Sato, K.; Ueda, H.; Han, Z.; An, J.; Katata, G.; Deushi, M.; Maki, T.; Oshima, N.; Kurokawa, J.; Ohara, T.; Takami, A.; Hatakeyama, S.

    2012-12-01

    A new aerosol chemical transport model, the Regional Air Quality Model 2 (RAQM2), was developed to simulate the Asian air quality. We implemented a simple version of a triple-moment modal aerosol dynamics model (MADMS) and achieved a completely dynamic (non-equilibrium) solution of a gas-to-particle mass transfer over a wide range of aerosol diameters from 1 nm to super-μm. To consider a variety of atmospheric aerosol properties, a category approach was utilized in which the aerosols were distributed into four categories: particles in the Aitken mode (ATK), soot-free particles in the accumulation mode (ACM), soot aggregates (AGR), and particles in the coarse mode (COR). The aerosol size distribution in each category is characterized by a single mode. The condensation, evaporation, and Brownian coagulations for each mode were solved dynamically. A regional-scale simulation (Δx = 60 km) was performed for the entire year of 2006 covering the Northeast Asian region. The modeled PM1/bulk ratios of the chemical components were consistent with observations, indicating that the simulated aerosol mixing types were consistent with those in nature. The non-sea-salt SO42- mixed with ATK + ACM was the largest at Hedo in summer, whereas the SOSO42- was substantially mixed with AGR in the cold seasons. Ninety-eight percent of the modeled NO3- was mixed with sea salt at Hedo, whereas 53.7% of the NO3- was mixed with sea salt at Gosan, which is located upwind toward the Asian continent. The condensation of HNO3 onto sea salt particles during transport over the ocean accounts for the difference in the NO3- mixing type at the two sites. Because the aerosol mixing type alters the optical properties and cloud condensation nuclei activity, its accurate prediction and evaluation are indispensable for aerosol-cloud-radiation interaction studies.

  16. Screening for multiple phosphodiesterase type 5 inhibitor drugs in dietary supplement materials by flow injection mass spectrometry and their quantification by liquid chromatography tandem mass spectrometry.

    PubMed

    Song, Fenhong; El-Demerdash, Aref; Lee, Shwn-Ji Susie H

    2012-11-01

    A flow injection tandem mass spectrometry method (FI-MS/MS) has been developed to detect enzyme phosphodiesterase type 5 inhibitors, including tadalafil, sildenafil, and vardenafil. Multiple reaction monitoring (MRM) was used to detect the drugs and product ion ratios were used for identification. FI-MS/MS was used for semi-quantification and liquid chromatography tandem mass spectrometry (LC-MS/MS) was used for further confirmation and quantification. One of 13 samples has been found to be adulterated with prescription levels of tadalafil and also low level of sildenafil. The method can be used for screening large numbers of herbal products for adulteration since it takes less than 1 min without chromatographic separation on a column.

  17. 75 FR 43092 - Airworthiness Directives; Viking Air Limited (Type Certificate Previously Held by Bombardier, Inc...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-07-23

    ... explosion. Viking Air Limited has revised Chapter 5 of the DHC-7 Maintenance Manual, PSM 1-7-2, to introduce..., and 5-113, all dated December 15, 2008, to the Viking DHC-7 Dash 7 Maintenance Manual, PSM-1-7-2... of this AD, to Chapter 5 of the Viking DHC-7 Dash 7 Maintenance Manual (MM), PSM 1- 7-2;...

  18. BVR photometric study of NSVS 2607629. A high mass-ratio W-type W UMa system

    NASA Astrophysics Data System (ADS)

    Gürol, Birol; Michel, Raul

    2017-02-01

    We present the results of our investigation of the geometrical and physical parameters of the W UMa-type binary system NSVS 2607629 based on CCD BVRc light curves and their analysis with the Wilson-Devinney code. New times of minima and light elements have been determined. We find that, as seen in eccentric systems, secondary minima do not occur at phase 0.5. According to our solution, the system is found to be a high mass-ratio W-type W UMa system. Combining our photometric solution with the emprical relation obtained for W UMa type systems by Dimitrov and Kjurkchieva (2015) we derive the masses and radii of the components of this eclipsing system as M1 = 0.44M⊙ , M2 = 0.73M⊙ , R1 = 0.57R⊙ and R2 = 0.71R⊙ . The evolutionary state of the system is also discussed.

  19. A statistical modeling approach for tumor-type identification in surgical neuropathology using tissue mass spectrometry imaging.

    PubMed

    Gholami, Behnood; Norton, Isaiah; Eberlin, Livia S; Agar, Nathalie Y R

    2013-05-01

    Current clinical practice involves classification of biopsied or resected tumor tissue based on a histopathological evaluation by a neuropathologist. In this paper, we propose a method for computer-aided histopathological evaluation using mass spectrometry imaging. Specifically, mass spectrometry imaging can be used to acquire the chemical composition of a tissue section and, hence, provides a framework to study the molecular composition of the sample while preserving the morphological features in the tissue. The proposed classification framework uses statistical modeling to identify the tumor type associated with a given sample. In addition, if the tumor type for a given tissue sample is unknown or there is a great degree of uncertainty associated with assigning the tumor type to one of the known tumor models, then the algorithm rejects the given sample without classification. Due to the modular nature of the proposed framework, new tumor models can be added without the need to retrain the algorithm on all existing tumor models.

  20. Characterization of ion processes in a GC/DMS air quality monitor by integration of the instrument to a mass spectrometer.

    PubMed

    Limero, T F; Nazarov, E G; Menlyadiev, M; Eiceman, G A

    2015-02-07

    The air quality monitor (AQM), which included a portable gas chromatograph (GC) and a detector was interfaced to a mass spectrometer (MS) by introducing flow from the GC detector to the atmospheric pressure ion source of the MS. This small GC system, with a gas recirculation loop for carrier and detector make-up gases, comprised an inlet to preconcentrate volatile organic compounds (VOCs) in air, a thermal desorber before the GC column, a differential mobility spectrometer (DMS), and another DMS as an atmospheric pressure ionization source for the MS. Return flow to the internally recirculated air system of the AQM's DMS was replenished using purified air. Although ions and unreacted neutral vapors flowed from the detector through Viton® tubing into the source of the MS, ions were not detected in the MS without the auxillary ion source, (63)Ni as in the mobility detector. The GC-DMS-MS instrument provided a 3-D measurement platform (GC, DMS, and MS analysis) to explore the gas composition inside the GC-DMS recirculation loop and provide DMS-MS measurement of the components of a complex VOC mixture with performance significantly enhanced by mass-analysis, either with mass spectral scans or with an extracted ion chromatogram. This combination of a mobility spectrometer and a mass spectrometer was possible as vapors and ions are carried together through the DMS analyzer, thereby preserving the chromatographic separation efficiency. The critical benefit of this instrument concept is that all flows in and through the thoroughly integrated GC-DMS analyzer are kept intact allowing a full measure of the ion and vapor composition in the complete system. Performance has been evaluated using a synthetic air sample and a sample of airborne vapors in a laboratory. Capabilities and performance values are described using results from AQM-MS analysis of purified air, ambient air from a research laboratory in a chemistry building, and a sample of synthetic air of known composition

  1. Solar system constraints on planetary Coriolis-type effects induced by rotation of distant masses

    SciTech Connect

    Iorio, Lorenzo

    2010-08-01

    We phenomenologically put local constraints on the rotation of distant masses by using the planets of the solar system. First, we analytically compute the orbital secular precessions induced on the motion of a test particle about a massive primary by a Coriolis-like force, treated as a small perturbation, in the case of a constant angular velocity vector Ψ directed along a generic direction in space. The semimajor axis a and the eccentricity e of the test particle do not secularly change, contrary to the inclination I, the longitude of the ascending node Ω, the longitude of the pericenter varpi and the mean anomaly M. Then, we compare our prediction for (dot varpi) with the corrections Δdot varpi to the usual perihelion precessions of the inner planets recently estimated by fitting long data sets with different versions of the EPM ephemerides. We obtain as preliminary upper bounds |Ψ{sub z}| ≤ 0.0006−0.013 arcsec cty{sup −1}, |Ψ{sub x}| ≤ 0.1−2.7 arcsec cty{sup −1}, |Ψ{sub y}| ≤ 0.3−2.3 arcsec cty{sup −1}. Interpreted in terms of models of space-time involving cosmic rotation, our results are able to yield constraints on cosmological parameters like the cosmological constant Λ and the Hubble parameter H{sub 0} not too far from their values determined with cosmological observations and, in some cases, several orders of magnitude better than the constraints usually obtained so far from space-time models not involving rotation. In the case of the rotation of the solar system throughout the Galaxy, occurring clockwise about the North Galactic Pole, our results for Ψ{sub z} are in disagreement with the expected value of it at more than 3−σ level. Modeling the Oort cloud as an Einstein-Thirring slowly rotating massive shell inducing Coriolis-type forces inside yields unphysical results for its putative rotation.

  2. Merger-driven evolution of the effective stellar initial mass function of massive early-type galaxies

    NASA Astrophysics Data System (ADS)

    Sonnenfeld, Alessandro; Nipoti, Carlo; Treu, Tommaso

    2017-02-01

    The stellar initial mass function (IMF) of early-type galaxies is the combination of the IMF of the stellar population formed in situ and that of accreted stellar populations. Using as an observable the effective IMF αIMF, defined as the ratio between the true stellar mass of a galaxy and the stellar mass inferred assuming a Salpeter IMF, we present a theoretical model for its evolution as a result of dry mergers. We use a simple dry-merger evolution model, based on cosmological N-body simulations, together with empirically motivated prescriptions for the IMF to make predictions on how the effective IMF of massive early-type galaxies changes from z = 2 to z = 0. We find that the IMF normalization of individual galaxies becomes lighter with time. At fixed velocity dispersion, αIMF is predicted to be constant with redshift. Current dynamical constraints on the evolution of the IMF are in slight tension with this prediction, even though systematic uncertainties, including the effect of radial gradients in the IMF, prevent a conclusive statement. The correlation of αIMF with stellar mass becomes shallower with time, while the correlation between αIMF and velocity dispersion is mostly preserved by dry mergers. We also find that dry mergers can mix the dependence of the IMF on stellar mass and velocity dispersion, making it challenging to infer, from z = 0 observations of global galactic properties, what is the quantity that is originally coupled with the IMF.

  3. Measurement and analysis of aerosol and black carbon in the southwestern United States and Panama and their dependence on air mass origin

    NASA Astrophysics Data System (ADS)

    Junker, C.; Sheahan, J. N.; Jennings, S. G.; O'Brien, P.; Hinds, B. D.; Martinez-Twary, E.; Hansen, A. D. A.; White, C.; Garvey, D. M.; Pinnick, R. G.

    2004-07-01

    Total aerosol mass loading, aerosol absorption, and black carbon (BC) content were determined from aerosol collected on 598 quartz fiber filters at a remote, semiarid site near Orogrande, New Mexico from December 1989 to October 1995. Aerosol mass was determined by weighing filters before and after exposure, and aerosol absorption was determined by measuring the visible light transmitted through loaded filter samples and converting these measurements to aerosol absorption. BC content was determined by measuring visible light transmitted through filter samples before and after firing and converting the absorption to BC mass, assuming a BC absorption cross section of 19 m2/g in the fiber filter medium. Two analyses were then performed on each of the logged variables: an autoregressive integrating moving average (ARIMA) analysis and a decomposition analysis using an autoregressive model to accommodate first-order autocorrelation. The two analyses reveal that BC mass has no statistically significant seasonal dependence at the 5% level of significance but only random fluctuations varying around an average annual value that has a long-term decreasing trend (from 0.16 to 0.11 μg/m3 during 1990-1995). Aerosol absorption, which is dominated by BC, also displays random fluctuations about an average value, and decreases from 1.9 Mm-1 to 1.3 Mm-1 during the same period. Unlike BC, aerosol mass at the Orogrande site displays distinctly different character. The analyses reveal a pronounced seasonal dependence, but no long-term trend for aerosol mass. The seasonal indices resulting from the autoregression analysis have a minimum in January (-0.78) and maximum in June (+0.58). The geometric mean value over the 1990-1995 period for aerosol mass is 16.0 μg/m3. Since BC aerosol at the Orogrande site is a product of long-range atmospheric transport, a back trajectory analysis of air masses was conducted. Back trajectory analyses indicate that air masses traversing high population

  4. SPITZER OBSERVATIONS OF THE {lambda} ORIONIS CLUSTER. II. DISKS AROUND SOLAR-TYPE AND LOW-MASS STARS

    SciTech Connect

    Hernandez, Jesus; Morales-Calderon, Maria; Calvet, Nuria; Hartmann, L.; Muzerolle, J.; Gutermuth, R.; Luhman, K. L.; Stauffer, J. E-mail: muzerol@stsci.ed

    2010-10-20

    We present IRAC/MIPS Spitzer Space Telescope observations of the solar-type and the low-mass stellar population of the young ({approx}5 Myr) {lambda} Orionis cluster. Combining optical and Two Micron All Sky Survey photometry, we identify 436 stars as probable members of the cluster. Given the distance (450 pc) and the age of the cluster, our sample ranges in mass from 2 M{sub sun} to objects below the substellar limit. With the addition of the Spitzer mid-infrared data, we have identified 49 stars bearing disks in the stellar cluster. Using spectral energy distribution slopes, we place objects in several classes: non-excess stars (diskless), stars with optically thick disks, stars with 'evolved disks' (with smaller excesses than optically thick disk systems), and 'transitional disk' candidates (in which the inner disk is partially or fully cleared). The disk fraction depends on the stellar mass, ranging from {approx}6% for K-type stars (R{sub C} - J < 2) to {approx}27% for stars with spectral-type M5 or later (R{sub C} - J>4). We confirm the dependence of disk fraction on stellar mass in this age range found in other studies. Regarding clustering levels, the overall fraction of disks in the {lambda} Orionis cluster is similar to those reported in other stellar groups with ages normally quoted as {approx}5 Myr.

  5. Chiral discrimination of a gemini-type surfactant with rigid spacer at the air-water interface.

    PubMed

    Shankar, B Vijai; Patnaik, Archita

    2007-10-04

    Spontaneous separation of chiral phases was observed in the monolayers of a racemate of gemini-type twin-tailed, twin-chiral amphiphiles, (2R,3R)-(+)-bis(decyloxy)succinic acid and (2S,3S)-(-)-bis(decyloxy)succinic acid. The pressure-area isotherms of the interfacial monolayers formed at the liquid-air interface, and the 2D lattice structures studied through surface probe measurements revealed that the racemate exhibits a homochiral discrimination of the enantiomers in two dimensions. An enantiomeric excess (e,e) of 20% was sufficient to break the chiral symmetry at the air-water interface for a homochiral interaction. Langmuir monolayers on ZnCl2 and CaCl2 subphases manifested chiral discrimination with Zn2+ evidencing homochiral interaction with a chelate-type complex, whereas Ca2+ resulted in a heterochiral interaction forming an ionic-type complex. For the chiral asymmetric units, oblique and rectangular unit cells of the racemic monolayer had exclusive requirements of homo- and heterochiral recognitions for Zn2+ and Ca2+ ions, respectively. Monolayers transferred from the condensed phase at 25 mN/m onto hydrophilic Si(100) and quartz substrates revealed the formation of bilayers through transfer-induced monolayer buckling. The emergence of homochiral discrimination was explained using the effective-pair-potential (EPP) approach.

  6. Performance Characteristics of a Micro Air Grinder Operated by a Two-Stages Axial-Type Turbine

    NASA Astrophysics Data System (ADS)

    Cho, Soo-Yong; Choi, Sang-Kyu

    Performance characteristics are experimentally studied with various nozzles, stators and rotors on a partially admitted small axial-type turbine, which could be applied to a driver of micro air grinders. When air tools adopt axial-type turbines as a driver, they could operate without friction and abrasion because the turbine rotor does not make contact with the casing. In order to maintain these merits on a small axial-type turbine without reducing power, performance characteristics are examined through measuring the specific output power with eight different stators and three different rotors and nozzles. The tested turbine consists of two-stages and its mean radius of flow passage is 9.2mm. The experimental results show that the output power improvement on the first stage is significant comparing with that on the second stage because partially admitted flow is fully diffused in the second stage. Meanwhile, the output power is increased to 16-22% by changing the nozzle blade angle from 60° to 70° because the first stage performance is directly affected by the flow spouted from the nozzle. These results indicate that blade angles greatly influence the performance of a micro turbine operating in partial admission. When an appropriate stator and rotor that are designed in accordance with the flow spouted from the nozzle are installed in the rotating part, the output power is increased up to 38% depending on the blade angle.

  7. 42 CFR 84.163 - Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... respirators, demand and pressure-demand classes; test requirements. 84.163 Section 84.163 Public Health PUBLIC... RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.163 Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand classes;...

  8. 42 CFR 84.163 - Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... respirators, demand and pressure-demand classes; test requirements. 84.163 Section 84.163 Public Health PUBLIC... RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.163 Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand classes;...

  9. 42 CFR 84.163 - Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... respirators, demand and pressure-demand classes; test requirements. 84.163 Section 84.163 Public Health PUBLIC... RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.163 Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand classes;...

  10. 42 CFR 84.163 - Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... respirators, demand and pressure-demand classes; test requirements. 84.163 Section 84.163 Public Health PUBLIC... RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.163 Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand classes;...

  11. 42 CFR 84.163 - Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... respirators, demand and pressure-demand classes; test requirements. 84.163 Section 84.163 Public Health PUBLIC... RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.163 Man test for gases and vapors; Type C supplied-air respirators, demand and pressure-demand classes;...

  12. LOSS Revisited. II. The Relative Rates of Different Types of Supernovae Vary between Low- and High-mass Galaxies

    NASA Astrophysics Data System (ADS)

    Graur, Or; Bianco, Federica B.; Modjaz, Maryam; Shivvers, Isaac; Filippenko, Alexei V.; Li, Weidong; Smith, Nathan

    2017-03-01

    In Paper I of this series, we showed that the ratio between stripped-envelope (SE) supernova (SN) and Type II SN rates reveals a significant SE SN deficiency in galaxies with stellar masses ≲ {10}10 {M}ȯ . Here, we test this result by splitting the volume-limited subsample of the Lick Observatory Supernova Search (LOSS) SN sample into low- and high-mass galaxies and comparing the relative rates of various SN types found in them. The LOSS volume-limited sample contains 180 SNe and SN impostors and is complete for SNe Ia out to 80 Mpc and core-collapse SNe out to 60 Mpc. All of these transients were recently reclassified by us in Shivvers et al. We find that the relative rates of some types of SNe differ between low- and high-mass galaxies: SNe Ib and Ic are underrepresented by a factor of ∼3 in low-mass galaxies. These galaxies also contain the only examples of SN 1987A-like SNe in the sample and host about nine times as many SN impostors. Normal SNe Ia seem to be ∼30% more common in low-mass galaxies, making these galaxies better sources for homogeneous SN Ia cosmology samples. The relative rates of SNe IIb are consistent in both low- and high-mass galaxies. The same is true for broad-line SNe Ic, although our sample includes only two such objects. The results presented here are in tension with a similar analysis from the Palomar Transient Factory, especially as regards SNe IIb.

  13. A solar type II radio burst from coronal mass ejection-coronal ray interaction: Simultaneous radio and extreme ultraviolet imaging

    SciTech Connect

    Chen, Yao; Du, Guohui; Feng, Shiwei; Kong, Xiangliang; Wang, Bing; Feng, Li; Guo, Fan; Li, Gang

    2014-05-20

    Simultaneous radio and extreme ultraviolet (EUV)/white-light imaging data are examined for a solar type II radio burst occurring on 2010 March 18 to deduce its source location. Using a bow-shock model, we reconstruct the three-dimensional EUV wave front (presumably the type-II-emitting shock) based on the imaging data of the two Solar TErrestrial RElations Observatory spacecraft. It is then combined with the Nançay radio imaging data to infer the three-dimensional position of the type II source. It is found that the type II source coincides with the interface between the coronal mass ejection (CME) EUV wave front and a nearby coronal ray structure, providing evidence that the type II emission is physically related to the CME-ray interaction. This result, consistent with those of previous studies, is based on simultaneous radio and EUV imaging data for the first time.

  14. Interlaboratory evaluation of trace element determination in workplace air filter samples by inductively coupled plasma mass spectrometry†‡

    PubMed Central

    Shulman, Stanley A.; Brisson, Michael J.; Howe, Alan M.

    2015-01-01

    Inductively coupled plasma mass spectrometry (ICP-MS) is becoming more widely used for trace elemental analysis in the occupational hygiene field, and consequently new ICP-MS international standard procedures have been promulgated by ASTM International and ISO. However, there is a dearth of interlaboratory performance data for this analytical methodology. In an effort to fill this data void, an interlaboratory evaluation of ICP-MS for determining trace elements in workplace air samples was conducted, towards fulfillment of method validation requirements for international voluntary consensus standard test methods. The study was performed in accordance with applicable statistical procedures for investigating interlaboratory precision. The evaluation was carried out using certified 37-mm diameter mixed-cellulose ester (MCE) filters that were fortified with 21 elements of concern in occupational hygiene. Elements were spiked at levels ranging from 0.025 to 10 μg filter−1, with three different filter loadings denoted “Low”, “Medium” and “High”. Participating laboratories were recruited from a pool of over fifty invitees; ultimately twenty laboratories from Europe, North America and Asia submitted results. Triplicates of each certified filter with elemental contents at three different levels, plus media blanks spiked with reagent, were conveyed to each volunteer laboratory. Each participant was also provided a copy of the test method which each participant was asked to follow; spiking levels were unknown to the participants. The laboratories were requested to prepare the filters by one of three sample preparation procedures, i.e., hotplate digestion, microwave digestion or hot block extraction, which were described in the test method. Participants were then asked to analyze aliquots of the prepared samples by ICP-MS, and to report their data in units of μg filter−1. Most interlaboratory precision estimates were acceptable for medium- and high

  15. Retrieval of vertical columns of sulfur dioxide from SCIAMACHY and OMI: Air mass factor algorithm development, validation, and error analysis

    NASA Astrophysics Data System (ADS)

    Lee, Chulkyu; Martin, Randall V.; van Donkelaar, Aaron; O'Byrne, Gray; Krotkov, Nickolay; Richter, Andreas; Huey, L. Gregory; Holloway, John S.

    2009-11-01

    We develop an improved retrieval of sulfur dioxide (SO2) vertical columns from two satellite instruments (SCIAMACHY and OMI) that measure ultraviolet solar backscatter. For each SCIAMACHY and OMI observation, a local air mass factor (AMF) algorithm converts line-of-sight "slant" columns to vertical columns using altitude-dependent scattering weights computed with a radiative transfer model (LIDORT), weighted by relative vertical SO2 profile (shape factor) determined locally with a global atmospheric chemistry model (GEOS-Chem). The scattering weights account for viewing geometry, surface albedo, cloud scattering, absorption by ozone, and scattering and absorption by aerosols. Absorption of radiation by mineral dust can reduce seasonal mean instrument sensitivity by 50%. Mean SO2 shape factors simulated with GEOS-Chem and used in the AMF calculation are highly consistent with airborne in situ measurements (INTEX-A and INTEX-B); differences would affect the retrieved SO2 columns by 10%. The retrieved vertical columns are validated with coincident airborne in situ measurements (INTEX-A, INTEX-B, and a campaign over east China). The annual mean AMF errors are estimated to be 35-70% in polluted regions (e.g., East Asia and the eastern United States) and less than 10% over clear ocean regions. The overall SO2 error assessment is 45-80% for yearly averages over polluted regions. Seasonal mean SO2 columns retrieved from SCIAMACHY and OMI for 2006 are significantly spatially correlated with those from GEOS-Chem, in particular over the United States (r = 0.85 for SCIAMACHY and 0.82 for OMI). A sensitivity study confirms the sensitivity of SCIAMACHY and OMI to anthropogenic SO2 emissions.

  16. sup 222 Rn, sup 222 Rn progeny and sup 220 Rn progeny as atmospheric tracers of air masses at the Mauno Loa Observatory

    SciTech Connect

    Hutter, A.R.; George, A.C.; Maiello, M.L.; Fisenne, I.M.; Larsen, R.J.; Beck, H.L.; Wilson, F.C.

    1990-03-01

    {sup 222}Rn, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations in air were measured at the Mauna Loa Observatory (MLO) in Hawaii during March 1989 in order to investigate the feasibility of using them as atmospheric tracers to help determine local air mass flow patterns. Charcoal traps, cooled to dry ice temperatures, were used to collect {sup 222}Rn, which was subsequently measured in pulse ionization chambers at the Environmental Measurements Laboratory (EML). {sup 222}Rn progeny and {sup 220}Rn progeny for 37 samples were measured at the Observatory by sampling high volumes of air through filters, which were counted for up to 11 h in alpha scintillation counters. Individual progeny concentrations were calculated using both least squares and maximum likelihood techniques. In general, {sup 222}Rn progeny and {sup 220}Rn progeny concentrations were low when free tropospheric air was present (downslope and tradewind conditions), and consistently higher when surface air from the island broke through the trade wind inversion layer (upslope conditions). The data suggest that {sup 222}Rn, {sup 222}Rn progeny, or {sup 220}Rn progeny monitoring may provide new and useful information to help indicate the different air flow patterns present at MLO. 17 refs., 5 figs., 2 tabs.

  17. Mobile selected ion flow tube mass spectrometry (SIFT-MS) devices and their use for pollution exposure monitoring in breath and ambient air-pilot study.

    PubMed

    Storer, Malina; Salmond, Jennifer; Dirks, Kim N; Kingham, Simon; Epton, Michael

    2014-09-01

    Studies of health effects of air pollution exposure are limited by inability to accurately determine dose and exposure of air pollution in field trials. We explored the feasibility of using a mobile selected ion flow tube mass spectrometry (SIFT-MS) device, housed in a van, to determine ambient air and breath levels of benzene, xylene and toluene following exercise in areas of high motor vehicle traffic. The breath toluene, xylene and benzene concentration of healthy subjects were measured before and after exercising close to a busy road. The concentration of the volatile organic compounds (VOCs), in ambient air were also analysed in real time. Exercise close to traffic pollution is associated with a two-fold increase in breath VOCs (benzene, xylene and toluene) with levels returning to baseline within 20 min. This effect is not seen when exercising away from traffic pollution sources. Situating the testing device 50 m from the road reduced any confounding due to VOCs in the inspired air prior to the breath testing manoeuvre itself. Real-time field testing for air pollution exposure is possible using a mobile SIFT-MS device. This device is suitable for exploring exposure and dose relationships in a number of large scale field test scenarios.

  18. Characteristics of particle number and mass emissions during heavy-duty diesel truck parked active DPF regeneration in an ambient air dilution tunnel

    NASA Astrophysics Data System (ADS)

    Yoon, Seungju; Quiros, David C.; Dwyer, Harry A.; Collins, John F.; Burnitzki, Mark; Chernich, Donald; Herner, Jorn D.

    2015-12-01

    Diesel particle number and mass emissions were measured during parked active regeneration of diesel particulate filters (DPF) in two heavy-duty diesel trucks: one equipped with a DPF and one equipped with a DPF + SCR (selective catalytic reduction), and compliant with the 2007 and 2010 emission standards, respectively. The emission measurements were conducted using an ambient air dilution tunnel. During parked active regeneration, particulate matter (PM) mass emissions measured from a 2007 technology truck were significantly higher than the emissions from a 2010 technology truck. Particle number emissions from both trucks were dominated by nucleation mode particles having a diameter less than 50 nm; nucleation mode particles were orders of magnitude higher than accumulation mode particles having a diameter greater than 50 nm. Accumulation mode particles contributed 77.8 %-95.8 % of the 2007 truck PM mass, but only 7.3 %-28.2 % of the 2010 truck PM mass.

  19. The Effects of Highlighting, Validity, and Feature Type on Air-to-Ground Target Acquisition Performance.

    DTIC Science & Technology

    2007-11-02

    cultura I taget Target type Validity X target X leadin interaction on initial response time (highlighted trials) WRONG HIGHLIGHTING ÖU - M ea...natural - leadin cultural ndurd cultura taget I taget Target type Figure 3.10: Validity X lead-in X Target interaction Confirmation time A

  20. Survey and Experimental Testing of Nongravimetric Mass Measurement Devices

    NASA Technical Reports Server (NTRS)

    Oakey, W. E.; Lorenz, R.

    1977-01-01

    Documentation presented describes the design, testing, and evaluation of an accelerated gravimetric balance, a low mass air bearing oscillator of the spring-mass type, and a centrifugal device for liquid mass measurement. A direct mass readout method was developed to replace the oscillation period readout method which required manual calculations to determine mass. A protoype 25 gram capacity micro mass measurement device was developed and tested.

  1. VOCs Emissions from Multiple Wood Pellet Types and Concentrations in Indoor Air

    PubMed Central

    Soto-Garcia, Lydia; Ashley, William J.; Bregg, Sandar; Walier, Drew; LeBouf, Ryan; Hopke, Philip K.; Rossner, Alan

    2016-01-01

    Wood pellet storage safety is an important aspect for implementing woody biomass as a renewable energy source. When wood pellets are stored indoors in large quantities (tons) in poorly ventilated spaces in buildings, such as in basements, off-gassing of volatile organic compounds (VOCs) can significantly affect indoor air quality. To determine the emission rates and potential impact of VOC emissions, a series of laboratory and field measurements were conducted using softwood, hardwood, and blended wood pellets manufactured in New York. Evacuated canisters were used to collect air samples from the headspace of drums containing pellets and then in basements and pellet storage areas of homes and small businesses. Multiple peaks were identified during GC/MS and GC/FID analysis, and four primary VOCs were characterized and quantified: methanol, pentane, pentanal, and hexanal. Laboratory results show that total VOCs (TVOCs) concentrations for softwood (SW) were statistically (p < 0.02) higher than blended or hardwood (HW) (SW: 412 ± 25; blended: 203 ± 4; HW: 99 ± 8, ppb). The emission rate from HW was the fastest, followed by blended and SW, respectively. Emissions rates were found to range from 10−1 to 10−5 units, depending upon environmental factors. Field measurements resulted in airborne concentrations ranging from 67 ± 8 to 5000 ± 3000 ppb of TVOCs and 12 to 1500 ppb of aldehydes, with higher concentrations found in a basement with a large fabric bag storage unit after fresh pellet delivery and lower concentrations for aged pellets. These results suggest that large fabric bag storage units resulted in a substantial release of VOCs into the building air. Occupants of the buildings tested discussed concerns about odor and sensory irritation when new pellets were delivered. The sensory response was likely due to the aldehydes. PMID:27022205

  2. COSMIC EVOLUTION OF VIRIAL AND STELLAR MASS IN MASSIVE EARLY-TYPE GALAXIES

    SciTech Connect

    Lagattuta, David J.; Fassnacht, Christopher D.; Auger, Matthew W.; Marshall, Philip J.; Bradac, Marusa; Treu, Tommaso; Gavazzi, Raphael; Schrabback, Tim; Faure, Cecile; Anguita, Timo

    2010-06-20

    We measure the average mass properties of a sample of 41 strong gravitational lenses at moderate redshift (z {approx} 0.4-0.9) and present the lens redshift for six of these galaxies for the first time. Using the techniques of strong and weak gravitational lensing on archival data obtained from the Hubble Space Telescope, we determine that the average mass overdensity profile of the lenses can be fit with a power-law profile ({Delta}{Sigma} {proportional_to} R {sup -0.86{+-}0.16}) that is within 1{sigma} of an isothermal profile ({Delta}{Sigma} {proportional_to} R {sup -1}) with velocity dispersion {sigma}{sub v} = 260 {+-} 20 km s{sup -1}. Additionally, we use a two-component de Vaucouleurs + Navarro-Frenk-White (NFW) model to disentangle the total mass profile into separate luminous and dark matter components and determine the relative fraction of each component. We measure the average rest frame V-band stellar mass-to-light ratio (Y{sub V} = 4.0 {+-} 0.6 h M{sub sun}/L{sub sun}) and virial mass-to-light ratio ({tau}{sub V} = 300 {+-} 90 h M{sub sun}/L{sub sun}) for our sample, resulting in a virial-to-stellar mass ratio of M{sub vir}/M{sub *} = 75 {+-} 25. Relaxing the NFW assumption, we estimate that changing the inner slope of the dark matter profile by {approx}20% yields a {approx}30% change in stellar mass-to-light ratio. Finally, we compare our results to a previous study using low-redshift lenses to understand how galaxy mass profiles evolve over time. We investigate the evolution of M{sub vir}/M{sub *}(z) = {alpha}(1 + z){sup {beta}}, and find best-fit parameters of {alpha} = 51 {+-} 36 and {beta} = 0.9 {+-} 1.8, constraining the growth of virial-to-stellar mass ratio over the last {approx}7 Gyr. We note that, by using a sample of strong lenses, we are able to constrain the growth of M{sub vir}/M{sub *}(z) without making any assumptions about the initial mass function of the stellar population.

  3. Air backed mandrel type fiber optic hydrophone with low noise floor

    NASA Astrophysics Data System (ADS)

    Rajesh, R.; V, Sreehari C.; N, Praveen Kumar; Awasthi, R. L.; K, Vivek; B, Vishnu M.; Santhanakrishnan, T.; Moosad, K. P. B.; Mathew, Basil

    2014-10-01

    Low noise fiber optic hydrophone based on optical fiber coil wound on air-backed mandrel was developed. The sensor can be effectively used for underwater acoustic sensing. The design and characterization of the hydrophone is illustrated in this paper. A fiber Mach-Zehnder Interferometer (MZI) was developed and coupled with a Distributed Feedback (DFB) fiber laser source and an optical phase demodulation system, with an active modulation in one of the arms. The sensor head design was optimized to achieve noise spectral density <10 μrad/√Hz, for yielding sufficient sensitivity to sense acoustic pressure close to Deep Sea Sate Zero (DSS0).

  4. Formation of H-type liquid crystal dimer at air-water interface

    SciTech Connect

    Karthik, C. Gupta, Adbhut Joshi, Aditya Manjuladevi, V. Gupta, Raj Kumar; Varia, Mahesh C.; Kumar, Sandeep

    2014-04-24

    We have formed the Langmuir monolayer of H-shaped Azo linked liquid crystal dimer molecule at the air-water interface. Isocycles of the molecule showed hysteresis suggesting the ir-reversible nature of the monolayer formed. The thin film deposited on the silicon wafer was characterized using Atomic Force Microscopy (AFM) and Field Emission Scanning Electron Microscopy (FESEM). The images showed uniform domains of the dimer molecule. We propose that these molecules tend to take book shelf configuration in the liquid phase.

  5. Effects of chromium brewer's yeast supplementation on body mass, blood carbohydrates, and lipids and minerals in type 2 diabetic patients.

    PubMed

    Król, Ewelina; Krejpcio, Zbigniew; Byks, Hanna; Bogdański, Paweł; Pupek-Musialik, Danuta

    2011-11-01

    Chromium(III) is considered as an essential element for carbohydrate and lipid metabolism. The aim of this clinical study was to evaluate the efficacy of Cr brewer's yeast supplementation on body mass, carbohydrate, lipids and mineral indices in type 2 diabetic patients. Twenty adult type 2 diabetic subjects (11 males and 9 females aged 37-63) were supplemented with Cr brewer's yeast in dosages of 500 μg Cr/person/day or placebo for 8 weeks in a double-blind, placebo-controlled crossover design. It was found that supplemental Cr did not affect body mass, blood lipid profile, resistin levels, and the serum and hair Zn, Fe, and Cu levels, but increased serum Cr (by 116%) and hair Cr (by 20.6%) concentrations and improved some blood carbohydrate indices (significant increase in the β cell function index by 18.8%) in type 2 diabetic patients. In conclusion, Cr brewer's yeast has a weak hypoglycemic potential, but does not affect body mass, blood biochemical profile, and microelement levels in type 2 diabetic subjects.

  6. Mass Conservation and Positivity Preservation with Ensemble-type Kalman Filter Algorithms

    NASA Technical Reports Server (NTRS)

    Janjic, Tijana; McLaughlin, Dennis B.; Cohn, Stephen E.; Verlaan, Martin

    2013-01-01

    Maintaining conservative physical laws numerically has long been recognized as being important in the development of numerical weather prediction (NWP) models. In the broader context of data assimilation, concerted efforts to maintain conservation laws numerically and to understand the significance of doing so have begun only recently. In order to enforce physically based conservation laws of total mass and positivity in the ensemble Kalman filter, we incorporate constraints to ensure that the filter ensemble members and the ensemble mean conserve mass and remain nonnegative through measurement updates. We show that the analysis steps of ensemble transform Kalman filter (ETKF) algorithm and ensemble Kalman filter algorithm (EnKF) can conserve the mass integral, but do not preserve positivity. Further, if localization is applied or if negative values are simply set to zero, then the total mass is not conserved either. In order to ensure mass conservation, a projection matrix that corrects for localization effects is constructed. In order to maintain both mass conservation and positivity preservation through the analysis step, we construct a data assimilation algorithms based on quadratic programming and ensemble Kalman filtering. Mass and positivity are both preserved by formulating the filter update as a set of quadratic programming problems that incorporate constraints. Some simple numerical experiments indicate that this approach can have a significant positive impact on the posterior ensemble distribution, giving results that are more physically plausible both for individual ensemble members and for the ensemble mean. The results show clear improvements in both analyses and forecasts, particularly in the presence of localized features. Behavior of the algorithm is also tested in presence of model error.

  7. A study on lithium/air secondary batteries-Stability of NASICON-type glass ceramics in acid solutions

    NASA Astrophysics Data System (ADS)

    Shimonishi, Y.; Zhang, T.; Johnson, P.; Imanishi, N.; Hirano, A.; Takeda, Y.; Yamamoto, O.; Sammes, N.

    The stability of a NASICON-type lithium ion conducting solid electrolyte, Li 1+ x+ yTi 2- xAl xP 3- ySi yO 12 (LTAP), in acetic acid and formic acid solutions was examined. XRD patterns of the LTAP powders immersed in 100% acetic acid and formic acid at 50 °C for 4 months showed no change as compared to the pristine LTAP. However, the electrical conductivity of LTAP drastically decreased. On the other hand, no significant electrical conductivity change of LTAP immersed in lithium formate saturated formic acid-water solution was observed, and the electrical conductivity of LTAP immersed in lithium acetate saturated acetic acid-water increased. Cyclic voltammogram tests suggested that acetic acid was stable up to a high potential, but formic acid decomposed under the decomposition potential of water. The acetic acid solution was considered to be a candidate for the active material in the air electrode of lithium-air rechargeable batteries. The cell reaction was considered as 2Li + 2 CH 3COOH + 1/2O 2 = 2CH 3COOLi + H 2O. The energy density of this lithium-air system is calculated to be 1477 Wh kg -1 from the weights of Li and CH 3COOH, and an observed open-circuit voltage of 3.69 V.

  8. The Fort Collins Commuter Study: Impact of route type and transport mode on personal exposure to multiple air pollutants

    PubMed Central

    Good, Nicholas; Mölter, Anna; Ackerson, Charis; Bachand, Annette; Carpenter, Taylor; Clark, Maggie L; Fedak, Kristen M; Kayne, Ashleigh; Koehler, Kirsten; Moore, Brianna; L'Orange, Christian; Quinn, Casey; Ugave, Viney; Stuart, Amy L; Peel, Jennifer L; Volckens, John

    2016-01-01

    Traffic-related air pollution is associated with increased mortality and morbidity, yet few studies have examined strategies to reduce individual exposure while commuting. The present study aimed to quantify how choice of mode and route type affects personal exposure to air pollutants during commuting. We analyzed within-person difference in exposures to multiple air pollutants (black carbon (BC), carbon monoxide (CO), ultrafine particle number concentration (PNC), and fine particulate matter (PM2.5)) during commutes between the home and workplace for 45 participants. Participants completed 8 days of commuting by car and bicycle on direct and alternative (reduced traffic) routes. Mean within-person exposures to BC, PM2.5, and PNC were higher when commuting by cycling than when driving, but mean CO exposure was lower when cycling. Exposures to CO and BC were reduced when commuting along alternative routes. When cumulative exposure was considered, the benefits from cycling were attenuated, in the case of CO, or exacerbated, in the case of particulate exposures, owing to the increased duration of the commute. Although choice of route can reduce mean exposure, the effect of route length and duration often offsets these reductions when cumulative exposure is considered. Furthermore, increased ventilation rate when cycling may result in a more harmful dose than inhalation at a lower ventilation rate. PMID:26507004

  9. Lipopolysaccharide-Activated Leukocytes Enhance Thymic Stromal Lymphopoietin Production in a Mouse Air-Pouch-Type Inflammation Model.

    PubMed

    Segawa, Ryosuke; Mizuno, Natsumi; Hatayama, Takahiro; Jiangxu, Dong; Hiratsuka, Masahiro; Endo, Yasuo; Hirasawa, Noriyasu

    2016-08-01

    Thymic stromal lymphopoietin (TSLP) is a key cytokine that exacerbates allergic and fibrotic reactions. Several microbes and virus components have been shown to induce TSLP production, mainly in epithelial cells. TLR4 activators, such as lipopolysaccharide (LPS), induce TSLP production in vivo, although the underlying mechanisms remain unclear. In this study, we investigated the contribution of LPS-activated leukocytes to the production of TSLP in a mouse air-pouch-type inflammation model. LPS induced the production of TSLP in this model but not in the mouse keratinocyte cell line PAM212. Transfer of the infiltrated leukocytes collected from an LPS-injected air pouch to the air pouch of another mouse enhanced TSLP production. Further, the LPS-activated leukocytes produced tumor necrosis factor alpha (TNF-α) and interleukin-1 beta (IL-1β); a deficiency in these cytokines attenuated the LPS-induced production of TSLP. TSLP production was induced by TNF-α and enhanced by IL-1β and LPS in the PAM212 cells. These results demonstrated that TNF-α and IL-1β, which are partly produced by LPS-activated leukocytes, contribute to TSLP production via TLR4 activation in vivo.

  10. Modeling of Camembert-type cheese mass loss in a ripening chamber: main biological and physical phenomena.

    PubMed

    Hélias, A; Mirade, P-S; Corrieu, G

    2007-11-01

    A model of the mass loss of Camembert-type cheese was established with data obtained from 2 experimental ripening trials carried out in 2 pilot ripening chambers. During these experiments, a cheese was continuously weighed and the relative humidity, temperature, oxygen, and carbon dioxide concentrations in the ripening chamber were recorded online. The aim was to establish a simple but accurate model that would predict cheese mass changes according to available online measurements. The main hypotheses were that 1) the cheese water activity was constant during ripening, 2) the respiratory activity of the microflora played a major role by inducing heat production, combined with important water evaporation, 3) the temperature gradient existing inside the cheese was negligible, and the limiting phenomenon was the convective transfer. The water activity and the specific heat of the cheeses were assessed by offline measurements. The others parameters in the model were obtained from the literature. This dynamic model was built with 2 state variables: the cheese mass and the surface temperature of the cheese. In this way, only the heat transfer coefficient had to be fitted, and it was strongly determined by the airflow characteristics close to the cheeses. Model efficiency was illustrated by comparing the estimated and measured mass and the mass loss rate for the 2 studied runs; the relative errors were less than 1.9 and 3.2% for the mass loss and the mass loss rate, respectively. The dynamic effects of special events, such as room defrosting or changes in chamber relative humidity, were well described by the model, especially in terms of kinetics (mass loss rates).

  11. Characterizing the chemical evolution of air masses via multi-platform measurements of volatile organic compounds (VOCs) during CalNEX: Composition, OH reactivity, and potential SOA formation

    NASA Astrophysics Data System (ADS)

    Gilman, J. B.; Kuster, W. C.; Bon, D.; Warneke, C.; Lerner, B. M.; Williams, E. J.; Holloway, J. S.; Pollack, I. B.; Ryerson, T. B.; Atlas, E. L.; Blake, D. R.; Herndon, S. C.; Zahniser, M. S.; Vlasenko, A. L.; Li, S.; Alvarez, S. L.; Rappenglueck, B.; Flynn, J. H.; Grossberg, N.; Lefer, B. L.; De Gouw, J. A.

    2011-12-01

    Volatile organic compounds (VOCs) are critical components in the photochemical production of ozone (O3) and secondary organic aerosol (SOA). During the CalNex 2010 field campaign, an extensive set of VOCs were measured at the Pasadena ground site, and aboard the NOAA WP-3D aircraft and the WHOI Research Vessel Atlantis. The measurements from each platform provide a unique perspective into the emissions, transport, and atmospheric processing of VOCs within the South Coast Air Basin (SoCAB). The observed enhancement ratios of the hydrocarbons measured on all three platforms are in good agreement and are generally well correlated with carbon monoxide (CO), indicating the prevalence of on-road VOC emission sources throughout the SoCAB. Offshore measurements aboard the ship and aircraft are used to characterize the air mass composition as a function of the land/sea-breeze effect. VOC ratios and other trace gases are used to identify air masses containing relatively fresh emissions that were often associated with offshore flow and re-circulated continental air associated with onshore flow conditions. With the prevailing southwesterly airflow pattern in the LAB throughout the daytime, the Pasadena ground site effectively functions as a receptor site and is used to characterize primary VOC emissions from downtown Los Angeles and to identify the corresponding secondary oxidation products. The chemical evolution of air masses as a function of the time of day is investigated in order to determine the relative impacts of primary emissions vs. secondary VOC products on OH reactivity and potential SOA formation. The reactivity of VOCs with the hydroxyl radical (OH) at the Pasadena site was dominated by the light hydrocarbons, isoprene, and oxygenated VOCs including aldehydes (secondary products) and alcohols (primary anthropogenic emissions). Toluene and benzaldehyde, both of which are associated with primary anthropogenic emissions, are the predominant VOC precursors to the

  12. Characterization of noncovalent complexes of antimalarial agents of the artemisinin-type and FE(III)-heme by electrospray mass spectrometry and collisional activation tandem mass spectrometry.

    PubMed

    Pashynska, Vlada A; Van den Heuvel, Hilde; Claeys, Magda; Kosevich, Marina V

    2004-08-01

    In this study, we demonstrate, using electrospray ionization mass spectrometry (ESI-MS) and collision-induced dissociation tandem mass spectrometry (ESI-MS/CID/MS), that stable noncovalent complexes can be formed between Fe(III)-heme and antimalarial agents, i.e., quinine, artemisinin, and the artemisinin derivatives, dihydroartemisinin, alpha- and beta-artemether, and beta-arteether. Differences in the binding behavior of the examined drugs with Fe(III)-heme and the stability of the drug-heme complexes are demonstrated. The results show that all tested antimalarial agents form a drug-heme complex with a 1:1 stoichiometry but that quinine also results in a second complex with the heme dimer. ESI-MS performed on mixtures of pairs of various antimalarial agents with heme indicate that quinine binds preferentially to Fe(III)-heme, while ESI-MS/CID/MS shows that the quinine-heme complex is nearly two times more stable than the complexes formed between heme and artemisinin or its derivatives. Moreover, it is found that dihydroartemisinin, the active metabolite of the artemisinin-type drugs in vivo, results in a Na(+)-containing heme-drug complex, which is as stable as the heme-quinine complex. The efficiency of drug-heme binding of artemisinin derivatives is generally lower and the decomposition under CID higher compared with quinine, but these parameters are within the same order of magnitude. These results suggest that the efficiency of antimalarial agents of the artemisinin-type to form noncovalent complexes with Fe(III)-heme is comparable with that of the traditional antimalarial agent, quinine. Our study illustrates that electrospray ionization mass spectrometry and collision-induced dissociation tandem mass spectrometry are suitable tools to probe noncovalent interactions between heme and antimalarial agents. The results obtained provide insights into the underlying molecular modes of action of the traditional antimalarial agent quinine and of the antimalarials of

  13. Measurement of the mass energy-absorption coefficient of air for x-rays in the range from 3 to 60 keV.

    PubMed

    Buhr, H; Büermann, L; Gerlach, M; Krumrey, M; Rabus, H

    2012-12-21

    For the first time the absolute photon mass energy-absorption coefficient of air in the energy range of 10 to 60 keV has been measured with relative standard uncertainties below 1%, considerably smaller than those of up to 2% assumed for calculated data. For monochromatized synchrotron radiation from the electron storage ring BESSY II both the radiant power and the fraction of power deposited in dry air were measured using a cryogenic electrical substitution radiometer and a free air ionization chamber, respectively. The measured absorption coefficients were compared with state-of-the art calculations and showed an average deviation of 2% from calculations by Seltzer. However, they agree within 1% with data calculated earlier by Hubbell. In the course of this work, an improvement of the data analysis of a previous experimental determination of the mass energy-absorption coefficient of air in the range of 3 to 10 keV was found to be possible and corrected values of this preceding study are given.

  14. Who should take responsibility for decisions on internationally recommended datasets? The case of the mass concentration of mercury in air at saturation

    NASA Astrophysics Data System (ADS)

    Brown, Richard J. C.; Brewer, Paul J.; Ent, Hugo; Fisicaro, Paola; Horvat, Milena; Kim, Ki-Hyun; Quétel, Christophe R.

    2015-10-01

    This paper considers how decisions on internationally recommended datasets are made and implemented and, further, how the ownership of these decisions comes about. Examples are given of conventionally agreed data and values where the responsibility is clear and comes about through official designation or by common usage and practice over long time periods. The example of the dataset describing the mass concentration of mercury in air at saturation is discussed in detail. This is a case where there are now several competing datasets that are in disagreement with each other, some with historical authority and some more recent but, arguably, with more robust metrological traceability to the SI. Further, it is elaborated that there is no body charged with the responsibility to make a decision on an international recommendation for such a dataset. This has led to the situation where several competing datasets are in use simultaneously. Close parallels are drawn with the current debate over changes to the ozone absorption cross section, which has equal importance to the measurement of ozone amount fraction in air and to subsequent compliance with air quality legislation. It is noted that in the case of the ozone cross section there is already a committee appointed to deliberate over any change. We make the proposal that a similar committee, under the auspices of IUPAC or the CIPM’s CCQM (if it adopted a reference data function) could be formed to perform a similar role for the mass concentration of mercury in air at saturation.

  15. SDSS-IV MaNGA: Variation of the Stellar Initial Mass Function in Spiral and Early-type Galaxies

    NASA Astrophysics Data System (ADS)

    Li, Hongyu; Ge, Junqiang; Mao, Shude; Cappellari, Michele; Long, R. J.; Li, Ran; Emsellem, Eric; Dutton, Aaron A.; Li, Cheng; Bundy, Kevin; Thomas, Daniel; Drory, Niv; Lopes, Alexandre Roman

    2017-04-01

    We perform Jeans anisotropic modeling (JAM) on elliptical and spiral galaxies from the MaNGA DR13 sample. By comparing the stellar mass-to-light ratios estimated from stellar population synthesis and from JAM, we find a systematic variation of the initial mass function (IMF) similar to that in the earlier {{ATLAS}}3{{D}} results. Early-type galaxies (elliptical and lenticular) with lower velocity dispersions within one effective radius are consistent with a Chabrier-like IMF, while galaxies with higher velocity dispersions are consistent with a more bottom-heavy IMF such as the Salpeter IMF. Spiral galaxies have similar systematic IMF variations, but with slightly different slopes and larger scatters, due to the uncertainties caused by the higher gas fractions and extinctions for these galaxies. Furthermore, we examine the effects of stellar mass-to-light ratio gradients on our JAM modeling, and we find that the trends become stronger after considering the gradients.

  16. AN EMPIRICAL CONNECTION BETWEEN THE ULTRAVIOLET COLOR OF EARLY-TYPE GALAXIES AND THE STELLAR INITIAL MASS FUNCTION

    SciTech Connect

    Zaritsky, Dennis; Gil de Paz, Armando; Bouquin, Alexandre Y. K.

    2014-01-01

    Using new UV magnitudes for a sample of early-type galaxies (ETGs) with published stellar mass-to-light ratios, Y{sub *}, we find a correlation between UV color and Y{sub *} that is tighter than those previously identified between Y{sub *} and either the central stellar velocity dispersion, metallicity, or alpha enhancement. The sense of the correlation is that galaxies with larger Y{sub *} are bluer in the UV. We conjecture that differences in the lower mass end of the stellar initial mass function (IMF) are related to the nature of the extreme horizontal branch populations that are generally responsible for the UV flux in ETGs. If so, then UV color can be used to identify ETGs with particular IMF properties and to estimate Y{sub *}.