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Sample records for air mass variability

  1. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    NASA Astrophysics Data System (ADS)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  2. Brief Communication: Upper-air relaxation in RACMO2 significantly improves modelled interannual surface mass balance variability in Antarctica

    NASA Astrophysics Data System (ADS)

    van de Berg, Willem Jan; Medley, Brooke

    2016-03-01

    The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in contrast to ERA-Interim, which resolves this variability well. In an attempt to remedy RACMO2 performance, we included additional upper-air relaxation (UAR) in RACMO2. With UAR, the correlation to observations is similar for RACMO2 and ERA-Interim. The spatial SMB patterns and ice-sheet-integrated SMB modelled using UAR remain very similar to the estimates of RACMO2 without UAR. We only observe an upstream smoothing of precipitation in regions with very steep topography like the Antarctic Peninsula. We conclude that UAR is a useful improvement for regional climate model simulations, although results in regions with steep topography should be treated with care.

  3. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  4. Atmospheric Thickness Variability During Air Mass Conditions and Winter Snow Events at Albany, NY: 2002-2012

    NASA Astrophysics Data System (ADS)

    Dubbs, A. M.; Swift, S.; Godek, M. L.

    2014-12-01

    A winter weather parameter that is underutilized in the prediction of Northeast snowfall events is critical thickness. Knowledge of atmospheric thickness values during snowfall can benefit the accuracy of winter forecasts, especially if thickness layer ranges at times without precipitation are known. This investigation aims to better understand atmospheric thickness variations in the 1000-500, 1000-700, and 1000-850 hPa layers at Albany, New York during snowfall with differing air mass conditions. Since snow can occur alongside a variety of air mass environments, distinctions in layer thickness between air mass types and critical levels will be examined. Pairing air mass information with an improved understanding of thicknesses may allow forecasters to determine normal snowfall conditions of the atmosphere and decipher when anomalous conditions are occurring alongside heavier snows. Daily geopotential height data are examined alongside Spatial Synoptic Classification weather types over the past decade. Air mass frequencies are computed and baseline thicknesses are established for non-snow days, days with snow and liquid precipitation, and days with only snowfall. Thicknesses are compared to those computed for seven air mass types and differences layers are examined for continuity. For the three air masses identified as prevalent during heavy snow, light-to-heavy and early-to-late season snowfall categories are established and thickness variations are evaluated against non-snow days for significant differences. Results indicate that the differences in layer thicknesses are comparable for all precipitation and non-snow days but around 40 geopotential meters less for pure-snow days. For air masses present during snow, layer thicknesses can vary by over 100 gpm with type. Isolating polar varieties, approximately 50 gpm thickness differences are found in pure-snow days. Comparable differences are detected between the moderate and polar types and the continuity between

  5. Seasonal variability of tritium and ion concentrations in rain at Kumamoto, Japan and back-trajectory analysis of air mass

    SciTech Connect

    Momoshima, N.; Sugihara, S.; Toyoshima, T.; Nagao, Y.; Takahashi, M.; Nakamura, Y.

    2008-07-15

    Tritium and major ion concentrations in rain were analyzed in Kumamoto (Japan)) between 2001 and 2006 to examine present tritium concentration and seasonal variation. The average tritium concentration was 0.36 {+-} 0.19 Bq/L (n=104) and higher tritium concentrations were observed in spring than the other seasons. Among the ions, non-sea-salt (nss) SO{sub 4}{sup 2}'- showed higher concentration in winter while other ions did not show marked increase in winter. Based on the back-trajectory analyses of air masses, the increase in tritium concentrations in spring arises from downward movement of naturally produced tritium from stratosphere to troposphere, while the increase of the nss-SO{sub 4}{sup 2-} concentrations in winter is due to long range transport of pollutants from China to Japan. (authors)

  6. Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Rosner, D. E.

    1984-01-01

    A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

  7. Inter-annual variability of air mass and acidified pollutants transboundary exchange in the north-eastern part of the EANET region

    NASA Astrophysics Data System (ADS)

    Gromov, Sergey A.; Trifonova-Yakovleva, Alisa; Gromov, Sergey S.

    2016-04-01

    ]. This dataset provides comprehensive monthly statistics on the wind meteorological regime at the stations of interest in a given range of altitudes. Based on long-term source observational data, the dataset is assumed being representative up to date, which allowed us to estimate monthly pollutant fluxes for the years 2006-2008 over segments of the Russian border and its whole [4]. In the current phase of our study, we calculate the inter-annual variations in the transboundary pollutant fluxes for 2000-2012 using longer-term EANET data and transient changes in air mass fluxes derived from the meteorological wind fields from ERA INTERIM re-analysis [5]. We gauge similar average air transport terms and dynamics from the statistical and reanalysis data, which bolsters our earlier findings. The reanalysis data, being naturally more variable, convolutes the variations in net air fluxes and pollutant concentrations into several episodes we emphasise, in addition to the integral pollutant transfer terms we estimate. At last, we discuss on the possibility of climate change effect on the flux strength and dynamics together with regional air quality tendencies in North-East Asia countries. References: Izrael, Yu.A., et al.: Monitoring of the Transboundary Air Pollution Transport. Gidrometeoizdat, Leningrad, 303 p., 187 (in Russian). Akimoto H., et al.: Periodic Report of the State of Acid Deposition in East Asia. Part I: Regional Assessment. EANET-UNEP/RRC.AP-ADORC, 258 p., 2006. Brukhan, F.F.: Aeroclimatic Characteristics of the Mean Winds over USSR (ed. Ignatjushina E.N.). Gidrometeoizdat, Moscow, 54 p., 1984 (in Russian). Gromov S.A., et al.: First-order evaluation of transboundary pollution fluxes in areas of EANET stations in Eastern Siberia and the Russian Far East. EANET Science Bulletin, vol. 3, pp. 195-203, 2013. Dee, D. P., et al.: The ERA-Interim reanalysis: configuration and performance of the data assimilation system, Quart. J. Royal Met. Soc., 137, 553-597, doi: 10

  8. Dynamics of Variable Mass Systems

    NASA Technical Reports Server (NTRS)

    Eke, Fidelis O.

    1998-01-01

    This report presents the results of an investigation of the effects of mass loss on the attitude behavior of spinning bodies in flight. The principal goal is to determine whether there are circumstances under which the motion of variable mass systems can become unstable in the sense that their transverse angular velocities become unbounded. Obviously, results from a study of this kind would find immediate application in the aerospace field. The first part of this study features a complete and mathematically rigorous derivation of a set of equations that govern both the translational and rotational motions of general variable mass systems. The remainder of the study is then devoted to the application of the equations obtained to a systematic investigation of the effect of various mass loss scenarios on the dynamics of increasingly complex models of variable mass systems. It is found that mass loss can have a major impact on the dynamics of mechanical systems, including a possible change in the systems stability picture. Factors such as nozzle geometry, combustion chamber geometry, propellant's initial shape, size and relative mass, and propellant location can all have important influences on the system's dynamic behavior. The relative importance of these parameters on-system motion are quantified in a way that is useful for design purposes.

  9. Surface Temperature variability from AIRS.

    NASA Astrophysics Data System (ADS)

    Ruzmaikin, A.; Dang, V. T.; Aumann, H. H.

    2015-12-01

    To address the existence and possible causes of the climate hiatus in the Earth's global temperature we investigate the trends and variability in the surface temperature using retrievals obtained from the measurements by the Atmospheric Infrared Sounder (AIRS) and its companion instrument, the Advanced Microwave Sounding Unit (AMSU), onboard of Aqua spacecraft in 2002-2014for the day and night conditions. The data used are L3 monthly means on a 1x1degree spatial grid. We separate the land and ocean temperatures, as well as temperatures in Artic, Antarctic and desert regions. We compare the satellite data with the new surface data produced by Karl et al. (2015) who denies the reality of the climate hiatus. The difference in the regional trends can help to explain why the global surface temperature remains almost unchanged but the frequency of occurrence of the extreme events increases under rising anthropogenic forcing. The day-night difference is an indicator of the anthropogenic trend. This work was supported by the Jet Propulsion Laboratory of the California Institute of Technology, under a contract with the National Aeronautics and Space Administration.

  10. Positive random variables with a discrete probability mass at the origin: Parameter estimation for left-censored samples with application to air quality monitoring data

    SciTech Connect

    Gogolak, C.V.

    1986-11-01

    The concentration of a contaminant measured in a particular medium might be distributed as a positive random variable when it is present, but it may not always be present. If there is a level below which the concentration cannot be distinguished from zero by the analytical apparatus, a sample from such a population will be censored on the left. The presence of both zeros and positive values in the censored portion of such samples complicates the problem of estimating the parameters of the underlying positive random variable and the probability of a zero observation. Using the method of maximum likelihood, it is shown that the solution to this estimation problem reduces largely to that of estimating the parameters of the distribution truncated at the point of censorship. The maximum likelihood estimate of the proportion of zero values follows directly. The derivation of the maximum likelihood estimates for a lognormal population with zeros is given in detail, and the asymptotic properties of the estimates are examined. The estimation method was used to fit several different distributions to a set of severely censored /sup 85/Kr monitoring data from six locations at the Savannah River Plant chemical separations facilities.

  11. Mass transfer cycles in cataclysmic variables

    NASA Technical Reports Server (NTRS)

    King, A. R.; Frank, J.; Kolb, U.; Ritter, H.

    1995-01-01

    It is well known that in cataclysmic variables the mass transfer rate must fluctuate about the evolutionary mean on timescales too long to be directly observable. We show that limit-cycle behavior can occur if the radius change of the secondary star is sensitive to the instantaneous mass transfer rate. The only reasonable way in which such a dependence can arise is through irradiation of this star by the accreting component. The system oscillates between high states, in which irradiation causes slow expansion of the secondary and drives an elevated transfer rate, and low states, in which this star contracts.

  12. Variability of hazardous air pollutants in an urban area

    NASA Astrophysics Data System (ADS)

    Spicer, Chester W.; Buxton, Bruce E.; Holdren, Michael W.; Smith, Deborah L.; Kelly, Thomas J.; Rust, Steven W.; Pate, Alan D.; Sverdrup, George M.; Chuang, Jane C.

    The variability of hazardous air pollutants (HAPs) is an important factor in determining human exposure to such chemicals, and in designing HAP measurement programs. This study has investigated the factors which contribute to HAP variability in an urban area. Six measurement sites separated by up to 12 km collected data with 3 h time resolution to examine spatial variability within neighborhoods and between neighborhoods. The measurements were made in Columbus, OH. The 3 h results also were used to study temporal variability, and duplicate samples collected at each site were used to determine the component of variability attributable to the measurement process. Hourly samples collected over 10 days at one site provided further insight into the temporal resolution needed to capture short-term peak concentrations. Measurements at the 6 spatial sites focused on 78 chemicals. Twenty-three of these species were found in at least 95% of the 3 h samples, and 39 chemicals were present at least 60% of the time. The relative standard deviations for most of these 39 frequently detected chemicals was 1.0 or lower. Variability was segmented into temporal, spatial, and measurement components. Temporal variation was the major contributor to HAP variability for 19 of the 39 frequently detected compounds, based on the 3 h data. Measurement imprecision contributed less than 25% for most of the volatile organic species, but 30% or more of the variability for carbonyl compounds, trace elements, and particle-bound extractable organic mass. Interestingly, the spatial component contributed less than 20% of the total variability for all the chemicals except sulfur. Based on the data with hourly resolution, peak to median ratios (hourly peak to 24 h median) averaged between 2 and 4 for most of the volatile organic compounds, but there were two species with peak to median ratios of about 10.

  13. The Effective Mass of a Ball in the Air

    ERIC Educational Resources Information Center

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  14. Changing air mass frequencies in Canada: potential links and implications for human health.

    PubMed

    Vanos, J K; Cakmak, S

    2014-03-01

    Many individual variables have been studied to understand climate change, yet an overall weather situation involves the consideration of many meteorological variables simultaneously at various times diurnally, seasonally, and yearly. The current study identifies a full weather situation as an air mass type using synoptic scale classification, in 30 population centres throughout Canada. Investigative analysis of long-term air mass frequency trends was completed, drawing comparisons between seasons and climate zones. We find that the changing air mass trends are highly dependent on the season and climate zone being studied, with an overall increase of moderate ('warm') air masses and decrease of polar ('cold') air masses. In the summertime, general increased moisture content is present throughout Canada, consistent with the warming air masses. The moist tropical air mass, containing the most hot and humid air, is found to increase in a statistically significant fashion in the summertime in 46% of the areas studied, which encompass six of Canada's ten largest population centres. This emphasises the need for heat adaptation and acclimatisation for a large proportion of the Canadian population. In addition, strong and significant decreases of transition/frontal passage days were found throughout Canada. This result is one of the most remarkable transition frequency results published to date due to its consistency in identifying declining trends, coinciding with research completed in the United States (US). We discuss relative results and implications to similar US air mass trend analyses, and draw upon research studies involving large-scale upper-level air flow and vortex connections to air mass changes, to small-scale meteorological and air pollution interactions. Further research is warranted to better understand such connections, and how these air masses relate to the overall and city-specific health of Canadians.

  15. Air velocity distributions from a variable-rate air-assisted sprayer for tree applications

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A capability that implements tree structure to control liquid and air flow rates is the preferential design in the development of variable-rate orchard and nursery sprayers. Air jet velocity distributions from an air assisted, five-port sprayer which was under the development to achieve variable-rat...

  16. Air Mass Origin as a Diagnostic of Seasonally-Varying Transport into the Arctic

    NASA Astrophysics Data System (ADS)

    Orbe, C.; Waugh, D. W.; Holzer, M. B.; Newman, P. A.; Polvani, L. M.; Oman, L.; Li, F.

    2013-12-01

    While the signatures of the seasonal cycle on basic state variables such as temperature, winds and on chemical composition have been explored in depth, its signature on air mass composition has received relatively little attention. To this end, we present the first analysis of the seasonally varying transport from the northern hemisphere (NH) midlatitudes into the Arctic using rigorously defined air masses. The fractional contribution from each air mass partitions Arctic air according to where it was last in the planetary boundary layer (PBL) at midlatitudes over the Pacific and Atlantic oceans, North America, Europe, and Asia. Air mass fractions are computed using the coupled climate-chemistry model GEOSCCM subject to fixed present-day climate forcings. We find that during DJF 48% of the air in the free troposphere poleward of 60N was last at midlatitudes primarily at the Pacific and Atlantic oceans, at 20% and 10% respectively. During JJA, however, the largest contributions to Arctic air come from Asian and North American source regions, revealing that transport from the industrialized midlatitude regions dominates during boreal summer. Preliminary calculations of future air masses for a model integration subject to A1B greenhouse gases also reveal the model's climate change response in arctic air mass composition. In concert with weakened tropospheric eddy kinetic energy and a weakened Hadley cell, we find that changes in annual mean arctic air mass fractions are of the order 10%, with increased contributions from air that was last in contact with the PBL over North America and over the Atlantic and Pacific oceans. Air-mass fractions, and their changes, thus help to isolate the role of transport to changes in composition, which are not only driven by changes in chemistry and emissions but also crucially by changes in atmospheric flow.

  17. Working characteristics of variable intake valve in compressed air engine.

    PubMed

    Yu, Qihui; Shi, Yan; Cai, Maolin

    2014-01-01

    A new camless compressed air engine is proposed, which can make the compressed air energy reasonably distributed. Through analysis of the camless compressed air engine, a mathematical model of the working processes was set up. Using the software MATLAB/Simulink for simulation, the pressure, temperature, and air mass of the cylinder were obtained. In order to verify the accuracy of the mathematical model, the experiments were conducted. Moreover, performance analysis was introduced to design compressed air engine. Results show that, firstly, the simulation results have good consistency with the experimental results. Secondly, under different intake pressures, the highest output power is obtained when the crank speed reaches 500 rpm, which also provides the maximum output torque. Finally, higher energy utilization efficiency can be obtained at the lower speed, intake pressure, and valve duration angle. This research can refer to the design of the camless valve of compressed air engine. PMID:25379536

  18. Working Characteristics of Variable Intake Valve in Compressed Air Engine

    PubMed Central

    Yu, Qihui; Shi, Yan; Cai, Maolin

    2014-01-01

    A new camless compressed air engine is proposed, which can make the compressed air energy reasonably distributed. Through analysis of the camless compressed air engine, a mathematical model of the working processes was set up. Using the software MATLAB/Simulink for simulation, the pressure, temperature, and air mass of the cylinder were obtained. In order to verify the accuracy of the mathematical model, the experiments were conducted. Moreover, performance analysis was introduced to design compressed air engine. Results show that, firstly, the simulation results have good consistency with the experimental results. Secondly, under different intake pressures, the highest output power is obtained when the crank speed reaches 500 rpm, which also provides the maximum output torque. Finally, higher energy utilization efficiency can be obtained at the lower speed, intake pressure, and valve duration angle. This research can refer to the design of the camless valve of compressed air engine. PMID:25379536

  19. Influence of the relative optical air mass on ultraviolet erythemal irradiance

    NASA Astrophysics Data System (ADS)

    Antón, M.; Serrano, A.; Cancillo, M. L.; García, J. A.

    2009-12-01

    The main objective of this article is to analyze the relationship between the transmissivity for ultraviolet erythemal irradiance (UVER) and the relative optical air mass at Badajoz (Southwestern Spain). Thus, a power expression between both variables is developed, which analyses in detail how atmospheric transmission is influenced by the total ozone column (TOC) and the atmospheric clearness. The period of analysis extends from 2001 to 2005. The experimental results indicate that clearness conditions play an important role in the relationship between UVER transmissivity and the relative optical air mass, while the effect of TOC is much smaller for this data set. In addition, the results show that UVER transmissivity is more sensitive to changes in atmospheric clearness than to TOC variability. Changes in TOC values higher than 15% cause UVER trasnmissivity to vary between 14% and 22%, while changes between cloud-free and overcast conditions produce variations in UVER transmissivity between 68% and 74% depending on the relative optical air mass.

  20. Structural/control system optimization with variable actuator masses

    NASA Technical Reports Server (NTRS)

    Jin, Ik M.; Sepulveda, Abdon E.

    1993-01-01

    A method is presented to integrate the design space for structural/control system optimization problems in the case of linear state feedback control. Nonstructural lumped masses and control system design variables as well as structural sizing variables are all treated equally as independent design variables in the optimization process. Structural and control design variable linking schemes are used in order to avoid a prohibitively large increase in the total number of independent design variables. When actuator masses are treated as nonstructural lumped mass design variables, special consideration is given to the relation between the transient peak responses and the required actuator masses which is formulated as a behavior constraint form. The original nonlinear mathematical programming problem based on a finite element formulation and linear state feedback is replaced by a sequence of explicit approximate problems exploiting various approximation concepts such as design variable linkings, temporary constraint deletion and first order Taylor series expansion of nonlinear behavior constraints in terms of intermediate design variables. Examples which involve a variety of dynamic behavior constraints (including constraints on closed-loop eigenvalues, peak transient displacements, peak actuator forces, and relations between the peak responses and the actuator masses) are effectively solved by using the method presented.

  1. Variability in properties of Salado Mass Concrete

    SciTech Connect

    Wakeley, L.D.; Harrington, P.T.; Hansen, F.D.

    1995-08-01

    Salado Mass Concrete (SMC) has been developed for use as a seal component in the Waste Isolation Pilot Plant. This concrete is intended to be mixed from pre-bagged materials, have an initial slump of 10 in., and remain pumpable and placeable for two hours after mixing. It is a mass concrete because it will be placed in monoliths large enough that the heat generated during cement hydration has the potential to cause thermal expansion and subsequent cracking, a phenomenon to avoid in the seal system. This report describes effects on concrete properties of changes in ratio of water to cement, batch size, and variations in characteristics of different lots of individual components of the concrete. The research demonstrates that the concrete can be prepared from laboratory-batched or pre-bagged dry materials in batches from 1.5 ft{sup 3} to 5.0 yd{sup 3}, with no chemical admixtures other than the sodium chloride added to improve bonding with the host rock, at a water-to-cement ratio ranging from 0.36 to 0.42. All batches prepared according to established procedures had adequate workability for at least 1.5 hours, and achieved or exceeded the target compressive strength of 4500 psi at 180 days after casting. Portland cement and fly ash from different lots or sources did not have a measurable effect on concrete properties, but variations in a shrinkage-compensating cement used as a component of the concrete did appear to affect workability. A low initial temperature and the water-reducing and set-retarding functions of the salt are critical to meeting target properties.

  2. Air sparging effectiveness: laboratory characterization of air-channel mass transfer zone for VOC volatilization.

    PubMed

    Braida, W J; Ong, S K

    2001-10-12

    Air sparging in conjunction with soil vapor extraction is one of many technologies currently being applied for the remediation of groundwater contaminated with volatile organic compounds (VOCs). Mass transfer at the air-water interface during air sparging is affected by various soil and VOC properties. In this study with a single air-channel apparatus, mass transfer of VOCs was shown to occur within a thin layer of saturated porous media next to the air channel. In this zone, the VOCs were found to rapidly deplete during air sparging resulting in a steep concentration gradient while the VOC concentration outside the zone remained fairly constant. The sizes of the mass transfer zone were found to range from 17 to 41 mm or 70d(50) and 215d(50) (d(50)=mean particle size) for low organic carbon content media (<0.01% OC). The size of the mass transfer zone was found to be proportional to the square root of the aqueous diffusivity of the VOC, and was affected by the mean particle size, and the uniformity coefficient. Effects of the volatility of the VOCs as represented by the Henry's law constants and the airflow rates on the mass transfer zone were found to be negligible but VOC mass transfer from air-water interface to bulk air phase seems to play a role. A general correlation for predicting the size of the mass transfer zone was developed. The model was developed using data from nine different VOCs and verified by two other VOCs. The existence of the mass transfer zone provides an explanation for the tailing effect of the air phase concentration under prolonged air sparging and the rebound in the VOC air phase concentration after the sparging system is turned off.

  3. Doubling down on peptide phosphorylation as a variable mass modification

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Some mass spectrometrists believe that searching for variable post-translational modifications like phosphorylation of serine or threonine when using database-search algorithms to interpret peptide tandem mass spectra will increase false positive rates. The basis for this is the premise that the al...

  4. Mass loss and OH maser emission from Mira variables

    NASA Technical Reports Server (NTRS)

    Michalitsianos, A. G.; Kafatos, M.

    1978-01-01

    The mass, radius, and luminosity of 26 Mira variables that are known OH sources of radio emission at 1612 MHz have been estimated. The time-independent solution of Salpeter's (1974) stellar-wind equation and a period-density relation are used to solve for basic stellar parameters, with the aid of the terminal expansion velocity of the OH maser cloud. Masses obtained from these calculations are consistent with other estimated values for masses of Mira variables. Good agreement is obtained when comparing the rate of mass loss as determined from Reimers's (1977) semiempirical relation with estimates of the mass-loss rate as deduced from theoretical models involving radiation pressure on grains. These calculations suggest a strong correlation between the mass-loss rate and the pulsation period. Arguments concerning the general properties of silicate grains from radiation-pressure-driven stellar-wind equations are discussed.

  5. Influence of Baseline Air Masses and Wildland Fires on Air Quality in the Western United States

    NASA Astrophysics Data System (ADS)

    Wigder, Nicole L.

    -- 2013. Enhancement ratios are the enhancement of a species in a plume normalized by the enhancement of a long-lived species such as carbon monoxide (CO) or carbon dioxide (CO2). I identified the source and transport time of each of the 55 plumes observed at MBO using backward air mass trajectories and satellite data. During the first two days of transport, PM enhancement ratios (relative to CO) were greater than documented emission factors (on average 0.29 mug m-3 ppbv-1 compared to an average emission factor of 0.16 mug m-3 ppbv -1 for temperate regions), which I attributed to net production of Secondary Organic Aerosol (SOA). At transport times of more than two days, PM enhancement ratios were relatively low, which I attributed to loss of PM (through deposition and/or cloud processing) exceeding net SOA production in the fire plumes. My research also showed that SOA production from non-methane organic carbon (NMOC) would be necessary to explain the high aerosol scattering/CO 2 enhancement ratios (20.46 -- 187.18 Mm-1 ppbv -1) observed in 2012 -- 2013. The fourth component of this dissertation is a comparison of daily satellite observations of CO with daily in situ observations of CO at MBO during 2004 -- 2013. I found that the daily variations in CO observed at MBO were also evident in the daytime AIRS CO observations, particularly during spring (r = 0.52 in spring). North American wildland fires were a major factor impacting the lower correlation between MBO and AIRS CO observations in the summer and autumn (r = 0.26 and 0.16, respectively), reflecting the inability of AIRS to quantify high CO in the boundary layer. The MBO and AIRS CO observations also showed the same inter-annual variability in spring (r = 0.77). During this season, CO and O3 concentrations at MBO are often influenced by long-range transport of Asian pollution (Asian LRT) and Upper Troposphere/ Lower Stratosphere (UT/LS) air masses. Through a case study, I showed that the correlation between the

  6. Controls of air temperature variability over an Alpine Glacier

    NASA Astrophysics Data System (ADS)

    Shaw, Thomas; Brock, Ben; Ayala, Álvaro; Rutter, Nick

    2016-04-01

    Near surface air temperature (Ta) is one of the most important controls on energy exchange between a glacier surface and the overlying atmosphere. However, not enough detail is known about the controls on Ta across a glacier due to sparse data availability. Recent work has provided insights into variability of Ta along glacier centre-lines in different parts of the world, yet there is still a limited understanding of off-centreline variability in Ta and how best to estimate it from distant off-glacier locations. We present a new dataset of distributed 2m Ta records for the Tsanteleina Glacier in Northwest Italy from July-September, 2015. Data provide detailed information of lateral (across-glacier) and centre-line variations in Ta, with ~20,000 hourly observations from 17 locations. The suitability of different vertical temperature gradients (VTGs) in estimating air temperature is considered under a range of meteorological conditions and from different forcing locations. A key finding is that local VTGs account for a lot of Ta variability under a broad range of climatic conditions. However, across-glacier variability is found to be significant, particularly for high ambient temperatures and for localised topographic depressions. The relationship of spatial Ta patterns with regional-scale reanalysis data and alternative Ta estimation methodologies are also presented. This work improves the knowledge of local scale Ta variations and their importance to melt modelling.

  7. Changes in large-scale air circulation and connection with climate variables in Romania

    NASA Astrophysics Data System (ADS)

    Stefan, Sabina; Barbu, Nicu

    2016-04-01

    The aim of this paper is the analysis of the relationship between climate variables (seasonal mean air temperature - T2m, and seasonal amount of precipitation - PP) and large-scale air circulation. In order to achieve this, the air circulation types were derived from GrossWetterTypen (GWT) and WetterLagenKlassifikation (WLK) Catalogues developed within COST733 framework. Daily air circulation types are divided into 18 groups according to the GWT Catalogue and in 40 groups according to the WLK Catalogue and for each type winter (DJF) and summer (JJA) occurrence frequency were calculated. To this end the Pearson correlation coefficient between climate variables and circulation type's frequency were computed. The results reveals that in wintertime the GWT circulation types captures better than WLK circulation types the T2m variability in time that for summer the WLK circulation types captures better than GWT circulation types. This is due to the seasonal variability of the horizontal extension of air masses. We found that the T2m is positive correlated to anticyclonic circulation types and negative correlated with cyclonic types and the PP is correlated to the cyclonic circulation and negative correlated to anticyclonic ones. Additionally, the trend significance of the climate variables as well as air circulation types have been analysed with the non-parametric Mann-Kendall test. The changes of the trends were detected by employing the non-parametric Pettit test. From the trend analysis we can state that some of the anticyclonic circulation types presents upward tendency and some of the cyclonic circulation presents downward tendency. This is an important results because explain the upward trend of the T2m and the downward trend of the PP.

  8. Subseasonal variability of North American wintertime surface air temperature

    NASA Astrophysics Data System (ADS)

    Lin, Hai

    2015-09-01

    Using observational pentad data of the recent 34 Northern Hemisphere extended winters, subseasonal variability of surface air temperature (SAT) over North America is analyzed. The four leading modes of subseasonal SAT variability, that are identified with an empirical orthogonal function (EOF) analysis, account for about 60% of the total variance. The first (EOF1) and second (EOF2) modes are independent of other modes, and thus are likely controlled by distinct processes. The third (EOF3) and fourth (EOF4) modes, however, tend to have a phase shift to each other in space and time, indicating that part of their variability is related to a common process and represent a propagating pattern over North America. Lagged regression analysis is conducted to identify the precursors of large-scale atmospheric circulation for each mode a few pentads in advance, and to understand the processes that influence the subseasonal SAT variability and the predictability signal sources. EOF1 is found to be closely related to the Pacific-North American (PNA) circulation pattern and at least part of its variability is preceded by the East Asian cold surge. The cold surge leads to low-level convergence and enhanced convection in the tropical central Pacific which in turn induces the PNA. EOF2 tends to oscillate at a period of about 70 days, and is influenced by the low-frequency component of the Madden-Julian Oscillation (MJO). On the other hand, EOF3 and EOF4 are connected to the high-frequency part of the MJO which has a period range of 30-50 days. These findings would help understanding the mechanisms of subseasonal surface air temperature variability in North America and improving weather predictions on a subseasonal time scale.

  9. On the generalized virial theorem for systems with variable mass

    NASA Astrophysics Data System (ADS)

    Ganghoffer, Jean-François; Rahouadj, Rachid

    2016-03-01

    We presently extend the virial theorem for both discrete and continuous systems of material points with variable mass, relying on developments presented in Ganghoffer (Int J Solids Struct 47:1209-1220, 2010). The developed framework is applicable to describe physical systems at very different scales, from the evolution of a population of biological cells accounting for growth to mass ejection phenomena occurring within a collection of gravitating objects at the very large astrophysical scales. As a starting basis, the field equations in continuum mechanics are written to account for a mass source and a mass flux, leading to a formulation of the virial theorem accounting for non-constant mass within the considered system. The scalar and tensorial forms of the virial theorem are then written successively in both Lagrangian and Eulerian formats, incorporating the mass flux. As an illustration, the averaged stress tensor in accreting gravitating solid bodies is evaluated based on the generalized virial theorem.

  10. Intraurban Spatiotemporal Variability of Ambient Air Pollutants across Metropolitan St. Louis

    NASA Astrophysics Data System (ADS)

    Du, Li

    Ambient air monitoring networks have been established in the United States since the 1970s to comply with the Clean Air Act. The monitoring networks are primarily used to determine compliance but also provide substantive support to air quality management and air quality research including studies on health effects of air pollutants. The Roxana Air Quality Study (RAQS) was conducted at the fenceline of a petroleum refinery in Roxana, Illinois. In addition to providing insights into air pollutant impacts from the refinery, these measurements increased the St. Louis area monitoring network density for gaseous air toxics and fine particulate matter (PM2.5) speciation and thus provided an opportunity to examine intraurban spatiotemporal variability for these air quality parameters. This dissertation focused on exploring and assessing aspects of ambient air pollutant spatiotemporal variability in the St. Louis area from three progressively expanded spatial scales using a suite of methods and metrics. RAQS data were used to characterize air quality conditions in the immediate vicinity of the petroleum refinery. For example, PM2.5 lanthanoids were used to track impacts from refinery fluidized bed catalytic cracker emissions. RAQS air toxics data were interpreted by comparing to network data from the Blair Street station in the City of St. Louis which is a National Air Toxics Trends Station. Species were classified as being spatially homogeneous (similar between sites) or heterogeneous (different between sites) and in the latter case these differences were interpreted using surface winds data. For PM 2.5 species, there were five concurrently operating sites in the St. Louis area - including the site in Roxana - which are either formally part of the national Chemical Speciation Network (CSN) or rigorously follow the CSN sampling and analytical protocols. This unusually large number of speciation sites for a region the size of St. Louis motivated a detailed examination of

  11. Geomagnetic activity and polar surface air temperature variability

    NASA Astrophysics Data System (ADS)

    Seppälä, A.; Randall, C. E.; Clilverd, M. A.; Rozanov, E.; Rodger, C. J.

    2009-10-01

    Here we use the ERA-40 and ECMWF operational surface level air temperature data sets from 1957 to 2006 to examine polar temperature variations during years with different levels of geomagnetic activity, as defined by the A p index. Previous modeling work has suggested that NO x produced at high latitudes by energetic particle precipitation can eventually lead to detectable changes in surface air temperatures (SATs). We find that during winter months, polar SATs in years with high A p index are different than in years with low A p index; the differences are statistically significant at the 2-sigma level and range up to about ±4.5 K, depending on location. The temperature differences are larger when years with wintertime Sudden Stratospheric Warmings (SSWs) are excluded. We take into account solar irradiance variations, unlike previous analyses of geomagnetic effects in ERA-40 and operational data. Although we cannot conclusively show that the polar SAT patterns are physically linked by geomagnetic activity, we conclude that geomagnetic activity likely plays a role in modulating wintertime surface air temperatures. We tested our SAT results against variation in the Quasi Biennial Oscillation, the El Niño Southern Oscillation and the Southern Annular Mode. The results suggested that these were not driving the observed polar SAT variability. However, significant uncertainty is introduced by the Northern Annular Mode, and we cannot robustly exclude a chance linkage between sea surface temperature variability and geomagnetic activity.

  12. Theories of Variable Mass Particles and Low Energy Nuclear Phenomena

    NASA Astrophysics Data System (ADS)

    Davidson, Mark

    2014-02-01

    Variable particle masses have sometimes been invoked to explain observed anomalies in low energy nuclear reactions (LENR). Such behavior has never been observed directly, and is not considered possible in theoretical nuclear physics. Nevertheless, there are covariant off-mass-shell theories of relativistic particle dynamics, based on works by Fock, Stueckelberg, Feynman, Greenberger, Horwitz, and others. We review some of these and we also consider virtual particles that arise in conventional Feynman diagrams in relativistic field theories. Effective Lagrangian models incorporating variable mass particle theories might be useful in describing anomalous nuclear reactions by combining mass shifts together with resonant tunneling and other effects. A detailed model for resonant fusion in a deuterium molecule with off-shell deuterons and electrons is presented as an example. Experimental means of observing such off-shell behavior directly, if it exists, is proposed and described. Brief explanations for elemental transmutation and formation of micro-craters are also given, and an alternative mechanism for the mass shift in the Widom-Larsen theory is presented. If variable mass theories were to find experimental support from LENR, then they would undoubtedly have important implications for the foundations of quantum mechanics, and practical applications may arise.

  13. Identifying Dynamically Induced Variability in Glacier Mass-Balance Records

    NASA Astrophysics Data System (ADS)

    Christian, J. E.; Siler, N.; Koutnik, M. R.; Roe, G.

    2015-12-01

    Glacier mass-balance (i.e., accumulation vs. ablation) provides a direct indicator of a glacier's relationship with climate. However, mass-balance records contain noise due to internal climate variability (i.e., from stochastic fluctuations in large-scale atmospheric circulation), which can obscure or bias trends in these relatively short timeseries. This presents a challenge in correctly identifying the signature of anthropogenic change. "Dynamical adjustment" is a technique that identifies patterns of variance shared between a climate timeseries of interest (e.g., mass-balance) and independent "predictor" variables associated with large-scale circulation (e.g., Sea Level Pressure, SLP, or Sea Surface Temperature, SST). Extracting the component of variance due to internal variability leaves a residual timeseries for which trends can more confidently be attributed to external forcing. We apply dynamical adjustments based on Partial Least Squares Regression to mass-balance records from South Cascade Glacier in Washington State and Wolverine and Gulkana Glaciers in Alaska, independently analyzing seasonal balance records to assess the dynamical influences on winter accumulation and summer ablation. Seasonally averaged North Pacific SLP and SST fields perform comparably as predictor variables, explaining 50-60% of the variance in winter balance and 30-40% of variance in summer balance for South Cascade and Wolverine Glaciers. Gulkana glacier, located further inland than the other two glaciers, is less closely linked to North Pacific climate variability, with the predictors explaining roughly one-third of variance in its winter and summer balance. We analyze the significance of linear trends in the raw and adjusted mass-balance records, and find that for all three glaciers, a) summer balance shows a statistically significant downward trend that is not substantially altered when dynamically induced variability is removed, and b) winter balance shows no statistically

  14. Warm-air advection, air mass transformation and fog causes rapid ice melt

    NASA Astrophysics Data System (ADS)

    Tjernström, Michael; Shupe, Matthew D.; Brooks, Ian M.; Persson, P. Ola G.; Prytherch, John; Salisbury, Dominic J.; Sedlar, Joseph; Achtert, Peggy; Brooks, Barbara J.; Johnston, Paul E.; Sotiropoulou, Georgia; Wolfe, Dan

    2015-07-01

    Direct observations during intense warm-air advection over the East Siberian Sea reveal a period of rapid sea-ice melt. A semistationary, high-pressure system north of the Bering Strait forced northward advection of warm, moist air from the continent. Air-mass transformation over melting sea ice formed a strong, surface-based temperature inversion in which dense fog formed. This induced a positive net longwave radiation at the surface while reducing net solar radiation only marginally; the inversion also resulted in downward turbulent heat flux. The sum of these processes enhanced the surface energy flux by an average of ~15 W m-2 for a week. Satellite images before and after the episode show sea-ice concentrations decreasing from > 90% to ~50% over a large area affected by the air-mass transformation. We argue that this rapid melt was triggered by the increased heat flux from the atmosphere due to the warm-air advection.

  15. Identifying climatic drivers of glacier mass balance variability of Lewis glacier, Mt. Kenya

    NASA Astrophysics Data System (ADS)

    Nicholson, Lindsey; Prinz, Rainer; Kaser, Georg

    2013-04-01

    Lewis Glacier (Kenya, 0°09' S; 37°18' E) has a 20 year historical annual mass balance record, spanning 1979-1996 and 2010-2012. This offers an opportunity to investigate the glacier-climate interactions at ~4800m a.s.l. in the equatorial zone, which in turn allows investigation of the possible tropical mid-tropospheric conditions that must have prevailed in order to permit formerly larger glacier extents on the mountain. Here we use field data of glacier annual mass balance, seasonal glacier surface height changes and monthly precipitation records to test the impact of potential drivers on the glacier variability. We examine relationships between these glaciological data and ERA-interim atmospheric fields, satellite measurements of outgoing long wave radiation and sea surface temperatures. In all years except the mass balance year of 1989 Lewis glacier experiences a negative mass balance. Strongly negative annual mass balances occur only if one or both of the wet seasons fail to bring snowfall to the summit and both annual mass balance and rainy season surface change is well correlated with measured precipitation and enhanced convection within the equatorial rain belt in East Africa and the western Indian Ocean. Seasonal glacier surface height change is correlated with air temperature throughout the whole tropical African zone during the dry months of January and February, but the only positive mass balance year experienced seasonal cold temperature anomalies over equatorial Africa in all seasons. No single season emerges as the dominant driver of the inter-annual mass balance variability, and the climate sensitivity of the glacier surface change differs between seasons. However Lewis Glacier mass balance over the study period can be explained by moisture variability as the primary driver and temperature variability as an additional driver of glacier mass change.

  16. Analysis of mass transfer performance in an air stripping tower

    SciTech Connect

    Chung, T.W.; Lai, C.H.; Wu, H.

    1999-10-01

    The carryover of working solution in a traditional stripping tower is of serious concern in real applications. A U-shaped spray tower to prevent carryover has been designed to study the stripping of water vapor from aqueous desiccant solutions of 91.8 to 95.8 wt% triethylene glycol. In this study, water vapor was removed from the diluted desiccant solution by heating the solution and stripping it with the ambient air. Therefore, the solution was concentrated to a desired concentration. This spray tower was capable of handling air flow rates from 3.2 to 5.13 kg/min and liquid flow rates from 1.6 to 2.76 kg/min. Since the literature data on air stripping towers are limited, studies on the mass transfer coefficient and other mass transfer parameters were carried out in this study. Under the operating conditions, the overall mass transfer coefficient calculated from the experimental data varied from 0.053 to 0.169 mol/m{sup 3}{center{underscore}dot}s. These corresponded to heights of a transfer unit of 2.3 to 0.71 m, respectively. The rates of stripping in this spray tower were typically varied from 2.28 to 12.15 kg H{sub 2}O/h. A correlation of the mass transfer coefficient for the air stripping process was also developed in this study.

  17. Identifying Modes of Temperature Variability Using AIRS Data.

    NASA Astrophysics Data System (ADS)

    Ruzmaikin, A.; Aumann, H. H.; Yung, Y.

    2007-12-01

    We use the Atmospheric Infrared Sounder (AIRS) and Advance Microwave Sounding Unit (AMSU) data obtained on Aqua spacecraft to study mid-tropospheric temperature variability between 2002-2007. The analysis is focused on daily zonal means of the AIRS channel at 2388 1/cm in the CO2 R-branch and the AMSU channel #5 in the 57 GHz Oxygen band, both with weighting function peaking in the mid-troposphere (400 mb) and the matching sea surface temperature from NCEP (Aumann et al., 2007). Taking into account the nonlinear and non- stationary behavior of the temperature we apply the Empirical Mode Decomposition (Huang et al., 1998) to better separate modes of variability. All-sky (cloudy) and clear sky, day and night data are analyzed. In addition to the dominant annual variation, which is nonlinear and latitude dependent, we identified the modes with higher frequency and inter-annual modes. Some trends are visible and we apply stringent criteria to test their statistical significance. References: Aumann, H. H., D. T. Gregorich, S. E. Broberg, and D. A. Elliott, Geophys. Res. Lett., 34, L15813, doi:10.1029/2006GL029191, 2007. Huang, N. E. Z. Shen, S. R. Long, M. C. Wu, H. H. Shih, Q. Zheng, N.-C. Yen, C. C. Tung, and H. H. Liu, Proc. R. Soc. Lond., A 454, 903-995, 1998.

  18. Linking geomagnetic activity and polar surface air temperature variability

    NASA Astrophysics Data System (ADS)

    Seppala, Annika

    ERA-40 and ECMWF operational surface level air temperature (SAT) data sets from 1957 to 2006 were used to examine polar temperature variations during years with different levels of geomagnetic activity, as defined by the Ap index. Previous modelling work has suggested that NOx produced at high latitudes by energetic particle precipitation can eventually lead to detectable changes in polar SATs. We find that during winter months, ERA-40 and ECMWF polar SATs in years with high Ap index are different than in years with low Ap index; the differences are statistically significant at the 2-sigma level and range up to about ±4.5 K, de-pending on location. The temperature differences are larger when years with wintertime Sudden Stratospheric Warmings are excluded. Solar irradiance variations were taken into account in the analysis. Although using the re-analysis and operational data sets it was not possible to conclusively show that the polar SAT patterns are physically linked by geomagnetic activity, we conclude that geomagnetic activity likely plays a role in modulating polar wintertime surface air temperature patterns. The SAT results were tested against variation in the Quasi Biennial Oscillation (QBO), the El Niño Southern Oscillation (ENSO) and the Southern Annular Mode n (SAM). The results suggested that these were not driving the observed polar SAT variability. However, significant uncertainty is introduced by the Northern Annular Mode (NAM) and we could not robustly exclude a chance linkage between sea surface temperature (SST) variability and geomagnetic activity. Examining the physical link between geomagnetic activity and polar surface temperature variability patterns using atmospheric models is an ongoing task.

  19. Variability of Winter Air Temperature in Mid-Latitude Europe

    NASA Technical Reports Server (NTRS)

    Otterman, J.; Ardizzone, J.; Atlas, R.; Bungato, D.; Cierniewski, J.; Jusem, J. C.; Przybylak, R.; Schubert, S.; Starr, D.; Walczewski, J.

    2002-01-01

    The aim of this paper is to report extreme winter/early-spring air temperature (hereinafter temperature) anomalies in mid-latitude Europe, and to discuss the underlying forcing to these interannual fluctuations. Warm advection from the North Atlantic in late winter controls the surface-air temperature, as indicated by the substantial correlation between the speed of the surface southwesterlies over the eastern North Atlantic (quantified by a specific Index Ina) and the 2-meter level air temperatures (hereinafter Ts) over Europe, 45-60 deg N, in winter. In mid-March and subsequently, the correlation drops drastically (quite often it is negative). This change in the relationship between Ts and Ina marks a transition in the control of the surface-air temperature: absorption of insolation replaces the warm advection as the dominant control. This forcing by maritime-air advection in winter was demonstrated in a previous publication, and is re-examined here in conjunction with extreme fluctuations of temperatures in Europe. We analyze here the interannual variability at its extreme by comparing warm-winter/early-spring of 1989/90 with the opposite scenario in 1995/96. For these two December-to-March periods the differences in the monthly mean temperature in Warsaw and Torun, Poland, range above 10 C. Short-term (shorter than a month) fluctuations of the temperature are likewise very strong. We conduct pentad-by-pentad analysis of the surface-maximum air temperature (hereinafter Tmax), in a selected location, examining the dependence on Ina. The increased cloudiness and higher amounts of total precipitable water, corollary effects to the warm low-level advection. in the 1989/90 winter, enhance the positive temperature anomalies. The analysis of the ocean surface winds is based on the Special Sensor Microwave/Imager (SSM/I) dataset; ascent rates, and over land wind data are from the European Centre for Medium-Range Weather Forecasts (ECMWF); maps of 2-m temperature, cloud

  20. Interaction of mid-latitude air masses with the polar dome area during RACEPAC and NETCARE

    NASA Astrophysics Data System (ADS)

    Bozem, Heiko; Hoor, Peter; Koellner, Franziska; Kunkel, Daniel; Schneider, Johannes; Schulz, Christiane; Herber, Andreas; Borrmann, Stephan; Wendisch, Manfred; Ehrlich, Andre; Leaitch, Richard; Willis, Megan; Burkart, Julia; Thomas, Jennie; Abbatt, Jon

    2016-04-01

    We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories as well as Flexpart particle dispersion modeling we analyze the transport regimes of mid-latitude air masses traveling to the high Arctic prevalent during spring (RACEPAC 2014, NETCARE 2015) and summer (NETCARE 2014). In general more northern parts of the high Arctic (Lat > 75°N) were relatively unaffected from mid-latitude air masses. In contrast, regions further south are influenced by air masses from Asia and Russia (eastern part of Canadian Arctic and European Arctic) as well as from North America (central and western parts of Canadian Arctic). The transition between the mostly isolated high Arctic and more southern regions indicated by tracer gradients is remarkably sharp. This allows for a chemical definition of the Polar dome based on the variability of CO and CO2 as a marker. Isentropic surfaces that slope from the surface to higher altitudes in the high Arctic form the polar dome that represents a transport barrier for mid-latitude air masses to enter the lower troposphere in the high Arctic. Synoptic-scale weather systems frequently disturb this transport barrier and foster the exchange between air masses from the mid-latitudes and polar regions. This can finally lead to enhanced pollution levels in the lower polar troposphere. Mid-latitude pollution plumes from biomass burning or flaring entering the polar dome area lead to an enhancement of 30% of the observed CO mixing ratio within the polar dome area.

  1. Mode Selection Techniques in Variable Mass Flexible Body Modeling

    NASA Technical Reports Server (NTRS)

    Quiocho, Leslie J.; Ghosh, Tushar K.; Frenkel, David; Huynh, An

    2010-01-01

    In developing a flexible body spacecraft simulation for the Launch Abort System of the Orion vehicle, when a rapid mass depletion takes place, the dynamics problem with time varying eigenmodes had to be addressed. Three different techniques were implemented, with different trade-offs made between performance and fidelity. A number of technical issues had to be solved in the process. This paper covers the background of the variable mass flexibility problem, the three approaches to simulating it, and the technical issues that were solved in formulating and implementing them.

  2. Comparative glacio-climatological analysis of mass balance variability along the geographical margin of Europe

    NASA Astrophysics Data System (ADS)

    Lehoczky, Annamária; Kern, Zoltán; Pongrácz, Rita

    2014-05-01

    Glacio-climatological studies recognise glacier mass balance changes as high-confident climate indicators. The climatic sensitivity of a glacier does not simply depend on regional climate variability but also influenced via large- and mesoscale atmospheric circulation patterns. This study focuses on recent changes in the mass balance using records from three border regions of Europe, and investigates the relationships between the seasonal mass balance components, regional climatic conditions, and distant atmospheric forcing. Since glaciers in different macro-climatological conditions (i.e., mid-latitudes or high-latitudes, dry-continental or maritime regions) may present strongly diverse mass balance characteristics, the three analysed regions were selected from different glacierised macroregions (using the database of the World Glacier Monitoring Service). These regions belong to the Caucasus Mountains (Central Europe macroregion), the Polar Ural (Northern Asia macroregion), and Svalbard (Arctic Islands macroregion). The analysis focuses on winter, summer, and annual mass balance series of eight glaciers. The climatic variables (atmospheric pressure, air temperature, precipitation) and indices of teleconnection patterns (e.g., North Atlantic Oscillation, Pacific Decadal Oscillation) are used from the gridded databases of the University of East Anglia, Climatic Research Unit and the National Oceanic and Atmospheric Administration, National Center for Environmental Prediction. However, the period and length of available mass balance data in the selected regions vary greatly (the first full record is in 1958, Polar Ural; the last is in 2010, Caucasus Mountains), a comparative analysis can be carried out for the period of 1968-1981. Since glaciers from different regions respond to large- and mesoscale climatic forcings differently, and because the mass balance of glaciers within a region often co-vary, our specific objectives are (i) to examine the variability and the

  3. Guide to transverse projections and mass-constraining variables

    SciTech Connect

    Barr, A. J.; Khoo, T. J.; Lester, C. G.; Konar, P.; Kong, K.; Matchev, K. T.; Park, M.

    2011-11-01

    This paper seeks to demonstrate that many of the existing mass-measurement variables proposed for hadron colliders (m{sub T}, m{sub eff}, m{sub T2}, missing p-vector{sub T}, h{sub T}, {radical}(s-circumflex){sub min}, etc.) are far more closely related to each other than is widely appreciated, and indeed can all be viewed as a common mass-bound specialized for a variety of purposes. A consequence of this is that one may understand better the strengths and weaknesses of each variable, and the circumstances in which each can be used to best effect. In order to achieve this, we find it necessary first to revisit the seemingly empty and infertile wilderness populated by the subscript 'T' (as in 'pe{sub T}') in order to remind ourselves what this process of transversification actually means. We note that, far from being simple, transversification can mean quite different things to different people. Those readers who manage to battle through the barrage of transverse notation distinguishing 'T' from 'v' or or from 'o', and 'early projection' from 'late projection', will find their efforts rewarded towards the end of the paper with (i) a better understanding of how collider mass variables fit together, (ii) an appreciation of how these variables could be generalized to search for things more complicated than supersymmetry, (iii) will depart with an aversion to thoughtless or naieve use of the so-called 'transverse methods' of any of the popular computer Lorentz-vector libraries, and (iv) will take care in their subsequent papers to be explicit about which of the 61 identified variants of the 'transverse mass' they are employing.

  4. Characterization of air profiles impeded by plant canopies for a variable-rate air-assisted sprayer

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The preferential design for variable-rate orchard and nursery sprayers relies on tree structure to control liquid and air flow rates. Demand for this advanced feature has been incremental as the public demand on reduction of pesticide use. A variable-rate, air assisted, five-port sprayer had been in...

  5. Analytical model for contaminant mass removal by air sparging

    SciTech Connect

    Rabideau, A.J.; Blayden, J.M.

    1998-12-31

    An analytical model was developed to predict the removal of volatile organic compounds (VOCs) from ground water by air sparging (AS). The model treats the air sparging zone as a completely mixed reactor subject to the removal of dissolved contaminants by volatilization, advection, and first-order decay. Nonequilibrium desorption is approximated as a first-order mass transfer process. The model reproduces the tailing and rebound behavior often observed at AS sites, and would normally require the estimation of three site-specific parameters. Dimensional analysis demonstrates that predicting tailing can be interpreted in terms of kinetic desorption or diffusion of aqueous phase contaminants into discrete air channels. Related work is ongoing to test the model against field data.

  6. Temporal variability of the Buenos Aires, Argentina, urban heat island

    NASA Astrophysics Data System (ADS)

    Camilloni, Inés; Barrucand, Mariana

    2012-01-01

    This paper describes the statistical characteristics and temporal variability of the urban heat island (UHI) intensity in Buenos Aires using 32-year surface meteorological data with 1-h time intervals. Seasonal analyses show that the UHI intensity is strongest during summer months and an "inverse" effect is found frequently during the afternoon hours of the same season. During winter, the UHI effect is in the minimal. The interannual trend and the seasonal variation of the UHI for the main synoptic hours for a longer record of 48 years are studied and associated to changes in meteorological factors as low-level circulation and cloud amount. Despite the population growth, it was found a negative trend in the nocturnal UHI intensity that could be explained by a decline of near clear-sky conditions, a negative trend in the calm frequencies and an increase in wind speed. Urban to rural temperature differences and rural temperatures are negatively correlated for diurnal and nocturnal hours both for annual and seasonal scales. This result is due to the lower interannual variability of urban temperatures in comparison to rural ones.

  7. The mass and speed dependence of meteor air plasma temperatures.

    PubMed

    Jenniskens, Peter; Laux, Christophe O; Wilson, Michael A; Schaller, Emily L

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  8. The mass and speed dependence of meteor air plasma temperatures

    NASA Technical Reports Server (NTRS)

    Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

    2004-01-01

    The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

  9. Air-kerma determination using a variable-volume cavity ionization chamber standard.

    PubMed

    Burns, D T; Kessler, C; Roger, P

    2007-12-01

    A graphite-walled cavity ionization chamber of modular design and variable volume has been used to determine the air-kerma rate in the reference 60Co field at the BIPM. The chamber can be configured in five sizes. High-accuracy mechanical measurements of the volume of the air cavity were made for each configuration using a co-ordinate measuring machine. Ionization current measurements were made for each configuration and corrected for the effects of ion recombination and diffusion, stem scatter and chamber orientation. Monte Carlo calculations of cavity dose were made to evaluate the correction factors kwall and kan. A reproducibility of the ionization current per mass of 1.5 parts in 10(4) was achieved on the repeated assembly of each configuration. The results show an air-kerma rate determination that increases with volume, the total change being around 8 parts in 10(4). When analysed differentially, the air-kerma rate relative to the BIPM standard is Kdiff/KBIPM = 1.0026(6). A detailed uncertainty budget is presented. Possible reasons for the observed behaviour are discussed that might have consequences for all existing standards for air-kerma.

  10. QUANTIFYING SUBGRID POLLUTANT VARIABILITY IN EULERIAN AIR QUALITY MODELS

    EPA Science Inventory

    In order to properly assess human risk due to exposure to hazardous air pollutants or air toxics, detailed information is needed on the location and magnitude of ambient air toxic concentrations. Regional scale Eulerian air quality models are typically limited to relatively coar...

  11. Disambiguating seesaw models using invariant mass variables at hadron colliders

    DOE PAGES

    Dev, P. S. Bhupal; Kim, Doojin; Mohapatra, Rabindra N.

    2016-01-19

    Here, we propose ways to distinguish between different mechanisms behind the collider signals of TeV-scale seesaw models for neutrino masses using kinematic endpoints of invariant mass variables. We particularly focus on two classes of such models widely discussed in literature: (i) Standard Model extended by the addition of singlet neutrinos and (ii) Left-Right Symmetric Models. Relevant scenarios involving the same "smoking-gun" collider signature of dilepton plus dijet with no missing transverse energy differ from one another by their event topology, resulting in distinctive relationships among the kinematic endpoints to be used for discerning them at hadron colliders. Furthermore, these kinematic endpoints are readily translated to the mass parameters of the on-shell particles through simple analytic expressions which can be used for measuring the masses of the new particles. We also conducted a Monte Carlo simulation with detector effects in order to test the viability of the proposed strategy in a realistic environment. Finally, we discuss the future prospects of testing these scenarios at themore » $$\\sqrt{s}$$ = 14 and 100TeV hadron colliders.« less

  12. Disambiguating seesaw models using invariant mass variables at hadron colliders

    NASA Astrophysics Data System (ADS)

    Dev, P. S. Bhupal; Kim, Doojin; Mohapatra, Rabindra N.

    2016-01-01

    We propose ways to distinguish between different mechanisms behind the collider signals of TeV-scale seesaw models for neutrino masses using kinematic endpoints of invariant mass variables. We particularly focus on two classes of such models widely discussed in literature: (i) Standard Model extended by the addition of singlet neutrinos and (ii) Left-Right Symmetric Models. Relevant scenarios involving the same "smoking-gun" collider signature of dilepton plus dijet with no missing transverse energy differ from one another by their event topology, resulting in distinctive relationships among the kinematic endpoints to be used for discerning them at hadron colliders. These kinematic endpoints are readily translated to the mass parameters of the on-shell particles through simple analytic expressions which can be used for measuring the masses of the new particles. A Monte Carlo simulation with detector effects is conducted to test the viability of the proposed strategy in a realistic environment. Finally, we discuss the future prospects of testing these scenarios at the √{s}=14 and 100 TeV hadron colliders.

  13. Assessing surface air temperature variability using quantile regression

    NASA Astrophysics Data System (ADS)

    Timofeev, A. A.; Sterin, A. M.

    2014-12-01

    Many researches in climate change currently involve linear trends, based on measured variables. And many of them only consider trends in mean values, whereas it is clear, that not only means, but also whole shape of distribution changes over time and requires careful assessment. For example extreme values including outliers may get bigger, while median has zero slope.Quantile regression provides a convenient tool, that enables detailed analysis of changes in full range of distribution by producing a vector of quantile trends for any given set of quantiles.We have applied quantile regression to surface air temperature observations made at over 600 weather stations across Russian Federation during last four decades. The results demonstrate well pronounced regions with similar values of significant trends in different parts of temperature value distribution (left tail, middle part, right tail). The uncertainties of quantile trend estimations for several spatial patterns of trends over Russia are estimated and analyzed for each of four seasons.For temperature trend estimation over vast territories, quantile regression is an effort consuming approach, but is more informative than traditional instrument, to assess decadal evolution of temperature values, including evolution of extremes.Partial support of ERA NET RUS ACPCA joint project between EU and RBRF 12-05-91656-ЭРА-А is highly appreciated.

  14. Newtonian Version of the Variable Mass Theory of Gravity

    NASA Astrophysics Data System (ADS)

    Carvalho, J. C.; Lima, J. A. S.

    1990-11-01

    RESUMEN. Se presenta una versi6n Newtoniana de los modelos cosmol6gicos espacialmente e isotr6picos con masa variable. La influencia de la variaci6n de masa en la evoluci6n de la funci6n de escala est establecida para el caso de un Universo lieno de polvo bajo Ia suposici6n de que esta variaci6n es un efecto estrictamente cosmol6jico. Se muestra que el hiperb6lico, parab6lico 0 el#ptico dcl movimiento de puede ser modificado a lo larjo de la expansi6n. ABSTRACT. This paper presents a Newtonian version of the spatially homojeneous and isotropic cosmolojical models with variable mass. The influence of the mass variation on the evolution of the scale function is established for the case of a dust-filled Universe under the assumption that this variation is a strict cosmolojical effect. It is shown that the hyperbolic, parabolic or elliptic character of the fluid motion can be modified alonj the expansion. Keq : COSMOLOGY

  15. Pulsation-Driven Mass Loss in Luminous Blue Variables

    NASA Astrophysics Data System (ADS)

    Guzik, J. A.; Cox, A. N.; Despain, K. M.

    2005-09-01

    We use a nonlinear hydrodynamics code (Cox & Ostlie 1993) that includes a nonlocal time-dependent convection treatment to explore the pulsation of massive star models (Mo=50 and 80 M⊙) (see also Guzik et al. 1997, 1998, 1999). We find that for high-mass models near the Humphreys-Davidson limit, pulsations can grow to large amplitudes, exceeding 100 km/sec in radial velocity. The pulsations are similar to those of the LBV microvariations, with periods of 5 to 50 days, and light curve variations of about 0.1 mag. Ionization of Fe-group elements is occurring in the envelope at 200,000-500,000 K, producing a convective region that transports a varying amount of the emergent luminosity during the pulsation cycle. Because convection takes some time to turn on and off during a pulsation cycle, the outgoing radiation is periodically dammed up, and the Eddington limit is exceeded locally for that part of the pulsation cycle. The impulse imparted to the outer layers causes a large abrupt increase in their outward motion, which may be the beginning of an LBV `outburst'. Rotation (not included in these models) will also lower the effective gravitational binding of the outer layers. Since the envelopes of these stars contain only ˜10-4 M⊙, this mechanism perhaps could initiate mass loss of at most a few times x 10-4 M⊙/yr, in agreement with observed mass loss rates of LBV stars during an outburst. It is likely that the mass loss rate would be variable, modulated by the build-up of pulsation amplitude, requiring several pulsation cycles to accelerate, and would occur in shells or clumps. We suggest that this mechanism is responsible for the winds and outbursts of `normal' LBV stars such as S Dor or AG Car (Humphreys & Davidson 1994).

  16. Functional forms for approximating the relative optical air mass

    NASA Astrophysics Data System (ADS)

    Rapp-Arrarás, Ígor; Domingo-Santos, Juan M.

    2011-12-01

    This article constitutes a review and systematic comparison of functional forms for approximating the air mass from the zenith to the horizon. Among them, we find the most meaningful forms in atmospheric optics, geophysics, meteorology, and solar energy science, as well as several forms arising from the study of the atmospheric delay of electromagnetic signals, whose relationship with the air mass was recently proved by the authors. In total, we have compared 26 functional forms, and the fits have been done for three atmospheric profiles, an observer at sea level, and the median wavelength of the Sun's spectral irradiance (0.7274 μm). As a result, the best of the uniparametric forms has more than three centuries of history; the best of the biparametric forms was recently introduced by one of the authors; the best of the tri- and tetraparametric forms were originally proposed for modeling the atmospheric delay of radio signals; and the best of the forms with more than four parameters is used here for the first time. On the basis of these, for the 1976 U.S. Standard Atmosphere (USSA-76), we provide one-, two-, three-, four-, and five-parameter formulas whose maximum deviations are 1.70, 2.91 × 10-1, 3.28 × 10-2, 2.49 × 10-3, and 3.24 × 10-4, respectively.

  17. The third-order Lagrange equation for mechanical systems of variable mass

    NASA Astrophysics Data System (ADS)

    Ma, Shan-Jun; Ge, Wei-Guo; Huang, Pei-Tian

    2005-05-01

    In this paper, based on the third-order D'Alembert-Lagrange principle for mechanical systems of variable mass, the third-order Lagrange equations of mechanical systems of variable mass are obtained. From the equations the motion of mechanical systems of variable mass can be studied. In addition, the equations may enrich the theory of third-order differential equation.

  18. An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

    NASA Astrophysics Data System (ADS)

    Zander, R.; Messina, A.; Godek, M. L.

    2012-12-01

    The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

  19. Modeling and Simulation of Variable Mass, Flexible Structures

    NASA Technical Reports Server (NTRS)

    Tobbe, Patrick A.; Matras, Alex L.; Wilson, Heath E.

    2009-01-01

    The advent of the new Ares I launch vehicle has highlighted the need for advanced dynamic analysis tools for variable mass, flexible structures. This system is composed of interconnected flexible stages or components undergoing rapid mass depletion through the consumption of solid or liquid propellant. In addition to large rigid body configuration changes, the system simultaneously experiences elastic deformations. In most applications, the elastic deformations are compatible with linear strain-displacement relationships and are typically modeled using the assumed modes technique. The deformation of the system is approximated through the linear combination of the products of spatial shape functions and generalized time coordinates. Spatial shape functions are traditionally composed of normal mode shapes of the system or even constraint modes and static deformations derived from finite element models of the system. Equations of motion for systems undergoing coupled large rigid body motion and elastic deformation have previously been derived through a number of techniques [1]. However, in these derivations, the mode shapes or spatial shape functions of the system components were considered constant. But with the Ares I vehicle, the structural characteristics of the system are changing with the mass of the system. Previous approaches to solving this problem involve periodic updates to the spatial shape functions or interpolation between shape functions based on system mass or elapsed mission time. These solutions often introduce misleading or even unstable numerical transients into the system. Plus, interpolation on a shape function is not intuitive. This paper presents an approach in which the shape functions are held constant and operate on the changing mass and stiffness matrices of the vehicle components. Each vehicle stage or component finite element model is broken into dry structure and propellant models. A library of propellant models is used to describe the

  20. High-Altitude Air Mass Zero Calibration of Solar Cells

    NASA Technical Reports Server (NTRS)

    Woodyard, James R.; Snyder, David B.

    2005-01-01

    Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

  1. Monitoring Trace Contaminants in Air Via Ion Trap Mass Spectrometry

    NASA Technical Reports Server (NTRS)

    Palmer, Peter T.; Karr, Dane; Pearson, Richard; Valero, Gustavo; Wong, Carla

    1995-01-01

    Recent passage of the Clean Air Act with its stricter regulation of toxic gas emissions, and the ever-growing number of applications which require faster turnaround times between sampling and analysis are two major factors which are helping to drive the development of new instrument technologies for in-situ, on-line, real-time monitoring. The ion trap, with its small size, excellent sensitivity, and tandem mass spectrometry capability is a rapidly evolving technology which is well-suited for these applications. In this paper, we describe the use of a commercial ion trap instrument for monitoring trace levels of chlorofluorocarbons (CFCs) and volatile organic compounds (VOCs) in air. A number of sample introduction devices including a direct transfer line interface, short column GC, and a cryotrapping interface are employed to achieve increasing levels of sensitivity. MS, MS/MS, and MS/MS/MS methods are compared to illustrate trade-offs between sensitivity and selectivity. Filtered Noise Field (FNF) technology is found to be an excellent means for achieving lower detection limits through selective storage of the ion(s) of interest during ionization. Figures of merit including typical sample sizes, detection limits, and response times are provided. The results indicate the potential of these techniques for atmospheric assessments, the High Speed Research Program, and advanced life support monitoring applications for NASA.

  2. Attenuating noise generated by variable-air-volume systems

    SciTech Connect

    Stokes, R.

    1985-03-01

    Sound generated by HVAC systems is receiving much attention because they are generally the principal contributors to room background sound levels that may become irritating and distracting noise if not controlled. This article discusses the creation of a quiet working environment through an analysis of the three traditional sound paths associated with air handling systems: radiated sound, inlet or return air sound and discharge sound. Recommended standards are given as well as a brief overview of materials used to fabricate HVAC system components.

  3. Investigating glacial mass balance variability around the Prince Gustav Channel

    NASA Astrophysics Data System (ADS)

    Royston, Samantha; Gudmundsson, Hilmar; Clarke, Lucy; Fox, Adrian

    2015-04-01

    Glaciers on the Antarctic Peninsula have shown a varied response to recent climatic change. Most commonly, AP tidewater glaciers have retreated at the calving front and their flow rate has accelerated, increasing the contribution to sea level rise. Here, we utilise the results from a new photogrammetric technique that unlocks the archives of aerial photography from the 1940's to present, to investigate the driving mechanisms of glacier mass change on the AP over this period. Surface DEMs at different epochs have been derived using the new technique for a number of individual glacier basins. A higher-order vertically-integrated ice stream model is used to investigate the driving mechanisms of change for the area around the Prince Gustav Channel, incorporating basins covered by the new datasets. The Prince Gustav Ice Shelf collapsed in January 1995, followed by significant frontal retreat and speed up of its tributary glaciers. Additionally, significant changes have been observed for non-tributary glaciers such as Whisky Glacier on James Ross Island. Here, we investigate the sensitivity of this region's glaciers to ice shelf collapse, atmospheric and oceanic variability.

  4. Interannual Variability of OLR as Observed by AIRS and CERES

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Molnar, Gyula; Iredell, Lena; Loeb, Norman G.

    2012-01-01

    This paper compares spatial anomaly time series of OLR (Outgoing Longwave Radiation) and OLR(sub CLR) (Clear Sky OLR) as determined using observations from CERES Terra and AIRS over the time period September 2002 through June 2011. Both AIRS and CERES show a significant decrease in global mean and tropical mean OLR over this time period. We find excellent agreement of the anomaly time-series of the two OLR data sets in almost every detail, down to 1 deg X 1 deg spatial grid point level. The extremely close agreement of OLR anomaly time series derived from observations by two different instruments implies that both sets of results must be highly stable. This agreement also validates to some extent the anomaly time series of the AIRS derived products used in the computation of the AIRS OLR product. The paper also examines the correlations of anomaly time series of AIRS and CERES OLR, on different spatial scales, as well as those of other AIRS derived products, with that of the NOAA Sea Surface Temperature (SST) product averaged over the NOAA Nino-4 spatial region. We refer to these SST anomalies as the El Nino Index. Large spatially coherent positive and negative correlations of OLR anomaly time series with that of the El Nino Index are found in different spatial regions. Anomalies of global mean, and especially tropical mean, OLR are highly positively correlated with the El Nino Index. These correlations explain that the recent global and tropical mean decreases in OLR over the period September 2002 through June 2011, as observed by both AIRS and CERES, are primarily the result of a transition from an El Nino condition at the beginning of the data record to La Nina conditions toward the end of the data period. We show that the close correlation of global mean, and especially tropical mean, OLR anomalies with the El Nino Index can be well accounted for by temporal changes of OLR within two spatial regions which lie outside the NOAA Nino-4 region, in which anomalies

  5. The variable immunological self: Genetic variation and nongenetic noise in Aire-regulated transcription

    PubMed Central

    Venanzi, Emily S.; Melamed, Rachel; Mathis, Diane; Benoist, Christophe

    2008-01-01

    The Aire transcription factor plays an important role in immunological self-tolerance by mediating the ectopic expression of peripheral self-antigens by thymic medullary epithelial cells (MECs), and the deletion of thymocytes that recognize them. In Aire-deficient humans or mice, central tolerance is incomplete and multiorgan autoimmune disease results. We examined the variability of Aire's effects on ectopic transcription among individual mice of three different inbred strains. Aire's function was, overall, quite similar in the three backgrounds, although generally stronger in C57BL/6 than in BALB/c or NOD mice, and a minority of Aire-regulated genes did show clear differences. Gene expression profiling of wild-type MECs from single mice, or from the two thymic lobes of the same mouse, revealed significantly greater variability in Aire-controlled ectopic gene expression than in Aire-independent transcripts. This “noisy” ectopic expression did not result from parental or early developmental imprinting, but from programming occurring after the formation of the thymic anlage, resulting from epigenetic effects or from the stochastic nature of Aire activity. Together, genetic and nongenetic variability in ectopic expression of peripheral antigens in the thymus make for differences in the portion of self determinants presented for tolerance induction. This variable self may be beneficial in preventing uniform holes in the T-cell repertoire in individuals of a species, but at the cost of variable susceptibility to autoimmunity. PMID:18838677

  6. Mass transfer of VOCs in laboratory-scale air sparging tank.

    PubMed

    Chao, Keh-Ping; Ong, Say Kee; Huang, Mei-Chuan

    2008-04-15

    Volatilization of VOCs was investigated using a 55-gal laboratory-scale model in which air sparging experiments were conducted with a vertical air injection well. In addition, X-ray imaging of an air sparging sand box showed air flows were in the form of air bubbles or channels depending on the size of the porous media. Air-water mass transfer was quantified using the air-water mass transfer coefficient which was determined by fitting the experimental data to a two-zone model. The two-zone model is a one-dimensional lumped model that accounts for the effects of air flow type and diffusion of VOCs in the aqueous phase. The experimental air-water mass transfer coefficients, KGa, obtained from this study ranged from 10(-2) to 10(-3)1/min. From a correlation analysis, the air-water mass transfer coefficient was found to be directly proportional to the air flow rate and the mean particle size of soil but inversely proportional to Henry's constant. The correlation results implied that the air-water mass transfer coefficient was strongly affected by the size of porous media and the air flow rates. PMID:17804158

  7. Mass balance and streamflow variability at Place Glacier, Canada, in relation to recent climate fluctuations

    NASA Astrophysics Data System (ADS)

    Moore, R. D.; Demuth, M. N.

    2001-12-01

    Although a great deal of research has focused on the hydrologic effects of climate variability and change, relatively little research has examined the effects on streamflow of interactions between climate variability and change and resulting glacier response. Place Glacier, in the southern Coast Mountains of British Columbia, Canada, has been monitored for mass balance since 1965, and a stream gauge was operated just below the glacier terminus from 1969 to 1989. This paper presents analyses of the mass balance history and streamflow variations in relation to recorded climatic variability.Place Glacier's winter and net balances are correlated with the Pacific Decadal Oscillation (PDO). Summer balance is positively correlated with summer temperature and negatively with the preceding winter balance, which enhances the effects of changes in winter balance on net balance. The well-documented post-1976 shift from the PDO cold phase to the present warm phase initiated a significant and persistent period of more negative net balance and terminal retreat. A reconstruction of net balance extending back to the 1890s, based on a regression with winter precipitation and summer temperature, displays decadal-scale fluctuations consistent with the PDO. Summer streamflow responded to interannual variations in winter snow accumulation and summer temperatures, which control the rate of rise of the glacier snowline and melt rates. After accounting for these influences via regression analysis, August streamflow displayed a negative trend in total runoff. Examination of air photographs and the reconstructed mass balance history suggest that significant firn depletion had occurred prior to 1965, such that the dominant effect of glacier changes was a reduction in ice area, resulting in decreased meltwater production.

  8. On the construction, comparison, and variability of airsheds for interpreting semivolatile organic compounds in passively sampled air.

    PubMed

    Westgate, John N; Wania, Frank

    2011-10-15

    Air mass origin as determined by back trajectories often aids in explaining some of the short-term variability in the atmospheric concentrations of semivolatile organic contaminants. Airsheds, constructed by amalgamating large numbers of back trajectories, capture average air mass origins over longer time periods and thus have found use in interpreting air concentrations obtained by passive air samplers. To explore some of their key characteristics, airsheds for 54 locations on Earth were constructed and compared for roundness, seasonality, and interannual variability. To avoid the so-called "pole problem" and to simplify the calculation of roundness, a "geodesic grid" was used to bin the back-trajectory end points. Departures from roundness were seen to occur at all latitudes and to correlate significantly with local slope but no strong relationship between latitude and roundness was revealed. Seasonality and interannual variability vary widely enough to imply that static models of transport are not sufficient to describe the proximity of an area to potential sources of contaminants. For interpreting an air measurement an airshed should be generated specifically for the deployment time of the sampler, especially when investigating long-term trends. Samples taken in a single season may not represent the average annual atmosphere, and samples taken in linear, as opposed to round, airsheds may not represent the average atmosphere in the area. Simple methods are proposed to ascertain the significance of an airshed or individual cell. It is recommended that when establishing potential contaminant source regions only end points with departure heights of less than ∼700 m be considered.

  9. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    PubMed

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  10. Kane's equations and Appell's equations for high order nonholonomic variable mass systems

    NASA Astrophysics Data System (ADS)

    Ge, Zheng-Ming; Wang, Tzu-Jun

    1991-04-01

    Based on the universal D'Alembert-Lagrange's principle for variable mass systems, by means of the new method of high-ordered variation, two forms of extended equations of motion are obtained for the high-ordered nonholonomic variable mass systems of which the corresponding conventional forms of equations of motion are the special cases. Kane's equations for high-ordered nonholonomic variable mass system are derived more naturally than Kane's original derivation in which the coefficients of generalized velocities are introduced somewhat artificially. Appell's equations expressed in energy of acceleration are extended for high-ordered nonholonomic variable mass systems.

  11. Variability of air ion concentrations in urban Paris

    NASA Astrophysics Data System (ADS)

    Dos Santos, V. N.; Herrmann, E.; Manninen, H. E.; Hussein, T.; Hakala, J.; Nieminen, T.; Aalto, P. P.; Merkel, M.; Wiedensohler, A.; Kulmala, M.; Petäjä, T.; Hämeri, K.

    2015-12-01

    Air ion concentrations influence new particle formation and consequently the global aerosol as potential cloud condensation nuclei. We aimed to evaluate air ion concentrations and characteristics of new particle formation events (NPF) in the megacity of Paris, France, within the MEGAPOLI (Megacities: Emissions, urban, regional and Global Atmospheric Pollution and climate effects, and Integrated tools for assessment and mitigation) project. We measured air ion number size distributions (0.8-42 nm) with an air ion spectrometer and fine particle number concentrations (> 6 nm) with a twin differential mobility particle sizer in an urban site of Paris between 26 June 2009 and 4 October 2010. Air ions were size classified as small (0.8-2 nm), intermediate (2-7 nm), and large (7-20 nm). The median concentrations of small and large ions were 670 and 680 cm-3, respectively, (sum of positive and negative polarities), whereas the median concentration of intermediate ions was only 20 cm-3, as these ions were mostly present during new particle formation bursts, i.e. when gas-to-particle conversion produced fresh aerosol particles from gas phase precursors. During peaks in traffic-related particle number, the concentrations of small and intermediate ions decreased, whereas the concentrations of large ions increased. Seasonal variations affected the ion population differently, with respect to their size and polarity. NPF was observed in 13 % of the days, being most frequent in spring and late summer (April, May, July, and August). The results also suggest that NPF was favoured on the weekends in comparison to workdays, likely due to the lower levels of condensation sinks in the mornings of weekends (CS weekdays 09:00: 18 × 10-3 s-1; CS weekend 09:00: 8 × 10-3 s-1). The median growth rates (GR) of ions during the NPF events varied between 3 and 7 nm h-1, increasing with the ion size and being higher on workdays than on weekends for intermediate and large ions. The median GR of

  12. Fume hood performance: Face velocity variability inconsistent air volume systems

    SciTech Connect

    Volin, C.E.; Joao, R.V.; Gershey, E.L.; Reiman, J.S.; Party, E.

    1998-09-01

    A 3-year survey of 366 bench-type fume hoods in working laboratories in conventional, constant air volume settings showed that face velocities varied greatly from unit to unit and over time. Fume hoods with bypasses performed better than those without; however, even newly fabricated bypass hoods exhibited large variations. These variations were due to several factors; however, face velocities at 100 {+-} 10 ft/min at working sash heights in the range of 20 to 40 cm (8 to 16 inches) were attainable. The use of smoke showed poor containment, especially at face velocities below 85 ft/min (0.425 m/s) or above 130 ft/min (0.65 m/s) and when the hoods were obstructed by large items placed on the work surface. Auxiliary/supplemental air created unstable face velocities and poor smoke patterns. The analysis of 3 years of fume hood monitoring showed clearly the need for and importance of a maintenance program where the fume hood lower slots are cleaned and fans, ducts, dampers, and hoods are checked periodically.

  13. Mathematical modeling of heat exchange between mine air and rock mass during fire

    SciTech Connect

    A.E. Krasnoshtein; B.P. Kazakov; A.V. Shalimov

    2006-05-15

    Solution of problems on heat exchange between ventilating air and rock mass and on gas admixture propagation in mine workings serve as a base for considering changes in heat-gas-air state at a mine after inflammation. The presented mathematical relations allow calculation of a varied velocity and movement direction of air flows, their temperatures and smoking conditions during fire.

  14. An objective definition of air mass types affecting Athens, Greece; the corresponding atmospheric pressure patterns and air pollution levels.

    PubMed

    Sindosi, O A; Katsoulis, B D; Bartzokas, A

    2003-08-01

    This work aims at defining characteristic air mass types that dominate in the region of Athens, Greece during the cold (November-March) and the warm (May-September) period of the year and also at evaluating the corresponding concentration levels of the main air pollutants. For each air mass type, the mean atmospheric pressure distribution (composite maps) over Europe and the Mediterranean is estimated in order to reveal the association of atmospheric circulation with air pollution levels in Athens. The data basis for this work consists of daily values of thirteen meteorological and six pollutant parameters covering the period 1993-97. The definition of the characteristic air mass types is attempted objectively by using the methods of Factor Analysis and Cluster Analysis. The results show that during the cold period of the year there are six prevailing air mass types (at least 3% of the total number of days) and six infrequent ones. The examination of the corresponding air pollution concentration levels shows that the primary air pollutants appear with increased concentrations when light or southerly winds prevail. This is usually the case when a high pressure system is located over the central Mediterranean or a low pressure system lays over south Italy, respectively. Low levels of the primary pollutants are recorded under northeasterly winds, mainly caused by a high pressure system over Ukraine. During the warm period of the year, the southwestern Asia thermal low and the subtropical anticyclone of the Atlantic Ocean affect Greece. Though these synoptic systems cause almost stagnant conditions, four main air mass types are dominant and ten others, associated with extreme weather, are infrequent. Despite the large amounts of total solar radiation characterizing this period, ozone concentrations remain at low levels in central Athens because of its destruction by nitric oxide.

  15. Into rude air: hummingbird flight performance in variable aerial environments.

    PubMed

    Ortega-Jimenez, V M; Badger, M; Wang, H; Dudley, R

    2016-09-26

    Hummingbirds are well known for their ability to sustain hovering flight, but many other remarkable features of manoeuvrability characterize the more than 330 species of trochilid. Most research on hummingbird flight has been focused on either forward flight or hovering in otherwise non-perturbed air. In nature, however, hummingbirds fly through and must compensate for substantial environmental perturbation, including heavy rain, unpredictable updraughts and turbulent eddies. Here, we review recent studies on hummingbirds flying within challenging aerial environments, and discuss both the direct and indirect effects of unsteady environmental flows such as rain and von Kármán vortex streets. Both perturbation intensity and the spatio-temporal scale of disturbance (expressed with respect to characteristic body size) will influence mechanical responses of volant taxa. Most features of hummingbird manoeuvrability remain undescribed, as do evolutionary patterns of flight-related adaptation within the lineage. Trochilid flight performance under natural conditions far exceeds that of microair vehicles at similar scales, and the group as a whole presents many research opportunities for understanding aerial manoeuvrability.This article is part of the themed issue 'Moving in a moving medium: new perspectives on flight'. PMID:27528777

  16. Interannual Variability of OLR as Observed by AIRS and CERES

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Molnar, Gyula I.; Iredell, Lena F.; Loeb, Norman G.

    2012-01-01

    The paper examines spatial anomaly time series of Outgoing Longwave Radiation (OLR) and Clear Sky OLR (OLR(sub CLR)) as determined using observations from CERES Terra and AIRS over the time period September 2002 through June 2011. We find excellent agreement of the two OLR data sets in almost every detail down to the x11deg spatial grid point level. The extremely close agreement of OLR anomaly time series derived from observations by two different instruments implies high stability of both sets of results. Anomalies of global mean, and especially tropical mean, OLR are shown to be strongly correlated with an El Nino index. These correlations explain that the recent global and tropical mean decreases in OLR over the time period studied are primarily the result of a transition from an El Nino condition at the beginning of the data record to La Nina conditions toward the end of the data period. We show that the close correlation of mean OLR anomalies with the El Nino Index can be well accounted for by temporal changes of OLR within two spatial regions, one to the east of, and one to the west of, the NOAA Nino-4 region. Anomalies of OLR in these two spatial regions are both strongly correlated with the El Nino Index as a result of the strong anti-correlation of anomalies of cloud cover and mid-tropospheric water vapor in these two regions with the El Nino Index.

  17. Into rude air: hummingbird flight performance in variable aerial environments.

    PubMed

    Ortega-Jimenez, V M; Badger, M; Wang, H; Dudley, R

    2016-09-26

    Hummingbirds are well known for their ability to sustain hovering flight, but many other remarkable features of manoeuvrability characterize the more than 330 species of trochilid. Most research on hummingbird flight has been focused on either forward flight or hovering in otherwise non-perturbed air. In nature, however, hummingbirds fly through and must compensate for substantial environmental perturbation, including heavy rain, unpredictable updraughts and turbulent eddies. Here, we review recent studies on hummingbirds flying within challenging aerial environments, and discuss both the direct and indirect effects of unsteady environmental flows such as rain and von Kármán vortex streets. Both perturbation intensity and the spatio-temporal scale of disturbance (expressed with respect to characteristic body size) will influence mechanical responses of volant taxa. Most features of hummingbird manoeuvrability remain undescribed, as do evolutionary patterns of flight-related adaptation within the lineage. Trochilid flight performance under natural conditions far exceeds that of microair vehicles at similar scales, and the group as a whole presents many research opportunities for understanding aerial manoeuvrability.This article is part of the themed issue 'Moving in a moving medium: new perspectives on flight'.

  18. Fume hood performance: Using a bypass in variable air volume systems

    SciTech Connect

    Joao, R.V.; Party, E.; Gershey, E.L.

    1998-10-01

    Variable air volume (VAV) exhaust systems provide sophisticated engineering controls for maintaining laboratory ventilation. Depending on how they are installed, they may be very responsive to changes in air flows and air pressures. Some of these changes are a consequence of natural phenomena and some are induced by the transit and actions of laboratory occupants. While the responsiveness of VAV controls can provide tight regulation, the dynamic nature of the VAV system may also introduce undesirable air flow fluctuations. Furthermore, since the volumes of air being exhausted vary, the amount of air available for fume hood capture and containment will also vary. These studies examine the responsiveness and consequences of ventilation system perturbations, as well as the effect of fume hood exhaust being reduced to very low air volumes. Face velocity and air volumes were measured at different sash heights and in response to rapid sash movements. In addition, capture of contaminants was evaluated at different sash heights by American National Standards Institute/American Society of Heating, Refrigerating, and Air-Conditioning Engineers 110-85 tests. The authors have found that at low sash heights the total volume of air may be reduced to a level that is insufficient to efficiently capture airborne contaminants. The addition of a fume hood bypass was necessary to ensure that the volume of air exhausted is sufficient to remove the contaminants present. Understanding the causes and characteristics of fume hood instabilities provides insight into how to prevent these perturbations.

  19. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  20. Temporal variability of mass transport across Canary Islands Channels

    NASA Astrophysics Data System (ADS)

    Marrero-Díaz, Ángeles; Rodríguez-Santana, Ángel; José Machín, Francisco; García-Weil, Luis; Sangrà, Pablo; Vélez-Belchí, Pedro; Fraile-Nuez, Eugenio

    2014-05-01

    The equatorward flowing Canary Current (CC) is the main feature of the circulation in the Canary Islands region. The CC flow perturbation by the Canary Islands originate the Canary Eddy Corridor which is the major pathway for long lived eddies in the subtropical North Atlantic (Sangrà et al., 2009, DSR). Therefore the variability of the CC passing through the Canary Archipelago will have both local and regional importance. Past studies on the CC variability trough the Canary Islands point out a clearly seasonal variability (Fraile-Nuez et al, 2010 (JGR); Hernández-Guerra et al, 2002 (DSR)). However those studies where focused on the eastern islands channels missing the variability through the western island channels which are the main source of long lived eddies. In order to fill this gap from November 2012 until September 2013 we conducted trimonthly surveys crossing the whole islands channels using opportunity ships (Naviera Armas Ferries). XBT and XCTD where launched along the cross channels transects. Additionally a closed box circling the Archipelago was performed on October 2013 as part of the cruise RAPROCAN-2013 (IEO) using also XBT and XCTD. Dynamical variables where derived inferring salinity from S(T,p) analytical relationships for the region updated with new XCTD data. High resolution, vertical sections of temperature, potential density, geostrophic velocity and transport where obtained. Our preliminary results suggest that the CC suffer a noticeable acceleration in those islands channels where eddy shedding is more frequent. They also indicate a clearly seasonal variability of the flows passing the islands channels. With this regard we observed significant differences on the obtained seasonal variability with respect the cited past studies on the eastern islands channel (Lanzarote / Fuerteventura - Africa coast). This work was co-funded by Canary Government (TRAMIC project: PROID20100092) and the European Union (FEDER).

  1. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Technical Reports Server (NTRS)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  2. A New Sample of Low-Mass AGNs Selected by X-ray Variability

    NASA Astrophysics Data System (ADS)

    Terashima, Yuichi

    2012-09-01

    We present results from our attempts to search for AGN containing relatively low-mass black holes (BHs) using X-ray variability. Variability time scales inversely correlate with black hole mass and can be used to select low-mass objects. We utilize the second XMM-Newton serendipitous source catalogue, which contains 262902 unique sources, to select highly variable objects. Black hole masses are derived by using the correlation between BH mass and normalized excess variance, where the effect of break in power spectra is properly taken into account. We present the sample selection and results of analysis including discovery of candidate low-mass AGNs with mass lower than 2e6 Msolar. We also present results on a peculiar AGN candidate showing soft thermal emission only found in our survey.

  3. Study on Variable Capacity Control Mechanism of Scroll Compressor for Automotive Air Conditioner

    NASA Astrophysics Data System (ADS)

    Hirano, Takahisa; Shigeoka, Tetsuo

    As for the automotive air conditioner, (1) to keep the automotive cabin temperature in a comfortable region, (2) to improve driving feeling, (3) to drive the air conditioning system economically through all seasons, are universally required. Recently, from these points, compressors with variable capacity control mechanism for automotive air conditioners have been remarkably requested. We have developed a scroll comoressor with variable capacity control mechanism. The capacity control mechanism, which changes the channel area of the bypass hole continuously, according to the suction gas pressure and the discharge gas pressure, has been developed. In this report, we describe the mechanism of variable capacity control and the performance simulation program that has been developed for the scroll compressor. Further, we describe the measuring results of cylinder pressure behavior, the results of energy loss analysis and the effect of comfort, drivability, power saving in the refrigerating cycle using the developed capacity control compressor.

  4. Variability of concentrations of polybrominated diphenyl ethers and polychlorinated biphenyls in air: implications for monitoring, modeling and control

    NASA Astrophysics Data System (ADS)

    Gouin, T.; Harner, T.; Daly, G. L.; Wania, F.; Mackay, D.; Jones, K. C.

    Monitoring data indicate that organic compounds with high octanol-air partition coefficients ( KOA), such as polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) exhibit seasonally variable air concentrations, especially during early spring, shortly after snow melt and before bud-burst when levels are elevated. This variability can complicate the interpretation of monitoring data designed to assess year-to-year changes. It is suggested that relatively simple dynamic multimedia mass balance models can assist interpretation by "factoring out" variability attributable to temperature and other seasonal effects as well as identifying likely contaminant sources. To illustrate this approach, high-volume air samples were collected from January to June, 2002 at a rural location in southern Ontario. Gas-phase concentrations for both ΣPBDE and ΣPCB rose from below the detection limit during the winter to 19 and 110 pg m -3, respectively, in early spring, only to decrease again following bud-burst. Passive air samples (PAS), deployed at seven urban, rural and remote sites for two one-month periods prior and following bud-burst, indicate a strong urban-rural gradient for both the PBDEs and PCBs. Calculated air concentrations from the PAS are shown to agree favorably with the high-volume air sampling data, with concentrations ranging 6-85 pg m -3 and 6-360 pg m -3 for ΣPBDE and ΣPCB, respectively. Concentrations in urban areas are typically 5 times greater than in rural locations. These data were interpreted using simulation results from a fate model including a seasonally variable forest canopy and snow pack, suggesting that the primary source is urban and that the "spring pulse" is the result of several interacting factors. Such contaminants are believed to be efficiently deposited in winter, accumulate in the snow pack and are released to terrestrial surfaces upon snow melt in spring. Warmer temperatures cause volatilization and a rise in air

  5. Computation of geographic variables for air pollution prediction models in South Korea

    PubMed Central

    Eum, Youngseob; Song, Insang; Kim, Hwan-Cheol; Leem, Jong-Han; Kim, Sun-Young

    2015-01-01

    Recent cohort studies have relied on exposure prediction models to estimate individuallevel air pollution concentrations because individual air pollution measurements are not available for cohort locations. For such prediction models, geographic variables related to pollution sources are important inputs. We demonstrated the computation process of geographic variables mostly recorded in 2010 at regulatory air pollution monitoring sites in South Korea. On the basis of previous studies, we finalized a list of 313 geographic variables related to air pollution sources in eight categories including traffic, demographic characteristics, land use, transportation facilities, physical geography, emissions, vegetation, and altitude. We then obtained data from different sources such as the Statistics Geographic Information Service and Korean Transport Database. After integrating all available data to a single database by matching coordinate systems and converting non-spatial data to spatial data, we computed geographic variables at 294 regulatory monitoring sites in South Korea. The data integration and variable computation were performed by using ArcGIS version 10.2 (ESRI Inc., Redlands, CA, USA). For traffic, we computed the distances to the nearest roads and the sums of road lengths within different sizes of circular buffers. In addition, we calculated the numbers of residents, households, housing buildings, companies, and employees within the buffers. The percentages of areas for different types of land use compared to total areas were calculated within the buffers. For transportation facilities and physical geography, we computed the distances to the closest public transportation depots and the boundary lines. The vegetation index and altitude were estimated at a given location by using satellite data. The summary statistics of geographic variables in Seoul across monitoring sites showed different patterns between urban background and urban roadside sites. This study

  6. Computation of geographic variables for air pollution prediction models in South Korea.

    PubMed

    Eum, Youngseob; Song, Insang; Kim, Hwan-Cheol; Leem, Jong-Han; Kim, Sun-Young

    2015-01-01

    Recent cohort studies have relied on exposure prediction models to estimate individuallevel air pollution concentrations because individual air pollution measurements are not available for cohort locations. For such prediction models, geographic variables related to pollution sources are important inputs. We demonstrated the computation process of geographic variables mostly recorded in 2010 at regulatory air pollution monitoring sites in South Korea. On the basis of previous studies, we finalized a list of 313 geographic variables related to air pollution sources in eight categories including traffic, demographic characteristics, land use, transportation facilities, physical geography, emissions, vegetation, and altitude. We then obtained data from different sources such as the Statistics Geographic Information Service and Korean Transport Database. After integrating all available data to a single database by matching coordinate systems and converting non-spatial data to spatial data, we computed geographic variables at 294 regulatory monitoring sites in South Korea. The data integration and variable computation were performed by using ArcGIS version 10.2 (ESRI Inc., Redlands, CA, USA). For traffic, we computed the distances to the nearest roads and the sums of road lengths within different sizes of circular buffers. In addition, we calculated the numbers of residents, households, housing buildings, companies, and employees within the buffers. The percentages of areas for different types of land use compared to total areas were calculated within the buffers. For transportation facilities and physical geography, we computed the distances to the closest public transportation depots and the boundary lines. The vegetation index and altitude were estimated at a given location by using satellite data. The summary statistics of geographic variables in Seoul across monitoring sites showed different patterns between urban background and urban roadside sites. This study

  7. Computation of geographic variables for air pollution prediction models in South Korea.

    PubMed

    Eum, Youngseob; Song, Insang; Kim, Hwan-Cheol; Leem, Jong-Han; Kim, Sun-Young

    2015-01-01

    Recent cohort studies have relied on exposure prediction models to estimate individuallevel air pollution concentrations because individual air pollution measurements are not available for cohort locations. For such prediction models, geographic variables related to pollution sources are important inputs. We demonstrated the computation process of geographic variables mostly recorded in 2010 at regulatory air pollution monitoring sites in South Korea. On the basis of previous studies, we finalized a list of 313 geographic variables related to air pollution sources in eight categories including traffic, demographic characteristics, land use, transportation facilities, physical geography, emissions, vegetation, and altitude. We then obtained data from different sources such as the Statistics Geographic Information Service and Korean Transport Database. After integrating all available data to a single database by matching coordinate systems and converting non-spatial data to spatial data, we computed geographic variables at 294 regulatory monitoring sites in South Korea. The data integration and variable computation were performed by using ArcGIS version 10.2 (ESRI Inc., Redlands, CA, USA). For traffic, we computed the distances to the nearest roads and the sums of road lengths within different sizes of circular buffers. In addition, we calculated the numbers of residents, households, housing buildings, companies, and employees within the buffers. The percentages of areas for different types of land use compared to total areas were calculated within the buffers. For transportation facilities and physical geography, we computed the distances to the closest public transportation depots and the boundary lines. The vegetation index and altitude were estimated at a given location by using satellite data. The summary statistics of geographic variables in Seoul across monitoring sites showed different patterns between urban background and urban roadside sites. This study

  8. Interdecadal linkages between Pacific decadal oscillation and interhemispheric air mass oscillation and their possible connections with East Asian Monsoon

    NASA Astrophysics Data System (ADS)

    Lu, C.

    2015-12-01

    The Pacific decadal oscillation (PDO) recently emerged in the literature as a robust signal in the Northern Hemisphere climate variability. Many studies reported that the relationships between PDO and East Asian monsoon (EAM) and climate variability in China are significant. However, the possible mechanisms are still unclear. The present study investigates the interdecadal relationship between Pacific decadal oscillation (PDO) and interhemispheric air mass imbalance or oscillation (IHO) between the Northern and Southern Hemispheres. The possible connection of PDO and IHO with both East Asian monsoon and climate variability in China are also assessed in this study. It is found that the interdecadal components (11-38 years) of PDO, IHO, and EAM contribute large variance to low frequency variations, and they are well-matched with each other on (inter)decadal timescale. In particular, their negative phases mainly appeared in the 1970s and late 1990s, while positive phase in period from 1980s to mid 1990s. Decadal change of global mean air columnar temperature may be the key factor for the notable difference between PDO and IHO from mid 1970s to mid 1990s. The spatial distributions of PDO and IHO associated surface air temperature and surface pressure anomalies exhibit highly similar and large scale characteristics, indicative of their intimate linkage with air mass redistribution over global domain especially over 300S-500N. The PDO associated columnar integral of velocity potential anomalies that maintain the air mass redistribution, show a dipole pattern with air mass flux emanating mainly from the eastern hemisphere to the Pacific regions in positive PDO phase. This contributes to hemispherical and land-sea mass exchange and redistribution, and also leads to the decadal displacement of both upward and downward branch of Walker circulation. In positive phase of PDO, an anomalous anticyclone is found in the Mongolian region in both boreal summer and winter seasons

  9. Observational Sensitivity to Climate Variability using AIRS/Aqua and MERRA

    NASA Astrophysics Data System (ADS)

    Hearty, T. J.; Fetzer, E.; Tian, B.; Yung, Y. L.; Vollmer, B.; Savtchenko, A. K.; Smith, P. M.; Theobald, M.; Ostrenga, D.

    2011-12-01

    The El Nino Southern Oscillation (ENSO) and North Atlantic Oscillation (NAO) are two of the largest climate variabilities seen in AIRS observations of temperature, water vapor, and clouds. Numerous climate feedbacks are involved in these oscillations. We examine these oscillations using observations from the Atmospheric Infrared Sounder (AIRS) and the Modern Era Retrospective-Analysis for Research and Applications (MERRA). Since sampling can be an issue for infrared satellites in low earth orbit, we examine the MERRA data sampled at the AIRS space-time locations both with and without the AIRS quality control. We estimate the sampling bias of an AIRS climatology and the atmospheric conditions where AIRS has a lower sampling rate and examine the apparent differences in the ENSO and NAO based on the different sampling. While the AIRS temperature and water vapor sampling biases are small at low latitudes, they can be more than a few degrees in temperature and 10 percent in water vapor at higher latitudes. While these numbers are small they can be important for understanding climate variability.

  10. [The analysis of the causes of variability of the relationship between leaf dry mass and area in plants].

    PubMed

    Vasfilov, S P

    2011-01-01

    The lamina dry mass: area ratio (LMA - Leaf Mass per Area) is a quite variable trait. Leaf dry mass consists of symplast mass (a set of all leaf protoplasts) and apoplast mass (a set of all cell walls in a leaf). The ratio between symplast and apoplast masses is positively related to any functional trait of leaf calculated per unit of dry mass. The value of this ratio is defined by cells size and their number per unit of leaf area, number of mesophyll cells layers and their differentiation between palisade and spongy ones, and also by density of cells packing. The LMA value is defined by leaf thickness and density. The extent and direction of variability in both leaf traits define the extent and direction of variability in LMA. Negative correlation between leaf thickness and density reduces the level of LMA variability. As a consequence of this correlation the following pattern emerges: the thinner a leaf, the denser it is. Changes in the traits that define the LMA value take place both within a species under the influence of environmental factors and between species that differ in leaf structure and functions. Light is the most powerful environmental factor that influences the LMA, increase in illumination leading to increase in LMA. This effect occurs during leaf growth at the expense of structural changes associated with the reduction of symplast/apoplast mass ratio. Under conditions of intense illumination, LMA may increase due to accumulation of starch. With regard to the majority of leaf functions, the mass of starch may be ascribed to apoplast. Starch accumulation in leaves is observed also under conditions of elevated CO2 concentration in the air. Under high illumination, however, LMA increases also due to increased apoplast contribution to leaf dry mass. Scarce mineral nutrition leads to LMA increase due to lowering of growth zones demands for phothosyntates and, therefore, to increase in starch content of leaves. High level of mineral nutrition during

  11. The water mass variability on the Romanian Black Sea shelf

    NASA Astrophysics Data System (ADS)

    Buga, Luminita; Mihailov, Maria-Emanuela; Malciu, Viorel; Stefan, Sabina

    2013-04-01

    The long-term trends in the water mass thermohaline structure and the effect of Danube River freshwater discharge into the western Black Sea during the last four decades (1971 - 2010) are analyzed using the data collected on the Romanian shelf (NIMRD data base). The variations of the temperature and salinity over the studied period are relatively small. The temperature data reveal a slightly warming trend for the upper mixed layer (UML) while for the shelf cold water (SCW) - identified by the 8˚C upper isotherm depth - thermohaline structure remains practically constant. At the same time the salinity exhibits a decreasing trend in the entire water column.

  12. The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

    ERIC Educational Resources Information Center

    Driscoll, John N.; Warneck, Peter

    1973-01-01

    Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

  13. Mammalian laryngseal air sacs add variability to the vocal tract impedance: Physical and computational modeling

    PubMed Central

    Riede, Tobias; Tokuda, Isao T.; Munger, Jacob B.; Thomson, Scott L.

    2008-01-01

    Cavities branching off the main vocal tract are ubiquitous in nonhumans. Mammalian air sacs exist in human relatives, including all four great apes, but only a substantially reduced version exists in humans. The present paper focuses on acoustical functions of the air sacs. The hypotheses are investigated on whether the air sacs affect amplitude of utterances and∕or position of formants. A multilayer synthetic model of the vocal folds coupled with a vocal tract model was utilized. As an air sac model, four configurations were considered: open and closed uniform tube-like side branches, a rigid cavity, and an inflatable cavity. Results suggest that some air sac configurations can enhance the sound level. Furthermore, an air sac model introduces one or more additional resonance frequencies, shifting formants of the main vocal tract to some extent but not as strongly as previously suggested. In addition, dynamic range of vocalization can be extended by the air sacs. A new finding is also an increased variability of the vocal tract impedance, leading to strong nonlinear source-filter interaction effects. The experiments demonstrated that air-sac-like structures can destabilize the sound source. The results were validated by a transmission line computational model. PMID:18647005

  14. What you must do for a quieter VAV system. [Variable air volume

    SciTech Connect

    Brandenburg, J.; Dudley, J.

    1982-04-01

    Application guidelines that incorporate acoustic considerations for variable air volume (VAV) ventilation systems are presented, ventilation system that save energy. Ideas discussed have a solid theoretical base and have been modified after experience with actual VAV systems. They represent the best applicational experience from more than 15,000 VAV system installations. How VAV noise sources are found, measured, and silenced is described.

  15. DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

    EPA Science Inventory

    The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

  16. Experimental Determination of the Mass of Air Molecules from the Law of Atmospheres.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Galvin, Vincent, Jr.

    1979-01-01

    A gas pressure gauge has been constructed for use in a student experiment involving the law of atmospheres. From pressure data obtained at selected elevations the average mass of air molecules is determined and compared to that calculated from the molecular weights and percentages of constituents to the air. (Author/BB)

  17. Improving microbial air quality in air-conditioned mass transport buses by opening the bus exhaust ventilation fans.

    PubMed

    Luksamijarulkul, Pipat; Arunchai, Nongphon; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2005-07-01

    The air quality in air-conditioned mass transport buses may affect bus drivers' health. In-bus air quality improvement with the voluntary participation of bus drivers by opening the exhaust ventilation fans in the bus was implemented in the Seventh Bus Zone of Bangkok Mass Transit Authority. Four bus numbers, including bus numbers 16, 63, 67 and 166, were randomly selected to investigate microbial air quality and to observe the effect of opening the exhaust ventilation fans in the bus. With each bus number, 9 to 10 air-conditioned buses (total, 39 air-conditioned buses) were included. In-bus air samples were collected at 5 points in each studied bus using the Millipore Air Tester. A total of 195 air samples were cultured for bacterial and fungal counts. The results reveal that the exhaust ventilation fans of 17 air-conditioned buses (43.6%) were opened to ventilate in-bus air during the cycle of the bus route. The means +/- SD of bacterial counts and fungal counts in the studied buses with opened exhaust ventilation fans (83.8 +/- 70.7 and 38.0 +/- 42.8 cfu/m3) were significantly lower than those in the studied buses without opened exhaust ventilation fans (199.6 +/- 138.8 and 294.1 +/- 178.7 cfu/m3), p < 0.0005. All the air samples collected from the studied buses with opened exhaust ventilation fans were at acceptable levels (< 500 cfu/m3) compared with 4.6% of the air samples collected from the studied buses without opened exhaust ventilation fans, which had high levels (> 500 cfu/m3). Of the studied buses with opened exhaust ventilation fans (17 buses), the bacterial and fungal counts after opening the exhaust ventilation fans (68.3 +/- 33.8 and 28.3 +/- 19.3 cfu/m3) were significantly lower than those before opening the exhaust ventilation fans (158.3 +/- 116.9 and 85.3 +/- 71.2 cfu/m3), p < 0.005.

  18. Variability And Mass-loss From Agb Stars In The Lmc

    NASA Astrophysics Data System (ADS)

    Riebel, David; Meixner, M.; Srinivasan, S.; Fraser, O.; Babler, B.; Block, M.; Bracker, S.; Engelbracht, S.; Gordon, K.; Hora, J.; Indebetouw, R.; Leitherer, C.; Meade, M.; Misselt, K.; Whitney, B.; Sewilo, M.; Vijh, U.

    2009-01-01

    Mass loss from evolved stars on the Asymptotic Giant Branch (AGB) is an important factor in both stellar and galactic evolution; the total amount of mass lost determines the star's eventual fate as a compact object and plays a significant role in the chemical enrichment of the interstellar medium. We combine excess infrared emission derived by Srinivasan et al. (2008) from the Spitzer SAGE survey of the LMC (Meixner, et al. 2006) with variability parameters derived from the MACHO survey (Fraser, et al. 2008, in press) to examine the effects of stellar variability on mass loss from evolved stars on the AGB. We find that stellar populations differing in chemical composition show different relationships between mass loss and the period and amplitude of variation, while general trends of increasing mass loss with increasing variability are visible in all populations.

  19. Atmospheric Parameter Climatologies from AIRS: Monitoring Short-, and Longer-Term Climate Variabilities and 'Trends'

    NASA Technical Reports Server (NTRS)

    Molnar, Gyula; Susskind, Joel

    2008-01-01

    The AIRS instrument is currently the best space-based tool to simultaneously monitor the vertical distribution of key climatically important atmospheric parameters as well as surface properties, and has provided high quality data for more than 5 years. AIRS analysis results produced at the GODDARD/DAAC, based on Versions 4 & 5 of the AIRS retrieval algorithm, are currently available for public use. Here, first we present an assessment of interrelationships of anomalies (proxies of climate variability based on 5 full years, since Sept. 2002) of various climate parameters at different spatial scales. We also present AIRS-retrievals-based global, regional and 1x1 degree grid-scale "trend"-analyses of important atmospheric parameters for this 5-year period. Note that here "trend" simply means the linear fit to the anomaly (relative the mean seasonal cycle) time series of various parameters at the above-mentioned spatial scales, and we present these to illustrate the usefulness of continuing AIRS-based climate observations. Preliminary validation efforts, in terms of intercomparisons of interannual variabilities with other available satellite data analysis results, will also be addressed. For example, we show that the outgoing longwave radiation (OLR) interannual spatial variabilities from the available state-of-the-art CERES measurements and from the AIRS computations are in remarkably good agreement. Version 6 of the AIRS retrieval scheme (currently under development) promises to further improve bias agreements for the absolute values by implementing a more accurate radiative transfer model for the OLR computations and by improving surface emissivity retrievals.

  20. Equations of motion for the variable mass flow-variable exhaust velocity rocket

    NASA Technical Reports Server (NTRS)

    Tempelman, W. H.

    1972-01-01

    An equation of motion for a one dimensional rocket is derived as a function of the mass flow rate into the acceleration chamber and the velocity distribution along the chamber, thereby including the transient flow changes in the chamber. The derivation of the mass density requires the introduction of the special time coordinate. The equation of motion is derived from both classical force and momentum approaches and is shown to be consistent with the standard equation expressed in terms of flow parameters at the exit to the acceleration chamber.

  1. Is volcanic air pollution associated with decreased heart-rate variability?

    PubMed Central

    Chow, Dominic C; Grandinetti, Andrew; Fernandez, Ed; Sutton, A J; Elias, Tamar; Brooks, Barbara; Tam, Elizabeth K

    2010-01-01

    Objectives To determine the autonomic cardiovascular control among residents of Hawaii who are exposed to varying levels of volcanic air pollution (vog), which consists largely of sulfur dioxide (SO2) and acid aerosols. Methods In a cross-sectional study between April 2006 and June 2008, the authors measured cardiovagal autonomic function by heart-rate variability (HRV) in 72 healthy individuals who lived in four exposure zones on Hawaii Island: vog-free (n=18); episodic exposure to SO2 >200 ppb and acid aerosol (n=19); chronic exposure to SO2 ≥30 ppb and acid aerosol (n=15); and chronic exposure to acid aerosols (n=20). Individuals with diabetes or heart disease, or who had smoked in the preceding month were excluded. HRV was measured in all subjects during rest, paced breathing and active standing (Ewing manoeuvre). HRV was analysed in time and frequency domains and compared between the four exposure zones. Results There were no significant differences between exposure zones in HRV, in either time or frequency domains, even after adjustment for age, gender, ethnicity and body mass index. There was no significant HRV change in three individuals in whom HRV was measured before and during an exposure to combined SO2 100–250 ppb and concentration of respirable particles of diameter ≤2.5 μ (PM2.5) >500 μg/m3. Age was significantly correlated with time-domain parameters during paced breathing and the Ewing manoeuvre. Conclusions This study of healthy individuals found no appreciable effects of vog on the autonomic nervous system. PMID:21546995

  2. Is volcanic air pollution associated with decreased heart-rate variability?

    PubMed

    Chow, Dominic C; Grandinetti, Andrew; Fernandez, Ed; Sutton, A J; Elias, Tamar; Brooks, Barbara; Tam, Elizabeth K

    2010-02-23

    OBJECTIVES: To determine the autonomic cardiovascular control among residents of Hawaii who are exposed to varying levels of volcanic air pollution (vog), which consists largely of sulfur dioxide (SO(2)) and acid aerosols. METHODS: In a cross-sectional study between April 2006 and June 2008, the authors measured cardiovagal autonomic function by heart-rate variability (HRV) in 72 healthy individuals who lived in four exposure zones on Hawaii Island: vog-free (n=18); episodic exposure to SO(2) >200 ppb and acid aerosol (n=19); chronic exposure to SO(2) ≥30 ppb and acid aerosol (n=15); and chronic exposure to acid aerosols (n=20). Individuals with diabetes or heart disease, or who had smoked in the preceding month were excluded. HRV was measured in all subjects during rest, paced breathing and active standing (Ewing manoeuvre). HRV was analysed in time and frequency domains and compared between the four exposure zones. RESULTS: There were no significant differences between exposure zones in HRV, in either time or frequency domains, even after adjustment for age, gender, ethnicity and body mass index. There was no significant HRV change in three individuals in whom HRV was measured before and during an exposure to combined SO(2) 100-250 ppb and concentration of respirable particles of diameter ≥2.5 μ (PM(2.5)) >500 μg/m(3). Age was significantly correlated with time-domain parameters during paced breathing and the Ewing manoeuvre. CONCLUSIONS: This study of healthy individuals found no appreciable effects of vog on the autonomic nervous system. PMID:21546995

  3. Large-Scale Atmospheric Variability in AIRS CO2 and O3

    NASA Astrophysics Data System (ADS)

    Li, Q.; Jiang, X.; Chahine, M.; Yung, Y.; Olsen, E.; Chen, L.

    2006-12-01

    We present a modeling analysis of carbon dioxide (CO2) and ozone (O3) from AIRS with results from two atmospheric chemistry and transport models (CTMs), in the context of the large-scale atmospheric transport. AIRS data, from selected periods in 2003 are retrieved applying the Vanishing Partial Derivative (VPD) method (Chahine et al. [GRL, 2005] and the presentation by Chahine et al., this meeting). Corresponding model results are simulated by 2-D and 3-D atmospheric CTMs. The AIRS retrieved and model simulated CO2 mixing ratios, averaged over 300-500 hPa, are compared with the Matsueda et al. observations in the tropics between 9 and 13 km (see the presentation by Jiang et al., this meeting). The latitudinal distributions of O3, both retrieved and simulated, are compared with ozonesonde data. Both comparisons show reasonable agreement. We then examine the spatiotemporal variabilities of CO2 and O3 and their correlation, both in the AIRS data and model results. Our objective is to better understand the AIRS observed atmospheric variability in CO2 that is associated with underlying large-scale atmospheric transport, particularly the stratosphere-troposphere- exchange (STE) at northern high latitudes in spring and the Asian monsoon summer circulation over South Asia.

  4. Near-infrared Variability in the 2MASS Calibration Fields: A Search for Planetary Transit Candidates

    NASA Technical Reports Server (NTRS)

    Plavchan, Peter; Jura, M.; Kirkpatrick, J. Davy; Cutri, Roc M.; Gallagher, S. C.

    2008-01-01

    The Two Micron All Sky Survey (2MASS) photometric calibration observations cover approximately 6 square degrees on the sky in 35 'calibration fields,' each sampled in nominal photometric conditions between 562 and 3692 times during the 4 years of the 2MASS mission. We compile a catalog of variables from the calibration observations to search for M dwarfs transited by extrasolar planets. We present our methods for measuring periodic and nonperiodic flux variability. From 7554 sources with apparent K(sub s) magnitudes between 5.6 and 16.1, we identify 247 variables, including extragalactic variables and 23 periodic variables. We have discovered three M dwarf eclipsing systems, including two candidates for transiting extrasolar planets.

  5. Active Flow Control Integrated Diffuser for increased Energy Efficiency in Variable Air Volume Systems

    NASA Astrophysics Data System (ADS)

    van der Schijff, Hermanus; Menicovich, David; Vollen, Jason; Amitay, Michael

    2013-11-01

    An experimental investigation was performed to study the application of flow control on an HVAC diffuser using synthetic jets distributed evenly along the diffuser edges. The study was conducted on 1:3 scale typical office space (150 ft2) , which included a simulated scale HVAC system supplied by compressed air. Two different jet momentum coefficients were investigated for two inlet flow rates of 40 and 60 CFM. The flow field was measured using hot wire anemometry and Particle Image Velocimetry. Current Variable Air Volume HVAC systems vary the incoming airflow to adjust to changing temperature conditions in the conditioned space. However, when the air flow rate drops below ideal, air distribution becomes inefficient. This study demonstrates the effectiveness of synthetic jets at controlling the incoming airflow and the distribution in the room, showing ability to affect throw coefficient parameters for different flow rates within the test chamber. The use of such devices has the potential to improve air quality and air distribution in building while simultaneously lowering energy demands of HVAC systems.

  6. Aerial observations of air masses transported from East Asia to the Western Pacific: Vertical structure of polluted air masses

    NASA Astrophysics Data System (ADS)

    Hatakeyama, Shiro; Ikeda, Keisuke; Hanaoka, Sayuri; Watanabe, Izumi; Arakaki, Takemitsu; Bandow, Hiroshi; Sadanaga, Yasuhiro; Kato, Shungo; Kajii, Yoshizumi; Zhang, Daizhou; Okuyama, Kikuo; Ogi, Takashi; Fujimoto, Toshiyuki; Seto, Takafumi; Shimizu, Atsushi; Sugimoto, Nobuo; Takami, Akinori

    2014-11-01

    There has been only limited information about the vertical chemical structure of the atmosphere, so far. We conducted aerial observations on 11, 12, and 14 December 2010 over the northern part of the East China Sea to analyze the spatial distribution of atmospheric pollutants from East Asia and to elucidate transformation processes of air pollutants during the long-range transport. On 11 December, a day on which Asian dust created hazy conditions, the average PM10 concentration was 40.69 μg m-3, and we observed high concentrations of chemical components such as Ca2+, NO3-, SO42-, Al, Ca, Fe, and Zn. The height of the boundary layer was about 1200 m, and most species of pollutants (except for dust particles and SO2) had accumulated within the boundary layer. In contrast, concentrations of pollutants were low in the boundary layer (up to 1000 m) on 12 December because clean Pacific air from the southeast had diluted the haze. However, we observed natural chemical components (Na+, Cl-, Al, Ca, and Fe) at 3000 m, the indication being that dust particles, including halite, were present in the lower free troposphere. On 14 December, peak concentrations of SO2 and black carbon were measured within the boundary layer (up to 700 m) and at 2300 m. The concentrations of anthropogenic chemical components such as NO3-, NH4+, and Zn were highest at 500 m, and concentrations of both anthropogenic and natural chemical components (SO42-, Pb, Ca2+, Ca, Al, and Fe) were highest at 2000 m. Thus, it was clearly indicated that the air above the East China Sea had a well-defined, layered structure below 3000 m.

  7. Movement simulation of the variable masses in the Gylden-Meshcherskii problem

    SciTech Connect

    Starinova, Olga L.; Salmin, Vadim V.

    2014-12-10

    The Gylden-Meshcherskii problem is used for various cases of dynamics of two points of the variable mass. For example, it describes of double star evolution due to mass loss at the photon expense and the corpuscular activity. Except, it is mathematical model for the movement of spacecraft with propulsion system. In the present work the mass variation laws, allowing a stationary form of the movement differential equations are considered. Movement simulation for all cases was conducted. The relative movement trajectories was constructed as for known Eddington-Jeans laws and for other mass variation laws.

  8. Temporal variability of air-sea CO2 exchange in a low-emission estuary

    NASA Astrophysics Data System (ADS)

    Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

    2016-07-01

    There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

  9. Burner rig study of variables involved in hole plugging of air cooled turbine engine vanes

    NASA Technical Reports Server (NTRS)

    Deadmore, D. L.; Lowell, C. E.

    1983-01-01

    The effects of combustion gas composition, flame temperatures, and cooling air mass flow on the plugging of film cooling holes by a Ca-Fe-P-containing deposit were investigated. The testing was performed on film-cooled vanes exposed to the combustion gases of an atmospheric Mach 0.3 burner rig. The extent of plugging was determined by measurement of the open hole area at the conclusion of the tests as well as continuous monitoring of some of the tests using stop-action photography. In general, as the P content increased, plugging rates also increased. The plugging was reduced by increasing flame temperature and cooling air mass flow rates. At times up to approximately 2 hours little plugging was observed. This apparent incubation period was followed by rapid plugging, reaching in several hours a maximum closure whose value depended on the conditions of the test.

  10. Using Mobile Monitoring to Assess Spatial Variability in Urban Air Pollution Levels: Opportunities and Challenges (Invited)

    NASA Astrophysics Data System (ADS)

    Larson, T.

    2010-12-01

    Measuring air pollution concentrations from a moving platform is not a new idea. Historically, however, most information on the spatial variability of air pollutants have been derived from fixed site networks operating simultaneously over space. While this approach has obvious advantages from a regulatory perspective, with the increasing need to understand ever finer scales of spatial variability in urban pollution levels, the use of mobile monitoring to supplement fixed site networks has received increasing attention. Here we present examples of the use of this approach: 1) to assess existing fixed-site fine particle networks in Seattle, WA, including the establishment of new fixed-site monitoring locations; 2) to assess the effectiveness of a regulatory intervention, a wood stove burning ban, on the reduction of fine particle levels in the greater Puget Sound region; and 3) to assess spatial variability of both wood smoke and mobile source impacts in both Vancouver, B.C. and Tacoma, WA. Deducing spatial information from the inherently spatio-temporal measurements taken from a mobile platform is an area that deserves further attention. We discuss the use of “fuzzy” points to address the fine-scale spatio-temporal variability in the concentration of mobile source pollutants, specifically to deduce the broader distribution and sources of fine particle soot in the summer in Vancouver, B.C. We also discuss the use of principal component analysis to assess the spatial variability in multivariate, source-related features deduced from simultaneous measurements of light scattering, light absorption and particle-bound PAHs in Tacoma, WA. With increasing miniaturization and decreasing power requirements of air monitoring instruments, the number of simultaneous measurements that can easily be made from a mobile platform is rapidly increasing. Hopefully the methods used to design mobile monitoring experiments for differing purposes, and the methods used to interpret those

  11. Modeling Spatial and Temporal Variability of Residential Air Exchange Rates for the Near-Road Exposures and Effects of Urban Air Pollutants Study (NEXUS)

    EPA Science Inventory

    Air pollution health studies often use outdoor concentrations as exposure surrogates. Failure to account for variability of residential infiltration of outdoor pollutants can induce exposure errors and lead to bias and incorrect confidence intervals in health effect estimates. Th...

  12. Stability of libration points in the restricted four-body problem with variable mass

    NASA Astrophysics Data System (ADS)

    Mittal, Amit; Aggarwal, Rajiv; Suraj, Md. Sanam; Bisht, Virender Singh

    2016-10-01

    We have investigated the stability of the Lagrangian solutions for the restricted four-body problem with variable mass. It has been assumed that the three primaries with masses m1, m2 and m3 form an equilateral triangle, wherein m2=m3. According to Jeans' law (Astronomy and Cosmogony, Cambridge University Press, Cambridge, 1928), the infinitesimal body varies its mass m with time. The space-time transformations of Meshcherskii (Studies on the Mechanics of Bodies of Variable Mass, GITTL, Moscow, 1949) are used by taking the values of the parameters q=1/2, k=0, n=1. The equations of motion of the infinitesimal body with variable mass have been determined. The equations of motion of the current problem differ from the ones of the restricted four-body problem with constant mass. There exist eight libration points, out of which two are collinear with the primary m1 and the rest are non-collinear for a fixed value of parameters γ (m {at time} t/m {at initial time}, 0<γ≤1 ), α (the proportionality constant in Jeans' law (Astronomy and Cosmogony, Cambridge University Press, Cambridge, 1928), 0≤α≤2.2) and μ=0.019 (the mass parameter). All the libration points are found to be unstable. The zero velocity surfaces (ZVS) are also drawn and regions of motion are discussed.

  13. Variable mass theories in relativistic quantum mechanics as an explanation for anomalous low energy nuclear phenomena

    NASA Astrophysics Data System (ADS)

    Davidson, Mark

    2015-05-01

    A recent theoretical explanation for observed anomalous low energy nuclear phenomena which have puzzled physicists for many years is expanded on. Based on covariant relativistic quantum mechanics and historical time wave equations, it explains a large number of observed anomalous effects by supposing that nuclear masses can vary in “nuclear active environments” in condensed matter settings. The modified quantum wave equation originally introduced by Fock and Stueckelberg in the 1930s with significant enhancements up to the present by Horwitz and others prove that variable masses are compatible with the principles of both quantum mechanics and relativity. They can explain all of these effects by modifying the kinematic constraints of the reaction, enhancing electron screening and quantum tunneling rates, and allowing for resonant tunneling. Some previous results are recounted, and experimental evidence based on variable radioactive decay rates and other evidence for variable masses is presented which adds some new potential support for this theory.

  14. Thin-Film Air-Mass-Flow Sensor of Improved Design Developed

    NASA Technical Reports Server (NTRS)

    Fralick, Gustave C.; Wrbanek, John D.; Hwang, Danny P.

    2003-01-01

    Researchers at the NASA Glenn Research Center have developed a new air-mass-flow sensor to solve the problems of existing mass flow sensor designs. NASA's design consists of thin-film resistors in a Wheatstone bridge arrangement. The resistors are fabricated on a thin, constant-thickness airfoil to minimize disturbance to the airflow being measured. The following photograph shows one of NASA s prototype sensors. In comparison to other air-mass-flow sensor designs, NASA s thin-film sensor is much more robust than hot wires, causes less airflow disturbance than pitot tubes, is more accurate than vane anemometers, and is much simpler to operate than thermocouple rakes. NASA s thin-film air-mass-flow sensor works by converting the temperature difference seen at each leg of the thin-film Wheatstone bridge into a mass-flow rate. The following figure shows a schematic of this sensor with air flowing around it. The sensor operates as follows: current is applied to the bridge, which increases its temperature. If there is no flow, all the arms are heated equally, the bridge remains in balance, and there is no signal. If there is flow, the air passing over the upstream legs of the bridge reduces the temperature of the upstream legs and that leads to reduced electrical resistance for those legs. After the air has picked up heat from the upstream legs, it continues and passes over the downstream legs of the bridge. The heated air raises the temperature of these legs, increasing their electrical resistance. The resistance difference between the upstream and downstream legs unbalances the bridge, causing a voltage difference that can be amplified and calibrated to the airflow rate. Separate sensors mounted on the airfoil measure the temperature of the airflow, which is used to complete the calculation for the mass of air passing by the sensor. A current application for air-mass-flow sensors is as part of the intake system for an internal combustion engine. A mass-flow sensor is

  15. Active flow control integrated diffuser (afcid) for increased energy efficiency in variable air volume systems

    NASA Astrophysics Data System (ADS)

    Van Der Schijff, Hermanus P.

    Variable air volume (VAV) air terminals are designed to save energy by reducing airflow into a given space based on occupancy and required load. Systems are typically designed to operate at peak load, however as load is reduced, performance is compromised due to inadequate throw. As a result, fans are installed to adjust for the losses, negating many of the energy savings. Additionally flow is vectored by the use of vanes, a basic passive type of flow control. An experimental investigation was performed to study the application of flow control on that of a HVAC diffuser using synthetic jets distributed evenly along the diffuser edge parallel to the flow field. The study was conducted on a 1:3 scale typical office space (150 ft2), which included a simulated scale HVAC system supplied by compressed air. Two different jet blowing ratios were investigated for system loads of 60% and 90%. The flow field was established using hot wire anemometry and Particle Image Velocimetry (PIV). This study demonstrates the effectiveness of synthetic jet based active flow control at controlling airflow, showing ability to affect throw parameters for changing flow rates within the test chamber. Vectoring of up to 20% and improvement in jet spread of 200% was demonstrated. The use of such devices has the potential to improve air quality and air distribution in building while simultaneously lowering energy demands of HVAC systems.

  16. The dynamical mass of a classical Cepheid variable star in an eclipsing binary system.

    PubMed

    Pietrzyński, G; Thompson, I B; Gieren, W; Graczyk, D; Bono, G; Udalski, A; Soszyński, I; Minniti, D; Pilecki, B

    2010-11-25

    Stellar pulsation theory provides a means of determining the masses of pulsating classical Cepheid supergiants-it is the pulsation that causes their luminosity to vary. Such pulsational masses are found to be smaller than the masses derived from stellar evolution theory: this is the Cepheid mass discrepancy problem, for which a solution is missing. An independent, accurate dynamical mass determination for a classical Cepheid variable star (as opposed to type-II Cepheids, low-mass stars with a very different evolutionary history) in a binary system is needed in order to determine which is correct. The accuracy of previous efforts to establish a dynamical Cepheid mass from Galactic single-lined non-eclipsing binaries was typically about 15-30% (refs 6, 7), which is not good enough to resolve the mass discrepancy problem. In spite of many observational efforts, no firm detection of a classical Cepheid in an eclipsing double-lined binary has hitherto been reported. Here we report the discovery of a classical Cepheid in a well detached, double-lined eclipsing binary in the Large Magellanic Cloud. We determine the mass to a precision of 1% and show that it agrees with its pulsation mass, providing strong evidence that pulsation theory correctly and precisely predicts the masses of classical Cepheids.

  17. The dynamical mass of a classical Cepheid variable star in an eclipsing binary system.

    PubMed

    Pietrzyński, G; Thompson, I B; Gieren, W; Graczyk, D; Bono, G; Udalski, A; Soszyński, I; Minniti, D; Pilecki, B

    2010-11-25

    Stellar pulsation theory provides a means of determining the masses of pulsating classical Cepheid supergiants-it is the pulsation that causes their luminosity to vary. Such pulsational masses are found to be smaller than the masses derived from stellar evolution theory: this is the Cepheid mass discrepancy problem, for which a solution is missing. An independent, accurate dynamical mass determination for a classical Cepheid variable star (as opposed to type-II Cepheids, low-mass stars with a very different evolutionary history) in a binary system is needed in order to determine which is correct. The accuracy of previous efforts to establish a dynamical Cepheid mass from Galactic single-lined non-eclipsing binaries was typically about 15-30% (refs 6, 7), which is not good enough to resolve the mass discrepancy problem. In spite of many observational efforts, no firm detection of a classical Cepheid in an eclipsing double-lined binary has hitherto been reported. Here we report the discovery of a classical Cepheid in a well detached, double-lined eclipsing binary in the Large Magellanic Cloud. We determine the mass to a precision of 1% and show that it agrees with its pulsation mass, providing strong evidence that pulsation theory correctly and precisely predicts the masses of classical Cepheids. PMID:21107425

  18. Air mass flow estimation in turbocharged diesel engines from in-cylinder pressure measurement

    SciTech Connect

    Desantes, J.M.; Galindo, J.; Guardiola, C.; Dolz, V.

    2010-01-15

    Air mass flow determination is needed for the control of current internal combustion engines. Current methods are based on specific sensors (as hot wire anemometers) or indirect estimation through manifold pressure. With the availability of cylinder pressure sensors for engine control, methods based on them can be used for replacing or complementing standard methods. Present paper uses in cylinder pressure increase during the intake stroke for inferring the trapped air mass. The method is validated on two different turbocharged diesel engines and compared with the standard methods. (author)

  19. Apparatus and method for generating large mass flow of high temperature air at hypersonic speeds

    NASA Technical Reports Server (NTRS)

    Sabol, A. P.; Stewart, R. B. (Inventor)

    1973-01-01

    High temperature, high mass air flow and a high Reynolds number test air flow in the Mach number 8-10 regime of adequate test flow duration is attained by pressurizing a ceramic-lined storage tank with air to a pressure of about 100 to 200 atmospheres. The air is heated to temperatures of 7,000 to 8,000 R prior to introduction into the tank by passing the air over an electric arc heater means. The air cools to 5,500 to 6,000 R while in the tank. A decomposable gas such as nitrous oxide or a combustible gas such as propane is injected into the tank after pressurization and the heated pressurized air in the tank is rapidly released through a Mach number 8-10 nozzle. The injected gas medium upon contact with the heated pressurized air effects an exothermic reaction which maintains the pressure and temperature of the pressurized air during the rapid release.

  20. The Use of Red Green Blue (RGB) Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Zavodsky, Bradley; Molthan, Andrew; Jedlovec, Gary

    2013-01-01

    AIRS ozone and model PV analysis confirm the stratospheric air in RGB Air Mass imagery. Trajectories confirm winds south of the low were distinct from CCB driven winds. Cross sections connect the tropopause fold, downward motion, and high nearsurface winds. Comparison to conceptual models show Shapiro-Keyser features and sting jet characteristics were observed in a storm that impacted the U.S. East Coast. RGB Air Mass imagery can be used to identify stratospheric air and regions susceptible to tropopause folding and attendant non-convective winds.

  1. Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; Pȩkala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcău, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Curci, G.

    2014-11-01

    The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth τa(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean τa(3.5 km) ∼ 0.04 - and shows a seasonal trend with a winter minimum - τa(3.5 km) ∼ 0.03 -, and a summer maximum - τa(3.5 km) ∼ 0.06 -, and an unexpected increase from August to September - τa(3.5 km) ∼ 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. Average concentrations are affected by continental sources (wind-blown dust and urban pollution), whilst the peak observed in September and October could be linked to biomass burning in the northern part of Argentina or air pollution coming from surrounding urban areas.

  2. Dynamics of variable mass systems with application to the star 48 solid rocket motor

    NASA Technical Reports Server (NTRS)

    Eke, F. O.

    1984-01-01

    Existing methods for the derivation of equations of motion of variable mass systems are reviewed and compared, the end product being a system of general dynamical equations for variable mass systems. These equations are used to study the lateral stability problem associated with the Star 48 solid rocket engine. It is shown that the shape of the combustion chamber could have a significant effect on the lateral stability of the rocket; specifically, a short and wide combustion chamber is destabilizing, while a long and narrow chamber is stabilizing.

  3. Mass extinction in a dynamical system of evolution with variable dimension.

    PubMed

    Tokita, K; Yasutomi, A

    1999-07-01

    Introducing the effect of extinction into the so-called replicator equations in mathematical biology, we construct a general model where the diversity of species, i.e., the dimension of the equation, is a time-dependent variable. The system shows very different behavior from the original replicator equation, and leads to mass extinction when the system initially has high diversity. The present theory can serve as a mathematical foundation for the paleontologic theory for mass extinction. This extinction dynamics is a prototype of dynamical systems where the variable dimension is inevitable.

  4. Statistical Variability and Persistence Change in Daily Air Temperature Time Series from High Latitude Arctic Stations

    NASA Astrophysics Data System (ADS)

    Suteanu, Cristian

    2015-07-01

    In the last decades, Arctic communities have been reporting that weather conditions are becoming less predictable. Most scientific studies have not been able to consistently confirm such a trend. The question regarding the possible increase in weather variability was addressed here based on daily minimum and maximum surface air temperature time series from 15 high latitude Arctic stations from Canada, Norway, and the Russian Federation. A range of analysis methods were applied, distinguished mainly by the way in which they treat time scale. Statistical L-moments were determined for temporal windows of different lengths. While the picture provided by L-scale and L-kurtosis is not consistent with an increasing variability, L-skewness was found to change towards more positive values, reflecting an enhancement of warm spells. Haar wavelet analysis was applied both to the entire time series and to running windows. Persistence diagrams were generated based on running windows advancing through time and on local slopes of Haar analysis graphs; they offer a more nuanced view on variability by reflecting its change over time on a range of temporal scales. Local increases in variability could be identified in some cases, but no consistent change was detected in any of the stations over the studied temporal scales. The possibility for other intervals of temporal scale (e.g., days, hours, minutes) to potentially reveal a different situation cannot be ruled out. However, in the light of the results presented here, explanations for the discrepancy between variability perception and results of pattern analysis might have to be explored using an integrative approach to weather variables such as air temperature, cloud cover, precipitation, wind, etc.

  5. Modeling spatiotemporal variability of intra-urban air pollutants in Detroit: A pragmatic approach

    NASA Astrophysics Data System (ADS)

    O'Leary, Brendan F.; Lemke, Lawrence D.

    2014-09-01

    This study combined a three-year time series of air pollutant measurements from the Michigan Air Sampling Network (MASN) with spatially detailed datasets for two two-week periods in September 2008 and June 2009. The objective was to produce monthly pollutant concentration models for the city of Detroit, Michigan, USA from January 2008 through December 2010, in support of a related epidemiological study examining adverse birth outcomes in Detroit. Two gaseous analytes, NO2 (nitrogen dioxide) and total BTEX (benzene, toluene, ethyl-benzene, and xylene), as well as two particulate matter size fractions, PM2.5 and PM10, were investigated. The September 2008 and June 2009 datasets were modeled using ordinary kriging to produce high spatial density concentration maps with 300 m by 300 m resolution across the city. A weighted average was applied to these maps to generate a series of monthly spatial models for each pollutant. Temporal variability was then incorporated by adjusting each monthly spatial model using an average bulk shift derived from MASN time series measurements for the corresponding month over the three-year study period. The resulting models incorporate temporal trends while preserving neighborhood scale spatial variability. Seasonal variation was evident in NO2 models, but not readily discernable in BTEX or PM models across the three year study period. The greatest spatial and temporal variability was observed in the BTEX distributions, which are inferred to be strongly influenced by local sources. The methodology employed assumes that the interpolated monthly models adequately capture spatial variability of the air pollutants across the study area, the spatial distribution of pollutant concentrations remained consistent while their magnitude fluctuated from month to month, and that the available time series measurements reflect temporal trends across the city of Detroit throughout the three-year study period.

  6. Modeling short-term variability of α-hexachlorocyclohexane in Northern Hemispheric air

    NASA Astrophysics Data System (ADS)

    Hansen, Kaj M.; Christensen, Jesper H.; Brandt, JøRgen; Frohn, Lise M.; Geels, Camilla; SkjøTh, Carsten Ambelas; Li, Yi-Fan

    2008-01-01

    The POP version of the Danish Eulerian Hemispheric Model (DEHM-POP) is a further development of a 3-D dynamic atmospheric chemistry transport model covering the Northern Hemisphere, which was originally developed to study atmospheric transport of conventional air pollutants and other atmospheric constituents (e.g., SOX, heavy metals, and CO2). Four different surface compartments (soil, ocean water, vegetation, and snow) are introduced in DEHM-POP with each compartment including the most dominant dynamic processes determining the exchange between air and the surface type to account for the consecutive cycles of deposition and reemission of persistent organic pollutants (POPs). This model setup makes it possible to study short-term atmospheric variability of POPs, which is exemplified in this paper by a study of the atmospheric variability of α-hexachlorocyclohexane (α-HCH), the major component of the worldwide most used insecticide: technical HCH. Simulated α-HCH air concentrations are evaluated against measurements from 21 monitoring stations within the model domain, and the model is able to predict the annual average concentration as well as the long-term trend for the 1990s. Significant correlations between simulated and measured short-term atmospheric concentrations of α-HCH are also found at the majority of the investigated monitoring stations, which shows that it is possible to resolve the atmospheric variability of POPs using an atmospheric chemistry transport model. Differences between simulated and measured atmospheric α-HCH variability can arise because the measurements may be influenced by local features that are not accounted for in the model with the relatively coarse horizontal resolution and surface description.

  7. Investigating the Use Of Portable Air Pollution Sensors to Capture the Spatial Variability Of Traffic-Related Air Pollution.

    PubMed

    Deville Cavellin, Laure; Weichenthal, Scott; Tack, Ryan; Ragettli, Martina S; Smargiassi, Audrey; Hatzopoulou, Marianne

    2016-01-01

    Advances in microsensor technologies for air pollution monitoring encourage a growing use of portable sensors. This study aims at testing their performance in the development of exposure surfaces for nitrogen dioxide (NO2) and ozone (O3). In Montreal, Canada, a data-collection campaign was conducted across three seasons in 2014 for 76 sites spanning the range of land uses and built environments of the city; each site was visited from 6 to 12 times, for 20 min, using NO2 and O3 sensors manufactured by Aeroqual. Land-use regression models were developed, achieving R(2) values of 0.86 for NO2 and 0.92 for O3 when adjusted for regional meteorology to control for the fact that all of the locations were not monitored at the same time. A total of two exposure surfaces were then developed for NO2 and O3 as averages over spring, summer, and fall. Validation against the fixed-station data and previous campaigns suggests that Aeroqual sensors tend to overestimate the highest NO2 and O3 concentrations, thus increasing the range of values across the city. However, the sensors suggest a good performance with respect to capturing the spatial variability in NO2 and O3 and are very convenient to use, having great potential for capturing temporal variability.

  8. Modal analysis of a nonuniform string with end mass and variable tension

    NASA Technical Reports Server (NTRS)

    Rheinfurth, M. H.; Galaboff, Z. J.

    1983-01-01

    Modal synthesis techniques for dynamic systems containing strings describe the lateral displacements of these strings by properly chosen shape functions. An iterative algorithm is provided to calculate the natural modes of a nonuniform string and variable tension for some typical boundary conditions including one end mass. Numerical examples are given for a string in a constant and a gravity gradient force field.

  9. Falling Chains as Variable-Mass Systems: Theoretical Model and Experimental Analysis

    ERIC Educational Resources Information Center

    de Sousa, Celia A.; Gordo, Paulo M.; Costa, Pedro

    2012-01-01

    In this paper, we revisit, theoretically and experimentally, the fall of a folded U-chain and of a pile-chain. The model calculation implies the division of the whole system into two subsystems of variable mass, allowing us to explore the role of tensional contact forces at the boundary of the subsystems. This justifies, for instance, that the…

  10. Apparent mass of the human body in the vertical direction: Inter-subject variability

    NASA Astrophysics Data System (ADS)

    Toward, Martin G. R.; Griffin, Michael J.

    2011-02-01

    The biodynamic responses of the seated human body to whole-body vibration vary considerably between people, but the reasons for the variability are not well understood. This study was designed to determine how the physical characteristics of people affect their apparent mass and whether inter-subject variability is influenced by the magnitude of vibration and the support of a seat backrest. The vertical apparent masses of 80 seated adults (41 males and 39 females aged 18-65) were measured at frequencies between 0.6 and 20 Hz with four backrest conditions (no backrest, upright rigid backrest, reclined rigid backrest, reclined foam backrest) and with three magnitudes of random vibration (0.5, 1.0 and 1.5 m s -2 rms). Relationships between subject physical characteristics (age, gender, weight, and anthropometry) and subject apparent mass were investigated with multiple regression models. The strongest predictor of the modulus of the vertical apparent mass at 0.6 Hz, at resonance, and at 12 Hz was body weight, with other factors having only a marginal effect. After correction for other variables, the principal resonance frequency was most consistently associated with age and body mass index. As age increased from 18 to 65 years, the resonance frequency increased by up to 1.7 Hz, and when the body mass index was increased from 18 to 34 kg m -2 the resonance frequency decreased by up to 1.7 Hz. These changes were greater than the 0.9-Hz increase in resonance frequency between sitting without a backrest and sitting with a reclined rigid backrest, and greater than the 1.0-Hz reduction in resonance frequency when the magnitude of vibration increased from 0.5 to 1.5 m s -2 rms. It is concluded that the effects of age, body mass index, posture, vibration magnitude, and weight should be taken into account when defining the vertical apparent mass of the seated human body.

  11. Effect of guide vanes on the performance of a variable chord self-rectifying air turbine

    NASA Astrophysics Data System (ADS)

    Govardhan, M.; Dhanasekaran, T. S.

    1998-12-01

    Wells turbine is a self rectifying air flow turbine capable of converting pneumatic power of the periodically reversing air stream in Oscillating Water Column into mechanical energy. One of the principal reasons for the low efficiency of the Wells turbine is its lower tangential force compared to its axial force. Guide vanes before and after the rotor suggest a means to improve the tangential force, hence its efficiency. Experimental investigations are carried out on the Wells turbine with a variable chord (VACR) blade rotor fitted with inlet and outlet guide vanes to understand the aerodynamics especially improvement in efficiency and starting characteristics. Numerical simulation has been made to clarify the unsteady characteristics of the turbine with guide vanes. Studies are done at various flow coefficients covering the entire range of flow coefficients over which the turbine is operable. The efficiency, starting characteristics of the Wells turbine has improved when compared with the turbine without guide vanes.

  12. Development and Evaluation of a Variable-Temperature Quadrupole Ion Trap Mass Spectrometer.

    PubMed

    Derkits, David; Wiseman, Alex; Snead, Russell F; Dows, Martina; Harge, Jasmine; Lamp, Jared A; Gronert, Scott

    2016-02-01

    A new, variable-temperature mass spectrometer system is described. By applying polyimide heating tape to the end-cap electrodes of a Bruker (Bremen, Germany) Esquire ion trap, it is possible to vary the effective temperature of the system between 40 and 100°C. The modification does not impact the operation of the ion trap and the heater can be used for extended periods without degradation of the system. The accuracy of the ion trap temperatures was assessed by examining two gas-phase equilibrium processes with known thermochemistry. In each case, the variable-temperature ion trap provided data that were in good accord with literature data, indicating the effective temperature in the ion trap environment was being successfully modulated by the changes in the set-point temperatures on the end-cap electrodes. The new design offers a convenient and effective way to convert commercial ion trap mass spectrometers into variable-temperature instruments. PMID:26483183

  13. Annual variation of coastal uplift in Greenland as an indicator of variable and accelerating ice mass loss

    NASA Astrophysics Data System (ADS)

    Yang, Qian; Wdowinski, Shimon; Dixon, Timothy H.

    2013-05-01

    Seasonal melting of the coastal part of the Greenland ice sheet is investigated using GPS vertical displacement data from coastal stations, combined with data on atmospheric and ocean temperatures. Using a high pass filter and cubic spline models, we estimate five variables describing seasonal uplift, a proxy for proximal mass loss, including duration of the melt season and the amount of summer uplift. Our analysis shows both temporal and spatial variations of uplift. Southern coastal Greenland experienced anomalously large uplift in summer 2010, implying significant melting that year. However, the northwest coast did not experience significant change in uplift at that time. Our data suggest that a combination of warm summer air temperature and warm sub-surface ocean water temperature drove the large mass losses in 2010. Using the uplift pattern of 2008-2010, and comparing to atmospheric data and ocean water temperature data, we show that warm Irminger Water (IW) exerted significant influence on coastal melting in southeastern, southern and southwestern Greenland, reaching about 69°N in 2010. North of this, IW did not exert significant influence, in effect defining the northward limit of the sub-polar gyre for that year. Thus, short-term variability in the coastal GPS uplift signal can be used to infer an oceanographic parameter that has a critical influence on Greenland ice sheet health.

  14. Inert gas purgebox for Fourier transform ion cyclotron resonance mass spectrometry of air-sensitive solids

    NASA Astrophysics Data System (ADS)

    May, Michael A.; Marshall, Alan G.

    1994-03-01

    A sealed rigid ``purgebox'' makes it possible to load air- and/or moisture-sensitive solids into the solids probe inlet of a Fourier transform ion cyclotron resonance (FT/ICR) mass spectrometer. A pelletized sample is transferred (in a sealed canister) from a commercial drybox to a Lucite(R) purgebox. After the box is purged with inert gas, an attached glove manipulator is used to transfer the sample from the canister to the solids probe of the mass spectrometer. Once sealed inside the inlet, the sample is pre-evacuated and then passed into the high vacuum region of the instrument at ˜10-7 Torr. The purgebox is transparent, portable, and readily assembled/disassembled. Laser desorption FT/ICR mass spectra of the air- and moisture-sensitive solids, NbCl5. NbCl2(C5H5)2, and Zr(CH3)2(C5H5)2 are obtained without significant oxidation. The residual water vapor concentration inside the purgebox was measured as 100±20 ppm after a 90-min purge with dry nitrogen gas. High-resolution laser desorption/ionization mass spectrometry of air-sensitive solids becomes feasible with the present purgebox interface. With minor modification of the purgebox geometry, the present method could be adapted to any mass spectrometer equipped with a solid sample inlet.

  15. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general. PMID:10548806

  16. Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

    PubMed

    Viggiano, A A; Hunton, D E

    1999-11-01

    Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general.

  17. Atmospheric control of Aedes aegypti populations in Buenos Aires (Argentina) and its variability

    NASA Astrophysics Data System (ADS)

    de Garín, A.; Bejarán, R. A.; Carbajo, A. E.; de Casas, S. C.; Schweigmann, N. J.

    The mosquito Aedes aegypti is the main urban vector responsible for the transmission of dengue fever and dengue hemorrhagic fever. The city of Buenos Aires, Argentina, is located at the southern end of the world distribution of the species. The population abundance of Ae. aegypti is mainly regulated by environmental factors. We calculated the potential number of times that a female could lay eggs during its mean life expectancy, based on potential egg production and daily meteorological records. The model considers those variables implying physical hazard to the survival of Ae. aegypti, mosquito flying activity and oviposition. The results, obtained after calibration and validation of the model with field observations, show significant correlation (P<0.001) for different lags depending on the life stage. From these results, more favorable atmospheric conditions for Ae. aegypti reproduction (linked to the urban climatic change) can be observed. The climatic variability in the last decade resembles conditions at the end of 19th century.

  18. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  19. Measuring Air-water Interfacial Area for Soils Using the Mass Balance Surfactant-tracer Method

    PubMed Central

    Araujo, Juliana B.; Mainhagu, Jon; Brusseau, Mark L.

    2015-01-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. PMID:25950136

  20. Turbulent heat and mass transfers across a thermally stratified air-water interface

    NASA Technical Reports Server (NTRS)

    Papadimitrakis, Y. A.; Hsu, Y.-H. L.; Wu, J.

    1986-01-01

    Rates of heat and mass transfer across an air-water interface were measured in a wind-wave research facility, under various wind and thermal stability conditions (unless otherwise noted, mass refers to water vapor). Heat fluxes were obtained from both the eddy correlation and the profile method, under unstable, neutral, and stable conditions. Mass fluxes were obtained only under unstable stratification from the profile and global method. Under unstable conditions the turbulent Prandtl and Schmidt numbers remain fairly constant and equal to 0.74, whereas the rate of mass transfer varies linearly with bulk Richardson number. Under stable conditions the turbulent Prandtl number rises steadily to a value of 1.4 for a bulk Richardson number of about 0.016. Results of heat and mass transfer, expressed in the form of bulk aerodynamic coefficients with friction velocity as a parameter, are also compared with field data.

  1. Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.

    PubMed

    Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L

    2015-09-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention.

  2. Aerosol composition and properties variation at the ground and over the column under different air masses advection in South Italy.

    PubMed

    Pavese, G; Lettino, A; Calvello, M; Esposito, F; Fiore, S

    2016-04-01

    Aerosol composition and properties variation under the advection of different air masses were investigated, as case studies, by contemporary measurements over the atmospheric column and at the ground in a semi-rural site in South Italy. The absence of local strong sources in this area allowed to characterize background aerosol and to compare particle mixing effects under various atmospheric circulation conditions. Aerosol optical depth (AOD) and Ǻngström parameters from radiometric measurements allowed the detection and identification of polluted, dust, and volcanic atmospheric conditions. AODs were the input for a suitable model to evaluate the columnar aerosol composition, according to six main atmospheric components (water-soluble, soot, sea salt accumulation, sea salt coarse, mineral dus,t and biological). Scanning electron microscope (SEM) analysis of particulate sampled with a 13-stage impactor at the ground showed not only fingerprints typical of the different air masses but also the effects of transport and aging on atmospheric particles, suggesting processes that changed their chemical and optical properties. Background columnar aerosol was characterized by 72% of water-soluble and soot, in agreement with ground-based findings that highlighted 60% of contribution from anthropogenic carbonate particles and soot. In general, a good agreement between ground-based and columnar results was observed. Under the advection of trans-boundary air masses, water-soluble and soot were always present in columnar aerosol, whereas, in variable percentages, sea salt and mineral particles characterized both dust and volcanic conditions. At the ground, sulfates characterized the amorphous matrix produced in finer stages by the evaporation of solutions of organic and inorganic aerosols. Sulfates were also one of the key players involved in heterogeneous chemical reactions, producing complex secondary aerosol, as such clay-sulfate internally mixed particle externally mixed

  3. On the Multi-scale Variability of High-frequency Surface Air Temperature

    NASA Astrophysics Data System (ADS)

    Cavanaugh, N. R.; Shen, S. S. P.

    2014-12-01

    We demonstrate that the first four statistical moments of sub-daily surface air temperature (SAT) anomalies exhibit large spatial patterns, globally, which differ from moment-to-moment and that many regions have statistically significant trends in moments from 1950-2010; these results imply that high-frequency SAT anomaly distributions are nearly identically distributed over very large spatial scales and that these distributions are undergoing characteristic changes in shape due to either decadal variability or climate change. Further, we examine the spatial scaling structure of higher-order and non-linear spatial correlations up to fourth-order which determine the variability distributions of SAT at larger spatial scales. Higher-order moment statistics suggest that SAT scales as an approximately locally homogeneous and isotropic quasi-Gaussian random field whose higher-order moments can be determined by functions of pair correlations, which in turn are related to regionally varying decorrelation length scales. These results have implications for the study of multi-scale atmospheric variability, extremes, and climate change involving geographically smooth variables and helps to define the theory which underlies the success of statistical downscaling techniques.

  4. MISR Aerosol Air Mass Type Mapping over Mega-City: Validation and Applications

    NASA Astrophysics Data System (ADS)

    Patadia, F.; Kahn, R. A.

    2010-12-01

    Most aerosol air-quality monitoring in mega-city environments is done from scattered ground stations having detailed chemical and optical sampling capabilities. Satellite instruments such as the Multi-angle Imaging SpectroRadiometer (MISR) can retrieve total-column Aerosol Optical Depth (AOD), along with some information about particle microphysical properties. Although the particle property information from MISR is much less detailed than that obtained from the ground sampling stations, the coverage is extensive, making it possible to put individual surface observations into the context of regional aerosol air mass types. This paper presents an analysis of MISR aerosol observations made coincident with aircraft and ground-based instruments during the INTEX-B field campaign. These detailed comparisons of satellite aerosol property retrievals against dedicated field measurements provide the opportunity to validate the retrievals quantitatively at a regional level, and help to improve aerosol representation in retrieval algorithms. Validation of MISR retrieved AOD and other aerosol properties over the INTEX-B study region in and around Mexico City will be presented. MISR’s ability to distinguish among aerosol air mass types will be discussed. The goal of this effort is to use the MISR aerosol property retrievals for mapping both aerosol air mass type and AOD gradients in mega-city environments over the decade-plus that MISR has made global observations.

  5. Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

    NASA Technical Reports Server (NTRS)

    Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.; Schlager, H.; Atlas, E.; Blake, D.; Coe, H.; Cohen, R. C.; Crosier, J.; Flocke, F.; Holloway, J. S.; Hopkins, J. R.; Huber, G.; McQuaid, J.; Purvis, R.; Rappengluck, B.; Ryerson, T. B.; Sachse, G. W.

    2006-01-01

    The International Consortium for Atmospheric Research on Transport and Transformation (ICARTT)-Lagrangian experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts using two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique is then used to identify Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these coincident matches is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown and the downwind minus upwind differences in tracers are discussed.

  6. Effect of body mass and midsole hardness on kinetic and perceptual variables during basketball landing manoeuvres.

    PubMed

    Nin, Darren Z; Lam, Wing K; Kong, Pui W

    2016-01-01

    This study investigated the effects of body mass and shoe midsole hardness on kinetic and perceptual variables during the performance of three basketball movements: (1) the first and landing steps of layup, (2) shot-blocking landing and (3) drop landing. Thirty male basketball players, assigned into "heavy" (n = 15, mass 82.7 ± 4.3 kg) or "light" (n = 15, mass 63.1 ± 2.8 kg) groups, performed five trials of each movement in three identical shoes of varying midsole hardness (soft, medium, hard). Vertical ground reaction force (VGRF) during landing was sampled using multiple wooden-top force plates. Perceptual responses on five variables (forefoot cushioning, rearfoot cushioning, forefoot stability, rearfoot stability and overall comfort) were rated after each movement condition using a 150-mm Visual Analogue Scale (VAS). A mixed factorial analysis of variance (ANOVA) (Body Mass × Shoe) was applied to all kinetic and perceptual variables. During the first step of the layup, the loading rate associated with rearfoot contact was 40.7% higher in the "heavy" than "light" groups (P = .014) and 12.4% higher in hard compared with soft shoes (P = .011). Forefoot peak VGRF in a soft shoe was higher (P = .011) than in a hard shoe during shot-block landing. Both "heavy" and "light" groups preferred softer to harder shoes. Overall, body mass had little effect on kinetic or perceptual variables. PMID:26211423

  7. Effect of body mass and midsole hardness on kinetic and perceptual variables during basketball landing manoeuvres.

    PubMed

    Nin, Darren Z; Lam, Wing K; Kong, Pui W

    2016-01-01

    This study investigated the effects of body mass and shoe midsole hardness on kinetic and perceptual variables during the performance of three basketball movements: (1) the first and landing steps of layup, (2) shot-blocking landing and (3) drop landing. Thirty male basketball players, assigned into "heavy" (n = 15, mass 82.7 ± 4.3 kg) or "light" (n = 15, mass 63.1 ± 2.8 kg) groups, performed five trials of each movement in three identical shoes of varying midsole hardness (soft, medium, hard). Vertical ground reaction force (VGRF) during landing was sampled using multiple wooden-top force plates. Perceptual responses on five variables (forefoot cushioning, rearfoot cushioning, forefoot stability, rearfoot stability and overall comfort) were rated after each movement condition using a 150-mm Visual Analogue Scale (VAS). A mixed factorial analysis of variance (ANOVA) (Body Mass × Shoe) was applied to all kinetic and perceptual variables. During the first step of the layup, the loading rate associated with rearfoot contact was 40.7% higher in the "heavy" than "light" groups (P = .014) and 12.4% higher in hard compared with soft shoes (P = .011). Forefoot peak VGRF in a soft shoe was higher (P = .011) than in a hard shoe during shot-block landing. Both "heavy" and "light" groups preferred softer to harder shoes. Overall, body mass had little effect on kinetic or perceptual variables.

  8. Climate variability modulates western US ozone air quality in spring via deep stratospheric intrusions

    PubMed Central

    Lin, Meiyun; Fiore, Arlene M.; Horowitz, Larry W.; Langford, Andrew O.; Oltmans, Samuel J.; Tarasick, David; Rieder, Harald E.

    2015-01-01

    Evidence suggests deep stratospheric intrusions can elevate western US surface ozone to unhealthy levels during spring. These intrusions can be classified as ‘exceptional events', which are not counted towards non-attainment determinations. Understanding the factors driving the year-to-year variability of these intrusions is thus relevant for effective implementation of the US ozone air quality standard. Here we use observations and model simulations to link these events to modes of climate variability. We show more frequent late spring stratospheric intrusions when the polar jet meanders towards the western United States, such as occurs following strong La Niña winters (Niño3.4<−1.0 °C). While El Niño leads to enhancements of upper tropospheric ozone, we find this influence does not reach surface air. Fewer and weaker intrusion events follow in the two springs after the 1991 volcanic eruption of Mt. Pinatubo. The linkage between La Niña and western US stratospheric intrusions can be exploited to provide a few months of lead time during which preparations could be made to deploy targeted measurements aimed at identifying these exceptional events. PMID:25964012

  9. Climate variability modulates western US ozone air quality in spring via deep stratospheric intrusions

    NASA Astrophysics Data System (ADS)

    Lin, Meiyun; Fiore, Arlene M.; Horowitz, Larry W.; Langford, Andrew O.; Oltmans, Samuel J.; Tarasick, David; Rieder, Harald E.

    2015-05-01

    Evidence suggests deep stratospheric intrusions can elevate western US surface ozone to unhealthy levels during spring. These intrusions can be classified as `exceptional events', which are not counted towards non-attainment determinations. Understanding the factors driving the year-to-year variability of these intrusions is thus relevant for effective implementation of the US ozone air quality standard. Here we use observations and model simulations to link these events to modes of climate variability. We show more frequent late spring stratospheric intrusions when the polar jet meanders towards the western United States, such as occurs following strong La Niña winters (Niño3.4<-1.0 °C). While El Niño leads to enhancements of upper tropospheric ozone, we find this influence does not reach surface air. Fewer and weaker intrusion events follow in the two springs after the 1991 volcanic eruption of Mt. Pinatubo. The linkage between La Niña and western US stratospheric intrusions can be exploited to provide a few months of lead time during which preparations could be made to deploy targeted measurements aimed at identifying these exceptional events.

  10. Climate variability modulates western US ozone air quality in spring via deep stratospheric intrusions.

    PubMed

    Lin, Meiyun; Fiore, Arlene M; Horowitz, Larry W; Langford, Andrew O; Oltmans, Samuel J; Tarasick, David; Rieder, Harald E

    2015-01-01

    Evidence suggests deep stratospheric intrusions can elevate western US surface ozone to unhealthy levels during spring. These intrusions can be classified as 'exceptional events', which are not counted towards non-attainment determinations. Understanding the factors driving the year-to-year variability of these intrusions is thus relevant for effective implementation of the US ozone air quality standard. Here we use observations and model simulations to link these events to modes of climate variability. We show more frequent late spring stratospheric intrusions when the polar jet meanders towards the western United States, such as occurs following strong La Niña winters (Niño3.4<-1.0 °C). While El Niño leads to enhancements of upper tropospheric ozone, we find this influence does not reach surface air. Fewer and weaker intrusion events follow in the two springs after the 1991 volcanic eruption of Mt. Pinatubo. The linkage between La Niña and western US stratospheric intrusions can be exploited to provide a few months of lead time during which preparations could be made to deploy targeted measurements aimed at identifying these exceptional events. PMID:25964012

  11. Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

    USGS Publications Warehouse

    Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

    2002-01-01

    Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

  12. Variability in AIRS CO2 during active and break phases of Indian summer monsoon.

    PubMed

    Revadekar, J V; Ravi Kumar, K; Tiwari, Yogesh K; Valsala, Vinu

    2016-01-15

    Due to human activities, the atmospheric concentration of Carbon Dioxide (CO2) has been rising extensively since the Industrial Revolution. Indian summer monsoon (ISM) has a dominant westerly component from ocean to land with a strong tendency to ascend and hence may have role in CO2 distribution in lower and middle troposphere over Indian sub-continent. A substantial component of ISM variability arises from the fluctuations on the intra-seasonal scale between active and break phases which correspond to strong and weak monsoon circulation. In view of the above, an attempt is made in this study to examine the AIRS/AQUA satellite retrieved CO2 distribution in response to atmospheric circulation with focus on active and break phase. Correlation analysis indicates the increase in AIRS CO2 linked with strong monsoon circulation. Study also reveals that anomalous circulation pattern during active and break phase show resemblance with high and low values of AIRS CO2. Homogeneous monsoon regions of India show substantial increase in CO2 levels during active phase. Hilly regions of India show strong contrast in CO2 and vertical velocity during active and break phases.

  13. Spatial variability of indoor air pollutants in schools. A multilevel approach

    NASA Astrophysics Data System (ADS)

    Banerjee, Soutrik; Annesi-Maesano, Isabella

    2012-12-01

    The measurement of indoor air pollutants and their health effects are less often studied due to the costs of collection of such data. We have analysed the variability in the measurement of five indoor school air pollutants: fine particulate matter of size ≤2.5 μm (PM2.5), nitrogen dioxide (NO2), and three Volatile Organic Compounds (VOC), namely formaldehyde, acetaldehyde and acrolein, objectively measured over five days of a week at representative points in more than 400 classrooms of 109 schools and courtyards in six French cities spread out over the year. Separate 3-stage multilevel models were fitted to partition the different nested variance components (i.e., classroom, school and city levels), and intra-class correlation (ICC) coefficients were computed to bring out the similarities of pollutants' concentrations among these spatial units. The indoor PM2.5 and NO2 concentrations showed a high degree of similarity (ICC coefficients equal to 76% and 81%, respectively) between the classrooms of a school (and city), whereas the formaldehyde, acetaldehyde and acrolein concentrations showed low to moderate degree of similarity (ICC coefficients equal to 25%, 36% and 57%, respectively) between the classrooms. We conclude that to investigate the impact of indoor air pollutants, a multilevel approach taking into account the full design of the study would be the most appropriate.

  14. Mass spectrometry of solid samples in open air using combined laser ionization and ambient metastable ionization

    NASA Astrophysics Data System (ADS)

    He, X. N.; Xie, Z. Q.; Gao, Y.; Hu, W.; Guo, L. B.; Jiang, L.; Lu, Y. F.

    2012-01-01

    Mass spectrometry of solid samples in open air was carried out using combined laser ionization and metastable ionization time-of-flight mass spectrometry (LI-MI-TOFMS) in ambient environment for qualitative and semiquantitative (relative analyte information, not absolute information) analysis. Ambient metastable ionization using a direct analysis in realtime (DART) ion source was combined with laser ionization time-of-flight mass spectrometry (LI-TOFMS) to study the effects of combining metastable and laser ionization. A series of metallic samples from the National Institute of Standards and Technology (NIST 494, 495, 498, 499, and 500) and a pure carbon target were characterized using LI-TOFMS in open air. LI-MI-TOFMS was found to be superior to laser-induced breakdown spectroscopy (LIBS). Laser pulse energies between 10 and 200 mJ at the second harmonic (532 nm) of an Nd:YAG laser were applied in the experiment to obtain a high degree of ionization in plasmas. Higher laser pulse energy improves signal intensities of trace elements (such as Fe, Cr, Mn, Ni, Ca, Al, and Ag). Data were analyzed by numerically calculating relative sensitivity coefficients (RSCs) and limit of detections (LODs) from mass spectrometry (MS) and LIBS spectra. Different parameters, such as boiling point, ionization potential, RSC, LOD, and atomic weight, were shown to analyze the ionization and MS detection processes in open air.

  15. The influence of sea ice extent variability on the Greenland surface mass and energy balance

    NASA Astrophysics Data System (ADS)

    Tedesco, M.; Quillet, A.; Alexander, P. M.; Rennermalm, A. K.; Stroeve, J. C.; Fettweis, X.; Orantes, E. J.; Tuia, D.; Parkan, M.

    2012-12-01

    Sea ice variations are known to affect local surface air temperature regimes, but other influences, in particular atmospheric circulation, are important. Several recent studies have found that, via atmospheric transport, atmospheric warming driven by sea ice loss affects surrounding areas. Indeed, while observed amplified autumn warming is focused over the areas where the sea ice has disappeared in summers (e.g. Beaufort, Chukchi and E. Siberian seas), wind patterns spread the anomalous warmth over open water areas to adjacent land areas and may extend up to 1500 km inland during periods of rapid ice loss through the 21st century. It is plausible that changes in the sea-ice/open- water regime surrounding the ice sheet are capable of modulating Greenland surface melt and precipitation. Diminished sea ice around Greenland may lead to large fluxes of heat into the atmosphere that could lead to enhanced ice-sheet surface-melt, increased coastal water temperatures, alter the vertical stability of the atmosphere, moisture availability and regional baroclinicity. Here we report results concerning the combined analysis of sea ice extent estimated from spaceborne microwave observations, the outputs of a regional climate model (Modèle Atmosphérique Régional, MAR) and in-situ measured quantities. In particular, we study the impact of the open water along the coasts of Greenland (divided into 16 longitudinal zones and two latitudinal ones) on surface mass balance (e.g., meltwater production, runoff, precipitation) and surface energy quantities (e.g., albedo, sensible heat flux, etc.) simulated over the Greenland ice sheet for the period 1979 - 2011. Among other things, our results indicate a statistically significant correlation between open water spatio-temporal variability and integrated liquid water content, with correlation values being highest for the month of August along the Southwest region of Greenland (e.g., Kangerlussuaq). Such dependency persists even after the

  16. Linking the spatial variability of glacier mass loss to fjord geometry

    NASA Astrophysics Data System (ADS)

    Porter, D. F.; Tinto, K. J.; Boghosian, A.; Cochran, J. R.; Csatho, B. M.; Bell, R. E.

    2015-12-01

    There is compelling evidence of increasing mass loss of the ice sheets using a diverse set of observations, including increased thinning rates measured from both airborne and satellite altimeters, elevated mass fluxes resulting from the acceleration of outlet glaciers, and mass changes measured directly from satellite gravimetry. A dominant characteristic of observed change in Greenland outlet glaciers is that it is locally random. Numerous studies have revealed a high degree of spatial and temporal variability of outlet glacier mass change. Modeling studies suggest that increased ocean temperatures may be responsible for the observed glacial retreat in Greenland through increased basal melting, leading to increased calving rates, terminus retreat, glacier speedup, and eventually thinning of inland ice. Knowledge of fjord geometry is crucial for ice-ocean interaction because the availability of ocean heat to the ice will be restricted by narrow sills and shallow grounding lines. We investigate whether the variability in observed changes among Greenland glaciers can be partially explained by variation in fjord geometry. Using statistical techniques commonly employed to detect patterns in complex spatial data, we objectively show that mass change in Greenland tidewater glaciers between 2003 and 2009 is indeed mostly spatially incoherent. Except for a few clusters of similar change in the NW and Scoresby Sund regions, there is significant glacier-scale variability in mass loss rates. To understand the drivers of this local variability, we compare fjord bathymetries from all regions of Greenland, modeled using airborne gravimetry measurements from NASA Operation IceBridge flights, to estimates of glaciological change. Specifically, we investigate the correlation between water depths at the grounding line and the dynamic mass loss of tidewater glaciers. In theory, a deep grounding line will allow greater interaction with the warm Atlantic Water observed in most fjords

  17. Model atmospheres with periodic shocks. [pulsations and mass loss in variable stars

    NASA Technical Reports Server (NTRS)

    Bowen, G. H.

    1989-01-01

    The pulsation of a long-period variable star generates shock waves which dramatically affect the structure of the star's atmosphere and produce conditions that lead to rapid mass loss. Numerical modeling of atmospheres with periodic shocks is being pursued to study the processes involved and the evolutionary consequences for the stars. It is characteristic of these complex dynamical systems that most effects result from the interaction of various time-dependent processes.

  18. Study of single and combined mass-sensitive observables of cosmic ray induced extensive air showers

    NASA Astrophysics Data System (ADS)

    Rastegarzadeh, G.; Nemati, M.

    2016-03-01

    In this study, combinations of the global arrival time, (Δτ_{global}), pseudorapidity, and lateral density distribution (ρ_{μ}) of muons, which are three mass-sensitive observables of cosmic ray induced extensive air showers, have been used as new parameters to study the primary mass discrimination around the knee energies (100 TeV-10 PeV). This is a simulation-based study and the simulations have been performed for the KASCADE array at Karlsruhe and the Alborz-I array at Tehran to study the effect of the altitude on the quality of the primary mass discrimination. The merit factors of the single and combined three mass-sensitive observables have been calculated to compare the discrimination power of combined and single observables. We have used the CORSIKA 7.4 code to simulate the extensive air showers (EASs) sample sets. Considering all aspects of our study, it is found that the ratio of the global time to the lateral density distribution of the muons gives better results than other ratios; also in the case of single observables, the muon density gives better results compared with the other observables. Also it is shown that below 1 PeV primary energies, the ratio of the muon global time to the muon density (Δτ_{global}/ρ_{μ}) results in a better mass discrimination relative to the muon density only.

  19. Neonatal Presentation of an Air-Filled Neck Mass that Enlarges with Valsalva: A Case Report

    PubMed Central

    Patel, Jasminkumar Bharatbhai; Kilbride, Howard; Paulson, Lorien

    2015-01-01

    Branchial cleft cysts are common causes of congenital neck masses in the pediatric population. However, neonatal presentation of branchial cleft cysts is uncommon, but recognizable secondary to acute respiratory distress from airway compression or complications secondary to infection. We report a 1-day-old infant presenting with an air-filled neck mass that enlarged with Valsalva and was not associated with respiratory distress. The infant was found to have a third branchial cleft cyst with an internal opening into the pyriform sinus. The cyst was conservatively managed with endoscopic surgical decompression and cauterization of the tract and opening. We review the embryology of branchial cleft cysts and current management. PMID:26495186

  20. Air Mass Origin in the Arctic and its Response to Future Warming

    NASA Astrophysics Data System (ADS)

    Orbe, C.; Newman, P. A.; Waugh, D. W.; Holzer, M. B.; Oman, L.; Polvani, L. M.; Li, F.

    2014-12-01

    Long-range transport from Northern Hemisphere (NH) midlatitudes plays a key role in setting the distributions of trace species and aerosols in the Arctic. While comprehensive models project a strengthening and poleward shift in the midlatitude tropospheric jets in response to future warming, relatively little attention has been paid to assessing the large-scale transport response in the Arctic. A natural way to quantify transport and its future changes is in terms of rigorously defined air masses that partition air according to where it last contacted the planetary boundary layer (PBL). Here we present climatologies of Arctic air mass origin for NH winter and summer, computed from two integrations of the Goddard Earth Observing System chemistry-climate model (GEOSCCM) subject to present-day and future climate forcings. The modeled transport response to A1B greenhouse-gas induced warming reveals that in the future ~10% more air in the Arctic will originate over NH midlatitudes, with a slighter weaker albeit significant increase in winter compared to summer. Our results indicate that transport changes alone may lead to "cleaner" Arctic winters, as air will be 5-10% more likely to have last contacted the PBL over the East Pacific and the Atlantic Oceans and less likely to have originated over Europe and North America. Conversely, in future summers the air mass fractions originating over Asia and North America increase by ~10%, indicating that Arctic pollutant levels may be enhanced owing solely to changes in transport. In particular, our results suggest that more stringent emissions caps may be needed to combat enhanced transport into the Arctic from Asia, where increases in black carbon emissions have already posed concerns. Future changes in air mass fractions are interpreted in terms of large-scale circulation responses that are consistent with CMIP5 multi-model mean projections - namely, upward and poleward shifted meridional transient eddies in future winters and

  1. Measurement of mass attenuation coefficients in air by application of detector linearity tests

    NASA Astrophysics Data System (ADS)

    Peele, A. G.; Chantler, C. T.; Paterson, D.; McMahon, P. J.; Irving, T. H.; Lin, J. J.; Nugent, K. A.; Brunton, A. N.; McNulty, I.

    2002-10-01

    Accurate knowledge of x-ray mass attenuation coefficients is essential for studies as diverse as atomic physics, materials science, and radiation safety. However, a significant discrepancy exists between theoretical tabulated results for air at soft x-ray energies. We outline a precision measurement of the mass attenuation coefficients for air at various energies using two types of detectors and a simple test of detector response. We discuss whether sufficient accuracy can be obtained using this data to distinguish between competing theoretical estimates. In the process, we investigate the intensity response of two common synchrotron x-ray detectors: an x ray to optical charge-coupled device camera using a crystal scintillator and an x-ray sensitive photodiode.

  2. A fully mass conservative variable parameter McCarthy-Muskingum method: Theory and verification

    NASA Astrophysics Data System (ADS)

    Perumal, Muthiah; Price, Roland K.

    2013-10-01

    This paper presents the hydraulic derivation of a fully mass conservative, variable parameter McCarthy-Muskingum (VPMM) method derived directly from the Saint-Venant equations for routing flood waves in prismatic channels having any cross-section shape, and using the Manning's friction law. The approach employed in the development of the method theoretically justifies the heuristic assumption made by McCarthy in 1938 in expressing the channel reach storage of the Muskingum method in terms of prism and wedge storages. The approach advocated in this paper also provides a solution to the mass conservation problem associated with the variable parameter Muskingum routing method, which has been a major issue in the hydrological literature for the last three decades. Moreover, the VPMM method enables the simultaneous computation of the stage hydrograph corresponding to a given inflow or routed discharge hydrograph. The verification of the methodology and the evaluation of its performance in routing floods in three different shapes of a hypothetical channels are presented by reproducing the corresponding numerical solutions of the Saint-Venant equations. The results are also compared with the corresponding results of the mass conservative variable parameter Muskingum-Cunge-Todini method proposed by Todini in 2007 with and without the inclusion of the correction introduced by Cappelaere in 1997 for diffusion.

  3. Mass Market Demand Response and Variable Generation Integration Issues: A Scoping Study

    SciTech Connect

    Cappers, Peter; Mills, Andrew; Goldman, Charles; Wiser, Ryan; Eto, Joseph H.

    2011-09-10

    This scoping study focuses on the policy issues inherent in the claims made by some Smart Grid proponents that the demand response potential of mass market customers which is enabled by widespread implementation of Advanced Metering Infrastructure (AMI) through the Smart Grid could be the “silver bullet” for mitigating variable generation integration issues. In terms of approach, we will: identify key issues associated with integrating large amounts of variable generation into the bulk power system; identify demand response opportunities made more readily available to mass market customers through widespread deployment of AMI systems and how they can affect the bulk power system; assess the extent to which these mass market Demand Response (DR) opportunities can mitigate Variable Generation (VG) integration issues in the near-term and what electricity market structures and regulatory practices could be changed to further expand the ability for DR to mitigate VG integration issues over the long term; and provide a qualitative comparison of DR and other approaches to mitigate VG integration issues.

  4. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  5. Impacts of Typhoon and Air-Mass Pathways on Rainwater Chemical Compositions

    NASA Astrophysics Data System (ADS)

    Cheng, M.; You, C.

    2006-12-01

    To assess the importance of chemical fluxes on trace elements by wet precipitation, we have collected time- series rain waters between 06/20/04 and 09/20/05 for ICPMS and IC measurements. The sampling site is located at Tainan city in southwest Taiwan and there were four typhoons, namely Mindulle, Rananim, Aere, and Haima, hit the island during this period. Combining trace element compositions with HYSPLIT model for air-mass transportation designed by NOAA, we were able to understand possible source, flux and migration pathway of pollutants in rainwater. Our results show that seasalt contribution and trace element fluxes were higher during typhoon events. The Na and Pb flux varied largely, between 0.03~1388 and 0.0002~2000 mg/m2/day respectively, depended on the pathways of air mass trajectory and wind strength. It is clear that typhoons carry not only sea spray but also major anthropogenic pollutants from south Asia. Among the four typhoons, the Mindulle carried the largest fluxes of seasalt and trace elements while Rananim was weak in strength and brought the lowest Na and Pb due to less degree of mixing with air mass on land. The calculated enriched factors normalized to seawater (EFsea) were near unity for Na and Mg, but were much larger for K and Ca possibly due to crust source contamination and biomass burning. The EFcrust or EFsea values of various trace metals (e.g., V, Cr, Mn, Co, Ni, Cu, Zn, As, Ba and Pb were all significantly larger than 10 indicating the importance of anthropogenic sources. Interestingly, the PCA results confirm that rain waters with similar chemical characteristics have shared common air mass backward trajectory history.

  6. Seasonal, anthropogenic, air mass, and meteorological influences on the atmospheric concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs): Evidence for the importance of diffuse combustion sources

    SciTech Connect

    Lee, R.G.M.; Green, N.J.L.; Lohmann, R.; Jones, K.C.

    1999-09-01

    Sampling programs were undertaken to establish air polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) concentrations at a semirural site on the northwest coast of England in autumn and summer and to investigate factors causing their variability. Changing source inputs, meteorological parameters, air masses, and the impact of a festival when it is customary to light fireworks and bonfires were investigated. Various lines of evidence from the study point to diffuse, combustion-related sources being a major influence on ambient air concentrations. Higher PCDD/F concentrations were generally associated with air masses that had originated and moved over land, particularly during periods of low ambient temperature. Low concentrations were associated with air masses that had arrived from the Atlantic Ocean/Irish Sea to the west of the sampling site and had little or no contact with urban/industrialized areas. Concentrations in the autumn months were 2 to 10 times higher than those found in the summer.

  7. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    PubMed Central

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2− and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  8. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  9. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

    NASA Technical Reports Server (NTRS)

    Bugbee, B.; Monje, O.; Tanner, B.

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

  10. Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity.

    PubMed

    Bugbee, B; Monje, O; Tanner, B

    1996-01-01

    Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature. PMID:11538791

  11. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways

    NASA Astrophysics Data System (ADS)

    Liu, D. X.; Liu, Z. C.; Chen, C.; Yang, A. J.; Li, D.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2016-04-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H+, nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2‑ and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios.

  12. Aqueous reactive species induced by a surface air discharge: Heterogeneous mass transfer and liquid chemistry pathways.

    PubMed

    Liu, D X; Liu, Z C; Chen, C; Yang, A J; Li, D; Rong, M Z; Chen, H L; Kong, M G

    2016-01-01

    Plasma-liquid interaction is a critical area of plasma science and a knowledge bottleneck for many promising applications. In this paper, the interaction between a surface air discharge and its downstream sample of deionized water is studied with a system-level computational model, which has previously reached good agreement with experimental results. Our computational results reveal that the plasma-induced aqueous species are mainly H(+), nitrate, nitrite, H2O2 and O3. In addition, various short-lived aqueous species are also induced, regardless whether they are generated in the gas phase first. The production/loss pathways for aqueous species are quantified for an air gap width ranging from 0.1 to 2 cm, of which heterogeneous mass transfer and liquid chemistry are found to play a dominant role. The short-lived reactive oxygen species (ROS) and reactive nitrogen species (RNS) are strongly coupled in liquid-phase reactions: NO3 is an important precursor for short-lived ROS, and in turn OH, O2(-) and HO2 play a crucial role for the production of short-lived RNS. Also, heterogeneous mass transfer depends strongly on the air gap width, resulting in two distinct scenarios separated by a critical air gap of 0.5 cm. The liquid chemistry is significantly different in these two scenarios. PMID:27033381

  13. A New Sample of Candidate Intermediate-mass Black Holes Selected by X-Ray Variability

    NASA Astrophysics Data System (ADS)

    Kamizasa, Naoya; Terashima, Yuichi; Awaki, Hisamitsu

    2012-05-01

    We present the results of X-ray variability and spectral analysis of a sample of 15 new candidates for active galactic nuclei with relatively low-mass black holes (BHs). They are selected from the Second XMM-Newton Serendipitous Source Catalogue based on strong variability quantified by normalized excess variances. Their BH masses are estimated to be (1.1-6.6) × 106 M ⊙ by using a correlation between excess variance and BH mass. Seven sources have estimated BH masses smaller than 2 × 106 M ⊙, which are in the range for intermediate-mass black holes. Eddington ratios of sources with known redshifts range from 0.07 to 0.46 and the mean Eddington ratio is 0.24. These results imply that some of our sources are growing supermassive black holes, which are expected to have relatively low masses with high Eddington ratios. X-ray photon indices of the 15 sources are in the range of ≈0.57-2.57 and 5 among them have steep (>2) photon indices, which are the range for narrow-line Seyfert 1s. Soft X-ray excess is seen in 12 sources and is expressed by a blackbody model with kT ≈ 83-294 eV. We derive a correlation between X-ray photon indices and Eddington ratios, and find that the X-ray photon indices of about a half of our sources are flatter than the positive correlation suggested previously. Based on observations obtained with XMM-Newton, an ESA science mission with instruments and contributions directly funded by ESA Member States and NASA.

  14. Variable oxygen/nitrogen enriched intake air system for internal combustion engine applications

    DOEpatents

    Poola, Ramesh B.; Sekar, Ramanujam R.; Cole, Roger L.

    1997-01-01

    An air supply control system for selectively supplying ambient air, oxygen enriched air and nitrogen enriched air to an intake of an internal combustion engine includes an air mixing chamber that is in fluid communication with the air intake. At least a portion of the ambient air flowing to the mixing chamber is selectively diverted through a secondary path that includes a selectively permeable air separating membrane device due a differential pressure established across the air separating membrane. The permeable membrane device separates a portion of the nitrogen in the ambient air so that oxygen enriched air (permeate) and nitrogen enriched air (retentate) are produced. The oxygen enriched air and the nitrogen enriched air can be selectively supplied to the mixing chamber or expelled to atmosphere. Alternatively, a portion of the nitrogen enriched air can be supplied through another control valve to a monatomic-nitrogen plasma generator device so that atomic nitrogen produced from the nitrogen enriched air can be then injected into the exhaust of the engine. The oxygen enriched air or the nitrogen enriched air becomes mixed with the ambient air in the mixing chamber and then the mixed air is supplied to the intake of the engine. As a result, the air being supplied to the intake of the engine can be regulated with respect to the concentration of oxygen and/or nitrogen.

  15. Intake fraction variability between air pollution emission sources inside an urban area.

    PubMed

    Tainio, Marko; Holnicki, Piotr; Loh, Miranda M; Nahorski, Zbigniew

    2014-11-01

    The cost-effective mitigation of adverse health effects caused by air pollution requires information on the contribution of different emission sources to exposure. In urban areas the exposure potential of different sources may vary significantly depending on emission height, population density, and other factors. In this study, we quantified this intraurban variability by predicting intake fraction (iF) for 3,066 emission sources in Warsaw, Poland. iF describes the fraction of the pollutant that is inhaled by people in the study area. We considered the following seven pollutants: particulate matter (PM), nitrogen oxides (NOx), sulfur dioxide (SO2), benzo[a] pyrene (BaP), nickel (Ni), cadmium (Cd), and lead (Pb). Emissions for these pollutants were grouped into four emission source categories (Mobile, Area, High Point, and Other Point sources). The dispersion of the pollutants was predicted with the CALPUFF dispersion model using the year 2005 emission rate data and meteorological records. The resulting annual average concentrations were combined with population data to predict the contribution of each individual source to population exposure. The iFs for different pollutant-source category combinations varied between 51 per million (PM from Mobile sources) and 0.013 per million (sulfate PM from High Point sources). The intraurban iF variability for Mobile sources primary PM emission was from 4 per million to 100 per million with the emission-weighted iF of 44 per million. These results propose that exposure due to intraurban air pollution emissions could be decreased more effectively by specifically targeting sources with high exposure potency rather than all sources.

  16. Drought Variability in Eastern Part of Romania and its Connection with Large-Scale Air Circulation

    NASA Astrophysics Data System (ADS)

    Barbu, Nicu; Stefan, Sabina; Georgescu, Florinela

    2014-05-01

    Drought is a phenomenon that appears due to precipitation deficit and it is intensified by strong winds, high temperatures, low relative humidity and high insolation; in fact, all these factors lead to increasing of evapotranspiration processes that contribute to soil water deficit. The Standardized Precipitation Evapotranspiration Index (SPEI) take into account all this factors listed above. The temporal variability of the drought in Eastern part of Romania for 50 years, during the period 1961-2010, is investigated. This study is focused on the drought variability related to large scale air circulation. The gridded dataset with spatial resolution of 0.5º lat/lon of SPEI, (https://digital.csic.es/handle/10261/72264) were used to analyze drought periods in connection with large scale air circulation determinate from the two catalogues (GWT - GrossWetter-Typen and WLK - WetterLargenKlassifikation) defined in COST733Action. The GWT catalogue uses at input dataset the sea level pressure and the WLK catalogue uses as input dataset the geopotential field at 925 hPa and 500 hPa, wind at 700 hPa and total water content for entire atmospheric column. In this study we use the GWT catalogue with 18 circulation types and the WLK catalogue with 40 circulation types. The analysis for Barlad Hydrological Basin indicated that the negative values (that means water deficit - drought period) of SPEI are associated with prevailing anticyclonic regime and positive values (that means water excess - rainy period) of SPEI are associated with prevailing cyclonic regime as was expected. In last decade was observed an increase of dry period associated with an increase of anticyclonic activity over Romania. Using GWT18 catalogue the drought are associated with the north-eastern anticyclonic circulation type (NE-A). According to the WLK40 catalogue, the dominant circulation type associated with the drought is north-west-anticyclonic-dry anticyclonic (NW-AAD) type. keywords: drought, SPEI

  17. Tree-ring inferred glacier mass balance variation in southeastern Tibetan Plateau and its linkage with climate variability

    NASA Astrophysics Data System (ADS)

    Duan, J.; Wang, L.; Li, L.; Sun, Y.

    2013-07-01

    A large number of glaciers in the Tibetan Plateau (TP) have experienced wastage in recent decades. And the wastage is different from region to region, even from glacier to glacier. A better understanding of long-term glacier variations and their linkage with climate variability requires extending the presently observed records. Here we present the first tree-ring-based glacier mass balance (MB) reconstruction in the TP, performed at the Hailuogou Glacier in southeastern TP during 1865-2007. The reconstructed MB is characterized mainly by ablation over the past 143 yr, and typical melting periods occurs in 1910s-1920s, 1930s-1960s, 1970s-1980s, and the last 20 yr. After the 1900s, only a few short periods (i.e., 1920s-1930s, the 1960s and the late 1980s) is characterized by accumulation. These variations can be validated by the terminus retreat velocity of the Hailuogou Glacier and the ice-core accumulation rate in Guliya and respond well to regional and Northern Hemisphere temperature anomaly. In addition, the reconstructed MB is significantly and negatively correlated with August-September all-Indian monsoon precipitation (AIR) (r1871-2008= -0.342, p < 0.0001). These results suggest that temperature variability is the dominant factor for the long-term MB variation at the Hailuogou Glacier. Indian summer monsoon precipitation doesn't affect the MB variation, yet the significant negative correlation between the MB and the AIR implies the positive effect of summer heating of the TP on Indian summer monsoon precipitation.

  18. Tree-ring-inferred glacier mass balance variation in southeastern Tibetan Plateau and its linkage with climate variability

    NASA Astrophysics Data System (ADS)

    Duan, J.; Wang, L.; Li, L.; Sun, Y.

    2013-11-01

    A large number of glaciers in the Tibetan Plateau (TP) have experienced wastage in recent decades. And the wastage is different from region to region, even from glacier to glacier. A better understanding of long-term glacier variations and their linkage with climate variability requires extending the presently observed records. Here we present the first tree-ring-based glacier mass balance (MB) reconstruction in the TP, performed at the Hailuogou Glacier in southeastern TP during 1868-2007. The reconstructed MB is characterized mainly by ablation over the past 140 yr, and typical melting periods occurred in 1910s-1920s, 1930s-1960s, 1970s-1980s, and the last 20 yr. After the 1900s, only a few short periods (i.e., 1920s-1930s, the 1960s and the late 1980s) were characterized by accumulation. These variations can be validated by the terminus retreat velocity of Hailuogou Glacier and the ice-core accumulation rate in Guliya and respond well to regional and Northern Hemisphere temperature anomaly. In addition, the reconstructed MB is significantly and negatively correlated with August-September all-India monsoon rainfall (AIR) (r1871-2008 = -0.342, p < 0.0001). These results suggest that temperature variability is the dominant factor for the long-term MB variation at the Hailuogou Glacier. Indian summer monsoon precipitation does not affect the MB variation, yet the significant negative correlation between the MB and the AIR implies the positive effect of summer heating of the TP on Indian summer monsoon precipitation.

  19. Energy studies on central and variable refrigerant flow air-conditioning systems

    NASA Astrophysics Data System (ADS)

    Abdullah, H.; Nitamakwuavan, S.; Jalaludin, A. F.

    2012-06-01

    Air-conditioning is a major contributor to energy end-use in commercial buildings. Different types of airconditioning systems are installed in commercial buildings including packaged systems, split units and central systems. With the advancement in control technology and the demand for energy efficient systems, variable refrigerant flow (VRF) air-conditioning system is seen to be a solution to the load-matching problem for airconditioning systems. In a VRF system, the volume or flow rate of the refrigerant is accurately matched to the required cooling load thereby saving energy and providing more accurate control. This study aims to determine the performance of the VRF system used in an actual building by calculating the Coefficient of Performance (COP) of the system. The COP is then compared to the COP of a centralized chilled water system used in the same building. The results showed that the COPs determined for the VRF and central systems are 3.3 and 2.0 respectively. The results also indicated that replacing older central system with a VRF system could lead to an energy savings of up to 39.5%.

  20. Measurements of CO in an aircraft experiment and their correlation with biomass burning and air mass origin in South America

    NASA Astrophysics Data System (ADS)

    Boian, C.; Kirchhoff, V. W. J. H.

    Carbon monoxide (CO) measurements are obtained in an aircraft experiment during 1-7 September 2000, conducted over Central Brazil in a special region of anticyclonic circulation. This is a typical transport regime during the dry season (July-September), when intense biomass burning occurs, and which gives origin to the transport of burning poluents from the source to distant regions. This aircraft experiment included in situ measurements of CO concentrations in three different scenarios: (1) areas of fresh biomass burning air masses, or source areas; (2) areas of aged biomass burning air masses; and (3) areas of clean air or pristine air masses. The largest CO concentrations were of the order of 450 ppbv in the source region near Conceicao do Araguaia (PA), and the smallest value near 100 ppbv, was found in pristine air masses, for example, near the northeast coastline (clean air, or background region). The observed concentrations were compared to the number of fire pixels seen by the AVHRR satellite instrument. Backward isentropic trajectories were used to determine the origin of the air masses at each sampling point. From the association of the observed CO mixing ratios, fire pixels and air mass trajectories, the previous scenarios may be subdivided as follows: (1a) source regions of biomass burning with large CO concentrations; (1b) regions with few local fire pixels and absence of contributions by transport. Areas with these characteristics include the northeast region of Brazil; (1c) regions close to the source region and strongly affected by transport (region of Para and Amazonas); (2) regions that have a consistent convergence of air masses, that have traveled over biomass burning areas during a few days (western part of the Cerrado region); (3a) Pristine air masses with origin from the ocean; (3b) regions with convergent transport that has passed over areas of no biomass burning, such as frontal weather systems in the southern regions.

  1. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2016-10-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  2. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2015-12-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  3. Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

    NASA Astrophysics Data System (ADS)

    Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

    2015-10-01

    We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

  4. Variability in young very low mass stars: two surprises from spectrophotometric monitoring

    NASA Astrophysics Data System (ADS)

    Bozhinova, I.; Scholz, A.; Eislöffel, J.

    2016-05-01

    We present simultaneous photometric and spectroscopic observations of seven young and highly variable M dwarfs in star-forming regions in Orion, conducted in four observing nights with FOcal Reducer and low dispersion Spectrograph2 at European Southern Observatory/VLT. All seven targets show significant photometric variability in the I band, with amplitudes between 0.1-0.8 mag, The spectra, however, remain remarkably constant, with spectral type changes less than 0.5 subtypes. Thus, the brightness changes are not caused by veiling that `fills in' absorption features. Three objects in the σ Ori cluster (age ˜3 Myr) exhibit strong Hα emission and Hα variability, in addition to the continuum variations. Their behaviour is mostly consistent with the presence of spots with temperature of ˜300 K above the photosphere and filling factors between 0.2-0.4, in contrast to typical hotspots observed in more massive stars. The remaining targets near ɛ Ori, likely to be older, show eclipse-like light curves, no significant Hα activity and are better represented by variable extinction due to circumstellar material. Interestingly, two of them show no evidence of infrared excess emission. Our study shows that high-amplitude variability in young very low mass stars can be caused by different phenomena than in more massive T Tauri stars and can persist when the disc has disappeared and accretion has ceased.

  5. The Role of Auxiliary Variables in Deterministic and Deterministic-Stochastic Spatial Models of Air Temperature in Poland

    NASA Astrophysics Data System (ADS)

    Szymanowski, Mariusz; Kryza, Maciej

    2015-11-01

    Our study examines the role of auxiliary variables in the process of spatial modelling and mapping of climatological elements, with air temperature in Poland used as an example. The multivariable algorithms are the most frequently applied for spatialization of air temperature, and their results in many studies are proved to be better in comparison to those obtained by various one-dimensional techniques. In most of the previous studies, two main strategies were used to perform multidimensional spatial interpolation of air temperature. First, it was accepted that all variables significantly correlated with air temperature should be incorporated into the model. Second, it was assumed that the more spatial variation of air temperature was deterministically explained, the better was the quality of spatial interpolation. The main goal of the paper was to examine both above-mentioned assumptions. The analysis was performed using data from 250 meteorological stations and for 69 air temperature cases aggregated on different levels: from daily means to 10-year annual mean. Two cases were considered for detailed analysis. The set of potential auxiliary variables covered 11 environmental predictors of air temperature. Another purpose of the study was to compare the results of interpolation given by various multivariable methods using the same set of explanatory variables. Two regression models: multiple linear (MLR) and geographically weighted (GWR) method, as well as their extensions to the regression-kriging form, MLRK and GWRK, respectively, were examined. Stepwise regression was used to select variables for the individual models and the cross-validation method was used to validate the results with a special attention paid to statistically significant improvement of the model using the mean absolute error (MAE) criterion. The main results of this study led to rejection of both assumptions considered. Usually, including more than two or three of the most significantly

  6. The variability of California summertime marine stratus: impacts on surface air temperatures

    USGS Publications Warehouse

    Iacobellis, Sam F.; Cayan, Daniel R.

    2013-01-01

    This study investigates the variability of clouds, primarily marine stratus clouds, and how they are associated with surface temperature anomalies over California, especially along the coastal margin. We focus on the summer months of June to September when marine stratus are the dominant cloud type. Data used include satellite cloud reflectivity (cloud albedo) measurements, hourly surface observations of cloud cover and air temperature at coastal airports, and observed values of daily surface temperature at stations throughout California and Nevada. Much of the anomalous variability of summer clouds is organized over regional patterns that affect considerable portions of the coast, often extend hundreds of kilometers to the west and southwest over the North Pacific, and are bounded to the east by coastal mountains. The occurrence of marine stratus is positively correlated with both the strength and height of the thermal inversion that caps the marine boundary layer, with inversion base height being a key factor in determining their inland penetration. Cloud cover is strongly associated with surface temperature variations. In general, increased presence of cloud (higher cloud albedo) produces cooler daytime temperatures and warmer nighttime temperatures. Summer daytime temperature fluctuations associated with cloud cover variations typically exceed 1°C. The inversion-cloud albedo-temperature associations that occur at daily timescales are also found at seasonal timescales.

  7. Impact of ENSO on variability of AIRS retrieved CO2 over India

    NASA Astrophysics Data System (ADS)

    Ravi Kumar, K.; Tiwari, Yogesh K.; Revadekar, J. V.; Vellore, Ramesh; Guha, Tania

    2016-10-01

    This study investigates the impact of ENSO on the CO2 variability over the Indian subcontinent for the period 2003-2011 based on the relationships between NINO indices derived from the sea surface temperature (SST) and AIRS-retrieved mid-tropospheric CO2 concentrations. The NINO4 region exhibits positive influence on the variability of CO2 almost during the entire year except for the post-monsoon/winter months (October through December; OND). Significant positive relationship (correlation coefficient r = +0.68) between NINO4 index and CO2 levels is observed for the month of June, while negative relationship (r = -0.73) for the month of October, and the negative relationship tends to continue till November with decreasing magnitudes (r = -0.41). The spatial distribution of mid-tropospheric CO2 concentrations during El Niño and La Niña periods also indicate large-scale impact over the Indian subcontinent with positive (negative) anomalies of about 1-2 ppm during El Niño (La Niña).

  8. Surface Time-Variable Gravity Signals and Possible Sources Including Core Mass Flow

    NASA Technical Reports Server (NTRS)

    Chao, Benjamin F.; Kuang, Weijia

    2003-01-01

    Over two decades of geodetic satellite-laser-ranging (SLR) data show that the variation of the Earth's oblateness parameter J2 has a clear seasonal signal of amplitude of about 3e-10 and a secular decrease of about -2.8e-11/year, superimposed on some interesting interannual fluctuations. Physically, any change in mass distribution or/inside the Earth will be reflected in the time-variable gravity signal obtained outside the Earth, according to Newton s gravitational law. Therefore, such signal contains contributions from all geophysical sources that redistribute mass, on all temporal and spatial scales, including those from the core. Besides Earth rotation and geomagnetic field variations, the time-variable gravity also contains information linking Earth surface observations with internal core dynamical processes. The time scales of the gravity signal are critical in helping differentiate different contributions. The atmosphere and hydrosphere are responsible for the seasonal and much of the interannual and intraseasoanl fluctuations, while the secular trend is due mainly to the post-glacial rebound but possibly core mass flow. To estimate the latter effect, we use our MoSST (Modular, Scalable, Self-consistent, Three-dimensional) core dynamics model to forward simulate the core flow, and density variation due to the core convection. Our results suggest that, when upward continued to the surface, the J2 component of the core mass redistribution can reach an overall amplitude of e-11/year, approaching the SLR detectability and significant in geophysical terms. We also find a general westward drift of the mass flow, with a speed comparable to that of the geomagnetic westward drift.

  9. Variability of mass-size relationships in tropical Mesoscale Convective Systems

    NASA Astrophysics Data System (ADS)

    Fontaine, Emmanuel; Leroy, Delphine; Delanoë, Julien; Dupuy, Régis; Lilie, Lyle; Strapp, Walter; Protat, Alain; Schwarzenböeck, Alfons

    2015-04-01

    The mass of individual ice hydrometeors in Mesoscale Convective Systems (MCS) has been investigated in the past using different methods in order to retrieve power law type mass-size relationships m(D) with m = α D^β. This study focuses on the variability of mass-size relationships in different types of MCS. Three types of tropical MCS were sampled during different airborne campaigns: (i) continental MCS during the West African monsoon (Megha-Tropique 2010), (ii) oceanic MCS over the Indian Ocean (Megha-Tropique 2011), and (iii) coastal MCS during the North-Australian monsoon (HAIC-HIWC). Mass-size relationships of ice hydrometeors are derived from a combined analysis of particle images from 2D-array probes and associated reflectivity factors measured with a Doppler cloud radar (94GHz) on the same research aircraft. A theoretical study of numerous hydrometeor shapes simulated in 3D and arbitrarily projected on a 2D plan allowed to constrain the exponent β of the m(D) relationship as a function of the derived surface-diameter relationship S(D), which is likewise written as a power law. Since S(D) always can be determined for real data from 2D optical array probes or other particle imagers, the evolution of the m(D) exponent β can be calculated along the flight trajectory. Then the pre-factor α of m(D) is constrained from theoretical simulations of the radar reflectivity factor matching the measured reflectivity factor along the aircraft trajectory. Finally, the Condensed Water Content (CWC) is deduced from measured particle size distributions (PSD) and retrieved m(D) relationships along the flight trajectory. Solely for the HAIC-HIWC campaign (North Australian Monsoon) a bulk reference measurement (IKP instrument) of high CWC could be performed in order to compare with the above described CWC deduced from ice hydrometeor images and reflectivity factors. Both CWC are coherent. Mean profiles of m(D) coefficients, PSD, and CWC are calculated as a function of the

  10. Dynamics of a variable mass system applied to spacecraft rocket attitude theory

    NASA Astrophysics Data System (ADS)

    Mudge, Jason Dominic

    This research project is a study of the dynamics of a variable mass system. The scope of this research project is to gain understanding as to how a variable mass system will behave. The intent is to bring the level of understanding of variable mass dynamics higher and closer to the level of constant mass dynamics in the area of spacecrafts in particular. A main contribution is the finding of a set of criteria to minimize or eliminate the deviation of the nutation angle (or cone angle or angle of attack) of spacecraft rockets passively, i.e. without active control. The motivation for this research project is the Star 48 anomaly. The Star 48 is a solid rocket motor which has propelled (boosted) communication satellites from lower earth orbit to a higher one during the 1980's. The anomaly is that when the spacecraft rocket is being propelled, the nutation angle may deviate excessively which is considered undesirable. In the first part of this research project, a variable mass system is described and defined and the governing equations are derived. The type of governing equations derived are those that are most useful for analyzing the motion of a spacecraft rocket. The method of derivation makes use of Leibnitz Theorem, Divergence Theorem and Newton's Second Law of Motion. Next, the governing equations are specialized with several assumptions which are generally accepted assumptions applied in the analysis of spacecraft rockets. With these assumptions, the form governing equations is discussed and then the equations are solved analytically for the system's angular velocity. Having solved for the angular velocity of the system, the attitude of the system is obtained using a unique method which circumvents the nonlinearities that exist using Euler Angles and their kinematical equations. The attitude is approximately found analytically and a set of criteria is discussed which will minimize or eliminate the deviation of the nutation angle of a spacecraft rocket. Finally

  11. Impact of Air Temperature and SST Variability on Cholera Incidence in Southeastern Africa, 1971-2006

    NASA Astrophysics Data System (ADS)

    Paz, Shlomit

    2010-05-01

    The most important climatic parameter related to cholera outbreaks is the temperature, especially of the water bodies and the aquatic environment. This factor governs the survival and growth of V. cholerae, since it has a direct influence on its abundance in the environment, or alternatively, through its indirect influence on other aquatic organisms to which the pathogen is found to attach. Thus, the potential for cholera outbreaks may rise, parallel to the increase in ocean surface temperature. Indeed, recent studies indicate that global warming might create a favorable environment for V. cholerae and increase its incidence in vulnerable areas. Africa is vulnerable to climate variability. According to the recent IPCC report on Africa, the air temperature has indicated a significant warming trend since the 1960s. In recent years, most of the research into disease vectors in Africa related to climate variability has focused on malaria. The IPCC indicated that the need exists to examine the vulnerabilities and impacts of climatic factors on cholera in Africa. In light of this, the study uses a Poisson Regression Model to analyze the possible association between the cholera rates in southeastern Africa and the annual variability of air temperature and sea surface temperature (SST) at regional and hemispheric scales, for the period 1971-2006. Data description is as follows: Number of cholera cases per year in Uganda, Kenya, Rwanda, Burundi, Tanzania, Malawi, Zambia and Mozambique. Source: WHO Global Health Atlas - cholera. Seasonal and annual temperature time series: Regional scale: a) Air temperature for southeastern Africa (30° E-36° E, 5° S-17° S), source: NOAA NCEP-NCAR; b) Sea surface temperature, for the western Indian Ocean (0-20° S, 40° E-45° E), source: NOAA, Kaplan SST dataset. Hemispheric scale (for the whole Southern Hemisphere): a) Air temperature anomaly; b) Sea surface temperature anomaly. Source: CRU, University of East Anglia. The following

  12. Has Natural Variability Masked the Expected Increase in Antarctic Surface Mass Balance with Global Warming?

    NASA Astrophysics Data System (ADS)

    Previdi, M. J.; Polvani, L. M.

    2015-12-01

    One of the expected and rather paradoxical consequences of anthropogenic global warming is an increase in Antarctic surface mass balance (or net snow accumulation), as robustly simulated by both global and regional climate models. This surface mass balance (SMB) increase occurs because the higher moisture content of a warmer atmosphere leads to increases in precipitation, with this precipitation falling in the form of snow over Antarctica. Despite these robust model projections, however, observations indicate that there has been no significant change in Antarctic SMB during the past several decades. Here, we show that this apparent discrepancy between models and observations can be explained by the fact that the anthropogenic climate change signal is still relatively small compared to the noise associated with natural climate variability. Using an ensemble of 35 global coupled climate models to separate signal and noise, we find that the forced SMB increase due to global warming in recent decades is unlikely to be detectable in a statistical sense as a result of large natural SMB variability on interannual-to-multidecadal timescales. However, our analysis reveals that if the world continues to follow the present trajectory of greenhouse gas emissions, the anthropogenic impact on Antarctic SMB will emerge from natural variability by the middle of the current century. With this, SMB increases over Antarctica will begin to mitigate global sea-level rise, partially offsetting the effects of dynamic ice loss.

  13. Has Natural Variability Masked the Expected Increase in Antarctic Surface Mass Balance with Global Warming?

    NASA Astrophysics Data System (ADS)

    Previdi, Michael; Polvani, Lorenzo M.

    2016-04-01

    One of the expected and rather paradoxical consequences of anthropogenic global warming is an increase in Antarctic surface mass balance (or net snow accumulation), as robustly simulated by both global and regional climate models. This surface mass balance (SMB) increase occurs because the higher moisture content of a warmer atmosphere leads to increases in precipitation, with this precipitation falling in the form of snow over Antarctica. Despite these robust model projections, however, observations indicate that there has been no significant change in Antarctic SMB during the past several decades. Here, we show that this apparent discrepancy between models and observations can be explained by the fact that the anthropogenic climate change signal is still relatively small compared to the noise associated with natural climate variability. Using an ensemble of 35 global coupled climate models to separate signal and noise, we find that the forced SMB increase due to global warming in recent decades is unlikely to be detectable in a statistical sense as a result of large natural SMB variability on interannual-to-multidecadal timescales. However, our analysis reveals that if the world continues to follow the present trajectory of greenhouse gas emissions, the anthropogenic impact on Antarctic SMB will emerge from natural variability by the middle of the current century. With this, SMB increases over Antarctica will begin to mitigate global sea-level rise, partially offsetting the effects of dynamic ice loss.

  14. Suspended sediment from the Gangotri Glacier: Quantification, variability and associations with discharge and air temperature

    NASA Astrophysics Data System (ADS)

    Haritashya, Umesh K.; Singh, Pratap; Kumar, Naresh; Gupta, R. P.

    2006-04-01

    To understand the sediment delivery variation for a Himalayan Glacier (Gangotri Glacier, Garhwal Himalayas) and to determine its relationship with discharge and air temperature, suspended sediment samples and discharge data were collected near the glacier snout (4000 m) for four melt seasons during the period 2000-2003. These data were used to estimate suspended sediment concentration (SSC), suspended sediment load (SSL), sediment yield and erosion rate in the glacier melt stream (Bhagirathi). The monthly distribution of suspended sediment and its variability from year to year have been examined. Mean monthly SSC for May, June, July, August, September and October were found to be 1942, 2063, 3658, 2551, 734 and 136 mg l -1, respectively. Maximum SSC in meltwater was observed in July followed by August. It was found that the cumulative percentage delivery of SSC precedes discharge throughout the melt season. Mean monthly total SSL for May, June, July, August, September and October during the study period was found to be 149, 423, 1220, 746, 143 and 5×10 3 ton, respectively. The strong variability is found in SSL ( Cv=1.1) than SSC ( Cv=0.8) because computation of SSL includes both discharge ( Cv=0.6) and SSC. Delivery response of SSL in terms of percentage of total load is less in the early part of the melt season than in the later stage in comparison to that of discharge. This may be due to the fact that in the beginning of the melt season low melt rate conditions prevails and thus, the low discharge velocity could not flush out stored glacial sediment. It has been observed that 59-64% of the sediment passed through the channel by the time 50% of the total discharge passed. The average suspended sediment yield for the whole melt season from the study area was estimated to be about 4834 ton km -2 and corresponding erosion rate was 1.8 mm. The relationship between mean monthly SSC and discharge ( R2=0.99) is much better than the daily SSC and discharge ( R2

  15. Assessing Scales of Variability for Constituents Relevant to Future Geostationary Satellite Observations and Models of Air Quality

    NASA Astrophysics Data System (ADS)

    Crawford, J. H.; Ryerson, T. B.; Weinheimer, A. J.; Cohen, R. C.; Diskin, G. S.; Sachse, G. W.; Holloway, J.; Chen, G.

    2009-12-01

    Establishing appropriate specifications for satellite observations of atmospheric composition is a difficult and inexact task since neither models nor field observations can provide both the resolution and spatial coverage required. Despite shortcomings in temporal and spatial coverage, field observations are unique in capturing atmospheric variability on scales down to and below those of satellite observations. Airborne field observations from NOAA and NASA-sponsored field campaigns offer dense observations focused on air quality across North America. Here we use variogram analyses to assess spatial variability in key constituents (NO2, O3, CO, and SO2) for a number of air quality focused field campaigns (ICARTT, TEXAQS2000 and 2006, ARCTAS-CARB). The resulting variograms provide a useful metric for evaluating resolution requirements for future geostationary satellite observations. Variograms also provide an assessment of subgrid variability expected to influence nonlinear ozone photochemistry within air quality models based on a chosen model resolution.

  16. Preliminary experimental results on studying possibility of variable mass liner (VML) formation

    SciTech Connect

    1995-12-31

    The main objective of the present experiment was to study the formation process and initial stage of acceleration of a variable-mass plasma liner (VML). The method is based on magnetic acceleration of a liner with the mass reduced during such acceleration. The experiment was carried out on February 16 at VNIIEF. This report describes the results of measurements obtained in the experiment and preliminary analysis of the results characterizing operation of the test facility main units: helical EMG; 5-module disk EMG 400 mm in diameter (DEMG); ponderomotive unit (PU) with a cylindric condensed liner and a special tooth-cutoff. The first part of the report presents measurement results obtained on the VNIIEF`s diagnostic equipment that are compared with those obtained by American specialists on their diagnostic equipment. Information submitted by American specialists is included in part 2 of this report. The second part of the report presents preliminary computational-theoretic analysis of the main measured results describing operation of DEMG TL system in the experiment; experimental data are compared with theoretical ones obtained before and after the experiment. But more emphasis is placed on the data preliminary analysis indicating that in the experiment a variable mass liner is formed (VML or plasma bubble).

  17. On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

    2012-12-01

    The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

  18. Effects of selected design variables on three ramp, external compression inlet performance. [boundary layer control bypasses, and mass flow rate

    NASA Technical Reports Server (NTRS)

    Kamman, J. H.; Hall, C. L.

    1975-01-01

    Two inlet performance tests and one inlet/airframe drag test were conducted in 1969 at the NASA-Ames Research Center. The basic inlet system was two-dimensional, three ramp (overhead), external compression, with variable capture area. The data from these tests were analyzed to show the effects of selected design variables on the performance of this type of inlet system. The inlet design variables investigated include inlet bleed, bypass, operating mass flow ratio, inlet geometry, and variable capture area.

  19. Air flow assisted ionization for remote sampling of ambient mass spectrometry and its application.

    PubMed

    He, Jiuming; Tang, Fei; Luo, Zhigang; Chen, Yi; Xu, Jing; Zhang, Ruiping; Wang, Xiaohao; Abliz, Zeper

    2011-04-15

    Ambient ionization methods are an important research area in mass spectrometry (MS) analysis. Under ambient conditions, the gas flow and atmospheric pressure significantly affect the transfer and focusing of ions. The design and implementation of air flow assisted ionization (AFAI) as a novel and effective, remote sampling method for ambient mass spectrometry are described herein. AFAI benefits from a high extracting air flow rate. A systematic investigation of the extracting air flow in the AFAI system has been carried out, and it has been demonstrated not only that it plays a role in the effective capture and remote transport of charged droplets, but also that it promotes desolvation and ion formation, and even prevents ion fragmentation during the ionization process. Moreover, the sensitivity of remote sampling ambient MS analysis was improved significantly by the AFAI method. Highly polar and nonpolar molecules, including dyes, pharmaceutical samples, explosives, drugs of abuse, protein and volatile compounds, have been successfully analyzed using AFAI-MS. The successful application of the technique to residue detection on fingers, large object analysis and remote monitoring in real time indicates its potential for the analysis of a variety of samples, especially large objects. The ability to couple this technique with most commercially available MS instruments with an API interface further enhances its broad applicability.

  20. Seasonality of new particle formation in Vienna, Austria - Influence of air mass origin and aerosol chemical composition

    NASA Astrophysics Data System (ADS)

    Wonaschütz, Anna; Demattio, Anselm; Wagner, Robert; Burkart, Julia; Zíková, Naděžda; Vodička, Petr; Ludwig, Wolfgang; Steiner, Gerhard; Schwarz, Jaroslav; Hitzenberger, Regina

    2015-10-01

    The impact of air mass origin and season on aerosol chemical composition and new particle formation and growth events (NPF events) in Vienna, Austria, is investigated using impactor samples from short-term campaigns and two long-term number size distribution datasets. The results suggest that air mass origin is most important for bulk PM concentrations, chemical composition of the coarse fraction (>1.5 μm) and the mass size distribution, and less important for chemical composition of the fine fraction (<1.5 μm). Continental air masses (crustal elements) were distinguished from air masses of marine origin (traces of sea salt). NPF events were most frequent in summer (22% of measurement days), and least frequent in winter (3% of measurement days). They were associated with above-average solar radiation and ozone concentrations, but were largely independent of PM2.5. Air mass origin was a secondary influence on NPF, largely through its association with meteorological conditions. Neither a strong dependence on the PM2.5 loading of the air masses, nor indications of a source area for NPF precursors outside the city were found.

  1. FTO genotype is associated with phenotypic variability of body mass index

    PubMed Central

    Yang, Jian; Loos, Ruth J. F.; Powell, Joseph E.; Medland, Sarah E.; Speliotes, Elizabeth K.; Chasman, Daniel I.; Rose, Lynda M.; Thorleifsson, Gudmar; Steinthorsdottir, Valgerdur; Mägi, Reedik; Waite, Lindsay; Smith, Albert Vernon; Yerges-Armstrong, Laura M.; Monda, Keri L.; Hadley, David; Mahajan, Anubha; Li, Guo; Kapur, Karen; Vitart, Veronique; Huffman, Jennifer E.; Wang, Sophie R.; Palmer, Cameron; Esko, Tõnu; Fischer, Krista; Zhao, Jing Hua; Demirkan, Ayşe; Isaacs, Aaron; Feitosa, Mary F.; Luan, Jian’an; Heard-Costa, Nancy L.; White, Charles; Jackson, Anne U.; Preuss, Michael; Ziegler, Andreas; Eriksson, Joel; Kutalik, Zoltán; Frau, Francesca; Nolte, Ilja M.; Van Vliet-Ostaptchouk, Jana V.; Hottenga, Jouke-Jan; Jacobs, Kevin B.; Verweij, Niek; Goel, Anuj; Medina-Gomez, Carolina; Estrada, Karol; Bragg-Gresham, Jennifer Lynn; Sanna, Serena; Sidore, Carlo; Tyrer, Jonathan; Teumer, Alexander; Prokopenko, Inga; Mangino, Massimo; Lindgren, Cecilia M.; Assimes, Themistocles L.; Shuldiner, Alan R.; Hui, Jennie; Beilby, John P.; McArdle, Wendy L.; Hall, Per; Haritunians, Talin; Zgaga, Lina; Kolcic, Ivana; Polasek, Ozren; Zemunik, Tatijana; Oostra, Ben A.; Junttila, M. Juhani; Grönberg, Henrik; Schreiber, Stefan; Peters, Annette; Hicks, Andrew A.; Stephens, Jonathan; Foad, Nicola S.; Laitinen, Jaana; Pouta, Anneli; Kaakinen, Marika; Willemsen, Gonneke; Vink, Jacqueline M.; Wild, Sarah H.; Navis, Gerjan; Asselbergs, Folkert W.; Homuth, Georg; John, Ulrich; Iribarren, Carlos; Harris, Tamara; Launer, Lenore; Gudnason, Vilmundur; O’Connell, Jeffrey R.; Boerwinkle, Eric; Cadby, Gemma; Palmer, Lyle J.; James, Alan L.; Musk, Arthur W.; Ingelsson, Erik; Psaty, Bruce M.; Beckmann, Jacques S.; Waeber, Gerard; Vollenweider, Peter; Hayward, Caroline; Wright, Alan F.; Rudan, Igor; Groop, Leif C.; Metspalu, Andres; Khaw, Kay Tee; van Duijn, Cornelia M.; Borecki, Ingrid B.; Province, Michael A.; Wareham, Nicholas J.; Tardif, Jean-Claude; Huikuri, Heikki V.; Cupples, L. Adrienne; Atwood, Larry D.; Fox, Caroline S.; Boehnke, Michael; Collins, Francis S.; Mohlke, Karen L.; Erdmann, Jeanette; Schunkert, Heribert; Hengstenberg, Christian; Stark, Klaus; Lorentzon, Mattias; Ohlsson, Claes; Cusi, Daniele; Staessen, Jan A.; Van der Klauw, Melanie M.; Pramstaller, Peter P.; Kathiresan, Sekar; Jolley, Jennifer D.; Ripatti, Samuli; Jarvelin, Marjo-Riitta; de Geus, Eco J. C.; Boomsma, Dorret I.; Penninx, Brenda; Wilson, James F.; Campbell, Harry; Chanock, Stephen J.; van der Harst, Pim; Hamsten, Anders; Watkins, Hugh; Hofman, Albert; Witteman, Jacqueline C.; Zillikens, M. Carola; Uitterlinden, André G.; Rivadeneira, Fernando; Zillikens, M. Carola; Kiemeney, Lambertus A.; Vermeulen, Sita H.; Abecasis, Goncalo R.; Schlessinger, David; Schipf, Sabine; Stumvoll, Michael; Tönjes, Anke; Spector, Tim D.; North, Kari E.; Lettre, Guillaume; McCarthy, Mark I.; Berndt, Sonja I.; Heath, Andrew C.; Madden, Pamela A. F.; Nyholt, Dale R.; Montgomery, Grant W.; Martin, Nicholas G.; McKnight, Barbara; Strachan, David P.; Hill, William G.; Snieder, Harold; Ridker, Paul M.; Thorsteinsdottir, Unnur; Stefansson, Kari; Frayling, Timothy M.; Hirschhorn, Joel N.; Goddard, Michael E.; Visscher, Peter M.

    2013-01-01

    There is evidence across several species for genetic control of phenotypic variation of complex traits1–4, such that the variance among phenotypes is genotype dependent. Understanding genetic control of variability is important in evolutionary biology, agricultural selection programmes and human medicine, yet for complex traits, no individual genetic variants associated with variance, as opposed to the mean, have been identified. Here we perform a meta-analysis of genome-wide association studies of phenotypic variation using 170,000 samples on height and body mass index (BMI) in human populations. We report evidence that the single nucleotide polymorphism (SNP) rs7202116 at the FTO gene locus, which is known to be associated with obesity (as measured by mean BMI for each rs7202116 genotype)5–7, is also associated with phenotypic variability. We show that the results are not due to scale effects or other artefacts, and find no other experiment-wise significant evidence for effects on variability, either at loci other than FTO for BMI or at any locus for height. The difference in variance for BMI among individuals with opposite homozygous genotypes at the FTO locus is approximately 7%, corresponding to a difference of 0.5 kilograms in the standard deviation of weight. Our results indicate that genetic variants can be discovered that are associated with variability, and that between-person variability in obesity can partly be explained by the genotype at the FTO locus. The results are consistent with reported FTO by environment interactions for BMI8, possibly mediated by DNA methylation9,10. Our BMI results for other SNPs and our height results for all SNPs suggest that most genetic variants, including those that influence mean height or mean BMI, are not associated with phenotypic variance, or that their effects on variability are too small to detect even with samples sizes greater than 100,000. PMID:22982992

  2. FTO genotype is associated with phenotypic variability of body mass index.

    PubMed

    Yang, Jian; Loos, Ruth J F; Powell, Joseph E; Medland, Sarah E; Speliotes, Elizabeth K; Chasman, Daniel I; Rose, Lynda M; Thorleifsson, Gudmar; Steinthorsdottir, Valgerdur; Mägi, Reedik; Waite, Lindsay; Smith, Albert Vernon; Yerges-Armstrong, Laura M; Monda, Keri L; Hadley, David; Mahajan, Anubha; Li, Guo; Kapur, Karen; Vitart, Veronique; Huffman, Jennifer E; Wang, Sophie R; Palmer, Cameron; Esko, Tõnu; Fischer, Krista; Zhao, Jing Hua; Demirkan, Ayşe; Isaacs, Aaron; Feitosa, Mary F; Luan, Jian'an; Heard-Costa, Nancy L; White, Charles; Jackson, Anne U; Preuss, Michael; Ziegler, Andreas; Eriksson, Joel; Kutalik, Zoltán; Frau, Francesca; Nolte, Ilja M; Van Vliet-Ostaptchouk, Jana V; Hottenga, Jouke-Jan; Jacobs, Kevin B; Verweij, Niek; Goel, Anuj; Medina-Gomez, Carolina; Estrada, Karol; Bragg-Gresham, Jennifer Lynn; Sanna, Serena; Sidore, Carlo; Tyrer, Jonathan; Teumer, Alexander; Prokopenko, Inga; Mangino, Massimo; Lindgren, Cecilia M; Assimes, Themistocles L; Shuldiner, Alan R; Hui, Jennie; Beilby, John P; McArdle, Wendy L; Hall, Per; Haritunians, Talin; Zgaga, Lina; Kolcic, Ivana; Polasek, Ozren; Zemunik, Tatijana; Oostra, Ben A; Junttila, M Juhani; Grönberg, Henrik; Schreiber, Stefan; Peters, Annette; Hicks, Andrew A; Stephens, Jonathan; Foad, Nicola S; Laitinen, Jaana; Pouta, Anneli; Kaakinen, Marika; Willemsen, Gonneke; Vink, Jacqueline M; Wild, Sarah H; Navis, Gerjan; Asselbergs, Folkert W; Homuth, Georg; John, Ulrich; Iribarren, Carlos; Harris, Tamara; Launer, Lenore; Gudnason, Vilmundur; O'Connell, Jeffrey R; Boerwinkle, Eric; Cadby, Gemma; Palmer, Lyle J; James, Alan L; Musk, Arthur W; Ingelsson, Erik; Psaty, Bruce M; Beckmann, Jacques S; Waeber, Gerard; Vollenweider, Peter; Hayward, Caroline; Wright, Alan F; Rudan, Igor; Groop, Leif C; Metspalu, Andres; Khaw, Kay Tee; van Duijn, Cornelia M; Borecki, Ingrid B; Province, Michael A; Wareham, Nicholas J; Tardif, Jean-Claude; Huikuri, Heikki V; Cupples, L Adrienne; Atwood, Larry D; Fox, Caroline S; Boehnke, Michael; Collins, Francis S; Mohlke, Karen L; Erdmann, Jeanette; Schunkert, Heribert; Hengstenberg, Christian; Stark, Klaus; Lorentzon, Mattias; Ohlsson, Claes; Cusi, Daniele; Staessen, Jan A; Van der Klauw, Melanie M; Pramstaller, Peter P; Kathiresan, Sekar; Jolley, Jennifer D; Ripatti, Samuli; Jarvelin, Marjo-Riitta; de Geus, Eco J C; Boomsma, Dorret I; Penninx, Brenda; Wilson, James F; Campbell, Harry; Chanock, Stephen J; van der Harst, Pim; Hamsten, Anders; Watkins, Hugh; Hofman, Albert; Witteman, Jacqueline C; Zillikens, M Carola; Uitterlinden, André G; Rivadeneira, Fernando; Zillikens, M Carola; Kiemeney, Lambertus A; Vermeulen, Sita H; Abecasis, Goncalo R; Schlessinger, David; Schipf, Sabine; Stumvoll, Michael; Tönjes, Anke; Spector, Tim D; North, Kari E; Lettre, Guillaume; McCarthy, Mark I; Berndt, Sonja I; Heath, Andrew C; Madden, Pamela A F; Nyholt, Dale R; Montgomery, Grant W; Martin, Nicholas G; McKnight, Barbara; Strachan, David P; Hill, William G; Snieder, Harold; Ridker, Paul M; Thorsteinsdottir, Unnur; Stefansson, Kari; Frayling, Timothy M; Hirschhorn, Joel N; Goddard, Michael E; Visscher, Peter M

    2012-10-11

    There is evidence across several species for genetic control of phenotypic variation of complex traits, such that the variance among phenotypes is genotype dependent. Understanding genetic control of variability is important in evolutionary biology, agricultural selection programmes and human medicine, yet for complex traits, no individual genetic variants associated with variance, as opposed to the mean, have been identified. Here we perform a meta-analysis of genome-wide association studies of phenotypic variation using ∼170,000 samples on height and body mass index (BMI) in human populations. We report evidence that the single nucleotide polymorphism (SNP) rs7202116 at the FTO gene locus, which is known to be associated with obesity (as measured by mean BMI for each rs7202116 genotype), is also associated with phenotypic variability. We show that the results are not due to scale effects or other artefacts, and find no other experiment-wise significant evidence for effects on variability, either at loci other than FTO for BMI or at any locus for height. The difference in variance for BMI among individuals with opposite homozygous genotypes at the FTO locus is approximately 7%, corresponding to a difference of ∼0.5 kilograms in the standard deviation of weight. Our results indicate that genetic variants can be discovered that are associated with variability, and that between-person variability in obesity can partly be explained by the genotype at the FTO locus. The results are consistent with reported FTO by environment interactions for BMI, possibly mediated by DNA methylation. Our BMI results for other SNPs and our height results for all SNPs suggest that most genetic variants, including those that influence mean height or mean BMI, are not associated with phenotypic variance, or that their effects on variability are too small to detect even with samples sizes greater than 100,000.

  3. Variability and mass loss in IA O-B-A supergiants

    NASA Technical Reports Server (NTRS)

    Schild, R. E.; Garrison, R. F.; Hiltner, W. A.

    1983-01-01

    Recently completed catalogs of MK spectral types and UBV photometry of 1227 OB stars in the southern Milky Way have been analyzed to investigate brightness and color variability among the Ia supergiants. It is found that brightness variability is common among the O9-B1 supergiants with typical amplitudes about 0.1 and time scales longer than a week and shorter than 1000 days. Among the A supergiants fluctuations in U-B color are found on similar time scales and with amplitude about 0.1. For many early Ia supergiants there is a poor correlation between Balmer jump and spectral type, as had been known previously. An attempt to correlate the Balmer jump deficiency with mass loss rate yielded uncertain results.

  4. Southern Hemisphere water mass conversion linked with North Atlantic climate variability.

    PubMed

    Pahnke, Katharina; Zahn, Rainer

    2005-03-18

    Intermediate water variability at multicentennial scales is documented by 340,000-year-long isotope time series from bottom-dwelling foraminifers at a mid-depth core site in the southwest Pacific. Periods of sudden increases in intermediate water production are linked with transient Southern Hemisphere warm episodes, which implies direct control of climate warming on intermediate water conversion at high southern latitudes. Coincidence with episodes of climate cooling and minimum or halted deepwater convection in the North Atlantic provides striking evidence for interdependence of water mass conversion in both hemispheres, with implications for interhemispheric forcing of ocean thermohaline circulation and climate instability.

  5. Southern Hemisphere water mass conversion linked with North Atlantic climate variability.

    PubMed

    Pahnke, Katharina; Zahn, Rainer

    2005-03-18

    Intermediate water variability at multicentennial scales is documented by 340,000-year-long isotope time series from bottom-dwelling foraminifers at a mid-depth core site in the southwest Pacific. Periods of sudden increases in intermediate water production are linked with transient Southern Hemisphere warm episodes, which implies direct control of climate warming on intermediate water conversion at high southern latitudes. Coincidence with episodes of climate cooling and minimum or halted deepwater convection in the North Atlantic provides striking evidence for interdependence of water mass conversion in both hemispheres, with implications for interhemispheric forcing of ocean thermohaline circulation and climate instability. PMID:15774752

  6. Apparatus and Method for Measuring Air Temperature Ahead of an Aircraft for Controlling a Variable Inlet/Engine Assembly

    NASA Technical Reports Server (NTRS)

    Gary, Bruce L. (Inventor)

    2001-01-01

    The apparatus and method employ remote sensing to measure the air temperature a sufficient distance ahead of the aircraft to allow time for a variable inlet/engine assembly to be reconfigured in response to the measured temperature, to avoid inlet unstart and/or engine compressor stall. In one embodiment, the apparatus of the invention has a remote sensor for measuring at least one air temperature ahead of the vehicle and an inlet control system for varying the inlet. The remote sensor determines a change in temperature value using at least one temperature measurement and prior temperature measurements corresponding to the location of the aircraft. The control system uses the change in air temperature value to vary the inlet configuration to maintain the position of the shock wave during the arrival of the measured air in the inlet. In one embodiment, the method of the invention includes measuring at least one air temperature ahead of the vehicle, determining an air temperature at the vehicle from prior air temperature measurements, determining a change in temperature value using the air temperature at the vehicle and the at least one air temperature measurement ahead of the vehicle, and using the change in temperature value to-reposition the airflow inlet, to cause the shock wave to maintain substantially the same position within the inlet as the airflow temperature changes within the inlet.

  7. Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry.

    PubMed

    Hengel, Matt; Lee, P

    2014-03-01

    Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil, chlorthal-dimethyl, cycloate, dicloran, dicofol, EPTC, ethalfluralin, iprodione, mefenoxam, metolachlor, PCNB, permethrin, pronamide, simazine, trifluralin, and vinclozolin. A GC with a flame photometric detector was used to determine chlorpyrifos, chlorpyrifos oxon, diazinon, diazinon oxon, dimethoate, dimethoate oxon, fonophos, fonophos oxon, malathion, malathion oxon, naled, and oxydemeton. Trapping efficiencies ranged from 78 to 92 % for low level (0.5 μg) and 37-104 % for high level (50 and 100 μg) recoveries. Little to no degradation of compounds occurred over 31 days; recoveries ranged from 78 to 113 %. In the California Department of Food and Agriculture (CDFA) method, pesticides were detected by analyzing the extract by GC-MS to determine chlorothalonil, chlorpyrifos, cypermethrin, dichlorvos, dicofol, endosulfan 1, endosulfan sulfate, oxyfluorfen, permethrin, propargite, and trifluralin. A liquid chromatograph coupled to a MS was used to determine azinphos-methyl, chloropyrifos oxon, DEF, diazinon, diazinon oxon, dimethoate, dimethoate oxon, diuron, EPTC, malathion, malathion oxon, metolachlor, molinate, norflurazon, oryzalin, phosmet, propanil, simazine and thiobencarb. Trapping efficiencies for compounds determined by the CDFA method ranged from 10 to 113, 22 to 114, and 56 to 132 % for 10, 5, and 2 μg spikes, respectively. Storage tests yielded 70-170 % recovery for up to 28 days. These multiresidue methods represent flexible, sensitive, accurate, and cost-effective ways to determine residues of various pesticides in ambient air. PMID:24370860

  8. Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 2

    NASA Technical Reports Server (NTRS)

    Hovel, H.; Woodall, J. M.

    1976-01-01

    Crystal growth procedures, fabrication techniques, and theoretical analysis were developed in order to make GaAlAs-GaAs solar cell structures which exhibit high performance at air mass 0 illumination and high temperature conditions.

  9. An examination of exposure measurement error from air pollutant spatial variability in time-series studies.

    PubMed

    Sarnat, Stefanie E; Klein, Mitchel; Sarnat, Jeremy A; Flanders, W Dana; Waller, Lance A; Mulholland, James A; Russell, Armistead G; Tolbert, Paige E

    2010-03-01

    Relatively few studies have evaluated the effects of heterogeneous spatiotemporal pollutant distributions on health risk estimates in time-series analyses that use data from a central monitor to assign exposures. We present a method for examining the effects of exposure measurement error relating to spatiotemporal variability in ambient air pollutant concentrations on air pollution health risk estimates in a daily time-series analysis of emergency department visits in Atlanta, Georgia. We used Poisson generalized linear models to estimate associations between current-day pollutant concentrations and circulatory emergency department visits for the 1998-2004 time period. Data from monitoring sites located in different geographical regions of the study area and at different distances from several urban geographical subpopulations served as alternative measures of exposure. We observed associations for spatially heterogeneous pollutants (CO and NO(2)) using data from several different urban monitoring sites. These associations were not observed when using data from the most rural site, located 38 miles from the city center. In contrast, associations for spatially homogeneous pollutants (O(3) and PM(2.5)) were similar, regardless of the monitoring site location. We found that monitoring site location and the distance of a monitoring site to a population of interest did not meaningfully affect estimated associations for any pollutant when using data from urban sites located within 20 miles from the population center under study. However, for CO and NO(2), these factors were important when using data from rural sites located > or = 30 miles from the population center, most likely owing to exposure measurement error. Overall, our findings lend support to the use of pollutant data from urban central sites to assess population exposures within geographically dispersed study populations in Atlanta and similar cities. PMID:19277071

  10. Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

    NASA Astrophysics Data System (ADS)

    Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

    2015-04-01

    While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

  11. Development and characterisation of a state-of-the-art GOME-2 formaldehyde air-mass factor algorithm

    NASA Astrophysics Data System (ADS)

    Hewson, W.; Barkley, M. P.; Gonzalez Abad, G.; Bösch, H.; Kurosu, T.; Spurr, R.

    2015-01-01

    Space-borne observations of formaldehyde (HCHO) are frequently used to derive surface emissions of isoprene, an important biogenic volatile organic compound. The conversion of retrieved HCHO slant column concentrations from satellite line of sight measurements to vertical columns is determined through application of an air mass factor (AMF), accounting for instrument viewing geometry, radiative transfer, and vertical profile of the absorber in the atmosphere. This step in the trace gas retrieval is subject to large errors. This work presents the AMF algorithm in use at the University of Leicester (UoL), which introduces scene specific variables into a per-observation full radiative transfer AMF calculation, including increasing spatial resolution of key environmental parameter databases, input variable area weighting, instrument specific scattering weight calculation, and inclusion of an ozone vertical profile climatology. Application of these updates to HCHO slant columns from the GOME-2 instrument is shown to typically adjust the AMF by ±10%, compared to a~reference algorithm without these advanced parameterisations. Furthermore, the new UoL algorithm also incorporates a full radiative transfer error calculation for each scene to help characterise AMF uncertainties. Global median AMF errors are typically 50-60%, and are dominated by uncertainties in the HCHO profile shape and its corresponding seasonal variation.

  12. What is the role of wind pumping on heat and mass transfer rates at the air-snow interface?

    NASA Astrophysics Data System (ADS)

    Helgason, W.; Pomeroy, J. W.

    2010-12-01

    Accurate prediction of the turbulent exchange of sensible heat and water vapour between the atmosphere and snowpack remains a challenging task under all but the most ideal conditions. Heat and mass transfer coefficients that recognize the unique properties of the snow surface are warranted. A particular area requiring improvement concerns the role of the porous nature of snow which provides a large surface area for heat and mass exchange with the atmosphere. Wind-pumping has long been considered as a viable mechanism for incorporating aerosols into snowpacks; however these processes are not considered in parameterization schemes for heat and mass transfer near the surface. This study attempts to determine the degree to which wind pumping can increase the rates of heat and mass transfer to snow, and to ascertain which structural properties of the snowpack are needed for inclusion in heat and mass transfer coefficients that reflect wind pumping processes. Based upon a review of recent geophysical and engineering literature where porous surfaces are exploited for their ability to augment heat and mass transfer rates, a technical analysis was conducted. Numerous conceptual mechanisms of wind pumping were considered: topographically-induced flow; barometric pressure changes; high frequency pressure fluctuations at the surface; and steady flow in the interfacial region. A sensitivity analysis was performed, subjecting each conceptual model to varying thermal and hydraulic conditions at the air-snow interface, as well as variable micro-structural properties of snow. It is shown that the rate of heat and mass exchange is most sensitive to the interfacial thermal conditions and factors controlling the energy balance of the uppermost snow grains. The effect upon the thermal regime of the snowpack was found to be most significant for mechanisms of wind pumping that result in shorter flow paths near the surface, rather than those caused by low frequency pressure changes. In

  13. Variable stars in the VVV globular clusters. I. 2MASS-GC 02 and Terzan 10

    SciTech Connect

    Alonso-García, Javier; Dékány, István; Catelan, Márcio; Ramos, Rodrigo Contreras; Gran, Felipe; Leyton, Paul; Minniti, Dante; Amigo, Pía E-mail: idekany@astro.puc.cl E-mail: rcontrer@astro.puc.cl E-mail: pia.amigo@uv.cl E-mail: dante@astrofisica.cl

    2015-03-01

    The VISTA Variables in the Vía Láctea (VVV) ESO Public Survey is opening a new window to study inner Galactic globular clusters (GCs) using their variable stars. These GCs have been neglected in the past due to the difficulties caused by the presence of elevated extinction and high field stellar densities in their lines of sight. However, the discovery and study of any present variables in these clusters, especially RR Lyrae stars, can help to greatly improve the accuracy of their physical parameters. It can also help to shed some light on the questions raised by the intriguing Oosterhoff dichotomy in the Galactic GC system. In a series of papers we plan to explore variable stars in the GCs falling inside the field of the VVV survey. In this first paper, we search for and study the variables present in two highly reddened, moderately metal-poor, faint, inner Galactic GCs: 2MASS-GC 02 and Terzan 10. We report the discovery of sizable populations of RR Lyrae stars in both GCs. We use near-infrared period–luminosity relations to determine the color excess of each RR Lyrae star, from which we obtain both accurate distances to the GCs and the ratios of the selective-to-total extinction in their directions. We find the extinction toward both clusters to be elevated, non-standard, and highly differential. We also find both clusters to be closer to the Galactic center than previously thought, with Terzan 10 being on the far side of the Galactic bulge. Finally, we discuss their Oosterhoff properties, and conclude that both clusters stand out from the dichotomy followed by most Galactic GCs.

  14. Diode laser-based air mass flux sensor for subsonic aeropropulsion inlets

    NASA Astrophysics Data System (ADS)

    Miller, Michael F.; Kessler, William J.; Allen, Mark G.

    1996-08-01

    An optical air mass flux sensor based on a compact, room-temperature diode laser in a fiber-coupled delivery system has been tested on a full-scale gas turbine engine. The sensor is based on simultaneous measurements of O 2 density and Doppler-shifted velocity along a line of sight across the inlet duct. Extensive tests spanning engine power levels from idle to full afterburner demonstrate accuracy and precision of the order of 1 2 of full scale in density, velocity, and mass flux. The precision-limited velocity at atmospheric pressure was as low as 40 cm s. Multiple data-reduction procedures are quantitatively compared to suggest optimal strategies for flight sensor packages.

  15. Effects of Mass and Volume Fraction Skewness in Variable Density Mixing Processes

    NASA Astrophysics Data System (ADS)

    Wachtor, Adam J.; Bakosi, Jozsef; Ristorcelli, Raymond

    2015-11-01

    Among the parameters characterizing mixing by variable density turbulence of fluids involving density variations of a factor of 5 to 10 are the Atwood, Froude, Schmidt, and Reynolds numbers. There is evidence that the amount of each fluid present when the two pure fluids mix, as described by the probability density function of the mass or molar (volume) fraction, also strongly affects the mixing process. To investigate this phenomena, implicit large-eddy simulations (ILES) are performed for binary fluid mixtures in statistically homogenous environments under constant acceleration. These coarse grained simulations are used as data for theory validation and mix model development. ILES has been demonstrated to accurately capture the mixing behavior of a passive scalar field through stirring and advection by a turbulent velocity field. The present work advances that research and studies the extent to which an under-resolved active scalar drives the subsequent fluid motion and determines the nature of the mixing process. Effects of initial distributions of the mass and molar (volume) fraction probability density function on the resulting variable density turbulence and mixing are investigated and compared to direct numerical simulations from the Johns Hopkins Turbulence Database. Funded by the LANL LDRD-ER on ``Inserting Nonlinear N-Material Coupling PDF Information into Turbulent Mixing Models'' through exploratory research project number 20150498ER.

  16. Luminous Blue Variables are Antisocial: Their Isolation Implies they are Kicked Mass Gainers in Binary Evolution

    NASA Astrophysics Data System (ADS)

    Tombleson, Ryan; Smith, Nathan

    2015-01-01

    Based on their relatively isolated environments, we argue that luminous blue variables (LBVs) must be primarily the product of binary evolution, challenging the traditional single-star view wherein LBVs mark a brief transition between massive O-type stars and Wolf-Rayet (WR) stars. If the latter were true, then LBVs should be concentrated in young massive clusters like early O-type stars. This is decidedly not the case. Examining locations of LBVs in our Galaxy and the Magellanic Clouds reveals that, with few exceptions, LBVs systematically avoid clusters of O-type stars. In the Large Magellanic Cloud, LBVs are statistically much more isolated than O-type stars, and (perhaps most surprisingly) even more isolated than WR stars. This makes it impossible for LBVs to be single 'massive stars in transition' to WR stars. Instead, we propose that massive stars and supernova (SN) subtypes are dominated by bifurcated evolutionary paths in interacting binaries, wherein most WR stars and SNe Ibc correspond to the mass donors, while LBVs (and their lower-mass analogs like B[e] supergiants, which are even more isolated) are the mass gainers. In this view, LBVs are evolved massive blue stragglers. Through binary mass transfer, rejuvinated mass gainers get enriched, spun up, and sometimes kicked far from their clustered birthsites by their companion's SN. This scenario agrees better with LBVs exploding as Type IIn SNe in isolation, and it predicts that many massive runaway stars may be rapid rotators. Mergers or Thorne-Zykow objects might also give rise to LBVs, but these scenarios may have a harder time explaining why LBVs avoid clusters.

  17. Probing the spatial and temporal variability of Enceladus mass-loading from ion cyclotron waves

    NASA Astrophysics Data System (ADS)

    Wei, H.; Russell, C. T.; Powell, R. L.; Cowee, M.; Leisner, J. S.; Jia, Y.; Dougherty, M. K.

    2013-12-01

    Enceladus plays a critical role in the Saturnian system by loading a significant amount of neutrals, ions and dust into the inner magnetosphere. Enceladus is also considered as the ultimate source for the dusty E-ring and the extended neutral cloud from 3.5 to 6.5 Saturn radii. When the freshly-added neutrals are ionized and accelerated by the electric and magnetic fields, left-handed electromagnetic waves, called ion cyclotron waves (ICW), grow from the free energy of the highly anisotropic distribution of these ions. The ICWs have been widely used to probe the rate of mass loading in different plasma environments in the solar system, because the wave power is proportional to the density and energy of the pickup ions. At Enceladus, ICWs are detected by Cassini not only near the moon but throughout the extended neutral cloud in all local times. However, the wave power is largely enhanced near the moon's longitude rather than far away from it. This indicates that on top of the relatively azimuthally-symmetric mass-loading source of the neutral cloud, there is a much denser cloud of neutrals centered on the moon and rotating with it. The latter source is the instantaneous mass-loading from plume of Enceladus, and it leads to asymmetry and dynamics in the magnetosphere. We investigate all available Cassini Enceladus flyby data to obtain a 3D spatial profile of the ICW power near the moon. By comparing with waves at longitudes far away from the moon, we investigate how significant is the plume mass-loading with respect to the neutral cloud mass-loading. We also compare the waves along several groups of identical trajectories to examine the temporal variability of the plume.

  18. CHANGES IN HEART RATE VARIABILITY AND LUNG FUNCTION OBSERVED IN NC PATROL TROOPERS EXPOSED TO PM AND AIR TOXICS

    EPA Science Inventory

    Changes in Heart Rate Variability and Lung Function in NC Patrol Troopers exposed to PM and Air Toxics

    Michael Riediker1, Wayne E Cascio1, Robert B Devlin2, Thomas Griggs1&4, Margaret Herbst1, Ronald W Williams3, Steve P McCorquodale4, Philip A Bromberg1
    1) University o...

  19. Influence of travel speed on spray deposition uniformity from an air-assisted variable-rate sprayer

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A newly developed LiDAR-guided air-assisted variable-rate sprayer for nursery and orchard applications was tested at various travel speeds to compare its spray deposition and coverage uniformity with constant-rate applications. Spray samplers, including nylon screens and water-sensitive papers (WSP)...

  20. Development of a Variable-Speed Residential Air-Source Integrated Heat Pump

    SciTech Connect

    Rice, C Keith; Shen, Bo; Munk, Jeffrey D; Ally, Moonis Raza; Baxter, Van D

    2014-01-01

    A residential air-source integrated heat pump (AS-IHP) is under development in partnership with a U.S. manufacturer. A nominal 10.6 kW (3-ton) cooling capacity variable-speed unit, the system provides both space conditioning and water heating. This multi-functional unit can provide domestic water heating (DWH) in either full condensing (FC) (dedicated water heating or simultaneous space cooling and water heating) or desuperheating (DS) operation modes. Laboratory test data were used to calibrate a vapor-compression simulation model for each mode of operation. The model was used to optimize the internal control options for efficiency while maintaining acceptable comfort conditions and refrigerant-side pressures and temperatures within allowable operating envelopes. Annual simulations were performed with the AS-IHP installed in a well-insulated house in five U.S. climate zones. The AS-IHP is predicted to use 45 to 60% less energy than a DOE minimum efficiency baseline system while meeting total annual space conditioning and water heating loads. Water heating energy use is lowered by 60 to 75% in cold to warmer climates, respectively. Plans are to field test the unit in Knoxville, TN.

  1. Long-period humidity variability in the Arctic atmosphere from upper-air observations

    NASA Astrophysics Data System (ADS)

    Agurenko, A.; Khokhlova, A.

    2014-12-01

    Under climate change, atmospheric water content also tends to change. This gives rise to changes in the amount of moisture transferred, clouds and precipitation, as well as in hydrological regime. This work analyzes seasonal climatic characteristics of precipitated water in the Arctic atmosphere, by using 1972-2011 data from 55 upper-air stations located north of 60°N. Regions of maximum and minimum mean values and variability trends are determined. In the summer, water amount is shown to increase in nearly the whole of the latitudinal zone. The comparison with the similar characteristics of reanalysis obtained by the other authors shows a good agreement. Time variation in the atmosphere moisture transport crossing 70°N, which is calculated from observation data, is presented and compared with model results. The work is supported by the joint EC ERA.Net RUS and Russian Fundamental Research Fund Project "Arctic Climate Processes Linked Through the Circulation of the Atmosphere" (ACPCA) (project 12-05-91656-ЭРА_а).

  2. Decadal slowdown in global air temperature rise triggered by variability in the Atlantic Meridional Overturning Circulation

    NASA Astrophysics Data System (ADS)

    England, Matthew H.

    2015-04-01

    Various explanations have been proposed for the recent slowdown in global surface air temperature (SAT) rise, either involving enhanced ocean heat uptake or reduced radiation reaching Earth's surface. Among the mechanisms postulated involving enhanced ocean heat uptake, past work has argued for both a Pacific and Atlantic origin, with additional contributions from the Southern Ocean. Here we examine the mechanisms driving 'hiatus' periods originating out of the Atlantic Ocean. We show that while Atlantic-driven hiatuses are entirely plausible and consistent with known climate feedbacks associated with variability in the Atlantic Meridional Overturning Circulation (AMOC), the present climate state is configured to enhance global-average SAT, not reduce it. We show that Atlantic hiatuses are instead characterised by anomalously cool fresh oceanic conditions in the North Atlantic, with the atmosphere advecting the cool temperature signature zonally. Compared to the 1980s and 1990s, however, the mean climate since 2001 has been characterised by a warm saline North Atlantic, suggesting the AMOC cannot be implicated as a direct driver of the current hiatus. We further discuss the impacts of a warm tropical Atlantic on the unprecedented trade wind acceleration in the Pacific Ocean, and propose that this is the main way that the Atlantic has contributed to the present "false pause" in global warming.

  3. THE PHYSICS OF ELEMENTARY PARTICLES AND FIELDS: Conservation Laws for Partially Conservative Variable Mass Systems via d'Alembert's Principle

    NASA Astrophysics Data System (ADS)

    Aftab, Ahmed; Naseer, Ahmed; Qudrat, Khan

    2008-09-01

    Conservation laws for partially conservative variable mass dynamical systems under symmetric infinitesimal transformations are determined. A generalization of Lagrange-d'Alembert's principle for a variable mass system in terms of asynchronous virtual variation is presented. The generalized Killing equations are obtained such that their solution yields the transformations and the associated conservation laws. An example illustrative of the theory is furnished at the end as well.

  4. Characteristics of dimethylsulfide, ozone, aerosols, and cloud condensation nuclei in air masses over the northwestern Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Nagao, Ippei; Matsumoto, Kiyoshi; Tanaka, Hiroshi

    1999-05-01

    Long-term measurements of several trace gases and aerosols were carried out from December 1994 to October 1996 at Ogasawara Hahajima Island over the northwestern Pacific Ocean. The continental impact on the concentrations of sulfur compounds, ozone (O3), and cloud condensation nuclei (CCN) was estimated on the basis of the classification of air mass into seven types by isentropic trajectory analysis. From May to October, the air mass originating from the central North Pacific Ocean is predominant and regarded as the clean marine air for the concentrations of sulfur compounds and CCN. From the results of the molar ratio of methane sulfonic acid to non-sea-salt sulfate (NSS) and the positive correlation between dimethylsulfide (DMS) and CCN in this air mass it can be concluded that DMS largely contributes to the production of NSS and CCN. On the other hand, continental and anthropogenic substances are preferably transported to the northwestern Pacific Ocean by the predominant continental air mass from November to March. The enhancement of concentrations by the outflow from the Asian continent are estimated by a factor of 2.8 for O3, 3.9 for SO2, 3.5 for CCN activated at 0.5% supersaturation (0.5% CCN), 4.7 for 1.0% CCN, and 5.5 for NSS. Moreover, the CCN supersaturation spectra are also affected by the continental substances resulting in factor 2 of enhancement of cloud droplet number concentration. The diurnal variations of DMS and O3 for each air mass show a pattern of daytime minimum and nighttime maximum, which are typically found in remote ocean, even though those amplitudes are different for each air mass. Consequently, it can be concluded that the influence of nitric oxides (NOx) for the daytime O3 production and nitrate (NO3) radical for the nighttime oxidation of DMS are small even in the continental air mass.

  5. The Barents Sea polar front and water masses variability (1980-2011)

    NASA Astrophysics Data System (ADS)

    Oziel, L.; Sirven, J.; Gascard, J.-C.

    2015-03-01

    The polar front separates the warm and saline Atlantic Waters encountered in the western part of the Barents Sea from the cold and fresh Arctic Waters situated in the northern part. These water masses can mix together, mainly in the eastern part of the Barents Sea, generating dense waters in winter which can cascade into the Arctic Ocean to form the Artic Intermediate Waters. To study the interannual variability and evolution of these water masses and the fronts, we have merged data from the International Council for the Exploration of the Sea and the Arctic and Antarctic Research Institute and have built a new database which covers the period 1980-2011. The summer data is interpolated on a regular grid and a "Probability Density Function" method is used to show that the polar front splits into two branches east of 32° E where the topographic constraint weakens. Two fronts can then be defined: the "Northern Polar Front" is associated with strong salinity gradients and the "Southern Polar Front" with temperature gradients. They enclose the dense Barents Sea Water. The interannual variability of the water masses is apparent in the observed data and is linked to that of the ice cover. In contrast, the link with the Arctic Oscillation is not clear. However, results from a general circulation model suggest that such a link could be found if winter data were taken into account. A strong trend, which amplifies during the last decade, is also found: the Atlantic Water occupies a larger volume of the Barents Sea. This "Atlantification" could be accompanied by a northwards displacement of the southern polar front in the eastern part of the Barents Sea (which is suggested by a model based study) and a decrease of the volume occupied by the Arctic Waters.

  6. Long Period Variables in the LMC: Results from MACHO and 2Mass

    SciTech Connect

    Fraser, O J; Cook, K H; Keller, S C; Hawley, S L

    2004-07-19

    We use the eight year light curve database from the MACHO (MAssive Compact Halo Objects) project together with infrared colors and magnitudes from 2MASS (the Two Micron All Sky Survey) to identify a sample of 22,000 long period variables in the Large Magellanic Cloud (referred to hereafter as LMC LPVs). A period luminosity diagram of these stars reveals six well defined sequences, in substantial agreement with previous analyses of samples from OGLE (Optical Gravitational Lensing Experiment). In our analysis we identify analogues to galactic LPVs in the LMC LPV sample. We find that carbon dominated AGB stars populate only two of the sequences, one of which includes the Mira variables. The high luminosity end of the same two sequences are also the location of the only stars with J K{sub s} > 2, indicating that they are enshrouded in dust. The unknown mechanism that produces the variability of the last sequence--those stars with long secondary periods--produces different morphology in the period luminosity diagram than what is seen in the first four sequences, which are thought to be caused by pulsation. In particular, the last sequence extends to lower luminosity RGB stars and the luminosity function does not peak among the AGB stars. We point out several features which will constrain new models of the period luminosity sequences.

  7. Multi-variable mathematical models for the air-cathode microbial fuel cell system

    NASA Astrophysics Data System (ADS)

    Ou, Shiqi; Kashima, Hiroyuki; Aaron, Douglas S.; Regan, John M.; Mench, Matthew M.

    2016-05-01

    This research adopted the version control system into the model construction for the single chamber air-cathode microbial fuel cell (MFC) system, to understand the interrelation of biological, chemical, and electrochemical reactions. The anodic steady state model was used to consider the chemical species diffusion and electric migration influence to the MFC performance. In the cathodic steady state model, the mass transport and reactions in a multi-layer, abiotic cathode and multi-bacteria cathode biofilm were simulated. Transport of hydroxide was assumed for cathodic pH change. This assumption is an alternative to the typical notion of proton consumption during oxygen reduction to explain elevated cathode pH. The cathodic steady state model provided the power density and polarization curve performance results that can be compared to an experimental MFC system. Another aspect considered was the relative contributions of platinum catalyst and microbes on the cathode to the oxygen reduction reaction (ORR). Simulation results showed that the biocatalyst in a cathode that includes a Pt/C catalyst likely plays a minor role in ORR, contributing up to 8% of the total power calculated by the models.

  8. Multi-variable mathematical models for the air-cathode microbial fuel cell system

    DOE PAGES

    Ou, Shiqi; Kashima, Hiroyuki; Aaron, Douglas S.; Regan, John M.; Mench, Matthew M.

    2016-03-10

    This research adopted the version control system into the model construction for the single chamber air-cathode microbial fuel cell (MFC) system, to understand the interrelation of biological, chemical, and electrochemical reactions. The anodic steady state model was used to consider the chemical species diffusion and electric migration influence to the MFC performance. In the cathodic steady state model, the mass transport and reactions in a multi-layer, abiotic cathode and multi-bacteria cathode biofilm were simulated. Transport of hydroxide was assumed for cathodic pH change. This assumption is an alternative to the typical notion of proton consumption during oxygen reduction to explainmore » elevated cathode pH. The cathodic steady state model provided the power density and polarization curve performance results that can be compared to an experimental MFC system. Another aspect we considered was the relative contributions of platinum catalyst and microbes on the cathode to the oxygen reduction reaction (ORR). We found simulation results showed that the biocatalyst in a cathode that includes a Pt/C catalyst likely plays a minor role in ORR, contributing up to 8% of the total power calculated by the models.« less

  9. Seasonal and inter-annual variability of lower stratospheric age of air spectra

    NASA Astrophysics Data System (ADS)

    Ploeger, Felix; Birner, Thomas

    2016-08-01

    Trace gas transport in the lower stratosphere is investigated by analysing seasonal and inter-annual variations of the age of air spectrum - the probability distribution of stratospheric transit times. Age spectra are obtained using the Chemical Lagrangian Model of the Stratosphere (CLaMS) driven by ERA-Interim winds and total diabatic heating rates, and using a time-evolving boundary-impulse-response (BIER) method based on multiple tracer pulses. Seasonal age spectra show large deviations from an idealized stationary uni-modal shape. Multiple modes emerge in the spectrum throughout the stratosphere, strongest at high latitudes, caused by the interplay of seasonally varying tropical upward mass flux, stratospheric transport barriers and recirculation. Inter-annual variations in transport (e.g. quasi-biennial oscillation) cause significant modulations of the age spectrum shape. In fact, one particular QBO phase may determine the spectrum's mode during the following 2-3 years. Interpretation of the age spectrum in terms of transport contributions due to the residual circulation and mixing is generally not straightforward. It turns out that advection by the residual circulation represents the dominant pathway in the deep tropics and in the winter hemisphere extratropics above 500 K, controlling the modal age in these regions. In contrast, in the summer hemisphere, particularly in the lowermost stratosphere, mixing represents the most probable pathway controlling the modal age.

  10. Spatial and temporal variability in distribution of water masses in Hornsund, Spitsbergen

    NASA Astrophysics Data System (ADS)

    Promińska, Agnieszka; Falck, Eva; Walczowski, Waldemar; Sundfjord, Arild

    2016-04-01

    Arctic fjords constitute an important part of many recent investigations because this is the place where different water masses meet, mix, and transform, influencing the stability of glaciers. Hornsund, the southernmost fjord of West Spitsbergen, has been studied during the past 15 years. Observations were based primarily on high resolution measurements of water temperature and salinity along fixed sections, that have been performed every July between 2001-2015. Research carried out in years 2010 - 2015 under Polish - Norwegian projects AWAKE and AWAKE-2 allowed for expansion of the database with data covering the period from spring to autumn. During this time measurements were also conducted from a small boat in the vicinity of glaciers with a time resolution of 1-2 weeks in addition to a mooring system deployed in the fjord and on the shelf just outside Hornsund. Synthesis of our measurements give an overview of water masses observed in the fjord. From summer to summer observations reveal high variability in water temperature and salinity giving a distinct division into an area influenced by oceanic factors (Main Basin) and an area which is more influenced by local factors (Brepollen). The chronology of water mass transformation has been obtained indicating a time of transition between winter (Arctic type), additionally interrupted by temporary inflow of waters of Atlantic origin, and summer (Atlantic type) conditions.

  11. Solitary fibrous tumor of the pleura manifesting as an air-containing cystic mass: radiologic and histopathologic correlation.

    PubMed

    Baek, Ji Eun; Ahn, Myeong Im; Lee, Kyo Young

    2013-01-01

    Solitary fibrous tumor (SFT) is a rare mesenchymal neoplasm that typically presents as a well-defined lobular soft tissue mass commonly arising from the pleura. We report an extremely rare case of an SFT containing air arising from the right major fissure in a 58-year-old woman. Chest CT showed an ovoid air-containing cystic mass with an internal, homogeneously enhancing solid nodule. To our knowledge, this is the first case in the literature. The histopathologic findings were correlated with the radiologic findings, and the mechanism of air retention within the tumor is discussed.

  12. Mixture model-based atmospheric air mass classification: a probabilistic view of thermodynamic profiles

    NASA Astrophysics Data System (ADS)

    Pernin, Jérôme; Vrac, Mathieu; Crevoisier, Cyril; Chédin, Alain

    2016-10-01

    Air mass classification has become an important area in synoptic climatology, simplifying the complexity of the atmosphere by dividing the atmosphere into discrete similar thermodynamic patterns. However, the constant growth of atmospheric databases in both size and complexity implies the need to develop new adaptive classifications. Here, we propose a robust unsupervised and supervised classification methodology of a large thermodynamic dataset, on a global scale and over several years, into discrete air mass groups homogeneous in both temperature and humidity that also provides underlying probability laws. Temperature and humidity at different pressure levels are aggregated into a set of cumulative distribution function (CDF) values instead of classical ones. The method is based on a Gaussian mixture model and uses the expectation-maximization (EM) algorithm to estimate the parameters of the mixture. Spatially gridded thermodynamic profiles come from ECMWF reanalyses spanning the period 2000-2009. Different aspects are investigated, such as the sensitivity of the classification process to both temporal and spatial samplings of the training dataset. Comparisons of the classifications made either by the EM algorithm or by the widely used k-means algorithm show that the former can be viewed as a generalization of the latter. Moreover, the EM algorithm delivers, for each observation, the probabilities of belonging to each class, as well as the associated uncertainty. Finally, a decision tree is proposed as a tool for interpreting the different classes, highlighting the relative importance of temperature and humidity in the classification process.

  13. Variation in particulate PAHs levels and their relation with the transboundary movement of the air masses.

    PubMed

    Ravindra, Khaiwal; Wauters, Eric; Van Grieken, René

    2008-06-25

    The levels of particulate polycyclic aromatic hydrocarbons (PAHs) were determined with a fast analytical approach to study their seasonal variations at Menen (Belgium) during 2003; they were found to be 5-7 times higher in January, February and December, in comparison to May, June and August. The annual average concentration of the sum of 16 US Environmental Protection Agency (EPA) criteria PAHs was 6.7 ng/m3 and around 63% of it was found to be probably carcinogenic to humans. The application of diagnostic ratio and principal component analysis showed vehicular emission as a major source. An increased ratio of 'combustion PAHs' to 'total EPA-PAHs' during the winter season indicated towards combustion activities. Further, the differences in PAHs concentration were assessed with relation to backward air mass trajectories, which show that the levels of PAHs increase when there is an air mass movement from Central and Western Europe and a fall when the trajectories spend most of their 4-day time over the Atlantic Ocean or in the Arctic region.

  14. Precipitation chemistry and corresponding transport patterns of influencing air masses at Huangshan Mountain in East China

    NASA Astrophysics Data System (ADS)

    Shi, ChunE; Deng, Xueliang; Yang, Yuanjian; Huang, Xiangrong; Wu, Biwen

    2014-09-01

    One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean (VWM) pH for the whole sampling period was 5.03. SO{4/2-} and Ca2+ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO{4/2-}]/[NO{3/-}] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.

  15. Impact of maritime air mass trajectories on the Western European coast urban aerosol.

    PubMed

    Almeida, S M; Silva, A I; Freitas, M C; Dzung, H M; Caseiro, A; Pio, C A

    2013-01-01

    Lisbon is the largest urban area in the Western European coast. Due to this geographical position the Atlantic Ocean serves as an important source of particles and plays an important role in many atmospheric processes. The main objectives of this study were to (1) perform a chemical characterization of particulate matter (PM2.5) sampled in Lisbon, (2) identify the main sources of particles, (3) determine PM contribution to this urban area, and (4) assess the impact of maritime air mass trajectories on concentration and composition of respirable PM sampled in Lisbon. During 2007, PM2.5 was collected on a daily basis in the center of Lisbon with a Partisol sampler. The exposed Teflon filters were measured by gravimetry and cut into two parts: one for analysis by instrumental neutron activation analysis (INAA) and the other by ion chromatography (IC). Principal component analysis (PCA) and multilinear regression analysis (MLRA) were used to identify possible sources of PM2.5 and determine mass contribution. Five main groups of sources were identified: secondary aerosols, traffic, calcium, soil, and sea. Four-day backtracking trajectories ending in Lisbon at the starting sampling time were calculated using the HYSPLIT model. Results showed that maritime transport scenarios were frequent. These episodes were characterized by a significant decrease of anthropogenic aerosol concentrations and exerted a significant role on air quality in this urban area.

  16. Factors influencing variability in the infiltration of PM2.5 mass and its components

    NASA Astrophysics Data System (ADS)

    MacNeill, M.; Wallace, L.; Kearney, J.; Allen, R. W.; Van Ryswyk, K.; Judek, S.; Xu, X.; Wheeler, A.

    2012-12-01

    The infiltration of particles into homes can vary seasonally, between homes in a community and between communities. However, few studies have examined the day to day variability across multiple homes. We used continuous data collected from a 2-year (2005-2006) personal exposure study conducted in Windsor, ON to estimate daily infiltration factors (Finf) for fine particulate matter (PM2.5), Black Carbon (BC), and ultrafine particles (UFP) as well as the ambient personal exposure factor (Fpex) for PM2.5. In addition, the daily ambient and non-ambient generated components of indoor and personal concentrations were estimated. Median daily Finf estimates ranged from 0.26 to 0.36 across seasons for PM2.5; from 0.28 to 0.59 for BC; and from 0.15 to 0.26 for UFP. Median daily Fpex estimates ranged from 0.24 to 0.31 across seasons. Daily PM2.5 and UFP Finf and Fpex estimates were higher in summer than winter, although BC showed the opposite trend. Predictors of daily infiltration were typically related to window-opening behaviours, air conditioning, meteorological variables, and home age. In addition, use of electrostatic precipitators and stand alone air cleaners was associated with significantly reduced infiltration factors, indicating that these devices may provide a cost effective mechanism of reducing human exposures to particles of ambient origin. The majority of indoor PM2.5 (median 57-73%) and indoor BC (median 90-100%) was of ambient origin across seasons, while both personal PM2.5 and indoor UFPs had significant non-ambient contributions (median 60-65%). Factors that were found to increase non-ambient particle concentrations were typically related to cooking, candle use, supplemental heating, cleaning, and number of people in the home. Factors that were found to decrease non-ambient particle concentrations were open windows, and air cleaner use. This work has several implications to both epidemiologic studies and risk management. A better understanding of the

  17. EXAMINING THE IMPACT OF CLIMATE CHANGE AND VARIABILITY OF REGIONAL AIR QUALITY OVER THE UNITED STATES

    EPA Science Inventory

    The United States has established a series of standards for criteria and other air pollutants to safeguard air quality to protect human health and the environment. The Climate Impact on Regional Air Quality (CIRAQ) project, a collaborative research effort involving multiple Fede...

  18. Methodological issues related to pooling results from panel studies of heart rate variability and its association with ambient air pollution.

    PubMed

    Buteau, Stephane; Goldberg, Mark S

    2015-07-01

    Reviews of observational studies and subsequent meta-analyses are challenging to interpret because of potential methodological issues and biases inherent in studies. In reviewing panel studies of the association between heart rate variability and ambient air pollution we identified a number of methodological issues that make difficult interpreting and pooling findings from longitudinal studies, notably issues related to associations arising from different type of designs, differences in design characteristics, including study populations, measurements of heart rate variability (e.g., duration and condition of the electrocardiogram recordings), exposure assessment (e.g., types of monitoring), metrics of exposure used, and parameters estimated from regression models. We conclude that many panel studies of the association between heart rate variability and ambient air pollution may not be comparable to each other, and thus caution must be exercised to avoid misleading conclusions.

  19. [Analysis of polycyclic aromatic hydrocarbons in air samples by gas chromatography-triple quadrupole mass spectrometry].

    PubMed

    Zhao, Bo; Li, Yuqing; Zhang, Sukun; Han, Jinglei; Xu, Zhencheng; Fang, Jiande

    2014-09-01

    A method of gas chromatography coupled to triple quadrupole tandem mass spectrometry (GC-MS/MS) has been optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in air samples. In the analysis step, isotope dilution was introduced to the quantification of PAHs. The GC-MS/MS method was applied to the analysis of the real air samples around a big petrochemical power plant in South China. The results were compared with those obtained by gas chromatography coupled to mass spectrometry (GC-MS). The results showed that better selectivity and sensitivity were obtained by GC-MS/MS. It was found that the external standard of deuterated-PAHs and internal standard of hexamethyl benzene were disturbed seriously with GC-MS, and the problems were both solved effectively by GC-MS/MS. Therefore more accurate quantification results of PAHs were obtained with GC-MS/MS. For the analysis of real samples, the RSDs of relative response factors ranged from 2.60% to 15.6% in standard curves; the recoveries of deuterated-PAHs ranged from 55.2% to 82.3%; the recoveries of spiked samples ranged from 98.9% to 111%; the RSDs of parallel specimens ranged from 6.50% to 18.4%; the concentrations of field blank samples ranged from not detected to 44.3 pg/m3; and the concentrations of library blank samples ranged from not detected to 36.5 pg/m3. The study indicated that the application of GC-MS/MS on the analysis of PAHs in air samples was recommended. PMID:25752088

  20. Air mass distribution and the heterogeneity of the climate change signal in the Hudson Bay/Foxe Basin region, Canada

    NASA Astrophysics Data System (ADS)

    Leung, Andrew; Gough, William

    2016-08-01

    The linkage between changes in air mass distribution and temperature trends from 1971 to 2010 is explored in the Hudson Bay/Foxe Basin region. Statistically significant temperature increases were found of varying spatial and temporal magnitude. Concurrent statistically significant changes in air mass frequency at the same locations were also detected, particularly in the declining frequency of dry polar (DP) air. These two sets of changes were found to be linked, and we thus conclude that the heterogeneity of the climatic warming signal in the region is at least partially the result of a fundamental shift in the concurrent air mass frequency in addition to global and regional changes in radiative forcing due to increases in long-lived greenhouse gases.

  1. Long-term optical variability of high-mass X-ray binaries. II. Spectroscopy

    NASA Astrophysics Data System (ADS)

    Reig, P.; Nersesian, A.; Zezas, A.; Gkouvelis, L.; Coe, M. J.

    2016-05-01

    Context. High-mass X-ray binaries are bright X-ray sources. The high-energy emission is caused by the accretion of matter from the massive companion onto a neutron star. The accreting material comes from either the strong stellar wind in binaries with supergiant companions or the cirscumstellar disk in Be/X-ray binaries. In either case, the Hα line stands out as the main source of information about the state of the accreting material. Aims: We present the results of our monitoring program to study the long-term variability of the Hα line in high-mass X-ray binaries. Our aim is to characterise the optical variability timescales and study the interaction between the neutron star and the accreting material. Methods: We fitted the Hα line with Gaussian profiles and obtained the line parameters and equivalent width. The peak separation in split profiles was used to determine the disk velocity law and estimate the disk radius. The relative intensity of the two peaks (V/R ratio) allowed us to investigate the distribution of gas particles in the disk. The equivalent width was used to characterise the degree of variability of the systems. We also studied the variability of the Hα line in correlation with the X-ray activity. Results: Our results can be summarised as follows: i) we find that Be/X-ray binaries with narrow orbits are more variable than systems with long orbital periods; ii) we show that a Keplerian distribution of gas particles provides a good description of the disks in Be/X-ray binaries, as it does in classical Be stars; iii) a decrease in the Hα equivalent width is generally observed after major X-ray outbursts; iv) we confirm that the Hα equivalent width correlates with disk radius; v) while systems with supergiant companions display multi-structured profiles, most of the Be/X-ray binaries show, at some epoch, double-peak asymmetric profiles, which indicates that density inhomogeneities is a common property in the disk of Be/X-ray binaries; vi) the

  2. Variability in Intermediate Water Mass Geometry in the Tropical W-Atlantic from LGM to Holocene

    NASA Astrophysics Data System (ADS)

    Poggemann, D. W.; Nuernberg, D.; Hathorne, E. C.; Bruhn, I.; Reißig, S.; Frank, M.

    2014-12-01

    The oceanic intermediate depth response to periods of abrupt climatic cooling during the last deglaciation, namely the Younger Dryas (YD) and Heinrich 1 event (H1), has been the focus of several recent studies (e.g. Pahnke et al., 2008; Huang et al., 2014; Xie et al., 2014; Gebbie et al., 2014). Intermediate water dynamics, in particular the interaction between Antarctic Intermediate Water (AAIW) and North Atlantic Deepwater (NADW) during the transition from the Last Glacial Maximum (LGM) to the Holocene and the connection with Atlantic Meridional Overturning Circulation (AMOC), however, are still debated widely. Several hypotheses suggest the short-term presence of AAIW in the subtropical Atlantic or N-Atlantic sourced intermediate water masses in the Florida Straits during deglacial cool periods when the AMOC was supposedly weak or collapsed (e.g. Xie et al., 2012). This study provides new water mass geometry information from the tropical W-Atlantic for the past 35 ka using a multiproxy approach. We analysed calcitic tests of benthic/planktonic foraminifera from various intermediate depth locations for Mg/Ca (temperature), Cdw (nutrients), δ18Osw (salinity), δ13C (ventilation), and ɛNd (water mass provenance and mixing) in order to improve our understanding of the intermediate water mass distribution and variability between 400 and 1500 m water depth on millennial time-scales. First results document the southward penetration of Glacial North Atlantic Intermediate Water (GNAIW) replacing the NADW during the LGM. Furthermore our data indicate a gradual shift from GNAIW influenced conditions during the LGM to AAIW dominated conditions throughout the Holocene.

  3. Variability of Mass Dependence of Auroral Acceleration Processes with Solar Activity

    NASA Technical Reports Server (NTRS)

    Ghielmetti, Arthur G.

    1997-01-01

    The objectives of this investigation are to improve understanding of the mass dependent variability of the auroral acceleration processes and so to clarify apparent discrepancies regarding the altitude and local time variations with solar cycle by investigating: (1) the global morphological relationships between auroral electric field structures and the related particle signatures under varying conditions of solar activity, and (2) the relationships between the electric field structures and particle signatures in selected events that are representative of the different conditions occurring during a solar cycle. The investigation is based in part on the Lockheed UFI data base of UpFlowing Ion (UFI) events in the 5OO eV to 16keV energy range and associated electrons in the energy range 7O eV to 24 keV. This data base was constructed from data acquired by the ion mass spectrometer on the S3-3 satellite in the altitude range of I to 1.3 Re. The launch of the POLAR spacecraft in early 1996 and successful operation of its TIMAS ion mass spectrometer has provided us with data from within the auroral acceleration regions during the current solar minimum. The perigee of POLAR is at about 1 Re, comparable to that of S3-3. The higher sensitivity and time resolution of TIMAS compared to the ion mass spectrometer on S3-3 together with its wider energy range, 15 eV to 33 keV, facilitate more detailed studies of upflowing ions.

  4. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins.

  5. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins. PMID:26930305

  6. Impacts of Atmospheric Modes of Variability on Air-Sea Heat Exchange in the Red Sea

    NASA Astrophysics Data System (ADS)

    Abualnaja, Yasser O.; Papadopoulos, Vassilis P.; Josey, Simon A.; Hoteit, Ibrahim; Kontoyiannis, Harilaos; Raitsos, Dionissios E.

    2014-05-01

    The potential impacts on Red Sea surface heat exchange of various major modes of atmospheric variability are investigated using the NASA Modern Era Retrospective Analysis for Research and Applications (MERRA) atmospheric reanalysis and the Objectively Analyzed Air-Sea Flux dataset (OAFlux) merged satellite+reanalysis dataset. The mode impacts on surface net heat flux are quantified by calculating the heat flux anomaly that corresponds to a unit positive value of each index for each grid point. The seasonal effects of the atmospheric forcing are investigated considering two and four typical seasons of a calendar year. Considering two seasons, the impacts are strongest during the winter-centered part of the year (October to March) mainly over the northern sub-basin. The North Atlantic Oscillation (NAO), the East Atlantic - West Russia Pattern (EAWR), and the Indian Monsoon Index (IMI) have the greatest effects. They generate negative anomalies (by definition additional ocean heat loss) of 7-12 W/m2 in the northern Red Sea basin mean net heat flux for a unit positive value of the mode index. During the summer (April to September), the signal is smaller and the East Atlantic (EA) and Multivariate ENSO Index (MEI) modes have the strongest impact which is now located in the southern Red Sea (sub-basin anomalies of 4 W/m2 for unit positive mode index, negative for EA and positive for MEI). Results obtained by analysis carried out on the traditional four-season basis reveal that indices impact peaks during the typical boreal winter (DJF) with average anomalies of 12-18 W/m2 to be found in the northern part. It is noteworthy that during the winter, the EAWR generates negative anomalies around 30 W/m2 over the most of the central Red Sea. During the spring (MAM), summer (JJA) and autumn (SON) the anomalies are considerably lower, especially during the spring when the mode impacts are negligible. Atmospheric modes have a stronger effect on air-sea heat flux over the northern

  7. Quantification of methane in humid air and exhaled breath using selected ion flow tube mass spectrometry.

    PubMed

    Dryahina, Kseniya; Smith, D; Spanel, P

    2010-05-15

    In selected ion flow tube mass spectrometry, SIFT-MS, analyses of humid air and breath, it is essential to consider and account for the influence of water vapour in the media, which can be profound for the analysis of some compounds, including H(2)CO, H(2)S and notably CO(2). To date, the analysis of methane has not been considered, since it is known to be unreactive with H(3)O(+) and NO(+), the most important precursor ions for SIFT-MS analyses, and it reacts only slowly with the other available precursor ion, O(2) (+). However, we have now experimentally investigated methane analysis and report that it can be quantified in both air and exhaled breath by exploiting the slow O(2) (+)/CH(4) reaction that produces CH(3)O(2) (+) ions. We show that the ion chemistry is significantly influenced by the presence of water vapour in the sample, which must be quantified if accurate analyses are to be performed. Thus, we have carried out a study of the loss rate of the CH(3)O(2) (+) analytical ion as a function of sample humidity and deduced an appropriate kinetics library entry that provides an accurate analysis of methane in air and breath by SIFT-MS. However, the associated limit of detection is rather high, at 0.2 parts-per-million, ppm. We then measured the methane levels, together with acetone levels, in the exhaled breath of 75 volunteers, all within a period of 3 h, which shows the remarkable sample throughput rate possible with SIFT-MS. The mean methane level in ambient air is seen to be 2 ppm with little spread and that in exhaled breath is 6 ppm, ranging from near-ambient levels to 30 ppm, with no significant variation with age and gender. Methane can now be included in the wide ranging analyses of exhaled breath that are currently being carried out using SIFT-MS.

  8. Aerosols in Polluted versus Nonpolluted Air Masses: Long-Range Transport and Effects on Clouds.

    NASA Astrophysics Data System (ADS)

    Pueschel, R. F.; van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-12-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United State, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, New York, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types-background continental, polluted continental, and maritime-that were advected to the sampling site. The results are the following (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds to thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (ii) A significant fraction of anthropogenic sulfur aerosols appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (iii) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (iv) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  9. Finite element analysis of an inflatable torus considering air mass structural element

    NASA Astrophysics Data System (ADS)

    Gajbhiye, S. C.; Upadhyay, S. H.; Harsha, S. P.

    2014-01-01

    Inflatable structures, also known as gossamer structures, are at high boom in the current space technology due to their low mass and compact size comparing to the traditional spacecraft designing. Internal pressure becomes the major source of strength and rigidity, essentially stiffen the structure. However, inflatable space based membrane structure are at high risk to the vibration disturbance due to their low structural stiffness and material damping. Hence, the vibration modes of the structure should be known to a high degree of accuracy in order to provide better control authority. In the past, most of the studies conducted on the vibration analysis of gossamer structures used inaccurate or approximate theories in modeling the internal pressure. The toroidal shaped structure is one of the important key element in space application, helps to support the reflector in space application. This paper discusses the finite-element analysis of an inflated torus. The eigen-frequencies are obtained via three-dimensional small-strain elasticity theory, based on extremum energy principle. The two finite-element model (model-1 and model-2) have cases have been generated using a commercial finite-element package. The structure model-1 with shell element and model-2 with the combination of the mass of enclosed fluid (air) added to the shell elements have been taken for the study. The model-1 is computed with present analytical approach to understand the convergence rate and the accuracy. The convergence study is made available for the symmetric modes and anti-symmetric modes about the centroidal-axis plane, meeting the eigen-frequencies of an inflatable torus with the circular cross section. The structural model-2 is introduced with air mass element and analyzed its eigen-frequency with different aspect ratio and mode shape response using in-plane and out-plane loading condition are studied.

  10. The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

    NASA Technical Reports Server (NTRS)

    Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

    2014-01-01

    The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

  11. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  12. Global Distribution and Variability of Surface Skin and Surface Air Temperatures as Depicted in the AIRS Version-6 Data Set

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Lee, Jae N.; Iredell, Lena

    2014-01-01

    In this presentation, we will briefly describe the significant improvements made in the AIRS Version-6 retrieval algorithm, especially as to how they affect retrieved surface skin and surface air temperatures. The global distribution of seasonal 1:30 AM and 1:30 PM local time 12 year climatologies of Ts,a will be presented for the first time. We will also present the spatial distribution of short term 12 year anomaly trends of Ts,a at 1:30 AM and 1:30 PM, as well as the spatial distribution of temporal correlations of Ts,a with the El Nino Index. It will be shown that there are significant differences between the behavior of 1:30 AM and 1:30 PM Ts,a anomalies in some arid land areas.

  13. Number size distribution of aerosols at Mt. Huang and Nanjing in the Yangtze River Delta, China: Effects of air masses and characteristics of new particle formation

    NASA Astrophysics Data System (ADS)

    Wang, Honglei; Zhu, Bin; Shen, Lijuan; An, Junlin; Yin, Yan; Kang, Hanqing

    2014-12-01

    Aerosol number spectra in the range of 10 nm-10 μm were observed at Mt. Huang (Aug. 15-Sep. 15) and Nanjing (Oct. 13-Nov. 15) by a wide-range particle spectrometer (WPS) in 2011. Based on the backward trajectories obtained using the HYSPLIT model, the transport pathways of observed air masses during the study periods were classified into the following four groups: maritime air mass, continental air mass, marine-continental mixed air mass and local air mass. The variations in the aerosol number spectrum and the new particle formation (NPF) events for various types of air masses were discussed, along with meteorological data. The results showed that the average number concentration was 12,540 cm- 3 at Nanjing and only 2791 cm- 3 at Mt. Huang. The aerosol number concentration in Nanjing was 3-7 times higher than that in Mt. Huang; the large discrepancy was in the range of 10-100 nm. Different types of air masses had different effects on number concentration distribution. The number concentration of aerosols was higher in marine air masses, continental air masses and continental-marine mixed air masses at 10-50 nm, 100-500 nm and 50-200 nm, respectively. Under the four types of air masses, the aerosol size spectra had bimodal distributions in Nanjing and unimodal distributions in Mt. Huang (except under continental air masses: HT1). The effects of the diverse air masses on aerosol size segments of the concentration peak in Mt. Huang were stronger than those in Nanjing. The local air masses were dominant at these two sites and accounted for 44% of the total air masses. However, the aerosol number concentration was the lowest in Mt. Huang and the highest in Nanjing when local air masses were present. The number concentrations for foreign air masses increased at Mt. Huang and decreased at Nanjing. Different types of air masses had greater effects on the aerosol spectrum distribution at Mt. Huang than at Nanjing. During the NPF events, the particle growth rates at Mt

  14. Measurement and analysis of aerosol and black carbon in the southwestern United States and Panama and their dependence on air mass origin

    NASA Astrophysics Data System (ADS)

    Junker, C.; Sheahan, J. N.; Jennings, S. G.; O'Brien, P.; Hinds, B. D.; Martinez-Twary, E.; Hansen, A. D. A.; White, C.; Garvey, D. M.; Pinnick, R. G.

    2004-07-01

    Total aerosol mass loading, aerosol absorption, and black carbon (BC) content were determined from aerosol collected on 598 quartz fiber filters at a remote, semiarid site near Orogrande, New Mexico from December 1989 to October 1995. Aerosol mass was determined by weighing filters before and after exposure, and aerosol absorption was determined by measuring the visible light transmitted through loaded filter samples and converting these measurements to aerosol absorption. BC content was determined by measuring visible light transmitted through filter samples before and after firing and converting the absorption to BC mass, assuming a BC absorption cross section of 19 m2/g in the fiber filter medium. Two analyses were then performed on each of the logged variables: an autoregressive integrating moving average (ARIMA) analysis and a decomposition analysis using an autoregressive model to accommodate first-order autocorrelation. The two analyses reveal that BC mass has no statistically significant seasonal dependence at the 5% level of significance but only random fluctuations varying around an average annual value that has a long-term decreasing trend (from 0.16 to 0.11 μg/m3 during 1990-1995). Aerosol absorption, which is dominated by BC, also displays random fluctuations about an average value, and decreases from 1.9 Mm-1 to 1.3 Mm-1 during the same period. Unlike BC, aerosol mass at the Orogrande site displays distinctly different character. The analyses reveal a pronounced seasonal dependence, but no long-term trend for aerosol mass. The seasonal indices resulting from the autoregression analysis have a minimum in January (-0.78) and maximum in June (+0.58). The geometric mean value over the 1990-1995 period for aerosol mass is 16.0 μg/m3. Since BC aerosol at the Orogrande site is a product of long-range atmospheric transport, a back trajectory analysis of air masses was conducted. Back trajectory analyses indicate that air masses traversing high population

  15. Interannual salinity variability of the Northern Yellow Sea Cold Water Mass

    NASA Astrophysics Data System (ADS)

    Li, Ang; Yu, Fei; Diao, Xinyuan

    2015-05-01

    This paper discusses the interannual variability of the Northern Yellow Sea Cold Water Mass (NYSCWM) and the factors that influence it, based on survey data from the 1976-2006 national standard section and the Korea Oceanographic Data Center, monthly E-P flux data from the European Centre for Medium-Range Weather Forecasts, and meridional wind speed data from the International Comprehensive Ocean-Atmosphere Data Set. The results show that: 1) the mean salinity of the NYSCWM center has a slightly decreasing trend, which is not consistent with the high salinity center; 2) both the southern salinity front and the halocline of the NYSCWM display a weakening trend, which indicates that the difference between the NYSCWM and coastal water decreases; 3) the Yellow Sea Warm Current intrusion, the E-P flux of the northern Yellow Sea, and the strength of the winter monsoon will affect the NYSCWM salinity during the following summer.

  16. Assesssing Variability of Dusty Galactic and Magellanic WRs and Seeking MIR Mass-Loss Nebulae

    NASA Astrophysics Data System (ADS)

    Cohen, Martin

    Wolf-Rayet (WR) stars are rare high-mass stars with potent winds which disturb and chemically enrich their surroundings, often creating optical nebulae as their ejecta sweep up the local interstellar medium. The intriguing dusty late-type carbon WRs) have generated thick circumstellar shells. Many WCs often have variable dust production, some periodic, others random. Only by studying all these highly energetic stars in depth will we decipher the nature of the dust condensation process and the pathway to grains in these hydrogen-poor atmospheres. This promises an accurate assessment of the quantitative contribution of WRs to the cosmic carbon budget. Such stars are few in number, but play a key role in generating the chemical elements and recycling stellar material. In 2001 we knew 227 Galactic WRs and 99% of the WC9s were dusty. Today we list close to 400 WR including the the WN and WO types. But only 56% of the WC9s are known to be dusty, dominated by those with persistent dust. Those for which we have determined both the existence of dust variability and know its temporal character is still of order 10. Much work remains to characterize the nature and variability of IR emission for many newly discovered WCs which have only optical classifications. Every new IR survey of the Galactic plane has the potential to offer crucial data on dusty WR stars, by finding new examples or providing another epoch of photometry for previously known WCs, to compare with earlier IR data to study the individual mass loss history for each. This is the method by which these variable stars were found to undergo episodes of dust making and it maximizes the value of old data sets, particularly when the effort is made to maintain a consistent absolute calibration for new missions. It is not enough merely to uncover new WCs, nor even to assign spectral classes to them. It is also essential to archive their spectral energy distributions (SEDs) as fiducial references for the future. Spitzer

  17. Social, Economic, and Resource Predictors of Variability in Household Air Pollution from Cookstove Emissions

    PubMed Central

    Yadama, Gautam N.; Peipert, John; Sahu, Manoranjan; Biswas, Pratim; Dyda, Venkat

    2012-01-01

    We examine if social and economic factors, fuelwood availability, market and media access are associated with owning a modified stove and variation in household emissions from biomass combustion, a significant environmental and health concern in rural India. We analyze cross-sectional household socio-economic data, and PM2.5 and particulate surface area concentration in household emissions from cookstoves (n = 100). This data set combines household social and economic variables with particle emissions indexes associated with the household stove. The data are from the Foundation for Ecological Society, India, from a field study of household emissions. In our analysis, we find that less access to ready and free fuelwood and higher wealth are associated with owning a replacement/modified stove. We also find that additional kitchen ventilation is associated with a 12% reduction in particulate emissions concentration (p<0.05), after we account for the type of stove used. We did not find a significant association between replacement/modified stove on household emissions when controlling for additional ventilation. Higher wealth and education are associated with having additional ventilation. Social caste, market and media access did not have any effect on the presence of replacement or modified stoves or additional ventilation. While the data available to us does not allow an examination of direct health outcomes from emissions variations, adverse environmental and health impacts of toxic household emissions are well established elsewhere in the literature. The value of this study is in its further examination of the role of social and economic factors and available fuelwood from commons in type of stove use, and additional ventilation, and their effect on household emissions. These associations are important since the two direct routes to improving household air quality among the poor are stove type and better ventilation. PMID:23056293

  18. The association of particulate air metal concentrations with heart rate variability.

    PubMed Central

    Magari, Shannon R; Schwartz, Joel; Williams, Paige L; Hauser, Russ; Smith, Thomas J; Christiani, David C

    2002-01-01

    Numerous studies show an association between particulate air pollution and adverse health effects. Particulate matter is a complex mixture of elemental carbon, ammonium, sulfates, nitrates, organic components, and metals. The mechanisms of action of particulate matter less than or equal to 2.5 micro m in mean aerodynamic diameter (PM(2.5)), as well as the constituents responsible for the observed cardiopulmonary health effects, have not been identified. In this study we focused on the association between the metallic component of PM(2.5) and cardiac autonomic function based on standard heart rate variability (HRV) measures in an epidemiologic study of boilermakers. Thirty-nine male boilermakers were monitored throughout a work shift. Each subject wore an ambulatory electrocardiogram (Holter) monitor and a personal monitor to measure PM(2.5). We used mixed-effects models to regress heart rate and SDNN index (standard deviation of the normal-to-normal) on PM(2.5) and six metals (vanadium, nickel, chromium, lead, copper, and manganese). There were statistically significant mean increases in the SDNN index of 11.30 msec and 3.98 msec for every 1 micro g/m(3) increase in the lead and vanadium concentrations, respectively, after adjusting for mean heart rate, age, and smoking status. Small changes in mean heart rate were seen with all exposure metrics. The results of this study suggest an association between exposure to airborne metals and significant alterations in cardiac autonomic function. These results extend our understanding of the adverse health effects of the metals component of ambient PM(2.5). PMID:12204821

  19. Intraseasonal variability of air temperature over the mid-high latitude Eurasia in boreal winter

    NASA Astrophysics Data System (ADS)

    Yang, Shuangyan; Li, Tim

    2016-10-01

    The intraseasonal oscillation (ISO) of air temperature over the mid- and high-latitude Eurasia in boreal winter was investigated by NCEP-NCAR reanalysis data. It is found that the intraseasonal temperature disturbances exhibit maximum variability near the surface in the region of 50°-75°N, 80°‒120°E and they propagate southeastwards at average zonal and meridional phase speeds of 3.2 and 2.5 m s-1, respectively. The low-level temperature signal is tightly coupled with upper-tropospheric height anomalies, and both propagate southeastward in a similar phase speed. A diagnosis of the temperature budget reveals that the southeastward propagation is primarily attributed to the advection of the temperature anomaly by the mean wind. A wave activity flux analysis indicates that the southeastward propagating wave train is likely a result of Rossby wave energy propagation. The source of the Rossby wave train appears at the high latitude Europe/Atlantic sector, where maximum wave activity flux convergence resides. During its southeastward journey, the ISO perturbation gains energy from the mean flow through both kinetic and potential energy conversions. A physics-based empirical model was constructed to predict the intraseasonal temperature anomaly over southeast China. The major predictability source is the southeastward-propagating ISO signal. The data for 1979‒2003 were used as a training period to construct the empirical model. A 10-yr (2004‒2013) independent forecast shows that the model attains a useful skill of up to 25 days.

  20. A new approach to the correlation of boundary layer mass transfer rates with thermal diffusion and/or variable properties

    NASA Technical Reports Server (NTRS)

    Srivastava, R.; Rosner, D. E.

    1979-01-01

    A rational approach to the correlation of boundary layer mass transport rates, applicable to many commonly encountered laminar flow conditions with thermal diffusion and/or variable properties, is outlined. The correlation scheme builds upon already available constant property blowing/suction solutions by introducing appropriate correction factors to account for the additional ('pseudo' blowing and source) effects identified with variable properties and thermal diffusion. Applications of the scheme to the particular laminar boundary layer mass transfer problems considered herein (alkali and transition metal compound vapor transport) indicates satisfactory accuracy up to effective blowing factors equivalent to about one third of the 'blow off' value. As a useful by-product of the variable property correlation, we extend the heat-mass transfer analogy, for a wide range of Lewis numbers, to include variable property effects.

  1. Mass spectrometric investigation of molecular variability of grass pollen group 1 allergens.

    PubMed

    Fenaille, François; Nony, Emmanuel; Chabre, Henri; Lautrette, Aurélie; Couret, Marie-Noëlle; Batard, Thierry; Moingeon, Philippe; Ezan, Eric

    2009-08-01

    Natural grass pollen allergens exhibit a wide variety of isoforms. Precise characterization of such microheterogeneity is essential to improve diagnosis and design appropriate immunotherapies. Moreover, standardization of allergen vaccine production is a prerequisite for product safety and efficiency. Both qualitative and quantitative analytical methods are thus required to monitor and control the huge natural variability of pollens, as well as final product quality. A proteomic approach has been set up to investigate in depth the structural variability of five group 1 allergens originating from distinct grass species (Ant o 1, Dac g 1, Lol p 1, Phl p 1, and Poa p 1). Whereas group 1 is the most conserved grass pollen allergen, great variations were shown between the various isoforms found in these five species using mass spectrometry, with many amino acid exchanges, as well as variations in proline hydroxylation level and in main N-glycan motifs. The presence of O-linked pentose residues was also demonstrated, with up to three consecutive units on the first hydroxyproline of Ant o 1. In addition, species-specific peptides were identified that might be used for product authentication or individual allergen quantification. Lastly, natural or process-induced modifications (deamidation, oxidation, glycation) were evidenced, which might constitute useful indicators of product degradation. PMID:19572759

  2. Nutrient characteristics of the water masses and their seasonal variability in the eastern equatorial Indian Ocean.

    PubMed

    Sardessai, S; Shetye, Suhas; Maya, M V; Mangala, K R; Prasanna Kumar, S

    2010-01-01

    Nutrient characteristics of four water masses in the light of their thermohaline properties are examined in the eastern Equatorial Indian Ocean during winter, spring and summer monsoon. The presence of low salinity water mass with "Surface enrichments" of inorganic nutrients was observed relative to 20 m in the mixed layer. Lowest oxygen levels of 19 microM at 3 degrees N in the euphotic zone indicate mixing of low oxygen high salinity Arabian Sea waters with the equatorial Indian Ocean. The seasonal variability of nutrients was regulated by seasonally varying physical processes like thermocline elevation, meridional and zonal transport, the equatorial undercurrent and biological processes of uptake and remineralization. Circulation of Arabian Sea high salinity waters with nitrate deficit could also be seen from low N/P ratio with a minimum of 8.9 in spring and a maximum of 13.6 in winter. This large deviation from Redfield N/P ratio indicates the presence of denitrified high salinity waters with a seasonal nitrate deficit ranging from -4.85 to 1.52 in the Eastern Equatorial Indian Ocean.

  3. Direct measurement of sub-surface mass change using the variable-baseline gravity gradient method

    USGS Publications Warehouse

    Kennedy, Jeffrey; Ferré, Ty P. A.; Güntner, Andreas; Abe, Maiko; Creutzfeldt, Benjamin

    2014-01-01

    Time-lapse gravity data provide a direct, non-destructive method to monitor mass changes at scales from cm to km. But, the effectively infinite spatial sensitivity of gravity measurements can make it difficult to isolate the signal of interest. The variable-baseline gravity gradient method, based on the difference of measurements between two gravimeters, is an alternative to the conventional approach of individually modeling all sources of mass and elevation change. This approach can improve the signal-to-noise ratio for many applications by removing the contributions of Earth tides, loading, and other signals that have the same effect on both gravimeters. At the same time, this approach can focus the support volume within a relatively small user-defined region of the subsurface. The method is demonstrated using paired superconducting gravimeters to make for the first time a large-scale, non-invasive measurement of infiltration wetting front velocity and change in water content above the wetting front.

  4. Annual and interannual variability of the Barents Sea water masses and polar front: 1980-2011

    NASA Astrophysics Data System (ADS)

    Oziel, Laurent; Sirven, Jerome; Gascard, Jean-Claude

    2015-04-01

    The Barents Sea (BS) is a transition area between the warm and saline Atlantic Waters (AW) and the cold and fresh Arctic Waters (ArW). The BS is characterized by a polar front structure separating AW from ArW. The mixing and cooling of these two water mass generates dense waters in winter. Dense waters are of prior importance because they cascade into the Arctic Ocean to form the Artic Intermediate Waters. This study will use a new hydrographic data set fulfilled by recent stations in the Russian area and a 3D model coupled with atmosphere and ice as a back up to investigate the link between fronts and water masses, as well as their variability over the last 30 years. This study suggests that the polar front structure is composed of two branches and that the dense waters are found in between. The BS, especially in the East, is experiencing an "Atlantification" accompanied with a drastic sea ice decline. These changes, amplified during the last decade, shift the southern branch of the polar front structure in the Norh-East direction and affect negatively the dense water formation. This could have major impacts on the Arctic Ocean ventilation and primary production.

  5. Nutrient characteristics of the water masses and their seasonal variability in the eastern equatorial Indian Ocean.

    PubMed

    Sardessai, S; Shetye, Suhas; Maya, M V; Mangala, K R; Prasanna Kumar, S

    2010-01-01

    Nutrient characteristics of four water masses in the light of their thermohaline properties are examined in the eastern Equatorial Indian Ocean during winter, spring and summer monsoon. The presence of low salinity water mass with "Surface enrichments" of inorganic nutrients was observed relative to 20 m in the mixed layer. Lowest oxygen levels of 19 microM at 3 degrees N in the euphotic zone indicate mixing of low oxygen high salinity Arabian Sea waters with the equatorial Indian Ocean. The seasonal variability of nutrients was regulated by seasonally varying physical processes like thermocline elevation, meridional and zonal transport, the equatorial undercurrent and biological processes of uptake and remineralization. Circulation of Arabian Sea high salinity waters with nitrate deficit could also be seen from low N/P ratio with a minimum of 8.9 in spring and a maximum of 13.6 in winter. This large deviation from Redfield N/P ratio indicates the presence of denitrified high salinity waters with a seasonal nitrate deficit ranging from -4.85 to 1.52 in the Eastern Equatorial Indian Ocean. PMID:20547419

  6. Link between Mass-loss and Variability Type for AGB Stars?

    NASA Astrophysics Data System (ADS)

    Ivezić, Ž.; Knapp, G. R.

    We find that AGB stars separate in the 25-12 vs. 12-K color-color diagram according to their chemistry (O, S vs. C) and variability type (Miras vs. SRb/Lb). While discrimination according to the chemical composition is not surprising, the separation of Miras from SRb/Lb variables is unexpected. We show that ``standard'' steady-state radiatively driven models provide excellent fits to the color distribution of Miras of all chemical types. However, these models are incapable of explaining the dust emission from O-rich SRb/Lb stars. The models can be altered to fit the data by postulating different optical properties for silicate grains, or by assuming that the dust temperature at the inner envelope radius is significantly lower (300-400 K) than typical condensation temperatures (800-1,000 K), a possibility which is also supported by the detailed characteristics of LRS data. While such lower temperatures are required only for O- and S-rich SRb/Lb stars, they are also consistent with the colors of C-rich SRb/Lb stars. The absence of hot dust for SRb/Lb stars can be interpreted as a recent (order of 100 yr) decrease in the mass-loss rate. The distribution of O-rich SRb/Lb stars in the 25-12 vs. K-12 color-color diagram shows that the mass-loss rate probably resumes again, on similar time scales. It cannot be ruled out that the mass-loss rate is changing periodically on such time scales, implying that the stars might oscillate between the Mira and SRb/Lb phases during their AGB evolution as proposed by Kerschbaum et al. (1996). Such a possibility appears to be supported by recent HST images of the Egg Nebula obtained by Sahai et al. (1997), the discovery of multiple CO winds reported by Knapp et al. (1998), and long-term visual light-curve changes detected for some stars by Mattei (1998).

  7. Link between Mass-loss and Variability Type for AGB Stars?

    NASA Astrophysics Data System (ADS)

    Ivezic, Z.; Knapp, G. R.

    1998-12-01

    We find that AGB stars separate in the 25-12 vs. 12-K color-color diagram according to their chemistry (O, S vs. C) and variability type (Miras vs. SRb/Lb). While discrimination according to the chemical composition is not surprising, the separation of Miras from SRb/Lb variables is unexpected. We show that ``standard'' steady-state radiatively driven models provide excellent fits to the color distribution of Miras of all chemical types. However, these models are incapable of explaining the dust emission from O-rich SRb/Lb stars. The models can be altered to fit the data by postulating different optical properties for silicate grains, or by assuming that the dust temperature at the inner envelope radius is significantly lower (300-400 K) than typical condensation temperatures (800-1000 K), a possibility which is also supported by the detailed characteristics of LRS data. While such lower temperatures are required only for O- and S-rich SRb/Lb stars, they are also consistent with the colors of C-rich SRb/Lb stars. The absence of hot dust for SRb/Lb stars can be interpreted as a recent (order of 100 yr) decrease in the mass-loss rate. The distribution of O-rich SRb/Lb stars in the 25-12 vs. K-12 color-color diagram shows that the mass-loss rate probably resumes again, on similar time scales. It cannot be ruled out that the mass-loss rate is changing periodically on such time scales, implying that the stars might oscillate between the Mira and SRb/Lb phases during their AGB evolution as proposed by Kerschbaum et al. (1996). Such a possibility appears to be supported by recent HST images of the Egg Nebula obtained by Sahai et al. (1997), the discovery of multiple CO winds reported by Knapp et al. (1998), and long-term visual light-curve changes detected for some stars by Mattei (1998).

  8. Probing Cloud-Driven Variability on Two of the Youngest, Lowest-Mass Brown Dwarfs in the Solar Neighborhood

    NASA Astrophysics Data System (ADS)

    Schneider, Adam; Cushing, Michael; Kirkpatrick, J. Davy

    2016-08-01

    Young, late-type brown dwarfs share many properties with directly imaged giant extrasolar planets. They therefore provide unique testbeds for investigating the physical conditions present in this critical temperature and mass regime. WISEA 1147-2040 and 2MASS 1119-1137, two recently discovered late-type (~L7) brown dwarfs, have both been determined to be members of the ~10 Myr old TW Hya Association (Kellogg et al. 2016, Schneider et al. 2016). Each has an estimated mass of 5-6 MJup, making them two of the youngest and lowest-mass free floating objects yet found in the solar neighborhood. As such, these two planetary mass objects provide unparalleled laboratories for investigating giant planet-like atmospheres far from the contaminating starlight of a host sun. Condensate clouds play a critical role in shaping the emergent spectra of both brown dwarfs and gas giant planets, and can cause photometric variability via their non-uniform spatial distribution. We propose to photometrically monitor WISEA 1147-2040 and 2MASS 1119-1137 in order to search for the presence of cloud-driven variability to 1) investigate the potential trend of low surface gravity with high-amplitude variability in a previously unexplored mass regime and 2) explore the angular momentum evolution of isolated planetary mass objects.

  9. Composition of air masses in Fuerteventura (Canary Islands) according to their origins

    SciTech Connect

    Patier, R.F.; Diez Hernandez, P.; Diaz Ramiro, E.; Ballesteros, J.S.; Santos-Alves, S.G. dos

    1994-12-31

    The Centro Nacional de Sanidad Ambiental has among their duties the background atmospheric pollution monitoring in Spain. To do so, the laboratory has set up 6 field stations in the Iberian Peninsula. In these stations, both gaseous and particulate pollutants are currently analyzed. However, there is a lack of data about the atmospheric pollution in the Canary, where they are a very strong influence of natural emissions from sea and the Saharan desert, mixed with anthropogenic ones. Therefore, during the ASTEX/MAGE project the CNSA established a station in Fuerteventura island, characterized by the nonexistence of man-made emissions, to measure some atmospheric pollutants, in order to foresee their origins. In this study, the authors analyzed some pollutants that are used to obtain a clue about the sources of air masses such as gaseous ozone and metallic compounds (vanadium, iron and manganese) in the atmospheric aerosol fractionated by size.

  10. Operational performance of a low cost, air mass 2 solar simulator

    NASA Technical Reports Server (NTRS)

    Yass, K.; Curtis, H. B.

    1975-01-01

    Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.

  11. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  12. Simultaneous measurement of mass and rotation of trapped absorbing particles in air.

    PubMed

    Bera, Sudipta K; Kumar, Avinash; Sil, Souvik; Saha, Tushar Kanti; Saha, Tanumoy; Banerjee, Ayan

    2016-09-15

    We trap absorbing micro-particles in air by photophoretic forces generated using a single loosely focused Gaussian trapping beam. We measure a component of the radial Brownian motion of a trapped particle cluster and determine the power spectral density, mean squared displacement, and normalized position and velocity autocorrelation functions to characterize the photophoretic body force in a quantitative fashion for the first time. The trapped particles also undergo spontaneous rotation due to the action of this force. This is evident from the spectral density that displays clear peaks at the rotation and the particles' inertial resonance frequencies. We fit the spectral density to the well-known analytical function derived from the Langevin equation, measure the resonance and rotation frequencies, and determine the values for particle mass that we verify at different trapping laser powers with reasonable accuracy. PMID:27628396

  13. The effects of air mass transport, seasonality, and meteorology on pollutant levels at the Iskrba regional background station (1996-2014)

    NASA Astrophysics Data System (ADS)

    Poberžnik, Matevž; Štrumbelj, Erik

    2016-06-01

    Our main goal was to estimate the effects of long-range air transport on pollutant concentrations measured at the Iskrba regional background station (Slovenia). We cluster back-trajectories into categories and simultaneously model the effects of meteorology, seasonality, trends, and air mass trajectory clusters using a Bayesian statistical approach. This simplifies the interpretation of results and allows us to better identify the effects of individual variables, which is important, because pollutant concentrations, meteorology, and trajectories are seasonal and correlated. Similar to related work from other European sites, we find that slow and faster moving trajectories from eastern Europe and the northern part of the Balkan peninsula are associated with higher pollutant levels, while fast-moving trajectories from the Atlantic are associated with lower pollutant concentration. Overall, pollutant concentrations have decreased in the studied period.

  14. Combustion of a Methane-Air Mixture in a Slot Burner with an Inert Insert in Mass Transfer to the Environment

    NASA Astrophysics Data System (ADS)

    Krainov, A. Yu.; Moiseeva, K. M.

    2016-03-01

    A problem on combustion of a methane-air mixture in a slot burner with an internal insert in mass transfer from the burner's exterior wall to the environment has been solved. A mathematical formulation of the problem takes account of the dependence of the diffusion, thermal-conductivity, and heat-transfer coefficients on temperature, and also of the heat removal from the gas to the environment by convective and radiant heat transfer. A numerical investigation has been carried out in a one-dimensional mathematical formulation of the problem in dimensional variables. The boundary of existence of a stable high-temperature regime of combustion of the methane-air mixture has been determined as a function of the rate of feed of the gas, the environmental temperature, and the width of the flow area of the burner.

  15. Variability and risk analysis of Hong Kong air quality based on Monsoon and El Niño conditions

    NASA Astrophysics Data System (ADS)

    Kim, Jong-Suk; Zhou, Wen; Cheung, Ho Nam; Chow, Chak Hang

    2013-03-01

    This study presents an exploratory analysis aimed at improving understanding of the variability of Hong Kong air quality associated with different climate conditions. Significantly negative correlations were found when Niño 3 led particulate matter ⩽10 μm PM10) and NO2 by 2-3 months over the Hong Kong territory, while the other pollutants (e.g., O3, SO2) showed modest correlations. A significant decreasing trend in visibility was observed during the autumn and winter, which has potential implications for the air-quality degradation and the endangerment of human health in Hong Kong. In an El Niño summer, the visibility was relatively better, while visibility in other seasons was diminished. On the other hand, in La Niña events, significant changes occurred in visibility in winter and autumn. Air pollution indices were less sensitive to the South China Summer Monsoon (SCSM), but a relatively high correlation existed between the East Asian Winter Monsoon (EAWM) and air pollutants. Rainfall was lower during most of the strong EAWM years compared to the weak years. This result suggests that the pollutants that accumulate in Hong Kong are not easy to wash out, so concentrations remain at a higher level. Finally, based on the conditional Air Pollution Index (API) risk assessment, site-specific vulnerabilities were analyzed to facilitate the development of the air-quality warning systems in Hong Kong.

  16. Identification of aerosol types over an urban site based on air-mass trajectory classification

    NASA Astrophysics Data System (ADS)

    Pawar, G. V.; Devara, P. C. S.; Aher, G. R.

    2015-10-01

    Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18°32‧N; 73°49‧E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD500 nm) and Ångström exponent (AE, α). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD500 nm scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (τpλ = 0.43 ± 0.13) and high AE (α = 1.19 ± 0.15). These values imply the presence of accumulation/sub-micron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (τpλ = 0.61 ± 0.21), and low AE (α = 0.54 ± 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant.

  17. AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

    EPA Science Inventory

    Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

  18. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    SciTech Connect

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  19. Ring waves as a mass transport mechanism in air-driven core-annular flows.

    PubMed

    Camassa, Roberto; Forest, M Gregory; Lee, Long; Ogrosky, H Reed; Olander, Jeffrey

    2012-12-01

    Air-driven core-annular fluid flows occur in many situations, from lung airways to engineering applications. Here we study, experimentally and theoretically, flows where a viscous liquid film lining the inside of a tube is forced upwards against gravity by turbulent airflow up the center of the tube. We present results on the thickness and mean speed of the film and properties of the interfacial waves that develop from an instability of the air-liquid interface. We derive a long-wave asymptotic model and compare properties of its solutions with those of the experiments. Traveling wave solutions of this long-wave model exhibit evidence of different mass transport regimes: Past a certain threshold, sufficiently large-amplitude waves begin to trap cores of fluid which propagate upward at wave speeds. This theoretical result is then confirmed by a second set of experiments that show evidence of ring waves of annular fluid propagating over the underlying creeping flow. By tuning the parameters of the experiments, the strength of this phenomenon can be adjusted in a way that is predicted qualitatively by the model.

  20. Synoptic patterns and air mass transport during ozone episodes in northwestern Iberia.

    PubMed

    Saavedra, S; Rodríguez, A; Taboada, J J; Souto, J A; Casares, J J

    2012-12-15

    High levels of ozone are frequently measured at the Galicia (NW Iberian Peninsula) air quality monitoring stations from March to October. However, there have been very few studies on surface ozone in the northwestern Iberian Peninsula, most likely because the climate of this region is not favourable to photochemical ozone generation. The occurrence of these episodes may be related to either local-scale photochemical pollution or regional-scale transport from other polluted regions. In addition, high ozone episodes usually are developed under specific synoptic conditions. The main purposes of this study are to characterise the atmospheric conditions that lead to the ozone episodes in this region and to identify possible advection paths of ozone and precursors. A surface hourly ozone dataset (2002-2007) measured at rural sites in Galicia was analysed to identify high ozone episodes together with their associated synoptic patterns using a subjective classification with 23 different synoptic types. The synoptic weather patterns revealed that most of the episodes occur with high surface pressures centred over the British Isles and/or Central Europe while a high-altitude anticyclonic ridge crosses the Peninsula from North Africa, causing easterly or southeasterly winds. This analysis was completed with 3-day backward air mass trajectories obtained with HYSPLIT to assess the contribution of long-range transport, resulting in the following main routes: Mediterranean-Peninsular, South Atlantic-Portuguese, local and French-Cantabric.

  1. Enantiomeric signatures of organochlorine pesticides in Asian, trans-Pacific, and western U.S. air masses.

    PubMed

    Genualdi, Susan A; Simonich, Staci L Massey; Primbs, Toby K; Bidleman, Terry F; Jantunen, Liisa M; Ryoo, Keon-Sang; Zhu, Tong

    2009-04-15

    The enantiomeric signatures of organochlorine pesticides were measured in air masses from Okinawa, Japan and three remote locations in the Pacific Northwestern United States: Cheeka Peak Observatory (CPO), a marine boundary layer site on the Olympic Peninsula of Washington at 500 m above sea level (m.a.s.l); Mary's Peak Observatory (MPO), a site at 1250 m.a.s.l in Oregon's Coast range; and Mt. Bachelor Observatory (MBO), a site at 2763 m.a.s.l in Oregon's Cascade range. The enantiomeric signatures of composite soil samples, collected from China, South Korea, and the western U.S. were also measured. The data from chiral analysis was expressed asthe enantiomeric fraction, defined as (+) enantiomer/(sum of the (+) and (-) enantiomers), where a racemic composition has EF = 0.5. Racemic alpha-hexachlorocyclohexane (alpha-HCH) was measured in Asian air masses at Okinawa and in Chinese and South Korean soils. Nonracemic alpha-HCH (EF = 0.528 +/- 0.0048) was measured in regional air masses at CPO, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the alpha-HCH EFs were significantly more racemic (EF = 0.513 +/- 0.0003, p < 0.001). Racemic alpha-HCH was consistently measured at MPO and MBO in trans-Pacific air masses that had spent considerable time in the free troposphere. The alpha-HCH EFs in CPO, MPO, and MBO air masses were negatively correlated (p = 0.0017) with the amount of time the air mass spent above the boundary layer, along the 10-day back air mass trajectory, prior to being sampled. This suggests that, on the West coast of the U.S., the alpha-HCH in the free troposphere is racemic. Racemic signatures of cis- and trans-chlordane were measured in air masses at all four air sampling sites, suggesting that Asian and U.S. urban areas continue to be sources of chlordane that has not yet been biotransformed. PMID:19475954

  2. Enantiomeric Signatures of Organochlorine Pesticides in Asian, Trans-Pacific and Western U.S. Air Masses

    PubMed Central

    Genualdi, Susan A.; Massey Simonich, Staci L.; Primbs, Toby K.; Bidleman, Terry F.; Jantunen, Liisa M.; Ryoo, Keon-Sang; Zhu, Tong

    2009-01-01

    The enantiomeric signatures of organochlorine pesticides were measured in air masses from Okinawa, Japan and three remote locations in the Pacific Northwestern U.S.: Cheeka Peak Observatory (CPO), a marine boundary layer site on the Olympic Peninsula of Washington at 500 meters above sea level (m.a.s.l); Mary’s Peak Observatory (MPO), a site at 1250 m.a.s.l in Oregon’s Coast range; and Mt. Bachelor Observatory (MBO), a site at 2763 m.a.s.l in Oregon’s Cascade range. The enantiomeric signatures of composite soil samples, collected from China, South Korea, and the western U.S. were also measured. The data from chiral analysis was expressed as the enantiomeric fraction (1), defined as (+) enantiomer/(sum of the (+) and (−) enantiomers), where a racemic composition has EF = 0.5. Racemic α-hexachlorocyclohexane (α-HCH) was measured in Asian air masses at Okinawa and in Chinese and South Korean soils. Non-racemic α-HCH (EF = 0.528 ± 0.0048) was measured in regional air masses at CPO, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the α-HCH EFs were significantly more racemic (EF = 0.513 ± 0.0003, p < 0.001). Racemic α-HCH was consistently measured at MPO and MBO in trans-Pacific air masses that had spent considerable time in the free troposphere. The α-HCH EFs in CPO, MPO, and MBO air masses were negatively correlated (p = 0.0017) with the amount of time the air mass spent above the boundary layer, along the 10-day back air mass trajectory, prior to being sampled. This suggests that, on the West coast of the U.S., the α-HCH in the free troposphere is racemic. Racemic signatures of cis- and trans-chlordane were measured in air masses at all four air sampling sites, suggesting that Asian and U.S. urban areas continue to be sources of chlordane that has not yet been biotransformed. PMID:19475954

  3. Enantiomeric signatures of organochlorine pesticides in Asian, trans-Pacific, and western U.S. air masses.

    PubMed

    Genualdi, Susan A; Simonich, Staci L Massey; Primbs, Toby K; Bidleman, Terry F; Jantunen, Liisa M; Ryoo, Keon-Sang; Zhu, Tong

    2009-04-15

    The enantiomeric signatures of organochlorine pesticides were measured in air masses from Okinawa, Japan and three remote locations in the Pacific Northwestern United States: Cheeka Peak Observatory (CPO), a marine boundary layer site on the Olympic Peninsula of Washington at 500 m above sea level (m.a.s.l); Mary's Peak Observatory (MPO), a site at 1250 m.a.s.l in Oregon's Coast range; and Mt. Bachelor Observatory (MBO), a site at 2763 m.a.s.l in Oregon's Cascade range. The enantiomeric signatures of composite soil samples, collected from China, South Korea, and the western U.S. were also measured. The data from chiral analysis was expressed asthe enantiomeric fraction, defined as (+) enantiomer/(sum of the (+) and (-) enantiomers), where a racemic composition has EF = 0.5. Racemic alpha-hexachlorocyclohexane (alpha-HCH) was measured in Asian air masses at Okinawa and in Chinese and South Korean soils. Nonracemic alpha-HCH (EF = 0.528 +/- 0.0048) was measured in regional air masses at CPO, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the alpha-HCH EFs were significantly more racemic (EF = 0.513 +/- 0.0003, p < 0.001). Racemic alpha-HCH was consistently measured at MPO and MBO in trans-Pacific air masses that had spent considerable time in the free troposphere. The alpha-HCH EFs in CPO, MPO, and MBO air masses were negatively correlated (p = 0.0017) with the amount of time the air mass spent above the boundary layer, along the 10-day back air mass trajectory, prior to being sampled. This suggests that, on the West coast of the U.S., the alpha-HCH in the free troposphere is racemic. Racemic signatures of cis- and trans-chlordane were measured in air masses at all four air sampling sites, suggesting that Asian and U.S. urban areas continue to be sources of chlordane that has not yet been biotransformed.

  4. Variables Related to Pre-Service Cannabis Use in a Sample of Air Force Enlistees.

    ERIC Educational Resources Information Center

    Mullins, Cecil J.; And Others

    This report is an attempt to add to the existing information about cannabis use, its correlates, and its effects. The sample population consisted of self-admitted abusers of various drugs, identified shortly after entering the Air Force. The subjects (N=4688) were located through the Drug Control Office at Lackland Air Force Base. Variables…

  5. Confirmation of mass-independent Ni isotopic variability in iron meteorites

    NASA Astrophysics Data System (ADS)

    Steele, Robert C. J.; Elliott, Tim; Coath, Christopher D.; Regelous, Marcel

    2011-12-01

    We report high-precision analyses of internally-normalised Ni isotope ratios in 12 bulk iron meteorites. Our measurements of 60Ni/ 61Ni, 62Ni/ 61Ni and 64Ni/ 61Ni normalised to 58Ni/ 61Ni and expressed in parts per ten thousand (‱) relative to NIST SRM 986 as ɛ60Ni,ɛ62Ni and ɛ64Ni, vary by 0.146, 0.228 and 0.687, respectively. The precision on a typical analysis is 0.03‱, 0.05‱ and 0.08‱ for ɛ60Ni, ɛ62Ni and ɛ64Ni, respectively, which is comparable to our sample reproducibility. We show that this 'mass-independent' Ni isotope variability cannot be ascribed to interferences, inaccurate correction of instrumental or natural mass-dependent fractionation, fractionation controlled by nuclear field shift effects, nor the influence of cosmic ray spallation. These results thus document the presence of mass-independent Ni isotopic heterogeneity in bulk meteoritic samples, as previously proposed by Regelous et al. (2008) (EPSL 272, 330-338), but our new analyses are more precise and include determination of 64Ni. Intriguingly, we find that terrestrial materials do not yield homogenous internally-normalised Ni isotope compositions, which, as pointed out by Young et al. (2002) (GCA 66, 1095-1104), may be the expected result of using the exponential (kinetic) law and atomic masses to normalise all fractionation processes. The certified Ni isotope reference material NIST SRM 986 defines zero in this study, while appropriate ratios for the bulk silicate Earth are given by the peridotites JP-1 and DTS-2 and, relative to NIST SRM 986, yield deviations in ɛ60Ni, ɛ62Ni and ɛ64Ni of -0.006‱, 0.036‱ and 0.119‱, respectively. There is a strong positive correlation between ɛ64Ni and ɛ62Ni in iron meteorites analyses, with a slope of 3.03 ± 0.71. The variations of Ni isotope anomalies in iron meteorites are consistent with heterogeneous distribution of a nucleosynthetic component from a type Ia supernova into the proto-solar nebula.

  6. Development and characterisation of a state-of-the-art GOME-2 formaldehyde air-mass factor algorithm

    NASA Astrophysics Data System (ADS)

    Hewson, W.; Barkley, M. P.; Gonzalez Abad, G.; Bösch, H.; Kurosu, T.; Spurr, R.; Tilstra, L. G.

    2015-10-01

    Space-borne observations of formaldehyde (HCHO) are frequently used to derive surface emissions of isoprene, an important biogenic volatile organic compound. The conversion of retrieved HCHO slant column concentrations from satellite line-of-sight measurements to vertical columns is determined through application of an air mass factor (AMF), accounting for instrument viewing geometry, radiative transfer, and vertical profile of the absorber in the atmosphere. This step in the trace gas retrieval is subject to large errors. This work presents the AMF algorithm in use at the University of Leicester (UoL), which introduces scene-specific variables into a per-observation full radiative transfer AMF calculation, including increasing spatial resolution of key environmental parameter databases, input variable area weighting, instrument-specific scattering weight calculation, and inclusion of an ozone vertical profile climatology. Application of these updates to HCHO slant columns from the GOME-2 instrument is shown to typically adjust the AMF by ±20 %, compared to a reference algorithm without these advanced parameterisations. On average the GOME-2 AMFs increase by 4 %, with over 70 % of locations having an AMF of 0-20 % larger than originally, largely resulting from the use of the latest GOME-2 reflectance product. Furthermore, the new UoL algorithm also incorporates a full radiative transfer error calculation for each scene to help characterise AMF uncertainties. Global median AMF errors are typically 50-60 %, and are driven by uncertainties in the HCHO profile shape and its vertical distribution relative to clouds and aerosols. If uncertainty on the a priori HCHO profile is relatively small (< 10 %) then the median AMF total error decreases to about 30-40 %.

  7. Spatiotemporal variability of tetrachloroethylene in residential indoor air due to vapor intrusion: a longitudinal, community-based study.

    PubMed

    Johnston, Jill E; Gibson, Jacqueline MacDonald

    2014-11-01

    The migration of volatile contaminants from groundwater and soil into indoor air is a potential health threat at thousands of contaminated sites across the country. This phenomenon, known as vapor intrusion, is characterized by spatial and temporal heterogeneity. This study examined short-term fluctuations in concentrations of tetrachloroethylene (PCE) in the indoor air of residential homes due to vapor intrusion in a community in San Antonio, Texas, that sits atop an extensive, shallow plume of contaminated groundwater. Using a community-based design, we removed potential indoor sources of PCE and then collected twelve 3-day passive indoor air samples in each of the 20 homes. Results demonstrated a one-order-of-magnitude variability in concentration across both space and time among the study homes, although all measured concentrations were below risk-based screening levels. We found that within any given home, indoor concentrations increase with the magnitude of the barometric pressure drop (P=0.048) and humidity (P<0.001), while concentrations decrease as wind speed increases (P<0.001) and also during winter (P=0.001). In a second analysis to examine sources of spatial variability, we found that indoor air PCE concentrations between homes increase with groundwater concentration (P=0.030) and a slab-on-grade (as compared with a crawl space) foundation (P=0.028), whereas concentrations decrease in homes without air conditioners (P=0.015). This study offers insights into the drivers of temporal and spatial variability in vapor intrusion that can inform decisions regarding monitoring and exposure assessment at affected sites.

  8. Regional variability in diving physiology and behavior in a widely distributed air-breathing marine predator, the South American sea lion (Otaria byronia).

    PubMed

    Hückstädt, Luis A; Tift, Michael S; Riet-Sapriza, Federico; Franco-Trecu, Valentina; Baylis, Alastair M M; Orben, Rachael A; Arnould, John P Y; Sepulveda, Maritza; Santos-Carvallo, Macarena; Burns, Jennifer M; Costa, Daniel P

    2016-08-01

    Our understanding of how air-breathing marine predators cope with environmental variability is limited by our inadequate knowledge of their ecological and physiological parameters. Because of their wide distribution along both coasts of the sub-continent, South American sea lions (Otaria byronia) provide a valuable opportunity to study the behavioral and physiological plasticity of a marine predator in different environments. We measured the oxygen stores and diving behavior of South American sea lions throughout most of its range, allowing us to demonstrate that diving ability and behavior vary across its range. We found no significant differences in mass-specific blood volumes of sea lions among field sites and a negative relationship between mass-specific oxygen storage and size, which suggests that exposure to different habitats and geographical locations better explains oxygen storage capacities and diving capability in South American sea lions than body size alone. The largest animals in our study (individuals from Uruguay) were the shallowest and shortest duration divers, and had the lowest mass-specific total body oxygen stores, while the deepest and longest duration divers (individuals from southern Chile) had significantly larger mass-specific oxygen stores, despite being much smaller animals. Our study suggests that the physiology of air-breathing diving predators is not fixed, but that it can be adjusted, to a certain extent, depending on the ecological setting and or habitat. These adjustments can be thought of as a 'training effect': as the animal continues to push its physiological capacity through greater hypoxic exposure, its breath-holding capacity increases.

  9. Regional variability in diving physiology and behavior in a widely distributed air-breathing marine predator, the South American sea lion (Otaria byronia).

    PubMed

    Hückstädt, Luis A; Tift, Michael S; Riet-Sapriza, Federico; Franco-Trecu, Valentina; Baylis, Alastair M M; Orben, Rachael A; Arnould, John P Y; Sepulveda, Maritza; Santos-Carvallo, Macarena; Burns, Jennifer M; Costa, Daniel P

    2016-08-01

    Our understanding of how air-breathing marine predators cope with environmental variability is limited by our inadequate knowledge of their ecological and physiological parameters. Because of their wide distribution along both coasts of the sub-continent, South American sea lions (Otaria byronia) provide a valuable opportunity to study the behavioral and physiological plasticity of a marine predator in different environments. We measured the oxygen stores and diving behavior of South American sea lions throughout most of its range, allowing us to demonstrate that diving ability and behavior vary across its range. We found no significant differences in mass-specific blood volumes of sea lions among field sites and a negative relationship between mass-specific oxygen storage and size, which suggests that exposure to different habitats and geographical locations better explains oxygen storage capacities and diving capability in South American sea lions than body size alone. The largest animals in our study (individuals from Uruguay) were the shallowest and shortest duration divers, and had the lowest mass-specific total body oxygen stores, while the deepest and longest duration divers (individuals from southern Chile) had significantly larger mass-specific oxygen stores, despite being much smaller animals. Our study suggests that the physiology of air-breathing diving predators is not fixed, but that it can be adjusted, to a certain extent, depending on the ecological setting and or habitat. These adjustments can be thought of as a 'training effect': as the animal continues to push its physiological capacity through greater hypoxic exposure, its breath-holding capacity increases. PMID:27247316

  10. Impact of fine particulate fluctuation and other variables on Beijing's air quality index.

    PubMed

    Chen, Bo; Lu, Shaowei; Li, Shaoning; Wang, Bing

    2015-04-01

    We analyzed fluctuation in Beijing's air quality over 328 days, based on air quality grades and air quality data from 35 atmospheric monitoring stations. Our results show the air over Beijing is subject to pollution 152 days of the year, or 46.34%. Among all pollutants, fine particulates, solid or liquid, 2.5 μm or less in size (PM2.5), appeared most frequently as the primary pollutant: 249 days, or 76% of the sample year (328 days). Nitrogen dioxide (NO2) and coarse particulates (PM10) cause the least pollution, appearing only 7 and 3 days, or 2 and 1% of the sample year, respectively. In Beijing, fine particulates like PM2.5 vary seasonally: 154.54 ± 18.60 in winter > 145.22 ± 18.61 in spring > 140.16 ± 20.76 in autumn > 122.37 ± 13.42 in summer. Air quality is best in August and worst in December, while various districts in Beijing experience different air quality. To be specific, from south to north and from west to east, air quality tends to improve. Meteorological elements have a constraining effect on air pollutants, which means there is a linear correlation between the air quality index and humidity, rainfall, wind speed, and temperature. Under a typical pollution scenario, the higher the air quality index (AQI) value, the lower the wind speed and the greater the relative humidity; the lower the AQI value, the higher the wind speed and lower the relative humidity. Analysis of influencing factors reveals that the air pollution is mainly particulate matter produced by burning coal, vehicle emissions, volatile oils and gas, fast development of food services, emissions from the surrounding region, and natural dust clouds formed in arid areas to the northwest. Topography affects the distribution of meteorological conditions, in turn varying air quality over the region from one location to another. Human activities also exercise impact on urban air quality with dual functions.

  11. Impact of fine particulate fluctuation and other variables on Beijing's air quality index.

    PubMed

    Chen, Bo; Lu, Shaowei; Li, Shaoning; Wang, Bing

    2015-04-01

    We analyzed fluctuation in Beijing's air quality over 328 days, based on air quality grades and air quality data from 35 atmospheric monitoring stations. Our results show the air over Beijing is subject to pollution 152 days of the year, or 46.34%. Among all pollutants, fine particulates, solid or liquid, 2.5 μm or less in size (PM2.5), appeared most frequently as the primary pollutant: 249 days, or 76% of the sample year (328 days). Nitrogen dioxide (NO2) and coarse particulates (PM10) cause the least pollution, appearing only 7 and 3 days, or 2 and 1% of the sample year, respectively. In Beijing, fine particulates like PM2.5 vary seasonally: 154.54 ± 18.60 in winter > 145.22 ± 18.61 in spring > 140.16 ± 20.76 in autumn > 122.37 ± 13.42 in summer. Air quality is best in August and worst in December, while various districts in Beijing experience different air quality. To be specific, from south to north and from west to east, air quality tends to improve. Meteorological elements have a constraining effect on air pollutants, which means there is a linear correlation between the air quality index and humidity, rainfall, wind speed, and temperature. Under a typical pollution scenario, the higher the air quality index (AQI) value, the lower the wind speed and the greater the relative humidity; the lower the AQI value, the higher the wind speed and lower the relative humidity. Analysis of influencing factors reveals that the air pollution is mainly particulate matter produced by burning coal, vehicle emissions, volatile oils and gas, fast development of food services, emissions from the surrounding region, and natural dust clouds formed in arid areas to the northwest. Topography affects the distribution of meteorological conditions, in turn varying air quality over the region from one location to another. Human activities also exercise impact on urban air quality with dual functions. PMID:25563832

  12. Body mass penalties in the physical fitness tests of the Army, Air Force, and Navy.

    PubMed

    Vanderburgh, Paul M; Crowder, Todd A

    2006-08-01

    Recent research has empirically documented a consistent penalty against heavier service members for events identical or similar to those in the physical fitness tests of the Army, Air Force, and Navy. These penalties, which are not related to body fatness, are based on biological scaling models and have a physiological basis. Using hypothetical cases, we quantified the penalties for men, with body mass of 60 vs. 90 kg, and women, 45 vs. 75 kg, to be 15% to 20% for the fitness tests of these three services. Such penalties alone can adversely affect awards and promotions for heavier service members. To deal equitably with these penalties in a practical manner, we offer two recommendations, i.e., (1) implementation of revised fitness tests with balanced events, in which the penalties of one event for heavier service members are balanced by an equal and opposite bias against lighter service members, or (2) development of correction factors that can be multiplied by raw scores to yield adjusted scores free of body mass bias.

  13. An in-vitro investigation of the effects of variable operating parameters on alumina air-abrasion cutting characteristics.

    PubMed

    Paolinelis, George; Banerjee, Avijit; Watson, Timothy F

    2009-01-01

    Air-abrasion is a tooth preparation technology developed in the 1940s that is currently gaining popularity due to its compatibility with adhesive restorations. Variables, including propellant pressure, powder flow rate, nozzle angle and distance to the tooth surface abrasion time, can affect the cutting rate of the air-abrasion unit. A static setup and a more clinically realistic dynamic experimental setup have been used to assess the effect of these parameters of the cutting rate on an enamel analogue. By keeping each parameter fixed, its effect on the cutting rate was examined. The results showed that increasing the propellant pressure (20-100 PSI) caused an almost linear increase in the cutting rate in both setups. Increasing the powder flow rate (0.5 - 3 g/minute) concurrently increased the powder flow and caused an increase in the cutting rate but with a plateau differing for the different propellant pressures. The nozzle angles producing the highest cutting rates were 60 degrees and 75 degrees for static and dynamic cutting, respectively, with smaller and larger angles producing lower rates. Increasing abrasion time in static cutting and the nozzle advancement rate in dynamic cutting both caused an increase in the cutting rate. These findings are relevant for both clinicians, who might wish to alter the cutting rate of their instrument, and researchers, who should always control the numerous parameters in studies involving air-abrasion in order to control the variables, which can influence the end effect of air-abrasion.

  14. Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)

    NASA Astrophysics Data System (ADS)

    Dall'Osto, Manuel; Beddows, David C. S.; Gietl, Johanna K.; Olatunbosun, Oluremi A.; Yang, Xiaoguang; Harrison, Roy M.

    2014-09-01

    There is a paucity of quantitative knowledge on the contributions of non-exhaust (abrasion and re-suspension) sources to traffic emissions. Abrasive emissions can be broadly categorised as tyre wear, brake wear and road dust/road surface wear. Current research often considers road dust and tyre dust as externally mixed particles, the former mainly composed of mineral matter and the latter solely composed of mainly organic matter and some trace elements. The aim of this work was to characterise tyre wear from both laboratory and field studies by using Aerosol Time-Of-Flight Mass Spectrometry (ATOFMS). Real-time single particle chemical composition was obtained from a set of rubber tyres rotating on a metal surface. Bimodal particle number size distributions peaking at 35 nm and 85 nm were obtained from SMPS/APS measurements over the range 6-20,000 nm. ATOFMS mass spectra of tyre wear in the particle size range 200-3000 nm diameter show peaks due to exo-sulphur compounds, nitrate, Zn and ions of high molecular weight (m/z > 100) attributed to organic polymers. Two large ATOFMS datasets collected from a number of outdoor studies were examined. The former was constituted of 48 road dust samples collected on the roads of London. The latter consisted of ATOFMS ambient air field studies from Europe, overall composed of more than 2,000,000 single particle mass spectra. The majority (95%) of tyre wear particles present in the road dust samples and atmospheric samples are internally mixed with metals (Li, Na, Ca, Fe, Ti), as well as phosphate. It is concluded that the interaction of tyres with the road surface creates particles internally mixed from two sources: tyre rubber and road surface materials. Measurements of the tyre rubber component alone may underestimate the contribution of tyre wear to concentrations of airborne particulate matter. The results presented are especially relevant for urban aerosol source apportionment and PM2.5 exposure assessment.

  15. Study Case of Air-Mass Modification over Poland and Romania Observed by the Means of Multiwavelength Raman Depolarization Lidars

    NASA Astrophysics Data System (ADS)

    Costa-Surós, Montserrat; Janicka, Lucja; Stachlewska, Iwona S.; Nemuc, Anca; Talianu, Camelia; Heese, Birgit; Engelmann, Ronny

    2016-06-01

    An air-mass modification, on its way from Poland to Romania, observed between 19-21 July 2014 is discussed. The air-mass was investigated using data of two multi-wavelength lidars capable of performing regular elastic, depolarization and Raman measurements in Warsaw, Poland, and in Magurele, Romania. The analysis was focused on evaluating optical properties of aerosol in order to search for similarities and differences in the vertical profiles describing the atmospheric layers above the two stations within given period.

  16. Modeling spatial and temporal variability of residential air exchange rates for the Near-Road Exposures and Effects of Urban Air Pollutants Study (NEXUS).

    PubMed

    Breen, Michael S; Burke, Janet M; Batterman, Stuart A; Vette, Alan F; Godwin, Christopher; Croghan, Carry W; Schultz, Bradley D; Long, Thomas C

    2014-11-07

    Air pollution health studies often use outdoor concentrations as exposure surrogates. Failure to account for variability of residential infiltration of outdoor pollutants can induce exposure errors and lead to bias and incorrect confidence intervals in health effect estimates. The residential air exchange rate (AER), which is the rate of exchange of indoor air with outdoor air, is an important determinant for house-to-house (spatial) and temporal variations of air pollution infiltration. Our goal was to evaluate and apply mechanistic models to predict AERs for 213 homes in the Near-Road Exposures and Effects of Urban Air Pollutants Study (NEXUS), a cohort study of traffic-related air pollution exposures and respiratory effects in asthmatic children living near major roads in Detroit, Michigan. We used a previously developed model (LBL), which predicts AER from meteorology and questionnaire data on building characteristics related to air leakage, and an extended version of this model (LBLX) that includes natural ventilation from open windows. As a critical and novel aspect of our AER modeling approach, we performed a cross validation, which included both parameter estimation (i.e., model calibration) and model evaluation, based on daily AER measurements from a subset of 24 study homes on five consecutive days during two seasons. The measured AER varied between 0.09 and 3.48 h(-1) with a median of 0.64 h(-1). For the individual model-predicted and measured AER, the median absolute difference was 29% (0.19 h‑1) for both the LBL and LBLX models. The LBL and LBLX models predicted 59% and 61% of the variance in the AER, respectively. Daily AER predictions for all 213 homes during the three year study (2010-2012) showed considerable house-to-house variations from building leakage differences, and temporal variations from outdoor temperature and wind speed fluctuations. Using this novel approach, NEXUS will be one of the first epidemiology studies to apply calibrated and

  17. Effect of environmental variables on body size evolution of crinoids between periods of mass extinctions

    NASA Astrophysics Data System (ADS)

    Jani, T.; Heim, N. A.; Payne, J.

    2013-12-01

    Body size plays a major role in determining whether or not an organism can sustain in its local environment. The ecosystem of an animal has a major effect on the fitness of organisms, and it would be interesting to note the degree to which various environmental factors alter body size. In my project, I identify three environmental factors that seem to affect body size of crinoids, marine invertebrates from phylum Echinodermata, and explore how these variables play out in the intervals between the five mass extinctions. The particular factors I study include atmospheric CO2 concentration (proxy for temperature), O2 concentration, and sea level. Although the r and p values for all of these factors were statistically insignificant to definitively make any correlation, there was a visual correlation. For O2, I noted a generally positive correlation with body size over time. CO2 trends suggested a negative correlation until the K-T boundary, but a positive correlation afterwards. Correlation with sea level was a little more complicated: correlation was positive from the start of the Phanerozoic to the Permian extinction; it turned negative until the Cretaceous-Tertiary boundary; afterwards, it again became positive. However, for all three variables, statistical values are too low to say definitively mark any correlation. Out of all three factors, CO2 levels had the highest correlation and lowest p-values in the most time intervals: from the start of the Phanerozoic to Ordovician-Silurian Extinction, from the Late Devonian to the Permian Extinction, and from the Cretaceous-Tertiary boundary to the present. When considering first differences, CO2 levels also had the highest correlation from the Permian Extinction to Triassic-Jurassic Extinction and from the Triassic-Jurassic Extinction to Cretaceous-Tertiary Extinction. Using PaleoTS, I found that body size evolution patterns either seemed to follow either an unbiased random walk (URW) or stasis in the intervals between

  18. Dynamical masses of a nova-like variable on the edge of the period gap

    NASA Astrophysics Data System (ADS)

    Rodríguez-Gil, P.; Shahbaz, T.; Marsh, T. R.; Gänsicke, B. T.; Steeghs, D.; Long, K. S.; Martínez-Pais, I. G.; Armas Padilla, M.; Schwarz, R.; Schreiber, M. R.; Torres, M. A. P.; Koester, D.; Dhillon, V. S.; Castellano, J.; Rodríguez, D.

    2015-09-01

    We present the first dynamical determination of the binary parameters of an eclipsing SW Sextantis star in the 3-4 h orbital period range during a low state. We obtained time-resolved optical spectroscopy and photometry of HS 0220+0603 during its 2004-2005 low-brightness state, as revealed in the combined Small & Moderate Aperture Research Telescope System, IAC80 and M1 Group long-term optical light curve. The optical spectra taken during primary eclipse reveal a secondary star spectral type of M5.5 ± 0.5 as derived from molecular band-head indices. The spectra also provide the first detection of a DAB white dwarf in a cataclysmic variable. By modelling its optical spectrum we estimate a white dwarf temperature of 30 000 ± 5000 K. By combining the results of modelling the white dwarf eclipse from ULTRACAM light curves with those obtained by simultaneously fitting the emission- and absorption-line radial velocity curves and I-band ellipsoidal light curves, we measure the stellar masses to be M1 = 0.87 ± 0.09 M⊙ and M2 = 0.47 ± 0.05 M⊙ for the white dwarf and the M dwarf, respectively, and an inclination of the orbital plane of i ≈ 79°. A radius of 0.0103 ± 0.0007 R⊙ is obtained for the white dwarf. The secondary star in HS 0220+0603 is likely too cool and undersized for its mass.

  19. PRECISION PHOTOMETRIC MONITORING OF VERY LOW MASS {sigma} ORIONIS CLUSTER MEMBERS: VARIABILITY AND ROTATION AT A FEW Myr

    SciTech Connect

    Cody, Ann Marie; Hillenbrand, Lynne A.

    2010-12-15

    We present high-precision photometry on 107 variable low-mass stars and brown dwarfs in the {approx}3 Myr {sigma} Orionis open cluster. We have carried out I-band photometric monitoring within two fields, encompassing 153 confirmed or candidate members of the low-mass cluster population, from 0.02 to 0.5 M {sub sun}. We are sensitive to brightness changes on timescales from 10 minutes to two weeks with amplitudes as low as 0.004 mag, and find variability on these timescales in nearly 70% of cluster members. We identify both periodic and aperiodic modes of variability, as well as semi-periodic rapid fading events that are not accounted for by the standard explanations of rotational modulation of surface features or accretion. We have incorporated both optical and infrared color data to uncover trends in variability with mass and circumstellar disks. While the data confirm that the lowest-mass objects (M < 0.2 M {sub sun}) rotate more rapidly than the 0.2-0.5 M {sub sun} members, they do not support a direct connection between rotation rate and the presence of a disk. Finally, we speculate on the origin of irregular variability in cluster members with no evidence for disks or accretion.

  20. Evaluation of a variable dose acquisition technique for microcalcification and mass detection in digital breast tomosynthesis

    SciTech Connect

    Das, Mini; Gifford, Howard C.; O'Connor, J. Michael; Glick, Stephen J.

    2009-06-15

    In this article the authors evaluate a recently proposed variable dose (VD)-digital breast tomosynthesis (DBT) acquisition technique in terms of the detection accuracy for breast masses and microcalcification (MC) clusters. With this technique, approximately half of the total dose is used for one center projection and the remaining dose is split among the other tomosynthesis projection views. This acquisition method would yield both a projection view and a reconstruction view. One of the aims of this study was to evaluate whether the center projection alone of the VD acquisition can provide equal or superior MC detection in comparison to the 3D images from uniform dose (UD)-DBT. Another aim was to compare the mass-detection capabilities of 3D reconstructions from VD-DBT and UD-DBT. In a localization receiver operating characteristic (LROC) observer study of MC detection, the authors compared the center projection of a VD acquisition scheme (at 2 mGy dose) with detector pixel size of 100 {mu}m with the UD-DBT reconstruction (at 4 mGy dose) obtained with a voxel size of 100 {mu}m. MCs with sizes of 150 and 180 {mu}m were used in the study, with each cluster consisting of seven MCs distributed randomly within a small volume. Reconstructed images in UD-DBT were obtained from a projection set that had a total of 4 mGy dose. The current study shows that for MC detection, using the center projection alone of VD acquisition scheme performs worse with area under the LROC curve (A{sub L}) of 0.76 than when using the 3D reconstructed image using the UD acquisition scheme (A{sub L}=0.84). A 2D ANOVA found a statistically significant difference (p=0.038) at a significance level of 0.05. In the current study, although a reconstructed image was also available using the VD acquisition scheme, it was not used to assist the MC detection task which was done using the center projection alone. In the case of evaluation of detection accuracy of masses, the reconstruction with VD-DBT (A

  1. Relationship among environmental quality variables, housing variables, and residential needs: a secondary analysis of the relationship among indoor, outdoor, and personal air (RIOPA) concentrations database

    NASA Astrophysics Data System (ADS)

    Garcia, Fausto; Shendell, Derek G.; Madrigano, Jaime

    2016-08-01

    Retrospective descriptive secondary analyses of data from relationships of indoor, outdoor, and personal air (RIOPA) study homes (in Houston, Texas; Los Angeles County, California; and, Elizabeth, New Jersey May 1999-February 2001) were conducted. Data included air exchange rates, associations between indoor and outdoor temperature and humidity, and calculated apparent temperature and humidex. Analyses examined if study homes provided optimum thermal comfort for residents during both heating and cooling seasons when compared to current American Society of Heating, Refrigerating and Air Conditioning Engineers (ASHRAE) Standards 62/62.1 and 55. Results suggested outdoor temperature, humidex, and apparent temperature during the cooling season potentially served as indicators of indoor personal exposure to parameters of thermal comfort. Outdoor temperatures, humidex, and apparent temperature during the cooling season had statistically significant predictive abilities in predicting indoor temperature. During the heating season, only humidex in Texas and combined data across study states were statistically significant, but with weaker to moderate predicative ability. The high degree of correlation between outdoor and indoor environmental variables provided support for the validity of epidemiologic studies of weather relying on temporal comparisons. Results indicated most RIOPA study residents experienced thermal comfort; however, many values indicated how several residents may have experienced some discomfort depending on clothing and indoor activities. With climate change, increases in temperature are expected, with more days of extreme heat and humidity and, potentially harsher, longer winters. Homes being built or modernized should be created with the appropriate guidelines to provide comfort for residents daily and in extreme weather events.

  2. The potential impacts of climate variability and change on air pollution-related health effects in the United States.

    PubMed Central

    Bernard, S M; Samet, J M; Grambsch, A; Ebi, K L; Romieu, I

    2001-01-01

    Climate change may affect exposures to air pollutants by affecting weather, anthropogenic emissions, and biogenic emissions and by changing the distribution and types of airborne allergens. Local temperature, precipitation, clouds, atmospheric water vapor, wind speed, and wind direction influence atmospheric chemical processes, and interactions occur between local and global-scale environments. If the climate becomes warmer and more variable, air quality is likely to be affected. However, the specific types of change (i.e., local, regional, or global), the direction of change in a particular location (i.e., positive or negative), and the magnitude of change in air quality that may be attributable to climate change are a matter of speculation, based on extrapolating present understanding to future scenarios. There is already extensive evidence on the health effects of air pollution. Ground-level ozone can exacerbate chronic respiratory diseases and cause short-term reductions in lung function. Exposure to particulate matter can aggravate chronic respiratory and cardiovascular diseases, alter host defenses, damage lung tissue, lead to premature death, and possibly contribute to cancer. Health effects of exposures to carbon monoxide, sulfur dioxide, and nitrogen dioxide can include reduced work capacity, aggravation of existing cardiovascular diseases, effects on pulmonary function, respiratory illnesses, lung irritation, and alterations in the lung's defense systems. Adaptations to climate change should include ensuring responsiveness of air quality protection programs to changing pollution levels. Research needs include basic atmospheric science work on the association between weather and air pollutants; improving air pollution models and their linkage with climate change scenarios; and closing gaps in the understanding of exposure patterns and health effects. PMID:11359687

  3. The potential impacts of climate variability and change on air pollution-related health effects in the United States.

    PubMed

    Bernard, S M; Samet, J M; Grambsch, A; Ebi, K L; Romieu, I

    2001-05-01

    Climate change may affect exposures to air pollutants by affecting weather, anthropogenic emissions, and biogenic emissions and by changing the distribution and types of airborne allergens. Local temperature, precipitation, clouds, atmospheric water vapor, wind speed, and wind direction influence atmospheric chemical processes, and interactions occur between local and global-scale environments. If the climate becomes warmer and more variable, air quality is likely to be affected. However, the specific types of change (i.e., local, regional, or global), the direction of change in a particular location (i.e., positive or negative), and the magnitude of change in air quality that may be attributable to climate change are a matter of speculation, based on extrapolating present understanding to future scenarios. There is already extensive evidence on the health effects of air pollution. Ground-level ozone can exacerbate chronic respiratory diseases and cause short-term reductions in lung function. Exposure to particulate matter can aggravate chronic respiratory and cardiovascular diseases, alter host defenses, damage lung tissue, lead to premature death, and possibly contribute to cancer. Health effects of exposures to carbon monoxide, sulfur dioxide, and nitrogen dioxide can include reduced work capacity, aggravation of existing cardiovascular diseases, effects on pulmonary function, respiratory illnesses, lung irritation, and alterations in the lung's defense systems. Adaptations to climate change should include ensuring responsiveness of air quality protection programs to changing pollution levels. Research needs include basic atmospheric science work on the association between weather and air pollutants; improving air pollution models and their linkage with climate change scenarios; and closing gaps in the understanding of exposure patterns and health effects.

  4. The potential impacts of climate variability and change on air pollution-related health effects in the United States.

    PubMed

    Bernard, S M; Samet, J M; Grambsch, A; Ebi, K L; Romieu, I

    2001-05-01

    Climate change may affect exposures to air pollutants by affecting weather, anthropogenic emissions, and biogenic emissions and by changing the distribution and types of airborne allergens. Local temperature, precipitation, clouds, atmospheric water vapor, wind speed, and wind direction influence atmospheric chemical processes, and interactions occur between local and global-scale environments. If the climate becomes warmer and more variable, air quality is likely to be affected. However, the specific types of change (i.e., local, regional, or global), the direction of change in a particular location (i.e., positive or negative), and the magnitude of change in air quality that may be attributable to climate change are a matter of speculation, based on extrapolating present understanding to future scenarios. There is already extensive evidence on the health effects of air pollution. Ground-level ozone can exacerbate chronic respiratory diseases and cause short-term reductions in lung function. Exposure to particulate matter can aggravate chronic respiratory and cardiovascular diseases, alter host defenses, damage lung tissue, lead to premature death, and possibly contribute to cancer. Health effects of exposures to carbon monoxide, sulfur dioxide, and nitrogen dioxide can include reduced work capacity, aggravation of existing cardiovascular diseases, effects on pulmonary function, respiratory illnesses, lung irritation, and alterations in the lung's defense systems. Adaptations to climate change should include ensuring responsiveness of air quality protection programs to changing pollution levels. Research needs include basic atmospheric science work on the association between weather and air pollutants; improving air pollution models and their linkage with climate change scenarios; and closing gaps in the understanding of exposure patterns and health effects. PMID:11359687

  5. Performance of Thermal Mass Flow Meters in a Variable Gravitational Environment

    NASA Technical Reports Server (NTRS)

    Brooker, John E.; Ruff, Gary A.

    2004-01-01

    The performance of five thermal mass flow meters, MKS Instruments 179A and 258C, Unit Instruments UFM-8100, Sierra Instruments 830L, and Hastings Instruments HFM-200, were tested on the KC-135 Reduced Gravity Aircraft in orthogonal, coparallel, and counterparallel orientations relative to gravity. Data was taken throughout the parabolic trajectory where the g-level varied from 0.01 to 1.8 times normal gravity. Each meter was calibrated in normal gravity in the orthogonal position prior to flight followed by ground testing at seven different flow conditions to establish a baseline operation. During the tests, the actual flow rate was measured independently using choked-flow orifices. Gravitational acceleration and attitude had a unique effect on the performance of each meter. All meters operated within acceptable limits at all gravity levels in the calibrated orthogonal position. However, when operated in other orientations, the deviations from the reference flow became substantial for several of the flow meters. Data analysis indicated that the greatest source of error was the effect of orientation, followed by the gravity level. This work emphasized that when operating thermal flow meters in a variable gravity environment, it is critical to orient the meter in the same direction relative to gravity in which it was calibrated. Unfortunately, there was no test in normal gravity that could predict the performance of a meter in reduced gravity. When operating in reduced gravity, all meters indicated within 5 percent of the full scale reading at all flow conditions and orientations.

  6. Influence of topography on mountain permafrost distribution through variable air and ground surface lapse rates, Yukon Territory, Canada

    NASA Astrophysics Data System (ADS)

    Lewkowicz, A. G.; Bonnaventure, P. P.

    2009-04-01

    The objective of this study is to evaluate the variability in air and ground surface temperatures in relation to topography and elevation in the southern half of the Yukon Territory, Canada. In particular, we explore the importance of persistent winter and nocturnal summer atmospheric temperature inversions on the variability in mountain climates in the region. Since permafrost is partially climatically controlled, this variability may impact its distribution. Five study areas from 60 °-65 °N are discussed: Johnson's Crossing, the Sa Dena Hes mine site, Faro, Keno and Dawson. In each area, 10-12 monitoring sites, selected to cover a range of elevations, aspects and topographic situations (e.g. ridge crests, valley bottoms, long slopes), operated in 2007-2008. They extended from below to above tree-line in and in total covered an elevation range of 300-2000 m a.s.l.. At each monitoring site, Onset Hobo Pro loggers were used to measure hourly shielded air temperature, ground surface temperature, and temperature near the top of permafrost (if present). In addition, site snow depths were monitored using miniature iButton temperature loggers arranged in a vertical array above the ground surface. Results can be described by individual area and collectively for the entire region. When grouped together, summer air temperatures show normal lapse rates that in July are close to the standard environmental lapse rate of -6.5 °C/km. In contrast, winter lapse rates are strongly inverted, with an increase of +11 °C/km in January 2008. The combined effect of these two trends cause air temperature amplitudes to decrease with elevation and a normal, but much reduced, lapse rate of about -4 °C/km. Temperatures at the ground surface in summer follow the air temperature trend within the same season and exhibit a normal lapse rate (-5 °C/km) with a higher degree of scatter that relates to the buffering effect of vegetation and the substrate. In winter, the variable effect of snow

  7. Health impact assessment of traffic-related air pollution at the urban project scale: influence of variability and uncertainty.

    PubMed

    Chart-Asa, Chidsanuphong; Gibson, Jacqueline MacDonald

    2015-02-15

    This paper develops and then demonstrates a new approach for quantifying health impacts of traffic-related particulate matter air pollution at the urban project scale that includes variability and uncertainty in the analysis. We focus on primary particulate matter having a diameter less than 2.5 μm (PM2.5). The new approach accounts for variability in vehicle emissions due to temperature, road grade, and traffic behavior variability; seasonal variability in concentration-response coefficients; demographic variability at a fine spatial scale; uncertainty in air quality model accuracy; and uncertainty in concentration-response coefficients. We demonstrate the approach for a case study roadway corridor with a population of 16,000, where a new extension of the University of North Carolina (UNC) at Chapel Hill campus is slated for construction. The results indicate that at this case study site, health impact estimates increased by factors of 4-9, depending on the health impact considered, compared to using a conventional health impact assessment approach that overlooks these variability and uncertainty sources. In addition, we demonstrate how the method can be used to assess health disparities. For example, in the case study corridor, our method demonstrates the existence of statistically significant racial disparities in exposure to traffic-related PM2.5 under present-day traffic conditions: the correlation between percent black and annual attributable deaths in each census block is 0.37 (t(114)=4.2, p<0.0001). Overall, our results show that the proposed new campus will cause only a small incremental increase in health risks (annual risk 6×10(-10); lifetime risk 4×10(-8)), compared to if the campus is not built. Nonetheless, the approach we illustrate could be useful for improving the quality of information to support decision-making for other urban development projects.

  8. PAH and PCB in the Baltic -- A budget approach including fluxes, occurrence and concentration variability in air, suspended and settling particulates in water, surface sediments and river water

    SciTech Connect

    Broman, D.; Axelman, J.; Bandh, C.; Ishaq, R.; Naef, C.; Pettersen, H.; Zebuehr, Y.

    1995-12-31

    In order to study the fate and occurrence of two groups of hydrophobic compounds in the Baltic aquatic environment a large number of samples were collected from the southern Baltic proper to the northern Bothnian Bay for the analyses of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs). The following sample matrices were collected; bottom surface sediments (0--1 cm, collected with gravity corer), settling particulate matter (collected with sediment traps), open water samples and over water samples (suspended particulates and dissolved fraction sampled by filtration) and air samples (aerosols and vapor phase sampled by filtration). All samples (except over water and air) were collected at open sea in the Baltic. The analyses results have been used to make a model approach on the whole Baltic and to elucidate different aspects of the behavior of PAHs and PCBs in the Baltic, such as the occurrence of the compounds in water and sediment, the total content as well as the concentration variabilities over such a large geographical area, Further, the data on settling particulate matter as well as the air concentration data were used to estimate the total fluxes of PAHs and PCBs to the bottoms of the Baltic and t o the total water area of the Baltic, respectively. Further, data on the PAH and PCB content in river water from four major rivers provides rough estimates of the riverine input to the Baltic. The dynamics of PAHs and PCBs within the water mass have also been studied in terms of settling velocities and residence times in the water mass for these type of compounds in the open Baltic.

  9. Long term mass changes and interannual variability in the Canadian Archipelago and Gulf of Alaska from GRACE

    NASA Astrophysics Data System (ADS)

    Harig, C.; Simons, F. J.

    2015-12-01

    The mass transfer from land ice to the oceans is a major contributor to global sea-level rise. The glaciated regions of the Canadian Archipelago and the Gulf of Alaska are the next largest ice mass loss contributors outside of the Greenland and Antarctic ice sheets. Here we estimate the ice mass change of these regions since 2003 using time-variable gravity data from the GRACE mission. We employ an estimation technique based on spherical Slepian localization functions. These Slepian functions form a sparse set of orthogonal basis functions for a specific region and maximize the signal-to-noise levels of the gravity fields, making them excellent candidates to analyze regional data on the sphere.Between 2003 and 2012 Ellesmere Island lost mass (-38 Gt/yr) at an accelerating rate (-8 Gt/yr2), while Baffin Island lost mass at a lower rate (-22 Gt/yr) with very low acceleration. During this time, interannual variations were well described by an average seasonal cycle. Since 2013 ice mass in Ellesmere and Baffin islands, as well as Greenland, have diverged from their long term mass change trends. During the summer of 2013 these areas had the lowest recorded melt since the start of the GRACE mission. Through the end of 2014, the difference between the observed mass and the extrapolated long term trend for Greenland grew to over 500 gigatons. In contrast to the Canadian Archipelago, the Gulf of Alaska region has average seasonal mass variations four times larger per unit area and greater variability from year to year. Recent years of below average mass loss have lowered the average mass loss rate from previous estimates.

  10. Simulated Future Air Temperature and Precipitation Climatology and Variability in the Mediterranean Basin by Using Downscaled Global Climate Model Outputs

    NASA Astrophysics Data System (ADS)

    Ozturk, Tugba; Pelin Ceber, Zeynep; Türkeş, Murat; Kurnaz, M. Levent

    2014-05-01

    The Mediterranean Basin is one of the regions that shall be affected most by the impacts of the future climate changes on temperature regime including changes in heat waves intensity and frequency, seasonal and interannual precipitation variability including changes in summer dryness and drought events, and hydrology and water resources. In this study, projected future changes in mean air temperature and precipitation climatology and inter-annual variability over the Mediterranean region were simulated. For performing this aim, the future changes in annual and seasonal averages for the future period of 2070-2100 with respect to the period from 1970 to 2000 were investigated. Global climate model outputs of the World Climate Research Program's (WCRP's) Coupled Model Intercomparison Project Phase 3 (CMIP3) multi-model dataset were used. SRES A2, A1B and B1 emission scenarios' outputs of the Intergovernmental Panel on Climate Change (IPCC) were used in future climate model projections. Future surface mean air temperatures of the larger Mediterranean basin increase mostly in summer and least in winter, and precipitation amounts decreases in all seasons at almost all parts of the basin. Future climate signals for surface air temperatures and precipitation totals will be much larger than the inter-model standard deviation. Inter-annual temperature variability increases evidently in summer season and decreases in the northern part of the domain in the winter season, while precipitation variability increases in almost all parts of domain. Probability distribution functions are found to be shifted and flattened for future period compared to reference period. This indicates that occurrence frequency and intensity of extreme weather conditions will increase in the future period. This work has been supported by Bogazici University BAP under project number 7362. One of the authors (MLK) was partially supported by Mercator-IPC Fellowship Program.

  11. Inclusive B-meson production at the LHC in the general-mass variable-flavor-number scheme

    SciTech Connect

    Kniehl, B. A.; Kramer, G.; Schienbein, I.

    2011-11-01

    We calculate the next-to-leading-order cross section for the inclusive production of B mesons in pp collisions in the general-mass variable-flavor-number scheme, an approach that takes into account the finite mass of the b quarks. We use realistic evolved nonperturbative fragmentation functions obtained from fits to e{sup +}e{sup -} data and compare our results for the transverse-momentum and rapidity distributions at a center-of-mass energy of 7 TeV with recent data from the CMS Collaboration at the CERN LHC. We find good agreement, in particular, at large values of p{sub T}.

  12. A comparison of surface air temperature variability in three 1000-Yr. coupled ocean-atmosphere model integrations

    SciTech Connect

    Stouffer, R.J.; Hegerl, G.; Tett, S.

    2000-02-01

    This study compares the variability of surface air temperature in three long coupled ocean-atmosphere general circulation model integrations. It is shown that the annual mean climatology of the surface air temperatures (SAT) in all three models is realistic and the linear trends over the 1,000-yr integrations are small over most areas of the globe. Second, although there are notable differences among the models, the models' SAT variability is fairly realistic on annual to decadal timescales, both in terms of the geographical distribution and of the global mean values. A notable exception is the poor simulation of observed tropical Pacific variability. In the HadCM2 model, the tropical variability is overestimated, while in the GFDL and HAM3L models, it is underestimated. Also, the ENSO-related spectral peak in the globally averaged observed SAT differs from that in any of the models. The relatively low resolution required to integrate models for long time periods inhibits the successful simulation of the variability in this region. On timescales longer than a few decades, the largest variance in the models is generally located near sea ice margins in high latitudes, which are also regions of deep oceanic convection and variability related to variations in the thermohaline circulation. However, the exact geographical location of these maxima varies from model to model. The preferred patterns of interdecadal variability that are common to all three coupled models can be isolated by computing empirical orthogonal functions (EOFs) of all model data simultaneously using the common EOF technique. A comparison of the variance each model associated with these common EOF patterns shows that the models generally agree on the most prominent patterns of variability. However, the amplitudes of the dominant models of variability differ to some extent between the models and between the models and observations. For example, two of the models have a mode with relatively large

  13. On the association between daily mortality and air mass types in Athens, Greece during winter and summer

    NASA Astrophysics Data System (ADS)

    Kassomenos, Pavlos A.; Gryparis, Alexandros; Katsouyanni, Klea

    2007-03-01

    In this study, we examined the short-term effects of air mass types on mortality in Athens, Greece. An objective air mass types classification was used, based on meteorological parameters measured at the surface. Mortality data were treated with generalized additive models (GAM) and extending Poisson regression, using a LOESS smoother to control for the confounding effects of seasonal patterns, adjusting also for temperature, long-term trends, day of the week, and ambient particle concentrations. The introduced air mass classification explains the daily variation of mortality to a statistically significant degree. The highest daily mortality was observed on days characterized by southerly flow conditions for both the cold (increase in relative risk for mortality 9%; with a 95% confidence interval: 3-14%), and the warm period (7%; with a 95% confidence interval: 2-13%) of the year. The northeasterly flow is associated with the lowest mortality. Effects on mortality, independent of temperature, are observed mainly for lag 0 during the cold period, but persist longer during the warm period. Not adjusting for temperature and/or ambient particle levels slightly alters the results, which then reflect the known temperature and particle effects, already reported in the literature. In conclusion, we find that air mass types have independent effects on mortality for both the cold and warm season and may be used to predict weather-related adverse health effects.

  14. Spatial and seasonal variability of the air-sea equilibration timescale of carbon dioxide

    NASA Astrophysics Data System (ADS)

    Jones, Daniel; Ito, Takamitsu; Takano, Yohei; Hsu, Wei-Ching

    2014-05-01

    The exchange of carbon dioxide between the ocean and the atmosphere tends to bring near-surface waters toward equilibrium by reducing the partial pressure gradient across the air-water interface. However, the equilibration process is not instantaneous; in general there is a lag between forcing and response. The timescale of air-sea equilibration depends on several factors involving the depth of the mixed layer, temperature, salinity, wind speed, and carbonate chemistry. In this work, we use a suite of observational datasets to generate climatological and seasonal composite maps of the air-sea equilibration timescale. The relaxation timescale exhibits considerable spatial and seasonal variations, which are largely set by changes in mixed layer depth and wind speed. The net effect is dominated by the mixed layer depth; the gas exchange velocity and carbonate chemistry parameters only provide partial compensation. Broadly speaking, the adjustment timescale tends to increase with latitude. We compare the observationally-derived air-sea gas exchange timescale with a model-derived surface residence time and a data-derived horizontal transport timescale, which allows us to define two non-dimensional metrics of gas exchange efficiency. These parameters highlight the Southern Ocean, equatorial Pacific, and North Atlantic as regions of inefficient air-sea equilibration where carbon anomalies are likely to form and persist. The efficiency parameters presented here can serve as simple tools for understanding regional air-sea disequilibrium in both observations and models. This work is distributed under the Creative Commons Attribution 3.0 Unported License together with an author copyright. This license does not conflict with the regulations of the Crown Copyright.

  15. Embedded computer controlled premixing inline injection system for air-assisted variable-rate sprayers

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Improvements to reduce chemical waste and environmental pollution for variable-rate sprayers used in orchards and ornamental nurseries require inline injection techniques. A microprocessor controlled premixing inline injection system implementing a ceramic piston chemical metering pump and two small...

  16. Association of Body Mass Index with Depression, Anxiety and Suicide—An Instrumental Variable Analysis of the HUNT Study

    PubMed Central

    Bjørngaard, Johan Håkon; Carslake, David; Lund Nilsen, Tom Ivar; Linthorst, Astrid C. E.; Davey Smith, George; Gunnell, David; Romundstad, Pål Richard

    2015-01-01

    Objective While high body mass index is associated with an increased risk of depression and anxiety, cumulative evidence indicates that it is a protective factor for suicide. The associations from conventional observational studies of body mass index with mental health outcomes are likely to be influenced by reverse causality or confounding by ill-health. In the present study, we investigated the associations between offspring body mass index and parental anxiety, depression and suicide in order to avoid problems with reverse causality and confounding by ill-health. Methods We used data from 32,457 mother-offspring and 27,753 father-offspring pairs from the Norwegian HUNT-study. Anxiety and depression were assessed using the Hospital Anxiety and Depression Scale and suicide death from national registers. Associations between offspring and own body mass index and symptoms of anxiety and depression and suicide mortality were estimated using logistic and Cox regression. Causal effect estimates were estimated with a two sample instrument variable approach using offspring body mass index as an instrument for parental body mass index. Results Both own and offspring body mass index were positively associated with depression, while the results did not indicate any substantial association between body mass index and anxiety. Although precision was low, suicide mortality was inversely associated with own body mass index and the results from the analysis using offspring body mass index supported these results. Adjusted odds ratios per standard deviation body mass index from the instrumental variable analysis were 1.22 (95% CI: 1.05, 1.43) for depression, 1.10 (95% CI: 0.95, 1.27) for anxiety, and the instrumental variable estimated hazard ratios for suicide was 0.69 (95% CI: 0.30, 1.63). Conclusion The present study’s results indicate that suicide mortality is inversely associated with body mass index. We also found support for a positive association between body mass index

  17. Caucasian children's fat mass: routine anthropometry v. air-displacement plethysmography.

    PubMed

    Michels, Nathalie; Huybrechts, Inge; Bammann, Karin; Lissner, Lauren; Moreno, Luis; Peeters, Maarten; Sioen, Isabelle; Vanaelst, Barbara; Vyncke, Krishna; De Henauw, Stefaan

    2013-04-28

    The present paper will use fat mass percentage (FM%) obtained via BOD POD® air-displacement plethysmography (FMADP%) to examine the relative validity of (1) anthropometric measurements/indices and (2) of FM% assessed with equations (FMeq%) based on skinfold thickness and bioelectrical impedance (BIA). In 480 Belgian children (aged 5-11 years) weight, height, skinfold thickness (triceps and subscapular), body circumferences (mid-upper arm, waist and hip), foot-to-foot BIA (Tanita®) and FMADP% were measured. Anthropometric measurements and calculated indices were compared with FMADP%. Next, published equations were used to calculate FMeq% using impedance (equations of Tanita®, Tyrrell, Shaefer and Deurenberg) or skinfold thickness (equations of Slaughter, Goran, Dezenberg and Deurenberg). Both indices and equations performed better in girls than in boys. For both sexes, the sum of skinfold thicknesses resulted in the highest correlation with FMADP%, followed by triceps skinfold, arm fat area and subscapular skinfold. In general, comparing FMeq% with FMADP% indicated mostly an age and sex effect, and an increasing underestimation but less dispersion with increasing FM%. The Tanita® impedance equation and the Deurenberg skinfold equation performed the best, although none of the used equations were interchangeable with FMADP%. In conclusion, the sum of triceps and subscapular skinfold thickness is recommended as marker of FM% in the absence of specialised technologies. Nevertheless, the higher workload, cost and survey management of an immobile device like the BOD POD® remains justified.

  18. Background NO/sub x/ mixing ratios in air masses over the North Atlantic ocean

    SciTech Connect

    Helas, G.; Warneck, P.

    1981-08-20

    A chemiluminescence analyzer was used to measure NO/sub x/ mixing ratios at the west coast of Ireland. Two measurement modes allowed the determination of NO and NO/sub x/ = NO+NO/sub 2/. In a third mode using a molybdenum converter, higher signals were observed than was in the second mode indicating that nitrogen compounds other than NO+NO/sub 2/ are registered. They are denoted 'excess NO/sub x/'. The average NO/sub 2/ mixing ratio for a week period was 101 +- 87 pptv. In pure marine air masses identified by means of trajectory calculations, the NO/sub 2/ mixing ratios were lower and exhibited in addition a diurnal variation with nighttime values of 37 +- 6 pptv and average values of 87 +- 47 pptv. Possible origins of the diurnal variation are discussed. For such conditions, the NO mixing ratio generally was unmeasurably small, certainly less than 10 pptv. The excess NO/sub x/ is also higher during the day compared with nighttime values of about 70 pptv. Further studies are required to identify the compounds involved.

  19. Analyzing consistency of interannual variability in air-sea sensible and latent heat fluxes in CMIP5 model simulations

    NASA Astrophysics Data System (ADS)

    Serykh, Ilya; Gulev, Sergey

    2015-04-01

    Surface turbulent heat fluxes are critically important in climate model experiments, since they represent a language of communication of the ocean and atmosphere. Interannual variability of surface turbulent heat fluxes is believed to be the major contributor to the changes in the ocean surface heat balance, at least in mid latitudes. Being relatively well assessed and validated in reanalyses, surface turbulent heat fluxes always were of a lesser attention in diagnostics of climate model experiments. We analysed interannual variability of sensible and latent heat fluxes in historical climate simulations with several CMIP5 models. Variability in surface turbulent sensible and latent heat fluxes in model simulations has been analysed during several last decades (from 1950s to 2005) with the emphasis on different scales of variability (short-term, interannual, decadal). At all scales has been found a little consistency between the changes in turbulent surface fluxes diagnosed by reanalyses and blended data sets (OA-FLUX) on one hand and model simulations on the other. Furthermore, some models (e.g. ECHAM, IPSL) surprisingly demonstrate large regions with negative correlations between sensible and latent heat fluxes, which is not the case in observational data sets (reanalyses and OAFLUX). Interestingly, variability in air temperature and surface humidity (which could be potentially considered as the reason for autocorrelation between sensible and latent fluxes) demonstrates consistency with each other at most scales. Further we discuss potential reasons for the discovered phenomenon.

  20. Time scales of the European surface air temperature variability: The role of the 7-8 year cycle

    NASA Astrophysics Data System (ADS)

    Jajcay, Nikola; Hlinka, Jaroslav; Kravtsov, Sergey; Tsonis, Anastasios A.; Paluš, Milan

    2016-01-01

    Air temperature variability on different time scales exhibits recurring patterns and quasi-oscillatory phenomena. Climate oscillations with the period about 7-8 years have been observed in many instrumental records in Europe. Although these oscillations are weak if considering their amplitude, they might have nonnegligible influence on temperature variability on shorter time scales due to cross-scale interactions recently observed by Paluš (2014). In order to quantify the cross-scale influence, we propose a simple conditional mean approach which estimates the effect of the cycle with the period close to 8 years on the amplitude of the annual cycle in surface air temperature (SAT) in the range 0.7-1.4°C and the effect on the overall variability of the SAT anomalies (SATA) leads to the changes 1.5-1.7°C in the annual SATA means. The strongest effect in the winter SATA means reaches 4-5°C in central European station and reanalysis data.

  1. New Directions: Questions surrounding suspended particle mass used as a surrogate for air quality and for regulatory control of ambient urban air pollution

    NASA Astrophysics Data System (ADS)

    Hoare, John L.

    2014-07-01

    The original choice of particulate matter mass (PM) as a realistic surrogate for gross air pollution has gradually evolved into routine use nowadays of epidemiologically-based estimates of the monetary and other benefits expected from regulating urban air quality. Unfortunately, the statistical associations facilitating such calculations usually are based on single indices of air pollution whereas the health effects themselves are more broadly based causally. For this and other reasons the economic benefits of control tend to be exaggerated. Primarily because of their assumed inherently inferior respirability, particles ≥10 μm are generally excluded from such considerations. Where the particles themselves are chemically heterogeneous, as in an urban context, this may be inappropriate. Clearly all air-borne particles, whether coarse or fine, are susceptible to inhalation. Hence, the possibility exists for any adhering potentially harmful semi-volatile substances to be subsequently de-sorbed in vivo thereby facilitating their transport deeper into the lungs. Consequently, this alone may be a sufficient reason for including rather than rejecting during air quality monitoring the relatively coarse 10-100 μm particle fraction, ideally in conjunction with routine estimation of the gaseous co-pollutants thereby facilitating a multi-pollutant approach apropos regulation.

  2. Variations of the glacio-marine air mass front in West Greenland through water vapor isotopes

    NASA Astrophysics Data System (ADS)

    Kopec, B. G.; Lauder, A. M.; Posmentier, E. S.; Feng, X.

    2012-12-01

    While the isotopic distribution of precipitation has been widely used for research in hydrology, paleoclimatology, and ecology for decades, intensive isotopic studies of atmospheric water vapor has only recently been made possible by spectral-based technology. New instrumentation based on this technology opens up many opportunities to investigate short-term atmospheric dynamics involving the water cycle and moisture transport. We deployed a Los Gatos Water Vapor Isotope Analyzer (WVIA) at Kangerlussuaq, Greenland from July 21 to August 15, and measured the water vapor concentration and its isotopic ratios continuously at 10s intervals. A Danish Meteorological Institute site is located about 1 km from the site of the deployment, and meteorological data is collected at 30 min intervals. During the observation period, the vapor concentration of the ambient air ranges from 5608.4 to 11189.4 ppm; dD and d18O range from -254.5 to -177.7 ‰ and -34.2 to -23.2 ‰, respectively. The vapor content (dew point) and the isotopic ratios are both strongly controlled by the wind direction. The easterly winds are associated with dry, isotopically depleted air masses formed over the glacier, while westerly winds are associated with moist and isotopically enriched air masses from the marine/fjord surface. This region typically experiences katabatic winds off of the ice sheet to the east. However, during some afternoons, the wind shifts 180 degrees, blowing off the fjord to the west. This wind switch marks the onset of a sea breeze, and significant isotopic enrichment results. Enrichment in deuterium is up to 60 ‰ with a mean of 15‰, and oxygen-18 is enriched by 3‰ on average and up to 8 ‰. Other afternoons have no change in wind, and only small changes in humidity and vapor isotopic ratios. The humidity and isotopic variations suggest the local atmosphere circulation is dominated by relatively high-pressure systems above the cold glaciers and cool sea surface, and diurnal

  3. Screening of Different Media and Substrates for Cultural Variability and Mass Culture of Arthrobotrys dactyloides Drechsler.

    PubMed

    Kumar, D; Singh, K P; Jaiswal, R K

    2005-12-01

    Variability in growth and sporulation of five isolates of Arthrobotrys dactyloides was studied on five agar, 6 bran and 5 grain media. Potato dextrose agar (PDA) supported maximum growth of isolate A, C and E, while growth of isolate B and D was significantly lower on this medium. On Czapek's agar and yeast glucose agar media the differentiation in the isolates in relation to growth was poor than PDA. The other two media showed much poorer differentiation. On Czapek's agar medium, sporulation was recorded in isolate B only, whereas other isolates showed rare sporulation. Among the bran media, pea bran agar medium supported maximum growth of all the isolates except isolate B. Gram and rice bran agar media were next best. However, the growth of isolate B on the gram bran agar medium was more or less equal as other isolates. On pigeon pea bran agar medium, isolate E failed to grow while other isolates recorded poor growth. On lentil bran agar medium, only isolate B and D recorded little growth, whereas other isolates failed to grow. All the isolates recorded good sporulation on bran agar media except pigeon pea and lentil bran agar media. The grain agar media supported moderate to very good growth of all the isolates. In general isolate B remained slow growing on these media except gram grain and sorghum grain agar media on which growth of this isolate was comparable to other isolates. Sporulation in general, was good on all the grain agar media. Among different substrates screened, barley grain and pea bran were found superior to others for mass culture of isolate A of A. dactyloides.

  4. Time-Variable Gravity Signal due to Extratropic Pacific Water Mass Redistribution

    NASA Technical Reports Server (NTRS)

    Chao, B. F.; Boy, J. -P.; Cox, C. M.; Au, A. Y.

    2003-01-01

    Using the satellite-laser-ranging (SLR) data, Cox and Chao [2002] reported the detection of a large post-1998 anomaly (in the form of a positive jump) in the time series of Earth s lowest-degree gravity harmonic 52, or the dynamic oblateness. Among several groups now examining the mass redistribution in the global geophysical fluids in search of the cause(s), we report here a temporally coinciding anomalies found in the extratropic north + south Pacific basins. Clearly seen in the leading EOFPC mode for extratropic Pacific, these anomalies occurred in sea-surface height, sea-surface temperature, and temperature- and salinity-depth profiles. We based our analysis on two different data sources: TOPEX/Poseidon altimetry, and the ECCO ocean general circulation model output assimilating T/P data. The magnitude of these changes, when converted to equivalent J2 change, appears to be a few times too small to explain the observed J2 directly. These findings, and the fact that the anomalies occurred following the strong 1997-98 El Nino, suggest strong geophysical connection of the interannual-to-decadal variation of 52 with the Pacific Decadal Oscillation (PDO) and the ultimate global-change processes that cause PDO. More work is underway, and additional independent data sources are examined, paying close attention to the fact that the J2 anomaly has been reversing back to normal since 2001. These include: (1) cryospheric contributions (melting of glaciers and ice sheets); (2) land hydrological contributions; (3) polar sea influences ( e g , via deep flow); (4) fluid flow in Earth's core; (5) time-variable gravity signals from SLR in higher harmonic degree/order, including J3,J4, (2,1), and (2,2) coefficients, considering their lower signal-to-noise ratios; (6) Earth rotation data in terms of length-of-day and polar motion.

  5. Time-variable gravity signal due to extratropic Pacific water mass redistribution

    NASA Astrophysics Data System (ADS)

    Chao, B. F.; Boy, J.-P.; Cox, C.; Au, A.

    2003-04-01

    Using the satellite-laser-ranging (SLR) data, Cox and Chao [2002] reported the detection of a large post-1998 anomaly (in the form of a positive "jump") in the time series of Earth's lowest-degree gravity harmonic J2, or the dynamic oblateness. Among several groups now examining the mass redistribution in the global geophysical fluids in search of the cause(s), we report here a temporally coinciding anomalies found in the extratropic north + south Pacific basins. Clearly seen in the leading EOF/PC mode for extratropic Pacific, these anomalies occurred in sea-surface height, sea-surface temperature, and temperature- and salinity-depth profiles. We based our analysis on two different data sources: TOPEX/Poseidon altimetry, and the ECCO ocean general circulation model output assimilating T/P data. The magnitude of these changes, when converted to equivalent J2 change, appears to be a few times too small to explain the observed J2 directly. These findings, and the fact that the anomalies occurred following the strong 1997-98 El Nino, suggest strong geophysical connection of the interannual-to-decadal variation of J2 with the Pacific Decadal Oscillation (PDO) and the ultimate global-change processes that cause PDO. More work is underway, and additional independent data sources are examined, paying close attention to the fact that the J2 anomaly has been reversing back to "normal" since 2001. These include: (1) cryospheric contributions (melting of glaciers and ice sheets); (2) land hydrological contributions; (3) polar sea influences (e.g., via deep flow); (4) fluid flow in Earth's core; (5) time-variable gravity signals from SLR in higher harmonic degree/order, including J3, J4, (2,1), and (2,2) coefficients, considering their lower signal-to-noise ratios; (6) Earth rotation data in terms of length-of-day and polar motion.

  6. Molecular records of continental air temperature and monsoon precipitation variability in East Asia spanning the past 130,000 years

    NASA Astrophysics Data System (ADS)

    Peterse, Francien; Martínez-García, Alfredo; Zhou, Bin; Beets, Christiaan J.; Prins, Maarten A.; Zheng, Hongbo; Eglinton, Timothy I.

    2014-01-01

    Our current understanding of past changes in East Asian summer monsoon (EASM) precipitation intensity derives from several loess-paleosol sequences and oxygen isotope (δ18O) records of well-dated stalagmites. Although temperature is generally presumed to have had minimal impact on EASM records, past air temperature dynamics over East Asia are, so far, relatively poorly understood, mainly due to the lack of tools to reconstruct continental paleotemperatures. Here we report a high-resolution record of East Asian air temperature over the past 130,000 years, based on soil bacterial lipid signatures preserved in a loess-paleosol sequence from the Mangshan loess plateau in China. We find that maximum local insolation is the main driver of air temperature, although greenhouse gas concentrations and southern hemisphere climate may influence temperature at times when insolation is weak, causing a decoupling with EASM precipitation intensity. Direct comparison of our temperature record with precipitation-induced changes in past soil pH, derived from the same suite of lipids confirms this decoupling. Subsequent cross-spectral analysis of the two molecular proxy records reveals that variations in monsoon precipitation consistently lag those in air temperature throughout the whole record at the dominant precession band. The length of this lag is variable however, and increases as glaciation develops. This observation is consistent with an increasing influence of northern hemisphere ice sheets on the modulation of EASM response to insolation forcing during ice ages.

  7. The impact of mass flow and masking on the pressure drop of air filter in heavy-duty diesel engine

    NASA Astrophysics Data System (ADS)

    Hoseeinzadeh, Sepideh; Gorji-Bandpy, Mofid

    2012-04-01

    This paper presents a computational fluid dynamics (CFD) calculation approach to predict and evaluate the impact of the mass-flow inlet on the pressure drop of turbocharger`s air filtfer in heavy-duty diesel engine. The numerical computations were carried out using a commercial CFD program whereas the inlet area of the air filter consisted of several holes connected to a channel. After entering through the channel, the air passes among the holes and enters the air filter. The effect of masking holes and hydraulic diameter is studied and investigated on pressure drop. The results indicate that pressure drop increase with decreasing of hydraulic diameter and masking of the holes has considerable affect on the pressure drop.

  8. Inter-annual variability of air pollutants over East Asia: an integrated analysis using satellite, lidar and numerical model.

    NASA Astrophysics Data System (ADS)

    Yumimoto, K.; Uno, I.; Kuribayashi, M.; Miyazaki, K.; Nishizawa, T.

    2014-12-01

    Air quality in East Asia has a drastic temporal and spatial variability. The rapid economic growth in the last three decades enhanced the increase of anthropogenic emission of air pollutions, and caused deterioration of the air quality in both source and downwind regions. The unprecedented heavy PM­2.5 pollution over the central China in January 2013 records the maximum PM2.5 concentration of 996 μg/m3 and raised critical environmental issues (e.g., mortality, human health, social activity and trans-boundary transport, etc.). Recently, efforts to reduce anthropogenic emissions (e.g., emission regulations and improvements of emission factors and removal efficiencies) decelerate their growth rates. In fact, Asian SO2 emission is estimated to be reducing from 2007 [Kurokawa et al., 2013]. However, growth rates other pollutant emissions (e.g., NOx and PM10) still remain in high. To understand the life cycle of pollutants (emission, transport, reaction and deposition) and their temporal and spatial variation, an integrated analysis using observation and numerical model (chemical transport model; CTM) is useful. In this study, we installed a comprehensive observation operator system, which converts model results into observed variables, into the GEOS-Chem CTM. A long-term (2005-2013) full-chemistry simulation over East Asia was performed, and simulation results are translated to tropospheric NO2 and SO2 columns and vertical profiles of aerosol extinction coefficient equivalent to satellite measurements and in-situ lidar network observations. Combining CTM and observations, and integrating analyses of aerosols over the downwind region and their precursors over the source region will provide important insights into temporal and spatial variation of air pollutants over East Asia.

  9. Surface-air mercury fluxes across Western North America: A synthesis of spatial trends and controlling variables

    USGS Publications Warehouse

    Eckley, Chris S.; Tate, Michael T.; Lin, Che-Jen; Gustin, Mae S.; Dent, Stephen; Eagles-Smith, Collin A.; Lutz, Michelle A; Wickland, Kimberly; Wang, Bronwen; Gray, John E.; Edwards, Grant; Krabbenhoft, David P.; Smith, David

    2016-01-01

    Mercury (Hg) emission and deposition can occur to and from soils, and are an important component of the global atmospheric Hg budget. This paper focuses on synthesizing existing surface-air Hg flux data collected throughout the Western North American region and is part of a series of geographically focused Hg synthesis projects. A database of existing Hg flux data collected using the dynamic flux chamber (DFC) approach from almost a thousand locations was created for the Western North America region. Statistical analysis was performed on the data to identify the important variables controlling Hg fluxes and to allow spatiotemporal scaling. The results indicated that most of the variability in soil-air Hg fluxes could be explained by variations in soil-Hg concentrations, solar radiation, and soil moisture. This analysis also identified that variations in DFC methodological approaches were detectable among the field studies, with the chamber material and sampling flushing flow rate influencing the magnitude of calculated emissions. The spatiotemporal scaling of soil-air Hg fluxes identified that the largest emissions occurred from irrigated agricultural landscapes in California. Vegetation was shown to have a large impact on surface-air Hg fluxes due to both a reduction in solar radiation reaching the soil as well as from direct uptake of Hg in foliage. Despite high soil Hg emissions from some forested and other heavily vegetated regions, the net ecosystem flux (soil flux + vegetation uptake) was low. Conversely, sparsely vegetated regions showed larger net ecosystem emissions, which were similar in magnitude to atmospheric Hg deposition (except for the Mediterranean California region where soil emissions were higher). The net ecosystem flux results highlight the important role of landscape characteristics in effecting the balance between Hg sequestration and (re-)emission to the atmosphere.

  10. A mass balance method for non-intrusive measurements of surface-air trace gas exchange

    NASA Astrophysics Data System (ADS)

    Denmead, O. T.; Harper, L. A.; Freney, J. R.; Griffith, D. W. T.; Leuning, R.; Sharpe, R. R.

    A mass balance method is described for calculating gas production from a surface or volume source in a small test plot from measurements of differences in the horizontal fluxes of the gas across upwind and downwind boundaries. It employs a square plot, 24 m×24 m, with measurements of gas concentration at four heights (up to 3.5 m) along each of the four boundaries. Gas concentrations are multiplied by the appropriate vector winds to yield the horizontal fluxes at each height on each boundary. The difference between these fluxes integrated over downwind and upwind boundaries represents production. Illustrations of the method, which involve exchanges of methane and carbon dioxide, are drawn from experiments with landfills, pastures and grazing animals. Tests included calculation of recovery rates from known gas releases and comparisons with a conventional micrometeorological approach and a backward dispersion model. The method performed satisfactorily in all cases. Its sensitivity for measuring exchanges of CO 2, CH 4 and N 2O in various scenarios was examined. As employed by us, the mass balance method can suffer from errors arising from the large number of gas analyses required for a flux determination, and becomes unreliable when there are light winds and variable wind directions. On the other hand, it is non-disturbing, has a simple theoretical basis, is independent of atmospheric stability or the shape of the wind profile, and is appropriate for flux measurement in situations where conventional micrometeorological methods can not be used, e.g. for small plots, elevated point sources, and heterogeneous surface sources.

  11. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses.

  12. Selected Ion Flow-Drift Tube Mass Spectrometry: Quantification of Volatile Compounds in Air and Breath.

    PubMed

    Spesyvyi, Anatolii; Smith, David; Španěl, Patrik

    2015-12-15

    A selected ion flow-drift tube mass spectrometric analytical technique, SIFDT-MS, is described that extends the established selected ion flow tube mass spectrometry, SIFT-MS, by the inclusion of a static but variable E-field along the axis of the flow tube reactor in which the analytical ion-molecule chemistry occurs. The ion axial speed is increased in proportion to the reduced field strength E/N (N is the carrier gas number density), and the residence/reaction time, t, which is measured by Hadamard transform multiplexing, is correspondingly reduced. To ensure a proper understanding of the physics and ion chemistry underlying SIFDT-MS, ion diffusive loss to the walls of the flow-drift tube and the mobility of injected H3O(+) ions have been studied as a function of E/N. It is seen that the derived diffusion coefficient and mobility of H3O(+) ions are consistent with those previously reported. The rate coefficient has been determined at elevated E/N for the association reaction of the H3O(+) reagent ions with H2O molecules, which is the first step in the production of H3O(+)(H2O)1,2,3 reagent hydrate ions. The production of hydrated analyte ion was also experimentally investigated. The analytical performance of SIFDT-MS is demonstrated by the quantification of acetone and isoprene in exhaled breath. Finally, the essential features of SIFDT-MS and SIFT-MS are compared, notably pointing out that a much lower speed of the flow-drive pump is required for SIFDT-MS, which facilitates the development of smaller cost-effective analytical instruments for real time breath and fluid headspace analyses. PMID:26583448

  13. Regression calibration with instrumental variables for longitudinal models with interaction terms, and application to air pollution studies

    PubMed Central

    Strand, M; Sillau, S; Grunwald, G K; Rabinovitch, N

    2015-01-01

    In this paper, we derive forms of estimators and associated variances for regression calibration with instrumental variables in longitudinal models that include interaction terms between two unobservable predictors and interactions between these predictors and covariates not measured with error; the inclusion of the latter interactions generalize results we previously reported. The methods are applied to air pollution and health data collected on children with asthma. The new methods allow for the examination of how the relationship between health outcome leukotriene E4 (LTE4, a biomarker of inflammation) and two unobservable pollutant exposures and their interaction are modified by the presence or absence of upper respiratory infections. The pollutant variables include secondhand smoke and ambient (outdoor) fine particulate matter. Simulations verify the accuracy of the proposed methods under various conditions. PMID:26640396

  14. Spatial Variability in Ozone and CO2 Flux during the Front Range Air Pollution and Photochemistry Experiment

    NASA Astrophysics Data System (ADS)

    Almand-Hunter, B.; Piedrahita, R.; Kaushik, A.; Noone, D. C.; Walker, J. T.; Hannigan, M.

    2014-12-01

    Air quality problems persist in the Northern Front-Range Metropolitan Area (NFRMA) of Colorado despite efforts to reduce emissions, and summertime ozone concentrations frequently exceed the NAAQS. Atmospheric modeling in the NFRMA is challenging due to the complex topography of the area, as well as diversity of pollutant sources (urban NOx and VOCs, power plants, oil and gas, agricultural emissions, biogenic emissions, and wildfires). An improved understanding of the local atmospheric chemistry will enable researchers to advance atmospheric models, which will subsequently be used to develop and test more effective air quality management strategies. The Front Range Air Pollution and Photochemistry Experiment (FRAPPE) investigates this problem through detailed examination of atmospheric chemistry in the NFRMA. Our project specifically explores the spatial variability in ozone (O3) concentration and dry deposition within the FRAPPE study area. One source of uncertainty in atmospheric models is O3 flux, which varies spatially due to local meteorology and variation in ambient concentration and deposition velocity. Model grid cells typically range in size from 10-100 km and 100-500 km, for regional and global models, respectively, and accurate representations of an entire grid cell cannot always be achieved. Large spatial variability within a model grid cell can lead to poor estimates of trace-gas flux and concentration. Our research addresses this issue by measuring spatial variability in O3 flux using low-cost dry-deposition flux chambers. We are measuring O3 and CO2 flux with 5 low-cost flux chambers and one eddy-covariance tower. The eddy-covariance tower is located at the Boulder Atmospheric Observatory in Erie, CO. All 5 chambers are within a 8.3 x 6 km square, with one chamber collocated with the eddy-covariance tower, and the other 4 chambers at distances of 0.33, 1.14, 3.22, and 7.55 km from the tower. The largest distance between any two chambers is 8.5 km. All

  15. Chiral Signatures of Anthropogenic Semi-Volatile Organic Compounds in Asian, trans- Pacific, and Pacific Northwestern Air Masses

    NASA Astrophysics Data System (ADS)

    Genualdi, S.; Primbs, T.; Bidleman, T.; Jantunen, L.; Simonich, S.

    2006-12-01

    The goal of this research is to use the chiral signatures of Semi-Volatile Organic Compounds (SOCs) to distinguish between new and old sources in Asian, trans-Pacific, and regional air masses. During 2004, a six week air sampling campaign was conducted at a remote site in Okinawa, Japan to determine the chemical composition of Eurasian air masses. During 2003 and 2004, high volume air samples were collected at three different locations in the Pacific Northwest of the United States. These sampling locations were; Mary's Peak Observatory (MPO) located at 1250m in the Oregon Coast Range, Mt. Bachelor located at 2800m in Oregon's Cascade Range, and Cheeka Peak Observatory (CPO) located at 500m in the state of Washington. The air samples consisted of both polyurethane foam and XAD-2 resin to collect the gas phase SOCs, and glass fiber filters to collect the particulate phase SOCs. The samples were extracted using accelerated solvent extraction and enantiomer fractions were determined using GCMS-ECNI with the use of a BGB Analytik chiral column. The chiral SOCs, á-Hexachlorocyclohexane, cis and trans chlordane, heptachlor epoxide, and o'p' DDT, were measured, the enantiomer ratios were determined, and potential new and historical sources of these compounds were identified.

  16. Paper spray mass spectrometry and PLS-DA improved by variable selection for the forensic discrimination of beers.

    PubMed

    Pereira, Hebert Vinicius; Amador, Victória Silva; Sena, Marcelo Martins; Augusti, Rodinei; Piccin, Evandro

    2016-10-12

    Paper spray mass spectrometry (PS-MS) combined with partial least squares discriminant analysis (PLS-DA) was applied for the first time in a forensic context to a fast and effective differentiation of beers. Eight different brands of American standard lager beers produced by four different breweries (141 samples from 55 batches) were studied with the aim at performing a differentiation according to their market prices. The three leader brands in the Brazilian beer market, which have been subject to fraud, were modeled as the higher-price class, while the five brands most used for counterfeiting were modeled as the lower-price class. Parameters affecting the paper spray ionization were examined and optimized. The best MS signal stability and intensity was obtained while using the positive ion mode, with PS(+) mass spectra characterized by intense pairs of signals corresponding to sodium and potassium adducts of malto-oligosaccharides. Discrimination was not apparent neither by using visual inspection nor principal component analysis (PCA). However, supervised classification models provided high rates of sensitivity and specificity. A PLS-DA model using full scan mass spectra were improved by variable selection with ordered predictors selection (OPS), providing 100% of reliability rate and reducing the number of variables from 1701 to 60. This model was interpreted by detecting fifteen variables as the most significant VIP (variable importance in projection) scores, which were therefore considered diagnostic ions for this type of beer counterfeit.

  17. Paper spray mass spectrometry and PLS-DA improved by variable selection for the forensic discrimination of beers.

    PubMed

    Pereira, Hebert Vinicius; Amador, Victória Silva; Sena, Marcelo Martins; Augusti, Rodinei; Piccin, Evandro

    2016-10-12

    Paper spray mass spectrometry (PS-MS) combined with partial least squares discriminant analysis (PLS-DA) was applied for the first time in a forensic context to a fast and effective differentiation of beers. Eight different brands of American standard lager beers produced by four different breweries (141 samples from 55 batches) were studied with the aim at performing a differentiation according to their market prices. The three leader brands in the Brazilian beer market, which have been subject to fraud, were modeled as the higher-price class, while the five brands most used for counterfeiting were modeled as the lower-price class. Parameters affecting the paper spray ionization were examined and optimized. The best MS signal stability and intensity was obtained while using the positive ion mode, with PS(+) mass spectra characterized by intense pairs of signals corresponding to sodium and potassium adducts of malto-oligosaccharides. Discrimination was not apparent neither by using visual inspection nor principal component analysis (PCA). However, supervised classification models provided high rates of sensitivity and specificity. A PLS-DA model using full scan mass spectra were improved by variable selection with ordered predictors selection (OPS), providing 100% of reliability rate and reducing the number of variables from 1701 to 60. This model was interpreted by detecting fifteen variables as the most significant VIP (variable importance in projection) scores, which were therefore considered diagnostic ions for this type of beer counterfeit. PMID:27662764

  18. Assessing Spatial and Temporal Variability of VOCs and PM-Components in Outdoor Air during the Detroit Exposure and Aerosol Research Study (DEARS)

    EPA Science Inventory

    Exposure models for air pollutants often adjust for effects of the physical environment (e.g., season, urban vs. rural populations) in order to improve exposure and risk predictions. Yet attempts are seldom made to attribute variability in observed outdoor air measurements to spe...

  19. Use of High Resolution Mobile Monitoring Techniques to Assess Near-Road Air Quality Variability

    EPA Science Inventory

    This presentation provides a description of the techniques used to develop and conduct effective mobile monitoring studies. It also provides a summary of mobile monitoring assessment studies that have been used to assess near-road concentrations and the variability of pollutant l...

  20. Noncognitive Variables as Predictors of Achievement in Freshmen English. AIR 1996 Annual Forum Paper.

    ERIC Educational Resources Information Center

    House, J. Daniel; Prion, Susan K.

    This study investigated the correlation between noncognitive variables and academic success in a freshman composition course. A sample of 257 freshmen taking an introductory English course completed a survey assessing their attitudes and achievement expectancies. The questionnaire measured self-ratings of overall academic ability, drive to…

  1. Use of High Resolution Mobile Monitoring Techniques to Assess Near Road Air Quality Variability

    EPA Science Inventory

    This presentation provides a description of the techniques used to develop and conduct effective mobile monitoring studies. It also provides a summary of mobile monitoring assessment studies that have been used to assess near-road concentrations and the variability of pollutant l...

  2. Desert Dust Air Mass Mapping in the Western Sahara, using Particle Properties Derived from Space-based Multi-angle Imaging

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Fiebig, Marcus; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

    2008-01-01

    Coincident observations made over the Moroccan desert during the SAhara Mineral dUst experiMent (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from Multi-angle Imaging SpectroRadiometer (MISR) observations, and to place the sub-orbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days for which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 to 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape, and single-scattering albedo. For the three study days, the satellite observations (a) highlight regional gradients in the mix of dust and background spherical particles, (b) identify a dust plume most likely part of a density flow, and (c) show an air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometers away.

  3. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    SciTech Connect

    Morrison, Glenn C.

    1999-12-01

    {sup {minus}7}, 10{sup {minus}5}, and 10{sup {minus}5} respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10{sup {minus}5}, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.

  4. Overview of aerosol properties associated with air masses sampled by the ATR-42 during the EUCAARI campaign (2008)

    NASA Astrophysics Data System (ADS)

    Crumeyrolle, S.; Schwarzenboeck, A.; Roger, J. C.; Sellegri, K.; Burkhart, J. F.; Stohl, A.; Gomes, L.; Quennehen, B.; Roberts, G.; Weigel, R.; Villani, P.; Pichon, J. M.; Bourrianne, T.; Laj, P.

    2013-05-01

    Within the frame of the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) project, the Météo-France aircraft ATR-42 performed 22 research flights over central Europe and the North Sea during the intensive observation period in May 2008. For the campaign, the ATR-42 was equipped to study the aerosol physical, chemical, hygroscopic and optical properties, as well as cloud microphysics. For the 22 research flights, retroplume analyses along the flight tracks were performed with FLEXPART in order to classify air masses into five sectors of origin, allowing for a qualitative evaluation of emission influence on the respective air parcel. This study shows that the extensive aerosol parameters (aerosol mass and number concentrations) show vertical decreasing gradients and in some air masses maximum mass concentrations (mainly organics) in an intermediate layer (1-3 km). The observed mass concentrations (in the boundary layer (BL): between 10 and 30 μg m-3; lower free troposphere (LFT): 0.8 and 14 μg m-3) are high especially in comparison with the 2015 European norms for PM2.5 (25 μg m-3) and with previous airborne studies performed over England (Morgan et al., 2009; McMeeking et al., 2012). Particle number size distributions show a larger fraction of particles in the accumulation size range in the LFT compared to BL. The chemical composition of submicron aerosol particles is dominated by organics in the BL, while ammonium sulphate dominates the submicron aerosols in the LFT, especially in the aerosol particles originated from north-eastern Europe (~ 80%), also experiencing nucleation events along the transport. As a consequence, first the particle CCN acting ability, shown by the CCN/CN ratio, and second the average values of the scattering cross sections of optically active particles (i.e. scattering coefficient divided by the optical active particle concentration) are increased in the LFT compared to BL.

  5. Influence of the ozone profile above Madrid (Spain) on Brewer estimation of ozone air mass factor

    NASA Astrophysics Data System (ADS)

    Antón, M.; López, M.; Costa, M. J.; Serrano, A.; Bortoli, D.; Bañón, M.; Vilaplana, J. M.; Silva, A. M.

    2009-08-01

    The methodology used by Brewer spectroradiometers to estimate the ozone column is based on differential absorption spectroscopy. This methodology employs the ozone air mass factor (AMF) to derive the total ozone column from the slant path ozone amount. For the calculating the ozone AMF, the Brewer algorithm assumes that the ozone layer is located at a fixed height of 22 km. However, for a real specific site the ozone presents a certain profile, which varies spatially and temporally depending on the latitude, altitude and dynamical conditions of the atmosphere above the site of measurements. In this sense, this work address the reliability of the mentioned assumption and analyses the influence of the ozone profiles measured above Madrid (Spain) in the ozone AMF calculations. The approximated ozone AMF used by the Brewer algorithm is compared with simulations obtained using the libRadtran radiative transfer model code. The results show an excellent agreement between the simulated and the approximated AMF values for solar zenith angle lower than 75°. In addition, the relative differences remain lower than 2% at 85°. These good results are mainly due to the fact that the altitude of the ozone layer assumed constant by the Brewer algorithm for all latitudes notably can be considered representative of the real profile of ozone above Madrid (average value of 21.7±1.8 km). The operational ozone AMF calculations for Brewer instruments are limited, in general, to SZA below 80°. Extending the usable SZA range is especially relevant for Brewer instruments located at high mid-latitudes.

  6. On the use and abuse of Newton's second law for variable mass problems

    NASA Astrophysics Data System (ADS)

    Plastino, Angel R.; Muzzio, Juan C.

    1992-09-01

    Solution techniques for celestial mechanics problems involving bodies of varying mass are considered analytically, emphasizing the fact that Newton's second law is valid only for fixed-mass bodies. In the restricted three-body problem, for example, it is pointed out that the motion of a body losing mass isotropically is unaffected by this loss. Expressions to be substituted in the cases of accretion or ablation are presented, and several recent works in which Newton's law is misused are discussed.

  7. Industrial air pollution in rural Kenya: community awareness, risk perception and associations between risk variables

    PubMed Central

    2014-01-01

    Background Developing countries have limited air quality management systems due to inadequate legislation and lack of political will, among other challenges. Maintaining a balance between economic development and sustainable environment is a challenge, hence investments in pollution prevention technologies get sidelined in favor of short-term benefits from increased production and job creation. This lack of air quality management capability translates into lack of air pollution data, hence the false belief that there is no problem. The objectives of the study were to: assess the population’s environmental awareness, explore their perception of pollution threat to their health; examine the association between specific health hazards. Methods A cross-sectional study was implemented by gathering quantitative information on demographic, health status, environmental perception and environmental knowledge of residents to understand their view of pollution in their neighborhood. Focus group discussions (FGDs) allowed for corroboration of the quantitative data. Results Over 80% of respondents perceived industrial pollution as posing a considerable risk to them despite the fact that the economy of the area largely depended on the factory. Respondents also argued that they had not been actively involved in identifying solutions to the environmental challenges. The study revealed a significant association between industrial pollution as a risk and, perception of risk from other familiar health hazards. The most important factors influencing the respondents’ pollution risk perception were environmental awareness and family health status. Conclusion This study avails information to policy makers and researchers concerning public awareness and attitudes towards environmental pollution pertinent to development and implementation of environmental policies for public health. PMID:24742166

  8. The Effects of Increasing Mass on the Variability of Movement & Segmental Movement Times.

    ERIC Educational Resources Information Center

    Byrne, Connell M. J.; And Others

    The effects of increasing the load of materials to be moved on rapid movement of these materials were measured using two dependent variables. The first analysis involved overall mean movement time (MT) and segmental movement times. The second analysis dealt with movement time variability evidenced by within subject MT and segmental MT standard…

  9. Seasonal and interannual variability of sea-air CO2 fluxes in the tropical Atlantic affected by the Amazon River plume

    NASA Astrophysics Data System (ADS)

    Ibánhez, J. Severino P.; Diverrès, Denis; Araujo, Moacyr; Lefèvre, Nathalie

    2015-10-01

    CO2 fugacities obtained from a merchant ship sailing from France to French Guyana were used to explore the seasonal and interannual variability of the sea-air CO2 exchange in the western tropical North Atlantic (TNA; 5-14°N, 41-52°W). Two distinct oceanic water masses were identified in the area associated to the main surface currents, i.e., the North Brazil Current (NBC) and the North Equatorial Current (NEC). The NBC was characterized by permanent CO2 oversaturation throughout the studied period, contrasting with the seasonal pattern identified in the NEC. The NBC retroflection was the main contributor to the North Equatorial Counter Current (NECC), thus spreading into the central TNA, the Amazon River plume, and the CO2-rich waters probably originated from the equatorial upwelling. Strong CO2 undersaturation was associated to the Amazon River plume. Total inorganic carbon drawdown due to biological activity was estimated to be 154 µmol kg-1 within the river plume. As a consequence, the studied area acted as a net sink of atmospheric CO2 (from -72.2 ± 10.2 mmol m-2 month-1 in February to 14.3 ± 4.5 mmol m-2 month-1 in May). This contrasted with the net CO2 efflux estimated by the main global sea-air CO2 flux climatologies. Interannual sea surface temperature changes in the TNA caused by large-scale climatic events could determine the direction and intensity of the sea-air CO2 fluxes in the NEC. Positive temperature anomalies observed in the TNA led to an almost permanent CO2 outgassing in the NEC in 2010.

  10. Determination of benzene, toluene, ethylbenzene and xylenes in air by solid phase micro-extraction/gas chromatography/mass spectrometry.

    PubMed

    Tumbiolo, Simonetta; Gal, Jean-François; Maria, Pierre-Charles; Zerbinati, Orfeo

    2004-11-01

    The aim of the study was to analyse BTEX compounds (benzene, toluene, ethylbenzene, xylenes) in air by solid phase micro-extraction/gas chromatography/mass spectrometry (SPME/GC/MS), and this article presents the features of the calibration method proposed. Examples of real-world air analysis are given. Standard gaseous mixtures of BTEX in air were generated by dynamic dilution. SPME sampling was carried out under non-equilibrium conditions using a Carboxen/PDMS fibre exposed for 30 min to standard gas mixtures or to ambient air. The behaviour of the analytical response was studied from 0 to 65 microg/m3 by adding increasing amounts of BTEX to the air matrix. Detection limits range from 0.05 to 0.1 microg/m3 for benzene, depending on the fibre. Inter-fibre relative standard deviations (reproducibility) are larger than 18%, although the repeatability for an individual fibre is better than 10%. Therefore, each fibre should be considered to be a particular sampling device, and characterised individually depending on the required accuracy. Sampling indoor and outdoor air by SPME appears to be a suitable short-delay diagnostic method for volatile organic compounds, taking advantage of short sampling time and simplicity.

  11. Greenland Ice Sheet seasonal and spatial mass variability from model simulations and GRACE (2003-2012)

    NASA Astrophysics Data System (ADS)

    Alexander, Patrick M.; Tedesco, Marco; Schlegel, Nicole-Jeanne; Luthcke, Scott B.; Fettweis, Xavier; Larour, Eric

    2016-06-01

    Improving the ability of regional climate models (RCMs) and ice sheet models (ISMs) to simulate spatiotemporal variations in the mass of the Greenland Ice Sheet (GrIS) is crucial for prediction of future sea level rise. While several studies have examined recent trends in GrIS mass loss, studies focusing on mass variations at sub-annual and sub-basin-wide scales are still lacking. At these scales, processes responsible for mass change are less well understood and modeled, and could potentially play an important role in future GrIS mass change. Here, we examine spatiotemporal variations in mass over the GrIS derived from the Gravity Recovery and Climate Experiment (GRACE) satellites for the January 2003-December 2012 period using a "mascon" approach, with a nominal spatial resolution of 100 km, and a temporal resolution of 10 days. We compare GRACE-estimated mass variations against those simulated by the Modèle Atmosphérique Régionale (MAR) RCM and the Ice Sheet System Model (ISSM). In order to properly compare spatial and temporal variations in GrIS mass from GRACE with model outputs, we find it necessary to spatially and temporally filter model results to reproduce leakage of mass inherent in the GRACE solution. Both modeled and satellite-derived results point to a decline (of -178.9 ± 4.4 and -239.4 ± 7.7 Gt yr-1 respectively) in GrIS mass over the period examined, but the models appear to underestimate the rate of mass loss, especially in areas below 2000 m in elevation, where the majority of recent GrIS mass loss is occurring. On an ice-sheet-wide scale, the timing of the modeled seasonal cycle of cumulative mass (driven by summer mass loss) agrees with the GRACE-derived seasonal cycle, within limits of uncertainty from the GRACE solution. However, on sub-ice-sheet-wide scales, some areas exhibit significant differences in the timing of peaks in the annual cycle of mass change. At these scales, model biases, or processes not accounted for by models related

  12. First Order Chemical Reaction Effects on Exponentially Accelerated Vertical Plate with Variable Mass Diffusion in the Presence of Thermal Radiation

    NASA Astrophysics Data System (ADS)

    Muthucumaraswamy, R.; Lakshmi, C. S.

    2015-05-01

    Effects of transfer of mass and free convection on the flow field of an incompressible viscous fluid past an exponentially accelerated vertical plate with variable surface temperature and mass diffusion are studied. Results for velocity, concentration, temperature are obtained by solving governing equations using the Laplace transform technique. It is observed that the velocity increases with decreasing values of the chemical reaction parameter or radiation parameter. But the trend is just reversed with respect to the time parameter. The skin friction is also studied.

  13. Variability in surface meteorology and air-sea fluxes due to cumulus convective systems observed during CINDY/DYNAMO

    NASA Astrophysics Data System (ADS)

    Yokoi, Satoru; Katsumata, Masaki; Yoneyama, Kunio

    2014-03-01

    This study examines the variability in surface meteorological parameters and air-sea heat fluxes due to cold pools emanating from cumulus convective systems observed over the tropical Indian Ocean in November 2011. In particular, this study focuses on convective systems that are spatially smaller than mesoscale convective systems in a southeasterly trade wind environment. Composite analyses of convectively active periods show an increase in the sensible heat flux by 15-20 W m-2 that is primarily attributed to an increase in the difference between the surface air temperature and sea surface temperature and an increase in the latent heat flux by 30-70 W m-2 due to enhanced surface wind speeds. A succession of convectively active periods leads to a greater influence than those occurring independently. The direction of the surface wind velocity anomaly due to cold pools tends to be close to that of the environmental wind velocity, resulting in an efficient enhancement of wind speed. This study also demonstrates the close relation between cold pool intensities and convective activity. In particular, two measures of cold pool intensity, a minimum surface air temperature and a maximum amount of surface wind speed enhancement, are correlated with each other and with the convective activity around the observation point measured by radar-estimated rainfall and radar echo coverage.

  14. Investigation on multi-variable decoupled temperature control system for enamelling machine with heated air circulation

    NASA Astrophysics Data System (ADS)

    Li, Yang; Qin, Le; Zou, Shipeng; Long, Shijun

    2014-04-01

    A lots of problems may occur frequently when controlling the temperature of the enamelling machine oven in the real industrial process, such as multi-variable coupled problem. an experimental rig with triple inputs and triple outputs was devised and a simulation modeling was established accordingly in this study,. the temperature control system based on the feedforward compensation algorithm was proposed. Experimental results have shown that the system is of high efficiency, good stability and promising application.

  15. Investigation on multi-variable decoupled temperature control system for enamelling machine with heated air circulation

    SciTech Connect

    Li, Yang; Qin, Le; Zou, Shipeng; Long, Shijun

    2014-04-11

    A lots of problems may occur frequently when controlling the temperature of the enamelling machine oven in the real industrial process, such as multi-variable coupled problem. an experimental rig with triple inputs and triple outputs was devised and a simulation modeling was established accordingly in this study,. the temperature control system based on the feedforward compensation algorithm was proposed. Experimental results have shown that the system is of high efficiency, good stability and promising application.

  16. An air-water interfacial area based variable tortuosity model for unsaturated sands

    SciTech Connect

    Khaleel, Raziuddin; Saripalli, Prasad

    2006-05-01

    Based on Kozeny-Carman equation for saturated media permeability, a new model is developed for the prediction of unsaturated hydraulic conductivity, K as a function of moisture content, ?. The K(???) estimates are obtained using laboratory measurements of moisture retention and saturated hydraulic conductivity, and a saturation-dependent tortuosity based on the immiscible fluid (air-water) interfacial area. Tortuosity (?a) for unsaturated media is defined as aaw/aaw,o (ratio of the specific air-water interfacial area of a real and the corresponding idealized porous medium). A correspondence between the real and idealized media is established by using the laboratory-measured soil moisture retention curve to calculate the interfacial area. The general trend in prediction of ?a as a function water saturation is in agreement with similar recent predictions based on diffusion theory. Unsaturated hydraulic conductivities measured for a number of coarse-textured, repacked Hanford sediments agree well with predictions based on the modified Kozeny-Carman relation. Because of the use of saturated hydraulic conductivity, a slight bias is apparent in measured and predicted K at low ?. While the modified Kozeny-Carman relation was found to be reasonably accurate in predicting K(??) for the repacked, sandy soils considered in this study, a further testing of the new model for undisturbed sediments and other soil textures would be useful.

  17. An automated gas chromatography time-of-flight mass spectrometry instrument for the quantitative analysis of halocarbons in air

    NASA Astrophysics Data System (ADS)

    Obersteiner, F.; Bönisch, H.; Engel, A.

    2015-09-01

    We present the characterization and application of a new gas chromatography-time-of-flight mass spectrometry instrument (GC-TOFMS) for the quantitative analysis of halocarbons in air samples. The setup comprises three fundamental enhancements compared to our earlier work (Hoker et al., 2015): (1) full automation, (2) a mass resolving power R = m/Δ m of the TOFMS (Tofwerk AG, Switzerland) increased up to 4000 Th/Th and (3) a fully accessible data format of the mass spectrometric data. Automation in combination with the accessible data allowed an in-depth characterization of the instrument. Mass accuracy was found around 5 ppm after automatic recalibration of the mass axis in each measurement. A TOFMS configuration giving R = 3500 was chosen to provide an R-to-sensitivity ratio suitable for our purpose. Calculated detection limits were as low as a few femtograms as mass traces could be made highly specific for selected molecule fragments with the accurate mass information. The precision for substance quantification was 0.15 % at the best for an individual measurement and in general mainly determined by the signal-to-noise ratio of the chromatographic peak. The TOFMS was found to be linear within a concentration range from about 1 pg to 1 ng of analyte per Liter of air. At higher concentrations, non-linearities of a few percent were observed (precision level: 0.2 %) but could be attributed to a potential source within the detection system. A straight-forward correction for those non-linearities was applied in data processing, again by exploiting the accurate mass information. Based on the overall characterization results, the GC-TOFMS instrument was found to be very well-suited for the task of quantitative halocarbon trace gas observation and a big step forward compared to scanning, low resolution quadrupole MS and a TOFMS technique reported to be non-linear and restricted by a small dynamical range.

  18. Advective-diffusive mass transfer in fractured porous media with variable rock matrix block size.

    PubMed

    Sharifi Haddad, Amin; Hassanzadeh, Hassan; Abedi, Jalal

    2012-05-15

    Traditional dual porosity models do not take into account the effect of matrix block size distribution on the mass transfer between matrix and fracture. In this study, we introduce the matrix block size distributions into an advective-diffusive solute transport model of a divergent radial system to evaluate the mass transfer shape factor, which is considered as a first-order exchange coefficient between the fracture and matrix. The results obtained lead to a better understanding of the advective-diffusive mass transport in fractured porous media by identifying two early and late time periods of mass transfer. Results show that fractured rock matrix block size distribution has a great impact on mass transfer during early time period. In addition, two dimensionless shape factors are obtained for the late time, which depend on the injection flow rate and the distance of the rock matrix from the injection point.

  19. Influence of air mass source region on nanoparticle events and hygroscopicity in central Virginia, U.S.

    NASA Astrophysics Data System (ADS)

    O'Halloran, T. L.; Fuentes, J. D.; Collins, D. R.; Cleveland, M. J.; Keene, W. C.

    During autumn, 2006, variation in the frequency of aerosol nucleation events, as inferred from nanoparticle growth events, and associated hygroscopicity were investigated as a function of air mass transport history at a mixed deciduous forest in central Virginia, U.S. Above-canopy size distributions of aerosols between 0.012 and 0.700 μm diameter, size-resolved particle hygroscopicity at eight dry diameters between 0.012 and 0.400 μm, and cloud condensation nuclei (CCN) activity were characterized. Air mass back trajectories were clustered to identify source regions. Growth events were most frequent in fast-moving air masses (mean = 9 m s -1) that originated over the north central U.S. Under these flow regimes, mean values for preexisting sub-μm aerosol number concentrations (4700 cm -3), corresponding surface area (142 μm 2 cm -3), air temperature (6.2 °C), and relative humidity (RH, 49.4%) were relatively low compared to other regimes. Under stagnant flow conditions (mean = 3 m s -1), mean number concentrations were higher (>6000 cm -3) and size fractions <0.1 μm diameter exhibited enhanced hygroscopicity compared to other source regions. These results indicate that precursors emitted into relatively clean, cold, and dry air transported over the southeastern U.S. reacted to form condensable intermediates that subsequently produced new aerosols via nucleation and growth. This pathway was an important source for CCN. During events in October, nanoparticles were produced in greater numbers and grew more rapidly compared to November and December.

  20. Flow and containment characteristics of a sash-less, variable-height inclined air-curtain fume hood.

    PubMed

    Huang, Rong Fung; Chen, Jia-Kun; Hung, Wei-Lun

    2013-08-01

    To increase containment efficiency and reduce energy consumption, a sash-less, variable-height inclined air-curtain fume hood (sIAC hood) was developed and tested by a laser-assisted flow visualization technique and tracer-gas detection method. This novel design requires neither sash nor baffle. The sIAC hood employed the inclined push-pull air-curtain technique and two deflection plates installed on the side walls of the hood to induce a tetra-vortex flow structure. The results of flow visualization showed that the slot for suction flow, offset from the slot for the up-blowing jet, caused the air curtain to incline towards the rear wall, thus enhancing the robustness of the tetra-vortex flow structure. Such a flow structure could reduce the influence of draught and human walk-by across the hood face. The containment around the central area of the hood was isolated by the inclined push-pull air curtain. The pollutants carried by the reverse flow induced by the flow separation were guided by the deflection plates from the side walls towards the rear, thus contributing to the formation of the tetra-vortex flow structure. The up/down movable ceiling positioned the suction slot close to the device's pollutant emission opening, but left room (less than 50 cm) for unrestricted hand movement. Testing was carried out based on the methodology described in EN14175. The results of a static test showed that small face velocities of 0.25 and 0.16 m s(-1) were enough to obtain nearly null leakage levels for low and tall pollutant sources. The results of a traversing plate test showed that the face velocity, 0.32 m s(-1), would cause negligibly small leakage levels. The sIAC hood could obtain significantly higher containment efficiency than a conventional hood by operating at a face velocity significantly lower than that of conventional hoods. PMID:23519947

  1. Flow and containment characteristics of a sash-less, variable-height inclined air-curtain fume hood.

    PubMed

    Huang, Rong Fung; Chen, Jia-Kun; Hung, Wei-Lun

    2013-08-01

    To increase containment efficiency and reduce energy consumption, a sash-less, variable-height inclined air-curtain fume hood (sIAC hood) was developed and tested by a laser-assisted flow visualization technique and tracer-gas detection method. This novel design requires neither sash nor baffle. The sIAC hood employed the inclined push-pull air-curtain technique and two deflection plates installed on the side walls of the hood to induce a tetra-vortex flow structure. The results of flow visualization showed that the slot for suction flow, offset from the slot for the up-blowing jet, caused the air curtain to incline towards the rear wall, thus enhancing the robustness of the tetra-vortex flow structure. Such a flow structure could reduce the influence of draught and human walk-by across the hood face. The containment around the central area of the hood was isolated by the inclined push-pull air curtain. The pollutants carried by the reverse flow induced by the flow separation were guided by the deflection plates from the side walls towards the rear, thus contributing to the formation of the tetra-vortex flow structure. The up/down movable ceiling positioned the suction slot close to the device's pollutant emission opening, but left room (less than 50 cm) for unrestricted hand movement. Testing was carried out based on the methodology described in EN14175. The results of a static test showed that small face velocities of 0.25 and 0.16 m s(-1) were enough to obtain nearly null leakage levels for low and tall pollutant sources. The results of a traversing plate test showed that the face velocity, 0.32 m s(-1), would cause negligibly small leakage levels. The sIAC hood could obtain significantly higher containment efficiency than a conventional hood by operating at a face velocity significantly lower than that of conventional hoods.

  2. On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2014-02-01

    Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

  3. On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

    NASA Astrophysics Data System (ADS)

    Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

    2013-02-01

    Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

  4. Novel models on fluid's variable thermo-physical properties for extensive study on convection heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Shang, De-Yi; Zhong, Liang-Cai

    2016-04-01

    Our novel models for fluid's variable physical properties are improved and reported systematically in this work for enhancement of theoretical and practical value on study of convection heat and mass transfer. It consists of three models, namely (1) temperature parameter model, (2) polynomial model, and (3) weighted-sum model, respectively for treatment of temperature-dependent physical properties of gases, temperature-dependent physical properties of liquids, and concentration- and temperature-dependent physical properties of vapour-gas mixture. Two related components are proposed, and involved in each model for fluid's variable physical properties. They are basic physic property equations and theoretical similarity equations on physical property factors. The former, as the foundation of the latter, is based on the typical experimental data and physical analysis. The latter is built up by similarity analysis and mathematical derivation based on the former basic physical properties equations. These models are available for smooth simulation and treatment of fluid's variable physical properties for assurance of theoretical and practical value of study on convection of heat and mass transfer. Especially, so far, there has been lack of available study on heat and mass transfer of film condensation convection of vapour-gas mixture, and the wrong heat transfer results existed in widespread studies on the related research topics, due to ignorance of proper consideration of the concentration- and temperature-dependent physical properties of vapour-gas mixture. For resolving such difficult issues, the present novel physical property models have their special advantages.

  5. IRAS observations of Delta Scuti variables - Implications for main-sequence mass loss and an IR period-luminosity relation

    SciTech Connect

    King, J.R. )

    1990-06-01

    The far-infrared detections of Delta Scuti variables in The Bright Star Catalog by the IRAS satellite are investigated; 52 percent of the sample was detected at 12 microns. The 12 micron luminosity is correlated with L(Bol) and ranges from about 3 x 10 to the 31st to about 6 x 10 to the 32nd erg/s. Comparable numbers of Delta Sct variables and A-F nonvariables show infrared excesses in at least one IRAS passband. Further considerations show that contributions to these excesses due to mass loss are minimal. This investigation suggests that the pulsating variables are not losing mass at higher rates than nonvariable A and F stars which themselves do not appear to be losing mass at a rate above an expected level. The existence of a Period-12 micron luminosity relation of small dispersion, quite surprising in light of the uncertainties in these data is reported. It is demonstrated that such relations also exist at the J, H, and K bands. The possibility of using such relations for distance determinations is discussed in light of good distance estimates to three clusters using the P-L relation. 20 refs.

  6. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

    PubMed

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-11-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

  7. Influence of power ultrasound application on mass transport and microstructure of orange peel during hot air drying

    NASA Astrophysics Data System (ADS)

    Ortuño, Carmen; Pérez-Munuera, Isabel; Puig, Ana; Riera, Enrique; Garcia-Perez, J. V.

    2010-01-01

    Power ultrasound application on convective drying of foodstuffs may be considered an emergent technology. This work deals with the influence of power ultrasound on drying of natural materials addressing the kinetic as well as the product's microstructure. Convective drying kinetics of orange peel slabs (thickness 5.95±0.41 mm) were carried out at 40 ∘C and 1 m/s with (US) and without (AIR) power ultrasound application. A diffusion model considering external resistance to mass transfer was considered to describe drying kinetics. Fresh, US and AIR dried samples were analyzed using Cryo-SEM. Results showed that drying kinetics of orange peel were significantly improved by the application of power ultrasound. From modeling, it was observed a significant (p¡0.05) increase in both mass transfer coefficient and effective moisture diffusivity. The effects on mass transfer properties were confirmed from microestructural observations. In the cuticle surface, the pores were obstructed by wax components scattering, which evidence the ultrasonic effects on the interfaces. The cells of the flavedo were compressed and large intercellular air spaces were generated in the albedo facilitating water transfer through it.

  8. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

    PubMed Central

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-01-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

  9. Low-frequency variability of surface air temperature over the Barents Sea: causes and mechanisms

    NASA Astrophysics Data System (ADS)

    van der Linden, Eveline C.; Bintanja, Richard; Hazeleger, Wilco; Graversen, Rune G.

    2016-08-01

    The predominant decadal to multidecadal variability in the Arctic region is a feature that is not yet well-understood. It is shown that the Barents Sea is a key region for Arctic-wide variability. This is an important topic because low-frequency changes in the ocean might lead to large variations in the sea-ice cover, which then cause massive changes in the ocean-atmosphere heat exchanges. Here we describe the mechanism driving surface temperatures and heat fluxes in the Barents Sea based primarily on analyzes of one global coupled climate model. It is found that the ocean drives the low-frequency changes in surface temperature, whereas the atmosphere compensates the oceanic transport anomalies. The seasonal dependence and the role of individual components of the ocean-atmosphere energy budget are analyzed in detail, showing that seasonally-varying climate mechanisms play an important role. Herein, sea ice is governing the seasonal response, by acting as a lid that opens and closes during warm and cold periods, respectively, thereby modulating the surface heat fluxes.

  10. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-03-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. OMI observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the tropospheric NO2 AMF calculation by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model for cloud-free scenes. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation (SD) of the difference was 0.6 ± 8%. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 72% of the daily OMAERUV AOD observations were within 0.3 of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10% higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30%, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and explicit aerosol parameters is on average 6 and 3

  11. Development of a pressure based vortex-shedding meter: measuring unsteady mass-flow in variable density gases

    NASA Astrophysics Data System (ADS)

    Ford, C. L.; Winroth, M.; Alfredsson, P. H.

    2016-08-01

    An entirely pressure-based vortex-shedding meter has been designed for use in practical time-dependent flows. The meter is capable of measuring mass-flow rate in variable density gases in spite of the fact that fluid temperature is not directly measured. Unlike other vortex meters, a pressure based meter is incredibly robust and may be used in industrial type flows; an environment wholly unsuitable for hot-wires for example. The meter has been tested in a number of static and dynamic flow cases, across a range of mass-flow rates and pressures. The accuracy of the meter is typically better than about 3% in a static flow and resolves the fluctuating mass-flow with an accuracy that is better than or equivalent to a hot-wire method.

  12. Coupled effect of flow variability and mass transfer on contaminant transport and attenuation in groundwater

    NASA Astrophysics Data System (ADS)

    Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon

    2016-04-01

    The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.

  13. Using sorted invariant mass variables to evade combinatorial ambiguities in cascade decays

    DOE PAGES

    Kim, Doojin; Matchev, Konstantin T.; Park, Myeonghun

    2016-02-19

    The classic method for mass determination in a SUSY-like cascade decay chain relies on measurements of the kinematic endpoints in the invariant mass distributions of suitable collections of visible decay products. However, the procedure is complicated by combinatorial ambiguities: e.g., the visible final state particles may be indistinguishable (as in the case of QCD jets), or one may not know the exact order in which they are emitted along the decay chain. In order to avoid such combinatorial ambiguities, we propose to treat the nal state particles fully democratically and consider the sorted set of the invariant masses of allmore » possible partitions of the visible particles in the decay chain. In particular, for a decay to N visible particles, one considers the sorted sets of all possible n-body invariant mass combinations (2≤ n≤ N) and determines the kinematic endpoint m(n,r)max of the distribution of the r-th largest n-body invariant mass m(n,r) for each possible value of n and r. For the classic example of a squark decay in supersymmetry, we provide analytical formulas for the interpretation of these endpoints in terms of the underlying physical masses. We point out that these measurements can be used to determine the structure of the decay topology, e.g., the number and position of intermediate on-shell resonances.« less

  14. Advanced variable speed air source integrated heat pump (AS-IHP) development - CRADA final report

    SciTech Connect

    Baxter, Van D.; Rice, C. Keith; Munk, Jeffrey D.; Ally, Moonis Raza; Shen, Bo

    2015-09-30

    Between August 2011 and September 2015, Oak Ridge National Laboratory (ORNL) and Nordyne, LLC (now Nortek Global HVAC LLC, NGHVAC) engaged in a Cooperative Research and Development Agreement (CRADA) to develop an air-source integrated heat pump (AS-IHP) system for the US residential market. Two generations of laboratory prototype systems were designed, fabricated, and lab-tested during 2011-2013. Performance maps for the system were developed using the latest research version of the DOE/ORNL Heat Pump Design Model, or HPDM, (Rice 1991; Rice and Jackson 2005; Shen et al 2012) as calibrated against the lab test data. These maps were the input to the TRNSYS (SOLAR Energy Laboratory, et al, 2010) system to predict annual performance relative to a baseline suite of equipment meeting minimum efficiency standards in effect in 2006 (combination of 13 SEER air-source heat pump (ASHP) and resistance water heater with Energy Factor (EF) of 0.9). Predicted total annual energy savings, while providing space conditioning and water heating for a tight, well insulated 2600 ft2 (242 m2) house at 5 U.S. locations, ranged from 46 to 61%, averaging 52%, relative to the baseline system (lowest savings at the cold-climate Chicago location). Predicted energy use for water heating was reduced 62 to 76% relative to resistance WH. Based on these lab prototype test and analyses results a field test prototype was designed and fabricated by NGHVAC. The unit was installed in a 2400 ft2 (223 m2) research house in Knoxville, TN and field tested from May 2014 to April 2015. Based on the demonstrated field performance of the AS-IHP prototype and estimated performance of a baseline system operating under the same loads and weather conditions, it was estimated that the prototype would achieve ~40% energy savings relative to the minimum efficiency suite. The estimated WH savings were >60% and SC mode savings were >50%. But estimated SH savings were only about 20%. It is believed that had the test

  15. An ion-drag air mass-flow sensor for automotive applications

    SciTech Connect

    Malaczynski, G.W.; Schroeder, T. )

    1992-04-01

    An air-flow meter, developed primarily for the measurement of intake air flow into an internal combustion engine, is described. The well-known process of corona ion deflection in a gas flow together with proper electrode geometry and a detection scheme provides the conceptual basis for a humidity-insensitive ionic air-flow sensor. Output characteristics of the sensor, such as response time and range of operation, are discussed and compared with those of a production hot-wore meter for the type that is currently used with electronic fuel injection systems.

  16. An assessment of the evidence from ATLAS3D for a variable initial mass function

    NASA Astrophysics Data System (ADS)

    Clauwens, Bart; Schaye, Joop; Franx, Marijn

    2015-06-01

    The ATLAS3D Survey has reported evidence for a non-universal stellar initial mass function (IMF) for early-type galaxies (ETGs). The IMF was constrained by comparing stellar mass measurements from kinematic data with those from spectral energy distribution (SED) fitting. Here, we investigate possible effects of scatter in the reported stellar mass measurements and their potential impact on the IMF determination. We find that a trend of the IMF mismatch parameter with the kinematic mass-to-light ratio, comparable to the trend observed by Cappellari et al., could arise if the Gaussian errors of the kinematic mass determination are typically 30 per cent. Without additional data, it is hard to separate between the option that the IMF has a true large intrinsic variation or the option that the errors in the determination are larger than anticipated. A correlation of the IMF with other properties would help to make this distinction, but no strong correlation has been found yet. The strongest correlation is with velocity dispersion. However, it has a large scatter and the correlation depends on sample selection and distance measurements. The correlation with velocity dispersion could be partly caused by the colour-dependent calibration of the surface brightness fluctuation distances of Tonry et al. We find that the K-band luminosity-limited ATLAS3D Survey is incomplete for the highest M/L galaxies below 1010.3 M⊙. There is a significant IMF-velocity dispersion trend for galaxies with SED masses above this limit, but no trend for galaxies with kinematic masses above this limit. We also find an IMF trend with distance, but no correlation between nearest neighbour ETGs, which excludes a large environmental dependence. Our findings do not rule out the reported IMF variations, but they suggest that further study is needed.

  17. High-Efficiency Variable Dehumidification for Air Conditioners: ClimaStat

    SciTech Connect

    West, Michael K., Ph.D. P.E.

    2006-04-30

    Advantek has successfully developed the first low-cost technology offering significant improvement in both Seasonal Energy Efficiency (SEER) and comfort & humidity control. A production prototype was constructed based on a commercial roof top package unit. The prototype was operated under a wide range of psychrometric conditions. Test data was analyzed to identify refinements, which were implemented to further improve performance in an iterative procedure that resulted in a fully optimized technology. The latest results show an increase in dehumidification capacity of 56% with ClimaStat™ in full dehumidify mode vs. with ClimaStat™ off. Dehumidification improved by a factor of 1.7 to 1.9 – meaning that the unit can provide nearly twice the water removal per unit of sensible cooling load. Performance testing results have been consistent, verifiable and repeatable. . ClimaStat™ cost-effectively controls humidity on-demand and improves indoor air quality while reducing annual energy costs. Test data clearly shows that ClimaStat™ costs 20% to 60% less to operate. ClimaStat™ is ready for market.

  18. High variability of Greenland surface temperature over the past 4000 years estimated from trapped air in an ice core

    NASA Astrophysics Data System (ADS)

    Kobashi, Takuro; Kawamura, Kenji; Severinghaus, Jeffrey P.; Barnola, Jean-Marc; Nakaegawa, Toshiyuki; Vinther, Bo M.; Johnsen, Sigfús J.; Box, Jason E.

    2011-11-01

    Greenland recently incurred record high temperatures and ice loss by melting, adding to concerns that anthropogenic warming is impacting the Greenland ice sheet and in turn accelerating global sea-level rise. Yet, it remains imprecisely known for Greenland how much warming is caused by increasing atmospheric greenhouse gases versus natural variability. To address this need, we reconstruct Greenland surface snow temperature variability over the past 4000 years at the GISP2 site (near the Summit of the Greenland ice sheet; hereafter referred to as Greenland temperature) with a new method that utilises argon and nitrogen isotopic ratios from occluded air bubbles. The estimated average Greenland snow temperature over the past 4000 years was -30.7°C with a standard deviation of 1.0°C and exhibited a long-term decrease of roughly 1.5°C, which is consistent with earlier studies. The current decadal average surface temperature (2001-2010) at the GISP2 site is -29.9°C. The record indicates that warmer temperatures were the norm in the earlier part of the past 4000 years, including century-long intervals nearly 1°C warmer than the present decade (2001-2010). Therefore, we conclude that the current decadal mean temperature in Greenland has not exceeded the envelope of natural variability over the past 4000 years, a period that seems to include part of the Holocene Thermal Maximum. Notwithstanding this conclusion, climate models project that if anthropogenic greenhouse gas emissions continue, the Greenland temperature would exceed the natural variability of the past 4000 years sometime before the year 2100.

  19. Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

    NASA Astrophysics Data System (ADS)

    Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

    2012-06-01

    The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

  20. Mass

    SciTech Connect

    Quigg, Chris

    2007-12-05

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  1. Chemical and Trajectory Analysis of an Air Mass Plume from Asia

    NASA Astrophysics Data System (ADS)

    Guo, J. J.; Marrero, J. E.; Blake, D. R.

    2014-12-01

    Tracking the source of pollution events is important in understanding the transport of pollution plumes and impact on areas far from the source. Previous studies have shown that the rising contribution of Asian air pollution to the US has increased the number of days that pollution events exceed National Ambient Air Quality Standards (NAAQS). Whole air samples collected over the Edwards Air Force Base during a June 2014 NASA Student Airborne Research Program (SARP) flight exhibited enhancements in the concentrations of several compounds between 23-32 thousand feet. Chemical tracer analysis of these high altitude samples reveal that the air does not correspond to California emitted air. Chemical signatures in the plume, including high levels of OCS, chloroform, and methyl chloride, and low levels of methyl bromide, indicate that the plume was most heavily influence by coal combustion with contributions from biomass burning events from Asia. Low concentrations of ethene at the high altitude despite enhanced concentrations of ethane and ethyne suggest that this plume was aged. Further analysis of the plume using meteorological wind trajectories reveal that the plume had originated in China approximately 4-5 days prior. This is faster than results from previous studies that had found a Spring transport time of approximately 6 days.

  2. The initial mass function of stars: evidence for uniformity in variable systems.

    PubMed

    Kroupa, Pavel

    2002-01-01

    The distribution of stellar masses that form in one star formation event in a given volume of space is called the initial mass function (IMF). The IMF has been estimated from low-mass brown dwarfs to very massive stars. Combining IMF estimates for different populations in which the stars can be observed individually unveils an extraordinary uniformity of the IMF. This general insight appears to hold for populations including present-day star formation in small molecular clouds, rich and dense massive star-clusters forming in giant clouds, through to ancient and metal-poor exotic stellar populations that may be dominated by dark matter. This apparent universality of the IMF is a challenge for star formation theory, because elementary considerations suggest that the IMF ought to systematically vary with star-forming conditions. PMID:11778039

  3. The initial mass function of stars: evidence for uniformity in variable systems.

    PubMed

    Kroupa, Pavel

    2002-01-01

    The distribution of stellar masses that form in one star formation event in a given volume of space is called the initial mass function (IMF). The IMF has been estimated from low-mass brown dwarfs to very massive stars. Combining IMF estimates for different populations in which the stars can be observed individually unveils an extraordinary uniformity of the IMF. This general insight appears to hold for populations including present-day star formation in small molecular clouds, rich and dense massive star-clusters forming in giant clouds, through to ancient and metal-poor exotic stellar populations that may be dominated by dark matter. This apparent universality of the IMF is a challenge for star formation theory, because elementary considerations suggest that the IMF ought to systematically vary with star-forming conditions.

  4. Targeted Multiplex Imaging Mass Spectrometry with Single Chain Fragment Variable (scfv) Recombinant Antibodies

    NASA Astrophysics Data System (ADS)

    Thiery, Gwendoline; Mernaugh, Ray L.; Yan, Heping; Spraggins, Jeffrey M.; Yang, Junhai; Parl, Fritz F.; Caprioli, Richard M.

    2012-10-01

    Recombinant scfv antibodies specific for CYP1A1 and CYP1B1 P450 enzymes were combined with targeted imaging mass spectrometry to simultaneously detect the P450 enzymes present in archived, paraffin-embedded, human breast cancer tissue sections. By using CYP1A1 and CYP1B1 specific scfv, each coupled to a unique reporter molecule (i.e., a mass tag) it was possible to simultaneously detect multiple antigens within a single tissue sample with high sensitivity and specificity using mass spectrometry. The capability of imaging multiple antigens at the same time is a significant advance that overcomes technical barriers encountered when using present day approaches to develop assays that can simultaneously detect more than a single antigen in the same tissue sample.

  5. Radon in indoor air of primary schools: determinant factors, their variability and effective dose.

    PubMed

    Madureira, Joana; Paciência, Inês; Rufo, João; Moreira, André; de Oliveira Fernandes, Eduardo; Pereira, Alcides

    2016-04-01

    Radon is a radioactive gas, abundant in granitic areas, such as in the city of Porto at the north-east of Portugal. This gas is a recognized carcinogenic agent, being appointed by the World Health Organization as the leading cause of lung cancer after smoking. The aim of this preliminary survey was to determine indoor radon concentrations in public primary schools, to analyse the main factors influencing their indoor concentration levels and to estimate the effective dose in students and teachers in primary schools. Radon concentrations were measured in 45 classrooms from 13 public primary schools located in Porto, using CR-39 passive radon detectors for about 2-month period. In all schools, radon concentrations ranged from 56 to 889 Bq/m(3) (mean = 197 Bq/m(3)). The results showed that the limit of 100 Bq/m(3) established by WHO IAQ guidelines was exceeded in 92 % of the measurements, as well as 8 % of the measurements exceeded the limit of 400 Bq/m(3) established by the national legislation. Moreover, the mean annual effective dose was calculated as 1.25 mSv/y (ranging between 0.58 and 3.07 mSv/y), which is below the action level (3-10 mSv). The considerable variability of radon concentration observed between and within floors indicates a need to monitor concentrations in several rooms for each floor. A single radon detector for each room can be used, provided that the measurement error is considerably lower than variability of radon concentration between rooms. The results of the present survey will provide useful baseline data for adopting safety measures and dealing effectively with radiation emergencies. In particular, radon remediation techniques should be used in buildings located in the highest radon risk areas of Portugal. The results obtained in the current study concerning radon levels and their variations will be useful to optimize the design of future research surveys.

  6. Radon in indoor air of primary schools: determinant factors, their variability and effective dose.

    PubMed

    Madureira, Joana; Paciência, Inês; Rufo, João; Moreira, André; de Oliveira Fernandes, Eduardo; Pereira, Alcides

    2016-04-01

    Radon is a radioactive gas, abundant in granitic areas, such as in the city of Porto at the north-east of Portugal. This gas is a recognized carcinogenic agent, being appointed by the World Health Organization as the leading cause of lung cancer after smoking. The aim of this preliminary survey was to determine indoor radon concentrations in public primary schools, to analyse the main factors influencing their indoor concentration levels and to estimate the effective dose in students and teachers in primary schools. Radon concentrations were measured in 45 classrooms from 13 public primary schools located in Porto, using CR-39 passive radon detectors for about 2-month period. In all schools, radon concentrations ranged from 56 to 889 Bq/m(3) (mean = 197 Bq/m(3)). The results showed that the limit of 100 Bq/m(3) established by WHO IAQ guidelines was exceeded in 92 % of the measurements, as well as 8 % of the measurements exceeded the limit of 400 Bq/m(3) established by the national legislation. Moreover, the mean annual effective dose was calculated as 1.25 mSv/y (ranging between 0.58 and 3.07 mSv/y), which is below the action level (3-10 mSv). The considerable variability of radon concentration observed between and within floors indicates a need to monitor concentrations in several rooms for each floor. A single radon detector for each room can be used, provided that the measurement error is considerably lower than variability of radon concentration between rooms. The results of the present survey will provide useful baseline data for adopting safety measures and dealing effectively with radiation emergencies. In particular, radon remediation techniques should be used in buildings located in the highest radon risk areas of Portugal. The results obtained in the current study concerning radon levels and their variations will be useful to optimize the design of future research surveys. PMID:26100326

  7. Ambient particulate air pollution, heart rate variability, and blood markers of inflammation in a panel of elderly subjects.

    PubMed Central

    Pope, C Arden; Hansen, Matthew L; Long, Russell W; Nielsen, Karen R; Eatough, Norman L; Wilson, William E; Eatough, Delbert J

    2004-01-01

    Epidemiologic studies report associations between particulate air pollution and cardiopulmonary morbidity and mortality. Although the underlying pathophysiologic mechanisms remain unclear, it has been hypothesized that altered autonomic function and pulmonary/systemic inflammation may play a role. In this study we explored the effects of air pollution on autonomic function measured by changes in heart rate variability (HRV) and blood markers of inflammation in a panel of 88 elderly subjects from three communities along the Wasatch Front in Utah. Subjects participated in multiple sessions of 24-hr ambulatory electrocardiographic monitoring and blood tests. Regression analysis was used to evaluate associations between fine particulate matter [aerodynamic diameter less than or equal to 2.5 microm (PM2.5)] and HRV, C-reactive protein (CRP), blood cell counts, and whole blood viscosity. A 100- microg/m3 increase in PM2.5 was associated with approximately a 35 (SE = 8)-msec decline in standard deviation of all normal R-R intervals (SDNN, a measure of overall HRV); a 42 (SE = 11)-msec decline in square root of the mean of the squared differences between adjacent normal R-R intervals (r-MSSD, an estimate of short-term components of HRV); and a 0.81 (SE = 0.17)-mg/dL increase in CRP. The PM2.5-HRV associations were reasonably consistent and statistically robust, but the CRP association dropped to 0.19 (SE = 0.10) after excluding the most influential subject. PM2.5 was not significantly associated with white or red blood cell counts, platelets, or whole-blood viscosity. Most short-term variability in temporal deviations of HRV and CRP was not explained by PM2.5; however, the small statistically significant associations that were observed suggest that exposure to PM2.5 may be one of multiple factors that influence HRV and CRP. PMID:14998750

  8. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  9. Hierarchical control of ride height system for electronically controlled air suspension based on variable structure and fuzzy control theory

    NASA Astrophysics Data System (ADS)

    Xu, Xing; Zhou, Kongkang; Zou, Nannan; Jiang, Hong; Cui, Xiaoli

    2015-09-01

    The current research of air suspension mainly focuses on the characteristics and design of the air spring. In fact, electronically controlled air suspension (ECAS) has excellent performance in flexible height adjustment during different driving conditions. However, the nonlinearity of the ride height adjusting system and the uneven distribution of payload affect the control accuracy of ride height and the body attitude. Firstly, the three-point measurement system of three height sensors is used to establish the mathematical model of the ride height adjusting system. The decentralized control of ride height and the centralized control of body attitude are presented to design the ride height control system for ECAS. The exact feedback linearization method is adopted for the nonlinear mathematical model of the ride height system. Secondly, according to the hierarchical control theory, the variable structure control (VSC) technique is used to design a controller that is able to adjust the ride height for the quarter-vehicle anywhere, and each quarter-vehicle height control system is independent. Meanwhile, the three-point height signals obtained by three height sensors are tracked to calculate the body pitch and roll attitude over time, and then by calculating the deviation of pitch and roll and its rates, the height control correction is reassigned based on the fuzzy algorithm. Finally, to verify the effectiveness and performance of the proposed combined control strategy, a validating test of ride height control system with and without road disturbance is carried out. Testing results show that the height adjusting time of both lifting and lowering is over 5 s, and the pitch angle and the roll angle of body attitude are less than 0.15°. This research proposes a hierarchical control method that can guarantee the attitude stability, as well as satisfy the ride height tracking system.

  10. Air core notch-coil magnet with variable geometry for fast-field-cycling NMR.

    PubMed

    Kruber, S; Farrher, G D; Anoardo, E

    2015-10-01

    In this manuscript we present details on the optimization, construction and performance of a wide-bore (71 mm) α-helical-cut notch-coil magnet with variable geometry for fast-field-cycling NMR. In addition to the usual requirements for this kind of magnets (high field-to-power ratio, good magnetic field homogeneity, low inductance and resistance values) a tunable homogeneity and a more uniform heat dissipation along the magnet body are considered. The presented magnet consists of only one machined metallic cylinder combined with two external movable pieces. The optimal configuration is calculated through an evaluation of the magnetic flux density within the entire volume of interest. The magnet has a field-to-current constant of 0.728 mT/A, allowing to switch from zero to 0.125 T in less than 3 ms without energy storage assistance. For a cylindrical sample volume of 35 cm(3) the effective magnet homogeneity is lower than 130 ppm. PMID:26367321

  11. Air core notch-coil magnet with variable geometry for fast-field-cycling NMR

    NASA Astrophysics Data System (ADS)

    Kruber, S.; Farrher, G. D.; Anoardo, E.

    2015-10-01

    In this manuscript we present details on the optimization, construction and performance of a wide-bore (71 mm) α -helical-cut notch-coil magnet with variable geometry for fast-field-cycling NMR. In addition to the usual requirements for this kind of magnets (high field-to-power ratio, good magnetic field homogeneity, low inductance and resistance values) a tunable homogeneity and a more uniform heat dissipation along the magnet body are considered. The presented magnet consists of only one machined metallic cylinder combined with two external movable pieces. The optimal configuration is calculated through an evaluation of the magnetic flux density within the entire volume of interest. The magnet has a field-to-current constant of 0.728 mT/A, allowing to switch from zero to 0.125 T in less than 3 ms without energy storage assistance. For a cylindrical sample volume of 35 cm3 the effective magnet homogeneity is lower than 130 ppm.

  12. Air core notch-coil magnet with variable geometry for fast-field-cycling NMR.

    PubMed

    Kruber, S; Farrher, G D; Anoardo, E

    2015-10-01

    In this manuscript we present details on the optimization, construction and performance of a wide-bore (71 mm) α-helical-cut notch-coil magnet with variable geometry for fast-field-cycling NMR. In addition to the usual requirements for this kind of magnets (high field-to-power ratio, good magnetic field homogeneity, low inductance and resistance values) a tunable homogeneity and a more uniform heat dissipation along the magnet body are considered. The presented magnet consists of only one machined metallic cylinder combined with two external movable pieces. The optimal configuration is calculated through an evaluation of the magnetic flux density within the entire volume of interest. The magnet has a field-to-current constant of 0.728 mT/A, allowing to switch from zero to 0.125 T in less than 3 ms without energy storage assistance. For a cylindrical sample volume of 35 cm(3) the effective magnet homogeneity is lower than 130 ppm.

  13. Impact of air pollution and genotype variability on DNA damage in Prague policemen.

    PubMed

    Novotna, Bozena; Topinka, Jan; Solansky, Ivo; Chvatalova, Irena; Lnenickova, Zdena; Sram, Radim J

    2007-07-30

    DNA integrity was analyzed in the lymphocytes of 65 non-smoking city policemen during January and September 2004 using the comet assay combined with excision repair enzymes. Information about inhalation exposure was obtained by (1) stationary monitoring of PM2.5 and carcinogenic polycyclic aromatic hydrocarbons (cPAHs) during the sampling periods and (2) personal exposure monitoring of cPAHs 48h before blood sampling. The data were completed by a lifestyle questionnaire. Regardless of the season of the year, policemen working outdoors (exposed group) exhibited higher levels of DNA damage than those working indoors (controls). Within the exposed group, the levels of both unspecified and oxidative DNA damage detected in January significantly exceeded those found in September. The controls did not show analogous inter-seasonal variability. The winter levels of oxidative DNA damage positively correlated with exposure to cPAHs, probably reflecting increased oxidative stress as a result of high concentrations of PM2.5. In comparison with the wild type genotype, the carriers of at least one mutated allele, CYP1A1*2C (Ile/Val), MTHFR 2656 or MS 2656, and the EPHX1-medium phenotype appeared to be more susceptible specifically to the induction of oxidative DNA damage, while the p53 MspI mutation predisposed the carrier to a higher incidence of both breaks and oxidative lesions in DNA. In contrast, GSTM1-null and vitamin C tended rather to protect DNA integrity. PMID:17590289

  14. VARIABLE BOUND-SITE CHARGING CONTRIBUTIONS TO SURFACE COMPLEXATION MASS ACTION EXPRESSIONS

    EPA Science Inventory

    One and two pK models of surface complexation reactions between reactive surface sites (>SOH) and the proton (H+) use mass action expressions of the form: Ka={[>SOHn-1z-1]g>SOH(0-1)aH+EXP(-xeY/kT)}/{[>SOHnz]g>SOH(n)} where Ka=the acidity constant, [ ]=reactive species concentrati...

  15. CORONAL MASS EJECTIONS AS A MECHANISM FOR PRODUCING IR VARIABILITY IN DEBRIS DISKS

    SciTech Connect

    Osten, Rachel; Livio, Mario; Lubow, Steve; Pringle, J. E.; Soderblom, David; Valenti, Jeff

    2013-03-10

    Motivated by recent observations of short-timescale variations in the infrared emission of circumstellar disks, we propose that coronal mass ejections can remove dust grains on timescales as short as a few days. Continuous monitoring of stellar activity, coupled with infrared observations, can place meaningful constraints on the proposed mechanism.

  16. Geomorphological characteristics and variability of Holocene mass-transport complexes, St. Lawrence River Estuary, Canada

    NASA Astrophysics Data System (ADS)

    Pinet, Nicolas; Brake, Virginia; Campbell, Calvin; Duchesne, Mathieu J.

    2015-01-01

    Recently acquired multibeam bathymetry data are used to investigate seafloor instability features along a 310 km-long segment of the St. Lawrence River Estuary. The analysis of this dataset indicates that submarine slides occur over a much larger area than previously recognized and that Holocene sediments are reworked by mass-transport along significant portions of both the northwest and southeast margins of the Laurentian Channel. In the surveyed area, 96 individual mass-transport complexes (MTCs) were identified representing 13% of the seabed. MTCs vary in area from less than 1 km2 to more than 40 km2 and exhibit various geomorphological signatures. Qualitative observation reveals an apparent disparity between MTCs that remain coherent and those that disintegrate during downslope transport evolving into a blocky morphological signature. For all MTCs, morphological parameters have been measured (area, length, and height) or calculated (slope and roughness). This quantitative analysis provides a unique opportunity to study these parameters in a statistically significant and homogeneous dataset located in a relatively small area that experienced a similar Quaternary history. In many cases, mass transport events appear to initiate in the vicinity of steep bedrock walls located along some segments of the estuary. The timing of mass-transport events was not constrained during this study. However, the fact that the region hosts the Charlevoix seismic zone, the most tectonically active area in eastern Canada, strongly suggests that earthquakes acted as a trigger for submarine landsliding.

  17. Impact of Climatic Variability on Atmospheric Mass Distribution and GRACE-Derived Gravity Fields

    NASA Technical Reports Server (NTRS)

    Salstein, David A.; Rosen, Richard D.; Ponte, Rui M.; Frey, Herbert (Technical Monitor)

    2003-01-01

    During the period we calculated the atmospheric data sets related to its mass and angular momentum distribution. For mass, we determined the various harmonics from the NCEP-NCAR reanalysis, especially the low-order harmonics that are useful in studying the gravitation distribution as will be determined from the GRACE mission. Atmospheric mass is also related to the atmospheric loading on the solid Earth; we cooperated with scientists who needed the atmospheric mass information for understanding its contributions to the overall loading, necessary for vertical and horizontal coordinate estimation. We calculated atmospheric angular momentum from the NCEP-NCAR reanalyses and 4 operational meteorological centers, based on the motion (wind) terms and the mass (surface pressure) terms. These are associated with motions of the planet, including its axial component causing changes in the length of day, more related to the winds, and the equatorial component related to motions of the pole, more related to the mass. Tasks related to the ocean mass and angular momentum were added to the project as well. For these we have noted the ocean impact on motions of the pole as well as the torque mechanisms that relate the transfer of angular momentum between oceans and solid earth. The activities of the project may be summarized in the following first manuscript written in December 2002, for a symposium that Dr. Salstein attended on Geodynamics. We have continued to assess ocean angular momentum (OAM) quantities derived from bottom pressure and velocity fields estimated with our finite-difference barotropic (single layer) model. Three years of output (1993-95) from a run without any data constraints was compared to output from a corresponding run that was constrained by altimeter data using a Kalman filter and smoother scheme. Respective OAM time series were combined with corresponding atmospheric series and compared to observed polar motion. The constrained OAM series provided

  18. Short-term variability and mass loss in Be stars. I. BRITE satellite photometry of η and μ Centauri

    NASA Astrophysics Data System (ADS)

    Baade, D.; Rivinius, Th.; Pigulski, A.; Carciofi, A. C.; Martayan, Ch.; Moffat, A. F. J.; Wade, G. A.; Weiss, W. W.; Grunhut, J.; Handler, G.; Kuschnig, R.; Mehner, A.; Pablo, H.; Popowicz, A.; Rucinski, S.; Whittaker, G.

    2016-04-01

    Context. Empirical evidence for the involvement of nonradial pulsations (NRPs) in the mass loss from Be stars ranges from (i) a singular case (μ Cen) of repetitive mass ejections triggered by multi-mode beating to (ii) several photometric reports about enormous numbers of pulsation modes that suddenly appear during outbursts and on to (iii) effective single-mode pulsators. Aims: The purpose of this study is to develop a more detailed empirical description of the star-to-disk mass transfer and to check the hypothesis that spates of transient nonradial pulsation modes accompany and even drive mass-loss episodes. Methods: The BRITE Constellation of nanosatellites was used to obtain mmag photometry of the Be stars η and μ Cen. Results: In the low-inclination star μ Cen, light pollution by variable amounts of near-stellar matter prevented any new insights into the variability and other properties of the central star. In the equator-on star η Cen, BRITE photometry and Heros echelle spectroscopy from the 1990s reveal an intricate clockwork of star-disk interactions. The mass transfer is modulated with the frequency difference of two NRP modes and an amplitude three times as large as the amplitude sum of the two NRP modes. This process feeds a high-amplitude circumstellar activity running with the incoherent and slightly lower so-called Štefl frequency. The mass-loss-modulation cycles are tightly coupled to variations in the value of the Štefl frequency and in its amplitude, albeit with strongly drifting phase differences. Conclusions: The observations are well described by the decomposition of the mass loss into a pulsation-related engine in the star and a viscosity-dominated engine in the circumstellar disk. Arguments are developed that large-scale gas-circulation flows occur at the interface. The propagation rates of these eddies manifest themselves as Štefl frequencies. Bursts in power spectra during mass-loss events can be understood as the noise inherent to

  19. Numerical investigation of interfacial mass transport resistance and two-phase flow in PEM fuel cell air channels

    NASA Astrophysics Data System (ADS)

    Koz, Mustafa

    Proton exchange membrane fuel cells (PEMFCs) are efficient and environmentally friendly electrochemical engines. The performance of a PEMFC is adversely affected by oxygen (O2) concentration loss from the air flow channel to the cathode catalyst layer (CL). Oxygen transport resistance at the gas diffusion layer (GDL) and air channel interface is a non-negligible component of the O2 concentration loss. Simplified PEMFC performance models in the available literature incorporate the O2 resistance at the GDL-channel interface as an input parameter. However, this parameter has been taken as a constant so far in the available literature and does not reflect variable PEMFC operating conditions and the effect of two-phase flow in the channels. This study numerically calculates the O2 transport resistance at the GDL-air channel interface and expresses this resistance through the non-dimensional Sherwood number (Sh). Local Sh is investigated in an air channel with multiple droplets and films inside. These water features are represented as solid obstructions and only air flow is simulated. Local variations of Sh in the flow direction are obtained as a function of superficial air velocity, water feature size, and uniform spacing between water features. These variations are expressed with mathematical expressions for the PEMFC performance models to utilize and save computational resources. The resulting mathematical correlations for Sh can be utilized in PEMFC performance models. These models can predict cell performance more accurately with the help of the results of this work. Moreover, PEMFC performance models do not need to use a look-up table since the results were expressed through correlations. Performance models can be kept simplified although their predictions will become more realistic. Since two-phase flow in channels is experienced mostly at lower temperatures, performance optimization at low temperatures can be done easier.

  20. Long-term Trend of Cold Air Mass Amount below a Designated Potential Temperature in Northern and Southern Hemisphere Winters with 7 Different Reanalysis Datasets

    NASA Astrophysics Data System (ADS)

    Kanno, Y.; Abdillah, M. R.; Iwasaki, T.

    2015-12-01

    This study addresses that the hemispheric total cold air mass amount defined below a threshold potential temperature of 280 K is a good indicator of the long-term trend of climate change in the polar region. We demonstrate quantitative analyses of warming trend in the Northern Hemisphere (NH) and Southern Hemisphere (SH) winters, using 7 different reanalysis datasets (JRA-55, JRA-55C, JRA-55AMIP, ERA-interim, CFSR, JRA-25, NCEP-NCAR). Hemispheric total cold air mass amount in the NH winter exhibit a statistically significant decreasing trend in all reanalysis datasets at a rate about -1.37 to -0.77% per decade over the period 1959-2012 and at a rate about -1.57 to -0.82% per decade over 1980-2012. There is no statistically significant trend in the equatorward cold air mass flux across latitude of 45N, which is an indicator for hemispheric-scale cold air outbreak, over the period 1980-2012 except for NCEP-NCAR reanalysis dataset which shows substantial decreasing trend of about -3.28% per decade. The spatial distribution of the long-term trend of cold air mass amount in the NH winter is almost consistent among reanalysis datasets except for JRA-55AMIP over the period 1980-2012. Cold air mass amount increases over Central Siberia, Kamchatka peninsula, and Bering Sea, while it decreases over Norwegian Sea, Barents Sea, Kara Sea, Greenland, Canada, Northern part of United States, and East Asia. In the SH winter, on the other hand, there is a large discrepancy in hemispheric total cold air mass amount and equatorward cold air mass flux across latitude of 50S over the period 1980-2010 among reanalysis datasets. This result indicate that there is a large uncertainty in the long-term trend of cold air mass amount in the SH winter.

  1. Use of Chiral Signatures of Organochlorine Pesticides in Asian, Trans-Pacific, and Western U.S. Air Masses to Identify Source Regions

    NASA Astrophysics Data System (ADS)

    Simonich, S.; Genualdi, S.; Primbs, T.; Ryoo, K.; Bidleman, T.; Jantunen, L.

    2008-12-01

    Chiral signatures of organochlorine pesticides were measured in air masses on Okinawa Japan and three remote locations in the Pacific Northwestern U.S.: Cheeka Peak Observatory (CPO), a coastal site on the Olympic Peninsula of Washington at 500 m; Mary's Peak Observatory (MPO), a site at 1250 m in Oregon's Coast range; and Mt. Bachelor Observatory (MBO), a site at 2300 m in Oregon's Cascade range. The chiral signature of composite soil samples collected from agricultural areas in China and South Korea were also measured. Racemic alpha-HCH was measured in Asian air masses and soil from China and South Korea. Non-racemic (enantiomer fraction (EF) = 0.528 ± 0.0048) alpha-HCH was measured in regional air masses at CPO, a marine boundary layer site, and may reflect volatilization from the Pacific Ocean and regional soils. However, during trans-Pacific transport events at CPO, the EFs were significantly (p-value <0.001) more racemic (EF = 0.513 ± 0.0003). Racemic alpha-HCH was consistently measured in trans- Pacific air masses at MPO and MBO. The alpha-HCH EFs in CPO, MPO, and MBO air masses were positively correlated (p-value = 0.0017) with the amount of time the air mass spent above the boundary layer along the 10-day back air mass trajectory prior to being sampled. This suggests that the alpha-HCH in the free troposphere is racemic. The racemic signatures of cis and trans chlordane in air masses at all four air sampling sites suggest that Asian and U.S. urban areas continue to be sources of chlordanes that have not yet undergone biotransformation.

  2. Bora event variability and the role of air-sea feedback

    USGS Publications Warehouse

    Pullen, J.; Doyle, J.D.; Haack, T.; Dorman, C.; Signell, R.P.; Lee, C.M.

    2007-01-01

    A two-way interacting high resolution numerical simulation of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM) and Coupled Ocean/ Atmosphere Mesoscale Prediction System (COAMPS??) was conducted to improve forecast momentum and heat flux fields, and to evaluate surface flux field differences for two consecutive bora events during February 2003. (COAMPS?? is a registered trademark of the Naval Research Laboratory.) The strength, mean positions and extensions of the bora jets, and the atmospheric conditions driving them varied considerably between the two events. Bora 1 had 62% stronger heat flux and 51% larger momentum flux than bora 2. The latter displayed much greater diurnal variability characterized by inertial oscillations and the early morning strengthening of a west Adriatic barrier jet, beneath which a stronger west Adriatic ocean current developed. Elsewhere, surface ocean current differences between the two events were directly related to differences in wind stress curl generated by the position and strength of the individual bora jets. The mean heat flux bias was reduced by 72%, and heat flux RMSE reduced by 30% on average at four instrumented over-water sites in the two-way coupled simulation relative to the uncoupled control. Largest reductions in wind stress were found in the bora jets, while the biggest reductions in heat flux were found along the north and west coasts of the Adriatic. In bora 2, SST gradients impacted the wind stress curl along the north and west coasts, and in bora 1 wind stress curl was sensitive to the Istrian front position and strength. The two-way coupled simulation produced diminished surface current speeds of ???12% over the northern Adriatic during both bora compared with a one-way coupled simulation. Copyright 2007 by the American Geophysical Union.

  3. Retrospective screening of pesticide metabolites in ambient air using liquid chromatography coupled to high-resolution mass spectrometry.

    PubMed

    López, Antonio; Yusà, Vicent; Millet, Maurice; Coscollà, Clara

    2016-04-01

    A new methodology for the retrospective screening of pesticide metabolites in ambient air was developed, using liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (UHPLC-HRMS), including two systematic workflows (i) post-run target screening (suspect screening) and (ii) non-target screening. An accurate-mass database was built and used for the post-run screening analysis. The database contained 240 pesticide metabolites found in different matrixes such as air, soil, water, plants, animals and humans. For non-target analysis, a "fragmentation-degradation" relationship strategy was selected. The proposed methodology was applied to 31 air samples (PM10) collected in the Valencian Region (Spain). In the post-target analysis 34 metabolites were identified, of which 11 (3-ketocarburan, carbofuran-7-phenol, carbendazim, desmethylisoproturon, ethiofencarb-sulfoxide, malaoxon, methiocarb-sulfoxide, N-(2-ethyl-6-methylphenyl)-L-alanine, omethoate, 2-hydroxy-terbuthylazine, and THPAM) were confirmed using analytical standards. The semiquantitative estimated concentration ranged between 6.78 and 198.31 pg m(-3). Likewise, two unknown degradation products of malaoxon and fenhexamid were elucidated in the non-target screening. PMID:26838378

  4. Thermal desorption-gas chromatography-mass spectrometry method to determine phthalate and organophosphate esters from air samples.

    PubMed

    Aragón, M; Borrull, F; Marcé, R M

    2013-08-16

    A method based on thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed to determine four organophosphate esters, seven phthalate esters, and bis(2-ethylhexyl) adipate in the gas phase from harbour and urban air samples. The method involves the sampling of 1.5L of air in a Tenax TA sorbent tube followed by thermal desorption (using a Tenax TA cryogenic trap) coupled to gas chromatography-mass spectrometry. The repeatability of the method expressed as %RSD (n=3) is less than 15% and the MQLs are between 0.007μgm(-3) (DMP, TBP, BBP, TPP and DnOP) and 6.7μgm(-3) (DEHP). The method was successfully applied in two areas (urban and harbour) testing two and three points in each one, respectively. Some of these compounds were found in both urban and harbour samples. Di-(2-ethylhexyl)phthalate was the most abundant compound found in both areas at concentration levels between 6.7μgm(-3) and 136.4μgm(-3). This study demonstrates that thermal desorption is an efficient method for the determination of these semi-volatile compounds in the gas phase fraction of air samples.

  5. Retrospective screening of pesticide metabolites in ambient air using liquid chromatography coupled to high-resolution mass spectrometry.

    PubMed

    López, Antonio; Yusà, Vicent; Millet, Maurice; Coscollà, Clara

    2016-04-01

    A new methodology for the retrospective screening of pesticide metabolites in ambient air was developed, using liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (UHPLC-HRMS), including two systematic workflows (i) post-run target screening (suspect screening) and (ii) non-target screening. An accurate-mass database was built and used for the post-run screening analysis. The database contained 240 pesticide metabolites found in different matrixes such as air, soil, water, plants, animals and humans. For non-target analysis, a "fragmentation-degradation" relationship strategy was selected. The proposed methodology was applied to 31 air samples (PM10) collected in the Valencian Region (Spain). In the post-target analysis 34 metabolites were identified, of which 11 (3-ketocarburan, carbofuran-7-phenol, carbendazim, desmethylisoproturon, ethiofencarb-sulfoxide, malaoxon, methiocarb-sulfoxide, N-(2-ethyl-6-methylphenyl)-L-alanine, omethoate, 2-hydroxy-terbuthylazine, and THPAM) were confirmed using analytical standards. The semiquantitative estimated concentration ranged between 6.78 and 198.31 pg m(-3). Likewise, two unknown degradation products of malaoxon and fenhexamid were elucidated in the non-target screening.

  6. Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

    NASA Astrophysics Data System (ADS)

    Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

    2014-08-01

    Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

  7. OMI tropospheric NO2 air mass factors over South America: effects of biomass burning aerosols

    NASA Astrophysics Data System (ADS)

    Castellanos, P.; Boersma, K. F.; Torres, O.; de Haan, J. F.

    2015-09-01

    Biomass burning is an important and uncertain source of aerosols and NOx (NO + NO2) to the atmosphere. Satellite observations of tropospheric NO2 are essential for characterizing this emissions source, but inaccuracies in the retrieval of NO2 tropospheric columns due to the radiative effects of aerosols, especially light-absorbing carbonaceous aerosols, are not well understood. It has been shown that the O2-O2 effective cloud fraction and pressure retrieval is sensitive to aerosol optical and physical properties, including aerosol optical depth (AOD). Aerosols implicitly influence the tropospheric air mass factor (AMF) calculations used in the NO2 retrieval through the effective cloud parameters used in the independent pixel approximation. In this work, we explicitly account for the effects of biomass burning aerosols in the Ozone Monitoring Instrument (OMI) tropospheric NO2 AMF calculation for cloud-free scenes. We do so by including collocated aerosol extinction vertical profile observations from the CALIOP instrument, and aerosol optical depth (AOD) and single scattering albedo (SSA) retrieved by the OMI near-UV aerosol algorithm (OMAERUV) in the DISAMAR radiative transfer model. Tropospheric AMFs calculated with DISAMAR were benchmarked against AMFs reported in the Dutch OMI NO2 (DOMINO) retrieval; the mean and standard deviation of the difference was 0.6 ± 8 %. Averaged over three successive South American biomass burning seasons (2006-2008), the spatial correlation in the 500 nm AOD retrieved by OMI and the 532 nm AOD retrieved by CALIOP was 0.6, and 68 % of the daily OMAERUV AOD observations were within 30 % of the CALIOP observations. Overall, tropospheric AMFs calculated with observed aerosol parameters were on average 10 % higher than AMFs calculated with effective cloud parameters. For effective cloud radiance fractions less than 30 %, or effective cloud pressures greater than 800 hPa, the difference between tropospheric AMFs based on implicit and

  8. An automated gas chromatography time-of-flight mass spectrometry instrument for the quantitative analysis of halocarbons in air

    NASA Astrophysics Data System (ADS)

    Obersteiner, F.; Bönisch, H.; Engel, A.

    2016-01-01

    We present the characterization and application of a new gas chromatography time-of-flight mass spectrometry instrument (GC-TOFMS) for the quantitative analysis of halocarbons in air samples. The setup comprises three fundamental enhancements compared to our earlier work (Hoker et al., 2015): (1) full automation, (2) a mass resolving power R = m/Δm of the TOFMS (Tofwerk AG, Switzerland) increased up to 4000 and (3) a fully accessible data format of the mass spectrometric data. Automation in combination with the accessible data allowed an in-depth characterization of the instrument. Mass accuracy was found to be approximately 5 ppm in mean after automatic recalibration of the mass axis in each measurement. A TOFMS configuration giving R = 3500 was chosen to provide an R-to-sensitivity ratio suitable for our purpose. Calculated detection limits are as low as a few femtograms by means of the accurate mass information. The precision for substance quantification was 0.15 % at the best for an individual measurement and in general mainly determined by the signal-to-noise ratio of the chromatographic peak. Detector non-linearity was found to be insignificant up to a mixing ratio of roughly 150 ppt at 0.5 L sampled volume. At higher concentrations, non-linearities of a few percent were observed (precision level: 0.2 %) but could be attributed to a potential source within the detection system. A straightforward correction for those non-linearities was applied in data processing, again by exploiting the accurate mass information. Based on the overall characterization results, the GC-TOFMS instrument was found to be very well suited for the task of quantitative halocarbon trace gas observation and a big step forward compared to scanning, quadrupole MS with low mass resolving power and a TOFMS technique reported to be non-linear and restricted by a small dynamical range.

  9. Air mass origin and its influence on radionuclide activities ( 7Be and 210Pb) in aerosol particles at a coastal site in the western Mediterranean

    NASA Astrophysics Data System (ADS)

    Dueñas, C.; Orza, J. A. G.; Cabello, M.; Fernández, M. C.; Cañete, S.; Pérez, M.; Gordo, E.

    2011-07-01

    Studies of radionuclide activities in aerosol particles provide a means for evaluating the integrated effects of transport and meteorology on the atmospheric loadings of substances with different sources. Measurements of aerosol mass concentration and specific activities of 7Be and 210Pb in aerosols at Málaga (36° 43' 40″ N; 4° 28' 8″ W) for the period 2000-2006 were used to obtain the relationships between radionuclide activities and airflow patterns by comparing the data grouped by air mass trajectory clusters. The average concentration values of 7Be and 210Pb over the 7 year period have been found to be 4.6 and 0.58 mBq m -3, respectively, with mean aerosol mass concentration of 53.6 μg m -3. The identified air flow types arriving at Málaga reflect the transitional location of the Iberian Peninsula and show significant differences in radionuclide activities. Air concentrations of both nuclides and the aerosol mass concentration are controlled predominantly by the synoptic scenarios leading to the entrance of dust-laden continental flows from northern Africa and the arrival of polar maritime air masses, as implied by the strong correlations found between the monthly frequencies of the different air masses and the specific activities of both radionuclides. Correlations between activity concentrations and precipitation are significant though lower than with air masses.

  10. Land use regression modeling of intra-urban residential variability in multiple traffic-related air pollutants

    PubMed Central

    Clougherty, Jane E; Wright, Rosalind J; Baxter, Lisa K; Levy, Jonathan I

    2008-01-01

    Background There is a growing body of literature linking GIS-based measures of traffic density to asthma and other respiratory outcomes. However, no consensus exists on which traffic indicators best capture variability in different pollutants or within different settings. As part of a study on childhood asthma etiology, we examined variability in outdoor concentrations of multiple traffic-related air pollutants within urban communities, using a range of GIS-based predictors and land use regression techniques. Methods We measured fine particulate matter (PM2.5), nitrogen dioxide (NO2), and elemental carbon (EC) outside 44 homes representing a range of traffic densities and neighborhoods across Boston, Massachusetts and nearby communities. Multiple three to four-day average samples were collected at each home during winters and summers from 2003 to 2005. Traffic indicators were derived using Massachusetts Highway Department data and direct traffic counts. Multivariate regression analyses were performed separately for each pollutant, using traffic indicators, land use, meteorology, site characteristics, and central site concentrations. Results PM2.5 was strongly associated with the central site monitor (R2 = 0.68). Additional variability was explained by total roadway length within 100 m of the home, smoking or grilling near the monitor, and block-group population density (R2 = 0.76). EC showed greater spatial variability, especially during winter months, and was predicted by roadway length within 200 m of the home. The influence of traffic was greater under low wind speed conditions, and concentrations were lower during summer (R2 = 0.52). NO2 showed significant spatial variability, predicted by population density and roadway length within 50 m of the home, modified by site characteristics (obstruction), and with higher concentrations during summer (R2 = 0.56). Conclusion Each pollutant examined displayed somewhat different spatial patterns within urban neighborhoods

  11. Intra-urban variability of air pollution in Windsor, Ontario-Measurement and modeling for human exposure assessment

    SciTech Connect

    Wheeler, Amanda J. Smith-Doiron, Marc; Xu Xiaohong; Gilbert, Nicolas L.; Brook, Jeffrey R.

    2008-01-15

    There are acknowledged difficulties in epidemiological studies to accurately assign exposure to air pollution for large populations, and large, long-term cohort studies have typically relied upon data from central monitoring stations. This approach has generally been adequate when populations span large areas or diverse cities. However, when the effects of intra-urban differences in exposure are being studied, the use of these existing central sites are likely to be inadequate for representing spatial variability that exists within an urban area. As part of the Border Air Quality Strategy (BAQS), an international agreement between the governments of Canada and the United States, a number of air health effects studies are being undertaken by Health Canada and the US EPA. Health Canada's research largely focuses on the chronic exposure of elementary school children to air pollution. The exposure characterization for this population to a variety of air pollutants has been assessed using land-use regression (LUR) models. This approach has been applied in several cities to nitrogen dioxide (NO{sub 2}), as an assumed traffic exposure marker. However, the models have largely been developed from limited periods of saturation monitoring data and often only represent one or two seasons. Two key questions from these previous efforts, which are examined in this paper, are: If NO{sub 2} is a traffic marker, what other pollutants, potentially traffic related, might it actually represent? How well is the within city spatial variability of NO{sub 2}, and other traffic-related pollutants, characterized by a single saturation monitoring campaign. Input data for the models developed in this paper were obtained across a network of 54 monitoring sites situated across Windsor, Ontario. The pollutants studied were NO{sub 2}, sulfur dioxide (SO{sub 2}) and volatile organic compounds, which were measured in all four seasons by deploying passive samplers for 2-week periods. Correlations

  12. Body mass index and other anthropometric variables in children with sickle cell anaemia

    PubMed Central

    Odetunde, Odutola Israel; Chinawa, Josephat Maduabuchi; Achigbu, Kingsley Ihedioha; Achigbu, Eberechukwu O

    2016-01-01

    Objectives: The objectives of this study were to determine the anthropometric variables of children with sickle cell anaemia and comparing it with those with normal haemoglobin genotype. Methods: A cross sectional study of anthropometric measurements was conducted over a period of six months. Children with sickle cell anaemia in steady state aged between 6-20 years were recruited. Nutritional assessment was done using anthropometrical variables. Data were analyzed using the Statistical Package for Social Sciences program (SPSS), version 20. Results: The sickle cell patients comprised of 20 males and 20 females. There were an equal number of controls with an equal male to female ratio of 1:1. Forty eight percent (19) of the children with sickle cell anemia were underweight (< 5th %ile) and this is statistically significant. χ2=18.02 and p=0.000. When compared with subjects with normal haemoglobin genotype only five of them (13%) were underweight. χ2=10.286 and p=0.001. The controls weighed significantly more than the HbSS patients and also had significantly larger body surface compared to the HbSS population (P<0.05). Conclusion: BMI and other anthropometric variables among children with sickle cell anemia were low when compared with children with normal Haemoglobin genotype. PMID:27182236

  13. [Determination of volatile organic compounds in ambient air by thermal desorption-gas chromatography-triple quadrupole tandem mass spectrometry].

    PubMed

    Feng, Lili; Hu, Xiaofang; Yu, Xiaojuan; Zhang, Wenying

    2016-02-01

    A method was established for the simultaneous determination of 23 volatile organic compounds (VOCs) in ambient air with combination of thermal desorption (TD) and gas chromatography-triple quadrupole tandem mass spectrometry (GC-MS/MS). The air samples were collected by active sampling method using Tenax-TA sorbent tubes, and desorbed by thermal desorption. The analytes were determined by GC-MS/MS in selected reaction monitoring (SRM) mode, and internal standard method was applied to quantify the VOCs. The results of all the 23 VOCs showed good linearities in low level (0. 01-1 ng) and high level (1-100 ng) with all the correlation coefficients (r2) more than 0. 99. The method quantification limits were between 0. 000 08-1 µg/m3. The method was validated by means of recovery experiments (n = 6) at three spiked levels of 2, 10 and 50 ng. The recoveries between 77% and 124% were generally obtained. The relative standard deviations (RSDs) in all cases were lower than 20%, except for chlorobenzene at the low spiked level. The developed method was applied to determine VOCs in ambient air collected at three sites in Shanghai. Several compounds, like benzene, toluene, ethylbenzene, m-xylenes, p-xylenes, styrene, 1, 2, 4-trimethylbenzene and hexachlorobutadiene were detected and confirmed in all the samples analyzed. The method is highly accurate, reliable and sensitive for monitoring the VOCs in ambient air. PMID:27382728

  14. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air. PMID:26493981

  15. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    PubMed

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

  16. Deep, Low Mass Ratio Overcontact Binary Systems. XIII. DZ Piscium with Intrinsic Light Variability

    NASA Astrophysics Data System (ADS)

    Yang, Y.-G.; Qian, S.-B.; Zhang, L.-Y.; Dai, H.-F.; Soonthornthum, B.

    2013-08-01

    New multi-color photometry for the eclipsing binary DZ Psc was performed in 2011 and 2012 using the 85 cm telescope at the Xinglong Station of the National Astronomical Observatories of China. Using the updated Wilson-Devinney (W-D) code, we deduced two sets of photometric solutions. The overcontact degree is f = 89.7(± 1.0)%, identifying DZ Psc as a deep, low mass ratio overcontact binary. The asymmetric light curves (i.e., LC2 in 2012) were modeled by a hot spot on the primary star. Based on all of the available light minimum times, we discovered that the orbital period of DZ Psc may be undergoing a secular period increase with a cyclic variation. The modulated period and semi-amplitude of this oscillation are P mod = 11.89(± 0.19) yr and A = 0.0064(± 0.0006) days, which may be possibly attributed to either cyclic magnetic activity or light-time effect due to the third body. The long-term period increases at a rate of dP/dt=+7.43(+/- 0.17)\\times 10^{-7}{\\,days\\, yr^{-1}}, which may be interpreted as conserved mass transfer from the less massive component to the more massive one. With mass transferring, DZ Psc will finally merge into a rapid-rotation single star when J spin/J orb > 1/3.

  17. Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

    NASA Astrophysics Data System (ADS)

    Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

    2016-03-01

    A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

  18. Modeling the Transport and Chemical Evolution of Onshore and Offshore Emissions and their Impact on Local and Regional Air Quality Using a Variable-Grid-Resolution Air Quality Model

    SciTech Connect

    Kiran Alapaty; Adel Hanna

    2006-10-16

    This research project has two primary objectives: (1) to further develop and refine the Multiscale Air Quality Simulation Platform-Variable Grid Resolution (MAQSIP-VGR) model, an advanced variable-grid-resolution air quality model, to provide detailed, accurate representation of the dynamical and chemical processes governing the fate of anthropogenic emissions in coastal environments; and (2) to improve current understanding of the potential impact of onshore and offshore oil and gas exploration and production (E&P) emissions on O{sub 3} and particulate matter nonattainment in the Gulf of Mexico and surrounding states.

  19. A MacCormack-TVD finite difference method to simulate the mass flow in mountainous terrain with variable computational domain

    NASA Astrophysics Data System (ADS)

    Ouyang, Chaojun; He, Siming; Xu, Qiang; Luo, Yu; Zhang, Wencheng

    2013-03-01

    A two-dimensional mountainous mass flow dynamic procedure solver (Massflow-2D) using the MacCormack-TVD finite difference scheme is proposed. The solver is implemented in Matlab on structured meshes with variable computational domain. To verify the model, a variety of numerical test scenarios, namely, the classical one-dimensional and two-dimensional dam break, the landslide in Hong Kong in 1993 and the Nora debris flow in the Italian Alps in 2000, are executed, and the model outputs are compared with published results. It is established that the model predictions agree well with both the analytical solution as well as the field observations.

  20. Continental Land Mass Air Traffic Control (COLM ATC). [using three artificial satellite configurations

    NASA Technical Reports Server (NTRS)

    Pecar, J. A.; Henrich, J. E.

    1973-01-01

    The application of various satellite systems and techniques relative to providing air traffic control services for the continental United States was studied. Three satellite configurations were reviewed. The characteristics and capabilities of the satellites are described. The study includes consideration for the various ranging waveforms, multiple access alternatives, and the power and bandwidth required as a function of the number of users.

  1. Stellar modelling of Spica, a high-mass spectroscopic binary with a β Cep variable primary component

    NASA Astrophysics Data System (ADS)

    Tkachenko, A.; Matthews, J. M.; Aerts, C.; Pavlovski, K.; Pápics, P. I.; Zwintz, K.; Cameron, C.; Walker, G. A. H.; Kuschnig, R.; Degroote, P.; Debosscher, J.; Moravveji, E.; Kolbas, V.; Guenther, D. B.; Moffat, A. F. J.; Rowe, J. F.; Rucinski, S. M.; Sasselov, D.; Weiss, W. W.

    2016-05-01

    Binary stars provide a valuable test of stellar structure and evolution, because the masses of the individual stellar components can be derived with high accuracy and in a model-independent way. In this work, we study Spica, an eccentric double-lined spectroscopic binary system with a β Cep type variable primary component. We use state-of-the-art modelling tools to determine accurate orbital elements of the binary system and atmospheric parameters of both stellar components. We interpret the short-period variability intrinsic to the primary component, detected on top of the orbital motion both in the photometric and spectroscopic data. The non-local thermodynamic equilibrium based spectrum analysis reveals two stars of similar atmospheric chemical composition consistent with the present-day cosmic abundance standard. The masses and radii of the stars are found to be 11.43 ± 1.15 M⊙ and 7.21 ± 0.75 M⊙, and 7.47 ± 0.54 R⊙ and 3.74 ± 0.53 R⊙ for the primary and secondary, respectively. We find the primary component to pulsate in three independent modes, of which one is identified as a radial mode, while the two others are found to be non-radial, low degree l modes. The frequency of one of these modes is an exact multiple of the orbital frequency, and the l = m = 2 mode identification suggests a tidal nature for this particular mode. We find a very good agreement between the derived dynamical and evolutionary masses for the Spica system to within the observational errors of the measured masses. The age of the system is estimated to be 12.5 ± 1 Myr.

  2. Detection of biological particles in ambient air using Bio-Aerosol Mass Spectrometry

    SciTech Connect

    McJimpsey, E L; Steele, P T; Coffee, K R; Fergenson, D P; Riot, V J; Woods, B W; Gard, E E; Frank, M; Tobias, H J; Lebrilla, C

    2006-03-16

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described.

  3. Rainwater monocarboxylic and dicarboxylic acid concentrations in southeastern North Carolina, USA, as a function of air-mass back-trajectory

    NASA Astrophysics Data System (ADS)

    Brooks Avery, G.; Kieber, Robert J.; Witt, Melanie; Willey, Joan D.

    Eight organic acids were measured in 111 rain events occurring between September 1996 and May 1998 in Wilmington, North Carolina. Formic and acetic acids were the most abundant comprising approximately 75% of the total molar quantity of organic acids. The annual volume-weighted concentrations of organic acids in order of decreasing abundance in rainwater was formic (9.9 μM), acetic (7.3 μM), oxalic (1.8 μM), lactic (1.3 μM), succinic (1.0 μM), malonic (0.7 μM), pyruvic (0.3 μM), and maleic (0.1 μM), with methanesulfonic and glyoxylic acids usually below their detection limit. Growing season back-trajectory data provided strong evidence that terrestrial organic acid sources dominated over marine sources. Air mass back-trajectory analysis indicated that during the growing season air mass origin had a consistent impact on concentrations of rainwater organic acids. Rain with continental back-trajectories coming from the west had the highest concentrations of organic acids while two predominately marine back-trajectories had the lowest concentrations. Concentrations of organic acids in non-growing season rain did not display a consistent pattern indicating variability in sources. Seasonality of individual organic acids for specific back-trajectories was most pronounced in terrestrial back-trajectories and least in the marine back-trajectories indicating that seasonality in rainwater organic acid concentrations is driven by variations in terrestrial sources. Formic to acetic acid ratios (F:A), previously an indicator of terrestrial versus marine sources of these organic acids, were similar for all back-trajectories reflecting anthropogenic impacts on F:A locally and regionally. The ratios of malonic to succinic acids (M:S), also an indicator of sources for these acids, indicated direct anthropogenic sources for terrestrial back-trajectories and secondary processes for marine back-trajectories.

  4. Seasonal cycle and interannual variability of the total CH4 mixing ratios in West Siberia: Results from AIRS/AMSU and chemistry transport models for 2003-2013

    NASA Astrophysics Data System (ADS)

    Lagutin, Anatoly; Mordvin, Egor

    Methane (CH4) is an important greenhouse gas. It has much higher global warming potential comparing to carbon dioxide on per mass emitted basis. Atmospheric methane also plays an important role in atmospheric ozone chemistry and is the main source of water vapor in the stratosphere. The recent increase of CH4 in 2007-2008, after a nearly stable period of about one decade, is attributed to the increased emissions from tropical and Arctic wetlands. However, many uncertainties regarding natural and anthropogenic methane emissions still exist. For example, the total CH4 emissions from wetlands in West Siberia are estimated to be in the range from 1.6 to 20 Tg/year. The main causes leading to such large uncertainties are significant spatial and temporal variation of CH4 emissions and the sparseness of ground observational networks. The purpose of this study is to investigate the seasonal cycle and interannual variability of the total CH4 mixing ratios (CH4-Tot) in West Siberia for 2003-2013 using the AIRS/AMSU-Aqua measurements and the results from chemistry transport models MOZART4 and ACTM-CCSR/NIES/FRCGC. The key feature of the proposed approach is chemistry transport model-based regression equation linking CH4-Tot with mid-upper tropospheric CH4 (in the layer from 50 to 250 hPa below the tropopause), the tropopause height and the surface temperature. The observational information in our approach comes from the AIRS/AMSU measurements. Comparison of the retrieved CH4-Tot with the measurements of CH4 from the Total Carbon Column Observing Network (TCCON) have shown that the model captures observed seasonal cycles and interannual variability at mid-latitude sites. The spatial and temporal distributions of CH4-Tot in West Siberia for 2003-2013 are presented. Analysis of deseasonalized time-series indicates that the total CH4 mixing ratios increases about 4 ppbv/yr from 2007. This work was supported in part by the Russian Foundation for Basic Research (grant No 13

  5. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    SciTech Connect

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-09-18

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22 cm diameter and 30 cm length, purifies an airflow rate of 5000 lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application.

  6. Investigation on the variability of East Asia Boreal Summer Front Frequency and Linkage between Tropical Air Temperature

    NASA Astrophysics Data System (ADS)

    Choi, Eunho; Lim, Gyu-Ho

    2016-04-01

    Summer time front is one of the most significant phenomena over East Asia including China, Korea and Japan. Many efforts have been established to understand the nature of front. However, there was no research conducting identifying East Asia summer time fronts objectively. We have established objective front recognition method. The method follows next procedures : 1) We calculate vorticity on 850-hPa surface. 2) Any grid point that have horizontal gradient of equivalent potential temperature (EPT hereafter) on 850-hPa surface less than 4 'c / 100km set to zero. 3) Next, we smooth this field using 9-point smoothing technique. 4) Finally we extract the main axis of closed contour correspond to vorticity of 1.5 10-5s-5. Voronoi diagram used to extract this axis. We define this axis as front on 850-hPa pressure surface. We have applied the method on 1981-2010 ERA-Interim dataset. From the result, front frequency maximums are in around of East China Sea (34N, 122E), north (38N, 136E) and south (34N, 140E) of main island of Japan. Below 30N and above 40N, front frequency tends to decrease maybe due to decrease in the magnitude of gradient of EPT and the frequency of cyclonic weather disturbance. Two main regions affect the variability of East Asia Front Frequency. One is equatorial positive region especially over Taiwan (25N, 120E). The other one is East Sea next to Korea (40N, 135E). Humid warm air transported from southern China (20N-30N, 100E-110E) and dry cold air transported from northern China (30N-40N, 100E-110E) compressed by clockwise high system over Taiwan and counter-clockwise low system over East Sea). This compressed precipitation-making system or front moves by extratropical westerly and transported out to north-western Pacific. It looks like geopotential over Taiwan affected by tropical activity, especially vertical integration of temperature (VIT hereafter) over tropical region (30S-30N). When VIT is higher than normal, geopotential over Taiwan also

  7. An Infinite Order Discrete Variable Representation of an Effective Mass Hamiltonian: Application to Exciton Wave Functions in Quantum Confined Nanostructures.

    PubMed

    Kaledin, Alexey L; Lian, Tianquan; Hill, Craig L; Musaev, Djamaladdin G

    2014-08-12

    We describe an extension of the conventional Fourier grid discrete variable representation (DVR) to the bound state problem of a particle with a position-dependent mass. An infinite order DVR, derived for a variable mass kinetic energy operator, coupled with an efficient grid contraction scheme yields essentially exact eigenvalues for a chosen grid spacing. Implementation of the method is shown to be very practical due to the fact that in a DVR no integral evaluation is necessary and that the resultant kinetic energy matrix is sparse. Numerical calculations are presented for exciton states of spherical, cylindrical, and toric Type I (CdSe/ZnS) core-shell quantum dots. In these examples, electron-hole interaction is treated explicitly by solving a self-consistent Schrödinger-Poisson equation on a contracted DVR grid. Prospective applications of the developed approach to calculating electron transfer rates between adsorbed molecular acceptors and quantum confined nanocrystals of generic shape, dimensionality, and composition are also discussed.

  8. Variability in atmospheric particulates and meteorological effects on their mass concentrations over Delhi, India

    NASA Astrophysics Data System (ADS)

    Tiwari, S.; Bisht, D. S.; Srivastava, A. K.; Pipal, A. S.; Taneja, A.; Srivastava, M. K.; Attri, S. D.

    2014-08-01

    Simultaneous and continuous measurements of PM2.5 and PM10 along with other co-existent pollutants viz., black carbon (BC), CO, NO and NOx were carried out over Delhi with high resolution (5 min) datasets from 1st Sept. 2010 to 23rd Aug. 2012. Arithmetic mean mass concentrations of PM2.5 and PM10 were about 130 ± 103 and 222 ± 142 μg m- 3 respectively during the entire measurement period, which are considerably higher than the annual averages of PM2.5 and PM10, stipulated by the National and International standards. It was noticed that the fine mode particles (PM2.5) were higher than the coarse mode particles (PM10-2.5) during post-monsoon (~ 89%), winter (~ 69%) and monsoon (~ 64%) periods; however, PM10-2.5 was higher (~ 22%) than PM2.5 during summer. Arithmetic mean mass concentrations of BC, CO, NO and NOx were about 7 ± 5 μg m- 3, 2 ± 1 ppm, 17 ± 17 ppb and 30 ± 24 ppb, respectively. In the present study, highest fraction of BC (~ 6%) in PM2.5 mass was in winter, whereas the lowest fraction (~ 4%) was in summer. Relationships among PMs (particulate matters) and other pollutants indicated that the fine mode particles are highly correlated with BC (0.74) and CO (0.51). The effects of meteorological parameters on aerosols have been studied and a significant negative relationship (- 0.45) between mixing height (MH) and PM2.5 has been noticed. Higher correlation was during winter (- 0.55), however lower was in summer (- 0.16). Relation between visibility (VIS) and PM2.5 was higher during post-monsoon (- 0.85) and winter (- 0.78) when the visibility was around 2 km; however, it was relatively less correlated when VIS was greater than 2 km during summer and monsoon. Relationship between PM2.5 and relative humidity (RH) showed a significant negative correlation (- 0.56) for the entire study period. A positive correlation (0.32) was observed during the winter period with fine mode particles whereas negative correlation was seen with coarse mode particles during

  9. Smart tetroons for Lagrangian air-mass tracking during ACE 1

    NASA Astrophysics Data System (ADS)

    Businger, Steven; Johnson, Randy; Katzfey, Jack; Siems, Steven; Wang, Qing

    1999-05-01

    A series of "smart" tetroons was released from shipboard during the recent ACE 1 field experiment designed to monitor changes in the sulfur budget in a remote marine boundary layer (MBL) south of Tasmania, Australia. The smart tetroons were designed at NOAA Air Resources Laboratory Field Research Division to provide air parcel tracking information. The adjective smart here refers here to the fact that the buoyancy of the tetroons automatically adjusts through the action of a pump and valves when the tetroon travels vertically outside a range of pressures set prior to tetroon release. The smart tetroon design provides GPS location, barometric pressure, temperature, relative humidity, and tetroon status data via a transponder to the NCAR C-130 research aircraft flying in the vicinity of the tetroons. In this paper we will describe (1) the design and capability of the smart tetroons and their performance during the two Lagrangian experiments conducted during ACE 1, (2) the synoptic context of the Lagrangians, including the origin of the air parcels being tracked, and (3) the results of trajectory predictions derived from the National Center for Environmental Prediction (NCEP) Global Spectral Model (GSM) and Australia's Commonwealth Scientific and Industrial Research Organization (CSIRO) Division of Atmospheric Research (DAR) limited-area model.

  10. Luminous blue variables are antisocial: their isolation implies that they are kicked mass gainers in binary evolution

    NASA Astrophysics Data System (ADS)

    Smith, Nathan; Tombleson, Ryan

    2015-02-01

    Based on their relatively isolated environments, we argue that luminous blue variables (LBVs) must be primarily the product of binary evolution, challenging the traditional single-star view wherein LBVs mark a brief transition between massive O-type stars and Wolf-Rayet (WR) stars. If the latter were true, then LBVs should be concentrated in young massive clusters like early O-type stars. This is decidedly not the case. Examining locations of LBVs in our Galaxy and the Magellanic Clouds reveals that, with only a few exceptions, LBVs systematically avoid clusters of O-type stars. In the Large Magellanic Cloud, LBVs are statistically much more isolated than O-type stars, and (perhaps most surprisingly) even more isolated than WR stars. This makes it impossible for LBVs to be single `massive stars in transition' to WR stars. Instead, we propose that massive stars and supernova (SN) subtypes are dominated by bifurcated evolutionary paths in interacting binaries, wherein most WR stars and Type Ibc supernovae (SNe Ibc) correspond to the mass donors, while LBVs (and their lower mass analogues like B[e] supergiants, which are even more isolated) are the mass gainers. In this view, LBVs are evolved massive blue stragglers. Through binary mass transfer, rejuvinated mass gainers get enriched, spun up, and sometimes kicked far from their clustered birth sites by their companion's SN. This scenario agrees better with LBVs exploding as SNe IIn in isolation, and it predicts that many massive runaway stars may be rapid rotators. Mergers or blue Thorne-Zytkow-like objects might also give rise to LBVs, but these scenarios may have a harder time explaining why LBVs avoid clusters.

  11. Mass transfer of volatile organic compounds from drinking water to indoor air: The role of residential dishwashers

    SciTech Connect

    Howard-Reed, C.; Corsi, R.L.; Moya, J.

    1999-07-01

    Contaminated tap water may be a source of volatile organic compounds (VOCs) in residential indoor air. To better understand the extent and impact of chemical emissions from this source, a two-phase mass balance model was developed based on mass transfer kinetics between each phase. Twenty-nine experiments were completed using a residential dishwasher to determine model parameters. During each experiment, inflow water was spiked with a cocktail of chemical tracers with a wide range of physicochemical properties. In each case, the effects of water temperature, detergent, and dish-loading pattern on chemical stripping efficiencies and mass transfer coefficients were determined. Dishwasher headspace ventilation rates were also measured using an isobutylene tracer gas. Chemical stripping efficiencies for a single cycle ranged from 18% to 55% for acetone, from 96% to 98% for toluene, and from 97% to 98% for ethylbenzene and were consistently 100% for cyclohexane. Experimental results indicate that dishwashers have a relatively low but continuous ventilation rate that results in significant chemical storage within the headspace of the dishwasher. In conjunction with relatively high mass transfer coefficients, low ventilation rates generally lead to emissions that are limited by equilibrium conditions after approximately 1--2 min of dishwasher operation.

  12. Insights into the Earth System mass variability from CSR-RL05 GRACE gravity fields

    NASA Astrophysics Data System (ADS)

    Bettadpur, S.

    2012-04-01

    The next-generation Release-05 GRACE gravity field data products are the result of extensive effort applied to the improvements to the GRACE Level-1 (tracking) data products, and to improvements in the background gravity models and processing methodology. As a result, the squared-error upper-bound in RL05 fields is half or less than the squared-error upper-bound in RL04 fields. The CSR-RL05 field release consists of unconstrained gravity fields as well as a regularized gravity field time-series that can be used for several applications without any post-processing error reduction. This paper will describe the background and the nature of these improvements in the data products, and provide an error characterization. We will describe the insights these new series offer in measuring the mass flux due to diverse Hydrologic, Oceanographic and Cryospheric processes.

  13. Precession-driven monsoon variability at the Permian-Triassic boundary — Implications for anoxia and the mass extinction

    NASA Astrophysics Data System (ADS)

    Winguth, Arne; Winguth, Cornelia

    2013-06-01

    By the end of the Late Permian, most continents had collided to form the supercontinent of Pangea. The associated climatic changes at the Permian-Triassic boundary coincided with the most severe mass extinction in the Phanerozoic. One extinction hypothesis favors a climatic response to an increase in large-scale volcanism resulting in ocean stagnation and widespread anoxia with fatal consequences for marine and land organisms. Recent interpretations of geochemical data suggest that orbitally-driven periodic upwelling of toxic hydrogen-sulfide rich water masses contributed to the extinction of species. In this paper, we use the Community Climate System Model (CCSM3) in order to explore the effect of eccentricity-modulated changes of the precession on the strength of Pangean megamonsoons and their impact on productivity and oxygen distribution. The climate model simulates high variability in monsoonal precipitation, trade winds and equatorial upwelling in response to precessional extremes, leading to remarkable fluctuations in the export of carbon from the euphotic zone and hence reduction in dissolved oxygen concentrations in subsurface layers. These findings are in general agreement with increased primary productivity, intensified euxinia within the oxygen-minimum zone, and decimation of the radiolarian zooplankton community as inferred from Japanese marine sections. Strong changes in river run-off linked to precipitation oscillations possibly led to a high variability in the nutrient supply to the Tethys Ocean, thus affecting regional productivity and oxygen distribution. The model results suggest that orbital variability in the sedimentary record and the associated extinction of species are related rather to periodic anoxia in near surface-to-intermediate depth than to widespread anoxic events in the Panthalassic deep-sea.

  14. Anthropogenic impact on Antarctic surface mass balance, currently masked by natural variability, to emerge by mid-century

    NASA Astrophysics Data System (ADS)

    Previdi, Michael; Polvani, Lorenzo M.

    2016-09-01

    Global and regional climate models robustly simulate increases in Antarctic surface mass balance (SMB) during the twentieth and twenty-first centuries in response to anthropogenic global warming. Despite these robust model projections, however, observations indicate that there has been no significant change in Antarctic SMB in recent decades. We show that this apparent discrepancy between models and observations can be explained by the fact that the anthropogenic climate change signal during the second half of the twentieth century is small compared to the noise associated with natural climate variability. Using an ensemble of 35 global coupled climate models to separate signal and noise, we find that the forced SMB increase due to global warming in recent decades is unlikely to be detectable as a result of large natural SMB variability. However, our analysis reveals that the anthropogenic impact on Antarctic SMB is very likely to emerge from natural variability by the middle of the current century, thus mitigating future increases in global sea level.

  15. Interaction of clothing and body mass index affects validity of air displacement plethysmography in adults

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Objective: Examine the effect of alternate clothing schemes on validity of Bod Pod to estimate percent body fat (BF) compared to dual x-ray absorptiometry (DXA), and determine if these effects differ by body mass index (BMI). Design: Cross-sectional Subjects: 132 healthy adults aged 19-81 classifi...

  16. Evaluating the Contribution of Natural Variability and Climate Model Response to Uncertainty in Projections of Climate Change Impacts on U.S. Air Quality

    EPA Science Inventory

    We examine the effects of internal variability and model response in projections of climate impacts on U.S. ground-level ozone across the 21st century using integrated global system modeling and global atmospheric chemistry simulations. The impact of climate change on air polluti...

  17. Determination of cooling air mass flow for a horizontally-opposed aircraft engine installation

    NASA Technical Reports Server (NTRS)

    Miley, S. J.; Cross, E. J., Jr.; Ghomi, N. A.; Bridges, P. D.

    1979-01-01

    The relationship between the amount of cooling air flow and the corresponding flow pressure difference across an aircraft engine was investigated in flight and on the ground. The flight test results were consistent with theory, but indicated a significant installation leakage problem. A ground test blower system was used to identify and reduce the leakage. The correlation between ground test cell determined engine orifice characteristics and flight measurements showed good agreement if the engine pressure difference was based on total pressure rather than static pressure.

  18. Long-term continuous measurement of near-road air pollution in Las Vegas: Seasonal variability in traffic emissions impact on local air quality

    EPA Science Inventory

    Excess air pollution along roadways is an issue of public health concern and motivated a long-term measurement effort established by the U.S. Environmental Protection Agency in Las Vegas, Nevada. Measurements of air pollutants – including black carbon (BC), carbon monoxide (CO),...

  19. Large Scale Variability of Mid-Tropospheric Carbon Dioxide as Observed by the Atmospheric Infrared Sounder (AIRS) on the NASA EOS Aqua Platform

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Olsen, Edward T.

    2012-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 microns to 15.4 microns and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy, water vapor profiles (20%/2km), infrared cloud height and fraction, and trace gas amounts for CO2, CO, SO2, O3 and CH4 in the mid to upper troposphere. AIRS wide swath(cedilla) +/-49.5 deg , enables daily global daily coverage for over 95% of the Earth's surface. AIRS data are used for weather forecasting, validating climate model distribution and processes, and observing long-range transport of greenhouse gases. In this study, we examine the large scale and regional horizontal variability in the AIRS Mid-tropospheric Carbon Dioxide product as a function of season and associate the observed variability with known atmospheric transport processes, and sources and sinks of CO2.

  20. An air-mass trajectory study of the transport of radioactivity from Fukushima to Thessaloniki, Greece and Milan, Italy

    NASA Astrophysics Data System (ADS)

    Ioannidou, A.; Giannakaki, E.; Manolopoulou, M.; Stoulos, S.; Vagena, E.; Papastefanou, C.; Gini, L.; Manenti, S.; Groppi, F.

    2013-08-01

    Analyses of 131I, 137Cs and 134Cs in airborne aerosols were carried out in daily samples at two different sites of investigation: Thessaloniki, Greece (40° N) and Milan, Italy (45° N) after the Fukushima accident during the period of March-April, 2011. The radionuclide concentrations were determined and studied as a function of time. The 131I concentration in air over Milan and Thessaloniki peaked on April 3-4, 2011, with observed activities 467 μBq m-3 and 497 μBq m-3, respectively. The 134Cs/137Cs activity ratio values in air were around 1 in both regions, related to the burn-up history of the damaged nuclear fuel of the destroyed nuclear reactor. The high 131I/137Cs ratio, observed during the first days after the accident, followed by lower values during the following days, reflects not only the initial release ratio but also the different volatility, attachment and removal of the two isotopes during transportation due to their different physico-chemical properties. No artificial radionuclides could be detected in air after April 28, 2011 in both regions of investigation. The different maxima of airborne 131I and 134,137Cs in these two regions were related to long-range air mass transport from Japan, across the Pacific and to Central Europe. Analysis of backward trajectories was used to confirm the arrival of artificial radionuclides following atmospheric transport and processing. HYSPLIT backward trajectories were applied for the interpretation of activity variations of measured radionuclides.

  1. Numerical simulation for the influence of laser-induced plasmas addition on air mass capture of hypersonic inlet

    NASA Astrophysics Data System (ADS)

    Zhao, Wei; Dou, Zhiguo; Li, Qian

    2012-03-01

    The theory of laser-induced plasmas addition to hypersonic airflow off a vehicle to increase air mass capture and improve the performance of hypersonic inlets at Mach numbers below the design value is explored. For hypersonic vehicles, when flying at mach numbers lower than the design one, we can increase the mass capture ratio of inlet through laser-induced plasmas injection to the hypersonic flow upstream of cowl lip to form a virtual cowl. Based on the theory, the model of interaction between laser-induced plasmas and hypersonic flow was established. The influence on the effect of increasing mass capture ratio was studied at different positions of laser-induced plasmas region for the external compression hypersonic inlet at Mach 5 while the design value is 6, the power of plasmas was in the range of 1-8mJ. The main results are as follows: 1. the best location of the plasma addition region is near the intersection of the nose shock of the vehicle with the continuation of the cowl line, and slightly below that line. In that case, the shock generated by the heating is close to the shock that is a reflection of the vehicle nose shock off the imaginary solid surface-extension of the cowl. 2. Plasma addition does increase mass capture, and the effect becomes stronger as more energy is added, the peak value appeared when the power of plasma was about 4mJ, when the plasma energy continues to get stronger, the mass capture will decline slowly.

  2. Petroleomics by electrospray ionization FT-ICR mass spectrometry coupled to partial least squares with variable selection methods: prediction of the total acid number of crude oils.

    PubMed

    Terra, Luciana A; Filgueiras, Paulo R; Tose, Lílian V; Romão, Wanderson; de Souza, Douglas D; de Castro, Eustáquio V R; de Oliveira, Mirela S L; Dias, Júlio C M; Poppi, Ronei J

    2014-10-01

    Negative-ion mode electrospray ionization, ESI(-), with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was coupled to a Partial Least Squares (PLS) regression and variable selection methods to estimate the total acid number (TAN) of Brazilian crude oil samples. Generally, ESI(-)-FT-ICR mass spectra present a power of resolution of ca. 500,000 and a mass accuracy less than 1 ppm, producing a data matrix containing over 5700 variables per sample. These variables correspond to heteroatom-containing species detected as deprotonated molecules, [M - H](-) ions, which are identified primarily as naphthenic acids, phenols and carbazole analog species. The TAN values for all samples ranged from 0.06 to 3.61 mg of KOH g(-1). To facilitate the spectral interpretation, three methods of variable selection were studied: variable importance in the projection (VIP), interval partial least squares (iPLS) and elimination of uninformative variables (UVE). The UVE method seems to be more appropriate for selecting important variables, reducing the dimension of the variables to 183 and producing a root mean square error of prediction of 0.32 mg of KOH g(-1). By reducing the size of the data, it was possible to relate the selected variables with their corresponding molecular formulas, thus identifying the main chemical species responsible for the TAN values.

  3. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  4. Flow of variably fluidized granular masses across three-dimensional terrain I. Coulomb mixture theory

    USGS Publications Warehouse

    Iverson, R.M.; Denlinger, R.P.

    2001-01-01

    Rock avalanches, debris flows, and related phenomena consist of grain-fluid mixtures that move across three-dimensional terrain. In all these phenomena the same basic forces, govern motion, but differing mixture compositions, initial conditions, and boundary conditions yield varied dynamics and deposits. To predict motion of diverse grain-fluid masses from initiation to deposition, we develop a depth-averaged, threedimensional mathematical model that accounts explicitly for solid- and fluid-phase forces and interactions. Model input consists of initial conditions, path topography, basal and internal friction angles of solid grains, viscosity of pore fluid, mixture density, and a mixture diffusivity that controls pore pressure dissipation. Because these properties are constrained by independent measurements, the model requires little or no calibration and yields readily testable predictions. In the limit of vanishing Coulomb friction due to persistent high fluid pressure the model equations describe motion of viscous floods, and in the limit of vanishing fluid stress they describe one-phase granular avalanches. Analysis of intermediate phenomena such as debris flows and pyroclastic flows requires use of the full mixture equations, which can simulate interaction of high-friction surge fronts with more-fluid debris that follows. Special numerical methods (described in the companion paper) are necessary to solve the full equations, but exact analytical solutions of simplified equations provide critical insight. An analytical solution for translational motion of a Coulomb mixture accelerating from rest and descending a uniform slope demonstrates that steady flow can occur only asymptotically. A solution for the asymptotic limit of steady flow in a rectangular channel explains why shear may be concentrated in narrow marginal bands that border a plug of translating debris. Solutions for static equilibrium of source areas describe conditions of incipient slope instability

  5. Influence of dissolved humic substances on the mass transfer of organic compounds across the air-water interface.

    PubMed

    Ramus, Ksenia; Kopinke, Frank-Dieter; Georgi, Anett

    2012-01-01

    The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal.

  6. A temperature-based variable for monitoring outdoor coil airflow in an air-source heat pump during frost-forming conditions

    SciTech Connect

    Payne, W.V. II; O`Neal, D.L.

    1994-12-31

    Frost-buildup tests were conducted on a 3-ton (10.6kW) nominal cooling capacity air-source heat pump with an orifice expansion device. This study was conducted to determine if a simple temperature-based control variable could be used to determine the amount of degradation in the outdoor airflow (and heating capacity) of the unit. Refrigerant pressures and temperatures were monitored through-out the system in addition to power requirements and airflow rates. A temperature-based variable was developed that could be used to predict airflow degradation across the outdoor heat exchanger. This variable was defined using the difference between ambient air temperature and a measured refrigerant temperature. Eight refrigerant temperatures in the system were recorded and evaluated. Plots of airflow as a function of this temperature variable, along with plots of the absolute value percent changes of this temperature variable and airflow, were evaluated to determine which refrigerant temperatures could best be used in the variable to predict degradation in airflow. The best fit between the temperature-based variable and airflow degradation occurred with the inclusion of the refrigerant temperature at the outlet from the evaporator. Calculations of percent changes based on values sampled after a defrost showed a polynomial or linear relationship between airflow and the temperature-based variable. Data from two previously tested heat pumps were also used to compare changes in the outdoor airflow to changes in the temperature-based variable. The base-case heat pump and another heat pump both used an orifice as the expansion device in the heating mode. A third heat pump, which used a thermostatic expansion valve (TXV) as the expansion device in the heating mode, failed to show the same goodness of fit between airflow and the temperature-based variable.

  7. Traffic-Related Air Pollution and Acute Changes in Heart Rate Variability and Respiratory Function in Urban Cyclists

    PubMed Central

    Kulka, Ryan; Dubeau, Aimee; Martin, Christina; Wang, Daniel; Dales, Robert

    2011-01-01

    Background: Few studies have examined the acute health effects of air pollution exposures experienced while cycling in traffic. Objectives: We conducted a crossover study to examine the relationship between traffic pollution and acute changes in heart rate variability. We also collected spirometry and exhaled nitric oxide measures. Methods: Forty-two healthy adults cycled for 1 hr on high- and low-traffic routes as well as indoors. Health measures were collected before cycling and 1–4 hr after the start of cycling. Ultrafine particles (UFPs; ≤ 0.1 μm in aerodynamic diameter), particulate matter ≤ 2.5 μm in aerodynamic diameter (PM2.5), black carbon, and volatile organic compounds were measured along each cycling route, and ambient nitrogen dioxide (NO2) and ozone (O3) levels were recorded from a fixed-site monitor. Mixed-effects models were used to estimate associations between air pollutants and changes in health outcome measures relative to precycling baseline values. Results: An interquartile range increase in UFP levels (18,200/cm3) was associated with a significant decrease in high-frequency power 4 hr after the start of cycling [β = –224 msec2; 95% confidence interval (CI), –386 to –63 msec2]. Ambient NO2 levels were inversely associated with the standard deviation of normal-to-normal (NN) intervals (β = –10 msec; 95% CI, –20 to –0.34 msec) and positively associated with the ratio of low-frequency to high-frequency power (β = 1.4; 95% CI, 0.35 to 2.5) 2 hr after the start of cycling. We also observed significant inverse associations between ambient O3 levels and the root mean square of successive differences in adjacent NN intervals 3 hr after the start of cycling. Conclusions: Short-term exposures to traffic pollution may contribute to altered autonomic modulation of the heart in the hours immediately after cycling. PMID:21672679

  8. Systematics of Rotational Bands in Odd-Mass Nuclei on the Basis of the Variable Moment of Inertia Model

    SciTech Connect

    Mitropolsky, I.

    2005-05-24

    On the grounds of a file of the evaluated nuclear data ENSDF, the most complete compilation of rotational bands in odd-A nuclei with mass numbers 43{<=}A{<=}253 is presented. The processing of experimental data has been carried out on the basis of generalization of the variable moment of inertia model for axial strong deformed nuclei, which is taking into account the decoupling effect for bands with K=1/2. The good description of rotational energies for the majority of rotational bands is obtained and the systematic behavior of the model parameters in all areas of the deformed nuclei is shown. The theoretical description was used for association of fragments of rotational bands, exclusion of 'superfluous' levels and prediction of a placement of 'missed' levels.

  9. Modelling aperiodic X-ray variability in black hole binaries as propagating mass accretion rate fluctuations: A short review

    NASA Astrophysics Data System (ADS)

    Ingram, A. R.

    2016-05-01

    Black hole binary systems can emit very bright and rapidly varying X-ray signals when material from the companion accretes onto the black hole, liberating huge amounts of gravitational potential energy. Central to this process of accretion is turbulence. In the propagating mass accretion rate fluctuations model, turbulence is generated throughout the inner accretion flow, causing fluctuations in the accretion rate. Fluctuations from the outer regions propagate towards the black hole, modulating the fluctuations generated in the inner regions. Here, I present the theoretical motivation behind this picture before reviewing the array of statistical variability properties observed in the light curves of black hole binaries that are naturally explained by the model. I also discuss the remaining challenges for the model, both in terms of comparison to data and in terms of including more sophisticated theoretical considerations.

  10. The Infrared Variability of GX17+2 and Low-Mass X-ray Binary Jets

    NASA Astrophysics Data System (ADS)

    McNamara, Bernard J.; Bornak, J.; Harrison, T.; Rupen, M.

    2007-12-01

    GX17+2 is a low-mass X-ray binary. It is also classified as a Z-source since it exhibits a distinctive Z-pattern in its X-ray color-color plot. GX17+2 is located in the direction of the galactic center and is not detectable at optical wavelengths. Its emission varies by over 4 magnitudes in the infrared. A number of explanations have been advanced to explain this variabilty. Based upon KPNO and Smarts IR observations, we suggest that it arises from a sychrotron jet which is periodically visible along our line of sight. This circumstance provides a rather unique opportunity to quantify a number of jet properties such as its opening angle, the sharpness of the jet boundaries, its variability, and the infrared emission uniformity across the jet.

  11. Uncertainties in Modelling Glacier Melt and Mass Balances: the Role of Air Temperature Extrapolation and Type of Melt Models

    NASA Astrophysics Data System (ADS)

    Pellicciotti, F.; Ragettli, S.; Carenzo, M.; Ayala, A.; McPhee, J. P.; Stoffel, M.

    2014-12-01

    While glacier responses to climate are understood in general terms and in their main trends, model based projections are affected by the type of model used and uncertainties in the meteorological input data, among others. Recent works have attempted at improving glacio-hydrological models by including neglected processes and investigating uncertainties in their outputs. In this work, we select two knowledge gaps in current modelling practices and illustrate their importance through modelling with a fully distributed mass balance model that includes some of the state of the art approaches for calculations of glacier ablation, accumulation and glacier geometry changes. We use an advanced mass balance model applied to glaciers in the Andes of Chile, Swiss Alps and Nepalese Himalaya to investigate two issues that seem of importance for a sound assessment of glacier changes: 1) the use of physically-based models of glacier ablation (energy balance) versus more empirical models (enhanced temperature index approaches); 2) the importance of the correct extrapolation of air temperature forcing on glaciers and the large uncertainty in model outputs associated with it. The ablation models are calibrated with a large amount of data from in-situ campaigns, and distributed observations of air temperature used to calculate lapse rates and calibrate a thermodynamic model of temperature distribution. We show that no final assessment can be made of what type of melt model is more appropriate or accurate for simulation of glacier ablation at the glacier scale, not even for relatively well studied glaciers. Both models perform in a similar manner at low elevations, but important differences are evident at high elevations, where lack of data prevents a final statement on which model better represent the actual ablation amounts. Accurate characterization of air temperature is important for correct simulations of glacier mass balance and volume changes. Substantial differences are

  12. The impacts of short-term exposure to noise and traffic-related air pollution on heart rate variability in young healthy adults.

    PubMed

    Huang, Jing; Deng, Furong; Wu, Shaowei; Lu, Henry; Hao, Yu; Guo, Xinbiao

    2013-01-01

    Traffic-related air pollution and noise are associated with cardiovascular diseases, and alternation of heart rate variability (HRV), which reflects cardiac autonomic function, is one of the mechanisms. However, few studies considered the impacts of noise when exploring associations between air pollution and HRV. We explored whether noise modifies associations between short-term exposure to traffic-related air pollution and HRV in young healthy adults. In this randomized, crossover study, 40 young healthy adults stayed for 2 h in a traffic center and, on a separate occasion, in a park. Personal exposure to traffic-related air pollutants and noise were measured and ambulatory electrocardiogram was performed. Effects were estimated using mixed-effects regression models. Traffic-related air pollution and noise were both associated with HRV, and effects of air pollutants were amplified at high noise level (>65.6 A-weighted decibels (dB[A])) compared with low noise level (≤ 65.6 dB[A]). High frequency (HF) decreased by -4.61% (95% confidence interval, -6.75% to-2.42%) per 10 μg/m(3) increment in fine particle (PM2.5) at 5-min moving average, but effects became insignificant at low noise level (P>0.05). Similar effects modification was observed for black carbon (BC) and carbon monoxide (CO). We conclude that noise is an important factor influencing the effects of air pollution on HRV.

  13. Variability of carbonaceous aerosols in remote, rural, urban and industrial environments in Spain: implications for air quality policy

    NASA Astrophysics Data System (ADS)

    Querol, X.; Alastuey, A.; Viana, M.; Moreno, T.; Reche, C.; Minguillón, M. C.; Ripoll, A.; Pandolfi, M.; Amato, F.; Karanasiou, A.; Pérez, N.; Pey, J.; Cusack, M.; Vázquez, R.; Plana, F.; Dall'Osto, M.; de la Rosa, J.; de la Campa Sánchez, A.; Fernández-Camacho, R.; Rodríguez, S.; Pío, C.; Alados-Arboledas, L.; Titos, G.; Artíñano, B.; Salvador, P.; Dos Santos García, S.; Patier Fernández, R.

    2013-03-01

    We interpret here the variability of levels of carbonaceous aerosols based on a 12-yr database from 78 monitoring stations across Spain especially compiled for this article. Data did not evidence any spatial trends of carbonaceous aerosols across the country. Conversely, results show marked differences in average concentrations from the cleanest, most remote sites (around 1 μg m-3 of non-mineral carbon (nmC), mostly made of organic carbon (OC), with very little elemental carbon (EC) 0.1 μg m-3; OC/EC = 12-15), to the highly polluted major cities (8-10 μg m-3 of nmC; 3-4 μg m-3 of EC; 4-5 μg m-3 of OC; OC/EC = 1-2). Thus, urban (and very specific industrial) pollution was found to markedly increase levels of carbonaceous aerosols in Spain, with much lower impact of biomass burning. Correlations between yearly averaged OC/EC and EC concentrations adjust very well to a potential equation (OC/EC = 3.37 EC-0.67 R2 = 0.94). A similar equation is obtained when including average concentrations obtained at other European sites (y = 3.61x-0.5, R2 = 0.78). A clear seasonal variability in OC and EC concentrations was detected. Both OC and EC concentrations were higher during winter at the traffic and urban sites, but OC increased during the warmer months at the rural sites. Hourly equivalent black carbon (EBC) concentrations at urban sites accurately depict road traffic contributions, varying with distance to road, traffic volume and density, mixing layer height and wind speed. Weekday urban rush-hour EBC peaks are mimicked by concentrations of primary gaseous emissions from road traffic, whereas a single midday peak is characteristic of remote and rural sites. Decreasing annual trends for carbonaceous aerosols were observed between 1999 and 2011 at a large number of stations, probably reflecting the impact of the EURO4 and EURO5 standards in reducing the diesel PM emissions. This has resulted in some cases in an increasing trend of NO2/OC+EC ratios, because these

  14. Variability of carbonaceous aerosols in remote, rural, urban and industrial environments in Spain: implications for air quality policy

    NASA Astrophysics Data System (ADS)

    Querol, X.; Alastuey, A.; Viana, M.; Moreno, T.; Reche, C.; Minguillón, M. C.; Ripoll, A.; Pandolfi, M.; Amato, F.; Karanasiou, A.; Pérez, N.; Pey, J.; Cusack, M.; Vázquez, R.; Plana, F.; Dall'Osto, M.; de la Rosa, J.; Sánchez de la Campa, A.; Fernández-Camacho, R.; Rodríguez, S.; Pio, C.; Alados-Arboledas, L.; Titos, G.; Artíñano, B.; Salvador, P.; García Dos Santos, S.; Fernández Patier, R.

    2013-07-01

    We interpret here the variability of levels of carbonaceous aerosols based on a 12 yr database from 78 monitoring stations across Spain specially compiled for this article. Data did not evidence any spatial trends of carbonaceous aerosols across the country. Conversely, results show marked differences in average concentrations from the cleanest, most remote sites (around 1 μg m-3 of non-mineral carbon (nmC), mostly made of organic carbon (OC) with very little elemental carbon (EC), around 0.1 μg m-3; OC / EC = 12-15), to the highly polluted major cities (8-10 μg m-3 of nmC; 3-4 μg m-3 of EC; 4-5 μg m-3 of OC; OC / EC = 1-2). Thus, urban (and very specific industrial) pollution was found to markedly increase levels of carbonaceous aerosols in Spain, with much lower impact of biomass burning and of biogenic emissions. Correlations between yearly averaged OC / EC and EC concentrations adjust very well to a potential equation (OC = 3.37 EC0.326, R2 = 0.8). A similar equation is obtained when including average concentrations obtained at other European sites (OC = 3.60EC0.491, R2 = 0.7). A clear seasonal variability in OC and EC concentrations was detected. Both OC and EC concentrations were higher during winter at the traffic and urban sites, but OC increased during the warmer months at the rural sites. Hourly equivalent black carbon (EBC) concentrations at urban sites accurately depict road traffic contributions, varying with distance from road, traffic volume and density, mixing-layer height and wind speed. Weekday urban rush-hour EBC peaks are mimicked by concentrations of primary gaseous emissions from road traffic, whereas a single midday peak is characteristic of remote and rural sites. Decreasing annual trends for carbonaceous aerosols were observed between 1999 and 2011 at a large number of stations, probably reflecting the impact of the EURO4 and EURO5 standards in reducing the diesel PM emissions. This has resulted in some cases in an increasing trend for

  15. Wind variability and sheltering effects on measurements and modeling of air-water exchange for a small lake

    NASA Astrophysics Data System (ADS)

    Markfort, Corey D.; Resseger, Emily; Porté-Agel, Fernando; Stefan, Heinz

    2014-05-01

    Lakes with a surface area of less than 10 km2 account for over 50% of the global cumulative lake surface water area, and make up more than 99% of the total number of global lakes, ponds, and wetlands. Within the boreal regions as well as some temperate and tropical areas, a significant proportion of land cover is characterized by lakes or wetlands, which can have a dramatic effect on land-atmosphere fluxes as well as the local and regional energy budget. Many