Science.gov

Sample records for air sea fluxes

  1. The Measurement of Air-Sea Fluxes

    DTIC Science & Technology

    1990-10-09

    induced by the motion of the wave (in a wave following coordinate system the rotor appears as an eddy in the wave trough). Strictly speaking, this is a...Droplet distribution and dispersion processes on breaking wind waves . jai. e . Tohoku University er. , Geophysics, 21, 1-25. Lai R.J. and O.H. Shemdin ...seaspray, Chapter 10 in Surface Waves and Fluxes: Current Theory ana Remote Sensing, G. Geernaert and W. Plant, Ed., Reidel, Holland. -4- 1 I 3. Fairall

  2. Parameterization of air sea gas fluxes at extreme wind speeds

    NASA Astrophysics Data System (ADS)

    McNeil, Craig; D'Asaro, Eric

    2007-06-01

    Air-sea flux measurements of O 2 and N 2 obtained during Hurricane Frances in September 2004 [D'Asaro, E. A. and McNeil, C. L., 2006. Measurements of air-sea gas exchange at extreme wind speeds. Journal Marine Systems, this edition.] using air-deployed neutrally buoyant floats reveal the first evidence of a new regime of air-sea gas transfer occurring at wind speeds in excess of 35 m s - 1 . In this regime, plumes of bubbles 1 mm and smaller in size are transported down from near the surface of the ocean to greater depths by vertical turbulent currents with speeds up to 20-30 cm s - 1 . These bubble plumes mostly dissolve before reaching a depth of approximately 20 m as a result of hydrostatic compression. Injection of air into the ocean by this mechanism results in the invasion of gases in proportion to their tropospheric molar gas ratios, and further supersaturation of less soluble gases. A new formulation for air-sea fluxes of weakly soluble gases as a function of wind speed is proposed to extend existing formulations [Woolf, D.K, 1997. Bubbles and their role in gas exchange. In: Liss, P.S., and Duce, R.A., (Eds.), The Sea Surface and Global Change. Cambridge University Press, Cambridge, UK, pp. 173-205.] to span the entire natural range of wind speeds over the open ocean, which includes hurricanes. The new formulation has separate contributions to air-sea gas flux from: 1) non-supersaturating near-surface equilibration processes, which include direct transfer associated with the air-sea interface and ventilation associated with surface wave breaking; 2) partial dissolution of bubbles smaller than 1 mm that mix into the ocean via turbulence; and 3) complete dissolution of bubbles of up to 1 mm in size via subduction of bubble plumes. The model can be simplified by combining "surface equilibration" terms that allow exchange of gases into and out of the ocean, and "gas injection" terms that only allow gas to enter the ocean. The model was tested against the

  3. Distribution and air-sea fluxes of carbon dioxide on the Chukchi Sea shelf

    NASA Astrophysics Data System (ADS)

    Pipko, I. I.; Pugach, S. P.; Repina, I. A.; Dudarev, O. V.; Charkin, A. N.; Semiletov, I. P.

    2015-12-01

    This article presents the results of long-term studies of the dynamics of carbonate parameters and air-sea carbon dioxide fluxes on the Chukchi Sea shelf during the summer. As a result of the interaction of physical and biological factors, the surface waters on the west of Chukchi Sea were undersaturated with carbon dioxide when compared with atmospheric air; the partial pressure of CO2 varied in the range from 134 to 359 μatm. The average value of CO2 flux in the Chukchi Sea per unit area varied in the range from-2.4 to-22.0 mmol /(m2 day), which is significantly higher than the average value of CO2 flux in the World Ocean. It has been estimated that the minimal mass of C absorbed by the surface of Chukchi Sea from the atmosphere during ice-free season is 13 × 1012 g; a great part of this carbon is transported to the deeper layers of sea and isolated from the atmosphere for a long period of time. The studies of the carbonate system of the Chukchi Sea, especially of its western part, will provide some new data on the fluxes of carbon dioxide in the Arctic Ocean and their changes. Our analysis can be used for an interpretation of the satellite assessment of CO2 fluxes and dissolved CO2 distribution in the upper layers of the ocean.

  4. Influence of surface kinematics on air-sea heat flux

    NASA Astrophysics Data System (ADS)

    Veron, Fabrice; Melville, Ken

    2004-11-01

    The top few meters of the oceanic boundary layer play a critical role in the transfers of momentum, gas, mass and heat between the atmosphere and the ocean. These exchanges must necessarily transfer through the surface, and presumably, the rates at which they do are influence by the dynamics of the surface layer. Heat flux in particular is regulated by the thin surface thermal layer which, at most, is only a few millimeter thick. We are specifically interested in the influence of small coherent structures of the surface turbulence on the heat flux. Using active and passive infrared imaging, we measured the evolution the surface velocity and temperature fields over small areas of a few square meters. High-resolution surface Eulerian velocity fields using cross-correlation techniques (PIV) are obtained. Using active marking of the surface with an infrared CO2 laser, we have not only shown that it is possible to directly recover the Langrangian surface velocity, but also, by marking appropriate patterns on the surface we have been able to measure the shear strain, vorticity, and surface divergence. With the penetration depth of infrared radiation at these wavelengths being a few microns, these techniques appear to be quite apt for direct measurements of ocean surface turbulence. We have also found that the flux of heat through the surface appears to be influenced by the surface wave field. We will discuss the results in the context of air sea heat flux and ocean surface turbulence.

  5. Air-sea fluxes and surface layer turbulence around a sea surface temperature front

    NASA Technical Reports Server (NTRS)

    Friehe, C. A.; Shaw, W. J.; Davidson, K. L.; Rogers, D. P.; Large, W. G.; Stage, S. A.; Crescenti, G. H.; Khalsa, S. J. S.; Greenhut, G. K.; Li, F.

    1991-01-01

    The observed effects of sharp changes in sea surface temperature (SST) on the air-sea fluxes, surface roughness, and the turbulence structure in the surface layer and the marine atmospheric boundary layer are discussed. In situ flux and turbulence observations were carried out from three aircraft and two ships within the FASINEX framework. Three other aircraft used remote sensors to measure waves, microwave backscatter, and lidar signatures of cloud tops. Descriptions of the techniques, intercomparison of aircraft and ship flux data, and use of different methods for analyzing the fluxes from the aircraft data are described. Changing synoptic weather on three successive days yielded cases of wind direction both approximately parallel and perpendicular to a surface temperature front. For the wind perpendicular to the front, wind over both cold-to-warm and warm-to-cold surface temperatures occurred. Model results consistent with the observations suggest that an internal boundary layer forms at the SST.

  6. Air-sea CO 2 fluxes in the Caribbean Sea from 2002-2004

    NASA Astrophysics Data System (ADS)

    Wanninkhof, Rik; Olsen, Are; Triñanes, Joaquin

    2007-06-01

    Air-sea fluxes in the Caribbean Sea are presented based on measurements of partial pressure of CO 2 in surface seawater, pCO 2sw, from an automated system onboard the cruise ship Explorer of the Seas for 2002 through 2004. The pCO 2sw values are used to develop algorithms of pCO 2sw based on sea surface temperature (SST) and position. The algorithms are applied to assimilated SST data and remotely sensed winds on a 1° by 1° grid to estimate the fluxes on weekly timescales in the region. The positive relationship between pCO 2sw and SST is lower than the isochemical trend suggesting counteracting effects from biological processes. The relationship varies systematically with location with a stronger dependence further south. Furthermore, the southern area shows significantly lower pCO 2sw in the fall compared to the spring at the same SST, which is attributed to differences in salinity. The annual algorithms for the entire region show a slight trend between 2002 and 2004 suggesting an increase of pCO 2sw over time. This is in accord with the increasing pCO 2sw due the invasion of anthropogenic CO 2. The annual fluxes of CO 2 yield a net invasion of CO 2 to the ocean that ranges from - 0.04 to - 1.2 mol m - 2 year - 1 over the 3 years. There is a seasonal reversal in the direction of the flux with CO 2 entering into the ocean during the winter and an evasion during the summer. Year-to-year differences in flux are primarily caused by temperature anomalies in the late winter and spring period resulting in changes in invasion during these seasons. An analysis of pCO 2sw before and after hurricane Frances (September 4-6, 2004), and wind records during the storm suggest a large local enhancement of the flux but minimal influence on annual fluxes in the region.

  7. Air-Sea Fluxes in Hurricanes From GPS Dropsondes and a Fully Coupled Model

    NASA Astrophysics Data System (ADS)

    Desflots, M.; Chen, S.; Zhao, W.; Bao, J.

    2006-12-01

    The importance of the surface fluxes for tropical cyclone (TC) intensity has long been recognized. However, accurate surface fluxes under extreme high-wind conditions are difficult to determine due to the lack of direct observations. The physical processes controlling the air-sea fluxes and the exchange coefficients for the enthalpy and momentum fluxes are not well understood. Furthermore, a large amount of sea spray produced by the breaking waves in high winds further complicates the processes at the air-sea interface. To understand the behaviour of the surface fluxes and the atmospheric and upper ocean boundary layers in a hurricane, we use a high-resolution (1-2 km grid spacing), fully coupled atmosphere-wave-ocean model. The components of the coupled model system are the 5th generation Pennsylvania State University/ National Center for Atmospheric Research non-hydrostatic Mesoscale Model (MM5), WAVEWATCH III (WW3), and the Woods Hole Oceanographic Institution three-dimensional upper ocean model (WHOI 3DPWP). The coupled model used in this study includes the CBLAST wind-wave coupling parameterization and a sea spray parameterization that include the effects of the surface waves. The sea spray parameterization was initially developed by Fairall et al. (1994) and modified by Bao et al. (2000). The model simulated air-sea fluxes and atmospheric profiles from several numerical experiments of a 5-day simulation of Hurricane Frances (2004) are compared with the Global Positioning System (GPS) dropsonde data. The coupled model simulations of Frances reproduce the observed storm track and intensity quite well. The observed cold wake at the ocean surface and the asymmetry in the air-sea fluxes are also evident in the model simulations. More detailed analysis is currently underway to better understand the physical processes affecting air-sea fluxes in hurricanes as well as their contribution to the storm structure and intensity.

  8. Ocean Winds and Turbulent Air-Sea Fluxes Inferred From Remote Sensing

    NASA Technical Reports Server (NTRS)

    Bourassa, Mark A.; Gille, Sarah T.; Jackson, Daren L.; Roberts, J. Brent; Wick, Gary A.

    2010-01-01

    Air-sea turbulent fluxes determine the exchange of momentum, heat, freshwater, and gas between the atmosphere and ocean. These exchange processes are critical to a broad range of research questions spanning length scales from meters to thousands of kilometers and time scales from hours to decades. Examples are discussed (section 2). The estimation of surface turbulent fluxes from satellite is challenging and fraught with considerable errors (section 3); however, recent developments in retrievals (section 3) will greatly reduce these errors. Goals for the future observing system are summarized in section 4. Surface fluxes are defined as the rate per unit area at which something (e.g., momentum, energy, moisture, or CO Z ) is transferred across the air/sea interface. Wind- and buoyancy-driven surface fluxes are called surface turbulent fluxes because the mixing and transport are due to turbulence. Examples of nonturbulent processes are radiative fluxes (e.g., solar radiation) and precipitation (Schmitt et al., 2010). Turbulent fluxes are strongly dependent on wind speed; therefore, observations of wind speed are critical for the calculation of all turbulent surface fluxes. Wind stress, the vertical transport of horizontal momentum, also depends on wind direction. Stress is very important for many ocean processes, including upper ocean currents (Dohan and Maximenko, 2010) and deep ocean currents (Lee et al., 2010). On short time scales, this horizontal transport is usually small compared to surface fluxes. For long-term processes, transport can be very important but again is usually small compared to surface fluxes.

  9. A Numerical Study of the Role of Air-Sea Fluxes in Extratropical Cyclogenesis.

    DTIC Science & Technology

    1981-09-01

    Extratropical Cyclogenesis; Air-sea Fluxes; Surface Fluxes; Ocean Cyclogenesis; Polar Low;KDiabatic Processes 20. \\#@SYrNACY (Coie. on Po~wes li It nRaea@inF...parameterization scheme and the Randall version of the Deardorff planetary boundary layer parameterization. Idealized initial conditions are speci- fied ...hydo- static equation. The reference geopotential profile is speci- fied at 300S (spring regime) in the balance routine to match the temperature field

  10. Controls on air-sea CO2 flux in the Southern Ocean east of Australia

    NASA Astrophysics Data System (ADS)

    Ayers, J.; Strutton, P. G.

    2014-12-01

    The temperate latitudes of the world oceans (~30-50° north and south) are strong sinks for atmospheric CO2 on a mean annual basis. Due to sparse data, the Southern Ocean is the least understood of these CO2 sink regions, with estimates of the annual air-sea CO2 flux varying by as much as 100%, depending upon the calculation method. This work investigates processes regulating air-sea CO2 flux in the Southern Ocean, with a focus on the Pacific sector east of Australia. We quantify the effects of temperature, biological drawdown, and the large-scale general circulation on seawater pCO2 on seasonal and annual timescales, and discuss the balance of these forcings. We expressly consider the impact of the general circulation on the air-sea CO2 flux, which we showed in a previous study to determine the location of the North Pacific carbon sink region. Worldwide, the regions of strong atmospheric CO2 uptake are all located in deep western boundary currents and their extensions, suggesting a larger role for the general circulation in forcing these sinks than is currently acknowledged or understood. Understanding the processes regulating air-sea CO2 flux in the Southern Ocean is critical for predicting how this gas exchange will change in the future.

  11. Narrowing the spread in CMIP5 model projections of air-sea CO2 fluxes

    PubMed Central

    Wang, Lei; Huang, Jianbin; Luo, Yong; Zhao, Zongci

    2016-01-01

    Large spread appears in the projection of air-sea CO2 fluxes using the latest simulations from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Here, two methods are applied to narrow this spread in 13 CMIP5 models. One method involves model selection based on the ability of models to reproduce the observed air-sea CO2 fluxes from 1980 to 2005. The other method involves constrained estimation based on the strong relationship between the historical and future air-sea CO2 fluxes. The estimated spread of the projected air-sea CO2 fluxes is effectively reduced by using these two approaches. These two approaches also show great agreement in the global ocean and three regional oceans of the equatorial Pacific Ocean, the North Atlantic Ocean and the Southern Ocean, including the average state and evolution characteristics. Based on the projections of the two approaches, the global ocean carbon uptake will increase in the first half of the 21st century then remain relatively stable and is projected to be 3.68–4.57 PgC/yr at the end of 21st century. The projections indicate that the increase in the CO2 uptake by the oceans will cease at the year of approximately 2070. PMID:27892473

  12. Air-to-sea fluxes of lipids at Enewetak Atoll

    NASA Astrophysics Data System (ADS)

    Zafiriou, Oliver C.; Gagosian, Robert B.; Peltzer, Edward T.; Alford, Jane B.; Loder, T.

    1985-02-01

    We report data for the Enewetak site of the SEAREX program from the rainy season in 1979. The concentrations of n-alkanes, n-alkanols, sterols, n-alkanoic acids and their salts, and total organic compounds in rain are reported, as well as the apparent gaseous hydrocarbon concentrations. These data and information on the particulate forms are analyzed in conjunction with ancillary chemical and meteorological data to draw inferences about sources, fluxes, and chemical speciations. While the higher molecular weight lipid biomarker components are exclusively terrestrial, the organic carbon in rain may be derived from atmospheric transformations of terrestrial carbon. Distinctively marine components are nearly absent. Comparison of the scavenging ratios of the organic components in rain vs. those for clays reveals that the alkanoic acids and the higher molecular weight alkanols behave as essentially particulate materials, whereas lower alkanols and most hydrocarbons show much higher scavenging ratios, probably due to the involvement of a gaseous phase or sampling artifact. Vaporization in the atmosphere and scavenging of a gas phase would lead to higher scavenging ratios; vaporization during sampling would give low aerosol concentrations and high gas-phase concentrations, leading to high scavenging ratios. The major fluxes at Enewetak result from rain rather than dry deposition, and extrapolating the measured values to meaningful annual averages requires adjustment for seasonally varying source intensity and rain dynamics. Aerosol data for other seasons and other substances are used to correct for source-strength intensity variations, and a 210Pb/organic compound correlation is established and extrapolated to adjust for rainfall volume effects. These corrections, assumed independent and applied together, yield inferred fluxes 2.5-9 times larger than the fluxes calculated for mean concentrations. The inferred fluxes to the ocean, while small compared to primary

  13. Distribution and sea-to-air fluxes of volatile halocarbons in the Bohai Sea and North Yellow Sea during spring.

    PubMed

    He, Zhen; Liu, Qiu-Lin; Zhang, Ying-Jie; Yang, Gui-Peng

    2017-01-26

    Concentrations of volatile halocarbons (VHCs), such as CHBr2Cl, CHBr3, C2HCl3, and C2Cl4, in the Bohai Sea (BS) and North Yellow Sea (NYS) were measured during the spring of 2014. The VHC concentrations varied widely and decreased with distance from the coast in the investigated area, with low values observed in the open sea. Depth profiles of the VHCs were characterized by the highest concentration generally found in the upper water column. The distributions of the VHCs in the BS and NYS were clearly influenced by the combined effects of biological production, anthropogenic activities, and riverine input. The sea-to-air fluxes of CHBr2Cl, CHBr3, C2HCl3, and C2Cl4 in the study area were estimated to be 47.17, 56.63, 162.56, and 104.37nmolm(-2)d(-1), respectively, indicating that the investigated area may be a source of atmospheric CHBr2Cl, CHBr3, C2HCl3, and C2Cl4 in spring.

  14. Comparisons of Ship-based Observations of Air-Sea Energy Budgets with Gridded Flux Products

    NASA Astrophysics Data System (ADS)

    Fairall, C. W.; Blomquist, B.

    2015-12-01

    Air-surface interactions are characterized directly by the fluxes of momentum, heat, moisture, trace gases, and particles near the interface. In the last 20 years advances in observation technologies have greatly expanded the database of high-quality direct (covariance) turbulent flux and irradiance observations from research vessels. In this paper, we will summarize observations from the NOAA sea-going flux system from participation in various field programs executed since 1999 and discuss comparisons with several gridded flux products. We will focus on comparisons of turbulent heat fluxes and solar and IR radiative fluxes. The comparisons are done for observing programs in the equatorial Pacific and Indian Oceans and SE subtropical Pacific.

  15. Annual and seasonal fCO2 and air-sea CO2 fluxes in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Lauvset, S. K.; Chierici, M.; Counillon, F.; Omar, A.; Nondal, G.; Johannessen, T.; Olsen, A.

    2013-03-01

    The Barents Sea is the strongest CO2 sink in the Arctic region, yet estimates of the air-sea CO2 flux in this area show a large span reflecting uncertainty as well as significant variability both seasonally and regionally. Here we use a previously unpublished data set of seawater CO2 fugacity (fCO2), and map these data over the western Barents Sea through multivariable linear regressions with SeaWiFS/MODIS remote sensing and TOPAZ model data fields. We find that two algorithms are necessary in order to cover the full seasonal cycle, mainly because not all proxy variables are available for the entire year, and because variability in fCO2 is driven by different mechanisms in summer and winter. A comprehensive skill assessment indicates that there is a good overall correspondence between observations and predictions. The algorithms are also validated using two independent data sets, with good results. The gridded fCO2 fields reveal tight links between water mass distribution and fCO2 in all months, and particularly in winter. The seasonal cycle show peaks in the total air-sea CO2 influx in May and September, caused by respectively biological drawdown of CO2 and low sea ice concentration leaving a large open water area. For 2007 the annual average air-sea CO2 flux is - 48 ± 5 gC m- 2, which is comparable to previous estimates.

  16. Air-to-sea fluxes of lipids at enewetak atoll

    SciTech Connect

    Zafiriou, O.C.; Gagosian, R.B.; Peltzer, E.T.; Alford, J.B.; Loder, T.

    1985-02-20

    We report data for the Enewetak site of the SEAREX program from the rainy season in 1979. The concentrations of n-alkanes, n-alkanols, sterols, n-alkanoic acids and their salts, and total organic compounds in rain are reported, as well as the apparent gaseous hydrocarbon concentrations. These data and information on the particulate forms are analyzed in conjunction with ancillary chemical and meterological data to draw inferences about sources, fluxes, and chemical speciations. While the higher molecular weight lipid biomarker components are exclusively terrestrial, the organic carbon in rain may be derived from atmospheric transformations of terrestrial carbon. Distinctively marine components are nearly absent. Comparison of the scavenging ratios of the organic components in rain vs. those for clays reveals that the alkanoic acids and the higher molecular weight alkanols behave as essentially particulate materials, whereas lower alkanols and most hydrocarbons show much higher scavenging ratios, probably due to the involvement of a gaseous phase or sampling artifact. Vaporization in the atmosphere and scaveging of a gas phase would lead to higher scaveging ratios; vaporization during sampling would give low aerosol concentrations and high gas-phase concentrations, leading to high scavening ratios. The major fluxes at Enewetak result from rain rather than dry deposition, and extrapolating the measured values to meaningful annual averages requires adjustment for seasonally varying source intensity and rain dynamics. Aerosol data for other seasons and other substances are used to correct for source-strength intensity variations, and a /sup 210/Pb/organic compound correlation is established and extrapolated to adjust for rainfall volume effects.

  17. Sea-air CO2 fluxes in the Indian Ocean between 1990 and 2009

    NASA Astrophysics Data System (ADS)

    Sarma, V. V. S. S.; Lenton, A.; Law, R.; Metzl, N.; Patra, P. K.; Doney, S.; Lima, I. D.; Dlugokencky, E.; Ramonet, M.; Valsala, V.

    2013-07-01

    The Indian Ocean (44° S-30° N) plays an important role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Several approaches have been used to estimate net sea-air CO2 fluxes in this region: interpolated observations, ocean biogeochemical models, atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Indian Ocean sea-air CO2 fluxes between 1990 and 2009. Using all of the models and inversions, the median annual mean sea-air CO2 uptake of -0.37 ± 0.06 Pg C yr-1, is consistent with the -0.24 ± 0.12 Pg C yr-1 calculated from observations. The fluxes from the Southern Indian Ocean (18° S-44° S; -0.43 ± 0.07 Pg C yr-1) are similar in magnitude to the annual uptake for the entire Indian Ocean. All models capture the observed pattern of fluxes in the Indian Ocean with the following exceptions: underestimation of upwelling fluxes in the northwestern region (off Oman and Somalia), over estimation in the northeastern region (Bay of Bengal) and underestimation of the CO2 sink in the subtropical convergence zone. These differences were mainly driven by a lack of atmospheric CO2 data in atmospheric inversions, and poor simulation of monsoonal currents and freshwater discharge in ocean biogeochemical models. Overall, the models and inversions do capture the phase of the observed seasonality for the entire Indian Ocean but over estimate the magnitude. The predicted sea-air CO2 fluxes by Ocean BioGeochemical Models (OBGM) respond to seasonal variability with strong phase lags with reference to climatological CO2 flux, whereas the atmospheric inversions predict an order of magnitude higher seasonal flux than OBGMs. The simulated interannual variability by the OBGMs is weaker than atmospheric inversions. Prediction of such weak interannual variability in CO2 fluxes by atmospheric inversions

  18. Sea-air CO2 fluxes in the Indian Ocean between 1990 and 2009

    NASA Astrophysics Data System (ADS)

    Sarma, V. V. S. S.; Lenton, A.; Law, R. M.; Metzl, N.; Patra, P. K.; Doney, S.; Lima, I. D.; Dlugokencky, E.; Ramonet, M.; Valsala, V.

    2013-11-01

    The Indian Ocean (44° S-30° N) plays an important role in the global carbon cycle, yet it remains one of the most poorly sampled ocean regions. Several approaches have been used to estimate net sea-air CO2 fluxes in this region: interpolated observations, ocean biogeochemical models, atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Indian Ocean sea-air CO2 fluxes between 1990 and 2009. Using all of the models and inversions, the median annual mean sea-air CO2 uptake of -0.37 ± 0.06 PgC yr-1 is consistent with the -0.24 ± 0.12 PgC yr-1 calculated from observations. The fluxes from the southern Indian Ocean (18-44° S; -0.43 ± 0.07 PgC yr-1 are similar in magnitude to the annual uptake for the entire Indian Ocean. All models capture the observed pattern of fluxes in the Indian Ocean with the following exceptions: underestimation of upwelling fluxes in the northwestern region (off Oman and Somalia), overestimation in the northeastern region (Bay of Bengal) and underestimation of the CO2 sink in the subtropical convergence zone. These differences were mainly driven by lack of atmospheric CO2 data in atmospheric inversions, and poor simulation of monsoonal currents and freshwater discharge in ocean biogeochemical models. Overall, the models and inversions do capture the phase of the observed seasonality for the entire Indian Ocean but overestimate the magnitude. The predicted sea-air CO2 fluxes by ocean biogeochemical models (OBGMs) respond to seasonal variability with strong phase lags with reference to climatological CO2 flux, whereas the atmospheric inversions predicted an order of magnitude higher seasonal flux than OBGMs. The simulated interannual variability by the OBGMs is weaker than that found by atmospheric inversions. Prediction of such weak interannual variability in CO2 fluxes by atmospheric

  19. Assessing the potential for dimethylsulfide enrichment at the sea surface and its influence on air-sea flux

    NASA Astrophysics Data System (ADS)

    Walker, Carolyn F.; Harvey, Mike J.; Smith, Murray J.; Bell, Thomas G.; Saltzman, Eric S.; Marriner, Andrew S.; McGregor, John A.; Law, Cliff S.

    2016-09-01

    The flux of dimethylsulfide (DMS) to the atmosphere is generally inferred using water sampled at or below 2 m depth, thereby excluding any concentration anomalies at the air-sea interface. Two independent techniques were used to assess the potential for near-surface DMS enrichment to influence DMS emissions and also identify the factors influencing enrichment. DMS measurements in productive frontal waters over the Chatham Rise, east of New Zealand, did not identify any significant gradients between 0.01 and 6 m in sub-surface seawater, whereas DMS enrichment in the sea-surface microlayer was variable, with a mean enrichment factor (EF; the concentration ratio between DMS in the sea-surface microlayer and in sub-surface water) of 1.7. Physical and biological factors influenced sea-surface microlayer DMS concentration, with high enrichment (EF > 1.3) only recorded in a dinoflagellate-dominated bloom, and associated with low to medium wind speeds and near-surface temperature gradients. On occasion, high DMS enrichment preceded periods when the air-sea DMS flux, measured by eddy covariance, exceeded the flux calculated using National Oceanic and Atmospheric Administration (NOAA) Coupled-Ocean Atmospheric Response Experiment (COARE) parameterized gas transfer velocities and measured sub-surface seawater DMS concentrations. The results of these two independent approaches suggest that air-sea emissions may be influenced by near-surface DMS production under certain conditions, and highlight the need for further study to constrain the magnitude and mechanisms of DMS production in the sea-surface microlayer.

  20. Air-Sea Spray Airborne Radar Profiler Characterizes Energy Fluxes in Hurricanes

    NASA Technical Reports Server (NTRS)

    Durden, Stephen L.; Esteban-Fermandez, D.

    2010-01-01

    A report discusses ASAP (Air-sea Spray Airborne Profiler), a dual-wavelength radar profiler that provides measurement information about the droplet size distribution (DSD) of sea-spray, which can be used to estimate heat and moisture fluxes for hurricane research. Researchers have recently determined that sea spray can have a large effect on the magnitude and distribution of the air-sea energy flux at hurricane -force wind speeds. To obtain information about the DSD, two parameters of the DSD are required; for example, overall DSD amplitude and DSD mean diameter. This requires two measurements. Two frequencies are used, with a large enough separation that the differential frequency provides size information. One frequency is 94 GHz; the other is 220 GHz. These correspond to the Rayleigh and Mie regions. Above a surface wind speed of 10 m/ s, production of sea spray grows exponentially. Both the number of large droplets and the altitude they reach are a function of the surface wind speed.

  1. Air-Sea Fluxes in Terra Nova Bay, Antarctica from In Situ Aircraft Measurements

    NASA Astrophysics Data System (ADS)

    Knuth, S. L.; Cassano, J. J.

    2011-12-01

    In September 2009, the first unmanned aerial vehicles (UAVs) were flown over Terra Nova Bay, Antarctica to collect information regarding air-sea interactions over a wintertime coastal polynya. The UAVs measured wind, temperature, pressure, and relative humidity in flights parallel to the downslope wind flow over the polynya, and in a series of vertical profiles at varying distances from the coast. During three flights on three different days, sufficient measurements were collected to calculate sensible heat, latent heat, and momentum fluxes over varying oceanic surface states, including frazil, pancake, and rafted ice, with background winds greater than 15 ms-1. During the three flights, sensible heat fluxes upwards of 600 Wm-2 were estimated near the coast, with maximum latent heat fluxes near 160 Wm-2 just downwind of the coast. The calculated accelerations due to the momentum flux divergence were on the order of 10-3 ms-2. In addition to the fluxes, changes in the overall momentum budget, including the horizontal pressure gradient force, were also calculated during the three flights. This presentation will summarize the methodology for calculating the fluxes from the UAV data, present the first ever in situ estimates of sensible heat, latent heat, and momentum fluxes and overall momentum budget estimates over Terra Nova Bay, and compare the UAV flux calculations to flux measurements taken during other field campaigns in other regions of the Antarctic, as well as to model estimates over Terra Nova Bay.

  2. Regulation of CO2 Air Sea Fluxes by Sediments in the North Sea

    NASA Astrophysics Data System (ADS)

    Burt, William; Thomas, Helmuth; Hagens, Mathilde; Brenner, Heiko; Pätsch, Johannes; Clargo, Nicola; Salt, Lesley

    2016-04-01

    A multi-tracer approach is applied to assess the impact of boundary fluxes (e.g. benthic input from sediments or lateral inputs from the coastline) on the acid-base buffering capacity, and overall biogeochemistry, of the North Sea. Analyses of both basin-wide observations in the North Sea and transects through tidal basins at the North-Frisian coastline, reveal that surface distributions of the δ13C signature of dissolved inorganic carbon (DIC) are predominantly controlled by a balance between biological production and respiration. In particular, variability in metabolic DIC throughout stations in the well-mixed southern North Sea indicates the presence of an external carbon source, which is traced to the European continental coastline using naturally-occurring radium isotopes (224Ra and 228Ra). 228Ra is also shown to be a highly effective tracer of North Sea total alkalinity (AT) compared to the more conventional use of salinity. Coastal inputs of metabolic DIC and AT are calculated on a basin-wide scale, and ratios of these inputs suggest denitrification as a primary metabolic pathway for their formation. The AT input paralleling the metabolic DIC release prevents a significant decline in pH as compared to aerobic (i.e. unbuffered) release of metabolic DIC. Finally, long-term pH trends mimic those of riverine nitrate loading, highlighting the importance of coastal AT production via denitrification in regulating pH in the southern North Sea.

  3. An air/sea flux model including the effects of capillary waves

    NASA Technical Reports Server (NTRS)

    Bourassa, Mark A.

    1993-01-01

    An improved model of the air/sea interface is developed. The improvements consist in including the effect of capillary (surface tension) waves on the tropical surface fluxes and the consideration of the sea state, both of which increase the magnitude of tropical surface fluxes. Changes in surface stress are most significant in the low wind-speed regions, which include the areas where westerly bursts occur. It is shown that the changes, from the regular wind conditions to those of a westerly burst or El-Nino, can double when the effects of capillary waves are considered. This implies a much stronger coupling between the ocean and the atmosphere than is predicted by other boundary layer models.

  4. Mechanisms controlling the SST air-sea heat flux feedback and its dependence on spatial scale

    NASA Astrophysics Data System (ADS)

    Hausmann, Ute; Czaja, Arnaud; Marshall, John

    2017-02-01

    The turbulent air-sea heat flux feedback (α, in {W m}^{-2} { K}^{-1}) is a major contributor to setting the damping timescale of sea surface temperature (SST) anomalies. In this study we compare the spatial distribution and magnitude of α in the North Atlantic and the Southern Ocean, as estimated from the ERA-Interim reanalysis dataset. The comparison is rationalized in terms of an upper bound on the heat flux feedback, associated with "fast" atmospheric export of temperature and moisture anomalies away from the marine boundary layer, and a lower bound associated with "slow" export. It is found that regions of cold surface waters (≤10 ° C) are best described as approaching the slow export limit. This conclusion is not only valid at the synoptic scale resolved by the reanalysis data, but also on basin scales. In particular, it applies to the heat flux feedback acting as circumpolar SST anomaly scales are approached in the Southern Ocean, with feedbacks of ≤10 {W m}^{-2} { K}^{-1}. In contrast, the magnitude of the heat flux feedback is close to that expected from the fast export limit over the Gulf Stream and its recirculation with values on the order of ≈40 {W m}^{-2} { K}^{-1}. Further analysis suggests that this high value reflects a compensation between a moderate thermodynamic adjustment of the boundary layer, which tends to weaken the heat flux feedback, and an enhancement of the surface winds over warm SST anomalies, which tend to enhance the feedback.

  5. An assessment of air-sea heat fluxes from ocean and coupled reanalyses

    NASA Astrophysics Data System (ADS)

    Valdivieso, Maria; Haines, Keith; Balmaseda, Magdalena; Chang, You-Soon; Drevillon, Marie; Ferry, Nicolas; Fujii, Yosuke; Köhl, Armin; Storto, Andrea; Toyoda, Takahiro; Wang, Xiaochun; Waters, Jennifer; Xue, Yan; Yin, Yonghong; Barnier, Bernard; Hernandez, Fabrice; Kumar, Arun; Lee, Tong; Masina, Simona; Andrew Peterson, K.

    2015-10-01

    Sixteen monthly air-sea heat flux products from global ocean/coupled reanalyses are compared over 1993-2009 as part of the Ocean Reanalysis Intercomparison Project (ORA-IP). Objectives include assessing the global heat closure, the consistency of temporal variability, comparison with other flux products, and documenting errors against in situ flux measurements at a number of OceanSITES moorings. The ensemble of 16 ORA-IP flux estimates has a global positive bias over 1993-2009 of 4.2 ± 1.1 W m-2. Residual heat gain (i.e., surface flux + assimilation increments) is reduced to a small positive imbalance (typically, +1-2 W m-2). This compensation between surface fluxes and assimilation increments is concentrated in the upper 100 m. Implied steady meridional heat transports also improve by including assimilation sources, except near the equator. The ensemble spread in surface heat fluxes is dominated by turbulent fluxes (>40 W m-2 over the western boundary currents). The mean seasonal cycle is highly consistent, with variability between products mostly <10 W m-2. The interannual variability has consistent signal-to-noise ratio (~2) throughout the equatorial Pacific, reflecting ENSO variability. Comparisons at tropical buoy sites (10°S-15°N) over 2007-2009 showed too little ocean heat gain (i.e., flux into the ocean) in ORA-IP (up to 1/3 smaller than buoy measurements) primarily due to latent heat flux errors in ORA-IP. Comparisons with the Stratus buoy (20°S, 85°W) over a longer period, 2001-2009, also show the ORA-IP ensemble has 16 W m-2 smaller net heat gain, nearly all of which is due to too much latent cooling caused by differences in surface winds imposed in ORA-IP.

  6. The atmospheric footprint of preindustrial, anthropogenic, and contemporary air-sea fluxes of CO2 estimated from an ocean inversion

    NASA Astrophysics Data System (ADS)

    Mikaloff Fletcher, S. E.; Gruber, N. P.; Sarmiento, J. L.; Jacobson, A. R.

    2006-12-01

    Air-sea exchange is a primary determinant of the spatial pattern of atmospheric carbon dioxide, yet there are substantial gaps in our understanding of the impact of the oceans on these gradients. Recent inverse modeling studies have used ocean interior observations of dissolved inorganic carbon (DIC) and other tracers and Ocean General Circulation Models (OGCMs) to estimate separately the natural air-sea flux that already existed in preindustrial times and the component of the air-sea flux that is due to the anthropogenic perturbation of atmospheric CO2. The sum of these components is the contemporary air-sea flux. Furthermore, the results from the ocean inversion have been combined with an analogous atmospheric inversion using surface observations of atmospheric carbon dioxide concentrations and atmospheric transport models to estimate air- sea and air-land fluxes. This work suggested that there might be an unexpectedly large source of carbon dioxide to the atmosphere from tropical land regions. We use the air-sea fluxes estimated from this ocean inversion together with estimates of the seasonal cycle of these fluxes from ΔpCO2 observations and bulk parameterizations as boundary conditions for the Model for Ozone And Related chemical Tracers (MOZART). The effects of preindustrial, anthropogenic, and contemporary air-sea fluxes on the spatial pattern of atmospheric CO2 are analyzed and the implications for ocean interior transport are discussed. In addition, we use atmospheric observations of 13C/12C isotopic ratios in carbon dioxide to independently test the finding of a large terrestrial source in the tropics, since the terrestrial biosphere discriminates against 13C much more strongly than the oceans.

  7. Influence of precipitation on the CO2 air-sea flux, an eddy covariance field study

    NASA Astrophysics Data System (ADS)

    Zavarsky, Alexander; Steinhoff, Tobias; Marandino, Christa

    2016-04-01

    During the SPACES-OASIS cruise (July-August 2015) from Durban, SA to Male, MV direct fluxes of CO2 and dimethyl sulfide (DMS) were measured using the eddy covariance (EC) technique. The cruise covered areas of sources and sinks for atmospheric CO2, where the bulk concentration gradient measurements resembled the Takahashi (2009) climatology. Most of the time, bulk CO2 fluxes (F=k* [cwater-cair]), calculated with the parametrization (k) by Nightingale et al. 2000, were in general agreement with direct EC measurements. However, during heavy rain events, the directly measured CO2 fluxes were 4 times higher than predicted. It has been previously described that rain influences the k parametrization of air-sea gas exchange, but this alone cannot explain the measured discrepancy. There is evidence that freshwater input and a change in the carbonate chemistry causes the water side concentration of ?c=cwater-cair to decrease. Unfortunately this cannot be detected by most bulk measurement systems. Using the flux measurements of an additional gas like DMS, this rain influence can be evaluated as DMS does not react to changes in the carbonate system and has a different solubility. A pending question is if the enhanced flux of CO2 in the ocean is sequestered into the ocean mixed layer and below. This question will be tackled using the GOTM model to understand the implications for the global carbon cycle.

  8. Sensitivity of Global Sea-Air CO2 Flux to Gas Transfer Algorithms, Climatological Wind Speeds, and Variability of Sea Surface Temperature and Salinity

    NASA Technical Reports Server (NTRS)

    McClain, Charles R.; Signorini, Sergio

    2002-01-01

    Sensitivity analyses of sea-air CO2 flux to gas transfer algorithms, climatological wind speeds, sea surface temperatures (SST) and salinity (SSS) were conducted for the global oceans and selected regional domains. Large uncertainties in the global sea-air flux estimates are identified due to different gas transfer algorithms, global climatological wind speeds, and seasonal SST and SSS data. The global sea-air flux ranges from -0.57 to -2.27 Gt/yr, depending on the combination of gas transfer algorithms and global climatological wind speeds used. Different combinations of SST and SSS global fields resulted in changes as large as 35% on the oceans global sea-air flux. An error as small as plus or minus 0.2 in SSS translates into a plus or minus 43% deviation on the mean global CO2 flux. This result emphasizes the need for highly accurate satellite SSS observations for the development of remote sensing sea-air flux algorithms.

  9. Sea-air carbon dioxide fluxes along 35°S in the South Atlantic Ocean

    NASA Astrophysics Data System (ADS)

    Lencina-Avila, J. M.; Ito, R. G.; Garcia, C. A. E.; Tavano, V. M.

    2016-09-01

    The oceans play an important role in absorbing a significant fraction of the atmospheric CO2 surplus, but there are still uncertainties concerning several open ocean regions, such as the under-sampled South Atlantic Ocean. This study assessed the net sea-air CO2 fluxes and distribution of sea-surface CO2 fugacity (f C O2sw) along the 35°S latitude in the South Atlantic, during 2011 spring and early summer periods. Underway CO2 molar fraction, temperature, salinity and dissolved oxygen measurements were taken continuously from South American to South African continental shelves. Values of both satellite and discrete in situ chlorophyll-a concentration along the ship's track were used as ancillary data. Both f C O2sw and difference in sea-air fugacity (ΔfCO2) showed high variability along the cruise track, with higher values found on the continental shelf and slope regions. All ΔfCO2 values were negative, implying that a sinking process was occurring during the cruise period, with an average net CO2 flux of -3.1±2.2 mmol CO2 m-2 day-1 (using Wanninkhof, 1992). Physical variables were the main drivers of f C O2sw variability in South American continental shelf and open ocean regions, while the biological factor dominated the South African continental shelf. Algorithms for estimating fCO2 and temperature-normalized fCO2 were developed and applied separately to the three defined sub-regions: the South American shelf, the open ocean and the South African continental shelf, with the regional temperature-normalized fCO2 models showing better results.

  10. Air-sea CO2 flux pattern along the southern Bay of Bengal waters

    NASA Astrophysics Data System (ADS)

    Shanthi, R.; Poornima, D.; Naveen, M.; Thangaradjou, T.; Choudhury, S. B.; Rao, K. H.; Dadhwal, V. K.

    2016-12-01

    Physico-chemical observations made from January 2013 to March 2015 in coastal waters of the southwest Bay of Bengal show pronounced seasonal variation in physico-chemical parameters including total alkalinity (TA: 1927.390-4088.642 μmol kg-1), chlorophyll (0.13-19.41 μg l-1) and also calculated dissolved inorganic carbon (DIC: 1574.219-3790.954 μmol kg-1), partial pressure of carbon dioxide (pCO2: 155.520-1488.607 μatm) and air-sea CO2 flux (FCO2: -4.808 to 11.255 mmol Cm-2 d-1). Most of the physical parameters are at their maximum during summer due to the increased solar radiation at cloud free conditions, less or no riverine inputs, and lack of vertical mixing of water column which leads to the lowest nutrients concentration, dissolved oxygen (DO), biological production, pCO2 and negative flux of CO2 to the atmosphere. Chlorophyll and DO concentrations enhanced due to increased nutrients during premonsoon and monsoon season due to the vertical mixing of water column driven by the strong winds and external inputs at respective seasons. The constant positive loading of nutrients, TA, DIC, chlorophyll, pCO2 and FCO2 against atmospheric temperature (AT), lux, sea surface temperature (SST), pH and salinity observed in principal component analysis (PCA) suggested that physical and biological parameters play vital role in the seasonal distribution of pCO2 along the southwest Bay of Bengal. The annual variability of CO2 flux clearly depicted that the southwest Bay of Bengal switch from sink (2013) to source status in the recent years (2014 and 2015) and it act as significant source of CO2 to the atmosphere with a mean flux of 0.204 ± 1.449 mmol Cm-2 d-1.

  11. Air-Sea Methane Flux after the Deepwater Horizon Oil Leak

    NASA Astrophysics Data System (ADS)

    McAdoo, J.; Sweeney, C.; Kiene, R. P.; McGillis, W. R.

    2012-12-01

    One of the key questions associated with the Deepwater Horizon's (DWH) oil leak involves understanding how much of its methane is still entrained in deep waters. Analysis of air-sea fluxes reveals a slight decrease in average aqueous CH4 from 3.3 nM in June to 3.1 and 2.8 nM in August and September, respectively. The flux estimate showed higher methane flux to the atmosphere after the blowout was capped (3.8 μmol m-2 d-1 in August) compared to 0.024 μmol m-2 d-1 during the leak. Almost all observations were within the range of historical levels. The exception was one large peak to the southwest of the wellhead, but its contribution to atmospheric methane is found to be insignificant compared to the total amount of methane released by the leak. This result supports findings that DWH methane remained entrained in the deep waters and consequently is available for biological degradation and threatens to deplete oxygen, adding further stress to an area that already suffers from anoxic-induced dead zones.

  12. Distribution and sea-to-air flux of isoprene in the East China Sea and the South Yellow Sea during summer.

    PubMed

    Li, Jian-Long; Zhang, Hong-Hai; Yang, Gui-Peng

    2017-07-01

    Spatial distribution and sea-to-air flux of isoprene in the East China Sea and the South Yellow Sea in July 2013 were investigated. This study is the first to report the concentrations of isoprene in the China marginal seas. Isoprene concentrations in the surface seawater during summer ranged from 32.46 to 173.5 pM, with an average of 83.62 ± 29.22 pM. Distribution of isoprene in the study area was influenced by the diluted water from the Yangtze River, which stimulated higher in-situ phytoplankton production of isoprene rather than direct freshwater input. Variations in isoprene concentrations were found to be diurnal, with high values observed during daytime. A significant correlation was observed between isoprene and chlorophyll a in the study area. Relatively higher isoprene concentrations were recorded at stations where the phytoplankton biomass was dominated by Chaetoceros, Skeletonema, Pennate-nitzschia, and Thalassiosira. Positive correlation was observed between isoprene and methyl iodide. In addition, sea-to-air fluxes of isoprene approximately ranged from 22.17 nmol m(-2) d(-1)-537.2 nmol m(-2) d(-1), with an average of 161.5 ± 133.3 nmol m(-2) d(-1). These results indicate that the coastal and shelf areas may be important sources of atmospheric isoprene.

  13. Mapping of the air-sea CO2 flux in the Arctic Ocean and its adjacent seas: Basin-wide distribution and seasonal to interannual variability

    NASA Astrophysics Data System (ADS)

    Yasunaka, Sayaka; Murata, Akihiko; Watanabe, Eiji; Chierici, Melissa; Fransson, Agneta; van Heuven, Steven; Hoppema, Mario; Ishii, Masao; Johannessen, Truls; Kosugi, Naohiro; Lauvset, Siv K.; Mathis, Jeremy T.; Nishino, Shigeto; Omar, Abdirahman M.; Olsen, Are; Sasano, Daisuke; Takahashi, Taro; Wanninkhof, Rik

    2016-09-01

    We produced 204 monthly maps of the air-sea CO2 flux in the Arctic north of 60°N, including the Arctic Ocean and its adjacent seas, from January 1997 to December 2013 by using a self-organizing map technique. The partial pressure of CO2 (pCO2) in surface water data were obtained by shipboard underway measurements or calculated from alkalinity and total inorganic carbon of surface water samples. Subsequently, we investigated the basin-wide distribution and seasonal to interannual variability of the CO2 fluxes. The 17-year annual mean CO2 flux shows that all areas of the Arctic Ocean and its adjacent seas were net CO2 sinks. The estimated annual CO2 uptake by the Arctic Ocean was 180 TgC yr-1. The CO2 influx was strongest in winter in the Greenland/Norwegian Seas (>15 mmol m-2 day-1) and the Barents Sea (>12 mmol m-2 day-1) because of strong winds, and strongest in summer in the Chukchi Sea (∼10 mmol m-2 day-1) because of the sea-ice retreat. In recent years, the CO2 uptake has increased in the Greenland/Norwegian Sea and decreased in the southern Barents Sea, owing to increased and decreased air-sea pCO2 differences, respectively.

  14. Mesoscale modulation of air-sea CO2 flux in Drake Passage

    NASA Astrophysics Data System (ADS)

    Song, Hajoon; Marshall, John; Munro, David R.; Dutkiewicz, Stephanie; Sweeney, Colm; McGillicuddy, D. J.; Hausmann, Ute

    2016-09-01

    We investigate the role of mesoscale eddies in modulating air-sea CO2 flux and associated biogeochemical fields in Drake Passage using in situ observations and an eddy-resolving numerical model. Both observations and model show a negative correlation between temperature and partial pressure of CO2 (pCO2) anomalies at the sea surface in austral summer, indicating that warm/cold anticyclonic/cyclonic eddies take up more/less CO2. In austral winter, in contrast, relationships are reversed: warm/cold anticyclonic/cyclonic eddies are characterized by a positive/negative pCO2 anomaly and more/less CO2 outgassing. It is argued that DIC-driven effects on pCO2 are greater than temperature effects in austral summer, leading to a negative correlation. In austral winter, however, the reverse is true. An eddy-centric analysis of the model solution reveals that nitrate and iron respond differently to the same vertical mixing: vertical mixing has a greater impact on iron because its normalized vertical gradient at the base of the surface mixed layer is an order of magnitude greater than that of nitrate.

  15. A Sensitivity Analysis of the Impact of Rain on Regional and Global Sea-Air Fluxes of CO2

    PubMed Central

    Shutler, J. D.; Land, P. E.; Woolf, D. K.; Quartly, G. D.

    2016-01-01

    The global oceans are considered a major sink of atmospheric carbon dioxide (CO2). Rain is known to alter the physical and chemical conditions at the sea surface, and thus influence the transfer of CO2 between the ocean and atmosphere. It can influence gas exchange through enhanced gas transfer velocity, the direct export of carbon from the atmosphere to the ocean, by altering the sea skin temperature, and through surface layer dilution. However, to date, very few studies quantifying these effects on global net sea-air fluxes exist. Here, we include terms for the enhanced gas transfer velocity and the direct export of carbon in calculations of the global net sea-air fluxes, using a 7-year time series of monthly global climate quality satellite remote sensing observations, model and in-situ data. The use of a non-linear relationship between the effects of rain and wind significantly reduces the estimated impact of rain-induced surface turbulence on the rate of sea-air gas transfer, when compared to a linear relationship. Nevertheless, globally, the rain enhanced gas transfer and rain induced direct export increase the estimated annual oceanic integrated net sink of CO2 by up to 6%. Regionally, the variations can be larger, with rain increasing the estimated annual net sink in the Pacific Ocean by up to 15% and altering monthly net flux by > ± 50%. Based on these analyses, the impacts of rain should be included in the uncertainty analysis of studies that estimate net sea-air fluxes of CO2 as the rain can have a considerable impact, dependent upon the region and timescale. PMID:27673683

  16. A Sensitivity Analysis of the Impact of Rain on Regional and Global Sea-Air Fluxes of CO2.

    PubMed

    Ashton, I G; Shutler, J D; Land, P E; Woolf, D K; Quartly, G D

    The global oceans are considered a major sink of atmospheric carbon dioxide (CO2). Rain is known to alter the physical and chemical conditions at the sea surface, and thus influence the transfer of CO2 between the ocean and atmosphere. It can influence gas exchange through enhanced gas transfer velocity, the direct export of carbon from the atmosphere to the ocean, by altering the sea skin temperature, and through surface layer dilution. However, to date, very few studies quantifying these effects on global net sea-air fluxes exist. Here, we include terms for the enhanced gas transfer velocity and the direct export of carbon in calculations of the global net sea-air fluxes, using a 7-year time series of monthly global climate quality satellite remote sensing observations, model and in-situ data. The use of a non-linear relationship between the effects of rain and wind significantly reduces the estimated impact of rain-induced surface turbulence on the rate of sea-air gas transfer, when compared to a linear relationship. Nevertheless, globally, the rain enhanced gas transfer and rain induced direct export increase the estimated annual oceanic integrated net sink of CO2 by up to 6%. Regionally, the variations can be larger, with rain increasing the estimated annual net sink in the Pacific Ocean by up to 15% and altering monthly net flux by > ± 50%. Based on these analyses, the impacts of rain should be included in the uncertainty analysis of studies that estimate net sea-air fluxes of CO2 as the rain can have a considerable impact, dependent upon the region and timescale.

  17. The Impact of the Ocean Thermal Skin Layer on Air-Sea Interfacial Heat Fluxes

    NASA Astrophysics Data System (ADS)

    Minnett, P. J.; Wong, E.

    2015-12-01

    The upper ocean heat content has been observed to be increasing over the past few decades much of which has been attributed to anthropogenic effects resulting in an increase in greenhouse gases thereby increasing the amounts of incoming longwave (LWin) radiation impinging onto the ocean's surface. However, the penetration depth of LWin extends to micrometer scales, where the ocean's thermal skin layer (TSL) exists, and does not directly heat the upper few meters of the ocean thereby raising the conundrum of how does the upper ocean warm with increasing levels of infrared (IR) radiation. The TSL consists of a strong temperature gradient on the aqueous side of the interface that sustains the upward heat flux by molecular conduction. As such, we hypothesize the heat lost through the air-sea interface which is controlled by the TSL, modulates the amount of heat stored in the upper few meters of the ocean. An analysis of properties of the retrieved TSL profiles from a shipboard IR spectrometer with heat fluxes (specifically LWin) and wind speeds from two cruises limited to night-time data are presented. We also show a comparison between these properties with current published viscous layer models. The results indicate that the data have an inherent wind speed dependence with net flux thereby requiring a segregation of the data into wind speed bins to acknowledge the effects of wind-driven shear in the analysis. The temperature differences derived from the models indicates that at low wind speeds (<2 m/s), where wind-driven shear effects are negligible and buoyancy effects dominate, the TSL profile's gradient is decreasing with increased LWin which leads to a lowered net heat flux and is in agreement with our hypothesis. However our field results show an opposite effect (higher gradient at higher LWin) which is believed to be due to the formation of a thicker TSL at low winds. The presence of a thicker TSL suggests that more of the vertical temperature gradient lies

  18. Assessing recent air-sea freshwater flux changes using a surface temperature-salinity space framework

    NASA Astrophysics Data System (ADS)

    Grist, Jeremy P.; Josey, Simon A.; Zika, Jan D.; Evans, Dafydd Gwyn; Skliris, Nikolaos

    2016-12-01

    A novel assessment of recent changes in air-sea freshwater fluxes has been conducted using a surface temperature-salinity framework applied to four atmospheric reanalyses. Viewed in the T-S space of the ocean surface, the complex pattern of the longitude-latitude space mean global Precipitation minus Evaporation (PME) reduces to three distinct regions. The analysis is conducted for the period 1979-2007 for which there is most evidence for a broadening of the (atmospheric) tropical belt. All four of the reanalyses display an increase in strength of the water cycle. The range of increase is between 2% and 30% over the period analyzed, with an average of 14%. Considering the average across the reanalyses, the water cycle changes are dominated by changes in tropical as opposed to mid-high latitude precipitation. The increases in the water cycle strength, are consistent in sign, but larger than in a 1% greenhouse gas run of the HadGEM3 climate model. In the model a shift of the precipitation/evaporation cells to higher temperatures is more evident, due to the much stronger global warming signal. The observed changes in freshwater fluxes appear to be reflected in changes in the T-S distribution of the Global Ocean. Specifically, across the diverse range of atmospheric reanalyses considered here, there was an acceleration of the hydrological cycle during 1979-2007 which led to a broadening of the ocean's salinity distribution. Finally, although the reanalyses indicate that the warm temperature tropical precipitation dominated water cycle change, ocean observations suggest that ocean processes redistributed the freshening to lower ocean temperatures.

  19. Sea surface carbon dioxide at the Georgia time series site (2006-2007): Air-sea flux and controlling processes

    NASA Astrophysics Data System (ADS)

    Xue, Liang; Cai, Wei-Jun; Hu, Xinping; Sabine, Christopher; Jones, Stacy; Sutton, Adrienne J.; Jiang, Li-Qing; Reimer, Janet J.

    2016-01-01

    Carbon dioxide partial pressure (pCO2) in surface seawater was continuously recorded every three hours from 18 July 2006 through 31 October 2007 using a moored autonomous pCO2 (MAPCO2) system deployed on the Gray's Reef buoy off the coast of Georgia, USA. Surface water pCO2 (average 373 ± 52 μatm) showed a clear seasonal pattern, undersaturated with respect to the atmosphere in cold months and generally oversaturated in warm months. High temporal resolution observations revealed important events not captured in previous ship-based observations, such as sporadically occurring biological CO2 uptake during April-June 2007. In addition to a qualitative analysis of the primary drivers of pCO2 variability based on property regressions, we quantified contributions of temperature, air-sea exchange, mixing, and biological processes to monthly pCO2 variations using a 1-D mass budget model. Although temperature played a dominant role in the annual cycle of pCO2, river inputs especially in the wet season, biological respiration in peak summer, and biological production during April-June 2007 also substantially influenced seawater pCO2. Furthermore, sea surface pCO2 was higher in September-October 2007 than in September-October 2006, associated with increased river inputs in fall 2007. On an annual basis this site was a moderate atmospheric CO2 sink, and was autotrophic as revealed by monthly mean net community production (NCP) in the mixed layer. If the sporadic short productive events during April-May 2007 were missed by the sampling schedule, one would conclude erroneously that the site is heterotrophic. While previous ship-based pCO2 data collected around this buoy site agreed with the buoy CO2 data on seasonal scales, high resolution buoy observations revealed that the cruise-based surveys undersampled temporal variability in coastal waters, which could greatly bias the estimates of air-sea CO2 fluxes or annual NCP, and even produce contradictory results.

  20. Using Empirical Mode Decomposition to Filter Out Non-turbulent Contributions to Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Martins, Luís Gustavo N.; Miller, Scott D.; Acevedo, Otávio C.

    2017-04-01

    A methodology based on Empirical mode decomposition (EMD) was used to filter out non-turbulent motions from measurements of atmospheric turbulence over the sea, aimed at reducing their contribution to eddy-covariance (EC) estimates of turbulent fluxes. The proposed methodology has two main objectives: (1) to provide more robust estimates of the fluxes of momentum, heat and CO_2; and (2) to reduce the number of flux intervals rejected due to non-stationarity criteria when using traditional EC data processing techniques. The method was applied to measurements from a 28-day cruise (HALOCAST 2010) in the Eastern Pacific region. Empirical mode decomposition was applied to 4-h long time series data and used to determine the cospectral gap time scale, T_{gap}. Intrinsic modes of oscillation with characteristic periods longer than the gap scale due to non-turbulent motions were assumed and filtered out. Turbulent fluxes were then calculated for sub-intervals of length T_{gap} from the filtered 4-h time series. In the HALOCAST data, the gap scale was successfully identified in 89% of the 4-h periods and had a mean of 37 s. The EMD approach resulted in the rejection of 11% of the flux intervals, which was much less than the 68% rejected when using standard filtering methods based on data non-stationarity. For momentum and sensible heat fluxes, the averaged difference in flux magnitude between the traditional and EMD approaches was small (3 and 1%, respectively). For the CO_2 flux, the magnitude of EMD flux estimates was on average 16% less than fluxes estimated from linear detrended 10-min time series. These results provide evidence that the EMD method can be used to reduce the effects of non-turbulent correlations from flux estimates.

  1. CLIVAR-GSOP/GODAE Ocean Synthesis Inter-Comparison of Global Air-Sea Fluxes From Ocean and Coupled Reanalyses

    NASA Astrophysics Data System (ADS)

    Valdivieso, Maria

    2014-05-01

    The GODAE OceanView and CLIVAR-GSOP ocean synthesis program has been assessing the degree of consistency between global air-sea flux data sets obtained from ocean or coupled reanalyses (Valdivieso et al., 2014). So far, fifteen global air-sea heat flux products obtained from ocean or coupled reanalyses have been examined: seven are from low-resolution ocean reanalyses (BOM PEODAS, ECMWF ORAS4, JMA/MRI MOVEG2, JMA/MRI MOVECORE, Hamburg Univ. GECCO2, JPL ECCOv4, and NCEP GODAS), five are from eddy-permitting ocean reanalyses developed as part of the EU GMES MyOcean program (Mercator GLORYS2v1, Reading Univ. UR025.3, UR025.4, UKMO GloSea5, and CMCC C-GLORS), and the remaining three are couple reanalyses based on coupled climate models (JMA/MRI MOVE-C, GFDL ECDA and NCEP CFSR). The global heat closure in the products over the period 1993-2009 spanned by all data sets is presented in comparison with observational and atmospheric reanalysis estimates. Then, global maps of ensemble spread in the seasonal cycle, and of the Signal to Noise Ratio of interannual flux variability over the 17-yr common period are shown to illustrate the consistency between the products. We have also studied regional variability in the products, particularly at the OceanSITES project locations (such as, for instance, the TAO/TRITON and PIRATA arrays in the Tropical Pacific and Atlantic, respectively). Comparisons are being made with other products such as OAFlux latent and sensible heat fluxes (Yu et al., 2008) combined with ISCCP satellite-based radiation (Zhang et al., 2004), the ship-based NOC2.0 product (Berry and Kent, 2009), the Large and Yeager (2009) hybrid flux dataset CORE.2, and two atmospheric reanalysis products, the ECMWF ERA-Interim reanalysis (referred to as ERAi, Dee et al., 2011) and the NCEP/DOE reanalysis R2 (referred to as NCEP-R2, Kanamitsu et al., 2002). Preliminary comparisons with the observational flux products from OceanSITES are also underway. References Berry, D

  2. Effect of Sampling Depth on Air-Sea CO2 Flux Estimates in River-Stratified Arctic Coastal Waters

    NASA Astrophysics Data System (ADS)

    Miller, L. A.; Papakyriakou, T. N.

    2015-12-01

    In summer-time Arctic coastal waters that are strongly influenced by river run-off, extreme stratification severely limits wind mixing, making it difficult to effectively sample the surface 'mixed layer', which can be as shallow as 1 m, from a ship. During two expeditions in southwestern Hudson Bay, off the Nelson, Hayes, and Churchill River estuaries, we confirmed that sampling depth has a strong impact on estimates of 'surface' pCO2 and calculated air-sea CO2 fluxes. We determined pCO2 in samples collected from 5 m, using a typical underway system on the ship's seawater supply; from the 'surface' rosette bottle, which was generally between 1 and 3 m; and using a niskin bottle deployed at 1 m and just below the surface from a small boat away from the ship. Our samples confirmed that the error in pCO2 derived from typical ship-board versus small-boat sampling at a single station could be nearly 90 μatm, leading to errors in the calculated air-sea CO2 flux of more than 0.1 mmol/(m2s). Attempting to extrapolate such fluxes over the 6,000,000 km2 area of the Arctic shelves would generate an error approaching a gigamol CO2/s. Averaging the station data over a cruise still resulted in an error of nearly 50% in the total flux estimate. Our results have implications not only for the design and execution of expedition-based sampling, but also for placement of in-situ sensors. Particularly in polar waters, sensors are usually deployed on moorings, well below the surface, to avoid damage and destruction from drifting ice. However, to obtain accurate information on air-sea fluxes in these areas, it is necessary to deploy sensors on ice-capable buoys that can position the sensors in true 'surface' waters.

  3. Characterization of Sea-Air Methane Fluxes Around a Seafloor Gas Seep in the Central Laptev Sea

    NASA Astrophysics Data System (ADS)

    Geibel, M. C.; Thornton, B. F.; Prytherch, J.; Brooks, I. M.; Salisbury, D. J.; Tjernstrom, M. K. H.; Semiletov, I. P.; Mörth, C. M.; Humborg, C.; Crill, P. M.

    2015-12-01

    The fate of CH4 released from thawing subsea permafrost on the East Siberian Arctic Shelf (ESAS) is unclear. In recent years, interest has focused on the possibility of large emissions of CH4 directly to the atmosphere from this remote area. It is uncertain how high those emissions are and whether they are primarily of biogenic or thermogenic nature, or some combination of sources. The SWERUS-C3 expedition onboard the Swedish icebreaker Oden during July-August 2014 sought to document possible CH4 release from subsea permafrost, and to understand mechanisms and magnitudes of such CH4 being released to the atmosphere. During the first leg of the expedition continuous high-resolution measurements were made to determine the in situ concentrations of CH4 in both the atmosphere and surface water. During SWERUS-C3, several underwater gas flares were found within the ESAS region showing elevated CH4 concentrations collocated in the surface waters. Here we focus on one seep area, a so-called "mega-flare" site, in the central Laptev Sea. Over individual gas flares of this site the surface water concentration of CH4 reached as high as 200ppm. The atmospheric concentrations of CH4 briefly (< 1 s) reached a maximum of ~3.2 ppm. More typical atmospheric values around the seeps were between 1.9-2.0 ppm (background values were approximately 1.88 ppm). However, such peak concentrations in both air and water were highly localized, returning to background levels within a few hundred meters of the source seeps. Together with continuous high-precision eddy-covariance measurements that were made during the SWERUS-C3 expedition, the combined dataset allows an intensive analysis these highly inhomogeneous gas flares. This gives the opportunity to calculate accurate high-resolution CH4 fluxes and thus give a better insight into the current rates of subsea CH4 outgassing reaching the atmosphere.

  4. Predicting the Turbulent Air-Sea Surface Fluxes, Including Spray Effects, from Weak to Strong Winds

    DTIC Science & Technology

    2012-09-30

    from Moon et al. (2007) and Mueller and Veron (2009) are not much different from our main straight-line result (6) for UN10 above 20 m/s...model the air-sea drag as a consequence of just wind-wave coupling. That is, Moon et al. (2007) and Mueller and Veron (2009) modeled the surface stress... Veron evidently realized that they were predicting u* to be a linear function of UN10 in high winds.) In other words, exotic processes like sea

  5. Dissolved methane concentration profiles and air-sea fluxes from 41°S to 27°N

    NASA Astrophysics Data System (ADS)

    Kelley, Cheryl A.; Jeffrey, Wade H.

    2002-07-01

    Water column samples from a transect cruise from southern Chile through the Panama Canal to the Gulf of Mexico were used to determine dissolved methane depth profiles and air-sea methane fluxes. In the Gulf of Mexico, surface concentrations were approximately 40% supersaturated with respect to the atmosphere, whereas near the equator and in the Peru upwelling region, 10-20% supersaturation generally occurred. These saturation ratios translate into an average flux of methane from the sea surface to the atmosphere of 0.38 μmol m-2 d-1. In addition, water column profiles of dissolved methane indicate that subsurface maxima in dissolved methane concentrations are a consistent feature of the open ocean, except near the equator. At the equator, the subsurface peak at the base of the mixed layer may be bowed down by the Equatorial Undercurrent. The highest methane concentration (12 nM) was observed in the Peru upwelling region.

  6. Multi-Satellite Characterization of Interannual Variation in Primary Production and Air-Sea CO2 Flux in the Ross Sea, Antarctica

    NASA Astrophysics Data System (ADS)

    Arrigo, K. R.

    2005-12-01

    The Ross Sea is the most productive sector of the Southern Ocean, the largest of the three iron limited HNLC regions. This productivity supports a rich upper trophic level community, including large numbers of penguins, seals, and whales. It also represents a large sink for atmospheric CO2. Since the advent of ocean color remote sensing using satellites such as CZCS, SeaWiFS, and MODIS, it has become increasingly clear that productivity in the Ross Sea is also characterized by a great deal of interannual variability. Passive microwave data from the Special Sensor Microwave/Imager show that distributions of sea ice within the Ross Sea vary markedly from year to year, with some years experiencing nearly ice-free springtime conditions while others remain nearly ice covered. This extreme variability in sea ice cover is due to changes in climate state as well as some unusual events specific to the Ross Sea, such as the calving of two enormous icebergs, one in 2000 and the other in 2002. Variation in ice cover during austral spring and summer impacts the growth of the phytoplankton community, whose cumulative rate of annual primary production ranges widely, from <10 Tg C in 2002-03 to almost 40 Tg C in 1999-00. When these satellite data are used in conjunction with a three-dimensional ocean ecosystem model of the Ross Sea, the calculated air-sea fluxes of CO2 are even more variable, varying over 50-fold between 1997 and 2004. Not surprisingly, the lowest atmospheric flux of CO2 into the surface waters of the Ross Sea (0.10 Tg C) is associated with the year having the lowest primary production and highest sea ice cover. The extreme sensitivity of rates of primary production and particularly air-sea CO2 fluxes to changes in sea ice distribution in the Southern Ocean suggest that this region may undergo dramatic changes if global temperatures continue to rise, as they have in the vicinity of the Antarctic Peninsula.

  7. A Climate Data Record of Near-Surface Over-Ocean Parameters and Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Clayson, C. A.; Brown, J.

    2015-12-01

    In this climate data record, we have derived surface and near-surface parameters of wind speed, temperature, and humidity from a combination of satellite observations, with a focus on the use of these variables towards determination of the air-sea turbulent heat fluxes. The dataset is a follow-on to the CDR SeaFlux v 1 dataset, which currently covers the time period of 1988 through 2008, and the variables of sea surface temperature and 10-m temperature, wind speed, and specific humidity at a 3-hourly, 0.25º resolution over the global oceans. These products have been developed for the specific focus of accurate determination of the surface turbulent fluxes. The current dataset is brought forward to short latency (roughly three months) by adding in SSMIS data. This talk will discuss the additional issues associated with including the much-noisier SSMIS data, comparisons of uncertainties from the time period of the SSMIS as compared to the SSMI era, and an analysis of interannual variability over the time period from 1988 through 2015, including the recent ENSO variability.

  8. Air-sea fluxes in a climate model using hourly coupling between the atmospheric and the oceanic components

    NASA Astrophysics Data System (ADS)

    Tian, Fangxing; von Storch, Jin-Song; Hertwig, Eileen

    2016-06-01

    We analyse the changes in the air-sea fluxes of momentum, heat and fresh water flux caused by increasing the ocean-atmosphere coupling frequency from once per day to once per hour in the Max Planck Institute Earth System Model. We diagnose the relative influences of daily averaging and high-frequency feedbacks on the basic statistics of the air-sea fluxes at grid point level and quantify feedback modes responsible for large scale changes in fluxes over the Southern Ocean and the Equatorial Pacific. Coupling once per hour instead of once per day reduces the mean of the momentum-flux magnitude by up to 7 % in the tropics and increases it by up to 10 % in the Southern Ocean. These changes result solely from feedbacks between atmosphere and ocean occurring on time scales shorter than 1 day . The variance and extremes of all the fluxes are increased in most parts of the oceans. Exceptions are found for the momentum and fresh water fluxes in the tropics. The increases result mainly from the daily averaging, while the decreases in the tropics are caused by the high-frequency feedbacks. The variance increases are substantial, reaching up to 50 % for the momentum flux, 100 % for the fresh water flux, and a factor of 15 for the net heat flux. These diurnal and intra-diurnal variations account for up to 50-90 % of the total variances and exhibit distinct seasonality. The high-frequency coupling can influence the large-scale feedback modes that lead to large-scale changes in the magnitude of wind stress over the Southern Ocean and Equatorial Pacific. In the Southern Ocean, the dependence of the SST-wind-stress feedback on the mean state of SST, which is colder in the experiment with hourly coupling than in the experiment with daily coupling, leads to an increase of westerlies. In the Equatorial Pacific, Bjerknes feedback in the hourly coupled experiment reveals a diurnal cycle during the El Niño events, with the feedback being stronger in the nighttime than in the daytime and

  9. Motion-correlated flow distortion and wave-induced biases in air-sea flux measurements from ships

    NASA Astrophysics Data System (ADS)

    Prytherch, J.; Yelland, M. J.; Brooks, I. M.; Tupman, D. J.; Pascal, R. W.; Moat, B. I.; Norris, S. J.

    2015-09-01

    Direct measurements of the turbulent air-sea fluxes of momentum, heat, moisture and gases are often made using sensors mounted on ships. Ship-based turbulent wind measurements are corrected for platform motion using well established techniques, but biases at scales associated with wave and platform motion are often still apparent in the flux measurements. It has been uncertain whether this signal is due to time-varying distortion of the air flow over the platform or to wind-wave interactions impacting the turbulence. Methods for removing such motion-scale biases from scalar measurements have previously been published but their application to momentum flux measurements remains controversial. Here we show that the measured motion-scale bias has a dependence on the horizontal ship velocity and that a correction for it reduces the dependence of the measured momentum flux on the orientation of the ship to the wind. We conclude that the bias is due to experimental error and that time-varying motion-dependent flow distortion is the likely source.

  10. Motion-correlated flow distortion and wave-induced biases in air-sea flux measurements from ships

    NASA Astrophysics Data System (ADS)

    Prytherch, J.; Yelland, M. J.; Brooks, I. M.; Tupman, D. J.; Pascal, R. W.; Moat, B. I.; Norris, S. J.

    2015-06-01

    Direct measurements of the turbulent air-sea fluxes of momentum, heat, moisture and gases. are often made using sensors mounted on ships. Ship-based turbulent wind measurements are corrected for platform motion using well established techniques, but biases at scales associated with wave and platform motion are often still apparent in the flux measurements. It has been uncertain whether this signal is due to time-varying distortion of the air flow over the platform, or to wind-wave interactions impacting the turbulence. Methods for removing such motion-scale biases from scalar measurements have previously been published but their application to momentum flux measurements remains controversial. Here we show that the measured motion-scale bias has a dependence on the horizontal ship velocity, and that a correction for it reduces the dependence of the measured momentum flux on the orientation of the ship to the wind. We conclude that the bias is due to experimental error, and that time-varying motion-dependent flow distortion is the likely source.

  11. Resolving the abundance and air-sea fluxes of airborne microorganisms in the North Atlantic Ocean.

    PubMed

    Mayol, Eva; Jiménez, María A; Herndl, Gerhard J; Duarte, Carlos M; Arrieta, Jesús M

    2014-01-01

    Airborne transport of microbes may play a central role in microbial dispersal, the maintenance of diversity in aquatic systems and in meteorological processes such as cloud formation. Yet, there is almost no information about the abundance and fate of microbes over the oceans, which cover >70% of the Earth's surface and are the likely source and final destination of a large fraction of airborne microbes. We measured the abundance of microbes in the lower atmosphere over a transect covering 17° of latitude in the North Atlantic Ocean and derived estimates of air-sea exchange of microorganisms from meteorological data. The estimated load of microorganisms in the atmospheric boundary layer ranged between 6 × 10(4) and 1.6 × 10(7) microbes per m(2) of ocean, indicating a very dynamic air-sea exchange with millions of microbes leaving and entering the ocean per m(2) every day. Our results show that about 10% of the microbes detected in the boundary layer were still airborne 4 days later and that they could travel up to 11,000 km before they entered the ocean again. The size of the microbial pool hovering over the North Atlantic indicates that it could play a central role in the maintenance of microbial diversity in the surface ocean and contribute significantly to atmospheric processes.

  12. A Newly Distributed Satellite-based Global Air-sea Surface Turbulent Fluxes Data Set -- GSSTF2b

    NASA Astrophysics Data System (ADS)

    Shie, C.; Nelkin, E.; Ardizzone, J.; Savtchenko, A.; Chiu, L. S.; Adler, R. F.; Lin, I.; Gao, S.

    2010-12-01

    Accurate sea surface turbulent flux measurements are crucial to understanding the global water and energy cycle changes. Remote sensing is a valuable tool for global monitoring of these flux measurements. The GSSTF (Goddard Satellite-based Surface Turbulent Fluxes) algorithm was thus developed and applied to remote sensing research and applications. The recently revived and produced daily global (1ox1o) GSSTF2b (Version-2b) dataset (July 1987-December 2008) is currently under processing for an official distribution by NASA GES DISC (Goddard Earth Sciences Data and Information Services Center) due by the end of this month (September, 2010). Like its predecessor product GSSTF2, GSSTF2b is expected to provide the scientific community a longer-period and useful turbulent surface flux dataset for global energy and water cycle research, as well as regional and short period data analyses. We have recently been funded by the NASA/MEaSUREs Program to resume processing of the GSSTF with an objective of continually producing an up-to-date uniform and reliable dataset of sea surface turbulent fluxes, derived from improved input remote sensing data and model reanalysis, which would continue to be useful for global energy and water flux research and applications. The daily global (1ox1o) GSSTF2b dataset has lately been produced using upgraded and improved input datasets such as the Special Sensor Microwave Imager (SSM/I) Version-6 (V6) product (including brightness temperature [Tb], total precipitable water [W], and wind speed [U]) and the NCEP/DOE Reanalysis-2 (R2) product (including sea skin temperature [SKT], 2-meter air temperature [T2m], and sea level pressure [SLP]). The input datasets previously used for producing the GSSTF2 product were the SSM/I Version-4 (V4) product and the NCEP Reanalysis-1 (R1) product. The newly produced GSSTF2b was found to generally agree better with available ship measurements obtained from several field experiments in 1999 than its counterpart

  13. Air-sea fluxes of CO2 and CH4 from the Penlee Point Atmospheric Observatory on the south-west coast of the UK

    NASA Astrophysics Data System (ADS)

    Yang, Mingxi; Bell, Thomas G.; Hopkins, Frances E.; Kitidis, Vassilis; Cazenave, Pierre W.; Nightingale, Philip D.; Yelland, Margaret J.; Pascal, Robin W.; Prytherch, John; Brooks, Ian M.; Smyth, Timothy J.

    2016-05-01

    We present air-sea fluxes of carbon dioxide (CO2), methane (CH4), momentum, and sensible heat measured by the eddy covariance method from the recently established Penlee Point Atmospheric Observatory (PPAO) on the south-west coast of the United Kingdom. Measurements from the south-westerly direction (open water sector) were made at three different sampling heights (approximately 15, 18, and 27 m above mean sea level, a.m.s.l.), each from a different period during 2014-2015. At sampling heights ≥ 18 m a.m.s.l., measured fluxes of momentum and sensible heat demonstrate reasonable ( ≤ ±20 % in the mean) agreement with transfer rates over the open ocean. This confirms the suitability of PPAO for air-sea exchange measurements in shelf regions. Covariance air-sea CO2 fluxes demonstrate high temporal variability. Air-to-sea transport of CO2 declined from spring to summer in both years, coinciding with the breakdown of the spring phytoplankton bloom. We report, to the best of our knowledge, the first successful eddy covariance measurements of CH4 emissions from a marine environment. Higher sea-to-air CH4 fluxes were observed during rising tides (20 ± 3; 38 ± 3; 29 ± 6 µmole m-2 d-1 at 15, 18, 27 m a.m.s.l.) than during falling tides (14 ± 2; 22 ± 2; 21 ± 5 µmole m-2 d-1), consistent with an elevated CH4 source from an estuarine outflow driven by local tidal circulation. These fluxes are a few times higher than the predicted CH4 emissions over the open ocean and are significantly lower than estimates from other aquatic CH4 hotspots (e.g. polar regions, freshwater). Finally, we found the detection limit of the air-sea CH4 flux by eddy covariance to be 20 µmole m-2 d-1 over hourly timescales (4 µmole m-2 d-1 over 24 h).

  14. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  15. Comparing air-sea turbulent fluxes in reanalyses and climate models - a new framework

    NASA Astrophysics Data System (ADS)

    Gulev, S.; Tilinina, N.; Belyaev, K.

    2013-12-01

    Reanalyses fluxes and flux-related variables at high temporal resolution are widely used for forcing ocean general circulation models, case studies and estimation of regional energy budgets. We suggest a new approach for comparative assessment of fluxes in reanalyses and models based on application of modified Fisher-Tippett (MFT) distribution to turbulent heat fluxes. Two comparisons were performed - using direct surface turbulent flux output from different products (NCEP, NCEP-DOE, NCEP-CFSR, MERRA, JRA-25, ERA-Interim) and applying a single parameterization (COARE-3) to the reanalysis state variables. These allow for distinguishing between the impact of reanalysis surface parameterizations and variables onto surface turbulent fluxes. Statistical properties of surface turbulent fluxes were intercompared in terms of the MFT distribution parameters (scale and location) and extreme flux estimates derived from the distribution tails. In all reanalyses extreme turbulent heat fluxes amount to 1500-2000 W/m2 (for the 99th percentile) and can exceed 2000 W/m2 for higher percentiles in the western boundary current extension (WBCE) regions. Different reanalyses show significantly different shape of MFT distribution, implying considerable differences in the estimates of extreme fluxes. The highest extreme turbulent latent heat fluxes are diagnosed in NCEP-DOE, ERA-Interim and NCEP-CFSR reanalyses with the smallest being in MERRA. These differences may not necessarily reflect the differences in mean values. Analysis shows that differences in statistical properties of the state variables are the major source of differences in the shape of PDF of fluxes and in the estimates of extreme fluxes while the contribution of computational schemes used in different reanalyses is minor. The strongest differences in the characteristics of probability distributions of surface fluxes between different reanalyses are found in the Southern Ocean. Importantly, climate models considerably

  16. Eddy covariance flux of sulfur dioxide to the sea surface: Air-side resistance to deposition of a highly soluble gas

    NASA Astrophysics Data System (ADS)

    Porter, J.; De Bruyn, W. J.; Miller, S. D.; Saltzman, E. S.

    2014-12-01

    Deposition to the sea surface represents a major atmospheric removal mechanism for sulfur dioxide and many other highly soluble products of tropospheric photochemistry. Such gases include nitric acid, ammonia, organic acids, sulfur dioxide, and highly soluble organic compounds such as methanol and acetone. The deposition of highly soluble gases is controlled by turbulent and diffusive transport on the air side of the air/sea interface. In this study, air/sea fluxes of the soluble gas sulfur dioxide (SO2 ), sensible and latent heat, and momentum were measured using eddy covariance. This was a pilot study carried out in April 2014 on Scripps pier in La Jolla, California, that was designed to assess the potential for measuring SO2 fluxes over the ocean. SO2 was detected using chemical ion mass spectrometry in negative ion mode with a sensitivity of roughly 100 Hz/ppt. The ionization scheme involved addition of ozone to a dried air stream and subsequent conversion of SO2 to the SO5 - ion. The results demonstrate the feasibility of seagoing SO2 flux measurements. Such measurements can be used to constrain the depositional velocities of soluble gases and test models for air-side resistance to air/sea gas transfer.

  17. Elemental mercury (Hg(0)) in air and surface waters of the Yellow Sea during late spring and late fall 2012: concentration, spatial-temporal distribution and air/sea flux.

    PubMed

    Ci, Zhijia; Wang, Chunjie; Wang, Zhangwei; Zhang, Xiaoshan

    2015-01-01

    The Yellow Sea in East Asia receives great Hg input from regional emissions. However, Hg cycling in this marine system is poorly investigated. In late spring and late fall 2012, we determined gaseous elemental Hg (GEM or Hg(0)) in air and dissolved gaseous Hg (DGM, mainly Hg(0)) in surface waters to explore the spatial-temporal variations of Hg(0) and further to estimate the air/sea Hg(0) flux in the Yellow Sea. The results showed that the GEM concentrations in the two cruises were similar (spring: 1.86±0.40 ng m(-3); fall: 1.84±0.50 ng m(-3)) and presented similar spatial variation pattern with elevated concentrations along the coast of China and lower concentrations in the open ocean. The DGM concentrations of the two cruises were also similar with 27.0±6.8 pg L(-1) in the spring cruise and 28.2±9.0 pg L(-1) in the fall cruise and showed substantial spatial variation. The air/sea Hg(0) fluxes in the spring cruise and fall cruise were estimated to be 1.06±0.86 ng m(-2) h(-1) and 2.53±2.12 ng m(-2) h(-1), respectively. The combination of this study and our previous summer cruise showed that the summer cruise presented enhanced values of GEM, DGM and air/sea Hg(0) flux. The possible reason for this trend was that high solar radiation in summer promoted Hg(0) formation in seawater, and the high wind speed during the summer cruise significantly increased Hg(0) emission from sea surface to atmosphere and subsequently enhanced the GEM levels.

  18. Relationships Between the Bulk-Skin Sea Surface Temperature Difference, Wind, and Net Air-Sea Heat Flux

    NASA Technical Reports Server (NTRS)

    Emery, William J.; Castro, Sandra L.; Lindstrom, Eric (Technical Monitor)

    2002-01-01

    The primary purpose of this project was to evaluate and improve models for the bulk-skin temperature difference to the point where they could accurately and reliably apply under a wide variety of environmental conditions. To accomplish this goal, work was conducted in three primary areas. These included production of an archive of available data sets containing measurements of the skin and bulk temperatures and associated environmental conditions, evaluation of existing skin layer models using the compiled data archive, and additional theoretical work on the development of an improved model using the data collected under diverse environmental conditions. In this work we set the basis for a new physical model of renewal type, and propose a parameterization for the temperature difference across the cool skin of the ocean in which the effects of thermal buoyancy, wind stress, and microscale breaking are all integrated by means of the appropriate renewal time scales. Ideally, we seek to obtain a model that will accurately apply under a wide variety of environmental conditions. A summary of the work in each of these areas is included in this report. A large amount of work was accomplished under the support of this grant. The grant supported the graduate studies of Sandra Castro and the preparation of her thesis which will be completed later this year. This work led to poster presentations at the 1999 American Geophysical Union Fall Meeting and 2000 IGARSS meeting. Additional work will be presented in a talk at this year's American Meteorological Society Air-Sea Interaction Meeting this May. The grant also supported Sandra Castro during a two week experiment aboard the R/P Flip (led by Dr. Andrew Jessup of the Applied Physics Laboratory) to help obtain additional shared data sets and to provide Sandra with a fundamental understanding of the physical processes needed in the models. In a related area, the funding also partially supported Dr. William Emery and Daniel

  19. Synoptic evaluation of carbon cycling in Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M.

    2013-10-01

    The accelerated decline in Arctic sea ice combined with an ongoing trend toward a more dynamic atmosphere is modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of identifying indices of ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. The mean atmospheric forcing was a mild upwelling-favorable wind (~5 km h-1) blowing from the N-E and a decaying ice cover (<80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2 with a mean uptake rate of -2.0 ± 3.3 mmol C m-2d-1. We attribute this discrepancy to: (1) elevated PP rates (>600 mg C m-2d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (>10mmol C m-2d-1). Although generally <100 mg C m-2d-1, daily PP rates cumulated to a total PP of ~437.6 × 103 t C, which was roughly twice higher than the organic carbon delivery by river inputs (~241.2 × 103 t C). Subsurface PP represented 37.4% of total PP for the

  20. Mercury in the marine boundary layer and seawater of the South China Sea: Concentrations, sea/air flux, and implication for land outflow

    NASA Astrophysics Data System (ADS)

    Fu, Xuewu; Feng, Xinbin; Zhang, Gan; Xu, Weihai; Li, Xiangdong; Yao, Hen; Liang, Peng; Li, Jun; Sommar, Jonas; Yin, Runsheng; Liu, Na

    2010-03-01

    Using R/V Shiyan 3 as a sampling platform, measurements of gaseous elemental mercury (GEM), surface seawater total mercury (THg), methyl mercury (MeHg), and dissolved gaseous mercury (DGM) were carried out above and in the South China Sea (SCS). Measurements were collected for 2 weeks (10 to 28 August 2007) during an oceanographic expedition, which circumnavigated the northern SCS from Guangzhou (Canton), Hainan Inland, the Philippines, and back to Guangzhou. GEM concentrations over the northern SCS ranged from 1.04 to 6.75 ng m-3 (mean: 2.62 ng m-3, median: 2.24 ng m-3). The spatial distribution of GEM was characterized by elevated concentrations near the coastal sites adjacent to mainland China and lower concentrations at stations in the open sea. Trajectory analysis revealed that high concentrations of GEM were generally related to air masses from south China and the Indochina peninsula, while lower concentrations of GEM were related to air masses from the open sea area, reflecting great Hg emissions from south China and Indochina peninsula. The mean concentrations of THg, MeHg, and DGM in surface seawater were 1.2 ± 0.3 ng L-1, 0.12 ± 0.05 ng L-1, and 36.5 ± 14.9 pg L-1, respectively. In general, THg and MeHg levels in the northern SCS were higher compared to results reported from most other oceans/seas. Elevated THg levels in the study area were likely attributed to significant Hg delivery from surrounding areas of the SCS primarily via atmospheric deposition and riverine input, whereas other sources like in situ production by various biotic and abiotic processes may be important for MeHg. Average sea/air flux of Hg in the study area was estimated using a gas exchange method (4.5 ± 3.4 ng m-2 h-1). This value was comparable to those from other coastal areas and generally higher than those from open sea environments, which may be attributed to the reemission of Hg previously transported to this area.

  1. Modeling air/sea flux parameters in a coastal area: A comparative study of results from the TOGA COARE model and the NOAA Buoy model

    NASA Astrophysics Data System (ADS)

    Sopkin, Kristin; Mizak, Connie; Gilbert, Sherryl; Subramanian, Vembu; Luther, Mark; Poor, Noreen

    Because estuaries and coastal regions are particularly susceptible to nutrient over-enrichment due to their close proximity to source-rich regions, a goal of the BRACE study was to improve estimates of nitrogen air/sea transfer rates in the Tampa Bay Estuary. Our objective was to critically evaluate two air/sea gas exchange models to determine their efficacy for use in a coastal region, with the ultimate goal of improving nitrogen exchange estimates in Tampa Bay. We used meteorological data and oceanographic parameters collected hourly at an instrumented tower located in Middle Tampa Bay, Florida. The data was used to determine the friction velocity and the turbulent flux of heat and moisture across the air/sea interface and then compared with modeled parameters at the same offshore site. On average both models underpredicted sensible heat flux and there was considerable scatter in the data during stable conditions, indicating that nitrogen gas exchange rates may also be underestimated. Model improvement, however, was observed with friction velocity comparisons. Model inter-comparisons of sensible heat flux and friction velocity suggest excellent agreement between the TOGA COARE and the NOAA Buoy models, but model estimated heat transfer coefficients and latent heat fluxes did not agree as well. Based on our analysis, we conclude that both models are suitable for use in a coastal environment to estimate nitrogen air/sea gas exchange, although the NOAA Buoy model requires fewer meteorological inputs. However, if the purpose is to conduct more sophisticated microscale modeling of air/sea interactions, we recommend the TOGA COARE model.

  2. Predicting the Turbulent Air-Sea Surface Fluxes, Including Spray Effects, from Weak to Strong Winds

    DTIC Science & Technology

    2013-09-30

    Engineering Laboratory started in FY12 a project to study spray icing of offshore structures that is funded under ONR’s Arctic program. In January...20295. [in press, refereed] Jones, K. F., and E. L Andreas, 2012: Sea spray concentrations and the icing of fixed offshore structures . Quarterly...Including Spray Effects, from Weak to Strong Winds Edgar L Andreas NorthWest Research Associates, Inc. 25 Eagle Ridge Lebanon, New Hampshire 03766

  3. Reconstruction of super-resolution fields of ocean pCO2 and air-sea fluxes of CO2 from satellite imagery in the Southeastern Atlantic

    NASA Astrophysics Data System (ADS)

    Hernández-Carrasco, I.; Sudre, J.; Garçon, V.; Yahia, H.; Garbe, C.; Paulmier, A.; Dewitte, B.; Illig, S.; Dadou, I.

    2015-01-01

    The knowledge of Green House Gases GHGs fluxes at the air-sea interface at high resolution is crucial to accurately quantify the role of the ocean in the absorption and emission of GHGs. In this paper we present a novel method to reconstruct maps of surface ocean partial pressure of CO2, pCO2, and air-sea CO2 fluxes at super resolution (4 km) using Sea Surface Temperature (SST) and Ocean Colour (OC) data at this resolution, and CarbonTracker CO2 fluxes data at low resolution (110 km). Inference of super-resolution of pCO2, and air-sea CO2 fluxes is performed using novel nonlinear signal processing methodologies that prove efficient in the context of oceanography. The theoretical background comes from the Microcanonical Multifractal Formalism which unlocks the geometrical determination of cascading properties of physical intensive variables. As a consequence, a multiresolution analysis performed on the signal of the so-called singularity exponents allows the correct and near optimal cross-scale inference of GHGs fluxes, as the inference suits the geometric realization of the cascade. We apply such a methodology to the study offshore of the Benguela area. The inferred representation of oceanic partial pressure of CO2 improves and enhances the description provided by CarbonTracker, capturing the small scale variability. We examine different combinations of Ocean Colour and Sea Surface Temperature products in order to increase the number of valid points and the quality of the inferred pCO2 field. The methodology is validated using in-situ measurements by means of statistical errors. We obtain that mean absolute and relative errors in the inferred values of pCO2 with respect to in-situ measurements are smaller than for CarbonTracker.

  4. Model studies of the flux of CO{sub 2} over the air-sea interface in the Baltic Sea

    SciTech Connect

    Ohlson, M.

    1994-12-31

    In the discussion about the green house effect generated by the burning of fossil fuels, carbon dioxide (CO{sub 2}) has a key role. A major part of the surplus CO{sub 2} has been suggested, by the scientific community, to be withdrawn from the atmosphere and to be taken up by the growth in continental shelf areas with high primary production, and in terrestrial forests. The exact quantity and reaction ways and mechanisms of those processes are not known today. The Baltic Sea is, for several reasons, a well chosen area to study this phenomenon. It is a shallow continental Mediterranean sea, in this area almost the first measurements of the carbonate system were carried out in the end of the last century. This has resulted in long time series of measurements of the carbonate system available for use in, e.g. modelling work, a working numerical carbonate model.

  5. CO2 air-sea fluxes across the Portuguese estuaries Tagus and Sado

    NASA Astrophysics Data System (ADS)

    Oliveira, A. P.; Cabeçadas, G.; Nogueira, M.

    2009-04-01

    Generally, estuaries and proximal shelves under the direct influence of river runoff and large inputs of organic matter are mostly heterotrophic and, therefore, act as a carbon source. In this context the CO2 dynamics in Tagus and Sado estuaries (SW Portugal) was studied under two different climate and hydrological situations. These moderately productive mesotidal coastal-plain lagoon-type estuaries, localised in the center of Portugal and distant 30-40 km apart, present quite different freshwater inflows, surface areas and water residence times. A study performed in 2001 revealed that the magnitude of CO2 fluxes in the two estuarine systems varied seasonally. CO2 emissions during the huge rainfall winter were similar in both estuaries, reaching a mean value of ~50 mmol m-2 d-1, while in spring emissions from Sado were ~6 times higher then Tagus ones, attaining a mean value of 62 mmol m-2 d-1. Nevertheless, in both sampling periods, Sado estuary showed, within the upper estuary (salinity

  6. Accounting for observation uncertainties in an evaluation metric of low latitude turbulent air-sea fluxes: application to the comparison of a suite of IPSL model versions

    NASA Astrophysics Data System (ADS)

    Servonnat, Jérôme; Găinuşă-Bogdan, Alina; Braconnot, Pascale

    2016-11-01

    Turbulent momentum and heat (sensible heat and latent heat) fluxes at the air-sea interface are key components of the whole energetic of the Earth's climate. The evaluation of these fluxes in the climate models is still difficult because of the large uncertainties associated with the reference products. In this paper we present an objective metric accounting for reference uncertainties to evaluate the annual cycle of the low latitude turbulent fluxes of a suite of IPSL climate models. This metric consists in a Hotelling T 2 test between the simulated and observed field in a reduce space characterized by the dominant modes of variability that are common to both the model and the reference, taking into account the observational uncertainty. The test is thus more severe when uncertainties are small as it is the case for sea surface temperature (SST). The results of the test show that for almost all variables and all model versions the model-reference differences are not zero. It is not possible to distinguish between model versions for sensible heat and meridional wind stress, certainly due to the large observational uncertainties. All model versions share similar biases for the different variables. There is no improvement between the reference versions of the IPSL model used for CMIP3 and CMIP5. The test also reveals that the higher horizontal resolution fails to improve the representation of the turbulent surface fluxes compared to the other versions. The representation of the fluxes is further degraded in a version with improved atmospheric physics with an amplification of some of the biases in the Indian Ocean and in the intertropical convergence zone. The ranking of the model versions for the turbulent fluxes is not correlated with the ranking found for SST. This highlights that despite the fact that SST gradients are important for the large-scale atmospheric circulation patterns, other factors such as wind speed, and air-sea temperature contrast play an

  7. Accounting for observational uncertainties in the evaluation of low latitude turbulent air-sea fluxes simulated in a suite of IPSL model versions

    NASA Astrophysics Data System (ADS)

    Servonnat, Jerome; Braconnot, Pascale; Gainusa-Bogdan, Alina

    2015-04-01

    Turbulent momentum and heat (sensible and latent) fluxes at the air-sea interface are key components of the whole energetic of the Earth's climate and their good representation in climate models is of prime importance. In this work, we use the methodology developed by Braconnot & Frankignoul (1993) to perform a Hotelling T2 test on spatio-temporal fields (annual cycles). This statistic provides a quantitative measure accounting for an estimate of the observational uncertainty for the evaluation of low-latitude turbulent air-sea fluxes in a suite of IPSL model versions. The spread within the observational ensemble of turbulent flux data products assembled by Gainusa-Bogdan et al (submitted) is used as an estimate of the observational uncertainty for the different turbulent fluxes. The methodology holds on a selection of a small number of dominating variability patterns (EOFs) that are common to both the model and the observations for the comparison. Consequently it focuses on the large-scale variability patterns and avoids the possibly noisy smaller scales. The results show that different versions of the IPSL couple model share common large scale model biases, but also that there the skill on sea surface temperature is not necessarily directly related to the skill in the representation of the different turbulent fluxes. Despite the large error bars on the observations the test clearly distinguish the different merits of the different model version. The analyses of the common EOF patterns and related time series provide guidance on the major differences with the observations. This work is a first attempt to use such statistic on the evaluation of the spatio-temporal variability of the turbulent fluxes, accounting for an observational uncertainty, and represents an efficient tool for systematic evaluation of simulated air-seafluxes, considering both the fluxes and the related atmospheric variables. References Braconnot, P., and C. Frankignoul (1993), Testing Model

  8. Synoptic evaluation of carbon cycling in the Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M.

    2014-05-01

    The accelerated decline in Arctic sea ice and an ongoing trend toward more energetic atmospheric and oceanic forcings are modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in the southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of documenting the ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. During the field campaign, the mean wind field was a mild upwelling-favorable wind (~ 5 km h-1) from the NE. A decaying ice cover (< 80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2, with an uptake rate of -2.0 ± 3.3 mmol C m-2 d-1 (mean ± standard deviation associated with spatial variability). We attribute this discrepancy to (1) elevated PP rates (> 600 mg C m-2 d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (> 10 mmol C m-2 d-1). Daily PP rates were generally < 100 mg C m-2 d-1 and cumulated to a total PP of ~ 437.6 × 103 t C for the region over a 35-day period. This amount was about twice the

  9. Natural Air-Sea Flux of CO2 in Simulations of the NASA-GISS Climate Model: Sensitivity to the Physical Ocean Model Formulation

    NASA Technical Reports Server (NTRS)

    Romanou, A.; Gregg, Watson W.; Romanski, J.; Kelley, M.; Bleck, R.; Healy, R.; Nazarenko, L.; Russell, G.; Schmidt, G. A.; Sun, S.; Tausnev, N.

    2013-01-01

    Results from twin control simulations of the preindustrial CO2 gas exchange (natural flux of CO2) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air-sea flux of CO2, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO2) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean).

  10. Spatio-temporal dynamics of biogeochemical processes and air-sea CO2 fluxes in the Western English Channel based on two years of FerryBox deployment

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Latimier, M.; Macé, E.; Morin, P.; Vernet, M.; Bozec, Y.

    2014-12-01

    From January 2011 to January 2013, a FerryBox system was installed on a Voluntary Observing Ship (VOS), which crossed the Western English Channel (WEC) between Roscoff (France) and Plymouth (UK) up to 3 times a day. The FerryBox continuously measured sea surface temperature (SST), sea surface salinity (SSS), dissolved oxygen (DO), fluorescence and partial pressure of CO2 (from April 2012) along the ferry track. Sensors were calibrated based on 714 bimonthly surface samplings with precisions of 0.016 for SSS, 3.3 μM for DO, 0.40 μg L- 1 for Chlorophyll-a (Chl-a) (based on fluorescence measurements) and 5.2 μatm for pCO2. Over the 2 years of deployment (900 crossings), we reported 9% of data lost due to technical issues and quality checked data was obtained to allow investigation of the dynamics of biogeochemical processes related to air-sea CO2 fluxes in the WEC. Based on this unprecedented high-frequency dataset, the physical structure of the WEC was assessed using SST anomalies and the presence of a thermal front was observed around the latitude 49.5°N, which divided the WEC in two main provinces: the seasonally stratified northern WEC (nWEC) and the all-year well-mixed southern WEC (sWEC). These hydrographical properties strongly influenced the spatial and inter-annual distributions of phytoplankton blooms, which were mainly limited by nutrients and light availability in the nWEC and the sWEC, respectively. Air-sea CO2 fluxes were also highly related to hydrographical properties of the WEC between late April and early September 2012, with the sWEC a weak source of CO2 to the atmosphere of 0.9 mmol m- 2 d- 1, whereas the nWEC acted as a sink for atmospheric CO2 of 6.9 mmol m- 2 d- 1. The study of short time-scale dynamics of air-sea CO2 fluxes revealed that an intense and short (less than 10 days) summer bloom in the nWEC contributed to 29% of the CO2 sink during the productive period, highlighting the necessity for high frequency observations in coastal

  11. High resolution measurements of methane and carbon dioxide in surface waters over a natural seep reveal dynamics of dissolved phase air-sea flux.

    PubMed

    Du, Mengran; Yvon-Lewis, Shari; Garcia-Tigreros, Fenix; Valentine, David L; Mendes, Stephanie D; Kessler, John D

    2014-09-02

    Marine hydrocarbon seeps are sources of methane and carbon dioxide to the ocean, and potentially to the atmosphere, though the magnitude of the fluxes and dynamics of these systems are poorly defined. To better constrain these variables in natural environments, we conducted the first high-resolution measurements of sea surface methane and carbon dioxide concentrations in the massive natural seep field near Coal Oil Point (COP), California. The corresponding high resolution fluxes were calculated, and the total dissolved phase air-sea fluxes over the surveyed plume area (∼363 km(2)) were 6.66 × 10(4) to 6.71 × 10(4) mol day(-1) with respect to CH4 and -6.01 × 10(5) to -5.99 × 10(5) mol day(-1) with respect to CO2. The mean and standard deviation of the dissolved phase air-sea fluxes of methane and carbon dioxide from the contour gridding analysis were estimated to be 0.18 ± 0.19 and -1.65 ± 1.23 mmol m(-2) day(-1), respectively. This methane flux is consistent with previous, lower-resolution estimates and was used, in part, to conservatively estimate the total area of the dissolved methane plume at 8400 km(2). The influx of carbon dioxide to the surface water refutes the hypothesis that COP seep methane appreciably influences carbon dioxide dynamics. Seeing that the COP seep field is one of the biggest natural seeps, a logical conclusion could be drawn that microbial oxidation of methane from natural seeps is of insufficient magnitude to change the resulting plume area from a sink of atmospheric carbon dioxide to a source.

  12. The carbon dioxide system on the Mississippi River-dominated continental shelf in the northern Gulf of Mexico: 1. Distribution and air-sea CO2 flux.

    PubMed

    Huang, Wei-Jen; Cai, Wei-Jun; Wang, Yongchen; Lohrenz, Steven E; Murrell, Michael C

    2015-03-01

    River-dominated continental shelf environments are active sites of air-sea CO2 exchange. We conducted 13 cruises in the northern Gulf of Mexico, a region strongly influenced by fresh water and nutrients delivered from the Mississippi and Atchafalaya River system. The sea surface partial pressure of carbon dioxide (pCO2) was measured, and the air-sea CO2 flux was calculated. Results show that CO2 exchange exhibited a distinct seasonality: the study area was a net sink of atmospheric CO2 during spring and early summer, and it was neutral or a weak source of CO2 to the atmosphere during midsummer, fall, and winter. Along the salinity gradient, across the shelf, the sea surface shifted from a source of CO2 in low-salinity zones (0≤S<17) to a strong CO2 sink in the middle-to-high-salinity zones (17≤S<33), and finally was a near-neutral state in the high-salinity areas (33≤S<35) and in the open gulf (S≥35). High pCO2 values were only observed in narrow regions near freshwater sources, and the distribution of undersaturated pCO2 generally reflected the influence of freshwater inputs along the shelf. Systematic analyses of pCO2 variation demonstrated the importance of riverine nitrogen export; that is, riverine nitrogen-enhanced biological removal, along with mixing processes, dominated pCO2 variation along the salinity gradient. In addition, extreme or unusual weather events were observed to alter the alongshore pCO2 distribution and to affect regional air-sea CO2 flux estimates. Overall, the study region acted as a net CO2 sink of 0.96 ± 3.7 mol m(-2) yr(-1) (1.15 ± 4.4 Tg C yr(-1)).

  13. Sea-air CO2 flux in the North Atlantic subtropical gyre: Role and influence of Sub-Tropical Mode Water formation

    NASA Astrophysics Data System (ADS)

    Andersson, Andreas J.; Krug, Lilian A.; Bates, Nicholas R.; Doney, Scott C.

    2013-07-01

    The uptake of atmospheric carbon dioxide (CO2) into the mid-latitudes of the North Atlantic Ocean through the production of wintertime Sub-Tropical Mode Water (STMW) also known as Eighteen Degree Water (EDW) is poorly quantified and constrained. Nonetheless, it has been proposed that the EDW could serve as an important short-term sink of anthropogenic CO2. The objective of the present investigation was to determine sea-air CO2 gas exchange rates and seawater CO2 dynamics during wintertime formation of EDW in the North Atlantic Ocean. During 2006 and 2007, several research cruises were undertaken as part of the CLIMODE project across the northwest Atlantic Ocean with the intent to study the pre-conditioning, formation, and the evolution of EDW. Sea-air CO2 exchange rates were calculated based on measurements of atmospheric pCO2, surface seawater pCO2 and wind speed with positive values denoting a net flux from the surface ocean to the atmosphere. Average sea-air CO2 flux calculated along cruise tracks in the formation region equaled -18±6 mmol CO2 m-2 d-1 and -14±9 mmol CO2 m-2 d-1 in January of 2006 and March of 2007, respectively. Average sea-air CO2 flux in newly formed outcropping EDW in February and March of 2007 equaled -28±10 mmol CO2 m-2 d-1. These estimates exceeded previous flux estimates in this region by 40-185%. The magnitude of CO2 flux was mainly controlled by the observed variability in wind speed and ΔpCO2 with smaller changes owing to variability in sea surface temperature. Small but statistically significant difference (4.1±2.6 μmol kg-1) in dissolved inorganic carbon (DIC) was observed in two occurrences of newly formed EDW in February and March of 2007. This difference was explained either by differences in the relative contribution from different water masses involved in the initial formation process of EDW or temporal changes owing to sea-air CO2 exchange (˜25%) and vertical and/or lateral mixing (˜75%) with water masses high in DIC

  14. Dynamics of air-sea CO2 fluxes in the North-West European Shelf based on Voluntary Observing Ship (VOS) and satellite observations

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Macé, E.; Morin, P.; Salt, L. A.; Vernet, M.; Taylor, B.; Paxman, K.; Bozec, Y.

    2015-04-01

    From January 2011 to December 2013, we constructed a comprehensive pCO2 dataset based on voluntary observing ship (VOS) measurements in the Western English Channel (WEC). We subsequently estimated surface pCO2 and air-sea CO2 fluxes in north-west European continental shelf waters using multiple linear regressions (MLRs) from remotely sensed sea surface temperature (SST), chlorophyll a concentration (Chl a), the gas transfer velocity coefficient (K), photosynthetically active radiation (PAR) and modeled mixed layer depth (MLD). We developed specific MLRs for the seasonally stratified northern WEC (nWEC) and the permanently well-mixed southern WEC (sWEC) and calculated surface pCO2 with relative uncertainties of 17 and 16 μatm, respectively. We extrapolated the relationships obtained for the WEC based on the 2011-2013 dataset (1) temporally over a decade and (2) spatially in the adjacent Celtic and Irish Seas (CS and IS), two regions which exhibit hydrographical and biogeochemical characteristics similar to those of WEC waters. We validated these extrapolations with pCO2 data from the SOCAT database and obtained relatively robust results with an average precision of 4 ± 22 μatm in the seasonally stratified nWEC and the southern and northern CS (sCS and nCS), but less promising results in the permanently well-mixed sWEC, IS and Cap Lizard (CL) waters. On an annual scale, seasonally stratified systems acted as a sink of CO2 from the atmosphere of -0.4, -0.9 and -0.4 mol C m-2 year-1 in the nCS, sCS and nWEC, respectively, whereas, permanently well-mixed systems acted as source of CO2 to the atmosphere of 0.2, 0.4 and 0.4 mol C m-2 year-1 in the sWEC, CL and IS, respectively. Air-sea CO2 fluxes showed important inter-annual variability resulting in significant differences in the intensity and/or direction of annual fluxes. We scaled the mean annual fluxes over six provinces for the last decade and obtained the first annual average uptake of -0.95 Tg C year-1 for this

  15. Modulation of air-sea fluxes by extratropical planetary waves and its impact during the recent surface warming slowdown

    NASA Astrophysics Data System (ADS)

    Molteni, Franco; Farneti, Riccardo; Kucharski, Fred; Stockdale, Timothy N.

    2017-02-01

    It is widely accepted that natural decadal variability played a major role in the slowdown in global warming observed in the 21st century, with sea surface cooling in the tropical Pacific recognized as a major contributor. However, the warming pause was most pronounced during boreal winter, with Northern Hemisphere flow anomalies also playing a role. Here we quantify the contribution of extratropical heat exchanges by comparing geopotential and temperature anomalies simulated by ensembles of seasonal forecasts with similar ocean temperature but different heat fluxes north of 40°N, as a result of planetary wave variability. We show that an important part of heat flux anomalies is associated with decadal variations in the phase of a specific planetary wave pattern. In model simulations covering the last three decades, this variability pattern accounts for a decrease of 0.35°C/decade in the post-1998 wintertime temperature trend over northern continents.

  16. Numerical investigation of the Arctic ice-ocean boundary layer and implications for air-sea gas fluxes

    NASA Astrophysics Data System (ADS)

    Bigdeli, Arash; Loose, Brice; Nguyen, An T.; Cole, Sylvia T.

    2017-01-01

    In ice-covered regions it is challenging to determine constituent budgets - for heat and momentum, but also for biologically and climatically active gases like carbon dioxide and methane. The harsh environment and relative data scarcity make it difficult to characterize even the physical properties of the ocean surface. Here, we sought to evaluate if numerical model output helps us to better estimate the physical forcing that drives the air-sea gas exchange rate (k) in sea ice zones. We used the budget of radioactive 222Rn in the mixed layer to illustrate the effect that sea ice forcing has on gas budgets and air-sea gas exchange. Appropriate constraint of the 222Rn budget requires estimates of sea ice velocity, concentration, mixed-layer depth, and water velocities, as well as their evolution in time and space along the Lagrangian drift track of a mixed-layer water parcel. We used 36, 9 and 2 km horizontal resolution of regional Massachusetts Institute of Technology general circulation model (MITgcm) configuration with fine vertical spacing to evaluate the capability of the model to reproduce these parameters. We then compared the model results to existing field data including satellite, moorings and ice-tethered profilers. We found that mode sea ice coverage agrees with satellite-derived observation 88 to 98 % of the time when averaged over the Beaufort Gyre, and model sea ice speeds have 82 % correlation with observations. The model demonstrated the capacity to capture the broad trends in the mixed layer, although with a significant bias. Model water velocities showed only 29 % correlation with point-wise in situ data. This correlation remained low in all three model resolution simulations and we argued that is largely due to the quality of the input atmospheric forcing. Overall, we found that even the coarse-resolution model can make a modest contribution to gas exchange parameterization, by resolving the time variation of parameters that drive the 222Rn budget

  17. Wintertime CO2 fluxes in an Arctic polynya using eddy covariance: Evidence for enhanced air-sea gas transfer during ice formation

    NASA Astrophysics Data System (ADS)

    Else, B. G. T.; Papakyriakou, T. N.; Galley, R. J.; Drennan, W. M.; Miller, L. A.; Thomas, H.

    2011-09-01

    Between Nov. 1 2007 and Jan. 31 2008, we calculated the air-sea flux of CO2, sensible heat, and water vapor in an Arctic polynya system (Amundsen Gulf, Canada) using eddy covariance equipment deployed on the research icebreaker CCGS Amundsen. During this time period, Amundsen Gulf was a dynamic sea ice environment composed primarily of first year ice with open water coverage varying between 1-14%. In all cases where measurements were influenced by open water we measured CO2 fluxes that were 1-2 orders of magnitude higher than those expected under similar conditions in the open ocean. Fluxes were typically directed toward the water surface with a mean flux of -4.88 μmol m-2 s-1 and a maximum of -27.95 μmol m-2 s-1. One case of rapid outgassing (mean value +2.10 μmol m-2 s-1) was also observed. The consistent patten of enhanced gas exchange over open water allows us to hypothesize that high water-side turbulence is the main cause of these events. Modification of the physical and chemical properties of the surface seawater by cooling and brine rejection may also play a role. A rough calculation using an estimate of open water coverage suggests that the contribution of these events to the annual regional air-sea CO2 exchange budget may make the winter months as important as the open water months. Although high, the uptake of CO2 fits within mixed layer dissolved inorganic carbon budgets derived for the region by other investigators.

  18. Response of biological production and air-sea CO2 fluxes to upwelling intensification in the California and Canary Current Systems

    NASA Astrophysics Data System (ADS)

    Lachkar, Zouhair; Gruber, Nicolas

    2013-01-01

    Upwelling-favorable winds have increased in most Eastern Boundary Upwelling Systems (EBUS) in the last decades, and it is likely that they increase further in response to global climate change. Here, we explore the response of biological production and air-sea CO2 fluxes to upwelling intensification in two of the four major EBUS, namely the California Current System (California CS) and Canary Current System (Canary CS). To this end, we use eddy-resolving regional ocean models on the basis of the Regional Oceanic Modeling System (ROMS) to which we have coupled a NPZD-type ecosystem model and a biogeochemistry module describing the carbon cycle and subject these model configurations to an idealized increase in the wind stress. We find that a doubling of the wind-stress doubles net primary production (NPP) in the southern California CS and central and northern Canary CS, while it leads to an increase of less than 50% in the central and northern California CS as well as in the southern Canary CS. This differential response is a result of i) different nutrient limitation states with higher sensitivity to upwelling intensification in regions where nutrient limitation is stronger and ii) more efficient nutrient assimilation by biology in the Canary CS relative to the California CS because of a faster nutrient-replete growth rate and longer nearshore water residence times. In the regions where production increases commensurably with upwelling intensification, the enhanced net biological uptake of CO2 compensates the increase in upwelling driven CO2 outgassing, resulting in only a small change in the biological pump efficiency and hence in a small sensitivity of air-sea CO2 fluxes to upwelling intensification. In contrast, in the central California CS as well as in the southern Canary CS around Cape Blanc, the reduced biological efficiency enhances the CO2 outgassing and leads to a substantial sensitivity of the air-sea CO2 fluxes to upwelling intensification.

  19. Production Flux of Sea-Spray Aerosol

    NASA Astrophysics Data System (ADS)

    de Leeuw, G.; Andreas, E. L.; Anguelova, M. D.; Fairall, C. W.; Lewis, E. R.; O'Dowd, C.; Schulz, M.; Schwartz, S. E.

    2010-12-01

    Knowledge of the size- and composition-dependent production flux of primary sea-spray aerosol (SSA) particles and its dependence on environmental variables is required for modeling cloud microphysical properties and aerosol radiative influences, interpreting measurements of particulate matter in coastal areas and its relation to air quality, and evaluating rates of uptake and reactions of gases in sea-spray drops. This review examines recent research pertinent to SSA production flux with emphasis on particles with r80 (equilibrium radius at 80% relative humidity) less than 1 µm and as small as 0.01 µm. Production of sea-spray particles and its dependence on controlling factors has been investigated in laboratory studies that have examined the dependences on water temperature, salinity, and the presence of organics, and in field measurements with micrometeorological techniques that use newly developed fast optical particle sizers. Extensive measurements show that water-insoluble organic matter contributes substantially to the composition of SSA particles with r80 < 0.25 µm and in locations with high biological activity can be the dominant constituent. Order-of-magnitude variation remains in estimates of the size-dependent production flux per white area, the quantity central to formulations of the production flux based on the whitecap method. This variation indicates that the production flux may depend on quantities, such as the volume flux of air bubbles to the surface, that are not accounted for in current models. Variation in estimates of the whitecap fraction as a function of wind speed contributes additional, comparable uncertainty to production flux estimates.

  20. Production flux of sea spray aerosol

    NASA Astrophysics Data System (ADS)

    de Leeuw, Gerrit; Andreas, Edgar L.; Anguelova, Magdalena D.; Fairall, C. W.; Lewis, Ernie R.; O'Dowd, Colin; Schulz, Michael; Schwartz, Stephen E.

    2011-05-01

    Knowledge of the size- and composition-dependent production flux of primary sea spray aerosol (SSA) particles and its dependence on environmental variables is required for modeling cloud microphysical properties and aerosol radiative influences, interpreting measurements of particulate matter in coastal areas and its relation to air quality, and evaluating rates of uptake and reactions of gases in sea spray drops. This review examines recent research pertinent to SSA production flux, which deals mainly with production of particles with r80 (equilibrium radius at 80% relative humidity) less than 1 μm and as small as 0.01 μm. Production of sea spray particles and its dependence on controlling factors has been investigated in laboratory studies that have examined the dependences on water temperature, salinity, and the presence of organics and in field measurements with micrometeorological techniques that use newly developed fast optical particle sizers. Extensive measurements show that water-insoluble organic matter contributes substantially to the composition of SSA particles with r80 < 0.25 μm and, in locations with high biological activity, can be the dominant constituent. Order-of-magnitude variation remains in estimates of the size-dependent production flux per white area, the quantity central to formulations of the production flux based on the whitecap method. This variation indicates that the production flux may depend on quantities such as the volume flux of air bubbles to the surface that are not accounted for in current models. Variation in estimates of the whitecap fraction as a function of wind speed contributes additional, comparable uncertainty to production flux estimates.

  1. Assessing the Potential to Derive Air-Sea Freshwater Fluxes from Aquarius-Like Observations of Surface Salinity

    NASA Technical Reports Server (NTRS)

    Zhen, Li; Adamec, David

    2009-01-01

    A state-of-the-art numerical model is used to investigate the possibility of determining freshwater flux fields from temporal changes io sea-surface salinity (SSS), a goal of the satellite salinity-measuring mission, Aquarius/SAC-D. Because the estimated advective temporal scale is usually longer than the Aquarius/SAC-D revisit time, the possibility of producing freshwater flux estimates from temporal salinity changes is first examined by using a correlation analysis. For the mean seasonal cycle, the patterns of the correlations between the freshwater fluxes and surface salinity temporal tendencies are mainly zonally oriented, and are highest where the local precipitation is also relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude moon tracks and are relatively small in the tropics. The complex correlation patterns presented here suggest that a global retrieval of the difference between evaporation and precipitation (E-P) from salinity changes requires more complex techniques than a simple consideration of local balance with surface forcing.

  2. Computation of Air-Sea Fluxes in Five Atmospheric Rivers over the Northeast Pacific Using Dropsonde Observations

    NASA Astrophysics Data System (ADS)

    Fairall, C. W.; Blomquist, B.; Gentemann, C. L.; Ralph, F. M.; Spackman, J. R.; Intrieri, J. M.; White, A. B.

    2014-12-01

    29 July 2014 Atmospheric Rivers (AR's) play a dominant role in variability of precipitation on the US W. Coast. A major AR study field effort with three research aircraft and the ship RV Ron Brown are committed to a campaign in January-February 2015. In this paper we report on an "early-start" deployment of the NOAA G-IV aircraft, which was conducted in February 2014 to test new flight modules and to work out key logistical and flight operations methods. In February 2014 the NOAA G-IV research aircraft sampled 10 ARs over the northeast Pacific Ocean. On five of these flights (Feb 08, 11, 13, 18, 21) dropsondes were deployed in a line crossing the AR so as to robustly sample the atmospheric structure. The sonde profiles yield gradients of wind speed, potential temperature, and water vapor mixing ratio in the surface layer over the ocean. Surface fluxes can be estimated from these gradients. If sea surface temperature (SST) is available, fluxes can also be computed using a bulk-flux algorithm. Conventional atmospheric sondes do not measure SST, but we developed a method to estimate SST by extrapolating the gradient to the surface. This was effective for temperature and water vapor profiles. A short iteration yielded reasonable estimates of SST and fluxes of momentum, sensible, and latent heat. The SST values were compared to satellite values. Five different satellite products were used: microwave, AMSR, wsat, TMI, and MODIS. A single satellite estimate was created as the median of these five. Standard deviation (std) of the five satellite estimates at each location is about 0.5 C. A grand comparison of satellite and sonde SST estimates for the five flights was made. For a total of 119 locations, the mean of Sonde-Satellite SST is about -0.02 C (std 0.76 C, correlation coefficient 0.983). For SST deduced from the humidity profile, the mean difference is 0.20 C (std 1.26, correlation 0.953). Surface fluxes were surprisingly small: sensible heat flux was typically

  3. The sea-air exchange of mercury (Hg) in the marine boundary layer of the Augusta basin (southern Italy): concentrations and evasion flux.

    PubMed

    Bagnato, E; Sproveri, M; Barra, M; Bitetto, M; Bonsignore, M; Calabrese, S; Di Stefano, V; Oliveri, E; Parello, F; Mazzola, S

    2013-11-01

    The first attempt to systematically investigate the atmospheric mercury (Hg) in the MBL of the Augusta basin (SE Sicily, Italy) has been undertaken. In the past the basin was the receptor for Hg from an intense industrial activity which contaminated the bottom sediments of the Bay, making this area a potential source of pollution for the surrounding Mediterranean. Three oceanographic cruises have been thus performed in the basin during the winter and summer 2011/2012, where we estimated averaged Hgatm concentrations of about 1.5±0.4 (range 0.9-3.1) and 2.1±0.98 (range 1.1-3.1) ng m(-3) for the two seasons, respectively. These data are somewhat higher than the background Hg atm value measured over the land (range 1.1±0.3 ng m(-3)) at downtown Augusta, while are similar to those detected in other polluted regions elsewhere. Hg evasion fluxes estimated at the sea/air interface over the Bay range from 3.6±0.3 (unpolluted site) to 72±0.1 (polluted site of the basin) ng m(-2) h(-1). By extending these measurements to the entire area of the Augusta basin (~23.5 km(2)), we calculated a total sea-air Hg evasion flux of about 9.7±0.1 g d(-1) (~0.004 tyr(-1)), accounting for ~0.0002% of the global Hg oceanic evasion (2000 tyr(-1)). The new proposed data set offers a unique and original study on the potential outflow of Hg from the sea-air interface at the basin, and it represents an important step for a better comprehension of the processes occurring in the marine biogeochemical cycle of this element.

  4. Net sea-air CO2 fluxes and modelled pCO2 in the southwestern subtropical Atlantic continental shelf during spring 2010 and summer 2011

    NASA Astrophysics Data System (ADS)

    Ito, Rosane Gonçalves; Garcia, Carlos Alberto Eiras; Tavano, Virginia Maria

    2016-05-01

    Sea-air CO2 fluxes over continental shelves vary substantially in time on both seasonal and sub-seasonal scales, driven primarily by variations in surface pCO2 due to several oceanic mechanisms. Furthermore, coastal zones have not been appropriately considered in global estimates of sea-air CO2 fluxes, despite their importance to ecology and to productivity. In this work, we aimed to improve our understanding of the role played by shelf waters in controlling sea-air CO2 fluxes by investigating the southwestern Atlantic Ocean (21-35°S) region, where physical, chemical and biological measurements were made on board the Brazilian R. V. Cruzeiro do Sul during late spring 2010 and early summer 2011. Features such as discharge from the La Plata River, intrusions of tropical waters on the outer shelf due to meandering and flow instabilities of the Brazil Current, and coastal upwelling in the Santa Marta Grande Cape and São Tomé Cape were detected by both in situ measurements and ocean colour and thermal satellite imagery. Overall, shelf waters in the study area were a source of CO2 to the atmosphere, with an average of 1.2 mmol CO2 m-2 day-1 for the late spring and 11.2 mmol CO2 m-2 day-1 for the early summer cruises. The spatial variability in ocean pCO2 was associated with surface ocean properties (temperature, salinity and chlorophyll-a concentration) in both the slope and shelf waters. Empirical algorithms for predicting temperature-normalized surface ocean pCO2 as a function of surface ocean properties were shown to perform well in both shelf and slope waters, except (a) within cyclonic eddies produced by baroclinic instability of the Brazil Current as detected by satellite SST imagery and (b) in coastal upwelling regions. In these regions, surface ocean pCO2 values were higher as a result of upwelled CO2-enriched subsurface waters. Finally, a pCO2 algorithm based on both sea surface temperature and surface chlorophyll-a was developed that enabled the spatial

  5. Climatological mean and decadal change in surface ocean pCO 2, and net sea-air CO 2 flux over the global oceans

    NASA Astrophysics Data System (ADS)

    Takahashi, Taro; Sutherland, Stewart C.; Wanninkhof, Rik; Sweeney, Colm; Feely, Richard A.; Chipman, David W.; Hales, Burke; Friederich, Gernot; Chavez, Francisco; Sabine, Christopher; Watson, Andrew; Bakker, Dorothee C. E.; Schuster, Ute; Metzl, Nicolas; Yoshikawa-Inoue, Hisayuki; Ishii, Masao; Midorikawa, Takashi; Nojiri, Yukihiro; Körtzinger, Arne; Steinhoff, Tobias; Hoppema, Mario; Olafsson, Jon; Arnarson, Thorarinn S.; Tilbrook, Bronte; Johannessen, Truls; Olsen, Are; Bellerby, Richard; Wong, C. S.; Delille, Bruno; Bates, N. R.; de Baar, Hein J. W.

    2009-04-01

    A climatological mean distribution for the surface water pCO 2 over the global oceans in non-El Niño conditions has been constructed with spatial resolution of 4° (latitude) ×5° (longitude) for a reference year 2000 based upon about 3 million measurements of surface water pCO 2 obtained from 1970 to 2007. The database used for this study is about 3 times larger than the 0.94 million used for our earlier paper [Takahashi et al., 2002. Global sea-air CO 2 flux based on climatological surface ocean pCO 2, and seasonal biological and temperature effects. Deep-Sea Res. II, 49, 1601-1622]. A time-trend analysis using deseasonalized surface water pCO 2 data in portions of the North Atlantic, North and South Pacific and Southern Oceans (which cover about 27% of the global ocean areas) indicates that the surface water pCO 2 over these oceanic areas has increased on average at a mean rate of 1.5 μatm y -1 with basin-specific rates varying between 1.2±0.5 and 2.1±0.4 μatm y -1. A global ocean database for a single reference year 2000 is assembled using this mean rate for correcting observations made in different years to the reference year. The observations made during El Niño periods in the equatorial Pacific and those made in coastal zones are excluded from the database. Seasonal changes in the surface water pCO 2 and the sea-air pCO 2 difference over four climatic zones in the Atlantic, Pacific, Indian and Southern Oceans are presented. Over the Southern Ocean seasonal ice zone, the seasonality is complex. Although it cannot be thoroughly documented due to the limited extent of observations, seasonal changes in pCO 2 are approximated by using the data for under-ice waters during austral winter and those for the marginal ice and ice-free zones. The net air-sea CO 2 flux is estimated using the sea-air pCO 2 difference and the air-sea gas transfer rate that is parameterized as a function of (wind speed) 2 with a scaling factor of 0.26. This is estimated by inverting

  6. Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

    NASA Technical Reports Server (NTRS)

    Signorini, Sergio; Mannino, Antonio; Najjar, Raymond G., Jr.; Friedrichs, Marjorie A. M.; Cai, Wei-Jun; Salisbury, Joe; Wang, Zhaohui Aleck; Thomas, Helmuth; Shadwick, Elizabeth

    2013-01-01

    Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.

  7. Effect of gas-transfer velocity parameterization choice on air-sea CO2 fluxes in the North Atlantic Ocean and the European Arctic

    NASA Astrophysics Data System (ADS)

    Wrobel, Iwona; Piskozub, Jacek

    2016-09-01

    The oceanic sink of carbon dioxide (CO2) is an important part of the global carbon budget. Understanding uncertainties in the calculation of this net flux into the ocean is crucial for climate research. One of the sources of the uncertainty within this calculation is the parameterization chosen for the CO2 gas-transfer velocity. We used a recently developed software toolbox, called the FluxEngine (Shutler et al., 2016), to estimate the monthly air-sea CO2 fluxes for the extratropical North Atlantic Ocean, including the European Arctic, and for the global ocean using several published quadratic and cubic wind speed parameterizations of the gas-transfer velocity. The aim of the study is to constrain the uncertainty caused by the choice of parameterization in the North Atlantic Ocean. This region is a large oceanic sink of CO2, and it is also a region characterized by strong winds, especially in winter but with good in situ data coverage. We show that the uncertainty in the parameterization is smaller in the North Atlantic Ocean and the Arctic than in the global ocean. It is as little as 5 % in the North Atlantic and 4 % in the European Arctic, in comparison to 9 % for the global ocean when restricted to parameterizations with quadratic wind dependence. This uncertainty becomes 46, 44, and 65 %, respectively, when all parameterizations are considered. We suggest that this smaller uncertainty (5 and 4 %) is caused by a combination of higher than global average wind speeds in the North Atlantic (> 7 ms-1) and lack of any seasonal changes in the direction of the flux direction within most of the region. We also compare the impact of using two different in situ pCO2 data sets (Takahashi et al. (2009) and Surface Ocean CO2 Atlas (SOCAT) v1.5 and v2.0, for the flux calculation. The annual fluxes using the two data sets differ by 8 % in the North Atlantic and 19 % in the European Arctic. The seasonal fluxes in the Arctic computed from the two data sets disagree with each

  8. A new framework for estimation and comparative assessment of air-sea turbulent fluxes in reanalyses and climate models

    NASA Astrophysics Data System (ADS)

    Gulev, Sergey; Tilinina, Natalia; Belyaev, Konstantin

    2013-04-01

    Reanalyses fluxes and flux-related variables at high temporal resolution are widely used forcing ocean general circulation models, for the case studies and estimation of regional energy budgets. In order to evaluate surface fluxes in modern era reanalyses and climate models we suggest a new approach based on two parametric modified Fisher-Tippett (MFT) distribution applied to turbulent heat fluxes. Two comparisons were performed - using direct surface turbulent flux output from different products (NCEP, NCEP-DOE, NCEP-CFSR, MERRA, JRA-25, ERA-Interim) and applying a single parameterization (COARE-3) to the reanalysis state variables. These allow for distinguishing between the impact of reanalysis surface parameterizations and variables onto surface turbulent fluxes. Statistical properties of surface turbulent fluxes were intercompared in terms of the distribution parameters (scale and location) and extreme fluxes derived from distribution tails. In all reanalyses extreme turbulent heat fluxes amount to 1500-2000 W/m2 (for the 99th percentile) and can exceed 2000 W/m2 for higher percentiles in the western boundary current extension (WBCE) regions. Different reanalyses show significantly different shape of MFT distribution, implying considerable differences in the estimates of extreme fluxes. The highest extreme turbulent latent heat fluxes are diagnosed in NCEP-DOE, ERA-Interim and NCEP-CFSR reanalyses with the smallest being in MERRA. These differences may not necessarily reflect the differences in mean values. Analysis show that differences in statistical properties of the state variables are the major source of differences in the shape of PDF and estimates of extreme fluxes while the contribution of computational schemes used in different reanalyses is minor. The strongest differences in the characteristics of probability distributions of surface fluxes between different reanalyses is found in the Southern Ocean. Importantly, climate models, being capable of

  9. Production and air-sea flux of halomethanes in the western subarctic Pacific in relation to phytoplankton pigment concentrations during the iron fertilization experiment (SEEDS II)

    NASA Astrophysics Data System (ADS)

    Hashimoto, Shinya; Toda, Shuji; Suzuki, Koji; Kato, Shungo; Narita, Yasusi; Kurihara, Michiko K.; Akatsuka, Yoko; Oda, Hiroshi; Nagai, Takahiro; Nagao, Ippei; Kudo, Isao; Uematsu, Mitsuo

    2009-12-01

    Iron could play a key role in controlling phytoplankton biomass and productivity in high-nutrient, low-chlorophyll regions. As a part of the iron fertilization experiment carried out in the western subarctic Pacific from July to August 2004 (Subarctic Pacific iron Experiment for Ecosystem Dynamics Study II—SEEDS II), we analysed the concentrations of trace gases in the seawater for 12 d following iron fertilization. The mean concentrations of chlorophyll a in the mixed layer (5-30 m depth) increased from 0.94 to 2.81 μg L -1 for 8 d in the iron patch. The mean concentrations of methyl bromide (CH 3Br; 5-30 m depth) increased from 6.4 to 13.4 pmol L -1 for 11 d; the in-patch concentration increased relative to the out-patch concentration. A linear correlation was observed between the concentrations of 19'-hexanoyloxyfucoxanthin, which is a biomarker of several prymnesiophytes, and CH 3Br in the seawater. After fertilization, the air-sea flux of CH 3Br inside the patch changed from influx to efflux from the ocean. There was no clear evidence for the increase in saturation anomaly of methyl chloride (CH 3Cl) due to iron fertilization. Furthermore, CH 3Cl fluxes did not show a tendency to increase after fertilization of the patch. In contrast to CH 3Br, no change was observed in the concentrations of bromoform (in-patch day 11 and out-patch day 11: 1.7 and 1.7 pmol L -1), dibromomethane (2.1 and 2.2 pmol L -1), and dibromochloromethane (1.0 and 1.2 pmol L -1, respectively). The concentration of isoprene, which is known to have a relationship with chlorophyll a, did not change in this study. The responses of trace gases during SEEDS II differed from the previous findings ( in situ iron enrichment experiment—EisenEx, Southern Ocean iron experiment—SOFeX, and Subarctic Ecosystem Response to Iron Enrichment Study—SERIES). Thus, in order to estimate the concomitant effect of iron fertilization on the climate, it is important to assess the induction of biological

  10. Roles of biological and physical processes in driving seasonal air-sea CO2 flux in the Southern Ocean: New insights from CARIOCA pCO2

    NASA Astrophysics Data System (ADS)

    Merlivat, L.; Boutin, J.; Antoine, D.

    2015-07-01

    On a mean annual basis, the Southern Ocean is a sink for atmospheric CO2. However the seasonality of the air-sea CO2 flux in this region is poorly documented. We investigate processes regulating air-sea CO2 flux in a large area of the Southern Ocean (38°S-55°S, 60°W-60°E) that represents nearly one third of the subantarctic zone. A seasonal budget of CO2 partial pressure, pCO2 and of dissolved inorganic carbon, DIC in the mixed layer is assessed by quantifying the impacts of biology, physics and thermodynamical effect on seawater pCO2. A focus is made on the quantification at a monthly scale of the biological consumption as it is the dominant process removing carbon from surface waters. In situ biological carbon production rates are estimated from high frequency estimates of DIC along the trajectories of CARIOCA drifters in the Atlantic and Indian sector of the Southern Ocean during four spring-summer seasons over the 2006-2009 period. Net community production (NCP) integrated over the mixed layer is derived from the daily change of DIC, and mixed layer depth estimated from Argo profiles. Eleven values of NCP are estimated and range from 30 to 130 mmol C m- 2 d- 1. They are used as a constraint for validating satellite net primary production (NPP). A satellite data-based global model is used to compute depth integrated net primary production, NPP, for the same periods along the trajectories of the buoys. Realistic NCP/NPP ratios are obtained under the condition that the SeaWiFS chlorophyll are corrected by a factor of ≈ 2-3, which is an underestimation previously reported for the Southern Ocean. Monthly satellite based NPP are computed over the 38°S-55°S, 60°W-60°E area. pCO2 derived from these NPP combined with an export ratio, and taking into account the impact of physics and thermodynamics is in good agreement with the pCO2 seasonal climatology of Takahashi (2009). On an annual timescale, mean NCP values, 4.4 to 4.9 mol C m- 2 yr- 1 are ≈ 4-5 times

  11. Sensitivity of modelled sulfate aerosol and its radiative effect on climate to ocean DMS concentration and air-sea flux

    NASA Astrophysics Data System (ADS)

    Tesdal, Jan-Erik; Christian, James R.; Monahan, Adam H.; von Salzen, Knut

    2016-09-01

    Dimethylsulfide (DMS) is a well-known marine trace gas that is emitted from the ocean and subsequently oxidizes to sulfate in the atmosphere. Sulfate aerosols in the atmosphere have direct and indirect effects on the amount of solar radiation reaching the Earth's surface. Thus, as a potential source of sulfate, ocean efflux of DMS needs to be accounted for in climate studies. Seawater concentration of DMS is highly variable in space and time, which in turn leads to high spatial and temporal variability in ocean DMS emissions. Because of sparse sampling (in both space and time), large uncertainties remain regarding ocean DMS concentration. In this study, we use an atmospheric general circulation model with explicit aerosol chemistry (CanAM4.1) and several climatologies of surface ocean DMS concentration to assess uncertainties about the climate impact of ocean DMS efflux. Despite substantial variation in the spatial pattern and seasonal evolution of simulated DMS fluxes, the global-mean radiative effect of sulfate is approximately linearly proportional to the global-mean surface flux of DMS; the spatial and temporal distribution of ocean DMS efflux has only a minor effect on the global radiation budget. The effect of the spatial structure, however, generates statistically significant changes in the global-mean concentrations of some aerosol species. The effect of seasonality on the net radiative effect is larger than that of spatial distribution and is significant at global scale.

  12. Air-Sea CO2 fluxes and NEP changes in a Baja California Coastal Lagoon during the anomalous North Pacific warm condition in 2014

    NASA Astrophysics Data System (ADS)

    Ávila López, M. D. C.; Martin Hernandez-Ayon, J. M.; Camacho-Ibar, V.; Sandoval Gil, J.; Mejía-Trejo, A.; Félix-Bermudez, A.; Pacheco-Ruiz, I.

    2015-12-01

    The present study examines the temporal variability of seawater carbonate chemistry and air-sea CO2 fluxes (FCO2) in a Baja California Mediterranean-climate coastal lagoon. This study was carried out from Nov-2013 to Nov-2014, a period in which anomalous warm conditions were present in the North Pacific Ocean influenced the local oceanography in the adjacent coastal waters off Baja California. These ocean conditions resulted on a negative anomaly of upwelling index, which led to summer-like season (weak upwelling condition) that could be observed in the response of carbon dynamics and metabolic status in San Quintín Bay. Minor changes in dissolved inorganic carbon (DIC) concentration during spring months (~100 µmol kg-1) where observed and were associated to biological processes within the lagoon. High DIC (~2200 µmol kg-1), pCO2 (~800 μatm), and minimum pH (~7.8) values were observed in summer, reflecting the predominance of respiration processes apparently mostly linked to the remineralization of sedimentary organic matter supplied from macroalgal blooms. San Quintín Bay acted as a weak source of CO2 to the atmosphere during the study period, with maximum value observed in July (~10 mmol C m-2 d-1). Temporal biomass production of macroalgae contributed to about 50% of total FCO2 estimated in spring-summer seasons, that was a potencial internal source of organic matter to fuel respiration processes in San Quintín Bay. Eelgrass metabolism contributes in a lower degree in total FCO2. During the anomalous ocean conditions in 2014, the lagoon switched seasonally between net heterotrophy and net autotrophy during the study period, where photosynthesis and respiration processes in the lagoon were closer to a balance. Whole-system metabolism and FCO2 clearly indicated the strong dependence of San Quintín Bay on upwelling conditions and benthic metabolism activity, which was mainly controlled by dominant primary producer communities.

  13. Nitrous oxide and methane in Atlantic and Mediterranean waters in the Strait of Gibraltar: Air-sea fluxes and inter-basin exchange

    NASA Astrophysics Data System (ADS)

    de la Paz, M.; Huertas, I. E.; Flecha, S.; Ríos, A. F.; Pérez, F. F.

    2015-11-01

    The global ocean plays an important role in the overall budget of nitrous oxide (N2O) and methane (CH4), as both gases are produced within the ocean and released to the atmosphere. However, for large parts of the open and coastal oceans there is little or no spatial data coverage for N2O and CH4. Hence, a better assessment of marine emissions estimates is necessary. As a contribution to remedying the scarcity of data on marine regions, N2O and CH4 concentrations have been determined in the Strait of Gibraltar at the ocean Fixed Time series (GIFT). During six cruises performed between July 2011 and November 2014 samples were collected at the surface and various depths in the water column, and subsequently measured using gas chromatography. From this we were able to quantify the temporal variability of the gas air-sea exchange in the area and examine the vertical distribution of N2O and CH4 in Atlantic and Mediterranean waters. Results show that surface Atlantic waters are nearly in equilibrium with the atmosphere whereas deeper Mediterranean waters are oversaturated in N2O, and a gradient that gradually increases with depth was detected in the water column. Temperature was found to be the main factor responsible for the seasonal variability of N2O in the surface layer. Furthermore, although CH4 levels did not reveal any feature clearly associated with the circulation of water masses, vertical distributions showed that higher concentrations are generally observed in the Atlantic layer, and that the deeper Mediterranean waters are considerably undersaturated (by up to 50%). Even though surface waters act as a source of atmospheric N2O during certain periods, on an annual basis the net N2O flux in the Strait of Gibraltar is only 0.35 ± 0.27 μmol m-2 d-1, meaning that these waters are almost in a neutral status with respect to the atmosphere. Seasonally, the region behaves as a slight sink for atmospheric CH4 in winter and as a source in spring and fall. Approximating

  14. Global sea-air CO 2 flux based on climatological surface ocean pCO 2, and seasonal biological and temperature effects

    NASA Astrophysics Data System (ADS)

    Takahashi, Taro; Sutherland, Stewart C.; Sweeney, Colm; Poisson, Alain; Metzl, Nicolas; Tilbrook, Bronte; Bates, Nicolas; Wanninkhof, Rik; Feely, Richard A.; Sabine, Christopher; Olafsson, Jon; Nojiri, Yukihiro

    Based on about 940,000 measurements of surface-water pCO 2 obtained since the International Geophysical Year of 1956-59, the climatological, monthly distribution of pCO 2 in the global surface waters representing mean non-El Niño conditions has been obtained with a spatial resolution of 4°×5° for a reference year 1995. The monthly and annual net sea-air CO 2 flux has been computed using the NCEP/NCAR 41-year mean monthly wind speeds. An annual net uptake flux of CO 2 by the global oceans has been estimated to be 2.2 (+22% or -19%) Pg C yr -1 using the (wind speed) 2 dependence of the CO 2 gas transfer velocity of Wanninkhof (J. Geophys. Res. 97 (1992) 7373). The errors associated with the wind-speed variation have been estimated using one standard deviation (about±2 m s -1) from the mean monthly wind speed observed over each 4°×5° pixel area of the global oceans. The new global uptake flux obtained with the Wanninkhof (wind speed) 2 dependence is compared with those obtained previously using a smaller number of measurements, about 250,000 and 550,000, respectively, and are found to be consistent within±0.2 Pg C yr -1. This estimate for the global ocean uptake flux is consistent with the values of 2.0±0.6 Pg C yr -1 estimated on the basis of the observed changes in the atmospheric CO 2 and oxygen concentrations during the 1990s (Nature 381 (1996) 218; Science 287 (2000) 2467). However, if the (wind speed) 3 dependence of Wanninkhof and McGillis (Res. Lett. 26 (1999) 1889) is used instead, the annual ocean uptake as well as the sensitivity to wind-speed variability is increased by about 70%. A zone between 40° and 60° latitudes in both the northern and southern hemispheres is found to be a major sink for atmospheric CO 2. In these areas, poleward-flowing warm waters meet and mix with the cold subpolar waters rich in nutrients. The pCO 2 in the surface water is decreased by the cooling effect on warm waters and by the biological drawdown of pCO 2 in

  15. Sensitivity analysis of an ocean carbon cycle model in the North Atlantic: an investigation of parameters affecting the air-sea CO2 flux, primary production and export of detritus

    NASA Astrophysics Data System (ADS)

    Scott, V.; Kettle, H.; Merchant, C. J.

    2011-06-01

    The sensitivity of the biological parameters in a nutrient-phytoplankton-zooplankton-detritus (NPZD) model in the calculation of the air-sea CO2 flux, primary production and detrital export is analysed. We explore the effect on these outputs of variation in the values of the twenty parameters that control ocean ecosystem growth in a 1-D formulation of the UK Met Office HadOCC NPZD model used in GCMs. We use and compare the results from one-at-a-time and all-at-a-time perturbations performed at three sites in the EuroSITES European Ocean Observatory Network: the Central Irminger Sea (60° N 40° W), the Porcupine Abyssal Plain (49° N 16° W) and the European Station for Time series in the Ocean Canary Islands (29° N 15° W). Reasonable changes to the values of key parameters are shown to have a large effect on the calculation of the air-sea CO2 flux, primary production, and export of biological detritus to the deep ocean. Changes in the values of key parameters have a greater effect in more productive regions than in less productive areas. The most sensitive parameters are generally found to be those controlling well-established ocean ecosystem parameterisations widely used in many NPZD-type models. The air-sea CO2 flux is most influenced by variation in the parameters that control phytoplankton growth, detrital sinking and carbonate production by phytoplankton (the rain ratio). Primary production is most sensitive to the parameters that define the shape of the photosynthesis-irradiance curve. Export production is most sensitive to the parameters that control the rate of detrital sinking and the remineralisation of detritus.

  16. Sensitivity analysis of an Ocean Carbon Cycle Model in the North Atlantic: an investigation of parameters affecting the air-sea CO2 flux, primary production and export of detritus

    NASA Astrophysics Data System (ADS)

    Scott, V.; Kettle, H.; Merchant, C. J.

    2010-12-01

    The sensitivity of the biological parameters in a nutrient-phytoplankton-zooplankton-detritus (NPZD) model in the calculation of the air-sea CO2 flux, primary production and detrital export is analysed. The NPZD model is the Hadley Centre Ocean Carbon Cycle model (HadOCC) from the UK Met Office, used in the Hadley Centre Coupled Model 3 (HadCM3) and FAst Met Office and Universities Simulator (FAMOUS) GCMs. Here, HadOCC is coupled to the 1-D General Ocean Turbulence Model (GOTM) and forced with European Centre for Medium-Range Weather Forecasting meteorology to undertake a sensitivity analysis of its twenty biological parameters. Analyses are performed at three sites in the EuroSITES European Ocean Observatory Network: the Central Irminger Sea (60° N 40° W), the Porcupine Abyssal Plain (49° N 16° W) and the European Station for Time series in the Ocean Canary Islands (29° N 15° W) to assess variability in parameter sensitivities at different locations in the North Atlantic Ocean. Reasonable changes to the values of key parameters are shown to have a large effect on the calculation of the air-sea CO2 flux, primary production, and export of biological detritus to the deep ocean. Changes in the values of key parameters have a greater effect in more productive regions than in less productive areas. We perform the analysis using one-at-a-time perturbations and using a statistical emulator, and compare results. The most sensitive parameters are generic to many NPZD ocean ecosystem models. The air-sea CO2 flux is most influenced by variation in the parameters that control phytoplankton growth, detrital sinking and carbonate production by phytoplankton (the rain ratio). Primary production is most sensitive to the parameters that define the shape of the photosythesis-irradiance curve. Export production is most sensitive to the parameters that control the rate of detrital sinking and the remineralisation of detritus.

  17. In situ evaluation of air-sea CO2 gas transfer velocity in an inner estuary using eddy covariance - with a special focus on the importance of using reliable CO2-fluxes

    NASA Astrophysics Data System (ADS)

    Jørgensen, E. T.; Sørensen, L. L.; Jensen, B.; Sejr, M. K.

    2012-04-01

    The air-sea exchange of CO2 or CO2 flux is driven by the difference in the partial pressure of CO2 in the water and the atmosphere (ΔpCO2), the solubility of CO2 (K0) and the gas transfer velocity (k) (Wanninkhof et al., 2009;Weiss, 1974) . ΔpCO2 and K0 are determined with relatively high precision and it is estimated that the biggest uncertainty when modelling the air-sea flux is the parameterization of k. As an example; the estimated global air-sea flux increases by 70 % when using the parameterization by Wanninkhof and McGillis (1999) instead of Wanninkhof (1992) (Rutgersson et al., 2008). In coastal areas the uncertainty is even higher and only few studies have focused on determining transfer velocity for the coastal waters and even fewer on estuaries (Borges et al., 2004;Rutgersson et al., 2008). The transfer velocity (k600) of CO2 in the inner estuary of Roskilde Fjord, Denmark was investigated using eddy covariance CO2 fluxes (ECM) and directly measured ΔpCO2 during May and June 2010. The data was strictly sorted to heighten the certainty of the results and the outcome was; DS1; using only ECM, and DS2; including the inertial dissipation method (IDM). The inner part of Roskilde Fjord showed to be a very biological active CO2 sink and preliminary results showed that the average k600 was more than 10 times higher than transfer velocities from similar studies of other coastal areas. The much higher transfer velocities were estimated to be caused by the greater fetch and shallower water in Roskilde Fjord, which indicated that turbulence in both air and water influence k600. The wind speed parameterization of k600 using DS1 showed some scatter but when including IDM the r2 of DS2 reached 0.93 with an exponential parameterization, where U10 was based on the Businger-Dyer relationships using friction velocity and atmospheric stability. This indicates that some of the uncertainties coupled with CO2 fluxes calculated by the ECM are removed when including the IDM.

  18. Design and construction of Information Systems of Ocean Satellite Monitoring for Air-sea CO2 Flux (IssCO2)

    NASA Astrophysics Data System (ADS)

    Zhu, Qiankun; Fang, Lei; Bai, Yan; He, Xianqiang; Sun, Xiaoxiao; Chen, Jianyu

    2013-10-01

    Climate change has become one of the hotspots of global attention in recent progress of globalization and industrialization. The mainstream opinion presented by Intergovernmental Panel on Climate Change (IPCC) regards that the global warming was caused mainly by greenhouse gases generated by human activities, such as anthropogenic CO2, which also resulting in the high-frequent happening of abnormal climate events. Satellite remote sensing is an efficient and economic method for CO2 flux observation. In this paper, we describe an Information System of Ocean Satellite Monitoring for Ari-sea CO2 Flux (IssCO2) which developed by the Second Institute of Oceanography, China. The IssCO2can achieve the whole procedure automatically from the satellite remote data receiving to products distribution, including the data acquirement and satellite image process, products generation, etc. The IssCO2 can process various types of in situ data, satellite data and model data, and validate the final satellite-derived CO2 flux products by in situ data; it can provide a real-time browsing and download of remote sensing products on the web based on the Geo-information System (GIS) technologies. The IssCO2 can meet the concurrent queries of different levels of users, and the query results can be visual displayed and analyzed on the client.

  19. Air-sea heat fluxes associated to mesoscale eddies in the Southwestern Atlantic Ocean and their dependence on different regional conditions

    NASA Astrophysics Data System (ADS)

    Leyba, Inés M.; Saraceno, Martín; Solman, Silvina A.

    2016-11-01

    Heat fluxes between the ocean and the atmosphere largely represent the link between the two media. A possible mechanism of interaction is generated by mesoscale ocean eddies. In this work we evaluate if eddies in Southwestern Atlantic (SWA) Ocean may significantly affect flows between the ocean and the atmosphere. Atmospherics conditions associated with eddies were examined using data of sea surface temperature (SST), sensible (SHF) and latent heat flux (LHF) from NCEP-CFSR reanalysis. On average, we found that NCEP-CFSR reanalysis adequately reflects the variability expected from eddies in the SWA, considering the classical eddy-pumping theory: anticyclonic (cyclonic) eddies cause maximum positive (negative) anomalies with maximum mean anomalies of 0.5 °C (-0.5 °C) in SST, 6 W/m2 (-4 W/m2) in SHF and 12 W/m2 (-9 W/m2) in LHF. However, a regional dependence of heat fluxes associated to mesoscale cyclonic eddies was found: in the turbulent Brazil-Malvinas Confluence (BMC) region they are related with positive heat flux anomaly (ocean heat loss), while in the rest of the SWA they behave as expected (ocean heat gain). We argue that eddy-pumping do not cool enough the center of the cyclonic eddies in the BMC region simply because most of them trapped very warm waters when they originate in the subtropics. The article therefore concludes that in the SWA: (1) a robust link exists between the SST anomalies generated by eddies and the local anomalous heat flow between the ocean and the atmosphere; (2) in the BMC region cyclonic eddies are related with positive heat anomalies, contrary to what is expected.

  20. Air-sea fluxes of dimethyl sulfide and carbon dioxide measured by the gradient technique in the subtropical and equatorial Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Omori, Y.; Tanimoto, H.; Inomata, S.; Iwata, T.; Sakuma, H.; Tsunogai, U.; Nakagawa, F.; Ishii, M.; Kosugi, N.; Tsuda, A.; Uematsu, M.

    2012-12-01

    Fluxes of dimethyl sulfide (DMS), acetone and CO2 from the ocean to the atmosphere were measured in the subtropical South Pacific Ocean and the equatorial Pacific Ocean in January-February 2012. Vertical profiles of these gases were obtained above the ocean surface by measurements at 7 heights from 1 to 1400 cm with a profiling buoy aboard R/V Hakuho-Maru during KH-11-10 and KH-12-1 (EqPOS) cruises. The concentrations of DMS, acetone and CO2 in gas samples were simultaneously monitored by a proton transfer reaction-mass spectrometry (PTR-MS) and a non-dispersive infrared detector (NDIR), respectively. In addition, DMS and acetone concentrations in the surface seawater and air were continuously measured with PTR-MS during the cruises. Average of seawater DMS concentrations in the subtropical ocean (2.1±0.5 nM) was slightly lower than that in the equatorial ocean (3.2±1.0 nM). The DMS fluxes significantly varied in the range of 3.6-13.1 and 0.1-18.9 μmol m-2 d-1 in the subtropical and equatorial ocean, respectively. The magnitude of DMS fluxes in both observations was dependent of that of wind speed. The gas transfer velocities of DMS were calculated from the fluxes and the seawater DMS concentrations. The magnitude of the gas transfer velocity mainly depended on that of wind speed. We will discuss the gas transfer velocity including results obtained from the CO2 and acetone observations.

  1. Mechanisms driving the seasonality of air-sea CO2 flux in the ice-free zone of the Southern Ocean and how these might evolve: A 1D vertical biogeochemical model approach.

    NASA Astrophysics Data System (ADS)

    Lancelot, C.; Pasquer, B.; Metzl, N.; Goosse, H.

    2015-12-01

    The biogeochemical SWAMCO-3 model is used to understand mechanisms governing the seasonality of air-sea CO2 exchanges in the ice-free Southern Ocean. The model explicitly details the dynamics of three Phytoplankton Functional Types (PFTs) of importance for C, N, P, Si, Fe cycling and air-sea CO2 exchange in this area. These are the diatoms, the pico-nanophytoplankton and the coccolithophores whose growth regulation by light, temperature and nutrients has been obtained from phenomenological observations available for these PFTs. The performance of the SWAMCO-3 model coupled to a vertical one-dimensional physical model is assessed at the location of the time-series station KERFIX (around 51°S-68°E). The model was able to reproduce a mean seasonal cycle based on years where a maximum of chemical and biological observations are available. Ocean fCO2 in equilibrium with the atmosphere are simulated both in winter associated with surface layer replenishment in DIC due to deep vertical mixing and in late summer as a consequence of the warming effect on the carbonate system. A clear under-saturation is simulated in summer driven by primary production. Model scenarios cancelling biological activity or only coccolithophores allowed, by comparison with the standard simulation, untangling the respective role of physical and biological processes in driving the sign and magnitude of air-sea CO2 exchanges. First, we show that coccolithophores are repressing the ocean C uptake, but only marginally (5%). Second, the model highlights the role of diatoms on the presence of a CO2 sink in summer. Altogether, this results in a weak annual air-sea CO2 flux (-0.9 mol m-2 y-1 or -0.1 Pg C y-1 for the ice-free zone south of 50°S), whose variability seems more related to the thermodynamical processes. We then speculate how global warming might influence the latter mechanisms and alter air-sea CO2 exchanges in this region.

  2. Effect of the accumulation of polycyclic aromatic hydrocarbons in the sea surface microlayer on their coastal air-sea exchanges

    NASA Astrophysics Data System (ADS)

    Guitart, C.; García-Flor, N.; Miquel, J. C.; Fowler, S. W.; Albaigés, J.

    2010-01-01

    Several measurements of polycyclic aromatic hydrocarbons (PAHs) in coastal marine compartments (viz. atmosphere, sea surface microlayer, subsurface seawater, sinking particles and sediments), made nearly simultaneously at two stations in the north-eastern Mediterranean, were used to estimate the transport fluxes of individual and total PAHs through the air-seawater-sediment system. Diffusive air-sea exchange fluxes were estimated using both subsurface water (SSW) and sea surface microlayer (SML) concentrations. The air-SML fluxes ranged from 411 to 12,292 ng m - 2 d - 1 (absorption) and from - 506 to -13,746 ng m - 2 d - 1 (volatilisation) for total PAHs (Σ15). Air-seawater column transport of particle-associated PAHs was estimated from the analysis of particulate atmospheric and sediment interceptor trap materials. Air-sea particle deposition fluxes of total PAHs ranged from 13 to 114 ng m - 2 d - 1 and seawater particle settling fluxes (upper 5 m water column) ranged from 184 to 323 ng m - 2 d - 1 . The results of this study indicate that both the magnitude and the direction of the calculated air-sea diffusive fluxes change when PAH concentrations in the SML are considered. As a result, PAHs accumulation in the SML could produce the so-called "flux capping effect". However, the high variability in the coastal air-sea PAHs flux estimations, mainly due to the parameters uncertainty, requires further experimental approaches, including improvement of parameterisations.

  3. Interannual fluctuations of sea-air CO2 fluxes and carbon transport between 1950 and 2000: Biological and temperature effects deduced from OBCMSs

    NASA Astrophysics Data System (ADS)

    Winguth, A.; Dobbel, M.; Maier-Reimer, E.; Wentzel, P.

    2003-04-01

    Factors controlling the interannual variability of air-sea CO2 in response to the changes in temperature, circulation, and phytoplankton or zooplankton are not well known and controversially discussed. A recent analysis of pCO2 data by Takahasi et al. (2002) show the importance of high-latitude northern and southern oceans as a sink for atmospheric CO2. These areas are source areas for deep an intermediate water masses and hence represents a direct connection between the atmosphere and the deep oceans. We are using two coupled ocean general circulation - marine ecosystem models with different resolution, the NPZD-type HAMOCC4 coupled to the LSG and the C-HOPE, to explore how biology, temperature, and circulation changes can explain some of the agreements and discrepancies between the data and the model in these regions. These exploratory sensitivity experiments are designed to be a first step towards a currently developed inverse ecosystem model to quantify large-scale interannual-to-decadal fluctuations of the marine carbon cycle and to provide more accurate predictions of the climate system.

  4. Annual sea ice. An air-sea gas exchange moderator

    SciTech Connect

    Gosink, T.A.; Kelley, J.J.

    1982-01-01

    Arctic annual sea ice, particularly when it is relatively warm (> -15/sup 0/C) permits significant gas exchange between the sea and air throughout the entire year. Sea ice, particularly annual sea ice, differs from freshwater ice with respect to its permeability to gases. The presence of brine allows for significant air-sea-ice exchange of CO/sub 2/ throughout the winter, which may significantly affect the global carbon dioxide balance. Other trace gases are also noted to be enriched in sea ice, but less is known about their importance to air-sea-interactions at this time. Both physical and biological factors cause and modify evolution of gases from the surface of sea ice. Quantitative and qualitative descriptions of the nature and physical behavior of sea ice with respect to brine and gases are discussed.

  5. A study of oceanic surface heat fluxes in the Greenland, Norwegian, and Barents Seas

    NASA Technical Reports Server (NTRS)

    Hakkinen, Sirpa; Cavalieri, Donald J.

    1989-01-01

    This study examines oceanic surface heat fluxes in the Norwegian, Greenland, and Barents seas using the gridded Navy Fleet Numerical Oceanography Central surface analysis and the First GARP Global Experiment (FGGE) IIc cloudiness data bases. Monthly and annual means of net and turbulent heat fluxes are computed for the FGGE year 1979. The FGGE IIb data base consisting of individual observations provides particularly good data coverage in this region for a comparison with the gridded Navy winds and air temperatures. The standard errors of estimate between the Navy and FGGE IIb winds and air temperatures are 3.6 m/s and 2.5 C, respectively. The computations for the latent and sensible heat fluxes are based on bulk formulas with the same constant heat exchange coefficient of 0.0015. The results show extremely strong wintertime heat fluxes in the northern Greenland Sea and especially in the Barents Sea in contrast to previous studies.

  6. Sea Spray Effects on Surface Heat and Moisture Fluxes

    DTIC Science & Technology

    2016-06-07

    DeCosmo, J., 1991: Air-sea exchange of momentum, heat and water vapor over whitecap sea states. Ph.D. dissertation, University of Washington, Seattle...212 pp. DeCosmo, J., K. B. Katsaros, S. D. Smith, R. J. Anderson, W. A. Oost, K. Bumke and H. Chadwick, 1996: Air-sea exchange of water vapor and

  7. Measurements of the Air-Sea Interface from an Instrumented Small Buoy

    DTIC Science & Technology

    2011-09-01

    xiv THIS PAGE INTENTIONALLY LEFT BLANK xv LIST OF ACRONYMS AND ABBREVIATIONS ASIT Air Sea Interaction Tower ASIS Air-sea Interaction Spar...or the Air-sea Interaction Tower (ASIT, Edson et al. 2007). Research buoys are an alternative to the stabilized platforms. One such buoy is the...instrument suite was deployed on the R/V Sproul in both 2009 and 2010. The basic instruments included one or two flux measurement towers , a

  8. The SeaFlux Turbulent Flux Dataset Version 1.0 Documentation

    NASA Technical Reports Server (NTRS)

    Clayson, Carol Anne; Roberts, J. Brent; Bogdanoff, Alec S.

    2012-01-01

    Under the auspices of the World Climate Research Programme (WCRP) Global Energy and Water cycle EXperiment (GEWEX) Data and Assessment Panel (GDAP), the SeaFlux Project was created to investigate producing a high-resolution satellite-based dataset of surface turbulent fluxes over the global oceans. The most current release of the SeaFlux product is Version 1.0; this represents the initial release of turbulent surface heat fluxes, associated near-surface variables including a diurnally varying sea surface temperature.

  9. Air-sea interactions during strong winter extratropical storms

    USGS Publications Warehouse

    Nelson, Jill; He, Ruoying; Warner, John C.; Bane, John

    2014-01-01

    A high-resolution, regional coupled atmosphere–ocean model is used to investigate strong air–sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air–sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air–sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere–ocean modeling framework.

  10. Combined Satellite - and ULS-Derived Sea-Ice Flux in the Weddell Sea

    NASA Technical Reports Server (NTRS)

    Drinkwater, M.; Liu, X.; Harms, S.

    2000-01-01

    Several years of daily microwave satellite ice-drift are combined with moored Upward Looking Sonar (ULS) ice-drafts into an ice volume flux record at points along a flux gate across the Weddell Sea, Antarctica.

  11. Atmospheric deposition flux estimates for chlorpyrifos and trifluralin in the chukchi sea

    Technology Transfer Automated Retrieval System (TEKTRAN)

    During the 1993 U.S.-Russian BERPAC expedition, residues of agricultural pesticides were detected in seawater, ice, surface microlayer, fog, and air of the Bering and Chukchi Seas. Gas exchange, wet deposition, and dry particle deposition fluxes of trifluralin and chlorpyrifos were estimated using m...

  12. Air-sea transfer of gas phase controlled compounds

    NASA Astrophysics Data System (ADS)

    Yang, M.; Bell, T. G.; Blomquist, B. W.; Fairall, C. W.; Brooks, I. M.; Nightingale, P. D.

    2016-05-01

    Gases in the atmosphere/ocean have solubility that spans several orders of magnitude. Resistance in the molecular sublayer on the waterside limits the air-sea exchange of sparingly soluble gases such as SF6 and CO2. In contrast, both aerodynamic and molecular diffusive resistances on the airside limit the exchange of highly soluble gases (as well as heat). Here we present direct measurements of air-sea methanol and acetone transfer from two open cruises: the Atlantic Meridional Transect in 2012 and the High Wind Gas Exchange Study in 2013. The transfer of the highly soluble methanol is essentially completely airside controlled, while the less soluble acetone is subject to both airside and waterside resistances. Both compounds were measured concurrently using a proton-transfer-reaction mass spectrometer, with their fluxes quantified by the eddy covariance method. Up to a wind speed of 15 m s-1, observed air-sea transfer velocities of these two gases are largely consistent with the expected near linear wind speed dependence. Measured acetone transfer velocity is ∼30% lower than that of methanol, which is primarily due to the lower solubility of acetone. From this difference we estimate the “zero bubble” waterside transfer velocity, which agrees fairly well with interfacial gas transfer velocities predicted by the COARE model. At wind speeds above 15 m s-1, the transfer velocities of both compounds are lower than expected in the mean. Air-sea transfer of sensible heat (also airside controlled) also appears to be reduced at wind speeds over 20 m s-1. During these conditions, large waves and abundant whitecaps generate large amounts of sea spray, which is predicted to alter heat transfer and could also affect the air-sea exchange of soluble trace gases. We make an order of magnitude estimate for the impacts of sea spray on air-sea methanol transfer.

  13. Air-Sea Interactions in CLIMODE: In-Situ Observations

    NASA Astrophysics Data System (ADS)

    Bigorre, S.; Weller, R.

    2006-12-01

    The subtropical mode water of the North Atlantic or Eighteen Degree Water (EDW) is an important component of the oceanic circulation. Its formation and evolution are linked to fundamental aspects of the oceanic climate. A central formation process involves the subduction of surface water through air-sea interactions. Conditions for this are ideal in the Gulf Stream region when warm water interacts with cold air above, sinks and is trapped in the late winter, thereby ventilating the interior. The study program CLIvar MOde Water Dynamic Experiment (CLIMODE), sponsored by NSF, is designed to quantify and understand which processes lead to the formation and dissipation of EDW. A key component to this goal is the knowledge of buoyancy fluxes in the region of EDW formation. The Upper Ocean Processes (UOP) group deployed a 3-m discus buoy anchored in the Gulf Stream (64W, 38N) in November 2005. Oceanographic instruments collect data along the mooring line while meteorological and surface sensors are placed on the buoy and collect data every minute. Since the deployment, hourly averages of the meteorological data were transmitted through the Argos satellite system. These data were plugged in the TOGA-COARE bulk algorithm to estimate air-sea fluxes. These preliminary results are presented, while the full dataset will be analyzed after recovery of the buoy in November 2006. Heat fluxes estimates indicate high heat loss events. In December 2005, regular losses larger than 1000W/m2 occurred. These heat loss events are associated with cold air outbreaks. When the air-sea temperature gradient increases, winds also tend to increase indicating a destabilization of the boundary layer and production of turbulence, enhancing further the heat transfer. As the air-sea temperature gradient decreases in the late winter, heat loss also decreases. The SST signal is seen to modulate the heat fluxes on lower frequencies than air temperature changes. This kind of signal tends therefore to be

  14. Wintertime boundary-layer structure and air sea interaction over the Japan/East Sea

    NASA Astrophysics Data System (ADS)

    Khelif, Djamal; Friehe, Carl A.; Jonsson, Haflidi; Wang, Qing; Rados, Konstantinos

    2005-06-01

    The wintertime meteorology over the Japan/East Sea (JES) is characterized by episodic strong northwesterly winds known as "cold-air outbreaks" resulting from the incursion of dry and cold air masses from the Eurasian continent. These were found by previous studies (mostly based on indirect methods) to greatly enhance the air-sea interaction and, in particular an area about 150 km in diameter off Vladivostok was identified as the Flux Center. Aircraft in situ measurements of turbulent fluxes and mean meteorological variables were made during the winter 2000. The existence and location of the Flux Center were confirmed although the turbulent sensible and latent-heat fluxes were not as high as previously found due to the air temperature being several degrees warmer. However, the stress was found to be significantly larger as a result of higher wind speeds. The internal boundary layer was found to grow linearly with the square root of offshore fetch, with a growth rate of 2.49m for an intense cold-air outbreak and 2.06m for a moderate one. A persistent initial decrease in the inversion height was observed at 41.86∘N,132.6∘E and may be attributable to the fanning out of the jet flow out of the Vladivostok gap as it expands onto the open ocean. The radiometric skin sea-surface temperature in the Flux Center exhibited large variability in the 0-4 °C range and was positively correlated with the total turbulent (latent+sensible) heat loss. Meteorological variables and surface fluxes results from Naval Research Laboratory Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) model compared reasonably, while the predictions of the internal boundary layer height were markedly lower than the observations.

  15. Seasonal variability of the Caspian Sea three-dimensional circulation, sea level and air-sea interaction

    NASA Astrophysics Data System (ADS)

    Ibrayev, R. A.; Özsoy, E.; Schrum, C.; Sur, H. I.

    2010-03-01

    A three-dimensional primitive equation model including sea ice thermodynamics and air-sea interaction is used to study seasonal circulation and water mass variability in the Caspian Sea under the influence of realistic mass, momentum and heat fluxes. River discharges, precipitation, radiation and wind stress are seasonally specified in the model, based on available data sets. The evaporation rate, sensible and latent heat fluxes at the sea surface are computed interactively through an atmospheric boundary layer sub-model, using the ECMWF-ERA15 re-analysis atmospheric data and model generated sea surface temperature. The model successfully simulates sea-level changes and baroclinic circulation/mixing features with forcing specified for a selected year. The results suggest that the seasonal cycle of wind stress is crucial in producing basin circulation. Seasonal cycle of sea surface currents presents three types: cyclonic gyres in December-January; Eckman south-, south-westward drift in February-July embedded by western and eastern southward coastal currents and transition type in August-November. Western and eastern northward sub-surface coastal currents being a result of coastal local dynamics at the same time play an important role in meridional redistribution of water masses. An important part of the work is the simulation of sea surface topography, yielding verifiable results in terms of sea level. The model successfully reproduces sea level variability for four coastal points, where the observed data are available. Analyses of heat and water budgets confirm climatologic estimates of heat and moisture fluxes at the sea surface. Experiments performed with variations in external forcing suggest a sensitive response of the circulation and the water budget to atmospheric and river forcing.

  16. Seasonal variability of the Caspian Sea three-dimensional circulation, sea level and air-sea interaction

    NASA Astrophysics Data System (ADS)

    Ibrayev, R. A.; Özsoy, E.; Schrum, C.; Sur, H. İ.

    2009-09-01

    A three-dimensional primitive equation model including sea ice thermodynamics and air-sea interaction is used to study seasonal circulation and water mass variability in the Caspian Sea under the influence of realistic mass, momentum and heat fluxes. River discharges, precipitation, radiation and wind stress are seasonally specified in the model, based on available data sets. The evaporation rate, sensible and latent heat fluxes at the sea surface are computed interactively through an atmospheric boundary layer sub-model, using the ECMWF-ERA15 re-analysis atmospheric data and model generated sea surface temperature. The model successfully simulates sea-level changes and baroclinic circulation/mixing features with forcing specified for a selected year. The results suggest that the seasonal cycle of wind stress is crucial in producing basin circulation. Seasonal cycle of sea surface currents presents three types: cyclonic gyres in December-January; Eckman south-, south-westward drift in February-July embedded by western and eastern southward coastal currents and transition type in August-November. Western and eastern northward sub-surface coastal currents being a result of coastal local dynamics at the same time play an important role in meridional redistribution of water masses. An important part of the work is the simulation of sea surface topography, yielding verifiable results in terms of sea level. Model successfully reproduces sea level variability for four coastal points, where the observed data are available. Analyses of heat and water budgets confirm climatologic estimates of heat and moisture fluxes at the sea surface. Experiments performed with variations in external forcing suggest a sensitive response of the circulation and the water budget to atmospheric and river forcing.

  17. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    USGS Publications Warehouse

    Hinckley, D.A.; Bidleman, T.F.; Rice, C.P.

    1991-01-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  18. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    SciTech Connect

    Hinckley, D.A.; Bidleman, T.F. ); Rice, C.P. )

    1991-04-15

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average {alpha}-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg/m{sup 3} and 2.4 ng/l, respectively, and average {gamma}-HCH concentrations were 68 pg/m{sup 3} in the atmosphere and 0.6 ng/l in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations ({alpha}-HCH, average 79% saturation; {gamma}-HCH, average 28% saturation). The flux for {alpha}-HCH ranged from {minus}47 ng/m{sup 2} day (sea to air) to 122 ng/m{sup 2} day (air to sea) and averaged 25 ng/m{sup 2} day air to sea. All fluxes of {gamma}-HCH were from air to sea, ranged from 17 to 54 ng/m{sup 2} day, and averaged 31 ng/m{sup 2} day.

  19. Phytoplankton carbon fixation gene (RuBisCO) transcripts and air-sea CO2 flux in the Mississippi River plume

    SciTech Connect

    John, David E.; Wang, Zhaohui A.; Liu, Xuewu; Byrne, Robert H.; Corredor, Jorge E.; López, José M.; Cabrera, Alvaro; Bronk, Deborah A.; Tabita, F. Robert; Paul, John H.

    2007-08-30

    River plumes deliver large quantities of nutrients to oligotrophic oceans, often resulting in significant CO2 drawdown. To determine the relationship between expression of the major gene in carbon fixation (large subunit of ribulose-1,5-bisphosphate carboxylase/oxygenase, RuBisCO) and CO2 dynamics, we evaluated rbcL mRNA abundance using novel quantitative PCR assays, phytoplankton cell analyses, photophysiological parameters, and pCO2 in and around the Mississippi River plume (MRP) in the Gulf of Mexico. Lower salinity (30–32) stations were dominated by rbcL mRNA concentrations from heterokonts, such as diatoms and pelagophytes, which were at least an order of magnitude greater than haptophytes, alpha-Synechococcus or high-light Prochlorococcus. However, rbcL transcript abundances were similar among these groups at oligotrophic stations (salinity 34–36). Diatom cell counts and heterokont rbcL RNA showed a strong negative correlation to seawater pCO2. While Prochlorococcus cells did not exhibit a large difference between low and high pCO2 water, Prochlorococcus rbcL RNA concentrations had a strong positive correlation to pCO2, suggesting a very low level of RuBisCO RNA transcription among Prochlorococcus in the plume waters, possibly due to their relatively poor carbon concentrating mechanisms (CCMs). These results provide molecular evidence that diatom/pelagophyte productivity is largely responsible for the large CO2 drawdown occurring in the MRP, based on the co-occurrence of elevated RuBisCO gene transcript concentrations from this group and reduced seawater pCO2 levels. This may partly be due to efficient CCMs that enable heterokont eukaryotes such as diatoms to continue fixing CO2 in the face of strong CO2 drawdown. Finally, our work represents the first attempt to relate in situ microbial gene expression to contemporaneous CO2 flux

  20. Air-sea interactions in sea surface temperature frontal region

    NASA Astrophysics Data System (ADS)

    Pianezze, Joris; Redelsperger, Jean-Luc; Ardhuin, Fabrice; Reynaud, Thierry; Marié, Louis; Bouin, Marie-Noelle; Garnier, Valerie

    2015-04-01

    Representation of air-sea exchanges in coastal, regional and global models represent a challenge firstly due to the small scale of acting turbulent processes comparatively to the resolved scales of these models. Beyond this subgrid parameterization issue, a comprehensive understanding of air-sea interactions at the turbulent process scales is still lacking. Many successful efforts are dedicated to measure the energy and mass exchanges between atmosphere and ocean, including the effect of surface waves. In comparison less efforts are brought to understand the interactions between the atmospheric boundary layer and the oceanic mixing layer. In this regard, we are developing research mainly based on ideal and realistic numerical simulations which resolve very small scales (horizontal resolutions from 1 to 100 meters) in using grid nesting technics and coupled ocean-wave-atmosphere models. As a first step, the impact of marked gradients in sea surface temperatures (SST) on air-sea exchanges has been explored through realistic numerical simulations at 100m horizontal resolution. Results from simulations of a case observed during the FROMVAR experiment will be shown. The talk will mainly focus on the marked impact of SST front on the atmospheric boundary layer (stability and winds), the air-sea exchanges and surface parameters (rugosity, drag coefficient) Results will be also shown on the strong impact on the simulated atmosphere of small scale variability of SST field.

  1. Synoptic Estimates of Air Sea Fluxes.

    DTIC Science & Technology

    1980-10-01

    98 X COMPONENT Y COMPONENT LLC’ LjJ 0 L) (3z--z _3, !Cr Z C Lrr, LLJ LAJ 0 ’ 1 u 6 00 11’ 0 HvERRGING PERIOD IN DAYS AVERRO -INC...n~2 Llii: u Ajc, I L,. t ’," J V C) I aI * CD LL-i u-i C)C3 0 1 1 0 10 0 100 0 1 1 0 10 0 100 0 AVERAGING PERIOD IN D’VTS AVERRO INf, PERIOD IN Dq-S

  2. Estimating ocean-air heat fluxes during cold air outbreaks by satellite

    NASA Technical Reports Server (NTRS)

    Chou, S. H.; Atlas, D.

    1981-01-01

    Nomograms of mean column heating due to surface sensible and latent heat fluxes were developed. Mean sensible heating of the cloud free region is related to the cloud free path (CFP, the distance from the shore to the first cloud formation) and the difference between land air and sea surface temperatures, theta sub 1 and theta sub 0, respectively. Mean latent heating is related to the CFP and the difference between land air and sea surface humidities q sub 1 and q sub 0 respectively. Results are also applicable to any path within the cloud free region. Corresponding heat fluxes may be obtained by multiplying the mean heating by the mean wind speed in the boundary layer. The sensible heating estimated by the present method is found to be in good agreement with that computed from the bulk transfer formula. The sensitivity of the solutions to the variations in the initial coastal soundings and large scale subsidence is also investigated. The results are not sensitive to divergence but are affected by the initial lapse rate of potential temperature; the greater the stability, the smaller the heating, other things being equal. Unless one knows the lapse rate at the shore, this requires another independent measurement. For this purpose the downwind slope of the square of the boundary layer height is used, the mean value of which is also directly proportional to the mean sensible heating. The height of the boundary layer should be measurable by future spaceborn lidar systems.

  3. The effects of sea surface temperature gradients on surface turbulent fluxes

    NASA Astrophysics Data System (ADS)

    Steffen, John

    A positive correlation between sea surface temperature (SST) and wind stress perturbation near strong SST gradients (DeltaSST) has been observed in different parts of the world ocean, such as the Gulf Stream in the North Atlantic and the Kuroshio Extension east of Japan. These changes in winds and SSTs can modify near-surface stability, surface stress, and latent and sensible heat fluxes. In general, these small scale processes are poorly modeled in Numerical Weather Prediction (NWP) and climate models. Failure to account for these air--sea interactions produces inaccurate values of turbulent fluxes, and therefore a misrepresentation of the energy, moisture, and momentum budgets. Our goal is to determine the change in these surface turbulent fluxes due to overlooking the correlated variability in winds, SSTs, and related variables. To model these air--sea interactions, a flux model was forced with and without SST--induced changes to the surface wind fields. The SST modification to the wind fields is based on a baroclinic argument as implemented by the University of Washington Planetary Boundary-Layer (UWPBL) model. Other input parameters include 2-m air temperature, 2-m dew point temperature, surface pressure (all from ERA--interim), and Reynolds Daily Optimum Interpolation Sea Surface Temperature (OISST). Flux model runs are performed every 6 hours starting in December 2002 and ending in November 2003. From these model outputs, seasonal, monthly, and daily means of the difference between DeltaSST and no DeltaSST effects on sensible heat flux (SHF), latent heat flux (LHF), and surface stress are calculated. Since the greatest impacts occur during the winter season, six additional December-January-February (DJF) seasons were analyzed for 1987--1990 and 1999--2002. The greatest differences in surface turbulent fluxes are concentrated near strong SST fronts associated with the Gulf Stream and Kuroshio Extension. On average, 2002---2003 DJF seasonal differences in SHF

  4. Turbulent aerosol fluxes over the Arctic Ocean: 2. Wind-driven sources from the sea

    NASA Astrophysics Data System (ADS)

    Nilsson, E. D.; Rannik, Ü.; Swietlicki, E.; Leck, C.; Aalto, P. P.; Zhou, J.; Norman, M.

    2001-12-01

    An eddy-covariance flux system was successfully applied over open sea, leads and ice floes during the Arctic Ocean Expedition in July-August 1996. Wind-driven upward aerosol number fluxes were observed over open sea and leads in the pack ice. These particles must originate from droplets ejected into the air at the bursting of small air bubbles at the water surface. The source flux F (in 106 m-2 s-1) had a strong dependency on wind speed, log>(F>)=0.20U¯-1.71 and 0.11U¯-1.93, over the open sea and leads, respectively (where U¯ is the local wind speed at about 10 m height). Over the open sea the wind-driven aerosol source flux consisted of a film drop mode centered at ˜100 nm diameter and a jet drop mode centered at ˜1 μm diameter. Over the leads in the pack ice, a jet drop mode at ˜2 μm diameter dominated. The jet drop mode consisted of sea-salt, but oxalate indicated an organic contribution, and bacterias and other biogenic particles were identified by single particle analysis. Particles with diameters less than -100 nm appear to have contributed to the flux, but their chemical composition is unknown. Whitecaps were probably the bubble source at open sea and on the leads at high wind speed, but a different bubble source is needed in the leads owing to their small fetch. Melting of ice in the leads is probably the best candidate. The flux over the open sea was of such a magnitude that it could give a significant contribution to the condensation nuclei (CCN) population. Although the flux from the leads were roughly an order of magnitude smaller and the leads cover only a small fraction of the pack ice, the local source may till be important for the CCN population in Arctic fogs. The primary marine aerosol source will increase both with increased wind speed and with decreased ice fraction and extent. The local CCN production may therefore increase and influence cloud or fog albedo and lifetime in response to greenhouse warming in the Arctic Ocean region.

  5. Recent changes in sea ice area flux through the Beaufort Sea during the summer

    NASA Astrophysics Data System (ADS)

    Howell, Stephen E. L.; Brady, Michael; Derksen, Chris; Kelly, Richard E. J.

    2016-04-01

    Over the annual cycle, sea ice is sequestered from the Canadian Basin and transported through the Beaufort Sea toward the Chukchi Sea. In recent years, the Beaufort Sea has experienced considerable ice loss during the summer, which may be indicative of recent changes to this process. In order to investigate this, we quantify the sea ice area flux using RADARSAT from 1997 to 2014 at three gates in Beaufort Sea: the Canadian Basin (entrance), mid-Beaufort (midpoint), and Chukchi (exit). There was a mean annual flux of 42 ± 56 × 103 km2 at the Canadian Basin gate, 94 ± 92 × 103 km2 at the mid-Beaufort gate and -83 ± 68 × 103 km2 at the Chukchi gate (positive and negative flux signs correspond to ice inflow and outflow, respectively). The majority of ice transport in Beaufort Sea was found to occur from October to May providing replenishment for ice lost during the summer months. The cross-strait gradient in sea level pressure explains ˜40% of the variance in the ice area flux at the gates. Remarkably, the mean July-October net sea ice area flux at the Chukchi gate decreased by ˜80% from 2008 to 2014 relative to 1997-2007 and became virtually ice-free every year since 2008. This reduction was associated with younger (thinner) ice that was unable to survive the summer melt season when either being sequestered from the Canadian Basin and transported through Beaufort Sea during the melt season (2008-2011) or remaining immobile and present in the vicinity of the Chukchi gate during the melt season (2012-2014).

  6. Ross sea ice motion, area flux, and deformation

    NASA Technical Reports Server (NTRS)

    kwok, Ron

    2005-01-01

    The sea ice motion, area export, and deformation of the Ross Sea ice cover are examined with satellite passive microwave and RADARSAT observations. The record of high-resolution synthetic aperture radar (SAR) data, from 1998 and 2000, allows the estimation of the variability of ice deformation at the small scale (10 km) and to assess the quality of the longer record of passive microwave ice motion. Daily and subdaily deformation fields and RADARSAT imagery highlight the variability of motion and deformation in the Ross Sea. With the passive microwave ice motion, the area export at a flux gate positioned between Cape Adare and Land Bay is estimated. Between 1992 and 2003, a positive trend can be seen in the winter (March-November) ice area flux that has a mean of 990 x 103 km2 and ranges from a low of 600 x 103 km2 in 1992 to a peak of 1600 x 103 km2 in 2001. In the mean, the southern Ross Sea produces almost twice its own area of sea ice during the winter. Cross-gate sea level pressure (SLP) gradients explain 60% of the variance in the ice area flux. A positive trend in this gradient, from reanalysis products, suggests a 'spinup' of the Ross Sea Gyre over the past 12 yr. In both the NCEP-NCAR and ERA-40 surface pressure fields, longer-term trends in this gradient and mean SLP between 1979 and 2002 are explored along with positive anomalies in the monthly cross-gate SLP gradient associated with the positive phase of the Southern Hemisphere annular mode and the extrapolar Southern Oscillation.

  7. Development of Unmanned Airborne System (UAS) instrumentation for air-sea-ice interaction research

    NASA Astrophysics Data System (ADS)

    Reineman, B. D.; Lenain, L.; Melville, W. K.

    2011-12-01

    We have developed Unmanned Airborne System (UAS) instrumentation packages to directly measure air-sea momentum transfer, as well as latent, sensible, and radiative heat fluxes, topography, and surface wave kinematics. Two UAS (BAE Manta C1s) flying in vertical formation over the ocean will allow the direct measurement of air-sea fluxes within the marine atmospheric boundary layer, and, with onboard high-resolution video and laser altimetry, simultaneous observation of sea surface kinematics and sea-ice topography. The low altitude required for accurate air-sea or air-ice flux measurements is below the typical safety limit of manned research aircraft; however, with advancements in laser altimeters, small-aircraft flight control, and real-time Differential GPS, it now is within the capability of the UAS platform. Fast response turbulence, hygrometer, and temperature probes in the lower UAS permit surface layer flux measurements, and short and long wave radiometers in the upper UAS allow the determination of net radiation, surface temperature, and albedo. Engineering test flights of the two UAS over land were performed in January 2011 at Camp Roberts, CA. The tests demonstrated the capability of the systems to measure vertical profiles of georeferenced wind, temperature, and moisture content, as well as momentum flux and sensible, latent, and radiative heat fluxes. UAS-derived fluxes from low-altitude (20 -- 30 m) flights are in agreement with fluxes measured by a nearby tower-mounted sonic anemometer-based eddy covariance system. We present a description of the instrumentation, a summary of results from flight tests, and discuss potential applications of these instrumented platforms for air-sea-ice interaction studies.

  8. Thermal Infrared Signatures and Heat Fluxes of Sea Foam

    DTIC Science & Technology

    2015-01-13

    supposition that enhanced evaporative -cooling is responsible for this phenomenon. A control volume technique was successfully used to estimate the...warmer bulk water and foam below. A parametric bulk flux method for the heat flux due to foam and analysis of the remote sensing signature are key...quantities (e.g. wind speed, air and water temperature, humidity) and determine the effect on remotely sensed thermal features. APPROACH To address

  9. Fecal Pellet Flux in the Mesopelagic Sargasso Sea

    NASA Astrophysics Data System (ADS)

    Koweek, D.; Shatova, O.; Conte, M. H.; Weber, J. C.

    2010-12-01

    The Oceanic Flux Program (OFP), located 75km SE of Bermuda, is the longest running sediment trap time-series of its kind, continually collecting deep sea particle flux since 1978. Recent application of digital microphotography to the size-fractionated OFP sediment trap material has generated a wealth of new quantitative visual information on particle flux composition, its changes with depth, and its temporal variability. We examined the fecal pellet flux at 1500m depth using image analysis of digital archives, in conjunction with data on the overlying surface ocean from the Bermuda Testbed Mooring (BTM) and the Bermuda Atlantic Time Series (BATS) programs, to investigate the role of mesoscale physical forcing on mesopelagic particle flux variability. During 2007, a productive cyclonic eddy, a mode water eddy and an anticyclonic eddy passed over the OFP site. Fecal pellet flux was enhanced during passage of both the cyclonic and mode water eddies. Total mass flux (TMF) was also enhanced during the productive cyclonic eddy, but was not influenced by the passage of the mode water eddy. No increase in fecal pellet flux or TMF was apparent during passage of the anticyclonic eddy despite indications of increased zooplankton abundance from ADCP backscatter intensity. Fecal pellet size frequency distributions indicate the presence of two, and sometimes three, distinct size classes. No seasonal trend in mean size of fecal pellets was observed for any size class, implying that the size distribution of the zooplankton populations producing the pellets is relatively constant throughout the year. We also investigated fecal pellet flux changes with depth at 500, 1500 and 3200m. Fecal pellet flux, and the fecal pellet contribution to TMF, were greatest at 500m and decreased with depth. The use of quantitative image analysis holds great potential as a powerful analytical tool in studies of marine particulate flux.

  10. Surface Flux Modeling for Air Quality Applications

    EPA Science Inventory

    For many gasses and aerosols, dry deposition is an important sink of atmospheric mass. Dry deposition fluxes are also important sources of pollutants to terrestrial and aquatic ecosystems. The surface fluxes of some gases, such as ammonia, mercury, and certain volatile organic c...

  11. Persistent organochlorine pesticides and polychlorinated biphenyls in air of the North Sea region and air-sea exchange.

    PubMed

    Mai, Carolin; Theobald, Norbert; Hühnerfuss, Heinrich; Lammel, Gerhard

    2016-12-01

    Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were studied to determine occurrence, levels and spatial distribution in the marine atmosphere and surface seawater during cruises in the German Bight and the wider North Sea in spring and summer 2009-2010. In general, the concentrations found in air are similar to, or below, the levels at coastal or near-coastal sites in Europe. Hexachlorobenzene and α-hexachlorocyclohexane (α-HCH) were close to phase equilibrium, whereas net atmospheric deposition was observed for γ-HCH. The results suggest that declining trends of HCH in seawater have been continuing for γ-HCH but have somewhat levelled off for α-HCH. Dieldrin displayed a close to phase equilibrium in nearly all the sampling sites, except in the central southwestern part of the North Sea. Here atmospheric deposition dominates the air-sea exchange. This region, close to the English coast, showed remarkably increased surface seawater concentrations. This observation depended neither on riverine input nor on the elevated abundances of dieldrin in the air masses of central England. A net depositional flux of p,p'-DDE into the North Sea was indicated by both its abundance in the marine atmosphere and the changes in metabolite pattern observed in the surface water from the coast towards the open sea. The long-term trends show that the atmospheric concentrations of DDT and its metabolites are not declining. Riverine input is a major source of PCBs in the German Bight and the wider North Sea. Atmospheric deposition of the lower molecular weight PCBs (PCB28 and PCB52) was indicated as a major source for surface seawater pollution.

  12. Wintertime air-sea interaction processes across the Gulf Stream

    NASA Astrophysics Data System (ADS)

    Bane, John M.; Osgood, Kenric E.

    1989-08-01

    Aircraft, buoy and satellite measurements have been used to study the wintertime air-sea interaction processes across the Gulf Stream during January 25-30, 1986. The turbulent flux regime in the marine atmospheric boundary layer exhibited considerable spatial and temporal variability during this 6-day period, which was related to both the evolution of the synoptic scale atmospheric conditions and the sea surface temperature (SST) field. During the pre-storm conditions prior to January 25, the spatial structure of the SST field played an important role in generating a shallow atmospheric frontal zone along the Gulf Stream front by causing differential heating of the marine atmospheric boundary layer over the stream versus over the cooler shelf waters. As this front moved shoreward on January 25, the warm, moist, maritime air flowing northwestward behind the front induced moderate ocean-to-atmosphere heat fluxes (˜300 W m-2 total heat flux measured over the core of the Gulf Stream). The subsequent outbreak of eastward flowing cold, dry, continental air over the ocean on January 27 and 28 generated high total heat fluxes (˜1060 W m-2 over the core of the Stream), as did a second, somewhat weaker outbreak which followed on January 30 (˜680 W2 over the core of the Stream). During each of these outbreaks, with air flowing from land out over the continental shelf, Gulf Stream and Sargasso Sea waters, the SST field again affected the spatial structure of the flux fields. The near-surface fluxes of both sensible and latent heat were found to be relatively low over the cool continental shelf waters, while higher fluxes were seen over the Gulf Stream and Sargasso Sea. Similar spatial structure was seen in the near-surface momentum flux values, but relative changes were typically smaller from one location to another on a particular day. The most noticeable responses of the Gulf Stream to these surface fluxes were the deepening of its mixed layer and a loss of upper layer

  13. Effect of sea sprays on air-sea momentum exchange at severe wind conditions

    NASA Astrophysics Data System (ADS)

    Troitskaya, Yu.; Ezhova, E.; Semenova, A.; Soustova, I.

    2012-04-01

    Wind-wave interaction at extreme wind speed is of special interest now in connection with the problem of explanation of the sea surface drag saturation at the wind speed exceeding 30 m/s. The idea on saturation (and even reduction) of the coefficient of aerodynamic resistance of the sea surface at hurricane wind speed was first suggested in [1] on the basis of theoretical analysis of sensitivity of maximum wind speed in a hurricane to the ratio of the enthalpy and momentum exchange coefficients. Both field [2-4] and laboratory [5] experiments confirmed that at hurricane wind speed the sea surface drag coefficient is significantly reduced in comparison with the parameterization obtained at moderate to strong wind conditions. Two groups of possible theoretical mechanisms for explanation of the effect of the sea surface drag reduction can be specified. In the first group of models developed in [6,7], the sea surface drag reduction is explained by peculiarities of the air flow over breaking waves. Another approach more appropriate for the conditions of developed sea exploits the effect of sea drops and sprays on the wind-wave momentum exchange. Papers[8,9] focused on the effect of the sea drops on stratification of the air-sea boundary layer similar to the model of turbulent boundary layer with the suspended particles [10], while papers [11-13] estimated the momentum exchange of sea drops and air-flow. A mandatory element of the spray induced momentum flux is a parameterization of the momentum exchange between droplets and air flow, which determines the "source function" in the momentum balance equation. In this paper a model describing the motion of a spume droplet, the wind tear away from the crest of a steep surface wave, and then falling into the water. We consider two models for the injection of droplets into the air flow. The first one assumes that the drop starts from the surface at the orbital velocity of the wave. In the second model we consider droplets from

  14. Impacts of air-sea exchange coefficients on snowfall events over the Korean Peninsula

    NASA Astrophysics Data System (ADS)

    Kang, Jung-Yoon; Kwon, Young Cheol

    2016-08-01

    Snowfall over the Korean Peninsula is mainly associated with air mass transformation by the fluxes across the air-sea interface during cold-air outbreaks over the warm Yellow Sea. The heat and momentum exchange coefficients in the surface flux parameterization are key parameters of flux calculations across the air-sea interface. This study investigates the effects of the air-sea exchange coefficients on the simulations of snowfall events over the Korean Peninsula using the Weather Research and Forecasting (WRF) model. Two snowfall cases are selected for this study. One is a heavy snowfall event that took place on January 4, 2010, and the other is a light snowfall event that occurred on December 23-24, 2011. Several sensitivity tests are carried out with increased and decreased heat and momentum exchange coefficients. The domain-averaged precipitation is increased (decreased) with increased (decreased) heat exchange coefficient because the increased (decreased) surface heat flux leads to more (less) moist conditions in the low level of the atmosphere. On the other hand, the domain-averaged precipitation is decreased (increased) with increased (decreased) momentum exchange coefficient because the increased (decreased) momentum coefficient causes reduction (increase) of wind speed and heat flux. The variation of precipitation in the heat exchange coefficient experiments is much larger than that in the momentum exchange coefficient experiments because the change of heat flux has a more direct impact on moisture flux and snowfall amount, while the change of momentum flux has a rather indirect impact via wind speed changes. The low-pressure system is intensified and moves toward North when the heat exchange coefficient is increased because warming and moistening of the lower atmosphere contributes to destabilize the air mass, resulting in the change of precipitation pattern over the Korean Peninsula in the heat exchange coefficient experiments.

  15. Eddy covariance measurements of the sea spray aerosol flux over the open ocean

    NASA Astrophysics Data System (ADS)

    Norris, Sarah J.; Brooks, Ian M.; Hill, Martin K.; Brooks, Barbara J.; Smith, Michael H.; Sproson, David A. J.

    2012-04-01

    Direct eddy covariance measurements of size-segregated sea spray aerosol fluxes over the open Atlantic Ocean are presented, along with a source function derived from them for a wind speed range of 4 to 18 m s-1 and a size range of 0.176 < R80 < 6.61 μm. This is in broad agreement with other recent estimates of the source function over this size range but shows a more rapid decrease with size above R80 = 2 μm than most other functions. The measurements were made during a 3 week cruise in the North Atlantic as part of the UK contribution to the international Surface Ocean-Lower Atmosphere Study (SOLAS) program. They utilized the new high-rate Compact Lightweight Aerosol Spectrometer Probe (CLASP), providing a 16-channel size spectrum (0.17 sea spray aerosol flux compared with other air-sea fluxes, both between individual estimates and in the scales contributing to the flux.

  16. Tropical Cyclone Induced Air-Sea Interactions Over Oceanic Fronts

    NASA Astrophysics Data System (ADS)

    Shay, L. K.

    2012-12-01

    Recent severe tropical cyclones underscore the inherent importance of warm background ocean fronts and their interactions with the atmospheric boundary layer. Central to the question of heat and moisture fluxes, the amount of heat available to the tropical cyclone is predicated by the initial mixed layer depth and strength of the stratification that essentially set the level of entrainment mixing at the base of the mixed layer. In oceanic regimes where the ocean mixed layers are thin, shear-induced mixing tends to cool the upper ocean to form cold wakes which reduces the air-sea fluxes. This is an example of negative feedback. By contrast, in regimes where the ocean mixed layers are deep (usually along the western part of the gyres), warm water advection by the nearly steady currents reduces the levels of turbulent mixing by shear instabilities. As these strong near-inertial shears are arrested, more heat and moisture transfers are available through the enthalpy fluxes (typically 1 to 1.5 kW m-2) into the hurricane boundary layer. When tropical cyclones move into favorable or neutral atmospheric conditions, tropical cyclones have a tendency to rapidly intensify as observed over the Gulf of Mexico during Isidore and Lili in 2002, Katrina, Rita and Wilma in 2005, Dean and Felix in 2007 in the Caribbean Sea, and Earl in 2010 just north of the Caribbean Islands. To predict these tropical cyclone deepening (as well as weakening) cycles, coupled models must have ocean models with realistic ocean conditions and accurate air-sea and vertical mixing parameterizations. Thus, to constrain these models, having complete 3-D ocean profiles juxtaposed with atmospheric profiler measurements prior, during and subsequent to passage is an absolute necessity framed within regional scale satellite derived fields.

  17. Eddy energy sources and flux in the Red Sea

    NASA Astrophysics Data System (ADS)

    Zhan, Peng; Subramanian, Aneesh C.; Kartadikaria, Aditya R.; Hoteit, Ibrahim

    2015-04-01

    In the Red Sea, eddies are reported to be one of the key features of hydrodynamics in the basin. They play a significant role in converting the energy among the large-scale circulation, the available potential energy (APE) and the eddy kinetic energy (EKE). Not only do eddies affect the horizontal circulation, deep-water formation and overturning circulation in the basin, but they also have a strong impact on the marine ecosystem by efficiently transporting heat, nutrients and carbon across the basin and by pumping the nutrient-enriched subsurface water to sustain the primary production. Previous observations and modeling work suggest that the Red Sea is rich of eddy activities. In this study, the eddy energy sources and sinks have been studied based on a high-resolution MITgcm. We have also investigated the possible mechanisms of eddy generation in the Red Sea. Eddies with high EKE are found more likely to appear in the central and northern Red Sea, with a significant seasonal variability. They are more inclined to occur during winter when they acquire their energy mainly from the conversion of APE. In winter, the central and especially the northern Red Sea are subject to important heat loss and extensive evaporation. The resultant densified upper-layer water tends to sink and release the APE through baroclinic instability, which is about one order larger than the barotropic instability contribution and is the largest source term for the EKE in the Red Sea. As a consequence, the eddy energy is confined to the upper layer but with a slope deepening from south to north. In summer, the positive surface heat flux helps maintain the stratification and impedes the gain of APE. The EKE is, therefore, much lower than that in winter despite a higher wind power input. Unlike many other seas, the wind energy is not the main source of energy to the eddies in the Red Sea.

  18. Aircraft measured atmospheric momentum, heat and radiation fluxes over Arctic sea ice

    NASA Astrophysics Data System (ADS)

    Hartmann, Jörg; Kottmeier, Christoph; Wamser, Christian; Augstein, Ernst

    The vertical turbulent momentum, sensible and latent heat fluxes and the surface radiation balance are derived from measurements of low level flights (<50 m height) with a highly instrumented aircraft over Fram Strait in September/October 1991. High resolution information on the sea ice cover is obtained with a digital line scan camera. It is found that the drag coefficient for neutral static stability at 10 m height can be composed of a skin drag (cdns = 1.1 . 10-3), which coincides with the open water value, and a form drag which linearly increases with the mean ice area perpendicular to the surface wind vector per unit surface area. The ratio of the generally small sensible and latent heat fluxes (both ≤ 20 Wm-2) is close to unity for near neutral atmospheric stratification and no dependence of these fluxes on sea ice concentration can be detected, at least for the encountered ice concentrations larger than 50%. Measurements at about 40 m height are not sufficient to study cases with stable stratification since the flight level seems to be fully decoupled from the surface processes. In this autumn measurements 50% to 90% of the net energy flux at the surface is made up by the radiation balance. Therefore, radiative fluxes form important components in polar air-sea exchange processes. The long wave downward radiation can be parameterised using the ɛσT4 law with the near surface air temperature and the empirically determined values for the emissivity ɛ = 0.71 and ɛ = 0.90 for clear and cloudy skies, respectively. The standard deviations of our measurements from this parameterisation are 4.6 Wm-2 for clear and 8.6 Wm-2 for cloudy skies. These values fall into the range ofthe instrumental uncertainty.

  19. Air-sea heat exchange, an element of the water cycle

    NASA Technical Reports Server (NTRS)

    Chahine, M. T.

    1984-01-01

    The distribution and variation of water vapor, clouds and precipitation are examined. Principal driving forces for these distributions are energy exchange and evaporation at the air-sea interface, which are also important elements of air-sea interaction studies. The overall aim of air-sea interaction studies is to quantitatively determine mass, momentum and energy fluxes, with the goal of understanding the mechanisms controlling them. The results of general circulation simulations indicate that the atmosphere in mid-latitudes responds to changes in the oceanic surface conditions in the tropics. This correlation reflects the strong interaction between tropical and mid-latitude conditions caused by the transport of heat and momentum from the tropics. Studies of air-sea exchanges involve a large number of physica, chemical and dynamical processes including heat flux, radiation, sea-surface temperature, precipitation, winds and ocean currents. The fluxes of latent heat are studied and the potential use of satellite data in determining them evaluated. Alternative ways of inferring heat fluxes will be considered.

  20. Air-Sea-Aerosol-Cloud Interactions

    DTIC Science & Technology

    2009-09-30

    hygrometer by mounting its source and detector tubes inside the housing of the obsolete AIR Lyman-alpha hygrometer . This fast responding sensor is...top is shown in Fig. 3. The path of the krypton hygrometer was set for optimum performance on the higher humidity range for the estimation of...path of the krypton hygrometer was set for optimum performance in the higher humidity range for the estimation of surface fluxes this is why its

  1. Methods, fluxes and sources of gas phase alkyl nitrates in the coastal air.

    PubMed

    Dirtu, Alin C; Buczyńska, Anna J; Godoi, Ana F L; Favoreto, Rodrigo; Bencs, László; Potgieter-Vermaak, Sanja S; Godoi, Ricardo H M; Van Grieken, René; Van Vaeck, Luc

    2014-10-01

    The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3-C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO₂ levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor.

  2. [Distribution, flux and biological consumption of carbon monoxide in the East China Sea and the South Yellow Sea in summer].

    PubMed

    Wang, Jing; Lu, Xiao-Lan; Yang, Gui-Peng; Xu, Guan-Qiu

    2014-11-01

    Carbon monoxide (CO) concentration distribution, sea-to-air flux and microbial consumption rate constant, along with atmospheric CO mixing ratio, were measured in the East China Sea and the South Yellow Sea in summer. Atmospheric CO mixing ratios varied from 68 x 10(-9) -448 x 10(-9), with an average of 117 x 10(-9) (SD = 68 x 10(-9), n = 36). Overall, the concentrations of atmospheric CO displayed a decreasing trend from the coastal stations to the offshore stations. The surface water CO concentrations in the investigated area ranged from 0.23-7.10 nmol x L(-1), with an average of 2.49 nmol x L(-1) (SD = 2.11, n = 36). The surface water CO concentrations were significantly affected by sunlight. Vertical profiles showed that CO concentrations rapidly declined with depth, with the maximum values appearing in the surface water. CO concentrations exhibited obvious diurnal variations in the study area, with the maximum values being 6-40 folds higher than the minimum values. Minimal concentrations of CO all occurred before dawn. However, the maximal concentrations of CO occurred at noon. Marked diurnal variation in the concentrations of CO in the water column indicated that CO was produced primarily by photochemistry. The surface CO concentrations were oversaturated relative to the atmospheric concentrations and the saturation factors ranged from 1.99-99.18, with an average of 29.36 (SD = 24.42, n = 29). The East China Sea and the South Yellow Sea was a net source of atmospheric CO. The sea-to-air fluxes of CO in the East China Sea and the South Yellow Sea ranged 0.37-44.84 μmol x (m2 x d)(-1), with an average of 12.73 μmol x (m2 x d)(-1) (SD = 11.40, n = 29). In the incubation experiments, CO concentrations decreased exponentially with incubation time and the processes conformed to the first order reaction characteristics. The microbial CO consumption rate constants (K(co)) in the surface water ranged from 0.12 to 1.45 h(-1), with an average of 0.47 h(-1) (SD = 0

  3. The 3He flux gauge in the Sargasso Sea: a determination of physical nutrient fluxes to the euphotic zone at the Bermuda Atlantic time series site

    NASA Astrophysics Data System (ADS)

    Stanley, R. H. R.; Jenkins, W. J.; Doney, S. C.; Lott, D. E., III

    2015-03-01

    We provide a new determination of the annual mean physical supply of nitrate to the euphotic zone in the western subtropical North Atlantic based on a three year time-series of measurements of tritiugenic 3He from 2003 to 2006 in the surface ocean at the Bermuda Atlantic Time-series Study (BATS) site. We combine the 3He data with a sophisticated noble gas calibrated air-sea gas exchange model to constrain the 3He flux across the sea-air interface, which must closely balance the upward 3He flux into the euphotic zone. The product of the 3He flux and the observed subsurface nitrate-3He relationship provides an estimate of the minimum rate of new production in the BATS region. We also applied the gas model to an earlier time series of 3He measurements at BATS in order to recalculate new production fluxes for the 1985 to 1988 time period. The observations, despite an almost three-fold difference in the nitrate-3He relationship, yield a roughly consistent estimate of nitrate flux. In particular, the nitrate flux from 2003-2006 is estimated to be 0.65 ± 0.3 mol m-2 y-1, which is ~ 40% smaller than the calculated flux for the period from 1985 to 1988. The difference between the time periods, which is barely significant, may be due to a real difference in new production resulting from changes in subtropical mode water formation. Overall, the nitrate flux is larger than most estimates of export fluxes or net community production fluxes made locally for BATS site, which is likely a reflection of the larger spatial scale covered by the 3He technique and potentially also by decoupling of 3He and nitrate during obduction of water masses from the main thermocline into the upper ocean.

  4. Air-ice CO2 fluxes and pCO2 dynamics in the Arctic coastal area (Amundsen Gulf, Canada)

    NASA Astrophysics Data System (ADS)

    Geilfus, Nicolas-Xavier; Tison, Jean Louis; Carnat, Gauthier; Else, Brent; Borges, Alberto V.; Thomas, Helmuth; Shadwick, Elizabeth; Delille, Bruno

    2010-05-01

    Sea ice covers about 7% of the Earth surface at its maximum seasonal extent. For decades sea ice was assumed to be an impermeable and inert barrier for air - sea exchange of CO2 so that global climate models do not include CO2 exchange between the oceans and the atmosphere in the polar regions. However, uptake of atmospheric CO2 by sea ice cover was recently reported raising the need to further investigate pCO2 dynamics in the marine cryosphere realm and related air-ice CO2 fluxes. In addition, budget of CO2 fluxes are poorly constrained in high latitudes continental shelves [Borges et al., 2006]. We report measurements of air-ice CO2 fluxes above the Canadian continental shelf and compare them to previous measurements carried out in Antarctica. We carried out measurements of pCO2 within brines and bulk ice, and related air-ice CO2 fluxes (chamber method) in Antarctic first year pack ice ("Sea Ice Mass Balance in Antarctica -SIMBA" drifting station experiment September - October 2007) and in Arctic first year land fast ice ("Circumpolar Flaw Lead" - CFL, April - June 2008). These 2 experiments were carried out in contrasted sites. SIMBA was carried out on sea ice in early spring while CFL was carried out in from the middle of the winter to the late spring while sea ice was melting. Both in Arctic and Antarctic, no air-ice CO2 fluxes were detected when sea ice interface was below -10°C. Slightly above -10°C, fluxes toward the atmosphere were observed. In contrast, at -7°C fluxes from the atmosphere to the ice were significant. The pCO2 of the brine exhibits a same trend in both hemispheres with a strong decrease of the pCO2 anti-correlated with the increase of sea ice temperature. The pCO2 shifted from a large over-saturation at low temperature to a marked under-saturation at high temperature. These air-ice CO2 fluxes are partly controlled by the permeability of the air-ice interface, which depends of the temperature of this one. Moreover, air-ice CO2 fluxes are

  5. Vertical fluxes of organic contaminants in the Ligurian Sea.

    NASA Astrophysics Data System (ADS)

    Deyme, Remi; Bouloubassi, Ioanna; Taphanel-Valt, Marie-Helene; Miquel, Juan-Carlos; Lorre, Anne; Marty, Jean-Claude; Mejanelle, Laurence

    2010-05-01

    High resolution temporal series of hydrological and biogeochemical parameters have been monitored throughout the SO-DYFAMED program, aiming at better understanding the response of the ocean to anthropic and climatic disturbance. The present contribution addresses fluxes of organic semi-volatile contaminants and of biogenic lipids associated with marine sinking particles. Sediment trap samples were collected at the DYFAMED station (Ligurian Sea, NW Mediterranean Sea) from December 2000 to July 2002, at a depth of 200m and 1000m, and with a time step of 2 to 3 weeks. Polycyclic Aromatic Hydrocarbons (PAHs) and Non-Aromatic Hydrocarbons (NAHs) were investigated to characterize the levels of contamination and the fluxes of contaminants transferred from the upper marine waters to intermediate waters. Specific lipids of phytoplankton, terrigeneous matter and faecal pellets were also determined, aiming at better understanding biogeochemical processes that may impact on pollutant transfer toward deeper marine horizons. Up to 36 PAHs were identified. The 13 parent compound levels (Σ PAH13) varied from 564 to 4156 ng.g-1, with highest concentrations corresponding to winter months. The molecular profile was dominated by low molecular weight PAHs and higher abundance of alkylated homologues over parent compounds. This characteristic, together with diagnostic molecular ratios attribute the main part of PAHs to a petrogenic origin. Aliphatic hydrocarbons were largely dominated by an UCM (Unresolved Complex Mixture), accounting for ca. 91 % of NAHs, which further confirms the dominant petrogenic origin of hydrocarbons. Fluxes of PAHs13 and NAHs varied from 0.29 to 0.422 and from 0.4 to 19.0 ?g.m2.d-1, respectively. Alike concentrations, PAH fluxes were higher than those reported in other open Mediterranean locations, revealing that the study site is under a stronger anthropogenic influence. Various inputs of contaminants at the study site may be pointed out: riverine inputs

  6. Air-Sea Interactions over Lakes on Titan

    NASA Astrophysics Data System (ADS)

    Soto, Alejandro; Rafkin, Scot C. R.

    2016-10-01

    The exchange of methane between the atmosphere and surface liquid reservoirs dominates the short time-scale methanological cycle. In this study, previous two-dimensional simulations of the exchange of methane vapor, sensible heat and momentum between the atmosphere and lakes are updated with the inclusion of radiative forcing, three dimensions, and realistic coastlines. Titan's air-sea exchange in two dimensions indicated that the exchange process was self-limiting. Evaporation from lakes produced a shallow but extremely stable marine layer that suppressed turbulent exchange. Furthermore, the circulation associated with the higher buoyancy of methane-rich atmosphere over the lake was offset by the oppositely directed thermal sea breeze circulation, which muted the mean wind. Two major weaknesses of this previous work were the lack of radiative forcing and the imposition of two dimensionality, which limited the full range of dynamical solutions. Based on early theoretical studies, it was thought that magnitude of turbulent energy flux exchanges would be much larger than radiative fluxes, thereby justifying the neglect of radiation, but the two-dimensional simulations indicated that this was not a valid assumption. The dynamical limitations of two-dimensional simulations are well known. Vorticity stretching (i.e., circulation intensification through vertical motion) is not possible and it is also not possible to produce dynamically balanced gradient wind-type circulations. As well, the irregular shape of a realistic coastline cannot be expressed in two dimensions, and these realistic structures will generally induce complex convergence and divergence circulations in the atmosphere. The impact of radiative forcing and the addition of the third dimension on the air-sea exchange are presented.

  7. Joint Air Sea Interaction (JASIN) experiment, Northwest coast of Scotland

    NASA Technical Reports Server (NTRS)

    Businger, J. A.

    1981-01-01

    The joint air sea interaction (JASIN) experiment took place off the Northwest coast of Scotland. Sea surface and boundary layer parameters were measured. The JASIN data was used as ground truth for various sensors on the SEASAT satellite.

  8. Direct control of air gap flux in permanent magnet machines

    DOEpatents

    Hsu, John S.

    2000-01-01

    A method and apparatus for field weakening in PM machines uses field weakening coils (35, 44, 45, 71, 72) to produce flux in one or more stators (34, 49, 63, 64), including a flux which counters flux normally produced in air gaps between the stator(s) (34, 49, 63, 64) and the rotor (20, 21, 41, 61) which carries the PM poles. Several modes of operation are introduced depending on the magnitude and polarity of current in the field weakening coils (35, 44, 45, 71, 72). The invention is particularly useful for, but not limited to, the electric vehicle drives and PM generators.

  9. Unstable Air-Sea Interaction in the Extratropical North Atlantic

    NASA Technical Reports Server (NTRS)

    Hakkinen, Sirpa

    1999-01-01

    The possibility of coupled modes in the extratropical North Atlantic has fascinated the climate community since 1960's. A significant aspect of such modes is an unstable air-sea interaction, also called positive feedback, where disturbances between the atmosphere and ocean grow unbound. If a delayed response exists before the negative feedback takes effect, an oscillatory behaviour will develop. Here we explore the relationship between heat flux (positive upward) and sea surface temperature (SST). Positive feedback is characterized by a cross-correlation between the two where correlation maintains a negative sign whether SST or heat flux leads. We use model results and observations to argue that in the North Atlantic there exist regions with positive feedback. The two main locations coincide with the well-known north-south SST dipole where anomalies of opposite sign occupy areas east of Florida and north-east of Newfoundland. We show that oceanic dynamics, wave propagation and advection, give rise to oceanic anomalies in these regions. Subsequently these anomalies are amplified by atmosphere- ocean interaction: thus a positive feedback.

  10. An automatic flux chamber for investigating gas flux at water - air interfaces

    NASA Astrophysics Data System (ADS)

    Duc, N. T.; Silverstein, S.; Lundmark, L.; Reyier, H.; Crill, P. M.; Bastviken, D.

    2011-12-01

    Aquatic ecosystems are major sources of greenhouse gases (GHG) and representative measurements of GHG fluxes from aquatic ecosystems to the atmosphere are vital in climate related biogeochemistry. One of the most important fluxes, ebullition (bubble flux) of methane (CH4) is episodic, with large fluxes during short time periods. To properly capture such fluxes long term measurement approaches are necessary which is labor intensive for manual flux chamber based methods, or require expensive equipment with e.g. eddy correlation methods. An inexpensive and easily mobile automatic flux chamber for long-term measurements has been designed to approach these drawbacks. This device includes a flux chamber, with a controller/datalogger, valves, a pump, a 12 V battery and a solar cell. Sensors used so far record CH4 concentration in the chamber headspace, temperature in water and air, barometric pressure. Other sensors for e.g. CO2 and weather variables can be attached. The unit can be programmed to measure in situ accumulation of gas in the chamber and also to collect gas samples in an array of sample bottles for subsequent analysis in the laboratory. Simultaneous deployment of many such units represent a cost efficient and easily managed solution for local long term flux monitoring.

  11. Monsoon-driven vertical fluxes of organic pollutants in the western Arabian Sea

    SciTech Connect

    Dachs, J.; Bayona, J.M.; Ittekkot, V.; Albaiges, J.

    1999-11-15

    A time series of sinking particles from the western Arabian Sea was analyzed for aliphatic and polycyclic aromatic hydrocarbons, polychlorinated biphenyls, 4,4{prime}-DDT and 4,4{prime}-DDE, to assess the role of monsoons on their vertical flux in the Indian Ocean. Concurrently, molecular markers such as sterols and linear and branched alkanes were analyzed enabling the characterization of the biogenic sources and biogeochemical processes occurring during the sampling period. Hierarchical cluster analysis (HCA) of the data set of concentrations and fluxes of these compounds confirmed a seasonal variability driven by the SW and NE monsoons. Moreover, the influence of different air masses is evidenced by the occurrence of higher concentrations of DDT, PCBs, and pyrolytic PAHs during the NE monsoon and of fossil hydrocarbons during the SW monsoon. Total annual fluxes to the deep Arabian Sea represent an important removal contribution of persistent organic pollutants, thus not being available for the global distillation process (volatilization and atmospheric transport from low or mid latitudes to cold areas). Therefore, monsoons may play a significant role on the global cycle of organic pollutants.

  12. To what extent does the salinity flux influence phytoplankton blooms? - Baltic Sea modeling study

    NASA Astrophysics Data System (ADS)

    Cieszyńska, Agata; Stramska, Małgorzata

    2016-04-01

    This work is focused on numerical modeling of biological-physical interactions and their influence on phytoplankton production and vertical distribution of biomass and its variability in the surface waters of the Baltic Sea. The area of interest is an inland sea with water salinity much smaller than observed in the global ocean (about one fifth of the open ocean value). Vertical distribution of the salinity has a significant influence on water column density stratification, and therefore influences intensity of mixing and the depth of mixed layer. This, in turn, defines environmental conditions for phytoplankton growth. Vertical distribution of water salinity in the basin is controlled by processes such as evaporation/precipitation, freezing/melting of sea ice and runoff of freshwater from land. There are a lot of different phytoplankton species in the area of the Baltic Sea. Every single one has its own characteristics and is sensitive to distinct complex environmental conditions. Biological-physical interactions controlling these microorganisms' life cycles are multiplicitous and because of their complexity difficult to quantify. The best and probably only way to study presented issue is the usage of numerical modeling tool. The results presented here are based on 1D numerical simulations carried out with Princeton Ocean Model (POM, http://www.ccpo.odu.edu/POMWEB/) merged with the Ecological Regional Ecosystem Model (ERGOM, http://ergom.net/) developed for the Baltic Sea research by German scientists from the Leibniz Institute for Baltic Sea Research in Warnemünde. In model simulations surface salinity flux was determined from the difference between the precipitation and evaporation rate at the air-sea interface. Data for parameterization of atmospheric forcing were defined based on data sets from National Centers of Environmental Prediction (NCEP). We carried out systematic calculations using different values of surface fluxes encompassing the range of

  13. Transfer Processes at the Air--Sea Interface

    NASA Astrophysics Data System (ADS)

    Guymer, T. H.; Businger, J. A.; Katsaros, K. B.; Shaw, W. J.; Taylor, P. K.; Large, W. G.; Payne, R. E.

    1983-02-01

    Near-surface data from ships, buoys, aircraft and a microwave remote-sensing satellite have been used to estimate the fluxes of momentum, heat and water vapour at the sea surface over a 200 km × 200 km area during the Joint Air--Sea Interaction Experiment of 1978. In particular, daily means of the surface heat balance and the wind stress are presented. Generally, the sensible heat flux was found to be less than 25% of the latent heat flux. Over periods of a day the total upward heat flux was about a third of the net radiation, implying that a significant proportion of the available energy went into heating the ocean. The Ekman pumping accounted for most of the divergence in the atmospheric boundary layer but only 10% at most of that in the upper ocean. Some case studies of the horizontal variation of the fluxes in relation to larger scales are also discussed and it is suggested that the fluxes are modulated by mesoscale patterns in sea-surface temperature. Surface turbulent fluxes and SST have been examined on scales from several kilometres to 200 km and for days to weeks by using a combination of ships, buoys, aircraft and microwave remote sensing. The net radiative flux had been obtained at the corners of the 200 km meteorological triangle either by direct measurements of the shortwave and longwave components or by parametrization techniques. This has enabled the surface heat budget to be examined on a daily basis. About 70% of the net flux (typically 100 W m-2 in phase 1 and 70 W m-2 in phase 2) is available for heating the ocean and, of the remainder, over 75% goes into the atmosphere as latent heat. In these near-neutral conditions the mean surface wind speed across the triangle was 77% of the geostrophic wind speed and the cross-isobar flow angle was 11 degrees (down-gradient). Significant variations in the thermodynamic fluxes across the area were found, associated partly with the SST distribution and also with the fact that the coldest and driest air was

  14. Air and seawater pollution and air-sea gas exchange of persistent toxic substances in the Aegean Sea: spatial trends of PAHs, PCBs, OCPs and PBDEs.

    PubMed

    Lammel, Gerhard; Audy, Ondřej; Besis, Athanasios; Efstathiou, Christos; Eleftheriadis, Kostas; Kohoutek, Jiři; Kukučka, Petr; Mulder, Marie D; Přibylová, Petra; Prokeš, Roman; Rusina, Tatsiana P; Samara, Constantini; Sofuoglu, Aysun; Sofuoglu, Sait C; Taşdemir, Yücel; Vassilatou, Vassiliki; Voutsa, Dimitra; Vrana, Branislav

    2015-08-01

    Near-ground air (26 substances) and surface seawater (55 substances) concentrations of persistent toxic substances (PTS) were determined in July 2012 in a coordinated and coherent way around the Aegean Sea based on passive air (10 sites in 5 areas) and water (4 sites in 2 areas) sampling. The direction of air-sea exchange was determined for 18 PTS. Identical samplers were deployed at all sites and were analysed at one laboratory. hexachlorobenzene (HCB), hexachlorocyclohexanes (HCHs) as well as dichlorodiphenyltrichloroethane (DDT) and its degradation products are evenly distributed in the air of the whole region. Air concentrations of p,p'-dichlorodiphenyldichloroethylene (p,p'-DDE) and o,p'-DDT and seawater concentrations of p,p'-DDE and p,p'-DDD were elevated in Thermaikos Gulf, northwestern Aegean Sea. The polychlorinated biphenyl (PCB) congener pattern in air is identical throughout the region, while polybrominated diphenylether (PBDE)patterns are obviously dissimilar between Greece and Turkey. Various pollutants, polycyclic aromatic hydrocarbons (PAHs), PCBs, DDE, and penta- and hexachlorobenzene are found close to phase equilibrium or net-volatilisational (upward flux), similarly at a remote site (on Crete) and in the more polluted Thermaikos Gulf. The results suggest that effective passive air sampling volumes may not be representative across sites when PAHs significantly partitioning to the particulate phase are included.

  15. 1994 Technology report: Land, sea & air

    SciTech Connect

    1994-12-31

    The IGTI 1994 Technology Report, Land, Sea & Air, is compiled, edited, published and distributed by the International Gas Turbine Institute in Atlanta, Georgia. The report represents the best industrial accomplishments and brightest technological advances in the gas turbine and aeroengine industry this year. The report consists of a compilation of submittals from companies, governmental agencies and organizations, universities, IGTI Committee chairs, and other individuals involved in gas turbine technology worldwide. This year`s edition features over 200 reports from twenty-six countries around the globe. In accordance with IGTI policy, these reports are new contributions to the gas turbine industry. No reports have been repeated from previous IGTI publications. There are 25 new contributors to the report including submissions from Hungary, Korea, Sweden and Turkey to this year`s edition. It demonstrates IGTI`s commitment to fostering cooperation and building partnerships on a truly international basis.

  16. Air-sea carbon dioxide exchange in the Southern Ocean and Antarctic Sea ice zone

    NASA Astrophysics Data System (ADS)

    Butterworth, Brian J.

    The Southern Ocean is an important part of the global carbon cycle, responsible for roughly half of the carbon dioxide (CO2) absorbed by the global ocean. The air-sea CO2 flux (Fc) can be expressed as the product of the water-air CO2 partial pressure difference (DeltapCO2) and the gas transfer velocity ( k), an exchange coefficient which represents the efficiency of gas exchange. Generally, Fc is negative (a sink) throughout the Southern Ocean and Antarctic sea ice zone (SIZ), but uncertainty in k has made it difficult to develop an accurate regional carbon budget. Constraining the functional dependence of k on wind speed in open water environments, and quantifying the effect of sea ice on k, will reduce uncertainty in the estimated contribution of the Southern Ocean and Antarctic SIZ to the global carbon cycle. To investigate Fc in the Southern Ocean, a ruggedized, unattended, closed-path eddy covariance (EC) system was deployed on the Antarctic research vessel Nathaniel B. Palmer for nine cruises during 18 months from January 2013 to June 2014 in the Southern Ocean and coastal Antarctica. The methods are described and results are shown for two cruises chosen for their latitudinal range, inclusion of open water and sea ice cover, and large DeltapCO2. The results indicated that ship-based unattended EC measurements in high latitudes are feasible, and recommendations for deployments in such environments were provided. Measurements of Fc and DeltapCO2 were used to compute k. The open water data showed a quadratic relationship between k (cm hr-1) and the neutral 10-m wind speed (U10n, m s -1), k=0.245 U10n 2+1.3, in close agreement with tracer-based results and much lower than previous EC studies. In the SIZ, it was found that k decreased in proportion to sea ice cover. This contrasted findings of enhanced Fc in the SIZ by previous open-path EC campaigns. Using the NBP results a net annual Southern Ocean (ocean south of 30°S) carbon flux of -1.1 PgC yr-1 was

  17. Formaldehyde in remote marine air and rain - Flux measurements and estimates

    NASA Astrophysics Data System (ADS)

    Zafiriou, O. C.; Alford, J.; Herrera, M.; Peltzer, E. T.; Gagosian, R. B.; Liu, S. C.

    1980-05-01

    The tropospheric trace constituent formaldehyde, HCHO, was measured in rain and in the gas phase during the wet season at Enewetak Atoll, a remote marine site in the central equatorial Pacific. Rainwater averaged 8 + or - 2 microgram/kg; the gas phase averaged 0.4 + or 0.2 ppbv (0.5 microgram/cu m). These values, especially the rain, are among the lowest reported to date. The formaldehyde flux to the sea by rainout and washout extrapolates to 0.010 g/sq m per year. The gaseous flux into the sea surface is estimated to be 0.05 g/sq m per year by an air-sea exchange calculation that takes into account enhanced uptake by hydroxide-catalyzed formaldehyde hydration. The measured mixing ratio is close to the 0.18 ppbv prediction of a tropospheric chemistry model calculation. The methane oxidation chain probably is the sole formaldehyde source in the Enewetak area. The total formaldehyde flux as carbon into the ocean is approximately 2% of the estimated total organic carbon from rainout and washout. About 2-4% of the calculated column formaldehyde production is removed from the atmosphere by these processes.

  18. A climatology of air-sea interactions at the Mediterranean LION and AZUR buoys

    NASA Astrophysics Data System (ADS)

    Caniaux, Guy; Prieur, Louis; Bouin, Marie-Noëlle; Giordani, Hervé

    2014-05-01

    The LION and AZUR buoys (respectively at 42.1°N 4.7°E and 43.4°N 7.8°E) provide an extended data set since respectively 1999 and 2001 to present for studying air-sea interactions in the northwestern Mediterranean basin. The two buoys are located where high wind events occur (resp. north western and north easterly gale winds), that force and condition deep oceanic winter convection in that region. A short-term climatology (resp. 13 and 11 years) of air-sea interactions has been developed, which includes classical meteo-oceanic parameters, but also waves period and significant wave heights and radiative fluxes. Moreover turbulent surface fluxes have been estimated from various bulk parameterizations, in order to estimate uncertainties on fluxes. An important dispersion of turbulent fluxes is found at high wind speeds according to the parameterization used, larger than taking into account the second order effects of cool skin, warm layer and waves. An important annual cycle affects air temperatures (ATs), SSTs and turbulent fluxes at the two buoys. The annual cycle of ATs and SSTs can be well reconstructed from the first two annual harmonics, while for the turbulent heat fluxes the erratic occurrence of high and low flux events, well correlated with high/dry and low windy periods, strongly affect their annual and interannual cycles. The frequency of high surface heat fluxes and high wind stress is found highest during the autumn and winter months, despite the fact that north-westerly gale winds occur all year long at LION buoy. During calm weather period, ATs and SSTs experience an important diurnal cycle (on average 1 and 0.5°C respectively), that affect latent and sensible heat fluxes. Finally, an estimate of the interannual variability of the turbulent fluxes in Autumn and Winter is discussed, in order to characterize their potential role on deep ocean convection.

  19. The 3He flux gauge in the Sargasso Sea: a determination of physical nutrient fluxes to the euphotic zone at the Bermuda Atlantic Time-series Site

    NASA Astrophysics Data System (ADS)

    Stanley, R. H. R.; Jenkins, W. J.; Doney, S. C.; Lott, D. E., III

    2015-09-01

    Significant rates of primary production occur in the oligotrophic ocean, without any measurable nutrients present in the mixed layer, fueling a scientific paradox that has lasted for decades. Here, we provide a new determination of the annual mean physical supply of nitrate to the euphotic zone in the western subtropical North Atlantic. We combine a 3-year time series of measurements of tritiugenic 3He from 2003 to 2006 in the surface ocean at the Bermuda Atlantic Time-series Study (BATS) site with a sophisticated noble gas calibrated air-sea gas exchange model to constrain the 3He flux across the sea-air interface, which must closely mirror the upward 3He flux into the euphotic zone. The product of the 3He flux and the observed subsurface nitrate-3He relationship provides an estimate of the minimum rate of new production in the BATS region. We also apply the gas model to an earlier time series of 3He measurements at BATS in order to recalculate new production fluxes for the 1985 to 1988 time period. The observations, despite an almost 3-fold difference in the nitrate-3He relationship, yield a roughly consistent estimate of nitrate flux. In particular, the nitrate flux from 2003 to 2006 is estimated to be 0.65 ± 0.14 mol m-2 yr-1, which is ~40 % smaller than the calculated flux for the period from 1985 to 1988. The difference in nitrate flux between the time periods may be signifying a real difference in new production resulting from changes in subtropical mode water formation. Overall, the nitrate flux is larger than most estimates of export fluxes or net community production fluxes made locally for the BATS site, which is likely a reflection of the larger spatial scale covered by the 3He technique and potentially also by the decoupling of 3He and nitrate during the obduction of water masses from the main thermocline into the upper ocean. The upward nitrate flux is certainly large enough to support observed rates of primary production at BATS and more generally

  20. Air-sea Exchange of Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs), Organochlorine Pesticides (OCPs) and Polybrominated Diphenyl Ethers (PBDEs) in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Lammel, G. P.; Heil, A.; Kukucka, P.; Meixner, F. X.; Mulder, M. D.; Prybilova, P.; Prokes, R.; Rusina, T. S.; Song, G. Z.; Vrana, B.

    2015-12-01

    The marine atmospheric environment is a receptor for persistent organic pollutants (POPs) which are advected from sources on land, primary, such as biomass burning by-products (PAHs, dioxins), and secondary, such as volatilization from contaminated soils (PCBs, pesticides). Primary sources do not exist in the marine environment, except for PAHs (ship engines) but following previous atmospheric deposition, the sea surface may turn to a secondary source by reversal of diffusive air-sea mass exchange. No monitoring is in place. We studied the vertical fluxes of a wide range of primary and secondary emitted POPs based on measurements in air and surface seawater at a remote coastal site in the eastern Mediterranean (2012). To this end, silicon rubbers were used as passive water samplers, vertical concentration gradients were determined in air and fluxes were quantified based on Eddy covariance. Diffusive air-sea exchange fluxes of hexachlorocyclohexanes (HCHs) and semivolatile PAHs were found close to phase equilibrium, except one PAH, retene, a wood burning tracer, was found seasonally net-volatilisational. Some PCBs, p,p'-DDE, penta- and hexachlorobenzene (PeCB, HCB) were mostly net-depositional, while PBDEs were net-volatilizational. Fluxes determined at a a remote coastal site ranged -33 - +2.4 µg m-2 d-1 for PAHs and -4.0 - +0.3 µg m-2 d-1for halogenated compounds (< 0 means net-deposition, > 0 means net-volatilization). It is concluded that nowadays in open seas more pollutants are undergoing reversal of the direction of air-sea exchange. Recgional fire activity records in combination with box model simulations suggest that deposition of retene during summer is followed by a reversal of air-sea exchange. The seawater surface as secondary source of pollution should be assessed based on flux measurements across seasons and over longer time periods.

  1. The potential role of sea spray droplets in facilitating air-sea gas transfer

    NASA Astrophysics Data System (ADS)

    Andreas, E. L.; Vlahos, P.; Monahan, E. C.

    2016-05-01

    For over 30 years, air-sea interaction specialists have been evaluating and parameterizing the role of whitecap bubbles in air-sea gas exchange. To our knowledge, no one, however, has studied the mirror image process of whether sea spray droplets can facilitate air-sea gas exchange. We are therefore using theory, data analysis, and numerical modeling to quantify the role of spray on air-sea gas transfer. In this, our first formal work on this subject, we seek the rate-limiting step in spray-mediated gas transfer by evaluating the three time scales that govern the exchange: τ air , which quantifies the rate of transfer between the atmospheric gas reservoir and the surface of the droplet; τ int , which quantifies the exchange rate across the air-droplet interface; and τ aq , which quantifies gas mixing within the aqueous solution droplet.

  2. Effect of air-sea coupling on the frequency distribution of intense tropical cyclones over the northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Ogata, Tomomichi; Mizuta, Ryo; Adachi, Yukimasa; Murakami, Hiroyuki; Ose, Tomoaki

    2015-12-01

    Effect of air-sea coupling on the frequency distribution of intense tropical cyclones (TCs) over the northwestern Pacific (NWP) region is investigated using an atmosphere and ocean coupled general circulation model (AOGCM). Monthly varying flux adjustment enables AOGCM to simulate both subseasonal air-sea interaction and realistic seasonal to interannual sea surface temperature (SST) variability. The maximum of intense TC distribution around 20-30°N in the AGCM shifts equatorward in the AOGCM due to the air-sea coupling. Hence, AOGCM reduces northward intense TC distribution bias seen in AGCM. Over the NWP, AOGCM-simulated SST variability is large around 20-30°N where the warm mixed layer becomes shallower rapidly. Active entrainment from subsurface water over this region causes stronger SST cooling, and hence, TC intensity decreases. These results suggest that air-sea coupling characterized by subsurface oceanic condition causes more realistic distribution of intense TCs over the NWP.

  3. Spatial variation of sea surface temperature and flux-related parameters measured from aircraft in the JASIN experiment

    NASA Technical Reports Server (NTRS)

    Liu, W. T.; Katsaros, K. B.

    1984-01-01

    Spatial variation of some parameters measured on two aircraft flying 100-km box and 200-km triangular patterns at low levels in the atmospheric boundary layer during the Joint Air Sea Interaction Experiment in the North Atlantic was studied. The variation should be representative of summer conditions in mid-latitude oceans. The variance density of remotely sensed sea surface temperature, corrected for sky reflection, is found to depend on the one-dimensional wave number raised to the power of approximately -5/3. Nonuniform clouds add low-frequency variance to observations of a downward looking radiometer and result in steeper slope of the spectra of uncorrected sea surface temperature. Turbulent fluxes of momentum, sensible heat, and moisture were determined with the bulk formulae from the parameters (wind speed, temperature, specific humidity, and sea surface temperature) measured from the aircraft. The averages of these fluxes over each flight leg were compared with the fluxes determined from the parameters averaged over the same leg. The difference is negligible, showing that spatially averaged observations, such as those from spaceborne sensors, can be used in the bulk formulae to evaluate the fluxes.

  4. Air-Sea Interaction Measurements from the Controlled Towed Vehicle

    NASA Astrophysics Data System (ADS)

    Khelif, D.; Bluth, R. T.; Jonsson, H.; Barge, J.

    2014-12-01

    The Controlled Towed Vehicle (CTV) uses improved towed drone technology to actively maintain via a radar altimeter and controllable wing a user-set height that can be as low as the canonical reference height of 10 m above the sea surface. After take-off, the drone is released from the tow aircraft on a ~700-m stainless steel cable. We have instrumented the 0.23 m diameter and 2.13 m long drone with high fidelity instruments to measure the means and turbulent fluctuations of 3-D wind vector, temperature, humidity, pressure, CO2 and IR sea surface temperature. Data are recorded internally at 40 Hz and simultaneously transmitted to the tow aircraft via dedicated wireless Ethernet link. The CTV accommodates 40 kg of instrument payload and provides it with 250 W of continuous power through a ram air propeller-driven generator. Therefore its endurance is only limited by that of the tow aircraft.We will discuss the CTV development, the engineering challenges and solutions that have been successfully implemented to overcome them. We present results from recent flights as low as 9 m over the coastal ocean and comparisons of profiles and turbulent fluxes from the CTV and the tow aircraft. Manned aircraft operation at low-level boundary-layer flights is very limited. Dropsondes and UAS (Unmanned Aerial Systems) and UAS are alternates for measurements near the ocean surface. However, dropsondes have limited sensor capability and do not measure fluxes, and most present UAS vehicles do not have the payload and power capacity nor the low-flying ability in high winds over the oceans. The CTV therefore, fills a needed gap between the dropsondes, in situ aircraft, and UAS. The payload, capacity and power of the CTV makes it suitable for a variety of atmospheric research measurements. Other sensors to measure aerosol, chemistry, radiation, etc., could be readily accommodated in the CTV.

  5. Linking air-sea energy exchanges and European anchovy potential spawning ground

    NASA Astrophysics Data System (ADS)

    Grammauta, R.; Molteni, D.; Basilone, G.; Guisande, C.; Bonanno, A.; Aronica, S.; Giacalone, G.; Fontana, I.; Zora, M.; Patti, B.; Cuttitta, A.; Buscaino, G.; Sorgente, R.; Mazzola, S.

    2008-10-01

    The physical and chemical processes of the sea greatly affect the reproductive biology of fishes, mainly influencing both the numbers of spawned eggs and the survivorship of early stages up to the recruitment period. In the central Mediterranean, the European anchovy constitutes one of the most important fishery resource. Because of its short living nature and of its recruitment variability, associated to high environmental variability, this small pelagic species undergo high interannual fluctuation in the biomass levels. Despite several efforts were addressed to characterize fishes spawning habitat from the oceanographic point of view, very few studies analyze the air-sea exchanges effects. To characterize the spawning habitat of these resources a specific technique (quotient rule analysis) was applied on air-sea heat fluxes, wind stress, sea surface temperature and turbulence data, collected in three oceanographic surveys during the summer period of 2004, 2005 and 2006. The results showed the existence of preferred values in the examined physical variables, associated to anchovy spawning areas. Namely, for heat fluxes the values were around -40 W/m2, for wind stress 0.04-0.11 N/m2, for SST 23°C, and 300 - 500 m3s-3 for wind mixing. Despite the obtained results are preliminary, this is the first relevant analysis on the air-sea exchanges and their relationship with the fish biology of pelagic species.

  6. Remote Sensing and Sea-Truth Measurements of Methane Flux to the Atmosphere (HYFLUX project)

    SciTech Connect

    Ian MacDonald

    2011-05-31

    A multi-disciplinary investigation of distribution and magnitude of methane fluxes from seafloor gas hydrate deposits in the Gulf of Mexico was conducted based on results obtained from satellite synthetic aperture radar (SAR) remote sensing and from sampling conducted during a research expedition to three sites where gas hydrate occurs (MC118, GC600, and GC185). Samples of sediments, water, and air were collected from the ship and from an ROV submersible using sediments cores, niskin bottles attached to the ROV and to a rosette, and an automated sea-air interface collector. The SAR images were used to quantify the magnitude and distribution of natural oil and gas seeps that produced perennial oil slicks on the ocean surface. A total of 176 SAR images were processed using a texture classifying neural network algorithm, which segmented the ocean surface into oil-free and oil-covered water. Geostatistical analysis indicates that there are a total of 1081 seep formations distributed over the entire Gulf of Mexico basin. Oil-covered water comprised an average of 780.0 sq. km (sd 86.03) distributed with an area of 147,370 sq. km. Persistent oil and gas seeps were also detected with SAR sampling on other ocean margins located in the Black Sea, western coast of Africa, and offshore Pakistan. Analysis of sediment cores from all three sites show profiles of sulfate, sulfide, calcium and alkalinity that indicated anaerobic oxidation of methane with precipitation of authigenic carbonates. Difference among the three sampling sites may reflect the relative magnitude of methane flux. Methane concentrations in water column samples collected by ROV and rosette deployments from MC118 ranged from {approx}33,000 nM at the seafloor to {approx}12 nM in the mixed layer with isolated peaks up to {approx}13,670 nM coincident with the top of the gas hydrate stability field. Average plume methane, ethane, and propane concentrations in the mixed layer are 7, 630, and 9,540 times saturation

  7. Air-Sea Interaction Measurements from R/P FLIP

    NASA Astrophysics Data System (ADS)

    Friehe, C. A.

    2002-12-01

    Soon after its inception, R/P FLIP was used to study the interaction of the atmosphere and ocean due to its unique stability and low flow distortion. A number of campaigns have been conducted to measure the surface fluxes of heat, water vapor and horizontal momentum of the wind with instrumentation as used over land, supported by the Office of Naval Research and the National Science Foundation. The size of FLIP allows for simultaneous ocean wave and mixed-layer measurements as well. Air-sea interaction was a prime component of BOMEX in 1968, where FLIP transited the Panama Canal. The methods used were similar to the over-land "Kansas" experiment of AFCRL in 1968. BOMEX was followed by many experiments in the north Pacific off San Diego, northern California, and Hawaii. Diverse results from FLIP include identification of the mechanism that causes erroneous fluctuating temperature measurements in the salt-aerosol-laden marine atmosphere, the role of humidity on optical refractive index fluctuations, and identification of Miles' critical layer in the air flow over waves.

  8. Developments in Airborne Oceanography and Air-Sea Interaction

    NASA Astrophysics Data System (ADS)

    Melville, W. K.

    2014-12-01

    , just as aircraft carriers "project force". Now we can measure winds, waves, temperatures, currents, radiative transfer, images and air-sea fluxes from aircraft over the ocean.I will review some of the history of airborne oceanography and present examples of how it can extend our knowledge and understanding of air-sea interaction.

  9. The sensitivity of latent heat flux to the air humidity approximations used in ocean circulation models

    NASA Technical Reports Server (NTRS)

    Liu, W. Timothy; Niiler, Pearn P.

    1990-01-01

    In deriving the surface latent heat flux with the bulk formula for the thermal forcing of some ocean circulation models, two approximations are commonly made to bypass the use of atmospheric humidity in the formula. The first assumes a constant relative humidity, and the second supposes that the sea-air humidity difference varies linearly with the saturation humidity at sea surface temperature. Using climatological fields derived from the Marine Deck and long time series from ocean weather stations, the errors introduced by these two assumptions are examined. It is shown that the errors reach above 100 W/sq m over western boundary currents and 50 W/sq m over the tropical ocean. The two approximations also introduce erroneous seasonal and spatial variabilities with magnitudes over 50 percent of the observed variabilities.

  10. Sea-air boundary meteorological sensor

    NASA Astrophysics Data System (ADS)

    Barbosa, Jose G.

    2015-05-01

    The atmospheric environment can significantly affect radio frequency and optical propagation. In the RF spectrum refraction and ducting can degrade or enhance communications and radar coverage. Platforms in or beneath refractive boundaries can exploit the benefits or suffer the effects of the atmospheric boundary layers. Evaporative ducts and surface-base ducts are of most concern for ocean surface platforms and evaporative ducts are almost always present along the sea-air interface. The atmospheric environment also degrades electro-optical systems resolution and visibility. The atmospheric environment has been proven not to be uniform and under heterogeneous conditions substantial propagation errors may be present for large distances from homogeneous models. An accurate and portable atmospheric sensor to profile the vertical index of refraction is needed for mission planning, post analysis, and in-situ performance assessment. The meteorological instrument used in conjunction with a radio frequency and electro-optical propagation prediction tactical decision aid tool would give military platforms, in real time, the ability to make assessments on communication systems propagation ranges, radar detection and vulnerability ranges, satellite communications vulnerability, laser range finder performance, and imaging system performance predictions. Raman lidar has been shown to be capable of measuring the required atmospheric parameters needed to profile the atmospheric environment. The atmospheric profile could then be used as input to a tactical decision aid tool to make propagation predictions.

  11. Air-Sea and Lateral Exchange Processes in East Indian Coastal Current off Sri Lanka

    DTIC Science & Technology

    2015-09-30

    of which have a bearing on local air-sea fluxes. The project seeks to collect hydrographic data sets in the international waters (R/V Roger Revelle...and in Sri Lankan coastal waters (R/V Samuddrika). The measurements include thermohaline stratification, currents and the kinetic energy...conducted CTD and ADCP measurements in the southern BoB onboard R/V Roger Revelle and in Sri Lanka coastal waters using R/V Samuddrika. The data analysis

  12. Temporal variability of air-sea CO2 exchange in a low-emission estuary

    NASA Astrophysics Data System (ADS)

    Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

    2016-07-01

    There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

  13. Atlantic Air-Sea Interaction Revisited

    NASA Astrophysics Data System (ADS)

    Rodwell, M. J.

    INTRODUCTION DATA AND MODELS THE ANALYSIS METHOD ATMOSPHERIC FORCING OF NORTH ATLANTIC SEA SURFACE TEMPERATURES NORTH ATLANTIC SEA SURFACE TEMPERATURE FORCING OF THE ATMOSPHERE Observational Evidence Model Results POTENTIAL SEASONAL PREDICTABILITY BASED ON THE ATMOSPHERE GENERAL - CIRCULATION MODEL CONCLUSIONS AND DISCUSSION REFERENCES

  14. Effects of the Sea Ice Floe Size Distribution on Polar Ocean Properties and Air-Sea Exchange

    NASA Astrophysics Data System (ADS)

    Horvat, C.; Tziperman, E.

    2014-12-01

    Recent scientific studies have demonstrated that sub-mesoscale ocean eddies, motions characterized by Rossby and Richardson numbers around 1, are important in determining the vertical density structure of the ocean, particularly in the mixed layer. Instabilities excited at the sub-mesoscale have timescales of days and length scales of less than 10 kilometers, and enhance ocean restratification by slumping lateral density gradients. In the polar oceans, a unique mechanism exists that may generate motions on these scales. Individual floes of sea ice may create lateral gradients in the ocean surface heat flux and wind stress curl, acting as an insulator and physical barrier between the ocean and the atmospheric processes that destabilize it. The "floe size distribution" describes the fraction of the ocean surface area covered by sea ice floes, as a function of the sea ice floe size, and determines the length scales over which gradients in atmospheric forcing are transmitted to the ocean. It may therefore play a significant role in exciting or inhibiting sub-mesoscale eddies, and consequently in restratification and air-sea exchange. Current GCMs simulate ice cover using grid-scale ice fraction alone, and lack information about the floe size distribution and of ice length scales that may be important in setting the larger-scale statistics of these motions. An important factor in determining the properties of the upper polar oceans might therefore be missing from modern GCMs. We consider this possibility by examining sub-mesoscale resolving ocean GCM experiments coupled to an energy-balanced atmosphere and idealized model of floes of sea ice. Varying the floe size distribution with a fixed sea ice fraction, we find that the length scales of individual floes and the floe size distribution itself play an important role in setting the steady-state ocean stratification, temperature, and air-sea exchange.

  15. The Gas Transfer through Polar Sea ice experiment: Insights into the rates and pathways that determine geochemical fluxes

    NASA Astrophysics Data System (ADS)

    Lovely, A.; Loose, B.; Schlosser, P.; McGillis, W.; Zappa, C.; Perovich, D.; Brown, S.; Morell, T.; Hsueh, D.; Friedrich, R.

    2015-12-01

    Sea ice is a defining feature of the polar marine environment. It is a critical domain for marine biota and it regulates ocean-atmosphere exchange, including the exchange of greenhouse gases such as CO2 and CH4. In this study, we determined the rates and pathways that govern gas transport through a mixed sea ice cover. N2O, SF6, 3He, 4He, and Ne were used as gas tracers of the exchange processes that take place at the ice-water and air-water interfaces in a laboratory sea ice experiment. Observation of the changes in gas concentrations during freezing revealed that He is indeed more soluble in ice than in water; Ne is less soluble in ice, and the larger gases (N2O and SF6) are mostly excluded during the freezing process. Model estimates of gas diffusion through ice were calibrated using measurements of bulk gas content in ice cores, yielding gas transfer velocity through ice (kice) of ˜5 × 10-4 m d-1. In comparison, the effective air-sea gas transfer velocities (keff) ranged up to 0.33 m d-1 providing further evidence that very little mixed-layer ventilation takes place via gas diffusion through columnar sea ice. However, this ventilation is distinct from air-ice gas fluxes driven by sea ice biogeochemistry. The magnitude of keff showed a clear increasing trend with wind speed and current velocity beneath the ice, as well as the combination of the two. This result indicates that gas transfer cannot be uniquely predicted by wind speed alone in the presence of sea ice.

  16. The Oceanic Flux Program: A three decade time-series of particle flux in the deep Sargasso Sea

    NASA Astrophysics Data System (ADS)

    Weber, J. C.; Conte, M. H.

    2010-12-01

    The Oceanic Flux Program (OFP), 75 km SE of Bermuda, is the longest running time-series of its kind. Initiated in 1978, the OFP has produced an unsurpassed, nearly continuous record of temporal variability in deep ocean fluxes, with a >90% temporal coverage at 3200m depth. The OFP, in conjunction with the co-located Bermuda-Atlantic Time Series (BATS) and the Bermuda Testbed Mooring (BTM) time-series, has provided key observations enabling detailed assessment of how seasonal and non-seasonal variability in the deep ocean is linked with the overlying physical and biogeochemical environment. This talk will focus on the short-term flux variability that overlies the seasonal flux pattern in the Sargasso Sea, emphasizing episodic extreme flux events. Extreme flux events are responsible for much of the year-to-year variability in mean annual flux and are most often observed during early winter and late spring when surface stratification is weak or transient. In addition to biological phenomena (e.g. salp blooms), passage of productive meso-scale features such as eddies, which alter surface water mixing characteristics and surface export fluxes, may initiate some extreme flux events. Yet other productive eddies show a minimal influence on the deep flux, underscoring the importance of upper ocean ecosystem structure and midwater processes on the coupling between the surface ocean environment and deep fluxes. Using key organic and inorganic tracers, causative processes that influence deep flux generation and the strength of the coupling with the surface ocean environment can be identified.

  17. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts.

    PubMed

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-07-20

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change.

  18. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    NASA Astrophysics Data System (ADS)

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-07-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change.

  19. Air-sea exchange of carbon dioxide in the Southern Ocean and Antarctic marginal ice zone

    NASA Astrophysics Data System (ADS)

    Butterworth, Brian J.; Miller, Scott D.

    2016-07-01

    Direct carbon dioxide flux measurements using eddy covariance from an icebreaker in the high-latitude Southern Ocean and Antarctic marginal ice zone are reported. Fluxes were combined with the measured water-air carbon dioxide partial pressure difference (ΔpCO2) to compute the air-sea gas transfer velocity (k, normalized to Schmidt number 660). The open water data showed a quadratic relationship between k (cm h-1) and the neutral 10 m wind speed (U10n, m s-1), kopen = 0.245 U10n2 + 1.3, in close agreement with decades old tracer-based results and much lower than cubic relationships inferred from previous open ocean eddy covariance studies. In the marginal ice zone, the effective gas transfer velocity decreased in proportion to sea ice cover, in contrast with predictions of enhanced gas exchange in the presence of sea ice. The combined open water and marginal ice zone results affect the calculated magnitude and spatial distribution of Southern Ocean carbon flux.

  20. Assessing Air-Sea Interaction in the Evolving NASA GEOS Model

    NASA Technical Reports Server (NTRS)

    Clayson, Carol Anne; Roberts, J. Brent

    2015-01-01

    In order to understand how the climate responds to variations in forcing, one necessary component is to understand the full distribution of variability of exchanges of heat and moisture between the atmosphere and ocean. Surface heat and moisture fluxes are critical to the generation and decay of many coupled air-sea phenomena. These mechanisms operate across a number of scales and contain contributions from interactions between the anomalous (i.e. non-mean), often extreme-valued, flux components. Satellite-derived estimates of the surface turbulent and radiative heat fluxes provide an opportunity to assess results from modeling systems. Evaluation of only time mean and variability statistics, however only provides limited traceability to processes controlling what are often regime-dependent errors. This work will present an approach to evaluate the representation of the turbulent fluxes at the air-sea interface in the current and evolving Goddard Earth Observing System (GEOS) model. A temperature and moisture vertical profile-based clustering technique is used to identify robust weather regimes, and subsequently intercompare the turbulent fluxes and near-surface parameters within these regimes in both satellite estimates and GEOS-driven data sets. Both model reanalysis (MERRA) and seasonal-to-interannual coupled GEOS model simulations will be evaluated. Particular emphasis is placed on understanding the distribution of the fluxes including extremes, and the representation of near-surface forcing variables directly related to their estimation. Results from these analyses will help identify the existence and source of regime-dependent biases in the GEOS model ocean surface turbulent fluxes. The use of the temperature and moisture profiles for weather-state clustering will be highlighted for its potential broad application to 3-D output typical of model simulations.

  1. Sensitivity of a climatologically-driven sea ice model to the ocean heat flux

    NASA Technical Reports Server (NTRS)

    Parkinson, C. L.; Good, M. R.

    1982-01-01

    Ocean heat flux sensitivity was studied on a numerical model of sea ice covering the Weddell Sea region of the southern ocean. The model is driven by mean monthly climatological atmospheric variables. For each model run, the ocean heat flux is uniform in both space and time. Ocean heat fluxes below 20 W m to the minus 2 power do not provide sufficient energy to allow the ice to melt to its summertime thicknesses and concentrations by the end of the 14 month simulation, whereas ocean heat fluxes of 30 W m to the minus 2 power and above result in too much ice melt, producing the almost total disappearance of ice in the Weddell Sea by the end of the 14 months. These results are dependent on the atmospheric forcing fields.

  2. Biofilm-like properties of the sea surface and predicted effects on air-sea CO2 exchange

    NASA Astrophysics Data System (ADS)

    Wurl, Oliver; Stolle, Christian; Van Thuoc, Chu; The Thu, Pham; Mari, Xavier

    2016-05-01

    fluxes by up to 15%, and, therefore, play important local and regional roles in regulating air-sea interactions.

  3. Assessing benthic oxygen fluxes in oligotrophic deep sea sediments (HAUSGARTEN observatory)

    NASA Astrophysics Data System (ADS)

    Donis, Daphne; McGinnis, Daniel F.; Holtappels, Moritz; Felden, Janine; Wenzhoefer, Frank

    2016-05-01

    Benthic oxygen fluxes, an established proxy for total organic carbon mineralization, were investigated in oligotrophic deep sea sediments. We used three different in situ technologies to estimate the benthic oxygen fluxes at an Arctic deep sea site (2500 m depth, HAUSGARTEN observatory) with limiting conditions of low oxygen gradients and fluxes, low turbulence and low particle content in the benthic boundary layer. The resolved eddy covariance turbulent oxygen flux (-0.9±0.2 (SD) mmol O2 m-2 d-1) compared well with simultaneous dissolved oxygen flux measurements carried out with a microprofiler (-1.02±0.3 (SD) mmol O2 m-2 d-1) and total oxygen uptake obtained by benthic chamber incubations (-1.1±0.1 (SD) mmol O2 m-2 d-1). The agreement between these different techniques revealed that microbial-mediated oxygen consumption was dominant at this site. The average benthic flux equals a carbon mineralization rate of 4.3 g C m-2 yr-1, which exceeds the annual sedimentation of particulate organic matter measured by sediment traps. The present study represents a detailed comparison of different in situ technologies for benthic flux measurements at different spatial scales in oligotrophic deep sea sediments. The use of eddy covariance, so far rarely used for deep sea investigations, is presented in detail.

  4. Sinking Particle Flux in the Sea Ice Zone of the Amundsen Shelf, Antarctica

    NASA Astrophysics Data System (ADS)

    Kim, M.; Hwang, J.; Kim, H. J.; Kim, D.; Ducklow, H. W.; Lee, S. H.; Yang, E. J.; Lee, S.

    2014-12-01

    We have examined the flux, compositions of biogenic components, and isotopic values of sinking particles collected by a sediment trap deployed in the sea ice zone (SIZ) of the Amundsen Sea from January 2011 for one year. Major portion of the particle flux occurred during the austral summer in January and February when sea ice concentration was reduced to below 60 %. Biogenic components, dominated by opal, accounted for over 75 % during this high flux period. The dominant source of sinking particles shifted from diatoms to soft-tissued organisms, evidenced by high particulate organic carbon (POC) content (> 30 %) during the polar night. CaCO3 content and its contribution to total particle flux were low throughout the study period. Contribution of aged POC likely supplied from sediment resuspension was considerable only from October to December, evidenced by low radiocarbon content and relatively high (30-50 %) content of the non-biogenic component. When compared to POC flux inside the Amundsen Sea polynya obtained by the US Amundsen Sea Polynya International Research Expedition (ASPIRE), the POC flux integrated over the austral summer in the SIZ was virtually identical although maximum POC flux was about half that inside the Amundsen Sea polynya. This comparatively high POC flux in the SIZ may be caused by persistence of phytoplankton bloom for longer period and more efficient export of organic matter owing to the diatom-dominant plankton community. If this observation is a general phenomenon on the Amundsen shelf, the role of the SIZ compared to the polynyas need to be examined more carefully when trying to characterize the POC export in this region.

  5. Salp contributions to vertical carbon flux in the Sargasso Sea

    NASA Astrophysics Data System (ADS)

    Stone, Joshua P.; Steinberg, Deborah K.

    2016-07-01

    We developed a one-dimensional model to estimate salp contributions to vertical carbon flux at the Bermuda Atlantic Time-series Study (BATS) site in the North Atlantic subtropical gyre for a 17-yr period (April 1994 to December 2011). We based the model parameters on published rates of salp physiology and experimentally determined sinking and decomposition rates of salp carcasses. Salp grazing was low during non-bloom conditions, but routinely exceeded 100% of chlorophyll standing stock and primary production during blooms. Fecal pellet production was the largest source of salp carbon flux (78% of total), followed by respiration below 200 m (19%), sinking of carcasses (3%), and DOC excretion below 200 m (<0.1%). Thalia democratica, Salpa fusiformis, Salpa aspera, Wheelia cylindrica, and Iasis zonaria were the five highest contributors, accounting for 95% of total salp-mediated carbon flux. Seasonally, salp flux was higher during spring-summer than fall-winter, due to seasonal changes in species composition and abundance. Salp carbon export to 200 m was on average 2.3 mg C m-2 d-1 across the entire time series. This is equivalent to 11% of the mean 200 m POC flux measured by sediment traps in the region. During years with significant salp blooms, however, annually-averaged salp carbon export was the equivalent of up to 60% of trap POC flux at 200 m. Salp carbon flux attenuated slowly, and at 3200 m the average modeled carbon from salps was 109% of the POC flux measured in sediment traps at that depth. Migratory and carcass carbon export pathways should also be considered (alongside fecal pellet flux) as facilitating carbon export to sequestration depths in future studies.

  6. Poleward eddy heat flux anomalies associated with recent Arctic sea ice loss

    NASA Astrophysics Data System (ADS)

    Hoshi, Kazuhira; Ukita, Jinro; Honda, Meiji; Iwamoto, Katsushi; Nakamura, Tetsu; Yamazaki, Koji; Dethloff, Klaus; Jaiser, Ralf; Handorf, Dörthe

    2017-01-01

    Details of the characteristics of upward planetary wave propagation associated with Arctic sea ice loss under present climate conditions are examined using reanalysis data and simulation results. Recent Arctic sea ice loss results in increased stratospheric poleward eddy heat fluxes in the eastern and central Eurasia regions and enhanced upward propagation of planetary-scale waves in the stratosphere. A linear decomposition scheme reveals that this modulation of the planetary waves arises from coupling of the climatological planetary wavefield with temperature anomalies for the eastern Eurasia region and with meridional wind anomalies for the central Eurasia region. Propagation of stationary Rossby wave packets results in a dynamic link between these temperature and meridional wind anomalies with sea ice loss over the Barents-Kara Sea. The results provide strong evidence that recent Arctic sea ice loss significantly modulates atmospheric circulation in winter to modify poleward eddy heat fluxes so as to drive stratosphere-troposphere coupling processes.

  7. Improving the Bulk Formula for Sea-Surface Fluxes

    DTIC Science & Technology

    2011-03-14

    weak SST heterogeneity. J. Geophys. Res, 115, D11103,doi:10.1029/2009JD013161. Vickers D and L. Mahrt 2010: Sea-surface roughness lengths in the midlatitude coastal zone. Quart. J. Roy. Meterol. Soc. 136, 1089 -1093.

  8. Measuring and modelling the frictional velocity u*, turbulence and heat fluxes above the North Sea

    NASA Astrophysics Data System (ADS)

    Tambke, Jens; Bye, John A. T.; Schmidt, Michael; Wolff, Jörg-Olaf

    2014-05-01

    In this study, we analyse the frictional velocity u*, drag coefficient, vertical wind speed and turbulence profiles observed at different met-masts in the German North and Baltic Sea. We present an analysis of different models for the frictional velocity u* in convective, neutral and stable thermal stratification of the atmosphere. Atmospheric turbulent momentum and heat flux measurements performed with ultra-sonic anemometers are compared to profile-derived values and a bulk Richardson number formulation of the atmospheric thermal stability. Modelling: An improved approach to model the vertical wind speed profile is presented and compared against meso-scale model results (WRF, COSMO): Bye-Ekman-Coupling (BEC) describes the flux of momentum from the Ekman layer of the atmosphere through the Prandtl layer down to the air-sea interface by a modified wave boundary layer with enhanced Charnock dynamics (Bye et al. 2010). The BEC model is based on the coupled pair of similarity relations for "aerodynamically rough flow" in both fluids (air and sea). The derived drag law is of Charnock form, almost independent of the wave age and consistent with the transfer of momentum to the wave spectrum - which takes place in the smaller rather than the dominant wavelengths. Measurements: It was found that the frictional velocity u* is considerably smaller than predicted by conventional approaches using the Charnock relation: For wind speeds between 10 m/s and 15 m/s at 40 m height above the sea surface, u*(observed) is 14% smaller than u*(Charnock). Most important, we found unexpected, strong and obviously artificial distortions concerning the three wind speed components in the 10Hz data of the three ultra-sonic anemometers at the offshore met-mast FINO1 at 40 m, 60 m and 80 m height. The pattern of these distortions is independent from different post-processing procedures (planar-fit etc.). We anticipate that these artefacts imply severe problems for the eddy covariance technique

  9. Environmental Drivers of Benthic Flux Variation and Ecosystem Functioning in Salish Sea and Northeast Pacific Sediments.

    PubMed

    Belley, Rénald; Snelgrove, Paul V R; Archambault, Philippe; Juniper, S Kim

    2016-01-01

    The upwelling of deep waters from the oxygen minimum zone in the Northeast Pacific from the continental slope to the shelf and into the Salish Sea during spring and summer offers a unique opportunity to study ecosystem functioning in the form of benthic fluxes along natural gradients. Using the ROV ROPOS we collected sediment cores from 10 sites in May and July 2011, and September 2013 to perform shipboard incubations and flux measurements. Specifically, we measured benthic fluxes of oxygen and nutrients to evaluate potential environmental drivers of benthic flux variation and ecosystem functioning along natural gradients of temperature and bottom water dissolved oxygen concentrations. The range of temperature and dissolved oxygen encountered across our study sites allowed us to apply a suite of multivariate analyses rarely used in flux studies to identify bottom water temperature as the primary environmental driver of benthic flux variation and organic matter remineralization. Redundancy analysis revealed that bottom water characteristics (temperature and dissolved oxygen), quality of organic matter (chl a:phaeo and C:N ratios) and sediment characteristics (mean grain size and porosity) explained 51.5% of benthic flux variation. Multivariate analyses identified significant spatial and temporal variation in benthic fluxes, demonstrating key differences between the Northeast Pacific and Salish Sea. Moreover, Northeast Pacific slope fluxes were generally lower than shelf fluxes. Spatial and temporal variation in benthic fluxes in the Salish Sea were driven primarily by differences in temperature and quality of organic matter on the seafloor following phytoplankton blooms. These results demonstrate the utility of multivariate approaches in differentiating among potential drivers of seafloor ecosystem functioning, and indicate that current and future predictive models of organic matter remineralization and ecosystem functioning of soft-muddy shelf and slope seafloor

  10. Environmental Drivers of Benthic Flux Variation and Ecosystem Functioning in Salish Sea and Northeast Pacific Sediments

    PubMed Central

    Belley, Rénald; Snelgrove, Paul V. R.; Archambault, Philippe; Juniper, S. Kim

    2016-01-01

    The upwelling of deep waters from the oxygen minimum zone in the Northeast Pacific from the continental slope to the shelf and into the Salish Sea during spring and summer offers a unique opportunity to study ecosystem functioning in the form of benthic fluxes along natural gradients. Using the ROV ROPOS we collected sediment cores from 10 sites in May and July 2011, and September 2013 to perform shipboard incubations and flux measurements. Specifically, we measured benthic fluxes of oxygen and nutrients to evaluate potential environmental drivers of benthic flux variation and ecosystem functioning along natural gradients of temperature and bottom water dissolved oxygen concentrations. The range of temperature and dissolved oxygen encountered across our study sites allowed us to apply a suite of multivariate analyses rarely used in flux studies to identify bottom water temperature as the primary environmental driver of benthic flux variation and organic matter remineralization. Redundancy analysis revealed that bottom water characteristics (temperature and dissolved oxygen), quality of organic matter (chl a:phaeo and C:N ratios) and sediment characteristics (mean grain size and porosity) explained 51.5% of benthic flux variation. Multivariate analyses identified significant spatial and temporal variation in benthic fluxes, demonstrating key differences between the Northeast Pacific and Salish Sea. Moreover, Northeast Pacific slope fluxes were generally lower than shelf fluxes. Spatial and temporal variation in benthic fluxes in the Salish Sea were driven primarily by differences in temperature and quality of organic matter on the seafloor following phytoplankton blooms. These results demonstrate the utility of multivariate approaches in differentiating among potential drivers of seafloor ecosystem functioning, and indicate that current and future predictive models of organic matter remineralization and ecosystem functioning of soft-muddy shelf and slope seafloor

  11. Gulf of Mexico Air/Sea Interaction: Measurements and Initial Data Characterization

    NASA Astrophysics Data System (ADS)

    MacDonald, C.; Huang, C. H.; Roberts, P. T.; Bariteau, L.; Fairall, C. W.; Gibson, W.; Ray, A.

    2011-12-01

    Corporate, government, and university researchers collaborated to develop an atmospheric boundary layer environmental observations program on an offshore platform in the Gulf of Mexico. The primary goals of this project were to provide data to (1) improve our understanding of boundary layer processes and air-sea interaction over the Gulf of Mexico; (2) improve regional-scale meteorological and air quality modeling; and (3) provide a framework for advanced offshore measurements to support future needs such as emergency response, exploration and lease decisions, wind energy research and development, and meteorological and air quality forecasting. In October 2010, meteorological and oceanographic sensors were deployed for an extended period (approximately 12 months) on a Chevron service platform (ST 52B, 90.5W, 29N) to collect boundary layer and sea surface data sufficient to support these objectives. This project has significant importance given the large industrial presence in the Gulf, sizeable regional population nearby, and the recognized need for precise and timely pollutant forecasts. Observations from this project include surface meteorology; sodar marine boundary layer winds; microwave radiometer profiles of temperature, relative humidity, and liquid water; ceilometer cloud base heights; water temperature and current profiles; sea surface temperature; wave height statistics; downwelling solar and infrared radiation; and air-sea turbulent momentum and heat fluxes. This project resulted in the collection of an unprecedented set of boundary layer measurements over the Gulf of Mexico that capture the range of meteorological and oceanographic interactions and processes that occur over an entire year. This presentation will provide insight into the logistical and scientific issues associated with the deployment and operations of unique measurements in offshore areas and provide results from an initial data analysis of boundary layer processes over the Gulf of

  12. Indirect air-sea interactions simulated with a coupled turbulence-resolving model

    NASA Astrophysics Data System (ADS)

    Esau, Igor

    2014-05-01

    A turbulence-resolving parallelized atmospheric large-eddy simulation model (PALM) has been applied to study turbulent interactions between the humid atmospheric boundary layer (ABL) and the salt water oceanic mixed layer (OML). The most energetic three-dimensional turbulent eddies in the ABL-OML system (convective cells) were explicitly resolved in these simulations. This study considers a case of shear-free convection in the coupled ABL-OML system. The ABL-OML coupling scheme used the turbulent fluxes at the bottom of the ABL as upper boundary conditions for the OML and the sea surface temperature at the top of the OML as lower boundary conditions for the ABL. The analysis of the numerical experiment confirms that the ABL-OML interactions involve both the traditional direct coupling mechanism and much less studied indirect coupling mechanism (Garrett Dyn Atmos Ocean 23:19-34, 1996). The direct coupling refers to a common flux-gradient representation of the air-sea exchange, which is controlled by the temperature difference across the air-water interface. The indirect coupling refers to thermal instability of the Rayleigh-Benard convection, which is controlled by the temperature difference across the entire mixed layer through formation of the large convective eddies or cells. The indirect coupling mechanism in these simulations explained up to 45 % of the ABL-OML co-variability on the turbulent scales. Despite relatively small amplitude of the sea surface temperature fluctuations, persistence of the OML cells organizes the ABL convective cells. Water downdrafts in the OML cells tend to be collocated with air updrafts in the ABL cells. The study concludes that the convective structures in the ABL and the OML are co-organized. The OML convection controls the air-sea turbulent exchange in the quasi-equilibrium convective ABL-OML system.

  13. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Meixner, Franz X.; Vrana, Branislav; Efstathiou, Christos I.; Kohoutek, Jiři; Kukučka, Petr; Mulder, Marie D.; Přibylová, Petra; Prokeš, Roman; Rusina, Tatsiana P.; Song, Guo-Zheng; Tsapakis, Manolis

    2016-05-01

    As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Δc/Δz > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8 µg m-2 day-1 for PAHs and -3.4 to +0.9 µg m-2 day-1 for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.

  14. Air-Sea Interaction Spar Buoy Systems

    DTIC Science & Technology

    2009-01-01

    properties and local slope and pressure above the waves are key to understanding the wave generation problem on the ocean. Ocean Turbulence: Hot wire ...staff wires in storm-forced sea states. APPROACH We are building on the previous success of the ASIS buoy and better state-of-the-art...film anemometry has a special place in fluid dynamics research, but they cannot be easily deployed in open ocean conditions. On the other hand

  15. Air-sea interaction measurements in the west Mediterranean Sea during the Tyrrhenian Eddy Multi-Platform Observations Experiment

    SciTech Connect

    Schiano, M.E.; Santoleri, R.; Bignami, F.; Leonardi, R.M. ); Marullo, S. ); Boehm, E. )

    1993-02-15

    Measurements of radiative fluxes were carried out in the Tyrrhenian Sea in fall and winter as part of the Tyrrhenian Eddy Multi-Platform Observations Experiment (TEMPO). These measurements have supplied the first experimental radiation data set over this basin. Seasonal variation of the different components of the budget are investigated. Since data collection was carried out in an area in which a quasi-permanent eddy is present, the behavior of the radiation parameters across the frontal zone is analyzed. The most interesting result of the air-sea interaction in proximity of a marine front consists in the covariation of sea surface temperature and downwelling long-wave radiation. Contemporaneous satellite data show a clear correlation between sea surface structure and horizontal distribution of columnar atmospheric water content. Therefore this inhomogeneity clearly is one of the main factors responsible for the variation of the downwelling radiation across the front. A comparison between experimental data and results of some of the most widely used bulk formulae is carried out for both short- and long-wave radiation. The mean differnece between measured and empirical solar radiation values is less than 3%, while in the case of the net long-wave radiation budge, poor agreement is found. Indeed, a 30 W/m[sup 2] bias results from the comparison. This discrepancy is consistent with the imbalance between previous bulk calculations of total heat budget at the surface and corresponding hydrographical observations of heat exchange at Gibraltar. 30 refs., 6 figs., 9 tabs.

  16. Impacts of Air-Sea Interaction on Tropical Cyclone Track and Intensity

    NASA Technical Reports Server (NTRS)

    Wu, Liguang; Wang, Bin; Braun, Scott A.

    2004-01-01

    The influence of hurricane-ocean coupling on intensity and track of tropical cyclones (TCs) is investigated through idealized numerical experiments using a coupled hurricane-ocean model. The focus is placed on how air-sea interaction affects TC tracks and intensity. It is found that the symmetric sea surface temperature (SST) cooling is primarily responsible for the TC weakening in the coupled experiments because the induced asymmetric circulation associated with the asymmetric SST anomalies is weak and shallow. The track difference between the coupled and fixed SST experiments is generally small because of the competing processes. One is associated with the modified TC asymmetries. The asymmetric SST anomalies - weaken the surface fluxes in the rear and enhance the fluxes in the front. As a result, the enhanced diabatic heating is located on the southern side for a westward-moving TC, tending to shift the TC southward. The symmetric SST anomalies weakens the TC intensity and thus the dymmetrization process, leading to more prominent TC asymmetries. The other is associated with the weakening of the beta drift resulting from the weakening of the TC outer strength. In the coupled experiment, the weakening of the beta drift leads to a more northward shift. By adjusting the vortex outer strength of the initial vortices, the beta drift can vary while the effect of air-sea interaction changes little. Two types of track differences simulated in the previous numerical studies are obtained.

  17. Snowflake Impact on the Air-Sea Interface

    NASA Astrophysics Data System (ADS)

    Murphy, David

    2016-11-01

    The air-sea interface is the site of globally important exchanges of mass, momentum, and heat between the sea and atmosphere. These climate-driving exchanges occur through small-scale processes such as bubble entrainment and bursting, raindrop impact, and wind-wave creation. The physics of snowflakes falling on the sea surface has not been previously considered. High speed imaging of natural snowflakes of characteristic size up to 6.5 mm falling at a mean speed of 1 m/s into an aquarium of chilled seawater reveals a complex multiphase flow. Snowflakes impacting and crossing the air-seawater interface appear to entrain a thin air film which forms micro-bubbles as the snowflake melts. Large, morphologically complex snowflakes may entrain hundreds of micro-bubbles which are up to 0.15 mm in diameter. Large snowflakes melt milliseconds after entry and subsequently form a downward-moving vortex ring of freshwater, evident from the motion of the bubbles it contains, which may penetrate up to 16 mm below the surface. Buoyant freshwater and bubbles then rise, with larger bubbles escaping from the downward flow more quickly than the smaller bubbles. The dissolution and popping of these bubbles represent previously unrecognized sources of air-sea gas transfer and marine aerosol droplet creation, respectively.

  18. Operationalizing Air-Sea Battle in the Pacific

    DTIC Science & Technology

    2015-02-01

    systems. 35. Chris Anderson, " Agricultural Drones ,• MIT ’Technology Review 117, no. 3 (May/June 2014): 58. 36. Van Thl et al., AirSea Battle: A Point...communications are re- established. These systems are vulnerable to antiair weapons; how- ever, 11relatively cheap drones with advanced sensors and

  19. AIRS Sea Surface Temperature and Pacific Decadal Oscillation

    NASA Astrophysics Data System (ADS)

    Chen, L. L.

    2015-12-01

    Atmospheric Infrared Sounder (AIRS) has been providing necessary measurements for long term atmospheric and surface processes aboard NASA' s Aqua polar orbiter since May 2002. Here, we use time series of AIRS sea surface temperature (SST) anomalies to show the time evolution of Pacific Decadal Oscillation (PDO) in the Gulf of Alaska (lon:-144.5, lat:54.5) from 2003 to 2014. PDO is connected to the first mode of North Pacific SST variability and is tele-connected to ENSO in the tropics. Further analysis of AIRS data can provide clarification of Pacific climate variability.

  20. Recent increases in Arctic freshwater flux affects Labrador Sea convection and Atlantic overturning circulation.

    PubMed

    Yang, Qian; Dixon, Timothy H; Myers, Paul G; Bonin, Jennifer; Chambers, Don; van den Broeke, M R

    2016-01-22

    The Atlantic Meridional Overturning Circulation (AMOC) is an important component of ocean thermohaline circulation. Melting of Greenland's ice sheet is freshening the North Atlantic; however, whether the augmented freshwater flux is disrupting the AMOC is unclear. Dense Labrador Sea Water (LSW), formed by winter cooling of saline North Atlantic water and subsequent convection, is a key component of the deep southward return flow of the AMOC. Although LSW formation recently decreased, it also reached historically high values in the mid-1990s, making the connection to the freshwater flux unclear. Here we derive a new estimate of the recent freshwater flux from Greenland using updated GRACE satellite data, present new flux estimates for heat and salt from the North Atlantic into the Labrador Sea and explain recent variations in LSW formation. We suggest that changes in LSW can be directly linked to recent freshening, and suggest a possible link to AMOC weakening.

  1. Recent increases in Arctic freshwater flux affects Labrador Sea convection and Atlantic overturning circulation

    NASA Astrophysics Data System (ADS)

    Yang, Qian; Dixon, Timothy H.; Myers, Paul G.; Bonin, Jennifer; Chambers, Don; van den Broeke, M. R.

    2016-01-01

    The Atlantic Meridional Overturning Circulation (AMOC) is an important component of ocean thermohaline circulation. Melting of Greenland's ice sheet is freshening the North Atlantic; however, whether the augmented freshwater flux is disrupting the AMOC is unclear. Dense Labrador Sea Water (LSW), formed by winter cooling of saline North Atlantic water and subsequent convection, is a key component of the deep southward return flow of the AMOC. Although LSW formation recently decreased, it also reached historically high values in the mid-1990s, making the connection to the freshwater flux unclear. Here we derive a new estimate of the recent freshwater flux from Greenland using updated GRACE satellite data, present new flux estimates for heat and salt from the North Atlantic into the Labrador Sea and explain recent variations in LSW formation. We suggest that changes in LSW can be directly linked to recent freshening, and suggest a possible link to AMOC weakening.

  2. Recent increases in Arctic freshwater flux affects Labrador Sea convection and Atlantic overturning circulation

    PubMed Central

    Yang, Qian; Dixon, Timothy H.; Myers, Paul G.; Bonin, Jennifer; Chambers, Don; van den Broeke, M. R.; Ribergaard, Mads H.; Mortensen, John

    2016-01-01

    The Atlantic Meridional Overturning Circulation (AMOC) is an important component of ocean thermohaline circulation. Melting of Greenland's ice sheet is freshening the North Atlantic; however, whether the augmented freshwater flux is disrupting the AMOC is unclear. Dense Labrador Sea Water (LSW), formed by winter cooling of saline North Atlantic water and subsequent convection, is a key component of the deep southward return flow of the AMOC. Although LSW formation recently decreased, it also reached historically high values in the mid-1990s, making the connection to the freshwater flux unclear. Here we derive a new estimate of the recent freshwater flux from Greenland using updated GRACE satellite data, present new flux estimates for heat and salt from the North Atlantic into the Labrador Sea and explain recent variations in LSW formation. We suggest that changes in LSW can be directly linked to recent freshening, and suggest a possible link to AMOC weakening. PMID:26796579

  3. Using a video-corer to evaluate hydrocarbon fluxes in the northern South China Sea

    NASA Astrophysics Data System (ADS)

    Hung, C. C.; Wang, C. C.; Chen, H. H.; Lin, Y. S.; Huang, K. H.

    2015-12-01

    Many natural methane seeps exist in the northern South China Sea. Researchers have often used gravity corers or piston corers to collect sediments and bottom seawater for estimating methane fluxes of these seeps. The actual sampling locations of these corers are difficult to match seeping vents detected by scientific echo sounder because of the difficulty in positioning of these corers when sampling at sea,. Thus, the hydrocarbon fluxes of the seeping vents estimated using these corers might not be representative hydrocarbon fluxes of seeping vents in the northern South China Sea. In this study, we used a real-time video multicorer to collect surface sediments and bottom seawater samples. This real-time multicorer can accurately obtain surface sediments and bottom seawater samples on hydrocarbon seeping vents. To estimate hydrocarbon diffusion fluxes of seeps in the northern South China Sea, we analyzed methane concentrations and carbon isotopes of methane in both porewater and bottom seawater. During the cruises conducted from August to December, 2014, methane fluxes in the study area ranged from 3 to 57000 μmol m-2 d-1 which are significantly higher than previously reported values (~160 μmol m-2 d-1). Besides, we have obtained some samples in the study area using real-time multicorer in 2015. These new results will be presented in the meeting. Overall, the observed result in this study suggests that the in-situ multicorer can be a suitable instrument sampling surface sediments and bottom seawater samples on hydrocarbon seeping vents.

  4. Modeling Biogeochemical-Physical Interactions and Carbon Flux in the Sargasso Sea (Bermuda Atlantic Time-series Study site)

    NASA Technical Reports Server (NTRS)

    Signorini, Sergio R.; McClain, Charles R.; Christian, James R.

    2001-01-01

    An ecosystem-carbon cycle model is used to analyze the biogeochemical-physical interactions and carbon fluxes in the Bermuda Atlantic Time-series Study (BATS) site for the period of 1992-1998. The model results compare well with observations (most variables are within 8% of observed values). The sea-air flux ranges from -0.32 to -0.50 mol C/sq m/yr, depending upon the gas transfer algorithm used. This estimate is within the range (-0.22 to -0.83 mol C/sq m/yr) of previously reported values which indicates that the BATS region is a weak sink of atmospheric CO2. The overall carbon balance consists of atmospheric CO2 uptake of 0.3 Mol C/sq m/yr, upward dissolved inorganic carbon (DIC) bottom flux of 1.1 Mol C/sq m/yr, and carbon export of 1.4 mol C/sq m/yr via sedimentation. Upper ocean DIC levels increased between 1992 and 1996 at a rate of approximately 1.2 (micro)mol/kg/yr, consistent with observations. However, this trend was reversed during 1997-1998 to -2.7 (micro)mol/kg/yr in response to hydrographic changes imposed by the El Nino-La Nina transition, which were manifested in the Sargasso Sea by the warmest SST and lowest surface salinity of the period (1992-1998).

  5. Evaluation of the swell effect on the air-sea gas transfer in the coastal zone

    NASA Astrophysics Data System (ADS)

    Gutiérrez-Loza, Lucía; Ocampo-Torres, Francisco J.

    2016-04-01

    Air-sea gas transfer processes are one of the most important factors regarding global climate and long-term global climate changes. Despite its importance, there is still a huge uncertainty on how to better parametrize these processes in order to include them on the global climate models. This uncertainty exposes the need to increase our knowledge on gas transfer controlling mechanisms. In the coastal regions, breaking waves become a key factor to take into account when estimating gas fluxes, however, there is still a lack of information and the influence of the ocean surface waves on the air-sea interaction and gas flux behavior must be validated. In this study, as part of the "Sea Surface Roughness as Air-Sea Interaction Control" project, we evaluate the effect of the ocean surface waves on the gas exchange in the coastal zone. Direct estimates of the flux of CO2 (FCO2) and water vapor (FH2O) through eddy covariance, were carried out from May 2014 to April 2015 in a coastal station located at the Northwest of Todos Santos Bay, Baja California, México. For the same period, ocean surface waves are recorded using an Acoustic Doppler Current Profiler (Workhorse Sentinel, Teledyne RD Instruments) with a sampling rate of 2 Hz and located at 10 m depth about 350 m away from the tower. We found the study area to be a weak sink of CO2 under moderate wind and wave conditions with a mean flux of -1.32 μmol/m2s. The correlation between the wind speed and FCO2 was found to be weak, suggesting that other physical processes besides wind may be important factors for the gas exchange modulation at coastal waters. The results of the quantile regression analysis computed between FCO2 and (1) wind speed, (2) significant wave height, (3) wave steepness and (4) water temperature, show that the significant wave height is the most correlated parameter with FCO2; Nevertheless, the behavior of their relation varies along the probability distribution of FCO2, with the linear regression

  6. Surfactant control of air-sea gas exchange across contrasting biogeochemical regimes

    NASA Astrophysics Data System (ADS)

    Pereira, Ryan; Schneider-Zapp, Klaus; Upstill-Goddard, Robert

    2014-05-01

    Air-sea gas exchange is important to the global partitioning of CO2.Exchange fluxes are products of an air-sea gas concentration difference, ΔC, and a gas transfer velocity, kw. The latter is controlled by the rate of turbulent diffusion at the air-sea interface but it cannot be directly measured and has a high uncertainty that is now considered one of the greatest challenges to quantifying net global air-sea CO2 exchange ...(Takahashi et al., 2009). One important control on kw is exerted by sea surface surfactants that arise both naturally from biological processes and through anthropogenic activity. They influence gas exchange in two fundamental ways: as a monolayer physical barrier and through modifying sea surface hydrodynamics and hence turbulent energy transfer. These effects have been demonstrated in the laboratory with artificial surfactants ...(Bock et al., 1999; Goldman et al., 1988) and through purposeful surfactant releases in coastal waters .(.).........().(Brockmann et al., 1982) and in the open ocean (Salter et al., 2011). Suppression of kwin these field experiments was ~5-55%. While changes in both total surfactant concentration and the composition of the natural surfactant pool might be expected to impact kw, the required in-situ studies are lacking. New data collected from the coastal North Sea in 2012-2013 shows significant spatio-temporal variability in the surfactant activity of organic matter within the sea surface microlayer that ranges from 0.07-0.94 mg/L T-X-100 (AC voltammetry). The surfactant activities show a strong winter/summer seasonal bias and general decrease in concentration with increasing distance from the coastline possibly associated with changing terrestrial vs. phytoplankton sources. Gas exchange experiments of this seawater using a novel laboratory tank and gas tracers (CH4 and SF6) demonstrate a 12-45% reduction in kw compared to surfactant-free water. Seasonally there is higher gas exchange suppression in the summer

  7. Sea ice-atmospheric interaction: Application of multispectral satellite data in polar surface energy flux estimates

    NASA Technical Reports Server (NTRS)

    Steffen, Konrad; Key, J.; Maslanik, J.; Schweiger, A.

    1993-01-01

    This is the third annual report on: Sea Ice-Atmosphere Interaction - Application of Multispectral Satellite Data in Polar Surface Energy Flux Estimates. The main emphasis during the past year was on: radiative flux estimates from satellite data; intercomparison of satellite and ground-based cloud amounts; radiative cloud forcing; calibration of the Advanced Very High Resolution Radiometer (AVHRR) visible channels and comparison of two satellite derived albedo data sets; and on flux modeling for leads. Major topics covered are arctic clouds and radiation; snow and ice albedo, and leads and modeling.

  8. A conceptual model of ocean freshwater flux derived from sea surface salinity

    NASA Astrophysics Data System (ADS)

    Nieves, V.; Wang, J.; Willis, J. K.

    2014-09-01

    A conceptual model is proposed to express freshwater flux (evaporation minus precipitation) as a function of sea surface salinity (and vice versa). The model is formulated using an idealized one-dimensional diffusion equation for the ocean surface layer. It is shown to provide good agreement with existing freshwater flux estimates and salinity observations. It also has the potential to enhance our capability of monitoring and modeling global freshwater fluxes and salinity as a data retrieval algorithm for remote sensing. The model may improve physical parameterization in coupled ocean-atmosphere models to study the global water cycle.

  9. Air-borne sound generated by sea waves.

    PubMed

    Bolin, Karl; Åbom, Mats

    2010-05-01

    This paper describes a semi-empiric model and measurements of air-borne sound generated by breaking sea waves. Measurements have been performed at the Baltic Sea. Shores with different slopes and sediment types have been investigated. Results showed that the sound pressure level increased from 60 dB at 0.4 m wave height to 78 dB at 2.0 m wave height. The 1/3 octave spectrum was dependent on the surf type. A scaling model based on the dissipated wave power and a surf similarity parameter is proposed and compared to measurements. The predictions show satisfactory agreement to the measurements.

  10. Evolution and fluxes of 137Cs in the Black Sea/Turkish Straits System/North Aegean Sea

    NASA Astrophysics Data System (ADS)

    Delfanti, R.; Özsoy, E.; Kaberi, H.; Schirone, A.; Salvi, S.; Conte, F.; Tsabaris, C.; Papucci, C.

    2014-07-01

    The vertical profiles of 137Cs were determined in the North Aegean, Marmara and Black Seas, to assess inventories and fluxes of the radionuclide in these basins. The inventory of 137Cs in the Western Black Sea integrated from the surface down to 400 m water depth is 3.4 ± 0.1 kBq m- 2, which is surprisingly close to the amount determined in 1988, decay corrected to 2007 (2.9 ± 0.1 kBq m- 2). On the other hand, based on the comparison of profiles roughly 20 years apart, it is estimated that about 1 kBq m- 2 has been transferred from above the halocline to depths below the halocline, emphasizing the effective redistribution of tracers within the same period. We estimate that about 12 TBq y- 1 of 137Cs presently leaves the Black Sea with the upper layer flow through the Bosphorus and only 2 TBq y- 1 is returned with the lower layer inflow of Mediterranean water from the Marmara Sea. Accounting for river fluxes, estimated on the order of 2 TBq y- 1 few years after the Chernobyl accident, and possibly decreased by now, we can thus estimate a net rate of loss of about 8-10 TBq y- 1. Investigating the effective redistribution in the upper water column, the supply by the inflowing Mediterranean water alone does not explain the increase of 137Cs concentration and inventory at intermediate depths in the Western Black Sea. The most important mechanism transferring 137Cs and dissolved contaminants from the surface water to the sub-pycnocline layer appears to be the turbulent entrainment of a larger quantity of Black Sea water into the inflowing plume of Mediterranean water through mixing processes on the southwestern shelf and continental slope following its exit from the Bosphorus. This process produces an extra export of some10 TBq y- 1 of 137Cs from the surface to the sub-pycnocline depths of the Black Sea, a quantity comparable in magnitude to the total export out from the basin. It is the entrainment flux resulting from the mixing, and the further advection and

  11. Air-Sea Exchange and Budget of Sulfur and Oxygen-Containing Volatile Organic Compounds in the Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Tanimoto, H.; Omori, Y.; Inomata, S.; Iwata, T.; Kameyama, S.

    2015-12-01

    By combining proton transfer reaction-mass spectrometry (PTR-MS) and gradient flux (GF) technique, in situ measurement of air-sea fluxes of multiple volatile organic compounds (VOCs) was developed and deployed. Starting in 2008, we made in situ observations of air-sea fluxes at 15 locations as well as underway observations of marine air/surface seawater bulk concentrations in the Pacific Ocean, during eight research cruises by R/V Hakuho-Maru. The fluxes of biogenic trace gases, DMS and isoprene, were always positive, with the magnitudes being in accordance with previously reported. In contrast, the fluxes of oxygenated VOCs including acetone and acetaldehyde varied from negative to positive, suggesting that the tropical and subtropical Pacific are a source, while the North Pacific is a sink. A basin-scale budget of VOCs were determined for 4 biogeochemical provinces in the Pacific Ocean, and the role of oceans for VOCs were discussed with respect to physical and biogeochemical processes.

  12. Effect of wind tunnel air velocity on VOC flux rates from CAFO manure and wastewater

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Wind tunnels and flux chambers are often used to estimate volatile organic compound (VOC) emissions from animal feeding operations (AFOs) without regard to air velocity or sweep air flow rates. Laboratory experiments were conducted to evaluate the effect of wind tunnel air velocity on VOC emission ...

  13. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    PubMed Central

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-01-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change. PMID:27435531

  14. Using rare earth elements to constrain particulate organic carbon flux in the East China Sea.

    PubMed

    Hung, Chin-Chang; Chen, Ya-Feng; Hsu, Shih-Chieh; Wang, Kui; Chen, Jian Feng; Burdige, David J

    2016-09-27

    Fluxes of particulate organic carbon (POC) in the East China Sea (ECS) have been reported to decrease from the inner continental shelf towards the outer continental shelf. Recent research has shown that POC fluxes in the ECS may be overestimated due to active sediment resuspension. To better characterize the effect of sediment resuspension on particle fluxes in the ECS, rare earth elements (REEs) and organic carbon (OC) were used in separate two-member mixing models to evaluate trap-collected POC fluxes. The ratio of resuspended particles from sediments to total trap-collected particles in the ECS ranged from 82-94% using the OC mixing model, and 30-80% using the REEs mixing model, respectively. These results suggest that REEs may be better proxies for sediment resuspension than OC in high turbidity marginal seas because REEs do not appear to undergo degradation during particle sinking as compared to organic carbon. Our results suggest that REEs can be used as tracers to provide quantitative estimates of POC fluxes in marginal seas.

  15. Using rare earth elements to constrain particulate organic carbon flux in the East China Sea

    PubMed Central

    Hung, Chin-Chang; Chen, Ya-Feng; Hsu, Shih-Chieh; Wang, Kui; Chen, Jian Feng; Burdige, David J.

    2016-01-01

    Fluxes of particulate organic carbon (POC) in the East China Sea (ECS) have been reported to decrease from the inner continental shelf towards the outer continental shelf. Recent research has shown that POC fluxes in the ECS may be overestimated due to active sediment resuspension. To better characterize the effect of sediment resuspension on particle fluxes in the ECS, rare earth elements (REEs) and organic carbon (OC) were used in separate two-member mixing models to evaluate trap-collected POC fluxes. The ratio of resuspended particles from sediments to total trap-collected particles in the ECS ranged from 82–94% using the OC mixing model, and 30–80% using the REEs mixing model, respectively. These results suggest that REEs may be better proxies for sediment resuspension than OC in high turbidity marginal seas because REEs do not appear to undergo degradation during particle sinking as compared to organic carbon. Our results suggest that REEs can be used as tracers to provide quantitative estimates of POC fluxes in marginal seas. PMID:27670426

  16. Sea surface temperature anomalies, planetary waves, and air-sea feedback in the middle latitudes

    NASA Technical Reports Server (NTRS)

    Frankignoul, C.

    1985-01-01

    Current analytical models for large-scale air-sea interactions in the middle latitudes are reviewed in terms of known sea-surface temperature (SST) anomalies. The scales and strength of different atmospheric forcing mechanisms are discussed, along with the damping and feedback processes controlling the evolution of the SST. Difficulties with effective SST modeling are described in terms of the techniques and results of case studies, numerical simulations of mixed-layer variability and statistical modeling. The relationship between SST and diabatic heating anomalies is considered and a linear model is developed for the response of the stationary atmosphere to the air-sea feedback. The results obtained with linear wave models are compared with the linear model results. Finally, sample data are presented from experiments with general circulation models into which specific SST anomaly data for the middle latitudes were introduced.

  17. Temporal variations in air-sea CO2 exchange near large kelp beds near San Diego, California

    NASA Astrophysics Data System (ADS)

    Ikawa, Hiroki; Oechel, Walter C.

    2015-01-01

    study presents nearly continuous air-sea CO2 flux for 7 years using the eddy covariance method for nearshore water near San Diego, California, as well as identifying environmental processes that appear to control temporal variations in air-sea CO2 flux at different time scales using time series decomposition. Monthly variations in CO2 uptake are shown to be positively influenced by photosynthetically active photon flux density (PPFD) and negatively related to wind speeds. In contrast to the monthly scale, wind speeds often influenced CO2 uptake positively on an hourly scale. Interannual variations in CO2 flux were not correlated with any independent variables, but did reflect surface area of the adjacent kelp bed in the following year. Different environmental influences on CO2 flux at different temporal scales suggest the importance of long-term flux monitoring for accurately identifying important environmental processes for the coastal carbon cycle. Overall, the study area was a strong CO2 sink into the sea (CO2 flux of ca. -260 g C m-2 yr-1). If all coastal areas inhabited by macrophytes had a similar CO2 uptake rate, the net CO2 uptake from these areas alone would roughly equal the net CO2 sink estimated for the entire global coastal ocean to date. A similar-strength CO2 flux, ranging between -0.09 and -0.01 g C m-2 h-1, was also observed over another kelp bed from a pilot study of boat-based eddy covariance measurements.

  18. Including latent and sensible heat fluxes from sea spray in global weather and climate models

    NASA Astrophysics Data System (ADS)

    Copsey, Dan

    2016-04-01

    Most standard weather and climate models calculate interfacial latent (evaporation) and sensible heat fluxes over the ocean based on parameterisations of atmospheric turbulence, using the wave state only in the calculation of surface roughness length. They ignore latent and sensible heat fluxes generated by sea spray, which is an acceptable assumption at low wind speeds. However at high wind speeds (> 15 m/s) a significant amount of sea spray is generated from the sea surface which, while airborne, cools to an equilibrium temperature, absorbs heat and releases moisture before re-impacting the sea surface. This could impact, for example, the total heat loss from the Southern Ocean (which is anomalously warm in Met Office coupled models) or the accuracy of tropical cyclone forecasts. A modified version of the Fairall sea spray parameterisation scheme has been tested in the Met Office Unified Model including the JULES surface exchange model in both climate and NWP mode. The fast part of the scheme models the temperature change of the droplets to an equilibrium temperature and the slow part of the scheme models the evaporation and heat absorption while the droplets remain airborne. Including this scheme in the model cools and moistens the near surface layers of the atmosphere during high wind events, including tropical cyclones. Sea spray goes on to increase the convection intensity and precipitation near the high wind events in the model.

  19. Eutrophication in the northern Adriatic Sea: Benthic fluxes and nutrient budgets

    SciTech Connect

    Berelson, W.M.; Hammond, D.E. ); Giordani, P. )

    1990-01-09

    The northern Adriatic Sea has been plagued by problems of eutrophication. This area is relatively shallow (maximum depth = 60m), becoming stratified during the summer months which inhibits oxygen transport to bottom waters. Anthropogenic nutrient loading in rivers entering the northern Adriatic has increased nutrient input to this system and stimulated algai growth. Five stations in the western Adriatic (south of the Po River Delta) were occupied during September, 1988 and benthic flux chambers used to measure nutrient fluxes. These sites included 3 stations previously studied in 1982. Flux measurements of dissolved silica, nitrate, oxygen, ammonia, phosphate, CO[sub 2], alkalinity and radon were made during 24 hour incubations of flux chambers (area covered - 0.07 m[sup 2], volume = [approximately]81) that were continuously stirred and sampled periodically. Nutrient fluxes measured were generally consistent with the fluxes measured previously in June, 1982 except for radon fluxes which were 203 times greater in the earlier field season. There was a general trend in nutrient fluxes to decrease offshore, a pattern probably controlled by the sedimentation patterns because fine grained, organic matter-rich sediment are concentrated in a zone near shore. Average regional fluxes were (in mmol m[sup -2]d[sup -1], negative values indicate flux into sediment): Oxygen (-12), CO[sub 2] (19), Alkalinity (4), Silica (3.3), Ammonia (1.5), Phosphate (0.1) and Nitrate (0.3). The carbon/ammonia flux ratio is about twice the C/N ratio in marine phytoplankton, suggesting that large amounts of denitrification may be occuring in these sediments. Comparisons of benthic fluxes and sediment burial rates indicate that 50-90% of the carbon, silica, phosphorus and nitrogen arriving at the sediment-water interface is recycled before burial. The nutrient input to the water column from NW Adriatic sediments is about equal to the input from coastal rivers.

  20. A stability dependent theory for air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Erickson, David J.

    1993-05-01

    The influence of thermal stability at the air-sea interface on computed values of the transfer velocities of trace gases is examined. The novel "whitecap" model for air-sea gas exchange of Monahan and Spillane (1984), extended here to include thermal stability effects, is linked with an atmospheric general circulation model to compute global transfer velocity patterns of a climate reactive gas, CO2. The important terms in the model equations such as the whitecap coverage, friction velocity, neutral and local drag coefficients and the stability parameter ψm(Z/L) are discussed and analyzed. The atmospheric surface level air temperature, relative humidity, wind speed and sea surface temperature, obtained from the National Center for Atmospheric Research Community Climate Model 1 (CCM1) are used to drive algorithms describing the air-sea transfer velocity of trace gases. The transfer velocity for CO2 (kCO2) is then computed for each 2.8° × 2.8° latitudinal-longitudinal area every 24 hours for 5 years of the seasonal-hydro runs of the CCM1. The new model results are compared to previously proposed formulations using the identical CCM1 forcing terms. Air-sea thermal stability effects on the transfer velocity for CO2 are most important at mid-high wind speeds. Where cold air from continental interiors is transported over relatively warm oceanic waters, the transfer velocities are enhanced over neutral stability values. The depression of computed kCO2 values when warm air resides over cold water is especially important, due to asymmetry in the stability dependence of the drag coefficient. The stability influence is 20% to 50% of kCO2 for modest air-sea temperature differences and up to 100% for extreme cases of stability or instability. The stability dependent "whitecap" model, using the transfer velocity coefficients for whitecap and nonwhitecap areas suggested by Monahan and Spillane (1984), produces CO2 transfer velocities that range from 13 to 50 cm h-1 for a

  1. Theoretical model for diffusive greenhouse gas fluxes estimation across water-air interfaces measured with the static floating chamber method

    NASA Astrophysics Data System (ADS)

    Xiao, Shangbin; Wang, Chenghao; Wilkinson, Richard Jeremy; Liu, Defu; Zhang, Cheng; Xu, Wennian; Yang, Zhengjian; Wang, Yuchun; Lei, Dan

    2016-07-01

    Aquatic systems are sources of greenhouse gases on different scales, however the uncertainty of gas fluxes estimated using popular methods are not well defined. Here we show that greenhouse gas fluxes across the air-water interface of seas and inland waters are significantly underestimated by the currently used static floating chamber (SFC) method. We found that the SFC CH4 flux calculated with the popular linear regression (LR) on changes of gas concentration over time only accounts for 54.75% and 35.77% of the corresponding real gas flux when the monitoring periods are 30 and 60 min respectively based on the theoretical model and experimental measurements. Our results do manifest that nonlinear regression models can improve gas flux estimations, while the exponential regression (ER) model can give the best estimations which are close to true values when compared to LR. However, the quadratic regression model is proved to be inappropriate for long time measurements and those aquatic systems with high gas emission rate. The greenhouse gases effluxes emitted from aquatic systems may be much more than those reported previously, and models on future scenarios of global climate changes should be adjusted accordingly.

  2. Decadal and annual changes in biogenic opal and carbonate fluxes to the deep Sargasso Sea

    USGS Publications Warehouse

    Deuser, W.G.; Jickells, T.D.; Commeau, Judith A.

    1995-01-01

    Analyses of samples from a 14-year series of sediment-trap deployments in the deep Sargasso Sea reveal a significant trend in the ratio of the sinking fluxes of biogenic calcium carbonate and silica. Although there are pronounced seasonal cycles for both flux components, the overall opal/CaCO3 ratio changed by 50% from 1978 to 1991 (largely due to a decrease of opal flux), while total flux had no significant trend. These results suggest that plankton communities respond rapidly to subtle climate change, such as is evident in regional variations of wind speed, precipitation, wintertime ventilation and midwater temperatures. If the trends we observe in the makeup of sinking particulate matter occur on a large scale, they may in turn modify climate by modulating ocean-atmosphere CO2 exchange and albedo over the ocean.

  3. Tidal elevation, current and energy flux in the area between the South China Sea and Java Sea

    NASA Astrophysics Data System (ADS)

    Wei, Z. X.; Fang, G. H.; Susanto, R. D.; Adi, T. R.; Fan, B.; Setiawan, A.; Li, S. J.; Wang, Y. G.; Gao, X. M.

    2015-11-01

    The South China Sea (SCS) and the Java Sea (JS) are connected through the Karimata Strait, Gaspar Strait, and the southern Natuna Sea, where the tides are often used as open boundary condition for tidal simulation in the SCS or Indonesian seas. Tides, tidal currents and tidal energy fluxes of the principle constituents K1, O1, Q1, M2, S2 and N2 at five stations in this area have been analyzed using in-situ observational data. The results show that the diurnal tides are the dominant constituents in the entire study area. The constituent K1 has the largest amplitude, exceeding 50 cm, whereas the amplitudes of M2 are smaller than 5 cm at all stations. The amplitudes of S2 may exceed M2 in Karimata and Gaspar Straits. Tidal currents are mostly of rectilinear type in this area. The major semi axis lengths of the diurnal tidal current ellipses are about 10 cm s-1, and those of the semi-diurnal tidal currents are smaller than 5 cm s-1. The diurnal tidal energy flows from the SCS to the JS. The semi-diurnal tidal energy flows from the SCS to the JS through the Karimata Strait and the eastern part of the southern Natuna Sea but flows in the opposite direction in the Gaspar Strait and the western part of the southern Natuna Sea. Harmonic analysis of sea level and current observation also suggest that the study area is located in the loop band of the diurnal tidal waves, and in the nodal band of the semi-diurnal tidal waves. Comparisons show that the existing models are basically consistent with the observational results, but further improvements are necessary.

  4. Tidal elevation, current, and energy flux in the area between the South China Sea and Java Sea

    NASA Astrophysics Data System (ADS)

    Wei, Zexun; Fang, Guohong; Dwi Susanto, R.; Rameyo Adi, Tukul; Fan, Bin; Setiawan, Agus; Li, Shujiang; Wang, Yonggang; Gao, Xiumin

    2016-04-01

    The South China Sea (SCS) and the Java Sea (JS) are connected through the Karimata Strait, Gaspar Strait, and the southern Natuna Sea, where the tides are often used as open boundary condition for tidal simulation in the SCS or Indonesian seas. Tides, tidal currents, and tidal energy fluxes of the principle constituents K1, O1, Q1, M2, S2, and N2 at five stations in this area have been analyzed using in situ observational data. The results show that the diurnal tides are the dominant constituents in the entire study area. The constituent K1 has the largest amplitude, exceeding 50 cm, whereas the amplitudes of M2 are smaller than 5 cm at all stations. The amplitudes of S2 may exceed M2 in the Karimata and Gaspar straits. Tidal currents are mostly of rectilinear type in this area. The semi-major axes lengths of the diurnal tidal current ellipses are about 10 cm s-1, and those of the semidiurnal tidal currents are smaller than 5 cm s-1. The diurnal tidal energy flows from the SCS to the JS. The semidiurnal tidal energy flows from the SCS to the JS through the Karimata Strait and the eastern part of the southern Natuna Sea but flows in the opposite direction in the Gaspar Strait and the western part of the southern Natuna Sea. Harmonic analysis of sea level and current observation also suggest that the study area is located in the antinodal band of the diurnal tidal waves, and in the nodal band of the semidiurnal tidal waves. Comparisons show that the existing models are basically consistent with the observational results, but further improvements are necessary.

  5. Air sea gas exchange at extreme wind speeds measured by autonomous oceanographic floats

    NASA Astrophysics Data System (ADS)

    D'Asaro, Eric; McNeil, Craig

    2007-06-01

    Measurements of the air-sea fluxes of N 2 and O 2 were made in winds of 15-57 m s - 1 beneath Hurricane Frances using two types of air-deployed neutrally buoyant and profiling underwater floats. Two "Lagrangian floats" measured O 2 and total gas tension (GT) in pre-storm and post-storm profiles and in the actively turbulent mixed layer during the storm. A single "EM-APEX float" profiled continuously from 30 to 200 m before, during and after the storm. All floats measured temperature and salinity. N 2 concentrations were computed from GT and O 2 after correcting for instrumental effects. Gas fluxes were computed by three methods. First, a one-dimensional mixed layer budget diagnosed the changes in mixed layer concentrations given the pre-storm profile and a time varying mixed layer depth. This model was calibrated using temperature and salinity data. The difference between the predicted mixed layer concentrations of O 2 and N 2 and those measured was attributed to air-sea gas fluxes FBO and FBN. Second, the covariance flux FCO( z) = < wO 2'>( z) was computed, where w is the vertical motion of the water-following Lagrangian floats, O 2' is a high-pass filtered O 2 concentration and <>( z) is an average over covariance pairs as a function of depth. The profile FCO( z) was extrapolated to the surface to yield the surface O 2 flux FCO(0). Third, a deficit of O 2 was found in the upper few meters of the ocean at the height of the storm. A flux FSO, moving O 2 out of the ocean, was calculated by dividing this deficit by the residence time of the water in this layer, inferred from the Lagrangian floats. The three methods gave generally consistent results. At the highest winds, gas transfer is dominated by bubbles created by surface wave breaking, injected into the ocean by large-scale turbulent eddies and dissolving near 10-m depth. This conclusion is supported by observations of fluxes into the ocean despite its supersaturation; by the molar flux ratio FBO/ FBN, which is

  6. Air sea gas exchange at extreme wind speeds measured by autonomous oceanographic floats

    NASA Astrophysics Data System (ADS)

    D'Asaro, Eric; McNeil, Craig

    2008-11-01

    Measurements of the air-sea fluxes of N 2 and O 2 were made in winds of 15-57 m s - 1 beneath Hurricane Frances using two types of air-deployed neutrally buoyant and profiling underwater floats. Two "Lagrangian floats" measured O 2 and total gas tension (GT) in pre-storm and post-storm profiles and in the actively turbulent mixed layer during the storm. A single "EM-APEX float" profiled continuously from 30 to 200 m before, during and after the storm. All floats measured temperature and salinity. N 2 concentrations were computed from GT and O 2 after correcting for instrumental effects. Gas fluxes were computed by three methods. First, a one-dimensional mixed layer budget diagnosed the changes in mixed layer concentrations given the pre-storm profile and a time varying mixed layer depth. This model was calibrated using temperature and salinity data. The difference between the predicted mixed layer concentrations of O 2 and N 2 and those measured was attributed to air-sea gas fluxes FBO and FBN. Second, the covariance flux FCO( z) = < wO 2'>( z) was computed, where w is the vertical motion of the water-following Lagrangian floats, O 2' is a high-pass filtered O 2 concentration and <>( z) is an average over covariance pairs as a function of depth. The profile FCO( z) was extrapolated to the surface to yield the surface O 2 flux FCO(0). Third, a deficit of O 2 was found in the upper few meters of the ocean at the height of the storm. A flux FSO, moving O 2 out of the ocean, was calculated by dividing this deficit by the residence time of the water in this layer, inferred from the Lagrangian floats. The three methods gave generally consistent results. At the highest winds, gas transfer is dominated by bubbles created by surface wave breaking, injected into the ocean by large-scale turbulent eddies and dissolving near 10-m depth. This conclusion is supported by observations of fluxes into the ocean despite its supersaturation; by the molar flux ratio FBO/ FBN, which is

  7. Sea ice-atmosphere interaction: Application of multispectral satellite data in polar surface energy flux estimates

    NASA Technical Reports Server (NTRS)

    Steffen, K.; Schweiger, A.; Maslanik, J.; Key, J.; Weaver, R.; Barry, R.

    1990-01-01

    The application of multi-spectral satellite data to estimate polar surface energy fluxes is addressed. To what accuracy and over which geographic areas large scale energy budgets can be estimated are investigated based upon a combination of available remote sensing and climatological data sets. The general approach was to: (1) formulate parameterization schemes for the appropriate sea ice energy budget terms based upon the remotely sensed and/or in-situ data sets; (2) conduct sensitivity analyses using as input both natural variability (observed data in regional case studies) and theoretical variability based upon energy flux model concepts; (3) assess the applicability of these parameterization schemes to both regional and basin wide energy balance estimates using remote sensing data sets; and (4) assemble multi-spectral, multi-sensor data sets for at least two regions of the Arctic Basin and possibly one region of the Antarctic. The type of data needed for a basin-wide assessment is described and the temporal coverage of these data sets are determined by data availability and need as defined by parameterization scheme. The titles of the subjects are as follows: (1) Heat flux calculations from SSM/I and LANDSAT data in the Bering Sea; (2) Energy flux estimation using passive microwave data; (3) Fetch and stability sensitivity estimates of turbulent heat flux; and (4) Surface temperature algorithm.

  8. Three-Dimensional Modeling of Air-Sea Interaction

    NASA Astrophysics Data System (ADS)

    Regis, J. L.; Slinn, D. N.

    2004-12-01

    Deep-water wave breaking is crucial in the transfer of heat, gases, and momentum between the ocean and the atmosphere. Observations of these events have provided qualitative support to this end, and yet accurate quantification of momentum transfer for strong winds and nonlinear waves has remained a challenge. In recent years, advances have been made in the development of numerous algorithms to capture and describe air-sea interaction. Most, however, are idealized and only capable of modeling fluid flow within the two-dimensional approximation. Thus, many important characteristics of the flow composition and breaking process are ignored, oversimplified, or remain unknown. We employ a three-dimensional, time-dependent, finite difference, volume of fluid model, including both the flow of air and water, entitled TRUCHAS, to address the issue of deep-water breaking waves. Our model utilizes the multidimensional piecewise linear interface calculation method to assess the volume fraction of each fluid material in every mesh cell. The model solves conservation equations for mass and momentum for multiple fluids within the domain and tracks the interfaces between them. A great many details of the flow development are available for analysis from the model output. These include wind and water velocities, pressure gradients in both the air and sea around a breaking wave, the development and evolution of wind-generated waves, and the corresponding transfer of momentum from the atmosphere to the ocean. Our results are correlated with laboratory experiments conducted at the University of Miami's Air-Sea Interaction Salt-water Tank that possesses both wind and wave generating capabilities. Preliminary model results show good qualitative agreement to laboratory data.

  9. Modeling of Air-Sea Interaction and Ocean Processes for the Northern Arabian Sea Circulation Autonomous Research Project

    DTIC Science & Technology

    2015-09-30

    and space-time variability in the Northwestern Indian Ocean and Arabian Sea on time scales from days up to several seasonal cycles . OBJECTIVES...determine the mechanisms causing vertical mixing in the Arabian Sea: wind mixing, role of air- sea interaction and surface heat and fresh water ...equatorial region and the East African Coastal current, a source of low-salinity water for the Arabian Sea. APPROACH The fast-flowing Somali

  10. Transpiration's inhibition of air pollution fluxes to substomatal cavities. [PRECP

    SciTech Connect

    Slinn, W.G.N.

    1987-05-01

    This report presents an estimate for the resistance to transport through stomatal openings, accounting for the counterflowing flux of water vapor associated with transpiration. The specific goal of this report is to estimate the influence of transpiration on the stomatal resistance, r/sub sto/; others have estimated the substomatal and mesophyll resistances r/sub ssc/ and r/sub mes/. It might be expected that any influence of the water-vapor flux on pollutant transport would be a maximum at the stomatal opening since, at the constricted area of the stoma, the water flux is a maximum. Transpiration through stomata appears to insigifnicantly inhibit the passage of relatively small molecules (e.g., SO/sub 2/, O/sub 3/, HNO/sub 3/, PAN, etc.) through the stomata, and therefore, by entering the substomatal cavity, such pollutants have greater potential for threatening plan survival, if their concentrations are excessive. 7 refs., 5 figs.

  11. Air--Sea CO2 Cycling in the Southeastern Beaufort Sea

    NASA Astrophysics Data System (ADS)

    Else, Brent Gordon Thomas

    During the fourth International Polar Year, an interdisciplinary study was conducted to examine the couplings between sea ice, ocean, atmosphere, and ecosystem in the southeastern Beaufort Sea. This thesis examines components of the system that control the air-sea exchange of carbon dioxide. Using eddy covariance measurements, we found enhanced CO2 exchange associated with new ice formation in winter flaw leads. This exchange was typically directed towards the surface, although we also measured one instance of outgassing. Sea surface dissolved CO2 measurements (pCO 2sw) in Amundsen Gulf showed significant undersaturation with respect to the atmosphere at freeze-up, followed by a slow increase over the winter until spring phytoplankton blooms caused strong undersaturation at break-up. Over the summer, pCO2sw increased until becoming slightly supersaturated due to surface warming. Along the southern margins of Amundsen Gulf and on the Mackenzie Shelf we found pCO2sw supersaturations in the fall due to wind-driven coastal upwelling. In the spring, this upwelling occurred along the landfast ice edges of Amundsen Gulf. By combining observations of enhanced winter gas exchange with observations of pCO 2sw in Amundsen Gulf, we derived an annual budget of air-sea CO2 exchange for the region. This exercise showed that uptake through the winter season was as important as the open water season, making the overall annual uptake of CO2 about double what had previously been calculated. Prior to this work, the prevailing paradigm of airsea CO2 cycling in Arctic polynya regions posited that strong CO2 absorption occurs in the open water seasons, and that a potential outgassing during the winter is inhibited by the sea ice cover. As a new paradigm, we propose that the spatial and temporal variability of many processes---including phytoplankton blooms, sea surface temperature and salinity changes, upwelling, river input, continental shelf processes, and the potential for high rates

  12. Towards More Realistic Simulation of Air-Sea Interaction over Lakes on Titan

    NASA Astrophysics Data System (ADS)

    Rafkin, Scot; Soto, Alejandro

    2016-06-01

    The exchange of methane between the atmosphere and surface liquid reservoirs dominates the short time-scale methanological cycle. In this study, previous two-dimensional simulations of the exchange of methane vapor, sensible heat and momentum between the atmosphere and lakes are updated with the inclusion of radiative forcing and extended to three dimensions, including the introduction of realistic coastlines. Previous studies of Titan's air-sea exchange in two dimensions suggested that the exchange process was self-limiting. Evaporation from lakes produced a shallow but extremely stable marine layer that suppressed turbulent exchange. Furthermore, the circulation associated with the higher buoyancy of methane-rich atmosphere over the lake was offset by the oppositely directed thermal sea breeze circulation, which muted the mean wind. Two major weaknesses of this previous work were the lack of radiative forcing and the imposition of two dimensionality that limited the full range of dynamical solutions. Based on early theoretical studies, it was thought that magnitude of turbulent energy flux exchanges would be much larger than radiative fluxes, thereby justifying the neglect of radiation, but the two-dimensional simulations indicated that this was not a valid assumption. The dynamical limitations of two-dimensional simulations are well known. Vorticity stretching (i.e., circulation intensification through vertical motion) is not possible and it is also not possible to produce dynamically balanced gradient wind-type circulations. As well, the irregular shape of a realistic coastline cannot be expressed in two dimensions, and these realistic structures will generally induce complex convergence and divergence circulations in the atmosphere. The impact of radiative forcing and the addition of the third dimension on the air-sea exchange are presented.

  13. Air-sea exchange of gaseous mercury in the tropical coast (Luhuitou fringing reef) of the South China Sea, the Hainan Island, China.

    PubMed

    Ci, Zhijia; Zhang, Xiaoshan; Wang, Zhangwei

    2016-06-01

    The air-sea exchange of gaseous mercury (mainly Hg(0)) in the tropical ocean is an important part of the global Hg biogeochemical cycle, but the related investigations are limited. In this study, we simultaneously measured Hg(0) concentrations in surface waters and overlaying air in the tropical coast (Luhuitou fringing reef) of the South China Sea (SCS), Hainan Island, China, for 13 days on January-February 2015. The purpose of this study was to explore the temporal variation of Hg(0) concentrations in air and surface waters, estimate the air-sea Hg(0) flux, and reveal their influencing factors in the tropical coastal environment. The mean concentrations (±SD) of Hg(0) in air and total Hg (THg) in waters were 2.34 ± 0.26 ng m(-3) and 1.40 ± 0.48 ng L(-1), respectively. Both Hg(0) concentrations in waters (53.7 ± 18.8 pg L(-1)) and Hg(0)/THg ratios (3.8 %) in this study were significantly higher than those of the open water of the SCS in winter. Hg(0) in waters usually exhibited a clear diurnal variation with increased concentrations in daytime and decreased concentrations in nighttime, especially in cloudless days with low wind speed. Linear regression analysis suggested that Hg(0) concentrations in waters were positively and significantly correlated to the photosynthetically active radiation (PAR) (R (2) = 0.42, p < 0.001). Surface waters were always supersaturated with Hg(0) compared to air (the degree of saturation, 2.46 to 13.87), indicating that the surface water was one of the atmospheric Hg(0) sources. The air-sea Hg(0) fluxes were estimated to be 1.73 ± 1.25 ng m(-2) h(-1) with a large range between 0.01 and 6.06 ng m(-2) h(-1). The high variation of Hg(0) fluxes was mainly attributed to the greatly temporal variation of wind speed.

  14. Carbon cycling in the upper waters of the Sargasso Sea: I. Numerical simulation of differential carbon and nitrogen fluxes

    NASA Astrophysics Data System (ADS)

    Bissett, W. P.; Walsh, J. J.; Dieterle, D. A.; Carder, K. L.

    1999-02-01

    A complex ecosystem model is developed for the area around Bermuda in the Sargasso Sea. The model is physically driven by seasonal changes in spectral light, temperature, and water column mixing. Autotrophic growth is represented by four functional groups of phytoplankton. The groups have light and nutrient utilization characteristics that reflect those of Prochlorococcus, Synechococcus and Chromophycota species. The model includes differential carbon and nitrogen cycling, nitrification, and nitrogen fixation to effect realistic allochthonous and autochthonous nutrient sources to the euphotic zone. This simulation yields realistic seasonal and vertical (1) succession of phytoplankton functional groups' biomass, productivity, and pigments; (2) profiles of dissolved inorganic carbon, nitrate, and ammonium; and (3) fluxes of carbon dioxide at the air-sea boundary and particulate carbon and nitrogen settling losses, when compared to the JGOFS BATS site. The addition of local nitrification, differential carbon and nitrogen remineralization, and nitrogen fixation removes the need for an unrealistically high upward vertical flux of nitrate to mimic the productivity and chlorophyll a stocks. The explicit numerical description of carbon and nitrogen utilization by heterotrophic bacteria simulated a population that was not nitrogen-limited in these waters. Instead, the heterotrophic bacteria community was limited by energy resources in the form of DOC, and was a nitrogen source for the autotrophic community through the excretion of excess NH 4 from the labile DOM energy source. Numerical descriptions of ecosystems based solely on nitrogen dynamics, or fixed carbon to nitrogen ratios, may yield an inaccurate prediction of carbon and nitrogen fluxes, and fail to properly predict the carbon cycle.

  15. Ocean Surface Temperature Response to Atmosphere-Ocean Interaction of the MJO: A Component of Coupled Air-Wave-Sea Processes in the Subtropics Department Research Initiative

    DTIC Science & Technology

    2012-09-30

    rawinsonde launches in addition to turbulent air-sea fluxes from the ship during the IOP. Further, we expect to have interactions with the many PIs...International Geoscience and Remote Sensing Symposium in Munich, Germany in July 2012. We also participated in the ONR LASP / DYNAMO DRI Meeting at the Hilton

  16. A new implementation of the Biogeochemical Flux Model in sea ice

    NASA Astrophysics Data System (ADS)

    Tedesco, L.; Vichi, M.

    2009-04-01

    The Biogeochemical Flux Model (BFM) is a direct descendent of the European Regional Seas Ecosystem Model (ERSEM) and it has been widely used and validated among the scientific community. The BFM view of the of the marine ecosystem is based upon the recognition that the major ecological functions of producers, decomposers and consumers and their specific trophic interactions can be expressed in terms of material flows of basic elements. The concentration and characteristics of organic and inorganic compounds are thus seen under a stoichiometrical perspective. This functional approach brings to the definition of Chemical Functional Families (CFF) and Living Functional Groups (LFG). The BFM is thus a set of biogeochemical equations describing the cycling of carbon, the macro-nutrients and oxygen through the lower trophic levels of marine ecosystems. A Sea-Ice system has now been implemented in the BFM and the new BFM-SI consists of three new LFG (sea ice algae, heterotrophic zooplankton, bacterioplankton), one new non-living organic functional group (sea ice DOM and POM) and two new inorganic functional groups: dissolved gases (sea ice CO2 and O2) and four nutrients (sea ice PO4, NH3, NO3 and SiO4). The innovative approach consists in simulating the biogeochemistry of the sea ice Biologically-Active-Layer (BAL), where the majority of the biomass (bottom communities) concentrates. The BFM-SI requires the physical properties of the BAL in order to be able to simulate the physiological and ecological response of the biological community to the physical environment. This is currently done by using an Enhanced 1-D thermo-halodynamic Sea Ice Model (ESIM2), developed to be suitable for biogeochemical studies. Since the biogeochemistry of sea ice is largely unknown, the BFM-SI is a useful tool that allow us to test hypotheses on the functioning of the sea ice ecosystem. By initially setting the sea ice community as having the same characteristics than the pelagic community

  17. Air-sea Forcing and Thermohaline Changes In The Ross Sea.

    NASA Astrophysics Data System (ADS)

    Fusco, G.; Budillon, G.

    Heat exchanges between sea and atmosphere from 1986 to 2000 in the Ross Sea (Antarctica) were computed from climatological data obtained from the European Centre for Medium Range Weather Forecasts. They have been related with the thermo- haline changes observed during 5 hydrological surveys performed between the austral summer 1994-1995 and 2000-2001 in the western sector of the Ross Sea. The esti- mated heat fluxes show extremely strong spatial and temporal variability over all the Ross Sea. As can be expected the largest heat losses occur between May and August, while during the period November-February the heat budget becomes positive. In the first six years of the investigated period the heat loss is very strong with its maximum about 166 Wm-2; while during the period 1992-2000 the yearly heat losses are the lowest. Thermohaline changes in the surface layer (upper pycnocline) of the western Ross Sea follow the expected seasonal pattern of warming and freshening from the be- ginning to the end of the austral summer. The heating changes are substantially lower than the estimated heat supplied by the atmosphere during the summer, which under- lines the importance in this season of the advective component carried by the currents in the total heat budget of this area. The year to year differences are about one or two orders of magnitude smaller than the seasonal changes in the surface layer. In the in- termediate and deep layers, the summer heat and salt variability is of the same order as or one order higher than from one summer to the next. Moreover a freshening of the near bottom layer has been observed, it is consistent with the High Salinity Shelf Water salinity decrease recently detected in the Ross Sea.

  18. Wave-Phase-Resolved Air-Sea Interaction

    DTIC Science & Technology

    2014-09-30

    to become an important asset in air-sea interaction research (Figure 3). Data from a scan-beam ADCP on FLIP was consistent with surface signatures...near-surface current velocity measured using a fan-beam ADCP mounted on FLIP’s hull. The bottom panel is a (contrast enhanced) image taken by the...video camera mounted on FLIP’s crows nest showing streak structures at the surface. The regions of convergence in the ADCP data are thought to correspond to the streak structures seen in the visible imagery.

  19. Air-Sea Interaction Studies of the Indian and Pacific Oceans

    DTIC Science & Technology

    2014-09-30

    tasks: Task 1: Air- Sea Interactions Impacting the North Arabian Sea Circulation Task 2: Satellite Observations of Flow Encountering Abrupt...resolution SAR data will allow monitoring of ocean processes in the North Arabian Sea circulation region due to current and/or meteorological forcing at a...1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Air- Sea Interaction Studies of the Indian and Pacific

  20. Air-sea exchange over Black Sea estimated from high resolution regional climate simulations

    NASA Astrophysics Data System (ADS)

    Velea, Liliana; Bojariu, Roxana; Cica, Roxana

    2013-04-01

    Black Sea is an important influencing factor for the climate of bordering countries, showing cyclogenetic activity (Trigo et al, 1999) and influencing Mediterranean cyclones passing over. As for other seas, standard observations of the atmosphere are limited in time and space and available observation-based estimations of air-sea exchange terms present quite large ranges of uncertainty. The reanalysis datasets (e.g. ERA produced by ECMWF) provide promising validation estimates of climatic characteristics against the ones in available climatic data (Schrum et al, 2001), while cannot reproduce some local features due to relatively coarse horizontal resolution. Detailed and realistic information on smaller-scale processes are foreseen to be provided by regional climate models, due to continuous improvements of physical parameterizations and numerical solutions and thus affording simulations at high spatial resolution. The aim of the study is to assess the potential of three regional climate models in reproducing known climatological characteristics of air-sea exchange over Black Sea, as well as to explore the added value of the model compared to the input (reanalysis) data. We employ results of long-term (1961-2000) simulations performed within ENSEMBLE project (http://ensemblesrt3.dmi.dk/) using models ETHZ-CLM, CNRM-ALADIN, METO-HadCM, for which the integration domain covers the whole area of interest. The analysis is performed for the entire basin for several variables entering the heat and water budget terms and available as direct output from the models, at seasonal and annual scale. A comparison with independent data (ERA-INTERIM) and findings from other studies (e.g. Schrum et al, 2001) is also presented. References: Schrum, C., Staneva, J., Stanev, E. and Ozsoy, E., 2001: Air-sea exchange in the Black Sea estimated from atmospheric analysis for the period 1979-1993, J. Marine Systems, 31, 3-19 Trigo, I. F., T. D. Davies, and G. R. Bigg (1999): Objective

  1. Benthic fluxes of dissolved organic carbon from gas hydrate sediments in the northern South China Sea

    PubMed Central

    Hung, Chia-Wei; Huang, Kuo-Hao; Shih, Yung-Yen; Lin, Yu-Shih; Chen, Hsin-Hung; Wang, Chau-Chang; Ho, Chuang-Yi; Hung, Chin-Chang; Burdige, David J.

    2016-01-01

    Hydrocarbon vents have recently been reported to contribute considerable amounts of dissolved organic carbon (DOC) to the oceans. Many such hydrocarbon vents widely exist in the northern South China Sea (NSCS). To investigate if these hydrocarbon vent sites release DOC, we used a real-time video multiple-corer to collect bottom seawater and surface sediments at vent sites. We analyzed concentrations of DOC in these samples and estimated DOC fluxes. Elevated DOC concentrations in the porewaters were found at some sites suggesting that DOC may come from these hydrocarbon vents. Benthic fluxes of DOC from these sediments were 28 to 1264 μmol m−2 d−1 (on average ~321 μmol m−2 d−1) which are several times higher than most DOC fluxes in coastal and continental margin sediments. The results demonstrate that the real-time video multiple-corer can precisely collect samples at vent sites. The estimated benthic DOC flux from the methane venting sites (8.6 × 106 mol y−1), is 24% of the DOC discharge from the Pearl River to the South China Sea, indicating that these sediments make an important contribution to the DOC in deep waters. PMID:27432631

  2. Benthic fluxes of dissolved organic carbon from gas hydrate sediments in the northern South China Sea

    NASA Astrophysics Data System (ADS)

    Hung, Chia-Wei; Huang, Kuo-Hao; Shih, Yung-Yen; Lin, Yu-Shih; Chen, Hsin-Hung; Wang, Chau-Chang; Ho, Chuang-Yi; Hung, Chin-Chang; Burdige, David J.

    2016-07-01

    Hydrocarbon vents have recently been reported to contribute considerable amounts of dissolved organic carbon (DOC) to the oceans. Many such hydrocarbon vents widely exist in the northern South China Sea (NSCS). To investigate if these hydrocarbon vent sites release DOC, we used a real-time video multiple-corer to collect bottom seawater and surface sediments at vent sites. We analyzed concentrations of DOC in these samples and estimated DOC fluxes. Elevated DOC concentrations in the porewaters were found at some sites suggesting that DOC may come from these hydrocarbon vents. Benthic fluxes of DOC from these sediments were 28 to 1264 μmol m-2 d-1 (on average ~321 μmol m-2 d-1) which are several times higher than most DOC fluxes in coastal and continental margin sediments. The results demonstrate that the real-time video multiple-corer can precisely collect samples at vent sites. The estimated benthic DOC flux from the methane venting sites (8.6 × 106 mol y-1), is 24% of the DOC discharge from the Pearl River to the South China Sea, indicating that these sediments make an important contribution to the DOC in deep waters.

  3. Teleconnections, Midlatitude Cyclones and Aegean Sea Turbulent Heat Flux Variability on Daily Through Decadal Time Scales

    NASA Technical Reports Server (NTRS)

    Romanski, Joy; Romanou, Anastasia; Bauer, Michael; Tselioudis, George

    2013-01-01

    We analyze daily wintertime cyclone variability in the central and eastern Mediterranean during 1958-2001, and identify four distinct cyclone states, corresponding to the presence or absence of cyclones in each basin. Each cyclone state is associated with wind flows that induce characteristic patterns of cooling via turbulent (sensible and latent) heat fluxes in the eastern Mediterranean basin and Aegean Sea. The relative frequency of occurrence of each state determines the heat loss from the Aegean Sea during that winter, with largest heat losses occurring when there is a storm in the eastern but not central Mediterranean (eNOTc), and the smallest occurring when there is a storm in the central but not eastern Mediterranean (cNOTe). Time series of daily cyclone states for each winter allow us to infer Aegean Sea cooling for winters prior to 1985, the earliest year for which we have daily heat flux observations. We show that cyclone states conducive to Aegean Sea convection occurred in 1991/1992 and 1992/1993, the winters during which deep water formation was observed in the Aegean Sea, and also during the mid-1970s and the winters of 1963/1964 and 1968/1969. We find that the eNOTc cyclone state is anticorrelated with the North Atlantic Oscillation (NAO) prior to 1977/1978. After 1977/1978, the cNOTe state is anticorrelated with both the NAO and the North Caspian Pattern (NCP), showing that the area of influence of large scale atmospheric teleconnections on regional cyclone activity shifted from the eastern to the central Mediterranean during the late 1970s. A trend toward more frequent occurrence of the positive phase of the NAO produced less frequent cNOTe states since the late 1970s, increasing the number of days with strong cooling of the Aegean Sea surface waters.

  4. Coexistence of Gas Hydrates and Free Gas in the Black Sea: High-Flux versus Low-Flux Areas

    NASA Astrophysics Data System (ADS)

    Klaucke, I.; Zander, T.; Klaeschen, D.; Papenberg, C. A.; Bialas, J.

    2012-12-01

    Batumi Seep and Kerch Flare are two methane seep areas located in 900-1000 m water depth in the Black Sea, i.e. within the zone gas hydrate stability. Both seeps, however, show the presence of both gas hydrates and free gas bubbles. A number of scenarios explaining such observations have been proposed and suggest either fresh pore water being unavailable or being inaccessible. Batumi Seep, which is located offshore Georgia and shows high fluxes of biogenic gas out of the uppermost hundreds of metres of the sedimentary succession, could well be a case, where the gas flux exceeds the availability of pore water. Kerch Flare, on the other hand, is located on the Don-Kuban Fan offshore Crimea and shows only limited and localised gas flux and most likely represents a case, where fresh pore water is inaccessible. Recently acquired sidescan sonar, water-column imaging and 3D-reflection seismic data around Kerch Flare show little impact of seep activity on the seafloor while a few gas bubble streams are present at the periphery of a central, slightly domed structure of a few hundreds of metres in diameter. Chirp subbottom profiler data do not penetrate this central area, but high-resolution seismic data indicate that Kerch Flare is fuelled from gas reservoirs at greater depth, i.e. several hundreds of metres below seafloor and below the gas hydrate stability zone. Kerch Flare is located on the flanks and not the top of a levee of one of the channels of the Don-Kuban deep-sea fan. Kerch Flare is, however, located right above the top of an older levee that might constitute the source level for the flare. The youngest levee is intensely faulted by sub-vertical faults of which one serves as a conduit for Kerch Flare. We interpret the sub-vertical faults as the result of strengthening of the levee deposits by gas hydrate cementation. Rising gas has to pass through the gas hydrate stability zone and even small amounts of gas within the faults would consequently be efficiently

  5. A numerical coupled model for studying air-sea-wave interaction

    NASA Astrophysics Data System (ADS)

    Ly, Le Ngoc

    1995-10-01

    A numerical coupled model of air-sea-wave interaction is developed to study the influence of ocean wind waves on dynamical, turbulent structures of the air-sea system and their impact on coupled modeling. The model equations for both atmospheric and oceanic boundary layers include equations for: (1) momentum, (2) a k-ɛ turbulence scheme, and (3) stratification in the atmospheric and oceanic boundary layers. The model equations are written in the same form for both the atmosphere and ocean. In this model, wind waves are considered as another source of turbulent energy in the upper layer of the ocean besides turbulent energy from shear production. The dissipation ɛ at the ocean surface is written as a linear combination of terms representing dissipation from mean flow and breaking waves. The ɛ from breaking waves is estimated by using similarity theory and observed data. It is written in terms of wave parameters such as wave phase speed, height, and length, which are then expressed in terms of friction velocity. Numerical experiments are designed for various geostrophic winds, wave heights, and wave ages, to study the influence of waves on the air-sea system. The numerical simulations show that the vertical profiles of ɛ in the atmospheric and oceanic boundary layers (AOBL) are similar. The magnitudes of ɛ in the oceanic surface zone are much larger than those in the atmospheric surface zone and in the interior of the oceanic boundary layer (OBL). The model predicts ɛ distributions with a surface zone of large dissipation which was not expected from similarity scaling based on observed wind stress and surface buoyancy. The simulations also show that waves have a strong influence on eddy viscosity coefficients (EVC) and momentum fluxes, and have a dominated effect on the component of fluxes in the direction of the wind. The depth of large changes in flux magnitudes and EVC in the ocean can reach to 10-20 m. The simulations of surface drift currents confirm that

  6. Air-sea interaction at the Southern Brazilian Continental Shelf: In situ observations

    NASA Astrophysics Data System (ADS)

    Pezzi, L. P.; Souza, R. B.; Farias, P. C.; Acevedo, O.; Miller, A. J.

    2016-09-01

    The influence of the cross-shelf oceanographic front occurring between the Brazil Current (BC) and the Brazilian Coastal Current (BCC) on the local Marine Atmospheric Boundary Layer (MABL) is investigated here. This front is typical of wintertime in the Southern Brazilian Continental Shelf (SBCS) and this is the first time that its effects are investigated over the above MABL. Here we analyze variability, vertical structure, and stability of MABL as well as heat fluxes at air-sea interface, across five oceanographic transects in the SBCS made during a winter 2012 cruise. Local thermal gradients associated with mixing between distinct water masses, play an essential role on MABL modulation and stability. Although weaker when compared with other frontal regions, the cross-shelf thermal gradients reproduce exactly what is expected for open ocean regions: Stronger (weaker) winds, lower (higher) sea level pressure, and a more unstable (stable) MABL are found over the warm (cold) side of the oceanographic front between the BC (warm) and coastal (cold) waters. Our findings strongly support the coexistence of both known MABL modulation mechanisms: the static and hydrostatic MABL stability. This is the first time that these modulation mechanisms are documented for this region. Turbulent fluxes were found to be markedly dependent on the cross-shelf SST gradients resulting in differences of up to 100 W.m-2 especially in the southernmost region where the gradients were more intense.

  7. Natural flux of greenhouse methane from the Timor Sea to the atmosphere

    NASA Astrophysics Data System (ADS)

    Brunskill, G. J.; Burns, K. A.; Zagorskis, I.

    2011-06-01

    Methane gas bubbles from the Cornea Seep were sampled at the sea surface in the Timor Sea continental shelf area in June 2005. Total bubble gas flux was 0.076 to 0.76 L m-2 h-1 during the 6 h d-1 periods of low neap tides in June 2005. This bubble gas contained an average of 26 mmol CH4 L-1 and about 0.16 and 0.006 mmol L-1 of ethane and propane. We estimate the daily flux from the sea surface to the atmosphere to be 0.012 to 0.12 mol CH4 m-2 d-1 or 0.13 to 1.3 t CH4 d-1 from an area of about 0.7 km2. This methane flux came from a 500 × 1400 m carbonate pavement dome on the seafloor at 84 m water depth. The seep hard ground was swath mapped, and 3.5 kHz subbottom profile data indicate that the seep dome was strongly reflective with poor penetration into the subsurface, consistent with the presence of a carbonate hard ground. Carbon and deuterium isotope ratios (δ13C = -41 to -42‰, δD = -157 to -158‰) of the seep bubble gas indicate that this methane had a thermogenic origin and was in the same isotopic range as gas within the Late Cretaceous Cornea oil and gas field. We could not detect inputs of fluids containing nutrients or short-lived radium isotopes at this site, commonly associated with other cold seeps. Tens to a hundred of kilometers seaward from the Cornea seep site, water column dissolved methane concentrations in this sector of the Timor Sea shelf and slope were 100-500 times supersaturated with respect to the atmosphere, and thus the water column is expected to be degassing additional methane to the atmosphere. Perhaps there are thousands of other methane seeps (of similar magnitude to the Cornea Seep) on this shelf and slope to account for all the excess dissolved methane (˜86,000 t) measured in the water column. These measured and calculated fluxes provide evidence for the hypothesis that shallow sea seeps may be a significant source of atmospheric methane, in contrast to deep sea vents, where most of the methane is dissolved and oxidized in

  8. Unravelling air-sea interactions driven by photochemistry in the sea-surface microlayer

    NASA Astrophysics Data System (ADS)

    George, Christian; Alpert, Peter; Tinel, Liselotte; Rossignol, Stéphanie; Perrier, Sébastien; Bernard, Francois; Ciuraru, Raluca; Hayeck, Nathalie

    2016-04-01

    Interfaces are ubiquitous in the environment, and in addition many atmospheric key processes, such as gas deposition, aerosol and cloud formation are, at one stage or the other, strongly impacted by physical- and chemical processes occurring at interfaces. Unfortunately, these processes have only been suggested and discussed but never fully addressed because they were beyond reach. We suggest now that photochemistry or photosensitized reactions exist at interfaces, and we will present and discuss their possible atmospheric implications. Obviously, one of the largest interface is the sea-surface microlayer (SML), which is a region lying at the uppermost tens to hundreds of micrometres of the water surface, with physical, chemical and biological properties that differ from those of the underlying sub-surface water. Organic film formation at the sea surface is made possible in the presence of an excess of surface-active material. Hydrophobic surfactant films are typically believed to play the role of a physical barrier to air-sea exchanges, especially at low wind speed. We will show that dissolved organic matter (DOM) can trigger photochemistry at the air-sea interface, releasing unsaturated, functionalized volatile organic compounds (VOCs), including isoprene,... acting as precursors for the formation of organic aerosols, that were thought, up to now, to be solely of biological origin! In addition, we suggest that when arranged at an air/water interface, hydrophobic surfactant can have weak chemical interactions among them, which can trigger the absorption of sunlight and can consequently induce photochemistry at such interfaces. A major question arises from such observations, namely: can the existence of such weak intra- or intermolecular interactions and the subsequent photochemistry be generalized to many other atmospheric objects such as aerosols? This topic will be presented and discussed.

  9. The Role of the U.S. Army in Air Sea Battle

    DTIC Science & Technology

    2013-04-01

    national power to the Asia -Pacific region. The military contribution to this new national security strategy is termed “ Air Sea Battle.” Air Sea Battle...Asian focus under our new national security strategy. The military contribution to this new national security strategy is currently termed “ Air Sea...against a foe with anti-access and area-denial capabilities. As a concept, Air Sea Battle is not new . In one form or another, it has been around as a

  10. Exchange of polycyclic aromatic hydrocarbons across the air-water interface in the Bohai and Yellow Seas

    NASA Astrophysics Data System (ADS)

    Chen, Yingjun; Lin, Tian; Tang, Jianhui; Xie, Zhiyong; Tian, Chongguo; Li, Jun; Zhang, Gan

    2016-09-01

    In this study, air and surface seawater samples collected from the Bohai (BS) and Yellow Seas (YS) in May 2012 were determined exchange of PAHs, especially of low-molecular-weight (LMW) PAHs (three- and four-ring PAHs) at the air-water interface. Net volatilization fluxes of LMW PAHs were 266-1454 ng/m2/d and decreased with distance from the coast, indicating that these PAHs transported from coastal runoff were potential contributors to the atmosphere in the BS and YS. Moreover, LMW PAHs were enriched in the dissolved phase compared with those in the particulate phase in the water column, possibly suggesting that the volatilized LMW PAHs were directly derived from wastewater discharge or petroleum pollution rather than released from contaminated sediments. The air-sea exchange fluxes of the three-ring PAHs were 2- to 20-fold higher than their atmospheric deposition fluxes in the BS and YS. The input to and output from the water reached equilibrium for four-ring PAHs. Differently, five- and six-ring PAHs were introduced into the marine environment primarily through dry and wet deposition, indicating that the water column was still a sink of these PAHs from the surrounding atmosphere.

  11. Late Quaternary fluctuations of biogenic component fluxes on the continental slope of the Ross Sea, Antarctica

    NASA Astrophysics Data System (ADS)

    Ceccaroni, L.; Frank, M.; Frignani, M.; Langone, L.; Ravaioli, M.; Mangini, A.

    1998-11-01

    A sediment core, collected from the western part of the continental slope of the Ross Sea at 2380 m water depth, records events of the last two climatic cycles (250 kyr). A 230Th ex-based chronology was obtained and boundaries of the isotope stages were set assuming that biological productivity was enhanced during periods of less ice cover. Then, 230Th ex0, organic carbon, biogenic silica and biogenic Ba distributions were compared to the glacial-interglacial stage boundaries and corresponding ages of the δ 18O record of Martinson et al. [Martinson, D.G., Pisias, N.G., Hays, J.D., Imbrie, J., Moore, T.C., Jr., Shackleton, N.J, 1987. Age dating and the orbital theory of the ice ages: development of a high-resolution 0 to 300,000-year chronostratigraphy. Quaternary Research, 27: 1-29]. Sediment accumulation rates ranged between 1.2 cm kyr -1 in the isotope stage 6 and 3.8 cm kyr -1 during the Holocene. Variations in the concentrations and fluxes of organic carbon, biogenic Ba, biogenic silica and Mn gave information on palaeoclimate changes. Processes of sediment redistribution in the Ross Sea margin were enlightened from a comparison of the measured and expected fluxes of 230Th ex. Calculation of the focusing-corrected accumulation rates of biogenic Ba enabled us to evaluate the export palaeoproductivity. Corrected accumulation rates of biogenic components and calculated palaeoproductivities were low, compared to the Antarctic Polar Front in the Atlantic sector, throughout the last two climatic cycles. Glacial-interglacial changes of sea ice cover and ventilation of the Ross Sea were probably major causes of variations in biogenic particle flux and distribution of redox-sensitive elements within the sediment column.

  12. Research in Observations of Oceanic Air/Sea Interaction

    NASA Technical Reports Server (NTRS)

    Long, David G.; Arnold, David V.

    1995-01-01

    The primary purpose of this research has been: (1) to develop an innovative research radar scatterometer system capable of directly measuring both the radar backscatter and the small-scale and large-scale ocean wave field simultaneously and (2) deploy this instrument to collect data to support studies of air/sea interaction. The instrument has been successfully completed and deployed. The system deployment lasted for six months during 1995. Results to date suggest that the data is remarkably useful in air/sea interaction studies. While the data analysis is continuing, two journal and fifteen conference papers have been published. Six papers are currently in review with two additional journal papers scheduled for publication. Three Master's theses on this research have been completed. A Ph.D. student is currently finalizing his dissertation which should be completed by the end of the calendar year. We have received additional 'mainstream' funding from the NASA oceans branch to continue data analysis and instrument operations. We are actively pursuing results from the data expect additional publications to follow. This final report briefly describes the instrument system we developed and results to-date from the deployment. Additional detail is contained in the attached papers selected from the bibliography.

  13. The impact of poleward moisture and sensible heat flux on Arctic winter sea-ice variability.

    NASA Astrophysics Data System (ADS)

    Park, H. S.; Lee, S.; Son, S. W.; Feldstein, S. B.; Kosaka, Y.

    2015-12-01

    The surface warming in recent decades has been most rapid in the Arctic, especially during the winter. Here, by utilizing global reanalysis and satellite datasets, we show that the northward flux of moisture into the Arctic during the winter strengthens the downward infrared radiation (IR) by 30-40 W m-2 over 1-2 weeks. This is followed by a decline of up to 10% in sea ice concentration over the Greenland, Barents and Kara Seas. A climate model simulation indicates that the wind-induced sea-ice drift leads the decline of sea-ice thickness during the early stage of the strong downward IR events, but that within one week the cumulative downward IR effect appears to be dominant. Further analysis indicates that strong downward IR events are preceded several days earlier by enhanced convection over the tropical Indian-western Pacific Ocean. This finding suggests that sea-ice predictions can benefit from an improved understanding of tropical convection and ensuing planetary wave dynamics.

  14. Novel dynamic flux chamber for measuring air-surface exchange of Hg(o) from soils.

    PubMed

    Lin, Che-Jen; Zhu, Wei; Li, Xianchang; Feng, Xinbin; Sommar, Jonas; Shang, Lihai

    2012-08-21

    Quantifying the air-surface exchange of Hg(o) from soils is critical to understanding the cycling of mercury in different environmental compartments. Dynamic flux chambers (DFCs) have been widely employed for Hg(o) flux measurement over soils. However, DFCs of different sizes, shapes, and sampling flow rates yield distinct measured fluxes for a soil substrate under identical environmental conditions. In this study, we performed an integrated modeling, laboratory and field study to design a DFC capable of producing a steady and uniform air flow over a flat surface. The new DFC was fabricated using polycarbonate sheets. The internal velocity field was experimentally verified against model predictions using both theoretical and computational fluid dynamics techniques, suggesting fully developed flow with velocity profiles in excellent agreement with model results. Laboratory flux measurements demonstrated that the new design improves data reproducibility as compared to a conventional DFC, and reproduces the model-predicted flux trend with increasing sampling flow. A mathematical relationship between the sampling flow rate and surface friction velocity, a variable commonly parametrized in atmospheric models, was developed for field application. For the first time, the internal shear property of a DFC can be precisely controlled using the sampling flow rate, and the flux under atmospheric condition can be inferred from the measured flux and surface shear property. The demonstrated methodology potentially bridges the gap in measured fluxes obtained by the DFC method and the micrometeorological methods.

  15. Wave-Ice and Air-Ice-Ocean Interaction During the Chukchi Sea Ice Edge Advance

    DTIC Science & Technology

    2014-09-30

    Zone Based on a Rheological Parameterization Shen Proving and Improving Wave Models in the Arctic Ocean and its MIZ Wadhams and Doble Wave Climate ...arctic_sea_state Ackley, S.F. et al. (6 others), accepted, Surface Flooding of Antarctic summer sea ice, Annals of Glaciology (publication 2015) Ackley, S.F...E. Murphy and H. Xie (accepted), Ocean heat flux under Antarctic sea ice in the Bellingshausen and Amundsen Seas, Annals of Glaciology

  16. Atmospheric fluxes of 210Pb to the western Mediterranean Sea and the Saharan dust influence

    NASA Astrophysics Data System (ADS)

    Garcia-Orellana, J.; Sanchez-Cabeza, J. A.; Masqué, P.; ÀVila, A.; Costa, E.; Loã¿E-Pilot, M. D.; Bruach-MenchéN, J. M.

    2006-08-01

    Pb 210 is a well known tracer of particle dynamics in the marine environment. Geochemical models partially rely on the knowledge of its atmospheric input. Unfortunately, this is poorly known in the western Mediterranean Sea, especially regarding long-term records. In this work we have evaluated the 210Pb annual atmospheric flux to this region from the analysis of 12 soil cores collected from coastal and island sites and total atmospheric deposition collected in Corsica during 1 year. The 210Pb fluxes ranged from 34 ± 3 to 121 ± 12 Bq m-2 yr-1, with an average of 75 Bq m-2 yr-1, and were strongly correlated (R2 = 0.95) with mean annual rainfall. This provides the possibility to determine 210Pb fluxes in a given location if the mean annual rainfall is well known, a useful outcome for both marine biogeochemical and soil erosion studies in this region. We have also estimated the mean annual atmospheric flux of 210Pb due to Saharan dust events registered in total deposition north of Barcelona during the last 17 years, yielding a value of 20 Bq m-2 yr-1. This flux represents a fraction of about 16% of the total atmospheric deposition of 210Pb in this area, but it could be up to 50% in sites with lower rainfall.

  17. Seasonality in the flux of natural radionuclides and plutonium in the deep Sargasso Sea. Technical report

    SciTech Connect

    Bacon, M.P.; Fleer, A.P.; Deuser, W.G.

    1985-01-01

    A record of radionuclide fluxes at a deep-ocean station near Bermuda (32/sup 0/ 05 min N, 64/sup 0/ 15 min W) was obtained from analysis of a 3-year collection of sediment-trap samples. The trap was placed at a depth of 3200 m, 1000 m above the sea floor, and the samples were recovered at 2-month intervals. Concentrations of U-238, -234, Th-232, -230, -228, Pa-231, Pb-210, Po-210, and Pu-239 and -240 were measured in the trapped material. Most of the radionuclide activity was found in the <37-micron sieved fraction. All radionuclide fluxes showed seasonal variations in phase with the variations in total sediment flux, which had been previously shown to be closely tied to the annual cycle of primary production in the overlying surface water. Seasonal variations are especially noteworthy for Th-230 and Pa-231, considering that most of their production occurs in the water column below the euphotic zone. Evidently the seasonal influence is transmitted downward by the varying particle flux so that radionuclide scavenging rates at depth, as well as at the surface, are affected. It is suggested that this could be brought about by seasonal variations in the flux of marine snow or in the rate of fecal-matter production in the deep-water column. Keywords: Pelagic sedimentation.

  18. Episodic particle flux in the deep Sargasso Sea: an organic geochemical assessment

    NASA Astrophysics Data System (ADS)

    Conte, Maureen H.; Weber, J. C.; Ralph, Nathan

    1998-11-01

    Since 1978, the Oceanic Flux Program (OFP) time-series sediment trap study has continuously measured particle fluxes in the deep Sargasso Sea (31°50'N, 64°10'W). One feature of this 19+ year record has been the episodic occurrence of large, short-lived flux maxima that are not associated with the annual spring bloom. These maxima generally occur during the Dec.-Jan. period, but not necessarily every year. They have also occurred in other seasons. In January 1996, OFP traps located at 3200 and 3400 m depths intercepted a major flux "event" in which there was an abrupt, threefold increase in mass flux at both depths. Mass flux measured at 3200 m during the event (87 mg m -2 d -1) was the highest recorded since biweekly resolved sampling was begun in 1989. Organic biomarker analyses of material collected prior to, and during, this high flux event determined that there was an abrupt change in material composition associated with the sudden flux increase. Prior to the event, cholesterol, a single bacteriaderived C 27 hopanone (22,29,30-tris norhopan-21-one), and saturated and odd/branched fatty acids predominated: these compounds indicated that the sedimenting material was extensively degraded. During the event, organic material was greatly enriched in C 26-C 29 phytosterols, haptophyte algae-derived C 37-C 39 alkenones, labile polyunsaturated acids, degradation products such as steroidal ketones, and also in bacteria-derived compounds such as C 27-C 34 hopanoids and β and ω-1 hydroxy acids. These compounds indicated the organic fraction contained a large amount of relatively fresh phytoplankton-derived debris and tracers of bacterial biomass and metabolism, which suggested that the sinking material was undergoing active bacterial decomposition. Thus, the flux "event" appears to have resulted from a shortlived bloom in the overlying surface waters which, for reasons not currently apparent, was inefficiently remineralized in the upper ocean and rapidly settled to

  19. GRACE Mass Flux Measurements of Inland and Marginal Seas from Mascons: Analysis and Validation

    NASA Astrophysics Data System (ADS)

    Loomis, B.; Luthcke, S. B.; Sabaka, T. J.

    2015-12-01

    The latest GRACE time-variable gravity mascon solution from the NASA Goddard Space Flight Center (GSFC) applies an optimized set of models and constraints towards the direct measurement of 1-arc-degree global mass flux parameters each month. Separate mascon spatial constraint regions have been defined for the largest inland and marginal seas: Mediterranean Sea, Black Sea, Caspian Sea, Red Sea, and Hudson Bay. The mascon estimation approach, when applied with well-designed constraints, minimizes signal leakage across regional boundaries and eliminates the need for post-processing strategies. These post-processing techniques (e.g. smoothed averaging kernels) are necessary for computing regional mass change from the unconstrained spherical harmonics provided by the GRACE project to reduce the effect of noisy high degree and order terms, but introduce signal leakage into and out of the considered region. These mass signals are also difficult to obtain from altimetry measurements due to the comparatively sparse temperature and salinity data in these regions, which is needed to compute and remove the steric component of sea level variations. We provide new GSFC mascon measurements of these inland and marginal seas and compare to results obtained from kernel-averaged spherical harmonic solutions and steric-corrected altimetry measurements. The relative accuracy of the various solutions is determined by incorporating their output into the set of forward models applied in our processing of the GRACE Level-1B data and analyzing the effect on the inter-satellite range-rate residuals, where a reduction in residuals is a direct validation of improved solution quality.

  20. High-resolution simulations of heavy precipitation events: role of the Adriatic SST and air-sea interactions

    NASA Astrophysics Data System (ADS)

    Davolio, Silvio; Stocchi, Paolo

    2016-04-01

    Strong Bora and Sirocco winds over the Adriatic Sea favour intense air-sea interactions and are often associated with heavy rainfall that affects the mountainous areas surrounding the basin. A convection-permitting model (MOLOCH) has been implemented at high resolution (2 km) in order to analyse several precipitation events over northern Italy, occurred during different seasons of the year and presenting different rainfall characteristics (stratiform, convective, orographic), and to possibly identify the relevant physical mechanisms involved. With the aim of assessing the impact of the sea surface temperature (SST) and surface fluxes on the intensity and location of the rainfall, sensitivity experiments have been performed taking into account the possible variability of SST analysis for model initialization. The model has been validated and specific diagnostic tools have been developed and applied to evaluate the vertically integrated moisture fluxes feeding the precipitating system or to compute a water balance in the atmosphere over the sea. The results show that the Adriatic Sea plays a role in determining the boundary layer characteristics through exchange of heat and moisture thus modifying the low-level flow dynamics and its interaction with the orography. This in turn impacts on the rainfall. Although the results vary among the analysed events, the precise definition of the SST and its evolution can be relevant for accurate precipitation forecasting.

  1. Reconstruction of sediment flux from the Changjiang (Yangtze River) to the sea since the 1860s

    NASA Astrophysics Data System (ADS)

    Wang, Houjie; Yang, Zuosheng; Wang, Yan; Saito, Yoshiki; Liu, J. Paul

    2008-02-01

    SummaryThe Changjiang (Yangtze River) has been effectively gauged since the 1950s and demonstrates the transformation of a river system due to intensified human activities in its drainage basin over the past 50 yr. However, the 50-yr measurements of water and sediment are inadequate to show the long-term trend of sediment flux from the river to the sea or to capture the transition from natural to human dominance over the sediment flux. In this study we used the existing water discharge and sediment load records (1950s-2005) at the Hankou gauging station, together with water discharge recorded since 1865 at the same station, to reconstruct the changes of sediment flux to the sea since the 1860s. We established rating curves between stream discharge and suspended sediment concentration from the recent 50-yr data sets, which show that human disturbances have had a substantial impact on rating parameters. The commissioning of dams and undertaking of soil-conservation works have decreased sediment supply, leading to a decrease in the rating coefficient a of the rating curve equation Cs = aQb. The decreases in suspended sediment concentration have increased the erosive power of the river, and hence increased the rating exponent b. In particular, the commissioning of the Three Gorges Reservoir in 2003 resulted in a further increase of b, and channel scour in the middle and lower reaches has increased sediment flux to the sea to a level higher than sediment supply from the upper reaches. Our results suggest that the rating curves derived from 1954 to 1968 data are appropriate for estimating sediment loads for the period from 1865 to 1953, since both were periods of minimal human disturbance. This approach provides a time series of sediment loads from 1865 to 2005 at Hankou gauging station, which yields a time series of sediment flux from the Changjiang to the sea over the past 140 yr. The estimated mean annual sediment flux to the sea between 1865 and 1968 was ∼488 Mt

  2. Investigating Characteristics of Air-Sea Interactions in the Wave and Surface Layers

    DTIC Science & Technology

    2008-07-02

    momentum, heat , and moisture fluxes. To ensure the data quality from the Pelican aircraft, we did tower-aircraft turbulence comparisons based on...and sensible and latent heat fluxes as functions of the wave age and atmospheric stability using the LongEZ aircraft data collected during the...Influences of swell on sensible and latent heat fluxes We found that both heat and moisture fluxes are weak over swell-dominant-sea since the wind is

  3. Distribution and air-sea exchange of mercury (Hg) in polluted marine environments

    NASA Astrophysics Data System (ADS)

    Bagnato, E.; Sprovieri, M.; Bitetto, M.; Bonsignore, M.; Calabrese, S.; Di Stefano, V.; Oliveri, E.; Parello, F.; Mazzola, S.

    2012-04-01

    Mercury (Hg) is emitted in the atmosphere by anthropogenic and natural sources, these last accounting for one third of the total emissions. Since the pre-industrial age, the atmospheric deposition of mercury have increased notably, while ocean emissions have doubled owing to the re-emission of anthropogenic mercury. Exchange between the atmosphere and ocean plays an important role in cycling and transport of mercury. We present the preliminary results from a study on the distribution and evasion flux of mercury at the atmosphere/sea interface in the Augusta basin (SE Sicily, southern Italy), a semi-enclosed marine area affected by a high degree of contamination (heavy metals and PHA) due to the oil refineries placed inside its commercial harbor. It seems that the intense industrial activity of the past have lead to an high Hg pollution in the bottom sediments of the basin, whose concentrations are far from the background mercury value found in most of the Sicily Strait sediments. The release of mercury into the harbor seawater and its dispersion by diffusion from sediments to the surface, make the Augusta basin a potential supplier of mercury both to the Mediterranean Sea and the atmosphere. Based on these considerations, mercury concentration and flux at the air-sea interface of the Bay have been estimated using a real-time atomic adsorption spectrometer (LUMEX - RA915+) and an home-made accumulation chamber, respectively. Estimated Total Atmospheric Mercury (TGM) concentrations during the cruise on the bay were in the range of 1-3 ng · m-3, with a mean value of about 1.4 ng · m-3. These data well fit with the background Hgatm concentration values detected on the land (1-2 ng · m-3, this work), and, more in general, with the background atmospheric TGM levels found in the North Hemisphere (1.5-1.7 ng · m-3)a. Besides, our measurements are in the range of those reported for other important polluted marine areas. The mercury evasion flux at the air-sea interface

  4. South Atlantic sea surface temperature anomalies and air-sea interactions: stochastic models

    NASA Astrophysics Data System (ADS)

    Dobrovolski, S. G.

    1994-09-01

    Data on the South Atlantic monthly sea surface temperature anomalies (SSTA) are analysed using the maximum-entropy method. It is shown that the Markov first-order process can describe, to a first approximation, SSTA series. The region of maximum SSTA values coincides with the zone of maximum residual white noise values (sub-Antarctic hydrological front). The theory of dynamic-stochastic climate models is applied to estimate the variability of South Atlantic SSTA and air-sea interactions. The Adem model is used as a deterministic block of the dynamic-stochastic model. Experiments show satisfactorily the SSTA intensification in the sub-Antarctic front zone, with appropriate standard deviations, and demonstrate the leading role of the abnormal drift currents in these processes.

  5. Assessing the sensitivity of modeled air-sea CO2 exchange to the remineralization depth of particulate organic and inorganic carbon

    NASA Astrophysics Data System (ADS)

    Schneider, Birgit; Bopp, Laurent; Gehlen, Marion

    2008-09-01

    To assess the sensitivity of surface ocean pCO2 and air-sea CO2 fluxes to changes in the remineralization depth of particulate organic and inorganic carbon (POC, PIC), a biogeochemical ocean circulation model (PISCES) was run with different parameterizations for vertical particle fluxes. On the basis of fluxes of POC and PIC, productivity, export, and the distributions of nitrogen (NO3), dissolved inorganic carbon (DIC), and alkalinity, a number of indices defined to estimate the efficiency of carbon transport away from the atmosphere are applied. With differing success for the respective indices the results show that the more efficient the vertical transport of organic carbon toward depth, the lower the surface ocean pCO2, the higher the air-sea CO2 flux, and the stronger the increase in the oceanic inventory of DIC. Along with POC flux it is important to consider variations in PIC flux, as the net effect of particle flux reorganizations on surface ocean pCO2 is a combination of changes in DIC and alkalinity. The results demonstrate that changes in the mechanistic formulation of vertical particle fluxes have direct and indirect effects on surface ocean pCO2 and may thus interact with the atmospheric CO2 reservoir.

  6. Air-Sea Exchange and Atmospheric Cycling of Mercury in South China Sea

    NASA Astrophysics Data System (ADS)

    Tseng, C. M.; Liu, C. S.; Lamborg, C. H.

    2014-12-01

    Limited knowledge exists concerning the role of the low-latitude marginal seas in mercury (Hg) emissions on a global scale, especially tropical-subtropical and monsoon-dominated marginal seas in East Asia. To assess this potential mobilization of Hg through air-sea gas exchange, we have determined the dissolved elemental Hg (DEM) and gaseous elemental Hg (GEM) concentrations in surface seawater and atmosphere, respectively, during seasonal oceanographic cruises to the SouthEast Asian Time-series Study (SEATS) station (18 oN, 116 oE) from 2003 to 2007. The sampling and analysis of GEM and DEM were performed on board ship by using an on-line mercury analyzer (GEMA). Over the SCS, the GEM concentrations are elevated 2-3 times above global background values, with higher enhancements in the winter when the northeast monsoon draws air from China. The impact of long-range transport, as controlled by seasonal monsoons, has on the Hg atmospheric distribution and cycling in the SCS. The DEM concentration varied seasonally, with a high in summer and a low in winter and showed a positive correlation with sea surface temperature (SST). The elevated DEM concentration in summer appears mainly abiologically driven. In winter, the SCS acts as a sink of atmosphere Hg0 as a result of low SST and high wind of the year, enhanced vertical mixing and elevated atmospheric gaseous elemental mercury. Annually, the SCS serves as a source of Hg0 to the atmosphere of 300±50 pmol m-2 d-1 (390±60 kmol Hg y-1, ~2.6% of global emission in ~1% of global ocean area), suggesting high regional Hg pollution impacts from the surrounding Mainland (mostly China).

  7. Measurement of air and VOC vapor fluxes during gas-driven soil remediation: bench-scale experiments.

    PubMed

    Kim, Heonki; Kim, Taeyun; Shin, Seungyeop; Annable, Michael D

    2012-09-04

    In this laboratory study, an experimental method was developed for the quantitative analyses of gas fluxes in soil during advective air flow. One-dimensional column and two- and three-dimensional flow chamber models were used in this study. For the air flux measurement, n-octane vapor was used as a tracer, and it was introduced in the air flow entering the physical models. The tracer (n-octane) in the gas effluent from the models was captured for a finite period of time using a pack of activated carbon, which then was analyzed for the mass of n-octane. The air flux was calculated based on the mass of n-octane captured by the activated carbon and the inflow concentration. The measured air fluxes are in good agreement with the actual values for one- and two-dimensional model experiments. Using both the two- and three-dimensional models, the distribution of the air flux at the soil surface was measured. The distribution of the air flux was found to be affected by the depth of the saturated zone. The flux and flux distribution of a volatile contaminant (perchloroethene) was also measured by using the two-dimensional model. Quantitative information of both air and contaminant flux may be very beneficial for analyzing the performance of gas-driven subsurface remediation processes including soil vapor extraction and air sparging.

  8. Development and evaluation of an ammonia bidirectional flux parameterization for air quality models

    NASA Astrophysics Data System (ADS)

    Pleim, Jonathan E.; Bash, Jesse O.; Walker, John T.; Cooter, Ellen J.

    2013-05-01

    is an important contributor to particulate matter in the atmosphere and can significantly impact terrestrial and aquatic ecosystems. Surface exchange between the atmosphere and biosphere is a key part of the ammonia cycle. New modeling techniques are being developed for use in air quality models that replace current ammonia emissions from fertilized crops and ammonia dry deposition with a bidirectional surface flux model including linkage to a detailed biogeochemical and farm management model. Recent field studies involving surface flux measurements over crops that predominate in North America have been crucial for extending earlier bidirectional flux models toward more realistic treatment of NH3 fluxes for croplands. Comparisons of the ammonia bidirection flux algorithm to both lightly fertilized soybeans and heavily fertilized corn demonstrate that the model can capture the magnitude and dynamics of observed ammonia fluxes, both net deposition and evasion, over a range of conditions with overall biases on the order of the uncertainty of the measurements. However, successful application to the field experiment in heavily fertilized corn required substantial modification of the model to include new parameterizations for in-soil diffusion resistance, ground quasi-laminar boundary layer resistance, and revised cuticular resistance that is dependent on in-canopy NH3 concentration and RH at the leaf surface. This new bidirectional flux algorithm has been incorporated in an air quality modeling system, which also includes an implementation of a soil nitrification model.

  9. Seasonal and annual dynamics of particulate carbon flux in the Barents Sea

    SciTech Connect

    Wassmann, P. ); Slagstad, D. )

    1993-08-01

    Mathematical modelling was used to explore the seasonal and annual variability of primary, new and secondary production as well as sedimentation between 72[degrees] and 80[degrees]N in the central Barents Sea during the years 1981 to 1983. 1981 and 1982 were years with extensive ice coverage while 1983 experienced little sea-ice. The phyto-plankton [open quotes]spring[close quotes] bloom started usually in April/May at about 75[degrees]N and was delayed from May/June in the south to August/September in the north as a function of thermal stratification and sea-ice dynamics. The model indicates that several, simultaneous spring bloom events, separated in space, can be found, especially during years with low ice coverage. The annual estimates of primary production, secondary production and sedimentation decreased on average from 73, 7.3 and 48 to 18, 1.8 and 9 gCm[sup [minus]2] year[sup [minus]1] between the southern and the northern part of the Barents Sea respectively. The annual estimates of particular carbon flux were much higher in 1983 compared to 1981-1982, especially in the north where up to 6 times higher rates were calculated for 1983. The number of zooplankton species present in spring in the southern Barents Sea is governed by over-wintering success, but probably also influenced by advection of Atlantic water. The model was run for Atlantic water with 10,000, 3,000 or none copepods per m[sup 2] present in March, indicating that sedimentation can vary between 38 and 61 gCm[sup [minus]2] year[sup [minus]1] due to zooplankton grazing alone. This suggests that the supply of organic carbon to the aphotic zone of the Barents Sea is only partly determined by the strength and duration of phytoplankton blooms, but strongly influenced by zooplankton dynamics. 49 refs., 6 figs., 3 tabs.

  10. Tropical Intraseasonal Air-Sea Exchanges during the 1997 Pacific Warming

    NASA Technical Reports Server (NTRS)

    Sui, C.-H.; Lau, K.-M.; Chou, S.-H.; Wang, Zihou

    1999-01-01

    The Madden Julian Oscillations (MJO) and associated westerly wind (WW) events account for much of the tropical intraseasonal variability (TISV). The TISV has been suggested as an important stochastic forcing that may be one of the underlying causes for the observed irregularities of the El Nino-Southern Oscillation (ENSO). Recent observational studies and theories of interannual to interdecadal-scale variability suggest that ENSO may arise from different mechanisms depending on the basic states. The Pacific warming event of 1997, being associated with a period of strong MJO and WW events, serves as a natural experiment for studying the possible role of TISV in triggering an ENSO event. We have performed a combined statistical and composite analysis of surface WW events based on the assimilated surface wind and sea level pressure for the period of 1980-1993, the SSM/I wind for the period of 1988-1997, and OLR. Results indicates that extratropical forcing contribute significantly to the evolution of MJO and establishment of WW events over the Pacific warm pool. Following the major WW events, there appeared an eastward extension of equatorial warm SST anomalies from the western Pacific warm pool. Such tropical-extratropical interaction is particularly clear in the winter of 96-97 that leads to the recent warming event in 1997/98. From the above discussion, our current study on this subject is based on the hypothesis that 1) there is an enhanced air-sea interaction associated with TISV and the northerly surges from the extratropics in the initial phase of the 97/98 warming event, and 2) the relevant mechanisms are functions of the basic state of the coupled system (in terms of SST distribution and atmospheric mean circulation) that varies at the interannual and interdecadal time scale. We are analyzing the space-time structure of the northerly surges, their association with air-sea fluxes and upper ocean responses during the period of September 1996 to June 1997. The

  11. The SOLAS air-sea gas exchange experiment (SAGE) 2004

    NASA Astrophysics Data System (ADS)

    Harvey, Mike J.; Law, Cliff S.; Smith, Murray J.; Hall, Julie A.; Abraham, Edward R.; Stevens, Craig L.; Hadfield, Mark G.; Ho, David T.; Ward, Brian; Archer, Stephen D.; Cainey, Jill M.; Currie, Kim I.; Devries, Dawn; Ellwood, Michael J.; Hill, Peter; Jones, Graham B.; Katz, Dave; Kuparinen, Jorma; Macaskill, Burns; Main, William; Marriner, Andrew; McGregor, John; McNeil, Craig; Minnett, Peter J.; Nodder, Scott D.; Peloquin, Jill; Pickmere, Stuart; Pinkerton, Matthew H.; Safi, Karl A.; Thompson, Rona; Walkington, Matthew; Wright, Simon W.; Ziolkowski, Lori A.

    2011-03-01

    The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX's), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO 2, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF 6/ 3He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments. There was a significant increase in the photosynthetic competence ( Fv/ Fm) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX's, rates of net primary production and column-integrated chlorophyll a concentrations had

  12. Air-sea coupling in the Hawaiian Archipelago

    NASA Astrophysics Data System (ADS)

    Souza, J. M.; Powell, B.; Mattheus, D.

    2014-12-01

    A coupled numerical model is used to investigate the ocean-atmosphere interaction in the lee of the Hawaiian archipelago. The wind curl generated by the island blocking of the trade winds is known to give rise to ocean eddies; however, the impact of the sea surface temperature (SST) and velocity fronts associated with these eddies on the atmosphere is less understood. The main coupling mechanisms are: (i) changes in the near-surface stability and surface stress, (ii) vertical transfer of momentum from higher atmospheric levels to the ocean surface due to an increase of the turbulence in the boundary layer, (iii) secondary circulations associated with perturbations in the surface atmospheric pressure over the SST fronts, and (iv) the impact of the oceanic eddy currents on the net momentum transferred between the atmosphere and the ocean. To assess the relative contribution from each process, a coupled simulation between the Regional Ocean Modeling System (ROMS) and the Weather Research and Forecasting (WRF) models is conducted for the main Hawaiian Islands. The impact of the coupling, the perturbation of the mean wind pattern, and the different spatial scales involved in the air-sea exchanges of momentum and heat are explored.

  13. Antarctic Sea ice variations and seasonal air temperature relationships

    NASA Technical Reports Server (NTRS)

    Weatherly, John W.; Walsh, John E.; Zwally, H. J.

    1991-01-01

    Data through 1987 are used to determine the regional and seasonal dependencies of recent trends of Antarctic temperature and sea ice. Lead-lag relationships involving regional sea ice and air temperature are systematically evaluated, with an eye toward the ice-temperature feedbacks that may influence climatic change. Over the 1958-1087 period the temperature trends are positive in all seasons. For the 15 years (l973-l987) for which ice data are available, the trends are predominantly positive only in winter and summer, and are most strongly positive over the Antarctic Peninsula. The spatially aggregated trend of temperature for this latter period is small but positive, while the corresponding trend of ice coverage is small but negative. Lag correlations between seasonal anomalies of the two variables are generally stronger with ice lagging the summer temperatures and with ice leading the winter temperatures. The implication is that summer temperatures predispose the near-surface waters to above-or below-normal ice coverage in the following fall and winter.

  14. Downward biogenic fluxes in the SW Black Sea: dynamics of their compositional and temporal patterns

    NASA Astrophysics Data System (ADS)

    Bouloubassi, I.; Gogou, A.; Stavrakakis, S.; Sanchez-Vidal, A.; Grégoire, M.

    2012-04-01

    In the Black Sea, downward fluxes of biogenic elements in the water column were monitored during a 1 yr (2007-2008) sediment trap deployment in the SW basin (at 1000 and 2000 m water depth) aiming at appraising their amplitude, seasonal variability and prime controlling factors, and thus better assessing the biogeochemical functioning of this environment. Particulate organic carbon (POC) and carbonate fluxes display a strong seasonal pattern, with peak values in late autumn (POC) and early summer (carbonates). Mean POC fluxes at 1000 and 2000 m were 11.3 and 6 mg/m2/d, respectively, corresponding to 1.8 and 1 % of the estimated primary production. We used source-specific lipid biomarkers in order to determine the major phytoplankton contributors to the biogenic fluxes, as well as terrestrial organic inputs, and to shed light into the composition and variability of the biological system. These molecular data clearly demonstrate that diatoms (in particular Rhizosolenia species) are foremost drivers of the peak POC flux in late autumn. As expected, diatom productivity is also closely related with the patterns of the export opal fluxes. Furthermore, biomarkers document a major bloom of Emiliania Huxleyi in late spring/early summer, likely sustained by riverine nutrient inputs and/or regenerated nutrients. However, POC export is less strong during the coccolithophorid bloom. In contract, this bloom controls the unique peak value of carbonate flux. Dinoflagellate-specific biomarkers reveal a less prominent seasonal pattern, with higher values in late autumn and summer. In all the aforementioned periods biomarker tracers also evidence that zooplankton (and its fecal pellets) are important constituents of the export POC flux. As for the terrestrial inputs, they are mostly characterized by a high peak in late spring/early summer, when enhanced riverine discharges occur. Our findings demonstrate that the export of biogenic elements is closely linked to the structure of the

  15. Air-sea interactions during tropical cyclone in the Indian Ocean

    NASA Astrophysics Data System (ADS)

    Rashmi, R.; Vethamony, P.; Aboobacker, V. M.

    2012-04-01

    Estimation of air-sea momentum flux during tropical cyclone is one of the most important fields of study in wind - wave modeling and prediction. A number of studies suggested that the Charnock coefficient depends on the sea state. The Charnock coefficient (α) is firstly considered as a constant 0.0144 (Charnock, 1955). Toba et al. (1990) suggested that α increases with the wave age (β) based on the observations of mostly young waves in a wave flume, while Donelan (1990), Johnson et al. (1998), Lange et al. (2004), showed that α decreases with the wave age β. Moon et al. (2004) studied the effect of surface waves on Charnock coefficient under tropical cyclones and pointed out that the Charnock coefficient is mainly determined by two parameters: the wave age and the wind speed. Also there is a strong correlation between drag coefficient (Cd) and wave age (β) for each wind speed. When the wind speed is higher than 30 m/s, Cd will increase with β, otherwise Cd will decrease with increasing β. Amorocho et al. (1980) showed that three regions exist in the development of the wind stress: (i) a lower region in which the wind waves have not begun to break, for which drag coefficient (Cd) is approximately constant; (ii) a transitional region after the onset of breakers, for which Cd varies non-linearly with U10; (iii) a limiting region for which Cd tends again toward a constant value, and corresponds to a condition of breaker saturation. The three regions described above can be classified as 'low roughness', 'transitional', and 'high roughness', respectively. Wavewatch III model was used to study the air sea interaction during tropical cyclone in the Indian Ocean. ECMWF winds (2.5° x 2.5°) have been used for forcing the wave model. Air-sea momentum data was obtained by simulating wave fields of tropical cyclones during 1996 in the Indian Ocean. The wave parameters from the model results have been compared with measured buoy data and with merged altimeter data. The

  16. Effect of redox conditions on bacterial community structure in Baltic Sea sediments with contrasting phosphorus fluxes.

    PubMed

    Steenbergh, Anne K; Bodelier, Paul L E; Slomp, Caroline P; Laanbroek, Hendrikus J

    2014-01-01

    Phosphorus release from sediments can exacerbate the effect of eutrophication in coastal marine ecosystems. The flux of phosphorus from marine sediments to the overlying water is highly dependent on the redox conditions at the sediment-water interface. Bacteria are key players in the biological processes that release or retain phosphorus in marine sediments. To gain more insight in the role of bacteria in phosphorus release from sediments, we assessed the effect of redox conditions on the structure of bacterial communities. To do so, we incubated surface sediments from four sampling sites in the Baltic Sea under oxic and anoxic conditions and analyzed the fingerprints of the bacterial community structures in these incubations and the original sediments. This paper describes the effects of redox conditions, sampling station, and sample type (DNA, RNA, or whole-cell sample) on bacterial community structure in sediments. Redox conditions explained only 5% of the variance in community structure, and bacterial communities from contrasting redox conditions showed considerable overlap. We conclude that benthic bacterial communities cannot be classified as being typical for oxic or anoxic conditions based on community structure fingerprints. Our results suggest that the overall structure of the benthic bacterial community has only a limited impact on benthic phosphate fluxes in the Baltic Sea.

  17. [Verification of exhaled air temperature and heat flux in respiratory diseases as useful biomarker].

    PubMed

    Ito, Wataru; Chihara, Junichi

    2008-12-01

    Asthma, chronic obstructive pulmonary disease, and diffuse panbronchiolitis are syndromes associated with chronic airway inflammation. In the conventional definition of inflammation, local pyrexia at the site of inflammation should be observed. However, there are very few reports that have evaluated the "heat" in inflammatory respiratory diseases. We considered that the evaluation of allergic airway inflammation such as asthma might be possible by measuring the exhaled air temperature, and devised an original device that stabilizes the flow rate, which is a very important factor for the direct measurement of heat. Moreover, an expiratory heat flux meter, which can detect a change in air temperature more precisely and immediately, was also incorporated into our original device. As a result, we succeeded in the measurement and evaluation of the heat flux and air temperature in healthy subjects and asthmatic patients, and, further, the air temperature was straightforwardly evaluated by a portable spirometer including a temperature sensor. These findings suggest that the heat flux and temperature of exhaled air can be used to objectively monitor airway inflammation noninvasively, and assist in the diagnosis/monitoring of inflammatory respiratory diseases, including asthma.

  18. Element transformation rates and fluxes across the sediment-water interface of the Baltic Sea

    NASA Astrophysics Data System (ADS)

    Lipka, Marko; Wegwerth, Antje; Dellwig, Olaf; Al-Raei, Abdul M.; Schoster, Frank; Böttcher, Michael E.

    2014-05-01

    Organic matter is mineralized in brackish-marine sediments by microbial activity using predominantly oxygen, sulfate, and metal oxides as electron acceptors. This leads to a reflux of carbon dioxide into the bottom waters. Under anoxic bottom water conditions, sulfate reduction dominates. Under specific conditions, shallow methane may be oxidized. Pore water profiles reflect biogeochemical processes, transformation rates and fluxes of dissolved species across the sediment-water interface. They are controlled by different factors like microbial activity, bottom water redox conditions, and availability of electron acceptors/donors. Microbial activity in the sediment leads to changes in redox conditions, formation of metabolites and may lead to the formation of authigenic minerals. As an example, organic matter mineralization and reduction of iron oxyhydroxides both may lead to the liberation of dissolved phosphate thereby leading to a reflux into the bottom waters. Hypoxic conditions will enhance this process. We present the results of a detailed biogeochemical investigation of interstitial waters from shallow sediments to study the biogeochemical processes in recent sediments and associated element fluxes at the sediment-water-interface in different areas of the Baltic Sea. Pore water and sediment samples were retrieved from short sediment cores that were collected with multicoring devices in key regions of the Baltic Sea. Pore waters were taken in sufficient depth resolution and analyzed for main and trace element concentrations (e.g., Mn, SO4, HS, PO4, DIC) to allow a modelling of steady-state transformation volumetric rates and element fluxes. A quantitative interpretation of vertical concentration profiles in the pore waters was performed using a diffusion-based modelling approach. Element fluxes across the sediment-water interface show for the Baltic Sea a dependence from bottom water redox conditions, sedimentology, organic contents, and formation conditions

  19. Temporal variability of vertical export flux at the DYFAMED time-series station (Northwestern Mediterranean Sea)

    NASA Astrophysics Data System (ADS)

    Heimbürger, Lars-Eric; Lavigne, Héloïse; Migon, Christophe; D'Ortenzio, Fabrizio; Estournel, Claude; Coppola, Laurent; Miquel, Juan-Carlos

    2013-12-01

    The temporal evolution of the vertical export flux at the DYFAMED time-series station (Ligurian Sea) over the last 20 years reveals a strong interannual variability. Winter convection allows particulate (and dissolved) matter to be vertically exported (“flush-down” effect). The efficiency of this process determines also the concentration of nutrients brought to surface waters and, therefore, the intensity of the subsequent phytoplankton bloom. The sequence “convection-bloom” is the main driving force of vertical export flux in this region. The present work attempts to better identify the parameters that control vertical export flux dynamics by observing a 20 year time-series in relation with the temporal variability of mixed layer depth and surface primary production. The consequences of a more stratified water column in the future on biological productivity and vertical export flux are pointed out. In winter, the cooling of surface water, combined with evaporation, increases its density and determines the vertical convection. This allows for a rapid downward transfer of dissolved and particulate matter, yielding high vertical export flux. This “flush-down effect” results from a combination of convection and gravitational flux, since the diving of dense surface waters breaks the stratification of the water column and carries all material (particulate + dissolved) accumulated in the surface layer to depth. The rapid downward transfer of dissolved and particulate matter by this “flush-down effect” yields high vertical export fluxes. The magnitude of these fluxes may vary according to the amount of atmospheric material accumulated in surface waters during the preceding stratified period. In the present data set, highest vertical export fluxes were observed in 1999, 2003 and 2004. In those years, the MLD was greater (Fig. 2), suggesting a causal relationship between the efficiency of vertical mixing and the subsequent vertical export flux. In spring

  20. Effect of Wind Tunnel Air Velocity on VOC Flux from Standard Solutions and CAFO Manure/Wastewater

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Researchers and practitioners have used wind tunnels and flux chambers to quantify the flux of volatile organic compounds (VOCs), ammonia, and hydrogen sulfide and estimate emission factors from animal feeding operations (AFOs) without accounting for effects of air velocity or sweep air flow rate. L...

  1. Imaging air volume fraction in sea ice using non-destructive X-ray tomography

    NASA Astrophysics Data System (ADS)

    Crabeck, O.; Galley, R. J.; Delille, B.; Else, B. G. T.; Geilfus, N.-X.; Lemes, M.; Des Roches, M.; Francus, P.; Tison, J.-L.; Rysgaard, S.

    2015-09-01

    Although the presence of a gas phase in sea ice creates the potential for gas exchange with the atmosphere, the distribution of gas bubbles and transport of gases within the sea ice are still poorly understood. Currently no straightforward technique exists to measure the vertical distribution of air volume fraction in sea ice. Here, we present a new fast and non-destructive X-ray computed tomography technique to quantify the air volume fraction and produce separate 3-D images of air-volume inclusions in sea ice. The technique was performed on relatively thin (4-22 cm) sea ice collected from an experimental ice tank. While most of the internal layers showed air-volume fractions < 2 %, the ice-air interface (top 2 cm) systematically showed values up to 5 %. We suggest that the air volume fraction is a function of both the bulk ice gas saturation factor and the size of the brine channel. We differentiate micro bubbles (∅ < 1 mm), large bubbles (1 < ∅ < 5 mm) and macro bubbles (∅ > 5 mm). While micro bubbles were the most abundant type of air inclusions, most of the air porosity observed resulted from the presence of large and macro bubbles. The ice microstructure (granular and columnar) as well as the permeability state of ice are important factors controlling the air volume fraction. The technique developed is suited for studies related to gas transport and bubble migration and can help considerably improving parameterization of these processes in sea ice biogeochemical models.

  2. An improved whitecap timescale for sea spray aerosol production flux modeling using the discrete whitecap method

    NASA Astrophysics Data System (ADS)

    Callaghan, Adrian H.

    2013-09-01

    The discrete whitecap method (DWM) to model the sea spray aerosol (SSA) production flux explicitly requires a whitecap timescale, which up to now has only considered a whitecap decay timescale, τdecay. A reevaluation of the DWM suggests that the whitecap timescale should account for the total whitecap lifetime (τwcap), which consists of both the formation timescale (τform) and the decay timescale (timescale definitions are given in the text). Here values of τform for 552 oceanic whitecaps measured at the Martha's Vineyard Coastal Observatory on the east coast of the USA are presented, and added to the corresponding values of τdecay to form 552 whitecap timescales. For the majority of whitecaps, τform makes up about 20-25% of τwcap, but this can be as large as 70% depending on the value of τdecay. Furthermore, an area-weighted mean whitecap timescale for use in the DWM (τDWM) is defined that encompasses the variable nature of individual whitecap lifetimes within a given time period, and is calculated to be 5.3 s for this entire data set. This value is combined with previously published whitecap coverage parameterizations and estimates of SSA particle production per whitecap area to form a size-resolved SSA production flux parameterization (dF(r80)/dlog10r80). This parameterization yields integrated sea-salt mass fluxes that are largely within the range of uncertainty of recent measurements over the size range 0.029 µm < r80 < 0.580 µm. Physical factors controlling whitecap lifetime such as bubble plume lifetime and surfactant stabilization are discussed in the context of SSA production from whitecaps.

  3. Spatial and temporal patterns in oxygen and nutrient fluxes in sediment of German Bight (North Sea)

    NASA Astrophysics Data System (ADS)

    Neumann, Andreas; Friedrich, Jana; van Beusekom, Justus; Naderipour, Céline

    2016-04-01

    The German Bight in the southern North Sea is affected by intensive anthropogenic exploitation. Over a century of intensive use by shipping, fishery, and input by polluted rivers has pushed the coastal ecosystem far from its pristine state. The nutrient load reached a maximum in the early 1990s (Amann et al. 2012), and implementation of environmental protection policies substantially decreased the riverine nutrient load. While the riverine input of pollutants has constantly reduced since then, new forms of sea exploitation emerge. The most noticeable example is the installation of more than 600 wind turbines over the past few years in the German EEZ, and additionally 1,200 are already planned. The impact of these installations on hydrology and biogeochemical cycles is largely unclear. In a series of monitoring cruises we repeatedly sampled the sediment at a set of monitoring stations, which represent all typical habitats of the German Bight. We deployed benthic landers for in-situ chamber incubations and performed ex-situ whole-core incubations to investigate the benthic fluxes of oxygen and nutrients, and their spatial and temporal variability. Our first results indicate that benthic nutrient recycling is more intense during summer than during winter, which suggests that biological processes contribute substantially to the recycling of nutrients. The fluxes of reactive nitrogen appear lower than observations from 1992 (Lohse et al. 1993), when riverine N loads were at their maximum (Amann et al. 2012). The comparison of our recent measurements with observations from the past decades will enable us to assess the effect of decreasing nutrient discharge into the coastal North Sea. Our results will further set a baseline for elucidating the impact of the massive installation of wind turbines in the near future. This study contributes to the NOAH project (North Sea; Observation and Assessment of Habitats). References Amann T., A. Weiss, and J. Hartmann (2012): Carbon

  4. Wind farm induced changes in wind speed and surface fluxes over the North Sea

    NASA Astrophysics Data System (ADS)

    Chatterjee, Fabien; van Lipzig, Nicole; Meyers, Johan

    2016-04-01

    Offshore wind farm deployment in the North Sea is foreseen to expand dramatically in the coming years. The strong expansion of offshore wind parks is likely to affect the regional climatology on the North Sea. We assess this impact by conducting a regional climate model simulation over future wind farms built near the German coast. In order to achieve this, the wind farm parameterisation of Fitch et al. 2012, where wind farms are parameterised as elevated sources of turbulent kinetic energy and sinks of momentum ( Blahak et al 2010 and Fitch et al 2012) is implemented in COSMO-CLM at a 1.5 km resolution. As a first step, COSMO-CLM's ability to reproduce wind profiles over the North Sea is evaluated using wind speed data from the FINO1 meteorological mast, toghether with QuikScat scatterometer data, for a time period of 2000-2008. Subsequently, the impact of windfarms on the regional climate over a period of ten years (1999-2008) is assessed. A large scale wind farm can create wakes which depending on the wind direction could affect the power production of a neighbouring farm. Furthermore, wind farms decelerate the flow and create a vertical circulation in the inflow region. As a result, changes in vertical fluxes of moisture are observed. This leads to enhanced low level cloud cover which may trigger changes in precipitation.

  5. Shipboard Investigation of Air-sea Interaction and Cloud Processes in the VOCALS Stratocumulus Region

    NASA Astrophysics Data System (ADS)

    Fairall, C.; Kollias, P.; Zuidema, P.

    2005-12-01

    NOAA ETL, University of Miami, and Brookhaven National Laboratory have cooperated with the Woods Hole Oceanographic Institution (WHOI) for two research cruises to the stratocumulus region of Peru/Chile as part of NOAA's PACS/EPIC program. Ship-based measurements have taken in October of 2001, November 2003, and December 2004 at the WHOI ocean reference buoy at 20 S 85 W during the annual cruise to service the buoy. The goal of this work is to improve understanding of coupled air-sea processes in subtropical stratocumulus regions and to gather statistics on flux, boundary layer, and cloud properties to promote the evaluation of models and satellite data products. Specific scientific objectives involve improved bulk cloud-radiative parameterizations, methods for retrieving cloud microphysical properties, and investigation of the relative roles of cloud-top entrainment and drizzle production on the dynamics of stratocumulus. The measurements provide a more detailed context for measurements made on the WHOI buoy over the annual cycle. This will be achieved through: *Comprehensive characterization of clouds, surface fluxes, and PBL profiles using a variety of in situ and remote sensing systems *Evaluation of various bulk models of stratocumulus cloud radiative transfer properties using resulting cloud microphysics (integrated liquid water, drop size and number concentration) determined with ship-board remote sensors In this paper we will present the results from the three cruises emphasizing then diurnal cycle of cloud properties and comparing the seasonal differences.

  6. Surface heat fluxes and ecosystem function in the Cretan Sea (eastern Mediterranean): a modelling study

    NASA Astrophysics Data System (ADS)

    Siddorn, J. R.; Allen, J. I.

    2003-01-01

    As a component of the Mediterranean Forecast System Pilot Project, a data buoy was deployed in the Cretan Sea. A 1-D ecosystem model of the site has been used to investigate the role of surface heat fluxes in determining modelled ecosystem behaviour. The method of calculation of these fluxes, the quality of the data used, and the temporal resolution of the data all had an impact upon the modelled ecosystem function. The effects of the changes in heat flux formulation were substantial, with both annually averaged properties of the system and the seasonal evolution of the biology being affected. It was also found that the ecosystem model was extremely sensitive to the accuracy of the meteorological forcing data used, with substantial changes in biology found when offsets in the forcing data were imposed. The frequency of forcing data was relatively unimportant in determining the biological function, although lower frequency forcing damped high frequency variability in the biology. During periods of mixing the biology showed an amplified response to changes in physical dynamics, but during periods of stratification the variations in the physics were found to be less important. Zooplankton showed more sensitivity to physical variability than either phytoplankton or bacteria. The consequences for ecosystem modelling are discussed.

  7. The role of breaking wavelets in air-sea gas transfer

    NASA Astrophysics Data System (ADS)

    Csanady, G. T.

    1990-01-01

    Molecular diffusion sustains the flux of soluble gases on the water side of the air-sea interface. The "handover" of this flux to more efficient eddy mixing begins with the smallest eddies, of size l;, which interact with the surface diffusion boundary layer (DBL), of thickness δ. Owing to the discrepancy of the scales, δ ≪ l, the flow field on the δ scale consists of horizontal motions of a velocity constant with depth and varying horizontally on the l scale. The vertical velocity is proportional to the divergence of the horizontal flow and increases linearly with depth. An exact solution of the advection-diffusion equation for the simple model of divergent stagnation point flow shows the mass transfer coefficient (velocity) k to be proportional to (aD1/2) and DBL thickness δ to be proportional to (D/a1/2), where a is divergence, D diffusivity. Over a solid wall a similar model of Hiemenz flow yields a more complex relationship, also involving viscosity. These models reveal the mechanism by which the DBL is kept thin. The most intense surface divergences on a wind-blown sea surface are associated with rollers on breaking wavelets. Vorticity and divergence in the rollers are both proportional to u*2/v;, where u* is friction velocity and v is viscosity. The mass transfer coefficient resulting from divergences of this magnitude is then given by k = const u* Sc-1/2, where Sc is Schmidt number. Exact solutions of the advection-diffusion equation for model rollers reveal the details of the handover process. A thin DBL is maintained over divergences by the upward velocity. At convergences, narrow downward plumes convey DBL fluid into the turbulent interior. Flux lines (analogous to streamlines) are horizontal over divergences and dive down under convergences. Application to the sea surface requires a parameter quantifying the surface density of divergences. Laboratory data imply that a substantial fraction of the surface is covered by the divergences at higher wind

  8. Improvements to TOVS retrievals over sea ice and applications to estimating Arctic energy fluxes

    NASA Technical Reports Server (NTRS)

    Francis, Jennifer A.

    1994-01-01

    Modeling studies suggest that polar regions play a major role in modulating the Earth's climate and that they may be more sensitive than lower latitudes to climate change. Until recently, however, data from meteorological stations poleward of 70 degs have been sparse, and consequently, our understanding of air-sea-ice interaction processes is relatively poor. Satellite-borne sensors now offer a promising opportunity to observe polar regions and ultimately to improve parameterizations of energy transfer processes in climate models. This study focuses on the application of the TIROS-N operational vertical sounder (TOVS) to sea-ice-covered regions in the nonmelt season. TOVS radiances are processed with the improved initialization inversion ('3I') algorithm, providng estimates of layer-average temperature and moisture, cloud conditions, and surface characteristics at a horizontal resolution of approximately 100 km x 100 km. Although TOVS has flown continuously on polar-orbiting satellites since 1978, its potential has not been realized in high latitudes because the quality of retrievals is often significantly lower over sea ice and snow than over the surfaces. The recent availability of three Arctic data sets has provided an opportunity to validate TOVS retrievals: the first from the Coordinated Eastern Arctic Experiment (CEAREX) in winter 1988/1989, the second from the LeadEx field program in spring 1992, and the third from Russian drifting ice stations. Comparisons with these data reveal deficiencies in TOVS retrievals over sea ice during the cold season; e.g., ice surface temperature is often 5 to 15 K too warm, microwave emissivity is approximately 15% too low at large view angles, clear/cloudy scenes are sometimes misidentified, and low-level inversions are often not captured. In this study, methods to reduce these errors are investigated. Improvements to the ice surface temperature retrieval have reduced rms errors from approximately 7 K to 3 K; correction of

  9. Sensitivity of air-sea CO2-exchange and calcite saturation depth to the remineralization depth of marine particulate organic and inorganic carbon

    NASA Astrophysics Data System (ADS)

    Schneider, B.; Bopp, L.; Gehlen, M.

    2009-04-01

    The present study addresses the question of what would happen to air-sea CO2 exchange and the depth of the calcite saturation horizon (CSH) if the remineralization depth of particulate organic and inorganic carbon (POC, PIC) was changing. Therefore, a biogeochemical ocean circulation model (PISCES) was run with four different parameterizations for vertical particle fluxes, starting from the same initial conditions. Particle fluxes undergo strong changes induced by a combination of the respective mechanistic formulation of the vertical particle flux and the resulting ecosystem response. Reorganizations in dissolved properties are caused by (i) changed fluxes of POC and PIC; (ii) advection; (iii) air-sea CO2 exchange (DIC). The results show that the more (less) efficient the vertical transport of POC (PIC) from the surface toward depth, the lower the surface ocean pCO2, the higher the air-sea CO2 flux, and the stronger the increase in the oceanic inventory of DIC, and vice versa. Consequently, in one experiment the ocean is turning into a CO2 source to the atmosphere, in two cases it becomes a weak sink and in one simulation it turns into a strong sink. Surprisingly, results for changes in the CSH are more similar among the simulations at larger scale with a general deepening in the North Pacific and a shoaling elsewhere. In most areas the readjustment of the CSH is controlled by DIC and alkalinity acting both towards the simulated CSH shifts, however, in some cases DIC (alkalinity) is overcompensating for an effect that would occur due to changes in alkalinity (DIC), alone. In detail, the differences found between the experiments can be well explained by the respective particle flux responses. The current study shows that reorganizations in the vertical flux of particulate matter in the ocean may have immediate and longer-term effects on the marine carbon cycle which could potentially feedback on the climate system.

  10. The role of sea spray in cleansing air pollution over ocean via cloud processes.

    PubMed

    Rosenfeld, Daniel; Lahav, Ronen; Khain, Alexander; Pinsky, Mark

    2002-09-06

    Particulate air pollution has been shown to strongly suppress precipitation from convective clouds over land. New observations show that precipitation from similar polluted clouds over oceans is much less affected, because large sea salt nuclei override the precipitation suppression effect of the large number of small pollution nuclei. Raindrops initiated by the sea salt grow by collecting small cloud droplets that form on the pollution particles, thereby cleansing the air. Therefore, sea salt helps cleanse the atmosphere of the air pollution via cloud processes. This implies that over oceans, the climatic aerosol indirect effects are significantly smaller than current estimates.

  11. Improvement of the GEOS-5 AGCM upon Updating the Air-Sea Roughness Parameterization

    NASA Technical Reports Server (NTRS)

    Garfinkel, C. I.; Molod, A.; Oman, L. D.; Song, I.-S.

    2011-01-01

    The impact of an air-sea roughness parameterization over the ocean that more closely matches recent observations of air-sea exchange is examined in the NASA Goddard Earth Observing System, version 5 (GEOS-5) atmospheric general circulation model. Surface wind biases in the GEOS-5 AGCM are decreased by up to 1.2m/s. The new parameterization also has implications aloft as improvements extend into the stratosphere. Many other GCMs (both for operational weather forecasting and climate) use a similar class of parameterization for their air-sea roughness scheme. We therefore expect that results from GEOS-5 are relevant to other models as well.

  12. A study of the evolution of the surface heat flux off the southeast coast of the United States during a cold air outbreak using satellite remote sensing data

    NASA Technical Reports Server (NTRS)

    Vukovich, Fred M.; Dunn, J. W.; Crissman, Bobby W.

    1990-01-01

    Attention is given to the contribution of the marine boundary layer to storm development via a study of the evolution of the spatial distribution of the heat flux during a cold-air outburst (CAO) which occurred during the GALE Field Program period in a 550,000-sq-km area off the southeast coast of the United States. The study focuses on a CAO that occurred in the period February 24-26, 1986. During the CAO, the area averaged total surface heat flux ranged from 190 W/sq m to 1114 W/sq m. The high value was characterized by a lower average surface air and dew-point temperatures and a higher average surface wind speed. In general, the surface heat flux increased as the sea-surface temperatures on the continental shelf increased. It reached the maximum over the Gulf Stream, and then decreased over the eastern portions of the Gulf Stream and over the Sargasso Sea. The configuration conforms with some of the earlier findings of Bane and Osgoode (1989) and Blanton et al. (1989).

  13. Comparison of two closed-path cavity-based spectrometers for measuring air-water CO2 and CH4 fluxes by eddy covariance

    NASA Astrophysics Data System (ADS)

    Yang, Mingxi; Prytherch, John; Kozlova, Elena; Yelland, Margaret J.; Parenkat Mony, Deepulal; Bell, Thomas G.

    2016-11-01

    In recent years several commercialised closed-path cavity-based spectroscopic instruments designed for eddy covariance flux measurements of carbon dioxide (CO2), methane (CH4), and water vapour (H2O) have become available. Here we compare the performance of two leading models - the Picarro G2311-f and the Los Gatos Research (LGR) Fast Greenhouse Gas Analyzer (FGGA) at a coastal site. Both instruments can compute dry mixing ratios of CO2 and CH4 based on concurrently measured H2O, temperature, and pressure. Additionally, we used a high throughput Nafion dryer to physically remove H2O from the Picarro airstream. Observed air-sea CO2 and CH4 fluxes from these two analysers, averaging about 12 and 0.12 mmol m-2 day-1 respectively, agree within the measurement uncertainties. For the purpose of quantifying dry CO2 and CH4 fluxes downstream of a long inlet, the numerical H2O corrections appear to be reasonably effective and lead to results that are comparable to physical removal of H2O with a Nafion dryer in the mean. We estimate the high-frequency attenuation of fluxes in our closed-path set-up, which was relatively small ( ≤ 10 %) for CO2 and CH4 but very large for the more polar H2O. The Picarro showed significantly lower noise and flux detection limits than the LGR. The hourly flux detection limit for the Picarro was about 2 mmol m-2 day-1 for CO2 and 0.02 mmol m-2 day-1 for CH4. For the LGR these detection limits were about 8 and 0.05 mmol m-2 day-1. Using global maps of monthly mean air-sea CO2 flux as reference, we estimate that the Picarro and LGR can resolve hourly CO2 fluxes from roughly 40 and 4 % of the world's oceans respectively. Averaging over longer timescales would be required in regions with smaller fluxes. Hourly flux detection limits of CH4 from both instruments are generally higher than the expected emissions from the open ocean, though the signal to noise of this measurement may improve closer to the coast.

  14. Effect of air gap variation on the performance of single stator single rotor axial flux permanent magnet generator

    NASA Astrophysics Data System (ADS)

    Kasim, Muhammad; Irasari, Pudji; Hikmawan, M. Fathul; Widiyanto, Puji; Wirtayasa, Ketut

    2017-02-01

    The axial flux permanent magnet generator (AFPMG) has been widely used especially for electricity generation. The effect of the air gap variation on the characteristic and performances of single rotor - single stator AFPMG has been described in this paper. Effect of air gap length on the magnetic flux distribution, starting torque and MMF has been investigated. The two dimensional finite element magnetic method has been deployed to model and simulated the characteristics of the machine which is based on the Maxwell equation. The analysis has been done for two different air gap lengths which were 2 mm and 4 mm using 2D FEMM 4.2 software at no load condition. The increasing of air gap length reduces the air-gap flux density. For air gap 2 mm, the maximum value of the flux density was 1.04 T while 0.73 T occured for air gap 4 mm.. Based on the experiment result, the increasing air gap also reduced the starting torque of the machine with 39.2 Nm for air gap 2 mm and this value decreased into 34.2 Nm when the air gap increased to 4 mm. Meanwhile, the MMF that was generated by AFPMG decreased around 22% at 50 Hz due to the reduction of magnetic flux induced on stator windings. Overall, the research result showed that the variation of air gap has significant effect on the machine characteristics.

  15. Radar Remote Sensing of Ice and Sea State and Air-Sea Interaction in the Marginal Ice Zone

    DTIC Science & Technology

    2014-09-30

    1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Radar Remote Sensing of Ice and Sea State and Air-Sea...Interaction in the Marginal Ice Zone Hans C. Graber RSMAS – Department of Ocean Sciences Center for Southeastern Tropical Advanced Remote Sensing...scattering and attenuation process of ocean waves interacting with ice . A nautical X-band radar on a vessel dedicated to science would be used to follow the

  16. Changes in C37 alkenones flux on the eastern continental shelf of the Bering Sea: the record of Emiliania huxleyi bloom over the past 100 years

    NASA Astrophysics Data System (ADS)

    Harada, N.; Sato, M.; Okazaki, Y.; Oguri, K.; Tadai, O.; Saito, S.; Konno, S.; Jordan, R. W.; Katsuki, K.; Shin, K.; Narita, H.

    2008-12-01

    Flourishes of coccolithophores can be detected by ocean color imagery with data from the satellite-borne Sea-viewing Wide Field-of-view sensor SeaWiFs that was launched in 1997. Thus, temporally and spatially large-scale blooms of Emiliania huxleyi (E. huxleyi) have been distinguished annually in the eastern continental shelf of the Bering Sea since 1997. In 1997, a combination of atmospheric mechanisms produced summer weather anomalies such as calm winds, clear skies, and warm air temperature over the Bering Sea and the weather anomalies caused depletion of the subpycnocline nutrient reservoir (Napp and Hunt, 2001). After depletion of nitrate and silicate, a sustained (more than 4-month-long) bloom of E. huxleyi was observed (Stockwell et al., 2001). Because of the speed and magnitude with which parts of the Bering Sea ecosystem responded to changes in atmospheric factors (Napp and Hunt, 2001) and because a bloom of the coccolithophorid, Coccolithus pelagicus has also been detected in the northeastern Atlantic Ocean off Iceland every year since 1997 (Ostermann, 2001), the appearance of an E. huxleyi bloom in the Bering Sea could be related to atmospherically forced decadal oscillations or global factors. We have investigated spatial expansion and temporal development of E. huxleyi bloom on the continental shelf in the Bering Sea by using a biomarker of E. huxleyi, C37 alkenones flux recorded in the sediments during the past 100 years. As a result, the E. huxleyi bloom had been prominent since 1970"fs at latest during the last 100 years. In this presentation, we will discuss the relationship between E. huxleyi bloom and activity of Aleutian low, and also changes in diatom assemblages. References Napp and Hunt, 2001, Fish Oceanogr., 10, 61-68. Ostermann, 2001, WHOI annual report, pp.17-18. Stockwell et al., 2001, Fish Oceanogr., 10, 99-116.

  17. Flight crew fatigue III: North Sea helicopter air transport operations.

    PubMed

    Gander, P H; Barnes, R M; Gregory, K B; Graeber, R C; Connell, L J; Rosekind, M R

    1998-09-01

    We studied 32 helicopter pilots before, during, and after 4-5 d trips from Aberdeen, Scotland, to service North Sea oil rigs. On duty days, subjects awoke 1.5 h earlier than pretrip or posttrip, after having slept nearly an hour less. Subjective fatigue was greater posttrip than pretrip. By the end of trip days, fatigue was greater and mood more negative than by the end of pretrip days. During trips, daily caffeine consumption increased 42%, reports of headache doubled, reports of back pain increased 12-fold, and reports of burning eyes quadrupled. In the cockpits studied, thermal discomfort and high vibration levels were common. Subjective workload during preflight, taxi, climb, and cruise was related to the crewmembers' ratings of the quality of the aircraft systems. During descent and approach, workload was affected by weather at the landing site. During landing, it was influenced by the quality of the landing site and air traffic control. Beginning duty later, and greater attention to aircraft comfort and maintenance, should reduce fatigue in these operations.

  18. Re-examining the roles of surface heat flux and latent heat release in a "hurricane-like" polar low over the Barents Sea

    NASA Astrophysics Data System (ADS)

    Kolstad, Erik W.; Bracegirdle, Thomas J.; Zahn, Matthias

    2016-07-01

    Polar lows are intense mesoscale cyclones that occur at high latitudes in both hemispheres during winter. Their sometimes evidently convective nature, fueled by strong surface fluxes and with cloud-free centers, have led to some polar lows being referred to as "arctic hurricanes." Idealized studies have shown that intensification by hurricane development mechanisms is theoretically possible in polar winter atmospheres, but the lack of observations and realistic simulations of actual polar lows have made it difficult to ascertain if this occurs in reality. Here the roles of surface heat fluxes and latent heat release in the development of a Barents Sea polar low, which in its cloud structures showed some similarities to hurricanes, are studied with an ensemble of sensitivity experiments, where latent heating and/or surface fluxes of sensible and latent heat were switched off before the polar low peaked in intensity. To ensure that the polar lows in the sensitivity runs did not track too far away from the actual environmental conditions, a technique known as spectral nudging was applied. This was shown to be crucial for enabling comparisons between the different model runs. The results presented here show that (1) no intensification occurred during the mature, postbaroclinic stage of the simulated polar low; (2) surface heat fluxes, i.e., air-sea interaction, were crucial processes both in order to attain the polar low's peak intensity during the baroclinic stage and to maintain its strength in the mature stage; and (3) latent heat release played a less important role than surface fluxes in both stages.

  19. Riverine nutrients fluxes to the North Sea and harmful algal blooms, what changed since 1984 ?

    NASA Astrophysics Data System (ADS)

    Passy, Paul; Gypens, Nathalie; Billen, Gilles; Garnier, Josette; Thieu, Vincent; Rousseau, Véronique; Callens, Julie; Parent, Jean-Yves; Lancelot, Christiane

    2013-04-01

    Nutrients fluxes delivered to the coastal zones reflect human activities taking place within watersheds. Silica (Si) fluxes mainly originate from soils and rocks weathering, so they are few impacted by human activities. On the contrary, nitrogen (N) and phosphorus (P) fluxes are dramatically impacted by human activities. N originates from urban waste water but mainly from agricultural activities. P originates mostly from urban and industrial waste waters. The enrichment of the hydrosystems in N and P leads to an imbalance between N and P in one hand and Si in the other hand. This imbalance leads to harmful algal blooms, which are damaging aquatic ecosystems, fishing activities and touristic activities. In 1992, the OSPAR convention was signed by 15 European States and targets to decrease the N and P fluxes delivered to the European coastal zones by 50 % with respect to the reference year of 1985. Focusing on the Seine, Somme and Scheldt watersheds (France and Belgium) and the adjacent coastal zone of the North Sea, we developed a retrospective modelling from 1984 to 2007 calculating nutrients fluxes from watersheds and Phaeocystis blooms occurring in the coastal zone. We coupled the biogeochemical deterministic model Seneque/Riverstrahler depicting processes occurring within hydrological networks with the marine model MIRO simulating Phaeocystis blooms in the coastal zone. The evolution of N and P fluxes were highly dissimilar. Indeed, P mainly originates from point sources. Thereby the banishment of P from the washing powders during the nineties, the development of sewage and the improvement of WWTP in terms of waste water treatment lead to a decrease of P fluxes delivered to the coastal zone. This decrease can be observed for the three watersheds. The P OSPAR objective is achieved since the middle of the 2000's years. On the other side, N, mostly originating from agricultural diffuse sources, did not decrease over the period. The fluxes even increased at the

  20. Low benthic respiration and nutrient flux at the highly productive Amundsen Sea Polynya, Antarctica

    NASA Astrophysics Data System (ADS)

    Kim, Sung-Han; Choi, Ayeon; Jin Yang, Eun; Lee, SangHoon; Hyun, Jung-Ho

    2016-01-01

    We investigated rates of total oxygen uptake (TOU) sulfate reduction (SRR), and benthic nutrient flux (BNF) in sediments of polynya (730-825 m water depth), ice shelf (1064 m water depth), and marginal sea-ice zone (530 m water depth) to evaluate the role of benthic mineralization in degrading organic material produced by primary production in the Amundsen Sea polynya (ASP), Antarctica. Despite high primary production (110 mmol C m-2 d-1) in the water column, benthic carbon mineralization in the ASP (average, 2.1±0.3 mmol C m-2 d-1) was strikingly lower than in other less productive polar regions, accounting for only 1.9% of primary production. Low sediment accumulation rates (0.18-0.20 cm yr-1) and sinking fluxes of organic matter likely caused the low oxygen consumption rates (2.44-3.11 mmol m-2 d-1) and low effluxes of dissolved inorganic nitrogen (0.12-0.13 mmol m-2 d-1) and phosphate (0.017-0.018 mmol m-2 d-1) in the ASP. Carbon oxidation by sulfate reduction (0.11-0.19 mmol C m-2 d-1) comprised only 10% of total benthic mineralization, indicating that anaerobic C oxidation plays a minor role in total C oxidation. Our results, including low sediment accumulation rates and benthic metabolic rates, suggest that most organic carbon produced by Phaeocystis blooms would be respired to CO2 in the water column, and thus the organic carbon reaching the sediment is not adequate to stimulate benthic metabolism in the ASP.

  1. Effects of a sea breeze discontinuity on air quality in an industrial coastal environment of the North Sea

    NASA Astrophysics Data System (ADS)

    Augustin, Patrick; Sokolov, Anton; Talbot, Charles; Fourmentin, Marc; Willart, Véronique; Delbarre, Hervé

    2010-05-01

    The effects of interaction between the sea breeze and synoptic wind on air pollutants have been studied in an industrial coastal environment of the North Sea. These effects have been investigated, during one day, using ground-based remote sensing systems and surface station data alongside with mesoscale modelling outputs. During a campaign in the North of France, continuous lidar measurements documented the structure and the evolution of the lower troposphere. The combination of lidar, sodar and surface station observations showed that the atmospheric boundary layer is well stratified during the night, with a stable double layer structure which slows the growing process of the mixing layer, in the morning and before the sea-breeze onset. During the day, we observed discontinuity in meteorological measurements due to the sea-breeze occurrences. We have found that these sudden changes were well correlated with high concentrations of sulphur dioxide at ground level (up to 400 ?g/m3). The first sea breeze puff generates a change of the structure of the lower troposphere with a coupling between the residual layer and the convective boundary layer. The discontinuity of the sea-breeze gravity current is well observed by lidar signals and sodar echo. The analysis revealed that the impacts of the sea-breeze discontinuity have significant implications on the local and the regional pollution above industrialized areas. This phenomenon triggers important changes on the local and regional air quality, more particularly in urban and industrial coastal localities.

  2. Transition from downward to upward air-sea momentum transfer in swell-dominated light wind condition

    NASA Astrophysics Data System (ADS)

    Smedman, Ann-Sofi; Högström, Ulf; Rutgersson, Anna

    2016-04-01

    Atmospheric and surface wave data from two oceanic experiments carried out on FLIP and ASIS platforms are analysed in order to identify swell-related effects on the momentum exchange during low wind speed conditions. The RED experiment was carried out on board an R/P Floating Instrument Platform, FLIP, anchored north east of the Hawaiian island Oahu with sonic anemometers at four levels: 5.1 m, 6.9 m, 9.9 m and 13.8 m respectively. The meteorological conditions were characterized by north- easterly trade wind and with swell present during most of the time. During swell the momentum flux was directed downwards meaning a positive contribution to the stress. The FETCH experiment was carried out in the Gulf of Lion in the north-western Mediterranean Sea. On the ASIS (air-sea interaction spar) buoy a sonic anemometer was mounted at 7 m above the mean surface level. During strong swell conditions the momentum flux was directed upwards meaning a negative contribution to the stress in this case. The downward momentum flux is shown to be a function of the orbital circulation while the upward momentum flux is a function of wave height. The dividing wind speed is found to be 3.5 m/s Conclusion: Wind speed > 3.5 m/s creates waves (ripples) and thus roughness. Combination of orbital motion and asymmetric structure of ripples lead to flow perturbation and downward transport of negative momentum. With low wind speed (no ripples but viscosity) circulations will form above the crest and the trough with opposite direction which will cause a pressure drop in the vertical direction and an upward momentum transport from the water to the air.

  3. Advances in Linked Air Quality, Farm Management and Biogeochemistry Models to Address Bidirectional Ammonia Flux in CMAQ

    EPA Science Inventory

    Recent increases in anthropogenic inputs of nitrogen to air, land and water media pose a growing threat to human health and ecosystems. Modeling of air-surface N flux is one area in need of improvement. Implementation of a linked air quality and cropland management system is de...

  4. "Advances in Linked Air Quality, Farm Management and Biogeochemistry Models to Address Bidrectional Ammonia Flux in CMAQ"

    EPA Science Inventory

    Recent increases in anthropogenic inputs of nitrogen to air, land and water media pose a growing threat to human health and ecosystems. Modeling of air-surface N flux is one area in need of improvement. Implementation of a linked air quality and cropland management system is de...

  5. Numerical Simulation of Air Mass Modification Over the East China Sea during the Winter Season

    NASA Astrophysics Data System (ADS)

    Hsu, Wu-Ron

    Air mass modification over the East China Sea during cold air outbreaks in the winter season was simulated by utilizing a high-resolution numerical model. The model includes most of the major physical processes, such as, surface exchange of heat and moisture between water and air; condensation and evaporation; and vertical turbulent transfer of heat, moisture, and momentum. The simulated convective boundary layer (CBL) consists of a surface layer, a subcloud layer, and a cloud layer. It is capped by an inversion with strong temperature and moisture gradients. Mesoscale cellular convection (MCC) embedded within the convective layer moves along with the mean wind. The average aspect ratio of the cells is 17.5, which agrees with observed aspect ratios for convective cells over the East China Sea. The upward convective motion correlates very well with the appearance of clouds, higher temperature, and higher moisture content in the CBL. The effects of diabatic heating were found to be very important in driving the thermal convection. Without the release of latent heat, the convective layer would be very shallow, and the convective motion would be greatly suppressed. Even though the formulation and dissipation of a cloud is associated with the movement of the resolvable scale MCC, the vertical transport of heat and moisture is achieved mainly by the unresolvable turbulent eddies. The distribution of specific humidity during the passage of the surface front reveals the moisture being pushed upward along the frontal surface as observed. The cold and dry air behind the cold front is quickly modified by strong convection over the warm water surface, especially over the Kuroshio Current. A cloud-free region exists near the coast where the CBL is too shallow for clouds to develop. A layer of stratocumulus forms downstream from the cloud-free region. The depth of the CBL increases toward the Kuroshio Current due to strong heat and moisture fluxes from the water surface. The CBL

  6. Imaging air volume fraction in sea ice using non-destructive X-ray tomography

    NASA Astrophysics Data System (ADS)

    Crabeck, Odile; Galley, Ryan; Delille, Bruno; Else, Brent; Geilfus, Nicolas-Xavier; Lemes, Marcos; Des Roches, Mathieu; Francus, Pierre; Tison, Jean-Louis; Rysgaard, Søren

    2016-05-01

    Although the presence of a gas phase in sea ice creates the potential for gas exchange with the atmosphere, the distribution of gas bubbles and transport of gases within the sea ice are still poorly understood. Currently no straightforward technique exists to measure the vertical distribution of air volume fraction in sea ice. Here, we present a new fast and non-destructive X-ray computed tomography technique to quantify the air volume fraction and produce separate images of air volume inclusions in sea ice. The technique was performed on relatively thin (4-22 cm) sea ice collected from an experimental ice tank. While most of the internal layers showed air volume fractions < 2 %, the ice-air interface (top 2 cm) systematically showed values up to 5 %. We suggest that the air volume fraction is a function of both the bulk ice gas saturation factor and the brine volume fraction. We differentiate micro bubbles (Ø < 1 mm), large bubbles (1 mm < Ø < 5 mm) and macro bubbles (Ø > 5 mm). While micro bubbles were the most abundant type of gas bubbles, most of the air porosity observed resulted from the presence of large and macro bubbles. The ice texture (granular and columnar) as well as the permeability state of ice are important factors controlling the air volume fraction. The technique developed is suited for studies related to gas transport and bubble migration.

  7. Thermocline mixing and vertical oxygen fluxes in the stratified central North Sea

    NASA Astrophysics Data System (ADS)

    Rovelli, Lorenzo; Dengler, Marcus; Schmidt, Mark; Sommer, Stefan; Linke, Peter; McGinnis, Daniel F.

    2016-03-01

    In recent decades, the central North Sea has been experiencing a general trend of decreasing dissolved oxygen (O2) levels during summer. To understand potential causes driving lower O2, we investigated a 3-day period of summertime turbulence and O2 dynamics in the thermocline and bottom boundary layer (BBL). The study focuses on coupling biogeochemical with physical transport processes to identify key drivers of the O2 and organic carbon turnover within the BBL. Combining our flux observations with an analytical process-oriented approach, we resolve drivers that ultimately contribute to determining the BBL O2 levels. We report substantial turbulent O2 fluxes from the thermocline into the otherwise isolated bottom water attributed to the presence of a baroclinic near-inertial wave. This contribution to the local bottom water O2 and carbon budgets has been largely overlooked and is shown to play a role in promoting high carbon turnover in the bottom water while simultaneously maintaining high O2 concentrations. This process may become suppressed with warming climate and stronger stratification, conditions which could promote migrating algal species that potentially shift the O2 production zone higher up within the thermocline.

  8. Correlations Between Sea-Surface Salinity Tendencies and Freshwater Fluxes in the Pacific Ocean

    NASA Technical Reports Server (NTRS)

    Li, Zhen; Adamec, David

    2007-01-01

    Temporal changes in sea-surface salinity (SSS) from 21 years of a high resolution model integration of the Pacific Ocean are correlated with the freshwater flux that was used to force the integration. The correlations are calculated on a 1 x10 grid, and on a monthly scale to assess the possibility of deducing evaporation minus precipitation (E-P) fields from the salinity measurements to be taken by the upcoming Aquarius/SAC-D mission. Correlations between the monthly mean E-P fields and monthly mean SSS temporal tendencies are mainly zonally-oriented, and are highest where the local precipitation is relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude storm tracks and are relatively small in the tropics. The response of the model's surface salinity to surface forcing is very complex, and retrievals of freshwater fluxes from SSS measurements alone will require consideration of other processes, including horizontal advection and vertical mixing, rather than a simple balance between the two.

  9. Sea ice-atmosphere interaction. Application of multispectral satellite data in polar surface energy flux estimates

    NASA Technical Reports Server (NTRS)

    Steffen, Konrad; Key, Jeff; Maslanik, Jim; Haefliger, Marcel; Fowler, Chuck

    1992-01-01

    Satellite data for the estimation of radiative and turbulent heat fluxes is becoming an increasingly important tool in large-scale studies of climate. One parameter needed in the estimation of these fluxes is surface temperature. To our knowledge, little effort has been directed to the retrieval of the sea ice surface temperature (IST) in the Arctic, an area where the first effects of a changing climate are expected to be seen. The reason is not one of methodology, but rather our limited knowledge of atmospheric temperature, humidity, and aerosol profiles, the microphysical properties of polar clouds, and the spectral characteristics of the wide variety of surface types found there. We have developed a means to correct for the atmospheric attenuation of satellite-measured clear sky brightness temperatures used in the retrieval of ice surface temperature from the split-window thermal channels of the advanced very high resolution radiometer (AVHRR) sensors on-board three of the NOAA series satellites. These corrections are specified for three different 'seasons' and as a function of satellite viewing angle, and are expected to be applicable to the perennial ice pack in the central Arctic Basin.

  10. Distribution, abundance, and feeding ecology of decapods in the Arabian Sea, with implications for vertical flux

    NASA Astrophysics Data System (ADS)

    Mincks, Sarah L.; Bollens, Stephen M.; Madin, Laurence P.; Horgan, Erich; Butler, Mari; Kremer, Patricia M.; Craddock, James E.

    Macrozooplankton and micronekton samples were collected on two cruises in the Arabian Sea conducted during the Spring Intermonsoon period (May) and the SW Monsoon period (August) of 1995. Discrete depth samples were collected down to depths of 1000-1500 m. Quantitative gut content analyses were performed on four species of decapod shrimps, Gennadas sordidus, Sergia filictum, Sergia creber, and Eupasiphae gilesii, as well as on the pelagic crab Charybdis smithii. Of the shrimps, only S. filictum and S. creber increased significantly in abundance between the Spring Intermonsoon and SW Monsoon seasons. These four species were found at all depths sampled, and most did not appear to be strong vertical migrators. G. sordidus and S. filictum did appear to spread upward at night, especially during the SW Monsoon, but this movement did not include the entire population. S. creber showed signs of diel vertical migration only in some areas. All four shrimp species except, to some degree, S. creber lived almost exclusively within the oxygen minimum zone (150-1000 m), and are likely to have respiratory adaptations that allow them to persist under such conditions. Feeding occurred at all depths throughout these species' ranges, but only modest feeding occurred in the surface layer (0-150 m). G. sordidus appeared to feed continuously throughout the day and night. Estimated contribution of fecal material to vertical flux ranged from <0.01-2.1% of particulate flux at 1000 m for the shrimps and 1.8-3.0% for C. smithii.

  11. Carbon fluxes and export in the northern and middle Atlantic Sea measured with drifting sediment traps

    SciTech Connect

    Miquel, J-C; Fowler, S; Hamilton, T; Heilmann, J P; LaRosa, J; Carroll, M

    2000-07-26

    In July 1993 and June 1995 drifting sediment traps were deployed near the Po outflow, in the coastal zone and in the Jabuka Pit in order to obtain quantitative information on the vertical flux of particulate material and export of organic carbon in the Northern and Middle Adriatic Sea. During these periods and in July 1994, the standing stock of carbon and nitrogen in the water column were also estimated. Carbon and nitrogen concentrations were higher in the north with a mean of 266 {micro}g C l{sup -1} in surface waters as compared to 92 {micro}g C l{sup -1} in Middle Adriatic; maximum concentrations were associated to the less-saline surface-subsurface waters in the north and to the chlorophyll a maximum in the Middle Adriatic. Organic carbon flux was roughly five times higher near the Po than in the more oligotrophic waters of the central region, with overall values (0.8 to 11.5 mg m{sup -2} d{sup -1}) being low compared to the open Northwestern Mediterranean. Comparison with primary production measurements yielded estimates of carbon export (f-ratio) of 4.7 and 3.4% in the Po and Pit stations, respectively, in 1993 and of 1.6 and 3.6% in the central part of the Adriatic in 1995. These consistently low values suggest enhanced carbon recycling in the upper water column, even in regions characterized by different production and organic flux regimes. Zooplankton fecal pellets were important conveyors of organic carbon in this region; particularly those produced by fishes in the North and coastal sites.

  12. Carbon Flux to the Deep in three open sites of the Southern European Seas

    NASA Astrophysics Data System (ADS)

    Gogou*, A.; Sanchez-Vidal*, A.; Stavrakakis, S.; Durrieu de Madron, X.; Calafat, A. M.; Stabholz, M.; Psarra, S.; Canals, M.; Heussner, S.; Stavrakaki, I.; Papathanassiou, E.

    2012-04-01

    In this study we investigate the functioning of the biological pump in the Southern European Seas (SES). In order to constrain the rates of carbon production and export to depth, we combine estimations of satellite primary production data, algorithm-generated fluxes out of the euphotic layer and particulate organic carbon (POC) fluxes, as measured by sediment traps at the mesopelagic and bathypelagic layers in three sites located in the Western Mediterranean (WMED), the Eastern Mediterranean (EMED), and the Black Sea (BS). POC fluxes were monitored during one year period (Sept 2007 - Sept 2008) in the frame of SESAME project. Annual primary production by satellite estimations yielded values of 396 mg C m-2d-1 (EMED), 563 mg C m-2d-1 (WMED) and 617 mg C m-2d-1 (BS) (SeaWiFS; http://emis.jrc.ec.europa.eu). At the scale of the whole Mediterranean and the Black Sea basins, spatiotemporal variability of Chl-a concentrations during the time of our experiments revealed significant differences in the seasonal cycles. While the WMED site showed increased biomass centred around spring (March-April 2008), the EMED site showed higher values in mid-winter (January 2008), even thought almost one order of magnitude lower than those recorded in the western site. In contrast, the BS site showed increased Chl-a concentration in autumn (Nov 2007) and a lower increase in early spring (March 2008). Overall, the observed Chl-a seasonal patterns for the WMED and EMED sites match quite well the typical seasonal patterns ascribed to their hosting areas, corresponding to "blooming" and "non-blooming" biogeographic regions, respectively, as proposed by D'Ortenzio and Ribera d'Alcala (D'Ortenzio and Ribera d'Alcala, 2009). Moreover, based on the timing of the bloom (late fall) the seasonal pattern of the BS site is quite similar to that observed in Mediterranean regions having a "coastal" regime. Thus, specific physical and biogeochemical settings in the three contrasting sites affect the

  13. A study of the Merritt Island, Florida sea breeze flow regimes and their effect on surface heat and moisture fluxes

    NASA Technical Reports Server (NTRS)

    Rubes, M. T.; Cooper, H. J.; Smith, E. A.

    1993-01-01

    Data collected during the Convective and Precipitation/Electrification Experiment were analyzed as part of an investigation of the sea breeze in the vicinity of Merritt Island, Florida. Analysis of near-surface divergence fields shows that the classical 24-hour oscillation in divergence over the island due to the direct sea breeze circulation is frequently disrupted and exhibits two distinct modes: the classical sea breeze pattern and deviations from that pattern. A comparison of clear day surface energy fluxes with fluxes on other days indicates that changes in magnitudes were dominated by the presence or absence of clouds. Non-classical sea breeze days tended to lose more available energy in the morning than classical sea breeze days due to earlier development of small cumulus over the island. A composite storm of surface winds, surface energy fluxes, rainfall, and satellite visible data was constructed. A spectral transmittance over the visible wavelengths for the cloud cover resulting from the composite storm was calculated. It is shown that pre-storm transmittances of 0.8 fall to values near 0.1 as the downdraft moves directly over the site. It is also found that under post-composite storm conditions of continuous clear sky days, 3.5 days are required to evaporate back into the atmosphere the latent heat energy lost to the surface by rainfall.

  14. Determination of temperature dependent Henry's law constants of polychlorinated naphthalenes: Application to air-sea exchange in Izmir Bay, Turkey

    NASA Astrophysics Data System (ADS)

    Odabasi, Mustafa; Adali, Mutlu

    2016-12-01

    The Henry's law constant (H) is a crucial variable to investigate the air-water exchange of persistent organic pollutants. H values for 32 polychlorinated naphthalene (PCN) congeners were measured using an inert gas-stripping technique at five temperatures ranging between 5 and 35 °C. H values in deionized water (at 25 °C) varied between 0.28 ± 0.08 Pa m3 mol-1 (PCN-73) and 18.01 ± 0.69 Pa m3 mol-1 (PCN-42). The agreement between the measured and estimated H values from the octanol-water and octanol-air partition coefficients was good (measured/estimated ratio = 1.00 ± 0.41, average ± SD). The calculated phase change enthalpies (ΔHH) were within the interval previously determined for other several semivolatile organic compounds (42.0-106.4 kJ mol-1). Measured H values, paired atmospheric and aqueous concentrations and meteorological variables were also used to reveal the level and direction of air-sea exchange fluxes of PCNs at the coast of Izmir Bay, Turkey. The net PCN air-sea exchange flux varied from -0.55 (volatilization, PCN-24/14) to 2.05 (deposition, PCN-23) ng m-2 day-1. PCN-19, PCN-24/14, PCN-42, and PCN-33/34/37 were mainly volatilized from seawater while the remaining congeners were mainly deposited. The overall number of the cases showing deposition was higher (67.9%) compared to volatilization (21.4%) and near equilibrium (10.7%).

  15. A 400-year record of black carbon flux in the Xisha archipelago, South China Sea and its implication.

    PubMed

    Liu, Xiaodong; Xu, Liqiang; Sun, Liguang; Liu, Fei; Wang, Yuhong; Yan, Hong; Liu, Yi; Luo, Yuhan; Huang, Jing

    2011-10-01

    We reconstructed the first long-term (∼ 400 years) records of black carbon (BC) deposition flux from three ornithogenic sediment profiles, which were collected from three remote, isolated islets of the Xisha archipelago, South China Sea. The significant correlations between black carbon, organic matter and excess (210)Pb suggested that black carbon was mainly derived from atmospheric deposition, and further enriched by plant-derived organic matter in sediments. During the past 400 years, the BC flux remained relatively low before the onset of 20th century; it started to increase from approximately 1900 AD, and peaked around the 1970s. In the recent 30 years, the BC flux seemed to display decreasing trend, very likely due to the change of energy structure and development of pollution control techniques. In comparison with marginal sea regions that are greatly impacted by anthropogenic activities, these pristine Xisha islands were not significantly influenced by black carbon of anthropogenic origin.

  16. Sensitivity of contemporary sea level trends in a global ocean state estimate to effects of geothermal fluxes

    NASA Astrophysics Data System (ADS)

    Piecuch, Christopher G.; Heimbach, Patrick; Ponte, Rui M.; Forget, Gaël

    2015-12-01

    Geothermal fluxes constitute a sizable fraction of the present-day Earth net radiative imbalance and corresponding ocean heat uptake. Model simulations of contemporary sea level that impose a geothermal flux boundary condition are becoming increasingly common. To quantify the impact of geothermal fluxes on model estimates of contemporary (1993-2010) sea level changes, two ocean circulation model experiments are compared. The two simulations are based on a global ocean state estimate, produced by the Estimating the Circulation and Climate of the Ocean (ECCO) consortium, and differ only with regard to whether geothermal forcing is applied as a boundary condition. Geothermal forcing raises the global-mean sea level trend by 0.11 mm yr-1 in the perturbation experiment by suppressing a cooling trend present in the baseline solution below 2000 m. The imposed forcing also affects regional sea level trends. The Southern Ocean is particularly sensitive. In this region, anomalous heat redistribution due to geothermal fluxes results in steric height trends of up to ± 1 mm yr-1 in the perturbation experiment relative to the baseline simulation. Analysis of a passive tracer experiment suggests that the geothermal input itself is transported by horizontal diffusion, resulting in more thermal expansion over deeper ocean basins. Thermal expansion in the perturbation simulation gives rise to bottom pressure increase over shallower regions and decrease over deeper areas relative to the baseline run, consistent with mass redistribution expected for deep ocean warming. These results elucidate the influence of geothermal fluxes on sea level rise and global heat budgets in model simulations of contemporary ocean circulation and climate.

  17. Annual variability and regulation of methane and sulfate fluxes in Baltic Sea estuarine sediments

    NASA Astrophysics Data System (ADS)

    Sawicka, Joanna E.; Brüchert, Volker

    2017-01-01

    Marine methane emissions originate largely from near-shore coastal systems, but emission estimates are often not based on temporally well-resolved data or sufficient understanding of the variability of methane consumption and production processes in the underlying sediment. The objectives of our investigation were to explore the effects of seasonal temperature, changes in benthic oxygen concentration, and historical eutrophication on sediment methane concentrations and benthic fluxes at two type localities for open-water coastal versus eutrophic, estuarine sediment in the Baltic Sea. Benthic fluxes of methane and oxygen and sediment pore-water concentrations of dissolved sulfate, methane, and 35S-sulfate reduction rates were obtained over a 12-month period from April 2012 to April 2013. Benthic methane fluxes varied by factors of 5 and 12 at the offshore coastal site and the eutrophic estuarine station, respectively, ranging from 0.1 mmol m-2 d-1 in winter at an open coastal site to 2.6 mmol m-2 d-1 in late summer in the inner eutrophic estuary. Total oxygen uptake (TOU) and 35S-sulfate reduction rates (SRRs) correlated with methane fluxes showing low rates in the winter and high rates in the summer. The highest pore-water methane concentrations also varied by factors of 6 and 10 over the sampling period with the lowest values in the winter and highest values in late summer-early autumn. The highest pore-water methane concentrations were 5.7 mM a few centimeters below the sediment surface, but they never exceeded the in situ saturation concentration. Of the total sulfate reduction, 21-24 % was coupled to anaerobic methane oxidation, lowering methane concentrations below the sediment surface far below the saturation concentration. The data imply that bubble emission likely plays no or only a minor role in methane emissions in these sediments. The changes in pore-water methane concentrations over the observation period were too large to be explained by temporal

  18. A semianalytical algorithm for quantitatively estimating sediment and atmospheric deposition flux from MODIS-derived sea ice albedo in the Bohai Sea, China

    NASA Astrophysics Data System (ADS)

    Xu, Zhantang; Hu, Shuibo; Wang, Guifen; Zhao, Jun; Yang, Yuezhong; Cao, Wenxi; Lu, Peng

    2016-05-01

    Quantitative estimates of particulate matter [PM) concentration in sea ice using remote sensing data is helpful for studies of sediment transport and atmospheric dust deposition flux. In this study, the difference between the measured dirty and estimated clean albedo of sea ice was calculated and a relationship between the albedo difference and PM concentration was found using field and laboratory measurements. A semianalytical algorithm for estimating PM concentration in sea ice was established. The algorithm was then applied to MODIS data over the Bohai Sea, China. Comparisons between MODIS derived and in situ measured PM concentration showed good agreement, with a mean absolute percentage difference of 31.2%. From 2005 to 2010, the MODIS-derived annual average PM concentration was approximately 0.025 g/L at the beginning of January. After a month of atmospheric dust deposition, it increased to 0.038 g/L. Atmospheric dust deposition flux was estimated to be 2.50 t/km2/month, similar to 2.20 t/km2/month reported in a previous study. The result was compared with on-site measurements at a nearby ground station. The ground station was close to industrial and residential areas, where larger dust depositions occurred than in the sea, but although there were discrepancies between the absolute magnitudes of the two data sets, they demonstrated similar trends.

  19. [Diurnal variations of greenhouse gas fluxes at the water-air interface of aquaculture ponds in the Min River estuary].

    PubMed

    Yang, Ping; Tong, Chuan; He, Qing-Hua; Huang, Jia-Fang

    2012-12-01

    Wetland reclamation and aquaculture is one of the main disturbance types in coastal wetlands. Diurnal variations of CO2, CH4 and N2O fluxes at the water-air interface were determined using a floating chambers + gas chromatography method in a shrimp pond, and a mixed culture pond of fish and shrimp in October in the Shanyutan Wetland of the Min River estuary, southeast China. Meanwhile, the meteorological indicators in ground surface and physical, chemical and biological indicators of surface water were also measured. CO2, CH4 and N2O fluxes at the water-air interface all demonstrated distinct diurnal variations. Both shrimp pond and mixed culture pond of fish and shrimp functioned as a sink of CO2 [the diurnal averaged CO2 fluxes were -48.79 and -105.25 mg x (m2 x h)(-1), respectively], and a source of CH4 [the diurnal averaged CH4 fluxes were 1.00 and 5.74 mg x (m2 x h)(-1), respectively]; the diurnal averaged CO2 and CH4 fluxes at the water-air interface of the mixed culture of fish and shrimp pond were higher than that of the shrimp pond. Greenhouse gas fluxes at the water-air interface from the aquaculture ponds were influenced by many factors. Multiple stepwise regression analysis showed that the concentration of Chlorophyll was the major factor affecting the CO2 fluxes, and the concentrations of SO4(2-) and PO4(3-) were the major factors affecting the CH4 fluxes at the water-air interface of the shrimp pond; whereas water temperature and Chlorophyll were the major factors affecting the CO2 fluxes, and dissolved oxygen, PO4(3-) and pH were the major factors affecting the CH4 fluxes at the water-air interface of the mixed culture pond of fish and shrimp.

  20. Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

    USGS Publications Warehouse

    Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

    2014-01-01

    Mangrove forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h−1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m−2 d−1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.

  1. Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

    NASA Astrophysics Data System (ADS)

    Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

    2014-01-01

    forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h-1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m-2 d-1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.

  2. A Simple Scheme for Estimating Turbulent Heat Flux over Landfast Arctic Sea Ice from Dry Snow to Advanced Melt

    NASA Astrophysics Data System (ADS)

    Raddatz, R. L.; Papakyriakou, T. N.; Else, B. G.; Swystun, K.; Barber, D. G.

    2015-05-01

    We describe a dynamic-parameter aggregation scheme to estimate hourly turbulent heat fluxes over landfast sea ice during the transition from winter to spring. Hourly albedo measurements are used to track the morphology of the surface as it evolved from a fairly smooth homogeneous dry snow surface to a rougher heterogeneous surface with spatially differential melting and melt ponds. The estimates of turbulent heat fluxes for 928 h are compared with eddy-covariance measurements. The model performance metrics (W m) for sensible heat flux were found to be: mean bias , root-mean-square error 6 and absolute accuracy 4, and for latent heat flux near zero, 3 and 2, respectively. The correlation coefficient between modelled and measured sensible heat fluxes was 0.82, and for latent heat fluxes 0.88. The turbulent heat fluxes were estimated more accurately without adjustments than with adjustments for atmospheric stability based on the bulk Richardson number. Overall, and across all metrics for both sensible and latent heat fluxes, the dynamic-parameter aggregation scheme outperformed the static Community Ice (C-ICE) scheme, part of the Community Climate System model, applied to the same winter-to-spring transition period.

  3. Bayesian Hierarchical Air-Sea Interaction Modeling: Application to the Labrador Sea

    NASA Technical Reports Server (NTRS)

    Niiler, Pearn P.

    2002-01-01

    The objectives are to: 1) Organize data from 26 MINIMET drifters in the Labrador Sea, including sensor calibration and error checking of ARGOS transmissions. 2) Produce wind direction, barometer, and sea surface temperature time series. In addition, provide data from historical file of 150 SHARP drifters in the Labrador Sea. 3) Work with data interpretation and data-modeling assimilation issues.

  4. Sea-air of CO2 in the North Pacific using shipboard and satellite data

    NASA Technical Reports Server (NTRS)

    Stephens, Mark P.; Samuels, Geoffrey; Olson, Donald B.; Fine, Rana A.; Takahashi, Taro

    1995-01-01

    A method has been developed to produce high-resolution maps of pCO2 in surface water for the North Pacific using satellite sea surface temperature (SST) data and statistical relationships between measured pCO2 and temperature. In the subtropical North Pacific the pCO in seawater is controlled primarily by temperature. Accordingly, pCO2 values that are calculated from the satellite SST data have good agreement with the measured values (rms deviation of +/- microatm). In the northwestern subpolar region the pCO2 is controlled not only by temperature, but also by significant seasonal changes in the total CO2 concentration, which are caused by seasonal changes in primary production, mixing with subsurface waters and sea-air exchange. Consequently, the parameterization of oceanic p CO2 based on SST data alone is not totally successful in the northwestern region (rms deviation of +/- 40 microatm). The use of additional satellite products, such as wind and ocean color data, as planned for a future study, is considered necessary to account for the pCO2 variability caused by seasonal changes in the total CO2 concentration. The net CO2 flux for the area of the North Pacific included in this study (north of 10 deg N) has been calculated using the monthly pCO2 distributions computed, and monthly wind speeds from the European Centre for Medium-Range Weather Forecasts. The region is found to be a net source to the atmosphere of 1.9 x 10(exp 12) to 5.8 x 10(exp 12) moles of CO2 per year (or 0.02-0.07 Gt C/yr), most of the outflux occurring in the subtropics.

  5. Observed air-sea interactions in tropical cyclone Isaac over Loop Current mesoscale eddy features

    NASA Astrophysics Data System (ADS)

    Jaimes, Benjamin; Shay, Lynn K.; Brewster, Jodi K.

    2016-12-01

    Air-sea interactions during the intensification of tropical storm Isaac (2012) into a hurricane, over warm oceanic mesoscale eddy features, are investigated using airborne oceanographic and atmospheric profilers. Understanding these complex interactions is critical to correctly evaluating and predicting storm effects on marine and coastal facilities in the Gulf of Mexico, wind-driven mixing and transport of suspended matter throughout the water column, and oceanic feedbacks on storm intensity. Isaac strengthened as it moved over a Loop Current warm-core eddy (WCE) where sea surface warming (positive feedback mechanism) of ∼0.5 °C was measured over a 12-h interval. Enhanced bulk enthalpy fluxes were estimated during this intensification stage due to an increase in moisture disequilibrium between the ocean and atmosphere. These results support the hypothesis that enhanced buoyant forcing from the ocean is an important intensification mechanism in tropical cyclones over warm oceanic mesoscale eddy features. Larger values in equivalent potential temperature (θE = 365   ∘K) were measured inside the hurricane boundary layer (HBL) over the WCE, where the vertical shear in horizontal currents (δV) remained stable and the ensuing cooling vertical mixing was negligible; smaller values in θE (355   ∘K) were measured over an oceanic frontal cyclone, where vertical mixing and upper-ocean cooling were more intense due to instability development in δV . Thus, correctly representing oceanic mesoscale eddy features in coupled numerical models is important to accurately reproduce oceanic responses to tropical cyclone forcing, as well as the contrasting thermodynamic forcing of the HBL that often causes storm intensity fluctuations over these warm oceanic regimes.

  6. Air-sea CO2 exchange process in the southern Yellow Sea in April of 2011, and June, July, October of 2012

    NASA Astrophysics Data System (ADS)

    Qu, Baoxiao; Song, Jinming; Yuan, Huamao; Li, Xuegang; Li, Ning

    2014-06-01

    The partial pressure of CO2 (pCO2) and air-sea CO2 exchange flux (FCO2) in the southern Yellow Sea (SYS, 120-125°E, 31.5-37°N) were investigated basing on the field surveys conducted in April of 2011, and June, July, October of 2012. With significant spatial variations, surface pCO2 ranged from 243 to 574 μatm, 206 to 620 μatm, 102 to 655 μatm and 328 to 557 μatm in April, June, July and October, respectively. Nearshore area of Shandong Peninsula and Jiangsu Shallow (depth<50 m) were pCO2-supersaturated (pCO2=400-600 μatm), as the result of intensive water mixing which brought the bottom CO2-rich water to the surface layer. Conversely, offshore area of SYS center (depth>50 m) was pCO2-undersaturated (pCO2<390 μatm) in April, June and October, but supersaturated in July. Phytoplankton production sustained by abundant nutrient and suitable hydrodynamic conditions was of great importance for this undersaturated pCO2. Moreover, extreme low pCO2 (pCO2<300 μatm) was observed in the Changjiang plume (32.5-33.5°N, 123-125°E) in July, which was also related with the biological uptake of CO2. Average air-sea CO2 exchange flux of the SYS in April, June, July and October was -3.16±0.40 mmol m-2 d-1, -4.56±0.34 mmol m-2 d-1, -0.36±0.51 mmol m-2 d-1, and 6.67±0.57 mmol m-2 d-1, respectively. As a whole, the SYS behaved as a weak CO2 sink during April to October, with an average flux for about -0.35 mmol m-2 d-1. As for the controlling factors for pCO2 variation, temperature played the dominant role in October, whereas the non-temperature factors, such as vertical mixing, Changjiang plume and biological activity, were considered as the primary controlling factors in June and July. Spatially, the control of temperature on pCO2 was predominant in the offshore SYS; the non-temperature factors were predominant in the shallow nearshore area, especially in coast of Shandong Peninsula and the Jiangsu Shallow.

  7. The impact of sea breeze under different synoptic patterns on air pollution within Athens basin.

    PubMed

    Mavrakou, Thaleia; Philippopoulos, Kostas; Deligiorgi, Despina

    2012-09-01

    Air quality in densely populated urban coastal areas is directly related to the coupling of the synoptic and the local scale flows. The dispersion conditions within Athens basin, under the influence of different meteorological forcings, lead to distinct spatio-temporal air pollution patterns. The aim of the current observational research is to identify and examine the effect of sea breeze under different atmospheric circulation patterns on air pollution levels for a one-year study period (2007). The study employs surface pressure maps, routine meteorological observations at two coastal sites and nitrogen monoxide (NO), nitrogen dioxide (NO(2)) and ozone (O(3)) concentrations from a network of four air quality stations within the Athens basin. A three-step methodology is applied that incorporates a set of criteria for classifying atmospheric circulation and identifying sea breeze events under each circulation pattern. Two types of sea breeze development are identified (pure sea breeze-PSB and modified sea breeze-MSB) with distinct characteristics. Sea breeze is found to develop more frequently under offshore compared to onshore and parallel to the shoreline background flows. Poor dispersion conditions (high nitrogen oxides-NO(x) and O(3) concentrations) are connected to the pure sea breeze cases and to those cases where sea breeze interacts with a moderate northerly flow during the warm period. The levels of NO(x) and O(3) for the northern Athens basin area are found to be significantly higher during the sea breeze days compared to the Etesian days. Regarding the diurnal variation of ozone for the sea breeze days, peak concentrations and higher intra-daily ranges are observed. Day-to-day pollution accumulation (build-up effect) is measured for O(3) at the northern stations in the Athens basin.

  8. Heat flux: thermohydraulic investigation of solar air heaters used in agro-industrial applications

    NASA Astrophysics Data System (ADS)

    Rahmati Aidinlou, H.; Nikbakht, A. M.

    2017-03-01

    A new design of solar air heater simulator is presented to comply with the extensive applications inagro-industry. A wise installation of increased heat transfer surface area provided uniform and efficient heat diffusion over the duct. Nusselt number and friction factor have been investigated based on the constant roughness parameters such as relative roughness height (e/D), relative roughness pitch (P/e), angle of attack (α) and aspect ratio with Reynolds numbers ranging from 5000 to 19,000 in the fully developed region. Heat fluxes of 800, 900 and 1000 Wm-2 were provided. The enhancement in friction factor is observed to be 3.1656, 3.47 and 3.0856 times, and for the Nusselt number either, augmentation is calculated to be 1.4437, 1.4963 and 1.535 times, respectively, over the smooth duct for 800, 900 and 1000 Wm-2 heat fluxes. Thermohydraulic performance is plotted versus the Reynolds number based on the aforementioned roughness parameters at varying heat fluxes. The results show up that thermohydraulic performance is found to be maximum for 1000 Wm-2 at the average Reynolds number of 5151. Based on the results, we can verify that the introduced solar simulator can help analyzing and developing solar collector installations at the simulated heat fluxes.

  9. Thermocline mixing and vertical oxygen fluxes in the stratified central North Sea

    NASA Astrophysics Data System (ADS)

    Rovelli, L.; Dengler, M.; Schmidt, M.; Sommer, S.; Linke, P.; McGinnis, D. F.

    2015-07-01

    In recent decades, the central North Sea has been experiencing a general trend of decreasing dissolved oxygen (O2) levels during summer. To understand the potential causes driving lower O2, we investigated summertime turbulence and O2 dynamics in the thermocline and bottom boundary layer (BBL). The study focuses on coupling biogeochemical processes with physical transport processes to identify key drivers of the O2 and organic carbon turnover within the BBL. Combining our flux observations with an analytical process-oriented approach, we resolve the key drivers that ultimately determine the BBL O2 levels. We report substantial tidally-driven turbulent O2 fluxes from the thermocline into the otherwise isolated bottom water. This contribution to the local bottom water O2 and carbon budgets has been largely overlooked and might be a central factor maintaining relatively high O2 levels in the bottom water throughout the stratification period. With the current climate warming projections, we propose that higher water temperature and reduced turbulence could favour migrating algal species that could out-compete other species for light and nutrients, and shift the oxygen production zone higher up within the thermocline while maintaining similar organic carbon export to the bottom water. Due to the substantially lower turbulence levels in the central region of the thermocline as compared to the higher turbulence observed at the thermocline-BBL interface, such a shift in the production layer could lead to further isolation of the bottom water and promote the seasonal occurrence of lower O2 concentrations.

  10. The air-sea DMS exchange experiment at platform Noordwijk, Dutch coastal zone: I. Spatial and temporal variability of biochemical parameters

    NASA Astrophysics Data System (ADS)

    Stefels, J.; Dacey, J. W. H.; Warneke, C.; Hintsa, E.; Zemmelink, H. J.

    2003-04-01

    One of the tasks within the project "Iron Resources and Ocean Nutrients - Advancement of Global Environmental Simulations" (IRONAGES) is to improve global ocean models with a functional description of the production of dimethyl sulphide (DMS) in relation to biochemical parameters. Emission of DMS from sea to atmosphere and its subsequent oxidation in the atmosphere affects the radiative properties of skies and clouds and it is therefore an important parameter in climate models. The flux of DMS across the air-sea interface is, however, still inaccurately determined. Up to date, fluxes are calculated from the product of the concentration difference between sea and air (which is effectively equal to the sea water concentration) and a kinetic factor, known as the transfer velocity (k). Estimations of k vary by a factor of two. Moreover, the DMS concentration in the water is subject to a wide variety of biological, chemical and hydrographical processes. More accurate estimates of DMS-fluxes, can only be provided by direct flux measurements in combination with knowledge on the characteristics of the source area.. During a joint pilot study on platform "Noordwijk", 10 km off shore the Dutch coast, direct flux measurements were compared with the conventional estimation of the DMS-flux. DMS is produced by enzymatic cleavage of dimethylsulphonio-propionate (DMSP), a compound produced by marine algae. Both the production of DMSP and its conversion into DMS are subject to a complex set of processes, related to the functioning of the foodweb. In addition, the flux of DMS to the atmosphere is dependent on the wind speed and temperature and the background concentration of DMS in the atmosphere is affected by oxidation processes. Here, we present data on the temporal (daily) and spatial (in the fetch area of the platform) heterogeneity of biological and chemical parameters in this highly turbulent and heterogeneous area, and their relationship to the concentration of aqueous and

  11. Particulate organic carbon export fluxes and size-fractionated POC/ 234Th ratios in the Ligurian, Tyrrhenian and Aegean Seas

    NASA Astrophysics Data System (ADS)

    Speicher, E. A.; Moran, S. B.; Burd, A. B.; Delfanti, R.; Kaberi, H.; Kelly, R. P.; Papucci, C.; Smith, J. N.; Stavrakakis, S.; Torricelli, L.; Zervakis, V.

    2006-11-01

    Measurements of 234Th/ 238U disequilibria and particle size-fractionated (1, 10, 20, 53, 70, 100 μm) organic C and 234Th were made to constrain estimates of the export flux of particulate organic C (POC) from the surface waters of the Ligurian, Tyrrhenian and Aegean Seas in March-June 2004. POC exported from the surface waters (75-100 m depth) averaged 9.2 mmol m -2 d -1 in the Ligurian and Tyrrhenian Seas (2.3±0.5-14.9±3.0 mmol m -2 d -1) and 0.9 mmol m -2 d -1 in the Aegean Sea. These results are comparable to previous measurements of 234Th-derived and sediment-trap POC fluxes from the upper 200 m in the Mediterranean Sea. Depth variations in the POC/ 234Th ratio suggest two possible controls. First, decreasing POC/ 234Th ratios with depth were attributed to preferential remineralization of organic C. Second, the occurrence of maxima or minima in the POC/ 234Th ratio near the DCM suggests influence by phytoplankton dynamics. To assess the accuracy of these data, the empirical 234Th-method was evaluated by quantifying the extent to which the 234Th-based estimate of POC flux, PPOC, deviates from the true flux, FPOC, defined as the p-ratio ( p-ratio= PPOC/FPOC= STh/SPOC, where S=particle sinking rate). Estimates of the p-ratio made using Stokes' Law and the particle size distributions of organic C and 234Th yield values ranging from 0.93-1.45. The proximity of the p-ratio to unity implies that differences in the sinking rates of POC- and 234Th-carrying particles did not bias 234Th-normalized POC fluxes by more than a factor of two.

  12. Sedimentary phosphorus species and sedimentation flux in the East China Sea

    NASA Astrophysics Data System (ADS)

    Fang, Tien-Hsi; Chen, Jui-Lin; Huh, Chih-An

    2007-06-01

    Core sediment samples were collected from the middle shelf of the East China Sea (ECS) to study the phosphorus forms, P accumulation rate (PAR), P burial efficiency and the burial flux in the ECS. The sediment samples were sequentially extracted and directly extracted to analyze different forms of sedimentary P: lossely sorbed P and iron-bound P (P CDB); inorganic P associated with francolite (carbonate fluorapatite, CFA), biogenic hydroxyapatite, smecite, and CaCO 3 (P CFA); detrital P (P Detrital); organic P (P Organic); and total P. In addition, the Fe contents in the citrate-dithionite-bicarbonate (CDB) extracted solution were also measured. The total concentrations of P in the surface sediments in the study area ranged from 13.5 to 22.3 μmol g -1. Inorganic P was the major form and accounted for 72-93% of the total P pool. The average percentage of each fraction of P followed the sequence: P Detrital (70%)>P Organic (15.5%)>P CDB (8.4%)>P CFA (5.8%). The distribution pattern of total P in the surface sediment was similar to that of P Detrital and P Organic, but different from that of P CDB and P CFA. The profile variation of P Organic was the most significant among the phosphorus forms at the study stations. The concentrations of P CDB and P CFA showed minor variation with depth. These results may suggest that transformations of P Organic, P CFA and P CDB occurred at the study stations during sedimentary P burial. Based on the concentrations of total P, P CDB and Fe CDB obtained in the present study and the mass accumulation rate (MAR) reported in the literature, the values of the PAR, the P diffusion flux ( JPFe) supplied by reducible iron hydroxides and the P burial efficiency were calculated. The calculated results for PAR and JPFe in the study area ranged from 1.02 to 24.23 μmol cm -2 yr -1 and from 0.1 to 2.11 μmol cm -2 yr -1, respectively. The phosphorus burial efficiency (PBE) was approximately 90%. The ECS is a phosphorus sink, and the average

  13. Extreme subseasonal tropical air-sea interactions and their relation to ocean thermal stratification

    NASA Astrophysics Data System (ADS)

    Lloyd, Ian D.

    2011-12-01

    This thesis is concerned with extreme, rapid timescale tropical air-sea interactions and the influence of large-scale oceanic conditions on these interactions. The focus is on two types of extreme events: equatorial Indian Ocean cooling events and tropical cyclones. Cooling events occur on timescales of a few days to several weeks, in which atmospheric forcing causes Sea Surface Temperature (SST) cooling in the range of 1--5K, in both observational and coupled climate models. Cooling events are driven by changes in air-sea enthalpy fluxes and Ekman upwelling. Because the cooling due to Ekman upwelling depends on thermocline depth, large-scale oceanic conditions influence SST cooling. La Nina and negative Indian Ocean Dipole conditions are conducive to a shallower southwest equatorial thermocline, resulting in greater intraseasonal SST cooling during these interannual events; El Nino and positive Indian Ocean Dipole conditions lead to a deeper thermocline and reduced SST cooling. Results indicate that cooling events are related to the eastward propagation of convective patterns that resemble the Madden-Julian Oscillation. For tropical cyclones, the response of intensity to cyclone-induced SST cooling was explored over 10-years of observational data. For slow moving (V/ f < 100km) tropical cyclones, it was found that the SST cooling response increases along with storm intensity from category 0--2 on the Saffir-Simpson scale. However, from category 2--5 the magnitude of SST cooling decreases. This result confirms model predictions indicating a prominent role for oceanic feedback controlling tropical cyclone intensity. Thus, only storms that develop in regions containing deep mixed layer and thermocline can achieve high intensity, and entrainment cooling is weaker for these storms. The SST-intensity response in observations was compared to the GFDL Hurricane Forecast Model (GHM) for the periods 2005 and 2006--2009. The GHM was modified in 2006 to include a

  14. Controls, budgets and variability of riverine sediment fluxes to the Gulf of Lions (NW Mediterranean Sea)

    NASA Astrophysics Data System (ADS)

    Sadaoui, Mahrez; Ludwig, Wolfgang; Bourrin, François; Raimbault, Patrick

    2016-09-01

    The present study investigates the spatio-temporal variability of riverine sediment fluxes to the Gulf of Lions, one of the most extensive shelf regions in the Mediterranean Sea. Small coastal rivers compete here with the Rhone River, nowadays the largest Mediterranean river in terms of water discharge. Our scientific objectives were to investigate the major controls of riverine sediment yields (SY) in this area and to quantify the role of the small coastal rivers, largely ignored in previous studies, in the total sediment budgets. Another objective concerned the source identification of the Rhone sediments with regard to the major tributary contributions, and to test whether the sediment fluxes are in equilibrium in the basin. For the calculation of representative long-term fluxes, we used a Simplified Rating Curve Approach (SiRCA) which could be validated by high resolution monitoring and existing literature data. An overall of 13 drainage basins could be distinguished, covering about 86% of the study area (6 coastal rivers, the Rhone River, and 6 of its tributaries). Representative SY range from 19 to 151 t km-2 yr-1 in the investigated drainage basins. Despite their smaller basin areas and more torrential discharge regimes, SY of the coastal rivers were generally lower compared to SY of the Rhone River and its tributaries. Confrontation with the lithological, morphological and hydroclimatic basin characteristics indicate that lithology exerts the dominant control on SY in the study region. In particular, the existence of erodible sedimentary rocks in the headwater regions yields high SY. Peak values of 135 and 151 t km-2 yr-1 were observed for the Isere and Durance tributaries of the Rhone River, where badlands exist. The coastal rivers contribute on average only to slightly more than 5% of the long-term sediment inputs to the Gulf of Lions. During individual years however, their contribution can strongly increase (up to 27% in 2011). Their contribution is

  15. Tidal motions and tidally induced fluxes through La Línea submarine canyon, western Alboran Sea

    NASA Astrophysics Data System (ADS)

    Lafuente, Jesús GarcíA.; Sarhan, Tarek; Vargas, Manuel; Vargas, Juan M.; Plaza, Francisco

    1999-02-01

    Detailed observations from two mooring lines deployed in La Línea submarine canyon, western Alboran Sea, are presented. This is a narrow canyon in the sense that its width is always less than the internal radius of deformation. Tidal currents within the canyon are polarized in the along-canyon direction according to its narrow nature. They have considerable amplitude (values of around 0.5 m/s are often observed) and are forced by the internal pressure gradients associated with the baroclinic tide that is generated in the surroundings. Subsequent amplification of onshore baroclinic currents within the canyon accounts for the large amplitude observed. Cross-shelf exchange through the canyon due to tidal motions is different from zero despite the close to zero mean of tidal currents. The explanation is based on the asymmetry of water properties flowing up-canyon and down-canyon (some sort of tidal rectification). Regarding the energy flux, the canyon seems to be an adequate conduit to carry energy to the shore. Estimations made from our observations indicate that energy input onto the shelf per unit length parallel to the shore at the canyon head is enough to maintain mixing on the shelf at intermediate depths.

  16. Variability of residual fluxes of suspended sediment in a multiple tidal-inlet system: the Dutch Wadden Sea

    NASA Astrophysics Data System (ADS)

    Sassi, Maximiliano; Duran-Matute, Matias; van Kessel, Thijs; Gerkema, Theo

    2015-09-01

    In multiple tidal-inlet systems such as the Dutch Wadden Sea, the exchange of sediments between the coastal lagoon and the adjacent sea is controlled by the combined effect of the tides, wind-driven flows, and density-driven flows. We investigate the variability of residual (tidally averaged) fluxes of suspended sediment with the three-dimensional numerical model GETM in relation to forcing mechanisms and model parameters. Sediment transport is modeled with three sediment classes. A modified Partheniades-Krone formulation describes the erosion and deposition fluxes from a single-layer sediment pool. The model is initialized with a uniform sediment pool for each class and the spin up period amounts to six months. Simulations span 1 year. Comparisons with observations show that model results are fairly realistic. Residual fluxes of water and suspended sediment are episodic in nature and vary strongly throughout the year, mainly due to wind variability. The net balance between import and export of material is very sensitive to model parameters. Residual fluxes are sensitive to the geographical orientation and location of the inlets, and the effect of driving mechanisms on the residual fluxes and concentrations can be organized hierarchically, with wind forcing having the largest effect on concentration levels and variability.

  17. Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Shirley, John A.; Winter, Michael

    1993-01-01

    An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

  18. Subseafloor to Sea-Air Interface Characterization of Methane Dynamics in the northern US Atlantic Margin Seep Province

    NASA Astrophysics Data System (ADS)

    Ruppel, C. D.; Kluesner, J.; Danforth, W. W.; Casso, M.; Pohlman, J.

    2015-12-01

    Since the discovery of hundreds of northern US Atlantic margin (USAM) cold seeps in 2012 and 2013, the USGS Gas Hydrates Project has undertaken intensive studies of the along-margin gas hydrate/free gas distribution, the plumbing systems sustaining seeps, seafloor gas emissions, and sea-air methane flux. Interest in the USAM is motivated both by climate change (i.e., documented ocean warming may contribute to seepage) and energy resource (i.e., the amount of gas-in-place in hydrates on the USAM is about the same as that in the northern Gulf of Mexico) issues. USGS-led field efforts have included an April 2015 study to acquire high-resolution multichannel seismic data, coincident split-beam water column methane plume imaging data, and real-time sea-air methane flux measurements between Wilmington and Norfolk Canyons and a September 2015 cruise (with OSU, UCLA, and Geomar) to collect piston cores, multicores, heat flow data, subbottom imagery, CTDs, and coincident water column imagery from Block Canyon to the Currituck Slide. In April 2015, we discovered methane seeps not included in the previously-published database, but found that some known seeps were not active. New high-resolution multi-channel seismic data revealed clear differences between the deep gas distribution in mid-Atlantic upper slope zones that are replete with (up to 240 sites) and lacking in seeps. Based on sea-air flux measurements, even shallow-water outer shelf (~125 m water depth) seeps and a 900-m-high methane plume originating on the mid-slope do not contribute methane to the atmosphere. Using thermistors placed on piston core outriggers, we will in September 2015 acquire thermal data to identify zones of high fluid advection and to constrain background geotherms in areas where heat flow has never been measured. During that same cruise, we will collect a series of piston cores across the no-hydrate/hydrate transition on the upper slope to constrain fluid and gas dynamics in this zone.

  19. Observation of oceanic heat flux to the sea ice using ice-tethered moorings: Canada Basin, Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Ha, Ho Kyung; Yae Son, Eun; Park, Jae Hun; Cole, Sylvia; Park, Keyhong; Sul La, Hyoung

    2016-04-01

    It is important to figure out the physical mechanisms (e.g. shear, turbulence) below the sea ice, because of its direct influence on oceanic heat flux that is closely related to sea ice melt. A short-term (3.5 days) mooring was conducted in August 2014 to measure the vertical profiles of velocity, salinity and temperature within the sea-ice boundary layer. The mooring package consisted of an acoustic Doppler current profiler (ADCP) and 3 MicroCats. A long-term mooring of an ice-tethered profiler with modular acoustic velocity sensor (MAVS) was conducted to acquire vertical profiles of salinity, temperature, pressure and velocity in the marginal ice zone. The mooring data was analyzed to examine the role of the Pacific Summer Water (PSW) as a heat source, which can provide oceanic heat to the overlying layer. The ADCP data showed distinctive upper-velocity fields induced by entrainment of the sea ice. It appeared up to about 15 m depth during the entire observation period. Periodical components of MAVS data were extracted through wavelet transform. Since sea ice extent is relatively low in summer, the wind forcing could be effectively delivered in the form of a near 12 hours period oscillation to the 60 m depth where the PSW was occupying. Even in winter, while the sea surface was fully covered with the sea ice, near 12 hours period oscillation was appeared at 60 m depth. In September and January, strong 12 hours period oscillation appeared up to a deeper layer, which is deeper than 150 m depth where the wind forcing is hard to reach. The relationship between the heat flux and the oscillation strength will be discussed during the presentation.

  20. Large particle flux of 239+240Pu on the continental margin of the East China Sea.

    PubMed

    Yamada, Masatoshi; Aono, Tatsuo

    2002-03-15

    Settling particles were collected from three locations in the East China Sea continental margin and analyzed for 239+240Pu. Two types of sediment traps were used, cylindrical traps and conical time-series traps. Surface sediment samples collected from five locations were also analyzed for 239+240Pu. Data from cylindrical traps showed there was a clear tendency for total mass fluxes to increase with depth at all three stations, and there was an especially large increase near the bottom. 239+240Pu concentrations in settling particles increased with depth from 1.76 mBq/g at 97-m depth to 3.0 mBq/g at 120-m depth and ranged from approximately 3 to 4 mBq/g at depths greater than 120 m. 239+240Pu concentrations collected in the near-bottom traps were approximately two times higher than those in the underlying surface sediments. Like total mass fluxes there was a clear tendency for 239+240Pu fluxes to increase with depth at every station, and the highest 239+240Pu fluxes were observed near the bottom. 239+240Pu concentrations in the time-series traps had little variation throughout the sampling period, though the total mass fluxes showed a large variation. A high variability of 239+240Pu fluxes occurred in very short period of time (1/2 day). The large fluxes of 239+240Pu might be attributed to episodic lateral transport of particles that flow down the continental slope with the nepheloid layer which was considered to be significant for 239+240Pu transport on the continental slope in the East China Sea.

  1. A multi-model ensemble view of winter heat flux dynamics and the dipole mode in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Liguori, Giovanni; Di Lorenzo, Emanuele; Cabos, William

    2017-02-01

    Changes in surface heat fluxes affect several climate processes controlling the Mediterranean climate. These include the winter formation of deep waters, which is the primary driver of the Mediterranean Sea overturning circulation. Previous studies that characterize the spatial and temporal variability of surface heat flux anomalies over the basin reveal the existence of two statistically dominant patterns of variability: a monopole of uniform sign and an east-west dipole of opposite signs. In this work, we use the 12 regional climate model ensemble from the EU-FP6 ENSEMBLES project to diagnose the large-scale atmospheric processes that control the variability of heat fluxes over the Mediterranean Sea from interannual to decadal timescales (here defined as timescales > 6 year). Our findings suggest that while the monopole structure captures variability in the winter-to-winter domain-average net heat flux, the dipole pattern tracks changes in the Mediterranean climate that are connected to the East Atlantic/Western Russia (EA/WR) atmospheric teleconnection pattern. Furthermore, while the monopole exhibits significant differences in the spatial structure across the multi-model ensemble, the dipole pattern is very robust and more clearly identifiable in the anomaly maps of individual years. A heat budget analysis of the dipole pattern reveals that changes in winds associated with the EA/WR pattern exert dominant control through both a direct effect on the latent heat flux (i.e., wind speed) and an indirect effect through specific humidity (e.g., wind advection). A simple reconstruction of the heat flux variability over the deep-water formation regions of the Gulf of Lion and the Aegean Sea reveals that the combination of the monopole and dipole time series explains over 90 % of the heat flux variance in these regions. Given the important role that surface heat flux anomalies play in deep-water formation and the regional climate, improving our knowledge on the dynamics

  2. A multi-model ensemble view of winter heat flux dynamics and the dipole mode in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Liguori, Giovanni; Di Lorenzo, Emanuele; Cabos, William

    2016-04-01

    Changes in surface heat fluxes affect several climate processes controlling the Mediterranean climate. These include the winter formation of deep waters, which is the primary driver of the Mediterranean Sea overturning circulation. Previous studies that characterize the spatial and temporal variability of surface heat flux anomalies over the basin reveal the existence of two statistically dominant patterns of variability: a monopole of uniform sign and an east-west dipole of opposite signs. In this work, we use the 12 regional climate model ensemble from the EU-FP6 ENSEMBLES project to diagnose the large-scale atmospheric processes that control the variability of heat fluxes over the Mediterranean Sea from interannual to decadal timescales (here defined as timescales > 6 year). Our findings suggest that while the monopole structure captures variability in the winter-to-winter domain-average net heat flux, the dipole pattern tracks changes in the Mediterranean climate that are connected to the East Atlantic/Western Russia (EA/WR) atmospheric teleconnection pattern. Furthermore, while the monopole exhibits significant differences in the spatial structure across the multi-model ensemble, the dipole pattern is very robust and more clearly identifiable in the anomaly maps of individual years. A heat budget analysis of the dipole pattern reveals that changes in winds associated with the EA/WR pattern exert dominant control through both a direct effect on the latent heat flux (i.e., wind speed) and an indirect effect through specific humidity (e.g., wind advection). A simple reconstruction of the heat flux variability over the deep-water formation regions of the Gulf of Lion and the Aegean Sea reveals that the combination of the monopole and dipole time series explains over 90 % of the heat flux variance in these regions. Given the important role that surface heat flux anomalies play in deep-water formation and the regional climate, improving our knowledge on the dynamics

  3. Surface-air mercury fluxes across Western North America: A synthesis of spatial trends and controlling variables.

    PubMed

    Eckley, Chris S; Tate, Mike T; Lin, Che-Jen; Gustin, Mae; Dent, Stephen; Eagles-Smith, Collin; Lutz, Michelle A; Wickland, Kimberly P; Wang, Bronwen; Gray, John E; Edwards, Grant C; Krabbenhoft, Dave P; Smith, David B

    2016-10-15

    Mercury (Hg) emission and deposition can occur to and from soils, and are an important component of the global atmospheric Hg budget. This paper focuses on synthesizing existing surface-air Hg flux data collected throughout the Western North American region and is part of a series of geographically focused Hg synthesis projects. A database of existing Hg flux data collected using the dynamic flux chamber (DFC) approach from almost a thousand locations was created for the Western North America region. Statistical analysis was performed on the data to identify the important variables controlling Hg fluxes and to allow spatiotemporal scaling. The results indicated that most of the variability in soil-air Hg fluxes could be explained by variations in soil-Hg concentrations, solar radiation, and soil moisture. This analysis also identified that variations in DFC methodological approaches were detectable among the field studies, with the chamber material and sampling flushing flow rate influencing the magnitude of calculated emissions. The spatiotemporal scaling of soil-air Hg fluxes identified that the largest emissions occurred from irrigated agricultural landscapes in California. Vegetation was shown to have a large impact on surface-air Hg fluxes due to both a reduction in solar radiation reaching the soil as well as from direct uptake of Hg in foliage. Despite high soil Hg emissions from some forested and other heavily vegetated regions, the net ecosystem flux (soil flux+vegetation uptake) was low. Conversely, sparsely vegetated regions showed larger net ecosystem emissions, which were similar in magnitude to atmospheric Hg deposition (except for the Mediterranean California region where soil emissions were higher). The net ecosystem flux results highlight the important role of landscape characteristics in effecting the balance between Hg sequestration and (re-)emission to the atmosphere.

  4. Surface-air mercury fluxes across Western North America: A synthesis of spatial trends and controlling variables

    USGS Publications Warehouse

    Eckley, Chris S.; Tate, Michael T.; Lin, Che-Jen; Gustin, Mae S.; Dent, Stephen; Eagles-Smith, Collin A.; Lutz, Michelle A; Wickland, Kimberly; Wang, Bronwen; Gray, John E.; Edwards, Grant; Krabbenhoft, David P.; Smith, David

    2016-01-01

    Mercury (Hg) emission and deposition can occur to and from soils, and are an important component of the global atmospheric Hg budget. This paper focuses on synthesizing existing surface-air Hg flux data collected throughout the Western North American region and is part of a series of geographically focused Hg synthesis projects. A database of existing Hg flux data collected using the dynamic flux chamber (DFC) approach from almost a thousand locations was created for the Western North America region. Statistical analysis was performed on the data to identify the important variables controlling Hg fluxes and to allow spatiotemporal scaling. The results indicated that most of the variability in soil-air Hg fluxes could be explained by variations in soil-Hg concentrations, solar radiation, and soil moisture. This analysis also identified that variations in DFC methodological approaches were detectable among the field studies, with the chamber material and sampling flushing flow rate influencing the magnitude of calculated emissions. The spatiotemporal scaling of soil-air Hg fluxes identified that the largest emissions occurred from irrigated agricultural landscapes in California. Vegetation was shown to have a large impact on surface-air Hg fluxes due to both a reduction in solar radiation reaching the soil as well as from direct uptake of Hg in foliage. Despite high soil Hg emissions from some forested and other heavily vegetated regions, the net ecosystem flux (soil flux + vegetation uptake) was low. Conversely, sparsely vegetated regions showed larger net ecosystem emissions, which were similar in magnitude to atmospheric Hg deposition (except for the Mediterranean California region where soil emissions were higher). The net ecosystem flux results highlight the important role of landscape characteristics in effecting the balance between Hg sequestration and (re-)emission to the atmosphere.

  5. Stable carbon isotope gradients in benthic foraminifera as proxy for organic carbon fluxes in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Theodor, Marc; Schmiedl, Gerhard; Jorissen, Frans; Mackensen, Andreas

    2016-11-01

    We have determined stable carbon isotope ratios of epifaunal and shallow infaunal benthic foraminifera in the Mediterranean Sea to relate the inferred gradient of pore water δ13CDIC to varying trophic conditions. This is a prerequisite for developing this difference into a potential transfer function for organic matter flux rates. The data set is based on samples retrieved from a well-defined bathymetric range (400-1500 m water depth) of sub-basins in the western, central, and eastern Mediterranean Sea. Regional contrasts in organic matter fluxes and associated δ13CDIC of pore water are recorded by the δ13C difference (Δδ13CUmed-Epi) between the shallow infaunal Uvigerina mediterranea and epifaunal species (Planulina ariminensis, Cibicidoides pachydermus, Cibicides lobatulus). Within epifaunal taxa, the highest δ13C values are recorded for P. ariminensis, providing the best indicator for bottom water δ13CDIC. In contrast, C. pachydermus reveals minor pore water effects at the more eutrophic sites. Because of ontogenetic trends in the δ13C signal of U. mediterranea of up to 1.04 ‰, only tests larger than 600 µm were used for the development of the transfer function. The recorded differences in the δ13C values of U. mediterranea and epifaunal taxa (Δδ13CUmed-Epi) range from -0.46 to -2.13 ‰, with generally higher offsets at more eutrophic sites. The measured δ13C differences are related to site-specific differences in microhabitat, depth of the principal sedimentary redox boundary, and TOC content of the ambient sediment. The Δδ13CUmed-Epi values reveal a consistent relation to Corg fluxes estimated from satellite-derived surface water primary production in open-marine settings of the Alboran Sea, Mallorca Channel, Strait of Sicily, and southern Aegean Sea. In contrast, Δδ13CUmed-Epi values in areas affected by intense resuspension and riverine organic matter sources of the northern to central Aegean Sea and the canyon systems of the Gulf of Lion

  6. On the Potential Impact of Daytime Surface Sensible Heat Flux on the Dissipation of Martian Cold Air Outbreaks

    NASA Technical Reports Server (NTRS)

    Segal, M.; Arritt, R. W.; Tillman, J. E.

    1997-01-01

    The Martian daytime soil surface temperature is governed primarily by the net irradiance balance and surface soil heat flux. Thus the outbreak of a cold air mass generates increased sensible heat flux that is conducive to daytime dissipation of the cold air mass thermal characteristics. Conceptual and scaling evaluations of this dissipation are provided while comparison is made with similar situations on Earth. It is estimated that sensible heat flux contribution to the dissipation of the original thermal structure of the cold air could be three times larger than the corresponding situation on Earth. Illustrative numerical model simulations provide scaling of the potential impact on the dissipation of cold air masses for various combinations of background wind speed and latitudes.

  7. Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights (Invited)

    NASA Astrophysics Data System (ADS)

    Tsuda, A.

    2010-12-01

    Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights Atsushi Tsuda Atmosphere and Ocean Research Institute, The University of Tokyo In the western Pacific (WESTPAC) region, dust originating from Asian and Australian arid regions to the North and South Pacific, biomass burning emissions from the Southeast Asia to sub-tropical Pacific, and other anthropogenic substances are transported regionally and globally to affect cloud and rainfall patterns, air quality, and radiative budgets downwind. Deposition of these compounds into the Asian marginal seas and onto the Pacific Ocean influence surface primary productivity and species composition. In the WESTPAC region, subarctic, subtropical oceans and marginal seas are located relatively narrow latitudinal range and these areas are influenced by the dust and anthropogenic inputs. Moreover, anthropogenic emission areas are located between the arid region and the oceans. The W-PASS (Western Pacific Air-Sea interaction Study) project has been funded for 5 years as a part of SOLAS-Japan activity in the summer of 2006. We aim to resolve air-sea interaction through field observation studies mainly using research vessels and island observatories over the western Pacific. We have carried out 5 cruises to the western North Pacific focusing on air-sea interactions. Also, an intensive marine atmospheric observation including direct atmospheric deposition measurement was accomplished by a dozen W-PASS research groups at the NIES Atmospheric and Aerosol Monitoring Station of Cape Hedo in the northernmost tip of the Okinawa main Island facing the East China Sea in the spring 2008. A few weak Kosa (dust) events, anthropogenic air outflows, typical local air and occupation of marine background air were identified during the campaign period. The W-PASS has four research groups mainly focusing on VOC emissions, air-sea gas exchange processes, biogeochemical responses to dust depositions and its modeling. We also

  8. Absorption of the atmospheric CO{sub 2} by oceanic biota near the air-sea interface

    SciTech Connect

    Gorshkov, V.G.; Makarieva, A.M.

    1997-12-31

    The oceanic phytoplancton productivity may essentially influence the total rate of the atmospheric CO{sub 2} absorption by the ocean - that is, a considerable amount of CO{sub 2} will be taken-up in the 50 micrometers thick layer near the air-sea interface. Even if phytoplancton production constitutes only 5% of the total oceanic biota production, this will increase the rate of CO{sub 2} absorption more than twice compared with the present estimates. The reason is that metabolic activity of phytoplancton leads to the emergence in a thin scin (50 micrometers, the average size of phytoplancton cells) layer near the water surface of an additional minimum in the CO{sub 2} partial pressure profile and of an additional maximum of {Delta} {sup 13}C in the same area. These two extremums cannot be detected if the corresponding characteristics are averaged over any microscopic area in the well mixing layer that is more than 1 meter deep, which is usually the case when the oceanic concentrations of CO{sub 2} are measured. This effect may account for the observed contradiction between the existing estimates of the rate of CO{sub 2} absorption, that are based either on measuring gradient of the concentrations of the dissolved organic and inorganic carbon or on measuring of the physical flux of CO{sub 2} through the air-sea interface.

  9. Upper ocean bubble measurements from the NE Pacific and estimates of their role in air-sea gas transfer of the weakly soluble gases nitrogen and oxygen

    NASA Astrophysics Data System (ADS)

    Vagle, Svein; McNeil, Craig; Steiner, Nadja

    2010-12-01

    Simultaneous observations of upper-ocean bubble clouds, and dissolved gaseous nitrogen (N2) and oxygen (O2) from three winter storms are presented and analyzed. The data were collected on the Canadian Surface Ocean Lower Atmosphere Study (C-SOLAS) mooring located near Ocean Station Papa (OSP) at 50°N, 145°W in the NE Pacific during winter of 2003/2004. The bubble field was measured using an upward looking 200 kHz echosounder. Direct estimates of bubble mediated gas fluxes were made using assumed bubble size spectra and the upward looking echosounder data. A one-dimensional biogeochemical model was used to help compare data and various existing models of bubble mediated air-sea gas exchange. The direct bubble flux calculations show an approximate quadratic/cubic dependence on mean bubble penetration depth. After scaling from N2/O2 to carbon dioxide, near surface, nonsupersaturating, air-sea transfer rates, KT, for U10 > 12 m s-1 fall between quadratic and cubic relationships. Estimates of the subsurface bubble induced air injection flux, VT, show an approximate quadratic/cubic dependence on mean bubble penetration depth. Both KT and VT are much higher than those measured during Hurricane Frances over the wind speed range 12 < U10 < 23 m s-1. This result implies that over the open ocean and this wind speed range, older and more developed seas which occur during winter storms are more effective in exchanging gases between the atmosphere and ocean than younger less developed seas which occur during the rapid passage of a hurricane.

  10. Air-sea interactions a techno-political history and future challenges

    NASA Astrophysics Data System (ADS)

    Geernaert, G.

    2003-04-01

    Air-sea interaction research has its origins in early inquiry into wave suppression and fisheries. These led to efforts designed to model current systems, predict risks and threats to commercial and exploit fisheries for economic benefit. A new set of national goals emerged about a century ago: exploit the physics of air-sea interactions for military superiority; to be followed a half century later with efforts to understand air-sea interactions to address water quality, offshore energy and climate challenges. In most part, sociopolitical events precipitated new scientific discoveries, through agency financed networks and targeted research programs. There are also examples of science driving the agency process. In this presentation, a brief history of political and scientific challenges will be given, to be followed by a summary of our greatest upcoming challenges.

  11. GSOD Based Daily Global Mean Surface Temperature and Mean Sea Level Air Pressure (1982-2011)

    SciTech Connect

    Xuan Shi, Dali Wang

    2014-05-05

    This data product contains all the gridded data set at 1/4 degree resolution in ASCII format. Both mean temperature and mean sea level air pressure data are available. It also contains the GSOD data (1982-2011) from NOAA site, contains station number, location, temperature and pressures (sea level and station level). The data package also contains information related to the data processing methods

  12. Linking atmospheric synoptic transport, cloud phase, surface energy fluxes, and sea-ice growth: observations of midwinter SHEBA conditions

    NASA Astrophysics Data System (ADS)

    Persson, P. Ola G.; Shupe, Matthew D.; Perovich, Don; Solomon, Amy

    2016-10-01

    Observations from the Surface Heat Budget of the Arctic Ocean (SHEBA) project are used to describe a sequence of events linking midwinter long-range advection of atmospheric heat and moisture into the Arctic Basin, formation of supercooled liquid water clouds, enhancement of net surface energy fluxes through increased downwelling longwave radiation, and reduction in near-surface conductive heat flux loss due to a warming of the surface, thereby leading to a reduction in sea-ice bottom growth. The analyses provide details of two events during Jan. 1-12, 1998, one entering the Arctic through Fram Strait and the other from northeast Siberia; winter statistics extend the results. Both deep, precipitating frontal clouds and post-frontal stratocumulus clouds impact the surface radiation and energy budget. Cloud liquid water, occurring preferentially in stratocumulus clouds extending into the base of the inversion, provides the strongest impact on surface radiation and hence modulates the surface forcing, as found previously. The observations suggest a minimum water vapor threshold, likely case dependent, for producing liquid water clouds. Through responses to the radiative forcing and surface warming, this cloud liquid water also modulates the turbulent and conductive heat fluxes, and produces a thermal wave penetrating into the sea ice. About 20-33 % of the observed variations of bottom ice growth can be directly linked to variations in surface conductive heat flux, with retarded ice growth occurring several days after these moisture plumes reduce the surface conductive heat flux. This sequence of events modulate pack-ice wintertime environmental conditions and total ice growth, and has implications for the annual sea-ice evolution, especially for the current conditions of extensive thinner ice.

  13. Effects of air-sea coupling over the North Sea and the Baltic Sea on simulated summer precipitation over Central Europe

    NASA Astrophysics Data System (ADS)

    Ho-Hagemann, Ha Thi Minh; Gröger, Matthias; Rockel, Burkhardt; Zahn, Matthias; Geyer, Beate; Meier, H. E. Markus

    2017-03-01

    This study introduces a new approach to investigate the potential effects of air-sea coupling on simulated precipitation inland over Central Europe. We present an inter-comparison of two regional climate models (RCMs), namely, the COSMO-CLM (hereafter CCLM) and RCA4 models, which are configured for the EURO-CORDEX domain in the coupled and atmosphere-only modes. Two versions of the CCLM model, namely, 4.8 and 5.0, join the inter-comparison being almost two different models while providing pronouncedly different summer precipitation simulations because of many changes in the dynamics and physics of CCLM in version 5.0. The coupling effect on the prominent summer dry bias over Central Europe is analysed using seasonal (JJA) mean statistics for the 30-year period from 1979 to 2009, with a focus on extreme precipitation under specific weather regimes. The weather regimes are compared between the coupled and uncoupled simulations to better understand the mechanism of the coupling effects. The comparisons of the coupled systems with the atmosphere-only models show that coupling clearly reduces the dry bias over Central Europe for CCLM 4.8, which has a large dry summer bias, but not for CCLM 5.0 and RCA4, which have smaller dry biases. This result implies that if the atmosphere-only model already yields reasonable summer precipitation over Central Europe, not much room for improvement exists that can be caused by the air-sea coupling over the North Sea and the Baltic Sea. However, if the atmosphere-only model shows a pronounced summer dry bias because of a lack of moisture transport from the seas into the region, the considered coupling may create an improved simulation of summer precipitation over Central Europe, such as for CCLM 4.8. For the latter, the benefit of coupling varies over the considered timescales. The precipitation simulations that are generated by the coupled system COSTRICE 4.8 and the atmosphere-only CCLM 4.8 are mostly identical for the summer mean

  14. Decadal trends in air-sea CO2 exchange in the Ross Sea (Antarctica)

    NASA Astrophysics Data System (ADS)

    Tagliabue, Alessandro; Arrigo, Kevin R.

    2016-05-01

    Highly productive Antarctic shelf systems, like the Ross Sea, play important roles in regional carbon budgets, but the drivers of local variations are poorly quantified. We assess the variability in the Ross Sea carbon cycle using a regional physical-biogeochemical model. Regionally, total partial pressure of CO2 (pCO2) increases are largely controlled by the biological pump and broadly similar to those in the offshore Southern Ocean. However, this masks substantial local variability within the Ross Sea, where interannual fluctuations in total pCO2 are driven by the biological pump and alkalinity, whereas those for anthropogenic pCO2 are related to physical processes. Overall, the high degree of spatial variability in the Ross Sea carbon cycle causes extremes in aragonite saturation that can be as large as long-term trends. Therefore, Antarctic shelf polynya systems like the Ross Sea will be strongly affected by local processes in addition to larger-scale phenomena.

  15. Connections Between the Spring Breakup of the Southern Hemisphere Polar Vortex, Stationary Waves, and Air-sea Roughness

    NASA Technical Reports Server (NTRS)

    Garfinkel, Chaim I.; Oman, Luke David; Barnes, Elizabeth A.; Waugh, Darryn W.; Hurwitz, Margaret H.; Molod, Andrea M.

    2013-01-01

    A robust connection between the drag on surface-layer winds and the stratospheric circulation is demonstrated in NASA's Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM). Specifically, an updated parameterization of roughness at the air-sea interface, in which surface roughness is increased for moderate wind speeds (4ms to 20ms), leads to a decrease in model biases in Southern Hemispheric ozone, polar cap temperature, stationary wave heat flux, and springtime vortex breakup. A dynamical mechanism is proposed whereby increased surface roughness leads to improved stationary waves. Increased surface roughness leads to anomalous eddy momentum flux convergence primarily in the Indian Ocean sector (where eddies are strongest climatologically) in September and October. The localization of the eddy momentum flux convergence anomaly in the Indian Ocean sector leads to a zonally asymmetric reduction in zonal wind and, by geostrophy, to a wavenumber-1 stationary wave pattern. This tropospheric stationary wave pattern leads to enhanced upwards wave activity entering the stratosphere. The net effect is an improved Southern Hemisphere vortex: the vortex breaks up earlier in spring (i.e., the spring late-breakup bias is partially ameliorated) yet is no weaker in mid-winter. More than half of the stratospheric biases appear to be related to the surface wind speed biases. As many other chemistry climate models use a similar scheme for their surface layer momentum exchange and have similar biases in the stratosphere, we expect that results from GEOSCCM may be relevant for other climate models.

  16. Phytoplankton dynamics driven by vertical nutrient fluxes during the spring inter-monsoon period in the northeastern South China Sea

    NASA Astrophysics Data System (ADS)

    Li, Q. P.; Dong, Y.; Wang, Y.

    2016-01-01

    A field survey from the coastal ocean zones to the offshore pelagic zones of the northeastern South China Sea (nSCS) was conducted during the inter-monsoon period of May 2014 when the region was characterized by prevailing low-nutrient conditions. Comprehensive field measurements were made for not only hydrographic and biogeochemical properties but also phytoplankton growth and microzooplankton grazing rates. We also performed estimations of the vertical turbulent diffusivity and diffusive nutrient fluxes using a Thorpe-scale method and the upwelling nutrient fluxes by Ekman pumping using satellite-derived wind stress curl. Our results indicated a positive correlation between the integrated phytoplankton chlorophyll a and vertical nutrient fluxes in the offshore region of the nSCS during the study period. We generally found an increasing role of turbulent diffusion but a decreasing role of curl-driven upwelling in vertical transport of nutrients from the coastal ocean zones to the offshore pelagic zones. Elevated nutrient fluxes near Dongsha Islands supported high new production leading to net growth of the phytoplankton community, whereas the low fluxes near the southwest of Taiwan had resulted in a negative net community growth leading to decline of a surface phytoplankton bloom. Overall, phytoplankton dynamics in the large part of the nSCS could be largely driven by vertical nutrient fluxes including turbulent diffusion and curl-driven upwelling during the spring inter-monsoon period.

  17. Recent variations of sea ice and air temperature in high latitudes

    SciTech Connect

    Chapman, W.L.; Walsh, J.E. )

    1993-01-01

    Feedbacks resulting from the retreat of sea ice and snow contribute to the polar amplification of the greenhouse warming projected by global climate models. A gridded sea-ice database, for which the record length is now approaching four decades for the Arctic and two decades for the Antarctic, is summarized here. The sea-ice fluctuations derived from the data set are characterized by (1) temporal scales of several seasons to several years and (2) spatial scales of 30[degrees]-180[degrees] of longitude. The ice data are examined in conjunction with air temperature data for evidence of recent climate change in the polar regions. The arctic sea-ice variations over the past several decades are compatible with the corresponding air temperatures, which show a distinct warming that is strongest over northern land areas during the winter and spring. The temperature trends over the sub arctic seas are smaller and even negative in the southern Greenland region. Statistically significant decreases of the summer extent of arctic ice are apparent in the sea-ice data, and new summer minima have been achieved three times in the past 15 years. There is no significant trend of ice extent in the Arctic during winter or in the Antarctic during any season. The seasonal and geographical changes of sea-ice coverage are consistent with the more recent greenhouse experiments performed with coupled atmosphere-ocean models.

  18. Balloons and Bottles: Activities on Air-Sea Heat Exchange.

    ERIC Educational Resources Information Center

    Murphree, Tom

    1998-01-01

    Presents an activity designed to demonstrate how heating and cooling an air mass affects its temperature, volume, density, and pressure. Illustrates how thermal energy can cause atmospheric motion such as expansion, contraction, and winds. (Author/WRM)

  19. BOREAS AFM-2 King Air 1994 Aircraft Flux and Moving Window Data

    NASA Technical Reports Server (NTRS)

    Kelly, Robert D.; Hall, Forrest G. (Editor); Newcomer, Jeffrey A. (Editor); Smith, David E. (Technical Monitor)

    2000-01-01

    The BOREAS AFM-2 team collected pass-by-pass fluxes (and many other statistics) for a large number of level (constant altitude), straight-line passes used in a variety of flight patterns. The data were collected by the University of Wyoming King Air in 1994 BOREAS IFCs 1-3. Most of these data were collected at 60-70 m above ground level, but a significant number of passes were also flown at various levels in the planetary boundary layer, up to about the inversion height. This documentation concerns only the data from the straight and level passes that are presented as original (over the NSA and SSA) and moving window values (over the Transect). Another archive of King Air data is also available, containing data from all the soundings flown by the King Air 1994 IFCs 1-3. The data are stored in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884) or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

  20. Carbon isotope evidence for the latitudinal distribution and wind speed dependence of the air-sea gas transfer velocity

    NASA Astrophysics Data System (ADS)

    Krakauer, Nir Y.; Randerson, James T.; Primeau, François W.; Gruber, Nicolas; Menemenlis, Dimitris

    2006-11-01

    The air-sea gas transfer velocity is an important determinant of the exchange of gases, including CO2, between the atmosphere and ocean, but the magnitude of the transfer velocity and what factors control it remains poorly known. Here, we use oceanic and atmospheric observations of 14C and 13C to constrain the global mean gas transfer velocity as well as the exponent of its wind speed dependence, utilizing the distinct signatures left by the air-sea exchange of 14CO2 and 13CO2. While the atmosphere and ocean inventories of 14CO2 and 13CO2 constrain the mean gas transfer velocity, the latitudinal pattern in the atmospheric and oceanic 14C and 13C distributions contain information about the wind speed dependence. We computed the uptake of bomb 14C by the ocean for different transfer velocity patterns using pulse response functions from an ocean general circulation model, and evaluated the match between the predicted bomb 14C concentrations and observationally based estimates for the 1970s-1990s. Using a wind speed climatology based on satellite measurements, we solved either for the best-fit global relationship between gas exchange and mean wind speed or for the mean gas transfer velocity over each of 11 ocean regions. We also compared the predicted consequences of different gas exchange relationships on the rate of change and interhemisphere gradient of 14C in atmospheric CO2 with tree-ring and atmospheric measurements. Our results suggest that globally, the dependence of the air-sea gas transfer velocity on wind speed is close to linear, with an exponent of 0.5 +/- 0.4, and that the global mean gas transfer velocity at a Schmidt number of 660 is 20 +/- 3 cm/hr, similar to the results of previous analyses. We find that the air-sea flux of 13C estimated from atmosphere and ocean observations also suggests a lower than quadratic dependence of gas exchange on wind speed.

  1. Dissolved methane in the Beaufort Sea and the Arctic Ocean, 1992-2009; sources and atmospheric flux

    USGS Publications Warehouse

    Lorenson, Thomas D.; Greinert, Jens; Coffin, Richard B.

    2016-01-01

    Methane concentration and isotopic composition was measured in ice-covered and ice-free waters of the Arctic Ocean during eleven surveys spanning the years of 1992-1995 and 2009. During ice-free periods, methane flux from the Beaufort shelf varies from 0.14 to 0.43 mg CH4 m-2 day-1. Maximum fluxes from localized areas of high methane concentration are up to 1.52 mg CH4 m-2 day-1. Seasonal buildup of methane under ice can produce short-term fluxes of methane from the Beaufort shelf that varies from 0.28 to 1.01 to mg CH4 m-2 day-1. Scaled-up estimates of minimum methane flux from the Beaufort Sea and pan-Arctic shelf for both ice-free and ice-covered periods range from 0.02 Tg CH4 yr-1 and 0.30 Tg CH4 yr-1 respectively to maximum fluxes of 0.18 Tg CH4 yr-1 and 2.2 Tg CH4 yr-1 respectively. A methane flux of 0.36 Tg CH4 yr-1from the deep Arctic Ocean was estimated using data from 1993-94. The flux can be as much as 2.35 Tg CH4 yr-1 estimated from maximum methane concentrations and wind speeds of 12 m/s, representing only 0.42% of the annual atmospheric methane budget of ~560 Tg CH4 yr-1. There were no significant changes in methane fluxes during the time period of this study. Microbial methane sources predominate with minor influxes from thermogenic methane offshore Prudhoe Bay and the Mackenzie River delta and may include methane from gas hydrate. Methane oxidation is locally important on the shelf and is a methane sink in the deep Arctic Ocean.

  2. Particle Fluxes in the Marginal Seas of Antarctica: A 20-year Synthesis in Honor of Jack Dymond

    NASA Astrophysics Data System (ADS)

    Dunbar, R. B.; Langone, L.

    2004-12-01

    One of Jack Dymond's long-standing scientific passions was the study of particles moving through the ocean water column. Jack's pioneering work in this area in the 1970's and generous mentoring of others throughout his career lead directly to the first authors involvement in sediment trap studies. Here we present a synthesis of 20 years of particle flux studies in coastal Antarctic (including the work of Collier and Dymond et al.) and highlight some of the important features and unresolved issues related to integrating particle trap interceptor data with other measures of production, transport, and deposition. The first sediment trap arrays were deployed on the Antarctic shelf in 1981 and 1982 in the Antarctic Peninsula. Simple instruments were also deployed in 1984 and 1986 in the Ross Sea. Since then, several nations (US, Italy, New Zealand) have recovered time series sediment trap data on moorings in both of these areas. This current synthesis makes use of data from approximately 22 sites, the majority of which are in the Ross Sea, and includes about 900 discrete samples of particles in vertical transit through the water column. We now have many complete time series that extend through the winter, allowing several important generalizations to be made. For example, annual particle-mediated organic C fluxes to below 200 meters in the Ross Sea average 4.4±3.3 g C m-2 yr-1. These values are significantly less than export fluxes calculated using short-term surface water mass balance approaches or Th isotope techniques yet are higher than seabed sediment accumulation rates. Intriguingly, seasonal seabed arrival rates of organic C estimated from in-situ summertime benthic respirometry studies yield C flux values similar in magnitude to those from sediment traps deployed at the same time, lending strong support to trap data. The cause of current disagreements between various methods of flux estimation may in fact not be solved until process studies are accomplished

  3. Experimental sea slicks: Their practical applications and utilization for basic studies of air-sea interactions

    NASA Astrophysics Data System (ADS)

    Hühnerfuss, Heinrich; Garrett, W. D.

    1981-01-01

    Practical applications of organic surface films added to the sea surface date back to ancient times. Aristotle, Plutarch, and Pliny the Elder describe the seaman's practice of calming waves in a storm by pouring oil onto the sea [Scott, 1977]. It was also noted that divers released oil beneath the water surface so that it could rise and spread over the sea surface, thereby suppressing the irritating flicker associated with the passage of light through a rippled surface. From a scientific point of view, Benjamin Franklin was the first to perform experiments with oils on natural waters. His experiment with a `teaspoonful of oil' on Clapham pond in 1773 inspired many investigators to consider sea surface phenomena or to conduct experiments with oil films. This early research has been reviewed by Giles [1969], Giles and Forrester [1970], and Scott [1977]. Franklin's studies with experimental slicks can be regarded as the beginning of surface film chemistry. His speculations on the wave damping influence of oil induced him to perform the first qualitative experiment with artificial sea slicks at Portsmouth (England) in October of 1773. Although the sea was calmed and very few white caps appeared in the oil-covered area, the swell continued through the oiled area to Franklin's great disappointment.

  4. Air/water subchannel measurements of the equilibrium quality and mass-flux distribution in a rod bundle. [BWR

    SciTech Connect

    Sterner, R.W.; Lahey, R.T. Jr.

    1983-07-01

    Subchannel measurements were performed in order to determine the equilibrium quality and mass flux distribution in a four rod bundle, using air/water flow. An isokinetic technique was used to sample the flow in the center, side and corner subchannels of this test section. Flow rates of the air and water in each sampled subchannel were measured. Experiments were performed for two test-section-average mass fluxes (0.333x10/sup 6/ and 0.666x10/sup 6/ lb/sub m//h-ft/sup 2/), and the test-section-average quality was varied from 0% to 0.54% for each mass flux. Single-phase liquid, bubbly, slug and churn-turbulent two-phase flow regimes were achieved. The observed data trends agreed with previous diabatic measurements in which the center subchannel had the highest quality and mass flux, while the corner subchannel had the lowest.

  5. Impacts of South East Biomass Burning on local air quality in South China Sea

    NASA Astrophysics Data System (ADS)

    Wai-man Yeung, Irene; Fat Lam, Yun; Eniolu Morakinyo, Tobi

    2016-04-01

    Biomass burning is a significant source of carbon monoxide and particulate matter, which is not only contribute to the local air pollution, but also regional air pollution. This study investigated the impacts of biomass burning emissions from Southeast Asia (SEA) as well as its contribution to the local air pollution in East and South China Sea, including Hong Kong and Taiwan. Three years (2012 - 2014) of the Hybrid Single Particle Lagrangian-Integrated Trajectory (HYSPLIT) with particles dispersion analyses using NCEP (Final) Operational Global Analysis data (FNL) data (2012 - 2014) were analyzed to track down all possible long-range transport from SEA with a sinking motion that worsened the surface air quality (tropospheric downwash from the free troposphere). The major sources of SEA biomass burning emissions were first identified using high fire emissions from the Global Fire Emission Database (GFED), followed by the HYSPLIT backward trajectory dispersion modeling analysis. The analyses were compared with the local observation data from Tai Mo Shan (1,000 msl) and Tap Mun (60 msl) in Hong Kong, as well as the data from Lulin mountain (2,600 msl) in Taiwan, to assess the possible impacts of SEA biomass burning on local air quality. The correlation between long-range transport events from the particles dispersion results and locally observed air quality data indicated that the background concentrations of ozone, PM2.5 and PM10 at the surface stations were enhanced by 12 μg/m3, 4 μg/m3 and 7 μg/m3, respectively, while the long-range transport contributed to enhancements of 4 μg/m3, 4 μg/m3 and 8 μg/m3 for O3, PM2.5 and PM10, respectively at the lower free atmosphere.

  6. Phytoplankton dynamics driven by vertical nutrient fluxes during the spring inter-monsoon period in the northeastern South China Sea

    NASA Astrophysics Data System (ADS)

    Li, Q. P.; Dong, Y.; Wang, Y.

    2015-05-01

    A field survey from the coastal upwelling zones to the offshore pelagic zones of the northeastern South China Sea (SCS) was conducted during the inter-monsoon period of May 2014 when the region was characterized by prevailing low-nutrient conditions. Comprehensive field measurements were made for not only hydrographic and biogeochemical properties but also phytoplankton growth and microzooplankton grazing rates. We also performed estimations of the vertical turbulent diffusivity and diffusive nutrient fluxes using a Thorpe-scale method and the upwelling nutrient fluxes by Ekman pumping using satellite-derived wind stress curl. Our results suggest that phytoplankton patchiness in the northeastern SCS during the study period could be largely controlled by vertical nutrient fluxes with combined contributions from both turbulent diffusion and curl-driven upwelling. Our results also reveal the generally increasing role of turbulent diffusion but decreasing role of curl-driven upwelling on vertical transport of nutrients from the coastal upwelling zones to the offshore pelagic zones in the northeastern SCS. Elevated nutrient fluxes observed near Dongsha Island were found to support high new production leading to net growth of a diatom-rich phytoplankton community, whereas the low nutrient fluxes near southwest Taiwan resulted in a negative net community growth leading to a decline of a picoplankton-dominant phytoplankton bloom.

  7. Directional gravity wave momentum fluxes in the stratosphere derived from high-resolution AIRS temperature data

    NASA Astrophysics Data System (ADS)

    Ern, M.; Hoffmann, L.; Preusse, P.

    2017-01-01

    In order to reduce uncertainties in modeling the stratospheric circulation, global observations of gravity wave momentum flux (GWMF) vectors are required for comparison with distributions of resolved and parametrized GWMF in global models. For the first time, we derive GWMF vectors globally from data of a nadir-viewing satellite instrument: we apply a 3-D method to an Atmospheric Infrared Sounder (AIRS) temperature data set that was optimized for gravity wave (GW) analysis. For January 2009, the resulting distributions of GW amplitudes and of net GWMF highlight the importance of GWs in the polar vortex and the summertime subtropics. Net GWMF is preferentially directed opposite to the background wind, and, interestingly, it is dominated by large-amplitude GWs of relatively long horizontal wavelength. For convective GW sources, these large horizontal scales are in contradiction with traditional thoughts. However, the observational filter effect needs to be kept in mind when interpreting the results.

  8. Occurrence and air-sea exchange of phthalates in the Arctic.

    PubMed

    Xie, Zhiyong; Ebinghaus, Ralf; Temme, Christian; Lohmann, Rainer; Caba, Armando; Ruck, Wolfgang

    2007-07-01

    Air and seawater samples were taken simultaneously to investigate the distribution and air-sea gas exchange of phthalates in the Arctic onboard the German Research Ship FS Polarstern. Samples were collected on expeditions ARK XX1&2 from the North Sea to the high Arctic (60 degrees N-85 degrees N) in the summer of 2004. The concentration of sigma6 phthalates (dimethyl phthalate (DMP), diethyl phthalate (DEP), di-i-butyl phthalate (DiBP), di-n-butyl phthalate (DnBP), butylbenzyl phthalate (BBP), and diethylhexyl phthalate (DEHP)) ranged from 30 to 5030 pg L(-1) in the aqueous dissolved phase and from 1110 to 3090 pg m(-3) in the atmospheric gas phase. A decreasing latitudinal trend was present in the seawater and to a lesser degree in the atmosphere from the Norwegian coast to the high Arctic. Overall, deposition dominated the air-sea gas exchange for DEHP, while volatilization from seawater took place in the near-coast environment. The estimated net gas deposition of DEHP was 5, 30, and 190 t year(-1) for the Norwegian Sea, the Greenland Sea, and the Arctic, respectively. This suggests that atmospheric transport and deposition of phthalates is a significant process for their occurrence in the remote Atlantic and Arctic Ocean.

  9. The organic sea surface microlayer in the upwelling region off Peru and implications for air-sea exchange processes

    NASA Astrophysics Data System (ADS)

    Engel, A.; Galgani, L.

    2015-07-01

    The sea surface microlayer (SML) is at the very surface of the ocean, linking the hydrosphere with the atmosphere, and central to a range of global biogeochemical and climate-related processes. The presence and enrichment of organic compounds in the SML have been suggested to influence air-sea gas exchange processes as well as the emission of primary organic aerosols. Among these organic compounds, primarily of plankton origin, are dissolved exopolymers, specifically polysaccharides and proteins, and gel particles, such as Transparent Exopolymer Particles (TEP) and Coomassie Stainable Particles (CSP). These organic substances often accumulate in the surface ocean when plankton productivity is high. Here, we report results obtained in December 2012 during the SOPRAN Meteor 91 cruise to the highly productive, coastal upwelling regime off Peru. Samples were collected from the SML and from ~ 20 cm below, and were analyzed for polysaccharidic and proteinaceous compounds, gel particles, total and dissolved organic carbon, bacterial and phytoplankton abundance. Our study provides insight to the physical and biological control of organic matter enrichment in the SML, and discusses the potential role of organic matter in the SML for air-sea exchange processes.

  10. Air-sea exchange of dimethylsulfide in the Southern Ocean: Measurements from SO GasEx compared to temperate and tropical regions

    NASA Astrophysics Data System (ADS)

    Yang, M.; Blomquist, B. W.; Fairall, C. W.; Archer, S. D.; Huebert, B. J.

    2011-04-01

    In the Southern Ocean Gas Exchange Experiment (SO GasEx), we measured an atmospheric dimethylsulfide (DMS) concentration of 118 ± 54 pptv (1σ), a DMS sea-to-air flux of 2.9 ± 2.1 μmol m-2 d-1 by eddy covariance, and a seawater DMS concentration of 1.6 ± 0.7 nM. Dividing flux by the concurrent air-sea concentration difference yields the transfer velocity of DMS (kDMS). The kDMS in the Southern Ocean was significantly lower than previous measurements in the equatorial east Pacific, Sargasso Sea, northeast Atlantic, and southeast Pacific. Normalizing kDMS for the temperature dependence in waterside diffusivity and solubility results in better agreement among various field studies and suggests that the low kDMS in the Southern Ocean is primarily due to colder temperatures. The higher solubility of DMS at a lower temperature results in greater airside control and less transfer of the gas by bubbles formed from breaking waves. The final normalized DMS transfer velocity is similar to k of less soluble gases such as carbon dioxide in low-to-moderate winds; in high winds, DMS transfer velocity is significantly lower because of the reduced bubble-mediated transfer.

  11. Carbon dioxide fluxes across the atmosphere-water-coastal eroded ice complex in the Arctic Ocean: Laptev and Kara seas

    NASA Astrophysics Data System (ADS)

    Semiletov, I. P.; Pipko, I. I.; Kosmach, D.; Salyuk, A.; Dudarev, O. V.; Repina, I.; Shakhova, N. E.

    2007-12-01

    Despite the significant progress that has been made in Arctic biogeochemical studies, large discrepancies still exist between recent estimations of the carbon balance and cycling in the Arctic seas [Romankevich and Vetrov, 2001; Stein and Macdonald, 2003; Macdonald et al., 2006] because reliable data are lacking. The Arctic Ocean has been suggested to be a net sink for atmospheric CO2, favoured by cold, relatively low salinity surface layers). Unfortunately, estimates of annual CO2 uptake from the atmosphere vary widely from 1700 × billions moles (Anderson, et al., 1998) up to 11000 billions moles (Lyakhin and Rusanov, 1983), due to high spatial variability and a difficulty of establishing representative values. To fill this gap with a substantial quantity of good-quality data is one of the primary purposes of this study. During the September 2006 expedition in the Laptev Sea and along the Northern Sea Route five research platforms were used to accomplish field work: the ice-strengthened commercial vessel Kapitan Danilkin, two small vessels, the TB 0012 and the Neptun, an Mi-8 helicopter, and diesel icebreaker Kapitan Dranitsyn. CO2 and CH4 fluxes were measured using micrometeorological methods, enclosure methods, or both. In our CO2 and CH4 exchange study setup, momentum and the fluxes of sensible and latent heat were measured using the eddy-correlation technique, which is the most direct micrometeorological method. Dynamics of the carbonate system was studied using pH- TALK technique. Preliminary results: 1. The coastal area of the Laptev Sea, strongly influenced by coastal erosion and river input of terrestrial carbon (suspended and dissolved), acts as a strong source of CO2 into the atmosphere. CO2 flux from the sea surface/nearshore zone ranged between 0.31 - 0.4 μM/?/sec (for comparison, ? release from the tundra soil ranged between 0.03 - 0.18 μM/?/sec). The highest rates of ? emission were measured in the freshly-exposed eroded depressions. 2. CO2 fluxes

  12. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model

    EPA Science Inventory

    Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions,...

  13. VARIATIONS OF THE MUON FLUX AT SEA LEVEL ASSOCIATED WITH INTERPLANETARY ICMEs AND COROTATING INTERACTION REGIONS

    SciTech Connect

    Augusto, C. R. A.; Kopenkin, V.; Navia, C. E.; Tsui, K. H.; Shigueoka, H.; Fauth, A. C.; Kemp, E.; Manganote, E. J. T.; Leigui de Oliveira, M. A.; Miranda, P.; Ticona, R.; Velarde, A.

    2012-11-10

    We present the results of an ongoing survey on the association between the muon flux variation at ground level (3 m above sea level) registered by the Tupi telescopes (Niteri-Brazil, 22.{sup 0}9S, 43.{sup 0}2W, 3 m) and the Earth-directed transient disturbances in the interplanetary medium propagating from the Sun (such as coronal mass ejections (CME), and corotating interaction regions (CIRs)). Their location inside the South Atlantic Anomaly region enables the muon telescopes to achieve a low rigidity of response to primary and secondary charged particles. The present study is primarily based on experimental events obtained by the Tupi telescopes in the period from 2010 August to 2011 December. This time period corresponds to the rising phase of solar cycle 24. The Tupi events are studied in correlation with data obtained by space-borne detectors (SOHO, ACE, GOES). Identification of interplanetary structures and associated solar activity was based on the nomenclature and definitions given by the satellite observations, including an incomplete list of possible interplanetary shocks observed by the CELIAS/MTOF Proton Monitor on the Solar and Heliospheric Observatory (SOHO) spacecraft. Among 29 experimental events reported in the present analysis, there are 15 possibly associated with the CMEs and sheaths, and 3 events with the CIRs (forward or reverse shocks); the origin of the remaining 11 events has not been determined by the satellite detectors. We compare the observed time (delayed or anticipated) of the muon excess (positive or negative) signal on Earth (the Tupi telescopes) with the trigger time of the interplanetary disturbances registered by the satellites located at Lagrange point L1 (SOHO and ACE). The temporal correlation of the observed ground-based events with solar transient events detected by spacecraft suggests a real physical connection between them. We found that the majority of observed events detected by the Tupi experiment were delayed in

  14. Air-Sea Interaction Patterns in the Equatorial Pacific

    DTIC Science & Technology

    1993-12-01

    Acquisition System (ATLAS) buoys and Equatorial Pacific Ocean Climate Studies ( EPOCS ) buoys. The ATLAS buoys used in this study are located at longitudes 156...8217E, 165°E, 170W, 169°W, 155°W, 140W, 1250W, I 10°W. The EPOCS buoys used in this study are located on the equator at 165°E, 140’W, and I 10°W. Fig. 3...sea surface temperature (SST), and subsurface temperatures. The EPOCS buoys measure surface wind, AT, SST, and currents. For both types of buoys, wind

  15. Impact of autumn SST in the Japan Sea on winter rainfall and air temperature in Northeast China

    NASA Astrophysics Data System (ADS)

    Shi, Xiaomeng; Sun, Jilin; Wu, Dexing; Yi, Li; Wei, Dongni

    2015-08-01

    We studied the impact of sea surface temperature anomaly (SSTA) in the Japan Sea and the sea area east of Japan on the winter rainfall and air temperature in Northeast (NE) China using the singular value decomposition (SVD) and empirical orthogonal function (EOF). The monthly-mean rainfall data observed at 160 stations in China, monthly-mean sea surface temperature (SST) of the Hadley Center for Climate Prediction and Research and monthly-mean air temperature from the NCEP reanalysis during 1960-2011 were used. Correlation analysis indicates that the SSTAs in the Japan Sea in September may last for three or four months and are an important index for forecasting the winter rainfall and air temperature in NE China. Positive SSTAs in the central Japan Sea and in the sea area east of Tokyo correspond to positive rainfall anomaly and negative air temperature anomaly in NE China. With the rise of SST in the Japan Sea, a weak cyclone appears over the Japan Sea. The northeasterly wind transports water vapor from the Okhotsk to NE China, resulting in more rainfall and lower air temperature. Negative SSTA years are accompanied by warmer air temperature and less snow in NE China. The 1000 hPa geopotential height anomaly and wind anomaly fields are simulated by IAP-9L model, which supports the analysis results.

  16. Influence of eutrophication on air-water exchange, vertical fluxes, and phytoplankton concentrations of persistent organic pollutants

    SciTech Connect

    Dachs, J.; Eisenreich, S.J.; Hoff, R.M.

    2000-03-15

    The influence of eutrophication on the biogeochemical cycles of persistent organic pollutants (POPs) such as polychlorinated biphenyls (PCBs) is largely unknown. In this paper, the application of a dynamic air-water-phytoplankton exchange model to Lake Ontario is used as a framework to study the influence of eutrophication on air-water exchange, vertical fluxes, and phytoplankton concentrations of POPs. The results of these simulations demonstrate that air-water exchange controls phytoplankton concentrations in remote aquatic environments with little influence from land-based sources of pollutants and supports levels in even historically contaminated systems. Furthermore, eutrophication or high biomass leads to a disequilibrium between the gas and dissolved phase, enhanced air-water exchange, and vertical sinking fluxes of PCBs. Increasing biomass also depletes the water concentrations leading to lower than equilibrium PCB concentrations in phytoplankton. Implications to future trends in PCB pollution in Lake Ontario are also discussed.

  17. On the use of a coupled ocean-atmosphere-wave model during an extreme cold air outbreak over the Adriatic Sea

    NASA Astrophysics Data System (ADS)

    Ricchi, Antonio; Miglietta, Mario Marcello; Falco, Pier Paolo; Benetazzo, Alvise; Bonaldo, Davide; Bergamasco, Andrea; Sclavo, Mauro; Carniel, Sandro

    2016-05-01

    An intense cold air outbreak affected the northern Adriatic Sea during winter 2012, determining an exceptional persistence of northeasterly Bora wind over the basin, which lasted for about 3 weeks. The cold air coming from the Balkans produced icing in the Venice lagoon and very intense snowfall in the Apennines Mountains and even near the coasts. In order to understand the importance and role of air-sea interactions for the evolution of the atmospheric fields, simulations with the Weather Research and Forecasting (WRF) model encompassing the whole period have been performed using sea surface temperature (SST) fields with an increasing level of complexity. Starting from a large-scale static sea temperature, the SST in the initial and boundary conditions has been progressively made more realistic. First, a more refined field, retrieved from a satellite radiometer was used; then, the same field was updated every 6 h. Next, the effect of including a simplified 1D ocean model reproducing the Oceanic Mixed Layer (OML) evolution has been tested. Finally, the potential improvements coming from a coupled description of atmosphere-ocean and atmosphere-ocean-waves interactions have been explored within the Coupled Ocean-Atmosphere-Wave Sediment Transport (COAWST) modeling system. Results highlight that the energy exchange between air and sea does not significantly impact the atmospheric fields, in particular 10 m wind and 2 m temperature, also because of the geography of the basin and the predominance of synoptic-scale flow in intense events of Bora, in the northern Adriatic. However, when sensible and latent heat fluxes, which are dependent on atmospheric and oceanic variables, are analyzed, the more realistic representation of SST drastically improves the model performances.

  18. Turbulent Fluxes and Pollutant Mixing during Wintertime Air Pollution Episodes in Complex Terrain.

    PubMed

    Holmes, Heather A; Sriramasamudram, Jai K; Pardyjak, Eric R; Whiteman, C David

    2015-11-17

    Cold air pools (CAPs) are stagnant stable air masses that form in valleys and basins in the winter. Low wintertime insolation limits convective mixing, such that pollutant concentrations can build up within the CAP when pollutant sources are present. In the western United States, wintertime CAPs often persist for days or weeks. Atmospheric models do not adequately capture the strength and evolution of CAPs. This is in part due to the limited availability of data quantifying the local turbulence during the formation, maintenance, and destruction of persistent CAPs. This paper presents observational data to quantify the turbulent mixing during two CAP episodes in Utah's Salt Lake Valley during February of 2004. Particulate matter (PM) concentration data and turbulence measurements for CAP and non-CAP time periods indicate that two distinct types of mixing scenarios occur depending on whether the CAP is dry or cloudy. Where cloudy, CAPs have enhanced vertical mixing due to top-down convection from the cloud layer. A comparison between the heat and momentum fluxes during 5 days of a dry CAP episode in February to those of an equivalent 5 day time period in March with no CAP indicates that the average turbulent kinetic energy during the CAP was suppressed by approximately 80%.

  19. A method of exploration of the atmosphere of Titan. [hot air balloon heated by solar radiation or planetary thermal flux

    NASA Technical Reports Server (NTRS)

    Blamont, J.

    1978-01-01

    A hot-air balloon, with the air heated by natural sources, is described. Buoyancy is accomplished by either solar heating or by utilizing the IR thermal flux of the planet to heat the gas in the balloon. Altitude control is provided by a valve which is opened and closed by a barometer. The balloon is made of an organic material which has to absorb radiant energy and to emit as little as possible.

  20. Scattering properties of a stratified air/snow/sea ice medium. Small slope approximation

    NASA Astrophysics Data System (ADS)

    Dusséaux, Richard; Afifi, Saddek; Dechambre, Monique

    2016-11-01

    The sea-ice thickness, a key parameter in Arctic studies, is derived from radar altimeter height measurements of the freeboard, taking into account not only snow load, but also the penetration depth of the electromagnetic waves inside the snow-this is the not generally the case. Within the framework of the small slope approximation method, we study in Ku-band (f = 13 GHz, λ = 2.31 cm in the air) the electromagnetic signature of an air/snow/sea ice rough layered medium. The snow is inhomogeneous and is represented as a stack of several layers with different relative permittivities. We show that the electromagnetic response is very sensitive to the isotropy factor of the air/snow interface and to the cross-correlation parameters of interfaces. xml:lang="fr"

  1. Low-frequency variability of surface air temperature over the Barents Sea: causes and mechanisms

    NASA Astrophysics Data System (ADS)

    van der Linden, Eveline C.; Bintanja, Richard; Hazeleger, Wilco; Graversen, Rune G.

    2016-08-01

    The predominant decadal to multidecadal variability in the Arctic region is a feature that is not yet well-understood. It is shown that the Barents Sea is a key region for Arctic-wide variability. This is an important topic because low-frequency changes in the ocean might lead to large variations in the sea-ice cover, which then cause massive changes in the ocean-atmosphere heat exchanges. Here we describe the mechanism driving surface temperatures and heat fluxes in the Barents Sea based primarily on analyzes of one global coupled climate model. It is found that the ocean drives the low-frequency changes in surface temperature, whereas the atmosphere compensates the oceanic transport anomalies. The seasonal dependence and the role of individual components of the ocean-atmosphere energy budget are analyzed in detail, showing that seasonally-varying climate mechanisms play an important role. Herein, sea ice is governing the seasonal response, by acting as a lid that opens and closes during warm and cold periods, respectively, thereby modulating the surface heat fluxes.

  2. Decomposition of thermal and dynamic changes in the South China Sea induced by boundary forcing and surface fluxes during 1970-2000

    NASA Astrophysics Data System (ADS)

    Wei, Jun; Malanotte-Rizzoli, Paola; Li, Ming-Ting; Wang, Hao

    2016-11-01

    Based on a fully coupled, high-resolution regional climate model, this study analyzed three-dimensional temperature and momentum changes in the South China Sea (SCS) from 1970 to 2000, during which period the climate shifts from a decadal La Niña-like condition (before 1976/1977) to a decadal El Niño-like condition afterward. With a set of partially coupled experiments, sea surface temperature (SST) and kinetic energy (KE) changes during this period are first decomposed into two components: those induced by lateral boundary forcing and those induced by atmospheric surface fluxes. The results showed that the total SST and KE changes show an increasing trend from 1970 to 2000. The two decomposed components together determined 96 and 89% of the SST and KE changes, respectively, implying their dominant roles on the SCS's surface variability. Spatially, a sandwich pattern of air-sea forcing relationship is revealed in the SCS basin. The increased KE, represented by a cyclonic flow anomaly in the northern SCS, was induced by enhanced cold water intrusion from Pacific into the SCS via the Luzon Strait (boundary forcing). This cold-water inflow, however, resulted in SST cooling along the northern shelf of the SCS. The maximal SST warming occurred in the central SCS and was attributed to the wind-evaporation-SST (WES) positive feedback (surface forcing), in which a southwestward wind anomaly is initialized by SST gradients between the northern and southern SCS. This wind anomaly decelerates the southwestly summer monsoons and in turn increases the SST gradients. Over the shallow Sunda shelf, which is far from the Luzon Strait, the SST/KE variability appeared to be determined primarily by local air-sea interactions. Furthermore, analyses on subsurface components indicated that the subsurface temperature changes are primarily induced by internal ocean mixing, which becomes significantly important below the thermocline. The enhanced subsurface flow is driven by the Luzon

  3. The composition and flux of particulate and dissolved carbohydrates from the Rhône River into the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Panagiotopoulos, C.; Sempéré, R.; Para, J.; Raimbault, P.; Rabouille, C.; Charrière, B.

    2011-11-01

    Carbohydrates are important components of the carbon cycle and may be used as indicators of the origin and the diagenetic status of marine and terrestrial organic matter. Nevertheless, comprehensive studies of both particulate (PCHO) and dissolved (DCHO) carbohydrates in rivers are scarce, and the seasonal and interannual variability of these compounds in relationship to the bulk particulate (POM) and dissolved organic matter (DOM) is largely unknown. For the period 2007-2009, we sampled once per month POM and DOM and measured the total suspended matter (TSM), POM, DOM, PCHO, and DCHO for the Rhône River, which flows into the Mediterranean Sea. Using these measurements, we estimated for the above parameters annual fluxes for the period 2001-2010. The estimated carbohydrate fluxes averaged 0.061±0.043×1010 moles Cy-1 for PCHO and 0.041±0.0062×1010 moles Cy-1 DCHO, representing 8% and 7% of the annual flux of POC and DOC, respectively. During flood and low-water periods, POM variations were reflected into the PCHO pool, whereas this was not observed for DOC and DCHO, indicating a decoupling between particulate and dissolved organic matter. Our results also showed that flood and low-water periods may be differentiated using the ratios PCHO/DCHO and POC/DOC, which had a significant linear relationship. Based on the carbohydrate abundances in both the PCHO and DCHO pools, we conclude that this material mainly derives from allochthonous sources (vascular plants, bacteria and soils). Moreover, during flood events, an enrichment in mannose in POM was observed, probably reflecting an angiosperm source (leaves or grasses). By expanding our results to the northwestern Mediterranean Sea (Gulf of Lions), we found that the total organic carbon (TOC) fluxes of the Rhône River accounted for ~1% of the standing stock of seawater TOC. Considering that glucose is the most abundant carbohydrate in both particulate and dissolved organic matter pools (~33%), its annual flux in the

  4. The composition and flux of particulate and dissolved carbohydrates from the Rhone River into the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Panagiotopoulos, C.; Sempéré, R.; Para, J.; Raimbault, P.; Rabouille, C.; Charrière, B.

    2012-05-01

    Carbohydrates are important components of the carbon cycle and may be used as indicators of the origin and the diagenetic status of marine and terrestrial organic matter. Nevertheless, comprehensive studies of both particulate (PCHO) and dissolved (DCHO) carbohydrates in rivers are scarce, and the seasonal and interannual variability of these compounds in relationship to the bulk particulate (POM) and dissolved organic matter (DOM) is largely unknown. For the period 2007-2009, we sampled once per month POM and DOM and measured the total suspended matter (TSM), POM, DOM, PCHO, and DCHO for the Rhône River, which flows into the Mediterranean Sea. Using these measurements, we estimated for the above parameters annual fluxes for the period 2007-2009. The estimated carbohydrate fluxes averaged 0.064 ± 0.026 × 1010 moles C yr-1 for PCHO and 0.042 ± 0.008 × 1010 moles C yr-1 DCHO, representing 6 % and 7 % of the annual flux of POC and DOC, respectively. During flood and low-water periods, POM variations were reflected into the PCHO pool, whereas this was not observed for DOC and DCHO, indicating a decoupling between particulate and dissolved organic matter. Our results also showed that flood and low-water periods may be differentiated using the ratios PCHO/DCHO and POC/DOC, which had a significant relationship. Based on the carbohydrate abundances in both the PCHO and DCHO pools, we conclude that this material mainly derives from allochthonous sources (vascular plants, bacteria and soils). Moreover, during flood events, an enrichment in mannose in POM was observed, probably reflecting an angiosperm source (leaves or grasses). By expanding our results to the northwestern Mediterranean Sea (Gulf of Lions), we found that the total organic carbon (TOC) fluxes of the Rhône River accounted for ~1 % of the standing stock of seawater TOC. Considering that glucose is the most abundant carbohydrate in both particulate and dissolved organic matter pools (~33 %), its annual

  5. Air-sea interaction with SSM/I and altimeter

    NASA Technical Reports Server (NTRS)

    1985-01-01

    A number of important developments in satellite remote sensing techniques have occurred recently which offer the possibility of studying over vast areas of the ocean the temporally evolving energy exchange between the ocean and the atmosphere. Commencing in spring of 1985, passive and active microwave sensors that can provide valuable data for scientific utilization will start to become operational on Department of Defense (DOD) missions. The passive microwave radiometer can be used to estimate surface wind speed, total air column humidity, and rain rate. The active radar, or altimeter, senses surface gravity wave height and surface wind speed.

  6. Preliminary study of osmotic membrane bioreactor: effects of draw solution on water flux and air scouring on fouling.

    PubMed

    Qin, Jian-Jun; Kekre, Kiran A; Oo, Maung H; Tao, Guihe; Lay, Chee L; Lew, Cheun H; Cornelissen, Emile R; Ruiken, Chris J

    2010-01-01

    Preliminary study on a novel osmotic membrane bioreactor (OMBR) was explored. Objective of this study was to investigate the effects of draw solution on membrane flux and air scouring at the feed side on fouling tendency in a pilot OMBR system composing the anoxic/aerobic and forward osmosis (FO) processes. Domestic sewage was the raw feed, FO membrane from HTI and NaCl/MgSO4 draw solutions were used in the experiments. Fluxes of 3 l/m2/h (LMH) and 7.2 LMH were achieved at osmotic pressure of 5 and 22.4 atm, respectively. No significant flux decline was observed at 3 LMH over 190 h and at 7.2 LMH over 150 h when air scouring was provided at the feed side of the membrane. However, without air scouring, the flux at 22.4 atm osmotic pressure declined by 30% after 195 h and then levelled off. The potential advantages of the fouling reversibility with air scouring under the operating conditions of the pilot OMBR and better water quality in OMBR over the conventional MBR were preliminarily demonstrated.

  7. Identifying the Role of Extratropical Air-Sea Interactions in North Pacific Climate Variability with a Hierarchy of CESM Simulations

    NASA Astrophysics Data System (ADS)

    Sun, T.; Okumura, Y.

    2015-12-01

    Large-scale patterns of extratropical sea surface temperature (SST) variability are primarily driven by intrinsic modes of atmospheric circulation variability through changes in surface heat fluxes and ocean currents. While these changes in extratropical SSTs in turn affect the atmospheric circulation, it remains unclear to what extent the oceanic feedback modifies the overall climate variability. The present study focuses on North Pacific variability and revisits this long-standing problem by analyzing multi-century-millennium control simulations of an atmospheric model (CAM4) coupled to the ocean with varying degrees: a 300-yr run of standalone CAM4, 500-year run of CAM4 coupled to a slab ocean (CAM4SOM), and 1300-yr run of fully coupled model (CCSM4). The leading mode of North Pacific atmospheric variability is very similar among three models and resembles the observed Pacific-North American (PNA) pattern, in support of the stochastic climate model. In CAM4SOM, the associated surface heat flux anomalies induce SST changes during boreal winter, which tend to persist into the following winter through positive cloud feedback. These SST changes leave weak, but distinct imprints on the atmosphere. The atmospheric response is highly seasonally dependent and projects onto the original PNA pattern in the upper troposphere during boreal winter while a direct baroclinic response becomes prevalent in the other seasons. The thermodynamic air-sea interactions only marginally increase the persistency of PNA variability in CAM4SOM compared to the standalone CAM4 simulation. In CCSM4, a similar influence of extratropical SSTs is suggested but difficult to isolate due to the dominant impact of El Nino-Southern Oscillation and associated atmospheric teleconnections. Nevertheless, dynamically-induced SST variability in the oceanic frontal region appears to add more persistency to atmospheric variability because of its low-frequency nature.

  8. Assessment of 137Cs and 90Sr Fluxes in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Matishov, Gennady; Usiagina, Irina; Kasatkina, Nadezhda; Ilin, Gennadii

    2014-05-01

    On the basis of published and own data the annual balance of radionuclide income/outcome was assessed for 137Cs and 90Sr in the Barents Sea for the period from 1950s to the presnt. The scheme of the isotope balance calculation in the Barents Sea included the following processes:atmospheric fallout; river run-off; liquid radioactive wastes releases, income from the Norwegian and the White Seas; outflow to the adjacent areas through the Novaya Zemlya straits and the transects Svalbard-Franz Josef Land and Franz Josef Land-Novaya Zemlya; radioactive decay. According to the multiyear dynamics, the inflow of 137Cs and 90Sr to the Barents Sea was significantly preconditioned by currents from the Norwegian Sea. Three peaks of 137Cs and 90Sr isotope concentrations were registered for the surface waters on the western border of the Barents Sea. The first one was observed in the mid-1960s and was conditioned by testing of nuclear weapons. The increase of isotope concentrations in 1975 and 1980 was preconditioned by the discharge of atomic waste by the Sellafield nuclear reprocessing plant. Nowadays, after the sewage disposal plant was built, the annual discharge of nuclear waste from Sellafield plant is low. The Norwegian Sea was a major source of 137Cs and 90Sr isotope income into the Barents Sea for the period of 1960-2014. Currently, the transborder transfer of 90Sr and 137Cs from the Norwegian Sea into the Barents Sea constitutes about 99% of income for each element. Atmospheric precipitation had a major impact in the 1950-1960s after the testing of the nuclear weapons, and in 1986 after the accident at Chernobyl Nuclear Power Station. In 1963, the atmospheric precipitation of 137Cs reached 1050 TBq; and that of 90Sr, 630 TBq. In 1986, a significant amount of 137Cs inflow (up to 1010 TBq/year) was registered. The 137Cs isotope income exceeded the 90Sr income in the 1960s-1980s, and equal amounts penetrated into the Barents Sea from the Norwegian Sea in the 1990s. Before

  9. Air-sea interaction in the tropical Pacific Ocean

    NASA Technical Reports Server (NTRS)

    Allison, L. J.; Steranka, J.; Holub, R. J.; Hansen, J.; Godshall, F. A.; Prabhakara, C.

    1972-01-01

    Charts of 3-month sea surface temperature (SST) anomalies in the eastern tropical Pacific Ocean were produced for the period 1949 to 1970. The anomalies along the United States and South American west coasts and in the eastern tropical Pacific appeared to be oscillating in phase during this period. Similarly, the satellite-derived cloudiness for each of four quadrants of the Pacific Ocean (130 deg E to 100 deg W, 30 deg N to 25 deg S) appeared to be oscillating in phase. In addition, a global tropical cloudiness oscillation from 30 deg N to 30 deg S was noted from 1965 to 1970, by using monthly satellite television nephanalyses. The SST anomalies were found to have a good degree of correlation both positive and negative with the following monthly geophysical parameters: (1) satellite-derived cloudiness, (2) strength of the North and South Pacific semipermanent anticyclones, (3) tropical Pacific island rainfall, and (4) Darwin surface pressure. Several strong direct local and crossequatorial relationships were noted. In particular, the high degree of correlation between the tropical island rainfall and the SST anomalies (r = +0.93) permitted the derivation of SST's for the tropical Pacific back to 1905. The close occurrence of cold tropical SST and North Pacific 700-mb positive height anomalies with central United States drought conditions was noted.

  10. Updating Sea Spray Aerosol Emissions in the Community Multiscale Air Quality Model

    NASA Astrophysics Data System (ADS)

    Gantt, B.; Bash, J. O.; Kelly, J.

    2014-12-01

    Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions, include sea surface temperature (SST) dependency, and revise surf zone emissions. Based on evaluation with several regional and national observational datasets in the continental U.S., the updated emissions generally improve surface concentrations predictions of primary aerosols composed of sea-salt and secondary aerosols affected by sea-salt chemistry in coastal and near-coastal sites. Specifically, the updated emissions lead to better predictions of the magnitude and coastal-to-inland gradient of sodium, chloride, and nitrate concentrations at Bay Regional Atmospheric Chemistry Experiment (BRACE) sites near Tampa, FL. Including SST-dependency to the SSA emission parameterization leads to increased sodium concentrations in the southeast U.S. and decreased concentrations along the Pacific coast and northeastern U.S., bringing predictions into closer agreement with observations at most Interagency Monitoring of Protected Visual Environments (IMPROVE) and Chemical Speciation Network (CSN) sites. Model comparison with California Research at the Nexus of Air Quality and Climate Change (CalNex) observations will also be discussed, with particular focus on the South Coast Air Basin where clean marine air mixes with anthropogenic pollution in a complex environment. These SSA emission updates enable more realistic simulation of chemical processes in coastal environments, both in clean marine air masses and mixtures of clean marine and polluted conditions.

  11. [Upward and regeneration fluxes of inorganic nitrogen and phosphorus in the deep-water areas of the Black-Sea].

    PubMed

    Krivenko, O V; Parkhomenko, A V

    2014-01-01

    Upward and regeneration fluxes of inorganic nitrogen and phosphorusin the euphotic zone of the Black Sea deep waters were estimated using data from long-term observations of nitrate and phosphate vertical distribution and modeling of plankton month- and area-averaged nutrients excretion. The upward fluxes were calculated using monthly average nitrate and phosphate concentrations and their gradients beneath the euphotic layer assuming that the vertical transport rates are controlled by the density gradient at the upper layer of the main pycnocline throughout the year. According to the calculations, the nutrient input into the euphotic layer due to physical processes changes gradually throughout the year from minimum values in July-August (0.1-0.3 mg-atN x m(-2) x day(-1) and 0.02-0.04 mg-atP x m(-2) x day(-1)) up to maximum ones in February-March (1.2-1.8 mg-atN x m(-2) x day(-1) and 0.2-0.3 mg-atP x m(-2) x day(-1)), contrary to the seasonal dynamics of the regeneration flux rates. In summer, plankton regeneration rates increase nearly five-fold as compared to the winter months. The contribution of the upward flux to the total nutrient euphotic zone input was calculated and designated as F(N)(F(P))-ratio along the lines with the f-ratio and e-ratio that reflect the ratio of "new" production and particle export to primary production, respectively. The monthly means vary for F(N) from 5 to 50% and for F(P) from 10 to 70% throughout the year in the same manner as the upward flux. Relationships between the monthly mean values of F(N,P) and vertically integrated nitrate and phosphate concentrations, chlorophyll "a", phytoplankton biomass, and primary production in the euphotic zone were established. The obtained relationships correspond to the general relationships between primary production, "new" production and the sinking flux of particles known for the Ocean. Potential values of "new", regenerated, and total production of phytoplankton in the deep-water areas of the

  12. Thirty Years of Continuous Particle Flux Observations in the Deep Sargasso Sea: Looking Back, Looking Forward

    NASA Astrophysics Data System (ADS)

    Conte, M. H.; Weber, J. C.

    2007-12-01

    The Oceanic Flux Program sediment traps have continuously measured the deep ocean particle flux off Bermuda since the late 1970s, with a >95% temporal coverage at 3200m depth. The early OFP discovery of a seasonal cycle in deep particle flux clearly demonstrated that the deep ocean environment was directly coupled to overlying surface productivity via the particle flux, laying to rest the (then) widely held view of the abyssal ocean as an invariant, largely isolated environment. In the years since, time-series observations of the OFP and others have clearly shown that deep ocean environment is closely linked to upper ocean variability on time-scales of days to decades. The OFP record to date shows that in fact, the deep particle flux- analogous to atmospheric precipitation- follows a strongly skewed (gamma) frequency distribution with transient flux ""rainstorms"" occurring predominately in the late fall and spring periods when surface stratification is weak. On annual time-scales, particle flux is negatively correlated with the wintertime (NDJF) NAO Index. This correlation reflects the greater frequency of transient, high flux events in years when the wintertime NAO Index is low, suggesting a direct influence of increased wintertime storminess. Many causal linkages identified between variability in deep flux and upper ocean forcing off Bermuda have been made possible because of the co-location of two other, complementary observational programs near the OFP mooring: BATS, a ship-based time-series established in 1988 that collects monthly data on upper ocean biogeochemical parameters, and the Bermuda Testbed Mooring (BTM), a platform for moored instrumentation that since 1994 has generated near-continuous data streams on meteorological, physical and bio-optical parameters. In turn, the OFP deep flux record has provided an essential reference point that enables direct evaluation of the biogeochemical consequences of the upper ocean variability observed by BATS and

  13. Heat fluxes and roll circulations over the western Gulf Stream during an intense cold-air outbreak

    NASA Technical Reports Server (NTRS)

    Chou, Shu-Hsien; Ferguson, Michael P.

    1991-01-01

    Turbulence and heat fluxes in the marine atmospheric boundary layer (MABL) for three aircraft stacks near the western Gulf Stream front, observed during the Genesis of Atlantic Lows Experiment (GALE) January 28, 1986 cold-air outbreak, has been studied using mixed-layer scaling. The GOES image and stability parameter indicates that these three stacks were in the roll vortex regime. The turbulence structure in the MABL is studied for this case, as well as the significance of roll vortices to heat fluxes. The roll circulations are shown to contribute significantly to the sensible (temperature) and latent heat (moisture) fluxes with importance increasing upward. The results suggest that the entrainment at the MABL top might affect the the budgets of temperature and humidity fluxes in the lower MABL, but not in the unstable surface layer.

  14. Composition of dispersed sedimentary matter and fluxes in the water column of the Caspian Sea

    NASA Astrophysics Data System (ADS)

    Lisitzin, A. P.; Lukashin, V. N.

    2015-09-01

    This article presents the first data on the chemical composition of dispersed matter from sediment traps with analysis of the sedimentary components that constitute suspended particulate matter (amorphous silica, organic matter (OM), carbonates, and lithogenic matter). It is established that the annual variability of fluxes demonstrates its seasonal growth in spring and summer. High fluxes of these components over the northern and southern slopes of the Derbent Basin are determined by deposition of material from the nepheloid layer formed by the contour current.

  15. The Air-Sea Interface and Surface Stress under Tropical Cyclones

    NASA Astrophysics Data System (ADS)

    Soloviev, Alexander; Lukas, Roger; Donelan, Mark; Ginis, Isaac

    2013-04-01

    Air-sea interaction dramatically changes from moderate to very high wind speed conditions (Donelan et al. 2004). Unresolved physics of the air-sea interface are one of the weakest components in tropical cyclone prediction models. Rapid disruption of the air-water interface under very high wind speed conditions was reported in laboratory experiments (Koga 1981) and numerical simulations (Soloviev et al. 2012), which resembled the Kelvin-Helmholtz instability at an interface with very large density difference. Kelly (1965) demonstrated that the KH instability at the air-sea interface can develop through parametric amplification of waves. Farrell and Ioannou (2008) showed that gustiness results in the parametric KH instability of the air-sea interface, while the gusts are due to interacting waves and turbulence. The stochastic forcing enters multiplicatively in this theory and produces an exponential wave growth, augmenting the growth from the Miles (1959) theory as the turbulence level increases. Here we complement this concept by adding the effect of the two-phase environment near the mean interface, which introduces additional viscosity in the system (turning it into a rheological system). The two-phase environment includes air-bubbles and re-entering spray (spume), which eliminates a portion of the wind-wave wavenumber spectrum that is responsible for a substantial part of the air sea drag coefficient. The previously developed KH-type interfacial parameterization (Soloviev and Lukas 2010) is unified with two versions of the wave growth model. The unified parameterization in both cases exhibits the increase of the drag coefficient with wind speed until approximately 30 m/s. Above this wind speed threshold, the drag coefficient either nearly levels off or even slightly drops (for the wave growth model that accounts for the shear) and then starts again increasing above approximately 65 m/s wind speed. Remarkably, the unified parameterization reveals a local minimum

  16. Seasonal biogeochemical fluxes of 234Th and210Po in the Upper Sargasso Sea: Influence from atmospheric iron deposition

    NASA Astrophysics Data System (ADS)

    Kim, Guebuem; Church, Thomas M.

    2001-09-01

    The naturally occurring radionuclide tracers, 234Th-238U and 210Po-210Pb pairs, were measured bimonthly at the Bermuda Atlantic Time-Series Study (BATS) site in the Sargasso Sea from October 1996 to August 1997. Biological production and biogeochemical fluxes of thorium, polonium, and particulate organic carbon were highest in December 1996 and August 1997. Although the enhanced production and fluxes in December 1996 could be due to winter nitrate inputs from the subsurface ocean, those in August 1997 were not expected, on the basis of the nutrient mass balance and extreme stratification of the Sargasso Sea during this summer. The fixed-nutrient inputs from the atmosphere, eddy intrusion, or deepwater upwelling were unlikely sources of such elevated summer productivity. Alternatively, the unusually high atmospheric "wet" deposition of Fe, which occurred during this summer period, appears to have fueled high nitrogen fixation and thus greater carbon and reactive-element export. Also as important, ocean production did not respond to significant "dry" deposition of Fe. This seems to be due to the reported lower solubility of Fe dust in seawater versus rainwater.

  17. Dynamic Effects of Airborne Water Droplets on Air-Sea Interactions: Sea-Spray and Rain

    DTIC Science & Technology

    2007-09-30

    SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10 . SPONSOR/MONITOR’S ACRONYM(S) 11. SPONSOR/MONITOR’S REPORT NUMBER(S) 12. DISTRIBUTION/AVAILABILITY...In order to assure a sufficiently long residence time to obtain statistical properties for this test case, the droplet was released at 10 meters...velocity is approximately 85% of the 10 -m wind speed. It should be noted that this effect also exist with sea spray, albeit to a lesser extent

  18. Base flow and stormwater net fluxes of carbon and trace metals to the Mediterranean sea by an urbanized small river.

    PubMed

    Nicolau, R; Lucas, Y; Merdy, P; Raynaud, M

    2012-12-15

    Base flow and storm flow events from a small, urbanized Mediterranean river located in the South of France were studied to evaluate net fluxes from the continent to the coastal sea water. Considered variables were: pH, conductivity, redox potential, temperature, dissolved O(2), SPM (Suspended Particulate Matter), Cl(-), NO(3)(-), SO(4)(2-), Na(+), K(+), Mg(2+), Ca(2+), DOC (Dissolved Organic Carbon), Cu, Zn, Cd and Pb in the dissolved fraction and POC (Particulate Organic Carbon), Cr, Mn, Fe, Ni, Cu, Zn, Cd and Pb in the particulate fraction. If rainfall intensity and antecedent rainfall history were sufficient to explain many observed variations, the patterns of particles and solutes transport greatly varied from one storm event to another. SPM, POC, particulate Cu, Zn, Cd and Pb had similar behavior characterized by an immediate increase at the beginning of the storm flow and the highest values at the first high discharge peak. Among dissolved species, Cl(-), SO(4)(2-), Na(+), Ca(2+) and Mg(2+) had a behavior very similar one to the other. They exhibited high concentrations and enrichment factors at the beginning of the storm flow, due to fast leaching of highly labile species. Their concentrations decreased during posterior discharge peaks but positive enrichment factors indicated permanent sources for these ions. DOC, K(+) and NO(3)(-) had different behaviors which indicated sources positively correlated with rainfall intensity. A 3D-fluorescence study showed that the humified organic matter contribution to DOC increased during storm flow. Relationships between DOC and dissolved Cu and Pb indicated differences in organic-matter binding properties between dry and humid periods. Storm flow were responsible for more than 90% of the annual output to the sea of SPM, POC and particulate Cu, Zn, Cd and Pb and more than 70% for dissolved Pb, Cd, NO(3)(-) and DOC. For the other dissolved species, outputs were balanced between base flow and storm flow. Contrary to what

  19. A Numerical Study of Tropical Sea-Air Interactions Using a Cloud Resolving Model Coupled with an Ocean Mixed-Layer Model

    NASA Technical Reports Server (NTRS)

    Shie, Chung-Lin; Tao, Wei-Kuo; Johnson, Dan; Simpson, Joanne; Li, Xiaofan; Sui, Chung-Hsiung; Einaudi, Franco (Technical Monitor)

    2001-01-01

    Coupling a cloud resolving model (CRM) with an ocean mixed layer (OML) model can provide a powerful tool for better understanding impacts of atmospheric precipitation on sea surface temperature (SST) and salinity. The objective of this study is twofold. First, by using the three dimensional (3-D) CRM-simulated (the Goddard Cumulus Ensemble model, GCE) diabatic source terms, radiation (longwave and shortwave), surface fluxes (sensible and latent heat, and wind stress), and precipitation as input for the OML model, the respective impact of individual component on upper ocean heat and salt budgets are investigated. Secondly, a two-way air-sea interaction between tropical atmospheric climates (involving atmospheric radiative-convective processes) and upper ocean boundary layer is also examined using a coupled two dimensional (2-D) GCE and OML model. Results presented here, however, only involve the first aspect. Complete results will be presented at the conference.

  20. Submarine groundwater discharge and associated nutrient fluxes into the Southern Yellow Sea: A case study for semi-enclosed and oligotrophic seas-implication for green tide bloom

    NASA Astrophysics Data System (ADS)

    Liu, Jian'an; Su, Ni; Wang, Xilong; Du, Jinzhou

    2017-01-01

    The biogenic elements concentrations in a coastal bay/estuary are strongly influenced not only by riverine input but also by submarine groundwater discharge (SGD) which has been identified as a typical process of land/ocean interactions in coastal zones. To assess the role of SGD in nutrient fluxes in the Southern Yellow Sea (SYS), 228Ra activities were measured in seawater collected in May 2014. Analyzing the sources and sinks of 228Ra, the flux of excess 228Ra through SGD was estimated to be (2.2 ± 1.0) ×1015 dpm yr-1. Based on the 228Ra mass balance model, we estimated the average SGD flux to be approximately (1.3 ± 0.87) ×1012 m3 yr-1 over the entire SYS, which is at least 3.3 times the estimated annual delivery from the Changjiang River into the SYS (˜1.3 × 1011 m3 yr-1). The SGD-derived biogenic elements loads (dissolved inorganic nitrogen (DIN), phosphorus (DIP) and silicon (DSi)) were estimated as (487 ± 384) × 109 mol yr-1, (2.8 ± 2.2) × 109 mol yr-1, and (313 ± 259) × 109 mol yr-1, respectively, which are approximately 18 times, 7 times and 13 times the riverine input from both mainland China and Korea. The accumulation nutrient fluxes derived by SGD may play one of the most important roles in the green tide bloom that originated from the Subei Shoal zone in the SYS. Additionally, DIN and DIP via SGD can provide the necessary amounts of nutrient for recovering nutrient concentrations to normal levels after the green tide bloom is terminated.

  1. Measurements of mixing layer height variability during the Ligurian air-sea interaction experiment (LASIE '07)

    NASA Astrophysics Data System (ADS)

    Förster, J.

    2009-09-01

    Air-sea interaction processes play a dominant role with respect to detection ranges of shipborne radar and infrared sensor systems. Especially in the littoral most often temperature and humidity gradients affect propagation paths and are the reason for abnormal phenomena such as ducting or mirage. Besides refractivity, spray and aerosols ejected from the sea surface can further degrade the quality of shipborne surveillance systems. Thus environmental effects might seriously hamper ship self defense. During the Ligurian Air-Sea Interaction Experiment (LASIE '07 - 16.06.-26.06.2007) the Federal Armed Forces Underwater Acoustics and Marine Geophysics Research Institute (FWG) carried out simultaneous in-situ measurements of meteorological and oceanographic parameters to study air-sea interaction processes with respect to littoral boundary layer variability. The characterization of the environment included both, in-situ measurements of atmospheric and sea surface parameters. Investigations were carried out on board RV PLANET, RV URANIA and at the ODAS-Italy1 buoy of the Italian National Council of Research (CNR). On board RV PLANET the sea surface and meteorological conditions were analyzed by two multi-sensor buoys, ship sensors and radiosondes. Emphasis was given to the vertical structure of the Marine Boundary Layer (MBL) and its variability. It was analyzed by a one lense lidar ceilometer CL31, a tethersonde system TT12 and radiosondes RS92 (Vaisala). The latter were launched every three hours. The TT12 consisted of three radiosondes, which could be adapted to separate altitudes of special interest. The experiment was characterized by changing meteorological conditions resulting in offshore and onshore blowing winds. In the first case the air temperature TAir was higher than the sea surface temperature TWater leading to a very stable surface layer. This situation was associated with a strong temperature inversion and a very clear atmosphere with a visibility of

  2. Bora event variability and the role of air-sea feedback

    USGS Publications Warehouse

    Pullen, J.; Doyle, J.D.; Haack, T.; Dorman, C.; Signell, R.P.; Lee, C.M.

    2007-01-01

    A two-way interacting high resolution numerical simulation of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM) and Coupled Ocean/ Atmosphere Mesoscale Prediction System (COAMPS??) was conducted to improve forecast momentum and heat flux fields, and to evaluate surface flux field differences for two consecutive bora events during February 2003. (COAMPS?? is a registered trademark of the Naval Research Laboratory.) The strength, mean positions and extensions of the bora jets, and the atmospheric conditions driving them varied considerably between the two events. Bora 1 had 62% stronger heat flux and 51% larger momentum flux than bora 2. The latter displayed much greater diurnal variability characterized by inertial oscillations and the early morning strengthening of a west Adriatic barrier jet, beneath which a stronger west Adriatic ocean current developed. Elsewhere, surface ocean current differences between the two events were directly related to differences in wind stress curl generated by the position and strength of the individual bora jets. The mean heat flux bias was reduced by 72%, and heat flux RMSE reduced by 30% on average at four instrumented over-water sites in the two-way coupled simulation relative to the uncoupled control. Largest reductions in wind stress were found in the bora jets, while the biggest reductions in heat flux were found along the north and west coasts of the Adriatic. In bora 2, SST gradients impacted the wind stress curl along the north and west coasts, and in bora 1 wind stress curl was sensitive to the Istrian front position and strength. The two-way coupled simulation produced diminished surface current speeds of ???12% over the northern Adriatic during both bora compared with a one-way coupled simulation. Copyright 2007 by the American Geophysical Union.

  3. Mueller matrix imaging of targets under an air-sea interface.

    PubMed

    Zhai, Peng-Wang; Kattawar, George W; Yang, Ping

    2009-01-10

    The Mueller matrix imaging method is a powerful tool for target detection. In this study, the effect of the air-sea interface on the detection of underwater objects is studied. A backward Monte Carlo code has been developed to study this effect. The main result is that the reflection of the diffuse sky light by the interface reduces the Mueller image contrast. If the air-sea interface is ruffled by wind, the distinction between different regions of the underwater target is smoothed out. The effect of the finite size of an active light source is also studied. The image contrast is found to be relatively insensitive to the size of the light source. The volume scattering function plays an important role on the underwater object detection. Generally, a smaller asymmetry parameter decreases the contrast of the polarimetry images.

  4. The contribution of ship emissions to air pollution in the North Sea regions.

    PubMed

    Matthias, Volker; Bewersdorff, Ines; Aulinger, Armin; Quante, Markus

    2010-06-01

    As a consequence of the global distribution of manufacturing sites and the increasing international division of labour, ship traffic is steadily increasing and is becoming more and more important as an origin of air pollution. This study investigates the impact of ship emissions in coastal areas of the North Sea under conditions of the year 2000 by means of a regional chemistry transport model which runs on a sufficiently high resolution to study air pollution in coastal regions. It was found that northern Germany and Denmark in summer suffer from more than 50% higher sulphate, nitrate and ammonium aerosol concentrations due to contributions from ships. The implementation of a sulphur emission control area (SECA) in the North Sea, as it was implemented at the end of 2007, directly results in reduced sulphur dioxide and sulphate aerosol concentrations while nitrate aerosol concentrations are slightly increased.

  5. The influence of coastal shape on winter mesoscale air-sea interaction

    NASA Technical Reports Server (NTRS)

    Atlas, D.; Chou, S.-H.; Byerly, W. P.

    1983-01-01

    In cold air outbreaks, the combination of coastal shape and sea surface isotherms has a profound effect in the establishment of mesoscale atmospheric circulation, due to differential heating resulting from both overwater path length and underlying sea surface temperature (SST) variations. Where coastal effects are dominant, a mesoscale front forms downstream of the point which marks the major bend in the coastline's orientation. The strength of the induced mesoscale circulation depends on the original contrast between the land air temperature and the SST. It is noted that where the coastline and the isotherm pattern are approximately normal to the mean boundary layer flow, and thermal contrast is sufficiently large, the cloud streets formed downstream will be convective in nature, and oriented with the axis of roll vortices along the wind direction.

  6. Disentangling the air-sea interaction in the South Atlantic Convergence Zone

    NASA Astrophysics Data System (ADS)

    tirabassi, giulio; masoller, cristina; barreiro, marcelo

    2014-05-01

    Air-sea interaction in the region of the South Atlantic Convergence Zone (SACZ) is disentangled using Granger causality as a measure of directional coupling. Calculation of the area weighted connectivity indicates that the SACZ region is the one with largest mutual air-sea connectivity in the south Atlantic basin during summertime. Focusing on the leading mode of daily coupled variability, Granger causality allows distinguishing four regimes characterized by different coupling: there are years in which the forcing is mainly directed from the atmosphere to the ocean, years in which the ocean forces the atmosphere, years in which the influence is mutual, and years in which the coupling is not significant. A composite analysis shows that ocean-driven events have atmospheric anomalies that develop first and are strongest over the ocean, while in events without coupling anomalies develop from the continent where they are strongest and have weaker oceanic extension.

  7. Variability of nutrient and particulate matter fluxes between the sea and a polder after partial tidal restoration, Northwestern France

    NASA Astrophysics Data System (ADS)

    Dausse, A.; Mérot, P.; Bouzillé, J.-B.; Bonis, A.; Lefeuvre, J.-C.

    2005-08-01

    This paper aims to investigate the patterns of exchanges of nutrients and suspended sediments between the sea and a polder, after partial tidal restoration, and to assess if these are comparable to those observed in natural salt marshes. The study site, situated in the Bay of Veys, in Northwestern France, was embanked in the 1870s and accidentally reconnected to the sea in 1990. Water now flows in and out of the polder by a single communication point with the sea, which facilitated water sampling and flux calculation for dissolved and particulate elements. The study was carried out for two years, from May 2002 to April 2004. Results showed that for all the months studied the water flowing out of the polder had lower concentrations of nitrates and suspended sediments, which lead to a retention of these elements throughout the year. Nitrates uptakes in the polder were much higher in winter (up to 473.9 g N ha -1 tide -1) than in summer where they were close to zero. The retention of suspended sediment could be over 80% of the import and was mainly composed of organic matter. Finally, the concentrations of dissolved organic carbon were higher in outflow than inflow water, but due to unbalanced water budgets this lead to low quantities imported in summer and higher amounts exported for all other seasons. No interpretable pattern was observed for ammonium. The nature of these fluxes, according to literature, is close to those observed in immature salt marshes, so as far as restoration is concerned, it has been shown that partial tidal restoration can allow the restitution of the salt marsh exchange functions that were studied.

  8. Plankton ecosystem functioning and nitrogen fluxes in the most oligotrophic waters of the Beaufort Sea, Arctic Ocean: a modeling study

    NASA Astrophysics Data System (ADS)

    Le Fouest, V.; Zakardjian, B.; Xie, H.; Raimbault, P.; Joux, F.; Babin, M.

    2012-10-01

    The Arctic Ocean (AO) undergoes profound changes of its physical and biotic environments due to climate change. The greater light exposure and stratification alter its plankton ecosystem structure, functioning and productivity promoting oligotrophy in some areas as the Beaufort Sea. A one-dimension (1-D) physical-biological coupled model based on the large multiparametric database of the Malina project in the Beaufort Sea was used (i) to infer the functioning and nitrogen fluxes within the summer plankton ecosystem and (ii) to assess the model sensitivity to key light-associated processes involved in nutrient recycling and phytoplankton growth. The coupled model suggested that ammonium photochemically produced from photosensitive dissolved organic nitrogen (i.e. photoammonification process) was a necessary nitrogen source to achieve the observed levels of microbial biomass and production. It contributed to ca. two-thirds and one-third of the simulated surface (0-10 m) and depth-integrated primary and bacterial production, respectively. The model also suggested that carbon to chlorophyll ratios for small (< 5 μm) phytoplankton (ca. 15-45 g g-1) lower than those commonly used in biogeochemical models applied to the AO were required to simulate the observed herbivorous versus microbial food web competition and realistic nitrogen fluxes in the Beaufort Sea oligotrophic waters. In face of accelerating Arctic warming, more attention should be paid in the future to the mechanistic processes involved in food webs and functional groups competition, nutrient recycling and primary production in poorly productive waters of the AO as they are expected to expand rapidly.

  9. Carbon dioxide production in surface sediments of temporarily anoxic basins (Baltic Sea) and resulting sediment-water interface fluxes

    NASA Astrophysics Data System (ADS)

    Böttcher, M. E.; Al-Raei, A. M.; Winde, V.; Lenz, C.; Dellwig, O.; Leipe, T.; Segl, M.; Struck, U.

    2009-04-01

    Organic matter is mineralized in marine sediments by microbial activity using predominantly oxygen, sulfate, and metal oxides as electron acceptors. Modern euxinic basins as found in the Baltic Sea or the Black Sea are of particular importance because they may serve as type systems for anoxia in Earth's history. We present here results from biogeochemical investigations carried out in the Baltic deeps (Gotland Basin, Landsort Deep) during the first scientific cruise of RV M.S. MERIAN in 2006, additionally during RV Prof. Penck cruises in 2006 and 2007. Short sediment cores were obtained with a multi-corer and analyzed for particulate and dissolved main, minor and trace elements, pH, DIC, methane alkalinity, besides the stable carbon isotopes of dissolved inorganic carbon (DIC). Microsensors were applied to analyze steep gradients of oxygen, sulphide and sulphate. Pore water profiles are evaluated in terms of process rates and associated element fluxes using the PROFILE software (Berg et al., 1998, L&O). Gross and net anaerobic mineralization rates were additionally obtained from core incubations with 35S. Steep gradients in DIC are associated with a strong enrichment of the light stable isotope resulting in the Gotland basin from oxidized OM. Element fluxes across the sediment-water interface are compared with literature data and show for the Baltic Sea a dependence from bottom water redox conditions, and sediment compositions and formation conditions (e.g., accumulation rates). DIC in the anoxic part of the water column in the Landsort Deep and the Gotland Deep show relatively similar isotope values, close to the bottom water value, but steep gradients towards heavier values above the pelagic redoxcline. Acknowledgements: The research was supported by Leibniz IO Warnemünde, DFG (Cruise RV MSM MERIAN 01), and MPG. Thanks to B. Schneider and F. Pollehne stimulating discussions, and S. Lage and A. Schipper for technical support.

  10. Dissolved organic nitrogen in wet deposition in a coastal city (Keelung) of the southern East China Sea: Origin, molecular composition and flux

    NASA Astrophysics Data System (ADS)

    Chen, You-Xin; Chen, Hung-Yu; Wang, Wei; Yeh, Jun-Xian; Chou, Wen-Chen; Gong, Gwo-Ching; Tsai, Fu-Jung; Huang, Shih-Jen; Lin, Cheng-Ting

    2015-07-01

    In this study, we collected and analyzed rainwater samples from Keelung, Taiwan, which is a coastal city located south of the East China Sea (ECS). From January 2012 until June 2013, 78 rainwater samples were collected over an 18-month period and were analyzed to examine the total dissolved nitrogen (TDN) and major ions in the rainwater. TDN can be divided into dissolved inorganic nitrogen (DIN) and dissolved organic nitrogen (DON). This study, which focused on the composition of DON, is the first study to employ ultrafiltration to separate DON in wet deposition into low molecular weight-DON (LMW-DON) and high molecular weight-DON (HMW-DON). The concentrations of dissolved nitrogen species observed in the research area between November 2012 and April 2013 were relatively high, whereas those observed between May 2013 and October 2012 were relatively low. The patterns of changes over time were similar to those of non-sea-salt (nss) ions. The concentration of nss-ions was high during months in which the total dissolved nitrogen concentration was also high, which occur frequently during the spring and winter. In addition, the concentration of nss-ions was low during months in which the TDN concentration was low, which primarily occurs during the summer. The amounts of DIN and DON accounted for 63 ± 5% and 37 ± 5% of the TDN, respectively, and the percentage of the DIN was higher during the spring and winter. The concentrations of LMW-DON and HMW-DON, which accounted for 84 ± 3% and 16 ± 3% of the DON, respectively, were both high in the winter and low in the summer. The percentage of LMW-DON increased in the summer, possibly because of the numerous oceanic air masses and typhoons. Furthermore, the percentage of HMW-DON increased in the spring, potentially due to biomass burning during agricultural activities. Regarding the wet deposition fluxes, the DIN (197 ± 10.27 mmol m-2 yr-1) and DON (129 ± 6.82 mmol m-2 yr-1) accounted for approximately 64% and 36% of the

  11. Impacts of air-sea interactions on regional air quality predictions using WRF/Chem v3.6.1 coupled with ROMS v3.7: southeastern US example

    NASA Astrophysics Data System (ADS)

    He, J.; He, R.; Zhang, Y.

    2015-11-01

    Air-sea interactions have significant impacts on coastal convection and surface fluxes exchange, which are important for the spatial and vertical distributions of air pollutants that affect public health, particularly in densely populated coastal areas. To understand the impacts of air-sea interactions on coastal air quality predictions, sensitivity simulations with different cumulus parameterization schemes and atmosphere-ocean coupling are conducted in this work over southeastern US in July 2010 using the Weather Research and Forecasting Model with Chemistry (WRF/Chem). The results show that different cumulus parameterization schemes can result in an 85 m difference in the domain averaged planetary boundary layer height (PBLH), and 4.8 mm difference in the domain averaged daily precipitation. Comparing to WRF/Chem without air-sea interactions, WRF/Chem with a 1-D ocean mixed layer model (WRF/Chem-OML) and WRF/Chem coupled with a 3-D Regional Ocean Modeling System (WRF/Chem-ROMS) predict the domain averaged changes in the sea surface temperature of 0.1 and 1.0 °C, respectively. The simulated differences in the surface concentrations of ozone (O3) and PM2.5 between WRF/Chem-ROMS and WRF/Chem can be as large as 17.3 ppb and 7.9 μg m-3, respectively. The largest changes simulated from WRF/Chem-ROMS in surface concentrations of O3 and particulate matter with diameter less than and equal to 2.5 μm (PM2.5) occur not only along coast and remote ocean, but also over some inland areas. Extensive validations against observations, show that WRF/Chem-ROMS improves the predictions of most cloud and radiative variables, and surface concentrations of some chemical species such as sulfur dioxide, nitric acid, maximum 1 h and 8 h O3, sulfate, ammonium, nitrate, and particulate matter with diameter less than and equal to 10 μm (PM10). This illustrates the benefits and needs of using coupled atmospheric-ocean model with advanced model representations of air-sea interactions for

  12. Small Autonomous Air/Sea System Concepts for Coast Guard Missions

    NASA Technical Reports Server (NTRS)

    Young, Larry A.

    2005-01-01

    A number of small autonomous air/sea system concepts are outlined in this paper that support and enhance U.S. Coast Guard missions. These concepts draw significantly upon technology investments made by NASA in the area of uninhabited aerial vehicles and robotic/intelligent systems. Such concepts should be considered notional elements of a greater as-yet-not-defined robotic system-of-systems designed to enable unparalleled maritime safety and security.

  13. pCO2 distributions and air-water CO2 fluxes in the Columbia River estuary

    NASA Astrophysics Data System (ADS)

    Evans, Wiley; Hales, Burke; Strutton, Peter G.

    2013-01-01

    Sources of time and space variability in the distributions of surface water carbon dioxide partial pressure (pCO2) and air-water CO2 flux were quantified in the Columbia River estuary (CRE) during five cruises in spring, summer and autumn 2007/08. The CRE is an upwelling margin river-dominated mesotidal system that is an estuary class not represented in global flux compilations. Data from the CRE show instances of pCO2 under and oversaturation with respect to the atmosphere during every season in association with tidal, wind, biological and storm-driven sources of variability. On average the CRE is a sink for atmospheric CO2 during spring and a source during summer and autumn, with large positive air-water CO2 fluxes during the snowmelt freshet coinciding with the functional transition in the estuary. It is hypothesized here that interannual variability in size of the snowmelt freshet largely influences the extent of springtime CO2 uptake in the CRE, and subsequently the magnitude of net annual CO2 emission from the estuary. Data collected during an autumn storm show that large fluxes can drop quickly, even in the presence of high gas transfer velocities, because of rapid CO2 exchange with the atmosphere in this weakly buffered system. Combining seasonal observations of CO2 exchange with an assumption of winter conditions, we estimate that the net annual emission from the CRE is approximately 1 mol C m-2 yr-1. The air-water CO2 fluxes reported here are the first from an upwelling margin river-dominated mesotidal estuary, and the estimate of net annual exchange is substantially lower than those from other tidal and/or large river systems represented in global flux compilations.

  14. Validation study of air-sea gas transfer modeling

    SciTech Connect

    Asher, W.E.; Farley, P.J.; Leifer, I.S.

    1995-07-01

    Laboratory results have demonstrated the importance of bubble plumes to air-water gas transfer (Asher et al., 1994). Bubble plumes enhance gas transfer by disrupting surface films, by directly transporting a gas, and by the creation of turbulence. Models of bubble gas transfer have been developed by different authors (Atkinson, 1973; Memery and Merlivat, 1985; Woolf and Thorpe, 1991) to determine the magnitude of gas transfer due to bubbles. Laboratory measurements of both the gas transfer rate k{sub L}, and the bubble distribution {phi} in a whitecap simulation tank (WST) have allowed these models to be validated and deficiencies in the theoretical assumptions to be explored. In the WST, each bucket tip simulates a wave breaking event. Important tests of these models include whether they can explain the experimentally determined solubility and Schmidt number dependency of k{sub L}, predict the time varying bubble concentrations, predict the evasion-invasion asymmetry, and predict the fraction of k{sub L} due to bubble plumes. Four different models were tested, a steady state model (Atkinson, 1973), a non-turbulence model with constant bubble radius (Memery and Merlivat, 1985), a turbulence model with constant bubble radius (Wolf and Thorpe, 1991), and a turbulence model with varying bubble radius. All models simulated multiple bubble tip cycles. The two turbulence models were run for sufficient tip cycles to generate statistically significant number of eddies ({number_sign}{gt}50) for bubbles affected by turbulence (V{sub B}{le}V{sub T}), found to be at least four tip cycles. The models allowed up to nine gases simultaneously and were run under different conditions of trace and major gas concentrations and partial pressures.

  15. Effects of acute fresh water exposure on water flux rates and osmotic responses in Kemp's ridley sea turtles (Lepidochelys kempi).

    PubMed

    Ortiz, R M; Patterson, R M; Wade, C E; Byers, F M

    2000-09-01

    Water flux rates and osmotic responses of Kemp's Ridley sea turtles (Lepidochelys kempi) acutely exposed to fresh water were quantified. Salt-water adapted turtles were exposed to fresh water for 4 d before being returned to salt water. During the initial salt water phase, absolute and relative water flux rates were 1.2+/-0.1 l d(-1) and 123.0+/-6.8 ml kg(-1) d(-1), respectively. When turtles were exposed to fresh water, rates increased by approximately 30%. Upon return to salt water, rates decreased to original levels. Plasma osmolality, Na(+), K(+), and Cl(-) decreased during exposure to fresh water, and subsequently increased during the return to salt water. The Na(+):K(+) ratio was elevated during the fresh water phase and subsequently decreased upon return to salt water. Aldosterone and corticosterone were not altered during exposure to fresh water. Elevated water flux rates during fresh water exposure reflected an increase in water consumption, resulting in a decrease in ionic and osmotic concentrations. The lack of a change in adrenocorticoids to acute fresh water exposure suggests that adrenal responsiveness to an hypo-osmotic environment may be delayed in marine turtles when compared to marine mammals.

  16. Effects of acute fresh water exposure on water flux rates and osmotic responses in Kemp's ridley sea turtles (Lepidochelys kempi)

    NASA Technical Reports Server (NTRS)

    Ortiz, R. M.; Patterson, R. M.; Wade, C. E.; Byers, F. M.

    2000-01-01

    Water flux rates and osmotic responses of Kemp's Ridley sea turtles (Lepidochelys kempi) acutely exposed to fresh water were quantified. Salt-water adapted turtles were exposed to fresh water for 4 d before being returned to salt water. During the initial salt water phase, absolute and relative water flux rates were 1.2+/-0.1 l d(-1) and 123.0+/-6.8 ml kg(-1) d(-1), respectively. When turtles were exposed to fresh water, rates increased by approximately 30%. Upon return to salt water, rates decreased to original levels. Plasma osmolality, Na(+), K(+), and Cl(-) decreased during exposure to fresh water, and subsequently increased during the return to salt water. The Na(+):K(+) ratio was elevated during the fresh water phase and subsequently decreased upon return to salt water. Aldosterone and corticosterone were not altered during exposure to fresh water. Elevated water flux rates during fresh water exposure reflected an increase in water consumption, resulting in a decrease in ionic and osmotic concentrations. The lack of a change in adrenocorticoids to acute fresh water exposure suggests that adrenal responsiveness to an hypo-osmotic environment may be delayed in marine turtles when compared to marine mammals.

  17. A controlling role for the air-sea interface in the chemical processing of reactive nitrogen in the coastal marine boundary layer.

    PubMed

    Kim, Michelle J; Farmer, Delphine K; Bertram, Timothy H

    2014-03-18

    The lifetime of reactive nitrogen and the production rate of reactive halogens in the marine boundary layer are strongly impacted by reactions occurring at aqueous interfaces. Despite the potential importance of the air-sea interface in serving as a reactive surface, few direct field observations are available to assess its impact on reactive nitrogen deposition and halogen activation. Here, we present direct measurements of the vertical fluxes of the reactant-product pair N2O5 and ClNO2 to assess the role of the ocean surface in the exchange of reactive nitrogen and halogens. We measure nocturnal N2O5 exchange velocities (Vex = -1.66 ± 0.60 cm s(-1)) that are limited by atmospheric transport of N2O5 to the air-sea interface. Surprisingly, vertical fluxes of ClNO2, the product of N2O5 reactive uptake to concentrated chloride containing surfaces, display net deposition, suggesting that elevated ClNO2 mixing ratios found in the marine boundary layer are sustained primarily by N2O5 reactions with aerosol particles. Comparison of measured deposition rates and in situ observations of N2O5 reactive uptake to aerosol particles indicates that N2O5 deposition to the ocean surface accounts for between 26% and 42% of the total loss rate. The combination of large Vex, N2O5 and net deposition of ClNO2 acts to limit NOx recycling rates and the production of Cl atoms by shortening the nocturnal lifetime of N2O5. These results indicate that air-sea exchange processes account for as much as 15% of nocturnal NOx removal in polluted coastal regions and can serve to reduce ClNO2 concentrations at sunrise by over 20%.

  18. Direct measurements of air-sea CO2 exchange over a coral reef

    NASA Astrophysics Data System (ADS)

    McGowan, Hamish A.; MacKellar, Mellissa C.; Gray, Michael A.

    2016-05-01

    Quantification of CO2 exchange with the atmosphere over coral reefs has relied on microscale measurements of pCO2 gradients across the air-sea interfacial boundary; shipboard measurements of air-sea CO2 exchange over adjacent ocean inferred to represent over reef processes or ecosystem productivity modeling. Here we present by way of case study the first direct measurements of air-sea CO2 exchange over a coral reef made using the eddy covariance method. Research was conducted during the summer monsoon over a lagoonal platform reef in the southern Great Barrier Reef, Australia. Results show the reef flat to be a net source of CO2 to the atmosphere of similar magnitude as coastal lakes, while adjacent shallow and deep lagoons were net sinks as was the surrounding ocean. This heterogeneity in CO2 exchange with the atmosphere confirms need for spatially representative direct measurements of CO2 over coral reefs to accurately quantify their role in atmospheric carbon budgets.

  19. Geochemistry of dispersed sedimentary matter and its fluxes in the water column of the Caspian Sea

    NASA Astrophysics Data System (ADS)

    Lukashin, V. N.; Lisitzin, A. P.

    2016-09-01

    The first data on the chemical composition of dispersed matter from sedimentary traps are reported. The suspended components of sedimentary matter (amorphous silica, organic matter, carbonates, and lithogenic material, as well as Fe, Mn, and minor elements) are considered. As a result, it is shown that the intraannual variability in vertical fluxes of sedimentary matter is characterized by a seasonal increase in spring and autumn. The high fluxes of the components of sedimentary matter on the northern and southern slopes of the Derbent Basin in winter are explained by precipitation of material from the nepheloid layer that forms over the contour current.

  20. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer

    Margaret Torn

    2015-01-14

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  1. Flux of Nutrients Between the Middle and Southern Adriatic Sea (Gargano-Split section)

    DTIC Science & Technology

    2013-04-28

    P rather than N limited. The only exception is the northern Adriatic where high primary production and eutrophication are caused by high river...southeastern Adriatic Sea coastal strip an eutrophic area? Estuar. Coast. Shelf. Sci. 88, 395–406. http://dx.doi.org/10.1016/j.ecss.2010.04.020. Martin

  2. A Pictorial History of the Code 717 Unmanned Systems Group: Air, Land, and Sea. Volume 1: 1970-1999

    DTIC Science & Technology

    2016-04-28

    including a drill press, band saw, sheet-metal sheer, and forming brake. To provide heat during the winter and protect the Unmanned Systems Branch’s...TECHNICAL DOCUMENT 3289 April 2016 A Pictorial History of the Code 717 Unmanned Systems Group: Air, Land, and Sea Volume 1: 1970–1999 H. R...the Code 717 Unmanned Systems Group: Air, Land, and Sea Volume 1: 1970–1999 H. R. Everett Approved for public release

  3. Air-sea interactions and oceanic processes in the development of different Atlantic Niño patterns

    NASA Astrophysics Data System (ADS)

    Martin-Rey, Marta; Polo, Irene; Rodríguez-Fonseca, Belén; Lazar, Alban

    2016-04-01

    Atlantic Niño is the leading mode of inter-annual variability of the tropical Atlantic basin at inter-annual time scales. A recent study has put forward that two different Atlantic Niño patterns co-exist in the tropical Atlantic basin during negative phases of the Atlantic Multidecadal Oscillation. The leading mode, Basin-Wide (BW) Atlantic Niño is characterized by an anomalous warming extended along the whole tropical basin. The second mode, the Dipolar (D) Atlantic Niño presents positive Sea Surface Temperature (SST) anomalies in the central-eastern equatorial band, surrounded by negative ones in the North and South tropical Atlantic. The BW Atlantic Niño is associated with a weakening of both Azores and Sta Helena High, which reduces the tropical trades during previous autumn-winter. On the other hand, the D-Atlantic Niño is related to a strengthening of the Azores and a weakening of Helena High given rise to a meridional Sea Level Pressure (SLP) gradient that originates an intensification of the subtropical trades and anomalous westerlies along the equatorial band. This different wind forcing suggests that different oceanic processes could act in the development of the BW and D Atlantic Niño patterns. For this reason, an inter-annual simulation with the ocean NEMO model has been performed and the heat budget analysis has been analysed for each Atlantic Niño mode. The results suggest that the two Atlantic Nino configurations have different timing. The heat budget analysis reveals that BW Atlantic Nino SST pattern is due to anomalous air-sea heat fluxes in the south tropical and western equatorial Atlantic during the autumn-winter, while vertical processes are responsible of the warming in the central and eastern part of the basin during late-winter and spring. For the D-Atlantic Nino, the subtropical cooling is attributed to turbulent heat fluxes, the equatorial SST signal is mainly forced by vertical entrainment. The role of the oceanic waves in the

  4. The Flux-Anomaly-Forced Model Intercomparison Project (FAFMIP) contribution to CMIP6: investigation of sea-level and ocean climate change in response to CO2 forcing

    NASA Astrophysics Data System (ADS)

    Gregory, Jonathan M.; Bouttes, Nathaelle; Griffies, Stephen M.; Haak, Helmuth; Hurlin, William J.; Jungclaus, Johann; Kelley, Maxwell; Lee, Warren G.; Marshall, John; Romanou, Anastasia; Saenko, Oleg A.; Stammer, Detlef; Winton, Michael

    2016-11-01

    The Flux-Anomaly-Forced Model Intercomparison Project (FAFMIP) aims to investigate the spread in simulations of sea-level and ocean climate change in response to CO2 forcing by atmosphere-ocean general circulation models (AOGCMs). It is particularly motivated by the uncertainties in projections of ocean heat uptake, global-mean sea-level rise due to thermal expansion and the geographical patterns of sea-level change due to ocean density and circulation change. FAFMIP has three tier-1 experiments, in which prescribed surface flux perturbations of momentum, heat and freshwater respectively are applied to the ocean in separate AOGCM simulations. All other conditions are as in the pre-industrial control. The prescribed fields are typical of pattern and magnitude of changes in these fluxes projected by AOGCMs for doubled CO2 concentration. Five groups have tested the experimental design with existing AOGCMs. Their results show diversity in the pattern and magnitude of changes, with some common qualitative features. Heat and water flux perturbation cause the dipole in sea-level change in the North Atlantic, while momentum and heat flux perturbation cause the gradient across the Antarctic Circumpolar Current. The Atlantic meridional overturning circulation (AMOC) declines in response to the heat flux perturbation, and there is a strong positive feedback on this effect due to the consequent cooling of sea-surface temperature in the North Atlantic, which enhances the local heat input to the ocean. The momentum and water flux perturbations do not substantially affect the AMOC. Heat is taken up largely as a passive tracer in the Southern Ocean, which is the region of greatest heat input, while the weakening of the AMOC causes redistribution of heat towards lower latitudes. Future analysis of these and other phenomena with the wider range of CMIP6 FAFMIP AOGCMs will benefit from new diagnostics of temperature and salinity tendencies, which will enable investigation of the

  5. Benthic nutrient fluxes in the Eastern Gotland Basin (Baltic Sea) with particular focus on microbial mat ecosystems

    NASA Astrophysics Data System (ADS)

    Noffke, A.; Sommer, S.; Dale, A. W.; Hall, P. O. J.; Pfannkuche, O.

    2016-06-01

    Benthic fluxes and water column distributions of dissolved inorganic nitrogen (DIN) and total dissolved phosphate (PO43 -) were measured in situ at 7 sites across a redox gradient from oxic to anoxic bottom waters in the Eastern Gotland Basin (Baltic Sea). The study area was divided into the oxic zone (60 to ca. 80 m water depth, O2 > 30 μM), the hypoxic transition zone (HTZ, ca. 80 to 120 m, O2 < 30 μM) and the deep anoxic and sulfidic basin (> ca. 120 m). Sediments in the HTZ were covered by mats of vacuolated sulfur bacteria. Ammonium (NH4+) fluxes in the deep basin and the HTZ were elevated at 0.6 mmol m- 2 d- 1 and 1 mmol m- 2 d- 1, respectively. Nitrate (NO3-) fluxes were directed into the sediment at all stations in the HTZ and were zero in the deep basin. PO43 - release was highest in the HTZ at 0.23 mmol m- 2 d- 1, with a further release of 0.2 mmol m- 2 d- 1 in the deep basin. Up-scaling the benthic fluxes to the Baltic Proper equals 109 kt yr- 1 of PO43 - and 266 kt yr- 1 of DIN. This is eight- and two-fold higher than the total external load of P (14 kt yr- 1) and DIN (140 kt yr- 1) in 2006 (HELCOM 2009b). The HTZ makes an important contribution to the internal nutrient loading in the Baltic Proper, releasing 70% of P (76 kt yr- 1) and 75% of DIN (200 kt yr- 1) despite covering only 51% of area.

  6. Boundary layer warming by condensation - Air-sea interaction during an extreme cold air outbreak from the eastern coast of the United States

    NASA Technical Reports Server (NTRS)

    Grossman, Robert L.

    1988-01-01

    Studies on an intense cold air outbreak that took place after a cold air cyclogenesis on January 27, 1986 are reviewed. Particular attention is given to data obtained during a multiaircraft research mission carried out on January 28, 1986 as part of the Genesis of Atlantic Lows Experiment. It was found that condensation heating of the subcloud layer air was comparable to heating by turbulent flux divergence.

  7. Inverse modeling of Asian (222)Rn flux using surface air (222)Rn concentration.

    PubMed

    Hirao, Shigekazu; Yamazawa, Hiromi; Moriizumi, Jun

    2010-11-01

    When used with an atmospheric transport model, the (222)Rn flux distribution estimated in our previous study using soil transport theory caused underestimation of atmospheric (222)Rn concentrations as compared with measurements in East Asia. In this study, we applied a Bayesian synthesis inverse method to produce revised estimates of the annual (222)Rn flux density in Asia by using atmospheric (222)Rn concentrations measured at seven sites in East Asia. The Bayesian synthesis inverse method requires a prior estimate of the flux distribution and its uncertainties. The atmospheric transport model MM5/HIRAT and our previous estimate of the (222)Rn flux distribution as the prior value were used to generate new flux estimates for the eastern half of the Eurasian continent dividing into 10 regions. The (222)Rn flux densities estimated using the Bayesian inversion technique were generally higher than the prior flux densities. The area-weighted average (222)Rn flux density for Asia was estimated to be 33.0 mBq m(-2) s(-1), which is substantially higher than the prior value (16.7 mBq m(-2) s(-1)). The estimated (222)Rn flux densities decrease with increasing latitude as follows: Southeast Asia (36.7 mBq m(-2) s(-1)); East Asia (28.6 mBq m(-2) s(-1)) including China, Korean Peninsula and Japan; and Siberia (14.1 mBq m(-2) s(-1)). Increase of the newly estimated fluxes in Southeast Asia, China, Japan, and the southern part of Eastern Siberia from the prior ones contributed most significantly to improved agreement of the model-calculated concentrations with the atmospheric measurements. The sensitivity analysis of prior flux errors and effects of locally exhaled (222)Rn showed that the estimated fluxes in Northern and Central China, Korea, Japan, and the southern part of Eastern Siberia were robust, but that in Central Asia had a large uncertainty.

  8. Towards Improved Estimates of Ocean Heat Flux

    NASA Astrophysics Data System (ADS)

    Bentamy, Abderrahim; Hollman, Rainer; Kent, Elisabeth; Haines, Keith

    2014-05-01

    Recommendations and priorities for ocean heat flux research are for instance outlined in recent CLIVAR and WCRP reports, eg. Yu et al (2013). Among these is the need for improving the accuracy, the consistency, and the spatial and temporal resolution of air-sea fluxes over global as well as at region scales. To meet the main air-sea flux requirements, this study is aimed at obtaining and analyzing all the heat flux components (latent, sensible and radiative) at the ocean surface over global oceans using multiple satellite sensor observations in combination with in-situ measurements and numerical model analyses. The fluxes will be generated daily and monthly for the 20-year (1992-2011) period, between 80N and 80S and at 0.25deg resolution. Simultaneous estimates of all surface heat flux terms have not yet been calculated at such large scale and long time period. Such an effort requires a wide range of expertise and data sources that only recently are becoming available. Needed are methods for integrating many data sources to calculate energy fluxes (short-wave, long wave, sensible and latent heat) across the air-sea interface. We have access to all the relevant, recently available satellite data to perform such computations. Yu, L., K. Haines, M. Bourassa, M. Cronin, S. Gulev, S. Josey, S. Kato, A. Kumar, T. Lee, D. Roemmich: Towards achieving global closure of ocean heat and freshwater budgets: Recommendations for advancing research in air-sea fluxes through collaborative activities. INTERNATIONAL CLIVAR PROJECT OFFICE, 2013: International CLIVAR Publication Series No 189. http://www.clivar.org/sites/default/files/ICPO189_WHOI_fluxes_workshop.pdf

  9. Deriving clear-sky longwave spectral flux from spaceborne hyperspectral radiance measurements: a case study with AIRS observations

    NASA Astrophysics Data System (ADS)

    Chen, Xiuhong; Huang, Xianglei

    2016-12-01

    Previous studies have shown that longwave (LW) spectral fluxes have unique merit in climate studies. Using Atmospheric Infrared Sounder (AIRS) radiances as a case study, this study presents an algorithm to derive the entire LW clear-sky spectral fluxes from spaceborne hyperspectral observations. No other auxiliary observations are needed in the algorithm. A clear-sky scene is identified using a three-step detection method. The identified clear-sky scenes are then categorized into different sub-scene types using information about precipitable water, lapse rate and surface temperature inferred from the AIRS radiances at six selected channels. A previously established algorithm is then used to invert AIRS radiances to spectral fluxes over the entire LW spectrum at 10 cm-1 spectral interval. Accuracy of the algorithms is evaluated against collocated Clouds and the Earth's Radiant Energy System (CERES) observations. For nadir-view observations, the mean difference between outgoing longwave radiation (OLR) derived by this algorithm and the collocated CERES OLR is 1.52 Wm-2 with a standard deviation of 2.46 Wm-2. When the algorithm is extended for viewing zenith angle up to 45°, the performance is comparable to that for nadir-view results.

  10. Soil-Air Mercury Flux near a Large Industrial Emission Source before and after Closure (Flin Flon, Manitoba, Canada).

    PubMed

    Eckley, Chris S; Blanchard, Pierrette; McLennan, Daniel; Mintz, Rachel; Sekela, Mark

    2015-08-18

    Prior to its closure, the base-metal smelter in Flin Flon, Manitoba, Canada was one of the North America's largest mercury (Hg) emission sources. Our project objective was to understand the exchange of Hg between the soil and the air before and after the smelter closure. Field and laboratory Hg flux measurements were conducted to identify the controlling variables and used for spatial and temporal scaling. Study results showed that deposition from the smelter resulted in the surrounding soil being enriched in Hg (up to 99 μg g(-1)) as well as other metals. During the period of smelter operation, air concentrations were elevated (30 ± 19 ng m(-3)), and the soil was a net Hg sink (daily flux: -3.8 ng m(-2) h(-1)). Following the smelter closure, air Hg(0) concentrations were reduced, and the soils had large emissions (daily flux: 108 ng m(-2) h(-1)). The annual scaling of soil Hg emissions following the smelter closure indicated that the landscape impacted by smelter deposition emitted or re-emitted almost 100 kg per year. Elevated soil Hg concentrations and emissions are predicted to continue for hundreds of years before background concentrations are re-established. Overall, the results indicate that legacy Hg deposition will continue to cycle in the environment long after point-source reductions.

  11. Food for the deep sea: utilization, dispersal, and flux of nekton falls at the Santa catalina basin floor

    NASA Astrophysics Data System (ADS)

    Smith, Craig R.

    1985-04-01

    The role of large food falls in the ecology of deep-sea benthos has been the topic of much speculation and little direct study. The submersible Alvin and free vehicles were used to assess experimentally the fate and flux of nekton falls at a depth of 1310 m in the Santa Catalina Basin. Parcels of dead fish (1 to 40 kg) placed on the basin floor rapidly attracted large aggregations of fish and invertebrate scavengers, which consumed the bulk of the carrion within hours to days. The most strongly attracted megafaunal scavenger was the ophiuroid Ophiophthalmus normani, the dominant megabenthic species in the background epifaunal assemblage. O. normani attained densities of 700 m -2 in aggregations containing thousands of individuals, and remained at elevated abundance around baitfalls for weeks. Six other megafaunal species also appeared to feed directly on carrion, including two of the next ten most abundant megabenthic organisms. Several of these species exhibited roosting behavior near baitfalls; this is probably an adaptation for exploiting rich but unpredictable food resources. Scavengers consumed bait parcels so rapidly and then dispersed so broadly that energy from nekton falls apparently reaches infaunal benthos only in very attenuated form, yielding at most minor community enhancement. Necrophagy was not the sole cause of megafaunal attraction to bait parcels; there is evidence that three predacious species were drawn to high concentrations of their ophiuroid prey. Benthic standing-crop and turnover-rate estimates for nekton falls suggest that perhaps 11% of benthic community respiratory requirements are met by nekton carcasses reaching the basin floor; the flux of energy to the deep sea through such fall events thus merits further study. These energy bonanzas occur frequently enough that O. normani, and other common necrophages, are likely to encounter at least one nekton fall per year. Such windfalls thus could influence the life histories of several