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Sample records for air sea gas

  1. In calm seas, precipitation drives air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Schultz, Colin

    2012-05-01

    In a series of experiments run in what resembles a heavily instrumented fish tank, Harrison et al. investigated the interwoven roles of wind and rain on air-sea gas exchange rates. Working with a 42-meterlong, 1-meter-wide, and 1.25-meter-tall experimental pool, the authors were able to control the wind speed, rainfall rate, water circulation speed, and other parameters, which they used to assess the effect of 24 different wind speed-rainfall rate combinations on the gas exchange rate of sulfur hexafuoride, a greenhouse gas. In trials that lasted up to 3 hours, the authors collected water samples from the tank at regular intervals, tracking the concentration of the dissolved gas.

  2. The potential role of sea spray droplets in facilitating air-sea gas transfer

    NASA Astrophysics Data System (ADS)

    Andreas, E. L.; Vlahos, P.; Monahan, E. C.

    2016-05-01

    For over 30 years, air-sea interaction specialists have been evaluating and parameterizing the role of whitecap bubbles in air-sea gas exchange. To our knowledge, no one, however, has studied the mirror image process of whether sea spray droplets can facilitate air-sea gas exchange. We are therefore using theory, data analysis, and numerical modeling to quantify the role of spray on air-sea gas transfer. In this, our first formal work on this subject, we seek the rate-limiting step in spray-mediated gas transfer by evaluating the three time scales that govern the exchange: τ air , which quantifies the rate of transfer between the atmospheric gas reservoir and the surface of the droplet; τ int , which quantifies the exchange rate across the air-droplet interface; and τ aq , which quantifies gas mixing within the aqueous solution droplet.

  3. Air-sea transfer of gas phase controlled compounds

    NASA Astrophysics Data System (ADS)

    Yang, M.; Bell, T. G.; Blomquist, B. W.; Fairall, C. W.; Brooks, I. M.; Nightingale, P. D.

    2016-05-01

    Gases in the atmosphere/ocean have solubility that spans several orders of magnitude. Resistance in the molecular sublayer on the waterside limits the air-sea exchange of sparingly soluble gases such as SF6 and CO2. In contrast, both aerodynamic and molecular diffusive resistances on the airside limit the exchange of highly soluble gases (as well as heat). Here we present direct measurements of air-sea methanol and acetone transfer from two open cruises: the Atlantic Meridional Transect in 2012 and the High Wind Gas Exchange Study in 2013. The transfer of the highly soluble methanol is essentially completely airside controlled, while the less soluble acetone is subject to both airside and waterside resistances. Both compounds were measured concurrently using a proton-transfer-reaction mass spectrometer, with their fluxes quantified by the eddy covariance method. Up to a wind speed of 15 m s-1, observed air-sea transfer velocities of these two gases are largely consistent with the expected near linear wind speed dependence. Measured acetone transfer velocity is ∼30% lower than that of methanol, which is primarily due to the lower solubility of acetone. From this difference we estimate the “zero bubble” waterside transfer velocity, which agrees fairly well with interfacial gas transfer velocities predicted by the COARE model. At wind speeds above 15 m s-1, the transfer velocities of both compounds are lower than expected in the mean. Air-sea transfer of sensible heat (also airside controlled) also appears to be reduced at wind speeds over 20 m s-1. During these conditions, large waves and abundant whitecaps generate large amounts of sea spray, which is predicted to alter heat transfer and could also affect the air-sea exchange of soluble trace gases. We make an order of magnitude estimate for the impacts of sea spray on air-sea methanol transfer.

  4. Dimethylsulfide air/sea gas transfer in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    De Bruyn, W. J.; Bell, T. G.; Marandino, C.; Saltzman, E. S.; Miller, S. D.; Law, C. S.; Smith, M. J.

    2012-12-01

    Air/sea dimethylsulfide (DMS) fluxes were measured by eddy correlation over the Southern Ocean (Feb/March 2012) aboard the R/V Tangaroa during the Surface Ocean Aerosol Production (SOAP) study. Atmospheric and seawater DMS were measured by atmospheric pressure chemical ionization mass spectrometry (API-CIMS). Seawater DMS was measured continuously from the ship underway system using a porous membrane equilibrator. The study included measurements inside and outside a dinoflagellate bloom of large areal extent, with seawater DMS levels ranging up to 20 nM. Horizontal wind speeds of up to 20 m/sec were encountered. Gas transfer coefficients were calculated from eddy covariance DMS flux measurements and the air-sea concentration gradient. This study represents a significant addition to the limited database of direct gas transfer measurements in the Southern Ocean.

  5. Observational Studies of Parameters Influencing Air-sea Gas Exchange

    NASA Astrophysics Data System (ADS)

    Schimpf, U.; Frew, N. M.; Bock, E. J.; Hara, T.; Garbe, C. S.; Jaehne, B.

    A physically-based modeling of the air-sea gas transfer that can be used to predict the gas transfer rates with sufficient accuracy as a function of micrometeorological parameters is still lacking. State of the art are still simple gas transfer rate/wind speed relationships. Previous measurements from Coastal Ocean Experiment in the Atlantic revealed positive correlations between mean square slope, near surface turbulent dis- sipation, and wind stress. It also demonstrated a strong negative correlation between mean square slope and the fluorescence of surface-enriched colored dissolved organic matter. Using heat as a proxy tracer for gases the exchange process at the air/water interface and the micro turbulence at the water surface can be investigated. The anal- ysis of infrared image sequences allow the determination of the net heat flux at the ocean surface, the temperature gradient across the air/sea interface and thus the heat transfer velocity and gas transfer velocity respectively. Laboratory studies were carried out in the new Heidelberg wind-wave facility AELOTRON. Direct measurements of the Schmidt number exponent were done in conjunction with classical mass balance methods to estimate the transfer velocity. The laboratory results allowed to validate the basic assumptions of the so called controlled flux technique by applying differ- ent tracers for the gas exchange in a large Schmidt number regime. Thus a modeling of the Schmidt number exponent is able to fill the gap between laboratory and field measurements field. Both, the results from the laboratory and the field measurements should be able to give a further understanding of the mechanisms controlling the trans- port processes across the aqueous boundary layer and to relate the forcing functions to parameters measured by remote sensing.

  6. ASGAMAGE, the Air-Sea Gas Exchange/MAGE experiment

    NASA Astrophysics Data System (ADS)

    Oost, Wiebe; Jacobs, Cor; Kohsiek, Wim; Goossens, Guus; van der Horn, Jaap; Sprung, Detlev; Rapsomanikis, Spyros; Kenntner, Thomas; Reiner, Thomas; Bowyer, Peter; Larsen, Søren; de Leeuw, Gerrit; Kunz, Gerard; Hall, Alan; Liss, Peter; Malin, Gill; Upstill-Goddard, Rob; Woolf, David; Graham, Angus; Nightingale, Phil; Fairall, Chris; Hare, Jeff; Dissly, Richard; Tans, Pieter; Anderson, Bob; Smith, Stu

    The ASGAMAGE project addressed the problem of the large discrepancy between the chemistry based and micrometeorological methods and aimed to determine any geophysical parameters apart from the wind speed that affect air-sea gas exchange in an effort to reduce the uncertainty in the global carbon balance. Experiments were performed in the spring and fall of 1996 at and near a research platform off the Dutch coast and two surface layer models were developed for the gas exchange process. The results gave a reduction of the difference between the two types of methods from an order of magnitude to a factor of two as well as indications for the causes of the remaining difference.

  7. The role of bubbles during air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Emerson, Steven; Bushinsky, Seth

    2016-06-01

    The potential for using the air-sea exchange rate of oxygen as a tracer for net community biological production in the ocean is greatly enhanced by recent accuracy improvements for in situ measurements of oxygen on unmanned platforms. A limiting factor for determining the exchange process is evaluating the air-sea flux contributed by bubble processes produced by breaking waves, particularly during winter months under high winds. Highly accurate measurements of noble gases (Ne, Ar & Kr) and nitrogen, N2, in seawater are tracers of the importance of bubble process in the surface mixed layer. We use measured distributions of these gases in the ventilated thermocline of the North Pacific and an annual time series of N2 in the surface ocean of the NE Subarctic Pacific to evaluate four different air-water exchange models chosen to represent the range of model interpretation of bubble processes. We find that models must have an explicit bubble mechanism to reproduce concentrations of insoluble atmospheric gases, but there are periods when they all depart from observations. The recent model of Liang et al. (2013) stems from a highly resolved model of bubble plumes and categorizes bubble mechanisms into those that are small enough to collapse and larger ones that exchange gases before they resurface, both of which are necessary to explain the data.

  8. Quantifying air-sea gas exchange using noble gases in a coastal upwelling zone

    NASA Astrophysics Data System (ADS)

    Manning, C. C.; Stanley, R. H. R.; Nicholson, D. P.; Squibb, M. E.

    2016-05-01

    The diffusive and bubble-mediated components of air-sea gas exchange can be quantified separately using time-series measurements of a suite of dissolved inert gases. We have evaluated the performance of four published air-sea gas exchange parameterizations using a five-day time-series of dissolved He, Ne, Ar, Kr, and Xe concentration in Monterey Bay, CA. We constructed a vertical model including surface air-sea gas exchange and vertical diffusion. Diffusivity was measured throughout the cruise from profiles of turbulent microstructure. We corrected the mixed layer gas concentrations for an upwelling event that occurred partway through the cruise. All tested parameterizations gave similar results for Ar, Kr, and Xe; their air-sea fluxes were dominated by diffusive gas exchange during our study. For He and Ne, which are less soluble, and therefore more sensitive to differences in the treatment of bubble-mediated exchange, the parameterizations gave widely different results with respect to the net gas exchange flux and the bubble flux. This study demonstrates the value of using a suite of inert gases, especially the lower solubility ones, to parameterize air-sea gas exchange.

  9. Surfactant control of air-sea gas exchange across contrasting biogeochemical regimes

    NASA Astrophysics Data System (ADS)

    Pereira, Ryan; Schneider-Zapp, Klaus; Upstill-Goddard, Robert

    2014-05-01

    Air-sea gas exchange is important to the global partitioning of CO2.Exchange fluxes are products of an air-sea gas concentration difference, ΔC, and a gas transfer velocity, kw. The latter is controlled by the rate of turbulent diffusion at the air-sea interface but it cannot be directly measured and has a high uncertainty that is now considered one of the greatest challenges to quantifying net global air-sea CO2 exchange ...(Takahashi et al., 2009). One important control on kw is exerted by sea surface surfactants that arise both naturally from biological processes and through anthropogenic activity. They influence gas exchange in two fundamental ways: as a monolayer physical barrier and through modifying sea surface hydrodynamics and hence turbulent energy transfer. These effects have been demonstrated in the laboratory with artificial surfactants ...(Bock et al., 1999; Goldman et al., 1988) and through purposeful surfactant releases in coastal waters .(.).........().(Brockmann et al., 1982) and in the open ocean (Salter et al., 2011). Suppression of kwin these field experiments was ~5-55%. While changes in both total surfactant concentration and the composition of the natural surfactant pool might be expected to impact kw, the required in-situ studies are lacking. New data collected from the coastal North Sea in 2012-2013 shows significant spatio-temporal variability in the surfactant activity of organic matter within the sea surface microlayer that ranges from 0.07-0.94 mg/L T-X-100 (AC voltammetry). The surfactant activities show a strong winter/summer seasonal bias and general decrease in concentration with increasing distance from the coastline possibly associated with changing terrestrial vs. phytoplankton sources. Gas exchange experiments of this seawater using a novel laboratory tank and gas tracers (CH4 and SF6) demonstrate a 12-45% reduction in kw compared to surfactant-free water. Seasonally there is higher gas exchange suppression in the summer

  10. Evaluation of the swell effect on the air-sea gas transfer in the coastal zone

    NASA Astrophysics Data System (ADS)

    Gutiérrez-Loza, Lucía; Ocampo-Torres, Francisco J.

    2016-04-01

    Air-sea gas transfer processes are one of the most important factors regarding global climate and long-term global climate changes. Despite its importance, there is still a huge uncertainty on how to better parametrize these processes in order to include them on the global climate models. This uncertainty exposes the need to increase our knowledge on gas transfer controlling mechanisms. In the coastal regions, breaking waves become a key factor to take into account when estimating gas fluxes, however, there is still a lack of information and the influence of the ocean surface waves on the air-sea interaction and gas flux behavior must be validated. In this study, as part of the "Sea Surface Roughness as Air-Sea Interaction Control" project, we evaluate the effect of the ocean surface waves on the gas exchange in the coastal zone. Direct estimates of the flux of CO2 (FCO2) and water vapor (FH2O) through eddy covariance, were carried out from May 2014 to April 2015 in a coastal station located at the Northwest of Todos Santos Bay, Baja California, México. For the same period, ocean surface waves are recorded using an Acoustic Doppler Current Profiler (Workhorse Sentinel, Teledyne RD Instruments) with a sampling rate of 2 Hz and located at 10 m depth about 350 m away from the tower. We found the study area to be a weak sink of CO2 under moderate wind and wave conditions with a mean flux of -1.32 μmol/m2s. The correlation between the wind speed and FCO2 was found to be weak, suggesting that other physical processes besides wind may be important factors for the gas exchange modulation at coastal waters. The results of the quantile regression analysis computed between FCO2 and (1) wind speed, (2) significant wave height, (3) wave steepness and (4) water temperature, show that the significant wave height is the most correlated parameter with FCO2; Nevertheless, the behavior of their relation varies along the probability distribution of FCO2, with the linear regression

  11. DOGEE-SOLAS: The Role of Surfactants in Air-Sea Gas Exchange

    NASA Astrophysics Data System (ADS)

    Salter, M. E.; Upstill-Goddard, R. C.; Nightingale, P.

    2008-12-01

    One of the major aims of DOGEE-SOLAS was to improve our understanding of the role of surfactants in air- sea gas exchange. With this in mind we carried out a number of artificial surfactant releases on a research cruise in the North Atlantic (D320), during June-July of 2007. We used oleyl alcohol, a surrogate for natural surfactants which is relatively cheap and easy to obtain (it is used in the manufacture of cosmetics). The main release overlaid a dual tracer "patch" of SF6 and 3He; our aim was to directly compare values of the gas transfer velocity, kw, estimated within the surfactant covered patch with those estimated quasi- simultaneously in a second, surfactant-free patch about 20km away. A second release in conjunction with colleagues from the University of Hawaii had the aim of measuring DMS fluxes by eddy correlation both inside and outside a surfactant slick, and a third was undertaken in the path of one of two 14m ASIS (Air-Sea Interaction Spar) buoys operated by the University of Miami for direct comparison of surfactant effects on the fluxes of CO2, H2O, heat and momentum (eddy correlation) etc. We present here some preliminary findings from the work.

  12. Sensitivity of Global Sea-Air CO2 Flux to Gas Transfer Algorithms, Climatological Wind Speeds, and Variability of Sea Surface Temperature and Salinity

    NASA Technical Reports Server (NTRS)

    McClain, Charles R.; Signorini, Sergio

    2002-01-01

    Sensitivity analyses of sea-air CO2 flux to gas transfer algorithms, climatological wind speeds, sea surface temperatures (SST) and salinity (SSS) were conducted for the global oceans and selected regional domains. Large uncertainties in the global sea-air flux estimates are identified due to different gas transfer algorithms, global climatological wind speeds, and seasonal SST and SSS data. The global sea-air flux ranges from -0.57 to -2.27 Gt/yr, depending on the combination of gas transfer algorithms and global climatological wind speeds used. Different combinations of SST and SSS global fields resulted in changes as large as 35% on the oceans global sea-air flux. An error as small as plus or minus 0.2 in SSS translates into a plus or minus 43% deviation on the mean global CO2 flux. This result emphasizes the need for highly accurate satellite SSS observations for the development of remote sensing sea-air flux algorithms.

  13. Decline of hexachlorocyclohexane in the Arctic atmosphere and reversal of air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Bidleman, T. F.; Jantunen, L. M.; Falconer, R. L.; Barrie, L. A.; Fellin, P.

    1995-02-01

    Hexachlorocyclohexanes (HCHs) are the most abundant organochlorine pesticides in the arctic atmosphere and ocean surface water. A compilation of measurements made between 1979-93 from stations in the Canadian and Norwegian Arctic and from cruises in the Bering and Chukchi seas indicates that atmospheric concentrations of α-HCH have declined significantly (p < 0.01), with a time for 50% decrease of about 4 y in summer-fall and 6 y in winter-spring. The 1992-93 levels of about 100 pg m-3 are 2-4 fold lower than values in the mid-1980s. The trend in γ-HCH is less pronounced, but a decrease is also suggested from measurements in the Canadian Arctic and the Bering-Chukchi seas. HCHs in ocean surface water have remained relatively constant since the early 1980s. The decline in atmospheric α-HCH has reversed the net direction of air-sea gas exchange to the point where some northern waters are now sources of the pesticide to the atmosphere instead of sinks.

  14. Using eddy covariance to estimate air-sea gas transfer velocity for oxygen

    NASA Astrophysics Data System (ADS)

    Andersson, Andreas; Rutgersson, Anna; Sahlée, Erik

    2016-07-01

    Air-sea gas transfer velocity for O2 is calculated using directly measured fluxes with the eddy covariance technique. It is a direct method and is frequently used to determine fluxes of heat, humidity, and CO2, but has not previously been used to estimate transfer velocities for O2, using atmospheric eddy covariance data. The measured O2 fluxes are upward directed, in agreement with the measured air-sea gradient of the O2 concentration, and opposite to the direction of the simultaneously measured CO2 fluxes. The transfer velocities estimated from measurements are compared with prominent wind speed parameterizations of the transfer velocity for CO2 and O2, previously established from various measurement techniques. Our result indicates stronger wind speed dependence for the transfer velocity of O2 compared to CO2 starting at intermediate wind speeds. This stronger wind speed dependence appears to coincide with the onset of whitecap formation in the flux footprint and the strong curvature of a cubic wind-dependent function for the transfer velocity provides the best fit to the data. Additional data using the measured O2 flux and an indirect method (based on the Photosynthetic Quotient) to estimate oxygen concentration in water, support the stronger wind dependence for the transfer velocity of O2 compared to CO2.

  15. Tuning a physically-based model of the air-sea gas transfer velocity

    NASA Astrophysics Data System (ADS)

    Jeffery, C. D.; Robinson, I. S.; Woolf, D. K.

    Air-sea gas transfer velocities are estimated for one year using a 1-D upper-ocean model (GOTM) and a modified version of the NOAA-COARE transfer velocity parameterization. Tuning parameters are evaluated with the aim of bringing the physically based NOAA-COARE parameterization in line with current estimates, based on simple wind-speed dependent models derived from bomb-radiocarbon inventories and deliberate tracer release experiments. We suggest that A = 1.3 and B = 1.0, for the sub-layer scaling parameter and the bubble mediated exchange, respectively, are consistent with the global average CO 2 transfer velocity k. Using these parameters and a simple 2nd order polynomial approximation, with respect to wind speed, we estimate a global annual average k for CO 2 of 16.4 ± 5.6 cm h -1 when using global mean winds of 6.89 m s -1 from the NCEP/NCAR Reanalysis 1 1954-2000. The tuned model can be used to predict the transfer velocity of any gas, with appropriate treatment of the dependence on molecular properties including the strong solubility dependence of bubble-mediated transfer. For example, an initial estimate of the global average transfer velocity of DMS (a relatively soluble gas) is only 11.9 cm h -1 whilst for less soluble methane the estimate is 18.0 cm h -1.

  16. Characterization of Sea-Air Methane Fluxes Around a Seafloor Gas Seep in the Central Laptev Sea

    NASA Astrophysics Data System (ADS)

    Geibel, M. C.; Thornton, B. F.; Prytherch, J.; Brooks, I. M.; Salisbury, D. J.; Tjernstrom, M. K. H.; Semiletov, I. P.; Mörth, C. M.; Humborg, C.; Crill, P. M.

    2015-12-01

    The fate of CH4 released from thawing subsea permafrost on the East Siberian Arctic Shelf (ESAS) is unclear. In recent years, interest has focused on the possibility of large emissions of CH4 directly to the atmosphere from this remote area. It is uncertain how high those emissions are and whether they are primarily of biogenic or thermogenic nature, or some combination of sources. The SWERUS-C3 expedition onboard the Swedish icebreaker Oden during July-August 2014 sought to document possible CH4 release from subsea permafrost, and to understand mechanisms and magnitudes of such CH4 being released to the atmosphere. During the first leg of the expedition continuous high-resolution measurements were made to determine the in situ concentrations of CH4 in both the atmosphere and surface water. During SWERUS-C3, several underwater gas flares were found within the ESAS region showing elevated CH4 concentrations collocated in the surface waters. Here we focus on one seep area, a so-called "mega-flare" site, in the central Laptev Sea. Over individual gas flares of this site the surface water concentration of CH4 reached as high as 200ppm. The atmospheric concentrations of CH4 briefly (< 1 s) reached a maximum of ~3.2 ppm. More typical atmospheric values around the seeps were between 1.9-2.0 ppm (background values were approximately 1.88 ppm). However, such peak concentrations in both air and water were highly localized, returning to background levels within a few hundred meters of the source seeps. Together with continuous high-precision eddy-covariance measurements that were made during the SWERUS-C3 expedition, the combined dataset allows an intensive analysis these highly inhomogeneous gas flares. This gives the opportunity to calculate accurate high-resolution CH4 fluxes and thus give a better insight into the current rates of subsea CH4 outgassing reaching the atmosphere.

  17. The relationship between ocean surface turbulence and air-sea gas transfer velocity: An in-situ evaluation

    NASA Astrophysics Data System (ADS)

    Esters, L.; Landwehr, S.; Sutherland, G.; Bell, T. G.; Saltzman, E. S.; Christensen, K. H.; Miller, S. D.; Ward, B.

    2016-05-01

    Although the air-sea gas transfer velocity k is usually parameterized with wind speed, the so-called small-eddy model suggests a relationship between k and ocean surface dissipation of turbulent kinetic energy ɛ. Laboratory and field measurements of k and ɛ have shown that this model holds in various ecosystems. Here, field observations are presented supporting the theoretical model in the open ocean. These observations are based on measurements from the Air-Sea Interaction Profiler and eddy covariance CO2 and DMS air-sea flux data collected during the Knorr11 cruise. We show that the model results can be improved when applying a variable Schmidt number exponent compared to a commonly used constant value of 1/2. Scaling ɛ to the viscous sublayer allows us to investigate the model at different depths and to expand its applicability for more extensive data sets.

  18. Air-sea gas transfer for two gases of different solubility (CO2 and O2)

    NASA Astrophysics Data System (ADS)

    Rutgersson, A.; Andersson, A.; Sahlée, E.

    2016-05-01

    At the land-based marine measuring site Östergarnsholm in the Baltic Sea, the eddy covariance technique was used to measure air-sea fluxes of carbon dioxide and oxygen. High- frequency measurements of oxygen were taken with a Microx TX3 optode using the luminescence lifetime technique. The system gives reasonable oxygen fluxes after the limited frequency response of the sensor was corrected for. For fluxes of carbon dioxide the LICOR-7500 instrument was used. Using flux data to estimate transfer velocities indicates higher transfer velocity for oxygen compared to carbon dioxide for winds above 5 m/s. There are too few data for any extensive conclusions, but a least-square fit of the data gives a cubic wind speed dependence of oxygen corresponding to k 660 = 0.074U 3 10. The more effective transfer for oxygen compared to carbon dioxide above 5 m/s is most likely due to enhanced efficiency of oxygen exchange across the surface. Oxygen has lower solubility compared with carbon dioxide and might be more influenced by near surface processes such as microscale wave breaking or sea spray.

  19. High wind speed measurements of dimethylsulfide air/sea gas transfer by eddy correlation in the North Atlantic

    NASA Astrophysics Data System (ADS)

    Bell, T. G.; De Bruyn, W. J.; Miller, S. D.; Saltzman, E. S.; Slawksy, L.; Stacy, B.; Callaghan, A. H.

    2012-12-01

    Air/sea dimethylsulphide (DMS) fluxes and gas transfer coefficients (kDMS) were measured by eddy correlation over the western North Atlantic Ocean during June/July 2011 aboard the R/V Knorr. Atmospheric and seawater DMS were measured using atmospheric pressure chemical ionization mass spectrometry (API-CIMS). Seawater DMS was measured continuously from the ship's underway system using a porous membrane equilibrator and API-CIMS. The cruise included regions of high biological productivity, wind speeds from 0-18 m/sec and whitecap areas of 0-5%. Four stations were occupied during the cruise for periods of 24-36 hours. In general, the stations exhibited a linear relationship between kDMS and wind speed, although there were significant variations in the slope of this relationship. One of the stations showed kDMS increasing with wind speed to 10 m/sec and then levelling off at higher wind speeds. The data from this cruise suggest that gas transfer can vary substantially due to parameters other than wind speed, most likely sea state and surfactants.

  20. Eddy covariance flux of sulfur dioxide to the sea surface: Air-side resistance to deposition of a highly soluble gas

    NASA Astrophysics Data System (ADS)

    Porter, J.; De Bruyn, W. J.; Miller, S. D.; Saltzman, E. S.

    2014-12-01

    Deposition to the sea surface represents a major atmospheric removal mechanism for sulfur dioxide and many other highly soluble products of tropospheric photochemistry. Such gases include nitric acid, ammonia, organic acids, sulfur dioxide, and highly soluble organic compounds such as methanol and acetone. The deposition of highly soluble gases is controlled by turbulent and diffusive transport on the air side of the air/sea interface. In this study, air/sea fluxes of the soluble gas sulfur dioxide (SO2 ), sensible and latent heat, and momentum were measured using eddy covariance. This was a pilot study carried out in April 2014 on Scripps pier in La Jolla, California, that was designed to assess the potential for measuring SO2 fluxes over the ocean. SO2 was detected using chemical ion mass spectrometry in negative ion mode with a sensitivity of roughly 100 Hz/ppt. The ionization scheme involved addition of ozone to a dried air stream and subsequent conversion of SO2 to the SO5 - ion. The results demonstrate the feasibility of seagoing SO2 flux measurements. Such measurements can be used to constrain the depositional velocities of soluble gases and test models for air-side resistance to air/sea gas transfer.

  1. Air-sea exchange of dimethylsulfide in the Southern Ocean: Measurements from SO GasEx compared to temperate and tropical regions

    NASA Astrophysics Data System (ADS)

    Yang, M.; Blomquist, B. W.; Fairall, C. W.; Archer, S. D.; Huebert, B. J.

    2011-04-01

    In the Southern Ocean Gas Exchange Experiment (SO GasEx), we measured an atmospheric dimethylsulfide (DMS) concentration of 118 ± 54 pptv (1σ), a DMS sea-to-air flux of 2.9 ± 2.1 μmol m-2 d-1 by eddy covariance, and a seawater DMS concentration of 1.6 ± 0.7 nM. Dividing flux by the concurrent air-sea concentration difference yields the transfer velocity of DMS (kDMS). The kDMS in the Southern Ocean was significantly lower than previous measurements in the equatorial east Pacific, Sargasso Sea, northeast Atlantic, and southeast Pacific. Normalizing kDMS for the temperature dependence in waterside diffusivity and solubility results in better agreement among various field studies and suggests that the low kDMS in the Southern Ocean is primarily due to colder temperatures. The higher solubility of DMS at a lower temperature results in greater airside control and less transfer of the gas by bubbles formed from breaking waves. The final normalized DMS transfer velocity is similar to k of less soluble gases such as carbon dioxide in low-to-moderate winds; in high winds, DMS transfer velocity is significantly lower because of the reduced bubble-mediated transfer.

  2. Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean

    NASA Astrophysics Data System (ADS)

    Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.

    2013-09-01

    Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate processes that control the distribution of δ13C of dissolved inorganic carbon (DIC) in the contemporary and preindustrial ocean. Biological fractionation and the sinking of isotopically light δ13C organic matter from the surface into the interior ocean leads to low δ13CDIC values at depths and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange has two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature-dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, since air-sea gas exchange is slow in the modern ocean, the biological effect dominates spatial δ13CDIC gradients both in the interior and at the surface, in contrast to conclusions from some previous studies. Calcium carbonate cycling, pH dependency of fractionation during air-sea gas exchange, and kinetic fractionation have minor effects on δ13CDIC. Accumulation of isotopically light carbon from anthropogenic fossil fuel burning has decreased the spatial variability of surface and deep δ13CDIC since the industrial revolution in our model simulations. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed and remineralized contributions as well as the effects of biology and air-sea gas exchange. The model reproduces major features of the observed large-scale distribution of δ13CDIC as well as the individual contributions and effects. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by

  3. Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean

    NASA Astrophysics Data System (ADS)

    Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.

    2013-05-01

    Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate the processes that control the distribution of δ13C in the contemporary and preindustrial ocean. Biological fractionation dominates the distribution of δ13CDIC of dissolved inorganic carbon (DIC) due to the sinking of isotopically light δ13C organic matter from the surface into the interior ocean. This process leads to low δ13CDIC values at dephs and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange provides an important secondary influence due to two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, air-sea gas exchange is slow, so biological effect dominate spatial δ13CDIC gradients both in the interior and at the surface, in constrast to conclusions from some previous studies. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed (δ13Cpre) and remineralized (δ13Crem) contributions as well as the effects of biology (Δδ13Cbio) and air-sea gas exchange (δ13C*). The model reproduces major features of the observed large-scale distribution of δ13CDIC, δ13Cpre, δ13Crem, δ13C*, and Δδ13Cbio. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by details of the ecosystem model formulation. For example, inclusion of a simple parameterization of iron limitation of phytoplankton growth rates and temperature-dependent zooplankton grazing rates improves the agreement with δ13CDIC

  4. Formation of gas-phase carbonyls from heterogeneous oxidation of polyunsaturated fatty acids at the air-water interface and of the sea surface microlayer

    NASA Astrophysics Data System (ADS)

    Zhou, S.; Gonzalez, L.; Leithead, A.; Finewax, Z.; Thalman, R.; Vlasenko, A.; Vagle, S.; Miller, L. A.; Li, S.-M.; Bureekul, S.; Furutani, H.; Uematsu, M.; Volkamer, R.; Abbatt, J.

    2014-02-01

    Motivated by the potential for reactive heterogeneous chemistry occurring at the ocean surface, gas-phase products were observed when a reactive sea surface microlayer (SML) component, i.e. the polyunsaturated fatty acids (PUFA) linoleic acid (LA), was exposed to gas-phase ozone at the air-seawater interface. Similar oxidation experiments were conducted with SML samples collected from two different oceanic locations, in the eastern equatorial Pacific Ocean and from the west coast of Canada. Online proton-transfer-reaction mass spectrometry (PTR-MS) University of Colorado light-emitting diode cavity-enhanced differential optical absorption spectroscopy (LED-CE-DOAS) were used to detect oxygenated gas-phase products from the ozonolysis reactions. The LA studies indicate that oxidation of a PUFA monolayer on seawater gives rise to prompt and efficient formation of gas-phase aldehydes. The products are formed via the decomposition of primary ozonides which form upon the initial reaction of ozone with the carbon-carbon double bonds in the PUFA molecules. In addition, two highly reactive dicarbonyls, malondialdehyde (MDA) and glyoxal, were also generated, likely as secondary products. Specific yields relative to reactant loss were 78%, 29%, 4% and < 1% for n-hexanal, 3-nonenal, MDA and glyoxal, respectively, where the yields for MDA and glyoxal are likely lower limits. Heterogeneous oxidation of SML samples confirm for the first time that similar carbonyl products are formed via ozonolysis of environmental samples.

  5. Formation of gas-phase carbonyls from heterogeneous oxidation of polyunsaturated fatty acids at the air-water interface and of the sea surface microlayer

    NASA Astrophysics Data System (ADS)

    Zhou, S.; Gonzalez, L.; Leithead, A.; Finewax, Z.; Thalman, R.; Vlasenko, A.; Vagle, S.; Miller, L.; Li, S.-M.; Bureekul, S.; Furutani, H.; Uematsu, M.; Volkamer, R.; Abbatt, J.

    2013-07-01

    Motivated by the potential for reactive heterogeneous chemistry occurring at the ocean surface, gas-phase products were observed when a reactive sea surface microlayer (SML) component, i.e. the polyunsaturated fatty acid (PUFA) linoleic acid (LA), was exposed to gas-phase ozone at the air-seawater interface. Similar oxidation experiments were conducted with SML samples collected from two different oceanic locations, in the eastern equatorial Pacific Ocean and from the west coast of Canada. Online proton-transfer-reaction mass spectrometry (PTR-MS) and light-emitting diode cavity enhanced differential optical absorption spectroscopy (LED-CE-DOAS) were used to detect oxygenated gas-phase products from the ozonolysis reactions. The LA studies indicate that oxidation of a PUFA monolayer on seawater gives rise to prompt and efficient formation of gas phase aldehydes. The products are formed via the decomposition of primary ozonides which form upon the initial reaction of ozone with the carbon-carbon double bonds in the PUFA molecules. In addition, two highly reactive di-carbonyls, malondialdehyde (MDA) and glyoxal, were also generated, likely as secondary products. Specific yields relative to reactant loss were 78%, 29%, 4% and <1% for n-hexanal, 3-nonenal, MDA and glyoxal, respectively, where the yields for MDA and glyoxal are likely lower limits. Heterogeneous oxidation of SML samples confirm for the first time that similar carbonyl products are formed via ozonolysis of environmental samples. The potential impact of such chemistry on the atmosphere of the marine boundary layer is discussed.

  6. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts.

    PubMed

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-07-20

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change.

  7. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    NASA Astrophysics Data System (ADS)

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-07-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change.

  8. In situ measurements of the air-sea gas transfer rate using heat as a proxy tracer

    SciTech Connect

    Haussecker, H.; Jaehne, B. |

    1994-12-31

    Conventional techniques to measure the transfer velocity k = j/{Delta}c of gases across the ocean interface are based on mass balance of the gas tracer in the water body. In order to determine j the temporal change {dot c}{sub w} of the tracer concentration in a volume of water V{sub w} has to be measured. The corresponding time constant {tau}{sub w} is in the order of days to weeks in the ocean. This long integration time prevents both an empirical parameterization of the gas transfer rate with friction velocity and other parameters such as the wave field and an insight into the mechanisms. Eddy correlation techniques are in principal suitable for flux measurements and parameterization of the gas transfer rate. So far, however, it could not be verified that they yield results that are consistent with geochemical methods and laboratory investigations. Here, an alternative approach is presented. The novel technique controls the tracer flux at the interface and uses heat as a proxy tracer.

  9. Effect of gas-transfer velocity parameterization choice on air-sea CO2 fluxes in the North Atlantic Ocean and the European Arctic

    NASA Astrophysics Data System (ADS)

    Wrobel, Iwona; Piskozub, Jacek

    2016-09-01

    The oceanic sink of carbon dioxide (CO2) is an important part of the global carbon budget. Understanding uncertainties in the calculation of this net flux into the ocean is crucial for climate research. One of the sources of the uncertainty within this calculation is the parameterization chosen for the CO2 gas-transfer velocity. We used a recently developed software toolbox, called the FluxEngine (Shutler et al., 2016), to estimate the monthly air-sea CO2 fluxes for the extratropical North Atlantic Ocean, including the European Arctic, and for the global ocean using several published quadratic and cubic wind speed parameterizations of the gas-transfer velocity. The aim of the study is to constrain the uncertainty caused by the choice of parameterization in the North Atlantic Ocean. This region is a large oceanic sink of CO2, and it is also a region characterized by strong winds, especially in winter but with good in situ data coverage. We show that the uncertainty in the parameterization is smaller in the North Atlantic Ocean and the Arctic than in the global ocean. It is as little as 5 % in the North Atlantic and 4 % in the European Arctic, in comparison to 9 % for the global ocean when restricted to parameterizations with quadratic wind dependence. This uncertainty becomes 46, 44, and 65 %, respectively, when all parameterizations are considered. We suggest that this smaller uncertainty (5 and 4 %) is caused by a combination of higher than global average wind speeds in the North Atlantic (> 7 ms-1) and lack of any seasonal changes in the direction of the flux direction within most of the region. We also compare the impact of using two different in situ pCO2 data sets (Takahashi et al. (2009) and Surface Ocean CO2 Atlas (SOCAT) v1.5 and v2.0, for the flux calculation. The annual fluxes using the two data sets differ by 8 % in the North Atlantic and 19 % in the European Arctic. The seasonal fluxes in the Arctic computed from the two data sets disagree with each

  10. Air-sea exchange fluxes of synthetic polycyclic musks in the North Sea and the Arctic.

    PubMed

    Xie, Zhiyong; Ebinghaus, Ralf; Temme, Christian; Heemken, Olaf; Ruck, Wolfgang

    2007-08-15

    Synthetic polycyclic musk fragrances Galaxolide (HHCB) and Tonalide (AHTN) were measured simultaneously in air and seawater in the Arctic and the North Sea and in the rural air of northern Germany. Median concentrations of gas-phase HHCB and AHTN were 4 and 18 pg m(-3) in the Arctic, 28 and 18 pg m(-3) in the North Sea, and 71 and 21 pg m(-3) in northern Germany, respectively. Various ratios of HHCB/AHTN implied that HHCB is quickly removed by atmospheric degradation, while AHTN is relatively persistent in the atmosphere. Dissolved concentrations ranged from 12 to 2030 pg L(-1) for HHCB and from below the method detection limit (3 pg L(-1)) to 965 pg L(-1) for AHTN with median values of 59 and 23 pg L(-1), respectively. The medians of volatilization fluxes for HHCB and AHTN were 27.2 and 14.2 ng m(-2) day(-1) and the depositional fluxes were 5.9 and 3.3 ng m(-2) day(-1), respectively, indicating water-to-air volatilization is a significant process to eliminate HHCB and AHTN from the North Sea. In the Arctic, deposition fluxes dominated the air-sea gas exchange of HHCB and AHTN, suggesting atmospheric input controls the levels of HHCB and AHTN in the polar region.

  11. Imaging air volume fraction in sea ice using non-destructive X-ray tomography

    NASA Astrophysics Data System (ADS)

    Crabeck, Odile; Galley, Ryan; Delille, Bruno; Else, Brent; Geilfus, Nicolas-Xavier; Lemes, Marcos; Des Roches, Mathieu; Francus, Pierre; Tison, Jean-Louis; Rysgaard, Søren

    2016-05-01

    Although the presence of a gas phase in sea ice creates the potential for gas exchange with the atmosphere, the distribution of gas bubbles and transport of gases within the sea ice are still poorly understood. Currently no straightforward technique exists to measure the vertical distribution of air volume fraction in sea ice. Here, we present a new fast and non-destructive X-ray computed tomography technique to quantify the air volume fraction and produce separate images of air volume inclusions in sea ice. The technique was performed on relatively thin (4-22 cm) sea ice collected from an experimental ice tank. While most of the internal layers showed air volume fractions < 2 %, the ice-air interface (top 2 cm) systematically showed values up to 5 %. We suggest that the air volume fraction is a function of both the bulk ice gas saturation factor and the brine volume fraction. We differentiate micro bubbles (Ø < 1 mm), large bubbles (1 mm < Ø < 5 mm) and macro bubbles (Ø > 5 mm). While micro bubbles were the most abundant type of gas bubbles, most of the air porosity observed resulted from the presence of large and macro bubbles. The ice texture (granular and columnar) as well as the permeability state of ice are important factors controlling the air volume fraction. The technique developed is suited for studies related to gas transport and bubble migration.

  12. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    USGS Publications Warehouse

    Hinckley, D.A.; Bidleman, T.F.; Rice, C.P.

    1991-01-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  13. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi seas

    NASA Astrophysics Data System (ADS)

    Hinckley, Daniel A.; Bidleman, Terry F.; Rice, Clifford P.

    1991-04-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for Organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average α-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average γ-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (α-HCH, average 79% saturation; γ-HCH, average 28% saturation). The flux for α-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of γ-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  14. Sea-ice melt CO2-carbonate chemistry in the western Arctic Ocean: meltwater contributions to air-sea CO2 gas exchange, mixed-layer properties and rates of net community production under sea ice

    NASA Astrophysics Data System (ADS)

    Bates, N. R.; Garley, R.; Frey, K. E.; Shake, K. L.; Mathis, J. T.

    2014-12-01

    The carbon dioxide (CO2)-carbonate chemistry of sea-ice melt and co-located, contemporaneous seawater has rarely been studied in sea-ice-covered oceans. Here, we describe the CO2-carbonate chemistry of sea-ice melt (both above sea-ice as "melt ponds" and below sea-ice as "interface waters") and mixed-layer properties in the western Arctic Ocean in the early summer of 2010 and 2011. At 19 stations, the salinity (∼0.5 to <6.5), dissolved inorganic carbon (DIC; ∼20 to <550 μmol kg-1) and total alkalinity (TA; ∼30 to <500 μmol kg-1) of above-ice melt pond water was low compared to the co-located underlying mixed layer. The partial pressure of CO2 (pCO2) in these melt ponds was highly variable (∼<10 to >1500 μatm) with the majority of melt ponds acting as potentially strong sources of CO2 to the atmosphere. The pH of melt pond waters was also highly variable ranging from mildly acidic (6.1 to 7) to slightly more alkaline than underlying seawater (>8.2 to 10.8). All of the observed melt ponds had very low (<0.1) saturation states (Ω) for calcium carbonate (CaCO3) minerals such as aragonite (Ωaragonite). Our data suggest that sea-ice generated alkaline or acidic type melt pond water. This melt water chemistry dictates whether the ponds are sources of CO2 to the atmosphere or CO2 sinks. Below-ice interface water CO2-carbonate chemistry data also indicated substantial generation of alkalinity, presumably owing to dissolution of CaCO3 in sea-ice. The interface waters generally had lower pCO2 and higher pH/Ωaragonite than the co-located mixed layer beneath. Sea-ice melt thus contributed to the suppression of mixed-layer pCO2, thereby enhancing the surface ocean's capacity to uptake CO2 from the atmosphere. Our observations contribute to growing evidence that sea-ice CO2-carbonate chemistry is highly variable and its contribution to the complex factors that influence the balance of CO2 sinks and sources (and thereby ocean acidification) is difficult to

  15. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts.

    PubMed

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-01-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change. PMID:27435531

  16. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    PubMed Central

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-01-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change. PMID:27435531

  17. A simulation study to identify the sea water depth for the presence of air waves in sea bed logging

    NASA Astrophysics Data System (ADS)

    Abdulkarim, Muhammad; Shafie, Afza; Yahya, Noorhana Binti; Razali, Radzuan; Ahmad, Wan Fatimah Wan

    2012-09-01

    Sea Bed Logging (SBL) is an offshore geophysical technique that can give information about resistivity variation beneath the seafloor. This information is crucial in offshore oil and gas exploration. However, data collected through this technique in shallow water at low frequencies is associated with a problem termed "air wave effect". The air wave effect is a phenomena resulting from Electro-Magnetic (EM) waves produced by the antenna (source) which interact with air-sea interface to generate air waves that diffuse from sea surface to the receivers. These air wave signals dominate the receivers at far offsets to the source and consequently, the refracted signal due the target is hardly distinguishable. The refracted signals from the target being masked by the airwaves can make it difficult to identify the hydrocarbon reservoir. The aim of this study is to investigate the sea water depth for the presence of air waves. Synthetic data are generated by simulating SBL environment without Hydro-Carbon (HC) target and varying the sea water depth from 1000m to 100m with the interval of 100m. The simulated distances for the source-receiver separation (offset) are divided into five ranges. The magnitude versus offset plot together with the Friedman and Wilcoxon statistical test are used to analyze the data. Results show that the air waves are present at 400m of sea water depth and below.

  18. Joint Air Sea Interaction (JASIN) experiment, Northwest coast of Scotland

    NASA Technical Reports Server (NTRS)

    Businger, J. A.

    1981-01-01

    The joint air sea interaction (JASIN) experiment took place off the Northwest coast of Scotland. Sea surface and boundary layer parameters were measured. The JASIN data was used as ground truth for various sensors on the SEASAT satellite.

  19. In situ evaluation of air-sea CO2 gas transfer velocity in an inner estuary using eddy covariance - with a special focus on the importance of using reliable CO2-fluxes

    NASA Astrophysics Data System (ADS)

    Jørgensen, E. T.; Sørensen, L. L.; Jensen, B.; Sejr, M. K.

    2012-04-01

    The air-sea exchange of CO2 or CO2 flux is driven by the difference in the partial pressure of CO2 in the water and the atmosphere (ΔpCO2), the solubility of CO2 (K0) and the gas transfer velocity (k) (Wanninkhof et al., 2009;Weiss, 1974) . ΔpCO2 and K0 are determined with relatively high precision and it is estimated that the biggest uncertainty when modelling the air-sea flux is the parameterization of k. As an example; the estimated global air-sea flux increases by 70 % when using the parameterization by Wanninkhof and McGillis (1999) instead of Wanninkhof (1992) (Rutgersson et al., 2008). In coastal areas the uncertainty is even higher and only few studies have focused on determining transfer velocity for the coastal waters and even fewer on estuaries (Borges et al., 2004;Rutgersson et al., 2008). The transfer velocity (k600) of CO2 in the inner estuary of Roskilde Fjord, Denmark was investigated using eddy covariance CO2 fluxes (ECM) and directly measured ΔpCO2 during May and June 2010. The data was strictly sorted to heighten the certainty of the results and the outcome was; DS1; using only ECM, and DS2; including the inertial dissipation method (IDM). The inner part of Roskilde Fjord showed to be a very biological active CO2 sink and preliminary results showed that the average k600 was more than 10 times higher than transfer velocities from similar studies of other coastal areas. The much higher transfer velocities were estimated to be caused by the greater fetch and shallower water in Roskilde Fjord, which indicated that turbulence in both air and water influence k600. The wind speed parameterization of k600 using DS1 showed some scatter but when including IDM the r2 of DS2 reached 0.93 with an exponential parameterization, where U10 was based on the Businger-Dyer relationships using friction velocity and atmospheric stability. This indicates that some of the uncertainties coupled with CO2 fluxes calculated by the ECM are removed when including the IDM.

  20. Unravelling air-sea interactions driven by photochemistry in the sea-surface microlayer

    NASA Astrophysics Data System (ADS)

    George, Christian; Alpert, Peter; Tinel, Liselotte; Rossignol, Stéphanie; Perrier, Sébastien; Bernard, Francois; Ciuraru, Raluca; Hayeck, Nathalie

    2016-04-01

    Interfaces are ubiquitous in the environment, and in addition many atmospheric key processes, such as gas deposition, aerosol and cloud formation are, at one stage or the other, strongly impacted by physical- and chemical processes occurring at interfaces. Unfortunately, these processes have only been suggested and discussed but never fully addressed because they were beyond reach. We suggest now that photochemistry or photosensitized reactions exist at interfaces, and we will present and discuss their possible atmospheric implications. Obviously, one of the largest interface is the sea-surface microlayer (SML), which is a region lying at the uppermost tens to hundreds of micrometres of the water surface, with physical, chemical and biological properties that differ from those of the underlying sub-surface water. Organic film formation at the sea surface is made possible in the presence of an excess of surface-active material. Hydrophobic surfactant films are typically believed to play the role of a physical barrier to air-sea exchanges, especially at low wind speed. We will show that dissolved organic matter (DOM) can trigger photochemistry at the air-sea interface, releasing unsaturated, functionalized volatile organic compounds (VOCs), including isoprene,... acting as precursors for the formation of organic aerosols, that were thought, up to now, to be solely of biological origin! In addition, we suggest that when arranged at an air/water interface, hydrophobic surfactant can have weak chemical interactions among them, which can trigger the absorption of sunlight and can consequently induce photochemistry at such interfaces. A major question arises from such observations, namely: can the existence of such weak intra- or intermolecular interactions and the subsequent photochemistry be generalized to many other atmospheric objects such as aerosols? This topic will be presented and discussed.

  1. Advances in Air-Sea Flux Measurement by Eddy Correlation

    NASA Astrophysics Data System (ADS)

    Blomquist, Byron W.; Huebert, Barry J.; Fairall, Christopher W.; Bariteau, Ludovic; Edson, James B.; Hare, Jeffrey E.; McGillis, Wade R.

    2014-09-01

    Eddy-correlation measurements of the oceanic flux are useful for the development and validation of air-sea gas exchange models and for analysis of the marine carbon cycle. Results from more than a decade of published work and from two recent field programs illustrate the principal interferences from water vapour and motion, demonstrating experimental approaches for improving measurement precision and accuracy. Water vapour cross-sensitivity is the greatest source of error for flux measurements using infrared gas analyzers, often leading to a ten-fold bias in the measured flux. Much of this error is not related to optical contamination, as previously supposed. While various correction schemes have been demonstrated, the use of an air dryer and closed-path analyzer is the most effective way to eliminate this interference. This approach also obviates density corrections described by Webb et al. (Q J R Meteorol 106:85-100, 1980). Signal lag and frequency response are a concern with closed-path systems, but periodic gas pulses at the inlet tip provide for precise determination of lag time and frequency attenuation. Flux attenuation corrections are shown to be 5 % for a cavity ring-down analyzer (CRDS) and dryer with a 60-m inlet line. The estimated flux detection limit for the CRDS analyzer and dryer is a factor of ten better than for IRGAs sampling moist air. While ship-motion interference is apparent with all analyzers tested in this study, decorrelation or regression methods are effective in removing most of this bias from IRGA measurements and may also be applicable to the CRDS.

  2. Occurrence and air-sea exchange of phthalates in the Arctic.

    PubMed

    Xie, Zhiyong; Ebinghaus, Ralf; Temme, Christian; Lohmann, Rainer; Caba, Armando; Ruck, Wolfgang

    2007-07-01

    Air and seawater samples were taken simultaneously to investigate the distribution and air-sea gas exchange of phthalates in the Arctic onboard the German Research Ship FS Polarstern. Samples were collected on expeditions ARK XX1&2 from the North Sea to the high Arctic (60 degrees N-85 degrees N) in the summer of 2004. The concentration of sigma6 phthalates (dimethyl phthalate (DMP), diethyl phthalate (DEP), di-i-butyl phthalate (DiBP), di-n-butyl phthalate (DnBP), butylbenzyl phthalate (BBP), and diethylhexyl phthalate (DEHP)) ranged from 30 to 5030 pg L(-1) in the aqueous dissolved phase and from 1110 to 3090 pg m(-3) in the atmospheric gas phase. A decreasing latitudinal trend was present in the seawater and to a lesser degree in the atmosphere from the Norwegian coast to the high Arctic. Overall, deposition dominated the air-sea gas exchange for DEHP, while volatilization from seawater took place in the near-coast environment. The estimated net gas deposition of DEHP was 5, 30, and 190 t year(-1) for the Norwegian Sea, the Greenland Sea, and the Arctic, respectively. This suggests that atmospheric transport and deposition of phthalates is a significant process for their occurrence in the remote Atlantic and Arctic Ocean.

  3. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model

    EPA Science Inventory

    Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions,...

  4. Atlantic Air-Sea Interaction Revisited

    NASA Astrophysics Data System (ADS)

    Rodwell, M. J.

    INTRODUCTION DATA AND MODELS THE ANALYSIS METHOD ATMOSPHERIC FORCING OF NORTH ATLANTIC SEA SURFACE TEMPERATURES NORTH ATLANTIC SEA SURFACE TEMPERATURE FORCING OF THE ATMOSPHERE Observational Evidence Model Results POTENTIAL SEASONAL PREDICTABILITY BASED ON THE ATMOSPHERE GENERAL - CIRCULATION MODEL CONCLUSIONS AND DISCUSSION REFERENCES

  5. Combustion gas properties. 2: Natural gas fuel and dry air

    NASA Technical Reports Server (NTRS)

    Wear, J. D.; Jones, R. E.; Trout, A. M.; Mcbride, B. J.

    1985-01-01

    A series of computations has been made to produce the equilibrium temperature and gas composition for natural gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only samples tables and figures are provided in this report. The complete set of tables and figures is provided on four microfiche films supplied with this report.

  6. Spatial and seasonal variability of the air-sea equilibration timescale of carbon dioxide

    NASA Astrophysics Data System (ADS)

    Jones, Daniel; Ito, Takamitsu; Takano, Yohei; Hsu, Wei-Ching

    2014-05-01

    The exchange of carbon dioxide between the ocean and the atmosphere tends to bring near-surface waters toward equilibrium by reducing the partial pressure gradient across the air-water interface. However, the equilibration process is not instantaneous; in general there is a lag between forcing and response. The timescale of air-sea equilibration depends on several factors involving the depth of the mixed layer, temperature, salinity, wind speed, and carbonate chemistry. In this work, we use a suite of observational datasets to generate climatological and seasonal composite maps of the air-sea equilibration timescale. The relaxation timescale exhibits considerable spatial and seasonal variations, which are largely set by changes in mixed layer depth and wind speed. The net effect is dominated by the mixed layer depth; the gas exchange velocity and carbonate chemistry parameters only provide partial compensation. Broadly speaking, the adjustment timescale tends to increase with latitude. We compare the observationally-derived air-sea gas exchange timescale with a model-derived surface residence time and a data-derived horizontal transport timescale, which allows us to define two non-dimensional metrics of gas exchange efficiency. These parameters highlight the Southern Ocean, equatorial Pacific, and North Atlantic as regions of inefficient air-sea equilibration where carbon anomalies are likely to form and persist. The efficiency parameters presented here can serve as simple tools for understanding regional air-sea disequilibrium in both observations and models. This work is distributed under the Creative Commons Attribution 3.0 Unported License together with an author copyright. This license does not conflict with the regulations of the Crown Copyright.

  7. On the Global Oxygen Anomaly and Air-Sea Flux

    NASA Technical Reports Server (NTRS)

    Garcia, Hernan E.; Keeling, Ralph F.

    2001-01-01

    A new climatology of monthly air-sea oxygen fluxes throughout the ice-free surface global ocean is presented. The climatology is based on weighted linear least squares regressions using heat flux monthly anomalies for spatial and temporal interpolation of historical O2 data. The seasonal oceanic variations show that the tropical belt (20 S - 20 N) is characterized by relatively small air-sea fluxes when compared to the middle to high latitudes (40 deg - 70 deg). The largest and lowest seasonal fluxes occur during summer and winter in both hemispheres. By means of an atmospheric transport model we show that our climatology is in better agreement with the observed amplitude and phasing of the variations in atmospheric O2/N2 ratios because of seasonal air-sea exchanges at baseline stations in the Pacific Ocean than with previous air-sea O2 climatologies. Our study indicates that the component of the air-sea O2 flux that correlates with heat flux dominates the large-scale air-sea O2 exchange on seasonal timescales. The contribution of each major oceanic basin to the atmospheric observations is described. The seasonal net thermal (SNO(sub T)) and biological (SNO(sub B)) outgassing components of the flux are examined in relation to latitudinal bands, basin-wide, and hemispheric contributions. The Southern Hemisphere's SNO(sub B) (approximately 0.26 Pmol) and SNO(sub T) (approximately 0.29 Pmol) values are larger than the Northern Hemisphere's SNO(sub B) (approximately 0.15 Pmol) and SNO(sub T) (approximately 0.16 Pmol) values (1 Pmol = 10(exp 15) mol). We estimate a global extratropical carbon new production during the outgassing season of 3.7 Pg C (1 Pg = 10(exp 15) g), lower than previous estimates with air-sea O2 climatologies.

  8. Assessing the potential for dimethylsulfide enrichment at the sea surface and its influence on air-sea flux

    NASA Astrophysics Data System (ADS)

    Walker, Carolyn F.; Harvey, Mike J.; Smith, Murray J.; Bell, Thomas G.; Saltzman, Eric S.; Marriner, Andrew S.; McGregor, John A.; Law, Cliff S.

    2016-09-01

    The flux of dimethylsulfide (DMS) to the atmosphere is generally inferred using water sampled at or below 2 m depth, thereby excluding any concentration anomalies at the air-sea interface. Two independent techniques were used to assess the potential for near-surface DMS enrichment to influence DMS emissions and also identify the factors influencing enrichment. DMS measurements in productive frontal waters over the Chatham Rise, east of New Zealand, did not identify any significant gradients between 0.01 and 6 m in sub-surface seawater, whereas DMS enrichment in the sea-surface microlayer was variable, with a mean enrichment factor (EF; the concentration ratio between DMS in the sea-surface microlayer and in sub-surface water) of 1.7. Physical and biological factors influenced sea-surface microlayer DMS concentration, with high enrichment (EF > 1.3) only recorded in a dinoflagellate-dominated bloom, and associated with low to medium wind speeds and near-surface temperature gradients. On occasion, high DMS enrichment preceded periods when the air-sea DMS flux, measured by eddy covariance, exceeded the flux calculated using National Oceanic and Atmospheric Administration (NOAA) Coupled-Ocean Atmospheric Response Experiment (COARE) parameterized gas transfer velocities and measured sub-surface seawater DMS concentrations. The results of these two independent approaches suggest that air-sea emissions may be influenced by near-surface DMS production under certain conditions, and highlight the need for further study to constrain the magnitude and mechanisms of DMS production in the sea-surface microlayer.

  9. Air extraction in gas turbines burning coal-derived gas

    SciTech Connect

    Yang, Tah-teh; Agrawal, A.K.; Kapat, J.S.

    1993-11-01

    In the first phase of this contracted research, a comprehensive investigation was performed. Principally, the effort was directed to identify the technical barriers which might exist in integrating the air-blown coal gasification process with a hot gas cleanup scheme and the state-of-the-art, US made, heavy-frame gas turbine. The guiding rule of the integration is to keep the compressor and the expander unchanged if possible. Because of the low-heat content of coal gas and of the need to accommodate air extraction, the combustor and perhaps, the flow region between the compressor exit and the expander inlet might need to be modified. In selecting a compressed air extraction scheme, one must consider how the scheme affects the air supply to the hot section of the turbine and the total pressure loss in the flow region. Air extraction must preserve effective cooling of the hot components, such as the transition pieces. It must also ensure proper air/fuel mixing in the combustor, hence the combustor exit pattern factor. The overall thermal efficiency of the power plant can be increased by minimizing the total pressure loss in the diffusers associated with the air extraction. Therefore, a study of airflow in the pre- and dump-diffusers with and without air extraction would provide information crucial to attaining high-thermal efficiency and to preventing hot spots. The research group at Clemson University suggested using a Griffith diffuser for the prediffuser and extracting air from the diffuser inlet. The present research establishes that the analytically identified problems in the impingement cooling flow are factual. This phase of the contracted research substantiates experimentally the advantage of using the Griffith diffuser with air extraction at the diffuser inlet.

  10. New research initiative on air sea interaction in South Africa

    SciTech Connect

    Rouault, M.; Leethorp, A.; Lutjeharms, J.R.E.

    1994-12-31

    Recent statistical results have demonstrated that the oceanic environment of Southern Africa plays a important regulating role in the climate of the subcontinent. Statistical teleconnections between oceanic temperature anomalies and precipitation over South Africa`s summer rainfall region have been demonstrated, even to the extent of being partially implicated in catastrophic floods. A research program to investigate the interaction between ocean and atmosphere in those ocean areas that have been identified as crucial to Southern Africa climate and rainfall has just started. The first step of this program was to set up a state of the art air-sea interaction measurement system aboard the antarctic research vessel S.A. Agulhas. The second step of the program was to install low cost automatic air sea interaction measurement systems on three research vessels which will provide an extensive database for air-sea interaction studies.

  11. The air-sea transformation and diapycnal overturning circulation within the Nordic Seas

    NASA Astrophysics Data System (ADS)

    Isachsen, P. E.; Nøst, O. A.

    2012-04-01

    Air-sea flux climatologies and reanalyzes show that the bulk of the oceanic heat and buoyancy loss over the Nordic Seas takes place over interior regions not easily accessible by the time-mean large-scale currents. Eddy transport of heat and buoyancy, from the boundary currents and into the deep basins, is thought to be a key mechanism. Here we use gridded observations, theory and a modern parametrization of eddy transport to quantify the buoyancy budget of this region. The calculations confirm that mean currents are unable to explain the air-sea transformation that takes place over the interior basins of the Nordic Seas and that eddy transport instead dominates. The parametrization of eddy transport also suggests a significant overturning cell between the eastern and western parts of the Nordic Seas. This cell is, however, unaccounted for in the remaining data sets studied here.

  12. Air-sea interactions and precipitation over the tropical oceans

    NASA Technical Reports Server (NTRS)

    Gautier, C.

    1992-01-01

    In this lecture, the author principally discusses air-sea exchanges that are relevant to climate and global problems. The processes of interest are those acting over time scales of months to decades, which in some instances are influenced by smaller-time-scale processes, down to the diurnal time scale. The repsective influence of these processes varies with regions, seasons and scales over which they occur and, because these processes are mostly nonlinear, scale interactions can be quite complex. Owing to the breadth of the topic addressed, the discussion is mostly focused on the tropical regions where air-sea interactions and precipitation processes eventually affect the entire globe. This allows a look in more detail at some air-sea processes, such as those associated with the El Nino southern oscillation (ENSO). This oscillation, which affects the climate of the entire globe, acts over periods of a year or longer and is caused, primarily, by sea surface temperature (SST) variations in the tropical Pacific. As a result, SST variability is often used as an indicator of coupled ocean-atmosphere low-frequency variability. Global or basin scale processes can uniquely be observed from space-born instruments with the coverage required. Space based techniques have been developed during the last decade which can now be used to illustrate the scientific issues presented and the presentation concludes with an overview of some Earth Observing System (EOS) capabilities for addressing air-sea interactions and hydrology issues.

  13. Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights (Invited)

    NASA Astrophysics Data System (ADS)

    Tsuda, A.

    2010-12-01

    Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights Atsushi Tsuda Atmosphere and Ocean Research Institute, The University of Tokyo In the western Pacific (WESTPAC) region, dust originating from Asian and Australian arid regions to the North and South Pacific, biomass burning emissions from the Southeast Asia to sub-tropical Pacific, and other anthropogenic substances are transported regionally and globally to affect cloud and rainfall patterns, air quality, and radiative budgets downwind. Deposition of these compounds into the Asian marginal seas and onto the Pacific Ocean influence surface primary productivity and species composition. In the WESTPAC region, subarctic, subtropical oceans and marginal seas are located relatively narrow latitudinal range and these areas are influenced by the dust and anthropogenic inputs. Moreover, anthropogenic emission areas are located between the arid region and the oceans. The W-PASS (Western Pacific Air-Sea interaction Study) project has been funded for 5 years as a part of SOLAS-Japan activity in the summer of 2006. We aim to resolve air-sea interaction through field observation studies mainly using research vessels and island observatories over the western Pacific. We have carried out 5 cruises to the western North Pacific focusing on air-sea interactions. Also, an intensive marine atmospheric observation including direct atmospheric deposition measurement was accomplished by a dozen W-PASS research groups at the NIES Atmospheric and Aerosol Monitoring Station of Cape Hedo in the northernmost tip of the Okinawa main Island facing the East China Sea in the spring 2008. A few weak Kosa (dust) events, anthropogenic air outflows, typical local air and occupation of marine background air were identified during the campaign period. The W-PASS has four research groups mainly focusing on VOC emissions, air-sea gas exchange processes, biogeochemical responses to dust depositions and its modeling. We also

  14. [Distribution and air-sea fluxes of methane in the Yellow Sea and the East China Sea in the spring].

    PubMed

    Cao, Xing-Peng; Zhang, Gui-Ling; Ma, Xiao; Zhang, Guo-Ling; Liu, Su-Mei

    2013-07-01

    A survey was carried out in the Yellow Sea and the East China Sea from March 17 to April 06 of 2011. Dissolved CH4 in various depths were measured and sea-to-air fluxes were estimated. Methane concentrations in surface and bottom waters ranged between 2.39-29.67 nmol x L(-1) and 2.63-30.63 nmol x L(-1), respectively. Methane concentrations in bottom waters were slightly higher than those in surface waters, suggesting the existence of methane source in bottom waters or sediments. The horizontal distribution of dissolved CH4 showed a decrease from the river mouth to the open sea, and was influenced by the freshwater discharge and the Kuroshio intrusion. Surface methane saturations ranged from 93%-1 038%. Sea to air CH4 fluxes were (2.85 +/- 5.11) micromol x (m2 x d)(-1) (5.18 +/- 9.99) micromol x (m2 x d)(-1) respectively, calculated using the Liss and Merlivat (LM86), the Wanninkhof (W92) relationships and in situ wind speeds, and estimated emission rates of methane from the East China Sea and the Yellow Sea range from 7.05 x 10(-2) - 12.0 x 10(-2) Tg x a(-1) and 1.17 x 10(-2) - 2.20 x 10(-2) Tg x a(-1), respectively. The Yellow Sea and East China Sea are the net sources of atmospheric methane in the spring.

  15. Minanre Gas Concentrators For Air Sampling

    SciTech Connect

    Dr. Seung Ho Hong

    2001-03-01

    The goal of this project was to demonstrate the feasibility of a compact, lightweight, gas-sampling device with rapid-cycle-time characteristics. The highlights of our Phase I work include: (1) Demonstration of a compact gas sampler with integrated heater. This device has an order of magnitude greater adsorption capacity and much faster heating/cooling times than commercial sorbent tubes. (2) Completion of computational fluid dynamics modeling of the gas sampler to determine airflow characteristics for various design options. These modeling efforts guided the development and testing of the Mesochannel Gas Sampler prototype. (3) Testing of the Mesochannel Gas Sampler in parallel with tests of two packed-bed samplers. These tests showed the Mesochannel Gas Sampler represents a substantial improvement compared with the packed-bed approach. Our mesochannel heat-exchanger/adsorber architecture allows very efficient use of adsorbent mass, high adsorbent loadings, and very low pressure drop, which makes possible very high air-sampling rates using a simple, low-power fan. This device is well-suited for collecting samples of trace-level contaminants. The integrated heater, which forms the adsorbent-coated mesochannel walls, allows direct heating of the adsorbent and results in very rapid desorption of the adsorbed species. We believe the Mesochannel Gas Sampler represents a promising technology for the improvement of trace-contaminant detection limits. In our Phase II proposal, we outline several improvements to the gas sampler that will further improve its performance.

  16. Greenhouse gas mitigation can reduce sea-ice loss and increase polar bear persistence.

    PubMed

    Amstrup, Steven C; Deweaver, Eric T; Douglas, David C; Marcot, Bruce G; Durner, George M; Bitz, Cecilia M; Bailey, David A

    2010-12-16

    On the basis of projected losses of their essential sea-ice habitats, a United States Geological Survey research team concluded in 2007 that two-thirds of the world's polar bears (Ursus maritimus) could disappear by mid-century if business-as-usual greenhouse gas emissions continue. That projection, however, did not consider the possible benefits of greenhouse gas mitigation. A key question is whether temperature increases lead to proportional losses of sea-ice habitat, or whether sea-ice cover crosses a tipping point and irreversibly collapses when temperature reaches a critical threshold. Such a tipping point would mean future greenhouse gas mitigation would confer no conservation benefits to polar bears. Here we show, using a general circulation model, that substantially more sea-ice habitat would be retained if greenhouse gas rise is mitigated. We also show, with Bayesian network model outcomes, that increased habitat retention under greenhouse gas mitigation means that polar bears could persist throughout the century in greater numbers and more areas than in the business-as-usual case. Our general circulation model outcomes did not reveal thresholds leading to irreversible loss of ice; instead, a linear relationship between global mean surface air temperature and sea-ice habitat substantiated the hypothesis that sea-ice thermodynamics can overcome albedo feedbacks proposed to cause sea-ice tipping points. Our outcomes indicate that rapid summer ice losses in models and observations represent increased volatility of a thinning sea-ice cover, rather than tipping-point behaviour. Mitigation-driven Bayesian network outcomes show that previously predicted declines in polar bear distribution and numbers are not unavoidable. Because polar bears are sentinels of the Arctic marine ecosystem and trends in their sea-ice habitats foreshadow future global changes, mitigating greenhouse gas emissions to improve polar bear status would have conservation benefits throughout

  17. Greenhouse gas mitigation can reduce sea-ice loss and increase polar bear persistence

    USGS Publications Warehouse

    Amstrup, Steven C.; Deweaver, E.T.; Douglas, D.C.; Marcot, B.G.; Durner, G.M.; Bitz, C.M.; Bailey, D.A.

    2010-01-01

    On the basis of projected losses of their essential sea-ice habitats, a United States Geological Survey research team concluded in 2007 that two-thirds of the worlds polar bears (Ursus maritimus) could disappear by mid-century if business-as-usual greenhouse gas emissions continue. That projection, however, did not consider the possible benefits of greenhouse gas mitigation. A key question is whether temperature increases lead to proportional losses of sea-ice habitat, or whether sea-ice cover crosses a tipping point and irreversibly collapses when temperature reaches a critical threshold. Such a tipping point would mean future greenhouse gas mitigation would confer no conservation benefits to polar bears. Here we show, using a general circulation model, that substantially more sea-ice habitat would be retained if greenhouse gas rise is mitigated. We also show, with Bayesian network model outcomes, that increased habitat retention under greenhouse gas mitigation means that polar bears could persist throughout the century in greater numbers and more areas than in the business-as-usual case. Our general circulation model outcomes did not reveal thresholds leading to irreversible loss of ice; instead, a linear relationship between global mean surface air temperature and sea-ice habitat substantiated the hypothesis that sea-ice thermodynamics can overcome albedo feedbacks proposed to cause sea-ice tipping points. Our outcomes indicate that rapid summer ice losses in models and observations represent increased volatility of a thinning sea-ice cover, rather than tipping-point behaviour. Mitigation-driven Bayesian network outcomes show that previously predicted declines in polar bear distribution and numbers are not unavoidable. Because polar bears are sentinels of the Arctic marine ecosystem and trends in their sea-ice habitats foreshadow future global changes, mitigating greenhouse gas emissions to improve polar bear status would have conservation benefits throughout

  18. AIRS Sea Surface Temperature and Pacific Decadal Oscillation

    NASA Astrophysics Data System (ADS)

    Chen, L. L.

    2015-12-01

    Atmospheric Infrared Sounder (AIRS) has been providing necessary measurements for long term atmospheric and surface processes aboard NASA' s Aqua polar orbiter since May 2002. Here, we use time series of AIRS sea surface temperature (SST) anomalies to show the time evolution of Pacific Decadal Oscillation (PDO) in the Gulf of Alaska (lon:-144.5, lat:54.5) from 2003 to 2014. PDO is connected to the first mode of North Pacific SST variability and is tele-connected to ENSO in the tropics. Further analysis of AIRS data can provide clarification of Pacific climate variability.

  19. Air-sea interactions during strong winter extratropical storms

    USGS Publications Warehouse

    Nelson, Jill; He, Ruoying; Warner, John C.; Bane, John

    2014-01-01

    A high-resolution, regional coupled atmosphere–ocean model is used to investigate strong air–sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air–sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air–sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere–ocean modeling framework.

  20. Air-sea feedback during coastal upwelling

    SciTech Connect

    Gallacher, P.C.

    1994-12-31

    The basic dynamics of coastal upwelling are well known. Consider a steady, curl-free, alongshore wind blowing down a coastline. This results in an Ekman divergence. If the resulting Ekman transport is offshore, coastal upwelling ensues. When this occurs, a front develops between the cold, upwelled water and the less dense offshore surface water. This front propagates offshore at a rate determined by the Ekman transport. The question is what effect does this front have on the atmosphere, and is there a feedback between the atmosphere and the ocean. The results of the FASINEX study have shown that the atmospheric boundary layer can respond dramatically to changes in the ocean surface temperature, and this may happen on small scales and quite rapidly. The author hypothesizes that an interaction can occur in which the atmospheric surface layer becomes more stable on the upwelling side of the front due the colder sea surface temperature.

  1. Distribution and air-sea exchange of current-use pesticides (CUPs) from East Asia to the high Arctic Ocean.

    PubMed

    Zhong, Guangcai; Xie, Zhiyong; Cai, Minghong; Möller, Axel; Sturm, Renate; Tang, Jianhui; Zhang, Gan; He, Jianfeng; Ebinghaus, Ralf

    2012-01-01

    Surface seawater and marine boundary layer air samples were collected on the ice-breaker R/V Xuelong (Snow Dragon) from the East China Sea to the high Arctic (33.23-84.5° N) in July to September 2010 and have been analyzed for six current-use pesticides (CUPs): trifluralin, endosulfan, chlorothalonil, chlorpyrifos, dacthal, and dicofol. In all oceanic air samples, the six CUPs were detected, showing highest level (>100 pg/m(3)) in the Sea of Japan. Gaseous CUPs basically decreased from East Asia (between 36.6 and 45.1° N) toward Bering and Chukchi Seas. The dissolved CUPs in ocean water ranged widely from air. Trifluralin in seawater was relatively high in the Sea of Japan (35.2° N) and evenly distributed between 36.9 and 72.5° N, but it remained below the detection limit at the highest northern latitudes in Chukchi Sea. In contrast with other CUPs, concentrations of chlorothalonil and dacthal were more abundant in Chukchi Sea and in East Asia. The air-sea gas exchange of CUPs was generally dominated by net deposition. Latitudinal trends of fugacity ratios of α-endosulfan, chlorothalonil, and dacthal showed stronger deposition of these compounds in East Asia than in Chukchi Sea, while trifluralin showed stronger deposition in Chukchi Sea (-455 ± 245 pg/m(2)/day) than in the North Pacific (-241 ± 158 pg/m(2)/day). Air-sea gas exchange of chlorpyrifos varied from net volatilizaiton in East Asia (<40° N) to equilibrium or net deposition in the North Pacific and the Arctic.

  2. A parameter model of gas exchange for the seasonal sea ice zone

    NASA Astrophysics Data System (ADS)

    Loose, B.; McGillis, W. R.; Perovich, D.; Zappa, C. J.; Schlosser, P.

    2013-07-01

    Carbon budgets for the polar oceans require better constraint on air-sea gas exchange in the sea ice zone (SIZ). Here, we utilize recent advances in the theory of turbulence, mixing and air-sea flux in the ice-ocean boundary layer (IOBL) to formulate a simple model for gas exchange when the surface ocean is partially covered by sea ice. The gas transfer velocity (k) is related to shear-driven and convection-driven turbulence in the aqueous mass boundary layer, and to the mean-squared wave slope at the air-sea interface. We use the model to estimate k along the drift track of Ice-Tethered Profilers (ITPs) in the Arctic. Individual estimates of daily-averaged k from ITP drifts ranged between 1.1 and 22 m d-1, and the fraction of open water (f) ranged from 0 to 0.83. Converted to area-weighted effective transfer velocities (keff), the minimum value of keff was 10-5 m d-1 near f = 0 with values exceeding keff = 5 m d-1 at f = 0.4. The largest values of k occurred during the periods when ice cover around the ITP was changing rapidly; either in advance or retreat. The model indicates that effects from shear and convection in the sea ice zone contribute an additional 40% to the magnitude of keff, beyond what would be predicted from an estimate of keff based solely upon a windspeed parameterization. Although the ultimate scaling relationship for gas exchange in the sea ice zone will require validation in laboratory and field studies, the basic parameter model described here demonstrates that it is feasible to formulate estimates of k based upon properties of the IOBL using data sources that presently exist.

  3. A parameter model of gas exchange for the seasonal sea ice zone

    NASA Astrophysics Data System (ADS)

    Loose, B.; McGillis, W. R.; Perovich, D.; Zappa, C. J.; Schlosser, P.

    2014-01-01

    Carbon budgets for the polar oceans require better constraint on air-sea gas exchange in the sea ice zone (SIZ). Here, we utilize advances in the theory of turbulence, mixing and air-sea flux in the ice-ocean boundary layer (IOBL) to formulate a simple model for gas exchange when the surface ocean is partially covered by sea ice. The gas transfer velocity (k) is related to shear-driven and convection-driven turbulence in the aqueous mass boundary layer, and to the mean-squared wave slope at the air-sea interface. We use the model to estimate k along the drift track of ice-tethered profilers (ITPs) in the Arctic. Individual estimates of daily-averaged k from ITP drifts ranged between 1.1 and 22 m d-1, and the fraction of open water (f) ranged from 0 to 0.83. Converted to area-weighted effective transfer velocities (keff), the minimum value of keff was 10-55 m d-1 near f = 0 with values exceeding keff = 5 m d-1 at f = 0.4. The model indicates that effects from shear and convection in the sea ice zone contribute an additional 40% to the magnitude of keff, beyond what would be predicted from an estimate of keff based solely upon a wind speed parameterization. Although the ultimate scaling relationship for gas exchange in the sea ice zone will require validation in laboratory and field studies, the basic parameter model described here demonstrates that it is feasible to formulate estimates of k based upon properties of the IOBL using data sources that presently exist.

  4. Distribution and air-sea fluxes of carbon dioxide on the Chukchi Sea shelf

    NASA Astrophysics Data System (ADS)

    Pipko, I. I.; Pugach, S. P.; Repina, I. A.; Dudarev, O. V.; Charkin, A. N.; Semiletov, I. P.

    2015-12-01

    This article presents the results of long-term studies of the dynamics of carbonate parameters and air-sea carbon dioxide fluxes on the Chukchi Sea shelf during the summer. As a result of the interaction of physical and biological factors, the surface waters on the west of Chukchi Sea were undersaturated with carbon dioxide when compared with atmospheric air; the partial pressure of CO2 varied in the range from 134 to 359 μatm. The average value of CO2 flux in the Chukchi Sea per unit area varied in the range from-2.4 to-22.0 mmol /(m2 day), which is significantly higher than the average value of CO2 flux in the World Ocean. It has been estimated that the minimal mass of C absorbed by the surface of Chukchi Sea from the atmosphere during ice-free season is 13 × 1012 g; a great part of this carbon is transported to the deeper layers of sea and isolated from the atmosphere for a long period of time. The studies of the carbonate system of the Chukchi Sea, especially of its western part, will provide some new data on the fluxes of carbon dioxide in the Arctic Ocean and their changes. Our analysis can be used for an interpretation of the satellite assessment of CO2 fluxes and dissolved CO2 distribution in the upper layers of the ocean.

  5. The Effect of Rain on Air-Water Gas Exchange

    NASA Technical Reports Server (NTRS)

    Ho, David T.; Bliven, Larry F.; Wanninkhof, Rik; Schlosser, Peter

    1997-01-01

    The relationship between gas transfer velocity and rain rate was investigated at NASA's Rain-Sea Interaction Facility (RSIF) using several SF, evasion experiments. During each experiment, a water tank below the rain simulator was supersaturated with SF6, a synthetic gas, and the gas transfer velocities were calculated from the measured decrease in SF6 concentration with time. The results from experiments with IS different rain rates (7 to 10 mm/h) and 1 of 2 drop sizes (2.8 or 4.2 mm diameter) confirm a significant and systematic enhancement of air-water gas exchange by rainfall. The gas transfer velocities derived from our experiment were related to the kinetic energy flux calculated from the rain rate and drop size. The relationship obtained for mono-dropsize rain at the RSIF was extrapolated to natural rain using the kinetic energy flux of natural rain calculated from the Marshall-Palmer raindrop size distribution. Results of laboratory experiments at RSIF were compared to field observations made during a tropical rainstorm in Miami, Florida and show good agreement between laboratory and field data.

  6. NOx Emissions from Oil and Gas Production in the North Sea

    NASA Astrophysics Data System (ADS)

    Lee, J. D.; Foulds, A.; Purvis, R.; Vaughan, A. R.; Carslaw, D.; Lewis, A. C.

    2015-12-01

    North Sea oil is a mixture of hydrocarbons, comprising liquid petroleum and natural gas, produced from petroleum reservoirs beneath the North Sea. As of January 2015, the North Sea is the world's most active offshore drilling region with 173 rigs drilling. During the summer of 2015, a series of survey flights took place on the UKs FAAM BAe 146 research aircraft with the primary aim to assess background methane (and other hydrocarbons) levels in the drilling areas of the North Sea. Also measured were Nitrogen Oxides (NO and NO2), which are emitted from almost all combustion processes and are a key air pollutant, both directly and as a precursor to ozone (O3). The oil and gas platforms in the North Sea are often manned and require significant power generation and support vessels for their continued operation, processes that potentially emit significant amounts of NOx into an otherwise relative clean environment. During these flights we were able to measure the NO­­­x (and any subsequently produced O3) emitted from specific rigs, as well as the NOx levels in the wider North Sea oil and gas production region (see figure for example). NOx mixing ratios of <10 ppbv were frequently observed in plumes, with significant perturbation to the wider North Sea background levels. NOx emissions from the rigs are point sources within the UKs National Atmospheric Emission Inventory (NAEI) and the measurements taken in plumes from individual rigs are used to assess the accuracy of these estimates.

  7. Air-borne sound generated by sea waves.

    PubMed

    Bolin, Karl; Åbom, Mats

    2010-05-01

    This paper describes a semi-empiric model and measurements of air-borne sound generated by breaking sea waves. Measurements have been performed at the Baltic Sea. Shores with different slopes and sediment types have been investigated. Results showed that the sound pressure level increased from 60 dB at 0.4 m wave height to 78 dB at 2.0 m wave height. The 1/3 octave spectrum was dependent on the surf type. A scaling model based on the dissipated wave power and a surf similarity parameter is proposed and compared to measurements. The predictions show satisfactory agreement to the measurements.

  8. Air-sea exchange of carbon dioxide in the Southern Ocean and Antarctic marginal ice zone

    NASA Astrophysics Data System (ADS)

    Butterworth, Brian J.; Miller, Scott D.

    2016-07-01

    Direct carbon dioxide flux measurements using eddy covariance from an icebreaker in the high-latitude Southern Ocean and Antarctic marginal ice zone are reported. Fluxes were combined with the measured water-air carbon dioxide partial pressure difference (ΔpCO2) to compute the air-sea gas transfer velocity (k, normalized to Schmidt number 660). The open water data showed a quadratic relationship between k (cm h-1) and the neutral 10 m wind speed (U10n, m s-1), kopen = 0.245 U10n2 + 1.3, in close agreement with decades old tracer-based results and much lower than cubic relationships inferred from previous open ocean eddy covariance studies. In the marginal ice zone, the effective gas transfer velocity decreased in proportion to sea ice cover, in contrast with predictions of enhanced gas exchange in the presence of sea ice. The combined open water and marginal ice zone results affect the calculated magnitude and spatial distribution of Southern Ocean carbon flux.

  9. Air Monitoring for Hazardous Gas Detection

    NASA Technical Reports Server (NTRS)

    Arkin, C. Richard; Naylor, Guy; Haskell, William; Floyd, David; Curley, Charles; Griffin, Timothy P.; Adams, Frederick; Follistein, Duke

    2003-01-01

    The Hazardous Gas Detection Lab is involved in the design and development of instrumentation that can detect and quantify various hazardous gases. Traditionally these systems are designed for leak detection of the cryogenic gases used for the propulsion of the Shuttle and other vehicles. Mass spectrometers are the basis of these systems, which provide excellent quantitation, sensitivity, selectivity, response and limits of detection. Unfortunately, these systems are large, heavy and expensive. This feature limits the ability to perform gas analysis in certain applications. Smaller and lighter mass spectrometer systems could be used in many more applications primarily due to the portability of the system. Such applications would include air analysis in confined spaces, in-situ environmental analysis and emergency response. In general, system cost is lowered as size is reduced. With a low cost air analysis system, several systems could be utilized for monitoring large areas. These networked systems could be deployed at job-sites for worker safety, throughout a community for pollution warnings, or dispersed in a battlefield for early warning of chemical or biological threats. Presented will be information on the first prototype of this type of system. Included will be field trial data, with this prototype performing air analysis autonomously from an aircraft.

  10. The organic sea surface microlayer in the upwelling region off Peru and implications for air-sea exchange processes

    NASA Astrophysics Data System (ADS)

    Engel, A.; Galgani, L.

    2015-07-01

    The sea surface microlayer (SML) is at the very surface of the ocean, linking the hydrosphere with the atmosphere, and central to a range of global biogeochemical and climate-related processes. The presence and enrichment of organic compounds in the SML have been suggested to influence air-sea gas exchange processes as well as the emission of primary organic aerosols. Among these organic compounds, primarily of plankton origin, are dissolved exopolymers, specifically polysaccharides and proteins, and gel particles, such as Transparent Exopolymer Particles (TEP) and Coomassie Stainable Particles (CSP). These organic substances often accumulate in the surface ocean when plankton productivity is high. Here, we report results obtained in December 2012 during the SOPRAN Meteor 91 cruise to the highly productive, coastal upwelling regime off Peru. Samples were collected from the SML and from ~ 20 cm below, and were analyzed for polysaccharidic and proteinaceous compounds, gel particles, total and dissolved organic carbon, bacterial and phytoplankton abundance. Our study provides insight to the physical and biological control of organic matter enrichment in the SML, and discusses the potential role of organic matter in the SML for air-sea exchange processes.

  11. The Gas Transfer through Polar Sea ice experiment: Insights into the rates and pathways that determine geochemical fluxes

    NASA Astrophysics Data System (ADS)

    Lovely, A.; Loose, B.; Schlosser, P.; McGillis, W.; Zappa, C.; Perovich, D.; Brown, S.; Morell, T.; Hsueh, D.; Friedrich, R.

    2015-12-01

    Sea ice is a defining feature of the polar marine environment. It is a critical domain for marine biota and it regulates ocean-atmosphere exchange, including the exchange of greenhouse gases such as CO2 and CH4. In this study, we determined the rates and pathways that govern gas transport through a mixed sea ice cover. N2O, SF6, 3He, 4He, and Ne were used as gas tracers of the exchange processes that take place at the ice-water and air-water interfaces in a laboratory sea ice experiment. Observation of the changes in gas concentrations during freezing revealed that He is indeed more soluble in ice than in water; Ne is less soluble in ice, and the larger gases (N2O and SF6) are mostly excluded during the freezing process. Model estimates of gas diffusion through ice were calibrated using measurements of bulk gas content in ice cores, yielding gas transfer velocity through ice (kice) of ˜5 × 10-4 m d-1. In comparison, the effective air-sea gas transfer velocities (keff) ranged up to 0.33 m d-1 providing further evidence that very little mixed-layer ventilation takes place via gas diffusion through columnar sea ice. However, this ventilation is distinct from air-ice gas fluxes driven by sea ice biogeochemistry. The magnitude of keff showed a clear increasing trend with wind speed and current velocity beneath the ice, as well as the combination of the two. This result indicates that gas transfer cannot be uniquely predicted by wind speed alone in the presence of sea ice.

  12. Air-Sea Interactions in CLIMODE: In-Situ Observations

    NASA Astrophysics Data System (ADS)

    Bigorre, S.; Weller, R.

    2006-12-01

    The subtropical mode water of the North Atlantic or Eighteen Degree Water (EDW) is an important component of the oceanic circulation. Its formation and evolution are linked to fundamental aspects of the oceanic climate. A central formation process involves the subduction of surface water through air-sea interactions. Conditions for this are ideal in the Gulf Stream region when warm water interacts with cold air above, sinks and is trapped in the late winter, thereby ventilating the interior. The study program CLIvar MOde Water Dynamic Experiment (CLIMODE), sponsored by NSF, is designed to quantify and understand which processes lead to the formation and dissipation of EDW. A key component to this goal is the knowledge of buoyancy fluxes in the region of EDW formation. The Upper Ocean Processes (UOP) group deployed a 3-m discus buoy anchored in the Gulf Stream (64W, 38N) in November 2005. Oceanographic instruments collect data along the mooring line while meteorological and surface sensors are placed on the buoy and collect data every minute. Since the deployment, hourly averages of the meteorological data were transmitted through the Argos satellite system. These data were plugged in the TOGA-COARE bulk algorithm to estimate air-sea fluxes. These preliminary results are presented, while the full dataset will be analyzed after recovery of the buoy in November 2006. Heat fluxes estimates indicate high heat loss events. In December 2005, regular losses larger than 1000W/m2 occurred. These heat loss events are associated with cold air outbreaks. When the air-sea temperature gradient increases, winds also tend to increase indicating a destabilization of the boundary layer and production of turbulence, enhancing further the heat transfer. As the air-sea temperature gradient decreases in the late winter, heat loss also decreases. The SST signal is seen to modulate the heat fluxes on lower frequencies than air temperature changes. This kind of signal tends therefore to be

  13. A Sensitivity Analysis of the Impact of Rain on Regional and Global Sea-Air Fluxes of CO2

    PubMed Central

    Shutler, J. D.; Land, P. E.; Woolf, D. K.; Quartly, G. D.

    2016-01-01

    The global oceans are considered a major sink of atmospheric carbon dioxide (CO2). Rain is known to alter the physical and chemical conditions at the sea surface, and thus influence the transfer of CO2 between the ocean and atmosphere. It can influence gas exchange through enhanced gas transfer velocity, the direct export of carbon from the atmosphere to the ocean, by altering the sea skin temperature, and through surface layer dilution. However, to date, very few studies quantifying these effects on global net sea-air fluxes exist. Here, we include terms for the enhanced gas transfer velocity and the direct export of carbon in calculations of the global net sea-air fluxes, using a 7-year time series of monthly global climate quality satellite remote sensing observations, model and in-situ data. The use of a non-linear relationship between the effects of rain and wind significantly reduces the estimated impact of rain-induced surface turbulence on the rate of sea-air gas transfer, when compared to a linear relationship. Nevertheless, globally, the rain enhanced gas transfer and rain induced direct export increase the estimated annual oceanic integrated net sink of CO2 by up to 6%. Regionally, the variations can be larger, with rain increasing the estimated annual net sink in the Pacific Ocean by up to 15% and altering monthly net flux by > ± 50%. Based on these analyses, the impacts of rain should be included in the uncertainty analysis of studies that estimate net sea-air fluxes of CO2 as the rain can have a considerable impact, dependent upon the region and timescale. PMID:27673683

  14. Tropical Cyclone Induced Air-Sea Interactions Over Oceanic Fronts

    NASA Astrophysics Data System (ADS)

    Shay, L.

    2012-04-01

    Recent severe tropical cyclones underscore the inherent importance of warm background ocean fronts and their interactions with the atmospheric boundary layer. Central to the question of heat and moisture fluxes from the ocean to the atmosphere, the amount of heat available to the tropical cyclone is predicated by the initial depth of the mixed layer and strength of the stratification level that set the level of entrainment mixing at the base of the oceanic mixed layer. For example in oceanic regimes where the ocean mixed layers are thin, shear-induced mixing tends to cool the upper ocean (and sea surface temperatures) quickly which reduces the air-sea fluxes. This is an example of negative feedback from the ocean to the atmosphere. By contrast, in regimes where the ocean mixed layers are deep (usually along the western part of the gyres), warm water advection by the nearly steady currents reduces the levels of turbulent mixing by shear instabilities. As these strong near-inertial shears are arrested, more heat and moisture is available through the sea surface. When tropical cyclones move into favorable or neutral atmospheric conditions (low vertical shear, anticyclonic circulation aloft), tropical cyclones have a tendency to rapidly intensify as observed over the Gulf of Mexico during Isidore and Lili in 2002, Katrina and Rita in 2005, Dean and Felix in 2007 in the Caribbean Sea, and Earl in 2010 just north of the Caribbean Islands. To predict these tropical cyclone deepening (as well as weakening) cycles, coupled models must have ocean models with realistic ocean conditions and accurate air-sea and vertical mixing parameterizations. These effects and possible impact on TC deepening and weakening underscores the necessity of having complete 3-D ocean measurements juxtaposed with atmospheric profiler measurements.

  15. Helium isotopes and heavier noble gas abundances of water in adjacent sea of Japan

    NASA Astrophysics Data System (ADS)

    Sano, Y.; Takahata, N.; Watanabe, T.; Shirai, K.; Nishizawa, M.

    2003-12-01

    We have measured helium isotopic ratios of water samples collected with various depths in adjacent sea of Japan. The 3He/4He ratios vary significantly from 0.989 Ratm to 1.242 Ratm where Ratm is the atmospheric ratio of 1.39x10-6. It is confirmed that all deep sea water (2000 - 2500 m) of western North Pacific is affected by the mantle helium with a high 3He/4He ratio. More precisely mid-depth (750 - 1500 m) profiles of 3He/4He ratios of northwestern Philippine Sea (Nansei Trench) and east of East China Sea (northeast and southwest of Okinawa Trough) are higher than those of western North Pacific (Off Joban) and comparable to those of northern Philippine Sea (Nankai Trough). Excess 3He of the mid-depth samples may be attributable to the subduction-type mantle helium originated from high-temperature hydrothermal sites in the Okinawa Trough. Noble gas abundances (neon, argon, krypton and xenon) were measured in water samples collected in western North Pacific and northwestern Philippine Sea. Neon abundances show slight excess relative to air saturated sea water at ambient temperature and salinity. This may be due to either air bubble effect or contamination during the sampling. When these effects are corrected using the neon anomaly, heavier noble gas abundances (argon, krypton and xenon) of samples with the temperature higher than 5° C (shallower than 500m) agree well with those of calculated air saturated seawater, while the lower temperature samples (deeper than 500 m) indicate anomaly of -7% to +10%.

  16. Coaxial fuel and air premixer for a gas turbine combustor

    DOEpatents

    York, William D; Ziminsky, Willy S; Lacy, Benjamin P

    2013-05-21

    An air/fuel premixer comprising a peripheral wall defining a mixing chamber, a nozzle disposed at least partially within the peripheral wall comprising an outer annular wall spaced from the peripheral wall so as to define an outer air passage between the peripheral wall and the outer annular wall, an inner annular wall disposed at least partially within and spaced from the outer annular wall, so as to define an inner air passage, and at least one fuel gas annulus between the outer annular wall and the inner annular wall, the at least one fuel gas annulus defining at least one fuel gas passage, at least one air inlet for introducing air through the inner air passage and the outer air passage to the mixing chamber, and at least one fuel inlet for injecting fuel through the fuel gas passage to the mixing chamber to form an air/fuel mixture.

  17. US Navy Submarine Sea Trial of the NASA Air Quality Monitor

    NASA Technical Reports Server (NTRS)

    Limero, Thomas; Wallace, William T.; Manney, Joshua A.; Mudgett, Paul D.

    2017-01-01

    For the past four years, the Air Quality Monitor (AQM) has been the operational instrument for measuring trace volatile organic compounds on the International Space Station (ISS). The key components of the AQM are the inlet preconcentrator, the gas chromatograph (GC), and the differential mobility spectrometer. Most importantly, the AQM operates at atmospheric pressure and uses air as the GC carrier gas, which translates into a small reliable instrument. Onboard ISS there are two AQMs, with different GC columns that detect and quantify 22 compounds. The AQM data contributes valuable information to the assessment of air quality aboard ISS for each crew increment. The U.S. Navy is looking to update its submarine air monitoring suite of instruments, and the success of the AQM on ISS has led to a jointly planned submarine sea trial of a NASA AQM. In addition to the AQM, the Navy is also interested in the Multi-Gas Monitor (MGM), which was successfully flown on ISS as a technology demonstration to measure major constituent gases (oxygen, carbon dioxide, water vapor, and ammonia). A separate paper will present the MGM sea trial results. A prototype AQM, which is virtually identical to the operational AQM, has been readied for the sea trial. Only one AQM will be deployed during the sea trial, but it is sufficient to detect the compounds of interest to the Navy for the purposes of this trial. A significant benefit of the AQM is that runs can be scripted for pre-determined intervals and no crew intervention is required. The data from the sea trial will be compared to archival samples collected prior to and during the trial period. This paper will give a brief overview of the AQM technology and protocols for the submarine trial. After a quick review of the AQM preparation, the main focus of the paper will be on the results of the submarine trial. Of particular interest will be the comparison of the contaminants found in the ISS and submarine atmospheres, as both represent

  18. Effect of sea sprays on air-sea momentum exchange at severe wind conditions

    NASA Astrophysics Data System (ADS)

    Troitskaya, Yu.; Ezhova, E.; Semenova, A.; Soustova, I.

    2012-04-01

    Wind-wave interaction at extreme wind speed is of special interest now in connection with the problem of explanation of the sea surface drag saturation at the wind speed exceeding 30 m/s. The idea on saturation (and even reduction) of the coefficient of aerodynamic resistance of the sea surface at hurricane wind speed was first suggested in [1] on the basis of theoretical analysis of sensitivity of maximum wind speed in a hurricane to the ratio of the enthalpy and momentum exchange coefficients. Both field [2-4] and laboratory [5] experiments confirmed that at hurricane wind speed the sea surface drag coefficient is significantly reduced in comparison with the parameterization obtained at moderate to strong wind conditions. Two groups of possible theoretical mechanisms for explanation of the effect of the sea surface drag reduction can be specified. In the first group of models developed in [6,7], the sea surface drag reduction is explained by peculiarities of the air flow over breaking waves. Another approach more appropriate for the conditions of developed sea exploits the effect of sea drops and sprays on the wind-wave momentum exchange. Papers[8,9] focused on the effect of the sea drops on stratification of the air-sea boundary layer similar to the model of turbulent boundary layer with the suspended particles [10], while papers [11-13] estimated the momentum exchange of sea drops and air-flow. A mandatory element of the spray induced momentum flux is a parameterization of the momentum exchange between droplets and air flow, which determines the "source function" in the momentum balance equation. In this paper a model describing the motion of a spume droplet, the wind tear away from the crest of a steep surface wave, and then falling into the water. We consider two models for the injection of droplets into the air flow. The first one assumes that the drop starts from the surface at the orbital velocity of the wave. In the second model we consider droplets from

  19. View of steam powered air compressor in boiler house. Gas ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of steam powered air compressor in boiler house. Gas engine powered electric generators are visible in far left background. - Burnsville Natural Gas Pumping Station, Saratoga Avenue between Little Kanawha River & C&O Railroad line, Burnsville, Braxton County, WV

  20. Temporal variability of air-sea CO2 exchange in a low-emission estuary

    NASA Astrophysics Data System (ADS)

    Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

    2016-07-01

    There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

  1. Impacts of Atmospheric Modes of Variability on Air-Sea Heat Exchange in the Red Sea

    NASA Astrophysics Data System (ADS)

    Abualnaja, Yasser O.; Papadopoulos, Vassilis P.; Josey, Simon A.; Hoteit, Ibrahim; Kontoyiannis, Harilaos; Raitsos, Dionissios E.

    2014-05-01

    The potential impacts on Red Sea surface heat exchange of various major modes of atmospheric variability are investigated using the NASA Modern Era Retrospective Analysis for Research and Applications (MERRA) atmospheric reanalysis and the Objectively Analyzed Air-Sea Flux dataset (OAFlux) merged satellite+reanalysis dataset. The mode impacts on surface net heat flux are quantified by calculating the heat flux anomaly that corresponds to a unit positive value of each index for each grid point. The seasonal effects of the atmospheric forcing are investigated considering two and four typical seasons of a calendar year. Considering two seasons, the impacts are strongest during the winter-centered part of the year (October to March) mainly over the northern sub-basin. The North Atlantic Oscillation (NAO), the East Atlantic - West Russia Pattern (EAWR), and the Indian Monsoon Index (IMI) have the greatest effects. They generate negative anomalies (by definition additional ocean heat loss) of 7-12 W/m2 in the northern Red Sea basin mean net heat flux for a unit positive value of the mode index. During the summer (April to September), the signal is smaller and the East Atlantic (EA) and Multivariate ENSO Index (MEI) modes have the strongest impact which is now located in the southern Red Sea (sub-basin anomalies of 4 W/m2 for unit positive mode index, negative for EA and positive for MEI). Results obtained by analysis carried out on the traditional four-season basis reveal that indices impact peaks during the typical boreal winter (DJF) with average anomalies of 12-18 W/m2 to be found in the northern part. It is noteworthy that during the winter, the EAWR generates negative anomalies around 30 W/m2 over the most of the central Red Sea. During the spring (MAM), summer (JJA) and autumn (SON) the anomalies are considerably lower, especially during the spring when the mode impacts are negligible. Atmospheric modes have a stronger effect on air-sea heat flux over the northern

  2. The impact of lower sea-ice extent on Arctic greenhouse-gas exchange

    USGS Publications Warehouse

    Parmentier, Frans-Jan W.; Christensen, Torben R.; Sørensen, Lise Lotte; Rysgaard, Søren; McGuire, A. David; Miller, Paul A.; Walker, Donald A.

    2013-01-01

    In September 2012, Arctic sea-ice extent plummeted to a new record low: two times lower than the 1979–2000 average. Often, record lows in sea-ice cover are hailed as an example of climate change impacts in the Arctic. Less apparent, however, are the implications of reduced sea-ice cover in the Arctic Ocean for marine–atmosphere CO2 exchange. Sea-ice decline has been connected to increasing air temperatures at high latitudes. Temperature is a key controlling factor in the terrestrial exchange of CO2 and methane, and therefore the greenhouse-gas balance of the Arctic. Despite the large potential for feedbacks, many studies do not connect the diminishing sea-ice extent with changes in the interaction of the marine and terrestrial Arctic with the atmosphere. In this Review, we assess how current understanding of the Arctic Ocean and high-latitude ecosystems can be used to predict the impact of a lower sea-ice cover on Arctic greenhouse-gas exchange.

  3. Gas Bubble Disease in the Brain of a Living California Sea Lion (Zalophus californianus).

    PubMed

    Van Bonn, William; Dennison, Sophie; Cook, Peter; Fahlman, Andreas

    2013-01-01

    A yearling California sea lion (Zalophus californianus) was admitted into rehabilitation with signs of cerebellar pathology. Diagnostic imaging that included radiography and magnetic resonance imaging (MRI) demonstrated space-occupying lesions predominantly in the cerebellum that were filled partially by CSF-like fluid and partially by gas, and cerebral lesions that were fluid filled. Over a maximum period of 4 months, the brain lesions reduced in size and the gas resorbed and was replaced by CSF-like fluid. In humans, the cerebellum is known to be essential for automating practiced movement patterns (e.g., learning to touch-type), also known as procedural learning or the consolidation of "motor memory." To test the animal in this study for motor memory deficits, an alternation task in a two-choice maze was utilized. The sea lion performed poorly similar to another case of pneumocerebellum previously reported, and contrary to data acquired from a group of sea lions with specific hippocampal injury. The learning deficits were attributed to the cerebellar injury. These data provide important insight both to the clinical presentation and behavioral observations of cerebellar injury in sea lions, as well as providing an initial model for long-term outcome following cerebellar injury. The specific etiology of the gas could not be determined. The live status of the patient with recovery suggests that the most likely etiologies for the gas are either de novo formation or air emboli secondary to trauma. A small air gun pellet was present within and was removed from soft tissues adjacent to the tympanic bulla. While no evidence to support the pellet striking bone was found, altered dive pattern associated with this human interaction may have provided the opportunity for gas bubble formation to occur. The similarity in distribution of the gas bubble related lesions in this case compared with another previously published case of pneumocerebellum suggests that preferential

  4. Control of Quaternary sea-level changes on gas seeps

    NASA Astrophysics Data System (ADS)

    Riboulot, Vincent; Thomas, Yannick; Berné, Serge; Jouet, Gwénaël.; Cattaneo, Antonio

    2014-07-01

    Gas seeping to the seafloor through structures such as pockmarks may contribute significantly to the enrichment of atmospheric greenhouse gases and global warming. Gas seeps in the Gulf of Lions, Western Mediterranean, are cyclical, and pockmark "life" is governed both by sediment accumulation on the continental margin and Quaternary climate changes. Three-dimensional seismic data, correlated to multi-proxy analysis of a deep borehole, have shown that these pockmarks are associated with oblique chimneys. The prograding chimney geometry demonstrates the syn-sedimentary and long-lasting functioning of the gas seeps. Gas chimneys have reworked chronologically constrained stratigraphic units and have functioned episodically, with maximum activity around sea level lowstands. Therefore, we argue that one of the main driving mechanisms responsible for their formation is the variation in hydrostatic pressure driven by relative sea level changes.

  5. Air-Sea Interactions over Lakes on Titan

    NASA Astrophysics Data System (ADS)

    Soto, Alejandro; Rafkin, Scot C. R.

    2016-10-01

    The exchange of methane between the atmosphere and surface liquid reservoirs dominates the short time-scale methanological cycle. In this study, previous two-dimensional simulations of the exchange of methane vapor, sensible heat and momentum between the atmosphere and lakes are updated with the inclusion of radiative forcing, three dimensions, and realistic coastlines. Titan's air-sea exchange in two dimensions indicated that the exchange process was self-limiting. Evaporation from lakes produced a shallow but extremely stable marine layer that suppressed turbulent exchange. Furthermore, the circulation associated with the higher buoyancy of methane-rich atmosphere over the lake was offset by the oppositely directed thermal sea breeze circulation, which muted the mean wind. Two major weaknesses of this previous work were the lack of radiative forcing and the imposition of two dimensionality, which limited the full range of dynamical solutions. Based on early theoretical studies, it was thought that magnitude of turbulent energy flux exchanges would be much larger than radiative fluxes, thereby justifying the neglect of radiation, but the two-dimensional simulations indicated that this was not a valid assumption. The dynamical limitations of two-dimensional simulations are well known. Vorticity stretching (i.e., circulation intensification through vertical motion) is not possible and it is also not possible to produce dynamically balanced gradient wind-type circulations. As well, the irregular shape of a realistic coastline cannot be expressed in two dimensions, and these realistic structures will generally induce complex convergence and divergence circulations in the atmosphere. The impact of radiative forcing and the addition of the third dimension on the air-sea exchange are presented.

  6. Tropical Cyclone Induced Air-Sea Interactions Over Oceanic Fronts

    NASA Astrophysics Data System (ADS)

    Shay, L. K.

    2012-12-01

    Recent severe tropical cyclones underscore the inherent importance of warm background ocean fronts and their interactions with the atmospheric boundary layer. Central to the question of heat and moisture fluxes, the amount of heat available to the tropical cyclone is predicated by the initial mixed layer depth and strength of the stratification that essentially set the level of entrainment mixing at the base of the mixed layer. In oceanic regimes where the ocean mixed layers are thin, shear-induced mixing tends to cool the upper ocean to form cold wakes which reduces the air-sea fluxes. This is an example of negative feedback. By contrast, in regimes where the ocean mixed layers are deep (usually along the western part of the gyres), warm water advection by the nearly steady currents reduces the levels of turbulent mixing by shear instabilities. As these strong near-inertial shears are arrested, more heat and moisture transfers are available through the enthalpy fluxes (typically 1 to 1.5 kW m-2) into the hurricane boundary layer. When tropical cyclones move into favorable or neutral atmospheric conditions, tropical cyclones have a tendency to rapidly intensify as observed over the Gulf of Mexico during Isidore and Lili in 2002, Katrina, Rita and Wilma in 2005, Dean and Felix in 2007 in the Caribbean Sea, and Earl in 2010 just north of the Caribbean Islands. To predict these tropical cyclone deepening (as well as weakening) cycles, coupled models must have ocean models with realistic ocean conditions and accurate air-sea and vertical mixing parameterizations. Thus, to constrain these models, having complete 3-D ocean profiles juxtaposed with atmospheric profiler measurements prior, during and subsequent to passage is an absolute necessity framed within regional scale satellite derived fields.

  7. Spatio-temporal visualization of air-sea CO2 flux and carbon budget using volume rendering

    NASA Astrophysics Data System (ADS)

    Du, Zhenhong; Fang, Lei; Bai, Yan; Zhang, Feng; Liu, Renyi

    2015-04-01

    This paper presents a novel visualization method to show the spatio-temporal dynamics of carbon sinks and sources, and carbon fluxes in the ocean carbon cycle. The air-sea carbon budget and its process of accumulation are demonstrated in the spatial dimension, while the distribution pattern and variation of CO2 flux are expressed by color changes. In this way, we unite spatial and temporal characteristics of satellite data through visualization. A GPU-based direct volume rendering technique using half-angle slicing is adopted to dynamically visualize the released or absorbed CO2 gas with shadow effects. A data model is designed to generate four-dimensional (4D) data from satellite-derived air-sea CO2 flux products, and an out-of-core scheduling strategy is also proposed for on-the-fly rendering of time series of satellite data. The presented 4D visualization method is implemented on graphics cards with vertex, geometry and fragment shaders. It provides a visually realistic simulation and user interaction for real-time rendering. This approach has been integrated into the Information System of Ocean Satellite Monitoring for Air-sea CO2 Flux (IssCO2) for the research and assessment of air-sea CO2 flux in the China Seas.

  8. Air-sea interaction and surface flux in non-equilibrium sea-states

    SciTech Connect

    Levy, G.; Ek, M.; Mahrt, L.

    1994-12-31

    The wind forcing over the ocean determines the air-sea exchanges of heat, moisture and momentum which affect and drive the surface wave dynamics and the mixed layer circulation. In turn, it has been shown that wave dynamics and wave age affect ocean surface roughness and air-sea exchange processes so that the wind flow is not always in equilibrium with the ocean surface waves. This effect of wave spectrum on surface roughness has been discussed by many authors; yet it is rarely, if ever, accounted for in flux parameterization in models of the marine atmospheric boundary layer (MABL). Proper representation of these effects in both remote sensors` signal to geophysical-parameter models and in physical models of the ocean and the atmosphere on all scales is essential given the increased reliance of ocean monitoring systems on remote sea-surface sensors and the fundamental sensitivity of physical models to surface fluxes. In this paper the authors present a methodology for modeling these effects from data along with some results from data analyses of observations taken in two field experiments.

  9. Acoustic Investigations of Gas and Gas Hydrate Formations, Offshore Southwestern Black Sea*

    NASA Astrophysics Data System (ADS)

    Kucuk, H. M.; Dondurur, D.; Ozel, O.; Atgin, O.; Sinayuc, C.; Merey, S.; Parlaktuna, M.; Cifci, G.

    2015-12-01

    The Black Sea is a large intercontinental back-arc basin with relatively high sedimentation rate. The basin was formed as two different sub-basins divided by Mid-Black Sea Ridge. The ridge is completely buried today and the Black Sea became a single basin in the early Miocene that is currently anoxic. Recent acoustic investigations in the Black Sea indicate potential for gas hydrate formation and gas venting. A total of 2500 km multichannel seismic, Chirp sub-bottom profiler and multibeam bathymetry data were collected during three different expeditions in 2010 and 2012 along the southwestern margin of the Black Sea. Box core sediment samples were collected for gas cromatography analysis. Wide spread BSRs and multiple BSRs are observed in the seismic profiles and may be categorized into two different types: cross-cutting BSRs (transecting sedimentary strata) and amplitude BSRs (enhanced reflections). Both types mimic the seabed reflection with polarity reversal. Some undulations of the BSR are observed along seismic profiles probably caused by local pressure and/or temperature changes. Shallow gas sources and chimney vents are clearly indicated by bright reflection anomalies in the seismic data. Gas cromatography results indicate the presence of methane and various components of heavy hydrocarbons, including Hexane. These observations suggest that the gas forming hydrate in the southwestern Black Sea may originate from deeper thermogenic hydrocarbon sources. * This study is supported by 2214-A programme of The Scientific and Technological Research Council of Turkey (TÜBITAK).

  10. Air-sea fluxes and surface layer turbulence around a sea surface temperature front

    NASA Technical Reports Server (NTRS)

    Friehe, C. A.; Shaw, W. J.; Davidson, K. L.; Rogers, D. P.; Large, W. G.; Stage, S. A.; Crescenti, G. H.; Khalsa, S. J. S.; Greenhut, G. K.; Li, F.

    1991-01-01

    The observed effects of sharp changes in sea surface temperature (SST) on the air-sea fluxes, surface roughness, and the turbulence structure in the surface layer and the marine atmospheric boundary layer are discussed. In situ flux and turbulence observations were carried out from three aircraft and two ships within the FASINEX framework. Three other aircraft used remote sensors to measure waves, microwave backscatter, and lidar signatures of cloud tops. Descriptions of the techniques, intercomparison of aircraft and ship flux data, and use of different methods for analyzing the fluxes from the aircraft data are described. Changing synoptic weather on three successive days yielded cases of wind direction both approximately parallel and perpendicular to a surface temperature front. For the wind perpendicular to the front, wind over both cold-to-warm and warm-to-cold surface temperatures occurred. Model results consistent with the observations suggest that an internal boundary layer forms at the SST.

  11. Developments in Airborne Oceanography and Air-Sea Interaction

    NASA Astrophysics Data System (ADS)

    Melville, W. K.

    2014-12-01

    , just as aircraft carriers "project force". Now we can measure winds, waves, temperatures, currents, radiative transfer, images and air-sea fluxes from aircraft over the ocean.I will review some of the history of airborne oceanography and present examples of how it can extend our knowledge and understanding of air-sea interaction.

  12. Distributions and sea-to-air fluxes of nitrous oxide in the South China Sea and the West Philippines Sea

    NASA Astrophysics Data System (ADS)

    Tseng, Hsiao-Chun; Chen, Chen-Tung Arthur; Borges, Alberto V.; DelValls, T. Angel; Lai, Chao-Ming; Chen, Ting-Yu

    2016-09-01

    Approximately 600 water samples from the South China Sea (SCS) and 250 water samples from the West Philippines Sea (WPS) were collected during seven cruises from August 2003 to July 2007 to determine nitrous oxide (N2O) distributions between the surface and a maximum depth of 4250 m. In the SCS, the average surface N2O concentration exceeded the atmospheric equilibrium concentration (on average 132±23%); however in the WPS, the surface N2O concentration was lower than the atmospheric equilibrium concentration (on average 90±22%). The N2O concentration reached a maximum (~23 nmol L-1) in the WPS at 800-1000 m, and (~28 nmol L-1) at a shallower depth of around 600-800 m in the SCS, owing to vertical mixing and intensive upwelling in the SCS. In the SCS, the surface N2O concentration was 7.59±1.32 nmol L-1 and the calculated sea-to-air flux was 5.5±3.9 μmol m-2 d-1. The surface N2O concentration in the WPS, 5.19±1.26 nmol L-1, was lower than that in the SCS. The WPS is a sink for N2O and the calculated sea-to-air flux was -1.7±3.9 μmol m-2 d-1. The SCS emitted 19.3×106 mol d-1 N2O to the atmosphere and exported 8.5×106 mol d-1 N2O to the WPS during the wet season.

  13. Air-sea Interaction Influence on the MJO propagation

    NASA Astrophysics Data System (ADS)

    May, P. W.; Chen, S.; Doyle, J.; Flatau, M. K.; Schmidt, J. M.

    2012-12-01

    The Madden-Julian oscillation (MJO) is a multi-scale low frequency mode that influences the intraseasonal variability of weather across the globe. One of the outstanding forecast challenges is the large model errors in the MJO eastward propagation as it transitions from the Indian Ocean to the Maritime Continent. We will discuss the air-sea coupling impact on the MJO propagation using the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) running in an extended forecast mode on the second CINDY/DYNAMO MJO. Preliminary comparison with uncoupled forecast indicates the effect of the full ocean coupling is to damp the westward propagating modes and retrograde the eastward propagating mode. The impacts of these changes are examined through the analysis of the model sensitivity and satellite data.

  14. Satellite observations of air-sea interaction over the Kuroshio

    NASA Astrophysics Data System (ADS)

    Xie, S.; Nonaka, M.; Hafner, J.; Liu, W. T.

    2002-12-01

    Satellite microwave measurements are analyzed, revealing robust co-variability in sea surface temperature (SST) and wind speed over the Kuroshio and its Extension (KE). Ocean hydrodynamic instabilities cause the KE to meander and result into large SST variations. Increased (reduced) wind speeds are found to be associated with warm (cold) SST anomalies. This positive SST-wind correlation in KE is confirmed by in-situ buoy measurements and is consistent with a vertical shear adjustment mechanism. Namely, an increase in SST reduces the static stability of the near-surface atmosphere, intensifying the vertical turbulence mixing and bringing fast-moving air from aloft to the sea surface. South of Japan, the Kuroshio is known to vary between nearshore and offshore paths. Both paths seem semi-permanent and can persist months to years. As the Kuroshio shifts its path, coherent wind changes are detected. In particular, winds are high south of Tokyo when the Kuroshio takes the nearshore path while they are greatly reduced when this warm current leaves the coast in the offshore path. Further upstream in the East China Sea, on the warmer flank of the Kuroshio Front, there are a zone of high wind speed and a band of raining cloud due to the region's unstable atmospheric stratification near the surface. Surface wind convergence is roughly collocated with the Kuroshio Current. By increasing the baroclinicity and condensational heating, the Kuroshio Front aids the growth of the so-called Taiwan cyclone, an important winter weather phenomenon for Japan. The positive SST-wind correlation over the strong Kuroshio Current and its extension is opposite to the negative one often observed in regions of weak currents such as south of the Aleutian low that is considered to be indicative of atmosphere-to-ocean forcing.

  15. Antarctic Sea ice variations and seasonal air temperature relationships

    NASA Technical Reports Server (NTRS)

    Weatherly, John W.; Walsh, John E.; Zwally, H. J.

    1991-01-01

    Data through 1987 are used to determine the regional and seasonal dependencies of recent trends of Antarctic temperature and sea ice. Lead-lag relationships involving regional sea ice and air temperature are systematically evaluated, with an eye toward the ice-temperature feedbacks that may influence climatic change. Over the 1958-1087 period the temperature trends are positive in all seasons. For the 15 years (l973-l987) for which ice data are available, the trends are predominantly positive only in winter and summer, and are most strongly positive over the Antarctic Peninsula. The spatially aggregated trend of temperature for this latter period is small but positive, while the corresponding trend of ice coverage is small but negative. Lag correlations between seasonal anomalies of the two variables are generally stronger with ice lagging the summer temperatures and with ice leading the winter temperatures. The implication is that summer temperatures predispose the near-surface waters to above-or below-normal ice coverage in the following fall and winter.

  16. Diagnosing Air-Sea Interactions on Intraseasonal Timescales

    NASA Astrophysics Data System (ADS)

    DeMott, C. A.

    2014-12-01

    What is the role of ocean coupling in the Madden Julian Oscillation (MJO)? Consensus thinking holds that the essential physics of the MJO involve interactions between convection, atmospheric wave dynamics, and boundary layer and free troposphere moisture. However, many modeling studies demonstrate improved MJO simulation when an atmosphere-only general circulation model (AGCM) is coupled to an ocean model, so feedbacks from the ocean are probably not negligible. Assessing the importance and processes of these feedbacks is challenging for at least two reasons. First, observations of the MJO only sample the fully coupled ocean-atmosphere system; there is no "uncoupled" MJO in nature. Second, the practice of analyzing the MJO in uncoupled and coupled GCMs (CGCMs) involves using imperfect tools to study the problem. Although MJO simulation is improving in many models, shortcomings remain in both AGCMs and CGCMs, making it difficult to determine if changes brought about through coupling reflect critical air-sea interactions or are simply part of the collective idiosyncracies of a given model. For the atmosphere, ocean feedbacks from intraseasonal sea surface temperature (SST) variations are communicated through their effects on surface fluxes of heat and moisture. This presentation suggests a set of analysis tools for diagnosing the impact of an interactive ocean on surface latent and sensible heat fluxes, including their mean, variance, spectral characteristics, and phasing with respect to wind, SST, and MJO convection. The diagnostics are demonstrated with application to several CMIP5 models, and reveal a variety of responses to coupled ocean feedbacks.

  17. The fate of gas hydrates in the Barents Sea and Kara Sea region

    NASA Astrophysics Data System (ADS)

    Klitzke, Peter; Scheck-Wenderoth, Magdalena; Schicks, Judith; Luzi-Helbing, Manja; Cacace, Mauro; Jacquey, Antoine; Sippel, Judith; Faleide, Jan Inge

    2016-04-01

    The Barents Sea and Kara Sea are located in the European Arctic. Recent seismic lines indicate the presence of gas hydrates in the Barents Sea and Kara Sea region. Natural gas hydrates contain huge amounts of methane. Their stability is mainly sensitive to pressure and temperature conditions which make them susceptible for climate change. When not stable, large volumes of methane will be released in the water column and - depending on the water depth - may also be released into the atmosphere. Therefore, studying the evolution in time and space of the gas hydrates stability zone in the Barents Sea region is of interest for both environmental impact and energy production. In this study, we assess the gas hydrate inventory of the Barents Sea and Kara Sea under the light of increasing ocean bottom temperatures in the next 200 years. Thereby, we make use of an existing 3D structural and thermal model which resolves five sedimentary units, the crystalline crust and the lithospheric mantle. The sedimentary units are characterised by the prevailing lithology and porosity including effects of post-depositional erosion which strongly affect the local geothermal gradient. Governing equations for the conductive 3D thermal field and momentum balance have been integrated in a massively parallel finite-element-method based framework (MOOSE). The MOOSE framework provides a powerful and flexible platform to solve multiphysics problems implicitly on unstructured meshes. First we calculate the present-day steady-state 3D thermal field. Subsequently, we use the latter as initial condition to calculate the transient 3D thermal field for the next 200 years considering an ocean temperature model as upper boundary. Temperature and load distributions are then used to calculate the thickness of the gas hydrate stability zone for each time step. The results show that the gas hydrate stability zone strongly varies in the region due to the local geothermal gradient changes. The latter

  18. Gas diffusion through columnar laboratory sea ice: implications for mixed-layer ventilation of CO2 in the seasonal ice zone

    NASA Astrophysics Data System (ADS)

    Loose, B.; Schlosser, P.; Perovich, D.; Ringelberg, D.; Ho, D. T.; Takahashi, T.; Richter-Menge, J.; Reynolds, C. M.; McGillis, W. R.; Tison, J.-L.

    2011-02-01

    Gas diffusion through the porous microstructure of sea ice represents a pathway for ocean-atmosphere exchange and for transport of biogenic gases produced within sea ice. We report on the experimental determination of the bulk gas diffusion coefficients, D, for oxygen (O2) and sulphur hexafluoride (SF6) through columnar sea ice under constant ice thickness conditions for ice surface temperatures between -4 and -12 °C. Profiles of SF6 through the ice indicate decreasing gas concentration from the ice/water interface to the ice/air interface, with evidence for solubility partitioning between gas-filled and liquid-filled pore spaces. On average, ? was 1.3 × 10-4 cm2 s-1 (±40%) and ? was 3.9 × 10-5 cm2 s-1 (±41%). The preferential partitioning of SF6 to the gas phase, which is the dominant diffusion pathway produced the greater rate of SF6 diffusion. Comparing these estimates of D with an existing estimate of the air-sea gas transfer through leads indicates that ventilation of the mixed layer by diffusion through sea ice may be negligible, compared to air-sea gas exchange through fractures in the ice pack, even when the fraction of open water is less than 1%.

  19. Air-Sea Interaction Measurements from R/P FLIP

    NASA Astrophysics Data System (ADS)

    Friehe, C. A.

    2002-12-01

    Soon after its inception, R/P FLIP was used to study the interaction of the atmosphere and ocean due to its unique stability and low flow distortion. A number of campaigns have been conducted to measure the surface fluxes of heat, water vapor and horizontal momentum of the wind with instrumentation as used over land, supported by the Office of Naval Research and the National Science Foundation. The size of FLIP allows for simultaneous ocean wave and mixed-layer measurements as well. Air-sea interaction was a prime component of BOMEX in 1968, where FLIP transited the Panama Canal. The methods used were similar to the over-land "Kansas" experiment of AFCRL in 1968. BOMEX was followed by many experiments in the north Pacific off San Diego, northern California, and Hawaii. Diverse results from FLIP include identification of the mechanism that causes erroneous fluctuating temperature measurements in the salt-aerosol-laden marine atmosphere, the role of humidity on optical refractive index fluctuations, and identification of Miles' critical layer in the air flow over waves.

  20. GAS CHROMATOGRAPHIC TECHNIQUES FOR THE MEASUREMENT OF ISOPRENE IN AIR

    EPA Science Inventory

    The chapter discusses gas chromatographic techniques for measuring isoprene in air. Such measurement basically consists of three parts: (1) collection of sufficient sample volume for representative and accurate quantitation, (2) separation (if necessary) of isoprene from interfer...

  1. Parameterization of Sea-Spray Impact on Air-Sea Momentum and Heat Fluxes in Hurricane Prediction Models

    NASA Astrophysics Data System (ADS)

    Bao, Jian-Wen; Fairall, Chris; Michelson, Sara; Bianco, Laura

    2010-05-01

    Although it is widely recognized that sea spray under hurricane-strength winds is omnipresent in the marine surface boundary layer (MSBL), how to parameterize the effects of sea spray on the air-sea momentum and heat fluxes at hurricane-strength winds in numerical weather prediction (NWP) models still remains a subject of research. This paper focuses on how the effects of sea spray on the momentum and heat fluxes are parameterized in NWP models using the Monin-Obukhov similarity theory. In this scheme, the effects of sea spray can be considered as an additional modification to the stratification of the near surface profiles of wind, temperature and moisture in the MSBL. The overall impact of sea-spray droplets on the mean profiles of wind, temperature and moisture depends on the wind speed at the level of sea-spray generation (or wave state if available). As the wind speed increases, the droplet size increases, rendering an increase in the spray-mediated total enthalpy flux from the sea to the air and leveling off of the surface drag. When the wind is below 35 ms-1, the droplets are small in size and tend to evaporate substantially and thus cool the spray-filled layer. When the wind is above 50 ms-1, the size of droplets is so big that they do not have enough time to evaporate that much before falling back into the sea. Furthermore, the scheme includes the physics of the suspended sea-spray droplets reducing the buoyancy of the MSBL air, therefore making the surface layer more stable. Results from testing the scheme in a numerical weather prediction model are presented along with a dynamical interpretation of the impact of sea spray on the intensification of tropical cyclones.

  2. Ocean Winds and Turbulent Air-Sea Fluxes Inferred From Remote Sensing

    NASA Technical Reports Server (NTRS)

    Bourassa, Mark A.; Gille, Sarah T.; Jackson, Daren L.; Roberts, J. Brent; Wick, Gary A.

    2010-01-01

    Air-sea turbulent fluxes determine the exchange of momentum, heat, freshwater, and gas between the atmosphere and ocean. These exchange processes are critical to a broad range of research questions spanning length scales from meters to thousands of kilometers and time scales from hours to decades. Examples are discussed (section 2). The estimation of surface turbulent fluxes from satellite is challenging and fraught with considerable errors (section 3); however, recent developments in retrievals (section 3) will greatly reduce these errors. Goals for the future observing system are summarized in section 4. Surface fluxes are defined as the rate per unit area at which something (e.g., momentum, energy, moisture, or CO Z ) is transferred across the air/sea interface. Wind- and buoyancy-driven surface fluxes are called surface turbulent fluxes because the mixing and transport are due to turbulence. Examples of nonturbulent processes are radiative fluxes (e.g., solar radiation) and precipitation (Schmitt et al., 2010). Turbulent fluxes are strongly dependent on wind speed; therefore, observations of wind speed are critical for the calculation of all turbulent surface fluxes. Wind stress, the vertical transport of horizontal momentum, also depends on wind direction. Stress is very important for many ocean processes, including upper ocean currents (Dohan and Maximenko, 2010) and deep ocean currents (Lee et al., 2010). On short time scales, this horizontal transport is usually small compared to surface fluxes. For long-term processes, transport can be very important but again is usually small compared to surface fluxes.

  3. Using an air thermometer to estimate the gas constant

    NASA Astrophysics Data System (ADS)

    Kinchin, John

    2015-03-01

    The air thermometer, widely used in physics laboratories to show the relationship between volume and temperature, can also be used to obtain values for the gas constant and hence Avogadro’s number. Using a very low cost, home-made air thermometer can give surprisingly good results in a very short period of time.

  4. Air-Sea Interaction Measurements from the Controlled Towed Vehicle

    NASA Astrophysics Data System (ADS)

    Khelif, D.; Bluth, R. T.; Jonsson, H.; Barge, J.

    2014-12-01

    The Controlled Towed Vehicle (CTV) uses improved towed drone technology to actively maintain via a radar altimeter and controllable wing a user-set height that can be as low as the canonical reference height of 10 m above the sea surface. After take-off, the drone is released from the tow aircraft on a ~700-m stainless steel cable. We have instrumented the 0.23 m diameter and 2.13 m long drone with high fidelity instruments to measure the means and turbulent fluctuations of 3-D wind vector, temperature, humidity, pressure, CO2 and IR sea surface temperature. Data are recorded internally at 40 Hz and simultaneously transmitted to the tow aircraft via dedicated wireless Ethernet link. The CTV accommodates 40 kg of instrument payload and provides it with 250 W of continuous power through a ram air propeller-driven generator. Therefore its endurance is only limited by that of the tow aircraft.We will discuss the CTV development, the engineering challenges and solutions that have been successfully implemented to overcome them. We present results from recent flights as low as 9 m over the coastal ocean and comparisons of profiles and turbulent fluxes from the CTV and the tow aircraft. Manned aircraft operation at low-level boundary-layer flights is very limited. Dropsondes and UAS (Unmanned Aerial Systems) and UAS are alternates for measurements near the ocean surface. However, dropsondes have limited sensor capability and do not measure fluxes, and most present UAS vehicles do not have the payload and power capacity nor the low-flying ability in high winds over the oceans. The CTV therefore, fills a needed gap between the dropsondes, in situ aircraft, and UAS. The payload, capacity and power of the CTV makes it suitable for a variety of atmospheric research measurements. Other sensors to measure aerosol, chemistry, radiation, etc., could be readily accommodated in the CTV.

  5. Annual and seasonal fCO2 and air-sea CO2 fluxes in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Lauvset, S. K.; Chierici, M.; Counillon, F.; Omar, A.; Nondal, G.; Johannessen, T.; Olsen, A.

    2013-03-01

    The Barents Sea is the strongest CO2 sink in the Arctic region, yet estimates of the air-sea CO2 flux in this area show a large span reflecting uncertainty as well as significant variability both seasonally and regionally. Here we use a previously unpublished data set of seawater CO2 fugacity (fCO2), and map these data over the western Barents Sea through multivariable linear regressions with SeaWiFS/MODIS remote sensing and TOPAZ model data fields. We find that two algorithms are necessary in order to cover the full seasonal cycle, mainly because not all proxy variables are available for the entire year, and because variability in fCO2 is driven by different mechanisms in summer and winter. A comprehensive skill assessment indicates that there is a good overall correspondence between observations and predictions. The algorithms are also validated using two independent data sets, with good results. The gridded fCO2 fields reveal tight links between water mass distribution and fCO2 in all months, and particularly in winter. The seasonal cycle show peaks in the total air-sea CO2 influx in May and September, caused by respectively biological drawdown of CO2 and low sea ice concentration leaving a large open water area. For 2007 the annual average air-sea CO2 flux is - 48 ± 5 gC m- 2, which is comparable to previous estimates.

  6. Methods, fluxes and sources of gas phase alkyl nitrates in the coastal air.

    PubMed

    Dirtu, Alin C; Buczyńska, Anna J; Godoi, Ana F L; Favoreto, Rodrigo; Bencs, László; Potgieter-Vermaak, Sanja S; Godoi, Ricardo H M; Van Grieken, René; Van Vaeck, Luc

    2014-10-01

    The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3-C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO₂ levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor. PMID:24952420

  7. Methods, fluxes and sources of gas phase alkyl nitrates in the coastal air.

    PubMed

    Dirtu, Alin C; Buczyńska, Anna J; Godoi, Ana F L; Favoreto, Rodrigo; Bencs, László; Potgieter-Vermaak, Sanja S; Godoi, Ricardo H M; Van Grieken, René; Van Vaeck, Luc

    2014-10-01

    The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3-C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO₂ levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor.

  8. Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface

    NASA Astrophysics Data System (ADS)

    Ciuraru, Raluca; Fine, Ludovic; van Pinxteren, Manuela; D'Anna, Barbara; Herrmann, Hartmut; George, Christian

    2015-08-01

    The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitize the chemical conversion of linear saturated fatty acids at the air-water interface into unsaturated functionalized gas phase products (i.e. saturated and unsaturated aldehydes and acids, alkenes and dienes,…) which are known precursors of secondary organic aerosols. These functionalized molecules have previously been thought to be of biological origin, but here we demonstrate that abiotic interfacial photochemistry has the potential to produce such molecules. As the ocean is widely covered by the SML, this new understanding will impact on our ability to describe atmospheric chemistry in the marine environment.

  9. Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface.

    PubMed

    Ciuraru, Raluca; Fine, Ludovic; van Pinxteren, Manuela; D'Anna, Barbara; Herrmann, Hartmut; George, Christian

    2015-01-01

    The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitize the chemical conversion of linear saturated fatty acids at the air-water interface into unsaturated functionalized gas phase products (i.e. saturated and unsaturated aldehydes and acids, alkenes and dienes,...) which are known precursors of secondary organic aerosols. These functionalized molecules have previously been thought to be of biological origin, but here we demonstrate that abiotic interfacial photochemistry has the potential to produce such molecules. As the ocean is widely covered by the SML, this new understanding will impact on our ability to describe atmospheric chemistry in the marine environment. PMID:26244712

  10. Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface

    PubMed Central

    Ciuraru, Raluca; Fine, Ludovic; van Pinxteren, Manuela; D’Anna, Barbara; Herrmann, Hartmut; George, Christian

    2015-01-01

    The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitize the chemical conversion of linear saturated fatty acids at the air-water interface into unsaturated functionalized gas phase products (i.e. saturated and unsaturated aldehydes and acids, alkenes and dienes,…) which are known precursors of secondary organic aerosols. These functionalized molecules have previously been thought to be of biological origin, but here we demonstrate that abiotic interfacial photochemistry has the potential to produce such molecules. As the ocean is widely covered by the SML, this new understanding will impact on our ability to describe atmospheric chemistry in the marine environment. PMID:26244712

  11. Improvement of the GEOS-5 AGCM upon Updating the Air-Sea Roughness Parameterization

    NASA Technical Reports Server (NTRS)

    Garfinkel, C. I.; Molod, A.; Oman, L. D.; Song, I.-S.

    2011-01-01

    The impact of an air-sea roughness parameterization over the ocean that more closely matches recent observations of air-sea exchange is examined in the NASA Goddard Earth Observing System, version 5 (GEOS-5) atmospheric general circulation model. Surface wind biases in the GEOS-5 AGCM are decreased by up to 1.2m/s. The new parameterization also has implications aloft as improvements extend into the stratosphere. Many other GCMs (both for operational weather forecasting and climate) use a similar class of parameterization for their air-sea roughness scheme. We therefore expect that results from GEOS-5 are relevant to other models as well.

  12. The role of sea spray in cleansing air pollution over ocean via cloud processes.

    PubMed

    Rosenfeld, Daniel; Lahav, Ronen; Khain, Alexander; Pinsky, Mark

    2002-09-01

    Particulate air pollution has been shown to strongly suppress precipitation from convective clouds over land. New observations show that precipitation from similar polluted clouds over oceans is much less affected, because large sea salt nuclei override the precipitation suppression effect of the large number of small pollution nuclei. Raindrops initiated by the sea salt grow by collecting small cloud droplets that form on the pollution particles, thereby cleansing the air. Therefore, sea salt helps cleanse the atmosphere of the air pollution via cloud processes. This implies that over oceans, the climatic aerosol indirect effects are significantly smaller than current estimates.

  13. Improvement of the GEOS-5 AGCM upon updating the air-sea roughness parameterization

    NASA Astrophysics Data System (ADS)

    Garfinkel, C. I.; Molod, A. M.; Oman, L. D.; Song, I.-S.

    2011-09-01

    The impact of an air-sea roughness parameterization over the ocean that more closely matches recent observations of air-sea exchange is examined in the NASA Goddard Earth Observing System, version 5 (GEOS-5) atmospheric general circulation model. Surface wind biases in the GEOS-5 AGCM are decreased by up to 1.2m/s. The new parameterization also has implications aloft as improvements extend into the stratosphere. Many other GCMs (both for operational weather forecasting and climate) use a similar class of parameterization for their air-sea roughness scheme. We therefore expect that results from GEOS-5 are relevant to other models as well.

  14. Genetic type of natural gas in Ya13-1 gas field, South China Sea

    SciTech Connect

    Zhang Gang

    1995-08-01

    Ya13-1 is one of the largest gas field ever found in China in recent years. Studying on the genetic type of natural gas in the field is one of the key factors to determine the regional hydrocarbon potential--Qiongdongnan Basin and Yinggerhaii Basin, northwest part of South China Sea. Series of geochemical methods have been undertook including the analysis of the chemical composition of the natural gas and their isotopic ratio discussed in this paper. Other related studied including geological settings, gas-source correlations, geochemistry of the condensates and extractable compounds of source rocks, and thermal simulation and evaluation of the marine shales provides further informations. It is noticeable that the higher content of mercury (44000 ng/cubic meter) and aromatics such as benzene and toluene may be related to the joint of condensates, which derived from coal-bearing Oligocene shales in the adjacent Qingdingnan Basin. Studies show that the natural gas in Ya13-1 gas field belong to high to post mature non-associated gas derived in marine source rocks, and mainly come from Oligocene to Pliocene marine shales in Yinggerhai Basin. This is quite different with the former studies, which believe the gas derived from Oligocene coal-bearing strata of Yacheng formation, Qiongdongnan Basin. The new results of the studies make sure further a pretty good potential of gas resources in the northwest part ofSouth China Sea.

  15. Gas transfer under high wind and its dependence on wave breaking and sea state

    NASA Astrophysics Data System (ADS)

    Brumer, Sophia; Zappa, Christopher; Fairall, Christopher; Blomquist, Byron; Brooks, Ian; Yang, Mingxi

    2016-04-01

    Quantifying greenhouse gas fluxes on regional and global scales relies on parameterizations of the gas transfer velocity K. To first order, K is dictated by wind speed (U) and is typically parameterized as a non-linear functions of U. There is however a large spread in K predicted by the traditional parameterizations at high wind speed. This is because a large variety of environmental forcing and processes (Wind, Currents, Rain, Waves, Breaking, Surfactants, Fetch) actually influence K and wind speed alone cannot capture the variability of air-water gas exchange. At high wind speed especially, breaking waves become a key factor to take into account when estimating gas fluxes. The High Wind Gas exchange Study (HiWinGS) presents the unique opportunity to gain new insights on this poorly understood aspects of air-sea interaction under high winds. The HiWinGS cruise took place in the North Atlantic during October and November 2013. Wind speeds exceeded 15 m s‑1 25% of the time, including 48 hrs with U10 > 20 m s‑1. Continuous measurements of turbulent fluxes of heat, momentum, and gas (CO2, DMS, acetone and methanol) were taken from the bow of the R/V Knorr. The wave field was sampled by a wave rider buoy and breaking events were tracked in visible imagery was acquired from the port and starboard side of the flying bridge during daylight hours at 20Hz. Taking advantage of the range of physical forcing and wave conditions sampled during HiWinGS, we test existing parameterizations and explore ways of better constraining K based on whitecap coverage, sea state and breaking statistics contrasting pure windseas to swell dominated periods. We distinguish between windseas and swell based on a separation algorithm applied to directional wave spectra for mixed seas, system alignment is considered when interpreting results. The four gases sampled during HiWinGS ranged from being mostly waterside controlled to almost entirely airside controlled. While bubble-mediated transfer

  16. Gas transfer under high wind and its dependence on wave breaking and sea state

    NASA Astrophysics Data System (ADS)

    Brumer, Sophia; Zappa, Christopher; Fairall, Christopher; Blomquist, Byron; Brooks, Ian; Yang, Mingxi

    2016-04-01

    Quantifying greenhouse gas fluxes on regional and global scales relies on parameterizations of the gas transfer velocity K. To first order, K is dictated by wind speed (U) and is typically parameterized as a non-linear functions of U. There is however a large spread in K predicted by the traditional parameterizations at high wind speed. This is because a large variety of environmental forcing and processes (Wind, Currents, Rain, Waves, Breaking, Surfactants, Fetch) actually influence K and wind speed alone cannot capture the variability of air-water gas exchange. At high wind speed especially, breaking waves become a key factor to take into account when estimating gas fluxes. The High Wind Gas exchange Study (HiWinGS) presents the unique opportunity to gain new insights on this poorly understood aspects of air-sea interaction under high winds. The HiWinGS cruise took place in the North Atlantic during October and November 2013. Wind speeds exceeded 15 m s-1 25% of the time, including 48 hrs with U10 > 20 m s-1. Continuous measurements of turbulent fluxes of heat, momentum, and gas (CO2, DMS, acetone and methanol) were taken from the bow of the R/V Knorr. The wave field was sampled by a wave rider buoy and breaking events were tracked in visible imagery was acquired from the port and starboard side of the flying bridge during daylight hours at 20Hz. Taking advantage of the range of physical forcing and wave conditions sampled during HiWinGS, we test existing parameterizations and explore ways of better constraining K based on whitecap coverage, sea state and breaking statistics contrasting pure windseas to swell dominated periods. We distinguish between windseas and swell based on a separation algorithm applied to directional wave spectra for mixed seas, system alignment is considered when interpreting results. The four gases sampled during HiWinGS ranged from being mostly waterside controlled to almost entirely airside controlled. While bubble-mediated transfer

  17. Gas Bubble Disease in the Brain of a Living California Sea Lion (Zalophus californianus)

    PubMed Central

    Van Bonn, William; Dennison, Sophie; Cook, Peter; Fahlman, Andreas

    2013-01-01

    A yearling California sea lion (Zalophus californianus) was admitted into rehabilitation with signs of cerebellar pathology. Diagnostic imaging that included radiography and magnetic resonance imaging (MRI) demonstrated space-occupying lesions predominantly in the cerebellum that were filled partially by CSF-like fluid and partially by gas, and cerebral lesions that were fluid filled. Over a maximum period of 4 months, the brain lesions reduced in size and the gas resorbed and was replaced by CSF-like fluid. In humans, the cerebellum is known to be essential for automating practiced movement patterns (e.g., learning to touch-type), also known as procedural learning or the consolidation of “motor memory.” To test the animal in this study for motor memory deficits, an alternation task in a two-choice maze was utilized. The sea lion performed poorly similar to another case of pneumocerebellum previously reported, and contrary to data acquired from a group of sea lions with specific hippocampal injury. The learning deficits were attributed to the cerebellar injury. These data provide important insight both to the clinical presentation and behavioral observations of cerebellar injury in sea lions, as well as providing an initial model for long-term outcome following cerebellar injury. The specific etiology of the gas could not be determined. The live status of the patient with recovery suggests that the most likely etiologies for the gas are either de novo formation or air emboli secondary to trauma. A small air gun pellet was present within and was removed from soft tissues adjacent to the tympanic bulla. While no evidence to support the pellet striking bone was found, altered dive pattern associated with this human interaction may have provided the opportunity for gas bubble formation to occur. The similarity in distribution of the gas bubble related lesions in this case compared with another previously published case of pneumocerebellum suggests that

  18. Occurrence and air-seawater exchange of brominated flame retardants and Dechlorane Plus in the North Sea

    NASA Astrophysics Data System (ADS)

    Möller, Axel; Xie, Zhiyong; Caba, Armando; Sturm, Renate; Ebinghaus, Ralf

    2012-01-01

    The occurrence, spatial and seasonal concentration variations in air and seawater and the air-seawater exchange of polybrominated diphenyl ethers (PBDEs), alternate brominated flame retardants (BFRs) and Dechlorane Plus (DP) were studied in the German part of the North Sea in 2010. BDE-209 and DP were found to be the dominating compounds, both in the atmosphere and in seawater. Sum PBDEs (∑ 10PBDEs) ranged from 0.31 to 10.7 pg m -3 in the atmosphere and from not detected (n.d.) to 10.5 pg L -1 in seawater, respectively. DP ranged from 0.13 to 22.3 pg m -3 and from 0.10 to 17.7 pg L -1 in air and seawater, respectively. Besides, four other BFRs including hexabromobenzene (HBB) and pentabromobenzene (PBBz) were detected. Elevated atmospheric concentrations were observed in continentally influenced air masses while highest seawater concentrations were observed at sampling stations close to the coast influenced by riverine discharge. The ratio of the two DP stereoisomers both in air and water was found to be close to the technical mixture at high concentrations but changed at lower concentrations giving first evidence for the alteration within the aquatic environment. Both dry air-seawater gas exchange and dry deposition are input pathways of BFRs and DP in the North Sea besides riverine discharge.

  19. Combustion gas properties. Part 3: Hydrogen gas fuel and dry air

    NASA Technical Reports Server (NTRS)

    Wear, J. D.; Jones, R. E.; Mcbride, B. J.; Beyerle, R. A.

    1985-01-01

    A series of computations has been made to produce the equilibrium temperature and gas composition for hydrogen gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only sample tables and figures are provided in this report.

  20. Noble gas tracers of ventilation during deep-water formation in the Weddell Sea

    NASA Astrophysics Data System (ADS)

    Nicholson, D. P.; Khatiwala, S.; Heimbach, P.

    2016-05-01

    To explore the dynamics and implications of incomplete air-sea equilibration during the formation of abyssal water masses, we simulated noble gases in the Estimating the Circulation & Climate of the Ocean (ECCO) global ocean state estimate. A novel computation approach utilizing a matrix-free Newton-Krylov (MFNK) scheme was applied to quickly compute the periodic seasonal solutions for noble gas tracers. MFNK allows for quick computation of a cyclo-stationary solution for tracers (i.e., a spun-up, repeating seasonal cycle), which would otherwise be computationally infeasible due to the long time scale of dynamic adjustment of the abyssal ocean (1000’s of years). A suite of experiments isolates individual processes, including atmospheric pressure effects, the solubility pump and air-sea bubble fluxes. In addition to these modeled processes, a volumetric contribution of 0.28 ± 0.07% of glacial melt water is required to reconcile deep-water observations in the Weddell Sea. Another primary finding of our work is that the saturation anomaly of heavy noble gases in model simulations is in excess of two-fold more negative than is suggested from Weddell Sea observations. This result suggests that model water masses are insufficiently ventilated prior to subduction and thus there is insufficient communication between atmosphere and ocean at high latitudes. The discrepancy between noble gas observations and ECCO simulations highlights that important inadequacies remain in how we model high-latitude ventilation with large implications for the oceanic uptake and storage of carbon.

  1. Air-sea CO2 fluxes measured by eddy covariance in a coastal station in Baja California, México

    NASA Astrophysics Data System (ADS)

    Gutiérrez-Loza, L.; Ocampo-Torres, F. J.

    2016-05-01

    The influence of wave-associated parameters controlling turbulent CO2 fluxes through the air-sea water interface is evaluated in a coastal region. The study area, located within the Todos Santos Bay, Baja California, México, was found to be a weak sink of CO2 with a mean flux of -1.32 µmol m-2s-1. The low correlation found between flux and wind speed (r = 0.09), suggests that the influence of other forcing mechanisms, besides wind, is important for gas transfer modulation through the sea surface, at least for the conditions found in this study. In addition, the results suggest that for short periods where an intensification of the wave conditions occurs, a CO2 flux response increases the transport of gas to the ocean.

  2. North Sea gas plants get process, scheduling tools

    SciTech Connect

    Mortimer, A.

    1998-11-16

    Mobil North Sea Ltd. has installed an operator guidance tool at its SAGE gas-processing plant at St. Fergus, Scotland (SAGE: Scottish Area Gas Evacuation). The system, supplied by MDC Technology, Teesside, U.K., will aid process decision making at the plant under MDC Technology`s RTO+ software. In addition, Shell U.K. Exploration and Production (Shell Expro) has installed a pipeline-scheduling system, also supplied by MDC Technology, at its Aberdeen control center. The system aids gas-movement scheduling through Shell Expro`s St. Fergus gas plant. The Northern Systems and Plant Scheduling (NSPS) system integrates MDC Technology`s RTO+ package with Microsoft Visual Basic and Excel. Mobil`s SAGE gas terminal at St. Fergus has two identical process trains (NGL recovery and acid-gas treatment), each with a capacity of 16.25 million std. cu m/day. The paper describes the guidance tool, the scheduling aid, and the installation of the NSPS.

  3. Airborne Measurements of Emissions from Oil and Gas Exploration and Production Activities in the Norwegian Sea

    NASA Astrophysics Data System (ADS)

    Kim, J.; Roiger, A.; Raut, J.; Rose, M.; Weinzierl, B.; Reiter, A.; Thomas, J. L.; Marelle, L.; Law, K.; Schlager, H.

    2013-12-01

    A rapid decline of Arctic sea ice is expected to promote hydrocarbon extraction in the Arctic, which in turn will increase emissions of atmospheric pollutants. To investigate impacts of different pollution sources on the Arctic atmosphere, an aircraft campaign based in northern Norway was conducted in July 2012, as a part of the EU ACCESS (Arctic Climate Change Economy and Society) project. One of the flights focused on measuring emissions from various oil/gas exploration and production facilities ~110 km south of the Arctic Circle in the Norwegian Sea. Fresh and aged (from 5 minutes to 2.5 hours old) exhaust plumes from oil/gas production platforms, drilling rigs and tankers were probed with extensive aerosol and trace gas instrumentations. It was found that different types of facilities emit plumes with distinct chemical compositions. For example, tanker plumes were characterized by high SO2 concentration and high fraction of non-volatile particles while plumes from oil/gas production platforms showed significant increase in the nucleation mode particle concentration. Drilling rigs were found to be high black carbon emitters. In addition to the fresh plumes, relatively aged plumes (1.5 - 2.5 hours old) from a facility under development were measured. Even in these aged plumes, total particle concentrations were more than 6 times higher than the background concentration. Therefore, emissions from oil and gas activities are expected to have a significant impact on local air quality and atmospheric composition. With the aid of FLEXPART-WRF (a Lagrangian dispersion model) simulations, the results of this study will be used to validate and improve current emission inventories. In the future, these improved emission inventories can be used in regional and global chemical transport models to more accurately predict future Arctic air pollution.

  4. Commercial air travel after intraocular gas injection.

    PubMed

    Houston, Stephen; Graf, Jürgen; Sharkey, James

    2012-08-01

    Passengers with intraocular gas are at risk of profound visual loss when exposed to reduced absolute pressure within the cabin of a typical commercial airliner. Information provided on the websites of the world's 10 largest airlines offer a considerable range of opinion as to when it might be safe to fly after gas injection. Physicians responsible for clearing pseassengers as 'fit to fly' should be aware modern retinal surgical techniques increasingly employ long-acting gases as vitreous substitutes. The kinetics of long-acting intraocular gases must be considered when deciding how long after surgery it is safe to travel. It is standard practice to advise passengers not to fly in aircraft until the gas is fully resorbed. To achieve this, it may be necessary to delay travel for approximately 2 wk after intraocular injection of sulfur hexafluoride (SF6) and for 6 wk after injection of perfluoropropane (C3F8).

  5. Commercial air travel after intraocular gas injection.

    PubMed

    Houston, Stephen; Graf, Jürgen; Sharkey, James

    2012-08-01

    Passengers with intraocular gas are at risk of profound visual loss when exposed to reduced absolute pressure within the cabin of a typical commercial airliner. Information provided on the websites of the world's 10 largest airlines offer a considerable range of opinion as to when it might be safe to fly after gas injection. Physicians responsible for clearing pseassengers as 'fit to fly' should be aware modern retinal surgical techniques increasingly employ long-acting gases as vitreous substitutes. The kinetics of long-acting intraocular gases must be considered when deciding how long after surgery it is safe to travel. It is standard practice to advise passengers not to fly in aircraft until the gas is fully resorbed. To achieve this, it may be necessary to delay travel for approximately 2 wk after intraocular injection of sulfur hexafluoride (SF6) and for 6 wk after injection of perfluoropropane (C3F8). PMID:22872998

  6. The Relation Between Wind Speed and Air-Sea Temperature Difference in the Marine Atmospheric Boundary Layer off Northwest Europe

    NASA Astrophysics Data System (ADS)

    Kettle, A. J.

    2014-12-01

    Wind speed and atmospheric stability have an important role in determining the turbulence in the marine atmospheric boundary layer (MABL) as well as the surface wave field. The understanding of MABL dynamics in northwest Europe is complicated by fetch effects, the proximity of coastlines, shallow topography, and larger scale circulation patterns (e.g., cold air outbreaks). Numerical models have difficulty simulating the marine atmospheric boundary layer in coastal areas and partially enclosed seas, and this is partly due to spatial resolution problems at coastlines. In these offshore environments, the boundary layer processes are often best understood directly from time series measurements from fixed platforms or buoys, in spite of potential difficulties from platform flow distortion as well as the spatial sparseness of the data sets. This contribution presents the results of time series measurements from offshore platforms in the North Sea and Norwegian Sea in terms of a summary diagnostic - wind speed versus air-sea temperature difference (U-ΔT) - with important implications for understanding atmospheric boundary layer processes. The U-ΔT diagram was introduced in earlier surveys of data from coastal (Sletringen; O.J. Andersen and J. Løvseth, J. Wind Eng. Ind. Aerodyn., 57, 97-109, 1995) and offshore (Statfjord A; K.J. Eidsvik, Boundary-Layer Meteorol., 32, 103-132, 1985) sites in northwest Europe to summarize boundary layer conditions at a given location. Additional information from a series of measurement purpose-built offshore measurement and oil/gas production platforms from the southern North Sea to the Norwegian Sea illustrates how the wind characteristics vary spatially over large distances, highlighting the influence of cold air outbreaks, in particular. The results are important for the offshore wind industry because of the way that wind turbines accrue fatigue damage in different conditions of atmospheric stability and wind speed.

  7. DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS

    SciTech Connect

    Noonkester, J.; Jackson, D.; Jones, W.; Hyde, W.; Kohn, J.; Walker, R.

    2012-09-20

    Soil vapor extraction (SVE) and air injection well testing was performed at the Dynamic Underground Stripping (DUS) site located near the M-Area Settling Basin (referred to as DUS II in this report). The objective of this testing was to determine the effectiveness of continued operation of these systems. Steam injection ended on September 19, 2009 and since this time the extraction operations have utilized residual heat that is present in the subsurface. The well testing campaign began on June 5, 2012 and was completed on June 25, 2012. Thirty-two (32) SVE wells were purged for 24 hours or longer using the active soil vapor extraction (ASVE) system at the DUS II site. During each test five or more soil gas samples were collected from each well and analyzed for target volatile organic compounds (VOCs). The DUS II site is divided into four parcels (see Figure 1) and soil gas sample results show the majority of residual VOC contamination remains in Parcel 1 with lesser amounts in the other three parcels. Several VOCs, including tetrachloroethylene (PCE) and trichloroethylene (TCE), were detected. PCE was the major VOC with lesser amounts of TCE. Most soil gas concentrations of PCE ranged from 0 to 60 ppmv with one well (VEW-22A) as high as 200 ppmv. Air sparging (AS) generally involves the injection of air into the aquifer through either vertical or horizontal wells. AS is coupled with SVE systems when contaminant recovery is necessary. While traditional air sparging (AS) is not a primary component of the DUS process, following the cessation of steam injection, eight (8) of the sixty-three (63) steam injection wells were used to inject air. These wells were previously used for hydrous pyrolysis oxidation (HPO) as part of the DUS process. Air sparging is different from the HPO operations in that the air was injected at a higher rate (20 to 50 scfm) versus HPO (1 to 2 scfm). . At the DUS II site the air injection wells were tested to determine if air sparging affected

  8. The origin of gas seeps and shallow gas in northern part of South China Sea

    NASA Astrophysics Data System (ADS)

    Li, M.; Jin, X.

    2003-04-01

    The northern part of South China Sea is of passive continental margin, which geologic units include shelf, slope and deep sea basin. There are rifting basins forming during Paleogene (or Cretaceous ?) to Quaternary developed on shelf and slope, which sediments are dominated by fluvial and lake clastic rock of Paleogene, and marine clastic rock and carbonate of Neogene - Quaternary. The main basins include the Pearl River Mouth Basin, Beibu Gulf basin, Qiongdongnan Basin and Yinggehai basin. They contain rich oil and gas resources, and have become important industrial oil and gas producing region in South China Sea. With the increasing of petroleum exploration actives and marine petroleum engineering, it has been paid more attention to the investigation and research of gas seeps and shallow gas, for they become a potential threaten to the marine engineering while they are regarded as the indicators of industrial oil and gas. By study the distribution and geochemical characteristics of gas seeps in northeast part of Yinggehai basin and shallow gas in sediments on slope, combined with their regional geologic background, this paper deals with the origin, migration pathway and emission mechanism of gas seeps and shallow gas in northern part of South China Sea, for providing a base knowledge for the evaluation of marine engineering geology. In northeast part of Yinggehai basin gas seeps have been found and recorded for near 100 years. During 1990s, as a part of petroleum exploration, the gas seeps in the basin have been investigated and research by oil companies (Baojia Huang et al., 1992; Jiaqiong He et al., 2000). Gas seeps were found in shallow water area along southwest coast of Hainan Island, water depth usually less than 50 m. The occurrence of gas seeps can be divided into two types: (1) gas continuously emission, continuous gas bubbles groups can be detected by sonar underwater and observed on water surface. (2) gas intermittently emission, the time intervals

  9. Detection of hydrogen chloride gas in air

    NASA Technical Reports Server (NTRS)

    Gregory, G. L.

    1978-01-01

    Launch vehicle effluent (LVE) monitoring is part of NASA's overall tropospheric and stratospheric environmental program. Following nine techniques are evaluated and developed in report: bubbler method, pH measurements, indicator tubes, microcoulometers, modified condensation nuclei counter, dual-isotope absorption, gas-filter correlation, chemiluminescent nitric oxide detection, chemiluminescent luminol-oxidation detection.

  10. Shallow gas in Cenozoic sediments of the Southern North Sea

    NASA Astrophysics Data System (ADS)

    Trampe, Anna F.; Lutz, Rüdiger; Franke, Dieter; Thöle, Hauke; Arfai, Jashar

    2013-04-01

    Shallow petroleum systems in the southern North Sea are known for several decades but they were not actively explored for a long time. In recent years these unconventional shallow petroleum systems are studied in greater detail and one shallow gas field (A-12) is in production in the Netherlands. Additionally, oil was encountered in Miocene sandstones in the southern Danish North Sea (Lille John well) just north of the Danish-German border. Seismic amplitude anomalies are an indication for hydrocarbons in sediments. Therefore we have mapped the occurrence of seismic amplitude anomalies in the German North Sea based on more than 25.000 km of 2D seismic data and around 4.000 km2 of 3D seismic data. Amplitude anomalies are ubiquitous phenomena in the study area. These anomalies are not only caused by hydrocarbons but also by changing lithologies e.g. peat or fluid migration. Therefore several classes of seismic anomalies, e.g. bright spots, chimneys, blanking areas and velocity pull-down were mapped. Examples for these classes were studied with AVO (amplitude variation with offset) analyses to verify the existence or non-existence of gas in the sediments. Shallow gas can be produced and transported through the dense pipeline grid of the southern and central North Sea or it could be burned offshore close to wind parks in small power plants and the electric energy then transported through the existing power connections of the wind parks. Thus enabling a continuous energy supply during calm wind periods. This study is carried out within the framework of the project "Geoscientific Potential of the German North Sea (GPDN)" in which the Cenozoic sedimentary system was mapped in great detail. A detailed model of delta evolution (Baltic river system) was developed which serves as a structural framework. The studied interval is time equivalent to the Utsira formation which is used offshore Norway for sequestration of CO2. These different possibilities of using or exploiting

  11. Dynamics and impacts of eddy-driven air-sea interaction in a regional air-sea coupled model for the US West Coast

    NASA Astrophysics Data System (ADS)

    Seo, H.; Miller, A. J.; Norris, J. R.

    2015-12-01

    The US West Coast coastal oceans feature energetic mesoscale eddies. The associated sea surface temperature (SST) and surface current modify the wind stress, leading to significant dynamic feedback on to the air-sea coupled system. Dynamics of the interaction and impacts on the regional coastal climate are however not well understood; this is an important research question for regional modeling studies for the coastal climate. A high-resolution (7km) SCOAR regional air-sea coupled climate model is used to investigate this question by implementing a novel model coupling technique that separates spatial scale of air-sea interaction. It allows the large-scale coupling effect to be preserved while suppressing the eddy-driven coupling via interactive spatial smoothing of SST and surface current. When the eddy-induced surface current is allowed to modify the wind stress, the eddy kinetic energy (EKE) is reduced by 42%, and this is primarily due to enhanced surface eddy drag. In contrast, the eddy-induced SST-wind coupling has little impact on the EKE. Eddies also modify the Ekman pumping; the resultant Ekman pumping velocity due to surface current attenuates the amplitude of eddies while the SST-induced Ekman pumping affects the propagation of eddies. Rectified change in time-mean SST is determined by the altered offshore temperature advection by the mean and eddy currents, but the magnitude of the mean SST change is greater with the eddy-induced current effect. The subsequent influence on the downstream winter rainfall variability on the US West Coast is stronger with the eddy-induced SST effect because of the proximity of SST anomalies to the coasts. The strong dynamical response in the coastal climate system to the eddy-driven air-sea interaction suggests that the fine-scale air-sea coupling should be better represented in the regional climate modeling studies for the coastal environments and the marine weather.

  12. Horizontal air drilling increases gas recovery in depleted zone

    SciTech Connect

    Elrod, J.P.

    1997-06-30

    Increased gas recoveries in depleted gas zones can be achieved through horizontal air drilling. In December 1995, OXY USA Inc. drilled the Pirkle 2, the first air-drilled horizontal well in the Carthage field of Texas. Targeting the Cretaceous Frost ``A`` zone of the lower Pettit limestone at 6,000 ft true vertical depth, the well established production in a 1,400 ft lateral section with a bottom hole pressure (BHP) of 185 psi. The initial BHP for the zone was 3,280 psi in 1942. As of April 27, 1997, the Pirkle 2 had produced 530 MMcf of gas at a rate of 1.1 MMcfd. Total cumulative gas production for the lower Pettit limestone in the Carthage field was 3.83 tcf as of January 1997. The paper discusses reservoir properties, abandonment pressure, minimizing well bore damage, drilling fluid selection, special equipment and modifications, compressors, BOPs, steering tools, drilling, completion, and production.

  13. Air Monitoring for Hazardous Gas Detection

    NASA Technical Reports Server (NTRS)

    Arkin, C. Richard; Griffin, Timothy P.; Adams, Frederick W.; Naylor, Guy; Haskell, William; Floyd, David; Curley, Charles; Follistein, Duke W.

    2004-01-01

    The Hazardous Gas Detection Lab (HGDL) at Kennedy Space Center is involved in the design and development of instrumentation that can detect and quantify various hazardous gases. Traditionally these systems are designed for leak detection of the cryogenic gases used for the propulsion of the Shuttle and other vehicles. Mass spectrometers are the basis of these systems, which provide excellent quantitation, sensitivity, selectivity, response times and detection limits. A Table lists common gases monitored for aerospace applications. The first five gases, hydrogen, helium, nitrogen, oxygen, and argon are historically the focus of the HGDL.

  14. Hydrogen-air energy storage gas-turbine system

    NASA Astrophysics Data System (ADS)

    Schastlivtsev, A. I.; Nazarova, O. V.

    2016-02-01

    A hydrogen-air energy storage gas-turbine unit is considered that can be used in both nuclear and centralized power industries. However, it is the most promising when used for power-generating plants based on renewable energy sources (RES). The basic feature of the energy storage system in question is combination of storing the energy in compressed air and hydrogen and oxygen produced by the water electrolysis. Such a process makes the energy storage more flexible, in particular, when applied to RES-based power-generating plants whose generation of power may considerably vary during the course of a day, and also reduces the specific cost of the system by decreasing the required volume of the reservoir. This will allow construction of such systems in any areas independent of the local topography in contrast to the compressed-air energy storage gas-turbine plants, which require large-sized underground reservoirs. It should be noted that, during the energy recovery, the air that arrives from the reservoir is heated by combustion of hydrogen in oxygen, which results in the gas-turbine exhaust gases practically free of substances hazardous to the health and the environment. The results of analysis of a hydrogen-air energy storage gas-turbine system are presented. Its layout and the principle of its operation are described and the basic parameters are computed. The units of the system are analyzed and their costs are assessed; the recovery factor is estimated at more than 60%. According to the obtained results, almost all main components of the hydrogen-air energy storage gas-turbine system are well known at present; therefore, no considerable R&D costs are required. A new component of the system is the H2-O2 combustion chamber; a difficulty in manufacturing it is the necessity of ensuring the combustion of hydrogen in oxygen as complete as possible and preventing formation of nitric oxides.

  15. Bayesian Hierarchical Air-Sea Interaction Modeling: Application to the Labrador Sea

    NASA Technical Reports Server (NTRS)

    Niiler, Pearn P.

    2002-01-01

    The objectives are to: 1) Organize data from 26 MINIMET drifters in the Labrador Sea, including sensor calibration and error checking of ARGOS transmissions. 2) Produce wind direction, barometer, and sea surface temperature time series. In addition, provide data from historical file of 150 SHARP drifters in the Labrador Sea. 3) Work with data interpretation and data-modeling assimilation issues.

  16. [Levels and sources of gaseous polybrominated diphenyl ethers in air over the northern South China Sea].

    PubMed

    Li, Qi-lu; Li, Jun; Liu, Xiang; Xu, Wei-hai; Zhang, Gan

    2012-08-01

    A total of 32 air samples collected during a Shiyan III voyage over the northern South China Sea (SCS) were analyzed for polybrominated diphenyl ethers (PBDEs) by gas chromatography/mass spectrometry. The concentrations of sigma 7 PBDEs ranged from 0.07 to 35.9 pg x m(-3). The sigma 7 PBDEs were dominated by tetra-(BDE-47) and penta-(BDE-99 and -100) components, which accounted for 51.5% and 36.9%, respectively. This result indicated that the widely used commercial penta-BDE product was the original source. The higher concentrations of PBDEs were monitored close to the coastline of the South China and Philippine, while the lower concentrations were found over the SCS adjacent to central coast of Vietnam. Back trajectory analysis showed that the high PBDE concentrations observed in air over the northern SCS may be related to the continental pollutant outflows from the southeast coast of China, especially the Pearl River Delta, Taiwan and Philippine, by prevailing northeast wind transport.

  17. Determination of methane in ambient air by multiplex gas chromatography

    NASA Technical Reports Server (NTRS)

    Valentin, J. R.; Carle, G. C.; Phillips, J. B.

    1985-01-01

    A multiplex gas chromatographic technique for the determination of methane in ambient air over extended periods is reported. A modest gas chromatograph which uses air as the carrier gas was modified by adding a silver oxide sample modulator for multiplex operation. The modulator selectively catalyzes the decomposition of methane in air. The resulting analytical system requires no consumables beyond power. A profile of the methane concentration in this laboratory was obtained for an 8-day period. During this period, methane concentration varied with an approximately daily period from a low of 1.53 + or - 0.60 ppm to a high of 4.63 + or - 0.59 ppm over the entire 8 days. Some of the measured concentrations are higher than those reported elsewhere indicating the presence of some local source or sources for methane. This work has demonstrated the utility of a relatively simple multiplex gas chromatograph for the analysis of environmental samples. The technique should be applicable to other trace components in air through use of other selective modulators.

  18. Determination of methane in ambient air by multiplex gas chromatography.

    PubMed

    Valentin, J R; Carle, G C; Phillips, J B

    1985-05-01

    A multiplex gas chromatographic technique for the determination of methane in ambient air over extended periods is reported. A modest gas chromatograph which uses air as the carrier gas was modified by adding a silver oxide sample modulator for multiplex operation. The modulator selectively catalyzes the decomposition of methane in air. The resulting analytical systems requires no consumables beyond power. A profile of the methane concentration in this laboratory was obtained for an 8-day period. During this period, methane concentration varied with an approximately daily period from a low of 1.53 +/- 0.60 ppm to a high of 4.63 +/- 0.59 ppm over the entire 8 days. Some of the measured concentrations are higher than those reported elsewhere indicating the presence of some local source or sources for methane. This work has demonstrated the utility of a relatively simple multiplex gas chromatograph for the analysis of environmental samples. The technique should be applicable to other trace components in air through use of other selective modulators. PMID:11536559

  19. Influence of precipitation on the CO2 air-sea flux, an eddy covariance field study

    NASA Astrophysics Data System (ADS)

    Zavarsky, Alexander; Steinhoff, Tobias; Marandino, Christa

    2016-04-01

    During the SPACES-OASIS cruise (July-August 2015) from Durban, SA to Male, MV direct fluxes of CO2 and dimethyl sulfide (DMS) were measured using the eddy covariance (EC) technique. The cruise covered areas of sources and sinks for atmospheric CO2, where the bulk concentration gradient measurements resembled the Takahashi (2009) climatology. Most of the time, bulk CO2 fluxes (F=k* [cwater-cair]), calculated with the parametrization (k) by Nightingale et al. 2000, were in general agreement with direct EC measurements. However, during heavy rain events, the directly measured CO2 fluxes were 4 times higher than predicted. It has been previously described that rain influences the k parametrization of air-sea gas exchange, but this alone cannot explain the measured discrepancy. There is evidence that freshwater input and a change in the carbonate chemistry causes the water side concentration of ?c=cwater-cair to decrease. Unfortunately this cannot be detected by most bulk measurement systems. Using the flux measurements of an additional gas like DMS, this rain influence can be evaluated as DMS does not react to changes in the carbonate system and has a different solubility. A pending question is if the enhanced flux of CO2 in the ocean is sequestered into the ocean mixed layer and below. This question will be tackled using the GOTM model to understand the implications for the global carbon cycle.

  20. Air quality concerns of unconventional oil and natural gas production.

    PubMed

    Field, R A; Soltis, J; Murphy, S

    2014-05-01

    Increased use of hydraulic fracturing ("fracking") in unconventional oil and natural gas (O & NG) development from coal, sandstone, and shale deposits in the United States (US) has created environmental concerns over water and air quality impacts. In this perspective we focus on how the production of unconventional O & NG affects air quality. We pay particular attention to shale gas as this type of development has transformed natural gas production in the US and is set to become important in the rest of the world. A variety of potential emission sources can be spread over tens of thousands of acres of a production area and this complicates assessment of local and regional air quality impacts. We outline upstream activities including drilling, completion and production. After contrasting the context for development activities in the US and Europe we explore the use of inventories for determining air emissions. Location and scale of analysis is important, as O & NG production emissions in some US basins account for nearly 100% of the pollution burden, whereas in other basins these activities make up less than 10% of total air emissions. While emission inventories are beneficial to quantifying air emissions from a particular source category, they do have limitations when determining air quality impacts from a large area. Air monitoring is essential, not only to validate inventories, but also to measure impacts. We describe the use of measurements, including ground-based mobile monitoring, network stations, airborne, and satellite platforms for measuring air quality impacts. We identify nitrogen oxides, volatile organic compounds (VOC), ozone, hazardous air pollutants (HAP), and methane as pollutants of concern related to O & NG activities. These pollutants can contribute to air quality concerns and they may be regulated in ambient air, due to human health or climate forcing concerns. Close to well pads, emissions are concentrated and exposure to a wide range of

  1. Air quality concerns of unconventional oil and natural gas production.

    PubMed

    Field, R A; Soltis, J; Murphy, S

    2014-05-01

    Increased use of hydraulic fracturing ("fracking") in unconventional oil and natural gas (O & NG) development from coal, sandstone, and shale deposits in the United States (US) has created environmental concerns over water and air quality impacts. In this perspective we focus on how the production of unconventional O & NG affects air quality. We pay particular attention to shale gas as this type of development has transformed natural gas production in the US and is set to become important in the rest of the world. A variety of potential emission sources can be spread over tens of thousands of acres of a production area and this complicates assessment of local and regional air quality impacts. We outline upstream activities including drilling, completion and production. After contrasting the context for development activities in the US and Europe we explore the use of inventories for determining air emissions. Location and scale of analysis is important, as O & NG production emissions in some US basins account for nearly 100% of the pollution burden, whereas in other basins these activities make up less than 10% of total air emissions. While emission inventories are beneficial to quantifying air emissions from a particular source category, they do have limitations when determining air quality impacts from a large area. Air monitoring is essential, not only to validate inventories, but also to measure impacts. We describe the use of measurements, including ground-based mobile monitoring, network stations, airborne, and satellite platforms for measuring air quality impacts. We identify nitrogen oxides, volatile organic compounds (VOC), ozone, hazardous air pollutants (HAP), and methane as pollutants of concern related to O & NG activities. These pollutants can contribute to air quality concerns and they may be regulated in ambient air, due to human health or climate forcing concerns. Close to well pads, emissions are concentrated and exposure to a wide range of

  2. Subseafloor to Sea-Air Interface Characterization of Methane Dynamics in the northern US Atlantic Margin Seep Province

    NASA Astrophysics Data System (ADS)

    Ruppel, C. D.; Kluesner, J.; Danforth, W. W.; Casso, M.; Pohlman, J.

    2015-12-01

    Since the discovery of hundreds of northern US Atlantic margin (USAM) cold seeps in 2012 and 2013, the USGS Gas Hydrates Project has undertaken intensive studies of the along-margin gas hydrate/free gas distribution, the plumbing systems sustaining seeps, seafloor gas emissions, and sea-air methane flux. Interest in the USAM is motivated both by climate change (i.e., documented ocean warming may contribute to seepage) and energy resource (i.e., the amount of gas-in-place in hydrates on the USAM is about the same as that in the northern Gulf of Mexico) issues. USGS-led field efforts have included an April 2015 study to acquire high-resolution multichannel seismic data, coincident split-beam water column methane plume imaging data, and real-time sea-air methane flux measurements between Wilmington and Norfolk Canyons and a September 2015 cruise (with OSU, UCLA, and Geomar) to collect piston cores, multicores, heat flow data, subbottom imagery, CTDs, and coincident water column imagery from Block Canyon to the Currituck Slide. In April 2015, we discovered methane seeps not included in the previously-published database, but found that some known seeps were not active. New high-resolution multi-channel seismic data revealed clear differences between the deep gas distribution in mid-Atlantic upper slope zones that are replete with (up to 240 sites) and lacking in seeps. Based on sea-air flux measurements, even shallow-water outer shelf (~125 m water depth) seeps and a 900-m-high methane plume originating on the mid-slope do not contribute methane to the atmosphere. Using thermistors placed on piston core outriggers, we will in September 2015 acquire thermal data to identify zones of high fluid advection and to constrain background geotherms in areas where heat flow has never been measured. During that same cruise, we will collect a series of piston cores across the no-hydrate/hydrate transition on the upper slope to constrain fluid and gas dynamics in this zone.

  3. Mercury in the marine boundary layer and seawater of the South China Sea: Concentrations, sea/air flux, and implication for land outflow

    NASA Astrophysics Data System (ADS)

    Fu, Xuewu; Feng, Xinbin; Zhang, Gan; Xu, Weihai; Li, Xiangdong; Yao, Hen; Liang, Peng; Li, Jun; Sommar, Jonas; Yin, Runsheng; Liu, Na

    2010-03-01

    Using R/V Shiyan 3 as a sampling platform, measurements of gaseous elemental mercury (GEM), surface seawater total mercury (THg), methyl mercury (MeHg), and dissolved gaseous mercury (DGM) were carried out above and in the South China Sea (SCS). Measurements were collected for 2 weeks (10 to 28 August 2007) during an oceanographic expedition, which circumnavigated the northern SCS from Guangzhou (Canton), Hainan Inland, the Philippines, and back to Guangzhou. GEM concentrations over the northern SCS ranged from 1.04 to 6.75 ng m-3 (mean: 2.62 ng m-3, median: 2.24 ng m-3). The spatial distribution of GEM was characterized by elevated concentrations near the coastal sites adjacent to mainland China and lower concentrations at stations in the open sea. Trajectory analysis revealed that high concentrations of GEM were generally related to air masses from south China and the Indochina peninsula, while lower concentrations of GEM were related to air masses from the open sea area, reflecting great Hg emissions from south China and Indochina peninsula. The mean concentrations of THg, MeHg, and DGM in surface seawater were 1.2 ± 0.3 ng L-1, 0.12 ± 0.05 ng L-1, and 36.5 ± 14.9 pg L-1, respectively. In general, THg and MeHg levels in the northern SCS were higher compared to results reported from most other oceans/seas. Elevated THg levels in the study area were likely attributed to significant Hg delivery from surrounding areas of the SCS primarily via atmospheric deposition and riverine input, whereas other sources like in situ production by various biotic and abiotic processes may be important for MeHg. Average sea/air flux of Hg in the study area was estimated using a gas exchange method (4.5 ± 3.4 ng m-2 h-1). This value was comparable to those from other coastal areas and generally higher than those from open sea environments, which may be attributed to the reemission of Hg previously transported to this area.

  4. Oil and gas bearing in Norwegian Sea basins

    NASA Astrophysics Data System (ADS)

    Zabanbark, A.

    2013-07-01

    The Norwegian passive continental margin is represented by an extensive gentle shelf and continental slope. On the continental slope, there are the isolated Vøring, Møre and Ras basins, the Halten Terrace is situated to the east of them at the shelf, then the Nordland submarine ridge and the Trondelag Platform at the seaboard. There are Paleozoic, Mesozoic and Cenozoic sediments in its sections. Two complex structures are clearly distinguished in the sedimentary section: the lower stage (up to the Upper Cretaceous), reflecting the rifting structure of the basins, broken by a system of dislocations to a series of horsts, grabens, and separated blocks; and the upper stage, poorly dislocated, like a mantle covering the lower stage, with erosion and sharp unconformity. The Halten Terrace is the principal oil and gas production basin. At present, there are more than 50 oil, gas, and condensate fields in it. The following particularities have been discovered: than the field lays in the deepwater, than the age of the hydrocarbon pay is younger. It is also interesting that all gas fields are situated in the Vøring and Møre basins and western part of the Halten Terrace; the oil and gas fields, mainly at the center of the Halten Terrace; but pure oil fields, in the north of the terrace. In conformity with discovering the particularities, it is possible to say that the prospects of oil and gas bearing in the Norwegian Sea are primarilyt related to the Halten Terrace and the Vøring and Møre basins, especially the territories situated at the boundary of the two basins, where it is possible to discover large hydrocarbon accumulations like the Ormen-Lange field, because the Paleocene-Upper Cretaceous productive turbidite thick at the boundary of these basins is on the continental slope, which is considered promising a priori.

  5. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    SciTech Connect

    Carerras-Sospedra, Marc; Brouwer, Jack; Dabdub, Donald; Lunden, Melissa; Singer, Brett

    2011-07-01

    The effects of liquefied natural gas (LNG) on pollutant emission inventories and air quality in the South Coast Air Basin of California were evaluated using recent LNG emission measurements by Lawrence Berkeley National Laboratory and the Southern California Gas Company (SoCalGas), and with a state-of-the-art air quality model. Pollutant emissions can be affected by LNG owing to differences in composition and physical properties, including the Wobbe index, a measure of energy delivery rate. This analysis uses LNG distribution scenarios developed by modeling Southern California gas flows, including supplies from the LNG receiving terminal in Baja California, Mexico. Based on these scenarios, the projected penetratino of LNG in the South Coast Air Basin is expected to be limited. In addition, the increased Wobbe index of delivered gas (resulting from mixtures of LNG and conventional gas supplies) is expected to cause increases smaller than 0.05 percent in overall (area-wide) emissions of nitrogen oxides (NOx). BAsed on the photochemical state of the South Coast Air Basin, any increase in NOx is expected to cause an increase in the highest local ozone concentrations, and this is reflected in model results. However, the magnitude of the increase is well below the generally accepted accuracy of the model and would not be discernible with the existing monitoring network. Modeling of hypothetical scenarios indicates that discernible changes to ambient ozone and particulate matter concentrations would occur only at LNG distribution rates that are not achievable with current or planned infrastructure and with Wobbe index vlaues that exceed current gas quality tariffs. Results of these hypothetical scenarios are presented for consideration of any proposed substantial expansion of LNG supply infrastructure in Southern California.

  6. The Impact of a Lower Sea Ice Extent on Arctic Greenhouse Gas Exchange

    NASA Astrophysics Data System (ADS)

    Parmentier, Frans-Jan W.; Christensen, Torben R.; Lotte Sørensen, Lise; Rysgaard, Søren; McGuire, A. David; Miller, Paul A.; Walker, Donald A.

    2013-04-01

    years has the potential to influence greenhouse gas exchange across terrestrial ecosystems and the Arctic Ocean, but the overall impact remains unclear. In this study, we therefore try to reduce this uncertainty by addressing the influence of the decline in sea ice extent on all affected greenhouse gas fluxes in the high latitudes. Also, we will address the need for more research, on the ocean and on the land, to understand the impact of a lower sea ice extent on Arctic greenhouse gas exchange. References: Bates, N. R., Moran, S. B., Hansell, D. A. and Mathis, J. T.: An increasing CO2 sink in the Arctic Ocean due to sea-ice loss, Geophys. Res. Lett., 33, L23609, doi:10.1029/2006GL027028, 2006. Cai, W.-J., Chen, L., Chen, B., Gao, Z., Lee, S. H., Chen, J., Pierrot, D., Sullivan, K., Wang, Y., Hu, X., Huang, W.-J., et al.: Decrease in the CO2 Uptake Capacity in an Ice-Free Arctic Ocean Basin, Science, 329(5991), 556-559, doi:10.1126/science.1189338, 2010. Kort, E. A., Wofsy, S. C., Daube, B. C., Diao, M., Elkins, J. W., Gao, R. S., Hintsa, E. J., Hurst, D. F., Jimenez, R., Moore, F. L., Spackman, J. R., et al.: Atmospheric observations of Arctic Ocean methane emissions up to 82 degrees north, Nature Geosci., 5(5), 318-321, doi:10.1038/NGEO1452, 2012. Nomura, D., Yoshikawa-Inoue, H. and Toyota, T.: The effect of sea-ice growth on air-sea CO2 flux in a tank experiment, vol. 58, pp. 418-426. 2006. Post, E., Forchhammer, M. C., Bret-Harte, M. S., Callaghan, T. V., Christensen, T. R., Elberling, B., Fox, A. D., Gilg, O., Hik, D. S., Høye, T. T., Ims, R. A., et al.: Ecological Dynamics Across the Arctic Associated with Recent Climate Change, Science, 325(5946), 1355-1358, doi:10.1126/science.1173113, 2009. Rysgaard, S., Glud, R. N., Sejr, M. K., Bendtsen, J. and Christensen, P. B.: Inorganic carbon transport during sea ice growth and decay: A carbon pump in polar seas, J. Geophys. Res., 112, C03016, doi:10.1029/2006JC003572, 2007. Schuur, E. A. G., Abbott, B. and Network, P. C

  7. Distribution of organochlorine pesticides in the northern South China Sea: implications for land outflow and air-sea exchange.

    PubMed

    Zhang, Gan; Li, Jun; Cheng, Hairong; Li, Xiangdong; Xu, Weihai; Jones, Kevin C

    2007-06-01

    The South China Sea (SCS) is surrounded by developing countries in Southeast Asia, where persistent organic pollutants (POPs), such as organochlorine pesticides (OCPs), are still used legally or illegally, and are of concern. Yet little is known about the distribution of OCPs in the water and atmosphere over SCS, as well as their air-sea equilibrium status and time trends. In this study, ship-board air samples and surface seawater collected in the northern SCS between September 6 and 22, 2005 were analyzed for selected OCPs. The measured OCP concentrations in the atmosphere over the northern SCS were influenced by proximity to source regions and air mass origins. The highest atmospheric OCP concentrations were found at sampling sites adjacent to continental South China. OCPs in surface seawater showed significant spatial variations, with the highest concentration observed in a water sample from off Vietnam. The coastal currents were suggested to play a key role in the delivery of waterborne OCPs in the northern SCS. Time trend, land outflow, and air-sea exchange of selected OCPs in the SCS were investigated, by comparison of this dataset with historical data.

  8. Regenerable Air Purification System for Gas-Phase Contaminant Control

    NASA Technical Reports Server (NTRS)

    Constantinescu, Ileana C.; Finn, John E.; LeVan, M. Douglas; Lung, Bernadette (Technical Monitor)

    2000-01-01

    Tests of a pre-prototype regenerable air purification system (RAPS) that uses water vapor to displace adsorbed contaminants from an adsorbent column have been performed at NASA Ames Research Center. A unit based on this design can be used for removing trace gas-phase contaminants from spacecraft cabin air or from polluted process streams including incinerator exhaust. During the normal operation mode, contaminants are removed from the air on the column. Regeneration of the column is performed on-line. During regeneration, contaminants are displaced and destroyed inside the closed oxidation loop. In this presentation we discuss initial experimental results for the performance of RAPS in the removal and treatment of several important spacecraft contaminant species from air.

  9. Using eddy covariance to estimate air–sea gas transfer velocity for oxygen

    NASA Astrophysics Data System (ADS)

    Andersson, Andreas; Rutgersson, Anna; Sahlée, Erik

    2016-07-01

    Air-sea gas transfer velocity for O2 is calculated using directly measured fluxes with the eddy covariance technique. It is a direct method and is frequently used to determine fluxes of heat, humidity, and CO2, but has not previously been used to estimate transfer velocities for O2, using atmospheric eddy covariance data. The measured O2 fluxes are upward directed, in agreement with the measured air-sea gradient of the O2 concentration, and opposite to the direction of the simultaneously measured CO2 fluxes. The transfer velocities estimated from measurements are compared with prominent wind speed parameterizations of the transfer velocity for CO2 and O2, previously established from various measurement techniques. Our result indicates stronger wind speed dependence for the transfer velocity of O2 compared to CO2 starting at intermediate wind speeds. This stronger wind speed dependence appears to coincide with the onset of whitecap formation in the flux footprint and the strong curvature of a cubic wind-dependent function for the transfer velocity provides the best fit to the data. Additional data using the measured O2 flux and an indirect method (based on the Photosynthetic Quotient) to estimate oxygen concentration in water, support the stronger wind dependence for the transfer velocity of O2 compared to CO2.

  10. Control of gas contaminants in air streams through biofiltration

    SciTech Connect

    Holt, T.; Lackey, L.

    1996-11-01

    According to the National Institute for Occupational Safety and Health (NIOSH), the maximum styrene concentration allowed in the work place is 50 ppm for up to a 10-hour work day during a 40-hour work week. The US EPA has classified styrene as one of the 189 hazardous air pollutants listed under Title 3 of the Clean Air Act Amendments to be reduced by a factor of 90% by the year 2000. Significant quantities of styrene are emitted to the atmosphere each year by boat manufacturers. A typical fiberglass boat manufacturing facility can emit over 273 metric tons/year of styrene. The concentration of styrene in the industrial exhaust gas ranges from 20 to 100 ppmv. Such dilute, high volume organically tainted air streams can make conventional abatement technologies such as thermal incineration, adsorption, or absorption technically incompetent or prohibitively expensive. An efficient, innovative, and economical means of remediating styrene vapors would be of value to industries and to the environment. Biofilter technology depends on microorganisms that are immobilized on the packing material in a solid phase reactor to remove or degrade environmentally undesirable compounds contaminating gas streams. The technology is especially successful for treating large volumes of air containing low concentrations of contaminants. The objective of this study was to investigate the feasibility of using biofiltration to treat waste gas streams containing styrene and to determine the critical design and operating parameters for such a system.

  11. Biofilm-like properties of the sea surface and predicted effects on air-sea CO2 exchange

    NASA Astrophysics Data System (ADS)

    Wurl, Oliver; Stolle, Christian; Van Thuoc, Chu; The Thu, Pham; Mari, Xavier

    2016-05-01

    Because the sea surface controls various interactions between the ocean and the atmosphere, it has a profound function for marine biogeochemistry and climate regulation. The sea surface is the gateway for the exchange of climate-relevant gases, heat and particles. Thus, in order to determine how the ocean and the atmosphere interact and respond to environmental changes on a global scale, the characterization and understanding of the sea surface are essential. The uppermost part of the water column is defined as the sea-surface microlayer and experiences strong spatial and temporal dynamics, mainly due to meteorological forcing. Wave-damped areas at the sea surface are caused by the accumulation of surface-active organic material and are defined as slicks. Natural slicks are observed frequently but their biogeochemical properties are poorly understood. In the present study, we found up to 40 times more transparent exopolymer particles (TEP), the foundation of any biofilm, in slicks compared to the underlying bulk water at multiple stations in the North Pacific, South China Sea, and Baltic Sea. We found a significant lower enrichment of TEP (up to 6) in non-slick sea surfaces compared to its underlying bulk water. Moreover, slicks were characterized by a large microbial biomass, another shared feature with conventional biofilms on solid surfaces. Compared to non-slick samples (avg. pairwise similarity of 70%), the community composition of bacteria in slicks was increasingly (avg. pairwise similarity of 45%) different from bulk water communities, indicating that the TEP-matrix creates specific environments for its inhabitants. We, therefore, conclude that slicks can feature biofilm-like properties with the excessive accumulation of particles and microbes. We also assessed the potential distribution and frequency of slick-formation in coastal and oceanic regions, and their effect on air-sea CO2 exchange based on literature data. We estimate that slicks can reduce CO2

  12. Characterization of gas diffusion electrodes for metal-air batteries

    NASA Astrophysics Data System (ADS)

    Danner, Timo; Eswara, Santhana; Schulz, Volker P.; Latz, Arnulf

    2016-08-01

    Gas diffusion electrodes are commonly used in high energy density metal-air batteries for the supply of oxygen. Hydrophobic binder materials ensure the coexistence of gas and liquid phase in the pore network. The phase distribution has a strong influence on transport processes and electrochemical reactions. In this article we present 2D and 3D Rothman-Keller type multiphase Lattice-Boltzmann models which take into account the heterogeneous wetting behavior of gas diffusion electrodes. The simulations are performed on FIB-SEM 3D reconstructions of an Ag model electrode for predefined saturation of the pore space with the liquid phase. The resulting pressure-saturation characteristics and transport correlations are important input parameters for modeling approaches on the continuum scale and allow for an efficient development of improved gas diffusion electrodes.

  13. Influence of sea-air interface on upward laser beam propagation

    NASA Astrophysics Data System (ADS)

    Zhou, Tian-hua; He, Yan; Zhu, Xiao-lei; Chen, Wei-biao

    2013-08-01

    The roughness of sea surface affects the optical property of the exiting upward laser, which constrains the application of the LIDAR and Laser Communication in ocean. The paper designs one pool test to study the influence of sea-air interfaces and develops a corresponding geometric optical model. It analyzes the optical property of the upward laser through the sea-air interface systematic. Results show that the roughness of wavy sea surface will affect beam spreading, pointing and scintillation when transmitting through the boundary. Further, experiment results in one water tank with man-made wave show that the incident angle and divergence angle are very important to the upward laser on the real-time and statistics change. Selecting one appropriate incident angle and divergence angle will get one stabilized performance, which is useful to the laser practical application on the marine areas.

  14. New challenges to air/gas cleaning systems

    SciTech Connect

    Kovach, J.L.

    1997-08-01

    This paper discusses the need for changes in the design and manufacturing of air and gas cleaning systems to meet waste management and site remediation requirements. Current design and manufacturing practices are primarily directed toward evaluating operational problems with existing systems in nuclear reactor facilities. However, nuclear waste management needs have developed which are much broader in scope and have different processing conditions. Numerous examples of air cleaning needs for waste management activities are provided; the major differences from operating facility needs are the requirement for continuous effluent treatment under widely different processing conditions. Related regulatory issues are also discussed briefly. 1 ref.

  15. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Meixner, Franz X.; Vrana, Branislav; Efstathiou, Christos I.; Kohoutek, Jiři; Kukučka, Petr; Mulder, Marie D.; Přibylová, Petra; Prokeš, Roman; Rusina, Tatsiana P.; Song, Guo-Zheng; Tsapakis, Manolis

    2016-05-01

    As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Δc/Δz > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8 µg m-2 day-1 for PAHs and -3.4 to +0.9 µg m-2 day-1 for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.

  16. Decadal trends in air-sea CO2 exchange in the Ross Sea (Antarctica)

    NASA Astrophysics Data System (ADS)

    Tagliabue, Alessandro; Arrigo, Kevin R.

    2016-05-01

    Highly productive Antarctic shelf systems, like the Ross Sea, play important roles in regional carbon budgets, but the drivers of local variations are poorly quantified. We assess the variability in the Ross Sea carbon cycle using a regional physical-biogeochemical model. Regionally, total partial pressure of CO2 (pCO2) increases are largely controlled by the biological pump and broadly similar to those in the offshore Southern Ocean. However, this masks substantial local variability within the Ross Sea, where interannual fluctuations in total pCO2 are driven by the biological pump and alkalinity, whereas those for anthropogenic pCO2 are related to physical processes. Overall, the high degree of spatial variability in the Ross Sea carbon cycle causes extremes in aragonite saturation that can be as large as long-term trends. Therefore, Antarctic shelf polynya systems like the Ross Sea will be strongly affected by local processes in addition to larger-scale phenomena.

  17. Air and gas pockets in sewerage pressure mains.

    PubMed

    Lubbers, C L; Clemens, F

    2005-01-01

    In The Netherlands, wastewater is collected in municipal areas and transported to large centralised WWTPs by means of an extensive system of pressure mains. Over the past decades these pressure mains did not receive much attention in terms of monitoring of performance or maintenance. For that reason, in practice their state of functioning is often not known. Failure of operation is only noticed when the capacity of the system proves to be insufficient to fulfil the minimum design capacity demand. A recent inventory showed that half of the pressure mains show an increased pressure loss for no directly obvious reason. Many causes may account for the reduction of the system's nominal capacity like an increased wall roughness, scaling or occurrence of free gas in the pipeline. The occurrence of free gas may be caused by degassing of dissolved (bio) gas or by air entrained at the pumps' inlet or at air valves. A research study is started that will focus on three main issues: The description of the gas-water phenomena in wastewater pressure mains with respect to transportation and dynamic hydraulic behaviour, A method to diagnose gas problems, and To overcome future problems by either applying remedial measures or improving the design of wastewater pressure systems. For this study, two experimental facilities are constructed, a small circuit for the study of multi-phase flow and a second, larger one for the research into diagnostic methods. This paper describes the preliminary results of the experiments in the multi-phase circuit.

  18. GSOD Based Daily Global Mean Surface Temperature and Mean Sea Level Air Pressure (1982-2011)

    DOE Data Explorer

    Xuan Shi, Dali Wang

    2014-05-05

    This data product contains all the gridded data set at 1/4 degree resolution in ASCII format. Both mean temperature and mean sea level air pressure data are available. It also contains the GSOD data (1982-2011) from NOAA site, contains station number, location, temperature and pressures (sea level and station level). The data package also contains information related to the data processing methods

  19. Coupled Air-Sea Observations and Modeling for Better Understanding Tropical Cyclone Prediction and Predictability

    NASA Astrophysics Data System (ADS)

    Chen, S. S.

    2014-12-01

    A systematic observational and modeling study is conducted to better understand the physical processes controlling air-sea interaction and their impact on tropical cyclone (TC) prediction and predictability using a fully coupled atmosphere-wave-ocean modeling system developed at the University of Miami and observations from field campaigns. We have developed a unified air-sea interface module that couples multiple atmosphere, wave, and ocean models using the Earth System Modeling Framework (ESMF). It is a physically based and computationally efficient coupling system that is flexible to use in a multi-model system and portable for transition to the next generation research and operational coupled atmosphere-wave-ocean-land models. This standardized coupling framework allows researchers to develop and test air-sea coupling parameterizations and coupled data assimilation, and to better facilitate research-to-operation activities. It also allows for ensemble forecasts that can be used for coupled atmosphere-ocean data assimilation and assessment of uncertainties in coupled model predictions. The coupled modeling system has been evaluated using the coupled air-sea observations (e.g., GPS dropsondes and AXBTs, ocean drifters and floats) collected in recent field campaigns in the Gulf of Mexico and TCs in the Atlantic and Pacific basins. This talk will provide 1) an overview of the unified air-sea interface model, 2) fully coupled atmosphere-wave-ocean model predictions of TCs and evaluation with coupled air-sea observations, and 3) results from high-resolution (1.3 km grid resolution) ensemble experiments using a stochastic kinetic energy backscatter (SKEB) perturbation method to assess the predictability and uncertainty in TC predictions.

  20. Balloons and Bottles: Activities on Air-Sea Heat Exchange.

    ERIC Educational Resources Information Center

    Murphree, Tom

    1998-01-01

    Presents an activity designed to demonstrate how heating and cooling an air mass affects its temperature, volume, density, and pressure. Illustrates how thermal energy can cause atmospheric motion such as expansion, contraction, and winds. (Author/WRM)

  1. Air-sea heat exchange, an element of the water cycle

    NASA Technical Reports Server (NTRS)

    Chahine, M. T.

    1984-01-01

    The distribution and variation of water vapor, clouds and precipitation are examined. Principal driving forces for these distributions are energy exchange and evaporation at the air-sea interface, which are also important elements of air-sea interaction studies. The overall aim of air-sea interaction studies is to quantitatively determine mass, momentum and energy fluxes, with the goal of understanding the mechanisms controlling them. The results of general circulation simulations indicate that the atmosphere in mid-latitudes responds to changes in the oceanic surface conditions in the tropics. This correlation reflects the strong interaction between tropical and mid-latitude conditions caused by the transport of heat and momentum from the tropics. Studies of air-sea exchanges involve a large number of physica, chemical and dynamical processes including heat flux, radiation, sea-surface temperature, precipitation, winds and ocean currents. The fluxes of latent heat are studied and the potential use of satellite data in determining them evaluated. Alternative ways of inferring heat fluxes will be considered.

  2. Curved centerline air intake for a gas turbine engine

    NASA Technical Reports Server (NTRS)

    Ruehr, W. C.; Younghans, J. L.; Smith, E. B. (Inventor)

    1980-01-01

    An inlet for a gas turbine engine was disposed about a curved centerline for the purpose of accepting intake air that is flowing at an angle to engine centerline and progressively turning that intake airflow along a curved path into alignment with the engine. This curved inlet is intended for use in under the wing locations and similar regions where airflow direction is altered by aerodynamic characteristics of the airplane. By curving the inlet, aerodynamic loss and acoustic generation and emission are decreased.

  3. [Working ability between air and trimix breathing gas under 8 ATA air condition].

    PubMed

    Shibayama, M; Kosugi, S; Mohri, M; Yamamura, I; Oda, S; Kimura, A; Takeuchi, J; Mano, Y

    1990-04-01

    Pneumatic caisson work in Japan has come into operation since 1924. Afterward, this technique of compressed air work has been widely utilized in the construction of foundation basements, shafts of the bottom tunnel shields for subway and so forth. While using this technique of compressed air work means that workers have to be exposed to hyperbaric environment, this technique has risks of not only decompression sickness (DCS) but also toxicity of poisonous gas and/or oxygen deficiency. However, this technique is independent of city construction work and the operation of compressed air work higher than 5ATA (4.0 kg/cm2G) is actually been planning recently. Accordingly unmanned caisson work is considered as a better technique for such higher pressurized work, even though workers must enter into hyperbaric working fields for maintenance or repair of unmanned operated machinery and materials. This research is to establish the safe work under hyperbaric air environment at 8ATA. PMID:2400467

  4. Gas chromatographic method for measuring nitrogen dioxide and peroxyacetyl nitrate in air without compressed gas cylinders

    SciTech Connect

    Burkhardt, M.R.; Maniga, N.I.; Stedman, D.H.; Paur, R.J.

    1988-04-15

    A gas chromatographic technique that measures atmospheric concentrations of peroxyacetyl nitrate (PAN) and NO/sub 2/ has been developed that uses luminol-based chemiluminescence for detection. The carrier gas is air that has been scrubbed by passing it over FeSO/sub 4/, which eliminates the need for any compressed gas cylinders. A novel gas sampling system and time enable variable sample volumes of contaminated air to be injected. Ambient PAN and NO/sub 2/ measurements can be made every 40 s with detection limits of 0.12 ppb for PAN and 0.2 ppb for NO/sub 2/. Seven other atmospheric species, including ozone, gave no interference. Linear response was observed for NO/sub 2/ from 0.2 to 170 ppb and for PAN from 1 to 70 ppb.

  5. Compressed air energy storage in depleted natural gas reservoirs: effects of porous media and gas mixing

    NASA Astrophysics Data System (ADS)

    Oldenburg, C. M.; Pan, L.

    2015-12-01

    Although large opportunities exist for compressed air energy storage (CAES) in aquifers and depleted natural gas reservoirs, only two grid-scale CAES facilities exist worldwide, both in salt caverns. As such, experience with CAES in porous media, what we call PM-CAES, is lacking and we have relied on modeling to elucidate PM-CAES processes. PM-CAES operates similarly to cavern CAES. Specifically, working gas (air) is injected through well(s) into the reservoir compressing the cushion gas (existing air in the reservoir). During energy recovery, high-pressure air from the reservoir flows first into a recuperator, then into an expander, and subsequently is mixed with fuel in a combustion turbine to produce electricity, thereby reducing compression costs. Energy storage in porous media is complicated by the solid matrix grains which provide resistance to flow (via permeability in Darcy's law); in the cap rock, low-permeability matrix provides the seal to the reservoir. The solid grains also provide storage capacity for heat that might arise from compression, viscous flow effects, or chemical reactions. The storage of energy in PM-CAES occurs variably across pressure gradients in the formation, while the solid grains of the matrix can release/store heat. Residual liquid (i.e., formation fluids) affects flow and can cause watering out at the production well(s). PG&E is researching a potential 300 MW (for ten hours) PM-CAES facility in a depleted gas reservoir near Lodi, California. Special considerations exist for depleted natural gas reservoirs because of mixing effects which can lead to undesirable residual methane (CH4) entrainment and reactions of oxygen and CH4. One strategy for avoiding extensive mixing of working gas (air) with reservoir CH4 is to inject an initial cushion gas with reduced oxygen concentration providing a buffer between the working gas (air) and the residual CH4 gas. This reduces the potential mixing of the working air with the residual CH4

  6. Experimental sea slicks: Their practical applications and utilization for basic studies of air-sea interactions

    NASA Astrophysics Data System (ADS)

    Hühnerfuss, Heinrich; Garrett, W. D.

    1981-01-01

    Practical applications of organic surface films added to the sea surface date back to ancient times. Aristotle, Plutarch, and Pliny the Elder describe the seaman's practice of calming waves in a storm by pouring oil onto the sea [Scott, 1977]. It was also noted that divers released oil beneath the water surface so that it could rise and spread over the sea surface, thereby suppressing the irritating flicker associated with the passage of light through a rippled surface. From a scientific point of view, Benjamin Franklin was the first to perform experiments with oils on natural waters. His experiment with a `teaspoonful of oil' on Clapham pond in 1773 inspired many investigators to consider sea surface phenomena or to conduct experiments with oil films. This early research has been reviewed by Giles [1969], Giles and Forrester [1970], and Scott [1977]. Franklin's studies with experimental slicks can be regarded as the beginning of surface film chemistry. His speculations on the wave damping influence of oil induced him to perform the first qualitative experiment with artificial sea slicks at Portsmouth (England) in October of 1773. Although the sea was calmed and very few white caps appeared in the oil-covered area, the swell continued through the oiled area to Franklin's great disappointment.

  7. The organic sea-surface microlayer in the upwelling region off the coast of Peru and potential implications for air-sea exchange processes

    NASA Astrophysics Data System (ADS)

    Engel, Anja; Galgani, Luisa

    2016-02-01

    The sea-surface microlayer (SML) is at the uppermost surface of the ocean, linking the hydrosphere with the atmosphere. The presence and enrichment of organic compounds in the SML have been suggested to influence air-sea gas exchange processes as well as the emission of primary organic aerosols. Here, we report on organic matter components collected from an approximately 50 µm thick SML and from the underlying water (ULW), ˜ 20 cm below the SML, in December 2012 during the SOPRAN METEOR 91 cruise to the highly productive, coastal upwelling regime off the coast of Peru. Samples were collected at 37 stations including coastal upwelling sites and off-shore stations with less organic matter and were analyzed for total and dissolved high molecular weight (> 1 kDa) combined carbohydrates (TCCHO, DCCHO), free amino acids (FAA), total and dissolved hydrolyzable amino acids (THAA, DHAA), transparent exopolymer particles (TEP), Coomassie stainable particles (CSPs), total and dissolved organic carbon (TOC, DOC), total and dissolved nitrogen (TN, TDN), as well as bacterial and phytoplankton abundance. Our results showed a close coupling between organic matter concentrations in the water column and in the SML for almost all components except for FAA and DHAA that showed highest enrichment in the SML on average. Accumulation of gel particles (i.e., TEP and CSP) in the SML differed spatially. While CSP abundance in the SML was not related to wind speed, TEP abundance decreased with wind speed, leading to a depletion of TEP in the SML at about 5 m s-1. Our study provides insight to the physical and biological control of organic matter enrichment in the SML, and discusses the potential role of organic matter in the SML for air-sea exchange processes.

  8. Impacts of South East Biomass Burning on local air quality in South China Sea

    NASA Astrophysics Data System (ADS)

    Wai-man Yeung, Irene; Fat Lam, Yun; Eniolu Morakinyo, Tobi

    2016-04-01

    Biomass burning is a significant source of carbon monoxide and particulate matter, which is not only contribute to the local air pollution, but also regional air pollution. This study investigated the impacts of biomass burning emissions from Southeast Asia (SEA) as well as its contribution to the local air pollution in East and South China Sea, including Hong Kong and Taiwan. Three years (2012 - 2014) of the Hybrid Single Particle Lagrangian-Integrated Trajectory (HYSPLIT) with particles dispersion analyses using NCEP (Final) Operational Global Analysis data (FNL) data (2012 - 2014) were analyzed to track down all possible long-range transport from SEA with a sinking motion that worsened the surface air quality (tropospheric downwash from the free troposphere). The major sources of SEA biomass burning emissions were first identified using high fire emissions from the Global Fire Emission Database (GFED), followed by the HYSPLIT backward trajectory dispersion modeling analysis. The analyses were compared with the local observation data from Tai Mo Shan (1,000 msl) and Tap Mun (60 msl) in Hong Kong, as well as the data from Lulin mountain (2,600 msl) in Taiwan, to assess the possible impacts of SEA biomass burning on local air quality. The correlation between long-range transport events from the particles dispersion results and locally observed air quality data indicated that the background concentrations of ozone, PM2.5 and PM10 at the surface stations were enhanced by 12 μg/m3, 4 μg/m3 and 7 μg/m3, respectively, while the long-range transport contributed to enhancements of 4 μg/m3, 4 μg/m3 and 8 μg/m3 for O3, PM2.5 and PM10, respectively at the lower free atmosphere.

  9. Regulation of CO2 Air Sea Fluxes by Sediments in the North Sea

    NASA Astrophysics Data System (ADS)

    Burt, William; Thomas, Helmuth; Hagens, Mathilde; Brenner, Heiko; Pätsch, Johannes; Clargo, Nicola; Salt, Lesley

    2016-04-01

    A multi-tracer approach is applied to assess the impact of boundary fluxes (e.g. benthic input from sediments or lateral inputs from the coastline) on the acid-base buffering capacity, and overall biogeochemistry, of the North Sea. Analyses of both basin-wide observations in the North Sea and transects through tidal basins at the North-Frisian coastline, reveal that surface distributions of the δ13C signature of dissolved inorganic carbon (DIC) are predominantly controlled by a balance between biological production and respiration. In particular, variability in metabolic DIC throughout stations in the well-mixed southern North Sea indicates the presence of an external carbon source, which is traced to the European continental coastline using naturally-occurring radium isotopes (224Ra and 228Ra). 228Ra is also shown to be a highly effective tracer of North Sea total alkalinity (AT) compared to the more conventional use of salinity. Coastal inputs of metabolic DIC and AT are calculated on a basin-wide scale, and ratios of these inputs suggest denitrification as a primary metabolic pathway for their formation. The AT input paralleling the metabolic DIC release prevents a significant decline in pH as compared to aerobic (i.e. unbuffered) release of metabolic DIC. Finally, long-term pH trends mimic those of riverine nitrate loading, highlighting the importance of coastal AT production via denitrification in regulating pH in the southern North Sea.

  10. Simulation-based study of air-sea momentum fluxes nearshore

    NASA Astrophysics Data System (ADS)

    Hao, Xuanting; Shen, Lian

    2015-11-01

    Momentum fluxes at sea surface are crucial to air-sea interactions. In nearshore regions, the bathymetry variation has a significant impact on the surface wave field and complicates the momentum fluxes at water surface. In this study, we extend a high order spectral method to address wave-bottom interactions and wave modeling. From the wave simulation data, we use the Hilbert-Huang transform to quantify the properties of the wave spectrum, based on which the wave field is reconstructed for the detailed mechanistic study of wind-wave interactions using large-eddy simulation for the wind field. The roughness of the water surface is quantified using a dynamic model for the effects of subgrid-scale waves. The results show that the waves are sensitive to the water depth variation. Associated with the changes in the wave field, the momentum fluxes at the air-sea interface increase in shallow regions.

  11. Effect of air on energy and rise-time spectra measured by proportional gas counter

    SciTech Connect

    Kawano, T.; Tanaka, M.; Isozumi, S.; Isozumi, Y.; Tosaki, M.; Sugiyama, T.

    2015-03-15

    Air exerts a negative effect on radiation detection using a gas counter because oxygen contained in air has a high electron attachment coefficient and can trap electrons from electron-ion pairs created by ionization from incident radiation in counting gas. This reduces radiation counts. The present study examined the influence of air on energy and rise-time spectra measurements using a proportional gas counter. In addition, a decompression procedure method was proposed to reduce the influence of air and its effectiveness was investigated. For the decompression procedure, the counting gas inside the gas counter was decompressed below atmospheric pressure before radiation detection. For the spectrum measurement, methane as well as various methane and air mixtures were used as the counting gas to determine the effect of air on energy and rise-time spectra. Results showed that the decompression procedure was effective for reducing or eliminating the influence of air on spectra measurement using a proportional gas counter. (authors)

  12. Air-sea interaction measurements in the west Mediterranean Sea during the Tyrrhenian Eddy Multi-Platform Observations Experiment

    SciTech Connect

    Schiano, M.E.; Santoleri, R.; Bignami, F.; Leonardi, R.M. ); Marullo, S. ); Boehm, E. )

    1993-02-15

    Measurements of radiative fluxes were carried out in the Tyrrhenian Sea in fall and winter as part of the Tyrrhenian Eddy Multi-Platform Observations Experiment (TEMPO). These measurements have supplied the first experimental radiation data set over this basin. Seasonal variation of the different components of the budget are investigated. Since data collection was carried out in an area in which a quasi-permanent eddy is present, the behavior of the radiation parameters across the frontal zone is analyzed. The most interesting result of the air-sea interaction in proximity of a marine front consists in the covariation of sea surface temperature and downwelling long-wave radiation. Contemporaneous satellite data show a clear correlation between sea surface structure and horizontal distribution of columnar atmospheric water content. Therefore this inhomogeneity clearly is one of the main factors responsible for the variation of the downwelling radiation across the front. A comparison between experimental data and results of some of the most widely used bulk formulae is carried out for both short- and long-wave radiation. The mean differnece between measured and empirical solar radiation values is less than 3%, while in the case of the net long-wave radiation budge, poor agreement is found. Indeed, a 30 W/m[sup 2] bias results from the comparison. This discrepancy is consistent with the imbalance between previous bulk calculations of total heat budget at the surface and corresponding hydrographical observations of heat exchange at Gibraltar. 30 refs., 6 figs., 9 tabs.

  13. Climatic Impacts of a Stochastic Parameterization of Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Williams, P. D.

    2014-12-01

    The atmosphere and ocean are coupled by the exchange of fluxes across the ocean surface. Air-sea fluxes vary partly on scales that are too small and fast to be resolved explicitly in numerical models of weather and climate, making them a candidate for stochastic parameterization. This presentation proposes a nonlinear physical mechanism by which stochastic fluctuations in the air-sea buoyancy flux may modify the mean climate, even though the mean fluctuation is zero. The mechanism relies on a fundamental asymmetry in the physics of the ocean mixed layer: positive surface buoyancy fluctuations cannot undo the vertical mixing caused by negative fluctuations. The mechanism has much in common with Stommel's mixed-layer demon. The presentation demonstrates the mechanism in climate simulations with a comprehensive coupled atmosphere-ocean general circulation model (SINTEX-G). In the SINTEX-G simulations with stochastic air-sea buoyancy fluxes, significant changes are detected in the time-mean oceanic mixed-layer depth, sea-surface temperature, atmospheric Hadley circulation, and net upward water flux at the sea surface. Also, El Niño Southern Oscillation (ENSO) variability is significantly increased. The findings demonstrate that noise-induced drift and noise-enhanced variability, which are familiar concepts from simple climate models, continue to apply in comprehensive climate models with millions of degrees of freedom. The findings also suggest that the lack of representation of sub-grid variability in air-sea fluxes may contribute to some of the biases exhibited by contemporary climate models.

  14. Impact of autumn SST in the Japan Sea on winter rainfall and air temperature in Northeast China

    NASA Astrophysics Data System (ADS)

    Shi, Xiaomeng; Sun, Jilin; Wu, Dexing; Yi, Li; Wei, Dongni

    2015-08-01

    We studied the impact of sea surface temperature anomaly (SSTA) in the Japan Sea and the sea area east of Japan on the winter rainfall and air temperature in Northeast (NE) China using the singular value decomposition (SVD) and empirical orthogonal function (EOF). The monthly-mean rainfall data observed at 160 stations in China, monthly-mean sea surface temperature (SST) of the Hadley Center for Climate Prediction and Research and monthly-mean air temperature from the NCEP reanalysis during 1960-2011 were used. Correlation analysis indicates that the SSTAs in the Japan Sea in September may last for three or four months and are an important index for forecasting the winter rainfall and air temperature in NE China. Positive SSTAs in the central Japan Sea and in the sea area east of Tokyo correspond to positive rainfall anomaly and negative air temperature anomaly in NE China. With the rise of SST in the Japan Sea, a weak cyclone appears over the Japan Sea. The northeasterly wind transports water vapor from the Okhotsk to NE China, resulting in more rainfall and lower air temperature. Negative SSTA years are accompanied by warmer air temperature and less snow in NE China. The 1000 hPa geopotential height anomaly and wind anomaly fields are simulated by IAP-9L model, which supports the analysis results.

  15. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

    NASA Astrophysics Data System (ADS)

    Gantt, B.; Kelly, J. T.; Bash, J. O.

    2015-11-01

    Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are also important due to the localized impact of SSAs on atmospheric chemistry near the coast. In this study, SSA emissions in the Community Multiscale Air Quality (CMAQ) model were updated to enhance the fine-mode size distribution, include sea surface temperature (SST) dependency, and reduce surf-enhanced emissions. Predictions from the updated CMAQ model and those of the previous release version, CMAQv5.0.2, were evaluated using several coastal and national observational data sets in the continental US. The updated emissions generally reduced model underestimates of sodium, chloride, and nitrate surface concentrations for coastal sites in the Bay Regional Atmospheric Chemistry Experiment (BRACE) near Tampa, Florida. Including SST dependency to the SSA emission parameterization led to increased sodium concentrations in the southeastern US and decreased concentrations along parts of the Pacific coast and northeastern US. The influence of sodium on the gas-particle partitioning of nitrate resulted in higher nitrate particle concentrations in many coastal urban areas due to increased condensation of nitric acid in the updated simulations, potentially affecting the predicted nitrogen deposition in sensitive ecosystems. Application of the updated SSA emissions to the California Research at the Nexus of Air Quality and Climate Change (CalNex) study period resulted in a modest improvement in the predicted surface concentration of sodium and nitrate at several central and southern California coastal sites. This update of SSA emissions enabled a more realistic simulation of the atmospheric chemistry in coastal environments where marine air mixes with urban pollution.

  16. Radon gas distribution in natural gas processing facilities and workplace air environment.

    PubMed

    Al-Masri, M S; Shwiekani, R

    2008-04-01

    Evaluation was made of the distribution of radon gas and radiation exposure rates in the four main natural gas treatment facilities in Syria. The results showed that radiation exposure rates at contact of all equipment were within the natural levels (0.09-0.1 microSvh(-1)) except for the reflex pumps where a dose rate value of 3 microSvh(-1) was recorded. Radon concentrations in Syrian natural gas varied between 15.4 Bq m(-3) and 1141 Bq m(-3); natural gas associated with oil production was found to contain higher concentrations than the non-associated natural gas. In addition, radon concentrations were higher in the central processing facilities than the wellheads; these high levels are due to pressurizing and concentrating processes that enhance radon gas and its decay products. Moreover, the lowest 222Rn concentration was in the natural gas fraction used for producing sulfur; a value of 80 Bq m(-3) was observed. On the other hand, maximum radon gas and its decay product concentrations in workplace air environments were found to be relatively high in the gas analysis laboratories; a value of 458 Bq m(-3) was observed. However, all reported levels in the workplaces in the four main stations were below the action level set by IAEA for chronic exposure situations involving radon, which is 1000 Bq m(-3). PMID:17905489

  17. Radon gas distribution in natural gas processing facilities and workplace air environment.

    PubMed

    Al-Masri, M S; Shwiekani, R

    2008-04-01

    Evaluation was made of the distribution of radon gas and radiation exposure rates in the four main natural gas treatment facilities in Syria. The results showed that radiation exposure rates at contact of all equipment were within the natural levels (0.09-0.1 microSvh(-1)) except for the reflex pumps where a dose rate value of 3 microSvh(-1) was recorded. Radon concentrations in Syrian natural gas varied between 15.4 Bq m(-3) and 1141 Bq m(-3); natural gas associated with oil production was found to contain higher concentrations than the non-associated natural gas. In addition, radon concentrations were higher in the central processing facilities than the wellheads; these high levels are due to pressurizing and concentrating processes that enhance radon gas and its decay products. Moreover, the lowest 222Rn concentration was in the natural gas fraction used for producing sulfur; a value of 80 Bq m(-3) was observed. On the other hand, maximum radon gas and its decay product concentrations in workplace air environments were found to be relatively high in the gas analysis laboratories; a value of 458 Bq m(-3) was observed. However, all reported levels in the workplaces in the four main stations were below the action level set by IAEA for chronic exposure situations involving radon, which is 1000 Bq m(-3).

  18. Scattering properties of a stratified air/snow/sea ice medium. Small slope approximation

    NASA Astrophysics Data System (ADS)

    Dusséaux, Richard; Afifi, Saddek; Dechambre, Monique

    2016-11-01

    The sea-ice thickness, a key parameter in Arctic studies, is derived from radar altimeter height measurements of the freeboard, taking into account not only snow load, but also the penetration depth of the electromagnetic waves inside the snow-this is the not generally the case. Within the framework of the small slope approximation method, we study in Ku-band (f = 13 GHz, λ = 2.31 cm in the air) the electromagnetic signature of an air/snow/sea ice rough layered medium. The snow is inhomogeneous and is represented as a stack of several layers with different relative permittivities. We show that the electromagnetic response is very sensitive to the isotropy factor of the air/snow interface and to the cross-correlation parameters of interfaces. xml:lang="fr"

  19. Sensor gas analyzer for acetone determination in expired air

    NASA Astrophysics Data System (ADS)

    Baranov, Vitaly V.

    2001-05-01

    Diseases and changes in the way of life change the concentration and composition of the expired air. Our adaptable gas analyzer is intended for the selective analysis of expired air and can be adapted for the solution of current diagnostic and analytical tasks by the user (a physician or a patient). Having analyzed the existing trends in the development of noninvasive diagnostics we have chosen the method of noninvasive acetone detection in expired air, where the acetone concentration correlates with blood and urine glucose concentrations. The appearance of acetone in expired air is indicative of disorders that may be caused not only by diabetes but also be wrong diet, incorrect sportsmen training etc. To control the disorders one should know the acetone concentration in the human body. This knowledge allows one to judge upon the state of the patient, choose a correct diet that will not cause damage to the patient's health, determine sportsmen training efficiency and results and solve the artificial pancreas problem. Our device provide highly accurate analysis, rapid diagnostics and authentic acetone quantification in the patient's body at any time aimed at prediction of the patient's state and assessing the efficiency of the therapy used. Clinical implementation of the device will improve the health and save lives of many thousands of diabetes sufferers.

  20. Simulating emission and chemical evolution of coarse sea-salt particles in the Community Multiscale Air Quality (CMAQ) model

    NASA Astrophysics Data System (ADS)

    Kelly, J. T.; Bhave, P. V.; Nolte, C. G.; Shankar, U.; Foley, K. M.

    2009-12-01

    Chemical processing of sea-salt particles in coastal environments significantly impacts concentrations of particle components and gas-phase species and has implications for human exposure to particulate matter and nitrogen deposition to sensitive ecosystems. Emission of sea-salt particles from the coastal surf zone is known to be elevated compared to that from the open ocean. Despite the importance of sea-salt emissions and chemical processing, the US EPA's Community Multiscale Air Quality (CMAQ) model has traditionally treated coarse sea-salt particles as chemically inert and has not accounted for enhanced surf-zone emissions. In this article, updates to CMAQ are described that enhance sea-salt emissions from the coastal surf zone and allow dynamic transfer of HNO3, H2SO4, HCl, and NH3 between coarse particles and the gas phase. Predictions of updated CMAQ models and the previous release version, CMAQv4.6, are evaluated using observations from three coastal sites during the Bay Regional Atmospheric Chemistry Experiment (BRACE) in Tampa, FL in May 2002. Model updates improve predictions of NO3-, SO42-, NH4+, Na+, and Cl- concentrations at these sites with only a 8% increase in run time. In particular, the chemically interactive coarse particle mode dramatically improves predictions of nitrate concentration and size distributions as well as the fraction of total nitrate in the particle phase. Also, the surf-zone emission parameterization improves predictions of total sodium and chloride concentration. Results of a separate study indicate that the model updates reduce the mean absolute error of nitrate predictions at coastal CASTNET and SEARCH sites in the eastern US. Although the new model features improve performance relative to CMAQv4.6, some persistent differences exist between observations and predictions. Modeled sodium concentration is biased low and causes under-prediction of coarse particle nitrate. Also, CMAQ over-predicts geometric mean diameter and

  1. Simulating emission and chemical evolution of coarse sea-salt particles in the Community Multiscale Air Quality (CMAQ) model

    NASA Astrophysics Data System (ADS)

    Kelly, J. T.; Bhave, P. V.; Nolte, C. G.; Shankar, U.; Foley, K. M.

    2010-04-01

    Chemical processing of sea-salt particles in coastal environments significantly impacts concentrations of particle components and gas-phase species and has implications for human exposure to particulate matter and nitrogen deposition to sensitive ecosystems. Emission of sea-salt particles from the coastal surf zone is known to be elevated compared to that from the open ocean. Despite the importance of sea-salt emissions and chemical processing, the US EPA's Community Multiscale Air Quality (CMAQ) model has traditionally treated coarse sea-salt particles as chemically inert and has not accounted for enhanced surf-zone emissions. In this article, updates to CMAQ are described that enhance sea-salt emissions from the coastal surf zone and allow dynamic transfer of HNO3, H2SO4, HCl, and NH3 between coarse particles and the gas phase. Predictions of updated CMAQ models and the previous release version, CMAQv4.6, are evaluated using observations from three coastal sites during the Bay Regional Atmospheric Chemistry Experiment (BRACE) in Tampa, FL in May 2002. Model updates improve predictions of NO3-, SO42-, NH4+, Na+, and Cl- concentrations at these sites with only a 8% increase in run time. In particular, the chemically interactive coarse particle mode dramatically improves predictions of nitrate concentration and size distributions as well as the fraction of total nitrate in the particle phase. Also, the surf-zone emission parameterization improves predictions of total sodium and chloride concentration. Results of a separate study indicate that the model updates reduce the mean absolute error of nitrate predictions at coastal CASTNET and SEARCH sites in the eastern US. Although the new model features improve performance relative to CMAQv4.6, some persistent differences exist between observations and predictions. Modeled sodium concentration is biased low and causes under-prediction of coarse particle nitrate. Also, CMAQ over-predicts geometric mean diameter and

  2. Assessment of Undiscovered Oil and Gas Resources of the Red Sea Basin Province

    USGS Publications Warehouse

    ,

    2010-01-01

    The U.S. Geological Survey estimated mean volumes of 5 billion barrels of undiscovered technically recoverable oil and 112 trillion cubic feet of recoverable gas in the Red Sea Basin Province using a geology-based assessment methodology.

  3. Regenerable Air Purification System for Gas-Phase Contaminant Control

    NASA Technical Reports Server (NTRS)

    Constantinescu, Ileana C.; Qi, Nan; LeVan, M. Douglas; Finn, Cory K.; Finn, John E.; Luna, Bernadette (Technical Monitor)

    2000-01-01

    A regenerable air purification system (RAPS) that uses water vapor to displace adsorbed contaminants from an. adsorbent column into a closed oxidation loop is under development through cooperative R&D between Vanderbilt University and NASA Ames Research Center. A unit based on this design can be used for removing trace gas-phase contaminants from spacecraft cabin air or from polluted process streams including incinerator exhaust. Recent work has focused on fabrication and operation of a RAPS breadboard at NASA Ames, and on measurement of adsorption isotherm data for several important organic compounds at Vanderbilt. These activities support the use and validation of RAPS modeling software also under development at Vanderbilt, which will in turn be used to construct a prototype system later in the project.

  4. Energy supplies and future engines for land, sea, and air.

    PubMed

    Wilson, David Gordon

    2012-06-01

    The years 2012 and beyond seem likely to record major changes in energy use and power generation. The Japanese tsunami has resulted in large countries either scaling back or abolishing the future use of nuclear energy. The discovery of what seems like vast amounts of economically deliverable natural gas has many forecasting a rapid switch from coal- to gas-fired generating plants. On the other hand, environmentalists have strong objections to the production of natural gas and of petroleum by hydraulic fracturing from shale, or by extraction of heavy oil. They believe that global warming from the use of fossil fuels is now established beyond question. There has been rapid progress in the development of alternative energy supplies, particularly from on-shore and off-shore wind. Progress toward a viable future energy mix has been slowed by a U.S. energy policy that seems to many to be driven by politics. The author will review the history of power and energy to put all of the above in context and will look at possible future developments. He will propose what he believes to be an idealized energy policy that could result in an optimum system that would be arrived at democratically. PMID:22788100

  5. Energy supplies and future engines for land, sea, and air.

    PubMed

    Wilson, David Gordon

    2012-06-01

    The years 2012 and beyond seem likely to record major changes in energy use and power generation. The Japanese tsunami has resulted in large countries either scaling back or abolishing the future use of nuclear energy. The discovery of what seems like vast amounts of economically deliverable natural gas has many forecasting a rapid switch from coal- to gas-fired generating plants. On the other hand, environmentalists have strong objections to the production of natural gas and of petroleum by hydraulic fracturing from shale, or by extraction of heavy oil. They believe that global warming from the use of fossil fuels is now established beyond question. There has been rapid progress in the development of alternative energy supplies, particularly from on-shore and off-shore wind. Progress toward a viable future energy mix has been slowed by a U.S. energy policy that seems to many to be driven by politics. The author will review the history of power and energy to put all of the above in context and will look at possible future developments. He will propose what he believes to be an idealized energy policy that could result in an optimum system that would be arrived at democratically.

  6. Air-sea interaction with SSM/I and altimeter

    NASA Technical Reports Server (NTRS)

    1985-01-01

    A number of important developments in satellite remote sensing techniques have occurred recently which offer the possibility of studying over vast areas of the ocean the temporally evolving energy exchange between the ocean and the atmosphere. Commencing in spring of 1985, passive and active microwave sensors that can provide valuable data for scientific utilization will start to become operational on Department of Defense (DOD) missions. The passive microwave radiometer can be used to estimate surface wind speed, total air column humidity, and rain rate. The active radar, or altimeter, senses surface gravity wave height and surface wind speed.

  7. Impacts of air-sea exchange coefficients on snowfall events over the Korean Peninsula

    NASA Astrophysics Data System (ADS)

    Kang, Jung-Yoon; Kwon, Young Cheol

    2016-08-01

    Snowfall over the Korean Peninsula is mainly associated with air mass transformation by the fluxes across the air-sea interface during cold-air outbreaks over the warm Yellow Sea. The heat and momentum exchange coefficients in the surface flux parameterization are key parameters of flux calculations across the air-sea interface. This study investigates the effects of the air-sea exchange coefficients on the simulations of snowfall events over the Korean Peninsula using the Weather Research and Forecasting (WRF) model. Two snowfall cases are selected for this study. One is a heavy snowfall event that took place on January 4, 2010, and the other is a light snowfall event that occurred on December 23-24, 2011. Several sensitivity tests are carried out with increased and decreased heat and momentum exchange coefficients. The domain-averaged precipitation is increased (decreased) with increased (decreased) heat exchange coefficient because the increased (decreased) surface heat flux leads to more (less) moist conditions in the low level of the atmosphere. On the other hand, the domain-averaged precipitation is decreased (increased) with increased (decreased) momentum exchange coefficient because the increased (decreased) momentum coefficient causes reduction (increase) of wind speed and heat flux. The variation of precipitation in the heat exchange coefficient experiments is much larger than that in the momentum exchange coefficient experiments because the change of heat flux has a more direct impact on moisture flux and snowfall amount, while the change of momentum flux has a rather indirect impact via wind speed changes. The low-pressure system is intensified and moves toward North when the heat exchange coefficient is increased because warming and moistening of the lower atmosphere contributes to destabilize the air mass, resulting in the change of precipitation pattern over the Korean Peninsula in the heat exchange coefficient experiments.

  8. Air toxics emissions from gas-fired engines

    SciTech Connect

    Meeks, H.N. Jr. )

    1992-07-01

    In 1190, 14 natural-gas-fired internal combustion engines (ICE's) in oilfield service were tested in Santa Barbara County, CA, to satisfy California air toxics legislation. The combustion exhaust was tested for formaldehyde, acetaldehyde, acrolein, benzene, toluene, xylences, naphthalene, and polycyclic aromatic hydrocarbons. The fuel was tested for aromatics to enable calculation of destruction efficiencies. Two-stroke and four-stroke engines were tested. Four-stroke engines ranging from 39 to 208 hp were used in pumping unit and constant load service. Emissions from four-stroke engines were unrelated to size and service. The two-stroke engines produced considerably higher emissions than the four-stroke engines. This paper reports that test results indicate natural-gas-fired ICE's produce toxic substances in small amounts. Formaldehyde and benzene dominated the toxic emission profile.

  9. First day of an oil spill on the open sea: early mass transfers of hydrocarbons to air and water.

    PubMed

    Gros, Jonas; Nabi, Deedar; Würz, Birgit; Wick, Lukas Y; Brussaard, Corina P D; Huisman, Johannes; van der Meer, Jan R; Reddy, Christopher M; Arey, J Samuel

    2014-08-19

    During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m(3) oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km(2) area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models.

  10. Air-Sea Spray Airborne Radar Profiler Characterizes Energy Fluxes in Hurricanes

    NASA Technical Reports Server (NTRS)

    Durden, Stephen L.; Esteban-Fermandez, D.

    2010-01-01

    A report discusses ASAP (Air-sea Spray Airborne Profiler), a dual-wavelength radar profiler that provides measurement information about the droplet size distribution (DSD) of sea-spray, which can be used to estimate heat and moisture fluxes for hurricane research. Researchers have recently determined that sea spray can have a large effect on the magnitude and distribution of the air-sea energy flux at hurricane -force wind speeds. To obtain information about the DSD, two parameters of the DSD are required; for example, overall DSD amplitude and DSD mean diameter. This requires two measurements. Two frequencies are used, with a large enough separation that the differential frequency provides size information. One frequency is 94 GHz; the other is 220 GHz. These correspond to the Rayleigh and Mie regions. Above a surface wind speed of 10 m/ s, production of sea spray grows exponentially. Both the number of large droplets and the altitude they reach are a function of the surface wind speed.

  11. Air-sea interaction in the tropical Pacific Ocean

    NASA Technical Reports Server (NTRS)

    Allison, L. J.; Steranka, J.; Holub, R. J.; Hansen, J.; Godshall, F. A.; Prabhakara, C.

    1972-01-01

    Charts of 3-month sea surface temperature (SST) anomalies in the eastern tropical Pacific Ocean were produced for the period 1949 to 1970. The anomalies along the United States and South American west coasts and in the eastern tropical Pacific appeared to be oscillating in phase during this period. Similarly, the satellite-derived cloudiness for each of four quadrants of the Pacific Ocean (130 deg E to 100 deg W, 30 deg N to 25 deg S) appeared to be oscillating in phase. In addition, a global tropical cloudiness oscillation from 30 deg N to 30 deg S was noted from 1965 to 1970, by using monthly satellite television nephanalyses. The SST anomalies were found to have a good degree of correlation both positive and negative with the following monthly geophysical parameters: (1) satellite-derived cloudiness, (2) strength of the North and South Pacific semipermanent anticyclones, (3) tropical Pacific island rainfall, and (4) Darwin surface pressure. Several strong direct local and crossequatorial relationships were noted. In particular, the high degree of correlation between the tropical island rainfall and the SST anomalies (r = +0.93) permitted the derivation of SST's for the tropical Pacific back to 1905. The close occurrence of cold tropical SST and North Pacific 700-mb positive height anomalies with central United States drought conditions was noted.

  12. Effect of air-sea coupling on the frequency distribution of intense tropical cyclones over the northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Ogata, Tomomichi; Mizuta, Ryo; Adachi, Yukimasa; Murakami, Hiroyuki; Ose, Tomoaki

    2015-12-01

    Effect of air-sea coupling on the frequency distribution of intense tropical cyclones (TCs) over the northwestern Pacific (NWP) region is investigated using an atmosphere and ocean coupled general circulation model (AOGCM). Monthly varying flux adjustment enables AOGCM to simulate both subseasonal air-sea interaction and realistic seasonal to interannual sea surface temperature (SST) variability. The maximum of intense TC distribution around 20-30°N in the AGCM shifts equatorward in the AOGCM due to the air-sea coupling. Hence, AOGCM reduces northward intense TC distribution bias seen in AGCM. Over the NWP, AOGCM-simulated SST variability is large around 20-30°N where the warm mixed layer becomes shallower rapidly. Active entrainment from subsurface water over this region causes stronger SST cooling, and hence, TC intensity decreases. These results suggest that air-sea coupling characterized by subsurface oceanic condition causes more realistic distribution of intense TCs over the NWP.

  13. Gas bubble dimensions in Archean lava flows indicate low air pressure at 2.7 Ga

    NASA Astrophysics Data System (ADS)

    Som, S. M.; Buick, R.; Hagadorn, J.; Blake, T.; Perreault, J.; Harnmeijer, J.; Catling, D. C.

    2014-12-01

    Air pressure constrains atmospheric composition, which, in turn, is linked to the Earth system through biogeochemical cycles and fluxes of volatiles from and to the Earth's interior. Previous studies have only placed maximum levels on surface air pressure for the early Earth [1]. Here, we calculate an absolute value for Archean barometric pressure using gas bubble size (vesicle) distributions in uninflated basaltic lava flows that solidified at sea level 2.7 billion years ago in the Pilbara Craton, Western Australia. These vesicles have been filled in by secondary minerals deposited during metasomatism and so are now amydules, but thin sections show that infilling did not change vesicle dimensions. Amygdule dimensions are measured using high-resolution X-ray tomography from core samples obtained from the top and bottom of the lava flows. The modal size expressed at the top and at the bottom of an uninflated flow can be linked to atmospheric pressure using the ideal gas law. Such a technique has been verified as a paleoaltimeter using Hawaiian Quaternary lava flows [2]. We use statistical methods to estimate the mean and standard deviation of the volumetric size of the amygdules by applying 'bootstrap'resampling and the Central Limit Theorem. Our data indicate a surprisingly low atmospheric pressure. Greater nitrogen burial under anaerobic conditions likely explains lower pressure. Refs: [1] Som et al. (2012) Nature 484, 359-262. D. L. Sahagian et al. (2002) J. Geol., 110, 671-685.

  14. Pleistocene slope instability of gas hydrate-laden sediment on the Beaufort Sea margin

    USGS Publications Warehouse

    Kayen, R.E.; Lee, H.J.

    1991-01-01

    In oceanic areas underlain by sediment with gas hydrate, reduction of sea level initiates disassociation along the base of the gas hydrate, which, in turn, causes the release of large volumes of gas into the sediment and creates excess pore-fluid pressures and reduced slope stability. Fluid diffusion properties dominate the disassociation process in fine-grained marine sediment. Slope failure appears likely for this sediment type on moderate slopes unless pressures can be adequately vented away from the gas hydrate base. Pleistocene eustatic-sea level regressions, likely triggered seafloor landslides on the continental slope of the Beaufort Sea and other margins where gas hydrate is present in seafloor sediment. -from Authors

  15. Intense air-sea exchange and heavy rainfall: impact of the northern Adriatic SST

    NASA Astrophysics Data System (ADS)

    Stocchi, P.; Davolio, S.

    2016-02-01

    Over the northern Adriatic basin, intense air-sea interactions are often associated with heavy precipitation over the mountainous areas surrounding the basin. In this study, a high-resolution mesoscale model is employed to simulate three severe weather events and to evaluate the effect of the sea surface temperature on the intensity and location of heavy rainfall. The sensitivity tests show that the impact of SST varies among the events and it mainly involves the modification of the PBL characteristics and thus the flow dynamics and its interaction with the orography.

  16. Use of exhaust gas as sweep flow to enhance air separation membrane performance

    DOEpatents

    Dutart, Charles H.; Choi, Cathy Y.

    2003-01-01

    An intake air separation system for an internal combustion engine is provided with purge gas or sweep flow on the permeate side of separation membranes in the air separation device. Exhaust gas from the engine is used as a purge gas flow, to increase oxygen flux in the separation device without increasing the nitrogen flux.

  17. Contribution of tropical cyclones to the air-sea CO2 flux: A global view

    NASA Astrophysics Data System (ADS)

    LéVy, M.; Lengaigne, M.; Bopp, L.; Vincent, E. M.; Madec, G.; Ethé, C.; Kumar, D.; Sarma, V. V. S. S.

    2012-06-01

    Previous case studies have illustrated the strong local influence of tropical cyclones (TCs) on CO2 air-sea flux ? suggesting that they can significantly contribute to the global ? In this study, we use a state-of-the art global ocean biochemical model driven by TCs wind forcing derived from a historical TCs database, allowing to sample the ? response under 1663 TCs. Our results evidence a very weak contribution of TCs to global ? one or two order of magnitude smaller than previous estimates extrapolated from case studies. This result arises from several competing effects involved in the ? response to TCs, not accounted for in previous studies. While previous estimates have hypothesized the ocean to be systematically oversaturated in CO2 under TCs, our results reveal that a similar proportion of TCs occur over oversaturated regions (i.e. the North Atlantic, Northeast Pacific and the Arabian Sea) and undersaturated regions (i.e. Westernmost North Pacific, South Indian and Pacific Ocean). Consequently, by increasing the gas exchange coefficient, TCs can generate either instantaneous CO2 flux directed from the ocean to the atmosphere (efflux) or the opposite (influx), depending on the CO2 conditions at the time of the TC passage. A large portion of TCs also occurs over regions where the ocean and the atmosphere are in near equilibrium, resulting in very weak instantaneous fluxes. Previous estimates also did not account for any asynchronous effect of TCs on ? during several weeks after the storm, oceanic pCO2 is reduced in response to vertical mixing, which systematically causes an influx anomaly. This implies that, contrary to previous estimates, TCs weakly affect the CO2 efflux when they blow over supersaturated areas because the instantaneous storm wind effect and post-storm mixing effect oppose with each other. In contrast, TCs increase the CO2 influx in undersaturated conditions because the two effects add up. These compensating effects result in a very weak

  18. Influence of Arctic sea-ice and greenhouse gas concentration change on the West African Monsoon.

    NASA Astrophysics Data System (ADS)

    Monerie, Paul-Arthur; Oudar, Thomas; Sanchez-Gomez, Emilia; Terray, Laurent

    2016-04-01

    The Sahelian precipitation are projected to increase in the CNRM-CM5 coupled climate model due to a strengthening of the land-Sea temperature gradient, the increase in the North Atlantic temperature and the deepening of the Heat Low. Arctic Sea-Ice loss impacts the low-level atmospheric circulation through a decrease in the northward heat transport. Some authors have linked the sea-ice loss to a poleward shift of the InterTropical Convergence Zone. Within the CMIP5 models the effect of these mechanisms are not distinguishable and it is difficult to understand the effect of the Arctic sea-ice loss on the West African Monsoon so far. We performed several sensitivity experiments with the CNRM-CM5 coupled climate models by modifying the arctic sea-ice extent and/or the greenhouse gas concentration. We then investigated separately the impact of Arctic sea-ice loss and greenhouse gas concentration increases on the West African Monsoon. The increase in greenhouse gas explains the northward shift and the strengthening of the monsoon. Its effect is stronger with a sea-ice free Arctic that leads to an increase in North Atlantic temperature and in Sahelian precipitation at the end of the rainy season (September-October). We argue that the decrease in sea-ice extent, in the context of the global warming, may moistens the Sahel during the rainy season by changing the pressure, winds and moisture fluxes at low-level.

  19. The Air-Sea Interface and Surface Stress under Tropical Cyclones

    NASA Astrophysics Data System (ADS)

    Soloviev, Alexander; Lukas, Roger; Donelan, Mark; Ginis, Isaac

    2013-04-01

    Air-sea interaction dramatically changes from moderate to very high wind speed conditions (Donelan et al. 2004). Unresolved physics of the air-sea interface are one of the weakest components in tropical cyclone prediction models. Rapid disruption of the air-water interface under very high wind speed conditions was reported in laboratory experiments (Koga 1981) and numerical simulations (Soloviev et al. 2012), which resembled the Kelvin-Helmholtz instability at an interface with very large density difference. Kelly (1965) demonstrated that the KH instability at the air-sea interface can develop through parametric amplification of waves. Farrell and Ioannou (2008) showed that gustiness results in the parametric KH instability of the air-sea interface, while the gusts are due to interacting waves and turbulence. The stochastic forcing enters multiplicatively in this theory and produces an exponential wave growth, augmenting the growth from the Miles (1959) theory as the turbulence level increases. Here we complement this concept by adding the effect of the two-phase environment near the mean interface, which introduces additional viscosity in the system (turning it into a rheological system). The two-phase environment includes air-bubbles and re-entering spray (spume), which eliminates a portion of the wind-wave wavenumber spectrum that is responsible for a substantial part of the air sea drag coefficient. The previously developed KH-type interfacial parameterization (Soloviev and Lukas 2010) is unified with two versions of the wave growth model. The unified parameterization in both cases exhibits the increase of the drag coefficient with wind speed until approximately 30 m/s. Above this wind speed threshold, the drag coefficient either nearly levels off or even slightly drops (for the wave growth model that accounts for the shear) and then starts again increasing above approximately 65 m/s wind speed. Remarkably, the unified parameterization reveals a local minimum

  20. Bomb radiocarbon in the Red Sea: A medium-scale gas exchange experiment

    SciTech Connect

    Cember, R.

    1989-02-15

    The history of bomb-produced radiocarbon in the surface waters of the Red Sea and the western Gulf of Aden was reconstructed from annual growth bands of corals. Gulf of Aden surface water entering the Red Sea and flowing to the north at the surface of the Red Sea becomes progressively enriched in bomb /sup 14/C by air-sea exchange of carbon dioxide. With physical oceanographic observations and analysis as the basis of a simple model, this progressive northward enrichment can be used to calculate a mean invasionn flux for CO/sub 2/ across the Red Sea surface. The CO/sub 2/ invasion flux so calculated is 8 mol/m/sup 2//yr with an uncertainty of approximately 2 mol/m/sup 2//yr. When combined with the extensive historical observations of wind speeds in the Red Sea, the calculated CO/sub 2/ invasion flux supports the empirical relationship between CO/sub 2/ invasion and wind speed proposed by other workers. Sea surface pCO/sub 2/ was measured at seven stations along the length of the Red Sea in January 1985. These pCO/sub 2/ data show that in midwinter the net flux of CO/sub 2/ across the Red Sea surface (i.e. the difference between the invasion and evasion fluxes) is approximately zero for the Red Sea as a whole. copyright American Geophysical Union 1989

  1. Size distribution of oceanic air bubbles entrained in sea-water by wave-breaking

    NASA Technical Reports Server (NTRS)

    Resch, F.; Avellan, F.

    1982-01-01

    The size of oceanic air bubbles produced by whitecaps and wave-breaking is determined. The production of liquid aerosols at the sea surface is predicted. These liquid aerosols are at the origin of most of the particulate materials exchanged between the ocean and the atmosphere. A prototype was designed and built using an optical technique based on the principle of light scattering at an angle of ninety degrees from the incident light beam. The output voltage is a direct function of the bubble diameter. Calibration of the probe was carried out within a range of 300 microns to 1.2 mm. Bubbles produced by wave-breaking in a large air-sea interaction simulating facility. Experimental results are given in the form of size spectrum.

  2. Numerical simulation of changes in tropical cyclone intensity using a coupled air-sea model

    NASA Astrophysics Data System (ADS)

    Duan, Yihong; Wu, Rongsheng; Yu, Runling; Liang, Xudong

    2013-10-01

    A coupled air-sea model for tropical cyclones (TCs) is constructed by coupling the Pennsylvania State University/National Center for Atmospheric Research mesoscale model (MM5) with the Princeton Ocean Model. Four numerical simulations of tropical cyclone development have been conducted using different configurations of the coupled model on the f-plane. When coupled processes are excluded, a weak initial vortex spins up into a mature symmetric TC that strongly resembles those observed and simulated in prior research. The coupled model reproduces the reduction in sea temperature induced by the TC reasonably well, as well as changes in the minimum central pressure of the TC that result from negative atmosphere-ocean feedbacks. Asymmetric structures are successfully simulated under conditions of uniform environmental flow. The coupled ocean-atmosphere model is suitable for simulating air-sea interactions under TC conditions. The effects of the ocean on the track of the TC and changes in its intensity under uniform environmental flow are also investigated. TC intensity responds nonlinearly to sea surface temperature (SST). The TC intensification rate becomes smaller once the SST exceeds a certain threshold. Oceanic stratification also influences TC intensity, with stronger stratification responsible for a larger decrease in intensity. The value of oceanic enthalpy is small when the ocean is weakly stratified and large when the ocean is strongly stratified, demonstrating that the oceanic influence on TC intensity results not only from SST distributions but also from stratification. Air-sea interaction has only a slight influence on TC movement in this model.

  3. Gas hydrate formation in the deep sea: In situ experiments with controlled release of methane, natural gas, and carbon dioxide

    USGS Publications Warehouse

    Brewer, P.G.; Orr, F.M.; Friederich, G.; Kvenvolden, K.A.; Orange, D.L.

    1998-01-01

    We have utilized a remotely operated vehicle (ROV) to initiate a program of research into gas hydrate formation in the deep sea by controlled release of hydrocarbon gases and liquid CO2 into natural sea water and marine sediments. Our objectives were to investigate the formation rates and growth patterns of gas hydrates in natural systems and to assess the geochemical stability of the reaction products over time. The novel experimental procedures used the carrying capacity, imaging capability, and control mechanisms of the ROV to transport gas cylinders to depth and to open valves selectively under desired P-T conditions to release the gas either into contained natural sea water or into sediments. In experiments in Monterey Bay, California, at 910 m depth and 3.9??C water temperature we find hydrate formation to be nearly instantaneous for a variety of gases. In sediments the pattern of hydrate formation is dependent on the pore size, with flooding of the pore spaces in a coarse sand yielding a hydrate cemented mass, and gas channeling in a fine-grained mud creating a veined hydrate structure. In experiments with liquid CO2 the released globules appeared to form a hydrate skin as they slowly rose in the apparatus. An initial attempt to leave the experimental material on the sea floor for an extended period was partially successful; we observed an apparent complete dissolution of the liquid CO2 mass, and an apparent consolidation of the CH4 hydrate, over a period of about 85 days.

  4. Gulf of Mexico Air/Sea Interaction: Measurements and Initial Data Characterization

    NASA Astrophysics Data System (ADS)

    MacDonald, C.; Huang, C. H.; Roberts, P. T.; Bariteau, L.; Fairall, C. W.; Gibson, W.; Ray, A.

    2011-12-01

    Corporate, government, and university researchers collaborated to develop an atmospheric boundary layer environmental observations program on an offshore platform in the Gulf of Mexico. The primary goals of this project were to provide data to (1) improve our understanding of boundary layer processes and air-sea interaction over the Gulf of Mexico; (2) improve regional-scale meteorological and air quality modeling; and (3) provide a framework for advanced offshore measurements to support future needs such as emergency response, exploration and lease decisions, wind energy research and development, and meteorological and air quality forecasting. In October 2010, meteorological and oceanographic sensors were deployed for an extended period (approximately 12 months) on a Chevron service platform (ST 52B, 90.5W, 29N) to collect boundary layer and sea surface data sufficient to support these objectives. This project has significant importance given the large industrial presence in the Gulf, sizeable regional population nearby, and the recognized need for precise and timely pollutant forecasts. Observations from this project include surface meteorology; sodar marine boundary layer winds; microwave radiometer profiles of temperature, relative humidity, and liquid water; ceilometer cloud base heights; water temperature and current profiles; sea surface temperature; wave height statistics; downwelling solar and infrared radiation; and air-sea turbulent momentum and heat fluxes. This project resulted in the collection of an unprecedented set of boundary layer measurements over the Gulf of Mexico that capture the range of meteorological and oceanographic interactions and processes that occur over an entire year. This presentation will provide insight into the logistical and scientific issues associated with the deployment and operations of unique measurements in offshore areas and provide results from an initial data analysis of boundary layer processes over the Gulf of

  5. Small Autonomous Air/Sea System Concepts for Coast Guard Missions

    NASA Technical Reports Server (NTRS)

    Young, Larry A.

    2005-01-01

    A number of small autonomous air/sea system concepts are outlined in this paper that support and enhance U.S. Coast Guard missions. These concepts draw significantly upon technology investments made by NASA in the area of uninhabited aerial vehicles and robotic/intelligent systems. Such concepts should be considered notional elements of a greater as-yet-not-defined robotic system-of-systems designed to enable unparalleled maritime safety and security.

  6. Direct measurements of air-sea CO2 exchange over a coral reef

    NASA Astrophysics Data System (ADS)

    McGowan, Hamish A.; MacKellar, Mellissa C.; Gray, Michael A.

    2016-05-01

    Quantification of CO2 exchange with the atmosphere over coral reefs has relied on microscale measurements of pCO2 gradients across the air-sea interfacial boundary; shipboard measurements of air-sea CO2 exchange over adjacent ocean inferred to represent over reef processes or ecosystem productivity modeling. Here we present by way of case study the first direct measurements of air-sea CO2 exchange over a coral reef made using the eddy covariance method. Research was conducted during the summer monsoon over a lagoonal platform reef in the southern Great Barrier Reef, Australia. Results show the reef flat to be a net source of CO2 to the atmosphere of similar magnitude as coastal lakes, while adjacent shallow and deep lagoons were net sinks as was the surrounding ocean. This heterogeneity in CO2 exchange with the atmosphere confirms need for spatially representative direct measurements of CO2 over coral reefs to accurately quantify their role in atmospheric carbon budgets.

  7. Review of Deep-Sea Ecology and Monitoring as They Relate to Deep-Sea Oil and Gas Operations

    SciTech Connect

    Kropp, Roy K.

    2004-01-30

    This review summarizes available information concerning deep-sea benthic ecology and how that information might be used to monitor and eventually reduce the potential impacts resulting from oil and gas production activities. The paper provides a brief overview of deep-sea ecology and benthic faunal groups and summarizes some of the physical and biological features that may be important in evaluating potential impacts. In addition, presented is a synopsis of issues related to the design of a sampling program and a discussion of analytical considerations related to the uncertain knowledge of deep faunas. Also included is an overview of some of the variety of sampling techniques and equipment available to study the deep sea. The review concludes with management considerations and recommendations.

  8. The impact of air-fuel mixture composition on SI engine performance during natural gas and producer gas combustion

    NASA Astrophysics Data System (ADS)

    Przybyła, G.; Postrzednik, S.; Żmudka, Z.

    2016-09-01

    The paper summarizers results of experimental tests of SI engine fuelled with gaseous fuels such as, natural gas and three mixtures of producer gas substitute that simulated real producer gas composition. The engine was operated under full open throttle and charged with different air-fuel mixture composition (changed value of air excess ratio). The spark timing was adjusted to obtain maximum brake torque (MBT) for each fuel and air-fuel mixture. This paper reports engine indicated performance based on in-cylinder, cycle resolved pressure measurements. The engine performance utilizing producer gas in terms of indicated efficiency is increased by about 2 percentage points when compared to fuelling with natural gas. The engine power de-rating when producer gas is utilized instead the natural gas, varies from 24% to 28,6% under stoichiometric combustion conditions. For lean burn (λ=1.5) the difference are lower and varies from 22% to 24.5%.

  9. Distribution and Sea-to-air Flux of Nitrous Oxide in the East China Sea during the Summer of 2013

    NASA Astrophysics Data System (ADS)

    Wang, Lan; Zhang, Guiling; Zhu, Zhuoyi; Li, Jia; Liu, Sumei; Ye, Wangwang; Han, Yu

    2016-07-01

    Dissolved nitrous oxide (N2O) at different depths of 73 stations in the Changjiang (Yangtze River) Estuary and the East China Sea (ECS) were determined from August 4 to 31 of 2013, and the sea-to-air fluxes of N2O were also estimated in this study. N2O concentrations in the surface waters ranged from 6.33 to 44.40 nmol L-1 with an average of (9.27±4.30) nmol L-1 and the values in the bottom waters ranged from 5.19 to 26.98 nmol L-1 with an average of (11.87±3.71) nmol L-1. The concentrations of N2O decreased with distance from the Changjiang Estuary to the open sea. The vertical distributions of N2O indicated great spatial variations. A region of significant bottom-water hypoxia, with oxygen concentration less than 1.5 mg L-1, occurred at the north of the ECS, and increased bottom N2O concentrations was observed. Frequent vertical mixing may enhance the emission of N2O from this hypoxic area. N2O in the surface waters of all stations were over-saturated, and the N2O saturations ranged from 106% to 658%, with an average of (149±62)%. We estimated the sea-to-air fluxes of N2O as (30.6±59.1) μmol m-2 d-1 from the Changjiang Estuary, (9.8±8.8) μmol m-2 d-1 from the coastal and shelf, and (21.0±12.7) μmol m-2 d-1 from the continental slope using the Wanninkhof 1992 equation, (24.9±47.2) μmol m-2 d-1, (8.0±6.7) μmol m-2 d-1 and (16.5±9.6) μmol m-2 d-1 using the Nightingale 2000 equation, respectively. N2O emission from the ECS was estimated to be about (8.2-16.0)×10-2 Tg-N2O yr-1, suggesting that the ECS was a significant net source of atmospheric N2O.

  10. Drilling gas hydrates with the sea floor drill rig MARUM-MeBo

    NASA Astrophysics Data System (ADS)

    Freudenthal, Tim; Bohrmann, Gerhard; Wefer, Gerold

    2015-04-01

    Large amounts of methane are bound in marine gas hydrate deposits. Local conditions like pressure, temperature, gas and pore water compositions define the boundaries of gas hydrate stability within the ocean sediments. Depending on those conditions gas hydrates can occur within marine sediments at depth down to several hundreds of meters up to sea floor. These oceanic methane deposits are widespread along continental margins. By forming cement in otherwise soft sediments gas hydrates are stabilizing the seafloor on continental slopes. Drilling operations are required for understanding the distribution of gas hydrates as well as for sampling them to study the composition, microstructure and its geomechanical and geophysical properties. The sea floor drill rig MARUM-MeBo200 has the capability to drill down to 200 m below sea floor well within the depth of major gas hydrate occurrences at continental margins. This drill rig is a transportable sea floor drill rig that can be deployed from a variety of multi-purpose research vessels. It is deployed on the sea bed and controlled from the vessel. It is the second generation MeBo (Freudenthal and Wefer, 2013) and was developed from 2011 to 2014 by MARUM in cooperation with BAUER Maschinen GmbH. Long term experiences with the first generation MeBo70 that was operated since 2005 on 15 research expeditions largely contributed to the development of MeBo200. It was first tested in October 2014 from the research vessel RV SONNE in the North Sea. In this presentation the suitability of MARUM-MeBo for drilling marine gas hydrates is discussed. We report on experiences drilling gas hydrates on two research expeditions with MeBo70. A research expedition for sampling gas hydrates in the Danube Paleodelta with MeBo200 as well as technical developments for improving the suitability of MeBo for gas hydrate exploration works are planned within the project SUGAR3 funded by the Federal Government for Economy and Energy (BMWi). Freudenthal

  11. Volcanic gas emissions and their effect on ambient air character

    SciTech Connect

    Sutton, A.J.; Elias, T.

    1994-01-01

    This bibliography was assembled to service an agreement between Department of Energy and the USGS to provide a body of references and useful annotations for understanding background gas emissions from Kilauea volcano. The current East Rift Zone (ERZ) eruption of Kilauea releases as much as 500,000 metric tonnes of SO{sub 2} annually, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl, and HF. Primary degassing locations on Kilauea are located in the summit caldera and along the middle ERZ. The effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Because of this complexity, we organized the bibliography into three main sections: (1) characterizing gases as they leave the edifice; (2) characterizing gases and chemical reaction products away from degassing sources; and (3) Hawaii Island meteorology.

  12. An analysis of observed large air-sea temperature differences in tropical cyclones

    SciTech Connect

    Kepert, J.D.

    1994-12-31

    At high wind speeds over the sea, the lower part of the atmospheric boundary layer becomes filled with spray. In recent years, much attention has been devoted to the question of whether the evaporation from these droplets contributes significantly to the total sea-air evaporative flux under such conditions. Direct observations of turbulent fluxes of heat, moisture and momentum over the sea at moderately high wind speeds were taken during HEXOS Main Experiment (HEXMAX). (HEXOS is the Humidity Exchange Over the Sea program.) An analysis of these results shows that the neutral transfer coefficient is nearly constant with wind speed, up to about 18 m/s, albeit with considerable scatter about the mean. Here the author describes a preliminary investigation of the possible effects evaporation of sea spray could have on the vertical structure of the atmospheric boundary layer at high wind speeds. The remainder of the paper consists of a brief discussion of a radiosonde ascent launched from a ship during a tropical cyclone, a description of the turbulent closure model used to investigate the role of the various physical processes, followed by a discussion of the model results and their relationship to the observation.

  13. Effect of Air-Sea coupling on the Frequency Distribution of Intense Tropical Cyclones over the Northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Ogata, Tomomichi; Mizuta, Ryo; Adachi, Yukimasa; Murakami, Hiroyuki; Ose, Tomomaki

    2016-04-01

    Effect of air-sea coupling on the frequency distribution of intense tropical cyclones (TCs) over the northwestern Pacific (NWP) region is investigated using an atmosphere and ocean coupled general circulation model (AOGCM). Monthly varying flux adjustment enables AOGCM to simulate both subseasonal air-sea interaction and realistic seasonal to interannual SST variability. The maximum of intense TC distribution around 20-30°N in the AGCM shifts equatorward in the AOGCM due to the air-sea coupling. Hence AOGCM reduces northward intense TC distribution bias seen in AGCM. Over the NWP, AOGCM-simulated SST variability is large around 20-30°N where the warm mixed layer becomes shallower rapidly. Active entrainment from subsurface water over this region causes stronger SST cooling and hence TC intensity decreases. These results suggest that air-sea coupling characterized by subsurface oceanic condition causes more realistic distribution of intense TCs over the NWP.

  14. Gas hydrates from the continental slope, offshore Sakhalin Island, Okhotsk Sea

    USGS Publications Warehouse

    Ginsburg, G.D.; Soloviev, V.A.; Cranston, R.E.; Lorenson, T.D.; Kvenvolden, K.A.

    1993-01-01

    Ten gas-vent fields were discovered in the Okhotsk Sea on the northeast continental slope offshore from Sakhalin Island in water depths of 620-1040 m. At one vent field, estimated to be more than 250 m across, gas hydrates, containing mainly microbial methane (??13C = -64.3???), were recovered from subbottom depths of 0.3-1.2 m. The sediment, having lenses and bedded layers of gas hydrate, contained 30-40% hydrate per volume of wet sediment. Although gas hydrates were not recovered at other fields, geochemical and thermal measurements suggest that gas hydrates are present. ?? 1993 Springer-Verlag.

  15. An air bearing system for small high speed gas turbines

    NASA Astrophysics Data System (ADS)

    Turner, A. B.; Davies, S. J.; Nimir, Y. L.

    1994-03-01

    This paper describes the second phase of an experimental program concerning the application of air bearings to small turbomachinery test rigs and small gas turbines. The first phase examined externally pressurized (EP) journal bearings, with a novel EP thrust bearing, for application to 'warm air' test rigs, and was entirely successful at rotational speeds in excess of 100,000 rpm. This second phase examined several designs of tilting pad-spiring journal bearings, one with a novel form of externally pressurized pad, but all using the original EP thrust bearing. The designs tested are described, including some oscillogram traces, for tests up to a maximum of 70,000 rpm; the most successful using a carbon pad-titanium beam spring arrangement. The thrust bearing which gave trouble-free operation throughout, is also described. The results of an original experiment to measure the 'runway speed' of a radial inflow turbine are also presented, which show that overspeeds of 58 percent above the design speed can result from free-power turbine coupling failure.

  16. Bering Sea summary report: Outer Continental Shelf oil and gas activities in the Bering Sea and their onshore impacts

    SciTech Connect

    Deis, J.; Pierson, R.; Kurz, F.

    1983-09-01

    Two federal offshore oil-and-gas lease sales have been held in the Bering Sea Subregion. Lease Sale 57, Norton Basin, was held on March 15, 1983. Lease Sale 70, St. George Basin, was held on April 12, 1983. The sale offered 479 tracts, of which 97 received bids. The Department of the Interior has indicated that it will accept 96 of the 97 high bids; however, to date, leases have not been awarded. The Department of the Interior was enjoined from issuing leases by the US District Court of Alaska because of possible impacts from postlease preliminary seismic activities on gray and right whales. In accordance with the Court's ruling, leases cannot be issued until the completion of a supplemental environmental impact statement, which is anticipated to occur in November 1983. Six lease offerings in the Bering Sea Subregion are scheduled through 1987. Six deep stratigraphic test wells are the only wells drilled to date in the Bering Sea Subregion. To date, oil companies have not submitted exploration plans for the Norton Basin Planning Area. Exploration in Norton Basin could begin in the summer of 1984, at the earliest. Exploration plans cannot be submitted for the St. George Basin Planning Area until the leases are awarded. At this time, various onshore areas are being considered as possible support bases for offshore oil-and-gas exploration. At this stage, before exploratory drilling has occurred and in the absence of a commercial discovery, plans for transporting petroleum from the Bering Sea to markets in the United States are unclear. The current estimates of risked resources for lands leased in Lease Sale 57, Norton Basin, are 33 million barrels of oil and 110 billion cubic feet of gas. Lease Sale 70, St. George Basin, estimates of risked resources for leased lands are 27 million barrels of oil and 310 billion cubic feet of gas. 55 references, 10 figures, 3 tables.

  17. Experimental study of wood downdraft gasification for an improved producer gas quality through an innovative two-stage air and premixed air/gas supply approach.

    PubMed

    Jaojaruek, Kitipong; Jarungthammachote, Sompop; Gratuito, Maria Kathrina B; Wongsuwan, Hataitep; Homhual, Suwan

    2011-04-01

    This study conducted experiments on three different downdraft gasification approaches: single stage, conventional two-stage, and an innovative two-stage air and premixed air/gas supply approach. The innovative two-stage approach has two nozzle locations, one for air supply at combustion zone and the other located at the pyrolysis zone for supplying the premixed gas (air and producer gas). The producer gas is partially bypassed to mix with air and supplied to burn at the pyrolysis zone. The result shows that producer gas quality generated by the innovative two-stage approach improved as compared to conventional two-stage. The higher heating value (HHV) increased from 5.4 to 6.5 MJ/Nm(3). Tar content in producer gas reduced to less than 45 mg/Nm(3). With this approach, gas can be fed directly to an internal combustion engine. Furthermore, the gasification thermal efficiency also improved by approximately 14%. The approach gave double benefits on gas qualities and energy savings. PMID:21292477

  18. Experimental study of wood downdraft gasification for an improved producer gas quality through an innovative two-stage air and premixed air/gas supply approach.

    PubMed

    Jaojaruek, Kitipong; Jarungthammachote, Sompop; Gratuito, Maria Kathrina B; Wongsuwan, Hataitep; Homhual, Suwan

    2011-04-01

    This study conducted experiments on three different downdraft gasification approaches: single stage, conventional two-stage, and an innovative two-stage air and premixed air/gas supply approach. The innovative two-stage approach has two nozzle locations, one for air supply at combustion zone and the other located at the pyrolysis zone for supplying the premixed gas (air and producer gas). The producer gas is partially bypassed to mix with air and supplied to burn at the pyrolysis zone. The result shows that producer gas quality generated by the innovative two-stage approach improved as compared to conventional two-stage. The higher heating value (HHV) increased from 5.4 to 6.5 MJ/Nm(3). Tar content in producer gas reduced to less than 45 mg/Nm(3). With this approach, gas can be fed directly to an internal combustion engine. Furthermore, the gasification thermal efficiency also improved by approximately 14%. The approach gave double benefits on gas qualities and energy savings.

  19. Air-water gas exchange by waving vegetation stems

    NASA Astrophysics Data System (ADS)

    Foster-Martinez, M. R.; Variano, E. A.

    2016-07-01

    Exchange between wetland surface water and the atmosphere is driven by a variety of motions, ranging from rainfall impact to thermal convection and animal locomotion. Here we examine the effect of wind-driven vegetation movement. Wind causes the stems of emergent vegetation to wave back and forth, stirring the water column and facilitating air-water exchange. To understand the magnitude of this effect, a gas transfer velocity (k600 value) was measured via laboratory experiments. Vegetation waving was studied in isolation by mechanically forcing a model canopy to oscillate at a range of frequencies and amplitudes matching those found in the field. The results show that stirring due to vegetation waving produces k600 values from 0.55 cm/h to 1.60 cm/h. The dependence of k600 on waving amplitude and frequency are evident from the laboratory data. These results indicate that vegetation waving has a nonnegligible effect on gas transport; thus, it can contribute to a mechanistic understanding of the fluxes underpinning biogeochemical processes.

  20. Gas and liquid measurements in air-water bubbly flows

    SciTech Connect

    Zhou, X.; Doup, B.; Sun, X.

    2012-07-01

    Local measurements of gas- and liquid-phase flow parameters are conducted in an air-water two-phase flow loop. The test section is a vertical pipe with an inner diameter of 50 mm and a height of 3.2 m. The measurements are performed at z/D = 10. The gas-phase measurements are performed using a four-sensor conductivity probe. The data taken from this probe are processed using a signal processing program to yield radial profiles of the void fraction, bubble velocity, and interfacial area concentration. The velocity measurements of the liquid-phase are performed using a state-of-the-art Particle Image Velocimetry (PIV) system. The raw PIV images are acquired using fluorescent particles and an optical filtration device. Image processing is used to remove noise in the raw PIV images. The statistical cross correlation is introduced to determine the axial velocity field and turbulence intensity of the liquid-phase. Measurements are currently being performed at z/D = 32 to provide a more complete data set. These data can be used for computational fluid dynamic model development and validation. (authors)

  1. Atmospheric emissions and air quality impacts from natural gas production and use.

    PubMed

    Allen, David T

    2014-01-01

    The US Energy Information Administration projects that hydraulic fracturing of shale formations will become a dominant source of domestic natural gas supply over the next several decades, transforming the energy landscape in the United States. However, the environmental impacts associated with fracking for shale gas have made it controversial. This review examines emissions and impacts of air pollutants associated with shale gas production and use. Emissions and impacts of greenhouse gases, photochemically active air pollutants, and toxic air pollutants are described. In addition to the direct atmospheric impacts of expanded natural gas production, indirect effects are also described. Widespread availability of shale gas can drive down natural gas prices, which, in turn, can impact the use patterns for natural gas. Natural gas production and use in electricity generation are used as a case study for examining these indirect consequences of expanded natural gas availability.

  2. Atmospheric emissions and air quality impacts from natural gas production and use.

    PubMed

    Allen, David T

    2014-01-01

    The US Energy Information Administration projects that hydraulic fracturing of shale formations will become a dominant source of domestic natural gas supply over the next several decades, transforming the energy landscape in the United States. However, the environmental impacts associated with fracking for shale gas have made it controversial. This review examines emissions and impacts of air pollutants associated with shale gas production and use. Emissions and impacts of greenhouse gases, photochemically active air pollutants, and toxic air pollutants are described. In addition to the direct atmospheric impacts of expanded natural gas production, indirect effects are also described. Widespread availability of shale gas can drive down natural gas prices, which, in turn, can impact the use patterns for natural gas. Natural gas production and use in electricity generation are used as a case study for examining these indirect consequences of expanded natural gas availability. PMID:24498952

  3. Distributions and sea-to-air fluxes of chloroform, trichloroethylene, tetrachloroethylene, chlorodibromomethane and bromoform in the Yellow Sea and the East China Sea during spring.

    PubMed

    He, Zhen; Yang, Gui-Peng; Lu, Xiao-Lan; Zhang, Hong-Hai

    2013-06-01

    Halocarbons including chloroform (CHCl3), trichloroethylene (C2HCl3), tetrachloroethylene (C2Cl4), chlorodibromomethane (CHBr2Cl) and bromoform (CHBr3) were measured in the Yellow Sea (YS) and the East China Sea (ECS) during spring 2011. The influences of chlorophyll a, salinity and nutrients on the distributions of these gases were examined. Elevated levels of these gases in the coastal waters were attributed to anthropogenic inputs and biological release by phytoplankton. The vertical distributions of these gases in the water column were controlled by different source strengths and water masses. Using atmospheric concentrations measured in spring 2012 and seawater concentrations obtained from this study, the sea-to-air fluxes of these gases were estimated. Our results showed that the emissions of C2HCl3, C2Cl4, CHBr2Cl, and CHBr3 from the study area could account for 16.5%, 10.5%, 14.6%, and 3.5% of global oceanic emissions, respectively, indicating that the coastal shelf may contribute significantly to the global oceanic emissions of these gases.

  4. Sea surface carbon dioxide at the Georgia time series site (2006-2007): Air-sea flux and controlling processes

    NASA Astrophysics Data System (ADS)

    Xue, Liang; Cai, Wei-Jun; Hu, Xinping; Sabine, Christopher; Jones, Stacy; Sutton, Adrienne J.; Jiang, Li-Qing; Reimer, Janet J.

    2016-01-01

    Carbon dioxide partial pressure (pCO2) in surface seawater was continuously recorded every three hours from 18 July 2006 through 31 October 2007 using a moored autonomous pCO2 (MAPCO2) system deployed on the Gray's Reef buoy off the coast of Georgia, USA. Surface water pCO2 (average 373 ± 52 μatm) showed a clear seasonal pattern, undersaturated with respect to the atmosphere in cold months and generally oversaturated in warm months. High temporal resolution observations revealed important events not captured in previous ship-based observations, such as sporadically occurring biological CO2 uptake during April-June 2007. In addition to a qualitative analysis of the primary drivers of pCO2 variability based on property regressions, we quantified contributions of temperature, air-sea exchange, mixing, and biological processes to monthly pCO2 variations using a 1-D mass budget model. Although temperature played a dominant role in the annual cycle of pCO2, river inputs especially in the wet season, biological respiration in peak summer, and biological production during April-June 2007 also substantially influenced seawater pCO2. Furthermore, sea surface pCO2 was higher in September-October 2007 than in September-October 2006, associated with increased river inputs in fall 2007. On an annual basis this site was a moderate atmospheric CO2 sink, and was autotrophic as revealed by monthly mean net community production (NCP) in the mixed layer. If the sporadic short productive events during April-May 2007 were missed by the sampling schedule, one would conclude erroneously that the site is heterotrophic. While previous ship-based pCO2 data collected around this buoy site agreed with the buoy CO2 data on seasonal scales, high resolution buoy observations revealed that the cruise-based surveys undersampled temporal variability in coastal waters, which could greatly bias the estimates of air-sea CO2 fluxes or annual NCP, and even produce contradictory results.

  5. Hurricane Frances as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS) and SeaWinds

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This image shows Hurricane Frances as captured by instruments onboard two different satellites: the AIRS infrared instrument onboard Aqua, and the SeaWinds scatterometer onboard QuikSCAT. Both are JPL-managed instruments. AIRS data are used to create global three-dimensional maps of temperature, humidity and clouds, while scatterometers measure surface wind speed and direction over the ocean.

    The red vectors in the image show Frances' surface winds as measured by SeaWinds on QuikSCAT. The background colors show the temperature of clouds and surface as viewed in the infrared by AIRS, with cooler areas pushing to purple and warmer areas are pushing to red. The color scale on the right gives the temperatures in degrees Kelvin. (The top of the scale, 320 degrees Kelvin, corresponds to 117 degrees Fahrenheit, and the bottom, 180 degrees K is -135 degrees F.) The powerful circulation of this storm is evident from the combined data as well as the development of a clearly-defined central 'eye'. The infrared signal does not penetrate through clouds, so the light blue areas reveal the cold clouds tops associated with strong thunderstorms embedded within the storm. In cloud-free areas the infrared signal comes from Earth's surface, revealing warmer temperatures.

    The power of the SeaWinds scatterometer data set lies in its ability to generate global maps of wind speed and direction, giving us a snapshot of how the atmosphere is circulating. Weather prediction centers, including the Tropical Prediction Center - a branch of NOAA that monitors the creation of ocean-born storms, use scatterometer data to help it 'see' where these storms are brewing so that warnings can be issued and the storms, with often erratic motions, can be tracked.

    While the SeaWinds instrument isn't designed to gather hurricane data, having difficulty seeing the surface in heavy rain, it's data can be used in combination with other data sets to give us an insight into these storms. In

  6. Impacts of Air-Sea Interaction on Tropical Cyclone Track and Intensity

    NASA Technical Reports Server (NTRS)

    Wu, Liguang; Wang, Bin; Braun, Scott A.

    2004-01-01

    The influence of hurricane-ocean coupling on intensity and track of tropical cyclones (TCs) is investigated through idealized numerical experiments using a coupled hurricane-ocean model. The focus is placed on how air-sea interaction affects TC tracks and intensity. It is found that the symmetric sea surface temperature (SST) cooling is primarily responsible for the TC weakening in the coupled experiments because the induced asymmetric circulation associated with the asymmetric SST anomalies is weak and shallow. The track difference between the coupled and fixed SST experiments is generally small because of the competing processes. One is associated with the modified TC asymmetries. The asymmetric SST anomalies - weaken the surface fluxes in the rear and enhance the fluxes in the front. As a result, the enhanced diabatic heating is located on the southern side for a westward-moving TC, tending to shift the TC southward. The symmetric SST anomalies weakens the TC intensity and thus the dymmetrization process, leading to more prominent TC asymmetries. The other is associated with the weakening of the beta drift resulting from the weakening of the TC outer strength. In the coupled experiment, the weakening of the beta drift leads to a more northward shift. By adjusting the vortex outer strength of the initial vortices, the beta drift can vary while the effect of air-sea interaction changes little. Two types of track differences simulated in the previous numerical studies are obtained.

  7. Simulating Emission and Chemical Evolution of Coarse Sea-Salt Particles in the Community Multiscale Air Quality (CMAQ) Model

    EPA Science Inventory

    Chemical processing of sea-salt particles in coastal environments significantly impacts concentrations of particle components and gas-phase species and has implications for human exposure to particulate matter and nitrogen deposition to sensitive ecosystems. Emission of sea-sal...

  8. Air-sea Exchange of Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs), Organochlorine Pesticides (OCPs) and Polybrominated Diphenyl Ethers (PBDEs) in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Lammel, G. P.; Heil, A.; Kukucka, P.; Meixner, F. X.; Mulder, M. D.; Prybilova, P.; Prokes, R.; Rusina, T. S.; Song, G. Z.; Vrana, B.

    2015-12-01

    The marine atmospheric environment is a receptor for persistent organic pollutants (POPs) which are advected from sources on land, primary, such as biomass burning by-products (PAHs, dioxins), and secondary, such as volatilization from contaminated soils (PCBs, pesticides). Primary sources do not exist in the marine environment, except for PAHs (ship engines) but following previous atmospheric deposition, the sea surface may turn to a secondary source by reversal of diffusive air-sea mass exchange. No monitoring is in place. We studied the vertical fluxes of a wide range of primary and secondary emitted POPs based on measurements in air and surface seawater at a remote coastal site in the eastern Mediterranean (2012). To this end, silicon rubbers were used as passive water samplers, vertical concentration gradients were determined in air and fluxes were quantified based on Eddy covariance. Diffusive air-sea exchange fluxes of hexachlorocyclohexanes (HCHs) and semivolatile PAHs were found close to phase equilibrium, except one PAH, retene, a wood burning tracer, was found seasonally net-volatilisational. Some PCBs, p,p'-DDE, penta- and hexachlorobenzene (PeCB, HCB) were mostly net-depositional, while PBDEs were net-volatilizational. Fluxes determined at a a remote coastal site ranged -33 - +2.4 µg m-2 d-1 for PAHs and -4.0 - +0.3 µg m-2 d-1for halogenated compounds (< 0 means net-deposition, > 0 means net-volatilization). It is concluded that nowadays in open seas more pollutants are undergoing reversal of the direction of air-sea exchange. Recgional fire activity records in combination with box model simulations suggest that deposition of retene during summer is followed by a reversal of air-sea exchange. The seawater surface as secondary source of pollution should be assessed based on flux measurements across seasons and over longer time periods.

  9. Shallow Gas and Gas Hydrates in the Barents Sea Imaged by High-Resolution 3D Seismic Data

    NASA Astrophysics Data System (ADS)

    Planke, S.; Eriksen, O.; Eriksen, F. N.; Bunz, S.; Berndt, C.

    2012-12-01

    Shallow gas and gas hydrates are potential hazards for the petroleum industry, but may also represent future resources. Detailed mapping of shallow gas and gas hydrates is important to reduce drilling risks, to exploit hydrocarbon resources, and to better understand procesesse of gas migration and accumulation. We have collected two high resolution 3D seismic cubes of 10-20 km2 in areas with shallow gas in the Barents Sea. The cubes were acquired using the P-Cable system in water depths of 300-500 m with the vessel R/V Jan Mayen. The data were processed using the RadexPro software and a standard sequence including geometry, tide corrections, binning, filtering, and migration. Two main sedimentary sequences are present in the data, a sub-horizontal glacial package overlying a westward-dipping Paleogene sequence. The seabed is characterized by up to 15 m deep glacial ploughmarks. An upper regional unconformity (URU) separates the glacial and Paleogene sediments. Three levels of high-amplitude reflections are interpreted as evidence of shallow gas. Minor gas accumulations are present as semi-circular anomalies within the glacial sequence and as north-south trending anomalies just below the URU. More extensive gas accumulations are found within the Paleogene sediments, and the top gas reflections are clearly cross-cutting the dipping Paleogene sequence. Several paleo-pockmarks are interpreted within the glacial sequence, whereas no pockmarks are identified on the seafloor. The gas is interpreted to be sealed by overlying gas hydrates. Gas hydrate models show that pure methane is outside the gas hydrate stability field in the surveyed region, but within the gas hydrate stability field if methane is mixed with minor amounts of higher-order hydrocarbons (ethane and propane).

  10. Air impacts of increased natural gas acquisition, processing, and use: a critical review.

    PubMed

    Moore, Christopher W; Zielinska, Barbara; Pétron, Gabrielle; Jackson, Robert B

    2014-01-01

    During the past decade, technological advancements in the United States and Canada have led to rapid and intensive development of many unconventional natural gas plays (e.g., shale gas, tight sand gas, coal-bed methane), raising concerns about environmental impacts. Here, we summarize the current understanding of local and regional air quality impacts of natural gas extraction, production, and use. Air emissions from the natural gas life cycle include greenhouse gases, ozone precursors (volatile organic compounds and nitrogen oxides), air toxics, and particulates. National and state regulators primarily use generic emission inventories to assess the climate, air quality, and health impacts of natural gas systems. These inventories rely on limited, incomplete, and sometimes outdated emission factors and activity data, based on few measurements. We discuss case studies for specific air impacts grouped by natural gas life cycle segment, summarize the potential benefits of using natural gas over other fossil fuels, and examine national and state emission regulations pertaining to natural gas systems. Finally, we highlight specific gaps in scientific knowledge and suggest that substantial additional measurements of air emissions from the natural gas life cycle are essential to understanding the impacts and benefits of this resource. PMID:24588259

  11. Air impacts of increased natural gas acquisition, processing, and use: a critical review.

    PubMed

    Moore, Christopher W; Zielinska, Barbara; Pétron, Gabrielle; Jackson, Robert B

    2014-01-01

    During the past decade, technological advancements in the United States and Canada have led to rapid and intensive development of many unconventional natural gas plays (e.g., shale gas, tight sand gas, coal-bed methane), raising concerns about environmental impacts. Here, we summarize the current understanding of local and regional air quality impacts of natural gas extraction, production, and use. Air emissions from the natural gas life cycle include greenhouse gases, ozone precursors (volatile organic compounds and nitrogen oxides), air toxics, and particulates. National and state regulators primarily use generic emission inventories to assess the climate, air quality, and health impacts of natural gas systems. These inventories rely on limited, incomplete, and sometimes outdated emission factors and activity data, based on few measurements. We discuss case studies for specific air impacts grouped by natural gas life cycle segment, summarize the potential benefits of using natural gas over other fossil fuels, and examine national and state emission regulations pertaining to natural gas systems. Finally, we highlight specific gaps in scientific knowledge and suggest that substantial additional measurements of air emissions from the natural gas life cycle are essential to understanding the impacts and benefits of this resource.

  12. Novel gas-tight multi-sampler for discrete deep-sea water

    NASA Astrophysics Data System (ADS)

    Huang, Haocai; Yang, Canjun; Chen, Shicheng; Chen, Daohua; Sun, Chunyan; Niu, Wenda; Li, Fengbo; Liu, Guanghu; Chen, Ying

    2012-07-01

    The issues of how to quickly collect seawater samples and of how to make sure that those samples truly reflect the in-situ information on gas composition and concentration have therefore become a hot but difficult topic in the field of ocean technology. Most conventional seawater samplers only focus on collecting seawater itself, but take little consideration on gas preservation. A set of new oceanographic tools are presented for ocean resource exploration such as hydrothermal sulfide and gas hydrate, and for investigations on the processes and mechanisms of marine physical, chemical and biological evolutions. A gas-tight deep-sea water sampling system (GTWSS) is designed for the collection of deep-sea geochemical samples. This set of tools mainly consists of a conductivity temperature depth profiler (CTD), release devices and gas-tight deep-sea water samplers (GTWS). The GTWS is able to hold the gases in deep-sea water samples tightly, providing in-situ information on gas contents in the seawater samples and can be deployed on a routine wire-deployed CTD sampler for multi-layer discrete sampling of gas-tight seawater. Sea trials are performed successfully in 2008 and 2009, on a research vessel named HaiYang Si Hao in South China Sea, with the deepest trial depth 3 930 m. GTWSS is capable of quickly sampling 12 discrete gas-tight seawater samples (8.3 L per sample) during its single deployment. The head space method is employed to separate the gases from the seawater samples immediately after recovery of the seawater samples on the vessel. Field geochemical analysis is carried out by gaseous hydrocarbon sensors and an infrared gas analyzer. Results show that the concentrations of CH4 and CO2 in the seawater sampled by GTWSS are higher than those sampled by general non-gas-tight water samplers, thus confirming the gas tightness of GTWSS. Seawater samples can be collected quickly by using GTWSS, and GTWSS can keep the samples' integrity quite well.

  13. Air-Sea Exchange Of CO2: A Multi-Technology Approach

    NASA Astrophysics Data System (ADS)

    Tengberg, A.; Almroth, E.; Anderson, L.; Hall, P.; Hjalmarsson, S.; Lefevre, D.; Omstedt, A.; Rutgersson, A.; Sahlee, E.; Smedman, A.; Wesslander, K.

    2006-12-01

    We report on experiences and results from a multidisciplinary project in which we try to elucidate the complex processes involved in air-sea exchange of CO2. This study was performed in the Baltic Sea (off the Swedish island Gotland) and combined the following technologies: - Meteorological measurements of wind, turbulence, temperature, humidity, humidity flux, CO2 and CO2 flux at several levels from a fixed observation tower - Hourly PCO2 measurements with a moored automatic instrument - Collection of dissolved oxygen, temperature, salinity and turbidity data at different levels in the water column at 1-minute intervals - Daily light (PAR) and primary production measurements obtained with a moored automatic incubator - Daily primary production measurements using manual methods - Use of an acoustic current profiler to collect water column information on currents, turbulence, water level and waves - Repetitive water column profiles, from a ship, of dissolved inorganic carbon, oxygen, nutrients, alkalinity, pH, PAR, Chlorophyll A, salinity and temperature

  14. New Constraints on Gas and Gas Hydrate Estimates in the Bering Sea using an Automated Sediment Physics Modeling Approach

    NASA Astrophysics Data System (ADS)

    Wood, W. T.; Martin, K. M.; Barth, G. A.; Scholl, D. W.

    2015-12-01

    We have developed a technique to invert vertical sound speed profiles, like those obtained from reflection seismic data, for grain and pore fluid properties. We have applied this process to seismic data from the Bering Sea to better constrain gas and gas hydrate concentrations. The inversion is based on iterative forward modeling of the sediment constituents and pressure-temperature (PT) regime to match the observed sound speed profile. Inversion input can be either interval or stacking velocities, and we avoid the assumption that stacking velocities are the same as root mean square average velocities. We use a series of constituent sediment physics models whose inputs are mainly porosity, gas saturation, temperature, pressure, effective pressure and grain type (for calculation of effective elastic moduli). The value of this approach is that every model run in the forward algorithm is geologically consistent. Vast portions of model space are eliminated from searching because, e.g. gas hydrate cannot exist outside its PT stability zone. Of particular interest in the Bering Sea are large (~5 km wide) anomalies in seismic reflection profiles almost certainly associated with gas accumulation at the base of gas hydrate stability (BGHS). We applied the inversion across one of these anomalies using stacking velocities from finely discretized semblance scans of seismic common midpoint gathers. Preliminary results suggest that little or no gas or gas hydrate need be present in areas away from the anomaly, in order to match the observed velocity profile. Directly over the center of the anomaly, the significantly reduced velocity below the BGHS requires at least 1-2% gas saturation, and the mildly elevated velocity above the BGHS requires 5-15% gas hydrate saturation.

  15. Gas dynamics of an air-blown electric are

    SciTech Connect

    Borodin, N.S.; Belousov, G.E.; Burmistrov, M.P.; Khitrov, V.G.; Suvorova, S.N.

    1986-05-01

    The authors obtained the basic evidence on the gas dynamics of an air-blown arc by modification of the track method, which involves photographing the tracks of incandescent particles and determining the lengths of the individual tracks and their positions in the arc. To photograph the tracks, the camera was placed so that the shutter blind moved in the opposite direction of the particles or perpendicular to that direction, while the plane of the film (FOTO-250) was 300-400mm from the electrodes. In the model for the blowing method, it is shown that there are differing factors rather than identical ones controlling the residence times for particles and vapor in the discharge zone, so it may be possible to control them seperately. This is particularly important for using chemical isoformation in conjunction with spectral analysis; it is not necessary for the collector particles to evaporate completely, and their higher transport speed in the discharge tends to reduce the intensity of the incoherent background, while the thin films of relevance on the particles, which may be refractory, enter the discharge fully. The emission time remains sufficient for the vapors.

  16. Sea-air CO2 fluxes in the Indian Ocean between 1990 and 2009

    NASA Astrophysics Data System (ADS)

    Sarma, V. V. S. S.; Lenton, A.; Law, R. M.; Metzl, N.; Patra, P. K.; Doney, S.; Lima, I. D.; Dlugokencky, E.; Ramonet, M.; Valsala, V.

    2013-11-01

    The Indian Ocean (44° S-30° N) plays an important role in the global carbon cycle, yet it remains one of the most poorly sampled ocean regions. Several approaches have been used to estimate net sea-air CO2 fluxes in this region: interpolated observations, ocean biogeochemical models, atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Indian Ocean sea-air CO2 fluxes between 1990 and 2009. Using all of the models and inversions, the median annual mean sea-air CO2 uptake of -0.37 ± 0.06 PgC yr-1 is consistent with the -0.24 ± 0.12 PgC yr-1 calculated from observations. The fluxes from the southern Indian Ocean (18-44° S; -0.43 ± 0.07 PgC yr-1 are similar in magnitude to the annual uptake for the entire Indian Ocean. All models capture the observed pattern of fluxes in the Indian Ocean with the following exceptions: underestimation of upwelling fluxes in the northwestern region (off Oman and Somalia), overestimation in the northeastern region (Bay of Bengal) and underestimation of the CO2 sink in the subtropical convergence zone. These differences were mainly driven by lack of atmospheric CO2 data in atmospheric inversions, and poor simulation of monsoonal currents and freshwater discharge in ocean biogeochemical models. Overall, the models and inversions do capture the phase of the observed seasonality for the entire Indian Ocean but overestimate the magnitude. The predicted sea-air CO2 fluxes by ocean biogeochemical models (OBGMs) respond to seasonal variability with strong phase lags with reference to climatological CO2 flux, whereas the atmospheric inversions predicted an order of magnitude higher seasonal flux than OBGMs. The simulated interannual variability by the OBGMs is weaker than that found by atmospheric inversions. Prediction of such weak interannual variability in CO2 fluxes by atmospheric

  17. Sea-air CO2 fluxes in the Indian Ocean between 1990 and 2009

    NASA Astrophysics Data System (ADS)

    Sarma, V. V. S. S.; Lenton, A.; Law, R.; Metzl, N.; Patra, P. K.; Doney, S.; Lima, I. D.; Dlugokencky, E.; Ramonet, M.; Valsala, V.

    2013-07-01

    The Indian Ocean (44° S-30° N) plays an important role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Several approaches have been used to estimate net sea-air CO2 fluxes in this region: interpolated observations, ocean biogeochemical models, atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Indian Ocean sea-air CO2 fluxes between 1990 and 2009. Using all of the models and inversions, the median annual mean sea-air CO2 uptake of -0.37 ± 0.06 Pg C yr-1, is consistent with the -0.24 ± 0.12 Pg C yr-1 calculated from observations. The fluxes from the Southern Indian Ocean (18° S-44° S; -0.43 ± 0.07 Pg C yr-1) are similar in magnitude to the annual uptake for the entire Indian Ocean. All models capture the observed pattern of fluxes in the Indian Ocean with the following exceptions: underestimation of upwelling fluxes in the northwestern region (off Oman and Somalia), over estimation in the northeastern region (Bay of Bengal) and underestimation of the CO2 sink in the subtropical convergence zone. These differences were mainly driven by a lack of atmospheric CO2 data in atmospheric inversions, and poor simulation of monsoonal currents and freshwater discharge in ocean biogeochemical models. Overall, the models and inversions do capture the phase of the observed seasonality for the entire Indian Ocean but over estimate the magnitude. The predicted sea-air CO2 fluxes by Ocean BioGeochemical Models (OBGM) respond to seasonal variability with strong phase lags with reference to climatological CO2 flux, whereas the atmospheric inversions predict an order of magnitude higher seasonal flux than OBGMs. The simulated interannual variability by the OBGMs is weaker than atmospheric inversions. Prediction of such weak interannual variability in CO2 fluxes by atmospheric inversions

  18. Estimating monthly averaged air-sea transfers of heat and momentum using the bulk aerodynamic method

    NASA Technical Reports Server (NTRS)

    Esbensen, S. K.; Reynolds, R. W.

    1981-01-01

    Air-sea transfers of sensible heat, latent heat and momentum are computed from 25 years of middle-latitude and subtropical ocean weather ship data in the North Atlantic and North Pacific using the bulk aerodynamic method. The results show that monthly averaged wind speeds, temperatures and humidities can be used to estimate the monthly averaged sensible and latent heat fluxes from the bulk aerodynamic equations to within a relative error of approximately 10%. The estimates of monthly averaged wind stress under the assumption of neutral stability are shown to be within approximately 5% of the monthly averaged nonneutral values.

  19. Possible deep-water gas hydrate accumulations in the Bering Sea

    USGS Publications Warehouse

    Barth, Ginger A.; Scholl, David W.; Childs, Jonathan R.

    2006-01-01

    Seismic reflection images from the deep-water Aleutian and Bowers Basins of the Bering Sea contain many hundreds of acoustic Velocity-AMPlitude (VAMP) anomalies, each of which may represent a large accumulation of natural gas hydrate. Against a backdrop of essentially horizontal sedimentary reflections, the VAMP anomalies stand out as both high-amplitude bright spots and zones of vertically aligned horizon distortions. The VAMPs are interpreted as natural gas chimneys overlain by concentrated hydrate caps.

  20. Theoretical model for diffusive greenhouse gas fluxes estimation across water-air interfaces measured with the static floating chamber method

    NASA Astrophysics Data System (ADS)

    Xiao, Shangbin; Wang, Chenghao; Wilkinson, Richard Jeremy; Liu, Defu; Zhang, Cheng; Xu, Wennian; Yang, Zhengjian; Wang, Yuchun; Lei, Dan

    2016-07-01

    Aquatic systems are sources of greenhouse gases on different scales, however the uncertainty of gas fluxes estimated using popular methods are not well defined. Here we show that greenhouse gas fluxes across the air-water interface of seas and inland waters are significantly underestimated by the currently used static floating chamber (SFC) method. We found that the SFC CH4 flux calculated with the popular linear regression (LR) on changes of gas concentration over time only accounts for 54.75% and 35.77% of the corresponding real gas flux when the monitoring periods are 30 and 60 min respectively based on the theoretical model and experimental measurements. Our results do manifest that nonlinear regression models can improve gas flux estimations, while the exponential regression (ER) model can give the best estimations which are close to true values when compared to LR. However, the quadratic regression model is proved to be inappropriate for long time measurements and those aquatic systems with high gas emission rate. The greenhouse gases effluxes emitted from aquatic systems may be much more than those reported previously, and models on future scenarios of global climate changes should be adjusted accordingly.

  1. From Space to Seafloor - Investigating Oil and Gas Seepage in the Eastern Black Sea

    NASA Astrophysics Data System (ADS)

    Körber, J.; Sahling, H.; Pape, T.; Heygster, G.; Bohrmann, G.

    2011-12-01

    Emissions of gases from the seafloor are of interest due to their relevance for the global climate, their potential as energy source, and impact on geochemical and biogeochemical cycles. Gas seepage has previously been reported to occur along the continental margin, on the shelf, and at some locations in the central deep Black Sea. These discoveries led to the assumption that seepage of light hydrocarbons from the seafloor is one of the major sources feeding the high methane concentrations of the Black Sea water body. It is commonly accepted that the proportion of pure bubble-forming methane released from deep-sea seeps reaching the hydrosphere/atmosphere interface is negligible since it is nearly entirely dissolved during its ascent through the water column or it is replaced by other gases diffusing from the water column into the bubbles. However, there is first evidence from recent studies at seeps showing intimate seepage of oil and gas that oil coatings around gas bubbles might protect the methane from complete dissolution. A set of Advanced Synthetic Aperture Radar (ASAR) satellite images has been analysed in order to detect oil slicks as sea surface expressions of natural seepage in the deep eastern Black Sea off Georgia. Eight oil seep sites located between 450 and 1200 m water depth have been identified. Intensive hydroacoustic seafloor and water column investigations during two ship expeditions in 2010 and 2011 in combination with shallow sediment sampling and evaluation of hydroacoustic data from earlier cruises confirmed seepage of oil and gas. Ratios of thermogenic and biogenic gas vary significantly between the oil and gas seeps (e.g. Pechori Mound) and pure gas seeps (e.g. Batumi seep). Oil seeps seem to be related to ridge structures and underlying shale diapirs originating from the hydrocarbon rich Oligocene-Miocene Maikop formation. High resolution mapping of the Colkheti Seep (1125 mbsl), one of the most prominent oil seeps off Georgia, using an

  2. Gas Hydrates on the Norway-Barents Sea-Svalbard margin(GANS)

    NASA Astrophysics Data System (ADS)

    Haflidason, H.; Mienert, J.; Kvamme, B.; Barth, T.; Knies, J.; Kvalstad, T.; Hoiland, S.; Planke, S.; Andersen, E. S.; Riis, F.; Hjelstuen, B. O.; Bunz, S.; Chand, S.

    2007-12-01

    The main objective of this Norwegian national initiative is to quantify gas accumulations in the form of hydrates in sediments on the Norway-Barents Sea-Svalbard margins, including an assessment of their dynamics and impacts on the seabed to provide knowledge; vital for a safe exploitation in oil and gas production. This overall objective is an initiative by five research institutions and the Norwegian Deepwater Programme, SEABED III (consortium of nine petroleum companies), to make a coordinated effort on a national level to achieve the main objective to make a coordinated effort on a national level to achieve the main objective by the following sub-goals: a) Geophysical characterisation of gas hydrates, b) Geological and geochemical setting of gas hydrate reservoirs and seeps, c) Gas hydrate dissociation and its effects on geomechanical properties, d) Theoretical and experimental evaluation of gas hydrate dynamics. Three contrasting target areas are of particular interest for field studies and experiments: (1) the mid-Norwegian margin at Nyegga, a national laboratory for gas hydrate research, (2) the Svalbard margin frontier area; important for understanding the geological controls on gas hydrates and fluids, and (3) the Barents Sea, a prolific area with possible occurrence of gas hydrates and clear evidence for active cold seeps. Our initiative allows for the establishment of an acknowledged Norwegian academia-industry network on gas hydrates where education of a new generation of interdisciplinarily trained scientists will be a central task. Our aims are to be achieved by integrating detailed geophysical studies of zones of gas hydrates and associated free gas in cooperation with geotechnical laboratory experiments, theoretical and experimental gas hydrate dynamic studies, geological studies, and geochemical studies of the fluids. The project is financed through the Norwegian Research Council - Petromaks (40 percent) and the SEABED III industry consortium (60

  3. Subsea template, pipeline anchor Troll-Oseberg gas-injection scheme in Norwegian North Sea

    SciTech Connect

    Weibye, B.S.

    1988-01-18

    The author discusses the subsea, gas production template and the 30-mile pipeline that are key elements in supplying as from the Troll field for injection into Oseberg field in the Norwegian North Sea by 1991. The author discusses the design basis and philosophies as well as the production system, template installation and control pods.

  4. Gas hydrate that breaches the sea floor on the continental slope of the Gulf of Mexico

    SciTech Connect

    MacDonald, I.R.; Guinasso, N.L. Jr.; Sassen, R.; Brooks, J.M.; Lee, L. ); Scott, K.T. )

    1994-08-01

    We report observations that concern formation and dissociation of gas hydrate near the sea floor at depths of [minus]540 m in the northern Gulf of Mexico. In August 1992, three lobes of gas hydrate were partly exposed beneath a thin layer of sediment. By May 1993, the most prominent lobe had evidently broken free and floated away, leaving a patch of disturbed sediment and exposed hydrate. The underside of the gas hydrate was about 0.2[degree]C warmer than ambient sea water and had trapped a large volume of oil and free gas. An in situ monitoring device, deployed on a nearby bed of mussels, recorded sustained releases of gas during a 44 day monitoring period. Gas venting coincided with a temporary rise in water temperature of 1[degree]C, which is consistent with thermally induced dissociation of hydrate composed mainly of methane and water. We conclude that the effects of accumulating buoyant force and fluctuating water temperature cause shallow gas hydrate alternately to check and release gas venting. 18 refs., 3 figs., 1 tab.

  5. Studies of the effects of experimentally produced noise associated with oil and gas exploration and development on sea otters in California. Final report

    SciTech Connect

    Riedman, M.L.

    1983-11-15

    During the winter 1983 tape-recorded industrial noises associated with offshore oil and gas operations were projected underwater at Soberanes Point, California. Seismic-exploration sounds were produced using a multiple air gun array (4000 cu. in) and a single air gun (100 cu. in) along a 10-15 km transect paralleling the coastline from Rocky Point to Yankee Point. The behavior, density, and distribution of sea otters (Enhydra lutris) within the vicinity of the sound projection area were not affected by the acoustic experiments. Foraging and diving behaviors of sea otters were normal and undisturbed. There were no movements of otters away from the sound source or out of the sound projection vicinity during either the winter or spring acoustic experiments.

  6. Performance of Simple Gas Foil Thrust Bearings in Air

    NASA Technical Reports Server (NTRS)

    Bruckner, Robert J.

    2012-01-01

    Foil bearings are self-acting hydrodynamics devices used to support high speed rotating machinery. The advantages that they offer to process fluid lubricated machines include: high rotational speed capability, no auxiliary lubrication system, non-contacting high speed operation, and improved damping as compared to rigid hydrodynamic bearings. NASA has had a sporadic research program in this technology for almost 6 decades. Advances in the technology and understanding of foil journal bearings have enabled several new commercial products in recent years. These products include oil-free turbochargers for both heavy trucks and automobiles, high speed electric motors, microturbines for distributed power generation, and turbojet engines. However, the foil thrust bearing has not received a complimentary level of research and therefore has become the weak link of oil-free turbomachinery. In an effort to both provide machine designers with basic performance parameters and to elucidate the underlying physics of foil thrust bearings, NASA Glenn Research Center has completed an effort to experimentally measure the performance of simple gas foil thrust bearing in air. The database includes simple bump foil supported thrust bearings with full geometry and manufacturing techniques available to the user. Test conditions consist of air at ambient pressure and temperatures up to 500 C and rotational speeds to 55,000 rpm. A complete set of axial load, frictional torque, and rotational speed is presented for two different compliant sub-structures and inter-pad gaps. Data obtained from commercially available foil thrust bearings both with and without active cooling is presented for comparison. A significant observation made possible by this data set is the speed-load capacity characteristic of foil thrust bearings. Whereas for the foil journal bearing the load capacity increases linearly with rotational speed, the foil thrust bearing operates in the hydrodynamic high speed limit. In

  7. Cold air outbreaks along a non-frozen sea channel: effects of wind on snow bands

    NASA Astrophysics Data System (ADS)

    Savijärvi, Hannu

    2015-08-01

    Wintertime cold air outbreaks along a non-frozen sea channel or a long lake can become destructive if the related bands of heavy snowfall hit onto land. The forcing for such bands is studied with a 2D numerical model set across an east-west sea channel at 60oN (`Gulf of Finland'), varying the basic geostrophic wind V g. Without any V g opposite coastal land breezes emerge with convergence. This results in a quasi-steady rising motion w max ~ 7.5 cm/s at 600 m in the middle of the gulf, which can force a snow band. During weak V g, the rising motion is reduced but least so for winds from 60o to 80o (~ENE), when modest alongshore bands could exist near the downstream (Estonian) coast. During V g of 4-6 m/s from any direction, the land breezes and rising motions are reduced more effectively, so snow bands are not expected during moderate basic flow. In contrast, during a strong V g of 20-25 m/s from 110o to 120o (~ESE) the land breeze perturbations are intense with w max up to 15-18 cm/s. The induced alongshore bands of heavy snowfall are located in these cases at the sea but quite close to the downstream (Finnish) coast. They can suddenly make a landfall if the basic wind turns clockwise.

  8. Characterization of air contaminants formed by the interaction of lava and sea water.

    PubMed

    Kullman, G J; Jones, W G; Cornwell, R J; Parker, J E

    1994-05-01

    We made environmental measurements to characterize contaminants generated when basaltic lava from Hawaii's Kilauea volcano enters sea water. This interaction of lava with sea water produces large clouds of mist (LAZE). Island winds occasionally directed the LAZE toward the adjacent village of Kalapana and the Hawaii Volcanos National Park, creating health concerns. Environmental samples were taken to measure airborne concentrations of respirable dust, crystalline silica and other mineral compounds, fibers, trace metals, inorganic acids, and organic and inorganic gases. The LAZE contained quantifiable concentrations of hydrochloric acid (HCl) and hydrofluoric acid (HF); HCl was predominant. HCl and HF concentrations were highest in dense plumes of LAZE near the sea. The HCl concentration at this sampling location averaged 7.1 ppm; this exceeds the current occupational exposure ceiling of 5 ppm. HF was detected in nearly half the samples, but all concentrations were <1 ppm Sulfur dioxide was detected in one of four short-term indicator tube samples at approximately 1.5 ppm. Airborne particulates were composed largely of chloride salts (predominantly sodium chloride). Crystalline silica concentrations were below detectable limits, less than approximately 0.03 mg/m3 of air. Settled dust samples showed a predominance of glass flakes and glass fibers. Airborne fibers were detected at quantifiable levels in 1 of 11 samples. These fibers were composed largely of hydrated calcium sulfate. These findings suggest that individuals should avoid concentrated plumes of LAZE near its origin to prevent over exposure to inorganic acids, specifically HCl.

  9. Characterization of air contaminants formed by the interaction of lava and sea water.

    PubMed

    Kullman, G J; Jones, W G; Cornwell, R J; Parker, J E

    1994-05-01

    We made environmental measurements to characterize contaminants generated when basaltic lava from Hawaii's Kilauea volcano enters sea water. This interaction of lava with sea water produces large clouds of mist (LAZE). Island winds occasionally directed the LAZE toward the adjacent village of Kalapana and the Hawaii Volcanos National Park, creating health concerns. Environmental samples were taken to measure airborne concentrations of respirable dust, crystalline silica and other mineral compounds, fibers, trace metals, inorganic acids, and organic and inorganic gases. The LAZE contained quantifiable concentrations of hydrochloric acid (HCl) and hydrofluoric acid (HF); HCl was predominant. HCl and HF concentrations were highest in dense plumes of LAZE near the sea. The HCl concentration at this sampling location averaged 7.1 ppm; this exceeds the current occupational exposure ceiling of 5 ppm. HF was detected in nearly half the samples, but all concentrations were <1 ppm Sulfur dioxide was detected in one of four short-term indicator tube samples at approximately 1.5 ppm. Airborne particulates were composed largely of chloride salts (predominantly sodium chloride). Crystalline silica concentrations were below detectable limits, less than approximately 0.03 mg/m3 of air. Settled dust samples showed a predominance of glass flakes and glass fibers. Airborne fibers were detected at quantifiable levels in 1 of 11 samples. These fibers were composed largely of hydrated calcium sulfate. These findings suggest that individuals should avoid concentrated plumes of LAZE near its origin to prevent over exposure to inorganic acids, specifically HCl. PMID:8593853

  10. The Aeroclipper: A new instrument for quasi-Lagrangian measurements at the air-sea interface

    NASA Astrophysics Data System (ADS)

    Duvel, J. P.; Reverdin, G.; Pichon, T.; Vargas, A.

    The Aeroclipper is a new balloon developed by CNES. The Aeroclipper is a balloon equipped with a cable extended by a guide-rope in contact with the surface of the ocean. The balloon is vertically stabilised at a given height (currently 40 to 60m above the sea surface) and move on quasi-Lagrangian trajectories depending on the surface wind. LMD (Laboratoire de Méteorologie Dynamique), LodyC (Laboratoire d'océanographie physique et de Climatologie) and ENSTA (Ecole Nationale Supérieure de Techniques Avancées) developed an instrumentation adapted to this new measurement system. This instrumentation is distributed on one atmospheric gondola and one oceanic gondola. The aim is to measure surface physical parameters (Air and sea surface temperatures, sea surface salinity, wind, pressure and humidity) and to derive turbulent fluxes of moisture, heat and momentum. The Aeroclippers will give legs of the different parameters at a relatively high spatial resolution and thus information on the perturbation of these parameters at mesoscale. A first test of the full system will be performed from Banyuls (France) during spring 2004. The first scientific use of the Aeroclipper is planned in February 2005 in the Indian Ocean South of the Equator in link with the pilot phase of the Vasco (Variability of the Atmosphere at the intra-Seasonal time scale and Coupling with the Ocean) experiment.

  11. Air-sea interaction at the subtropical convergence south of Africa

    SciTech Connect

    Rouault, M.; Lutjeharms, J.R.E.; Ballegooyen, R.C. van

    1994-12-31

    The oceanic region south of Africa plays a key role in the control of Southern Africa weather and climate. This is particularly the case for the Subtropical Convergence region, the northern border of the Southern Ocean. An extensive research cruise to investigate this specific front was carried out during June and July 1993. A strong front, the Subtropical Convergence was identified, however its geographic disposition was complicated by the presence of an intense warm eddy detached from the Agulhas current. The warm surface water in the eddy created a strong contrast between it and the overlying atmosphere. Oceanographic measurements (XBT and CTD) were jointly made with radiosonde observations and air-sea interaction measurements. The air-sea interaction measurement system included a Gill sonic anemometer, an Ophir infrared hygrometer, an Eppley pyranometer, an Eppley pyrgeometer and a Vaissala temperature and relative humidity probe. Turbulent fluxes of momentum, sensible heat and latent heat were calculated in real time using the inertial dissipation method and the bulk method. All these measurements allowed a thorough investigation of the net heat loss of the ocean, the deepening of the mixed layer during a severe storm as well as the structure of the atmospheric boundary layer and ocean-atmosphere exchanges.

  12. Resolving the abundance and air-sea fluxes of airborne microorganisms in the North Atlantic Ocean.

    PubMed

    Mayol, Eva; Jiménez, María A; Herndl, Gerhard J; Duarte, Carlos M; Arrieta, Jesús M

    2014-01-01

    Airborne transport of microbes may play a central role in microbial dispersal, the maintenance of diversity in aquatic systems and in meteorological processes such as cloud formation. Yet, there is almost no information about the abundance and fate of microbes over the oceans, which cover >70% of the Earth's surface and are the likely source and final destination of a large fraction of airborne microbes. We measured the abundance of microbes in the lower atmosphere over a transect covering 17° of latitude in the North Atlantic Ocean and derived estimates of air-sea exchange of microorganisms from meteorological data. The estimated load of microorganisms in the atmospheric boundary layer ranged between 6 × 10(4) and 1.6 × 10(7) microbes per m(2) of ocean, indicating a very dynamic air-sea exchange with millions of microbes leaving and entering the ocean per m(2) every day. Our results show that about 10% of the microbes detected in the boundary layer were still airborne 4 days later and that they could travel up to 11,000 km before they entered the ocean again. The size of the microbial pool hovering over the North Atlantic indicates that it could play a central role in the maintenance of microbial diversity in the surface ocean and contribute significantly to atmospheric processes.

  13. The air-sea interface and surface stress under tropical cyclones.

    PubMed

    Soloviev, Alexander V; Lukas, Roger; Donelan, Mark A; Haus, Brian K; Ginis, Isaac

    2014-01-01

    Tropical cyclone track prediction is steadily improving, while storm intensity prediction has seen little progress in the last quarter century. Important physics are not yet well understood and implemented in tropical cyclone forecast models. Missing and unresolved physics, especially at the air-sea interface, are among the factors limiting storm predictions. In a laboratory experiment and coordinated numerical simulation, conducted in this work, the microstructure of the air-water interface under hurricane force wind resembled Kelvin-Helmholtz shear instability between fluids with a large density difference. Supported by these observations, we bring forth the concept that the resulting two-phase environment suppresses short gravity-capillary waves and alters the aerodynamic properties of the sea surface. The unified wave-form and two-phase parameterization model shows the well-known increase of the drag coefficient (Cd) with wind speed, up to ~30 ms(-1). Around 60 ms(-1), the new parameterization predicts a local peak of Ck/Cd, under constant enthalpy exchange coefficient Ck. This peak may explain rapid intensification of some storms to major tropical cyclones and the previously reported local peak of lifetime maximum intensity (bimodal distribution) in the best-track records. The bimodal distribution of maximum lifetime intensity, however, can also be explained by environmental parameters of tropical cyclones alone. PMID:24930493

  14. Resolving the abundance and air-sea fluxes of airborne microorganisms in the North Atlantic Ocean

    PubMed Central

    Mayol, Eva; Jiménez, María A.; Herndl, Gerhard J.; Duarte, Carlos M.; Arrieta, Jesús M.

    2014-01-01

    Airborne transport of microbes may play a central role in microbial dispersal, the maintenance of diversity in aquatic systems and in meteorological processes such as cloud formation. Yet, there is almost no information about the abundance and fate of microbes over the oceans, which cover >70% of the Earth's surface and are the likely source and final destination of a large fraction of airborne microbes. We measured the abundance of microbes in the lower atmosphere over a transect covering 17° of latitude in the North Atlantic Ocean and derived estimates of air-sea exchange of microorganisms from meteorological data. The estimated load of microorganisms in the atmospheric boundary layer ranged between 6 × 104 and 1.6 × 107 microbes per m2 of ocean, indicating a very dynamic air-sea exchange with millions of microbes leaving and entering the ocean per m2 every day. Our results show that about 10% of the microbes detected in the boundary layer were still airborne 4 days later and that they could travel up to 11,000 km before they entered the ocean again. The size of the microbial pool hovering over the North Atlantic indicates that it could play a central role in the maintenance of microbial diversity in the surface ocean and contribute significantly to atmospheric processes. PMID:25400625

  15. Large Temporal Variations in Air-Sea CO2 Flux off the Coast of Georgia

    NASA Astrophysics Data System (ADS)

    Caves, J. K.; Sabine, C.; Cai, W.; Alin, S.

    2008-12-01

    Though the inner shelf is a small portion of global ocean area, its air-sea CO2 flux is disproportionately high. Due to its tight links with both terrestrial and oceanic systems, the inner shelf is likely to experience significant spatial and temporal variability. We measured the fugacity of CO2 (fCO2) continuously from July 2006 to June 2008 on a moored platform in Gray's Reef National Marine Sanctuary on Georgia's inner shelf. The long-term, high temporal resolution data has allowed us to begin to measure interannual variations in CO2 flux along the inner Georgia shelf. From July 2006-June 2007, the inner Georgia shelf was a CO2 sink (-3.26mmol/m2/day), while during following year, the shelf switched to being a source (2.26mmol/m2/day). Choice of wind data (satellite or buoy-derived) significantly alters these estimates of annual fluxes. QuikSCAT satellite wind data indicate a much larger sink (- 6.13mmol/m2/day) during 2006-2007, and a non-existent source (0.02mmol/m2/day) during 2007- 2008. An earlier, high-resolution spatial study from January 2005-May 2006 found that the inner shelf within the South Atlantic Bight may have been a source of 0.65 to 1.20mmol/m2/day, suggesting that the inner shelf may experience dramatic swings in CO2 flux. Though sea-surface temperature (SST) is the largest influence on surface water fCO2, average monthly SST varied little between both years; instead, possible explanations for the large variation in interannual CO2 flux include decreased biological production and increased river flow (and, hence carbon export) during 2007-2008. This is the first evidence of large-scale, annual switches in air-sea CO2 flux within an inner shelf, and it holds significant implications for global estimates of air-sea CO2 flux.

  16. Breaking waves and near-surface sea spray aerosol dependence on changing winds: Wave breaking efficiency and bubble-related air-sea interaction processes

    NASA Astrophysics Data System (ADS)

    Hwang, P. A.; Savelyev, I. B.; Anguelova, M. D.

    2016-05-01

    Simultaneous measurements of sea spray aerosol (SSA), wind, wave, and microwave brightness temperature are obtained in the open ocean on-board Floating Instrument Platform (FLIP). These data are analysed to clarify the ocean surface processes important to SSA production. Parameters are formulated to represent surface processes with characteristic length scales spanning a broad range. The investigation reveals distinct differences of the SSA properties in rising winds and falling winds, with higher SSA volume in falling winds. Also, in closely related measurements of whitecap coverage, higher whitecap fraction as a function of wind speed is found in falling winds than in rising winds or in older seas than in younger seas. Similar trend is found in the short scale roughness reflected in the microwave brightness temperature data. In the research of length and velocity scales of breaking waves, it has been observed that the length scale of wave breaking is shorter in mixed seas than in wind seas. For example, source function analysis of short surface waves shows that the characteristic length scale of the dissipation function shifts toward higher wavenumber (shorter wavelength) in mixed seas than in wind seas. Similarly, results from feature tracking or Doppler analysis of microwave radar sea spikes, which are closely associated with breaking waves, show that the magnitude of the average breaking wave velocity is smaller in mixed seas than in wind seas. Furthermore, breaking waves are observed to possess geometric similarity. Applying the results of breaking wave analyses to the SSA and whitecap observations described above, it is suggestive that larger air cavities resulting from the longer breakers are entrained in rising high winds. The larger air cavities escape rapidly due to buoyancy before they can be fully broken down into small bubbles for the subsequent SSA production or whitecap manifestation. In contrast, in falling winds (with mixed seas more likely), the

  17. Combustion characteristics of pulverized coal and air/gas premixed flame in a double swirl combustor

    SciTech Connect

    Kamal, M.M.

    2009-07-01

    An experimental work was performed to investigate the co-firing of pulverized coal and premixed gas/air streams in a double swirl combustor. The results showed that the NOx emissions are affected by the relative rates of thermal NOx formation and destruction via the pyrolysis of the fuel-N species in high temperature fuel-rich zones. Various burner designs were tested in order to vary the temperature history and the residence time across both coal and gas flames inside the furnace. It was found that by injecting the coal with a gas/air mixture as a combined central jet surrounded by a swirled air stream, a double flame envelope develops with high temperature fuel-rich conditions in between the two reaction zones such that the pyrolysis reactions to N{sub 2} are accelerated. A further reduction in the minimum NOx emissions, as well as in the minimum CO concentrations, was reported for the case where the coal particles are fed with the gas/air mixture in the region between the two swirled air streams. On the other hand, allocating the gas/air mixture around the swirled air-coal combustion zone provides an earlier contact with air and retards the NOx reduction mechanism in such a way that the elevated temperatures around the coal particles allow higher overall NOx emissions. The downstream impingement of opposing air jets was found more efficient than the impinging of particle non-laden premixed flames for effective NOx reduction. In both cases, there is an upstream flow from the stagnation region to the coal primary combustion region, but with the case of air impingement, the hot fuel-rich zone develops earlier. The optimum configuration was found by impinging all jets of air and coal-gas/air mixtures that pronounced minimum NOx and CO concentrations of 310 and 480ppm, respectively.

  18. Gas hydrate saturation from acoustic impedance and resistivity logs in the shenhu area, south china sea

    USGS Publications Warehouse

    Wang, X.; Wu, S.; Lee, M.; Guo, Y.; Yang, S.; Liang, J.

    2011-01-01

    During the China's first gas hydrate drilling expedition -1 (GMGS-1), gas hydrate was discovered in layers ranging from 10 to 25 m above the base of gas hydrate stability zone in the Shenhu area, South China Sea. Water chemistry, electrical resistivity logs, and acoustic impedance were used to estimate gas hydrate saturations. Gas hydrate saturations estimated from the chloride concentrations range from 0 to 43% of the pore space. The higher gas hydrate saturations were present in the depth from 152 to 177 m at site SH7 and from 190 to 225 m at site SH2, respectively. Gas hydrate saturations estimated from the resistivity using Archie equation have similar trends to those from chloride concentrations. To examine the variability of gas hydrate saturations away from the wells, acoustic impedances calculated from the 3 D seismic data using constrained sparse inversion method were used. Well logs acquired at site SH7 were incorporated into the inversion by establishing a relation between the water-filled porosity, calculated using gas hydrate saturations estimated from the resistivity logs, and the acoustic impedance, calculated from density and velocity logs. Gas hydrate saturations estimated from acoustic impedance of seismic data are ???10-23% of the pore space and are comparable to those estimated from the well logs. The uncertainties in estimated gas hydrate saturations from seismic acoustic impedances were mainly from uncertainties associated with inverted acoustic impedance, the empirical relation between the water-filled porosities and acoustic impedances, and assumed background resistivity. ?? 2011 Elsevier Ltd.

  19. Sea-air carbon dioxide fluxes along 35°S in the South Atlantic Ocean

    NASA Astrophysics Data System (ADS)

    Lencina-Avila, J. M.; Ito, R. G.; Garcia, C. A. E.; Tavano, V. M.

    2016-09-01

    The oceans play an important role in absorbing a significant fraction of the atmospheric CO2 surplus, but there are still uncertainties concerning several open ocean regions, such as the under-sampled South Atlantic Ocean. This study assessed the net sea-air CO2 fluxes and distribution of sea-surface CO2 fugacity (f C O2sw) along the 35°S latitude in the South Atlantic, during 2011 spring and early summer periods. Underway CO2 molar fraction, temperature, salinity and dissolved oxygen measurements were taken continuously from South American to South African continental shelves. Values of both satellite and discrete in situ chlorophyll-a concentration along the ship's track were used as ancillary data. Both f C O2sw and difference in sea-air fugacity (ΔfCO2) showed high variability along the cruise track, with higher values found on the continental shelf and slope regions. All ΔfCO2 values were negative, implying that a sinking process was occurring during the cruise period, with an average net CO2 flux of -3.1±2.2 mmol CO2 m-2 day-1 (using Wanninkhof, 1992). Physical variables were the main drivers of f C O2sw variability in South American continental shelf and open ocean regions, while the biological factor dominated the South African continental shelf. Algorithms for estimating fCO2 and temperature-normalized fCO2 were developed and applied separately to the three defined sub-regions: the South American shelf, the open ocean and the South African continental shelf, with the regional temperature-normalized fCO2 models showing better results.

  20. Towards More Realistic Simulation of Air-Sea Interaction over Lakes on Titan

    NASA Astrophysics Data System (ADS)

    Rafkin, Scot; Soto, Alejandro

    2016-06-01

    The exchange of methane between the atmosphere and surface liquid reservoirs dominates the short time-scale methanological cycle. In this study, previous two-dimensional simulations of the exchange of methane vapor, sensible heat and momentum between the atmosphere and lakes are updated with the inclusion of radiative forcing and extended to three dimensions, including the introduction of realistic coastlines. Previous studies of Titan's air-sea exchange in two dimensions suggested that the exchange process was self-limiting. Evaporation from lakes produced a shallow but extremely stable marine layer that suppressed turbulent exchange. Furthermore, the circulation associated with the higher buoyancy of methane-rich atmosphere over the lake was offset by the oppositely directed thermal sea breeze circulation, which muted the mean wind. Two major weaknesses of this previous work were the lack of radiative forcing and the imposition of two dimensionality that limited the full range of dynamical solutions. Based on early theoretical studies, it was thought that magnitude of turbulent energy flux exchanges would be much larger than radiative fluxes, thereby justifying the neglect of radiation, but the two-dimensional simulations indicated that this was not a valid assumption. The dynamical limitations of two-dimensional simulations are well known. Vorticity stretching (i.e., circulation intensification through vertical motion) is not possible and it is also not possible to produce dynamically balanced gradient wind-type circulations. As well, the irregular shape of a realistic coastline cannot be expressed in two dimensions, and these realistic structures will generally induce complex convergence and divergence circulations in the atmosphere. The impact of radiative forcing and the addition of the third dimension on the air-sea exchange are presented.

  1. Compact optical system for imaging underwater and through the air/sea interface

    NASA Astrophysics Data System (ADS)

    Alley, Derek; Mullen, Linda; Laux, Alan

    2012-06-01

    Typical line-of-sight (LOS)/monostatic optical imaging systems include a laser source and receiver that are co-located on the same platform. The performance of such systems is deteriorated in turbid ocean water due to the large amount of light that is scattered on the path to and from an object of interest. Imagery collected with the LOS/monostatic system through the air/sea interface is also distorted due to wave focusing/defocusing effects. The approach of this project is to investigate an alternate, non-line-of-sight (NLOS)/bistatic approach that offers some advantages over these traditional LOS/monostatic imaging techniques. In this NLOS system the laser and receiver are located on separate platforms with the laser located closer to the object of interest. As the laser sequentially scans the underwater object, a time-varying intensity signal corresponding to reflectivity changes in the object is detected by the distant receiver. A modulated laser illuminator is used to communicate information about the scan to the distant receiver so it can recreate the image with the collected scattered light. This NLOS/bistatic configuration also enables one to view an underwater target through the air-sea interface (transmitter below the surface and receiver above the surface) without the distortions experienced with the LOS/monostatic sensor. In this paper, we will review the results of recent laboratory water tank experiments where an underwater object was imaged with the receiver both below and above the sea surface.

  2. Exercise-induced intrapulmonary shunting of venous gas emboli does not occur after open-sea diving.

    PubMed

    Dujić, Zeljko; Palada, Ivan; Obad, Ante; Duplancić, Darko; Brubakk, Alf O; Valic, Zoran

    2005-09-01

    Paradoxical arterializations of venous gas emboli can lead to neurological damage after diving with compressed air. Recently, significant exercise-induced intrapulmonary anatomical shunts have been reported in healthy humans that result in widening of alveolar-to-arterial oxygen gradient. The aim of this study was to examine whether intrapulmonary shunts can be found following strenuous exercise after diving and, if so, whether exercise should be avoided during that period. Eleven healthy, military male divers performed an open-sea dive to 30 m breathing air, remaining at pressure for 30 min. During the bottom phase of the dive, subjects performed mild exercise at approximately 30% of their maximal oxygen uptake. The ascent rate was 9 m/min. Each diver performed graded upright cycle ergometry up to 80% of the maximal oxygen uptake 40 min after the dive. Monitoring of venous gas emboli was performed in both the right and left heart with an ultrasonic scanner every 20 min for 60 min after reaching the surface pressure during supine rest and following two coughs. The diving profile used in this study produced significant amounts of venous bubbles. No evidence of intrapulmonary shunting was found in any subject during either supine resting posture or any exercise grade. Also, short strenuous exercise after the dive did not result in delayed-onset decompression sickness in any subject, but studies with a greater number of participants are needed to confirm whether divers should be allowed to exercise after diving.

  3. Hurricane Isabel, AIRS Infrared and SeaWinds Scatterometer Data Combined

    NASA Technical Reports Server (NTRS)

    2003-01-01

    [figure removed for brevity, see original site] [figure removed for brevity, see original site] Figure 1Figure 2

    These two images show Hurricane Isabel as viewed by AIRS and each of the two SeaWinds scatterometers on the ADEOS-2 and QuikScat satellites, all JPL-managed experiments. AIRS data are used to create global three-dimensional maps of temperature, humidity and clouds, while scatterometers measure surface wind speed and direction.

    Figure 1 shows Isabel on September 13, 2003, when it was a Category 5 storm threatening the Caribbean and southern United States. At the time Isabel was the strongest Atlantic storm since hurricane Mitch killed thousands in central America in 1997. The red vectors in the image show Isabel's surface winds as measured by SeaWinds on ADEOS-2, and the background colors show the temperature of clouds and surface, as viewed in the infrared by AIRS. The hurricane's powerful swirling winds are apparent. These winds circle the hurricane's eye, seen as the red dot near the middle top of the image. Light blue areas shows adjacent cold clouds tops associated with strong thunderstorms embedded within the storm.

    Figure 2 shows Isabel as it approached landfall on the outer banks of North Carolina on September 18. The hurricane weakened in the five days since the earlier image was observed, as indicated by a less clearly defined eye. Nevertheless, it was still a powerful storm. The winds blowing onshore north of the eye knocked over trees, blew roofs off buildings, and drove large waves that breached the coastal barrier islands in many places. Water, transportation and power are still not fully restored to many of the areas in the image. The winds apparently blowing away from the eye of the storm are an artifact of one of the hurricane's other destructive phenomena: rain. The darkest blue clouds observed by AIRS show the most intense thunderstorms, and hence the heaviest rains. Hard rain fools the the SeaWinds on Quik

  4. Distinct microbial communities thriving in gas hydrate-associated sediments from the eastern Japan Sea

    NASA Astrophysics Data System (ADS)

    Yanagawa, Katsunori; Kouduka, Mariko; Nakamura, Yuri; Hachikubo, Akihiro; Tomaru, Hitoshi; Suzuki, Yohey

    2014-08-01

    Marine gas hydrate and cold-seep systems, which maintain a large amount of methane in the seabed, may critically impact the geochemical and ecological characteristics of the deep-sea sedimentary environment. However, it remains unclear whether marine sediments associated with gas hydrate harbor novel microbial communities that are distinct from those from typical marine sediments. In this study, microbial community structures thriving in sediments associated with and without gas hydrate in the eastern Japan Sea were characterized by 16S rRNA gene-based phylogenetic analyses. Uncultivated bacterial lineages of candidate division JS1 and a novel group NT-B2 were dominant in the sediments from gas hydrate-associated sites. Whereas, microbial populations from sites not associated with gas hydrate were mainly composed of Bacteroidetes, Nitrospirales, Chlamydiales, Chlorobiales, and yet-uncultured bacterial lineages of OD1 and TM06. The good correlation between the dominance of JS1 and NT-B2 and the association of gas hydrate could be attributed to the supply of more energetically favorable energy sources in gas-rich fluids from the deep subsurface than refractory organic matter of terrigenous and diatomaceous origin.

  5. Occurrence and air/sea-exchange of novel organic pollutants in the marine environment

    NASA Astrophysics Data System (ADS)

    Ebinghaus, R.; Xie, Z.

    2006-12-01

    A number of studies have demonstrated that several classes of chemicals act as biologically relevant signalling substances. Among these chemicals, many, including PCBs, DDT and dioxins, are semi-volatile, persistent, and are capable of long-range atmospheric transport via atmospheric circulation. Some of these compounds, e.g. phthalates and alkylphenols (APs) are still manufactured and consumed worldwide even though there is clear evidence that they are toxic to aquatic organisms and can act as endocrine disruptors. Concentrations of NP, t-OP and NP1EO, DMP, DEP, DBP, BBP, and DEHP have been simultaneously determined in the surface sea water and atmosphere of the North Sea. Atmospheric concentrations of NP and t-OP ranged from 7 to 110 pg m - 3, which were one to three orders of magnitude below coastal atmospheric concentrations already reported. NP1EO was detected in both vapor and particle phases, which ranged from 4 to 50 pg m - 3. The concentrations of the phthalates in the atmosphere ranged from below the method detection limit to 3.4 ng m - 3. The concentrations of t-OP, NP, and NP1EO in dissolved phase were 13-300, 90-1400, and 17-1660 pg L - 1. DBP, BBP, and DEHP were determined in the water phase with concentrations ranging from below the method detection limit to 6.6 ng L - 1. This study indicates that atmospheric deposition of APs and phthalates into the North Sea is an important input pathway. The net fluxes indicate that the air sea exchange is significant and, consequently the open ocean and polar areas will be an extensive sink for APs and phthalates.

  6. Air/fuel supply system for use in a gas turbine engine

    DOEpatents

    Fox, Timothy A; Schilp, Reinhard; Gambacorta, Domenico

    2014-06-17

    A fuel injector for use in a gas turbine engine combustor assembly. The fuel injector includes a main body and a fuel supply structure. The main body has an inlet end and an outlet end and defines a longitudinal axis extending between the outlet and inlet ends. The main body comprises a plurality of air/fuel passages extending therethrough, each air/fuel passage including an inlet that receives air from a source of air and an outlet. The fuel supply structure communicates with and supplies fuel to the air/fuel passages for providing an air/fuel mixture within each air/fuel passage. The air/fuel mixtures exit the main body through respective air/fuel passage outlets.

  7. Microwave and Electro-optical Transmission Experiments in the air-sea Boundary Layer

    NASA Astrophysics Data System (ADS)

    Anderson, K. D.

    2002-12-01

    , deployment, operation, and recovery of R/P FLIP. These problems ranged from the U.S.N.S. Sioux cutting a mooring line, which delayed deployment by more than 4 days, nearly loosing Tommy during the first attempt at deployment, inadequate air conditioning in the lab spaces, causing at least one instrument to temporarily fail, and problems associated with too many people and too many sensors on board. These issues will be discussed and recommendations will be made to improve future microwave and electro-optical experiments at sea.

  8. Tracking Dissolved Methane Concentrations near Active Seeps and Gas Hydrates: Sea of Japan.

    NASA Astrophysics Data System (ADS)

    Snyder, G. T.; Aoki, S.; Matsumoto, R.; Tomaru, H.; Owari, S.; Nakajima, R.; Doolittle, D. F.; Brant, B.

    2015-12-01

    A number of regions in the Sea of Japan are known for active gas venting and for gas hydrate exposures on the sea floor. In this investigation we employed several gas sensors mounted on a ROV in order to determine the concentrations of dissolved methane in the water near these sites. Methane concentrations were determined during two-second intervals throughout each ROV deployment during the cruise. The methane sensor deployments were coupled with seawater sampling using Niskin bottles. Dissolved gas concentrations were later measured using gas chromatography in order to compare with the sensor results taken at the same time. The observed maximum dissolved methane concentrations were much lower than saturation values, even when the ROV manipulators were in contact with gas hydrate. Nonetheless, dissolved concentrations did reach several thousands of nmol/L near gas hydrate exposures and gas bubbles, more than two orders of magnitude over the instrumental detection limits. Most of the sensors tested were able to detect dissolved methane concentrations as low as 10 nmol/L which permitted detection when the ROV approached methane plume sites, even from several tens of meters above the sea floor. Despite the low detection limits, the methane sensors showed variable response times when returning to low-background seawater (~5nM). For some of the sensors, the response time necessary to return to background values occurred in a matter of minutes, while for others it took several hours. Response time, as well as detection limit, should be an important consideration when selecting methane sensors for ROV or AUV investigations. This research was made possible, in part, through funding provided by the Japanese Ministry of Economy, Trade and Industry (METI).

  9. A climatology of air-sea interactions at the Mediterranean LION and AZUR buoys

    NASA Astrophysics Data System (ADS)

    Caniaux, Guy; Prieur, Louis; Bouin, Marie-Noëlle; Giordani, Hervé

    2014-05-01

    The LION and AZUR buoys (respectively at 42.1°N 4.7°E and 43.4°N 7.8°E) provide an extended data set since respectively 1999 and 2001 to present for studying air-sea interactions in the northwestern Mediterranean basin. The two buoys are located where high wind events occur (resp. north western and north easterly gale winds), that force and condition deep oceanic winter convection in that region. A short-term climatology (resp. 13 and 11 years) of air-sea interactions has been developed, which includes classical meteo-oceanic parameters, but also waves period and significant wave heights and radiative fluxes. Moreover turbulent surface fluxes have been estimated from various bulk parameterizations, in order to estimate uncertainties on fluxes. An important dispersion of turbulent fluxes is found at high wind speeds according to the parameterization used, larger than taking into account the second order effects of cool skin, warm layer and waves. An important annual cycle affects air temperatures (ATs), SSTs and turbulent fluxes at the two buoys. The annual cycle of ATs and SSTs can be well reconstructed from the first two annual harmonics, while for the turbulent heat fluxes the erratic occurrence of high and low flux events, well correlated with high/dry and low windy periods, strongly affect their annual and interannual cycles. The frequency of high surface heat fluxes and high wind stress is found highest during the autumn and winter months, despite the fact that north-westerly gale winds occur all year long at LION buoy. During calm weather period, ATs and SSTs experience an important diurnal cycle (on average 1 and 0.5°C respectively), that affect latent and sensible heat fluxes. Finally, an estimate of the interannual variability of the turbulent fluxes in Autumn and Winter is discussed, in order to characterize their potential role on deep ocean convection.

  10. Air-water exchange of brominated anisoles in the northern Baltic Sea.

    PubMed

    Bidleman, Terry F; Agosta, Kathleen; Andersson, Agneta; Haglund, Peter; Nygren, Olle; Ripszam, Matyas; Tysklind, Mats

    2014-06-01

    Bromophenols produced by marine algae undergo O-methylation to form bromoanisoles (BAs), which are exchanged between water and air. BAs were determined in surface water of the northern Baltic Sea (Gulf of Bothnia, consisting of Bothnian Bay and Bothnian Sea) during 2011-2013 and on a transect of the entire Baltic in September 2013. The abundance decreased in the following order: 2,4,6-tribromoanisole (2,4,6-TBA)>2,4-dibromoanisole (2,4-DBA)≫2,6-dibromoanisole (2,6-DBA). Concentrations of 2,4-DBA and 2,4,6-TBA in September were higher in the southern than in the northern Baltic and correlated well with the higher salinity in the south. This suggests south-to-north advection and dilution with fresh riverine water enroute, and/or lower production in the north. The abundance in air over the northern Baltic also decreased in the following order: 2,4,6-TBA>2,4-DBA. However, 2,6-DBA was estimated as a lower limit due to breakthrough from polyurethane foam traps used for sampling. Water/air fugacity ratios ranged from 3.4 to 7.6 for 2,4-DBA and from 18 to 94 for 2,4,6-TBA, indicating net volatilization. Flux estimates using the two-film model suggested that volatilization removes 980-1360 kg of total BAs from Bothnian Bay (38000 km2) between May and September. The release of bromine from outgassing of BAs could be up to 4-6% of bromine fluxes from previously reported volatilization of bromomethanes and bromochloromethanes.

  11. Response of air-sea carbon fluxes and climate to orbital forcing changes in the Community Climate System Model

    NASA Astrophysics Data System (ADS)

    Jochum, M.; Peacock, S.; Moore, K.; Lindsay, K.

    2010-07-01

    A global general circulation model coupled to an ocean ecosystem model is used to quantify the response of carbon fluxes and climate to changes in orbital forcing. Compared to the present-day simulation, the simulation with the Earth's orbital parameters from 115,000 years ago features significantly cooler northern high latitudes but only moderately cooler southern high latitudes. This asymmetry is explained by a 30% reduction of the strength of the Atlantic Meridional Overturning Circulation that is caused by an increased Arctic sea ice export and a resulting freshening of the North Atlantic. The strong northern high-latitude cooling and the direct insolation induced tropical warming lead to global shifts in precipitation and winds to the order of 10%-20%. These climate shifts lead to regional differences in air-sea carbon fluxes of the same order. However, the differences in global net air-sea carbon fluxes are small, which is due to several effects, two of which stand out: first, colder sea surface temperature leads to a more effective solubility pump but also to increased sea ice concentration which blocks air-sea exchange, and second, the weakening of Southern Ocean winds that is predicted by some idealized studies occurs only in part of the basin, and is compensated by stronger winds in other parts.

  12. Geophysics Characteristic on Gas Hydrates Zone in Northern South China Sea

    NASA Astrophysics Data System (ADS)

    Sha, Zhibin

    2015-04-01

    Gas hydrates are very important because of their vast resources potential, their roles as submarine geohazard, and their effects on global climate in the word. In China, the research of gas hydrates was initiated further later ,but the South China Sea has found a number of geophysical anomalies of gas hydrate by researching of almost 10 years. In order to determine the nature and distribution of marine gas hydrate, a series of geophysical techniques are used. By using the traditional seismic data processing, purpose seismic data processing, wave impedance inversion techniques and geophysical well logging data processing based on Self-organizing feature map neural network, a great deal of useful information are abstracted to determine the gas hydrate zone beneath the seabed. The results show (1) Conventional multi-channel seismic reflection processing data from the SCS reveal various seismic indicators of gas hydrate and associated gas, such as the BSR, enhanced reflections below the BSR, Weak reflection or blanking zone above the BSRs.;(2) special processing techniques, such as attribute extraction and wave impedance inversion, is necessary so as to mine more effective data, they could compensate the shortage of conventional seismic data processing techniques used for distinguishing gas-bearing reservoirs;(3) as a kind of intelligent information processing technology, SOFM neural network is feasible for lithologic identification by logging data and has a high rate of identification of gas hydrate. In the end, the author hopes it may provide some useful clues to the exploration of gas hydrate.

  13. SEISMIC AND GEOCHEMICAL EVIDENCE FOR SHALLOW GAS IN SEDIMENT ON NAVARIN CONTINENTAL MARGIN, BERING SEA.

    USGS Publications Warehouse

    Carlson, Paul R.; Golan-Bac, Margaret; Karl, Herman A.; Kvenvolden, Keith A.

    1985-01-01

    Marine sesmic studies coupled with geochemical investigations demonstrate tha hydrocarbon gases are ubiquitous in the near-surface sediment of the Navarin continental margin in the northern Bering Sea. Three types of acoustic anomalies appear to be related to the presence of gas in the sediment. These anomalies are most prevalent in the northern half of the Navarin basin. Acoustic anomalies attributed to gas hydrates and to diagenetic boundaries are present on seismic records of the lower slope between Navarinsky and Zhemchug Canyons. Hydrocarbon gases, methane through butanes, are common in the surface sediment of the Navarin continental margin. The source of methane is mainly biogenic, but the hydrocarbon gas compositions in 17 of 141 cores suggest the presence of thermogenic gas. No direct correlation could be found between acoustic anomalies and gas concentrations in the sediment. Refs.

  14. Arterial blood gas reference values for sea level and an altitude of 1,400 meters.

    PubMed

    Crapo, R O; Jensen, R L; Hegewald, M; Tashkin, D P

    1999-11-01

    Blood gas measurements were collected on healthy lifetime nonsmokers at sea level (n = 96) and at an altitude of 1,400 meters (n = 243) to establish reference equations. At each study site, arterial blood samples were analyzed in duplicate on two separate blood gas analyzers and CO-oximeters. Arterial blood gas variables included Pa(O(2)), Pa(CO(2)), pH, and calculated alveolar-arterial PO(2) difference (AaPO(2)). CO-oximeter variables were Hb, COHb, MetHb, and Sa(O(2)). Subjects were 18 to 81 yr of age with 166 male and 173 female. Outlier data were excluded from multiple regression analysis, and reference equations were fitted to the data in two ways: (1) best fit using linear, squared, and cross-product terms; (2) simple equations, including only the variables that explained at least 3% of the variance. Two sets of equations were created: (1) using only the sea level data and (2) using the combined data with barometric pressure as an independent variable. Comparisons with earlier studies revealed small but significant differences; the decline in Pa(O(2)) with age at each altitude was consistent with most previous studies. At sea level, the equation that included barometric pressure predicted Pa(O(2)) slightly better than the sea level specific equation. The inclusion of barometric pressure in the equations allows better prediction of blood gas reference values at sea level and at altitudes as high as 1,400 meters. PMID:10556115

  15. Relationships Between the Bulk-Skin Sea Surface Temperature Difference, Wind, and Net Air-Sea Heat Flux

    NASA Technical Reports Server (NTRS)

    Emery, William J.; Castro, Sandra L.; Lindstrom, Eric (Technical Monitor)

    2002-01-01

    The primary purpose of this project was to evaluate and improve models for the bulk-skin temperature difference to the point where they could accurately and reliably apply under a wide variety of environmental conditions. To accomplish this goal, work was conducted in three primary areas. These included production of an archive of available data sets containing measurements of the skin and bulk temperatures and associated environmental conditions, evaluation of existing skin layer models using the compiled data archive, and additional theoretical work on the development of an improved model using the data collected under diverse environmental conditions. In this work we set the basis for a new physical model of renewal type, and propose a parameterization for the temperature difference across the cool skin of the ocean in which the effects of thermal buoyancy, wind stress, and microscale breaking are all integrated by means of the appropriate renewal time scales. Ideally, we seek to obtain a model that will accurately apply under a wide variety of environmental conditions. A summary of the work in each of these areas is included in this report. A large amount of work was accomplished under the support of this grant. The grant supported the graduate studies of Sandra Castro and the preparation of her thesis which will be completed later this year. This work led to poster presentations at the 1999 American Geophysical Union Fall Meeting and 2000 IGARSS meeting. Additional work will be presented in a talk at this year's American Meteorological Society Air-Sea Interaction Meeting this May. The grant also supported Sandra Castro during a two week experiment aboard the R/P Flip (led by Dr. Andrew Jessup of the Applied Physics Laboratory) to help obtain additional shared data sets and to provide Sandra with a fundamental understanding of the physical processes needed in the models. In a related area, the funding also partially supported Dr. William Emery and Daniel

  16. Physical and chemical processes of air masses in the Aegean Sea during Etesians: Aegean-GAME airborne campaign.

    PubMed

    Tombrou, M; Bossioli, E; Kalogiros, J; Allan, J D; Bacak, A; Biskos, G; Coe, H; Dandou, A; Kouvarakis, G; Mihalopoulos, N; Percival, C J; Protonotariou, A P; Szabó-Takács, B

    2015-02-15

    High-resolution measurements of gas and aerosols' chemical composition along with meteorological and turbulence parameters were performed over the Aegean Sea (AS) during an Etesian outbreak in the framework of the Aegean-GAME airborne campaign. This study focuses on two distinct Etesian patterns, with similarities inside the Marine Atmospheric Boundary Layer (MABL) and differences at higher levels. Under long-range transport and subsidence the pollution load is enhanced (by 17% for CO, 11% for O3, 28% for sulfate, 62% for organic mass, 47% for elemental carbon), compared to the pattern with a weaker synoptic system. Sea surface temperature (SST) was a critical parameter for the MABL structure, turbulent fluxes and pollutants' distribution at lower levels. The MABL height was below 500 m asl over the eastern AS (favoring higher accumulation), and deeper over the western AS. The most abundant components of total PM1 were sulfate (40-50%) and organics (30-45%). Higher average concentrations measured over the eastern AS (131 ± 76 ppbv for CO, 62.5 ± 4.1 ppbv for O3, 5.0 ± 1.1 μg m(-3) for sulfate, 4.7 ± 0.9 μg m(-3) for organic mass and 0.5 ± 0.2 μg m(-3) for elemental carbon). Under the weaker synoptic system, cleaner but more acidic air masses prevailed over the eastern part, while distinct aerosol layers of different signature were observed over the western part. The Aitken and accumulation modes contributed equally during the long-range transport, while the Aitken modes dominated during local or medium range transport. PMID:25460953

  17. Preliminary formation analysis for compressed air energy storage in depleted natural gas reservoirs :

    SciTech Connect

    Gardner, William Payton

    2013-06-01

    The purpose of this study is to develop an engineering and operational understanding of CAES performance for a depleted natural gas reservoir by evaluation of relative permeability effects of air, water and natural gas in depleted natural gas reservoirs as a reservoir is initially depleted, an air bubble is created, and as air is initially cycled. The composition of produced gases will be evaluated as the three phase flow of methane, nitrogen and brine are modeled. The effects of a methane gas phase on the relative permeability of air in a formation are investigated and the composition of the produced fluid, which consists primarily of the amount of natural gas in the produced air are determined. Simulations of compressed air energy storage (CAES) in depleted natural gas reservoirs were carried out to assess the effect of formation permeability on the design of a simple CAES system. The injection of N2 (as a proxy to air), and the extraction of the resulting gas mixture in a depleted natural gas reservoir were modeled using the TOUGH2 reservoir simulator with the EOS7c equation of state. The optimal borehole spacing was determined as a function of the formation scale intrinsic permeability. Natural gas reservoir results are similar to those for an aquifer. Borehole spacing is dependent upon the intrinsic permeability of the formation. Higher permeability allows increased injection and extraction rates which is equivalent to more power per borehole for a given screen length. The number of boreholes per 100 MW for a given intrinsic permeability in a depleted natural gas reservoir is essentially identical to that determined for a simple aquifer of identical properties. During bubble formation methane is displaced and a sharp N2methane boundary is formed with an almost pure N2 gas phase in the bubble near the borehole. During cycling mixing of methane and air occurs along the boundary as the air bubble boundary moves. The extracted gas mixture changes as a

  18. Removing a small quantity of THT from gas storage groundwater through air stripping and gas-phase carbon adsorption

    SciTech Connect

    Girod, J.F.; Leclerc, J.P.; Muhr, H.

    1996-12-31

    This paper deals with the response to a case of contaminated groundwater located in France. The natural gas is stored during summer in porous underground rocks. When energy requirements increase (particularly in winter), gas is drawn off, but water is also pumped during this operation. The water has a strong characteristic odour of the TetraHydroThiophene (THT), which has been used by Gaz de France as an additive in order to detect gas leakages because of its strong odour. Unfortunately, the presence of THT in medium other than natural gas can be responsible for safety problems. Gas stripping combined with adsorption on granular activated carbon was chosen to obtain removal of THT from the groundwater. The gas to water ratio for stripping column is higher than usual and the gas used for stripping was recycled in order to prevent air pollution. Carbon consumption is approximately 3 tons a year. 8 refs., 5 figs., 2 tabs.

  19. On The Impact of Borescope Camera Air Purge on DWPF Melter Off-Gas Flammability

    SciTech Connect

    CHOI, ALEXANDER

    2004-07-22

    DWPF Engineering personnel requested that a new minimum backup film cooler air flow rate, which will meet the off-gas safety basis limits for both normal and seismic sludge-only operations, be calculated when the air purge to the borescope cameras is isolated from the melter. Specifically, it was requested that the latest calculations which were used to set the off-gas flammability safety bases for the sludge batch 2 and 3 feeds be revised, while maintaining all other process variables affecting off-gas flammability such as total organic carbon (TOC), feed rate, melter air purges, and vapor space temperature at their current respective maximum or minimum limits. Before attempting to calculate the new minimum backup film cooler air flow, some of the key elements of the combustion model were reviewed, and it was determined that the current minimum backup film cooler air flow of 233 lb/hr is adequate to satisfy the off-gas flammability safety bases for both normal and seismic operations i n the absence of any borescope camera air purge. It is, therefore, concluded that there is no need to revise the reference E-7 calculations. This conclusion is in essence based on the fact that the current minimum backup film cooler air flow was set to satisfy the minimum combustion air requirement under the worst-case operating scenario involving a design basis earthquake during which all the air purges not only to the borescope cameras but to the seal pot are presumed to be lost due to pipe ruptures. The minimum combustion air purge is currently set at 150 per cent of the stoichiometric air flow required to combust 3 times the normal flow of flammable gases. The DWPF control strategy has been that 100 per cent of the required minimum combustion air is to be provided by the controlled air purge through the backup film cooler alone.

  20. Tropical Intraseasonal Air-Sea Exchanges during the 1997 Pacific Warming

    NASA Technical Reports Server (NTRS)

    Sui, C.-H.; Lau, K.-M.; Chou, S.-H.; Wang, Zihou

    1999-01-01

    The Madden Julian Oscillations (MJO) and associated westerly wind (WW) events account for much of the tropical intraseasonal variability (TISV). The TISV has been suggested as an important stochastic forcing that may be one of the underlying causes for the observed irregularities of the El Nino-Southern Oscillation (ENSO). Recent observational studies and theories of interannual to interdecadal-scale variability suggest that ENSO may arise from different mechanisms depending on the basic states. The Pacific warming event of 1997, being associated with a period of strong MJO and WW events, serves as a natural experiment for studying the possible role of TISV in triggering an ENSO event. We have performed a combined statistical and composite analysis of surface WW events based on the assimilated surface wind and sea level pressure for the period of 1980-1993, the SSM/I wind for the period of 1988-1997, and OLR. Results indicates that extratropical forcing contribute significantly to the evolution of MJO and establishment of WW events over the Pacific warm pool. Following the major WW events, there appeared an eastward extension of equatorial warm SST anomalies from the western Pacific warm pool. Such tropical-extratropical interaction is particularly clear in the winter of 96-97 that leads to the recent warming event in 1997/98. From the above discussion, our current study on this subject is based on the hypothesis that 1) there is an enhanced air-sea interaction associated with TISV and the northerly surges from the extratropics in the initial phase of the 97/98 warming event, and 2) the relevant mechanisms are functions of the basic state of the coupled system (in terms of SST distribution and atmospheric mean circulation) that varies at the interannual and interdecadal time scale. We are analyzing the space-time structure of the northerly surges, their association with air-sea fluxes and upper ocean responses during the period of September 1996 to June 1997. The

  1. A numerical coupled model for studying air-sea-wave interaction

    NASA Astrophysics Data System (ADS)

    Ly, Le Ngoc

    1995-10-01

    A numerical coupled model of air-sea-wave interaction is developed to study the influence of ocean wind waves on dynamical, turbulent structures of the air-sea system and their impact on coupled modeling. The model equations for both atmospheric and oceanic boundary layers include equations for: (1) momentum, (2) a k-ɛ turbulence scheme, and (3) stratification in the atmospheric and oceanic boundary layers. The model equations are written in the same form for both the atmosphere and ocean. In this model, wind waves are considered as another source of turbulent energy in the upper layer of the ocean besides turbulent energy from shear production. The dissipation ɛ at the ocean surface is written as a linear combination of terms representing dissipation from mean flow and breaking waves. The ɛ from breaking waves is estimated by using similarity theory and observed data. It is written in terms of wave parameters such as wave phase speed, height, and length, which are then expressed in terms of friction velocity. Numerical experiments are designed for various geostrophic winds, wave heights, and wave ages, to study the influence of waves on the air-sea system. The numerical simulations show that the vertical profiles of ɛ in the atmospheric and oceanic boundary layers (AOBL) are similar. The magnitudes of ɛ in the oceanic surface zone are much larger than those in the atmospheric surface zone and in the interior of the oceanic boundary layer (OBL). The model predicts ɛ distributions with a surface zone of large dissipation which was not expected from similarity scaling based on observed wind stress and surface buoyancy. The simulations also show that waves have a strong influence on eddy viscosity coefficients (EVC) and momentum fluxes, and have a dominated effect on the component of fluxes in the direction of the wind. The depth of large changes in flux magnitudes and EVC in the ocean can reach to 10-20 m. The simulations of surface drift currents confirm that

  2. Gas dispersion and immobile gas volume in solid and porous particle biofilter materials at low air flow velocities.

    PubMed

    Sharma, Prabhakar; Poulsen, Tjalfe G

    2010-07-01

    Gas-phase dispersion in granular biofilter materials with a wide range of particle sizes was investigated using atmospheric air and nitrogen as tracer gases. Two types of materials were used: (1) light extended clay aggregates (LECA), consisting of highly porous particles, and (2) gravel, consisting of solid particles. LECA is a commercial material that is used for insulation, as a soil conditioner, and as a carrier material in biofilters for air cleaning. These two materials were selected to have approximately the same particle shape. Column gas transport experiments were conducted for both materials using different mean particle diameters, different particle size ranges, and different gas flow velocities. Measured breakthrough curves were modeled using the advection-dispersion equation modified for mass transfer between mobile and immobile gas phases. The results showed that gas dispersivity increased with increasing mean particle diameter for LECA but was independent of mean particle diameter for gravel. Gas dispersivity also increased with increasing particle size range for both media. Dispersivities in LECA were generally higher than for gravel. The mobile gas content in both materials increased with increasing gas flow velocity but it did not show any strong dependency on mean particle diameter or particle size range. The relative fraction of mobile gas compared with total porosity was highest for gravel and lowest for LECA likely because of its high internal porosity. PMID:20681430

  3. Gas dispersion and immobile gas volume in solid and porous particle biofilter materials at low air flow velocities.

    PubMed

    Sharma, Prabhakar; Poulsen, Tjalfe G

    2010-07-01

    Gas-phase dispersion in granular biofilter materials with a wide range of particle sizes was investigated using atmospheric air and nitrogen as tracer gases. Two types of materials were used: (1) light extended clay aggregates (LECA), consisting of highly porous particles, and (2) gravel, consisting of solid particles. LECA is a commercial material that is used for insulation, as a soil conditioner, and as a carrier material in biofilters for air cleaning. These two materials were selected to have approximately the same particle shape. Column gas transport experiments were conducted for both materials using different mean particle diameters, different particle size ranges, and different gas flow velocities. Measured breakthrough curves were modeled using the advection-dispersion equation modified for mass transfer between mobile and immobile gas phases. The results showed that gas dispersivity increased with increasing mean particle diameter for LECA but was independent of mean particle diameter for gravel. Gas dispersivity also increased with increasing particle size range for both media. Dispersivities in LECA were generally higher than for gravel. The mobile gas content in both materials increased with increasing gas flow velocity but it did not show any strong dependency on mean particle diameter or particle size range. The relative fraction of mobile gas compared with total porosity was highest for gravel and lowest for LECA likely because of its high internal porosity.

  4. Topographic features of gas hydrate mounds of shallow gas hydrate areas in Joetsu Basin , eastern margin of Japan Sea

    NASA Astrophysics Data System (ADS)

    Hiromatsu, M.; Machiyama, H.; Matsumoto, R.

    2010-12-01

    Mega pockmarks and mounds, both of which are 300m to 500m in diamater and 30m to 40 m deep or high, characterize the Umitaka Spur and Joetsu Knoll of the Joetsu Basin. A number of pockmarks and mounds develop in NNE to SSW direction parallel to the general trend of mobile belt along the eastern margin of Japan Sea, suggesting that the topography has been strongly controlled by regional tectonics. Seismic profiles have revealed well-developed chaotic to transparent zones (gas chimneys) in the area of pockmarks and mounds, from which a number of active methane plumes stand up to 700m above sea floor. Ultra-high resolution bathymetric data and reflection images were acquired by Multi Beam Echo Sounder (MBES) and Side Scan Sonar (SSS) of the AUV "URASHIMA” during the YK10-08 cruise of R/V Yokosuka (JAMSTEC), July 2010. Based on mosaic images of MBES and SSS, we could identify several types of the hydrate mounds over gas chimney zones. Some are represented as a smooth and low bulge without strong reflections of background level, but the others show rough and uneven topography, featured by a few meter scale depressions, crevasses and minor ridges with strong reflector images, indicating the development of hard ground. Such strong reflectors are due to carbonate crusts and concretions and gas hydrate exposures as observed by ROV . Micro-topographic features are likely to represent a growth stage of hydrate mounds, and perhaps the accumulation of shallow gas hydrates. MBES and SSS onboard AUV are powerful tools to identify gas hydrate accumulation and evolution of shallow gas hydrate system.

  5. High pressure ceramic air heater for indirectly fired gas turbine applications

    SciTech Connect

    LaHaye, P.G.; Briggs, G.F.; Orozxo, N.J.; Seger, J.L.

    1993-11-01

    The EFCC cycle is conceptually simple. Air enters the compressor where it is pressurized and becomes the tube-side flow of the ceramic air heater. Heat transferred from the hot combustion gases flowing through the shell-side raises the air temperature to the desired turbine inlet temperature. Internally insulated high pressure piping returns the heated compressor air to the turbine, where it is expanded providing power to drive the electric generator and gas turbine compressor. Exhaust air from the turbine is used as the combustion air for the coal combustor. The EFCC cycle burns pulverized coal in an atmospheric combustion chamber similar to the combustion system in a conventional steam generator. The combustion gas exits the combustor and enters a slag screen, or impact separator, where the larger ash particles are collected to prevent fouling of the heat exchanger. After the slag screen, the combustion gas enters the shell-side of the CerHX where its thermal energy is transferred to the tube side air flow. Shell-side exit temperatures are sufficiently high to provide thermal energy for the bottoming Rankine Cycle through a heat recovery steam generator. Exhaust gas exiting the steam generator passes through a flue gas desulfurization system and a particulate removal system.

  6. The Use of an Air-Natural Gas Flame in Atomic Absorption.

    ERIC Educational Resources Information Center

    Melucci, Robert C.

    1983-01-01

    Points out that excellent results are obtained using an air-natural gas flame in atomic absorption experiments rather than using an air-acetylene flame. Good results are obtained for alkali metals, copper, cadmium, and zinc but not for the alkaline earths since they form refractory oxides. (Author/JN)

  7. Cooling air recycling for gas turbine transition duct end frame and related method

    DOEpatents

    Cromer, Robert Harold; Bechtel, William Theodore; Sutcu, Maz

    2002-01-01

    A method of cooling a transition duct end frame in a gas turbine includes the steps of a) directing cooling air into the end frame from a region external of the transition duct and the impingement cooling sleeve; and b) redirecting the cooling air from the end frame into the annulus between the transition duct and the impingement cooling sleeve.

  8. MP3 - A Meteorology and Physical Properties Package to explore Air:Sea interaction on Titan

    NASA Astrophysics Data System (ADS)

    Lorenz, R. D.

    2012-04-01

    The exchange of mass, heat and momentum at the air:sea interface are profound influences on our environment. Titan presents us with an opportunity to study these processes in a novel physical context. The MP3 instrument, under development for the proposed Discovery mission TiME (Titan Mare Explorer) is an integrated suite of small, simple sensors that combines the a traditional meteorology package with liquid physical properties and depth-sounding. In TiME's 6-Titan-day (96-day) nominal mission, MP3 will have an extended measurement opportunity in one of the most evocative environments in the solar system. The mission and instrument benefit from APL's expertise and experience in marine as well as space systems. The topside meteorology sensors (METH, WIND, PRES, TEMP) will yield the first long-duration in-situ data to constrain Global Circulation Models. The sea sensors (TEMP, TURB, DIEL, SOSO) allow high cadence bulk composition measurements to detect heterogeneities as the TiME capsule drifts across Ligeia, while a depth sounder (SONR) will measure the bottom profile. The combination of these sensors (and vehicle dynamics, ACCL) will characterize air:sea exchange. In addition to surface data, a measurement subset (ACCL, PRES, METH, TEMP) is made during descent to characterize the structure of the polar troposphere and marine boundary layer. A single electronics box inside the vehicle performs supervising and data handling functions and is connected to the sensors on the exterior via a wire and fiber optic harness. ACCL: MEMS accelerometers and angular rate sensors measure the vehicle motion during descent and on the surface, to recover wave amplitude and period and to correct wind measurements for vehicle motion. TEMP: Precision sensors are installed at several locations above and below the 'waterline' to measure air and sea temperatures. Installation of topside sensors at several locations ensures that at least one is on the upwind side of the vehicle. PRES: The

  9. Model estimating the effect of marginal ice zone processes on the phytoplankton primary production and air-sea flux of CO2 in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Dvornikov, Anton; Sein, Dmitry; Ryabchenko, Vladimir; Gorchakov, Victor; Martjyanov, Stanislav

    2016-04-01

    This study is aimed to assess the impact of sea ice on the primary production of phytoplankton (PPP) and air-sea CO2 flux in the Barents Sea. To get the estimations, we apply a three-dimensional eco-hydrodynamic model based on the Princeton Ocean Model which includes: 1) a module of sea ice with 7 categories, and 2) the 11-component module of marine pelagic ecosystem developed in the St. Petersburg Branch, Institute of Oceanology. The model is driven by atmospheric forcing, prescribed from the reanalysis NCEP / NCAR, and conditions on the open sea boundary, prescribed from the regional model of the atmosphere-ocean-sea ice-ocean biogeochemistry, developed at Max Planck Institute for Meteorology, Hamburg. Comparison of the model results for the period 1998-2007 with satellite data showed that the model reproduces the main features of the evolution of the sea surface temperature, seasonal changes in the ice extent, surface chlorophyll "a" concentration and PPP in the Barents Sea. Model estimates of the annual PPP for whole sea, APPmod, appeared in 1.5-2.3 times more than similar estimates, APPdata, from satellite data. The main reasons for this discrepancy are: 1) APPdata refers to the open water, while APPmod, to the whole sea area (under the pack ice and marginal ice zone (MIZ) was produced 16 - 38% of PPP); and 2) values of APPdata are underestimated because of the subsurface chlorophyll maximum. During the period 1998-2007, the modelled maximal (in the seasonal cycle) sea ice area has decreased by 15%. This reduction was accompanied by an increase in annual PPP of the sea at 54 and 63%, based, respectively, on satellite data and the model for the open water. According to model calculations for the whole sea area, the increase is only 19%. Using a simple 7-component model of oceanic carbon cycle incorporated into the above hydrodynamic model, the CO2 exchange between the atmosphere and sea has been estimated in different conditions. In the absence of biological

  10. Distribution and air-sea exchange of mercury (Hg) in polluted marine environments

    NASA Astrophysics Data System (ADS)

    Bagnato, E.; Sprovieri, M.; Bitetto, M.; Bonsignore, M.; Calabrese, S.; Di Stefano, V.; Oliveri, E.; Parello, F.; Mazzola, S.

    2012-04-01

    Mercury (Hg) is emitted in the atmosphere by anthropogenic and natural sources, these last accounting for one third of the total emissions. Since the pre-industrial age, the atmospheric deposition of mercury have increased notably, while ocean emissions have doubled owing to the re-emission of anthropogenic mercury. Exchange between the atmosphere and ocean plays an important role in cycling and transport of mercury. We present the preliminary results from a study on the distribution and evasion flux of mercury at the atmosphere/sea interface in the Augusta basin (SE Sicily, southern Italy), a semi-enclosed marine area affected by a high degree of contamination (heavy metals and PHA) due to the oil refineries placed inside its commercial harbor. It seems that the intense industrial activity of the past have lead to an high Hg pollution in the bottom sediments of the basin, whose concentrations are far from the background mercury value found in most of the Sicily Strait sediments. The release of mercury into the harbor seawater and its dispersion by diffusion from sediments to the surface, make the Augusta basin a potential supplier of mercury both to the Mediterranean Sea and the atmosphere. Based on these considerations, mercury concentration and flux at the air-sea interface of the Bay have been estimated using a real-time atomic adsorption spectrometer (LUMEX - RA915+) and an home-made accumulation chamber, respectively. Estimated Total Atmospheric Mercury (TGM) concentrations during the cruise on the bay were in the range of 1-3 ng · m-3, with a mean value of about 1.4 ng · m-3. These data well fit with the background Hgatm concentration values detected on the land (1-2 ng · m-3, this work), and, more in general, with the background atmospheric TGM levels found in the North Hemisphere (1.5-1.7 ng · m-3)a. Besides, our measurements are in the range of those reported for other important polluted marine areas. The mercury evasion flux at the air-sea interface

  11. Comparisons of Ship-based Observations of Air-Sea Energy Budgets with Gridded Flux Products

    NASA Astrophysics Data System (ADS)

    Fairall, C. W.; Blomquist, B.

    2015-12-01

    Air-surface interactions are characterized directly by the fluxes of momentum, heat, moisture, trace gases, and particles near the interface. In the last 20 years advances in observation technologies have greatly expanded the database of high-quality direct (covariance) turbulent flux and irradiance observations from research vessels. In this paper, we will summarize observations from the NOAA sea-going flux system from participation in various field programs executed since 1999 and discuss comparisons with several gridded flux products. We will focus on comparisons of turbulent heat fluxes and solar and IR radiative fluxes. The comparisons are done for observing programs in the equatorial Pacific and Indian Oceans and SE subtropical Pacific.

  12. Oceanic Whitecaps and Their Role in Air-Sea Exchange Processes

    NASA Astrophysics Data System (ADS)

    Glazman, R. E.

    The book is based on the proceedings of the 1983 Whitecap Workshop, held at University College, Galway, Ireland. The 22 full-length papers and 18 abstracts of poster presentations that it contains cover a wide range of topics. The small-scale air-sea exchange processes triggered by the breaking of wind-generated gravity waves serve as the common ground from which specialized excursions are made into the fields of acoustics and optics of bubbly water, statistics and hydrodynamics of water waves, remote sensing, atmospheric electricity, and physicochemical hydrodynamics of bubbles, droplets, and water surfaces coated with organic films. The book opens with “The Life and Science of Alfred H. Woodcock” by Duncan Blanchard (State University of New York, Albany).

  13. Characterization of air contaminants formed by the interaction of lava and sea water.

    PubMed Central

    Kullman, G J; Jones, W G; Cornwell, R J; Parker, J E

    1994-01-01

    We made environmental measurements to characterize contaminants generated when basaltic lava from Hawaii's Kilauea volcano enters sea water. This interaction of lava with sea water produces large clouds of mist (LAZE). Island winds occasionally directed the LAZE toward the adjacent village of Kalapana and the Hawaii Volcanos National Park, creating health concerns. Environmental samples were taken to measure airborne concentrations of respirable dust, crystalline silica and other mineral compounds, fibers, trace metals, inorganic acids, and organic and inorganic gases. The LAZE contained quantifiable concentrations of hydrochloric acid (HCl) and hydrofluoric acid (HF); HCl was predominant. HCl and HF concentrations were highest in dense plumes of LAZE near the sea. The HCl concentration at this sampling location averaged 7.1 ppm; this exceeds the current occupational exposure ceiling of 5 ppm. HF was detected in nearly half the samples, but all concentrations were <1 ppm Sulfur dioxide was detected in one of four short-term indicator tube samples at approximately 1.5 ppm. Airborne particulates were composed largely of chloride salts (predominantly sodium chloride). Crystalline silica concentrations were below detectable limits, less than approximately 0.03 mg/m3 of air. Settled dust samples showed a predominance of glass flakes and glass fibers. Airborne fibers were detected at quantifiable levels in 1 of 11 samples. These fibers were composed largely of hydrated calcium sulfate. These findings suggest that individuals should avoid concentrated plumes of LAZE near its origin to prevent over exposure to inorganic acids, specifically HCl. Images Figure 1. Figure 2. Figure 3. Figure 4. A Figure 4. B Figure 4. C Figure 4. D PMID:8593853

  14. Selected current-use and historic-use pesticides in air and seawater of the Bohai and Yellow Seas, China

    NASA Astrophysics Data System (ADS)

    Zhong, Guangcai; Tang, Jianhui; Xie, Zhiyong; Möller, Axel; Zhao, Zhen; Sturm, Renate; Chen, Yingjun; Tian, Chongguo; Pan, Xiaohui; Qin, Wei; Zhang, Gan; Ebinghaus, Ralf

    2014-01-01

    Consumption of pesticides in China has increased rapidly in recent years; however, occurrence and fate of current-use pesticides (CUPs) in China coastal waters are poorly understood. Globally banned pesticides, so-called historic-use pesticides (HUPs), are still commonly observed in the environment. In this work, air and surface seawater samples taken from the Bohai and Yellow Seas in May 2012 were analyzed for CUPs including trifluralin, quintozene, chlorothalonil, dicofol, chlorpyrifos, and dacthal, as well as HUPs (hexachlorobenzene (HCB), hexachlorocyclohexanes (HCHs), and endosulfan). CUP profile in both air and seawater samples generally reflected their consumption patterns in China. HUPs in the air and seawater samples were in comparable levels as those of CUPs with high concentrations. α-Endosulfan, dicofol, and chlorothalonil showed strong net deposition likely resulting from their intensive use in recent years, while CUPs with low consumption amount (quintozene and dacthal) were close to equilibrium at most samplings sites. Another CUP with high usage amout (i.e., chlorpyrifos) underwent volatilization possibly due to its longer half-life in seawater than that in air. α-HCH and γ-HCH were close to equilibrium in the Bohai Sea, but mainly underwent net deposition in the Yellow Sea. The net deposition of α-HCH could be attributed to polluted air pulses from the East China identified by air mass back trajectories. β-HCH showed net volatilization in the Bohai Sea, which was driven by its relative enrichment in seawater. HCB either slightly favored net volatilization or was close to equilibrium in the Bohai and Yellow Seas.

  15. Assessing Air-Sea Interaction in the Evolving NASA GEOS Model

    NASA Technical Reports Server (NTRS)

    Clayson, Carol Anne; Roberts, J. Brent

    2015-01-01

    In order to understand how the climate responds to variations in forcing, one necessary component is to understand the full distribution of variability of exchanges of heat and moisture between the atmosphere and ocean. Surface heat and moisture fluxes are critical to the generation and decay of many coupled air-sea phenomena. These mechanisms operate across a number of scales and contain contributions from interactions between the anomalous (i.e. non-mean), often extreme-valued, flux components. Satellite-derived estimates of the surface turbulent and radiative heat fluxes provide an opportunity to assess results from modeling systems. Evaluation of only time mean and variability statistics, however only provides limited traceability to processes controlling what are often regime-dependent errors. This work will present an approach to evaluate the representation of the turbulent fluxes at the air-sea interface in the current and evolving Goddard Earth Observing System (GEOS) model. A temperature and moisture vertical profile-based clustering technique is used to identify robust weather regimes, and subsequently intercompare the turbulent fluxes and near-surface parameters within these regimes in both satellite estimates and GEOS-driven data sets. Both model reanalysis (MERRA) and seasonal-to-interannual coupled GEOS model simulations will be evaluated. Particular emphasis is placed on understanding the distribution of the fluxes including extremes, and the representation of near-surface forcing variables directly related to their estimation. Results from these analyses will help identify the existence and source of regime-dependent biases in the GEOS model ocean surface turbulent fluxes. The use of the temperature and moisture profiles for weather-state clustering will be highlighted for its potential broad application to 3-D output typical of model simulations.

  16. Oceanic distributions and air-sea fluxes of biogenic halocarbons in the open ocean

    NASA Astrophysics Data System (ADS)

    Chuck, Adele L.; Turner, Suzanne M.; Liss, Peter S.

    2005-10-01

    Surface seawater and atmospheric concentrations of methyl iodide, chloroiodomethane, bromoform, dichlorobromomethane, and chlorodibromethane were measured during three open ocean cruises in the Atlantic and Southern oceans. The measurements spanned a longitudinal range of 115°, between 50°N and 65°S. The saturation anomalies and the instantaneous air-sea fluxes of the gases during one of these cruises (ANT XVIII/1) are presented and discussed. Methyl iodide and chloroiodomethane were highly supersaturated (>1000%) throughout the temperate and tropical regions, with calculated mean fluxes of 15 and 5.5 nmol m-2 d-1, respectively. The oceanic emissions of the brominated compounds were less substantial, and a significant area of the temperate Atlantic Ocean was found to be a sink for bromoform. Correlation analyses have been used to investigate possible controls on the concentrations of these gases. In particular, the relationship of CH3I with sea surface temperature and light is discussed, with the tentative conclusion that this compound may be formed abiotically.

  17. Application of the Hilbert-Huang Transform to the Estimation of Air-Sea Turbulent Fluxes

    NASA Astrophysics Data System (ADS)

    Wang, Juanjuan; Song, Jinbao; Huang, Yansong; Fan, Conghui

    2013-06-01

    The Hilbert-Huang transform (HHT) is applied to analyzing the turbulent time series obtained within the atmospheric boundary layer over the ocean. A method based on the HHT is introduced to reduce the influence of non-turbulent motions on the eddy-covariance based flux by removing non-turbulent modes from the time series. The scale dependence of the flux is examined and a gap mode is identified to distinguish between turbulent modes and non-turbulent modes. To examine the effectiveness of this method it is compared with three conventional methods (block average, moving-window average, and multi-resolution decomposition). The data used are from three sonic anemometers installed on a moored buoy at about 6, 4 and 2.7 m height above the sea surface. For each method, along-wind and cross-wind momentum fluxes and sensible heat fluxes at the three heights are calculated. According to the assumption of a constant-flux layer, there should be no significant difference between the fluxes at the three heights. The results show that the fluxes calculated using HHT exhibit a smaller difference and higher correlation than the other methods. These results support the successful application of HHT to the estimation of air-sea turbulent fluxes.

  18. Mechanisms controlling the SST air-sea heat flux feedback and its dependence on spatial scale

    NASA Astrophysics Data System (ADS)

    Hausmann, Ute; Czaja, Arnaud; Marshall, John

    2016-05-01

    The turbulent air-sea heat flux feedback (α , in {W m}^{-2}{ K}^{-1} ) is a major contributor to setting the damping timescale of sea surface temperature (SST) anomalies. In this study we compare the spatial distribution and magnitude of α in the North Atlantic and the Southern Ocean, as estimated from the ERA-Interim reanalysis dataset. The comparison is rationalized in terms of an upper bound on the heat flux feedback, associated with "fast" atmospheric export of temperature and moisture anomalies away from the marine boundary layer, and a lower bound associated with "slow" export. It is found that regions of cold surface waters (≤ 10° C) are best described as approaching the slow export limit. This conclusion is not only valid at the synoptic scale resolved by the reanalysis data, but also on basin scales. In particular, it applies to the heat flux feedback acting as circumpolar SST anomaly scales are approached in the Southern Ocean, with feedbacks of ≤ 10 {W m}^{-2}{ K}^{-1} . In contrast, the magnitude of the heat flux feedback is close to that expected from the fast export limit over the Gulf Stream and its recirculation with values on the order of ≈40 {W m}^{-2}{ K}^{-1} . Further analysis suggests that this high value reflects a compensation between a moderate thermodynamic adjustment of the boundary layer, which tends to weaken the heat flux feedback, and an enhancement of the surface winds over warm SST anomalies, which tend to enhance the feedback.

  19. Combustion Gas Properties I-ASTM Jet a Fuel and Dry Air

    NASA Technical Reports Server (NTRS)

    Jones, R. E.; Trout, A. M.; Wear, J. D.; Mcbride, B. J.

    1984-01-01

    A series of computations was made to produce the equilibrium temperature and gas composition for ASTM jet A fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0.

  20. Some possibilities of using gas mixtures other than air in aerodynamic research

    NASA Technical Reports Server (NTRS)

    Chapman, Dean R

    1956-01-01

    A study is made of the advantages that can be realized in compressible-flow research by employing a substitute heavy gas in place of air. The present report is based on the idea that by properly mixing a heavy monatomic gas with a suitable heavy polyatomic gas, it is possible to obtain a heavy gas mixture which has the correct ratio of specific heats and which is nontoxic, nonflammable, thermally stable, chemically inert, and comprised of commercially available components. Calculations were made of wind-tunnel characteristics for 63 gas pairs comprising 21 different polyatomic gases properly mixed with each of three monatomic gases (argon, krypton, and zenon).

  1. Nitrogen-doped carbonaceous catalysts for gas-diffusion cathodes for alkaline aluminum-air batteries

    NASA Astrophysics Data System (ADS)

    Davydova, E. S.; Atamanyuk, I. N.; Ilyukhin, A. S.; Shkolnikov, E. I.; Zhuk, A. Z.

    2016-02-01

    Cobalt tetramethoxyphenyl porphyrin and polyacrylonitrile - based catalysts for oxygen reduction reaction were synthesized and characterized by means of SEM, TEM, XPS, BET, limited evaporation method, rotating disc and rotating ring-disc electrode methods. Half-cell and Al-air cell tests were carried out to determine the characteristics of gas-diffusion cathodes. Effect of active layer thickness and its composition on the characteristics of the gas-diffusion cathodes was investigated. Power density of 300 mW cm-2 was achieved for alkaline Al-air cell with an air-breathing polyacrylonitrile-based cathode.

  2. Gas phase dispersion in compost as a function of different water contents and air flow rates

    NASA Astrophysics Data System (ADS)

    Sharma, Prabhakar; Poulsen, Tjalfe G.

    2009-07-01

    Gas phase dispersion in a natural porous medium (yard waste compost) was investigated as a function of gas flow velocity and compost volumetric water content using oxygen and nitrogen as tracer gases. The compost was chosen because it has a very wide water content range and because it represents a wide range of porous media, including soils and biofilter media. Column breakthrough curves for oxygen and nitrogen were measured at relatively low pore gas velocities, corresponding to those observed in for instance soil vapor extraction systems or biofilters for air cleaning at biogas plants or composting facilities. Total gas mechanical dispersion-molecular diffusion coefficients were fitted from the breakthrough curves using a one-dimensional numerical solution to the advection-dispersion equation and used to determine gas dispersivities at different volumetric gas contents. The results showed that gas mechanical dispersion dominated over molecular diffusion with mechanical dispersion for all water contents and pore gas velocities investigated. Importance of mechanical dispersion increased with increasing pore gas velocity and compost water content. The results further showed that gas dispersivity was relatively constant at high values of compost gas-filled porosity but increased with decreasing gas-filled porosity at lower values of gas-filled porosity. Results finally showed that measurement uncertainty in gas dispersivity is generally highest at low values of pore gas velocity.

  3. Local effects of ice floes and leads on skin sea surface temperature, mixing and gas transfer in the marginal ice zone

    NASA Astrophysics Data System (ADS)

    Zappa, Christopher; Brumer, Sophia; Brown, Scott; LeBel, Deborah; McGillis, Wade; Schlosser, Peter; Loose, Brice

    2014-05-01

    Recent years have seen extreme changes in the Arctic. Marginal ice zones (MIZ), or areas where the "ice-albedo feedback" driven by solar warming is highest and ice melt is extensive, may provide insights into the extent of these changes. Furthermore, MIZ play a central role in setting the air-sea CO2 balance making them a critical component of the global carbon cycle. Incomplete understanding of how the sea-ice modulates gas fluxes renders it difficult to estimate the carbon budget in MIZ. Here, we investigate the turbulent mechanisms driving gas exchange in leads, polynyas and in the presence of ice floes using both field and laboratory measurements. Here, we present measurements of visible and IR imagery of melting ice floes in the marginal ice zone north of Oliktok Point AK in the Beaufort Sea made during the Marginal Ice Zone Ocean and Ice Observations and Processes EXperiment (MIZOPEX) in July-August 2013. The visible and IR imagery were taken from the unmanned airborne vehicle (UAV) ScanEagle. The visible imagery clearly defines the scale of the ice floes. The IR imagery show distinct cooling of the skin sea surface temperature (SST) as well as an intricate circulation and mixing pattern that depends on the surface current, wind speed, and near-surface vertical temperature/salinity structure. Individual ice floes develop turbulent wakes as they drift and cause transient mixing of an influx of colder surface (fresh) melt water. We capture a melting and mixing event that explains the changing pattern observed in skin SST and is substantiated using laboratory experiments. The Gas Transfer through Polar Sea Ice experiment was performed at the US Army Cold Regions Research and Engineering Laboratory (Hanover, NH) under varying ice coverage, winds speed, fetch and currents. Supporting measurements were made of air and water temperature, humidity, salinity and wave height. Air-side profiling provided momentum, heat, and CO2 fluxes. Transfer velocities are also

  4. OAFlux Satellite-Based High-Resolution Analysis of Air-Sea Turbulent Heat, Moisture, and Momentum Fluxes

    NASA Astrophysics Data System (ADS)

    Yu, Lisan

    2016-04-01

    The Objectively Analyzed air-sea Fluxes (OAFlux) project at the Woods Hole Oceanographic Institution has recently developed a new suite of products: the satellite-based high-resolution (HR) air-sea turbulent heat, moisture, and momentum fluxes over the global ocean from 1987 to the present. The OAFlux-HR fluxes are computed from the COARE bulk algorithm using air-sea variables (vector wind, near-surface humidity and temperature, and ocean surface temperature) derived from multiple satellite sensors and multiple missions. The vector wind time series are merged from 14 satellite sensors, including 4 scatterometers and 10 passive microwave radiometers. The near-surface humidity and temperature time series are retrieved from 11 satellite sensors, including 7 microwave imagers and 4 microwave sounders. The endeavor has greatly improved the depiction of the air-sea turbulent exchange on the frontal and meso-scales. The OAFlux-HR turbulent flux products are valuable datasets for a broad range of studies, including the study of the long-term change and variability in the oean-surface forcing functions, quantification of the large-scale budgets of mass, heat, and freshwater, and assessing the role of the ocean in the change and variability of the Earth's climate.

  5. Second international conference on air-sea interaction and on meteorology and oceanography of the coastal zone

    SciTech Connect

    1994-12-31

    This conference was held September 22--27, 1994 in Lisbon, Portugal. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on air-sea interactions. Individual papers have been processed separately for inclusion in the appropriate data bases.

  6. On the role of extratropical air-sea interaction in the persistence of the Southern Annular Mode

    NASA Astrophysics Data System (ADS)

    Xiao, Bei; Zhang, Yang; Yang, Xiu-Qun; Nie, Yu

    2016-08-01

    Using the daily atmosphere and ocean reanalysis data, this study highlights the role of extratropical air-sea interaction in the variability of the Southern Annular Mode (SAM). Our analysis shows that the SAM-induced meridional dipolar sea surface temperature (SST) anomalies, through surface heat fluxes, can maintain persistent lower tropospheric temperature anomalies, which further results in anomalous eddy momentum forcing enhancing the persistence of the SAM. With the Finite Amplitude Wave Activity diagnosis, we illustrate that response of the eddy momentum forcing to SST anomalies can be attributed to changes in both baroclinic processes as baroclinic eddy generation and barotropic processes as wave breaking thus resultant diffusive eddy mixing, with the former confined at high latitudes and the latter strongest at midlatitudes. Spectral analysis further suggests that the above air-sea interactions are important for bimonthly and longer time scale SAM variations. The dipolar SST pattern may be an indicator for predicting subseasonal and interseasonal variabilities of the SAM.

  7. Open Air Silicon Deposition by Atmospheric Pressure Plasma under Local Ambient Gas Control

    NASA Astrophysics Data System (ADS)

    Naito, Teruki; Konno, Nobuaki; Yoshida, Yukihisa

    2015-09-01

    In this paper, we report open air silicon (Si) deposition by combining a silane free Si deposition technology and a newly developed local ambient gas control technology. Recently, material processing in open air has been investigated intensively. While a variety of materials have been deposited, there were only few reports on Si deposition due to the susceptibility to contamination and the hazardous nature of source materials. Since Si deposition is one of the most important processes in device fabrication, we have developed open air silicon deposition technologies in BEANS project. For a clean and safe process, a local ambient gas control head was designed. Process gas leakage was prevented by local evacuation, and air contamination was shut out by inert curtain gas. By numerical and experimental investigations, a safe and clean process condition with air contamination less than 10 ppm was achieved. Si film was deposited in open air by atmospheric pressure plasma enhanced chemical transport under the local ambient gas control. The film was microcrystalline Si with the crystallite size of 17 nm, and the Hall mobility was 2.3 cm2/V .s. These properties were comparable to those of Si films deposited in a vacuum chamber. This research has been conducted as one of the research items of New Energy and Industrial Technology Development Organization ``BEANS'' project.

  8. 75 FR 63504 - Outer Continental Shelf, Alaska OCS Region, Chukchi Sea Planning Area, Oil and Gas Lease Sale 193

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-15

    ..., Chukchi Sea Planning Area, Oil and Gas Lease Sale 193 AGENCY: Bureau of Ocean Energy Management... information identified by BOEMRE in the 193 FEIS was essential or relevant under 40 CFR 1502.22; and (3... whether missing information identified by BOEMRE in the FEIS for Chukchi Sea Lease Sale 193 was...

  9. Effects of air current speed on gas exchange in plant leaves and plant canopies

    NASA Astrophysics Data System (ADS)

    Kitaya, Y.; Tsuruyama, J.; Shibuya, T.; Yoshida, M.; Kiyota, M.

    To obtain basic data on adequate air circulation to enhance plant growth in a closed plant culture system in a controlled ecological life support system (CELSS), an investigation was made of the effects of the air current speed ranging from 0.01 to 1.0 m s-1 on photosynthesis and transpiration in sweetpotato leaves and photosynthesis in tomato seedlings canopies. The gas exchange rates in leaves and canopies were determined by using a chamber method with an infrared gas analyzer. The net photosynthetic rate and the transpiration rate increased significantly as the air current speeds increased from 0.01 to 0.2 m s-1. The transpiration rate increased gradually at air current speeds ranging from 0.2 to 1.0 m s-1 while the net photosynthetic rate was almost constant at air current speeds ranging from 0.5 to 1.0 m s-1. The increase in the net photosynthetic and transpiration rates were strongly dependent on decreased boundary-layer resistances against gas diffusion. The net photosynthetic rate of the plant canopy was doubled by an increased air current speed from 0.1 to 1.0 m s-1 above the plant canopy. The results demonstrate the importance of air movement around plants for enhancing the gas exchange in the leaf, especially in plant canopies in the CELSS.

  10. Preparation of Fiber Based Binder Materials to Enhance the Gas Adsorption Efficiency of Carbon Air Filter.

    PubMed

    Lim, Tae Hwan; Choi, Jeong Rak; Lim, Dae Young; Lee, So Hee; Yeo, Sang Young

    2015-10-01

    Fiber binder adapted carbon air filter is prepared to increase gas adsorption efficiency and environmental stability. The filter prevents harmful gases, as well as particle dusts in the air from entering the body when a human inhales. The basic structure of carbon air filter is composed of spunbond/meltblown/activated carbon/bottom substrate. Activated carbons and meltblown layer are adapted to increase gas adsorption and dust filtration efficiency, respectively. Liquid type adhesive is used in the conventional carbon air filter as a binder material between activated carbons and other layers. However, it is thought that the liquid binder is not an ideal material with respect to its bonding strength and liquid flow behavior that reduce gas adsorption efficiency. To overcome these disadvantages, fiber type binder is introduced in our study. It is confirmed that fiber type binder adapted air filter media show higher strip strength, and their gas adsorption efficiencies are measured over 42% during 60 sec. These values are higher than those of conventional filter. Although the differential pressure of fiber binder adapted air filter is relatively high compared to the conventional one, short fibers have a good potential as a binder materials of activated carbon based air filter.

  11. Compressor discharge bleed air circuit in gas turbine plants and related method

    SciTech Connect

    Anand, Ashok Kumar; Berrahou, Philip Fadhel; Jandrisevits, Michael

    2002-01-01

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  12. Compressor discharge bleed air circuit in gas turbine plants and related method

    SciTech Connect

    Anand, Ashok Kumar; Berrahou, Philip Fadhel; Jandrisevits, Michael

    2003-04-08

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  13. Extreme subseasonal tropical air-sea interactions and their relation to ocean thermal stratification

    NASA Astrophysics Data System (ADS)

    Lloyd, Ian D.

    2011-12-01

    This thesis is concerned with extreme, rapid timescale tropical air-sea interactions and the influence of large-scale oceanic conditions on these interactions. The focus is on two types of extreme events: equatorial Indian Ocean cooling events and tropical cyclones. Cooling events occur on timescales of a few days to several weeks, in which atmospheric forcing causes Sea Surface Temperature (SST) cooling in the range of 1--5K, in both observational and coupled climate models. Cooling events are driven by changes in air-sea enthalpy fluxes and Ekman upwelling. Because the cooling due to Ekman upwelling depends on thermocline depth, large-scale oceanic conditions influence SST cooling. La Nina and negative Indian Ocean Dipole conditions are conducive to a shallower southwest equatorial thermocline, resulting in greater intraseasonal SST cooling during these interannual events; El Nino and positive Indian Ocean Dipole conditions lead to a deeper thermocline and reduced SST cooling. Results indicate that cooling events are related to the eastward propagation of convective patterns that resemble the Madden-Julian Oscillation. For tropical cyclones, the response of intensity to cyclone-induced SST cooling was explored over 10-years of observational data. For slow moving (V/ f < 100km) tropical cyclones, it was found that the SST cooling response increases along with storm intensity from category 0--2 on the Saffir-Simpson scale. However, from category 2--5 the magnitude of SST cooling decreases. This result confirms model predictions indicating a prominent role for oceanic feedback controlling tropical cyclone intensity. Thus, only storms that develop in regions containing deep mixed layer and thermocline can achieve high intensity, and entrainment cooling is weaker for these storms. The SST-intensity response in observations was compared to the GFDL Hurricane Forecast Model (GHM) for the periods 2005 and 2006--2009. The GHM was modified in 2006 to include a

  14. Combatting urban air pollution through Natural Gas Vehicle (NGV) analysis, testing, and demonstration

    SciTech Connect

    1995-03-01

    Deteriorating urban air quality ranks as a top concern worldwide, since air pollution adversely affects both public health and the environment. The outlook for improving air quality in the world`s megacities need not be bleak, however, The use of natural gas as a transportation fuel can measurably reduce urban pollution levels, mitigating chronic threats to health and the environment. Besides being clean burning, natural gas vehicles (NGVs) are economical to operate and maintain. The current cost of natural gas is lower than that of gasoline. Natural gas also reduces the vehicle`s engine wear and noise level, extends engine life, and decreases engine maintenance. Today, about 700,000 NGVs operate worldwide, the majority of them converted from gasoline or diesel fuel. This article discusses the economic, regulatory and technological issues of concern to the NGV industry.

  15. Numerical simulation of high pressure release and dispersion of hydrogen into air with real gas model

    NASA Astrophysics Data System (ADS)

    Khaksarfard, R.; Kameshki, M. R.; Paraschivoiu, M.

    2010-06-01

    Hydrogen is a renewable and clean source of energy, and it is a good replacement for the current fossil fuels. Nevertheless, hydrogen should be stored in high-pressure reservoirs to have sufficient energy. An in-house code is developed to numerically simulate the release of hydrogen from a high-pressure tank into ambient air with more accuracy. Real gas models are used to simulate the flow since high-pressure hydrogen deviates from ideal gas law. Beattie-Bridgeman and Abel Noble equations are applied as real gas equation of state. A transport equation is added to the code to calculate the concentration of the hydrogen-air mixture after release. The uniqueness of the code is to simulate hydrogen in air release with the real gas model. Initial tank pressures of up to 70 MPa are simulated.

  16. Gas bubbles in fossil amber as possible indicators of the major gas composition of ancient air

    USGS Publications Warehouse

    Berner, R.A.; Landis, G.P.

    1988-01-01

    Gases trapped in Miocene to Upper Cretaceous amber were released by gently crushing the amber under vacuum and were analyzed by quadrupole mass spectrometry. After discounting the possibility that the major gases N2, O2, and CO2 underwent appreciable diffusion and diagenetic exchange with their surroundings or reaction with the amber, it has been concluded that in primary bubbles (gas released during initial breakage) these gases represent mainly original ancient air modified by the aerobic respiration of microorganisms. Values of N2/(CO2+O2) for each time period give consistent results despite varying O2/CO2 ratios that presumably were due to varying degrees of respiration. This allows calculation of original oxygen concentrations, which, on the basis of these preliminary results, appear to have changed from greater than 30 percent O2 during one part ofthe Late Cretaceous (between 75 and 95 million years ago) to 21 percent during the Eocene-Oligocene and for present-day samples, with possibly lower values during the Oligocene-Early Miocene. Variable O2 levels over time in general confirm theoretical isotope-mass balance calculations and suggest that the atmosphere has evolved over Phanerozoic time.

  17. Hyperbaric oxygen treatment for air or gas embolism.

    PubMed

    Moon, R E

    2014-01-01

    Gas can enter arteries (arterial gas embolism) due to alveolar-capillary disruption (caused by pulmonary overpressurization, e.g., breath-hold ascent by divers) or veins (venous gas embolism, VGE) as a result of tissue bubble formation due to decompression (diving, altitude exposure) or during certain surgical procedures where capillary hydrostatic pressure at the incision site is sub-atmospheric. Both AGE and VGE can be caused by iatrogenic gas injection. AGE usually produces strokelike manifestations, such as impaired consciousness, confusion, seizures and focal neurological deficits. Small amounts of VGE are often tolerated due to filtration by pulmonary capillaries. However, VGE can cause pulmonary edema, cardiac "vapor lock" and AGE due to transpulmonary passage or right-to-left shunt through a patent foramen ovale. Intravascular gas can cause arterial obstruction or endothelial damage and secondary vasospasm and capillary leak. Vascular gas is frequently not visible with radiographic imaging, which should not be used to exclude the diagnosis of AGE. Isolated VGE usually requires no treatment; AGE treatment is similar to decompression sickness (DCS), with first aid oxygen then hyperbaric oxygen. Although cerebral AGE (CAGE) often causes intracranial hypertension, animal studies have failed to demonstrate a benefit of induced hypocapnia. An evidence-based review of adjunctive therapies is presented.

  18. Fuel-air mixing apparatus for reducing gas turbine combustor exhaust emissions

    NASA Technical Reports Server (NTRS)

    Zupanc, Frank J. (Inventor); Yankowich, Paul R. (Inventor)

    2006-01-01

    A fuel-air mixer for use in a combustion chamber of a gas turbine engine is provided. The fuel air mixing apparatus comprises an annular fuel injector having a plurality of discrete plain jet orifices, a first swirler wherein the first swirler is located upstream from the fuel injector and a second swirler wherein the second swirler is located downstream from the fuel injector. The plurality of discrete plain jet orifices are situated between the highly swirling airstreams generated by the two radial swirlers. The distributed injection of the fuel between two highly swirling airstreams results in rapid and effective mixing to the desired fuel-air ratio and prevents the formation of local hot spots in the combustor primary zone. A combustor and a gas turbine engine comprising the fuel-air mixer of the present invention are also provided as well as a method using the fuel-air mixer of the present invention.

  19. Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

    NASA Astrophysics Data System (ADS)

    Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

    2015-04-01

    While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

  20. Detection of room air contamination of angiographic CO2 with use of a gas analyzer.

    PubMed

    Culp, William C; Culp, William C

    2002-07-01

    The purpose of this study was to describe a practical method to detect room air contamination in CO2 used for angiography. Samples of CO2 with known room air contamination levels were used in a "bag system" of CO2 delivery and sampled by a gas analyzer commonly used in anesthesia. Nitrogen levels were reliably detected indicating contamination with as little as 2% air. Oxygen levels were reliably detected, indicating contamination with as little as 5% air. Measured CO2 values were unreliable with higher-than-true values at all levels except 100%. All clinically important amounts of N2 and O2 contamination were readily detected by this practical method.

  1. Hypothetical air ingress scenarios in advanced modular high temperature gas cooled reactors

    SciTech Connect

    Kroeger, P.G.

    1988-01-01

    Considering an extremely hypothetical scenario of complete cross duct failure and unlimited air supply into the reactor vessel of a modular high temperature gas cooled ractor, it is found that the potential air inflow remains limited due to the high friction pressure drop through the active core. All incoming air will be oxidized to CO and some local external burning would be temporarily possible in such a scenario. The accident would have to continue with unlimited air supply for hundreds of hours before the core structural integrity would be jeopardized.

  2. Air-sea exchange of gaseous mercury in the tropical coast (Luhuitou fringing reef) of the South China Sea, the Hainan Island, China.

    PubMed

    Ci, Zhijia; Zhang, Xiaoshan; Wang, Zhangwei

    2016-06-01

    The air-sea exchange of gaseous mercury (mainly Hg(0)) in the tropical ocean is an important part of the global Hg biogeochemical cycle, but the related investigations are limited. In this study, we simultaneously measured Hg(0) concentrations in surface waters and overlaying air in the tropical coast (Luhuitou fringing reef) of the South China Sea (SCS), Hainan Island, China, for 13 days on January-February 2015. The purpose of this study was to explore the temporal variation of Hg(0) concentrations in air and surface waters, estimate the air-sea Hg(0) flux, and reveal their influencing factors in the tropical coastal environment. The mean concentrations (±SD) of Hg(0) in air and total Hg (THg) in waters were 2.34 ± 0.26 ng m(-3) and 1.40 ± 0.48 ng L(-1), respectively. Both Hg(0) concentrations in waters (53.7 ± 18.8 pg L(-1)) and Hg(0)/THg ratios (3.8 %) in this study were significantly higher than those of the open water of the SCS in winter. Hg(0) in waters usually exhibited a clear diurnal variation with increased concentrations in daytime and decreased concentrations in nighttime, especially in cloudless days with low wind speed. Linear regression analysis suggested that Hg(0) concentrations in waters were positively and significantly correlated to the photosynthetically active radiation (PAR) (R (2) = 0.42, p < 0.001). Surface waters were always supersaturated with Hg(0) compared to air (the degree of saturation, 2.46 to 13.87), indicating that the surface water was one of the atmospheric Hg(0) sources. The air-sea Hg(0) fluxes were estimated to be 1.73 ± 1.25 ng m(-2) h(-1) with a large range between 0.01 and 6.06 ng m(-2) h(-1). The high variation of Hg(0) fluxes was mainly attributed to the greatly temporal variation of wind speed.

  3. Modeling CO2 air dispersion from gas driven lake eruptions

    NASA Astrophysics Data System (ADS)

    Chiodini, Giovanni; Costa, Antonio; Rouwet, Dmitri; Tassi, Franco

    2016-04-01

    The most tragic event of gas driven lake eruption occurred at Lake Nyos (Cameroon) on 21 August 1986, when a dense cloud of CO2 suffocated more than 1700 people and an uncounted number of animals in just one night. The event stimulated a series of researches aimed to understand gas origins, gas release mechanisms and strategies for gas hazard mitigation. Very few studies have been carried out for describing the transport of dense CO2 clouds in the atmosphere. Although from a theoretical point of view, gas dispersion can be fully studied by solving the complete equations system for mass, momentum and energy transport, in actual practice, different simplified models able to describe only specific phases or aspects have to be used. In order to simulate dispersion of a heavy gas and to assess the consequent hazard we used a model based on a shallow layer approach (TWODEE2). This technique which uses depth-averaged variables to describe the flow behavior of dense gas over complex topography represents a good compromise between the complexity of computational fluid dynamic models and the simpler integral models. Recently the model has been applied for simulating CO2 dispersion from natural gas emissions in Central Italy. The results have shown how the dispersion pattern is strongly affected by the intensity of gas release, the topography and the ambient wind speed. Here for the first time we applied TWODEE2 code to simulate the dispersion of the large CO2 clouds released by limnic eruptions. An application concerns the case of the 1986 event at lake Nyos. Some difficulties for the simulations were related to the lack of quantitative information: gas flux estimations are not well constrained, meteorological conditions are only qualitatively known, the digital model of the terrain is of poor quality. Different scenarios were taken into account in order to reproduce the qualitative observations available for such episode. The observations regard mainly the effects of gas on

  4. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

    EPA Science Inventory

    Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are...

  5. Dynamics of air-sea CO2 fluxes in the North-West European Shelf based on Voluntary Observing Ship (VOS) and satellite observations

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Macé, E.; Morin, P.; Salt, L. A.; Vernet, M.; Taylor, B.; Paxman, K.; Bozec, Y.

    2015-04-01

    From January 2011 to December 2013, we constructed a comprehensive pCO2 dataset based on voluntary observing ship (VOS) measurements in the Western English Channel (WEC). We subsequently estimated surface pCO2 and air-sea CO2 fluxes in north-west European continental shelf waters using multiple linear regressions (MLRs) from remotely sensed sea surface temperature (SST), chlorophyll a concentration (Chl a), the gas transfer velocity coefficient (K), photosynthetically active radiation (PAR) and modeled mixed layer depth (MLD). We developed specific MLRs for the seasonally stratified northern WEC (nWEC) and the permanently well-mixed southern WEC (sWEC) and calculated surface pCO2 with relative uncertainties of 17 and 16 μatm, respectively. We extrapolated the relationships obtained for the WEC based on the 2011-2013 dataset (1) temporally over a decade and (2) spatially in the adjacent Celtic and Irish Seas (CS and IS), two regions which exhibit hydrographical and biogeochemical characteristics similar to those of WEC waters. We validated these extrapolations with pCO2 data from the SOCAT database and obtained relatively robust results with an average precision of 4 ± 22 μatm in the seasonally stratified nWEC and the southern and northern CS (sCS and nCS), but less promising results in the permanently well-mixed sWEC, IS and Cap Lizard (CL) waters. On an annual scale, seasonally stratified systems acted as a sink of CO2 from the atmosphere of -0.4, -0.9 and -0.4 mol C m-2 year-1 in the nCS, sCS and nWEC, respectively, whereas, permanently well-mixed systems acted as source of CO2 to the atmosphere of 0.2, 0.4 and 0.4 mol C m-2 year-1 in the sWEC, CL and IS, respectively. Air-sea CO2 fluxes showed important inter-annual variability resulting in significant differences in the intensity and/or direction of annual fluxes. We scaled the mean annual fluxes over six provinces for the last decade and obtained the first annual average uptake of -0.95 Tg C year-1 for this

  6. Natural Air-Sea Flux of CO2 in Simulations of the NASA-GISS Climate Model: Sensitivity to the Physical Ocean Model Formulation

    NASA Technical Reports Server (NTRS)

    Romanou, A.; Gregg, Watson W.; Romanski, J.; Kelley, M.; Bleck, R.; Healy, R.; Nazarenko, L.; Russell, G.; Schmidt, G. A.; Sun, S.; Tausnev, N.

    2013-01-01

    Results from twin control simulations of the preindustrial CO2 gas exchange (natural flux of CO2) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air-sea flux of CO2, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO2) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean).

  7. High-pressure ceramic air heater for indirectly fired gas turbine applications

    NASA Astrophysics Data System (ADS)

    Lahaye, P. G.; Briggs, G. F.; Vandervort, C. L.; Seger, J. L.

    The Externally-Fired Combined Cycle (EFCC) offers a method for operating high-efficiency gas and steam turbine combined cycles on coal. In the EFCC, an air heater replaces the gas turbine combustor so that the turbine can be indirectly fired. Ceramic materials are required for the heat exchange surfaces to accommodate the operating temperatures of modern gas turbines. The ceramic air heater or heat exchanger is the focus of this program, and the two primary objectives are (1) to demonstrate that a ceramic air heater can be reliably pressurized to a level of 225 psia (1.5 MPa); and (2) to show that the air heater can withstand exposure to the products of coal combustion at elevated temperatures. By replacing the gas turbine combustor with a ceramic air heater, the cycle can use coal or other ash-bearing fuels. Numerous programs have attempted to fuel high efficiency gas turbines directly with coal, often resulting in significant ash deposition upon turbine components and corrosion or erosion of turbine blades. This report will show that a ceramic air heater is significantly less susceptible to ash deposition or corrosion than a gas turbine when protected by rudimentary methods of gas-stream clean-up. A 25 x 10(sup 6) Btu/hr (7 MW) test facility is under construction in Kennebunk, Maine. It is anticipated that this proof of concept program will lead to commercialization of the EFCC by electric utility and industrial organizations. Applications are being pursued for power plants ranging from 10 to 100 megawatts.

  8. Methane distribution and sea-to-air flux in the East China Sea during the summer of 2013: Impact of hypoxia

    NASA Astrophysics Data System (ADS)

    Ye, Wangwang; Zhang, Guiling; Zhu, Zhuoyi; Huang, Daji; Han, Yu; Wang, Lan; Sun, Mingshuang

    2016-02-01

    We measured dissolved methane (CH4) at different depths and calculated sea-to-air CH4 fluxes at 65 stations in the East China Sea (ECS) from August 4 to 31 of 2013. CH4 concentrations in surface waters ranged from 2.07 to 27.39 nM and concentrations in bottom waters ranged from 1.76 to 31.35 nM. The concentration of CH4 also decreased with distance from the Changjiang (Yangtze River) Estuary. Analysis of the depth profiles of CH4 indicated great variations among the different stations due to the influence of different water masses and variations in other factors. A region of significant bottom-water hypoxia, with an oxygen level less than 1.5 mg L-1, occurred at the northern region of the ECS. This hypoxic region also had enhanced CH4 production in the water column and sedimentary release of CH4. CH4 saturations in the surface waters ranged from 113% to 1364%, with an average of 317% (±236). We estimated the sea-to-air CH4 flux as 6.5±7.4 μmol m-2 d-1 using the LM86 equation, and as 11.5±11.9 μmol m-2 d-1 using the W92 equation. The overall estimated CH4 emission rate from the ECS was 6.4×10-2 Tg yr-1. The saturation and sea-to-air flux of CH4 varied significantly among the stations. Taken together, our data suggest that the ECS is a net source of atmospheric CH4.

  9. Nondestructive natural gas hydrate recovery driven by air and carbon dioxide

    NASA Astrophysics Data System (ADS)

    Kang, Hyery; Koh, Dong-Yeun; Lee, Huen

    2014-10-01

    Current technologies for production of natural gas hydrates (NGH), which include thermal stimulation, depressurization and inhibitor injection, have raised concerns over unintended consequences. The possibility of catastrophic slope failure and marine ecosystem damage remain serious challenges to safe NGH production. As a potential approach, this paper presents air-driven NGH recovery from permeable marine sediments induced by simultaneous mechanisms for methane liberation (NGH decomposition) and CH4-air or CH4-CO2/air replacement. Air is diffused into and penetrates NGH and, on its surface, forms a boundary between the gas and solid phases. Then spontaneous melting proceeds until the chemical potentials become equal in both phases as NGH depletion continues and self-regulated CH4-air replacement occurs over an arbitrary point. We observed the existence of critical methane concentration forming the boundary between decomposition and replacement mechanisms in the NGH reservoirs. Furthermore, when CO2 was added, we observed a very strong, stable, self-regulating process of exchange (CH4 replaced by CO2/air; hereafter CH4-CO2/air) occurring in the NGH. The proposed process will work well for most global gas hydrate reservoirs, regardless of the injection conditions or geothermal gradient.

  10. Nondestructive natural gas hydrate recovery driven by air and carbon dioxide

    PubMed Central

    Kang, Hyery; Koh, Dong-Yeun; Lee, Huen

    2014-01-01

    Current technologies for production of natural gas hydrates (NGH), which include thermal stimulation, depressurization and inhibitor injection, have raised concerns over unintended consequences. The possibility of catastrophic slope failure and marine ecosystem damage remain serious challenges to safe NGH production. As a potential approach, this paper presents air-driven NGH recovery from permeable marine sediments induced by simultaneous mechanisms for methane liberation (NGH decomposition) and CH4-air or CH4-CO2/air replacement. Air is diffused into and penetrates NGH and, on its surface, forms a boundary between the gas and solid phases. Then spontaneous melting proceeds until the chemical potentials become equal in both phases as NGH depletion continues and self-regulated CH4-air replacement occurs over an arbitrary point. We observed the existence of critical methane concentration forming the boundary between decomposition and replacement mechanisms in the NGH reservoirs. Furthermore, when CO2 was added, we observed a very strong, stable, self-regulating process of exchange (CH4 replaced by CO2/air; hereafter CH4-CO2/air) occurring in the NGH. The proposed process will work well for most global gas hydrate reservoirs, regardless of the injection conditions or geothermal gradient. PMID:25311102

  11. Sea-air of CO2 in the North Pacific using shipboard and satellite data

    NASA Technical Reports Server (NTRS)

    Stephens, Mark P.; Samuels, Geoffrey; Olson, Donald B.; Fine, Rana A.; Takahashi, Taro

    1995-01-01

    A method has been developed to produce high-resolution maps of pCO2 in surface water for the North Pacific using satellite sea surface temperature (SST) data and statistical relationships between measured pCO2 and temperature. In the subtropical North Pacific the pCO in seawater is controlled primarily by temperature. Accordingly, pCO2 values that are calculated from the satellite SST data have good agreement with the measured values (rms deviation of +/- microatm). In the northwestern subpolar region the pCO2 is controlled not only by temperature, but also by significant seasonal changes in the total CO2 concentration, which are caused by seasonal changes in primary production, mixing with subsurface waters and sea-air exchange. Consequently, the parameterization of oceanic p CO2 based on SST data alone is not totally successful in the northwestern region (rms deviation of +/- 40 microatm). The use of additional satellite products, such as wind and ocean color data, as planned for a future study, is considered necessary to account for the pCO2 variability caused by seasonal changes in the total CO2 concentration. The net CO2 flux for the area of the North Pacific included in this study (north of 10 deg N) has been calculated using the monthly pCO2 distributions computed, and monthly wind speeds from the European Centre for Medium-Range Weather Forecasts. The region is found to be a net source to the atmosphere of 1.9 x 10(exp 12) to 5.8 x 10(exp 12) moles of CO2 per year (or 0.02-0.07 Gt C/yr), most of the outflux occurring in the subtropics.

  12. Air pollutant transport in a coastal environment. Part 1: Two-dimensional simulations of sea-breeze and mountain effects

    NASA Technical Reports Server (NTRS)

    Lu, Rong; Turco, Richard P.

    1994-01-01

    Over the southern California coastal region, observations of the vertical distributions of pollutants show that maximum concentrations can occur within temperature inversion layers well above the surface. A mesoscale model is used to study the dynamical phenomena that cause such layers, including sea breezes and mountain flows, and to study the characteristics of air pollutant transport in a coastal environment capped by a temperature inversion. The mathematical and physical structure of the model is described. Two-dimensional simulations corresponding to four configurations of coastal plains and mountains are discussed. The simulations reveal that pollutant transport over a coastal plain is strongly influenced by the topographic configuration, including the height of coastal mountains and their distance from the coastline. Sea breezes induced by land-sea thermal contrasts, as well as upslope winds induced along mountain flanks, both create vertical transport that can lead to the formation of elevated pollution layers. The sea-breeze circulation generates pollution layers by undercutting the mixed layer and lofting pollutants into the stable layer. Heating of mountain slopes acts to vent pollutants above the mountain ridge during the day; during the evening, pollutants can be injected directly into the inversion layer from the decaying upslope flows. In a land-sea configuration with mountains close to the coastline, the sea breeze and heated-mountain flow are strongly coupled. In the afternoon, this interaction can produce upslope flow from which polluted air is detrained into the inversion layer as a return circulation. When the mountains lie farther inland, however, pollutants may be trapped aloft when the mixed layer stabilizes in the late afternoon. As the nocturnal boundary layer forms over the coast in the evening, polluted mixed-layer air is effectively left behind in the inversion layer. In the Los Angeles Basin, the formation mechanism for elevated

  13. Roughness of Weddell Sea Ice and Estimates of the Air-Ice Drag Coefficient

    NASA Astrophysics Data System (ADS)

    Andreas, Edgar L.; Lange, Manfred A.; Ackley, Stephen F.; Wadhams, Peter

    1993-07-01

    The roughness of a sheet of sea ice encodes its deformational history and determines its aerodynamic coupling with the overlying air and underlying water. Here we report snow surface, ice surface, and ice underside roughness computed from 47 surface elevation profiles collected during a transect of the Weddell Sea. The roughness for each surface, parameterized as the standard deviation of the surface elevation, segregates according to whether or not a floe has been deformed: deformed ice has greater roughness than undeformed ice. Regardless of deformational history, the underside roughness is almost always greater than the snow surface and ice surface roughnesses, which are nearly equal. Roughness spectra for all three surfaces and for both deformed and undeformed ice roll off roughly as k-1 when the wavenumber k is between 0.1 and 3 rad m-1. The snow surface and underside spectra roll off somewhat faster than k-1, and the ice surface spectra roll off somewhat slower than k-1. Both top and underside Arctic ice roughness spectra, on the other hand, have been reported to roll off faster than k-2. We speculate that the excess spectral intensity at high wavenumbers in the Antarctic ice surface spectra results from the small-scale roughness that the ice sheet had on consolidation. This excess high-wavenumber spectral intensity persists in the ice surface spectra of second-year ice. Evidently, once formed, the ice surface remains unchanged on the microscale until the entire ice sheet melts. With a remote measurement of roughness, we should be able to decide whether an ice floe is deformed or undeformed. Our spectral analysis hints that remote sensing may also be able to differentiate between first-year and second-year ice. From the snow surface spectra, we compute a roughness scale ξ that parameterizes the air-ice momentum coupling and lets us estimate the neutral stability drag coefficient referenced to a height of 10 m, CDN10. Typical CDN10 values are 1.1-1.4 × 10

  14. First assessment of effects of air-gun seismic shooting on marine resources in the central Adriatic sea

    SciTech Connect

    La Bella, G.; Cannata, S.; Froglia, C.

    1996-11-01

    A series of investigations were carried out to test the effects of air-gun seismic shooting on main fishery resources of the Adriatic Sea during summer 1995. The energy source used for the trial was formed by one air-gun array made up by two sub-arrays consisting in 8 air-guns each developing a total volume of c.a. 2500 i{sup 3} at 2000 psi with an amplitude of 60 bar/m. The interval between two was of 25 s. The intensity was of 210 dB re 1 mPa-m/Hz. Acoustical and spectral analysis were performed simultaneously in the surveyed areas to correlate fishery and behavior observations with sound pattern of the energization. Main results were: (1) Analysis of trawl catch data evidenced no significant changes before and after the air-gun seismic profiling. (2) Echosurvey relative estimate of pelagic biomass, performed simultaneously to trawling operations, failed to evidence any significant change in the pelagic biomass subsequent to the seismic shooting. (3) Small differences were observed in the trammel net catch composition, but one single set of pre-post fishing operations could be done in the study period. (4) Similar density estimate were obtained from dredge surveys performed by an hydraulic dredger before and after air-gun seismic profiling over a clam bed in 14 in depth. (5) Video recording of captive fish, kept into cages moored on the sea bottom at 12 in depth, evidenced a Behavioral response to the approach of the sound source; but no lethal event was recorded on captive sea-bass immediately after the seismic shooting. (6) Biochemical and histological analysis were performed to verify if it is to be related to the captive condition or is somewhat consequent to the air-gun energization. These results confirm that no relevant effects are induced on fishery resources by seismic air-gun shooting.

  15. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  16. Natural Gas and Hydrate Accumulations in the Aleutian Basin of the Bering Sea

    NASA Astrophysics Data System (ADS)

    Barth, G. A.; Scholl, D. W.; Childs, J. R.

    2003-12-01

    The deep water Aleutian Basin of the Bering Sea is a major storehouse of trapped greenhouse gases. Preliminary volume estimates based on seismic reflection observations easily approach 1000 Tcf of natural gas within the basin. USGS seismic reflection data from the deep water (>3500 m) Bering Sea region include over 20,000 km of single channel profiles coincident with GLORIA sonar tracks acquired during the 1986-7 EEZscan program, plus several older multichannel lines also crossing the deep water Aleutian and Bowers Basins. These airgun-source data all provide images from seafloor to basement, over 3 km of penetration. The basin fill includes generally horizontal and uniform sedimentary reflection sequences, comprising predominantly mudstones and distal turbidites, upon oceanic crust of probable Cretaceous age. In seismic reflection images of these flat-lying sediments, methane chimneys overlain by hydrate caps stand out as distinctive velocity pseudostructures. These velocity-amplitude anomaly structures ("VAMPs") characteristically include a zone of velocity pull-up (attributed to high-seismic-velocity hydrate within the sediment) directly overlying a zone of velocity push-down (attributed to low-seismic-velocity gas in the pore spaces). A prominent hydrate bottom simulating reflection (BSR) is also present throughout the basin. Within the VAMPs, the BSR roughly separates the pull-up from the push-down. Hundreds of VAMPs have been imaged, and thousands must exist within the deep water basin. Individual examples vary widely in lateral extent, focused appearance, and amplitude effects. Some also present a seafloor manifestation of slight doming. Five example case studies are presented, focusing particularly on interval travel time anomalies and quantitative interpretation in terms of presence of hydrate and free gas. Individual large VAMPs (1-3 km across, ˜30 ms pull-up, ˜80 ms push-down) are estimated to contain gas volumes (including hydrate) similar to those of

  17. Template-directed fabrication of porous gas diffusion layer for magnesium air batteries

    NASA Astrophysics Data System (ADS)

    Xue, Yejian; Miao, He; Sun, Shanshan; Wang, Qin; Li, Shihua; Liu, Zhaoping

    2015-11-01

    The uniform micropore distribution in the gas diffusion layers (GDLs) of the air-breathing cathode is very important for the metal air batteries. In this work, the super-hydrophobic GDL with the interconnected regular pores is prepared by a facile silica template method, and then the electrochemical properties of the Mg air batteries containing these GDLs are investigated. The results indicate that the interconnected and uniform pore structure, the available water-breakout pressure and the high gas permeability coefficient of the GDL can be obtained by the application of 30% silica template. The maximum power density of the Mg air battery containing the GDL with 30% regular pores reaches 88.9 mW cm-2 which is about 1.2 times that containing the pristine GDL. Furthermore, the GDL with 30% regular pores exhibits the improved the long term hydrophobic stability.

  18. Blood platelet-derived microparticles release and bubble formation after an open-sea air dive.

    PubMed

    Pontier, Jean-Michel; Gempp, Emmanuel; Ignatescu, Mihaela

    2012-10-01

    Bubble-induced platelet aggregation offers an index for evaluating decompression severity in humans and in a rat model of decompression sickness. Endothelial cells, blood platelets, or leukocytes shed microparticles (MP) upon activation and during cell apoptosis. The aim was to study blood platelet MP (PMP) release and bubble formation after a scuba-air dive in field conditions. Healthy, experienced divers were assigned to 1 experimental group (n = 10) with an open-sea air dive to 30 msw for 30 min and 1 control group (n = 5) during head-out water immersion for the same period. Bubble grades were monitored with a pulsed doppler according to Kissman Integrated Severity Score (KISS). Blood samples for platelet count (PC) and PMP (annexin V and CD41) were taken 1 h before and after exposure in both groups. The result showed a decrease in post-dive PC compared with pre-dive values in experimental group with no significant change in the control group. We observed a significant increase in PMP values after the dive while no change was revealed in the control group. There was a significant positive correlation between the PMP values after the dive and the KISS bubble score. The present study highlighted a relationship between the post-dive decrease in PC, platelet MP release, and bubble formation. Release of platelet MPs could reflect bubble-induced platelet aggregation and could play a key role in alteration of the coagulation. Further studies must investigate endothelial and leukocyte MP release in the same field conditions.

  19. Regional Mapping and Resource Assessment of Shallow Gas Hydrates of Japan Sea - METI Launched 3 Years Project in 2013.

    NASA Astrophysics Data System (ADS)

    Matsumoto, R.

    2014-12-01

    Agency of Natural Resources and Energy of METI launched a 3 years shallow gas hydrate exploration project in 2013 to make a precise resource assessment of shallow gas hydrates in the eastern margin of Japan Sea and around Hokkaido. Shallow gas hydrates of Japan Sea occur in fine-grained muddy sediments of shallow subsurface of mounds and gas chimneys in the form of massive nodular to platy accumulation. Gas hydrate bearing mounds are often associated with active methane seeps, bacterial mats and carbonate concretions and pavements. Gases of gas hydrates are derived either from deep thermogenic, shallow microbial or from the mixed gases, contrasting with totally microbial deep-seated stratigraphically controlled hydrates. Shallow gas hydrates in Japan Sea have not been considered as energy resource due to its limited distribution in narrow Joetsu basin. However recently academic research surveys have demonstrated regional distribution of gas chimney and hydrate mound in a number of sedimentary basins along the eastern margin of Japan Sea. Regional mapping of gas chimney and hydrate mound by means of MBES and SBP surveys have confirmed that more than 200 gas chimneys exist in 100 km x 100 km area. ROV dives have identified dense accumulation of hydrates on the wall of half collapsed hydrate mound down to 30 mbsf. Sequential LWD and shallow coring campaign in the Summer of 2014, R/V Hakurei, which is equipped with Fugro Seacore R140 drilling rig, drilled through hydrate mounds and gas chimneys down to the BGHS (base of gas hydrate stability) level and successfully recovered massive gas hydrates bearing sediments from several horizons.

  20. Neotectonics, sea level change, and Quaternary natural gas occurrence in coastal Maine

    SciTech Connect

    Kelly, J.T.; Belknap, D.F.; Shipp, C.R.

    1985-02-01

    The glaciated, passive continental margin of northern New England is not a likely location for either tectonic activity or hydrocarbon accumulation, but neotectonic action has played a role in creating favorable stratigraphic traps for natural gas in the Quaternary inner-shelf and estuarine deposits of Maine. During late glacial time (13,000 year B.P.), a marine inundation accompanied ice retreat across the isostatically depressed lowlands of coastal Maine and blanketed the area with marine sediment (Presumpscot Formation) up to 50 m thick. Unloading of the ice led to rapid coastal rebound within a few thousand years, and the former sea floor became emergent to present depths of -65 m. A gullied and weathered lag surface on the muddy Presumpscot Formation marks the regression that followed deposition. Since about 8000 years B.P., sea level has risen in Maine, and within historic times it has been accompanied by seismicity and subsidence rates up to 9 mm/yr. Examinations of over 1500 km of seismic reflection profiles and limited coring reveal the presence of abundant natural gas in Holocene sediments filling ravines cut into the Presumpscot Formation during emergence. It appears that the gas is derived from and trapped by mud deposited in estuarine depocenters that migrated landward during the Holocene transgression.

  1. Fluid Leakage Pathways and Shallow Gas Accumulation in Peon field, northern North Sea

    NASA Astrophysics Data System (ADS)

    Vadakkepuliyambatta, S.; Planke, S.; Bunz, S.

    2012-12-01

    Shallow gas accumulations are well known as a hazard for drilling activities as well as future prospective reservoirs. The Peon field is a huge shallow gas accumulation located in the northern North Sea discovered by Statoil in 2005. The Peon sandstone reservoir is formed as a sub-aquatic, ice-contact glaciomarine fan in Pleistocene (0.01-1.8 Ma) and is located 574m below sea level. The reservoir covers a large area of 250 km2 and contains approximately 35GSm3 gas in place. We use high-resolution P-Cable 3D seismic data to characterize the shallow gas reservoir, fluid leakage pathways and geological features in the Pleistocene sediments. The survey was acquired in 2009 and covers an area of 210 km2. The seismic data has a vertical resolution of 4.5m and provide significantly improved details of the internal structure of shallow gas reservoir and associated fluid flow. The P-Cable data provide high-resolution seismic images up to one second two-way travel time. Conventional 3D seismic data is used to analyze deeper features. In addition, well logs from exploration wells in the area are integrated with the seismic interpretation. The top of Peon sandstone reservoir is marked by a strong, polarity-reversed reflection at ~165m below seafloor. The neutron porosity log and density log distinguish gas-water contact at ~184m below seafloor. The upper regional unconformity (URU) marks the base of the sandstone body at ~198m below seafloor and separates it from westward dipping Late Pliocene sequences. Unconsolidated Pleistocene sediment sequences overlying the reservoir exhibits glacial plough marks indicating periodic glacial activity. High-amplitude reflections in the glacially deposited, unconsolidated formations above the reservoir and pull-down in reflections indicate presence of gas. Chaotic, low-amplitude reflections below the high-amplitude reflections could be due to upward migrating gas. Pockmark-like depressions, varying in width from ~200m to ~400m occur at

  2. CACD (Complex Air Cleaning Devices) of the GTE (Gas turbine electrostation)-110: Problems and solutions

    NASA Astrophysics Data System (ADS)

    Budakov, I. V.; Neuimin, V. M.

    2015-12-01

    The paper considers CACD of the compressor of the GTE-110 gas turbine. The CACD efficiency has been tested under different conditions of the GTE-325 of the Ivanovo combined cycle plant (CCP) JSC INTER RAO-Electrogeneration Exploitation. It sets out the requirements for the dust collector, de-icing system, and air intake tract CACD. De-icing and air preparation methods are shown.

  3. An evaluation of thermal energy storage options for precooling gas turbine inlet air

    SciTech Connect

    Antoniak, Z.I.; Brown, D.R.; Drost, M.K.

    1992-12-01

    Several approaches have been used to reduce the temperature of gas turbine inlet air. One of the most successful uses off-peak electric power to drive vapor-compression-cycle ice makers. The ice is stored until the next time high ambient temperature is encountered, when the ice is used in a heat exchanger to cool the gas turbine inlet air. An alternative concept would use seasonal thermal energy storage to store winter chill for inlet air cooling. The objective of this study was to compare the performance and economics of seasonal thermal energy storage in aquifers with diurnal ice thermal energy storage for gas turbine inlet air cooling. The investigation consisted of developing computer codes to model the performance of a gas turbine, energy storage system, heat exchangers, and ancillary equipment. The performance models were combined with cost models to calculate unit capital costs and levelized energy costs for each concept. The levelized energy cost was calculated for three technologies in two locations (Minneapolis, Minnesota and Birmingham, Alabama). Precooling gas turbine inlet air with cold water supplied by an aquifer thermal energy storage system provided lower cost electricity than simply increasing the size of the turbine for meteorological and geological conditions existing in the Minneapolis vicinity. A 15 to 20% cost reduction resulted for both 0.05 and 0.2 annual operating factors. In contrast, ice storage precooling was found to be between 5 and 20% more expensive than larger gas turbines for the Minneapolis location. In Birmingham, aquifer thermal energy storage precooling was preferred at the higher capacity factor and ice storage precooling was the best option at the lower capacity factor. In both cases, the levelized cost was reduced by approximately 5% when compared to larger gas turbines.

  4. Measurements of laminar burning velocities for natural gas-hydrogen-air mixtures

    SciTech Connect

    Huang, Zuohua; Zhang, Yong; Zeng, Ke; Liu, Bing; Wang, Qian; Jiang, Deming

    2006-07-15

    Laminar flame characteristics of natural gas-hydrogen-air flames were studied in a constant-volume bomb at normal temperature and pressure. Laminar burning velocities and Markstein lengths were obtained at various ratios of hydrogen to natural gas (volume fraction from 0 to 100%) and equivalence ratios (f from 0.6 to 1.4). The influence of stretch rate on flame was also analyzed. The results show that, for lean mixture combustion, the flame radius increases with time but the increasing rate decreases with flame expansion for natural gas and for mixtures with low hydrogen fractions, while at high hydrogen fractions, there exists a linear correlation between flame radius and time. For rich mixture combustion, the flame radius shows a slowly increasing rate at early stages of flame propagation and a quickly increasing rate at late stages of flame propagation for natural gas and for mixtures with low hydrogen fractions, and there also exists a linear correlation between flame radius and time for mixtures with high hydrogen fractions. Combustion at stoichiometric mixture demonstrates the linear relationship between flame radius and time for natural gas-air, hydrogen-air, and natural gas-hydrogen-air flames. Laminar burning velocities increase exponentially with the increase of hydrogen fraction in mixtures, while the Markstein length decreases and flame instability increases with the increase of hydrogen fractions in mixture. For a fixed hydrogen fraction, the Markstein number shows an increase and flame stability increases with the increase of equivalence ratios. Based on the experimental data, a formula for calculating the laminar burning velocities of natural gas-hydrogen-air flames is proposed. (author)

  5. An evaluation of thermal energy storage options for precooling gas turbine inlet air

    NASA Astrophysics Data System (ADS)

    Antoniak, Z. I.; Brown, D. R.; Drost, M. K.

    1992-12-01

    Several approaches have been used to reduce the temperature of gas turbine inlet air. One of the most successful uses off-peak electric power to drive vapor-compression-cycle ice makers. The ice is stored until the next time high ambient temperature is encountered, when the ice is used in a heat exchanger to cool the gas turbine inlet air. An alternative concept would use seasonal thermal energy storage to store winter chill for inlet air cooling. The objective of this study was to compare the performance and economics of seasonal thermal energy storage in aquifers with diurnal ice thermal energy storage for gas turbine inlet air cooling. The investigation consisted of developing computer codes to model the performance of a gas turbine, energy storage system, heat exchangers, and ancillary equipment. The performance models were combined with cost models to calculate unit capital costs and levelized energy costs for each concept. The levelized energy cost was calculated for three technologies in two locations (Minneapolis, Minnesota and Birmingham, Alabama). Precooling gas turbine inlet air with cold water supplied by an aquifer thermal energy storage system provided lower cost electricity than simply increasing the size of the turbine for meteorological and geological conditions existing in the Minneapolis vicinity. A 15 to 20 percent cost reduction resulted for both 0.05 and 0.2 annual operating factors. In contrast, ice storage precooling was found to be between 5 and 20 percent more expensive than larger gas turbines for the Minneapolis location. In Birmingham, aquifer thermal energy storage precooling was preferred at the higher capacity factor and ice storage precooling was the best option at the lower capacity factor. In both cases, the levelized cost was reduced by approximately 5 percent when compared to larger gas turbines.

  6. Spatial and temporal variability of air-sea CO2 exchange of alongshore waters in summer near Barrow, Alaska

    NASA Astrophysics Data System (ADS)

    Ikawa, Hiroki; Oechel, Walter C.

    2014-03-01

    Alongshore water off Barrow, Alaska is a useful area for studying the carbon cycle of the Arctic coastal sea, because the different coastal characteristics extant in the area likely represent much larger regions of the coastal water of the western Arctic Ocean. Especially noteworthy is the inflow shelf water transferred northward by the Arctic Coastal Current into the Chukchi Sea from the North Pacific and turbid water in the Elson Lagoon where a significant amount of coastal erosion has been reported along the extensive coastal line and where a part of the water from the lagoon drains into the Beaufort Sea adjacent to the Chukchi Sea. To investigate spatial and temporal variations of air-sea CO2 flux (CO2 flux) of the alongshore water, partial pressure of CO2 of surface seawater (pCO2sw) was measured in summer, 2007 and 2008, and CO2 flux was directly measured by eddy covariance at a fixed point for the Beaufort Sea in summer 2008. Measured pCO2sw in the Chukchi Sea side was the lowest in the beginning of the measurement season and increased later in the season both in 2007 and 2008. The average CO2 flux estimated based on pCO2sw in the Chukchi Sea side was -0.10 μmol m-2 s-1 (±0.1 s.d.) using the sign convention of positive fluxes into the atmosphere from the ocean. pCO2sw in the Beaufort Sea and the Elson Lagoon was relatively higher in early summer and decreased in the middle of the summer. The overall average CO2 flux was -0.07 μmol m-2 s-1 (±0.1 s.d.) for the Beaufort Sea side and -0.03 μmol m-2 s-1 (±0.07 s.d.) for the Elson Lagoon respectively, indicating a sink of CO2 despite high carbon inflows from the terrestrial margin into the Elson Lagoon. A strong sink of CO2 was often observed from the Beaufort Sea by eddy covariance in the middle of the summer. This sink activity in the middle summer in the Beaufort Sea and Elson Lagoon was likely due to biological carbon uptake as inferred by low apparent oxygen utilization and high chlorophyll

  7. Fate of hazardous air pollutants in oxygen-fired coal combustion with different flue gas recycling.

    PubMed

    Zhuang, Ye; Pavlish, John H

    2012-04-17

    Experiments were performed to characterize transformation and speciation of hazardous air pollutants (HAPs), including SO(2)/SO(3), NO(x), HCl, particulate matter, mercury, and other trace elements in oxygen-firing bituminous coal with recirculation flue gas (RFG) from 1) an electrostatic precipitator outlet or 2) a wet scrubber outlet. The experimental results showed that oxycombustion with RFG generated a flue gas with less volume and containing HAPs at higher levels, while the actual emissions of HAPs per unit of energy produced were much less than that of air-blown combustion. NO(x) reduction was achieved in oxycombustion because of the elimination of nitrogen and the destruction of NO in the RFG. The elevated SO(2)/SO(3) in flue gas improved sulfur self-retention. SO(3) vapor could reach its dew point in the flue gas with high moisture, which limits the amount of SO(3) vapor in flue gas and possibly induces material corrosion. Most nonvolatile trace elements were less enriched in fly ash in oxycombustion than air-firing because of lower oxycombustion temperatures occurring in the present study. Meanwhile, Hg and Se were found to be enriched on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion.

  8. Fate of hazardous air pollutants in oxygen-fired coal combustion with different flue gas recycling.

    PubMed

    Zhuang, Ye; Pavlish, John H

    2012-04-17

    Experiments were performed to characterize transformation and speciation of hazardous air pollutants (HAPs), including SO(2)/SO(3), NO(x), HCl, particulate matter, mercury, and other trace elements in oxygen-firing bituminous coal with recirculation flue gas (RFG) from 1) an electrostatic precipitator outlet or 2) a wet scrubber outlet. The experimental results showed that oxycombustion with RFG generated a flue gas with less volume and containing HAPs at higher levels, while the actual emissions of HAPs per unit of energy produced were much less than that of air-blown combustion. NO(x) reduction was achieved in oxycombustion because of the elimination of nitrogen and the destruction of NO in the RFG. The elevated SO(2)/SO(3) in flue gas improved sulfur self-retention. SO(3) vapor could reach its dew point in the flue gas with high moisture, which limits the amount of SO(3) vapor in flue gas and possibly induces material corrosion. Most nonvolatile trace elements were less enriched in fly ash in oxycombustion than air-firing because of lower oxycombustion temperatures occurring in the present study. Meanwhile, Hg and Se were found to be enriched on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion. PMID:22439940

  9. Near-surface physics during convection affecting air-water gas transfer

    NASA Astrophysics Data System (ADS)

    Fredriksson, S. T.; Arneborg, L.; Nilsson, H.; Handler, R. A.

    2016-05-01

    The gas flux at the water surface is affected by physical processes including turbulence from wind shear, microscale wave breaking, large-scale breaking, and convection due to heat loss at the surface. The main route in the parameterizations of the gas flux has been to use the wind speed as a proxy for the gas flux velocity, indirectly taking into account the dependency of the wind shear and the wave processes. The interest in the contributions from convection processes has increased as the gas flux from inland waters (with typically lower wind and sheltered conditions) now is believed to play a substantial role in the air-water gas flux budget. The gas flux is enhanced by convection through the mixing of the mixed layer as well as by decreasing the diffusive boundary layer thickness. The direct numerical simulations performed in this study are shown to be a valuable tool to enhance the understanding of this flow configuration often present in nature.

  10. Air-Sea Methane Flux after the Deepwater Horizon Oil Leak

    NASA Astrophysics Data System (ADS)

    McAdoo, J.; Sweeney, C.; Kiene, R. P.; McGillis, W. R.

    2012-12-01

    One of the key questions associated with the Deepwater Horizon's (DWH) oil leak involves understanding how much of its methane is still entrained in deep waters. Analysis of air-sea fluxes reveals a slight decrease in average aqueous CH4 from 3.3 nM in June to 3.1 and 2.8 nM in August and September, respectively. The flux estimate showed higher methane flux to the atmosphere after the blowout was capped (3.8 μmol m-2 d-1 in August) compared to 0.024 μmol m-2 d-1 during the leak. Almost all observations were within the range of historical levels. The exception was one large peak to the southwest of the wellhead, but its contribution to atmospheric methane is found to be insignificant compared to the total amount of methane released by the leak. This result supports findings that DWH methane remained entrained in the deep waters and consequently is available for biological degradation and threatens to deplete oxygen, adding further stress to an area that already suffers from anoxic-induced dead zones.

  11. Distinctive precursory air-sea signals between regular and super El Niños

    NASA Astrophysics Data System (ADS)

    Chen, Lin; Li, Tim; Behera, Swadhin K.; Doi, Takeshi

    2016-08-01

    Statistically different precursory air-sea signals between a super and a regular El Niño group are investigated, using observed SST and rainfall data, and oceanic and atmospheric reanalysis data. The El Niño events during 1958-2008 are first separated into two groups: a super El Niño group (S-group) and a regular El Niño group (R-group). Composite analysis shows that a significantly larger SST anomaly (SSTA) tendency appears in S-group than in R-group during the onset phase [April-May(0)], when the positive SSTA is very small. A mixed-layer heat budget analysis indicates that the tendency difference arises primarily from the difference in zonal advective feedback and the associated zonal current anomaly ( u'). This is attributed to the difference in the thermocline depth anomaly ( D') over the off-equatorial western Pacific prior to the onset phase, as revealed by three ocean assimilation products. Such a difference in D' is caused by the difference in the wind stress curl anomaly in situ, which is mainly regulated by the anomalous SST and precipitation over the Maritime Continent and equatorial Pacific.

  12. A Unified Air-Sea Visualization System: Survey on Gridding Structures

    NASA Technical Reports Server (NTRS)

    Anand, Harsh; Moorhead, Robert

    1995-01-01

    The goal is to develop a Unified Air-Sea Visualization System (UASVS) to enable the rapid fusion of observational, archival, and model data for verification and analysis. To design and develop UASVS, modelers were polled to determine the gridding structures and visualization systems used, and their needs with respect to visual analysis. A basic UASVS requirement is to allow a modeler to explore multiple data sets within a single environment, or to interpolate multiple datasets onto one unified grid. From this survey, the UASVS should be able to visualize 3D scalar/vector fields; render isosurfaces; visualize arbitrary slices of the 3D data; visualize data defined on spectral element grids with the minimum number of interpolation stages; render contours; produce 3D vector plots and streamlines; provide unified visualization of satellite images, observations and model output overlays; display the visualization on a projection of the users choice; implement functions so the user can derive diagnostic values; animate the data to see the time-evolution; animate ocean and atmosphere at different rates; store the record of cursor movement, smooth the path, and animate a window around the moving path; repeatedly start and stop the visual time-stepping; generate VHS tape animations; work on a variety of workstations; and allow visualization across clusters of workstations and scalable high performance computer systems.

  13. Design and manufacturing considerations for high-performance gimbals used for land, sea, air, and space

    NASA Astrophysics Data System (ADS)

    Sweeney, Mike; Redd, Lafe; Vettese, Tom; Myatt, Ray; Uchida, David; Sellers, Del

    2015-09-01

    High performance stabilized EO/IR surveillance and targeting systems are in demand for a wide variety of military, law enforcement, and commercial assets for land, sea, air, and space. Operating ranges, wavelengths, and angular resolution capabilities define the requirements for EO/IR optics and sensors, and line of sight stabilization. Many materials and design configurations are available for EO/IR pointing gimbals depending on trade-offs of size, weight, power (SWaP), performance, and cost. Space and high performance military aircraft applications are often driven toward expensive but exceptionally performing beryllium and aluminum beryllium components. Commercial applications often rely on aluminum and composite materials. Gimbal design considerations include achieving minimized mass and inertia simultaneous with demanding structural, thermal, optical, and scene stabilization requirements when operating in dynamic operational environments. Manufacturing considerations include precision lapping and honing of ball bearing interfaces, brazing, welding, and casting of complex aluminum and beryllium alloy structures, and molding of composite structures. Several notional and previously developed EO/IR gimbal platforms are profiled that exemplify applicable design and manufacturing technologies.

  14. Descriptive Epidemiology of Musculoskeletal Injuries in Naval Special Warfare Sea, Air, and Land Operators.

    PubMed

    Lovalekar, Mita; Abt, John P; Sell, Timothy C; Wood, Dallas E; Lephart, Scott M

    2016-01-01

    The purpose of this analysis was to describe medical chart reviewed musculoskeletal injuries among Naval Special Warfare Sea, Air, and Land Operators. 210 Operators volunteered (age: 28.1 ± 6.0 years, height: 1.8 ± 0.1 m, weight: 85.4 ± 9.3 kg). Musculoskeletal injury data were extracted from subjects' medical charts, and injuries that occurred during 1 year were described. Anatomic location of injury, cause of injury, activity when injury occurred, and injury type were described. The frequency of injuries was 0.025 per Operator per month. Most injuries involved the upper extremity (38.1% of injuries). Frequent anatomic sublocations for injuries were the shoulder (23.8%) and lumbopelvic region of the spine (12.7%). Lifting was the cause of 7.9% of injuries. Subjects were participating in training when 38.1% of injuries occurred and recreational activity/sports when 12.7% of injuries occurred. Frequent injury types were strain (20.6%), pain/spasm/ache (19.0%), fracture (11.1%), and sprain (11.1%). The results of this analysis underscore the need to investigate the risk factors, especially of upper extremity and physical activity related injuries, in this population of Operators. There is a scope for development of a focused, customized injury prevention program, targeting the unique injury profile of this population. PMID:26741478

  15. Active seafloor gas vents on the Shelf and upper Slope in Canadian Beaufort Sea

    NASA Astrophysics Data System (ADS)

    Paull, C. K.; Dallimore, S. R.; Hughes Clarke, J. E.; Blasco, S.; Taylor, A. E.; Melling, H.; Vagle, S.; Conway, K.; Riedel, M.; Lundsten, E.; Gwiazda, R.

    2012-12-01

    In the Canadian Arctic shelf and upper slope, a thermal disturbance caused by sea level rise at the end of the last glacial period, is still propagating into the subsurface and heating shelf sediments, where submerged terrestrial permafrost and gas hydrate, and marine gas hydrate are believed to occur in close proximity. On-going studies show evidence of gas venting in association with three distinct environments: Pingo-Like-Features (PLF) on the mid-shelf; along the shelf edge near the 100m contour; and ~1 km wide circular topographic features on the upper continental slope. Observations with a Remotely Operated Vehicle (ROV) show that methane is venting vigorously over point sources on the PLF's on the mid-shelf, and diffusely along the shelf edge. The stable isotopic composition of methane emanating from these environments indicates a microbial origin for the venting gas. Their negligible radiocarbon content indicates a geological source, as opposed to methangenisis associated with modern sediments. This is consistent with the change in the thermal regime produced by the last transgression. During glacial periods lower sea level exposed the current shelf to frigid sub-aerial temperatures. As a result, some areas of the shelf are underlain by >600m of ice-bonded permafrost with the base of methane hydrate stability at >1000m depths. The marine transgression imposed a change in mean annual surface temperature from -15°C or lower, to mean annual sea bottom temperatures near 0°C. The thermal disturbance is still propagating into the subsurface, stimulating the decomposition of both terrestrial permafrost and gas hydrate at depth and liberating methane. The PLF vents are believed to be sourced from the top of the gas hydrate stability field, while the gas emanating along the shelf edge can be from the decomposition of gas trapped in the permafrost or gas-hydrate underneath the continental shelf. The occurrence of water column flares over the distinctive circular

  16. Origin of pingo-like features on the Beaufort Sea shelf and their possible relationship to decomposing methane gas hydrates

    USGS Publications Warehouse

    Paull, C.K.; Ussler, W.; Dallimore, S.R.; Blasco, S.M.; Lorenson, T.D.; Melling, H.; Medioli, B.E.; Nixon, F.M.; McLaughlin, F.A.

    2007-01-01

    The Arctic shelf is currently undergoing dramatic thermal changes caused by the continued warming associated with Holocene sea level rise. During this transgression, comparatively warm waters have flooded over cold permafrost areas of the Arctic Shelf. A thermal pulse of more than 10??C is still propagating down into the submerged sediment and may be decomposing gas hydrate as well as permafrost. A search for gas venting on the Arctic seafloor focused on pingo-like-features (PLFs) on the Beaufort Sea Shelf because they may be a direct consequence of gas hydrate decomposition at depth. Vibracores collected from eight PLFs had systematically elevated methane concentrations. ROV observations revealed streams of methane-rich gas bubbles coming from the crests of PLFs. We offer a scenario of how PLFs may be growing offshore as a result of gas pressure associated with gas hydrate decomposition. Copyright 2007 by the American Geophysical Union.

  17. Internally coated air-cooled gas turbine blading

    NASA Technical Reports Server (NTRS)

    Hsu, L.; Stevens, W. G.; Stetson, A. R.

    1979-01-01

    Ten candidate modified nickel-aluminide coatings were developed using the slip pack process. These coatings contain additives such as silicon, chromium and columbium in a nickel-aluminum coating matrix with directionally solidified MAR-M200 + Hf as the substrate alloy. Following a series of screening tests which included strain tolerance, dynamic oxidation and hot corrosion testing, the Ni-19A1-1Cb (nominal composition) coating was selected for application to the internal passages of four first-stage turbine blades. Process development results indicate that a dry pack process is suitable for internal coating application resulting in 18 percent or less reduction in air flow. Coating uniformity, based on coated air-cooled blades, was within + or - 20 percent. Test results show that the presence of additives (silicon, chromium or columbium) appeared to improve significantly the ductility of the NiA1 matrix. However, the environmental resistance of these modified nickel-aluminides were generally inferior to the simple aluminides.

  18. Gas-fired boiler and turbine air toxics summary report. Final report, January-September 1995

    SciTech Connect

    Rossi-Lane, C.; Stein, D.; Himes, R.

    1996-08-01

    The objective of the report is to provide a summary of the criteria pollutants and hazardous air pollutants (HAPs) emitted from a variety of gas-fired stationary sources including utility boilers, utility turbines, and turbines used for natural gas transmission. The report provides emission factors for each compound measured as a function of load to support general use during the preparation of Title V permit applications.

  19. A SOLAS challenge: How can we test test feedback loops involving air-sea exchange?

    NASA Astrophysics Data System (ADS)

    Huebert, B. J.

    2004-12-01

    It is now well accepted that the Earth System links biological and physical processes in the water, on land, and in the air, creating countless feedback loops and dependencies that are at best difficult to quantify. One example of interest to SOLAS scientists is the suspension and long-range transport of dust from Asia, which may or may not interact with acidic air pollutants, that may increase the biological availability of iron, thereby increasing primary productivity in parts of the Pacific. This could increase DMS emissions and modify the radiative impact of Pacific clouds, affecting the climate and the hydrological system that limits the amount of dust lofted each year. Air-sea exchange is central to many such feedbacks: Variations in productivity in upwelling waters off Peru probably change DMS emissions and modify the stratocumulus clouds that blanket that region, thereby feeding back to productivity. The disparate time and space scales of the controlling processes make it difficult to observationally constrain such systems without the use of multi-year time-series and intensive multiplatform process studies. Unfortunately, much of the infrastructure for funding Earth science is poorly suited for supporting multidisciplinary research. For example, NSF's program managers are organized into disciplines and sub-disciplines, and rely on disciplinary reviewer communities that are protective of their slices of the funding pie. It is easy to find authors of strong, innovative, cross-disciplinary (yet unsuccessful) proposals who say they'll never try it again, because there is so little institutional support for interfacial research. Facility issues also complicate multidisciplinary projects, since there are usually several allocating groups that don't want to commit their ships, airplanes, or towers until the other groups have done so. The result is that there are very few examples of major interdisciplinary projects, even though IGBP core programs have articulated

  20. Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

    NASA Technical Reports Server (NTRS)

    Signorini, Sergio; Mannino, Antonio; Najjar, Raymond G., Jr.; Friedrichs, Marjorie A. M.; Cai, Wei-Jun; Salisbury, Joe; Wang, Zhaohui Aleck; Thomas, Helmuth; Shadwick, Elizabeth

    2013-01-01

    Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.

  1. Response of electrochemical oxygen sensors to inert gas-air and carbon dioxide-air mixtures: measurements and mathematical modelling.

    PubMed

    Walsh, P T; Gant, S E; Dowker, K P; Batt, R

    2011-02-15

    Electrochemical oxygen gas sensors are widely used for monitoring the state of inertisation of flammable atmospheres and to warn of asphyxiation risks. It is well established but not widely known by users of such oxygen sensors that the response of the sensor is affected by the nature of the diluent gas responsible for the decrease in ambient oxygen concentration. The present work investigates the response of electrochemical sensors, with either acid or alkaline electrolytes, to gas mixtures comprising air with enhanced levels of nitrogen, carbon dioxide, argon or helium. The measurements indicate that both types of sensors over-read the oxygen concentrations when atmospheres contain high levels of helium. Sensors with alkaline electrolytes are also shown to underestimate the severity of the hazard in atmospheres containing high levels of carbon dioxide. This deviation is greater for alkaline electrolyte sensors compared to acid electrolyte sensors. A Computational Fluid Dynamics (CFD) model is developed to predict the response of an alkaline electrolyte, electrochemical gas sensor. Differences between predicted and measured sensor responses are less than 10% in relative terms for nearly all of the gas mixtures tested, and in many cases less than 5%. Extending the model to simulate responses of sensors with acid electrolytes would be straightforward.

  2. Flame holding tolerant fuel and air premixer for a gas turbine combustor

    DOEpatents

    York, William David; Johnson, Thomas Edward; Ziminsky, Willy Steve

    2012-11-20

    A fuel nozzle with active cooling is provided. It includes an outer peripheral wall, a nozzle center body concentrically disposed within the outer wall in a fuel and air pre-mixture. The fuel and air pre-mixture includes an air inlet, a fuel inlet and a premixing passage defined between the outer wall in the center body. A gas fuel flow passage is provided. A first cooling passage is included within the center body in a second cooling passage is defined between the center body and the outer wall.

  3. Distinct synoptic patterns and air masses responsible for long-range desert dust transport and sea spray in Palermo, Italy

    NASA Astrophysics Data System (ADS)

    Dimitriou, K.; Paschalidou, A. K.; Kassomenos, P. A.

    2016-09-01

    Undoubtedly, anthropogenic emissions carry a large share of the risk posed on public health by particles exposure in urban areas. However, natural emissions, in the form of desert dust and sea spray, are well known to contribute significantly to the PM load recorded in many Mediterranean environments, posing an extra risk burden on public health. In the present paper, we examine the synoptic climatology in a background station in Palermo, Italy, through K-means clustering of the mean sea-level pressure (MSLP) maps, in an attempt to associate distinct synoptic patterns with increased PM10 levels. Four-day backward trajectory analysis is then applied, in order to study the origins and pathways of air masses susceptible of PM10 episodes. It is concluded that a number of atmospheric patterns result in several kind of flows, namely south, west, and slow-moving/stagnant flows, associated with long-range dust transport and sea spray.

  4. Submarine slope failures in the Beaufort Sea; Influence of gas hydrate decomposition

    NASA Astrophysics Data System (ADS)

    Grozic, J. L.; Dallimore, S.

    2012-12-01

    The continental shelf of the Beaufort Sea is composed of complex of marine and non-marine sequences of clay, silt, and sand. In many areas of the shelf these sediments contain occurrences of ice-bonded permafrost and associated pressure and temperature conditions that are conducive to the occurrence of methane gas hydrates. This complex environment is undergoing dramatic warming, where changes in sea level, ocean bottom temperatures, and geothermal regimes are inducing permafrost thawing and gas hydrate decomposition. Decomposition is inferred to be occurring at the base and top of the gas hydrate stability zone, which will cause sediment weakening and the generation of excess water and free gas. In such settings, the overlying permafrost cap may act as a permeability barrier, which could result in significant excess pore pressures and reduction in sediment stability. The shelf to slope transition is thought to be an area of extensive regional instability with acoustic records indicating there is upwards of 500 km of slumps and glides extending over the entire Beaufort margin. Some of these slide regions are coincident with up-dip limit of the permafrost gas hydrate stability zone. In this paper, a two dimensional model of the Beaufort shelf was constructed to examine the influence of gas hydrate decomposition on slope stability. The model relies on available data on the Beaufort sediments generated from offshore hydrocarbon exploration in the 1980s and 90s, as well as knowledge available from multidisciplinary marine research programs conducted in the outer shelf area. The slope stability model investigates the influence of marine transgression and ocean bottom warming by coupling soil deformation with hydrate dissociation during undrained conditions. By combining mechanical and thermal loading of the sediment, a more accurate indication of slope stability was obtained. The stability analysis results indicate a relatively low factor of safety for the Beaufort

  5. Laboratory modeling of air-sea interaction under severe wind conditions

    NASA Astrophysics Data System (ADS)

    Troitskaya, Yuliya; Vasiliy, Kazakov; Nicolay, Bogatov; Olga, Ermakova; Mikhail, Salin; Daniil, Sergeev; Maxim, Vdovin

    2010-05-01

    Wind-wave interaction at extreme wind speed is of special interest now in connection with the problem of explanation of the sea surface drag saturation at the wind speed exceeding 30 m/s. The idea on saturation (and even reduction) of the coefficient of aerodynamic resistance of the sea surface at hurricane wind speed was first suggested by Emanuel (1995) on the basis of theoretical analysis of sensitivity of maximum wind speed in a hurricane to the ratio of the enthalpy and momentum exchange coefficients. Both field (Powell, Vickery, Reinhold, 2003, French et al, 2007, Black, et al, 2007) and laboratory (Donelan et al, 2004) experiments confirmed that at hurricane wind speed the sea surface drag coefficient is significantly reduced in comparison with the parameterization obtained at moderate to strong wind conditions. Two groups of possible theoretical mechanisms for explanation of the effect of the sea surface drag reduction can be specified. In the first group of models developed by Kudryavtsev & Makin (2007) and Kukulka,Hara Belcher (2007), the sea surface drag reduction is explained by peculiarities of the air flow over breaking waves. Another approach more appropriate for the conditions of developed sea exploits the effect of sea drops and sprays on the wind-wave momentum exchange (Andreas, 2004; Makin, 2005; Kudryavtsev, 2006). The main objective of this work is investigation of factors determining momentum exchange under high wind speeds basing on the laboratory experiment in a well controlled environment. The experiments were carried out in the Thermo-Stratified WInd-WAve Tank (TSWIWAT) of the Institute of Applied Physics. The parameters of the facility are as follows: airflow 0 - 25 m/s (equivalent 10-m neutral wind speed U10 up to 60 m/s), dimensions 10m x 0.4m x 0.7 m, temperature stratification of the water layer. Simultaneous measurements of the airflow velocity profiles and wind waves were carried out in the wide range of wind velocities. Airflow

  6. Violent Gas Venting on the Heng-Chun Mud Volcano, South China Sea Active Continental Margin offshore SW Taiwan

    NASA Astrophysics Data System (ADS)

    Lin, S.; Cheng, W. Y.; Tseng, Y. T.; Chen, N. C.; Hsieh, I. C.; Yang, T. F.

    2014-12-01

    Accumulation of methane as gas hydrate under the sea floor has been considered a major trap for both thermal and biogenic gas in marine environment. Aided by rapid AOM process near the sea floor, fraction of methane escaping the sea floor has been considered at minuscule. However, most studies focused mainly on deepwater gas hydrate systems where gas hydrate remain relatively stable. We have studied methane seeps on the active margin offshore Taiwan, where rapid tectonic activities occur. Our intention is to evaluate the scale and condition of gas seeps in the tectonic active region. Towcam, coring, heat probe, chirp, multibeam bathymetric mapping and echo sounding were conducted at the study areas. Our results showed that gas is violently venting at the active margin, not only through sediments, but also through overlying sea water, directly into the atmosphere. Similar ventings, but, not in this scale, have also been identified previously in the nearby region. High concentrations of methane as well as traces of propane were found in sediments and in waters with flares. In conjunction, abundant chemosynthetic community, life mussel, clams, tube worms, bacterial mats together with high concentrations of dissolve sulfide, large authigenic carbonate buildups were also found. Our results indicate that methane could be another major green house gas in the shallow water active margin region.

  7. Impact of increasing inflow of warm Atlantic water on the sea-air exchange of carbon dioxide and methane in the Laptev Sea

    NASA Astrophysics Data System (ADS)

    Wâhlström, Iréne; Dieterich, Christian; Pemberton, Per; Meier, H. E. Markus

    2016-07-01

    The Laptev Sea is generally a sink for atmospheric carbon dioxide and a source of methane to the atmosphere. We investigate how sensitive the net sea-air exchange of carbon dioxide and methane in the Laptev Sea are to observed changes in the inflow of Atlantic water into the Arctic Ocean and in atmospheric conditions occurring after 1990. Using a time-dependent coupled physical-biogeochemical column model, both the physical and biogeochemical effects are investigated in a series of sensitivity experiments. The forcing functions are kept constant at 40 year climatological values except successively selected drivers that vary in time. Their effects are examined by comparing two periods, 1971-1989 and 1991-2009. We find that the flux of carbon dioxide is more sensitive to the increased Atlantic water inflow than the methane exchange. The increased volume transport of water in the Atlantic layer increases the ocean net uptake of carbon dioxide more than the warming of the incoming bottom water as the vertical advection is enhanced in the first case. The methane cycling is mainly affected by the increase in temperature, irrespective of whether the warming originates from the atmosphere or the incoming bottom water, causing increased outgassing to the atmosphere. In summary, our results suggest that the observed changes in the atmosphere and ocean potentially had a substantial impact on carbon dioxide uptake on the Siberian Shelf. However, the results suggest that the impact on the outgassing of methane might have been relatively modest compared to the interannual variability of sea-air fluxes of methane.

  8. Ambient air cooling arrangement having a pre-swirler for gas turbine engine blade cooling

    DOEpatents

    Lee, Ching-Pang; Tham, Kok-Mun; Schroeder, Eric; Meeroff, Jamie; Miller, Jr., Samuel R; Marra, John J

    2015-01-06

    A gas turbine engine including: an ambient-air cooling circuit (10) having a cooling channel (26) disposed in a turbine blade (22) and in fluid communication with a source (12) of ambient air: and an pre-swirler (18), the pre-swirler having: an inner shroud (38); an outer shroud (56); and a plurality of guide vanes (42), each spanning from the inner shroud to the outer shroud. Circumferentially adjacent guide vanes (46, 48) define respective nozzles (44) there between. Forces created by a rotation of the turbine blade motivate ambient air through the cooling circuit. The pre-swirler is configured to impart swirl to ambient air drawn through the nozzles and to direct the swirled ambient air toward a base of the turbine blade. The end walls (50, 54) of the pre-swirler may be contoured.

  9. Tropospheric gas at potentially toxic levels in air

    NASA Astrophysics Data System (ADS)

    Bhattacharya, Atreyee

    2012-08-01

    Forest fires and emission of air pollutants, such as fumes from vehicles running on diesel and slow burning of coal and charcoal, release isocyanic acid in the troposphere. In 2011, scientists first detected isocyanic acid in the ambient atmosphere at levels toxic to human populations; at concentrations exceeding 1 part per billion by volume (ppbv), human beings could experience tissue decay when exposed to the toxin. For the first time, using a chemical transport model designed to estimate the distribution and budget of isocyanic acid in the troposphere, Young et al. showed that in several parts of the world, local emissions may increase the concentration of isocyanic acid in the ambient atmosphere, thereby exposing large populations to potentially toxic levels of the acid.

  10. Ozone Air Quality Impacts of Shale Gas Development in South Texas Urban Areas

    NASA Astrophysics Data System (ADS)

    Chang, C.; Liao, K.

    2013-12-01

    Recent technological advances, mainly horizontal drilling and hydraulic fracturing, and continued drilling in shale, have increased domestic production of oil and gas in the United State (U.S.). However, shale gas developments could also affect the environment and human health, particularly in areas where oil and gas developments are new activities. This study is focused on the impacts of shale gas developing activities on summertime ozone air quality in South Texas urban areas since many of them are already ozone nonattainment areas. We use an integrated approach to investigate the ozone air quality impact of the shale gas development in South Texas urban areas. They are: (1) satellite measurement of precursors, (2) observations of ground-level ozone concentrations, and (3) air mass trajectory modeling. Nitrogen dioxide (NO2) is an important precursor to ozone formation, and summertime average tropospheric nitrogen dioxide (NO2) column densities measured by the National Aeronautics and Space Administration's Ozone Monitoring Instrument increased in the South Texas shale area (i.e., the Eagle Ford Shale area) in 2011 and 2012 as compared to 2008-2010. The U.S. Environmental Protection Agency's ground-level observations showed summertime average and peak ozone (i.e., the 4th highest daily maximum 8-hour average ozone) concentrations slightly increased from 2010 to 2012 in Austin and San Antonio. However, the frequencies of peak ozone concentrations above the 75ppb ozone standard have been significantly increasing since 2011 in Austin and San Antonio. It is expected to increase the possibilities of violating the ozone National Ambient Air Quality Standard (NAAQS) for South Texas urban areas in the future. The results of trajectory modeling showed air masses transported from the southeastern Texas could reach Austin and San Antonio and confirmed that emissions from the Eagle Ford Shale area could affect ozone air quality in South Texas urban areas in 2011 and 2012

  11. Pingos, craters and methane-leaking seafloor in the central Barents Sea: signals of decomposing gas hydrate releasing gas from deeper hydrocarbon reservoirs?

    NASA Astrophysics Data System (ADS)

    Andreassen, K.; Plaza-Faverola, A. A.; Winsborrow, M.; Deryabin, A.; Mattingsdal, R.; Vadakkepuliyambatta, S.; Serov, P.; Mienert, J.; Bünz, S.

    2015-12-01

    A cluster of large craters and mounds appear on the gas-leaking sea floor in the central Barents Sea around the upper limit for methane hydrate stability, covering over 360 km2. We use multibeam bathymetry, single-beam echo sounder and high-resolution seismic data to reveal the detailed geomorphology and internal structure of craters and mounds, map the distribution gas in the water and to unravel the subsurface plumbing system and sources of gas leakage. Distinct morphologies and geophysical signatures of mounds and craters are inferred to reflect different development stages of shallow gas hydrate formation and dissociation. Over 600 gas flares extending from the sea floor into the water are mapped, many of these from the seafloor mounds and craters, but most from their flanks and surroundings. Analysis of geophysical data link gas flares in the water, craters and mounds to seismic indications of gas advection from deeper hydrocarbon reservoirs along faults and fractures. We present a conceptual model for formation of mounds, craters and gas leakage of the area.

  12. CLOUDS, AEROSOLS, RADIATION AND THE AIR-SEA INTERFACE OF THE SOUTHERN OCEAN: ESTABLISHING DIRECTIONS FOR FUTURE RESEARCH

    SciTech Connect

    Wood, Robert; Bretherton, Chris; McFarquhar, Greg; Protat, Alain; Quinn, Patricia; Siems, Steven; Jakob, Christian; Alexander, Simon; Weller, Bob

    2014-09-29

    A workshop sponsored by the Department of Energy was convened at the University of Washington to discuss the state of knowledge of clouds, aerosols and air-sea interaction over the Southern Ocean and to identify strategies for reducing uncertainties in their representation in global and regional models. The Southern Ocean plays a critical role in the global climate system and is a unique pristine environment, yet other than from satellite, there have been sparse observations of clouds, aerosols, radiation and the air-sea interface in this region. Consequently, much is unknown about atmospheric and oceanographic processes and their linkage in this region. Approximately 60 scientists, including graduate students, postdoctoral fellows and senior researchers working in atmospheric and oceanic sciences at U.S. and foreign universities and government laboratories, attended the Southern Ocean Workshop. It began with a day of scientific talks, partly in plenary and partly in two parallel sessions, discussing the current state of the science for clouds, aerosols and air-sea interaction in the Southern Ocean. After the talks, attendees broke into two working groups; one focused on clouds and meteorology, and one focused on aerosols and their interactions with clouds. This was followed by more plenary discussion to synthesize the two working group discussions and to consider possible plans for organized activities to study clouds, aerosols and the air-sea interface in the Southern Ocean. The agenda and talk slides, including short summaries of the highlights of the parallel session talks developed by the session chars, are available at http://www.atmos.washington.edu/socrates/presentations/SouthernOceanPresentations/.

  13. Interannual variability of the Indian summer monsoon associated with the air-sea feedback in the northern Indian Ocean

    NASA Astrophysics Data System (ADS)

    Shukla, Ravi P.; Huang, Bohua

    2016-03-01

    Using observation-based analyses, this study identifies the leading interannual pattern of the Indian summer monsoon rainfall (ISMR) independent of ENSO and examines the potential mechanisms of its formation. For this purpose, an objective procedure is used to isolate the variability of the summer precipitation associated with the contemporary ENSO state and in previous winter-spring, which influence the Indian summer monsoon (ISM) region in opposite ways. It is shown that the leading pattern of these ENSO-related monsoon rainfall anomalies reproduces some major ISMR features and well represents its connections to the global-scale ENSO features in both lower and upper troposphere. On the other hand, the leading pattern derived from the precipitation anomalies with the ENSO component removed in the ISM and surrounding region also accounts for a substantial amount of the monsoon precipitation centered at the eastern coast of the subtropical Arabian Sea, extending into both the western Indian Ocean and the Indian subcontinent. The associated atmospheric circulation change is regional in nature, mostly confined in the lower to mid troposphere centered in the Arabian Sea, with a mild connection to an opposite tendency centered at the South China Sea. Further analyses show that this regional pattern is associated with a thermodynamic air-sea feedback during early to mid summer season. Specifically, before the monsoon onset, an anomalous atmospheric high pressure over the Arabian Sea causes excessive shortwave radiation to the sea surface and increases SST in May. The warm SST anomalies peak in June and reduce the sea level pressure. The anomalous cyclonic circulation generates regional convection and precipitation, which also induces subsidence and anticyclonic circulation over the South China Sea. The combined cyclonic-anticyclonic circulation further transport moisture from the western Pacific into the Indian Ocean and causes its convergence into the Arabian Sea. As a

  14. Petrophysical Properties Of Sandy Sediments Possibly Hosting Gas Hydrate In The Eastern Margin Of Japan Sea

    NASA Astrophysics Data System (ADS)

    Uchida, T.; Takashima, I.; Sunaga, H.; Sasaki, S.; Matsumoto, R.

    2011-12-01

    In 2010 the MD179 project was undertaken by the Marion Dufresne aiming at recovery of deep seated gas and gas hydrate, methane induced carbonate, and deep sediments older than 300 ka in order to develop geologic model of gas hydrate accumulation and evaluate the possible environmental impact of gas hydrate for the last glacial-interglacial cycles. Sediment samples below the seafloor were obtained in the Umitaka Spur, Joetsu Channel, Toyama Trough, Japan Basin, Nishi Tsugaru and Okushiri Ridge areas by the MD179 cruise. Small amounts of sandy sediment have been retrieved as thin intercalations in Pleistocene and Holocene silty layers, where trace fossils and strong bioturbations are commonly observed. Those sandy sediments consist of very fine- to fine-grained sand grains, and are sometimes tuffaceous. Pore-size distribution measurements and thin-section observations of these arenite sands were undertaken, which indicatesd that porosities of muddy sediments are around 50 % but those of arenites range from 42 to 52 %, of which mean pore sizes and permeabilities are larger than those of siltstones and mudstones. These coarser sediments might have been transported approximately around 3 to 30 ka, where supplying sediments may not be abundant due to sea level fluctuation during the Pleistocene ice age. While the presence of gas hydrate in intergranular pores of arenite sands has not been confirmed, the soupy occurrence in recovered sediments may strongly indicate the presence of gas hydrate filling the intergranular pore system of arenite sands that is called pore-space hydrates. They have been recognized till now in the Mallik as well as in the Nankai Trough areas, which are considered to be very common even in the subsurface sandy sediments at the eastern margin of Japan Sea. Concentration of gas hydrate may need primary intergranular pores large enough to occur within a host sediment that may be arenite sand without matrix grains deposited in the sedimentary

  15. Wintertime Air Quality Impacts from Oil and Natural Gas Drilling Operations in the Bakken Formation Region

    NASA Astrophysics Data System (ADS)

    Evanoski-Cole, Ashley; Sive, Barkley; Zhou, Yong; Prenni, Anthony; Schurman, Misha; Day, Derek; Sullivan, Amy; Li, Yi; Hand, Jenny; Gebhart, Kristi; Schichtel, Bret; Collett, Jeffrey

    2016-04-01

    Oil and natural gas extraction has dramatically increased in the last decade in the United States due to the increased use of unconventional drilling techniques which include horizontal drilling and hydraulic fracturing. The impact of these drilling activities on local and regional air quality in oil and gas basins across the country are still relatively unknown, especially in recently developed basins such as the Bakken shale formation. This study is the first to conduct a comprehensive characterization of the regional air quality in the Bakken region. The Bakken shale formation, part of the Williston basin, is located in North Dakota and Montana in the United States and Saskatchewan and Manitoba in Canada. Oil and gas drilling operations can impact air quality in a variety of ways, including the generation of atmospheric particulate matter (PM), hazardous air pollutants, ozone, and greenhouse gas emissions. During the winter especially, PM formation can be enhanced and meteorological conditions can favor increased concentrations of PM and other pollutants. In this study, ground-based measurements throughout the Bakken region in North Dakota and Montana were collected over two consecutive winters to gain regional trends of air quality impacts from the oil and gas drilling activities. Additionally, one field site had a comprehensive suite of instrumentation operating at high time resolution to gain detailed characterization of the atmospheric composition. Measurements included organic carbon and black carbon concentrations in PM, the characterization of inorganic PM, inorganic gases, volatile organic compounds (VOCs), precipitation and meteorology. These elevated PM episodes were further investigated using the local meteorological conditions and regional transport patterns. Episodes of elevated concentrations of nitrogen oxides and sulfur dioxide were also detected. The VOC concentrations were analyzed and specific VOCs that are known oil and gas tracers were used

  16. Sea ice pCO2 dynamics and air-ice CO2 fluxes during the Sea Ice Mass Balance in the Antarctic (SIMBA) experiment - Bellingshausen Sea, Antarctica

    NASA Astrophysics Data System (ADS)

    Geilfus, N.-X.; Tison, J.-L.; Ackley, S. F.; Galley, R. J.; Rysgaard, S.; Miller, L. A.; Delille, B.

    2014-12-01

    Temporal evolution of pCO2 profiles in sea ice in the Bellingshausen Sea, Antarctica, in October 2007 shows physical and thermodynamic processes controls the CO2 system in the ice. During the survey, cyclical warming and cooling strongly influenced the physical, chemical, and thermodynamic properties of the ice cover. Two sampling sites with contrasting characteristics of ice and snow thickness were sampled: one had little snow accumulation (from 8 to 25 cm) and larger temperature and salinity variations than the second site, where the snow cover was up to 38 cm thick and therefore better insulated the underlying sea ice. We show that each cooling/warming event was associated with an increase/decrease in the brine salinity, total alkalinity (TA), total dissolved inorganic carbon (TCO2), and in situ brine and bulk ice CO2 partial pressures (pCO2). Thicker snow covers reduced the amplitude of these changes: snow cover influences the sea ice carbonate system by modulating the temperature and therefore the salinity of the sea ice cover. Results indicate that pCO2 was undersaturated with respect to the atmosphere both in the in situ bulk ice (from 10 to 193 μatm) and brine (from 65 to 293 μatm), causing the sea ice to act as a sink for atmospheric CO2 (up to 2.9 mmol m-2 d-1), despite supersaturation of the underlying seawater (up to 462 μatm).

  17. Model studies of the flux of CO{sub 2} over the air-sea interface in the Baltic Sea

    SciTech Connect

    Ohlson, M.

    1994-12-31

    In the discussion about the green house effect generated by the burning of fossil fuels, carbon dioxide (CO{sub 2}) has a key role. A major part of the surplus CO{sub 2} has been suggested, by the scientific community, to be withdrawn from the atmosphere and to be taken up by the growth in continental shelf areas with high primary production, and in terrestrial forests. The exact quantity and reaction ways and mechanisms of those processes are not known today. The Baltic Sea is, for several reasons, a well chosen area to study this phenomenon. It is a shallow continental Mediterranean sea, in this area almost the first measurements of the carbonate system were carried out in the end of the last century. This has resulted in long time series of measurements of the carbonate system available for use in, e.g. modelling work, a working numerical carbonate model.

  18. Enhanced methane emissions from oil and gas exploration areas to the atmosphere--the central Bohai Sea.

    PubMed

    Zhang, Yong; Zhao, Hua-de; Zhai, Wei-dong; Zang, Kun-peng; Wang, Ju-ying

    2014-04-15

    The distributions of dissolved methane in the central Bohai Sea were investigated in November 2011, May 2012, July 2012, and August 2012. Methane concentration in surface seawater, determined using an underway measurement system combined with wavelength-scanned cavity ring-down spectroscopy, showed marked spatiotemporal variations with saturation ratio from 107% to 1193%. The central Bohai Sea was thus a source of atmospheric methane during the survey periods. Several episodic oil and gas spill events increased surface methane concentration by up to 4.7 times and raised the local methane outgassing rate by up to 14.6 times. This study demonstrated a method to detect seafloor CH4 leakages at the sea surface, which may have applicability in many shallow sea areas with oil and gas exploration activities around the world. PMID:24602676

  19. Enhanced methane emissions from oil and gas exploration areas to the atmosphere--the central Bohai Sea.

    PubMed

    Zhang, Yong; Zhao, Hua-de; Zhai, Wei-dong; Zang, Kun-peng; Wang, Ju-ying

    2014-04-15

    The distributions of dissolved methane in the central Bohai Sea were investigated in November 2011, May 2012, July 2012, and August 2012. Methane concentration in surface seawater, determined using an underway measurement system combined with wavelength-scanned cavity ring-down spectroscopy, showed marked spatiotemporal variations with saturation ratio from 107% to 1193%. The central Bohai Sea was thus a source of atmospheric methane during the survey periods. Several episodic oil and gas spill events increased surface methane concentration by up to 4.7 times and raised the local methane outgassing rate by up to 14.6 times. This study demonstrated a method to detect seafloor CH4 leakages at the sea surface, which may have applicability in many shallow sea areas with oil and gas exploration activities around the world.

  20. Performance and economic enhancement of cogeneration gas turbines through compressor inlet air cooling

    NASA Astrophysics Data System (ADS)

    Delucia, M.; Bronconi, R.; Carnevale, E.

    1994-04-01

    Gas turbine air cooling systems serve to raise performance to peak power levels during the hot months when high atmospheric temperatures cause reductions in net power output. This work describes the technical and economic advantages of providing a compressor inlet air cooling system to increase the gas turbine's power rating and reduce its heat rate. The pros and cons of state-of-the-art cooling technologies, i.e., absorption and compression refrigeration, with and without thermal energy storage, were examined in order to select the most suitable cooling solution. Heavy-duty gas turbine cogeneration systems with and without absorption units were modeled, as well as various industrial sectors, i.e., paper and pulp, pharmaceuticals, food processing, textiles, tanning, and building materials. The ambient temperature variations were modeled so the effects of climate could be accounted for in the simulation. The results validated the advantages of gas turbine cogeneration with absorption air cooling as compared to other systems without air cooling.

  1. Approximation of flammability region for natural gas-air-diluent mixture.

    PubMed

    Liao, S Y; Jiang, D M; Huang, Z H; Cheng, Q; Gao, J; Hu, Y

    2005-10-17

    The growing implementation of exhaust gas recirculation (EGR) in reducing NO(x) emissions of engine is of paramount motivation to perform a fundamental research on the flammability characteristics of fuel-air-diluent mixtures. In this work, the influences of EGR on the flammability region of natural gas-air-diluent flames were experimentally studied in a constant volume bomb. An assumption of critical burning velocity at flammability limit is proposed to approximately determine the flammability region of these mixtures. Based on this assumption, an estimation of the flammability map for natural gas-air-diluent mixtures was obtained by using the empirical formula of burning velocity data. The flammability regions of natural gas-air mixtures with EGR are plotted versus the EGR rate. From the comparison of estimated results and experimental measurements, it is suggested that the accuracy of prediction is largely dependent upon the formula of burning velocity used. Meanwhile, the influence of pressure on the critical burning velocity at flammability limit is also investigated. On the basis of the pressure dependence criterion, the estimation was performed for the circumstance of high temperature and pressure, and the prediction results still agree well with those of experiments.

  2. Evaluation of Length-of-Stain Gas Indicator Tubes for Measuring Carbon Monoxide in Air.

    ERIC Educational Resources Information Center

    Klaubert, Earl C.; And Others

    Techniques for detection and measurement of carbon monoxide (CO) in air are of interest and utility in many aspects of automotive safety. CO concentrations may range from less than 100 parts per million (ppm), or 0.01 percent, to about 10 percent by volume. Gas indicator tubes have been used for many years primarily as detectors of hazardous gases…

  3. Air Pollutant Emissions from Oil and Gas Production pads (Investigating Low Cost Passive Samplers)

    EPA Science Inventory

    To help achieve the goal of sustainable, environmentally responsible development of oil and gas resources, it isnecessary to understand the potential for air pollutant emissions from various extraction and production (E&P)processes at the upstream, wellpad level. Upstream oil and...

  4. The Measurement of Fuel-Air Ratio by Analysis for the Oxidized Exhaust Gas

    NASA Technical Reports Server (NTRS)

    Gerrish, Harold C.; Meem, J. Lawrence, Jr.

    1943-01-01

    An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy fuel Specification No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs for the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124.

  5. The Measurement of Fuel-air Ratio by Analysis of the Oxidized Exhaust Gas

    NASA Technical Reports Server (NTRS)

    Memm, J. Lawrence, Jr.

    1943-01-01

    An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy Fuel Specification, No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs or the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124

  6. Air separation membranes : an alternative to EGR in large bore natural gas engines.

    SciTech Connect

    Biruduganti, M.; Gupta, S.; Bihari, B.; McConnell, S.; Sekar, R.; Energy Systems

    2010-08-01

    Air separation membranes (ASMs) could potentially replace exhaust gas recirculation (EGR) technology in engines due to the proven benefits in NOx reduction but without the drawbacks of EGR. Previous investigations of nitrogen-enriched air (NEA) combustion using nitrogen bottles showed up to 70% NOx reduction with modest 2% nitrogen enrichment. The investigation in this paper was performed with an ASM capable of delivering at least 3.5% NEA to a single-cylinder spark-ignited natural gas engine. Low temperature combustion is one of the pathways to meet the mandatory ultra low NOx emissions levels set by regulatory agencies. In this study, a comparative assessment is made between natural gas combustion in standard air and 2% NEA. Enrichment beyond this level degraded engine performance in terms of power density, brake thermal efficiency (BTE), and unburned hydrocarbon emissions for a given equivalence ratio. The ignition timing was optimized to yield maximum brake torque for standard air and NEA. Subsequently, conventional spark ignition was replaced by laser ignition (LI) to extend lean ignition limit. Both ignition systems were studied under a wide operating range from {Psi} :1.0 to the lean misfire limit. It was observed that with 2% NEA, for a similar fuel quantity, the equivalence ratio {Psi} increases by 0.1 relative to standard air conditions. Analysis showed that lean burn operation along with NEA and alternative ignition source, such as LI, could pave the pathway for realizing lower NO{sub x} emissions with a slight penalty in BTE.

  7. High-resolution simulations of heavy precipitation events: role of the Adriatic SST and air-sea interactions

    NASA Astrophysics Data System (ADS)

    Davolio, Silvio; Stocchi, Paolo

    2016-04-01

    Strong Bora and Sirocco winds over the Adriatic Sea favour intense air-sea interactions and are often associated with heavy rainfall that affects the mountainous areas surrounding the basin. A convection-permitting model (MOLOCH) has been implemented at high resolution (2 km) in order to analyse several precipitation events over northern Italy, occurred during different seasons of the year and presenting different rainfall characteristics (stratiform, convective, orographic), and to possibly identify the relevant physical mechanisms involved. With the aim of assessing the impact of the sea surface temperature (SST) and surface fluxes on the intensity and location of the rainfall, sensitivity experiments have been performed taking into account the possible variability of SST analysis for model initialization. The model has been validated and specific diagnostic tools have been developed and applied to evaluate the vertically integrated moisture fluxes feeding the precipitating system or to compute a water balance in the atmosphere over the sea. The results show that the Adriatic Sea plays a role in determining the boundary layer characteristics through exchange of heat and moisture thus modifying the low-level flow dynamics and its interaction with the orography. This in turn impacts on the rainfall. Although the results vary among the analysed events, the precise definition of the SST and its evolution can be relevant for accurate precipitation forecasting.

  8. Internal coating of air-cooled gas turbine blades

    NASA Technical Reports Server (NTRS)

    Hsu, L. L.; Stetson, A. R.

    1980-01-01

    Four modified aluminide coatings were developed for IN-792 + Hf alloy using a powder pack method applicable to internal surfaces of air-cooled blades. The coating compositions are Ni-19Al-1Cb, Ni-19Al-3Cb, Ni-17Al-20Cr, and Ni-12Al-20Cr. Cyclic burner rig hot corrosion (900 C) and oxidation (1050 C) tests indicated that Ni-Al-Cb coatings provided better overall resistance than Ni-Al-Cr coatings. Tensile properties of Ni-19Al-1Cb and Ni-12Al-20Cr coated test bars were fully retained at room temperature and 649 C. Stress rupture results exhibited wide scatter around uncoated IN-792 baseline, especially at high stress levels. High cycle fatigue lives of Ni-19Al-1Cb and Ni-12Al-20Cr coated bars (as well as RT-22B coated IN-792) suffered approximately 30 percent decrease at 649 C. Since all test bars were fully heat treated after coating, the effects of coating/processing on IN-792 alloy were not recoverable. Internally coated Ni-19Al-1Cb, Ni-19Al-3Cb, and Ni-12Al-20Cr blades were included in 500-hour endurance engine test and the results were similar to those obtained in burner rig oxidation testing.

  9. Density measurement in air with a saturable absorbing seed gas

    NASA Technical Reports Server (NTRS)

    Baganoff, D.

    1981-01-01

    Resonantly enhanced scattering from the iodine molecule is studied experimentally for the purpose of developing a scheme for the measurement of density in a gas dynamic flow. A study of the spectrum of iodine, the collection of saturation data in iodine, and the development of a mathematical model for correlating saturation effects were pursued for a mixture of 0.3 torr iodine in nitrogen and for mixture pressures up to one atmosphere. For the desired pressure range, saturation effects in iodine were found to be too small to be useful in allowing density measurements to be made. The effects of quenching can be reduced by detuning the exciting laser wavelength from the absorption line center of the iodine line used (resonant Raman scattering). The signal was found to be nearly independent of pressure, for pressures up to one atmosphere, when the excitation beam was detuned 6 GHz from line center for an isolated line in iodine. The signal amplitude was found to be nearly equal to the amplitude for fluorescence at atmospheric pressure, which indicates a density measurement scheme is possible.

  10. Dust in the Earth system: the biogeochemical linking of land, air and sea.

    PubMed

    Ridgwell, Andy J

    2002-12-15

    Understanding the response of the Earth's climate system to anthropogenic perturbation has been a pressing priority for society since the late 1980s. However, recent years have seen a major paradigm shift in how such an understanding can be reached. Climate change demands analysis within an integrated 'Earth-system' framework, taken to encompass the suite of interacting physical, chemical, biological and human processes that, in transporting and transforming materials and energy, jointly determine the conditions for life on the whole planet. This is a highly complex system, characterized by multiple nonlinear responses and thresholds, with linkages often between apparently disparate components. The interconnected nature of the Earth system is wonderfully illustrated by the diverse roles played by atmospheric transport of mineral 'dust', particularly in its capacity as a key pathway for the delivery of nutrients essential to plant growth, not only on land, but perhaps more importantly, in the ocean. Dust therefore biogeochemically links land, air and sea. This paper reviews the biogeochemical role of mineral dust in the Earth system and its interaction with climate, and, in particular, the potential importance of both past and possible future changes in aeolian delivery of the micro-nutrient iron to the ocean. For instance, if, in the future, there was to be a widespread stabilization of soils for the purpose of carbon sequestration on land, a reduction in aeolian iron supply to the open ocean would occur. The resultant weakening of the oceanic carbon sink could potentially offset much of the carbon sequestered on land. In contrast, during glacial times, enhanced dust supply to the ocean could have 'fertilized' the biota and driven atmospheric CO(2) lower. Dust might even play an active role in driving climatic change; since changes in dust supply may affect climate, and changes in climate, in turn, influence dust, a 'feedback loop' is formed. Possible feedback

  11. [Fire disaster due to deflagration of a propane gas-air mixture].

    PubMed

    Nadjem, Hadi; Vogt, Susanne; Simon, Karl-Heinz; Pollak, Stefan; Geisenberger, Dorothee; Kramer, Lena; Pircher, Rebecca; Perdekampl, Markus Große; Thierauf-Emberger, Annette

    2015-01-01

    On 26 Nov 2012, a serious fire occurred at Neustadt/Black Forest in which 14 persons in a sheltered workshop died and 10 other individuals were injured. The fire was caused by the unbridled escape of propane gas due to accidental disconnection of the screw fixing between a gas bottle and a catalytic heater. Deflagration of the propane gas-air mixture set the workshop facilities on fire. In spite of partly extensive burns the fatally injured victims could be rapidly identified. The results of the fire investigations at the scene and the autopsy findings are presented. Carboxyhemoglobin concentrations ranged between 8 and 56 % and signs of fire fume inhalation were present in all cases. Three victims had eardrum ruptures due to the sudden increase in air pressure during the deflagration. PMID:26548032

  12. Flue gas treatment for SO2 removal with air-sparged hydrocyclone technology.

    PubMed

    Bokotko, Romuald P; Hupka, Jan; Miller, Jan D

    2005-02-15

    Laboratory results from an initial study on the removal of SO2 from gas mixtures are reported using air-sparged hydrocyclone (ASH) technology. Tap water and alkaline solutions were used for absorption, and the influence of gas flow rate, water flow rate, and length of the ASH unit were investigated. The research results indicate thatthe air-sparged hydrocyclone can be used as a highly efficient absorber for SO2 emissions. The ASH allows for 97% SO2 removal using water alone for sulfur dioxide content in the gas phase of 5 g/m3. All SO2 is removed in weakly alkaline solution (0.01 mol NaOH/dm3).

  13. Mercury in soil gas and air--A potential tool in mineral exploration

    USGS Publications Warehouse

    McCarthy, Joseph Howard; Vaughn, W.W.; Learned, R.E.; Meuschke, J.L.

    1969-01-01

    The mercury content in soil gas and in the atmosphere was measured in several mining districts to test the possibility that the mercury content in the atmosphere is higher over ore deposits than over barren ground. At Cortez, Nev., the distribution of anorhalous amounts of mercury in the air collected at ground level (soil gas) correlates well with the distribution of gold-bearing rocks that are covered by as much as 100 feet of gravel. The mercury content in the atmosphere collected at an altitude of 200 feet by an aircraft was 20 times background over a mercury posit and 10 times background over two porphyry copper deposits. Measurement of mercury in soil gas and air may prove to be a valuable exploration tool.

  14. [Fire disaster due to deflagration of a propane gas-air mixture].

    PubMed

    Nadjem, Hadi; Vogt, Susanne; Simon, Karl-Heinz; Pollak, Stefan; Geisenberger, Dorothee; Kramer, Lena; Pircher, Rebecca; Perdekampl, Markus Große; Thierauf-Emberger, Annette

    2015-01-01

    On 26 Nov 2012, a serious fire occurred at Neustadt/Black Forest in which 14 persons in a sheltered workshop died and 10 other individuals were injured. The fire was caused by the unbridled escape of propane gas due to accidental disconnection of the screw fixing between a gas bottle and a catalytic heater. Deflagration of the propane gas-air mixture set the workshop facilities on fire. In spite of partly extensive burns the fatally injured victims could be rapidly identified. The results of the fire investigations at the scene and the autopsy findings are presented. Carboxyhemoglobin concentrations ranged between 8 and 56 % and signs of fire fume inhalation were present in all cases. Three victims had eardrum ruptures due to the sudden increase in air pressure during the deflagration.

  15. Methane emission and consumption at a North Sea gas seep (Tommeliten area)

    NASA Astrophysics Data System (ADS)

    Niemann, H.; Elvert, M.; Hovland, M.; Orcutt, B.; Judd, A.; Suck, I.; Gutt, J.; Joye, S.; Damm, E.; Finster, K.; Boetius, A.

    2005-11-01

    The North Sea hosts large coal, oil and gas reservoirs of commercial value. Natural leakage pathways of subsurface gas to the hydrosphere have been recognized during geological surveys (Hovland and Judd, 1988). The Tommeliten seepage area is part of the Greater Ekofisk area, which is situated above the Tommeliten Delta salt diapir in the central North Sea. In this study, we report of an active seep site (56°29.90'N, 2°59.80'E) located in the Tommeliten area, Norwegian Block 1/9, at 75 m water depth. Here, cracks in a buried marl horizon allow methane to migrate into overlying clay-silt and sandy sediments. Hydroacoustic sediment echosounding showed several venting spots coinciding with the apex of marl domes where methane is released into the water column and potentially to the atmosphere during deep mixing situations. In the vicinity of the gas seeps, sea floor observations showed small mats of giant sulphide-oxidizing bacteria above patches of black sediments and carbonate crusts, which are exposed 10 to 50 cm above seafloor forming small reefs. These Methane-Derived Authigenic Carbonates (MDACs) contain 13C-depleted, archaeal lipids indicating previous gas seepage and AOM activity. High amounts of sn2-hydroxyarchaeol relative to archaeol and low abundances of biphytanes in the crusts give evidence that ANaerobic MEthane-oxidising archaea (ANME) of the phylogenetic cluster ANME-2 were the potential mediators of Anaerobic Oxidation of Methane (AOM) at the time of carbonate formation. Small pieces of MDACs were also found subsurface at about 1.7 m sediment depth, associated with the Sulphate-Methane Transition Zone (SMTZ). The SMTZ of Tommeliten is characterized by elevated AOM and Sulphate Reduction (SR) rates, increased concentrations of 13C-depleted tetraether derived biphytanes, and specific bacterial Fatty Acids (FA). Further biomarker and 16S rDNA based analyses give evidence that AOM at the Tommeliten SMTZ is mediated by archaea belonging to the ANME-1b

  16. A review and assessment of gas hydrate potential in Çınarcık Basin, Sea of Marmara

    NASA Astrophysics Data System (ADS)

    Sile, Hande; Akin, Cansu; Ucarkus, Gulsen; Namik Cagatay, M.

    2016-04-01

    The Sea of Marmara (NW Turkey), an intracontinental sea between the Mediterranean and Black Seas, is located in a tectonically active region with the formation of shallow gas hydrates and free gas. It is widely known that, Sea of Marmara sediments are organic-rich and conducive to production of methane, which is released on the sea floor through active fault segments of the North Anatolian Fault (Geli et al., 2008). Here we study the gas hydrate potential of the Çınarcık Basin using published data and our core analyses together with gas hydrate stability relations. The gas sampled in the Çınarcık Basin is composed mainly of biogenic methane and trace amounts of heavier hydrocarbons (Bourry et al., 2009). The seafloor at 1273 m depth on the Çınarcık Basin with temperature of 14.5oC and hydrostatic pressure of 127.3 atm corresponds to the physical limit for gas hydrate formation with respect to phase behavior of gas hydrates in marine sediments (Ménot and Bard, 2010). In order to calculate the base of the gas hydrate stability zone in Çınarcık Basin, we plotted T (oC) calculated considering the geothermal gradient versus P (atm) on the phase boundary diagram. Below the seafloor, in addition to hydrostatic pressure (10 Mpa/km), we calculated lithostatic pressure due to sediment thickness considering the MSCL gamma ray density values (~1.7 gr/cm3). Our estimations show that, gas hydrate could be stable in the upper ~20 m of sedimentary succession in Çınarcık Basin. The amount of gas hydrate in the Çınarcık Basin can be determined using the basinal area below 1220 m depth (483 km2) and average thickness of the gas hydrate stability zone (20 m) and the sediment gas hydrate saturation (1.2 % used as Milkov, 2004 suggested). The calculations indicate the potential volume of gas hydrate in Çınarcık Basin as ~11.6x107 m3. Such estimates are helpful for the consideration of gas hydrates as a new energy resource, for assessment of geohazards or their

  17. Gas hydrates in the deep water Ulleung Basin, East Sea, Korea.

    NASA Astrophysics Data System (ADS)

    Ryu, Byong-Jae

    2016-04-01

    Studies on gas hydrates in the deep-water Ulleung Basin, East Sea, Korea was initiated by the Korea Institute of Geoscience and Mineral Resources (KIGAM) to secure the future energy resources in 1996. Bottom simulating reflectors (BSRs) were first identified on seismic data collected in the southwestern part of the basin from 1998 to 1999. Regional geophysical surveys and geological studies of gas hydrates in the basin have been carried out by KIGAM from 2000 to 2004. The work included 12,367 km of 2D multi-channel seismic reflection lines and 38 piston cores 5 to 8 m long. As a part of the Korean National Gas Hydrate Program that has been performed since 2005, 6690 km of 2D multi-channel reflection seismic lines, 900 km2 of 3D seismic data, 69 piston cores and three PROD cores were additionally collected. In addition, two gas hydrate drilling expeditions were performed in 2007 and 2010. Cracks generally parallel to beddings caused by the dissociation of gas hydrate were often observed in cores. The lack of higher hydrocarbons and the carbon isotope ratios indicate that the methane is primarily biogenic. The seismic data showed clear and wide-spread bottom-simulating reflectors (BSRs). The BSR was identified by (a) its polarity opposite to the seafloor, (b) its seafloor-parallel reflection behavior, and (c) its occurrence at a sub-bottom depth corresponding to the expected base of gas hydrate stability zone. Several vertical to sub-vertical chimney-like blank zones up to several kilometers in diameter were also identified in the study area. They are often associated with velocity pull-up structures that are interpreted due to higher velocity in gas hydrate-bearing deposits. Seismic velocity analysis also showed a high velocity anomaly within the pull-up structure. Gas hydrate samples were collected from the shallow sedimentary section of blanking zone by piston coring in 2007. BSRs mainly occur in the southern part of the basin. They also locally observed in the

  18. Regional mesoscale air-sea coupling impacts and extreme meteorological events role on the Mediterranean Sea water budget

    NASA Astrophysics Data System (ADS)

    Lebeaupin Brossier, Cindy; Bastin, Sophie; Béranger, Karine; Drobinski, Philippe

    2015-02-01

    The Mediterranean Sea water budget (MWB) is a key parameter, as it controls the Mediterranean Sea water loss and thus the Atlantic Water inflow and the Mediterranean general circulation. More accurately, the MWB controls the net flow through the Strait of Gibraltar, which implies both inflow and outflow. Generally considered at the basin scale and over long-term periods, the MWB is in fact characterized by a large variability in space and time, induced by the complex topography of the region, mesoscale processes and (short) intense events in the ocean and atmosphere compartments. In this study, we use an ocean-atmosphere coupled system at mesoscale able to represent such phenomena, to evaluate the MWB atmospheric components: Evaporation (E) and Precipitation (P). We compare two companion regional simulations: an uncoupled atmospheric run using the ERA-interim Sea Surface Temperature (SST) reanalysis and a coupled run using the MORCE system with the two-way coupling between the NEMO-MED12 eddy-resolving ocean model and the non-hydrostatic Weather Research and Forecasting atmospheric model. We first evaluate the SST validity against satellite data and evidence the coupled system ability in representing SST mesoscale structures, characteristics of the Mediterranean circulation and of small-scale ocean processes, despite a colder mean value and a lower amplitude of the annual cycle. Then, the comparison aims to examine the coupled processes effects (meaning the impacts of the interactive high-resolution and high-frequency SST) on E and P and on their variability. The comparison highlights that the SST is the controlling factor for E and P budgets, with reduction by 6 and 3 % in the coupled run compared to the uncoupled run, respectively. The modifications propagate until 750 km inland far from the Mediterranean coast, as towards the Atlantic Ocean and the Black Sea. This indicates that coupling plays a major role in distributing water at mesoscale. The coupling

  19. Increased continental-margin slumping frequency during sea-level lowstands above gas hydrate-bearing sediments

    SciTech Connect

    Paull, C.K.; Buelow, W.J.; Ussler, W. III; Borowski, W.S.

    1996-02-01

    We present {sup 14}C data on sediment samples from cores of the upper 7 m of the sediment column overlying a major continental-rise gas hydrate field on the southern Carolina Rise and inner Blake Ridge offshore the southeastern United States. The data show that glacial-age sediments are underrepresented in the cores. The observation is consistent with a previously predicted association between sea-level lowstands and increased frequency of sea-floor slumping on continental margins containing gas hydrates. 26 refs., 3 figs.

  20. Gas flaring and resultant air pollution: A review focusing on black carbon.

    PubMed

    Fawole, Olusegun G; Cai, X-M; MacKenzie, A R

    2016-09-01

    Gas flaring is a prominent source of VOCs, CO, CO2, SO2, PAH, NOX and soot (black carbon), all of which are important pollutants which interact, directly and indirectly, in the Earth's climatic processes. Globally, over 130 billion cubic metres of gas are flared annually. We review the contribution of gas flaring to air pollution on local, regional and global scales, with special emphasis on black carbon (BC, "soot"). The temporal and spatial characteristics of gas flaring distinguishes it from mobile combustion sources (transport), while the open-flame nature of gas flaring distinguishes it from industrial point-sources; the high temperature, flame control, and spatial compactness distinguishes gas flaring from both biomass burning and domestic fuel-use. All of these distinguishing factors influence the quantity and characteristics of BC production from gas flaring, so that it is important to consider this source separately in emissions inventories and environmental field studies. Estimate of the yield of pollutants from gas flaring have, to date, paid little or no attention to the emission of BC with the assumption often being made that flaring produces a smokeless flame. In gas flares, soot yield is known to depend on a number of factors, and there is a need to develop emission estimates and modelling frameworks that take these factors into consideration. Hence, emission inventories, especially of the soot yield from gas flaring should give adequate consideration to the variation of fuel gas composition, and to combustion characteristics, which are strong determinants of the nature and quantity of pollutants emitted. The buoyant nature of gas flaring plume, often at temperatures in the range of 2000 K, coupled with the height of the stack enables some of the pollutants to escape further into the free troposphere aiding their long-range transport, which is often not well-captured by model studies.

  1. Gas flaring and resultant air pollution: A review focusing on black carbon.

    PubMed

    Fawole, Olusegun G; Cai, X-M; MacKenzie, A R

    2016-09-01

    Gas flaring is a prominent source of VOCs, CO, CO2, SO2, PAH, NOX and soot (black carbon), all of which are important pollutants which interact, directly and indirectly, in the Earth's climatic processes. Globally, over 130 billion cubic metres of gas are flared annually. We review the contribution of gas flaring to air pollution on local, regional and global scales, with special emphasis on black carbon (BC, "soot"). The temporal and spatial characteristics of gas flaring distinguishes it from mobile combustion sources (transport), while the open-flame nature of gas flaring distinguishes it from industrial point-sources; the high temperature, flame control, and spatial compactness distinguishes gas flaring from both biomass burning and domestic fuel-use. All of these distinguishing factors influence the quantity and characteristics of BC production from gas flaring, so that it is important to consider this source separately in emissions inventories and environmental field studies. Estimate of the yield of pollutants from gas flaring have, to date, paid little or no attention to the emission of BC with the assumption often being made that flaring produces a smokeless flame. In gas flares, soot yield is known to depend on a number of factors, and there is a need to develop emission estimates and modelling frameworks that take these factors into consideration. Hence, emission inventories, especially of the soot yield from gas flaring should give adequate consideration to the variation of fuel gas composition, and to combustion characteristics, which are strong determinants of the nature and quantity of pollutants emitted. The buoyant nature of gas flaring plume, often at temperatures in the range of 2000 K, coupled with the height of the stack enables some of the pollutants to escape further into the free troposphere aiding their long-range transport, which is often not well-captured by model studies. PMID:27262132

  2. Extreme air-sea surface turbulent fluxes in mid latitudes - estimation, origins and mechanisms

    NASA Astrophysics Data System (ADS)

    Gulev, Sergey; Natalia, Tilinina

    2014-05-01

    provide locally high winds and air-sea temperature gradients. For this purpose we linked characteristics of cyclone activity over the midlatitudinal oceans with the extreme surface turbulent heat fluxes. Cyclone tracks and parameters of cyclone life cycle (deepening rates, propagation velocities, life time and clustering) were derived from the same reanalyses using state of the art numerical tracking algorithm. The main questions addressed in this study are (i) through which mechanisms extreme surface fluxes are associated with cyclone activity? and (ii) which types of cyclones are responsible for forming extreme turbulent fluxes? Our analysis shows that extreme surface fluxes are typically associated not with cyclones themselves but rather with cyclone-anticyclone interaction zones. This implies that North Atlantic and North Pacific series of intense cyclones do not result in the anomalous surface fluxes. Alternatively, extreme fluxes are most frequently associated with blocking situations, particularly with the intensification of the Siberian and North American Anticyclones providing cold-air outbreaks over WBC regions.

  3. Constraints on sea to air emissions from methane clathrates in the vicinity of Svalbard

    NASA Astrophysics Data System (ADS)

    Pisso, Ignacio; Vadakkepuliyambatta, Sunil; Platt, Stephen Matthew; Eckhardt, Sabine; Allen, Grant; Pitt, Joseph; Silyakova, Anna; Hermansen, Ove; Schmidbauer, Norbert; Mienert, Jurgen; Myhre, Cathrine Lund; Stohl, Andreas

    2016-04-01

    Methane stored in the seabed in the form of clathrates has the potential to be released into the atmosphere due to ongoing ocean warming. The Methane Emissions from Arctic Ocean to Atmosphere (MOCA, http://moca.nilu.no/) proje sct conducted measurement campaigns in the vicinity of Svalbard during the summers of 2014 and 2015 in collaboration with the Centre for Arctic Gas Hydrate, Environment and Climate (CAGE, https://cage.uit.no/) and the MAMM (https://arcticmethane.wordpress.com) project . The extensive set of measurements includes air (BAe 146) and ship (RV Helmer Hansen) borne methane concentrations, complemented with the nearby monitoring site at Zeppelin mountain. In order to assess the atmospheric impact of emissions from seabed methane hydrates, we characterised the local and long range atmospheric transport during the aircraft campaign and different scenarios for the emission sources. We present a range of upper bounds for the CH4 emissions during the campaign period as well as the methodologies used to obtain them. The methodologies include a box model, Lagrangian transport and elementary inverse modelling. We emphasise the analysis of the aircraft data. We discuss in detail the different methodologies used for determining the upper flux bounds as well as its uncertainties and limitations. The additional information provided by the ship and station observations will be briefly mentioned.

  4. Living marine resources of the Chukchi Sea: a resource report for the Chukchi Sea oil and gas lease sale Number 85. Technical memo

    SciTech Connect

    Morris, B.F.

    1981-04-01

    An area of the outer continental shelf of the northeastern Chukchi Sea is currently proposed by the Department of the Interior's Bureau of Land Management for oil and gas leasing in February 1985. The report assesses the biological resources of the northeastern Chukchi Sea that may be at risk from petroleum exploration and development, and proposes research needs to minimize and avoid potential biological impacts. The Chukchi Sea supports large populations of marine mammals and seabirds, which depend on the fish and invertebrate populations of the region. The marine mammals of major importance in the region are the bowhead whale, gray whale, beluga whale, walrus, ringed seal, bearded seal, spotted seal, and polar bear. Less frequent but regular visitors to the area are the fin, minke, humpback, and killer whales, the harbor porpoise, and ribbon seals.

  5. Sewer Gas: An Indoor Air Source of PCE to Consider During Vapor Intrusion Investigations

    PubMed Central

    Pennell, Kelly G.; Scammell, Madeleine Kangsen; McClean, Michael D.; Ames, Jennifer; Weldon, Brittany; Friguglietti, Leigh; Suuberg, Eric M.; Shen, Rui; Indeglia, Paul A.; Heiger-Bernays, Wendy J.

    2013-01-01

    The United States Environmental Protection Agency (USEPA) is finalizing its vapor intrusion guidelines. One of the important issues related to vapor intrusion is background concentrations of volatile organic chemicals (VOCs) in indoor air, typically attributed to consumer products and building materials. Background concentrations can exist even in the absence of vapor intrusion and are an important consideration when conducting site assessments. In addition, the development of accurate conceptual models that depict pathways for vapor entry into buildings is important during vapor intrusion site assessments. Sewer gas, either as a contributor to background concentrations or as part of the site conceptual model, is not routinely evaluated during vapor intrusion site assessments. The research described herein identifies an instance where vapors emanating directly from a sanitary sewer pipe within a residence were determined to be a source of tetrachloroethylene (PCE) detected in indoor air. Concentrations of PCE in the bathroom range from 2.1 to 190 ug/m3 and exceed typical indoor air concentrations by orders of magnitude resulting in human health risk classified as an “Imminent Hazard” condition. The results suggest that infiltration of sewer gas resulted in PCE concentrations in indoor air that were nearly two-orders of magnitude higher as compared to when infiltration of sewer gas was not known to be occurring. This previously understudied pathway whereby sewers serve as sources of PCE (and potentially other VOC) vapors is highlighted. Implications for vapor intrusion investigations are also discussed. PMID:23950637

  6. Disruption of the air-sea interface and formation of two-phase transitional layer in hurricane conditions

    NASA Astrophysics Data System (ADS)

    Soloviev, A.; Matt, S.; Fujimura, A.

    2012-04-01

    The change of the air-sea interaction regime in hurricane conditions is linked to the mechanism of direct disruption of the air-sea interface by pressure fluctuations working against surface tension forces (Soloviev and Lukas, 2010). The direct disruption of the air-sea interface due to the Kelvin-Helmholtz (KH) instability and formation of a two-phase transitional layer have been simulated with a computational fluid dynamics model. The volume of fluid multiphase model included surface tension at the water-air interface. The model was initialized with either a flat interface or short wavelets. Wind stress was applied at the upper boundary of the air layer, ranging from zero stress to hurricane force stress in different experiments. Under hurricane force wind, the numerical model demonstrated disruption of the air-water interface and the formation of spume and the two-phase transition layer. In the presence of a transition layer, the air-water interface is no longer explicitly identifiable. As a consequence, the analysis of dimensions suggests a linear dependence for velocity and logarithm of density on depth (which is consistent with the regime of marginal stability in the transition layer). The numerical simulations confirmed the presence of linear segments in the corresponding profiles within the transition layer. This permitted a parameterization of the equivalent drag coefficient due to the presence of the two-phase transition layer at the air-sea interface. This two-phase layer parameterization represented the lower limit imposed on the drag coefficient under hurricane conditions. The numerical simulations helped to reduce the uncertainty in the critical Richardson number applicable to the air-sea interface and in the values of two dimensionless constants; this reduced the uncertainty in the parameterization of the lower limit on the drag coefficient. The available laboratory data (Donelan et al., 2004) are bounded by the two-phase layer parameterization from

  7. Predicting Air Quality Impacts Associated with Oil and Gas Development in the Uinta Basin Using EPA’s Photochemical Air Quality Model

    EPA Science Inventory

    Rural areas with close proximity to oil and natural gas operations in Utah have experienced winter ozone levels that exceed EPA’s National Ambient Air Quality Standards (NAAQS). Through a collaborative effort, EPA Region 8 – Air Program, ORD, and OAQPS used the Commun...

  8. Noble gas adsorption with and without mechanical stress: Not Martian signatures but fractionated air

    NASA Astrophysics Data System (ADS)

    Schwenzer, Susanne P.; Herrmann, Siegfried; Ott, Ulrich

    2012-06-01

    Sample preparation, involving physical and chemical methods, is an unavoidable step in geochemical analysis. From a noble gas perspective, the two important effects are loss of sample gas and/or incorporation of air, which are significant sources of analytical artifacts. This article reports on the effects of sample exposure to laboratory air without mechanical influence and during sample grinding. The experiments include pure adsorption on terrestrial analog materials (gibbsite and olivine) and grinding of Martian meteorites. A consistent observation is the presence of an elementally fractionated air component in the samples studied. This is a critical form of terrestrial contamination in meteorites as it often mimics the heavy noble gas signatures of known extra-terrestrial end-members that are the basis of important conclusions about the origin and evolution of a meteorite. Although the effects of such contamination can be minimized by avoiding elaborate sample preparation protocols, caution should be exercised in interpreting the elemental ratios (Ar/Xe, Kr/Xe), especially in the low-temperature step extractions. The experiments can also be transferred to the investigation of Martian meteorites with long terrestrial residence times, and to Mars, where the Mars Science Laboratory mission will be able to measure noble gas signatures in the current atmosphere and in rocks and soils collected on the surface in Gale crater.

  9. Remediation of MTBE from drinking water: air stripping followed by off-gas adsorption.

    PubMed

    Ramakrishnan, Balaji; Sorial, George A; Speth, Thomas F; Clark, Patrick; Zaffiro, Alan; Patterson, Craig; Hand, David W

    2004-05-01

    The widespread use of methyl tertiary butyl ether (MTBE) as an oxygenate in gasoline has resulted in the contamination of a large number of ground and surface water sources. Even though air stripping has been proven to be an effective treatment technology for MTBE removal, off-gas treatment often is required in conjunction with it. This study evaluated the combined treatment technologies of air stripping followed by off-gas adsorption on a pilot scale for the treatment of MTBE-contaminated water. The effect of air/water ratios on the treatment efficiency was studied, and the mass transfer coefficient was determined. Air/water ratios of 105:1, 151:1, 177:1, 190:1, 202:1, and 206:1 were used, and a treatment efficiency of >99% was achieved for all the runs conducted. The depth of packing required to achieve maximum treatment efficiency decreased with increasing air/water ratio. Relative humidity (RH) impacts on the MTBE adsorption capacity of a granular activated carbon (GAC) and carbonaceous resin were determined from pilot plant studies. Breakthrough profiles obtained from the pilot plant studies conducted at 20, 30, and 50% RH indicated that GAC has a higher adsorptive capacity than resin. The adsorptive capacity of GAC decreased with increasing RH, whereas RH did not impact the resin adsorptive capacity.

  10. Potential hazards of compressed air energy storage in depleted natural gas reservoirs.

    SciTech Connect

    Cooper, Paul W.; Grubelich, Mark Charles; Bauer, Stephen J.

    2011-09-01

    This report is a preliminary assessment of the ignition and explosion potential in a depleted hydrocarbon reservoir from air cycling associated with compressed air energy storage (CAES) in geologic media. The study identifies issues associated with this phenomenon as well as possible mitigating measures that should be considered. Compressed air energy storage (CAES) in geologic media has been proposed to help supplement renewable energy sources (e.g., wind and solar) by providing a means to store energy when excess energy is available, and to provide an energy source during non-productive or low productivity renewable energy time periods. Presently, salt caverns represent the only proven underground storage used for CAES. Depleted natural gas reservoirs represent another potential underground storage vessel for CAES because they have demonstrated their container function and may have the requisite porosity and permeability; however reservoirs have yet to be demonstrated as a functional/operational storage media for compressed air. Specifically, air introduced into a depleted natural gas reservoir presents a situation where an ignition and explosion potential may exist. This report presents the results of an initial study identifying issues associated with this phenomena as well as possible mitigating measures that should be considered.

  11. Sequestration of flue gas CO₂ by direct gas-solid carbonation of air pollution control system residues.

    PubMed

    Tian, Sicong; Jiang, Jianguo

    2012-12-18

    Direct gas-solid carbonation reactions of residues from an air pollution control system (APCr) were conducted using different combinations of simulated flue gas to study the impact on CO₂ sequestration. X-ray diffraction analysis of APCr determined the existence of CaClOH, whose maximum theoretical CO₂ sequestration potential of 58.13 g CO₂/kg APCr was calculated by the reference intensity ratio method. The reaction mechanism obeyed a model of a fast kinetics-controlled process followed by a slow product layer diffusion-controlled process. Temperature is the key factor in direct gas-solid carbonation and had a notable influence on both the carbonation conversion and the CO₂ sequestration rate. The optimal CO₂ sequestrating temperature of 395 °C was easily obtained for APCr using a continuous heating experiment. CO₂ content in the flue gas had a definite influence on the CO₂ sequestration rate of the kinetics-controlled process, but almost no influence on the final carbonation conversion. Typical concentrations of SO₂ in the flue gas could not only accelerate the carbonation reaction rate of the product layer diffusion-controlled process, but also could improve the final carbonation conversion. Maximum carbonation conversions of between 68.6% and 77.1% were achieved in a typical flue gas. Features of rapid CO₂ sequestration rate, strong impurities resistance, and high capture conversion for direct gas-solid carbonation were proved in this study, which presents a theoretical foundation for the applied use of this encouraging technology on carbon capture and storage.

  12. Sedation and anesthesia of hatchling leatherback sea turtles (Dermochelys coriacea) for auditory evoked potential measurement in air and in water.

    PubMed

    Harms, Craig A; Piniak, Wendy E D; Eckert, Scott A; Stringer, Elizabeth M

    2014-03-01

    Sedation or anesthesia of hatchling leatherback sea turtles was employed to acquire auditory evoked potential (AEP) measurements in air and in water to assess their hearing sensitivity in relation to potential consequences from anthropogenic noise. To reduce artifacts in AEP collection caused by muscle movement, hatchlings were sedated with midazolam 2 or 3 mg/kg i.v. for in-air (n = 7) or in-water (n = 11) AEP measurements; hatchlings (n = 5) were anesthetized with ketamine 6 mg/kg and dexmedetomidine 30 microg/kg i.v. reversed with atipamezole 300 microg/kg, half i.m. and half i.v. for in-air AEP measurements. Midazolam-sedated turtles were also physically restrained with a light elastic wrap. For in-water AEP measurements, sedated turtles were brought to the surface every 45-60 sec, or whenever they showed intention signs for breathing, and not submerged again until they took a breath. Postprocedure temperature-corrected venous blood pH, pCO2, pO2, and HCO3- did not differ among groups, although for the midazolam-sedated in-water group, pCO2 trended lower, and in the ketamine-dexmedetomidine anesthetized group there was one turtle considered clinically acidotic (temperature-corrected pH = 7.117). Venous blood lactate was greater for hatchlings recently emerged from the nest than for turtles sedated with midazolam in air, with the other two groups falling intermediate between, but not differing significantly from the high and low lactate groups. Disruptive movements were less frequent with anesthesia than with sedation in the in-air group. Both sedation with midazolam and anesthesia with ketamine-dexmedetomidine were successful for allowing AEP measurements in hatchling leatherback sea turtles. Sedation allowed the turtle to protect its airway voluntarily while limiting flipper movement. Midazolam or ketamine-dexmedetomidine (and reversal with atipamezole) would be useful for other procedures requiring minor or major restraint in leatherback sea turtle hatchlings

  13. Sedation and anesthesia of hatchling leatherback sea turtles (Dermochelys coriacea) for auditory evoked potential measurement in air and in water.

    PubMed

    Harms, Craig A; Piniak, Wendy E D; Eckert, Scott A; Stringer, Elizabeth M

    2014-03-01

    Sedation or anesthesia of hatchling leatherback sea turtles was employed to acquire auditory evoked potential (AEP) measurements in air and in water to assess their hearing sensitivity in relation to potential consequences from anthropogenic noise. To reduce artifacts in AEP collection caused by muscle movement, hatchlings were sedated with midazolam 2 or 3 mg/kg i.v. for in-air (n = 7) or in-water (n = 11) AEP measurements; hatchlings (n = 5) were anesthetized with ketamine 6 mg/kg and dexmedetomidine 30 microg/kg i.v. reversed with atipamezole 300 microg/kg, half i.m. and half i.v. for in-air AEP measurements. Midazolam-sedated turtles were also physically restrained with a light elastic wrap. For in-water AEP measurements, sedated turtles were brought to the surface every 45-60 sec, or whenever they showed intention signs for breathing, and not submerged again until they took a breath. Postprocedure temperature-corrected venous blood pH, pCO2, pO2, and HCO3- did not differ among groups, although for the midazolam-sedated in-water group, pCO2 trended lower, and in the ketamine-dexmedetomidine anesthetized group there was one turtle considered clinically acidotic (temperature-corrected pH = 7.117). Venous blood lactate was greater for hatchlings recently emerged from the nest than for turtles sedated with midazolam in air, with the other two groups falling intermediate between, but not differing significantly from the high and low lactate groups. Disruptive movements were less frequent with anesthesia than with sedation in the in-air group. Both sedation with midazolam and anesthesia with ketamine-dexmedetomidine were successful for allowing AEP measurements in hatchling leatherback sea turtles. Sedation allowed the turtle to protect its airway voluntarily while limiting flipper movement. Midazolam or ketamine-dexmedetomidine (and reversal with atipamezole) would be useful for other procedures requiring minor or major restraint in leatherback sea turtle hatchlings

  14. Synoptic evaluation of carbon cycling in Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M.

    2013-10-01

    The accelerated decline in Arctic sea ice combined with an ongoing trend toward a more dynamic atmosphere is modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of identifying indices of ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. The mean atmospheric forcing was a mild upwelling-favorable wind (~5 km h-1) blowing from the N-E and a decaying ice cover (<80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2 with a mean uptake rate of -2.0 ± 3.3 mmol C m-2d-1. We attribute this discrepancy to: (1) elevated PP rates (>600 mg C m-2d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (>10mmol C m-2d-1). Although generally <100 mg C m-2d-1, daily PP rates cumulated to a total PP of ~437.6 × 103 t C, which was roughly twice higher than the organic carbon delivery by river inputs (~241.2 × 103 t C). Subsurface PP represented 37.4% of total PP for the

  15. Characteristics and interpretation of fracture-filled gas hydrate: an example from the Ulleung Basin, East Sea of Korea

    USGS Publications Warehouse

    Lee, Myung Woong; Collett, Timothy S.

    2013-01-01

    Through the use of 2-D and 3-D seismic data, a total of thirteen sites were selected and drilled in the East Sea of Korea in 2010. A suite of logging-while-drilling (LWD) logs was acquired at each site. LWD logs from the UBGH2-3A well indicate significant gas hydrate in clay-bearing sediments including several zones with massive gas hydrate with a bulk density less than 1.0 g/m3 for depths between 5 and 103 m below the sea floor. The UBGH2-3A well was drilled on a seismically identified chimney structure with a mound feature at the sea floor. Average gas hydrate saturations estimated from the isotropic analysis of ring resistivity and P-wave velocity logs are 80 ± 13% and 47 ± 16%, respectively, whereas they are 46 ± 17% and 45 ± 16%, respectively from the anisotropic analysis. Modeling indicates that the upper part of chimney (between 5 and 45 m below sea floor [mbsf]) is characterized by gas hydrate filling near horizontal fractures (7° dip) and the lower part of chimney (between 45 and 103 mbsf) is characterized by gas hydrate filling high angle fractures on the basis of ring resistivity and P-wave velocity. The anisotropic analysis using P40H resistivity (phase shift resistivity at 32 mHz with 40 inch spacing) and the P-wave velocity yields a gas hydrate saturation of 46 ± 15% and 46 ± 15% respectively, similar to those estimated using ring resistivity and P-wave velocity, but with quite different fracture dip angles. Differences in vertical resolution, depth of investigation, and a finite fracture dimension relative to the tool separation appear to contribute to this discrepancy. Forward modeling of anisotropic resistivity and velocity are essential to identify gas hydrate in fractures and to estimate accurate gas hydrate amounts.

  16. Air-Sea Exchange and Budget of Sulfur and Oxygen-Containing Volatile Organic Compounds in the Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Tanimoto, H.; Omori, Y.; Inomata, S.; Iwata, T.; Kameyama, S.

    2015-12-01

    By combining proton transfer reaction-mass spectrometry (PTR-MS) and gradient flux (GF) technique, in situ measurement of air-sea fluxes of multiple volatile organic compounds (VOCs) was developed and deployed. Starting in 2008, we made in situ observations of air-sea fluxes at 15 locations as well as underway observations of marine air/surface seawater bulk concentrations in the Pacific Ocean, during eight research cruises by R/V Hakuho-Maru. The fluxes of biogenic trace gases, DMS and isoprene, were always positive, with the magnitudes being in accordance with previously reported. In contrast, the fluxes of oxygenated VOCs including acetone and acetaldehyde varied from negative to positive, suggesting that the tropical and subtropical Pacific are a source, while the North Pacific is a sink. A basin-scale budget of VOCs were determined for 4 biogeochemical provinces in the Pacific Ocean, and the role of oceans for VOCs were discussed with respect to physical and biogeochemical processes.

  17. Exchange of polycyclic aromatic hydrocarbons across the air-water interface in the Bohai and Yellow Seas

    NASA Astrophysics Data System (ADS)

    Chen, Yingjun; Lin, Tian; Tang, Jianhui; Xie, Zhiyong; Tian, Chongguo; Li, Jun; Zhang, Gan

    2016-09-01

    In this study, air and surface seawater samples collected from the Bohai (BS) and Yellow Seas (YS) in May 2012 were determined exchange of PAHs, especially of low-molecular-weight (LMW) PAHs (three- and four-ring PAHs) at the air-water interface. Net volatilization fluxes of LMW PAHs were 266-1454 ng/m2/d and decreased with distance from the coast, indicating that these PAHs transported from coastal runoff were potential contributors to the atmosphere in the BS and YS. Moreover, LMW PAHs were enriched in the dissolved phase compared with those in the particulate phase in the water column, possibly suggesting that the volatilized LMW PAHs were directly derived from wastewater discharge or petroleum pollution rather than released from contaminated sediments. The air-sea exchange fluxes of the three-ring PAHs were 2- to 20-fold higher than their atmospheric deposition fluxes in the BS and YS. The input to and output from the water reached equilibrium for four-ring PAHs. Differently, five- and six-ring PAHs were introduced into the marine environment primarily through dry and wet deposition, indicating that the water column was still a sink of these PAHs from the surrounding atmosphere.

  18. Exchange of polycyclic aromatic hydrocarbons across the air-water interface in the Bohai and Yellow Seas

    NASA Astrophysics Data System (ADS)

    Chen, Yingjun; Lin, Tian; Tang, Jianhui; Xie, Zhiyong; Tian, Chongguo; Li, Jun; Zhang, Gan

    2016-09-01

    In this study, air and surface seawater samples collected from the Bohai (BS) and Yellow Seas (YS) in May 2012 were determined exchange of PAHs, especially of low-molecular-weight (LMW) PAHs (three- and four-ring PAHs) at the air-water interface. Net volatilization fluxes of LMW PAHs were 266-1454 ng/m2/d and decreased with distance from the coast, indicating that these PAHs transported from coastal runoff were potential contributors to the atmosphere in the BS and YS. Moreover, LMW PAHs were enriched in the dissolved phase compared with those in the particulate phase in the water column, possibly suggesting that the volatilized LMW PAHs were directly derived from wastewater discharge or petroleum pollution rather than released from contaminated sediments. The air-sea exchange fluxes of the three-ring PAHs were 2- to 20-fold higher than their atmospheric deposition fluxes in the BS and YS. The input to and output from the water reached equilibrium for four-ring PAHs. Differently, five- and six-ring PAHs were introduced into the marine environment primarily through dry and wet deposition, indicating that the water column was still a sink of these PAHs from the surrounding atmosphere.

  19. Variability in surface meteorology and air-sea fluxes due to cumulus convective systems observed during CINDY/DYNAMO

    NASA Astrophysics Data System (ADS)

    Yokoi, Satoru; Katsumata, Masaki; Yoneyama, Kunio

    2014-03-01

    This study examines the variability in surface meteorological parameters and air-sea heat fluxes due to cold pools emanating from cumulus convective systems observed over the tropical Indian Ocean in November 2011. In particular, this study focuses on convective systems that are spatially smaller than mesoscale convective systems in a southeasterly trade wind environment. Composite analyses of convectively active periods show an increase in the sensible heat flux by 15-20 W m-2 that is primarily attributed to an increase in the difference between the surface air temperature and sea surface temperature and an increase in the latent heat flux by 30-70 W m-2 due to enhanced surface wind speeds. A succession of convectively active periods leads to a greater influence than those occurring independently. The direction of the surface wind velocity anomaly due to cold pools tends to be close to that of the environmental wind velocity, resulting in an efficient enhancement of wind speed. This study also demonstrates the close relation between cold pool intensities and convective activity. In particular, two measures of cold pool intensity, a minimum surface air temperature and a maximum amount of surface wind speed enhancement, are correlated with each other and with the convective activity around the observation point measured by radar-estimated rainfall and radar echo coverage.

  20. Proceedings of the 1992 Gas Research Institute, glycol dehydrator air emissions conference

    SciTech Connect

    Rueter, C.O.; Heath, C.J.

    1992-01-01

    Emissions of benzene, toluene, ethyl benzene, and the xylene isomers (BTEX) and other volatile organic compounds (VOC) from the reboiler still vent of glycol dehydration units have become a major concern for the natural gas industry as a result of increasing regulatory pressure. The Clean Air Act Amendments of 1990 have provided an impetus for regulating these emissions, and several states are regulating or considering regulation of these units. Because the estimated 20,000--30,000 glycol units in the United States treat virtually all of the domestically produced gas, this issue is of crucial importance to the natural gas industry. To encourage communication and a transfer of regulatory and technical information, the Gas Research Institute sponsored a two and a half day conference on glycol dehydrator air emissions issues. Twenty-two technical papers were presented on regulatory issues and activities, industry approaches to addressing emissions, research and development programs, process and emissions modeling, and control technologies. An open question and answer forum was also held. The conference was attended by 190 people from the production, processing, pipeline, and storage segments of the natural gas industry, as well as regulators, researchers, vendors, and other interested in the conference topic.

  1. Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

    USGS Publications Warehouse

    Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

    2014-01-01

    Mangrove forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h−1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m−2 d−1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.

  2. Comparison of CO2 Dynamics and Air-Sea Exchange in Contrasting Tropical Reef Environments

    NASA Astrophysics Data System (ADS)

    Drupp, P. S.; De Carlo, E. H.; Mackenzie, F. T.; Shamberger, K. E.; Musielewicz, S. B.; Maenner-Jones, S.; Sabine, C. L.; Feely, R. A.

    2011-12-01

    Multiyear high temporal resolution CO2 records in three differing coral reef settings were obtained using buoys deployed in coastal waters of Oahu since June 2008. The buoys are located on the barrier reef of Kaneohe Bay and offshore of Honolulu, on the south shore of Oahu. Annualized CO2 air-sea fluxes at the three buoys ranged from +0.05 mol C/m2/yr offshore Honolulu on a fringing reef well mixed with the open ocean to -1.12 mol C/m2/yr on a barrier reef flat in Kaneohe Bay (positive values represent CO2 sinks from the atmosphere and negative values represent sources). These fluxes compare well to those estimated from previous studies in Kaneohe Bay as well as in other tropical reef environments. pCO2 measurements, made every 3 hours, at each location show strong temporal cycles on multiple time scales ranging from diel to seasonal at each buoy and an anticorrelation with pO2. These records, when combined with those of a prior buoy deployment in southern Kaneohe Bay and several synoptic studies, allow us to examine how the principal biological cycles of productivity/respiration and calcification/carbonate dissolution are influenced by changing water column properties, physical processes (e.g. residence time) and atmospheric conditions and how these processes ultimately impact the exchange of CO2 between the ocean and atmosphere on hourly to interannual cycles. The data clearly demonstrate the need for high frequency pCO2 data to characterize completely and accurately short-term local changes in the CO2-carbonic acid system parameters and how these changes overprint the longer scale process of ocean acidification as a result of invasion of CO2 into the ocean due to emissions of anthropogenic CO2 to the atmosphere. Since many coral reef ecosystems are still sources of CO2 to the atmosphere because of positive net ecosystem calcification, and in some instances net heterotrophy, such data are even more critical in terms of assessing future changes in the direction

  3. Composition of primary cosmic rays near the bend from a study of hadrons in air showers at sea level

    NASA Technical Reports Server (NTRS)

    Mincer, A. I.; Freudenreich, H. T.; Goodman, J. A.; Tonwar, S. C.; Yodh, G. B.; Ellsworth, R. W.; Berley, D.

    1985-01-01

    Data on hadrons in air showers arriving at sea level were studied to find sensitivity to primary cosmic ray composition. The rate of showers which satisfy minimum shower density and hadron energy requirements as well as the rate of showers containing hadrons delayed with respect to the electron shower front are compared to Monte Carlo simulations. The data on the rate of total triggers and delayed hadrons are compared to predicted rates for two models of primary composition. The data are consistent with models which require an increasing heavy nuclei fraction near 10 to the 15th power eV. The spectra which are consistent with the observed rate are also compared to the observed shower size spectrum at sea level and mountain level.

  4. Dissolved methane concentration profiles and air-sea fluxes from 41°S to 27°N

    NASA Astrophysics Data System (ADS)

    Kelley, Cheryl A.; Jeffrey, Wade H.

    2002-07-01

    Water column samples from a transect cruise from southern Chile through the Panama Canal to the Gulf of Mexico were used to determine dissolved methane depth profiles and air-sea methane fluxes. In the Gulf of Mexico, surface concentrations were approximately 40% supersaturated with respect to the atmosphere, whereas near the equator and in the Peru upwelling region, 10-20% supersaturation generally occurred. These saturation ratios translate into an average flux of methane from the sea surface to the atmosphere of 0.38 μmol m-2 d-1. In addition, water column profiles of dissolved methane indicate that subsurface maxima in dissolved methane concentrations are a consistent feature of the open ocean, except near the equator. At the equator, the subsurface peak at the base of the mixed layer may be bowed down by the Equatorial Undercurrent. The highest methane concentration (12 nM) was observed in the Peru upwelling region.

  5. Climatological mean and decadal change in surface ocean pCO 2, and net sea-air CO 2 flux over the global oceans

    NASA Astrophysics Data System (ADS)

    Takahashi, Taro; Sutherland, Stewart C.; Wanninkhof, Rik; Sweeney, Colm; Feely, Richard A.; Chipman, David W.; Hales, Burke; Friederich, Gernot; Chavez, Francisco; Sabine, Christopher; Watson, Andrew; Bakker, Dorothee C. E.; Schuster, Ute; Metzl, Nicolas; Yoshikawa-Inoue, Hisayuki; Ishii, Masao; Midorikawa, Takashi; Nojiri, Yukihiro; Körtzinger, Arne; Steinhoff, Tobias; Hoppema, Mario; Olafsson, Jon; Arnarson, Thorarinn S.; Tilbrook, Bronte; Johannessen, Truls; Olsen, Are; Bellerby, Richard; Wong, C. S.; Delille, Bruno; Bates, N. R.; de Baar, Hein J. W.

    2009-04-01

    A climatological mean distribution for the surface water pCO 2 over the global oceans in non-El Niño conditions has been constructed with spatial resolution of 4° (latitude) ×5° (longitude) for a reference year 2000 based upon about 3 million measurements of surface water pCO 2 obtained from 1970 to 2007. The database used for this study is about 3 times larger than the 0.94 million used for our earlier paper [Takahashi et al., 2002. Global sea-air CO 2 flux based on climatological surface ocean pCO 2, and seasonal biological and temperature effects. Deep-Sea Res. II, 49, 1601-1622]. A time-trend analysis using deseasonalized surface water pCO 2 data in portions of the North Atlantic, North and South Pacific and Southern Oceans (which cover about 27% of the global ocean areas) indicates that the surface water pCO 2 over these oceanic areas has increased on average at a mean rate of 1.5 μatm y -1 with basin-specific rates varying between 1.2±0.5 and 2.1±0.4 μatm y -1. A global ocean database for a single reference year 2000 is assembled using this mean rate for correcting observations made in different years to the reference year. The observations made during El Niño periods in the equatorial Pacific and those made in coastal zones are excluded from the database. Seasonal changes in the surface water pCO 2 and the sea-air pCO 2 difference over four climatic zones in the Atlantic, Pacific, Indian and Southern Oceans are presented. Over the Southern Ocean seasonal ice zone, the seasonality is complex. Although it cannot be thoroughly documented due to the limited extent of observations, seasonal changes in pCO 2 are approximated by using the data for under-ice waters during austral winter and those for the marginal ice and ice-free zones. The net air-sea CO 2 flux is estimated using the sea-air pCO 2 difference and the air-sea gas transfer rate that is parameterized as a function of (wind speed) 2 with a scaling factor of 0.26. This is estimated by inverting

  6. Urban leakage of liquefied petroleum gas and its impact on Mexico City air quality

    SciTech Connect

    Blake, D.R.; Rowland, F.S.

    1995-08-18

    Alkane hydrocarbons (propane, isobutane, and n-butane) from liquefied petroleum gas (LPG) are present in major quantities throughout Mexico City air because of leakage of the unburned gas from numerous urban sources. These hydrocarbons, together with olefinic minor LPG components, furnish substantial amounts of hydroxyl radical reactivity, a major precursor to formation of the ozone component of urban smog. The combined processes of unburned leakage and incomplete combustion of LPG play significant role in causing the excessive ozone characteristic of Mexico City. Reductions in ozone levels should be possible through changes in LPG composition and lowered rates of leakage. 23 refs., 3 tabs.

  7. Environmental influences of oil and gas development in the Arctic Slope and Beaufort Sea

    USGS Publications Warehouse

    Brooks, J.W.; Bartonek, J.C.; Klein, D.R.; Spencer, D.

    1971-01-01

    This report describes the environmental characteristics and renewable resources of the Arctic Slope and the Beaufort Sea in relation to oil and gas development. Problems associated with industrial activities are identified, and recommendations for avoiding or minimizing environmental and resource damage are advanced. It is noted that the simplicity of the ecosystems, the slow rate of organic processes, and the presence of permafrost create unique problems in connection with pollution, waste disposal, restoration of vegetation, and all activities which disturb the vegetated surface. In the Beaufort Sea, the shallowness of the continental shelf and the presence of pack ice represent serious physical obstacles to oil development and transportation and heighten the probability of potentially harmful accidents. The risk of serious environmental and resource damage in the Arctic will be greatly lessened by the imposition of high operational and safety standards. There is need for strengthening legal authority to promulgate essential regulations. As an interim substitute, close and effective cooperation between Government and industry must be developed. Both Government and industry have an obligation to support research aimed at providing an adequate understanding of numerous environmental and technical questions.

  8. Sea-level-- and gas-hydrate-controlled catastrophic sediment failures on the Amazon Fan

    SciTech Connect

    Maslin, M.; Mikkelsen, N.; Vilela, C.; Haq, B.

    1998-12-01

    The architecture and Quaternary history of the massive and highly structured Amazon Fan has been reconstructed using sediment recovered by Ocean Drilling Program Leg 155. Huge regional mass-transport deposits make up a significant component of the Amazon Fan. These massive mass-transport deposits each cover an area over 15,000 km{sup 2} (approximately the size of Jamaica), reach a maximum thickness of 200 m, and consist of {approx}50,000 Gt of sediment. Analysis of both benthic foraminiferal fauna and the sediments indicates that the mass-transport deposits originated at a water depth of between 200 and 600 m on the continental slope, which is at least 200 km lateral to and 1500 m above their present position. Each mass-failure event was formed by the catastrophic failure of the continental slope and has been dated and correlated with climate-induced changes in sea level. Two different mechanisms initiated these catastrophic slumps: (1) Rapid drops in sea level destabilized continental slope gas hydrate reservoirs, causing slope failure and the glacial mass-transport deposits, and (2) deglaciation of the Andes and the consequent flushing of Amazon River sediment to the continental slope caused over-burdening and the deglacial mass-transport deposits.

  9. The impact of shipping emissions on air pollution in the greater North Sea region - Part 1: Current emissions and concentrations

    NASA Astrophysics Data System (ADS)

    Aulinger, A.; Matthias, V.; Zeretzke, M.; Bieser, J.; Quante, M.; Backes, A.

    2016-01-01

    The North Sea is one of the areas with the highest ship traffic densities worldwide. At any time, about 3000 ships are sailing its waterways. Previous scientific publications have shown that ships contribute significantly to atmospheric concentrations of NOx, particulate matter and ozone. Especially in the case of particulate matter and ozone, this influence can even be seen in regions far away from the main shipping routes. In order to quantify the effects of North Sea shipping on air quality in its bordering states, it is essential to determine the emissions from shipping as accurately as possible. Within Interreg IVb project Clean North Sea Shipping (CNSS), a bottom-up approach was developed and used to thoroughly compile such an emission inventory for 2011 that served as the base year for the current emission situation. The innovative aspect of this approach was to use load-dependent functions to calculate emissions from the ships' current activities instead of averaged emission factors for the entire range of the engine loads. These functions were applied to ship activities that were derived from hourly records of Automatic Identification System signals together with a database containing the engine characteristics of the vessels that traveled the North Sea in 2011. The emission model yielded ship emissions among others of NOx and SO2 at high temporal and spatial resolution that were subsequently used in a chemistry transport model in order to simulate the impact of the emissions on pollutant concentration levels. The total emissions of nitrogen reached 540 Gg and those of sulfur oxides 123 Gg within the North Sea - including the adjacent western part of the Baltic Sea until 5° W. This was about twice as much of those of a medium-sized industrialized European state like the Netherlands. The relative contribution of ships to, for example, NO2 concentration levels ashore close to the sea can reach up to 25 % in summer and 15 % in winter. Some hundred kilometers

  10. Estimating Riverine Air-Water Gas Exchange and Metabolism from Long Oxygen Time Series

    NASA Astrophysics Data System (ADS)

    Hall, R. O., Jr.; Appling, A.; Yackulic, C. B.; Arroita, M.

    2015-12-01

    To accurately depict the role of streams and rivers in carbon cycling requires estimating air- water gas exchange, productivity, and respiration. It is possible to estimate gas exchange and metabolism (gross primary production and ecosystem respiration) simultaneously from oxygen data themselves, but estimates from any single day often contain a substantial (and unknown) amount of parameter error. Here we developed a statistical method to leverage the extra information in a long time series to better estimate daily rates of gas exchange and metabolism. Such time series are ubiquitous in water quality monitoring programs, and these data are readily available over broad spatial scales. We developed a hierarchical model that estimates gas exchange as a function of discharge for a year-long time series of dissolved oxygen data. Gas exchange, and therefore metabolism, had much lower temporal variability than if we estimated parameters on separate days. Rates of gas exchange were positively related with discharge, but the relationship was river specific and often nonlinear. Our approach provides a robust means to estimate gas exchange and metabolism from the many rivers that have oxygen time series collected as part of water quality monitoring.

  11. Gas migration and carbon capture in one of the World's largest pockmark fields, the Norwegian Sea

    NASA Astrophysics Data System (ADS)

    Mazzini, A.; Svensen, H.; Planke, S.; Hammer, O.; Linge, H. C.; Forsberg, C. F.; Tjelta, T.

    2013-12-01

    Acoustic imaging has revealed more than 7000 pockmarks above the Troll East gas field in the Norwegian Sea. The pockmarks range in size from 10 to 100 meters in diameter and are typically 6 meters deep. High-resolution bathymetric data shows that there is no evidence of structural control on the location of the pockmarks. This conclusion is in agreement with statistical analysis of the pockmark distribution which shows neighbor avoidance up to a scale of hundreds of meters and no indication of a fractal geometry. The pockmarks generally represent isolated structures and sometimes are identified in clusters with a central parent pockmark surrounded by smaller sized satellite pockmarks. Seafloor observations show that carbonate deposits are common within the pockmarks, providing shelter to the local fauna. Carbonate blocks collected from the pockmarks showed evidence for three distinct generations including micritic Mg-calcite/aragonite, micritic aragonite, and botryoidal aragonite. The carbon isotopic values of these phases are 13C depleted and 18O enriched, indicating a methanogenic origin and possibly a component sourced from dissociation of gas hydrates. Water geochemistry from shallow cores within and outside the pockmarks gave no indication of active seepage. This conclusion is further supported by no direct observations of fluid flow within the pockmarks, no bacterial mats nor obvious chemosymbiotic communities. In addition, oxidized carbonate surfaces indicate a gradual excavation and exposure at the sea floor. We conclude that one of the world's largest pockmark fields is currently inactive and that its formation is likely related to deglaciation processes about 11 ky ago.

  12. Research on inert gas narcosis and air velocity effects on metabolic performance

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The effects of air velocity on metabolic performance are studied by using high forced airflow in a closed environment as a mechanism to control the concentration of volatile animal wastes. Air velocities between 100 and 200 ft/min are without significant effects on the metabolism of rats. At velocities of 200 ft/min and above, oxygen consumption and CO2 production as well as food consumption increase. In most instances, the changes are on the order of 5-10%. At the same time, the RQ for the animals increases slightly and generally correlates well with oxygen consumption and CO2 production. Experiments on the nature of inert gas narcosis show that halothane and methoxyflurane are rather potent inhibitors of the NADH:O2 oxidoreductase system in rats. These experiments suggest that the mechanism of inert gas narcosis is not mandatorily related to a membrane surface phenomenon.

  13. Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass

    SciTech Connect

    Anuar, S.H.; Keener, H.M.

    1995-12-31

    The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

  14. Air-sea interaction and formation of the Asian summer monsoon onset vortex over the Bay of Bengal

    NASA Astrophysics Data System (ADS)

    Wu, Guoxiong; Guan, Yue; Liu, Yimin; Yan, Jinghui; Mao, Jiangyu

    2012-01-01

    In spring over the southern Bay of Bengal (BOB), a vortex commonly develops, followed by the Asian summer monsoon onset. An analysis of relevant data and a case study reveals that the BOB monsoon onset vortex is formed as a consequence of air-sea interaction over BOB, which is modulated by Tibetan Plateau forcing and the land-sea thermal contrast over the South Asian area during the spring season. Tibetan Plateau forcing in spring generates a prevailing cold northwesterly over India in the lower troposphere. Strong surface sensible heating is then released, forming a prominent surface cyclone with a strong southwesterly along the coastal ocean in northwestern BOB. This southwesterly induces a local offshore current and upwelling, resulting in cold sea surface temperatures (SSTs). The southwesterly, together with the near-equatorial westerly, also results in a surface anticyclone with descending air over most of BOB and a cyclone with ascending air over the southern part of BOB. In the eastern part of central BOB, where sky is clear, surface wind is weak, and ocean mixed layer is shallow, intense solar radiation and low energy loss due to weak surface latent and sensible heat fluxes act onto a thin ocean layer, resulting in the development of a unique BOB warm pool in spring. Near the surface, water vapor is transferred from northern BOB and other regions to southeastern BOB, where surface sensible heating is relatively high. The atmospheric available potential energy is generated and converted to kinetic energy, thereby resulting in vortex formation. The vortex then intensifies and moves northward, where SST is higher and surface sensible heating is stronger. Meanwhile, the zonal-mean kinetic energy is converted to eddy kinetic energy in the area east of the vortex, and the vortex turns eastward. Eventually, southwesterly sweeps over eastern BOB and merges with the subtropical westerly, leading to the onset of the Asian summer monsoon.

  15. Effect of Sampling Depth on Air-Sea CO2 Flux Estimates in River-Stratified Arctic Coastal Waters

    NASA Astrophysics Data System (ADS)

    Miller, L. A.; Papakyriakou, T. N.

    2015-12-01

    In summer-time Arctic coastal waters that are strongly influenced by river run-off, extreme stratification severely limits wind mixing, making it difficult to effectively sample the surface 'mixed layer', which can be as shallow as 1 m, from a ship. During two expeditions in southwestern Hudson Bay, off the Nelson, Hayes, and Churchill River estuaries, we confirmed that sampling depth has a strong impact on estimates of 'surface' pCO2 and calculated air-sea CO2 fluxes. We determined pCO2 in samples collected from 5 m, using a typical underway system on the ship's seawater supply; from the 'surface' rosette bottle, which was generally between 1 and 3 m; and using a niskin bottle deployed at 1 m and just below the surface from a small boat away from the ship. Our samples confirmed that the error in pCO2 derived from typical ship-board versus small-boat sampling at a single station could be nearly 90 μatm, leading to errors in the calculated air-sea CO2 flux of more than 0.1 mmol/(m2s). Attempting to extrapolate such fluxes over the 6,000,000 km2 area of the Arctic shelves would generate an error approaching a gigamol CO2/s. Averaging the station data over a cruise still resulted in an error of nearly 50% in the total flux estimate. Our results have implications not only for the design and execution of expedition-based sampling, but also for placement of in-situ sensors. Particularly in polar waters, sensors are usually deployed on moorings, well below the surface, to avoid damage and destruction from drifting ice. However, to obtain accurate information on air-sea fluxes in these areas, it is necessary to deploy sensors on ice-capable buoys that can position the sensors in true 'surface' waters.

  16. The Influence of Tropical Air-Sea Interaction on the Climate Impact of Aerosols: A Hierarchical Modeling Approach

    NASA Astrophysics Data System (ADS)

    Hsieh, W. C.; Saravanan, R.; Chang, P.; Mahajan, S.

    2014-12-01

    In this study, we use a hierarchical modeling approach to investigate the influence of tropical air-sea feedbacks on climate impacts of aerosols in the Community Earth System Model (CESM). We construct four different models by coupling the atmospheric component of CESM, the Community Atmospheric Model (CAM), to four different ocean models: (i) the Data Ocean Model (DOM; prescribed SST), (i) Slab Ocean Model (SOM; thermodynamic coupling), (iii) Reduced Gravity Ocean Model (RGOM; dynamic coupling), and (iv) the Parallel Ocean Program (POP; full ocean model). These four models represent progressively increasing degree of coupling between the atmosphere and the ocean. The RGOM model, in particular, is tuned to produce a good simulation of ENSO and the associated tropical air-sea interaction, without being impacted by the climate drifts exhibited by fully-coupled GCMs. For each method of coupling, a pair of numerical experiments, including present day (year 2000) and preindustrial (year 1850) sulfate aerosol loading, were carried out. Our results indicate that the inclusion of air-sea interaction has large impacts on the spatial structure of the climate response induced by aerosols. In response to sulfate aerosol forcing, ITCZ shifts southwards as a result of the anomalous clockwise MMC change which transports moisture southwardly across the Equator. We present analyses of the regional response to sulfate aerosol forcing in the equatorial Pacific as well as the zonally-averaged response. The decomposition of the change in the net surface energy flux shows the most dominant terms are net shortwave radiative flux at the surface and latent heat flux. Further analyses show all ocean model simulations simulate a positive change of northward atmospheric energy transport across the Equator in response to the perturbed radiative sulfate forcing. This positive northward atmospheric energy transport change plays a role in compensating partially cooling caused by sulfate aerosols.

  17. 76 FR 53481 - Outer Continental Shelf, Alaska OCS Region, Chukchi Sea Planning Area, Oil and Gas Lease Sale 193

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-26

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF THE INTERIOR Bureau of Ocean Energy Management, Regulation and Enforcement Outer Continental Shelf, Alaska OCS Region... Continental Shelf (OCS) Oil and Gas Lease Sale 193, Chukchi Sea, Alaska (OCS EIS/EA BOEMRE 2011-041)....

  18. 78 FR 59715 - Outer Continental Shelf (OCS), Alaska OCS Region, Chukchi Sea Planning Area, Proposed Oil and Gas...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-27

    ... Bureau of Ocean Energy Management Outer Continental Shelf (OCS), Alaska OCS Region, Chukchi Sea Planning Area, Proposed Oil and Gas Lease Sale 237 AGENCY: Bureau of Ocean Energy Management (BOEM), Interior... later than November 12, 2013. FOR FURTHER INFORMATION CONTACT: Michael S. Rolland, Chief,...

  19. Volatile garlic odor components: gas phases and adsorbed exhaled air analysed by headspace gas chromatography-mass spectrometry.

    PubMed

    Laakso, I; Seppänen-Laakso, T; Hiltunen, R; Müller, B; Jansen, H; Knobloch, K

    1989-06-01

    Combined headspace gas chromatography-mass spectrometry (HSGC-MS) was used in the analysis of garlic volatile compounds. Twenty major components were identified in the gas phases enriched by fresh, sliced garlic cloves ( ALLIUM SATIVUM L, Allioceae, Liliidae). Suspended dry garlic powder and crushed garlic, incubated in vegetable oil, revealed a different pattern since mainly the amounts of di- and trisulfides were decreased. The considerable compositional differences found in the analyses for the gas phase of garlic cloves, kept in oil, are likely associated with the poor stability of allicin in a lipophilic environment; a marked increase in the amounts of 2-propene-1-thiol, acetic acid, and ethanol was observed in the gas phase, whereas trisulfides were present in traces only. The occurrence of 2-propene-1-thiol and diallyl disulfide, the two principal sulfur components in exhaled air, also may indicate a rapid degradation of most garlic volatile components probably caused by the enzymatically active human salivary or digestive system. PMID:17262412

  20. U.S. Air Quality and Health Benefits from Avoided Climate Change under Greenhouse Gas Mitigation.

    PubMed

    Garcia-Menendez, Fernando; Saari, Rebecca K; Monier, Erwan; Selin, Noelle E

    2015-07-01

    We evaluate the impact of climate change on U.S. air quality and health in 2050 and 2100 using a global modeling framework and integrated economic, climate, and air pollution projections. Three internally consistent socioeconomic scenarios are used to value health benefits of greenhouse gas mitigation policies specifically derived from slowing climate change. Our projections suggest that climate change, exclusive of changes in air pollutant emissions, can significantly impact ozone (O3) and fine particulate matter (PM2.5) pollution across the U.S. and increase associated health effects. Climate policy can substantially reduce these impacts, and climate-related air pollution health benefits alone can offset a significant fraction of mitigation costs. We find that in contrast to cobenefits from reductions to coemitted pollutants, the climate-induced air quality benefits of policy increase with time and are largest between 2050 and 2100. Our projections also suggest that increasing climate policy stringency beyond a certain degree may lead to diminishing returns relative to its cost. However, our results indicate that the air quality impacts of climate change are substantial and should be considered by cost-benefit climate policy analyses.

  1. U.S. Air Quality and Health Benefits from Avoided Climate Change under Greenhouse Gas Mitigation.

    PubMed

    Garcia-Menendez, Fernando; Saari, Rebecca K; Monier, Erwan; Selin, Noelle E

    2015-07-01

    We evaluate the impact of climate change on U.S. air quality and health in 2050 and 2100 using a global modeling framework and integrated economic, climate, and air pollution projections. Three internally consistent socioeconomic scenarios are used to value health benefits of greenhouse gas mitigation policies specifically derived from slowing climate change. Our projections suggest that climate change, exclusive of changes in air pollutant emissions, can significantly impact ozone (O3) and fine particulate matter (PM2.5) pollution across the U.S. and increase associated health effects. Climate policy can substantially reduce these impacts, and climate-related air pollution health benefits alone can offset a significant fraction of mitigation costs. We find that in contrast to cobenefits from reductions to coemitted pollutants, the climate-induced air quality benefits of policy increase with time and are largest between 2050 and 2100. Our projections also suggest that increasing climate policy stringency beyond a certain degree may lead to diminishing returns relative to its cost. However, our results indicate that the air quality impacts of climate change are substantial and should be considered by cost-benefit climate policy analyses. PMID:26053628

  2. Air-water gas exchange of chlorinated pesticides in four lakes spanning a 1,205 meter elevation range in the Canadian Rocky Mountains.

    PubMed

    Wilkinson, Andrew C; Kimpe, Lynda E; Blais, Jules M

    2005-01-01

    Concentrations of selected persistent organic pollutants (POPs) in air and water were measured from four lakes that transect the Canadian Rocky Mountains. These data were used in combination with wind velocity and temperature-adjusted Henry's law constants to estimate the direction and magnitude of chemical exchange across the air-water interface of these lakes. Bow Lake (1,975 m above sea level [masl]) was studied during the summers of 1998 through 2000; Donald (770 masl) was studied during the summer of 1999; Dixon Dam Lake (946 masl) and Kananaskis Lake (1,667 masl) were studied during the summer of 2000. Hexachlorobenzene (HCB) and dieldrin volatilized from Bow Lake in spring and summer of 1998 to 2000 at a rate of 0.92 +/-1.1 and 0.55+/-0.37 ng m(-2) d(-1), respectively. The alpha-endosulfan deposited to Bow Lake at a rate of 3.4+/-2.2 ng m(-2) d(-1). Direction of gas exchange for gamma-hexachlorocyclohexane (gamma-HCH) changed from net deposition in 1998 to net volatilization in 1999, partly because of a surge in y-HCH concentrations in the water at Bow Lake in 1999. Average gamma-HCH concentrations in air declined steadily over the three-year period, from 0.021 ng m(-3) in 1998, to 0.0023 ng m(-3) in 2000, and to volatilization in 1999 and 2000. Neither the concentrations of organochlorine compounds (OCs) in air and water, nor the direction and rate of air-water gas exchange correlate with temperature or elevation. In general, losses of pesticides by outflow were greater than the amount exchanged across the air-water interface in these lakes. PMID:15683168

  3. The Decompression Sickness and Venous Gas Emboli Consequences of Air Breaks During 100% Oxygen Prebreathe

    NASA Technical Reports Server (NTRS)

    Conkin, Johnny; Gernhardt, Michael L.; Powell, Michael R.

    2005-01-01

    Not enough is known about the increased risk of hypobaric decompression sickness (DCS) and production of venous (VGE) and arterial (AGE) gas emboli following an air break in an otherwise normal 100% resting oxygen (O2) prebreathe (PB), and certainly a break in PB when exercise is used to accelerate nitrogen (N2) elimination from the tissues. Current Aeromedical Flight Rules at the Johnson Space Center about additional PB payback times are untested, possibly too conservative, and therefore not optimized for operational use.

  4. The transfer of trace constituents across the air-sea interface

    SciTech Connect

    Businger, J.A.

    1994-12-31

    The study of the transfer of properties, and especially the transfer of trace constituents, has received considerable attention from the scientific community during the last 20 years or so. The author will highlight some relevant topics which include: the role of the molecular sublayer near the interface; the transfer of momentum from the atmosphere to the ocean; the energy budget of the sea surface and the cool skin; bubbles, sea spray, and whitecap coverage; the measurement of fluxes; and a global perspective.

  5. Estimating monthly-averaged air-sea transfers of heat and momentum using the bulk aerodynamic method

    NASA Technical Reports Server (NTRS)

    Esbensen, S. K.; Reynolds, R. W.

    1980-01-01

    Air-sea transfers of sensible heat, latent heat, and momentum are computed from twenty-five years of middle-latitude and subtropical ocean weather ship data in the North Atlantic and North Pacific using the bulk aerodynamic method. The results show that monthly-averaged wind speeds, temperatures, and humidities can be used to estimate the monthly-averaged sensible and latent heat fluxes computed from the bulk aerodynamic equations to within a relative error of approximately 10%. The estimate of monthly-averaged wind stress under the assumption of neutral stability are shown to be within approximately 5% of the monthly-averaged non-neutral values.

  6. Effects of the sniffing port air makeup in gas chromatography-olfactometry.

    PubMed

    Hanaoka, K; Sieffermann, J M; Giampaoli, P

    2000-06-01

    A time-intensity gas chromatography-olfactometry (GCO) apparatus was developed to study some aerodynamic parameters that may influence odor detection and intensity measurements by the subjects. The addition of humidified air at the elution place of the compounds is generally recommended for several reasons (essentially to prevent nasal mucosa dehydration and to improve chromatographic effluent carriage out of the column), but clues about these effects are yet to be published. This question is studied through two complementary experiments using synthetic solutions of 3-methyl-1-butanethiol, hexan-2-one, octanal, nonanal, furfural, citronellal, benzaldehyde, octan-1-ol, 2-phenylethyl acetate, guaiacol, 2-phenylethanol, and vanillin. This work demonstrates the need for an air makeup to increase odor detection frequency and intensity rating. With the conditions tested, a minimum makeup air flow rate of 50 L.min(-)(1) is necessary. On the contrary, humidification of the makeup is useless for the sniffers comfort and to improve the quantitative GCO results.

  7. Performance and evaluation of gas engine driven rooftop air conditioning equipment at the Willow Grove (PA) Naval Air Station

    SciTech Connect

    Armstrong, P.R.; Conover, D.R.

    1993-05-01

    In a field evaluation conducted for the US Department of Energy (DOE) Office of Federal Energy Management Program (FEMP), the Pacific Northwest Laboratory (PNL) examined the performance of a new US energy-related technology under the FEMP Test Bed Demonstration Program. The technology was a 15-ton natural gas engine driven roof top air conditioning unit. Two such units were installed on a naval retail building to provide space conditioning to the building. Under the Test Bed Demonstration Program, private and public sector interests are focused to support the installation and evaluation of new US technologies in the federal sector. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) with DOE were the American Gas Cooling Center, Philadelphia Electric Company, Thermo King Corporation, and the US Naval Air Station at Willow Grove, Pennsylvania. Equipment operating and service data as well as building interior and exterior conditions were secured for the 1992 cooling season. Based on a computer assessment of the building using standard weather data, a comparison was made with the energy and operating costs associated with the previous space conditioning system. Based on performance during the 1992 cooling season and adjusted to a normal weather year, the technology will save the site $6,000/yr in purchased energy costs. An additional $9,000 in savings due to electricity demand ratchet charge reductions will also be realized. Detailed information on the technology, the installation, and the results of the technology test are provided to illustrate the advantages to the federal sector of using this technology. A history of the CRADA development process is also reported.

  8. Common versus noble Bacillus subtilis differentially responds to air and argon gas plasma.

    PubMed

    Winter, Theresa; Bernhardt, Jörg; Winter, Jörn; Mäder, Ulrike; Schlüter, Rabea; Weltmann, Klaus-Dieter; Hecker, Michael; Kusch, Harald

    2013-09-01

    The applications of low-temperature plasma are not only confined to decontamination and sterilization but are also found in the medical field in terms of wound and skin treatment. For the improvement of already established and also for new plasma techniques, in-depth knowledge on the interactions between plasma and microorganism is essential. In an initial study, the interaction between growing Bacillus subtilis and argon plasma was investigated by using a growth chamber system suitable for low-temperature gas plasma treatment of bacteria in liquid medium. In this follow-up investigation, a second kind of plasma treatment-namely air plasma-was applied. With combined proteomic and transcriptomic analyses, we were able to investigate the plasma-specific stress response of B. subtilis toward not only argon but also air plasma. Besides an overlap of cellular responses due to both argon and air plasma treatment (DNA damage and oxidative stress), a variety of gas-dependent cellular responses such as growth retardation and morphological changes were observed. Only argon plasma treatments lead to a phosphate starvation response whereas air plasma induced the tryptophan operon implying damage by photooxidation. Biological findings were supported by the detection of reactive plasma species by optical emission spectroscopy and Fourier transformed infrared spectroscopy measurements.

  9. Common versus noble Bacillus subtilis differentially responds to air and argon gas plasma.

    PubMed

    Winter, Theresa; Bernhardt, Jörg; Winter, Jörn; Mäder, Ulrike; Schlüter, Rabea; Weltmann, Klaus-Dieter; Hecker, Michael; Kusch, Harald

    2013-09-01

    The applications of low-temperature plasma are not only confined to decontamination and sterilization but are also found in the medical field in terms of wound and skin treatment. For the improvement of already established and also for new plasma techniques, in-depth knowledge on the interactions between plasma and microorganism is essential. In an initial study, the interaction between growing Bacillus subtilis and argon plasma was investigated by using a growth chamber system suitable for low-temperature gas plasma treatment of bacteria in liquid medium. In this follow-up investigation, a second kind of plasma treatment-namely air plasma-was applied. With combined proteomic and transcriptomic analyses, we were able to investigate the plasma-specific stress response of B. subtilis toward not only argon but also air plasma. Besides an overlap of cellular responses due to both argon and air plasma treatment (DNA damage and oxidative stress), a variety of gas-dependent cellular responses such as growth retardation and morphological changes were observed. Only argon plasma treatments lead to a phosphate starvation response whereas air plasma induced the tryptophan operon implying damage by photooxidation. Biological findings were supported by the detection of reactive plasma species by optical emission spectroscopy and Fourier transformed infrared spectroscopy measurements. PMID:23794223

  10. Effect of isobaric breathing gas shifts from air to heliox mixtures on resolution of air bubbles in lipid and aqueous tissues of recompressed rats.

    PubMed

    Hyldegaard, O; Kerem, D; Melamed, Y

    2011-09-01

    Deep tissue isobaric counterdiffusion that may cause unwanted bubble formation or transient bubble growth has been referred to in theoretical models and demonstrated by intravascular gas formation in animals, when changing inert breathing gas from nitrogen to helium after hyperbaric air breathing. We visually followed the in vivo resolution of extravascular air bubbles injected at 101 kPa into nitrogen supersaturated rat tissues: adipose, spinal white matter, skeletal muscle or tail tendon. Bubbles were observed during isobaric breathing-gas shifts from air to normoxic (80:20) heliox mixture while at 285 kPa or following immediate recompression to either 285 or 405 kPa, breathing 80:20 and 50:50 heliox mixtures. During the isobaric shifts, some bubbles in adipose tissue grew marginally for 10-30 min, subsequently they shrank and disappeared at a rate similar to or faster than during air breathing. No such bubble growth was observed in spinal white matter, skeletal muscle or tendon. In spinal white matter, an immediate breathing gas shift after the hyperbaric air exposure from air to both (80:20) and (50:50) heliox, coincident with recompression to either 285 or 405 kPa, caused consistent shrinkage of all air bubbles, until they disappeared from view. Deep tissue isobaric counterdiffusion may cause some air bubbles to grow transiently in adipose tissue. The effect is marginal and of no clinical consequence. Bubble disappearance rate is faster with heliox breathing mixtures as compared to air. We see no reason for reservations in the use of heliox breathing during treatment of air-diving-induced decompression sickness.

  11. Effect of isobaric breathing gas shifts from air to heliox mixtures on resolution of air bubbles in lipid and aqueous tissues of recompressed rats.

    PubMed

    Hyldegaard, O; Kerem, D; Melamed, Y

    2011-09-01

    Deep tissue isobaric counterdiffusion that may cause unwanted bubble formation or transient bubble growth has been referred to in theoretical models and demonstrated by intravascular gas formation in animals, when changing inert breathing gas from nitrogen to helium after hyperbaric air breathing. We visually followed the in vivo resolution of extravascular air bubbles injected at 101 kPa into nitrogen supersaturated rat tissues: adipose, spinal white matter, skeletal muscle or tail tendon. Bubbles were observed during isobaric breathing-gas shifts from air to normoxic (80:20) heliox mixture while at 285 kPa or following immediate recompression to either 285 or 405 kPa, breathing 80:20 and 50:50 heliox mixtures. During the isobaric shifts, some bubbles in adipose tissue grew marginally for 10-30 min, subsequently they shrank and disappeared at a rate similar to or faster than during air breathing. No such bubble growth was observed in spinal white matter, skeletal muscle or tendon. In spinal white matter, an immediate breathing gas shift after the hyperbaric air exposure from air to both (80:20) and (50:50) heliox, coincident with recompression to either 285 or 405 kPa, caused consistent shrinkage of all air bubbles, until they disappeared from view. Deep tissue isobaric counterdiffusion may cause some air bubbles to grow transiently in adipose tissue. The effect is marginal and of no clinical consequence. Bubble disappearance rate is faster with heliox breathing mixtures as compared to air. We see no reason for reservations in the use of heliox breathing during treatment of air-diving-induced decompression sickness. PMID:21318313

  12. Co-benefits of Global Greenhouse Gas Mitigation for Future Air Quality and Human Health.

    PubMed

    West, J Jason; Smith, Steven J; Silva, Raquel A; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zachariah; Fry, Meridith M; Anenberg, Susan; Horowitz, Larry W; Lamarque, Jean-Francois

    2013-10-01

    Actions to reduce greenhouse gas (GHG) emissions often reduce co-emitted air pollutants, bringing co-benefits for air quality and human health. Past studies(1-6) typically evaluated near-term and local co-benefits, neglecting the long-range transport of air pollutants(7-9), long-term demographic changes, and the influence of climate change on air quality(10-12). Here we simulate the co-benefits of global GHG reductions on air quality and human health using a global atmospheric model and consistent future scenarios, via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. We use new relationships between chronic mortality and exposure to fine particulate matter(13) and ozone(14), global modeling methods(15), and new future scenarios(16). Relative to a reference scenario, global GHG mitigation avoids 0.5±0.2, 1.3±0.5, and 2.2±0.8 million premature deaths in 2030, 2050, and 2100. Global average marginal co-benefits of avoided mortality are $50-380 (ton CO2)(-1), which exceed previous estimates, exceed marginal abatement costs in 2030 and 2050, and are within the low range of costs in 2100. East Asian co-benefits are 10-70 times the marginal cost in 2030. Air quality and health co-benefits, especially as they are mainly local and near-term, provide strong additional motivation for transitioning to a low-carbon future.

  13. Co-benefits of Global Greenhouse Gas Mitigation for Future Air Quality and Human Health.

    PubMed

    West, J Jason; Smith, Steven J; Silva, Raquel A; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zachariah; Fry, Meridith M; Anenberg, Susan; Horowitz, Larry W; Lamarque, Jean-Francois

    2013-10-01

    Actions to reduce greenhouse gas (GHG) emissions often reduce co-emitted air pollutants, bringing co-benefits for air quality and human health. Past studies(1-6) typically evaluated near-term and local co-benefits, neglecting the long-range transport of air pollutants(7-9), long-term demographic changes, and the influence of climate change on air quality(10-12). Here we simulate the co-benefits of global GHG reductions on air quality and human health using a global atmospheric model and consistent future scenarios, via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. We use new relationships between chronic mortality and exposure to fine particulate matter(13) and ozone(14), global modeling methods(15), and new future scenarios(16). Relative to a reference scenario, global GHG mitigation avoids 0.5±0.2, 1.3±0.5, and 2.2±0.8 million premature deaths in 2030, 2050, and 2100. Global average marginal co-benefits of avoided mortality are $50-380 (ton CO2)(-1), which exceed previous estimates, exceed marginal abatement costs in 2030 and 2050, and are within the low range of costs in 2100. East Asian co-benefits are 10-70 times the marginal cost in 2030. Air quality and health co-benefits, especially as they are mainly local and near-term, provide strong additional motivation for transitioning to a low-carbon future. PMID:24926321

  14. The role of soil air composition for noble gas tracer applications in tropical groundwater

    NASA Astrophysics Data System (ADS)

    Mayer, Simon; Jenner, Florian; Aeschbach, Werner; Weissbach, Therese; Peregovich, Bernhard; Machado, Carlos

    2016-04-01

    Dissolved noble gases (NGs) in groundwater provide a well-established tool for paleo temperature reconstruction. However, reliable noble gas temperature (NGT) determination needs appropriate assumptions or rather an exact knowledge of soil air composition. Deviations of soil air NG partial pressures from atmospheric values have already been found in mid latitudes during summer time as a consequence of subsurface oxygen depletion. This effect depends on ambient temperature and humidity and is thus expected to be especially strong in humid tropical soils, which was not investigated so far. We therefore studied NGs in soil air and shallow groundwater near Santarém (Pará, Brazil) at the end of the rainy and dry seasons, respectively. Soil air data confirms a correlation between NG partial pressures, the sum value of O2+CO2 and soil moisture contents. During the rainy season, we find significant NG enhancements in soil air by up to 7% with respect to the atmosphere. This is twice as much as observed during the dry season. Groundwater samples show neon excess values between 15% and 120%. Nearly all wells show no seasonal variations of excess air, even though the local river level seasonally fluctuates by about 8 m. Assuming atmospheric NG contents in soil air, fitted NGTs underestimate the measured groundwater temperature by about 1-2° C. However, including enhanced soil air NG contents as observed during the rainy season, resulting NGTs are in good agreement with local groundwater temperatures. Our presented data allows for a better understanding of subsurface NG variations. This is essential with regard to NG tracer applications in humid tropical areas, for which reliable paleoclimate data is of major importance for modern climate research.

  15. CLIVAR-GSOP/GODAE Ocean Synthesis Inter-Comparison of Global Air-Sea Fluxes From Ocean and Coupled Reanalyses

    NASA Astrophysics Data System (ADS)

    Valdivieso, Maria

    2014-05-01

    The GODAE OceanView and CLIVAR-GSOP ocean synthesis program has been assessing the degree of consistency between global air-sea flux data sets obtained from ocean or coupled reanalyses (Valdivieso et al., 2014). So far, fifteen global air-sea heat flux products obtained from ocean or coupled reanalyses have been examined: seven are from low-resolution ocean reanalyses (BOM PEODAS, ECMWF ORAS4, JMA/MRI MOVEG2, JMA/MRI MOVECORE, Hamburg Univ. GECCO2, JPL ECCOv4, and NCEP GODAS), five are from eddy-permitting ocean reanalyses developed as part of the EU GMES MyOcean program (Mercator GLORYS2v1, Reading Univ. UR025.3, UR025.4, UKMO GloSea5, and CMCC C-GLORS), and the remaining three are couple reanalyses based on coupled climate models (JMA/MRI MOVE-C, GFDL ECDA and NCEP CFSR). The global heat closure in the products over the period 1993-2009 spanned by all data sets is presented in comparison with observational and atmospheric reanalysis estimates. Then, global maps of ensemble spread in the seasonal cycle, and of the Signal to Noise Ratio of interannual flux variability over the 17-yr common period are shown to illustrate the consistency between the products. We have also studied regional variability in the products, particularly at the OceanSITES project locations (such as, for instance, the TAO/TRITON and PIRATA arrays in the Tropical Pacific and Atlantic, respectively). Comparisons are being made with other products such as OAFlux latent and sensible heat fluxes (Yu et al., 2008) combined with ISCCP satellite-based radiation (Zhang et al., 2004), the ship-based NOC2.0 product (Berry and Kent, 2009), the Large and Yeager (2009) hybrid flux dataset CORE.2, and two atmospheric reanalysis products, the ECMWF ERA-Interim reanalysis (referred to as ERAi, Dee et al., 2011) and the NCEP/DOE reanalysis R2 (referred to as NCEP-R2, Kanamitsu et al., 2002). Preliminary comparisons with the observational flux products from OceanSITES are also underway. References Berry, D

  16. Psychromonas ingrahamii sp. nov., a novel gas vacuolate, psychrophilic bacterium isolated from Arctic polar sea ice.

    PubMed

    Auman, Ann J; Breezee, Jennifer L; Gosink, John J; Kämpfer, Peter; Staley, James T

    2006-05-01

    A gas vacuolate bacterium, designated strain 37T, was isolated from a sea ice core collected from Point Barrow, Alaska, USA. Cells of strain 37T were large (6-14 microm in length), rod-shaped, contained gas vacuoles of two distinct morphologies, and grew well at NaCl concentrations of 1-10 % and at temperatures of -12 to 10 degrees C. The DNA G+C content was 40 mol%. Whole-cell fatty acid analysis showed that 16 : 1omega7c comprised 67 % of the total fatty acid content. Phylogenetic analysis of 16S rRNA gene sequences indicated that this bacterium was closely related to members of the genus Psychromonas, with highest sequence similarity (96.8 %) to Psychromonas antarctica. Phenotypic analysis differentiated strain 37T from P. antarctica on the basis of several characteristics, including cell morphology, growth temperature range and the ability to hydrolyse polymers. DNA-DNA hybridization experiments revealed a level of relatedness of 37 % between strain 37T and P. antarctica, providing further support that it represents a distinct species. The name Psychromonas ingrahamii sp. nov. is proposed for this novel species. The type strain is 37T (=CCUG 51855T=CIP 108865T).

  17. Impact of natural gas extraction on Pah levels in ambient air

    PubMed Central

    Paulik, L. Blair; Donald, Carey E.; Smith, Brian W.; Tidwell, Lane G.; Hobbie, Kevin A.; Kincl, Laurel; Haynes, Erin N.; Anderson, Kim A.

    2015-01-01

    Natural gas extraction, often referred to as “fracking,” has increased rapidly in the U.S. in recent years. To address potential health impacts, passive air samplers were deployed in a rural community heavily affected by the natural gas boom. Samplers were analyzed for 62 polycyclic aromatic hydrocarbons (PAHs). Results were grouped based on distance from each sampler to the nearest active well. PAH levels were highest when samplers were closest to active wells. Additionally, PAH levels closest to natural gas activity were an order of magnitude higher than levels previously reported in rural areas. Sourcing ratios indicate that PAHs were predominantly petrogenic, suggesting that elevated PAH levels were influenced by direct releases from the earth. Quantitative human health risk assessment estimated the excess lifetime cancer risks associated with exposure to the measured PAHs. Closest to active wells, the risk estimated for maximum residential exposure was 2.9 in 10,000, which is above the U.S. EPA's acceptable risk level. Overall, risk estimates decreased 30% when comparing results from samplers closest to active wells to those farthest. This work suggests that natural gas extraction may be contributing significantly to PAHs in air, at levels that are relevant to human health. PMID:25810398

  18. Impact of natural gas extraction on PAH levels in ambient air.

    PubMed

    Paulik, L Blair; Donald, Carey E; Smith, Brian W; Tidwell, Lane G; Hobbie, Kevin A; Kincl, Laurel; Haynes, Erin N; Anderson, Kim A

    2015-04-21

    Natural gas extraction, often referred to as "fracking," has increased rapidly in the U.S. in recent years. To address potential health impacts, passive air samplers were deployed in a rural community heavily affected by the natural gas boom. Samplers were analyzed for 62 polycyclic aromatic hydrocarbons (PAHs). Results were grouped based on distance from each sampler to the nearest active well. PAH levels were highest when samplers were closest to active wells. Additionally, PAH levels closest to natural gas activity were an order of magnitude higher than levels previously reported in rural areas. Sourcing ratios indicate that PAHs were predominantly petrogenic, suggesting that elevated PAH levels were influenced by direct releases from the earth. Quantitative human health risk assessment estimated the excess lifetime cancer risks associated with exposure to the measured PAHs. Closest to active wells, the risk estimated for maximum residential exposure was 2.9 in 10 000, which is above the U.S. EPA's acceptable risk level. Overall, risk estimates decreased 30% when comparing results from samplers closest to active wells to those farthest. This work suggests that natural gas extraction may be contributing significantly to PAHs in air, at levels that are relevant to human health. PMID:25810398

  19. Emissions of Polycyclic Aromatic Hydrocarbons from Natural Gas Extraction into Air.

    PubMed

    Paulik, L Blair; Donald, Carey E; Smith, Brian W; Tidwell, Lane G; Hobbie, Kevin A; Kincl, Laurel; Haynes, Erin N; Anderson, Kim A

    2016-07-19

    Natural gas extraction, often referred to as "fracking", has increased rapidly in the United States in recent years. To address potential health impacts, passive air samplers were deployed in a rural community heavily affected by the natural gas boom. Samplers were analyzed for 62 polycyclic aromatic hydrocarbons (PAHs). Results were grouped based on distance from each sampler to the nearest active well. Levels of benzo[a]pyrene, phenanthrene, and carcinogenic potency of PAH mixtures were highest when samplers were closest to active wells. PAH levels closest to natural gas activity were comparable to levels previously reported in rural areas in winter. Sourcing ratios indicated that PAHs were predominantly petrogenic, suggesting that PAH levels were influenced by direct releases from the earth. Quantitative human health risk assessment estimated the excess lifetime cancer risks associated with exposure to the measured PAHs. At sites closest to active wells, the risk estimated for maximum residential exposure was 0.04 in a million, which is below the U.S. Environmental Protection Agency's acceptable risk level. Overall, risk estimates decreased 30% when comparing results from samplers closest to active wells to those farthest from them. This work suggests that natural gas extraction is contributing PAHs to the air, at levels that would not be expected to increase cancer risk. PMID:27400263

  20. Emissions of Polycyclic Aromatic Hydrocarbons from Natural Gas Extraction into Air.

    PubMed

    Paulik, L Blair; Donald, Carey E; Smith, Brian W; Tidwell, Lane G; Hobbie, Kevin A; Kincl, Laurel; Haynes, Erin N; Anderson, Kim A

    2016-07-19

    Natural gas extraction, often referred to as "fracking", has increased rapidly in the United States in recent years. To address potential health impacts, passive air samplers were deployed in a rural community heavily affected by the natural gas boom. Samplers were analyzed for 62 polycyclic aromatic hydrocarbons (PAHs). Results were grouped based on distance from each sampler to the nearest active well. Levels of benzo[a]pyrene, phenanthrene, and carcinogenic potency of PAH mixtures were highest when samplers were closest to active wells. PAH levels closest to natural gas activity were comparable to levels previously reported in rural areas in winter. Sourcing ratios indicated that PAHs were predominantly petrogenic, suggesting that PAH levels were influenced by direct releases from the earth. Quantitative human health risk assessment estimated the excess lifetime cancer risks associated with exposure to the measured PAHs. At sites closest to active wells, the risk estimated for maximum residential exposure was 0.04 in a million, which is below the U.S. Environmental Protection Agency's acceptable risk level. Overall, risk estimates decreased 30% when comparing results from samplers closest to active wells to those farthest from them. This work suggests that natural gas extraction is contributing PAHs to the air, at levels that would not be expected to increase cancer risk.

  1. Impact of natural gas extraction on PAH levels in ambient air.

    PubMed

    Paulik, L Blair; Donald, Carey E; Smith, Brian W; Tidwell, Lane G; Hobbie, Kevin A; Kincl, Laurel; Haynes, Erin N; Anderson, Kim A

    2015-04-21

    Natural gas extraction, often referred to as "fracking," has increased rapidly in the U.S. in recent years. To address potential health impacts, passive air samplers were deployed in a rural community heavily affected by the natural gas boom. Samplers were analyzed for 62 polycyclic aromatic hydrocarbons (PAHs). Results were grouped based on distance from each sampler to the nearest active well. PAH levels were highest when samplers were closest to active wells. Additionally, PAH levels closest to natural gas activity were an order of magnitude higher than levels previously reported in rural areas. Sourcing ratios indicate that PAHs were predominantly petrogenic, suggesting that elevated PAH levels were influenced by direct releases from the earth. Quantitative human health risk assessment estimated the excess lifetime cancer risks associated with exposure to the measured PAHs. Closest to active wells, the risk estimated for maximum residential exposure was 2.9 in 10 000, which is above the U.S. EPA's acceptable risk level. Overall, risk estimates decreased 30% when comparing results from samplers closest to active wells to those farthest. This work suggests that natural gas extraction may be contributing significantly to PAHs in air, at levels that are relevant to human health.

  2. Study of air-sea interaction processes over the Arabian Sea and the Bay of Bengal using satellite data

    SciTech Connect

    Gautam, N.; Simon, B.; Pandey, P.C.

    1995-12-01

    The main objective of this work is to study the latitudinal and seasonal variation of latent heat fluxes (LHF) and associated atmospheric and oceanic parameters over the Arabian Sea (AS) and the Bay of Bengal (BB) for the year 1988. A significant latitudinal variation is observed in LHF for most of the months over the AS and the BB, while other oceanic and atmospheric parameters are characterized by a strong latitudinal variation in nonmonsoon months. Seasonal variations in LHF are more significant at higher latitudes compared to lower latitudes over the AS and the BB. The effect of coastal upwelling near the Somali coast decreases LHF, while surface winds near the Indian coast during monsoon months increases LHF. A comparative study over the AS and the BB demonstrates higher PW and SST over the BB than over the AS. LHF is found to be greater over the AS than over the BB for nonmonsoon months. Correlation analysis indicates that LHF is found to be highly correlated with DQ (difference between the humidity at the surface and humidity near the surface) over the AS and weakly correlated over the BB during nonmonsoon months. Throughout the year, DQ is found to be a dominant factor for LHF over the AS. However, WS exercised better control over the BB in generating LHF. SST and PW are found to be highly correlated with each other over the AS (r = 0.87) and the BB (r = 0.75) for nonmonsoon months. The correlation becomes weakly negative over the AS (r = 0.15) and weak over the BB (r = 0.26) during monsoon months. Precipitable water is found to have a high correlation with WS over the AS (r = 0.72). This unique feature is revealed by SSM/I data and has not been reported earlier due to paucity of data over this region.

  3. Geothermal ground gas emissions and indoor air pollution in Rotorua, New Zealand.

    PubMed

    Durand, Michael; Scott, Bradley J

    2005-06-01

    The emission of toxic gases from the soil is a hazard in geothermal regions that are also urbanized because buildings constructed on geothermal ground may be subject to the ingress of gases from the soil directly into the structure. The Rotorua geothermal field, New Zealand, is extensively urbanized but to date no studies have evaluated the extent of the ground gas hazard. The main gases emitted are hydrogen sulphide (H2S) and carbon dioxide (CO2), both of which are highly toxic and denser than air. This paper reports preliminary findings from a study of selected buildings constructed in the gas anomaly area. Properties were investigated for evidence of ingress by H2S, CO2, and 222Rn, with a view to determine the means and rates of gas entry and the nature of any consequent hazard. H2S and CO2 were investigated using infrared active gas analysers and passive detector tubes left in place for 10-48 h. 222Rn was measured over a period of 3 months by poly-allyl diglycol carbonate sensors. Eight of the nine buildings studied were found to suffer problems with soil gases entering the indoor air through the structure. The primary means of gas entry was directly from the ground through the floors, walls, and subsurface pipes. Indoor vents were located and found emitting up to approximately 200 ppm H2S and approximately 15% CO2, concentrations high enough to present an acute respiratory hazard to persons close to the vent (e.g., children playing at floor level). In some properties, gas problems occurred despite preventative measures having been made during construction or during later renovations. Typically, these measures include the under-laying of concrete floors with a gas-proof butanol seal, under-floor ventilation systems or the installation of positive-pressure air conditioning. Recently constructed buildings (<10 years) with butanol seals were nevertheless affected by ground gas emissions, and we conclude that such measures are not always effective in the long term

  4. Evidence of injury caused by gas bubbles in a live marine mammal: barotrauma in a California sea lion Zalophus californianus.

    PubMed

    Van Bonn, W; Montie, E; Dennison, S; Pussini, N; Cook, P; Greig, D; Barakos, J; Colegrove, K; Gulland, F

    2011-09-01

    A yearling male California sea lion Zalophus californianus with hypermetric ataxia and bilateral negative menace reflexes was brought to The Marine Mammal Center, Sausalito, California, U.S.A., in late 2009 for medical assessment and treatment. The clinical signs were due to multiple gas bubbles within the cerebellum. These lesions were intraparenchymal, multifocal to coalescing, spherical to ovoid, and varied from 0.5 to 2.4 cm diameter. The gas composed 21.3% of the total cerebellum volume. Three rib fractures were also noted during diagnostic evaluation and were presumed to be associated with the gas bubbles in the brain. The progression of clinical signs and lesion appearance were monitored with magnetic resonance imaging, cognitive function testing and computed tomography. Gas filled voids in the cerebellum were filled with fluid on follow up images. Clinical signs resolved and the sea lion was released with a satellite tag attached. Post release the animal travelled approximately 75 km north and 80 km south of the release site and the tag recorded dives of over 150 m depth. The animal re-stranded 25 d following release and died of a subacute bronchopneumonia and pleuritis. This is the first instance of clinical injury due to gas bubble formation described in a living pinniped and the first sea lion with quantifiable cerebellar damage to take part in spatial learning and memory testing.

  5. Evidence of injury caused by gas bubbles in a live marine mammal: barotrauma in a California sea lion Zalophus californianus.

    PubMed

    Van Bonn, W; Montie, E; Dennison, S; Pussini, N; Cook, P; Greig, D; Barakos, J; Colegrove, K; Gulland, F

    2011-09-01

    A yearling male California sea lion Zalophus californianus with hypermetric ataxia and bilateral negative menace reflexes was brought to The Marine Mammal Center, Sausalito, California, U.S.A., in late 2009 for medical assessment and treatment. The clinical signs were due to multiple gas bubbles within the cerebellum. These lesions were intraparenchymal, multifocal to coalescing, spherical to ovoid, and varied from 0.5 to 2.4 cm diameter. The gas composed 21.3% of the total cerebellum volume. Three rib fractures were also noted during diagnostic evaluation and were presumed to be associated with the gas bubbles in the brain. The progression of clinical signs and lesion appearance were monitored with magnetic resonance imaging, cognitive function testing and computed tomography. Gas filled voids in the cerebellum were filled with fluid on follow up images. Clinical signs resolved and the sea lion was released with a satellite tag attached. Post release the animal travelled approximately 75 km north and 80 km south of the release site and the tag recorded dives of over 150 m depth. The animal re-stranded 25 d following release and died of a subacute bronchopneumonia and pleuritis. This is the first instance of clinical injury due to gas bubble formation described in a living pinniped and the first sea lion with quantifiable cerebellar damage to take part in spatial learning and memory testing. PMID:22013748

  6. Chemical kinetics with electrical and gas dynamics modelization for NOx removal in an air corona discharge

    NASA Astrophysics Data System (ADS)

    Eichwald, O.; Guntoro, N. A.; Yousfi, M.; Benhenni, M.

    2002-03-01

    A non-stationary reactive gas dynamics model in a mono-dimensional geometry, including radial mass diffusion, gas temperature variation and chemical kinetics, is developed in this paper. The aim is to analyse the spatio-temporal evolution of the main neutral species involved in a corona discharge used for NO pollution control in polluted air at atmospheric pressure and ambient temperature. The present reactive gas dynamics model takes into account 16 neutral chemical species (including certain metastable species) reacting following 110 selected chemical reactions. The initial concentration of each neutral species is obtained from a 1.5D electrical discharge model. The gas temperature variations are due to direct Joule heating during the discharge phase, and also result from the delayed heating due to the relaxation of the vibrational energy into a random thermal energy during the post-discharge phase. The simulation conditions are those of an existing experimental setup (anode voltage of 10 kV in the case of a point to plane geometry with an interelectrode distance of 10 mm). The obtained results show that the diffusion phenomena and the gas temperature rise affect quite well the gas reactivity and the neutral species evolution. This allows us to better understand the different reaction processes and transport phenomena affecting the NO concentration magnitude inside the discharge channel.

  7. The impact of shipping emissions on air pollution in the Greater North Sea region - Part 1: Current emissions and concentrations

    NASA Astrophysics Data System (ADS)

    Aulinger, A.; Matthias, V.; Zeretzke, M.; Bieser, J.; Quante, M.; Backes, A.

    2015-04-01

    The North Sea is one of the areas with the highest ship traffic densities worldwide. At any time, about 3000 ships are sailing its waterways. Previous scientific publications have shown that ships contribute significantly to atmospheric concentrations of NOx, particulate matter and ozone. Especially in the case of particulate matter and ozone this influence can even be seen in regions far away from the main shipping routes. In order to quantify the effects of North Sea shipping on air quality in its bordering states, it is essential to determine the emissions from shipping as accurately as possible. Within the Interreg IVb project Clean North Sea Shipping (CNSS) a bottom-up approach was developed and used to thoroughly compile such an emission inventory for 2011 that served as the base year for the current emission situation. The innovative aspect of this approach was to use load dependent functions to calculate emissions from the ships' current activities instead of averaged emission factors for the entire range of the engine loads. These functions were applied to ship activities that were derived from hourly records of Automatic Identification System signals together with a data base containing the engine characteristics of the vessels that traveled the North Sea in 2011. The emission model yielded ship emissions among others of NOx and SO2 in high temporal and spatial resolution that were subsequently used in a chemistry transport model in order to simulate the impact of the emissions on pollutant concentration levels. The total emissions of nitrogen reached 540 Gg and of sulfur oxides 123 Gg within the North Sea, which was about twice as much of those of a medium-sized industrialized European state like the Netherlands. The relative contribution of ships to, for example, NO2 concentration levels ashore close to the sea can reach up to 25% in summer and 15% in winter. Some hundred kilometers away from the sea the contribution was about 6% in summer and 4% in

  8. Problems in creation of modern air inlet filters of power gas turbine plants in Russia and methods of their solving

    NASA Astrophysics Data System (ADS)

    Mikhaylov, V. E.; Khomenok, L. A.; Sherapov, V. V.

    2016-08-01

    The main problems in creation and operation of modern air inlet paths of gas turbine plants installed as part of combined-cycle plants in Russia are presented. It is noted that design features of air inlet filters shall be formed at the stage of the technical assignment not only considering the requirements of gas turbine plant manufacturer but also climatic conditions, local atmospheric air dustiness, and a number of other factors. The recommendations on completing of filtration system for air inlet filter of power gas turbine plants depending on the facility location are given, specific defects in design and experience in operation of imported air inlet paths are analyzed, and influence of cycle air preparation quality for gas turbine plant on value of operating expenses and cost of repair works is noted. Air treatment equipment of various manufacturers, influence of aerodynamic characteristics on operation of air inlet filters, features of filtration system operation, anti-icing system, weather canopies, and other elements of air inlet paths are considered. It is shown that nonuniformity of air flow velocity fields in clean air chamber has a negative effect on capacity and aerodynamic resistance of air inlet filter. Besides, the necessity in installation of a sufficient number of differential pressure transmitters allowing controlling state of each treatment stage not being limited to one measurement of total differential pressure in the filtration system is noted in the article. According to the results of the analysis trends and methods for modernization of available equipment for air inlet path, the importance of creation and implementation of new technologies for manufacturing of filtering elements on sites of Russia within the limits of import substitution are given, and measures on reliability improvement and energy efficiency for air inlet filter are considered.

  9. Quantifying real-gas effects on a laminar n-dodecane - air premixed flame

    NASA Astrophysics Data System (ADS)

    Gopal, Abishek; Yellapantula, Shashank; Larsson, Johan

    2015-11-01

    With the increasing demand for higher efficiencies in aircraft gas-turbine engines, there has been a progressive march towards high pressure-ratio cycles. Under these conditions, the aviation fuel, Jet A, is injected into the combustor at supercritical pressures. In this work, we study and quantify the effects of transcriticality on a 1D freely propagating laminar n-dodecane - air premixed flame. The impact of the constitutive state relations arising from the Ideal Gas equation of state(EOS) and Peng-Robinson EOS on flame structure and propagation is presented. The effects of real-gas models of transport properties, such as viscosity on laminar flame speed, are also presented.

  10. Bio-inspired, efficient, artificial lung employing air as the ventilating gas.

    PubMed

    Potkay, Joseph A; Magnetta, Michael; Vinson, Abigail; Cmolik, Brian

    2011-09-01

    Artificial lungs have recently been utilized to rehabilitate patients suffering from lung diseases. However, significant advances in