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Sample records for air sea transect-pacific

  1. Annual sea ice. An air-sea gas exchange moderator

    SciTech Connect

    Gosink, T.A.; Kelley, J.J.

    1982-01-01

    Arctic annual sea ice, particularly when it is relatively warm (> -15/sup 0/C) permits significant gas exchange between the sea and air throughout the entire year. Sea ice, particularly annual sea ice, differs from freshwater ice with respect to its permeability to gases. The presence of brine allows for significant air-sea-ice exchange of CO/sub 2/ throughout the winter, which may significantly affect the global carbon dioxide balance. Other trace gases are also noted to be enriched in sea ice, but less is known about their importance to air-sea-interactions at this time. Both physical and biological factors cause and modify evolution of gases from the surface of sea ice. Quantitative and qualitative descriptions of the nature and physical behavior of sea ice with respect to brine and gases are discussed.

  2. Impact of Sea Spray on Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Veron, Fabrice; Mueller, James

    2013-11-01

    The contributions of sea spray drops to the total air-sea exchanges of momentum, heat, and mass remain an open question. A number of factors obscure any simple quantification of their contribution: the number of drops formed at the ocean surface and the per-drop contribution to the fluxes. To estimate these per-droplet fluxes, we present results from a large number of drop trajectories, which are simulated with a recently developed Lagrangian Stochastic model adapted for the heavy drop transport and evaporation within the marine boundary layer. Then, using commonly accepted spray generation functions we present estimates of spray fluxes which account for the mediating feedback effects from the droplets on the atmosphere. The results suggest that common simplifications in previous sea spray models, such as the residence time in the marine boundary layer, may not be appropriate. We further show that the spray fluxes may be especially sensitive to the size distribution of the drops. The total effective air-sea fluxes lead to drag and enthalpy coefficients that increase modestly with wind speed. The rate of increase for the drag coefficient is greatest at moderate wind speeds, while the rate of increase for the enthalpy coefficient is greatest at higher wind speeds. Funded by grants OCE-0850663 and OCE-0748767 from the National Science Foundation.

  3. Air and sea rescue via satellite systems

    NASA Astrophysics Data System (ADS)

    Scales, W. C.; Swanson, R.

    1984-03-01

    Two approaches to a satellite system for air and sea rescue to be put into use by the 1990s, one employing polar-orbiting satellites and the other using fixed geosynchronous satellites over the equator, are discussed. A battery-powered transmitter on a ship or aircraft would be activated in an accident to emit a low-power omnidirectional signal that would be relayed by a satellite to an earth station. The polar-orbiting approach, now being evaluated on a small-scale with the Cospas-Sarsat system, allows complete coverage of the earth, including the poles, and provides a fix on the origin of the distress signals by means of the Doppler shift. A parallel effort for the testing of geostationary satellites to measure system sensitivity to various interference sources, to optimize design, and to measure land and sea performance is reviewed.

  4. Joint Air Sea Interaction (JASIN) experiment, Northwest coast of Scotland

    NASA Technical Reports Server (NTRS)

    Businger, J. A.

    1981-01-01

    The joint air sea interaction (JASIN) experiment took place off the Northwest coast of Scotland. Sea surface and boundary layer parameters were measured. The JASIN data was used as ground truth for various sensors on the SEASAT satellite.

  5. In calm seas, precipitation drives air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Schultz, Colin

    2012-05-01

    In a series of experiments run in what resembles a heavily instrumented fish tank, Harrison et al. investigated the interwoven roles of wind and rain on air-sea gas exchange rates. Working with a 42-meterlong, 1-meter-wide, and 1.25-meter-tall experimental pool, the authors were able to control the wind speed, rainfall rate, water circulation speed, and other parameters, which they used to assess the effect of 24 different wind speed-rainfall rate combinations on the gas exchange rate of sulfur hexafuoride, a greenhouse gas. In trials that lasted up to 3 hours, the authors collected water samples from the tank at regular intervals, tracking the concentration of the dissolved gas.

  6. The potential role of sea spray droplets in facilitating air-sea gas transfer

    NASA Astrophysics Data System (ADS)

    Andreas, E. L.; Vlahos, P.; Monahan, E. C.

    2016-05-01

    For over 30 years, air-sea interaction specialists have been evaluating and parameterizing the role of whitecap bubbles in air-sea gas exchange. To our knowledge, no one, however, has studied the mirror image process of whether sea spray droplets can facilitate air-sea gas exchange. We are therefore using theory, data analysis, and numerical modeling to quantify the role of spray on air-sea gas transfer. In this, our first formal work on this subject, we seek the rate-limiting step in spray-mediated gas transfer by evaluating the three time scales that govern the exchange: τ air , which quantifies the rate of transfer between the atmospheric gas reservoir and the surface of the droplet; τ int , which quantifies the exchange rate across the air-droplet interface; and τ aq , which quantifies gas mixing within the aqueous solution droplet.

  7. Lasers as probes for air and sea

    NASA Astrophysics Data System (ADS)

    Svanberg, S.

    1980-12-01

    The rapid development of quantum electronics has permitted the introduction of efficient remote-sensing techniques for air and sea, based on applied laser spectroscopy. In this paper basic interactions between laser light and molecules are discussed as a background for a description of laser probing of the atmosphere and the hydrosphere. For the atmosphere both meteorological parameters and pollution levels can be measured. Long-path absorption and lidar (laser radar) techniques yield average or range-resolved values for several environmental parameters. Tropospheric and stratospheric measurements of particles and gaseous pollutants are described. Laser light can be used for marine probing within the blue-green optical window of water. Much of the effort in this field aims at the development of airborne measuring systems. Bathymetric experiments and the detection of schools of fish are discussed. Laser-induced fluorescence can be used for airborne monitoring of pollutants like mineral oils and pulp-mill wastes. Accurate laboratory measurements of spectral 'signatures' of different materials are important.

  8. Sea-air boundary meteorological sensor

    NASA Astrophysics Data System (ADS)

    Barbosa, Jose G.

    2015-05-01

    The atmospheric environment can significantly affect radio frequency and optical propagation. In the RF spectrum refraction and ducting can degrade or enhance communications and radar coverage. Platforms in or beneath refractive boundaries can exploit the benefits or suffer the effects of the atmospheric boundary layers. Evaporative ducts and surface-base ducts are of most concern for ocean surface platforms and evaporative ducts are almost always present along the sea-air interface. The atmospheric environment also degrades electro-optical systems resolution and visibility. The atmospheric environment has been proven not to be uniform and under heterogeneous conditions substantial propagation errors may be present for large distances from homogeneous models. An accurate and portable atmospheric sensor to profile the vertical index of refraction is needed for mission planning, post analysis, and in-situ performance assessment. The meteorological instrument used in conjunction with a radio frequency and electro-optical propagation prediction tactical decision aid tool would give military platforms, in real time, the ability to make assessments on communication systems propagation ranges, radar detection and vulnerability ranges, satellite communications vulnerability, laser range finder performance, and imaging system performance predictions. Raman lidar has been shown to be capable of measuring the required atmospheric parameters needed to profile the atmospheric environment. The atmospheric profile could then be used as input to a tactical decision aid tool to make propagation predictions.

  9. Atlantic Air-Sea Interaction Revisited

    NASA Astrophysics Data System (ADS)

    Rodwell, M. J.

    INTRODUCTION DATA AND MODELS THE ANALYSIS METHOD ATMOSPHERIC FORCING OF NORTH ATLANTIC SEA SURFACE TEMPERATURES NORTH ATLANTIC SEA SURFACE TEMPERATURE FORCING OF THE ATMOSPHERE Observational Evidence Model Results POTENTIAL SEASONAL PREDICTABILITY BASED ON THE ATMOSPHERE GENERAL - CIRCULATION MODEL CONCLUSIONS AND DISCUSSION REFERENCES

  10. Air-sea transfer of gas phase controlled compounds

    NASA Astrophysics Data System (ADS)

    Yang, M.; Bell, T. G.; Blomquist, B. W.; Fairall, C. W.; Brooks, I. M.; Nightingale, P. D.

    2016-05-01

    Gases in the atmosphere/ocean have solubility that spans several orders of magnitude. Resistance in the molecular sublayer on the waterside limits the air-sea exchange of sparingly soluble gases such as SF6 and CO2. In contrast, both aerodynamic and molecular diffusive resistances on the airside limit the exchange of highly soluble gases (as well as heat). Here we present direct measurements of air-sea methanol and acetone transfer from two open cruises: the Atlantic Meridional Transect in 2012 and the High Wind Gas Exchange Study in 2013. The transfer of the highly soluble methanol is essentially completely airside controlled, while the less soluble acetone is subject to both airside and waterside resistances. Both compounds were measured concurrently using a proton-transfer-reaction mass spectrometer, with their fluxes quantified by the eddy covariance method. Up to a wind speed of 15 m s-1, observed air-sea transfer velocities of these two gases are largely consistent with the expected near linear wind speed dependence. Measured acetone transfer velocity is ∼30% lower than that of methanol, which is primarily due to the lower solubility of acetone. From this difference we estimate the “zero bubble” waterside transfer velocity, which agrees fairly well with interfacial gas transfer velocities predicted by the COARE model. At wind speeds above 15 m s-1, the transfer velocities of both compounds are lower than expected in the mean. Air-sea transfer of sensible heat (also airside controlled) also appears to be reduced at wind speeds over 20 m s-1. During these conditions, large waves and abundant whitecaps generate large amounts of sea spray, which is predicted to alter heat transfer and could also affect the air-sea exchange of soluble trace gases. We make an order of magnitude estimate for the impacts of sea spray on air-sea methanol transfer.

  11. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    NASA Astrophysics Data System (ADS)

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-07-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change.

  12. Air-sea interactions during strong winter extratropical storms

    NASA Astrophysics Data System (ADS)

    Nelson, Jill; He, Ruoying; Warner, John C.; Bane, John

    2014-09-01

    A high-resolution, regional coupled atmosphere-ocean model is used to investigate strong air-sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air-sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air-sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere-ocean modeling framework.

  13. Air-sea interactions and precipitation over the tropical oceans

    NASA Technical Reports Server (NTRS)

    Gautier, C.

    1992-01-01

    In this lecture, the author principally discusses air-sea exchanges that are relevant to climate and global problems. The processes of interest are those acting over time scales of months to decades, which in some instances are influenced by smaller-time-scale processes, down to the diurnal time scale. The repsective influence of these processes varies with regions, seasons and scales over which they occur and, because these processes are mostly nonlinear, scale interactions can be quite complex. Owing to the breadth of the topic addressed, the discussion is mostly focused on the tropical regions where air-sea interactions and precipitation processes eventually affect the entire globe. This allows a look in more detail at some air-sea processes, such as those associated with the El Nino southern oscillation (ENSO). This oscillation, which affects the climate of the entire globe, acts over periods of a year or longer and is caused, primarily, by sea surface temperature (SST) variations in the tropical Pacific. As a result, SST variability is often used as an indicator of coupled ocean-atmosphere low-frequency variability. Global or basin scale processes can uniquely be observed from space-born instruments with the coverage required. Space based techniques have been developed during the last decade which can now be used to illustrate the scientific issues presented and the presentation concludes with an overview of some Earth Observing System (EOS) capabilities for addressing air-sea interactions and hydrology issues.

  14. Climatic impacts of stochastic fluctuations in air-sea fluxes

    NASA Astrophysics Data System (ADS)

    Williams, Paul D.

    2012-05-01

    Air-sea fluxes vary partly on scales that are too small or fast to be resolved explicitly by global climate models. This paper proposes a nonlinear physical mechanism by which stochastic fluctuations in the air-sea buoyancy flux may modify the mean climate. The paper then demonstrates the mechanism in climate simulations with a comprehensive coupled general circulation model. Significant changes are detected in the time-mean oceanic mixed-layer depth, sea-surface temperature, atmospheric Hadley circulation, and net upward water flux at the sea surface. Also, El Niño Southern Oscillation (ENSO) variability is significantly increased. The findings demonstrate that noise-induced drift and noise-enhanced variability, which are familiar concepts from simple climate models, continue to apply in comprehensive climate models with millions of degrees of freedom. The findings also suggest that the lack of representation of sub-grid variability in air-sea fluxes may contribute to some of the biases exhibited by contemporary climate models.

  15. Air-sea interaction with multiple sensors - Seasat legacy

    NASA Technical Reports Server (NTRS)

    Liu, W. T.; Tang, W.

    2003-01-01

    By flying a number of ocean observing sensors together, Seasat demonstrated potential of not only sensor synergism, but also science synergism, which has illuminated the path of spacebased air-sea interaction studies in more than two decades since its demise.

  16. NASA Wallops Flight Facility Air-Sea Interaction Research Facility

    NASA Technical Reports Server (NTRS)

    Long, Steven R.

    1992-01-01

    This publication serves as an introduction to the Air-Sea Interaction Research Facility at NASA/GSFC/Wallops Flight Facility. The purpose of this publication is to provide background information on the research facility itself, including capabilities, available instrumentation, the types of experiments already done, ongoing experiments, and future plans.

  17. Air-sea interactions during strong winter extratropical storms

    USGS Publications Warehouse

    Nelson, Jill; He, Ruoying; Warner, John C.; Bane, John

    2014-01-01

    A high-resolution, regional coupled atmosphere–ocean model is used to investigate strong air–sea interactions during a rapidly developing extratropical cyclone (ETC) off the east coast of the USA. In this two-way coupled system, surface momentum and heat fluxes derived from the Weather Research and Forecasting model and sea surface temperature (SST) from the Regional Ocean Modeling System are exchanged via the Model Coupling Toolkit. Comparisons are made between the modeled and observed wind velocity, sea level pressure, 10 m air temperature, and sea surface temperature time series, as well as a comparison between the model and one glider transect. Vertical profiles of modeled air temperature and winds in the marine atmospheric boundary layer and temperature variations in the upper ocean during a 3-day storm period are examined at various cross-shelf transects along the eastern seaboard. It is found that the air–sea interactions near the Gulf Stream are important for generating and sustaining the ETC. In particular, locally enhanced winds over a warm sea (relative to the land temperature) induce large surface heat fluxes which cool the upper ocean by up to 2 °C, mainly during the cold air outbreak period after the storm passage. Detailed heat budget analyses show the ocean-to-atmosphere heat flux dominates the upper ocean heat content variations. Results clearly show that dynamic air–sea interactions affecting momentum and buoyancy flux exchanges in ETCs need to be resolved accurately in a coupled atmosphere–ocean modeling framework.

  18. Atmospheric variability and air-sea interaction

    NASA Technical Reports Server (NTRS)

    Middleton, J. W.; Reiter, E. R.

    1980-01-01

    The topics studied include: (1) processing of Northern Hemispheric precipitation data, in order to fill in the transition seasons to provide a continuous 40 year data base on the variability of continental precipitation; (2) comparison of seasonally averaged fields of sea surface temperature obtained from ship observations in the North Atlantic and North Pacific in 1970 with the corresponding fields inferred from satellite observations; (3) estimation of seasonal average of total precipitable water at those admittedly few oceanic stations where repeated vertical soundings were made in 1970 and comparison with corresponding values inferred from satellite measurements; (4) comparison of seasonally averaged evaporation fields determined from ground based observations in 1970 with the field of divergence of the seasonal total horizontal water vapor flux inferred from satellite total water measurements and NMC wind data for the lower troposphere; (5) examination of meaning of convection-inversion index.

  19. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    USGS Publications Warehouse

    Hinckley, D.A.; Bidleman, T.F.; Rice, C.P.

    1991-01-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  20. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi seas

    NASA Astrophysics Data System (ADS)

    Hinckley, Daniel A.; Bidleman, Terry F.; Rice, Clifford P.

    1991-04-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for Organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average α-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average γ-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (α-HCH, average 79% saturation; γ-HCH, average 28% saturation). The flux for α-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of γ-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  1. Distribution and air-sea fluxes of carbon dioxide on the Chukchi Sea shelf

    NASA Astrophysics Data System (ADS)

    Pipko, I. I.; Pugach, S. P.; Repina, I. A.; Dudarev, O. V.; Charkin, A. N.; Semiletov, I. P.

    2015-12-01

    This article presents the results of long-term studies of the dynamics of carbonate parameters and air-sea carbon dioxide fluxes on the Chukchi Sea shelf during the summer. As a result of the interaction of physical and biological factors, the surface waters on the west of Chukchi Sea were undersaturated with carbon dioxide when compared with atmospheric air; the partial pressure of CO2 varied in the range from 134 to 359 μatm. The average value of CO2 flux in the Chukchi Sea per unit area varied in the range from-2.4 to-22.0 mmol /(m2 day), which is significantly higher than the average value of CO2 flux in the World Ocean. It has been estimated that the minimal mass of C absorbed by the surface of Chukchi Sea from the atmosphere during ice-free season is 13 × 1012 g; a great part of this carbon is transported to the deeper layers of sea and isolated from the atmosphere for a long period of time. The studies of the carbonate system of the Chukchi Sea, especially of its western part, will provide some new data on the fluxes of carbon dioxide in the Arctic Ocean and their changes. Our analysis can be used for an interpretation of the satellite assessment of CO2 fluxes and dissolved CO2 distribution in the upper layers of the ocean.

  2. Observational Buoy Studies of Coastal Air-Sea Fluxes.

    NASA Astrophysics Data System (ADS)

    Frederickson, Paul A.; Davidson, Kenneth L.

    2003-02-01

    Recent advancements in measurement and analysis techniques have allowed air-sea fluxes to be measured directly from moving platforms at sea relatively easily. These advances should lead to improved surface flux parameterizations, and thus to improved coupled atmosphere-ocean modeling. The Naval Postgraduate School has developed a `flux buoy' (FB) that directly measures air-sea fluxes, mean meteorological parameters, and one-dimensional and directional wave spectra. In this study, the FB instrumentation and data analysis techniques are described, and the data collected during two U.S. east coast buoy deployments are used to examine the impact of atmospheric and surface wave properties on air-sea momentum transfer in coastal ocean regions. Data obtained off Duck, North Carolina, clearly show that, for a given wind speed, neutral drag coefficients in offshore winds are higher than those in onshore winds. Offshore wind drag coefficients observed over the wind speed range from 5 to 21 m s1 were modeled equally well by a linear regression on wind speed, and a Charnock model with a constant of 0.016. Measurements from an FB deployment off Wallops Island, Virginia, show that neutral drag coefficients in onshore winds increase as the wind-wave direction differences increase, especially beyond ±60°.

  3. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts

    PubMed Central

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-01-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change. PMID:27435531

  4. Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts.

    PubMed

    Galgani, Luisa; Piontek, Judith; Engel, Anja

    2016-01-01

    The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice harbors high amounts of polymeric substances that are produced by cells growing within the sea-ice brine. Here, we report from a research cruise to the central Arctic Ocean in 2012. Our study shows that microbial polymers accumulate at the air-sea interface when the sea ice melts. Proteinaceous compounds represented the major fraction of polymers supporting the formation of a gelatinous interface microlayer and providing a hitherto unrecognized potential source of marine POA. Our study indicates a novel link between sea ice-ocean and atmosphere that may be sensitive to climate change. PMID:27435531

  5. Sea surface temperature anomalies, planetary waves, and air-sea feedback in the middle latitudes

    NASA Technical Reports Server (NTRS)

    Frankignoul, C.

    1985-01-01

    Current analytical models for large-scale air-sea interactions in the middle latitudes are reviewed in terms of known sea-surface temperature (SST) anomalies. The scales and strength of different atmospheric forcing mechanisms are discussed, along with the damping and feedback processes controlling the evolution of the SST. Difficulties with effective SST modeling are described in terms of the techniques and results of case studies, numerical simulations of mixed-layer variability and statistical modeling. The relationship between SST and diabatic heating anomalies is considered and a linear model is developed for the response of the stationary atmosphere to the air-sea feedback. The results obtained with linear wave models are compared with the linear model results. Finally, sample data are presented from experiments with general circulation models into which specific SST anomaly data for the middle latitudes were introduced.

  6. Tropical Cyclone Induced Air-Sea Interactions Over Oceanic Fronts

    NASA Astrophysics Data System (ADS)

    Shay, L.

    2012-04-01

    Recent severe tropical cyclones underscore the inherent importance of warm background ocean fronts and their interactions with the atmospheric boundary layer. Central to the question of heat and moisture fluxes from the ocean to the atmosphere, the amount of heat available to the tropical cyclone is predicated by the initial depth of the mixed layer and strength of the stratification level that set the level of entrainment mixing at the base of the oceanic mixed layer. For example in oceanic regimes where the ocean mixed layers are thin, shear-induced mixing tends to cool the upper ocean (and sea surface temperatures) quickly which reduces the air-sea fluxes. This is an example of negative feedback from the ocean to the atmosphere. By contrast, in regimes where the ocean mixed layers are deep (usually along the western part of the gyres), warm water advection by the nearly steady currents reduces the levels of turbulent mixing by shear instabilities. As these strong near-inertial shears are arrested, more heat and moisture is available through the sea surface. When tropical cyclones move into favorable or neutral atmospheric conditions (low vertical shear, anticyclonic circulation aloft), tropical cyclones have a tendency to rapidly intensify as observed over the Gulf of Mexico during Isidore and Lili in 2002, Katrina and Rita in 2005, Dean and Felix in 2007 in the Caribbean Sea, and Earl in 2010 just north of the Caribbean Islands. To predict these tropical cyclone deepening (as well as weakening) cycles, coupled models must have ocean models with realistic ocean conditions and accurate air-sea and vertical mixing parameterizations. These effects and possible impact on TC deepening and weakening underscores the necessity of having complete 3-D ocean measurements juxtaposed with atmospheric profiler measurements.

  7. An overview of sea state conditions and air-sea fluxes during RaDyO

    NASA Astrophysics Data System (ADS)

    Zappa, Christopher J.; Banner, Michael L.; Schultz, Howard; Gemmrich, Johannes R.; Morison, Russel P.; Lebel, Deborah A.; Dickey, Tommy

    2012-07-01

    Refining radiative-transfer modeling capabilities for light transmission through the sea surface requires a more detailed prescription of the sea surface roughness beyond the probability density function of the sea surface slope field. To meet this need, exciting new measurement methodologies now provide the opportunity to enhance present knowledge of sea surface roughness, especially at the microscale. In this context, two intensive field experiments using R/PFloating Instrument Platformwere staged within the Office of Naval Research's Radiance in a Dynamic Ocean (RaDyO) field program in the Santa Barbara Channel and in the central Pacific Ocean south of Hawaii. As part of this program, our team gathered and analyzed a comprehensive suite of sea surface roughness measurements designed to provide optimal coverage of fundamental optical distortion processes associated with the air-sea interface. This contribution describes the ensemble of instrumentation deployed. It provides a detailed documentation of the ambient environmental conditions that prevailed during the RaDyO field experiments. It also highlights exciting new sea surface roughness measurement capabilities that underpin a number of the scientific advances resulting from the RaDyO program. For instance, a new polarimetric imaging camera highlights the complex interplay of wind and surface currents in shaping the roughness of the sea surface that suggests the traditional Cox-Munk framework is not sufficient. In addition, the breaking crest length spectral density derived from visible and infrared imagery is shown to be modulated by the development of the wavefield (wave age) and alignment of wind and surface currents at the intermediate (dominant) scale of wave breaking.

  8. Air--Sea CO2 Cycling in the Southeastern Beaufort Sea

    NASA Astrophysics Data System (ADS)

    Else, Brent Gordon Thomas

    During the fourth International Polar Year, an interdisciplinary study was conducted to examine the couplings between sea ice, ocean, atmosphere, and ecosystem in the southeastern Beaufort Sea. This thesis examines components of the system that control the air-sea exchange of carbon dioxide. Using eddy covariance measurements, we found enhanced CO2 exchange associated with new ice formation in winter flaw leads. This exchange was typically directed towards the surface, although we also measured one instance of outgassing. Sea surface dissolved CO2 measurements (pCO 2sw) in Amundsen Gulf showed significant undersaturation with respect to the atmosphere at freeze-up, followed by a slow increase over the winter until spring phytoplankton blooms caused strong undersaturation at break-up. Over the summer, pCO2sw increased until becoming slightly supersaturated due to surface warming. Along the southern margins of Amundsen Gulf and on the Mackenzie Shelf we found pCO2sw supersaturations in the fall due to wind-driven coastal upwelling. In the spring, this upwelling occurred along the landfast ice edges of Amundsen Gulf. By combining observations of enhanced winter gas exchange with observations of pCO 2sw in Amundsen Gulf, we derived an annual budget of air-sea CO2 exchange for the region. This exercise showed that uptake through the winter season was as important as the open water season, making the overall annual uptake of CO2 about double what had previously been calculated. Prior to this work, the prevailing paradigm of airsea CO2 cycling in Arctic polynya regions posited that strong CO2 absorption occurs in the open water seasons, and that a potential outgassing during the winter is inhibited by the sea ice cover. As a new paradigm, we propose that the spatial and temporal variability of many processes---including phytoplankton blooms, sea surface temperature and salinity changes, upwelling, river input, continental shelf processes, and the potential for high rates

  9. The role of bubbles during air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Emerson, Steven; Bushinsky, Seth

    2016-06-01

    The potential for using the air-sea exchange rate of oxygen as a tracer for net community biological production in the ocean is greatly enhanced by recent accuracy improvements for in situ measurements of oxygen on unmanned platforms. A limiting factor for determining the exchange process is evaluating the air-sea flux contributed by bubble processes produced by breaking waves, particularly during winter months under high winds. Highly accurate measurements of noble gases (Ne, Ar & Kr) and nitrogen, N2, in seawater are tracers of the importance of bubble process in the surface mixed layer. We use measured distributions of these gases in the ventilated thermocline of the North Pacific and an annual time series of N2 in the surface ocean of the NE Subarctic Pacific to evaluate four different air-water exchange models chosen to represent the range of model interpretation of bubble processes. We find that models must have an explicit bubble mechanism to reproduce concentrations of insoluble atmospheric gases, but there are periods when they all depart from observations. The recent model of Liang et al. (2013) stems from a highly resolved model of bubble plumes and categorizes bubble mechanisms into those that are small enough to collapse and larger ones that exchange gases before they resurface, both of which are necessary to explain the data.

  10. Air-sea exchange over Black Sea estimated from high resolution regional climate simulations

    NASA Astrophysics Data System (ADS)

    Velea, Liliana; Bojariu, Roxana; Cica, Roxana

    2013-04-01

    Black Sea is an important influencing factor for the climate of bordering countries, showing cyclogenetic activity (Trigo et al, 1999) and influencing Mediterranean cyclones passing over. As for other seas, standard observations of the atmosphere are limited in time and space and available observation-based estimations of air-sea exchange terms present quite large ranges of uncertainty. The reanalysis datasets (e.g. ERA produced by ECMWF) provide promising validation estimates of climatic characteristics against the ones in available climatic data (Schrum et al, 2001), while cannot reproduce some local features due to relatively coarse horizontal resolution. Detailed and realistic information on smaller-scale processes are foreseen to be provided by regional climate models, due to continuous improvements of physical parameterizations and numerical solutions and thus affording simulations at high spatial resolution. The aim of the study is to assess the potential of three regional climate models in reproducing known climatological characteristics of air-sea exchange over Black Sea, as well as to explore the added value of the model compared to the input (reanalysis) data. We employ results of long-term (1961-2000) simulations performed within ENSEMBLE project (http://ensemblesrt3.dmi.dk/) using models ETHZ-CLM, CNRM-ALADIN, METO-HadCM, for which the integration domain covers the whole area of interest. The analysis is performed for the entire basin for several variables entering the heat and water budget terms and available as direct output from the models, at seasonal and annual scale. A comparison with independent data (ERA-INTERIM) and findings from other studies (e.g. Schrum et al, 2001) is also presented. References: Schrum, C., Staneva, J., Stanev, E. and Ozsoy, E., 2001: Air-sea exchange in the Black Sea estimated from atmospheric analysis for the period 1979-1993, J. Marine Systems, 31, 3-19 Trigo, I. F., T. D. Davies, and G. R. Bigg (1999): Objective

  11. Unravelling air-sea interactions driven by photochemistry in the sea-surface microlayer

    NASA Astrophysics Data System (ADS)

    George, Christian; Alpert, Peter; Tinel, Liselotte; Rossignol, Stéphanie; Perrier, Sébastien; Bernard, Francois; Ciuraru, Raluca; Hayeck, Nathalie

    2016-04-01

    Interfaces are ubiquitous in the environment, and in addition many atmospheric key processes, such as gas deposition, aerosol and cloud formation are, at one stage or the other, strongly impacted by physical- and chemical processes occurring at interfaces. Unfortunately, these processes have only been suggested and discussed but never fully addressed because they were beyond reach. We suggest now that photochemistry or photosensitized reactions exist at interfaces, and we will present and discuss their possible atmospheric implications. Obviously, one of the largest interface is the sea-surface microlayer (SML), which is a region lying at the uppermost tens to hundreds of micrometres of the water surface, with physical, chemical and biological properties that differ from those of the underlying sub-surface water. Organic film formation at the sea surface is made possible in the presence of an excess of surface-active material. Hydrophobic surfactant films are typically believed to play the role of a physical barrier to air-sea exchanges, especially at low wind speed. We will show that dissolved organic matter (DOM) can trigger photochemistry at the air-sea interface, releasing unsaturated, functionalized volatile organic compounds (VOCs), including isoprene,... acting as precursors for the formation of organic aerosols, that were thought, up to now, to be solely of biological origin! In addition, we suggest that when arranged at an air/water interface, hydrophobic surfactant can have weak chemical interactions among them, which can trigger the absorption of sunlight and can consequently induce photochemistry at such interfaces. A major question arises from such observations, namely: can the existence of such weak intra- or intermolecular interactions and the subsequent photochemistry be generalized to many other atmospheric objects such as aerosols? This topic will be presented and discussed.

  12. Research in Observations of Oceanic Air/Sea Interaction

    NASA Technical Reports Server (NTRS)

    Long, David G.; Arnold, David V.

    1995-01-01

    The primary purpose of this research has been: (1) to develop an innovative research radar scatterometer system capable of directly measuring both the radar backscatter and the small-scale and large-scale ocean wave field simultaneously and (2) deploy this instrument to collect data to support studies of air/sea interaction. The instrument has been successfully completed and deployed. The system deployment lasted for six months during 1995. Results to date suggest that the data is remarkably useful in air/sea interaction studies. While the data analysis is continuing, two journal and fifteen conference papers have been published. Six papers are currently in review with two additional journal papers scheduled for publication. Three Master's theses on this research have been completed. A Ph.D. student is currently finalizing his dissertation which should be completed by the end of the calendar year. We have received additional 'mainstream' funding from the NASA oceans branch to continue data analysis and instrument operations. We are actively pursuing results from the data expect additional publications to follow. This final report briefly describes the instrument system we developed and results to-date from the deployment. Additional detail is contained in the attached papers selected from the bibliography.

  13. Tropical Cyclone Induced Air-Sea Interactions Over Oceanic Fronts

    NASA Astrophysics Data System (ADS)

    Shay, L. K.

    2012-12-01

    Recent severe tropical cyclones underscore the inherent importance of warm background ocean fronts and their interactions with the atmospheric boundary layer. Central to the question of heat and moisture fluxes, the amount of heat available to the tropical cyclone is predicated by the initial mixed layer depth and strength of the stratification that essentially set the level of entrainment mixing at the base of the mixed layer. In oceanic regimes where the ocean mixed layers are thin, shear-induced mixing tends to cool the upper ocean to form cold wakes which reduces the air-sea fluxes. This is an example of negative feedback. By contrast, in regimes where the ocean mixed layers are deep (usually along the western part of the gyres), warm water advection by the nearly steady currents reduces the levels of turbulent mixing by shear instabilities. As these strong near-inertial shears are arrested, more heat and moisture transfers are available through the enthalpy fluxes (typically 1 to 1.5 kW m-2) into the hurricane boundary layer. When tropical cyclones move into favorable or neutral atmospheric conditions, tropical cyclones have a tendency to rapidly intensify as observed over the Gulf of Mexico during Isidore and Lili in 2002, Katrina, Rita and Wilma in 2005, Dean and Felix in 2007 in the Caribbean Sea, and Earl in 2010 just north of the Caribbean Islands. To predict these tropical cyclone deepening (as well as weakening) cycles, coupled models must have ocean models with realistic ocean conditions and accurate air-sea and vertical mixing parameterizations. Thus, to constrain these models, having complete 3-D ocean profiles juxtaposed with atmospheric profiler measurements prior, during and subsequent to passage is an absolute necessity framed within regional scale satellite derived fields.

  14. Observational Studies of Parameters Influencing Air-sea Gas Exchange

    NASA Astrophysics Data System (ADS)

    Schimpf, U.; Frew, N. M.; Bock, E. J.; Hara, T.; Garbe, C. S.; Jaehne, B.

    A physically-based modeling of the air-sea gas transfer that can be used to predict the gas transfer rates with sufficient accuracy as a function of micrometeorological parameters is still lacking. State of the art are still simple gas transfer rate/wind speed relationships. Previous measurements from Coastal Ocean Experiment in the Atlantic revealed positive correlations between mean square slope, near surface turbulent dis- sipation, and wind stress. It also demonstrated a strong negative correlation between mean square slope and the fluorescence of surface-enriched colored dissolved organic matter. Using heat as a proxy tracer for gases the exchange process at the air/water interface and the micro turbulence at the water surface can be investigated. The anal- ysis of infrared image sequences allow the determination of the net heat flux at the ocean surface, the temperature gradient across the air/sea interface and thus the heat transfer velocity and gas transfer velocity respectively. Laboratory studies were carried out in the new Heidelberg wind-wave facility AELOTRON. Direct measurements of the Schmidt number exponent were done in conjunction with classical mass balance methods to estimate the transfer velocity. The laboratory results allowed to validate the basic assumptions of the so called controlled flux technique by applying differ- ent tracers for the gas exchange in a large Schmidt number regime. Thus a modeling of the Schmidt number exponent is able to fill the gap between laboratory and field measurements field. Both, the results from the laboratory and the field measurements should be able to give a further understanding of the mechanisms controlling the trans- port processes across the aqueous boundary layer and to relate the forcing functions to parameters measured by remote sensing.

  15. Developments in Airborne Oceanography and Air-Sea Interaction

    NASA Astrophysics Data System (ADS)

    Melville, W. K.

    2014-12-01

    , just as aircraft carriers "project force". Now we can measure winds, waves, temperatures, currents, radiative transfer, images and air-sea fluxes from aircraft over the ocean.I will review some of the history of airborne oceanography and present examples of how it can extend our knowledge and understanding of air-sea interaction.

  16. Infrared propagation in the air-sea boundary layer

    NASA Astrophysics Data System (ADS)

    Larsen, R.; Preedy, K. A.; Drake, G.

    1990-03-01

    Over the oceans and other large bodies of water the structure of the lowest layers of the atmosphere is often strongly modified by evaporation of water vapor from the water surface. At radio wavelengths this layer will usually be strongly refracting or ducting, and the layer is commonly known as the evaporation duct. However, the refractive index of air at infrared wavelengths differs from that at radio wavelengths, and the effects of the marine boundary layer on the propagation of infrared radiation are examined. Meteorological models of the air-sea boundary layer are used to compute vertical profiles of temperature and water-vapor pressure. From these are derived profiles of atmospheric refractive index at radio wavelengths and at infrared wavelengths in the window regions of low absorption. For duct propagation to occur it is necessary that the refractivity of air decreases rapidly with increasing height above the surface. At radio wavelengths this usually occurs when there is a strong lapse of water vapor pressure with increasing height. By contrast, at infrared wavelengths the refractive index is almost independent of water vapor pressure, and it is found that an infrared duct is formed only when there is a temperature inversion.

  17. Distributions and sea-to-air fluxes of nitrous oxide in the South China Sea and the West Philippines Sea

    NASA Astrophysics Data System (ADS)

    Tseng, Hsiao-Chun; Chen, Chen-Tung Arthur; Borges, Alberto V.; DelValls, T. Angel; Lai, Chao-Ming; Chen, Ting-Yu

    2016-09-01

    Approximately 600 water samples from the South China Sea (SCS) and 250 water samples from the West Philippines Sea (WPS) were collected during seven cruises from August 2003 to July 2007 to determine nitrous oxide (N2O) distributions between the surface and a maximum depth of 4250 m. In the SCS, the average surface N2O concentration exceeded the atmospheric equilibrium concentration (on average 132±23%); however in the WPS, the surface N2O concentration was lower than the atmospheric equilibrium concentration (on average 90±22%). The N2O concentration reached a maximum (~23 nmol L-1) in the WPS at 800-1000 m, and (~28 nmol L-1) at a shallower depth of around 600-800 m in the SCS, owing to vertical mixing and intensive upwelling in the SCS. In the SCS, the surface N2O concentration was 7.59±1.32 nmol L-1 and the calculated sea-to-air flux was 5.5±3.9 μmol m-2 d-1. The surface N2O concentration in the WPS, 5.19±1.26 nmol L-1, was lower than that in the SCS. The WPS is a sink for N2O and the calculated sea-to-air flux was -1.7±3.9 μmol m-2 d-1. The SCS emitted 19.3×106 mol d-1 N2O to the atmosphere and exported 8.5×106 mol d-1 N2O to the WPS during the wet season.

  18. The SOLAS air-sea gas exchange experiment (SAGE) 2004

    NASA Astrophysics Data System (ADS)

    Harvey, Mike J.; Law, Cliff S.; Smith, Murray J.; Hall, Julie A.; Abraham, Edward R.; Stevens, Craig L.; Hadfield, Mark G.; Ho, David T.; Ward, Brian; Archer, Stephen D.; Cainey, Jill M.; Currie, Kim I.; Devries, Dawn; Ellwood, Michael J.; Hill, Peter; Jones, Graham B.; Katz, Dave; Kuparinen, Jorma; Macaskill, Burns; Main, William; Marriner, Andrew; McGregor, John; McNeil, Craig; Minnett, Peter J.; Nodder, Scott D.; Peloquin, Jill; Pickmere, Stuart; Pinkerton, Matthew H.; Safi, Karl A.; Thompson, Rona; Walkington, Matthew; Wright, Simon W.; Ziolkowski, Lori A.

    2011-03-01

    The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX's), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO 2, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF 6/ 3He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments. There was a significant increase in the photosynthetic competence ( Fv/ Fm) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX's, rates of net primary production and column-integrated chlorophyll a concentrations had

  19. Satellite observations of air-sea interaction over the Kuroshio

    NASA Astrophysics Data System (ADS)

    Xie, S.; Nonaka, M.; Hafner, J.; Liu, W. T.

    2002-12-01

    Satellite microwave measurements are analyzed, revealing robust co-variability in sea surface temperature (SST) and wind speed over the Kuroshio and its Extension (KE). Ocean hydrodynamic instabilities cause the KE to meander and result into large SST variations. Increased (reduced) wind speeds are found to be associated with warm (cold) SST anomalies. This positive SST-wind correlation in KE is confirmed by in-situ buoy measurements and is consistent with a vertical shear adjustment mechanism. Namely, an increase in SST reduces the static stability of the near-surface atmosphere, intensifying the vertical turbulence mixing and bringing fast-moving air from aloft to the sea surface. South of Japan, the Kuroshio is known to vary between nearshore and offshore paths. Both paths seem semi-permanent and can persist months to years. As the Kuroshio shifts its path, coherent wind changes are detected. In particular, winds are high south of Tokyo when the Kuroshio takes the nearshore path while they are greatly reduced when this warm current leaves the coast in the offshore path. Further upstream in the East China Sea, on the warmer flank of the Kuroshio Front, there are a zone of high wind speed and a band of raining cloud due to the region's unstable atmospheric stratification near the surface. Surface wind convergence is roughly collocated with the Kuroshio Current. By increasing the baroclinicity and condensational heating, the Kuroshio Front aids the growth of the so-called Taiwan cyclone, an important winter weather phenomenon for Japan. The positive SST-wind correlation over the strong Kuroshio Current and its extension is opposite to the negative one often observed in regions of weak currents such as south of the Aleutian low that is considered to be indicative of atmosphere-to-ocean forcing.

  20. Diagnosing Air-Sea Interactions on Intraseasonal Timescales

    NASA Astrophysics Data System (ADS)

    DeMott, C. A.

    2014-12-01

    What is the role of ocean coupling in the Madden Julian Oscillation (MJO)? Consensus thinking holds that the essential physics of the MJO involve interactions between convection, atmospheric wave dynamics, and boundary layer and free troposphere moisture. However, many modeling studies demonstrate improved MJO simulation when an atmosphere-only general circulation model (AGCM) is coupled to an ocean model, so feedbacks from the ocean are probably not negligible. Assessing the importance and processes of these feedbacks is challenging for at least two reasons. First, observations of the MJO only sample the fully coupled ocean-atmosphere system; there is no "uncoupled" MJO in nature. Second, the practice of analyzing the MJO in uncoupled and coupled GCMs (CGCMs) involves using imperfect tools to study the problem. Although MJO simulation is improving in many models, shortcomings remain in both AGCMs and CGCMs, making it difficult to determine if changes brought about through coupling reflect critical air-sea interactions or are simply part of the collective idiosyncracies of a given model. For the atmosphere, ocean feedbacks from intraseasonal sea surface temperature (SST) variations are communicated through their effects on surface fluxes of heat and moisture. This presentation suggests a set of analysis tools for diagnosing the impact of an interactive ocean on surface latent and sensible heat fluxes, including their mean, variance, spectral characteristics, and phasing with respect to wind, SST, and MJO convection. The diagnostics are demonstrated with application to several CMIP5 models, and reveal a variety of responses to coupled ocean feedbacks.

  1. Air-sea coupling in the Hawaiian Archipelago

    NASA Astrophysics Data System (ADS)

    Souza, J. M.; Powell, B.; Mattheus, D.

    2014-12-01

    A coupled numerical model is used to investigate the ocean-atmosphere interaction in the lee of the Hawaiian archipelago. The wind curl generated by the island blocking of the trade winds is known to give rise to ocean eddies; however, the impact of the sea surface temperature (SST) and velocity fronts associated with these eddies on the atmosphere is less understood. The main coupling mechanisms are: (i) changes in the near-surface stability and surface stress, (ii) vertical transfer of momentum from higher atmospheric levels to the ocean surface due to an increase of the turbulence in the boundary layer, (iii) secondary circulations associated with perturbations in the surface atmospheric pressure over the SST fronts, and (iv) the impact of the oceanic eddy currents on the net momentum transferred between the atmosphere and the ocean. To assess the relative contribution from each process, a coupled simulation between the Regional Ocean Modeling System (ROMS) and the Weather Research and Forecasting (WRF) models is conducted for the main Hawaiian Islands. The impact of the coupling, the perturbation of the mean wind pattern, and the different spatial scales involved in the air-sea exchanges of momentum and heat are explored.

  2. Unstable Air-Sea Interaction in the Extratropical North Atlantic

    NASA Technical Reports Server (NTRS)

    Hakkinen, Sirpa

    1999-01-01

    The possibility of coupled modes in the extratropical North Atlantic has fascinated the climate community since 1960's. A significant aspect of such modes is an unstable air-sea interaction, also called positive feedback, where disturbances between the atmosphere and ocean grow unbound. If a delayed response exists before the negative feedback takes effect, an oscillatory behaviour will develop. Here we explore the relationship between heat flux (positive upward) and sea surface temperature (SST). Positive feedback is characterized by a cross-correlation between the two where correlation maintains a negative sign whether SST or heat flux leads. We use model results and observations to argue that in the North Atlantic there exist regions with positive feedback. The two main locations coincide with the well-known north-south SST dipole where anomalies of opposite sign occupy areas east of Florida and north-east of Newfoundland. We show that oceanic dynamics, wave propagation and advection, give rise to oceanic anomalies in these regions. Subsequently these anomalies are amplified by atmosphere- ocean interaction: thus a positive feedback.

  3. Antarctic Sea ice variations and seasonal air temperature relationships

    NASA Technical Reports Server (NTRS)

    Weatherly, John W.; Walsh, John E.; Zwally, H. J.

    1991-01-01

    Data through 1987 are used to determine the regional and seasonal dependencies of recent trends of Antarctic temperature and sea ice. Lead-lag relationships involving regional sea ice and air temperature are systematically evaluated, with an eye toward the ice-temperature feedbacks that may influence climatic change. Over the 1958-1087 period the temperature trends are positive in all seasons. For the 15 years (l973-l987) for which ice data are available, the trends are predominantly positive only in winter and summer, and are most strongly positive over the Antarctic Peninsula. The spatially aggregated trend of temperature for this latter period is small but positive, while the corresponding trend of ice coverage is small but negative. Lag correlations between seasonal anomalies of the two variables are generally stronger with ice lagging the summer temperatures and with ice leading the winter temperatures. The implication is that summer temperatures predispose the near-surface waters to above-or below-normal ice coverage in the following fall and winter.

  4. Air-Sea Interaction Measurements from R/P FLIP

    NASA Astrophysics Data System (ADS)

    Friehe, C. A.

    2002-12-01

    Soon after its inception, R/P FLIP was used to study the interaction of the atmosphere and ocean due to its unique stability and low flow distortion. A number of campaigns have been conducted to measure the surface fluxes of heat, water vapor and horizontal momentum of the wind with instrumentation as used over land, supported by the Office of Naval Research and the National Science Foundation. The size of FLIP allows for simultaneous ocean wave and mixed-layer measurements as well. Air-sea interaction was a prime component of BOMEX in 1968, where FLIP transited the Panama Canal. The methods used were similar to the over-land "Kansas" experiment of AFCRL in 1968. BOMEX was followed by many experiments in the north Pacific off San Diego, northern California, and Hawaii. Diverse results from FLIP include identification of the mechanism that causes erroneous fluctuating temperature measurements in the salt-aerosol-laden marine atmosphere, the role of humidity on optical refractive index fluctuations, and identification of Miles' critical layer in the air flow over waves.

  5. Air-sea exchange of gaseous mercury in the East China Sea.

    PubMed

    Wang, Chunjie; Ci, Zhijia; Wang, Zhangwei; Zhang, Xiaoshan

    2016-05-01

    Two oceanographic cruises were carried out in the East China Sea (ECS) during the summer and fall of 2013. The main objectives of this study are to identify the spatial-temporal distributions of gaseous elemental mercury (GEM) in air and dissolved gaseous mercury (DGM) in surface seawater, and then to estimate the Hg(0) flux. The GEM concentration was lower in summer (1.61 ± 0.32 ng m(-3)) than in fall (2.20 ± 0.58 ng m(-3)). The back-trajectory analysis revealed that the air masses with high GEM levels during fall largely originated from the land, while the air masses with low GEM levels during summer primarily originated from ocean. The spatial distribution patterns of total Hg (THg), fluorescence, and turbidity were consistent with the pattern of DGM with high levels in the nearshore area and low levels in the open sea. Additionally, the levels of percentage of DGM to THg (%DGM) were higher in the open sea than in the nearshore area, which was consistent with the previous studies. The THg concentration in fall was higher (1.47 ± 0.51 ng l(-1)) than those of other open oceans. The DGM concentration (60.1 ± 17.6 pg l(-1)) and Hg(0) flux (4.6 ± 3.6 ng m(-2) h(-1)) in summer were higher than those in fall (DGM: 49.6 ± 12.5 pg l(-1) and Hg(0) flux: 3.6 ± 2.8 ng m(-2) h(-1)). The emission flux of Hg(0) from the ECS was estimated to be 27.6 tons yr(-1), accounting for ∼0.98% of the global Hg oceanic evasion though the ECS only accounts for ∼0.21% of global ocean area, indicating that the ECS plays an important role in the oceanic Hg cycle. PMID:26975003

  6. Air-Sea Interaction Measurements from the Controlled Towed Vehicle

    NASA Astrophysics Data System (ADS)

    Khelif, D.; Bluth, R. T.; Jonsson, H.; Barge, J.

    2014-12-01

    The Controlled Towed Vehicle (CTV) uses improved towed drone technology to actively maintain via a radar altimeter and controllable wing a user-set height that can be as low as the canonical reference height of 10 m above the sea surface. After take-off, the drone is released from the tow aircraft on a ~700-m stainless steel cable. We have instrumented the 0.23 m diameter and 2.13 m long drone with high fidelity instruments to measure the means and turbulent fluctuations of 3-D wind vector, temperature, humidity, pressure, CO2 and IR sea surface temperature. Data are recorded internally at 40 Hz and simultaneously transmitted to the tow aircraft via dedicated wireless Ethernet link. The CTV accommodates 40 kg of instrument payload and provides it with 250 W of continuous power through a ram air propeller-driven generator. Therefore its endurance is only limited by that of the tow aircraft.We will discuss the CTV development, the engineering challenges and solutions that have been successfully implemented to overcome them. We present results from recent flights as low as 9 m over the coastal ocean and comparisons of profiles and turbulent fluxes from the CTV and the tow aircraft. Manned aircraft operation at low-level boundary-layer flights is very limited. Dropsondes and UAS (Unmanned Aerial Systems) and UAS are alternates for measurements near the ocean surface. However, dropsondes have limited sensor capability and do not measure fluxes, and most present UAS vehicles do not have the payload and power capacity nor the low-flying ability in high winds over the oceans. The CTV therefore, fills a needed gap between the dropsondes, in situ aircraft, and UAS. The payload, capacity and power of the CTV makes it suitable for a variety of atmospheric research measurements. Other sensors to measure aerosol, chemistry, radiation, etc., could be readily accommodated in the CTV.

  7. Annual and seasonal fCO2 and air-sea CO2 fluxes in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Lauvset, S. K.; Chierici, M.; Counillon, F.; Omar, A.; Nondal, G.; Johannessen, T.; Olsen, A.

    2013-03-01

    The Barents Sea is the strongest CO2 sink in the Arctic region, yet estimates of the air-sea CO2 flux in this area show a large span reflecting uncertainty as well as significant variability both seasonally and regionally. Here we use a previously unpublished data set of seawater CO2 fugacity (fCO2), and map these data over the western Barents Sea through multivariable linear regressions with SeaWiFS/MODIS remote sensing and TOPAZ model data fields. We find that two algorithms are necessary in order to cover the full seasonal cycle, mainly because not all proxy variables are available for the entire year, and because variability in fCO2 is driven by different mechanisms in summer and winter. A comprehensive skill assessment indicates that there is a good overall correspondence between observations and predictions. The algorithms are also validated using two independent data sets, with good results. The gridded fCO2 fields reveal tight links between water mass distribution and fCO2 in all months, and particularly in winter. The seasonal cycle show peaks in the total air-sea CO2 influx in May and September, caused by respectively biological drawdown of CO2 and low sea ice concentration leaving a large open water area. For 2007 the annual average air-sea CO2 flux is - 48 ± 5 gC m- 2, which is comparable to previous estimates.

  8. Flight crew fatigue III: North Sea helicopter air transport operations.

    PubMed

    Gander, P H; Barnes, R M; Gregory, K B; Graeber, R C; Connell, L J; Rosekind, M R

    1998-09-01

    We studied 32 helicopter pilots before, during, and after 4-5 d trips from Aberdeen, Scotland, to service North Sea oil rigs. On duty days, subjects awoke 1.5 h earlier than pretrip or posttrip, after having slept nearly an hour less. Subjective fatigue was greater posttrip than pretrip. By the end of trip days, fatigue was greater and mood more negative than by the end of pretrip days. During trips, daily caffeine consumption increased 42%, reports of headache doubled, reports of back pain increased 12-fold, and reports of burning eyes quadrupled. In the cockpits studied, thermal discomfort and high vibration levels were common. Subjective workload during preflight, taxi, climb, and cruise was related to the crewmembers' ratings of the quality of the aircraft systems. During descent and approach, workload was affected by weather at the landing site. During landing, it was influenced by the quality of the landing site and air traffic control. Beginning duty later, and greater attention to aircraft comfort and maintenance, should reduce fatigue in these operations. PMID:9749937

  9. Improvement of the GEOS-5 AGCM upon Updating the Air-Sea Roughness Parameterization

    NASA Technical Reports Server (NTRS)

    Garfinkel, C. I.; Molod, A.; Oman, L. D.; Song, I.-S.

    2011-01-01

    The impact of an air-sea roughness parameterization over the ocean that more closely matches recent observations of air-sea exchange is examined in the NASA Goddard Earth Observing System, version 5 (GEOS-5) atmospheric general circulation model. Surface wind biases in the GEOS-5 AGCM are decreased by up to 1.2m/s. The new parameterization also has implications aloft as improvements extend into the stratosphere. Many other GCMs (both for operational weather forecasting and climate) use a similar class of parameterization for their air-sea roughness scheme. We therefore expect that results from GEOS-5 are relevant to other models as well.

  10. Overview of the Frontal Air-Sea Interaction Experiment (FASINEX) - A study of air-sea interaction in a region of strong oceanic gradients

    NASA Technical Reports Server (NTRS)

    Weller, Robert A.

    1991-01-01

    From 1984 to 1986 the cooperative Frontal Air-Sea Interaction Experiment (FASINEX) was conducted in the subtropical convergence zone southwest of Bermuda. The overall objective of the experiment was to study air-sea interaction on 1- to 100-km horizontal scales in a region of the open ocean characterized by strong horizontal gradients in upper ocean and sea surface properties. Ocean fronts provided both large spatial gradients in sea surface temperature and strong jetlike flows in the upper ocean. The motivation for and detailed objectives of FASINEX are reviewed. Then the components of the field program are summarized. Finally, selected results are presented in order to provide an overview of the outcome of FASINEX.

  11. Imaging air volume fraction in sea ice using non-destructive X-ray tomography

    NASA Astrophysics Data System (ADS)

    Crabeck, Odile; Galley, Ryan; Delille, Bruno; Else, Brent; Geilfus, Nicolas-Xavier; Lemes, Marcos; Des Roches, Mathieu; Francus, Pierre; Tison, Jean-Louis; Rysgaard, Søren

    2016-05-01

    Although the presence of a gas phase in sea ice creates the potential for gas exchange with the atmosphere, the distribution of gas bubbles and transport of gases within the sea ice are still poorly understood. Currently no straightforward technique exists to measure the vertical distribution of air volume fraction in sea ice. Here, we present a new fast and non-destructive X-ray computed tomography technique to quantify the air volume fraction and produce separate images of air volume inclusions in sea ice. The technique was performed on relatively thin (4-22 cm) sea ice collected from an experimental ice tank. While most of the internal layers showed air volume fractions < 2 %, the ice-air interface (top 2 cm) systematically showed values up to 5 %. We suggest that the air volume fraction is a function of both the bulk ice gas saturation factor and the brine volume fraction. We differentiate micro bubbles (Ø < 1 mm), large bubbles (1 mm < Ø < 5 mm) and macro bubbles (Ø > 5 mm). While micro bubbles were the most abundant type of gas bubbles, most of the air porosity observed resulted from the presence of large and macro bubbles. The ice texture (granular and columnar) as well as the permeability state of ice are important factors controlling the air volume fraction. The technique developed is suited for studies related to gas transport and bubble migration.

  12. Sea-air CO2 exchange in the western Arctic coastal ocean

    NASA Astrophysics Data System (ADS)

    Evans, Wiley; Mathis, Jeremy T.; Cross, Jessica N.; Bates, Nicholas R.; Frey, Karen E.; Else, Brent G. T.; Papkyriakou, Tim N.; DeGrandpre, Mike D.; Islam, Fakhrul; Cai, Wei-Jun; Chen, Baoshan; Yamamoto-Kawai, Michiyo; Carmack, Eddy; Williams, William. J.; Takahashi, Taro

    2015-08-01

    The biogeochemical seascape of the western Arctic coastal ocean is in rapid transition. Changes in sea ice cover will be accompanied by alterations in sea-air carbon dioxide (CO2) exchange, of which the latter has been difficult to constrain owing to sparse temporal and spatial data sets. Previous assessments of sea-air CO2 flux have targeted specific subregional areas of the western Arctic coastal ocean. Here a holistic approach is taken to determine the net sea-air CO2 flux over this broad region. We compiled and analyzed an extensive data set of nearly 600,000 surface seawater CO2 partial pressure (pCO2) measurements spanning 2003 through 2014. Using space-time colocated, reconstructed atmospheric pCO2 values coupled with the seawater pCO2 data set, monthly climatologies of sea-air pCO2 differences (ΔpCO2) were created on a 0.2° latitude × 0.5° longitude grid. Sea-air CO2 fluxes were computed using the ΔpCO2 grid and gas transfer rates calculated from climatology of wind speed second moments. Fluxes were calculated with and without the presence of sea ice, treating sea ice as an imperfect barrier to gas exchange. This allowed for carbon uptake by the western Arctic coastal ocean to be assessed under existing and reduced sea ice cover conditions, in which carbon uptake increased 30% over the current 10.9 ± 5.7 Tg C (1 Tg = 1012 g) yr-1 of sea ice-adjusted exchange in the region. This assessment extends beyond previous subregional estimates in the region in an all-inclusive manner and points to key unresolved aspects that must be targeted by future research.

  13. Bayesian Hierarchical Air-Sea Interaction Modeling: Application to the Labrador Sea

    NASA Technical Reports Server (NTRS)

    Niiler, Pearn P.

    2002-01-01

    The objectives are to: 1) Organize data from 26 MINIMET drifters in the Labrador Sea, including sensor calibration and error checking of ARGOS transmissions. 2) Produce wind direction, barometer, and sea surface temperature time series. In addition, provide data from historical file of 150 SHARP drifters in the Labrador Sea. 3) Work with data interpretation and data-modeling assimilation issues.

  14. Air-sea interaction and spatial variability of the surface evaporation duct in a coastal environment

    NASA Astrophysics Data System (ADS)

    Brooks, Ian M.

    Aircraft observations are presented of the horizontal variability in the depth of the surface evaporation duct and the relationship with the mesoscale structure of air-sea interaction processes. The 2-dimensional fields of near-surface wind, stress, wind-stress curl, air and sea-surface temperature are measured directly for flow around a headland. The sea surface temperature field indicates cold upwelling driven by the wind-stress curl. Boundary-layer stability responds rapidly to the spatial changes in surface temperature. These changes result in modification of the evaporation duct, which decreases significantly in depth over the cooler upwelling water.

  15. The impact of sea breeze under different synoptic patterns on air pollution within Athens basin.

    PubMed

    Mavrakou, Thaleia; Philippopoulos, Kostas; Deligiorgi, Despina

    2012-09-01

    Air quality in densely populated urban coastal areas is directly related to the coupling of the synoptic and the local scale flows. The dispersion conditions within Athens basin, under the influence of different meteorological forcings, lead to distinct spatio-temporal air pollution patterns. The aim of the current observational research is to identify and examine the effect of sea breeze under different atmospheric circulation patterns on air pollution levels for a one-year study period (2007). The study employs surface pressure maps, routine meteorological observations at two coastal sites and nitrogen monoxide (NO), nitrogen dioxide (NO(2)) and ozone (O(3)) concentrations from a network of four air quality stations within the Athens basin. A three-step methodology is applied that incorporates a set of criteria for classifying atmospheric circulation and identifying sea breeze events under each circulation pattern. Two types of sea breeze development are identified (pure sea breeze-PSB and modified sea breeze-MSB) with distinct characteristics. Sea breeze is found to develop more frequently under offshore compared to onshore and parallel to the shoreline background flows. Poor dispersion conditions (high nitrogen oxides-NO(x) and O(3) concentrations) are connected to the pure sea breeze cases and to those cases where sea breeze interacts with a moderate northerly flow during the warm period. The levels of NO(x) and O(3) for the northern Athens basin area are found to be significantly higher during the sea breeze days compared to the Etesian days. Regarding the diurnal variation of ozone for the sea breeze days, peak concentrations and higher intra-daily ranges are observed. Day-to-day pollution accumulation (build-up effect) is measured for O(3) at the northern stations in the Athens basin. PMID:22766425

  16. Biofilm-like properties of the sea surface and predicted effects on air-sea CO2 exchange

    NASA Astrophysics Data System (ADS)

    Wurl, Oliver; Stolle, Christian; Van Thuoc, Chu; The Thu, Pham; Mari, Xavier

    2016-05-01

    Because the sea surface controls various interactions between the ocean and the atmosphere, it has a profound function for marine biogeochemistry and climate regulation. The sea surface is the gateway for the exchange of climate-relevant gases, heat and particles. Thus, in order to determine how the ocean and the atmosphere interact and respond to environmental changes on a global scale, the characterization and understanding of the sea surface are essential. The uppermost part of the water column is defined as the sea-surface microlayer and experiences strong spatial and temporal dynamics, mainly due to meteorological forcing. Wave-damped areas at the sea surface are caused by the accumulation of surface-active organic material and are defined as slicks. Natural slicks are observed frequently but their biogeochemical properties are poorly understood. In the present study, we found up to 40 times more transparent exopolymer particles (TEP), the foundation of any biofilm, in slicks compared to the underlying bulk water at multiple stations in the North Pacific, South China Sea, and Baltic Sea. We found a significant lower enrichment of TEP (up to 6) in non-slick sea surfaces compared to its underlying bulk water. Moreover, slicks were characterized by a large microbial biomass, another shared feature with conventional biofilms on solid surfaces. Compared to non-slick samples (avg. pairwise similarity of 70%), the community composition of bacteria in slicks was increasingly (avg. pairwise similarity of 45%) different from bulk water communities, indicating that the TEP-matrix creates specific environments for its inhabitants. We, therefore, conclude that slicks can feature biofilm-like properties with the excessive accumulation of particles and microbes. We also assessed the potential distribution and frequency of slick-formation in coastal and oceanic regions, and their effect on air-sea CO2 exchange based on literature data. We estimate that slicks can reduce CO2

  17. Quantifying air-sea gas exchange using noble gases in a coastal upwelling zone

    NASA Astrophysics Data System (ADS)

    Manning, C. C.; Stanley, R. H. R.; Nicholson, D. P.; Squibb, M. E.

    2016-05-01

    The diffusive and bubble-mediated components of air-sea gas exchange can be quantified separately using time-series measurements of a suite of dissolved inert gases. We have evaluated the performance of four published air-sea gas exchange parameterizations using a five-day time-series of dissolved He, Ne, Ar, Kr, and Xe concentration in Monterey Bay, CA. We constructed a vertical model including surface air-sea gas exchange and vertical diffusion. Diffusivity was measured throughout the cruise from profiles of turbulent microstructure. We corrected the mixed layer gas concentrations for an upwelling event that occurred partway through the cruise. All tested parameterizations gave similar results for Ar, Kr, and Xe; their air-sea fluxes were dominated by diffusive gas exchange during our study. For He and Ne, which are less soluble, and therefore more sensitive to differences in the treatment of bubble-mediated exchange, the parameterizations gave widely different results with respect to the net gas exchange flux and the bubble flux. This study demonstrates the value of using a suite of inert gases, especially the lower solubility ones, to parameterize air-sea gas exchange.

  18. Decadal trends in air-sea CO2 exchange in the Ross Sea (Antarctica)

    NASA Astrophysics Data System (ADS)

    Tagliabue, Alessandro; Arrigo, Kevin R.

    2016-05-01

    Highly productive Antarctic shelf systems, like the Ross Sea, play important roles in regional carbon budgets, but the drivers of local variations are poorly quantified. We assess the variability in the Ross Sea carbon cycle using a regional physical-biogeochemical model. Regionally, total partial pressure of CO2 (pCO2) increases are largely controlled by the biological pump and broadly similar to those in the offshore Southern Ocean. However, this masks substantial local variability within the Ross Sea, where interannual fluctuations in total pCO2 are driven by the biological pump and alkalinity, whereas those for anthropogenic pCO2 are related to physical processes. Overall, the high degree of spatial variability in the Ross Sea carbon cycle causes extremes in aragonite saturation that can be as large as long-term trends. Therefore, Antarctic shelf polynya systems like the Ross Sea will be strongly affected by local processes in addition to larger-scale phenomena.

  19. The influence of sea ice cover on air-sea gas exchange estimated with radon-222 profiles

    NASA Astrophysics Data System (ADS)

    Rutgers van der Loeff, Michiel M.; Cassar, Nicolas; Nicolaus, Marcel; Rabe, Benjamin; Stimac, Ingrid

    2014-05-01

    Air-sea gas exchange plays a key role in the cycling of greenhouse and other biogeochemically important gases. Although air-sea gas transfer is expected to change as a consequence of the rapid decline in summer Arctic sea ice cover, little is known about the effect of sea ice cover on gas exchange fluxes, especially in the marginal ice zone. During the Polarstern expedition ARK-XXVI/3 (TransArc, August/September 2011) to the central Arctic Ocean, we compared 222Rn/226Ra ratios in the upper 50 m of 14 ice-covered and 4 ice-free stations. At three of the ice-free stations, we find 222Rn-based gas transfer coefficients in good agreement with expectation based on published relationships between gas transfer and wind speed over open water when accounting for wind history from wind reanalysis data. We hypothesize that the low gas transfer rate at the fourth station results from reduced fetch due to the proximity of the ice edge, or lateral exchange across the front at the ice edge by restratification. No significant radon deficit could be observed at the ice-covered stations. At these stations, the average gas transfer velocity was less than 0.1 m/d (97.5% confidence), compared to 0.5-2.2 m/d expected for open water. Our results show that air-sea gas exchange in an ice-covered ocean is reduced by at least an order of magnitude compared to open water. In contrast to previous studies, we show that in partially ice-covered regions, gas exchange is lower than expected based on a linear scaling to percent ice cover.

  20. Future Arctic sea ice loss reduces severity of cold air outbreaks in midlatitudes

    NASA Astrophysics Data System (ADS)

    Ayarzagüena, Blanca; Screen, James A.

    2016-03-01

    The effects of Arctic sea ice loss on cold air outbreaks (CAOs) in midlatitudes remain unclear. Previous studies have defined CAOs relative to the present-day climate, but changes in CAOs, defined in such a way, may reflect changes in mean climate and not in weather variability, and society is more sensitive to the latter. Here we revisit this topic but applying changing temperature thresholds relating to climate conditions of the time. CAOs do not change in frequency or duration in response to projected sea ice loss. However, they become less severe, mainly due to advection of warmed polar air, since the dynamics associated with the occurrence of CAOs are largely not affected. CAOs weaken even in midlatitude regions where the winter mean temperature decreases in response to Arctic sea ice loss. These results are robustly simulated by two atmospheric models prescribed with differing future sea ice states and in transient runs where external forcings are included.

  1. Sea breeze forcing of estuary turbulence and air-water CO2 exchange

    NASA Astrophysics Data System (ADS)

    Orton, Philip M.; McGillis, Wade R.; Zappa, Christopher J.

    2010-07-01

    The sea breeze is often a dominant meteorological feature at the coastline, but little is known about its estuarine impacts. Measurements at an anchored catamaran and meteorological stations along the Hudson River and New York Bay estuarine system are used to illustrate some basic characteristics and impacts of the feature. The sea breeze propagates inland, arriving in phase with peak solar forcing at seaward stations, but several hours later at up-estuary stations. Passage of the sea breeze front raises the water-to-air CO2 flux by 1-2 orders of magnitude, and drives turbulence comparable to spring tide levels in the upper meter of the water column, where most primary productivity occurs in this highly turbid system. Modeling and observational studies often use remotely-measured winds to compute air-water fluxes (e.g., momentum, CO2), and this leads to a factor of two flux error on sea breeze days during the study.

  2. Sensitivity of Air-sea Exchange In A Regional Scale Coupled Ice/ocean/atmosphere Model

    NASA Astrophysics Data System (ADS)

    Schrum, C.; Hübner, U.; Jacob, D.; Podzun, R.

    The sub-systems ice, ocean and atmosphere are coupled on the global as well as the regional scale. However, regional coupled modeling is only in the beginning, full cou- pled models which are able to describe the interaction on the regional scale and the feedback mechanism are rare at the moment. For the North Sea and the Baltic Sea such a coupled model has been developed and exemplary integrated over a full seasonal cy- cle. By comparison of different regionalization studies the impact of the regional at- mospheric modeling and coupling on the air sea fluxes have been investigated. It was shown that the regionalization as well as the coupling show strong influence on the air/sea fluxes and thus on the oceanic conditions. Further problems in regional mod- eling like the description of storm track variability and its influence on the regional ocean model were identified.

  3. Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights (Invited)

    NASA Astrophysics Data System (ADS)

    Tsuda, A.

    2010-12-01

    Western Pacific Air-Sea Interaction Study (W-PASS), Introduction and Highlights Atsushi Tsuda Atmosphere and Ocean Research Institute, The University of Tokyo In the western Pacific (WESTPAC) region, dust originating from Asian and Australian arid regions to the North and South Pacific, biomass burning emissions from the Southeast Asia to sub-tropical Pacific, and other anthropogenic substances are transported regionally and globally to affect cloud and rainfall patterns, air quality, and radiative budgets downwind. Deposition of these compounds into the Asian marginal seas and onto the Pacific Ocean influence surface primary productivity and species composition. In the WESTPAC region, subarctic, subtropical oceans and marginal seas are located relatively narrow latitudinal range and these areas are influenced by the dust and anthropogenic inputs. Moreover, anthropogenic emission areas are located between the arid region and the oceans. The W-PASS (Western Pacific Air-Sea interaction Study) project has been funded for 5 years as a part of SOLAS-Japan activity in the summer of 2006. We aim to resolve air-sea interaction through field observation studies mainly using research vessels and island observatories over the western Pacific. We have carried out 5 cruises to the western North Pacific focusing on air-sea interactions. Also, an intensive marine atmospheric observation including direct atmospheric deposition measurement was accomplished by a dozen W-PASS research groups at the NIES Atmospheric and Aerosol Monitoring Station of Cape Hedo in the northernmost tip of the Okinawa main Island facing the East China Sea in the spring 2008. A few weak Kosa (dust) events, anthropogenic air outflows, typical local air and occupation of marine background air were identified during the campaign period. The W-PASS has four research groups mainly focusing on VOC emissions, air-sea gas exchange processes, biogeochemical responses to dust depositions and its modeling. We also

  4. GSOD Based Daily Global Mean Surface Temperature and Mean Sea Level Air Pressure (1982-2011)

    SciTech Connect

    Xuan Shi, Dali Wang

    2014-05-05

    This data product contains all the gridded data set at 1/4 degree resolution in ASCII format. Both mean temperature and mean sea level air pressure data are available. It also contains the GSOD data (1982-2011) from NOAA site, contains station number, location, temperature and pressures (sea level and station level). The data package also contains information related to the data processing methods

  5. Robust comparison of climate models with observations using blended land air and ocean sea surface temperatures

    NASA Astrophysics Data System (ADS)

    Cowtan, Kevin; Hausfather, Zeke; Hawkins, Ed; Jacobs, Peter; Mann, Michael E.; Miller, Sonya K.; Steinman, Byron A.; Stolpe, Martin B.; Way, Robert G.

    2015-08-01

    The level of agreement between climate model simulations and observed surface temperature change is a topic of scientific and policy concern. While the Earth system continues to accumulate energy due to anthropogenic and other radiative forcings, estimates of recent surface temperature evolution fall at the lower end of climate model projections. Global mean temperatures from climate model simulations are typically calculated using surface air temperatures, while the corresponding observations are based on a blend of air and sea surface temperatures. This work quantifies a systematic bias in model-observation comparisons arising from differential warming rates between sea surface temperatures and surface air temperatures over oceans. A further bias arises from the treatment of temperatures in regions where the sea ice boundary has changed. Applying the methodology of the HadCRUT4 record to climate model temperature fields accounts for 38% of the discrepancy in trend between models and observations over the period 1975-2014.

  6. Robust Comparison of Climate Models with Observations Using Blended Land Air and Ocean Sea Surface Temperatures

    NASA Astrophysics Data System (ADS)

    Hausfather, Z.; Jacobs, P.; Cowtan, K.; Hawkins, E.; Mann, M. E.; Miller, S. K.; Steinman, B. A.; Way, R. G.; Stolpe, M.

    2015-12-01

    Model-observation comparisons provide an important test of climate models' ability to realistically simulate the transient evolution of the system. A great deal of attention has recently focused on the so-called "hiatus" period of the past ~15 years, when estimates of recent surface temperature evolution fall at the lower end of climate model projections. This work quantifies a systematic bias in model-observation comparisons arising from differential warming rates between sea surface temperatures and surface air temperatures over oceans. Global mean temperatures from climate model simulations are typically calculated using surface air temperatures, while the corresponding observations are based on a blend of air and sea surface temperatures. A further bias arises from the treatment of temperatures in regions where the sea ice boundary has changed. We discuss the magnitude of these biases, and their implications for the evaluation of climate model performance over the "hiatus" period and the full instrumental record.

  7. Influence of Land-sea Breeze on Air Quality Over Taiwan Coastal Environment

    NASA Astrophysics Data System (ADS)

    Chang, J. S.; Chiang, C.

    2008-12-01

    Taiwan is is an island nation in western Pacific close to Mainland China. As such Land-sea breeze is a natural processes. Many major cities and industrial developments naturally developed near coastal area. As air quality in urban and industrial centers worsened impact on coastal areas increases. Land-sea breeze naturally plays an important role in transport of pollutants to and from polluted regions to the coastal environment. In this study we analyzed a full year of Taiwan EPA monitored hourly data on O3, NOx, CO, CO2, temperature, wind direction and speed to group and identify time and place with significant land-sea breeze phenomenon. We first compare coastal air quality condition with and without land-sea breeze and then use a 3-D regional-scale transport and chemistry model to provide detailed diagnostic interpretations of the coupling of pollution source regions and coastal areas. From this we can clarify when and how land-sea breeze may play a role in determining coastal air quality. Two different subregions of Taiwan are of interest in this study, Taipei and Kaoshiung environments, in the north and south of Taiwan respectively. Taipei is about 30-50 km away from its impacted coastal area while Kaoshiung is directly at and inland of its coastal shore. For Taipei region daytime upper air pollutants can be transported out to sea and then subside and return to the coastal area at night. But under summer severely polluted condition surface Taipei urban pollutants actually extend beyond the coastal area hence at night the return flow only brings back the same air mass. In contrast, Kaoshiung area is almost always under high pollution status. Its domain of influence always extends far beyond the coastal shore. Therefore, with and without land-sea breeze, coastal pollution remains about the same. We shall present detailed 2-D and 3-D data and station by station analyses in support of these findings.

  8. Air-sea heat exchange, an element of the water cycle

    NASA Technical Reports Server (NTRS)

    Chahine, M. T.

    1984-01-01

    The distribution and variation of water vapor, clouds and precipitation are examined. Principal driving forces for these distributions are energy exchange and evaporation at the air-sea interface, which are also important elements of air-sea interaction studies. The overall aim of air-sea interaction studies is to quantitatively determine mass, momentum and energy fluxes, with the goal of understanding the mechanisms controlling them. The results of general circulation simulations indicate that the atmosphere in mid-latitudes responds to changes in the oceanic surface conditions in the tropics. This correlation reflects the strong interaction between tropical and mid-latitude conditions caused by the transport of heat and momentum from the tropics. Studies of air-sea exchanges involve a large number of physica, chemical and dynamical processes including heat flux, radiation, sea-surface temperature, precipitation, winds and ocean currents. The fluxes of latent heat are studied and the potential use of satellite data in determining them evaluated. Alternative ways of inferring heat fluxes will be considered.

  9. Balloons and Bottles: Activities on Air-Sea Heat Exchange.

    ERIC Educational Resources Information Center

    Murphree, Tom

    1998-01-01

    Presents an activity designed to demonstrate how heating and cooling an air mass affects its temperature, volume, density, and pressure. Illustrates how thermal energy can cause atmospheric motion such as expansion, contraction, and winds. (Author/WRM)

  10. Experimental sea slicks: Their practical applications and utilization for basic studies of air-sea interactions

    NASA Astrophysics Data System (ADS)

    Hühnerfuss, Heinrich; Garrett, W. D.

    1981-01-01

    Practical applications of organic surface films added to the sea surface date back to ancient times. Aristotle, Plutarch, and Pliny the Elder describe the seaman's practice of calming waves in a storm by pouring oil onto the sea [Scott, 1977]. It was also noted that divers released oil beneath the water surface so that it could rise and spread over the sea surface, thereby suppressing the irritating flicker associated with the passage of light through a rippled surface. From a scientific point of view, Benjamin Franklin was the first to perform experiments with oils on natural waters. His experiment with a `teaspoonful of oil' on Clapham pond in 1773 inspired many investigators to consider sea surface phenomena or to conduct experiments with oil films. This early research has been reviewed by Giles [1969], Giles and Forrester [1970], and Scott [1977]. Franklin's studies with experimental slicks can be regarded as the beginning of surface film chemistry. His speculations on the wave damping influence of oil induced him to perform the first qualitative experiment with artificial sea slicks at Portsmouth (England) in October of 1773. Although the sea was calmed and very few white caps appeared in the oil-covered area, the swell continued through the oiled area to Franklin's great disappointment.

  11. Regulation of CO2 Air Sea Fluxes by Sediments in the North Sea

    NASA Astrophysics Data System (ADS)

    Burt, William; Thomas, Helmuth; Hagens, Mathilde; Brenner, Heiko; Pätsch, Johannes; Clargo, Nicola; Salt, Lesley

    2016-04-01

    A multi-tracer approach is applied to assess the impact of boundary fluxes (e.g. benthic input from sediments or lateral inputs from the coastline) on the acid-base buffering capacity, and overall biogeochemistry, of the North Sea. Analyses of both basin-wide observations in the North Sea and transects through tidal basins at the North-Frisian coastline, reveal that surface distributions of the δ13C signature of dissolved inorganic carbon (DIC) are predominantly controlled by a balance between biological production and respiration. In particular, variability in metabolic DIC throughout stations in the well-mixed southern North Sea indicates the presence of an external carbon source, which is traced to the European continental coastline using naturally-occurring radium isotopes (224Ra and 228Ra). 228Ra is also shown to be a highly effective tracer of North Sea total alkalinity (AT) compared to the more conventional use of salinity. Coastal inputs of metabolic DIC and AT are calculated on a basin-wide scale, and ratios of these inputs suggest denitrification as a primary metabolic pathway for their formation. The AT input paralleling the metabolic DIC release prevents a significant decline in pH as compared to aerobic (i.e. unbuffered) release of metabolic DIC. Finally, long-term pH trends mimic those of riverine nitrate loading, highlighting the importance of coastal AT production via denitrification in regulating pH in the southern North Sea.

  12. Impacts of South East Biomass Burning on local air quality in South China Sea

    NASA Astrophysics Data System (ADS)

    Wai-man Yeung, Irene; Fat Lam, Yun; Eniolu Morakinyo, Tobi

    2016-04-01

    Biomass burning is a significant source of carbon monoxide and particulate matter, which is not only contribute to the local air pollution, but also regional air pollution. This study investigated the impacts of biomass burning emissions from Southeast Asia (SEA) as well as its contribution to the local air pollution in East and South China Sea, including Hong Kong and Taiwan. Three years (2012 - 2014) of the Hybrid Single Particle Lagrangian-Integrated Trajectory (HYSPLIT) with particles dispersion analyses using NCEP (Final) Operational Global Analysis data (FNL) data (2012 - 2014) were analyzed to track down all possible long-range transport from SEA with a sinking motion that worsened the surface air quality (tropospheric downwash from the free troposphere). The major sources of SEA biomass burning emissions were first identified using high fire emissions from the Global Fire Emission Database (GFED), followed by the HYSPLIT backward trajectory dispersion modeling analysis. The analyses were compared with the local observation data from Tai Mo Shan (1,000 msl) and Tap Mun (60 msl) in Hong Kong, as well as the data from Lulin mountain (2,600 msl) in Taiwan, to assess the possible impacts of SEA biomass burning on local air quality. The correlation between long-range transport events from the particles dispersion results and locally observed air quality data indicated that the background concentrations of ozone, PM2.5 and PM10 at the surface stations were enhanced by 12 μg/m3, 4 μg/m3 and 7 μg/m3, respectively, while the long-range transport contributed to enhancements of 4 μg/m3, 4 μg/m3 and 8 μg/m3 for O3, PM2.5 and PM10, respectively at the lower free atmosphere.

  13. Linking air-sea energy exchanges and European anchovy potential spawning ground

    NASA Astrophysics Data System (ADS)

    Grammauta, R.; Molteni, D.; Basilone, G.; Guisande, C.; Bonanno, A.; Aronica, S.; Giacalone, G.; Fontana, I.; Zora, M.; Patti, B.; Cuttitta, A.; Buscaino, G.; Sorgente, R.; Mazzola, S.

    2008-10-01

    The physical and chemical processes of the sea greatly affect the reproductive biology of fishes, mainly influencing both the numbers of spawned eggs and the survivorship of early stages up to the recruitment period. In the central Mediterranean, the European anchovy constitutes one of the most important fishery resource. Because of its short living nature and of its recruitment variability, associated to high environmental variability, this small pelagic species undergo high interannual fluctuation in the biomass levels. Despite several efforts were addressed to characterize fishes spawning habitat from the oceanographic point of view, very few studies analyze the air-sea exchanges effects. To characterize the spawning habitat of these resources a specific technique (quotient rule analysis) was applied on air-sea heat fluxes, wind stress, sea surface temperature and turbulence data, collected in three oceanographic surveys during the summer period of 2004, 2005 and 2006. The results showed the existence of preferred values in the examined physical variables, associated to anchovy spawning areas. Namely, for heat fluxes the values were around -40 W/m2, for wind stress 0.04-0.11 N/m2, for SST 23°C, and 300 - 500 m3s-3 for wind mixing. Despite the obtained results are preliminary, this is the first relevant analysis on the air-sea exchanges and their relationship with the fish biology of pelagic species.

  14. The organic sea surface microlayer in the upwelling region off Peru and implications for air-sea exchange processes

    NASA Astrophysics Data System (ADS)

    Engel, A.; Galgani, L.

    2015-07-01

    The sea surface microlayer (SML) is at the very surface of the ocean, linking the hydrosphere with the atmosphere, and central to a range of global biogeochemical and climate-related processes. The presence and enrichment of organic compounds in the SML have been suggested to influence air-sea gas exchange processes as well as the emission of primary organic aerosols. Among these organic compounds, primarily of plankton origin, are dissolved exopolymers, specifically polysaccharides and proteins, and gel particles, such as Transparent Exopolymer Particles (TEP) and Coomassie Stainable Particles (CSP). These organic substances often accumulate in the surface ocean when plankton productivity is high. Here, we report results obtained in December 2012 during the SOPRAN Meteor 91 cruise to the highly productive, coastal upwelling regime off Peru. Samples were collected from the SML and from ~ 20 cm below, and were analyzed for polysaccharidic and proteinaceous compounds, gel particles, total and dissolved organic carbon, bacterial and phytoplankton abundance. Our study provides insight to the physical and biological control of organic matter enrichment in the SML, and discusses the potential role of organic matter in the SML for air-sea exchange processes.

  15. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model

    EPA Science Inventory

    Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions,...

  16. Variational iteration method for solving sea-air oscillator of the ENSO model

    NASA Astrophysics Data System (ADS)

    Noor, N. F. M.

    2015-10-01

    A class of sea-air oscillator of the El Nino-Southern Oscillation (ENSO) mechanism is considered. Variational iteration method (VIM) is applied to generate approximate solution to the system. Numerical VIM solutions obtained are then compared with results from the analytical solution and the Runge-Kutta-Fehlberg method of fourth-fifth order (RKF45).

  17. Air-sea interaction measurements in the west Mediterranean Sea during the Tyrrhenian Eddy Multi-Platform Observations Experiment

    SciTech Connect

    Schiano, M.E.; Santoleri, R.; Bignami, F.; Leonardi, R.M. ); Marullo, S. ); Boehm, E. )

    1993-02-15

    Measurements of radiative fluxes were carried out in the Tyrrhenian Sea in fall and winter as part of the Tyrrhenian Eddy Multi-Platform Observations Experiment (TEMPO). These measurements have supplied the first experimental radiation data set over this basin. Seasonal variation of the different components of the budget are investigated. Since data collection was carried out in an area in which a quasi-permanent eddy is present, the behavior of the radiation parameters across the frontal zone is analyzed. The most interesting result of the air-sea interaction in proximity of a marine front consists in the covariation of sea surface temperature and downwelling long-wave radiation. Contemporaneous satellite data show a clear correlation between sea surface structure and horizontal distribution of columnar atmospheric water content. Therefore this inhomogeneity clearly is one of the main factors responsible for the variation of the downwelling radiation across the front. A comparison between experimental data and results of some of the most widely used bulk formulae is carried out for both short- and long-wave radiation. The mean differnece between measured and empirical solar radiation values is less than 3%, while in the case of the net long-wave radiation budge, poor agreement is found. Indeed, a 30 W/m[sup 2] bias results from the comparison. This discrepancy is consistent with the imbalance between previous bulk calculations of total heat budget at the surface and corresponding hydrographical observations of heat exchange at Gibraltar. 30 refs., 6 figs., 9 tabs.

  18. Climatic Impacts of a Stochastic Parameterization of Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Williams, P. D.

    2014-12-01

    The atmosphere and ocean are coupled by the exchange of fluxes across the ocean surface. Air-sea fluxes vary partly on scales that are too small and fast to be resolved explicitly in numerical models of weather and climate, making them a candidate for stochastic parameterization. This presentation proposes a nonlinear physical mechanism by which stochastic fluctuations in the air-sea buoyancy flux may modify the mean climate, even though the mean fluctuation is zero. The mechanism relies on a fundamental asymmetry in the physics of the ocean mixed layer: positive surface buoyancy fluctuations cannot undo the vertical mixing caused by negative fluctuations. The mechanism has much in common with Stommel's mixed-layer demon. The presentation demonstrates the mechanism in climate simulations with a comprehensive coupled atmosphere-ocean general circulation model (SINTEX-G). In the SINTEX-G simulations with stochastic air-sea buoyancy fluxes, significant changes are detected in the time-mean oceanic mixed-layer depth, sea-surface temperature, atmospheric Hadley circulation, and net upward water flux at the sea surface. Also, El Niño Southern Oscillation (ENSO) variability is significantly increased. The findings demonstrate that noise-induced drift and noise-enhanced variability, which are familiar concepts from simple climate models, continue to apply in comprehensive climate models with millions of degrees of freedom. The findings also suggest that the lack of representation of sub-grid variability in air-sea fluxes may contribute to some of the biases exhibited by contemporary climate models.

  19. Air-sea interaction with SSM/I and altimeter

    NASA Technical Reports Server (NTRS)

    1985-01-01

    A number of important developments in satellite remote sensing techniques have occurred recently which offer the possibility of studying over vast areas of the ocean the temporally evolving energy exchange between the ocean and the atmosphere. Commencing in spring of 1985, passive and active microwave sensors that can provide valuable data for scientific utilization will start to become operational on Department of Defense (DOD) missions. The passive microwave radiometer can be used to estimate surface wind speed, total air column humidity, and rain rate. The active radar, or altimeter, senses surface gravity wave height and surface wind speed.

  20. Enhanced sea-air CO2 exchange influenced by a tropical depression in the South China Sea

    NASA Astrophysics Data System (ADS)

    Sun, Qingyang; Tang, DanLing; Legendre, Louis; Shi, Ping

    2014-10-01

    Ship measurements made 2 days after the passage of a tropical depression (TD) in the South China Sea (SCS, April 2011) showed two contrasted responses of the partial pressure of CO2 at sea surface (pCO2,sw). In low sea-surface salinity (SSS) water, pCO2,sw was low (349 ± 7 μatm), and the area was a carbon sink (-4.7 ± 1.8 mmol CO2 m-2 d-1), whereas in water with high SSS and chlorophyll a and low dissolved oxygen and sea surface temperature, pCO2,sw was higher than for normal SCS water (376 ± 8 versus 362 ± 4 μatm) and the area was a carbon source (1.2 ± 3.1 mmol CO2 m-2 d-1). Satellite data showed two large areas of low SSS before the TD, which were likely influenced by rainfall, and these areas were considered to have low pCO2,sw because of their low SSS. The high pCO2,sw after the TD is explained by the uplifting to the surface of deeper and CO2-rich water, due to winds accompanied by the TD. The difference in sea-air CO2 flux between the TD-affected area and the lower-SSS water was 1.99 + 4.70 = 6.7 mmol CO2 m-2 d-1, indicating a 100% change caused by the TD compared to the average seasonal value in spring in southern SCS (3.3 ± 0.3 mmol CO2 m-2 d-1). Undersaturation of CO2 prior to the TD due to dilution by freshwater and the preexisting cold eddy, and slow translation speed of the TD, are considered to account for the CO2 flux change.

  1. Impacts of air-sea exchange coefficients on snowfall events over the Korean Peninsula

    NASA Astrophysics Data System (ADS)

    Kang, Jung-Yoon; Kwon, Young Cheol

    2016-08-01

    Snowfall over the Korean Peninsula is mainly associated with air mass transformation by the fluxes across the air-sea interface during cold-air outbreaks over the warm Yellow Sea. The heat and momentum exchange coefficients in the surface flux parameterization are key parameters of flux calculations across the air-sea interface. This study investigates the effects of the air-sea exchange coefficients on the simulations of snowfall events over the Korean Peninsula using the Weather Research and Forecasting (WRF) model. Two snowfall cases are selected for this study. One is a heavy snowfall event that took place on January 4, 2010, and the other is a light snowfall event that occurred on December 23-24, 2011. Several sensitivity tests are carried out with increased and decreased heat and momentum exchange coefficients. The domain-averaged precipitation is increased (decreased) with increased (decreased) heat exchange coefficient because the increased (decreased) surface heat flux leads to more (less) moist conditions in the low level of the atmosphere. On the other hand, the domain-averaged precipitation is decreased (increased) with increased (decreased) momentum exchange coefficient because the increased (decreased) momentum coefficient causes reduction (increase) of wind speed and heat flux. The variation of precipitation in the heat exchange coefficient experiments is much larger than that in the momentum exchange coefficient experiments because the change of heat flux has a more direct impact on moisture flux and snowfall amount, while the change of momentum flux has a rather indirect impact via wind speed changes. The low-pressure system is intensified and moves toward North when the heat exchange coefficient is increased because warming and moistening of the lower atmosphere contributes to destabilize the air mass, resulting in the change of precipitation pattern over the Korean Peninsula in the heat exchange coefficient experiments.

  2. Air-sea interaction in the tropical Pacific Ocean

    NASA Technical Reports Server (NTRS)

    Allison, L. J.; Steranka, J.; Holub, R. J.; Hansen, J.; Godshall, F. A.; Prabhakara, C.

    1972-01-01

    Charts of 3-month sea surface temperature (SST) anomalies in the eastern tropical Pacific Ocean were produced for the period 1949 to 1970. The anomalies along the United States and South American west coasts and in the eastern tropical Pacific appeared to be oscillating in phase during this period. Similarly, the satellite-derived cloudiness for each of four quadrants of the Pacific Ocean (130 deg E to 100 deg W, 30 deg N to 25 deg S) appeared to be oscillating in phase. In addition, a global tropical cloudiness oscillation from 30 deg N to 30 deg S was noted from 1965 to 1970, by using monthly satellite television nephanalyses. The SST anomalies were found to have a good degree of correlation both positive and negative with the following monthly geophysical parameters: (1) satellite-derived cloudiness, (2) strength of the North and South Pacific semipermanent anticyclones, (3) tropical Pacific island rainfall, and (4) Darwin surface pressure. Several strong direct local and crossequatorial relationships were noted. In particular, the high degree of correlation between the tropical island rainfall and the SST anomalies (r = +0.93) permitted the derivation of SST's for the tropical Pacific back to 1905. The close occurrence of cold tropical SST and North Pacific 700-mb positive height anomalies with central United States drought conditions was noted.

  3. Sea Breeze Forcing of Estuary Turbulence and Air-Water Exchanges

    NASA Astrophysics Data System (ADS)

    Orton, P. M.; McGillis, W. R.; Zappa, C. J.

    2010-12-01

    The sea breeze is often a dominant meteorological feature at the coastline, but little is known about its estuarine impacts. It arises on sunny days with weak synoptic weather forcing, due to O(100 km) scale atmospheric pressure differences that develop as a result of the different solar absorption properties of sea and land. Here, measurements at an anchored catamaran and meteorological stations along the Hudson River and New York Bay estuarine system are used to illustrate some basic characteristics and impacts of the feature. The sea breeze propagates inland, arriving in phase with peak solar forcing at seaward stations, but several hours later at up-estuary stations. Passage of the sea breeze front raises the water-to-air CO2 flux by 1-2 orders of magnitude, and drives turbulence comparable to spring tide levels in the upper meter of the water column, where most primary productivity occurs in this highly turbid system. Modeling and observational studies often use remotely-measured winds with quadratic parameterizations to compute air-water fluxes (e.g. momentum, CO2), and this leads to a factor of two flux error on sea breeze days during the study. We conclude with a survey of how common these features are in the Hudson as well as other estuaries.

  4. Air-Sea Spray Airborne Radar Profiler Characterizes Energy Fluxes in Hurricanes

    NASA Technical Reports Server (NTRS)

    Durden, Stephen L.; Esteban-Fermandez, D.

    2010-01-01

    A report discusses ASAP (Air-sea Spray Airborne Profiler), a dual-wavelength radar profiler that provides measurement information about the droplet size distribution (DSD) of sea-spray, which can be used to estimate heat and moisture fluxes for hurricane research. Researchers have recently determined that sea spray can have a large effect on the magnitude and distribution of the air-sea energy flux at hurricane -force wind speeds. To obtain information about the DSD, two parameters of the DSD are required; for example, overall DSD amplitude and DSD mean diameter. This requires two measurements. Two frequencies are used, with a large enough separation that the differential frequency provides size information. One frequency is 94 GHz; the other is 220 GHz. These correspond to the Rayleigh and Mie regions. Above a surface wind speed of 10 m/ s, production of sea spray grows exponentially. Both the number of large droplets and the altitude they reach are a function of the surface wind speed.

  5. Effect of air-sea coupling on the frequency distribution of intense tropical cyclones over the northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Ogata, Tomomichi; Mizuta, Ryo; Adachi, Yukimasa; Murakami, Hiroyuki; Ose, Tomoaki

    2015-12-01

    Effect of air-sea coupling on the frequency distribution of intense tropical cyclones (TCs) over the northwestern Pacific (NWP) region is investigated using an atmosphere and ocean coupled general circulation model (AOGCM). Monthly varying flux adjustment enables AOGCM to simulate both subseasonal air-sea interaction and realistic seasonal to interannual sea surface temperature (SST) variability. The maximum of intense TC distribution around 20-30°N in the AGCM shifts equatorward in the AOGCM due to the air-sea coupling. Hence, AOGCM reduces northward intense TC distribution bias seen in AGCM. Over the NWP, AOGCM-simulated SST variability is large around 20-30°N where the warm mixed layer becomes shallower rapidly. Active entrainment from subsurface water over this region causes stronger SST cooling, and hence, TC intensity decreases. These results suggest that air-sea coupling characterized by subsurface oceanic condition causes more realistic distribution of intense TCs over the NWP.

  6. Intense air-sea exchange and heavy rainfall: impact of the northern Adriatic SST

    NASA Astrophysics Data System (ADS)

    Stocchi, P.; Davolio, S.

    2016-02-01

    Over the northern Adriatic basin, intense air-sea interactions are often associated with heavy precipitation over the mountainous areas surrounding the basin. In this study, a high-resolution mesoscale model is employed to simulate three severe weather events and to evaluate the effect of the sea surface temperature on the intensity and location of heavy rainfall. The sensitivity tests show that the impact of SST varies among the events and it mainly involves the modification of the PBL characteristics and thus the flow dynamics and its interaction with the orography.

  7. Development of an Eddy Covariance System for Air-Sea Carbon Dioxide Exchange

    NASA Astrophysics Data System (ADS)

    Miller, S. D.; Marandino, C. A.; McCormick, C.; Saltzman, E. S.

    2006-12-01

    We are developing a ship-based system to measure the air-sea pCO2 gradient and air-sea turbulent flux of CO2 over the ocean. The eddy covariance flux system uses off-the-shelf instruments to measure the turbulent wind vector (Campbell Scientific CSAT3 sonic anemometer), platform motion (Systron Donner Motion Pak II), and carbon dioxide molar density (LiCor 7000 Infrared Gas Analyzer). Two major sources of uncertainty in calculated fluxes are the effect of water vapor fluctuations on air density fluctuations (the WPL effect, Webb, Pearman and Leuning. 1980), and a spurious CO2 signal due to the sensitivity of the gas analyzer to platform motion (McGillis et al., 1998). Two flux systems were deployed side-by-side on a cruise from Manzanillo, Mexico to Puntas Arenas, Chile, in January 2006. Results from the cruise are presented, with a focus on our attempts to reduce biases in the calculated air-sea CO2 flux due to the WPL effect and the motion sensitivity of the gas analyzer.

  8. Updating Sea Spray Aerosol Emissions in the Community Multiscale Air Quality Model

    NASA Astrophysics Data System (ADS)

    Gantt, B.; Bash, J. O.; Kelly, J.

    2014-12-01

    Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions, include sea surface temperature (SST) dependency, and revise surf zone emissions. Based on evaluation with several regional and national observational datasets in the continental U.S., the updated emissions generally improve surface concentrations predictions of primary aerosols composed of sea-salt and secondary aerosols affected by sea-salt chemistry in coastal and near-coastal sites. Specifically, the updated emissions lead to better predictions of the magnitude and coastal-to-inland gradient of sodium, chloride, and nitrate concentrations at Bay Regional Atmospheric Chemistry Experiment (BRACE) sites near Tampa, FL. Including SST-dependency to the SSA emission parameterization leads to increased sodium concentrations in the southeast U.S. and decreased concentrations along the Pacific coast and northeastern U.S., bringing predictions into closer agreement with observations at most Interagency Monitoring of Protected Visual Environments (IMPROVE) and Chemical Speciation Network (CSN) sites. Model comparison with California Research at the Nexus of Air Quality and Climate Change (CalNex) observations will also be discussed, with particular focus on the South Coast Air Basin where clean marine air mixes with anthropogenic pollution in a complex environment. These SSA emission updates enable more realistic simulation of chemical processes in coastal environments, both in clean marine air masses and mixtures of clean marine and polluted conditions.

  9. Surfactant control of air-sea gas exchange across contrasting biogeochemical regimes

    NASA Astrophysics Data System (ADS)

    Pereira, Ryan; Schneider-Zapp, Klaus; Upstill-Goddard, Robert

    2014-05-01

    Air-sea gas exchange is important to the global partitioning of CO2.Exchange fluxes are products of an air-sea gas concentration difference, ΔC, and a gas transfer velocity, kw. The latter is controlled by the rate of turbulent diffusion at the air-sea interface but it cannot be directly measured and has a high uncertainty that is now considered one of the greatest challenges to quantifying net global air-sea CO2 exchange ...(Takahashi et al., 2009). One important control on kw is exerted by sea surface surfactants that arise both naturally from biological processes and through anthropogenic activity. They influence gas exchange in two fundamental ways: as a monolayer physical barrier and through modifying sea surface hydrodynamics and hence turbulent energy transfer. These effects have been demonstrated in the laboratory with artificial surfactants ...(Bock et al., 1999; Goldman et al., 1988) and through purposeful surfactant releases in coastal waters .(.).........().(Brockmann et al., 1982) and in the open ocean (Salter et al., 2011). Suppression of kwin these field experiments was ~5-55%. While changes in both total surfactant concentration and the composition of the natural surfactant pool might be expected to impact kw, the required in-situ studies are lacking. New data collected from the coastal North Sea in 2012-2013 shows significant spatio-temporal variability in the surfactant activity of organic matter within the sea surface microlayer that ranges from 0.07-0.94 mg/L T-X-100 (AC voltammetry). The surfactant activities show a strong winter/summer seasonal bias and general decrease in concentration with increasing distance from the coastline possibly associated with changing terrestrial vs. phytoplankton sources. Gas exchange experiments of this seawater using a novel laboratory tank and gas tracers (CH4 and SF6) demonstrate a 12-45% reduction in kw compared to surfactant-free water. Seasonally there is higher gas exchange suppression in the summer

  10. The Air-Sea Interface and Surface Stress under Tropical Cyclones

    NASA Astrophysics Data System (ADS)

    Soloviev, Alexander; Lukas, Roger; Donelan, Mark; Ginis, Isaac

    2013-04-01

    Air-sea interaction dramatically changes from moderate to very high wind speed conditions (Donelan et al. 2004). Unresolved physics of the air-sea interface are one of the weakest components in tropical cyclone prediction models. Rapid disruption of the air-water interface under very high wind speed conditions was reported in laboratory experiments (Koga 1981) and numerical simulations (Soloviev et al. 2012), which resembled the Kelvin-Helmholtz instability at an interface with very large density difference. Kelly (1965) demonstrated that the KH instability at the air-sea interface can develop through parametric amplification of waves. Farrell and Ioannou (2008) showed that gustiness results in the parametric KH instability of the air-sea interface, while the gusts are due to interacting waves and turbulence. The stochastic forcing enters multiplicatively in this theory and produces an exponential wave growth, augmenting the growth from the Miles (1959) theory as the turbulence level increases. Here we complement this concept by adding the effect of the two-phase environment near the mean interface, which introduces additional viscosity in the system (turning it into a rheological system). The two-phase environment includes air-bubbles and re-entering spray (spume), which eliminates a portion of the wind-wave wavenumber spectrum that is responsible for a substantial part of the air sea drag coefficient. The previously developed KH-type interfacial parameterization (Soloviev and Lukas 2010) is unified with two versions of the wave growth model. The unified parameterization in both cases exhibits the increase of the drag coefficient with wind speed until approximately 30 m/s. Above this wind speed threshold, the drag coefficient either nearly levels off or even slightly drops (for the wave growth model that accounts for the shear) and then starts again increasing above approximately 65 m/s wind speed. Remarkably, the unified parameterization reveals a local minimum

  11. Sensitivity of Global Sea-Air CO2 Flux to Gas Transfer Algorithms, Climatological Wind Speeds, and Variability of Sea Surface Temperature and Salinity

    NASA Technical Reports Server (NTRS)

    McClain, Charles R.; Signorini, Sergio

    2002-01-01

    Sensitivity analyses of sea-air CO2 flux to gas transfer algorithms, climatological wind speeds, sea surface temperatures (SST) and salinity (SSS) were conducted for the global oceans and selected regional domains. Large uncertainties in the global sea-air flux estimates are identified due to different gas transfer algorithms, global climatological wind speeds, and seasonal SST and SSS data. The global sea-air flux ranges from -0.57 to -2.27 Gt/yr, depending on the combination of gas transfer algorithms and global climatological wind speeds used. Different combinations of SST and SSS global fields resulted in changes as large as 35% on the oceans global sea-air flux. An error as small as plus or minus 0.2 in SSS translates into a plus or minus 43% deviation on the mean global CO2 flux. This result emphasizes the need for highly accurate satellite SSS observations for the development of remote sensing sea-air flux algorithms.

  12. Measuring important parameters for air-sea heat exchange

    NASA Astrophysics Data System (ADS)

    Garbe, Christoph; Schimpf, Uwe; Jaehne, Bernd

    2002-03-01

    The heat transfer between the ocean and the atmosphere is one of the most important parameters governing the global climate. Important parameters include the heat transfer velocity and the net heat flux as well as parameters of the underlying transport model. However, the net heat flux is hard to measure since processes take place in the thermal boundary layer, that is the topmost layer of the ocean less than 1 mm thick. Current techniques rely on three independent measurements of the constituent fluxes, the sensible heat flux, latent heat flux and radiative flux. They depend on indirect measurements of meteorological parameters and rely on a combination of data from different sensors using a number of heuristic assumptions. High relative errors and the need for long temporal averaging reduce the practicability of these techniques. In this paper a novel technique is presented that circumvents these drawbacks by directly measuring the net heat flux across the air-water interface with a single low-NETD infrared camera. A newly developed digital image processing technique allows to simultaneously estimating the surface velocity field and parameters of the temporal temperature change. In particular, this technique allows estimating the total derivative of the temperature with respect to time from a sequence of infrared images, together with error bounds on the estimates. This derivative can be used to compute the heat flux density and the heat transfer velocity, as well as the probability density function of the underlying surface renewal model. It is also possible to estimate the bulk-skin temperature difference given rise to by the net heat flux. Our technique has been successfully used in both laboratory measurements in the Heidelberg Aeolotron, as well as in field measurements in the equatorial pacific during the NOAA GasExII experiment this spring. The data show that heat flux measurements to an accuracy of better than 5% on a time scale of seconds are feasible.

  13. Mueller matrix imaging of targets under an air-sea interface.

    PubMed

    Zhai, Peng-Wang; Kattawar, George W; Yang, Ping

    2009-01-10

    The Mueller matrix imaging method is a powerful tool for target detection. In this study, the effect of the air-sea interface on the detection of underwater objects is studied. A backward Monte Carlo code has been developed to study this effect. The main result is that the reflection of the diffuse sky light by the interface reduces the Mueller image contrast. If the air-sea interface is ruffled by wind, the distinction between different regions of the underwater target is smoothed out. The effect of the finite size of an active light source is also studied. The image contrast is found to be relatively insensitive to the size of the light source. The volume scattering function plays an important role on the underwater object detection. Generally, a smaller asymmetry parameter decreases the contrast of the polarimetry images. PMID:19137035

  14. Size distribution of oceanic air bubbles entrained in sea-water by wave-breaking

    NASA Technical Reports Server (NTRS)

    Resch, F.; Avellan, F.

    1982-01-01

    The size of oceanic air bubbles produced by whitecaps and wave-breaking is determined. The production of liquid aerosols at the sea surface is predicted. These liquid aerosols are at the origin of most of the particulate materials exchanged between the ocean and the atmosphere. A prototype was designed and built using an optical technique based on the principle of light scattering at an angle of ninety degrees from the incident light beam. The output voltage is a direct function of the bubble diameter. Calibration of the probe was carried out within a range of 300 microns to 1.2 mm. Bubbles produced by wave-breaking in a large air-sea interaction simulating facility. Experimental results are given in the form of size spectrum.

  15. Small Autonomous Air/Sea System Concepts for Coast Guard Missions

    NASA Technical Reports Server (NTRS)

    Young, Larry A.

    2005-01-01

    A number of small autonomous air/sea system concepts are outlined in this paper that support and enhance U.S. Coast Guard missions. These concepts draw significantly upon technology investments made by NASA in the area of uninhabited aerial vehicles and robotic/intelligent systems. Such concepts should be considered notional elements of a greater as-yet-not-defined robotic system-of-systems designed to enable unparalleled maritime safety and security.

  16. An assessment of the Atlantic and Arctic sea-air CO2 fluxes, 1990-2009

    NASA Astrophysics Data System (ADS)

    Schuster, U.; McKinley, G. A.; Bates, N.; Chevallier, F.; Doney, S. C.; Fay, A. R.; González-Dávila, M.; Gruber, N.; Jones, S.; Krijnen, J.; Landschützer, P.; Lefèvre, N.; Manizza, M.; Mathis, J.; Metzl, N.; Olsen, A.; Rios, A. F.; Rödenbeck, C.; Santana-Casiano, J. M.; Takahashi, T.; Wanninkhof, R.; Watson, A. J.

    2013-01-01

    The Atlantic and Arctic Oceans are critical components of the global carbon cycle. Here we quantify the net sea-air CO2 flux, for the first time, across different methodologies for consistent time and space scales for the Atlantic and Arctic basins. We present the long-term mean, seasonal cycle, interannual variability and trends in sea-air CO2 flux for the period 1990 to 2009, and assign an uncertainty to each. We use regional cuts from global observations and modeling products, specifically a pCO2-based CO2 flux climatology, flux estimates from the inversion of oceanic and atmospheric data, and results from six ocean biogeochemical models. Additionally, we use basin-wide flux estimates from surface ocean pCO2 observations based on two distinct methodologies. Our estimate of the contemporary sea-air flux of CO2 (sum of anthropogenic and natural components) by the Atlantic between 40° S and 79° N is -0.49 ± 0.05 Pg C yr-1, and by the Arctic it is -0.12 ± 0.06 Pg C yr-1, leading to a combined sea-air flux of -0.61 ± 0.06 Pg C yr-1 for the two decades (negative reflects ocean uptake). We do find broad agreement amongst methodologies with respect to the seasonal cycle in the subtropics of both hemispheres, but not elsewhere. Agreement with respect to detailed signals of interannual variability is poor, and correlations to the North Atlantic Oscillation are weaker in the North Atlantic and Arctic than in the equatorial region and southern subtropics. Linear trends for 1995 to 2009 indicate increased uptake and generally correspond between methodologies in the North Atlantic, but there is disagreement amongst methodologies in the equatorial region and southern subtropics.

  17. Atlantic and Arctic sea-air CO2 fluxes, 1990-2009

    NASA Astrophysics Data System (ADS)

    Schuster, U.; McKinley, G. A.; Bates, N.; Chevallier, F.; Doney, S. C.; Fay, A. R.; González-Dávila, M.; Gruber, N.; Jones, S.; Krijnen, J.; Landschützer, P.; Lefèvre, N.; Manizza, M.; Mathis, J.; Metzl, N.; Olsen, A.; Rios, A. F.; Rödenbeck, C.; Santana-Casiano, J. M.; Takahashi, T.; Wanninkhof, R.; Watson, A. J.

    2012-08-01

    The Atlantic and Arctic oceans are critical components of the global carbon cycle. Here we quantify the net sea-air CO2 flux, for the first time, across different methodologies for consistent time and space scales, for the Atlantic and Arctic basins. We present the long-term mean, seasonal cycle, interannual variability and trends in sea-air CO2 flux for the period 1990 to 2009, and assign an uncertainty to each. We use regional cuts from global observations and modelling products, specifically a pCO2-based CO2 flux climatology, flux estimates from the inversion of oceanic and atmospheric data, and results from six ocean biogeochemical models. Additionally, we use basin-wide flux estimates from surface ocean pCO2 observations based on two distinct methodologies. Our best estimate of the contemporary sea-to-air flux of CO2 (sum of anthropogenic and natural components) by the Atlantic between 40° S and 79° N is -0.49 ± 0.11 Pg C yr-1 and by the Arctic is -0.12 ± 0.06 Pg C yr-1, leading to a combined sea-to-air flux of -0.61 ± 0.12 Pg C yr-1 for the two decades (negative reflects ocean uptake). We do find broad agreement amongst methodologies with respect to the seasonal cycle in the subtropics of both hemispheres, but not elsewhere. Agreement with respect to detailed signals of interannual variability is poor; and correlations to the North Atlantic Oscillation are weaker in the North Atlantic and Arctic than in the equatorial region and South Subtropics. Linear trends for 1995 to 2009 indicate increased uptake and generally correspond between methodologies in the North Atlantic, but there is disagreement amongst methodologies in the equatorial region and South Subtropics.

  18. Gulf of Mexico Air/Sea Interaction: Measurements and Initial Data Characterization

    NASA Astrophysics Data System (ADS)

    MacDonald, C.; Huang, C. H.; Roberts, P. T.; Bariteau, L.; Fairall, C. W.; Gibson, W.; Ray, A.

    2011-12-01

    Corporate, government, and university researchers collaborated to develop an atmospheric boundary layer environmental observations program on an offshore platform in the Gulf of Mexico. The primary goals of this project were to provide data to (1) improve our understanding of boundary layer processes and air-sea interaction over the Gulf of Mexico; (2) improve regional-scale meteorological and air quality modeling; and (3) provide a framework for advanced offshore measurements to support future needs such as emergency response, exploration and lease decisions, wind energy research and development, and meteorological and air quality forecasting. In October 2010, meteorological and oceanographic sensors were deployed for an extended period (approximately 12 months) on a Chevron service platform (ST 52B, 90.5W, 29N) to collect boundary layer and sea surface data sufficient to support these objectives. This project has significant importance given the large industrial presence in the Gulf, sizeable regional population nearby, and the recognized need for precise and timely pollutant forecasts. Observations from this project include surface meteorology; sodar marine boundary layer winds; microwave radiometer profiles of temperature, relative humidity, and liquid water; ceilometer cloud base heights; water temperature and current profiles; sea surface temperature; wave height statistics; downwelling solar and infrared radiation; and air-sea turbulent momentum and heat fluxes. This project resulted in the collection of an unprecedented set of boundary layer measurements over the Gulf of Mexico that capture the range of meteorological and oceanographic interactions and processes that occur over an entire year. This presentation will provide insight into the logistical and scientific issues associated with the deployment and operations of unique measurements in offshore areas and provide results from an initial data analysis of boundary layer processes over the Gulf of

  19. Temporal variability of air-sea CO2 exchange in a low-emission estuary

    NASA Astrophysics Data System (ADS)

    Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

    2016-07-01

    There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

  20. Distribution and Sea-to-air Flux of Nitrous Oxide in the East China Sea during the Summer of 2013

    NASA Astrophysics Data System (ADS)

    Wang, Lan; Zhang, Guiling; Zhu, Zhuoyi; Li, Jia; Liu, Sumei; Ye, Wangwang; Han, Yu

    2016-07-01

    Dissolved nitrous oxide (N2O) at different depths of 73 stations in the Changjiang (Yangtze River) Estuary and the East China Sea (ECS) were determined from August 4 to 31 of 2013, and the sea-to-air fluxes of N2O were also estimated in this study. N2O concentrations in the surface waters ranged from 6.33 to 44.40 nmol L-1 with an average of (9.27±4.30) nmol L-1 and the values in the bottom waters ranged from 5.19 to 26.98 nmol L-1 with an average of (11.87±3.71) nmol L-1. The concentrations of N2O decreased with distance from the Changjiang Estuary to the open sea. The vertical distributions of N2O indicated great spatial variations. A region of significant bottom-water hypoxia, with oxygen concentration less than 1.5 mg L-1, occurred at the north of the ECS, and increased bottom N2O concentrations was observed. Frequent vertical mixing may enhance the emission of N2O from this hypoxic area. N2O in the surface waters of all stations were over-saturated, and the N2O saturations ranged from 106% to 658%, with an average of (149±62)%. We estimated the sea-to-air fluxes of N2O as (30.6±59.1) μmol m-2 d-1 from the Changjiang Estuary, (9.8±8.8) μmol m-2 d-1 from the coastal and shelf, and (21.0±12.7) μmol m-2 d-1 from the continental slope using the Wanninkhof 1992 equation, (24.9±47.2) μmol m-2 d-1, (8.0±6.7) μmol m-2 d-1 and (16.5±9.6) μmol m-2 d-1 using the Nightingale 2000 equation, respectively. N2O emission from the ECS was estimated to be about (8.2-16.0)×10-2 Tg-N2O yr-1, suggesting that the ECS was a significant net source of atmospheric N2O.

  1. Direct measurements of air-sea CO2 exchange over a coral reef

    NASA Astrophysics Data System (ADS)

    McGowan, Hamish A.; MacKellar, Mellissa C.; Gray, Michael A.

    2016-05-01

    Quantification of CO2 exchange with the atmosphere over coral reefs has relied on microscale measurements of pCO2 gradients across the air-sea interfacial boundary; shipboard measurements of air-sea CO2 exchange over adjacent ocean inferred to represent over reef processes or ecosystem productivity modeling. Here we present by way of case study the first direct measurements of air-sea CO2 exchange over a coral reef made using the eddy covariance method. Research was conducted during the summer monsoon over a lagoonal platform reef in the southern Great Barrier Reef, Australia. Results show the reef flat to be a net source of CO2 to the atmosphere of similar magnitude as coastal lakes, while adjacent shallow and deep lagoons were net sinks as was the surrounding ocean. This heterogeneity in CO2 exchange with the atmosphere confirms need for spatially representative direct measurements of CO2 over coral reefs to accurately quantify their role in atmospheric carbon budgets.

  2. A reconciliation of empirical and mechanistic models of the air-sea gas transfer velocity

    NASA Astrophysics Data System (ADS)

    Goddijn-Murphy, Lonneke; Woolf, David K.; Callaghan, Adrian H.; Nightingale, Philip D.; Shutler, Jamie D.

    2016-01-01

    Models of the air-sea transfer velocity of gases may be either empirical or mechanistic. Extrapolations of empirical models to an unmeasured gas or to another water temperature can be erroneous if the basis of that extrapolation is flawed. This issue is readily demonstrated for the most well-known empirical gas transfer velocity models where the influence of bubble-mediated transfer, which can vary between gases, is not explicitly accounted for. Mechanistic models are hindered by an incomplete knowledge of the mechanisms of air-sea gas transfer. We describe a hybrid model that incorporates a simple mechanistic view—strictly enforcing a distinction between direct and bubble-mediated transfer—but also uses parameterizations based on data from eddy flux measurements of dimethyl sulphide (DMS) to calibrate the model together with dual tracer results to evaluate the model. This model underpins simple algorithms that can be easily applied within schemes to calculate local, regional, or global air-sea fluxes of gases.

  3. Sensitivity of the air-sea CO2 exchange in the Baltic Sea and Danish inner waters to atmospheric short-term variability

    NASA Astrophysics Data System (ADS)

    Lansø, A. S.; Bendtsen, J.; Christensen, J. H.; Sørensen, L. L.; Chen, H.; Meijer, H. A. J.; Geels, C.

    2015-05-01

    Minimising the uncertainties in estimates of air-sea CO2 exchange is an important step toward increasing the confidence in assessments of the CO2 cycle. Using an atmospheric transport model makes it possible to investigate the direct impact of atmospheric parameters on the air-sea CO2 flux along with its sensitivity to, for example, short-term temporal variability in wind speed, atmospheric mixing height and atmospheric CO2 concentration. With this study, the importance of high spatiotemporal resolution of atmospheric parameters for the air-sea CO2 flux is assessed for six sub-basins within the Baltic Sea and Danish inner waters. A new climatology of surface water partial pressure of CO2 (pCO2w) has been developed for this coastal area based on available data from monitoring stations and on-board pCO2w measuring systems. Parameterisations depending on wind speed were applied for the transfer velocity to calculate the air-sea CO2 flux. Two model simulations were conducted - one including short-term variability in atmospheric CO2 (VAT), and one where it was not included (CAT). A seasonal cycle in the air-sea CO2 flux was found for both simulations for all sub-basins with uptake of CO2 in summer and release of CO2 to the atmosphere in winter. During the simulated period 2005-2010, the average annual net uptake of atmospheric CO2 for the Baltic Sea, Danish straits and Kattegat was 287 and 471 Gg C yr-1 for the VAT and CAT simulations, respectively. The obtained difference of 184 Gg C yr-1 was found to be significant, and thus ignoring short-term variability in atmospheric CO2 does have a sizeable effect on the air-sea CO2 exchange. The combination of the atmospheric model and the new pCO2w fields has also made it possible to make an estimate of the marine part of the Danish CO2 budget for the first time. A net annual uptake of 2613 Gg C yr-1 was found for the Danish waters. A large uncertainty is connected to the air-sea CO2 flux in particular caused by the transfer

  4. Sensitivity of the air-sea CO2 exchange in the Baltic Sea and Danish inner waters to atmospheric short term variability

    NASA Astrophysics Data System (ADS)

    Lansø, A. S.; Bendtsen, J.; Christensen, J. H.; Sørensen, L. L.; Chen, H.; Meijer, H. A. J.; Geels, C.

    2014-12-01

    Minimising the uncertainties in estimates of air-sea CO2 exchange is an important step toward increasing the confidence in assessments of the CO2 cycle. Using an atmospheric transport model makes it possible to investigate the direct impact of atmospheric parameters on the air-sea CO2 flux along with its sensitivity to e.g. short-term temporal variability in wind speed, atmospheric mixing height and the atmospheric CO2 concentration. With this study the importance of high spatiotemporal resolution of atmospheric parameters for the air-sea CO2 flux is assessed for six sub-basins within the Baltic Sea and Danish inner waters. A new climatology of surface water partial pressure of CO2 (pCO2) has been developed for this coastal area based on available data from monitoring stations and underway pCO2 measuring systems. Parameterisations depending on wind speed were applied for the transfer velocity to calculate the air-sea CO2 flux. Two model simulations were conducted - one including short term variability in atmospheric CO2 (VAT), and one where it was not included (CAT). A seasonal cycle in the air-sea CO2 flux was found for both simulations for all sub-basins with uptake of CO2 in summer and release of CO2 to the atmosphere in winter. During the simulated period 2005-2010 the average annual net uptake of atmospheric CO2 for the Baltic Sea, Danish Straits and Kattegat was 287 and 471 Gg C yr-1 for the VAT and CAT simulations, respectively. The obtained difference of 184 Gg C yr-1 was found to be significant, and thus ignoring short term variability in atmospheric CO2 does have a sizeable effect on the air-sea CO2 exchange. The combination of the atmospheric model and the new pCO2 fields has also made it possible to make an estimate of the marine part of the Danish CO2 budget for the first time. A net annual uptake of 2613 Gg C yr-1 was found for the Danish waters. A large uncertainty is connected to the air-sea CO2 flux in particular caused by the transfer velocity

  5. Effect of Air-Sea coupling on the Frequency Distribution of Intense Tropical Cyclones over the Northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Ogata, Tomomichi; Mizuta, Ryo; Adachi, Yukimasa; Murakami, Hiroyuki; Ose, Tomomaki

    2016-04-01

    Effect of air-sea coupling on the frequency distribution of intense tropical cyclones (TCs) over the northwestern Pacific (NWP) region is investigated using an atmosphere and ocean coupled general circulation model (AOGCM). Monthly varying flux adjustment enables AOGCM to simulate both subseasonal air-sea interaction and realistic seasonal to interannual SST variability. The maximum of intense TC distribution around 20-30°N in the AGCM shifts equatorward in the AOGCM due to the air-sea coupling. Hence AOGCM reduces northward intense TC distribution bias seen in AGCM. Over the NWP, AOGCM-simulated SST variability is large around 20-30°N where the warm mixed layer becomes shallower rapidly. Active entrainment from subsurface water over this region causes stronger SST cooling and hence TC intensity decreases. These results suggest that air-sea coupling characterized by subsurface oceanic condition causes more realistic distribution of intense TCs over the NWP.

  6. Sea-air CO2 fluxes in the Southern Ocean for the period 1990-2009

    NASA Astrophysics Data System (ADS)

    Lenton, A.; Tilbrook, B.; Law, R.; Bakker, D.; Doney, S. C.; Gruber, N.; Hoppema, M.; Ishii, M.; Lovenduski, N. S.; Matear, R. J.; McNeil, B. I.; Metzl, N.; Mikaloff Fletcher, S. E.; Monteiro, P.; Rödenbeck, C.; Sweeney, C.; Takahashi, T.

    2013-01-01

    The Southern Ocean (44° S-75° S) plays a critical role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Different approaches have been used to estimate sea-air CO2 fluxes in this region: synthesis of surface ocean observations, ocean biogeochemical models, and atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Southern Ocean sea-air CO2 fluxes between 1990-2009. Using all models and inversions (26), the integrated median annual sea-air CO2 flux of -0.42 ± 0.07 Pg C yr-1 for the 44° S-75° S region is consistent with the -0.27 ± 0.13 Pg C yr-1 calculated using surface observations. The circumpolar region south of 58° S has a small net annual flux (model and inversion median: -0.04 ± 0.07 Pg C yr-1 and observations: +0.04 ± 0.02 Pg C yr-1), with most of the net annual flux located in the 44° S to 58° S circumpolar band (model and inversion median: -0.36 ± 0.09 Pg C yr-1 and observations: -0.35 ± 0.09 Pg C yr-1). Seasonally, in the 44° S-58° S region, the median of 5 ocean biogeochemical models captures the observed sea-air CO2 flux seasonal cycle, while the median of 11 atmospheric inversions shows little seasonal change in the net flux. South of 58° S, neither atmospheric inversions nor ocean biogeochemical models reproduce the phase and amplitude of the observed seasonal sea-air CO2 flux, particularly in the Austral Winter. Importantly, no individual atmospheric inversion or ocean biogeochemical model is capable of reproducing both the observed annual mean uptake and the observed seasonal cycle. This raises concerns about projecting future changes in Southern Ocean CO2 fluxes. The median interannual variability from atmospheric inversions and ocean biogeochemical models is substantial in the Southern Ocean; up to 25% of the annual mean flux with 25% of this

  7. Sea surface carbon dioxide at the Georgia time series site (2006-2007): Air-sea flux and controlling processes

    NASA Astrophysics Data System (ADS)

    Xue, Liang; Cai, Wei-Jun; Hu, Xinping; Sabine, Christopher; Jones, Stacy; Sutton, Adrienne J.; Jiang, Li-Qing; Reimer, Janet J.

    2016-01-01

    Carbon dioxide partial pressure (pCO2) in surface seawater was continuously recorded every three hours from 18 July 2006 through 31 October 2007 using a moored autonomous pCO2 (MAPCO2) system deployed on the Gray's Reef buoy off the coast of Georgia, USA. Surface water pCO2 (average 373 ± 52 μatm) showed a clear seasonal pattern, undersaturated with respect to the atmosphere in cold months and generally oversaturated in warm months. High temporal resolution observations revealed important events not captured in previous ship-based observations, such as sporadically occurring biological CO2 uptake during April-June 2007. In addition to a qualitative analysis of the primary drivers of pCO2 variability based on property regressions, we quantified contributions of temperature, air-sea exchange, mixing, and biological processes to monthly pCO2 variations using a 1-D mass budget model. Although temperature played a dominant role in the annual cycle of pCO2, river inputs especially in the wet season, biological respiration in peak summer, and biological production during April-June 2007 also substantially influenced seawater pCO2. Furthermore, sea surface pCO2 was higher in September-October 2007 than in September-October 2006, associated with increased river inputs in fall 2007. On an annual basis this site was a moderate atmospheric CO2 sink, and was autotrophic as revealed by monthly mean net community production (NCP) in the mixed layer. If the sporadic short productive events during April-May 2007 were missed by the sampling schedule, one would conclude erroneously that the site is heterotrophic. While previous ship-based pCO2 data collected around this buoy site agreed with the buoy CO2 data on seasonal scales, high resolution buoy observations revealed that the cruise-based surveys undersampled temporal variability in coastal waters, which could greatly bias the estimates of air-sea CO2 fluxes or annual NCP, and even produce contradictory results.

  8. Hurricane Frances as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS) and SeaWinds

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This image shows Hurricane Frances as captured by instruments onboard two different satellites: the AIRS infrared instrument onboard Aqua, and the SeaWinds scatterometer onboard QuikSCAT. Both are JPL-managed instruments. AIRS data are used to create global three-dimensional maps of temperature, humidity and clouds, while scatterometers measure surface wind speed and direction over the ocean.

    The red vectors in the image show Frances' surface winds as measured by SeaWinds on QuikSCAT. The background colors show the temperature of clouds and surface as viewed in the infrared by AIRS, with cooler areas pushing to purple and warmer areas are pushing to red. The color scale on the right gives the temperatures in degrees Kelvin. (The top of the scale, 320 degrees Kelvin, corresponds to 117 degrees Fahrenheit, and the bottom, 180 degrees K is -135 degrees F.) The powerful circulation of this storm is evident from the combined data as well as the development of a clearly-defined central 'eye'. The infrared signal does not penetrate through clouds, so the light blue areas reveal the cold clouds tops associated with strong thunderstorms embedded within the storm. In cloud-free areas the infrared signal comes from Earth's surface, revealing warmer temperatures.

    The power of the SeaWinds scatterometer data set lies in its ability to generate global maps of wind speed and direction, giving us a snapshot of how the atmosphere is circulating. Weather prediction centers, including the Tropical Prediction Center - a branch of NOAA that monitors the creation of ocean-born storms, use scatterometer data to help it 'see' where these storms are brewing so that warnings can be issued and the storms, with often erratic motions, can be tracked.

    While the SeaWinds instrument isn't designed to gather hurricane data, having difficulty seeing the surface in heavy rain, it's data can be used in combination with other data sets to give us an insight into these storms. In

  9. Impact of air-sea interaction on East Asian summer monsoon climate in WRF

    NASA Astrophysics Data System (ADS)

    Kim, Eun-Jung; Hong, Song-You

    2010-10-01

    This study investigates the effects of air-sea interaction on the simulated East Asian summer monsoon (EASM) climate in a regional climate model. An ocean mixed layer model with a revised surface roughness length formulation that was originally designed for tropical cyclone simulation and a prognostic sea surface skin temperature scheme that considers the heat budget at the water surface are systematically evaluated on the monsoonal climate over East Asia for July 2006 in the regional Weather Research and Forecasting (WRF) model. Also, 9-year (2000-2008) June-August simulations are performed to evaluate the overall impacts of these three components on the simulated EASM climatology. The 1 month simulation for July 2006 reveals that the inclusion of the ocean mixed layer model cools the water surface due to enhanced mixing, in particular, when winds are strong. Such cooling is largely compensated by the inclusion of prognostic skin temperature since solar heating in daytime overwhelms the cooling in nighttime. The revised surface roughness length effectively reduces the surface heat flux by reducing the exchange coefficients, against the conventional Charnock formula. Consideration of the three components together results in the reduction of systemic biases of excessive precipitation and weakening of the North Pacific high in the summer climate from 2000 to 2008. It is concluded that the methodology designed in this study can be an efficient way to represent the air-sea interaction in regional atmospheric models for numerical weather prediction and climate simulation.

  10. Impacts of Air-Sea Interaction on Tropical Cyclone Track and Intensity

    NASA Technical Reports Server (NTRS)

    Wu, Liguang; Wang, Bin; Braun, Scott A.

    2004-01-01

    The influence of hurricane-ocean coupling on intensity and track of tropical cyclones (TCs) is investigated through idealized numerical experiments using a coupled hurricane-ocean model. The focus is placed on how air-sea interaction affects TC tracks and intensity. It is found that the symmetric sea surface temperature (SST) cooling is primarily responsible for the TC weakening in the coupled experiments because the induced asymmetric circulation associated with the asymmetric SST anomalies is weak and shallow. The track difference between the coupled and fixed SST experiments is generally small because of the competing processes. One is associated with the modified TC asymmetries. The asymmetric SST anomalies - weaken the surface fluxes in the rear and enhance the fluxes in the front. As a result, the enhanced diabatic heating is located on the southern side for a westward-moving TC, tending to shift the TC southward. The symmetric SST anomalies weakens the TC intensity and thus the dymmetrization process, leading to more prominent TC asymmetries. The other is associated with the weakening of the beta drift resulting from the weakening of the TC outer strength. In the coupled experiment, the weakening of the beta drift leads to a more northward shift. By adjusting the vortex outer strength of the initial vortices, the beta drift can vary while the effect of air-sea interaction changes little. Two types of track differences simulated in the previous numerical studies are obtained.

  11. Air-sea exchange of carbon dioxide in the Southern Ocean and Antarctic marginal ice zone

    NASA Astrophysics Data System (ADS)

    Butterworth, Brian J.; Miller, Scott D.

    2016-07-01

    Direct carbon dioxide flux measurements using eddy covariance from an icebreaker in the high-latitude Southern Ocean and Antarctic marginal ice zone are reported. Fluxes were combined with the measured water-air carbon dioxide partial pressure difference (ΔpCO2) to compute the air-sea gas transfer velocity (k, normalized to Schmidt number 660). The open water data showed a quadratic relationship between k (cm h-1) and the neutral 10 m wind speed (U10n, m s-1), kopen = 0.245 U10n2 + 1.3, in close agreement with decades old tracer-based results and much lower than cubic relationships inferred from previous open ocean eddy covariance studies. In the marginal ice zone, the effective gas transfer velocity decreased in proportion to sea ice cover, in contrast with predictions of enhanced gas exchange in the presence of sea ice. The combined open water and marginal ice zone results affect the calculated magnitude and spatial distribution of Southern Ocean carbon flux.

  12. Distribution and air-sea exchange of organochlorine pesticides in the North Pacific and the Arctic

    NASA Astrophysics Data System (ADS)

    Cai, Minghong; Ma, Yuxin; Xie, Zhiyong; Zhong, Guangcai; MöLler, Axel; Yang, Haizhen; Sturm, Renate; He, Jianfeng; Ebinghaus, Ralf; Meng, Xiang-Zhou

    2012-03-01

    Surface seawater and boundary layer air samples were collected on the icebreaker Xuelong (Snow Dragon) during the Fourth Chinese Arctic Research Expedition (CHINARE2010) cruise in the North Pacific and Arctic Oceans during 2010. Samples were analyzed for organochlorine pesticides (OCPs), including three isomers of hexachlorocyclohexane (HCH), hexachlorobenzene (HCB), and two isomers of heptachlor epoxide. The gaseous total HCH (ΣHCHs) concentrations were approximately four times lower (average 12.0 pg m-3) than those measured during CHINARE2008 (average 51.4 pg m-3), but were comparable to those measured during CHINARE2003 (average 13.4 pg m-3) in the same study area. These changes are consistent with the evident retreat of sea ice coverage from 2003 to 2008 and increase of sea ice coverage from 2008 to 2009 and 2010. Gaseous β-HCH concentrations in the atmosphere were typically below the method detection limit, consistent with the expectation that ocean currents provide the main transport pathway for β-HCH into the Arctic. The concentrations of all dissolved HCH isomers in seawater increase with increasing latitude, and levels of dissolved HCB also increase (from 5.7 to 7.1 pg L-1) at high latitudes (above 73°N). These results illustrate the role of cold condensation processes in the transport of OCPs. The observed air-sea gas exchange gradients in the Arctic Ocean mainly favored net deposition of OCPs, with the exception of those for β-HCH, which favored volatilization.

  13. Sea surface microlayers: A unified physicochemical and biological perspective of the air-ocean interface

    NASA Astrophysics Data System (ADS)

    Cunliffe, Michael; Engel, Anja; Frka, Sanja; Gašparović, Blaženka; Guitart, Carlos; Murrell, J. Colin; Salter, Matthew; Stolle, Christian; Upstill-Goddard, Robert; Wurl, Oliver

    2013-02-01

    The sea surface microlayer (SML) covers more than 70% of the Earth's surface and is the boundary layer interface between the ocean and the atmosphere. This important biogeochemical and ecological system is critical to a diverse range of Earth system processes, including the synthesis, transformation and cycling of organic material, and the air-sea exchange of gases, particles and aerosols. In this review we discuss the SML paradigm, taking into account physicochemical and biological characteristics that define SML structure and function. These include enrichments in biogenic molecules such as carbohydrates, lipids and proteinaceous material that contribute to organic carbon cycling, distinct microbial assemblages that participate in air-sea gas exchange, the generation of climate-active aerosols and the accumulation of anthropogenic pollutants with potentially serious implications for the health of the ocean. Characteristically large physical, chemical and biological gradients thus separate the SML from the underlying water and the available evidence implies that the SML retains its integrity over wide ranging environmental conditions. In support of this we present previously unpublished time series data on bacterioneuston composition and SML surfactant activity immediately following physical SML disruption; these imply timescales of the order of minutes for the reestablishment of the SML following disruption. A progressive approach to understanding the SML and hence its role in global biogeochemistry can only be achieved by considering as an integrated whole, all the key components of this complex environment.

  14. Air-sea Exchange of Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs), Organochlorine Pesticides (OCPs) and Polybrominated Diphenyl Ethers (PBDEs) in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Lammel, G. P.; Heil, A.; Kukucka, P.; Meixner, F. X.; Mulder, M. D.; Prybilova, P.; Prokes, R.; Rusina, T. S.; Song, G. Z.; Vrana, B.

    2015-12-01

    The marine atmospheric environment is a receptor for persistent organic pollutants (POPs) which are advected from sources on land, primary, such as biomass burning by-products (PAHs, dioxins), and secondary, such as volatilization from contaminated soils (PCBs, pesticides). Primary sources do not exist in the marine environment, except for PAHs (ship engines) but following previous atmospheric deposition, the sea surface may turn to a secondary source by reversal of diffusive air-sea mass exchange. No monitoring is in place. We studied the vertical fluxes of a wide range of primary and secondary emitted POPs based on measurements in air and surface seawater at a remote coastal site in the eastern Mediterranean (2012). To this end, silicon rubbers were used as passive water samplers, vertical concentration gradients were determined in air and fluxes were quantified based on Eddy covariance. Diffusive air-sea exchange fluxes of hexachlorocyclohexanes (HCHs) and semivolatile PAHs were found close to phase equilibrium, except one PAH, retene, a wood burning tracer, was found seasonally net-volatilisational. Some PCBs, p,p'-DDE, penta- and hexachlorobenzene (PeCB, HCB) were mostly net-depositional, while PBDEs were net-volatilizational. Fluxes determined at a a remote coastal site ranged -33 - +2.4 µg m-2 d-1 for PAHs and -4.0 - +0.3 µg m-2 d-1for halogenated compounds (< 0 means net-deposition, > 0 means net-volatilization). It is concluded that nowadays in open seas more pollutants are undergoing reversal of the direction of air-sea exchange. Recgional fire activity records in combination with box model simulations suggest that deposition of retene during summer is followed by a reversal of air-sea exchange. The seawater surface as secondary source of pollution should be assessed based on flux measurements across seasons and over longer time periods.

  15. Sea level oscillations in coastal waters of the Buenos Aires province, Argentina

    NASA Astrophysics Data System (ADS)

    Dragani, W. C.; Mazio, C. A.; Nuñez, M. N.

    2002-03-01

    Sea level oscillations, with periods ranging from a few minutes to almost 2 h, have been observed at various tide stations located on the coast of Buenos Aires. Simultaneous records of sea level elevation measured in Mar de Ajó, Pinamar and Mar del Plata during 1982 have been spectrally analyzed. Significant spectral energy has been detected between 0.85 and 4.69 cycles per hour (cph) and the most energetic peaks have frequencies between 1.17 and 1.49 cph. Spectra, coherence, and phase difference have been analyzed for the most energetic event of the year. During that event, the most intensive spectral peak is at 1.17 cph for Mar de Ajó and Pinamar, and at 1.49 cph for Mar del Plata. Simultaneous total energy peaks at Mar de Ajó, Pinamar and Mar del Plata, and the coherence function estimated between Mar de Ajó and Pinamar suggests that sea level oscillations could be a regional phenomenon. The analyzed data suggest that sea level oscillations could be forced by atmospheric gravity waves associated with frontal passages.

  16. Air-Sea Exchange Of CO2: A Multi-Technology Approach

    NASA Astrophysics Data System (ADS)

    Tengberg, A.; Almroth, E.; Anderson, L.; Hall, P.; Hjalmarsson, S.; Lefevre, D.; Omstedt, A.; Rutgersson, A.; Sahlee, E.; Smedman, A.; Wesslander, K.

    2006-12-01

    We report on experiences and results from a multidisciplinary project in which we try to elucidate the complex processes involved in air-sea exchange of CO2. This study was performed in the Baltic Sea (off the Swedish island Gotland) and combined the following technologies: - Meteorological measurements of wind, turbulence, temperature, humidity, humidity flux, CO2 and CO2 flux at several levels from a fixed observation tower - Hourly PCO2 measurements with a moored automatic instrument - Collection of dissolved oxygen, temperature, salinity and turbidity data at different levels in the water column at 1-minute intervals - Daily light (PAR) and primary production measurements obtained with a moored automatic incubator - Daily primary production measurements using manual methods - Use of an acoustic current profiler to collect water column information on currents, turbulence, water level and waves - Repetitive water column profiles, from a ship, of dissolved inorganic carbon, oxygen, nutrients, alkalinity, pH, PAR, Chlorophyll A, salinity and temperature

  17. Ocean Carbon Cycling and CO2 Air-Sea Exchange in Eastern Boundary Upwelling Systems

    NASA Astrophysics Data System (ADS)

    Plattner, G.; Gruber, N.; Lachkar, Z.; Frenzel, H.; Loher, D.

    2008-12-01

    Eastern boundary current (EBC) upwelling systems are regions of intense biogeochemical transformations and transports. Strong upwelling of nutrient- and carbon-rich waters tends to lead to CO2 outgassing nearshore and biologically-driven CO2 uptake offshore. Yet, the net air-sea CO2 balance of EBCs remains unknown. High near-shore productivity coupled with filaments and other meso- and submesoscale phenomena cause a substantial lateral export of organic carbon. We investigate these coastal processes in the California Current (CalCS) and the Canary Current Systems (CanCS), on the basis of the eddy-resolving, physical-biogeochemical model ROMS. Our results confirm the onshore-offshore trends in the air-sea fluxes, with substantial spatial and temporal differences due to topography, upwelling strength, and eddy activity. The CalCS is modeled to be, on average, a very small source of CO2 to the atmosphere, consistent with a recent data-based estimate by Chavez and Takahashi, while for the CanCS this is not clear yet. Regarding offshore transport, the CalCS appears to be stronger than the CanCS. Spatio-temporal variability of all carbon fluxes is substantial, particularly nearshore, posing a tremendous challenge for observing systems targeting e.g. air-sea CO2 fluxes in these dynamic regions. Further analyses of the processes that determine the mean carbon fluxes and their spatio-temporal variability will be presented. Characteristic differences and similarities between the two EBC systems will be discussed.

  18. Weak ENSO asymmetry due to weak nonlinear air-sea interaction in CMIP5 climate models

    NASA Astrophysics Data System (ADS)

    Sun, Yan; Wang, Fan; Sun, De-Zheng

    2016-03-01

    State-of-the-art climate models have long-standing intrinsic biases that limit their simulation and projection capabilities. Significantly weak ENSO asymmetry and weakly nonlinear air-sea interaction over the tropical Pacific was found in CMIP5 (Coupled Model Intercomparison Project, Phase 5) climate models compared with observation. The results suggest that a weak nonlinear air-sea interaction may play a role in the weak ENSO asymmetry. Moreover, a weak nonlinearity in air-sea interaction in the models may be associated with the biases in the mean climate—the cold biases in the equatorial central Pacific. The excessive cold tongue bias pushes the deep convection far west to the western Pacific warm pool region and suppresses its development in the central equatorial Pacific. The deep convection has difficulties in further moving to the eastern equatorial Pacific, especially during extreme El Ni˜no events, which confines the westerly wind anomaly to the western Pacific. This weakens the eastern Pacific El Ni˜no events, especially the extreme El Ni˜no events, and thus leads to the weakened ENSO asymmetry in climate models. An accurate mean state structure (especially a realistic cold tongue and deep convection) is critical to reproducing ENSO events in climate models. Our evaluation also revealed that ENSO statistics in CMIP5 climate models are slightly improved compared with those of CMIP3. The weak ENSO asymmetry in CMIP5 is closer to the observation. It is more evident in CMIP5 that strong ENSO activities are usually accompanied by strong ENSO asymmetry, and the diversity of ENSO amplitude is reduced.

  19. The marine boundary layer - new findings from the Östergarnsholm air-sea interaction site

    NASA Astrophysics Data System (ADS)

    Smedman, A.; Högström, U.

    2003-04-01

    From studies at the air-sea interaction site Östergarnsholm, a coherent picture of how waves interact with the atmosphere is now beginning to emerge. It is clear that the surface of the ocean behaves similar to that of a solid surface with regard to the turbulence structure in the surface layer only for conditions of pure wind sea, i.e. during the phase when waves are in the process of being built up by increasing wind. At that stage of wave development, the dominant waves are short and move slowly relative to the wind. Then the drag coefficient CDN is a function only of the wave age, expressed as u*/c_p (where u* is friction velocity and c_p is the phase velocity of the dominant waves). The relation obtained by us is identical to the corresponding expression obtained from several recent ocean experiments, Drennan et al. (2000). As soon as the wave field develops behind the "pure wind sea" stage towards conditions where relatively long waves start to gain importance, inter-actions caused by these longer waves are felt in the atmosphere at our lowest turbulence measuring height, 10 m. For example it is demonstrated that the logarithmic wind law is not valid in near-neutral conditions except when pure wind sea conditions prevail and, further that for mixed seas and swell conditions, CDN is a function not only of the wave age parameter u*/c_p but also of a second wave parameter E_1/E_2, which is a measure of the proportion of energy of relatively long waves to short waves. The neutral Stanton Number, CHN, is found to follow predictions from surface-renewal theory quite well for unstable conditions up to a wind speed of about 10 ms-1. For higher wind speed CHN increases with increasing wind speed and the interpretation is made that spray is the cause of the increase.

  20. Air-sea CO2 fluxes in the East China Sea based on multiple-year underway observations

    NASA Astrophysics Data System (ADS)

    Guo, X.-H.; Zhai, W.-D.; Dai, M.-H.; Zhang, C.; Bai, Y.; Xu, Y.; Li, Q.; Wang, G.-Z.

    2015-09-01

    This study reports the most comprehensive data set thus far of surface seawater pCO2 (partial pressure of CO2) and the associated air-sea CO2 fluxes in a major ocean margin, the East China Sea (ECS), based on 24 surveys conducted in 2006 to 2011. We showed highly dynamic spatial variability in sea surface pCO2 in the ECS except in winter, when it ranged across a narrow band of 330 to 360 μatm. We categorized the ECS into five different domains featuring with different physics and biogeochemistry to better characterize the seasonality of the pCO2 dynamics and to better constrain the CO2 flux. The five domains are (I) the outer Changjiang estuary and Changjiang plume, (II) the Zhejiang-Fujian coast, (III) the northern ECS shelf, (IV) the middle ECS shelf, and (V) the southern ECS shelf. In spring and summer, pCO2 off the Changjiang estuary was as low as < 100 μatm, while it was up to > 400 μatm in autumn. pCO2 along the Zhejiang-Fujian coast was low in spring, summer and winter (300 to 350 μatm) but was relatively high in autumn (> 350 μatm). On the northern ECS shelf, pCO2 in summer and autumn was > 340 μatm in most areas, higher than in winter and spring. On the middle and southern ECS shelf, pCO2 in summer ranged from 380 to 400 μatm, which was higher than in other seasons (< 350 μatm). The area-weighted CO2 flux on the entire ECS shelf was -10.0 ± 2.0 in winter, -11.7 ± 3.6 in spring, -3.5 ± 4.6 in summer and -2.3 ± 3.1 mmol m-2 d-1 in autumn. It is important to note that the standard deviations in these flux ranges mostly reflect the spatial variation in pCO2 rather than the bulk uncertainty. Nevertheless, on an annual basis, the average CO2 influx into the entire ECS shelf was 6.9 ± 4.0 mmol m-2 d-1, about twice the global average in ocean margins.

  1. Air-sea CO2 fluxes in the East China Sea based on multiple-year underway observations

    NASA Astrophysics Data System (ADS)

    Guo, X.-H.; Zhai, W.-D.; Dai, M.-H.; Zhang, C.; Bai, Y.; Xu, Y.; Li, Q.; Wang, G.-Z.

    2015-04-01

    This study reports thus far a most comprehensive dataset of surface seawater pCO2 (partial pressure of CO2) and the associated air-sea CO2 fluxes in a major ocean margin, the East China Sea (ECS) based on 24 surveys conducted in 2006 to 2011. We showed highly dynamic spatial variability of sea surface pCO2 in the ECS except in winter when it ranged in a narrow band of 330 to 360 μatm. In this context, we categorized the ECS into five different domains featured with different physics and biogeochemistry to better characterize the seasonality of the pCO2 dynamics and to better constrain the CO2 flux. The five domains are (I) the outer Changjiang estuary and Changjiang plume, (II) the Zhejiang-Fujian coast, (III) the northern ECS shelf, (IV) the middle ECS shelf, and (V) the southern ECS shelf. In spring and summer, pCO2 off the Changjiang estuary was as low as < 100 μatm, while it was up to > 400 μatm in fall. pCO2 along the Zhejiang-Fujian coast was low in spring, summer and winter (300 to 350 μatm) but was relatively high in fall (> 350 μatm). In the northern ECS shelf, pCO2 in summer and fall was > 340 μatm in most areas, higher than in winter and spring. In the middle and southern ECS shelf, pCO2 in summer ranged from 380 to 400 μatm, which was higher than in other seasons (< 350 μatm). The area-weighted CO2 flux in the entire ECS shelf was -10.0 ± 2.0 mmol m-2 d-1 in winter, -11.7 ± 3.6 mmol m-2 d-1 in spring, -3.5 ± 4.6 mmol m-2 d-1 in summer and -2.3 ± 3.1 mmol m-2 d-1 in fall. It is important to note that the standard deviations in these flux ranges mostly reflect the spatial variation of pCO2, which differ from the spatial variance nor the bulk uncertainty. Nevertheless, on an annual basis, the average CO2 influx into the entire ECS shelf was -6.9 ± 4.0 mmol m-2 d-1, about twice the global average in ocean margins.

  2. Air-sea interaction during an extreme cold air outbreak from the eastern coast of the United States

    NASA Technical Reports Server (NTRS)

    Grossman, Robert L.; Betts, Alan K.

    1990-01-01

    An aircraft investigation of boundary layer mean and turbulent structure is reported, and the Lagrangian budgets of temperature and moisture in the subcloud layer following a streamline during an extreme cold air outbreak are evaluated. The maximum sea-air temperature difference was 23 K. Two aircraft were used: the NCAR Electra, which measured turbulent fluxes and investigated subcloud layer conditions, and the NASA Electra, which measured the height of cloud tops using lidar. A stratocumulus overcast was found from about 60 km offshore to the Gulf Stream core with cloud top rising downstream. East of the Gulf Stream cumulus congestus and snow showers were observed. Cloud base decreased downstream and numerous steam plumes filled the subcloud layer. Temperature cross sections show most warming, and moistening of the subcloud layer occurred before the Gulf Stream core. Windspeeds increased downstream and maxima were observed near cloud top (inversion) and in the subcloud layer. Lagrangian budgets showed most warming, and moistening of the layer between 70 m and about 100 m below mean cloud base was due to turbulent flux divergence.

  3. Large conversion rates of NO2 to HNO2 observed in air masses from the South China Sea: Evidence of strong production at sea surface?

    NASA Astrophysics Data System (ADS)

    Zha, Qiaozhi; Xue, Likun; Wang, Tao; Xu, Zheng; Yeung, Chungpong; Louie, Peter K. K.; Luk, Connie W. Y.

    2014-11-01

    Nitrous acid (HONO) plays important roles in tropospheric chemistry, but its source(s) are not completely understood. Here we analyze measurements of HONO, nitrogen dioxide (NO2), and related parameters at a coastal site in Hong Kong during September-December 2012. The nocturnal NO2-to-HONO conversion rates were estimated in air masses passing over land and sea surfaces. The conversion rates in the "sea cases" (3.17-3.36 × 10-2 h-1) were significantly higher than those in the "land cases" in our study (1.20-1.30 × 10-2 h-1) and in previous studies by others. These results suggest that air-sea interactions may be a significant source of atmospheric HONO and need to be considered in chemical transport models.

  4. Breaking waves and near-surface sea spray aerosol dependence on changing winds: Wave breaking efficiency and bubble-related air-sea interaction processes

    NASA Astrophysics Data System (ADS)

    Hwang, P. A.; Savelyev, I. B.; Anguelova, M. D.

    2016-05-01

    Simultaneous measurements of sea spray aerosol (SSA), wind, wave, and microwave brightness temperature are obtained in the open ocean on-board Floating Instrument Platform (FLIP). These data are analysed to clarify the ocean surface processes important to SSA production. Parameters are formulated to represent surface processes with characteristic length scales spanning a broad range. The investigation reveals distinct differences of the SSA properties in rising winds and falling winds, with higher SSA volume in falling winds. Also, in closely related measurements of whitecap coverage, higher whitecap fraction as a function of wind speed is found in falling winds than in rising winds or in older seas than in younger seas. Similar trend is found in the short scale roughness reflected in the microwave brightness temperature data. In the research of length and velocity scales of breaking waves, it has been observed that the length scale of wave breaking is shorter in mixed seas than in wind seas. For example, source function analysis of short surface waves shows that the characteristic length scale of the dissipation function shifts toward higher wavenumber (shorter wavelength) in mixed seas than in wind seas. Similarly, results from feature tracking or Doppler analysis of microwave radar sea spikes, which are closely associated with breaking waves, show that the magnitude of the average breaking wave velocity is smaller in mixed seas than in wind seas. Furthermore, breaking waves are observed to possess geometric similarity. Applying the results of breaking wave analyses to the SSA and whitecap observations described above, it is suggestive that larger air cavities resulting from the longer breakers are entrained in rising high winds. The larger air cavities escape rapidly due to buoyancy before they can be fully broken down into small bubbles for the subsequent SSA production or whitecap manifestation. In contrast, in falling winds (with mixed seas more likely), the

  5. Combined land/sea surface-air-temperature trends, 1949-1972

    SciTech Connect

    Chen, R.S.

    1982-04-01

    A major deficiency in most previous studies of fluctuations in the earth's climate based on air temperature records has been the dearth of data from oceanic areas and the Southern Hemisphere. This study analyzes a unique collection of ship-based observations of surface air temperature assembled by the UK Meteorological Office in parallel with the station-based dataset developed by the National Center for Atmospheric Research from the publications World Weather Records and Monthly Climatic Data for the World. Based on this much more geographically comprehensive database, it is concluded that, during the 24-year period 1949 to 1972, no statistically significant warming or cooling trends were evident in the time series of globally averaged surface air temperature measurements. However, temperature trends did vary latitudinally, with significant cooling in northern extra-tropical latitudes, no trend in equatorial latitudes, and significant but not homogeneous warming in southern extra-tropical latitudes. Time series of air temperatures over land and sea exhibited qualitatively similar behavior over the period 1949 to 1972, indicative of both the comparable quality of the two datasets and the probable lack of significant widespread bias in the land-based measurements due to urban development. The results of this study underscore the need for dense and geographically comprehensive measurements from both land and ocean areas and from both hemispheres in analyzing the global behavior of the earth's climate.

  6. The Aeroclipper: A new instrument for quasi-Lagrangian measurements at the air-sea interface

    NASA Astrophysics Data System (ADS)

    Duvel, J. P.; Reverdin, G.; Pichon, T.; Vargas, A.

    The Aeroclipper is a new balloon developed by CNES. The Aeroclipper is a balloon equipped with a cable extended by a guide-rope in contact with the surface of the ocean. The balloon is vertically stabilised at a given height (currently 40 to 60m above the sea surface) and move on quasi-Lagrangian trajectories depending on the surface wind. LMD (Laboratoire de Méteorologie Dynamique), LodyC (Laboratoire d'océanographie physique et de Climatologie) and ENSTA (Ecole Nationale Supérieure de Techniques Avancées) developed an instrumentation adapted to this new measurement system. This instrumentation is distributed on one atmospheric gondola and one oceanic gondola. The aim is to measure surface physical parameters (Air and sea surface temperatures, sea surface salinity, wind, pressure and humidity) and to derive turbulent fluxes of moisture, heat and momentum. The Aeroclippers will give legs of the different parameters at a relatively high spatial resolution and thus information on the perturbation of these parameters at mesoscale. A first test of the full system will be performed from Banyuls (France) during spring 2004. The first scientific use of the Aeroclipper is planned in February 2005 in the Indian Ocean South of the Equator in link with the pilot phase of the Vasco (Variability of the Atmosphere at the intra-Seasonal time scale and Coupling with the Ocean) experiment.

  7. Decline of hexachlorocyclohexane in the Arctic atmosphere and reversal of air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Bidleman, T. F.; Jantunen, L. M.; Falconer, R. L.; Barrie, L. A.; Fellin, P.

    1995-02-01

    Hexachlorocyclohexanes (HCHs) are the most abundant organochlorine pesticides in the arctic atmosphere and ocean surface water. A compilation of measurements made between 1979-93 from stations in the Canadian and Norwegian Arctic and from cruises in the Bering and Chukchi seas indicates that atmospheric concentrations of α-HCH have declined significantly (p < 0.01), with a time for 50% decrease of about 4 y in summer-fall and 6 y in winter-spring. The 1992-93 levels of about 100 pg m-3 are 2-4 fold lower than values in the mid-1980s. The trend in γ-HCH is less pronounced, but a decrease is also suggested from measurements in the Canadian Arctic and the Bering-Chukchi seas. HCHs in ocean surface water have remained relatively constant since the early 1980s. The decline in atmospheric α-HCH has reversed the net direction of air-sea gas exchange to the point where some northern waters are now sources of the pesticide to the atmosphere instead of sinks.

  8. Air-sea gas transfer for two gases of different solubility (CO2 and O2)

    NASA Astrophysics Data System (ADS)

    Rutgersson, A.; Andersson, A.; Sahlée, E.

    2016-05-01

    At the land-based marine measuring site Östergarnsholm in the Baltic Sea, the eddy covariance technique was used to measure air-sea fluxes of carbon dioxide and oxygen. High- frequency measurements of oxygen were taken with a Microx TX3 optode using the luminescence lifetime technique. The system gives reasonable oxygen fluxes after the limited frequency response of the sensor was corrected for. For fluxes of carbon dioxide the LICOR-7500 instrument was used. Using flux data to estimate transfer velocities indicates higher transfer velocity for oxygen compared to carbon dioxide for winds above 5 m/s. There are too few data for any extensive conclusions, but a least-square fit of the data gives a cubic wind speed dependence of oxygen corresponding to k 660 = 0.074U 3 10. The more effective transfer for oxygen compared to carbon dioxide above 5 m/s is most likely due to enhanced efficiency of oxygen exchange across the surface. Oxygen has lower solubility compared with carbon dioxide and might be more influenced by near surface processes such as microscale wave breaking or sea spray.

  9. Cold air outbreaks along a non-frozen sea channel: effects of wind on snow bands

    NASA Astrophysics Data System (ADS)

    Savijärvi, Hannu

    2015-08-01

    Wintertime cold air outbreaks along a non-frozen sea channel or a long lake can become destructive if the related bands of heavy snowfall hit onto land. The forcing for such bands is studied with a 2D numerical model set across an east-west sea channel at 60oN (`Gulf of Finland'), varying the basic geostrophic wind V g. Without any V g opposite coastal land breezes emerge with convergence. This results in a quasi-steady rising motion w max ~ 7.5 cm/s at 600 m in the middle of the gulf, which can force a snow band. During weak V g, the rising motion is reduced but least so for winds from 60o to 80o (~ENE), when modest alongshore bands could exist near the downstream (Estonian) coast. During V g of 4-6 m/s from any direction, the land breezes and rising motions are reduced more effectively, so snow bands are not expected during moderate basic flow. In contrast, during a strong V g of 20-25 m/s from 110o to 120o (~ESE) the land breeze perturbations are intense with w max up to 15-18 cm/s. The induced alongshore bands of heavy snowfall are located in these cases at the sea but quite close to the downstream (Finnish) coast. They can suddenly make a landfall if the basic wind turns clockwise.

  10. Characterization of air contaminants formed by the interaction of lava and sea water.

    PubMed

    Kullman, G J; Jones, W G; Cornwell, R J; Parker, J E

    1994-05-01

    We made environmental measurements to characterize contaminants generated when basaltic lava from Hawaii's Kilauea volcano enters sea water. This interaction of lava with sea water produces large clouds of mist (LAZE). Island winds occasionally directed the LAZE toward the adjacent village of Kalapana and the Hawaii Volcanos National Park, creating health concerns. Environmental samples were taken to measure airborne concentrations of respirable dust, crystalline silica and other mineral compounds, fibers, trace metals, inorganic acids, and organic and inorganic gases. The LAZE contained quantifiable concentrations of hydrochloric acid (HCl) and hydrofluoric acid (HF); HCl was predominant. HCl and HF concentrations were highest in dense plumes of LAZE near the sea. The HCl concentration at this sampling location averaged 7.1 ppm; this exceeds the current occupational exposure ceiling of 5 ppm. HF was detected in nearly half the samples, but all concentrations were <1 ppm Sulfur dioxide was detected in one of four short-term indicator tube samples at approximately 1.5 ppm. Airborne particulates were composed largely of chloride salts (predominantly sodium chloride). Crystalline silica concentrations were below detectable limits, less than approximately 0.03 mg/m3 of air. Settled dust samples showed a predominance of glass flakes and glass fibers. Airborne fibers were detected at quantifiable levels in 1 of 11 samples. These fibers were composed largely of hydrated calcium sulfate. These findings suggest that individuals should avoid concentrated plumes of LAZE near its origin to prevent over exposure to inorganic acids, specifically HCl. PMID:8593853

  11. Evaluation of the swell effect on the air-sea gas transfer in the coastal zone

    NASA Astrophysics Data System (ADS)

    Gutiérrez-Loza, Lucía; Ocampo-Torres, Francisco J.

    2016-04-01

    Air-sea gas transfer processes are one of the most important factors regarding global climate and long-term global climate changes. Despite its importance, there is still a huge uncertainty on how to better parametrize these processes in order to include them on the global climate models. This uncertainty exposes the need to increase our knowledge on gas transfer controlling mechanisms. In the coastal regions, breaking waves become a key factor to take into account when estimating gas fluxes, however, there is still a lack of information and the influence of the ocean surface waves on the air-sea interaction and gas flux behavior must be validated. In this study, as part of the "Sea Surface Roughness as Air-Sea Interaction Control" project, we evaluate the effect of the ocean surface waves on the gas exchange in the coastal zone. Direct estimates of the flux of CO2 (FCO2) and water vapor (FH2O) through eddy covariance, were carried out from May 2014 to April 2015 in a coastal station located at the Northwest of Todos Santos Bay, Baja California, México. For the same period, ocean surface waves are recorded using an Acoustic Doppler Current Profiler (Workhorse Sentinel, Teledyne RD Instruments) with a sampling rate of 2 Hz and located at 10 m depth about 350 m away from the tower. We found the study area to be a weak sink of CO2 under moderate wind and wave conditions with a mean flux of -1.32 μmol/m2s. The correlation between the wind speed and FCO2 was found to be weak, suggesting that other physical processes besides wind may be important factors for the gas exchange modulation at coastal waters. The results of the quantile regression analysis computed between FCO2 and (1) wind speed, (2) significant wave height, (3) wave steepness and (4) water temperature, show that the significant wave height is the most correlated parameter with FCO2; Nevertheless, the behavior of their relation varies along the probability distribution of FCO2, with the linear regression

  12. Resolving the abundance and air-sea fluxes of airborne microorganisms in the North Atlantic Ocean

    PubMed Central

    Mayol, Eva; Jiménez, María A.; Herndl, Gerhard J.; Duarte, Carlos M.; Arrieta, Jesús M.

    2014-01-01

    Airborne transport of microbes may play a central role in microbial dispersal, the maintenance of diversity in aquatic systems and in meteorological processes such as cloud formation. Yet, there is almost no information about the abundance and fate of microbes over the oceans, which cover >70% of the Earth's surface and are the likely source and final destination of a large fraction of airborne microbes. We measured the abundance of microbes in the lower atmosphere over a transect covering 17° of latitude in the North Atlantic Ocean and derived estimates of air-sea exchange of microorganisms from meteorological data. The estimated load of microorganisms in the atmospheric boundary layer ranged between 6 × 104 and 1.6 × 107 microbes per m2 of ocean, indicating a very dynamic air-sea exchange with millions of microbes leaving and entering the ocean per m2 every day. Our results show that about 10% of the microbes detected in the boundary layer were still airborne 4 days later and that they could travel up to 11,000 km before they entered the ocean again. The size of the microbial pool hovering over the North Atlantic indicates that it could play a central role in the maintenance of microbial diversity in the surface ocean and contribute significantly to atmospheric processes. PMID:25400625

  13. Air-sea temperature decoupling in western Europe during the last interglacial-glacial transition

    NASA Astrophysics Data System (ADS)

    Sánchez Goñi, María Fernanda; Bard, Edouard; Landais, Amaelle; Rossignol, Linda; D'Errico, Francesco

    2013-10-01

    A period of continental ice growth between about 80,000 and 70,000 years ago was controlled by a decrease in summer insolation, and was among the four largest ice expansions of the past 250,000 years. The moisture source for this ice sheet expansion, known as the Marine Isotope Stage (MIS) 5a/4 transition, has been proposed to be the warm subpolar and northern subtropical Atlantic Ocean. However, the mechanism by which glaciers kept growing through three suborbital cooling events within this period, which were associated with iceberg discharge in the North Atlantic and cooling over Greenland, is unclear. Here we reconstruct parallel records of sea surface and air temperatures from marine microfossil and pollen data, respectively, from two sediment cores collected within the northern subtropical gyre. The thermal gradient between the cold air and warmer sea increased throughout the MIS5a/4 transition, and was marked by three intervals of even more pronounced thermal gradients associated with the C20, C19 and C18' cold events. We argue that the warm ocean surface along the western European margin provided a source of moisture that was transported, through northward-tracking storms, to feed ice sheets in colder Greenland, northern Europe and the Arctic.

  14. The air-sea interface and surface stress under tropical cyclones.

    PubMed

    Soloviev, Alexander V; Lukas, Roger; Donelan, Mark A; Haus, Brian K; Ginis, Isaac

    2014-01-01

    Tropical cyclone track prediction is steadily improving, while storm intensity prediction has seen little progress in the last quarter century. Important physics are not yet well understood and implemented in tropical cyclone forecast models. Missing and unresolved physics, especially at the air-sea interface, are among the factors limiting storm predictions. In a laboratory experiment and coordinated numerical simulation, conducted in this work, the microstructure of the air-water interface under hurricane force wind resembled Kelvin-Helmholtz shear instability between fluids with a large density difference. Supported by these observations, we bring forth the concept that the resulting two-phase environment suppresses short gravity-capillary waves and alters the aerodynamic properties of the sea surface. The unified wave-form and two-phase parameterization model shows the well-known increase of the drag coefficient (Cd) with wind speed, up to ~30 ms(-1). Around 60 ms(-1), the new parameterization predicts a local peak of Ck/Cd, under constant enthalpy exchange coefficient Ck. This peak may explain rapid intensification of some storms to major tropical cyclones and the previously reported local peak of lifetime maximum intensity (bimodal distribution) in the best-track records. The bimodal distribution of maximum lifetime intensity, however, can also be explained by environmental parameters of tropical cyclones alone. PMID:24930493

  15. Resolving the abundance and air-sea fluxes of airborne microorganisms in the North Atlantic Ocean.

    PubMed

    Mayol, Eva; Jiménez, María A; Herndl, Gerhard J; Duarte, Carlos M; Arrieta, Jesús M

    2014-01-01

    Airborne transport of microbes may play a central role in microbial dispersal, the maintenance of diversity in aquatic systems and in meteorological processes such as cloud formation. Yet, there is almost no information about the abundance and fate of microbes over the oceans, which cover >70% of the Earth's surface and are the likely source and final destination of a large fraction of airborne microbes. We measured the abundance of microbes in the lower atmosphere over a transect covering 17° of latitude in the North Atlantic Ocean and derived estimates of air-sea exchange of microorganisms from meteorological data. The estimated load of microorganisms in the atmospheric boundary layer ranged between 6 × 10(4) and 1.6 × 10(7) microbes per m(2) of ocean, indicating a very dynamic air-sea exchange with millions of microbes leaving and entering the ocean per m(2) every day. Our results show that about 10% of the microbes detected in the boundary layer were still airborne 4 days later and that they could travel up to 11,000 km before they entered the ocean again. The size of the microbial pool hovering over the North Atlantic indicates that it could play a central role in the maintenance of microbial diversity in the surface ocean and contribute significantly to atmospheric processes. PMID:25400625

  16. The air-sea interface and surface stress under tropical cyclones

    NASA Astrophysics Data System (ADS)

    Soloviev, Alexander V.; Lukas, Roger; Donelan, Mark A.; Haus, Brian K.; Ginis, Isaac

    2014-06-01

    Tropical cyclone track prediction is steadily improving, while storm intensity prediction has seen little progress in the last quarter century. Important physics are not yet well understood and implemented in tropical cyclone forecast models. Missing and unresolved physics, especially at the air-sea interface, are among the factors limiting storm predictions. In a laboratory experiment and coordinated numerical simulation, conducted in this work, the microstructure of the air-water interface under hurricane force wind resembled Kelvin-Helmholtz shear instability between fluids with a large density difference. Supported by these observations, we bring forth the concept that the resulting two-phase environment suppresses short gravity-capillary waves and alters the aerodynamic properties of the sea surface. The unified wave-form and two-phase parameterization model shows the well-known increase of the drag coefficient (Cd) with wind speed, up to ~30 ms-1. Around 60 ms-1, the new parameterization predicts a local peak of Ck/Cd, under constant enthalpy exchange coefficient Ck. This peak may explain rapid intensification of some storms to major tropical cyclones and the previously reported local peak of lifetime maximum intensity (bimodal distribution) in the best-track records. The bimodal distribution of maximum lifetime intensity, however, can also be explained by environmental parameters of tropical cyclones alone.

  17. Ocean Winds and Turbulent Air-Sea Fluxes Inferred From Remote Sensing

    NASA Technical Reports Server (NTRS)

    Bourassa, Mark A.; Gille, Sarah T.; Jackson, Daren L.; Roberts, J. Brent; Wick, Gary A.

    2010-01-01

    Air-sea turbulent fluxes determine the exchange of momentum, heat, freshwater, and gas between the atmosphere and ocean. These exchange processes are critical to a broad range of research questions spanning length scales from meters to thousands of kilometers and time scales from hours to decades. Examples are discussed (section 2). The estimation of surface turbulent fluxes from satellite is challenging and fraught with considerable errors (section 3); however, recent developments in retrievals (section 3) will greatly reduce these errors. Goals for the future observing system are summarized in section 4. Surface fluxes are defined as the rate per unit area at which something (e.g., momentum, energy, moisture, or CO Z ) is transferred across the air/sea interface. Wind- and buoyancy-driven surface fluxes are called surface turbulent fluxes because the mixing and transport are due to turbulence. Examples of nonturbulent processes are radiative fluxes (e.g., solar radiation) and precipitation (Schmitt et al., 2010). Turbulent fluxes are strongly dependent on wind speed; therefore, observations of wind speed are critical for the calculation of all turbulent surface fluxes. Wind stress, the vertical transport of horizontal momentum, also depends on wind direction. Stress is very important for many ocean processes, including upper ocean currents (Dohan and Maximenko, 2010) and deep ocean currents (Lee et al., 2010). On short time scales, this horizontal transport is usually small compared to surface fluxes. For long-term processes, transport can be very important but again is usually small compared to surface fluxes.

  18. The air-sea interface and surface stress under tropical cyclones

    PubMed Central

    Soloviev, Alexander V.; Lukas, Roger; Donelan, Mark A.; Haus, Brian K.; Ginis, Isaac

    2014-01-01

    Tropical cyclone track prediction is steadily improving, while storm intensity prediction has seen little progress in the last quarter century. Important physics are not yet well understood and implemented in tropical cyclone forecast models. Missing and unresolved physics, especially at the air-sea interface, are among the factors limiting storm predictions. In a laboratory experiment and coordinated numerical simulation, conducted in this work, the microstructure of the air-water interface under hurricane force wind resembled Kelvin-Helmholtz shear instability between fluids with a large density difference. Supported by these observations, we bring forth the concept that the resulting two-phase environment suppresses short gravity-capillary waves and alters the aerodynamic properties of the sea surface. The unified wave-form and two-phase parameterization model shows the well-known increase of the drag coefficient (Cd) with wind speed, up to ~30 ms−1. Around 60 ms−1, the new parameterization predicts a local peak of Ck/Cd, under constant enthalpy exchange coefficient Ck. This peak may explain rapid intensification of some storms to major tropical cyclones and the previously reported local peak of lifetime maximum intensity (bimodal distribution) in the best-track records. The bimodal distribution of maximum lifetime intensity, however, can also be explained by environmental parameters of tropical cyclones alone. PMID:24930493

  19. Micrometeorological survey of air-sea ice CO2 fluxes in arctic coastal waters

    NASA Astrophysics Data System (ADS)

    Heinesch, Bernard; Tison, Jean-Louis; Carnat, Gauthier; Heicken, Hajo; Geilfus, Nicolas-Xavier; Goosens, Thomas; Papakyriakou, Tim; Yernaux, Michel; Delille, Bruno

    2010-05-01

    We carried out a 6 month study that aimed to robustly track CO2 exchange between land-fast sea-ice and the atmosphere during the winter and spring season. A meteorological mast equipped for eddy-covariance measurements was installed on land-fast sea-ice near Barrow (Alaska), 1 km off the coast, from the end of January 2009 to the beginning of June 2009, before ice break-up. These data were supported by continuous measurements of solar radiation, snow depth, ice thickness and temperature profile in the ice. Biogeochemical data necessary for the understanding of the CO2 dynamics in sea-ice were obtained through discrete ice coring. Two regimes were detected for the CO2 exchanges linked with the status of the sea-ice: a winter regime and a spring summer regime. From 27 of March onwards brine volume at the sea ice-snow interface was above the threshold of permeability for liquid according to Golden et al (1998). During this period, we observed some conspicuous CO2 fluxes events tightly linked to wind speed. The flux was directed from the sea-ice to the atmosphere and reached up to 0.6 umol m-2 s-1 (51.8 mmol m-2 d-1). This flux to the atmosphere is expected as sea-ice at the air interface is permeable during a large part of the period and brines are oversaturated compared to the atmosphere. CO2 may accumulate in the snow layer which thus acts as a buffer that is flushed under occurrence of high wind speeds and associated pressure pumping. During the spring-summer period i.e. from 27 of April onwards, we observed a marked increase in sea ice temperature. Temperature profiles suggest that convective events occurred within the ice cover between April 27 and May 05. Within these convective events, two regimes were observed. First, for a period of 5 days, pCO2 was still above the threshold of saturation and CO2 fluxes were still mainly positive but lower than in the winter period, ranging from 0.1 to 0.2 umol m-2 s-1. This flux was only moderately controlled by windspeed

  20. Sea-air carbon dioxide fluxes along 35°S in the South Atlantic Ocean

    NASA Astrophysics Data System (ADS)

    Lencina-Avila, J. M.; Ito, R. G.; Garcia, C. A. E.; Tavano, V. M.

    2016-09-01

    The oceans play an important role in absorbing a significant fraction of the atmospheric CO2 surplus, but there are still uncertainties concerning several open ocean regions, such as the under-sampled South Atlantic Ocean. This study assessed the net sea-air CO2 fluxes and distribution of sea-surface CO2 fugacity (f C O2sw) along the 35°S latitude in the South Atlantic, during 2011 spring and early summer periods. Underway CO2 molar fraction, temperature, salinity and dissolved oxygen measurements were taken continuously from South American to South African continental shelves. Values of both satellite and discrete in situ chlorophyll-a concentration along the ship's track were used as ancillary data. Both f C O2sw and difference in sea-air fugacity (ΔfCO2) showed high variability along the cruise track, with higher values found on the continental shelf and slope regions. All ΔfCO2 values were negative, implying that a sinking process was occurring during the cruise period, with an average net CO2 flux of -3.1±2.2 mmol CO2 m-2 day-1 (using Wanninkhof, 1992). Physical variables were the main drivers of f C O2sw variability in South American continental shelf and open ocean regions, while the biological factor dominated the South African continental shelf. Algorithms for estimating fCO2 and temperature-normalized fCO2 were developed and applied separately to the three defined sub-regions: the South American shelf, the open ocean and the South African continental shelf, with the regional temperature-normalized fCO2 models showing better results.

  1. Compact optical system for imaging underwater and through the air/sea interface

    NASA Astrophysics Data System (ADS)

    Alley, Derek; Mullen, Linda; Laux, Alan

    2012-06-01

    Typical line-of-sight (LOS)/monostatic optical imaging systems include a laser source and receiver that are co-located on the same platform. The performance of such systems is deteriorated in turbid ocean water due to the large amount of light that is scattered on the path to and from an object of interest. Imagery collected with the LOS/monostatic system through the air/sea interface is also distorted due to wave focusing/defocusing effects. The approach of this project is to investigate an alternate, non-line-of-sight (NLOS)/bistatic approach that offers some advantages over these traditional LOS/monostatic imaging techniques. In this NLOS system the laser and receiver are located on separate platforms with the laser located closer to the object of interest. As the laser sequentially scans the underwater object, a time-varying intensity signal corresponding to reflectivity changes in the object is detected by the distant receiver. A modulated laser illuminator is used to communicate information about the scan to the distant receiver so it can recreate the image with the collected scattered light. This NLOS/bistatic configuration also enables one to view an underwater target through the air-sea interface (transmitter below the surface and receiver above the surface) without the distortions experienced with the LOS/monostatic sensor. In this paper, we will review the results of recent laboratory water tank experiments where an underwater object was imaged with the receiver both below and above the sea surface.

  2. Sea-air CO2 fluxes in the Southern Ocean for the period 1990-2009

    NASA Astrophysics Data System (ADS)

    Lenton, A.; Tilbrook, B.; Law, R. M.; Bakker, D.; Doney, S. C.; Gruber, N.; Ishii, M.; Hoppema, M.; Lovenduski, N. S.; Matear, R. J.; McNeil, B. I.; Metzl, N.; Mikaloff Fletcher, S. E.; Monteiro, P. M. S.; Rödenbeck, C.; Sweeney, C.; Takahashi, T.

    2013-06-01

    The Southern Ocean (44-75° S) plays a critical role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Different approaches have been used to estimate sea-air CO2 fluxes in this region: synthesis of surface ocean observations, ocean biogeochemical models, and atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Southern Ocean sea-air CO2 fluxes between 1990-2009. Using all models and inversions (26), the integrated median annual sea-air CO2 flux of -0.42 ± 0.07 Pg C yr-1 for the 44-75° S region, is consistent with the -0.27 ± 0.13 Pg C yr-1 calculated using surface observations. The circumpolar region south of 58° S has a small net annual flux (model and inversion median: -0.04 ± 0.07 Pg C yr-1 and observations: +0.04 ± 0.02 Pg C yr-1), with most of the net annual flux located in the 44 to 58° S circumpolar band (model and inversion median: -0.36 ± 0.09 Pg C yr-1 and observations: -0.35 ± 0.09 Pg C yr-1). Seasonally, in the 44-58° S region, the median of 5 ocean biogeochemical models captures the observed sea-air CO2 flux seasonal cycle, while the median of 11 atmospheric inversions shows little seasonal change in the net flux. South of 58° S, neither atmospheric inversions nor ocean biogeochemical models reproduce the phase and amplitude of the observed seasonal sea-air CO2 flux, particularly in the Austral Winter. Importantly, no individual atmospheric inversion or ocean biogeochemical model is capable of reproducing both the observed annual mean uptake and the observed seasonal cycle. This raises concerns about projecting future changes in Southern Ocean CO2 fluxes. The median interannual variability from atmospheric inversions and ocean biogeochemical models is substantial in the Southern Ocean; up to 25% of the annual mean flux, with 25% of this interannual

  3. Hurricane Isabel, AIRS Infrared and SeaWinds Scatterometer Data Combined

    NASA Technical Reports Server (NTRS)

    2003-01-01

    [figure removed for brevity, see original site] [figure removed for brevity, see original site] Figure 1Figure 2

    These two images show Hurricane Isabel as viewed by AIRS and each of the two SeaWinds scatterometers on the ADEOS-2 and QuikScat satellites, all JPL-managed experiments. AIRS data are used to create global three-dimensional maps of temperature, humidity and clouds, while scatterometers measure surface wind speed and direction.

    Figure 1 shows Isabel on September 13, 2003, when it was a Category 5 storm threatening the Caribbean and southern United States. At the time Isabel was the strongest Atlantic storm since hurricane Mitch killed thousands in central America in 1997. The red vectors in the image show Isabel's surface winds as measured by SeaWinds on ADEOS-2, and the background colors show the temperature of clouds and surface, as viewed in the infrared by AIRS. The hurricane's powerful swirling winds are apparent. These winds circle the hurricane's eye, seen as the red dot near the middle top of the image. Light blue areas shows adjacent cold clouds tops associated with strong thunderstorms embedded within the storm.

    Figure 2 shows Isabel as it approached landfall on the outer banks of North Carolina on September 18. The hurricane weakened in the five days since the earlier image was observed, as indicated by a less clearly defined eye. Nevertheless, it was still a powerful storm. The winds blowing onshore north of the eye knocked over trees, blew roofs off buildings, and drove large waves that breached the coastal barrier islands in many places. Water, transportation and power are still not fully restored to many of the areas in the image. The winds apparently blowing away from the eye of the storm are an artifact of one of the hurricane's other destructive phenomena: rain. The darkest blue clouds observed by AIRS show the most intense thunderstorms, and hence the heaviest rains. Hard rain fools the the SeaWinds on Quik

  4. Occurrence and air/sea-exchange of novel organic pollutants in the marine environment

    NASA Astrophysics Data System (ADS)

    Ebinghaus, R.; Xie, Z.

    2006-12-01

    A number of studies have demonstrated that several classes of chemicals act as biologically relevant signalling substances. Among these chemicals, many, including PCBs, DDT and dioxins, are semi-volatile, persistent, and are capable of long-range atmospheric transport via atmospheric circulation. Some of these compounds, e.g. phthalates and alkylphenols (APs) are still manufactured and consumed worldwide even though there is clear evidence that they are toxic to aquatic organisms and can act as endocrine disruptors. Concentrations of NP, t-OP and NP1EO, DMP, DEP, DBP, BBP, and DEHP have been simultaneously determined in the surface sea water and atmosphere of the North Sea. Atmospheric concentrations of NP and t-OP ranged from 7 to 110 pg m - 3, which were one to three orders of magnitude below coastal atmospheric concentrations already reported. NP1EO was detected in both vapor and particle phases, which ranged from 4 to 50 pg m - 3. The concentrations of the phthalates in the atmosphere ranged from below the method detection limit to 3.4 ng m - 3. The concentrations of t-OP, NP, and NP1EO in dissolved phase were 13-300, 90-1400, and 17-1660 pg L - 1. DBP, BBP, and DEHP were determined in the water phase with concentrations ranging from below the method detection limit to 6.6 ng L - 1. This study indicates that atmospheric deposition of APs and phthalates into the North Sea is an important input pathway. The net fluxes indicate that the air sea exchange is significant and, consequently the open ocean and polar areas will be an extensive sink for APs and phthalates.

  5. Microwave and Electro-optical Transmission Experiments in the air-sea Boundary Layer

    NASA Astrophysics Data System (ADS)

    Anderson, K. D.

    2002-12-01

    , deployment, operation, and recovery of R/P FLIP. These problems ranged from the U.S.N.S. Sioux cutting a mooring line, which delayed deployment by more than 4 days, nearly loosing Tommy during the first attempt at deployment, inadequate air conditioning in the lab spaces, causing at least one instrument to temporarily fail, and problems associated with too many people and too many sensors on board. These issues will be discussed and recommendations will be made to improve future microwave and electro-optical experiments at sea.

  6. The relationship between ocean surface turbulence and air-sea gas transfer velocity: An in-situ evaluation

    NASA Astrophysics Data System (ADS)

    Esters, L.; Landwehr, S.; Sutherland, G.; Bell, T. G.; Saltzman, E. S.; Christensen, K. H.; Miller, S. D.; Ward, B.

    2016-05-01

    Although the air-sea gas transfer velocity k is usually parameterized with wind speed, the so-called small-eddy model suggests a relationship between k and ocean surface dissipation of turbulent kinetic energy ɛ. Laboratory and field measurements of k and ɛ have shown that this model holds in various ecosystems. Here, field observations are presented supporting the theoretical model in the open ocean. These observations are based on measurements from the Air-Sea Interaction Profiler and eddy covariance CO2 and DMS air-sea flux data collected during the Knorr11 cruise. We show that the model results can be improved when applying a variable Schmidt number exponent compared to a commonly used constant value of 1/2. Scaling ɛ to the viscous sublayer allows us to investigate the model at different depths and to expand its applicability for more extensive data sets.

  7. A climatology of air-sea interactions at the Mediterranean LION and AZUR buoys

    NASA Astrophysics Data System (ADS)

    Caniaux, Guy; Prieur, Louis; Bouin, Marie-Noëlle; Giordani, Hervé

    2014-05-01

    The LION and AZUR buoys (respectively at 42.1°N 4.7°E and 43.4°N 7.8°E) provide an extended data set since respectively 1999 and 2001 to present for studying air-sea interactions in the northwestern Mediterranean basin. The two buoys are located where high wind events occur (resp. north western and north easterly gale winds), that force and condition deep oceanic winter convection in that region. A short-term climatology (resp. 13 and 11 years) of air-sea interactions has been developed, which includes classical meteo-oceanic parameters, but also waves period and significant wave heights and radiative fluxes. Moreover turbulent surface fluxes have been estimated from various bulk parameterizations, in order to estimate uncertainties on fluxes. An important dispersion of turbulent fluxes is found at high wind speeds according to the parameterization used, larger than taking into account the second order effects of cool skin, warm layer and waves. An important annual cycle affects air temperatures (ATs), SSTs and turbulent fluxes at the two buoys. The annual cycle of ATs and SSTs can be well reconstructed from the first two annual harmonics, while for the turbulent heat fluxes the erratic occurrence of high and low flux events, well correlated with high/dry and low windy periods, strongly affect their annual and interannual cycles. The frequency of high surface heat fluxes and high wind stress is found highest during the autumn and winter months, despite the fact that north-westerly gale winds occur all year long at LION buoy. During calm weather period, ATs and SSTs experience an important diurnal cycle (on average 1 and 0.5°C respectively), that affect latent and sensible heat fluxes. Finally, an estimate of the interannual variability of the turbulent fluxes in Autumn and Winter is discussed, in order to characterize their potential role on deep ocean convection.

  8. Relationships Between the Bulk-Skin Sea Surface Temperature Difference, Wind, and Net Air-Sea Heat Flux

    NASA Technical Reports Server (NTRS)

    Emery, William J.; Castro, Sandra L.; Lindstrom, Eric (Technical Monitor)

    2002-01-01

    The primary purpose of this project was to evaluate and improve models for the bulk-skin temperature difference to the point where they could accurately and reliably apply under a wide variety of environmental conditions. To accomplish this goal, work was conducted in three primary areas. These included production of an archive of available data sets containing measurements of the skin and bulk temperatures and associated environmental conditions, evaluation of existing skin layer models using the compiled data archive, and additional theoretical work on the development of an improved model using the data collected under diverse environmental conditions. In this work we set the basis for a new physical model of renewal type, and propose a parameterization for the temperature difference across the cool skin of the ocean in which the effects of thermal buoyancy, wind stress, and microscale breaking are all integrated by means of the appropriate renewal time scales. Ideally, we seek to obtain a model that will accurately apply under a wide variety of environmental conditions. A summary of the work in each of these areas is included in this report. A large amount of work was accomplished under the support of this grant. The grant supported the graduate studies of Sandra Castro and the preparation of her thesis which will be completed later this year. This work led to poster presentations at the 1999 American Geophysical Union Fall Meeting and 2000 IGARSS meeting. Additional work will be presented in a talk at this year's American Meteorological Society Air-Sea Interaction Meeting this May. The grant also supported Sandra Castro during a two week experiment aboard the R/P Flip (led by Dr. Andrew Jessup of the Applied Physics Laboratory) to help obtain additional shared data sets and to provide Sandra with a fundamental understanding of the physical processes needed in the models. In a related area, the funding also partially supported Dr. William Emery and Daniel

  9. Spatio-temporal visualization of air-sea CO2 flux and carbon budget using volume rendering

    NASA Astrophysics Data System (ADS)

    Du, Zhenhong; Fang, Lei; Bai, Yan; Zhang, Feng; Liu, Renyi

    2015-04-01

    This paper presents a novel visualization method to show the spatio-temporal dynamics of carbon sinks and sources, and carbon fluxes in the ocean carbon cycle. The air-sea carbon budget and its process of accumulation are demonstrated in the spatial dimension, while the distribution pattern and variation of CO2 flux are expressed by color changes. In this way, we unite spatial and temporal characteristics of satellite data through visualization. A GPU-based direct volume rendering technique using half-angle slicing is adopted to dynamically visualize the released or absorbed CO2 gas with shadow effects. A data model is designed to generate four-dimensional (4D) data from satellite-derived air-sea CO2 flux products, and an out-of-core scheduling strategy is also proposed for on-the-fly rendering of time series of satellite data. The presented 4D visualization method is implemented on graphics cards with vertex, geometry and fragment shaders. It provides a visually realistic simulation and user interaction for real-time rendering. This approach has been integrated into the Information System of Ocean Satellite Monitoring for Air-sea CO2 Flux (IssCO2) for the research and assessment of air-sea CO2 flux in the China Seas.

  10. Characteristics of easterly-induced snowfall in Yeongdong and its relationship to air-sea temperature difference

    NASA Astrophysics Data System (ADS)

    Nam, Hyoung-Gu; Kim, Byung-Gon; Han, Sang-Ok; Lee, Chulkyu; Lee, Seoung-Soo

    2014-08-01

    Characteristics of snowfall episodes have been investigated for the past ten years in order to study its association with lowlevel stability and air-sea temperature difference over the East Sea. In general, the selected snowfall episodes have similar synoptic setting such as the Siberian High extended to northern Japan along with the Low passing by the southern Korean Peninsula, eventually resulting in the easterly flow in the Yeongdong region. Especially in the heavy snowfall episodes, convective unstable layers have been identified over the East sea due to relatively warm sea surface temperature (SST) about 8˜10°C and specifically cold pool around 1˜2 km above the surface level (ASL), which can be derived from Regional Data Assimilation and Prediction System (RDAPS), but that have not been clearly exhibited in the weak snowfall episodes. The basic mechanism to initiate snowfall around Yeongdong seems to be similar to that of lake-effect snowstorms around Great Lakes in the United States (Kristovich et al., 2003). Difference of equivalent potential temperature ( θ e ) between 850 hPa and surface as well as difference between air and sea temperatures altogether gradually began to increase in the pre-snowfall period and reached their maximum values in the course of the period, whose air (850 hPa) — sea temperature difference and snowfall intensity in case of the heavy snowfall episodes are almost larger than 20°C and 6 tims greater than the weak snowfall episodes, respectively. Interestingly, snowfall appeared to begin in case of an air-sea temperature difference exceeding over 15°C. The current analysis is overall consistent with the previous finding (Lee et al., 2012) that an instabilityinduced moisture supply to the lower atmosphere from the East sea, being cooled and saturated in the lower layer, so to speak, East Sea-Effect Snowfall (SES), would make a low-level ice cloud which eventually moves inland by the easterly flow. In addition, a longlasting

  11. Land, sea, and air unmanned systems research and development at SPAWAR Systems Center Pacific

    NASA Astrophysics Data System (ADS)

    Nguyen, Hoa G.; Laird, Robin; Kogut, Greg; Andrews, John; Fletcher, Barbara; Webber, Todd; Arrieta, Rich; Everett, H. R.

    2009-05-01

    The Space and Naval Warfare (SPAWAR) Systems Center Pacific (SSC Pacific) has a long and extensive history in unmanned systems research and development, starting with undersea applications in the 1960s and expanding into ground and air systems in the 1980s. In the ground domain, we are addressing force-protection scenarios using large unmanned ground vehicles (UGVs) and fixed sensors, and simultaneously pursuing tactical and explosive ordnance disposal (EOD) operations with small man-portable robots. Technology thrusts include improving robotic intelligence and functionality, autonomous navigation and world modeling in urban environments, extended operational range of small teleoperated UGVs, enhanced human-robot interaction, and incorporation of remotely operated weapon systems. On the sea surface, we are pushing the envelope on dynamic obstacle avoidance while conforming to established nautical rules-of-the-road. In the air, we are addressing cooperative behaviors between UGVs and small vertical-takeoff- and-landing unmanned air vehicles (UAVs). Underwater applications involve very shallow water mine countermeasures, ship hull inspection, oceanographic data collection, and deep ocean access. Specific technology thrusts include fiber-optic communications, adaptive mission controllers, advanced navigation techniques, and concepts of operations (CONOPs) development. This paper provides a review of recent accomplishments and current status of a number of projects in these areas.

  12. Tropical Intraseasonal Air-Sea Exchanges during the 1997 Pacific Warming

    NASA Technical Reports Server (NTRS)

    Sui, C.-H.; Lau, K.-M.; Chou, S.-H.; Wang, Zihou

    1999-01-01

    The Madden Julian Oscillations (MJO) and associated westerly wind (WW) events account for much of the tropical intraseasonal variability (TISV). The TISV has been suggested as an important stochastic forcing that may be one of the underlying causes for the observed irregularities of the El Nino-Southern Oscillation (ENSO). Recent observational studies and theories of interannual to interdecadal-scale variability suggest that ENSO may arise from different mechanisms depending on the basic states. The Pacific warming event of 1997, being associated with a period of strong MJO and WW events, serves as a natural experiment for studying the possible role of TISV in triggering an ENSO event. We have performed a combined statistical and composite analysis of surface WW events based on the assimilated surface wind and sea level pressure for the period of 1980-1993, the SSM/I wind for the period of 1988-1997, and OLR. Results indicates that extratropical forcing contribute significantly to the evolution of MJO and establishment of WW events over the Pacific warm pool. Following the major WW events, there appeared an eastward extension of equatorial warm SST anomalies from the western Pacific warm pool. Such tropical-extratropical interaction is particularly clear in the winter of 96-97 that leads to the recent warming event in 1997/98. From the above discussion, our current study on this subject is based on the hypothesis that 1) there is an enhanced air-sea interaction associated with TISV and the northerly surges from the extratropics in the initial phase of the 97/98 warming event, and 2) the relevant mechanisms are functions of the basic state of the coupled system (in terms of SST distribution and atmospheric mean circulation) that varies at the interannual and interdecadal time scale. We are analyzing the space-time structure of the northerly surges, their association with air-sea fluxes and upper ocean responses during the period of September 1996 to June 1997. The

  13. Distributions and air-sea fluxes of carbon dioxide in the Western Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Gao, Zhongyong; Chen, Liqi; Sun, Heng; Chen, Baoshan; Cai, Wei-Jun

    2012-12-01

    The uptake of carbon dioxide (CO2) by the Arctic Ocean is most likely increasing because of the rapid sea-ice retreat that lifted the barriers preventing gas exchange and light penetration for biological growth. Measurements of atmospheric and surface sea water partial pressure of CO2 (pCO2) were conducted during the Chinese National Arctic Research Expedition (CHINARE) cruises from July to September in 2003 and 2008. The latitudinal distribution of pCO2 along the 169°W transect showed a below-atmopsheric pCO2 level in most of the Western Arctic Ocean, with distinct regional differences from Bering Strait northward to the Central Acrctic Ocean. The average air-sea CO2 fluxes on the shelf and slope of the Chukchi Sea were -17.0 and -8.1 mmol m-2 d-1 respectively. In the ice-free zone, the partially ice-covered zone, and the heavily ice-covered zone of the Canada Basin, the fluxes were -4.2, -8.6, -2.5 mmol m-2 d-1 respectively. These rates are lower than other recent estimates. Our new results not only confirmed previous observations that most areas of the Western Arctic Ocean were a CO2 sink in general, but they also revealed that the previously unsampled central basins were a moderate CO2 sink. Analysis of controlling factors in different areas shows that pCO2 in Bering Strait was influenced not only by the Bering inflow waters but also by the high biological production. However, pCO2 fluctuated sharply because of strong water mixing both laterally and vertically. In the marginal ice zone (Chukchi Sea), pCO2 was controlled by ice melt and biological production, both of which would decrease pCO2 onshore of the ice edge. In the nearly ice-free southern Canada Basin, pCO2 increasd latitudinally as a result of atmospheric CO2 uptake due to intensive gas exchange, increased temperature, and decresed biological CO2 uptake due to limited nutrient supply. Finally, pCO2 was moderately lower than the atmospheric value and was relatively stable under the ice sheet of the

  14. Model estimating the effect of marginal ice zone processes on the phytoplankton primary production and air-sea flux of CO2 in the Barents Sea

    NASA Astrophysics Data System (ADS)

    Dvornikov, Anton; Sein, Dmitry; Ryabchenko, Vladimir; Gorchakov, Victor; Martjyanov, Stanislav

    2016-04-01

    This study is aimed to assess the impact of sea ice on the primary production of phytoplankton (PPP) and air-sea CO2 flux in the Barents Sea. To get the estimations, we apply a three-dimensional eco-hydrodynamic model based on the Princeton Ocean Model which includes: 1) a module of sea ice with 7 categories, and 2) the 11-component module of marine pelagic ecosystem developed in the St. Petersburg Branch, Institute of Oceanology. The model is driven by atmospheric forcing, prescribed from the reanalysis NCEP / NCAR, and conditions on the open sea boundary, prescribed from the regional model of the atmosphere-ocean-sea ice-ocean biogeochemistry, developed at Max Planck Institute for Meteorology, Hamburg. Comparison of the model results for the period 1998-2007 with satellite data showed that the model reproduces the main features of the evolution of the sea surface temperature, seasonal changes in the ice extent, surface chlorophyll "a" concentration and PPP in the Barents Sea. Model estimates of the annual PPP for whole sea, APPmod, appeared in 1.5-2.3 times more than similar estimates, APPdata, from satellite data. The main reasons for this discrepancy are: 1) APPdata refers to the open water, while APPmod, to the whole sea area (under the pack ice and marginal ice zone (MIZ) was produced 16 - 38% of PPP); and 2) values of APPdata are underestimated because of the subsurface chlorophyll maximum. During the period 1998-2007, the modelled maximal (in the seasonal cycle) sea ice area has decreased by 15%. This reduction was accompanied by an increase in annual PPP of the sea at 54 and 63%, based, respectively, on satellite data and the model for the open water. According to model calculations for the whole sea area, the increase is only 19%. Using a simple 7-component model of oceanic carbon cycle incorporated into the above hydrodynamic model, the CO2 exchange between the atmosphere and sea has been estimated in different conditions. In the absence of biological

  15. MP3 - A Meteorology and Physical Properties Package to explore Air:Sea interaction on Titan

    NASA Astrophysics Data System (ADS)

    Lorenz, R. D.

    2012-04-01

    The exchange of mass, heat and momentum at the air:sea interface are profound influences on our environment. Titan presents us with an opportunity to study these processes in a novel physical context. The MP3 instrument, under development for the proposed Discovery mission TiME (Titan Mare Explorer) is an integrated suite of small, simple sensors that combines the a traditional meteorology package with liquid physical properties and depth-sounding. In TiME's 6-Titan-day (96-day) nominal mission, MP3 will have an extended measurement opportunity in one of the most evocative environments in the solar system. The mission and instrument benefit from APL's expertise and experience in marine as well as space systems. The topside meteorology sensors (METH, WIND, PRES, TEMP) will yield the first long-duration in-situ data to constrain Global Circulation Models. The sea sensors (TEMP, TURB, DIEL, SOSO) allow high cadence bulk composition measurements to detect heterogeneities as the TiME capsule drifts across Ligeia, while a depth sounder (SONR) will measure the bottom profile. The combination of these sensors (and vehicle dynamics, ACCL) will characterize air:sea exchange. In addition to surface data, a measurement subset (ACCL, PRES, METH, TEMP) is made during descent to characterize the structure of the polar troposphere and marine boundary layer. A single electronics box inside the vehicle performs supervising and data handling functions and is connected to the sensors on the exterior via a wire and fiber optic harness. ACCL: MEMS accelerometers and angular rate sensors measure the vehicle motion during descent and on the surface, to recover wave amplitude and period and to correct wind measurements for vehicle motion. TEMP: Precision sensors are installed at several locations above and below the 'waterline' to measure air and sea temperatures. Installation of topside sensors at several locations ensures that at least one is on the upwind side of the vehicle. PRES: The

  16. Distribution and air-sea exchange of mercury (Hg) in polluted marine environments

    NASA Astrophysics Data System (ADS)

    Bagnato, E.; Sprovieri, M.; Bitetto, M.; Bonsignore, M.; Calabrese, S.; Di Stefano, V.; Oliveri, E.; Parello, F.; Mazzola, S.

    2012-04-01

    Mercury (Hg) is emitted in the atmosphere by anthropogenic and natural sources, these last accounting for one third of the total emissions. Since the pre-industrial age, the atmospheric deposition of mercury have increased notably, while ocean emissions have doubled owing to the re-emission of anthropogenic mercury. Exchange between the atmosphere and ocean plays an important role in cycling and transport of mercury. We present the preliminary results from a study on the distribution and evasion flux of mercury at the atmosphere/sea interface in the Augusta basin (SE Sicily, southern Italy), a semi-enclosed marine area affected by a high degree of contamination (heavy metals and PHA) due to the oil refineries placed inside its commercial harbor. It seems that the intense industrial activity of the past have lead to an high Hg pollution in the bottom sediments of the basin, whose concentrations are far from the background mercury value found in most of the Sicily Strait sediments. The release of mercury into the harbor seawater and its dispersion by diffusion from sediments to the surface, make the Augusta basin a potential supplier of mercury both to the Mediterranean Sea and the atmosphere. Based on these considerations, mercury concentration and flux at the air-sea interface of the Bay have been estimated using a real-time atomic adsorption spectrometer (LUMEX - RA915+) and an home-made accumulation chamber, respectively. Estimated Total Atmospheric Mercury (TGM) concentrations during the cruise on the bay were in the range of 1-3 ng · m-3, with a mean value of about 1.4 ng · m-3. These data well fit with the background Hgatm concentration values detected on the land (1-2 ng · m-3, this work), and, more in general, with the background atmospheric TGM levels found in the North Hemisphere (1.5-1.7 ng · m-3)a. Besides, our measurements are in the range of those reported for other important polluted marine areas. The mercury evasion flux at the air-sea interface

  17. Comparisons of Ship-based Observations of Air-Sea Energy Budgets with Gridded Flux Products

    NASA Astrophysics Data System (ADS)

    Fairall, C. W.; Blomquist, B.

    2015-12-01

    Air-surface interactions are characterized directly by the fluxes of momentum, heat, moisture, trace gases, and particles near the interface. In the last 20 years advances in observation technologies have greatly expanded the database of high-quality direct (covariance) turbulent flux and irradiance observations from research vessels. In this paper, we will summarize observations from the NOAA sea-going flux system from participation in various field programs executed since 1999 and discuss comparisons with several gridded flux products. We will focus on comparisons of turbulent heat fluxes and solar and IR radiative fluxes. The comparisons are done for observing programs in the equatorial Pacific and Indian Oceans and SE subtropical Pacific.

  18. Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface

    NASA Astrophysics Data System (ADS)

    Ciuraru, Raluca; Fine, Ludovic; van Pinxteren, Manuela; D'Anna, Barbara; Herrmann, Hartmut; George, Christian

    2015-08-01

    The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitize the chemical conversion of linear saturated fatty acids at the air-water interface into unsaturated functionalized gas phase products (i.e. saturated and unsaturated aldehydes and acids, alkenes and dienes,…) which are known precursors of secondary organic aerosols. These functionalized molecules have previously been thought to be of biological origin, but here we demonstrate that abiotic interfacial photochemistry has the potential to produce such molecules. As the ocean is widely covered by the SML, this new understanding will impact on our ability to describe atmospheric chemistry in the marine environment.

  19. The EOSDIS Version 0 Distributed Active Archive Center for physical oceanography and air-sea interaction

    NASA Technical Reports Server (NTRS)

    Hilland, Jeffrey E.; Collins, Donald J.; Nichols, David A.

    1991-01-01

    The Distributed Active Archive Center (DAAC) at the Jet Propulsion Laboratory will support scientists specializing in physical oceanography and air-sea interaction. As part of the NASA Earth Observing System Data and Information System Version 0 the DAAC will build on existing capabilities to provide services for data product generation, archiving, distribution and management of information about data. To meet scientist's immediate needs for data, existing data sets from missions such as Seasat, Geosat, the NOAA series of satellites and the Global Positioning Satellite system will be distributed to investigators upon request. In 1992, ocean topography, wave and surface roughness data from the Topex/Poseidon radar altimeter mission will be archived and distributed. New data products will be derived from Topex/Poseidon and other sensor systems based on recommendations of the science community. In 1995, ocean wind field measurements from the NASA Scatterometer will be supported by the DAAC.

  20. Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface

    PubMed Central

    Ciuraru, Raluca; Fine, Ludovic; van Pinxteren, Manuela; D’Anna, Barbara; Herrmann, Hartmut; George, Christian

    2015-01-01

    The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitize the chemical conversion of linear saturated fatty acids at the air-water interface into unsaturated functionalized gas phase products (i.e. saturated and unsaturated aldehydes and acids, alkenes and dienes,…) which are known precursors of secondary organic aerosols. These functionalized molecules have previously been thought to be of biological origin, but here we demonstrate that abiotic interfacial photochemistry has the potential to produce such molecules. As the ocean is widely covered by the SML, this new understanding will impact on our ability to describe atmospheric chemistry in the marine environment. PMID:26244712

  1. Characterization of air contaminants formed by the interaction of lava and sea water.

    PubMed Central

    Kullman, G J; Jones, W G; Cornwell, R J; Parker, J E

    1994-01-01

    We made environmental measurements to characterize contaminants generated when basaltic lava from Hawaii's Kilauea volcano enters sea water. This interaction of lava with sea water produces large clouds of mist (LAZE). Island winds occasionally directed the LAZE toward the adjacent village of Kalapana and the Hawaii Volcanos National Park, creating health concerns. Environmental samples were taken to measure airborne concentrations of respirable dust, crystalline silica and other mineral compounds, fibers, trace metals, inorganic acids, and organic and inorganic gases. The LAZE contained quantifiable concentrations of hydrochloric acid (HCl) and hydrofluoric acid (HF); HCl was predominant. HCl and HF concentrations were highest in dense plumes of LAZE near the sea. The HCl concentration at this sampling location averaged 7.1 ppm; this exceeds the current occupational exposure ceiling of 5 ppm. HF was detected in nearly half the samples, but all concentrations were <1 ppm Sulfur dioxide was detected in one of four short-term indicator tube samples at approximately 1.5 ppm. Airborne particulates were composed largely of chloride salts (predominantly sodium chloride). Crystalline silica concentrations were below detectable limits, less than approximately 0.03 mg/m3 of air. Settled dust samples showed a predominance of glass flakes and glass fibers. Airborne fibers were detected at quantifiable levels in 1 of 11 samples. These fibers were composed largely of hydrated calcium sulfate. These findings suggest that individuals should avoid concentrated plumes of LAZE near its origin to prevent over exposure to inorganic acids, specifically HCl. Images Figure 1. Figure 2. Figure 3. Figure 4. A Figure 4. B Figure 4. C Figure 4. D PMID:8593853

  2. Oceanic distributions and air-sea fluxes of biogenic halocarbons in the open ocean

    NASA Astrophysics Data System (ADS)

    Chuck, Adele L.; Turner, Suzanne M.; Liss, Peter S.

    2005-10-01

    Surface seawater and atmospheric concentrations of methyl iodide, chloroiodomethane, bromoform, dichlorobromomethane, and chlorodibromethane were measured during three open ocean cruises in the Atlantic and Southern oceans. The measurements spanned a longitudinal range of 115°, between 50°N and 65°S. The saturation anomalies and the instantaneous air-sea fluxes of the gases during one of these cruises (ANT XVIII/1) are presented and discussed. Methyl iodide and chloroiodomethane were highly supersaturated (>1000%) throughout the temperate and tropical regions, with calculated mean fluxes of 15 and 5.5 nmol m-2 d-1, respectively. The oceanic emissions of the brominated compounds were less substantial, and a significant area of the temperate Atlantic Ocean was found to be a sink for bromoform. Correlation analyses have been used to investigate possible controls on the concentrations of these gases. In particular, the relationship of CH3I with sea surface temperature and light is discussed, with the tentative conclusion that this compound may be formed abiotically.

  3. Mechanisms controlling the SST air-sea heat flux feedback and its dependence on spatial scale

    NASA Astrophysics Data System (ADS)

    Hausmann, Ute; Czaja, Arnaud; Marshall, John

    2016-05-01

    The turbulent air-sea heat flux feedback (α , in {W m}^{-2}{ K}^{-1} ) is a major contributor to setting the damping timescale of sea surface temperature (SST) anomalies. In this study we compare the spatial distribution and magnitude of α in the North Atlantic and the Southern Ocean, as estimated from the ERA-Interim reanalysis dataset. The comparison is rationalized in terms of an upper bound on the heat flux feedback, associated with "fast" atmospheric export of temperature and moisture anomalies away from the marine boundary layer, and a lower bound associated with "slow" export. It is found that regions of cold surface waters (≤ 10° C) are best described as approaching the slow export limit. This conclusion is not only valid at the synoptic scale resolved by the reanalysis data, but also on basin scales. In particular, it applies to the heat flux feedback acting as circumpolar SST anomaly scales are approached in the Southern Ocean, with feedbacks of ≤ 10 {W m}^{-2}{ K}^{-1} . In contrast, the magnitude of the heat flux feedback is close to that expected from the fast export limit over the Gulf Stream and its recirculation with values on the order of ≈40 {W m}^{-2}{ K}^{-1} . Further analysis suggests that this high value reflects a compensation between a moderate thermodynamic adjustment of the boundary layer, which tends to weaken the heat flux feedback, and an enhancement of the surface winds over warm SST anomalies, which tend to enhance the feedback.

  4. The spatial-temporal variability of air-sea momentum fluxes observed at a tidal inlet

    NASA Astrophysics Data System (ADS)

    Ortiz-Suslow, D. G.; Haus, B. K.; Williams, N. J.; Laxague, N. J. M.; Reniers, A. J. H. M.; Graber, H. C.

    2015-02-01

    Coastal waters are an aerodynamically unique environment that has been little explored from an air-sea interaction point of view. Consequently, most studies must assume that open ocean-derived parameterizations of the air-sea momentum flux are representative of the nearshore wind forcing. Observations made at the New River Inlet in North Carolina, during the Riverine and Estuarine Transport experiment (RIVET), were used to evaluate the suitability of wind speed-dependent, wind stress parameterizations in coastal waters. As part of the field campaign, a small, agile research vessel was deployed to make high-resolution wind velocity measurements in and around the tidal inlet. The eddy covariance method was employed to recover direct estimates of the 10 m neutral atmospheric drag coefficient from the three-dimensional winds. Observations of wind stress angle, near-surface currents, and heat flux were used to analyze the cross-shore variability of wind stress steering off the mean wind azimuth. In general, for onshore winds above 5 m/s, the drag coefficient was observed to be two and a half times the predicted open ocean value. Significant wind stress steering is observed within 2 km of the inlet mouth, which is observed to be correlated with the horizontal current shear. Other mechanisms such as the reduction in wave celerity or depth-limited breaking could also play a role. It was determined that outside the influence of these typical coastal processes, the open ocean parameterizations generally represent the wind stress field. The nearshore stress variability has significant implications for observations and simulations of coastal transport, circulation, mixing, and general surf-zone dynamics.

  5. Assessing Air-Sea Interaction in the Evolving NASA GEOS Model

    NASA Technical Reports Server (NTRS)

    Clayson, Carol Anne; Roberts, J. Brent

    2015-01-01

    In order to understand how the climate responds to variations in forcing, one necessary component is to understand the full distribution of variability of exchanges of heat and moisture between the atmosphere and ocean. Surface heat and moisture fluxes are critical to the generation and decay of many coupled air-sea phenomena. These mechanisms operate across a number of scales and contain contributions from interactions between the anomalous (i.e. non-mean), often extreme-valued, flux components. Satellite-derived estimates of the surface turbulent and radiative heat fluxes provide an opportunity to assess results from modeling systems. Evaluation of only time mean and variability statistics, however only provides limited traceability to processes controlling what are often regime-dependent errors. This work will present an approach to evaluate the representation of the turbulent fluxes at the air-sea interface in the current and evolving Goddard Earth Observing System (GEOS) model. A temperature and moisture vertical profile-based clustering technique is used to identify robust weather regimes, and subsequently intercompare the turbulent fluxes and near-surface parameters within these regimes in both satellite estimates and GEOS-driven data sets. Both model reanalysis (MERRA) and seasonal-to-interannual coupled GEOS model simulations will be evaluated. Particular emphasis is placed on understanding the distribution of the fluxes including extremes, and the representation of near-surface forcing variables directly related to their estimation. Results from these analyses will help identify the existence and source of regime-dependent biases in the GEOS model ocean surface turbulent fluxes. The use of the temperature and moisture profiles for weather-state clustering will be highlighted for its potential broad application to 3-D output typical of model simulations.

  6. Assessing air-sea interaction in the evolving NASA GEOS model

    NASA Astrophysics Data System (ADS)

    Clayson, C. A.; Roberts, J. B.

    2014-12-01

    In order to understand how the climate responds to variations in forcing, one necessary component is to understand the full distribution of variability of exchanges of heat and moisture between the atmosphere and ocean. Surface heat and moisture fluxes are critical to the generation and decay of many coupled air-sea phenomena. These mechanisms operate across a number of scales and contain contributions from interactions between the anomalous (i.e. non-mean), often extreme-valued, flux components. Satellite-derived estimates of the surface turbulent and radiative heat fluxes provide an opportunity to assess results from modeling systems. Evaluation of only time mean and variability statistics, however only provides limited traceability to processes controlling what are often regime-dependent errors. This work will present an approach to evaluate the representation of the turbulent fluxes at the air-sea interface in the current and evolving Goddard Earth Observing System (GEOS) model. A temperature and moisture vertical profile-based clustering technique is used to identify robust weather regimes, and subsequently intercompare the turbulent fluxes and near-surface parameters within these regimes in both satellite estimates and GEOS-driven data sets. Both model reanalysis (MERRA) and seasonal-to-interannual coupled GEOS model simulations will be evaluated. Particular emphasis is placed on understanding the distribution of the fluxes including extremes, and the representation of near-surface forcing variables directly related to their estimation. Results from these analyses will help identify the existence and source of regime-dependent biases in the GEOS model ocean surface turbulent fluxes. The use of the temperature and moisture profiles for weather-state clustering will be highlighted for its potential broad application to 3-D output typical of model simulations.

  7. Elemental mercury (Hg(0)) in air and surface waters of the Yellow Sea during late spring and late fall 2012: concentration, spatial-temporal distribution and air/sea flux.

    PubMed

    Ci, Zhijia; Wang, Chunjie; Wang, Zhangwei; Zhang, Xiaoshan

    2015-01-01

    The Yellow Sea in East Asia receives great Hg input from regional emissions. However, Hg cycling in this marine system is poorly investigated. In late spring and late fall 2012, we determined gaseous elemental Hg (GEM or Hg(0)) in air and dissolved gaseous Hg (DGM, mainly Hg(0)) in surface waters to explore the spatial-temporal variations of Hg(0) and further to estimate the air/sea Hg(0) flux in the Yellow Sea. The results showed that the GEM concentrations in the two cruises were similar (spring: 1.86±0.40 ng m(-3); fall: 1.84±0.50 ng m(-3)) and presented similar spatial variation pattern with elevated concentrations along the coast of China and lower concentrations in the open ocean. The DGM concentrations of the two cruises were also similar with 27.0±6.8 pg L(-1) in the spring cruise and 28.2±9.0 pg L(-1) in the fall cruise and showed substantial spatial variation. The air/sea Hg(0) fluxes in the spring cruise and fall cruise were estimated to be 1.06±0.86 ng m(-2) h(-1) and 2.53±2.12 ng m(-2) h(-1), respectively. The combination of this study and our previous summer cruise showed that the summer cruise presented enhanced values of GEM, DGM and air/sea Hg(0) flux. The possible reason for this trend was that high solar radiation in summer promoted Hg(0) formation in seawater, and the high wind speed during the summer cruise significantly increased Hg(0) emission from sea surface to atmosphere and subsequently enhanced the GEM levels. PMID:24999267

  8. The OceanFlux Greenhouse Gases methodology for deriving a sea surface climatology of CO2 fugacity in support of air-sea gas flux studies

    NASA Astrophysics Data System (ADS)

    Goddijn-Murphy, L. M.; Woolf, D. K.; Land, P. E.; Shutler, J. D.; Donlon, C.

    2015-07-01

    Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean CO2 Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. As fCO2 is highly sensitive to temperature, the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrently with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air-sea CO2 fluxes, it is therefore desirable to calculate fCO2 valid for a more consistent and averaged SST. This paper presents the OceanFlux Greenhouse Gases methodology for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using monthly composite SST data on a 1° × 1° grid from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010, including the prediction errors of fCO2 produced by the spatial interpolation technique. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air-sea CO2 flux, and hence the presented fCO2 distributions can be used in air-sea gas flux calculations together with climatologies of other climate variables.

  9. OAFlux Satellite-Based High-Resolution Analysis of Air-Sea Turbulent Heat, Moisture, and Momentum Fluxes

    NASA Astrophysics Data System (ADS)

    Yu, Lisan

    2016-04-01

    The Objectively Analyzed air-sea Fluxes (OAFlux) project at the Woods Hole Oceanographic Institution has recently developed a new suite of products: the satellite-based high-resolution (HR) air-sea turbulent heat, moisture, and momentum fluxes over the global ocean from 1987 to the present. The OAFlux-HR fluxes are computed from the COARE bulk algorithm using air-sea variables (vector wind, near-surface humidity and temperature, and ocean surface temperature) derived from multiple satellite sensors and multiple missions. The vector wind time series are merged from 14 satellite sensors, including 4 scatterometers and 10 passive microwave radiometers. The near-surface humidity and temperature time series are retrieved from 11 satellite sensors, including 7 microwave imagers and 4 microwave sounders. The endeavor has greatly improved the depiction of the air-sea turbulent exchange on the frontal and meso-scales. The OAFlux-HR turbulent flux products are valuable datasets for a broad range of studies, including the study of the long-term change and variability in the oean-surface forcing functions, quantification of the large-scale budgets of mass, heat, and freshwater, and assessing the role of the ocean in the change and variability of the Earth's climate.

  10. Second international conference on air-sea interaction and on meteorology and oceanography of the coastal zone

    SciTech Connect

    1994-12-31

    This conference was held September 22--27, 1994 in Lisbon, Portugal. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on air-sea interactions. Individual papers have been processed separately for inclusion in the appropriate data bases.

  11. [Levels and sources of gaseous polybrominated diphenyl ethers in air over the northern South China Sea].

    PubMed

    Li, Qi-lu; Li, Jun; Liu, Xiang; Xu, Wei-hai; Zhang, Gan

    2012-08-01

    A total of 32 air samples collected during a Shiyan III voyage over the northern South China Sea (SCS) were analyzed for polybrominated diphenyl ethers (PBDEs) by gas chromatography/mass spectrometry. The concentrations of sigma 7 PBDEs ranged from 0.07 to 35.9 pg x m(-3). The sigma 7 PBDEs were dominated by tetra-(BDE-47) and penta-(BDE-99 and -100) components, which accounted for 51.5% and 36.9%, respectively. This result indicated that the widely used commercial penta-BDE product was the original source. The higher concentrations of PBDEs were monitored close to the coastline of the South China and Philippine, while the lower concentrations were found over the SCS adjacent to central coast of Vietnam. Back trajectory analysis showed that the high PBDE concentrations observed in air over the northern SCS may be related to the continental pollutant outflows from the southeast coast of China, especially the Pearl River Delta, Taiwan and Philippine, by prevailing northeast wind transport. PMID:23213869

  12. Air-sea exchange of gaseous mercury in the tropical coast (Luhuitou fringing reef) of the South China Sea, the Hainan Island, China.

    PubMed

    Ci, Zhijia; Zhang, Xiaoshan; Wang, Zhangwei

    2016-06-01

    The air-sea exchange of gaseous mercury (mainly Hg(0)) in the tropical ocean is an important part of the global Hg biogeochemical cycle, but the related investigations are limited. In this study, we simultaneously measured Hg(0) concentrations in surface waters and overlaying air in the tropical coast (Luhuitou fringing reef) of the South China Sea (SCS), Hainan Island, China, for 13 days on January-February 2015. The purpose of this study was to explore the temporal variation of Hg(0) concentrations in air and surface waters, estimate the air-sea Hg(0) flux, and reveal their influencing factors in the tropical coastal environment. The mean concentrations (±SD) of Hg(0) in air and total Hg (THg) in waters were 2.34 ± 0.26 ng m(-3) and 1.40 ± 0.48 ng L(-1), respectively. Both Hg(0) concentrations in waters (53.7 ± 18.8 pg L(-1)) and Hg(0)/THg ratios (3.8 %) in this study were significantly higher than those of the open water of the SCS in winter. Hg(0) in waters usually exhibited a clear diurnal variation with increased concentrations in daytime and decreased concentrations in nighttime, especially in cloudless days with low wind speed. Linear regression analysis suggested that Hg(0) concentrations in waters were positively and significantly correlated to the photosynthetically active radiation (PAR) (R (2) = 0.42, p < 0.001). Surface waters were always supersaturated with Hg(0) compared to air (the degree of saturation, 2.46 to 13.87), indicating that the surface water was one of the atmospheric Hg(0) sources. The air-sea Hg(0) fluxes were estimated to be 1.73 ± 1.25 ng m(-2) h(-1) with a large range between 0.01 and 6.06 ng m(-2) h(-1). The high variation of Hg(0) fluxes was mainly attributed to the greatly temporal variation of wind speed. PMID:26931659

  13. Seasonal variations of seawater pCO2 and sea-air CO2 fluxes in a fringing coral reef, northern South China Sea

    NASA Astrophysics Data System (ADS)

    Yan, Hongqiang; Yu, Kefu; Shi, Qi; Tan, Yehui; Liu, Guohui; Zhao, Meixia; Li, Shu; Chen, Tianran; Wang, Yinghui

    2016-01-01

    Evidence based on four field surveys conducted between July 2009 and April 2011 indicates that both sea surface partial pressures of CO2 (pCO2) and sea-air CO2 fluxes at Luhuitou fringing reef in Sanya, Hainan Island, northern South China Sea (SCS) are subject to significant seasonal variations. The diurnal variation of seawater pCO2 ranges from 264 to 579 μatm in summer, which is much larger than that in autumn (152-335 μatm), in winter (84-260 μatm), and in spring (114-228 μatm). The sea-air CO2 flux in summer (˜9.6 mmol CO2 m-2 d-1) is also larger than that in other seasons (i.e.,˜3 mmol CO2 m-2 d-1 in spring, ˜3.5 mmol CO2 m-2 d-1 in autumn, and ˜2.7 mmol CO2 m-2 d-1 in winter). The atmospheric pCO2 in this reef shows small diurnal and seasonal variations. The integration of the time-series pCO2 data shows that the reef area is a weak source of atmospheric CO2 at ˜0.54 mol CO2 m-2 yr-1. Further analyses indicate that the seasonal variations of the surface seawater pCO2 in Luhuitou fringing reef are mainly affected by seasonally-dependent biological metabolic processes (organic processe and inorganic process), and that the organic process play a more important role than the inorganic process. Seasonal sea surface temperature (SST) variations and hydrodynamic processes may also have some influence on seawater pCO2 variation.

  14. Methane distribution and sea-to-air flux in the East China Sea during the summer of 2013: Impact of hypoxia

    NASA Astrophysics Data System (ADS)

    Ye, Wangwang; Zhang, Guiling; Zhu, Zhuoyi; Huang, Daji; Han, Yu; Wang, Lan; Sun, Mingshuang

    2016-02-01

    We measured dissolved methane (CH4) at different depths and calculated sea-to-air CH4 fluxes at 65 stations in the East China Sea (ECS) from August 4 to 31 of 2013. CH4 concentrations in surface waters ranged from 2.07 to 27.39 nM and concentrations in bottom waters ranged from 1.76 to 31.35 nM. The concentration of CH4 also decreased with distance from the Changjiang (Yangtze River) Estuary. Analysis of the depth profiles of CH4 indicated great variations among the different stations due to the influence of different water masses and variations in other factors. A region of significant bottom-water hypoxia, with an oxygen level less than 1.5 mg L-1, occurred at the northern region of the ECS. This hypoxic region also had enhanced CH4 production in the water column and sedimentary release of CH4. CH4 saturations in the surface waters ranged from 113% to 1364%, with an average of 317% (±236). We estimated the sea-to-air CH4 flux as 6.5±7.4 μmol m-2 d-1 using the LM86 equation, and as 11.5±11.9 μmol m-2 d-1 using the W92 equation. The overall estimated CH4 emission rate from the ECS was 6.4×10-2 Tg yr-1. The saturation and sea-to-air flux of CH4 varied significantly among the stations. Taken together, our data suggest that the ECS is a net source of atmospheric CH4.

  15. Air-Sea CO2 fluxes in the Atlantic as measured during boreal spring and autumn

    NASA Astrophysics Data System (ADS)

    Padin, X. A.; Vázquez-Rodríguez, M.; Castaño, M.; Velo, A.; Alonso-Pérez, F.; Gago, J.; Gilcoto, M.; Álvarez, M.; Pardo, P. C.; de La Paz, M.; Ríos, A. F.; Pérez, F. F.

    2010-05-01

    A total of fourteen hydrographic cruises from 2000 to 2008 were conducted during the spring and autumn seasons between Spain and the Southern Ocean under the framework of the Spanish research project FICARAM. The underway measurements were processed and analysed to describe the meridional air-sea CO2 fluxes (FCO2) in the covered sector of the Atlantic Ocean. The data has been grouped into different biogeochemical oceanographic provinces based on thermohaline characteristics. The spatial and temporal distributions of FCO2 followed expected distributions and annual trends reproducing the recent climatological ΔfCO2 estimations with a mean difference of -3 ± 18 μatm (Takahashi et al., 2009). The reduction in the CO2 saturation along the meridional FICARAM cruises represented an increase of 0.02 ± 0.14 mol m-2 yr-1 in the ocean uptake of atmospheric CO2. The subtropical waters in both Hemispheres acted as a sink of atmospheric CO2 during the successive spring seasons and as a source in autumn. The coarse reduction of the ocean uptake of atmospheric CO2 observed in the North Atlantic Ocean was linked to conditions of negative phase of the North Atlantic Oscillation that prevailed during the FICARAM period. Surface waters in the North Equatorial Counter Current revealed a significant long-term decrease of sea surface salinity of -0.16 ± 0.01 yr-1 coinciding with a declination of -3.5 ± 0.9 μatm yr-1 in the air-sea disequilibrium of CO2 fugacity and a rise of oceanic CO2 uptake of -0.09 ± 0.03 mol m-2 yr-1. The largest CO2 source was located in the equatorial upwelling system. These tropical waters that reached emissions of 0.7 ± 0.5 and 1.0 ± 0.7 mol m-2 y-1 in spring and autumn, respectively, showed an interannual warming of 0.11 ± 0.03 °C yr-1 and a wind speed decrease of -0.58 ± 0.14 m s-1 yr-1 in spring cruises which suggest the weakening of upwelling events associated with warm El Niño - Southern Oscillation episodes. Contrary the surface waters of the

  16. Air/sea DMS gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed

    NASA Astrophysics Data System (ADS)

    Bell, T. G.; De Bruyn, W.; Miller, S. D.; Ward, B.; Christensen, K.; Saltzman, E. S.

    2013-05-01

    Shipboard measurements of eddy covariance DMS air/sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k660) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s-1. At higher wind speeds the relationship between k660 and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent suppression of air/sea gas flux at higher wind speeds appears to be related to sea state, as determined from shipboard wave measurements. These observations are consistent with the idea that long waves suppress near surface water side turbulence, and decrease interfacial gas transfer. This effect may be more easily observed for DMS than for less soluble gases, such as CO2, because the air/sea exchange of DMS is controlled by interfacial rather than bubble-mediated gas transfer under high wind speed conditions.

  17. The NEMO-AROME WMED high-resolution air-sea coupled system: impact on dense water formation

    NASA Astrophysics Data System (ADS)

    Léger, Fabien; Lebeaupin Brossier, Cindy; Giordani, Hervé; Arsouze, Thomas; Beuvier, Jonathan; Bouin, Marie-Noëlle; Ducrocq, Véronique; Fourrié, Nadia

    2016-04-01

    The North-Western Mediterranean Sea is a key location where intense air-sea exchanges occur, especially during winter when the succession of strong northerly and north-westerly wind boosts the dense water formation. The second Special Observation Period (SOP2) of the HyMeX program, which took place between 1st February and 15th March 2013, was dedicated to the observation of the dense water formation and ocean deep convection processes. During this period, several platforms sampled the area, providing a unique dataset to better identify the coupled processes leading to dense water formation. This study investigates the impacts of the fine scale ocean-atmosphere coupled processes on dense water formation during winter 2012-2013. We developed the coupling between the NEMO-WMED36 ocean model (1/36° resolution) and the AROME-WMED numerical weather prediction model (2.5 km resolution) and ran the high-resolution air-sea coupled system over SOP2. The coupled simulation is compared to an ocean-only simulation forced by AROME-WMED operational forecasts and to air-sea observations collected during the HyMeX SOP2. The results show small differences in term of surface fluxes. Dense water formation is slightly changed in the coupled simulation, whereas fine-scale ocean processes are significantly modified.

  18. Sea-air of CO2 in the North Pacific using shipboard and satellite data

    NASA Technical Reports Server (NTRS)

    Stephens, Mark P.; Samuels, Geoffrey; Olson, Donald B.; Fine, Rana A.; Takahashi, Taro

    1995-01-01

    A method has been developed to produce high-resolution maps of pCO2 in surface water for the North Pacific using satellite sea surface temperature (SST) data and statistical relationships between measured pCO2 and temperature. In the subtropical North Pacific the pCO in seawater is controlled primarily by temperature. Accordingly, pCO2 values that are calculated from the satellite SST data have good agreement with the measured values (rms deviation of +/- microatm). In the northwestern subpolar region the pCO2 is controlled not only by temperature, but also by significant seasonal changes in the total CO2 concentration, which are caused by seasonal changes in primary production, mixing with subsurface waters and sea-air exchange. Consequently, the parameterization of oceanic p CO2 based on SST data alone is not totally successful in the northwestern region (rms deviation of +/- 40 microatm). The use of additional satellite products, such as wind and ocean color data, as planned for a future study, is considered necessary to account for the pCO2 variability caused by seasonal changes in the total CO2 concentration. The net CO2 flux for the area of the North Pacific included in this study (north of 10 deg N) has been calculated using the monthly pCO2 distributions computed, and monthly wind speeds from the European Centre for Medium-Range Weather Forecasts. The region is found to be a net source to the atmosphere of 1.9 x 10(exp 12) to 5.8 x 10(exp 12) moles of CO2 per year (or 0.02-0.07 Gt C/yr), most of the outflux occurring in the subtropics.

  19. Air pollutant transport in a coastal environment. Part 1: Two-dimensional simulations of sea-breeze and mountain effects

    NASA Technical Reports Server (NTRS)

    Lu, Rong; Turco, Richard P.

    1994-01-01

    Over the southern California coastal region, observations of the vertical distributions of pollutants show that maximum concentrations can occur within temperature inversion layers well above the surface. A mesoscale model is used to study the dynamical phenomena that cause such layers, including sea breezes and mountain flows, and to study the characteristics of air pollutant transport in a coastal environment capped by a temperature inversion. The mathematical and physical structure of the model is described. Two-dimensional simulations corresponding to four configurations of coastal plains and mountains are discussed. The simulations reveal that pollutant transport over a coastal plain is strongly influenced by the topographic configuration, including the height of coastal mountains and their distance from the coastline. Sea breezes induced by land-sea thermal contrasts, as well as upslope winds induced along mountain flanks, both create vertical transport that can lead to the formation of elevated pollution layers. The sea-breeze circulation generates pollution layers by undercutting the mixed layer and lofting pollutants into the stable layer. Heating of mountain slopes acts to vent pollutants above the mountain ridge during the day; during the evening, pollutants can be injected directly into the inversion layer from the decaying upslope flows. In a land-sea configuration with mountains close to the coastline, the sea breeze and heated-mountain flow are strongly coupled. In the afternoon, this interaction can produce upslope flow from which polluted air is detrained into the inversion layer as a return circulation. When the mountains lie farther inland, however, pollutants may be trapped aloft when the mixed layer stabilizes in the late afternoon. As the nocturnal boundary layer forms over the coast in the evening, polluted mixed-layer air is effectively left behind in the inversion layer. In the Los Angeles Basin, the formation mechanism for elevated

  20. The Relation Between Wind Speed and Air-Sea Temperature Difference in the Marine Atmospheric Boundary Layer off Northwest Europe

    NASA Astrophysics Data System (ADS)

    Kettle, A. J.

    2014-12-01

    Wind speed and atmospheric stability have an important role in determining the turbulence in the marine atmospheric boundary layer (MABL) as well as the surface wave field. The understanding of MABL dynamics in northwest Europe is complicated by fetch effects, the proximity of coastlines, shallow topography, and larger scale circulation patterns (e.g., cold air outbreaks). Numerical models have difficulty simulating the marine atmospheric boundary layer in coastal areas and partially enclosed seas, and this is partly due to spatial resolution problems at coastlines. In these offshore environments, the boundary layer processes are often best understood directly from time series measurements from fixed platforms or buoys, in spite of potential difficulties from platform flow distortion as well as the spatial sparseness of the data sets. This contribution presents the results of time series measurements from offshore platforms in the North Sea and Norwegian Sea in terms of a summary diagnostic - wind speed versus air-sea temperature difference (U-ΔT) - with important implications for understanding atmospheric boundary layer processes. The U-ΔT diagram was introduced in earlier surveys of data from coastal (Sletringen; O.J. Andersen and J. Løvseth, J. Wind Eng. Ind. Aerodyn., 57, 97-109, 1995) and offshore (Statfjord A; K.J. Eidsvik, Boundary-Layer Meteorol., 32, 103-132, 1985) sites in northwest Europe to summarize boundary layer conditions at a given location. Additional information from a series of measurement purpose-built offshore measurement and oil/gas production platforms from the southern North Sea to the Norwegian Sea illustrates how the wind characteristics vary spatially over large distances, highlighting the influence of cold air outbreaks, in particular. The results are important for the offshore wind industry because of the way that wind turbines accrue fatigue damage in different conditions of atmospheric stability and wind speed.

  1. Roughness of Weddell Sea Ice and Estimates of the Air-Ice Drag Coefficient

    NASA Astrophysics Data System (ADS)

    Andreas, Edgar L.; Lange, Manfred A.; Ackley, Stephen F.; Wadhams, Peter

    1993-07-01

    The roughness of a sheet of sea ice encodes its deformational history and determines its aerodynamic coupling with the overlying air and underlying water. Here we report snow surface, ice surface, and ice underside roughness computed from 47 surface elevation profiles collected during a transect of the Weddell Sea. The roughness for each surface, parameterized as the standard deviation of the surface elevation, segregates according to whether or not a floe has been deformed: deformed ice has greater roughness than undeformed ice. Regardless of deformational history, the underside roughness is almost always greater than the snow surface and ice surface roughnesses, which are nearly equal. Roughness spectra for all three surfaces and for both deformed and undeformed ice roll off roughly as k-1 when the wavenumber k is between 0.1 and 3 rad m-1. The snow surface and underside spectra roll off somewhat faster than k-1, and the ice surface spectra roll off somewhat slower than k-1. Both top and underside Arctic ice roughness spectra, on the other hand, have been reported to roll off faster than k-2. We speculate that the excess spectral intensity at high wavenumbers in the Antarctic ice surface spectra results from the small-scale roughness that the ice sheet had on consolidation. This excess high-wavenumber spectral intensity persists in the ice surface spectra of second-year ice. Evidently, once formed, the ice surface remains unchanged on the microscale until the entire ice sheet melts. With a remote measurement of roughness, we should be able to decide whether an ice floe is deformed or undeformed. Our spectral analysis hints that remote sensing may also be able to differentiate between first-year and second-year ice. From the snow surface spectra, we compute a roughness scale ξ that parameterizes the air-ice momentum coupling and lets us estimate the neutral stability drag coefficient referenced to a height of 10 m, CDN10. Typical CDN10 values are 1.1-1.4 × 10

  2. Mercury in the marine boundary layer and seawater of the South China Sea: Concentrations, sea/air flux, and implication for land outflow

    NASA Astrophysics Data System (ADS)

    Fu, Xuewu; Feng, Xinbin; Zhang, Gan; Xu, Weihai; Li, Xiangdong; Yao, Hen; Liang, Peng; Li, Jun; Sommar, Jonas; Yin, Runsheng; Liu, Na

    2010-03-01

    Using R/V Shiyan 3 as a sampling platform, measurements of gaseous elemental mercury (GEM), surface seawater total mercury (THg), methyl mercury (MeHg), and dissolved gaseous mercury (DGM) were carried out above and in the South China Sea (SCS). Measurements were collected for 2 weeks (10 to 28 August 2007) during an oceanographic expedition, which circumnavigated the northern SCS from Guangzhou (Canton), Hainan Inland, the Philippines, and back to Guangzhou. GEM concentrations over the northern SCS ranged from 1.04 to 6.75 ng m-3 (mean: 2.62 ng m-3, median: 2.24 ng m-3). The spatial distribution of GEM was characterized by elevated concentrations near the coastal sites adjacent to mainland China and lower concentrations at stations in the open sea. Trajectory analysis revealed that high concentrations of GEM were generally related to air masses from south China and the Indochina peninsula, while lower concentrations of GEM were related to air masses from the open sea area, reflecting great Hg emissions from south China and Indochina peninsula. The mean concentrations of THg, MeHg, and DGM in surface seawater were 1.2 ± 0.3 ng L-1, 0.12 ± 0.05 ng L-1, and 36.5 ± 14.9 pg L-1, respectively. In general, THg and MeHg levels in the northern SCS were higher compared to results reported from most other oceans/seas. Elevated THg levels in the study area were likely attributed to significant Hg delivery from surrounding areas of the SCS primarily via atmospheric deposition and riverine input, whereas other sources like in situ production by various biotic and abiotic processes may be important for MeHg. Average sea/air flux of Hg in the study area was estimated using a gas exchange method (4.5 ± 3.4 ng m-2 h-1). This value was comparable to those from other coastal areas and generally higher than those from open sea environments, which may be attributed to the reemission of Hg previously transported to this area.

  3. First assessment of effects of air-gun seismic shooting on marine resources in the central Adriatic sea

    SciTech Connect

    La Bella, G.; Cannata, S.; Froglia, C.

    1996-11-01

    A series of investigations were carried out to test the effects of air-gun seismic shooting on main fishery resources of the Adriatic Sea during summer 1995. The energy source used for the trial was formed by one air-gun array made up by two sub-arrays consisting in 8 air-guns each developing a total volume of c.a. 2500 i{sup 3} at 2000 psi with an amplitude of 60 bar/m. The interval between two was of 25 s. The intensity was of 210 dB re 1 mPa-m/Hz. Acoustical and spectral analysis were performed simultaneously in the surveyed areas to correlate fishery and behavior observations with sound pattern of the energization. Main results were: (1) Analysis of trawl catch data evidenced no significant changes before and after the air-gun seismic profiling. (2) Echosurvey relative estimate of pelagic biomass, performed simultaneously to trawling operations, failed to evidence any significant change in the pelagic biomass subsequent to the seismic shooting. (3) Small differences were observed in the trammel net catch composition, but one single set of pre-post fishing operations could be done in the study period. (4) Similar density estimate were obtained from dredge surveys performed by an hydraulic dredger before and after air-gun seismic profiling over a clam bed in 14 in depth. (5) Video recording of captive fish, kept into cages moored on the sea bottom at 12 in depth, evidenced a Behavioral response to the approach of the sound source; but no lethal event was recorded on captive sea-bass immediately after the seismic shooting. (6) Biochemical and histological analysis were performed to verify if it is to be related to the captive condition or is somewhat consequent to the air-gun energization. These results confirm that no relevant effects are induced on fishery resources by seismic air-gun shooting.

  4. Air-sea boundary layer dynamics in the presence of mesoscale surface currents

    NASA Astrophysics Data System (ADS)

    Rooth, Claes; Xie, Lian

    1992-09-01

    In the presence of surface currents, a shear stress at the air-sea interface is induced by the surface currents. In the case of a unidirectional current, a quadratic stress law leads to a stress curl proportional to and opposing the surface current vorticity even with a uniform wind. This causes a spindown effect on the surface vorticity field at a rate proportional to the wind speed. In the steady state, or in slowly varying processes which can be treated as parametrically developing quasi-steady states, the surface-layer potential vorticity modulation causes upwelling and downwelling patterns associated with the surface-current vorticity. These effects are analyzed for an idealized jet current, and for a physical situation characteristic of a Gulf Stream boundary ring along the Florida Keys, where the induced transport patterns may be important for onshore transport of fish and spiny lobster larvae, as well as for onshore transport to the Florida Keys of general flotsam transported past them by the Gulf Stream. The spindown time scale (t*) for a 1.5-layer system is H/( ρ'cdVa) for a surface jet on the deformation radius scale (where H is the thickness of the surface layer, Va the surface wind speed, ρ' the air to water density ratio and cd the surface drag coefficient) and increases for large horizontal scales in proportion to the current width squared. For a typical wind speed of 5 m/s and a density normalized drag coefficient ρ'cd= 2 × 10-6, t* is on the order of 1 month for a 30-m surface layer. In the more general case of a stratified interior water column, the vorticity spindown directly affects only the potential vorticity of the surface layer and generally leads to subsurface velocity and vorticity maxima for mesoscale eddies and jets.

  5. Spatial and temporal variability of air-sea CO2 exchange of alongshore waters in summer near Barrow, Alaska

    NASA Astrophysics Data System (ADS)

    Ikawa, Hiroki; Oechel, Walter C.

    2014-03-01

    Alongshore water off Barrow, Alaska is a useful area for studying the carbon cycle of the Arctic coastal sea, because the different coastal characteristics extant in the area likely represent much larger regions of the coastal water of the western Arctic Ocean. Especially noteworthy is the inflow shelf water transferred northward by the Arctic Coastal Current into the Chukchi Sea from the North Pacific and turbid water in the Elson Lagoon where a significant amount of coastal erosion has been reported along the extensive coastal line and where a part of the water from the lagoon drains into the Beaufort Sea adjacent to the Chukchi Sea. To investigate spatial and temporal variations of air-sea CO2 flux (CO2 flux) of the alongshore water, partial pressure of CO2 of surface seawater (pCO2sw) was measured in summer, 2007 and 2008, and CO2 flux was directly measured by eddy covariance at a fixed point for the Beaufort Sea in summer 2008. Measured pCO2sw in the Chukchi Sea side was the lowest in the beginning of the measurement season and increased later in the season both in 2007 and 2008. The average CO2 flux estimated based on pCO2sw in the Chukchi Sea side was -0.10 μmol m-2 s-1 (±0.1 s.d.) using the sign convention of positive fluxes into the atmosphere from the ocean. pCO2sw in the Beaufort Sea and the Elson Lagoon was relatively higher in early summer and decreased in the middle of the summer. The overall average CO2 flux was -0.07 μmol m-2 s-1 (±0.1 s.d.) for the Beaufort Sea side and -0.03 μmol m-2 s-1 (±0.07 s.d.) for the Elson Lagoon respectively, indicating a sink of CO2 despite high carbon inflows from the terrestrial margin into the Elson Lagoon. A strong sink of CO2 was often observed from the Beaufort Sea by eddy covariance in the middle of the summer. This sink activity in the middle summer in the Beaufort Sea and Elson Lagoon was likely due to biological carbon uptake as inferred by low apparent oxygen utilization and high chlorophyll

  6. Mississippi State University Center for Air Sea Technology FY95 Research Program

    NASA Technical Reports Server (NTRS)

    Yeske, Lanny; Corbin, James H.

    1995-01-01

    The Mississippi State University (MSU) Center for Air Sea Technology (CAST) evolved from the Institute for Naval Oceanography's (INO) Experimental Center for Mesoscale Ocean Prediction (ECMOP) which was started in 1989. MSU CAST subsequently began operation on 1 October 1992 under an Office of Naval Research (ONR) two-year grant which ended on 30 September 1994. In FY95 MSU CAST was successful in obtaining five additional research grants from ONR, as well as several other research contracts from the Naval Oceanographic Office via NASA, the Naval Research Laboratory, the Army Corps of Engineers, and private industry. In the past, MSU CAST technical research and development has produced tools, systems, techniques, and procedures that improve efficiency and overcome deficiency for both the operational and research communities residing with the Department of Defense, private industry, and university ocean modeling community. We continued this effort with the following thrust areas: to develop advanced methodologies and tools for model evaluation, validation and visualization, both oceanographic and atmospheric; to develop a system-level capability for conducting temporally and ; spatially scaled ocean simulations driven by or are responsive to ocean models, and take into consideration coupling to atmospheric models; to continue the existing oceanographic/atmospheric data management task with emphasis on distributed databases in a network environment, with database optimization and standardization, including use of Mosaic and World Wide Web (WWW) access; and to implement a high performance parallel computing technology for CAST ocean models

  7. A Unified Air-Sea Visualization System: Survey on Gridding Structures

    NASA Technical Reports Server (NTRS)

    Anand, Harsh; Moorhead, Robert

    1995-01-01

    The goal is to develop a Unified Air-Sea Visualization System (UASVS) to enable the rapid fusion of observational, archival, and model data for verification and analysis. To design and develop UASVS, modelers were polled to determine the gridding structures and visualization systems used, and their needs with respect to visual analysis. A basic UASVS requirement is to allow a modeler to explore multiple data sets within a single environment, or to interpolate multiple datasets onto one unified grid. From this survey, the UASVS should be able to visualize 3D scalar/vector fields; render isosurfaces; visualize arbitrary slices of the 3D data; visualize data defined on spectral element grids with the minimum number of interpolation stages; render contours; produce 3D vector plots and streamlines; provide unified visualization of satellite images, observations and model output overlays; display the visualization on a projection of the users choice; implement functions so the user can derive diagnostic values; animate the data to see the time-evolution; animate ocean and atmosphere at different rates; store the record of cursor movement, smooth the path, and animate a window around the moving path; repeatedly start and stop the visual time-stepping; generate VHS tape animations; work on a variety of workstations; and allow visualization across clusters of workstations and scalable high performance computer systems.

  8. Influence of precipitation on the CO2 air-sea flux, an eddy covariance field study

    NASA Astrophysics Data System (ADS)

    Zavarsky, Alexander; Steinhoff, Tobias; Marandino, Christa

    2016-04-01

    During the SPACES-OASIS cruise (July-August 2015) from Durban, SA to Male, MV direct fluxes of CO2 and dimethyl sulfide (DMS) were measured using the eddy covariance (EC) technique. The cruise covered areas of sources and sinks for atmospheric CO2, where the bulk concentration gradient measurements resembled the Takahashi (2009) climatology. Most of the time, bulk CO2 fluxes (F=k* [cwater-cair]), calculated with the parametrization (k) by Nightingale et al. 2000, were in general agreement with direct EC measurements. However, during heavy rain events, the directly measured CO2 fluxes were 4 times higher than predicted. It has been previously described that rain influences the k parametrization of air-sea gas exchange, but this alone cannot explain the measured discrepancy. There is evidence that freshwater input and a change in the carbonate chemistry causes the water side concentration of ?c=cwater-cair to decrease. Unfortunately this cannot be detected by most bulk measurement systems. Using the flux measurements of an additional gas like DMS, this rain influence can be evaluated as DMS does not react to changes in the carbonate system and has a different solubility. A pending question is if the enhanced flux of CO2 in the ocean is sequestered into the ocean mixed layer and below. This question will be tackled using the GOTM model to understand the implications for the global carbon cycle.

  9. Distinctive precursory air-sea signals between regular and super El Niños

    NASA Astrophysics Data System (ADS)

    Chen, Lin; Li, Tim; Behera, Swadhin K.; Doi, Takeshi

    2016-08-01

    Statistically different precursory air-sea signals between a super and a regular El Niño group are investigated, using observed SST and rainfall data, and oceanic and atmospheric reanalysis data. The El Niño events during 1958-2008 are first separated into two groups: a super El Niño group (S-group) and a regular El Niño group (R-group). Composite analysis shows that a significantly larger SST anomaly (SSTA) tendency appears in S-group than in R-group during the onset phase [April-May(0)], when the positive SSTA is very small. A mixed-layer heat budget analysis indicates that the tendency difference arises primarily from the difference in zonal advective feedback and the associated zonal current anomaly ( u'). This is attributed to the difference in the thermocline depth anomaly ( D') over the off-equatorial western Pacific prior to the onset phase, as revealed by three ocean assimilation products. Such a difference in D' is caused by the difference in the wind stress curl anomaly in situ, which is mainly regulated by the anomalous SST and precipitation over the Maritime Continent and equatorial Pacific.

  10. Tuning a physically-based model of the air-sea gas transfer velocity

    NASA Astrophysics Data System (ADS)

    Jeffery, C. D.; Robinson, I. S.; Woolf, D. K.

    Air-sea gas transfer velocities are estimated for one year using a 1-D upper-ocean model (GOTM) and a modified version of the NOAA-COARE transfer velocity parameterization. Tuning parameters are evaluated with the aim of bringing the physically based NOAA-COARE parameterization in line with current estimates, based on simple wind-speed dependent models derived from bomb-radiocarbon inventories and deliberate tracer release experiments. We suggest that A = 1.3 and B = 1.0, for the sub-layer scaling parameter and the bubble mediated exchange, respectively, are consistent with the global average CO 2 transfer velocity k. Using these parameters and a simple 2nd order polynomial approximation, with respect to wind speed, we estimate a global annual average k for CO 2 of 16.4 ± 5.6 cm h -1 when using global mean winds of 6.89 m s -1 from the NCEP/NCAR Reanalysis 1 1954-2000. The tuned model can be used to predict the transfer velocity of any gas, with appropriate treatment of the dependence on molecular properties including the strong solubility dependence of bubble-mediated transfer. For example, an initial estimate of the global average transfer velocity of DMS (a relatively soluble gas) is only 11.9 cm h -1 whilst for less soluble methane the estimate is 18.0 cm h -1.

  11. Design and manufacturing considerations for high-performance gimbals used for land, sea, air, and space

    NASA Astrophysics Data System (ADS)

    Sweeney, Mike; Redd, Lafe; Vettese, Tom; Myatt, Ray; Uchida, David; Sellers, Del

    2015-09-01

    High performance stabilized EO/IR surveillance and targeting systems are in demand for a wide variety of military, law enforcement, and commercial assets for land, sea, air, and space. Operating ranges, wavelengths, and angular resolution capabilities define the requirements for EO/IR optics and sensors, and line of sight stabilization. Many materials and design configurations are available for EO/IR pointing gimbals depending on trade-offs of size, weight, power (SWaP), performance, and cost. Space and high performance military aircraft applications are often driven toward expensive but exceptionally performing beryllium and aluminum beryllium components. Commercial applications often rely on aluminum and composite materials. Gimbal design considerations include achieving minimized mass and inertia simultaneous with demanding structural, thermal, optical, and scene stabilization requirements when operating in dynamic operational environments. Manufacturing considerations include precision lapping and honing of ball bearing interfaces, brazing, welding, and casting of complex aluminum and beryllium alloy structures, and molding of composite structures. Several notional and previously developed EO/IR gimbal platforms are profiled that exemplify applicable design and manufacturing technologies.

  12. Descriptive Epidemiology of Musculoskeletal Injuries in Naval Special Warfare Sea, Air, and Land Operators.

    PubMed

    Lovalekar, Mita; Abt, John P; Sell, Timothy C; Wood, Dallas E; Lephart, Scott M

    2016-01-01

    The purpose of this analysis was to describe medical chart reviewed musculoskeletal injuries among Naval Special Warfare Sea, Air, and Land Operators. 210 Operators volunteered (age: 28.1 ± 6.0 years, height: 1.8 ± 0.1 m, weight: 85.4 ± 9.3 kg). Musculoskeletal injury data were extracted from subjects' medical charts, and injuries that occurred during 1 year were described. Anatomic location of injury, cause of injury, activity when injury occurred, and injury type were described. The frequency of injuries was 0.025 per Operator per month. Most injuries involved the upper extremity (38.1% of injuries). Frequent anatomic sublocations for injuries were the shoulder (23.8%) and lumbopelvic region of the spine (12.7%). Lifting was the cause of 7.9% of injuries. Subjects were participating in training when 38.1% of injuries occurred and recreational activity/sports when 12.7% of injuries occurred. Frequent injury types were strain (20.6%), pain/spasm/ache (19.0%), fracture (11.1%), and sprain (11.1%). The results of this analysis underscore the need to investigate the risk factors, especially of upper extremity and physical activity related injuries, in this population of Operators. There is a scope for development of a focused, customized injury prevention program, targeting the unique injury profile of this population. PMID:26741478

  13. A SOLAS challenge: How can we test test feedback loops involving air-sea exchange?

    NASA Astrophysics Data System (ADS)

    Huebert, B. J.

    2004-12-01

    It is now well accepted that the Earth System links biological and physical processes in the water, on land, and in the air, creating countless feedback loops and dependencies that are at best difficult to quantify. One example of interest to SOLAS scientists is the suspension and long-range transport of dust from Asia, which may or may not interact with acidic air pollutants, that may increase the biological availability of iron, thereby increasing primary productivity in parts of the Pacific. This could increase DMS emissions and modify the radiative impact of Pacific clouds, affecting the climate and the hydrological system that limits the amount of dust lofted each year. Air-sea exchange is central to many such feedbacks: Variations in productivity in upwelling waters off Peru probably change DMS emissions and modify the stratocumulus clouds that blanket that region, thereby feeding back to productivity. The disparate time and space scales of the controlling processes make it difficult to observationally constrain such systems without the use of multi-year time-series and intensive multiplatform process studies. Unfortunately, much of the infrastructure for funding Earth science is poorly suited for supporting multidisciplinary research. For example, NSF's program managers are organized into disciplines and sub-disciplines, and rely on disciplinary reviewer communities that are protective of their slices of the funding pie. It is easy to find authors of strong, innovative, cross-disciplinary (yet unsuccessful) proposals who say they'll never try it again, because there is so little institutional support for interfacial research. Facility issues also complicate multidisciplinary projects, since there are usually several allocating groups that don't want to commit their ships, airplanes, or towers until the other groups have done so. The result is that there are very few examples of major interdisciplinary projects, even though IGBP core programs have articulated

  14. Air

    MedlinePlus

    ... do to protect yourself from dirty air . Indoor air pollution and outdoor air pollution Air can be polluted indoors and it can ... this chart to see what things cause indoor air pollution and what things cause outdoor air pollution! Indoor ...

  15. Sea ice pCO2 dynamics and air-ice CO2 fluxes during the Sea Ice Mass Balance in the Antarctic (SIMBA) experiment - Bellingshausen Sea, Antarctica

    NASA Astrophysics Data System (ADS)

    Geilfus, N.-X.; Tison, J.-L.; Ackley, S. F.; Galley, R. J.; Rysgaard, S.; Miller, L. A.; Delille, B.

    2014-12-01

    Temporal evolution of pCO2 profiles in sea ice in the Bellingshausen Sea, Antarctica, in October 2007 shows physical and thermodynamic processes controls the CO2 system in the ice. During the survey, cyclical warming and cooling strongly influenced the physical, chemical, and thermodynamic properties of the ice cover. Two sampling sites with contrasting characteristics of ice and snow thickness were sampled: one had little snow accumulation (from 8 to 25 cm) and larger temperature and salinity variations than the second site, where the snow cover was up to 38 cm thick and therefore better insulated the underlying sea ice. We show that each cooling/warming event was associated with an increase/decrease in the brine salinity, total alkalinity (TA), total dissolved inorganic carbon (TCO2), and in situ brine and bulk ice CO2 partial pressures (pCO2). Thicker snow covers reduced the amplitude of these changes: snow cover influences the sea ice carbonate system by modulating the temperature and therefore the salinity of the sea ice cover. Results indicate that pCO2 was undersaturated with respect to the atmosphere both in the in situ bulk ice (from 10 to 193 μatm) and brine (from 65 to 293 μatm), causing the sea ice to act as a sink for atmospheric CO2 (up to 2.9 mmol m-2 d-1), despite supersaturation of the underlying seawater (up to 462 μatm).

  16. Interannual variability of the Indian summer monsoon associated with the air-sea feedback in the northern Indian Ocean

    NASA Astrophysics Data System (ADS)

    Shukla, Ravi P.; Huang, Bohua

    2016-03-01

    Using observation-based analyses, this study identifies the leading interannual pattern of the Indian summer monsoon rainfall (ISMR) independent of ENSO and examines the potential mechanisms of its formation. For this purpose, an objective procedure is used to isolate the variability of the summer precipitation associated with the contemporary ENSO state and in previous winter-spring, which influence the Indian summer monsoon (ISM) region in opposite ways. It is shown that the leading pattern of these ENSO-related monsoon rainfall anomalies reproduces some major ISMR features and well represents its connections to the global-scale ENSO features in both lower and upper troposphere. On the other hand, the leading pattern derived from the precipitation anomalies with the ENSO component removed in the ISM and surrounding region also accounts for a substantial amount of the monsoon precipitation centered at the eastern coast of the subtropical Arabian Sea, extending into both the western Indian Ocean and the Indian subcontinent. The associated atmospheric circulation change is regional in nature, mostly confined in the lower to mid troposphere centered in the Arabian Sea, with a mild connection to an opposite tendency centered at the South China Sea. Further analyses show that this regional pattern is associated with a thermodynamic air-sea feedback during early to mid summer season. Specifically, before the monsoon onset, an anomalous atmospheric high pressure over the Arabian Sea causes excessive shortwave radiation to the sea surface and increases SST in May. The warm SST anomalies peak in June and reduce the sea level pressure. The anomalous cyclonic circulation generates regional convection and precipitation, which also induces subsidence and anticyclonic circulation over the South China Sea. The combined cyclonic-anticyclonic circulation further transport moisture from the western Pacific into the Indian Ocean and causes its convergence into the Arabian Sea. As a

  17. CLOUDS, AEROSOLS, RADIATION AND THE AIR-SEA INTERFACE OF THE SOUTHERN OCEAN: ESTABLISHING DIRECTIONS FOR FUTURE RESEARCH

    SciTech Connect

    Wood, Robert; Bretherton, Chris; McFarquhar, Greg; Protat, Alain; Quinn, Patricia; Siems, Steven; Jakob, Christian; Alexander, Simon; Weller, Bob

    2014-09-29

    A workshop sponsored by the Department of Energy was convened at the University of Washington to discuss the state of knowledge of clouds, aerosols and air-sea interaction over the Southern Ocean and to identify strategies for reducing uncertainties in their representation in global and regional models. The Southern Ocean plays a critical role in the global climate system and is a unique pristine environment, yet other than from satellite, there have been sparse observations of clouds, aerosols, radiation and the air-sea interface in this region. Consequently, much is unknown about atmospheric and oceanographic processes and their linkage in this region. Approximately 60 scientists, including graduate students, postdoctoral fellows and senior researchers working in atmospheric and oceanic sciences at U.S. and foreign universities and government laboratories, attended the Southern Ocean Workshop. It began with a day of scientific talks, partly in plenary and partly in two parallel sessions, discussing the current state of the science for clouds, aerosols and air-sea interaction in the Southern Ocean. After the talks, attendees broke into two working groups; one focused on clouds and meteorology, and one focused on aerosols and their interactions with clouds. This was followed by more plenary discussion to synthesize the two working group discussions and to consider possible plans for organized activities to study clouds, aerosols and the air-sea interface in the Southern Ocean. The agenda and talk slides, including short summaries of the highlights of the parallel session talks developed by the session chars, are available at http://www.atmos.washington.edu/socrates/presentations/SouthernOceanPresentations/.

  18. Model studies of the flux of CO{sub 2} over the air-sea interface in the Baltic Sea

    SciTech Connect

    Ohlson, M.

    1994-12-31

    In the discussion about the green house effect generated by the burning of fossil fuels, carbon dioxide (CO{sub 2}) has a key role. A major part of the surplus CO{sub 2} has been suggested, by the scientific community, to be withdrawn from the atmosphere and to be taken up by the growth in continental shelf areas with high primary production, and in terrestrial forests. The exact quantity and reaction ways and mechanisms of those processes are not known today. The Baltic Sea is, for several reasons, a well chosen area to study this phenomenon. It is a shallow continental Mediterranean sea, in this area almost the first measurements of the carbonate system were carried out in the end of the last century. This has resulted in long time series of measurements of the carbonate system available for use in, e.g. modelling work, a working numerical carbonate model.

  19. High-resolution simulations of heavy precipitation events: role of the Adriatic SST and air-sea interactions

    NASA Astrophysics Data System (ADS)

    Davolio, Silvio; Stocchi, Paolo

    2016-04-01

    Strong Bora and Sirocco winds over the Adriatic Sea favour intense air-sea interactions and are often associated with heavy rainfall that affects the mountainous areas surrounding the basin. A convection-permitting model (MOLOCH) has been implemented at high resolution (2 km) in order to analyse several precipitation events over northern Italy, occurred during different seasons of the year and presenting different rainfall characteristics (stratiform, convective, orographic), and to possibly identify the relevant physical mechanisms involved. With the aim of assessing the impact of the sea surface temperature (SST) and surface fluxes on the intensity and location of the rainfall, sensitivity experiments have been performed taking into account the possible variability of SST analysis for model initialization. The model has been validated and specific diagnostic tools have been developed and applied to evaluate the vertically integrated moisture fluxes feeding the precipitating system or to compute a water balance in the atmosphere over the sea. The results show that the Adriatic Sea plays a role in determining the boundary layer characteristics through exchange of heat and moisture thus modifying the low-level flow dynamics and its interaction with the orography. This in turn impacts on the rainfall. Although the results vary among the analysed events, the precise definition of the SST and its evolution can be relevant for accurate precipitation forecasting.

  20. The exchange of SVOCs across the air-sea interface in Singapore's coastal environment

    NASA Astrophysics Data System (ADS)

    He, J.; Balasubramanian, R.

    2010-02-01

    Coastal areas are vulnerable to the accumulation of semivolatile organic compounds, such as PAHs, OCPs and PCBs from atmospheric inputs. Dry particulate and wet depositions, and air-water diffusive exchange in the Singapore's south coastal area, where most of chemical and oil refinery industries are situated in, were estimated. Based on a yearly dataset, the mean annual dry particulate deposition fluxes of ∑16-PAHs, ∑7 OCPs and ∑21 PCBs were 1328.8±961.1 μg m-2 y-1, 5421.4±3426.7 ng m-2 y-1 and 811.8±578.3 ng m-2 y-1, and the wet deposition of ∑16-PAHs and ∑7 OCPs were 6667.1±1745.2 and 115.4±98.3 μg m-2 y-1, respectively. Seasonal variation of atmospheric depositions was influenced by meteorological conditions. Air-water gas exchange fluxes were shown to be negative values for PAHs, HCHs and DDXs, indicating Singapore's south coast as a sink for the above-mentioned SVOCs. The relative contribution of each depositional process to the total atmospheric input was assessed by annual fluxes. The profile of dry particulate deposition, wet deposition and gas exchange fluxes seemed to be correlated with individual pollutant's properties such as molecular weight and Henry's law constant, etc. For the water column partitioning, the organic carbon-normalized partition coefficients between particulate and dissolved phases (KOC) for both PAHs and OCPs were obtained. The relationships between KOC of PAHs and OCPs and their respective octanol-water partition coefficient (KOW) were examined. In addition, both adsorption onto combustion-derived soot carbon and absorption into natural organic matter for PAHs in marine water column were investigated. Enrichment factors in the sea-surface microlayer (SML) of the particulate phase were 1.2-7.1 and 3.0-4.9 for PAHs and OCPs, and those of dissolved phase were 1.1-4.9 and 1.6-4.2 for PAHs and OCPs, respectively. These enrichment factors are relatively higher than those reported for nearby coastal areas, which

  1. The exchange of SVOCs across the air-sea interface in Singapore's coastal environment

    NASA Astrophysics Data System (ADS)

    He, J.; Balasubramanian, R.

    2009-06-01

    Coastal areas are vulnerable to the accumulation of semi-volatile organic compounds such as PAHs, OCPs and PCBs from atmospheric inputs. Dry particulate and wet depositions, and air-water diffusive exchange in the Singapore's south coastal area, where most of chemical and oil refinery industries are situated in, were estimated. Based on a yearly dataset, the mean annual dry particulate deposition fluxes of ∑16PAHs, ∑7OCPs and ∑21PCBs were 1328.8±961.1 μg m-2 y-1, 5421.4±3426.7 ng m-2 y-1 and 811.8±578.3 ng m-2 y-1, and the wet deposition of ∑16PAHs and ∑7OCPs were 6667.1±1745.2 and 115.4±98.3 μg m-2 y-1, respectively. Seasonal variation of atmospheric depositions was influenced by meteorological conditions. Air-water gas exchange fluxes had negative values for PAHs, HCHs and DDXs, indicating Singapore's south coast as a sink for the above-mentioned SVOCs. The relative contribution of each depositional process to the total atmospheric input was assessed by annual fluxes. The profile of dry particulate deposition, wet deposition and gas exchange fluxes seemed to be correlated with individual pollutant's properties such as molecular weight and Henry's law constant, etc. For the water column partitioning, the organic carbon-normalized partition coefficients between particulate and dissolved phases (KOC) for both PAHs and OCPs were obtained. The relationships between KOC of PAHs and OCPs and their respective octanol-water partition coefficient (KOW) were examined. In addition, both adsorption onto combustion-derived soot carbon and absorption into natural organic matter for PAHs in marine water column were investigated. Enrichment factors in the sea-surface microlayer (SML) of the particulate phase were 1.2~7.1 and 3.0~4.9 for PAHs and OCPs, and those of dissolved phase were 1.1~4.9 and 1.6~4.2 for PAHs and OCPs, respectively. These enrichment factors are relatively higher than those reported for nearby coastal areas, which are most likely due

  2. Biases in the air-sea flux of CO2 resulting from ocean surface temperature gradients

    NASA Astrophysics Data System (ADS)

    Ward, B.; Wanninkhof, R.; McGillis, W. R.; Jessup, A. T.; Degrandpre, M. D.; Hare, J. E.; Edson, J. B.

    2004-08-01

    The difference in the fugacities of CO2 across the diffusive sublayer at the ocean surface is the driving force behind the air-sea flux of CO2. Bulk seawater fugacity is normally measured several meters below the surface, while the fugacity at the water surface, assumed to be in equilibrium with the atmosphere, is measured several meters above the surface. Implied in these measurements is that the fugacity values are the same as those across the diffusive boundary layer. However, temperature gradients exist at the interface due to molecular transfer processes, resulting in a cool surface temperature, known as the skin effect. A warm layer from solar radiation can also result in a heterogeneous temperature profile within the upper few meters of the ocean. Here we describe measurements carried out during a 14-day study in the equatorial Pacific Ocean (GasEx-2001) aimed at estimating the gradients of CO2 near the surface and resulting flux anomalies. The fugacity measurements were corrected for temperature effects using data from the ship's thermosalinograph, a high-resolution profiler (SkinDeEP), an infrared radiometer (CIRIMS), and several point measurements at different depths on various platforms. Results from SkinDeEP show that the largest cool skin and warm layer biases occur at low winds, with maximum biases of -4% and +4%, respectively. Time series ship data show an average CO2 flux cool skin retardation of about 2%. Ship and drifter data show significant CO2 flux enhancement due to the warm layer, with maximums occurring in the afternoon. Temperature measurements were compared to predictions based on available cool skin parameterizations to predict the skin-bulk temperature difference, along with a warm layer model.

  3. An assessment of air-sea heat fluxes from ocean and coupled reanalyses

    NASA Astrophysics Data System (ADS)

    Valdivieso, Maria; Haines, Keith; Balmaseda, Magdalena; Chang, You-Soon; Drevillon, Marie; Ferry, Nicolas; Fujii, Yosuke; Köhl, Armin; Storto, Andrea; Toyoda, Takahiro; Wang, Xiaochun; Waters, Jennifer; Xue, Yan; Yin, Yonghong; Barnier, Bernard; Hernandez, Fabrice; Kumar, Arun; Lee, Tong; Masina, Simona; Andrew Peterson, K.

    2015-10-01

    Sixteen monthly air-sea heat flux products from global ocean/coupled reanalyses are compared over 1993-2009 as part of the Ocean Reanalysis Intercomparison Project (ORA-IP). Objectives include assessing the global heat closure, the consistency of temporal variability, comparison with other flux products, and documenting errors against in situ flux measurements at a number of OceanSITES moorings. The ensemble of 16 ORA-IP flux estimates has a global positive bias over 1993-2009 of 4.2 ± 1.1 W m-2. Residual heat gain (i.e., surface flux + assimilation increments) is reduced to a small positive imbalance (typically, +1-2 W m-2). This compensation between surface fluxes and assimilation increments is concentrated in the upper 100 m. Implied steady meridional heat transports also improve by including assimilation sources, except near the equator. The ensemble spread in surface heat fluxes is dominated by turbulent fluxes (>40 W m-2 over the western boundary currents). The mean seasonal cycle is highly consistent, with variability between products mostly <10 W m-2. The interannual variability has consistent signal-to-noise ratio (~2) throughout the equatorial Pacific, reflecting ENSO variability. Comparisons at tropical buoy sites (10°S-15°N) over 2007-2009 showed too little ocean heat gain (i.e., flux into the ocean) in ORA-IP (up to 1/3 smaller than buoy measurements) primarily due to latent heat flux errors in ORA-IP. Comparisons with the Stratus buoy (20°S, 85°W) over a longer period, 2001-2009, also show the ORA-IP ensemble has 16 W m-2 smaller net heat gain, nearly all of which is due to too much latent cooling caused by differences in surface winds imposed in ORA-IP.

  4. Regionalized global budget of the CO2 exchange at the air-water interface in continental shelf seas

    NASA Astrophysics Data System (ADS)

    Laruelle, Goulven G.; Lauerwald, Ronny; Pfeil, Benjamin; Regnier, Pierre

    2014-11-01

    Over the past decade, estimates of the atmospheric CO2 uptake by continental shelf seas were constrained within the 0.18-0.45 Pg C yr-1 range. However, most of those estimates are based on extrapolations from limited data sets of local flux measurements (n < 100). Here we propose to derive the CO2 air-sea exchange of the shelf seas by extracting 3 · 106 direct surface ocean CO2 measurements from the global database SOCAT (Surface Ocean CO2 Atlas), atmospheric CO2 values from GlobalVIEW and calculating gas transfer rates using readily available global temperature, salinity, and wind speed fields. We then aggregate our results using a global segmentation of the shelf in 45 units and 152 subunits to establish a consistent regionalized CO2 exchange budget at the global scale. Within each unit, the data density determines the spatial and temporal resolutions at which the air-sea CO2 fluxes are calculated and range from a 0.5° resolution in the best surveyed regions to a whole unit resolution in areas where data coverage is limited. Our approach also accounts, for the first time, for the partial sea ice cover of polar shelves. Our new regionalized global CO2 sink estimate of 0.19 ± 0.05 Pg C yr-1 falls in the low end of previous estimates. Reported to an ice-free surface area of 22 · 106 km2, this value yields a flux density of 0.7 mol C m-2 yr-1, ~40% more intense than that of the open ocean. Our results also highlight the significant contribution of Arctic shelves to this global CO2 uptake (0.07 Pg C yr-1).

  5. The organic sea-surface microlayer in the upwelling region off the coast of Peru and potential implications for air-sea exchange processes

    NASA Astrophysics Data System (ADS)

    Engel, Anja; Galgani, Luisa

    2016-02-01

    The sea-surface microlayer (SML) is at the uppermost surface of the ocean, linking the hydrosphere with the atmosphere. The presence and enrichment of organic compounds in the SML have been suggested to influence air-sea gas exchange processes as well as the emission of primary organic aerosols. Here, we report on organic matter components collected from an approximately 50 µm thick SML and from the underlying water (ULW), ˜ 20 cm below the SML, in December 2012 during the SOPRAN METEOR 91 cruise to the highly productive, coastal upwelling regime off the coast of Peru. Samples were collected at 37 stations including coastal upwelling sites and off-shore stations with less organic matter and were analyzed for total and dissolved high molecular weight (> 1 kDa) combined carbohydrates (TCCHO, DCCHO), free amino acids (FAA), total and dissolved hydrolyzable amino acids (THAA, DHAA), transparent exopolymer particles (TEP), Coomassie stainable particles (CSPs), total and dissolved organic carbon (TOC, DOC), total and dissolved nitrogen (TN, TDN), as well as bacterial and phytoplankton abundance. Our results showed a close coupling between organic matter concentrations in the water column and in the SML for almost all components except for FAA and DHAA that showed highest enrichment in the SML on average. Accumulation of gel particles (i.e., TEP and CSP) in the SML differed spatially. While CSP abundance in the SML was not related to wind speed, TEP abundance decreased with wind speed, leading to a depletion of TEP in the SML at about 5 m s-1. Our study provides insight to the physical and biological control of organic matter enrichment in the SML, and discusses the potential role of organic matter in the SML for air-sea exchange processes.

  6. Does atmospheric CO2 seasonality play an important role in governing the air-sea flux of CO2?

    NASA Astrophysics Data System (ADS)

    Halloran, P. R.

    2012-06-01

    The amplitude, phase, and form of the seasonal cycle of atmospheric CO2 concentrations varies on many time and space scales (Peters et al., 2007). Intra-annual CO2 variation is primarily driven by seasonal uptake and release of CO2 by the terrestrial biosphere (Machta et al., 1977; Buchwitz et al., 2007), with a small (Cadule et al., 2010; Heimann et al., 1998), but potentially changing (Gorgues et al., 2010) contribution from the ocean. Variability in the magnitude, spatial distribution, and seasonal drivers of terrestrial net primary productivity (NPP) will be induced by, amongst other factors, anthropogenic CO2 release (Keeling et al., 1996), land-use change (Zimov et al., 1999) and planetary orbital variability, and will lead to changes in CO2atm seasonality. Despite CO2atm seasonality being a dynamic and prominent feature of the Earth System, its potential to drive changes in the air-sea flux of CO2 has not previously (to the best of my knowledge) been explored. It is important that we investigate the impact of CO2atm seasonality change, and the potential for carbon-cycle feedbacks to operate through the modification of the CO2atm seasonal cycle, because the decision had been made to prescribe CO2atm concentrations (rather than emissions) within model simulations for the fifth IPCC climate assessment (Taylor et al., 2009). In this study I undertake ocean-model simulations within which different magnitude CO2atm seasonal cycles are prescribed. These simulations allow me to examine the effect of a change in CO2atm seasonal cycle magnitude on the air-sea CO2 flux. I then use an off-line model to isolate the drivers of the identified air-sea CO2 flux change, and propose mechanisms by which this change may come about. Three mechanisms are identified by which co-variability of the seasonal cycles in atmospheric CO2 concentration, and seasonality in sea-ice extent, wind-speed and ocean temperature, could potentially lead to changes in the air-sea flux of CO2 at mid

  7. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

    NASA Astrophysics Data System (ADS)

    Lammel, Gerhard; Meixner, Franz X.; Vrana, Branislav; Efstathiou, Christos I.; Kohoutek, Jiři; Kukučka, Petr; Mulder, Marie D.; Přibylová, Petra; Prokeš, Roman; Rusina, Tatsiana P.; Song, Guo-Zheng; Tsapakis, Manolis

    2016-05-01

    As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Δc/Δz > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8 µg m-2 day-1 for PAHs and -3.4 to +0.9 µg m-2 day-1 for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.

  8. Synoptic evaluation of carbon cycling in Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M.

    2013-10-01

    The accelerated decline in Arctic sea ice combined with an ongoing trend toward a more dynamic atmosphere is modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of identifying indices of ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. The mean atmospheric forcing was a mild upwelling-favorable wind (~5 km h-1) blowing from the N-E and a decaying ice cover (<80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2 with a mean uptake rate of -2.0 ± 3.3 mmol C m-2d-1. We attribute this discrepancy to: (1) elevated PP rates (>600 mg C m-2d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (>10mmol C m-2d-1). Although generally <100 mg C m-2d-1, daily PP rates cumulated to a total PP of ~437.6 × 103 t C, which was roughly twice higher than the organic carbon delivery by river inputs (~241.2 × 103 t C). Subsurface PP represented 37.4% of total PP for the

  9. Sedation and anesthesia of hatchling leatherback sea turtles (Dermochelys coriacea) for auditory evoked potential measurement in air and in water.

    PubMed

    Harms, Craig A; Piniak, Wendy E D; Eckert, Scott A; Stringer, Elizabeth M

    2014-03-01

    Sedation or anesthesia of hatchling leatherback sea turtles was employed to acquire auditory evoked potential (AEP) measurements in air and in water to assess their hearing sensitivity in relation to potential consequences from anthropogenic noise. To reduce artifacts in AEP collection caused by muscle movement, hatchlings were sedated with midazolam 2 or 3 mg/kg i.v. for in-air (n = 7) or in-water (n = 11) AEP measurements; hatchlings (n = 5) were anesthetized with ketamine 6 mg/kg and dexmedetomidine 30 microg/kg i.v. reversed with atipamezole 300 microg/kg, half i.m. and half i.v. for in-air AEP measurements. Midazolam-sedated turtles were also physically restrained with a light elastic wrap. For in-water AEP measurements, sedated turtles were brought to the surface every 45-60 sec, or whenever they showed intention signs for breathing, and not submerged again until they took a breath. Postprocedure temperature-corrected venous blood pH, pCO2, pO2, and HCO3- did not differ among groups, although for the midazolam-sedated in-water group, pCO2 trended lower, and in the ketamine-dexmedetomidine anesthetized group there was one turtle considered clinically acidotic (temperature-corrected pH = 7.117). Venous blood lactate was greater for hatchlings recently emerged from the nest than for turtles sedated with midazolam in air, with the other two groups falling intermediate between, but not differing significantly from the high and low lactate groups. Disruptive movements were less frequent with anesthesia than with sedation in the in-air group. Both sedation with midazolam and anesthesia with ketamine-dexmedetomidine were successful for allowing AEP measurements in hatchling leatherback sea turtles. Sedation allowed the turtle to protect its airway voluntarily while limiting flipper movement. Midazolam or ketamine-dexmedetomidine (and reversal with atipamezole) would be useful for other procedures requiring minor or major restraint in leatherback sea turtle hatchlings

  10. Dust in the Earth system: the biogeochemical linking of land, air and sea.

    PubMed

    Ridgwell, Andy J

    2002-12-15

    Understanding the response of the Earth's climate system to anthropogenic perturbation has been a pressing priority for society since the late 1980s. However, recent years have seen a major paradigm shift in how such an understanding can be reached. Climate change demands analysis within an integrated 'Earth-system' framework, taken to encompass the suite of interacting physical, chemical, biological and human processes that, in transporting and transforming materials and energy, jointly determine the conditions for life on the whole planet. This is a highly complex system, characterized by multiple nonlinear responses and thresholds, with linkages often between apparently disparate components. The interconnected nature of the Earth system is wonderfully illustrated by the diverse roles played by atmospheric transport of mineral 'dust', particularly in its capacity as a key pathway for the delivery of nutrients essential to plant growth, not only on land, but perhaps more importantly, in the ocean. Dust therefore biogeochemically links land, air and sea. This paper reviews the biogeochemical role of mineral dust in the Earth system and its interaction with climate, and, in particular, the potential importance of both past and possible future changes in aeolian delivery of the micro-nutrient iron to the ocean. For instance, if, in the future, there was to be a widespread stabilization of soils for the purpose of carbon sequestration on land, a reduction in aeolian iron supply to the open ocean would occur. The resultant weakening of the oceanic carbon sink could potentially offset much of the carbon sequestered on land. In contrast, during glacial times, enhanced dust supply to the ocean could have 'fertilized' the biota and driven atmospheric CO(2) lower. Dust might even play an active role in driving climatic change; since changes in dust supply may affect climate, and changes in climate, in turn, influence dust, a 'feedback loop' is formed. Possible feedback

  11. Air-Sea Exchange and Budget of Sulfur and Oxygen-Containing Volatile Organic Compounds in the Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Tanimoto, H.; Omori, Y.; Inomata, S.; Iwata, T.; Kameyama, S.

    2015-12-01

    By combining proton transfer reaction-mass spectrometry (PTR-MS) and gradient flux (GF) technique, in situ measurement of air-sea fluxes of multiple volatile organic compounds (VOCs) was developed and deployed. Starting in 2008, we made in situ observations of air-sea fluxes at 15 locations as well as underway observations of marine air/surface seawater bulk concentrations in the Pacific Ocean, during eight research cruises by R/V Hakuho-Maru. The fluxes of biogenic trace gases, DMS and isoprene, were always positive, with the magnitudes being in accordance with previously reported. In contrast, the fluxes of oxygenated VOCs including acetone and acetaldehyde varied from negative to positive, suggesting that the tropical and subtropical Pacific are a source, while the North Pacific is a sink. A basin-scale budget of VOCs were determined for 4 biogeochemical provinces in the Pacific Ocean, and the role of oceans for VOCs were discussed with respect to physical and biogeochemical processes.

  12. Exchange of polycyclic aromatic hydrocarbons across the air-water interface in the Bohai and Yellow Seas

    NASA Astrophysics Data System (ADS)

    Chen, Yingjun; Lin, Tian; Tang, Jianhui; Xie, Zhiyong; Tian, Chongguo; Li, Jun; Zhang, Gan

    2016-09-01

    In this study, air and surface seawater samples collected from the Bohai (BS) and Yellow Seas (YS) in May 2012 were determined exchange of PAHs, especially of low-molecular-weight (LMW) PAHs (three- and four-ring PAHs) at the air-water interface. Net volatilization fluxes of LMW PAHs were 266-1454 ng/m2/d and decreased with distance from the coast, indicating that these PAHs transported from coastal runoff were potential contributors to the atmosphere in the BS and YS. Moreover, LMW PAHs were enriched in the dissolved phase compared with those in the particulate phase in the water column, possibly suggesting that the volatilized LMW PAHs were directly derived from wastewater discharge or petroleum pollution rather than released from contaminated sediments. The air-sea exchange fluxes of the three-ring PAHs were 2- to 20-fold higher than their atmospheric deposition fluxes in the BS and YS. The input to and output from the water reached equilibrium for four-ring PAHs. Differently, five- and six-ring PAHs were introduced into the marine environment primarily through dry and wet deposition, indicating that the water column was still a sink of these PAHs from the surrounding atmosphere.

  13. Composition of primary cosmic rays near the bend from a study of hadrons in air showers at sea level

    NASA Technical Reports Server (NTRS)

    Mincer, A. I.; Freudenreich, H. T.; Goodman, J. A.; Tonwar, S. C.; Yodh, G. B.; Ellsworth, R. W.; Berley, D.

    1985-01-01

    Data on hadrons in air showers arriving at sea level were studied to find sensitivity to primary cosmic ray composition. The rate of showers which satisfy minimum shower density and hadron energy requirements as well as the rate of showers containing hadrons delayed with respect to the electron shower front are compared to Monte Carlo simulations. The data on the rate of total triggers and delayed hadrons are compared to predicted rates for two models of primary composition. The data are consistent with models which require an increasing heavy nuclei fraction near 10 to the 15th power eV. The spectra which are consistent with the observed rate are also compared to the observed shower size spectrum at sea level and mountain level.

  14. Air-sea CO2 fluxes measured by eddy covariance in a coastal station in Baja California, México

    NASA Astrophysics Data System (ADS)

    Gutiérrez-Loza, L.; Ocampo-Torres, F. J.

    2016-05-01

    The influence of wave-associated parameters controlling turbulent CO2 fluxes through the air-sea water interface is evaluated in a coastal region. The study area, located within the Todos Santos Bay, Baja California, México, was found to be a weak sink of CO2 with a mean flux of -1.32 µmol m-2s-1. The low correlation found between flux and wind speed (r = 0.09), suggests that the influence of other forcing mechanisms, besides wind, is important for gas transfer modulation through the sea surface, at least for the conditions found in this study. In addition, the results suggest that for short periods where an intensification of the wave conditions occurs, a CO2 flux response increases the transport of gas to the ocean.

  15. Dissolved methane concentration profiles and air-sea fluxes from 41°S to 27°N

    NASA Astrophysics Data System (ADS)

    Kelley, Cheryl A.; Jeffrey, Wade H.

    2002-07-01

    Water column samples from a transect cruise from southern Chile through the Panama Canal to the Gulf of Mexico were used to determine dissolved methane depth profiles and air-sea methane fluxes. In the Gulf of Mexico, surface concentrations were approximately 40% supersaturated with respect to the atmosphere, whereas near the equator and in the Peru upwelling region, 10-20% supersaturation generally occurred. These saturation ratios translate into an average flux of methane from the sea surface to the atmosphere of 0.38 μmol m-2 d-1. In addition, water column profiles of dissolved methane indicate that subsurface maxima in dissolved methane concentrations are a consistent feature of the open ocean, except near the equator. At the equator, the subsurface peak at the base of the mixed layer may be bowed down by the Equatorial Undercurrent. The highest methane concentration (12 nM) was observed in the Peru upwelling region.

  16. The impact of shipping emissions on air pollution in the greater North Sea region - Part 1: Current emissions and concentrations

    NASA Astrophysics Data System (ADS)

    Aulinger, A.; Matthias, V.; Zeretzke, M.; Bieser, J.; Quante, M.; Backes, A.

    2016-01-01

    The North Sea is one of the areas with the highest ship traffic densities worldwide. At any time, about 3000 ships are sailing its waterways. Previous scientific publications have shown that ships contribute significantly to atmospheric concentrations of NOx, particulate matter and ozone. Especially in the case of particulate matter and ozone, this influence can even be seen in regions far away from the main shipping routes. In order to quantify the effects of North Sea shipping on air quality in its bordering states, it is essential to determine the emissions from shipping as accurately as possible. Within Interreg IVb project Clean North Sea Shipping (CNSS), a bottom-up approach was developed and used to thoroughly compile such an emission inventory for 2011 that served as the base year for the current emission situation. The innovative aspect of this approach was to use load-dependent functions to calculate emissions from the ships' current activities instead of averaged emission factors for the entire range of the engine loads. These functions were applied to ship activities that were derived from hourly records of Automatic Identification System signals together with a database containing the engine characteristics of the vessels that traveled the North Sea in 2011. The emission model yielded ship emissions among others of NOx and SO2 at high temporal and spatial resolution that were subsequently used in a chemistry transport model in order to simulate the impact of the emissions on pollutant concentration levels. The total emissions of nitrogen reached 540 Gg and those of sulfur oxides 123 Gg within the North Sea - including the adjacent western part of the Baltic Sea until 5° W. This was about twice as much of those of a medium-sized industrialized European state like the Netherlands. The relative contribution of ships to, for example, NO2 concentration levels ashore close to the sea can reach up to 25 % in summer and 15 % in winter. Some hundred kilometers

  17. Effect of Sampling Depth on Air-Sea CO2 Flux Estimates in River-Stratified Arctic Coastal Waters

    NASA Astrophysics Data System (ADS)

    Miller, L. A.; Papakyriakou, T. N.

    2015-12-01

    In summer-time Arctic coastal waters that are strongly influenced by river run-off, extreme stratification severely limits wind mixing, making it difficult to effectively sample the surface 'mixed layer', which can be as shallow as 1 m, from a ship. During two expeditions in southwestern Hudson Bay, off the Nelson, Hayes, and Churchill River estuaries, we confirmed that sampling depth has a strong impact on estimates of 'surface' pCO2 and calculated air-sea CO2 fluxes. We determined pCO2 in samples collected from 5 m, using a typical underway system on the ship's seawater supply; from the 'surface' rosette bottle, which was generally between 1 and 3 m; and using a niskin bottle deployed at 1 m and just below the surface from a small boat away from the ship. Our samples confirmed that the error in pCO2 derived from typical ship-board versus small-boat sampling at a single station could be nearly 90 μatm, leading to errors in the calculated air-sea CO2 flux of more than 0.1 mmol/(m2s). Attempting to extrapolate such fluxes over the 6,000,000 km2 area of the Arctic shelves would generate an error approaching a gigamol CO2/s. Averaging the station data over a cruise still resulted in an error of nearly 50% in the total flux estimate. Our results have implications not only for the design and execution of expedition-based sampling, but also for placement of in-situ sensors. Particularly in polar waters, sensors are usually deployed on moorings, well below the surface, to avoid damage and destruction from drifting ice. However, to obtain accurate information on air-sea fluxes in these areas, it is necessary to deploy sensors on ice-capable buoys that can position the sensors in true 'surface' waters.

  18. Biogenic Production of Reactive Bromocarbons: New Field Data and sea-air Fluxes in the Atlantic Ocean

    NASA Astrophysics Data System (ADS)

    Dunk, R. M.; Jones, C. E.; Hornsby, K. E.; Keely, B. J.; Poulton, A. J.; Carpenter, L. J.

    2007-12-01

    Biogenic bromine production by phytoplankton and macroalgae is thought to represent an important link between ocean biology, climate and atmospheric composition. Models of atmospheric bromine chemistry suggest that natural sources of bromocarbons such as CHBr3 and CH2Br2 may account for up to 30% of stratospheric and tropospheric O3 depletion. However, at present these models are limited by the accuracy to which the bromine source terms can be described. In particular, simultaneous measurements of ocean surface water and marine boundary layer bromocarbon concentrations are lacking, limiting the ability to estimate sea to air fluxes to a reasonable degree of accuracy. Furthermore, little is known regarding the factors that control biogenic bromine production, or the temporal and spatial variability of the bromine source term at the regional scale. We present new data from two research cruises during which we measured a range of bromocarbons, including CHBr3, CH2Br2 and CH2IBr, in both surface seawater and the marine boundary layer using two GC-MS systems. The first cruise was to the North Eastern Atlantic (latitudinal range 53-59°N) in summer 2006, while the second cruise was to the Tropical and Subtropical Atlantic and the Mauritanian Upwelling (latitudinal range 16-30°N) in spring 2007. Concentration data and resulting sea air fluxes generally decrease in the order coastal > shelf > upwelling ~ open ocean. Although a broad trend of elevated seawater concentrations in waters with high chlorophyll a (phytoplankton productivity proxy) is observed, the relationship is not simple. We explore this complex relationship between phytoplankton and bromocarbon production in more detail, examining changes in phytoplankton assemblage and health as indicated by cell counts and pigment distributions. We then use these relationships to present a revised regional estimate for the North Atlantic sea to air flux of biogenic bromine.

  19. The Influence of Tropical Air-Sea Interaction on the Climate Impact of Aerosols: A Hierarchical Modeling Approach

    NASA Astrophysics Data System (ADS)

    Hsieh, W. C.; Saravanan, R.; Chang, P.; Mahajan, S.

    2014-12-01

    In this study, we use a hierarchical modeling approach to investigate the influence of tropical air-sea feedbacks on climate impacts of aerosols in the Community Earth System Model (CESM). We construct four different models by coupling the atmospheric component of CESM, the Community Atmospheric Model (CAM), to four different ocean models: (i) the Data Ocean Model (DOM; prescribed SST), (i) Slab Ocean Model (SOM; thermodynamic coupling), (iii) Reduced Gravity Ocean Model (RGOM; dynamic coupling), and (iv) the Parallel Ocean Program (POP; full ocean model). These four models represent progressively increasing degree of coupling between the atmosphere and the ocean. The RGOM model, in particular, is tuned to produce a good simulation of ENSO and the associated tropical air-sea interaction, without being impacted by the climate drifts exhibited by fully-coupled GCMs. For each method of coupling, a pair of numerical experiments, including present day (year 2000) and preindustrial (year 1850) sulfate aerosol loading, were carried out. Our results indicate that the inclusion of air-sea interaction has large impacts on the spatial structure of the climate response induced by aerosols. In response to sulfate aerosol forcing, ITCZ shifts southwards as a result of the anomalous clockwise MMC change which transports moisture southwardly across the Equator. We present analyses of the regional response to sulfate aerosol forcing in the equatorial Pacific as well as the zonally-averaged response. The decomposition of the change in the net surface energy flux shows the most dominant terms are net shortwave radiative flux at the surface and latent heat flux. Further analyses show all ocean model simulations simulate a positive change of northward atmospheric energy transport across the Equator in response to the perturbed radiative sulfate forcing. This positive northward atmospheric energy transport change plays a role in compensating partially cooling caused by sulfate aerosols.

  20. APO observations in Southern Greenland: evaluation of modelled air-sea O2 and CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Bonne, Jean-Louis; Bopp, Laurent; Delmotte, Marc; Cadule, Patricia; Resplandy, Laure; Nevison, Cynthia; Manizza, Manfredi; Valentin Lavric, Jost; Manning, Andrew C.; Masson-Delmotte, Valérie

    2014-05-01

    Since September 2007, the atmospheric CO2 mole fraction and O2/N2 ratio (a proxy for O2 concentration) have been monitored continuously at the coastal site of Ivittuut, southern Greenland (61.21° N, 48.17° W). From 2007 to 2013, our measurements show multi-annual trends of +2.0 ppm/year and -20 per meg/year respectively for CO2 and O2/N2, with annual average peak-to-peak seasonal amplitudes of 14+/-1 ppm and 130+/-15 per meg. We investigate the implications of our data set in terms of APO (Atmospheric Potential Oxygen). This tracer, obtained by a linear combination of CO2 and O2/N2 data, is invariant to CO2 and O2 exchanges in the land biota, but sensitive to the oceanic component of the O2 cycle. It is used as a bridge to evaluate air-sea CO2 and O2 fluxes from atmospheric variations of CO2 and O2/N2. Global ocean biogeochemical models produce estimates of CO2 and O2 air-sea fluxes. Atmospheric APO variations can be simulated through transportation of these fluxes in the atmosphere by Eulerian transport models. Thus, model values of atmospheric APO can be extracted at the station location. This study is based on air-sea flux outputs from CMIP5 simulations. After atmospheric transportation, they give access to atmospheric APO climatologies which can be compared, in terms of seasonal cycles and inter-annual variability, to the in situ observations. A preliminary study is based on the CCSM ocean model air-sea fluxes transported in the atmosphere with the MATCH transport model, over the period 1979-2004. The amplitude of the APO seasonal cycle is correctly captured, but year to year variations on this seasonal cycle appears to be underestimated compared to observations. The LMDZ atmospheric transport model is also used to transport the ocean fluxes from five CMIP5 models, over the period 1979-2005, showing different amplitudes and timings of APO seasonal cycles. This methodology is a first step to evaluate the origin of observed APO variations at our site and then

  1. Study of air-sea interaction processes over the Arabian Sea and the Bay of Bengal using satellite data

    SciTech Connect

    Gautam, N.; Simon, B.; Pandey, P.C.

    1995-12-01

    The main objective of this work is to study the latitudinal and seasonal variation of latent heat fluxes (LHF) and associated atmospheric and oceanic parameters over the Arabian Sea (AS) and the Bay of Bengal (BB) for the year 1988. A significant latitudinal variation is observed in LHF for most of the months over the AS and the BB, while other oceanic and atmospheric parameters are characterized by a strong latitudinal variation in nonmonsoon months. Seasonal variations in LHF are more significant at higher latitudes compared to lower latitudes over the AS and the BB. The effect of coastal upwelling near the Somali coast decreases LHF, while surface winds near the Indian coast during monsoon months increases LHF. A comparative study over the AS and the BB demonstrates higher PW and SST over the BB than over the AS. LHF is found to be greater over the AS than over the BB for nonmonsoon months. Correlation analysis indicates that LHF is found to be highly correlated with DQ (difference between the humidity at the surface and humidity near the surface) over the AS and weakly correlated over the BB during nonmonsoon months. Throughout the year, DQ is found to be a dominant factor for LHF over the AS. However, WS exercised better control over the BB in generating LHF. SST and PW are found to be highly correlated with each other over the AS (r = 0.87) and the BB (r = 0.75) for nonmonsoon months. The correlation becomes weakly negative over the AS (r = 0.15) and weak over the BB (r = 0.26) during monsoon months. Precipitable water is found to have a high correlation with WS over the AS (r = 0.72). This unique feature is revealed by SSM/I data and has not been reported earlier due to paucity of data over this region.

  2. CLIVAR-GSOP/GODAE Ocean Synthesis Inter-Comparison of Global Air-Sea Fluxes From Ocean and Coupled Reanalyses

    NASA Astrophysics Data System (ADS)

    Valdivieso, Maria

    2014-05-01

    The GODAE OceanView and CLIVAR-GSOP ocean synthesis program has been assessing the degree of consistency between global air-sea flux data sets obtained from ocean or coupled reanalyses (Valdivieso et al., 2014). So far, fifteen global air-sea heat flux products obtained from ocean or coupled reanalyses have been examined: seven are from low-resolution ocean reanalyses (BOM PEODAS, ECMWF ORAS4, JMA/MRI MOVEG2, JMA/MRI MOVECORE, Hamburg Univ. GECCO2, JPL ECCOv4, and NCEP GODAS), five are from eddy-permitting ocean reanalyses developed as part of the EU GMES MyOcean program (Mercator GLORYS2v1, Reading Univ. UR025.3, UR025.4, UKMO GloSea5, and CMCC C-GLORS), and the remaining three are couple reanalyses based on coupled climate models (JMA/MRI MOVE-C, GFDL ECDA and NCEP CFSR). The global heat closure in the products over the period 1993-2009 spanned by all data sets is presented in comparison with observational and atmospheric reanalysis estimates. Then, global maps of ensemble spread in the seasonal cycle, and of the Signal to Noise Ratio of interannual flux variability over the 17-yr common period are shown to illustrate the consistency between the products. We have also studied regional variability in the products, particularly at the OceanSITES project locations (such as, for instance, the TAO/TRITON and PIRATA arrays in the Tropical Pacific and Atlantic, respectively). Comparisons are being made with other products such as OAFlux latent and sensible heat fluxes (Yu et al., 2008) combined with ISCCP satellite-based radiation (Zhang et al., 2004), the ship-based NOC2.0 product (Berry and Kent, 2009), the Large and Yeager (2009) hybrid flux dataset CORE.2, and two atmospheric reanalysis products, the ECMWF ERA-Interim reanalysis (referred to as ERAi, Dee et al., 2011) and the NCEP/DOE reanalysis R2 (referred to as NCEP-R2, Kanamitsu et al., 2002). Preliminary comparisons with the observational flux products from OceanSITES are also underway. References Berry, D

  3. The impact of shipping emissions on air pollution in the Greater North Sea region - Part 1: Current emissions and concentrations

    NASA Astrophysics Data System (ADS)

    Aulinger, A.; Matthias, V.; Zeretzke, M.; Bieser, J.; Quante, M.; Backes, A.

    2015-04-01

    The North Sea is one of the areas with the highest ship traffic densities worldwide. At any time, about 3000 ships are sailing its waterways. Previous scientific publications have shown that ships contribute significantly to atmospheric concentrations of NOx, particulate matter and ozone. Especially in the case of particulate matter and ozone this influence can even be seen in regions far away from the main shipping routes. In order to quantify the effects of North Sea shipping on air quality in its bordering states, it is essential to determine the emissions from shipping as accurately as possible. Within the Interreg IVb project Clean North Sea Shipping (CNSS) a bottom-up approach was developed and used to thoroughly compile such an emission inventory for 2011 that served as the base year for the current emission situation. The innovative aspect of this approach was to use load dependent functions to calculate emissions from the ships' current activities instead of averaged emission factors for the entire range of the engine loads. These functions were applied to ship activities that were derived from hourly records of Automatic Identification System signals together with a data base containing the engine characteristics of the vessels that traveled the North Sea in 2011. The emission model yielded ship emissions among others of NOx and SO2 in high temporal and spatial resolution that were subsequently used in a chemistry transport model in order to simulate the impact of the emissions on pollutant concentration levels. The total emissions of nitrogen reached 540 Gg and of sulfur oxides 123 Gg within the North Sea, which was about twice as much of those of a medium-sized industrialized European state like the Netherlands. The relative contribution of ships to, for example, NO2 concentration levels ashore close to the sea can reach up to 25% in summer and 15% in winter. Some hundred kilometers away from the sea the contribution was about 6% in summer and 4% in

  4. Destruction of Iodocarbons in Surface Seawater - Implications for Sea-Air Flux Calculations and the Atmospheric Iodine Budget

    NASA Astrophysics Data System (ADS)

    Jones, C. E.; Dunk, R. M.; Hornsby, K. E.; McFiggans, G.; Carpenter, L. J.

    2007-12-01

    Although it is now widely accepted that CH3I is the major volatile organic source of iodine from the surface ocean to the atmosphere, CH3I emissions alone cannot balance the global iodine budget, which implies that there must be some additional source(s). Seawater and air measurements made during two cruises in the Atlantic Ocean during summer 2006 and spring 2007 suggest that other iodocarbons, in particular the dihaloalkanes CH2I2, CH2IBr and CH2ICl, may provide a combined global iodine atom source which is comparable to that of CH3I. However, deriving sea-to-air fluxes of these volatile gases is not straightforward. Established flux parameterizations are based on air and surface water concentrations, but seawater samples from ship campaigns are typically taken from at least 2-6 m depth (since there are technical difficulties associated with sampling closer to the surface). Given its relatively long lifetime in the oceans, sea-air fluxes of CH3I may be adequately approximated directly from concentrations measured a few metres below the surface, however for the dihalomethanes this is likely to give rise to considerable inaccuracies due to their short lifetimes with respect to photolysis in surface waters. Consequently, we have used a one-dimensional oceanic mixed layer model to constrain the extent of dihalomethane photodecay within the top few metres of the water column such that we can extrapolate surface seawater concentrations from sub-surface measurements, which in turn allows more accurate sea-air fluxes to be determined for these gases. A number of mono-iodinated alkanes were also detected in Atlantic seawater, including C2H5I and 1- C3H7I. Laboratory based studies have been carried out in order to parameterize the temperature- dependent chemical destruction of a number of mono-iodinated alkanes in saltwater, such that the oceanic lifetimes of these species may be predicted as a simple function of the surface seawater temperature. In light of these results

  5. Air-sea fluxes of CO2 and CH4 from the Penlee Point Atmospheric Observatory on the south-west coast of the UK

    NASA Astrophysics Data System (ADS)

    Yang, Mingxi; Bell, Thomas G.; Hopkins, Frances E.; Kitidis, Vassilis; Cazenave, Pierre W.; Nightingale, Philip D.; Yelland, Margaret J.; Pascal, Robin W.; Prytherch, John; Brooks, Ian M.; Smyth, Timothy J.

    2016-05-01

    We present air-sea fluxes of carbon dioxide (CO2), methane (CH4), momentum, and sensible heat measured by the eddy covariance method from the recently established Penlee Point Atmospheric Observatory (PPAO) on the south-west coast of the United Kingdom. Measurements from the south-westerly direction (open water sector) were made at three different sampling heights (approximately 15, 18, and 27 m above mean sea level, a.m.s.l.), each from a different period during 2014-2015. At sampling heights ≥ 18 m a.m.s.l., measured fluxes of momentum and sensible heat demonstrate reasonable ( ≤ ±20 % in the mean) agreement with transfer rates over the open ocean. This confirms the suitability of PPAO for air-sea exchange measurements in shelf regions. Covariance air-sea CO2 fluxes demonstrate high temporal variability. Air-to-sea transport of CO2 declined from spring to summer in both years, coinciding with the breakdown of the spring phytoplankton bloom. We report, to the best of our knowledge, the first successful eddy covariance measurements of CH4 emissions from a marine environment. Higher sea-to-air CH4 fluxes were observed during rising tides (20 ± 3; 38 ± 3; 29 ± 6 µmole m-2 d-1 at 15, 18, 27 m a.m.s.l.) than during falling tides (14 ± 2; 22 ± 2; 21 ± 5 µmole m-2 d-1), consistent with an elevated CH4 source from an estuarine outflow driven by local tidal circulation. These fluxes are a few times higher than the predicted CH4 emissions over the open ocean and are significantly lower than estimates from other aquatic CH4 hotspots (e.g. polar regions, freshwater). Finally, we found the detection limit of the air-sea CH4 flux by eddy covariance to be 20 µmole m-2 d-1 over hourly timescales (4 µmole m-2 d-1 over 24 h).

  6. Atmospheric dry deposition in the vicinity of the Salton Sea, California - I: Air pollution and deposition in a desert environment

    USGS Publications Warehouse

    Alonso, R.; Bytnerowicz, A.; Boarman, W.I.

    2005-01-01

    Air pollutant concentrations and atmospheric dry deposition were monitored seasonally at the Salton Sea, southern California. Measurements of ozone (O 3), nitric acid vapor (HNO3), ammonia (NH3), nitric oxide (NO), nitrogen dioxide (NO2) and sulfur dioxide (SO 2) were performed using passive samplers. Deposition rates of NO 3-, NH4+, Cl-, SO 42-, Na+, K+ and Ca2+ to creosote bush branches and nylon filters as surrogate surfaces were determined for one-week long exposure periods. Maximum O3 values were recorded in spring with 24-h average values of 108.8 ??g m-3. Concentrations of NO and NO2 were low and within ranges of the non-urban areas in California (0.4-5.6 and 3.3-16.2 ??g m-3 ranges, respectively). Concentrations of HNO3 (2.0-6.7 ??g m-3) and NH 3 (6.4-15.7 ??g m-3) were elevated and above the levels typical for remote locations in California. Deposition rates of Cl-, SO42-, Na+, K+ and Ca2+ were related to the influence of sea spray or to suspended soil particles, and no strong enrichments caused by ions originated by human activities were detected. Dry deposition rates of NO3- and NH4+ were similar to values registered in areas where symptoms of nitrogen saturation and changes in species composition have been described. Deposition of nitrogenous compounds might be contributing to eutrophication processes at the Salton Sea. ?? 2005 Elsevier Ltd. All rights reserved.

  7. First day of an oil spill on the open sea: early mass transfers of hydrocarbons to air and water.

    PubMed

    Gros, Jonas; Nabi, Deedar; Würz, Birgit; Wick, Lukas Y; Brussaard, Corina P D; Huisman, Johannes; van der Meer, Jan R; Reddy, Christopher M; Arey, J Samuel

    2014-08-19

    During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m(3) oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km(2) area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models. PMID:25103722

  8. Using an ensemble data set of turbulent air-sea fluxes to evaluate the IPSL climate model in tropical regions

    NASA Astrophysics Data System (ADS)

    Gainusa-Bogdan, Alina; Servonnat, Jerome; Braconnot, Pascale

    2014-05-01

    Low-latitude turbulent ocean-atmosphere fluxes play a major role in the ocean and atmosphere dynamics, heat distribution and availability for meridional transport to higher latitudes, as well as for the global freshwater cycle. Their representation in coupled ocean-atmosphere models is thus of chief importance in climate simulations. Despite numerous reports of important observational uncertainties in large-scale turbulent flux products, only few model flux evaluation studies attempt to quantify and directly consider these uncertainties. To address this problem for large-scale, climatological flux evaluation, we assemble a comprehensive database of 14 climatological surface flux products, including in situ-based, satellite, hybrid and reanalysis data sets. We develop an associated analysis protocol and use it together with this database to offer an observational ensemble approach to model flux evaluation. We use this approach to perform an evaluation of the representation of the intertropical turbulent air-sea fluxes in a suite of CMIP5 historical simulations run with different recent versions of the IPSL model. To enhance model understanding, we consider both coupled and forced atmospheric model configurations. For the same purpose, we not only analyze the surface fluxes, but also their associated meteorological state variables and inter-variable relationships. We identify an important, systematic underestimation of the near-surface wind speed and a significant exaggeration of the sea-air temperature contrast in all the IPSL model versions considered. Furthermore, the coupled model simulations develop important sea surface temperature and associated air humidity bias patterns. Counterintuitively, these biases do not systematically transfer to significant biases in the surface fluxes. This is due to a combination of compensation of effects and the large flux observational spread. Our analyses reveal several inconsistencies in inter-variable relationships between

  9. Levels and spatial distribution of gaseous polychlorinated biphenyls and polychlorinated naphthalenes in the air over the northern South China Sea

    NASA Astrophysics Data System (ADS)

    Li, Qilu; Xu, Yue; Li, Jun; Pan, Xiaohui; Liu, Xiang; Zhang, Gan

    2012-09-01

    Monitoring marine persistent organic pollutants (POPs) is important because oceans play a significant role in the cycling of POPs. The South China Sea (SCS) is surrounded by developing countries in Southeast Asia which are centers of e-waste recycling and the ship dismantling industry. In this study, shipboard air samples collected over the SCS between September 6 and 22, 2005 were analyzed for polychlorinated biphenyls (PCBs) and polychlorinated naphthalenes (PCNs). The levels of ∑12PCBs ranged from 32.3 to 167 pg m-3, with a mean value of 98.4 ± 36.0 pg m-3. Tetra-CBs were the predominant congeners. The concentrations of ∑18PCNs ranged from N.D. to 26.0 pg m-3, with a mean value of 10.5 ± 7.16 pg m-3, and tri-CNs were predominant. The gaseous concentrations of PCBs and PCNs over the SCS were consistent with those over other seas and oceans. Compared with previous studies, it was found that the concentrations of PCBs exhibited an obviously declining trend. The measured PCB and PCN concentrations in the atmosphere over the SCS were influenced by their proximity to source regions and air mass origins. The highest gaseous PCB and PCN concentrations were found at sampling sites adjacent to the continental South China. E-waste recycling, ship dismantling and combustion in South China and some Southeast Asian countries might contribute PCBs and PCNs to the atmosphere of the SCS.

  10. Temporal variations in air-sea CO2 exchange near large kelp beds near San Diego, California

    NASA Astrophysics Data System (ADS)

    Ikawa, Hiroki; Oechel, Walter C.

    2015-01-01

    study presents nearly continuous air-sea CO2 flux for 7 years using the eddy covariance method for nearshore water near San Diego, California, as well as identifying environmental processes that appear to control temporal variations in air-sea CO2 flux at different time scales using time series decomposition. Monthly variations in CO2 uptake are shown to be positively influenced by photosynthetically active photon flux density (PPFD) and negatively related to wind speeds. In contrast to the monthly scale, wind speeds often influenced CO2 uptake positively on an hourly scale. Interannual variations in CO2 flux were not correlated with any independent variables, but did reflect surface area of the adjacent kelp bed in the following year. Different environmental influences on CO2 flux at different temporal scales suggest the importance of long-term flux monitoring for accurately identifying important environmental processes for the coastal carbon cycle. Overall, the study area was a strong CO2 sink into the sea (CO2 flux of ca. -260 g C m-2 yr-1). If all coastal areas inhabited by macrophytes had a similar CO2 uptake rate, the net CO2 uptake from these areas alone would roughly equal the net CO2 sink estimated for the entire global coastal ocean to date. A similar-strength CO2 flux, ranging between -0.09 and -0.01 g C m-2 h-1, was also observed over another kelp bed from a pilot study of boat-based eddy covariance measurements.

  11. Eddy covariance flux of sulfur dioxide to the sea surface: Air-side resistance to deposition of a highly soluble gas

    NASA Astrophysics Data System (ADS)

    Porter, J.; De Bruyn, W. J.; Miller, S. D.; Saltzman, E. S.

    2014-12-01

    Deposition to the sea surface represents a major atmospheric removal mechanism for sulfur dioxide and many other highly soluble products of tropospheric photochemistry. Such gases include nitric acid, ammonia, organic acids, sulfur dioxide, and highly soluble organic compounds such as methanol and acetone. The deposition of highly soluble gases is controlled by turbulent and diffusive transport on the air side of the air/sea interface. In this study, air/sea fluxes of the soluble gas sulfur dioxide (SO2 ), sensible and latent heat, and momentum were measured using eddy covariance. This was a pilot study carried out in April 2014 on Scripps pier in La Jolla, California, that was designed to assess the potential for measuring SO2 fluxes over the ocean. SO2 was detected using chemical ion mass spectrometry in negative ion mode with a sensitivity of roughly 100 Hz/ppt. The ionization scheme involved addition of ozone to a dried air stream and subsequent conversion of SO2 to the SO5 - ion. The results demonstrate the feasibility of seagoing SO2 flux measurements. Such measurements can be used to constrain the depositional velocities of soluble gases and test models for air-side resistance to air/sea gas transfer.

  12. MP3 - A Meteorology and Physical Properties Package for Titan Air-Sea Studies

    NASA Astrophysics Data System (ADS)

    Lorenz, R. D.; Stofan, E.; Lunine, J. I.; Zarnecki, J. C.; Harri, A.-M.; Karkoschka, E.; Newman, C. E.; Bierhaus, E. B.; Clark, B. C.; Yelland, M.; Leese, M. R.; Boldt, J.; Darlington, E.; Neish, C. D.; Sotzen, K.; Arvelo, J.; Rasbach, C.; Kretsch, W.; Strohbehn, K.; Grey, M.; Mann, J.; Zimmerman, H.; Reed, C.

    2012-10-01

    MP3 is a sensor suite for the proposed Titan Mare Explorer (TiME) Discovery mission to Ligeia Mare. MP3 will measure temperatures, and wind velocity, methane humidity, and pressure, as well as sea turbidity, dielectric properties, and depth via sonar.

  13. Low-frequency variability of surface air temperature over the Barents Sea: causes and mechanisms

    NASA Astrophysics Data System (ADS)

    van der Linden, Eveline C.; Bintanja, Richard; Hazeleger, Wilco; Graversen, Rune G.

    2016-08-01

    The predominant decadal to multidecadal variability in the Arctic region is a feature that is not yet well-understood. It is shown that the Barents Sea is a key region for Arctic-wide variability. This is an important topic because low-frequency changes in the ocean might lead to large variations in the sea-ice cover, which then cause massive changes in the ocean-atmosphere heat exchanges. Here we describe the mechanism driving surface temperatures and heat fluxes in the Barents Sea based primarily on analyzes of one global coupled climate model. It is found that the ocean drives the low-frequency changes in surface temperature, whereas the atmosphere compensates the oceanic transport anomalies. The seasonal dependence and the role of individual components of the ocean-atmosphere energy budget are analyzed in detail, showing that seasonally-varying climate mechanisms play an important role. Herein, sea ice is governing the seasonal response, by acting as a lid that opens and closes during warm and cold periods, respectively, thereby modulating the surface heat fluxes.

  14. Coupled Air-ocean Nested Modeling Studies Of The Adriatic Sea

    NASA Astrophysics Data System (ADS)

    Pullen, J.; Doyle, J.; Hodur, R.; Cummings, J.

    We have conducted simulations of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM), with surface forcing provided by the atmospheric component of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS). Our aim is to document and investigate the response pattern of the Adriatic to the complex combined forcing of the bora winds and strong Po River run-off. Separate three- dimensional multivariate optimum interpolation (MVOI) analysis techniques are used to generate the initial conditions for both COAMPS and NCOM. First, we used a 6-km NCOM grid over the entire Mediterranean Sea, with forcing supplied by sur- face stresses from a 27-km COAMPS grid, also covering the entire Mediterranean Sea area. Both the atmospheric and ocean fields produced were part of independent 12-hour incremental data assimilation cycles over the time period of interest. The re- sulting NCOM forecasts were then used as lateral boundary conditions for a series of higher resolution (2 km) NCOM forecasts of the Adriatic Sea. In these forecasts, a set of surface stress fields from COAMPS, using a nested 4 km grid centered over the Adriatic Sea, were used to force the NCOM high-resolution ocean nest. In addition, the 2 km Adriatic Sea model is forced by observed daily river discharge values from the Po River. We have focused on the time period of winter and spring 2001 when there were several bora wind events documented by the pilot program observations taken in preparation for the fall and winter 2002-2003 Adriatic Current Experiment (ACE). In addition, we analyze results from a multi-month simulation in fall/winter 1999 to establish circu- lation patterns that may appear during the upcoming observational season. The ACE observations will include ADCP's, moored buoys, CTD sections, and radar sites. The observational programs will generate much data about the circulation of this shallow sea subjected to river floods and strong bora wind events. The main goals of our work are to

  15. Guidelines for the air-sea interaction special study: An element of the NASA climate research program, JPL/SIO workshop report

    NASA Technical Reports Server (NTRS)

    1980-01-01

    A program in the area of air sea interactions is introduced. A space capability is discussed for global observations of climate parameters which will contribute to the understanding of the processes which influence climate and its predictability. The following recommendations are some of the suggestions made for air sea interaction studies: (1) a major effort needs to be devoted to the preparation of space based climatic data sets; (2) NASA should create a group or center for climatic data analysis due to the substantial long term effort that is needed in research and development; (3) funding for the analyses of existing data sets should be augmented and continued beyond the termination of present programs; (4) NASA should fund studies in universities, research institutions and governments' centers; and (5) the planning for an air sea interaction mission should be an early task.

  16. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

    NASA Astrophysics Data System (ADS)

    Gantt, B.; Kelly, J. T.; Bash, J. O.

    2015-11-01

    Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are also important due to the localized impact of SSAs on atmospheric chemistry near the coast. In this study, SSA emissions in the Community Multiscale Air Quality (CMAQ) model were updated to enhance the fine-mode size distribution, include sea surface temperature (SST) dependency, and reduce surf-enhanced emissions. Predictions from the updated CMAQ model and those of the previous release version, CMAQv5.0.2, were evaluated using several coastal and national observational data sets in the continental US. The updated emissions generally reduced model underestimates of sodium, chloride, and nitrate surface concentrations for coastal sites in the Bay Regional Atmospheric Chemistry Experiment (BRACE) near Tampa, Florida. Including SST dependency to the SSA emission parameterization led to increased sodium concentrations in the southeastern US and decreased concentrations along parts of the Pacific coast and northeastern US. The influence of sodium on the gas-particle partitioning of nitrate resulted in higher nitrate particle concentrations in many coastal urban areas due to increased condensation of nitric acid in the updated simulations, potentially affecting the predicted nitrogen deposition in sensitive ecosystems. Application of the updated SSA emissions to the California Research at the Nexus of Air Quality and Climate Change (CalNex) study period resulted in a modest improvement in the predicted surface concentration of sodium and nitrate at several central and southern California coastal sites. This update of SSA emissions enabled a more realistic simulation of the atmospheric chemistry in coastal environments where marine air mixes with urban pollution.

  17. A review of the sources of uncertainties when estimating global-scale turbulent air-sea fluxes

    NASA Astrophysics Data System (ADS)

    Brodeau, Laurent; Barnier, Bernard

    2015-04-01

    Bulk formulae are used to estimate turbulent air-sea fluxes needed to provide surface boundary conditions to most of present-day OGCMs, AGCMs and coupled Earth systems. This study aims at making an inventory of the major sources of uncertainties and errors made when estimating turbulent air-sea fluxes with the bulk method, namely wind stress, evaporation (latent heat flux) and sensible heat flux. We use 6-hourly near-surface atmospheric fields and daily SST of ERA-Interim to compute global estimates of these fluxes during the last three decades. Those fluxes are computed using different bulk routines and different types of physical and numerical simplifications widely used within the GCM community. Moreover, to assess the sensitivity of these flux estimates to possible errors in the input atmospheric fields and SST, user-controlled biases are applied to each of these fields prior to bulk computation. As a result, a quantification of the potential sources of uncertainties related to the accuracy of both the parametrization and input fields is proposed. Any parametrization-related approximation can also be expressed in terms of a bias on a given input field. We find that the largest source of flux uncertainties is the choice of the bulk algorithm used to estimate the bulk transfer coefficients. The resulting disagreement in terms of globally-averaged heat flux and evaporation is 8 W/m2 and 1 Sv. In mid latitudes, this heat flux disagreement is about 10 W/m2, which independently compares to a bias of 1 m/s in surface wind speed, 3° in SST, 0.5° in surface temperature, or a modification of 5% in the surface humidity. Our study also underlies the relative importance of the accuracy of the estimate of the air density and the specific humidity at saturation.

  18. Energetic delayed hadrons in large air showers observed at 5200m above sea level

    NASA Technical Reports Server (NTRS)

    Kaneko, T.; Hagiwara, K.; Yoshii, H.; Martinic, N.; Siles, L.; Miranda, P.; Kakimoto, F.; Tsuchimoto, I.; Inoue, N.; Suga, K.

    1985-01-01

    Energetic delayed hadrons in air showers with electron sizes in the range 10 to the 6th power to 10 to the 9th power were studied by observing the delayed bursts produced in the shield of nine square meter scintillation detectors in the Chacaltaya air-shower array. The frequency of such delayed burst is presented as a function of electron size, core distance and sec theta.

  19. Synoptic evaluation of carbon cycling in the Beaufort Sea during summer: contrasting river inputs, ecosystem metabolism and air-sea CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Forest, A.; Coupel, P.; Else, B.; Nahavandian, S.; Lansard, B.; Raimbault, P.; Papakyriakou, T.; Gratton, Y.; Fortier, L.; Tremblay, J.-É.; Babin, M.

    2014-05-01

    The accelerated decline in Arctic sea ice and an ongoing trend toward more energetic atmospheric and oceanic forcings are modifying carbon cycling in the Arctic Ocean. A critical issue is to understand how net community production (NCP; the balance between gross primary production and community respiration) responds to changes and modulates air-sea CO2 fluxes. Using data collected as part of the ArcticNet-Malina 2009 expedition in the southeastern Beaufort Sea (Arctic Ocean), we synthesize information on sea ice, wind, river, water column properties, metabolism of the planktonic food web, organic carbon fluxes and pools, as well as air-sea CO2 exchange, with the aim of documenting the ecosystem response to environmental changes. Data were analyzed to develop a non-steady-state carbon budget and an assessment of NCP against air-sea CO2 fluxes. During the field campaign, the mean wind field was a mild upwelling-favorable wind (~ 5 km h-1) from the NE. A decaying ice cover (< 80% concentration) was observed beyond the shelf, the latter being fully exposed to the atmosphere. We detected some areas where the surface mixed layer was net autotrophic owing to high rates of primary production (PP), but the ecosystem was overall net heterotrophic. The region acted nonetheless as a sink for atmospheric CO2, with an uptake rate of -2.0 ± 3.3 mmol C m-2 d-1 (mean ± standard deviation associated with spatial variability). We attribute this discrepancy to (1) elevated PP rates (> 600 mg C m-2 d-1) over the shelf prior to our survey, (2) freshwater dilution by river runoff and ice melt, and (3) the presence of cold surface waters offshore. Only the Mackenzie River delta and localized shelf areas directly affected by upwelling were identified as substantial sources of CO2 to the atmosphere (> 10 mmol C m-2 d-1). Daily PP rates were generally < 100 mg C m-2 d-1 and cumulated to a total PP of ~ 437.6 × 103 t C for the region over a 35-day period. This amount was about twice the

  20. In-Air Evoked Potential Audiometry of Grey Seals (Halichoerus grypus) from the North and Baltic Seas

    PubMed Central

    Ruser, Andreas; Dähne, Michael; Sundermeyer, Janne; Lucke, Klaus; Houser, Dorian S.; Finneran, James J.; Driver, Jörg; Pawliczka, Iwona; Rosenberger, Tanja; Siebert, Ursula

    2014-01-01

    In-air anthropogenic sound has the potential to affect grey seal (Halichoerus grypus) behaviour and interfere with acoustic communication. In this study, a new method was used to deliver acoustic signals to grey seals as part of an in-air hearing assessment. Using in-ear headphones with adapted ear inserts allowed for the measurement of auditory brainstem responses (ABR) on sedated grey seals exposed to 5-cycle (2-1-2) tone pips. Thresholds were measured at 10 frequencies between 1–20 kHz. Measurements were made using subcutaneous electrodes on wild seals from the Baltic and North Seas. Thresholds were determined by both visual and statistical approaches (single point F-test) and good agreement was obtained between the results using both methods. The mean auditory thresholds were ≤40 dB re 20 µPa peak equivalent sound pressure level (peSPL) between 4–20 kHz and showed similar patterns to in-air behavioural hearing tests of other phocid seals between 3 and 20 kHz. Below 3 kHz, a steep reduction in hearing sensitivity was observed, which differed from the rate of decline in sensitivity obtained in behavioural studies on other phocids. Differences in the rate of decline may reflect influence of the ear inserts on the ability to reliably transmit lower frequencies or interference from the structure of the distal end of the ear canal. PMID:24632891

  1. In-air evoked potential audiometry of grey seals (Halichoerus grypus) from the North and Baltic Seas.

    PubMed

    Ruser, Andreas; Dähne, Michael; Sundermeyer, Janne; Lucke, Klaus; Houser, Dorian S; Finneran, James J; Driver, Jörg; Pawliczka, Iwona; Rosenberger, Tanja; Siebert, Ursula

    2014-01-01

    In-air anthropogenic sound has the potential to affect grey seal (Halichoerus grypus) behaviour and interfere with acoustic communication. In this study, a new method was used to deliver acoustic signals to grey seals as part of an in-air hearing assessment. Using in-ear headphones with adapted ear inserts allowed for the measurement of auditory brainstem responses (ABR) on sedated grey seals exposed to 5-cycle (2-1-2) tone pips. Thresholds were measured at 10 frequencies between 1-20 kHz. Measurements were made using subcutaneous electrodes on wild seals from the Baltic and North Seas. Thresholds were determined by both visual and statistical approaches (single point F-test) and good agreement was obtained between the results using both methods. The mean auditory thresholds were ≤40 dB re 20 µPa peak equivalent sound pressure level (peSPL) between 4-20 kHz and showed similar patterns to in-air behavioural hearing tests of other phocid seals between 3 and 20 kHz. Below 3 kHz, a steep reduction in hearing sensitivity was observed, which differed from the rate of decline in sensitivity obtained in behavioural studies on other phocids. Differences in the rate of decline may reflect influence of the ear inserts on the ability to reliably transmit lower frequencies or interference from the structure of the distal end of the ear canal. PMID:24632891

  2. The air-sea equilibrium and time trend of hexachlorocyclohexanes in the Atlantic Ocean between the Arctic and Antarctica.

    PubMed

    Lakaschus, Sonke; Weber, Kurt; Wania, Frank; Bruhn, Regina; Schrems, Otto

    2002-01-15

    Hexachlorocyclohexanes (HCHs) were determined simultaneously in air and seawater during two cruises across the Atlantic Ocean between the Arctic Ocean (Ny-Alesund/ Svalbard, 79 degrees N; 12 degrees E) and the Antarctic Continent (Neumayer Station/ Ekstroem Ice Shelf, 70 degrees S; 8.2 degrees W) in 1999/ 2000. The concentrations of alpha-HCH and gamma-HCH in air and surface waters of the Arctic exceeded those in Antarctica by 1-2 orders of magnitude. The gaseous concentrations of gamma-HCH were highest above the North Sea and between 20 degrees N and 30 degrees S. Fugacity fractions were used to estimate the direction of the air-sea gas exchange. These showed for alpha-HCH thatthe measured concentrations in both phases were close to equilibrium in the North Atlantic (78 degrees N-40 degrees N), slightly undersaturated between 30 degrees N and 10 degrees S and again close to equilibrium between 20 degrees S and 50 degrees S. Y-HCH has reached phase equilibrium in the North Atlantic as alpha-HCH, but the surface waters of the tropical and southern Atlantic were strongly undersaturated with y-HCH, especially between 30 degrees N and 20 degrees S. These findings are significantly different from two earlier estimates around 1990 as a result of global emission changes within the past decade. Therefore, we investigated the time trend of the HCHs in the surface waters of the Atlantic between 50 degrees N and 60 degrees S on the basis of archived samples taken in 1987-1997 and those from 1999. A decrease of alpha-HCH by a factor of approximately 4 is observed at all sampling locations. No decrease of gamma-HCH occurred between 30 degrees N and 30 degrees S, but there was a decrease in the North Atlantic, North Sea, and in the South Atlantic south of 40 degrees S. The constant level of gamma-HCH in the tropical Atlantic confirms the conclusion that the tropical Atlantic acts as a sink for y-HCH at present time. The measured alpha-HCH seawater concentrations were compared

  3. Spatial and temporal variability of heat, water vapor, carbon dioxide, and momentum air-sea exchange in a coastal environment

    NASA Astrophysics Data System (ADS)

    Crawford, Timothy L.; McMillen, Robert T.; Meyers, Tilden P.; Hicks, Bruce B.

    1993-07-01

    Simultaneous eddy correlation measurements from a tower, a boat, and an aircraft platform are used to assess the spatial and temporal variability of heat, moisture, momentum, and CO2 turbulent fluxes in a coastal environment. Dissolved CO2 in the coastal waters and atmospheric CO2 concentrations were continuously measured throughout the experiment. Good agreement was found among the different sensing systems. Air-to-sea gas, momentum, and energy flux density measurements are shown to be achievable from both a boat and an aircraft. The observed 10 W/sq m sensible heat flux was time-invariant but did not vary spatially with surface temperature, which was strongly correlated with ocean depth. The 100 to 200 W/sq m evaporative moisture flux dominated energy exchange and varied both in time and space. No consistent diurnal variation was observed, but the spatial trend also followed surface temperature. CO2 exchange exhibited large spatial and temporal variance.

  4. Using wind setdown and storm surge on Lake Erie to calibrate the air-sea drag coefficient.

    PubMed

    Drews, Carl

    2013-01-01

    The air-sea drag coefficient controls the transfer of momentum from wind to water. In modeling storm surge, this coefficient is a crucial parameter for estimating the surge height. This study uses two strong wind events on Lake Erie to calibrate the drag coefficient using the Coupled Ocean Atmosphere Wave Sediment Transport (COAWST) modeling system and the the Regional Ocean Modeling System (ROMS). Simulated waves are generated on the lake with Simulating WAves Nearshore (SWAN). Wind setdown provides the opportunity to eliminate wave setup as a contributing factor, since waves are minimal at the upwind shore. The study finds that model results significantly underestimate wind setdown and storm surge when a typical open-ocean formulation without waves is used for the drag coefficient. The contribution of waves to wind setdown and storm surge is 34.7%. Scattered lake ice also increases the effective drag coefficient by a factor of 1.1. PMID:23977309

  5. Using Wind Setdown and Storm Surge on Lake Erie to Calibrate the Air-Sea Drag Coefficient

    PubMed Central

    Drews, Carl

    2013-01-01

    The air-sea drag coefficient controls the transfer of momentum from wind to water. In modeling storm surge, this coefficient is a crucial parameter for estimating the surge height. This study uses two strong wind events on Lake Erie to calibrate the drag coefficient using the Coupled Ocean Atmosphere Wave Sediment Transport (COAWST) modeling system and the the Regional Ocean Modeling System (ROMS). Simulated waves are generated on the lake with Simulating WAves Nearshore (SWAN). Wind setdown provides the opportunity to eliminate wave setup as a contributing factor, since waves are minimal at the upwind shore. The study finds that model results significantly underestimate wind setdown and storm surge when a typical open-ocean formulation without waves is used for the drag coefficient. The contribution of waves to wind setdown and storm surge is 34.7%. Scattered lake ice also increases the effective drag coefficient by a factor of 1.1. PMID:23977309

  6. Seasonality of diffusive exchange of polychlorinated biphenyls and hexachlorobenzene across the air-sea interface of Kaohsiung Harbor, Taiwan.

    PubMed

    Fang, Meng-Der; Ko, Fung-Chi; Baker, Joel E; Lee, Chon-Lin

    2008-12-15

    Gaseous and dissolved concentrations of polychlorinated biphenyls (PCBs) and hexachlorobenzene (HCB) were measured in the ambient air and water of Kaohsiung Harbor lagoon, Taiwan, from December 2003 to January 2005. During the rainy season (April to September), gaseous PCB and HCB concentrations were low due to both scavenging by precipitation and dilution by prevailing southwesterly winds blown from the atmosphere of the South China Sea. In contrast, trace precipitation and prevailing northeasterly winds during the dry season (October to March) resulted in higher gaseous PCB and HCB concentrations. Instantaneous air-water exchange fluxes of PCB homologues and HCB were calculated from 22 pairs of air and water samples from Kaohsiung Harbor lagoon. All net fluxes of PCB homologues and HCB in this study are from water to air (net volatilization). The highest net volatile flux observed was +172 ng m(-)(2) day(-1) (dichlorobiphenyls) in December, 2003 due to the high wind speed and high dissolved concentration. The PCB homologues and HCB fluxes were significantly governed by dissolved concentrations in Kaohsiung Harbor lagoon. For low molecular weight PCBs (LMW PCBs), their fluxes were also significantly correlated with wind speed. The net PCB and HCB fluxes suggest that the annual sums of 69 PCBs and HCB measured in this study were mainly volatile (57.4 x 10(3) and 28.3 x 10(3) ng m(-2) yr(-1), respectively) and estimated yearly, 1.5 kg and 0.76 kg of PCBs and HCB were emitted from the harbor lagoon surface waters to the ambient atmosphere. The average tPCB flux in this study was about one-tenth of tPCB fluxes seen in New York Harbor and in the Delaware River, which are reported to be greatly impacted by PCBs. PMID:18977513

  7. Tropical air-sea coupling accelerates the recovery of the Atlantic Meridional Overturning Circulation after glacial meltwater event

    NASA Astrophysics Data System (ADS)

    Krebs-Kanzow, U.; Timmermann, A.

    2009-04-01

    During "Heinrich events" brief and exceptionally large discharges of icebergs from the Laurentide and European ice sheets coincide with cold periods followed abrupt warmings. Climate reconstructions suggest that the freshwater pulses caused a temporary collapse of the Atlantic Meridional Overturning Circulation (AMOC) by stabilizing the stratification in the regions of North Atlantic Deep Water (NADW) formation. Using a coupled ocean sea-ice atmosphere model of intermediate complexity we trigger a complete shut-down of the AMOC by injection of a freshwater pulse to the northern North Atlantic. (Analyzing)The analysis of fully and partially coupled freshwater perturbation experiments under glacial conditions reveals that the reduction of northward heat transport in the North Atlantic leads to a cooling north of the thermal equator. Due to advection of cold air and an intensification of the tradewinds the Intertropical Convergence Zone (ITCZ) is shifted southward. Changes of the accumulated precipitation lead to generation of a positive salinity anomaly in the northern tropical Atlantic and a negative anomaly in the southern tropical Atlantic. During the shut-down phase of the AMOC, the cross-equatorial oceanic surface flow is halted, preventing a dilution of the positive salinity anomaly in the North Atlantic. Advected northward by the wind driven ocean circulation the positive salinity anomaly increases the upper ocean density in the deep water formation regions, thereby accelerating the recovery of the AMOC considerably. Partially coupled experiments which neglect tropical air-sea coupling reveal that the recovery time of the AMOC is almost twice as long as in the fully coupled case.

  8. Transition from downward to upward air-sea momentum transfer in swell-dominated light wind condition

    NASA Astrophysics Data System (ADS)

    Smedman, Ann-Sofi; Högström, Ulf; Rutgersson, Anna

    2016-04-01

    Atmospheric and surface wave data from two oceanic experiments carried out on FLIP and ASIS platforms are analysed in order to identify swell-related effects on the momentum exchange during low wind speed conditions. The RED experiment was carried out on board an R/P Floating Instrument Platform, FLIP, anchored north east of the Hawaiian island Oahu with sonic anemometers at four levels: 5.1 m, 6.9 m, 9.9 m and 13.8 m respectively. The meteorological conditions were characterized by north- easterly trade wind and with swell present during most of the time. During swell the momentum flux was directed downwards meaning a positive contribution to the stress. The FETCH experiment was carried out in the Gulf of Lion in the north-western Mediterranean Sea. On the ASIS (air-sea interaction spar) buoy a sonic anemometer was mounted at 7 m above the mean surface level. During strong swell conditions the momentum flux was directed upwards meaning a negative contribution to the stress in this case. The downward momentum flux is shown to be a function of the orbital circulation while the upward momentum flux is a function of wave height. The dividing wind speed is found to be 3.5 m/s Conclusion: Wind speed > 3.5 m/s creates waves (ripples) and thus roughness. Combination of orbital motion and asymmetric structure of ripples lead to flow perturbation and downward transport of negative momentum. With low wind speed (no ripples but viscosity) circulations will form above the crest and the trough with opposite direction which will cause a pressure drop in the vertical direction and an upward momentum transport from the water to the air.

  9. Climatology and Real-Data Simulations of Snow Bands over the English Channel and Irish Sea during Cold-Air Outbreaks

    NASA Astrophysics Data System (ADS)

    Norris, J.; Vaughan, G.; Schultz, D. M.

    2012-04-01

    During the winters of 2009—2010 and 2010—2011, anti-cyclonic blocking over the north Atlantic led to cold, dry air being advected over the UK from the north and east, generating widespread snow depths not seen since the early 1980s. The societal and economical impacts of this snow were severe and diverse, including those on transport, industry, commerce, emergency services, and retail. The most distinctive precipitation features during these winters formed over the English Channel and Irish Sea, where convection frequently organised into bands, as diagnosed from Met Office NIMROD precipitation radar images, forming along the major axis of each body of water (hereafter, sea) when the boundary-layer flow was roughly parallel to each of those axes (hereafter, along-sea). In this study, we address the atmospheric conditions, diagnosed from soundings from suitable locations, at times when bands were observed and at times that they were not, during the cold-air outbreaks in these winters. We find that, for both seas, a band was present the majority of times that the 850-hPa flow was along-sea. We subsequently find that, of these times of along-sea flow, for both seas, 850-hPa wind speed and surface-to-850-hPa temperature difference were significantly greater when bands were present than when they were not. Real-data simulations using the Weather Research and Forecasting (WRF) model are then presented for a typical band over each sea and the model is found to be accurate in reproducing the structures observed on radar. Output from control runs for each band is compared to that in which topography, surface heat fluxes, and land-sea borders are each removed in turn in order to investigate how the low-level flow evolves to generate the observed bands.

  10. Sea-air partitioning of mercury in the equatorial Pacific Ocean

    SciTech Connect

    Kim, J.P.; Fitzgerald, W.F.

    1986-03-07

    The partitioning of gaseous mercury between the atmosphere and surface waters was determined in the equatorial Pacific Ocean. The highest concentrations of dissolved gaseous mercury occurred in cooler, nutrient-rich waters that characterize equatorial upwelling and increased biological productivity at the sea surface. The surface waters were supersaturated with respect to elemental mercury; a significant flux of elemental mercury to the atmosphere is predicted for the equatorial Pacific. When normalized to primary production on a global basis, the ocean effluxes of mercury may rival anthropogenic emissions of mercury to the atmosphere. 23 references, 2 figures.

  11. Influence of air-sea fluxes on chlorine isotopic composition of ocean water: implications for constancy in delta37Cl--a statistical inference.

    PubMed

    Shirodkar, P V; Xiao, Y K; Sarkar, A; Dalal, S G; Chivas, A R

    2006-02-01

    The behaviors of chlorine isotopes in relation to air-sea flux variables have been investigated through multivariate statistical analyses (MSA). The MSA technique provides an approach to reduce the data set and was applied to a set of 7 air-sea flux variables to supplement and describe the variation in chlorine isotopic compositions (delta37Cl) of ocean water. The variation in delta37Cl values of surface ocean water from 51 stations in 4 major world oceans--the Pacific, Atlantic, Indian and the Southern Ocean has been observed from -0.76 to +0.74 per thousand (av. 0.039+/-0.04 per thousand). The observed delta37Cl values show basic homogeneity and indicate that the air-sea fluxes act differently in different oceanic regions and help to maintain the balance between delta37Cl values of the world oceans. The study showed that it is possible to model the behavior of chlorine isotopes to the extent of 38-73% for different geographical regions. The models offered here are purely statistical in nature; however, the relationships uncovered by these models extend our understanding of the constancy in delta37Cl of ocean water in relation to air-sea flux variables. PMID:16214214

  12. Air-sea Exchange of Dimethylsulfide (DMS) - Separation of the Transfer Velocity to Buoyancy, Turbulence, and Wave Driven Components

    NASA Astrophysics Data System (ADS)

    Yang, M.; Blomquist, B.; Huebert, B. J.; Fairall, C. W.

    2009-12-01

    In the past several years, we have measured the sea-to-air flux of DMS directly with eddy covariance on five cruises in distinct oceanic environments, including the equatorial Pacific (TAO 2003), Sargasso Sea (Biocomplexity 2004), Northern Atlantic (DOGEE 2007), Southern Ocean (SO-GasEX 2008), and Peruvian/Chilean upwelling region (VOCALS-REx 2008). Normalizing DMS flux by its concurrent air-sea concentration difference gave us the transfer velocity of DMS (kDMS). Our wealth of kDMS measurements (~2000 hourly values) in very different oceans and across a wide range of wind speeds (0.5~20.5 m/s) provides an opportunity to evaluate existing parameterizations of k and quantify the importance of various controlling factors on gas exchange. Gas exchange in different wind speed regimes is driven by distinct physical mechanisms. In low winds (<4 m/s), buoyancy-driven convection results in a finite and positive kDMS. In moderate winds (4~10 m/s), turbulence from wind-stress prevails, as we found a near linear dependence of kDMS on wind speed and on friction velocity (u*). In high winds (>10 m/s), there is additional bubble-mediated exchange from wave-breaking, which depends on gas solubility (a function of temperature and to a lesser degree, salinity). When normalizing kDMS to a reference temperature of 20°C, we found the oft-used Schmidt number correction (for diffusivity) to be inadequate because it does not account for the temperature dependence in solubility. To quantify the solubility effect, we subtract the small buoyancy-driven term computed by the NOAA-COARE model 3.0a from k660 (kDMS corrected to a Schmidt number of 660). A linear fit to the residual k660 in the moderate wind regime allows us to further separate the turbulence-driven and wave-breaking components. A solubility correction is applied to the latter, which is then added back to the buoyancy and turbulence-driven terms to give k660,C. Compared to k660, k660,C shows a significant reduction in scatter

  13. Legacy of the Seasat mission for studies of the atmosphere and air-sea-ice interactions

    SciTech Connect

    Katsaros, K.B.; Brown, R.A. )

    1991-07-01

    Studies of midlatitude and tropical cyclones and regional weather and climate analyses are examined. Consideration is also given to studies of long swell, sea ice, and continental ice sheets with Seasat data. Many of these results of the Seasat mission were serendipitous. In preparation for the major NASA initiative for the next decade, the Earth Observing Satellite program, it was thought timely to bring some of the Seasat experiences to the fore, since valuable lessons can be learned from the successes and the failures (or omissions) of the Seasat program. Data have been obtained about: (1) the synergistic value of integrated overlapping sampling by several instruments, (2) the invaluable contribution of carefully planned surface measurements, and (3) the importance of retaining flexibility in the system (enough data retention) to allow unexpected and innovative analysis techniques. 72 refs.

  14. In-air spectral signatures of the Baltic Sea macrophytes and their statistical separability

    NASA Astrophysics Data System (ADS)

    Kotta, Jonne; Remm, Kalle; Vahtmäe, Ele; Kutser, Tiit; Orav-Kotta, Helen

    2014-01-01

    Many macroalgal species potentially have distinctive spectral signatures detectable using remote sensing. In order to map the spatial distribution of these species, their spectral properties have to be quantified and statistical differences between species need to be assessed. In the present study, we collected a spectral library of the key benthic macrophyte species in the Baltic Sea area and presented the methodology that allows quantifying statistical differences between their reflectance spectra. The results indicate that three broad groups of algae-green, brown, and red algae-can be separated based on their optical signatures. In general, the between-species differences are too small to allow easy recognition of benthic algae based on their untransformed reflectance spectra. However, the distinctness of the studied species and taxa improves if standardized reflectance values are used. The best indicative spectral range was at 530 to 570 nm for the separation of species and of larger taxonomic units.

  15. A stratospheric intrusion at the subtropical jet over the Mediterranean Sea: air-borne remote sensing observations and model results

    NASA Astrophysics Data System (ADS)

    Weigel, K.; Hoffmann, L.; Günther, G.; Khosrawi, F.; Olschewski, F.; Preusse, P.; Spang, R.; Stroh, F.; Riese, M.

    2012-09-01

    Remote sensing measurements from the Cryogenic Infrared Spectrometers and Telescope for the Atmosphere - New Frontiers (CRISTA-NF) during a flight on 29 July 2006 are presented. This flight is part of the AMMA-SCOUT-O3 measurement campaign, where CRISTA-NF was deployed on the high-flying research aircraft M55-Geophysica. The flight path was located over Italy and the Mediterranean Sea and crossed over the subtropical jet twice. Measurements of temperature, and the volume mixing ratios of water vapor (H2O), ozone (O3), nitric acid (HNO3) and peroxyacetyl nitrate (PAN) are available with a vertical resolution of up to 500 m between about 6 to 21 km altitude. CRISTA-NF observes these trace gases simultaneously and provides a quasi-2-D view of the transition region between the troposphere and the stratosphere. The observation of these different trace gases allows to determine tropospheric and stratospheric air masses. As expected, higher abundances are found where the main source of the trace gases is located: in the stratosphere for O3 and in the troposphere for H2O and PAN. Tracer-tracer correlations between O3 and PAN are used to identify the mixed tropospheric and lowermost stratospheric air at the subtropical jet and around the thermal tropopause north of the jet. An intrusion of stratospheric air into the troposphere associated with the subtropical jet is found in the CRISTA-NF observations. The observations indicate that the intrusion is connected to a tropopause fold which is not resolved in the ECMWF analysis data. The intrusion was reproduced in a simulation with the Chemical Lagrangian Model of the Stratosphere (CLaMS). The CLaMS simulation shows, that the lowermost stratospheric air masses in the intrusion where transported along the the subtropical jet. The tropospheric air masses around the intrusion originate from the vicinity of the Asian monsoon anticyclone. This work discusses the nature of the observed processes at the subtropical jet based on the

  16. Air-sea fluxes and satellite-based estimation of water masses formation

    NASA Astrophysics Data System (ADS)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  17. Air-sea dimethylsulfide (DMS) gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed

    NASA Astrophysics Data System (ADS)

    Bell, T. G.; De Bruyn, W.; Miller, S. D.; Ward, B.; Christensen, K.; Saltzman, E. S.

    2013-11-01

    Shipboard measurements of eddy covariance dimethylsulfide (DMS) air-sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k660) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s-1. At higher wind speeds the relationship between k660 and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent suppression of air-sea gas flux at higher wind speeds appears to be related to sea state, as determined from shipboard wave measurements. These observations are consistent with the idea that long waves suppress near-surface water-side turbulence, and decrease interfacial gas transfer. This effect may be more easily observed for DMS than for less soluble gases, such as CO2, because the air-sea exchange of DMS is controlled by interfacial rather than bubble-mediated gas transfer under high wind speed conditions.

  18. Physical and chemical processes of air masses in the Aegean Sea during Etesians: Aegean-GAME airborne campaign.

    PubMed

    Tombrou, M; Bossioli, E; Kalogiros, J; Allan, J D; Bacak, A; Biskos, G; Coe, H; Dandou, A; Kouvarakis, G; Mihalopoulos, N; Percival, C J; Protonotariou, A P; Szabó-Takács, B

    2015-02-15

    High-resolution measurements of gas and aerosols' chemical composition along with meteorological and turbulence parameters were performed over the Aegean Sea (AS) during an Etesian outbreak in the framework of the Aegean-GAME airborne campaign. This study focuses on two distinct Etesian patterns, with similarities inside the Marine Atmospheric Boundary Layer (MABL) and differences at higher levels. Under long-range transport and subsidence the pollution load is enhanced (by 17% for CO, 11% for O3, 28% for sulfate, 62% for organic mass, 47% for elemental carbon), compared to the pattern with a weaker synoptic system. Sea surface temperature (SST) was a critical parameter for the MABL structure, turbulent fluxes and pollutants' distribution at lower levels. The MABL height was below 500 m asl over the eastern AS (favoring higher accumulation), and deeper over the western AS. The most abundant components of total PM1 were sulfate (40-50%) and organics (30-45%). Higher average concentrations measured over the eastern AS (131 ± 76 ppbv for CO, 62.5 ± 4.1 ppbv for O3, 5.0 ± 1.1 μg m(-3) for sulfate, 4.7 ± 0.9 μg m(-3) for organic mass and 0.5 ± 0.2 μg m(-3) for elemental carbon). Under the weaker synoptic system, cleaner but more acidic air masses prevailed over the eastern part, while distinct aerosol layers of different signature were observed over the western part. The Aitken and accumulation modes contributed equally during the long-range transport, while the Aitken modes dominated during local or medium range transport. PMID:25460953

  19. Space-based retrievals of air-sea gas transfer velocities using altimeters: Calibration for dimethyl sulfide

    NASA Astrophysics Data System (ADS)

    Goddijn-Murphy, Lonneke; Woolf, David K.; Marandino, Christa

    2012-08-01

    This study is the first to directly correlate gas transfer velocity, measured at sea using the eddy-correlation (EC) technique, and satellite altimeter backscattering. During eight research cruises in different parts of the world, gas transfer velocity of dimethyl sulfide (DMS) was measured. The sample times and locations were compared with overpass times and locations of remote sensing satellites carrying Ku-band altimeters: ERS-1, ERS-2, TOPEX, POSEIDON, GEOSAT Follow-On, JASON-1, JASON-2 and ENVISAT. The result was 179 pairs of gas transfer velocity measurements and backscattering coefficients. An inter-calibration of the different altimeters significantly reduced data scatter. The inter-calibrated data was best fitted to a quadratic relation between the inverse of the backscattering coefficients and the gas transfer velocity measurements. A gas transfer parameterization based on backscattering, corresponding with sea surface roughness, might be expected to perform better than wind speed-based parameterizations. Our results, however, did not show improvement compared to direct correlation of shipboard wind speeds. The relationship of gas transfer velocity to satellite-derived backscatter, or wind speed, is useful to provide retrieval algorithms. Gas transfer velocity (cm/hr), corrected to a Schmidt number of 660, is proportional to wind speed (m/s). The measured gas transfer velocity is controlled by both the individual water-side and air-side gas transfer velocities. We calculated the latter using a numerical scheme, to derive water-side gas transfer velocity. DMS is sufficiently soluble to neglect bubble-mediated gas transfer, thus, the DMS transfer velocities could be applied to estimate water-side gas transfer velocities through the unbroken surface of any other gas.

  20. On the use of a coupled ocean-atmosphere-wave model during an extreme cold air outbreak over the Adriatic Sea

    NASA Astrophysics Data System (ADS)

    Ricchi, Antonio; Miglietta, Mario Marcello; Falco, Pier Paolo; Benetazzo, Alvise; Bonaldo, Davide; Bergamasco, Andrea; Sclavo, Mauro; Carniel, Sandro

    2016-05-01

    An intense cold air outbreak affected the northern Adriatic Sea during winter 2012, determining an exceptional persistence of northeasterly Bora wind over the basin, which lasted for about 3 weeks. The cold air coming from the Balkans produced icing in the Venice lagoon and very intense snowfall in the Apennines Mountains and even near the coasts. In order to understand the importance and role of air-sea interactions for the evolution of the atmospheric fields, simulations with the Weather Research and Forecasting (WRF) model encompassing the whole period have been performed using sea surface temperature (SST) fields with an increasing level of complexity. Starting from a large-scale static sea temperature, the SST in the initial and boundary conditions has been progressively made more realistic. First, a more refined field, retrieved from a satellite radiometer was used; then, the same field was updated every 6 h. Next, the effect of including a simplified 1D ocean model reproducing the Oceanic Mixed Layer (OML) evolution has been tested. Finally, the potential improvements coming from a coupled description of atmosphere-ocean and atmosphere-ocean-waves interactions have been explored within the Coupled Ocean-Atmosphere-Wave Sediment Transport (COAWST) modeling system. Results highlight that the energy exchange between air and sea does not significantly impact the atmospheric fields, in particular 10 m wind and 2 m temperature, also because of the geography of the basin and the predominance of synoptic-scale flow in intense events of Bora, in the northern Adriatic. However, when sensible and latent heat fluxes, which are dependent on atmospheric and oceanic variables, are analyzed, the more realistic representation of SST drastically improves the model performances.

  1. Air-sea interactions and oceanic processes in the development of different Atlantic Niño patterns

    NASA Astrophysics Data System (ADS)

    Martin-Rey, Marta; Polo, Irene; Rodríguez-Fonseca, Belén; Lazar, Alban

    2016-04-01

    Atlantic Niño is the leading mode of inter-annual variability of the tropical Atlantic basin at inter-annual time scales. A recent study has put forward that two different Atlantic Niño patterns co-exist in the tropical Atlantic basin during negative phases of the Atlantic Multidecadal Oscillation. The leading mode, Basin-Wide (BW) Atlantic Niño is characterized by an anomalous warming extended along the whole tropical basin. The second mode, the Dipolar (D) Atlantic Niño presents positive Sea Surface Temperature (SST) anomalies in the central-eastern equatorial band, surrounded by negative ones in the North and South tropical Atlantic. The BW Atlantic Niño is associated with a weakening of both Azores and Sta Helena High, which reduces the tropical trades during previous autumn-winter. On the other hand, the D-Atlantic Niño is related to a strengthening of the Azores and a weakening of Helena High given rise to a meridional Sea Level Pressure (SLP) gradient that originates an intensification of the subtropical trades and anomalous westerlies along the equatorial band. This different wind forcing suggests that different oceanic processes could act in the development of the BW and D Atlantic Niño patterns. For this reason, an inter-annual simulation with the ocean NEMO model has been performed and the heat budget analysis has been analysed for each Atlantic Niño mode. The results suggest that the two Atlantic Nino configurations have different timing. The heat budget analysis reveals that BW Atlantic Nino SST pattern is due to anomalous air-sea heat fluxes in the south tropical and western equatorial Atlantic during the autumn-winter, while vertical processes are responsible of the warming in the central and eastern part of the basin during late-winter and spring. For the D-Atlantic Nino, the subtropical cooling is attributed to turbulent heat fluxes, the equatorial SST signal is mainly forced by vertical entrainment. The role of the oceanic waves in the

  2. Air-sea fluxes in a climate model using hourly coupling between the atmospheric and the oceanic components

    NASA Astrophysics Data System (ADS)

    Tian, Fangxing; von Storch, Jin-Song; Hertwig, Eileen

    2016-06-01

    We analyse the changes in the air-sea fluxes of momentum, heat and fresh water flux caused by increasing the ocean-atmosphere coupling frequency from once per day to once per hour in the Max Planck Institute Earth System Model. We diagnose the relative influences of daily averaging and high-frequency feedbacks on the basic statistics of the air-sea fluxes at grid point level and quantify feedback modes responsible for large scale changes in fluxes over the Southern Ocean and the Equatorial Pacific. Coupling once per hour instead of once per day reduces the mean of the momentum-flux magnitude by up to 7 % in the tropics and increases it by up to 10 % in the Southern Ocean. These changes result solely from feedbacks between atmosphere and ocean occurring on time scales shorter than 1 day . The variance and extremes of all the fluxes are increased in most parts of the oceans. Exceptions are found for the momentum and fresh water fluxes in the tropics. The increases result mainly from the daily averaging, while the decreases in the tropics are caused by the high-frequency feedbacks. The variance increases are substantial, reaching up to 50 % for the momentum flux, 100 % for the fresh water flux, and a factor of 15 for the net heat flux. These diurnal and intra-diurnal variations account for up to 50-90 % of the total variances and exhibit distinct seasonality. The high-frequency coupling can influence the large-scale feedback modes that lead to large-scale changes in the magnitude of wind stress over the Southern Ocean and Equatorial Pacific. In the Southern Ocean, the dependence of the SST-wind-stress feedback on the mean state of SST, which is colder in the experiment with hourly coupling than in the experiment with daily coupling, leads to an increase of westerlies. In the Equatorial Pacific, Bjerknes feedback in the hourly coupled experiment reveals a diurnal cycle during the El Niño events, with the feedback being stronger in the nighttime than in the daytime and

  3. Bora event variability and the role of air-sea feedback

    USGS Publications Warehouse

    Pullen, J.; Doyle, J.D.; Haack, T.; Dorman, C.; Signell, R.P.; Lee, C.M.

    2007-01-01

    A two-way interacting high resolution numerical simulation of the Adriatic Sea using the Navy Coastal Ocean Model (NCOM) and Coupled Ocean/ Atmosphere Mesoscale Prediction System (COAMPS??) was conducted to improve forecast momentum and heat flux fields, and to evaluate surface flux field differences for two consecutive bora events during February 2003. (COAMPS?? is a registered trademark of the Naval Research Laboratory.) The strength, mean positions and extensions of the bora jets, and the atmospheric conditions driving them varied considerably between the two events. Bora 1 had 62% stronger heat flux and 51% larger momentum flux than bora 2. The latter displayed much greater diurnal variability characterized by inertial oscillations and the early morning strengthening of a west Adriatic barrier jet, beneath which a stronger west Adriatic ocean current developed. Elsewhere, surface ocean current differences between the two events were directly related to differences in wind stress curl generated by the position and strength of the individual bora jets. The mean heat flux bias was reduced by 72%, and heat flux RMSE reduced by 30% on average at four instrumented over-water sites in the two-way coupled simulation relative to the uncoupled control. Largest reductions in wind stress were found in the bora jets, while the biggest reductions in heat flux were found along the north and west coasts of the Adriatic. In bora 2, SST gradients impacted the wind stress curl along the north and west coasts, and in bora 1 wind stress curl was sensitive to the Istrian front position and strength. The two-way coupled simulation produced diminished surface current speeds of ???12% over the northern Adriatic during both bora compared with a one-way coupled simulation. Copyright 2007 by the American Geophysical Union.

  4. Particulate PAHs and n-alkanes in the air over Southern and Eastern Mediterranean Sea.

    PubMed

    Romagnoli, Paola; Balducci, Catia; Perilli, Mattia; Perreca, Erica; Cecinato, Angelo

    2016-09-01

    Particulate polycyclic aromatic hydrocarbons, n-alkanes and polar organic compounds were investigated in the marine atmosphere of Southern and Eastern Mediterranean Sea, in the frame of the scientific cruise of Urania ship between 27 July and 11 August 2013. The PM10 fraction of aerosol to which most organic substances are associated, were collected daily; contemporarily, gaseous regulated toxicants (ozone, nitrogen oxides and carbon oxide) and carbonyls were recorded. Samplings were carried out in front of Palermo and Messina, respectively the start and end harbors, and along the cruise, both in movement (transects, N = 14) and at stops (N = 11). Total PAHs ranged from 0.06 ng/m(3) up to 1.8 ng/m(3), with the maximums observed close to harbors. Unlike total concentrations that were in general comparable, the percent composition of PAHs was distinct for harbors, transects and stops, which allowed to draw insights about the pollution sources impact. Concentrations of n-alkanes (C18-C35) ranging from 6.7 to 43 ng/m(3) were quantified. The carbonyls evaluation revealed relatively high concentrations of formaldehyde (∼4-24 μg/m(3)) and acetone (∼5-35 μg/m(3)) near harbors, and of acrolein (up to 12 μg/m(3)) offshore, while benzaldehyde was quite independent of the site type (≈0.5 μg/m(3)). Nicotine and caffeine were detected, at different extents (0.0-2.2 ng/m(3) and 0.01-0.17 ng/m(3), respectively), in ca. 70% and 100% of samples. Alkyl phthalates ranged from 2.7 to 67 ng/m(3) and showed variable percentages in the samples. Finally, traces of N,N-diethyl-meta-toluene amide (up to 0.4 ng/m(3)) were found at all sites. PMID:27341155

  5. The ESA SMOS+SOS Project: Oceanography using SMOS for innovative air-sea exchange studies

    NASA Astrophysics Data System (ADS)

    Banks, Chris; Gommenginger, Christine; Boutin, Jacqueline; Reul, Nicolas; Martin, Matthew; Ash, Ellis; Reverdin, Gilles; Donlon, Craig

    2013-04-01

    We report on the work plan of the SMOS+Surface Ocean Salinity and Synergy (SMOS+SOS) project. SMOS+SOS is funded through the Support to Science Element (STSE) component of the European Space Agency's (ESA) Earth Observation Envelope Programme. The SMOS+SOS consortium consists of four organisations namely the National Oceanography Centre (UK), the LOCEAN/IFREMER/CATDS research team (France), the Met Office (UK) and Satellite Oceanographic Consultants Ltd (UK). The end of the SMOS+SOS project will be marked by a final open workshop most likely hosted by the UK Met Office in September/October 2014. The project is concerned with demonstrating the performance and scientific value of SMOS Sea Surface Salinity (SSS) products through a number of well-defined case studies. The case studies include: Amazon/Orinoco plumes (freshwater outflow); Agulhas and Gulf Stream (strong water mass boundary); Tropical Pacific/Atlantic (strong precipitation regime); sub-tropical North Atlantic (ie SPURS; strong evaporative regime); and Equatorial Pacific (equatorial upwelling). With SMOS measuring the SSS in the top cm of the ocean, validating SMOS against in situ salinity data taken typically at a few meters depth introduces assumptions about the vertical structure of salinity in the upper ocean. To address these issues, the project will examine and quantify discrepancies between SMOS and in situ surface salinity data at various depths in different regions characterised by strong precipitation or evaporation regimes. Equally, data editing and spatio-temporal averaging play a central role in determining the quality, errors and correlations in SMOS SSS data. The project will explore various processing and spatio-temporal averaging choices to define the SMOS SSS products that best address the needs of the oceanographic and data assimilation user community. One key aspect of this project is to determine how one can achieve useful accuracy/uncertainty in SSS without jeopardising SMOS's ability

  6. Constraints on sea to air emissions from methane clathrates in the vicinity of Svalbard

    NASA Astrophysics Data System (ADS)

    Pisso, Ignacio; Vadakkepuliyambatta, Sunil; Platt, Stephen Matthew; Eckhardt, Sabine; Allen, Grant; Pitt, Joseph; Silyakova, Anna; Hermansen, Ove; Schmidbauer, Norbert; Mienert, Jurgen; Myhre, Cathrine Lund; Stohl, Andreas

    2016-04-01

    Methane stored in the seabed in the form of clathrates has the potential to be released into the atmosphere due to ongoing ocean warming. The Methane Emissions from Arctic Ocean to Atmosphere (MOCA, http://moca.nilu.no/) proje sct conducted measurement campaigns in the vicinity of Svalbard during the summers of 2014 and 2015 in collaboration with the Centre for Arctic Gas Hydrate, Environment and Climate (CAGE, https://cage.uit.no/) and the MAMM (https://arcticmethane.wordpress.com) project . The extensive set of measurements includes air (BAe 146) and ship (RV Helmer Hansen) borne methane concentrations, complemented with the nearby monitoring site at Zeppelin mountain. In order to assess the atmospheric impact of emissions from seabed methane hydrates, we characterised the local and long range atmospheric transport during the aircraft campaign and different scenarios for the emission sources. We present a range of upper bounds for the CH4 emissions during the campaign period as well as the methodologies used to obtain them. The methodologies include a box model, Lagrangian transport and elementary inverse modelling. We emphasise the analysis of the aircraft data. We discuss in detail the different methodologies used for determining the upper flux bounds as well as its uncertainties and limitations. The additional information provided by the ship and station observations will be briefly mentioned.

  7. Impact of phytoplankton-generated surfactants on air-sea gas exchange

    NASA Astrophysics Data System (ADS)

    Frew, Nelson M.; Goldman, Joel C.; Dennett, Mark R.; Johnson, A. Sherwood

    1990-03-01

    The effect of surface-active organic matter generated by seven common species of marine phytoplankton on gas exchange rates under turbulent conditions at the air-water interface was determined. Reductions in oxygen evasion rates ranging from 5 to 50% were observed relative to clean seawater controls. Relative oxygen exchange coefficients (expressed as R = Kw [sample]/Kw [control]) were shown to be sensitive to small changes in total dissolved carbohydrate at concentrations <1 mg C (carbon) L-1 and to asymptotically decrease to a lower limit (R = 55-70%) at concentrations between 2 and 6 mg C L-1. A corresponding relationship was observed in which R decreased with increasing relative surfactant amounts derived from surface pressure-area measurements. However, gas exchange reductions were significant for plankton exudate samples displaying surface pressures ≲1 mN m-1. It thus seems that condensed monolayer films are not a prerequisite for reduced gas exchange and that relatively soluble surfactants derived from phytoplankton can strongly affect the dissipation of near-surface turbulence and lead to changes in the Schmidt number dependency of Kw. Based on detailed analyses of carbohydrate-containing surface-active exudates isolated by solid phase extraction from one of the species, Phaeodactylum tricornutum, it appears that small glucans and heteropolysaccharides associated with proteins and possibly lipids were responsible for the observed reductions in R.

  8. Air-sea interactions over Terra Nova Bay during winter: Simulation with a coupled atmosphere-polynya model

    NASA Astrophysics Data System (ADS)

    Gallée, Hubert

    A preliminary simulation of the Terra Nova Bay polynya has been performed with a coupled atmosphere-polynya model. The atmospheric model is a hydrostatic primitive equations model that has been validated previously by a simulation of the strong katabatic winds observed in that area. The polynya model includes a representation of the free drift of frazil ice and simple sea-ice dynamics and thermodynamics. Two and three-dimensional experiments have been performed under polar night conditions. Two-dimensional experiments show that an open (warm) water area influences significantly the atmospheric circulation in the antarctic coastal zone: an additional ice-breeze effect is simulated and is responsible for the strengthening of the katabatic winds near the coast. Because of the important temperature difference between the continental air and the ice-free ocean (up to 40°C), strong surface heat fluxes are simulated over the polynya. Finally, a three-dimensional experiment has been performed. The integration domain includes Terra Nova Bay. The polynya observed in that region is well simulated. It is found that heat losses from the polynya surface are stronger than previously thought but are probably constrained by the idealized representation of frazil ice, which is assumed to be uniform in each grid box. This stresses the need for having a better knowledge of frazil ice evolution in large polynyas.

  9. Profiles of exercise history and overuse injuries among United States Navy Sea, Air, and Land (SEAL) recruits.

    PubMed

    Shwayhat, A F; Linenger, J M; Hofherr, L K; Slymen, D J; Johnson, C W

    1994-01-01

    This prospective study examined running history as a risk factor for subsequent overuse injury in Navy Sea, Air, and Land (SEAL) recruits. Recruits preparing to be Navy SEALs undergo 6 months of rigorous physical training programs, which place these recruits at high risk for developing an overuse injury. We assessed the independent variables of age; prior running frequency, duration, and pace; and training surface. Univariate and multivariate estimates of risk were determined for each variable. We observed an incidence of 3.4 overuse injuries per 1000 recruit-days. Assessing the physical activity of the recruits in the 6 months before entrance into basic training, we found that the recruits who ran at a pace slower than 8 minutes per mile and on softer training surfaces were more likely to sustain an overuse injury during basic training, in both univariate and multivariate estimates of risk. Recruits who ran fewer weekly miles and for shorter durations before basic training were also more likely to sustain an overuse injury according to univariate estimates of risk. Our findings suggest that risk of overuse injuries can be reduced by adjusting exercise routines before training. Running on different type surfaces with a gradual increase in speed, duration, and weekly mileage in the period preceding basic training may reduce risk of overuse injury. PMID:7856809

  10. Connections Between the Spring Breakup of the Southern Hemisphere Polar Vortex, Stationary Waves, and Air-sea Roughness

    NASA Technical Reports Server (NTRS)

    Garfinkel, Chaim I.; Oman, Luke David; Barnes, Elizabeth A.; Waugh, Darryn W.; Hurwitz, Margaret H.; Molod, Andrea M.

    2013-01-01

    A robust connection between the drag on surface-layer winds and the stratospheric circulation is demonstrated in NASA's Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM). Specifically, an updated parameterization of roughness at the air-sea interface, in which surface roughness is increased for moderate wind speeds (4ms to 20ms), leads to a decrease in model biases in Southern Hemispheric ozone, polar cap temperature, stationary wave heat flux, and springtime vortex breakup. A dynamical mechanism is proposed whereby increased surface roughness leads to improved stationary waves. Increased surface roughness leads to anomalous eddy momentum flux convergence primarily in the Indian Ocean sector (where eddies are strongest climatologically) in September and October. The localization of the eddy momentum flux convergence anomaly in the Indian Ocean sector leads to a zonally asymmetric reduction in zonal wind and, by geostrophy, to a wavenumber-1 stationary wave pattern. This tropospheric stationary wave pattern leads to enhanced upwards wave activity entering the stratosphere. The net effect is an improved Southern Hemisphere vortex: the vortex breaks up earlier in spring (i.e., the spring late-breakup bias is partially ameliorated) yet is no weaker in mid-winter. More than half of the stratospheric biases appear to be related to the surface wind speed biases. As many other chemistry climate models use a similar scheme for their surface layer momentum exchange and have similar biases in the stratosphere, we expect that results from GEOSCCM may be relevant for other climate models.

  11. Impacts of air-sea interactions on regional air quality predictions using WRF/Chem v3.6.1 coupled with ROMS v3.7: southeastern US example

    NASA Astrophysics Data System (ADS)

    He, J.; He, R.; Zhang, Y.

    2015-11-01

    Air-sea interactions have significant impacts on coastal convection and surface fluxes exchange, which are important for the spatial and vertical distributions of air pollutants that affect public health, particularly in densely populated coastal areas. To understand the impacts of air-sea interactions on coastal air quality predictions, sensitivity simulations with different cumulus parameterization schemes and atmosphere-ocean coupling are conducted in this work over southeastern US in July 2010 using the Weather Research and Forecasting Model with Chemistry (WRF/Chem). The results show that different cumulus parameterization schemes can result in an 85 m difference in the domain averaged planetary boundary layer height (PBLH), and 4.8 mm difference in the domain averaged daily precipitation. Comparing to WRF/Chem without air-sea interactions, WRF/Chem with a 1-D ocean mixed layer model (WRF/Chem-OML) and WRF/Chem coupled with a 3-D Regional Ocean Modeling System (WRF/Chem-ROMS) predict the domain averaged changes in the sea surface temperature of 0.1 and 1.0 °C, respectively. The simulated differences in the surface concentrations of ozone (O3) and PM2.5 between WRF/Chem-ROMS and WRF/Chem can be as large as 17.3 ppb and 7.9 μg m-3, respectively. The largest changes simulated from WRF/Chem-ROMS in surface concentrations of O3 and particulate matter with diameter less than and equal to 2.5 μm (PM2.5) occur not only along coast and remote ocean, but also over some inland areas. Extensive validations against observations, show that WRF/Chem-ROMS improves the predictions of most cloud and radiative variables, and surface concentrations of some chemical species such as sulfur dioxide, nitric acid, maximum 1 h and 8 h O3, sulfate, ammonium, nitrate, and particulate matter with diameter less than and equal to 10 μm (PM10). This illustrates the benefits and needs of using coupled atmospheric-ocean model with advanced model representations of air-sea interactions for

  12. Concentrations, size-distributions and air-to-sea fluxes of bio-active trace elements on the New Jersey coast

    NASA Astrophysics Data System (ADS)

    Gao, Y.; Xu, G.; Xu, T.; Mukherjee, P.

    2014-12-01

    The coastal marine atmosphere adjacent to large urban and industrial centers can be strongly impacted by pollution emissions, resulting in high loading of pollutants in the ambient air. Among airborne substances are certain bioactive trace elements including Cd, Cu, and Zn from a variety of emission sources. High concentrations of these elements in coastal air could not only result in enhanced air-to-sea deposition fluxes to coastal waters, but they could also be transported over the open ocean, affecting the composition of the remote marine atmosphere. In this presentation, we will discuss the concentrations, particle-size distributions of selected trace elements in aerosols and their properties in precipitation observed on the New Jersey coast. The estimates of the air-to-water deposition fluxes of these elements will also be discussed.

  13. Stress induced by hooking, net towing, elevated sea water temperature and air in sablefish: Lack of concordance between mortality and physiological measures of stress

    USGS Publications Warehouse

    Davis, M.W.; Olla, B.L.; Schreck, C.B.

    2001-01-01

    In a series of laboratory studies designed to simulate bycatch processes, sablefish Anoplopoma fimbria were either hooked for up to 24 h or towed in a net for 4 h and then subjected to an abrupt transfer to elevated sea water temperature and air. Mortality did not result from hooking or net towing followed by exposure to air, but increased for both capture methods as fish were exposed to elevated temperatures, reflecting the magnifying effect of elevated temperature on mortality. Hooking and exposure to air resulted in increased plasma cortisol and lactate concentrations, while the combination of hooking and exposure to elevated temperature and air resulted in increased lactate and potassium concentrations. In fish that were towed in a net and exposed to air, cortisol, lactate, potassium and sodium concentrations increased, but when subjected to elevated temperature and air, no further increases occurred above the concentrations induced by net towing and air, suggesting a possible maximum of the physiological stress response. The results suggest that caution should be exercised when using physiological measures to quantify stress induced by capture and exposure to elevated temperature and air, that ultimately result in mortality, since the connections between physiological stress and mortality in bycatch processes remain to be fully understood.

  14. Reconstruction of super-resolution fields of ocean pCO2 and air-sea fluxes of CO2 from satellite imagery in the Southeastern Atlantic

    NASA Astrophysics Data System (ADS)

    Hernández-Carrasco, I.; Sudre, J.; Garçon, V.; Yahia, H.; Garbe, C.; Paulmier, A.; Dewitte, B.; Illig, S.; Dadou, I.

    2015-01-01

    The knowledge of Green House Gases GHGs fluxes at the air-sea interface at high resolution is crucial to accurately quantify the role of the ocean in the absorption and emission of GHGs. In this paper we present a novel method to reconstruct maps of surface ocean partial pressure of CO2, pCO2, and air-sea CO2 fluxes at super resolution (4 km) using Sea Surface Temperature (SST) and Ocean Colour (OC) data at this resolution, and CarbonTracker CO2 fluxes data at low resolution (110 km). Inference of super-resolution of pCO2, and air-sea CO2 fluxes is performed using novel nonlinear signal processing methodologies that prove efficient in the context of oceanography. The theoretical background comes from the Microcanonical Multifractal Formalism which unlocks the geometrical determination of cascading properties of physical intensive variables. As a consequence, a multiresolution analysis performed on the signal of the so-called singularity exponents allows the correct and near optimal cross-scale inference of GHGs fluxes, as the inference suits the geometric realization of the cascade. We apply such a methodology to the study offshore of the Benguela area. The inferred representation of oceanic partial pressure of CO2 improves and enhances the description provided by CarbonTracker, capturing the small scale variability. We examine different combinations of Ocean Colour and Sea Surface Temperature products in order to increase the number of valid points and the quality of the inferred pCO2 field. The methodology is validated using in-situ measurements by means of statistical errors. We obtain that mean absolute and relative errors in the inferred values of pCO2 with respect to in-situ measurements are smaller than for CarbonTracker.

  15. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    NASA Technical Reports Server (NTRS)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  16. Reconstruction of super-resolution ocean pCO2 and air-sea fluxes of CO2 from satellite imagery in the southeastern Atlantic

    NASA Astrophysics Data System (ADS)

    Hernández-Carrasco, I.; Sudre, J.; Garçon, V.; Yahia, H.; Garbe, C.; Paulmier, A.; Dewitte, B.; Illig, S.; Dadou, I.; González-Dávila, M.; Santana-Casiano, J. M.

    2015-09-01

    An accurate quantification of the role of the ocean as source/sink of greenhouse gases (GHGs) requires to access the high-resolution of the GHG air-sea flux at the interface. In this paper we present a novel method to reconstruct maps of surface ocean partial pressure of CO2 ( pCO2) and air-sea CO2 fluxes at super resolution (4 km, i.e., 1/32° at these latitudes) using sea surface temperature (SST) and ocean color (OC) data at this resolution, and CarbonTracker CO2 fluxes data at low resolution (110 km). Inference of super-resolution pCO2 and air-sea CO2 fluxes is performed using novel nonlinear signal processing methodologies that prove efficient in the context of oceanography. The theoretical background comes from the microcanonical multifractal formalism which unlocks the geometrical determination of cascading properties of physical intensive variables. As a consequence, a multi-resolution analysis performed on the signal of the so-called singularity exponents allows for the correct and near optimal cross-scale inference of GHG fluxes, as the inference suits the geometric realization of the cascade. We apply such a methodology to the study offshore of the Benguela area. The inferred representation of oceanic partial pressure of CO2 improves and enhances the description provided by CarbonTracker, capturing the small-scale variability. We examine different combinations of ocean color and sea surface temperature products in order to increase the number of valid points and the quality of the inferred pCO2 field. The methodology is validated using in situ measurements by means of statistical errors. We find that mean absolute and relative errors in the inferred values of pCO2 with respect to in situ measurements are smaller than for CarbonTracker.

  17. The carbon dioxide system on the Mississippi River-dominated continental shelf in the northern Gulf of Mexico: 1. Distribution and air-sea CO2 flux

    NASA Astrophysics Data System (ADS)

    Huang, Wei-Jen; Cai, Wei-Jun; Wang, Yongchen; Lohrenz, Steven E.; Murrell, Michael C.

    2015-03-01

    River-dominated continental shelf environments are active sites of air-sea CO2 exchange. We conducted 13 cruises in the northern Gulf of Mexico, a region strongly influenced by fresh water and nutrients delivered from the Mississippi and Atchafalaya River system. The sea surface partial pressure of carbon dioxide (pCO2) was measured, and the air-sea CO2 flux was calculated. Results show that CO2 exchange exhibited a distinct seasonality: the study area was a net sink of atmospheric CO2 during spring and early summer, and it was neutral or a weak source of CO2 to the atmosphere during midsummer, fall, and winter. Along the salinity gradient, across the shelf, the sea surface shifted from a source of CO2 in low-salinity zones (0≤S<17) to a strong CO2 sink in the middle-to-high-salinity zones (17≤S<33), and finally was a near-neutral state in the high-salinity areas (33≤S<35) and in the open gulf (S≥35). High pCO2 values were only observed in narrow regions near freshwater sources, and the distribution of undersaturated pCO2 generally reflected the influence of freshwater inputs along the shelf. Systematic analyses of pCO2 variation demonstrated the importance of riverine nitrogen export; that is, riverine nitrogen-enhanced biological removal, along with mixing processes, dominated pCO2 variation along the salinity gradient. In addition, extreme or unusual weather events were observed to alter the alongshore pCO2 distribution and to affect regional air-sea CO2 flux estimates. Overall, the study region acted as a net CO2 sink of 0.96 ± 3.7 mol m-2 yr-1 (1.15 ± 4.4 Tg C yr-1).

  18. A diagram of wind speed versus air-sea temperature difference to understand the dynamics of the marine atmospheric boundary layer off northwest Europe

    NASA Astrophysics Data System (ADS)

    Kettle, Anthony

    2015-04-01

    Wind speed and atmospheric stability have an important role in determining the turbulence in the marine atmospheric boundary layer (MABL) as well as the surface wave field. The understanding of MABL dynamics in northwest Europe is complicated by fetch effects, the proximity of coastlines, shallow topography, and larger scale circulation patterns (e.g., cold air outbreaks). Numerical models have difficulty simulating the marine atmospheric boundary layer in coastal areas and partially enclosed seas, and this is partly due to spatial resolution problems at land-sea coastline discontinuities. In these offshore environments, the boundary layer processes are often best understood directly from time series measurements from measurement platforms or buoys, in spite of potential difficulties from platform flow distortion as well as the spatial sparseness of the data sets. This contribution presents updated results of measurements from offshore platforms in the North Sea and Norwegian Sea in terms of a summary diagnostic - wind speed versus air-sea temperature difference (U-ΔT) - with important implications for understanding atmospheric boundary layer processes. The U-ΔT diagram was introduced in earlier surveys of data from coastal and offshore sites in northwest Europe to summarize boundary layer conditions at a given location. Additional information from a series of measurement purpose-built offshore measurement and oil/gas production platforms from the North Sea illustrates how the wind characteristics vary spatially over large distances. The results are important for the offshore wind industry because of the way that wind turbines accrue fatigue damage in different conditions of atmospheric stability and wind speed.

  19. Interannual variability of the air-sea heat exchange in the western Mediterranean in relation to the deep-water formation processes

    NASA Astrophysics Data System (ADS)

    Soto, J.; Criado Aldeanueva, F.; García Lafuente, J.; Sanchez Román, A.; Carracedo, L.

    2009-04-01

    A 60-year long time series of heat fluxes (long and short wave radiation, sensible and latent contributions) from NCEP reanalysis dataset and a 22-year long time series of Sea Surface Temperature (SST) from JPL AVHRR Oceans Pathfinder dataset have been combined to study the seasonal and interannual variability of air-sea heat exchanges over the Mediterranean Sea and correlate them with the characteristics of the Mediterranean outflow through the Strait of Gibraltar collected in the frame of the INGRES projects in the last years. Special attention has been devoted to the historically reported deep-water formation basin of the Western Mediterranean (Gulf of Lions) during the pre-conditioning (November and December) and winter seasons. Until around 1970, no clear trend is found in the net heat flux winter series since positive and negative anomalies are observed alternatively. From then onwards, negative anomalies are frequently observed until the 2003-2006 positive events. A net heat loss of about 150 W/m2 is observed in 2005, the highest value since 1956, especially due to evaporation losses towards the atmosphere. The anomalously cold air and sea surface temperature in the area help to increase this contribution that reflects in a higher fraction of Western Mediterranean Deep Water (WMDW) in the outflow through the Strait.

  20. Climate simulations with a new air-sea turbulent flux parameterization in the National Center for Atmospheric Research Community Atmosphere Model (CAM3)

    NASA Astrophysics Data System (ADS)

    Ban, Junmei; Gao, Zhiqiu; Lenschow, Donald H.

    2010-01-01

    This study examines climate simulations with the National Center for Atmospheric Research Community Atmosphere Model version 3 (NCAR CAM3) using a new air-sea turbulent flux parameterization scheme. The current air-sea turbulent flux scheme in CAM3 consists of three basic bulk flux equations that are solved simultaneously by an iterative computational technique. We recently developed a new turbulent flux parameterization scheme where the Obukhov stability length is parameterized directly by using a bulk Richardson number, an aerodynamic roughness length, and a heat roughness length. Its advantages are that it (1) avoids the iterative process and thus increases the computational efficiency, (2) takes account of the difference between z0m and z0h and allows large z0m/z0h, and (3) preserves the accuracy of iteration. An offline test using Tropical Ocean-Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA COARE) data shows that the original scheme overestimates the surface fluxes under very weak winds but the new scheme gives better results. Under identical initial and boundary conditions, the original CAM3 and CAM3 coupled with the new turbulent flux scheme are used to simulate the global distribution of air-sea surface turbulent fluxes, and precipitation. Comparisons of model outputs against the European Remote Sensing Satellites (ERS), the Objectively Analyzed air-sea Fluxes (OAFlux), and Climate Prediction Center (CPC) Merged Analysis of Precipitation (CMAP) show that: (1) the new scheme produces more realistic surface wind stress in the North Pacific and North Atlantic trade wind belts and wintertime extratropical storm track regions; (2) the latent heat flux in the Northern Hemisphere trade wind zones shows modest improvement in the new scheme, and the latent heat flux bias in the western boundary current region of the Gulf Stream is reduced; and (3) the simulated precipitation in the new scheme is closer to observation in the Asian monsoon

  1. Interannual and seasonal variabilities in air-sea CO2 fluxes along the U.S. eastern continental shelf and their sensitivity to increasing air temperatures and variable winds

    NASA Astrophysics Data System (ADS)

    Cahill, Bronwyn; Wilkin, John; Fennel, Katja; Vandemark, Doug; Friedrichs, Marjorie A. M.

    2016-02-01

    Uncertainty in continental shelf air-sea CO2 fluxes motivated us to investigate the impact of interannual and seasonal variabilities in atmospheric forcing on the capacity of three shelf regions along the U.S. eastern continental shelf to act as a sink or source of atmospheric CO2. Our study uses a coupled biogeochemical-circulation model to simulate scenarios of "present-day" and "future-perturbed" mesoscale forcing variability. Overall, the U.S. eastern continental shelf acts as a sink for atmospheric CO2. There is a clear gradient in air-sea CO2 flux along the shelf region, with estimates ranging from -0.6 Mt C yr-1 in the South Atlantic Bight (SAB) to -1.0 Mt C yr-1 in the Mid-Atlantic Bight (MAB) and -2.5 Mt C yr-1 in the Gulf of Maine (GOM). These fluxes are associated with considerable interannual variability, with the largest interannual signal exhibited in the Gulf of Maine. Seasonal variability in the fluxes is also evident, with autumn and winter being the strongest CO2 sink periods and summer months exhibiting some outgassing. In our future-perturbed scenario spatial differences tend to cancel each other out when the fluxes are integrated over the MAB and GOM, resulting in only minor differences between future-perturbed and present-day air-sea CO2 fluxes. This is not the case in the SAB where the position of the along-shelf gradient shifts northward and the SAB becomes a source of CO2 to the atmosphere (0.7 Mt C yr-1) primarily in response to surface warming. Our results highlight the importance of temperature in regulating air-sea CO2 flux variability.

  2. Air-sea Energy Transfer at Mesoscale in a Coupled High-resolution Model: Impact of Resolution and Current Feedback

    NASA Astrophysics Data System (ADS)

    Jullien, S.; Colas, F.; Masson, S. G.; Oerder, V.; Echevin, V.; Samson, G.; Crétat, J.; Berthet, S.; Hourdin, C.

    2015-12-01

    Winds are usually considered to force the ocean but recent studies suggested that oceanic mesoscale activity, characterized by eddies, filaments and fronts, could also affect the wind field. These structures feature abrupt changes in sea surface temperature (SST), surface pressure and surface currents that could impact the atmosphere by enhancing/reducing air-sea fluxes, accelerating/decelerating winds, modifying the wind-pressure balance… At this time, the detailed processes associated to such coupling, its intensity and significance remain a matter of research. Here, a state-of-the-art WRF-OASIS-NEMO coupled model is set up over a wide tropical channel (45°S-45°N) at various resolutions: 3/4°, 1/4° and 1/12° in both the ocean and the atmosphere. Several experiments are conducted in forced, partially or fully coupled modes, to highlight the effect of resolution and the role of SST vs. current feedback to energy injection into the ocean and the atmosphere. In strong mesoscale activity regions, a negative wind power input from the atmosphere to the ocean is seen at scales ranging from 100km to more than 1000km. Nonexistent at 3/4°, this negative forcing, acting against oceanic mesoscale activity, is almost twice more important at 1/12° than at 1/4°. In addition, partially coupled simulations, i.e. without current feedback, show that the impact of thermal coupling on this process is very limited. Energy injection to the marine atmospheric boundary layer also features imprints from oceanic mesoscale. Energy injection by scales shorter than 300km represents up to 20% of the total. Finally we show that increasing oceanic resolution, and therefore mesoscale activity, is necessary to resolve the full wind stress spectrum and has an upscaling effect by enhancing atmospheric mesoscale, which is larger scale than in the ocean. Using 1/4°oceanic resolution instead of 1/12° leads to a 50% loss of energy in the atmospheric mesoscale.

  3. Dynamics of air-sea CO2 fluxes in the northwestern European shelf based on voluntary observing ship and satellite observations

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Macé, E.; Morin, P.; Salt, L. A.; Vernet, M.; Taylor, B.; Paxman, K.; Bozec, Y.

    2015-09-01

    From January 2011 to December 2013, we constructed a comprehensive pCO2 data set based on voluntary observing ship (VOS) measurements in the western English Channel (WEC). We subsequently estimated surface pCO2 and air-sea CO2 fluxes in northwestern European continental shelf waters using multiple linear regressions (MLRs) from remotely sensed sea surface temperature (SST), chlorophyll a concentration (Chl a), wind speed (WND), photosynthetically active radiation (PAR) and modeled mixed layer depth (MLD). We developed specific MLRs for the seasonally stratified northern WEC (nWEC) and the permanently well-mixed southern WEC (sWEC) and calculated surface pCO2 with uncertainties of 17 and 16 μatm, respectively. We extrapolated the relationships obtained for the WEC based on the 2011-2013 data set (1) temporally over a decade and (2) spatially in the adjacent Celtic and Irish seas (CS and IS), two regions which exhibit hydrographical and biogeochemical characteristics similar to those of WEC waters. We validated these extrapolations with pCO2 data from the SOCAT and LDEO databases and obtained good agreement between modeled and observed data. On an annual scale, seasonally stratified systems acted as a sink of CO2 from the atmosphere of -0.6 ± 0.3, -0.9 ± 0.3 and -0.5 ± 0.3 mol C m-2 yr-1 in the northern Celtic Sea, southern Celtic sea and nWEC, respectively, whereas permanently well-mixed systems acted as source of CO2 to the atmosphere of 0.2 ± 0.2 and 0.3 ± 0.2 mol C m-2 yr-1 in the sWEC and IS, respectively. Air-sea CO2 fluxes showed important inter-annual variability resulting in significant differences in the intensity and/or direction of annual fluxes. We scaled the mean annual fluxes over these provinces for the last decade and obtained the first annual average uptake of -1.11 ± 0.32 Tg C yr-1 for this part of the northwestern European continental shelf. Our study showed that combining VOS data with satellite observations can be a powerful tool to

  4. The Coupled Boundary Layers and Air-Sea Transfer (CBLAST) Experiments at the Martha's Vineyard Coastal Observatory

    NASA Astrophysics Data System (ADS)

    Edson, J. B.

    2001-12-01

    The Woods Hole Oceanographic Institution (WHOI) completed the initial phase of the Martha's Vineyard Coastal Observatory (MVCO) in July of 2001. The MVCO is being using to monitor coastal atmospheric and oceanic processes. Specifically, the observatory is expected to: - Provide continuous long-term observations for climate studies. - Provide a reliable system and rugged sensors that allow opportunistic sampling of extreme events. - Provide a local climatology for intensive, short duration field campaigns. - Further facilitate regional studies of coastal processes by providing infrastructure that supports easy access to power and data. This talk provides an example of the last two objectives using the low wind component of the Office of Naval Research's (ONR) Coupled Boundary Layers and Air-Sea Transfer (CBLAST) program. CBLAST-LOW has been designed to investigate air-sea interaction and coupled atmospheric and oceanic boundary layer dynamics at low wind speeds where the dynamic processes are driven and/or strongly modulated by thermal forcing. This effort is being carried out by scientists at WHOI, NPS, NOAA, NRL, Rutgers, UW/APL, JH/APL, OSU, NCAR, and other institutions, and includes observational and modeling components. The MVCO is providing observations and infrastructure in support of several intensive operating periods in the summers of 2001, 2002, and possibly 2003. During these periods, the observational network around the observatory was and will be greatly expanded using traditional oceanographic moorings and bottom mounted instrumentation, innovative 2- and 3-D moored and drifting arrays, survey ships, AUVs, satellite remote sensing, and heavily instrumented aircraft. In addition, the MVCO cabled components will be extended out to the 20-m isobath where we plan to deploy a 35-m tower. The tower will be instrumented from 15-m above the ocean surface to the ocean bottom with instruments capable of directly measuring the momentum, heat, and radiative

  5. What can we learn about ship emission inventories from measurements of air pollutants over the Mediterranean Sea?

    NASA Astrophysics Data System (ADS)

    Marmer, E.; Dentener, F.; Aardenne, J. V.; Cavalli, F.; Vignati, E.; Velchev, K.; Hjorth, J.; Boersma, F.; Vinken, G.; Mihalopoulos, N.; Raes, F.

    2009-03-01

    Ship emission estimates diverge widely for all chemical compounds for several reasons: use of different methodologies (bottom-up or top-down), activity data and emission factors can easily result in a difference from a factor of 1.5 to two orders of magnitude. Despite these large discrepancies in existing ship emission inventories for air pollutants very little has been done to evaluate their consistency with atmospheric measurements at open sea. Combining three sets of observational data - ozone and black carbon measurements sampled at three coastal sites and on board of a Mediterranean cruise ship, as well as satellite observations of atmospheric NO2 column concentration over the same area - we assess the accuracy of the three most commonly used ship emission inventories, EDGAR FT (Olivier et al., 2005), emissions described by Eyring et al. (2005) and emissions reported by EMEP (Vestreng et al., 2007). Our tool is a global atmospheric chemistry transport model which simulates the chemical state of the Mediterranean atmosphere applying different ship emission inventories. The simulated contributions of ships to air pollutant levels in the Mediterranean atmosphere are significant but strongly depend on the inventory applied. Close to the major shipping routes relative contributions vary from 10 to 50% for black carbon and from 2 to 12% for ozone in the surface layer, as well as from 5 to 20% for nitrogen dioxide atmospheric column burden. The relative contributions are still significant over the North African coast, but less so over the South European coast. The observations poorly constrain the ship emission inventories in the Eastern Mediterranean where the influence of uncertain land based emissions, the model transport and wet deposition are at least as important as the signal from ships. In the Western Mediterranean, the regional EMEP emission inventory gives the best match with most measurements, followed by Eyring for NO2 and ozone and by EDGAR for black

  6. Spatio-temporal dynamics of biogeochemical processes and air-sea CO2 fluxes in the Western English Channel based on two years of FerryBox deployment

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Latimier, M.; Macé, E.; Morin, P.; Vernet, M.; Bozec, Y.

    2014-12-01

    From January 2011 to January 2013, a FerryBox system was installed on a Voluntary Observing Ship (VOS), which crossed the Western English Channel (WEC) between Roscoff (France) and Plymouth (UK) up to 3 times a day. The FerryBox continuously measured sea surface temperature (SST), sea surface salinity (SSS), dissolved oxygen (DO), fluorescence and partial pressure of CO2 (from April 2012) along the ferry track. Sensors were calibrated based on 714 bimonthly surface samplings with precisions of 0.016 for SSS, 3.3 μM for DO, 0.40 μg L- 1 for Chlorophyll-a (Chl-a) (based on fluorescence measurements) and 5.2 μatm for pCO2. Over the 2 years of deployment (900 crossings), we reported 9% of data lost due to technical issues and quality checked data was obtained to allow investigation of the dynamics of biogeochemical processes related to air-sea CO2 fluxes in the WEC. Based on this unprecedented high-frequency dataset, the physical structure of the WEC was assessed using SST anomalies and the presence of a thermal front was observed around the latitude 49.5°N, which divided the WEC in two main provinces: the seasonally stratified northern WEC (nWEC) and the all-year well-mixed southern WEC (sWEC). These hydrographical properties strongly influenced the spatial and inter-annual distributions of phytoplankton blooms, which were mainly limited by nutrients and light availability in the nWEC and the sWEC, respectively. Air-sea CO2 fluxes were also highly related to hydrographical properties of the WEC between late April and early September 2012, with the sWEC a weak source of CO2 to the atmosphere of 0.9 mmol m- 2 d- 1, whereas the nWEC acted as a sink for atmospheric CO2 of 6.9 mmol m- 2 d- 1. The study of short time-scale dynamics of air-sea CO2 fluxes revealed that an intense and short (less than 10 days) summer bloom in the nWEC contributed to 29% of the CO2 sink during the productive period, highlighting the necessity for high frequency observations in coastal

  7. Coral Sr/Ca-based sea surface temperature and air temperature variability from the inshore and offshore corals in the Seribu Islands, Indonesia.

    PubMed

    Cahyarini, Sri Yudawati; Zinke, Jens; Troelstra, Simon; Suharsono; Aldrian, Edvin; Hoeksema, B W

    2016-09-30

    The ability of massive Porites corals to faithfully record temperature is assessed. Porites corals from Kepulauan Seribu were sampled from one inshore and one offshore site and analyzed for their Sr/Ca variation. The results show that Sr/Ca of the offshore coral tracked SST, while Sr/Ca variation of the inshore coral tracked ambient air temperature. In particular, the inshore SST variation is related to air temperature anomalies of the urban center of Jakarta. The latter we relate to air-sea interactions modifying inshore SST associated with the land-sea breeze mechanism and/or monsoonal circulation. The correlation pattern of monthly coral Sr/Ca with the Niño3.4 index and SEIO-SST reveals that corals in the Seribu islands region respond differently to remote forcing. An opposite response is observed for inshore and offshore corals in response to El Niño onset, yet similar to El Niño mature phase (December to February). SEIO SSTs co-vary strongly with SST and air temperature variability across the Seribu island reef complex. The results of this study clearly indicate that locations of coral proxy record in Indonesia need to be chosen carefully in order to identify the seasonal climate response to local and remote climate and anthropogenic forcing. PMID:27181035

  8. Seasonal and interannual variability of sea-air CO2 fluxes in the tropical Atlantic affected by the Amazon River plume

    NASA Astrophysics Data System (ADS)

    Ibánhez, J. Severino P.; Diverrès, Denis; Araujo, Moacyr; Lefèvre, Nathalie

    2015-10-01

    CO2 fugacities obtained from a merchant ship sailing from France to French Guyana were used to explore the seasonal and interannual variability of the sea-air CO2 exchange in the western tropical North Atlantic (TNA; 5-14°N, 41-52°W). Two distinct oceanic water masses were identified in the area associated to the main surface currents, i.e., the North Brazil Current (NBC) and the North Equatorial Current (NEC). The NBC was characterized by permanent CO2 oversaturation throughout the studied period, contrasting with the seasonal pattern identified in the NEC. The NBC retroflection was the main contributor to the North Equatorial Counter Current (NECC), thus spreading into the central TNA, the Amazon River plume, and the CO2-rich waters probably originated from the equatorial upwelling. Strong CO2 undersaturation was associated to the Amazon River plume. Total inorganic carbon drawdown due to biological activity was estimated to be 154 µmol kg-1 within the river plume. As a consequence, the studied area acted as a net sink of atmospheric CO2 (from -72.2 ± 10.2 mmol m-2 month-1 in February to 14.3 ± 4.5 mmol m-2 month-1 in May). This contrasted with the net CO2 efflux estimated by the main global sea-air CO2 flux climatologies. Interannual sea surface temperature changes in the TNA caused by large-scale climatic events could determine the direction and intensity of the sea-air CO2 fluxes in the NEC. Positive temperature anomalies observed in the TNA led to an almost permanent CO2 outgassing in the NEC in 2010.

  9. 33 CFR 334.1290 - In Bering Sea, Shemya Island Area, Alaska; meteorological rocket launching facility, Alaskan Air...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., Alaska; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. 334.1290 Section...; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. (a) The danger zone. An arc of a...) Rockets will normally be launched one each day Monday through Friday between 9 a.m. and 3 p.m....

  10. 33 CFR 334.1290 - In Bering Sea, Shemya Island Area, Alaska; meteorological rocket launching facility, Alaskan Air...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., Alaska; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. 334.1290 Section...; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. (a) The danger zone. An arc of a...) Rockets will normally be launched one each day Monday through Friday between 9 a.m. and 3 p.m....

  11. 33 CFR 334.1290 - In Bering Sea, Shemya Island Area, Alaska; meteorological rocket launching facility, Alaskan Air...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., Alaska; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. 334.1290 Section...; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. (a) The danger zone. An arc of a...) Rockets will normally be launched one each day Monday through Friday between 9 a.m. and 3 p.m....

  12. 33 CFR 334.1290 - In Bering Sea, Shemya Island Area, Alaska; meteorological rocket launching facility, Alaskan Air...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., Alaska; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. 334.1290 Section...; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. (a) The danger zone. An arc of a...) Rockets will normally be launched one each day Monday through Friday between 9 a.m. and 3 p.m....

  13. 33 CFR 334.1290 - In Bering Sea, Shemya Island Area, Alaska; meteorological rocket launching facility, Alaskan Air...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., Alaska; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. 334.1290 Section...; meteorological rocket launching facility, Alaskan Air Command, U.S. Air Force. (a) The danger zone. An arc of a...) Rockets will normally be launched one each day Monday through Friday between 9 a.m. and 3 p.m....

  14. 3D Tomographic Imaging of the Crustal Velocity Structure beneath the Marmara Sea using Air-gun and Earthquake Data

    NASA Astrophysics Data System (ADS)

    Tarancioglu, Adil; Kocaoglu, Argun H.; Ozalaybey, Serdar

    2014-05-01

    The objective of this study is to investigate the local seismicity and obtain a detailed three-dimensional crustal velocity structure beneath the Marmara Sea in an area surrounding the North Anatolian Fault Zone (NAFZ) by tomographic inversion using both controlled-source (air-gun) and earthquake data. The tomographic inversion is carried out by using the local earthquake tomography code SIMUL2000. Two sets of seismological data, collected in 2006 (EOSMARMARA experiment) and 2001 (SEISMARMARA experiment), are re-processed and used in this study. A total of 441 high quality earthquakes and 452 air-gun shots recorded by a total of 53 Ocean Bottom Seismometers (OBS) are selected for the simultaneous inversion for velocity and hypocentral parameters. The OBS location and time-drift errors are identified from air-gun shot records by a grid search method and required corrections are made on the travel time data. The initial (reference) velocity model and earthquake locations required for the three dimensional tomographic inversion are derived from the one-dimensional velocity model obtained by using the VELEST algorithm in which a subset of earthquakes are selected such that phase readings were made by at least five stations and maximum azimuthal gap was 180o. The inversion results are checked for initial model dependence and the effect of damping factor. The reliability of the results is also evaluated in terms of derivative-weighted-sum, resolution-diagonal-elements values and checkerboard tests. The hypocenter locations of the local earthquakes have been remarkably improved by the three-dimensional velocity model obtained from the tomographic inversion. The three-dimensional velocity model shows that the Tekirdag, Central and Cinarcik Basins are characterized generally by lower Vp (3.0 - 3.5 km/s) values and most of the earthquakes across these regions are located at the depths of 10 to 17 km, about 5 km deeper than those obtained from the one-dimensional reference

  15. Simulating Emission and Chemical Evolution of Coarse Sea-Salt Particles in the Community Multiscale Air Quality (CMAQ) Model

    EPA Science Inventory

    Chemical processing of sea-salt particles in coastal environments significantly impacts concentrations of particle components and gas-phase species and has implications for human exposure to particulate matter and nitrogen deposition to sensitive ecosystems. Emission of sea-sal...

  16. Contrast of local air-sea relationships between 10-20-day and 30-60-day intraseasonal oscillations during May-September over the South China Sea and western North Pacific

    NASA Astrophysics Data System (ADS)

    Ye, Kunhui; Wu, Renguang

    2015-12-01

    Present study compares local air-sea relationship of 10-20-day and 30-60-day intraseasonal oscillations (ISOs) over the South China Sea (SCS) and western North Pacific (WNP) during May through September for the period 1998-2010. It is shown that sea surface temperature (SST) has a larger intraseasonal variance in the North Indian Ocean, the SCS, and subtropical WNP on the 30-60-day time scale, but in tropical WNP on the 10-20-day time scale. The local correlation of SST with rain, surface shortwave radiation (SWR) and latent heat flux (LHF) displays a southwest-northeast tilted structure on the 10-20-day time scale, but a broad west-east pattern with a larger correlation on the 30-60-day time scale. The time of SST leading rain is larger in off-equatorial regions than in near-equatorial regions for both types of ISOs, whereas the time of rain leading SST is larger in near-equatorial regions than in off-equatorial regions. A similar feature is seen for SWR, but an opposite feature for LHF. The atmospheric ISOs induce intraseasonal SST variations through cloud-radiation and wind-evaporation changes. The intraseasonal SST variations feedback on the atmosphere through modulation of atmospheric stability over off-equatorial regions on both timescales. The SST impacts on the atmosphere appear larger on the 30-60-day time scale than on the 10-20-day time scale. The distinct spatial patterns of local air-sea relationship on the two types of ISOs are associated with different spatial structures in both atmospheric ISO-associated SWR and LHF anomalies and SST-induced atmospheric stability anomalies.

  17. Air-sea exchange of dimethylsulfide in the Southern Ocean: Measurements from SO GasEx compared to temperate and tropical regions

    NASA Astrophysics Data System (ADS)

    Yang, M.; Blomquist, B. W.; Fairall, C. W.; Archer, S. D.; Huebert, B. J.

    2011-04-01

    In the Southern Ocean Gas Exchange Experiment (SO GasEx), we measured an atmospheric dimethylsulfide (DMS) concentration of 118 ± 54 pptv (1σ), a DMS sea-to-air flux of 2.9 ± 2.1 μmol m-2 d-1 by eddy covariance, and a seawater DMS concentration of 1.6 ± 0.7 nM. Dividing flux by the concurrent air-sea concentration difference yields the transfer velocity of DMS (kDMS). The kDMS in the Southern Ocean was significantly lower than previous measurements in the equatorial east Pacific, Sargasso Sea, northeast Atlantic, and southeast Pacific. Normalizing kDMS for the temperature dependence in waterside diffusivity and solubility results in better agreement among various field studies and suggests that the low kDMS in the Southern Ocean is primarily due to colder temperatures. The higher solubility of DMS at a lower temperature results in greater airside control and less transfer of the gas by bubbles formed from breaking waves. The final normalized DMS transfer velocity is similar to k of less soluble gases such as carbon dioxide in low-to-moderate winds; in high winds, DMS transfer velocity is significantly lower because of the reduced bubble-mediated transfer.

  18. Interannual Variability of South-Eastern African Summer Rainfall. Part 1: Relationships with Air-Sea Interaction Processes

    NASA Astrophysics Data System (ADS)

    Rocha, Alfredo; Simmonds, Ian

    1997-03-01

    This paper investigates the role that air-sea interaction processes may play in interannual variability of south-eastern African summer rainfall. The principal spatial modes of south-eastern African summer rainfall are first identified using principal component analysis. Four modes are retained. The most important mode of variability is found to represent rainfall variability over most of the domain, particularly in the regions to the south.The influence of ENSO (as measured by the SOI) on summer rainfall is investigated in detail for different SOI leads. The relationship is such that during the summer following the onset of an ENSO event, south-eastern Africa tends to experience dry conditions. Strongest relationships are found with the SOI leading rainfall by about 3 to 6 months.A second index, the Brandon-Marion Index (BMI) which is indicative of changes in the pressure field over the Indian Ocean correlates with rainfall better than the SOI. Strongest correlations are found when this index leads rainfall by about 1 to 3 months. More importantly, a partial correlation analysis reveals that the BMI influences rainfall independently of ENSO. Both the SOI and the BMI are potential predictors of summer rainfall.An investigation of rainfall associations with global SST anomalies reveals areas in the tropical Indian and Pacific Oceans that are linked with rainfall changes over the subcontinent. The relationship is such that warm anomalies tend to be followed by dry conditions over much of south-eastern Africa. Strongest relationships are found when SSTs lead the rainfall season by about 1 to 3 months. Well-defined atmospheric anomalies are identified during dry south-eastern African summers. These include, amongst others, anomalously warm tropospheric temperatures and marked low-level cyclonic circulation anomalies over the central Indian Ocean, which generate abnormally weak easterly winds along much of the south-eastern coast of Africa. These perturbations to the

  19. Hurricane-related air-sea interactions, circulation modifications, and coastal impacts on the eastern Louisiana coastline

    NASA Astrophysics Data System (ADS)

    Walker, N. D.; Pilley, C.; Li, C.; Liu, B.; Leben, R. R.; Raghunthan, V.; Ko, D.; Teague, W. J.

    2012-12-01

    Beginning in 1995, Atlantic hurricane activity increased significantly relative to the 1970s and 1980s. In 2005, records were broken when two hurricanes intensified rapidly to Category 5 for a period of time within the Gulf of Mexico, later landed, and flooded vast expanses of Louisiana's coastal regions within the span of 30 days. In this study, we investigate major hurricane events (including 2005) to elucidate air-sea interactions pertinent to hurricane intensity changes, shelf circulation, coastal flooding, and coastal land losses. We employ satellite measurements from passive sensors (temperature, true color, pigments) and active sensors (scatterometers, altimeters) in tandem with in-situ measurements from WAVCIS, NDBC, USGS, and NRL, as well as dedicated field campaigns along the coast. A selection of hurricane events during the 1998 to 2008 time period are used in this investigation. Research has shown that the Loop Current and its warm-core anticyclonic eddies (with high heat content) can intensify hurricanes transiting the Gulf; whereas, the cold-core cyclonic eddies (which are upwelling regions) can weaken hurricanes. Hurricane winds can intensify cold-core cyclonic eddies, which in some cases can impact outer shelf currents, mixing, and thermal structure throughout the water column. The exceptionally strong winds and waves in the northeast quadrant of these cyclonic atmospheric storms drive strong and long-lived westward currents. Storm surges and/or set-up of 2-6 m commonly occur along the Louisiana coastline, sometimes as a result of hurricanes traveling across the central Gulf of Mexico, at great distances from the coastal region experiencing the flooding (e.g. Hurricanes Rita and Gustav). The eastern shelf, north of the Mississippi River Birdfoot Delta, is particularly vulnerable to water level set-up and storm surge intensification due to the coastal orientation that causes the trapping of water. This area experienced land loss of 169 km2, or ~20

  20. Dependence of the microwave radar cross section on ocean surface variables - Comparison of measurements and theory using data from the Frontal Air-Sea Interaction Experiment

    NASA Technical Reports Server (NTRS)

    Weissman, David E.

    1990-01-01

    The purpose of this investigation was to study the ability of theoretical radar cross section (RCS) models to predict the absolute magnitude of the ocean radar cross section under a wide variety of sea and atmospheric conditions. The dependence of the RCS on wind stress (as opposed to wind speed) was also studied. An extensive amount of experimental data was acquired during the Frontal Air-Sea Interaction Experiment. Measurements across an ocean front demonstrated that the vertical polarization and horizontal polarization radar cross section were more strongly dependent on wind stress than on wind magnitude. Current theoretical models for the RCS, based on stress, were tested with this data. In situations where the Bragg scattering theory does not agree with the measured radar cross section (magnitude and angle dependence), revisions are hypothesized and evaluated.

  1. A Numerical Study of Tropical Sea-Air Interactions Using a Cloud Resolving Model Coupled with an Ocean Mixed-Layer Model

    NASA Technical Reports Server (NTRS)

    Shie, Chung-Lin; Tao, Wei-Kuo; Johnson, Dan; Simpson, Joanne; Li, Xiaofan; Sui, Chung-Hsiung; Einaudi, Franco (Technical Monitor)

    2001-01-01

    Coupling a cloud resolving model (CRM) with an ocean mixed layer (OML) model can provide a powerful tool for better understanding impacts of atmospheric precipitation on sea surface temperature (SST) and salinity. The objective of this study is twofold. First, by using the three dimensional (3-D) CRM-simulated (the Goddard Cumulus Ensemble model, GCE) diabatic source terms, radiation (longwave and shortwave), surface fluxes (sensible and latent heat, and wind stress), and precipitation as input for the OML model, the respective impact of individual component on upper ocean heat and salt budgets are investigated. Secondly, a two-way air-sea interaction between tropical atmospheric climates (involving atmospheric radiative-convective processes) and upper ocean boundary layer is also examined using a coupled two dimensional (2-D) GCE and OML model. Results presented here, however, only involve the first aspect. Complete results will be presented at the conference.

  2. Regional variability in diving physiology and behavior in a widely distributed air-breathing marine predator, the South American sea lion (Otaria byronia).

    PubMed

    Hückstädt, Luis A; Tift, Michael S; Riet-Sapriza, Federico; Franco-Trecu, Valentina; Baylis, Alastair M M; Orben, Rachael A; Arnould, John P Y; Sepulveda, Maritza; Santos-Carvallo, Macarena; Burns, Jennifer M; Costa, Daniel P

    2016-08-01

    Our understanding of how air-breathing marine predators cope with environmental variability is limited by our inadequate knowledge of their ecological and physiological parameters. Because of their wide distribution along both coasts of the sub-continent, South American sea lions (Otaria byronia) provide a valuable opportunity to study the behavioral and physiological plasticity of a marine predator in different environments. We measured the oxygen stores and diving behavior of South American sea lions throughout most of its range, allowing us to demonstrate that diving ability and behavior vary across its range. We found no significant differences in mass-specific blood volumes of sea lions among field sites and a negative relationship between mass-specific oxygen storage and size, which suggests that exposure to different habitats and geographical locations better explains oxygen storage capacities and diving capability in South American sea lions than body size alone. The largest animals in our study (individuals from Uruguay) were the shallowest and shortest duration divers, and had the lowest mass-specific total body oxygen stores, while the deepest and longest duration divers (individuals from southern Chile) had significantly larger mass-specific oxygen stores, despite being much smaller animals. Our study suggests that the physiology of air-breathing diving predators is not fixed, but that it can be adjusted, to a certain extent, depending on the ecological setting and or habitat. These adjustments can be thought of as a 'training effect': as the animal continues to push its physiological capacity through greater hypoxic exposure, its breath-holding capacity increases. PMID:27247316

  3. An Approach to Minimizing Artifacts Caused by Cross-Sensitivity in the Determination of Air-Sea CO2 Flux Using the Eddy-Covariance Technique

    NASA Astrophysics Data System (ADS)

    Duan, Ziqiang; Gao, Huiwang; Gao, Zengxiang; Wang, Renlei; Xue, Yuhuan; Yao, Xiaohong

    2013-07-01

    The air-sea CO2 flux was measured from a research vessel in the North Yellow Sea in October 2007 using an open-path eddy-covariance technique. In 11 out of 64 samples, the normalized spectra of scalars (C}2, water vapour, and temperature) showed similarities. However, in the remaining samples, the normalized CO2 spectra were observed to be greater than those of water vapour and temperature at low frequencies. In this paper, the noise due to cross-sensitivity was identified through a combination of intercomparisons among the normalized spectra of three scalars and additional analyses. Upon examination, the cross-sensitivity noise appeared to be mainly present at frequencies {<}0.8 Hz. Our analysis also suggested that the high-frequency fluctuations of CO2 concentration (frequency {>}0.8 Hz) was probably less affected by the cross-sensitivity. To circumvent the cross-sensitivity issue, the cospectrum in the high-frequency range 0.8-1.5 Hz, instead of the whole range, was used to estimate the CO2 flux by taking the contribution of the high frequency to the CO2 flux to be the same as the contribution to the water vapour flux. The estimated air-sea CO2 flux in the North Yellow Sea was -0.039 ± 0.048 mg m^{-2} s^{-1}, a value comparable to the estimates using the inertial dissipation method and Edson's method (Edson et al., J Geophys Res 116:C00F10, 2011).

  4. The impact of shipping emissions on air pollution in the greater North Sea region - Part 2: Scenarios for 2030

    NASA Astrophysics Data System (ADS)

    Matthias, V.; Aulinger, A.; Backes, A.; Bieser, J.; Geyer, B.; Quante, M.; Zeretzke, M.

    2016-01-01

    Scenarios for future shipping emissions in the North Sea have been developed in the framework of the Clean North Sea Shipping project. The effects of changing NOx and SO2 emissions were investigated with the CMAQ chemistry transport model for the year 2030 in the North Sea area. It has been found that, compared to today, the contribution of shipping to the NO2 and O3 concentrations will increase due to the expected enhanced traffic by more than 20 and 5 %, respectively, by 2030 if no regulation for further emission reductions is implemented in the North Sea area. PM2.5 will decrease slightly because the sulfur contents in ship fuels will be reduced as international regulations foresee. The effects differ largely between regions, seasons and date of the implementation of stricter regulations for NOx emissions from newly built ships.

  5. The impact of shipping emissions on air pollution in the Greater North Sea region - Part 2: Scenarios for 2030

    NASA Astrophysics Data System (ADS)

    Matthias, V.; Aulinger, A.; Backes, A.; Bieser, J.; Geyer, B.; Quante, M.; Zeretzke, M.

    2015-04-01

    Scenarios for future shipping emissions in the North Sea have been developed in the framework of the Clean North Sea Shipping project. The effects of changing NOx and SO2 emissions were invesigated with the chemistry transport model CMAQ for the year 2030 in the North Sea area. It has been found that, compared to today, the contribution of shipping to the NO2 and O3 concentrations will increase due to the expected enhanced traffic by more than 20 and 5%, respectively, by 2030 if no regulation for further emission reductions will be implemented in the North Sea area. PM2.5 will decrease slightly because the sulphur contents in ship fuels will be reduced as international regulations foresee. The effects differ largely between regions, seasons and date of the implementation of stricter regulations for NOx emissions from new built ships.

  6. Dynamics of air-sea CO2 fluxes in the North-West European Shelf based on Voluntary Observing Ship (VOS) and satellite observations

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Macé, E.; Morin, P.; Salt, L. A.; Vernet, M.; Taylor, B.; Paxman, K.; Bozec, Y.

    2015-04-01

    From January 2011 to December 2013, we constructed a comprehensive pCO2 dataset based on voluntary observing ship (VOS) measurements in the Western English Channel (WEC). We subsequently estimated surface pCO2 and air-sea CO2 fluxes in north-west European continental shelf waters using multiple linear regressions (MLRs) from remotely sensed sea surface temperature (SST), chlorophyll a concentration (Chl a), the gas transfer velocity coefficient (K), photosynthetically active radiation (PAR) and modeled mixed layer depth (MLD). We developed specific MLRs for the seasonally stratified northern WEC (nWEC) and the permanently well-mixed southern WEC (sWEC) and calculated surface pCO2 with relative uncertainties of 17 and 16 μatm, respectively. We extrapolated the relationships obtained for the WEC based on the 2011-2013 dataset (1) temporally over a decade and (2) spatially in the adjacent Celtic and Irish Seas (CS and IS), two regions which exhibit hydrographical and biogeochemical characteristics similar to those of WEC waters. We validated these extrapolations with pCO2 data from the SOCAT database and obtained relatively robust results with an average precision of 4 ± 22 μatm in the seasonally stratified nWEC and the southern and northern CS (sCS and nCS), but less promising results in the permanently well-mixed sWEC, IS and Cap Lizard (CL) waters. On an annual scale, seasonally stratified systems acted as a sink of CO2 from the atmosphere of -0.4, -0.9 and -0.4 mol C m-2 year-1 in the nCS, sCS and nWEC, respectively, whereas, permanently well-mixed systems acted as source of CO2 to the atmosphere of 0.2, 0.4 and 0.4 mol C m-2 year-1 in the sWEC, CL and IS, respectively. Air-sea CO2 fluxes showed important inter-annual variability resulting in significant differences in the intensity and/or direction of annual fluxes. We scaled the mean annual fluxes over six provinces for the last decade and obtained the first annual average uptake of -0.95 Tg C year-1 for this

  7. Response of biological production and air-sea CO2 fluxes to upwelling intensification in the California and Canary Current Systems

    NASA Astrophysics Data System (ADS)

    Lachkar, Zouhair; Gruber, Nicolas

    2013-01-01

    Upwelling-favorable winds have increased in most Eastern Boundary Upwelling Systems (EBUS) in the last decades, and it is likely that they increase further in response to global climate change. Here, we explore the response of biological production and air-sea CO2 fluxes to upwelling intensification in two of the four major EBUS, namely the California Current System (California CS) and Canary Current System (Canary CS). To this end, we use eddy-resolving regional ocean models on the basis of the Regional Oceanic Modeling System (ROMS) to which we have coupled a NPZD-type ecosystem model and a biogeochemistry module describing the carbon cycle and subject these model configurations to an idealized increase in the wind stress. We find that a doubling of the wind-stress doubles net primary production (NPP) in the southern California CS and central and northern Canary CS, while it leads to an increase of less than 50% in the central and northern California CS as well as in the southern Canary CS. This differential response is a result of i) different nutrient limitation states with higher sensitivity to upwelling intensification in regions where nutrient limitation is stronger and ii) more efficient nutrient assimilation by biology in the Canary CS relative to the California CS because of a faster nutrient-replete growth rate and longer nearshore water residence times. In the regions where production increases commensurably with upwelling intensification, the enhanced net biological uptake of CO2 compensates the increase in upwelling driven CO2 outgassing, resulting in only a small change in the biological pump efficiency and hence in a small sensitivity of air-sea CO2 fluxes to upwelling intensification. In contrast, in the central California CS as well as in the southern Canary CS around Cape Blanc, the reduced biological efficiency enhances the CO2 outgassing and leads to a substantial sensitivity of the air-sea CO2 fluxes to upwelling intensification.

  8. Accounting for observational uncertainties in the evaluation of low latitude turbulent air-sea fluxes simulated in a suite of IPSL model versions

    NASA Astrophysics Data System (ADS)

    Servonnat, Jerome; Braconnot, Pascale; Gainusa-Bogdan, Alina

    2015-04-01

    Turbulent momentum and heat (sensible and latent) fluxes at the air-sea interface are key components of the whole energetic of the Earth's climate and their good representation in climate models is of prime importance. In this work, we use the methodology developed by Braconnot & Frankignoul (1993) to perform a Hotelling T2 test on spatio-temporal fields (annual cycles). This statistic provides a quantitative measure accounting for an estimate of the observational uncertainty for the evaluation of low-latitude turbulent air-sea fluxes in a suite of IPSL model versions. The spread within the observational ensemble of turbulent flux data products assembled by Gainusa-Bogdan et al (submitted) is used as an estimate of the observational uncertainty for the different turbulent fluxes. The methodology holds on a selection of a small number of dominating variability patterns (EOFs) that are common to both the model and the observations for the comparison. Consequently it focuses on the large-scale variability patterns and avoids the possibly noisy smaller scales. The results show that different versions of the IPSL couple model share common large scale model biases, but also that there the skill on sea surface temperature is not necessarily directly related to the skill in the representation of the different turbulent fluxes. Despite the large error bars on the observations the test clearly distinguish the different merits of the different model version. The analyses of the common EOF patterns and related time series provide guidance on the major differences with the observations. This work is a first attempt to use such statistic on the evaluation of the spatio-temporal variability of the turbulent fluxes, accounting for an observational uncertainty, and represents an efficient tool for systematic evaluation of simulated air-seafluxes, considering both the fluxes and the related atmospheric variables. References Braconnot, P., and C. Frankignoul (1993), Testing Model

  9. Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean

    NASA Astrophysics Data System (ADS)

    Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.

    2013-09-01

    Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate processes that control the distribution of δ13C of dissolved inorganic carbon (DIC) in the contemporary and preindustrial ocean. Biological fractionation and the sinking of isotopically light δ13C organic matter from the surface into the interior ocean leads to low δ13CDIC values at depths and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange has two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature-dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, since air-sea gas exchange is slow in the modern ocean, the biological effect dominates spatial δ13CDIC gradients both in the interior and at the surface, in contrast to conclusions from some previous studies. Calcium carbonate cycling, pH dependency of fractionation during air-sea gas exchange, and kinetic fractionation have minor effects on δ13CDIC. Accumulation of isotopically light carbon from anthropogenic fossil fuel burning has decreased the spatial variability of surface and deep δ13CDIC since the industrial revolution in our model simulations. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed and remineralized contributions as well as the effects of biology and air-sea gas exchange. The model reproduces major features of the observed large-scale distribution of δ13CDIC as well as the individual contributions and effects. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by

  10. Separating the influence of projected changes in air temperature and wind on patterns of sea level change and ocean heat content

    NASA Astrophysics Data System (ADS)

    Saenko, Oleg A.; Yang, Duo; Gregory, Jonathan M.; Spence, Paul; Myers, Paul G.

    2015-08-01

    We present ocean model sensitivity experiments aimed at separating the influence of the projected changes in the "thermal" (near-surface air temperature) and "wind" (near-surface winds) forcing on the patterns of sea level and ocean heat content. In the North Atlantic, the distribution of sea level change is more due to the "thermal" forcing, whereas it is more due to the "wind" forcing in the North Pacific; in the Southern Ocean, the "thermal" and "wind" forcing have a comparable influence. In the ocean adjacent to Antarctica the "thermal" forcing leads to an inflow of warmer waters on the continental shelves, which is somewhat attenuated by the "wind" forcing. The structure of the vertically integrated heat uptake is set by different processes at low and high latitudes: at low latitudes it is dominated by the heat transport convergence, whereas at high latitudes it represents a small residual of changes in the surface flux and advection of heat. The structure of the horizontally integrated heat content tendency is set by the increase of downward heat flux by the mean circulation and comparable decrease of upward heat flux by the subgrid-scale processes; the upward eddy heat flux decreases and increases by almost the same magnitude in response to, respectively, the "thermal" and "wind" forcing. Regionally, the surface heat loss and deep convection weaken in the Labrador Sea, but intensify in the Greenland Sea in the region of sea ice retreat. The enhanced heat flux anomaly in the subpolar Atlantic is mainly caused by the "thermal" forcing.

  11. Modeling the impact of air, sea, and land travel restrictions supplemented by other interventions on the emergence of a new influenza pandemic virus

    PubMed Central

    2012-01-01

    Background During the early stages of a new influenza pandemic, travel restriction is an immediate and non-pharmaceutical means of retarding incidence growth. It extends the time frame of effective mitigation, especially when the characteristics of the emerging virus are unknown. In the present study, we used the 2009 influenza A pandemic as a case study to evaluate the impact of regulating air, sea, and land transport. Other government strategies, namely, antivirals and hospitalizations, were also evaluated. Methods Hong Kong arrivals from 44 countries via air, sea, and land transports were imported into a discrete stochastic Susceptible, Exposed, Infectious and Recovered (SEIR) host-flow model. The model allowed a number of latent and infectious cases to pass the border, which constitutes a source of local disease transmission. We also modeled antiviral and hospitalization prevention strategies to compare the effectiveness of these control measures. Baseline reproduction rate was estimated from routine surveillance data. Results Regarding air travel, the main route connected to the influenza source area should be targeted for travel restrictions; imposing a 99% air travel restriction delayed the epidemic peak by up to two weeks. Once the pandemic was established in China, the strong land connection between Hong Kong and China rendered Hong Kong vulnerable. Antivirals and hospitalization were found to be more effective on attack rate reductions than travel restrictions. Combined strategies (with 99% restriction on all transport modes) deferred the peak for long enough to establish a vaccination program. Conclusion The findings will assist policy-makers with decisions on handling similar future pandemics. We also suggest regulating the extent of restriction and the transport mode, once restriction has been deemed necessary for pandemic control. Although travel restrictions have yet to gain social acceptance, they allow time for mitigation response when a new and

  12. Sea-ice melt CO2-carbonate chemistry in the western Arctic Ocean: meltwater contributions to air-sea CO2 gas exchange, mixed-layer properties and rates of net community production under sea ice

    NASA Astrophysics Data System (ADS)

    Bates, N. R.; Garley, R.; Frey, K. E.; Shake, K. L.; Mathis, J. T.

    2014-12-01

    The carbon dioxide (CO2)-carbonate chemistry of sea-ice melt and co-located, contemporaneous seawater has rarely been studied in sea-ice-covered oceans. Here, we describe the CO2-carbonate chemistry of sea-ice melt (both above sea-ice as "melt ponds" and below sea-ice as "interface waters") and mixed-layer properties in the western Arctic Ocean in the early summer of 2010 and 2011. At 19 stations, the salinity (∼0.5 to <6.5), dissolved inorganic carbon (DIC; ∼20 to <550 μmol kg-1) and total alkalinity (TA; ∼30 to <500 μmol kg-1) of above-ice melt pond water was low compared to the co-located underlying mixed layer. The partial pressure of CO2 (pCO2) in these melt ponds was highly variable (∼<10 to >1500 μatm) with the majority of melt ponds acting as potentially strong sources of CO2 to the atmosphere. The pH of melt pond waters was also highly variable ranging from mildly acidic (6.1 to 7) to slightly more alkaline than underlying seawater (>8.2 to 10.8). All of the observed melt ponds had very low (<0.1) saturation states (Ω) for calcium carbonate (CaCO3) minerals such as aragonite (Ωaragonite). Our data suggest that sea-ice generated alkaline or acidic type melt pond water. This melt water chemistry dictates whether the ponds are sources of CO2 to the atmosphere or CO2 sinks. Below-ice interface water CO2-carbonate chemistry data also indicated substantial generation of alkalinity, presumably owing to dissolution of CaCO3 in sea-ice. The interface waters generally had lower pCO2 and higher pH/Ωaragonite than the co-located mixed layer beneath. Sea-ice melt thus contributed to the suppression of mixed-layer pCO2, thereby enhancing the surface ocean's capacity to uptake CO2 from the atmosphere. Our observations contribute to growing evidence that sea-ice CO2-carbonate chemistry is highly variable and its contribution to the complex factors that influence the balance of CO2 sinks and sources (and thereby ocean acidification) is difficult to

  13. Arrival time distributions of electrons in air showers with primary energies above 10 (18)eV observed at 900m above sea level

    NASA Technical Reports Server (NTRS)

    Kakimoto, F.; Enoki, T.; Nishi, K.; Tsuchimoto, I.; Suga, K.

    1985-01-01

    Detection of air showers with primary energies above 10 to the 19th power eV with sufficient statistics is extremely important in an astrophysical aspect related to the Greisen cut off and the origin of such high energy cosmic rays. Recently, a method is proposed to observe such giant air showers by measuring the arrival time distributions of air-shower particles at large core distances with a mini array. Experiments to measure the arrival time distributions of muons were started in 1981 and those of electrons in early 1983 in the Akeno air-shower array (930 gcm cm squared atmospheric depth, 900m above sea level). During the time of observation, the detection area of the Akeno array was expanded from 1 sq km to sq km in 1982 and to 20 sq km in 1984. Now the arrival time distribution of electrons and muons can be measured for showers with primary energies above 1019eV at large core distances.

  14. Using Sea Level to Probe Linkages Between Heat Transport Convergence, Heat Storage Rate, and Air-Sea Heat Exchange in the Subtropical North Atlantic

    NASA Astrophysics Data System (ADS)

    Thompson, L.; Kelly, K. A.; Booth, J. F.

    2014-12-01

    Annual mean surface heat fluxes from the ocean to the atmosphere in midlatitudes are maximum in the Gulf Stream and that surface flux is driven by geostrophic heat transport convergence. Evidence is mounting that on interannual times scales, the surface flux of heat in the Gulf Stream region is controlled by the amount of heat that is stored in the region and that the heat storage rate is in turn controlled by geostrophic heat transport convergence. In addition, variations in meridional heat transport have been linked to the meridional overturning circulation just to the south of the Gulf Stream at the RAPID/MOCHA array at 26.5N, suggesting that changes in the meridional overturning circulation might be linked to surface heat exchange in the Gulf Stream. The twenty-year record of satellite sea level (SSH) along with high quality surface heat fluxes allow a detailed evaluation of the interaction between stored oceanic heat in this region and surface heat fluxes on interannual times scales. Using gridded sea level from AVISO as a proxy for upper ocean heat content along with surface turbulent heat flux from OAFlux, we evaluate the lagged correlations between interannual surface turbulent heat fluxes and SSH variability. Previous work has shown that where advection is small lagged correlations between SST (sea surface temperature) and surface turbulent heat flux are generally antisymmetric about zero lag with negative correlations when SST leads and positive correlations when SST lags. This indicates that surface heat fluxes force SST anomalies that at later times are damped by surface fluxes. In contrast, the lagged correlation between SSH anomalies and the turbulent flux of heat in the Gulf Stream region show a distinctly asymmetric relationship about zero-lag. The correlations are negative when SSH leads but are not significant when SSH lags indicating the dominant role in heat transport convergence in driving heat content changes, and that the heat content

  15. Effects of the Tibetan Plateau on the onsetof the summer monsoon in South Asia: The role of the air-sea interaction

    NASA Astrophysics Data System (ADS)

    Abe, Manabu; Hori, Masatake; Yasunari, Tetsuzo; Kitoh, Akio

    2013-02-01

    Using both a coupled atmosphere-ocean general circulation model (GCM) and an atmospheric GCM, we investigate the effects of the Tibetan Plateau (TP) on the onset of the South Asian summer monsoon by conducting simulations with and without the TP. In the coupled GCM, the presence of the TP causes the monsoon onset to occur approximately 15 days later in the Arabian Sea (AS) and India (ID) and approximately 10 days earlier in the Bay of Bengal (BB). These changes are attributed to different atmospheric circulation patterns and different conditions within the adjacent oceans, such as the AS and the BB. When the TP is included, lower sea surface temperatures (SSTs) in the AS contribute to a stable lower atmosphere, which suppresses convection over the AS and ID in May. In contrast, low pressure over South Asia, caused by the TP, induces a southwesterly toward the BB that transports a substantial amount of water vapor to the BB. This flow results in an earlier monsoon in the BB. Without the TP, higher SSTs that are formed in the AS in May destabilize the lower atmosphere and create a depression, resulting in an earlier onset of the monsoon over the AS and ID. Consequently, the cyclonic circulation spreads abruptly to the BB, and precipitation begins to increase over the BB. Therefore, the air-sea interaction in the adjacent ocean under the influence of the TP strongly modulates the onset of the South Asian summer monsoon. This modulation was verified by the atmospheric GCM experiments.

  16. Net sea-air CO2 fluxes and modelled pCO2 in the southwestern subtropical Atlantic continental shelf during spring 2010 and summer 2011

    NASA Astrophysics Data System (ADS)

    Ito, Rosane Gonçalves; Garcia, Carlos Alberto Eiras; Tavano, Virginia Maria

    2016-05-01

    Sea-air CO2 fluxes over continental shelves vary substantially in time on both seasonal and sub-seasonal scales, driven primarily by variations in surface pCO2 due to several oceanic mechanisms. Furthermore, coastal zones have not been appropriately considered in global estimates of sea-air CO2 fluxes, despite their importance to ecology and to productivity. In this work, we aimed to improve our understanding of the role played by shelf waters in controlling sea-air CO2 fluxes by investigating the southwestern Atlantic Ocean (21-35°S) region, where physical, chemical and biological measurements were made on board the Brazilian R. V. Cruzeiro do Sul during late spring 2010 and early summer 2011. Features such as discharge from the La Plata River, intrusions of tropical waters on the outer shelf due to meandering and flow instabilities of the Brazil Current, and coastal upwelling in the Santa Marta Grande Cape and São Tomé Cape were detected by both in situ measurements and ocean colour and thermal satellite imagery. Overall, shelf waters in the study area were a source of CO2 to the atmosphere, with an average of 1.2 mmol CO2 m-2 day-1 for the late spring and 11.2 mmol CO2 m-2 day-1 for the early summer cruises. The spatial variability in ocean pCO2 was associated with surface ocean properties (temperature, salinity and chlorophyll-a concentration) in both the slope and shelf waters. Empirical algorithms for predicting temperature-normalized surface ocean pCO2 as a function of surface ocean properties were shown to perform well in both shelf and slope waters, except (a) within cyclonic eddies produced by baroclinic instability of the Brazil Current as detected by satellite SST imagery and (b) in coastal upwelling regions. In these regions, surface ocean pCO2 values were higher as a result of upwelled CO2-enriched subsurface waters. Finally, a pCO2 algorithm based on both sea surface temperature and surface chlorophyll-a was developed that enabled the spatial

  17. Direct Measurement of Air-Sea Exchange of N2O5 and ClNO2 at a Polluted Coastal Site (Invited)

    NASA Astrophysics Data System (ADS)

    Bertram, T. H.; Kim, M.; Ryder, O. S.; Farmer, D.

    2013-12-01

    The reactive uptake of N2O5 at aqueous interfaces can serve as both an efficient NOx removal mechanism and regionally significant halogen activation process through the production of photo-labile ClNO2 molecules. Both the reaction rate and ClNO2 product yield are a complex function of the chemical composition and chloride molarity of the reactive surface. To date, analysis of the impact of N2O5 chemistry on oxidant loadings in the marine boundary layer has been limited to reactions occurring on aerosol particles, with little attention paid to reactions occurring at the air-sea interface. Here, we report the first direct measurements of the air-sea flux of N2O5 and ClNO2 made via eddy covariance in the polluted marine boundary layer in La Jolla, CA. We observe rapid N2O5 deposition to the ocean surface, while ClNO2 deposition rates were significantly lower and fastest during the first three hours following sunset. The results are interpreted using a time-dependent box-model, suggesting that under conditions characterized by shallow marine boundary layer heights (< 100 m) and representative aerosol reactive uptake coefficients (< 0.01), N2O5 deposition to the ocean surface can account for over 50% of the total N2O5 loss rate.

  18. Natural Air-Sea Flux of CO2 in Simulations of the NASA-GISS Climate Model: Sensitivity to the Physical Ocean Model Formulation

    NASA Technical Reports Server (NTRS)

    Romanou, A.; Gregg, Watson W.; Romanski, J.; Kelley, M.; Bleck, R.; Healy, R.; Nazarenko, L.; Russell, G.; Schmidt, G. A.; Sun, S.; Tausnev, N.

    2013-01-01

    Results from twin control simulations of the preindustrial CO2 gas exchange (natural flux of CO2) between the ocean and the atmosphere are presented here using the NASA-GISS climate model, in which the same atmospheric component (modelE2) is coupled to two different ocean models, the Russell ocean model and HYCOM. Both incarnations of the GISS climate model are also coupled to the same ocean biogeochemistry module (NOBM) which estimates prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2. Model intercomparison is carried out at equilibrium conditions and model differences are contrasted with biases from present day climatologies. Although the models agree on the spatial patterns of the air-sea flux of CO2, they disagree on the strength of the North Atlantic and Southern Ocean sinks mainly because of kinematic (winds) and chemistry (pCO2) differences rather than thermodynamic (SST) ones. Biology/chemistry dissimilarities in the models stem from the different parameterizations of advective and diffusive processes, such as overturning, mixing and horizontal tracer advection and to a lesser degree from parameterizations of biogeochemical processes such as gravitational settling and sinking. The global meridional overturning circulation illustrates much of the different behavior of the biological pump in the two models, together with differences in mixed layer depth which are responsible for different SST, DIC and nutrient distributions in the two models and consequently different atmospheric feedbacks (in the wind, net heat and freshwater fluxes into the ocean).

  19. Variability of 14C reservoir age and air-sea flux of CO2 in the Peru-Chile upwelling region during the past 12,000 years

    NASA Astrophysics Data System (ADS)

    Carré, Matthieu; Jackson, Donald; Maldonado, Antonio; Chase, Brian M.; Sachs, Julian P.

    2016-01-01

    The variability of radiocarbon marine reservoir age through time and space limits the accuracy of chronologies in marine paleo-environmental archives. We report here new radiocarbon reservoir ages (ΔR) from the central coast of Chile (~ 32°S) for the Holocene period and compare these values to existing reservoir age reconstructions from southern Peru and northern Chile. Late Holocene ΔR values show little variability from central Chile to Peru. Prior to 6000 cal yr BP, however, ΔR values were markedly increased in southern Peru and northern Chile, while similar or slightly lower-than-modern ΔR values were observed in central Chile. This extended dataset suggests that the early Holocene was characterized by a substantial increase in the latitudinal gradient of marine reservoir age between central and northern Chile. This change in the marine reservoir ages indicates that the early Holocene air-sea flux of CO2 could have been up to five times more intense than in the late Holocene in the Peruvian upwelling, while slightly reduced in central Chile. Our results show that oceanic circulation changes in the Humboldt system during the Holocene have substantially modified the air-sea carbon flux in this region.

  20. Seasonality of Air-sea-ice-land Variables for Arctic Tundra in Northern Eurasia and North America

    NASA Astrophysics Data System (ADS)

    Bhatt, U. S.; Walker, D. A.; Raynolds, M. K.; Steele, M.; Epstein, H.; Jia, G.; Comiso, J. C.; Pinzon, J. E.; Tucker, C. J.

    2009-12-01

    The strength of tundra productivity trends as measured by the annual maximum Normalized Difference Vegetation Index (MaxNDVI) and time integrated NDVI (TI-NDVI) vary around the Arctic over the 1982-2008 period. Our analysis suggests that the timing of terrestrial vegetation growth is connected to seasonal patterns of sea-ice concentrations, ocean temperatures and land surface temperatures. This study used SSMI estimates of sea ice concentration, based on a bootstrap algorithm and AVHRR radiometric surface temperature. Summer Warmth Index (SWI) was calculated as the sum from May to August of the degree months above freezing of surface temperature at each pixel and is an accepted measure of plant growth potential. The Normalized Difference Vegetation Index (NDVI) represents vegetation greenness and has been used extensively to monitor changes in the Arctic. The albedo of green plants varies with solar radiation wavelength, which is the basis for the NDVI index. The analysis was conducted within 50 km of the Arctic coastline to focus on the region of maximum maritime influence. Time series of regional sea-ice concentration, SWI and NDVI were constructed for the 50-km width domains for the Pan-Arctic, North America, Eurasia and Arctic subregions. Standard climate analysis techniques were applied to the regional time series to investigate the seasonality of sea ice, NDVI and SWI. MaxNDVI has increased in the 50-km land domain contiguous to the Beaufort Sea by 17% since 1982, whereas it has only increased by 3% in the coastal Kara Sea region. Analysis of semimonthly MaxNDVI indicates that the vegetation greens up more rapidly in the spring in the Beaufort than the W. Kara and the Kara has slightly higher NDVI in the fall. The climatological weekly sea ice concentrations in 50-km coastal domain displays an earlier breakup in the Beaufort and a later freeze-up in the Kara Sea area. Regional differences in the seasonal cycle can in part explain the spatially varied trends

  1. Extreme air-sea interaction over the North Atlantic subpolar gyre during the winter of 2013-2014 and its sub-surface legacy

    NASA Astrophysics Data System (ADS)

    Grist, Jeremy P.; Josey, Simon A.; Jacobs, Zoe L.; Marsh, Robert; Sinha, Bablu; Van Sebille, Erik

    2016-06-01

    Exceptionally low North American temperatures and record-breaking precipitation over the British Isles during winter 2013-2014 were interconnected by anomalous ocean evaporation over the North Atlantic subpolar gyre region (SPG). This evaporation (or oceanic latent heat release) was accompanied by strong sensible heat loss to the atmosphere. The enhanced heat loss over the SPG was caused by a combination of surface westerly winds from the North American continent and northerly winds from the Nordic Seas region that were colder, drier and stronger than normal. A distinctive feature of the air-sea exchange was that the enhanced heat loss spanned the entire width of the SPG, with evaporation anomalies intensifying in the east while sensible heat flux anomalies were slightly stronger upstream in the west. The immediate impact of the strong air-sea fluxes on the ocean-atmosphere system included a reduction in ocean heat content of the SPG and a shift in basin-scale pathways of ocean heat and atmospheric freshwater transport. Atmospheric reanalysis data and the EN4 ocean data set indicate that a longer-term legacy of the winter has been the enhanced formation of a particularly dense mode of Subpolar Mode Water (SPMW)—one of the precursors of North Atlantic Deep Water and thus an important component of the Atlantic Meridional Overturning Circulation. Using particle trajectory analysis, the likely dispersal of newly-formed SPMW is evaluated, providing evidence for the re-emergence of anomalously cold SPMW in early winter 2014/2015.

  2. Sea-ice melt CO2-carbonate chemistry in the western Arctic Ocean: meltwater contributions to air-sea CO2 gas exchange, mixed layer properties and rates of net community production under sea ice

    NASA Astrophysics Data System (ADS)

    Bates, N. R.; Garley, R.; Frey, K. E.; Shake, K. L.; Mathis, J. T.

    2014-01-01

    The carbon dioxide (CO2)-carbonate chemistry of sea-ice melt and co-located, contemporaneous seawater has rarely been studied in sea ice covered oceans. Here, we describe the CO2-carbonate chemistry of sea-ice melt (both above sea ice as "melt ponds" and below sea ice as "interface waters") and mixed layer properties in the western Arctic Ocean in the early summer of 2010 and 2011. At nineteen stations, the salinity (~ 0.5 to < 6.5), dissolved inorganic carbon (DIC; ~ 20 to < 550 μmol kg-1) and total alkalinity (TA; ~ 30 to < 500 μmol kg-1) of above-ice melt pond water was low compared to water in the underlying mixed layer. The partial pressure of CO2 (pCO2) in these melt ponds was highly variable (~ < 10 to > 1500 μatm) with the majority of melt ponds acting as potentially strong sources of CO2 to the atmosphere. The pH of melt pond waters was also highly variable ranging from mildly acidic (6.1 to 7) to slightly more alkaline than underlying seawater (8 to 10.7). All of observed melt ponds had very low (< 0.1) saturation states (Ω) for calcium carbonate (CaCO3) minerals such as aragonite (Ωaragonite). Our data suggests that sea ice generated "alkaline" or "acidic" melt pond water. This melt-water chemistry dictates whether the ponds are sources of CO2 to the atmosphere or CO2 sinks. Below-ice interface water CO2-carbonate chemistry data also indicated substantial generation of alkalinity, presumably owing to dissolution of calcium CaCO3 in sea ice. The interface waters generally had lower pCO2 and higher pH/Ωaragonite than the co-located mixed layer beneath. Sea-ice melt thus contributed to the suppression of mixed layer pCO2 enhancing the surface ocean's capacity to uptake CO2 from the atmosphere. Meltwater contributions to changes in mixed-layer DIC were also used to estimate net community production rates (mean of 46.9 ±29.8 g C m-2 for the early-season period) under sea-ice cover. Although sea-ice melt is a transient seasonal feature, above-ice melt

  3. Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

    EPA Science Inventory

    Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are...

  4. Error estimations of dry deposition velocities of air pollutants using bulk sea surface temperature under common assumptions

    NASA Astrophysics Data System (ADS)

    Lan, Yung-Yao; Tsuang, Ben-Jei; Keenlyside, Noel; Wang, Shu-Lun; Arthur Chen, Chen-Tung; Wang, Bin-Jye; Liu, Tsun-Hsien

    2010-07-01

    It is well known that skin sea surface temperature (SSST) is different from bulk sea surface temperature (BSST) by a few tenths of a degree Celsius. However, the extent of the error associated with dry deposition (or uptake) estimation by using BSST is not well known. This study tries to conduct such an evaluation using the on-board observation data over the South China Sea in the summers of 2004 and 2006. It was found that when a warm layer occurred, the deposition velocities using BSST were underestimated within the range of 0.8-4.3%, and the absorbed sea surface heat flux was overestimated by 21 W m -2. In contrast, under cool skin only conditions, the deposition velocities using BSST were overestimated within the range of 0.5-2.0%, varying with pollutants and the absorbed sea surface heat flux was underestimated also by 21 W m -2. Scale analysis shows that for a slightly soluble gas (e.g., NO 2, NO and CO), the error in the solubility estimation using BSST is the major source of the error in dry deposition estimation. For a highly soluble gas (e.g., SO 2), the error in the estimation of turbulent heat fluxes and, consequently, aerodynamic resistance and gas-phase film resistance using BSST is the major source of the total error. In contrast, for a medium soluble gas (e.g., O 3 and CO 2) both the errors from the estimations of the solubility and aerodynamic resistance are important. In addition, deposition estimations using various assumptions are discussed. The largest uncertainty is from the parameterizations for chemical enhancement factors. Other important areas of uncertainty include: (1) various parameterizations for gas-transfer velocity; (2) neutral-atmosphere assumption; (3) using BSST as SST, and (4) constant pH value assumption.

  5. Flow mechanism for the long-range transport of air pollutants by the sea breeze causing inland nighttime high oxidants

    SciTech Connect

    Ueda, H.; Mitsumoto, S.; Kurita, H.

    1988-02-01

    Flow mechanism causing nightttime smog was investigated by analyzing 1) continuous records of meteorological data and concentration of oxidants (Ox) for 15 days and 2) aircraft data along the transportation route of a polluted air mass.

  6. Effect of Sea Breeze on Air Pollution in the Greater Athens Area. Part II: Analysis of Different Emission Scenarios.

    NASA Astrophysics Data System (ADS)

    Grossi, Paola; Thunis, Philippe; Martilli, Alberto; Clappier, Alain

    2000-04-01

    The Mediterranean Campaign of Photochemical Tracers-Transport and Chemical Evolution that took place in the greater Athens area from 20 August to 20 September 1994 has confirmed the role of sea-breeze circulation in photochemical smog episodes that had been suggested already by a number of experiments and numerical studies.The meteorological and photochemical modeling of this campaign were discussed in Part I. Part II focuses on the study of the 14 September photochemical smog event associated with a sea-breeze circulation. The objective of the study is to identify and to understand better the nonlinear processes that produce high ozone concentrations. In particular, the effect of land and sea breezes is investigated by isolating the effect of nighttime and daytime emissions on ozone concentrations. The same principle then is used to isolate the effect on ozone concentrations of the two main sources of emissions in the greater Athens area: the industrial area around Elefsis and the Athens urban area. Last, the buildup of ozone from one day to another is investigated.From this study, it comes out that ozone production in the Athens area is mainly a 1-day phenomenon. The increased values of photochemical pollutant (up to 130 ppb at ground level) reached during summertime late afternoons on mountain slopes to the north and northeast of the city are related mainly to the current-day emissions. Nevertheless, the recirculation of old pollutants can have an important effect on ozone concentrations in downtown Athens, the southern part of the peninsula, and over the sea, especially near Aigina Island.

  7. Albedo patterns and gypsum generation in the central Namib Desert - Land, sea and air interactions on an arid West Coast

    NASA Technical Reports Server (NTRS)

    Wilkinson, M. J.; Helms, D. R.; Whitehead, V. S.

    1992-01-01

    In the central Namib Desert, dune-free surfaces are separated abruptly from a sea of yellow and red sand dunes at the Kuiseb River canyon. The off-white hues of the dune-free area result from anomalously high surficial gypsum enrichment. Satellite imagery indicates that the gypsum surfaces are associated with lower surface maximum temperatures than those of the darker dune surfaces to the south. One of various sources of sulfate for the gypsum bodies is oceanic H2S, supplied to desert land-surfaces by regular fog incursions. Since fog events are widespread along the coast, the question of anomalous gypsum accumulations north of the dune sea arises. Satellite imagery, in conjunction with more detailed handheld photography from the space shuttle, indicates that the penetration of fog inland is significantly greater over the gypsum surfaces than it is over the dunes. It is postulated that the thermal gradient between these surfaces generates a heat low centered over the northern part of dune sea and that this enhances fog and H2S advection on its north side onto the nearby dune-free zone. In such a system, gypsum/caliche surfaces reinforce advection of fog over themselves in a positive feedback mode.

  8. Biology and air-sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean

    NASA Astrophysics Data System (ADS)

    Schmittner, A.; Gruber, N.; Mix, A. C.; Key, R. M.; Tagliabue, A.; Westberry, T. K.

    2013-05-01

    Analysis of observations and sensitivity experiments with a new three-dimensional global model of stable carbon isotope cycling elucidate the processes that control the distribution of δ13C in the contemporary and preindustrial ocean. Biological fractionation dominates the distribution of δ13CDIC of dissolved inorganic carbon (DIC) due to the sinking of isotopically light δ13C organic matter from the surface into the interior ocean. This process leads to low δ13CDIC values at dephs and in high latitude surface waters and high values in the upper ocean at low latitudes with maxima in the subtropics. Air-sea gas exchange provides an important secondary influence due to two effects. First, it acts to reduce the spatial gradients created by biology. Second, the associated temperature dependent fractionation tends to increase (decrease) δ13CDIC values of colder (warmer) water, which generates gradients that oppose those arising from biology. Our model results suggest that both effects are similarly important in influencing surface and interior δ13CDIC distributions. However, air-sea gas exchange is slow, so biological effect dominate spatial δ13CDIC gradients both in the interior and at the surface, in constrast to conclusions from some previous studies. Analysis of a new synthesis of δ13CDIC measurements from years 1990 to 2005 is used to quantify preformed (δ13Cpre) and remineralized (δ13Crem) contributions as well as the effects of biology (Δδ13Cbio) and air-sea gas exchange (δ13C*). The model reproduces major features of the observed large-scale distribution of δ13CDIC, δ13Cpre, δ13Crem, δ13C*, and Δδ13Cbio. Residual misfits are documented and analyzed. Simulated surface and subsurface δ13CDIC are influenced by details of the ecosystem model formulation. For example, inclusion of a simple parameterization of iron limitation of phytoplankton growth rates and temperature-dependent zooplankton grazing rates improves the agreement with δ13CDIC

  9. Spatiotemporal variability and drivers of pCO2 and air-sea CO2 fluxes in the California Current System: an eddy-resolving modeling study

    NASA Astrophysics Data System (ADS)

    Turi, G.; Lachkar, Z.; Gruber, N.

    2014-02-01

    We quantify the CO2 source/sink nature of the California Current System (CalCS) and determine the drivers and processes behind the mean and spatiotemporal variability of the partial pressure of CO2 (pCO2) in the surface ocean. To this end, we analyze eddy-resolving, climatological simulations of a coupled physical-biogeochemical oceanic model on the basis of the Regional Oceanic Modeling System (ROMS). In the annual mean, the entire CalCS within 800 km of the coast and from ∼33° N to 46° N is essentially neutral with regard to atmospheric CO2: the model simulates an integrated uptake flux of -0.9 ± 3.6 Tg C yr-1, corresponding to an average flux density of -0.05 ± 0.20 mol C m-2 yr-1. This near zero flux is a consequence of an almost complete regional compensation between (i) strong outgassing in the nearshore region (first 100 km) that brings waters with high concentrations of dissolved inorganic carbon (DIC) to the surface and (ii) and a weaker, but more widespread uptake flux in the offshore region due to an intense biological reduction of this DIC, driven by the nutrients that are upwelled together with the DIC. The air-sea CO2 fluxes vary substantially in time, both on seasonal and sub-seasonal timescales, largely driven by variations in surface ocean pCO2. Most of the variability in pCO2 is associated with the seasonal cycle, with the exception of the nearshore region, where sub-seasonal variations driven by mesoscale processes dominate. In the regions offshore of 100 km, changes in surface temperature are the main driver, while in the nearshore region, changes in surface temperature, as well as anomalies in DIC and alkalinity (Alk) owing to changes in circulation, biological productivity and air-sea CO2 fluxes dominate. The prevalence of eddy-driven variability in the nearshore 100 km leads to a complex spatiotemporal mosaic of surface ocean pCO2 and air-sea CO2 fluxes that require a substantial observational effort to determine the source

  10. Multiyear ice transport and small scale sea ice deformation near the Alaska coast measured by air-deployable Ice Trackers

    NASA Astrophysics Data System (ADS)

    Mahoney, A. R.; Kasper, J.; Winsor, P.

    2015-12-01

    Highly complex patterns of ice motion and deformation were captured by fifteen satellite-telemetered GPS buoys (known as Ice Trackers) deployed near Barrow, Alaska, in spring 2015. Two pentagonal clusters of buoys were deployed on pack ice by helicopter in the Beaufort Sea between 20 and 80 km offshore. During deployment, ice motion in the study region was effectively zero, but two days later the buoys captured a rapid transport event in which multiyear ice from the Beaufort Sea was flushed into the Chukchi Sea. During this event, westward ice motion began in the Chukchi Sea and propagated eastward. This created new openings in the ice and led to rapid elongation of the clusters as the westernmost buoys accelerated away from their neighbors to the east. The buoys tracked ice velocities of over 1.5 ms-1, with fastest motion occurring closest to the coast indicating strong current shear. Three days later, ice motion reversed and the two clusters became intermingled, rendering divergence calculations based on the area enclosed by clusters invalid. The data show no detectable difference in velocity between first year and multiyear ice floes, but Lagrangian timeseries of SAR imagery centered on each buoy show that first year ice underwent significant small-scale deformation during the event. The five remaining buoys were deployed by local residents on prominent ridges embedded in the landfast ice within 16 km of Barrow in order to track the fate of such features after they detached from the coast. Break-up of the landfast ice took place over a period of several days and, although the buoys each initially followed a similar eastward trajectory around Point Barrow into the Beaufort Sea, they rapidly dispersed over an area more than 50 km across. With rapid environmental and socio-economic change in the Arctic, understanding the complexity of nearshore ice motion is increasingly important for predict future changes in the ice and the tracking ice-related hazards

  11. A cold air outbreak over the Norwegian Sea observed with the Tiros-N Operational Vertical Sounder (TOVS) and the Special Sensor Microwave/Imager (SSM/I)

    NASA Technical Reports Server (NTRS)

    Claud, Chantal; Katsaros, Kristina B.; Petty, Grant W.; Chedin, Alain; Scott, Noelle A.

    1992-01-01

    Until recently, the scarcity of meteorological observations over polar areas has limited studies of high-latitude weather systems, but now data from polar orbiting satellites offer a new opportunity to observe and describe these systems. TOVS data have been used successfully for delineating synoptic and subsynoptic systems, since they provide the vertical temperature structure of the atmosphere; SSM/I observations have proved valuable for analyzing storms through water vapor and rain determinations. These positive results prompted simultaneous analysis of TOVS and SSM/I observations obtained during a cold air outbreak over the Norwegian Sea. After a description of the instruments and the retrieval schemes, the mutually supporting information from these two independent instruments is discussed. Implications for the monitoring of polar lows are presented.

  12. A cold air outbreak over the Norwegian Sea observed with the Tiros-N Operational Vertical Sounder (TOVS) and the Special Sensor Microwave/Imager (SSM/I)

    NASA Technical Reports Server (NTRS)

    Claud, Chantal; Katsaros, Kristina B.; Petty, Grant W.; Chedin, Alain; Scott, Noelle A.

    1992-01-01

    Until recently, the scarcity of meteorological observations over polar areas has limited studies of high latitude weather systems, but now data from polar orbiting satellites offer a new opportunity to observe and describe these systems. TOVS data were used successfully for delineating synoptic and subsynoptic systems since they provide the vertical temperature structure of the atmosphere: SSM/I observations have proved valuable for analyzing storms through water vapor and rain determinations. These positive results prompted us to analyze simultaneous TOVS and SSM/I observations obtained during a cold air outbreak over the Norwegian Sea. After a description of the instruments and the retrieval schemes, the mutually supporting information from these two independent instruments is discussed. Implications for the monitoring of polar lows are presented.

  13. Blast94: Bromine latitudinal air/sea transect 1994. Report on oceanic measurements of methyl bromide and other compounds. Technical memo

    SciTech Connect

    Lobert, J.M.; Butler, J.H.; Geller, L.S.; Yvon, S.A.; Montzka, S.A.

    1996-02-01

    Methyl bromide (CH3Br) is of particular interest because it is both produced and consumed in the ocean, thus allowing the ocean to act as a buffer for CH3Br in the atmosphere. The main objective of the two NOAA/CMDL Bromine Latitudinal Air/Sea Transect Expeditions has been to resolve the discrepancy in previously reported data for oceanic CH3Br, and to extend the understanding of the distribution and cycling of CH3Br between the atmosphere and ocean. This was pursued by making frequent, shipboard measurements of CH3Br in the surface water and the marine atmosphere along the cruise tracks and by obtaining depth profiles of CH3Br at selected stations. Secondary objectives included obtaining atmospheric and surface water data for other methyl halides, most notably CH3Cl, CH3I, CH2Br2, and CHBr3.

  14. Southern Ocean air-sea heat flux, SST spatial anomalies, and implications for multi-decadal upper ocean heat content trends.

    NASA Astrophysics Data System (ADS)

    Tamsitt, V. M.; Talley, L. D.; Mazloff, M. R.

    2014-12-01

    The Southern Ocean displays a zonal dipole (wavenumber one) pattern in sea surface temperature (SST), with a cool zonal anomaly in the Atlantic and Indian sectors and a warm zonal anomaly in the Pacific sector, associated with the large northward excursion of the Malvinas and southeastward flow of the Antarctic Circumpolar Current (ACC). To the north of the cool Indian sector is the warm, narrow Agulhas Return Current (ARC). Air-sea heat flux is largely the inverse of this SST pattern, with ocean heat gain in the Atlantic/Indian, cooling in the southeastward-flowing ARC, and cooling in the Pacific, based on adjusted fluxes from the Southern Ocean State Estimate (SOSE), a ⅙° eddy permitting model constrained to all available in situ data. This heat flux pattern is dominated by turbulent heat loss from the ocean (latent and sensible), proportional to perturbations in the difference between SST and surface air temperature, which are maintained by ocean advection. Locally in the Indian sector, intense heat loss along the ARC is contrasted by ocean heat gain of 0.11 PW south of the ARC. The IPCC AR5 50 year depth-averaged 0-700 m temperature trend shows surprising similarities in its spatial pattern, with upper ocean warming in the ARC contrasted by cooling to the south. Using diagnosed heat budget terms from the most recent (June 2014) 6-year run of the SOSE we find that surface cooling in the ARC is balanced by heating from south-eastward advection by the current whereas heat gain in the ACC is balanced by cooling due to northward Ekman transport driven by strong westerly winds. These results suggest that spatial patterns in multi-decadal upper ocean temperature trends depend on regional variations in upper ocean dynamics.

  15. Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

    NASA Technical Reports Server (NTRS)

    Signorini, Sergio; Mannino, Antonio; Najjar, Raymond G., Jr.; Friedrichs, Marjorie A. M.; Cai, Wei-Jun; Salisbury, Joe; Wang, Zhaohui Aleck; Thomas, Helmuth; Shadwick, Elizabeth

    2013-01-01

    Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.

  16. The role of sea-salt emissions and heterogeneous chemistry in the air quality of polluted coastal areas

    NASA Astrophysics Data System (ADS)

    Athanasopoulou, E.; Tombrou, M.; Pandis, S. N.; Russell, A. G.

    2008-02-01

    Open-ocean and surf-zone sea-salt aerosol (SSA) emissions algorithms are incorporated in the CAMx aerosol model and applied over an area with an extended Archipelago (Greece), with a fine grid nested over the highly populated Attica peninsula. The maximum indirect impact of SSA on PM10 mass (35%) is located over a marine area with moderate SSA production and elevated shipping emissions (central Aegean Sea) where SSA interacts with anthropogenic nitric acid forming sodium nitrate. SSA increases PM10 levels in the Athens city center up to 27% during stable onshore winds. Under such conditions both open-ocean and surf-zone mechanisms contribute to aerosol production over Attica. A hybrid scheme for gas-to-particle mass transfer is necessary for accurately simulating semi-volatile aerosol components when coarse SSA is included. Dynamically simulating mass transfer to the coarse particles leads to a quadrupling of predicted PM10 nitrate in the Athens city center and up to two orders of magnitude in its coarse mass in comparison to using a bulk equilibrium approach.

  17. The role of sea-salt emissions and heterogeneous chemistry in the air quality of polluted coastal areas

    NASA Astrophysics Data System (ADS)

    Athanasopoulou, E.; Tombrou, M.; Pandis, S. N.; Russell, A. G.

    2008-10-01

    Open-ocean and surf-zone sea-salt aerosol (SSA) emission parameterizations are incorporated in the CAMx aerosol model and applied over an area with an extended Archipelago (Greece), with a fine grid nested over the highly populated Attica peninsula. The maximum indirect impact of SSA on PM10 mass (35%) is located over a marine area with moderate SSA production and elevated shipping emissions (central Aegean Sea) where SSA interacts with anthropogenic nitric acid forming sodium nitrate. SSA increases PM10 levels in the Athens city center up to 25% during stable onshore winds. Under such conditions both open-ocean and surf-zone mechanisms contribute to aerosol production over Attica. A hybrid scheme for gas-to-particle mass transfer is necessary for accurately simulating semi-volatile aerosol components when coarse SSA is included. Dynamically simulating mass transfer to the coarse particles leads to a quadrupling of predicted PM10 nitrate in the Athens city center and up to two orders of magnitude in its coarse mass in comparison to using a bulk equilibrium approach.

  18. On the calculation of air-sea fluxes of CO2 in the presence of temperature and salinity gradients

    NASA Astrophysics Data System (ADS)

    Woolf, D. K.; Land, P. E.; Shutler, J. D.; Goddijn-Murphy, L. M.; Donlon, C. J.

    2016-02-01

    The presence of vertical temperature and salinity gradients in the upper ocean and the occurrence of variations in temperature and salinity on time scales from hours to many years complicate the calculation of the flux of carbon dioxide (CO2) across the sea surface. Temperature and salinity affect the interfacial concentration of aqueous CO2 primarily through their effect on solubility with lesser effects related to saturated vapor pressure and the relationship between fugacity and partial pressure. The effects of temperature and salinity profiles in the water column and changes in the aqueous concentration act primarily through the partitioning of the carbonate system. Climatological calculations of flux require attention to variability in the upper ocean and to the limited validity of assuming "constant chemistry" in transforming measurements to climatological values. Contrary to some recent analysis, it is shown that the effect on CO2 fluxes of a cool skin on the sea surface is large and ubiquitous. An opposing effect on calculated fluxes is related to the occurrence of warm layers near the surface; this effect can be locally large but will usually coincide with periods of low exchange. A salty skin and salinity anomalies in the upper ocean also affect CO2 flux calculations, though these haline effects are generally weaker than the thermal effects.

  19. Roles of biological and physical processes in driving seasonal air-sea CO2 flux in the Southern Ocean: New insights from CARIOCA pCO2

    NASA Astrophysics Data System (ADS)

    Merlivat, L.; Boutin, J.; Antoine, D.

    2015-07-01

    On a mean annual basis, the Southern Ocean is a sink for atmospheric CO2. However the seasonality of the air-sea CO2 flux in this region is poorly documented. We investigate processes regulating air-sea CO2 flux in a large area of the Southern Ocean (38°S-55°S, 60°W-60°E) that represents nearly one third of the subantarctic zone. A seasonal budget of CO2 partial pressure, pCO2 and of dissolved inorganic carbon, DIC in the mixed layer is assessed by quantifying the impacts of biology, physics and thermodynamical effect on seawater pCO2. A focus is made on the quantification at a monthly scale of the biological consumption as it is the dominant process removing carbon from surface waters. In situ biological carbon production rates are estimated from high frequency estimates of DIC along the trajectories of CARIOCA drifters in the Atlantic and Indian sector of the Southern Ocean during four spring-summer seasons over the 2006-2009 period. Net community production (NCP) integrated over the mixed layer is derived from the daily change of DIC, and mixed layer depth estimated from Argo profiles. Eleven values of NCP are estimated and range from 30 to 130 mmol C m- 2 d- 1. They are used as a constraint for validating satellite net primary production (NPP). A satellite data-based global model is used to compute depth integrated net primary production, NPP, for the same periods along the trajectories of the buoys. Realistic NCP/NPP ratios are obtained under the condition that the SeaWiFS chlorophyll are corrected by a factor of ≈ 2-3, which is an underestimation previously reported for the Southern Ocean. Monthly satellite based NPP are computed over the 38°S-55°S, 60°W-60°E area. pCO2 derived from these NPP combined with an export ratio, and taking into account the impact of physics and thermodynamics is in good agreement with the pCO2 seasonal climatology of Takahashi (2009). On an annual timescale, mean NCP values, 4.4 to 4.9 mol C m- 2 yr- 1 are ≈ 4-5 times

  20. Experimental study of the structure of isotropic turbulence with intermediate range of Reynolds number. [sea-air interaction

    NASA Technical Reports Server (NTRS)

    Ling, S. C.; Saad, A.

    1977-01-01

    The energetic isotropic turbulence generated by a waterfall of low head was found to be developed in part through the unstable two-phase flow of entrained air bubbles. The resulting turbulent field had a turbulent Reynolds number in excess of 20,000 and maintained a self-similar structure throughout the decay period studied. The present study may provide some insight into the structure of turbulence produced by breaking waves over the ocean.

  1. Sea spray production by bag breakup mode of fragmentation of the air-water interface at strong and hurricane wind

    NASA Astrophysics Data System (ADS)

    Troitskaya, Yuliya; Kandaurov, Alexander; Ermakova, Olga; Kozlov, Dmitry; Sergeev, Daniil; Zilitinkevich, Sergej

    2016-04-01

    Sea sprays is a typical element of the marine atmospheric boundary layer (MABL) of large importance for marine meteorology, atmospheric chemistry and climate studies. They are considered as a crucial factor in the development of hurricanes and severe extratropical storms, since they can significantly enhance exchange of mass, heat and momentum between the ocean and the atmosphere. This exchange is directly provided by spume droplets with the sizes from 10 microns to a few millimeters mechanically torn off the crests of a breaking waves and fall down to the ocean due to gravity. The fluxes associated with the spray are determined by the rate of droplet production at the surface quantified by the sea spray generation function (SSGF), defined as the number of spray particles of radius r produced from the unit area of water surface in unit time. However, the mechanism of spume droplets' formation is unknown and empirical estimates of SSGF varied over six orders of magnitude; therefore, the production rate of large sea spray droplets is not adequately described and there are significant uncertainties in estimations of exchange processes in hurricanes. Experimental core of our work comprise laboratory experiments employing high-speed video-filming, which have made it possible to disclose how water surface looks like at extremely strong winds and how exactly droplets are torn off wave crests. We classified events responsible for spume droplet, including bursting of submerged bubbles, generation and breakup of "projections" or liquid filaments (Koa, 1981) and "bag breakup", namely, inflating and consequent blowing of short-lived, sail-like pieces of the water-surface film, "bags". The process is similar to "bag-breakup" mode of fragmentation of liquid droplets and jets in gaseous flows. Basing on statistical analysis of results of these experiments we show that the main mechanism of spray-generation is attributed to "bag-breakup mechanism On the base of general principles

  2. Sea to land transfer of anthropogenic radionuclides to the North Wales coast, Part I: external gamma radiation and radionuclide concentrations in intertidal sediments, soil and air.

    PubMed

    Bryan, S E; McDonald, P; Hill, R; Wilson, R C

    2008-01-01

    Previous projects specifically aimed at performing radiological assessments in the vicinity of North Wales, investigating the presence and transfer of radionuclides from sea to land, were in 1986 and 1989. Since then, changes have occurred in the radioactive discharges from the British Nuclear Group Sellafield site. Annual discharges of (137)Cs, (238)Pu, (239,340)Pu and (241)Am have decreased markedly whereas, up until recent years, discharges of (99)Tc have increased. It is therefore desirable to quantify current transfer processes of radionuclides in the North Wales region and thus provide an update on 15-year-old studies. A field campaign was conducted collecting soil samples from 10 inland transects and air particulates on air filters from three High Volume Air Samplers, along the northern coast of Wales at Amlwch, Bangor Pier and Flint. Complementary field data relating to external gamma dose rates were collected at the soil sites. The field data generated for (137)Cs, (238)Pu, (239,340)Pu and (241)Am were consistent with what had been reported 15 years previously. Therefore, there has been no increase in the supply of these Sellafield-derived radionuclides to the terrestrial environment of the North Wales coast. The (99)Tc data in sediments were consistent with reported values within annual monitoring programmes, however, a relatively high activity concentration was measured in one sediment sample. This site was further investigated to determine the reason why such a high value was found. At present there is no clear evidence as to why this elevated concentration should be present, but the role of seaweed and its capacity in accumulating (99)Tc and transferring it to sediment is of interest. The analysis of the field samples for (99)Tc, (137)Cs, (238)Pu, (239,240)Pu and (241)Am has provided a data set that can be used for the modelling of the transfer of anthropogenic radionuclides from sea to land and its subsequent radiological implications and is reported

  3. Comparison of two different sea-salt aerosol schemes as implemented in air quality models applied to the Mediterranean Basin

    NASA Astrophysics Data System (ADS)

    Jimenez-Guerrero, P.; Jorba, O.; Pay, M. T.; Montavez, J. P.; Jerez, S.; Gomez-Navarro, J. J.; Baldasano, J. M.

    2010-12-01

    A number of attempts have been made to incorporate sea-salt aerosols (SSA) source functions in chemistry transport models with varying results according to the complexity of the scheme considered. This contribution compares the inclusion of two different SSA algorithms in two chemistry transport models: CMAQ and CHIMERE. The main goal is to examine the differences in average SSA mass and composition and to study the seasonality of the prediction of SSA when applied to the Mediterranean area with high resolution in a reference year. Dry and wet deposition schemes are also analyzed to better understand the differences observed between both models in the target area. The applied emission algorithm in CHIMERE uses a semi-empirical formulation which obtains the surface emission rate of SSA as a function of the surface wind speed cubed and particle size. The emission parameterization included within CMAQ is somehow more sophisticated, since fluxes of SSA are corrected with relative humidity. In order to evaluate their strengths and weaknesses, the participating algorithms as implemented in the chemistry transport models were evaluated against AOD measurements from Aeronet and available surface measurements in Southern Europe and the Mediterranean area, showing biases around -0.003 and -1.2 μg m-3, respectively. The results indicate that both models represent accurately the patterns and dynamics of SSA and its non-uniform behavior in the Mediterranean basin, showing a strong seasonality. The levels of SSA vary strongly across the Western and the Eastern Mediterranean, reproducing CHIMERE higher annual levels in the Aegean Sea (12 μg m-3) and CMAQ in the Gulf of Lion (9 μg m-3). The large difference found for the ratio PM2.5/total SSA in CMAQ and CHIMERE is also investigated. The dry and wet removal rates are very similar for both models despite the different schemes implemented. Dry deposition essentially follows the surface drag stress patterns, meanwhile wet

  4. Comparison of two different sea-salt aerosol schemes as implemented in air quality models applied to the Mediterranean Basin

    NASA Astrophysics Data System (ADS)

    Jiménez-Guerrero, P.; Jorba, O.; Pay, M. T.; Montávez, J. P.; Jerez, S.; Gómez-Navarro, J. J.; Baldasano, J. M.

    2011-05-01

    A number of attempts have been made to incorporate sea-salt aerosol (SSA) source functions in chemistry transport models with varying results according to the complexity of the scheme considered. This contribution compares the inclusion of two different SSA algorithms in two chemistry transport models: CMAQ and CHIMERE. The main goal is to examine the differences in average SSA mass and composition and to study the seasonality of the prediction of SSA when applied to the Mediterranean area with high resolution for a reference year. Dry and wet deposition schemes are also analyzed to better understand the differences observed between both models in the target area. The applied emission algorithm in CHIMERE uses a semi-empirical formulation which obtains the surface emission rate of SSA as a function of the particle size and the surface wind speed raised to the power 3.41. The emission parameterization included within CMAQ is somehow more sophisticated, since fluxes of SSA are corrected with relative humidity. In order to evaluate their strengths and weaknesses, the participating algorithms as implemented in the chemistry transport models were evaluated against AOD measurements from Aeronet and available surface measurements in Southern Europe and the Mediterranean area, showing biases around -0.002 and -1.2 μg m-3, respectively. The results indicate that both models represent accurately the patterns and dynamics of SSA and its non-uniform behavior in the Mediterranean basin, showing a strong seasonality. The levels of SSA strongly vary across the Western and the Eastern Mediterranean, reproducing CHIMERE higher annual levels in the Aegean Sea (12 μg m-3) and CMAQ in the Gulf of Lion (9 μg m-3). The large difference found for the ratio PM2.5/total SSA in CMAQ and CHIMERE is also investigated. The dry and wet removal rates are very similar for both models despite the different schemes implemented. Dry deposition essentially follows the surface drag stress patterns

  5. Assessing the Potential to Derive Air-Sea Freshwater Fluxes from Aquarius-Like Observations of Surface Salinity

    NASA Technical Reports Server (NTRS)

    Zhen, Li; Adamec, David

    2009-01-01

    A state-of-the-art numerical model is used to investigate the possibility of determining freshwater flux fields from temporal changes io sea-surface salinity (SSS), a goal of the satellite salinity-measuring mission, Aquarius/SAC-D. Because the estimated advective temporal scale is usually longer than the Aquarius/SAC-D revisit time, the possibility of producing freshwater flux estimates from temporal salinity changes is first examined by using a correlation analysis. For the mean seasonal cycle, the patterns of the correlations between the freshwater fluxes and surface salinity temporal tendencies are mainly zonally oriented, and are highest where the local precipitation is also relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude moon tracks and are relatively small in the tropics. The complex correlation patterns presented here suggest that a global retrieval of the difference between evaporation and precipitation (E-P) from salinity changes requires more complex techniques than a simple consideration of local balance with surface forcing.

  6. Effects of the air-sea coupling time frequency on the ocean response during Mediterranean intense events

    NASA Astrophysics Data System (ADS)

    Lebeaupin Brossier, Cindy; Ducrocq, Véronique; Giordani, Hervé

    2009-08-01

    The near-sea surface meteorological conditions associated with the Mediterranean heavy precipitation events constitute, on a short time scale, a strong forcing on the ocean mixed layer. This study addresses the question of the optimal time frequency of the atmospheric forcing to drive an ocean model in order to make it able to capture the fine scale ocean mixed layer response to severe meteorological conditions. The coupling time frequency should allow the ocean model to reproduce the formation of internal low-salty boundary layers due to sudden input of intense precipitation, as well as the cooling and deepening of the ocean mixed layer through large latent heat fluxes and stress under the intense low-level jet associated with these events. In this study, the one-dimensional ocean model is driven by 2.4-km atmospheric simulated fields on a case of Mediterranean heavy precipitation, varying the time resolution of the atmospheric forcing. The results show that using a finer temporal resolution than 1 h for the atmospheric forcing is not necessary, but a coarser temporal resolution (3 or 6 h) modifies the event course and intensity perceived by the ocean. Consequently, when using a too coarse temporal resolution forcing, typically 6 h, the ocean model fails to reproduce the ocean mixed layer fine scale response under the heavy rainfall pulses and the strong wind gusts.

  7. The Relation between Indian Monsoon Rainfall, the Southern Oscillation, and Hemispheric Air and Sea Temperature: 1884-1984.

    NASA Astrophysics Data System (ADS)

    Elliott, W. P.; Angell, J. K.

    1987-08-01

    Correlations between the June-September Indian monsoon rainfall and Santiago minus Darwin pressure, Tahiti minus Darwin pressure, and Wright's Southern Oscillation index, as well as the individual station pressure deviations themselves, show that the monsoon rainfall anticipates the Southern Oscillation Indices and the individual pressure deviations with the exception of the pressure at Santiago. Monsoon rainfall is also negatively correlated with sea surface temperatures in the eastern equatorial Pacific one to two seasons later. The correlations suggest that above average monsoon rainfall is associated with below average Southern Hemisphere temperatures two to three seasons later, whereas above average Northern Hemisphere winter temperatures-particularly continental temperatures-anticipate above average rainfall. The correlations with hemispheric temperatures are significant only since about 1947, however. A strong negative correlation (0.64) between the seasonal change in Darwin's pressure deviation from December-February to March-May prior to the monsoon, and monsoon rainfall is found in the period 1947-84, but only weakly in the period before 1947.

  8. Carbon isotopic disequilibrium between seawater and air in the coastal Northern South China Sea over the past century

    NASA Astrophysics Data System (ADS)

    Xu, Shendong; Jia, Guodong; Deng, Wenfeng; Wei, Gangjian; Chen, Weifang; Huh, Chih-An

    2014-08-01

    Six coastal sediment cores collected from the Northern South China Sea were dated by 210Pb and analyzed for stable carbon and oxygen isotope composition of planktonic foraminifer Globigerinoides ruber (δ13CGr and δ18OGr). Three of these cores were located east of Hainan Island and the other three off the Pearl River Estuary (PRE). Surface seawater δ18O and dissolved inorganic carbon (DIC) δ13C were identified as the dominant factors controlling downcore variations of δ18OGr and δ13CGr, respectively. Results of δ13CGr were then used to study surface water δ13CDIC and its relation to δ13C of atmospheric CO2 (δ13Catm) over the past century. Downcore records showed rather constant δ13CGr in cores off Hainan Island, but moderate decreases of δ13CGr, at rates between -0.006‰ and -0.009‰ per year, in cores off the PRE. Isotopic disequilibrium between δ13CDIC and δ13Catm was observed, with δ13CDIC apparently higher than expected at equilibrium with δ13Catm except at the site closest to the PRE. The relatively steady δ13CGr values east of Hainan Island were explained by balanced vertical mixing and biological pump, whereas the moderate δ13CGr decreases with time off the PRE were attributable to fluvial input of terrestrial carbon.

  9. Tropical cyclogenesis in Eastern Atlantique: Impact of earlier passage of African Easterly Wave trough on the evolution of Mesoscale Convective Systems and air-sea interaction

    NASA Astrophysics Data System (ADS)

    Lahat Dieng, Abdou; Eymard, Laurence; Moustapha Sall, Saidou; Lazar, Alban; Leduc-Leballeur, Marion

    2014-05-01

    A large part of Atlantic tropical depressions is generated in the Eastern basin in relation with the African Easterly Waves and the Mesoscale Convective Systems coming from the African continent. But initial surface oceanic and atmosphere conditions favoring such evolution are largely unknown. This study analyzes the structures of strengthening and dissipating MCSs evolving near the West African coast and evaluates the role of the surface oceanic condition on their evolutions. Satellite brightness temperature from Meteosat Second Generation over the summer season of 2006 and radar data for the same season between 1993 and 1999 are used to subjectively select fourteen cases of strengthening (dissipating) MCSs when they cross the Senegalese coast. With these observed MCSs locations, a lagged composite analysis is then performed using Era interim and CFSR reanalyses. Results show that the strengthening MCS composite is preceded by prior passage of an AEW near the West African coast. This first trough wave was associated with a cyclonic circulation in the low and middle troposphere and has enhanced southwest wind flow behind him feeding humidly to the strengthening MCS composite which was located in the vicinity of the second AEW trough. The contraction of the wave length associated with the two troughs was probably facilitated this supply in humidity. The Sea Surface Temperature seem contribute to the MCS enhancement through surface evaporation flux but this contribution is less important than humidity advection by the fist system. These conditions were not found in the dissipating MCS case which dissipated in a drying environment air dominated by subsidence and anticyclonic circulation. Key words: Mesoscale Convective System, African Easterly Wave, Sea Surface Temperature, tropical depression.

  10. Spatiotemporal variability and drivers of pCO2 and air-sea CO2 fluxes in the California Current System: an eddy-resolving modeling study

    NASA Astrophysics Data System (ADS)

    Turi, G.; Lachkar, Z.; Gruber, N.

    2013-08-01

    nutrient concentrations of the upwelled waters a primary determinant of the overall source/sink nature of the CalCS. The comparison of the standard simulation with one for preindustrial conditions show that the CalCS is taking up anthropogenic CO2 at a rate of about -1 mol C m-2 yr-1, implying that the region was a small source of CO2 to the atmosphere in preindustrial times. The air-sea CO2 fluxes vary substantially in time, both on seasonal and sub-seasonal timescales, largely driven by variations in surface ocean pCO2. There are important differences among the subregions. Notably, the total variance of the fluxes in the central nearshore CalCS is roughly 4-5 times larger than elsewhere. Most of the variability in pCO2 is associated with the seasonal cycle, except in the nearshore, where sub-seasonal variations driven by mesoscale processes dominate. In the regions offshore of 100 km, changes in surface temperature are the main driver, while in the nearshore region, changes in surface temperature, as well as anomalies in DIC and alkalinity (Alk) owing to changes in circulation, biological productivity and air-sea CO2 fluxes dominate. The dominance of eddy-driven variability in the nearshore 100 km leads to a complex spatiotemporal mosaic of surface ocean pCO2 and air-sea CO2 fluxes that require a substantial observational effort to determine the source/sink nature of this region reliably.

  11. Air sea gas transfer velocity estimates from the Jason-1 and TOPEX altimeters: Prospects for a long-term global time series

    NASA Astrophysics Data System (ADS)

    Glover, David M.; Frew, Nelson M.; McCue, Scott J.

    2007-06-01

    Estimation of global and regional air-sea fluxes of climatically important gases is a key goal of current climate research programs. Gas transfer velocities needed to compute these fluxes can be estimated by combining altimeter-derived mean square slope with an empirical relation between transfer velocity and mean square slope derived from field measurements of gas fluxes and small-scale wave spectra [Frew, N.M., Bock, E.J., Schimpf, U., Hara, T., Hauβecker, H., Edson, J.B., McGillis, W.R., Nelson, R.K., McKenna, S.P., Uz, B.M., Jähne, B., 2004. Air-sea gas transfer: Its dependence on wind stress, small-scale roughness and surface films, J. Geophys. Res., 109, C08S17, doi: 10.1029/2003JC002131.]. We previously reported initial results from a dual-frequency (Ku- and C-band) altimeter algorithm [Glover, D.M., Frew, N.M., McCue, S.J., Bock, E.J., 2002. A Multi-year Time Series of Global Gas Transfer Velocity from the TOPEX Dual Frequency, Normalized Radar Backscatter Algorithm, In: Gas Transfer at Water Surfaces, editors: Donelan, M., Drennan, W., Saltzman, E., and Wanninkhof, R., Geophysical Monograph 127, American Geophysical Union, Washington, DC, 325-331.] for estimating the air-sea gas transfer velocity ( k) from the mean square slope of short wind waves (40-100 rad/m) and derived a 6-year time series of global transfer velocities based on TOPEX observations. Since the launch of the follow-on altimeter Jason-1 in December 2001 and commencement of the TOPEX/Jason-1 Tandem Mission, we have extended this time series to 12 years, with improvements to the model parameters used in our algorithm and using the latest corrected data releases. The prospect of deriving multi-year and interdecadal time series of gas transfer velocity from TOPEX, Jason-1 and follow-on altimeter missions depends on precise intercalibration of the normalized backscatter. During the Tandem Mission collinear phase, both satellites followed identical orbits with a mere 73-s time separation. The

  12. High concentration episodes of PM10 in the air over the urbanized coastal zone of the Baltic Sea (Gdynia — Poland)

    NASA Astrophysics Data System (ADS)

    Lewandowska, Anita Urszula; Falkowska, Lucyna Mirosława

    2013-02-01

    During the years 2008-2009, studies were conducted on PM10 in the atmosphere over Gdynia. The basic chemical composition of PM10 aerosols (inorganic species, organic and elemental carbon) was measured during periods of heightened health risk. As the quality of air depends on natural as well as anthropogenic factors, it was important to specify which of these factors prevail under different synoptic conditions and at different times, and which have the greatest influence on human health. In the course of the 24-month research period, the daily PM10 limit value (50 μg·m- 3) in the coastal zone of the Gulf of Gdansk, was exceeded 25 times. High concentration episodes invariably occurred in the cold months of the year. The first kind of episode was related to sea activity and the highest share of sea salt in aerosols (NaCl = 46.5%). A second type of high PM10 concentration occurred at south-eastern advection when secondary aerosols, aging on the way from the source, were carried over Gdynia. In the spring of 2009, as a result of biomass combustion (fires and grass burning) in Ukraine and Southern Russia, the PM10 mass concentration climbed to 117.1 μg·m- 3 and was accompanied by substantial increases in nitrogen, sulfur and carbon compounds (reaching 32.5 μg·m- 3, 20.0 μg·m- 3, and 6.0 μg·m- 3, respectively). The third kind of high PM10 concentration was related to local sources, mostly within the communal sector, the harbor area and the transshipment base, and was the consequence of low dispersion of pollution at a wind speed of 1 m·s- 1. At such times there was a rapid increase of carbon compound concentrations (53.8%). Elemental carbon, an air pollution indicator which originates from means of transport, had the highest proportion in such instances, reaching 15.8% of the total PM10 mass concentration.

  13. What can we learn about ship emission inventories from measurements of air pollutants over the Mediterranean Sea?

    NASA Astrophysics Data System (ADS)

    Marmer, E.; Dentener, F.; Aardenne, J. V.; Cavalli, F.; Vignati, E.; Velchev, K.; Hjorth, J.; Boersma, F.; Vinken, G.; Mihalopoulos, N.; Raes, F.

    2009-09-01

    Ship emission estimates diverge widely for all chemical compounds for several reasons: use of different methodologies (bottom-up or top-down), activity data and emission factors can easily result in a difference ranging from a factor of 1.5 to even an order of magnitude. Combining three sets of observational data - ozone and black carbon measurements sampled at three coastal sites and on board of a Mediterranean cruise ship, as well as satellite observations of atmospheric NO2 column concentration over the same area - we assess the accuracy of the three most commonly used ship emission inventories, EDGAR FT (Olivier et al., 2005), emissions described by Eyring et al. (2005) and emissions reported by EMEP (Vestreng et al., 2007). Our tool is a global atmospheric chemistry transport model which simulates the chemical state of the Mediterranean atmosphere applying different ship emission inventories. The simulated contributions of ships to air pollutant levels in the Mediterranean atmosphere are significant but strongly depend on the inventory applied. Close to the major shipping routes relative contributions vary from 10 to 50% for black carbon and from 2 to 12% for ozone in the surface layer, as well as from 5 to 20% for nitrogen dioxide atmospheric column burden. The relative contributions are still significant over the North African coast, but less so over the South European coast because densely populated regions with significant human activity contribute relatively more to air pollution than ships, even if these regions attract a lot of ship traffic. The observations poorly constrain the ship emission inventories in the Eastern Mediterranean where the influence of uncertain land based emissions, the model transport and wet deposition are at least as important as the signal from ships. In the Western Mediterranean, the regional EMEP emission inventory gives the best match with most measurements, followed by Eyring for NO2 and ozone and by EDGAR for black carbon

  14. Dimethyl sulfide air-sea fluxes and biogenic sulfur as a source of new aerosols in the Arctic fall

    NASA Astrophysics Data System (ADS)

    Rempillo, Ofelia; Seguin, Alison Michelle; Norman, Ann-Lise; Scarratt, Michael; Michaud, Sonia; Chang, Rachel; Sjostedt, Steve; Abbatt, Jon; Else, Brent; Papakyriakou, Tim; Sharma, Sangeeta; Grasby, Steve; Levasseur, Maurice

    2011-09-01

    Dimethyl sulfide (DMS) and its oxidation products, which have been proposed to provide a climate feedback mechanism by affecting aerosol and cloud radiative properties, were measured on board the Canadian Coast Guard ship Amundsen in sampling campaigns in the Arctic in the fall of 2007 and 2008. DMS flux was calculated based on the surface water measurements and yielded 0.1-2.6 μmol m-2 d-1 along the Northwest Passage in 2007 and 0.2-1.3 μmol m-2 d-1 along Baffin Bay in 2008. DMS oxidation products, sulfur dioxide (SO2), methane sulfonic acid (MSA), and sulfate in aerosols were also measured. The amounts of biogenic SO2 and sulfate were approximated using stable isotope apportionment techniques. Calculating the threshold amount of SO2 needed for significant new particle formation from the formulation by Pirjola et al. (1999), the study suggests that instances of elevated biogenic SO2 concentrations (between 8 and 9 September 2008) derived using conservative assumptions may have been sufficient to form new aerosols in clean air conditions in the Arctic region.

  15. Examination of air-sea CO2 fluxes from the low-latitude coastal Eastern Pacific: Application of predictive algorithms to new VOS observations.

    NASA Astrophysics Data System (ADS)

    Hales, B.; Alin, S.; Feely, R. A.; Hernandez-Ayon, M.; Letelier, R.; Strutton, P. G.; Cosca, C.

    2008-12-01

    Coastal oceans are regions of large and highly variable air-sea CO2 fluxes, leading to highly uncertain predictions of globally significant contributions to the atmospheric carbon budget. Estimates of net annual regional fluxes are often the balance between poorly-constrained, large-magnitude sinks and sources. This is the case for the Pacific coast of North America, where a recent synthesis (Chavez et al., 2007) predicted low total fluxes resulting from the near-cancellation of large, lightly-sampled fluxes of opposite sign. In particular, the low latitude coastal waters off Central America appeared to be a large source of CO2 to the atmosphere, but there was very low spatial and temporal observational coverage in these waters. Recently, new VOS data in this region has become available that has dramatically increased both spatial and temporal sampling density in this region. In previous work we developed a new remote sensing-based synthetic approach applied to the mid-latitude regions of the North American Pacific coast that gave strong predictive power and was subsequently validated by in-water measurements in the summer of 2007. We present the results of applying this predictive approach to the target study region, and the predictive relationship is then combined with seasonally resolved remote sensing data to generate annual net flux estimates and to evaluate the prediction of strong efflux from these low-latitude waters based on the sparse historical data.

  16. Formation of gas-phase carbonyls from heterogeneous oxidation of polyunsaturated fatty acids at the air-water interface and of the sea surface microlayer

    NASA Astrophysics Data System (ADS)

    Zhou, S.; Gonzalez, L.; Leithead, A.; Finewax, Z.; Thalman, R.; Vlasenko, A.; Vagle, S.; Miller, L. A.; Li, S.-M.; Bureekul, S.; Furutani, H.; Uematsu, M.; Volkamer, R.; Abbatt, J.

    2014-02-01

    Motivated by the potential for reactive heterogeneous chemistry occurring at the ocean surface, gas-phase products were observed when a reactive sea surface microlayer (SML) component, i.e. the polyunsaturated fatty acids (PUFA) linoleic acid (LA), was exposed to gas-phase ozone at the air-seawater interface. Similar oxidation experiments were conducted with SML samples collected from two different oceanic locations, in the eastern equatorial Pacific Ocean and from the west coast of Canada. Online proton-transfer-reaction mass spectrometry (PTR-MS) University of Colorado light-emitting diode cavity-enhanced differential optical absorption spectroscopy (LED-CE-DOAS) were used to detect oxygenated gas-phase products from the ozonolysis reactions. The LA studies indicate that oxidation of a PUFA monolayer on seawater gives rise to prompt and efficient formation of gas-phase aldehydes. The products are formed via the decomposition of primary ozonides which form upon the initial reaction of ozone with the carbon-carbon double bonds in the PUFA molecules. In addition, two highly reactive dicarbonyls, malondialdehyde (MDA) and glyoxal, were also generated, likely as secondary products. Specific yields relative to reactant loss were 78%, 29%, 4% and < 1% for n-hexanal, 3-nonenal, MDA and glyoxal, respectively, where the yields for MDA and glyoxal are likely lower limits. Heterogeneous oxidation of SML samples confirm for the first time that similar carbonyl products are formed via ozonolysis of environmental samples.

  17. The composition of cosmic rays near the Bend (10 to the 15th power eV) from a study of muons in air showers at sea level

    NASA Technical Reports Server (NTRS)

    Goodman, J. A.; Gupta, S. C.; Freudenreich, H. T.; Sivaprasad, K.; Tonwar, S. C.; Yodh, G. B.; Ellsworth, R. W.; Goodman, M. C.; Bogert, M. C.; Burnstein, R.

    1985-01-01

    The distribution of muons near shower cores was studied at sea level at Fermilab using the E594 neutrino detector to sample the muon with E testing 3 GeV. These data are compared with detailed Monte Carlo simulations to derive conclusions about the composition of cosmic rays near the bend in the all particle spectrum. Monte Carlo simulations generating extensive air showers (EAS) with primary energy in excess of 50 TeV are described. Each shower record contains details of the electron lateral distribution and the muon and hadron lateral distributions as a function of energy, at the observation level of 100g/cm. The number of detected electrons and muons in each case was determined by a Poisson fluctuation of the number incident. The resultant predicted distribution of muons, electrons, the rate events are compared to those observed. Preliminary results on the rate favor a heavy primary dominated cosmic ray spectrum in energy range 50 to 1000 TeV.

  18. Net sea-air CO2 flux uncertainties in the Bay of Biscay based on the choice of wind speed products and gas transfer parameterizations

    NASA Astrophysics Data System (ADS)

    Otero, P.; Padín, X. A.; Ruiz-Villarreal, M.; García-García, L. M.; Ríos, A. F.; Pérez, F. F.

    2012-08-01

    The estimation of sea-air CO2 fluxes are largely dependent on wind speed through the gas transfer velocity parameterization. In this paper, we quantify uncertainties in the estimation of the CO2 uptake in the Bay of Biscay resulting from using different sources of wind speed such as three different global reanalysis meteorological models (NCEP/NCAR 1, NCEP/DOE 2 and ERA-Interim), one regional high-resolution forecast model (HIRLAM-AEMet) and QuikSCAT winds, in combination with some of the most widely used gas transfer velocity parameterizations. Results show that net CO2 flux estimations during an entire seasonal cycle may differ up to 240% depending on the wind speed product and the gas exchange parameterization. The comparison of satellite and model derived winds with observations at buoys advises against the systematic overestimation of NCEP-2 and the underestimation of NCEP-1. In this region, QuikSCAT has the best performing, although ERA-Interim becomes the best choice in areas near the coastline or when the time resolution is the constraint.

  19. Net sea-air CO2 flux uncertainties in the Bay of Biscay based on the choice of wind speed products and gas transfer parameterizations

    NASA Astrophysics Data System (ADS)

    Otero, P.; Padin, X. A.; Ruiz-Villarreal, M.; García-García, L. M.; Ríos, A. F.; Pérez, F. F.

    2013-05-01

    The estimation of sea-air CO2 fluxes is largely dependent on wind speed through the gas transfer velocity parameterization. In this paper, we quantify uncertainties in the estimation of the CO2 uptake in the Bay of Biscay resulting from the use of different sources of wind speed such as three different global reanalysis meteorological models (NCEP/NCAR 1, NCEP/DOE 2 and ERA-Interim), one high-resolution regional forecast model (HIRLAM-AEMet), winds derived under the Cross-Calibrated Multi-Platform (CCMP) project, and QuikSCAT winds in combination with some of the most widely used gas transfer velocity parameterizations. Results show that net CO2 flux estimations during an entire seasonal cycle (September 2002-September 2003) may vary by a factor of ~ 3 depending on the selected wind speed product and the gas exchange parameterization, with the highest impact due to the last one. The comparison of satellite- and model-derived winds with observations at buoys advises against the systematic overestimation of NCEP-2 and the underestimation of NCEP-1. In the coastal region, the presence of land and the time resolution are the main constraints of QuikSCAT, which turns CCMP and ERA-Interim in the preferred options.

  20. The relationship between the microwave radar cross section and both wind speed and stress: Model function studies using Frontal Air-Sea Interaction Experiment data

    NASA Technical Reports Server (NTRS)

    Weissman, David E.; Davidson, Kenneth L.; Brown, Robert A.; Friehe, Carl A.; Li, Fuk

    1994-01-01

    The Frontal Air-Sea Interaction Experiment (FASINEX) provided a unique data set with coincident airborne scatterometer measurements of the ocean surface radar cross section (RCS)(at Ku band) and near-surface wind and wind stress. These data have been analyzed to study new model functions which relate wind speed and surface friction velocity (square root of the kinematic wind stress) to the radar cross section and to better understand the processes in the boundary layer that have a strong influence on the radar backscatter. Studies of data from FASINEX indicate that the RCS has a different relation to the friction velocity than to the wind speed. The difference between the RCS models using these two variables depends on the polarization and the incidence angle. The radar data have been acquired from the Jet Propulsion Laboratory airborne scatterometer. These data span 10 different flight days. Stress measurements were inferred from shipboard instruments and from aircraft flying at low altitudes, closely following the scatterometer. Wide ranges of radar incidence angles and environmental conditions needed to fully develop algorithms are available from this experiment.

  1. Inference of super-resolution ocean pCO2 and air-sea CO2 fluxes from non-linear and multiscale processing methods

    NASA Astrophysics Data System (ADS)

    Hernández-Carrasco, Ismael; Sudre, Joel; Garçon, Veronique; Yahia, Hussein; Dewitte, Boris; Garbe, Christoph; Illig, Séréna; Montes, Ivonne; Dadou, Isabelle; Paulmier, Aurélien; Butz, André

    2014-05-01

    In recent years the role of submesoscale activity is emerging as being more and more important to understand global ocean properties, for instance, for accurately estimating the sources and sinks of Greenhouse Gases (GHGs) at the air-sea interface. The scarcity of oceanographic cruises and the lack of available satellite products for GHG concentrations at high resolution prevent from obtaining a global assessment of their spatial variability at small scales. In this work we develop a novel method to reconstruct maps of CO2 fluxes at super resolution (4km) using SST and ocean colour data at this resolution, and CarbonTracker CO2 fluxes data at low resolution (110 km). The responsible process for propagating the information between scales is related to cascading properties and multiscale organization, typical of fully developed turbulence. The methodology, based on the Microcanonical Multifractal Formalism, makes use, from the knowledge of singularity exponents, of the optimal wavelet for the determination of the energy injection mechanism between scales. We perform a validation analysis of the results of our algorithm using pCO2 ocean data from in-situ measurements in the upwelling region off Namibia.

  2. The European Fixed point Open Ocean Observatory network (FixO3): Multidisciplinary observations from the air-sea interface to the deep seafloor

    NASA Astrophysics Data System (ADS)

    Lampitt, Richard; Cristini, Luisa; Alexiou, Sofia

    2015-04-01

    The Fixed point Open Ocean Observatory network (FixO3, http://www.fixo3.eu/ ) integrates 23 European open ocean fixed point observatories and improves access to these infrastructures for the broader community. These provide multidisciplinary observations in all parts of the oceans from the air-sea interface to the deep seafloor. Started in September 2013 with a budget of 7 Million Euros over 4 years, the project has 29 partners drawn from academia, research institutions and SME's coordinated by the National Oceanography Centre, UK. Here we present the programme's achievements in the 18 months and the activities of the 12 Work Packages which have the objectives to: • integrate and harmonise the current procedures and processes • offer free access to observatory infrastructures to those who do not have such access, and free and open data services and products • innovate and enhance the current capability for multidisciplinary in situ ocean observation Open ocean observation is a high priority for European marine and maritime activities. FixO3 provides important data and services to address the Marine Strategy Framework Directive and in support of the European Integrated Maritime Policy. FixO3 provides a strong integrated framework of open ocean facilities in the Atlantic from the Arctic to the Antarctic and throughout the Mediterranean, enabling an integrated, regional and multidisciplinary approach to understand natural and anthropogenic change in the ocean.

  3. Nitrous oxide and methane in Atlantic and Mediterranean waters in the Strait of Gibraltar: Air-sea fluxes and inter-basin exchange

    NASA Astrophysics Data System (ADS)

    de la Paz, M.; Huertas, I. E.; Flecha, S.; Ríos, A. F.; Pérez, F. F.

    2015-11-01

    The global ocean plays an important role in the overall budget of nitrous oxide (N2O) and methane (CH4), as both gases are produced within the ocean and released to the atmosphere. However, for large parts of the open and coastal oceans there is little or no spatial data coverage for N2O and CH4. Hence, a better assessment of marine emissions estimates is necessary. As a contribution to remedying the scarcity of data on marine regions, N2O and CH4 concentrations have been determined in the Strait of Gibraltar at the ocean Fixed Time series (GIFT). During six cruises performed between July 2011 and November 2014 samples were collected at the surface and various depths in the water column, and subsequently measured using gas chromatography. From this we were able to quantify the temporal variability of the gas air-sea exchange in the area and examine the vertical distribution of N2O and CH4 in Atlantic and Mediterranean waters. Results show that surface Atlantic waters are nearly in equilibrium with the atmosphere whereas deeper Mediterranean waters are oversaturated in N2O, and a gradient that gradually increases with depth was detected in the water column. Temperature was found to be the main factor responsible for the seasonal variability of N2O in the surface layer. Furthermore, although CH4 levels did not reveal any feature clearly associated with the circulation of water masses, vertical distributions showed that higher concentrations are generally observed in the Atlantic layer, and that the deeper Mediterranean waters are considerably undersaturated (by up to 50%). Even though surface waters act as a source of atmospheric N2O during certain periods, on an annual basis the net N2O flux in the Strait of Gibraltar is only 0.35 ± 0.27 μmol m-2 d-1, meaning that these waters are almost in a neutral status with respect to the atmosphere. Seasonally, the region behaves as a slight sink for atmospheric CH4 in winter and as a source in spring and fall. Approximating

  4. Remote sensing aides studies of climate and wildlife in the Arctic-on land, at sea, and in the air (Invited)

    NASA Astrophysics Data System (ADS)

    Douglas, D. C.; Durner, G. M.; Gill, R. E.; Griffith, B.; Schmutz, J. A.

    2013-12-01

    Every day a variety of remote sensing technologies collects large volumes of data that are supporting new analyses and new interpretations about how weather and climate influence the status and distribution of wildlife populations worldwide. Understanding how climate presently affects wildlife is crucial for projecting how climate change could affect wildlife in the future. This talk highlights climate-related wildlife studies by the US Geological Survey in the Arctic. The Arctic is experiencing some of the most pronounced climate changes on earth, raising concerns for species that have evolved seasonal migration strategies tuned to habitat availability and quality. On land, large herbivores such as caribou select concentrated calving areas with high abundance of rapidly growing vegetation and calf survival increases with earlier green-up and with the quantity of food available to cows at peak lactation. Geese time their migrations and reproductive efforts to coincide with optimal plant phenology and peak nutrient availability and departures from this synchrony can influence the survival of goslings. At sea, the habitats of polar bears and other sea-ice-dependent species have dramatically changed over just the past two decades. The ice pack is comprised of younger ice that melts much more extensively during summer-a trend projected to continue by all general circulation models under all but the most aggressive greenhouse gas mitigation scenarios. Studies show that by mid-century optimal polar bear habitats will be so reduced that the species may become extirpated from some regions of the Arctic. In the air, a variety of shorebird species make non-stop endurance flights between northern and southern hemispheres. The bar-tailed godwit undertakes a trans-Pacific flight between Alaska and Australasia that lasts more than seven days and spans more than 10,000 km. Studies show that godwits time their flights to coincide with favorable wind conditions, but stochastic

  5. Regional coupled ocean-atmosphere downscaling in the Southeast Pacific: impacts on upwelling, mesoscale air-sea fluxes, and ocean eddies

    NASA Astrophysics Data System (ADS)

    Putrasahan, Dian A.; Miller, Arthur J.; Seo, Hyodae

    2013-05-01

    Ocean-atmosphere coupling in the Humboldt Current System (HCS) of the Southeast Pacific is studied using the Scripps Coupled Ocean-atmosphere Regional (SCOAR) model, which is used to downscale the National Center for Environmental Prediction (NCEP) Reanalysis-2 (RA2) product for the period 2000-2007 at 20-km resolution. An interactive 2-D spatial smoother within the sea-surface temperature (SST)-flux coupler is invoked in a separate run to isolate the impact of the mesoscale (˜50-200 km, in the oceanic sense) SST field felt by the atmosphere in the fully coupled run. For the HCS, SCOAR produces seasonal wind stress and wind stress curl patterns that agree better with QuikSCAT winds than those from RA2. The SCOAR downscaled wind stress distribution has substantially different impacts on the magnitude and structure of wind-driven upwelling processes along the coast compared to RA2. Along coastal locations such as Arica and Taltal, SCOAR and RA2 produce seasonally opposite signs in the total wind-driven upwelling transport. At San Juan, SCOAR shows that upwelling is mainly due to coastal Ekman upwelling transport, while in RA2 upwelling is mostly attributed to Ekman pumping. Fully coupled SCOAR shows significant SST-wind stress coupling during fall and winter, while smoothed SCOAR shows insignificant coupling throughout, indicating the important role of ocean mesoscale eddies on air-sea coupling in HCS. Coupling between SST, wind speed, and latent heat flux is incoherent in large-scale coupling and full coupling mode. In contrast, coupling between these three variables is clearly identified for oceanic mesoscales, which suggests that mesoscale SST affects latent heat directly through the bulk formulation, as well as indirectly through stability changes on the overlying atmosphere, which affects surface wind speeds. The SST-wind stress and SST-heat-flux couplings, however, fail to produce a strong change in the ocean eddy statistics. No rectified effects of ocean

  6. Formation of gas-phase carbonyls from heterogeneous oxidation of polyunsaturated fatty acids at the air-water interface and of the sea surface microlayer

    NASA Astrophysics Data System (ADS)

    Zhou, S.; Gonzalez, L.; Leithead, A.; Finewax, Z.; Thalman, R.; Vlasenko, A.; Vagle, S.; Miller, L.; Li, S.-M.; Bureekul, S.; Furutani, H.; Uematsu, M.; Volkamer, R.; Abbatt, J.

    2013-07-01

    Motivated by the potential for reactive heterogeneous chemistry occurring at the ocean surface, gas-phase products were observed when a reactive sea surface microlayer (SML) component, i.e. the polyunsaturated fatty acid (PUFA) linoleic acid (LA), was exposed to gas-phase ozone at the air-seawater interface. Similar oxidation experiments were conducted with SML samples collected from two different oceanic locations, in the eastern equatorial Pacific Ocean and from the west coast of Canada. Online proton-transfer-reaction mass spectrometry (PTR-MS) and light-emitting diode cavity enhanced differential optical absorption spectroscopy (LED-CE-DOAS) were used to detect oxygenated gas-phase products from the ozonolysis reactions. The LA studies indicate that oxidation of a PUFA monolayer on seawater gives rise to prompt and efficient formation of gas phase aldehydes. The products are formed via the decomposition of primary ozonides which form upon the initial reaction of ozone with the carbon-carbon double bonds in the PUFA molecules. In addition, two highly reactive di-carbonyls, malondialdehyde (MDA) and glyoxal, were also generated, likely as secondary products. Specific yields relative to reactant loss were 78%, 29%, 4% and <1% for n-hexanal, 3-nonenal, MDA and glyoxal, respectively, where the yields for MDA and glyoxal are likely lower limits. Heterogeneous oxidation of SML samples confirm for the first time that similar carbonyl products are formed via ozonolysis of environmental samples. The potential impact of such chemistry on the atmosphere of the marine boundary layer is discussed.

  7. Simulation of the Indian Summer Monsoon Using Comprehensive Atmosphere-land Interactions, in the Absence of Two-way Air-sea Interactions

    NASA Technical Reports Server (NTRS)

    Lim, Young-Kwon; Shin, D. W.; Cocke, Steven; Kang, Sung-Dae; Kim, Hae-Dong

    2011-01-01

    Community Land Model version 2 (CLM2) as a comprehensive land surface model and a simple land surface model (SLM) were coupled to an atmospheric climate model to investigate the role of land surface processes in the development and the persistence of the South Asian summer monsoon. Two-way air-sea interactions were not considered in order to identify the reproducibility of the monsoon evolution by the comprehensive land model, which includes more realistic vertical soil moisture structures, vegetation and 2-way atmosphere-land interactions at hourly intervals. In the monsoon development phase (May and June). comprehensive land-surface treatment improves the representation of atmospheric circulations and the resulting convergence/divergence through the improvements in differential heating patterns and surface energy fluxes. Coupling with CLM2 also improves the timing and spatial distribution of rainfall maxima, reducing the seasonal rainfall overestimation by approx.60 % (1.8 mm/d for SLM, 0.7 mm/dI for CLM2). As for the interannual variation of the simulated rainfall, correlation coefficients of the Indian seasonal rainfall with observation increased from 0.21 (SLM) to 0.45 (CLM2). However, in the mature monsoon phase (July to September), coupling with the CLM2 does not exhibit a clear improvement. In contrast to the development phase, latent heat flux is underestimated and sensible heat flux and surface temperature over India are markedly overestimated. In addition, the moisture fluxes do not correlate well with lower-level atmospheric convergence, yielding correlation coefficients and root mean square errors worse than those produced by coupling with the SLM. A more realistic representation of the surface temperature and energy fluxes is needed to achieve an improved simulation for the mature monsoon period.

  8. Air-Sea CO2 fluxes and NEP changes in a Baja California Coastal Lagoon during the anomalous North Pacific warm condition in 2014

    NASA Astrophysics Data System (ADS)

    Ávila López, M. D. C.; Martin Hernandez-Ayon, J. M.; Camacho-Ibar, V.; Sandoval Gil, J.; Mejía-Trejo, A.; Félix-Bermudez, A.; Pacheco-Ruiz, I.

    2015-12-01

    The present study examines the temporal variability of seawater carbonate chemistry and air-sea CO2 fluxes (FCO2) in a Baja California Mediterranean-climate coastal lagoon. This study was carried out from Nov-2013 to Nov-2014, a period in which anomalous warm conditions were present in the North Pacific Ocean influenced the local oceanography in the adjacent coastal waters off Baja California. These ocean conditions resulted on a negative anomaly of upwelling index, which led to summer-like season (weak upwelling condition) that could be observed in the response of carbon dynamics and metabolic status in San Quintín Bay. Minor changes in dissolved inorganic carbon (DIC) concentration during spring months (~100 µmol kg-1) where observed and were associated to biological processes within the lagoon. High DIC (~2200 µmol kg-1), pCO2 (~800 μatm), and minimum pH (~7.8) values were observed in summer, reflecting the predominance of respiration processes apparently mostly linked to the remineralization of sedimentary organic matter supplied from macroalgal blooms. San Quintín Bay acted as a weak source of CO2 to the atmosphere during the study period, with maximum value observed in July (~10 mmol C m-2 d-1). Temporal biomass production of macroalgae contributed to about 50% of total FCO2 estimated in spring-summer seasons, that was a potencial internal source of organic matter to fuel respiration processes in San Quintín Bay. Eelgrass metabolism contributes in a lower degree in total FCO2. During the anomalous ocean conditions in 2014, the lagoon switched seasonally between net heterotrophy and net autotrophy during the study period, where photosynthesis and respiration processes in the lagoon were closer to a balance. Whole-system metabolism and FCO2 clearly indicated the strong dependence of San Quintín Bay on upwelling conditions and benthic metabolism activity, which was mainly controlled by dominant primary producer communities.

  9. Effect of gas-transfer-velocity parameterization choice on CO2 air-sea fluxes in the North Atlantic and European Arctic

    NASA Astrophysics Data System (ADS)

    Wróbel, I.; Piskozub, J.

    2015-11-01

    The ocean sink is an important part of the anthropogenic CO2 budget. Because the terrestrial biosphere is usually treated as a residual, understanding the uncertainties the net flux into the ocean sink is crucial for understanding the global carbon cycle. One of the sources of uncertainty is the parameterization of CO2 gas transfer velocity. We used a recently developed software tool, FluxEngine, to calculate monthly net carbon air-sea flux for the extratropical North Atlantic, European Arctic as well as global values (or comparison) using several available parameterizations of gas transfer velocity of different dependence of wind speed, both quadratic and cubic. The aim of the study is to constrain the uncertainty caused by the choice of parameterization in the North Atlantic, a large sink of CO2 and a region with good measurement coverage, characterized by strong winds. We show that this uncertainty is smaller in the North Atlantic and in the Arctic than globally, within 5 % in the North Atlantic and 4 % in the European Arctic, comparing to 9 % for the World Ocean when restricted to functions with quadratic wind dependence and respectively 42, 40 and 67 % for all studied parameterizations. We propose an explanation of this smaller uncertainty due to the combination of higher than global average wind speeds in the North Atlantic and lack of seasonal changes in the flux direction in most of the region. We also compare the available pCO2 climatologies (Takahashi and SOCAT) pCO2 discrepancy in annual flux values of 8 % in the North Atlantic and 19 % in the European Arctic. The seasonal flux changes in the Arctic have inverse seasonal change in both climatologies, caused most probably by insufficient data coverage, especially in winter.

  10. Two approaches to determining the sea-to-air flux of dimethyl sulfide: Satellite ocean color and a photochemical model with atmospheric measurements

    SciTech Connect

    Thompson, A.M.; Esaias, W.E. ); Iverson, R.L. )

    1990-11-20

    Two estimates of the ocean-to-atmosphere flux of dimethyl sulfide (DMS) are presented to determine the feasibility of using remotely sensed data to map the marine sources of a photoreactive trace gas. First, an empirical relationship between chlorophyll a and DMS in surface seawater is used with NASA coastal zone color scanner (CZCS) data for chlorophyll a pigment to derive a mean DMS flux for a region in the tropical North Atlantic for October 1980. This is compared with the sea-to-air flux derived from a one-dimensional photochemical model that reproduces boundary layer concentrations of O{sub 3}, CO, NO, and hydrocarbon s measured on a cruise at the same location and time (Meteor 56/1). Both evaluations of DMS fluxes are in the range (2-7) {times} 10{sup 9} molecules DMS cm{sup {minus}2} s{sup {minus}1} and agree well with fluxes based on the seawater DMS concentration given by Barnard et al. (1982) for the Meteor cruise. The applicability of the results to strategies for satellite remote sensing of the tropospheric sulfur cycle is discussed. For some species (e.g., DMS) surface sensing of sources is feasible, but only in regions and seasons where phytoplankton pigment is a meaningful marker for biogenic emissions. The general applicability of ocean color to DMS determination awaits the development of an algorithm that can extract distributions of DMS emitting species from the optical signal. For other sulfur constituents (e.g., SO{sub 2}, COS) atmospheric measurements are appropriate for determining tropospheric distribution. Wind, moisture, cloud, precipitation, and temperature data are also required for complete characterization of the marine sulfur cycle.

  11. Air sea rescue, telemedicine style.

    PubMed

    Ferguson, J; Aujla, K; Pedley, D; Palombo, A

    2002-01-01

    Historically, requests from shipping in UK coastal waters for emergency medical advice have been handled on an ad hoc basis by various accident and emergency departments on behalf of the Coastguard. A formal contract to provide this service has recently been established with the Aberdeen Royal Infirmary in Scotland and the Royal Alexandra Hospital in Portsmouth, England. A pre-contract audit showed that the involvement of medical professionals in the evacuation decision improved the quality of triage and intervention. The medical staff at both hospitals received training in giving medical advice and the level of medical knowledge that could reasonably be expected of ships crews. Providing advice to commercial airlines developed from the maritime service. In association with a private company, staff at the Aberdeen Royal Infirmary have developed procedures to support cabin crew and medical professionals on board (initial figures suggest that a medical professional is present on about 45% of flights). At present, although there are insufficient data to draw any firm conclusions, it appears that up to two-thirds of diversions could be avoided using this service. PMID:12217123

  12. Influence and impact of the parametrization of the turbulent air-sea fluxes on atmospheric moisture and convection in the tropics

    NASA Astrophysics Data System (ADS)

    Torres, Olivier; Braconnot, Pascale; Gainusa-Bogdan, Alina; Hourdin, Frédéric; Marti, Olivier; Pelletier, Charles

    2016-04-01

    The turbulent fluxes across the ocean/atmosphere interface represent one of the principal driving forces of the global atmospheric and oceanic circulation and are also responsible for various phenomena like the water supply to the atmospheric column, which itself is extremely important for atmospheric convection. Although the representation of these fluxes has been the subject of major studies, it still remains a very challenging problem. Our aim is to better understand the role of these fluxes in climate change experiments and in the equator-pole redistribution of heat and water by the oceanic and atmospheric circulation. For this, we are developing a methodology starting from idealized 1D experiments and going all the way up to fully coupled ocean-atmosphere simulations of past and future climates. The poster will propose a synthesis of different simulations we have performed with a 1D version of the LMDz atmosphere model towards a first objective of understanding how different parameterizations of the turbulent fluxes affect the moisture content of the atmosphere and the feedback with the atmospheric boundary layer and convection schemes. Air-sea fluxes are not directly resolved by the models because they are subgrid-scale phenomena and are therefore represented by parametrizations. We investigate the differences between several 1D simulations of the TOGA-COARE campaign (1992-1993, Pacific warm pool region), for which 1D boundary conditions and observations are available to test the results of atmospheric models. Each simulation considers a different version of the LMDz model in terms of bulk formula (four) used to compute the turbulent fluxes. We also consider how the representation of gustiness in these parameterizations affects the results. The use of this LMDz test case (very constrained within an idealized framework) allows us to determine how the response of surface fluxes helps to reinforce or damp the atmospheric water vapor content or cloud feedbacks

  13. Fixed point Open Ocean Observatory network (FixO3): Multidisciplinary observations from the air-sea interface to the deep seafloor

    NASA Astrophysics Data System (ADS)

    Lampitt, Richard; Cristini, Luisa

    2014-05-01

    The Fixed point Open Ocean Observatory network (FixO3) seeks to integrate the 23 European open ocean fixed point observatories and to improve access to these key installations for the broader community. These will provide multidisciplinary observations in all parts of the oceans from the air-sea interface to the deep seafloor. Coordinated by the National Oceanography Centre, UK, FixO3 builds on the significant advances achieved through the previous Europe-funded FP7 programmes EuroSITES, ESONET and CARBOOCEAN. Started in September 2013 with a budget of 7 Million Euros over 4 years the project has 29 partners drawn from academia, research institutions and SME's. In addition 12 international experts from a wide range of disciplines comprise an Advisory Board. On behalf of the FixO3 Consortium, we present the programme that will be achieved through the activities of 12 Work Packages: 1. Coordination activities to integrate and harmonise the current procedures and processes. Strong links will be fostered with the wider community across academia, industry, policy and the general public through outreach, knowledge exchange and training. 2. Support actions to offer a) free access to observatory infrastructures to those who do not have such access, and b) free and open data services and products. 3. Joint research activities to innovate and enhance the current capability for multidisciplinary in situ ocean observation. Support actions include Transnational Access (TNA) to FixO3 infrastructure, meaning that European organizations can apply to free-of-charge access to the observatories for research and testing in two international calls during the project lifetime. The first call for TNA opens in summer 2014. More information can be found on FixO3 website (www.fixo3.eu/). Open ocean observation is currently a high priority for European marine and maritime activities. FixO3 will provide important data on environmental products and services to address the Marine Strategy

  14. The Development of Instrumentation and Methods for Measurement of Air-Sea Interaction and Coastal Processes from Manned and Unmanned Aircraft

    NASA Astrophysics Data System (ADS)

    Reineman, Benjamin D.

    I present the development of instrumentation and methods for the measurement of coastal processes, ocean surface phenomena, and air-sea interaction in two parts. In the first, I discuss the development of a portable scanning lidar (light detection and ranging) system for manned aircraft and demonstrate its functionality for oceanographic and coastal measurements. Measurements of the Southern California coastline and nearshore surface wave fields from seventeen research flights between August 2007 and December 2008 are analyzed and discussed. The October 2007 landslide on Mt. Soledad in La Jolla, California was documented by two of the flights. The topography, lagoon, reef, and surrounding wave field of Lady Elliot Island in Australia's Great Barrier Reef were measured with the airborne scanning lidar system on eight research flights in April 2008. Applications of the system, including coastal topographic surveys, wave measurements, ship wake studies, and coral reef research, are presented and discussed. In the second part, I detail the development of instrumentation packages for small (18 -- 28 kg) unmanned aerial vehicles (UAVs) to measure momentum fluxes and latent, sensible, and radiative heat fluxes in the atmospheric boundary layer (ABL), and the surface topography. Fast-response turbulence, hygrometer, and temperature probes permit turbulent momentum and heat flux measurements, and short- and long-wave radiometers allow the determination of net radiation, surface temperature, and albedo. Careful design and testing of an accurate turbulence probe, as demonstrated in this thesis, are essential for the ability to measure momentum and scalar fluxes. The low altitude required for accurate flux measurements (typically assumed to be 30 m) is below the typical safety limit of manned research aircraft; however, it is now within the capability of small UAV platforms. Flight tests of two instrumented BAE Manta UAVs over land were conducted in January 2011 at Mc

  15. The air-water CO2 exchange of a coastal sea—A sensitivity study on factors that influence the absorption and outgassing of CO2 in the Baltic Sea

    NASA Astrophysics Data System (ADS)

    Gustafsson, Erik; Omstedt, Anders; Gustafsson, Bo G.

    2015-08-01

    In this study, the BALTSEM model is used to estimate how air-water CO2 fluxes in the Baltic Sea respond to parameterizations of organic alkalinity (Aorg), gas transfer, and phytoplankton growth, and further to changes in river loads. The forcing data include the most complete compilation of Baltic river loads for dissolved inorganic and organic carbon (DIC and DOC) and total alkalinity (TA). In addition, we apply the most recent estimates of internal TA generation in the system. Our results clearly demonstrate how air-water CO2 fluxes of a coastal sea depend on river loads of carbon, TA, and nutrients as well the freshwater import itself. Long-term changes in DIC loads are shown to be compensated by corresponding changes in air-water CO2 exchange. By adding Aorg, a discrepancy in the carbonate system calculations was removed, and the simulated net CO2 absorption of the system decreased by 11%. A new parameterization for cyanobacteria growth significantly improved the seasonal development of pCO2 in the central Baltic Sea, although the net effect on CO2 fluxes was below 5%. By applying either a linear, quadratic, or cubic wind speed dependence for gas transfer, the long-term net CO2 exchange was adjusted by less than 5%. There is no clear indication that any one of these parameterizations provides a more accurate estimate of CO2 fluxes than the other two. Our findings are applicable in other coastal areas that are heavily influenced by river loads of TA, DIC, and DOC.

  16. X-ray computed microtomography of sea ice - comment on "A review of air-ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow" by Bartels-Rausch et al. (2014)

    NASA Astrophysics Data System (ADS)

    Obbard, R. W.

    2015-07-01

    This comment addresses a statement made in "A review of air-ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow" by Bartels-Rausch et al. (Atmos. Chem. Phys., 14, 1587-1633, doi:10.5194/acp-14-1587-2014, 2014). Here we rebut the assertion that X-ray computed microtomography of sea ice fails to reveal liquid brine inclusions by discussing the phases present at the analysis temperature.

  17. Dynamics of air-sea CO2 fluxes based on FerryBox measurements and satellite-based prediction of pCO2 in the Western English Channel

    NASA Astrophysics Data System (ADS)

    Marrec, Pierre; Thierry, Cariou; Eric, Mace; Pascal, Morin; Marc, Vernet; Yann, Bozec

    2014-05-01

    Since April 2012, we installed an autonomous FerryBox system on a Voluntary Observing Ship (VOS), which crosses the Western English Channel (WEC) between Roscoff and Plymouth on a daily basis. High-frequency data of sea surface temperature (SST), salinity (SSS), fluorescence, dissolved oxygen (DO) and partial pressure of CO2 (pCO2) were recorded for two years across the all-year mixed southern WEC (sWEC) and the seasonally stratified northern WEC (nWEC). These contrasting hydrographical provinces strongly influenced the spatio-temporal distributions of pCO2 and air-sea CO2 fluxes. During the productive period (from May to September), the nWEC acted as a sink for atmospheric CO2 of -5.6 mmolC m-2 d-1 and -4.6 mmolC m-2 d-1, in 2012 and 2013, respectively. During the same period, the sWEC showed significant inter-annual variability degassing CO2 to the atmosphere in 2012 (1.4 mmolC m-2 d-1) and absorbing atmospheric CO2 in 2013 (-1.6 mmolC m-2 d-1). In 2012, high-frequency data revealed that an intense and short (less than 10 days) summer phytoplankton bloom in the nWEC contributed to 31% of the total CO2 drawdown during the productive period, highlighting the necessity of pCO2 high-frequency measurements in coastal ecosystems. Based on this multi-annual dataset, we developed pCO2 algorithms using multiple linear regression (MLR) based on SST, SSS, chlorophyll-a (Chl-a) concentration, time, latitude and mixed layer depth to predict pCO2 in the two hydrographical provinces of the WEC. MLR were performed based on more than 200,000 underway observations spanning the range from 150 to 480 µatm. The root mean square errors (RMSE) of the MLR fit to the data were 17.2 µatm and 21.5 µatm for the s WEC and the nWEC with correlation coefficient (r²) of 0.71 and 0.79, respectively. We applied these algorithms to satellite SST and Chl-a products and to modeled SSS estimates in the entire WEC. Based on these high-frequency and satellite approaches, we will discuss the main

  18. NASA Tropical Rainfall Measurement Mission (TRMM): Effects of tropical rainfall on upper ocean dynamics, air-sea coupling and hydrologic cycle

    NASA Technical Reports Server (NTRS)

    Lagerloef, Gary; Busalacchi, Antonio J.; Liu, W. Timothy; Lukas, Roger B.; Niiler, Pern P.; Swift, Calvin T.

    1995-01-01

    This was a Tropical Rainfall Measurement Mission (TRMM) modeling, analysis and applications research project. Our broad scientific goals addressed three of the seven TRMM Priority Science Questions, specifically: What is the monthly average rainfall over the tropical ocean areas of about 10(exp 5) sq km, and how does this rain and its variability affect the structure and circulation of the tropical oceans? What is the relationship between precipitation and changes in the boundary conditions at the Earth's surface (e.g., sea surface temperature, soil properties, vegetation)? How can improved documentation of rainfall improve understanding of the hydrological cycle in the tropics?

  19. Long-range air transmission of bacteria.

    PubMed

    Bovallius, A; Bucht, B; Roffey, R; Anäs, P

    1978-06-01

    Bacterial spores from a sandstorm area north of the Black Sea were transmitted to Sweden by air, giving increased concentrations of viable bacterial spores at two air sampling stations in Sweden. PMID:677884

  20. Red Sea

    Atmospheric Science Data Center

    2013-04-16

    article title:  The Red Sea     View Larger Image ... Imaging SpectroRadiometer (MISR) image of the Red Sea was acquired on August 13, 2000. Located between the East African coast and the Saudi Arabian peninsula, the Red Sea got its name because the blooms of a type of algae,  Trichodesmium ...

  1. Bering Sea

    NASA Technical Reports Server (NTRS)

    2002-01-01

    Much of the Bering Sea is clear in this SeaWiFS image. The large expanse of bright aquamarine water is clearly visible. Credit: Provided by the SeaWiFS Project, NASA/Goddard Space Flight Center, and ORBIMAGE

  2. Bering Sea

    NASA Technical Reports Server (NTRS)

    2002-01-01

    The skies of the Bering Sea were relatively clear again in this SeaWiFS image showing a band of aquamarine colored water. Credit: Provided by the SeaWiFS Project, NASA/Goddard Space Flight Center, and ORBIMAGE

  3. Longitudinal development of muons in large air showers studies from the arrival time distributions measured at 900m above sea level

    NASA Technical Reports Server (NTRS)

    Kakimoto, F.; Tsuchimoto, I.; Enoki, T.; Suga, K.; Nishi, K.

    1985-01-01

    The arrival time distributions of muons with energies above 1.0GeV and 0.5GeV have been measured in the Akeno air-shower array to study the longitudinal development of muons in air showers with primary energies in the range 10 to the 17th power to 10 to the 18th power ev. The average rise times of muons with energies above 1.0GeV at large core distances are consistent with those expected from very high multiplicity models and, on the contrary, with those expected from the low multiplicity models at small core distances. This implies that the longitudinal development at atmospheric depth smaller than 500 cm square is very fast and that at larger atmospheric depths is rather slow.

  4. Bubble bursting as an aerosol generation mechanism during an oil spill in the deep-sea environment: molecular dynamics simulations of oil alkanes and dispersants in atmospheric air/salt water interfaces.

    PubMed

    Liyana-Arachchi, Thilanga P; Zhang, Zenghui; Ehrenhauser, Franz S; Avij, Paria; Valsaraj, Kalliat T; Hung, Francisco R

    2014-01-01

    Potential of mean force (PMF) calculations and molecular dynamics (MD) simulations were performed to investigate the properties of oil n-alkanes [i.e., n-pentadecane (C15), n-icosane (C20) and n-triacontane (C30)], as well as several surfactant species [i.e., the standard anionic surfactant sodium dodecyl sulfate (SDS), and three model dispersants similar to the Tween and Span species present in Corexit 9500A] at air/salt water interfaces. This study was motivated by the 2010 Deepwater Horizon (DWH) oil spill, and our simulation results show that, from the thermodynamic point of view, the n-alkanes and the model dispersants have a strong preference to remain at the air/salt water interface, as indicated by the presence of deep free energy minima at these interfaces. The free energy minimum of these n-alkanes becomes deeper as their chain length increases, and as the concentration of surfactant species at the interface increases. The n-alkanes tend to adopt a flat orientation and form aggregates at the bare air/salt water interface. When this interface is coated with surfactants, the n-alkanes tend to adopt more tilted orientations with respect to the vector normal to the interface. These simulation results are consistent with the experimental findings reported in the accompanying paper [Ehrenhauser et al., Environ. Sci.: Processes Impacts 2013, in press, (DOI: 10.1039/c3em00390f)]. The fact that these long-chain n-alkanes show a strong thermodynamic preference to remain at the air/salt water interfaces, especially if these interfaces are coated with surfactants, makes these species very likely to adsorb at the surface of bubbles or droplets and be ejected to the atmosphere by sea surface processes such as whitecaps (breaking waves) and bubble bursting. Finally, the experimental finding that more oil hydrocarbons are ejected when Corexit 9500A is present in the system is consistent with the deeper free energy minima observed for the n-alkanes at the air/salt water

  5. Dynamics of Arctic sea ice discussed at workshop

    NASA Astrophysics Data System (ADS)

    Overland, James; Ukita, Jinro

    Sea ice is an interesting geophysical material: it behaves as a large-scale hardening plastic. Consider the impact of the sea-ice covers mechanical behavior on the energy and momentum exchange within the complex atmosphere-ice-ocean system. Sea ice acts as an insulator between the relatively warm ocean water and the cold polar atmosphere. Sea ice cover interacts with the atmosphere by regulating air-sea fluxes, changing surface albedo, and influencing the long-wave radiative balance.

  6. Thermaikos Gulf Coastal System, NW Aegean Sea: an overview of water/sediment fluxes in relation to air land ocean interactions and human activities

    NASA Astrophysics Data System (ADS)

    Poulos, S. E.; Chronis, G. Th; Collins, M. B.; Lykousis, V.

    2000-04-01

    This study presents an overview of the Holocene formation and evolution of the coastal system of Thermaikos Gulf (NW Aegean Sea). The system is divided into the terrestrial sub-system and the oceanic sub-system; the former represents 90%, while the latter includes only 10% of the total area. This particular coastal zone includes the second most important socio-economic area of Greece and in the southern Balkans, the Thessaloniki region; this is in terms of population concentration (>1 million people), industry, agriculture, aquaculture, trade and services. The geomorphology of the coastal zone is controlled by sediment inputs, nearshore water circulation, and the level of wave activity. The large quantities of sediments (with yields >500 tonnes/km 2 per year), delivered annually by the main rivers (Axios, Aliakmon, Pinios, and Gallikos) and other seasonal streams are responsible for the general progradation of the coastline and the formation of the Holocene sedimentary cover over the seabed of the Gulf. Changes to the coastline can be identified on macro- and meso-time scales; the former include the evolution of the deltaic plains (at >1 km 2/year), while the latter incorporates seasonal changes along sections of the coastline (e.g. sandy spits), mostly due to the anthropogenic activities. The overall water circulation pattern in Thermaikos Gulf is characterised by northerly water movement, from the central and eastern part of the Gulf; this is compensated by southerly movement along its western part. The prevailing climate (winds and pressure systems) appears to control the surface water circulation, while near-bed current measurements reveal a general moderate (<15 cm/s) southerly flow, i.e. offshore, towards the deep water Sporades Basin. Waves approaching from southerly directions play also a role in controlling the shoreline configuration. Various human activities within the coastal system place considerable pressure on the natural evolution of the coastal

  7. Air-sea energy exchanges measured by eddy covariance during a localised coral bleaching event, Heron Reef, Great Barrier Reef, Australia

    NASA Astrophysics Data System (ADS)

    MacKellar, Mellissa C.; McGowan, Hamish A.

    2010-12-01

    Despite the widely claimed association between climate change and coral bleaching, a paucity of data exists relating to exchanges of heat, moisture and momentum between the atmosphere and the reef-water surface. We present in situ measurements of reef-water-air energy exchanges made using the eddy covariance method during a summer coral bleaching event at Heron Reef, Australia. Under settled, cloud-free conditions and light winds, daily net radiation exceeded 800 W m-2, with up to 95% of the net radiation during the morning partitioned into heating the water column, substrate and benthic cover including corals. Heating was exacerbated by a mid-afternoon low tide when shallow reef flat water reached 34°C and near-bottom temperatures 33°C, exceeding the thermal tolerance of corals, causing bleaching. Results suggest that local to synoptic scale meteorology, particularly clear skies, solar heating, light winds and the timing of low tide were the primary controls on coral bleaching.

  8. The size dependence of the average transverse momentum of hadrons with respect to the shower axis direction in extensive air showers observed at sea level

    NASA Astrophysics Data System (ADS)

    Ashton, F.; Nejabat, H.

    The simplest way of studying whether the characteristics of a nucleon-nucleon interaction change with increasing energy is to observe whether the mean value of hadron energy at the orthogonal core distance depends on shower size. Ashton et al. (1977) used a high-energy hadron detector as a master trigger and measured the core position and shower size of any accompanying air shower; results showed that the average transverse momentum of hadrons with respect to the shower axis direction increases with shower size. These results are checked, but with the following experimental changes: (1) the master trigger is now either an electron density inner ring trigger or an electron density outer ring trigger of the Durham EAS array; (2) the orthogonal core distances between measured hadron interactions and the shower axis direction are found; and (3) the charged or neutral state of a sample of detected hadrons is determined. The previously obtained results are confirmed by the experiment, and a change in the character of the nucleon-nucleon interaction is indicated for energies greater than 2 x 10 to the 14th eV.

  9. Estimating Seasonal Cycles of Atmospheric CO2 and APO Resulting from Terrestrial NEE and Air-Sea O2 Fluxes using the Transcom T3L2 Pulse-Response Functions

    NASA Astrophysics Data System (ADS)

    Nevison, C. D.

    2011-12-01

    We present a method for translating modeled terrestrial net ecosystem exchange (NEE) fluxes of carbon into the corresponding annual mean cycles in atmospheric CO2. The method is based on the pulse-response functions from the Transcom 3 atmospheric tracer transport model (ATM) intercomparison. An oceanic version of the method is applied to air-sea O2 fluxes to estimate the corresponding annual mean cycles in atmospheric potential oxygen (APO). The estimated atmospheric seasonal cycles can be evaluated against observed atmospheric CO2 and APO data, which are measured at high precision at a wide range of monitoring sites and reflect the integrated impact of surface CO2 and O2 fluxes, respectively, across broad regions. The pulse-response function method is considerably faster than a full forward ATM simulation, allowing seasonal cycles from 13 different ATMS to be computed in minutes, rather than the days or weeks required for a single forward simulation. We evaluate the method against the results of full forward ATM simulations and examine the uncertainties associated with neglecting additional surface fluxes, e.g., from fossil fuel combustion, that may contribute to the observed seasonal cycles of CO2 and APO.

  10. Air-sea CO2 fluxes and the controls on ocean surface pCO2 seasonal variability in the coastal and open-ocean southwestern Atlantic Ocean: a modeling study

    NASA Astrophysics Data System (ADS)

    Arruda, R.; Calil, P. H. R.; Bianchi, A. A.; Doney, S. C.; Gruber, N.; Lima, I.; Turi, G.

    2015-10-01

    We use an eddy-resolving, regional ocean biogeochemical model to investigate the main variables and processes responsible for the climatological spatio-temporal variability of pCO2 and the air-sea CO2 fluxes in the southwestern Atlantic Ocean. Overall, the region acts as a sink of atmospheric CO2 south of 30° S, and is close to equilibrium with the atmospheric CO2 to the north. On the shelves, the ocean acts as a weak source of CO2, except for the mid/outer shelves of Patagonia, which act as sinks. In contrast, the inner shelves and the low latitude open ocean of the southwestern Atlantic represent source regions. Observed nearshore-to-offshore and meridional pCO2 gradients are well represented by our simulation. A sensitivity analysis shows the importance of the counteracting effects of temperature and dissolved inorganic carbon (DIC) in controlling the seasonal variability of pCO2. Biological production and solubility are the main processes regulating pCO2, with biological production being particularly important on the shelves. The role of mixing/stratification in modulating DIC, and therefore surface pCO2, is shown in a vertical profile at the location of the Ocean Observatories Initiative (OOI) site in the Argentine Basin (42° S, 42° W).

  11. Atlantic mercury emission determined from continuous analysis of the elemental mercury sea-air concentration difference within transects between 50°N and 50°S

    NASA Astrophysics Data System (ADS)

    Kuss, J.; Zülicke, C.; Pohl, C.; Schneider, B.

    2011-09-01

    Mercury in the environment deserves serious concern because of the mobility of volatile elemental mercury (Hg0) in the atmosphere, in combination with the harmful effect of Hg compounds on human health and the ecosystem. A major source of global atmospheric mercury is presumed to be oceanic Hg0 emission. However, available Hg0 surface water data to reliably estimate the ocean's mercury emissions are sparse. In this study, high-resolution surface water and air measurements of Hg0 were carried out between Europe and South Africa in November 2008 and between South America and Europe in April-May 2009. On each cruise a strong enrichment of Hg0 in tropical surface water was determined that apparently followed the seasonal shift of the Intertropical Convergence Zone (ITCZ). A combination of a high Hg0 production rate constant and the actual low wind speeds, which prevented emission, probably caused the accumulation of Hg0 in surface waters of the ITCZ. Hg0 emissions in the tropics were significant only if wind speed variability on a monthly scale was considered, in which case the observed significant decline of total Hg in tropical surface waters during the northern winter could be explained. In the midlatitudes, increased autumn Hg0 emissions were calculated for November in the Northern Hemisphere and for May in the Southern Hemisphere; conversely, emissions were low during both the northern and the southern spring. Mercury removal from surface waters by Hg0 emission and sinking particles was comparable to its supply through wet and dry deposition.

  12. A coupled decadal-scale air-sea interaction theory: the NAT-NAO-AMO-AMOC coupled mode and its global impacts

    NASA Astrophysics Data System (ADS)

    Li, Jianping; Sun, Cheng; Jin, Fei-Fei

    2016-04-01

    Observational analysis shows that the North Atlantic Oscillation (NAO) leads the oceanic Atlantic Multidecadal Oscillation (AMO) by 15-20 years and the latter also leads the former by around 15 years. The Community Climate System Model (CCSM) version 4 is employed to investigate the relevant mechanism in the linkage between the NAO and AMO. The results show that the positive North Atlantic Oscillation (NAO) forces the strengthening of the Atlantic meridional overturning circulation (AMOC) and induces a basin-wide uniform sea surface temperature (SST) warming that corresponds to the Atlantic multidecadal oscillation (AMO). The SST field exhibits a delayed response to the preceding enhanced AMOC, and shows a pattern similar to the North Atlantic tripole (NAT), with SST warming in the northern North Atlantic and cooling in the southern part. This SST pattern (negative NAT phase) may lead to an atmospheric response that resembles the negative NAO phase, and subsequently the oscillation proceeds, but in the opposite sense. This implies a NAO-AMO-AMOC coupled mode in decadal scale. Based on these mechanisms, a simple delayed oscillator model is established to explain the quasi-periodic multidecadal variability of the NAO. The magnitude of the NAO forcing of the AMOC/AMO and the time delay of the AMOC/AMO feedback are two key parameters of the delayed oscillator. For a given set of parameters, the quasi 60-year cycle of the NAO can be well predicted. This delayed oscillator model is useful for understanding of the oscillatory mechanism of the NAO, which has significant potential for decadal predictions as well as the interpretation of proxy data records. The NAT-NAO-AMO-AMOC coupled mode has important influences on global and regional climate. The twentieth century Northern Hemisphere mean surface temperature (NHT) is characterized by a multidecadal warming-cooling-warming pattern followed by a flat trend since about 2000 (recent warming hiatus). Here we demonstrate that

  13. N2O seasonal distributions and air-sea exchange in UK estuaries: Implications for the tropospheric N2O source from European coastal waters

    NASA Astrophysics Data System (ADS)

    Barnes, J.; Upstill-Goddard, R. C.

    2011-03-01

    We report measurements of dissolved nitrous oxide (N2O), dissolved inorganic nitrogen, and turbidity in surveys of six UK inner estuaries between February 2000 and October 2002: the Humber, Forth, Tamar, Tyne, Tees, and Tay. We also present dissolved N2O data for the Wash outer estuary from May 1995 and dissolved O2 data for the Forth estuary from June 2001. N2O was always supersaturated relative to air and was highest in the Humber (range 140-6500%) and generally higher at all sites during summer. In estuaries with well defined turbidity maximum zones (TMZs) at low salinity, N2O was maximal in the TMZ, coincident with high NH4+ and/or NO3-. Inspection of the broad relationships between N2O, NH4+, NO3-, NO2-, and O2 revealed a predominantly nitrification source for the N2O in the estuaries studied; denitrification-derived N2O was apparently unimportant and denitrification did not constitute a significant NO3- sink. In the anthropogenically impacted Tees estuary N2O (saturation 140-2000%) was attributed to high NH4+ in sewage and industrial effluent. N2O emissions were thus primarily a function of NH4+ derived from internal resuspension and/or ammonification, or external inputs and were independent of river-borne NO3-. We reevaluated total UK and European estuarine N2O emissions using these and published data, based on an aerially weighted approach that separately identified inner and outer estuaries, and a downward revision of the total European estuarine area used in a recent synthesis. Our revised estimates, ˜1.9 ± 1.2 × 109 g N2O yr-1 for the UK and 6.8 ± 13.2 × 109 g N2O yr-1 for Europe (including UK) are dominated by large (area ˜200-500 km2) anthropogenically impacted macrotidal inner estuaries. By contrast large pristine macrotidal systems, small inner estuaries, and large outer estuaries appear to be comparatively minor N2O sources. The UK estuarine N2O source is <2% of the UK N2O budget. Our revised European estuarine N2O emission is around 2 orders

  14. Sea Legs

    NASA Astrophysics Data System (ADS)

    Macdonald, Kenneth C.

    Forty-foot, storm-swept seas, Spitzbergen polar bears roaming vast expanses of Arctic ice, furtive exchanges of forbidden manuscripts in Cold War Moscow, the New York city fashion scene, diving in mini-subs to the sea floor hot srings, life with the astronauts, romance and heartbreak, and invading the last bastions of male exclusivity: all are present in this fast-moving, non-fiction account of one woman' fascinating adventures in the world of marine geology and oceanography.

  15. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, dust, ... a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  16. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, ... Ozone, a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  17. Black Sea

    NASA Technical Reports Server (NTRS)

    2002-01-01

    The Black Sea in eastern Russia is experiencing an ongoing phytoplankton bloom. This image, the most recent in a series that began in early may, shows the waters to be even more colorful than before. part of the increased brightness may be due to the presence of sun glint , especially in the center of the sea. However, more organisms appear to be present as well, their photosynthetic pigments reflecting different wavelengths of light.This Moderate Resolution Imaging Spectroradiometer (MODIS) image was captured on June 15, 2002.

  18. Sea Ice

    NASA Technical Reports Server (NTRS)

    Perovich, D.; Gerland, S.; Hendricks, S.; Meier, Walter N.; Nicolaus, M.; Richter-Menge, J.; Tschudi, M.

    2013-01-01

    During 2013, Arctic sea ice extent remained well below normal, but the September 2013 minimum extent was substantially higher than the record-breaking minimum in 2012. Nonetheless, the minimum was still much lower than normal and the long-term trend Arctic September extent is -13.7 per decade relative to the 1981-2010 average. The less extreme conditions this year compared to 2012 were due to cooler temperatures and wind patterns that favored retention of ice through the summer. Sea ice thickness and volume remained near record-low levels, though indications are of slightly thicker ice compared to the record low of 2012.

  19. Aral Sea

    NASA Technical Reports Server (NTRS)

    2002-01-01

    This series of MODIS images shows the dwindling Aral Sea. Once one of the world's largest freshwater lakes, the Aral Sea has decreased by as much as 60% over the past few decades due to diversion of the water to grow cotton and rice. These diversion have dropped the lake levels, increased salinity, and nearly decimated the fishing industry. The previous extent of the lake is clearly visible as a whitish perimeter in these image from April 16, May 18, and June 3, 2002. s. Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC

  20. Ross Sea

    Atmospheric Science Data Center

    2013-04-16

    article title:  Icebergs in the Ross Sea     View Larger Image Two large icebergs, designated B-15A and C-16, are captured in this Multi-angle Imaging ... the longitudinal quadrant in which it is first seen, and new icebergs sighted in that quadrant are sequentially numbered. B-15 divided from ...

  1. ALTITUDE AS A FACTOR IN AIR POLLUTION

    EPA Science Inventory

    Air pollution is affected by change in altitude. Cities with surface elevations above 1500 meters have atmospheric pressures which are approximately fifteen percent (15%) below pressures at sea level. Consequently, mobile sources designed to operate at pressures of one atmosphere...

  2. Warm-air advection, air mass transformation and fog causes rapid ice melt

    NASA Astrophysics Data System (ADS)

    Tjernström, Michael; Shupe, Matthew D.; Brooks, Ian M.; Persson, P. Ola G.; Prytherch, John; Salisbury, Dominic J.; Sedlar, Joseph; Achtert, Peggy; Brooks, Barbara J.; Johnston, Paul E.; Sotiropoulou, Georgia; Wolfe, Dan

    2015-07-01

    Direct observations during intense warm-air advection over the East Siberian Sea reveal a period of rapid sea-ice melt. A semistationary, high-pressure system north of the Bering Strait forced northward advection of warm, moist air from the continent. Air-mass transformation over melting sea ice formed a strong, surface-based temperature inversion in which dense fog formed. This induced a positive net longwave radiation at the surface while reducing net solar radiation only marginally; the inversion also resulted in downward turbulent heat flux. The sum of these processes enhanced the surface energy flux by an average of ~15 W m-2 for a week. Satellite images before and after the episode show sea-ice concentrations decreasing from > 90% to ~50% over a large area affected by the air-mass transformation. We argue that this rapid melt was triggered by the increased heat flux from the atmosphere due to the warm-air advection.

  3. The wave and wave forecasting in the China Seas

    SciTech Connect

    Xu Fuxiang

    1993-12-31

    The China Seas located at the Southeastern part of the large Eurasia continent, and beside the largest ocean, the Pacific. They are greatly influenced by continent and the ocean. Due to it across the tropical zone, the subtropical zone and the extropical zone, the cold and warm air circulation in Northsouth is a very active exchange. In the summer, the South China Sea and the East China Sea are frequently hit by typhoon waves. In spring and autumn, the bohai sea, the Yellow sea and the East China Seas had series disasters caused by the extropical cyclone wave and the cold air wave. In this paper the time-space distribution and formative cases of wave disaster in the China Seas, and the wave monitoring and prediction system, the wave prediction method, and two automatic systems of numerical wave forecasting are briefly introduced.

  4. From Sea to Shining Sea

    ERIC Educational Resources Information Center

    Scott, Beverly

    2005-01-01

    Deep down in the depths of the sea, beautiful fish, mysterious ocean life, and unusual plants glimmer and glow in the eerie atmosphere of an ever-changing ocean. This article describes how, with this vision and a purpose in mind, three teachers pulled open classroom walls and joined forces so their second graders could create a mammoth 30 x 75"…

  5. Sea Breezes over the Red Sea: Affect of topography and interaction with Desert Convective Boundary Layer

    NASA Astrophysics Data System (ADS)

    Khan, Basit A.; Stenchikov, Georgiy; Abualnaja, Yasser

    2014-05-01

    Thermodynamic structure of sea-breeze, its interaction with coastal mountains, desert plateau and desert convective boundary layer have been investigated in the middle region of the Red Sea around 25°N, at the Western coast of Saudi Arabia. Sea and land breeze is a common meteorological phenomenon in most of the coastal regions around the world. Sea-Breeze effects the local meteorology and cause changes in wind speed, direction, cloud cover and sometimes precipitation. The occurrence of sea-breeze, its intensity and landward propagation are important for wind energy resource assessment, load forecasting for existing wind farms, air pollution, marine and aviation applications. The thermally induced mesoscale circulation of sea breeze modifies the desert Planetary Boundary Layer (PBL) by forming Convective Internal Boundary Layer (CIBL), and propagates inland as a density current. The leading edge of the denser marine air rapidly moves inland undercutting the hot and dry desert air mass. The warm air lifts up along the frontal boundary and if contains enough moisture a band of clouds is formed along the sea breeze front (SBF). This study focuses on the thermodynamic structure of sea-breeze as it propagates over coastal rocky mountain range of Al-Sarawat, east of the Red Sea coast, and the desert plateau across the mountain range. Additional effects of topographical gaps such as Tokar gap on the dynamics of sea-land breezes have also been discussed. Interaction of SBF with the desert convective boundary layer provide extra lifting that could further enhance the convective instability along the frontal boundary. This study provides a detailed analysis of the thermodynamics of interaction of the SBF and convective internal boundary layer over the desert. Observational data from a buoy and meteorological stations have been utilized while The Advanced Research WRF (ARW) modeling system has been employed in real and 2D idealized configuration.

  6. Air Abrasion

    MedlinePlus

    ... delivered directly to your desktop! more... What Is Air Abrasion? Article Chapters What Is Air Abrasion? What Happens? The Pros and Cons Will I Feel Anything? Is Air Abrasion for Everyone? print full article print this ...

  7. Improving the WRF model's simulation over sea ice surface through coupling with a complex thermodynamic sea ice model

    NASA Astrophysics Data System (ADS)

    Yao, Y.; Huang, J.; Luo, Y.; Zhao, Z.

    2015-12-01

    Sea ice plays an important role in the air-ice-ocean interaction, but it is often represented simply in many regional atmospheric models. The Noah sea ice model, which has been widely used in the Weather Research and Forecasting (WRF) model, exhibits cold bias in simulating the Arctic sea ice temperature when validated against the Surface Heat Budget of the Arctic Ocean (SHEBA) in situ observations. According to sensitivity tests, this bias is attributed not only to the simulation of snow depth and turbulent fluxes but also to the heat conduction within snow and ice. Compared with the Noah sea ice model, the high-resolution thermodynamic snow and ice model (HIGHTSI) has smaller bias in simulating the sea ice temperature. HIGHTSI is further coupled with the WRF model to evaluate the possible added value from better resolving the heat transport and solar penetration in sea ice from a complex thermodynamic sea ice model. The cold bias in simulating the surface temperature over sea ice in winter by the original Polar WRF is reduced when HIGHTSI rather than Noah is coupled with the WRF model, and this also leads to a better representation of surface upward longwave radiation and 2 m air temperature. A discussion on the impact of specifying sea ice thickness in the WRF model is presented. Consistent with previous research, prescribing the sea ice thickness with observational information would result in the best simulation among the available methods. If no observational information is available, using an empirical method based on the relationship between sea ice concentration and sea ice thickness could mimic the large-scale spatial feature of sea ice thickness. The potential application of a thermodynamic sea ice model in predicting the change in sea ice thickness in a RCM is limited by the lack of sea ice dynamic processes in the model and the coarse assumption on the initial value of sea ice thickness.

  8. Organic iodine in Antarctic sea ice: A comparison between winter in the Weddell Sea and summer in the Amundsen Sea

    NASA Astrophysics Data System (ADS)

    Granfors, Anna; Ahnoff, Martin; Mills, Matthew M.; Abrahamsson, Katarina

    2014-12-01

    Recent studies have recognized sea ice as a source of reactive iodine to the Antarctic boundary layer. Volatile iodinated compounds (iodocarbons) are released from sea ice, and they have been suggested to contribute to the formation of iodine oxide (IO), which takes part in tropospheric ozone destruction in the polar spring. We measured iodocarbons (CH3I, CH2ClI, CH2BrI, and CH2I2) in sea ice, snow, brine, and air during two expeditions to Antarctica, OSO 10/11 to the Amundsen Sea during austral summer and ANT XXIX/6 to the Weddell Sea in austral winter. These are the first reported measurements of iodocarbons from the Antarctic winter. Iodocarbons were enriched in sea ice in relation to seawater in both summer and winter. During summer, the positive relationship to chlorophyll a biomass indicated a biological origin. We suggest that CH3I is formed biotically in sea ice during both summer and winter. For CH2ClI, CH2BrI, and CH2I2, an additional abiotic source at the snow/ice interface in winter is suggested. Elevated air concentrations of CH3I and CH2ClI during winter indicate that they are enriched in lower troposphere and may take part in the formation of IO at polar sunrise.

  9. Sea Ice, Climate and Fram Strait

    NASA Technical Reports Server (NTRS)

    Hunkins, K.

    1984-01-01

    When sea ice is formed the albedo of the ocean surface increases from its open water value of about 0.1 to a value as high as 0.8. This albedo change effects the radiation balance and thus has the potential to alter climate. Sea ice also partially seals off the ocean from the atmosphere, reducing the exchange of gases such as carbon dioxide. This is another possible mechanism by which climate might be affected. The Marginal Ice Zone Experiment (MIZEX 83 to 84) is an international, multidisciplinary study of processes controlling the edge of the ice pack in that area including the interactions between sea, air and ice.

  10. Sea Ice

    NASA Technical Reports Server (NTRS)

    Parkinson, Claire L.; Cavalieri, Donald J.

    2005-01-01

    Sea ice covers vast areas of the polar oceans, with ice extent in the Northern Hemisphere ranging from approximately 7 x 10(exp 6) sq km in September to approximately 15 x 10(exp 6) sq km in March and ice extent in the Southern Hemisphere ranging from approximately 3 x 10(exp 6) sq km in February to approximately 18 x 10(exp 6) sq km in September. These ice covers have major impacts on the atmosphere, oceans, and ecosystems of the polar regions, and so as changes occur in them there are potential widespread consequences. Satellite data reveal considerable interannual variability in both polar sea ice covers, and many studies suggest possible connections between the ice and various oscillations within the climate system, such as the Arctic Oscillation, North Atlantic Oscillation, and Antarctic Oscillation, or Southern Annular Mode. Nonetheless, statistically significant long-term trends are also apparent, including overall trends of decreased ice coverage in the Arctic and increased ice coverage in the Antarctic from late 1978 through the end of 2003, with the Antarctic ice increases following marked decreases in the Antarctic ice during the 1970s. For a detailed picture of the seasonally varying ice cover at the start of the 21st century, this chapter includes ice concentration maps for each month of 2001 for both the Arctic and the Antarctic, as well as an overview of what the satellite record has revealed about the two polar ice covers from the 1970s through 2003.

  11. Mammals of the Sea.

    ERIC Educational Resources Information Center

    Naturescope, 1986

    1986-01-01

    Presents information on sea mammals, including definitions and characteristics of cetaceans, pinnipeds, and sirenians. Contains descriptions of the teaching activities "Whale Music,""Draw A Whale to Scale,""Adopt a Sea Mammal," and "Sea Mammal Sleuths." (TW)

  12. Melting Ice, Rising Seas

    NASA Video Gallery

    Sea level rise is an indicator that our planet is warming. Much of the world's population lives on or near the coast, and rising seas are something worth watching. Sea level can rise for two reason...

  13. Sea Ice in the NCEP Climate Forecast System

    NASA Astrophysics Data System (ADS)

    Wu, X.; Grumbine, R. W.

    2015-12-01

    Sea ice is known to play a significant role in the global climate system. For a weather or climate forecast system (CFS), it is important that the realistic distribution of sea ice is represented. Sea ice prediction is challenging; sea ice can form or melt, it can move with wind and/or ocean current; sea ice interacts with both the air above and ocean underneath, it influences by, and has impact on the air and ocean conditions. NCEP has developed coupled CFS (version 2, CFSv2) and carried out CFS reanalysis (CFSR), which includes a coupled model with the NCEP global forecast system, a land model, an ocean model (GFDL MOM4), and a sea ice model. In this work, we present the NCEP coupled model, the CFSv2 sea ice component that includes a dynamic thermodynamic sea ice model and a simple "assimilation" scheme, how sea ice has been assimilated in CFSR, the characteristics of the sea ice from CFSR and CFSv2, and the improvements of sea ice needed for future CFS (version 3) and the CFSR.

  14. Sea Ventures Development Phase, October 1, 1975 - September 30, 1978.

    ERIC Educational Resources Information Center

    Sea Ventures, Highlands, NJ.

    A detailed profile of the largest fresh-air education program in the country for disadvantaged youth -- Sea Ventures -- is provided in this document. Created entirely through the effort of volunteers, Sea Ventures provides learning opportunities that go beyond occupying youngsters. This multi-racial/lingual juvenile delinquency prevention program…

  15. Air resources

    SciTech Connect

    1995-10-01

    This section describes the ambient (surrounding) air quality of the TVA region, discusses TVA emission contributions to ambient air quality, and identifies air quality impacts to human health and welfare. Volume 2 Technical Document 2, Environmental Consequences, describes how changes in TVA emissions could affect regional air quality, human health, environmental resources, and materials. The primary region of the affected environment is broadly defined as the state of Tennessee, as well as southern Kentucky, western Virginia, southern West Virginia, western North Carolina, and northern Georgia, Alabama, and Mississippi. This area represents the watershed of the Tennessee River and the 201 counties of the greater TVA service area. Emissions from outside the Tennessee Valley region contribute to air quality in the Valley. Also, TVA emissions are transported outside the Valley and have some impact on air quality beyond the primary study area. Although the study area experiences a number of air quality problems, overall air quality is good.

  16. Air Pollution.

    ERIC Educational Resources Information Center

    Gilpin, Alan

    A summary of one of our most pressing environmental problems, air pollution, is offered in this book by the Director of Air Pollution Control for the Queensland (Australia) State Government. Discussion of the subject is not restricted to Queensland or Australian problems and policies, however, but includes analysis of air pollution the world over.…

  17. STUDIES OF OXIDANT TRANSPORT BEYOND URBAN AREAS. NEW ENGLAND SEA BREEZE, 1975

    EPA Science Inventory

    Relationships between ambient air quality and sea breeze conditions in southern New England are examined. In the Boston area, sea breeze conditions were observed on approximately 25% of the days of the study (July-August 1975). The sea breeze effect can either moderate or enhance...

  18. Colorful Underwater Sea Creatures

    ERIC Educational Resources Information Center

    McCutcheon, Heather

    2011-01-01

    In this article, the author describes a project wherein students created colorful underwater sea creatures. This project began with a discussion about underwater sea creatures and how they live. The first step was making the multi-colored tissue paper that would become sea creatures and seaweed. Once students had the shapes of their sea creatures…

  19. Sensitivity of modeled atmospheric nitrogen species and nitrogen deposition to variations in sea salt emissions in the North Sea and Baltic Sea regions

    NASA Astrophysics Data System (ADS)

    Neumann, Daniel; Matthias, Volker; Bieser, Johannes; Aulinger, Armin; Quante, Markus

    2016-03-01

    Coarse sea salt particles are emitted ubiquitously from the ocean surface by wave-breaking and bubble-bursting processes. These particles impact the atmospheric chemistry by affecting the condensation of gas-phase species and, thus, indirectly the nucleation of new fine particles, particularly in regions with significant air pollution. In this study, atmospheric particle concentrations are modeled for the North Sea and Baltic Sea regions in northwestern Europe using the Community Multiscale Air Quality (CMAQ) modeling system and are compared to European Monitoring and Evaluation Programme (EMEP) measurement data. The sea salt emission module is extended by a salinity-dependent scaling of the sea salt emissions because the salinity in large parts of the Baltic Sea is very low, which leads to considerably lower sea salt mass emissions compared to other oceanic regions. The resulting improvement in predicted sea salt concentrations is assessed. The contribution of surf zone emissions is considered separately. Additionally, the impacts of sea salt particles on atmospheric nitrate and ammonium concentrations and on nitrogen deposition are evaluated. The comparisons with observational data show that sea salt concentrations are commonly overestimated at coastal stations and partly underestimated farther inland. The introduced salinity scaling improves the predicted Baltic Sea sea salt concentrations considerably. The dates of measured peak concentrations are appropriately reproduced by the model. The impact of surf zone emissions is negligible in both seas. Nevertheless, they might be relevant because surf zone emissions were cut at an upper threshold in this study. Deactivating sea salt leads to minor increases in NH3 + NH4+ and HNO3 + NO3- and a decrease in NO3- concentrations. However, the overall effect on NH3 + NH4+ and HNO3 + NO3- concentrations is smaller than the deviation from the measurements. Nitrogen wet deposition is underestimated by the model at most

  20. Beaufort Sea: information update

    SciTech Connect

    Becker, P.R.

    1988-04-01

    The report is based on a multi-disciplinary meeting held March 6-7, 1985, as part of preparations for the Beaufort Sea Sale 97. The chapters are based on presentations given: The causeway effect: Modification of nearshore thermal regime resulting from causeways; Summertime sea ice intrusions in the Chukchi Sea; The deepwater limit of ice gouging on the Beaufort Sea shelf; Distribution, abundance, migration, harvest, and stock identity of Belukha Whales in the Beaufort Sea; Ringed seals in the Beaufort Sea; Beaufort Sea socioeconomics; The Baffin Island Oil Spill, (BIOS) Project.

  1. Processes driving sea ice variability in the Bering Sea in an eddying ocean/sea ice model: Mean seasonal cycle

    NASA Astrophysics Data System (ADS)

    Li, Linghan; McClean, Julie L.; Miller, Arthur J.; Eisenman, Ian; Hendershott, Myrl C.; Papadopoulos, Caroline A.

    2014-12-01

    The seasonal cycle of sea ice variability in the Bering Sea, together with the thermodynamic and dynamic processes that control it, are examined in a fine resolution (1/10°) global coupled ocean/sea-ice model configured in the Community Earth System Model (CESM) framework. The ocean/sea-ice model consists of the Los Alamos National Laboratory Parallel Ocean Program (POP) and the Los Alamos Sea Ice Model (CICE). The model was forced with time-varying reanalysis atmospheric forcing for the time period 1970-1989. This study focuses on the time period 1980-1989. The simulated seasonal-mean fields of sea ice concentration strongly resemble satellite-derived observations, as quantified by root-mean-square errors and pattern correlation coefficients. The sea ice energy budget reveals that the seasonal thermodynamic ice volume changes are dominated by the surface energy flux between the atmosphere and the ice in the northern region and by heat flux from the ocean to the ice along the southern ice edge, especially on the western side. The sea ice force balance analysis shows that sea ice motion is largely associated with wind stress. The force due to divergence of the internal ice stress tensor is large near the land boundaries in the north, and it is small in the central and southern ice-covered region. During winter, which dominates the annual mean, it is found that the simulated sea ice was mainly formed in the northern Bering Sea, with the maximum ice growth rate occurring along the coast due to cold air from northerly winds and ice motion away from the coast. South of St Lawrence Island, winds drive the model sea ice southwestward from the north to the southwestern part of the ice-covered region. Along the ice edge in the western Bering Sea, model sea ice is melted by warm ocean water, which is carried by the simulated Bering Slope Current flowing to the northwest, resulting in the S-shaped asymmetric ice edge. In spring and fall, similar thermodynamic and dynamic

  2. SeaWiFS Images Fires on Yucatan Peninsula

    NASA Technical Reports Server (NTRS)

    2002-01-01

    This image from the Sea-viewing Wide Field-of-View Sensor (SeaWiFS) shows dense smoke from fires in the Yucatan peninsula on April 24, 2000. In the El Nino year of 1998 fires in the region emitted enough smoke to cause authorities in Texas to issue air quality warnings. For more information, see: SeaWiFS Project Home Page Global Fire Monitoring 4km2 TRMM Fire Data Image provided by the SeaWiFS Project, NASA/Goddard Space Flight Center, and ORBIMAGE

  3. Implementation of an aorcm in the mediterranean sea

    NASA Astrophysics Data System (ADS)

    de Zolt, S.; Lionello, P.; Malguzzi, P.

    2003-04-01

    This study describes a dynamical downscaling in the Mediterranean region, carried out using the coupled atmosphere-ocean-wave model MIAO. The MIAO (Model of Interacting Atmosphere and Ocean) model is composed of three modules, BOLAM (limited area atmospheric circulation model), POM (ocean circulation model) and WAM (ocean waves model), that can be coupled to each other. In the Mediterranean region, which is characterized by complex land-sea distribution, steep orography near the coasts, and intense air-sea interactions, the air-sea fluxes show interesting mesoscale features, important for dense water formation processes and Mediterranean cyclogenesis. In order to study the importance of the coupling between atmosphere and ocean, two two-year long simulations have been carried out in both coupled and uncoupled mode. The differences in the Sea Surface Temperature (SST), precipitation and air-sea interface fields (air-sea fluxes, air temperature, significant wave height, etc.) between the two simulations are discussed. It is stressed that the coupled simulation results in a much better reproduction of the SST annual cycle.

  4. Advanced deep sea diving equipment

    NASA Technical Reports Server (NTRS)

    Danesi, W. A.

    1972-01-01

    Design requirements are generated for a deep sea heavy duty diving system to equip salvage divers with equipment and tools that permit work of the same quality and in times approaching that done on the surface. The system consists of a helmet, a recirculator for removing carbon dioxide, and the diver's dress. The diver controls the inlet flow by the recirculatory control valve and is able to change closed cycle operation to open cycle if malfunction occurs. Proper function of the scrubber in the recirculator minimizes temperature and humidity effects as it filters the returning air.

  5. Sea urchin granuloma.

    PubMed

    Rossetto, André Luiz; de Macedo Mora, Jamesson; Haddad Junior, Vidal

    2006-01-01

    Injuries caused by venomous and poisonous aquatic animals may provoke important morbidity in humans. The phylum Echinoderma include more than 6000 species of starfish, sea urchins, sand dollars, and sea cucumbers some of which have been found responsible for injuries to humans. Initial injuries by sea urchins are associated with trauma and envenomation, but later effects can be observed. Sea urchin granuloma is a chronic granulomatous skin disease caused by frequent and successive penetration of sea urchin spines which have not been removed from wounds. The authors report a typical case of sea urchin granuloma in a fisherman and its therapeutic implications. PMID:17086323

  6. Divergent patterns of recent sea ice cover across the Bering, Chukchi, and Beaufort seas of the Pacific Arctic Region

    NASA Astrophysics Data System (ADS)

    Frey, Karen E.; Moore, G. W. K.; Cooper, Lee W.; Grebmeier, Jacqueline M.

    2015-08-01

    Over the past three decades of the observed satellite record, there have been significant changes in sea ice cover across the Bering, Chukchi, and Beaufort seas of the Pacific Arctic Region (PAR). Satellite data reveal that patterns in sea ice cover have been spatially heterogeneous, with significant declines in the Chukchi and Beaufort seas, yet more complex multi-year variability in the Bering Sea south of St. Lawrence Island. These patterns in the Chukchi and Beaufort seas have intensified since 2000, indicating a regime shift in sea ice cover across the northern portion of the PAR. In particular, satellite data over 1979-2012 reveal localized decreases in sea ice presence of up to -1.64 days/year (Canada Basin) and -1.24 days/year (Beaufort Sea), which accelerated to up to -6.57 days/year (Canada Basin) and -12.84 days/year (Beaufort Sea) over the 2000-2012 time period. In contrast, sea ice in the Bering Sea shows more complex multi-year variability with localized increases in sea ice presence of up to +8.41 days/year since 2000. The observed increases in sea ice cover since 2000 in the southern Bering Sea shelf region are observed in wintertime, whereas sea ice losses in the Canada Basin and Beaufort Sea have occurred during summer. We further compare sea ice variability across the region with the National Centers for Environmental Prediction (NCEP) North American Regional Reanalysis (NARR) wind and air temperature fields to determine the extent to which this recent variability is driven by thermal vs. wind-driven processes. Results suggest that for these localized areas that are experiencing the most rapid shifts in sea ice cover, those in the Beaufort Sea are primarily wind driven, those offshore in the Canada Basin are primarily thermally driven, and those in the Bering Sea are influenced by elements of both. Sea ice variability (and its drivers) across the PAR provides critical insight into the forcing effects of recent shifts in climate and its likely

  7. Primary and Secondary Aerosol Investigation from Different Sea-Waters in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    D'anna, B.; Marchand, N.; Sellegri, K.; Sempéré, R.; Mas, S.; George, C.; Meme, A.; Frihi, A.; Pey, J.; Schwier, A.; Delmont, A.

    2014-12-01

    The Mediterranean Sea is a special marine environment characterized by low biological activity and high anthropogenic pressure. It is often difficult to discriminate the contribution of Primary and Secondary Aerosol formed at the sea-air interface from background level of the aerosol. We therefore decided to study the sea-air exchanges in a controlled environment provided by a 2m3simulation chamber, using freshly collected sea-water samples from the SEMEX site (43°15'64 N, 05°20'01 E) near Marseille bay. Two types of experiments were conducted for 4 weeks testing 3 different sea-waters. Primary sea-aerosol was generated by bubble-bursting method, then introduced in the simulation chamber and exposed to atmospheric oxidants (O3, OH) and light to simulated primary aerosol aging. A second set of experiments focused on secondary particle formation upon illumination and/or ozone exposure of the sea-water surface (15l of sea-water were deposited in a pyrex container located inside the simulation chamber). New particle formation was only observed for relatively high DOC level of the sea-water sample. Particles detection and analysis was followed by a PSM (1nm size), a CPC (2.5nm size), a SMPS (granulometry), a CCN chamber for hygroscopicity studies, a TOF-AMS (Aerodyne) for chemical analysis of the sub-micrometer fraction. Off-line analysis included TEM-EDX samples for morphology and size distribution studies and a hybrid quadrupole-orbitrap mass spectrometer (Thermo Fischer) for the molecular identification of the organic fraction. VOCs were measured on-line by PTR-HR-MS. The seawater samples were filtered at 60μm before use and were daily analyzed for chemical (colored dissolved organic matter, particulate matter and related polar compounds, transparent polysaccharides and nutrients concentration) and biological (chlorophyll a, virus, phytoplankton and zooplankton) analyses.

  8. Aral Sea basin: a sea dies, a sea also rises.

    PubMed

    Glantz, Michael H

    2007-06-01

    The thesis of this article is quite different from many other theses of papers, books, and articles on the Aral Sea. It is meant to purposely highlight the reality of the situation in Central Asia: the Aral Sea that was once a thriving body of water is no more. That sea is dead. What does exist in its place are the Aral seas: there are in essence three bodies of water, one of which is being purposefully restored and its level is rising (the Little Aral), and two others which are still marginally connected, although they continue to decline in level (the Big Aral West and the Big Aral East). In 1960 the level of the sea was about 53 m above sea level. By 2006 the level had dropped by 23 m to 30 m above sea level. This was not a scenario generated by a computer model. It was a process of environmental degradation played out in real life in a matter of a few decades, primarily as a result of human activities. Despite wishes and words to the contrary, it will take a heroic global effort to save what remains of the Big Aral. It would also take a significant degree of sacrifice by people and governments in the region to restore the Big Aral to an acceptable level, given that the annual rate of flow reaching the Amudarya River delta is less than a 10th of what it was several decades ago. Conferring World Heritage status to the Aral Sea(s) could spark restoration efforts for the Big Aral. PMID:17626470

  9. Air Pollution.

    ERIC Educational Resources Information Center

    Fox, Donald L.

    1989-01-01

    Materials related to air pollution are reviewed for the period January 1987, to October 1988. The topics are pollution monitoring, air pollution, and environmental chemistry. The organization consists of two major analytical divisions: (1) gaseous methods; and (2) aerosol and particulate methods. (MVL)

  10. Air Pollution.

    EPA Science Inventory

    Air quality is affected by many types of pollutants that are emitted from various sources, including stationary and mobile. These sources release both criteria and hazardous air pollutants, which cause health effects, ecological harm, and material damage. They are generally categ...

  11. Sea ice transports in the Weddell Sea

    NASA Astrophysics Data System (ADS)

    Harms, Sabine; Fahrbach, Eberhard; Strass, Volker H.

    2001-05-01

    Time series of sea ice draft in the Weddell Sea are evaluated together with hydrographic observations, satellite passive microwave data, and ice drift for estimation of the freshwater fluxes into and out of the Weddell Sea. Ice draft is measured with moored upward looking sonars since 1990 along two transects across the Weddell Gyre. One transect, extending from the tip of the Antarctic Peninsula to Kapp Norvegia, was sampled between 1990 and 1994 and covers the flow into and out of the southern Weddell Sea. The other transect, sampled since 1996 and extending from the Antarctic continent northward along the Greenwich meridian, covers the exchange of water masses between the eastern and the western Weddell Sea. In order to relate results obtained during the different time periods, empirical relationships are established between the length of the sea ice season, derived from the satellite passive microwave data and defined as the number of days per year with the sea ice concentration exceeding 15%, and (1) the annual mean ice draft and (2) the annual mean ice volume transport. By using these empirical relationships, estimates of annual mean ice drafts and ice volume transports are derived at all mooring sites for the period February 1979 through February 1999. Wind and current force a westward ice transport in the coastal areas of the eastern Weddell Sea and a northward ice transport in the west. During the 2-year period 1991/1992 the mean ice volume export from the Weddell Sea is (50 ± 19) × 103 m3 s-1. This freshwater export is representative for a longer-term (20-year) mean and exceeds the average amount of freshwater gained by precipitation and ice shelf melt by about 19×103 m3 s-1, yielding an upper bound for the formation rate of newly ventilated bottom water in the Weddell Sea of 2.6 Sv.

  12. MODIS Global Sea Surface Temperature

    NASA Technical Reports Server (NTRS)

    2002-01-01

    Every day the Moderate-resolution Imaging Spectroradiometer (MODIS) measures sea surface temperature over the entire globe with high accuracy. This false-color image shows a one-month composite for May 2001. Red and yellow indicates warmer temperatures, green is an intermediate value, while blues and then purples are progressively colder values. The new MODIS sea surface temperature product will be particularly useful in studies of temperature anomalies, such as El Nino, as well as research into how air-sea interactions drive changes in weather and climate patterns. In the high resolution image, notice the amazing detail in some of the regional current patterns. For instance, notice the cold water currents that move from Antarctica northward along South America's west coast. These cold, deep waters upwell along an equatorial swath around and to the west of the Galapagos Islands. Note the warm, wide currents of the Gulf Stream moving up the United States' east coast, carrying Caribbean warmth toward Newfoundland and across the Atlantic toward Western Europe. Note the warm tongue of water extending from Africa's east coast to well south of the Cape of Good Hope. MODIS was launched in December 1999 aboard NASA's Terra satellite. For more details on this and other MODIS data products, please see NASA Unveils Spectacular Suite of New Global Data Products from MODIS. Image courtesy MODIS Ocean Group, NASA GSFC, and the University of Miami

  13. Chemical munitions dumped at sea

    NASA Astrophysics Data System (ADS)

    Edwards, Margo; Bełdowski, Jacek

    2016-06-01

    Modern chemical warfare is a byproduct of the industrial revolution, which created factories capable of rapidly producing artillery shells that could be filled with toxic chemicals such as chlorine, phosgene and mustard agent. The trench warfare of World War I inaugurated extensive deployments of modern chemical weapons in 1915. Concomitantly, the need arose to dispose of damaged, captured or excess chemical munitions and their constituents. Whereas today chemical warfare agents (CWA) are destroyed via chemical neutralization processes or high-temperature incineration in tandem with environmental monitoring, in the early to middle 20th century the options for CWA disposal were limited to open-air burning, burial and disposal at sea. The latter option was identified as the least likely of the three to impact mankind, and sea dumping of chemical munitions commenced. Eventually, the potential impacts of sea dumping human waste were recognized, and in 1972 an international treaty, the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, was developed to protect the marine environment from pollution caused by the dumping of wastes and other matter into the ocean. By the time this treaty, referred to as the London Convention, was signed by a majority of nations, millions of tons of munitions were known to have been disposed throughout the world's oceans.

  14. All That Unplowed Sea

    ERIC Educational Resources Information Center

    MOSAIC, 1975

    1975-01-01

    Hunting and gathering at sea may fast be approaching their productive limits. Aquaculture - farming at sea - linked to conservation represents the sea's promise. If the system works, it might prove to be the key to supplying large amounts of food and fresh water at no cost in nonrenewable energy resources. (BT)

  15. Spatial sensitivity of inorganic carbon to model setup: North Sea and Baltic Sea with ECOSMO

    NASA Astrophysics Data System (ADS)

    Castano Primo, Rocio; Schrum, Corinna; Daewel, Ute

    2015-04-01

    In ocean biogeochemical models it is critical to capture the key processes adequately so they do not only reproduce the observations but that those processes are reproduced correctly. One key issue is the choice of parameters, which in most cases are estimates with large uncertainties. This can be the product of actual lack of detailed knowledge of the process, or the manner the processes are implemented, more or less complex. In addition, the model sensitivity is not necessarily homogenous across the spatial domain modelled, which adds another layer of complexity to biogeochemical modelling. In the particular case of the inorganic carbon cycle, there are several sets of carbonate constants that can be chosen. The calculated air-sea CO2 flux is largely dependent on the parametrization chosen. In addition, the different parametrizations all the underlying processes that in some way impact the carbon cycle beyond the carbonate dissociation and fluxes give results that can be significantly different. Examples of these processes are phytoplankton growth rates or remineralization rates. Despite their geographical proximity, the North and Baltic Seas exhibit very different dynamics. The North Sea receives important inflows of Atlantic waters, while the Baltic Sea is an almost enclosed system, with very little exchange from the North Sea. Wind, tides, and freshwater supply act very differently, but dominantly structure the ecosystem dynamics on spatial and temporal scales. The biological community is also different. Cyanobacteria, which are important due to their ability to fix atmospheric nitrogen, and they are only present in the Baltic Sea. These differentiating features have a strong impact in the biogeochemical cycles and ultimately shape the variations in the carbonate chemistry. Here the ECOSMO model was employed on the North Sea and Baltic Sea. The model is set so both are modelled at the same time, instead of having them run separately. ECOSMO is a 3-D coupled

  16. An oceanic heat transport pathway to the Amundsen Sea Embayment

    NASA Astrophysics Data System (ADS)

    Rodriguez, Angelica R.; Mazloff, Matthew R.; Gille, Sarah T.

    2016-05-01

    The Amundsen Sea Embayment (ASE) on the West Antarctic coastline has been identified as a region of accelerated glacial melting. A Southern Ocean State Estimate (SOSE) is analyzed over the 2005-2010 time period in the Amundsen Sea region. The SOSE oceanic heat budget reveals that the contribution of parameterized small-scale mixing to the heat content of the ASE waters is small compared to advection and local air-sea heat flux, both of which contribute significantly to the heat content of the ASE waters. Above the permanent pycnocline, the local air-sea flux dominates the heat budget and is controlled by seasonal changes in sea ice coverage. Overall, between 2005 and 2010, the model shows a net heating in the surface above the pycnocline within the ASE. Sea water below the permanent pycnocline is isolated from the influence of air-sea heat fluxes, and thus, the divergence of heat advection is the major contributor to increased oceanic heat content of these waters. Oceanic transport of mass and heat into the ASE is dominated by the cross-shelf input and is primarily geostrophic below the permanent pycnocline. Diagnosis of the time-mean SOSE vorticity budget along the continental shelf slope indicates that the cross-shelf transport is sustained by vorticity input from the localized wind-stress curl over the shelf break.

  17. Antarctic Sea Ice Patterns and Its Relationship with Climate

    NASA Astrophysics Data System (ADS)

    Barreira, S.

    2015-12-01

    Antarctic sea ice concentration fields show a strong seasonal and interannual variation closely tied to changes in climate patterns. The Ross, Amundsen, Bellingshausen, and Weddell Seas during Summer-Autumn and the Southern Ocean regions north of these areas during Winter-Spring have the greatest sea ice variability. Principal components analysis in T- mode, Varimax-rotated applied on Antarctic monthly sea ice concentration anomaly (SICA) fields for 1979-2015 (NASA Team algorithm data sets available at nsidc.org) revealed the main spatial characteristics of Antarctic sea ice patterns and their relationship with atmospheric circulation. This analysis yielded five patterns of sea ice for winter-spring and three patterns for summer-autumn, each of which has a positive and negative phase. To understand the links between the SICA patterns and climate, we extracted the mean pressure and temperature fields for the months with high loadings (positive or negative) of the sea ice patterns. The first pattern of winter-spring sea ice concentration is a dipole structure between the Drake Passage and northern regions of the Bellingshausen and Weddell Seas and, the South Atlantic Ocean. The negative phase shows a strong negative SICA over the Atlantic basin. This pattern can be associated with to the atmospheric structures related to a positive SAM index and a wave-3 arrangement around the continent. That is, a strong negative pressure anomaly centered over the Bellingshausen Sea accompanied by three positive pressure anomalies in middle-latitudes. For summer-autumn, the first pattern shows two strong positive SICA areas, in the eastern Weddell Sea and the northwestern Ross Sea. A negative SICA covers the Amundsen-Bellingshausen Seas and northwest of the Antarctic Peninsula. This pattern, frequently seen in summers since 2008, is associated with cool conditions over the Weddell Sea but warmer temperatures and high surface air pressure west, north and northwest of the Peninsula.

  18. Sensitivity of modeled atmospheric nitrogen species to variations in sea salt emissions in the North and Baltic Sea regions

    NASA Astrophysics Data System (ADS)

    Neumann, D.; Matthias, V.; Bieser, J.; Aulinger, A.; Quante, M.

    2015-10-01

    Coarse sea salt particles are emitted ubiquitously from the oceans' surfaces by wave breaking and bubble bursting processes. These particles impact atmospheric chemistry by affecting condensation of gas-phase species and nucleation of new fine particles, particularly in regions with high air pollution. In this study, atmospheric particle concentrations are modeled for the North and Baltic Sea regions, Northwestern Europe, using the Community Multiscale Air Quality (CMAQ) modeling system and evaluated against European Monitoring and Evaluation Programme (EMEP) measurement data. As model extension, sea salt emissions are scaled by water salinity because of low salinity in large parts of the Baltic Sea and in certain river estuaries. The resulting improvement in predicted sea salt concentrations is assessed. The contribution of surf zone emissions is separately considered. Additionally, the impact of sea salt particles on atmospheric nitrate, ammonium and sulfate concentrations is evaluated. The comparisons show that sea salt concentrations are commonly overestimated at coastal stations and partly underestimated when going inland. The introduced salinity scaling improves predicted Baltic Sea sea salt concentrations considerably. Dates of measured peak concentrations are appropriately reproduced by the model. The impact of surf zone emissions is negligible in both seas. Nevertheless, they might be relevant because surf zone emissions were cut at an upper threshold in this study. Deactivating sea salt leads to a minor increase of NH4+ and NO3- and a minor decrease of SO42- concentrations. However, the overall effect is very low and lower than the deviation from measurements. Size resolved measurements of Na+, NH4+, NO3-, and SO42- are needed for a more detailed analysis on the impact of sea salt particles.

  19. Seasonal variability of the Red Sea, from GRACE time-variable gravity and altimeter sea surface height measurements

    NASA Astrophysics Data System (ADS)

    Wahr, John; Smeed, David; Leuliette, Eric; Swenson, Sean

    2014-05-01

    Seasonal variability of sea surface height and mass within the Red Sea, occurs mostly through the exchange of heat with the atmosphere and wind-driven inflow and outflow of water through the strait of Bab el Mandab that opens into the Gulf of Aden to the south. The seasonal effects of precipitation and evaporation, of water exchange through the Suez Canal to the north, and of runoff from the adjacent land, are all small. The flow through the Bab el Mandab involves a net mass transfer into the Red Sea during the winter and a net transfer out during the summer. But that flow has a multi-layer pattern, so that in the summer there is actually an influx of cool water at intermediate (~100 m) depths. Thus, summer water in the southern Red Sea is warmer near the surface due to higher air temperatures, but cooler at intermediate depths (especially in the far south). Summer water in the northern Red Sea experiences warming by air-sea exchange only. The temperature profile affects the water density, which impacts the sea surface height but has no effect on vertically integrated mass. Here, we study this seasonal cycle by combining GRACE time-variable mass estimates, altimeter (Jason-1, Jason-2, and Envisat) measurements of sea surface height, and steric sea surface height contributions derived from depth-dependent, climatological values of temperature and salinity obtained from the World Ocean Atlas. We find good consistency, particularly in the northern Red Sea, between these three data types. Among the general characteristics of our results are: (1) the mass contributions to seasonal SSHT variations are much larger than the steric contributions; (2) the mass signal is largest in winter, consistent with winds pushing water into the Red Sea through the Strait of Bab el Mandab in winter, and out during the summer; and (3) the steric signal is largest in summer, consistent with summer sea surface warming.

  20. The structure and formation mechanism of a sea fog event over the Yellow Sea

    NASA Astrophysics Data System (ADS)

    Guo, Jingtian; Li, Pengyuan; Fu, Gang; Zhang, Wei; Gao, Shanhong; Zhang, Suping

    2015-02-01

    In this paper, a heavy sea fog event occurring over the Yellow Sea on 11 April 2004 was investigated based upon observational and modeling analyses. From the observational analyses, this sea fog event is a typical advection cooling case. Sea surface temperature (SST) and specific humidity (SH) show strong gradients from south to north, in which warm water is located in the south and consequently, moisture is larger in the south than in the north due to evaporation processes. After fog formation, evaporation process provides more moisture into the air and further contributes to fog evolution. The sea fog event was reproduced by the Regional Atmospheric Modeling System (RAMS) reasonably. The roles of important physical processes such as radiation, turbulence as well as atmospheric stratification in sea fog's structure and its formation mechanisms were analyzed using the model results. The roles of long wave radiation cooling, turbulence as well as atmospheric stratification were analyzed based on the modeling results. It is found that the long wave radiative cooling at the fog top plays an important role in cooling down the fog layer through turbulence mixing. The fog top cooling can overpower warming from the surface. Sea fog develops upward with the aid of turbulence. The buoyancy term, i.e., the unstable layer, contributes to the generation of TKE in the fog region. However, the temperature inversion layer prevents fog from growing upward.

  1. Regional sea level variability in the Bohai Sea, Yellow Sea, and East China Sea

    NASA Astrophysics Data System (ADS)

    Cheng, Yongcun; Plag, Hans-Peter; Hamlington, Benjamin D.; Xu, Qing; He, Yijun

    2015-12-01

    The regional sea level variability in the Bohai Sea (BS), Yellow Sea (YS) and East China Sea (ECS) is investigated based on tide gauge, satellite altimeter data and an independent oceanic general circulation model for the Earth Simulator (OFES) model outputs. It is found that atmospheric forcing significantly affects local sea level variability in the BS and YS and local sea level variability at the Southern ECS is highly correlated with along-shore currents. Particularly, the annual sea level fluctuations potentially change inundation risk and the frequency and magnitude of flooding in regions with high annual sea level. Hence, the cyclostationary empirical orthogonal function (CSEOF) analysis is carried out to investigate the variations of annual sea level cycle amplitude. Similar spatial distribution characteristics of annual sea level amplitude fluctuations are presented from satellite altimeter data and model outputs. The variability of annual sea level amplitude estimated from the satellite altimeter data agrees well with that from the tide gauge data, and positively (negatively) correlates with Southern Oscillation Index (Pacific Decadal Oscillation). The OFES model, however, underestimates the fluctuation of the annual cycle. After removing the annual signal, the low-passed (i.e., 13-month running mean) tide gauge data shows high correlations with SOI and PDO on time scales over 8 years in the BS and ECS.

  2. Dust Storm, Aral Sea

    NASA Technical Reports Server (NTRS)

    2002-01-01

    The Aral Sea has shrunk to less than half its size since 1985. The Aral Sea receives little water (sometimes no water) from the two major rivers that empty into it-the Syr Darya and Amu Darya. Instead, the river water is diverted to support irrigation for the region's extensive cotton fields. Recently, water scarcity has increased due to a prolonged drought in Central Asia. As the Aral Sea recedes, its former sea bed is exposed. The Aral's sea bed is composed of fine sediments-including fertilizers and other agricultural chemicals-that are easily picked up by the region's strong winds, creating thick dust storms. The International Space Station crew observed and recorded a large dust storm blowing eastward from the Aral Sea in late June 2001. This image illustrates the strong coupling between human activities (water diversions and irrigation), and rapidly changing land, sea and atmospheric processes-the winds blow across the

  3. Air Pollution

    MedlinePlus

    ... tobacco smoke. How is air pollution linked to climate change? While climate change is a global process, it ... ozone levels are also a concern. Impacts of Climate Change on Human Health in the United States: A ...

  4. Air Apparent.

    ERIC Educational Resources Information Center

    Harbster, David A.

    1988-01-01

    Explains the principle upon which a barometer operates. Describes how to construct two barometric devices for use in the classroom that show air's changing pressure. Cites some conditions for predicting weather. (RT)

  5. Recent State of Arctic Sea Ice

    NASA Astrophysics Data System (ADS)

    Nghiem, S. V.; Rigor, I. G.; Clemente-Colón, P.; Perovich, D. K.; Richter-Menge, J. A.; Chao, Y.; Neumann, G.; Ortmeyer, M.

    2008-12-01

    Route, and most of two routes of the Northwest Passage, north and south of Victoria Island, which facilitated ice retreat and the opening of waterways this summer. Most importantly, the shift from a perennial to a seasonal ice covered Arctic Ocean significantly decreases the overall surface albedo resulting in enhanced solar heat absorption in spring and summer, which further decreases the Arctic ice pack through the ice albedo feedback mechanism. In early September 2008, a major melt event occurred over a large region extending from the Beaufort Sea across the Kara Sea toward the Laptev Sea, with active melt areas encroaching in the NP vicinity. This melt event was caused by an advection of warm air from the south, which melted and pushed sea ice away at the same time. At that time, the total extent of Arctic sea ice was about 0.5 million km2 (size of Spain) larger than that at the same time last year.

  6. Dynamical downscaling of warming scenarios with NEMO-Nordic setup for the North Sea and Baltic Sea

    NASA Astrophysics Data System (ADS)

    Gröger, Matthias; Almroth Rosell, Elin; Anderson, Helén; Axell, Lars; Dieterich, Christain; Edman, Moa; Eilola, Kari; Höglund, Anders; Hordoir, Robinson; Hieronymus, Jenny; Karlsson, Bengt; Liu, Ye; Meier, Markus; Pemberton, Per; Saraiva, Sofia

    2016-04-01

    The North Sea and Baltic Sea constitute one of the most complex and challenging areas in the world. The oceanographic setting ranges from quasi open ocean conditions in the northern North Sea to more brackish conditions in the Baltic Sea which is also affected by sea ice in winter. The two seas are connected by narrow straits which sporadically allow the important inflow of salt and oxygen rich bottom waters into the Baltic Sea. For this, the high resolution regional model NEMO-Nordic has recently been developed. Here, the model is applied on hindcast simulations and used to downscale several climate warming scenarios. The model can be interactively coupled to the regional atmosphere model RCA4 by exchanging air sea fluxes of mass and energy (Wang et al., 2015). Comparison with well established models and newly compiled observational data sets (Bersch et al., 2013) indicates NEMO-Nordic performs well on climate relevant time scales. Emphasis is laid on thermal dynamics. Hindcast simulations demonstrate that simulated winter temperatures in the Baltic Sea can benefit from interactive air sea coupling by allowing interactive feedback loops to take place between the ocean and the atmosphere (Gröger et al. 2015). Likewise, a more realistic dynamical behaviour makes the interactive coupled model suitable for dynamic downscaling of climate warming scenarios. Depending on the driving global climate model and IPCC representative concentration pathway scenario NEMO-Nordic shows an average warming of the North Sea between 2 and 4 K at the end of the 21st century. However the warming pattern is spatially inhomogeneous showing strong east west gradients. Involved processes such as circulation changes and changes in radiative forcing will be discussed. Bersch, M., Gouretski, V., Sadikni, R., Hinrichs, I., 2013. Hydrographic climatology of the North Sea and surrounding regions. Centre for Earth System Research and Sustainability, University of Hamburg, www

  7. Odd cloud in the Ross Sea, Antarctica

    NASA Technical Reports Server (NTRS)

    2002-01-01

    On January 28, 2002, MODIS captured this image of an interesting cloud formation in the boundary waters between Antarctica's Ross Sea and the Southern Ocean. A dragon? A snake? A fish? No, but it is an interesting example of the atmospheric physics of convection. The 'eye' of this dragon-looking cloud is likely a small spot of convection, the process by which hot moist air rises up into the atmosphere, often producing big, fluffy clouds as moisture in the air condenses as rises into the colder parts of the atmosphere. A false color analysis that shows different kinds of clouds in different colors reveals that the eye is composed of ice crystals while the 'body' is a liquid water cloud. This suggests that the eye is higher up in the atmosphere than the body. The most likely explanation for the eye feature is that the warm, rising air mass had enough buoyancy to punch through the liquid water cloud. As a convective parcel of air rises into the atmosphere, it pushes the colder air that is higher up out of its way. That cold air spills down over the sides of the convective air mass, and in this case has cleared away part of the liquid cloud layer below in the process. This spilling over of cold air from higher up in the atmosphere is the reason why thunderstorms are often accompanied by a cool breeze. Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC

  8. Estimating microwave emissivity of sea foam by Rayleigh method

    NASA Astrophysics Data System (ADS)

    Liu, Shu-Bo; Wei, En-Bo; Jia, Yan-Xia

    2013-01-01

    To estimate microwave emissivity of sea foam consisting of dense seawater-coated air bubbles, the effective medium approximation is applied by regarding the foam layer as an isotropic dielectric medium. The Rayleigh method is developed to calculate effective permittivity of the sea foam layer at different microwave frequencies, air volume fraction, and seawater coating thickness. With a periodic lattice model of coated bubbles and multilayered structures of effective foam media, microwave emissivities of sea foam layers with different effective permittivities obtained by the Rayleigh method are calculated. Good agreement is obtained by comparing model results with experimental data at 1.4, 10.8, and 36.5 GHz. Furthermore, sea foam microwave emissivities calculated by well-known effective permittivity formulas are investigated, such as the Silberstein, refractive model, and Maxwell-Garnett formulas. Their results are compared with those of our model. It is shown that the Rayleigh method gives more reasonable results.

  9. Rapid formation of a sea ice barrier east of Svalbard

    NASA Astrophysics Data System (ADS)

    Nghiem, S. V.; van Woert, M. L.; Neumann, G.

    2005-11-01

    Daily SeaWinds scatterometer images acquired by the QuikSCAT satellite show an elongated sea ice feature that formed very rapidly (˜1-2 days) in November 2001 east of Svalbard over the Barents Sea. This sea ice structure, called "the Svalbard sea ice barrier," spanning approximately 10° in longitude and 2° in latitude, restricts the sea route and poses a significant navigation hazard. The secret of its formation appears to lie in the bottom of the sea: A comparison between bathymetry from the International Bathymetric Chart of the Arctic Ocean data and the pattern of sea ice formation from scatterometer data reveals that the sea ice barrier conforms well with and stretches above a deep elongated channel connecting the Franz Josef-Victoria Trough to the Hinlopen Basin between Svalbard and Franz Josef Land. Historic hydrographic data from this area indicate that this sea channel contains cold Arctic water less than 50 m below the surface. Strong and persistent cold northerly winds force strong heat loss from this shallow surface layer, leading to the rapid formation of the sea ice barrier. Heat transfer rates estimated from European Centre for Medium-Range Weather Forecasts temperature and wind data over this region suggest that the surface water along the deep channel can be rapidly cooled to the freezing point. Scatterometer results in 1999-2003 show that sea ice forms in this area between October and December. Understanding the ice formation mechanisms helps to select appropriate locations for deployment of buoys measuring wind and air-sea temperature profile and to facilitate ice monitoring, modeling, and forecasting.

  10. ESA Sea Level Climate Change Initiative

    NASA Astrophysics Data System (ADS)

    Larnicol, Gilles; Cazenave, Anny; Faugere, Yannice; Ablain, Michael; Johannessen, Johnny; Stammer, Detlef; Timms, Gary; Knudsen, Per; Cipollini, Paolo; Roca, Monica; Rudenko, Sergei; Fernandes, Joana; Balmaseda, Magdalena; Guinle, Thierry; Benveniste, Jerome

    2013-04-01

    Sea level is a very sensitive index of climate change and variability. As the ocean warms in response to global warming, sea waters expand and, as a result, sea level rises. When mountain glaciers melt in response to increasing air temperature, sea level rises because more freshwater glacial runoff discharges into the oceans. Similarly, ice mass loss from the ice sheets causes sea-level rise. Therefore, understanding the sea level variability and changes implies in addition to the understanding of the ocean variability and the exchanges between ocean, land, cryosphere, and atmosphere, an accurate monitoring of the sea level variable at climate scales. That is why Sea Level is one of the variables selected in the frame of the ESA Climate change Initiative (CCI) program initiated by ESA in July 2010. In overall, this program aims to provide an adequate, comprehensive, and timely response to the extremely challenging set of requirements for highly stable, long-term satellite-based products for climate, that have been addressed to Space Agencies via the Global Climate Observing System (GCOS) and the Committee on Earth Observation Satellites (CEOS). In order to achieve this global objective, the specific objectives of the sea level CCI project are: to involve the climate research community to collect their needs and feedbacks on product quality, to develop, test and select the best algorithms and standards to generate a climate time series (so called SL ECV products), and to provide a complete specification of the production system. After two of projects the first two objectives have been completed. Hereafter, we aim to provide an overview and the current status of the Sea Level project of the ESA Climate Change Initiative (CCI) that has started in july 2010. The main objective of this project is to produce and validate the Sea Level Essential Climate Variable (ECV) product. Two years after the project kick-off, the 20 Years of Progress in Radar Altimetry Symposium was

  11. Monthly average polar sea-ice concentration

    USGS Publications Warehouse

    Schweitzer, Peter N.

    1995-01-01

    The data contained in this CD-ROM depict monthly averages of sea-ice concentration in the modern polar oceans. These averages were derived from the Scanning Multichannel Microwave Radiometer (SMMR) and Special Sensor Microwave/Imager (SSM/I) instruments aboard satellites of the U.S. Air Force Defense Meteorological Satellite Program from 1978 through 1992. The data are provided as 8-bit images using the Hierarchical Data Format (HDF) developed by the National Center for Supercomputing Applications.

  12. Wave Clouds over the Arabian Sea

    NASA Technical Reports Server (NTRS)

    2007-01-01

    Like a massive, ethereal bird gliding into the Persian Gulf, a large cluster of wave clouds spans the Arabian Sea from Oman to India. This cloud formation is likely an undular bore, which is created in the interaction between the cool, dry air in a low-pressure system with a stable layer of warm, moist air. In this case, a low-pressure system probably sits over the Arabian Peninsula, the Gulf of Oman, and Iran and Pakistan. The strong winds generated by the low-pressure system are kicking up clouds of dust from Iran and Pakistan, and, to a lesser degree, Oman. The low-pressure system is also pushing air south-southeast, and this south-moving wave of displaced air pushes ahead of the low-pressure system like a mound of water moving ahead of a boat in calm water. The wave of cool, dry air pushes forward until it meets the wall of warm, moist air that blankets the Arabian Sea. When the two air masses clash, the cool air pushes the warm air up. The warm air rises, cools at the peak of the wave, falls again, and then rises to a slightly lower peak, and so forth, until the wave dissipates. Clouds form at the high-altitude peaks of the waves, with the most defined cloud at the front of the group, where the initial wave formed, followed by increasingly less-defined lines of cloud. The air that moves in front of the low-pressure system does not push forward in a uniform wall; instead it pushes forward in a ragged band, with one part racing ahead of another, like a line of crew racers on a river. Because the air is not uniform, there are small, interacting arcs of waves within the larger band of clouds. Undular bores are rare and hard to predict. This particular undular bore formed over the Arabian Sea on May 8, 2007, when the Moderate Resolution Imaging Spectroradiometer (MODIS) on NASA's Aqua satellite captured this photo-like image. Typical undular bore patterns might display one or two rows of clouds. With more than thirty waves of clouds, this cloud pattern is unusually

  13. Hierarchy and sea ice mechanics: A case study from the Beaufort Sea

    NASA Astrophysics Data System (ADS)

    Overland, James E.; Walter, Bernard A.; Curtin, Thomas B.; Turet, Philip

    1995-03-01

    Hierarchy implies that the study of sea ice can be divided into analysis of subsets of processes based on scale and their interaction with adjacent scales. We apply these concepts to regional sea ice dynamics. The apparent self-similar property of ice floes seen in aircraft or satellite images argues for an aggregate nature of sea ice, that viscouslike regional behavior arises from discrete floe interactions. However, for some regions and some times, characteristic behavior, where lead patterns seen in basin-wide advanced very high resolution radiometer images appear to be related to coastal orientation hundreds of kilometers away, suggests that small regional scale processes O(10 km) and discontinuities in the velocity or stress state along boundaries can affect the larger-scale sea ice distribution and dynamics O(500 km). Thus sea ice displays both aggregate type behavior and discontinuous type behavior based on the history of forcing and shape of the enclosing basin. The appropriate matching of atmospheric processes to sea ice processes in air-ice interaction is through the sea ice deformation field rather than the response of ice velocity to the local wind. This is because atmospheric forcing and sea ice deformation have matching energetic scales at several hundred kilometers and timescales of days. An example of northerly winds during the April 1992 Arctic Leads Experiment period suggests discontinuous type behavior upwind of the Alaska coast followed by a general opening behavior with easterly winds. There appear to be natural scale divisions between climate scale sea ice processes of O(100-300 km) which resolve aggregate behavior, regional scale O(10-50 km) which is necessary to resolve observed shearing behavior, and the floe scale O(1 km). Because the climate scale is two levels removed from the floe scale, care must be exercised in using ice properties from the floe scale in climate scale models; ice strength is an example of such a scale dependent

  14. Temporal variatiions of Sea ice cover in the Baltic Sea derived from operational sea ice products used in NWP.

    NASA Astrophysics Data System (ADS)

    Lange, Martin; Paul, Gerhard; Potthast, Roland

    2014-05-01

    Sea ice cover is a crucial parameter for surface fluxes of heat and moisture over water areas. The isolating effect and the much higher albedo strongly reduces the turbulent exchange of heat and moisture from the surface to the atmosphere and allows for cold and dry air mass flow with strong impact on the stability of the whole boundary layer and consequently cloud formation as well as precipitation in the downstream regions. Numerical weather centers as, ECMWF, MetoFrance or DWD use external products to initialize SST and sea ice cover in their NWP models. To the knowledge of the author there are mainly two global sea ice products well established with operational availability, one from NOAA NCEP that combines measurements with satellite data, and the other from OSI-SAF derived from SSMI/S sensors. The latter one is used in the Ostia product. DWD additionally uses a regional product for the Baltic Sea provided by the national center for shipping and hydrografie which combines observations from ships (and icebreakers) for the German part of the Baltic Sea and model analysis from the hydrodynamic HIROMB model of the Swedish meteorological service for the rest of the domain. The temporal evolution of the three different products are compared for a cold period in Februar 2012. Goods and bads will be presented and suggestions for a harmonization of strong day to day jumps over large areas are suggested.

  15. Sea surface temperature and torrential rains in the Valencia region: modelling the role of recharge areas

    NASA Astrophysics Data System (ADS)

    Pastor, Francisco J.

    2016-04-01

    Heavy rain events are frequently recorded in the Western Mediterranean causing economic and human losses. A main factor in the development of torrential rains is ocean-atmosphere exchange of heat and moisture that can destabilize air masses travelling over the sea. The study of air mass trajectories previous to the rain event permits the identification of sea areas that could probably contribute to the development or intensification of rainfall. From a Mediterranean sea surface temperature climatology, its spatio-temporal distribution patterns have been studied showing two main distribution modes in winter and summer and transitional regimes in spring and autumn. Hence, three heavy precipitation events, for such winter and summer sea temperature regimes and for fall transition, affecting the Valencia region have been selected to study the effect of sea surface temperature in torrential rains. Simulations with perturbed sea surface temperature in different areas along the air mass path were run to compare results with unperturbed simulation. The variation of sea surface temperature in certain areas caused significant changes in model accumulated values and its spatial distribution. Therefore, the existence of areas that at a greater extent favour air-sea interaction leading to the development of torrential rainfall in the Valencia region is shown. This methodology could be extended to other Mediterranean regions to look for such potential recharge areas. The identification of sea areas that contribute to the development or intensification of heavy rain events in the Mediterranean countries could be a useful prognosis and/or monitoring tool.

  16. Polarimetric Signatures of Sea Ice. Part 1; Theoretical Model

    NASA Technical Reports Server (NTRS)

    Nghiem, S. V.; Kwok, R.; Yueh, S. H.; Drinkwater, M. R.

    1995-01-01

    Physical, structural, and electromagnetic properties and interrelating processes in sea ice are used to develop a composite model for polarimetric backscattering signatures of sea ice. Physical properties of sea ice constituents such as ice, brine, air, and salt are presented in terms of their effects on electromagnetic wave interactions. Sea ice structure and geometry of scatterers are related to wave propagation, attenuation, and scattering. Temperature and salinity, which are determining factors for the thermodynamic phase distribution in sea ice, are consistently used to derive both effective permittivities and polarimetric scattering coefficients. Polarimetric signatures of sea ice depend on crystal sizes and brine volumes, which are affected by ice growth rates. Desalination by brine expulsion, drainage, or other mechanisms modifies wave penetration and scattering. Sea ice signatures are further complicated by surface conditions such as rough interfaces, hummocks, snow cover, brine skim, or slush layer. Based on the same set of geophysical parameters characterizing sea ice, a composite model is developed to calculate effective permittivities and backscattering covariance matrices at microwave frequencies for interpretation of sea ice polarimetric signatures.

  17. Polarimetric signatures of sea ice. 1: Theoretical model

    NASA Technical Reports Server (NTRS)

    Nghiem, S. V.; Kwok, R.; Yueh, S. H.; Drinkwater, M. R.

    1995-01-01

    Physical, structral, and electromagnetic properties and interrelating processes in sea ice are used to develop a composite model for polarimetric backscattering signatures of sea ice. Physical properties of sea ice constituents such as ice, brine, air, and salt are presented in terms of their effects on electromagnetic wave interactions. Sea ice structure and geometry of scatterers are related to wave propagation, attenuation, and scattering. Temperature and salinity, which are determining factors for the thermodynamic phase distribution in sea ice, are consistently used to derive both effective permittivities and polarimetric scattering coefficients. Polarmetric signatures of sea ice depend on crystal sizes and brine volumes, which are affected by ice growth rates. Desalination by brine expulsion, drainage, or other mechanisms modifies wave penetration and scattering. Sea ice signatures are further complicated by surface conditions such as rough interfaces, hummocks, snow cover, brine skim, or slush layer. Based on the same set of geophysical parameters characterizing sea ice, a composite model is developed to calculate effective permittivities and backscattering covariance matrices at microwave frequencies to interpretation of sea ice polarimetric signatures.

  18. A destabilizing thermohaline circulation-atmosphere-sea ice feedback

    SciTech Connect

    Jayne, S.R.; Marotzke, J.

    1999-02-01

    Some of the interactions and feedbacks between the atmosphere, thermohaline circulation, and sea ice are illustrated using a simple process model. A simplified version of the annual-mean coupled ocean-atmosphere box model of Nakamura, Stone, and Marotzke is modified to include a parameterization of sea ice. The model includes the thermodynamic effects of sea ice and allows for variable coverage. It is found that the addition of sea ice introduces feedbacks that have a destabilizing influence on the thermohaline circulation: Sea ice insulates the ocean from the atmosphere, creating colder air temperatures at high latitudes, which cause larger atmospheric eddy heat and moisture transports and weaker oceanic heat transports. These in turn lead to thicker ice coverage and hence establish a positive feedback. The results indicate that generally in colder climates, the presence of sea ice may lead to a significant destabilization of the thermohaline circulation. Brine rejection by sea ice plays no important role in this model`s dynamics. The net destabilizing effect of sea ice in this model is the result of two positive feedbacks and one negative feedback and is shown to be model dependent. To date, the destabilizing feedback between atmospheric and oceanic heat fluxes, mediated by sea ice, has largely been neglected in conceptual studies of thermohaline circulation stability, but it warrants further investigation in more realistic models.

  19. Air surveillance

    SciTech Connect

    Patton, G.W.

    1995-06-01

    This section of the 1994 Hanford Site Environmental Report summarizes the air surveillance and monitoring programs currently in operation at that Hanford Site. Atmospheric releases of pollutants from Hanford to the surrounding region are a potential source of human exposure. For that reason, both radioactive and nonradioactive materials in air are monitored at a number of locations. The influence of Hanford emissions on local radionuclide concentrations was evaluated by comparing concentrations measured at distant locations within the region to concentrations measured at the Site perimeter. This section discusses sample collection, analytical methods, and the results of the Hanford air surveillance program. A complete listing of all analytical results summarized in this section is reported separately by Bisping (1995).

  20. East Siberian Sea, Russia

    NASA Technical Reports Server (NTRS)

    2002-01-01

    The winter sea ice in the east Siberian Sea is looking a bit like a cracked windshield in these true-color Moderate Resolution Imaging Spectroradiometer (MODIS) images from June 16 and 23, 2002. North of the thawing tundra, the sea ice takes on its cracked, bright blue appearance as it thins, which allows the reflection of the water to show through. Numerous still-frozen lakes dot the tundra. Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC

  1. Decreasing intensity of open-ocean convection in the Greenland and Iceland seas

    NASA Astrophysics Data System (ADS)

    Moore, G. W. K.; Våge, K.; Pickart, R. S.; Renfrew, I. A.

    2015-09-01

    The air-sea transfer of heat and fresh water plays a critical role in the global climate system. This is particularly true for the Greenland and Iceland seas, where these fluxes drive ocean convection that contributes to Denmark Strait overflow water, the densest component of the lower limb of the Atlantic Meridional Overturning Circulation (AMOC; ref. ). Here we show that the wintertime retreat of sea ice in the region, combined with different rates of warming for the atmosphere and sea surface of the Greenland and Iceland seas, has resulted in statistically significant reductions of approximately 20% in the magnitude of the winter air-sea heat fluxes since 1979. We also show that modes of climate variability other than the North Atlantic Oscillation (NAO; refs , , , , ) are required to fully characterize the regional air-sea interaction. Mixed-layer model simulations imply that further decreases in atmospheric forcing will exceed a threshold for the Greenland Sea whereby convection will become depth limited, reducing the ventilation of mid-depth waters in the Nordic seas. In the Iceland Sea, further reductions have the potential to decrease the supply of the densest overflow waters to the AMOC (ref. ).

  2. High Lapse Rates in AIRS Retrieved Temperatures in Cold Air Outbreaks

    NASA Technical Reports Server (NTRS)

    Fetzer, Eric J.; Kahn, Brian; Olsen, Edward T.; Fishbein, Evan

    2004-01-01

    The Atmospheric Infrared Sounder (AIRS) experiment, on NASA's Aqua spacecraft, uses a combination of infrared and microwave observations to retrieve cloud and surface properties, plus temperature and water vapor profiles comparable to radiosondes throughout the troposphere, for cloud cover up to 70%. The high spectral resolution of AIRS provides sensitivity to important information about the near-surface atmosphere and underlying surface. A preliminary analysis of AIRS temperature retrievals taken during January 2003 reveals extensive areas of superadiabatic lapse rates in the lowest kilometer of the atmosphere. These areas are found predominantly east of North America over the Gulf Stream, and, off East Asia over the Kuroshio Current. Accompanying the high lapse rates are low air temperatures, large sea-air temperature differences, and low relative humidities. Imagery from a Visible / Near Infrared instrument on the AIRS experiment shows accompanying clouds. These lines of evidence all point to shallow convection in the bottom layer of a cold air mass overlying warm water, with overturning driven by heat flow from ocean to atmosphere. An examination of operational radiosondes at six coastal stations in Japan shows AIRS to be oversensitive to lower tropospheric lapse rates due to systematically warm near-surface air temperatures. The bias in near-surface air temperature is seen to be independent of sea surface temperature, however. AIRS is therefore sensitive to air-sea temperature difference, but with a warm atmospheric bias. A regression fit to radiosondes is used to correct AIRS near-surface retrieved temperatures, and thereby obtain an estimate of the true atmosphere-ocean thermal contrast in five subtropical regions across the north Pacific. Moving eastward, we show a systematic shift in this air-sea temperature differences toward more isothermal conditions. These results, while preliminary, have implications for our understanding of heat flow from ocean to

  3. Large-Scale Environmental Influences on the Onset, Maintenance, and Dissipation of Six Sea Fog Cases over the Yellow Sea

    NASA Astrophysics Data System (ADS)

    Li, Pengyuan; Fu, Gang; Lu, Chungu

    2012-05-01

    Sea fog is typically formed and developed under a set of favorable environmental conditions, which are associated with the station pressure changes, sea level pressure, winds, temperature, water vapor supply, and sea surface temperature. Understanding of these environmental factors during the evolution of a sea fog episode is crucial for forecasting the occurrence and severity of sea fogs over the ocean and adjacent coastal areas. In this study, the large-scale environment variability of six fog events over the Yellow Sea was investigated. It was realized in the present study that the northwest Pacific Ocean high (NPH) is vital to fog formation over the Yellow Sea. In our study, six fog cases can be basically divided into two types: (1) pressure-weakening type, (2) pressure-strengthening type. The former type happened in spring and the latter type in summer. Prevailing southerly winds, accompanied with the well-positioned NPH, may supply a large amount of warm water vapor for the fog formation and maintenance. The intensity of the air temperature inversion is stronger in summer cases than that in spring ones. The wind direction change from south to north and the unstable lower atmosphere may lead to fog's dissipation. This study may provide a comprehensive understanding of sea fog's onset, maintenance, and dissipation over the Yellow Sea.

  4. Iodocarbons and Bromocarbons Associated with Arctic Sea Ice

    NASA Astrophysics Data System (ADS)

    Roscoe, H. K.; Obbard, R. W.; Atkinson, H. M.; Hughes, C.; Liss, P. S.

    2015-12-01

    Short-lived halocarbons were measured in Arctic sea-ice brine, seawater and air above the Greenland and Norwegian seas at about 81°N in mid-summer, from a melting ice floe at the edge of the ice pack. In the ice floe, concentrations of C2H5I, 2-C3H7I and CH2Br2 showed significant enhancement in the sea ice brine, of average factors of 1.7, 1.4 and 2.5 times respectively, compared to the water underneath and after normalising to brine volume. Concentrations of mono-iodocarbons in air are the highest ever reported, and our calculations suggest increased fluxes of halocarbons to the atmosphere may result from their sea-ice enhancement. Laboratory measurements suggest that sea-ice diatoms produce iodocarbons in response to salinity stress. Concentrations of halocarbons in the Arctic ice were similar to those in earlier work in Antarctic sea ice that was similarly warm and porous. As climate warms and Arctic sea ice becomes more like that of the Antarctic, our results lead us to expect the production of iodocarbons and so of reactive iodine gases to increase.

  5. Air Pollution.

    ERIC Educational Resources Information Center

    Scorer, Richard S.

    The purpose of this book is to describe the basic mechanisms whereby pollution is transported and diffused in the atmosphere. It is designed to give practitioners an understanding of basic mechanics and physics so they may have a correct basis on which to formulate their decisions related to practical air pollution control problems. Since many…

  6. /Air Atmospheres

    NASA Astrophysics Data System (ADS)

    Emami, Samar; Sohn, Hong Yong; Kim, Hang Goo

    2014-08-01

    Molten magnesium oxidizes rapidly when exposed to air causing melt loss and handling difficulties. The use of certain additive gases such as SF6, SO2, and CO2 to form a protective MgO layer over a magnesium melt has been proposed. The oxidation behavior of molten magnesium in air containing various concentrations of SF6 was investigated. Measurements of the kinetics of the oxide layer growth at various SF6 concentrations in air and temperatures were made. Experiments were performed using a thermogravimetric analysis unit in the temperature range of 943 K to 1043 K (670 °C to 770 °C). Results showed that a thin, coherent, and protective MgF2 layer was formed under SF6/Air mixtures, with a thickness ranging from 300 nm to 3 μm depending on SF6 concentration, temperature, and exposure time. Rate parameters were calculated and a model for the process was developed. The morphology and composition of the surface films were studied using scanning electron microscope and energy-dispersive spectroscope.

  7. Air Pollution

    PubMed Central

    Clifton, Marjorie

    1964-01-01

    Dr Marjorie Clifton describes the classification of gaseous and nongaseous constituents of air pollution and then outlines the methods of measuring these. The National Survey embraced 150 towns of all sizes throughout England and Wales and provided data on smoke and sulphur dioxide in relation to climate, topography, industrialization, population density, fuel utilization and urban development. Dr W C Turner discusses the relationship between air pollution and mortality from respiratory conditions, and particularly the incidence of chronic bronchitis. He postulates a theory that such respiratory conditions arise as an allergy to the spores of certain moulds, spore formation being encouraged by the air humidity in Greatv Britain and overcrowded and damp living conditions. He describes the results of a twenty-week study undertaken in 1962-3, showing associations between respiratory disease and levels of air pollution. Dr Stuart Carne undertook a survey in general practice to plot the patterns of respiratory illness in London during the winter of 1962-3. There were two peaks of respiratory illnesses coinciding with the fog at the beginning of December and the freeze-up from the end of December until the beginning of March. PMID:14178955

  8. Air Trafficco

    ERIC Educational Resources Information Center

    Kasunic, Kevin

    1970-01-01

    The work of the 14,000 air traffic controllers can be both challenging and nerve-racking. Concentration, steady nerves, and a clear voice are required to remember the routing and identification of the maze of aircraft and to instruct each of them accurately. Controllers must have a high school diploma and three years work experience or a college…

  9. The role of sea ice in 2 x CO2 climate model sensitivity. Part 1: The total influence of sea ice thickness and extent

    NASA Technical Reports Server (NTRS)

    Rind, D.; Healy, R.; Parkinson, C.; Martinson, D.

    1995-01-01

    As a first step in investigating the effects of sea ice changes on the climate sensitivity to doubled atmospheric CO2, the authors use a standard simple sea ice model while varying the sea ice distributions and thicknesses in the control run. Thinner ice amplifies the atmospheric temperature senstivity in the